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1
6405-6408
14 Give two reactions that show the acidic nature of phenol Compare acidity of phenol with that of ethanol 7 15 Explain why is ortho nitrophenol more acidic than ortho methoxyphenol
1
6406-6409
Compare acidity of phenol with that of ethanol 7 15 Explain why is ortho nitrophenol more acidic than ortho methoxyphenol 7
1
6407-6410
7 15 Explain why is ortho nitrophenol more acidic than ortho methoxyphenol 7 16 Explain how does the –OH group attached to a carbon of benzene ring activate it towards electrophilic substitution
1
6408-6411
15 Explain why is ortho nitrophenol more acidic than ortho methoxyphenol 7 16 Explain how does the –OH group attached to a carbon of benzene ring activate it towards electrophilic substitution 7
1
6409-6412
7 16 Explain how does the –OH group attached to a carbon of benzene ring activate it towards electrophilic substitution 7 17 Give equations of the following reactions: (i) Oxidation of propan-1-ol with alkaline KMnO4 solution
1
6410-6413
16 Explain how does the –OH group attached to a carbon of benzene ring activate it towards electrophilic substitution 7 17 Give equations of the following reactions: (i) Oxidation of propan-1-ol with alkaline KMnO4 solution (ii) Bromine in CS2 with phenol
1
6411-6414
7 17 Give equations of the following reactions: (i) Oxidation of propan-1-ol with alkaline KMnO4 solution (ii) Bromine in CS2 with phenol (iii) Dilute HNO3 with phenol
1
6412-6415
17 Give equations of the following reactions: (i) Oxidation of propan-1-ol with alkaline KMnO4 solution (ii) Bromine in CS2 with phenol (iii) Dilute HNO3 with phenol (iv) Treating phenol wih chloroform in presence of aqueous NaOH
1
6413-6416
(ii) Bromine in CS2 with phenol (iii) Dilute HNO3 with phenol (iv) Treating phenol wih chloroform in presence of aqueous NaOH 7
1
6414-6417
(iii) Dilute HNO3 with phenol (iv) Treating phenol wih chloroform in presence of aqueous NaOH 7 18 Explain the following with an example
1
6415-6418
(iv) Treating phenol wih chloroform in presence of aqueous NaOH 7 18 Explain the following with an example (i) Kolbe’s reaction
1
6416-6419
7 18 Explain the following with an example (i) Kolbe’s reaction (ii) Reimer-Tiemann reaction
1
6417-6420
18 Explain the following with an example (i) Kolbe’s reaction (ii) Reimer-Tiemann reaction (iii) Williamson ether synthesis
1
6418-6421
(i) Kolbe’s reaction (ii) Reimer-Tiemann reaction (iii) Williamson ether synthesis (iv) Unsymmetrical ether
1
6419-6422
(ii) Reimer-Tiemann reaction (iii) Williamson ether synthesis (iv) Unsymmetrical ether 7
1
6420-6423
(iii) Williamson ether synthesis (iv) Unsymmetrical ether 7 19 Write the mechanism of acid dehydration of ethanol to yield ethene
1
6421-6424
(iv) Unsymmetrical ether 7 19 Write the mechanism of acid dehydration of ethanol to yield ethene 7
1
6422-6425
7 19 Write the mechanism of acid dehydration of ethanol to yield ethene 7 20 How are the following conversions carried out
1
6423-6426
19 Write the mechanism of acid dehydration of ethanol to yield ethene 7 20 How are the following conversions carried out (i) Propene ® Propan-2-ol
1
6424-6427
7 20 How are the following conversions carried out (i) Propene ® Propan-2-ol (ii) Benzyl chloride ® Benzyl alcohol
1
6425-6428
20 How are the following conversions carried out (i) Propene ® Propan-2-ol (ii) Benzyl chloride ® Benzyl alcohol (iii) Ethyl magnesium chloride ® Propan-1-ol
1
6426-6429
(i) Propene ® Propan-2-ol (ii) Benzyl chloride ® Benzyl alcohol (iii) Ethyl magnesium chloride ® Propan-1-ol (iv) Methyl magnesium bromide ® 2-Methylpropan-2-ol
1
6427-6430
(ii) Benzyl chloride ® Benzyl alcohol (iii) Ethyl magnesium chloride ® Propan-1-ol (iv) Methyl magnesium bromide ® 2-Methylpropan-2-ol 7
1
6428-6431
(iii) Ethyl magnesium chloride ® Propan-1-ol (iv) Methyl magnesium bromide ® 2-Methylpropan-2-ol 7 21 Name the reagents used in the following reactions: (i) Oxidation of a primary alcohol to carboxylic acid
1
6429-6432
(iv) Methyl magnesium bromide ® 2-Methylpropan-2-ol 7 21 Name the reagents used in the following reactions: (i) Oxidation of a primary alcohol to carboxylic acid (ii) Oxidation of a primary alcohol to aldehyde
1
6430-6433
7 21 Name the reagents used in the following reactions: (i) Oxidation of a primary alcohol to carboxylic acid (ii) Oxidation of a primary alcohol to aldehyde (iii) Bromination of phenol to 2,4,6-tribromophenol
1
6431-6434
21 Name the reagents used in the following reactions: (i) Oxidation of a primary alcohol to carboxylic acid (ii) Oxidation of a primary alcohol to aldehyde (iii) Bromination of phenol to 2,4,6-tribromophenol (iv) Benzyl alcohol to benzoic acid
1
6432-6435
(ii) Oxidation of a primary alcohol to aldehyde (iii) Bromination of phenol to 2,4,6-tribromophenol (iv) Benzyl alcohol to benzoic acid (v) Dehydration of propan-2-ol to propene
1
6433-6436
(iii) Bromination of phenol to 2,4,6-tribromophenol (iv) Benzyl alcohol to benzoic acid (v) Dehydration of propan-2-ol to propene (vi) Butan-2-one to butan-2-ol
1
6434-6437
(iv) Benzyl alcohol to benzoic acid (v) Dehydration of propan-2-ol to propene (vi) Butan-2-one to butan-2-ol 7
1
6435-6438
(v) Dehydration of propan-2-ol to propene (vi) Butan-2-one to butan-2-ol 7 22 Give reason for the higher boiling point of ethanol in comparison to methoxymethane
1
6436-6439
(vi) Butan-2-one to butan-2-ol 7 22 Give reason for the higher boiling point of ethanol in comparison to methoxymethane Rationalised 2023-24 224 Chemistry 7
1
6437-6440
7 22 Give reason for the higher boiling point of ethanol in comparison to methoxymethane Rationalised 2023-24 224 Chemistry 7 23 Give IUPAC names of the following ethers: 7
1
6438-6441
22 Give reason for the higher boiling point of ethanol in comparison to methoxymethane Rationalised 2023-24 224 Chemistry 7 23 Give IUPAC names of the following ethers: 7 24 Write the names of reagents and equations for the preparation of the following ethers by Williamson’s synthesis: (i) 1-Propoxypropane (ii) Ethoxybenzene (iii) 2-Methoxy-2-methylpropane (iv) 1-Methoxyethane 7
1
6439-6442
Rationalised 2023-24 224 Chemistry 7 23 Give IUPAC names of the following ethers: 7 24 Write the names of reagents and equations for the preparation of the following ethers by Williamson’s synthesis: (i) 1-Propoxypropane (ii) Ethoxybenzene (iii) 2-Methoxy-2-methylpropane (iv) 1-Methoxyethane 7 25 Illustrate with examples the limitations of Williamson synthesis for the preparation of certain types of ethers
1
6440-6443
23 Give IUPAC names of the following ethers: 7 24 Write the names of reagents and equations for the preparation of the following ethers by Williamson’s synthesis: (i) 1-Propoxypropane (ii) Ethoxybenzene (iii) 2-Methoxy-2-methylpropane (iv) 1-Methoxyethane 7 25 Illustrate with examples the limitations of Williamson synthesis for the preparation of certain types of ethers 7
1
6441-6444
24 Write the names of reagents and equations for the preparation of the following ethers by Williamson’s synthesis: (i) 1-Propoxypropane (ii) Ethoxybenzene (iii) 2-Methoxy-2-methylpropane (iv) 1-Methoxyethane 7 25 Illustrate with examples the limitations of Williamson synthesis for the preparation of certain types of ethers 7 26 How is 1-propoxypropane synthesised from propan-1-ol
1
6442-6445
25 Illustrate with examples the limitations of Williamson synthesis for the preparation of certain types of ethers 7 26 How is 1-propoxypropane synthesised from propan-1-ol Write mechanism of this reaction
1
6443-6446
7 26 How is 1-propoxypropane synthesised from propan-1-ol Write mechanism of this reaction 7
1
6444-6447
26 How is 1-propoxypropane synthesised from propan-1-ol Write mechanism of this reaction 7 27 Preparation of ethers by acid dehydration of secondary or tertiary alcohols is not a suitable method
1
6445-6448
Write mechanism of this reaction 7 27 Preparation of ethers by acid dehydration of secondary or tertiary alcohols is not a suitable method Give reason
1
6446-6449
7 27 Preparation of ethers by acid dehydration of secondary or tertiary alcohols is not a suitable method Give reason 7
1
6447-6450
27 Preparation of ethers by acid dehydration of secondary or tertiary alcohols is not a suitable method Give reason 7 28 Write the equation of the reaction of hydrogen iodide with: (i) 1-propoxypropane (ii) methoxybenzene and (iii) benzyl ethyl ether
1
6448-6451
Give reason 7 28 Write the equation of the reaction of hydrogen iodide with: (i) 1-propoxypropane (ii) methoxybenzene and (iii) benzyl ethyl ether 7
1
6449-6452
7 28 Write the equation of the reaction of hydrogen iodide with: (i) 1-propoxypropane (ii) methoxybenzene and (iii) benzyl ethyl ether 7 29 Explain the fact that in aryl alkyl ethers (i) the alkoxy group activates the benzene ring towards electrophilic substitution and (ii) it directs the incoming substituents to ortho and para positions in benzene ring
1
6450-6453
28 Write the equation of the reaction of hydrogen iodide with: (i) 1-propoxypropane (ii) methoxybenzene and (iii) benzyl ethyl ether 7 29 Explain the fact that in aryl alkyl ethers (i) the alkoxy group activates the benzene ring towards electrophilic substitution and (ii) it directs the incoming substituents to ortho and para positions in benzene ring 7
1
6451-6454
7 29 Explain the fact that in aryl alkyl ethers (i) the alkoxy group activates the benzene ring towards electrophilic substitution and (ii) it directs the incoming substituents to ortho and para positions in benzene ring 7 30 Write the mechanism of the reaction of HI with methoxymethane
1
6452-6455
29 Explain the fact that in aryl alkyl ethers (i) the alkoxy group activates the benzene ring towards electrophilic substitution and (ii) it directs the incoming substituents to ortho and para positions in benzene ring 7 30 Write the mechanism of the reaction of HI with methoxymethane 7
1
6453-6456
7 30 Write the mechanism of the reaction of HI with methoxymethane 7 31 Write equations of the following reactions: (i) Friedel-Crafts reaction – alkylation of anisole
1
6454-6457
30 Write the mechanism of the reaction of HI with methoxymethane 7 31 Write equations of the following reactions: (i) Friedel-Crafts reaction – alkylation of anisole (ii) Nitration of anisole
1
6455-6458
7 31 Write equations of the following reactions: (i) Friedel-Crafts reaction – alkylation of anisole (ii) Nitration of anisole (iii) Bromination of anisole in ethanoic acid medium
1
6456-6459
31 Write equations of the following reactions: (i) Friedel-Crafts reaction – alkylation of anisole (ii) Nitration of anisole (iii) Bromination of anisole in ethanoic acid medium (iv) Friedel-Craft’s acetylation of anisole
1
6457-6460
(ii) Nitration of anisole (iii) Bromination of anisole in ethanoic acid medium (iv) Friedel-Craft’s acetylation of anisole 7
1
6458-6461
(iii) Bromination of anisole in ethanoic acid medium (iv) Friedel-Craft’s acetylation of anisole 7 32 Show how would you synthesise the following alcohols from appropriate alkenes
1
6459-6462
(iv) Friedel-Craft’s acetylation of anisole 7 32 Show how would you synthesise the following alcohols from appropriate alkenes CH3 OH OH OH OH (i) (ii) (iii) (iv) 7
1
6460-6463
7 32 Show how would you synthesise the following alcohols from appropriate alkenes CH3 OH OH OH OH (i) (ii) (iii) (iv) 7 33 When 3-methylbutan-2-ol is treated with HBr, the following reaction takes place: Give a mechanism for this reaction
1
6461-6464
32 Show how would you synthesise the following alcohols from appropriate alkenes CH3 OH OH OH OH (i) (ii) (iii) (iv) 7 33 When 3-methylbutan-2-ol is treated with HBr, the following reaction takes place: Give a mechanism for this reaction (Hint : The secondary carbocation formed in step II rearranges to a more stable tertiary carbocation by a hydride ion shift from 3rd carbon atom
1
6462-6465
CH3 OH OH OH OH (i) (ii) (iii) (iv) 7 33 When 3-methylbutan-2-ol is treated with HBr, the following reaction takes place: Give a mechanism for this reaction (Hint : The secondary carbocation formed in step II rearranges to a more stable tertiary carbocation by a hydride ion shift from 3rd carbon atom Rationalised 2023-24 225 Alcohols, Phenols and Ethers Answers to Some Intext Questions 7
1
6463-6466
33 When 3-methylbutan-2-ol is treated with HBr, the following reaction takes place: Give a mechanism for this reaction (Hint : The secondary carbocation formed in step II rearranges to a more stable tertiary carbocation by a hydride ion shift from 3rd carbon atom Rationalised 2023-24 225 Alcohols, Phenols and Ethers Answers to Some Intext Questions 7 1 Primary alcohols (i), (ii), (iii) Secondary alcohols (iv) and (v) Tertiary alcohols (vi) 7
1
6464-6467
(Hint : The secondary carbocation formed in step II rearranges to a more stable tertiary carbocation by a hydride ion shift from 3rd carbon atom Rationalised 2023-24 225 Alcohols, Phenols and Ethers Answers to Some Intext Questions 7 1 Primary alcohols (i), (ii), (iii) Secondary alcohols (iv) and (v) Tertiary alcohols (vi) 7 2 Allylic alcohols (ii) and (vi) 7
1
6465-6468
Rationalised 2023-24 225 Alcohols, Phenols and Ethers Answers to Some Intext Questions 7 1 Primary alcohols (i), (ii), (iii) Secondary alcohols (iv) and (v) Tertiary alcohols (vi) 7 2 Allylic alcohols (ii) and (vi) 7 3 (i) 4-Chloro-3-ethyl-2-(1-methylethyl)-butan-1-ol (ii) 2, 5-Dimethylhexane-1,3-diol (iii) 3-Bromocyclohexanol (iv) Hex-1-en-3-ol (v) 2-Bromo-3-methylbut-2-en-1-ol 7
1
6466-6469
1 Primary alcohols (i), (ii), (iii) Secondary alcohols (iv) and (v) Tertiary alcohols (vi) 7 2 Allylic alcohols (ii) and (vi) 7 3 (i) 4-Chloro-3-ethyl-2-(1-methylethyl)-butan-1-ol (ii) 2, 5-Dimethylhexane-1,3-diol (iii) 3-Bromocyclohexanol (iv) Hex-1-en-3-ol (v) 2-Bromo-3-methylbut-2-en-1-ol 7 4 7
1
6467-6470
2 Allylic alcohols (ii) and (vi) 7 3 (i) 4-Chloro-3-ethyl-2-(1-methylethyl)-butan-1-ol (ii) 2, 5-Dimethylhexane-1,3-diol (iii) 3-Bromocyclohexanol (iv) Hex-1-en-3-ol (v) 2-Bromo-3-methylbut-2-en-1-ol 7 4 7 5 CH3 CH3 CH (i) OH OH (ii) CH2 C OCH3 O CH3 CH OH 2 CH (iii) CH3 CH2 7
1
6468-6471
3 (i) 4-Chloro-3-ethyl-2-(1-methylethyl)-butan-1-ol (ii) 2, 5-Dimethylhexane-1,3-diol (iii) 3-Bromocyclohexanol (iv) Hex-1-en-3-ol (v) 2-Bromo-3-methylbut-2-en-1-ol 7 4 7 5 CH3 CH3 CH (i) OH OH (ii) CH2 C OCH3 O CH3 CH OH 2 CH (iii) CH3 CH2 7 7 (i) 1-Methylcyclohexene (ii) A Mixture of but-1-ene and but-2-ene
1
6469-6472
4 7 5 CH3 CH3 CH (i) OH OH (ii) CH2 C OCH3 O CH3 CH OH 2 CH (iii) CH3 CH2 7 7 (i) 1-Methylcyclohexene (ii) A Mixture of but-1-ene and but-2-ene But-2-ene is the major product formed due to rearrangement to give secondary carbocation
1
6470-6473
5 CH3 CH3 CH (i) OH OH (ii) CH2 C OCH3 O CH3 CH OH 2 CH (iii) CH3 CH2 7 7 (i) 1-Methylcyclohexene (ii) A Mixture of but-1-ene and but-2-ene But-2-ene is the major product formed due to rearrangement to give secondary carbocation 7
1
6471-6474
7 (i) 1-Methylcyclohexene (ii) A Mixture of but-1-ene and but-2-ene But-2-ene is the major product formed due to rearrangement to give secondary carbocation 7 10 C H OH 2 5 CH3 – CH2 – CH – CH3 CH – ONa CH3 HBr C H Br 2 5 C H Br 2 5 + CH3 – CH2 – CH – CH3 CH – OC H 2 5 CH3 2-Ethoxy-3-methylpentane Rationalised 2023-24 226 Chemistry 7
1
6472-6475
But-2-ene is the major product formed due to rearrangement to give secondary carbocation 7 10 C H OH 2 5 CH3 – CH2 – CH – CH3 CH – ONa CH3 HBr C H Br 2 5 C H Br 2 5 + CH3 – CH2 – CH – CH3 CH – OC H 2 5 CH3 2-Ethoxy-3-methylpentane Rationalised 2023-24 226 Chemistry 7 11 (ii) 7
1
6473-6476
7 10 C H OH 2 5 CH3 – CH2 – CH – CH3 CH – ONa CH3 HBr C H Br 2 5 C H Br 2 5 + CH3 – CH2 – CH – CH3 CH – OC H 2 5 CH3 2-Ethoxy-3-methylpentane Rationalised 2023-24 226 Chemistry 7 11 (ii) 7 12 (i)  3 2 2 3 CH CH CH OH CH Br (ii) (iii) (iv)  3 2 5 3 CH C I C H OH   Rationalised 2023-24 After studying this Unit, you will be •able to write the common and IUPAC names of aldehydes, ketones and carboxylic acids; • write the structures of the compounds containing functional groups namely carbonyl and carboxyl groups; • describe the important methods of preparation and reactions of these classes of compounds; • correlate physical properties and chemical reactions of aldehydes, ketones and carboxylic acids, with their structures; • explain the mechanism of a few selected reactions of aldehydes and ketones; • understand various factors affecting the acidity of carboxylic acids and their reactions; • describe the uses of aldehydes, ketones and carboxylic acids
1
6474-6477
10 C H OH 2 5 CH3 – CH2 – CH – CH3 CH – ONa CH3 HBr C H Br 2 5 C H Br 2 5 + CH3 – CH2 – CH – CH3 CH – OC H 2 5 CH3 2-Ethoxy-3-methylpentane Rationalised 2023-24 226 Chemistry 7 11 (ii) 7 12 (i)  3 2 2 3 CH CH CH OH CH Br (ii) (iii) (iv)  3 2 5 3 CH C I C H OH   Rationalised 2023-24 After studying this Unit, you will be •able to write the common and IUPAC names of aldehydes, ketones and carboxylic acids; • write the structures of the compounds containing functional groups namely carbonyl and carboxyl groups; • describe the important methods of preparation and reactions of these classes of compounds; • correlate physical properties and chemical reactions of aldehydes, ketones and carboxylic acids, with their structures; • explain the mechanism of a few selected reactions of aldehydes and ketones; • understand various factors affecting the acidity of carboxylic acids and their reactions; • describe the uses of aldehydes, ketones and carboxylic acids Objectives Carbonyl compounds are of utmost importance to organic chemistry
1
6475-6478
11 (ii) 7 12 (i)  3 2 2 3 CH CH CH OH CH Br (ii) (iii) (iv)  3 2 5 3 CH C I C H OH   Rationalised 2023-24 After studying this Unit, you will be •able to write the common and IUPAC names of aldehydes, ketones and carboxylic acids; • write the structures of the compounds containing functional groups namely carbonyl and carboxyl groups; • describe the important methods of preparation and reactions of these classes of compounds; • correlate physical properties and chemical reactions of aldehydes, ketones and carboxylic acids, with their structures; • explain the mechanism of a few selected reactions of aldehydes and ketones; • understand various factors affecting the acidity of carboxylic acids and their reactions; • describe the uses of aldehydes, ketones and carboxylic acids Objectives Carbonyl compounds are of utmost importance to organic chemistry They are constituents of fabrics, flavourings, plastics and drugs
1
6476-6479
12 (i)  3 2 2 3 CH CH CH OH CH Br (ii) (iii) (iv)  3 2 5 3 CH C I C H OH   Rationalised 2023-24 After studying this Unit, you will be •able to write the common and IUPAC names of aldehydes, ketones and carboxylic acids; • write the structures of the compounds containing functional groups namely carbonyl and carboxyl groups; • describe the important methods of preparation and reactions of these classes of compounds; • correlate physical properties and chemical reactions of aldehydes, ketones and carboxylic acids, with their structures; • explain the mechanism of a few selected reactions of aldehydes and ketones; • understand various factors affecting the acidity of carboxylic acids and their reactions; • describe the uses of aldehydes, ketones and carboxylic acids Objectives Carbonyl compounds are of utmost importance to organic chemistry They are constituents of fabrics, flavourings, plastics and drugs 8 Unit Unit Unit Unit Unit8 Aldehydes Aldehydes Aldehydes Aldehydes Aldehydes,,,,, KKKKKeeeeetones tones tones tones tones and and and and and Carboxylic Carboxylic Carboxylic Carboxylic Carboxylic AAAAAcids cids cids cids cids Aldehydes Aldehydes Aldehydes Aldehydes Aldehydes,,,,, KKKKKeeeeetones tones tones tones tones and and and and and Carboxylic Carboxylic Carboxylic Carboxylic Carboxylic AAAAAcids cids cids cids cids In the previous Unit, you have studied organic compounds with functional groups containing carbon- oxygen single bond
1
6477-6480
Objectives Carbonyl compounds are of utmost importance to organic chemistry They are constituents of fabrics, flavourings, plastics and drugs 8 Unit Unit Unit Unit Unit8 Aldehydes Aldehydes Aldehydes Aldehydes Aldehydes,,,,, KKKKKeeeeetones tones tones tones tones and and and and and Carboxylic Carboxylic Carboxylic Carboxylic Carboxylic AAAAAcids cids cids cids cids Aldehydes Aldehydes Aldehydes Aldehydes Aldehydes,,,,, KKKKKeeeeetones tones tones tones tones and and and and and Carboxylic Carboxylic Carboxylic Carboxylic Carboxylic AAAAAcids cids cids cids cids In the previous Unit, you have studied organic compounds with functional groups containing carbon- oxygen single bond In this Unit, we will study about the organic compounds containing carbon-oxygen double bond (>C=O) called carbonyl group, which is one of the most important functional groups in organic chemistry
1
6478-6481
They are constituents of fabrics, flavourings, plastics and drugs 8 Unit Unit Unit Unit Unit8 Aldehydes Aldehydes Aldehydes Aldehydes Aldehydes,,,,, KKKKKeeeeetones tones tones tones tones and and and and and Carboxylic Carboxylic Carboxylic Carboxylic Carboxylic AAAAAcids cids cids cids cids Aldehydes Aldehydes Aldehydes Aldehydes Aldehydes,,,,, KKKKKeeeeetones tones tones tones tones and and and and and Carboxylic Carboxylic Carboxylic Carboxylic Carboxylic AAAAAcids cids cids cids cids In the previous Unit, you have studied organic compounds with functional groups containing carbon- oxygen single bond In this Unit, we will study about the organic compounds containing carbon-oxygen double bond (>C=O) called carbonyl group, which is one of the most important functional groups in organic chemistry In aldehydes, the carbonyl group is bonded to a carbon and hydrogen while in the ketones, it is bonded to two carbon atoms
1
6479-6482
8 Unit Unit Unit Unit Unit8 Aldehydes Aldehydes Aldehydes Aldehydes Aldehydes,,,,, KKKKKeeeeetones tones tones tones tones and and and and and Carboxylic Carboxylic Carboxylic Carboxylic Carboxylic AAAAAcids cids cids cids cids Aldehydes Aldehydes Aldehydes Aldehydes Aldehydes,,,,, KKKKKeeeeetones tones tones tones tones and and and and and Carboxylic Carboxylic Carboxylic Carboxylic Carboxylic AAAAAcids cids cids cids cids In the previous Unit, you have studied organic compounds with functional groups containing carbon- oxygen single bond In this Unit, we will study about the organic compounds containing carbon-oxygen double bond (>C=O) called carbonyl group, which is one of the most important functional groups in organic chemistry In aldehydes, the carbonyl group is bonded to a carbon and hydrogen while in the ketones, it is bonded to two carbon atoms The carbonyl compounds in which carbon of carbonyl group is bonded to carbon or hydrogen and oxygen of hydroxyl moiety (-OH) are known as carboxylic acids, while in compounds where carbon is attached to carbon or hydrogen and nitrogen of -NH2 moiety or to halogens are called amides and acyl halides respectively
1
6480-6483
In this Unit, we will study about the organic compounds containing carbon-oxygen double bond (>C=O) called carbonyl group, which is one of the most important functional groups in organic chemistry In aldehydes, the carbonyl group is bonded to a carbon and hydrogen while in the ketones, it is bonded to two carbon atoms The carbonyl compounds in which carbon of carbonyl group is bonded to carbon or hydrogen and oxygen of hydroxyl moiety (-OH) are known as carboxylic acids, while in compounds where carbon is attached to carbon or hydrogen and nitrogen of -NH2 moiety or to halogens are called amides and acyl halides respectively Esters and anhydrides are derivatives of carboxylic acids
1
6481-6484
In aldehydes, the carbonyl group is bonded to a carbon and hydrogen while in the ketones, it is bonded to two carbon atoms The carbonyl compounds in which carbon of carbonyl group is bonded to carbon or hydrogen and oxygen of hydroxyl moiety (-OH) are known as carboxylic acids, while in compounds where carbon is attached to carbon or hydrogen and nitrogen of -NH2 moiety or to halogens are called amides and acyl halides respectively Esters and anhydrides are derivatives of carboxylic acids The general formulas of these classes of compounds are given below: Rationalised 2023-24 228 Chemistry Aldehydes, ketones and carboxylic acids are widespread in plants and animal kingdom
1
6482-6485
The carbonyl compounds in which carbon of carbonyl group is bonded to carbon or hydrogen and oxygen of hydroxyl moiety (-OH) are known as carboxylic acids, while in compounds where carbon is attached to carbon or hydrogen and nitrogen of -NH2 moiety or to halogens are called amides and acyl halides respectively Esters and anhydrides are derivatives of carboxylic acids The general formulas of these classes of compounds are given below: Rationalised 2023-24 228 Chemistry Aldehydes, ketones and carboxylic acids are widespread in plants and animal kingdom They play an important role in biochemical processes of life
1
6483-6486
Esters and anhydrides are derivatives of carboxylic acids The general formulas of these classes of compounds are given below: Rationalised 2023-24 228 Chemistry Aldehydes, ketones and carboxylic acids are widespread in plants and animal kingdom They play an important role in biochemical processes of life They add fragrance and flavour to nature, for example, vanillin (from vanilla beans), salicylaldehyde (from meadow sweet) and cinnamaldehyde (from cinnamon) have very pleasant fragrances
1
6484-6487
The general formulas of these classes of compounds are given below: Rationalised 2023-24 228 Chemistry Aldehydes, ketones and carboxylic acids are widespread in plants and animal kingdom They play an important role in biochemical processes of life They add fragrance and flavour to nature, for example, vanillin (from vanilla beans), salicylaldehyde (from meadow sweet) and cinnamaldehyde (from cinnamon) have very pleasant fragrances 8
1
6485-6488
They play an important role in biochemical processes of life They add fragrance and flavour to nature, for example, vanillin (from vanilla beans), salicylaldehyde (from meadow sweet) and cinnamaldehyde (from cinnamon) have very pleasant fragrances 8 1
1
6486-6489
They add fragrance and flavour to nature, for example, vanillin (from vanilla beans), salicylaldehyde (from meadow sweet) and cinnamaldehyde (from cinnamon) have very pleasant fragrances 8 1 1 Nomenclature I
1
6487-6490
8 1 1 Nomenclature I Aldehydes and ketones Aldehydes and ketones are the simplest and most important carbonyl compounds
1
6488-6491
1 1 Nomenclature I Aldehydes and ketones Aldehydes and ketones are the simplest and most important carbonyl compounds There are two systems of nomenclature of aldehydes and ketones
1
6489-6492
1 Nomenclature I Aldehydes and ketones Aldehydes and ketones are the simplest and most important carbonyl compounds There are two systems of nomenclature of aldehydes and ketones (a) Common names Aldehydes and ketones are often called by their common names instead of IUPAC names
1
6490-6493
Aldehydes and ketones Aldehydes and ketones are the simplest and most important carbonyl compounds There are two systems of nomenclature of aldehydes and ketones (a) Common names Aldehydes and ketones are often called by their common names instead of IUPAC names The common names of most aldehydes are derived from the common names of the corresponding carboxylic acids [Section 8
1
6491-6494
There are two systems of nomenclature of aldehydes and ketones (a) Common names Aldehydes and ketones are often called by their common names instead of IUPAC names The common names of most aldehydes are derived from the common names of the corresponding carboxylic acids [Section 8 6
1
6492-6495
(a) Common names Aldehydes and ketones are often called by their common names instead of IUPAC names The common names of most aldehydes are derived from the common names of the corresponding carboxylic acids [Section 8 6 1] by replacing the ending –ic of acid with aldehyde
1
6493-6496
The common names of most aldehydes are derived from the common names of the corresponding carboxylic acids [Section 8 6 1] by replacing the ending –ic of acid with aldehyde At the same time, the names reflect the Latin or Greek term for the original source of the acid or aldehyde
1
6494-6497
6 1] by replacing the ending –ic of acid with aldehyde At the same time, the names reflect the Latin or Greek term for the original source of the acid or aldehyde The location of the substituent in the carbon chain is indicated by Greek letters a, b, g, d, etc
1
6495-6498
1] by replacing the ending –ic of acid with aldehyde At the same time, the names reflect the Latin or Greek term for the original source of the acid or aldehyde The location of the substituent in the carbon chain is indicated by Greek letters a, b, g, d, etc The a-carbon being the one directly linked to the aldehyde group, b- carbon the next, and so on
1
6496-6499
At the same time, the names reflect the Latin or Greek term for the original source of the acid or aldehyde The location of the substituent in the carbon chain is indicated by Greek letters a, b, g, d, etc The a-carbon being the one directly linked to the aldehyde group, b- carbon the next, and so on For example 8
1
6497-6500
The location of the substituent in the carbon chain is indicated by Greek letters a, b, g, d, etc The a-carbon being the one directly linked to the aldehyde group, b- carbon the next, and so on For example 8 1 8
1
6498-6501
The a-carbon being the one directly linked to the aldehyde group, b- carbon the next, and so on For example 8 1 8 1 8
1
6499-6502
For example 8 1 8 1 8 1 8
1
6500-6503
1 8 1 8 1 8 1 8
1
6501-6504
1 8 1 8 1 8 1 Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group They are used in many food products and pharmaceuticals to add flavours
1
6502-6505
1 8 1 8 1 Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group They are used in many food products and pharmaceuticals to add flavours Some of these families are manufactured for use as solvents (i
1
6503-6506
1 8 1 Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group They are used in many food products and pharmaceuticals to add flavours Some of these families are manufactured for use as solvents (i e
1
6504-6507
1 Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group Nomenclature and Structure of Carbonyl Group They are used in many food products and pharmaceuticals to add flavours Some of these families are manufactured for use as solvents (i e , acetone) and for preparing materials like adhesives, paints, resins, perfumes, plastics, fabrics, etc