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| null | NEUTRAL | rus | NOT SPAM | 4 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 0 | 0 | 2 | 0 | 1 | true |
118 | null | Гептоксид марганца (Mn2O7) — масло красного цвета, но становится зеленым при контакте с серной кислотой. | https://t.me/chemistrytg2021/9464?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,100 | 0 | 1,734,524,401 | 1,736,456,937 | 1,129 | 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| [{"ner":"2","lemma":"2","label":"NUM","start_pos":22,"end_pos":23},{"ner":"7","lemma":"7","label":"NUM","start_pos":24,"end_pos":25}] | NEUTRAL | rus | NOT SPAM | 15 | 0 | 0 | 0.947368 | 0.052632 | 0 | 3 | 1 | 0 | 0 | 6 | 0 | 5 | true |
118 | null | Завораживающий эффект
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118 | null | На сайте
журнала «Наносистемы: физика, химия, математика»
опубликован очередной номер (2024, Volume 15, Issue 5, pp. 563-728)
Содержание раздела раздела «Chemistry and material science» со ссылками на статьи:
Proton beam-induced radiosensitizing effect of Ce0.8Gd0.2O2-x nanoparticles against melanoma cells in vitro.
D.D. Kolmanovich, M.V. Romanov, S.A. Khaustov, V.K. Ivanov, A.E. Shemyakov, N.N. Chukavin, A.L. Popov
http://nanojournal.ifmo.ru/en/articles-2/volume15/15-5/chemistry/paper11/
Physicochemical properties and biological activity of novel cerium oxide nanoparticles modified with pyrroloquinoline quinone.
Е.А. Zamyatina, О.A. Goryacheva, N.R. Popova
http://nanojournal.ifmo.ru/en/articles-2/volume15/15-5/chemistry/paper12/
Ceramic materials prepared from nanocrystalline InFeZnO4 powder: optical and mechanical properties, and evaluation of radiation tolerance.
O.N. Kondrat’eva, M.N. Smirnova, G.E. Nikiforova, A.D. Yapryntsev, D.F. Kondakov, L.D. Yagudin
http://nanojournal.ifmo.ru/en/articles-2/volume15/15-5/chemistry/paper13/
Highly dispersed anti-Stokes phosphors based on KGd2F7:Yb,Er single-phase solid solutions.
A.S. Zakharova, S.V. Kuznetsov, A.A. Alexandrov, D.V. Pominova, V.V. Voronov, P.P. Fedorov, V.K. Ivanov
http://nanojournal.ifmo.ru/en/articles-2/volume15/15-5/chemistry/paper14/
Synthesis of CdSTe nanoparticles by laser ablation.
M.A. Jafarov, V.M. Salmanov, R.M. Mamedov, E.F.Nasirov,T.A. Mammadova
http://nanojournal.ifmo.ru/en/articles-2/volume15/15-5/chemistry/paper15/
Ionic channel structure in perfluorinated membranes studied by small angle X-ray scattering, optical and Mössbauer spectroscopy.
V.T. Lebedev, V.S. Kozlov, M.V. Remizov, Yu.V. Kulvelis, O.N. Primachenko, E.A. Marinenko, G.S. Peters
http://nanojournal.ifmo.ru/en/articles-2/volume15/15-5/chemistry/paper16/
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118 | null | Витринная выставка из собрания Архива РАН, посвященная 300-летию РАН
29 ноября на Никитском бульваре в Москве стартовала витринная выставка из собрания Архива РАН, посвященная 300-летию Российской академии наук. Передвижная выставка будет работать весь 2025 г. на всех бульварах Садового кольца Москвы – Гоголевском, Тверском, Сретенском, Рождественском… Открывала выставку заместитель директора по науке Архива РАН, кандидат исторических наук Надежда Михайловна Осипова.
Считается, что науку, а тем более научный поиск, трудно визуализировать. Однако в данном случае, сами персонажи выставки помогли организаторам. Помимо выдающихся достижений в той или иной области знания (о чем кратко рассказано в легенде к каждому плакату), рассказ о каждом из персонажей выставки сопровождается иллюстративным материалом: репродукции схем, зарисовок, чертежей… Уже сами по себе эти документы, показанные, так сказать, в открытом доступе, дорогого стоят.
Среди персонажей выставки есть и два химика: Александр Несмеянов и Александр Толстиков.
Выдающийся химик-органик, президент Академии наук СССР (1951–1961) Александр Николаевич Несмеянов обладал и несомненным художественным даром. Очень атмосферные, тонко исполненные пейзажи открывают малоизвестную сторону таланта Несмеянова.
На выставке представлены и работы нашего коллеги, члена Комиссии РАН по истории химии, академика Российской академии художеств и члена-корреспондента РАН, тоже химика-органика, Александра Генриховича Толстикова. Мастер портретной живописи, Александр Толстиков представил пять репродукций своих работ, в том числе замечательные женские портреты. Кстати, одна из его моделей, Наталия Шушанян, присутствовала на открытии выставки. Можно напомнить, что Александр Толстиков создал целую галерею портретов своих коллег – ученых Российской академии наук, в том числе и химиков. Искусствовед, академик РАХ Марина Вяжевич так оценивает эти работы ученого и художника А.Г. Толстикова: «Он выходит за пределы двухмерного холста, дополненный предметами самих «персонажей холста, погружая зрителя в «поле» каждого из героев». | https://t.me/chemrussia/5090?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,500 | 0 | 1,733,119,395 | 1,736,456,937 | 1,131 | 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118 | null | РНФ подвел итоги конкурса малых отдельных научных групп
Конкурс на получение грантов РНФ по мероприятию «Проведение фундаментальных научных исследований и поисковых научных исследований малыми отдельными научными группами» направлен на поддержку и развитие научных коллективов, занимающих лидирующих позиции в определенных областях наук.
Гранты выделяются на осуществление фундаментальных и поисковых научных исследований в 2025 – 2026 годах. Проекты реализуются коллективами от 2 до 4 человек, размер одного гранта составляет до 1,5 млн. рублей ежегодно.
Поддержку РНФ в рамках конкурса получили
7 проектов
сотрудников ИОНХ РАН:
- Анисимов А.А. «Изучение влияния функционализации Nсалицилиден-4-амино-1,2,4-триазолов и их производных на механизм и структурные аспекты фото- и термохромизма»;
- Воробей А.М. «Влияние числа фаз системы диоксид углеродарастворитель-микронизуемое вещество на размер и морфологию частиц, получаемых методом сверхкритического антисольвентного осаждения»;
- к.х.н. Гоголева Н.В. «Синтез и исследование антикоррозионных свойств фотолюминесцентных координационных соединений цинка(II) и лантанидов(III)»;
- к.х.н. Клюкин И.Н. «Разработка теоретических основ моделирования молекулярных комплексов кластерных анионов бора с аминокислотами, олигопептидами и белками»;
- д.х.н. Козюхин С.А. «Комплексные исследования пигментов методами физико-химического анализа как основа для создания открытой базы данных»;
- д.х.н. Луценко И.А. «Координационные соединения серебра как перспективные антимикробные агенты для преодоления резистентности»;
- к.х.н. Михайлов А.А. «Стабилизация органических и неорганических пероксосольватов в кристаллах и нанокомпозитах для применения в качестве безопасных и эффективных реагентов и функциональных материалов».
Подробная информация о конкурсе и список победителей опубликованы на
сайте РНФ
#конкурс #ионх | https://t.me/chemrussia/5091?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 2,000 | 0 | 1,733,137,310 | 1,736,456,937 | 1,128 | 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118 | null | День в истории химии: Иван Левкоев
Ровно 115 лет назад в селе Епанчино Тамбовской губернии родился
Игорь Иванович Левкоев
(1909-1978), советский химик-органик, член-корреспондент АН СССР, специалист в области фотографической химии. Создал много сенсибилизаторов и десенсибилизаторов, в годы Великой Отечественной занимался созданием материалов для аэрофотосъемки.
#деньвисториихимии
Материал подготовлен ИОНХ РАН для Виртуального музея химии при грантовой поддержке Минобрнауки России в рамках федерального проекта «Популяризация науки и технологий» | https://t.me/chemrussia/5092?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,400 | 0 | 1,733,160,751 | 1,736,456,937 | 1,128 | 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| [{"ner":"Иван Левкоев\nРовно","lemma":"иван левкоев\nровно","label":"PER","start_pos":22,"end_pos":40},{"ner":"Епанчино","lemma":"епанчино","label":"LOC","start_pos":62,"end_pos":70},{"ner":"Тамбовской губернии","lemma":"тамбовский губерния","label":"LOC","start_pos":71,"end_pos":90},{"ner":"Игорь Иванович Левкоев","lemma":"игорь иванович левкоев","label":"PER","start_pos":99,"end_pos":121},{"ner":"АН","lemma":"ан","label":"ORG","start_pos":179,"end_pos":181},{"ner":"СССР","lemma":"ссср","label":"LOC","start_pos":182,"end_pos":186},{"ner":"ИОНХ","lemma":"ионх","label":"ORG","start_pos":404,"end_pos":408},{"ner":"РАН","lemma":"ран","label":"ORG","start_pos":409,"end_pos":412},{"ner":"Виртуального музея химии","lemma":"виртуальный музей химия","label":"ORG","start_pos":417,"end_pos":441},{"ner":"Минобрнауки","lemma":"минобрнауки","label":"ORG","start_pos":466,"end_pos":477},{"ner":"России","lemma":"россия","label":"LOC","start_pos":478,"end_pos":484},{"ner":"09-19","lemma":"09-19","label":"DATE","start_pos":125,"end_pos":130},{"ner":"115","lemma":"115","label":"NUM","start_pos":41,"end_pos":44},{"ner":"1909","lemma":"1909","label":"NUM","start_pos":123,"end_pos":127},{"ner":"1978","lemma":"1978","label":"NUM","start_pos":128,"end_pos":132}] | NEUTRAL | rus | NOT SPAM | 66 | 1 | 4 | 1 | 0 | 0 | 11 | 4 | 0 | 2 | 31 | 2 | 12 | true |
118 | null | Ванадий
В мире микроэлементов есть тот, кто занимает особое место - ванадий. Спрятанный в тени своих более известных коллег, как железо и цинк, ванадий обладает свойствами, которые делают его неотъемлемым участником нашего здоровья.
Ванадий играет ключевую роль в регуляции углеродного и липидного обмена в организме. Ученые отмечают, что ванадий может способствовать предупреждению таких серьезных заболеваний, как диабет, остеопороз и даже рак. Правда, эти данные все еще находятся в стадии исследования, и окончательные выводы пока не сделаны.
Но самое удивительное во всем этом заключается в количестве ванадия в нашем теле. Представьте, что весь ванадий в одном человеке весит всего 100 микрограмм. Это так мало, что если бы мы хотели собрать всего лишь 1 грамм ванадия, нам бы потребовалось 10 000 людей! Вот это да!
Так что, если вы когда-нибудь задумывались, как важны даже самые малые детали нашего тела, вспомните о ванадии. Этот микроэлемент может играть макророль в поддержании нашего здоровья!
💪 | https://t.me/incredible_chemistry/286?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,400 | 0 | 1,685,422,800 | 1,736,456,937 | 1,131 | 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118 | null | #юмор | https://t.me/incredible_chemistry/287?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,300 | 0 | 1,685,509,200 | 1,736,456,937 | 1,131 | 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| null | NEUTRAL | rus | NOT SPAM | 1 | 0 | 0 | 1 | 0 | 0 | 0 | 0 | 0 | 0 | 1 | 0 | 1 | true |
118 | null | #органика
https://telegra.ph/Strashnaya-istoriya-sinteticheskogo-ehstrogena-05-31 | https://t.me/incredible_chemistry/289?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,300 | 0 | 1,685,595,600 | 1,736,456,937 | 1,130 | 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| [{"ner":"05-31","lemma":"05-31","label":"DATE","start_pos":76,"end_pos":81},{"ner":"31","lemma":"31","label":"NUM","start_pos":79,"end_pos":81}] | NEUTRAL | eng | NOT SPAM | 2 | 0 | 0 | 0.75 | 0.25 | 0 | 0 | 0 | 0 | 0 | 1 | 0 | 1 | true |
118 | null | Американское химическое общество опубликовало результаты исследования коктейля «Кровавая Мэри», который состоит из водки, томатного сока, сельдерея, соли, перца и соуса табаско, а также усложненной композиции с вустерским соусом, хреном и лимоном.
Анализ был затруднен обилием веществ, входящих в состав коктейля. Для упрощения исследования все компоненты были сразу разделены на летучие и нелетучие, а также на устойчивые и быстро разрушающиеся.
Определяющими вкус напитка веществами - пигмент ликопин из томатного сока, аллилизоцианат из хрена, соединения растительного происхождения из лимона и спирт из водки.
Было установлено, что вскоре после приготовления коктейля в смеси происходят разнообразные химические реакции между входящими в его состав веществами, в частности, разложение вкусовых добавок. При этом часть важных компонентов просто улетучивается.
Пить «Кровавую Мэри» следует сразу после приготовления, подавать со льдом, поскольку снижение температуры замедляет скорость нежелательных реакций. | https://t.me/incredible_chemistry/290?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 3,100 | 0 | 1,685,689,201 | 1,736,456,937 | 1,128 | 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| [{"ner":"Американское химическое общество","lemma":"американский химический общество","label":"ORG","start_pos":0,"end_pos":32}] | NEUTRAL | rus | NOT SPAM | 129 | 2 | 0 | 1 | 0 | 0 | 17 | 15 | 2 | 0 | 51 | 6 | 28 | true |
118 | null | Хотел бы показать вам замечательный конспект моей ученицы!
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Рассматривали метаболизм арахидоновой кислоты и кислотно-щелочное равновесие
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Как вам?
😇 | https://t.me/simplebestbiochemistry/451?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,100 | 0 | 1,728,022,736 | 1,736,456,937 | 1,131 | 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| null | NEUTRAL | rus | NOT SPAM | 20 | 0 | 0 | 1 | 0 | 0 | 5 | 3 | 2 | 0 | 5 | 0 | 5 | true |
118 | null | Немного классики) | https://t.me/simplebestbiochemistry/452?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,700 | 0 | 1,728,207,434 | 1,736,456,937 | 1,131 | 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| null | NEUTRAL | rus | NOT SPAM | 2 | 0 | 0 | 1 | 0 | 0 | 0 | 0 | 0 | 0 | 1 | 1 | 1 | true |
118 | null | КРОВЬ. Белки плазмы
Друзья, мы продолжаем с вами цикл уроков по белкам и сегодня начинаем говорить о белках плазмы крови!
❗️
Напоминаю, что у нас был
бесплатный вебинар
по биохимии соединительной ткани и белка коллагена. Если вы не успели на регистрацию или у вас нет записи, напишите моему ассистенту
@ysavnin
, мы вышлем вам лекцию!
👨⚕️
Итак, давайте вспомним, что кровь - полноценная ткань, которая относится к соединительной! Почему?
А потому что полностью соответствует формуле:
клетки + межклеточное вещество.
Клетки - наши форменные элементы: лейкоциты, эритроциты, тромбоциты.
А межклеточное вещество или плазма - это вода с растворенными в ней белками и многообразием прочих органических и неорганических веществ.
🤷♂️
Как вы понимаете белков крови чрезвычайно много. Они отличаются по функциям, размерам, свойствам и так далее. Но мы можем разделить их на три группы:
1️⃣
Альбумины;
2️⃣
Глобулины;
3️⃣
Фибриноген и протромбин;
❗️
Когда мы лабораторно измеряем общий белок плазмы крови, то получаем как раз суммарное количество всех этих белков. Но ответить каких больше или меньше мы можем только измеряя конкретные белки и их фракции.
😊
Но об этом поговорим в следующих постах, а также будем подробно разбирать на большом курсе по обмену белков и аминокислот! | https://t.me/simplebestbiochemistry/453?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,600 | 0 | 1,728,286,651 | 1,736,456,937 | 1,131 | 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| [{"ner":"1","lemma":"1","label":"NUM","start_pos":880,"end_pos":881},{"ner":"2","lemma":"2","label":"NUM","start_pos":895,"end_pos":896},{"ner":"3","lemma":"3","label":"NUM","start_pos":910,"end_pos":911}] | NEUTRAL | rus | NOT SPAM | 194 | 0 | 3 | 0.996154 | 0.003846 | 0 | 20 | 24 | 16 | 1 | 58 | 16 | 42 | true |
118 | null | АЛЬБУМИНЫ. Строение
Как мы вчера с вами узнали,
альбумины
- ключевые белки плазмы крови, которые составляют до 55% от массы всех белков сыворотки.
Альбумины по своему строению имеют только белковую часть и не имеют никаких небелковых компонентов. Их молекулярная масса довольно велика - около 69 кДа (килодальтон).
🧳
Например, масса инсулина 6кДа, а гемоглобина 64 кДа.
Очень важной особенностью строения белка альбумина является наличие большого количества аминокислоты глутамата в своем составе.
Глутамат, за счет наличия двух карбоксильных групп -COOH в своем составе, придает альбумину
кислые свойства, высокий отрицательный заряд и гидрофильность.
Благодаря этому альбумины очень хорошо растворяются в воде и обладают способностью притягивать другие молекулы.
❗️
А это формирует их ключевые функции!
А вот о функциях и биологической роли мы поговорим в следующем уроке.
А пока задаю вам вопросы, знаете ли вы какие функции выполняет белок альбумин в сыворотке крови?
😉 | https://t.me/simplebestbiochemistry/454?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,700 | 0 | 1,728,367,674 | 1,736,456,937 | 1,131 | 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| [{"ner":"АЛЬБУМИНЫ","lemma":"альбумины","label":"ORG","start_pos":0,"end_pos":9},{"ner":"Глутамат","lemma":"глутамат","label":"PER","start_pos":498,"end_pos":506},{"ner":"55","lemma":"55","label":"NUM","start_pos":111,"end_pos":113},{"ner":"69","lemma":"69","label":"NUM","start_pos":293,"end_pos":295},{"ner":"6","lemma":"6","label":"NUM","start_pos":342,"end_pos":343},{"ner":"64","lemma":"64","label":"NUM","start_pos":362,"end_pos":364}] | NEUTRAL | rus | NOT SPAM | 141 | 0 | 5 | 0.994413 | 0.005587 | 0 | 16 | 14 | 8 | 5 | 51 | 7 | 24 | true |
118 | null | Что происходит с алкоголем в организме?
🍸
Какие химические превращения происходят со спиртом при попадании в организм человека? Почему наступает похмелье? И какими лекарствами лечат алкоголизм?
👩🏻🔬
Думаю, формула
этанола
вам хорошо знакома —
CH₃CH₂OH
. При попадании алкоголя в организм, спирт окисляется сразу тремя ферментами. Самое активное действие в этом процессе принимает
алкогольдегидрогеназа
. Попробуйте хоть разок прочитать это длинное название
😉
В дальнейшем будем использовать сокращение
АЛДГ
.
В результате действия ключевого фермента
спирт превращается в уксусный альдегид
. Его формулу
CH₃CHO
можно представить, как этиловый спирт, от которой отщепилась одна молекула воды. Именно уксусный альдегид становится
причиной похмелья и всех токсических эффектов
.
К счастью, альдегид является промежуточным продуктом расщепления, и дальше за дело берётся другой фермент –
ацетальдегидрогеназа (АДГ)
. Если с первого взгляда вам показалось, что это длинное название не отличается от упомянутого выше, то прочитайте их еще раз и вы заметите разницу.
АДГ превращает уксусный альдегид в относительно безопасную
уксусную кислоту CH₃COOH
, которая в дальнейшем на клеточном уровне
окисляется до углекислого газа CO₂ и воды H₂O и выводится из организма
.
При
избытке
алкоголя в крови ферменты не справляются с полным превращением альдегида в уксусную кислоту, в результате он
накапливается
в организме. Причем альдегид в десятки раз в 10—30 токсичнее самого этилового спирта. Когда к утру организм не успевает расправиться с ацетальдегидом, наступает похмелье
🥴
А теперь представьте себе такое вещество, которое будет
блокировать действие АДГ
. Фермент
перестанет выполнять свою функцию по обезвреживанию вредного альдегида
— его концентрация в организме выпившего человека вырастает в несколько раз, чем обычно при такой же дозе алкоголя. При этом гарантированно начнется рвота, головокружение и острая головная боль — все самые неприятные симптомы похмелья
🤮
Таким веществом является
дисульфирам
, который используют при
медикаментозном лечении алкоголизма
. Пациенту, принимающему дисульфирам, под контролем врача дают выпить небольшое количество спиртного. Так как ферменты окисления этанола
заблокированы
, в организме накапливается ацетальдегид и
возникает острая интоксикация
, которая сопровождается
неприятными, болезненными ощущениями
🤢
В результате формируется условно-рефлекторная реакция отвращения к вкусу и запаху этанола.
Помимо лечения алкогольной зависимости, исследуется эффективность дисульфирама и его производных в качестве
противоопухолевых препаратов
💊
В ряде исследований обнаружено, что в сочетании с некоторыми металлами дисульфирам ускоряет естественный процесс смерти клеток,
приостанавливая рост опухоли и метастаз
.
Теперь вы имеете представление о том, какой путь проделывает алкоголь после попадания в организм.
Лучше получайте удовольствие от живого общения без лишних бокалов с напитками
🥂 | https://t.me/ychemistry/961?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,900 | 0 | 1,721,298,963 | 1,736,456,937 | 1,132 | 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| [{"ner":"АЛДГ","lemma":"алдг","label":"ORG","start_pos":502,"end_pos":506},{"ner":"CH₃CHO","lemma":"ch₃cho","label":"ORG","start_pos":603,"end_pos":609},{"ner":"АДГ","lemma":"адг","label":"ORG","start_pos":905,"end_pos":908},{"ner":"CH₃COOH","lemma":"ch₃cooh","label":"ORG","start_pos":1135,"end_pos":1142},{"ner":"АДГ","lemma":"адг","label":"ORG","start_pos":1643,"end_pos":1646},{"ner":"10—30","lemma":"10—30","label":"DATE","start_pos":1439,"end_pos":1444},{"ner":"₃","lemma":"₃","label":"NUM","start_pos":245,"end_pos":246},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":248,"end_pos":249},{"ner":"₃","lemma":"₃","label":"NUM","start_pos":605,"end_pos":606},{"ner":"₃","lemma":"₃","label":"NUM","start_pos":1137,"end_pos":1138},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":1219,"end_pos":1220},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":1229,"end_pos":1230},{"ner":"30","lemma":"30","label":"NUM","start_pos":1442,"end_pos":1444}] | NEUTRAL | rus | NOT SPAM | 397 | 0 | 16 | 0.99 | 0.01 | 0 | 47 | 53 | 16 | 3 | 138 | 14 | 59 | true |
118 | null |
Из
чего делают пигменты?
Об
одном из двух основных компонентов
, входящих в состав красок, мы уже поговорили в предыдущем посте. Настало время окунуться в яркую палитру цветов. Только начнём с
ахроматических
, то есть чёрного, белого и всех оттенков серого между ними и, как всегда, с
точки зрения химии
👩🏻🔬
Думаю, вы с легкостью догадаетесь, из чего состоит
черный пигмент
🔳
Да, это одна из модификаций углерода —
сажа
. Она образуется в ходе
неполного сгорания
или
термического разложения
углеводородов и представляет собой
чистый углерод C
🔥
Почему неполного?
Если горение будет протекать в
избытке кислорода O₂
, то, как мы знаем, углеводороды сгорают с образованием
углекислого газа CO₂ и воды H₂O
. Но если процесс горения поддерживать при
недостатке кислорода
, то образуется ядовитый угарный газ CO и сажа С, которую осаждают из
коптящего пламени
на специальных охлаждаемых поверхностях. Например, много сажи образуется при сжигании
бензола
, который горит характерным коптящим пламенем
⚗️
Выбор пигмента
белого цвета
уже шире
🔲
. Вы наверняка слышали об одном из древнейших белых пигментов —
свинцовых белилах
(основный карбонат свинца
2PbCO₃·Pb(OH)₂
). Сейчас этот пигмент
запрещен
для использования в малярных работах из-за его
высокой токсичности
, но несколько веков назад люди не знали об опасности соединений свинца и добавляли его даже в косметику
☠️
. С помощью свинцовых белил дамы из высшего света добивались ровного и белоснежного цвета лица, нанося при этом
непоправимый вред коже и своему здоровью
.
Существенным недостатком свинцовых белил также было
взаимодействие с сероводородом H₂S
, содержащимся в небольших количествах в воздухе. При реакции свинца с серой образуется очень прочное соединение
черного цвета
—
сульфид свинца PbS
. В ходе необратимого процесса белый цвет на картинах постепенно темнел.
На смену свинцовым белилам пришли
цинковые белила
—
оксид цинка ZnO
. Благодаря своему
противовоспалительному
действию он вам может быть известен как основной компонент
цинковой мази
, которая как раз имеет белоснежный цвет.
В современных эмалях используют
титановые белила
—
диоксид титана TiO₂
, — которые по многим свойствам обыгрывают цинковые. Титановые белила обладают более сильной
кроющей
способностью и
не меняют
своего цвета со временем и при нагревании.
Но между цинковыми и титановыми белилами есть отличия помимо кроющей способности, существенные в работе художника
👩🏻🎨
Цинковые обладают
более холодным
слегка голубоватым оттенком, а титановые наоборот —
более теплым
и желтоватым. Поэтому в профессиональных наборах масляных красок так и сохранились эти два «оттенка» белого
🤷🏻♀️
Диоксид титана
не является
токсичным соединением и используется в качестве зарегистрированной
пищевой добавки E171
. В качестве
абразивного вещества
его добавляют, например, в зубную пасту
🦷
Оттенки серого
, очевидно, получают смешением белого и черного. Но известны и пигменты серого цвета, приготовленные из
металлического порошка
или графита. Например,
измельченный цинк или алюминий
.
О пигментах
хроматических
цветов, то есть оттенков цветового круга (красный, желтый, синий и др.) поговорим в следующий раз
🎨
Оставайтесь на связи
😉 | https://t.me/ychemistry/962?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,100 | 0 | 1,721,639,188 | 1,736,456,937 | 1,131 | 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| [{"ner":"PbS","lemma":"pbs","label":"ORG","start_pos":1757,"end_pos":1760},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":616,"end_pos":617},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":693,"end_pos":694},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":703,"end_pos":704},{"ner":"2","lemma":"2","label":"NUM","start_pos":1149,"end_pos":1150},{"ner":"₃","lemma":"₃","label":"NUM","start_pos":1154,"end_pos":1155},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":1162,"end_pos":1163},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":1610,"end_pos":1611},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":2128,"end_pos":2129},{"ner":"171","lemma":"171","label":"NUM","start_pos":2741,"end_pos":2744}] | NEUTRAL | rus | NOT SPAM | 470 | 0 | 13 | 0.982428 | 0.017572 | 0 | 78 | 55 | 20 | 10 | 135 | 24 | 82 | true |
118 | null | Жирные кислоты. Зачем они нужны?
🐟
Если вы интересуетесь
здоровым питанием
и периодически заглядываете на
iHerb
в поисках витаминов и БАДов, то наверняка натыкались на такую биодобавку, как
омега-3
. Даже если эта тема раньше обходила вас стороной,
это не значит, что знать о ней необязательно
. Потому что жирные кислоты непосредственно
входят в рацион каждого человека
.
А вот для чего они нужны и в каком виде, мы сейчас разберёмся
👩🏻🔬
Как можно понять из названия,
жирные кислоты поступают в наш организм вместе с жирами из пищи
🍳
Они же после ряда биохимических преобразований входят
в состав всех липидных клеточных мембран и выполняют важные функции
. От того, какие жирные кислоты и в каком количестве мы получаем из пищи, напрямую зависит
наше здоровье
: от состояния кожи и сердечно-сосудистой системы до развития плода во время беременности
❤️
С точки зрения
химического строения
, жирные кислоты представляют
длинную углеродную цепочку
🧬
Начинается она с
карбоксильной группы -COOH
, отвечающей за кислотные свойства, от которой тянется зигзагообразный хвост, заканчивающийся
метильным фрагментом -CH₃
. Число групп в хвосте варьируется от 4 до 24. Когда
три
таких огромных молекулы объединяются в одну с помощью простого
глицерина
, мы получаем полноценную
молекулу жира
💦
Начало
углеродной цепочки принято обозначать первой буквой греческого алфавита
α «альфа»
, а ее
конец — ω «омега»
. Если жирные кислоты содержать
только одинарные
простые связи, то такие кислоты называются
насыщенными
.
Они не так полезны для нашего организма, но поговорить о них можно в другой раз
.
Если в углеродной цепочки есть
двойные связи
, то такие жирные кислоты называются
не
насыщенными, и к ним как раз относятся
омега-3,-6,-9
. Цифра в названии говорит о том,
где находится двойная связь
. Например, в омега-6 двойная связь расположена на
6 атоме углерода
, если начинать отсчёт от омега-конца. Положение двойных связей очень важно, потому что от этого зависят свойства
👁
Пожалуй, с сухой теорией мы разобрались. Теперь к более жизненным моментам
Омега-3
относится к
незаменимым
жирным кислотам, то есть наш организм самостоятельно
не может
их вырабатывать —
они должны поступать с пищей
. Основным источником в рационе является морская рыба: рыбий жир, сельдь, лосось, печень трески, красная и черная икра
🐟
Омега-6
также относится к
незаменимым
жирным кислотам, однако мы можем получить
достаточное
её количество из рациона. Омега-6 содержится в растительных маслах, семенах, некоторых овощах и мясе
🥩
Омега-9 не являются незаменимыми
, в отличие от омега-3 и омега-6. Иными словами, наш организм не испытывает дефицита омега-9, так как в нужных количествах
сам способен синтезировать её
из других жирных кислот
🍗
Большинство людей получают из рациона в 15-25 раз больше омега-6, чем омега-3, и это плохо отражается на здоровье
. В лабораторных испытаниях
доказано
, что достаточное количество омега-3 обладает
противовоспалительным
действием, улучшает состояние
кожи
, уменьшает риск заболеваний
сердца
, эффективно при
депрессивных состояниях
и очень важно для нормального
роста детей
👩🏻⚕️
Будем честны
, большинство из нас не ест жирную рыбу необходимые два раза в неделю, поэтому
омега-3 не поступает в нужном количестве вместе с пищей
. А отсюда все последствия
дефицита
, которые вы можете подчеркнуть из абзаца выше
🤔
Хорошо, что в настоящее время существует большой выбор одноименных
биодобавок
, которые способны поддерживать уровень
омега-3
, но перед их применением нужно
обязательно проконсультироваться со специалистом
💊
Поэтому важно обращать внимание на то, что мы едим
🥑 | https://t.me/ychemistry/963?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,100 | 0 | 1,721,713,989 | 1,736,456,937 | 1,128 | 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118 | null | То чувство, когда натрия в воде слишком много. | https://t.me/chemistrytg2021/9458?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,100 | 0 | 1,734,427,200 | 1,736,456,938 | 1,136 | 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| null | NEUTRAL | rus | NOT SPAM | 8 | 0 | 0 | 1 | 0 | 0 | 0 | 0 | 0 | 0 | 3 | 2 | 2 | true |
118 | null | Мини эксперимент со спичками. | https://t.me/chemistrytg2021/9459?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,200 | 0 | 1,734,438,001 | 1,736,456,938 | 1,136 | 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118 | null | Мыльные пузыри наполненные метаном. | https://t.me/chemistrytg2021/9460?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,734,448,800 | 1,736,456,938 | 1,131 | 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| null | NEUTRAL | rus | NOT SPAM | 4 | 0 | 0 | 1 | 0 | 0 | 1 | 1 | 0 | 0 | 2 | 0 | 1 | true |
118 | null | Химический быт в видеозарисовках. Ретроспектива. Растим кристаллы
С начала работы нашего музея мы публиковали цикл авторских видео о «химической рутине» в нашем музее. Но количество подписчиков за это время увеличилось - как во ВКонтакте, так и в Телеграме.
Поэтому мы во-первых,
выложили
все 28 (пока что 28) видео на сайте музея. А во-вторых делаем ретроспективу наших предыдущих выпусков.
Итак, слово сотруднику ИОНХ РАН Дмитрию Ямбулатову.
Давайте покажу за минуту, как мы в лаборатории
выращиваем кристаллы.
Школьники работают в основном в стаканчиках с концентрированными растворами.
Я же часто использую метод выращивания кристаллов из перегретых растворителей. Но для этого нужны очки, защитные стекла и так далее.
#бытхимика
#видео
Материал подготовлен ИОНХ РАН для Виртуального музея химии при грантовой поддержке Минобрнауки России в рамках федерального проекта «Популяризация науки и технологий» | https://t.me/chemrussia/5083?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,400 | 0 | 1,733,032,917 | 1,736,456,938 | 1,136 | 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118 | null | Недавно опубликованная статья в The Journal of Physical Chemistry Letters исследует динамику обмена воды в пористом кремнеземе с применением методов ЯМР-релаксации. Исследователи впервые использует модель обменно-ориентированной рандомизации (EMOR), которая позволяет количественно оценить влияние обменных процессов между молекулами воды и поверхностью кремнезема на ЯМР релаксацию. В работе варьируется время обмена для молекул H2O и D2O, при помощи добавления фосфата натрия, что позволяет детально изучить, как эти обменные процессы влияют на релаксационные характеристики ЯМР, важные для более точного моделирования взаимодействий воды на поверхностях.
https://doi.org/10.1021/acs.jpclett.4c02590 | https://t.me/chemrussia/5084?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,400 | 0 | 1,733,119,101 | 1,736,456,938 | 1,131 | 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118 | null | Царская водка: как растворить золото
Пытаясь получить золото, алхимики поставили задачу сделать универсальный растворитель. Итальянский алхимик Джованни Фиданца приготовил раствор нашатыря (хлорида аммония, NH4Cl) в азотной кислоте которую тогда называли крепкой водкой. В этой смеси растворилось золото, которое считалось царем металлов, за что она и получила название царской водки. Сегодня же царской водкой называется смесь концентрированных азотной и соляной кислот в пропорции 1:3 по объему.
Если этот пост наберет 200 или больше реакций, мы запишем видео растворения золота в царской водке.
😊 | https://t.me/incredible_chemistry/283?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,500 | 0 | 1,685,077,204 | 1,736,456,938 | 1,136 | 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| [{"ner":"Джованни Фиданца","lemma":"джованни фиданца","label":"PER","start_pos":144,"end_pos":160},{"ner":"4","lemma":"4","label":"NUM","start_pos":209,"end_pos":210},{"ner":"1","lemma":"1","label":"NUM","start_pos":484,"end_pos":485},{"ner":"3","lemma":"3","label":"NUM","start_pos":486,"end_pos":487},{"ner":"200","lemma":"200","label":"NUM","start_pos":522,"end_pos":525}] | NEUTRAL | rus | NOT SPAM | 82 | 0 | 1 | 0.989899 | 0.010101 | 0 | 11 | 13 | 5 | 3 | 28 | 3 | 14 | true |
118 | null | С Днем химика!
Поздравляем героев химической промышленности за их профессионализм, работу в сложных условиях и стремление к прогрессу. Ваше значение непомерно, благодарим вас.
Приветствуем ученых и преподавателей химии. Ваши открытия, исследования и желание делиться знаниями важны для общества. Желаем вам новых научных открытий и воспитания талантливых учеников.
Специальное поздравление для студентов-химиков. Вперед к познанию секретов этой великолепной науки. Преодолевайте препятствия, сохраняйте любопытство и решимость.
И, конечно, поздравления для всех любителей химии. Ваша любовь к науке вдохновляет.
С Днем химика, друзья! Пусть ваша жизнь будет полна открытий и экспериментов! | https://t.me/incredible_chemistry/284?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,600 | 0 | 1,685,253,605 | 1,736,456,938 | 1,139 | 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| null | POSITIVE | rus | NOT SPAM | 88 | 0 | 3 | 1 | 0 | 0 | 9 | 8 | 2 | 0 | 41 | 2 | 20 | true |
118 | null | #неорганика
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| [{"ner":"05-28","lemma":"05-28","label":"DATE","start_pos":52,"end_pos":57},{"ner":"28","lemma":"28","label":"NUM","start_pos":55,"end_pos":57}] | NEUTRAL | eng | NOT SPAM | 2 | 0 | 0 | 0.75 | 0.25 | 0 | 0 | 0 | 0 | 0 | 1 | 0 | 1 | true |
118 | null | Коллеги, всех благодарю за внимание! Всем будет выслана запись лекции!
Буду рад обратной связи, кто присутствовал в онлайне!
❤️ | https://t.me/simplebestbiochemistry/444?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,900 | 0 | 1,727,521,098 | 1,736,456,938 | 1,140 | 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| null | NEUTRAL | rus | NOT SPAM | 19 | 0 | 0 | 1 | 0 | 0 | 2 | 3 | 2 | 0 | 6 | 0 | 7 | true |
118 | null | КОЛЛАГЕНАЗА. Биологическая роль
Друзья, вчера мы выслали всем зарегистрированным участникам запись вебинара на почту. Сегодня продолжим высылать тем, кто просил запись, но не был зарегистрирован.
❗️
Если вы вдруг не получили запись лекции, можете продублировать информацию моему ассистенту
@ysavnin
👨⚕️
А я сегодня хотел бы рассказать вам о роли фермента, который, наоборот, принимает участие в разрушении коллагена - это фермент
коллагеназа
.
Тканевая коллагеназа или, по-другому, «матричная металлопротеиназа - 1» (ММП - 1) - сложный фермент, имеющий в своем каталитическом центре 3 иона Ca 2+ и 2 иона Zn 2+ и оказывающий физиологическую функцию гидролиза коллагена с целью его естественного самообновления.
Поскольку для работы этого фермента нужны металлы, поэтому и фермент называется металлопротеиназой!
Важнейшим метаболитом коллагена является -
гидроксипролин
- специфическая аминокислота, которая, как мы с вами говорили на вебинаре, характерна именно для структуры коллагена. Повышение этой аминокислоты является маркером избыточного распада, например, при развитии коллагенозов или фиброза.
😇
Ее кстати можно посмотреть в сыворотке крови!
🦠
А еще коллагеназу имеют некоторые патогенные бактерии, например, Clostridia perfringers - возбудитель газовой гангрены, которая расплавляет ткани с помощью этого фермента. | https://t.me/simplebestbiochemistry/445?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,800 | 0 | 1,727,762,238 | 1,736,456,938 | 1,137 | 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| [{"ner":"КОЛЛАГЕНАЗА","lemma":"коллагеназа","label":"ORG","start_pos":0,"end_pos":11},{"ner":"1","lemma":"1","label":"NUM","start_pos":514,"end_pos":515},{"ner":"1","lemma":"1","label":"NUM","start_pos":524,"end_pos":525},{"ner":"3","lemma":"3","label":"NUM","start_pos":584,"end_pos":585},{"ner":"2","lemma":"2","label":"NUM","start_pos":594,"end_pos":595},{"ner":"2","lemma":"2","label":"NUM","start_pos":599,"end_pos":600},{"ner":"2","lemma":"2","label":"NUM","start_pos":609,"end_pos":610}] | NEUTRAL | rus | NOT SPAM | 178 | 0 | 4 | 0.978723 | 0.021277 | 0 | 15 | 22 | 11 | 6 | 57 | 14 | 38 | true |
118 | null | ДИАГНОЗ ПО КАРТИНКЕ
Друзья, в медицинских каналах и чатах любят предлагать студентам и врачам поставить диагноз по клинической картине.
😊
А я вам предлагаю попробовать предположить! вероятный диагноз по художественной картине великого Рембранта «Вирсавия с письмом царя Давида».
😉
Сразу дам дам небольшую подсказку. Эта патология встречается только у женщин и на фото есть более менее четкий патогномоничный признак.
Жду в комментариях ваших предположений
⤵️ | https://t.me/simplebestbiochemistry/446?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,900 | 0 | 1,727,849,173 | 1,736,456,938 | 1,136 | 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| [{"ner":"Давида","lemma":"давид","label":"PER","start_pos":270,"end_pos":276}] | NEUTRAL | rus | NOT SPAM | 65 | 0 | 4 | 1 | 0 | 0 | 8 | 11 | 2 | 0 | 20 | 3 | 9 | true |
118 | null | Правильный ответ
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На самом деле никто до конца не знает точного диагноза, но многие из вас дали предположительно правильный ответ!
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Ключевой патогномоничный признак -
опухолевидное образование
в области левой подмышечной впадины. Трактуется это в первую очередь, как аденокарцинома левой молочной железы с вовлечением подмышечных лимфатических узлов. Простым языком - рак.
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Однако, если углубиться в историю, то Хендрикье Стоффлес, героиня, предположительно изображенная на холсте, прожила еще 9 лет, что не совсем согласуется с диагнозом рака МЖ.
В одной современной медицинской статье выдвигается гипотеза о том, что опухолевидное образование у натурщицы - следствие острого тромбофлебита поверхностной вены молочной железы.
Однако некоторые исследователи говорят о том, что хоть голова здесь действительно Хендрикье Стоффлес, близкой подруги Рембрандта, но вот само туловище принадлежит другой неизвестной героине, которая могла иметь аденокарциному МЖ.
👨⚕️
Также я согласен с теми, кто визуально отметил наличие эстрогендоминирования и характерного абдоминального ожирения.
Вот так искусство заставляет нас думать и мыслить клинически
😉 | https://t.me/simplebestbiochemistry/447?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,000 | 0 | 1,727,936,493 | 1,736,456,938 | 1,131 | 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| [{"ner":"Хендрикье Стоффлес","lemma":"хендрикье стоффлес","label":"PER","start_pos":417,"end_pos":435},{"ner":"Хендрикье Стоффлес","lemma":"хендрикье стоффлес","label":"PER","start_pos":814,"end_pos":832},{"ner":"Рембрандта","lemma":"рембрандт","label":"PER","start_pos":850,"end_pos":860},{"ner":"9","lemma":"9","label":"NUM","start_pos":499,"end_pos":500}] | NEUTRAL | rus | NOT SPAM | 154 | 0 | 3 | 1 | 0 | 0 | 30 | 17 | 10 | 2 | 42 | 12 | 25 | true |
118 | null | Веселящий газ. Как работает наркоз?
😷
В настоящее время почти невозможно представить даже незначительное хирургическое вмешательство без применения
анестезии
. Она необходима
не только
для того, чтобы
пациент не чувствовал боли
, но и
чтобы убрать напряжение мышц и других тканей
, мешающее работе хирурга. Только мало кто знает, что применение современных анестезирующих препаратов
начиналось с открытия самых простых химических веществ
👩🏻🔬
Каким образом анестезия блокирует боль?
Если совсем просто, то сами по себе болевые ощущения
формируются в головном или спинном мозге
в ответ на
болевые импульсы
, идущие от специальных рецепторов по всему телу
🧠
Анестезия блокирует нервные окончания
, нарушая цепочку специальных биохимических реакций, — из-за этого болевой импульс не доходит до центральной нервной системы.
Местная анестезия
нарушает передачу импульса в определенном участке, а
общая
(именно её называют
наркозом
) полностью угнетает ЦНС, убирая болевую чувствительность по всему телу.
Одним из самых популярных веществ для ингаляционного наркоза является
оксид азота (I) N₂O (закись азота)
. Вскоре после его открытия на рубеже 17-18 веков было обнаружено, что вдыхание небольших количеств закиси азота сопровождается эффектом
опьянения, эйфории и появлением приступов смеха
. За эту особенность закиси азота дали еще одно название —
веселящий газ
.
Смекалистые умельцы уже на том этапе исторического развития нашли открытому газу альтернативное применение, вдыхая его на светских вечеринках.
Впрочем, мало что изменилось.
Воздушные шары с веселящим газом по-прежнему продают в клубах и на вечеринках. Но я настаиваю на том, чтобы вы не злоупотребляли закисью азота без медицинской необходимости
🤔
В
высоких концентрациях
оксид азота применяется в медицине для обеспечения хирургического наркоза во время мелких и крупных операций.
Другим популярным летучим веществом для ингаляционной анестезии является
диэтиловый эфир
. Вещество с простой химической формулой получило широкое распространение в анестезиологии благодаря
сильному эффекту и безопасности применения
. Выдающийся отечественный хирург
Н.И.Пирогов
первым в истории медицины начал оперировать в полевых условиях раненых с использованием диэтилового эфира в качестве обезболивающего.
В современной медицине используются различные комбинации анестезирующих веществ для достижения эффективного и безопасного наркоза. Помимо веществ
ингаляционного типа
, то есть тех, что вводятся через дыхательные пути (+ к упомянутым выше:
хлороформ, фторотан, изофлуран
), распространены
инъекционные вещества
— кетамин, производные барбитуровой кислоты и др.
🧪
Выбор
типа анестезии и препаратов
осуществляется
анестезиологом
на основе предварительных исследований. Именно он контролирует как состояние организма во время операции, так и режим подачи анестезирующих веществ.
Поэтому ни одно оперативное вмешательство не может обойтись без врача-анестезиолога
😉 | https://t.me/ychemistry/957?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,300 | 0 | 1,721,041,264 | 1,736,456,938 | 1,136 | 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| [{"ner":"ЦНС","lemma":"цнс","label":"ORG","start_pos":947,"end_pos":950},{"ner":"17-18","lemma":"17-18","label":"DATE","start_pos":1142,"end_pos":1147},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":1086,"end_pos":1087},{"ner":"18","lemma":"18","label":"NUM","start_pos":1145,"end_pos":1147}] | NEUTRAL | rus | NOT SPAM | 394 | 0 | 6 | 0.996032 | 0.003968 | 0 | 63 | 53 | 12 | 6 | 133 | 16 | 58 | true |
118 | null | 🍅
Томатный сок и бром
В состав сока входит соединение под названием ликопин, который делает томаты красными.
В ходе реакции с бромом все его одиннадцать двойных связей последовательно бромируются, из-за чего происходит многократное изменение цвета. В результате мы можем увидеть целую палитру красок по всей высоте цилиндра. | https://t.me/ychemistry/958?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,200 | 0 | 1,721,126,113 | 1,736,456,938 | 1,136 | 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| null | NEUTRAL | rus | NOT SPAM | 47 | 0 | 3 | 1 | 0 | 0 | 5 | 6 | 3 | 1 | 20 | 1 | 5 | true |
118 | null | Бром при нормальных условиях является тяжёлой едкой жидкостью красно-бурого цвета с сильным неприятным «тяжёлым» запахом, отдалённо напоминающим запах одновременно иода и хлора. Летуч, ядовит. | https://t.me/chemistrytg2021/9452?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,734,340,801 | 1,736,456,939 | 1,142 | 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| null | NEUTRAL | rus | NOT SPAM | 24 | 0 | 0 | 1 | 0 | 0 | 10 | 2 | 0 | 0 | 7 | 2 | 6 | true |
118 | null | Эксперимент "балансирование".
Если в алюминиевой банке оставить жидкости примерно треть, то банку можно сбалансировать под углом в 45 градусов.
#интереснаяфизика | https://t.me/chemistrytg2021/9453?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,734,351,600 | 1,736,456,939 | 1,139 | 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| [{"ner":"45","lemma":"45","label":"NUM","start_pos":131,"end_pos":133}] | NEUTRAL | rus | NOT SPAM | 20 | 0 | 0 | 1 | 0 | 0 | 1 | 2 | 0 | 1 | 9 | 2 | 6 | true |
118 | null | Процесс пайки печатной платы. | https://t.me/chemistrytg2021/9454?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,100 | 0 | 1,734,362,400 | 1,736,456,939 | 1,139 | 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| null | NEUTRAL | rus | NOT SPAM | 4 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 0 | 0 | 3 | 0 | 1 | true |
118 | null | Голограмма
Голограммы - это виртуальные трехмерные изображения, создаваемые интерференцией световых лучей, отражающих реальные физические объекты. Голограммы сохраняют глубину, параллакс и другие свойства исходного объекта.
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| null | NEUTRAL | rus | NOT SPAM | 25 | 0 | 0 | 1 | 0 | 0 | 7 | 3 | 0 | 0 | 10 | 0 | 7 | true |
118 | null | Супероксид калия и порошок фосфора вступают в реакцию при добавлении воды! | https://t.me/chemistrytg2021/9456?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,100 | 0 | 1,734,416,400 | 1,736,456,939 | 1,139 | 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| null | NEUTRAL | rus | NOT SPAM | 11 | 0 | 0 | 1 | 0 | 0 | 0 | 1 | 0 | 0 | 7 | 0 | 1 | true |
118 | null | На
Reddit
всплыла история про по-настоящему мощный
retract
Похоже, автор статьи не просто её написал, но еще и сам
отрецензировал.
Как он это сделал
❓
Да очень просто, в контактную информацию для рецензентов вписал уважаемых людей, правда с
фейковыми email
👏
Спекулятивно можно предположить, что такие адреса почты были связаны именно с кем-то из авторов работы.
Схема конечно любопытная
🧐
Из плюсов:
можно относительно легко опубликовать статью
😏
Из минусов:
нужно писать рецензию на самого себя и потом с собой же и переписываться
💊
Кстати, у ученого уже отозвали десяток статей после всего этого. Репутация, видимо, дала трещину...
🙁
https://doi.org/10.1016/j.scitotenv.2022.154046 | https://t.me/chemrussia/5078?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,300 | 0 | 1,732,946,425 | 1,736,456,939 | 1,139 | 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| [{"ner":"Reddit","lemma":"reddit","label":"ORG","start_pos":3,"end_pos":9},{"ner":"10.10","lemma":"10.10","label":"DATE","start_pos":653,"end_pos":658},{"ner":"22.15","lemma":"22.15","label":"DATE","start_pos":675,"end_pos":680},{"ner":"1016","lemma":"1016","label":"NUM","start_pos":656,"end_pos":660},{"ner":"2022","lemma":"2022","label":"NUM","start_pos":673,"end_pos":677},{"ner":"154046","lemma":"154046","label":"NUM","start_pos":678,"end_pos":684}] | NEUTRAL | rus | NOT SPAM | 100 | 0 | 0 | 0.971429 | 0.028571 | 0 | 9 | 12 | 9 | 0 | 20 | 16 | 14 | true |
118 | null | Журнал Nature сообщает, что доверие общества к ученым, проявляющим скромность в своей научной деятельности, значительно выше. Скромность повышает уровень доверия к ученому и результатам его исследований, способствует намерению следовать его рекомендациям и опираться на представленную им информацию.
https://www.nature.com/articles/d41586-024-03858-5
https://www.nature.com/articles/s41562-024-02060-x
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118 | null | Согласны с Ландау
👍
, не согласны
👎
, какая разница люблю и физику
❤️ | https://t.me/incredible_chemistry/279?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,400 | 0 | 1,684,731,604 | 1,736,456,939 | 1,139 | 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| [{"ner":"Ландау","lemma":"ландау","label":"PER","start_pos":11,"end_pos":17}] | NEUTRAL | rus | NOT SPAM | 15 | 0 | 0 | 1 | 0 | 0 | 2 | 1 | 0 | 0 | 2 | 0 | 6 | true |
118 | null | Черная смородина, кошачья моча и виноделие
«Пахнет кошачьей мочей» - это выражение часто используют для описания запаха черной смородины, некоторых разновидностей белого совиньона и белых вин региона Сансер, а также некоторых фруктовых нот красного вина. Речь идет о летучих серосодержащих органических соединениях (тиолах). В вине они образуются благодаря спиртовой ферментации. Зато в натуральном виде молекулы триолов присутствуют в грейпфруте и тропических фруктах с цветочными нотами, таких как маракуйя. В слабых дозах тиолы придают блюдам и напиткам фруктовые или цветочные ноты, но при сильной концентрации по запаху напоминают кошачью мочу. (Рафаэль Омон "Вкусы химика") | https://t.me/incredible_chemistry/280?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,500 | 0 | 1,684,818,003 | 1,736,456,939 | 1,142 | 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| [{"ner":"Сансер","lemma":"сансер","label":"LOC","start_pos":200,"end_pos":206},{"ner":"Рафаэль Омон","lemma":"рафаэль омон","label":"PER","start_pos":651,"end_pos":663}] | NEUTRAL | rus | NOT SPAM | 93 | 2 | 2 | 1 | 0 | 0 | 19 | 8 | 1 | 0 | 36 | 2 | 19 | true |
118 | null | #органика #лекарство
https://telegra.ph/Streptocid-istoriya-pervogo-antibiotika-05-23 | https://t.me/incredible_chemistry/281?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,400 | 0 | 1,684,904,404 | 1,736,456,939 | 1,139 | 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| [{"ner":"05-23","lemma":"05-23","label":"DATE","start_pos":80,"end_pos":85},{"ner":"23","lemma":"23","label":"NUM","start_pos":83,"end_pos":85}] | NEUTRAL | other | NOT SPAM | 3 | 0 | 0 | 0.833333 | 0.166667 | 0 | 0 | 0 | 0 | 0 | 2 | 0 | 2 | true |
118 | null | #видео Иы хотели повторить один известный опыт, но что-то пошло не так
😜 | https://t.me/incredible_chemistry/282?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,300 | 0 | 1,684,990,804 | 1,736,456,939 | 1,139 | 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| [{"ner":"Иы","lemma":"иы","label":"PER","start_pos":7,"end_pos":9}] | NEUTRAL | rus | NOT SPAM | 13 | 0 | 0 | 1 | 0 | 0 | 1 | 3 | 3 | 1 | 2 | 1 | 2 | true |
118 | null | ПОЛНОЦЕННЫЙ БЕЛОК.
Критерии качества
Друзья, напоминаю, что у нас активно идет регистрация на бесплатный вебинар по биохимии белка коллагена и соединительной ткани. Вся информация в шапке профиля
⤴️
Те, кто принимал участие в лекции по перевариванию белков, наверняка знают ответ на этот вопрос о понятии полноценного белка, но давай осветим его еще раз.
🔥
Кстати, данная лекция доступна в
магазине знаний.
По всем вопросам пишите моему ассистенту
@ysavnin
Итак, мы с вами регулярно употребляем белок в пищу. Яйца, говядина, свинина, рыба, молочка, растительные продукты, все эти продукты, без сомнений, содержат белки. Однако по своей биологической ценности и аминокислотному составу они далеко не одинаковы.
Поэтому биохимиками было введено понятие -
полноценного и неполноценного белка
.
Полноценный белок это тот, который наиболее полно удовлетворяет критериям качества:
1️⃣
Соотношение заменимых и незаменимых аминокислот – в белке должно быть не менее 32% незаменимых аминокислот;
2️⃣
Близость аминокислотного состава белка к аминокислотному составу усредненного белка тела человека;
3️⃣
Легкость переваривания в ЖКТ;
Отсюда у меня к вам два вопроса:
❓
Как вы думаете, белок какого продукта наиболее полноценный?
❓
Будет ли белок коллаген считаться полноценным белком, если мы будем активно употреблять его в пищу?
Жду ваши предположения, а в следующем посте я раскрою ответы на данные вопросы!
😉 | https://t.me/simplebestbiochemistry/439?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,000 | 0 | 1,727,156,411 | 1,736,456,939 | 1,140 | 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| [{"ner":"БЕЛОК","lemma":"белок","label":"ORG","start_pos":12,"end_pos":17},{"ner":"1","lemma":"1","label":"NUM","start_pos":876,"end_pos":877},{"ner":"32","lemma":"32","label":"NUM","start_pos":959,"end_pos":961},{"ner":"2","lemma":"2","label":"NUM","start_pos":988,"end_pos":989},{"ner":"3","lemma":"3","label":"NUM","start_pos":1091,"end_pos":1092}] | NEUTRAL | rus | NOT SPAM | 203 | 0 | 3 | 0.996241 | 0.003759 | 0 | 22 | 19 | 14 | 3 | 70 | 15 | 38 | true |
118 | null | ЯИЧНЫЙ БЕЛОК - самый полноценный
Напоминаю, что уже через два дня мы проводим с вами бесплатный вебинар по теме
биохимии белка коллагена и соединительной ткани
. Успевайте
присоединиться!
❤️
Друзья, очень рад читать ваши ответы и комментарии к предыдущему посту, многие из вас дали правильные ответы на мои вопросы!
Давайте, в целом, скажем о том, что белки животного происхождения более полноценные, поскольку их аминокислотный состав ближе к составу усредненного белка человека, чем у растительного протеина.
🥚
А вот лидером является, как раз, яичный белок! Яичный белок состоит из нескольких представителей, но в наибольшем количестве содержится - ОВАЛЬБУМИН или яичный альбумин, составляя более 50% от всего яичного белка. Кстати, именно он вызывает аллергическую реакцию.
А что насчёт коллагена?
❗️
Как многие правильно сказали, коллаген, действительно, неполноценный.
Во-первых, у него скудный аминокислотный состав, представленный преимущественно глицином, пролином и лизином. Кстати про строение мы будем подробно говорить на вебинаре.
А во-вторых, в его структуре содержаться много дисульфидных связей, поэтому он дольше и сложнее гидролизуется (распадается до свободных аминокислот).
Поэтому кушать яичницу однозначно полезнее, чем хрящи и косточки
😅 | https://t.me/simplebestbiochemistry/440?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,200 | 0 | 1,727,330,022 | 1,736,456,939 | 1,140 | 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| [{"ner":"Напоминаю","lemma":"напоминать","label":"PER","start_pos":33,"end_pos":42},{"ner":"50","lemma":"50","label":"NUM","start_pos":699,"end_pos":701}] | NEUTRAL | rus | NOT SPAM | 175 | 0 | 6 | 1 | 0 | 0 | 28 | 21 | 8 | 3 | 48 | 23 | 39 | true |
118 | null | Отличная демонстрация прочного фундамента любого специалиста, работающего со здоровьем!
А уже завтра мы затронем
гистологию
- поговорим о соединительной ткани, ее строении и роли, а также
биохимию
белка коллагена - ключевого компонента соединительной ткани!
А еще вы узнаете пример специализированной соединительной ткани, лишенной коллагена. Знаете такую?
😉
Уверен, будет интересно и полезно!
😇
Регистрация в закрепленном сообщении
⤴️ | https://t.me/simplebestbiochemistry/441?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,200 | 0 | 1,727,413,483 | 1,736,456,939 | 1,140 | 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| [{"ner":"⤴️","lemma":"⤴️","label":"ORG","start_pos":433,"end_pos":435}] | NEUTRAL | rus | NOT SPAM | 58 | 0 | 2 | 1 | 0 | 0 | 13 | 6 | 2 | 0 | 18 | 4 | 10 | true |
118 | null | Коллеги, через 1.5 часа мы начинаем онлайн лекцию!
❗️
Напоминаю, что всем будет выслана запись вебинара!
Если еще не успели зарегистрироваться, вся информация в закрепленном сообщении
⤴️ | https://t.me/simplebestbiochemistry/442?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,000 | 0 | 1,727,508,400 | 1,736,456,939 | 1,140 | 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118 | null | Мыльный раствор
Любила я в детстве пускать мыльные пузыри. Если честно, то и сейчас при виде бутылочки с пузырями не сдерживаю себя и пускаю их. Они же такие классные! Поэтому я очень рада, что могу поделиться с вами интересными химическими фактами о мыльном растворе.
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Пузыри не лопаются благодаря трехслойной структуре стенки. Гидрофильные концы молекул мыла обращены к воде внутрь пленки. А гидрофобные - к воздуху по обе стороны стенок. Такое строение задерживает испарение, позволяет пузырю растягиваться и "прожить" дольше.
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Если знать основы коллоидной химии (она занимается пленками), то можно сделать пузыри более прочными. Для этого необходимо увеличить вязкость воды и использовать сильные поверхностно-активные вещества.
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Все мы в детстве использовали стандартный рецепт для мыльных пузырей шампунь и вода в соотношении 1:1. Но есть и более мощный рецепт, который сделает пузыри ещё прочнее: 80 мл дистиллированной воды; 20 мл средства для мытья посуды; 15 мл глицерина; 5 г сахарного песка. Кстати, если добавить в смесь 2 грамма желатина, то получатся огромные супер пузыри, которые часто пускают на различных представлениях. Желатин нужно расплавить и смешать с подогретой водой. Когда смесь станет однородной, добавлять остальные компоненты. Смешивать интенсивно, но не взбалтывать!
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Если наполнить мыльные пузыри водородом (сильная кислота с цинком), они будут взлетать в небо. А еще они взрываются (аккуратно!).
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Не все знают, что мыльный пузырь можно взять в руки... в варежках. Волокна шерсти работают как пружинки, не позволяя сфере деформироваться и лопнуть.
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Еще опыт. В мороз -15 и ниже надуть мыльный пузырь на улице. Обещаю, будет классно.
Надеюсь, эти интересные факты помогут вам создать идеальный мыльный раствор для супер пузырей! | https://t.me/ychemistry/953?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,100 | 0 | 1,720,526,550 | 1,736,456,939 | 1,139 | 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| [{"ner":"1","lemma":"1","label":"NUM","start_pos":835,"end_pos":836},{"ner":"1","lemma":"1","label":"NUM","start_pos":837,"end_pos":838},{"ner":"80","lemma":"80","label":"NUM","start_pos":907,"end_pos":909},{"ner":"20","lemma":"20","label":"NUM","start_pos":936,"end_pos":938},{"ner":"15","lemma":"15","label":"NUM","start_pos":969,"end_pos":971},{"ner":"5","lemma":"5","label":"NUM","start_pos":986,"end_pos":987},{"ner":"2","lemma":"2","label":"NUM","start_pos":1037,"end_pos":1038},{"ner":"15","lemma":"15","label":"NUM","start_pos":1607,"end_pos":1609}] | NEUTRAL | rus | NOT SPAM | 263 | 0 | 3 | 1 | 0 | 0 | 37 | 43 | 15 | 7 | 75 | 18 | 54 | true |
118 | null | Сульфаты и косметика
Впервые о вреде SLS заговорили несколько лет назад. Споры об этом веществе продолжаются и сегодня. Поэтому я решила рассказать вам подробнее о SLS и разобрать все мифы об этом веществе.
SLS (sodium lauryl sulfate, лаурилсульфат натрия), SLES (sodium laureth sulfate, лаурет сульфат натрия) – это поверхностно-активные вещества, которые используют в производстве пенно-моющей продукции.
ПАВы выполняют роль очищающих реагентов, они расщепляют жиры и удаляют загрязнения. Чем мягче ПАВ, тем щадяще он очищает поверхность. SLES - более мягкий, чем SLS.
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Почему же тогда их боятся?
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Вызывают рак, заболевания кожи, проникают в почки и мозг
Миф. Научно доказано, что к этому SLS и SLES не причастны.
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Канцерогены
Нет, SLS и SLES – хорошие, а вот их производство сопровождается побочными канцерогенными продуктами. Однако производители обязаны тщательно очищать сульфаты.
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SLS, SLES вызывают раздражения кожи
Да, такое бывает, особенно если у вас чувствительная кожа. Хотя тесты были странные: руку человека погружали на час в высококонцентрированный раствор SLS. Возникало раздражение. А теперь давайте подумаем, долго ли гель для душа или шампунь находится на коже? Нет.
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SLS, SLES сушат кожу
Да, несмотря на небольшие концентрации, может возникать сухость. Поэтому нужно пользоваться бальзамами для волос, кремами для тела, если вас это беспокоит.
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SLS есть в средствах для машин!
Да, и что? Поваренную соль, например, насыпают на улице от снега/гололеда, она разъедает обувь, металлы, раздражает кожу и вообще от нескольких столовых ложек соли можно умереть. Но мы же почему-то не отказываемся от нее? Потому что все дело в мере и концентрациях.
Вокруг SLS столько шума, однако это вещество уже изучено вдоль и поперек. Смущать вас должно другое: «А какое вещество будет в товаре взамен SLS и насколько оно будет изучено?» | https://t.me/ychemistry/954?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,300 | 0 | 1,720,596,622 | 1,736,456,939 | 1,141 | 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| [{"ner":"SLS","lemma":"sls","label":"ORG","start_pos":37,"end_pos":40},{"ner":"лаурилсульфат","lemma":"лаурилсульфат","label":"LOC","start_pos":236,"end_pos":249},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":408,"end_pos":411},{"ner":"Миф","lemma":"миф","label":"PER","start_pos":662,"end_pos":665},{"ner":"SLS","lemma":"sls","label":"ORG","start_pos":696,"end_pos":699},{"ner":"SLS","lemma":"sls","label":"ORG","start_pos":740,"end_pos":743}] | NEUTRAL | rus | NOT SPAM | 279 | 0 | 21 | 0.935829 | 0.064171 | 0 | 22 | 39 | 17 | 2 | 73 | 30 | 68 | true |
118 | null | Как пахнет море?
Море напоминает мне о моем ничтожестве и о ничтожестве всего рода людского
Каждый отвечает на этот вопрос по разному. Для кого-то море пахнет летом, свободой, отпуском или банально йодом. Химики не самые романтичные люди на свете, поэтому их ответ не так поэтичен, как вышеописанные, зато правдив.
Оказывается море
🌊
пахнет летучими органическими соединениями серы, а также отходами водорослей и бактерий
🤢
. Как-то не очень романтично выходит, правда? А мы то всегда говорили, что море - это запах свежести, соли и чего-то морского. А оно вон как оказалось.
Основным газом
💨
который летает возле моря является сероводород. Да да тот самый, который пахнет тухлыми яйцами. Он между прочим в больших концентрациях может быть токсичным и опасным для человека
😱
. Но не пугайтесь, возле моря витает допустимая норма данного газа. Наш организм способен разрушить данные молекулы.
После сероводородного газа следует диметилсульфид с запахом капусты. Это второй аромат, который мы чувствуем у моря. Он образуется при разрушении диметилсульфониопропионата (DMSP) в клетках водорослей.
Вышеописанные соединения обладают не самым приятным ароматом по отдельности. Но из-за смешивания с друг-другом и не сильной концентрации аромат выходит приятный
😊
. Да что там лукавить, для некоторых это самый прекрасный запах на земле. Лично я обожаю
😍
запах моря
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и никогда ни с чем его не перепутаю. Могу вдыхать его хоть 360 дней в году.
Также в зависимости от контекста запах может чувствоваться нами по разному, эдакое плацебо – когда мы в отпуске рядом с морем, то нам приятно и хорошо. В эти дни мы наслаждаемся жизнью, отдыхаем и не чувствуем сероводород. А даже если и чувствуем, то для нас он кажется свежим, приятным запахом. | https://t.me/ychemistry/955?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,400 | 0 | 1,720,768,098 | 1,736,456,939 | 1,139 | 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| [{"ner":"360","lemma":"360","label":"NUM","start_pos":1420,"end_pos":1423}] | NEUTRAL | rus | NOT SPAM | 272 | 0 | 5 | 0.997093 | 0.002907 | 0 | 34 | 35 | 29 | 1 | 73 | 17 | 47 | true |
118 | null | Как защитить себя от солнца?
🌞
С приходом солнечных дней у многих возникает вопрос —
как правильно защитить кожу от УФ-излучения?
Давайте выясним,
какие бывают солнцезащитные средства, по какому принципу они работают и что такое SPF?
Озоновый слой, конечно, защищает нас от
самого опасного
спектра солнечного излучения, но до поверхности Земли доходят два типа УФ-лучей: малая часть
UVB-
и практически полностью
UVA-лучи.
Под воздействием первых наша кожа краснеет и даже может получить солнечный ожог, а вторые проникают в кожу глубже, ускоряя процесс
старения и разрушая её изнутри
💥
Существует два типа солнцезащитных фильтров, используемых в косметике:
физический и химический.
В кремах на основе
физических фильтров
частицы минералов действуют
как зеркало
на поверхности кожи, отражая UVB- и UVA-лучи. Самые распространённые физические фильтры это диоксид титана
TiO₂
(
Titanium Dioxide
) и оксид цинка
ZnO
(
Zinc Oxide
). Средства на их основе редко вызывают раздражение и подходят для чувствительной и детской кожи. Но к сожалению, они часто оставляют
белый налёт
после нанесения
👻
В средствах на основе
химических фильтров
специальные вещества проникают в поверхностный слой кожи и
преобразуют
солнечное излучение в безопасную тепловую энергию. В составе эти компоненты вы сможете встретить под названиями авобензон (
avobenzone
), мексорил (
ecamsule/mexoryl SX
), тиносорб (
tinosorb
), оксибензон (
oxybenzone
) и другие.
Такие фильтры отлично работают даже в небольшой концентрации,
равномерно
распределяются по коже и не оставляют следов. Но их недостатками являются возможные
аллергические реакции
и недостаточная эффективность против всего спектра УФ-излучения
🌤
Поэтому для максимальной защиты от солнца лучше использовать средства, в которых
сочетаются
физические и химические фильтры — именно такие сейчас встречаются всё чаще и чаще
👍🏻
А теперь о том, что такое SPF?
Фактор защиты от солнца —
SPF
— рассчитывается на основании того, сколько времени мы можем провести на солнце, когда наша кожа
защищена кремом,
до первых признаков загара (покраснения) по сравнению
с кожей без крема.
Если санскрин имеет SPF 30, то кожа покраснеет
в 30 раз медленнее,
чем если бы на ней вообще не было средства
👙
Важно отметить, что SPF разных средств
не складываются,
а считаются по высшему. Например, если вы нанесли сначала SPF 50, а потом SPF 30, то фактор защиты так и останется на отметке 50.
Но большой SPF нам в
большинстве случаев и не нужен.
Средство с SPF 30 уже блокирует
97%
солнечного излучения. Но ни один крем
не защищает на 100%.
Так что разница между SPF 15, SPF 30 и SPF 50 в целом не такая уж большая
☀️
Главная ошибка, которую допускают при использовании солнцезащитных средств, — это
недостаточное количество
наносимого крема. Рекомендуемая плотность покрытия — 2 мг средства на см² кожи (около
половины чайной ложки на лицо
). И не забывайте обязательно смывать его в конце дня
🙌🏻
А если вам кажется, что защита от солнца — это бесполезное занятие, то уточню, что помимо фотостарения УФ-излучение значительно повышает риск развития
меланомы и других злокачественных образований на коже
👁
Наслаждайтесь солнечными днями без риска для здоровья
😌 | https://t.me/ychemistry/956?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,100 | 0 | 1,720,962,702 | 1,736,456,939 | 1,141 | 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| NEUTRAL | rus | NOT SPAM | 487 | 0 | 28 | 0.956989 | 0.043011 | 0 | 53 | 55 | 18 | 18 | 132 | 27 | 82 | true |
118 | null | Химия в природе
Биолюминесцентные грибы.
Механизм свечения ученые изучили еще не у всех светящихся грибов, но почти у всех случаев он довольно прост. В грибах содержится так называемый пигмент люциферина. Именно он при взаимодействии с кислородом окисляется и испускает зеленоватый свет. Это очень необычно! | https://t.me/chemistrytg2021/9448?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,400 | 0 | 1,734,265,200 | 1,736,456,940 | 1,136 | 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| null | NEUTRAL | rus | NOT SPAM | 44 | 0 | 1 | 1 | 0 | 0 | 4 | 6 | 3 | 0 | 14 | 5 | 6 | true |
118 | null | «Химические часы» или реакция Бриггса - Раушера. | https://t.me/chemistrytg2021/9449?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,100 | 0 | 1,734,276,000 | 1,736,456,940 | 1,133 | 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118 | null | Аллюминий реагирует с гидроксидом натрия(NaOH) и водой с образованием газообразного водорода. | https://t.me/chemistrytg2021/9450?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,300 | 0 | 1,734,286,800 | 1,736,456,940 | 1,133 | 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| null | NEUTRAL | rus | NOT SPAM | 11 | 0 | 0 | 1 | 0 | 0 | 1 | 1 | 0 | 0 | 4 | 0 | 2 | true |
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118 | null | Ученые Санкт‑Петербургского государственного университета синтезировали первые соединения платины, которые под действием зеленого света катализируют реакции получения полезных мономеров. Эти комплексы могут помочь в разработке экологически чистого синтеза важных полимеров и лекарств.
https://spbu.ru/news-events/novosti/khimiki-spbgu-pervymi-sozdali-soedineniya-platiny-dlya-sinteza-polimerov-i
https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.202403264
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118 | null | Друзья, подписчики, химики! Опыт с Дзеном закончен. Больше никакого Дзена, так как платформа не очень хорошая, вернее плохая, точнее отвратительная. Извините за долгое молчание, канал возрождается. | https://t.me/incredible_chemistry/274?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,600 | 0 | 1,684,158,096 | 1,736,456,940 | 1,136 | 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| [{"ner":"Дзеном","lemma":"дзен","label":"PER","start_pos":36,"end_pos":42},{"ner":"Дзена","lemma":"дзен","label":"PER","start_pos":69,"end_pos":74}] | NEGATIVE | rus | NOT SPAM | 26 | 0 | 0 | 1 | 0 | 0 | 4 | 3 | 0 | 1 | 7 | 4 | 10 | true |
118 | null | Еще одна хорошая новость! Наш чат-бот
@ChemWikiBot
снова в строю. Воспользоваться вы можете после перехода в чат этого канала. Там нужно найти бот
@ChemtWikiBot
и ввести /start. Да, не забывайте, что у нас есть чат канала, где мы обсуждаем все на свете, кроме политики) Вступайте в группу) | https://t.me/incredible_chemistry/275?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,600 | 0 | 1,684,213,590 | 1,736,456,940 | 1,136 | 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| [{"ner":"Вступайте","lemma":"вступать","label":"LOC","start_pos":271,"end_pos":280}] | NEUTRAL | rus | NOT SPAM | 47 | 0 | 0 | 0.953125 | 0.046875 | 0 | 2 | 8 | 4 | 1 | 14 | 4 | 11 | true |
118 | null | #органика #парфюм
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118 | null | Всем работникам лабораторий посвящается! | https://t.me/incredible_chemistry/277?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 4,400 | 0 | 1,684,389,608 | 1,736,456,940 | 1,133 | 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| null | NEUTRAL | rus | NOT SPAM | 4 | 0 | 0 | 1 | 0 | 0 | 0 | 1 | 0 | 0 | 2 | 0 | 1 | true |
118 | null | #органика #взрывчатка
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| [{"ner":"05-18","lemma":"05-18","label":"DATE","start_pos":50,"end_pos":55},{"ner":"18","lemma":"18","label":"NUM","start_pos":53,"end_pos":55}] | NEUTRAL | other | NOT SPAM | 3 | 0 | 0 | 0.833333 | 0.166667 | 0 | 0 | 0 | 0 | 0 | 2 | 0 | 2 | true |
118 | null | #классика
Напомню, что синтез и сборка любого белка идет по строгому порядку! От первичной структуры, и далее постепенно формируя уникальную пространственную конфигурацию!
Очередной пример «наглядной биохимии»
😇 | https://t.me/simplebestbiochemistry/434?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,000 | 0 | 1,726,813,285 | 1,736,456,940 | 1,137 | 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| null | NEUTRAL | rus | NOT SPAM | 27 | 0 | 0 | 1 | 0 | 0 | 6 | 2 | 0 | 0 | 9 | 2 | 7 | true |
118 | null | КОЛЛАГЕН. Ключевые аминокислоты
❗️
Друзья, есть идея провести бесплатный
вебинар
по теме соединительной ткани и белка коллагена.
Рассказать, в целом, о месте соединительной ткани в нашем организме, роли коллагена, биохимических механизмах его синтеза. Совершенно бесплатный, для всех желающих. Напишите в комментарии
⤵️
, если вам интересна эта тема!
А сегодня хотел бы кратко рассказать о том, какие аминокислоты входят в состав коллагена.
🧪
Итак, молекула белка коллагена состоит из повторяющихся трипептидов - фрагмент из трех аминокислот.
На первом месте всегда стоит аминокислота глицин. А вот на втором и третьем месте могут располагаться разные аминокислоты. Поэтому часто трипептид коллагена кодируют следующим образом:
Гли - X - Y
На месте X чаще всего располагается пролин, а на месте Y пролин, лизин или аланин.
👨⚕️
Другие аминокислоты тоже могут встречаться в этих положениях, но сравнительно реже.
❗️
Таким образом, ключевыми аминокислотами являются: глицин, пролин, лизин и аланин.
Далее с пролином и лизином будут происходить модификации, но об этом мы поговорим уже в следующих уроках.
А также буду рад рассказать вам об этом на бесплатном вебинаре! | https://t.me/simplebestbiochemistry/435?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,900 | 0 | 1,726,987,586 | 1,736,456,940 | 1,137 | 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| [{"ner":"Гли - X - Y","lemma":"гли - x - y","label":"PER","start_pos":728,"end_pos":739}] | NEUTRAL | rus | NOT SPAM | 172 | 0 | 8 | 0.982379 | 0.017621 | 0 | 18 | 21 | 7 | 1 | 60 | 13 | 36 | true |
118 | null | БЕСПЛАТНЫЙ ВЕБИНАР по биохимии белка коллагена и соединительной ткани
Друзья, очень рад, что биохимия вызывает активный живой интерес, поэтому с радостью объявляю о том, что мы с вами проведем бесплатную лекцию, где обсудим:
1️⃣
Этапы и механизмы синтеза белка коллагена;
2️⃣
Роль коферментов и витамина С;
3️⃣
Ассоциированные патологические состояния;
4️⃣
Эффективность экзогенного приема коллагена;
5️⃣
Роль соединительной ткани в работе организма;
Ключевая информация:
📅
28 сентября, 12:00 мск
🖥️
Online лекция + запись каждому участнику
🛜
На площадке Zoom
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⤵️
Обязательно корректно заполняйте номер телефона и электронную почту, чтобы вам пришла запись вебинара!
https://biochimia.timepad.ru/event/3049645/ | https://t.me/simplebestbiochemistry/437?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,200 | 0 | 1,727,068,749 | 1,736,456,940 | 1,133 | 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| [{"ner":"ВЕБИНАР","lemma":"вебинар","label":"ORG","start_pos":11,"end_pos":18},{"ner":"Zoom","lemma":"zoom","label":"ORG","start_pos":555,"end_pos":559},{"ner":"28 сентября","lemma":"28 сентября","label":"DATE","start_pos":474,"end_pos":485},{"ner":"30496","lemma":"30496","label":"DATE","start_pos":723,"end_pos":728},{"ner":"12:00","lemma":"12:00","label":"DATE","start_pos":487,"end_pos":492},{"ner":"1","lemma":"1","label":"NUM","start_pos":225,"end_pos":226},{"ner":"2","lemma":"2","label":"NUM","start_pos":272,"end_pos":273},{"ner":"3","lemma":"3","label":"NUM","start_pos":307,"end_pos":308},{"ner":"4","lemma":"4","label":"NUM","start_pos":353,"end_pos":354},{"ner":"5","lemma":"5","label":"NUM","start_pos":401,"end_pos":402},{"ner":"00","lemma":"00","label":"NUM","start_pos":490,"end_pos":492}] | NEUTRAL | rus | SPAM | 98 | 0 | 3 | 0.977941 | 0.022059 | 0 | 15 | 6 | 4 | 3 | 40 | 5 | 18 | true |
118 | null | Пюре или фри?
СМИ давно говорят о том, что в зеленой картошке содержатся яды, но так ли это на самом деле? Сегодня расскажу вам всё, что знаю про зеленый картофель.
Любой зародыш будущего растения
🌱
может находиться в трех состояниях.
"
Спящем
", во время которого все биохимические процессы спят и зародыш ожидает нужные условия.
"
Самопереваривающим
". Он включается при наступлении теплой и влажной погоды, которая благотворно влияет на запуск процесса развития. В этом состоянии рост происходит за счёт питательных веществ самого клубня/семени.
"
Аутотрофном
", бесплатная энергия от солнца. В этом случае в кожуре и ростках клубня активно синтезируется хлорофилл, преобразующий солнечный свет во внутриклеточную энергию. Этот режим, очень важен для любого растения.
🥔
Зеленый картофель относится к семейству пасленовых, как и помидоры. В нем находится токсичный гликоалкалоид - соланин. Но боятся не стоит, поскольку он находится только в кожуре. А также он разрушается при варке или засолке.
Активный синтез соланина начинается в зеленеющих клубнях, поэтому такую кожуру следует срезать особенно тщательно, чтобы ядовитое вещество не попало в ваш организм. Некоторые и вовсе выбрасывают зеленую картошку, но это делать не обязательно.
Летальная доза (LD50) соланина для млекопитающих примерно 0,1 г на кг веса. По расчетам это означает, что взрослому человеку опасно съесть больше 1,5 кг (!) сырой зеленой картофельной кожуры или ростков.
Не думаю, что на практике кому-нибудь придёт в голову есть сырую картошку, кожуру или ростки. Поэтому не нужно боятся зеленый картофель, при правильном его приготовлении он абсолютно безвреден. | https://t.me/ychemistry/947?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,000 | 0 | 1,720,106,490 | 1,736,456,940 | 1,136 | 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| [{"ner":"СМИ","lemma":"сми","label":"ORG","start_pos":14,"end_pos":17},{"ner":"Спящем","lemma":"спящем","label":"ORG","start_pos":237,"end_pos":243},{"ner":"Аутотрофном","lemma":"аутотрофном","label":"ORG","start_pos":551,"end_pos":562},{"ner":"50","lemma":"50","label":"NUM","start_pos":1259,"end_pos":1261},{"ner":"0","lemma":"0","label":"NUM","start_pos":1299,"end_pos":1300},{"ner":"1","lemma":"1","label":"NUM","start_pos":1301,"end_pos":1302},{"ner":"1","lemma":"1","label":"NUM","start_pos":1387,"end_pos":1388},{"ner":"5","lemma":"5","label":"NUM","start_pos":1389,"end_pos":1390}] | NEUTRAL | rus | NOT SPAM | 242 | 0 | 6 | 0.996732 | 0.003268 | 0 | 32 | 33 | 17 | 3 | 66 | 17 | 50 | true |
118 | null | Как работает холодильник?
☃️
Невозможно представить современную жизнь без холодильных установок. Только попробуйте сосчитать,
сколько раз в день вы открываете дверцу холодильника
.
Число вас удивит
. А как приятно зайти
в помещение с кондиционером
после палящего летнего солнца
🌇
Все эти блага основаны на
фундаментальных физико-химических законах и свойствах особых веществ
.
Давайте поговорим о том, по какому принципу работают холодильники
.
Начнём с процессов, которые протекают внутри
компрессионного холодильника
— наиболее распространенного в быту охлаждающего устройства. В нём главным переносчиком тепла является
специальное вещество — хладагент
❄️
Компрессор
засасывает хладагент в виде
пара
💨
и сжимает его за счёт повышения давления, при этом температура хладагента возрастает. После сжатия вещество попадает в
конденсатор
, где
нагретый хладагент остывает
, отдавая тепло во внешнюю среду. Если вы имели дело со старыми холодильниками, то наверняка замечали
змееподобную трубку
на его задней стороне, которая довольно-таки сильно нагревалась во время работы. В нём
хладагент с выделением тепла конденсируется, то есть превращается в жидкость
💧
Жидкое вещество под давлением поступает через
узкий капилляр
или регулируемый вентиль в
испаритель
, где за счёт резкого
уменьшения давления
происходит испарение жидкости
🌬
Так как испарение — это процесс, протекающий с
поглощением тепла
, хладагент
отнимает
его из окружающей среды через стенки испарителя, за счёт чего происходит охлаждение.
Чтобы вам было легче представить это явление, вспомните, какое чувство прохлады вы испытываете,
выходя на сушу из тёплого водоёма
🏖
Ваше тело охлаждается за счёт
испарения капель воды с поверхности кожи
. За счёт аналогичных процессов наш организм охлаждается, когда мы потеем, чтобы избежать перегрева. Это лежит в основе естественной терморегуляции.
Таким образом,
в конденсаторе
хладагент под воздействием высокого давления переходит в жидкое состояние,
выделяя тепло
, а в
испарителе
под воздействием низкого давления вскипает и переходит в газ,
поглощая тепло
. Затем хладагент снова поступает через компрессор в конденсатор, и
цикл многократно повторяется
🔁
Общая схема довольно-таки проста
Стоит отметить, что большое значение имеет
чистота хладагента
: вода и примеси могут засорить капилляр или повредить компрессор
🙅♀️
Примеси могут образовываться в результате
коррозии
внутренних стенок трубопроводов холодильника, а влага может попасть при его
заправке
. Поэтому в каждом холодильнике имеется фильтр-осушитель, наполненный адсорбентом, который защищает капиллярную трубку.
Также существует несколько вариантов компоновки. Наиболее привычной для нас является
«европейская»
, когда морозильная камера находится
снизу
, а холодильная —
сверху
. Вариант с обратным расположением камер классифицируют как
«азиатский»
. Компоновку, в которой холодильное и морозильное отделение расположены
по всей высоте устройства
, называют
«американской»
или
side-by-side
. | https://t.me/ychemistry/948?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,000 | 0 | 1,720,182,116 | 1,736,456,940 | 1,136 | 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| null | NEUTRAL | rus | NOT SPAM | 408 | 0 | 3 | 0.994565 | 0.005435 | 0 | 46 | 68 | 17 | 2 | 138 | 19 | 68 | true |
118 | null | Без SLS и SLES. Что скрывается за этой надписью?
Я думаю, ты часто замечал надпись
"Без SLS и SLES"
, обведённую в зелёный кружочек на упаковке шампуня, геля для душа или пенки для умывания. Давай разберёмся, что значит сочетание этих букв и почему маркетологи так активно его используют.
SLS и SLES
— это сокращение названий
sodium lauryl sulfate
и
sodium laureth sulfate
(лаурил- и лауретсульфаты натрия), которые представляют собой одни из самых распространенных ПАВов в косметической продукции. И для того, чтобы понять их назначение, давай рассмотрим, что такое
ПАВ
.
Задача поверхностно-активных веществ — удалять грязь с поверхности.
Если в качестве поверхности выступает наша кожа, ПАВ проникают в жир, который естественным образом скапливается на ней, встраиваются в него, дробят на мелкие частицы, обволакивают и смывают вместе с водопроводной водой. Стоит понимать, что
очищающих средств без ПАВ просто не может существовать
, но есть разные типы, отличающиеся друг от друга по строению и воздействию.
Анионные ПАВ
— самый распространённые и в то же время самый агрессивные. К этому типу относятся те самые
сульфаты
, которых многие остерегаются. Их достоинствами являются
невысокая стоимость и эффективность — способность образовывать объемную пену.
Сочетание этих качеств побуждает производителей бюджетных средств использовать анионные ПАВы в своей продукции. Но
главный минус — сульфаты раздражают кожу — особенно отражается на обладателях чувствительной и проблемной кожи.
После использования средств с анионными ПАВами наблюдается чувство сухости и стянутости.
Второй тип —
катионные ПАВ
— используется в составах для смягчения агрессивного действия анионных.
Третий тип —
неионогенные ПАВ
— обладает
самым мягким воздействием
, поэтому их включают в состав детской косметики и средств для чувствительной и проблемной кожи. Но тут мы сталкиваемся с
главным минусом — неиногенные ПАВ почти не пенятся,
поэтому их чаще всего используют в комбинации с анионными.
И последний тип —
амфотерные ПАВ
— так же максимально мягко воздействует на кожу и обладает бактерицидными свойствами.
Исследователи считают, что
сульфаты в целом безопасны
для здоровья человека, потому что они используются в тех средствах, которые быстро наносятся и так же быстро смываются (нам же не нужно оставлять шампунь на волосах в течение нескольких часов). Агрессивность анионных ПАВ может стать решающим фактором в выборе средств для чувствительной и проблемной кожи, но это не значит, что стоит выбрасывать все шампуни и гели с SLS и SLES в составе.
Производители качественной продукции добавляют в состав другие типы ПАВ для уменьшения раздражающего действия SLS.
Если ты видишь в составе после sodium lauryl sulfate мягкие ПАВы — Cocamidopropyl Betaine, Decyl Glucoside и многие другие — то скорее всего очищающее действие такого средства
сбалансировано.
Ты можешь погуглить другие названия мягких ПАВ, потому что их действительно много.
Надпись "Не содержит SLS" — это скорее маркетинговый ход, поэтому не стоит ориентироваться на неё при выборе косметики.
Читай составы, изучай компоненты и обязательно ориентируйся на реакцию своей кожи. | https://t.me/ychemistry/949?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,100 | 0 | 1,720,347,191 | 1,736,456,940 | 1,133 | 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| [{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":466,"end_pos":469},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":567,"end_pos":570},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":690,"end_pos":693},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":903,"end_pos":906},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":1022,"end_pos":1025},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":1350,"end_pos":1353},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":1529,"end_pos":1532},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":1601,"end_pos":1604},{"ner":"ПАВ","lemma":"пава","label":"ORG","start_pos":1703,"end_pos":1706},{"ner":"SLS","lemma":"sls","label":"ORG","start_pos":2517,"end_pos":2520},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":2607,"end_pos":2610},{"ner":"SLS","lemma":"sls","label":"ORG","start_pos":2649,"end_pos":2652},{"ner":"Decyl Glucoside","lemma":"decyl glucoside","label":"ORG","start_pos":2745,"end_pos":2760},{"ner":"Читай","lemma":"читать","label":"LOC","start_pos":3049,"end_pos":3054}] | NEUTRAL | rus | NOT SPAM | 459 | 0 | 25 | 0.959147 | 0.040853 | 0 | 56 | 67 | 26 | 1 | 113 | 26 | 78 | true |
118 | null | Химия пыли
Когда мы приходим в гости к другу и замечаем на его столе слой пыли
🔍
, то сразу делаем вывод, что это неопрятный и ленивый человек. Хотя это необязательно так! Бывает вытираешь пыль, а через 10 минут она опять на месте, как будто никто её и не убирал. Дело в том, что от этих «летающих» частиц размером 0,1 - 100 мкм - не так просто избавиться.
Всего за сутки на квадратом сантиметре квартиры
🏤
оседает около 1000 пылевых «кусочков». 40% - минеральные частицы, в первую очередь, глинозем (Al2O3) и кремнезем (SiO2). 20% - кусочки кожи человека, 15% - текстильные и бумажные волокна, 10% цветочная пыльца, 3% - частицы сажи и дыма.
💨
Соотношение частиц может меняться, но средний состав неизменен - половину производит человек, остальное - природа.
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Насколько вредна пыль?
Она безобидна если у вас нет аллергии. А вот если вы аллергик, то лучше проводить регулярные влажные уборки. Однако есть вещи похуже аллергии. Нередко в квартиру попадает очень мелкая строительная пыль и другие «острые» химически активные наночастицы. Они обитают в воздухе и считаются довольно опасными для организма человека.
Как бороться?
🚿
Регулярная влажная уборка, желательно без дополнительных химических средств.
💦
Поддержание влажности воздуха в помещении 40-70% (купите гигрометр психрометрический - он точнее китайских поделок).
💧
Водяной пылесос+ HEPA-фильтр.
Так пыли не будет слишком много. | https://t.me/ychemistry/951?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 1,800 | 0 | 1,720,521,192 | 1,736,456,940 | 1,133 | 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118 | null | Максимальное приближение чайного пакетика. | https://t.me/chemistrytg2021/9444?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,200 | 0 | 1,734,189,600 | 1,736,456,941 | 1,136 | 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118 | null | На сайте Научной электронной библиотеки
Elibrary.ru
опубликован очередной номер Журнала общей химии (том 94, № 6, 2024 г.)
Содержание выпуска со ссылками на статьи:
Получение, реакции и применение 2,2-диметил-4-оксиметил-1,3-диоксолана (обзор).
Нуриева Э.Р., Борисова Ю.Г., Раскильдина Г.З., Султанова Р.М., Злотский С.С.
https://www.elibrary.ru/item.asp?id=74210270
Аддукты Дильса-Альдера N-замещенных 2-пиридонов с малеинимидами. Синтез и противовирусная активность.
Сорокина А., Ковальская А.В., Лобов А.Н., Ильина П.А., Зарубаев В.В., Цыпышева И.П.
https://www.elibrary.ru/item.asp?id=74210271
Синтез и строение этил-4-арил-2-оксо-2,3,4,10-тетрагидробензо[4,5]имидазо[1,2-а]-пиримидин-3-карбоксилатов.
Подчезерцева К.В., Замараева Т.М., Слепова Н.В., Дмитриев М.В.
https://www.elibrary.ru/item.asp?id=74210272
Особенности взаимодействия орто-карбораниллития с 3,6-бис(3,5-диметил-1H-пиразол-1-ил)-1,2,4,5-тетразином.
Мосеев Т.Д., Смышляева Л.А., Копчук Д.С., Ишметова Р.И., Слепухин П.А., Рыбакова А.В., Русинов Г.Л., Зырянов Г.В., Вараксин М.В., Чарушин В.Н., Чупахин О.Н.
https://www.elibrary.ru/item.asp?id=74210273
Производные (-)-цитизина с тиомочевинным фрагментом. Синтез и противовирусная активность.
Ковальская А.В., Лобов А.Н., Зарубаев В.В., Цыпышева И.П.
https://www.elibrary.ru/item.asp?id=74210274
Синтез производных бетулоновой и бетулиновой кислот с сульфонамидным фрагментом, связанным с тритерпеноидом амидоалкановым спейсером.
Комиссарова Н.Г., Орлов А.В., Спирихин Л.В.
https://www.elibrary.ru/item.asp?id=74210275
Влияние производных аминофенола и аминокислот на уровень нитрозил- радикала и его активных форм in vitro.
Овсянникова Е.М., Бурко А.А., Ксендзова Г.А., Сорокин В.Л., Каранкевич Е.Г., Юркова И.Л.
https://www.elibrary.ru/item.asp?id=74210276
Спектрофотометрический анализ сополиариленфталидов и их сополимеров с метилметакрилатом и стиролом.
Юмагулова Р.Х., Янгиров Т.А., Аюпова А.Р., Крайкин В.А.
https://www.elibrary.ru/item.asp?id=74210277
Гетероядерные глицинатные комплексы Fe(II), Fe(III) И Co(II), их модельные параметры.
Бобоназарзода Г.Б.
https://www.elibrary.ru/item.asp?id=74210279
Влияние строения карбамоилметилфосфиноксидов на экстракцию лантанидов(III) из азотнокислых растворов в присутствии динонилнафталинсульфокислоты.
Туранов А.Н., Карандашев В.К., Артюшин О.И., Шарова Е.В.
https://www.elibrary.ru/item.asp?id=74210280
Термические и люминесцентные свойства разнолигандных комплексов европия(III) c пиразиновой кислотой.
Калиновская И.В., Задорожная А.Н., Курявый В.Г., Попов Л.Д.
https://www.elibrary.ru/item.asp?id=74210281
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| NEUTRAL | rus | SPAM | 245 | 0 | 54 | 0.947514 | 0.052486 | 0 | 30 | 3 | 1 | 5 | 62 | 0 | 71 | true |
118 | null | В рамках национального проекта "Наука и университеты" Министерством науки и высшего образования РФ в 2024 году была создана Молодежная лаборатория новых антибактериальных координационных соединений.
В telegram-канале молодежной лаборатории
Химический CoFe
публикуются интересные и познавательные материалы, посвященные:
✅
разработке биологически активных органических и металлсодержащих соединений в рубрике #DrugDesign
💊
✅
металлам в живых и неживых системах в рубрике #Металлы_inVitro@inVivo
🧫
✅
красивой химии, миру кристаллов в природе и лаборатории в рубрике #УдивительноеРядом
🪄
🔬
✅
жизни молодёжной лаборатории: конференции, публикации, интересные опыты в рубрике #МолЛаб
👩🔬
✅
сотрудничеству с другими научными институтами, проведению совместных работ, стажировок, выпуску публикаций в рубрике #Сотрудничество
🤝
Присоединяйтесь к каналу наших коллег, будет интересно!
#ионх | https://t.me/chemrussia/5070?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,600 | 0 | 1,732,773,637 | 1,736,456,941 | 1,138 | 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| [{"ner":"Министерством науки и высшего образования","lemma":"министерство наука и высокий образование","label":"ORG","start_pos":55,"end_pos":96},{"ner":"РФ","lemma":"рф","label":"LOC","start_pos":97,"end_pos":99},{"ner":"Молодежная лаборатория новых антибактериальных координационных соединений","lemma":"молодёжный лаборатория новый антибактериальный координационный соединение","label":"ORG","start_pos":125,"end_pos":198},{"ner":"telegram-канале","lemma":"telegram-канал","label":"ORG","start_pos":202,"end_pos":217},{"ner":"МолЛаб","lemma":"моллаб","label":"LOC","start_pos":674,"end_pos":680},{"ner":"2024","lemma":"2024","label":"NUM","start_pos":102,"end_pos":106}] | NEUTRAL | rus | NOT SPAM | 109 | 0 | 3 | 0.974359 | 0.025641 | 0 | 22 | 7 | 0 | 0 | 46 | 1 | 20 | true |
118 | null | БЕЛОК КОЛЛАГЕН. Биологическая роль
👨⚕️
Когда на занятии речь заходит про белок коллаген, я всегда в самом начале задаю вопрос своим студентам: а какой самый распространенный белок в нашем организме?
Некоторые отвечают, что это актин и миозин - белки мышечной ткани, другие рассуждают про белки плазмы крови, но ответ лежит в названии темы - это
белок коллаген
.
⚡️
Белок коллаген - самый распространенный белок млекопитающих, в том числе и человека, составляя от 30 до 45% от массы всех белков.
Он является основным компонентом соединительной ткани, которая не отвечает за работу какого либо конкретного органа, а выполняет структурообразующую, опорную и трофическую функцию. Поэтому коллаген - основной белок сухожилий, связок, костей, хрящей, дермы, фасций, базальных мембран, дентина и даже роговицы глаза.
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Коллаген образует, как макроскелет: кости, хрящи, связки, так и «микроскелет» : базальные мембраны, на которых располагаются эпителиальные клетки или фасции, выстилающие мышцы и сухожилия.
Скоро я расскажу и про виды коллагена, и про синтез, и про роль витамина С, а на курсе по белкам мы в подробностях разберем с вами все этапы синтеза и созревания.
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А пока расскажите, что вы знаете про коллаген? | https://t.me/simplebestbiochemistry/430?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,000 | 0 | 1,726,465,073 | 1,736,456,941 | 1,112 | 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| [{"ner":"БЕЛОК КОЛЛАГЕН","lemma":"белок коллаген","label":"ORG","start_pos":0,"end_pos":14},{"ner":"Коллаген","lemma":"коллаген","label":"PER","start_pos":813,"end_pos":821},{"ner":"30","lemma":"30","label":"NUM","start_pos":464,"end_pos":466},{"ner":"45","lemma":"45","label":"NUM","start_pos":470,"end_pos":472}] | NEUTRAL | rus | NOT SPAM | 185 | 0 | 4 | 1 | 0 | 0 | 22 | 17 | 9 | 2 | 65 | 5 | 46 | true |
118 | null | КОЛЛАГЕН. Типы
Тема белка коллагена вызвала бурный
интерес, поэтому будем рассказывать и отвечать на вопросы в следующий постах!
А сегодня давайте поговорим о типах коллагена.
Как мы сказали в предыдущем уроке, коллаген - самый распространенный белок в организме, и входит в состав соединительной ткани. Однако соединительная ткань несколько отличается по своим свойствам в разных органах и тканях, а потому и белок коллаген имеет несколько разное строение.
Сегодня описано 28 типов коллагена. Они отличаются друг от друга по аминокислотной последовательности, а также по степени модификации — интенсивности гидроксилирования (как много групп -OH присоединено к аминокислотам) и гликозилирования (как много молекул глюкозы или галактозы присоединено к аминокислотам). Но самые распространенные - первые 4 типа. Давайте скажем их локализацию.
1️⃣
Тип - сетчатый слой кожи, костная ткань, сухожилия, дентин, склера, стенка артерий, роговица глаза.
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Первый тип наиболее распространенный, поэтому встречается в том или ином количестве во всей соединительной ткани.
2️⃣
Тип - преимущественно гиалиновые и фиброзные хрящи (компоненты суставов), стекловидное тело, роговица глаза.
3️⃣
Тип - стенка крупных кровеносных сосудов, матка, ретикулярные волокна органов кроветворения.
4️⃣
Тип - базальная мембрана - соединительнотканная основа для всех эпителиальных тканей - эпителий кожи, слизистых, эндотелий сосудов.
А в следующем посте мы поговорим с вами про синтез белка коллагена, и ответим на вопрос о роли пищевого приема коллагена, как БАДа
🔥 | https://t.me/simplebestbiochemistry/432?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,000 | 0 | 1,726,642,428 | 1,736,456,941 | 1,137 | 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| [{"ner":"БАДа\n🔥","lemma":"бада\n🔥","label":"ORG","start_pos":1535,"end_pos":1541},{"ner":"28","lemma":"28","label":"NUM","start_pos":474,"end_pos":476},{"ner":"4","lemma":"4","label":"NUM","start_pos":803,"end_pos":804},{"ner":"1","lemma":"1","label":"NUM","start_pos":842,"end_pos":843},{"ner":"2","lemma":"2","label":"NUM","start_pos":1063,"end_pos":1064},{"ner":"3","lemma":"3","label":"NUM","start_pos":1176,"end_pos":1177},{"ner":"4","lemma":"4","label":"NUM","start_pos":1273,"end_pos":1274}] | NEUTRAL | rus | NOT SPAM | 215 | 0 | 4 | 0.99635 | 0.00365 | 0 | 40 | 18 | 6 | 3 | 84 | 15 | 43 | true |
118 | null | Как потрогать коллаген руками?
Интересный факт, который я рассказываю своим студентом, когда мы разбираем тему коллагена и соединительной ткани, заключается в том, что все натуральные изделия из выделанной кожи - не что иное как
прочная и густая сеть коллагеновых волокон
и практически больше ничего!
Процесс дубления кожи, говоря простым языком, направлен на то, чтобы, во-первых, полностью удалить жидкую часть, а, во-вторых, дополнительно «склеить и скрепить» коллагеновые волокна между собой с помощью дубильных средств.
Вот такая вот «наглядная биохимия»!
😂 | https://t.me/simplebestbiochemistry/433?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,000 | 0 | 1,726,724,526 | 1,736,456,941 | 1,137 | 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| null | NEUTRAL | rus | NOT SPAM | 79 | 0 | 0 | 1 | 0 | 0 | 13 | 9 | 8 | 0 | 20 | 11 | 22 | true |
118 | null | Графит, алмаз... а что еще?
💎
Раз уж мы затронули тему
аллотропных модификаций
, я не могу пройти мимо элемента с самым большим их количеством. И речь идёт об
углероде
— его модификации наиболее радикально отличаются друг от друга: от мягкого к твёрдому, непрозрачного к прозрачному, дешёвого к дорогому.
Давайте познакомимся с некоторыми из них
👀
Напомню, что под явлением
аллотропии понимают существование двух и более простых веществ одного и того же химического элемента
. Помимо известных каждому форм —
графита и алмаза
— углерод имеет
более 9
аллотропных соединений. И почти каждое из них представляет интерес для современной науки
👩🏻🔬
Начнём с
графита
— черного блестящего минерала со слоистой структурой. Чтобы понять его строение, представьте себе торт наполеон из бесчисленного количества слоёв. Благодаря тому, что эти слои легко скользят относительно друг друга, графит
очень мягок
и используется в грифелях карандашей и в качестве смазочного материала. Также за счёт своей
инертности и электропроводности
из графита делают электроды и термостойкую посуду. Если в 2019 году вы посмотрели нашумевший сериал о катастрофе на
ЧАЭС
, то наверняка обратили внимание, что графитовые стержни также используется в
ядерных реакторах
☢️
Если от слоёного графитового пирога отделить слой
толщиной в один атом
, будет получено другое соединение —
графен
. Это по истине удивительный материал и первопроходец в мире двумерных кристаллов. Графен, представляющий плёнку толщиной всего в один атом, обладает рекордной тепло- и электропроводностью. Эти и другие качества делают его перспективным современным материалом для наноэлектроники и производства микросхем. В 2018 году из графена изготовили
сверхтонкие фильтры
для очистки воды и синтезированы
противораковые препараты
. Причем количество исследований и патентов, связанных с графеновыми материалами, растёт без остановки
🔬
Если из листа графена сделать выкройку и свернуть её особым образом, будет получена
углеродная нанотрубка
. Это другая модификация углерода, исследования которой не дают покоя учёным. За счёт высокой прочности и особого строения из нанотрубок создают удивительные вещи: начиная от сверхпрочных нитей и капилляров, заканчивая искусственными мышцами и
космическими лифтами
🧬
Если вы сейчас подумаете о
футбольном мяче
, то вы без проблем представите структуру еще одной модификации углерода —
фуллерена
. Это шарообразные молекулы, число атомов в которых может варьироваться от
60 до 400
. Помимо применения в качестве проводниковых материалов, фуллерены изучаются и в медицинских целях. Они являются мощнейшими
антиоксидантами
— веществами, препятствующими процессу окисления в живых организмах. Помимо этого, экспериментально подтверждена эффективность фуллерена в лечении
ВИЧ
🦠
Теперь вы представляете, какое многообразие скрывается за элементом, который ассоциировался у нас с углём и сажей
💁🏻♀️ | https://t.me/ychemistry/942?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,100 | 0 | 1,719,750,690 | 1,736,456,941 | 1,111 | 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118 | null | Как сделать бомбы для ванны своими руками?
🛁
Если вы любите устраивать домашние спа-процедуры, принимать расслабляющие ванны, или просто фанатеете от
бомбочек
из Lush, но не готовы выкладывать за них предложенную цену, то данный пост будет для вас
актуальным
.
Он в любом случае будет полезным, потому что всё, что связано с химией — это интересно
👩🏻🔬
Прогуливаясь в торговом центре мимо стендов со средствами для душа, я обратила внимание на
бомбы для ванны
. Вернее, на ту
цену
, за которую предлагают приобрести довольно-таки
примитивную химическую смесь
, учитывая, что её можно приготовить из
«кухонных»
реактивов. Хотя поспорить не могу,
пахнут они
потрясающе и в воде выглядят эффектно
✨
Основа любой бомбочки для ванны — это два компонента.
Пищевая сода и лимонная кислота
. Именно благодаря их взаимодействию получается тот самый
бурлящий и пузырящийся эффект
🌊
Пищевая сода — это кислая соль угольной кислоты с формулой NaHCO₃
. В составах ей приписывают разные наименования:
бикарбонат натрия, гидрокарбонат натрия, натрий двууглекислый
или пищевая добавка под номером
E500 (ii)
. Это всё названия одного и того же вещества
🤔
Лимонная кислота — это слабая органическая кислота
, используемая как
консервант
и
регулятор кислотности
в пищевой промышленности. При взаимодействии с пищевой содой она вытесняет гидрокарбонат-ион в виде
угольной кислоты
, которая
не устойчива
в растворе и мгновенно распадается на
углекислый газ CO₂ и воду H₂O
. Наверное, это один из самых простых типов взаимодействия, который только можно представить. Выделяющийся
углекислый газ как раз и образует мелкие пузырьки и шипение
💨
На этой реакции основано использовании бикарбоната натрия в пищевой промышленности в качестве
разрыхлителя
🍞
Хозяйки добавляют соду в тесто, а содержащиеся в нём кислые компоненты (
уксус и молочная кислота
) аналогичным образом взаимодействуют с гидрокарбонатом натрия.
Выделяющийся углекислый газ вспучивает тесто и делает его пористым и воздушным
🍰
А теперь к методике изготовления бомбочек для ванны
. В качестве базы используем смесь
2 частей пищевой соды и 1 части лимонной кислоты
(можно перемолоть сухие компоненты, чтобы избежать попадания крупных кусков).
А дальше включаем фантазию
🧙🏻♀️
Можно добавить к смеси несколько капель
пищевых красителей
, создавая узоры на самой бомбочке. Тогда непосредственно во время использования мы получим цветную пену и окрашенную воду
🌈
Приятным дополнением будет несколько капель
эфирных масел
с вашим любимым ароматом. Какую-то глобальную пользу для кожи они вряд ли принесут, но приятный запах в ванной уж точно обеспечат
🌺
За ароматическое сопровождение спа-процедуры могут отвечать сухие измельченные травы или натуральные компоненты: мёд, цедра лимона или апельсина, масло какао, молотый кофе, сухое молоко или сливки
🍯
После создания неповторимой рецептуры смесь стоит
утрамбовать в шарообразные формочки
, при необходимости сбрызнуть водой из пульверизатора для лучшего склеивания и
оставить на 4-5 часов в сухом месте
. После полного затвердевания бомбы можно отложить на пару дней или использовать сразу по назначению
🛀🏻
Уверена, бомбы для ванны у вас получатся не хуже, чем на полках в магазине, а сам процесс принесет удовольствие и позволит почувствовать себя в роли химика-технолога, разрабатывающего рецептуру нового средства для ухода за телом
⚗️ | https://t.me/ychemistry/943?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,200 | 0 | 1,719,910,108 | 1,736,456,941 | 1,136 | 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| [{"ner":"Lush","lemma":"lush","label":"ORG","start_pos":162,"end_pos":166},{"ner":"цедра лимона","lemma":"цедра лимон","label":"PER","start_pos":2711,"end_pos":2723},{"ner":"₃","lemma":"₃","label":"NUM","start_pos":936,"end_pos":937},{"ner":"500","lemma":"500","label":"NUM","start_pos":1082,"end_pos":1085},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":1438,"end_pos":1439},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":1448,"end_pos":1449},{"ner":"2","lemma":"2","label":"NUM","start_pos":2059,"end_pos":2060},{"ner":"1","lemma":"1","label":"NUM","start_pos":2083,"end_pos":2084},{"ner":"4","lemma":"4","label":"NUM","start_pos":2969,"end_pos":2970},{"ner":"5","lemma":"5","label":"NUM","start_pos":2971,"end_pos":2972}] | NEUTRAL | rus | NOT SPAM | 495 | 0 | 7 | 0.990566 | 0.009434 | 0 | 66 | 57 | 23 | 10 | 167 | 23 | 73 | true |
118 | null | Немного интересных фактов:
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Ботву от семейства пасленовых (томаты, болгарский перец, картофель, перец чили, баклажаны и т.д.) теоретически можно курить, потому что она содержит никотин. В растениях он используется как химическое оружие – убивает колорадских жуков
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Химики-пищевики используют потовые кислоты (да-да, те, что содержатся в нашем поту, только вряд ли их выделяют из пота, не пугайтесь) для создания различных ароматов в йогуртах
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Бананы радиоактивны!
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Они содержат в себе изотоп калия-40. В ядерной энергетике есть даже «банановый эквивалент» – понятие, характеризующее активность радиоактивного источника. Также природный уровень радиации выше среднего у картофеля, бобов, орехов и т.д. Вот и живите теперь с этим, любители натурального:)
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Кислород – это тоже пищевая добавка! Е949, используется для упаковки товаров. | https://t.me/ychemistry/944?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,100 | 0 | 1,720,010,802 | 1,736,456,941 | 1,136 | 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118 | null | Тайна второго носка. Что такое энтропия и как она объясняет беспорядок в твоей комнате
Ты наверняка замечал, как после уборки в шкафу футболки, носки, джинсы вновь образуют одну большую кучу. Или как через пару дней после наведения порядка на столе тетради, книги и ручки разбросаны по всей квартире. Это не ты такой халява —
это фундаментальные законы природы.
В рамках
классической термодинамики
— раздела физики, изучающего тепловые процессы, — вводится понятие
энтропии
. У этого термина много определений. Условимся считать, что энтропия — мера беспорядка, хаоса. И еще запомним вот это:
самопроизвольно в природе протекают только те процессы, в которых энтропия возрастает
. Так звучит одна из формулировок
второго закона термодинамики.
Простой пример. Представим, что у нас есть прямоугольный сосуд, разделенный непроницаемой перегородкой. В одной половине сосуда находится один газ, во второй половине — другой. Грубо говоря, наша
система упорядочена.
Молекулы двух разных газов, как рубашки и брюки, лежат в отдельных стопочках.
А теперь уберём перегородку. Очевидно, что газы смешаются, молекулы одного газа окажутся в окружении другого. И уже ни о какой упорядоченности не может идти речи. Произошел
необратимый процесс
, результатом которого стала смесь газов. В системе стало
больше беспорядка, энтропия возросла.
Второй закон термодинамики в действии.
Получается, что
в природе всё стремится к беспорядку.
Ты не найдешь лес, где стройными рядами растут деревья одного вида. Не найдешь пляж, где камни разного размера разложены по отдельным кучкам.
То же самое происходит и в нашей жизни. Как только ты проводишь дома генеральную уборку, вся система желает перейти в более выгодное состояние с наибольшим значением энтропии.
Порядок сменяется хаосом.
И это следует из фундаментального закона :) | https://t.me/ychemistry/945?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,200 | 0 | 1,720,093,849 | 1,736,456,941 | 1,136 | 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| null | NEUTRAL | rus | NOT SPAM | 265 | 0 | 8 | 1 | 0 | 0 | 26 | 39 | 15 | 8 | 91 | 14 | 56 | true |
118 | null | Яблоко «Черный алмаз».
Их выращивают в горах Тибета на высоте 3,5 тысяч метров. Почему же оно такого цвета? Все дело в экстремальных условиях, в которых оно растет. Резкие суточные перепады температур и сильное ультрафиолетовое излучение привело к потемнению его кожуры. | https://t.me/chemistrytg2021/9440?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,500 | 0 | 1,734,114,001 | 1,736,456,942 | 1,111 | 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| null | NEUTRAL | rus | NOT SPAM | 4 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 0 | 0 | 2 | 0 | 0 | true |
118 | null | Айфон против раскалённой лавы. | https://t.me/chemistrytg2021/9442?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,734,168,000 | 1,736,456,942 | 1,111 | 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| null | NEUTRAL | rus | NOT SPAM | 4 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 0 | 0 | 2 | 0 | 1 | true |
118 | null | Если бы ракеты были прозрачными.
Красный = Керосин РП-1
Желтый = жидкий водород LH2
Синий = жидкий кислород LOX | https://t.me/chemistrytg2021/9443?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,300 | 0 | 1,734,178,500 | 1,736,456,942 | 1,111 | 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| [{"ner":"1","lemma":"1","label":"NUM","start_pos":54,"end_pos":55},{"ner":"2","lemma":"2","label":"NUM","start_pos":82,"end_pos":83}] | NEUTRAL | rus | NOT SPAM | 19 | 0 | 3 | 0.913044 | 0.086957 | 0 | 6 | 0 | 0 | 0 | 4 | 0 | 3 | true |
118 | null | 3-5 февраля 2025 г. в Анталии (Турция) состоится 5 Анатолийская конференция по органической химии (ACOC5).
В числе тематик конференции - катализ, металлорганическая химия, химия гетероциклов, фотокатализ, органический синтез, электросинтез.
Регистрация на конференцию открыта до 5 января 2025 г.
https://anatolianorgchem.org
#конференция | https://t.me/chemrussia/5063?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 4,300 | 0 | 1,732,687,241 | 1,736,456,942 | 1,111 | 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118 | null | На сайте научной электронной библиотеки
eLibrary.ru
опубликован очередной номер журнала «Координационная химия» (2024, Том 50, № 8, с. 413-468)
Содержание номера со ссылками на статьи:
Синтез (η6-арен)хромтрикарбонильных комплексов 1,3-бензодиоксанов.
Гришина Н.Ю., Сазонова Е.В., Ушакова П.С., Сомов Н.В., Медведева Е.А., Шишкин А.Ю., Артемов А.Н.
https://www.elibrary.ru/item.asp?id=73951685
2D-координационные полимеры Zn(II) с дианионами диэтилмалоновой кислоты и 4,4 '-бипиридином: синтез и строение.
Чистяков А.С., Зорина-Тихонова Е.Н., Вологжанина А.В., Кискин М.А., Еременко И.Л.
https://www.elibrary.ru/item.asp?id=73951686
Кристаллическое строение солей лантаноидов с 2,4-дихлорфеноксиуксусной кислотой.
Кискин М.А., Конник О.В., Шульгин В.Ф., Гусев А.Н.
https://www.elibrary.ru/item.asp?id=73951687
Первый пример дикуба нового комплекса никеля(II) в ряду несимметрично замещенных дикетонов.
Хамидуллина Л.А., Пузырев И.С., Дороватовский П.В., Хрусталев В.Н., Пестов А.В.
https://www.elibrary.ru/item.asp?id=73951688
Метилсульфатный комплекс (Bu4N)2[Mo6I8(O3SOCH3)6]: синтез, строение, лабильность лигандов и фосфоресценция.
Михайлов М.А., Сухих Т.С., Шевень Д.Г., Березин А.С., Соколов М.Н., Компаньков Н.Б.
https://www.elibrary.ru/item.asp?id=73951689
Псевдополимерный ди-изо-амилдитиофосфат таллия(1), [Tl{S2P(O-изо-C5HJ2}]: получение, структура (роль вторичных взаимодействий T1-S и Tl-O в супрамолекулярной самоорганизации) и термическое поведение.
Бредюк О.А., Луценко И.А., Нелюбина Ю.В., Зинченко С.В., Иванов А.В.
https://www.elibrary.ru/item.asp?id=73951690
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118 | null | Использование металл-органического координационного полимера с фрагментами 2,1,3-бензотиадиазола для люминесцентного обнаружение ионов галлия
Ученые из Института неорганической химии имени А.В. Николаева СО РАН синтезировали четыре различных металл-органических координационных полимера (МОКП), построенных из катионов цинка(II), анионов терефталевой кислоты и люминесцентного лиганда 4,7-ди(1,2,4-триазол-1-ил)-2,1,3-бензотиадиазола. Выявлено, что полученные соединения проявляют чувствительный отклик на присутствие в растворе катионов Ga3+ с пределом обнаружения около 2 мкмоль/л. Важно отметить, что галлий широко применяется в микроэлектронной промышленности и, хотя его катионы не проявляют выраженной острой токсичности, влияние длительного воздействия низких концентраций галлия на здоровье человека еще не полностью изучено, в связи с чем природоохранными организациями рекомендуется осуществлять мониторинг содержания галлия в объектах окружающей среды. Исследование фотофизических характеристик ряда МОКП, построенных из одинаковых лигандов, но имеющих различное координационное окружение центрального иона, размерность и особенности межмолекулярных взаимодействий, позволило выполнить анализ влияния этих факторов на люминесцентные и сенсорные свойства МОКП.
Результаты работы опубликованы в журнале «Crystal Growth & Design».
Pavlov D.I., Ryadun A.A., Fedin V.P., Yu X., Potapov A.S. Structural Diversity and Tunable Luminescent Properties of Zn(II) Metal–Organic Frameworks with Terephthalate and 4,7-Di(1,2,4-Triazol-1-yl)-2,1,3-Benzothiadiazole Linkers. Cryst. Growth Des. 2024. Vol. 24. 9415-9424.
https://doi.org/10.1021/acs.cgd.4c00797
Источник:
ИНХ СО РАН
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118 | null | С 14 по 16 ноября 2024 г. в Центре культур Высшей школы экономики на Покровском бульваре состоялся 1-й Московский форум дополнительного образования «Вызовы цифровизации и новые университетские решения». Это событие стало крупнейшим в России в сфере дополнительного профессионального образования (ДПО). Программа включала более 50 мероприятий по 10 тематическим трекам. Обсуждались такие актуальные темы как государственная политика и новые решения в ДПО, цифровая трансформация; качество ДПО; продуктовый подход и маркетинг в ДПО; искусственный интеллект и анализ данных в непрерывном образовании; дизайн и организация программ ДПО, а также образовательные решения, результаты исследований, современные направления развития и подходы к организации ДПО и многое другое.
В мероприятии приняла участие заведующая Центром коллективного пользования физическими методами исследований веществ и материалов, главный научный сотрудник, профессор, доктор химических наук Барановская Василиса Борисовна.
В ИОНХ РАН активно развивается система ДПО в области химии и материаловедения. Профессорами и экспертами ИОНХ разработаны уникальные программы повышения квалификации с упором на прикладные навыки, которые помогут решать современные научные и производственные задачи.
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118 | null | #явление
https://telegra.ph/Vosplamenyayushchaya-strast-himii-04-25 | https://t.me/incredible_chemistry/266?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 3,800 | 0 | 1,682,485,203 | 1,736,456,942 | 1,113 | 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| [{"ner":"04-25","lemma":"04-25","label":"DATE","start_pos":62,"end_pos":67},{"ner":"25","lemma":"25","label":"NUM","start_pos":65,"end_pos":67}] | NEUTRAL | eng | NOT SPAM | 2 | 0 | 0 | 0.75 | 0.25 | 0 | 0 | 0 | 0 | 0 | 1 | 0 | 1 | true |
118 | null | ГЛИЦИН. Тормозная аминокислота
Глицин, с точки зрения химического строения, одна из самых простых аминокислот, имеющая формулу:
NH2 — CH2 — COOH
Функции глицина разнообразны. Это и ключевая аминокислота для синтез белков, и субстрат для синтез гема (а далее гемоглобина), и субстрат для синтез пуриновых нуклеотидов (компонентов ДНК и РНК).
Но одна функция наиболее интересна, глицин -
ключевая аминокислота ЦНС
! При этом ее функция двояка.
1️⃣
Глицин связывается с глициновыми рецепторами (кодируемые генами GLRA1, GLRA2, GLRA3 и GLRB) в головном и спинном мозге и оказывает с одной стороны тормозное действие, уменьшая выработку глутамата и повышая выделение ГАМК.
2️⃣
Также глицин связывается и с NMDA – рецепторами, но на них оказывает активирующее действие, наоборот, стимулируя выработку нейромедиаторных аминокислот аспартата и глутамата, которые обладают возбуждающим действием.
❗️
Таким образом, глицин, действительно, обладает успокаивающим и тормозящим эффектом. Но есть одно но!
Глицин из плазмы крови не попадает в нейроны, поскольку не проникает через ГЭБ. А потому таблетки глицина, в каких бы дозировках они не были, торможения в ЦНС не вызывают.
А вот откуда он берется в нейронах, мы разберем с вами завтра! А пока напишите в комментариях свои догадки
😉
⬇️ | https://t.me/simplebestbiochemistry/428?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,300 | 0 | 1,726,044,884 | 1,736,456,942 | 1,112 | 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| [{"ner":"ГЛИЦИН","lemma":"глицин","label":"ORG","start_pos":0,"end_pos":6},{"ner":"ЦНС","lemma":"цнс","label":"ORG","start_pos":408,"end_pos":411},{"ner":"ЦНС","lemma":"цнс","label":"ORG","start_pos":1147,"end_pos":1150},{"ner":"2","lemma":"2","label":"NUM","start_pos":130,"end_pos":131},{"ner":"2","lemma":"2","label":"NUM","start_pos":136,"end_pos":137},{"ner":"1","lemma":"1","label":"NUM","start_pos":442,"end_pos":443},{"ner":"1","lemma":"1","label":"NUM","start_pos":514,"end_pos":515},{"ner":"2","lemma":"2","label":"NUM","start_pos":521,"end_pos":522},{"ner":"3","lemma":"3","label":"NUM","start_pos":528,"end_pos":529},{"ner":"2","lemma":"2","label":"NUM","start_pos":668,"end_pos":669}] | NEUTRAL | rus | NOT SPAM | 188 | 0 | 18 | 0.967213 | 0.032787 | 0 | 18 | 21 | 8 | 3 | 53 | 9 | 44 | true |
118 | null | ОТКУДА ГЛИЦИН В ЦНС?
Друзья, в посте выше
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мы узнали с вами, что глицин - ключевая тормозная аминокислота в ЦНС, однако ГЭБ непроницаем для данной аминокислоты. Ни пассивная диффузия, ни белки транспортеры не имеют возможности перемещать глицин в нейрональную ткань.
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Есть ли в этом смысл и откуда тогда берется глицин в ЦНС?
Да, смысл чрезвычайно огромен. Поскольку глицин обладает тормозным действием, его содержание в синаптической щели строго регулируется. Если бы ГЭБ был полностью проницаем для глицина, то тогда после каждого приема белковой пищи мы бы получали тотально торможение ЦНС, поскольку глицин содержится во всех пищевых белках.
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Как нейроны синтезируют глицин?
Наиболее точный ответ дала Олеся Матвеева
@almatveeval
💪🏻
, правильно уточнив, что аминокислота глицин синтезируется в клетках астроцитах из аминокислоты серина.
Астроциты - вспомогательные клетки нервной системы, выполняющие трофическую функцию и имеющие фермент -
серингидроксиметилтрансферазу
- которая ответственна за превращение аминокислоты серин в глицин.
🔥
Кстати, тетрагидрофолат (витамин В9) является коферментом данного фермента и необходим для протекания данной реакции. Саму реакцию вы можете увидеть в начале данного поста
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А вы пьете глицин?
😇 | https://t.me/simplebestbiochemistry/429?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,300 | 0 | 1,726,213,414 | 1,736,456,942 | 1,112 | 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| [{"ner":"ОТКУДА ГЛИЦИН","lemma":"откуда глицин","label":"ORG","start_pos":0,"end_pos":13},{"ner":"ЦНС","lemma":"цнс","label":"ORG","start_pos":16,"end_pos":19},{"ner":"ЦНС","lemma":"цнс","label":"ORG","start_pos":110,"end_pos":113},{"ner":"ЦНС","lemma":"цнс","label":"ORG","start_pos":324,"end_pos":327},{"ner":"ЦНС","lemma":"цнс","label":"ORG","start_pos":592,"end_pos":595},{"ner":"Олеся Матвеева","lemma":"олеся матвеев","label":"PER","start_pos":710,"end_pos":724},{"ner":"9","lemma":"9","label":"NUM","start_pos":1082,"end_pos":1083}] | NEUTRAL | rus | NOT SPAM | 177 | 0 | 11 | 0.995536 | 0.004464 | 0 | 24 | 21 | 7 | 0 | 54 | 11 | 30 | true |
118 | null | ☀️
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СЮДА | https://t.me/ychemistry/938?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 1,800 | 0 | 1,719,482,539 | 1,736,456,942 | 1,111 | 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| [{"ner":"Начни","lemma":"начать","label":"PER","start_pos":62,"end_pos":67},{"ner":"ФИПИ","lemma":"фипи","label":"ORG","start_pos":330,"end_pos":334},{"ner":"СЮДА","lemma":"сюда","label":"ORG","start_pos":432,"end_pos":436},{"ner":"2","lemma":"2","label":"NUM","start_pos":136,"end_pos":137}] | NEUTRAL | rus | NOT SPAM | 65 | 0 | 5 | 1 | 0 | 0 | 11 | 5 | 1 | 2 | 23 | 3 | 11 | true |
118 | null | Серебро. Так ли оно полезно?
👽
Наверняка вы вспомните, как бабушки и дедушки клали в кувшин с водой
ложки, кольца и другие серебряные изделия
, чтобы
обеззаразить
воду и придать ей
целебные
свойства. Попробуем выяснить, насколько этот метод является
эффективным
🍶
Серебро — драгоценный металл
, которому уже давно было найдено применение в
медицине
. До середины прошлого века
нитрат серебра AgNO₃
использовался в качестве наружного
антисептика
под названием
ляпис
. Было обнаружено, что
небольшие
его концентрации
подавляют
жизнедеятельность микробов, прижигают рану и устраняют воспаления.
Концентрированные
растворы представляют
опасность
, так как способны вызвать глубокий химический
ожог
😰
Эти свойства обусловлены
разложением нитрата серебра
на свободное серебро Ag, оксид азота NO₂ и молекулярный кислород O₂.
Однако в настоящее время ляпис
почти не используется из-за своей токсичностью
. Ему на смену быстро пришли более эффективные антисептики
💊
Другой интересной с медицинской точки зрения формой серебра является
коллоидный раствор
, то есть
мельчайшие частицы серебра
размером от 1 нанометра,
равномерно распределенные в воде
. Такой раствор является своеобразным
генератором ионов серебра
, потому что частички металла постепенно окисляются кислородов воздуха и переходят в растворимую форму.
Было установлено, что гарантированно
убивать
некоторые бактерии способны растворы с концентрацией ионов серебра
свыше 150 мкг/л
, что
в три раза больше предельно допустимой концентрации
для человека... Получается, что концентрированные растворы могут не только расправиться с микробами, но и нанести ощутимый
вред нашему организму
🦠
Более того,
серебро — это ядовитый тяжёлый металл
, никак не участвующий в метаболизме и способный накапливаться в органах. При длительном поступлении в организм избыточных доз серебра развивается
аргирия (аргироз)
— болезнь, при которой
кожа принимает серебристый или синевато-серый оттенок
😨
Получается, что
риск подвергнуться токсическому воздействию серебра превышает возможную антибактериальную эффективность
. Поэтому распространение коллоидных серебряных продуктов
регулируется
, а препараты на его основе назначаются лишь в
исключительных случаях
🔬
Но спешу обрадовать
. Серебряная ложка, залегающая на дне кувшина,
никогда не поднимет
концентрацию ионов серебра в воде до значимого уровня
🍴
Поэтому вреда от такой воды никакого. Ровно, как и пользы
И напоследок предлагаю взглянуть на главный симптом аргироза — сине-фиолетовую пигментация. Вот к чему приводит накопление серебра в организме
⬇️ | https://t.me/ychemistry/939?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 1,900 | 0 | 1,719,486,122 | 1,736,456,942 | 1,111 | 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118 | null | Что такое октановое число?
🚘
Автолюбители и просто читатели, проезжавшие мимо заправок, вы задумывались над тем,
что значат числа на электронном табло?
И я сейчас не о постоянно растущих ценах на бензин, а о загадочных номерах 80, 92, 95 и далее по списку. Эти числа обозначают
октановое число
данной марки бензина, и сейчас мы разберемся, что за ним скрывается
🚀
Вопреки распространённому заблуждению, числа на электронном табло заправочных станций
не говорят напрямую о качества состава топлива.
Бензин, независимо от марки, должен быть чистым, прозрачным, обеспечивать лёгкость запуска мотора, не содержать откровенной отравы и давать в меру токсичный выхлоп. Большинство параметров, включая содержание примесей, для любого бензина одинаково и
строго контролируется официальными документами.
Но одним из важнейших свойств топлива является
детонационная стойкость — способность воспламеняться и сгорать в цилиндрах двигателя без нежелательных взрывных процессов
💥
Именно детонационную стойкость характеризует октановое число.
За эталон детонационной устойчивости принята смесь органических соединений —
изооктана и н-гептана
, причем этих веществ
почти не содержится в самом бензине
. Устойчивость изооктана равна
100
единиц, а н-гептана —
0
. То есть если бензин имеет октановое число, равное
92
, то он детонирует так же, как смесь из
92
частей изооктана и
8
частей гептана. Это как взвешивать колбасу на весах с гирями — мы определяем массу куска по количеству гирь, при этом самих гирь в колбасе не содержится, они выступают в качестве эталона массы
⚖️
Вот только октановое число не получится определить так же легко, как массу или содержание примесей. Это связано с тем, что
реальное топливо не является смесью изооктана и гептана
, поэтому результаты определения зависят от метода — октановые числа можно измерять в лабораторных установках или на реальных автомобилях в процессе езды. Данный анализ является довольно-таки
затратным
по всем параметрам
🤔
Бензин с более высоким октановым числом может выдержать более высокую степень сжатия без досрочного самовоспламенения —
детонации
.
Чем она опасна?
Быстрое сгорание бензина в цилиндрах создает волны давления, которые отражаются от стенок и создают характерный «стук» — металлический звон. Такой процесс
снижает мощность двигателя и ускоряет его износ
. При возникновении сильных детонационных волн двигатель может быть даже
поврежден или разрушен
. Поэтому производители добавляют в топливо специальные присадки, которые увеличивают его устойчивость при сжатии, а так же используют более современные методы переработки нефти
⚙️
Если вы желаете услышать, какой бензин заливать, то
универсального ответа нет
. В первую очередь следует учитывать рекомендации производителя автомобилей. Для
мощных двигателей
применяют исключительно бензин с высокими октановыми числами
🏎
Если залить в него топливо с меньшей устойчивостью, будет сильная детонация и мотор быстро выйдет из строя. В
простые машины
заливать высоко-октановое топливо не имеет смысла
🚗
Расход если и упадет, то незначительно, а лучше машина ехать точно не станет.
И напоследок хочу отметить, что октановое число используется при характеристике
бензина
. Для
дизельного
и
газообразного
топлива используются
цетановое
и
метановые
числа соответственно. Там действуют совершенно иные характеристики воспламеняемости.
Что хорошо для бензинового мотора, для дизеля категорически противопоказано.
Как говорится — каждому своё
😉 | https://t.me/ychemistry/940?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 1,800 | 0 | 1,719,583,027 | 1,736,456,942 | 1,111 | 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| [{"ner":"80","lemma":"80","label":"NUM","start_pos":227,"end_pos":229},{"ner":"92","lemma":"92","label":"NUM","start_pos":231,"end_pos":233},{"ner":"95","lemma":"95","label":"NUM","start_pos":235,"end_pos":237},{"ner":"100","lemma":"100","label":"NUM","start_pos":1216,"end_pos":1219},{"ner":"0","lemma":"0","label":"NUM","start_pos":1242,"end_pos":1243},{"ner":"92","lemma":"92","label":"NUM","start_pos":1297,"end_pos":1299},{"ner":"92","lemma":"92","label":"NUM","start_pos":1340,"end_pos":1342},{"ner":"8","lemma":"8","label":"NUM","start_pos":1362,"end_pos":1363}] | NEUTRAL | rus | NOT SPAM | 489 | 0 | 4 | 1 | 0 | 0 | 67 | 68 | 20 | 12 | 147 | 31 | 72 | true |
118 | null | Термитная смесь. Пламя, которое не потушишь
🔥
Сегодня я хочу рассказать вам об одной «
горячей штучке
». Несмотря на то, что вы вряд ли встретите её в быту, она находит большое применение в некоторых отраслях промышленности. И если вы подумали, что
термитная смесь
— это солянка из насекомых-вредителей, то вам точно стоит прочитать этот пост
🐜
Термитная смесь — это смесь порошков алюминия Al с оксидами различных металлов
(обычно используются опилки оксида железа Fe₃O₄).
Что же в ней необычного?
Дело в том, что при поджигании она интенсивно сгорает с выделением
большого количества тепла
— температура горения составляет
2300—2700 °C
. А в случае применения других оксидов, например никеля Ni, хрома Cr или вольфрама W, температура
превышает 3500 °C
.
Нехило, правда?
🤯
Такое колоссальное количество теплоты выделяется в ходе простейшей реакции: Al + Fe₃O₄ → Al₂O₃ + Fe. Алюминий, как более активный металл, вытесняет железо из его оксида — в результате мы получаем
раскаленную смесь плавящихся металлов
💥
Поджигают термит обычно специальным запалом — смесью окислителей, например пероксида бария, магния и натрия. Эти вещества при небольшом нагревании разлагаются и
инициируют неконтролируемый процесс горения
термита.
Термитная смесь обладает рядом
интересных свойств
:
• Она способна гореть без присутствия кислорода
🔥
• Её невозможно потушить водой. Попробуйте представить, что будет с водой, если её мгновенно нагреть до температуры 3000°C
💨
• Термит обладает чрезвычайно сильным прожигающим действием — в расплавленном виде он легко делает дырки в листах дюраля, стали и железа. Более того, при такой температуре растрескивается бетон, кирпич и плавится стекло
😱
А теперь о
применении
. Главная сфера использования — это
термитная сварка
. Например, термит широко используют
для сварки рельсов
железных дорог России — такой способ сварки не требует дорогостоящего оборудования и не требует большого количества времени
🚂
Также с помощью термитной сварки соединяют телефонные кабели, провода и небольшие трубы. В
металлургии
термит используется для получения сплавов железа, в
пиротехнике
— для создания осветительных смесей. Термитные смеси также добавляли в зажигательные снаряды для поражения техники противника
🚀
Вот такой горячий пост сегодня получился
🔥 | https://t.me/ychemistry/941?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,100 | 0 | 1,719,647,563 | 1,736,456,942 | 1,112 | 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6 | 110 | 22 | 58 | true |
118 | null | Концентрированная серная кислота известна тем, что обугливает органику.
Предлагаем вам насладиться этой зрелищной реакцией. В данном случае сахар превращается в углерод и воду. | https://t.me/chemistrytg2021/9439?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,734,103,201 | 1,736,456,943 | 1,112 | 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| null | NEUTRAL | rus | NOT SPAM | 23 | 0 | 1 | 1 | 0 | 0 | 5 | 4 | 2 | 0 | 7 | 0 | 4 | true |
118 | null | 28 ноября 2024 г. состоится бесплатный вебинар журнала Molecules (MDPI), посвященный редокс-активным соединениям в контексте биомедицинских исследований.
Программа вебинара:
Prof. Gregory Giles
Modulation of Reactive Nitric Oxide in Drug Discovery: Photoresponsive Systems for Precision Control
Prof. Cecilia Battistelli
Selenotriazines: A Path to Neuroprotection and Treatment of Alzheimer's Disease
Dr. Ahmad Yaman Abdin
Panel Discussion
Подробная информация и регистрация на вебинар по ссылке:
https://sciforum.net/event/Molecules-35
#семинар | https://t.me/chemrussia/5062?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,600 | 0 | 1,732,600,885 | 1,736,456,943 | 1,111 | 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| [{"ner":"Molecules (MDPI)","lemma":"molecules (mdpi)","label":"ORG","start_pos":55,"end_pos":71},{"ner":"Gregory Giles\nModulation of Reactive Nitric Oxide in Drug Discovery","lemma":"gregory giles\nmodulation of reactive nitric oxide in drug discovery","label":"ORG","start_pos":180,"end_pos":247},{"ner":"Cecilia Battistelli\nSelenotriazines","lemma":"cecilia battistelli\nselenotriazines","label":"ORG","start_pos":301,"end_pos":336},{"ner":"Ahmad Yaman Abdin\nPanel Discussion","lemma":"ahmad yaman abdin\npanel discussion","label":"ORG","start_pos":405,"end_pos":439},{"ner":"28 ноября 2024","lemma":"28 ноября 2024","label":"DATE","start_pos":0,"end_pos":14},{"ner":"2024","lemma":"2024","label":"NUM","start_pos":10,"end_pos":14},{"ner":"35","lemma":"35","label":"NUM","start_pos":534,"end_pos":536}] | NEUTRAL | other | SPAM | 64 | 0 | 2 | 0.561798 | 0.438202 | 0 | 7 | 2 | 0 | 0 | 15 | 0 | 12 | true |
118 | null | А вот пример синтеза конкретных заменимых аминокислот из их кетоаналогов (те самые органические кислоты из анализа)
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Кто участвовал в курсе по обмену углеводов, узнаете путь окисления глюкозы?
😉 | https://t.me/simplebestbiochemistry/426?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,000 | 0 | 1,725,860,276 | 1,736,456,943 | 1,112 | 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| null | NEUTRAL | rus | NOT SPAM | 29 | 0 | 1 | 1 | 0 | 0 | 3 | 3 | 1 | 0 | 12 | 0 | 5 | true |
118 | null | Как исследуют реальные объекты?
🔬
Вполне очевидно, как проводятся эксперименты с
лабораторными реактивами
— просто берём раствор в баночке с полки и смешиваем его в колбе с другим реактивом
🧪
Но проблема возникает, когда речь заходит о
реальных объектах
. Вы вряд ли что-то сможете определить, засунув кусок
торта
, ломтик
колбасы
или горсть
земли
в пробирку
🍰
Чтобы провести анализ, необходимо перевести объект в подходящую форму
, и обычно такой формой является
раствор
. Причем необходимо учитывать, желаем мы определить
конкретный элемент
(содержание
серы S
в нефтепродуктах),
соединение
(примесь
метанола CH₃OH
в этиловом спирте) или целую
группу веществ
(общая
кислотность
вина), потому что часть из них может улетучиваться в виде газов, реагировать между собой с образованием побочных продуктов или распадаться вовсе
⚗️
Проще говоря, способ разложения выбирается индивидуально для решения конкретной химической задачи.
Главное — перевести в раствор
все
определяемые компоненты и не допустить их потерь
👩🏻🔬
Издавна способы разложения пробы делятся на
«сухие»
🔥
и
«мокрые»
💧
Под
«мокрыми»
методами разложения понимается растворение пробы в растворителях, преимущественно
в кислотах и их смесях
при нагревании. Идеальным вариантом является чистая вода, но зачастую вещество не будет растворяться в ней
💦
Например, многие
сульфидные руды
растворяют при нагревании в
соляной кислоте HCl
с добавлением
азотной HNO₃
. Зачастую добавляют
окисляющие реагенты
(перекись водорода, бром и др.), которые ускоряют процесс растворения и переводят вещество в удобную для анализа форму. Избежать потерь серы в виде газа сероводорода H₂S при анализе серосодержащих руд можно с помощью концентрированной азотной кислоты и брома, которые сразу окисляют сульфиды до сульфатов
💥
Мокрый способ
разложения используется при определении
содержания белков в пищевых продуктах методом Кьельдаля
. Например, овсяную или гречневую крупу растворяют в концентрированной серной кислоте с добавлением катализатора и при нагревании. И только после разложения пробы проводят анализ
🍪
Для растворения
полимерных
материалов используют
органические
растворители: спирты, эфиры, жидкие углеводороды и хлорорганику
🧽
«Сухие»
способы разложения используются
реже
— в тех случаях, когда проба не растворяется или содержит сложные органические примеси. В таких ситуациях пробу прокаливают над пламенем горелки, в муфельной печи или токе кислорода. Зачастую для вскрытия пробы используются различные твёрдые плавни (например, карбонат и пиросульфат натрия) и добавляются окислители (нитраты и хлораты)
🌡
Внимательно нужно относиться к
выбору посуды
для сухого разложения. Сплавление необходимо проводить в
тугоплавких
керамических, графитовых или платиновых тиглях. При щелочном разложении нельзя использовать стеклянную или керамическую посуду, потому что входящие в её состав
оксиды кремния SiO₂
будут
постепенно растворяться в щелочи
😱
Современное оборудование позволяет проводить разложение пробы в герметичных сосудах — автоклавах
. Использование автоклавов позволяет
избежать улетучивания и разбрызгивания
компонентов, а также ускорить сам процесс минерализации, потому что разложение протекает при высоком давлении (10-20 атмосфер)
🧭
Всё шире и шире используется современное оборудование для минерализации реальных объектов —
специальные микроволновые печи
. Принцип работы у них такой же, как у бытовых микроволновок, только размер и мощность побольше. По сравнению с традиционными лабораторными методами разложения,
использование микроволновых минерализаторов ускоряет процесс почти в 20 раз
⏳ | https://t.me/ychemistry/936?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 1,800 | 0 | 1,719,397,233 | 1,736,456,943 | 1,111 | 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