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118 | null | Эмульгаторы. Для чего их добавляют в продукты?
🥛
Лецитин, сорбит, гуаровая или ксантовая камедь
... Вы наверняка встречали эти компоненты
в составе продуктов питания или косметических средств
. Сегодня мы выясним,
что скрывается за загадочными названиями
👩🏻🔬
Одними из самых популярных
пищевых добавок
являются
эмульгаторы — вещества, обеспечивающие создание эмульсии из несмешивающихся жидкостей
🚰
Что же такое эмульсия?
Если
по-научному
, то
эмульсия
— это дисперсная система, то есть смесь из нескольких жидкостей,
не способных раствориться друг в друге
или химически взаимодействовать, а потому сохраняющихся в виде
мельчайших капель
💦
А если
по-бытовому
, то
эмульсия
— это однородная смесь воды и жидкостей (масло, жир), которые
не растворяются
в воде
🍺
Проще всего эмульсию представить и понять на примере
молока
— самой распространённой природной эмульсии
🐄
В молоке
капли молочного жира равномерно распределены в воде
. Если оценивать эмульсию невооружённым взглядом, то такая система не отличается от однородной жидкости, потому что капли нерастворённого вещества имеют
микроскопический размер
🔬
А теперь давайте сами приготовим эмульсию
. Добавим к стакану воды чуть поменьше стакан растительного масла. Как бы мы не старалась и не перемешивали нашу смесь, она останется двухфазной:
слой масла будет находиться над слоем воды
🥃
И вот тут нам помогут эмульгаторы
. Добавляя верно подобранный эмульгирующий компонент при постоянном перемешивании, мы можем добиться
однородной
жидкой смеси, в которой
масло равномерно распределено в воде
👍🏻
Сами по себе эмульгаторы выполняют роль
поверхностно-активных веществ
, которые
уменьшают поверхностное натяжение
на границе раздела масла и воды. Благодаря этому слой масла разделяется на
множество мельчайших капель
и равномерно распределяется в воде
💧
В том же молоке
помимо воды и молочного жира
присутствует третий компонент —
комплекс белка и лецитина
, — который выступает в роли эмульгатора и отвечает за привычную консистенцию
🥛
В промышленных масштабах эмульгаторы получают как из
природного
сырья
🌱
, так и
синтетическим
путём
🧪
Например,
пектин
, используемый в производстве десертов, майонеза и молочных продуктов, получают из яблочных и цитрусовых выжимок
🍏
Лецитин
, добавляемый к шоколаду и выпечке, получают из соевого масла, а различные
полисорбаты
— из кокосового и пальмового
🥥
К синтетическим эмульгаторам относятся
производные жирных кислот, глицерина и продукты их этерификации
⚗️
Помимо продуктов питания, эмульгаторы являются
неотъемлемым компонентом косметики и лекарственных препаратов
— они позволяют делать жидкие смеси из тех компонентов, которые сами по себе не смешиваются друг с другом
💄
💊
Не стоит бояться натуральных эмульгаторов
в пищевых изделиях — большинство из них не несут никакого вреда, за исключением случаев индивидуальной непереносимости. Синтетические эмульгаторы наш организм воспринимает
аналогично натуральным
, поэтому они
безопасны
в тех количествах, в которых их добавляют к продуктам питания
😉 | https://t.me/ychemistry/937?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 1,800 | 0 | 1,719,475,380 | 1,736,456,943 | 1,111 | 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| [{"ner":"Лецитин","lemma":"лецитин","label":"PER","start_pos":49,"end_pos":56}] | NEUTRAL | rus | NOT SPAM | 429 | 0 | 7 | 1 | 0 | 0 | 57 | 55 | 28 | 2 | 125 | 26 | 61 | true |
118 | null | Ремонт стены 3D-ручкой.
Основные материалы, используемые в работе 3D-ручек нагревательного типа, — пластики ABS и PLA.
Пластик ABS
В основе полимера ABS — соединения, получаемые из нефти. Он не подвержен разложению, очень прочен и поэтому стал наиболее распространённым материалом для 3D-печати.
Пластик PLA — органический, биоразлагаемый полилактид, произведенный на основе сахарного тростника или кукурузы. | https://t.me/chemistrytg2021/9437?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,200 | 0 | 1,734,081,600 | 1,736,456,953 | 1,111 | 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| [{"ner":"ABS","lemma":"abs","label":"ORG","start_pos":108,"end_pos":111},{"ner":"PLA","lemma":"pla","label":"ORG","start_pos":114,"end_pos":117},{"ner":"PLA","lemma":"pla","label":"ORG","start_pos":304,"end_pos":307},{"ner":"3","lemma":"3","label":"NUM","start_pos":13,"end_pos":14},{"ner":"3","lemma":"3","label":"NUM","start_pos":66,"end_pos":67},{"ner":"3","lemma":"3","label":"NUM","start_pos":285,"end_pos":286}] | NEUTRAL | rus | NOT SPAM | 54 | 0 | 9 | 0.893333 | 0.106667 | 0 | 7 | 5 | 1 | 0 | 20 | 3 | 14 | true |
118 | null | Nescafe + Пероксид натрия + Молоко
Категорически запрещено повторять эксперимент в домашних условиях! | https://t.me/chemistrytg2021/9438?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,200 | 0 | 1,734,092,400 | 1,736,456,953 | 1,111 | 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118 | null | Новый учебник по неорганической химии
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В издательстве "Лаборатория знаний" вышел новый учебник
"Современная неорганическая химия"
под редакцией член-корр. РАН А.В. Шевелькова.
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Коллектив авторов - сотрудники кафедры неорганической химии с многолетним опытом преподавания неорганики - А.А. Дроздов, В.П. Зломанов, Ф.М. Спиридонов, Г.Н. Мазо, М.Е. Тамм, А.В. Шевельков.
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В основу двухтомника положен легендарный трехтомник под редакцией академика Ю. Д. Третьякова, структура которого претерпела существенные изменения с учетом современного развития неорганической химии. В первом томе изложены физико-химические основы неорганической химии и систематизирована химия непереходных элементов. Второй том посвящен химии переходных элементов.
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Учебник предназначен для студентов высших учебных заведений, обучающихся по основным образовательным программам высшего образования уровня бакалавриата и специалитета по направлениям подготовки 04.03.01 «Химия», 04.03.02 «Химия, физика и механика материалов» и специальности 04.05.01 «Фундаментальная и прикладная химия». | https://t.me/chemrussia/5061?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,400 | 0 | 1,732,600,832 | 1,736,456,953 | 1,111 | 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118 | null | #органика
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| [{"ner":"04-17","lemma":"04-17","label":"DATE","start_pos":46,"end_pos":51},{"ner":"17","lemma":"17","label":"NUM","start_pos":49,"end_pos":51}] | NEUTRAL | eng | NOT SPAM | 2 | 0 | 0 | 0.75 | 0.25 | 0 | 0 | 0 | 0 | 0 | 1 | 0 | 1 | true |
118 | null | #неорганика
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| [{"ner":"04-23","lemma":"04-23","label":"DATE","start_pos":73,"end_pos":78},{"ner":"23","lemma":"23","label":"NUM","start_pos":76,"end_pos":78}] | NEUTRAL | eng | NOT SPAM | 2 | 0 | 0 | 0.75 | 0.25 | 0 | 0 | 0 | 0 | 0 | 1 | 0 | 1 | true |
118 | null | Пишите правильные ответы в комментарии
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| null | NEUTRAL | rus | NOT SPAM | 7 | 0 | 0 | 1 | 0 | 0 | 1 | 1 | 0 | 0 | 2 | 0 | 1 | true |
118 | null | СИНТЕЗ АМИНОКИСЛОТ ИЗ ГЛЮКОЗЫ
Как вы прекрасно знаете, глюкоза - основной энергетический источник для всех клеток нашего организма, но часто для учеников становится открытием, что промежуточные продукты окисления глюкозы являются субстратом для синтеза почти всех заменимых аминокислот.
Если быть даже более точным, то именно органические кислоты, которые образуются в процессе сгорания глюкозы, далее используются, как углеводородный скелет для синтеза аминокислот.
Например:
✅
Пировиноградная кислота (пируват) превращается в
аланин
;
✅
Щавелевоуксусная кислота (оксалоацетат) превращается в
аспартат
, а далее в
аспарагин
;
✅
Альфа-кетоглутаровая кислота превращается в
глутамат
, который далее может идти на синтез
глутамина
,
аргинина
и
пролина
;
⚡️
Ферменты, которые катализируют данные реакции синтеза аминокислот называются трансаминазами, а их коферментом является витамин Б6 - пиридоксальфосфат.
Более полно и подробно мы будем разбирать данный материал на большом курсе по обмену белков и аминокислот, но уже сейчас вы знаете ключевой механизм - продукты распада глюкозы, идут на синтез заменимых аминокислот.
Вот такая вот уникальная глюкоза
🔥 | https://t.me/simplebestbiochemistry/425?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,200 | 0 | 1,725,786,899 | 1,736,456,953 | 1,112 | 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| [{"ner":"СИНТЕЗ","lemma":"синтез","label":"ORG","start_pos":0,"end_pos":6},{"ner":"АМИНОКИСЛОТ","lemma":"аминокислот","label":"ORG","start_pos":7,"end_pos":18},{"ner":"ГЛЮКОЗЫ","lemma":"глюкозы","label":"ORG","start_pos":22,"end_pos":29},{"ner":"6","lemma":"6","label":"NUM","start_pos":883,"end_pos":884}] | NEUTRAL | rus | NOT SPAM | 158 | 0 | 5 | 1 | 0 | 0 | 16 | 18 | 6 | 0 | 54 | 14 | 28 | true |
118 | null | Вся правда о пищевых добавках
То, что сегодня практически в каждом продукте
🥙
находятся добавки ни для кого не секрет. Большинство людей больше не обращает внимания на то, есть ли в составе E621. Для тех, кто не знает, именно так обозначается популярная добавка глутамат натрия.
E621 - это глутаминовая кислота, которая относится к 20 природным аминокислотам, из которых построен наш организм. Она присутствует не только в животном белке
🐔
, но и в растительном
🍌
. Например, в орехах и кукурузе
🌽
содержат до 2% глутамата!
Если вы хоть раз ели пищу
🍔
🍟
🍕
с данной добавкой, то отвыкнуть от неё будет не так уж и просто. Всё дело в том, что присутствие глутамата в еде усиливает вкус. Именно поэтому продукты с E621 хочется есть снова и снова. К примеру, употребляя чипсы с избытком глутамата, вы приучаете свой язык к высоким дозам "вкусности"
😋
. Обычная картошка после этого покажется пресной. Большинство взрослых людей способны силой воли отказаться от пищевого "наркотика": избытка сахара, соли и глутамата. А вот ребенок может привыкнуть к чипсам и газировке. В последствии такая "диета" может серьёзно навредить желудку.
Признаюсь честно, я до сих пор завишу от чипсов. Понимаю, что это вредно, но просто не могу отказаться от любимого лакомства
🍟
.
Это вещество для нашего языка
👅
- основой носитель пятого вкуса - "умами" - вкуса белка и мяса. По аналогии: хлорид натрия - "поставщик" соленого
🌭
, глюкоза - сладкого
🍬
, кислоты - кислого
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, а алкалоиды - горького вкусов.
До сих пор мнения учёных по этому поводу двоякое. Никаких "повреждений мозга" от употребления глутамата натрия у вас не будет. Иначе придется признать, что также наш мозг многие тысячелетия повреждают кукуруза
🌽
и бананы
🍌
! С другой стороны, обманывать свои рецепторы тоже неправильно.
Поэтому в следующий раз, когда найдете глутамат (Е620) в пище - не пугайтесь! В отличие от красителей и многих других добавок, он безвреден. Просто питайтесь сбалансировано и всё будет хорошо. Если есть возможность не брать такой продукт, лучше не берите. | https://t.me/ychemistry/934?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 1,800 | 0 | 1,719,219,139 | 1,736,456,953 | 1,113 | 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| [{"ner":"🍋","lemma":"🍋","label":"ORG","start_pos":1449,"end_pos":1450},{"ner":"621","lemma":"621","label":"NUM","start_pos":191,"end_pos":194},{"ner":"621","lemma":"621","label":"NUM","start_pos":280,"end_pos":283},{"ner":"20","lemma":"20","label":"NUM","start_pos":332,"end_pos":334},{"ner":"2","lemma":"2","label":"NUM","start_pos":510,"end_pos":511},{"ner":"621","lemma":"621","label":"NUM","start_pos":712,"end_pos":715},{"ner":"620","lemma":"620","label":"NUM","start_pos":1821,"end_pos":1824}] | NEUTRAL | rus | NOT SPAM | 333 | 0 | 9 | 0.992974 | 0.007026 | 0 | 30 | 40 | 18 | 4 | 98 | 21 | 70 | true |
118 | null | Какие бывают ткани?
🧶
Текстильная
промышленность является ярким примером использования химических знаний для решения бытовых проблем.
Сегодня мы разберёмся вместе с вами, из чего шьют одежду
👚
Все текстильные волокна делятся на
три большие группы
:
Натуральные волокна
используются с древнейших времён и хорошо нам знакомы. Из
растительного сырья
производят
хлопок, лён, пеньку и джут
🌿
Волокна
животного
происхождения представлены
шерстью и натуральным шёлком
🐏
И существуют
минеральные
волокна, к которым относится
асбест
— собирательное название нескольких минералов, образующих тончайшие гибкие нити. Из асбеста изготавливают огнеупорные ткани, кровельные и строительные материалы
🔥
К сожалению,
асбестовая пыль является сильнейшим канцерогеном
— она повышает вероятность появления злокачественных опухолей при попадании в дыхательные пути. Поэтому изделия из асбеста в разных странах
запрещены или частично, или полностью
. В России разрешено около трёх тысяч видов продукции из наиболее безопасного асбестового минерала —
хризотила
. В них асбест находится в связанном состоянии с полимерами, цементом или смолой, поэтому
безопасен
👩🏻🔬
К
химическим волокнам
относят волокна, получаемые в заводских условиях. Из разделяют на
искусственные и синтетические
.
К
искусственным
относят волокна на основе целлюлозы и ее производных. Например,
вискозу
вырабатывают из целлюлозы, полученной из древесины ели, пихты или сосны. После химической обработки целлюлозы (
обработка сероуглеродом в щелочной среде
) из неё формируют тонкие нити, пропуская через специальные аппараты со множеством мелких отверстий —
фильеры
. Из вязкой жидкости мы получаем тонкие нити вискозы. Ткани из вискозы хорошо впитывают воду и пропускают воздух, отличаются высокой прочностью и мягкостью, а благодаря характерному блеску порой ассоциируются с искусственным шёлком
👗
К
искусственным
также относятся
ацетатные и триацетатные волокна
, получаемые из обработанного уксусной кислотой хлопка. Ацетатные волокна менее распространены из-за ряда недостатков: высокая электризуемость, низкая устойчивость к истиранию и высоким температурам
🌡
Синтетические
волокна получают путём
синтеза из низкомолекулярных продуктов
переработки нефти, каменного угля и природного газа (
фенол, этилен, ацетилен, метан
). На выходе образуются длинные цепочки
полимеров
🧬
К тканям из
синтетических
волокон относятся
нейлон, капрон, лавсан, акрил, лайкра, спандекс и многие другие
🧵
Капрон
обладает высокой прочностью, эластичностью и,
в отличие от натурального шёлка
, не гниёт и не слёживается. Благодаря этому капрон пришёл на смену шёлку в производстве
парашютов
. Нейлон и лавсан используются не только в качестве тканей — модифицированные волокна используются в машиностроении, производстве техники и пластиковой тары
⚗️
Большинство синтетических волокон зарегистрировано под
своими торговыми названиями
. Каждый вид представлен несколькими модификациями для устранения определенных недостатков и решения конкретных производственных задач
👀
Поэтому
не стоит пугаться непривычных названий в составе ткани
при выборе одежды. Как мы выяснили,
многие химические волокна по своим свойствам превосходят натуральные
. Надпись
«хлопок 100%»
уже давно
не является гарантом высочайшего качества
. Большинство дешёвых хлопковых изделий изготавливается из низкокачественных продуктов переработки
🧦
Только правильное сочетание натуральных, искусственных и синтетических волокон оправдает ваши ожидания от новой одежды
👍🏻 | https://t.me/ychemistry/935?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 1,800 | 0 | 1,719,301,808 | 1,736,456,953 | 1,112 | 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118 | null | Трииодит азота (NI3) - соединение азота и йода, в сухом виде представляет собой чрезвычайно активное вещество, которое взрывается от прикосновения. | https://t.me/chemistrytg2021/9435?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,100 | 0 | 1,734,027,600 | 1,736,456,954 | 1,133 | 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118 | null | Термическое поведение и электропроводность винил- и алкилимидазолиевых цвиттер-ионов
Международный коллектив ученых из Института химии растворов им. Г.А. Крестова РАН и Вьетнамского национального университета (Вьетнам, Ханой) изучили термическое поведение и электропроводность винил- и алкилимидазолиевых цвиттер-ионов, содержащих алкан-сульфокислотную группу, и солей на их основе. Выявлено, что температуры плавления цвиттер-ионов и солей с винилимидазолиевым катионом выше, чем у соединений с алкильным катионом. Большинство ионных жидкостей с алкан-сульфокислотной группой менее стабильны, чем соответствующие цвиттер-ионы. При охлаждении функционализированные ионные жидкости стеклуются, а соли, содержащие нефункционализированный катион, кристаллизуются при температурах ниже 100°C. Функционализация катиона 1-винилимидазолия приводит к значительному снижению электропроводности солей.
Результаты исследования опубликованы в «Journal of Molecular Liquids» и могут быть использованы для создания новых полимерных протон-проводящих электролитов.
L.E. Shmukler, Yu.A. Fadeeva, M.S. Gruzdev, Nguyen Van Thuc, L.P. Safonova. Zwitterionic and vinyl-N-imidazolium ionic liquids. Journal of Molecular Liquids. V. 413. 2024. 125897.
https://doi.org/10.1016/j.molliq.2024.125897
Источник:
ИХР РАН / ISC RAS
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118 | null | 27 ноября 2024 г. в 18:00 мск состоится вебинар Международного золь-гель общества на тему «Микроэмульсии типа «масло в воде» и бинепрерывные эмульсии для синтеза металлических и металлооксидных наночастиц, а также наночастиц и наноструктур на основе координационных полимеров».
Анонс вебинара:
Since first being reported in 1982, the microemulsion reaction method has been employed extensively for the synthesis of a variety of metallic, metal oxide and other inorganic nanoparticles with a narrow size distribution, high specific surface area (SSA) and a good performance in applications such as catalysis. Most of those investigations were based on water-in-oil (w/o) microemulsions. However, the use of w/o microemulsions requires high amounts of solvent, hindering its applications at the industrial scale. Hence, from a practical, environmental, and economical point of view, the possibility of using oil-in-water (o/w) microemulsions may offer advantages, since the major phase is water. Such approach implies the use of organometallic precursors, dissolved in nanometer scale oil droplets (stabilized by surfactant), and dispersed in the continuous aqueous phase; the precipitating agents, which are usually water-soluble, can be added directly to the microemulsion as an aqueous solutions without compromising microemulsion stability. It was reported for the first time as a proof of concept by our group in 2009, and it was demonstrated that small nanoparticles with a narrow size distribution, good crystallinity and high SSA could be obtained. On the other hand, in recent years we also investigated the synthesis of nanomaterials in nonionic bicontinuous microemulsions, resulting in hierarchical superstructures of metal, metal oxide and some hybrid systems.
In this contribution, we present an insight into the most important aspects of the use of microemulsions as confined reaction media, as well as examples of the synthesis of various nanomaterials obtained in O/W and bicontinuous microemulsions carried out by our research group, including nanoparticles, hybrid nanocrystals and hierarchical superstructures. Finally, our latest efforts are being directed towards the synthesis of nanostructured MOFs in both O/W and bicontinuous microemulsions, and we have been able to obtain some nanostructured MOFs of the UiO-66 family at room temperature. The obtained results demonstrate the feasibility of this approach for the preparation of a great variety of nanomaterials with many potential applications, in particular those related with catalysis, photocatalysis, electrocatalysis, SERS substrates and remediation of pollutants, amongst others.
Докладчик - докт. Маргарита Санчес-Домингез, Мексика.
Подключение в Zoom:
https://us02web.zoom.us/j/3072916432?pwd=7QJuTLwRGE99tWC1y1Dapf2qavybTy.1&omn=81115951584
Пароль: 8a9A&79)
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118 | null | 📚
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сайте Центра дополнительного образования в ИОНХ РАН
#обучение #ионх | https://t.me/chemrussia/5059?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,900 | 0 | 1,732,514,420 | 1,736,456,954 | 1,131 | 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118 | null | Добрый день! Новое видео на нашем канале в Дзене! Приглашаю к просмотру и прошу подписаться, это важно для нас!
https://dzen.ru/video/watch/64254ed88927b438d3d3b934?share_to=link | https://t.me/incredible_chemistry/259?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 3,800 | 0 | 1,680,167,150 | 1,736,456,954 | 1,131 | 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118 | null | Добрый день! Опытная версия чат-бота для выдачи случайной статьи по химии готова! Протестировать ее вы можете после перехода в чат этого канала. Там нужно найти бот
@ChemtWikiBot
и ввести /start. Наслаждайтесь! Вопросы, предложения и замечания в чате. Заодно, не забудьте подписаться! | https://t.me/incredible_chemistry/261?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 3,900 | 0 | 1,680,584,867 | 1,736,456,954 | 1,113 | 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| null | NEUTRAL | rus | NOT SPAM | 41 | 0 | 0 | 0.962963 | 0.037037 | 0 | 5 | 7 | 2 | 0 | 16 | 2 | 10 | true |
118 | null | Кадры рабочего процесса! | https://t.me/simplebestbiochemistry/420?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,700 | 0 | 1,725,428,969 | 1,736,456,954 | 1,131 | 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| null | NEUTRAL | rus | NOT SPAM | 3 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 0 | 0 | 2 | 0 | 1 | true |
118 | null | ОБЕЗВРЕЖИВАНИЕ НЕЙРОМЕДИАТОРОВ
С точки
зрения биохимии и физиологии нервной системы, важной задачей является не только синтезировать нейромедиаторы, но еще при этом их быстро обезвреживать и утилизировать.
Почему это важно? Потому что избыток нейромедиатора в синаптической щели приведет к чрезмерному возбуждению нейрона и его повреждению.
За обезвреживание и утилизацию отвечают два ключевых фермента:
1️⃣
Моноаминооксидаза (МАО)
Фермент МАО отщепляет от нейромедиатора аминогруппу -NH2, в результате чего нейромедиатор превращается в другое соединение - альдегид, который уже не возбуждает синаптические рецепторы. А аминогруппа выделяется в виде аммиака NH3.
❗️
Поэтому нервная ткань сама является поставщиком продуктов азотистого обмена - аммиака!
2️⃣
Метил-трансфераза (КОМТ)
Особенностью данного фермента является способность присоединять к нейромедиатору метильную группу - CH3, в результате чего метилированый нейромедиатор уже не выполняет своей функции.
❗️
Кстати донором метильной группы является активная форма метионина -
S аденозин метионин (SAM).
👨⚕️
У всех этих ферментов есть свои коферменты, определенные особенности работы, но их сложно кратко сформулировать в одном посте,
поэтому более подробно и основательно будем разбирать эту тему на большом курсе по обмену белков и аминокислот.
А вам интересна эта тема? | https://t.me/simplebestbiochemistry/423?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,100 | 0 | 1,725,514,094 | 1,736,456,954 | 1,131 | 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| [{"ner":"ОБЕЗВРЕЖИВАНИЕ","lemma":"обезвреживание","label":"ORG","start_pos":0,"end_pos":14},{"ner":"НЕЙРОМЕДИАТОРОВ","lemma":"нейромедиаторов","label":"ORG","start_pos":15,"end_pos":30},{"ner":"Фермент МАО","lemma":"фермент мао","label":"PER","start_pos":432,"end_pos":443},{"ner":"1","lemma":"1","label":"NUM","start_pos":404,"end_pos":405},{"ner":"2","lemma":"2","label":"NUM","start_pos":487,"end_pos":488},{"ner":"3","lemma":"3","label":"NUM","start_pos":660,"end_pos":661},{"ner":"2","lemma":"2","label":"NUM","start_pos":753,"end_pos":754},{"ner":"3","lemma":"3","label":"NUM","start_pos":884,"end_pos":885}] | NEUTRAL | rus | NOT SPAM | 177 | 0 | 14 | 0.97807 | 0.02193 | 0 | 21 | 18 | 9 | 2 | 60 | 13 | 30 | true |
118 | null | Диффузия. Как распространяются запахи?
👃
А еще почему
смешиваются краски
двух разных цветов? Благодаря чему мы
дышим и получаем питательные вещества
из пищи? Как промышленные
отходы попадают в атмосферу и водоёмы
?
Всё это происходит благодаря
диффузии — процессу проникновения молекул одного вещества между молекулами другого
💢
Основной причиной диффузии является
постоянное движение молекул и стремление к равновесию
. Когда в одной области появляется
избыточная
концентрация частиц, молекулы стремятся перейти в области с
меньшей
концентрацией.
Концентрация выравнивается
за счёт взаимного проникновения частиц.
Диффузия может протекать в разных агрегатных состояниях:
газ, жидкость, твёрдое тело
. И в каждой среде
скорость смешивания частиц увеличивается при нагревании
— чем выше температура, тем быстрее движутся частицы
🌡
Также скорость диффузии можно увеличить за счёт
внешнего воздействия
— чтобы сахар быстрее растворился в чае, мы размешиваем его ложкой
☕️
Диффузия в газах происходит быстрее всего
💨
Частицы газа
далеко
удалены друг от друга. Между ними существуют
огромные промежутки
, сквозь которые легко и быстро перемещаются молекулы другого вещества. Поэтому запах освежителя воздуха за считанные секунды распространяется по комнате, а новые парфюм коллеги ощущается по всему офису уже с порога.
Диффузия в жидкостях протекает ощутимо дольше
💦
В зависимости от температуры и плотности вещества, на смешивание может понадобиться от пары минут до нескольких часов. Это связано с тем, что
промежутки между соседними молекулами жидкости меньше размеров самих молекул
— частицы не бегают свободно от столкновения до столкновения, как в газе, а
колеблются около одного положения или перескоками меняются местами
с соседними молекулами. Поэтому мы можем наблюдать, как медленно растекается капля краски в стакане с водой, оставляя потрясающие объемные узоры
🌀
Из-за большой плотности твердых тел диффузия в них протекает очень медленно
— без внешнего воздействия на появление первых признаков смешивания уйдёт несколько лет. Промежутки между частицами в кристаллической структуре
очень маленькие
, поэтому другим веществам трудно проникнуть между ними. В одном из экспериментов друг на друга были положены две пластины —
свинцовая и золотая
. Спустя пять лет было обнаружено, что золото незначительно проникло в свинцовую пластину, а атомы свинца — в золотую.
Но не более, чем на один миллиметр
🔬
Поэтому диффузию в твердых телах ускоряют в условиях
высокой температуры и механического воздействия
. Мы довольно-таки быстро можем смешать два куска разноцветного пластилина, переминая их в руках
👐
Но если просто прижать их друг к другу и оставит, то на смешивание уйдут годы
🤔
Диффузия играет главную роль во многих
биологических процессах
. Благодаря ей осуществляется газообмен в лёгких, всасывание веществ в кишечнике, навигация животных по запаху и поиск пищи плотоядными рыбами в воде
🐟
И так же быстро благодаря диффузии выхлопные газы попадают в атмосферу, а реки, озера и моря загрязняются токсичными отходами производства
🏭 | https://t.me/ychemistry/930?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,200 | 0 | 1,718,706,630 | 1,736,456,954 | 1,131 | 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| null | NEUTRAL | rus | NOT SPAM | 441 | 0 | 5 | 1 | 0 | 0 | 47 | 52 | 23 | 13 | 149 | 30 | 53 | true |
118 | null | Какая кислота самая сильная?
Азотная HNO₃? А может быть серная H₂SO₄? Какие еще кислоты ты помнишь с уроков химии?
👩🏻🏫
На самом деле, существуют соединения, кислотные свойства которых в тысячи раз сильнее концентрированной серной кислоты — их называют
суперкислотами
. Прочитав этот пост, ты узнаешь о некоторых из них.
Мы уже обсуждали меру кислотности —
значение pH,
— но при рассмотрении суперкислот бессмысленно опираться на водородный показатель, потому что он используется только для водных растворов и его диапазон
строго ограничен.
Для характеристики силы суперкислот была введена особая величина —
параметр или функция кислотности Гаммета
. Она и позволяет сравнивать свойства более экзотических соединений.
Для
100% серной кислоты
функция кислотности составляет
11,93
. Это значение является точкой отчёта — все вещества, для которых оно больше, относятся к
суперкислотам
💪
К таким соединениям относится
хлорная кислота HClO₄
. В чистом виде хлорная кислота является
бесцветной
дымящей жидкостью, но при длительном хранении она
желтеет
и становится
взрывоопасной
за счёт накопления оксида хлора Cl₂O₇. Соли хлорной кислоты используются в производстве
взрывчатых веществ
💥
Безводная
фторсерная кислота HSO₃F
еще сильнее чем серная и хлорная вместе взятые. Это желтая, едкая и токсичная жидкость, которая разрушает многие вещества, устойчивые под действием обычных кислот — органические волокна и металлические поверхности. Её водные смеси способны растворять даже
стеклянную посуду
🍽
Карборановые кислоты
являются одними из
самых сильных суперкислот
, известных человеку, — эти соединения сильнее серной кислоты почти в десятки тысяч раз. Первые карборановые кислоты синтезировали в
2005
году в университете Калифорнии при участии сотрудников Российской академии наук. Карборановые кислоты обладают структурой
икосаэдра
— многогранника с 20 гранями — и за счёт этого являются
стабильными веществами,
которые можно хранить и использовать в лабораторных условиях
👩🏻🔬
«Магическая кислота»
—
смесь уже упомянутой фторсерной кислоты HSO₃F и фторида сурьмы SbF₅
. Эта смесь получила своё название после того, как на новогодней вечеринке один из сотрудников показал фокус с исчезновением свечи — он растворил её в
«магической кислоте»
🧞♀️
. Исследование показало, что кислота
настолько сильная,
что способна расщепить молекулы парафинов, из которых состоит свеча. Оказалось, что она более чем в
миллион
раз сильнее, чем серная.
Существуют и многие
другие суперкислоты,
каждая из которых представляют интерес для науки и производства. С их помощью удаётся запустить те реакции, которые или не идут совсем
🙅♀️
, или требуют экстремальных условий
🤷♀️
.
Желаю тебе отличного дня! И помни, что
серная кислота далеко не самая сильная
👀 | https://t.me/ychemistry/931?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 3,300 | 0 | 1,718,872,872 | 1,736,456,954 | 1,131 | 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118 | null | Что такое контракция в химии. Объясняю на примере приготовления домашней водки
На первом курсе химфака у нас была лекция, как приготовить водно-спиртовой раствор. В чем сложность вообще? Крепость водки по российским стандартам —
40%
. Берем 400 мл чистого спирта, добавляем 600 мл воды — и получаем водку.
Нифига, это так не работает.
Вот поэтому нужно знать химию.
В нашем расчёте было 400 мл этанола. Причём до разбавления это должен быть чистый продукт,
не содержащий воды.
Чтобы было понимание:
100%-ый этиловый спирт
— такая же редкость, как трезвая пятница. Даже медицинский спирт, который продается в аптеках и используют в больницах, имеет концентрацию 95-96%. Окей, тогда
берем 95% медицинский спирт
и вносим первую поправку в наши расчёты. Но это еще не все!
Складываем 400 мл этанола и 600 мл воды — и получаем 916 мл водно-спиртовой смеси. Где потеряли почти стопку отборной водки? А
это и есть контракция
! Это когда при сложении двух жидкостей их суммарный объем уменьшается. Происходит это из-за
специфического взаимодействия молекул и водородных связей
. Контракция создает трудности для многих отраслей промышленности, поэтому я считаю, что ты должен знать о ней :)
Что в итоге? Задача усложнилась, но решить её не составит труда, имея под рукой
таблицу плотности водно-спиртовых смесей
. Я не буду загружать тебя расчётами, а сразу напишу результат.
Идеальной пропорцией для получения 40%-го алкогольного напитка является соотношение 5 к 7: 5 частей медицинского спирта на 7 частей чистой воды.
Контракция — важная штука в химии, а
пример с водкой очень наглядно показывает, как она работает
. Теперь у вас есть понимание, как приготовить водку в домашних условиях, но я надеюсь, что делать вы этого не будете :) | https://t.me/ychemistry/932?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,200 | 0 | 1,718,963,443 | 1,736,456,954 | 1,132 | 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| NEUTRAL | rus | NOT SPAM | 273 | 0 | 4 | 1 | 0 | 0 | 32 | 37 | 23 | 19 | 83 | 15 | 50 | true |
118 | null | Игра в конструктор. Как построить молекулу?
🧬
Со школы мы знаем, что молекулы образуются за счёт возникновения
химических связей
между атомами. Например, молекула воды H₂O существует благодаря ковалентным связям между атомами водорода H и кислорода O, в кристаллы поваренной соли NaCl сформированы за счет ионной связи между хлорид-ионами и натрием.
Но можно ли построить молекулу без химических связей?
Неожиданный ответ — отчасти
да, можно
. Этой идеей загорелись ученые еще в прошлом веке — и у них получилось синтезировать молекулы, разные части которых удерживаются исключительно
механически
. Давайте посмотрим, что это за молекулы.
Первыми были получены
катенаны
. Представьте себе звенья цепи — кольца, соединенные друг с другом
⛓
А теперь представьте молекулу, которая имеет аналогичное строение —
две циклические структуры, продетые друг в друга.
Длинная органическая цепочка состоит из атомов, соединенных химической связью, но между собой кольца соединены лишь
механически
— как два обруча, продетых друг в друга
🔗
На картинке молекула катенана схематически изображена
слева
.
Первые синтезы катенанов опирались на принципы вероятности. Бралась реакционная смесь из длинных молекул, которые могли при определенных условиях образовывать кольцо, и надеялись:
вдруг какая-то из них во время замыкания окажется продетой в уже существующий цикл и получится два звена, соединенных между собой
. Чисто статистически катенаны действительно образовывались — их удавалось зафиксировать, но содержание было чрезвычайно
мало
(около 0,0001%).
Другой тип молекул —
ротаксаны
— представляет собой структуры, состоящие из гантели и надетного на нее обруча
⭕️
В данном случае соскользнуть с перекладины кольцу мешают массивные группы на концах
📍
На картинке модель молекулы ротаксана находится
справа
.
Первые синтезы ротаксана так же были предложены на основе статистики: какая-то доля циклических молекул в смеси могла замкнуться вокруг гантелевидных молекул.
Существуют катенаны с большим числом звеньев и ротаксаны с большим числом надетых колец, а так же другие типы молекул с механическим взаимодействием:
узлы и молекулярные кольца
. Синтез подобных веществ представляет собой интересную задачу. В настоящее время никто не надеется на авось — разработаны новые методы направленного синтеза.
Также хочу сказать пару слов о применении полученных экзотических соединений. Ротаксаны стали объектом внимания и биологов, и нанотехнологов. Современные ученые рассматривают такие структуры как элементы молекулярных машин — уже построены ротаксановые молекулярные переключатели, «молекулярные мышцы» и нанороботы.
Наука не стоит на месте
👩🔬 | https://t.me/ychemistry/933?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,100 | 0 | 1,719,162,514 | 1,736,456,954 | 1,131 | 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118 | null | Замечательные замедленные кадры со старта корабля "Союз ТМА-11М" | https://t.me/chemistrytg2021/9427?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,800 | 0 | 1,733,908,801 | 1,736,456,955 | 1,133 | 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| [{"ner":"11","lemma":"11","label":"NUM","start_pos":60,"end_pos":62}] | NEUTRAL | rus | NOT SPAM | 8 | 0 | 1 | 1 | 0 | 0 | 1 | 1 | 0 | 0 | 5 | 0 | 2 | true |
118 | null | Спички которые практически невозможно потушить.
Штормоустойчивые спички UCO могут загореться во время дождя, сильного ветра или снега. | https://t.me/chemistrytg2021/9428?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,733,919,601 | 1,736,456,955 | 1,133 | 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| null | NEUTRAL | rus | NOT SPAM | 17 | 0 | 1 | 0.952381 | 0.047619 | 0 | 3 | 3 | 1 | 0 | 6 | 1 | 3 | true |
118 | null | Приземления ракеты SpaсeX Илона Маска | https://t.me/chemistrytg2021/9429?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,733,930,400 | 1,736,456,955 | 1,133 | 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118 | null | Отскок дротика от 4 поддонов и попадание в яблочко.
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118 | null | Новый эффективный подход к синтезу производных тиено[3,2-b]тиофена
Ученые из Института органического синтеза им. И.Я. Постовского УрО РАН разработали эффективную стратегию построения молекул тиено[3,2-b]тиофена из 3-нитротиофенов, содержащих карбонильные фрагменты при атомах С-2 и С-5, путем нуклеофильного ароматического замещения нитрогруппы в этих субстратах. Предложенный химиками метод подходит для синтеза производных тиено[3,2-b]тиофена в граммовых количествах благодаря доступности исходных материалов и простоте выполнения процедур. Полученные производные тиено[3,2-b]тиофена содержат различные функциональные группы и представляют интерес в качестве строительных блоков для дизайна более сложных молекул.
Результаты исследования опубликованы в журнале «Organics» и могут найти применение при получении фото- и электроактивных соединений, перспективных для создания органических светодиодов, полевых транзисторов, органических солнечных элементов.
Irgashev R.A.; Kazin N.A. Synthesis of Thieno[3,2-b]thiophenes from 2,5-Dicarbonyl 3-Nitrothiophenes via Nucleophilic Aromatic Substitution of the Nitro Group with Thiolates. Organics. 2024, 5, 507-519.
https://doi.org/10.3390/org5040027
Источник:
ИОС УрО РАН
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118 | null | На обложке Журнала Американского химического общества анонсирована работа исследователей, описывающая синтез хиральных частиц платины, палладия и серебра с использованием соответствующих темплатов из кремнезема. Предполагается, что этот подход может быть также использован для получения других хиральных материалов, в том числе оксидных.
https://pubs.acs.org/doi/full/10.1021/jacs.4c10143#
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118 | null | Описание web-сайта Российского центра научной информации (РЦНИ) содержит единственную строку: «Наиболее значимое учреждение науки».
https://rcsi.science/
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118 | null | День в истории химии: Генри Мозли
137 лет назад родился человек, чей научный взлет был прерван пулей турецкого снайпера под Галлиполи на самом взлет. 27 лет - что можно успеть за это время?
Генри Мозли
успел многое. В первую очередь - экспериментально установить связь частоты характеристического рентгеновского излучения атома химического элемента с его порядковым номером. Де факто - обосновать физически Периодический закон Д.И. Менделеева. И предсказать новые элементы, не предсказанные Менделеевым. И этим своим открытием заставив всерьез воспринимать работы Резерфорда по атомному ядру.
Как говорил Милликен, то, что сделал Мозли «в
сегда будет одним из десятка наиболее блестящих по замыслу, изяществу исполнения и информативности в истории науки
». И это мы молчим про первый работающий радиоизотопный генератор электрической энергии и многое другое.
Вероятно, Айзек Азимов был прав, написав, что с точки зрения того, каких открытий мог ещё достигнуть Мозли…
его смерть вполне возможно была самой большой единичной утратой в Первой мировой войне для всего человечества.
#деньвисториихимии
Материал подготовлен ИОНХ РАН для Виртуального музея химии при грантовой поддержке Минобрнауки России в рамках федерального проекта «Популяризация науки и технологий» | https://t.me/chemrussia/5053?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,600 | 0 | 1,732,386,072 | 1,736,456,955 | 1,133 | 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| [{"ner":"Генри Мозли","lemma":"генри мозли","label":"PER","start_pos":22,"end_pos":33},{"ner":"Галлиполи","lemma":"галлиполи","label":"LOC","start_pos":124,"end_pos":133},{"ner":"Генри Мозли","lemma":"генри мозли","label":"PER","start_pos":190,"end_pos":201},{"ner":"Д.И. Менделеева","lemma":"д.и. менделеев","label":"PER","start_pos":427,"end_pos":442},{"ner":"Менделеевым","lemma":"менделеев","label":"PER","start_pos":491,"end_pos":502},{"ner":"Резерфорда","lemma":"резерфорд","label":"PER","start_pos":564,"end_pos":574},{"ner":"Милликен","lemma":"милликен","label":"PER","start_pos":605,"end_pos":613},{"ner":"Мозли","lemma":"мозли","label":"PER","start_pos":630,"end_pos":635},{"ner":"Айзек Азимов","lemma":"айзек азимов","label":"PER","start_pos":869,"end_pos":881},{"ner":"Мозли","lemma":"мозли","label":"PER","start_pos":960,"end_pos":965},{"ner":"ИОНХ","lemma":"ионх","label":"ORG","start_pos":1118,"end_pos":1122},{"ner":"РАН","lemma":"ран","label":"ORG","start_pos":1123,"end_pos":1126},{"ner":"Виртуального музея химии","lemma":"виртуальный музей химия","label":"ORG","start_pos":1131,"end_pos":1155},{"ner":"Минобрнауки","lemma":"минобрнауки","label":"ORG","start_pos":1180,"end_pos":1191},{"ner":"России","lemma":"россия","label":"LOC","start_pos":1192,"end_pos":1198},{"ner":"137","lemma":"137","label":"NUM","start_pos":34,"end_pos":37},{"ner":"27","lemma":"27","label":"NUM","start_pos":150,"end_pos":152}] | NEUTRAL | rus | NOT SPAM | 177 | 0 | 7 | 1 | 0 | 0 | 25 | 19 | 6 | 3 | 52 | 13 | 26 | true |
118 | null | Одним из самых популярных способов получения силоксановых полимеров является
полимеризация с раскрытием цикла (ROP)
. Регулярно исследователи предлагают новые катализаторы, способные улучшить данный процесс. Так группа китайских учёных под руководством
Yin-Ning Zhou
предложила метод получения полиорганосилоксанов по катионному варианту
ROP, инициируемой с помощью светового излучения,
где подавляется большинство побочных реакций благодаря использованию фотокислотных катализаторов на основе мероцианина.
💥
Fun fact: полученные катализаторы имеют различные яркие цвета: оранжевый и фиолетовый. При этом оранжевый катализатор лишен алкильных групп, что не даёт ему в полной мере растворяться в апротонных органических растворителях. Кроме того, относительно более высокая энергия связи кремний−кислород по сравнению с органическими С−О−С-связями в циклическом сложном эфире требует более сильных кислотных условий для инициирования ROP. Поэтому выбор был сделан в пользу фиолетового катализатора.
Облучение стимулирует обратимые изомерные преобразования молекул катализатора, в ходе которых образуется анион, необходимый для полимеризации. Между анионами катализатора и ионами трисилоксония возникает устойчивая связь, препятствующая прохождению побочных реакций, таких как внутримолекулярный перенос и межмолекулярная передача цепи.
В ходе работы были получены полимеры с полидисперсностью от 1.18 до 1.48 при различных соотношениях кремнийорганического мономера, инициатора, катализатора и с использованием в качестве растворителя толуола, циклогексана и хлороформа. В независимости от используемого силоксанового мономера полимеры получались с низким значением полидисперсности, однако конверсия за сутки не превышала 50%.
Предложенный метод инициирования CROP довольно интересный и перспективный, однако на данном этапе полученные полимеры имеют небольшие молекулярные массы (до 30000), что ограничивает сферы их использования.
📄
Работа
опубликована
в журнале JACS Au | https://t.me/chemrussia/5054?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,900 | 0 | 1,732,428,066 | 1,736,456,955 | 1,134 | 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118 | null | Продолжаем делиться шикарными каналами по химии. Если пропустили и еще не подписаны, обратите внимание на telegram-канал научной школы акад. В.П. Ананикова. Хотите узнать о том, над чем сейчас работают сотрудники одной из лучших научных групп в стране по катализу и органическому синтезу - подписывайтесь!
https://t.me/ananikovlab | https://t.me/incredible_chemistry/252?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 3,700 | 0 | 1,679,038,968 | 1,736,456,955 | 1,133 | 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118 | null | #органика #яд Ура!! Сегодня долгожданный пост! Интересно до жути, наслаждайтесь!
https://telegra.ph/Veselye-griby-03-26 | https://t.me/incredible_chemistry/253?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 3,100 | 0 | 1,679,893,202 | 1,736,456,955 | 1,135 | 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| [{"ner":"03-26","lemma":"03-26","label":"DATE","start_pos":114,"end_pos":119},{"ner":"26","lemma":"26","label":"NUM","start_pos":117,"end_pos":119}] | POSITIVE | other | NOT SPAM | 11 | 0 | 0 | 0.947368 | 0.052632 | 0 | 2 | 1 | 0 | 0 | 4 | 1 | 7 | true |
118 | null | Друзья, наш канал с сегодня также существует в Дзене. Прошу Вас поддержать начинание и подписаться, а за это мы подготовим Вам эксклюзивный контент которого нет в нашем канале в телеге. Подпишитесь и поставьте лайк, ну пожалуйста)
https://dzen.ru/a/ZCEzVov-zg1Cz_zT?share_to=link | https://t.me/incredible_chemistry/256?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 3,500 | 0 | 1,679,901,168 | 1,736,456,955 | 1,133 | 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| [{"ner":"Дзене","lemma":"дзен","label":"LOC","start_pos":47,"end_pos":52},{"ner":"Подпишитесь","lemma":"подпишитесь","label":"LOC","start_pos":186,"end_pos":197},{"ner":"1","lemma":"1","label":"NUM","start_pos":259,"end_pos":260}] | NEUTRAL | rus | NOT SPAM | 37 | 0 | 0 | 0.977273 | 0.022727 | 0 | 1 | 8 | 5 | 0 | 7 | 3 | 6 | true |
118 | null | Биохимически доказано
✅
😉
А гипоталамо-гипофизарные гормоны, кстати, по своей природе являются классическими белками
👨⚕️ | https://t.me/simplebestbiochemistry/416?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,600 | 0 | 1,725,251,743 | 1,736,456,955 | 1,133 | 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| null | NEUTRAL | rus | NOT SPAM | 15 | 0 | 1 | 1 | 0 | 0 | 4 | 2 | 0 | 0 | 3 | 2 | 4 | true |
118 | null | ДЕЗАМИНИРОВАНИЕ АМИНОКИСЛОТ
На прошлой неделе мы
говорили
с вами о том, что когда от аминокислоты отщепляется группа -COOH и выделяется в виде CO2, то синтезируются биогенные амины - нейромедиаторы и биологически активные вещества.
❓
А что если от аминокислоты будет отщепляться - NH2 группа?
👨⚕️
А вот в этом случае будут синтезироваться Альфа-кетокислоты.
Отщепление аминогруппы NH2 от аминокислоты с выделением газа аммиака NH3 приводит к синтезу новых альфа-кетокислот.
Далее альфа-кетокислоты могут идти на синтез новых заменимых аминокислот, а также сгорать до энергии.
Например:
✅
Аланин дезаминируется до
пировиноградной кислоты;
✅
Аспартат дезаминирцется до
щавелевоуксусной кислоты
(оксалоацетата);
✅
Глутамат дезаминирцется до
альфа-кетоглутаровой кислоты;
Кто проходил курс по обмену углеводов вспомнит, что это промежуточные продукты Цикла !
💨
А что происходит с аммиаком? А вот он дальше подвергается обязательному обезвреживанию и выведению! | https://t.me/simplebestbiochemistry/417?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,700 | 0 | 1,725,344,733 | 1,736,456,955 | 1,133 | 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| [{"ner":"ДЕЗАМИНИРОВАНИЕ","lemma":"дезаминирование","label":"ORG","start_pos":0,"end_pos":15},{"ner":"Альфа-кетокислоты","lemma":"альфа-кетокислоты","label":"ORG","start_pos":340,"end_pos":357},{"ner":"NH2","lemma":"nh2","label":"ORG","start_pos":382,"end_pos":385},{"ner":"Цикла","lemma":"цикл","label":"ORG","start_pos":848,"end_pos":853},{"ner":"2","lemma":"2","label":"NUM","start_pos":145,"end_pos":146},{"ner":"2","lemma":"2","label":"NUM","start_pos":283,"end_pos":284},{"ner":"2","lemma":"2","label":"NUM","start_pos":384,"end_pos":385},{"ner":"3","lemma":"3","label":"NUM","start_pos":430,"end_pos":431}] | NEUTRAL | rus | NOT SPAM | 130 | 0 | 11 | 0.972376 | 0.027624 | 0 | 12 | 19 | 7 | 0 | 39 | 5 | 21 | true |
118 | null | Пересыщенные растворы
🧂
Могу поспорить, что хоть раз в своей жизни вы натыкались на наглядные инструкции,
как вырастить кристаллы в домашних условиях
из обычной поваренной соли
NaCl
или медного купороса
CuSO₄
. А если такие тексты не попадались вам на глаза, то советую посмотреть несколько ссылок на странице соответствующего поискового запроса.
Вещь занятная и легко воспроизводимая с помощью подручных материалов.
А вот какие химические процессы стоят за растущими кристаллами мы рассмотрим здесь
🔬
Важной характеристикой неорганических и органических соединений является их
растворимость
, которая показывает,
сколько вещества способно раствориться в определенном объёме жидкости
. Чаще всего в качестве
растворителя
рассматривают обычную
воду
💦
Например,
растворимость NaCl
в воде при комнатной температуре составляет около
36 г/100 мл
. Это означает, что мы можем ложкой отсыпать 36 граммов поваренной соли и полностью растворить их в 100 мл воды
🥄
Условно различные неорганические соединения делят на
растворимые и малорастворимые.
Но стоит отметить, что абсолютно нерастворимых веществ
не существует
. В той или иной степени все вещества способны растворяться, пусть даже в
совершенно незначимых количествах
. Поваренная соль относится к
хорошо растворимым
соединениям. А вот какой-нибудь
сульфид ртути HgS
— к малорастворимым или практически нерастворимым. В 100 мл воды вы не сможете растворить
даже одной молекулы
HgS — всё вещество будет осадком лежать на дне
😱
Может быть, взяв объем воды побольше, вам и удастся перевести одну молекулу в растворенную форму,
но разве это имеет хоть какое-то значение?
🤔
Вернёмся к нашей соли.
Если при комнатной температуре мы добавим к воде больше NaCl, чем может раствориться в данном объеме воды, то этот избыток будет лежать на дне в виде кристалликов. Раствор, находящийся в равновесии с твёрдым нерастворившимся веществом, называется
насыщенным
.
Думаю, вы замечали, что соль в кастрюле с водой лучше растворяется при нагревании.
Всё верно, с увеличением температуры увеличивается растворимость
. При 100℃ в 100 мл воды растворяется уже почти 40 граммов NaCl
🌡
Собственно, на этом и основано выращивание кристаллов
. В горячей воде мы растворяем избыток соли, а при охлаждении он начинает кристаллизоваться на затравке, подвешенной за нитку, потому что растворимость снижается
💎
Но если мы добьемся, чтобы в нашем сосуде
не было центров кристаллизации
(пылинок и различных неоднородных примесей), то при охлаждении избыток соли
не будет выпадать в осадок
, а мы получим
пересыщенный раствор
. Такие системы
неустойчивы
(
метастабильны
) — избыток растворенного вещества легко кристаллизуется при встряхивании или возникновении неоднородностей
👏🏻
Если в случае с поваренной солью увеличение растворимости при нагревании не так ощутимо, то для других солей, например
ацетата натрия
, числа принимают более весомые значения (124 г при 20°C и 170г при 100°C на 100 мл воды)
📈
И вот что будет с пересыщенным раствором, если его потревожить
👀 | https://t.me/ychemistry/926?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,100 | 0 | 1,718,524,606 | 1,736,456,955 | 1,133 | 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| NEUTRAL | rus | NOT SPAM | 444 | 0 | 9 | 0.984127 | 0.015873 | 0 | 44 | 65 | 22 | 17 | 123 | 24 | 60 | true |
118 | null | Что такое pH? Или зачем нужен тоник для лица.
Думаю, каждый из нас натыкался на рекламу уходового средства, где говорилось о его pH, близком к коже лица и тела. Давай разбираться, почему
водородный показатель
— так еще расшифровывается сочетание
pH
— имеет большое значение не только в уходе за кожей, но и в нашей жизни.
рН — это мера кислотности водных растворов. Запомним главное — чем меньше его значение, тем более кислый перед нами раствор. Также важно знать, что в водных системах значение водородного показателя изменяется
от 0 до 14.
Нейтральной среде соответствует
pH = 7.
Соответственно, всё, что больше 7 - это
щелочная
среда, а всё что меньше —
кислая.
А теперь немного о том, какая среда у растворов в нашей жизни.
Свежая дистиллированная вода
имеет нейтральный pH, равный 7. Но при стоянии на воздухе она поглощает углекислый газ, который, растворяясь, образует слабую кислоту, pH понижается до 5-6.
Сок лимона
имеет кислую среду за счёт содержания лимонной кислоты, рН равен 2.
Желудочный сок
еще кислее, чем лимонный. Его pH приближается к 1.
Обычное мыло
даёт щелочную реакцию — pН достигает 11. Теперь вы интуитивно можете представить, какие растворы будут кислыми, а какие — щелочными. Кислоты обладают кисло-горьким вкусом, а щелочи на ощупь будут мыльными и скользкими.
Вода из-под крана
имеет слабо-щелочную среду — pH приблизительно равен 8. Это связано с наличием ионов металлов, которые мы обсуждали в тексте про
жесткость
.
Отбеливатели и средства для прочистки труб
— это
сильные щелочи
, их pH достигает 13. Поэтому работать с этими веществами обязательно нужно в перчатках!
У
кожи лица
среда слабо-кислая, pH колеблется в районе 5. И это очень важно!
Большое количество дерматологических проблем связано с нарушением уровня pH.
Смещение баланса в щелочную среду приводит к
разрушению естественной липидной мембраны
на поверхности и способствует
размножению бактерий
. Здоровая кожа способна самостоятельно восстанавливать баланс, но и ей нужна поддержка. В качестве такой помощи могут выступать
тоники
для лица. После умывания рекомендуют пользоваться тоником, который, помимо действующих компонентов, имеет
кислую среду
. Тоник нейтрализует остатки слабо-щелочной воды из-под крана и нормализует рН кожи лица. К тому же, все дальнейшие стадии ухода становятся более эффективными — кожа лучше впитывает крема и сыворотки.
Хорошего вам дня, обняла!
❤️ | https://t.me/ychemistry/927?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,000 | 0 | 1,718,599,856 | 1,736,456,955 | 1,133 | 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21 | 73 | true |
118 | null | Тяжелая вода
💧
Опасна ли она для нашего организма?
Думаю, все слышали о том, что вода может быть
«тяжелой»
. А кто-то до сих пор боится несколько раз кипятить воду в чайнике, якобы она постепенно превращается в яд. Давайте разберёмся,
чем этот опасный тяжеловесный зверь отличается от обычной воды и развеем главный миф
💦
Начнём с важного понятия. В природе у химических элементов существуют
изотопы
— разновидности атомов, которые имеют
одинаковый заряд ядра и число протонов
, но у этих разновидностей
разное количество нейтронов
в ядре и следовательно
разная масса
. Изотопы не отличаются друг от друга с точки зрения химии, то есть вступают в одинаковые реакции, но отличаются с точки зрения физики — у изотопов разные температуры кипения, энергии связи с другими атомами и стабильность — все мы слышали о радиоактивных изотопах, но об этом поговорим в другой раз.
Вернемся к нашей жидкости. Дело в том, что водород, входящий в состав молекулы воды имеет
три изотопа
, каждый из которых получил собственные названия: H —
протий, D — дейтерий и T — тритий
(радиоактивен). Ядро самого распространённого изотопа — протия H — состоит из единственного протона. Ядро тяжелого водорода — дейтерия D состоит уже из одного протона и одного нейтрона, то есть его масса почти в два раза больше. Этот эффект разницы в массе особенно заметен только в случае водорода. Радиоактивный тритий мы пока опустим, но по аналогии можно догадаться, что его ядро состоит так же из одного протона, но к нему прибавляется уже два нейтрона, масса увеличивается втрое.
Дейтерий естественным образом встречается в природе, вот только его содержание
ничтожно мало — на 6500-9100 атомов привычного протия H приходится всего один атом экзотического дейтерия D.
🤔
Тяжёлая вода вместо двух атомов обычного водорода H содержит два атома его тяжёлого изотопа. Формула тяжёлой воды обычно записывается как D₂O. Внешне такая вода выглядит как обычная — бесцветная, без вкуса и запаха. Отличия проявляются на уровне физико-химических свойств: лёд из тяжелой воды тает почти при +4°С, а закипает при +101°С. Также все реакции в среде тяжелой воды протекают
ощутимо медленнее.
Это является причиной, почему её считают ядовитой
⚗️
Да, погибла не одна мышь, которую поили тяжелой водой в лабораторных испытаниях. Когда 25% воды в организме млекопитающего замещалось на тяжелую, животное становилось стерильным, при больших концентрациях — погибало. В испытаниях с человеком установлено, что без особого вреда для здоровья можно выпить три стакана чистой дейтерированной воды, которая выведется из организма через несколько дней
🥛
А теперь хочу напомнить, насколько
ничтожно мало
естественное содержание тяжелого изотопа водорода — ни о каком негативном влиянии таких концентраций не идёт речи.
А теперь развеем миф, который многие из вас наверняка слышали
🤨
При длительном кипячении концентрация дейтерия в воде увеличивается, что делает такую воду ядовитой.
Численное опровержение этой гипотезы: чтобы повысить естественное содержание дейтерия в воде всего в десять раз нужно выпарить столько тонн вод, что в этом числе будет
30 нулей.
Это в сотни миллионов раз больше содержания воды на Земле в целом
🌏
Вкус воды если и меняется после кипячения, то не из-за накопления дейтерия, а из-за разрушения различных примесей.
Да и к тому же, если бы можно было так легко синтезировать тяжелую воду, она бы не стоила
так дорого.
1 грамм дейтерированной воды стоит 1 евро. Немалая сумма выходит за стаканчик.
💰 | https://t.me/ychemistry/929?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,200 | 0 | 1,718,657,754 | 1,736,456,955 | 1,133 | 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118 | null | Черный раствор представляет собой комплекс йода с крахмалом, а прозрачный раствор содержит ионы тиосульфата. При смешивании тиосульфат восстанавливает йод до йодида, который разрушает комплекс и цвет исчезает. | https://t.me/chemistrytg2021/9422?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,733,844,000 | 1,736,456,956 | 1,413 | 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| null | NEUTRAL | rus | NOT SPAM | 27 | 0 | 0 | 1 | 0 | 0 | 2 | 5 | 2 | 0 | 13 | 0 | 4 | true |
118 | null | Камень гранат Альмандин
Гранаты — это обширная группа минералов, представленная силикатами марганца, магния, железа, алюминия, кальция и хрома. Наиболее распространенными в этом сообществе являются камни красной палитры и называющиеся: пироп и альмандин. | https://t.me/chemistrytg2021/9423?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,800 | 0 | 1,733,854,800 | 1,736,456,956 | 1,403 | 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| [{"ner":"Альмандин\nГранаты","lemma":"альмандин\nграната","label":"LOC","start_pos":14,"end_pos":31}] | NEUTRAL | rus | NOT SPAM | 32 | 0 | 0 | 1 | 0 | 0 | 3 | 3 | 0 | 0 | 16 | 1 | 9 | true |
118 | null | Кровь и перекись водорода.
⠀
При смешивании с кровью пероксид водорода распадается на воду и кислород. Этому способствует специальный фермент Каталаза, входящий в состав крови. А так же ионы железа. В ходе реакции выделяется кислород, который и приводит к вспениванию. | https://t.me/chemistrytg2021/9424?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,733,898,000 | 1,736,456,956 | 1,405 | 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| [{"ner":"Каталаза","lemma":"каталаза","label":"LOC","start_pos":142,"end_pos":150}] | NEUTRAL | rus | NOT SPAM | 40 | 0 | 2 | 1 | 0 | 0 | 1 | 6 | 2 | 0 | 17 | 1 | 8 | true |
118 | null | Интересные эксперименты со льдом | https://t.me/chemistrytg2021/9425?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,800 | 0 | 1,733,898,000 | 1,736,456,956 | 1,403 | 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| null | NEUTRAL | rus | NOT SPAM | 4 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 0 | 0 | 2 | 0 | 0 | true |
118 | null | Окислительно-восстановительная реакция пероксида натрия с серой:
2Na2O2 + S = 2Na2O - SO2. | https://t.me/chemistrytg2021/9426?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,800 | 0 | 1,733,908,801 | 1,736,456,956 | 1,403 | 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118 | null | На сайте научной электронной библиотеки
eLibrary.ru
опубликован очередной номер журнала «Координационная химия» (2024, Том 50, № 7, с. 413-468)
Содержание номера со ссылками на статьи:
Метод динамической магнитной восприимчивости в исследовании координационных соединений.
Ефимов Н. Н., Бабешкин К. А., Ротов А. В.
https://www.elibrary.ru/item.asp?id=73887869
Темплатный синтез комплекса железа(III) с лигандами на основе ацилпиразолонпиридинов.
Струнин Д.Д., Никовский И.А., Даньшина А.А., Нелюбина Ю.В.
https://www.elibrary.ru/item.asp?id=73887879
Трехъядерный циклопентадиенильный комплекс лютеция(III) с дианионом 2,2'-бипиридина.
Бардонов Д.А., Ройтерштейн Д.М., Насырова Д.И., Миняев М.Е.
https://www.elibrary.ru/item.asp?id=73887880
Координационные соединения щелочных и редкоземельных металлов на основе центросимметричного хлорзамещенного бисмеркаптооксазола. Синтез, строение и особенности люминесценции.
Рогожин А.Ф., Ильичев В.А., Силантьева Л.И., Ковылина Т.А., Козлова Е.А., Фукин Г.К., Бочкарев М.Н.
https://www.elibrary.ru/item.asp?id=73887883
Дицианоаргентатные комплексы никеля(II) и меди(II) с этилендиаминовыми и 4,4'-бипиридильными лигандами.
Пашнин Д.Р., Шевченко Д.П., Шарутин В.В., Шарутина О.К.
https://www.elibrary.ru/item.asp?id=73887885
#российскаянаука #ионх | https://t.me/chemrussia/5048?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,900 | 0 | 1,732,168,916 | 1,736,456,956 | 1,403 | 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118 | null | День в истории химии: Владимир Ипатьев
Все-таки поразительные бывают повороты жизни. Одна девушка Анна Глики в юности влюбляется в учителя физики, но ее отдают замуж за состоятельного пожилого архитектора, которому она рожает трех детей - Веру, Николая и Владимира. Николай станет известным инженером, потом переедет в Екатеринбург, строит дорогу Пермь-Екатеринбург, а в доме его потом расстреляют царскую семью.
Владимир, день рождения которого празднуется сегодня, станет химиком, а Анна Ипатьева бросит мужа, выйдет-таки за бывшего своего учителя - и родит ему еще одного сына, Льва.
Да, далеко не все знают, что
Владимир Ипатьев
и
Лев Чугаев
, выдающиеся химики первой половины ХХ века - единоутробные братья. Про Чугаева мы писали, жизнь Владимира Ипатьева оказалась дольше. Он станет специалистом по созданию взрывчатых веществ, обеспечит армию в Первую мировую, останется в СССР, но в 1930 году не вернется из-за границы и переберется в США, где придумает каталитический крекинг нефти. Удивительны зигзаги судьбы!
#деньвисториихимии
Материал подготовлен ИОНХ РАН для Виртуального музея химии при грантовой поддержке Минобрнауки России в рамках федерального проекта «Популяризация науки и технологий» | https://t.me/chemrussia/5049?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,600 | 0 | 1,732,201,284 | 1,736,456,956 | 1,403 | 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| [{"ner":"Владимир Ипатьев\nВсе-таки","lemma":"владимир ипатьев\nвсе-таки","label":"PER","start_pos":22,"end_pos":47},{"ner":"Анна Глики","lemma":"анна глики","label":"PER","start_pos":98,"end_pos":108},{"ner":"Николая","lemma":"николай","label":"PER","start_pos":245,"end_pos":252},{"ner":"Владимира","lemma":"владимир","label":"PER","start_pos":255,"end_pos":264},{"ner":"Николай","lemma":"николай","label":"PER","start_pos":266,"end_pos":273},{"ner":"Екатеринбург","lemma":"екатеринбург","label":"LOC","start_pos":319,"end_pos":331},{"ner":"Пермь-Екатеринбург","lemma":"пермь-екатеринбург","label":"LOC","start_pos":347,"end_pos":365},{"ner":"Владимир","lemma":"владимир","label":"PER","start_pos":413,"end_pos":421},{"ner":"Анна Ипатьева","lemma":"анна ипатьев","label":"PER","start_pos":485,"end_pos":498},{"ner":"Льва","lemma":"лев","label":"PER","start_pos":581,"end_pos":585},{"ner":"Владимир Ипатьев","lemma":"владимир ипатьев","label":"PER","start_pos":616,"end_pos":632},{"ner":"Лев 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true |
118 | null | #БАД #органика #спортпит
https://telegra.ph/Ibutamoren-03-06 | https://t.me/incredible_chemistry/247?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 4,300 | 0 | 1,678,165,219 | 1,736,456,956 | 1,414 | 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| [{"ner":"03-06","lemma":"03-06","label":"DATE","start_pos":55,"end_pos":60},{"ner":"06","lemma":"06","label":"NUM","start_pos":58,"end_pos":60}] | NEUTRAL | other | NOT SPAM | 4 | 0 | 1 | 0.875 | 0.125 | 0 | 0 | 1 | 0 | 0 | 2 | 0 | 2 | true |
118 | null | Приглашаем всех неравнодушных к органической химии подписаться на новый авторский канал, посвященной этой замечательной науке
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Внутри вы найдете разборы актуальных исследований, новостей, методов синтеза и немного органического юмора
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@Azide_Alkyne | https://t.me/incredible_chemistry/249?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 4,300 | 0 | 1,678,692,195 | 1,736,456,956 | 1,404 | 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| [{"ner":"Хлорофиллы Вудворда","lemma":"хлорофиллы вудворда","label":"PER","start_pos":274,"end_pos":293}] | NEUTRAL | rus | NOT SPAM | 43 | 0 | 0 | 0.949153 | 0.050847 | 0 | 8 | 4 | 1 | 0 | 13 | 2 | 7 | true |
118 | null | Отличная блок схема, демонстрирующая все функции белков с примерами!
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Кстати нейромедиаторы по природе не являются белками! | https://t.me/simplebestbiochemistry/412?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,800 | 0 | 1,724,818,740 | 1,736,456,956 | 1,412 | 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| null | NEUTRAL | rus | NOT SPAM | 17 | 0 | 0 | 1 | 0 | 0 | 1 | 2 | 0 | 0 | 8 | 1 | 4 | true |
118 | null | СИНТЕЗ НЕЙРОМЕДИАТОРОВ
Если говорить кратко, то субстратом для синтеза многих нейромедиаторов (но не всех!) являются аминокислоты!
Ключевые примеры:
➡️
тирозин идет на синтез
дофамина
и
норадреналина
;
➡️
триптофан превращается в
серотонин
;
➡️
глутамат является предшественником ГАМК -
гамма-аминомасляной кислоты
;
❓
Как это происходит с точки зрения биохимии?
Более подробно и углубленно мы будем говорить об этом механизме на планирующемся
большом курсе по обмену белков и аминокислот
!
А если сформулировать кратко, то ключевым механизмом является - декарбоксилирование аминокислоты.
Как вы помните, аминокислоты имеют -NH2 и -COOH группы. А процесс декарбоксилирования, это отщепление карбоксильной группы -COOH в виде углекислого газа CO2
💨
.
Таким образом, останется соединение лишь с одной амино группой -NH2. Такие соединения называются «биогенными аминами», а нейромедиаторы это как раз их наиболее яркие представители!
На фото выше представлен пример декарбоксилирования глутамата с образованием ГАМК - важнейшего тормозного нейромедиатора!
👨⚕️
Кстати, а что вы понимаете под словом тормозной нейромедиатор? Как вы думаете, что это значит и какова физиология этого процесса? | https://t.me/simplebestbiochemistry/413?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,500 | 0 | 1,724,991,182 | 1,736,456,956 | 1,403 | 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118 | null | Йодированная соль. Нужно ли?
🤔
Йод — важный микроэлемент в нашем организме
, входящий в состав гормонов щитовидной железы —
тироксина (Т₄) и трийодтиронина (T₃)
. При недостатке йода эти гормоны не синтезируются в необходимых количествах, что приводит к сбоям в обмене веществ и нарушению процессов роста и развития всего организма
😨
К сожалению,
проблема йододефицита
затрагивает около четверти населения планеты, что связано с неравномерным распространением йода
🌍
Из пищи йод в достаточных количествах получают в основном жители приморских районов. В тех местах, где содержаний йода в почве, воде и воздухе
очень мало
, было предложено искусственно добавлять его соединения в продукты питания.
Соединения йода пробовали добавлять в хлеб, молоко, воду... Но остановились на самом
универсальном и удобном варианте
—
поваренной соли
🧂
Как йодируют соль?
По технологии добавки выделяют два способа:
сухой и влажный
. Здесь всё просто. В сухом методе йодирующий агент смешивают сначала с небольшим количеством поваренной соли, а потом полученный концентрат равномерно распределяют в основной массе. В данном методе важно равномерно перемешать и распределить компонент:
всего 40 миллиграмм на целую тонну соли
⚖️
Во
влажном способе
йодирующий агент растворяют в воде и распыляют полученный раствор над массой соли. Незначительное повышение влажности поваренной соли допускается согласно ГОСТу
💦
А теперь о том, какие соединения йода используют
. Йодировать соль начинали с помощью
йодида калия KI
, но данное соединение
неустойчиво
— под действием
света и воздуха
йодид калия окислялся до
свободного йода I₂
и улетучивался. Поэтому соль с такой добавкой хранили в темных пакетах и в рамках срока годности. Сейчас соль йодируют преимущественно
йодатом калия KIO₃
, который более стабилен при хранении и внешнем воздействии
🌤
С разложением соединений йода связана одна из проблем йодированной соли — она
непригодна для домашнего консервирования
. Выделяющийся свободный йод, как антисептик, мешает квашению капусты и засолке огурцов. Это безвредно для потребителя и сказывается лишь на эстетических качествах — овощи темнеют
🥒
Всем ли нужна йодированная соль?
Нет
🤷♀️
Как недостаточное, так и избыточное поступление йода вызывает отрицательный эффект. Учитывая, что большинство из нас
не знает об уровне йода
в своём организме, не стоит надеяться, что йодированная соль станет панацеей от недугов.
Безусловно, в истории есть достаточное количество
благоприятных примеров
: в Швейцарии, России, Казахстане и других странах центральной Азии общий уровень йододефицита удалось снизить за годы использования йодированной соли
📉
Но на мой взгляд более разумно, чтобы контроль над
риском йододефицитных заболеваний
проводил ваш
лечащий врач
. На основе анализов специалист может назначить куда более эффективные витамины и добавки, если они будут необходимы
💊
Оптимальным вариантом профилактики может стать
сбалансированное и разнообразное питание
: ешьте рыбу, морепродукты и морскую капусту
🐟
А соль выбирайте ту, что больше нравится
😉 | https://t.me/ychemistry/921?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 1,900 | 0 | 1,718,086,380 | 1,736,456,956 | 1,413 | 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118 | null | В России создается виртуальный музей химии
Институт общей и неорганической химии Российской академии наук начал работу над созданием виртуального музея химии.
Экспозиция виртуального музея химии включает в себя различные рубрики:
• биографии выдающихся химиков России и мира;
• истории открытия и изучения отдельных веществ;
• новая популярная библиотека химических элементов;
• история химии на карте России (репортажи из химических музеев и музеев науки, домов-музеев выдающихся химиков);
• история химических институтов страны;
• химическая повседневность (история химических сосудов, приборов и устройств, принципы их работы и использование в современной лаборатории).
Подписывайтесь на канал музея в Телеграм:
https://t.me/chemmuseum | https://t.me/ychemistry/922?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 1,900 | 0 | 1,718,102,205 | 1,736,456,956 | 1,404 | 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118 | null | Чем опасны инертные газы?
🎈
Думаю, многие из вас хотя бы раз в жизни вдыхали
шары с гелием
, чтобы наложить на свой голос весёлый звуковой эффект.
Надеюсь, что после прочтения сегодняшнего поста вам будет, о чём задуматься, прежде чем сделать это снова
🤔
Еще со школы мы знаем об
элементах восьмой группы таблицы Менделеева — благородных или инертных газах,
— которые ни с чем не реагируют и ассоциируются у нас в голове с
безопасными
. Есть ряд так называемых
физиологически инертных газов
, которые не вступают в химические реакции со средой нашего организма. Если
угарный газ CO
прочно связывается с гемоглобином в крови,
хлор Cl₂ и фосген COCl₂
вызывают сильнейший ожог лёгочной ткани и разрушают алвьеолы, то
азот N₂, благородные газы
(гелий He, неон Ne, аргон Ar, криптон Kr) и другие инертные при обычных условиях соединения (например,
гексафторид серы SF₆
)
не вызовут такого разрушающего эффекта
.
Их опасность скрывается в другом
👀
Вдыхаемый нами воздух в норме содержит
78% азота N₂, 21% кислорода O₂ и 1% составляют все остальные газы
— углекислый CO₂, аргон Ar и другие. Когда мы вдыхаем избыток инертного газа, он выступает в роли
«разбавителя»
, уменьшая содержание кислорода в воздухе и, соответственно, в крови.
Развивается гипоксия
😨
Вдыхая воздух, в котором кислорода содержится
в два раза меньше
, человек чувствует сильное головокружение, он теряет возможность объективно оценивать происходящее, возрастает пульс и частота дыхания, синеют губы
🥴
При концентрации кислорода в воздухе
от 4 до 6% потеря сознания наступает через 40 секунд
, а
минуты
будет достаточно, чтобы наступила смерть
⏳
Всё коварство заключается в том, что физиологически инертные газы
не имеют запаха или вкуса и не вызывают болезненных ощущений при вдыхании
. Когда наступает дискомфорт, связанный с недостатком кислорода, человек
не успевает понять, с чем это связано
.
Из-за недостаточной информированности об удушающих свойствах азота и других инертных газов происходят
несчастные случаи
. От массовой потери сознания на вечеринке с жидким азотом до смерти в ходе криотерапии с использованием того же жидкого азота. Удушье гелием случается реже и в основном связано с его промышленным использованием.
Удушье азотом
является одним из методов
смертной казни
и используется для безболезненного оглушения животных на фермах.
Сегодняшний текст
не является
призывом отказаться от использования шаров с гелием и
не написан
с целью напугать вас.
Я хотела лишь напомнить, что понятие техники безопасности применимо к большинству ситуаций, даже когда мы имеем дело с безобидными на первый взгляд веществами
👩🏻🔬 | https://t.me/ychemistry/923?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,200 | 0 | 1,718,105,878 | 1,736,456,956 | 1,403 | 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| NEUTRAL | rus | NOT SPAM | 399 | 0 | 7 | 0.97451 | 0.02549 | 0 | 45 | 58 | 20 | 9 | 120 | 11 | 61 | true |
118 | null | 🧪
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ОГЭ:
https://t.me/oge_chemisst | https://t.me/ychemistry/924?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,100 | 0 | 1,718,258,660 | 1,736,456,956 | 1,404 | 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| [{"ner":"БЕСПЛАТНЫЕ","lemma":"бесплатные","label":"ORG","start_pos":23,"end_pos":33},{"ner":"ОГЭ","lemma":"огэ","label":"ORG","start_pos":58,"end_pos":61}] | NEUTRAL | rus | NOT SPAM | 50 | 0 | 8 | 0.972603 | 0.027397 | 0 | 3 | 2 | 0 | 0 | 17 | 2 | 5 | true |
118 | null | Чем дезинфицировать смартфоны?
📲
Главные атрибуты эпохи самоизоляции —
антисептики для рук
и
медицинские маски
— мы уже успели обсудить, но хочу обратить ваше внимание на ещё один не менее важный момент —
гаджеты
💡
Мобильные телефоны уже давно стали нашими верными проводниками в решении всех бытовых задач. Можете ли вы представить вылазку до ближайшего магазина или прогулку с домашним любимцем
без смартфона
? Как дела по дому, так и любой выход из него проходят с телефоном или в руке, или в кармане одежды
👣
Что мы делаем, выходя каждый раз из дома?
Верно. Хватаемся за дверные ручки, нажимаем кнопки лифта, берём в руки товары в магазине, которые до нас
сотни раз
брали другие люди, и периодически держим в руках мобильный телефон
🤳🏻
Приходим домой.
Моем руки
(хорошо, что этому нас научили инструкция ВОЗ и видео в TicTok), берём в очередной раз смартфон, выложенный на полку или кровать и...
Спрашивается — зачем мыли руки?
👐🏻
Думаю, вы хорошо понимаете ту цепочку, благодаря которой телефон становится
главным носителем патогенных микроорганизмов
. Порой страшно представить, с каких публичных мест микробы попадают на экран смартфона, из-за чего он становится
в 10 раз грязнее унитаза
🚽
Некоторые специалисты заявляют, что
дезинфекция носимых устройств более важна, чем ношение лицевых масок
— коронавирус выживает на стеклянных поверхностях до нескольких дней
🦠
Чем очищать смартфон?
Официальная рекомендация Apple и другие компании советуют делать это
мягкими салфетками из микрофибры, смоченными в 70% изопропиловом спирте
. Не рекомендуется использовать отбеливающие вещества (перекись водорода).
Альтернатива — хлоргексидин или специальные дезинфицирующие салфетки (Clorox)
🧴
Важно — выдерживайте экспозицию!
⏰
Зараза не погибает моментально — оставьте гаджет в «визуально влажном» состоянии не менее чем на минуту.
Когда нужно дезинфицировать?
После каждого «выхода в свет»
. Причём сначала обработали смартфон, а уже затем вымыли руки
🙌🏻
Эта рекомендация актуальна не только в период распространения вируса, но и
в любое другое время
. Прикладывая телефон или руки после использования гаджета к лицу, мы каждый раз переносим микробы на зоны вблизи слизистых оболочек
👀
Стоит отметить, что Bluetooth-гарнитуры эффективно сокращают эти контакты.
Не исключено, что в скором времени производители будут выпускать гаджеты из
специальных антибактериальных материалов и покрытий
. На торговых площадках уже появляются
портативные кейсы-санитайзеры со встроенными бактерицидными УФ-лампами
для смартфонов.
А пока мы будем учиться полезным привычкам
👩🏻🔬 | https://t.me/ychemistry/925?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,500 | 0 | 1,718,262,241 | 1,736,456,956 | 1,403 | 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| [{"ner":"ВОЗ","lemma":"воз","label":"ORG","start_pos":809,"end_pos":812},{"ner":"TicTok","lemma":"tictok","label":"ORG","start_pos":823,"end_pos":829},{"ner":"Apple","lemma":"apple","label":"ORG","start_pos":1421,"end_pos":1426},{"ner":"Причём","lemma":"причём","label":"PER","start_pos":1893,"end_pos":1899},{"ner":"10","lemma":"10","label":"NUM","start_pos":1173,"end_pos":1175},{"ner":"70","lemma":"70","label":"NUM","start_pos":1512,"end_pos":1514}] | NEUTRAL | rus | NOT SPAM | 375 | 0 | 3 | 0.991886 | 0.008114 | 0 | 42 | 51 | 16 | 4 | 116 | 22 | 69 | true |
118 | null | При непродолжитeльнoм контакте руки с расплавленным металлом, человек не получaет ожогов. В момент соприкосновения, влага на поверхности руки создаёт слой пара, который изолирует поверхность руки от прямого взаимодeйствия с температурой в 1500 °C. Но лучше не повторять! | https://t.me/chemistrytg2021/9420?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,733,822,400 | 1,736,456,957 | 1,389 | 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| [{"ner":"1500","lemma":"1500","label":"NUM","start_pos":239,"end_pos":243}] | NEUTRAL | rus | NOT SPAM | 37 | 0 | 2 | 0.977273 | 0.022727 | 0 | 2 | 3 | 1 | 1 | 18 | 1 | 6 | true |
118 | null | Смешиваем воду + соляную кислоту + алюминий + сульфат меди - получаем синий огонь | https://t.me/chemistrytg2021/9421?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,733,833,200 | 1,736,456,957 | 1,411 | 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| null | NEUTRAL | rus | NOT SPAM | 14 | 0 | 0 | 1 | 0 | 0 | 2 | 2 | 0 | 0 | 7 | 0 | 1 | true |
118 | null | День в истории химии: Михаил Ломоносов
Сегодня у российских химиков - очень важный день. 313 лет назад неподалеку от поморских Холмогор родился «наше все» в области отечественной химии,
Михаил Васильевич Ломоносов
.
Помимо всего того, что сделал Ломоносов для науки вообще и для химии в частности, именно его стараниями 276 лет назад в Санкт-Петербурге появилась первая
научная химическая лаборатория
и, таким образом, де-факто началась химия как академическая наука.
#деньвисториихимии
Материал подготовлен ИОНХ РАН для Виртуального музея химии при грантовой поддержке Минобрнауки России в рамках федерального проекта «Популяризация науки и технологий» | https://t.me/chemrussia/5040?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,600 | 0 | 1,732,028,506 | 1,736,456,957 | 1,416 | 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| [{"ner":"Михаил Ломоносов","lemma":"михаил ломоносов","label":"PER","start_pos":22,"end_pos":38},{"ner":"Холмогор","lemma":"холмогор","label":"PER","start_pos":127,"end_pos":135},{"ner":"Михаил Васильевич Ломоносов","lemma":"михаил василиевич ломоносов","label":"PER","start_pos":186,"end_pos":213},{"ner":"Ломоносов","lemma":"ломоносов","label":"PER","start_pos":246,"end_pos":255},{"ner":"Санкт-Петербурге","lemma":"санкт-петербург","label":"LOC","start_pos":336,"end_pos":352},{"ner":"ИОНХ","lemma":"ионх","label":"ORG","start_pos":508,"end_pos":512},{"ner":"РАН","lemma":"ран","label":"ORG","start_pos":513,"end_pos":516},{"ner":"Виртуального музея химии","lemma":"виртуальный музей химия","label":"ORG","start_pos":521,"end_pos":545},{"ner":"Минобрнауки","lemma":"минобрнауки","label":"ORG","start_pos":570,"end_pos":581},{"ner":"России","lemma":"россия","label":"LOC","start_pos":582,"end_pos":588},{"ner":"313","lemma":"313","label":"NUM","start_pos":89,"end_pos":92},{"ner":"276","lemma":"276","label":"NUM","start_pos":320,"end_pos":323}] | NEUTRAL | rus | NOT SPAM | 90 | 0 | 2 | 1 | 0 | 0 | 11 | 5 | 3 | 2 | 27 | 9 | 15 | true |
118 | null | Оптически активные микроэмульсионные пленки из наночастиц золота
Ученые из Новосибирского государственного университета и Института неорганической химии имени А.В. Николаева СО РАН разработали новый подход к получению оптически активных композитных пленок на основе органозоля наночастиц золота. Предложенная методика позволяет формировать образцы с «настраиваемым» сигналом плазмонного поглощения. Пленки обладают стабильным во времени и термочувствительным сигналом поверхностного плазмонного резонанса.
Результаты исследования опубликованы в журнале «Colloids and Surfaces A: Physicochemical and Engineering Aspects» и могут быть использованы для создания оптических датчиков температуры.
Kolodin A.N., Syrokvashin M.M., Korotaev E.V. Gold nanoparticle microemulsion films with tunable surface plasmon resonance signal. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2024, 701, 134904.
https://doi.org/10.1016/j.colsurfa.2024.134904
Источник:
ИНХ СО РАН
#российскаянаука | https://t.me/chemrussia/5041?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,700 | 0 | 1,732,082,485 | 1,736,456,957 | 1,415 | 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118 | null | Новый эффективный подход к получению альдолей
Ученые из Института органической химии им. Н.Д. Зелинского РАН разработали простой и эффективный способ получения альдолей - органических веществ, которые широко применяются в производстве лекарственных препаратов, включая антибиотики. Были изменены полярность (распределение зарядов) молекул-субстратов, используемых для синтеза альдолей, на противоположную. В стандартную альдольную конденсацию вступает отрицательно заряженное соединение (енолят) и несущий частичный положительный заряд альдегид. Химики подобрали их аналоги, но с противоположной полярностью. Роль положительно заряженного енолята играло соединение с нитрогруппой, а отрицательно заряженного - органическое соединение серы. Взаимодействие этих веществ привело к образованию промежуточного гетероциклического продукта, который в присутствии никелевого катализатора и водорода превращался в целевой альдоль. При этом выходы продуктов, отражающие эффективность процесса, доходили до 89%, что позволяло избегать образования побочных продуктов. Изменяя структуру молекул-субстратов, с помощью предложенного подхода удалось синтезировать более двадцати различных альдолей. Избирательное получение большинства этих продуктов с помощью классической альдольной конденсации невозможно.
Результаты работы, поддержанной РНФ, опубликованы в «The Journal of Organic Chemistry» и могут быть использованы для получения фармацевтически ценных соединений разнообразной структуры.
Pavel Yu. Ushakov, Alexey Yu. Sukhorukov. Umpolung Approach to Aldol Products via Isoxazoline N-Oxides as IntermediatesClick to copy article link. The Journal of Organic Chemistry. 89 (21). 2024.
https://pubs.acs.org/doi/10.1021/acs.joc.4c01671
Источник:
РНФ
#российскаянаука | https://t.me/chemrussia/5042?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,800 | 0 | 1,732,082,508 | 1,736,456,957 | 1,415 | 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| [{"ner":"Института органической химии им. Н.Д. Зелинского РАН","lemma":"институт органический химия им. н.д. зелинского ран","label":"ORG","start_pos":56,"end_pos":108},{"ner":"РНФ","lemma":"рнф","label":"ORG","start_pos":1324,"end_pos":1327},{"ner":"The Journal of Organic Chemistry","lemma":"the journal of organic chemistry","label":"ORG","start_pos":1345,"end_pos":1377},{"ner":"Alexey Yu","lemma":"alexey yu","label":"ORG","start_pos":1497,"end_pos":1506},{"ner":"The Journal of Organic Chemistry","lemma":"the journal of organic chemistry","label":"ORG","start_pos":1625,"end_pos":1657},{"ner":"10.10","lemma":"10.10","label":"DATE","start_pos":1699,"end_pos":1704},{"ner":"01671","lemma":"01671","label":"DATE","start_pos":1717,"end_pos":1722},{"ner":"89","lemma":"89","label":"NUM","start_pos":996,"end_pos":998},{"ner":"89","lemma":"89","label":"NUM","start_pos":1659,"end_pos":1661},{"ner":"21","lemma":"21","label":"NUM","start_pos":1663,"end_pos":1665},{"ner":"2024","lemma":"2024","label":"NUM","start_pos":1668,"end_pos":1672},{"ner":"1021","lemma":"1021","label":"NUM","start_pos":1702,"end_pos":1706},{"ner":"4","lemma":"4","label":"NUM","start_pos":1715,"end_pos":1716}] | NEUTRAL | rus | NOT SPAM | 198 | 0 | 6 | 0.873518 | 0.126482 | 0 | 31 | 24 | 4 | 5 | 69 | 6 | 41 | true |
118 | null | Петр Фурман. Сын рыбака
Как вы помните, вчера мы отмечали 313 лет со дня рождения первого русского химика и много еще кого,
Михаила Васильевича Ломоносова
. И сегодня мы хотим представить вам очень интересную книгу, написанную не ученым, а журналистом. Правда, журналистом и публицистом позапрошлого века,
Петром Романовичем Фурманом
, коллегой и современником Михаила Салтыкова-Щедрина. Фурман прожил всего 39 лет, но успел написать много статей и даже несколько популярных книг для детей. В том числе и «
Сын рыбака, Михаил Васильевич Ломоносов
», написанную в 1847 году.
И пусть и Салтыков-Щедрин, и «неистовый Виссарион» Белинский разгромили эту и некоторые другие книжки Фурмана за слабый слог и морализм, мы считаем, что ознакомиться с этим произведением будет очень любопытно для читателя любого возраста в XXI веке.
https://chem-museum.ru/biblioteka/petr-furman-syn-rybaka/
#библиотека
Материал подготовлен ИОНХ РАН для Виртуального музея химии при грантовой поддержке Минобрнауки России в рамках федерального проекта «Популяризация науки и технологий» | https://t.me/chemrussia/5047?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,400 | 0 | 1,732,168,883 | 1,736,456,957 | 1,416 | 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| [{"ner":"Петр Фурман","lemma":"пётр фурман","label":"PER","start_pos":0,"end_pos":11},{"ner":"Михаила Васильевича Ломоносова","lemma":"михаил василиевич ломоносов","label":"PER","start_pos":124,"end_pos":154},{"ner":"Петром Романовичем Фурманом","lemma":"пётр романович фурман","label":"PER","start_pos":306,"end_pos":333},{"ner":"Михаила Салтыкова-Щедрина","lemma":"михаил салтыков-щедрин","label":"PER","start_pos":362,"end_pos":387},{"ner":"Фурман","lemma":"фурман","label":"PER","start_pos":389,"end_pos":395},{"ner":"Михаил Васильевич Ломоносов","lemma":"михаил василиевич ломоносов","label":"PER","start_pos":520,"end_pos":547},{"ner":"Салтыков-Щедрин","lemma":"салтыков-щедрин","label":"PER","start_pos":585,"end_pos":600},{"ner":"Белинский","lemma":"белинский","label":"PER","start_pos":626,"end_pos":635},{"ner":"Фурмана","lemma":"фурман","label":"PER","start_pos":677,"end_pos":684},{"ner":"ИОНХ","lemma":"ионх","label":"ORG","start_pos":916,"end_pos":920},{"ner":"РАН","lemma":"ран","label":"ORG","start_pos":921,"end_pos":924},{"ner":"Виртуального музея химии","lemma":"виртуальный музей химия","label":"ORG","start_pos":929,"end_pos":953},{"ner":"Минобрнауки","lemma":"минобрнауки","label":"ORG","start_pos":978,"end_pos":989},{"ner":"России","lemma":"россия","label":"LOC","start_pos":990,"end_pos":996},{"ner":"313","lemma":"313","label":"NUM","start_pos":58,"end_pos":61},{"ner":"39","lemma":"39","label":"NUM","start_pos":409,"end_pos":411},{"ner":"1847","lemma":"1847","label":"NUM","start_pos":564,"end_pos":568}] | NEUTRAL | rus | NOT SPAM | 147 | 0 | 6 | 0.989247 | 0.010753 | 0 | 14 | 13 | 6 | 4 | 39 | 7 | 27 | true |
118 | null | В нашем производственном процессе используется мощный растворитель, часть которого уничтожается. Мы долго думали куда его можно применить. Один из вариантов представлен на видео. На часть капота ВАЗ 2110 (десятка) нанесен наш растворитель, который предварительно загустили. Результат - полное удаление лакокрасочного покрытия, в том числе и грунта. Что скажете? Идея рабочая? | https://t.me/incredible_chemistry/243?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 4,500 | 0 | 1,675,918,813 | 1,736,456,957 | 1,389 | 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| [{"ner":"2110","lemma":"2110","label":"NUM","start_pos":199,"end_pos":203}] | NEUTRAL | rus | NOT SPAM | 50 | 0 | 2 | 1 | 0 | 0 | 5 | 8 | 5 | 2 | 15 | 4 | 13 | true |
118 | null | #органика
https://telegra.ph/Mentol--himiya-i-primenenie-02-13 | https://t.me/incredible_chemistry/244?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 4,800 | 0 | 1,676,350,816 | 1,736,456,957 | 1,414 | 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118 | null | #органика
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118 | null | #органика #БАД #cпортпит
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118 | null | Интенсивные трудовые будние! | https://t.me/simplebestbiochemistry/406?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,700 | 0 | 1,724,242,233 | 1,736,456,957 | 1,389 | 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| null | NEUTRAL | rus | NOT SPAM | 3 | 0 | 0 | 1 | 0 | 0 | 2 | 0 | 0 | 0 | 1 | 0 | 1 | true |
118 | null | АМИНОКИСЛОТЫ. Строение и химизм
Одна из тем, которая часто интересует моих учеников, это аминокислоты и пути их превращения. Обмен аминокислот, по своей сути, это отдельный большой раздел биохимии, который нужно разбирать в комплексе. Кстати, именно о нем, я планирую в сентябре запустить большой образовательный курс.
А пока давайте разберемся, как в общем виде выглядят аминокислоты.
Как мы говорили ранее, каждая аминокислота имеет:
-COOH группу
- так называемая карбоксильная группа, которая обладает выраженными кислотными свойствами;
❗️
Карбоксильная группа может отщепляться от аминокислоты с выделением углекислого газа CO2, и такой процесс будет называться
декарбоксилированием аминокислот;
-NH2 группу
- а это аминогруппа, которая, наоборот, обладает щелочными свойствами и имеется у каждой аминокислоты;
❗️
Аминогруппа может отщепляться от аминокислоты с выделением аммиака NH3
💨
, такая реакция будет называться
дезаминированием,
или аминогруппа может переноситься на
другие соединения, тогда такой процесс будет называться
трансаминированием.
👨⚕️
Таким образом, присутствие карбоксильный группы с выраженными
кислотными
свойствами, а также наличие
аминогруппы в
составе формирует правильное номенклатурное название - аминокислоты.
Расскажите в комментариях
⤵️
, а что вы знаете про аминокислоты и их обмен? | https://t.me/simplebestbiochemistry/407?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,700 | 0 | 1,724,392,504 | 1,736,456,957 | 1,412 | 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| [{"ner":"АМИНОКИСЛОТЫ","lemma":"аминокислоты","label":"ORG","start_pos":0,"end_pos":12},{"ner":"2","lemma":"2","label":"NUM","start_pos":630,"end_pos":631},{"ner":"2","lemma":"2","label":"NUM","start_pos":703,"end_pos":704},{"ner":"3","lemma":"3","label":"NUM","start_pos":887,"end_pos":888}] | NEUTRAL | rus | NOT SPAM | 175 | 0 | 6 | 0.983122 | 0.016878 | 0 | 16 | 27 | 13 | 1 | 56 | 9 | 40 | true |
118 | null | На этой неделе рассказывал обмен углеводов ученице из заграницы на английском языке. Интересный опыт
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Биохимическая терминология в русском и английском языке практически одинаковая, поэтому преподавать, читать литературу и статьи значительно легче.
Кто был на курсе по обмену углеводов, узнаете биологический процесс?
😉 | https://t.me/simplebestbiochemistry/408?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,600 | 0 | 1,724,495,929 | 1,736,456,957 | 1,412 | 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| null | NEUTRAL | rus | NOT SPAM | 43 | 0 | 0 | 1 | 0 | 0 | 8 | 4 | 1 | 0 | 15 | 3 | 7 | true |
118 | null | #о_рабочем
Временный наружный кардиостимулятор
Выходные прошли очень интенсивно и по-рабочему, поэтому в понедельник захотелось поделиться частью рабочих будней!
После больших полостных операций на открытом сердце
🩻
всегда есть риск возникновения аритмии, ведь было травматичное вмешательство. В том числе могут возникать брадиаритмии (замедление ритма), асистолии (полное прекращение сердцебиений) и нарушения проводимости.
❗️
Поэтому всем пациентам в обязательно порядке к сердцу подшиваются электроды, выводятся на переднюю брюшную стенку и к ним подключается наружный временный электрокардиостимулятор (ЭКС), аппарат наверху на фото
👆🏻
, который страхует пациента, а при необходимости сам навязывает нужный ритм.
👨⚕️
Нашей задачей, как хирургов аритмологов, является подключение и настройка ЭКС, проверка свойств миокарда и выставление нужных параметров.
Например, после операции по протезированию клапанов, мы выставляем ЧСС 80-90 ударов в минуту.
Если в течение 5 дней у пациента все хорошо с собственным ритмом, аппарат снимается, а электроды аккуратно извлекаются.
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Вот так маленький машинки страхуют и спасают ежедневно наших пациентов! | https://t.me/simplebestbiochemistry/410?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,600 | 0 | 1,724,648,007 | 1,736,456,957 | 1,411 | 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| [{"ner":"асистолии","lemma":"асистолия","label":"LOC","start_pos":355,"end_pos":364},{"ner":"ЧСС","lemma":"чсс","label":"ORG","start_pos":927,"end_pos":930},{"ner":"80-90","lemma":"80-90","label":"DATE","start_pos":931,"end_pos":936},{"ner":"90","lemma":"90","label":"NUM","start_pos":934,"end_pos":936},{"ner":"5","lemma":"5","label":"NUM","start_pos":969,"end_pos":970}] | NEUTRAL | rus | NOT SPAM | 150 | 0 | 4 | 1 | 0 | 0 | 17 | 19 | 4 | 4 | 54 | 14 | 36 | true |
118 | null | Нейромедиаторы. Биологическая роль!
Одна из важнейших тем в биохимии и физиологии - нейромедиаторы, но ученики и студенты не до конца понимают, а как именно нейромедиаторы работают.
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Как вы знаете, нервная система, это совокупность миллиардов нейронов, взаимодействующих между собой посредством электрических импульсов.
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Однако важно понимать, что электрический импульс может двигаться только по одному нейрону, но самостоятельно вызвать возбуждение следующего нейрона не может, посколько между нейронами имеется небольшое свободное пространство - синаптическая щель.
И вот тут на помощь приходят нейромедиаторы. Когда возбуждение охватывает первый нейрон и импульс подходит к ПРЕсинаптической мембране, происходит выделение из везикул (пузырьков)
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химического вещества - нейромедиатора, который секретируется в синаптическую щель и достигает ПОСТсинаптической мембраны. Далее, достигнув постсинаптической мембраны, нейромедиатор способствует генерации импульса
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на втором нейроне, который продолжает движение дальше.
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Таким образом, взаимодействие нейронов имеет
электрохимическую природу
. Поскольку электрический импульс двигается по нейрону, а связь между нейронами осуществляется благодаря выделению нейромедиаторов с синаптическую щель.
Изображение выше
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максимально простое, но понятное и простое. Рассмотрите внимательно строение синапса, и вы наглядной поймете, как работает передача импульса с помощью нейромедиаторов. | https://t.me/simplebestbiochemistry/411?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,700 | 0 | 1,724,738,628 | 1,736,456,957 | 1,412 | 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| null | NEUTRAL | rus | NOT SPAM | 176 | 0 | 1 | 1 | 0 | 0 | 26 | 25 | 6 | 3 | 61 | 11 | 37 | true |
118 | null | Чёрное золото
🛢
Нефть
...
как часто мы слышим о ней из каждого новостного ресурса?
Кажется, будто весь мир сейчас зависит от её цен. Феномены стран, достигших пика развития после открытия нефтяных запасов, и прогнозы мировой экономики мы оставим соответствующим специалистам, а я хочу обсудить чёрное золото
с точки зрения химии
👩🏻🔬
Что делают из нефти?
Непосредственно
из сырой — ничего
, а вот из продуктов её
переработки — почти всё
, что только можно представить. От топлива до декоративной косметики
💄
Сырая нефть представляет смесь больше чем из
2000
компонентов, большую часть которых представляют органические вещества: жидкие и газообразные углеводороды, сернистые, азотистые и кислородные соединения. Возникает закономерная задача — отделить одни вещества от других.
Эту проблему решают с помощью
ректификации
— процесса разделения жидких смесей на фракции, различающиеся температурами кипения, путём многократного испарения и конденсации.
А теперь простыми словами.
Каждое вещество в составе сырой нефти имеет свою температуру кипения. Мы нагреваем смесь до одной температуры
🌡
, при которой испаряется легколетучий компонент, конденсируем пар
💨
, как под крышкой кастрюли с кипящей водой, и отводим из системы собранную чистую фракцию
💧
Затем повторяем процедуру многократно и при разных температурах, чтобы отделить каждое вещество.
Это если совсем грубо.
В реальности весь процесс проводят в огромных
ректификационных колоннах
, где одновременно протекает множество актов испарения и конденсации. Каждый миг наполнен движением: из колонки постоянно отводятся чистые фракции и загружается сырая нефть. Такая неравновесная система с трудом поддается даже строгому химическому описанию
🤯
На выходе получаем фракции разного состава:
• При температуре до
100℃
выкипает
петролейная
фракция — смесь легких бесцветных углеводородов (пентаны С₅Н₁₂ и гексаны С₆Н₁₄ ). Используется в качестве растворителя, топлива для горелок и зажигалок
⚗️
• При
140℃
выделяется
бензиновая
фракция, которая уходит на производство горючего для двигателей внутреннего сгорания. Стоит отметить, что хороший бензин получается далеко не их всех сортов нефти, ведь его качество напрямую зависит от содержания определенных ароматических соединений
🚘
• От
140 до 180°С
испаряется
лигроиновая
фракция — более тяжелая смесь горючих углеводородов. Она идёт на производство растворителей, лакокрасочных смесей, добавок к топливу и других продуктов нефтехимии
🧪
• До
220°С
выделяется
керосиновая
фракция — в первую очередь представляющая топливо для реактивных двигателей самолетов и ракет
✈️
• При
350°С
испаряются последняя летучая
дизельная
фракция — компонент топлива для морских судов и горючего для отопительных систем
🚢
• Дальнейшая ректификация
осложняется
, так как остаются труднолетучие вязкие смеси —
мазут и гудрон
. Их разделяют вакуумной перегонкой и получают компоненты технических масел, парафина и той самой черной тягучей жидкости для дорожных покрытий и кровельных материалов
🛢
А если вам кажется, что на этом путь переработки нефти заканчивается, то спешу обрадовать. Это было только начало
😉 | https://t.me/ychemistry/917?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,000 | 0 | 1,717,910,120 | 1,736,456,957 | 1,411 | 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118 | null | Кислоту в воду или воду в кислоту?
👩🏻🔬
Во всех учебниках написано и каждый учитель пытался донести, что
нельзя лить воду в кислоту
. Если у нас есть концентрированная кислота и нам нужно разбавить её, что мы делаем? Правильно!
Осторожно и по каплям добавляем кислоту в стакан с водой
👩🏻🏫
Но мало кто упоминал, почему нужно делать именно так...
Для начала проведём мысленный бунтарский эксперимент
💢
Возьмем стаканы с
азотной HNO₃, соляной HCl и серной H₂SO₄
кислотами. В каждый из них будем наливать воду и измерять температуру смеси. Разумеется, все кислоты
концентрированные
.
Что наблюдаем?
При добавлении воды к азотной кислоте температура незначительно повысилась, стакан слегка нагрелся. Аналогичная ситуация в случае соляной кислоты — раствор стал чуть теплее. Ничего необычного
🤔
И как только мы наливаем воду в стакан с концентрированной серной кислотой, в разные стороны начинают лететь кипящие брызги жидкости, смесь очень
сильно нагревается
🤯
Вы только представьте эту жуткую картину — капли концентрированной горячей кислоты попадают на все ближайшие поверхности. Даже отчаянные химики не повторяют таких экспериментов, хотя бы потому что дорожат своими глазами, руками и другими частями тела.
Что не так с серной кислотой?
Дело в том, что концентрированная серная кислота очень
гигроскопична
— она активно присоединяет воду, и в результате этой реакции выделяется
много тепла
. Поэтому в нашем мысленном эксперименте смесь буквально закипела.
Но какая же разница: лить воду в кислоту или кислоту в воду, если в обоих случаях раствор нагреется?
Тут стоит рассмотреть другую характеристику.
Плотность
серной кислоты почти в два раза больше плотности воды. Значит,
кислота тяжелее и всегда будет на дне
. Если мы наливаем воду, то она мгновенно закипает на поверхности кислоты и разбрызгивается во все стороны. Как капли воды в горячем масле
💦
Но если мы осторожно будем добавлять серную кислоту к воде, она
будет погружаться на дно
. Теплота выделяется в том же количестве, но в отличие от первого случая не только на поверхности, а равномерно во всём объеме.
Без вскипания и лишних брызг
🙅♀️
Почему с азотной и соляной кислотами всё было не так проблематично?
Всё просто — они менее активно реагируют с водой и их концентрированные растворы на самом деле не такие концентрированные. Если серная кислота в лаборатории бывает
98%-ной
, то азотная и соляная в основном
65
и
36%-ные
соответственно
🧪
Вот почему концентрированную серную кислоту нужно медленно и при постоянном перемешивании добавлять в воду.
Не плюй в серную кислоту, иначе она плюнет в тебя
🥽 | https://t.me/ychemistry/918?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 1,800 | 0 | 1,718,012,471 | 1,736,456,957 | 1,411 | 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| [{"ner":"₃","lemma":"₃","label":"NUM","start_pos":430,"end_pos":431},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":455,"end_pos":456},{"ner":"₄","lemma":"₄","label":"NUM","start_pos":458,"end_pos":459},{"ner":"98","lemma":"98","label":"NUM","start_pos":2340,"end_pos":2342},{"ner":"65","lemma":"65","label":"NUM","start_pos":2382,"end_pos":2384},{"ner":"36","lemma":"36","label":"NUM","start_pos":2387,"end_pos":2389}] | NEUTRAL | rus | NOT SPAM | 400 | 0 | 4 | 0.993988 | 0.006012 | 0 | 48 | 46 | 22 | 6 | 103 | 32 | 57 | true |
118 | null | Как производят серную кислоту?
H₂SO₄
— эта формула прекрасно вам знакома. Серную кислоту используют повсеместно:
для обработки руд
редких элементов и металлов,
в качестве электролита
в свинцовых аккумуляторах, для производства химических
волокон и взрывчатых веществ
🧨
Причём
бóльшее
количество получаемой серной кислоты уходит на производство
минеральных удобрений
— около 50% от мирового объема
🍂
Но откуда H₂SO₄ берётся в таких количествах?
Подземных источников серной кислоты в чистом виде вы
не обнаружите
на нашей планете — её не выкачивают из недр Земли, как в случае с нефтью и газом. Поэтому сегодня мы рассмотрим
промышленное производство серной кислоты
🏭
Природным сырьем для получения H₂SO₄ сейчас в основном служит
самородная сера
, меньшая доля приходится на другие минералы (сульфиды и сульфаты металлов) и газ — сероводород. Также используются
газы от переработки неочищенной нефти
, так как в ней содержится большое количество органических примесей серы
💨
На первой стадии сырье окисляют до диоксида серы SO₂
. Рассмотрим на примере обжига минерала
пирита
(дисульфида железа FeS₂), названного
«золотом дураков»
из-за внешнего сходства с драгоценным металлом
⭐️
FeS₂ + O₂ → Fe₂O₃ + SO₂
Полученный печной газ помимо интересующего нас диоксида серы содержит
кучу примесей
. Поэтому газ пропускают через серьезную
систему очистки
: крупную пыль удаляют с помощью устройства, подобного
центрифуге
, мелкую пыль отделяют с помощью
электрофильтра
, а от примесей воды избавляются в
сушильной башне
. Причём последняя представляет интересную конструкцию: диоксид серы в башню подаётся снизу, а сверху
распыляется концентрированная серная кислота
, которая, проходя через газ, беспощадно поглощает воду
💧
Далее необходимо еще сильнее окислить сернистый газ SO₂ до серного ангидрида SO₃
:
SO₂ + O₂ → SO₃
Причём этот процесс протекает
не так эффективно
, как сгорание пирита, поэтому для его ускорения применяют катализатор —
высший оксид ванадия V₂O₅
— наиболее экономичный и удобный вариант. Также очень важно поддерживать
оптимальную температуру и давление
🧭
При слишком низкой температуре реакция будет идти очень медленно, а слишком высокая вызовет разложение целевого продукта
🌡
И последняя стадия — поглощение серного ангидрида
. Но ни в коем случае не водой, как вы могли подумать.
Мы уже разбирали, что будет, если добавить концентрированную H₂SO₄ к воде.
В промышленных масштабах ситуация аналогичная: если добавлять серный ангидрид к воде, будет выделяться
колоссальное количество тепла
и вместо жидкости образуется
сернокислый туман
🔥
Поэтому серный газ поглощают уже готовой концентрированной серной кислотой
, получая
олеум — раствор серного ангидрида в серной кислоте
. Это очень едкая дымящая жидкость, которую в стальных цистернах транспортируют до места назначения.
И уже из олеума путём аккуратного разбавления получают растворы серной кислоты необходимой концентрации
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| null | POSITIVE | rus | NOT SPAM | 2 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 0 | 0 | 1 | 0 | 0 | true |
118 | null | Огонь+водород.
Газообразный водород легче воздуха и его можно разжечь пламенем или искрой, что приведет к впечатляющему взрыву.
Вот почему сейчас чаще используется гелий, а не водород для наполнения аэростатов. | https://t.me/chemistrytg2021/9417?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,733,757,600 | 1,736,456,958 | 1,392 | 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| null | NEUTRAL | rus | NOT SPAM | 29 | 0 | 0 | 1 | 0 | 0 | 3 | 3 | 2 | 0 | 10 | 4 | 5 | true |
118 | null | Спички частично сделаны из хлората калия, сильного окислителя.
Как только серная кислота вступает в контакт с солью, она образует хлорную кислоту, еще более сильный окислитель и гораздо более реакционноспособное соединение. Он отвечает за зажигание. | https://t.me/chemistrytg2021/9418?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,100 | 0 | 1,733,768,400 | 1,736,456,958 | 1,392 | 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| null | NEUTRAL | rus | NOT SPAM | 34 | 0 | 0 | 1 | 0 | 0 | 5 | 4 | 2 | 0 | 11 | 5 | 6 | true |
118 | null | Taкиe элeмeнты, кaк углepoд, жeлeзo, кpeмний, aзoт и киcлopoд, кoтopыe мы нaxoдим нa Зeмлe, нa caмoм дeлe пpoизoшли в ходе взрыва сверхновых. | https://t.me/chemistrytg2021/9419?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,733,811,600 | 1,736,456,958 | 1,389 | 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118 | null | Накрутить на Нобелевскую премию - V
Мы продолжаем наш анализ того, как А.В. Труханов и компания добились нобелевских масштабов цитирования своих статей (начало см. здесь:
https://t.me/chemrussia/4794
,
https://t.me/chemrussia/4865
,
https://t.me/chemrussia/4913
,
https://t.me/chemrussia/4970
).
Как вы помните, одним из основных источников цитирований для работ Труханова является насильственное принуждение других авторов к цитированию. В прошлый раз при анализе работ Труханова и компании мы наткнулись на совершенно замечательный кейс: авторы одной из найденных нами статей прямо во введении к статье указали, что их принудили к цитированию работ Труханова и его друзей (не можем не процитировать это повторно: «As strongly requested by the reviewers, here we cite some references [35-47] although they are completely irrelevant to the present work»).
Эта история, после ее обнародования на нашем канале 6 ноября, облетела и российскую, и зарубежную аудитории (см., например, посты в Reddit
(
https://www.reddit.com/r/MaliciousCompliance/comments/1gnd5yw/malicious_compliance_academic_version/?rdt=33347
),
многочисленных социальных сетях, на
Chemport.ru
(
http://ftp.chemport.ru/forum/viewtopic.php?f=1&t=34009&start=14900
),
Medium.com
, GitHub и т.д. и т.п.). Насколько мы можем видеть, количество упоминаний и репостов этого кейса исчисляется уже тысячами. Увы, далеко не все на нас сослались, но мы не в обиде. Судя по всему, с нашей подачи об этом кейсе узнал весь научный мир
🙂
Сегодня мы решили еще немного понаблюдать за тем, каким образом авторы статей, вынужденные ссылаться на нерелевантные статьи Труханова, делают это. Итак, вот как выглядят некоторые ссылки на те статьи Труханова, которые посвящены исключительно ферритам металлов и их магнитным свойствам:
• The chemical properties of sodium are quite similar to those of lithium, which allows for the development of sodium-ion batteries (SIBs) that can potentially match the performance characteristics of their lithium-ion batteries (LIBs)
• Nowadays, the application of organic coatings on the metallic material surface is a widely accepted strategy to provide the robust barrier against harsh environments with the aim of preventing corrosion damage on the substrate
• However, to compete with well-established wide bandgap semiconductor materials such as SiC or GaN and to achieve practical applications, single crystal diamond films must reach inch-scale dimensions
• In the landscape of sodium cathode candidates, which includes layered transition metal oxides, polyanionic compounds, prussian blue analogues, and organic compounds, layered manganese-based cathode materials (NaxMnO2, with 0 < x ≤ 1) are particularly notable for their impressive specific capacity and operational potential, thus ensuring a high energy density for the complete battery system
• However, the metals, hydroxides, oxychlorides, phosphates, phosphides, their alloys and composites are not free from some disadvantages
• Therefore, it has a long-term practical and economic significance to develop a high-value, green and high-efficiency application for Shanxi lignite
• Generally, the incorporation of other active species not only brings extra active sites, but also leads to new composite materials with better properties
• Thus, the limited vertical range of a probe restricts the allowed roughness of the examined surface
И таких примеров - тысячи!
Как вы видите, ничего общего с темой ферритов здесь нет, и авторы статей проявляют чудеса изворотливости (а чаще всего не проявляют
🙂
), чтобы сослаться на Труханова. Как вы думаете, кто заставил их это сделать?
😉
#накруткацитирований | https://t.me/chemrussia/5036?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,600 | 0 | 1,731,995,019 | 1,736,456,958 | 1,403 | 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118 | null | Не можем не процитировать здесь целиком реакцию коллег на «кейс Труханова», опубликованную на сайте
forbetterscience.com
:
As strongly requested by the reviewers
The
International Journal of Hydrogen Energy
(
IJHE
, impact factor 8.1) is owned by the Veziroglu family from Turkey (residing in Florida), it is published by Elsevier.
IJHE
publishes almost exclusively fraud, mostly by papermills, and in breathtaking amounts.
A win-win situation for all involved: the fraudster authors, the papermills, the Veziroglus and of course also for Elsevier, which apparently instructs its employees never to interfere into the
IJHE
business or worse, attempt to retract any papers there. That’s what happens when honest authors accidentally submit a manuscript to
IJHE
:
Fan-Xi Yang , Yi-Fei Zhu , Shuo Cao, Chao-Ming Wang , Ying-Jie Ma , Rui Yang , Qing-Miao Hu
Origin of the distinct site occupations of H atom in hcp Ti and Zr/Hf
International Journal of Hydrogen Energy
(2024) doi:
10.1016/j.ijhydene.2024.10.197
All these papers the authors had to reference are “authored” by two russian brothers,
Alex and Sergey Trukhanov
. They were briefly mentioned here:
https://forbetterscience.com/2024/10/28/the-incorrigible-elsevier/
You can probably imagine who the reviewers were. I predict that Elsevier will soon erase that sentence and sack those who allowed it to be published:
“As strongly requested by the reviewers, here we cite some references
[[35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45], [46], [47]]
although they are completely irrelevant to the present work.”
https://forbetterscience.com/2024/11/15/schneider-shorts-15-11-2024-not-a-clinical-research-article-with-new-data/#ijhe
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118 | null | На сайте RetractionWatch сообщают об очередном случае отзыва (ретракции) статей по причине использования нелицензионного программного обеспечения:
https://retractionwatch.com/2024/11/08/complaint-from-engineering-software-company-prompts-two-retractions/
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118 | null | Лекция «Титановые сплавы для медицинского применения» в рамках цикла семинаров «Новые функциональные материалы: синтез, свойства и области применения» в ИОНХ РАН
Цикл семинаров
«Новые функциональные материалы: синтез, свойства и области применения»
организован Советом молодых ученых Института общей и неорганической химии им. Н.С. Курнакова РАН при поддержке Научного совета по неорганической химии РАН в рамках Десятилетия науки и технологий
20 ноября 2024 г в 15:00
состоится очередной семинар, лектор – ведущий научный сотрудник Лаборатории прочности и пластичности металлических и композиционных материалов и наноматериалов Института металлургии и материаловедения им. А.А. Байкова Российской академии наук (ИМЕТ РАН),
к.т.н. Севостьянов Михаил Анатольевич
Семинар пройдёт в лекционной аудитории ИОНХ РАН (Москва, Ленинский проспект, д. 31, 2 этаж, каб. 217) с одновременной трансляцией через онлайн-платформу
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на сайте ИОНХ РАН
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| null | NEUTRAL | rus | NOT SPAM | 3 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 0 | 0 | 2 | 0 | 2 | true |
118 | null | #органика
https://telegra.ph/Lirika-01-30 | https://t.me/incredible_chemistry/242?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 4,600 | 0 | 1,675,141,207 | 1,736,456,958 | 1,391 | 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| [{"ner":"01-30","lemma":"01-30","label":"DATE","start_pos":36,"end_pos":41},{"ner":"30","lemma":"30","label":"NUM","start_pos":39,"end_pos":41}] | NEUTRAL | other | NOT SPAM | 2 | 0 | 0 | 0.75 | 0.25 | 0 | 0 | 0 | 0 | 0 | 1 | 0 | 1 | true |
118 | null | СНИЖЕНИЕ ВЫРАБОТКИ ФАКТОРА КАСЛА
Вчера мы с вами сказали о функции фактора Касла, как о ключевом гликопептиде, ответственном за всасывание витамина Б-12.
❓
Каковы же могут быть причины его снижения?
Многие из вас ответили совершенно верно. Чаще всего, ключевой механизм патогенеза - повреждение париетальных клеток желудка. Причины же этого повреждения могут быть самыми разными!
1️⃣
Аутоантитела к обкладочным клеткам желудка
Аутоагрессия к собственным париетальным (обкладочным) клеткам приводит к их повреждению. Как следствие, мы получаем и дефицит внутреннего фактора, так и гипоацидное состояние, поскольку эти клетки вырабатывают еще и соляную кислоту!
2️⃣
Заболевания желудка различной этиологии
В целом все заболевания ЖКТ мы можем отнести к этой группе. Гастриты различной этиологии, язвенная болезнь, онкология и т.д. Механизм один - повреждение париетальных клеток желудка и снижение синтеза фактора Касла.
Особенно стоит быть внимательным к пациентам с хроническими проблемами, поскольку процесс развития гиповитаминоза по витамину Б12 развивается в течение длительного времени.
3️⃣
Резекция желудка/части тонкого кишечника
Тут в целом все логично. Удаление даже части желудка снижает кол-во выработки внутреннего фактора, а удаление тонкого кишечника, особенно дистальной его части, ассоциируется со снижением всасывания.
4️⃣
Аутоантитела к внутреннему фактору Касла
Собственная иммунная система расценивает гликопептид (сам фактор), как антиген, и вырабатывает против него антитела блокирующего (тип 1) или связывающего (тип 2) характера.
Так или иначе, блокируется связывающий центр (активный центр), что фактически выключает этот гликопротеин.
👨⚕️
А я напоминаю, что совсем недавно у нас была большая лекция по ПЕРЕВАРИВАНИЮ БЕЛКОВ. Очень подробно говорили о желудке и соляной кислоте.
По всем вопросам и для приобретения писать моему ассистенту
@ysavnin | https://t.me/simplebestbiochemistry/405?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,700 | 0 | 1,724,221,826 | 1,736,456,958 | 1,389 | 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| [{"ner":"ВЫРАБОТКИ","lemma":"выработки","label":"ORG","start_pos":10,"end_pos":19},{"ner":"ФАКТОРА","lemma":"фактора","label":"ORG","start_pos":20,"end_pos":27},{"ner":"Касла","lemma":"касла","label":"PER","start_pos":76,"end_pos":81},{"ner":"ЖКТ","lemma":"жкт","label":"ORG","start_pos":730,"end_pos":733},{"ner":"Касла","lemma":"касла","label":"PER","start_pos":914,"end_pos":919},{"ner":"Касла\nСобственная иммунная система расценивает гликопептид","lemma":"касла\nсобственный иммунный система расценивать гликопептид","label":"ORG","start_pos":1377,"end_pos":1435},{"ner":"12","lemma":"12","label":"NUM","start_pos":151,"end_pos":153},{"ner":"1","lemma":"1","label":"NUM","start_pos":381,"end_pos":382},{"ner":"2","lemma":"2","label":"NUM","start_pos":661,"end_pos":662},{"ner":"12","lemma":"12","label":"NUM","start_pos":1048,"end_pos":1050},{"ner":"3","lemma":"3","label":"NUM","start_pos":1094,"end_pos":1095},{"ner":"4","lemma":"4","label":"NUM","start_pos":1338,"end_pos":1339},{"ner":"1","lemma":"1","label":"NUM","start_pos":1517,"end_pos":1518},{"ner":"2","lemma":"2","label":"NUM","start_pos":1542,"end_pos":1543}] | NEUTRAL | rus | NOT SPAM | 252 | 0 | 11 | 0.996933 | 0.003067 | 0 | 33 | 27 | 13 | 3 | 86 | 16 | 48 | true |
118 | null | 🎓
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Секрет успешной сдачи экзаменов раскрыт!
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С этими МИКРОНАУШНИКАМИ вы забудете о волнении и будете уверены в своих знаниях. Эти незаметные помощники помогут вам получить высокие баллы без лишнего стресса!
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Преимущества этих микронаушников:
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Миниатюрный размер:
никто и не догадается! Неслышен снаружи.
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Безопасный динамик:
идеальная передача информации, НЕВОЗМОЖНО перебить другими наушниками.
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Легкость в использовании:
подключение за пару секунд.
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Микрофон распознает тихую речь.
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Доступность:
качество, которое не бьет по карману, одни из самых бюджетных на рынке.
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Готовы к успеху? Заказывайте микронаушники прямо сейчас и забудьте о проблемах с подготовкой!
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ССЫЛКА НА ТОВАР
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Артикул WB 216246895
Не оставляйте свой успех на волю случая — будьте на шаг впереди!
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✅ | https://t.me/ychemistry/912?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 1,900 | 0 | 1,717,491,846 | 1,736,456,958 | 1,404 | 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| [{"ner":"МИКРОНАУШНИКАМИ","lemma":"микронаушниками","label":"ORG","start_pos":57,"end_pos":72},{"ner":"НЕВОЗМОЖНО","lemma":"невозможно","label":"ORG","start_pos":363,"end_pos":373},{"ner":"21624","lemma":"21624","label":"DATE","start_pos":733,"end_pos":738}] | NEUTRAL | rus | NOT SPAM | 127 | 0 | 7 | 0.994872 | 0.005128 | 0 | 13 | 12 | 4 | 1 | 36 | 4 | 41 | true |
118 | null | Чем мы чистим зубы?
С детства нас учили тому, что утром и вечером нужно чистить зубы
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. Следуя правилам и привычкам, ежедневно два раза в день, мы это делаем. При этом мало кто из нас обращает внимание на состав зубной пасты. Мы слепо верим рекламе и даже не пытаемся выяснить, действительно ли данное средство защищает зубы от налёта, кариеса и прочих проблем.
Интересный факт. Наши далекие предки
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, которые даже не знали про существование "быстрых" углеводов, жили без кариеса до 30-40 лет. Сегодня же кариес появляется даже у детей
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до 5 лет.
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Любая зубная паста состоит из четырех видов компонентов: абразивные, поверхностно-активные, связующие и вспомогательные. Абразивные вещества - одни из самых главных, они убирают налёт, в котором обычно размножаются бактерии. Когда-то для этих целей использовали зубной порошок, однако из-за того, что у большинства людей чувствительная эмаль, его запретили.
Сегодня эффект своеобразной "терки" создаётся благодаря полимерным силикатам. Секрет "отбеливающих" паст заключается в обыкновенной пищевой соде. Поэтому если вы любитель отбеливающей пасты, рекомендую использовать её не чаще трёх раз в неделю. Кристаллы соды довольно твёрдые, поэтому могут повредить эмаль.
Содержащиеся в зубных пастах ПАВ отвечают за пенообразование
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, чистящий эффект и уменьшение вероятности появления микроцарапин на эмали. По статистике, люди больше любят пенящиеся зубные пасты. Поэтому практически в каждом тюбике есть ПАВ.
Связующие компоненты, вроде карбоксиметилцеллюлозы, нужны для того, чтобы паста была именно пастой, а не жидкостью
💧
. Так что можем считать данный ингредиент своего рода загустителем.
У любой зубной пасты есть 2 главные задачи - стерилизация полости рта
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и реминерализация зубов. За первое отвечают различные экстракты трав
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, за второе - соединения кальция и фтора. По последним исследованиям, кальций в зубной пасте бесполезен, а вот ионы фтора, действительно, успевают проникнуть в эмаль и ее укрепить.
Лучше не использовать пасты с антибиотиками, часть всегда попадает в желудок и убивает наших симбионтов. Кроме того, бесконтрольное использование бактерицидов ускоряет эволюцию бактерий, а так можно вывести совсем неубиваемого микроба. Прямо у себя во рту
😕
.
Поэтому стоматологи и химики рекомендуют использоваться зубные пасты с экстрактами трав
🌿
. Помимо запаха они могут обладать противовоспалительным и бактериостатичным эффектом: десны быстрее успокаиваются и бактерии хуже размножаются. | https://t.me/ychemistry/913?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 1,900 | 0 | 1,717,495,441 | 1,736,456,958 | 1,390 | 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| [{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":1248,"end_pos":1251},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":1456,"end_pos":1459},{"ner":"30-40","lemma":"30-40","label":"DATE","start_pos":485,"end_pos":490},{"ner":"40","lemma":"40","label":"NUM","start_pos":488,"end_pos":490},{"ner":"5","lemma":"5","label":"NUM","start_pos":543,"end_pos":544},{"ner":"2","lemma":"2","label":"NUM","start_pos":1672,"end_pos":1673}] | NEUTRAL | rus | NOT SPAM | 358 | 0 | 4 | 1 | 0 | 0 | 43 | 52 | 22 | 8 | 111 | 29 | 66 | true |
118 | null | Разрушители озонового слоя
🌎
Раз уж мы обсудили
принципы, на основе которых работают холодильники
, нельзя пройти мимо связанной с использованием хладагентов
проблемы разрушения озонового слоя
. О том, как формируется озоновой слой, из-за чего появляются озоновые дыры и какую роль в этом процессе играют
фреоны
, предлагаю узнать прямо сейчас
👁
Озоновый слой
— это слой атмосферы Земли с наибольшим содержанием озона. Молекула озона O₃ образуется в результате действия
ультрафиолетового излучения
Солнца на привычный для нас молекулярный кислород
🌤
O₂ + УФ-излучение → 2O:
(образуется высокоактивный
атомарный кислород
)
O₂ + O: → O₃
(который затем реагирует с другой молекулой кислорода, образуя озон)
В равновесии с реакцией получения озона находится процесс его разрушения под действием того же солнечного излучения:
O₃ + УФ-излучение → O₂ + O:
O₃ + O: → 2O₂
(озон разрушается, превращаясь в две молекулы кислорода)
В ходе реакций образования и распада озона
поглощаются самые опасные типы УФ-излучения
, благодаря чему
возможно существование живых организмов
на поверхности нашей планеты
🐸
Существует несколько механизмов разрушения озонового слоя, один из которых упомянут выше. В природе
процессы образования-разрушения сбалансированы
— сколько озона погибает в ходе одной реакции, столько образуется в ходе другой.
Но деятельность человека внесла свои коррективы, сместив баланс, как чашу весов, в сторону разрушения
⚖️
И одну из ключевых ролей в этом процессе сыграли
фреоны
.
Фреоны
— производные метана CH₄ (реже этана С₂Н₆), в которых атомы водорода заменены на
фтор F, хлор Cl или бром Br
. Они были получены американским химиком
То́масом Ми́джли
с целью сделать холодильники безопасными, поскольку ранее в них использовались ядовитые и горючие вещества
👨🏻🔬
Помимо уникальных термических свойств, фреоны
инертны, невзрывоопасны и нетоксичны
, что способствовало их распространению не только в холодильных установках, но и в качестве основы аэрозолей, газовых баллончиков и огнетушителей
🧯
К сожалению, некоторые фреоны (
не все!
), попадая в атмосферу и достигая озонового слоя, вступают в реакцию с озоном,
ускоряя его разрушение
, что и приводит к образованию
озоновых дыр
. Массовое использование фреонов во второй половине прошлого века сильно отразилось на толщине озонового слоя в отдельных регионах. Это наглядно можно проследить на ежегодном мониторинге
🌍
Мировое сообщество не оставило эту проблему без внимания,
ограничив использование
тех фреонов, которые оказывают озоноразрушающее влияние, но в отдельных странах до сих пор производится часть из них (
R-12 и R-22
). И пока организации стараются перейти на безопасные для озонового слоя фреоны,
над Антарктидой
еще долго будет зиять
огромнейшая озоновая дыра
, в образовании которой важную роль сыграло их накопление
☁️
Конечно, в одном ряду с фреонами истончают озоновый слой и другие результаты деятельности человека.
Но вы только задумайтесь, какой огромный вклад в этот процесс внесло небольшое открытие, сделанное одним человеком
🤔 | https://t.me/ychemistry/914?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,300 | 0 | 1,717,567,647 | 1,736,456,958 | 1,389 | 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| NEUTRAL | rus | NOT SPAM | 442 | 0 | 27 | 0.968641 | 0.031359 | 0 | 49 | 52 | 22 | 9 | 149 | 17 | 70 | true |
118 | null | О трансжирах и маргарине
🍟
Сколько страшилок и громких заголовков связано с
вредом маргарина
— неотъемлемого компонента кондитерских изделий, выпечки и фастфуда.
Но как много правды в этих словах?
Давайте разложим всё по полочкам
👩🏻🔬
Напомню, что
молекула жира
состоит из молекулы
глицерина
, к которому присоединены три длинных хвоста
жирных кислот
. Если в строении цепочки жирной кислоты между атомами углерода есть
двойные связи (-С=С-)
, то такие кислоты называются
НЕнасыщенными
. Большинство из них полезны для обмена веществ в нашем организме, в том числе
омега-3,6 и 9
, о которых мы говорили в
этом посте
👍🏻
Если все связи между углеродными фрагментами
одинарные (-С-С-)
, то такие кислоты относят к
насыщенным
. В
умеренных
количествах они
не представляют угрозы
для организма и так же необходимы для нормального обмена веществ, обеспечивая клетки строительным материалом и энергией
🔋
Если
НЕнасыщенные
кислоты преимущественно содержатся в
жидких
растительных маслах
🌻
, то
насыщенные
образуют
твердые
жиры, поступая в организм вместе с мясными и молочными продуктами, колбасными изделиями и сливочным маслом
🍖
На
схеме
ниже показано, что НЕнасыщенные жирные кислоты (те, где есть фрагменты с двойной связью -С=С-) могут быть в
двух конфигурациях
: ЦИС- и ТРАНС-, которые сильно отличаются по свойствам.
В ЦИС-конфигурации
атомы водорода относительно двойной связи находятся
по одну сторону
. Такой вариант жирных кислот наиболее распространен
в природе
и в правильных пропорциях не опасен для нашего организма
🌱
В ТРАНС-жирных кислотах
водороды находятся
по разные стороны
от двойной связи. Эта конфигурация в основном образуется искусственным путём. Например, при сильном нагревании масел и жиров во время жарки фритюра или дезодорации
🍔
Другой вариант образования транс-жиров — промышленное
гидрирование
растительных масел.
Что это такое?
Жидкие растительные масла
(подсолнечное, рапсовое, соевое), содержащие двойные связи -C=C-, обрабатывают
водородом Н₂
при оптимальных давлении, температуре и катализаторе, чтобы получить из них твёрдые жиры. Эта процедура лежала в основе получения
маргарина
—
эмульсии
воды в масле с внесением различных добавок (соль, красители, ароматизаторы)
🥞
В результате
побочных
реакций под влиянием температуры в ходе этого процесса
часть природных ЦИС-кислот переходит в ТРАНС-конфигурацию
😨
К сожалению, из ряда исследований установлено, что
трансжиры увеличивают риск сердечно-сосудистых заболеваний
. Поэтому во многих странах их содержание в пищевой продукции
строго регулируется
, а ВОЗ рекомендует
исключать
из рациона продукты, богатые трансжирами: кондитерский крем, торты, выпечку и фастфуд. Или ограничить их поступление
до 1%
от суточной нормы энергетического потребления —
не более 2-3 граммов
трансжиров
🥯
Но
далеко не весь маргарин — это зло
. В настоящее время масла для маргарина делают твёрдыми с помощью более современного химического процесса — реакции
переэтерификации
, — что позволяют
избежать
образования трансжиров или
снизить
их содержание до минимума
🧪
К тому же, небольшое количество трансжиров естественным образом содержится в
натуральных мясных и молочных продуктах
. Мы вряд ли когда-то сможем полностью обезопасить себя.
Только ответственный подход к питанию поможет сохранить здоровье нашего организма
👁 | https://t.me/ychemistry/915?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,200 | 0 | 1,717,683,095 | 1,736,456,958 | 1,389 | 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118 | null | Духи, парфюм, туалетная вода. В чем разница?
🌺
Косметика и парфюмерия
— это те области, которые
не существовали бы без химической науки
. Каждый аромат, рекламу которого мы видим, — это прежде всего результат работы профессионального химика, разработавшего состав и формулу будущего продукта
👩🏻🔬
Вы наверняка сталкивались со стереотипом —
туалетная вода не такая стойкая как парфюм или духи
. Отчасти это так, но зависимость между стойкостью аромата и концентрацией парфюмерной композиции выполняется
далеко не всегда
.
Почему? Давайте вместе это выясним
👁
Если совсем просто, то
парфюмерия — это растворы ароматических веществ в этиловом спирте
с добавлением красителей и других стабилизирующих агентов. И одна из классификаций парфюмерии основана на
концентрации ароматической составляющей
.
Самый концентрированный вариант, помимо чистых эфирных масел, — собственно
духи
(маркировки
Parfum, Extrait, Pure Perfume, Extrait de Parfum
). Концентрация ароматических веществ может
достигать 40%
. Чаще всего, этот формат представлен лимитированными флаконами небольших объемов и по более высокой цене
💎
Парфюмерная вода
(
Eau de Parfum, EdP
) — самая распространённый формат аромата с концентрацией душистых компонентов
от 10 до 20%.
Отлично подходит для вечернего выхода
💄
В
туалетной воде
(
Eau de Toilettem, EdT
) концентрация композиции поменьше —
около 4-10%
, что как раз оптимально для повседневной носки
👔
И, наконец,
одеколон
(
Eau de Cologne, EdC
) —
легкая
версия популярных ароматов с яркими верхними нотами. Концентрация душистых веществ находится
в районе 5%
🌊
Запах формируется за счёт
испарения
ароматической композиции вместе со спиртом с поверхности тела или одежды. Начальная или верхняя нота состоит из
легколетучих
парфюмерных материалов, например, цитрусовых и травяных нот
🍋
К базовым нотам относятся вещества, которые испаряются намного медленнее (например пачули, сантал, амбра)
🍁
За счёт этой разницы происходит так называемое
раскрытие аромата
👃🏻
Например, если смешать масла кедра и лимона, сначала мы будем чувствовать
оба компонента сразу
, но вскоре лимон, как верхняя нота композиции, начнет чувствоваться меньше, и будет придавать кедру совсем другой оттенок запаха. Благодаря этому аромат меняется во времени
⏳
Безусловно, интенсивность и стойкость аромата будут зависеть от концентрации душистых веществ. Но может быть и так, что парфюмерная вода окружит вас
резким запахом лишь на пару часов
, а шлейф от туалетной воды сохранится
на весь день, хоть и не в такой яркой форме
. Стойкость формируется на основе характерных свойств компонентов и множества других факторов, влияющих на
скорость испарения
. Одни вещества прочнее засядут на вашей коже, а от других не останется и следа к концу дня
💨
Поэтому вы всегда сможете найти
туалетную воду
, которая на вашей коже будет
более стойкой
, чем
парфюмерная вода
.
Слушайте аромат, тестируйте его на себе и ориентируйтесь на собственное восприятие, а не только на надпись на флаконе
🌸 | https://t.me/ychemistry/916?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,000 | 0 | 1,717,834,822 | 1,736,456,958 | 1,390 | 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118 | null | Хлорная кислота – одноосновная безводная кислота, относящаяся к самым сильным, опасным и распространенным химреактивам. | https://t.me/chemistrytg2021/9411?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,400 | 0 | 1,733,660,400 | 1,736,456,959 | 1,353 | 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| null | NEUTRAL | rus | NOT SPAM | 5 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 0 | 0 | 3 | 0 | 1 | true |
118 | null | Играемся с меркурием
⚠️
Острожно, меркурий очень опасен | https://t.me/chemistrytg2021/9414?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,500 | 0 | 1,733,725,200 | 1,736,456,959 | 1,403 | 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| null | NEUTRAL | rus | NOT SPAM | 8 | 0 | 0 | 1 | 0 | 0 | 1 | 1 | 0 | 0 | 2 | 2 | 2 | true |
118 | null | Dobot magician
Потрясающий многофункциональный настольный роботизированный манипулятор с обратной связью для практического обучения. | https://t.me/chemistrytg2021/9415?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,733,736,000 | 1,736,456,959 | 1,403 | 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| [{"ner":"Потрясающий","lemma":"Потрясающий","label":"WORK_OF_ART","start_pos":15,"end_pos":26},{"ner":"обратной связью","lemma":"обратной связью","label":"PER","start_pos":89,"end_pos":104}] | NEUTRAL | rus | NOT SPAM | 13 | 0 | 0 | 0.866667 | 0.133333 | 0 | 4 | 2 | 0 | 0 | 3 | 0 | 1 | true |
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