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Зачем лёд посыпают солью?
❄️
Каждую зиму мы наблюдаем, как на утро после ночных заморозков сотрудники коммунальных служб усиленно
посыпают реагентами застывшие дороги и тротуары
. Интуитивно мы понимаем, для чего они это делают, но химические процессы, стоящие за методом борьбы с гололёдом, вряд ли были известны... До настоящего момента
👩🏻🔬
В свойствах многокомпонентных систем есть интересная закономерность:
температура плавления смеси веществ ниже, чем температура плавления каждого из чистых компонентов по отдельности
. Мы знаем, что температура плавления льда 0℃. Температура, при которой плавится твердый хлорид натрия NaCl около 800℃. А если к воде постепенно добавлять соль, то
вода начнёт превращаться в лёд при температуре заметно ниже 0℃
. И достигнув определенной пропорции мы получим раствор, который превращается в лёд
только при -21℃
(смотри диаграмму).
Ощутимо, правда?
На этом и основан метод борьбы с гололёдом
💡
Если посыпать лёд солью, температура его плавления понизится, и он начнёт таять
. Стоит учитывать, что если температура воздуха ниже -21℃, то лёд так и останется в твёрдом состоянии, ведь даже в смеси с солью он находится при температуре ниже точки замерзания.
Поэтому, если вы видите, как в лютые заморозки кто-то посыпает лёд солью, то знайте, что он делает это зря
. Данный способ работает в мягких зимних условиях, когда столбик термометра не опускается ниже определенной температуры
🌡
Точка на диаграмме, которая отражает минимум температуры замерзания смеси, называется
точкой эвтектики
, а сама температура —
криогидратной
. Необходимым условием существования эвтектической точки является
наличие трёх фаз
: твердая соль, лёд и раствор данного состава. Поэтому температура не будет достигать минимального значения, если исчезнет одна из фаз (растворится вся соль или растает весь лёд)
🤔
Помимо поваренной соли в качестве добавки можно использовать другие вещества, причём криогидратная температура будет меняться. Смесь в определенных пропорциях воды с
калиевой селитрой KNO₃
замерзает при -10,9℃, с
хлоридом магния MgCl₂
— почти при -34℃, а с
хлоридами кальция CaCl₂ и железа FeCl₂
— при -55℃.
Вы можете себе представить водный раствор, который замерзает при такой температуре?
❄️
На этом основано действие
охлаждающих смесей
— смесей льда с солями. Они буквально высасывают тепло из окружения. Их используют для поддержания низких температур в условиях эксперимента, или чтобы быстро охладить напитки
🍸
При работе с такими смесями можно получить холодовые травмы, поэтому нужно быть осторожным
.
К сожалению, использование зимой соляных реагентов
отрицательно
сказывается как на нашей жизни, так и на экологической обстановке. Соль вызывает коррозию многих поверхностей (автомобили, мосты, исторические памятники), портит обувь и сильно раздражает подушечки лап домашних любимцев во время прогулок
🐾
Хлориды в большом количестве попадают в сточные воды и почву, что оказывает
токсичное влияние
на растения и другие организмы. | https://t.me/ychemistry/1015?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,300 | 0 | 1,730,096,607 | 1,736,456,925 | 1,250 | 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| [{"ner":"NaCl","lemma":"nacl","label":"ORG","start_pos":631,"end_pos":635},{"ner":"CaCl₂","lemma":"cacl₂","label":"ORG","start_pos":2106,"end_pos":2111},{"ner":"0","lemma":"0","label":"NUM","start_pos":571,"end_pos":572},{"ner":"800","lemma":"800","label":"NUM","start_pos":642,"end_pos":645},{"ner":"0","lemma":"0","label":"NUM","start_pos":752,"end_pos":753},{"ner":"21","lemma":"21","label":"NUM","start_pos":851,"end_pos":853},{"ner":"21","lemma":"21","label":"NUM","start_pos":1071,"end_pos":1073},{"ner":"₃","lemma":"₃","label":"NUM","start_pos":2018,"end_pos":2019},{"ner":"10","lemma":"10","label":"NUM","start_pos":2035,"end_pos":2037},{"ner":"9","lemma":"9","label":"NUM","start_pos":2038,"end_pos":2039},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":2064,"end_pos":2065},{"ner":"34","lemma":"34","label":"NUM","start_pos":2079,"end_pos":2081},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":2110,"end_pos":2111},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":2125,"end_pos":2126},{"ner":"55","lemma":"55","label":"NUM","start_pos":2134,"end_pos":2136}] | NEUTRAL | rus | NOT SPAM | 433 | 0 | 5 | 0.991023 | 0.008977 | 0 | 44 | 57 | 26 | 6 | 149 | 25 | 83 | true |
118 | null | Почему пахнут цветы?
Химия цветов
— это наука сложная. У каждого цветка свой
химический состав
, свои
летучие органические соединения
. Интересно то, что у цветов нет отдельных молекул, отвечающих за запах растения. У каждой разновидности
свой аромат
, который складывается из сложной вариации молекул.
Поскольку все цветы как
внешне
, так и
по составу различны
друг от друга, я решила разобраться в химии самых популярных цветов. Первой в очереди оказалась
роза
. Это, пожалуй, самый популярный цветок, который дарят всем и всегда. Неповторимый аромат этому цветку придаёт
молекула (-)-цис-розового оксида
. Данная молекула представляет собой изомер розового оксида (всего их обнаружено четыре). Помимо этого, в розе присутствуют ещё два компонента, влияющих на запах это эфирные масла
бета-дамасценон
и
бета-ионон
. Но их мы как правило не способны почувствовать, поскольку порог их летучести более низкий. Остальные соединения, которые придают розе тот самый волшебный аромат:
гераниол, нерол, (-)-цитронеллол, фарнезол, и линалол
.
Следующий цветок, который не менее популярен — это
лилия
. Её аромат в несколько раз сильнее и ярче, чем у розы. Как пахнет лилия, можно почувствовать даже на расстоянии. Кстати, не всем нравиться как пахнет этот цветок. Например, мне он попросту неприятен. Главной составляющей всех лилий считается
(Е)-бета-оксимен и линалол
. Последнее соединение вообще широко распространено в мире растений, его часто добавляют в состав средств ухода за телом и, собственно, в сами
духи
. Еще одно вещество, встречающееся в эфирном масле лилий —
мирцен
. Он также входит в состав некоторых сортов хмеля, употребляемых в пивоварении. | https://t.me/ychemistry/1016?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,300 | 0 | 1,730,280,609 | 1,736,456,925 | 1,301 | 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| null | NEUTRAL | rus | NOT SPAM | 247 | 0 | 2 | 1 | 0 | 0 | 33 | 26 | 21 | 4 | 78 | 18 | 60 | true |
118 | null | Почему вино игристое?
Считается, что пузырьки шампанского образуются вокруг небольших загрязнений на бокале. Однако эти естественные загрязнения обычно слишком малы, чтобы стать такими центрами образования пузырьков,
пузырьки же формируются
на
волокнах целлюлозы
, которые либо присутствуют в окружающей
воздушной пыли
, либо остаются после
натирания бокала
.
🍾
В ста миллилитрах шампанского, содержится около 20 миллионов пузырьков углекислого газа. Только
20% углекислого газа выходит из шампанского в виде пузырьков
. Остальное теряется при прямой диффузии из жидкости.
🥂
Когда пузырьки шампанского идут на поверхность
, с собой они несут
вкус и аромат соединений
, входящих в состав шампанского. Вот некоторые из них:
— Гамма-Декалактон - фруктовый, персиковый, сладкий;
— Метилдегидрожасмонат - сладкий, фруктовый, цветочный;
— Декановая кислота - согревающий, кислый;
— Этилмиристат - сладкий, восковатый;
— Пальмитолеиновая кислота - маслянистый, восковатый.
Приблизительно в
0,75 литровой бутылке шампанского
содержиться около
5 литров углекислого газа
. А давление в бутылке составляет 5-6 атмосфер. Для сравнения в большинстве автомобильных шин приблизительное давление от 1,5 до 2,5 атмосфер.
💨
Количество сахара
, добавляемого после вторичного брожения и выдержки, варьируют, получая
сорта
:
— doux - сладкое;
— demi-sec - полусухое;
— sec - сухое;
— extra sec - экстра-сухое;
— brut - самое сухое;
— extra brut/brut nature/brut zero - чрезмерно сухое (сахар или ликёр не добавляется вовсе).
⚡️ | https://t.me/ychemistry/1017?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,200 | 0 | 1,730,444,726 | 1,736,456,925 | 1,300 | 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| [{"ner":"20","lemma":"20","label":"NUM","start_pos":410,"end_pos":412},{"ner":"20","lemma":"20","label":"NUM","start_pos":458,"end_pos":460},{"ner":"0","lemma":"0","label":"NUM","start_pos":983,"end_pos":984},{"ner":"75","lemma":"75","label":"NUM","start_pos":985,"end_pos":987},{"ner":"5","lemma":"5","label":"NUM","start_pos":1035,"end_pos":1036},{"ner":"5","lemma":"5","label":"NUM","start_pos":1095,"end_pos":1096},{"ner":"6","lemma":"6","label":"NUM","start_pos":1097,"end_pos":1098},{"ner":"1","lemma":"1","label":"NUM","start_pos":1183,"end_pos":1184},{"ner":"5","lemma":"5","label":"NUM","start_pos":1185,"end_pos":1186},{"ner":"2","lemma":"2","label":"NUM","start_pos":1190,"end_pos":1191},{"ner":"5","lemma":"5","label":"NUM","start_pos":1192,"end_pos":1193}] | NEUTRAL | rus | NOT SPAM | 215 | 0 | 2 | 0.957096 | 0.042904 | 0 | 31 | 21 | 4 | 10 | 63 | 7 | 58 | true |
118 | null | Вся правда о пищевых добавках
То, что сегодня практически в каждом продукте
🥙
находятся добавки ни для кого не секрет. Большинство людей больше не обращает внимания на то, есть ли в составе E621. Для тех, кто не знает, именно так обозначается популярная добавка глутамат натрия.
E621 - это глутаминовая кислота, которая относится к 20 природным аминокислотам, из которых построен наш организм. Она присутствует не только в животном белке
🐔
, но и в растительном
🍌
. Например, в орехах и кукурузе
🌽
содержат до 2% глутамата!
Если вы хоть раз ели пищу
🍔
🍟
🍕
с данной добавкой, то отвыкнуть от неё будет не так уж и просто. Всё дело в том, что присутствие глутамата в еде усиливает вкус. Именно поэтому продукты с E621 хочется есть снова и снова. К примеру, употребляя чипсы с избытком глутамата, вы приучаете свой язык к высоким дозам "вкусности"
😋
. Обычная картошка после этого покажется пресной. Большинство взрослых людей способны силой воли отказаться от пищевого "наркотика": избытка сахара, соли и глутамата. А вот ребенок может привыкнуть к чипсам и газировке. В последствии такая "диета" может серьёзно навредить желудку.
Признаюсь честно, я до сих пор завишу от чипсов. Понимаю, что это вредно, но просто не могу отказаться от любимого лакомства
🍟
.
Это вещество для нашего языка
👅
- основой носитель пятого вкуса - "умами" - вкуса белка и мяса. По аналогии: хлорид натрия - "поставщик" соленого
🌭
, глюкоза - сладкого
🍬
, кислоты - кислого
🍋
, а алкалоиды - горького вкусов.
До сих пор мнения учёных по этому поводу двоякое. Никаких "повреждений мозга" от употребления глутамата натрия у вас не будет. Иначе придется признать, что также наш мозг многие тысячелетия повреждают кукуруза
🌽
и бананы
🍌
! С другой стороны, обманывать свои рецепторы тоже неправильно.
Поэтому в следующий раз, когда найдете глутамат (Е620) в пище - не пугайтесь! В отличие от красителей и многих других добавок, он безвреден. Просто питайтесь сбалансировано и всё будет хорошо. Если есть возможность не брать такой продукт, лучше не берите.
Не забудьте, что лайк = спасибо за пост. Хорошей всем недели!
❤️ | https://t.me/ychemistry/1018?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,000 | 0 | 1,730,619,122 | 1,736,456,925 | 1,300 | 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118 | null |
Жирные кислоты. Зачем они нужны?
🐟
Если вы интересуетесь
здоровым питанием
и периодически заглядываете на
iHerb
в поисках витаминов и БАДов, то наверняка натыкались на такую биодобавку, как
омега-3
. Даже если эта тема раньше обходила вас стороной,
это не значит, что знать о ней необязательно
. Потому что жирные кислоты непосредственно
входят в рацион каждого человека
.
А вот для чего они нужны и в каком виде, мы сейчас разберёмся
👩🏻🔬
Как можно понять из названия,
жирные кислоты поступают в наш организм вместе с жирами из пищи
🍳
Они же после ряда биохимических преобразований входят
в состав всех липидных клеточных мембран и выполняют важные функции
. От того, какие жирные кислоты и в каком количестве мы получаем из пищи, напрямую зависит
наше здоровье
: от состояния кожи и сердечно-сосудистой системы до развития плода во время беременности
❤️
С точки зрения
химического строения
, жирные кислоты представляют
длинную углеродную цепочку
🧬
Начинается она с
карбоксильной группы -COOH
, отвечающей за кислотные свойства, от которой тянется зигзагообразный хвост, заканчивающийся
метильным фрагментом -CH₃
. Число групп в хвосте варьируется от 4 до 24. Когда
три
таких огромных молекулы объединяются в одну с помощью простого
глицерина
, мы получаем полноценную
молекулу жира
💦
Начало
углеродной цепочки принято обозначать первой буквой греческого алфавита
α «альфа»
, а ее
конец — ω «омега»
. Если жирные кислоты содержать
только одинарные
простые связи, то такие кислоты называются
насыщенными
.
Они не так полезны для нашего организма, но поговорить о них можно в другой раз
.
Если в углеродной цепочки есть
двойные связи
, то такие жирные кислоты называются
не
насыщенными, и к ним как раз относятся
омега-3,-6,-9
. Цифра в названии говорит о том,
где находится двойная связь
. Например, в омега-6 двойная связь расположена на
6 атоме углерода
, если начинать отсчёт от омега-конца. Положение двойных связей очень важно, потому что от этого зависят свойства
👁
Пожалуй, с сухой теорией мы разобрались. Теперь к более жизненным моментам
Омега-3
относится к
незаменимым
жирным кислотам, то есть наш организм самостоятельно
не может
их вырабатывать —
они должны поступать с пищей
. Основным источником в рационе является морская рыба: рыбий жир, сельдь, лосось, печень трески, красная и черная икра
🐟
Омега-6
также относится к
незаменимым
жирным кислотам, однако мы можем получить
достаточное
её количество из рациона. Омега-6 содержится в растительных маслах, семенах, некоторых овощах и мясе
🥩
Омега-9 не являются незаменимыми
, в отличие от омега-3 и омега-6. Иными словами, наш организм не испытывает дефицита омега-9, так как в нужных количествах
сам способен синтезировать её
из других жирных кислот
🍗
Большинство людей получают из рациона в 15-25 раз больше омега-6, чем омега-3, и это плохо отражается на здоровье
. В лабораторных испытаниях
доказано
, что достаточное количество омега-3 обладает
противовоспалительным
действием, улучшает состояние
кожи
, уменьшает риск заболеваний
сердца
, эффективно при
депрессивных состояниях
и очень важно для нормального
роста детей
👩🏻⚕️
Будем честны
, большинство из нас не ест жирную рыбу необходимые два раза в неделю, поэтому
омега-3 не поступает в нужном количестве вместе с пищей
. А отсюда все последствия
дефицита
, которые вы можете подчеркнуть из абзаца выше
🤔
Хорошо, что в настоящее время существует большой выбор одноименных
биодобавок
, которые способны поддерживать уровень
омега-3
, но перед их применением нужно
обязательно проконсультироваться со специалистом
💊
Поэтому важно обращать внимание на то, что мы едим
🥑 | https://t.me/ychemistry/1019?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 1,800 | 0 | 1,730,800,948 | 1,736,456,925 | 1,301 | 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118 | null | Разноцветное горение хлоридных солей в этаноле. | https://t.me/chemistrytg2021/9511?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,100 | 0 | 1,735,291,201 | 1,736,456,926 | 1,259 | 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| null | NEUTRAL | rus | NOT SPAM | 6 | 0 | 0 | 1 | 0 | 0 | 2 | 0 | 0 | 0 | 3 | 0 | 1 | true |
118 | null | Реакция взаимодействия coca-cola и хлорки для бассейна. | https://t.me/chemistrytg2021/9512?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,100 | 0 | 1,735,302,001 | 1,736,456,926 | 1,250 | 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| [{"ner":"coca-cola","lemma":"coca-cola","label":"ORG","start_pos":23,"end_pos":32}] | NEUTRAL | rus | NOT SPAM | 7 | 0 | 0 | 0.8 | 0.2 | 0 | 0 | 0 | 0 | 0 | 4 | 0 | 1 | true |
118 | null | Кристаллы парацетамола под микроскопом.
Кристаллы осаждаются из раствора на слайде микроскопа и фотографируются в поляризованном свете . | https://t.me/chemistrytg2021/9513?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,735,313,100 | 1,736,456,926 | 1,250 | 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| null | NEUTRAL | rus | NOT SPAM | 17 | 0 | 0 | 1 | 0 | 0 | 1 | 2 | 0 | 0 | 8 | 0 | 2 | true |
118 | null | Вулкан пены
«Зубная паста для слона» — один из самых красивых химических опытов. Внешне это напоминает вулкан пены: ее получается так много, что это наводит на мысли о зубной пасте для слона. | https://t.me/chemistrytg2021/9514?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,100 | 0 | 1,735,323,600 | 1,736,456,926 | 1,250 | 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| null | NEUTRAL | rus | NOT SPAM | 32 | 0 | 0 | 1 | 0 | 0 | 5 | 4 | 3 | 1 | 9 | 3 | 7 | true |
118 | null | Реакция горения различных химических соединений | https://t.me/chemistrytg2021/9515?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,735,366,800 | 1,736,456,926 | 1,254 | 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| null | NEUTRAL | rus | NOT SPAM | 5 | 0 | 0 | 1 | 0 | 0 | 2 | 0 | 0 | 0 | 3 | 0 | 0 | true |
118 | null | Реакция натрия со льдом.
Фактически это тоже самое, что реакция с водой, но с более эффектной концовкой.
При взаимодействии натрия с водой, натрий от тепла реакции расплавляется, шипит и бегает по воде, при этом образуется щёлочь (NaOH) и выделяется газообразный водород (H₂). Водород тут же поджигается от выделяемого тепла, взаимодействует с кислородом в воздухе и образует воду (H₂O). | https://t.me/chemistrytg2021/9516?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,800 | 0 | 1,735,377,601 | 1,736,456,926 | 1,252 | 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| [{"ner":"₂","lemma":"₂","label":"NUM","start_pos":273,"end_pos":274},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":383,"end_pos":384}] | NEUTRAL | rus | NOT SPAM | 58 | 0 | 2 | 0.960526 | 0.039474 | 0 | 4 | 8 | 2 | 0 | 20 | 4 | 16 | true |
118 | null | Новый фторсодержащий кремнийорганический полимер
Ученые из Иркутского института химии им. А.Е. Фаворского СО РАН синтезировали новый растворимый полисилсесквиоксан с фторированными линейными боковыми цепями на основе оригинального мономера триэтокси[3-(2,2,3,3-тетрафторпропокси)пропил]силана, обладающий высокой термо- и химической стабильностью, прочностью и биосовместимостью. Химики изучили полученный полимер с помощью ЯМР-спектроскопии, инфракрасной Фурье-спектроскопии, гель-проникающей хроматографии порошковой рентгеновской дифракции, а также термогравиметрического анализа и дифференциальной сканирующей калориметрии. Показано, что на основе нового соединения можно создавать гидрофобные защитные покрытия и протонпроводящие мембраны, например, для топливных элементов.
Результаты работы опубликованы в журнале Applied Materials Today и открывают новые возможности для разработки инновационных технологий и материалов.
Artem Emel'yanov, Mark Stepanov, Yuliya Bolgova, Olga Trofimova, Galina Prozorova, Alexander Pozdnyakov. Synthesis and characterization of a novel polyfluorinated silsesquioxane polymer as a promising material for creating hydrophobic coatings and proton-conducting membranes. V. 41, 2024, 102516.
https://doi.org/10.1016/j.apmt.2024.102516
Источник:
Кругобайкальская наука
#российскаянаука | https://t.me/chemrussia/5138?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 2,000 | 0 | 1,734,067,814 | 1,736,456,926 | 1,261 | 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118 | null | Google обновил свой
PDF Reader для Google Scholar
, добавив функцию ИИ-конспектов, которая значительно упрощает процесс чтения научных статей.
Эта новая функция представляет собой расширенный оглавление статьи, где для каждого ключевого раздела выделены основные моменты. Теперь пользователи могут быстро просмотреть основные идеи и, при необходимости, углубиться в интересующие их аспекты, такие как методы, результаты или обсуждения. ИИ-конспектов доступны для выбранных статей на английском языке. Чтобы воспользоваться этой функцией, достаточно кликнуть по ссылке PDF в Google Scholar. Если ИИ-конспектов недоступен для конкретного документа, можно запросить его с помощью значка AI Outline.
Кроме ИИ-конспектов, Scholar PDF Reader предлагает множество других возможностей для более быстрого чтения: однокнопочный просмотр цитируемых статей, ссылки на упоминаемые фигуры и таблицы, а также режимы светлой и темной темы.
#googlescholar #ИИ
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@rujournals
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118 | null | В журнале Physical Review E опубликована работа исследователей из Дании, детально изучивших проблему порезов от бумаги. С использованием специально разработанной физической модели они установили, что наибольшую опасность в плане порезов представляют собой листы бумаги толщиной 65 микрометров.
https://journals.aps.org/pre/abstract/10.1103/PhysRevE.110.025003
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118 | null | День в истории химии: день рождения топливного элемента
Ровно 186 лет назад в редакцию
The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science
поступило письмо
On voltaic series and the combination of gases
by platinum из валлийского Суонси. В нем молодой
Уильям Гроув
сообщал о создании первого в истории водородного топливного элемента. Тогда этот тип электрохимического источника тока оказался никому не нужен. Новое рождение топливные элементы пережили уже в 1960-е годы, когда они потребовались для освоения космоса.
#деньвисториихимии
Материал подготовлен ИОНХ РАН для Виртуального музея химии при грантовой поддержке Минобрнауки России в рамках федерального проекта «Популяризация науки и технологий» | https://t.me/chemrussia/5141?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,300 | 0 | 1,734,188,449 | 1,736,456,926 | 1,253 | 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118 | null | https://telegra.ph/Himiya-v-silovyh-trenirovkah-10-03 | https://t.me/incredible_chemistry/333?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 3,100 | 0 | 1,696,395,600 | 1,736,456,926 | 1,260 | 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118 | null | В самом начале Вселенной, произошло то, что ученые называют эпохой рекомбинации. В это время температура Вселенной достаточно снизилась, чтобы протоны и электроны смогли объединиться, образовав водород. В свою очередь, гелий образовался из ядерных реакций, которые происходили в условиях экстремально высоких температур и плотности в первые минуты после Большого Взрыва.
Водород и гелий стали основой для всего химического разнообразия во Вселенной. Именно благодаря их простоте и легкости, эти элементы стали основными строительными блоками для более сложных атомов и молекул. Под воздействием гравитации водородные и гелиевые облака стали сжиматься, образуя первые звезды и галактики. В глубинах звезд водород и гелий претерпевали ядерные реакции, создавая тяжелые элементы, которые стали материалом для формирования новых звезд, планет и, в конечном итоге, жизни.
Водород и гелий, занимая 98% всей материи в наблюдаемой Вселенной, являются фундаментом, на котором строится вся химическая сложность вокруг нас. | https://t.me/incredible_chemistry/334?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,500 | 0 | 1,696,827,600 | 1,736,456,926 | 1,253 | 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| [{"ner":"98","lemma":"98","label":"NUM","start_pos":894,"end_pos":896}] | NEUTRAL | rus | NOT SPAM | 137 | 0 | 4 | 1 | 0 | 0 | 17 | 20 | 5 | 1 | 47 | 3 | 24 | true |
118 | null | При пригорании жиров в кухне распространяется острый запах, который многие считают неприятным. Этот запах вызван химическим веществом под названием акролеин.
Запах пригоревшего жира вызван образованием акролеина из глицерина в процессе нагревания. Когда глицерин нагревается до 280°C, он разлагается, образуя акролеин.
Этот процесс может происходить как при непосредственном нагревании глицерина, так и при его нагревании в присутствии дегидратирующих агентов, таких как сульфат калия, пентоксид фосфора или концентрированная серная кислота.
Акролеин применяется в промышленности для производства других химических соединений, таких как аминокислота метионин.
Эта маленькая химическая реакция в кухонной сковороде открывает перед нами мир химических процессов, происходящих в повседневной жизни. | https://t.me/incredible_chemistry/335?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 3,700 | 0 | 1,696,939,200 | 1,736,456,926 | 1,250 | 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| [{"ner":"280","lemma":"280","label":"NUM","start_pos":278,"end_pos":281}] | NEUTRAL | rus | NOT SPAM | 98 | 0 | 1 | 0.991667 | 0.008333 | 0 | 15 | 12 | 3 | 1 | 42 | 1 | 15 | true |
118 | null | ❗️
Одно место на индивидуальные занятия!
Друзья, имеется возможность взять на индивидуальное обучение биохимии одного ученика (возможно нескольких при организации группы).
Для связи пишите в личные сообщения
@fedor_1999 | https://t.me/simplebestbiochemistry/497?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,800 | 0 | 1,731,042,807 | 1,736,456,926 | 1,250 | 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| [{"ner":"1999","lemma":"1999","label":"NUM","start_pos":215,"end_pos":219}] | NEUTRAL | rus | NOT SPAM | 28 | 0 | 0 | 0.973684 | 0.026316 | 0 | 4 | 3 | 0 | 3 | 11 | 0 | 6 | true |
118 | null | Найдено на просторах соц. сетей
😅
Напомню вам, что:
HbF
- фетальный гемоглобин, работающий в период внутриутробного развития плода и обладающий высоким сродством к кислороду!
HbA1
- гемоглобин взрослого человека, активно синтезируется после рождения ребенка и обладает меньшим сродством к кислороду, чем HbF.
HbA1c
- гликированный гемоглобин, показатель отражающий уровень глюкозы в крови за последние три месяца. Чем выше уровень глюкозы, тем выше гликированный гемоглобин.
А что вы знаете про эти формы гемоглобина? | https://t.me/simplebestbiochemistry/498?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,900 | 0 | 1,731,133,731 | 1,736,456,926 | 1,250 | 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| [{"ner":"1","lemma":"1","label":"NUM","start_pos":178,"end_pos":179},{"ner":"1","lemma":"1","label":"NUM","start_pos":312,"end_pos":313}] | NEUTRAL | rus | NOT SPAM | 73 | 0 | 1 | 0.957447 | 0.042553 | 0 | 12 | 8 | 3 | 1 | 25 | 2 | 13 | true |
118 | null | СУДЬБА ГЛЮКОЗЫ В КЛЕТКЕ
Давно у нас с вами не было классических биохимических тем, поэтому давайте поговорим о БАЗЕ!
Итак, после того как глюкоза попала в клетку, она подвергается следующим метаболическим процессам:
1️⃣
Используется, как источник энергии.
Важная и первоочередная функция!
Сперва идет процесс гликолиза, потом окислительное декарбоксилирование, а в конце цикл Кребса. Все это последовательные реакции, идущие друг за другом, в процессе которых выделяется главная энергомолекула - АТФ!
Этот процесс идет во всех клетках нашего организма!
2️⃣
Синтез гликогена
Гликоген - это депо глюкозы на голодные времена. Резервно-энергетическая форма, снабжающая нас глюкозой во время голода или физической нагрузки.
❗️
Синтез гликогена идет наиболее активно в гепатоцитах (клетки печени) и в скелетной мускулатуре.
3️⃣
Пентозофосфатный путь.
Довольно сложный процесс, но, если кратко - снабжает нас рибозами для синтеза РНК и ДНК, а также синтезирует молекулы NADFH2 (необходимы для синтеза жирных кислот, холестерола, для работы антиоксиданты систем)
4️⃣
Синтез нейтрального жира при избытке!
Да, при избытке, глюкоза идет на синтез жирных кислота и далее нейтрального жира, который откладывается, как энергетический запас на голодные времена!
Синтез жирных кислот и нейтрального жира идет в адипоцитах (клетки жировой ткани) и в гепатоцитах.
Это ключевые пути, куда расходуется и куда откладывается молекула глюкозы в нашем организме!
С учениками мы говорим подробнее о каждом процессе, о его химизме, ферментах, биохимическом смысле. При правильном подходе и последовательном обучении все это оказывается простым и логичным!
#простоосложном | https://t.me/simplebestbiochemistry/499?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,900 | 0 | 1,731,300,881 | 1,736,456,926 | 1,250 | 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| [{"ner":"СУДЬБА ГЛЮКОЗЫ","lemma":"судьба глюкозы","label":"ORG","start_pos":0,"end_pos":14},{"ner":"КЛЕТКЕ\n","lemma":"клетке","label":"ORG","start_pos":17,"end_pos":24},{"ner":"Кребса","lemma":"кребса","label":"PER","start_pos":376,"end_pos":382},{"ner":"Синтез","lemma":"синтез","label":"PER","start_pos":557,"end_pos":563},{"ner":"1","lemma":"1","label":"NUM","start_pos":216,"end_pos":217},{"ner":"2","lemma":"2","label":"NUM","start_pos":553,"end_pos":554},{"ner":"3","lemma":"3","label":"NUM","start_pos":818,"end_pos":819},{"ner":"2","lemma":"2","label":"NUM","start_pos":968,"end_pos":969},{"ner":"4","lemma":"4","label":"NUM","start_pos":1055,"end_pos":1056}] | NEUTRAL | rus | NOT SPAM | 228 | 0 | 10 | 0.996656 | 0.003344 | 0 | 37 | 21 | 14 | 0 | 74 | 15 | 48 | true |
118 | null | Страдания ради науки
☠️
В настоящее время мы воспринимаем многие законы природы как нечто
привычное и обыденное.
Мы смотрим на таблицу Менделеева, не размышляя над тем, как были открыты те или иные химические элементы. Мы видим солнечный свет, заливающий комнату по утрам, не задумываясь о его природе, громадном пути, который он преодолел, и о том, почему мы его вообще видим. А ведь всего пару веков назад
эти мысли не давали покоя учёным
, имена которых нам хорошо известны.
Многим кажется, что
наука — это своего рода развлечение,
приятным результатом которого становятся гениальные открытия. Вот только очень часто поиск истины превращался в
причинение вреда собственному организму
. Сегодня я хочу поделиться с тобой историями трёх ученых, пожертвовавших свои здоровьем во имя науки.
Гениальность
Исаака Ньютона
порой не останавливала его от совершения весьма глупых и опасных поступков. В своей лаборатории Ньютон, вырезав из слоновой кости тонкий изогнутый зонд,
запускал его себе в глаз и давил им на заднюю сторону глазного яблока
, чтобы понять, почему мы вообще видим окружающий мир.
👁
В другой период своих научных интересов Ньютон внимательно смотрел на солнце столько,
сколько мог выдержать,
чтобы выяснить, как это отразится на его зрении. Итогом опыта стало длительное восстановление в условиях кромешной темноты. Скорее всего, благодаря этим экспериментам в дальнейшем было тщательно исследовано негативное влияние прямых солнечных лучей на органы зрения.
Шведский химик
Карл Шееле
является первооткрывателем многих химических соединений. За его именем скрывается обнаружение кислорода, фтора и марганца, получение винной, молочной и щавелевой кислот, а также привычной для нас "марганцовки" и целого списка газов. В современных справочниках в описании свойств напротив многих соединений указывается их вкус и запах.
Есть идеи, откуда учёные знают о вкусе ядовитых веществ?
🧪
Думаю, тут не обошлось без заслуг Карла Шееле, курьезной
страстью которого была тяга пробовать на вкус всё
, с чем он имел дело. Он пробовал токсичные соли
ртути
, смертельно ядовитые
цианиды
и многие другие опасные для здоровья вещества. К сожалению, эта страсть обернулась
смертью
— учёного нашли мертвым на своем рабочем месте в окружении массы ядовитых реактивов
в день его свадьбы.
И третья история связана с именем
Марии Склодовской-Кюри,
которая совместно с мужем, Пьером Кюри, и Анри Беккерелем впервые исследовала явление
радиоактивности.
Открытие радиоактивности стало переломным моментом в науке прошлого столетия, благодаря чему мы сейчас используем энергию атомных электростанций и исследуем наш организм с помощью рентгенографии.
💡
Но история Марии Склодовской-Кюри так же показала, насколько
опасным
может быть влияние радиации на живой организм. Постоянно получая смертельные дозы излучения, Мария погибла от лучевой болезни и лейкемии.
Страшная ирония
открытия радиоактивности заключается в том, что по началу люди и учёные были уверены в
положительном
и даже
лечебном
влиянии гамма-излучения на живые ткани, и
добровольно
облучались колоссальными дозами радиации для укрепления здоровья.
Сейчас же для нас эти истории кажутся полным безумием, но они были объективной реальностью ушедших эпох.
Пытливость ума и страсть к познанию — вот что объединяло учёных, принесших себя в жертву во имя открытий!
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❤️ | https://t.me/ychemistry/1012?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,400 | 0 | 1,729,500,704 | 1,736,456,926 | 1,253 | 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| [{"ner":"Менделеева","lemma":"менделеев","label":"PER","start_pos":135,"end_pos":145},{"ner":"Исаака Ньютона","lemma":"исаак ньютон","label":"PER","start_pos":803,"end_pos":817},{"ner":"Ньютон","lemma":"ньютон","label":"PER","start_pos":914,"end_pos":920},{"ner":"Ньютон","lemma":"ньютон","label":"PER","start_pos":1138,"end_pos":1144},{"ner":"Карл Шееле","lemma":"карл шееле","label":"PER","start_pos":1489,"end_pos":1499},{"ner":"Карла Шееле","lemma":"карл шееле","label":"PER","start_pos":1928,"end_pos":1939},{"ner":"Марии Склодовской-Кюри","lemma":"мария склодовской-кюри","label":"PER","start_pos":2315,"end_pos":2337},{"ner":"Пьером Кюри","lemma":"пьер кюри","label":"PER","start_pos":2366,"end_pos":2377},{"ner":"Анри Беккерелем","lemma":"анри беккерелем","label":"PER","start_pos":2381,"end_pos":2396},{"ner":"Марии Склодовской-Кюри","lemma":"мария склодовской-кюри","label":"PER","start_pos":2651,"end_pos":2673},{"ner":"Мария","lemma":"мария","label":"PER","start_pos":2802,"end_pos":2807}] | NEUTRAL | rus | NOT SPAM | 485 | 0 | 7 | 1 | 0 | 0 | 62 | 60 | 36 | 4 | 152 | 30 | 75 | true |
118 | null |
Серебро. Так ли оно полезно?
👽
Наверняка вы вспомните, как бабушки и дедушки клали в кувшин с водой
ложки, кольца и другие серебряные изделия
, чтобы
обеззаразить
воду и придать ей
целебные
свойства. Попробуем выяснить, насколько этот метод является
эффективным
🍶
Серебро — драгоценный металл
, которому уже давно было найдено применение в
медицине
. До середины прошлого века
нитрат серебра AgNO₃
использовался в качестве наружного
антисептика
под названием
ляпис
. Было обнаружено, что
небольшие
его концентрации
подавляют
жизнедеятельность микробов, прижигают рану и устраняют воспаления.
Концентрированные
растворы представляют
опасность
, так как способны вызвать глубокий химический
ожог
😰
Эти свойства обусловлены
разложением нитрата серебра
на свободное серебро Ag, оксид азота NO₂ и молекулярный кислород O₂.
Однако в настоящее время ляпис
почти не используется из-за своей токсичностью
. Ему на смену быстро пришли более эффективные антисептики
💊
Другой интересной с медицинской точки зрения формой серебра является
коллоидный раствор
, то есть
мельчайшие частицы серебра
размером от 1 нанометра,
равномерно распределенные в воде
. Такой раствор является своеобразным
генератором ионов серебра
, потому что частички металла постепенно окисляются кислородов воздуха и переходят в растворимую форму.
Было установлено, что гарантированно
убивать
некоторые бактерии способны растворы с концентрацией ионов серебра
свыше 150 мкг/л
, что
в три раза больше предельно допустимой концентрации
для человека... Получается, что концентрированные растворы могут не только расправиться с микробами, но и нанести ощутимый
вред нашему организму
🦠
Более того,
серебро — это ядовитый тяжёлый металл
, никак не участвующий в метаболизме и способный накапливаться в органах. При длительном поступлении в организм избыточных доз серебра развивается
аргирия (аргироз)
— болезнь, при которой
кожа принимает серебристый или синевато-серый оттенок
😨
Получается, что
риск подвергнуться токсическому воздействию серебра превышает возможную антибактериальную эффективность
. Поэтому распространение коллоидных серебряных продуктов
регулируется
, а препараты на его основе назначаются лишь в
исключительных случаях
🔬
Но спешу обрадовать
. Серебряная ложка, залегающая на дне кувшина,
никогда не поднимет
концентрацию ионов серебра в воде до значимого уровня
🍴
Поэтому вреда от такой воды никакого. Ровно, как и пользы
И напоследок предлагаю взглянуть на главный симптом аргироза — сине-фиолетовую пигментация. Вот к чему приводит накопление серебра в организме
⬇ | https://t.me/ychemistry/1013?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,200 | 0 | 1,729,677,869 | 1,736,456,926 | 1,250 | 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118 | null | Что такое октановое число?
🚘
Автолюбители и просто читатели, проезжавшие мимо заправок, вы задумывались над тем,
что значат числа на электронном табло?
И я сейчас не о постоянно растущих ценах на бензин, а о загадочных номерах 80, 92, 95 и далее по списку. Эти числа обозначают
октановое число
данной марки бензина, и сейчас мы разберемся, что за ним скрывается
🚀
Вопреки распространённому заблуждению, числа на электронном табло заправочных станций
не говорят напрямую о качества состава топлива.
Бензин, независимо от марки, должен быть чистым, прозрачным, обеспечивать лёгкость запуска мотора, не содержать откровенной отравы и давать в меру токсичный выхлоп. Большинство параметров, включая содержание примесей, для любого бензина одинаково и
строго контролируется официальными документами.
Но одним из важнейших свойств топлива является
детонационная стойкость — способность воспламеняться и сгорать в цилиндрах двигателя без нежелательных взрывных процессов
💥
Именно детонационную стойкость характеризует октановое число.
За эталон детонационной устойчивости принята смесь органических соединений —
изооктана и н-гептана
, причем этих веществ
почти не содержится в самом бензине
. Устойчивость изооктана равна
100
единиц, а н-гептана —
0
. То есть если бензин имеет октановое число, равное
92
, то он детонирует так же, как смесь из
92
частей изооктана и
8
частей гептана. Это как взвешивать колбасу на весах с гирями — мы определяем массу куска по количеству гирь, при этом самих гирь в колбасе не содержится, они выступают в качестве эталона массы
⚖️
Вот только октановое число не получится определить так же легко, как массу или содержание примесей. Это связано с тем, что
реальное топливо не является смесью изооктана и гептана
, поэтому результаты определения зависят от метода — октановые числа можно измерять в лабораторных установках или на реальных автомобилях в процессе езды. Данный анализ является довольно-таки
затратным
по всем параметрам
🤔
Бензин с более высоким октановым числом может выдержать более высокую степень сжатия без досрочного самовоспламенения —
детонации
.
Чем она опасна?
Быстрое сгорание бензина в цилиндрах создает волны давления, которые отражаются от стенок и создают характерный «стук» — металлический звон. Такой процесс
снижает мощность двигателя и ускоряет его износ
. При возникновении сильных детонационных волн двигатель может быть даже
поврежден или разрушен
. Поэтому производители добавляют в топливо специальные присадки, которые увеличивают его устойчивость при сжатии, а так же используют более современные методы переработки нефти
⚙️
Если вы желаете услышать, какой бензин заливать, то
универсального ответа нет
. В первую очередь следует учитывать рекомендации производителя автомобилей. Для
мощных двигателей
применяют исключительно бензин с высокими октановыми числами
🏎
Если залить в него топливо с меньшей устойчивостью, будет сильная детонация и мотор быстро выйдет из строя. В
простые машины
заливать высоко-октановое топливо не имеет смысла
🚗
Расход если и упадет, то незначительно, а лучше машина ехать точно не станет.
И напоследок хочу отметить, что октановое число используется при характеристике
бензина
. Для
дизельного
и
газообразного
топлива используются
цетановое
и
метановые
числа соответственно. Там действуют совершенно иные характеристики воспламеняемости.
Что хорошо для бензинового мотора, для дизеля категорически противопоказано.
Как говорится — каждому своё
😉 | https://t.me/ychemistry/1014?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,000 | 0 | 1,729,927,374 | 1,736,456,926 | 1,250 | 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118 | null | Интересный опыт со свечой.
#интереснаяфизика | https://t.me/chemistrytg2021/9507?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,100 | 0 | 1,735,215,600 | 1,736,456,927 | 1,106 | 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| null | NEUTRAL | rus | NOT SPAM | 5 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 0 | 0 | 3 | 0 | 2 | true |
118 | null | Белый фосфор — самая химически активная модификация фосфора. Он имеет молекулярную кристаллическую решётку, в узлах которой находятся четырёхатомные молекулы тетраэдрического строения.
Температура воспламенения небольшая, всего 35 С, также может загореться от трения, именно поэтому, его держат и режут под водой | https://t.me/chemistrytg2021/9508?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,735,226,400 | 1,736,456,927 | 1,261 | 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118 | null | Горение магния. | https://t.me/chemistrytg2021/9509?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,735,237,200 | 1,736,456,927 | 1,259 | 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| null | NEUTRAL | rus | NOT SPAM | 4 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 0 | 0 | 2 | 0 | 1 | true |
118 | null | Огромное спасибо нашим новым и старым подписчикам, а также тем, кто помогал и помогает развивать наш канал!
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https://t.me/color_quant
https://t.me/ckp_igic | https://t.me/chemrussia/5136?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,700 | 0 | 1,734,067,786 | 1,736,456,927 | 1,259 | 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| null | NEUTRAL | other | NOT SPAM | 32 | 0 | 0 | 0.75 | 0.25 | 0 | 4 | 3 | 1 | 0 | 5 | 1 | 3 | true |
118 | null | #неорганика
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118 | null | #органика #природное
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| [{"ner":"09-24","lemma":"09-24","label":"DATE","start_pos":79,"end_pos":84},{"ner":"24","lemma":"24","label":"NUM","start_pos":82,"end_pos":84}] | NEUTRAL | other | NOT SPAM | 3 | 0 | 0 | 0.833333 | 0.166667 | 0 | 1 | 0 | 0 | 0 | 1 | 0 | 2 | true |
118 | null | #органика #природное
https://telegra.ph/Anabazein-ubijca-nasekomyh-ili-lekarstvo-ot-bolezni-Alcgejmera-09-26 | https://t.me/incredible_chemistry/331?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 3,200 | 0 | 1,695,790,800 | 1,736,456,927 | 1,260 | 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| [{"ner":"09-26","lemma":"09-26","label":"DATE","start_pos":103,"end_pos":108},{"ner":"26","lemma":"26","label":"NUM","start_pos":106,"end_pos":108}] | NEUTRAL | eng | NOT SPAM | 3 | 0 | 0 | 0.833333 | 0.166667 | 0 | 1 | 0 | 0 | 0 | 1 | 0 | 2 | true |
118 | null | В 1995 году в Австралии произошло ужасное происшествие. Химик, работавший в лаборатории, случайно пролил на свои колени от 200 до 230 миллилитров плавиковой кислоты, что аналогично полному стакану воды. Эта кислота попала ему на оба бедра. Мужчина среагировал мгновенно: сперва обмыл пораженные участки водой, а затем прыгнул в хлорированный бассейн, который, к счастью, находился на заднем дворе предприятия. В воде он провел около 40 минут, ожидая скорую помощь.
К сожалению, несмотря на его быстрые действия, состояние мужчины в больнице стало ухудшаться. Через семь дней после инцидента врачи были вынуждены ампутировать ему правую ногу в попытке остановить распространение яда. Однако через 15 дней после несчастного случая химик скончался от полиорганной недостаточности, вызванной действием фтористоводородной кислоты.
Этот трагический случай напоминает нам о том, как важно соблюдать осторожность при работе с опасными веществами, даже если речь идет о небольшом количестве, сравнимом со стаканом воды. | https://t.me/incredible_chemistry/332?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 3,400 | 0 | 1,696,222,800 | 1,736,456,927 | 1,259 | 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118 | null | Как выжить 67 дней без еды в океане?
Разбор с точки зрения биохимии
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Меньше месяца назад всю страну облетела новость о трех туристах, которые пропали в Охотском море и были обнаружены 67 дней спустя в открытом море. Но выжить, к сожалению, удалось только одному путешественнику. Остальные погибли от истощения, так и не дождавшись помощи.
❓
Возникает вопрос, как одному из туристов все таки удалось выжить и как это объяснить с точки зрения биохимических процессов?
В условиях экстремально длительного голода и стресса, следующие факторы способствовали выживанию организма в таких условиях.
Осторожно, длинный пост!
1️⃣
Доступ к питьевой воды
У нас мало конкретной информации, но насколько мы знаем, на лодке сперва был некоторый запас питьевой воды. Также в августе-сентября в регионе пропажи шли регулярные дожди, что без сомнений сыграло благоприятную роль, поскольку путешественники смогли собирать дождевую воду и хранить ее в термосе.
Питьевая вода в таких условиях лимитирующий фактор, поскольку организм не может жить больше 36-48 часов без воды, а морская вода абсолютно не пригодна, поскольку является гиперосмолярной - содержит много растворенных солей, и ее употребление еще больше усилит потребности в чистой воде.
2️⃣
Наличие жировых запасов
Насколько нам известно, выживший мужчина был по своей комплекции довольно «плотным», и хоть мы и не знаем точный состав тела, у нас имеется информация, что до трагедии он имел лишний вес.
В данном случае жир выполнил ту самую эволюционную функцию, ради которой он и был задуман - энергетическое депо. И если с точки зрения профилактики сердечно-сосудистых рисков и сахарного диабета мы стремимся избавиться от избытка жировой массы, то в условиях экстремально длительного голода наличие жирового депо однозначное преимущество. И чем оно больше, тем резервы выше.
👨🔬
🥼
Нейтральный жир подвергается липолизу (распаду) до жирных кислот и глицерола. Жирные кислоты используются, как эффективный энергетический субстрат практически всеми органами, кроме нервной ткани и эритроцитов. Особенно активно используют жирные кислоты - сердце, мышцы, печень. Также печень из жирных кислот синтезирует кетоновые тела, которые становятся важным энергетическим субстратом именно для головного мозга. Спирт глицерол идет на синтез глюкозы. Также при распаде жирных кислот образуется метаболическая вода. Хоть она и не может закрыть всю потребность в воде, но тем не менее вносит свой вклад.
Мышечная ткань также идет в топку, поскольку аминокислоты расходуются, как топливо.
3️⃣
Скудные запасы продуктов
Как пишут журналисты, в лодке оставались хоть и скудные, но тем не менее запасы еды - сухая лапша и горох. Наверняка этих объемов не было достаточно для троих человек, однако любые продукты, хоть и в небольших количествах, дают возможность растянуть собственные энергетические запасы.
4️⃣
Стрессоустойчивость
Не вызывает сомнений, что выживший мужчина испытал колоссальный длительный 67 дневный стресс, но при этом смог продемонстрировать стрессоустойчивость и волю к жизни.
Сам по себе стресс явление здоровое и физиологическое, но если он оказывается длительным и чрезмерным, то тогда превращается в
дистресс
(теория стресса Ганса Селье), который имеет деструктивный характер.
Состояние хронического мощного стресса активирует и истощает симпато-адреналовую систему, а также приводит к повышению уровня кортизола, который в избытке оказывает патологическое действие.
Вот эти четыре ключевых составляющих с точки зрения биохимии и физиологии позволили выжить практические без еды и воды в течение 67 дней в открытом океане.
А что вы думаете по этому поводу? Поделитесь в комментариях
⤵️ | https://t.me/simplebestbiochemistry/495?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,000 | 0 | 1,730,875,779 | 1,736,456,927 | 1,259 | 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| [{"ner":"Охотском море","lemma":"охотский море","label":"LOC","start_pos":154,"end_pos":167},{"ner":"Ганса Селье","lemma":"ганс селье","label":"PER","start_pos":3174,"end_pos":3185},{"ner":"36-48","lemma":"36-48","label":"DATE","start_pos":1035,"end_pos":1040},{"ner":"67","lemma":"67","label":"NUM","start_pos":11,"end_pos":13},{"ner":"67","lemma":"67","label":"NUM","start_pos":186,"end_pos":188},{"ner":"1","lemma":"1","label":"NUM","start_pos":618,"end_pos":619},{"ner":"48","lemma":"48","label":"NUM","start_pos":1038,"end_pos":1040},{"ner":"2","lemma":"2","label":"NUM","start_pos":1230,"end_pos":1231},{"ner":"3","lemma":"3","label":"NUM","start_pos":2518,"end_pos":2519},{"ner":"4","lemma":"4","label":"NUM","start_pos":2832,"end_pos":2833},{"ner":"67","lemma":"67","label":"NUM","start_pos":2931,"end_pos":2933},{"ner":"67","lemma":"67","label":"NUM","start_pos":3545,"end_pos":3547}] | NEUTRAL | rus | NOT SPAM | 523 | 0 | 6 | 1 | 0 | 0 | 82 | 68 | 26 | 14 | 165 | 32 | 78 | true |
118 | null | #о_рабочем
Аорто-коронарное шунтирование за 1 минуту
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Отрабатываем навык имплантации шунта
🥼
А вы знаете для чего проводится такая операция? | https://t.me/simplebestbiochemistry/496?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,000 | 0 | 1,730,959,041 | 1,736,456,927 | 1,259 | 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| [{"ner":"1","lemma":"1","label":"NUM","start_pos":44,"end_pos":45}] | NEUTRAL | rus | NOT SPAM | 20 | 0 | 1 | 1 | 0 | 0 | 3 | 3 | 2 | 1 | 6 | 0 | 3 | true |
118 | null | Как работает холодильник?
☃️
Невозможно представить современную жизнь без холодильных установок. Только попробуйте сосчитать,
сколько раз в день вы открываете дверцу холодильника
.
Число вас удивит
. А как приятно зайти
в помещение с кондиционером
после палящего летнего солнца
🌇
Все эти блага основаны на
фундаментальных физико-химических законах и свойствах особых веществ
.
Давайте поговорим о том, по какому принципу работают холодильники
.
Начнём с процессов, которые протекают внутри
компрессионного холодильника
— наиболее распространенного в быту охлаждающего устройства. В нём главным переносчиком тепла является
специальное вещество — хладагент
❄️
Компрессор
засасывает хладагент в виде
пара
💨
и сжимает его за счёт повышения давления, при этом температура хладагента возрастает. После сжатия вещество попадает в
конденсатор
, где
нагретый хладагент остывает
, отдавая тепло во внешнюю среду. Если вы имели дело со старыми холодильниками, то наверняка замечали
змееподобную трубку
на его задней стороне, которая довольно-таки сильно нагревалась во время работы. В нём
хладагент с выделением тепла конденсируется, то есть превращается в жидкость
💧
Жидкое вещество под давлением поступает через
узкий капилляр
или регулируемый вентиль в
испаритель
, где за счёт резкого
уменьшения давления
происходит испарение жидкости
🌬
Так как испарение — это процесс, протекающий с
поглощением тепла
, хладагент
отнимает
его из окружающей среды через стенки испарителя, за счёт чего происходит охлаждение.
Чтобы вам было легче представить это явление, вспомните, какое чувство прохлады вы испытываете,
выходя на сушу из тёплого водоёма
🏖
Ваше тело охлаждается за счёт
испарения капель воды с поверхности кожи
. За счёт аналогичных процессов наш организм охлаждается, когда мы потеем, чтобы избежать перегрева. Это лежит в основе естественной терморегуляции.
Таким образом,
в конденсаторе
хладагент под воздействием высокого давления переходит в жидкое состояние,
выделяя тепло
, а в
испарителе
под воздействием низкого давления вскипает и переходит в газ,
поглощая тепло
. Затем хладагент снова поступает через компрессор в конденсатор, и
цикл многократно повторяется
🔁
Общая схема довольно-таки проста
Стоит отметить, что большое значение имеет
чистота хладагента
: вода и примеси могут засорить капилляр или повредить компрессор
🙅♀️
Примеси могут образовываться в результате
коррозии
внутренних стенок трубопроводов холодильника, а влага может попасть при его
заправке
. Поэтому в каждом холодильнике имеется фильтр-осушитель, наполненный адсорбентом, который защищает капиллярную трубку.
Также существует несколько вариантов компоновки. Наиболее привычной для нас является
«европейская»
, когда морозильная камера находится
снизу
, а холодильная —
сверху
. Вариант с обратным расположением камер классифицируют как
«азиатский»
. Компоновку, в которой холодильное и морозильное отделение расположены
по всей высоте устройства
, называют
«американской»
или
side-by-side
. | https://t.me/ychemistry/1008?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,500 | 0 | 1,728,641,929 | 1,736,456,927 | 1,106 | 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| null | NEUTRAL | rus | NOT SPAM | 408 | 0 | 3 | 0.994565 | 0.005435 | 0 | 46 | 68 | 17 | 2 | 138 | 19 | 68 | true |
118 | null |
Аэрозоли и спреи
💨
Приходя в аптеку, мы сталкиваемся с
многообразием форм лекарственных препаратов
👩🏻⚕️
Помимо привычных
таблеток, мазей и капель
, на витринах представлены
спреи и аэрозоли
, как более новые и удобные способы доставки действующих веществ.
Давайте выясним, в чем принципиальная разница между двумя похожими на первый взгляд формами
👀
Внутри
аэрозольного баллончика
под
давлением
находится раствор действующего вещества в сжиженном
пропелленте
. И если с действующими веществами всё понятно — они меняются в зависимости от назначения аэрозоля, — то
в качестве пропеллента используется ограниченный ряд газов
🧪
Когда-то в качестве газового наполнителя баллончиков использовались
фреоны
, но после исследования их разрушающего действия на озоновый слой, на смену пришли более экологичные вещества. В
бытовых аэрозолях
— лаки для волос, дезодоранты, освежители воздуха — используются
углеводородные пропелленты
(
пропан, н-бутан и изобутан
). К сожалению, эти газы очень
горючи и взрывоопасны
, поэтому обращение с ними требует особых правил. По этой же причине для распыления веществ в экстремальных условиях продолжают использовать
более инертные и негорючие
фреоны (например, в огнетушителях)
🧯
Для распыления
пищевых продуктов
(например, взбитые сливки
🍦
) используют
закись азота N₂O или углекислый газ CO₂
.
Когда мы нажимаем на аэрозоль, внутри открывается клапан, и содержимое баллончика выбрасывается
за счет высокого давления газа
. Взамен
часть жидкого пропеллента внутри испаряется, возвращая давление в баллончике на исходную отметку
🧭
На выходе из аэрозоля мы получаем облако из мельчайших частичек жидкости, распределенных в воздухе.
В свою очередь
спреи не содержат пропеллента
, а высвобождение содержимого происходит за счет
нажатия на поршень микронасоса
. При этом давление во флаконе и вне его одинаковое. Это позволяет брать спреи в
самолеты
, походы, подвергать действию солнечных лучей и температуры, не опасаясь за повреждение флакона
✈️
Спрей так же равномерно распределяет частицы действующего вещества, только их размер чуть
больше
(
от 5 микрометров
) по сравнению с частицами
аэрозольного распылителя
(
от 2 до 5 мкм
)
💦
Дозировать вещество с помощью аэрозоля очень непросто
— размер порции зависит от того, как долго мы жмём на кнопку. К тому же, если плохо встряхнуть баллон перед использованием, можно получить пустую струю газа. В случае спрея всё намного удобнее.
Один пшик — чёткое дозирование
💨
Лекарственные препараты в формате спреев и аэрозолей облегчают доставку действующего вещества и способ нанесения. Согласитесь, что
использовать пантенол на место ожога из аэрозольного баллончика или лекарство от насморка в виде спрея намного удобнее и быстрее, чем в виде мази или капель
🤔
Зная принципиальные отличия аэрозоля от спрея, вы всегда сможете выбрать наиболее подходящий для вас формат
😉 | https://t.me/ychemistry/1009?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,100 | 0 | 1,728,971,746 | 1,736,456,927 | 1,106 | 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118 | null | Какую соль выбрать?
🧂
Соль
— самая распространённая пищевая добавка, без которой не обходится ни одно блюдо в ресторане или на кухне
🥗
При этом, химический состав её предельно прост и знаком каждому.
Откуда тогда на полках в магазине берётся такое разнообразие хлорида натрия? И почему стоимость одной упаковки может быть в десять раз больше, чем другой?
Начнём с того,
как добывают пищевую соль
.
ГОСТ выделяет четыре способа производства
, которые указывают на упаковке:
Каменная соль
добывается в шахтах или карьерах из соляных залежей, не подвергаясь тепловой и водной обработке
⛏
Выварочную соль
выпаривают из соляных растворов. Бывает так, что строить целую шахту для добычи соли невыгодно. Тогда бурят небольшие скважины, заливают их водой, которая растворяет соль, затем рассол выкачивают, фильтруют и вываривают
💨
Встречаются также естественные подземные рассолы, с которыми поступают аналогичным образом.
Садочную соль
осаждают из соленой воды в специальных бассейнах. В теплый сезон в местностях с подходящим климатом вода испаряется из искусственных плоских водоёмов, оставляя следы соли
🏝
И, наконец,
самосадочная соль
— это та, которая оседает естественным образом на дне водоема. Чаще всего это озерная соль. На самом известном в России соляном озере —
Баскунчак
— получают до 80 % от общей добычи соли в стране
🗻
Согласно одному из основных законов химии —
закону постоянства состава
— определенное химически чистое соединение,
независимо от способа получения
, состоит из одних и тех же химических элементов. Вне зависимости от того,
как был получен хлорид натрия
, он будет иметь однозначную формулу NaCl и обладать одинаковыми химическими свойствами
👁
Другая сторона вопроса —
сорт соли
, который определяет внешний вид, цвет, вкус, запах и состав продукта.
ГОСТ выделяет четыре сорта
, для каждого из которых указано минимальное содержание содержание чистого хлорида натрия: экстра —
99,7%
, высший —
98,4%
, первый —
97,7%
, второй —
97%
.
Остальные проценты — это следование содержания
других минералов
, характерных для места добычи соли (кальций, магний, калий, железо и т.д.). Эти элементы необходимы для нормальной работы нашего организма, правда получаем мы их в основном из другой пищи
🍎
Как можно заметить,
соль ЭКСТРА
— это практически химически чистый реактив, подходящий для экспериментов в лаборатории
🧪
А соль
первого и второго сорта
может иметь тёмные вкрапления соединений железа и других минералов, которые никак не сказываются на её вкусовых качествах.
И другая характеристика соли — это
помол
. Занятно, что при использовании крупной соли блюдо
сложнее пересолить
, потому что в щепотке крупного помола хлорида натрия на самом деле меньше, чем в щепотке мелкого из-за наличия
пустот между кристалликами
💎
Вывод
. Как бы ни старался
современный маркетинг
, вкус дорогой морской соли ничем
не будет отличаться
от дешёвой каменной. Чем ниже сорт, тем больше содержание других
полезных элементов
, а чем крупнее помол, тем лучше соль ведёт себя
при готовке
. И не стоит
бояться
тёмных частиц — это лишь вкрапления
других минералов
.
Но обращайте внимание
на состав
😉
Иногда в соль добавляют компоненты
против слёживания и комкования
. Если вы желаете купить
натуральный продукт
, выбирайте упаковку с
наиболее кратким и лаконичным составом
👩🏻🔬 | https://t.me/ychemistry/1010?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,300 | 0 | 1,729,061,955 | 1,736,456,927 | 1,262 | 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| [{"ner":"🧂\nСоль","lemma":"🧂\nсоль","label":"ORG","start_pos":20,"end_pos":26},{"ner":"России","lemma":"россия","label":"LOC","start_pos":1245,"end_pos":1251},{"ner":"NaCl","lemma":"nacl","label":"ORG","start_pos":1618,"end_pos":1622},{"ner":"80","lemma":"80","label":"NUM","start_pos":1292,"end_pos":1294},{"ner":"99","lemma":"99","label":"NUM","start_pos":1904,"end_pos":1906},{"ner":"7","lemma":"7","label":"NUM","start_pos":1907,"end_pos":1908},{"ner":"98","lemma":"98","label":"NUM","start_pos":1921,"end_pos":1923},{"ner":"4","lemma":"4","label":"NUM","start_pos":1924,"end_pos":1925},{"ner":"97","lemma":"97","label":"NUM","start_pos":1938,"end_pos":1940},{"ner":"7","lemma":"7","label":"NUM","start_pos":1941,"end_pos":1942},{"ner":"97","lemma":"97","label":"NUM","start_pos":1955,"end_pos":1957}] | NEUTRAL | rus | NOT SPAM | 506 | 0 | 9 | 0.998471 | 0.001529 | 0 | 84 | 49 | 20 | 16 | 151 | 22 | 88 | true |
118 | null | Чем опасны инертные газы?
🎈
Думаю, многие из вас хотя бы раз в жизни вдыхали
шары с гелием
, чтобы наложить на свой голос весёлый звуковой эффект.
Надеюсь, что после прочтения сегодняшнего поста вам будет, о чём задуматься, прежде чем сделать это снова
🤔
Еще со школы мы знаем об
элементах восьмой группы таблицы Менделеева — благородных или инертных газах,
— которые ни с чем не реагируют и ассоциируются у нас в голове с
безопасными
. Есть ряд так называемых
физиологически инертных газов
, которые не вступают в химические реакции со средой нашего организма. Если
угарный газ CO
прочно связывается с гемоглобином в крови,
хлор Cl₂ и фосген COCl₂
вызывают сильнейший ожог лёгочной ткани и разрушают алвьеолы, то
азот N₂, благородные газы
(гелий He, неон Ne, аргон Ar, криптон Kr) и другие инертные при обычных условиях соединения (например,
гексафторид серы SF₆
)
не вызовут такого разрушающего эффекта
.
Их опасность скрывается в другом
👀
Вдыхаемый нами воздух в норме содержит
78% азота N₂, 21% кислорода O₂ и 1% составляют все остальные газы
— углекислый CO₂, аргон Ar и другие. Когда мы вдыхаем избыток инертного газа, он выступает в роли
«разбавителя»
, уменьшая содержание кислорода в воздухе и, соответственно, в крови.
Развивается гипоксия
😨
Вдыхая воздух, в котором кислорода содержится
в два раза меньше
, человек чувствует сильное головокружение, он теряет возможность объективно оценивать происходящее, возрастает пульс и частота дыхания, синеют губы
🥴
При концентрации кислорода в воздухе
от 4 до 6% потеря сознания наступает через 40 секунд
, а
минуты
будет достаточно, чтобы наступила смерть
⏳
Всё коварство заключается в том, что физиологически инертные газы
не имеют запаха или вкуса и не вызывают болезненных ощущений при вдыхании
. Когда наступает дискомфорт, связанный с недостатком кислорода, человек
не успевает понять, с чем это связано
.
Из-за недостаточной информированности об удушающих свойствах азота и других инертных газов происходят
несчастные случаи
. От массовой потери сознания на вечеринке с жидким азотом до смерти в ходе криотерапии с использованием того же жидкого азота. Удушье гелием случается реже и в основном связано с его промышленным использованием.
Удушье азотом
является одним из методов
смертной казни
и используется для безболезненного оглушения животных на фермах.
Сегодняшний текст
не является
призывом отказаться от использования шаров с гелием и
не написан
с целью напугать вас.
Я хотела лишь напомнить, что понятие техники безопасности применимо к большинству ситуаций, даже когда мы имеем дело с безобидными на первый взгляд веществами
👩🏻🔬 | https://t.me/ychemistry/1011?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,400 | 0 | 1,729,260,691 | 1,736,456,927 | 1,259 | 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| NEUTRAL | rus | NOT SPAM | 399 | 0 | 7 | 0.97451 | 0.02549 | 0 | 45 | 58 | 20 | 9 | 120 | 11 | 61 | true |
118 | null | Эксперимент с пероксидом водорода.
⠀
Концентрированная перекись водорода смешивается с жидким мылом, после чего в неё добавляют катализатор — обычно йодид калия.
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Катализатор вызывает быстрое разложение перекиси на воду и кислород; последний, собираясь в пузырьки, резко увеличивает объём смеси, создавая в мыльном растворе пузырьки и пену. | https://t.me/chemistrytg2021/9504?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,735,150,800 | 1,736,456,928 | 1,111 | 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| null | NEUTRAL | rus | NOT SPAM | 47 | 0 | 0 | 1 | 0 | 0 | 5 | 7 | 1 | 0 | 18 | 2 | 11 | true |
118 | null | Необыкновенно четкий снимок ударной волны
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Поразительно резкий фотоснимок ударной волны удалось получить канадскому фотографу во время экспериментов, связанных со взрывотехникой.
#интереснаяфизика | https://t.me/chemistrytg2021/9505?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,735,194,000 | 1,736,456,928 | 1,106 | 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| null | NEUTRAL | rus | NOT SPAM | 22 | 0 | 0 | 1 | 0 | 0 | 5 | 3 | 0 | 0 | 9 | 2 | 4 | true |
118 | null | От рельсотрона не спасет никакая броня.
Вы наверняка слышали про рельсотрон, орудие стреляющее снарядами со скоростью в 7 раз превышающую скорость звука без какого либо пороха, только с помощью электричества. | https://t.me/chemistrytg2021/9506?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,735,204,800 | 1,736,456,928 | 1,106 | 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| [{"ner":"7","lemma":"7","label":"NUM","start_pos":120,"end_pos":121}] | NEUTRAL | rus | NOT SPAM | 30 | 0 | 0 | 1 | 0 | 0 | 0 | 4 | 1 | 1 | 12 | 1 | 4 | true |
118 | null | Китайские исследователи создали новый адсорбент на основе двух наиболее распространенных в природе полисахаридов - хитина и целлюлозы. Полученный биополимерный композитный материал обладает высокой пористостью и способен улавливать из окружающей среды частицы микропластика, что было продемонстрировано авторами на примере частиц полистирола, полиметилметакрилата, полипропилена и полиэтилентерефталата. Эффективность удаления микропластика из модельных сред составила 98-99,9%.
https://www.science.org/doi/10.1126/sciadv.adn8662
#науказарубежом | https://t.me/chemrussia/5126?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,500 | 0 | 1,733,983,230 | 1,736,456,928 | 1,106 | 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| [{"ner":"10.11","lemma":"10.11","label":"DATE","start_pos":507,"end_pos":512},{"ner":"98-99","lemma":"98-99","label":"DATE","start_pos":469,"end_pos":474},{"ner":"99","lemma":"99","label":"NUM","start_pos":472,"end_pos":474},{"ner":"9","lemma":"9","label":"NUM","start_pos":475,"end_pos":476},{"ner":"1126","lemma":"1126","label":"NUM","start_pos":510,"end_pos":514},{"ner":"8662","lemma":"8662","label":"NUM","start_pos":525,"end_pos":529}] | NEUTRAL | rus | SPAM | 54 | 0 | 0 | 0.984849 | 0.015152 | 0 | 8 | 8 | 1 | 4 | 24 | 1 | 7 | true |
118 | null | Расшифрована структура распространенного консерванта
Ученые из Института общей и неорганической химии им. Н.С. Курнакова РАН установили строение ряда пищевых добавок в твердом состоянии, что позволило оценить безопасность их использования при повышенных температурах и на свету. Химикам удалось синтезировать и изучить кристаллы сорбата калия (Е202), сорбата кальция (Е203) и сорбата натрия (Е201). Исследования показали, что полученные кристаллы устойчивы к нагреванию и УФ-облучению, а, следовательно, безопасны как консервирующие агенты и неприхотливы в хранении.
Результаты работы, поддержанной Российским научным фондом (№ 23-23-00208), опубликованы в журнале Crystal Growth & Design и могут найти применение в пищевой промышленности.
Paulina Kalle, Stanislav I. Bezzubov, Lyudmila G. Kuzmina, and Andrei V. Churakov; New Insights into the Structure, Thermal Properties, and Photostability of Industrially Relevant Salts of Sorbic Acid. Crystal Growth & Design, 2024, 24 (21), 9173-9181.
https://doi.org/10.1021/acs.cgd.4c01197
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Научный микроблог Минобрнауки России
#российскаянаука #ионх | https://t.me/chemrussia/5127?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,600 | 0 | 1,733,983,252 | 1,736,456,928 | 1,106 | 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118 | null | В ИОНХ РАН состоялась вторая научная сессия «Химия соединений платиновых металлов и перспективные материалы на их основе» Научного совета РАН по неорганической химии в ИОНХ РАН
В мероприятии приняли участие специалисты в области технологий переработки минерального и вторичного сырья, ведущие исследователи в области получения функциональных материалов на основе платиновых металлов.
Список докладов:
Ляхов Н. З., Григорьева Т.Ф.
«Механохимический перевод в растворимые формы
химически инертных металлов – спутников платины»
Шевельков А. В.
«К вопросу о создании термоэлектрических материалов на
основе полярных интерметаллических соединений рутения»
Парфенов В. А.
(ОАО «Красноярский завод цветных металлов
имени В.Н. Гулидова») Сорбционное разделение ДМ и НБЭ из бедных по ДМ растворов сложного состава
Кузнецов А. Н.
«Дизайн новых твердотельных соединений платины и
палладия со сложными архитектурами»
Таран О. П.
«Перспективные Ru-содержащие катализаторы для
гетерогенно-каталитических процессов в водной среде»
Козлова Е. А.
«Использование комплексных соединений платиновых
металлов для создания фотокатализаторов выделения
водорода»
Темеров С. А.
(ОАО «Красноярский завод цветных металлов
имени В.Н. Гулидова»)
«Вывод меди из аффинажного цикла»
Гущин А. Л.
«Координационные соединения платиновых металлов с
редокс-активными лигандами»
Беззубов С. И.
«Синтез, строение, свойства и применение
циклометаллированных комплексов иридия(III) и родия(III)»
#конференция #ионх | https://t.me/chemrussia/5133?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 2,500 | 0 | 1,733,983,743 | 1,736,456,928 | 1,106 | 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118 | null | #органика
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118 | null | #природное #органика
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| [{"ner":"https://telegra.ph/Dgliceraldegid-09-18","lemma":"https://telegra.ph/dgliceraldegid-09-18","label":"ORG","start_pos":22,"end_pos":61},{"ner":"09-18","lemma":"09-18","label":"DATE","start_pos":56,"end_pos":61},{"ner":"18","lemma":"18","label":"NUM","start_pos":59,"end_pos":61}] | NEUTRAL | other | NOT SPAM | 3 | 0 | 0 | 0.857143 | 0.142857 | 0 | 1 | 0 | 0 | 0 | 1 | 0 | 2 | true |
118 | null | Друзья, делимся с вами первым уроком из большого курса по обмену белков и аминокислот!
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@ysavnin | https://t.me/simplebestbiochemistry/491?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,900 | 0 | 1,730,353,034 | 1,736,456,928 | 1,108 | 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| null | NEUTRAL | rus | NOT SPAM | 43 | 0 | 0 | 0.964912 | 0.035088 | 0 | 2 | 6 | 2 | 0 | 16 | 2 | 8 | true |
118 | null | БЕЛОК И ПОЧКИ
Важнейшей функцией почечного фильтра является его
селективность по отношению к белкам плазмы
- альбуминам и глобулинам.
Почечный фильтр здоровых почек имеет очень маленькие отверстия - фенестрации, которые гораздо меньше диаметра белка, а потому белки плазмы просто не могут «просочиться» сквозь мембрану и остаются в плазме.
🔬
Это важнейший механизм, который сберегает белок в крови, именно поэтому в норме в общем анализе мочи белка не должно быть совсем или максимум могут быть его следы (до 0,033 г/л).
🚨
А вот появления белка в моче - тревожный звонок, указывающий, что почечная мембрана повреждена и необходимо срочно разбираться в причинах повреждения и принимать меры.
Картинка выше
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хорошо демонстрирует принцип работы почечного аппарата по отношению к белкам! | https://t.me/simplebestbiochemistry/492?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,000 | 0 | 1,730,440,225 | 1,736,456,928 | 1,106 | 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| [{"ner":"БЕЛОК","lemma":"белок","label":"ORG","start_pos":0,"end_pos":5},{"ner":"ПОЧКИ\nВажнейшей функцией почечного фильтра","lemma":"почки\nважный функция почечный фильтр","label":"ORG","start_pos":8,"end_pos":50},{"ner":"0","lemma":"0","label":"NUM","start_pos":509,"end_pos":510},{"ner":"033","lemma":"033","label":"NUM","start_pos":511,"end_pos":514}] | NEUTRAL | rus | NOT SPAM | 117 | 1 | 4 | 1 | 0 | 0 | 15 | 12 | 4 | 2 | 46 | 7 | 17 | true |
118 | null | ПОСЛЕДНИЕ ДНИ УЧАСТИЯ
Друзья, напоминаю, что сегодня и завтра последние дни, когда вы еще можете успеть принять участие в нашем большом
курсе по обмену белков и аминокислот
!
🚨
Напоминаю, что ключевая цель обучения - сформировать прочный фундамент понимания метаболизма и научиться интегрировать его в практику!
Ознакомиться с первым уроком и форматом подачи материала вы можете
тут.
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Имеется возможность приобретения в рассрочку без участия банка посредника.
Для связи и приобретения писать моему ассистенту
@ysavnin
Вся информация, подробный план, цены и прочее на сайте:
http://simplebiochemistry.tilda.ws/menu | https://t.me/simplebestbiochemistry/493?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,800 | 0 | 1,730,615,360 | 1,736,456,928 | 1,108 | 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118 | null | ЖИЗНЬ БЕЗ СЛАДКОГО!
❓
Может ли организм прожить, полностью исключив сахар и легкоусвояемые углеводы?
Тема довольно популярная и уже порядком избитая, но давайте ответим на этот вопрос исключительно с точки зрения биохимии.
1️⃣
Во-первых, уровень глюкозы будет поддерживаться за счет распада длинноцепочечных углеводов (например, крахмала), присутствующих в нашем рационе.
Крахмал - это очень большая и длинная цепочка молекул глюкозы, соединенных между собой. В отличие от обычного сахара (сахароза), она распадается медленно, поскольку сама по себе большая и крупная, а потому и уровень глюкозы повышается постепенно, медленно.
2️⃣
Во-вторых, даже если мы исключим вообще все углеводы, то уровень глюкозы все равно будет поддерживаться на уровне физиологической нормы. Каким образом?
😉
Запустятся механизмы синтеза эндогенной глюкозы! Сперва в топку пойдет гликоген, а когда он закончится, то начнется
глюконеогенез
- путь синтеза глюкозы de novo из аминокислот, спирта глицерола (вследствие распада Жиров) и лактата. На этом механизме кстати работает кетодиета, когда резко ограничиваются углеводы из рациона, но организм, тем не менее, не впадает в гипогликемию.
Таким образом, полное прекращение употребления короткоцепочечных углеводов не является для организма проблемой, поскольку будут работать собственные биохимические механизмы, направленные на поддержание нормального уровня глюкозы.
🧑🏼⚕️
Человеческий организм тысячами лет развивался в условиях регулярного голода и энергетического дефицита. Пищевой сахар был однозначно в абсолютном дефиците, поэтому даже его полное исключение не приведет ни к каким фатальным последствиям и осложнениям! | https://t.me/simplebestbiochemistry/494?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,400 | 0 | 1,730,785,349 | 1,736,456,928 | 1,108 | 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| [{"ner":"Жиров","lemma":"жир","label":"LOC","start_pos":1001,"end_pos":1006},{"ner":"1","lemma":"1","label":"NUM","start_pos":223,"end_pos":224},{"ner":"2","lemma":"2","label":"NUM","start_pos":629,"end_pos":630}] | NEUTRAL | rus | NOT SPAM | 220 | 0 | 4 | 0.992982 | 0.007018 | 0 | 26 | 24 | 6 | 0 | 74 | 24 | 47 | true |
118 | null | Химия жемчуга
🐚
В любом правиле есть исключения
😉
Так и среди драгоценных камней, определенных федеральным законом, затаилась белая ворона.
Жемчуг не является минералом
. Его относят к
биогенным соединениям
— веществам, представляющим продукты жизнедеятельности живых организмов. Но хоть природный жемчуг и не добывают в шахтах, он является драгоценным камнем в одном ряду с алмазами, изумрудами и другими сверкающими минералами
💍
Как формируется жемчужинка и из чего она состоит?
Образование жемчуга является
защитной реакцией
организма моллюска на любое инородное тело, попавшее в раковину. Теоретически, все виды моллюсков, имеющих раковину, могут создавать жемчуг, но коммерческой ценностью обладают только
перламутровые
жемчужинки, а их образуют лишь двустворчатые и некоторые брюхоногие виды
🐚
Моллюски имеют особую складку тела —
мантию
, — которая состоит в том числе из множества
железистых
клеток, вырабатывающих различные слои раковины. В норме эти клетки вырабатывают
перламутр
— особое вещество с характерным нежным разноцветным отливом, образующее внутренний слой раковины. Но как только внутрь раковины попадает песчинка, моллюск старается обезопасить себя и обволакивает инородное тело перламутром, давая начало будущей жемчужине. Она может срастись со створкой раковины или, если инородное тело попадает внутрь мантии, образовать свободную округлую жемчужину
🔘
Сам по себе перламутр состоит одновременно из
минерального и органического
вещества. Тончайшие пластинки карбоната кальция
CaCO₃
(в форме минерала
арагонита
) разделяются слоями эластичного рогового вещества — смеси
биополимеров
(хитин и шелкоподобные белки). Блеск и игра света на жемчуге обусловлены тонкой структурой перламутровых слоёв
✨
Природный жемчуг
встречается во множестве оттенков: от белого или кремово-розового до черного. Голубые являются самыми редкими и наиболее привлекательными за счёт свинцово-серого отлива. Окраска определяется
видом моллюска и условиями
, в которых созревала жемчужина: солёность воды и температура
🌊
Как известно, жемчуг можно выращивать в промышленных масштабах. Для этого создают
искусственные
условия, внедряя раздражители в тело моллюска и провоцируя образование жемчужин. И если природный жемчуг преимущественно состоит из множества тончайших слоёв перламутра, то в культивируемом внутренний объем по большей части занят специальной затравкой. Эта разница обуславливает различия в стоимости природного жемчуга и специально выращенного
💸
Хочу также отметить, что жемчужины могут
«стареть»
. С течением времени органическое вещество в составе слоев перламутра разрушается, и жемчужина теряет структуру и характерный блеск. К счастью, для этого требуется
не одно столетие
. Но всё же ювелирные украшения из жемчуга, особенно музейные экспонаты, стараются хранить в подходящих условиях
👩🏻🔬 | https://t.me/ychemistry/1003?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,600 | 0 | 1,727,603,157 | 1,736,456,928 | 1,106 | 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| [{"ner":"CaCO₃","lemma":"caco₃","label":"ORG","start_pos":1501,"end_pos":1506},{"ner":"₃","lemma":"₃","label":"NUM","start_pos":1505,"end_pos":1506}] | NEUTRAL | rus | NOT SPAM | 377 | 0 | 5 | 0.997912 | 0.002088 | 0 | 65 | 56 | 12 | 2 | 133 | 10 | 62 | true |
118 | null | Эмульгаторы. Для чего их добавляют в продукты?
🥛
Лецитин, сорбит, гуаровая или ксантовая камедь
... Вы наверняка встречали эти компоненты
в составе продуктов питания или косметических средств
. Сегодня мы выясним,
что скрывается за загадочными названиями
👩🏻🔬
Одними из самых популярных
пищевых добавок
являются
эмульгаторы — вещества, обеспечивающие создание эмульсии из несмешивающихся жидкостей
🚰
Что же такое эмульсия?
Если
по-научному
, то
эмульсия
— это дисперсная система, то есть смесь из нескольких жидкостей,
не способных раствориться друг в друге
или химически взаимодействовать, а потому сохраняющихся в виде
мельчайших капель
💦
А если
по-бытовому
, то
эмульсия
— это однородная смесь воды и жидкостей (масло, жир), которые
не растворяются
в воде
🍺
Проще всего эмульсию представить и понять на примере
молока
— самой распространённой природной эмульсии
🐄
В молоке
капли молочного жира равномерно распределены в воде
. Если оценивать эмульсию невооружённым взглядом, то такая система не отличается от однородной жидкости, потому что капли нерастворённого вещества имеют
микроскопический размер
🔬
А теперь давайте сами приготовим эмульсию
. Добавим к стакану воды чуть поменьше стакан растительного масла. Как бы мы не старалась и не перемешивали нашу смесь, она останется двухфазной:
слой масла будет находиться над слоем воды
🥃
И вот тут нам помогут эмульгаторы
. Добавляя верно подобранный эмульгирующий компонент при постоянном перемешивании, мы можем добиться
однородной
жидкой смеси, в которой
масло равномерно распределено в воде
👍🏻
Сами по себе эмульгаторы выполняют роль
поверхностно-активных веществ
, которые
уменьшают поверхностное натяжение
на границе раздела масла и воды. Благодаря этому слой масла разделяется на
множество мельчайших капель
и равномерно распределяется в воде
💧
В том же молоке
помимо воды и молочного жира
присутствует третий компонент —
комплекс белка и лецитина
, — который выступает в роли эмульгатора и отвечает за привычную консистенцию
🥛
В промышленных масштабах эмульгаторы получают как из
природного
сырья
🌱
, так и
синтетическим
путём
🧪
Например,
пектин
, используемый в производстве десертов, майонеза и молочных продуктов, получают из яблочных и цитрусовых выжимок
🍏
Лецитин
, добавляемый к шоколаду и выпечке, получают из соевого масла, а различные
полисорбаты
— из кокосового и пальмового
🥥
К синтетическим эмульгаторам относятся
производные жирных кислот, глицерина и продукты их этерификации
⚗️
Помимо продуктов питания, эмульгаторы являются
неотъемлемым компонентом косметики и лекарственных препаратов
— они позволяют делать жидкие смеси из тех компонентов, которые сами по себе не смешиваются друг с другом
💄
💊
Не стоит бояться натуральных эмульгаторов
в пищевых изделиях — большинство из них не несут никакого вреда, за исключением случаев индивидуальной непереносимости. Синтетические эмульгаторы наш организм воспринимает
аналогично натуральным
, поэтому они
безопасны
в тех количествах, в которых их добавляют к продуктам питания
😉 | https://t.me/ychemistry/1004?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,500 | 0 | 1,727,856,650 | 1,736,456,928 | 1,110 | 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| [{"ner":"Лецитин","lemma":"лецитин","label":"PER","start_pos":49,"end_pos":56}] | NEUTRAL | rus | NOT SPAM | 429 | 0 | 7 | 1 | 0 | 0 | 57 | 55 | 28 | 2 | 125 | 26 | 61 | true |
118 | null | Тяжелая вода
💧
Опасна ли она для нашего организма?
Думаю, все слышали о том, что вода может быть
«тяжелой»
. А кто-то до сих пор боится несколько раз кипятить воду в чайнике, якобы она постепенно превращается в яд. Давайте разберёмся,
чем этот опасный тяжеловесный зверь отличается от обычной воды и развеем главный миф
💦
Начнём с важного понятия. В природе у химических элементов существуют
изотопы
— разновидности атомов, которые имеют
одинаковый заряд ядра и число протонов
, но у этих разновидностей
разное количество нейтронов
в ядре и следовательно
разная масса
. Изотопы не отличаются друг от друга с точки зрения химии, то есть вступают в одинаковые реакции, но отличаются с точки зрения физики — у изотопов разные температуры кипения, энергии связи с другими атомами и стабильность — все мы слышали о радиоактивных изотопах, но об этом поговорим в другой раз.
Вернемся к нашей жидкости. Дело в том, что водород, входящий в состав молекулы воды имеет
три изотопа
, каждый из которых получил собственные названия: H —
протий, D — дейтерий и T — тритий
(радиоактивен). Ядро самого распространённого изотопа — протия H — состоит из единственного протона. Ядро тяжелого водорода — дейтерия D состоит уже из одного протона и одного нейтрона, то есть его масса почти в два раза больше. Этот эффект разницы в массе особенно заметен только в случае водорода. Радиоактивный тритий мы пока опустим, но по аналогии можно догадаться, что его ядро состоит так же из одного протона, но к нему прибавляется уже два нейтрона, масса увеличивается втрое.
Дейтерий естественным образом встречается в природе, вот только его содержание
ничтожно мало — на 6500-9100 атомов привычного протия H приходится всего один атом экзотического дейтерия D.
🤔
Тяжёлая вода вместо двух атомов обычного водорода H содержит два атома его тяжёлого изотопа. Формула тяжёлой воды обычно записывается как D₂O. Внешне такая вода выглядит как обычная — бесцветная, без вкуса и запаха. Отличия проявляются на уровне физико-химических свойств: лёд из тяжелой воды тает почти при +4°С, а закипает при +101°С. Также все реакции в среде тяжелой воды протекают
ощутимо медленнее.
Это является причиной, почему её считают ядовитой
⚗
Да, погибла не одна мышь, которую поили тяжелой водой в лабораторных испытаниях. Когда 25% воды в организме млекопитающего замещалось на тяжелую, животное становилось стерильным, при больших концентрациях — погибало. В испытаниях с человеком установлено, что без особого вреда для здоровья можно выпить три стакана чистой дейтерированной воды, которая выведется из организма через несколько дней
🥛
А теперь хочу напомнить, насколько
ничтожно мало
естественное содержание тяжелого изотопа водорода — ни о каком негативном влиянии таких концентраций не идёт речи.
А теперь развеем миф, который многие из вас наверняка слышали
🤨
При длительном кипячении концентрация дейтерия в воде увеличивается, что делает такую воду ядовитой.
Численное опровержение этой гипотезы: чтобы повысить естественное содержание дейтерия в воде всего в десять раз нужно выпарить столько тонн вод, что в этом числе будет
30 нулей.
Это в сотни миллионов раз больше содержания воды на Земле в целом
🌏
Вкус воды если и меняется после кипячения, то не из-за накопления дейтерия, а из-за разрушения различных примесей.
Да и к тому же, если бы можно было так легко синтезировать тяжелую воду, она бы не стоила
так дорого.
1 грамм дейтерированной воды стоит 1 евро. Немалая сумма выходит за стаканчик.
💰
Не забывайте ставить
❤️
🙂 | https://t.me/ychemistry/1005?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,500 | 0 | 1,728,118,785 | 1,736,456,928 | 1,109 | 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| [{"ner":"Земле","lemma":"земля","label":"LOC","start_pos":3150,"end_pos":3155},{"ner":"00-91","lemma":"00-91","label":"DATE","start_pos":1646,"end_pos":1651},{"ner":"6500","lemma":"6500","label":"NUM","start_pos":1644,"end_pos":1648},{"ner":"9100","lemma":"9100","label":"NUM","start_pos":1649,"end_pos":1653},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":1875,"end_pos":1876},{"ner":"4","lemma":"4","label":"NUM","start_pos":2045,"end_pos":2046},{"ner":"101","lemma":"101","label":"NUM","start_pos":2066,"end_pos":2069},{"ner":"25","lemma":"25","label":"NUM","start_pos":2280,"end_pos":2282},{"ner":"30","lemma":"30","label":"NUM","start_pos":3088,"end_pos":3090},{"ner":"1","lemma":"1","label":"NUM","start_pos":3383,"end_pos":3384},{"ner":"1","lemma":"1","label":"NUM","start_pos":3418,"end_pos":3419}] | NEUTRAL | rus | NOT SPAM | 543 | 0 | 16 | 0.986607 | 0.013393 | 0 | 63 | 65 | 27 | 23 | 169 | 31 | 84 | true |
118 | null | Без SLS и SLES. Что скрывается за этой надписью?
Я думаю, ты часто замечал надпись
"Без SLS и SLES"
, обведённую в зелёный кружочек на упаковке шампуня, геля для душа или пенки для умывания. Давай разберёмся, что значит сочетание этих букв и почему маркетологи так активно его используют.
SLS и SLES
— это сокращение названий
sodium lauryl sulfate
и
sodium laureth sulfate
(лаурил- и лауретсульфаты натрия), которые представляют собой одни из самых распространенных ПАВов в косметической продукции. И для того, чтобы понять их назначение, давай рассмотрим, что такое
ПАВ
.
Задача поверхностно-активных веществ — удалять грязь с поверхности.
Если в качестве поверхности выступает наша кожа, ПАВ проникают в жир, который естественным образом скапливается на ней, встраиваются в него, дробят на мелкие частицы, обволакивают и смывают вместе с водопроводной водой. Стоит понимать, что
очищающих средств без ПАВ просто не может существовать
, но есть разные типы, отличающиеся друг от друга по строению и воздействию.
Анионные ПАВ
— самый распространённые и в то же время самый агрессивные. К этому типу относятся те самые
сульфаты
, которых многие остерегаются. Их достоинствами являются
невысокая стоимость и эффективность — способность образовывать объемную пену.
Сочетание этих качеств побуждает производителей бюджетных средств использовать анионные ПАВы в своей продукции. Но
главный минус — сульфаты раздражают кожу — особенно отражается на обладателях чувствительной и проблемной кожи.
После использования средств с анионными ПАВами наблюдается чувство сухости и стянутости.
Второй тип —
катионные ПАВ
— используется в составах для смягчения агрессивного действия анионных.
Третий тип —
неионогенные ПАВ
— обладает
самым мягким воздействием
, поэтому их включают в состав детской косметики и средств для чувствительной и проблемной кожи. Но тут мы сталкиваемся с
главным минусом — неиногенные ПАВ почти не пенятся,
поэтому их чаще всего используют в комбинации с анионными.
И последний тип —
амфотерные ПАВ
— так же максимально мягко воздействует на кожу и обладает бактерицидными свойствами.
Исследователи считают, что
сульфаты в целом безопасны
для здоровья человека, потому что они используются в тех средствах, которые быстро наносятся и так же быстро смываются (нам же не нужно оставлять шампунь на волосах в течение нескольких часов). Агрессивность анионных ПАВ может стать решающим фактором в выборе средств для чувствительной и проблемной кожи, но это не значит, что стоит выбрасывать все шампуни и гели с SLS и SLES в составе.
Производители качественной продукции добавляют в состав другие типы ПАВ для уменьшения раздражающего действия SLS.
Если ты видишь в составе после sodium lauryl sulfate мягкие ПАВы — Cocamidopropyl Betaine, Decyl Glucoside и многие другие — то скорее всего очищающее действие такого средства
сбалансировано.
Ты можешь погуглить другие названия мягких ПАВ, потому что их действительно много.
Надпись "Не содержит SLS" — это скорее маркетинговый ход, поэтому не стоит ориентироваться на неё при выборе косметики.
Читай составы, изучай компоненты и обязательно ориентируйся на реакцию своей кожи.
Не забудьте, что
❤️
= спасибо за пост. Проведите это воскресенье с пользой! | https://t.me/ychemistry/1006?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,500 | 0 | 1,728,295,436 | 1,736,456,928 | 1,110 | 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| [{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":466,"end_pos":469},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":567,"end_pos":570},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":690,"end_pos":693},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":903,"end_pos":906},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":1022,"end_pos":1025},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":1350,"end_pos":1353},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":1529,"end_pos":1532},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":1601,"end_pos":1604},{"ner":"ПАВ","lemma":"пава","label":"ORG","start_pos":1703,"end_pos":1706},{"ner":"SLS","lemma":"sls","label":"ORG","start_pos":2517,"end_pos":2520},{"ner":"ПАВ","lemma":"пав","label":"ORG","start_pos":2607,"end_pos":2610},{"ner":"SLS","lemma":"sls","label":"ORG","start_pos":2649,"end_pos":2652},{"ner":"Decyl Glucoside","lemma":"decyl glucoside","label":"ORG","start_pos":2745,"end_pos":2760},{"ner":"Читай","lemma":"читать","label":"LOC","start_pos":3049,"end_pos":3054}] | NEUTRAL | rus | NOT SPAM | 472 | 0 | 25 | 0.960549 | 0.039451 | 0 | 56 | 69 | 26 | 1 | 117 | 26 | 83 | true |
118 | null | Пюре или фри?
СМИ давно говорят о том, что в зеленой картошке содержатся яды, но так ли это на самом деле? Сегодня расскажу вам всё, что знаю про зеленый картофель.
Любой зародыш будущего растения
🌱
может находиться в трех состояниях.
"
Спящем
", во время которого все биохимические процессы спят и зародыш ожидает нужные условия.
"
Самопереваривающим
". Он включается при наступлении теплой и влажной погоды, которая благотворно влияет на запуск процесса развития. В этом состоянии рост происходит за счёт питательных веществ самого клубня/семени.
"
Аутотрофном
", бесплатная энергия от солнца. В этом случае в кожуре и ростках клубня активно синтезируется хлорофилл, преобразующий солнечный свет во внутриклеточную энергию. Этот режим, очень важен для любого растения.
🥔
Зеленый картофель относится к семейству пасленовых, как и помидоры. В нем находится токсичный гликоалкалоид - соланин. Но боятся не стоит, поскольку он находится только в кожуре. А также он разрушается при варке или засолке.
Активный синтез соланина начинается в зеленеющих клубнях, поэтому такую кожуру следует срезать особенно тщательно, чтобы ядовитое вещество не попало в ваш организм. Некоторые и вовсе выбрасывают зеленую картошку, но это делать не обязательно.
Летальная доза (LD50) соланина для млекопитающих примерно 0,1 г на кг веса. По расчетам это означает, что взрослому человеку опасно съесть больше 1,5 кг (!) сырой зеленой картофельной кожуры или ростков.
Не думаю, что на практике кому-нибудь придёт в голову есть сырую картошку, кожуру или ростки. Поэтому не нужно боятся зеленый картофель, при правильном его приготовлении он абсолютно безвреден. | https://t.me/ychemistry/1007?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,600 | 0 | 1,728,467,238 | 1,736,456,928 | 1,109 | 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118 | null | Машина для производства льда. | https://t.me/chemistrytg2021/9500?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,735,107,600 | 1,736,456,929 | 1,150 | 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| null | NEUTRAL | rus | NOT SPAM | 4 | 0 | 0 | 1 | 0 | 0 | 0 | 0 | 0 | 0 | 3 | 0 | 1 | true |
118 | null | Плавка металла при помощи магнитной индукции. | https://t.me/chemistrytg2021/9501?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,735,118,400 | 1,736,456,929 | 1,145 | 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| null | NEUTRAL | rus | NOT SPAM | 6 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 0 | 0 | 4 | 0 | 1 | true |
118 | null | В этом эксперименте в огонь помещают калиевую соль, и можно увидеть пурпурно-фиолетовый цвет. Фотоны калия имеют длину волны, соответствующую пурпурному цвету. Так работают фейерверки, яркие цветные вывески и люминесцентные лампы. | https://t.me/chemistrytg2021/9502?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,735,129,200 | 1,736,456,929 | 1,250 | 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| null | NEUTRAL | rus | NOT SPAM | 30 | 0 | 1 | 1 | 0 | 0 | 8 | 5 | 0 | 0 | 12 | 2 | 6 | true |
118 | null | Самодельное ракетное топливо
Твердое ракетное топливо содержит окислитель и топливо, которые тонко перемешаны и спрессованы в форму. В этом случае используются перхлорат аммония, порошок магния и обычная строительная пена. | https://t.me/chemistrytg2021/9503?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,735,140,000 | 1,736,456,929 | 1,111 | 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| null | NEUTRAL | rus | NOT SPAM | 29 | 0 | 1 | 1 | 0 | 0 | 6 | 4 | 1 | 0 | 11 | 1 | 4 | true |
118 | null | Приказом Министра промышленности и торговли Российской Федерации заместитель директора ИОНХ РАН, чл.-корр. РАН А.А. Вошкин награжден Почетной грамотой Минпромторга России.
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| [{"ner":"Российской Федерации","lemma":"российский федерация","label":"LOC","start_pos":44,"end_pos":64},{"ner":"ИОНХ","lemma":"ионх","label":"ORG","start_pos":87,"end_pos":91},{"ner":"РАН","lemma":"ран","label":"ORG","start_pos":92,"end_pos":95},{"ner":"РАН","lemma":"ран","label":"ORG","start_pos":107,"end_pos":110},{"ner":"А.А. Вошкин","lemma":"а.а. вошкин","label":"PER","start_pos":111,"end_pos":122},{"ner":"Минпромторга","lemma":"минпромторга","label":"ORG","start_pos":153,"end_pos":165},{"ner":"России","lemma":"россия","label":"LOC","start_pos":166,"end_pos":172}] | NEUTRAL | rus | NOT SPAM | 21 | 0 | 4 | 1 | 0 | 0 | 2 | 1 | 0 | 0 | 7 | 0 | 3 | true |
118 | null | Управляемый магнитный материал на основе спин-поляризованных структур для высокоточной электроники
Сотрудники Института общей и неорганической химии им. Н.С. Курнакова РАН совместно с учеными из Физического института им. П.Н. Лебедева РАН и НИЦ «Курчатовский институт» разрабатывают высокочувствительные управляемые магнитные материалы на основе спин-поляризованных структур. Исследования проводятся на полупроводниковых соединениях (антимониды группы АIIIВV и арсениды кадмия) в качестве материала матрицы, а в качестве ферромагнетиков используются антимонид и арсенид марганца. Применение полупроводников ввиду высокой подвижности носителей заряда предпочтительно при создании спин-поляризованных структур.
Результаты работы, выполненной при поддержке РНФ (проект № 21-73-20220), опубликованы в журнале Vacuum и могут быть использованы при разработке устройств магнитной памяти, средств связи, сенсоров и микроэлектроники нового поколения.
A.I. Ril’, L.N. Oveshnikov, A.V. Ovcharov, S.F. Marenkin. Synthesis and phase composition of Cd3As2 Dirac semimetal crystals doped with Cr. Vacuum 230, 113692 (2024). DOI: 10.1016/j.vacuum.2024.113692.
https://doi.org/10.1016/j.vacuum.2024.113692
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Mendeleev.info
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118 | null | Исследователи из Нанкайского университета (Китай) синтезировали кластер, состоящий из 68 атомов сурьмы и имеющий форму тора. Предложенный синтетический подход может быть также применен для синтеза циклических молекул, состоящих из атомов других элементов.
https://pubs.acs.org/doi/abs/10.1021/jacs.4c09102#
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118 | null | Все что нужно знать химику о нейросети Яндекса
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| [{"ner":"Яндекса","lemma":"яндекс","label":"PER","start_pos":39,"end_pos":46}] | NEUTRAL | rus | NOT SPAM | 11 | 0 | 0 | 1 | 0 | 0 | 1 | 1 | 2 | 0 | 2 | 0 | 9 | true |
118 | null | #органика #синтез
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| [{"ner":"08-23","lemma":"08-23","label":"DATE","start_pos":59,"end_pos":64},{"ner":"23","lemma":"23","label":"NUM","start_pos":62,"end_pos":64}] | NEUTRAL | other | NOT SPAM | 3 | 0 | 0 | 0.833333 | 0.166667 | 0 | 0 | 0 | 0 | 0 | 2 | 0 | 2 | true |
118 | null | Нам кажется что, лимон неотделим от рыбы. Но его роль состоит не сколько в том, чтобы ароматизировать, а скорее в том, чтобы маскировать запах: мякоть рыбы содержит большое количество свободных аминокислот (их больше, чем в мясе), способных легко разлагаться. Метиламин, триметиламин и некоторые серосодержащие соединения пахнут тухлой рыбой! Кроме своего вкуса, лимонная кислота, содержащаяся в лимоне, помогает расщеплению этих ароматических соединений, а значит, и устранению неприятных запахов. Правильная (низкая) температура приготовления рыбы значительно ограничивает расщепление аминокислот: рыба, приготовленная при 52 градусах прекрасно прожарена и...хорошо пахнет. | https://t.me/incredible_chemistry/323?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 3,400 | 0 | 1,693,371,601 | 1,736,456,929 | 1,106 | 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| [{"ner":"Метиламин","lemma":"метиламин","label":"PER","start_pos":260,"end_pos":269},{"ner":"52","lemma":"52","label":"NUM","start_pos":625,"end_pos":627}] | NEUTRAL | rus | NOT SPAM | 85 | 0 | 0 | 1 | 0 | 0 | 9 | 15 | 5 | 3 | 27 | 6 | 25 | true |
118 | null | #о_рабочем
❗️
Осторожно, выше кадры хирургических влажных препаратов!
Специальность «сердечно-сосудистая хирургия» требует навыков всего многообразия хирургических манипуляций на сердце и сосудах, поэтому хоть я и занимаюсь хирургической аритмологией, мы тренируем навыки всех вмешательств!
👨⚕️
Вчера была выполнена
пластика митрального клапана на свином сердце опорным полукольцом
из PTFE материала (безопасный и надежный).
Как вы знаете, камеры сердца
🫀
соединены клапанами, которые регулируют направление тока крови, и не дают ей возможность течь в противоположном направлении.
Направление тока крови следующее: предсердие
➡️
желудочек
➡️
магистральный сосуд.
⚠️
В том случае, когда кольцо клапана растягивается и расползается, клапан перестает быть герметичным, начинает сбрасывать кровь или «подтекать», как говорят хирурги. Это называется клапанной недостаточностью.
В случае, когда недостаточность становится тяжелой, можно хирургически стабилизировать клапан, сузить его отверстие и восстановить функцию путем имплантации опорного кольца или полукольца, который выполняет роль жесткого скелета и как бы подтягивает створки клапана друг к другу.
На фотографиях выше
⬆️
вы как раз можете увидеть этапы имплантации опорного полукольца! | https://t.me/simplebestbiochemistry/489?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,900 | 0 | 1,730,266,218 | 1,736,456,929 | 1,250 | 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| null | NEUTRAL | rus | NOT SPAM | 158 | 0 | 3 | 0.995475 | 0.004525 | 0 | 23 | 25 | 10 | 0 | 56 | 7 | 40 | true |
118 | null | https://disk.yandex.ru/i/ZiZKlHpQgoUTqg | https://t.me/simplebestbiochemistry/490?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,900 | 0 | 1,730,353,023 | 1,736,456,929 | 1,106 | 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118 | null | Оранжевая ягода
Хурма - это удивительная, мясистая ягода, которая известна всем своими вяжущими свойствами. Сегодня я попытаюсь объяснить, почему эта ягода оранжевого цвета вяжет на вкус.
Когда хурма ещё не созрела в ней содержится большое количество танинов, которые и вызывают вяжущие свойства. Эти соединения при контакте со слизистой оболочкой полости рта сворачивают белки, вызывая вяжущее ощущение, также они снижают секрецию слюнных желез и сужают капилляры.
При дозревании плодов танины распадаются, соответственно, хурма меньше "вяжет" или перестает совсем. Поэтому если вы купили хурму и она вяжет вам язык, то скорее всего она просто не дозрела.
Танины также встречаются в очень крепком чае, красном вине, кожуре винограда, семенах, древесине и других продуктах. Также используются как пищевой краситель Е181.⠀⠀
Как уменьшить количество танинов?
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Подождать пару дней, пока хурма дозреет естественным путем
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Подержать несколько минут под горячей водой (при повышенной температуре должно произойти разложение части дубильных веществ)
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Заморозить (скорее всего, это немного поможет, потому что уменьшится скорость реакции с белками). | https://t.me/ychemistry/1000?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,900 | 0 | 1,727,073,891 | 1,736,456,929 | 1,150 | 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| [{"ner":"181","lemma":"181","label":"NUM","start_pos":816,"end_pos":819}] | NEUTRAL | rus | NOT SPAM | 159 | 0 | 1 | 1 | 0 | 0 | 20 | 26 | 12 | 1 | 52 | 16 | 37 | true |
118 | null | Мёд — пчелиная рвота?!
Хоть это и не сильно связано с химией (но связь все-таки есть!), я считаю, что посты про мёд нужно завершить именно этой темой. Ведь это, как минимум, интересно!
Пчелиный улей – это настоящий социум; целый городок, занимающийся сельским хозяйством. Необычайно умный и слаженный механизм. Начало сезона пчелы начинают с уборки в улье, после – отправляют разведчиков в поля, чтобы собрать информацию по источникам пищи
Потом полевые пчелы вылетают на рейд и собирают хоботком нектар с цветков во второй специальных желудок. Чтобы заполнить свой «бак» до конца, им нужно облететь больше 1000 цветков! При этом весь нектар может весить как сама пчела
😱
Прилетев в улей, пчелы срыгивают нектар в рот другой рабочей пчеле, та, пожевав немного, срыгивает в рот другой и так далее до нужного эффекта. Каждая пчелка добавляет таким образом свои ферменты, которые помогают расщепить сложные сахара (в основном, сахарозу) на моносахариды (в основном, на глюкозу и фруктозу). А теперь шок-контент: мы любим есть пчелиную рвоту
😅
После пережеванный нектар заливается в соты, и трудолюбивые пчелы начинают сушить его крыльями (изначальный процент воды ~70% уменьшается до ~20%). Это происходит в течение 1-3 дней, дальше уже пчеловод начинает собирать соты
Вообще, пчелы готовят мёд для себя, чтобы питаться им зимой. Получается, что люди, забирая постоянно его, стимулируют их собирать еще больше мёда, ведь зима близко, а запасы все еще пусты. И вот мне стало интересно, как защитники животных относятся к такой эксплуатации
🤔 | https://t.me/ychemistry/1001?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,900 | 0 | 1,727,246,944 | 1,736,456,929 | 1,250 | 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118 | null | Электроны Ким Кардашьян можно найти где-то рядом с тобой
Кликбейт?
Нет, только научный факт.
Давай разбираться. А я помогу тебе в этом. Это самый важный пост, который выходил на этом канале. Потрать
3-4 минуты
на чтение — и ты поймешь
одну из самых красивых научных теорий
.
Вспомните уроки химии в 8 классе, когда учитель на доске рисовал
ядро, вокруг которого по орбитам вращались электрончики
. «Кекс с изюмом», планетарная модель, электронные облака... Знакомые слова? Круто!
Лучше всего строение и описание атома объясняет
квантовая механика
. Это новый раздел теоретической физики, который занимается описанием свойств систем с электронно-ядерным строением. Поведение атомов, электронов, фотонов и элементарных частиц... в общем, всё то, с чем плохо справляется физика в рамках классической механики.
Как и многие другие научные дисциплины, вся квантовая механика опирается на несколько главных постулатов, одним из следствий которых является
уравнение Шрёдингера
.
Важный нюанс. В рамках квантовой механики микроскопические объекты при одних условиях проявляют свойства частицы, а при других — волны.
И для описания такой двойственности в микромире было выведено уравнение Шрёдингера, которое выглядит пугающе, поэтому мы не будем отбирать хлеб у физиков, занимаясь его решением. Запомним только, что решение уравнения Шрёдингера представляет собой
волновую функцию
, смысл которой заключается в вероятности обнаружить электрон в той или иной точке пространства. Все, волновая функция, запомнили
🙂
Для наглядного толкования рисуют
график радиального распределения электронной плотности
. На оси Y откладывается величина, пропорциональная вероятности обнаружить электрон в точке пространства, а на оси X — расстояние от центра атома.
И самое интересное. По мере удаления от центра атома вероятность найти электрон уменьшается (
логично, да
). Приближается к нулю...
Но она никогда его не достигает
! То есть даже на бесконечно большом расстоянии от атомного ядра существует
ненулевая вероятность
обнаружить электрон, связанный с этим ядром!
И это факт, подтвержденный учёными, которые занимаются решением квантовых задач на
мощнейших суперкомпьютерах
. Другое дело, что вероятность обнаружить электрон после определенного расстояния ничтожно мало
🙂
Но ты только представь, что
рядом с тобой можно найти частички преподавателя
, который рассказывает лекцию в другом конце аудитории. Электрон от любой знаменитости, сториз которой ты иногда смотришь в Инстаграме*. Или электрон от девушки или парня напротив тебя в метро. Мысль об этом сводит меня с ума!
*Instagram принадлежит Meta, которая признана экстремисткой организацией и запрещена в России. | https://t.me/ychemistry/1002?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 3,000 | 0 | 1,727,419,833 | 1,736,456,929 | 1,106 | 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118 | null | Опыт который не стоит повторять в домашних условиях — алюминиевая фольга в микроволновке. | https://t.me/ychemistry/998?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 3,500 | 0 | 1,726,644,991 | 1,736,456,929 | 1,150 | 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| null | NEUTRAL | rus | NOT SPAM | 13 | 0 | 0 | 1 | 0 | 0 | 2 | 2 | 1 | 0 | 4 | 0 | 2 | true |
118 | null | Через легендарную Нокию 3310 пропустили миллион вольт, а она не только осталась жива, но и смогла найти сеть и принять звонок.
Воистину неубиваемый аппарат! | https://t.me/ychemistry/999?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 3,200 | 0 | 1,726,810,424 | 1,736,456,929 | 1,150 | 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| [{"ner":"Нокию","lemma":"нокию","label":"LOC","start_pos":18,"end_pos":23},{"ner":"3310","lemma":"3310","label":"NUM","start_pos":24,"end_pos":28}] | POSITIVE | rus | NOT SPAM | 24 | 0 | 0 | 1 | 0 | 0 | 3 | 5 | 1 | 1 | 5 | 1 | 4 | true |
118 | null | Визуализация воздушного потока вокруг носового шасси Боинга 777. | https://t.me/chemistrytg2021/9496?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,800 | 0 | 1,735,032,000 | 1,736,456,930 | 1,150 | 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| [{"ner":"777","lemma":"777","label":"NUM","start_pos":60,"end_pos":63}] | NEUTRAL | rus | NOT SPAM | 8 | 0 | 0 | 1 | 0 | 0 | 2 | 0 | 0 | 1 | 3 | 0 | 1 | true |
118 | null | Эксперимент "балансирование".
Если в алюминиевой банке оставить жидкости примерно треть, то банку можно сбалансировать под углом в 45 градусов.
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| [{"ner":"45","lemma":"45","label":"NUM","start_pos":131,"end_pos":133}] | NEUTRAL | rus | NOT SPAM | 20 | 0 | 0 | 1 | 0 | 0 | 1 | 2 | 0 | 1 | 9 | 2 | 6 | true |
118 | null | Завораживающий родамин в УФ-лучах
Родамины — это семейство близких химических веществ, флуороновых красителей. Характерные представители — Родамин 6G и Родамин Б. Родаминовые красители флуоресцируют, для обнаружения используются простые и недорогие методы флуориметрии. Родаминовые красители используются в биотехнологии, в таких методах как флуоресцентная микроскопия, проточная цитометрия и иммуноферментный анализ.
Родаминовые красители в целом токсичны и растворимы в воде, метаноле и этаноле.
Интенсивность флуоресценции во много раз увеличивается при растворении в органических растворителях, например диметилсульфоксиде (димексиде), диметилформамиде. | https://t.me/chemistrytg2021/9498?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,200 | 0 | 1,735,053,600 | 1,736,456,930 | 1,150 | 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| [{"ner":"Родамин 6G","lemma":"родамин 6g","label":"ORG","start_pos":139,"end_pos":149},{"ner":"Родамин Б. 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118 | null | Номенклатура органической химии - циклические соединения с общими названиями. | https://t.me/chemistrytg2021/9499?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,100 | 0 | 1,735,064,401 | 1,736,456,930 | 1,150 | 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| null | NEUTRAL | rus | NOT SPAM | 9 | 0 | 0 | 1 | 0 | 0 | 3 | 0 | 0 | 0 | 5 | 0 | 1 | true |
118 | null | Постановлением Президиума РАН внесены изменения в положение о медалях РАН с премиями для молодых ученых и студентов. Предельный возраст для подачи документов на соискание медали может быть увеличен в том случае, если соискатель находился в отпуске по уходу за ребенком (в зависимости от количества детей; суммарно не более чем на 5 лет).
#инфраструктуранауки | https://t.me/chemrussia/5119?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,900 | 0 | 1,733,809,683 | 1,736,456,930 | 1,150 | 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| [{"ner":"Президиума","lemma":"президиум","label":"ORG","start_pos":15,"end_pos":25},{"ner":"РАН","lemma":"ран","label":"ORG","start_pos":26,"end_pos":29},{"ner":"РАН","lemma":"ран","label":"ORG","start_pos":70,"end_pos":73},{"ner":"5","lemma":"5","label":"NUM","start_pos":330,"end_pos":331}] | NEUTRAL | rus | NOT SPAM | 53 | 0 | 2 | 1 | 0 | 0 | 2 | 4 | 0 | 1 | 22 | 2 | 7 | true |
118 | null | Переключаемые неорганические энзимы
Исследователи из Института общей и неорганической химии им. Н.С. Курнакова РАН и Института теоретической и экспериментальной биофизики РАН впервые получили неорганические аналоги природных энзимов на основе наночастиц диоксида церия и яблочной кислоты. Выявлено, как именно энзимоподобные свойства этих наночастиц зависят от их состава, то есть количества органических молекул на поверхности наночастиц. Для исследования свойств наночастиц использовали чрезвычайно высокочувствительный хемилюминесцентный метод. Неожиданным результатом работы явилось то, что при малом содержании органического стабилизатора на поверхности наночастиц диоксида церия они увеличивают скорость образования реакционноспособных свободных радикалов в системе, то есть способствуют протеканию окислительных реакций. Аналогичную активность по отношению к пероксиду водорода проявляет и природный фермент пероксидаза. Напротив, при высоком содержании яблочной кислоты наночастицы замедляли образование радикалов, то есть показали антиоксидантную активность. Таким образом, изменяя количество молекул, находящихся на поверхности наночастиц, можно переключать их свойства. Для описания этого эффекта можно использовать довольно простую геометрическую модель, которая может быть использована для предсказания биологических свойств и других наноматериалов. Кроме того, ученые провели тщательные исследования биологической совместимости полученных наночастиц, которые достоверно показали, что они не являются токсичными по отношению к стволовым клеткам человека.
Результаты работы, выполненой при поддержке РНФ (проект № 24-13-00370), опубликованы в журнале Nanomaterials и открывают новые возможности для получения биосовместимых неорганических наноматериалов с регулируемыми про- и антиоксидантными свойствами.
A.D. Filippova, A.E. Baranchikov, M.A. Teplonogova, I.V. Savintseva, A.L. Popov, V.K. Ivanov. Ligand-to-metal ratio governs radical-scavenging ability of malate-stabilised ceria nanoparticles // Nanomaterials. 2024. V.14(23). 1908. DOI: 10.3390/nano14231908.
https://www.mdpi.com/2079-4991/14/23/1908
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Научный микроблог Минобнауки России
#российскаянаука #ионх | https://t.me/chemrussia/5121?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,700 | 0 | 1,733,809,705 | 1,736,456,930 | 1,150 | 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118 | null | IX Международная конференция «Современные синтетические методологии для создания лекарственных препаратов и функциональных материалов» пройдёт с 8 по 12 сентября 2025 г. в Перми.
Основные тематики конференции: • Синтез и свойства органических соединений • Химия гетероциклических соединений • Химия элементорганических соединений • Медицинская и биоорганическая химия • Катализ в органическом синтезе • Электрохимические методы в органическом синтезе • Супрамолекулярная химия • Асимметрический синтез и катализ • Агрохимия и современные средства защиты растений
Регистрация на конференцию открыта до 01 июня 2025 г.
Подробная информация о конференции - по ссылке:
https://mosm.psu.ru/?page_id=15
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118 | null | #органика
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118 | null | #органика
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| [{"ner":"07-21","lemma":"07-21","label":"DATE","start_pos":59,"end_pos":64},{"ner":"21","lemma":"21","label":"NUM","start_pos":62,"end_pos":64}] | NEUTRAL | eng | NOT SPAM | 2 | 0 | 0 | 0.75 | 0.25 | 0 | 0 | 0 | 0 | 0 | 1 | 0 | 1 | true |
118 | null | #органика
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| [{"ner":"07-24","lemma":"07-24","label":"DATE","start_pos":54,"end_pos":59},{"ner":"24","lemma":"24","label":"NUM","start_pos":57,"end_pos":59}] | NEUTRAL | eng | NOT SPAM | 2 | 0 | 0 | 0.75 | 0.25 | 0 | 0 | 0 | 0 | 0 | 1 | 0 | 1 | true |
118 | null | #органика
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| [{"ner":"08-15","lemma":"08-15","label":"DATE","start_pos":41,"end_pos":46},{"ner":"15","lemma":"15","label":"NUM","start_pos":44,"end_pos":46}] | NEUTRAL | eng | NOT SPAM | 1 | 0 | 0 | 0 | 1 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | true |
118 | null | 5-HTP. Что это такое?
👨⚕️
Наверняка многие из вас знают и знакомы с такой добавкой, как 5-HTP и даже знают, что она необходима для синтеза серотонина и мелатонина, но что это такое с точки зрения биохимии?
😉
На самом деле все просто. 5-HTP - сокращение от названия молекулы
5 - гидрокситриптофана
. Важного промежуточного метаболита аминокислоты триптофана.
Триптофан имеет разные пути превращения. Но для того, чтобы превратиться именно в серотонин, а далее мелатонин, он сперва должен присоединить к себе гидроксильную группу -OH. При этом она присоединяется к пятому углеродному атому. Поэтому и получается 5-гидрокситриптофан (5-HTP).
💊
Кстати для синтеза 5-HTP нужен биоптерин (BH4), железо (кофактор фермента), молекула кислорода (аэробная спортивная нагрузка кстати улучшает доставку кислорода), а также витамин B3.
Смотрите схему выше
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Более подробно про триптофан и другие аминокислоты мы говорим на нашем курсе по обмену белков и аминокислот.
http://simplebiochemistry.tilda.ws/menu
Расскажите, а что вы знаете об этой молекуле?
😇 | https://t.me/simplebestbiochemistry/485?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,100 | 0 | 1,730,178,941 | 1,736,456,930 | 1,152 | 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этой","label":"PER","start_pos":1021,"end_pos":1035},{"ner":"4","lemma":"4","label":"NUM","start_pos":687,"end_pos":688},{"ner":"3","lemma":"3","label":"NUM","start_pos":822,"end_pos":823}] | NEUTRAL | rus | NOT SPAM | 151 | 0 | 8 | 0.955446 | 0.044554 | 0 | 17 | 11 | 14 | 8 | 40 | 10 | 35 | true |
118 | null | Как делали первые фотографии?
📸
Сейчас мы
не можем представить свою жизнь
без новых
селфи
в инстаграме*,
фотографий
с друзьями во время редких встреч и
фотосессий
на рекламных постерах. Но путь к цифровой фотографии и её массовому распространению
был очень сложен и интересен
.
А начиналось всё, как и положено, с химии
👩🏻🔬
Еще в
1727
году немецкий химик
Шульце
обнаружил
чувствительность солей серебра к свету
— они темнели на свету и оставались без изменений в темноте
💡
Например,
белый хлорид серебра
темнел под действием света за счёт образования
металлического серебра
:
AgCl + свет → Ag + Cl₂
Вскоре был предложен способ
закрепить
полученное изображение с помощью
раствора аммиака NH₃
, который
растворял
не засвеченный хлорид серебра:
AgCl + NH₃ → Ag(NH₃)₂Cl
Поскольку хлорид серебра удалялся, дальнейшее
действие света никак не влияло на изображение
🙅♀️
Следующим этапом в развитии фотографии стало появление
дагеротипии
— фотопроцесса на основе светочувствительности
йодида серебра AgI
. В качестве основы под фотографию использовалась
серебряная пластинка, обработанная парами йода
. Её помещали в прототип фотоаппарата —
камеру-обскура
🎥
Что из себя представляла камера-обскура?
Простой светонепроницаемый ящик с маленьким отверстием (от 0,1 до 5 мм в зависимости от фокусного расстояния), через которое внутрь проникали лучи света и попадали на экран с противоположной стороны
🎇
Свет
, падая на пластинку, покрытую йодидом серебра,
вызывал его разложение
по уже знакомой нам схеме:
AgI + свет → Ag + I₂
Полученное изображение было настолько слабым и незаметным, что человеческий глаз не мог его разглядеть, поэтому его называли
скрытым
🔍
Чтобы проявить скрытое изображение
пластинку помешали в камеру, наполненную
парами ртути Hg
, которые образовывали
амальгаму серебра
. Изображение усиливалось за счёт увеличения массы, то есть происходило его
проявление
👁
Чтобы
«закрепить»
изображение, нужно было
удалить светочувствительный йодид серебра
с поверхности. Для этого со временем стали применять
тиосульфат натрия Na₂S₂O₃
, который быстро растворял йодид серебра:
AgI + Na₂S₂O₃ → Na₃Ag(S₂O₃)₂ + NaI
В результате засвеченные места пластинки, покрытые сплавом ртути и серебра, рассеивали отражённый свет, а в теневых участках отражались окружающие предметы, как в зеркале
. Расположив готовый
дагерротип
напротив чёрного бархата, получали
позитивное
изображение — чёрно-белую картинку, где тени, как и положено, были черные, а светлые участки — белыми
🔘
В дальнейшем была изобретена
калотипия
— способ получения изображения с использованием
бумаги
, пропитанной йодидом серебра. А уже потом стали использовать
фотоэмульсии
—
смеси галогенидов серебра и фотографического желатина
🎞
Дальнейшие открытий позволили ускорить и упростить процесс получения изображений, что в итоге привело к
тиражированию
и появлению
моментальных фотографий
🖨
Такие снимки не требовали манипуляций в лаборатории, а светочувствительное покрытие обрабатывалось встроенными химреактивами
📷
После
«полароидных»
снимком наступила
эра цифровой фотографии
, развитие которой мы наблюдаем по сей день
👀
И это лишь очень малая часть всей предыстории, скрытой за миниатюрными мощнейшими фотокамерами в наших смартфонах
📱
*Instagram принадлежит Meta, которая признана экстремисткой организацией и запрещена в России. | https://t.me/ychemistry/993?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,400 | 0 | 1,726,141,369 | 1,736,456,930 | 1,150 | 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Не веришь, что в России создают что-то действительно крутое?
Убедись сам! | https://t.me/ychemistry/994?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,100 | 0 | 1,726,153,340 | 1,736,456,930 | 1,150 | 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| [{"ner":"Telegram-канал","lemma":"telegram-канал","label":"ORG","start_pos":113,"end_pos":127},{"ner":"Техносфера","lemma":"техносфера","label":"PER","start_pos":129,"end_pos":139},{"ner":"России","lemma":"россия","label":"LOC","start_pos":390,"end_pos":396}] | NEUTRAL | rus | NOT SPAM | 58 | 0 | 1 | 0.9875 | 0.0125 | 0 | 13 | 10 | 4 | 0 | 16 | 1 | 14 | true |
118 | null | Из чего состоит мыло?
Ежедневно мы используем данное средство, однако даже не догадываемся, из чего оно состоит. Большинству известно только то, что это щелочной продукт и всё. Поэтому сегодня подробно разберём, из чего же состоит мыло.
Начнём с того, что мыло - смесь солей жирных кислот, чаще всего его получают воздействием щелочи на жиры. Именно благодаря открытию этой реакции, в прошлом человечество победило многие эпидемии. Да что там прошлое, на сегодняшний день гигиена для африканских племен, оказывает на здоровье больший эффект, чем лекарства.
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Главная характеристика мыла - щелочность. Чем выше pH, тем агрессивнее ведет себя мыло по отношению к коже. Но это не плохо, поскольку так мыло лучше отмывает. Проверить pH можно индикаторной бумажкой: >9 - щелочное, 5-9 - нейтральное. Если вы изучали в школе химию, то скорее всего проводили эксперименты с помощью этих индикаторов. Они моментально меняют цвет в зависимости от среды.
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Отмывающий эффект основан на том, что молекулы Поверхностно-Активных Веществ, из которых состоит мыло (те самые соли жирных кислот), «обволакивают» частицы грязи и жира, делая их более растворимыми в воде.
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"Хозяйственное" мыло по ГОСТ моет лучше всего, но содержит больше всего щелочи. Отмыть руки от масла - лучше не придумаешь, но пользоваться постоянно нежелательно. Оптимальный баланс эффективность / агрессивность, чаще всего, у детского мыла. Кстати, оно моё любимое. Рекомендую обратить особое внимание именно на него.
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Мыло, сделанное только из мылящихся растительных экстрактов, не вредит коже, но моет не очень хорошо. Жидкое мыло более удобно и гигиенично, чем твердое, но, по статистике, оно расходуется намного быстрее. Добавки эфирных масел и трав приятны, но малоэффективны - мыло само их и смоет. Поэтому многие дерматологи советуют после использования жидкого мыла, наносить на сухую кожу крем.
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А вот любимое многими антибактериальное мыло я не советую использовать. Оно может нарушить баланс микроорганизмов на коже и вызывать экзему. Или даже хуже: создать бактерию, устойчивую к антибиотикам. Триклозан убивает 99,9% бактерий, а остальные 0,1% уже его не боятся и нападают на владельца.
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Любое щелочное мыло надежнее во много раз. В сотый раз убеждаюсь, что всё что нам говорят по телевизору - это полная ерунда. Однако большинство людей, увы, доверяют рекламе по ТВ. | https://t.me/ychemistry/995?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 3,300 | 0 | 1,726,156,941 | 1,736,456,930 | 1,152 | 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118 | null | Шарик с водой vs теннисная ракетка. | https://t.me/ychemistry/996?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 3,100 | 0 | 1,726,302,646 | 1,736,456,930 | 1,150 | 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118 | null | Кинорежиссёр и фотограф создал для съёмок ледяную пещеру из сахара, кукурузного сиропа и пищевого красителя. | https://t.me/ychemistry/997?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 3,500 | 0 | 1,726,468,798 | 1,736,456,930 | 1,150 | 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| null | NEUTRAL | rus | NOT SPAM | 15 | 0 | 0 | 1 | 0 | 0 | 3 | 1 | 0 | 0 | 6 | 0 | 2 | true |
118 | null | Несколько любопытных вещей под микроскопом:
⠀
1. Хлопок
2. Красное вино
3. Лук
4. Кристаллики льда | https://t.me/chemistrytg2021/9491?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,300 | 0 | 1,734,945,601 | 1,736,456,931 | 1,143 | 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118 | null | Невероятный «эффект Домино» | https://t.me/chemistrytg2021/9492?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,734,956,400 | 1,736,456,931 | 1,143 | 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| null | NEUTRAL | rus | NOT SPAM | 3 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 0 | 0 | 1 | 0 | 2 | true |
118 | null | Самодельный эллекторо-магнит: железный сердечник (гвоздь), провод и источник постоянного тока (батарея D) - когда цепь замкнута, магнит включается. Закон Ампера: движущийся заряд (ток) создает магнитное поле.
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118 | null | Испытания экологически чистого и быстро эффективного огнетушителя. | https://t.me/chemistrytg2021/9495?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,735,021,200 | 1,736,456,931 | 1,150 | 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| null | NEUTRAL | rus | NOT SPAM | 7 | 0 | 0 | 1 | 0 | 0 | 2 | 0 | 0 | 0 | 2 | 2 | 1 | true |
118 | null | Власти Китая
ввели прямой запрет
на экспорт в США ряда материалов, которые, по мнению китайских властей, могут иметь потенциальное военное применение
, передает Reuters.
Так, под запрет попали галлий, германий, сурьма и сверхтвердые материалы (какие именно, не уточняется). Вышеперечисленные материалы, в частности, имеют важное значение для производства полупроводниковых компонентов.
Директива Пекина о так называемых товарах двойного назначения, в которой говорится о защите национальной безопасности и интересов и которая вступает в силу немедленно, также требует более строгого контроля конечного использования графитовых изделий, поставляемых в США.
#тожехимия | https://t.me/chemrussia/5116?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,900 | 0 | 1,733,637,661 | 1,736,456,931 | 1,139 | 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118 | null | Объявлен сбор заявок на соискание премии ИЮПАК-Солвэй 2025 для молодых химиков, защитивших диссертации в 2024 г. Премия традиционно вручается соискателям, имеющим публикации в наиболее высокорейтинговых журналах. Заявки принимаются до 15 февраля 2025 г.
Подробная информация - по ссылке:
https://iupac.org/2025-iupac-solvay-international-award-for-young-chemists-call-for-applicants/
#конкурс | https://t.me/chemrussia/5117?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 2,100 | 0 | 1,733,723,140 | 1,736,456,931 | 1,139 | 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