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1
2005-2008
13) Rationalised 2023-24 39 Electrochemistry If the circuit in Daniell cell (Fig 2 1) is closed then we note that the reaction Zn(s) + Cu2+(aq) ® Zn2+(aq) + Cu(s) (2 1) takes place and as time passes, the concentration of Zn2+ keeps on increasing while the concentration of Cu2+ keeps on decreasing
1
2006-2009
2 1) is closed then we note that the reaction Zn(s) + Cu2+(aq) ® Zn2+(aq) + Cu(s) (2 1) takes place and as time passes, the concentration of Zn2+ keeps on increasing while the concentration of Cu2+ keeps on decreasing At the same time voltage of the cell as read on the voltmeter keeps on decreasing
1
2007-2010
1) is closed then we note that the reaction Zn(s) + Cu2+(aq) ® Zn2+(aq) + Cu(s) (2 1) takes place and as time passes, the concentration of Zn2+ keeps on increasing while the concentration of Cu2+ keeps on decreasing At the same time voltage of the cell as read on the voltmeter keeps on decreasing After some time, we shall note that there is no change in the concentration of Cu2+ and Zn2+ ions and at the same time, voltmeter gives zero reading
1
2008-2011
1) takes place and as time passes, the concentration of Zn2+ keeps on increasing while the concentration of Cu2+ keeps on decreasing At the same time voltage of the cell as read on the voltmeter keeps on decreasing After some time, we shall note that there is no change in the concentration of Cu2+ and Zn2+ ions and at the same time, voltmeter gives zero reading This indicates that equilibrium has been attained
1
2009-2012
At the same time voltage of the cell as read on the voltmeter keeps on decreasing After some time, we shall note that there is no change in the concentration of Cu2+ and Zn2+ ions and at the same time, voltmeter gives zero reading This indicates that equilibrium has been attained In this situation the Nernst equation may be written as: E(cell) = 0 = ( ) o Ecell – 2
1
2010-2013
After some time, we shall note that there is no change in the concentration of Cu2+ and Zn2+ ions and at the same time, voltmeter gives zero reading This indicates that equilibrium has been attained In this situation the Nernst equation may be written as: E(cell) = 0 = ( ) o Ecell – 2 303 2 log [Zn ] [Cu ] 2 2 RT F + + or ( ) o Ecell = 2 2 2
1
2011-2014
This indicates that equilibrium has been attained In this situation the Nernst equation may be written as: E(cell) = 0 = ( ) o Ecell – 2 303 2 log [Zn ] [Cu ] 2 2 RT F + + or ( ) o Ecell = 2 2 2 303 [Zn ] log 2 [Cu ] RT F   But at equilibrium, [ ] [ ] Zn Cu 2 2 + + = Kc for the reaction 2
1
2012-2015
In this situation the Nernst equation may be written as: E(cell) = 0 = ( ) o Ecell – 2 303 2 log [Zn ] [Cu ] 2 2 RT F + + or ( ) o Ecell = 2 2 2 303 [Zn ] log 2 [Cu ] RT F   But at equilibrium, [ ] [ ] Zn Cu 2 2 + + = Kc for the reaction 2 1 and at T = 298K the above equation can be written as ( ) o Ecell = 0 059 2
1
2013-2016
303 2 log [Zn ] [Cu ] 2 2 RT F + + or ( ) o Ecell = 2 2 2 303 [Zn ] log 2 [Cu ] RT F   But at equilibrium, [ ] [ ] Zn Cu 2 2 + + = Kc for the reaction 2 1 and at T = 298K the above equation can be written as ( ) o Ecell = 0 059 2 V log KC = 1
1
2014-2017
303 [Zn ] log 2 [Cu ] RT F   But at equilibrium, [ ] [ ] Zn Cu 2 2 + + = Kc for the reaction 2 1 and at T = 298K the above equation can be written as ( ) o Ecell = 0 059 2 V log KC = 1 1 V ( ( ) o Ecell = 1
1
2015-2018
1 and at T = 298K the above equation can be written as ( ) o Ecell = 0 059 2 V log KC = 1 1 V ( ( ) o Ecell = 1 1V) log KC = (1
1
2016-2019
V log KC = 1 1 V ( ( ) o Ecell = 1 1V) log KC = (1 1V × 2) 37
1
2017-2020
1 V ( ( ) o Ecell = 1 1V) log KC = (1 1V × 2) 37 288 0
1
2018-2021
1V) log KC = (1 1V × 2) 37 288 0 059 V  KC = 2 × 1037 at 298K
1
2019-2022
1V × 2) 37 288 0 059 V  KC = 2 × 1037 at 298K In general, ( ) o Ecell = 2
1
2020-2023
288 0 059 V  KC = 2 × 1037 at 298K In general, ( ) o Ecell = 2 303RT nF log KC (2
1
2021-2024
059 V  KC = 2 × 1037 at 298K In general, ( ) o Ecell = 2 303RT nF log KC (2 14) Thus, Eq
1
2022-2025
In general, ( ) o Ecell = 2 303RT nF log KC (2 14) Thus, Eq (2
1
2023-2026
303RT nF log KC (2 14) Thus, Eq (2 14) gives a relationship between equilibrium constant of the reaction and standard potential of the cell in which that reaction takes place
1
2024-2027
14) Thus, Eq (2 14) gives a relationship between equilibrium constant of the reaction and standard potential of the cell in which that reaction takes place Thus, equilibrium constants of the reaction, difficult to measure otherwise, can be calculated from the corresponding Eo value of the cell
1
2025-2028
(2 14) gives a relationship between equilibrium constant of the reaction and standard potential of the cell in which that reaction takes place Thus, equilibrium constants of the reaction, difficult to measure otherwise, can be calculated from the corresponding Eo value of the cell 2
1
2026-2029
14) gives a relationship between equilibrium constant of the reaction and standard potential of the cell in which that reaction takes place Thus, equilibrium constants of the reaction, difficult to measure otherwise, can be calculated from the corresponding Eo value of the cell 2 3
1
2027-2030
Thus, equilibrium constants of the reaction, difficult to measure otherwise, can be calculated from the corresponding Eo value of the cell 2 3 1 Equilibrium Constant from Nernst Equation Example 2
1
2028-2031
2 3 1 Equilibrium Constant from Nernst Equation Example 2 1 Example 2
1
2029-2032
3 1 Equilibrium Constant from Nernst Equation Example 2 1 Example 2 1 Example 2
1
2030-2033
1 Equilibrium Constant from Nernst Equation Example 2 1 Example 2 1 Example 2 1 Example 2
1
2031-2034
1 Example 2 1 Example 2 1 Example 2 1 Example 2
1
2032-2035
1 Example 2 1 Example 2 1 Example 2 1 Represent the cell in which the following reaction takes place Mg(s) + 2Ag+(0
1
2033-2036
1 Example 2 1 Example 2 1 Represent the cell in which the following reaction takes place Mg(s) + 2Ag+(0 0001M) ® Mg2+(0
1
2034-2037
1 Example 2 1 Represent the cell in which the following reaction takes place Mg(s) + 2Ag+(0 0001M) ® Mg2+(0 130M) + 2Ag(s) Calculate its E(cell) if ( ) o Ecell = 3
1
2035-2038
1 Represent the cell in which the following reaction takes place Mg(s) + 2Ag+(0 0001M) ® Mg2+(0 130M) + 2Ag(s) Calculate its E(cell) if ( ) o Ecell = 3 17 V
1
2036-2039
0001M) ® Mg2+(0 130M) + 2Ag(s) Calculate its E(cell) if ( ) o Ecell = 3 17 V The cell can be written as Mgú Mg2+(0
1
2037-2040
130M) + 2Ag(s) Calculate its E(cell) if ( ) o Ecell = 3 17 V The cell can be written as Mgú Mg2+(0 130M)úú Ag+(0
1
2038-2041
17 V The cell can be written as Mgú Mg2+(0 130M)úú Ag+(0 0001M)ú Ag  Ecell = ( ) + + 2 o cell 2 Mg –RT 2Fln Ag E = 3
1
2039-2042
The cell can be written as Mgú Mg2+(0 130M)úú Ag+(0 0001M)ú Ag  Ecell = ( ) + + 2 o cell 2 Mg –RT 2Fln Ag E = 3 17 V – 0 059 2 0 0001 2
1
2040-2043
130M)úú Ag+(0 0001M)ú Ag  Ecell = ( ) + + 2 o cell 2 Mg –RT 2Fln Ag E = 3 17 V – 0 059 2 0 0001 2 log (
1
2041-2044
0001M)ú Ag  Ecell = ( ) + + 2 o cell 2 Mg –RT 2Fln Ag E = 3 17 V – 0 059 2 0 0001 2 log ( ) V 0
1
2042-2045
17 V – 0 059 2 0 0001 2 log ( ) V 0 130 = 3
1
2043-2046
log ( ) V 0 130 = 3 17 V – 0
1
2044-2047
) V 0 130 = 3 17 V – 0 21V = 2
1
2045-2048
130 = 3 17 V – 0 21V = 2 96 V
1
2046-2049
17 V – 0 21V = 2 96 V Solution Solution Solution Solution Solution Rationalised 2023-24 40 Chemistry The standard electrode potential for Daniell cell is 1
1
2047-2050
21V = 2 96 V Solution Solution Solution Solution Solution Rationalised 2023-24 40 Chemistry The standard electrode potential for Daniell cell is 1 1V
1
2048-2051
96 V Solution Solution Solution Solution Solution Rationalised 2023-24 40 Chemistry The standard electrode potential for Daniell cell is 1 1V Calculate the standard Gibbs energy for the reaction: Zn(s) + Cu2+(aq) ¾® Zn2+(aq) + Cu(s) DrGo = – nF o (cell) E n in the above equation is 2, F = 96487 C mol–1 and ( ) o Ecell = 1
1
2049-2052
Solution Solution Solution Solution Solution Rationalised 2023-24 40 Chemistry The standard electrode potential for Daniell cell is 1 1V Calculate the standard Gibbs energy for the reaction: Zn(s) + Cu2+(aq) ¾® Zn2+(aq) + Cu(s) DrGo = – nF o (cell) E n in the above equation is 2, F = 96487 C mol–1 and ( ) o Ecell = 1 1 V Therefore, DrGo = – 2 × 1
1
2050-2053
1V Calculate the standard Gibbs energy for the reaction: Zn(s) + Cu2+(aq) ¾® Zn2+(aq) + Cu(s) DrGo = – nF o (cell) E n in the above equation is 2, F = 96487 C mol–1 and ( ) o Ecell = 1 1 V Therefore, DrGo = – 2 × 1 1V × 96487 C mol–1 = – 21227 J mol–1 = – 212
1
2051-2054
Calculate the standard Gibbs energy for the reaction: Zn(s) + Cu2+(aq) ¾® Zn2+(aq) + Cu(s) DrGo = – nF o (cell) E n in the above equation is 2, F = 96487 C mol–1 and ( ) o Ecell = 1 1 V Therefore, DrGo = – 2 × 1 1V × 96487 C mol–1 = – 21227 J mol–1 = – 212 27 kJ mol–1 Example 2
1
2052-2055
1 V Therefore, DrGo = – 2 × 1 1V × 96487 C mol–1 = – 21227 J mol–1 = – 212 27 kJ mol–1 Example 2 3 Example 2
1
2053-2056
1V × 96487 C mol–1 = – 21227 J mol–1 = – 212 27 kJ mol–1 Example 2 3 Example 2 3 Example 2
1
2054-2057
27 kJ mol–1 Example 2 3 Example 2 3 Example 2 3 Example 2
1
2055-2058
3 Example 2 3 Example 2 3 Example 2 3 Example 2
1
2056-2059
3 Example 2 3 Example 2 3 Example 2 3 Solution Solution Solution Solution Solution Electrical work done in one second is equal to electrical potential multiplied by total charge passed
1
2057-2060
3 Example 2 3 Example 2 3 Solution Solution Solution Solution Solution Electrical work done in one second is equal to electrical potential multiplied by total charge passed If we want to obtain maximum work from a galvanic cell then charge has to be passed reversibly
1
2058-2061
3 Example 2 3 Solution Solution Solution Solution Solution Electrical work done in one second is equal to electrical potential multiplied by total charge passed If we want to obtain maximum work from a galvanic cell then charge has to be passed reversibly The reversible work done by a galvanic cell is equal to decrease in its Gibbs energy and therefore, if the emf of the cell is E and nF is the amount of charge passed and DrG is the Gibbs energy of the reaction, then DrG = – nFE(cell) (2
1
2059-2062
3 Solution Solution Solution Solution Solution Electrical work done in one second is equal to electrical potential multiplied by total charge passed If we want to obtain maximum work from a galvanic cell then charge has to be passed reversibly The reversible work done by a galvanic cell is equal to decrease in its Gibbs energy and therefore, if the emf of the cell is E and nF is the amount of charge passed and DrG is the Gibbs energy of the reaction, then DrG = – nFE(cell) (2 15) It may be remembered that E(cell) is an intensive parameter but DrG is an extensive thermodynamic property and the value depends on n
1
2060-2063
If we want to obtain maximum work from a galvanic cell then charge has to be passed reversibly The reversible work done by a galvanic cell is equal to decrease in its Gibbs energy and therefore, if the emf of the cell is E and nF is the amount of charge passed and DrG is the Gibbs energy of the reaction, then DrG = – nFE(cell) (2 15) It may be remembered that E(cell) is an intensive parameter but DrG is an extensive thermodynamic property and the value depends on n Thus, if we write the reaction Zn(s) + Cu2+(aq) ¾® Zn2+(aq) + Cu(s) (2
1
2061-2064
The reversible work done by a galvanic cell is equal to decrease in its Gibbs energy and therefore, if the emf of the cell is E and nF is the amount of charge passed and DrG is the Gibbs energy of the reaction, then DrG = – nFE(cell) (2 15) It may be remembered that E(cell) is an intensive parameter but DrG is an extensive thermodynamic property and the value depends on n Thus, if we write the reaction Zn(s) + Cu2+(aq) ¾® Zn2+(aq) + Cu(s) (2 1) DrG = – 2FE(cell) but when we write the reaction 2 Zn (s) + 2 Cu2+(aq) ¾®2 Zn2+(aq) + 2Cu(s) DrG = – 4FE(cell) If the concentration of all the reacting species is unity, then E(cell) = ( ) o Ecell and we have DrGo = – nF o E(cell) (2
1
2062-2065
15) It may be remembered that E(cell) is an intensive parameter but DrG is an extensive thermodynamic property and the value depends on n Thus, if we write the reaction Zn(s) + Cu2+(aq) ¾® Zn2+(aq) + Cu(s) (2 1) DrG = – 2FE(cell) but when we write the reaction 2 Zn (s) + 2 Cu2+(aq) ¾®2 Zn2+(aq) + 2Cu(s) DrG = – 4FE(cell) If the concentration of all the reacting species is unity, then E(cell) = ( ) o Ecell and we have DrGo = – nF o E(cell) (2 16) Thus, from the measurement of ( ) o Ecell we can obtain an important thermodynamic quantity, DrGo, standard Gibbs energy of the reaction
1
2063-2066
Thus, if we write the reaction Zn(s) + Cu2+(aq) ¾® Zn2+(aq) + Cu(s) (2 1) DrG = – 2FE(cell) but when we write the reaction 2 Zn (s) + 2 Cu2+(aq) ¾®2 Zn2+(aq) + 2Cu(s) DrG = – 4FE(cell) If the concentration of all the reacting species is unity, then E(cell) = ( ) o Ecell and we have DrGo = – nF o E(cell) (2 16) Thus, from the measurement of ( ) o Ecell we can obtain an important thermodynamic quantity, DrGo, standard Gibbs energy of the reaction From the latter we can calculate equilibrium constant by the equation: DrGo = –RT ln K
1
2064-2067
1) DrG = – 2FE(cell) but when we write the reaction 2 Zn (s) + 2 Cu2+(aq) ¾®2 Zn2+(aq) + 2Cu(s) DrG = – 4FE(cell) If the concentration of all the reacting species is unity, then E(cell) = ( ) o Ecell and we have DrGo = – nF o E(cell) (2 16) Thus, from the measurement of ( ) o Ecell we can obtain an important thermodynamic quantity, DrGo, standard Gibbs energy of the reaction From the latter we can calculate equilibrium constant by the equation: DrGo = –RT ln K 2
1
2065-2068
16) Thus, from the measurement of ( ) o Ecell we can obtain an important thermodynamic quantity, DrGo, standard Gibbs energy of the reaction From the latter we can calculate equilibrium constant by the equation: DrGo = –RT ln K 2 3
1
2066-2069
From the latter we can calculate equilibrium constant by the equation: DrGo = –RT ln K 2 3 2 Electro- chemical Cell and Gibbs Energy of the Reaction Calculate the equilibrium constant of the reaction: Cu(s) + 2Ag+(aq) ® Cu2+(aq) + 2Ag(s) ( ) o Ecell = 0
1
2067-2070
2 3 2 Electro- chemical Cell and Gibbs Energy of the Reaction Calculate the equilibrium constant of the reaction: Cu(s) + 2Ag+(aq) ® Cu2+(aq) + 2Ag(s) ( ) o Ecell = 0 46 V ( ) o Ecell = 0 059 2
1
2068-2071
3 2 Electro- chemical Cell and Gibbs Energy of the Reaction Calculate the equilibrium constant of the reaction: Cu(s) + 2Ag+(aq) ® Cu2+(aq) + 2Ag(s) ( ) o Ecell = 0 46 V ( ) o Ecell = 0 059 2 V log KC = 0
1
2069-2072
2 Electro- chemical Cell and Gibbs Energy of the Reaction Calculate the equilibrium constant of the reaction: Cu(s) + 2Ag+(aq) ® Cu2+(aq) + 2Ag(s) ( ) o Ecell = 0 46 V ( ) o Ecell = 0 059 2 V log KC = 0 46 V or log KC = 0 46
1
2070-2073
46 V ( ) o Ecell = 0 059 2 V log KC = 0 46 V or log KC = 0 46 0 0592 V V × = 15
1
2071-2074
V log KC = 0 46 V or log KC = 0 46 0 0592 V V × = 15 6 KC = 3
1
2072-2075
46 V or log KC = 0 46 0 0592 V V × = 15 6 KC = 3 92 × 1015 Example 2
1
2073-2076
0 0592 V V × = 15 6 KC = 3 92 × 1015 Example 2 2 Example 2
1
2074-2077
6 KC = 3 92 × 1015 Example 2 2 Example 2 2 Example 2
1
2075-2078
92 × 1015 Example 2 2 Example 2 2 Example 2 2 Example 2
1
2076-2079
2 Example 2 2 Example 2 2 Example 2 2 Example 2
1
2077-2080
2 Example 2 2 Example 2 2 Example 2 2 Solution Solution Solution Solution Solution Rationalised 2023-24 41 Electrochemistry It is necessary to define a few terms before we consider the subject of conductance of electricity through electrolytic solutions
1
2078-2081
2 Example 2 2 Example 2 2 Solution Solution Solution Solution Solution Rationalised 2023-24 41 Electrochemistry It is necessary to define a few terms before we consider the subject of conductance of electricity through electrolytic solutions The electrical resistance is represented by the symbol ‘R’ and it is measured in ohm (W) which in terms of SI base units is equal to (kg m2)/(S3 A2)
1
2079-2082
2 Example 2 2 Solution Solution Solution Solution Solution Rationalised 2023-24 41 Electrochemistry It is necessary to define a few terms before we consider the subject of conductance of electricity through electrolytic solutions The electrical resistance is represented by the symbol ‘R’ and it is measured in ohm (W) which in terms of SI base units is equal to (kg m2)/(S3 A2) It can be measured with the help of a Wheatstone bridge with which you are familiar from your study of physics
1
2080-2083
2 Solution Solution Solution Solution Solution Rationalised 2023-24 41 Electrochemistry It is necessary to define a few terms before we consider the subject of conductance of electricity through electrolytic solutions The electrical resistance is represented by the symbol ‘R’ and it is measured in ohm (W) which in terms of SI base units is equal to (kg m2)/(S3 A2) It can be measured with the help of a Wheatstone bridge with which you are familiar from your study of physics The electrical resistance of any object is directly proportional to its length, l, and inversely proportional to its area of cross section, A
1
2081-2084
The electrical resistance is represented by the symbol ‘R’ and it is measured in ohm (W) which in terms of SI base units is equal to (kg m2)/(S3 A2) It can be measured with the help of a Wheatstone bridge with which you are familiar from your study of physics The electrical resistance of any object is directly proportional to its length, l, and inversely proportional to its area of cross section, A That is, R µ l A or R = r l A (2
1
2082-2085
It can be measured with the help of a Wheatstone bridge with which you are familiar from your study of physics The electrical resistance of any object is directly proportional to its length, l, and inversely proportional to its area of cross section, A That is, R µ l A or R = r l A (2 17) The constant of proportionality, r (Greek, rho), is called resistivity (specific resistance)
1
2083-2086
The electrical resistance of any object is directly proportional to its length, l, and inversely proportional to its area of cross section, A That is, R µ l A or R = r l A (2 17) The constant of proportionality, r (Greek, rho), is called resistivity (specific resistance) Its SI units are ohm metre (W m) and quite often its submultiple, ohm centimetre (W cm) is also used
1
2084-2087
That is, R µ l A or R = r l A (2 17) The constant of proportionality, r (Greek, rho), is called resistivity (specific resistance) Its SI units are ohm metre (W m) and quite often its submultiple, ohm centimetre (W cm) is also used IUPAC recommends the use of the term resistivity over specific resistance and hence in the rest of the book we shall use the term resistivity
1
2085-2088
17) The constant of proportionality, r (Greek, rho), is called resistivity (specific resistance) Its SI units are ohm metre (W m) and quite often its submultiple, ohm centimetre (W cm) is also used IUPAC recommends the use of the term resistivity over specific resistance and hence in the rest of the book we shall use the term resistivity Physically, the resistivity for a substance is its resistance when it is one metre long and its area of cross section is one m2
1
2086-2089
Its SI units are ohm metre (W m) and quite often its submultiple, ohm centimetre (W cm) is also used IUPAC recommends the use of the term resistivity over specific resistance and hence in the rest of the book we shall use the term resistivity Physically, the resistivity for a substance is its resistance when it is one metre long and its area of cross section is one m2 It can be seen that: 1 W m = 100 W cm or 1 W cm = 0
1
2087-2090
IUPAC recommends the use of the term resistivity over specific resistance and hence in the rest of the book we shall use the term resistivity Physically, the resistivity for a substance is its resistance when it is one metre long and its area of cross section is one m2 It can be seen that: 1 W m = 100 W cm or 1 W cm = 0 01 W m The inverse of resistance, R, is called conductance, G, and we have the relation: G = 1 R = ρ A=κ A l l (2
1
2088-2091
Physically, the resistivity for a substance is its resistance when it is one metre long and its area of cross section is one m2 It can be seen that: 1 W m = 100 W cm or 1 W cm = 0 01 W m The inverse of resistance, R, is called conductance, G, and we have the relation: G = 1 R = ρ A=κ A l l (2 18) The SI unit of conductance is siemens, represented by the symbol ‘S’ and is equal to ohm–1 (also known as mho) or W–1
1
2089-2092
It can be seen that: 1 W m = 100 W cm or 1 W cm = 0 01 W m The inverse of resistance, R, is called conductance, G, and we have the relation: G = 1 R = ρ A=κ A l l (2 18) The SI unit of conductance is siemens, represented by the symbol ‘S’ and is equal to ohm–1 (also known as mho) or W–1 The inverse of resistivity, called conductivity (specific conductance) is represented by the symbol, k (Greek, kappa)
1
2090-2093
01 W m The inverse of resistance, R, is called conductance, G, and we have the relation: G = 1 R = ρ A=κ A l l (2 18) The SI unit of conductance is siemens, represented by the symbol ‘S’ and is equal to ohm–1 (also known as mho) or W–1 The inverse of resistivity, called conductivity (specific conductance) is represented by the symbol, k (Greek, kappa) IUPAC has recommended the use of term conductivity over specific conductance and hence we shall use the term conductivity in the rest of the book
1
2091-2094
18) The SI unit of conductance is siemens, represented by the symbol ‘S’ and is equal to ohm–1 (also known as mho) or W–1 The inverse of resistivity, called conductivity (specific conductance) is represented by the symbol, k (Greek, kappa) IUPAC has recommended the use of term conductivity over specific conductance and hence we shall use the term conductivity in the rest of the book The SI units of conductivity are S m–1 but quite often, k is expressed in S cm–1
1
2092-2095
The inverse of resistivity, called conductivity (specific conductance) is represented by the symbol, k (Greek, kappa) IUPAC has recommended the use of term conductivity over specific conductance and hence we shall use the term conductivity in the rest of the book The SI units of conductivity are S m–1 but quite often, k is expressed in S cm–1 Conductivity of a material in S m–1 is its conductance when it is 1 m long and its area of cross section is 1 m2
1
2093-2096
IUPAC has recommended the use of term conductivity over specific conductance and hence we shall use the term conductivity in the rest of the book The SI units of conductivity are S m–1 but quite often, k is expressed in S cm–1 Conductivity of a material in S m–1 is its conductance when it is 1 m long and its area of cross section is 1 m2 It may be noted that 1 S cm–1 = 100 S m–1
1
2094-2097
The SI units of conductivity are S m–1 but quite often, k is expressed in S cm–1 Conductivity of a material in S m–1 is its conductance when it is 1 m long and its area of cross section is 1 m2 It may be noted that 1 S cm–1 = 100 S m–1 2
1
2095-2098
Conductivity of a material in S m–1 is its conductance when it is 1 m long and its area of cross section is 1 m2 It may be noted that 1 S cm–1 = 100 S m–1 2 4 2
1
2096-2099
It may be noted that 1 S cm–1 = 100 S m–1 2 4 2 4 2
1
2097-2100
2 4 2 4 2 4 2
1
2098-2101
4 2 4 2 4 2 4 2
1
2099-2102
4 2 4 2 4 2 4 Conductance Conductance Conductance Conductance Conductance of Electrolytic of Electrolytic of Electrolytic of Electrolytic of Electrolytic Solutions Solutions Solutions Solutions Solutions Intext Questions Intext Questions Intext Questions Intext Questions Intext Questions 2
1
2100-2103
4 2 4 2 4 Conductance Conductance Conductance Conductance Conductance of Electrolytic of Electrolytic of Electrolytic of Electrolytic of Electrolytic Solutions Solutions Solutions Solutions Solutions Intext Questions Intext Questions Intext Questions Intext Questions Intext Questions 2 4 Calculate the potential of hydrogen electrode in contact with a solution whose pH is 10
1
2101-2104
4 2 4 Conductance Conductance Conductance Conductance Conductance of Electrolytic of Electrolytic of Electrolytic of Electrolytic of Electrolytic Solutions Solutions Solutions Solutions Solutions Intext Questions Intext Questions Intext Questions Intext Questions Intext Questions 2 4 Calculate the potential of hydrogen electrode in contact with a solution whose pH is 10 2
1
2102-2105
4 Conductance Conductance Conductance Conductance Conductance of Electrolytic of Electrolytic of Electrolytic of Electrolytic of Electrolytic Solutions Solutions Solutions Solutions Solutions Intext Questions Intext Questions Intext Questions Intext Questions Intext Questions 2 4 Calculate the potential of hydrogen electrode in contact with a solution whose pH is 10 2 5 Calculate the emf of the cell in which the following reaction takes place: Ni(s) + 2Ag+ (0
1
2103-2106
4 Calculate the potential of hydrogen electrode in contact with a solution whose pH is 10 2 5 Calculate the emf of the cell in which the following reaction takes place: Ni(s) + 2Ag+ (0 002 M) ® Ni2+ (0
1
2104-2107
2 5 Calculate the emf of the cell in which the following reaction takes place: Ni(s) + 2Ag+ (0 002 M) ® Ni2+ (0 160 M) + 2Ag(s) Given that o Ecell = 1