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9
3139-3142
93494 u and m ( 28 13 Al ) = 27 98191 u Rationalised 2023-24 Physics 322 13 7 The fission properties of 239 94 Pu are very similar to those of 235 92 U
9
3140-3143
98191 u Rationalised 2023-24 Physics 322 13 7 The fission properties of 239 94 Pu are very similar to those of 235 92 U The average energy released per fission is 180 MeV
9
3141-3144
Rationalised 2023-24 Physics 322 13 7 The fission properties of 239 94 Pu are very similar to those of 235 92 U The average energy released per fission is 180 MeV How much energy, in MeV, is released if all the atoms in 1 kg of pure 239 94 Pu undergo fission
9
3142-3145
7 The fission properties of 239 94 Pu are very similar to those of 235 92 U The average energy released per fission is 180 MeV How much energy, in MeV, is released if all the atoms in 1 kg of pure 239 94 Pu undergo fission 13
9
3143-3146
The average energy released per fission is 180 MeV How much energy, in MeV, is released if all the atoms in 1 kg of pure 239 94 Pu undergo fission 13 8 How long can an electric lamp of 100W be kept glowing by fusion of 2
9
3144-3147
How much energy, in MeV, is released if all the atoms in 1 kg of pure 239 94 Pu undergo fission 13 8 How long can an electric lamp of 100W be kept glowing by fusion of 2 0 kg of deuterium
9
3145-3148
13 8 How long can an electric lamp of 100W be kept glowing by fusion of 2 0 kg of deuterium Take the fusion reaction as 2 2 3 1 1 2 H+ H He+n+3
9
3146-3149
8 How long can an electric lamp of 100W be kept glowing by fusion of 2 0 kg of deuterium Take the fusion reaction as 2 2 3 1 1 2 H+ H He+n+3 27 MeV β†’ 13
9
3147-3150
0 kg of deuterium Take the fusion reaction as 2 2 3 1 1 2 H+ H He+n+3 27 MeV β†’ 13 9 Calculate the height of the potential barrier for a head on collision of two deuterons
9
3148-3151
Take the fusion reaction as 2 2 3 1 1 2 H+ H He+n+3 27 MeV β†’ 13 9 Calculate the height of the potential barrier for a head on collision of two deuterons (Hint: The height of the potential barrier is given by the Coulomb repulsion between the two deuterons when they just touch each other
9
3149-3152
27 MeV β†’ 13 9 Calculate the height of the potential barrier for a head on collision of two deuterons (Hint: The height of the potential barrier is given by the Coulomb repulsion between the two deuterons when they just touch each other Assume that they can be taken as hard spheres of radius 2
9
3150-3153
9 Calculate the height of the potential barrier for a head on collision of two deuterons (Hint: The height of the potential barrier is given by the Coulomb repulsion between the two deuterons when they just touch each other Assume that they can be taken as hard spheres of radius 2 0 fm
9
3151-3154
(Hint: The height of the potential barrier is given by the Coulomb repulsion between the two deuterons when they just touch each other Assume that they can be taken as hard spheres of radius 2 0 fm ) 13
9
3152-3155
Assume that they can be taken as hard spheres of radius 2 0 fm ) 13 10 From the relation R = R0A1/3, where R0 is a constant and A is the mass number of a nucleus, show that the nuclear matter density is nearly constant (i
9
3153-3156
0 fm ) 13 10 From the relation R = R0A1/3, where R0 is a constant and A is the mass number of a nucleus, show that the nuclear matter density is nearly constant (i e
9
3154-3157
) 13 10 From the relation R = R0A1/3, where R0 is a constant and A is the mass number of a nucleus, show that the nuclear matter density is nearly constant (i e independent of A)
9
3155-3158
10 From the relation R = R0A1/3, where R0 is a constant and A is the mass number of a nucleus, show that the nuclear matter density is nearly constant (i e independent of A) Rationalised 2023-24 14
9
3156-3159
e independent of A) Rationalised 2023-24 14 1 INTRODUCTION Devices in which a controlled flow of electrons can be obtained are the basic building blocks of all the electronic circuits
9
3157-3160
independent of A) Rationalised 2023-24 14 1 INTRODUCTION Devices in which a controlled flow of electrons can be obtained are the basic building blocks of all the electronic circuits Before the discovery of transistor in 1948, such devices were mostly vacuum tubes (also called valves) like the vacuum diode which has two electrodes, viz
9
3158-3161
Rationalised 2023-24 14 1 INTRODUCTION Devices in which a controlled flow of electrons can be obtained are the basic building blocks of all the electronic circuits Before the discovery of transistor in 1948, such devices were mostly vacuum tubes (also called valves) like the vacuum diode which has two electrodes, viz , anode (often called plate) and cathode; triode which has three electrodes – cathode, plate and grid; tetrode and pentode (respectively with 4 and 5 electrodes)
9
3159-3162
1 INTRODUCTION Devices in which a controlled flow of electrons can be obtained are the basic building blocks of all the electronic circuits Before the discovery of transistor in 1948, such devices were mostly vacuum tubes (also called valves) like the vacuum diode which has two electrodes, viz , anode (often called plate) and cathode; triode which has three electrodes – cathode, plate and grid; tetrode and pentode (respectively with 4 and 5 electrodes) In a vacuum tube, the electrons are supplied by a heated cathode and the controlled flow of these electrons in vacuum is obtained by varying the voltage between its different electrodes
9
3160-3163
Before the discovery of transistor in 1948, such devices were mostly vacuum tubes (also called valves) like the vacuum diode which has two electrodes, viz , anode (often called plate) and cathode; triode which has three electrodes – cathode, plate and grid; tetrode and pentode (respectively with 4 and 5 electrodes) In a vacuum tube, the electrons are supplied by a heated cathode and the controlled flow of these electrons in vacuum is obtained by varying the voltage between its different electrodes Vacuum is required in the inter-electrode space; otherwise the moving electrons may lose their energy on collision with the air molecules in their path
9
3161-3164
, anode (often called plate) and cathode; triode which has three electrodes – cathode, plate and grid; tetrode and pentode (respectively with 4 and 5 electrodes) In a vacuum tube, the electrons are supplied by a heated cathode and the controlled flow of these electrons in vacuum is obtained by varying the voltage between its different electrodes Vacuum is required in the inter-electrode space; otherwise the moving electrons may lose their energy on collision with the air molecules in their path In these devices the electrons can flow only from the cathode to the anode (i
9
3162-3165
In a vacuum tube, the electrons are supplied by a heated cathode and the controlled flow of these electrons in vacuum is obtained by varying the voltage between its different electrodes Vacuum is required in the inter-electrode space; otherwise the moving electrons may lose their energy on collision with the air molecules in their path In these devices the electrons can flow only from the cathode to the anode (i e
9
3163-3166
Vacuum is required in the inter-electrode space; otherwise the moving electrons may lose their energy on collision with the air molecules in their path In these devices the electrons can flow only from the cathode to the anode (i e , only in one direction)
9
3164-3167
In these devices the electrons can flow only from the cathode to the anode (i e , only in one direction) Therefore, such devices are generally referred to as valves
9
3165-3168
e , only in one direction) Therefore, such devices are generally referred to as valves These vacuum tube devices are bulky, consume high power, operate generally at high voltages (~100 V) and have limited life and low reliability
9
3166-3169
, only in one direction) Therefore, such devices are generally referred to as valves These vacuum tube devices are bulky, consume high power, operate generally at high voltages (~100 V) and have limited life and low reliability The seed of the development of modern solid-state semiconductor electronics goes back to 1930’s when it was realised that some solid- state semiconductors and their junctions offer the possibility of controlling the number and the direction of flow of charge carriers through them
9
3167-3170
Therefore, such devices are generally referred to as valves These vacuum tube devices are bulky, consume high power, operate generally at high voltages (~100 V) and have limited life and low reliability The seed of the development of modern solid-state semiconductor electronics goes back to 1930’s when it was realised that some solid- state semiconductors and their junctions offer the possibility of controlling the number and the direction of flow of charge carriers through them Simple excitations like light, heat or small applied voltage can change the number of mobile charges in a semiconductor
9
3168-3171
These vacuum tube devices are bulky, consume high power, operate generally at high voltages (~100 V) and have limited life and low reliability The seed of the development of modern solid-state semiconductor electronics goes back to 1930’s when it was realised that some solid- state semiconductors and their junctions offer the possibility of controlling the number and the direction of flow of charge carriers through them Simple excitations like light, heat or small applied voltage can change the number of mobile charges in a semiconductor Note that the supply Chapter Fourteen SEMICONDUCTOR ELECTRONICS: MATERIALS, DEVICES AND SIMPLE CIRCUITS Rationalised 2023-24 Physics 324 and flow of charge carriers in the semiconductor devices are within the solid itself, while in the earlier vacuum tubes/valves, the mobile electrons were obtained from a heated cathode and they were made to flow in an evacuated space or vacuum
9
3169-3172
The seed of the development of modern solid-state semiconductor electronics goes back to 1930’s when it was realised that some solid- state semiconductors and their junctions offer the possibility of controlling the number and the direction of flow of charge carriers through them Simple excitations like light, heat or small applied voltage can change the number of mobile charges in a semiconductor Note that the supply Chapter Fourteen SEMICONDUCTOR ELECTRONICS: MATERIALS, DEVICES AND SIMPLE CIRCUITS Rationalised 2023-24 Physics 324 and flow of charge carriers in the semiconductor devices are within the solid itself, while in the earlier vacuum tubes/valves, the mobile electrons were obtained from a heated cathode and they were made to flow in an evacuated space or vacuum No external heating or large evacuated space is required by the semiconductor devices
9
3170-3173
Simple excitations like light, heat or small applied voltage can change the number of mobile charges in a semiconductor Note that the supply Chapter Fourteen SEMICONDUCTOR ELECTRONICS: MATERIALS, DEVICES AND SIMPLE CIRCUITS Rationalised 2023-24 Physics 324 and flow of charge carriers in the semiconductor devices are within the solid itself, while in the earlier vacuum tubes/valves, the mobile electrons were obtained from a heated cathode and they were made to flow in an evacuated space or vacuum No external heating or large evacuated space is required by the semiconductor devices They are small in size, consume low power, operate at low voltages and have long life and high reliability
9
3171-3174
Note that the supply Chapter Fourteen SEMICONDUCTOR ELECTRONICS: MATERIALS, DEVICES AND SIMPLE CIRCUITS Rationalised 2023-24 Physics 324 and flow of charge carriers in the semiconductor devices are within the solid itself, while in the earlier vacuum tubes/valves, the mobile electrons were obtained from a heated cathode and they were made to flow in an evacuated space or vacuum No external heating or large evacuated space is required by the semiconductor devices They are small in size, consume low power, operate at low voltages and have long life and high reliability Even the Cathode Ray Tubes (CRT) used in television and computer monitors which work on the principle of vacuum tubes are being replaced by Liquid Crystal Display (LCD) monitors with supporting solid state electronics
9
3172-3175
No external heating or large evacuated space is required by the semiconductor devices They are small in size, consume low power, operate at low voltages and have long life and high reliability Even the Cathode Ray Tubes (CRT) used in television and computer monitors which work on the principle of vacuum tubes are being replaced by Liquid Crystal Display (LCD) monitors with supporting solid state electronics Much before the full implications of the semiconductor devices was formally understood, a naturally occurring crystal of galena (Lead sulphide, PbS) with a metal point contact attached to it was used as detector of radio waves
9
3173-3176
They are small in size, consume low power, operate at low voltages and have long life and high reliability Even the Cathode Ray Tubes (CRT) used in television and computer monitors which work on the principle of vacuum tubes are being replaced by Liquid Crystal Display (LCD) monitors with supporting solid state electronics Much before the full implications of the semiconductor devices was formally understood, a naturally occurring crystal of galena (Lead sulphide, PbS) with a metal point contact attached to it was used as detector of radio waves In the following sections, we will introduce the basic concepts of semiconductor physics and discuss some semiconductor devices like junction diodes (a 2-electrode device) and bipolar junction transistor (a 3-electrode device)
9
3174-3177
Even the Cathode Ray Tubes (CRT) used in television and computer monitors which work on the principle of vacuum tubes are being replaced by Liquid Crystal Display (LCD) monitors with supporting solid state electronics Much before the full implications of the semiconductor devices was formally understood, a naturally occurring crystal of galena (Lead sulphide, PbS) with a metal point contact attached to it was used as detector of radio waves In the following sections, we will introduce the basic concepts of semiconductor physics and discuss some semiconductor devices like junction diodes (a 2-electrode device) and bipolar junction transistor (a 3-electrode device) A few circuits illustrating their applications will also be described
9
3175-3178
Much before the full implications of the semiconductor devices was formally understood, a naturally occurring crystal of galena (Lead sulphide, PbS) with a metal point contact attached to it was used as detector of radio waves In the following sections, we will introduce the basic concepts of semiconductor physics and discuss some semiconductor devices like junction diodes (a 2-electrode device) and bipolar junction transistor (a 3-electrode device) A few circuits illustrating their applications will also be described 14
9
3176-3179
In the following sections, we will introduce the basic concepts of semiconductor physics and discuss some semiconductor devices like junction diodes (a 2-electrode device) and bipolar junction transistor (a 3-electrode device) A few circuits illustrating their applications will also be described 14 2 CLASSIFICATION OF METALS, CONDUCTORS AND SEMICONDUCTORS On the basis of conductivity On the basis of the relative values of electrical conductivity (s ) or resistivity (r = 1/s ), the solids are broadly classified as: (i) Metals: They possess very low resistivity (or high conductivity)
9
3177-3180
A few circuits illustrating their applications will also be described 14 2 CLASSIFICATION OF METALS, CONDUCTORS AND SEMICONDUCTORS On the basis of conductivity On the basis of the relative values of electrical conductivity (s ) or resistivity (r = 1/s ), the solids are broadly classified as: (i) Metals: They possess very low resistivity (or high conductivity) r ~ 10–2 – 10–8 W m s ~ 102 – 108 S m–1 (ii) Semiconductors: They have resistivity or conductivity intermediate to metals and insulators
9
3178-3181
14 2 CLASSIFICATION OF METALS, CONDUCTORS AND SEMICONDUCTORS On the basis of conductivity On the basis of the relative values of electrical conductivity (s ) or resistivity (r = 1/s ), the solids are broadly classified as: (i) Metals: They possess very low resistivity (or high conductivity) r ~ 10–2 – 10–8 W m s ~ 102 – 108 S m–1 (ii) Semiconductors: They have resistivity or conductivity intermediate to metals and insulators r ~ 10–5 – 106 W m s ~ 105 – 10–6 S m–1 (iii)Insulators: They have high resistivity (or low conductivity)
9
3179-3182
2 CLASSIFICATION OF METALS, CONDUCTORS AND SEMICONDUCTORS On the basis of conductivity On the basis of the relative values of electrical conductivity (s ) or resistivity (r = 1/s ), the solids are broadly classified as: (i) Metals: They possess very low resistivity (or high conductivity) r ~ 10–2 – 10–8 W m s ~ 102 – 108 S m–1 (ii) Semiconductors: They have resistivity or conductivity intermediate to metals and insulators r ~ 10–5 – 106 W m s ~ 105 – 10–6 S m–1 (iii)Insulators: They have high resistivity (or low conductivity) r ~ 1011 – 1019 W m s ~ 10–11 – 10–19 S m–1 The values of r and s given above are indicative of magnitude and could well go outside the ranges as well
9
3180-3183
r ~ 10–2 – 10–8 W m s ~ 102 – 108 S m–1 (ii) Semiconductors: They have resistivity or conductivity intermediate to metals and insulators r ~ 10–5 – 106 W m s ~ 105 – 10–6 S m–1 (iii)Insulators: They have high resistivity (or low conductivity) r ~ 1011 – 1019 W m s ~ 10–11 – 10–19 S m–1 The values of r and s given above are indicative of magnitude and could well go outside the ranges as well Relative values of the resistivity are not the only criteria for distinguishing metals, insulators and semiconductors from each other
9
3181-3184
r ~ 10–5 – 106 W m s ~ 105 – 10–6 S m–1 (iii)Insulators: They have high resistivity (or low conductivity) r ~ 1011 – 1019 W m s ~ 10–11 – 10–19 S m–1 The values of r and s given above are indicative of magnitude and could well go outside the ranges as well Relative values of the resistivity are not the only criteria for distinguishing metals, insulators and semiconductors from each other There are some other differences, which will become clear as we go along in this chapter
9
3182-3185
r ~ 1011 – 1019 W m s ~ 10–11 – 10–19 S m–1 The values of r and s given above are indicative of magnitude and could well go outside the ranges as well Relative values of the resistivity are not the only criteria for distinguishing metals, insulators and semiconductors from each other There are some other differences, which will become clear as we go along in this chapter Our interest in this chapter is in the study of semiconductors which could be: (i) Elemental semiconductors: Si and Ge (ii) Compound semiconductors: Examples are: Β· Inorganic: CdS, GaAs, CdSe, InP, etc
9
3183-3186
Relative values of the resistivity are not the only criteria for distinguishing metals, insulators and semiconductors from each other There are some other differences, which will become clear as we go along in this chapter Our interest in this chapter is in the study of semiconductors which could be: (i) Elemental semiconductors: Si and Ge (ii) Compound semiconductors: Examples are: Β· Inorganic: CdS, GaAs, CdSe, InP, etc Β· Organic: anthracene, doped pthalocyanines, etc
9
3184-3187
There are some other differences, which will become clear as we go along in this chapter Our interest in this chapter is in the study of semiconductors which could be: (i) Elemental semiconductors: Si and Ge (ii) Compound semiconductors: Examples are: Β· Inorganic: CdS, GaAs, CdSe, InP, etc Β· Organic: anthracene, doped pthalocyanines, etc Β· Organic polymers: polypyrrole, polyaniline, polythiophene, etc
9
3185-3188
Our interest in this chapter is in the study of semiconductors which could be: (i) Elemental semiconductors: Si and Ge (ii) Compound semiconductors: Examples are: Β· Inorganic: CdS, GaAs, CdSe, InP, etc Β· Organic: anthracene, doped pthalocyanines, etc Β· Organic polymers: polypyrrole, polyaniline, polythiophene, etc Most of the currently available semiconductor devices are based on elemental semiconductors Si or Ge and compound inorganic semiconductors
9
3186-3189
Β· Organic: anthracene, doped pthalocyanines, etc Β· Organic polymers: polypyrrole, polyaniline, polythiophene, etc Most of the currently available semiconductor devices are based on elemental semiconductors Si or Ge and compound inorganic semiconductors However, after 1990, a few semiconductor devices using Rationalised 2023-24 325 Semiconductor Electronics: Materials, Devices and Simple Circuits organic semiconductors and semiconducting polymers have been developed signalling the birth of a futuristic technology of polymer- electronics and molecular-electronics
9
3187-3190
Β· Organic polymers: polypyrrole, polyaniline, polythiophene, etc Most of the currently available semiconductor devices are based on elemental semiconductors Si or Ge and compound inorganic semiconductors However, after 1990, a few semiconductor devices using Rationalised 2023-24 325 Semiconductor Electronics: Materials, Devices and Simple Circuits organic semiconductors and semiconducting polymers have been developed signalling the birth of a futuristic technology of polymer- electronics and molecular-electronics In this chapter, we will restrict ourselves to the study of inorganic semiconductors, particularly elemental semiconductors Si and Ge
9
3188-3191
Most of the currently available semiconductor devices are based on elemental semiconductors Si or Ge and compound inorganic semiconductors However, after 1990, a few semiconductor devices using Rationalised 2023-24 325 Semiconductor Electronics: Materials, Devices and Simple Circuits organic semiconductors and semiconducting polymers have been developed signalling the birth of a futuristic technology of polymer- electronics and molecular-electronics In this chapter, we will restrict ourselves to the study of inorganic semiconductors, particularly elemental semiconductors Si and Ge The general concepts introduced here for discussing the elemental semiconductors, by-and-large, apply to most of the compound semiconductors as well
9
3189-3192
However, after 1990, a few semiconductor devices using Rationalised 2023-24 325 Semiconductor Electronics: Materials, Devices and Simple Circuits organic semiconductors and semiconducting polymers have been developed signalling the birth of a futuristic technology of polymer- electronics and molecular-electronics In this chapter, we will restrict ourselves to the study of inorganic semiconductors, particularly elemental semiconductors Si and Ge The general concepts introduced here for discussing the elemental semiconductors, by-and-large, apply to most of the compound semiconductors as well On the basis of energy bands According to the Bohr atomic model, in an isolated atom the energy of any of its electrons is decided by the orbit in which it revolves
9
3190-3193
In this chapter, we will restrict ourselves to the study of inorganic semiconductors, particularly elemental semiconductors Si and Ge The general concepts introduced here for discussing the elemental semiconductors, by-and-large, apply to most of the compound semiconductors as well On the basis of energy bands According to the Bohr atomic model, in an isolated atom the energy of any of its electrons is decided by the orbit in which it revolves But when the atoms come together to form a solid they are close to each other
9
3191-3194
The general concepts introduced here for discussing the elemental semiconductors, by-and-large, apply to most of the compound semiconductors as well On the basis of energy bands According to the Bohr atomic model, in an isolated atom the energy of any of its electrons is decided by the orbit in which it revolves But when the atoms come together to form a solid they are close to each other So the outer orbits of electrons from neighbouring atoms would come very close or could even overlap
9
3192-3195
On the basis of energy bands According to the Bohr atomic model, in an isolated atom the energy of any of its electrons is decided by the orbit in which it revolves But when the atoms come together to form a solid they are close to each other So the outer orbits of electrons from neighbouring atoms would come very close or could even overlap This would make the nature of electron motion in a solid very different from that in an isolated atom
9
3193-3196
But when the atoms come together to form a solid they are close to each other So the outer orbits of electrons from neighbouring atoms would come very close or could even overlap This would make the nature of electron motion in a solid very different from that in an isolated atom Inside the crystal each electron has a unique position and no two electrons see exactly the same pattern of surrounding charges
9
3194-3197
So the outer orbits of electrons from neighbouring atoms would come very close or could even overlap This would make the nature of electron motion in a solid very different from that in an isolated atom Inside the crystal each electron has a unique position and no two electrons see exactly the same pattern of surrounding charges Because of this, each electron will have a different energy level
9
3195-3198
This would make the nature of electron motion in a solid very different from that in an isolated atom Inside the crystal each electron has a unique position and no two electrons see exactly the same pattern of surrounding charges Because of this, each electron will have a different energy level These different energy levels with continuous energy variation form what are called energy bands
9
3196-3199
Inside the crystal each electron has a unique position and no two electrons see exactly the same pattern of surrounding charges Because of this, each electron will have a different energy level These different energy levels with continuous energy variation form what are called energy bands The energy band which includes the energy levels of the valence electrons is called the valence band
9
3197-3200
Because of this, each electron will have a different energy level These different energy levels with continuous energy variation form what are called energy bands The energy band which includes the energy levels of the valence electrons is called the valence band The energy band above the valence band is called the conduction band
9
3198-3201
These different energy levels with continuous energy variation form what are called energy bands The energy band which includes the energy levels of the valence electrons is called the valence band The energy band above the valence band is called the conduction band With no external energy, all the valence electrons will reside in the valence band
9
3199-3202
The energy band which includes the energy levels of the valence electrons is called the valence band The energy band above the valence band is called the conduction band With no external energy, all the valence electrons will reside in the valence band If the lowest level in the conduction band happens to be lower than the highest level of the valence band, the electrons from the valence band can easily move into the conduction band
9
3200-3203
The energy band above the valence band is called the conduction band With no external energy, all the valence electrons will reside in the valence band If the lowest level in the conduction band happens to be lower than the highest level of the valence band, the electrons from the valence band can easily move into the conduction band Normally the conduction band is empty
9
3201-3204
With no external energy, all the valence electrons will reside in the valence band If the lowest level in the conduction band happens to be lower than the highest level of the valence band, the electrons from the valence band can easily move into the conduction band Normally the conduction band is empty But when it overlaps on the valence band electrons can move freely into it
9
3202-3205
If the lowest level in the conduction band happens to be lower than the highest level of the valence band, the electrons from the valence band can easily move into the conduction band Normally the conduction band is empty But when it overlaps on the valence band electrons can move freely into it This is the case with metallic conductors
9
3203-3206
Normally the conduction band is empty But when it overlaps on the valence band electrons can move freely into it This is the case with metallic conductors If there is some gap between the conduction band and the valence band, electrons in the valence band all remain bound and no free electrons are available in the conduction band
9
3204-3207
But when it overlaps on the valence band electrons can move freely into it This is the case with metallic conductors If there is some gap between the conduction band and the valence band, electrons in the valence band all remain bound and no free electrons are available in the conduction band This makes the material an insulator
9
3205-3208
This is the case with metallic conductors If there is some gap between the conduction band and the valence band, electrons in the valence band all remain bound and no free electrons are available in the conduction band This makes the material an insulator But some of the electrons from the valence band may gain external energy to cross the gap between the conduction band and the valence band
9
3206-3209
If there is some gap between the conduction band and the valence band, electrons in the valence band all remain bound and no free electrons are available in the conduction band This makes the material an insulator But some of the electrons from the valence band may gain external energy to cross the gap between the conduction band and the valence band Then these electrons will move into the conduction band
9
3207-3210
This makes the material an insulator But some of the electrons from the valence band may gain external energy to cross the gap between the conduction band and the valence band Then these electrons will move into the conduction band At the same time they will create vacant energy levels in the valence band where other valence electrons can move
9
3208-3211
But some of the electrons from the valence band may gain external energy to cross the gap between the conduction band and the valence band Then these electrons will move into the conduction band At the same time they will create vacant energy levels in the valence band where other valence electrons can move Thus the process creates the possibility of conduction due to electrons in conduction band as well as due to vacancies in the valence band
9
3209-3212
Then these electrons will move into the conduction band At the same time they will create vacant energy levels in the valence band where other valence electrons can move Thus the process creates the possibility of conduction due to electrons in conduction band as well as due to vacancies in the valence band Let us consider what happens in the case of Si or Ge crystal containing N atoms
9
3210-3213
At the same time they will create vacant energy levels in the valence band where other valence electrons can move Thus the process creates the possibility of conduction due to electrons in conduction band as well as due to vacancies in the valence band Let us consider what happens in the case of Si or Ge crystal containing N atoms For Si, the outermost orbit is the third orbit (n = 3), while for Ge it is the fourth orbit (n = 4)
9
3211-3214
Thus the process creates the possibility of conduction due to electrons in conduction band as well as due to vacancies in the valence band Let us consider what happens in the case of Si or Ge crystal containing N atoms For Si, the outermost orbit is the third orbit (n = 3), while for Ge it is the fourth orbit (n = 4) The number of electrons in the outermost orbit is 4 (2s and 2p electrons)
9
3212-3215
Let us consider what happens in the case of Si or Ge crystal containing N atoms For Si, the outermost orbit is the third orbit (n = 3), while for Ge it is the fourth orbit (n = 4) The number of electrons in the outermost orbit is 4 (2s and 2p electrons) Hence, the total number of outer electrons in the crystal is 4N
9
3213-3216
For Si, the outermost orbit is the third orbit (n = 3), while for Ge it is the fourth orbit (n = 4) The number of electrons in the outermost orbit is 4 (2s and 2p electrons) Hence, the total number of outer electrons in the crystal is 4N The maximum possible number of electrons in the outer orbit is 8 (2s + 6p electrons)
9
3214-3217
The number of electrons in the outermost orbit is 4 (2s and 2p electrons) Hence, the total number of outer electrons in the crystal is 4N The maximum possible number of electrons in the outer orbit is 8 (2s + 6p electrons) So, for the 4N valence electrons there are 8N available energy states
9
3215-3218
Hence, the total number of outer electrons in the crystal is 4N The maximum possible number of electrons in the outer orbit is 8 (2s + 6p electrons) So, for the 4N valence electrons there are 8N available energy states These 8N discrete energy levels can either form a continuous band or they may be grouped in different bands depending upon the distance between the atoms in the crystal (see box on Band Theory of Solids)
9
3216-3219
The maximum possible number of electrons in the outer orbit is 8 (2s + 6p electrons) So, for the 4N valence electrons there are 8N available energy states These 8N discrete energy levels can either form a continuous band or they may be grouped in different bands depending upon the distance between the atoms in the crystal (see box on Band Theory of Solids) At the distance between the atoms in the crystal lattices of Si and Ge, the energy band of these 8N states is split apart into two which are separated by an energy gap Eg (Fig
9
3217-3220
So, for the 4N valence electrons there are 8N available energy states These 8N discrete energy levels can either form a continuous band or they may be grouped in different bands depending upon the distance between the atoms in the crystal (see box on Band Theory of Solids) At the distance between the atoms in the crystal lattices of Si and Ge, the energy band of these 8N states is split apart into two which are separated by an energy gap Eg (Fig 14
9
3218-3221
These 8N discrete energy levels can either form a continuous band or they may be grouped in different bands depending upon the distance between the atoms in the crystal (see box on Band Theory of Solids) At the distance between the atoms in the crystal lattices of Si and Ge, the energy band of these 8N states is split apart into two which are separated by an energy gap Eg (Fig 14 1)
9
3219-3222
At the distance between the atoms in the crystal lattices of Si and Ge, the energy band of these 8N states is split apart into two which are separated by an energy gap Eg (Fig 14 1) The lower band which is completely occupied by the 4N valence electrons at temperature of absolute zero is the valence band
9
3220-3223
14 1) The lower band which is completely occupied by the 4N valence electrons at temperature of absolute zero is the valence band The other band consisting of 4N energy states, called the conduction band, is completely empty at absolute zero
9
3221-3224
1) The lower band which is completely occupied by the 4N valence electrons at temperature of absolute zero is the valence band The other band consisting of 4N energy states, called the conduction band, is completely empty at absolute zero Rationalised 2023-24 Physics 326 The lowest energy level in the conduction band is shown as EC and highest energy level in the valence band is shown as EV
9
3222-3225
The lower band which is completely occupied by the 4N valence electrons at temperature of absolute zero is the valence band The other band consisting of 4N energy states, called the conduction band, is completely empty at absolute zero Rationalised 2023-24 Physics 326 The lowest energy level in the conduction band is shown as EC and highest energy level in the valence band is shown as EV Above EC and below EV there are a large number of closely spaced energy levels, as shown in Fig
9
3223-3226
The other band consisting of 4N energy states, called the conduction band, is completely empty at absolute zero Rationalised 2023-24 Physics 326 The lowest energy level in the conduction band is shown as EC and highest energy level in the valence band is shown as EV Above EC and below EV there are a large number of closely spaced energy levels, as shown in Fig 14
9
3224-3227
Rationalised 2023-24 Physics 326 The lowest energy level in the conduction band is shown as EC and highest energy level in the valence band is shown as EV Above EC and below EV there are a large number of closely spaced energy levels, as shown in Fig 14 1
9
3225-3228
Above EC and below EV there are a large number of closely spaced energy levels, as shown in Fig 14 1 The gap between the top of the valence band and bottom of the conduction band is called the energy band gap (Energy gap Eg)
9
3226-3229
14 1 The gap between the top of the valence band and bottom of the conduction band is called the energy band gap (Energy gap Eg) It may be large, small, or zero, depending upon the material
9
3227-3230
1 The gap between the top of the valence band and bottom of the conduction band is called the energy band gap (Energy gap Eg) It may be large, small, or zero, depending upon the material These different situations, are depicted in Fig
9
3228-3231
The gap between the top of the valence band and bottom of the conduction band is called the energy band gap (Energy gap Eg) It may be large, small, or zero, depending upon the material These different situations, are depicted in Fig 14
9
3229-3232
It may be large, small, or zero, depending upon the material These different situations, are depicted in Fig 14 2 and discussed below: Case I: This refers to a situation, as shown in Fig
9
3230-3233
These different situations, are depicted in Fig 14 2 and discussed below: Case I: This refers to a situation, as shown in Fig 14
9
3231-3234
14 2 and discussed below: Case I: This refers to a situation, as shown in Fig 14 2(a)
9
3232-3235
2 and discussed below: Case I: This refers to a situation, as shown in Fig 14 2(a) One can have a metal either when the conduction band is partially filled and the balanced band is partially empty or when the conduction and valance bands overlap
9
3233-3236
14 2(a) One can have a metal either when the conduction band is partially filled and the balanced band is partially empty or when the conduction and valance bands overlap When there is overlap electrons from valence band can easily move into the conduction band
9
3234-3237
2(a) One can have a metal either when the conduction band is partially filled and the balanced band is partially empty or when the conduction and valance bands overlap When there is overlap electrons from valence band can easily move into the conduction band This situation makes a large number of electrons available for electrical conduction
9
3235-3238
One can have a metal either when the conduction band is partially filled and the balanced band is partially empty or when the conduction and valance bands overlap When there is overlap electrons from valence band can easily move into the conduction band This situation makes a large number of electrons available for electrical conduction When the valence band is partially empty, electrons from its lower level can move to higher level making conduction possible
9
3236-3239
When there is overlap electrons from valence band can easily move into the conduction band This situation makes a large number of electrons available for electrical conduction When the valence band is partially empty, electrons from its lower level can move to higher level making conduction possible Therefore, the resistance of such materials is low or the conductivity is high
9
3237-3240
This situation makes a large number of electrons available for electrical conduction When the valence band is partially empty, electrons from its lower level can move to higher level making conduction possible Therefore, the resistance of such materials is low or the conductivity is high FIGURE 14
9
3238-3241
When the valence band is partially empty, electrons from its lower level can move to higher level making conduction possible Therefore, the resistance of such materials is low or the conductivity is high FIGURE 14 2 Difference between energy bands of (a) metals, (b) insulators and (c) semiconductors