Why is optimistic locking faster than pessimistic locking? Both forms of locking cause a process to wait for a correct copy of the record if its currently in use by another process. With pessimistic locking, the lock mechanism comes from the DB itself (a native lock object), whereas with optimistic locking, the lock mechanism is some form of row versioning like a timestamp to check whether a record is "stale" or not.

But both cause a 2nd process to hang. So I ask: why is optimistic locking generally considered faster/superior than pessimistic locking? And, are there are use cases where pessimistic is preferred over optimistic? Thanks in advance!
You misunderstand optimistic locking.

Optimistic locking does not cause transactions to wait for each other.

Optimistic locking possibly causes a transaction to fail, but it does so without any "lock" ever having been taken.  And if a transaction fails because of optimistic locking, the user is required to start all over again.  The word "optimistic" derives from exactly the expectation that the condition that causes transactions to fail for this very reason, will occur only very exceptionally.  "Optimistic" locking is the approach that says "I will not be taking actual locks because I hope they won't be needed anyway.  If it turns out I was wrong about that, I will accept the inevitable failure.".