Does the 'ORDER BY' clause of a subquery pass through to the main results (POSTGRES) I've got a query written something like this.....

with subquery as
(
  SELECT A, B, C, D, 
  row_number() OVER(PARTITION BY X ORDER BY Y) as RN
  FROM blah blah
  ORDER BY A,B
  LIMIT 100
)
SELECT C,D
FROM subquery
WHERE RN=1


As you can see, the subquery is sorted, but the top-level query isn't.

The top level query doesn't do anything complicated, it just selects based on the partition by clause.

Will the sort order from the subquery be maintained in the final results?

Observation of the various data-sets I've tested against indicates the sort order IS maintained, but I'm not sure if this is just a lucky coincidence or not.
No, the order by or the sub-query will not influence the order of the outside result. 

If at all, it might be influenced by the order by of the window function. 

But you can never rely on that. 

If you need a specific order for the outer query that you can rely on, you have to use an order by there as well.