Can someone explain the relationship between asynchronous NSURL requests and GCD and NSOperationQueues?

I am not sure when to use each.

Right now, I have been "getting away" with asynchronous NSURL requests when I need to fetch/upload data to the server. But it has been suggested that I should use GCD. My problem is I do not know in what real life examples GCD would be better. Does anyone have any common use cases for me? And if I use GCD to store a queue of 10 asynchronous NSURL GET requests, for example, how would this benefit me? Does it even make sense to have an asynchronous NSURL request inside grand central dispatch queue or an NSOperationQueue?

Thank you!