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considers this warrant as permanent equity per ASC 815-40-35-2. As such, there is no value assigned to this extension. On November 1, 2016, the Company
launched a unit offering under the Company’s DSPP pursuant to which participants could purchase units comprised of seven shares
of Common Stock and seven Common Stock purchase warrants, at a per unit purchase price of $10. The warrant is referred to as “ZNWAE.” The ZNWAE warrants became
exercisable on May 1, 2017 and continued to be exercisable through May 1, 2020 at a per share exercise price of $1.00. On May 29, 2019, the Company
extended the termination date of the ZNWAE Warrant by one (1) year from the expiration date of May 1, 2020 to May 1, 2021. Zion considers
this warrant as permanent equity per ASC 815-40-35-2. As such, there is no value assigned to this extension. On September 15, 2020, the
Company extended the termination date of the ZNWAE Warrant by two (2) years from the expiration date of May 1, 2021 to May 1, 2023. Zion
considers this warrant as permanent equity per ASC 815-40-35-2. As such, there is no value assigned to this extension. The warrant terms provide
that if the Company’s Common Stock trades above $5.00 per share at the closing price for 15 consecutive trading days at any time
prior to the expiration date of the warrant, the Company may, in its sole discretion, accelerate the termination of the warrant upon providing
60 days advanced notice to the warrant holders. 36 On May 22, 2017, the Company
launched a new unit offering. This unit offering consisted of a new combination of common stock and warrants, a new time period in which
to purchase under the program, and a new unit price, but otherwise the same unit program features, conditions and terms in the Prospectus
Supplement applied. The unit offering terminated on July 12, 2017. This unit offering enabled participants to purchase Units of the Company’s
securities where each Unit (priced at $250.00 each) was comprised of (i) the number of shares of Common Stock determined by dividing $250.00
(the price of one Unit) by the average of the high and low sale prices of the Company’s Common Stock as reported on the NASDAQ on
the unit purchase date and (ii) Common Stock purchase warrants to purchase an additional 25 shares of Common Stock at a warrant exercise
price of $1.00 per share. The warrant is referred to as “ZNWAF.” All ZNWAF warrants became
exercisable on August 14, 2017 and continued to be exercisable through August 14, 2020 at a per share exercise price of $1.00. On May 29, 2019, the Company
extended the termination date of the ZNWAF Warrant by one (1) year from the expiration date of August 14, 2020 to August 14, 2021. Zion
considers this warrant as permanent equity per ASC 815-40-35-2. As such, there is no value assigned to this extension. On September 15, 2020, the
Company extended the termination date of the ZNWAF Warrant by two (2) years from the expiration date of August 14, 2021 to August 14,
2023. Zion considers this warrant as permanent equity per ASC 815-40-35-2. As such, there is no value assigned to this extension. The warrant terms provide
that if the Company’s Common Stock trades above $5.00 per share as the closing price for 15 consecutive trading days at any time
prior to the expiration date of the warrant, the Company has the sole discretion to accelerate the termination date of the warrant upon
providing 60 days advanced notice to the warrant holders. An Amendment No. 2 to the
Prospectus Supplement (as described below) was filed on October 12, 2017. Under Amendment No. 2, the
Company initiated another unit offering which terminated on December 6, 2017. This unit offering enabled participants to purchase Units
of the Company’s securities where each Unit (priced at $250.00 each) was comprised of (i) a certain number of shares of Common Stock
determined by dividing $250.00 (the price of one Unit) by the average of the high and low sale prices of the Company’s Common Stock
as reported on the NASDAQ on the unit purchase date and (ii) Common Stock purchase warrants to purchase an additional 15 shares of Common
Stock at a warrant exercise price of $1.00 per share. The warrant is referred to as “ZNWAG.” The warrants became exercisable on January 8, 2018 and continue to
be exercisable through January 8, 2024 at a revised per share exercise price of $.25. The warrant terms provide that if the Company’s
Common Stock trades above $5.00 per share as the closing price for 15 consecutive trading days at any time prior to the expiration date
of the warrant, the Company has the sole discretion to accelerate the termination date of the warrant upon providing 60 days advanced
notice to the warrant holders. On December 14, 2022, the
Company extended the termination date of the ZNWAG warrant by one (1) year from the expiration date of January 8, 2023 to January 8, 2024.
Zion considers this warrant as permanent equity per ASC 815-40-35-2. As such, there is no value assigned to this extension. On February 1, 2018, the Company
launched another unit offering which terminated on February 28, 2018. The unit offering consisted of Units of our securities where each
Unit (priced at $250.00 each) was comprised of (i) 50 shares of Common Stock and (ii) Common Stock purchase warrants to purchase an additional
50 shares of Common Stock. The investor’s Plan account was credited with the number of shares of the Company’s Common Stock
acquired under the Units purchased. Each warrant affords the investor the opportunity to purchase one share of Company Common Stock at
a warrant exercise price of $5.00. The warrant is referred to as “ZNWAH.” 37 The warrants became exercisable
on April 2, 2018 and continued to be exercisable through April 2, 2020 at a per share exercise price of $5.00, after the Company, on December
4, 2018, extended the termination date of the Warrant by one (1) year from the expiration date of April 2, 2019 to April 2, 2020. On May 29, 2019, the Company
extended the termination date of the ZNWAH Warrant by one (1) year from the expiration date of April 2, 2020 to April 2, 2021. Zion considers
this warrant as permanent equity per ASC 815-40-35-2. As such, there is no value assigned to this extension. On September 15, 2020, the
Company extended the termination date of the ZNWAH Warrant by two (2) years from the expiration date of April 2, 2021 to April 2, 2023.
Zion considers this warrant as permanent equity per ASC 815-40-35-2. As such, there is no value assigned to this extension. On August 21, 2018, the Company
initiated another unit offering, and it terminated on September 26, 2018. The unit offering consisted of Units of the Company’s
securities where each Unit (priced at $250.00 each) was comprised of (i) a certain number of shares of Common Stock determined by dividing
$250.00 (the price of one Unit) by the average of the high and low sale prices of the Company’s publicly traded common stock as
reported on the NASDAQ on the Unit Purchase Date and (ii) Common Stock purchase warrants to purchase an additional twenty-five (25) shares
of Common Stock. The investor’s Plan account was credited with the number of shares of the Company’s Common Stock acquired
under the Units purchased. Each warrant affords the investor the opportunity to purchase one share of Company Common Stock at a warrant
exercise price of $1.00. The warrant is referred to as “ZNWAJ.” The warrants became exercisable
on October 29, 2018 and continued to be exercisable through October 29, 2020 at a per share exercise price of $1.00, after the Company,
on December 4, 2018, extended the termination date of the Warrant by one (1) year from the expiration date of October 29, 2019 to October
29, 2020. On May 29, 2019, the Company
extended the termination date of the ZNWAJ Warrant by one (1) year from the expiration date of October 29, 2020 to October 29, 2021. Zion
considers this warrant as permanent equity per ASC 815-40-35-2. As such, there is no value assigned to this extension. On September 15, 2020, the
Company extended the termination date of the ZNWAJ Warrant by two (2) years from the expiration date of October 29, 2021 to October 29,
2023. Zion considers this warrant as permanent equity per ASC 815-40-35-2. As such, there is no value assigned to this extension. On December 10, 2018, the
Company initiated another unit offering, and it terminated on January 23, 2019. The unit offering consisted of Units of the Company’s
securities where each Unit (priced at $250.00 each) was comprised of (i) two hundred and fifty (250) shares of Common Stock and (ii) Common
Stock purchase warrants to purchase an additional two hundred and fifty (250) shares of Common Stock at a per share exercise price of
$0.01. The investor’s Plan account was credited with the number of shares of the Company’s Common Stock and Warrants that
are acquired under the Units purchased. Each warrant affords the participant the opportunity to purchase one share of our Common Stock
at a warrant exercise price of $0.01. The warrant is referred to as “ZNWAK.” The warrants became exercisable
on February 25, 2019 and continued to be exercisable through February 25, 2020 at a per share exercise price of $0.01. On May 29, 2019, the Company
extended the termination date of the ZNWAK warrant by one (1) year from the expiration date of February 25, 2020 to February 25, 2021.
Zion considers this warrant as permanent equity per ASC 815-40-35-2. As such, there is no value assigned to this extension. 38 On September 15, 2020, the
Company extended the termination date of the ZNWAK warrant by two (2) years from the expiration date of February 25, 2021 to February
25, 2023. Zion considers this warrant as permanent equity per ASC 815-40-35-2. As such, there is no value assigned to this extension. On April 24, 2019, the Company
initiated another unit offering, and it terminated on June 26, 2019, after the Company, on June 5, 2019, extended the termination date
of the unit offering. The unit offering consisted
of Units of the Company’s securities where each Unit (priced at $250.00 each) was comprised of (i) two hundred and fifty (250) shares
of Common Stock and (ii) Common Stock purchase warrants to purchase an additional fifty (50) shares of Common Stock at a per share exercise
price of $2.00. The investor’s Plan account was credited with the number of shares of the Company’s Common Stock and Warrants
acquired under the Units purchased. For Plan participants who enrolled into the Unit Program with the purchase of at least one Unit and
also enrolled in the separate Automatic Monthly Investments (“AMI”) program at a minimum of $50.00 per month or more, received
an additional twenty-five (25) warrants at an exercise price of $2.00 during this Unit Option Program. The twenty-five (25) additional
warrants were for enrolling into the AMI program. Existing subscribers to the AMI were entitled to the additional twenty-five (25) warrants
once, if they purchased at least one (1) unit during the Unit program. Each warrant affords the participant the opportunity to purchase
one share of our Common Stock at a warrant exercise price of $2.00. The warrant is referred to as “ZNWAL.” The warrants became exercisable
on August 26, 2019 and continued to be exercisable through August 26, 2021 at a per share exercise price of $2.00. On September 15, 2020, the
Company extended the termination date of the ZNWAL warrant by two (2) years from the expiration date of August 26, 2021 to August 26,
2023. Zion considers this warrant as permanent equity per ASC 815-40-35-2. As such, there is no value assigned to this extension. Under our Plan, the Company
under a Request For Waiver Program executed Waiver Term Sheets of a unit option program consisting of a Unit (shares of stock and warrants)
of its securities and subsequently an option program consisting of shares of stock to a participant. The participant’s Plan account
was credited with the number of shares of the Company’s Common Stock and Warrants that were acquired. Each warrant affords the participant
the opportunity to purchase one share of our Common Stock at a warrant exercise price of $1.00. The warrant shall have the company notation
of “ZNWAM.” The warrants will not be registered for trading on the OTCQX or any other stock market or trading market. The
warrants became exercisable on January 15, 2021 and continue to be exercisable through July 15, 2023 at a per share exercise price of
$0.05. On February 1, 2021, the Company
initiated a unit offering, and it terminated on March 17, 2021. The unit offering consisted
of Units of the Company’s securities where each Unit (priced at $250.00 each) was comprised of (i) the number of Common Stock shares
represented by the high-low average on the purchase date and (ii) Common Stock purchase warrants to purchase an additional twenty-five
(25) shares of Common Stock at a per share exercise price of $1.00. The investor’s Plan account was credited with the number of
shares of the Company’s Common Stock and Warrants acquired under the Units purchased. For Plan participants who enrolled into the