Under normal conditions, smoke would rise into the atmosphere and disperse, but an anticyclone was hanging over the region. This pushes air downwards, warming it as it descends. This creates an inversion, where air close to the ground is cooler than the air higher above it. So when the warm smoke comes out of the chimney, it is trapped. The inversion of 1952 also trapped particles and gases emitted from factory chimneys in the London area, along with pollution which the winds from the east had brought from industrial areas on the continent.
What is the difference between mist, fog and haze?
How do you forecast fog?