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* Exposure Controls/Personal Protection *
Respiratory Protection:IF PERS EXPOS CANNOT BE CNTRLD BELOW APPLIC
LIMITS BY VENT, WEAR NIOSH/MSHA APPRVD PROPERLY FITTED ORG
VAP/PARTICULATE RESP FOR PROT AGAINST MATLS IN ING SEC. WHEN
SANDING/ABRADING DRIED FILM, WEAR NI OSH/MSHA APPRVD DUST/MIST RESP
(SUPDAT)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATLS IN
INGREDIENTS SECTION IS MAINTAIN BELOW APPLIC EXPOS LIMITS.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
PH: 8.3-9.8. FIRE FIGHT PROC: PREVENT PRESSURE BUILDUP AND POSS
AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. EFTS OF OVEREXP: AT
NOT ATTAINABLE IN WORKPLACE. RESP PROT: FOR DUST WHICH MAY BE
GENERATED FROM PRODUCT, UNDERLYING PAINT/ABRASIVE.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ETHYLENE GLYCOL (SARA III)
Fraction by Wt: 0-5%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (QUARTZ)
OSHA PEL:SEE TABLE Z3
Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE; (CRISTOBALITE)
Fraction by Wt: 0-5%
OSHA PEL:SEE TABLE Z3
Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC)
OSHA PEL:2 MG/M3 RDUST
ACGIH TLV:2 MG/M3 RDUST
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
Ingred Name:OTHER PREC:CARBONATE (SEE ACGIH TLV LIST, PREFACE &
APPENDIX D), WHICH MAY BE PRESENT AT HAZ LEVS ONLY DURING (ING 7)
Ingred Name:ING 6: SANDING/ABRADING OF DRIED FILM,IF NO SPECIAL DUSTS
ARE LISTED IN ING SEC, APPLIC LIMITS FOR NUISANCE DUSTS(ING 8)
MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION).
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & UPPER
RESP SYS. IN CONFINED AREA VAPS IN HIGH CONCS MAY CAUSE HDCH,
NAUS/DIZZ. CHRONIC: LONG TERM EXPOS TO HIGH LEVS OF SILICA DUST,
WHICH CAN OCCUR ONLY WHEN SANDING/ABRA DING DRY FILM, MAY CAUSE
LUNG DMG (SILICOSIS) & POSS CANCER. ETHYLENE GLYCOL IS CONSIDERED
AN ANIMAL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE (QUARTZ,
CRISTOBALITE): ANTICIPATED TO BE A CARC, NTP SIXTH ANNUAL REPORT ON
CARCINOGENS, (ING 9)
Effects of Overexposure:HLTH HAZ:TERATOGEN. IT HAS BEEN SHOWN TO CAUSE
BIRTH DEFECTS IN RATS & MICE AT HIGH DOSES WHEN GIVEN IN DRINKING
WATER/BY GAVAGE. THERE IS NO EVIDENCE TO INDICATE IT CAUSES BIRTH
DEFECTS IN HUMANS. PR LNGD OVEREXP TO SOLV INGREDS MAY CAUSE
ADVERSE EFTS TO LIVER & URINARY SYS. RATS EXPOS TO TITANIUM DIOXIDE
DUST (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP
WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND
WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
GET MEDICAL ATTENTION. INGESTION: CALL MD IMMEDIATELY .
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT
EQUIP.WATER SPRAY MAY BE INEFT.IF WATER USED, FOG NOZZ ARE
PREF.WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
TRANSFER ONLY TO APPROVED CONTAINERS WITH COMPLETE AND APPROPRIATE
LABELING. DO NOT TAKE INTERNALLY.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. USE ONLY W/ADEQ VENT.
AVOID BRTHG VAP & SPRAY MIST. AVOID CONT W/SKIN & EYES. WASH HANDS
AFTER USING. COATING MAY CONTAIN MATLS CLASSIFIED AS NUISANCE
PARTICULATES, SUCHAS TITANIUM DIOXIDE/CALCIUM (ING 6)
* Physical/Chemical Properties *
Vapor Density:HVR/AIR
pH:SUPDAT
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:WASTE FROM PRODUCT IS NOT HAZARDOUS AS DEFINED
INCINERATE CLOSED CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL,
STATE, AND LOCAL REGUL ATIONS REGARDING POLLUTION.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT NORMALLY REQUIRED. USE NIOSH APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:NOT NORMALLY REQUIRED. PROCESSING OF LARGE QUANTITIES OF
FILM SHOULD BE HANDLED WITH LOCAL EXHAUST VENTILATION.
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
DROPS RAPIDLY AFTER PROCESSING. FIRST AID PROC: NOTES TO MD: PRLNG
CONT W/SKIN MAY PRODUCE ALKALI BURNS. EYE PROT. & FACESHIELD .
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POTASSIUM HYDROXIDE (CERCLA)
OSHA PEL:C 2 MG/M3
ACGIH TLV:C 2 MG/M3
Ingred Name:1 H-BENZOTRIAZOLE
Fraction by Wt: 1-5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:PHENETHYL PICOLINIUM BROMIDE; (N-PHENETHYL-2-PICOLINIUM
BROMIDE)
Fraction by Wt: 1-5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ZINC (II) NITRATE, HEXAHYDRATE (1:2:6); (ZINC NITRATE
HEXAHYDRATE)
Fraction by Wt: 0.1-1%
Ingred Name:SODIUM HYDROXIDE (CERCLA)
Fraction by Wt: 1-5%
OSHA PEL:2 MG/M3
ACGIH TLV:C 2 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: MAY BE AN IRRITANT.
SKIN: CORROSIVE. MAY CAUSE BURNS TO SKIN AND MOUTH. EYES:
CORROSIVE. EYE CONTACT WITH DEVELOPER MAY CAUSE PERMANENT EYE
DAMAGE. INGESTION: CORROSIVE. CHRONIC: NO NE CURRENTLY KNOWN.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
MED ATTN. SKIN: FLUSH AFFECTED AREA W/PLENTY OF WATER. INGEST:
RINSE MOUTH IMMED W/PLENTY OF WATER. DRINK WATER/CITRUS JUICES TO
DILUTE/NE UTRALIZE ANY ALKALI THAT MAY HAVE BEEN SWALLOWED. DO NOT
INDUCE VOMIT. SEEK MED ATTN IMMED. INHAL: REMOVE TO FRESH AIR.
SUPPORT BRTHG (GIVE OXYGEN/ARTF RESP) . (SUP DAT)
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:MIXTURE WILL NOT BURN. USE MEDIA SUITABLE FOR
SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:HANDLE FILM SO AS NOT TO BREAK DEVELOPER PODS
PRIOR TO FILM DEVELOPMENT. SMALL QUANTITIES OF DEVELOPER FLUID MAY
BE WIPED UP WITH A DAMP PAPER TOWEL USING CARE TO AVOID ANY SKIN OR
EYE CONTACT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:WARNING: CONTAINS ALKALI. EYE CONTACT
MAY CAUSE PERMANENT EYE DAMAGE. SKIN AND MOUTH CONTACT MAY CAUSE
IRRITATION OR BURNS.
Other Precautions:DO NOT GET IN EYES, ON SKIN, MOUTH OR CLOTHING.
* Physical/Chemical Properties *
Spec Gravity:1.1 (H*2O=1)
pH:SUPDAT
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Appearance and Odor:CREAM, WHITE, TAN GREY OR PINK VISCOUS LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:PRODUCT (FILM PACK, PICTURE AND THROW AWAY PART)
IS NOT CLASSIFIED OR REGULATED UNDER U.S. FEDERAL LAW AS "RCRA
HAZARDOUS" BEFORE OR AFTER PROCESSING. DISPOSE OF IN ACCORDANCE
WITH LOCAL, STATE AND FE DERAL REGULATIONS .
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF ADEQUATE VENTILATION CANNOT BE MAINTAINED,
Ventilation:PROVIDE CONSTANT FLOW OF FRESH AIR TO MEET TLV
REQUIREMENTS. OPEN WINDOWS & DOORS TO PERMIT FRESH AIR ENTRY
(SUPDAT)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH WITH SOAP AND WATER BEFORE EATING,
DRINKING SMOKING.
Supplemental Safety and Health
* Product Identification *
CAGE:0K1A4
* Composition/Information on Ingredients *
Ingred Name:STODDARD SOLVENT (MINERAL SPIRITS)
Ingred Name:VEHICLE
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ADDITIVES
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:PIGMENTS
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INGESTION:CAN CAUSE
GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING & DIARRHEA. SKIN:CAN
CAUSE DEFATTING & DRYING OF SKIN; WHICH MAY RESULT IN SKIN
IRRITATION & DERMATITIS. EYE:CAN CAUSE SEVERE IR RITATION, REDNESS,
TEARING OR BLURRED VISION. INHALATION:CAN CAUSE NASAL AND
RESPIRATORY IRRITATION, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:DIZZINESS, FATIGUE, NAUSEA, HEADACHE,
NERVOUS IRRITABILITY, UNCONSCIOUSNESS & ASPHYXIATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:EYES:REMOVE CONT LENS IF PRESENT; FLUSH W/PLENTY OF WATER FOR
OF WATER. IF IRRIT PERSISTS, GET MED ATTN. INGEST:DO NOT INDUCE
VOMIT. CALL PHYS IMMED! KEEP PATIENT WARM & QUIET. INHAL:REMOVE TO
FRESH AIR. MAINTAIN RESPIRATION AS NECESSARY & CALL PHYS! NOTE TO
PHYS:IF SWALLOWED:ASPIR OF MATL INTO LUNGS DUE TO VOMIT CAN
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:0.9%
Upper Limits:6.0%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM & WATER
FOG.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER IS
NOT NORMALLY EFTIVE EXTING AGENT. WHEN BURNING THIS PROD GIVES OFF
TOX BYPRODS OF CARBON MONOXIDE. (SUPDAT)
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:PROVIDE ADEQUATE VENT. REMOVE IGNIT SOURCES
FROM SPILL AREA. UTILIZE SAND, RAGS, PAPER, VERMICULITE, FLOOR
ABSORBENT, MATERIAL & PLACE IN LEAK-PROOF DRUMS FOR DISPOSAL. USE
PROTECTIVE EQUIPMENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:DO NOT USE OR STORE NEAR HEAT, SPARKS,
OPEN FLAME/OTHER SOURCES OF IGNITION. CLOSE CNTNR AFTER EACH USE.
STORE ONLY IN ORIGINAL CONTAINER.
Other Precautions:KEEP OUT OF SURFACE WATERS AND ANY WATER COURSES OR
SEWERS ENTERING OR LEADING TO SURFACE WATERS. KEEP OUT OF REACH OF
CHILDREN.
GASES SHOULD BE AVOIDED. FIRST AID PROC:CAUSE CHEMICAL PNEUMONITIS
WHICH CAN BE FATAL. VENT:DURING APPLICATION.
* Physical/Chemical Properties *
Vapor Density:4.8
Spec Gravity:SUPDAT
Solubility in Water:NIL
Appearance and Odor:AMBER LIQUID-MILD HYDROCARBON ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:INCOMPLETE COMBUSTION PRODUCES CARBON
MONOXIDE, CARBON DIOXIDE & UNIDENTIFIED ORGANIC COMPOUNDS.
* Disposal Considerations *
Waste Disposal Methods:RCRA HAZ WASTE CLASSIFICATION:IGNITABLE. NUMBER
INCINERATION IS PREFERRED.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WITH SATIFACTORY VENTILATION, RESPIRATORY
PROTECTION NOT USUALLY REQUIRED.
Ventilation:GENERAL ROOM VENTILATION IS USUALLY SATISFACTORY, USE LOCAL
EXHAUST VENTILATION WHEN NECESSARY.
Other Protective Equipment:WEAR DISPOSABLE GARMENTS IF DIRECT SKIN
CONTACT IS ANTICIPATED.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
* Product Identification *
Product ID:LIDOCAINE HYDROCHLORIDE INJECTION
Preparer's Name:GREGORY KOLAR
* Composition/Information on Ingredients *
Ingred Name:LIDOCAINE HYDROCHLORIDE
Other REC Limits:NONE RECOMMENDED
Ingred Name:METHYLPARABEN
Other REC Limits:NONE RECOMMENDED
Ingred Name:WATER FOR INJECTION (NOTE: PH ADJUSTED WITH HYDRCHLORIC
ACID AND/OR SODIUM HYDROXIDE.)
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE,SKIN,RESPIRATORY
IRRITATION,UNUSUALLY SLOW HEARTBEAT,DIFFICULTY BREATHING,SWELLING
MAY OCCUR.PRODUCT INTENDED FOR THERAPUTIC USE ONLY WHEN PRESCRIBED
BY A PHYSICIAN.POTENTIAL ADVERSE REACTIONS FRO M PRESCRIBED DOSES
AND OVERDOSES ARE DESCRIBED IN PACKAGE INSERT.OCCUPATIONAL EXPOSURE
HAS NOT BEEN FULLY INVESTIGATED.
Effects of Overexposure:EYE,SKIN,RESPIRATORY IRRITATION,UNUSUALLY SLOW
HEARTBEAT,DIFFICULTY BREATHING,SWELLING MAY OCCUR.PRODUCT INTENDED
FOR THERAPUTIC USE ONLY WHEN PRESCRIBED BY A PHYSICIAN.POTENTIAL
ADVERSE REACTIONS FRO M PRESCRIBED DOSES AND OVERDOSES ARE
DESCRIBED IN PACKAGE INSERT.OCCUPATIONAL EXPOSURE HAS NOT BEEN
FULLY INVESTIGATED.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. GET MEDICAL
ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. FLUSH AREA WITH
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. INHALATION: MOVE TO
FRESH AIR. IF NOT BREATHING GIVE CPR. GET MEDICAL ATTENTION.
INGESTION: FLUSH MOUTH OUT WITH WATER IMMEDIATELY. GET MEDICAL
ATTENTION. GENERAL: FOR ADDITIONAL INFORMATION SEE THE PRODUCT
INSERT.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE OR FOAM
AS APPROPRIATE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:WHEN HEATED TO DECOMPOSITION IT EMITS
TOXIC FUMES OF NITROGEN OXIDES (NOX).
* Accidental Release Measures *
Spill Release Procedures:CLEAN-UP; WEAR RECOMMENDED PERSONAL PROTECTIVE
EQUIPMENT. USE ABSORBENT TOWELS OR BOOMS TO CLEAN-UP SPILL. WIPE
SURFACES CLEAN AND WASH WITH SOAP AND WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AS A GENERAL RULE, WHEN HANDLING
PHARMACEUTICAL PRODUCTS AVOID ALL CONTACT AND INHALATION OF DUST,
FUME, MISTS, OR VAPORS ASSOCIATED WITH THE PRODUCT.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:N1
pH:5 - 7
Solubility in Water:SOLUBLE(WITH HCL)
Appearance and Odor:CLEAR, COLORLESS SOLUTION. ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:PROTECT FROM FREEZING.
Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION IT EMITS
TOXIC FUMES OF NITROGEN OXIDES (NOX).
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:CHEMICAL FUME HOOD.
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER, EYE
BATH.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. DISCARD CONTAMINATED SHOES. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
HLTH HZRD CONT'D: LITHIUM ION CAN CAUSE KIDNEY DAMAGE, DERMATOLOGICAL
EFFECTS, CNS EFFECTS, NEUROMUSCULAR EFFECTS MAY OCCUR. CYANOSIS &
T-WAVE INVERSION HAVE OCCURED IN THE BREAST-FED INFANTS OF WOMEN
RECEIVING LITHIUM CARBONATE THERAPY.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:LITHIUM HYDROXIDE, MONOHYDRATE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY BE FATAL IF INHALED. EXTREMELY
DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES & UPPER RESPIRATORY
TRACT, EYES & SKIN. INHALATION: FATAL, RESULTING IN EDEMA OF THE
LARYNX, BRONCHI, CHEMICAL PNEUMONI TIS & PULMONARY EDEMA. MAY CAUSE
CONGENITAL MALFORMATION IN THE FETUS. CNS, CARDIOVASCULAR SYSTEM &
KIDNEYS. (SEE SUPP)
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SPASM, INFLAMMATION, BURNING SENSATION,
COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE,
NAUSEA, VOMITING, DIZZINESS, PROSTATION, DEHYDRATION, WEIGHT LOSS,
THYROID DISTURBANCES, SLURRED SPEECH, BLURRED VISION, SENSORY
LOSS, ATAXIA, CONVULSIONS, DIARRHEA, TREMOR, CLONUS, HYPERACTIVE
REFLEXES.
* First Aid Measures *
INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED.
INGESTION: WASH OUT MOUTH W/WATER IF CONSCIOUS. OBTAIN MEDICAL
ATTENTION IN ALL CAS ES.
* Fire Fighting Measures *
Extinguishing Media:CO2, DRY CHEMICAL POWDER/APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE AREA. WEAR SCBA, RUBBER BOOTS & HEAVY
VENTILATE AREA & WASH SITE AFTER MATERIAL PICKUP IS COMPLETE.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL DRY PLACE. KEEP
TIGHTLY CLOSED.
Other Precautions:AVOID PROLONGED/REPEATED EXPOSURE. DON'T GET IN EYES,
SKIN/CLOTHING. DON'T BREATH DUST.
* Physical/Chemical Properties *
Appearance and Odor:SOLID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS.
Hazardous Decomposition Products:COMBUSTION: CO2, LITHIUM OXIDES.
* Disposal Considerations *
Waste Disposal Methods:CAUTIOUSLY ADD A LARGE AMOUNT OF WATER. ADJUST
THE PH TO NEUTRAL, SEPARATE INSOLUBLE SOLIDS/LIQUIDS & PACKAGE THEM
FOR HAZARDOUS WASTE DISPOSAL, IAW/FEDERAL, STATE & LOCAL
REGULATIONS. FLUSH THE AQUEO US SOLUTION DOWN THE DRAIN W/PLENTY OF
WATER.(SUPP
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPVD RESP.OR GAS MASK WHEN TLV IS
EXCEEDED
Ventilation:MECH.(GENERAL)VENTIL;IF INADEQUATE,USE SUPPL.LOCAL EXHAUST.
Other Protective Equipment:EYE WASH;SAFETY SHOWER
Supplemental Safety and Health
PART D OF 5 PART KIT.KEY1:F2.
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III)
* Hazards Identification *
Effects of Overexposure:EYE:IRR;SKIN:IRR,DERMAT;SYSTEMIC
EFFECT:RESP.TRACT IRR,MAUSEA,VOMIT,INEBRIATION,BLINDNESS,CNS DEPRES
* First Aid Measures *
First Aid:INHAL:RMV TO FRESH AIR. IF NOT BRTHNG GIVE CPR; IF BRTHNG
DIFF GIVE OXYGEN. EYE:IMMED FLUSH W/PLENTY OF WATER. SKIN:WASH
W/SOAP&WATER. RMV CONTAM CLTHG&SHOES. INGEST:INDUCE VOMIT. RPT
UNTIL VOMIT IS C LEAR. NOTHG BY MOUTH IF UNCONSC. GET MEDICAL ATTN.
* Fire Fighting Measures *
Extinguishing Media:CO*2, FOAM, DRY CHEM.
Fire Fighting Procedures:USE SCBA-USE WTR TO KEEP FIRE EXPSD CONT.COOL.
Unusual Fire/Explosion Hazard:KEEP WORK AREAS FREE OF HOT METAL SURF.&
OTHER IGN.SOURCES-AVOID SPREADING BURNING LIQ.W.COOLNG WTR.
* Accidental Release Measures *
Spill Release Procedures:REMOVE IGNITION SOURCES,VENTILATE AREA
WELL.ABSORB WITH VERMICULITE OR OTHER MATERIALS, SUCH AS
SAWDUST,RAGS,PAPER & PLACE IN CLOSED CONTAINER. USE NON SPARKING
TOOLS. WEAR PROPER PROTECTIVE EQUIPMENT DURING CLEAN UP.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL,DRY WELL VENTED LOW FIRE
RISK AREA. PROTECT FROM HEAT,SHOCK,FRICTION. KEEP CONTAINERS
CLOSED.
Other Precautions:AVOID INH.OF VAPORS-AVOID PERSONAL CONTACT W.THE
PRODUCT-SHOULD CONTACT BE MADE,REMOVE SATURATED CLOTHING & FLUSH
AFFECTED AREAS W.WATER.
* Physical/Chemical Properties *
HCC:F2
Vapor Density:>1
Spec Gravity:<1
Evaporation Rate & Reference:<1(ETHER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIQUID,LITTLE IF ANY COLOR,CHARACTERIST.ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED
Stability Condition to Avoid:NONE SPECIFIED
Hazardous Decomposition Products:NONE NOTED,BUT EXPECT CO, CO*2, H*2O.
* Disposal Considerations *
Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE &
DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF ENGINEERING CONTROLS ARE INADEQUATE TO
CONTROL VAPOR CONCENTRATIONS TO AN ACCEPTABLE LEVEL, A
NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR SHOULD BE WORN. A PROGRAM
Ventilation:LOCAL EXHAUST
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND
IMPERVIOUS CLOTHING
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
* Product Identification *
Product ID:ETHYLENE GLYCOL,INHIBITED
* Composition/Information on Ingredients *
Ingred Name:ETHYLENE GLYCOL (SARA III) *
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:WATER
Fraction by Wt: 4.0%
Ingred Name:SODIUM NITRATE (RUST INHIBITOR)
Fraction by Wt: <0.2%
Ingred Name:SODIUM TETRABORATE, DECAHYDRATE *
Fraction by Wt: <0.5%
Ingred Name:SODIUM METASILICATE (RUST INHIBITOR)
Fraction by Wt: <0.2%
Ingred Name:SODIUM ORTHOPHOSPHATE (RUST INHIBITOR)
Fraction by Wt: <0.3%
Ingred Name:SODIUM MOLYBDATE (RUST INHIBITOR)
Fraction by Wt: <0.3%
Ingred Name:SODIUM TOLYLTRIAZOLE (RUST INHIBITOR)
Fraction by Wt: <0.2%
Ingred Name:SODIUM MERCAPTOBENZOTHIAZOLE (RUST INHIBITOR)
Fraction by Wt: <0.3%
Ingred Name:NON-IONIC SURFACTANT
Ingred Name:STABILIZER
Fraction by Wt: <0.1%
Ingred Name:DYES
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE-INHALE:VAPOR/MIST MAY CAUSE
RESPIRATORY IRRITATION & MAY RESULT IN UNCONSCIOUSNESS.ORAL:WILL
CAUSE ACUTE POISONING RESULTING IN SEVERE ABDOMINAL
DISTURBANCES,CNS DEPRESSION & POSSIBLE RESPIRATOR Y AND/OR RENAL
FAILURE.EYE/SKIN:WILL RESULT IN TEMPORARY IRRITATION.CHRONIC-NONE
KNOWN.
Effects of Overexposure:VAPOR/MIST MAY CAUSE RESPIRATORY IRRITATION &
MAY RESULT IN UNCONSCIOUSNESS. ORALLY WILL CAUSE ACUTE POISONING
RESULTING IN SEVERE ABDOMINAL DISTURBANCES, CNS DEPRESSION &
POSSIBLE RESPIRATORY AND/OR RENAL FAILURE. EYE/SKIN CONTACT WILL
RESULT IN TEMPORARY IRRITATION.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING LIVER,
KIDNEY OR RESPIRATORY DISORDERS MAY BE MORE SUSCEPTIBLE TO THE
EFFECTS OF THE SUBSTANCE.
* First Aid Measures *
MINUTES,HOLDING EYELIDS OPEN.SKIN:WASH WITH SOAP &
WATER.INHALED:REMOVE TO FRESH AIR.PROVIDE CPR/OXYGEN IF
NEEDED.ORAL:IF CONSCIOUS,INDUCE V OMITING.CALL A PHYSICIAN/POISON
CONTROLCENTER IMMEDIATELY.NEVER GIVE FLUIDS OR INDUCE VOMITING IF
PATIENT IS UNCONSCIOUS OR HAVING CONVULSIONS!
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:WATER SPRAY, CO2, FOAM/DRY CHEMICAL. WATER SPRAY
MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS
AWAY.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL ALONG GROUND TO
IGNITION SOURCE AND FLASH BACK.
* Accidental Release Measures *
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT.ELIMINATE SOURCES OF
IGNITION.VENTILATE THE AREA.STOP LEAK IF POSSIBLE.CONTAIN THE
SPILL.PICK UP LARGE SPILL WITH NON-SPARKING TOOLS;SMALL
SPILLS/RESIDUE WITH ABSORBENT MATER IAL.PLACE IN NON-LEAK
CONTAINERS.CONTAIN RUN-OFF.
*Handling and Storage *
Handling and Storage Precautions:STORAGE-STORE IN COOL,WELL-VENTILATED
AREA AWAY FROM INCOMPATIBLES.AVOID CONTACT WITH FOOD AND FOODSTUFF.
Other Precautions:EMPTY CONTAINERS MAY BE UNSAFE DUE TO PRESENCE OF
RESIDUES. WASH THOROUGHLY AFTER HANDLING. AVOID BREATHING VAPORS OR
MISTS. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING.
* Physical/Chemical Properties *
HCC:V5
Solubility in Water:COMPLETE
Appearance and Odor:SLIGHTLY HAZY, FLUORESCENT GREEN LIQUID, SLIGHT
GLYCOL ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:EXCESSIVE HEAT, FLAME, IGNITION SOURCES
Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NORMALLY REQUIRED.
Ventilation:LOCAL AIR CIRCULATION.
Other Protective Equipment:APRON TO KEEP PRODUCT OFF CLOTHES.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
THIS MSDS WAS PRESENTED BY CAGE 0C3Y2 FOR CONTRACT (NUMBER UNKNOWN) FEB
NUMBER BJPHD; HOWEVER, THE MSDS IS DATED THE SAME AS THE CURREN T
RECORD. DLA-HMIS IS RESEARCHING AS OFTHIS INPUT DATE AS TO WHY THE
EARLIER INPUT RECORD HAS A DIFFERENT FORMULATION.
* Product Identification *
CAGE:0C3Y2
CAGE:0C3Y2
* Composition/Information on Ingredients *
Ingred Name:MORPHOLINE
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: CONTACT MAY CAUSE SLIGHT SKIN
IRRITATION. CHRONIC: NONE SPECIFIED BY MANUFACTURER.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:SKIN-IRRITATION, REDNESS OF SKIN.
Medical Cond Aggravated by Exposure:IRRITATED SKIN.
* First Aid Measures *
First Aid:EYES-FLUSH WITH WATER. SEE PHYSICIAN IF IRRITATION PERSISTS.
SKIN-FLUSH WITH WATER. INGESTED-CONTACT PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:WATER FOG, CARBON DIOXIDE, FOAM.
Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:FLUSH WITH WATER INTO SEWER SYSTEM.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. KEEP
FROM FREEZING.
Other Precautions:USE PRODUCT IAW DIRECTIONS.
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:COMPLETE
Appearance and Odor:TAN COLORED-NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:NONE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:RENDER CONTAINER USELESS. DISPOSE WITH IAW
LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST:PREFERABLE. MECHANICL (GENERAL):ACCEPTABLE.
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE
SHOWER .
Work Hygienic Practices:AVOID BREATHING VAPOR OR SPRAY MIST. AVOID
CONTACT WITH SKIN OR EYES.
Supplemental Safety and Health
EVAP RATE:SLOWER THAN ETHER (BUTYL ACETATE =1).
* Product Identification *
CAGE:ACEHA
CAGE:ACEHA
* Composition/Information on Ingredients *
Ingred Name:TITANIUM DIOXIDE
Ingred Name:NEPHELINE SYENITE
OSHA PEL:N/K
ACGIH TLV:5 MG/CUM (MFR)
Ingred Name:SILICA, AMORPHOUS, DIATOMACEOUS EARTH; (DIATOMACEOUS
SILICA)
Fraction by Wt: 2.3%
Ingred Name:SILICA GEL; (AMORPHOUS SILICA)
Fraction by Wt: 1.2%
OSHA PEL:6 MG/M3
Ingred Name:1,2-PROPANEDIOL; (PROPYLENE GLYCOL)
Fraction by Wt: 2.3%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:IRON (III) OXIDE; (IRON OXIDE)
Fraction by Wt: 6.0%
ACGIH TLV:5 MG(FE)/M3 FUME, B2
Ingred Name:HYDRATED IRON OXIDE
Fraction by Wt: 3.9%
OSHA PEL:N/K
ACGIH TLV:N/K
Fraction by Wt: <0.1%
Ingred Name:ALUMINUM HYDROXIDE
Fraction by Wt: 0.9%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:PALYGORSKITE; (MAGNESIUM ALUMINUM SILICATE)
Fraction by Wt: 0.3%
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT REFINED
(SEVERE) HEAVY PARAFFINIC; (ALIPHATIC PETROLEUM DISTILLATE)
Fraction by Wt: 0.5%
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:IN A CONFINED AREA VAPORS IN
HIGH CONCENTRATION ARE ANESTHETIC. IRRITANT TO UPPER RESPIRATORY
SYSTEM. SIGNS AND SYMPTOMS OF EXPOSURE:LIGHTHEADEDNESS AND
STAGGERED GAIT. CHRONIC PROBLEMS WITH RES PIRATORY SYSTEM MAY BE
AGGRAVATED BY EXPOSURE TO VAPORS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:CHRONIC PROBLEMS WITH RESPIRATORY
SYSTEM MAY BE AGGRAVATED TO EXPOSURE TO VAPORS.
* First Aid Measures *
First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE FROM
EXPOSURE-RESTORE BREATHING-KEEP WARM AND QUIET. SKIN:WASH WITH SOAP
MEDICAL AID. LAUND ER CONTAMINATED CLOTHING BEFORE REUSE.
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:NON-COMBUSTIBLE-FOR DRY SOLIDS USE WATER, FOAM
CO*2, DRY CHEMICALS.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . WATER MAY BE USED TO COOL CLOSED CONTAINERS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPOSED TO EXTREME HEAT
MAY RUPTURE DUE TO PRESSURE BUILD-UP. CONTENTS MAY SPATTER IF
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:DOL STORAGE CATEGORY 3B.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.
* Physical/Chemical Properties *
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SUPP DATA
Solubility in Water:INSOLUBLE
Appearance and Odor:COLORED PIGMENTED LIQUID WITH SLIGHT AMMONIA ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NO HAZARDOUS REACTIONS ARE EXPECTED UNDER NORMAL USE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE IN APPROVED FACILITY. DO NOT
INCINERATE CLOSED CONTAINERS. DISPOSE OF IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS REGARDING POLLUTION.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SHOULD BE NEEDED.
W/VENTI RATES.
Other Protective Equipment:EYEBATH, WASHING FACILITIES, SAFETY
SHOWER.PROTECTIVE CLOTHING APPROPRIATE FOR RISK OF EXPOSURE.
Work Hygienic Practices:WASH CONTAM CLOTH BEF REUSE;DESTROY/CLEAN WELL
CONTAM SHOES.WASH THOROUGHLY AFT HNDLG.
Supplemental Safety and Health
ATTN.NEVER GIVE ANYTHING BY MOUTH IF UNCONSC. PART B SEE PNIND:A.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POTASSIUM CARBONATE
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:ETHANOL, 2,2',2"-NITRILOTRI-; (TRIETHANOLAMINE)
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:5 MG/M3
Ingred Name:DIETHYLHYDROXYLAMINE
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
Ingred
Name:4-(N-ETHYL-N-2-METHANESULFONYLAMINOETHYL)-2-METHYLPHENYLENEDIA
MINE
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:WATER
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL:EXPECTED TO BE LOW HAZ FOR
RECOMMENDED HANDLING.EYES:NO SPECIFIC HAZARD KNOWN.MAY CAUSE
TRANSIENT IRRITATION.SKIN:MAY CAUSE ALLERGIC SKIN
REACTION.INGEST:HARMFUL IF SWALLOWED.MAY CAUSE IRRITATIO N OF
GASTROINTESTINAL TRACT.
Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY
CLASSIFICATION:IARC/ACGIH/NTP/OSHA:NONE.
Effects of Overexposure:TRANSIENT EYE IRRITATION, ALLERGIC SKIN
REACTION, GASTROINTESTINAL TRACT.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:MOVE TO FRESH AIR.TREAT SYMPTOMAT.SYMPT PERSIST GET MED
GET MED ATTN.NOTE TO DR:STRONG ALKALIS BIND TISSUE PROTEIN.FOLLOW
INITI AL FLUSH W/H2O CONT IRRIGA W/SALINE.CONT TIL PH OF TEARS
NEUTRAL.SKIN:IMMED FLUSH W/LOTS OF WATER.WASH
W/NONALKALINE(ACID)TYP SKIN CLNR.IRRIT/ALLERGIC RX DEVLP GET MED
ATTN.REMOVE CONTAM CLOTH(SUPPLE)
* Fire Fighting Measures *
Flash Point:NONE,NON-COMBUST
Autoignition Temp:Autoignition Temp Text:NP
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATH APPARATUS &
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:FLUSH TO SEWER W/LG AMTS OF WATER.MAY REQUIRE
INERT MATL.THEN PLACE IN CNTNR FOR CHEMICAL WASTE.CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDU AL CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AVOID PROL/REP MIST/VAP BREATH.AVOID
EYE/SKIN/CLOTH CONTACT.ROUTINE USE OF NONALKALINE(ACID)TYP SKIN
Other Precautions:USE W/ADEQUATE VENTI.KEEP CNTNR CLSD.
* Physical/Chemical Properties *
HCC:B3
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Density:0.6
pH:SUPPLE
Viscosity:NP
Evaporation Rate & Reference:NP
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID, LIGHT YELLOW COLOR, SLIGHT AMINE ODOR
Corrosion Rate:NP
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE W/COMMON MATERIALS & CONTAMINANTS W/WHICH MATERIAL MAY REASONABLY
COME INTO CONTACT.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE (NON-COMBUSTIBLE)
* Disposal Considerations *
Waste Disposal Methods:DISCHARGE/TREATMENT/DISPOSAL MAY BE SUBJ TO
NATIONAL/STATE/LOCAL LAWS.FLUSH TO SEWER W/LG AMTS OF WATER.SINCE
EMPTY CNTNRS RETAINPROD RESIDUE FOLLOW LABEL WARNINGS EVEN AFT
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SHOULD BE REQUIRED. USE NIOSH/MSHA APPROVED
ORGANIC VAPOR RESPIRATOR FOR WHEN VENTILATION PRACTICES ARE NOT
ADEQUATE FOR MINIMIZING EXPOSURE.
Ventilation:LOC EXHST FOR HOT PROCESSING-VENT TO ELEVATED STACK.
MECHANICAL FOR ORDINARY HANDLING. VENTILATE ENCLOSED SPACES.
Other Protective Equipment:EYE WASH FACILITY.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:CHROMIC ACID, LEAD (2+) SALT (1:1);(LEAD CHROMATE YELLOW)
Fraction by Wt: <5%
Ingred Name:BARIUM (AS FOUND IN INGREDIENT 1)
Fraction by Wt: <2%
OSHA PEL:0.5 MG/M3
ACGIH TLV:0.5 MG/M3
Ingred Name:CADMIUM (AS FOUND IN INGREDIENT 2)
Fraction by Wt: <2%
Ingred Name:LEAD (AS FOUND IN INGREDIENT 3)
Fraction by Wt: <0.2%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:CHROMIUM (AS FOUND IN INGREDIENT 3)
Fraction by Wt: <0.1%
OSHA PEL:0.5 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:BARIUM METABORATE; (BARIUM METABORATE MONOHYDRATE)
Fraction by Wt: <3%
OSHA PEL:0.5 MG/M3 (BA)
ACGIH TLV:0.5 MG/M3 (BA)
Ingred Name:ORGANO-METALLIC STABILIZER
Fraction by Wt: <2%
OSHA PEL:0.2 MG/M3 (MFR)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:LIQUID MAY IRRITATE EYE TISSUE
IF CONTACTED. CHRONIC:NONE CURENTLY KNOWN.
Explanation of Carcinogenicity:CADMIUM:GROUP 2 (IARC), GROUP 2 (NTP).
CHROMIUM:GROUP 1 (IARC), GROUP 1 (NTP).
Effects of Overexposure:TREAT SYMPTOMATICALLY.
Medical Cond Aggravated by Exposure:NONE KNOWN.
* First Aid Measures *
MINUTES. DO NOT RUB, CALL MD IF IRRITATION PERSISTS. SKIN:WASH WITH
SOAP & WATER. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
DESTROY CONTAMINATED SHOES. INHAL:MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. INGEST:INDUCE VOMITING, CALL MD.
* Fire Fighting Measures *
Extinguishing Media:FOAM OR WATER MIST SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:FIRE CONDITIONS PRODUCE HYDROGEN
CHLORIDE.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN SPILL TO LIMIT AFFECTED AREA, SCRAPE
UP BULK OF MATERIAL, USE ABSORBENT TOWELS TO WIPE UP RESIDUAL.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:AVOID PROLONGED OR REPEATED CONTACT OF
LIQUID WITH SKIN.
Other Precautions:
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:VISCOUS LIQUID. NEGLIGIBLE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, STRONG ALKALIS. SOLUBLE IN KETONES AND ORGANIC SOLVENTS.
Stability Condition to Avoid:EXCESS HEAT DURING CURE PROCESS.
Hazardous Decomposition Products:ACRID SMOKE AND FUMES EMITTED WHEN
HEATED TO DECOMPOSITION.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOSURE ABOVE THE PEL OR TLV, NIOSH APPROVED
RESPIRATOR FOR FUME OR DUST, DEPENDENT UPON THE SOURCE OF AIRBORNE
CONTAMINANT.
Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL) REQUIRED IF DUST OR
FUMES ARE CREATED.
Other Protective Equipment:AS REQUIRED FOR THE WORK DONE ON OR WITH THE
METAL. I.E. FACE SHIELDS & SPECIALLY TINTED GLASSES.
Work Hygienic Practices:EVALUATE THE JOBS DONE ON THIS PRODUCT IN
ACCORDANCE W/OSHA, STATE, FEDERAL, OR LOCAL STANDARDS.
Supplemental Safety and Health
UNDER NORMAL HANDLING CONDITIONS THE SOLID ALLOY PRESENTS NO
SIGNIFICANT HEALTH HAZARDS. PROCESSING OF THE ALLOY BY DUST OR FUME
PRODUCING OPERATIONS (GRINDING, BUFFING, HEATING, WELDING, ETC.)
MAY RE SULT IN THE POTENTIAL FOR EXPOSURE TO AIRBORNE METAL
PARTICULATES OR FUMES.
* Product Identification *
CAGE:COPPE
CAGE:COPPE
* Composition/Information on Ingredients *
Ingred Name:COPPER (DUST & MIST), BRONZE POWDER
Other REC Limits:1 MG(CU)/M3 (DUST)
OSHA PEL:0.1 MG(CU)/M3 (FUME)
ACGIH TLV:0.2 MG/M3 (FUME)
Ingred Name:ZINC OXIDE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: METAL FUME FEVER W/FLU
SYMPTOMS, FEET/HAND KERATINIZATION, UPPER RESPIRATORY TRACT
IRRITATION, METALLIC TASTE, NAUSEA, NOSE/MOUTH/THROAT IRRITATION,
COUGH, HEADACHE, VOMITING, CHILLS, FEVE R, MUSCLE/JOINT/STOMACH
PAIN, THIRST, BRONCHITIS & PNEUMONIA. SKIN: BLUISH
TINT/DISCOLORATION. HAIR: DISCOLORATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: METAL FUME FEVER W/FLU SYMPTOMS,
FEET/HAND KERATINIZATION, UPPER RESPIRATORY TRACT IRRITATION,
METALLIC TASTE, NAUSEA, NOSE/MOUTH/THROAT IRRITATION, COUGH,
HEADACHE, VOMITING, CHILLS, FEVE R, MUSCLE/JOINT/STOMACH PAIN,
THIRST, BRONCHITIS & PNEUMONIA. SKIN: BLUISH TINT/DISCOLORATION.
HAIR: DISCOLORATION.
* First Aid Measures *
First Aid:EYES: FLUSH W/PLENTY OF WATER. SKIN: VACUUM OFF EXCESS DUST.
WASH WELL W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR.
INGESTION: OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:SPECIAL MIXTURES OF DRY CHEMICAL OR SAND.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NON COMBUSTIBLE. MODERATE WHEN MATERIAL
IS IN THE FORM OF DUST & EXPOSED TO HEAT, FLAMES, CHEMICAL REACTION
OR IN CONTACT W/POWERFUL OXIDIZERS.
* Accidental Release Measures *
Spill Release Procedures:DUST: VACUUM OR WET SWEEP. VENTILATE AREA.
LIQUIDS (ACIDS/BASES) CONTAINING SOLUBILIZED METAL, EVACUATE
UNPROTECTED PERSONNEL. ABSORB W/VERMICULITE, DRY SAND, OR SIMILAR
MATERIAL. CLEANUP PERSONNEL SH OULD WEAR RESPIRATORS & PROTECTIVE
CLOTHING.
*Handling and Storage *
Handling and Storage Precautions:AVOID INCOMPATIBLE MATERIALS & KEEP
DUST FROM SOURCES OF IGNITION.
Other Precautions:MOLTEN METAL MAY REACT VIOLENTLY W/WATER.
* Physical/Chemical Properties *
Solubility in Water:INSOLUBLE
Appearance and Odor:SOLID, SILVER OR YELLOW TO RED, ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS, BASES & OXIDIZERS.
Stability Condition to Avoid:HEAT, FLAME, CHEMICAL REACTION & OTHER
SOURCES WHEN MATERIAL IS IN DUST FORM.
Hazardous Decomposition Products:METAL FUME
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IN AREAS WHERE TLVS MAY BE EXCEEDED/IF SPRAY
MIST IS PRESENT, USE NIOSH/MSHA APPROVED RESPIRATOR. IN CONFINED
AREAS, USE NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATORS.
Ventilation:GENERAL DILUTION/LOCAL EXHAUST: TO KEEP LEVEL <
RECOMMENDED/REGULATED PEL LIMIT WHERE EMPLOYEES MAY BE EXPOSED.
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER, EYE
BATH, WASHING FACILITIES.
Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING BEFORE REUSE.
PREVENT PROLONGED CONTACT W/CONTAMINATED CLOTHING.
Supplemental Safety and Health
FIRE HAZARD CONT'D: CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT. HEALTH HAZ CONT'D: EYES: IRRITANT. INGESTION: GI
IRRITANT. OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN &
NERVOUS SYSTEM DAMAGE. DON'T INHALE THE VAPORS.DON'T
CUT/PUNCTURE/WELD ON/NEAR DRUM. EMPTY DRUMS MAY CONTAIN EXPLOSIVE
VAPORS.
* Product Identification *
Preparer's Name:SHERRIE M STEVENSON
* Composition/Information on Ingredients *
Ingred Name:DIPHENYLMETHANEDIISOCYANATE (MDI), METHYLENE BIS
(PHENYLISOCYANATE), 4,4 DIPHENYLMETHANE DIISOCYANATE (MDI)
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:AROMATIC POLYISOCYANATE
Ingred Name:2-BUTANONE (METHYL ETHYL KETONE) (MEK)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: NASAL & RESPIRATORY
IRRITANT & CNS DEPRESSION. ASPHYXIATION MAY RESULT FROM BREATHING
OXYGEN DEFICIENT AIR. ISOCYANATES: MAY CAUSE ALLERGIC SENSITIZATION
& IRRITATION TO MUCOUS MEMBRANE & RESPIRATORY TRACT. ASTHMA-LIKE
ATTACKS.SKIN: IRRITATION, DERMATITIS. SENSITIZATION IN SOME
INDIVIDUALS. (SEE SUPP)
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, DIZZINESS, STAGGERING GAIT,
CONFUSION, UNCONSCIOUSNESS, ASPHYXIATION, TIGHTNESS IN CHEST,
COUGHING, HEADACHE, SHORTNESS OF BREATH, DEFATTING,NAUSEA,
VOMITING, DIARRHEA. OVEREXPOSURE TO SOL VENTS: CONCENTRATION
DIFFICULTIES, DIMINISHED MANUAL DEXTERITY, MEMORY LOSS.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, LUNG & EYE
CONDITIONS.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF
NECESSARY. KEEP WARM & QUIET. SKIN: WASH W/SOAP & WATER. DON'T USE
IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:CO2, DRY CHEMICAL/FOAM
Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. COOL FIRE
EXPOSED CONTAINERS W/WATER. FOG NOZZLES ARE PREFERRED. WEAR
NIOSH/MSHA APPROVED SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:VAPORS MAY ACCUMULATE IN INADEQUATELY
VENTILATED/CONFINED AREAS/FORM EXPLOSIVE MIXTURES W/AIR. MAY TRAVEL
LONG DISTANCES, FLASHBACK/FLAME TO HANDLING SITE.(SUPP
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL IGNITION SOURCES. WEAR PROTECTIVE
EQUIPMENT. USE NON-SPARKING TOOLS.SMALL: DIKE & ABSORB W/INERT
MATERIAL. COLLECT IN OPEN TOP DRUM & TAKE TO ISOLATED AREA
(OUTDOORS). FILL DRUM W/DECONTAMI NATION SOLUTION. NEUTRALIZE AREA
W/SOLUTION.
(2%) & AMMONIA (3-8%).
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED & FROM
IAW/NFPA CODES & GOVERNMENTAL REGULATIONS.
Other Precautions:GROUNDING & BONDING PROCEDURES SHOULD BE FOLLOWED
AVOID FREE FALL OF LIQUID. NO SMOKING WHERE USED/STORED. AVOID
SKIN/EYE CONTACT & BREA THING OF VAPORS. DON'T TAKE INTERNALLY.
* Physical/Chemical Properties *
Vapor Density:>1
Evaporation Rate & Reference:SLOWER THAN N-BU ACETATE
Appearance and Odor:LIQUID W/SOLVENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOLS, AMINES & FOREIGN MATERIALS
Stability Condition to Avoid:MOISTURE, HEAT, SPARKS, FLAME, ELECTRICAL
EQUIP, TEMPS >MAXIMUM STORAGE TEMPS, HOT SURFACES & OTHER IGNITION
SOURCES
Hazardous Decomposition Products:CO, CO2, OXIDES OF NITROGEN, TRACES OF
HYDROGEN CYANIDE, ISOCYANATE MONOMER
* Disposal Considerations *
Waste Disposal Methods:WHEN DISPOSING OF THIS MATERIAL, ENSURE IT IS
PACKAGED, STORED, TRANSPORTED & OTHERWISE MANAGED IAW/LOCAL, STATE
& FEDERAL REGULATIONS. AVOID CONTAMINATING GROUND/SURFACE WATERS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR A PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATORY APPROVED BY NIOSH FOR PROTECTION
AGAINST LISTED INGREDIENTS.
Ventilation:LOCAL EXHAUST PREF. GENERAL EXHAUST ACCEPTABLE IF EXPOSURE
TO LISTED MATERIALS IS MAINTAINED BELOW APPLICABLE (ING 6)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: TO PREVENT PRESS BUILD-UP & POSS AUTOIGNIT OR EXPLO
WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: SURFS REQS SPECIAL
PRECAUTIONS. DURING EMERGENCY CNDTNS OVEREXP TO DECOMP PRODS MAY
CAUSE A HEALTH HAZARD. SYMPS MAY NOT BE IMMEDIATELY APPARENT.
OBTAIN MED ATTN.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC; (MINERAL
SPIRITS) VP: 2
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:HNDLG/STOR PRECS: LIGHTS & HEATERS - TURN OFF STOVES, ELEC
TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. (ING 4)
Ingred Name:ING 3: CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING
PROCEDURES. KEEP CNTNR CLOSED WHEN NOT IN USE. TRANSFER (ING 5)
Ingred Name:ING 4: ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LABELING.
DO NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP
SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESS. EXTREME OVEREXP MAY
RESULT IN UNCON & POSSIBLY DEATH. HEADACHE, DIZZINESS, NAUSEA &
LOSS OF COORDINATION ARE INDICATIONS OF EXCESS EXPOS TO
VAPORS/SPRAY MIST. REDNESS & ITCHING/BURNING SENSATION MAY INDICATE
EYE/EXCESS SKIN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: EXPOS. CHRONIC: PRLNGD OVEREXP TO
LISTED SOLVENT INGREDS MAY CAUSE ADVERSE EFFECTS TO LIVER & URINARY
SYSTEMS. REPORTS HAVE ASSOCIATED RPTD & PRLNGD OVEREXP TO SOLVS
W/PERMANENT BRAIN & NERV OUS SYSTEM DAMAGE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
* First Aid Measures *
First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP &
WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES:
MED ATTN. INGEST: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. DO NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK
MED ATTN.
* Fire Fighting Measures *
Lower Limits:0.8%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA &FULL PROT EQUIP . WATER
SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF. WATER
MAY BE USED TO COOL CLSD CNTNRS (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. APPLICATION TO HOT (SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN
FLAME. DURING USE & UNTIL ALL VAPS ARE GONE: KEEP AREA VENTILATED -
DO NOT SMOKE - EXTING ALL FLAMES, PILOT (ING 3)
Other Precautions:INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING &
INHALING THE CONTENTS CAN BE HARMFUL OR FATAL. USE ONLY WITH
ADEQUATE VENTILATION. AVOID BREATHING VAPOR AND SPRAY MIST. AVOID
CONTACT WITH SKIN AND EYES. WASH HANDS AFTER USING.
* Physical/Chemical Properties *
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:WASTE FROM THESE PRODS MAY BE HAZ AS DEFINED
APPLIC EPA HAZ WASTE NUMBERS. INCIN IN APPRVD FACILITY. DO NOT
INCIN CLSD CNTNR. DISPOSE OF I/A/W FED, STATE & LOC REGS REGARDING
POLLUTION.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SCBA IF INVOLVED IN FIRE, OTHERWISE GAS MASK.
Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV
Other Protective Equipment:EYE WASH STATION. APRONS. SPECIAL IMPERVIOUS
CLOTHING.
Supplemental Safety and Health
BY DGSC-STF.
* Product Identification *
* Composition/Information on Ingredients *
* Hazards Identification *
Effects of Overexposure:HAZ DEGREE DEPENDS ON TYPE/QUANT OF RADIATION.
LATENT EFFECTS:SOMATIC/GENETIC DAMAGE.
* First Aid Measures *
First Aid:USE FIRST AID. CALL MEDICAL EMERGENCY CARE. REMOVE/ISOLATE
COMTAMINATED CLOTHING.SHOWER VICTIM(S) W. SOAP & H*2O. DETAIN
PERSONNEL/EQUIPMENT EXPOSED. ADVISE MEDICAL PERSONNEL THAT
VICTIM(S) MAY BE CON TAMINATED.
* Fire Fighting Measures *
Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD
BRTHG APP.
Unusual Fire/Explosion Hazard:SOME OF MATL MAY BURN. CONT MAY EXPLODE
IN HEAT OF FIRE.
* Accidental Release Measures *
*Handling and Storage *
Handling and Storage Precautions:SHIELD ACCORDING TO EMITTED RADIATION.
PROTECT FROM FILM/FILM PLATES. KEEP CONTAINERS CLOSED. STORE IN
AREA FOR RADIOACTIVE MATERIALS.
* Physical/Chemical Properties *
HCC:A3
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ISOLATE,SEGREGATE FROM MOST OTHER TYPE MATERIAL
Hazardous Decomposition Products:DEPENDS ON CHEMICAL COMPOSITION;
FISSION PRODUCTS
* Disposal Considerations *
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-IN ACCORDANCE WITH
DOD REGULATIONS AND FEDERAL,STATE & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:EXPOSURE TO ORGANIC CHEMICALS MAY NOT REQ
RESPIRATOR PROTECTION IN VENTED AREAS. RESTRICT VENT-USE NIOSH
CHEMICAL CARTRIDGE RESPIRATOR. SPRAYING-MECHANICAL PREFILTER.
Ventilation:GENERAL DILUTION/LOCAL EXHAUST TO KEEP BELOW TLV. REMOVE
DECOMP PRODUCT FROM WELD/CUT/BRAZING OBJECTS COATED W/PRODUCT.
Other Protective Equipment:EYEWASH FACILITY, SAFETY SHOWER.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:W. A. ELLISON
CAGE:PRATT
CAGE:PRATT
* Composition/Information on Ingredients *
(LFL 1.0 / UFL 7.0)
Other REC Limits:NONE SPECIFIED
Ingred Name:SOLVENT NAPTHA, LIGHT AROMATIC (SOLVENT)
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
(LFL 1.7 / UFL 7.6)
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
Ingred Name:SILICA, CRYSTALLINE (PIGMENT)
Fraction by Wt: <1%
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE TABLE Z3
Ingred Name:METHYL ISOAMYL KETONE (SOLVENT)
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
(LFL 1.0 / UFL 7.0)
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
Ingred Name:LIGROIN (PETROLEUM HYDROCARBON MIXTURE) (SOLVENT)
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INGEST: GASTROINTESTINAL IRRITATION,
NAUSEA, VOMITING. ASPIR OF MATL INTO LUNG-CHEM PNEUMONITIS-FATAL.
INHAL: NOSE/ THROAT IRRIT. CNS DEPRESSION W/HEADACHES, DIZZINESS,
NAUSEA, CONFUSION. EYE: SEVERE IRRIT, CORNEAL DAMAGE. SKIN: LIQ
MATL MAY BE ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. MAY CAUSE
SEVERE SKIN IRRITATION.
Explanation of Carcinogenicity:IARC CONSIDERS CRYSTALLINE SILICA TO
HAVE LIMITED EVIDENCE OF CARCINOGENICITY IN HUMANS.
Effects of Overexposure:SILICOSIS. LIVER, KIDNEYS AND BLOOD.
PREEXISTING RESPIRATORY CONDITIONS MAY BE AGGRAVATED BY EXPOSURE TO
CRYSTALLINE SILICA. PERIPHERAL NEUROPATHY. PERMANENT BRAIN AND
NERVOUS SYSTEM DAMAGE. INTENTION AL MISUSE BY DELIBERATELY
CONCENTRATINGAND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL.
Medical Cond Aggravated by Exposure:ANY TREATMENT THAT MIGHT BE
REQUIRED FOR OVEREXPOSURE SHOULD BE DIRECTED AT THE CONTROL OF
SYMPTOMS AND THE CLINICAL CONDITIONS.
* First Aid Measures *
First Aid:INGEST: DO NOT INDUCE VOMITING. CALL POISON CONTROL
CENTER/HOSPITAL EMERGENCY ROOM/DR IMMED. INHAL: MOVE TO FRESH AIR
IMMED. IF BREATHING STOPPED-GIVE ARTIF RESP. KEEP WARM/QUIET. GET
MED ATTN IMMED. EYE: FLUSH W/LG AMOUNTS OF WATER, LIFTING LIDS FOR
AFFECTED AREA WITH SOAP AND WATER. OBTAIN MEDICAL ATTENTION IF
IRRITATION PERSISTS.
* Fire Fighting Measures *
Lower Limits:1%
Extinguishing Media:NFPA CLASS B FIRE EXTING (CO2-ALL PURP DRY CHEM-
ALCOHOL FOAM) TO EXTING LIQ FIRES. POLYMER FOAM PREFERRED FOR LG
FIRES.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE-USE TO COOL EXPOSED
CNTNRS TO PREVENT PRESSURE BLDUP/POSS AUTO-IGNIT/EXPLOSION
W/EXTREME HEAT. FOG NOZZLES PREFERRED W/WATER USE.
Unusual Fire/Explosion Hazard:DURING EMERGENCY CONDITIONS OVEREXPOSURE
TO DECOMP PRODUCTS-HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY
APPARENT. OBTAIN MEDICAL ATTN. WARNING: FLAMMABLE.
* Accidental Release Measures *
Spill Release Procedures:WEAR RESP-EYE-HAND-BODY PROTECT APPROP FOR
SPILL SIZE. EVAC AREA-ELIM IGNIT SRCS. DIKE/CONTAIN W/INERT MATL.
TRANSFER LIQ TO COVERED METAL CNTNRS-DISPOSE/RMV W/INERT ABSORB.
NON-SPARK TOOLS. PREVENT C ONTAM OF SEWERS-STREAMS-GROUNDWATER
W/USED ABSORB.
*Handling and Storage *
SHOULD BE GROUNDED/BONDED TO RECEIVING CONTAINER.
Other Precautions:DO NOT INGEST. CLOSE CONTAINER AFTER EACH USE. DO NOT
BREATHE SANDING DUST. EMPTY CNTNRS MUST NOT BE WASHED/RE-USED FOR
ANY PURPOSE. DO NOT WELD, BRAZE OR CUT ON EMPTY CONTAINER. NEVER
USE PRESSURE TO EMPTY. DRUM IS NOT A PRESSURE VESSEL.
* Physical/Chemical Properties *
HCC:F2
Vapor Density:> THAN AIR
Spec Gravity:1.0
pH:4-7STD
Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER
Solubility in Water:SLIGHT
Appearance and Odor:LIQUID, SOLVENT ODOR
Corrosion Rate:NA
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS. OXIDIZING MATERIALS.
OF IGNITION.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE AND CARBON
DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE W/FEDERAL-STATE-LOCAL
LAWS/ REGS. INCINERATE ONLY IN EPA FACILITY. DO NOT INCINERATE
CLOSED CNTNRS. OBSERVE PRECAUTIONS FOR DISPOSAL OF FLAMMABLE
MATERIALS. DISPOSE CONTAMINATED ABSORBANT IN HAZARDOUS WASTE
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NO SPECIAL EQUIPMENT REQUIRED.
Ventilation:MECHANICAL(GENERAL): GOOD VENTILATION.
Other Protective Equipment:PROTECTIVE APRON. EYE WASH STATION & SAFETY
SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
* Product Identification *
Product ID:COPYRAPID LIQUID OFFSET DEVELOPER
* Composition/Information on Ingredients *
Ingred Name:SODIUM HYDROXIDE (SARA III)
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3
Ingred Name:HYDROQUINONE (SARA III)
Fraction by Wt: 1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:1-PHENYL-3-PYRAZOLIDONE
Fraction by Wt: 0.2%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE IRRITATION OF SKIN.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:MAY BURN EYES.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INGESTION: OBTAIN IMMEDIATE MEDICAL ATTENTION. CONTACT WITH
SKIN: FLUSH WITH WATER. CONTACT WITH EYES: FLUSH WITH WATER, OBTAIN
MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:NONE
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:FLUSH ANY SPILLAGE WITH WATER.
*Handling and Storage *
Handling and Storage Precautions:NONE
Other Precautions:FOLLOW ALL INSTRUCTIONS ON THE LABEL.
* Physical/Chemical Properties *
HCC:B1
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:NONE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:DILUTE WITH WATER. DISPOSAL MUST BE MADE IN
ACCORDANCE WITH APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
Control Measures
*
*
Preparer Co. when other than Responsible Party Co.
*
Assigned Ind: Y
*
Contractor Summary
*
*
Ingredients
*
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ALLERGIC REACTIONS HAVE BEEN REPORTED, WHICH MAY INCLUDE
EYE IRRITATION.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: RASH, NASAL CONGESTION, COUGH, DRY THROAT,
GASTROINTESTINAL UPSET, IRRITATION, ANAPHYLACTIC SHOCK.
Medical Cond Aggravated By Exposure: PENICILLIN/CEPHALOSPORIN HYPERSENSITIVITY.
First Aid: EYES: FLUSH W/PLENTY OF WATER. SKIN: WASH W/PLENTY OF SOAP &
WATER. INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING, PROIDE CPR IF
NECESSARY. INGESTION: DON'T INDUCE VOMITING. ADMINISTER ACTIVATED CHA RCOAL
(6-8 HEAPING TEASPOONFULS) W/TWO TO THREE GLASSES OF WATER. DON'T GIVE
ANYTHING BY MOUTH IF UNCONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES.
*
Handling and Disposal
*
Spill Release Procedures: CONTAIN DRY MATERIAL BY SWEEPING UP/VACUUMING USING A
DUST COLLECTION FILTER. BE AWARE OF DUST EXPLOSION WHEN USING ELECTRICAL
EXPOSURE.
Waste Disposal Methods: DISPOSE OF ANY CLEANUP MATERIALS & WASTE RESIDUE IN
ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
Handling And Storage Precautions: UNDER NORMAL USE & HANDLING CONDITIONS,
NO PROTECTIVE EQUIPMENT IS REQUIRED.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: WATER, CO2, DRY CHEMICAL, FOAM/HALON
Unusual Fire/Explosion Hazard: AS A FINELY DIVIDED MATERIAL, MAY FORM EXPLOSIVE
DUST MIXTURES IN AIR WHICH COULD EXPLODE IF SUBJECTED TO A SOURCE OF
IGNITION.
*
*
Respiratory Protection: USE AN APPROVED RESPIRATOR. IN PRODUCTION,
AIRLINE-SUPPLIED, HOOD-TYPE RESPIRATORS ARE PREFERRED.
Ventilation: LABORATORY FUME HOOD/LOCAL EXHAUST
Other Protective Equipment: CHEMICAL RESISTANT CLOTHING, SAFETY GLASSES
Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
WASH THOROUGHLY AFTER HANDLING.
*
Physical/Chemical Properties
*
PH: (SUPP)
Solubility in Water: COMPLETE
Appearance and Odor: WHITE TO OFF-WHITE CRYSTALLINE POWDER W/NO ODOR
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: HEAT
Materials To Avoid: STRONG OXIDIZING AGENTS
Hazardous Decomposition Products: TOXIC FUMES WHEN HEATED
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Assigned IND: Y
Company Name: LILLY ELI & CO PHARMACEUTICAL DIV
Street: LILLY CORPORATE CENTER
Label Required IND: Y
Status Code: C
Origination Code: G
Hazard And Precautions: ALLERGIC REACTIONS HAVE BEEN REPORTED, WHICH MAY
INCLUDE EYE IRRITATION.
RASH, NASAL CONGESTION, COUGH, DRY THROAT, GASTR
OINTESTINAL UPSET, IRRITATION, ANAPHYLACTIC SHOCK.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE UNDER NORMAL USAGE.
Ventilation:LOCAL EXHAUST RECOMMENDED.
Other Protective Equipment:PROTECTIVE CLOTHING, EYE WASH, RUBBER APRON.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:W.DONALD WILSON
* Composition/Information on Ingredients *
Ingred Name:DIBUTYLTIN DILAURATE
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1 MG SN/M3 SKIN
ACGIH TLV:0.1 MG SN/M3
Ingred Name:STANNOUS OCTOATE
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:OVEREXPOSURE VIA INHALATION OR SKIN
ABSORPTION MAY CAUSE HEADACHE AND NAUSEA.CONTACT W/EYES/SKIN MAY
CAUSE BURNS & TISSUE DAMAGE.TOXIC IF INGESTED.
Effects of Overexposure:OVEREXPOSURE VIA INHALATION OR SKIN ABSORPTION
MAY CAUSE HEADAHCE AND NAUSEA.COTNACT W/EYE/SKIN MAY CAUSE BURNS &
TISSUE DAMAGE.TOXIC IF INGESTED.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
PHYSICIAN.SKIN:FLUSH W/WATER THEN WASH W/SOAP/WATER.INGEST:GET MED
ATTN.INHAL:MOVE INDIVIDUAL TO FRESH AIR.CALL PHYSICIAN.
* Fire Fighting Measures *
Flash Point:NE
Autoignition Temp:Autoignition Temp Text:NE
Lower Limits:NE
Upper Limits:NE
Extinguishing Media:WATER SPRAY, FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD BE EQUIPPED
Unusual Fire/Explosion Hazard:IRRITATING FUMES MAY DEVELOP WHEN PRODUCT
IS HEATED.
* Accidental Release Measures *
Spill Release Procedures:MAY BE HAZARDOUS TO AQUATIC LIFE IF RELEASED
TO OPEN WATERS.COVER SPILL W/ABSORBENT MATERIAL.TRANSFER TO
SUITABLE CONTAINER FOR DISPOSAL.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM FOOD STUFFS,STORE IN
COOL DRY AREA.
Other Precautions:NORMAL WAREHOUS HANDLING AND STORAGE IN COOL DRY
AREA.
* Physical/Chemical Properties *
HCC:N1
Boiling Pt:B.P. Text:NE
Melt/Freeze Pt:M.P/F.P Text:NE
Decomp Temp:Decomp Text:NP
Vapor Pres:NA
Vapor Density:NE
Spec Gravity:1.0
pH:NA
Evaporation Rate & Reference:NA
Solubility in Water:SLIGHTLY
Appearance and Odor:LIGHT BLUISH LIQUID WITH CHARACTERISTIC ODOR
Percent Volatiles by Volume:0
Corrosion Rate:NA
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZERS
Stability Condition to Avoid:ELEVATED TEMPERATURES OR OPEN FLAME.
* Disposal Considerations *
Waste Disposal Methods:SPREAD VERMICULITE OR SAND ON SPILLED
MATERIAL.SCOOP UP & DISCARD ACCORDING TO LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED AIR SUPPLIED RESPIRATOR IF TLV
LIMITS ARE EXCEEDED. NIOSH APPROVED MECHANICAL FILTER TO REMOVE
SOLID AIRBORNE PARTICLES OF OVERSPRAY DURING APPLICATION.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV.
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
IMPERVIOUS CLTHG & BOOTS SUGGESTED TO PREVENT PRLNG/RPTD SKIN
CONTACT.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING
BATHROOM. DO NOT REUSE CONTAMINATED CLOTHING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
CAGE:TRUTE
* Composition/Information on Ingredients *
Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (HYDROUS
MAGNESIUM SILICATE)
ACGIH TLV:2 MG/M3 RDUST
Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (MINERAL SPIRITS) VP:
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SEVERE EYE IRRITATION, DRYING
OF SKIN. EXCESSIVE INHALATION CAUSES HEADACHE, DIZZINESS AND
NAUSEA. CHRONIC:
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE KNOWN TO MANUFACTURER.
* First Aid Measures *
MINUTES. SEEK MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER.
INHALATION: REMOVE TO FRESH AIR. USE ARTIFICIAL RESPIRATION IF
NECESSARY. GET M EDICAL ATTENTION. INGESTION: DO NOT INDUCE
VOMITING. KEEP PERSON WARM AND QUIET. GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Lower Limits:0.9%
Extinguishing Media:FOAM, "ALCOHOL" FOAM, CARBON DIOXIDE, DRY CHEMICAL,
WATER FOG.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROT EQUIP .
TREAT AS VOLATILE LIQUID FIRE. WATER SPRAY MAY BE INEFFECTIVE. IF
WATER IS USED, FOG NOZZLES ARE PREFERABLE.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. ISOLATE FROM HEAT, SPARKS, AND OPEN FLAME.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. CONTAIN SPILL,
ABSORB LIQUID WITH CLAY, SAND OR FLOOR ABSORBENT. PREVENT RUN-OFF
TO SEWERS, STREAMS OR OTHER BODIES OF WATER.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS AND OPEN
Other Precautions:DO NOT TAKE INTERNALLY. AVOID PROLONGED CONTACT WITH
SKIN. CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL
OF MORE THAN 2-3 INCHES WHEN POURING.
* Physical/Chemical Properties *
Vapor Pres:SEE ING 2
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:ISOLATE FROM HEAT AND OPEN FLAME.
Hazardous Decomposition Products:
* Disposal Considerations *
Waste Disposal Methods:CONTAMINATED ABSORBENT MAY BE DEPOSITED IN A
LANDFILL IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPRVD CHEM RESP FOR ORGANIC VAPORS
AS REQD
Ventilation:GEN DILTN OF LOC EXHST IN VOL & PATTERN TO KEEP BELOW TLV
Supplemental Safety and Health
DO NOT APPLY PRODUCT TO HOT SURFACES.PART A OF A TWO PART PRODUCT.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE) (EGEEA)
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
Fraction by Wt: 2%
Ingred Name:METHYL N-AMYL KETONE
Ingred Name:POLYESTER
* Hazards Identification *
Effects of Overexposure:INH:ANESTH.IRRIT RESP TRACT OR ACUTE CNS
DEPRESS W/HDCH,DIZ,STAG,UNCON.SEV EYE IRRIT;DRY SKIN
* First Aid Measures *
First Aid:INH:REMOVE TO RESH AIR.APPLY ARTIF RESP IR NEC.KEEP WARM &
QUIET. CALL MD.SKIN:WASH AREAS W/SOAP & WATER.REMOVE CONTAM
* Fire Fighting Measures *
Extinguishing Media:NFPA CLASS B EXTING,CO*2,DRY CHEMICAL,FOAM
Fire Fighting Procedures:USE WATER FOG TO COOL EXPOS CANS & PREVENT
PRESSURE BUILDUP
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY XCLSD.KEEP FRM
IGNIT SOURCES.CLSD CAN MAY EXPLO FRM EXTREM HEAT.(SUP DATA)
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT.AVOID BRTHNG
VAPORS.VENTIL AREA.REMOVE W/INERT ABSORBENT.WIPE UP W/SOLENT TO
REMOVE FINAL RESIDUE.OBSERVE SPECIAL PROTECTION INFO.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL,DRY PLACE.STORE LG QTY
INBUILDINGS DESIGNED & PROTECTED FOR STORAGE OF NFPA CLASS II
COMBUST LIQ.
Other Precautions:DO NOT TAKE INTERNALLY.AVOID PROLONGED CONTACT
W/SKIN;CONTAM CLOTHING SHOULD BE REMOVED IMMED.GROUND CONTAINER
WHEN POURING.AVOID FREE FALL OF LIQ IN EXCESS OF A FEW IN.
* Physical/Chemical Properties *
HCC:F4
Vapor Density:>1.0
Evaporation Rate & Reference:SLOWER THAN ETHER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CAN REACT W/STRONG OXIDIZING MATERIALS
Hazardous Decomposition Products:CO,CO*2
* Disposal Considerations *
Waste Disposal Methods:MFR RECM INCIN IN APPRVD FACILITY.DO NOT INCIN
CLSD CONTAINERS.DISPOSE IAW FED,STATE & LOCAL CODES.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:TYPICAL USE OF PRODUCT DOES NOT REQUIRE THE USE
OF A RESPIRATOR. IF PRODUCT IS MISTED, USE NIOSH/MSHA APPROVED MASK
FOR SPRAY MISTS.
Ventilation:LOCAL EXHAUST VENTILATION SUFFICIENT TO MAINTAIN WORKPLACE
CONCENTRATION BELOW PEL.
Other Protective Equipment:NOT APPLICABLE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC:PERSON WARM, QUIET & GET MEDICAL ATTENTION. ASPIRATION
OF MATERIAL INTO LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL
PNEUMONTIS WHICH CAN BE FATAL. NOTES TO MD: GASTRIC LAVAGE IS
INDICATED.DO NOT INDUCE VOMITING.
* Product Identification *
Preparer's Name:R. STOLLEY
* Composition/Information on Ingredients *
Ingred Name:CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHENYL)-,(R)-;
(D-LIMONENE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:HYDROTREATED HEAVY NAPHTHA (PETROLEUM); (HYDROTREATED HEAVY
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:1-PROPANOL, 2-(2-(2-METHOXYPROPOXY)PROPOXY)-; (TRIPROPYLENE
OSHA PEL:N/K
ACGIH TLV:N/K
OXALATE; (CITRAL)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:VANILLIN
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:MAY BE IRRITATING TO EYES &
SKIN. MAY CAUSE DEFATTING OF SKIN. INGESTION OF LGE QTYS CAN CAUSE
NAUS, CRAMPS, VOM & DIARR. ASPIR OF MATL INTO LUNGS CAN CAUSE CHEM
PNEUMONITIS WHICH CAN BE FATAL. EXCESSIVE BRTHG OF VAPS/SPRAY
MISTS CANLEAD TO NASAL & RESP IRRIT. CHRONIC: MARKED IRRIT TO EYES.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:EXCESSIVE OVEREXPOSURE TO SKIN CAN
CAUSE DERMATITIS & CHAPPING. SOME STUDIES HAVE INDICATED THAT
INGREDS IN THIS PRODUCT COULD CAUSE SENSITIZATION OF SKIN &
RESPIRATORY SYSTEM.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR & PROVIDE SUPPORTIVE MEASURES.
UPPER/LOWER LIDS OCCASNLY. GET MED ATTN IF IRRIT PERSISTS.
TREATMENT IS MOST EFTIV E W/IN ONE MINUTE. SKIN:THORO WASH W/SOAP &
WATER. REMOVE CONTAMD CLTHG & LAUNDER BEFORE REUSE. APPLY EMOLLIENT
RICH CREAM. IF IRRIT DEVELOPS, SEEK MED ATTN. INGEST:DO NOT INDUCE
VOM. KEEP (SUP DAT)
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL OR WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIP . WEAR EQUIP WHEN FIGHTING FIRES IN CONFINED AREAS
TO PVNT EXPOS TO ACRID SMOKE & HAZ DECOMP PRODS.
Unusual Fire/Explosion Hazard:PRODUCTS OF COMBUSTION INCLUDE OXIDES OF
CARBON & ACRID SMOKE.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. USE ABSORBANT
SUCH AS PAPER, VERMICULITE, ETC. TO CONTAIN SPILL. DO NOT FLUSH TO
SEWER. PLACE INTO LABELED CONTAINERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
SIDE TO PVNT CONDENSATION & SUBSEQUENT CONTAM OF PROD. KEEP AWAY
FROM IGNIT SOURCES. KEEP CONTR TIGHTLY CLSD.
Other Precautions:KEEP AWAY FROM CHILDREN. READ ENTIRE LABEL BEFORE
USING PRODUCT.
* Physical/Chemical Properties *
HCC:V4
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:TRANSPARENT AMBER; ORANGE-VANILLA ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS SUCH AS LIQUID CHLORINE, LIQUID OXYGEN & SODIUM OR
CALCIUM HYPOCHLORITES.
Stability Condition to Avoid:AVOID EXPOSURE TO HEAT, SPARKS & OPEN
FLAMES.
Hazardous Decomposition Products:OXIDES OF CARBON & ACRID SMOKE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/ALL FEDERAL, STATE &
LOCAL POLLUTION REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF TLV IS EXCEEDED, A NIOSH/MSHA JOINTLY
APPROVED AIR SUPPLY RESPIRATOR IS ADVISED IN ABSENCE OF PROPER
ENVIRONMENTAL CONTROL.
Ventilation:SUFFICIENT MECHANICAL (GENERAL/LOCAL EXHAUST) VENTILATION
TO MAINTAIN EXPOSURE BELOW TLVS.
Other Protective Equipment:SOLVENT IMPERVIOUS CLOTHING & BOOTS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH W/SOAP & WATER AFTER USE, BEFORE EATING/SMOKING.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:P D MOORE
* Composition/Information on Ingredients *
Ingred Name:PROPYLENEGLYCOL MONOMETHYL ETHER ACETATE,
1-METHOXY-2-PROPANOL ACETATE
Fraction by Wt: 5%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE IRRITATION TO
THE RESPIRATORY TRACT; NOSE, THROAT, LUNGS & CAUSE NARCOSIS. EYES:
IRRITATING, MAY INJURE TISSUE IF NOT PROPERLY REMOVED. SKIN: SLIGHT
IRRITANT. INGESTION: MODERATE LY TOXIC.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, NAUSEA, VOMITING, DIARRHEA,
NARCOSIS
Medical Cond Aggravated by Exposure:RESPIRATORY PROBLEMS.
* First Aid Measures *
INHALATION: MOVE TO FRESH AIR. INGESTION: DON'T INDUCE VOMITING.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1.1
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS W/A
FULL FACEPIECE OPERATED IN PRESSURE-DEMAND WHEN FIGHTING FIRES. USE
WATER FOG NOZZLES TO COOL CLOSED CONTAINERS.
Unusual Fire/Explosion Hazard:DON'T USE WATER. FLAMMABLE LIQUID CAN
RELEASE VAPORS THAT FORM MIXTURES AT TEMP AT/ABOVE FLASHPOINT.
ELIMINATE/ISOLATE IGNITION SOURCES. MAY PRODUCE TOXIC GASES
* Accidental Release Measures *
Spill Release Procedures:WEAR RESPIRATOR, ABSORB W/VERMICULITE/OTHER
ABSORBENT MATERIAL. ELIMINATE ALL IGNITION SOURCES. STOP LEAK AT
SOURCE & PREVENT SPREADING.
*Handling and Storage *
Handling and Storage Precautions:STORE IN DRY AREA. KEEP CONTAINERS
CLOSED. PROTECT FROM PHYSICAL DAMAGE. EMPTIED CONTAINERS RETAIN
Other Precautions:STORE LARGE QUANTITIES IN BUILDINGS DESIGNED TO
DON'T STORE NEAR HEAT/SPARKS/FLAME. DON'T GET IN EYES. KEEP AWAY
FROM CHILDREN. AVOID SK IN CONTACT. DON'T TAKE INTERNALLY.
* Physical/Chemical Properties *
Vapor Density:>1
Spec Gravity:1.1
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:<0.1
Appearance and Odor:BLACK LIQUID W/SOLVENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:EXCESSIVE HEAT, SPARKS, FLAME, TEMPS
Hazardous Decomposition Products:BY BURNING: CO2, CO
* Disposal Considerations *
Waste Disposal Methods:DESTROY BY LIQUID INCINERATION. CONTAMINATED
ABSORBENT MAY BE DEPOSITED IN A LANDFILL IAW/LOCAL, STATE & FEDERAL
REGULATIONS.
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED UNDER NORMAL USE. NIOSH APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:NONE REQUIRED UNDER NORMAL USE.
WHEN HANDLING BULK AMOUNTS. ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:AVOID INHALATION, INGESTION, SKIN OR EYE
CONTACT.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
2-4)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:IRON (III) OXIDE (IRON OXIDE). REC EXPOS LIM:5 MG/M3
(AUSTRALIA NOHSC)
Other REC Limits:SEE INGREDIENT
ACGIH TLV:5 MG(FE)/M3 FUME, B2
(AUSTRALIA NOHSC)
Other REC Limits:SEE INGREDIENT
Ingred Name:COPPER OXIDE
OSHA PEL:1 MG CU/M3
ACGIH TLV:1 MG CU/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:MINIMAL RESPIRATORY TRACT
IRRITATION MAY OCCUR AS WITH EXPOSURE TO LARGE AMOUNTS OF ANY
NON-TOXIC DUST. CHRONIC:NONE LISTED BY MANUFACTURER.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NOT APPLICABLE.
* First Aid Measures *
First Aid:SKIN:WASH WITH SOAP AND WATER. EYE:FLUSH THOROUGHLY WITH
INGEST:DILUTE STOMACH CONTENTS WITH SEVERAL GLASSES OF WATER AND
SEEK MEDICAL TREATME NT. INHAL:PROMPTLY REMOVE FROM EXPOSURETO
FRESH AIR AND SEEK MEDICAL TREATMENT.
* Fire Fighting Measures *
Extinguishing Media:IF PRODUCT BECOMES INVOLVED IN A FIRE, USE CARBON
DIOXIDE EXTINGUISHER.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . WATER, FOAM OR DRY CHEMICAL.
Unusual Fire/Explosion Hazard:NONE UNDER NORMAL STORAGE AND USE
CONDITIONS.
* Accidental Release Measures *
Spill Release Procedures:CLEAN UP WITH A VACUUM CLEANER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:CLOSE CAP TIGHTLY AND STORE IN A COOL,
DRY AND DARK PLACE.
Other Precautions:AVOID COMBUSTION.
* Physical/Chemical Properties *
Melt/Freeze Pt:M.P/F.P Text:SUPDAT
Solubility in Water:INSOLUBLE
Appearance and Odor:BLACK POWDER, ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:NONE IN NORMAL HANDLING AND USE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:A RESPIRATOR THAT IS RECOMMENDED OR APPROVED FOR
USE IN ISOCYANATE CONTAINING ENVIROMENTS (AIR PURIFYING OR FRESH
AIR SUPPLIED) IS NECESSARY. OBSERVE OSHA REGULATIONS FOR RESPIRATOR
USE.
Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP THE AIRBORNE
CONCENTRATIONS OF THE SOLVENT VAPORS OR MIST BELOW THEIR TLV'S.
Other Protective Equipment:USE LONG SLEEVE AND LONG LEG CLOTHING.
REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING
WASHROOM. SMOKE IN SMOKING AREAS ONLY.
Supplemental Safety and Health
OTHER PRECAUTIONS: PROLONGED OVEREXPOSURE CAN CAUSE AN ALLERGIC
REACTION. AVOID CONTACT WITH SKIN AND EYES. DO NOT TAKE INETRNALLY.
DO NOT HANDLE UNTIL MANUFACTURES SAFETY PRECAUTIONS HAVE BEEN READ
A ND UNDERSTOOD.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:METHYL ISOBUTYL KETONE
Other REC Limits:NONE RECOMMENDED
Ingred Name:2-ETHOXYETHYL ACETATE
Fraction by Wt: 5%
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:5 PPM
Ingred Name:TOLUENE
Fraction by Wt: <5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:HOMOPOLYMER OF HEXAMETHYLENE DIISOCYANATE (HDI)
Other REC Limits:NONE RECOMMENDED
Ingred Name:N-BUTYL ACETATE
Fraction by Wt: <5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:XYLENE
Fraction by Wt: <5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:METHYL ETHYL KETONE
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: VAPORS OR MISTS AT
CONCENTRATIONS ABOVE SUGGESTED TLV CAB IRRITATE THE MUCOUS
MEMBRANES IN THE RESPIRATORY TRACT CAUSING RUNNY NOSE, SORE THROAT,
COUGHING, CHEST DISCOMFORT, SHORTNESS OF BREATH & REDUCED LUNG
FUNCTION. CHRONIC: CERTAIN INDIVIDUALS WILL DEVELOP ISOCYANATE
SENSITIZATION.
Explanation of Carcinogenicity:NONE OF THE LISTED HAZARDOUS INGREDIENTS
ARE LISTED AS CARCINOGENS BY NTP, IARC MONOGRAPHS OR OSHA.
Effects of Overexposure:INHALATION-HEADACHE, DIZZINESS, STAGGERING
GAIT, CONFUNSION, UNCONSCIOUSNESS OR COMA. SKIN & EYE-MAY BE
SWELLING, REDNESS, RASH. TEARING, REDNESS & SWELLING ACCOMPANIED BY
STINGING SENSATION. INGESTIO N-VOMITING MAY CAUSE ASPIRATION OF THE
SOLVENT RESULTING IN CHEMICAL PNEUMONITIS.
Medical Cond Aggravated by Exposure:ISOCYANATE SENSITIZATION. ASTHMA.
DERMATITIS.
* First Aid Measures *
First Aid:INHALE:MOVE TO AN AREA FREE FROM RISK OF FUTHER EXPOSURE.
RESTORE BREATHING. OBTAIN MEDICAL ATTN. SKIN:REMOVE CONTAMINATED
CLOTHING. WASH AFFECTED AREAS THOROUGHLY WITH SOAP & WATER.
LIFTING EYELIDS. OBTAIN MEDICAL ATTENTION. INGEST:DO NOT INDUCE
VOMITING. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
OBTAIN MEDICAL ATTENTION
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1.7
Extinguishing Media:FOAM, ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL,
WATER FOG.
Fire Fighting Procedures:FULL FIRE FIGHTING EQUIPMENT WITH
SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING
SHOULD BE WARN BY FIRE FIGHTERS.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, SPARKS, ELECTRICAL EQUIPMENT AND OPEN FLAME. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE ALL NONESSENTIAL PERSONNEL. REMOVE
ALL SOURCES OF IGNITION (FLAME, HOT SURFACES, SPARK SOURCES)
VENTILATE AREA. CONTAIN AND REMOVE WITH INERT ABSORBENT AND
NON-SPARKING TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN BUILDING DESIGNED TO COMPLY
OPEN FLAMES & SPARK SOURCES.
Other Precautions:STORE IN TIGHTLY CLOSED CONTAINERS. STORE IN WELL
VENTILATED AREAS. KEEP CONTAINERS TIGHT & UPRIGHT TO PREVENT
LEAKAGE. PREVENT PROLONGED OR REPEATED BREATHING OF VAPORS OR SPRAY
MIST.
* Physical/Chemical Properties *
HCC:F3
Vapor Density:>AIR
Spec Gravity:0.9
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR, LIGHT AMBER COLOR WITH SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE
ACTIVE MATERIALS.
Stability Condition to Avoid:CONTACT WITH MOISTURE, MATERIALS WHICH
REACT WITH ISOCYANATES, AND HIGH TEMPERATURES.
Hazardous Decomposition Products:BY HIGH HEAT AND FIRE: CARBON DIOXIDE,
CARBON MONOXIDE, OXIDES OF NITROGEN, TRACES OF HCN, HDI.
* Disposal Considerations *
Waste Disposal Methods:WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH
FEDERAL, STATE AND LCOAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY
CONTAINERS MUST BE HANDLED WITHCARE DUE TO PRODUCT RESIDUE AND
FLAMMABLE VAPOR. DO NOT IN CINERATE CLOSED CONTAINERS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE SUPPLIED-AIR RESPIRATORY PROTECTION IN
CONFINED OR ENCLOSED SPACES, IF NEEDED.
Ventilation:SUFFICIENT TO MAINTAIN ATMOSPHERE BELOW TLV LIMIT.
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. CHEMICALLY
RESISTANT BOOTS AND APRONS RECOMMENDED.
Work Hygienic Practices:DO NOT TAKE INTERNALLY. AVOID SKIN CONTACT.
WASH SKIN AFTER USING PRODUCT. DO NOT EAT, DRINK OR SMOKE IN WORK
AREA.
Supplemental Safety and Health
WASH OR TAKE SHOWER IF GENERAL CONTACT OCCURS. REMOVE OIL-SOAKED
CLOTHING AND LAUNDER BEFORE REUSE. DISCARD CONTAMINATED LEATHER
GENERATED,OBSERVE A TWA/PEL OF 5 MG/M3 FOR MINERAL OIL MIST.
* Product Identification *
CAGE:0BCE7
CAGE:0BCE7
* Composition/Information on Ingredients *
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY
PARAFFINIC
Other REC Limits:NONE SPECIFIED
ACGIH TLV:5 MG/M3 (OIL MIST)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE-INGESTION:NOT EXPECTED TO CAUSE
ILL EFFECTS. INHALATION:NO ADVERSE HEALTH EFFECTS
EXPECTED,HOWEVER,MINUTE AMOUNTS ASPIRATED INTO LUNGS MAY CAUSE
PULMONARY INJURY. EYE: IRRITATION. SKIN: NOT NORM ALLY EXPECTED TO
CAUSE ILL EFFECTS.CHRONIC-PROLONGED/REPEATED SKIN CONTACT MAY
CAUSE IRRITATION,DERMATITIS.
Explanation of Carcinogenicity:THE COMPONENTS OF THIS PRODUCT HAVE NOT
SHOWN ANY EVIDENCE OF BEING CARCINOGENIC.
Effects of Overexposure:PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE
SKIN IRRITATION. EYE CONTACT MAY CAUSE EYE IRRITATION.
Medical Cond Aggravated by Exposure:PERSONS WITH A SKIN DISORDER SHOULD
AVOID PROLONGED CONTACT WHEN HANDLING OR USING THIS PRODUCT.
* First Aid Measures *
First Aid:SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER.
GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INHALATION: REMOVE TO
FRESH AIR & RESTORE BREATHING IF NECESSARY. GET MEDICAL ATTENTION.
EYELIDS OPEN. GET MEDICAL ATTENTION. INGESTION: GET IMMEDIATE
MEDICAL ATTENTION. DO NOT INDUCE VOMITING. NOTHING BY MOUTH IF
UNCONSCIOUS.
* Fire Fighting Measures *
Flash Point Method:OC
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS, SUCH AS OXIDES OF
CARBON, NITROGEN AND SULPHUR.
* Accidental Release Measures *
Spill Release Procedures:RECOVER FREE PRODUCT, OR ABSORB WITH
DIATOMACEOUS EARTH OR OTHER INERT MATERIAL. STORE IN APPROPRIATE
CONTAINER FOR DISPOSAL. KEEP PRODUCT OUT OF SEWERS AND WATERCOURSES
BY DIKING OR IMPOUNDING. MINIM IZE SKIN CONTACT AND BREATHING
VAPORS.
*Handling and Storage *
Handling and Storage Precautions:AVOID STORAGE NEAR OPEN FLAME OR OTHER
SOURCES OF IGNITION,AND STRONG OXIDANTS.KEEP CONTAINERS CLOSED.
Other Precautions:EMPTY CONTAINERS RETAIN RESIDUE.DO NOT
PRESSURIZE,CUT,WELD OR EXPOSE TO HEAT,FLAME,STATIC ELECTRICITY, OR
OTHER SOURCES OF IGNITION;THEY MAY EXPLODE AND CAUSE INJURY.
* Physical/Chemical Properties *
Vapor Pres:0.1
Solubility in Water:INSOLUBLE
Appearance and Odor:DARK AMBER COLORED LIQUID WITH NO OILY ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS SUCH AS HYDROGEN PEROXIDE, BROMINE, AND CHROMIC
ACID.
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES
Hazardous Decomposition Products:FUMES,SMOKE., OXIDES OF CARBON,
NITRGEN AND SULFUR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:UNDER NORMAL USE CONDITIONS NO RESPIRATORY
PROTECTION IS REQUIRED WHEN USING THIS PRODUCT.SELF-CONTAINED
BREATHING APPARATUS IS REQUIRED IF LARGE SPILL OCCURS.
Ventilation:NORMAL VENTIL FOR STD USE PROCEDURES GEN ADEQUATE.LOC EXHAU
FOR WHEN LG AMTS RELEASED.MECHAN VENTI IN LOW/ENCLSD PLACES.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
CAUTION IN SITUATIONS OF EMERG LIFE SUPPORT.EMESIS/GASTRIC LAVAGE
SHOULDN'T BE EMPLOYED UNLESS RISK IS JUSTIFIED BY PRESENCE OF ADDN
TOXIC SUBSTANCES.
* Product Identification *
Product ID:FREON TF CLEANING AGENT FREON PRECISION CLEANING AGENT
Preparer's Name:ENGINE & PRODUCT SAFETY
CAGE:0WLZ8
* Composition/Information on Ingredients *
Other REC Limits:NONE RECOMMENDED
Ozone Depleting Chemical:1
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:VERY LOW TOXICITY BY
INHAL.LIFE-THREATENING EXPO MAY OCCUR IF HNDLD CARELESSLY.VAP
HEAVIER THAN AIR POSING HAZ OF ASPHYXIATION IF TRAPPED IN
ENCLSD/LOW PLACES.@FLAME TEMPS CMPD DECPO TO HYDROGEN FLUO
RIDE-LETHAL @LOW CONC.PRODUCT POSES HAZOF FATAL HEART IRREG IF
INHAL @HI CONC.SKIN/EYE IRRIT.PROL SKIN (SIGNS/SYMPTOMS)
Explanation of Carcinogenicity:PER MSDS:NONE OF COMPONENTS PRESENT IN
MATL @CONC =/> 0.1% ARE LISTED BY IARC/NTP/OSHA/ACGIH AS
CARCINOGEN.
Effects of Overexposure:HEALTH HAZ:CONTACT DRYING.INHAL/INGEST CAUSE
DIZZ,HEAD,CONFUSION,INCOORD,LOSS OF CONSC. MILD SKIN/EYE
IRRIT,DISCOMFT,RASH,TINGLING NUMB,COLD,DRY.TEARING,BLUR
VISION.ASPIRATION-CHEM PNEUMONIA,COUGH,GAS P,CHOKE,BREATH
SHORTNESS,BLUISH DISCOLOR,RAPID
BREATH,DROWS,CONF,COMA,SEIZURES.TEMP CNS DEPRESS,ALT HEART ELECT
ACTIVITY
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:IMMED REMOVE TO FRESH AIR.KEEP CALM.NOT BREATH GIVE ART
RESP;DIFFI BREATH GIVE OXY.CALL DR.SKIN:FLUSH W/PLENTY OF WATER FOR
CMPD NOT LIKELY TO BE HAZ BY INGEST.DO NOT INDUCE VOMIT.HOWEVER
CONSULT DR IF NECESSARY.DR:ADMIN ACTIVATE CHARCOAL
* Fire Fighting Measures *
Flash Point:WILL NOT BURN
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NP
Upper Limits:NP
Extinguishing Media:NONE SPECIFIED BY MANUFACTURER.
Fire Fighting Procedures:USE WATERSPRAY/FOG TO COOL
CNTNR.SELF-CONTAINED BREATHING APPARATUS(SCBA)REQUIRED IF DRUMS
RUPTURE & CONTENTS SPILLED UNDER FIRE CONDITIONS.
Unusual Fire/Explosion Hazard:DRUMS MAY RUPTURE UNDER FIRE CONDITIONS.
DECOMPOSITION MAY OCCUR.
* Accidental Release Measures *
Spill Release Procedures:REVIEW MSDS.USE APPROPRIATE PPE DURING
CLEANUP.VENTILATE AREA.DONT FLUSH INTO SEWERS.DIKE/COLLECT ON
ABSORBENT MATL.TRANSF TO STEEL DR FOR RECOVER/DISPO.USE SCBA FOR LG
SPILLS.COMPLY W/FED/STATE/LOC R EGS ON REPORTING RELEASES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AVOID BREATH VAP/PROL SKIN EXPO.USE
W/SUFFICIENT VENTI TO KEEP EMPLOYEE EXPO BELOW RECOMMENDED
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Density:2.9
pH:NEUTRA
Viscosity:NP
Evaporation Rate & Reference:>1 (CCL4=1).
Appearance and Odor:SLIGHT ETHEREAL ODOR, LIQUID, CLEAR, COLORLESS.
Corrosion Rate:NP
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE W/ALKALI OR ALKALINE EARTH METALS-POWDERED AL, ZN, BE,
ETC.
Stability Condition to Avoid:AVOID OPEN FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:DECOMP PROD HAZ.CAN BE DECOMPO BY HI
TEMP(OPN FLAME,GLOW METAL SURFACES,ETC)FORM HCL,HYDROFLUORIC
ACIDS,CARBONYL HALIDES
* Disposal Considerations *
Waste Disposal Methods:COMPLY W/FED/STATE/LOC REGS.REMOVE TO PERMITTED
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A
NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED.
CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK
AT HAND.
Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS
GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS.
Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE
GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL
Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS.
USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST
CREATION
Supplemental Safety and Health
GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING
ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR
MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE
REMOVED.
* Product Identification *
Preparer's Name:DOD HMIS/DGSC-SSH
* Composition/Information on Ingredients *
Ingred Name:ASBESTOS, CHRYSOTILE
OSHA PEL:0.2 FIBERS/CC
Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER & STEEL & NICKEL
COMPOSITION
Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE
CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR"
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN;
CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING,
FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE
TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA.
SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG
CANCER RISK!
Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS
OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA.
Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING
ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO
ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION
FROM AIRBORNE DUST; INGEST: N/K.
Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO
REPEATED INHALATION OF AIRBORNE FIBERS.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN:
WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF
IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A
PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING
DUST PARTICLES INTO OTHER AREAS
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE
TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES
INVOLVING CHEMICAL PRODUCTS.
Unusual Fire/Explosion Hazard:NONE KNOWN
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET
CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/
AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO
THE ATMOSPHERE.
*Handling and Storage *
Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE
FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL
PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!!
Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT
A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS &
DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME
AIRBORNE.
* Physical/Chemical Properties *
HCC:T6
Evaporation Rate & Reference:NONE
Solubility in Water:NOT SOLUBLE
Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS:
"ITEM-NAME"
Percent Volatiles by Volume:NONE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE KNOWN
* Disposal Considerations *
Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR
LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER
CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
| 1 | gloves_mandatory |
Control Measures
*
Product ID: PITTCLOR
*
Contractor Summary
*
*
Ingredients
*
CHLORINE)) (CERCLA)
OSHA PEL: 0.5 PPM (CL)
ACGIH TLV: 0.5 PPM; 1 STEL (CL)
------------------------------
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
& RECREATIONAL WATER. STUDIES HAVE BEEN
-----------------------------
WATER. SEVEN GENERATIONS OF RATS WERE GIVEN
-----------------------------
GROWTH, BLOOD PARAMETERS/SPECIFIC ORGAN TOX
-----------------------------
STUDIES BY DIFFERENT GOVT AGENCIES DETERMINED
-----------------------------
DEVELOPING FETUS. SAFE HNDLG OF MATL ON
-----------------------------
EXPOSURE.
-----------------------------
UNCON OR IN CONVLS, TAKE IMMED TO HOSPITAL.
-----------------------------
PERSON. NOTE TO MD: TREAT SYMPTOMATICALLY.
-----------------------------
WASTE MATERIAL AS OUTLINED IN WASTE DISPOSAL SECTION.
-----------------------------
MATL W/PLENTY OF WATER & FLUSH TO SEWER.
-----------------------------
INTERFERE W/TREATMENT PLANT OPERATION.
-----------------------------
HYDROGEN PEROXIDE SOLN OVER ALL SPILLED MATL
-----------------------------
WHEN USING/DISP OF CHEM MATLS &/OR THEIR
-----------------------------
CHEM MATLS &/OR THEIR CNTNRS I/A/W CLEAN
-----------------------------
STATE & LOCAL LAWS/REGS REGARDING DISPOSAL.
-----------------------------
CLEAN, DRY SCOOP MADE OF METAL/PLASTIC EACH
-----------------------------
DEVICE CONTAINING REMNANTS OF ANY OTHER
-----------------------------
PROD ONLY TO WATER. MAY CAUSE FIRE/EXPLO
-----------------------------
EASILY COMBUST MATLS SUCH AS OIL, KEROSENE,
-----------------------------
CNTNR. RESIDUAL MATL REMAINING IN EMPTY DRUM
-----------------------------
THEN DESTROY BY PLACING IN TRASH
-----------------------------
DISPOSAL.
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INHAL OF ING 1 AS DUST & DECOMP OF PARTICLES IN
RESP TRACT CAN LEAD TO IRRIT OF TISS & VARIETY OF EFTS DEPENDING ON
CONC:UPPER RESP TRACT IRRIT, NASAL CONGESTION, COUGH, SORE THROAT, LARYNGITIS
, SHORTNESS OF BRTH. IF THERE ARE HIGH CONCS OF RESPIRABLE PARTICULATES, PULM
EDEMA POSS; CAN THREATEN (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:LIFE. SINCE PROD IN GRANULAR
FORM, PARTICLES OF RESPIRABLE SIZE NOT USUALLY ENCOUNTERED. EYE:ING 1 IS
CORR. EVEN MINUTE AMT OF DUST IN CNTCT W/EYES FOR SHORT DURATION CAN CAUSE
SEV IRRIT, BLN DNESS. SKIN:SEV IRRIT, BURNS/TISS DESTRUCTION. INGEST:CAUSES
SEV BURNS TO DIGEST TRACT & IS POSS FATAL. CHRONIC:(SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG GIVE ARTF RESP, PREF
MOUTH-TO-MOUTH. IF BRTHG IS DFCLT, GIVE OXYGEN. CALL MD. SKIN:FLUSH W/PLENTY
GET IMMED MED ATTN. INGEST: IF CONSCIOUS, DRINK LG QTYS OF WATER & ANY
COMMON COOKING (VEGETABLE) OIL, IF AVAIL.
*
Handling and Disposal
*
Spill Release Procedures: NOTE:USE EXTREME CAUTION IN HNDLG SPILLED MATL.
CONTAM W/ORG OR COMBUST MATL MAY CAUSE FIRE/VIOLENT DECOMP. IF FIRE/DECOMP
OCCURS IN AREA OF SPILL, IMMED DOUSE W/PLENTY OF WATER. OTHERWISE, SWEEP UP A
LL VISIBLE MATL USING CLEAN, DRY SHOVEL
CALCIUM HYPOCHLORITE.
Waste Disposal Methods: SPILLED MATL THAT HAS BEEN SWEPT UP & DISSOLVED IN
WATER SHOULD BE USED IMMED IN NORM APPLICATN FOR WHICH ING 1 IS BEING
CONSUMED. IF NOT POSS, CAREFULLY NEUT DISSOLVED MATL BY ADDING HYDROGEN
Handling And Storage Precautions: DO NOT GET IN EYES/ON SKIN/CLTHG. KEEP IN
ORIGINAL CNTNR IN COOL, DRY PLACE. KEEP CNTNR CLSD WHEN NOT IN USE. KEEP AWAY
FROM HEAT SOURCES,
Other Precautions: KEEP OUT OF REACH OF CHILDREN. STRONG OXIDIZER-FIRE MAY RSLT
FROM CNTCT W/HEAT, ACIDS, ORG OR COMBUST MATTER. MAY BE FATAL/HARMFUL IF
SWALLOWED. MAY CAUSE CHEM BURNS. IRRIT TO NOSE & THROAT-AVOID BRTH G
DUST. WASH HANDS AFTER HNDLG.
*
Fire and Explosion Hazard Information
*
Flash Point Text: NONE
Extinguishing Media: WATER ONLY! SMOTHERING INEFFECTIVE - PRODUCT SUPPLIES OWN
OXYGEN.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N).
CONTAINERS MAY RUPTURE.
*
*
Respiratory Protection: IF DUSTY CONDITIONS ARE ENCOUNTERED, USE NIOSH APPROVED
RESPIRATOR W/ACID GAS CARTRIDGE & DUST PREFILTER. RESPIRATOR USE
LIMITATIONS SPECIFIED BY NIOSH OR MFR MUST BE OBSERVED. RESPIRATORY
Ventilation: NONE, UNLESS DUSTY CONDITIONS ARE ENCOUNTERED.
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
BOOTS, APRONS OR CHEMICAL SUITS WHEN NECESSARY TO PREVENT SKIN CONTACT.
Work Hygienic Practices: PERSONAL PROTECTIVE CLOTHING & USE OF EQUIPMENT MUST
OVEREXP:GENOTOX:ING 1 PRDCED POS RESPONSES IN IN-VITRO ASSAYS USING BACTERIAL
SYS (AMES TEST) & CHROMOSOMAL ABERRATIONS IN CHINESE HAMSTER FIBROBLASTS.
CHROMOSOMAL ABNORMS PRDCED. ONE OF MAJOR
*
Physical/Chemical Properties
*
B.P. Text: SUPDAT
PH: SUPDAT
Appearance and Odor: WHITE POWDER WITH SLIGHT CHLORINE ODOR.
*
Reactivity Data
*
Stability Indicator: NO
Materials To Avoid: ACIDS, COMBUSTIBLE MATERIALS, ORGANICS, REDUCING AGENTS.
Hazardous Decomposition Products: ACIDS OR AMMONIA CONTAM WILL RELS TOX GASES.
EXCESSIVE HEAT WILL CAUSE DECOMP RSLTG IN RELS OF OXYGEN & CHLORINE GAS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Product ID: PITTCLOR
Company Name: PPG INDUSTRIES INC
Street: ONE PPG PLACE
Label Required IND: Y
Status Code: C
Origination Code: G
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: Slight
Hazard And Precautions: DECOMPOSITION PRODUCTS MAY BE TOXIC. ACUTE: UPPER
RESPIRATORY TRACT IRRITATION, NASAL CONGESTION, COUGH, SORE THROAT,
LARYNGITIS, SHORTNESS OF BREATH, PULMONARY EDEMA. EYES: CORROSIVE; SEVERE
IRRITATI ON, BLINDNESS. SKIN: SEVERE IRRITATION,BURNS OR TISSUE DESTRUCTION.
INGESTION: SEVERE BURNS TO DIGESTIVE TRACT AND CAN BE FATAL. CHRONIC: NONE
LISTED BY MANUFACTURER.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE THE FOLLOWING NIOSH/MSHA APPROVED RESP: HIGH
LEVELS-DUST MASK, EXCEPT SINGLE-USE RESP. FIREFIGHTING - SCBA
W/FULL FACEPIECE OPER IN PRESS DMD/OTHER POSITIVE PRESS MODE.
Ventilation:PROVIDE LOCAL EXHAUST OR GENERAL DILUTION VENTILATION
SYSTEM.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:1,5-DIPHENYLCARBAZIDE
* Composition/Information on Ingredients *
Ingred Name:CARBOHYDRAZIDE, 1,5-DIPHENYL (1,5-DIPHENYLCARBAZIDE)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: (ACUTE) POWDER/MIST MAY CAUSE
IRRIT & TOXIC EFTS. (CHRONIC) HAS NOT BEEN RPTD. SKIN: (ACUTE) DUST
CONT MAY CAUSE IRRIT. (CHRONIC) HAS NOT BEEN RPTD. EYE: (ACUTE)
DUST CONT MAY CAUSE IRRIT. (CHR ONIC) HAS NOT BEEN RPTD. INGEST:
(ACUTE) MAY HAVE SERIOUS TOXIC EFTS: CARBAZIDE, THE PARENT CMPD,
(SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: IS TOXIC, AND SHOULD BE ASSUMED
FATAL. (CHRONIC) HAS NOT BEEN RPTD.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:INHAL: REMOVE FROM EXPOS. IF BRTHG IS DFCLT, GIVE OXYGEN. GET
IRRIT PERSISTS, GET MD. EYE: IMMED FLUSH W/WATER, CONTINUING FOR AT
LEAST 1 5 MIN. GET MD. INGEST: IF VICTIM IS CONSCIOUS, IMMED GIVE 2
TO 4 GLASSES OF WATER, & INDUCE VOMIT BY TOUCHING FINGER TO BACK OF
THROAT. GET MD IMMED. ANTIDOTE: NO SPEC ANTIDOTE. TREAT SYMP &
SUPPORT.
* Fire Fighting Measures *
Flash Point:COMBUSTIBLE
Extinguishing Media:DRY CHEMICAL, CO*2, HALON, WATER SPRAY/STANDARD
FOAM. FOR LRG FIRES, USE WATER SPRAY, FOG/STANDARD FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROT
EQUIP . NO ACUTE HAZARD. MOVE CNTNR FROM FIRE AREA IF POSS. AVOID
BRTHG VAPS/DUSTS; KEEP UPWIND.
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME. FINELY DISPERSED PARTICLES ARE EXPLOSIVE.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE CONFINED SPACES. SWEEP UP, AVOIDING
DISPERSION OF DUST, AND COLLECT IN SUITABLE CONTAINER. LABEL WITH
CONTENTS AND MARK AS "POISON".
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:
Other Precautions:CONTACT LENSES SHOULD NOT BE WORN.
* Physical/Chemical Properties *
HCC:V4
Boiling Pt:B.P. Text:DECOMPOSES
Solubility in Water:INSOLUBLE
Appearance and Odor:ODORLESS, WHITE TO PINK POWDER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, HALOGENS, STRONG ACIDS.
Stability Condition to Avoid:DECOMPOSES ON EXPOSURE TO LIGHT.
Hazardous Decomposition Products:
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .
| 1 | gloves_mandatory |
Control Measures
*
*
Contractor Summary
*
Box: NK/
*
Ingredients
*
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: IRRITATING TO EYES, RESPIRATORY SYSTEM & SKIN. MAY
CAUSE SENSITIZATION BY SKIN CONTACT.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INGEST:CALL MD IMMEDIATELY (FP N). INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) (FP N). EYES:RINSE OPENED EYE W/PLENTY
ALL CONTAMINATED CLOTHING. WASH SKIN W/PLENTY OF WATER & SOAP, THEN APPLY
*
Handling and Disposal
*
Spill Release Procedures: EVACUATE AREA. SHUT OFF ALL SOURCES OF IGNIT. WEAR
W/ABSORB MATL (DIATOMACEOUS EARTH, SAND, UNIVERSAL BINDING AGENT), DISPOSE OF
CORRECTLY.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF CORRECTLY ON CONSULTATION W/APPROP LOCAL
AUTHORITY AS HAZARDOUS WASTE; DISPOSE OF EMPTY CONTAINERS ONLY AFTER
CLEANING. OBSERVE ALL FEDERAL, STATE & LOCAL LAWS. DO NOT EMPTY INTO
WATERS OR DRAINS. LIQ HAZARDOUS TO WATER; CLASS 1.
Handling And Storage Precautions: PROTECT AGAINST PHYSICAL DMG.
OUTSIDE/DETACHED STOR IS PREF. INSIDE STOR SHOULD BE IN STD FLAMM LIQS
ROOM/CABINET. SENSITIZER. KEEP TIGHTLY CLSD.
Other Precautions: SEPARATE FROM OXIDIZING MATLS. KEEP AWAY FROM SOURCES OF
IGNIT, PROTECT FROM STATIC DISCHARGE. COOL CNTNRS W/WATER SPRAY. DO NOT
BREATHE VAP. DO NOT GET IN EYES, ON SKIN, ON CLTHG. AVOID PRLNG/RPTD EX POS.
CORROSIVE. LACHRYMATOR. (SUPDAT)
*
Fire and Explosion Hazard Information
*
Flash Point Method: OC
Lower Limits: 2.1%
Extinguishing Media: USE CO*2, DRY POWDER EXTINGUISHER, FOAM. DO NOT USE DIRECT
WATER JET.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). KEEP FIRE-EXPOSED CONTAINERS COOL W/WATER. FLAMMABLE
LIQUID.
Unusual Fire/Explosion Hazard: VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE
OF IGNITION & FLASH BACK. MAY UNDERGO AUTOPOLYMERIZATION. CONTAINER
EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS.
*
*
Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation: NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment: SAFETY SHOWER & EYE BATH.
Work Hygienic Practices: WASH THORO AFTER HNDLG. USUAL INDUSTRIAL HYGIENE, KEEP
WORK CLOTHES SEPARATELY. REMOVE ALL CONTAM CLOTHING.
Supplemental Safety and Health: OTHER PREC:KEEP AWAY FROM HEAT, SPARKS &
OPEN FLAMES.
*
Physical/Chemical Properties
*
HCC: F3
Vapor Density: 1.2
Solubility in Water: SLIGHTLY SOLUBLE
Appearance and Odor: CLEAR, SLIGHTLY YELLOWISH; DISTINCTIVE, ESTER-LIKE ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: HEAT.
Materials To Avoid: OXIDIZING AGENTS, PEROXIDES, BASES, ACIDS, REDUCING AGENTS,
AMINES, HALOGENS.
Hazardous Decomposition Products: NONE WHEN USED FOR INTENDED PURPOSE & HANDLED
CORRECTLY. TOXIC FUMES OF: CARBON MONOXIDE, CARBON DIOXIDE.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: MAY POLYMERIZE ON EXPOSURE TO LIGHT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Assigned IND: Y
Company Name: LECO CORPORATION
PO Box: NK/
Label Required IND: Y
Status Code: C
Origination Code: G
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE LIQUID. CORROSIVE. AVOID EYE, SKIN &
CLOTHING CONTACT. ACUTE:IRRITATING TO EYES, RESPIRATORY SYSTEM & SKIN.
MAY CAUSE SENSITIZATION BY SKIN CONTACT. CHRONIC:NONE LISTED BY MANUFACTURER.
*
| 1 | gloves_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INHAL: IRRIT OF RESP TRACT, LUNGS. PRLNG INHAL MAY
LEAD TO FATG, NAUS, COUGHING, RESP PROBLEMS, PNEUMOCONIOSIS. SKIN: IRRIT.
EYES: IRRIT. PRLNG/RPTD CONT CAN CAUSE CONJ. INGEST: MAY CAUSE GI DI STURBS.
OVEREXP MAY CAUSE TOXICITY TO LUNGS. NUISANCE DUST HAZ-OVEREXP MAY CAUSE MECH
IRRIT OF EYES, SKIN, & RESP TRACT.
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: EYE, SKIN, RESPIRATORY DISORDERS.
First Aid: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG.
GET EMER MED ATTN. HAVE TRAINED PERS GIVE OXYGEN IF NEC. GET MED HELP FOR ANY
BRTHG DFCLTY. REMOVE TO FRESH AIR IF INHAL CAUSES EYE WATER ING, HDCH,
DIZZ/OTHER DISCOMFORT. GET MED ATTN IF DISCOMFORT/IRRIT PERSISTS. SKIN: FLUSH
FROM SKIN W/WATER. THEN WASH THORO W/SOAP & WATER. REMOVE CONTAM CLTHG.
IF IRRIT OCCURS, CONSULT MD.
*
Handling and Disposal
*
Spill Release Procedures: COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL
REGULATIONS. VENTILATE AREA. SPILLS MAY BE COLLECTED WITH ABSORBENT
MATERIALS. PLACE COLLECTED MATERIAL IN PROPER CONTAINER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS (FP N).
W/ADEQ VENT. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID
CONT W/SKIN & EYES, & BRTHG VAPS.
Other Precautions: KEEP CONTRS TIGHTLY CLSD & UPRIGHT WHEN NOT IN USE.
AVOID CNDTNS WHICH RSLT IN FORM OF INHALABLE PARTICLES SUCH AS
SPRAYING/ABRADING (SANDING) PAINTED SURFS. IF SUCH CNDTNS CANNOT BE AVOIDED,
USE APPR OP NIOSH APPRVD RESP PROT.
*
Fire and Explosion Hazard Information
*
Flash Point Text: NONE
Extinguishing Media: DRY CHEMICAL OR FOAM WATER FOG. CARBON DIOXIDE.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N). WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: CLSD CONTRS MAY BURST IF EXPOSED TO EXTREME
HEAT/FIRE. MAY DECOMPOSE UNDER FIRE CNDTNS EMITTING IRRIT &/OR TOX GASES.
IN CLSD TANKS, WATER/FOAM MAY (SUP DAT)
*
*
Respiratory Protection: WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY
Ventilation: PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP
OF VAPORS.
Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N). APRON.
Work Hygienic Practices: WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY
BEFORE EATING OR SMOKING.
SERIES. USERS OF THE "L" VERSION OF SHOULD CONSULT "LR" VERSION FOR
ADDITIONAL INFORMATION (FP N). EXPLO HAZ: CAUSE FROTHING/ERUPTION. MATLS TO
AVOID: POT ASSIUM. NITRATES.
*
Physical/Chemical Properties
*
Appearance and Odor: WHITE
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: CONTACT WITH OXIDIZING AGENTS, CONTACT WITH
ALUMINUM OR ZINC, STORAGE NEAR ACIDS, FREEZING.
Materials To Avoid: OXIDIZERS, ACIDS, BASES, ALUMINUM, ZINC, HYPOCHLORITE,
HYDRAZIDES, HALOGENATED COMPOUNDS, MAGNESIUM, SODIUM, (SUP DAT)
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, OXYGEN,
TOXIC GASES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Assigned IND: Y
Company Name: ICI PAINTS
Label Required IND: Y
Status Code: C
Origination Code: G
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: INHALATION: IRRITATION OF
RESPIRATORY TRACT, LUNGS. PROLONGED INHALATION MAY LEAD TO FATIGUE, NAUSEA,
COUGHING, RESPIRATORY PROBLEMS, PNEUMOCONIOSIS. SKIN: IRRITATION. EYES:
IRRITA TION. PROLONGED OR REPEATED CONTACT CANCAUSE CONJUNCTIVITIS.
INGESTION: MAY CAUSE GASTROINTESTINAL DISTURBANCES. OVEREXPOSURE MAY CAUSE
TOXICITY TO LUNGS. NUISANCE DUST HAZARD - OVEREXPOSURE MAY CAUSE MECHANICAL
IRRITATION OF EYES, SKIN, AND RESPIRATORY TRACT. CHRONIC: NONE SPECIFIED BY
MANUFACTURER.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
NECESSARY.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW PELS.
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN
CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING & WASH BEFORE REUSE.
Supplemental Safety and Health
EXPLO HAZ:GENERATED BY THERMAL DECOMP/COMBUST. FLAMM LIQ. CAN RELS VAPS
THAT FORM EXPLO MIXTS AT TEMPS ABOVE FLASHPOINT. SPILL PROC:COMBUST
MATL SUCH AS EARTH, SAND/VERMICULITE. MATLS TO AVOID:SODIUM
HYPOCHLORITE), ACTIVE METALS (SUCH AS POTASSIUM & MAGNESIUM).
SUBSTANCE IS ALSO (ING 2)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SUPDAT:INCOMPAT W/SPECIFIC CHEMS INCL:ACETYL BROMIDE, ALKYL
ALUMINUM SALTS, BERYLLIUM DIHYDRIDE, CARBON (ING 3)
Ingred Name:ING 2:TETRACHLORIDE + METALS, CHLOROFORM + HEAT, CHLOROFORM
+ SODIUM HYDROXIDE, CYANURIC CHLORIDE, DIETHYL ZINC, (ING 4)
Ingred Name:ING 3:NITRIC ACID & POTASSIUM TERTBUTOXIDE. PLEASE REFER TO
NFPA FIRE PROTECTION GUIDE FOR ALL SPECIFICS.
Ingred Name:EFTS OF OVEREXP:CHRONIC:PRLNG/RPTD SKIN CONT MAY CAUSE
DERM. CHRONIC INHAL & INGEST MAY CAUSE EFTS SIMILAR TO (ING 6)
Ingred Name:ING 5:THOSE OF ACUTE INHAL & INGEST. TARGET ORGS:KIDNEYS,
CNS, LIVER, EYES. TOX INFO:EFTS ON NEWBORN:BEHAVIORAL; (ING 7)
Ingred Name:ING 6:EMBRYO/FETUS:FETOTOXICITY; SPECIFIC DEVEL
ABNORMS:CVS, MUSCULOSKELETAL, UROGENITAL; PATERNAL EFTS: (ING 8)
Ingred Name:ING 7:SPERMATOGENESIS; DNA DAMAGE; DNA INHIBITOR.
Ingred Name:FIRST AID PROC:TSP OF SYRUP OF IPECAC. INHAL:GET MED AID
Ingred Name:ING 9:BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG.
Ingred Name:OTHER PREC:STORAGE AREA. HARMFUL IF INHALED. POISON-CANNOT
ADVICE IMMED (SHOW LBL WHERE POSS). KEEP CNTNR TIGHTLY CLOSED.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE:CAUSES MOD IRRIT. VAPS MAY
CAUSE IRRIT. MAY CAUSE PAINFUL SENSIT TO LIGHT. SKIN:MAY CAUSE
IRRIT. MAY BE ABSORBED IN HARMFUL AMTS. INGEST:MAY CAUSE IRRIT OF
DIGEST TRACT. MAY CAUSE CNS DEPRES S, CHARACT BY EXCITEMENT,
FOLLOWED BY HDCH, DIZZ, DROW & NAUS. ADVANCED STAGES MAY CAUSE
COLLAPSE, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:UNCON, COMA & POSS DEATH DUE TO RESP
FAILURE. MAY CAUSE KIDNEY FAILURE. INHAL:MAY CAUSE RESP TRACT
IRRIT. MAY CAUSE LIVER & KIDNEY DMG. MAY CAUSE ADVERSE CNS EFTS
INCL HDCH, CONVLS & POSS DEA TH. MAY CAUSE VISUAL IMPAIRMENT & POSS
PERM BLINDNESS. MAY CAUSE EFTS SIMILAR TO THOSE DESCRIBED FOR
INGEST. (ING 5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM
TO RUB/KEEP EYES CLSD. SKIN:FLUSH W/PLENTY OF SOAP & WATER FOR AT
IRRIT DEVELS/PERSISTS. INGEST:IF VICTIM IS CONSCIOUS & ALERT, GIVE
2-4 CUPFULS OF MILK/WATER. GET MED AID IMMED. INDUCE VOMIT BY
GIVING 1 (ING 9)
* Fire Fighting Measures *
Lower Limits:6%
Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE,
WATER SPRAY OR ALCOHOL-RESISTANT FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE WATER TO COOL FIRE-EXPOSED CONTAINERS. WATER MAY BE
INEFFECTIVE.
Unusual Fire/Explosion Hazard:CNTNRS CAN BUILD UP PRESS IF EXPOS TO
HEAT &/OR FIRE. VAPS CAN TRAVEL TO SOURCE OF IGNIT & FLASH BACK.
DURING FIRE, IRRIT & HIGHLY TOX GASES MAY BE (SUPP DATA)
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PPE AS INDICATED IN EXPOS CONTROLS,
PERSONAL PROT SECTION. SCOOP UP W/NONSPARKING TOOL, THEN PLACE INTO
SUITABLE CNTNR FOR DISP. USE WATER SPRAY TO DISPERSE GAS/VAP.
REMOVE ALL SOURCES OF I GNIT. ABSORB SPILL USING ABSORB, NON- (SUPP
DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:USE W/ADEQUATE VENT. EMPTY CONTAINERS
RETAIN PRODUCT RESIDUE (LIQUID &/OR VAPOR) & CAN BE DANGEROUS. DO
NOT GET ON SKIN/IN EYES. DO NOT INGEST/INHALE.
Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND/EXPOSE EMPTY CNTNRS TO HEAT, SPKS/OPEN FLAMES. KEEP AWAY FROM
SOURCES OF IGNIT-NO SMOKING. STORE IN COOL, DRY, WELL-VENTED AREA
* Physical/Chemical Properties *
Vapor Density:1.1
Evaporation Rate & Reference:5.2 (ETHER=1)
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID; SLIGHT ALCOHOL-LIKE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDANTS (SUCH AS BARIUM PERCHLORATE, BROMINE, CHLORINE, HYDROGEN
PEROXIDE, LEAD PERCHLORATE, PERCHLORIC ACID, (SUPDAT)
Stability Condition to Avoid:HIGH TEMPERATURES, INCOMPATIBLE MATERIALS,
IGNITION SOURCES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
FORMALDEHYDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT W/FEDERAL,
WASTE). THIS MATERIAL IS BANNED FROM LAND DISPOSAL ACCORDING TO
RCRA.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL
AIRBORNE LEVELS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING/SHOES
BEFORE REUSE.
Supplemental Safety and Health
MATS TO AVOID: SULFURIC ACID, PERCHLORIC ACID & LEAD OXIDE.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:GLYCERINE, 1,2,3,-TRIHYDROXYPROPANE, GLYCEROL, ANHYDROUS
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION. INGESTION: MAY
CAUSE GASTROINTESTINAL IRRITATION. INHALATION: MAY CAUSE
RESPIRATORY TRACT IRRITATION. MAY CAUSE KIDNEY INJURY.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, NAUSEA, VOMITING, DIARRHEA.
* First Aid Measures *
ALERT, GIVE 4 CUPS OF MOLK/WATER. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS PERSON. INHALATION: REMOVE FROM AREA. IF NOT
BREATHING GIVE CPR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. OBTAIN
MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Lower Limits:1.1
Extinguishing Media:WATER, DRY CHEMICAL, CHEMICAL FOAM/ALCOHOL
RESISTANT FOAM.
Fire Fighting Procedures:WEAR SCBA, PRESSURE-DEMAND, MSHA/NIOSH
APPROVED & FULL PROTECTIVE GEAR.
* Accidental Release Measures *
Spill Release Procedures:ABSORB W/INERT MATERIAL SUCH AS DRY
SAND/EARTH, THEN PLACE INTO A CHEMICAL WASTE CONTAINER.
*Handling and Storage *
Handling and Storage Precautions:WASH THOROUGHLY AFTER HANDLING. STORE
IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE
SUBSTANCES.
* Physical/Chemical Properties *
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR VISCOUS LIQUID W/BLAND ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, MIXTURES W/HYDROGEN PEROXIDE, POTASSIUM
PERMANGANATE/CALCIUM HYPOCHLORITE, NITRIC ACID. (SUPP)
Stability Condition to Avoid:IGNITION SOURCES & EXCESS HEAT.
Hazardous Decomposition Products:CO, CO2.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED
Other Protective Equipment:SAFETY SHOWER, EYE BATH.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ACETIC ACID, DIETHYLPHOSPHONO-, ETHYL ESTER
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HARMFUL BY INHALATION, INGESTION/SKIN
ABSORPTION. EYES/SKIN: IRRITATION. IRRITATING TO MUCOUS MEMBRANES &
UPPER RESPIRATORY TRACT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION.
* First Aid Measures *
WASH W/SOAP & COPIOUS AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH
AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: WASH OUT MOUTH W/WATER
PROVIDED PERSON IS CONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
* Fire Fighting Measures *
Extinguishing Media:WATER SPRAY, CO2, DRY CHEMICAL POWDER/APPROPRIATE
FOAM.
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
* Accidental Release Measures *
ABSORB ON SAND/VERMICULITE & PLACE IN CLOSED CONTAINERS FOR
DISPOSAL. VENTILATE AREA & WASH SITE AFTER MATERIAL PICKUP IS
COMPLETE.
*Handling and Storage *
Handling and Storage Precautions:KEEP TIGHTLY CLOSED. STORE IN A COOL
DRY PLACE.
Other Precautions:AVOID CONTACT & INHALATION. DON'T GET IN EYES, ON
SKIN/CLOTHING.
* Physical/Chemical Properties *
Appearance and Odor:COLORLESS LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Hazardous Decomposition Products:COMBUSTION: CO, CO2. THERMAL:
PHOSPHORUS OXIDES &/PHOSPHINE.
* Disposal Considerations *
Waste Disposal Methods:DISSOLVE/MIX W/COMBUSTIBLE SOLVENT & BURN IN A
CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER & SCRUBBER. DISPOSE OF
IAW/FEDERAL, STATE & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NORMALLY NOT NEEDED. NIOSH/MSHA APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:LOCAL VENTILATION AT SOURCE OF VAPORS.
Other Protective Equipment:IF REPEATED SKIN CONTACT IS LIKELY,
PROTECTIVE CLOTHING SHOULD BE WORN.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Preparer's Name:BERTRAND W. GREENWALD
* Composition/Information on Ingredients *
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (MILD)
HEAVY NAPHTHENIC; (HYDROTREATED HEAVY NAPHTHENIC OIL)
OSHA PEL:5 MG/M3
Ingred Name:PARAFFIN WAXES AND HYDROCARBON WAXES, CHLORINATED;
(CHLORINATED PARAFFIN)
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (MILD)
LIGHT NAPHTHENIC; (HYDROTREATED LIGHT NAPHTHENIC OIL)
OSHA PEL:5 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL: HOT VAPORS OR OIL MIST MAY
CAUSE MILD IRRITATION. SKIN: PRODUCT IS MILD ALKALI, PROLONGED AND
REPEATED CONTACT MAY LEAD TO VARIOUS SKIN DISORDERS SUCH AS
DERMATITIS. EYE: PRODUCT CAN BE MILDLY IRRITATING TO THE EYES.
INGEST: MAY RESULT IN VOMITING.
Explanation of Carcinogenicity:CHLOROPARAFFIN WAXES AND HYDROCARBON
WAXES: GROUP 2B (IARC).
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR. GIVE O2 IF NEEDED. SEEK MEDICAL
ATTENTION. SKIN: WASH CONTAMINATED AREAS WITH WATER. WASH CLOTHING
BEFORE REUSE. DO NOT REUSE HEAVILY CONTAMINATED CLOTHING. INGEST:
NOT INDUCE VOMITING. SEEK MEDICAL ATTENTION. EYE: FLUSH WITH H2O
* Fire Fighting Measures *
Extinguishing Media:WATER SPRAY, CHEMICAL FOAM, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. USE H2O SPRAY TO COOL FIRE EXPOSED SURFACES AND TO PROTECT
PERSONNEL. ISOLATE "FUEL" SUPPLY FROM FIRE.
Unusual Fire/Explosion Hazard:
* Accidental Release Measures *
Spill Release Procedures:REMOVE SOURCES OF IGNITION. DIKE TO PREVENT
LIQUID FROM ENTERING WATERWAYS. RECOVER LIQUID FOR DISPOSAL.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:DO NOT CONTAMINATE WITH NITRITES:
NITROSAMINES MAY FORM. IF PRODUCT FREEZES, THAW COMPLETELY BEFORE
USE AND AGITATE DRUM.
Other Precautions:THE PHYSICAL DATA PRESENTED ON THIS SHEET IS TO BE
CONSTRUED FOR THE PURPOSE OF SAFETY DETERMINATION ONLY. THE DATA
REFLECTS MAX/MIN LIMITS AND DOES NOT REPRESENT ACTUAL PRODUCT
SPECS.
* Physical/Chemical Properties *
HCC:T6
Vapor Pres:<5
Vapor Density:>1
Spec Gravity:<1 (H2O=1)
Evaporation Rate & Reference:<1 (ETHYL ETHER=1)
Solubility in Water:EMULSIFIABLE
Appearance and Odor:GREEN MODERATELY VISCOUS OIL WITH SASSAFRAS ODOR.
Percent Volatiles by Volume:NIL
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
LIQUID OXYGEN OR CHLORINE OR STRONG OXIDIZED AGENTS.
Stability Condition to Avoid:
Hazardous Decomposition Products:CO, CO2, NOX, HCL.
* Disposal Considerations *
Waste Disposal Methods:RECOVER FREE PRODUCT. ADD SAND, EARTH OR OTHER
ABSORBENT TO SPILL AREA. ASSURE CONFORMITY WITH APPLICABLE
GOVERNMENT REGULATIONS. DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL
REGULATIONS .
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:PROVIDE LOCAL EXHAUST FOR NORMAL GOOD ROOM VENTILATION.
Other Protective Equipment:SLEEVE PROTECTION
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:LACTOSE
Fraction by Wt: 1.2%
Ingred Name:SUCROSE
Fraction by Wt: 1.2%
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES/INGESTION: IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN/EYES/INGESTION: IRRITATION.
* First Aid Measures *
First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER. INGESTION:
INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:CO2, DRY CHEMICAL, OR WATER
* Accidental Release Measures *
Spill Release Procedures:SWEEP OR MOP UP & PLACE IN WASTE CONTAINER.
FLUSH AREA W/WATER.
*Handling and Storage *
Handling and Storage Precautions:AVOID INGESTION & CONTACT W/SKIN.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE, &
LOCAL CODES.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR MSHA/NIOSH APPROVED RESPIRATOR.
Ventilation:CHEMICAL FUME HOOD
Other Protective Equipment:LAB COAT, CHEMICAL RESISTANT CLOTHING.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH CAREFULLY AFTER USE.
Supplemental Safety and Health
HLTH HZRD CONT'D: IRRITANT OF THE EYES, MUCOUS MEMBRANES & SKIN. EYES:
SEVERE BURNS & PERMANENT DAMAGE. SKIN: SEVERE & PENETRATING BURNS.
INGESTION: BURNS OF THE MOUTH, ESOPHAGUS & GI TRACT. INHALATIO N:
FATAL, EDEMA OF THE LARYNX & BRONCHI, CHEMICAL PNEUMONITIS &
PULMONARY EDEMA.
* Product Identification *
* Composition/Information on Ingredients *
Fraction by Wt: 2-5%
OSHA PEL:5 MG/CUM
ACGIH TLV:5.2 MG/CUM
Ingred Name:INDIUM
Fraction by Wt: 0.1-1%
ACGIH TLV:0.1 MG/CUM
Ingred Name:WATER
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INDIUM COMPOUNDS-HARMFUL IF INHALED,
INGESTED/CONTACTED W/SKIN/EYES. INHALATION: IRRITATION TO THE UPPER
RESPIRATORY TRACT, MUCOUS MEMBRANES & BURNING. OVEREXPOSURE CAN
CAUSE LIVER, HEART, KIDNEY DAMA GE & BLOOD EFFECTS. CONCENTRATED
NITRICACID-FATAL IF INHALED/ABSORBED THROUGH SKIN. (SEE SUPP)
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INDIUM COMPOUNDS: BURNING
SENSATION/COUGHING/WHEEZING/LARYNGITIS/SHORTNESS OF
BREATH/HEADACHE/NAUSEA/VOMITING. CONCENTRATED NITRIC ACID:
IRRITATION/BURNS/VISUAL IMPAIRMENT/DEEP ULCERS/YELLOWISH STAINS
/EROSION OF
TEETH/SPASM/INFLAMMATION/COUGHING/WHEEZING/LARYNGITIS/SHORTNESS OF
BREATH/HEADACHE/NAUSEA/VOMITING.
* First Aid Measures *
FRESH AIR. INGESTION: IF CONSCIOUS, GIVE LARGE AMOUNTS OF
WATER/MILK. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:USE APPROPRIATE MEDIA FOR SURROUNDING FIRE.
Unusual Fire/Explosion Hazard:CONCENTRATED NITRIC ACID REACTS
EXPLOSIVELY W/COMBUSTIBLE ORGANIC/READILY OXIDIZABLE MATERIALS. CAN
REACT W/METALS TO RELEASE FLAMMABLE HYDROGEN GAS.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA. DILUTE W/WATER & NEUTRALIZE.
WIPE UP & PUT INTO A SEALED CONTAINER FOR PROPER DISPOSAL. WASH OFF
W/WATER AFTER PICKUP IS COMPLETE. WEAR CHEMICAL RESISTANT GLASSES,
Neutralizing Agent:SODA ASH, LIMESTONE.
*Handling and Storage *
Handling and Storage Precautions:CONCENTRATED NITRIC ACID WILL ATTACK
SOME FORMS OF PLASTICS, RUBBER & COATINGS. STORE AT ROOM TEMP. KEEP
TIGHTLY SEALED WHEN NOT IN USE.
Other Precautions:AVOID INHALATION, INGESTION & CONTACT W/EYES & SKIN.
* Physical/Chemical Properties *
Spec Gravity:1
Solubility in Water:COMPLETE
Appearance and Odor:TRANSPARENT W/AN ACRID ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENT, ALCOHOL, WOOD, TURPENTINE, METAL POWDERS, HYDROGEN
SULFIDE, STRONG BASES.
Stability Condition to Avoid:ELEVATED TEMPS
Hazardous Decomposition Products:TOXIC NITROGEN OXIDE FUMES & VAPORS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATORS DESIGNED TO
REMOVE MISTS & ORGANIC SOLVENT VAPORS. THIS PRODUCT SHOULD NOT BE
USED BY PERSONS WITH CHRONIC LUNG OR BREATHING PROBLEMS OR BY
INDIVIDUALS WHO HAVE HAD PREVIOUS REACTION TO ISOCYANATES.
Ventilation:GEN DILUTION OR LOC EXHST VENT SHOULD BE PROVIDED TO KEEP
EXPOS BELOW ACCEPTABLE LIMS & TO KEEP SOLV VAPS (ING 5)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
IMPERMEABLE CLTHG SHOULD BE WORN TO PVNT PRLNGD/RPTD CNTCT OF (ING
6)
Work Hygienic Practices:ALWAYS WASH HANDS AFTER USING THIS MATERIAL AND
BEFORE EATING, DRINKING OR SMOKING.
Supplemental Safety and Health
FIRE FIGHT PROC: RUPTURE OF CNTNRS. EXPLO HAZ: CNDTNS. DECOMP PRODS,
GENERATED BY FIRE CNDTNS, MAY POSE HLTH RISK. POLYM OF MATL IN CLSD
CNTNR CAN CREATE PRESS BUILDUP WHICH MAY CAUSE RUPTURE OF CNTNR .
EFTS OF OVEREXP: INCREASED ALLERGIC RXN ON RPTD EXPOS. HNDLG/STOR
PRECS: AVOID CNTCT W/INCOMPAT MATLS.
* Product Identification *
* Composition/Information on Ingredients *
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (CERCLA) VP:
Ingred Name:HEXANE, 1,6-DIISOCYANATO-;(HEXAMETHYLENE DIISOCYANATE
Fraction by Wt: <1.5%
OSHA PEL:N/K
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:OTHER PRECS: OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY.
AVOID CONTACT WITH EYES AND SKIN.
Ingred Name:VENT: BELOW LOWER EXPLOSION LIMIT.
Ingred Name:OTHER PROT EQUIP: WET MATERIAL WITH SKIN. BARRIER CREAM MAY
BE WORN FOR ADDITIONAL SKIN PROTECTION.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: CONTACT W/LIQ OR VAP MAY
RSLT IN IRRIT, REDNESS, TEARING & BLURRED VISION. SKIN: CNTCT W/WET
MATL MAY RSLT IN IRRIT, DERM & POSS SENSIT OF SKIN. INAHL: EXCESS
INHAL OF VAPS MAY CAUSE NASA L & RESP IRRIT, ACUTE NERVS SYS
DEPRESS, FATG, WEAK, NAUS, HDCH & DIZZ. MAY CAUSE ALLERGIC RESP RXN
IN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: SUSCEPTIBLE INDIVIDUALS. INGEST:
INGESTION OF MATL MAY CAUSE GI IRRIT, NAUS, DIARR & VOMIT. ASPIR OF
MATL INTO LUNGS DUE TO VOMIT MAY PRDCE CHEM PNEUM WHICH CAN BE
FATAL. CHRONIC: EXCESS OVE REXP TO SOLVS HAS BEEN ASSOC W/PERM
BRAIN & NERVS SYS DMG. PERSONS SENSITIVE TO ISOCYANATES WILL
EXPERIENCE (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
MIN. SEE MD FOR MEDICAL TREATMENT. SKIN: IMMED WASH AFFECTED AREA
W/SOAP & WATER. REMOVE CONTAMD CLTHG. CONSULT MD IF IRRITATION
DEVELOPS. IN HAL: REMOVE TO FRESH AIR. RESTORE BRTHG. KEEP PERSON
WARM & QUIET. TREAT SYMPTOMATICALLY. GET MED ATTN. INGEST: KEEP
PERSON WARM & QUIET. CONSULT MD OR POISON CONTROL CENTER IMMED.
* Fire Fighting Measures *
Lower Limits:1.4%
Extinguishing Media:FOAM, CARBON DIOXIDE AND DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
WATER, ALCOHOLS, AMINES & OTHER CMPDS REACT W/ISOCYANATES WHICH MAY
CAUSE PRESS BUILD-UP & POSS (SUPDAT)
Unusual Fire/Explosion Hazard:SOLV VAPS ARE HVR/AIR & MAY TRAVEL ALONG
FLOOR & BE IGNITED BY SPKS/FLAME AT DIST FROM WHERE MATL IS BEING
USED. POLYM OF MATL MAY OCCUR UNDER FIRE (SUDPAT)
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. VENT AREA. WEAR
CNTNRS & ADD MORE AMMONI A. COVER LOOSELY. WASH SPILL AREA W/SOAP &
WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE MATL IN COOL, WELL-VENTD AREA.
OPEN FLAME. KEEP CNTNRS TIGHT CLSD. (SUPDAT)
Other Precautions:THIS PROD MUST BE MIXED W/OTHER MATLS BEFORE USE. MIX
WILL HAV HAZ PROPERTIES OF ALL COMPONENTS. PLEASE REFER TO MSDS FOR
EACH COMPONENT PRIOR TO USE. IF PROD IS TO BE SPRAYED, APPROP
NIOSH/MSHA APPRV D RESP PROT IS REQD. KEEP OUT (ING 4)
* Physical/Chemical Properties *
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOLS AND AMINES.
Stability Condition to Avoid:HIGH TEMPERATURES, IGNITION SOURCES AND
CONTACT WITH INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:DISP OF I/A/W FED, STATE & LOC REGS. WASTE FROM
TESTED FOR IGNIT TO DETERM APPLIC EPA HAZ WASTE NUMBERS. BEFORE
ATTEMPTING CLEAN-UP/DISP O F MATL, REFER TO HAZ INFO IN OTHER
MSDSSECTIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA-APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Other Protective Equipment:SAFETY SHOWER AND EYE BATH.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. AVOID
INHALATION. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID
PROLONGED OR REPEATED EXPOSURE.
Supplemental Safety and Health
* Product Identification *
Kit Part:Y
CAGE:1FPM8
CAGE:1FPM8
CAGE:1FPM8
* Composition/Information on Ingredients *
Ingred Name:ACETIC ACID
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:ACUTE EFFECTS: MAY CAUSE SKIN
IRRITATION. MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN. MAY CAUSE
EYE IRRITATION. MAY BE HARMFUL IF INHALED. MATERIAL MAY BE
IRRITATING TO MUCOUS MEMBRANES AND UPPER RES PIRATORY TRACT. MAY BE
HARMFUL IF SWALLOWED. THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL
PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
Effects of Overexposure:ACUTE EFFECTS: MAY CAUSE SKIN IRRITATION. MAY
BE HARMFUL IF ABSORBED THROUGH THE SKIN. MAY CAUSE EYE IRRITATION.
MAY BE HARMFUL IF INHALED. MATERIAL MAY BE IRRITATING TO MUCOUS
MEMBRANES AND UPPER RES PIRATORY TRACT. MAY BE HARMFUL IF
SWALLOWED. THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL PROPERTIES
HAVE NOT BEEN THOROUGHLY INVESTIGATED.
* First Aid Measures *
First Aid:IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS
CONSCIOUS. CALL A PHYSICIAN. IF INHALED, REMOVE TO FRESH AIR. IF
BREATHING BECOMES DIFFICULT, CALL A PHYSICIAN. IN CASE OF CONTACT,
IMMEDIATE LY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER. IN
CASE OF CONTACT WITH EYES, FLUSH WITH COPIOUS AMOUNTS OF WATER FOR
EYELIDS WITH FINGERS. CALL A PHYSICIAN.
* Fire Fighting Measures *
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
* Accidental Release Measures *
AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND
WASH SPILL SITE AFTER MATE RIAL PICKUP IS COMPLETE.
*Handling and Storage *
Handling and Storage Precautions:KEEP TIGHTLY CLOSED. STORE IN A COOL
DRY PLACE. WASH THOROUGHLY AFTER HANDLING. AVOID INHALATION. AVOID
CONTACT WITH EYES, SKIN AND CLOTHING. AVOID PROLONGED OR REPEATED
EXPOSURE.
* Physical/Chemical Properties *
HCC:C2
Appearance and Odor:LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:STABLE.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR,
* Disposal Considerations *
Waste Disposal Methods:CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL
SERVICE TO DISPOSE OF THIS MATERIAL. DISSOLVE OR MIX THE MATERIAL
WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR
EQUIPPED WITH AN AFTERBUR NER AND SCRUBBER. OBSERVE ALL FEDERAL,
STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
| 1 | gloves_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Item Description Information
*
Item Manager: S9G
Item Name: CLEANING COMPOUND,SOLVENT
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: DR
UI Container Qty: 0
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: NO
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: MAY CAUSE SKIN AND EYE IRRITATION. MAY BE HARMFUL IF
SWALLOWED. MAY CAUSE SEVERE MUCOSAL DAMAGE AND GASTRIC DISTRESS. MAY CAUSE
SYSTEMIC INTOXICATION.
Explanation Of Carcinogenicity: NO INGREDIENT OF A CONCENTRATION OF 0.1% OR
GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Signs And Symptions Of Overexposure: NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated By Exposure: DERMATITIS AND RELATED DISORDERS OF THE
SKIN. INHALATION MAY IRRITATE EXISTING BRONCHIAL CONDITIONS.
FOR SKIN: THOROUGHLY WASH WITH WATER AND APPLY EMOLLIENT CREME. IF IRRITATION
PERSISTS GET MEDICAL AID. IF INGESTED: DO NOT INDUCE V OMITING. GIVE MILK OR
WATER. GET IMMEDIATE MEDICAL ATTENTION.
*
Handling and Disposal
*
Spill Release Procedures: RECONTAINERIZE BY MOPPINGM, WET VACUUM OR SUITABLE
ABSORBENT. RINSE REMAINING MATERIAL TO DRAINS. BE CAUTIOUS OF SLIPPERY FLOOR.
Waste Disposal Methods: FOLLOW LOCAL, STATE AND FEDERAL REGULATIONS.
Other Precautions: KEEP OUT OF REACH OF CHILDREN. FOR SALE TO, USE AND STORAGE
BY SERVICE PERSONNEL ONLY.
*
Fire and Explosion Hazard Information
*
Flash Point Method: TOC
Flash Point Text: NONE TO BOILING
Extinguishing Media: NONE SPECIFIED BY MANUFACTURER.
Fire Fighting Procedures: NONE SPECIFIED BY MANUFACTURER.
Unusual Fire/Explosion Hazard: NONE
*
*
Respiratory Protection: GENERALYY NOT REQUIRED.
Ventilation: LOCAL EXHAUST.
Other Protective Equipment: RUBBER BOOTS SHOULD BE WORN IF WORKING IN STANDING
CONDITIONS.
Work Hygienic Practices: WASH HANDS AFTER USE AND BEFORE EATING, DRINKING, OR
SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health: NONE
*
Physical/Chemical Properties
*
HCC: B3
Decomp Text: UNKNOWN
Evaporation Rate & Reference: 1 (WATER=1)
Solubility in Water: COMPLETE
Appearance and Odor: CLEAR, THIN, BLUE LIQUID; NO ODOR
Corrosion Rate: UNKNOWN
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NONE
Materials To Avoid: ACIDS AND OXIDIZERS.
Hazardous Decomposition Products: CARBON OXIDES AND AMINES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
Transportation Information
*
AF MMAC Code: NR
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: DR
Container QTY: 0
*
Detail DOT Information
*
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail IMO Information
*
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
*
Detail IATA Information
*
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail AFI Information
*
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
HAZCOM Label
*
Company Name: BEACH CHEMICAL AND PAPER PRODUCTS
Label Required IND: Y
Status Code: C
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: CAUTION
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
RECONTAINERIZE BY MOPPINGM, WET VACUUM OR SUITABLE ABSORBENT. RINSE REMAINING
MATERIAL TO DRAINS. BE CAUTIOUS OF SLIPPERY FLOOR. FIRST AID: IF EYES: FLUSH
WASH WITH WATER AND APPLY EMOLLIENT CREME. IF IRRITATION PERSISTS GET MEDICAL
AID. IF INGESTED: DO NOT INDUCE VOMITING. GIVE MILK OR WATER. GET IMMEDIATE
MEDICAL ATTENTION.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE USUALLY NECESSARY UNDER MOST INDUSTRIAL
OPERATING CONDITIONS.
Ventilation:GOOD GENERAL VENTILATION USUALLY ADEQUATE.
Other Protective Equipment:CLEAN LONG SLEEVES LONG LEG CLOTHING.
Supplemental Safety and Health
* Product Identification *
CAGE:BFGAD
CAGE:BFGAD
* Composition/Information on Ingredients *
Ingred Name:2,2-BIS(4-(2,3-EPOXYPROPYLOXY)PHENYL)PROPANE, BISPHENOL A
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: MINOR IRRITATION. SKIN: MAY
DEVELOPE ALLERIC REACTION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES/SKIN: MINOR IRRITATION. SKIN: MAY DEVELOPE
ALLERGIC REACTION. INHALATION: NONE LIKELY UNLESS HEATED TO HIGH
TEMPERATURE.
Medical Cond Aggravated by Exposure:SKIN ALLERGIES
* First Aid Measures *
First Aid:EYES: FLUSH WITH WATER. SEE A PHYSICIAN IF IRRITATION
DEVELOPS. SKIN: WASH WITH SOAP & WATER. REMOVE AND WASH
CONTAMINATED CLOTHING. SEE A PHYSICIAN IF IRRITATION DEVELOPS.
INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Extinguishing Media:WATER, CO2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:DO NOT ENTER CONFINED FIRE SPACE W/PROPER
PROTECTIVE EQUIPMENT INCLUDING NIOSH APPROVED SCBA.
Unusual Fire/Explosion Hazard:TOXIC FUMES POSSIBLE.
* Accidental Release Measures *
Spill Release Procedures:AVOID EYE AND SKIN CONTACT. ABSORB WITH INERT
ABSORBANT, AND DISCARD.
*Handling and Storage *
Handling and Storage Precautions:AVOID EYE & SKIN CONTACT. KEEP OUT OF
THE REACH OF CHILDREN. STORE IN A COOL DRY PLACE AWAY FROM HEAT.
Other Precautions:EMPTY CONTAINERS MAY HAZARDOUS & ALL PRECAUTIONS
CITIED SHOULD BE OBSERVED.
* Physical/Chemical Properties *
HCC:N1
Vapor Density:>AIR
Spec Gravity:>1
Appearance and Odor:VISCOUS LIQUID EPOXY ODOR.
Percent Volatiles by Volume:0.0%
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACID, BASE
Stability Condition to Avoid:AMINE COMPOUNDS IN UNCONTROLLED
CONDITIONS.
Hazardous Decomposition Products:CO2, CO
* Disposal Considerations *
Waste Disposal Methods:THIS MATERIAL IF DISCARD MAY BE HAZARDOUS AS
DEFINED BY GOVERNMENT REGULATIONS & THEREFORE MAY BE SUBJECT TO
STORAGE, TRANSPORATION, AND DISPOSAL REQUIREMENTS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SEEK PROFESSIONAL ADVICE PRIOR TO RESP SELECTION
NIOSH APPRVD RESP. SELECT RESP BASED ON ITS SUITABILITY TO PROVIDE
ADEQ WORKER PROT FOR GIVEN WORKING CNDTNS, LEVEL OF (SUPDAT)
Ventilation:PROVIDE GEN/LOC EXHST VENT SYS TO MAINTAIN AIRBORNE CONCS
BELOW OSHA PEL'S. LOC EXHST VENT IS PREF BECAUSE IT (SUPDAT)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . WEAR LONG SLEEVE SHIRT & LONG PANTS.
Work Hygienic Practices:PRACTICE GOOD PERSONAL HYGIENE AFTER USING THIS
MATL, ESP BEFORE EATING, DRINKING, SMOKING, USING TOILET OR (SUPP
DATA)
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:GAL ROOF COATING. VENT:PREVENTS CONTAM
DISPERSION INTO WORK AREA BY CONTROLLING IT AT ITS SOURCE. HYGIENE
PRACT: APPLYING COSMETICS. RESP PROT:AIRBORNE CONTAM & PRESENCE OF
SU FFICIENT OXYG. FOR EMER/NONROUTINE OPERATIONS (CLEANING SPILLS,
REACTOR VESSELS/STOR TANKS), WEAR NIOSH APPRVD (ING 6)
* Product Identification *
CAGE:0GJN0
CAGE:0GJN0
* Composition/Information on Ingredients *
Ingred Name:SOLVENT COMPOSITION (CONSISTING OF INGS 3 & 4). FL
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:PARAFFINS
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:AROMATICS
Fraction by Wt: 7.5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPP DTA:SCBA. WARNING! AIR-PURIFYING RESPS DO NOT PROT
WORKERS IN OXYG-DEFICIENT ATMS. IF RESPS ARE USED, OSHA (ING 7)
Ingred Name:ING 6:REQUIRES A WRITTEN RESPIRATORY PROTECTION PROGRAM
THAT INCLUDES AT LST: MED CERTIFICATION, TRAINING, FIT- (ING 8)
Ingred Name:ING 7:TESTING, PERIODIC ENVIRON MONITORING, MAINT,
INSPECTION, CLEANING & CONVENIENT, SANITARY STORAGE AREAS.
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN:MAY CAUSE IRRITATION.
INGESTION:MAY BE HARMFUL OR FATAL IF SWALLOWED.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF
W/SOAP & WATER. INGEST:DO NOT INDUCE VOMITING. GET IMMEDIATE
MEDICAL ATT ENTION. AFTER FIRST AID, GET APPROPRIATE IN-PLANT,
PARAMEDIC OR COMMUNITY MEDICAL SUPPORT.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1.1% V/V
Upper Limits:6.4% V/V
Extinguishing Media:CO*2, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . DO NOT ENTER FIRE AREA W/OUT PROPER PROTECTIVE
EQUIPMENT.
Unusual Fire/Explosion Hazard:HANDLE AS A COMBUSTIBLE PRODUCT.
* Accidental Release Measures *
Spill Release Procedures:EXTINGUISH ALL SOURCES OF IGNITION IN VICINITY
OF SPILL. CLEAN UP SPILLS AS SOON AS POSSIBLE. SCOOP LARGE SPILLS
INTO PROPER DISPOSABLE CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, WELL VENTILATED AREA
AWAY FROM SOURCES OF IGNITION.
Other Precautions:NEVER EAT, DRINK OR SMOKE IN WORK AREAS.
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:SEE ING 1
Vapor Density:4.9
Spec Gravity:1.3 (H*2O=1)
Solubility in Water:NIL
Appearance and Odor:THICK VISCOSITY FIBROUS MATERIAL, WHITE W/MILD
AROMATIC ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
MAY REACT W/STRONG OXIDIZING MATERIALS.
Stability Condition to Avoid:STABLE AT ROOM TEMPERATURE IN CLOSED
CONTAINERS UNDER NORMAL STORAGE & HANDLING CONDITIONS.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:FOLLOW APPLICABLE FEDERAL, STATE & LOCAL
REGULATIONS.
* Other Information *
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* Exposure Controls/Personal Protection *
Respiratory Protection:IF MERDCURY SPILLAGE AND PEL IS EXCEEDED.
RESPIRATORY PROTECTION SHOULD BE NIOSH-NESA CERTIFIED.
Ventilation:FOR MERCURY TO KEEP CONCENTRATIONS UNDER PEL. LOCAL
MECHANICAL EXHAUST.
Other Protective Equipment:TIGHTLY WOVEN(I.E. TYVEK) WORK CLOTHING
FITTING CLOSELY ABOUT NECK, WRISTS AND ANKLES SHOULD BE WORN.
CLOTHING SHOULD BE REMOVED AND WASHED FREQUENTLY.
Work Hygienic Practices:NO FOOD, FOOD STUFF, OR TOBACCO PRODUCTS SHOULD
BE PRESENT IN MERCURY AREA. NO SMOKING OR EATING IN MERCURY AREAS.
Supplemental Safety and Health
* Product Identification *
Product ID:MERCURY IN GLASS THERMOMETER
* Composition/Information on Ingredients *
Ingred Name:MERCURY
OSHA PEL:see Table Z-2
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: SKIN, EYES, RESPIRATORY
SYSTEM, CENTRAL NERVOUS SYSTEM, KIDNEYS, LIVER. ACUTE: INHALATION
OF HIGH LEVELS OF MERCURY CAN LEAD TO SEVERE RESPIRATORY
IRRITATION, BREATHING DIFFICULTIES WHI CH CAN BE FATAL IF
RESPIRATORY IRRITATION IS SEVERE. DAMAGE TO THE TARGET ORGANS CAN
OCCUR. THESE SYMPTOMS MAY ALSO BE ACCOMPANIED BY SOME OR ALL
SYMPTOMS OF CHRONIC POISONING. CHRONIC: EXPOSURE TO LO W LEVELS OF
MERCURY VAPOR MAY RESULT IN GUM & MOUTH INFLAMMATION, GINGIVITIS,
IRRITABILITY, TREMORS, DEPRESSION, PERSONALITY CHANGES &
NERVOUSNESS, STOMATITIS. CHRONIC EFFECTS OF OVEREXPOSURE CAN RESU
LT IN DAMAGE TO THE TARGET ORGANS.
Explanation of Carcinogenicity:MERCURY IS NOT LISTED AS A CARCINOGEN BY
THE NTP, IARC OR OSHA. MERCURY IS A CUMULATIVE POISON THAT
CONCENTRATES IN THE BRAIN, KIDNEYS & LIVER. IT IS VERY HAZARDOUS
WHEN SPILLED OR HEATED.
Effects of Overexposure:INHALATION: CHEST PAIN, COUGHING. INGESTION:
SALIVATION AND METALLIC TASTE.
Medical Cond Aggravated by Exposure:PERSONS WITH CHRONIC DISEASES SUCH
AS TUBERCULOSIS, KIDNEY DISEASE, LIVER DISEASE AND ALCOHOLISM OR
ARE IN POOR PHYSICAL CONDITION SHOULD BE EXCLUDED FROM CONTINUOUS
ASSIGNMENT WHERE MERCURY IS PRESENT.
* First Aid Measures *
First Aid:INHALATION-REMOVE PERSON FROM SOURCE OF EXPOSURE TO FRESH
AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. EYES-OCCASIONAL ACCIDENTAL CONTACT WITH
EYES IS US UALLY HARMLESS IF WASHED OUT IMMEDIATELY. HOLD UPPER &
MIN. CONSULT A PHYSICIAN. SKIN-WASH EXPOSED AREA THOROUGHLY WITH
SOAP & WATER . CAN PENETRATE UNDAMAGED SKIN WITH SUBSEQUENT
ABSORPTION BY CIRCULATORY SYSTEM. INGESTION-ACCIDENTAL SWALLOWING
OR INGESTION OF MERCURY IS USUALLY HARMLESS. DO NOT INDUCE
VOMITING. CONSULT A PHYSICIA N.
* Fire Fighting Measures *
Extinguishing Media:APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:AT HIGH TEMPERATURES MERCURY VAPORIZES RAPIDLY
TO FORM HIGHLY TOXIC, ODORLESS, COLORLESS FUMES. USE AIR LINE OR
SELF CONTAINED BREATHING APPRARATUSES WITH FULL FACE PIECES
OPERATED IN POSITIVE PRESSUR E MODE ONLY.
Unusual Fire/Explosion Hazard:MERCURY IS NOT COMBUSTIBLE, FLAMMABLE, OR
EXPLOSIVE, BUT WILL EVAPORATE WHEN HEATED CREATING TOXIC FUMES
WHICH ARE BOTH ODORLESS AND COLORLESS. WILL COMBINE WITH OTHER
COMPOUNDS(I.E. AMMONIA) TO CREAT E UNSTABLE COMPOUNDS.
* Accidental Release Measures *
Spill Release Procedures:USE APPROPIATE RESPIRATORY PROTECTION IF PEL
IS EXCEEDED AND PROPER PROTECTIVE CLOTHING. CLEAN UP SPILLS
IMMEDIATELY WITH VACUUM EQUIPMENT THAT HAS A FILTERED EXHAUST. DO
NOT DRY SWEEP. DECONTAMINATE WITH A MERCURY DECONTAMINANT. KEEP
COLLECTED MERCURY IN A SEALED CONTAINER FOR DISPOSAL. AVOID SKIN
CONTACT WITH MERCURY. WASH CONTACTED AREA WITH SOAP AND WATER.
*Handling and Storage *
Handling and Storage Precautions:HANDLE AND STORE THERMOMETER WITH
PROPER CARE.
* Physical/Chemical Properties *
HCC:Z2
Evaporation Rate & Reference:DEPENDS ON TEMP AND PRESS
Appearance and Odor:SILVER METALLIC LIQUID, MOBILE AND ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
HALOGENS, NITRIC ACID, AMMONIA GAS, ALUMINUM, ACETYLENE AND ACCTYLENO
PRODUCTS, BORON PHOSPHODIADINE, CHLORINE, CHLORINE DIOXIDE, METHYL
AZIDE, SODIUM CARBIDE, OLEUM, SULFURIC ACID. MERCURY WILL READILY
FORM ANALGAMS WITH G
Stability Condition to Avoid:HEAT AND HIGH TEMPERATURES.
Hazardous Decomposition Products:MERCURY VAPORS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Toxicological Information*
Toxicological Information:THERMOMETER CONTAINS APPROXIMATELY 0.5 CC OF
MERCURY. HAZARDOUS ONLY IF BROKEN.
* Disposal Considerations *
Waste Disposal Methods:REMOVE MERCURY AND MATERIALS THAT HAVE COME IN
CONTACT WITH MERCURY TO PROPER DISPOSAL AREA. MERCURY IS
RECYCLABLE. DO NOT PUT INRO GARBAGE, FLUSH TO SEWER, OR INCINERATE.
DISPOSE OF IN ACCORDANCE WIT H ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS. DO NOT DISPOSE IN LANDFILL.
* MSDS Transport Information *
SHIPPING NAME: MERCURY, METAL. DOT LABEL: NONE. DOT HAZARD CLASS:
* Regulatory Information *
SARA Title III Information:REPORTABLE QUANTITY (RQ): 1 POUND. THE
REQUIRES THAT A RELEASE EQUAL TO OR HIGHER THAT THE REPORTABLE
QUANTITY FOR THIS SUBSTANCE BE IMM EDIATELY REPORTED TO THE LOCAL
EMERGENCY PLANNING COMMITTEE AND THE STATE EMERGENCY RESPONSE
COMMISSION.
Federal Regulatory Information:THIS SUBSTANCE IS ALSO REPORTABLE UNDER
State Regulatory Information:
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Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
% Wt: BALANCE
------------------------------
% high Wt: 5.
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: EYE: NON-IRRITATING TO THE EYES. SKIN:
NON-IRRITATING TO THE SKIN. INGESTION: NO HAZARD IS EXPECTED DURING NORMAL
USE.INHALATION: NO HAZARD EXPECTED DURING NORMAL USE. CHRONIC: NO
INFORMATION FOUND. TARGET ORGANS: NONE KNOWN.
MINUTES, SEEK ASSISTANCE FROM MD (FP N).IF IRRIT DEVELOPS , GET MED AID.
SKIN: GET MEDICAL AID IF IRRITATION DEVELOPS OR PERSISTS. INGEST ION: DO NOT
INDUCE VOMITING. GET MEDICAL AID. INHALATION: NO SPECIFIC TREATMENT IS
NECESSARY SINCE THIS MATERIAL IS NOT LIKELY TO BE HAZARDOUS BY INHALATION.
REMOVE TO FRESH AIR. SUPPORT BREATHING (GI VE O*2/ARTF RESP) (FP N). NOTES TO
PHYSICIAN: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
*
Handling and Disposal
*
Spill Release Procedures: ABSORB SPILL USING AN ABSORBENT, NON-COMBUSTIBLE
MATERIAL SUCH AS EARTH, SAND, DIATOMACEOUS EARTH, VERMICULITE, OR OTHER
SUITABLE ABSORBENT. USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN
S EC. 8.
Waste Disposal Methods: DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE,
AND LOCAL REGULATIONS.
Handling And Storage Precautions: STORE CAPPED AT ROOM TEMPERATURE.
*
Fire and Explosion Hazard Information
*
Flash Point Text: NO INFO AVAIL
Extinguishing Media: FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER
SPRAY OR ALCOHOL-RESISTANT FOAM.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NEGLIGIBLE FIRE AND EXPLOSION HAZARD WHEN
EXPOSED TO HEAT OR FLAME.
*
*
Respiratory Protection: NOT REQUIRED FOR NORMAL USE. USE NIOSH APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N).
Ventilation: GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL AIRBORNE
LEVELS.
Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N). DO NOT WEAR CONTACT LENSES WHEN WORKING WITH
CHEMICALS. PROTECTIVE COVERALLS ARE REC.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
*
Physical/Chemical Properties
*
Decomp Text: NO INFO AVAIL
Vapor Density: 0.7
Spec Gravity: /DENSITY: 1
PH: NO INFO AVAIL
Solubility in Water: SOLUBLE
Appearance and Odor: CLEAR LIQUID; SLIGHT OPALESENT, ODORLESS.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: TEMPERATURES ABOVE RECOMMENDED TEMPERATURES.
Materials To Avoid: NONE REPORTED.
Hazardous Decomposition Products: OXIDES OF NITROGEN, OXIDES OF CARBON, OXIDES
OF SODIUM.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
*
Toxicological Information
*
Toxicological Information: EPIDEMIOLOGY: DISODIUM EDTA MAY CAUSE SKIN, EYE, AND
*
Ecological Information
*
Ecological: NO INFORMATION AVAILABLE.
*
*
Transport Information: US DOT SHIPPING NAME: NO INFORMATION AVAILABLE.
*
Regulatory Information
*
ON THIS LIST. SARA REPORTABLE QUANTITIES (RQ): NONE OF THE COMPONENTS ARE ON
THIS LIST.
Federal Regulatory Information: OSHA - HIGHLY HAZARDOUS: NONE OF THE COMPONENTS
LOPMENT USE ONLY.
State Regulatory Information: US STATE: STATE RIGHT TO KNOW CALIFORNIA
REGULATIONS.
*
Other Information
*
ORIGINAL.
*
HAZCOM Label
*
Company Name: LABCHEM,INC.
Label Required IND: Y
Status Code: A
Origination Code: F
Skin Protection IND: YES
Signal Word: NONE
Respiratory Protection IND: YES
Health Hazard: None
Contact Hazard: None
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EYE: NON-IRRITATING TO THE EYES. SKIN:
NON-IRRITATING TO THE SKIN. INGESTION: NO HAZARD IS EXPECTED DURING NORMAL
USE.INHALATION: NO HAZARD EXPECTED DURING NORMAL USE. CHRONIC: NO
INFORMATION FOUND. TARGET ORGANS: NONE KNOWN.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
RESPIRATOR.
Ventilation:MECHANICAL: RECOMMENDED.
Work Hygienic Practices:WASH HANDS W/SOAP & WATER.
Supplemental Safety and Health
* Product Identification *
Product ID:PURPLE K POTASSIUM BICARBONATE BASE DRY CHEMICAL
* Composition/Information on Ingredients *
Ingred Name:MICA - SILICATES (< 1% CRYSTALLINE SILICA)
Fraction by Wt: <5%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: TRANSIENT COUGH,
IRRITATION OF AIRWAYS, SHORTNESS OF BREATH, & PNEUMOCONIOSIS.
SKIN/EYES: IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: TRANSIENT COUGH, IRRITATION OF
AIRWAYS, SHORTNESS OF BREATH, & PNEUMOCONIOSIS. SKIN/EYES:
IRRITATION.
Medical Cond Aggravated by Exposure:ASTHMA, BRONCHITIS, OR OTHER
RESPIRATORY DISEASES
* First Aid Measures *
First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/LARGE AMOUNTS OF
AS A MINERAL DUST. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point:NON-COMBUSTIBLE
Extinguishing Media:THIS MATERIAL IS A FIRE EXTINGUISHING AGENT.
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP. STORE IN COVERED CONTAINERS. DON'T
REUSE.
*Handling and Storage *
Handling and Storage Precautions:STORE IN ORIGINAL COVERED CONTAINER OR
IN SEALED FIRE EXTINGUISHERS. DON'T MIX W/DIFFERENT TYPES OF DRY
CHEMICAL EXTINGUISHING AGENTS. DON'T REUSE.
Other Precautions:AVOID INHALATION OF DUST.
* Physical/Chemical Properties *
Solubility in Water:SLIGHT
Appearance and Odor:FINE LIGHT PURPLE POWDER W/NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OTHER DRY CHEMICAL EXTINGUISHING AGENTS
Hazardous Decomposition Products:CO2
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS FOR AN INERT NON-METALLIC POWDER.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR A PROPERLY FITTED VAPOR/PARTICULATE
CONFINED SPACES, WEAR A POSITIVE PRESSURE, SUPPLIED AIR RESPIRATOR
Ventilation:SUFFICIENT IN VOLUME & PATTERN TO KEEP CONTAMINANTS <
APPLICABLE OSHA LIMITS.
Other Protective Equipment:COVERALLS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE
EATING/SMOKING.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:T R LOUER
* Composition/Information on Ingredients *
Ingred Name:P-TERY-BUTYLBENZOIC ACID, PENTAERYTHRITOL, PHTHALIC
ANHYDRIDE, SOYBEAN OIL POLYMER
Ingred Name:LINSEED OIL, POLYMER WITH CONJUGATED SAFFLOWER OIL,
GLYCEROL, ISOPHTHALIC ACID, ALKYD RESIN C
Ingred Name:ALKYD RESIN G
Ingred Name:SOLVENT NAPHTHA, PETROLEUM, LIGHT AROMATIC, HIGH FLASH
Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL
Fraction by Wt: 5%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE NOSE & THROAT
IRRITATION. EYES: MAY CAUSE IRRITATION/BURNING. SKIN: IRRITATION &
DERMATITIS. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE
PERMANENT BRAIN & NERVOUS SYSTE M DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:GI DISTRESS, IRRITATION, EYE WATERING,
HEADACHES, NAUSEA, DIZZINESS, LOSS OF COORDINATION, BURNING,
DISCOMFORT.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: IMMEDIATELY FLUSH
MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:CC
Lower Limits:0.8
Extinguishing Media:WATER SPRAY, FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT & SCBA. WATER
FROM FOG NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS.
Unusual Fire/Explosion Hazard:WHEN HEATED > THE FLASH POINT, EMITS
FLAMMABLE VAPORS WHEN MIXED W/AIR, CAN BURN/BE EXPLOSIVE. FINE
MISTS/SPRAYS MAY BE FLAMMABLE AT TEMPS < THE FLASH POINT.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION.
PREVENT SKIN CONTACT & BREATHING OF VAPOR. WEAR A PROPERTY FITTED
W/INERT ABSORBENT.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, FLAME.
CLOSE CONTAINER AFTER EACH USE. GROUND CONTAINERS WHEN POURING.
Other Precautions:OBSERVE LABEL PRECAUTIONS. DON'T SAND, FLAME CUT,
BRAZE/WELD DRY COATING W/O A NIOSH/MSHA APPROVED
RESPIRATOR/APPROPRIATE VENTILATION. DON'T PERMIT ANYONE W/O
PROTECTION IN THE PAINTING AREA. DON'T BR EATHE VAPORS/MISTS.
* Physical/Chemical Properties *
Vapor Density:>1
VOC Grams/Liter:4.2
Evaporation Rate & Reference:LESS THAN ETHER
Solubility in Water:MISCIBLE
Percent Volatiles by Volume:(SUPP)
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORSEEABLE.
Hazardous Decomposition Products:CO, CO2, SMOKE.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE/DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. DON'T ALLOW MATERIAL TO CONTAMINATE GROUND WATER
SYSTEMS. DON'T INCINERATE IN CLOSED CONTAINERS. FLAMMABLE LIQUID
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR WHEN AIRBORNE DUST
CONCENTRATIONS >PEL/TLV.
Ventilation:SUFFICIENT GENERAL & LOCAL EXHAUST TO KEEP <PEL/TLV
Other Protective Equipment:EYEWASH FOUNTAIN
Work Hygienic Practices:MAINTAIN GOOD HOUSEKEEPING TECHNIQUES SUCH AS
WET SWEEPING OR VACUUMING TO REMOVE DUST ACCUMULATION
Supplemental Safety and Health
* Product Identification *
CAGE:WESGO
CAGE:WESGO
* Composition/Information on Ingredients *
Ingred Name:SILVER
ACGIH TLV:0.1 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ALUMINUM (POWDER)
Fraction by Wt: 5%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION/DISCOLORATION. SKIN:
IRRITATION/ALLERGIC REACTION/RASH/DERMATITIS/DISCOLORATION.
INHALATION: NOSE/THROAT IRRITATION/SENSITIZED RESPIRATORY
DISEASE/COUGH/SHORTNESS OF BREATH/NERVOUS SY STEM
EFFECTS/WALKING/BALANCING DIFFICULTY/WEAKNESS/CRAMPS IN
LEGS/HOARSENSS OF VOICE/MEMORY/JUDGMENT TROUBLE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: BENIGN PNEUMOCONIOSIS CALLED
STANNOSIS, MUCOUS MEMBRANE DISCOLORATION, UNSTABLE EMOTIONS,
PNEUMONIA-LIKE ILLNESS. COPPER MAY PRODUCE KERATINIZATION OF
HANDS/SOLES OF FEET. COBALT MAY PRODU CE PERMANENT DISABILITY OR
DEATH. BORONMAY PRODUCE SHOCK/COMA. TITANIUM MAY PRODUCE LUNG
FIBROSIS/CHRONIC BRONCHITIS.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. SUPPORT RESPIRATION AS
NEEDED. SKIN: WASH W/MILD DETERGENT & WATER. EYES: FLUSH W/WATER
CASES.
* Fire Fighting Measures *
Extinguishing Media:DON'T USE WATER USE DRY CHEMICAL, SAND OR OTHER
APPROPRIATE EXTINGUISHING AGENT FOR SURROUNDING FIRE
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:MAY OCCUR W/CERTAIN METAL DUST FIRES.
* Accidental Release Measures *
Spill Release Procedures:USE NORMAL CLEAN-UP PROCEDURES USING WET
SWEEPING OR VACUUM, TAKING CARE TO AVOID EXCESSIVE DUSTING.
*Handling and Storage *
Other Precautions:AVOID DUST INHALATION & CONTACT OF MATERIALS W/EYES.
* Physical/Chemical Properties *
Spec Gravity:6-9
Solubility in Water:INSOLUBLE
Appearance and Odor:SOLID METAL OR POWDER W/NO ODOR
Percent Volatiles by Volume:0%
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS, STRONG OXIDIZERS, STRONG BASES, & MOISTURE
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SHOULD BE REQUIRED.
Ventilation:MECHANICAL (GEN) RECOMMENDED.
Other Protective Equipment:NONE
Supplemental Safety and Health
KEY1:ZO1;ITEM IS 9 PARTS KIT;IT CONSISTS OF DEVL(PART A&B),BLEACH(PART
A&B),FIRST DEVL,FIXER CONDITIONER,REVERSAL
NAME&CAT#;SEE PNI J THRU O FOR NEW KIT;THIS IS:FIXER IN 1 PINT
KIT.KEY:C3
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Fraction by Wt: 7.5%
Ingred Name:SODIUM BISULFITE (SASA III)
OSHA PEL:5 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Effects of Overexposure:SKIN & EYE IRRITATION.
* First Aid Measures *
WASH SKIN W/SOAP & WATER. GET MED ATTN IF ALLERGIC REACTION
DEVELOPS.
* Fire Fighting Measures *
Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:NONE
Extinguishing Media:USE AGENT APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN & EYES.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:FLUSH MATERIAL TO SEWER W/LARGE AMOUNTS OF
WATER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED WHEN NOT
IN USE.
Other Precautions:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR
SMOKING.
* Physical/Chemical Properties *
HCC:C1
Vapor Density:0.6
pH:6.2
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, SLIGHTLY YELLOW LIQUID. NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID MINERAL ACIDS.
Stability Condition to Avoid:EXPOSURE TO HIGH HEAT/TEMPERATURE.
Hazardous Decomposition Products:SULFUR DIOXIDE
* Disposal Considerations *
Waste Disposal Methods:DISPOSE I/A/W ALL LOCAL, STATE & FEDERAL
REGULATIONS WHERE APPLICABLE.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF TLV IS EXCEEDED, WEAR NIOSH-APPROVED ORGANIC
VAPOR RESPIRATOR OR AIR-PURIFYING RESPIRATOR. IN EMERGENCY, WEAR A
NIOSH-APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREATHING
APPARATUS.
Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWERS SHOULD BE
AVAILABLE IN THE IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE.
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING,
DRINKING/SMOKING.
Supplemental Safety and Health
EXTREMELY FLAMMABLE. CONTENTS UNDER PRESSURE. CONTAINS FLAMMABLE GAS
SUCH AS PROPANE AND FLAMMABLE LIQUID. DO NOT USE IN CONFINED AREA
OR AREA WITH LITTLE AIR MOVEMENT. EMPLOY MEANS TO PREVENT VAPOR B
UILDUP.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ISOBUTANE
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
Ingred Name:ISOHEXANE
Other REC Limits:NONE RECOMMENDED
Ingred Name:PROPANE
Other REC Limits:NONE RECOMMENDED
Ingred Name:ACRYLATE POLYMER
Other REC Limits:NONE RECOMMENDED
Ingred Name:3-METHYL PENTANE
Other REC Limits:NONE RECOMMENDED
Ingred Name:2,3-DIMETHYLBUTANE
Other REC Limits:NONE RECOMMENDED
Ingred Name:NEOHEXANE/2,2-DIMETHYLBUTANE
Other REC Limits:NONE RECOMMENDED
Ingred Name:HEXANE (N-HEXANE) (CERCLA)
Fraction by Wt: 0.1 - 1%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, CNS, LUNGS.
ACUTE- INHALATION OF VAPORS MAY CAUSE CNS DEPRESSION. MAY CAUSE
IRRITATION OF EYES, SKIN & RESPIRATORY TRACT. MAY CAUSE SKIN
DEFATTING. HARMFUL/FATAL IF SWALLOWED . CAN BE ABSORBED THROUGH
SKIN IN HARMFUL AMOUNTS. CHRONIC- OVEREXPOSURE MAY CAUSE
DERMATITIS, CNS DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHE, DIFFICULTY IN BREATHING,
NAUSEA, VOMITING, DEFATTING, DIZZINESS, LOSS OF COORDINATION,
FATIGUE, CONFUSION, DERMATITIS, BLURRED VISION, TEARING
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING
DISEASES OF THE EYE, SKIN, RESPIRATORY TRACT, CNS MAY HAVE
INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES.
* First Aid Measures *
First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH
MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO
NOT IN DUCE VOMITING. IF CONSCIOUS, DRINK 2 GLASSES OF WATER. SEEK
IMMEDIATE MEDICAL ATTENTION. IF SPONTANEOUS VOMITING OCCURS, KEEP
HEAD BELOW HIPS TO PREVENT ASPIRATION OF VOMITUS INTO LUNGS.
* Fire Fighting Measures *
Flash Point:FLAMMABL AEROSOL
Lower Limits:1.2
Upper Limits:7.7
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM. COOL
FIRE-EXPOSED CONTAINERS WITH WATER SPRAY.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING, INCLUDING
HELMET AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH
FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:SPRAY CANS UNDER PRESSURE. EXTREMELY
FLAMMABLE. EXPLOSION HAZARD EXISTS WHEN SPRAY CANS HEATED. DO NOT
ENTER SPRAY CAN STORAGE AREA IF FIRE PRESENT.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA. REMOVE IGNITION SOURCES.
LEAKING CONTAINERS SHOULD BE PLACED OUTDOORS, IN AN OPEN CONTAINER,
AWAY FROM SOURCES OF IGNITION. ALLOW PRESSURE TO DISSIPATE. ABSORB
LIQUID WITH NON-FLAMMABL E ABSORBENT AND PLACE IN CONTAINER FOR
DISPOSAL.
Neutralizing Agent:NOT RELEVANT
*Handling and Storage *
Handling and Storage Precautions:STORE SPRAY CANS IN COOL, WELL
VENTILATED AREAS AWAY FROM SOURCES OF IGNITION & SUNLIGHT. DO NOT
Other Precautions:"EMPTY" CONTAINERS RETAIN RESIDUE AND MAY BE
DANGEROUS. FOLLOW ALL LABEL INSTRUCTIONS. AVOID REPEATED/PROLONGED
SKIN CONTACT. KEEP OUT OF REACH OF CHILDREN. DO NOT BREATHE VAPORS.
DO NOT SPRAY TOWARD FACE/HOT SURFACES. WASH AFTER HANDLING.
* Physical/Chemical Properties *
HCC:V3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:COMPRES.GAS
Vapor Density:>1
Viscosity:NOT KNOWN
Evaporation Rate & Reference:COMPRESSED GAS
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIQUID IN AEROSOL CONTAINER, TRANSPARENT, MILD
SOLVENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES, DIRECT SUNLIGHT,
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, TOXIC
VAPORS, GASES OR PARTICULTES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS. DO NOT PUNCTURE, INCINERATE SPRAY CANS
EVEN AFTER USE. DO NOT FLUSH INTO DRAINS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:USE MECHANICAL EXHAUST.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:MINERAL OIL, WHITE; (WHITE MINERAL OIL MIXTURE) CONTAINS
ING 2 PRESENT AS AN ORGANO METALLIC SALT
Other REC Limits:5MG/M3 OIL MIST(MFR)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SODIUM
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY PRODUCE SLIGHT TRANSITORY EYE
IRRITATION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
* First Aid Measures *
OCCURS AND PERSISTS, OBTAIN MEDICAL ATTENTION. SKIN: FLUSH WITH
WATER; IF IRRITATION OCCURS AND PERSISTS, OBTAIN MEDICAL ATTENTION.
INHAL: REMOVE TO FRESH AIR. INGEST: OBTAIN MEDICAL ATTENTION.
* Fire Fighting Measures *
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . WATER-SPRAY SHOULD BE USED WITH CAUTION TO
PREVENT SPREAD OF FLAMES.
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:ABSORB WITH INERT MATERIAL SUCH AS SAND,
EARTH/VERMICULITE.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL DRY AREA, KEEP CONTAINER
COVERED. AVOID INHALATION. AVOID CONTACT W/EYES. USE IN WELL
VENTILATED AREA.
Other Precautions:
* Physical/Chemical Properties *
HCC:N1
Spec Gravity:<1(H2O=1)
Appearance and Odor:CLEAR COLORLESS VISCOUS LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:UPON COMBUSTION, CO2 AND CO ARE
GENERATED.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE I/A/W STATE, FEDERAL AND LOCAL EPA
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:THE USE OF LOCAL EXHAUST IS DESIRABLE.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . IF
PROLONGED CONTACT IS ANTICIPATED, USE BARRIER SKIN CREAM.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:PRINTING INK UL MEGA DNS BLACK
CAGE:KHLMA
CAGE:KHLMA
* Composition/Information on Ingredients *
Ingred Name:NON-HAZARDOUS INGREDIENTS
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PRODUCT MAY CAUSE SKIN AND EYE
IRRITATION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE KNOWN.
* First Aid Measures *
First Aid:EYES: FLUSH EYES THOROUGHLY WITH STERILE EYE WASH SOLUTION
PERSISTS. SKIN: WASH SKIN WITH SOAP AND WATER. SEEK MEDICAL
ATTENTION OF IRRITA TION PERSISTS. INHAL: REMOVE TO FRESH AIR IF
BREATHING IS DIFFICULT. SEEK MEDICAL ATTENTION IF DIFFICULTY
PERSISTS. INGEST: IF INGESTION OCCURS, SEEK MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point Method:SCC
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM RECOMMENDED.
APPLY WATER SPRAY TO COOL EXPOSED CONTAINERS.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . OSHA CLASS IIIB (COMBUSTIBLE).
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS.
* Accidental Release Measures *
Spill Release Procedures:CLEAN UP WITH ABSORBENT MATERIAL. TRANSFER TO
APPROPRIATE CONTAINERS FOR DISPOSAL.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:AVOID CONTACT WITH SKIN, EYE OR
CLOTHING. WASH HANDS AFTER USE. STORE IN CLOSED CONTAINERS AWAY
FROM DIRECT SOURCES OF HEAT.
Other Precautions:
* Physical/Chemical Properties *
Evaporation Rate & Reference:SLOWER THAN WATER
Solubility in Water:INSOLUBLE
Appearance and Odor:OILY ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
THIS PRODUCT IS NOT COMPATIBLE WITH WATER-BASED MATERIALS.
Stability Condition to Avoid:THIS PRODUCT IS A STABLE MIXTURE.
Hazardous Decomposition Products:DECOMPOSITION IF NOT ANTICIPATED.
NOXIOUS GASES MAY BE EVOLVED IN A FIRE.
* Disposal Considerations *
Waste Disposal Methods:THIS PRODUCT SHOULD BE DISPOSED OF IN ACCORDANCE
WITH APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. THIS PRODUCT
NOT REGULATED UNDER CERCLA (SUPERFUND).
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH-APPROVED RESPIRATOR AS REQUIRED TO
PREVENT OVER EXPOSURE.
Ventilation:IF USED IN CONFINED AREA, PROVIDE POSITIVE VENTILATION
BEFORE ENTERING THE AREA TO AVOID DEPLETION OF OXYGEN IN THE AIR.
Other Protective Equipment:EYE WASH & EMERGENCY SHOWER.
Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING. WASH THOROUGHLY
AFTER HANDLING.
Supplemental Safety and Health
WE RECOMMEND THAT ALL CHEMICALS BE STORED/USED IN LOCATIONS WHICH WILL
NOT PERMIT DIRECT ACCESS TO SANITARY OR SURFACE DRAINS. THESE AREAS
SHOULD BE CONSTRUCTED IN SUCH A MANNER THAT ANY CHEMICALS LOS T CAN
BE EITHER SALVAGED OR SUITABLY TREATED TO PREVENT POLLUTION.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:STODDARD SOLVENT
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
Ingred Name:NONANE
Ingred Name:TRIMETHYL BENZENE (SARA III)
Ingred Name:NAPHTHALENE (SARA III)
Ingred Name:DISTILLATES, PETROLEUM, CHEMICALLY NEUTRALIZED HEAVY
ACGIH TLV:5 MG/CUM
Ingred Name:HYDROCARBON RESIN, ARIEN
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES: SEVERE IRRITATION, REDNESS,
TEARING, BLURRED VISION. INHALATION: CENTRAL NERVOUS SYSTEM
DEPRESSION, UNCONSCIOUSNESS. SKIN: IRRITATION & ITCHING,
DERMATITIS.
Explanation of Carcinogenicity:UNTREATED PETROLEUM OILS HAVE PRODUCED
SKIN CANCER IN TESTS W/LABORATORY ANIMALS.
Effects of Overexposure:SKIN: REPEATED CONTACT MAY CAUSE DERMATITIS.
EYES: SEVERE IRRITATION, REDNESS, TEARING, BLURRED VISION.
INHALATION: CENTRAL NERVOUS SYSTEM DEPRESSION, UNCONSCIOUSNESS.
* First Aid Measures *
WATER. INGESTION: DON'T INDUCE VOMITING. INHALATION: REMOVE TO
FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. OBTAIN
MEDICAL ATT ENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:CO2, WATER, FOAM, HALON, DRY CHEMICAL.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA OF SPILL. REMOVE ALL IGNITION
SOURCES. DON'T PERMIT SUBSTANCE TO ENTER SEWERS OR STREAMS. ABSORB
ON NON-COMBUSTIBLE MATERIAL (VERMICULITE, SAND, EARTH) & PLACE IN A
POLYETHYLENE OR POLY ETHYLENE-LINED CONTAINER FOR DISPOSAL.
*Handling and Storage *
Handling and Storage Precautions:"EMPTY" PRODUCT CONTAINERS RETAIN
PRODUCT RESIDUE. DON'T PRESSURIZE, CUT, HEAT, WELD OR EXPOSE SUCH
CONTAINERS TO FLAME.
Other Precautions:AVOID CONTACT W/SKIN, EYES, CLOTHING. WASH THOROUGHLY
FOR INDUSTRIAL USE ONLY. KEEP AWAY FROM HEAT & OPEN
FLAMES. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. PROVIDE A
SOURCE OF RU NNING WATER NEARBY.
* Physical/Chemical Properties *
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIGHT AMBER LIQUID, PETROLEUM SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:IGNITION SOURCES, HEAT, OPEN FLAMES, &
HIGH TEMPERATURES.
Hazardous Decomposition Products:CO, CO2, UNIDENTIFIED ORGANIC
MATERIALS, TOXIC MATERIALS, VARIOUS HYDROCARBONS, ETC.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS HIGH, USE
APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR OR DUST MASK.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST TO KEEP VAPOR AND
MIST LEVELS AS LOW AS POSSIBLE.
Other Protective Equipment:WEAR UNIFORM AND APRON.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
CAGE:JVMAN
CAGE:JVMAN
* Composition/Information on Ingredients *
Ingred Name:ETHANOL, 2,2',2"-NITRILOTRI-; (TRIETHANOLAMINE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:THYMOL, 6,6'-(3H-2,1-BENZOXATHIOL-3-YLIDENE)DI-,
S,S-DIOXIDE; (THYMOL BLUE)
Fraction by Wt: <1%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:WATER
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: CONTACT WITH SKIN OR EYES MAY
CAUSE IRRITATION. INGESTION MAY CAUSE NAUSEA AND VOMITING.
INGESTION MAY CAUSE IRRITATION AND BURNING TO MOUTH AND STOMACH.
CHRONIC: KIDNEYS AND/OR LIVER DAMAGE.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
MEDICAL ATTENTION.
* Fire Fighting Measures *
Extinguishing Media:USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:TOXIC GASES PRODUCED: NITROGEN OXIDES,
AMMONIA, CARBON DIOXIDE, SULFUR DIOXIDE.
* Accidental Release Measures *
Spill Release Procedures:WEAR SCBA AND FULL PROTECTIVE CLOTHING. STOP
LEAK IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE
VAPOR. TAKE UP WITH NON-COMBUSTIBLE SORBENT MATERIAL AND PLACE IN
CONTAINER FOR LATER DISPOSA L. FLUSH SPILL AREA WITH WATER.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED.
SUITABLE FOR ANY GENERAL CHEMICAL STORAGE AREA. STORE IN LIGHT
RESISTANT CONTAINER.
Other Precautions:
* Physical/Chemical Properties *
Spec Gravity:N/A (H*2O=1)
pH:2.5
Evaporation Rate & Reference:N/A (BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:RED LIQUID WITH SLIGHT AMMONIACAL ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
COPPER, STRONG OXIDIZERS.
Stability Condition to Avoid:AIR, LIGHT, HEAT.
Hazardous Decomposition Products:OXIDES OF NITROGEN, AMMONIA, CARBON
DIOXIDE, CARBON MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . USE
APPROPRIATE OSHA/MSHA APPROVED SAFETY EQUIPMENT.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN IN THE
LABORATORY.
Supplemental Safety and Health
FIRST AID PROC: ADMIN ARTF RESP. IF IN CARD ARREST ADMIN CPR. CONTINUE
LIFE SUPPORTING MEASURES UNTIL MED ASSISTANCE HAS ARRIVED. INGEST:
CALL MD IMMED .
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:CYCLOHEXANE, METHYL-; (4-METHYLCYCLOHEXENE (MFR CAS
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ALL CHEMICALS SHOULD BE CONSIDERED
HAZARDOUS - AVOID DIRECT PHYSICAL CONTACT! CAN CAUSE SKIN
IRRITATION. CAN CAUSE EYE IRRITATION. CAN BE HARMFUL IF ABSORBED
THROUGH THE SKIN. CAN BE HARMFUL IF INHALE D. CAN BE HARMFUL IF
SWALLOWED. CAN BE IRRITATING TO MUCOUS MEMBRANES.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:ANTIDOTE IS SUBSTANCE INTENDED TO COUNTERACT EFT OF POISON.
IT SHOULD BE ADMIN ONLY BY MD/TRAINED EMER PERS. MED ADVICE CAN BE
OBTAINED FROM POIS CTL CTR. EYES:FLUSH CONTINUOUSLY W/WATER FOR AT
HAVE OCCURRED-USE SOAP & WATER TO CLEANSE SKIN. INHAL: REMOVE TO
FRESH AIR. ADMIN OXYGEN IF HAVING DFCLTY BRTHG. IF BRTHG HAS
STOPPED (SUPDAT)
* Fire Fighting Measures *
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THIS IS A FLAMMABLE CHEMICAL.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE AREA. WEAR APPROPRIATE OSHA-REGULATED
EQUIPMENT. VENTILATE AREA. ABSORB ON VERMICULITE OR SIMILAR
MATERIAL. SWEEP UP AND PLACE IN AN APPROPRIATE CONTAINER. HOLD FOR
DISPOSAL. WASH CONTAMINATE D SURFACES TO REMOVE ANY RESIDUES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. KEEP TIGHTLY CLOSED AND STORE IN A COOL, DRY PLACE. STORE
ONLY WITH COMPATIBLE CHEMICALS.
Other Precautions:PERSONS NOT SPECIFICALLY & PROPERLY TRAINED SHOULD
NOT HANDLE THIS CHEM OR ITS CNTNR. THIS PROD IS FURNISHED FOR LAB
USE ONLY! PRODS MAY NOT BE USED AS DRUGS, COSMETICS,
AGRICULTURAL/PESTICIDAL PRODS, FOOD ADDITIVES OR AS HOUSEHOLD
CHEMS.
* Physical/Chemical Properties *
Solubility in Water:INSOL (IMMISCIBLE)
Appearance and Odor:COLORLESS LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:EASILY OXIDIZED-MAY BE A PEROXIDE
FORMER-CHECK FOR PEROXIDES ON ALL OPENED SAMPLES. FLAMMABLE.
Hazardous Decomposition Products:DECOMPOSITION LIBERATES TOXIC FUMES.
DECOMPOSITION PRODUCTS ARE CORROSIVE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS . BURN IN A CHEMICAL INCINERATOR
EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:MFR STATES "NONE WHEN USED AS INTENDED" HMIS
SUGGESTS NIOSH APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE
WHEN TLV IS EXCEEDED. (SPILLS ETC.)
Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV
Other Protective Equipment:NONE
Work Hygienic Practices:NORMAL PERSONAL HYGIENE PRACTICES ARE
SATISFACTORY
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ISOPARAFFINIC PETROLEUM SOLVENT (PETROLEUM NAPHTHA)
Ingred Name:POLYMER (CLAIMED AS TRADE SECRET)
Ingred Name:PIGMENT (CONTAINS CARBON BLACK)(CLAIMED AS TRADE SECRET)
OSHA PEL:3.5 MG/CUM CARBON BK
ACGIH TLV:3.5 MG/CUM CARBON BK
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MATERIAL IS LISTED BY MFR AS "WHEN
USED AS INTENDED, IT DOES NOT REPRESENT A HEALTH HAZARD". TOXICITY
WILL RESULT FROM ACCIDENT OR MISUSE.
Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION. INHALE:
ABNORMAL HEART RHYTHMS, RESPIRATORY ARREST, CENTRAL NERVOUS SYSTEM
TOXICITY. INGEST: CENTRAL NERVOUS SYSTEM DEPRESSION, RESPIRATORY
DISTRESS BY ASPIRATION
Medical Cond Aggravated by Exposure:NONE
* First Aid Measures *
First Aid:EYES:FLUSH WITH WATER. SKIN: REMOVE CONTAMINATED CLOTHING,
WASH WITH SOAP AND WATER. INHALE:REMOVE TO FRESH AIR, GIVE OXYGEN
OR CPR AS NEEDED. INGEST:DILUTE STOMACH CONTENTS BY DRINKING WATER.
DO NOT INDUCE VOMITING. CONTACT A PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:0.8%
Upper Limits:7.0%
Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE, WATER FOG
CONTR.
Unusual Fire/Explosion Hazard:NONE LISTED BY MFR. HMIS: VAPORS ARE
HEAVIER THAN AIR AND MAY "FLASHBACK" FROM IGNITION SOURCES
* Accidental Release Measures *
Spill Release Procedures:REMOVE IGNITION SOURCES. RECOVER FREE LIQUID
WITH ABSORBANT (VERMICULITE,SAWDUST,FIRE RETARDANT,ETC.)
Neutralizing Agent:NONE
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA. DO NOT STORE OR HANDLE NEAR HEAT, STRONG LIGHT, SPARKS, OPEN
FLAME OR STRONG OXIDANTS. KEEP TIGHTLY CLOSED
* Physical/Chemical Properties *
HCC:F4
Vapor Pres:1MM
Vapor Density:5.0
Solubility in Water:IMMISCIBLE
Appearance and Odor:BLACK LIQUID,SLIGHT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS SUCH AS CHLORINE, CALCIUM HYPOCHLORITE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:FUMES, SMOKE, CARBON DIOXIDE
* Disposal Considerations *
Waste Disposal Methods:SEND TO APPROVED DISPOSAL SITE OR FACILITY I/A/W
FEDERAL,STATE,LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
Ventilation:USE ADEQ GEN/LOC EXHST VENT TO KEEP AIRBORNE CONCS BELOW
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE.
Supplemental Safety and Health
OTHER PRECS:HEAT, SPKS/OPEN FLAME. EXTING MEDIA:FIRES:USE DRY CHEM,
* Product Identification *
* Composition/Information on Ingredients *
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: MAY CAUSE MODERATE EYE IRRIT.
VAPS MAY CAUSE EYE IRRIT. SKIN: MAY BE HARMFUL IF ABSORBED THRU
SKIN. MAY BE METABOLIZED TO CYANIDE WHICH IN TURN ACTS BY
INHIBITING CYTOCHROME OXIDASE IMPAIRING CEL LULAR RESPIRATION.
INGEST: MAY CAUSE IRRIT OF DIGESTIVE TRACT. MAY CAUSE EFTS SIMILAR
TO THOSE FOR INHAL EXPOS. INHAL: HARMFUL IF INHALED. INHAL OF HIGH
CONCS MAY CAUSE CNS EFTS CHARACTERIZED BY HDCH, DIZZ, UNCON &
COMA. MAY CAUSE LIVER & KIDNEY DMG. VAPS MAY CAUSE DIZZ OR
SUFFOCATION. MAY CAUSE NAUS, DIZZ & HDCH. INHAL MAY LEAD TO DIZZ,
WEAK & DROW, LEADING TO STUPOR, UNCON & EVEN DEATH. INHAL MA Y LEAD
TO(EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ: HEMATEMESIS, CONVULSIONS, CHOCK, COMA
& POSSIBLE DEATH. CHRONIC: CHRONIC INHAL & INGEST MAY CAUSE EFTS
SIMILAR TO THOSE OF ACUTE INHAL & INGEST. MAY BE METABOLIZED TO
CYANIDE WHICH IN TURN A CTS BY INHIBITING CYTOCHROME OXIDASE
IMPAIRING CELLULAR RESPIRATION. ANIMAL STUDIES HAVE REPORTED THAT
FETAL EFTS/ABNORMALITIES MAY OCCUR WHEN MATERNAL TOXICITY IS SEEN.
* First Aid Measures *
LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. SKIN: GET MED AID
WHILE REMOV ING CONTAM CLTHG & SHOES. INGEST: IF VICTIM CONSCIOUS &
ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER GIVE ANYTHING BY
MOUTH TO UNCON PERSON. GET MED AID IMMED. INHAL: GET MED AID
IMMED. REMOVE FRO M EXPOS TO FRESH AIR IMMED. IF BRTHG IS DFCLT,
GIVE OXYG. NOTES TO MD: EXPOS SHOULD BE TREATED AS CYANIDE
POISONING. EFTS MAY BE DELAYED. ANTIDOTE: ALWAYS HAVE CYANIDE
ANTIDOTE KIT ON HAND WHEN WORING W/CYANIDE CMPDS. GET MED ADVICE
TO USE.
* Fire Fighting Measures *
Lower Limits:4.4%
Extinguishing Media:SM FIRES:USE DRY CHEM, CO*2, WATER
SPRAY/ALCOHOL-RESIST FOAM. USE WATER SPRAY TO COOL FIRE-EXPOS
CNTNRS. WATER MAY BE INEFFECTIVE. DO NOT USE STRAIGHT STREAMS OF
WATER. LG (SUPDAT)
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . NFPA RATING: HEALTH-2; FLAMMABILITY-3; REACTIVITY-0.
Unusual Fire/Explosion Hazard:CNTNRS CAN BUILD UP PRESS IF EXPOS TO
HEAT &/OR FIRE. VAPS MAY FORM EXPLO MIX W/AIR. VAPS CAN TRAVEL TO
IGNIT SOURCE & FLASH BACK. COMBUST GENERATES TOX FUMES. USE WATER
SPRAY TO KEEP FIRE-EXPOS CNTNR S COOL. FLAM LIQ. VAPS MAY BE
HVR/AIR. THEY CAN SPREAD ALONG GROUND & COLLECT IN LOW/CONFINED
AREAS. CNTNRS MAY (SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT.
AVOID RUNOFF INTO STORM SEWERS AND DITCHES WHICH LEAD TO WATERWAYS.
REMOVE ALL SOURCES OF IGNITION. ABSORB SPILL USING AN ABSORBENT,
NON-COMBUSTIBLE MATERIAL SUCH AS EARTH, SAND OR VERMICULITE. A
VAPOR SUPPRESSING FOAM MAY BE USED TO REDUCE VAPORS. WATER SPRAY
MAY REDUCE VAPOR BUT MAY NOT PREVENT IGNITION IN CLOSED SPACES.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPKS & FLAME.
KEEP AWAY FROM SOURCES OF IGNIT. STORE IN TIGHTLY CLOSED CNTNR.
KEEP FROM CNTCT W/OXIDIZING MATLS. STORE IN COOL, DRY, WELL-VENTD
AREA AWAY FROM INCOMPAT SUBSTANCES. WASH THOROUGHLY AFTER HNDLG.
REMOVE CONTAM CLTHG & WASH BEFORE USE. USE ONLY IN WELL VENTD AREA.
Other Precautions:GROUND & BOND CNTNRS WHEN TRANSFERRING MATL. AVOID
CNTCT W/EYES, SKIN & CLTHG. EMPTY CNTNRS RETAIN PROD RESIDUE (LIQ
&/OR VAP) & CAN BE DANGEROUS. KEEP CNTNR TIGHTLY CLSD. AVOID CNTCT
W/HEAT, SPKS & F LAME. DO NOT INGEST/INHALE. DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE EMPTY C NTNRS TO
(SUPDAT)
CO*2, ALCOHOL-RESIST FOAM/WATER SPRAY. COOL CNTNRS W/FLOODING QTYS
OF WATER UNTIL WELL AFTER FIRE IS OUT. EXPLO HAZ:MAY EXPLODE WHEN
* Physical/Chemical Properties *
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Density:1.4(AIR=1)
pH:NOT AVAILABLE
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID; SWEETISH ODOR - AROMATIC
ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CHLORINE FLUORIDE, FLUORINE, 2-CYANO-2-PROPYL NITRATE, DINITROGEN
TETRAOXIDE, INDIUM, DIPHENYL SULFOXIDE, TRICHLOROSILANE, N-FLUORO
CMPDS, IRON (III) PERCHLORATE, LANTHANIDE, NITRIC ACID, PERCHLORIC
ACID, SULFURIC ACID, SUL
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES. AVOID INCOMPATIBLE MATERIALS, IGNITION SOURCES.
Hazardous Decomposition Products:HYDROGEN CYANIDE, NITROGEN OXIDES,
CARBON MONOXIDE, CARBON DIOXIDE.
* Toxicological Information*
CLASSIFIABLE AS HUMAN CARCIN. EPIDEMIOLOGY - NO INFO AVAIL.
TETRAGENICITY - EMBRYO OR FETUS: STUNTED FETUS, IHL -HAMSTER
* Ecological Information *
ENVIRONMENTAL FATE: NO INFO REPORTED. PHYSICAL/CHEMICAL: NO INFO
AVAIL. OTHER: NONE. OTHER INFO: ADVICE IMMED (SHOW LABEL WHERE
CLASSIFICATION OF B2, D1B, D2B. IT IS NOT LISTED ON CANADA'S INGRED
(TRANSPORT INFO)
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF
CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE
LEVELS: NONE LIS TED. RCRA F-SERIES: NONE LISTED. RCRA P-SERIES:
WASTE; TOXIC WASTE).
* MSDS Transport Information *
Transport Information:SHIPPING NAME - US DOT: ACETONITRILE; IATA: NO
INFO AVAIL; RID/ADR: NO INFO AVAIL. IMO: NO INFO AVAIL.
ACETONITRILE. HAZ CLASS - US DOT: 3; IMO: 3(6.1). UN NUMBER: US
ADDNL INFO: IMO: FLASHPOINT 6C. ECOLOGICAL INFO: SKIN
* Regulatory Information *
PRODUCT HAVE TPQ. SARA CODES: ACUTE, CHRONIC, FLAMMABLE. SECTION
HAVE SNUR UNDER TSCA. CLEAN AIR ACT: LISTED AS HAZ AIR POLLUTANT
(HAP). MATL DOES NOT CNTN ANY CLASS 1 OR CLASS 2 OZONE DEPLETORS.
CLEAN WATER ACT: NONE OF CHEMS IN PROD LISTED AS HAZ SUBSTANCES
UNDER C WA. NONE OF CHEMS LISTED AS PRIORITY OR TOX POLLUTANTS
UNDER CWA. NONE CONSIDERED HIGHLY HAZ BY OSHA.
EUROPEAN/INTERNATIONAL (OTHER INFO)
STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA,
PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO SIGNIFICANT
RISK LEVEL: NONE OF CHEMS IN THIS P ROD ARE LISTED. TRANSPORT INFO:
KOREA CHECK ACGIH. TLV OEL IN NEW ZEALA ND, SINGAPORE, VIETNAM
CHECK ACGIH TLV.
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED UNDER NORMAL HANDLING CONDITIONS.
USE NIOSH/MSHA APPROVED RESPIRATOR IF VAP/MIST LEVELS ARE
IRRITATING.
Ventilation:GENERAL.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:STANDARD INDUSTRIAL PROCEDURES.
Supplemental Safety and Health
IRRIT PERSISTS, GET MED ATTN. EFTS OF OVEREXP:HAZ LIST INFO & SAFE
HNDLG & EXPOS INFO . ADDNL NOTES ON TOXICITY:MAY BE ABSORBE D THRU
SKIN IN HARMFUL AMTS. SLIGHTLY TOXIC ORALLY. INHAL:PRLNG EXPOS TO
HIGH LEVELS CAN CAUSE HEADACHE, (ING 3)
* Product Identification *
Preparer's Name:PHILIP A. TOSCANO
* Composition/Information on Ingredients *
Ingred Name:ETHANOL, 2-METHOXY-; (METHYL CELLOSOLVE) (EGME) (SARA III).
ACGIH TLV:5 PPM
Ingred Name:SUPDAT:DIZZI, DROW & OTHER NERVOUS SYS EFFTS. EYE:CAN CAUSE
SEVERE IRRIT W/POSS CORNEAL DAM. (ING 4)
Ingred Name:ING 3:CAN CAUSE CNS, KIDNEY & LIVER EFFTS, AS WELL AS DAM
TO BLOOD-FORMING & REPROD ORGANS. (ING 5)
Ingred Name:ING 4:HAS BEEN SHOWN TO CAUSE BIRTH DEFECTS IN ANIMALS.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:BASED ON ITS LOW
VOLATILITY, PROD IS NOT CONSIDERED TO BE RESPIR HAZ UNDER NORMAL
COND OF USE. IRRIT AND/OR TOXIC VAPS MAY BE RELS AT ELEVATED TEMP.
INGEST:IRRIT TO MOUTH, THROAT & STOM. M AY CAUSE GASTRIC TRACT
DISORDER &/OR DAM. EYE:IRRIT, & WILL INJURE EYE TISS IF NOT REMOVED
PROMPTLY.(EFTS OF OVEREXPOS)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:SKIN:FREQUENT OR PRLNG CONTACT MAY
IRRIT & CAUSE DERMAT. CHRONIC:EYE CONTACT MAY CAUSE CONJ;
REPEATED/PRLNG SKIN CONTACT MAY CAUSE SENSITIZATION DERM.
NOTE:2-METHOXYETHANOL (EGME) APPEARS ON THE NAVY LISTING OF OCCUP
CHEM REPRO HAZ. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS
CONCERNING LATEST (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:FIRST AID IS NOT NORMALLY REQD. REMOVE TO FRESH AIR.
GET MED ATTN IF IRRIT PERSISTS. INGEST:INDUCE VOMIT ONLY IF VICTIM
IS ALERT. GET PROMPT MED ATTN. DO NOT ATTEMPT TO GIVE ANYTHING BY
MOUTH TO A DROW/UNCON PERSON. SKIN:FLUSH EXPOS AREA THORO W/ SOAP
& WATER UNTIL ALL CHEM IS REMOVED. REMOVE CONTAM CLTH & LAUNDER
BEFORE REUSE. IF IRRIT PERSISTS, GET MD. EYE:FLUSH EYES WITH LG
AMTS (SUPDAT)
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:2.5
Extinguishing Media:CO2; FOAM; DRY CHEMICAL; WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . COOL EXPOSED EQUIPMENT WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION MAY RELEASE NOXIOUS OR TOXIC
VAPORS. SEE REACTIVITY, SECTION 7. PROHIBIT SMOKING & OPEN FLAMES.
AVOID SPARKS/OTHER SOURCES OF STATIC ELECTRICITY.
* Accidental Release Measures *
Spill Release Procedures:TAKE UP WITH SAND/OTHER ABSORBENT MATL & PLACE
IN CNTNR FOR LATER DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:ROOM TEMP. AVOID EXCESSIVE HEAT. STORE
OUT OF DIRECT SUNLIGHT IN A DRY AREA. MAXIMUM STORAGE TEMPERATURE
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:F4
Spec Gravity:1(WATER =1)
Evaporation Rate & Reference:0.5 (BUTYL ACETATE =1)
Solubility in Water:SLIGHTLY SOLUBLE
Appearance and Odor:AMBER LIQUID; SWEET ETHER-LIKE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:ACIDS, EPOXY RESINS IN UNCONTROLLED
CONDITIONS.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
AMMONIA, AMINES.
* Disposal Considerations *
Waste Disposal Methods:IN ACCORDANCE WITH EXISTING FEDERAL, STATE AND
LOCAL ENVIRONMENTAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR IF DUST
CONDITIONS OCCUR.
Ventilation:LOCAL EXHAUST ADEQUATE TO REMOVE DUST.
Other Protective Equipment:COVERALLS OR APRON TO PREVENT CONTAMINATION
OF CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:LAUREL DUNSCOMB
* Composition/Information on Ingredients *
Ingred Name:NON HAZARDOUS INGREDIENTS
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
NUISANCE DUST-AS W/ALL DUSTS, AVOID HIGH CONCENTRATIONS. EYES:MAY
CAUSE IRRITATION. SKIN:MAY CAUSE IRRITATION, LOCAL DERMATITIS &
ALLERGIC DERMATITIS. INGEST:MAY CAUSE ALLERGIC REACTION INCLUDING
NAUSEA, DIARRHEA, ITCHING, SWELLING, ASTHMA ATTACKS,
UNCONSCIOUSNESS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:& ANAPHYLACTIC SHOCK. INHAL:MAY CAUSE
IRRITATION TO UPPER RESPIRATORY TRACT.
Medical Cond Aggravated by Exposure:MAY CAUSE ALLERGIC REACTION IN SOME
INDIVIDUALS W/ASTHMA.
* First Aid Measures *
SKIN:WASH THOROUGHLY W/SOAP & WATER. CONSULT MD IF IRRITATION
PERSISTS. INGEST:GIVE 1 OR 2 GLASSES OF WATER. INDUCE VOMITING. GET
MEDICAL ATTENTION . INHAL:REMOVE TO FRESH AIR.
* Fire Fighting Measures *
Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL,
ALCOHOL-TYPE OR UNIVERSAL TYPE FOAMS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:FLAMMABLE SOLIDS MAY PROVIDE CONDITIONS
FOR A DUST EXPLOSION.
* Accidental Release Measures *
Spill Release Procedures:USE ADEQUATE PERSONAL PROTECTION AS DESCRIBED
IN CONTROL MEASURES SECTION. SALVAGE LARGE SPILLS FOR REPROCESSING.
THIS MATERIAL HAS A HIGH OXYGEN DEMAND & DISPOSAL AREAS SHOULD BE
SELECTED W/THIS CONS IDERATION. FLUSH AREA W/WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN CLOSED CONTAINERS IN DRY
AREA. AVOID CONTACT W/SKIN, EYES & CLOTHING. USE W/ADEQUATE
VENTILATION. AVOID BREATHING DUST.
Other Precautions:DO NOT TAKE INTERNALLY. AVOID PROLONGED OR REPEATED
CONTACT W/SKIN.
* Physical/Chemical Properties *
HCC:N1
pH:SUPDAT
Appearance and Odor:WHITE, TAN OR PINK POWDER; NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS CAUSE RELEASE OF SO2 GAS. STRONG REAGENTS MAY REACT VIGOROUSLY.
STRONG OXIDIZERS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:UNDER HIGH HEAT, SULFUR DIOXIDE GAS &
SODIUM SULFIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:A FULL FACEPIECE CHEMICAL CARTRIDGE
RESPIRATOR,OR A SUPPLIED AIR FULL FACEPIECE RESPIRATOR OR AIRLINE
HOOD,DEPENDING UPON THE EXPOSURE OF CONCERN.
Ventilation:LOCAL EXHAUST AND/OR MECHANICAL(GENERAL) VENTILATION
RECOMMENDED. LOCAL EXHAUST,PREFERRED.
Other Protective Equipment:BOOTS,LAB COAT,APRON OR COVERALLS. EYEWASH
STATION & SAFETY SHOWER.
Work Hygienic Practices:AVOID BREATHING VAPORS.AVOID CONTACT WITH
EYES,SKIN & CLOTHING. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
* Product Identification *
Product ID:ISOPROPYL ALCOHOL
* Composition/Information on Ingredients *
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
Other REC Limits:NONE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:SEE SIGNS & SYMPTOMS OF
OVEREXPOSURE. CHRONIC:PROLONGED CONTACT WITH SKIN MAY CAUSE MILD
IRRITATION,DRYING,CRACKING,OR CONTACT DERMATITIS. SINGLE LETHAL
Effects of Overexposure:EYES:SEVERE IRRITATION,POSSIBLE CORNEAL BURNS &
EYE DAMAGE;SKIN:IRRITATION,BURNING,DEFATTING;INHALATION:IRRITATION
OF NOSE & THROAT,NARCOTIC
EFFECT,DROWSINESS,HEADACHE,STAGGERING,UNCONSCIOUSNESS,DEATH
;INGESTION:GASTROINTESTINAL PAIN,CRAMPS,NAUSEA,VOMIT,DIARRHEA.MAY
CAUSE DROWSINESS,UNCONSCIOUSNESS,DEATH.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS,EYE
PROBLEMS,IMPAIRED RESPIRATORY FUNCTIONS.
* First Aid Measures *
First Aid:EYES:FLUSH WITH PLENTY OF WATER.SEE DOCTOR
IMMEDIATELY;SKIN:REMOVE CONTAMINATED CLOTHING.WASH WITH SOAP &
WATER.IF IRRITATION PERSISTS,SEE DOCTOR;INHALATION:REMOVE TO FRESH
AIR.GIVE CPR/OXYGEN IF NEED ED.SEE DOCTOR;INGESTION:GIVE
WATER.INDUCE VOMIT.SEE DOCTOR IMMEDIATELY.NOTHING BY MOUTH IF
UNCONSCIOUS.
* Fire Fighting Measures *
Flash Point Method:CC
Lower Limits:2.0
Extinguishing Media:WATER SPRAY,DRY CHEMICAL,ALCOHOL FOAM,CO*2
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING. USE WATER
SPRAY TO COOL FIRE EXPOSED CONTAINERS AND TO DISPERSE UNIGNITED
VAPORS.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR.CAN TRAVEL
ALONG GROUND A LONG DISTANCE AND FLASHBACK.
* Accidental Release Measures *
Spill Release Procedures:REMOVE IGNITION SOURCES.VENTILATE.WEAR
RESPIRATORY PROTECTION & PROTECTIVE CLOTHING.SMALL SPILLS MAY BE
ABSORBED IN PAPER TOWELS & EVAPORATED IN A FUME HOOD.ALLOW FUMES TO
CLEAR HOOD,THEN IGNITE PAPER IN SUITABLE LOCATION AWAY FROM
COMBUSTIBLES.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
PLACE,AWAY FROM STRONG OXIDIZERS & IGNITION SOURCES.PROTECT FROM
PHYSICAL.STORE IN NON-SMOKING AREA.
Other Precautions:CONTAINERS SHOULD BE BONDED & GROUNDED FOR TRANSFERS.
* Physical/Chemical Properties *
HCC:F2
Vapor Density:2.1
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR,COLORLESS LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS,ACETALDEHYDE,CHLORINE,ETHYLENE OXIDE
Stability Condition to Avoid:HEAT,SUNLIGHT,SPARKS,OPEN FLAMES
Hazardous Decomposition Products:CO,TOXIC GASES & VAPORS
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL,STATE & LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AVOID BRTHG VAP &/OR DUST. USE NIOSH APPRVD RESP
PROT EQUIP (FULL FACEPIECE RECOMMENDED) WHEN AIRBORNE EXPOS IS
EXCESS. CONSULT RESP MANUFACTURER TO DETERMINE APPROPRIATE TYPE
EQUIP FOR GIVEN APPLICAT ION. OBSERVE RESP USE LIMITATIONS
SPECIFIED BY NIOSH/MANUFACTURER. RESP PROT PROGRAMS MUST COMPLY
Ventilation:PROVIDE NATURAL/MECHANICAL VENT TO MINIMIZE EXPOSURE. IF
PRACTICAL, USE LOCAL MECH EXHAUST VENT AT SOURCES OF AIR
CONTAMINATION SUCH AS OPEN PROCESS EQUIP.
Other Protective Equipment:EYEWASH & DELUGE SHOWER MTG ANSI DESIGN
CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. WASH
CONTAMINATED SKIN PROMPTLY. LAUNDER CONTAMINATED CLOTHING AND CLEAN
PROTECTIVE EQUIPMENT BEFORE REUSE.
Supplemental Safety and Health
SPILL PROC: BURN CONTAINERS IN APPROVED INCINERATOR/DISPOSE OF IN
CHEMICAL LANDFILL WHICH COMPLIES W/ALL APPLIC LOCAL, STATE &
FEDERAL LAWS & REGS. FOR EMERGENCY ASSISTANCE (ONLY IN EVENT OF
CHEM EMER GENCIES INVOLVING SPILL, LEAK, EXPOS/ACCIDENT INVOLVING
* Product Identification *
Product ID:SANTOGARD PVI PREVULCANIZATION INHIBITOR
* Composition/Information on Ingredients *
Ingred Name:N-(CYCLOHEXYLTHIO) PHTHALIMIDE
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Ingred Name:BUTYL OLEATE. PRESENT ONLY IN SANTOGARD PVI-DS.
= Wt:1.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:THE FOLLOWING INFORMATION SUMMARIZES
HUMAN EXPERIENCE AND RESULTS OF SCIENTIFIC INVESTIGATIONS REVIEWED
BY HEALTH PROFESSIONALS FOR HAZARD EVALUATION OF SANTOGARD PVI
PREVULCANIZATION INHIBITOR AND DE VELOPMENT OF PRECAUTIONARY
STATEMENTS AND OCCUPATIONAL CONTROL PROCEDURES RECOMMENDED IN THIS
DOCUMENT. SKIN CONTACT AND INHALATION ARE EXPECTED TO BE THE
PRIMARY ROUTES OF OCCUPATIONAL EXPOSURE TO SA NTOGARD PVI
PREVULCANIZATION INHIBITOR. OCCUPATIONAL EXPOSURE TO THIS MATERIAL
HAS BEEN REPORTED TO CAUSE EYE AND SKIN IRRITATION. (EFFECTS OF
OVEREXPOSURE)
Effects of Overexposure:HEALTH HAZARDS: IN ADDITION, THIS MATERIAL MAY
PRODUCE ALLERGIC SKIN REACTION IN SUSCEPTIBLE INDIVIDUALS.
FOLLOWING EXPOSURE TO SANTOGARD PVI, WORKERS HAVE REPORTED THE
PRESENCE OF A STRONG ODOR (MERC APTAN-LIKE) ON THE SKIN WHICH CAN
BE REMOVED BY PERSPIRATION, WASHING OR SHOWERING. SOME EXPOSED
INDIVIDUALS HAVE REPORTED NAUSEA DUE TO THIS STRONG ODOR.
* First Aid Measures *
MINUTES. GET MEDICAL ATTENTION. SKIN: IMMEDIATELY WASH WITH SOAP
AND PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION.WASH CLOTHING BEFORE REUSE. INHALATION: REMOVE PERSON
TO FRESH AIR. REMOVE MATERIAL FROM EYES, SKIN AND CLOTHING.
INGESTION: CALL MD IMMEDIATELY .
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:WATER SPRAY OR OTHER CLASS A EXTINGUISHING AGENT.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT . THOROUGHLY DECONTAMINATE
EQUIPMENT AFTER USE.
Unusual Fire/Explosion Hazard:CARBON MONOXIDE, SULFUR DIOXIDE &
NITROGEN OXIDE ARE EMITTED WHEN PROD IS IGNITED. NOTE: PROD IS
SOMETIMES SOLD AS MILLED GRADE. THIS FINE PARTICLE SIZE CREATES
POTENTIAL FOR DUST EXPLO/FIRES. FOR ANY OPERATIONS INVOLVING
MILLED PROD/ANY ADDN TO FLAMM SOLVS, USE ONLY ELEC EQUIP THAT IS
SUITABLE FOR HAZ (OTHER INFO)
* Accidental Release Measures *
Spill Release Procedures:AVOID CREATING DUST CLOUD AS THIS MATL, IF
DISPERSED IN AIR, COULD PRESENT POTENTIAL DUST EXPLO HAZ. DO NOT
BLOW MATL. USE VACUUM EQUIP DESIGNED SPECIFICALLY FOR HNDLG COMBUST
DUSTS. VACUUM/SWEEP UP & PLACE IN DRY, COVERED, CLEAN CONTR. WEAR
MATL OUT OF SEWERS, WATERSHEDS & WATERWAYS. (SUP DAT)
*Handling and Storage *
Handling and Storage Precautions:DURING STOR AVOID EXTREMES OF TEMPS &
HUMIDITY. SUGGESTED MAX STOR TIME IS ONE YEAR. COMBUST DUST - EXPLO
POTENTIAL. KEEP AWAY FROM HEAT, SPARKS & FLAME. AVOID CREATING DUST
IN HNDLG, TRANSFER/CLEAN U P. AVOID CONT W/EYES, SKIN & CLOTHING.
AVOID BREATHING VAP/DUST. KEEP CONTR CLOSED. USE W/ADEQ VENT.
Other Precautions:EMPTIED CONTR RETAINS VAP & PROD RESIDUE. OBSERVE ALL
LABELED SAFEGUARDS UNTIL CONTR IS CLEANED, RECONDITIONED/DESTROYED.
STORE IN COOL DRY PLACE, AWAY FROM FOODSTUFFS & ACIDS. FOR ADDNL
PROD INFO, IN CL PROD FORMS, CHARACTS & APPLICATIONS, & FDA REGS,
CONSULT MONSANTO RUBBER CHEMICALS PURCHASING GUI DE.
* Physical/Chemical Properties *
Solubility in Water:INSOLUBLE
Appearance and Odor:LIGHT TAN TO WHITE CRYSTALS; SLIGHT MERCAPTAN ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS.
Hazardous Decomposition Products:IF STRONGLY HEATED, THIS PRODUCT MAY
CATCH FIRE AND GIVE OFF TOXIC FUMES OF CARBON MONOXIDE, SULFUR
DIOXIDE AND NITROGEN OXIDES.
* Toxicological Information*
Toxicological Information:DATA FROM AVAIL SCIENTIFIC LITERATURE ARE
GIVEN BELOW: SINGLE-DOSE (ACUTE) STUDIES INDICATE: ORAL: SLIGHTLY
TESTED FOR POTENTIAL TO PRDCE ALLERGIC SKIN RXN IN CONTROLLED SKIN
CONT STUDIES W/HUMAN VOLUNTEERS. P OTENTIAL FOR PRIMARY &
CUMULATIVE IRRIT WAS DEMONSTRATED & ALLERGIC SKIN RXN WAS OBSERVED.
THIS MATL, WHEN PRESENT AT 2 PHR IN RUBBER STOCK, WAS ONLY A
CUMULATIVE SKIN IRRITANT IN HUMAN VOLUNTEERS. (T RANSPORT INFO)
* Ecological Information *
W/ TRANSFERRING PROD, GROUND EQUIP, PROV INERT ATM & PROP
DESIGNING MATL HNDLG EQUIP, TO PVNT ELECTROSTATIC CHARGE.
(PHYS/CHEM PROPERTIES): NOTE: PHYS DATA ARE TYP VALUES BSD ON MATL
TESTED BUT MAY VARY. TYP VALUES SHD NOT BE CONSTRUED AS GUARAN
ANALYSIS OF ANY SPECIFIC LOT. MFR INTERNAL EXP LIMIT: 0.5 MG/M3, 8
HR TWA, SKIN ABS MAY ADD TO THE OVERALL EXP. AVOID SKIN CONTACT.
* Disposal Considerations *
Waste Disposal Methods:WHEN DISCARDED, MATL IS NOT "HAZ WASTE" AS THAT
HAZ WASTE". BURN IN APPRVD INCIN/DISPOSE OF IN APPRVD CHEM LANDFILL
WHICH COMPLIES W/A LL APPLIC LOC, STATE & FED LAWS & REGS. CONSULT
YOUR ATTORNEY/APPROP REGULATORY OFFICIALS FOR INFO O N SUCH DISP.
* MSDS Transport Information *
Transport Information:DOT PROPER SHIPPING NAME: ORM-A, N.O.S. (VIA
N/A. U.S. SURF FREIGHT CLASSIFICATION: RUBBER PRESERVATIVES,
N.O.I.B.N. TOX INFO: NO ADVER SE EFTS WERE OBSERVED IN RATS EXPOSED
PROD DUST, RATS SHOWED INCRD KIDNEY WTS & DMG, & LUNG EFTS. THIS
MATL GIVEN TO RATS IN THEIR D IETS FOR 4 WKS PRDCED ONLY DECRD BODY
WTS. PROD GIVEN TO RATS BY DIETARY ADMIN WAS SHOWN TO ENHANCE
CARCIN ACTIVITY OF DIETHYLNITROSAMINE, A KNOWN CARCIN. (SARA REGS)
* Regulatory Information *
SARA Title III Information:HAZARD CATEGORIES UNDER CRITERIA OF SARA
DECREASED BODY WTS, SERUM CHEMISTRY CHANGES, BLOOD CHANGES,
INCREASED KIDNEY & LIVER WTS AS WELL AS CHANGES IN THESE ORGANS.
DOSE-RELATED INCR IN BENIGN LIVER TUMORS WA S ALSO OBSERVED IN
FEMALE RATS. A MULTIGENERATIONAL STUDY W/RATS GIVEN PROD IN THEIR
DIETS REPORTED DECREASED BODY WTS IN FIRTS GENERATION RATS &
INCREASE IN MORTALITY IN OFFSPRINGS OF SECOND GENERATI ON. (STATE
REGS)
Federal Regulatory Information:EPA REG NUMBER: NOT APPLICABLE. TSCA
INVENTORY: THIS PRODUCT APPEARS ON THE INVENTORY OF CHEMICAL
SUBSTANCES PUBLISHED BY THE U.S. ENVIRONMENTAL PROTECTION AGENCY
(EPA) UNDER THE AUTHORITY OF THE TOXI C SUBSTANCES CONTROL ACT
REGULATIONS: NOT APPLICABLE. HAZARDOUS CHEMICAL(S) UNDER OSHA
HAZARD COMMUNICATION STANDARD: THIS CHEMICAL IS ID ENTIFIED AS A
HAZARDOUS CHEMICAL UNDER THE CRITERIA OF THE OSHA HAZARD
State Regulatory Information:SARA REGS: HOWEVER, NO CONSISTENT ADVERSE
REPRODUCTIVE EFFECTS WERE OBSERVED IN THIS STUDY. NO BIRTH DEFECTS
WERE OBSERVED IN RABBITS GIVEN THIS MATERIAL ORALLY DURING
PREGNANCY, EVEN AT LEVELS WHICH PRODUCED TOXIC EFFECTS IN THE
MOTHERS AND OFFSPRINGS. NO ADVERSE GENETIC CHANGES WERE OBSERVED IN
STANDARD TESTS USING BACTERIAL AND ANIMAL CELLS AND ANIMALS.
* Other Information *
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* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED RESPIRATORS AS SPECIFIED BY
INDUSTRIAL HYGIENIST OR QUALIFIED SAFETY PROFESSIONAL. LUNG
FUNCTION TESTS ARE RECOMMENDED FOR USERS OF NEGATIVE PRESSURE
DEVICES.
Ventilation:LOC EXHST VENT SHOULD BE USED TO CONTROL EXPOS TO AIRBORNE
Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE
SHOWER . PROT CLTHG SUCH AS UNIFORMS, DISPOSABLE COVERALLS, SAFETY
(SUPDAT)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXTING MEDIA:GRAPHITE/OTHER CLASS "D" FIRE EXTING PWDR. OTHER PREC:&
SOURCES OF IGNIT. MED SURVEILLANCE:LUNG FUNC TESTS, CHEST X-RAYS &
ROUTINE PHYSICAL EXAMS MAY BE USEFUL TO DETERM EFTS OF DUST/FUME
EXPOS. OTHER PROT EQUIP:SHOES, ETC, MAY BE REQD DURING METAL HNDLG
OPERATIONS AS APPROP TO CIRCUMSTANCES OF EXPOS.
* Product Identification *
Preparer's Name:L.C. WOODSIDE
CAGE:NGKME
CAGE:NGKME
* Composition/Information on Ingredients *
Fraction by Wt: 2.5%
OSHA PEL:0.1 MG/M3
Fraction by Wt: BALANCE
OSHA PEL:0.1MG/M3 FUME;1 DUST
ACGIH TLV:0.2 MG/M3 FUME
Ingred Name:EFTS OF OVEREXP:SYMPS. CHRONIC:RESP DISEASE W/SYMPS RANGING
FROM SHORTNESS OF BREATH & COUGH TO PERM DISABILITY (ING 5)
Ingred Name:ING 4:DUE TO LOSS OF LUNG FUNC, FIBROSIS/SUBSEQUENT EFTS ON
HEART MAY BE CAUSED BY EXCESSIVE EXPOS TO METAL DUST/(ING 6)
Ingred Name:ING 5:FUMES CNTNG BERYLLIUM & COBALT. BERYLLIUM & CERTAIN
CMPDS HAVE BEEN LINKED TO NASAL, BRONCH & LUNG CANCERS.(ING 7)
Ingred Name:ING 6:INHAL OF BERYLLIUM IN EXCESS CONCS CAN CAUSE SERIOUS
LUNG DISEASE; BERYLIOSIS. CHRONIC HLTH EFTS SPECIFIC (ING 8)
Ingred Name:ING 7:TO ELEMENT(S) MAY BE DFCLT TO DETECT DUE TO NUMEROUS
ELEMENTAL CONSTITUENTS IN THIS ALLOY.
Ingred Name:MED CNDTNS:AS ASTHMA, EMPHYSEMA, CHRONIC BRONCH, ETC, MAY
Ingred Name:ING 9:FUME ARE INHALED. IF PRIOR DMG OR DISEASE TO
NEUROLOGIC (NERV), CIRCULATORY, HEMATOLOGIC (BLOOD) OR RENAL (ING
CAUSES EXCESSIVE EXPOSURE.
Ingred Name:FIRST AID PROC:VOMIT IF CONSCIOUS. OBTAIN MED ASSISTANCE AT
CONT LENSES SHOULD NOT BE WORN IF WORKING W/METAL DUSTS & PWDRS.
Ingred Name:SPILL PROC:PWDR/DUST & AVOID CONTAM OF AIR & WATER.
C).
Ingred Name:VENT:TO INGS CAN BE BEST DETERMINED BY HAVING AIR SAMPLES
TAKEN IN EMPLOYEE BRTHG ZONE, WORK AREA OR DEPARTMENT.
Ingred Name:EXPLAN OF CARCIN:CARCIN. HUMAN:LUNG FIBROSIS. COBALT:IARC
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:UNDER NORMAL HNDLG & USE OF SOLID FORM
OF THIS MATL THERE ARE FEW HLTH HAZS. CUTTING, WELDING, MELTING,
GRINDING, ETC, OF THIS MATL WILL PRDCE DUST, FUME/PARTICULATE WHICH
MAY PRESENT SIGNIFICANT HLTH HAZS. ACUTE:METAL DUST & FUMES CAN
CAUSE IRRIT TO SKIN, EYE & MUC MEMBS. CONT W/COBALT & COPPER MAY
(EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ:CAUSE ALLERGIC SKIN RXNS. AS DUST,
PWDR/FUME, EXPOS WHICH ABRADES SKIN CAN CAUSE IRRIT & DERM. INJURY
TO EYES IS GENRLY RSLT OF PARTICULATE IRRIT/MECH INJURY TO
CORNEA/CONJ BY DUST/PARTICULAT E. EXCESSIVE INHAL OF COBALT &
COPPER CAN CAUSE RESP IRRIT, COUGH, BRONCH, CHILLS, "FUME FEVER" &
ASTHMA-LIKE (ING 4)
Medical Cond Aggravated by Exposure:INDIVIDUALS WHO MAY HAVE HAD
ALLERGIC RXN/SENSITIVITY TO METALS SUCH AS COPPER MAY ENCOUNTER
SKIN RASH/DERM IF SKIN CONT W/PROD OCCURS. PERS W/IMPAIRED PULM
FUNC, AIRWAY DISEASES & CNDTNS SUCH (ING 9)
* First Aid Measures *
First Aid:INHAL:BRTHG DFCLTY CAUSED BY INHAL OF DUST/FUME REQS REMOVAL
TO FRESH AIR. IF BRTHG HAS STOPPED, PERFORM ARTF RESP & OBTAIN MED
ASSISTANCE AT ONCE. IF OVEREXP TO METAL FUME PRDCES CHILLS, MUSC
ACHES/F EVER, MOVE EXPOS PERS TO FRESH AIR & OBTAIN MED ASSISTANCE
AT ONCE. INGEST:SWALLOWING METAL PWDR/DUST CAN BE TREATED BY HAVING
AFFECTED PERS SWALLOW LG QTYS OF WATER & ATTEMPTING TO INDUCE (ING
* Fire Fighting Measures *
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:THIS ALLOY IS NONCOMBUST. USE EXTING MEDIA APPROP
TO SURROUND FIRE. TO EXTING METAL PWDR FIRE USE DRY SAND, DRY
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . IF THIS MATERIAL IS REDUCED TO POWDER FORM, CAUTION
MUST BE USED TO PREVENT FIRE OR EXPLOSION.
Unusual Fire/Explosion Hazard:NO UNUSUAL FIRE OR EXPLOSION HAZARDS ARE
ASSOCIATED WITH THIS MATERIAL.
* Accidental Release Measures *
Spill Release Procedures:IN SOLID FORM THIS MATL POSES NO SPECIAL
CLEAN-UP PROBS. IF THIS MATL IS IN PWDR/DUST FORM, CLEAN-UP SHOULD
BE CONDUCTED W/VACUUM SYS UTILIZING HIGH EFFICIENCY PARTICULATE AIR
FILTRATION SYS. CAUT SHO ULD BE TAKEN TO MIN AIRBORNE
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:THIS PROD MUST BE HNDLD ACCORDINGLY TO
SIZE, SHAPE & QTY OF MATL INVOLVED. SOLID METAL MAY REQ USE OF
HOISTS, CRANES, ETC. AVOID BRTHG DUST/FUME.
Other Precautions:PWDRS SHOULD BE MOVED/TRANSPORTED TO MIN SPILL/RELS
POTNTL. IN SOLID FORM MATL POSES NO SPEC STOR PROBS. STORE METAL &
METAL PWDR IN DRY AREA. DO NOT STORE ADJACENT TO MINERAL ACIDS.
FINE METAL PWDR S HOULD BE KEPT AWAY FROM FLAMES (SUPDAT)
* Physical/Chemical Properties *
Appearance and Odor:SOLID - BRASS COLOR; NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONT W/MINERAL ACIDS & OXIDIZING AGENTS THAT MAY GENERATE
HYDROGEN GAS; EVOLUTION OF HYDROGEN MAY BE EXPLO HAZ.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:VARIOUS ELEMENTAL METALS & METAL
OXIDES MAY BE GENERATED FROM MELTING OR DROSS HANDLING OPERATIONS.
* Disposal Considerations *
Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . PRIOR
TO DISP CONSIDER IF MATL HAS RECOVERY VALUE. STATE/FED REGS MAY REQ
SPEC LABELING, PACKING, STOR, TRANSPORTATION & DISP PROCS. CONT
ENVIRON ENGIN EER/CONSULTANT FAMILIAR W/WASTE DISP REGS.
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* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED IF GOOD VENTILATION IS MAINTAINED.
WHEN NEEDED, A NIOSH/MSHA APPROVED RESPIRATOR SHOULD BE WORN.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE PRACTICE.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:LOOK GLASS CLEANER CONCENTRATE
* Composition/Information on Ingredients *
Ingred Name:AMMONIUM HYDROXIDE(SARA III)
Fraction by Wt: <1%
OSHA PEL:N/K
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXY ETHANOL)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:DIRECT CNTCT OF PROD W/EYES MAY CAUSE
IRRIT. MAY BE HARMFUL IF INHALED/ABSORBED THRU SKIN. HIGH VAP CONC
MAY IRRIT EYES & RESP TRACT. PRLNG/RPTD CNTCT W/SKIN MAY CAUSE
IRRIT. CHRONIC: ANIMAL STUDIES C LEARLY DEMONSTRATED DOSE-RELATED
ADVERSE EFTS ON CNS, HEMATOPOIETIC TISSUES, BLOOD, KIDNEYS & LIVER,
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: ASSOCIATED W/THE ADMINISTRATION OF
. REPEATED OVEREXPOSURE MAY CAUSE HEMOLYSIS OF RED BLOOD CELLS
LEADING TO POSSIBL E LIVER & KIDNEY DAMAGE.
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN AND
RESPIRATORY DISORDERS MAY BE AGGRAVATED.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. SEEK MEDICAL ATTENTION. EYES: FLUSH WITH
CALL MD IF IRRITATION DEVELOPS. INGESTION: DRINK LARGE QUANTITIES
OF WATER. DO NOT INDUCE VOMITING. CALL MD.
* Fire Fighting Measures *
Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . IN CASE OF FIRE, COOL UNINVOLVED CONTAINERS
WITH WATER.
Unusual Fire/Explosion Hazard:WHEN EXPOSED TO TEMPERATURES AT OR NEAR
FLASH POINT, BUILD-UP OF IGNITABLE VAPORS MAY OCCUR.
* Accidental Release Measures *
Spill Release Procedures:BEFORE ATTEMPTING CLEAN-UP, REFER TO HAZARD
INFORMATION. REMOVE IGNITION SOURCES. CONTAIN SPILL. USE MOP,
ABSORBENT OR WET VACUUM TO COLLECT MATERIAL FOR PROPER DISPOSAL.
RINSE AREA WITH WATER.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:WASH CONTAMINATED CLOTHING AND
EQUIPMENT BEFORE REUSE.
Other Precautions:
* Physical/Chemical Properties *
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR BLUE LIQUID; SLIGHT AMMONIA ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN TO THE MANUFACTURER.
Stability Condition to Avoid:NONE KNOWN TO THE MANUFACTURER.
Hazardous Decomposition Products:NORMAL PRODUCTS OF COMBUSTION.
* Disposal Considerations *
Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION AND DISPOSAL
OF THIS MATERIAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS.
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* Exposure Controls/Personal Protection *
Respiratory Protection:IN RESTRICTED VENTILATION AREAS, A NIOSH/MSHA
APPROVED ORGANIC VAPOR RESPIRATOR IS RECOMMENDED. DURING SPRAY
APPLICATION, A RESPIRATOR PROVIDING ORGANIC VAPOR & SPRAY MIST
PROTECTION IS RECOMMENDED UN LESS ENGINEERING CONTROLS ARE
ADEQUATE.
Ventilation:CONFINED AREAS MECHANICAL VENTILATION REQUIRED TO KEEP THE
AIR CONTAMINANT CONCENTRATION BELOW OSHA PERMISSIBLE LIMITS.
Other Protective Equipment:PREVENT PROLONGED SKIN CONTACT WITH
CONTAMINATED CLOTHING. REMOVE & WASH CONTAMINATED CLOTHING BEFORE
REUSE.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING
WASHROOM FACILITIES.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:TITANIUM DIOXIDE ( AS NUISANCE DUST)
Fraction by Wt: > 1%
Other REC Limits:NONE SPECIFIED
Ingred Name:CARBON BLACK
Fraction by Wt: > 1%
Other REC Limits:NONE SPECIFIED
ACGIH TLV:3.5 MG/M3
Ingred Name:MINERAL SPIRITS (LEL 1.0)
Fraction by Wt: > 1%
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRITATION OF EYES & SKIN MAY
OCCUR WITH OVEREXPOSURE. CONTINUSED BREATHING OF VAPORS MAY
IRRITATE RESPIRATORY TRACT CAUSING HEADACHE, NAUSEA & DIZZINESS.
CHRONIC: REPORTS HAVE ASSOCIATEDREPEATED & PROLONGED
OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN & NERVOUS SYSTEM
DAMAGE.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE RESPIRATION IF
NECESSARY. TREAT SYMPTOMATICALLY. EYE CONTACT: FLUSH IMMEDIATELY
A PHYSICIAN IF IRRITATION PERSISTS. INGESTION: DRINK 1 - 2 GLASSES
LUNGS. GET MED ATTN.
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER MIST.
Fire Fighting Procedures:SMOTHER FLAMES WITH ONE OF THE ABOVE
EXTINGUISHING MEDIA. WATER MAY BE USED TO COOL DOWN UNOPENED
CONTAINERS IN VICINITY.
Unusual Fire/Explosion Hazard:CONTAINS FLAMMBLE SOLVENT. DO NOT USE IN
AREAS WHERE SPARKS OR OPEN FLAMES ARE PRESENT.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. WEAR
APPROPRIATE PERSONAL PROTECTION EQUIPMENT & APPROVED RESPIRATOR.
PREVENT MATERIAL FROM CONTACTING ANY WATER SOURCES OR SEWERS
LEADING TO SURFACE WATERS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN AREAS DESIGNED TO COMPLY WITH
Other Precautions:GROUND CONTAINERS WHEN POURING LIQUIDS & POWDERS TO
AVOID STATIC CHARGE BUILDUP. DO NOT HANDLE UNTIL MANUFACTURERS
SAFETY PRECAUTION HAVE BEEN READ & UNDERSTOOD. PROVIDE ADEQUATE
VENTILATION & RESPIRA TORY PROTECTION.
* Physical/Chemical Properties *
HCC:F4
Vapor Density:> AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS
Stability Condition to Avoid:EXTREME HEAT, SPARKS OR OPEN FLAMES.
Hazardous Decomposition Products:MAY PRODUCE HAZARDOUS FUMES WHEN
HEATED
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE &
FEDERAL REGULATIONS.
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* Exposure Controls/Personal Protection *
Respiratory Protection:THE USE OF RESPIRATORY PROTECTION IS ADVISED
WHEN CONCENTRATIONS EXCEED THE ESTABLISHED EXPOSURE LIMITS.
DEPENDING ON THE AIRBORNE CONCENTRATION, USE A RESPIRATOR OR GAS
MASK WITH APPROPRIATE CARTRIDG ES & CANNISTERS(NIOSH APPROVED,IF
AVAILABLE) OR SUPPLIED AIR EQUIPMENT.
Ventilation:IF CURRENT VENTI PRACT NOT ADEQ TO MAINTAIN AIRBORNE CONC
BELOW ESTABLISHED EXPO LIMITS,ADDNT VNETI OR EXHAUST SYST MAYBE
REQUIRED.(SEE SUPPLEM SAF/HEALTH)
MATERIAL HANDLED IS ADVISED
CONTACT,IRRIT,INJURY
Other Protective Equipment:IT IS SUGGESTED THAT A SOURCE OF CLEAN WATER
BE AVAILABLE IN WORK AREA FOR FLUSHING EYES AND SKIN. IMPERVIOUS
CLOTHING SHOULD BE WORN AS NEEDED.
Supplemental Safety and Health
BE PRESENT,SYSTEMS SAFE FOR SUCH LOCATIONS SHOULD BE USED.
* Product Identification *
Product ID:CYCLOHEXANE
* Composition/Information on Ingredients *
Ingred Name:CYCLOHEXANE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE/SKIN:IRRITATION.
INHALATION:BREATHING HIGH CONCENTRATIONS MAY CAUSE IRRITATION OF
NOSE AND THROAT. INGESTION:EXCESSIVE QUANTITIES MAY CAUSE
IRRITATION OF DIGESTION TRACT.REPORTS HAVE ASSOC REPEATE D & PROL
OCCUPATIONAL OVEREXPO TO SOLVENTS W/PERM BRAIN & NERV SYS DMG
(SOMETIME REFERRED TO AS SOLVENT OR PAINTERS' SYNDROME).INTENTIONAL
MISUS BY DELIBERATELY CONC & INHAL THIS PRODUCT MAYBE HARMFUL OR
FATAL.NO HARMFUL EFFECTS HAVE BEEN DEMONSTRATED IN SKIN ABSORPTION
STUDIES.ASPIRATION HAZ-MATL CAN ENTER LUNGS DURING SWALLOWING OR
VOMITING & CAUSE LUNG INFLAMM & DMG.
Explanation of Carcinogenicity:THIS SUBSTANCE HAS NOT BEEN IDENTIFIED
AS A CARCINOGEN OR POSSIBLE CARCINOGEN BY NTP, IARC, OR OSHA.
Effects of Overexposure:EYES:LIQ/VAP/MIST TEARING, STINGING,REDNESS.
SKIN:REDNESS, BURNING AND DRYING AND CRACKING OF SKIN.
INHALATION:NERVOUS SYSTEM DEPRESSION INCLUDING
DROWSINESS,DIZZINESS, LOSS OF COORDINATION AND FATIGU E;
ASTHMA-LOKE CONDITIONS. INGESTION:DROWSINESS, DIZZINESS,LOSS OF
COORDINATION AND FATIGUE; DIARRHEA, ASPIRATION HAZARD.
Medical Cond Aggravated by Exposure:PERSONS WITHPRE-EXISTING SKIN
DISORDERS, LUNG DISORDERS (LIKE ASTHMAS) MAY BE MORE SUSCEPTIBLE OR
MAYBE AGGRQVATED BY EXPO.
* First Aid Measures *
First Aid:HAVE DR CALL POIS CNTL.EYE:IRRIT/RED DVLPS MOVE AWAY FRM
EXPO,INTO FRESH AIR.SIGNS PERSISTS GET MED ATTN.DIRECT CONTACT HOLD
EYELIDS APART,FLUSH W/CLEAN H2O.GET MED ATTN.SKIN: REMOVE CONTAM
CLOTH.CLEA NSE AREA WELL W/MILD SOAP/H2O.IRRIT/RED DVLPS/PERSISTS
GET MED ATTN.INHAL:SYMPT DVLP MOVE AWAY FROM EXPO SOURCE,INTO FRESH
AIR.SYMPT PERSIST GET IMMED MED ATTN.NOT BREATH ADMIN ART
RESP;DIFFI BREATH A MIN OXY BY QUAL PERSONNEL.GET MED
ATTN.INGEST:ASPIRATION HAZ-DON?T INDUCE VOMIT OR GIVE ANYTHING BY
MOUTH---MATL CAN ENTER LUNGS & CAUSE SEVERE LUND DMG.IF
DROWSY/UNCONSC PLACE ON LEFT SIDE W/HEAD DOW N.DON?T LEAVE
UNATTENDED.GET MED ATTN.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1.0
Upper Limits:9.0
Extinguishing Media:EXTINGUISH WITH DRY CHEMICAL, CO2 OR A UNIVERSAL
TYPE FOAM.
Fire Fighting Procedures:THE USE OF A SCBA IS RECOMMENDED FOR FIRE
FIGHTERS. WATER SPRAY MAY BE USEFUL IN MINIMIZING VAPORS AND
COOLING CONTAINERS EXPOSED TO HEAT AND FLAME. AVOID SPREADING
BURNING LIQUID WITH WATER USED FORCOOLING PURPOSES.
Unusual Fire/Explosion Hazard:FLASHBACK ALONG VAPOR TRAIL MAY OCCUR.
THIS MATERIAL IS EXTREMELY FLAMMABLE AND MAY BE IGNITED BY HEAT,
SPARKS, FLAME OR STATIC ELECTRICITY
* Accidental Release Measures *
Spill Release Procedures:STAY UPWIND,AWAY FRM SPILL.KEEP ALL IGN
SOURCES AWAY.INDOORS VENTI AREA.UNIVERSAL TYPE FOAM MAY BE USED TO
SUPPRESS VAP.KEEP OUT OF DRAINS/SEWERS/H2OWAYS.USE SAND/OTHER INERT
MATL TO DAM/CONTAIN SPILL .DON?T FLUSH AREA W/2HO.SM SPILLS DON?T
FLUSH W/H2O;USE ABSORBANT PADS.CONTACT FIRE AUTHORITIES & APPROP
FED/STATE/LOC AGENCIES.SPILL IN EXCESS OF EPA RQ IS MADE INTO
ENVIRO (SEE OTHER INFO).
*Handling and Storage *
Handling and Storage Precautions:KEEP CNTNR COOL,DRY,AWAY FRM IGN
SOURCES.USE&STORE W/ADEQ VENTIL.KEEP WORKAREA FREE OF HOT METAL
SURF&OTHER IGN SOURCES.AVOID VAP INHAL&PERS CONTACT W/PROD.EMPTY
CNTNR RETAIN RESIDUE(LIQ7/OR VAP),CAN BE DANGEROUS.DON'T
PRESSURIZE,CUT,WELD,BRAZE,SOLDER,DRILL, GRIND,EXPO EMPTY CNTNR TO
(OTHER INFO)
* Physical/Chemical Properties *
HCC:F2
Vapor Density:2.9
Solubility in Water:NEGLIGIBLE (<5%)
Appearance and Odor:CLEAR, LITTLE IF ANY COLOR ;CHARACTERISTIC ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
THIS PRODUCT IS INCOMPATIBLE WITH STRONG ACIDS OR BASES, OXIDIZING
AGENTS AND SELECTED AMINES.
Hazardous Decomposition Products:COMBUSTION MAY YIELD CARBON MONOXIDE
AND/OR CARBON DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
* MSDS Transport Information *
* Regulatory Information *
SARA Title III Information:THIS PRODUCT CONTAINS THE FOLLOWING
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A
NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED.
CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK
AT HAND.
Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS
GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS.
Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE
GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL
Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS.
USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST
CREATION
Supplemental Safety and Health
GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING
ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR
MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE
REMOVED.
* Product Identification *
Preparer's Name:DOD HMIS/DGSC-SSH
* Composition/Information on Ingredients *
Ingred Name:ASBESTOS, CHRYSOTILE
OSHA PEL:0.2 FIBERS/CC
Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER COMPOSITION
Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE
CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR"
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN;
CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING,
FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE
TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA.
SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG
CANCER RISK!
Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS
OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA.
Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING
ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO
ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION
FROM AIRBORNE DUST; INGEST: N/K.
Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO
REPEATED INHALATION OF AIRBORNE FIBERS.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN:
WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF
IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A
PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING
DUST PARTICLES INTO OTHER AREAS
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE
TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES
INVOLVING CHEMICAL PRODUCTS.
Unusual Fire/Explosion Hazard:NONE KNOWN
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET
CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/
AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO
THE ATMOSPHERE.
*Handling and Storage *
Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE
FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL
PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!!
Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT
A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS &
DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME
AIRBORNE.
* Physical/Chemical Properties *
HCC:T6
Evaporation Rate & Reference:NONE
Solubility in Water:NOT SOLUBLE
Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS:
"ITEM-NAME"
Percent Volatiles by Volume:NONE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE KNOWN
* Disposal Considerations *
Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR
LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER
CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:NONE REQUIRED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MANUFACTURERS ADDRESS: NISHISHINJUKU 1 CHOME SHINJUKUKU. SPEC GRAV:
(COATING). (2.7 AS A WHOLE).
* Product Identification *
Preparer's Name:A. KATO
* Composition/Information on Ingredients *
Ingred Name:POLYCARBONATE
Fraction by Wt: <1%
Ingred Name:POLYACRYLATE FILM
Ingred Name:3-PINANONE, 2-HYDROXY-; (OPC COMPOUND)
Ingred Name:ORGANIC PIGMENT
Ingred Name:ALUMINUM
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:THE PRODUCT HAS BEEN EXTENSIVELY
TESTED AND EVALUATED BY KONICA CORPORATION. WHEN USED AS INTENDED,
IT DOES NOT PRESENT ANY KNOWN HEALTH OR SAFETY HAZARD.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION: REMOVE FROM EXPOSURE. SUPPORT BREATHING (GIVE
ARTIFICIAL RESPIRATION/OXYGEN). CALL MD . INGESTION: CALL MD
IMMEDIATELY . SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER . EYES:
* Fire Fighting Measures *
Extinguishing Media:WATER, FOAM OR CARBON DIOXIDE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVE SCBA & FULL PROTECTIVE
EQUIPMENT . WHEN IN MACHINE, TREAT AS ELECTRICAL FIRE, AND DO NOT
USE WATER OR FOAM.
Unusual Fire/Explosion Hazard:NONE AND NON-EXPLOSIVE.
* Accidental Release Measures *
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:NONE.
Other Precautions:AVOID EXPOSURE TO HIGH TEMPERATURES.
* Physical/Chemical Properties *
HCC:N1
Spec Gravity:1.2(SUPP DATA)
Solubility in Water:INSOLUBLE
Appearance and Odor:BLUE FILM WITH NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS.
Hazardous Decomposition Products:NONE.
* Disposal Considerations *
Waste Disposal Methods:THE WESTE BELTS TO NOT CONTAIN ANY DANGEROUS
SUBSTANCES, THEREFORE, THEY SHOULD BE DISPOSED OF IN SAME MANNER AS
WASTE PLASTICS. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS (FP N).
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATORY PROTECTION -
SELF-CONTAINED BREATHING APPARATUS WHEN EXPOSED TO HIGH
CONCENTRATIONS.
Ventilation:PROVIDE EXPLOSION-PROOF VENTILATION TO CONTROL VAPOR LEVEL.
ELIMINATE FIRE, SPARKS AND OPEN FLAME.
Other Protective Equipment:EYEWASH STATION AND SAFETY SHOWER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
* Product Identification *
Product ID:VISACLEAN SPRAY EYEGLASS CLEANER
* Composition/Information on Ingredients *
Ingred Name:PROPELLANT CONTAINING INGS 3 & 4
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:PROPANE
ACGIH TLV:ASPHYXIANT
Ingred Name:PROPANE, 2-METHYL-; (ISOBUTANE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:WATER
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:POLY(OXY-1,2-ETHANEDIYL)-,
ALPHA-SULFO-OMEGA-(NONYLPHENOXY)-,AMMONIUM SALT; (AMMONIUM
NONOXYNOL-4 SULFATE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SILICONE FLUID
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:MORPHOLINE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: LARGE QUANTITIES MAY CAUSE
FLUSHING, HEADACHE, DIZZINESS, NAUSEA & VOMITING. IF CAN IS
PUNCTURED & PROPELLANTS ARE RELEASED, BREATHING HIGH CONCENTRATIONS
OF PROPELLANTS MAY CAUSE AN ANESTHETIC EFFECT. INGEST: POSSIBLE
HEADACHE, RESTLESSNESS & NAUSEA. SKIN: PROLONGED CONTACT MAY CAUSE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: IRRITATION TO SKIN & MUCOUS MEMBRANE.
EYES: POSSIBLE IRRITATION, BURNING & STINGING.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR. INGEST: CONSIDERATION SHOULD BE
GIVEN FOR EMESIS OR ADVICE FROM HEALTH PROFESSIONAL DEPENDING ON
CLINICAL SITUATION. SKIN: REMOVE CONTAMINATED CLOTHING & WASH SKIN
THORO W/ MILD SOAP & WATER. IF SKIN IRRITATION PERSISTS, SEEK
ADVICE OF HEALTH PROFESSIONAL. EYES: IRRIGATE W/WATER FOR AT LEAST
PROFESSIONAL.
* Fire Fighting Measures *
Flash Point Method:CC
Lower Limits:2%
Extinguishing Media:FOAM, ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL,
WATER SPRAY.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . KEEP CONTAINERS COOL WITH WATER SPRAY AND IF
POSSIBLE REMOVE FROM FIRE AREA.
CAUSE BURSTING.
* Accidental Release Measures *
Spill Release Procedures:NOTIFY SAFETY PERSONNEL OF LEAKS/SPILLS.
REMOVE SOURCES OF HEAT OR IGNITION. STOP RELEASE & PROVIDE ADEQUATE
VENTILATION. COVER SPILLS W/INERT, NON-COMBUSTIBLE ABSORBENT
MATERIAL & REMOVE TO DISPOSAL CONTAINER. DO NOT CONTAMINATE WATER,
FOOD/FEED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY, WELL-VENT AREA OF
NON-COMBUSTIBLE CONSTRUCTION AWAY FROM EMER EXITS. DO NOT ALLOW
Other Precautions:POST "NO SMOKING OR OPEN FLAMES" SIGNS IN STORAGE
AREA. THERE SHOULD BE NO SOURCES OF IGNITION IN THE STORAGE OR USE
AREA. CONTAINERS MAY BURST WHEN INVOLVED IN FIRE SITUATION. UNLESS
LARGE QUANTITY I S INVOLVED, HAZARD IS NOT SIGNIFICANT.
SPRAYING). APPEAR/ODOR: W/SUFFICIENT FOAM TO CONFINE LIQ W/IN
SPRAYED AREA.
* Physical/Chemical Properties *
Vapor Density:2
Spec Gravity:SUPDAT
Evaporation Rate & Reference:CIRCA WATER (AFTER SPRAY)
Solubility in Water:SUPDAT
Appearance and Odor:CLEAR, COLORLESS TO WEAKLY YELLOW SOLN W/CHARACT
ODOR OF ISOPROPANOL (SUPDAT)
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:DO NOT STORE WHERE TEMPERATURES WILL
INCINERATE.
Hazardous Decomposition Products:NONE KNOWN.
* Disposal Considerations *
Waste Disposal Methods:FOR DISPOSAL, CANS SHOULD BE DESTROYED IN
MECHANICAL SHREDDER OR CRUSHED & THEN REMOVED TO APPROVED LANDFILL.
WASTE MATERIAL SHOULD BE DISPOSED OF IN ACCORDANCE WITH FEDERAL,
STATE & LOCAL ENVIRONMENT AL REGS VIA LICENSED WASTE DISPOSAL
COMPANY.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF ABOVE TLV, NIOSH/MSHA AIR SUPPLIED RESPIRATOR
ADVISED IN ABSENCE OF ENVIRONMENTAL CONTROL. OSHA REGS ALSO PERMIT
OTHER NIOSH/MSHA RESPIRATORS UNDER SPECIFIED CONDITIONS (SEE SFTY
EQUIP SUPPLIER).IM PLEMENT ENGINEER/ADMINISTRATIVE CONTROLS
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:TO PREVENT REPEATED OR PROLONGED SKIN
CONTACT, WEAR IMPERVIOUS CLOTHING AND BOOTS.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING, OR USING
WASHROOM.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:BJG
* Composition/Information on Ingredients *
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: 9%
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: 3%
Other REC Limits:NONE RECOMMENDED
Ingred Name:ETHYL ACETATE
Fraction by Wt: 5%
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: NASAL & RESP IRRIT, DIZZINESS,
FATIGUE, NAUSEA, HEADACHE, UNCONSCIOUS, ASPHYXIATION. SKIN:
PROLONGED/REPEATED: IRRITATION. ABSORPTION: POTENTIAL HAZARD. EYES:
SEVERE IRRIT, REDNESS, TEARING, BL URRED VISION. INGEST: GI
IRRITATION, NAUSEA, VOMITING, DIARRHEA, ASPIRATION INTO LUNGS CAN
CAUSE CHEMICAL PNEUMONITIS.
Effects of Overexposure:ACUTE: IRRITATION OF SKIN, EYES, MUCOUS
MEMBRANES, DRYING, DEFATTING OF SKIN. AVOID INGESTION AND BREATHING
OF VAPORS. CHRONIC: EYE, LIVER, KIDNEY, AND CENTRAL NERVOUS SYSTEM
DAMAGE MAY OCCUR.
Medical Cond Aggravated by Exposure:MAY PROVOKE ASTHMATIC RESPONSE IN
PERSON WITH ASTHMA WHO ARE SENSITIVE TO AIRWAY IRRITANT.
* First Aid Measures *
First Aid:IF SPILLED ON THE SKIN OR IN THE EYE, WASH WITH COPIOUS
QUANTITIES OF WATER, CONTACT PHYSICIAN IF SPILLED IN THE EYE(S). IF
INGESTED, DO NOT INDUCE VOMITING, KEEP PERSON WARM, QUIET AND
CONTACT PHYSIC IAN. BREATHING: REMOVE PERSON TO FRESH AIR. GIVE
OXYGEN IF BREATHING DIFFICULT; GIVE ARTIFICIAL RESPIRATION IF
BREATHING STOPS. KEEP PERSON WARM AND GET MEDICAL HELP.
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WITH A
FULL FACE PIECE OPERATED IN PRESSURE DEMAND OR OTHER POSITIVE
PRESSURE MODE WHEN FIGHTING FIRES.
Unusual Fire/Explosion Hazard:VAPOR HEAVIER THAN AIR MAY TRAVEL ALONG
GROUND OR BE MOVED BY VENT & IGNITED BY HEAT, PILOT LIGHTS, FLAME &
IGNITION SOURCES AT LOCATIONS DISTANT FROM SOURCE.
* Accidental Release Measures *
Spill Release Procedures:DIKE UP AND CONTAIN SPILL WITH INERT MATERIAL,
MOP UP & PLACE MATERIAL INTO CONTAINERS. PREVENT RUN-OFF TO SEWER,
STREAMS. NOTIFY AUTHORITIES.
*Handling and Storage *
Handling and Storage Precautions:DON'T STORE OR USE IN HIGH TEMPERATURE
AREAS, SPARKS, FLAME. KEEP CLOSURE TIGHT & CONTAINER UPRIGHT TO
PREVENT LEAK. STORE IN VENTED AREA.
Other Precautions:AVOID CONTACT WITH OR BREATHING OF VAPORS RELEASED
DURING CURING PROCESS. DO NOT TAKE INTERNALLY. AVOID CONTACT WITH
SKIN & EYES. AVOID BREATHING OF VAPOR & MIST. ALL HAZARD
PRECAUTIONS GIVEN IN MSDS MUST BE OBSERVED.
* Physical/Chemical Properties *
HCC:F2
Vapor Density:> AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NOT SOLUBLE
Appearance and Odor:BLUE VISCOUS LIQUIDS WITH LACQUER SOLVENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NEVER USE WELDING OR CUTTING TORCH ON/NEAR
DRUMS (EVEN EMPTY) BECAUSE PRODUCT (EVEN RESIDUE) CAN IGNITE
EXPLOSIVELY.
* Disposal Considerations *
Waste Disposal Methods:SMALL: ALLOW VOLATILE PART TO EVAPORATE IN HOOD.
ALLOW TIME TO COMPLETELY CLEAR HOOD DUCTS. DISPOSE OF REMAINING
MAT'L IN ACCORD W/REGS. LRG: DESTROY BY LIQ INCINERATION. CONTAM
ABSORB MAY BE DEPOSITE D IN LANDFILL IN ACCORD W/LOCAL, STATE,FED
REGS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED FULL-FACE ORG VAP
CARTRIDGE OR CANISTER RESPIRATOR WITHIN USE LIMITATIONS OF THESE
DEVICES; IN ALL OTHER SITUATIONS, USE NIOSH/MSHA APPRVD SCBA, WHEN
CONC EXCEED PEL OR ACGIH V ALUES AS SHOWN IN INGREDIENTS SECTION.
Ventilation:LOC EXHST: RECOM WHEN APPROP TO CNTRL EMPLOYEE EXPOS. MECH
(GEN): NOT RECOM AS SOLE MEANS OF CONTROLLING EMPLOYEE EXPOS.
Other Protective Equipment:FOR OPERS WHERE SPILLS/SPLASHING CAN OCCUR,
USE IMPERVIOUS BODY COVERING & BOOTS.SFTY SHOWER & EYE BATH SHOULD
BE AVAIL.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPILL PROCEDURE: AREA SPARINGLY WITH WATER OR USE AN ABSORBANT. AVOID
RUN-OFF INTO STORM SEWERS AND DITCHES WHICH LEAD TO NATURAL
WATERWAYS. ALL CLEAN-UP AND DISPOSAL SHOULD BE CARRIED OUT IN
ACCORDAN CE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ETHANOL, 2-ETHOXY-; (ETHYLENE GLYCOL MONOETHYL ETHER). VP:
ACGIH TLV:5 PPM, S
Ingred Name:2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (SARA
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE:PRIMARY IRRITATION. SKIN: PRIMARY
IRRITATION. INHALATION: ANESTHETIC. IRRITATION OF RESPIRATORY TRACT
OR ACUTE NERVOUS SYSTEM DEPRESSION CHARACTERIZED BY HEADACHE,
DIZZINESS, STAGGERING GAIT, CONF USION, UNCONSCIOUSNESS OR COMA.
ETHYLENE GLYCOL MONOETHYL ETHER APPEARS ON NAVY LISTING OF
OCCUPATIONAL(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HEALTH HAZARDS: CHEMICAL REPRODUCTIVE HAZARDS.
SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING
LATEST HAZARD LIST INFORMATION AND SAFE HANDLING AND EXPOSURE
INFORMATION .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
MINUTES. CONSULT PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. REMOVE
CONTAMINATED CLOTHING. CONSULT PHYSICIAN IF IRRITATION PERSISTS.
INHALATI ON: REMOVE TO FRESH AIR. RESTORE BREATHING. TREAT
SYMPTOMS. CONSULT PHYSICIAN. INGESTION: DRINK WATER TO DILUTE. DO
NOT INDUCE VOMITING. CONSULT PHYSICIAN OR POISON CONTROL CENTER
IMMEDIATELY.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1%
Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
WATER MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILDUP & POSS
AUTOIGNIT. IF WATER USED, FOG NOZZ PREF.
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, SPARKS, ELECTRICAL EQUIP & OPEN FLAME. CLSD CNTNRS MAY EXPLO
WHEN EXPOS TO EXTREME HEAT. DO NOT APPLY TO HOT SURFS.
* Accidental Release Measures *
Spill Release Procedures:AVOID EYE/SKIN CONT. PLACE LEAKING CNTNRS IN
WELL-VENT AREA. ELIM IGNIT SOURCES. IF FIRE POTNTL EXISTS, BLANKET
SPILL W/FOAM/USE WATER SPRAY TO DISPERSE VAPS. CONTAIN SPILL TO MIN
CONTAMD AREA & FACIL ITATE SALVAGE/DISP. TO CLEAN SPILL, FLUSH
(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
QUANTITIES IN BUILDINGS DESIGNED FOR STORAGE OF NFPA CLASS IC
FLAMMABLE LIQUIDS.
Other Precautions:DO NOT TAKE INTERNALLY. CONTAINERS SHOULD BE GROUNDED
WHEN POURING. AVOID FREE FALL OF LIQUIDS IN EXCESS OF FEW INCHES.
DO NOT FLAME CUT, BRAZE, OR WELD WITHOUT MSHA OR NIOSH APPROVED
RESPIRATOR OR AP PROPRIATE VENTILATION.
* Physical/Chemical Properties *
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:HONEY LIKE CONSISTENCY.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY PRDCE HAZ FUMES WHEN HEATED TO
DECOMP AS IN WELDING. FUMES MAY CONTAIN CARBON MONOXIDE AND OXIDES
OF NITROGEN.
* Disposal Considerations *
Waste Disposal Methods:RECOVERED LIQS MAY BE SENT TO LICENSED RECLAIMER
OR INCIN FACILITY. CONTAMD MATL MUST BE DISP OF IN A PERMITTED
WASTE MANAGEMENT FACILITY. CONSULT FEDERAL, STATE, OR LOCAL
DISPOSAL AUTHORITIES FOR APP RVD PROCS. DISP I/A/W FED, ST,& LOC
REGS .
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED FOR CONDITIONS WHERE EXPOSURE TO
DUST IS APPARENT, A DUST/MIST RESPIRATOR MAY BE WORN. FOR
EMERGENCIES WEAR SELF CONTAINED BREATHING APPARATUS
Ventilation:LOCAL EXHAUST:CAPTURES CONTAMINANT AT ITS SOURCE IS
RECOMMENDED TO PREVENT DISPERSION OF CONTAMINANT INTO WORKROOM AIR.
Other Protective Equipment:CLEAN BODY COVERING, EYE WASH FOUNTAIN,
QUICK DRENCH FACILITIES
Work Hygienic Practices:WASH THROUGHLY AFTER HANDLING.
Supplemental Safety and Health
* Product Identification *
CAGE:0STM5
* Composition/Information on Ingredients *
Ingred Name:POTASSIUM CHLORIDE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN: IRRITATION. EYES: IRRITATION.
INHALATION: NASAL, LUNG IRRITATION. INGESTION: GASTROINTEST
INAL IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INGESTION: WEAKNESS, VOMITING, CIRCULATORY
PROBLEMS. EYES: REDNESS, TEARING, ABRASION SKIN: RASH.
Medical Cond Aggravated by Exposure:IMPAIRED KIDNEYS
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IF
BREATHING IS DIFFICULT. INGESTION: GIVE SEVERAL GLASSES OF WATER TO
DRINK. SKIN: REMOVE CONTAMINATED CLOTHING. WASH W/PLENTY OF WATER
OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:USE MEANS SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & NIOSH APPROVED
SELF CONTAINED BREATHING APPARATUS W/FULL FACEPIECE OPERATED THE
PRESSURE DEMAND/OTHER POSITIVE MODE.
* Accidental Release Measures *
Spill Release Procedures:SWEEP, SCOOP OR PICK UP SPILLED MATERIAL.
COLLECTED WASTE MAY BE TRANSFERRED TO A CLOSED, PREFERABLY METAL,
CONTAINER & SENT TO AN APPROVED WASTE DISPOSAL FACILITY.
*Handling and Storage *
Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER,
STORED IN A COOL DRY VENTILATED AREA. PROTECT AGAINST PHYSICAL
DAMAGE.
Other Precautions:CONTACT LENSES SHOULD NOT BE WORN.
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:SUPP
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS OR WHITE CRYSTALS W/NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
BROMINE TRIFLUORIDE, POTASSIUM PERMANGANATE, SULFURIC ACID
Hazardous Decomposition Products:OXIDES OF CONTAINED METAL & HALOGEN,
FREE IONIC HALOGEN
* Disposal Considerations *
Waste Disposal Methods:ENSURE COMPLIANCE W/LOCAL, STATE & FEDERAL
REGULATIONS.
| 1 | gloves_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: EYE: CAUSES IRRIT, REDNESS, TEARING & BLURRED
VISION. SKIN: MAY CAUSE IRRIT, REDNESS, EDEMA & DERM. MAY BE ABSORBED
THRU SKIN CAUSING HDCHS, DIZZ, NAUS & DECR BLOOD PRESS. MAY CAUSE SKIN
SENSIT . INHAL: EXCESS INHAL OF VAPS MAY CAUSENASAL & RESP IRRIT, CNS
EFTS INCL DIZZ, WEAK, FATG, NAUS, HDCH,(EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: CONVLS, DFCLTY IN BRTHG, VISUAL
IMPAIRMENT, POSSIBLY LEADING TO UNCON, ASPHY & DEATH. MAY BE ABSORBED
THRU LUNGS. INGEST: MAY CAUSE GI IRRIT, NAUS, VOMIT, DIARR & ABDOM PAIN.
INGEST & SUBSEQ UENT VOMIT OF THIS PROD CAN LEAD TO ASPIR OF SOLV INTO
LUNGS, WHICH COULD CAUSE DMG & COULD BE FATAL. CHRONIC: (SUPDAT)
Medical Cond Aggravated By Exposure: PRE-EXISTING LIVER AND KIDNEY DISEASES.
First Aid: INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, CLEAR AIRWAY & START
MOUTH-TO-MOUTH ARTF RESP. GET IMMED MED ATTN. EYE: IMMED RINSE W/WATER.
EYELIDS APART TO ENSURE RINSING OF ENTIRE SURF OF EYES & LIDS W/WATER.
REMOVE CONTAMD CLTHG & SHOES. GET IMMED MED ATTN.
*
Handling and Disposal
*
Spill Release Procedures: ELIMINATE ALL SOURCES OF IGNIT & VENTILATE AREA.
STOPE LEAK & CONTAIN SPILL. USE INERT ABSORBANT MATERIAL, PLACE SPILLED
MATERIAL INTO LABELED CONTAINER FOR PROPER DISPOSAL.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND
LOCAL REGULATIONS.
AWAY FROM IGNIT SOURCES. STORE INDOORS/LAY CNTNRS ON THEIR SIDES FOR OUTDOOR
STORAGE.
Other Precautions: KEEP CNTNR CLSD WHEN NOT IN USE. KEEP OUT OF REACH OF
CHILDREN. READ ENTIRE LBL BEFORE USING PROD. IF UE (USE EXEMPTION) APPEARS
UNDER UPPER % LIMIT, END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE PRO D IS
USED & LBLD FOR ROUTINE
*
Fire and Explosion Hazard Information
*
Flash Point Method: TCC
Lower Limits: 0.7%
Upper Limits: 7.0%
Extinguishing Media: FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures: NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). WATER
MAY BE USED TO COOL EXPOSED CNTNRS. WATER MAY CAUSE SPLATTERING. MATL MAY
FLOAT ON WATER.
Unusual Fire/Explosion Hazard: VAPS ARE HVR/AIR & MAY ACCUM IN LOW
AREAS/AREAS INADEQUATELY VENTILATED. VAPS MAY ALSO TRAVEL ALONG GROUND TO BE
IGNITED AT LOCATIONS DISTANT FROM HNDLG SITE.
*
*
Respiratory Protection: TYPICAL USE DOES NOT REQ RESPS. HOWEVER, WEAR NIOSH
APPROVED RESPIRATOR IF EXPOSURE LEVELS ARE ABOVE THE RECOMMENDED EXPOSURE
LIMITS.
Ventilation: TYPICAL USE OF THIS PRODUCT DOES NOT REQUIRE SPECIAL VENT. GENERAL
EXHAUST IS SUFFICIENT.
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: USERS OF "L" VERSION OF SHOULD CONSULT WITH
"LR" VERSION FOR ADDNL INFO (FP N). EFTS OF OVEREXP: INHAL: MAY LEAD TO
KIDNEY & LIVER DMG. TARGET ORGANS: CNS, KIDNEYS. HYDROXYETHYLATED
AMINOETHYLAMI DE: LIFETIME SKIN PAINTING STUDIES W/PRODS SIMILAR TO KEROSENE
USUALLY PRDCE SKIN TUMORS & SKIN CANCER IN LAB
*
Physical/Chemical Properties
*
Vapor Pres: 5.0
Vapor Density: 4.7
Solubility in Water: INSOLUBLE
Appearance and Odor: CLEAR OPAQUE, OCTYL NITRATE ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: HEAT, SPARKS, HOT SURFACES AND OPEN FLAMES.
Materials To Avoid: OXIDIZERS, REDUCING AGENTS, HALOGENS & HALOGENATED
COMPOUNDS.
Hazardous Decomposition Products: OXIDES OF CARBON AND NITROGEN, ALDEHYDES,
SMOKE AND FUMES, FREE AROMATIC AMINES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE SPECIFIED BY MANUFACTURER.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: CERTIFIED LABS
Street: UNKNOWN
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EYE: CAUSES IRRIT, REDNESS, TEARING &
BLURRED VISION. SKIN: MAY CAUSE IRRIT, REDNESS, EDEMA & DERMATITIS. MAY
BE ABSORBED THRU SKIN CAUSING HEADACHES, DIZZINESS, NAUSEA & DECREASED
BLOOD PRESS.INHAL: EXCESSIVE INHAL OF VAPORS MAY CAUSE NASAL &
RESPIRATORY IRRIT, CNS EFTS INCLUDE DIZZINESS, WEAKNESS, FATG, NAUSEA,
HEADACHE, CONVULSIONS, DIFFICULTY BREATHING, VISUAL IMPAIRMENT, POSS LEADING
TO UNCON, ASPHYXIATION AND DEATH. INGEST: MAY CAUSE GI IRRIATION, NAUSEA,
VOMITING, DIARRHEA AND ABDOM PAIN. ASPIR HAZARD. CHRONIC: INHAL: MAY LEAD TO
LIVER AND KIDNEY DAMAGE. TARGET ORGANS: CNS, KIDN EYS. MAY CAUSE SKIN
SENSITIZATION.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:LOCAL EXHAUST PREFERABLE,MECHANICAL ACCEPTABLE.
Other Protective Equipment:CLEAN LONG LEGGED & SLEEVED CLOTHING
Supplemental Safety and Health
* Product Identification *
Product ID:PHILLYBOND,6 HARDENER
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:SILICA, AMORPHOUS, DUST
OSHA PEL:6 MG/M3
Ingred Name:CARBON BLACK
OSHA PEL:3.5 MG/M3
Ingred Name:TALC (CONTAINING NO ASBESTOS)
OSHA PEL:2 MG/M3 RDUST
Ingred Name:PHENOL
OSHA PEL:S, 5 PPM
* Hazards Identification *
Effects of Overexposure:SKIN-IRRIT,SENSITIZER
* First Aid Measures *
WATER IMMEDIATELY
* Fire Fighting Measures *
Extinguishing Media:CO*2,FOAM,DRY CHEMICALS,WATER
Fire Fighting Procedures:NONE PER MFR
Unusual Fire/Explosion Hazard:NONE KNOWN PER MFR
* Accidental Release Measures *
Spill Release Procedures:WIPE UP WITH CLEAN RAGS.RESIDUE MAY BE CLEANED
W/ SOLVENT DAMPENED RAG.
*Handling and Storage *
Handling and Storage Precautions:AVOID BREATHING VAPORS AND AVOID SKIN
CONTACT.
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:N/K PER MFR
Spec Gravity:2
Evaporation Rate & Reference:NON-VOLATILE
Solubility in Water:N/K PER MFR
Appearance and Odor:BLACK,AMINE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS & BASES
Hazardous Decomposition Products:CO,CO*2,OXIDES OF N*2
Conditions to Avoid Polymerization:UNCONTROLLED AMOUNTS OF EPOXY RESIN
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE &
LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:LOCAL VENTILATION
Supplemental Safety and Health
MATERIALS TO AVOID CONT'D: NITRATES & SALTS OF METALS, IRON, COPPER,
ZINC.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:EPINEPHRINE
Ingred Name:HYDROCHLORIC ACID, HYDROGEN CHLORIDE, MURIATIC ACID
HYDROCHLORIDE
Other REC Limits:7 PPM
OSHA PEL:5 PPM
Ingred Name:SODIUM CITRATE
Ingred Name:CITRIC ACID, MONOHYDRATE
Ingred Name:SODIUM CHLORIDE
Fraction by Wt: 0.6%
Ingred Name:SODIUM BISULFATE, SODIUM HYDROGEN SULFATE
Fraction by Wt: 0.1%
Ingred Name:WATER
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PERICARDIAL DISTRESS, PULMONARY EDEMA,
FATAL CARDIAC ARRHYTHMIAS, KIDNEY FAILURE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:VOMITING, HEADACHE, DYSPNEA, ELEVATED BLOOD
PRESSURE, TRANSIENT BRADYCARDIA, TACHYCARDIA, MULTIFOCAL
VENTRICULAR TACHYCARDIA RHYTHM, ATRIAL TACHYCARDIA,
ATRIOVENTRICULAR BLOCK, PALLOR, COLDNESS, METAB OLIC ACIDOSIS,
CONSTRICTION OF RENAL BLOOD VESSELS, DECREASE URINE FORMATION.
* First Aid Measures *
First Aid:SKIN: WASH W/MILD SOAP & COPIOUS AMOUNTS OF WATER. EYES:
FLUSH W/COPIOUS AMOUNTS OF WATER. TREATMENT: MOST TOXIC EFFECTS CAN
BE COUTERACTED BY INJECTION OF AN ALPHA-ADRENERGIC BLOCKER &
BETA-ADRENERGI C BLOCKER, NOROPINEPHRINE. RAPIDLY ACTING
ALPHA-ADRENERGIC BLOCKING DRUG. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
* Fire Fighting Measures *
Extinguishing Media:WATER, CO2, DRY CHEMICAL, FOAM.
* Accidental Release Measures *
Spill Release Procedures:ABSORB ONTO PAPER. WASH SITE W/COPIOUS AMOUNTS
OF WATER.
* Physical/Chemical Properties *
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR, COLORLESS, ODORLESS SOLUTION.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ALKALIES/OXIDIZING AGENTS, SODIUM BICARBONATE, HALOGENS, PERMANGANATES,
CHROMATES, NITRATES (SEE SUPP)
* Disposal Considerations *
Waste Disposal Methods:APPROVED CHEMICAL WASTE INCINERATION/APPROVED
AQUEOUS DISCHARGE TO MUNICIPAL/ON-SITE WASTE-WATER TREATMENT
SYSTEMS. DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: HLTH STUDIES HAVE SHOWN THAT MANY PETRO HYDROCARBONS &
SYNTHETIC LUBRICANTS POSE POTENTIAL HUMAN HLTH RISKS WHICH MAY VARY FROM PERS
TO PERS. AS PREC, EXPOS TO LIQS, VAPS, MISTS/FUMES SHOULD BE MIN. A
CUTE/CHRONIC: PRLNG/RPTD SKIN CONT MAY CAUSE IRRIT. PRLNG/RPTD SKIN CONT
W/THIS PROD TENDS TO REMOVE (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: SKIN OILS, POSS LEADING TO IRRIT
& DERM; HOWEVER, BASED ON HUMAN EXPERIENCE & AVAIL TOX DATA, THIS
PROD IS JUDGED TO BE NEITHER "CORR" NOR "IRRIT" BY OSHA CRITERIA. PROD
CONTACTING EYES MAY CAUSE IRRIT. PROD HAS LOW ORDER OF ACUTE ORAL &
DERMAL TOX, BUT MIN AMTS ASPIRATED INTO LUNGS DURING INGEST/
Medical Cond Aggravated By Exposure: NONE RECOGNIZED.
IF IRRIT PERSISTS, CALL MD. SKIN: REMOVE ANY CONTAM CLTHG & WASH SKIN
W/SOAP & WATER. LAUNDER/DRY-CLEAN CLTHG BEFORE REUSE. IF PROD I S
INJECTED INTO/UNDER SKIN/INTO ANY PART OF BODY, REGARDLESS OF APPEAR OF
WOUND/ITS SIZE, INDIVIDUAL SHOULD BE EVALUATED IMMED BY MD AS SURGICAL EMER.
EVEN THOUGH INITIAL SYMPS FROM HIGH
*
Handling and Disposal
*
Spill Release Procedures: RECOVER FREE PROD. ADD SAND, EARTH/OTHER SUITABLE
ABSORB TO SPILL AREA. MIN BRTHG VAPS & SKIN CONT. OPEN ALL WINDOWS &
DOORS. KEEP PROD OUT OF SEWERS & WATERCOURSES BY DIKING/IMPOUNDING.
ADVISE AUTH I F PROD HAS ENTERED/MAY ENTER SEWERS,
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS (FP N).
Handling And Storage Precautions: "EMPTY" CONTAINER WARNING: "EMPTY" CONTAINERS
RETAIN RESIDUE (LIQUID AND/OR VAPOR) AND CAN BE DANGEROUS. AVOID PRLNG/RPTD
CONT W/SKIN.
Other Precautions: DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND/EXPOSE SUCH CONTRS TO HEAT, FLAME, SPKS, STATIC ELEC/OTHER SOURCES OF
IGNITION; THEY MAY EXPLODE & CAUSE INJURY/DEATH. DO NOT ATTEMPT TO CLEAN
SINCE RESIDUE IS DFCLT TO
*
Fire and Explosion Hazard Information
*
Flash Point Method: COC
Extinguishing Media: FOAM, WATER SPRAY (FOG), DRY CHEM, CARBON DIOXIDE &
VAPORIZING LIQ TYPE EXTING AGENTS, DEPENDING ON SIZE OR (SUP DAT)
Fire Fighting Procedures: WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
USE WATER TO KEEP FIRE-EXPOSED CONTRS COOL. IF LEAK/SPILL HAS NOT IGNITED,
USE WATER SPRAY TO DISPERSE
Unusual Fire/Explosion Hazard: FUMES, SMOKE, CARBON MONOXIDE, SULFUR OXIDES,
NITROGEN OXIDES, ALDEHYDES AND OTHER DECOMPOSITION PRODUCTS, IN THE CASE OF
INCOMPLETE COMBUSTION.
*
*
Respiratory Protection: USE NIOSH APPROVED SUPPLIED-AIR RESPIRATORY PROTECTION
IN CONFINED OR ENCLOSED SPACES, IF NEEDED. MINIMIZE BREATHING VAPOR,
MIST/FUMES.
Ventilation: USE LOC EXHST TO CAPTURE VAP, MISTS/FUMES, IF NEC. PROVIDE VENT
SUFFICIENT TO PVNT EXCEEDING REC EXPOS LIM OR
Other Protective Equipment: ANSI APPRVD EMER EYEWASH & DELUGE SHOWER (FP N).
USE CHEM-RESIST APRON/OTHER IMPERVIOUS CLTHG, IF NEEDED, TO
Work Hygienic Practices: REMOVE CONTAM CLTHG; LAUNDER/DRY-CLEAN BEFORE REUSE.
REMOVE CONTAM SHOES & THORO CLEAN BEFORE REUSE; DISCARD
Supplemental Safety and Health: USERS OF "L" VERSION OF SHOULD CONSULT "LR"
VERSION FOR ADDNL INFO (FP N). EXTING MEDIA: POTENTIAL SIZE OF FIRE &
CIRCUMSTANCES RELATED TO SITUATION. PLAN FIRE PROT & RESPONSE STRATEGY
THRU CONSU LT W/LOC FIRE PROT AUTH/APPROP SPECIALISTS. MATLS TO AVOID: AS
THIS PRESENTS A SERIOUS EXPLOSION HAZARD.
*
Physical/Chemical Properties
*
Vapor Density: >5
PH: NEUT
Solubility in Water: NEGLIGIBLE;
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER
Percent Volatiles by Volume: NEGLIG
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: AVOID CONT W/STRONG OXIDANTS SUCH AS LIQ CHLORINE, CONC
OXYGEN, SODIUM HYPOCHLORITE, CALCIUM HYPOCHLORITE, ETC,(SUP DAT)
Hazardous Decomposition Products: NONE SPECIFIED BY MANUFACTURER.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: EXXON CO USA
Label Required IND: Y
Status Code: C
Origination Code: G
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: SKIN: IRRITATION; DERMATITIS. EYES: IRRITATION.
INGESTION: LOW ORDER OF ACUTE ORAL AND DERMAL TOXICITY. ASPIRATION HAZARD.
VOMITING MAY CAUSE MILD TO SEVERE PULMONARY INJURY AND POSSIBLY DEATH.
CHRONIC: NONE SPECIFIED BY MANUFACTURER.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
0.1 MG/CUM, A HALF-MASK AIR PURIFYING RESPIRATOR EQUIPPED W/HIGH
EFFECIENCY PARTICULATE FILTERS SHOULD BE USED
Ventilation:SUFFICIENT LOCAL EXHAUST
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING/SHOES
BEFORE REUSE. WASH HANDS BEFORE EATING, DRINKING, SMOKING OR AFTER
WORK.
Supplemental Safety and Health
MG/KG FOR EACH INJECTION - DAY 1 & 2, EVERY 4 HOURS; DAY 3, EVERY 6
ING HAS NOT ALREADY OCCURRED. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
* Product Identification *
Preparer's Name:TERI MUCHOW
CAGE:WOODC
CAGE:WOODC
* Composition/Information on Ingredients *
Ingred Name:ARSENIC ACID
OSHA PEL:0.5 MG/CUM
ACGIH TLV:0.2 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:CHROMIC ACID (SOLID OR SOLUTION), CRO3, CHROMIUM (VI)
OXIDE,CR-O3 (A1 CARCINOGEN)
OSHA PEL:0.1 MG/CUM (CRO3)
Ingred Name:COPPER OXIDE
Fraction by Wt: 9%
OSHA PEL:1 MG/CUM
ACGIH TLV:1 MG/CUM
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SOLUTION IS HIGHLY CORROSIVE. SKIN:
SEVERE BURNS, ULCERS, HIGHLY IRRITATING, DERMATITIS. EYES: SEVERE
BURNS, HIGHLY IRRITATING. INHALATION: HIGHLY IRRITATING & CHEMICAL
PNEUMONITIS. INGESTION: GASTROE NTERITIS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INGESTION: ESOPHAGEAL PAIN, VOMITING, ANURIA &
OLIGURIA.
Medical Cond Aggravated by Exposure:SKIN, KIDNEY, LIVER, LUNGS OR
NERVOUS SYSTEM
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. EYES:
FLUSH W/PLENTY OF WATER. SKIN: FLUSH W/PLENTY OF WATER. INGESTION:
DON'T INDUCE VOMITING. IF CONSCIOUS, GIVE ONE GLASS OF MILK,
PREFERABLY CON TAINING 2 OUNCES OF MILK OF MAGNESIA OR3 EGG WHITES
OR GIVE LIME WATER OR 1 TBS SALT IN WARM WATER; INDUCE VOMITING.
NOTE TO PHYSICIAN: TREAT FOR ARSENIC PENTOXIDE & CHROMIUM TRIOXIDE.
(SEE SUPP)
* Fire Fighting Measures *
Extinguishing Media:WATER FOG, CO2
Fire Fighting Procedures:WEAR FULL-FACE MSHA/NIOSH APPROVED
AQUEOUS SOLUTION. POISON.
Unusual Fire/Explosion Hazard:MAY CAUSE FIRE ON CONTACT W/COMBUSTIBLE
MATERIALS. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME
HEAT/FIRE.
* Accidental Release Measures *
Spill Release Procedures:AVOID CONTACT W/SOLUTION. PREVENT SPREAD.
RECOVER/NEUTRALIZE FREE STANDING LIQUID. COLLECT ABSORBENT &
CONTAMINATED SOIL IN DOT APPROVED CONTAINERS. MATERIAL IS TOXIC TO
FISH/WILDLIFE. DON'T ALLOW IT TO CONTAMINATE WATERWAYS.
Neutralizing Agent:OSMOSE NEUTRALIZING COMPOUND OR SAWDUST
*Handling and Storage *
Other Precautions:ENGINEERING CONTROLS ARE THE PREFERRED METHOD FOR
CONTROLLING EXPOSURE TO CHEMICALS. IF ENGINEERING CONTROLS ARE NOT
FEASIBLE, THEN PERSONAL PROTECTIVE EQUIPMENT SHOULD BE UTILIZED.
READ PRODUCT LABEL .
* Physical/Chemical Properties *
pH:<1
Solubility in Water:COMPLETE
Appearance and Odor:DARK RED-ORANGE LIQUID W/NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG REDUCING/OXIDIZING AGENTS; ALUMINUM & ZINC IN AN ACID MEDIUM
Stability Condition to Avoid:HEAT/FIRE
Hazardous Decomposition Products:ALUMINUM & ZINC SUCH AS GALVANIZED
STEEL; ARSINE MAY BE GENERATED. ARSENIC.
* Disposal Considerations *
Waste Disposal Methods:EXCESS CHEMICAL/WASTE MATERIAL COLLECTED MUST BE
DISPOSED OF IN APPROVED HAZARDOUS WASTE DISPOSAL SITE IN ACCORDANCE
W/FEDERAL, STATE & LOCAL REGULATIONS. CONTAINERS MAY BE TRIPLE
RINSED/BURIED IN SAN ITARY LANDFILL/REMOVED TO DRUM RECLAIMER.
| 1 | gloves_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Item Description Information
*
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: MAY BE HARMFUL BY INHALATION, INGESTION OR SKIN
ABSORPTION. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. MATERIAL MAY
BE IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
First Aid: EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST
WASH CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: REMOV E TO FRESH AIR. IF
NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE
OXYGEN. INGESTION: WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL MD.
*
Handling and Disposal
*
Spill Release Procedures: WEAR NIOSH APPROVED RESPIRATOR, CHEMICAL SAFETY
AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND WASH SPILL
SITE AFTER MATERIAL PICKUP IS COMPLETE.
Waste Disposal Methods: DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT
AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
Handling And Storage Precautions: AVOID INHALATION. AVOID CONTACT WITH EYES,
SKIN AND CLOTHING. AVOID PROLONGED AND REPEATED EXPOSURE. KEEP TIGHTLY
CLOSED. STORE IN A COOL, DRY PLACE.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TO
SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N).
*
*
Respiratory Protection: NIOSH APPROVED RESPIRATOR.
Ventilation: MECHANICAL EXHAUST REQUIRED.
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
*
Physical/Chemical Properties
*
Appearance and Odor: LIQUID.
*
Reactivity Data
*
Stability Indicator: YES
Materials To Avoid: STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: NATURE OF DECOMPOSITION PRODUCTS NOT KNOWN.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
*
Toxicological Information
*
Toxicological Information: TO THE BEST OF MFR'S KNOWLEDGE, THE CHEMICAL,
PHYSICAL AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
*
Ecological Information
*
Ecological: DATA NOT YET AVAILABLE.
*
*
Transport Information: CONTACT FLUKA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
*
Regulatory Information
*
Federal Regulatory Information: EUROPEAN INFORMATION: CAUTION: SUBSTANCE NOT
YET FULLY TESTED.
*
HAZCOM Label
*
Company Name: FLUKA CHEMICAL CORP
Label Required IND: Y
Status Code: A
Origination Code: F
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: MAY BE HARMFUL BY INHALATION, INGESTION OR SKIN
ABSORPTION. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. MATERIAL MAY
BE IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. CHRO NIC: NONE
LISTED BY MANUFACTURER.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOS LIMIT IS EXCEEDED, A NIOSH APPRVD FULL
FACEPIECE RESP W/HIGH EFFICIENCY DUST/MIST FILTER MAY BE WORN UP TO
AGENCY/RESP SUPPLIE R, WHICHEVER IS LOWEST. FOR EMER/INSTANCES
WHERE EXPOS LEVELS ARE NOT KNOWN, USE NIOSH APPRVD FULL-FACEPIECE
POS-PRESS AIR-SUPPLIED RESP. WARNING: (OTHER INFO)
Ventilation:SYS OF LOC AND/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS
BELOW AIRBORNE EXPOS LIMITS. LOC EXHST VENT IS GENERALLY PREF
(OTHER INFO)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR IMPERVIOUS CLTHG, INCL BOOTS, LAB COAT, APRON OR COVERALLS, AS
APPROP TO PVNT SKIN CONT.
Work Hygienic Practices:WASH CLOTHING BEFORE REUSE. WASH THOROUGHLY
AFTER HANDLING.
Supplemental Safety and Health
SPILL PROC: SUCH AS SAW DUST. DO NOT FLUSH TO SEWER. US REGS (CERCLA)
REQ RPTG SPILLS & RELEASES TO SOIL, WATER & AIR IN EXCESS OF
REPORTABLE QTYS. TOLL FREE NUMBER FOR US COAST GUARD NATL RESPONSE
FED, STATE & LOC REQUIREMENTS. PH: 1.5(0.1 N AQUEOUS SOLN).
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:PHOSPHORIC ACID
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
ACGIH STEL:3 MG/M3
Ingred Name:WATER
Minumum % Wt:5.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: IS NOT AN EXPECTED
HAZARD UNLESS MISTED OR HEATED TO HIGH TEMPERATURES. MIST OR VAPOR
INHALATION CAN CAUSE IRRITATON TO THE NOSE, THROAT, AND UPPER
RESPIRATORY TRACT. SEVERE EXPOSUR ES CAN LEAD TO CHEMICAL
PNEUMONITIS. INGESTION: CORROSIVE. MAY CAUSE SORE THROAT, ABDOMINAL
PAIN, NAUSEA, AND SEVERE BURNS OF THE MOUTH, THROAT, AND STOMACH.
SEVERE EXPOSURES CAN LEAD TO SHOCK, CIRCUL ATORY COLLAPSE, AND
DEATH. SKIN CONT: CORROSIVE. MAY CAUSE REDNESS, PAIN, AND SEVERE
SKIN BURNS. EYE CONT: CORROSIVE. MAY CAUSE REDNESS, PAIN, BLURRED
VISION, EYE BURNS, AND (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZS: PERMANENT EYE DAMAGE. CHRONIC: NO
INFORMATION FOUND.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE EXISITING SKIN
DISORDERS OR EYE PROBLEMS, OR IMPAIRED RESPIRATORY FUNCTION MAY BE
MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE OXYG. CALL PHYS IMMED. INGEST: DO NOT INDUCE
VOMIT. GIVE LG QTYS OF WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON
PERSO N. GET MED ATTN IMMED. SKIN CONT: IMMED FLUSH W/PLENTY OF
PHYS IMMED. WASH CLTHG BEFORE REUSE. EYE CONT: IMMED FLUSH W/GENTLE
EYELIDS OCCASIONALLY. CALL PHYS IMMED.
* Fire Fighting Measures *
Extinguishing Media:FIRE: NOT CONSIDERED TO BEFIRE HAZARD. CONTACT
WITH MOST METALS CAUSES FORMATION OF FLAMM AND EXPLOSIVE HYDROGEN
GAS. USE ANY MEDIA SUITABLE FOR EXTINGUISHING SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS
COOL. IF WATER IS USED, USE IN ABUNDANCE TO CONTROL HEAT AND ACID
BUILD-UP.
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA OF LEAK/SPILL. WEAR APPROP
PERSONAL PROT EQUIP AS SPECIFIED IN EXPOSURE CONTROLS/PERSONAL PROT
SECTION. ISOLATE HAZARD. KEEP UNNEC & UNPROTECTED PERS FROM
ENTERING. CNTN & RECOVER LIQ W HEN POSS. NEUT W/ALKALINE MATL (SODA
ASH LIME) THEN ABSORB W/INERT MATL (E.G. VERMICULITE, DRY SAND,
EARTH), & PLACE IN CHEM WASTE CNTNR. DO NOT USE COMBUST MATLS,
(SUPDAT)
Neutralizing Agent:J.J. BAKER NEUTRASORB(TM) OR TEAM(TM) 'LOW NA+' ACID
NEUTRALIZERS ARE RECOMMENDED FOR SPILLS OF THIS PRODUCT.
*Handling and Storage *
Handling and Storage Precautions:KEEP IN TIGHTLY CLSD CNTNR. PROTECT
FROM PHYSICAL DMG. STORE IN COO, DRY, VENTILATED AREA AWAY FROM
SOURCES OF HEAT,MOISTURE, INCOMPATIBILITIES, & DIRECT SUNLIGHT.
FOR PHOSPHORIC ACID. DO NOT WASH OUT CNTNR & USE FOR OTHER
PURPOSES.
Other Precautions:WHEN DILUTING, ACID SHOULD ALWAYS BE ADDED SLOWLY TO
WATER & IN SM AMTS. NEVER USE HOT WATER & NEVER ADD WATER TO ACID.
WATER ADDED TO ACID CAN CAUSE UNCONTROLLED BOILING & SPLASHING.
PROTECT FROM FRE EZING. CNTNRS OF MATL MAY BE HAZ WHEN EMPTY SINCE
THEY RETAIN PROD RESIDUES(VAPS, LIQ): OSBSERVE ALL(OTHER INFO)
* Physical/Chemical Properties *
Vapor Density:3.4
pH:SUPDAT
Evaporation Rate & Reference:NO INFORMATION FOUND
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR, COLORLESS SYRUPY LIQUID. ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
LIBERATES EXPLO HYDROGEN GAS WHEN REACTING W/CHLORIDES & STAINLESS
STEEL. CAN REACT VIOLENTLY W/SODIUM TETRAHYDROBORATE. EXOTHERMIC
RXNS W/ALDEHYDES, AMINES, AMIDES, ALCOHOLS & GLYCOLS, AZO-CMPDS,
CARBAMATES, ESTERS, CAUSTI
Stability Condition to Avoid:STABLE UNDER ORDINARY CNDTNS OF USE &
STORAGE. SUBSTANCE CAN SUPERCOOL WITHOUT CRYSTALLIZING.
INCOMPATIBILITIES.
Hazardous Decomposition Products:PHOSPHORUS OXIDES MAY FORM WHEN HEATED
TO DECOMPOSITION.
* Toxicological Information*
MUTAGEN. OTHER INFO: IT ALSO FORMS TOXIC FUMES WITH EYANIDES,
SULFIDE, FLUORIDES, ORGANIC PEROXIDES AND HALOGENATED ORGANICS.
MIXTURES WITH NITROMETHANE AR E EXPOLOSIVE.
* Ecological Information *
Ecological:ENVIRONMENTAL FATE: WHEN RELEASED INTO SOIL, THIS MATL MAY
LEACH INTO GROUNDWATER. WHEN RELEASED TO WATER, ACIDS MAY BE
READILY REDICED BY NATURAL WATER HARDNESS MINERALS. THE PHOSPHATE,
HOWEVER, MAY PERSIST INDEFINITELY. ENVIRONMENTAL TOX: NO
INFORMATION FOUND.
* Disposal Considerations *
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING
SHOULD BE HNDLD AS HAZ WASTE & SENT TO RCRA APPRVD INCIN/DISPOSED
IN RCRA APPRVD WASTE FACILITY. PROCESSING, USE/CONTAM OF PROD MAY
CHANGE WASTE MANAGEM ENT OPTIONS. STATE & LOC DISP REGS MAY DIFFER
FROM FED DISP REGS. DISPOSE OF CNTNR (SUPDAT)
* MSDS Transport Information *
Transport Information:DOMESTIC (LAND, D.O.T.). PROPER SHIPPING NAME:
(WATER, I.M.O.). PROPER SHIPPING NAME: PHOSPHORIC ACID. LIQUID.
* Regulatory Information *
SARA Title III Information:FED, STATE & INTERNATION REGS - PART 1.
ACUTE: YES. CHRONIC: NO. FIRE: NO. PRESSURE: NO. REACTIVITY: NO.
(PURE/LIQUID).
Federal Regulatory Information:CHEM INVENTORY STATUS-PART 1. INGRED:
JAPAN-YES, AUSTRALIA-YES. CHEM INVENTORY STATU S-PART 2. INGRED:
PHIL-YES. FED, STATE & INTERNATION REGS-PART 2. IN GRED: PHOSPHORIC
State Regulatory Information:AUSTRALIAN HAZCHEM CODE: 2R. POISON
SCHEDULE S5. WHMIS: THIS MSDS HAS BEEN PREPARED ACCORD TO HAZ
CRITERIA OF CONTROLLED PRODS REGS (CPR) & MSDS CNTNS ALL OF INFO
REQD BY CPR. OTHER INFO: NFPA RATINGS : HLTH: 3. FLAMM: 0.
REACTIVITY:0. LBL HAZ WARNING: DANGER! CORR. CAUSES SEV IRRIT &
BURNS TO EVERY AREA OF CONT. HARMFUL IF SWALLOWED/INHALED. LABEL
PRECAUTIONS: DO NOT GET IN EYES, ON SKIN/ON CLTHG.KEEP CNTNR
CLSD. USE ONLY W/ADEQ VENT. DO NOT BREATH VAP/MIST.
* Other Information *
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* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SHOULD BE NEEDED.
SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS
Other Protective Equipment:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE SKIN CONTACT. EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
LOW HAZARD FOR RECOMMENDED HANDLING. KEEP OUT OF REACH OF CHILDREN.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:AMMONIUM THIOSULFATE
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM BISULFITE (SASA III) (CERCLA)
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3
Ingred Name:AMMONIUM BISULFITE (CERCLA)
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:AMMONIUM ACETATE (CERCLA)
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:WATER
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION-EXPECTED TO BE A LOW HAZARD
FOR RECOMMENDED HANDLING. EYES-NO SPECIFIC HAZARD KNOWN. SKIN-LOW
HAZARD FOR RECOMMENDED HANDLING. INGESTION-EXPECTED TO BE A LOW
INGESTION HAZARD.
Explanation of Carcinogenicity:NOT CARCINOGENIC.
Effects of Overexposure:EYES-MAY CAUSE TRANSIENT IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION-IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSISTS. EYES-ANY MATERIAL THAT CONTACTS THE
EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. GET MEDICAL
ATTENTION IF SYMPTOMS OCCUR. SKIN-WASH WITH SOAP ANDWATER. GET
MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION-DRINK 1-2 GLASSES OF
WATER. SEEK MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:USE APPROPIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY CAUSE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
AWAY FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. KEEP FROM CONTACT WITH OXIDIZING MATERIALS.
* Physical/Chemical Properties *
HCC:N1
Vapor Density:0.6
pH:4.9
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID. COLORLESS -LIGHT YELLOW. VINEGAR ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
BASES, SODIUM HYPOCHLORITE, STRONG OXIDDIZING AGENTS, STRONG ACIDS.
CONTACT WITH BASE LIBERATES FLAMMABLE MATERIAL.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:AMMONIA, CHLORAMINE, SULFUR DIOXIDE,
NITROGEN OXIDES.
* Disposal Considerations *
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNTS
OF WATER.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF COMPONENT TLV LIMITS ARE EXCEEDED, USE NIOSH
APPROVED RESPIRATOR TO REMOVE VAPORS. USE A NIOSH APPROVED
AIR-SUPPLIED RESPIRATOR IF NECESSARY.
Ventilation:USE ADEQUATE VENTILATION IN VOLUME & PATTERN TO KEEP
TLV/PEL BELOW RECOMMENDED LEVELS. EXPLOSION-PROOF VENT MAY BE NEC.
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . WEAR PROTECTIVE CLOTHING AS REQUIRED TO PREVENT SKIN
CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
AMTS OF SOME CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM MAY BE PRESENT IN
THIS PRODUCT.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:2-BUTANONE, PEROXIDE; (METHYL ETHYL KETONE PEROXIDE) (MEKP)
(CERCLA)
OSHA PEL:0.7 PPM, C
ACGIH TLV:0.2 PPM, C
Fraction by Wt: 0-5%
OSHA PEL:1 PPM
ACGIH TLV:1 PPM
Ingred Name:PHTHALIC ACID, DIMETHYL ESTER; (DIMETHYL PHTHALATE) (SARA
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
Ingred Name:1,3-PENTANEDIOL, 2,2,4-TRIMETHYL-, DIISOBUTYRATE (ESTER);
(2,2,4-TRIMETHYLPENTANEDIOL-1, 3-DIISOBUTYRATE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:VOLATILE ORGANIC COMPOUNDS: NIL.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYES:CONTACT CAN CAUSE IMMEDIATE
SEVERE REACTION AND MAY RESULT IN LOSS OF FUNCTIONAL VISION. MAY
CAUSE DELAYED KERATITIS. SKIN:CONTACT CAN CAUSE IRRITATION, (MINOR
ITCHING, BURNING AND/OR REDNE SS), DERMATITIS, DEFATTING. MAY BE
READILY ABSORBED THROUGH SKIN. INHALATION: INHALATION OF VAPORS CAN
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:CAUSE NASAL & RESP IRRIT, DIZZ, WEAK,
FATG, NAUS, HDCH, POSS UNCON &/OR ASPHY. ASPIR OF MATL INTO LUNGS
MAY RSLT IN CHEM PNEUM WHICH CAN BE FATAL. INGEST:CAN CAUSE GI
IRRIT, NAUS, VOMIT, DIAR R. CHRONIC:OVEREXP TO THIS MATL HAS
APPARENTLY BEEN KNOWN TO CAUSE EYE/SKIN DMG & CYTOGENETIC EFTS IN
LAB (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:REMOVE VICTIM FROM EXPOSURE TO A WELL-VENTILATED AREA.
MAKE THEM COMFORTABLY WARM, BUT NOT HOT. USE OXYGEN OR ARTIFICIAL
RESPIRATION AS REQUIRED. CONSULT MD. SKIN:WASH PROMPTLY W/SOAP &
MINUTES. CONSULT MD. INGEST:DO NOT INDUCE VOMITING. GIVE VICTIM A
GLASS OF WATER. CALL MD IMMEDIATELY.
* Fire Fighting Measures *
Flash Point Method:SCC
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . FIGHT LIKE FUEL OIL FIRE. COOL FIRE EXPOSED CONTAINERS
W/WATER SPRAY.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPOSED TO HIGH
TEMPERATURES, SUCH AS FIRE CONDITIONS MAY RUPTURE.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA. REMOVE ALL POSSIBLE SOURCES OF
IGNITION. AVOID PROLONGED BREATHING OF VAPOR. CONTAIN SPILL W/INERT
ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:USE W/ADEQUATE VENTILATION. AVOID
CONTACT W/EYES & SKIN. AVOID BREATHING VAPORS. DO NOT STORE PRODUCT
Other Precautions:DO NOT FLAME CUT, BRAZE, WELD OR MELD EMPTY
CONTAINERS. KEEP PRODUCT AWAY FROM HEAT, OPEN FLAME & OTHER SOURCES
OF IGNITION. AVOID CONTACT W/STRONG ACIDS, ALKALIES & OXIDIZERS.
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:DECOMPOSES
Vapor Pres:0.1
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR OR RED LIQUID W/FAINT KETONE ODOR.
Percent Volatiles by Volume:SUPDAT
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, ALKALIES, OXIDIZERS.
Stability Condition to Avoid:OPEN FLAMES, SPARKS, HEAT, ELECTRICAL &
STATIC DISCHARGE. STABLE AT AMBIENT TEMPS, BUT MAY DECOMPOSE AT
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE &
CARBON.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE & FEDERAL
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOLLOW NIOSH AND EQUIPMENT MANUFACTURE
RECOMMENDATIONS TO DETERMINE APPROPRIATE RESPIRATOR.
Ventilation:USE IN AN AREA PROVIDED WITH GENERAL AND LOCAL EXHAUST
VENTILATION MEETING OSHA REQUIREMENTS.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . PROTECTIVE CLOTHING MEETING LABORATORY SAFETY PRECAUTIONS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY
EXPOSED TO CHLOROCARBONS . EXPLAN OF CARCIN: ANTIC TO BE CARCIN.
ANIMAL: LUNG. FIRST AID PROC: ANYTHING BY MOUTH TO VICTIM THA T IS
UNCON/HAVING CONVLS. CONT MD IMMED.
* Product Identification *
* Composition/Information on Ingredients *
(CERCLA)
Ingred Name:DECANE
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:DODECANE
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TETRADECANE
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:HEXADECANE
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:OCTADECANE
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:DICOSANE
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:DOCOSANE
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TETRACOSANE
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:HEXACOSANE
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:OCTACOSANE
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: CAN CAUSE LT-HEAD,
VERTIGO, DROW, NARCOSIS, HDCH & DIZZ, UNCON, & EVEN DEATH IN
EXTREME CASES. EXPOS TO VAPS CAN ELEVATE CARBOXYHEMOGLOBIN LEVEL IN
CARDIOVASCULAR SYS. EYES: LIQ/HIGH VAP CONC CAN CAUSE PAIN & IRRIT
W/SLIGHT CORNEAL INJURY POSS. SKIN: PRLNG/RPTD CONT CAN CAUSE IRRIT
& (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: IARC MONO, SUPP, VOL
(SUP DAT)
Effects of Overexposure:HLTH HAZ: DERM THRU DEFAT OF SKIN. PRLNG CONT
CAN RSLT IN SKIN ABSORPTION. INGEST: CAN CAUSE BURNING OF THROAT &
MOUTH. CHLOROCARBON MATLS HAVE PRDCED SENSIT OF MYOCARDIUM TO
EPINEPHRINE IN LAB ANIMAL S & COULD HAVE SIMILAR EFT IN HUMANS.
ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT
FOR (SUP DAT)
Medical Cond Aggravated by Exposure:LIVER, KIDNEY, AND HEART
CONDITIONS.
* First Aid Measures *
First Aid:EYES: REMOVE CONT LENSES IF PRESENT. HOLD EYELIDS OPEN &
SKIN: IMMED WASH W/SOAP & WATER. CONTINUE RINSING W/LGE VOLS OF
REMOVE TO FRESH AIR. HAVE TRAINED PERS ADMIN OXYGEN & CPR IF
NEEDED. CONT MD IMMED. INGEST: CONT POIS CTL CTR FOR ASSIST. NEVER
GIVE (SUP DAT)
* Fire Fighting Measures *
Flash Point Method:CC
Flash Point:NONE
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM, WATER SPRAY AS
APPROPRIATE FOR SURROUNDING FIRE AND MATERIALS.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA AND
FULL PROTECTIVE EQUIPMENT . KEEP FIRE-EXPOSED CONTAINERS COOL WITH
WATER SPRAY.
Unusual Fire/Explosion Hazard:HEAT WILL BUILD PRESSURE AND MAY RUPTURE
CLOSED STORAGE CONTAINERS. THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL AND PHOSGENE .
* Accidental Release Measures *
Spill Release Procedures:WEAR PERSONAL PROTECTIVE EQUIPMENT. ABSORB
SMALL SPILLS ON PAPER, VERMICULITE, OR OTHER ABSORBENT. COLLECT AND
STORE IN CLOSED CONTAINER FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AVOID ALL INHAL/CONT. KEEP IN TIGHTLY
CLSD CONTR AT ALL TIMES. PROTECT FROM MOISTURE, TEMP EXTREMES &
DIRECT SUNLIGHT. STORE IN COOL, WELL-VENTD AREA.
Other Precautions:HANDLE W/UTMOST CARE. STORE IN EXPLOSION-PROOF
REFRIGERATOR AT 4C. NO SMOKING IN AREA OF USE. DO NOT USE IN
GENERAL VICINITY OF ARC WELDING, OPEN FLAMES/HOT SURFACES. HEAT
&/OR UV RADIATION MAY CAUSE FORM OF HCL &/OR PHOSGENE .
* Physical/Chemical Properties *
Appearance and Odor:COLORLESS; ETHER-LIKE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACTIVE METALS AND STRONG ALKALINE SOLUTIONS.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES, MOISTURE.
Hazardous Decomposition Products:TOXIC AND CORROSIVE GASES ARE FORMED
ON CONTACT WITH FLAMES OR HOT SURFACES. HCL, PHOSGENE .
* Disposal Considerations *
Waste Disposal Methods:INCINERATE AT AN APPROVED FACILITY IN ACCORDANCE
WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE HYDROCARBON VAPOR CANISTER OR SUPPLIED AIR
RESPIRATOR IN CONFINED AREAS.
ADEQUATE VENTILATION. MECHANICAL-USE EXPLOSION PROOF EQUIPMENT.
Other Protective Equipment:USE CHEMICAL RESISTANT APRONS OR CLOTHING TO
AVOID REPEATED SKIN CONTACT.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:FRED ARMSTRONG
* Composition/Information on Ingredients *
Ingred Name:STODDARD SOLVENT
Other REC Limits:% WT. BY PAINT
Fraction by Wt: .1%
Other REC Limits:% WT. BY PAINT
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Health Hazards Acute and Chronic:HIGH VAPOR CONCENTRATIONS (GREATER
RESPIRATORY TRACT, MAY CAUSE HEADACHES AND DIZZINESS. PROLONGED
SKIN CONTACT IRRITATES.
Effects of Overexposure:HIGH VAPOR CONCENTRATIONS (GREATER THAN
RESPIRATORY TRACT, MAY CAUSE HEADACHES AND DIZZINESS. PROLONGED
SKIN CONTACT IRRITATES.
* First Aid Measures *
SUBSIDES. IF IRRITATION PERSISTS CALL A PHYSICIAN. SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND WASH THOROUGHLY WITH SOAP AND
WATER. INHA LATION: IF OVERCOME BY VAPORS, REMOVE TO FRESH AIR,
CALL A PHYSICIAN. INGESTION: DO NOT INDUCE VOMITING, CALL A
PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:.9
Upper Limits:7
Extinguishing Media:CARBON DIOXIDE, FOAM, WATER FOG, DRY CHEMICAL.
Fire Fighting Procedures:USE AIR SUPPLIED BREATHING EQUIPMENT. COOL
ENCLOSED CONTAINERS WITH WATER SPRAY. AVOID BREATHING VAPORS OR
FUMES.
Unusual Fire/Explosion Hazard:IF LEAK OR SPILL HAS IGNITED, USE WATER
SPRAY TO DISPERSE THE VAPORS FROM FIRE FIGHTERS.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL IGNITION SOURCES. KEEP FROM HEAT,
SPARKS & OPEN FLAMES. ADD ABSORBENT(SAND,EARTH,SAWDUST)TO SPILL.
VENTILATE AREA(OPEN WINDOWS,DOORS). IF LARGE SPILL KEEP FROM
ENTERING SEWERS & WATERCOURSE S BY DIKING. ADVISE AUTHORITIES IF
PRODUCT ENTERS.
*Handling and Storage *
Other Precautions:NONE
* Physical/Chemical Properties *
Vapor Density:4.8
Solubility in Water:INSOLUBLE
Appearance and Odor:REDISH BROWN LIQUID WITH KEROSENE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CAN REACT WITH OXIDIZING MATERIALS WHEN HEATED TO DECOMPOSITION.
Stability Condition to Avoid:HIGH TEMPERATURES OR HEATING.
Hazardous Decomposition Products:CARBON MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:ASSURE CONFORMITY WITH APPLICABLE DISPOSAL
REGULATIONS. DISPOSE OF ABSORBED MATERIAL AT AN APPROVED DISPOSAL
SITE OR FACILITY.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESP DEVICE IN ACCORD WITH
EXPOSURE OF CONCERN.
Ventilation:LOCAL
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:AMMONIA (SARA III)
* Hazards Identification *
Effects of Overexposure:EYE: SEVERE DAMAGE. SKIN: BURNS.
VAPORS:IRRIATION.
* First Aid Measures *
WITH WATER,CALL A PHYSICIAN. INHALATION: REMOVE FROM EXPOSURE,GIVE
ARTIFICAL RESPIRATION IF NEEDED,CALL A PHYSICIAN.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:WATER FOG
Unusual Fire/Explosion Hazard:FIRE CAN BE CAUSE BY IGNITION OF HIGH
* Accidental Release Measures *
Spill Release Procedures:FLUSH WITH LARGE QUANTITIES OF COLD WATER,KEEP
VAPOR TO MINIMUM WITH WATER FOG. DO NOT DISCHARGE THIS SOLUTION
INTO SEWERS CONFINED DRAINS OR SURFACE WATER.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM SUN,HEAT AND STRONG
ACIDS. HEATING OF PRODUCT WILL FORM EXPLOSIVE MIXTURE OF AMMONIA.
Other Precautions:USE PROPER PERSONAL PROTECTIVE EQUIPMENT.
* Physical/Chemical Properties *
HCC:C2
Vapor Pres:9.9
Vapor Density:<1
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID;STRONG,PUNGENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
MERCURY,COPPER,ACIDS,GALVANIZED SURFACE,ALUMINUM/COPPER ALOY
Hazardous Decomposition Products:NH*3 VAPOR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL,STATE AND FEDERAL
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NO SPECIAL REQUIREMENTS.
Ventilation:ADEQUATE TO ELIMINATE MISTS.
Other Protective Equipment:FULL WORK CLOTHING; FACE SHIELD WHEN
USING/MIXING PRODUCT.
Supplemental Safety and Health
GL SOLUTION PART A OF TWO PART PRODUCT UNDER THIS NSN, KEY1:B3.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POTASSIUM HYDROXIDE (SARA III)
OSHA PEL:C, 2 MG/M3
Ingred Name:HYDROQUINONE (SARA III)
Fraction by Wt: 4.5%
OSHA PEL:2 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Fraction by Wt: 3%
Ingred Name:AQUEOUS SOLUTION,NON-HAZARDOUS,UNIDENTIFIED COMPONENTS; WT%
BY DIFFERENCE
* Hazards Identification *
Effects of Overexposure:EYES: BURNS; SKIN:IRRITATION. REPEATED SKIN
CONTACT MAY RESULT IN ALLERGIC SKIN REACTION.
* First Aid Measures *
MIN;INHALE:REMOVE TO FRESH AIR, KEEP CALM;INGEST:RINSE MOUTH,DO NOT
INDUCE VOMIT;GET IMMEDIATE MEDICAL ATTENTION FOR EYES OR INGEST.
* Fire Fighting Measures *
Extinguishing Media:NOT COMBUSTIBLE:USE MEDIA SUITABLE FOR ADJACENT
FIRE.
Fire Fighting Procedures:WEAR SELF-CNTND BRTHG APP;H*2O SPRAY COOL
CONT.
Unusual Fire/Explosion Hazard:CONTAINERS MAY RUPTURE IN HEAT OF FIRE.
ALKALINE SOLUTION:AVOID PHYSICAL CONTACT.
* Accidental Release Measures *
Spill Release Procedures:DO NOT TOUCH SPILLED MATERIAL. WEAR PROTECTIVE
EQUIPMENT. STOP LEAK IF POSSIBLE WITHOUT RISK. SM SP: ABSORB W
COMMERCIAL ABSORBENT & PUMP IN APPR CONTAINERS. LG SP: CONTAIN W
DIKE & TRANSFER TO APPR C ONTAINERS; ALKALINE SOLUTION.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
AREA; PROTECT FROM PHYSICAL DAMAGE & AVOID CONTACT. KEEP CONTAINERS
TIGHTLY CLOSED. PREVENT SKIN CONTACT.
Other Precautions:REMOVE & WASH CONTAMINATED CLOTHING. MAINTAIN STRICT
HYGIENE. USE OF NON-ALKALINE(ACID) TYPE HAND CLEANER REDUCES RISK
OF ALLERGIC SKIN REACTION.
* Physical/Chemical Properties *
HCC:C1
Solubility in Water:COMPLETE
Appearance and Odor:LIGHT BROWN AQUEOUS SOLUTION; ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE NOTED(THIS IS ALKALINE SOLUTION)
Stability Condition to Avoid:NONE NOTED.
Hazardous Decomposition Products:NONE
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN FULL ACCORDANCE WITH ALL APPLICABLE
INTERNATIONAL, FEDERAL, STATE & LOCAL REGULATIONS, MFG SUGGESTS
FLUSH TO SEWER W EXCESS H*2O.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF TLV OF THE PRODUCT OR ANY COMPONENT IS
EXCEEDED, A NIOSH/MSHA JOINTLY APPROVED AIR SUPPLIED RESPIRATOR IS
ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA
REGULATIONS ALSO PERMIT OTHER NIOS H/MSHA RESPIRATORS UNDER
SPECIFIED CONDITIONS.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
REGULATIONS ARE ADVISED. CHECK
Other Protective Equipment:TO PREVENT REPEATED OR PROLONGED SKIN
CONTACT, WEAR IMPERVIOUS CLOTHING AND BOOTS.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING, OR USING
WASHROOM. SMOKE IN SMOKING PERMITTED AREAS ONLY.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:ERNEST CARTER
* Composition/Information on Ingredients *
Ingred Name:NAPHTHA, SOLVENT
Ingred Name:LIGHT AROMATIC SOLVENT NAPHTHA (PETROLEUM)
Ingred Name:METHYL ETHYL KETOXIME
< Wt:.5
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF SKIN, EYES, MUCOUS
MEMBRANES, DRYING, DEFATTING OF SKIN. AVOID INGESTION AND BREATHING
OF VAPORS. CHRONIC: EYE. LIVER, KIDNEY, AND CENTRAL NERVOUS SYSTEM
DAMAGE MAY OCCUR.
Effects of Overexposure:INHALATION: EXCESSIVE INHALATION OF VAPORS CAN
CAUSE NASAL AND RESPIRATORY IRRITATION, DIZZINESS, FATIGUE, NAUSEA,
HEADACHE, POSSIBLE UNCONSCIOUSNESS, AND EVEN ASPHYXIATION AS
NUISANCE DUSTS. AS RESPI RABLE NUISANCE DUSTS. PROLONGED OR
REPEATED CONTACT WITH PRODUCT CAN CAUSE MODERATE SKIN IRRITATION,
DEFTTING, DERMATITIS. EYES: CAN CAUSE SEVERE IRRITATION, REDNESS,
TEARING, BLURRED VISION. SKIN ABS ORPTION MAY POTENTIALLY
CONTRIBUTE TO OVERALL EXPOSURE TO THIS MATERIAL. INGESTION CAN
CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, AND DIARRHEA.
ASPIRATION OF MATERIAL INTO THE LUNGS CAN CAUS E CHEMICAL
PNEUMONITIS, WHICH CAN BE F
* First Aid Measures *
First Aid:SKIN: THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING. LAUNDER CLOTHING BEFORE REUSE. EYES:
FLUSH WITH LARGE AMOUNTS OF WATER, LIFTING UPPER AND LOWER LIDS
OCCASIONALLY. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE
VOMITING. KEEP PERSON WARM, QUIET. AND GET MEDICAL ATTENTION.
ASPIRATION OF MATERIAL INTO LUNGS DUE TO VOMITING CAN CAUSE
CHEMICAL PNEUMONITIS, WHICH C AN BE FATAL. BREATHING: REMOVE PERSON
TO FRESH AIR. GIVE OXYGEN IF BREATHING DIFFICULT; GIVE ARTIFICIAL
RESPIRATION IF BREATHING STOPS. KEEP PERSON WARM AND GET MEDICAL
ATTENTION.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:0.5%
Upper Limits:7.0%
Extinguishing Media:FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS WITH A
FULL FACE PIECE OPERATED IN PRESSURE DEMAND OR OTHER POSITIVE
PRESSURE MODE WHEN FIGHTING FIRES.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
TRAVEL ALONG THE GROUND OR BE MOVED BY VENTILATION AND IGNITED BY
HEAT, PILOT LIGHTS, OTHER FLAMES AND IGNITION SOURCES AT
LOCATIONS DISTANT FROM MATERIAL HANDLIN G PORT.
* Accidental Release Measures *
Spill Release Procedures:SMALL: ABSORB, PREFERRABLY WITH FLOOR
ABSORBENT, TRANSFER TO HOOD. LARGE: ELIMINATE ALL IGNITION SOURCES.
WEAR PROTECTIVE CLOTHING. STOP SPILL, DIKE AREA, PUMP TO SALVAGE
TANK. PREVENT RUN-OFF TO SEWE RS, STREAMS.NOTIFY AUTHORITIES.
*Handling and Storage *
Handling and Storage Precautions:DO NOT STORE OR USE IN HIGH
TEMPERATURE AREAS OR NEAR HEAT, SPARKS, OR OPEN FLAME. KEEP CLOSURE
TIGHT AND CONTAINER UPRIGHT TO PREVENT LEAKAGE. STORE ONLY IN WELL
VENTILATED AREAS. AVOID CONTACT WITH OR BREATHING OF VAPORS
RELEASED DURING CURING PROCESS.
Other Precautions:DO NOT TAKE INTERNALLY. AVOID CONTACT WITH SKIN AND
EYES. AVOID BREATHING OF VAPORS OR SPRAY MIST. ALL HAZARD
PRECAUTIONS GIVEN IN THE DATA SHEET MUST BE OBSERVED.
* Physical/Chemical Properties *
HCC:F4
Vapor Density:HEAVIER
Spec Gravity:0.9
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NOT SOLUBLE IN WATER
Appearance and Odor:CLEAR/AMBER LIQUID WITH ALIPHATIC SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NEVER USE WELDING OR CUTTING TORCH ON OR
NEAR DRUMS(EVEN EMPTY) BECAUSE PRODUCT(EVEN JUST RESIDUE) CAN
IGNITE EXPLOSIVELY.
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE,
VARIOUS HYDROCARBONS, ETC.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:SMALL SPILL: ALLOW VOLATILE PORTION TO EVAPORATE
IN HOOD. ALLOW SUFFICIENT TIME FOR VAPORS TO COMPLETELY CLEAR HOOD
DUCT WORK. DISPOSE OF REMAINING MATERIAL IN ACCORDANCE WITH
APPLICABLE REGULATIONS. LARGE SPILL: DESTROY BY LIQUID
INCINERATION. CONTAMINATED ABSORBENT MAY BE DEPOSITED IN A LANDFILL
I N ACCORADNCE WITH LOCAL, STATE, AND FEDERAL REGULA
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE GENERALLY REQUIRED W/NORMAL USE. WEAR A
NIOSH/MSHA APPROVED SELF-CONTAINED RESPIRATOR FOR ORGANIC VAPORS IF
TLV IS EXCEEDED, A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IN
CONFINED SPACES OR EX TREME CONCENTRATIONS.
Ventilation:LOCAL EXHAUST:WHEN LARGE AMOUNTS ARE RELEASED. MECHANICAL
(GENERAL):USE IN LOW PLACES.
Other Protective Equipment:WEAR AS NEEDED TO PREVENT PROLONGED OR
REPEATED SKIN CONTACT DURING USE.
Work Hygienic Practices:GENERAL HYGIENIC PRACTICES INCLUDE WASHING
HANDS AFTER USE, BEFORE EATING, DRINKING OR SMOKING, W/SOAP &
WATER.
Supplemental Safety and Health
EXPLO HAZ:CHLORIDES & PHOSGENE . EFTS OF OVEREXP:INGEST IS TO BE
AVOIDED. ING 2:IN CONFINED AREA, VAPS IN HIGH CONCS MAY BE ANESTH.
VAPS ARE IRRIT TO SKIN & UPPER RESP TRACT. OVEREXP MAY RSLT IN LT
HEAD, GIDD, STAG GAIT, POSS NAUS. AT 2-3% CONCS, SYMPS OF SIMPLE
ASPHYXIA OCCUR. AT 3-5% CONCS, (ING 3)
* Product Identification *
Preparer's Name:ROBERT M. EICHHORN
* Composition/Information on Ingredients *
Ingred Name:ING 5:CHLOROFLUOROCARBON (CFC) MATLS HAVE PRDCD SENSIT OF
MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE A(ING 7)
Ingred Name:ING 6:SIMILAR EFT IN HUMANS. ADRENOMIMETICS
(I.E.,EPINEPHRINE) MAY BE CONTRA-INDICATED EXCEPT FOR
LIFE-SUSTAINING(ING 8)
Ingred Name:ING 7:USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO
CFC'S .
Ingred Name:ING 9:MINS. IF IRRIT DEVELOPS/PERSISTS, CALL MD.
INGEST:CALL MD IMMED. DO NOT INDUCE VOMIT AS HAZ OF ASPIR OF (ING
Ingred Name:ETHANE, 1,1,2-TRICHLORO-1,2,2-TRIFLUORO-;
(TRICHLOROTRIFLUOROETHANE)(SARA III)
Ozone Depleting Chemical:1
Ingred Name:CARBON DIOXIDE
VOMIT & UNCON OCCUR. AT HIGHER CONCS, CIRCULATORY (ING 4)
Ingred Name:ING 3:INSUFFICIENCY LEADING TO COMA & DEATH CAN OCCUR. ING
2 IS THE MOST POWERFUL CEREBRAL VASODILATOR KNOWN. (ING 5)
Ingred Name:ING 4:REPORTS HAVE ASSOC CHRONIC OVEREXP ON REPETITIVE
BASIS TO SOLVENTS W/PERMANENT BRAIN & NERV SYS DMG. (ING 6)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ING 1:INHAL:VAP IS HVR/AIR & CAN CAUSE
SUFFOCATION BY REDUCING OXYGEN AVAIL FOR BRTHG. BRTHG HIGH CONCS OF
VAP MAY CAUSE LT HEAD, GIDD, SHORTNESS OF BREATH & MAY LEAD TO
NARCOS, CARDIAC IRREGS, UNCON/ DEATH. IN SCREENING TESTS W/LAB
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INTRAVENOUS EPINEPHRINE CHALLANGE, HAS
INDUCED SERIOUS CARDIAC IRREGS. SKIN:NOT CORR/IRRIT AFTER SINGLE
CONT. HOWEVER, RPTD LIQ CONT CAN CAUSE DEFAT RESULTING IN IRRIT.
THIS MATL IS POORLY AB SORBED THRU SKIN. EYE:LIQ CONT CAN CAUSE
DISCOMFORT. USUALLY NO EXTENDED EFTS. INGEST:ALTHOUGH ORAL TOX IS
LOW, (SUPDAT)
Medical Cond Aggravated by Exposure:ING 1:CVS DISEASE. ING
2:PRE-EXISTING CHRONIC RESP/HEART DISEASE. PERS W/ILL HLTH WHERE
SUCH CNDTNS WOULD BE AGGRAVATED BY EXPOS TO THIS MATL SHOULD NOT BE
ALLOWED TO WORK W/OR HANDLE THIS PRODUCT.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR. CALL MD. IF NOT BRTHG, GIVE ARTF
RESP, PREFERABLY MOUTH-TO-MOUTH. IF BRTHG IS DFCLT, ADMIN OXYGEN.
DO NOT GIVE EPINEPHRINE/SIMILAR DRUGS. SEEK MED ATTN. NOTE TO MD:
BECAUSE OF POSS INCR RISK OF ELICITING CARDIAC DYRSYTHMIAS,
CATECHLOLAMINE DRUGS, SUCH AS EPINEPHRINE, SHOULD BE CONSIDERED
ONLY AS LAST RESORT IN LIFE-THREATENING EMERS. EYE:IMMED FLUSH
W/PLENTY OF (ING 9)
* Fire Fighting Measures *
Flash Point Method:TOC
Flash Point:NONE
Extinguishing Media:AS APPROPRIATE FOR SURROUNDING COMBUSTIBLES.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EXPOS TO HIGH TEMPS MAY CAUSE CNTNR
FAILURE. HIGH TEMPS & FLAME CONT MAY DECOMPOSE PROD & PRDCE HAZ BY
BYPRODS. THERMAL DECOMP PRODS MAY INCL FLUORIDES,(SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:EXTINGUISH OPEN FLAMES, VENTILATE AREA. SOAK
UP SPILL ON INERT ABSORBANT & PLACE INTO APPROVED WASTE CONTAINER
FOR DISPOSAL. DO NOT FLUSH INTO SEWERS OR WATERWAYS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN CLEAN, DRY AREA, AWAY FROM
SUNLIGHT. AVOID PRLNG/RPTD SKIN CONT.
Other Precautions:AVOID BRTHG OF VAPS. USE IN WELL VENTILATED AREAS. NO
SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF ARC WELDING,
OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE FORM OF
CHLORIDES, FLUORIDES/P HOSGENE .
* Physical/Chemical Properties *
HCC:N1
Vapor Density:6.5
Spec Gravity:1.6 (H2O=1)
Evaporation Rate & Reference:0.3 (CCL4=1)
Solubility in Water:NIL
Appearance and Odor:CLEAR, COLORLESS LIQUID; SLIGHT ETHEREAL ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/ALKALI OR ALKALINE EARTH METALS, POWDERED AL, ZN, BE &
SO FORTH.
Stability Condition to Avoid:AVOID CONTACT W/HIGH TEMPERATURES, OPEN
FLAME.
Hazardous Decomposition Products:HYDROCHLORIC & HYDROFLUORIC ACIDS,
POSSIBLY CARBONYL HALIDES. CHLORIDES, FLUORIDES & PHOSGENE .
* Disposal Considerations *
Waste Disposal Methods:COMPLY W/ALL FEDERAL, STATE & LOCAL REGULATIONS.
GENERATED.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRABLE FUME RESP/AIR
SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED SPACE/WHERE LOCAL
EXHAUST/ VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV.
Ventilation:USE ENOUGH VENT, LOC EXHST @ ARC/BOTH, TO KEEP FUMES &
Other Protective Equipment:WEAR HEAD, HAND & BODY PROT WHICH HELP TO
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR TRADE NAME/PART #: STAINLESS STEEL COVERED ELECTRODES. EXPLAN OF
CARCIN: CARCIN. HUMAN/ANIMAL: LUNG CANCER, SKIN ULCERS. NICKEL:
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:IRON
ACGIH TLV:5 MG/M3
Ingred Name:NICKEL
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:CALCIUM CARBONATE
Ingred Name:SILICIC ACID (H*2SIO*3), DISODIUM SALT; (SODIUM SILICATE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:CHROMIUM
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:MANGANESE
OSHA PEL:5 MG/M3 DUST
ACGIH TLV:5 MG/M3 DUST
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
Ingred Name:CALCIUM FLUORIDE
OSHA PEL:2.5 MG/M3
ACGIH TLV:2.5 MG/M3
Ingred Name:FELDSPAR
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPP DATA: WASHINGTON, D.C. FOR MORE DETAILS.
Ingred Name:VENT: TRAIN WELDER TO KEEP HIS HEAD OUT OF FUMES.
Ingred Name:OTHER PROT EQUIP: MINIMUM, THIS INCL ARM PROTECTORS,
PARTS AND TO INSULATE HIMSELF FROM WORK AND GROUND.
Ingred Name:EYE PROT: LENS. AS A RULE OF THUMB, START W/A SHADE WHICH
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:FUMES & GASES CAN BE DANGEROUS TO YOUR
HLTH. ACUTE: OVEREXPOSURE TO WELDING FUMES MAY RSLT IN DISCOMFORT
SUCH AS: DIZZ, NAUS/DRY/IRRIT OF NOSE, THROAT/EYES. CHRONIC: MAY
LEAD TO SIDEROSIS (IRON DEPOSI TS IN LUNG) & IS BELIEVED BY SOME
INVESTIGATORS TO AFFECT PULMONARY FUNC. ARC RAYS CAN INJURE EYES
(EFTS OF OVEREXP)
BE (SUPP DATA)
Effects of Overexposure:HLTH HAZ: AND BURN SKIN. ELECTRIC SHOCK CAN
KILL.
Medical Cond Aggravated by Exposure:AGGRAVATION OF PREEXISTING
RESPIRATORY OR ALLERGIC CONDITIONS MAY OCCUR IN SOME WORKERS.
* First Aid Measures *
First Aid:CALL FOR MED AID. EMPLOY FIRST AID TECH RECOMM BY AMERICAN
RED CROSS. INHAL: REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O2/ARTF
RESP) . INGEST: CALL MD IMMED . SKIN: FLUSH WITH COPIOUS AMOUN TS
OF WATER. CALL MD . EYE: IMMEDFLUSH WITH POTABLE WATER FOR A
* Fire Fighting Measures *
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONFLAMMABLE: WELDING ARC AND SPARKS CAN
IGNITE COMBUSTIBLES.
* Accidental Release Measures *
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:READ & UNDERSTAND MFR'S INSTRUCTIONS & PRECAUTIONARY
* Physical/Chemical Properties *
HCC:T7
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:GASEOUS RXN PRODS MAY INCL CARBON
MONOXIDE & CARBON DIOXIDE. OZONE & NITROGEN OXIDES MAY BE FORMED BY
RADIA FROM ARC.
* Disposal Considerations *
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER, OR
LINER IN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH
FEDERAL, STATE ANDLOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FULL FACE RESPIRATOR
Ventilation:LOCAL EXHAUST TO MAINTN BELOW TLV.
Other Protective Equipment:FULL PROTECTIVE CLOTHING,SAFETY SHOWER,EYE
WASH STATION
Supplemental Safety and Health
* Product Identification *
Product ID:CYCLOHEXANONE
* Composition/Information on Ingredients *
Ingred Name:CYCLOHEXANONE (SARA III)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED,INHALED OR
ABSORBED THROUGH SKIN. CAUSES IRRITATION. AFFECTS CENTRAL NERVOUS
SYSTEM.
Effects of Overexposure:INH:MAY IRRIT RESP TRACT;ING:MAY DISTRB GI
SYSTM;SKIN:MAY BE ABSRBD THRU;EYES:VAP IRRIT.CORNL INJRY.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR.GIVE CPR/OXYGEN IF NEEDED;INGEST:IF
SWALLOWED,GIVE TWO GLASSES OF WATER & INDUCE VOMIT.NOTHING BY MOUTH
IF UNCON;SKIN/EYE EXPOSURE:RMV CONTMNTD CLOTHG.WASH SKIN W/SOAP &
H*2O .FLUSH SKIN/EYES W/LG H*2O;GET MED HELPIMMEDIATLY
* Fire Fighting Measures *
Lower Limits:1.1
Upper Limits:8.1
Extinguishing Media:DRY CHEM,ALCHL FOAM,CO*2;WATER SPRAY TO KEEP EXPSD
CANS COOL
PROT.CLTHG.
Unusual Fire/Explosion Hazard:ABOVE FLASH POINT,VAP-AIR MIXTURES ARE
* Accidental Release Measures *
Spill Release Procedures:VENTILATE & EVAC AREA.USE PROTCTV CLOTHG &
RESP PROTCTION FM VAP.CONTAIN & RECOVR LIQ WHEN POSS.SPILLS MAY BE
ABSORBED W/INERT MATL,VERMICULITE,DRY SAND & PLACE IN A CONTNR
PENDING DISPOSAL.DO NOT FLU SH TO SEWER.HAVE DRY POWDR EXTINGUISHR
ON HAND.
*Handling and Storage *
Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTNRS AT
COOL,DRY,VENTILATED PLACE.PROTECT AGAINST PHY DAMAGE.ISOLATE FM
OXIDIZING MATL.KEEP AWAY FROM HEAT & FLAME.
Other Precautions:AVOID BREATHING MIST.USE W/ADEQUATE VENTILATION.KEEP
CONTAINRS CLOSED.WASH THOROUGHLY AFTER HANDLING.AVOID SKIN,EYES &
CLOTHING CONTACT.DO NOT ENTER STORAGE AREA UNLESS ADEQUATELY
VENTILATED.
* Physical/Chemical Properties *
HCC:F4
Vapor Pres:2
Vapor Density:3.4
Solubility in Water:APPRECIABLE
Appearance and Odor:CLEAR,COLORLESS/LIGHT YEL,OIL LIQ.ACETONE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING MATL.MAY ATTACK PLASTICS,RESINS,& RUBBER.
Stability Condition to Avoid:HEAT, IGNITION SOURCES
Hazardous Decomposition Products:OXIDES OF CARBON(CO,CO*2) WHEN HEATED
TO DECOMPOSITION.
* Disposal Considerations *
Waste Disposal Methods:COLLECTED SPILLS MAY BE ATOMIZED IN A
RCRA-APPROVED COMBUSTION CHAMBER OR SHIPPED TO RCRA APPROVED
W/LOCAL,STATE & FEDERAL REGS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF VENTD,MAY NOT REQ RSPRTR.IN RESTRICTD
VENT,NIOSH CHEM CARTRIDGE RSPRTR MAY BE REQ'D.SPRAYNG,MECHAN
PREFILTER MAY ALSO BE REQ'D.CONFIND AREAS,USE AIR SUPPLD RSPRTR.SEE
GUIDELINE"AIHA
Ventilation:LOCAL EXHAUST VENT TO KEEP BELOW TLV. REMOVE DECOMPOSITION
PRODUCT. SEE "INDUST VENT-MANUAL RECOMMENDED PRACTICES" ACGIH
Other Protective Equipment:EYEWASH FACILITY, SAFETY SHOWER.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:W A ELLISON
* Composition/Information on Ingredients *
(LFL 1.7; UFL 7.6)
Fraction by Wt: <5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SOLVENT NAPHTHA, LIGHT AROMATIC (SOLVENT)
Fraction by Wt: <5%
Other REC Limits:NONE RECOMMENDED
(LFL 1.0; UFL 7.0)
Fraction by Wt: <5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:METHYL ISOAMYL KETONE (SOLVENT)
Other REC Limits:NONE RECOMMENDED
Ingred Name:TITANIUM DIOXIDE (PIGMENT)
Other REC Limits:NONE RECOMMENDED
Ingred Name:TALC (PIGMENT)
Other REC Limits:NONE RECOMMENDED
Ingred Name:SILICA, CRYSTALLINE (PIGMENT)
Fraction by Wt: 5%
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: 5%
Other REC Limits:NONE RECOMMENDED
(LFL: 1.0 UFL: 7.0)
Fraction by Wt: <5%
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES
Health Hazards Acute and Chronic:ACUTE; INGEST: GASTROINTESTINAL IRRIT,
NAUSEA, VOMITING. ASPIRATION INTO LUNG MAY CAUSE CHEM PNEUMONITIS
(CAN BE FATAL). INHAL: NOSE OR THROAT IRRIT. ACUTE CENTRAL NERVOUS
SYSTEM DEPRESSION (HEADACHES , DIZZINESS, NAUSEA, CONFUSION). EYE:
SEVERE IRRIT. SKIN: ABSORBED THROUGH SKIN IN HARMFUL AMTS.
DEFATTING & SKIN IRRIT.
Explanation of Carcinogenicity:IARC CONSIDERS CRYSTALLINE SILICA TO
HAVE LIMITED EVIDENCE OF CARCINOGENICITY IN HUMANS & SUFFICIENT IN
ANIMALS.
Effects of Overexposure:CHRONIC; SILICOSIS (DISABLING LUNG DISEASE).
LIVER, KIDNEY AND BLOOD INJURY. ENHANCES NEUROTOXICITY (SYNERGISTIC
EFFECT RESULTED IN PERIPHERAL NEUROPATHY). PROLONGED & REPEATED
OVEREXPOSURE: PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE.
CONCENTRATING & INHALING PRODUCT MAY BE HARMFUL OR FATAL.
Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY CONDITIONS
MAY BE AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA.
* First Aid Measures *
First Aid:INGEST: DONT INDUCE VOMITING. CALL POISON CTR/EMERG ROOM/DR
IMMED. INHAL:REMOVE TO FRESH AIR IMMED. IF BREATHING STOPPED, GIVE
ARTIF RESPRTN. KEEP WARM & QUIET. GET MED AID IMMED. EYE: FLUSH
W/WATER 1 5 MIN, LIFTING EYELIDS. GET MED AID. SKIN: REMOVE CONTAM
CLOTHES. WASH AFFECTED AREA W/SOAP & WATER. GET MED AID IF IRRIT
PERSISTS. NOTE TO DR:DIRECT TREATMENT AT CLINICAL CONDITION &
SYMPTOM CONTROL.
* Fire Fighting Measures *
Lower Limits:1.0
Extinguishing Media:NFPA CLASS B EXTINGUISHERS (CO2, DRY CHEMICAL,
ALCOHOL FOAM) FOR FLAMMABLE LIQ. POLYMER FOAM PREFERRED FOR LARGE
FIRES.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE, USE TO COOL EXPOSED
CONTAINERS (FOG NOZZLES PREFERRED) TO PREVENT PRESSURE BUILDUP,
AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO HEAT.
Unusual Fire/Explosion Hazard:DURING EMERGENCY CONDITIONS, OVEREXPOSURE
TO DECOMPOSITION PRODUCTS MAY BE HEALTH HAZARD. SYMPTOMS MAY NOT BE
IMMEDIATELY APPARENT. GET MEDICAL AID. FLAMMABLE.
* Accidental Release Measures *
Spill Release Procedures:WEAR RSPRTR,EYE,HAND,BODY PROTECTN. KEEP
SPECTATORS AWAY. ELIMINATE IGNIT SOURCES. DIKE & CONTAIN W/INERT
MAT'L (SAND/EARTH/ETC). TRANSFER LIQ/USED ABSORBENT TO COVERED
METAL CONTAINER. USE NON-SPARKI NG TOOL. PREVENT SEWER, GROUNDWATER
CONTAMINATION.
*Handling and Storage *
INTERNALLY. DO NOT BREATHE SANDING DUST.
Other Precautions:CLOSE CONTAINER AFTER EACH USE. DO NOT WASH & REUSE
EMPTY CONTAINER FOR ANY PURPOSE. GROUND & BOND CONTAINERS TO
RECEIVING CONTAINER. DO NOT WELD, BRAZE, OR CUT ON EMPTY CONTAINER.
NEVER USE PRESSURETO EMPTY. DRUM IS NOT A PRESSURE VESSEL.
* Physical/Chemical Properties *
Vapor Density:> AIR
Spec Gravity:1.5
pH:4-7
Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER
Solubility in Water:SLIGHT IN WATER
Appearance and Odor:LIQUID, SOLVENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS. OXIDIZING MATERIALS.
OF IGNITION.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE & CARBON
DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE, &
LOCAL LAWS OR REGULATIONS. THIS PRODUCT, IF DISCARDED DIRECTLY,
WOULD BE CLASSIFIED A HAZARDOUS WASTE BASED ON ITS IGNITABILITY
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AVOID INHALING AEROSOLIZED PRODUCT. WEAR
DUST/MIST/HEPA-FILTERED RESPIRATOR IN SITUATIONS WHERE PRODUCT MAY
BECOME AIRBORNE.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
* Product Identification *
Product ID:ONCASPAR
* Composition/Information on Ingredients *
Ingred Name:ONCASPAR
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITANT TO MUCOUS MEMBRANES.
SKIN: MAY CAUSE IRRITATION. INHALATION: IRRITANT TO MUCOUS
MEMBRANES. MAY CAUSE RESPIRATORY TRACT IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
* First Aid Measures *
W/PLENTY OF WATER. INGESTION: RINSE MOUTH IMMEDIATELY. INDUCE
VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTE TO PHYSICIAN:
TOXICOLOGY STUD IES HAVE SHOWN MATERIAL TO BE VERY LOW ACUTE
TOXICITY. THERE IS NO SPECIFICANTIDOTE. TREATMENT OF OVEREXPOSURE
SHOULD BE DIRECTED AT THE OF SYPMTOMS & CLINICAL CONDITION. (SUPP)
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:WATER, CO2, DRY CHEMICAL
Fire Fighting Procedures:CONFINED SPACES REQUIRE FULL PROTECTIVE GEAR &
SUPPLIED AIR RESPIRATORY PROTECTION.
* Accidental Release Measures *
APPROPRIATE CONTAINER FOR DISPOSAL. WASH AREA AFTER SPILL IS
COMPLETE.
*Handling and Storage *
Handling and Storage Precautions:PREVENT PHYSICAL DAMAGE TO PACKAGE.
PATIENT. STORE UNDER NORMAL CONDITIONS.
Other Precautions:AVOID EXTREMES OF TEMPS.
* Physical/Chemical Properties *
Vapor Pres:AS WATER
Vapor Density:AS WATER
Spec Gravity:>1
pH:(SUPP)
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID IN BOTTLES
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, STRONG BASES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:A RESPIRATOR SHOULD BE WORN IF HAZARDOUS
DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE BEEN RELEASED.
RESPIRATOR TYPE: ACID GAS. IF RESPIRATORS ARE USED, A PROGRAM
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
FOR RISK OF EXPOSURE.
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER
RECOMMENDED.
Supplemental Safety and Health
DEVELOPER & REPLENISHER). THE HMIS SERIAL NUMBERS FOR ALL PARTS OF
THIS KIT (INCLUDING THE ONE FOR THIS MSDS) ARE: CLHDZ (WORKING
SOL' N), CLHDS, CLHDT, AND CLHDW.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:WATER
Ingred Name:SODIUM SULFITE
Minumum % Wt:5.
Ingred Name:SODIUM METABORATE
Minumum % Wt:1.
Maxumum % Wt:5.
Ingred Name:HYDROQUINONE
< Wt:1.
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:4-(METHYLAMINO)PHENOL SULFATE
< Wt:1.
Ingred Name:SODIUM HYDROXIDE
< Wt:1.
OSHA PEL:2 MG/M3
ACGIH STEL:C2 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE LOW HAZARD
FOR RECOMMENDED HANDLING. IN CONTACT WITH STRONG ACIDS OR IF
HEATED, SULFITES LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS
IRRITATING TO RESPIRATORY TRACT. ASTHMATICS OR HYPERSENSITIVE
INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES
IRRITATION. SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN
REACTION BASED ON HUMAN EXPERIENCE. INGESTION: M AY BE HARMFUL IF
SWALLOWED.ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS MAY
EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES,
FAINTNESS, WEAKNESS AND DIARRHEA. MAY CAUSE IRRITATION OF GASTR
OINTESTINAL TRACT.
Explanation of Carcinogenicity:FOR COMPONENTS PRESENT AT 0.1% OR MORE:
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE - AMERICAN
CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH):
HYDROQUINONE, A3; CONFIRMED ANIMALCARCINOGEN WITH UNKNOWN
RELEVANCE TO HUMANS. - NATIONAL TOXICOLOGY PROGRAM (NTP): NONE -
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE
Effects of Overexposure:EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO BE
LOW HAZARD FOR RECOMMENDED HANDLING. IN CONTACT WITH STRONG ACIDS
OR IF HEATED, SULFITES LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE
GAS IS IRRITATING T O RESPIRATORY TRACT. ASTHMATICS OR
HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING.
EYES: CAUSES IRRITATION. SKIN: CAUSES IRRITATION. MAY CAUSE
ALLERGIC SKIN REACTION BASED ON HUMAN EXPE RIENCE. INGESTION: MAY
BE HARMFUL IF SWALLOWED. ASTHMATICS OR SULFITE-SENSITIVE
INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH
UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA. MAY CAUSE
IRRITATION OF GASTROINTESTINAL TRACT.
Medical Cond Aggravated by Exposure:ASTHMATICS OR SULFITE-SENSITIVE
INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH
UPSET, HIVES, FAINTNESS, WEAKNESS, AND DIARRHEA.
* First Aid Measures *
First Aid:INHALATION: MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET
MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: FLUSH WITH WATER FOR
MINUTES W HILE REMOVING CONTAMINATED CLOTHING AND SHOES. IF SKIN
IRRITATION OR AN ALLERGIC SKIN REACTION DEVELOPS, GET MEDICAL
ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE. DESTROY OR
THOROUGHLY CLEAN CON TAMINATED SHOES. INGESTION: DRINK 1-2 GLASSES
OF WATER. SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS PERSON.
* Fire Fighting Measures *
Flash Point:NONE.
Extinguishing Media:NONCOMBUSTIBLE LIQUID. USE APPROPRIATE AGENT FOR
ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE. NONCOMBUSTILE LIQUID.
* Accidental Release Measures *
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
*Handling and Storage *
Handling and Storage Precautions:PREVENTION OF FIRE AND EXPLOSION: NO
SPECIAL PRECAUTIONARY MEASURES SHOULD BE NEEDED UNDER ANTICIPATED
CONDITIONS OF USE. STORAGE: KEEP CONTAINER CLOSED. KEEP AWAY FROM
INCOMPATIBLE SUBSTANCES.
Other Precautions:AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH
EYES, SKIN, AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH
THOROUGHLY AFTER HANDLING. THE ROUTINE USE OF A NONALKALINE (ACID)
TYPE OF HAND CLEANER AND REGULAR CLEANING OF WORKING SURFACES,
REACTION.
* Physical/Chemical Properties *
HCC:B3
Vapor Density:0.6(AIR=1)
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS, ODORLESS, LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS.
Stability Condition to Avoid:STABLE.
Hazardous Decomposition Products:SULFUR DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Toxicological Information*
Toxicological Information:EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED
HANDLING. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY
LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO
THE RESPIRATORY TRACT. SO ME ASTHMATICS OR HYPERSENSITIVE
INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING.
* Ecological Information *
Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
* Disposal Considerations *
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS E VEN AFTER CONTAINER IS EMPTIED.
* MSDS Transport Information *
Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
MONDAY THROUGH FRIDAY.
* Regulatory Information *
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE. MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE.
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NO SPECIAL REQMNTS UNDER ORDINARY
CONDITIONS/ADEQUATE VENT.
Ventilation:MECH(GEN)OR LOCAL EXHAUST THAT PROVIDES ADEQUATE
VENTILATION
Other Protective Equipment:AS REQUIRED TO PREVENT PROLONGED CONTACT.
Supplemental Safety and Health
MSDS IS UNDATED.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SYNTHETIC HYDROCARBON
Fraction by Wt: UNKN
ACGIH TLV:NOT SPECIFIED
Ingred Name:ESTER
Fraction by Wt: UNK
ACGIH TLV:NOT SPECIFIED
Ingred Name:ADDITIVES (PERFORMANCE)
Fraction by Wt: UNKN
ACGIH TLV:NOT SPECIFIED
* Hazards Identification *
Effects of Overexposure:IN LOW & MODERATE DOSAGES,THE PRODUCT IS
CONSIDERED NON HAZARDOUS THROUGH INGESTN,INHALTN,SKIN&EYES
* First Aid Measures *
First Aid:UTILIZE GENERALLY ACCEPTABLE FIRST AID PROCEDURES FOR
TREATING INJURIES BELIEVED CAUSED BY ORGANIC CHEMICALS OF ANERT
NATURE.CALL A DOCTOR IF NECESSARY.
* Fire Fighting Measures *
Lower Limits:UNKN
Upper Limits:UNKN
Extinguishing Media:CO*2,FOAM,DRY CHEMICAL
Fire Fighting Procedures:NONE SPECIFIED BY THE MFR
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY THE MFR.
* Accidental Release Measures *
Spill Release Procedures:UTILIZE GENERALLY ACCEPTABLE PROCEDURES FOR
HANDLING CHEMICALS OF AN INERT NATURE.
*Handling and Storage *
Handling and Storage Precautions:STORE AT AMBIENT TEMPERATURES.USE
ADEQUATE VENTILATION
Other Precautions:AVOID SKIN AND EYE CONTACT.
* Physical/Chemical Properties *
HCC:V6
Vapor Pres:1.0
Evaporation Rate & Reference:NELIGIBLE
Solubility in Water:NEGLIGIBLE
Appearance and Odor:RED TINTED LIQUID SLIGHT ESTER ODOR.
Percent Volatiles by Volume:NEGL
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY THE MFR
Stability Condition to Avoid:NONE SPECIFIED BY THE MFR.
Hazardous Decomposition Products:NONE SPECIFIED BY THE MFR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL,STATE AND
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF TLV OF PROD OR ANY COMPONENT IS EXCEEDED, A
NIOSH/MSHA APPRVD AIR-SUPPLIED RESP IS ADVISED IN ABSENCE OF PROPER
ENVIRONMENTAL CONTROL. OSHA REGS ALSO PERMIT OTHER RESP UNDER
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV'S.
Other Protective Equipment:WEAR IMPERVIOUS CLOTHING & BOOTS. USE
BARRIER CREAMS & TAKE DAILY SHOWERS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:MOTORS, STATIC DISCHARGE OR OTHER IGNIT SOURCES AT LOCATIONS
DISTANT FROM MATL HNDLG POINT. NEVER USE WELDING/CUTTING TORCH
ON/NEAR DRUM (EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDUE) CAN IGN
ITE EXPLOSIVELY. SPILL PROC:ELEC SPARKS). PERSONS NOT WEARING PROT
EQUIP SHOULD BE EXCLUDED FROM AREA OF (SEE ING 5)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ING 7:OCCURS, NOTIFY PROPER AUTHORITIES AS REQUIRED, THAT A
SPILL HAS OCCURRED.
Ingred Name:WASTE DISP METH:DEPOSITED IN LANDFILL I/A/W LOCAL, STATE &
FEDERAL REGULATIONS.
Ingred Name:RESP PROT:BE IMPLEMENTED TO REDUCE EXPOSURE.
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
Fraction by Wt: <5%
Ingred Name:TOLUENE (SARA III)
Ingred Name:ISOBUTYL ACETATE (SARA III)
Ingred Name:ALIPHATIC PETROLEUM DISTILLATE
Ingred Name:SUPP DATA:SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP
SPILL AT SOURCE, DIKE AREA OF SPILL TO PVNT SPREADING(SEE ING 6)
Ingred Name:ING 5:& PUMP LIQ TO SALVAGE TANK. REMAINING LIQ MAY BE
TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORB, OR OTHER (SEE ING 7)
Ingred Name:ING 6:ABSORB MATL & SHOVELED INTO CNTNRS. PVNT RUN-OFF TO
SEWERS, STREAMS OR BODIES OF WATER. IF RUN-OFF (SEE ING 8)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE:CAN CAUSE SEVERE IRRITATION,
REDNESS, TEARING, OR BLURRED VISION. SKIN:PRLNGD/RPTD CONTACT CAN
CAUSE MODERATE IRRITATION, DEFATTING OR DERMATITIS. INHAL:EXCESSIVE
INHALATION OF VAPORS CAN CAUSE NA SAL & RESPIRATORY IRRITATION,
DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, POSSIBLE UNCON,
(SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:& EVEN ASPHYXIATION. INGEST:CAN CAUSE
GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, OR DIARRHEA.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:SKIN:THORO WASH EXPOSED AREA W/SOAP/WATER. REMOVE CONTAMD
CLTHG.WASH CONTAMD CLTHG BEFORE RE-USE. EYE:FLUSH W/LG AMTS OF
2 GLASSES OF WATER. INDUCE VOMIT IMMED BY STICKING FINGERS DOWN
THROAT.CALL MD. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON.
INHAL:REMOVE TO FRESH AIR. IF BRTHG STOPPED, GIVE ARTF RESP. KEEP
WARM/QUIET. GET MD.
* Fire Fighting Measures *
Flash Point Method:CC
Lower Limits:0
Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA W/FULL FACEPIECE
OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:VAPS ARE HEAVIER THAN AIR & MAY TRAVEL
ALONG GROUND OR MAY BE MOVED BY VENT & IGNITED BY PILOT LIGHTS,
OTHER FLAMES, SPARKS, HEATERS, SMOKING, ELEC (SUPP DATA)
* Accidental Release Measures *
Spill Release Procedures:SML:ABSORB LIQ ON PAPER, FLOOR ABSORB, OR
OTHER ABSORB MATL & TRANSFER TO HOOD. ELIMINATE ALL SOURCES OF
IGNIT SUCH AS FLARES, FLAMES (INCLDG PILOT LIGHTS) & ELEC SPARKS.
LG:ELIMINATE ALL IGNIT SOURCE S (FLARES,FLAMES, INCLDG PILOT
LIGHTS, (SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN
USE. CONTAINERS MAY BE HAZARDOUS WHEN EMPTY.
Other Precautions:SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES
(VAPOR, LIQUID &/OR SOLIDS), ALL HAZARD PRECAUTIONS GIVEN IN THIS
DATA SHEET MUST BE OBSERVED.
* Physical/Chemical Properties *
HCC:F3
Vapor Density:HVR/AIR
Solubility in Water:NONE
Appearance and Odor:POURABLE LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CO, CO*2.
* Disposal Considerations *
Waste Disposal Methods:SML:ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD.
ALLOW SUFFICIENT TIME FOR VAPS TO COMPLETLY CLEAR HOOD DUCT WORK.
DISPOSE OF REMAINING MATL I/A/W APPLICABLE REGS. LG:DESTROY BY LIQ
INCINERATION W/OFF -GASS SCRUBBER. CONTAMD ABSORB MAY BE (SEE ING
9)
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:A NIOSH-APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN .
Ventilation:SUITABLE TO MAINTAIN CONCENTRATION BELOW TLV'S.
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA .
Supplemental Safety and Health
PHYSICAL/CHEMICAL PROPERTIES (CON'T): PH (SUPPLIED): NOT DETERMINED. PH
NAME: LOCK-EASE.
* Product Identification *
Product ID:LOCK-EASE, PLASTIC BOTTLE, 3.4 OZ., LE-4
Preparer's Name:CHUCK HIDDEMA
* Composition/Information on Ingredients *
Ingred Name:COLLOIDAL GRAPHITE DISPERSION. (MFR CAS#: NOT ASSIGNED)
Minumum % Wt:1.
Maxumum % Wt:5.
ACGIH TLV:5 CU. M. (OIL MIST)
Ingred Name:ALUMINUM STEARATE BENZOATE COMPLEX. (MFR CAS#: NOT
ASSIGNED)
Minumum % Wt:1.
Maxumum % Wt:5.
ACGIH TLV:NOT ASSIGNED
Ingred Name:ALIPHATIC PETROLEUM NAPTHA
Ingred Name:PETROLEUM OIL. (MFR CAS#: NOT ASSIGNED)
Minumum % Wt:5.
ACGIH TLV:5 CU. M. (MIST)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: MAY CAUSE IRRITATION. SKIN: MAY
CAUSE IRRITATION, DEFATTING, DERMATITIS. CONTAMINATED CLOTHING MAY
CAUSE SEVERE IRRITATION. INGESTION: MAY CAUSE GASTROINTESTINAL
IRRITATION, NAUSEA AND VOMITING. INHALATION: MAY CAUSE IRRITATION
OR RESPIRATORY TRACT AND CENTRAL NERVOUS SYSTEM DEPRESSION. OTHER
EFFECTS: ASPIRATION INTO LUNGS MAY CAUSE PNEUMONITIS.
* First Aid Measures *
PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED
CLOTHING. IF ADVERSE EFFECTS OCCUR, CONSULT PHYSICIAN. INGESTION:
DO NOT INDUCE VOMITING; GET IMMEDIATE MEDICAL ATTENTION.
INHALATION: REMOVE TO FRESH AIR. ADMINISTER OXYGEN OR ARTIFICIAL
RESPIRATION AS REQUIRED. CONSULT PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:TCC
Autoignition Temp:Autoignition Temp Text:N/D
Lower Limits:N/D
Upper Limits:N/D
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM AND/OR WATER
FOG.
Fire Fighting Procedures:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT . WATER FOG MAY BE USED TO
REDUCE VAPOR CONCENTRATION.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND
ACCUMULATE IN LOW AREAS.
* Accidental Release Measures *
Spill Release Procedures:ABSORB WITH AN INERT MATERIAL.
*Handling and Storage *
Handling and Storage Precautions:CONDITIONS TO AVOID: EXCESSIVE HEAT.
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:NOT DETERMINED
Vapor Pres:NOT DETERMINED
Vapor Density:>1 (AIR=1)
pH:OTHER INFO.
Evaporation Rate & Reference:NOT DETERMINED
Solubility in Water:NIL
Appearance and Odor:BLACK LIQUID WITH PETROLEUM ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Hazardous Decomposition Products:OXIDES OF CARBON AND ALUMINUM.
* Toxicological Information*
Toxicological Information:PETROLEUM OIL IS SEVERELY HYDROTREATED OR
SOLVENT REFINED; IT DOES NOT REQUIRE LABEL AS A CARCINOGEN.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS . REMOVAL BY AN APPROVED
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE SCBA PP MODE W/FULL FACEPIECE.
Ventilation:GENERAL MECHANICAL
Other Protective Equipment:APRON, BOOTS OF NEOPRENE.
Work Hygienic Practices:WASH SOAP & WATER BEFORE EATING OR SMOKING.
REMOVE ALL CONTAMINATED CLOTHING, CAUNDER BEFORE REUSE AT JOBSITE
ONLY.
Supplemental Safety and Health
* Product Identification *
Product ID:TURCO TRANSPO GX (NEW FORM)
CAGE:0BYN5
CAGE:0BYN5
* Composition/Information on Ingredients *
Ingred Name:PHENOL
Other REC Limits:NONE
OSHA PEL:S, 5 PPM
Ingred Name:METHYLENE CHLORIDE(SARA III)
Other REC Limits:NONE GIVEN
Ingred Name:SODIUM BICHROMATE (SARA III)
= Wt:.4
Other REC Limits:NONE GIVEN
OSHA PEL:0.1 PPM CRO3;CEILING
Ingred Name:OCTYL PHENOL POLYETHYLENE GLYCOL ETHER
= Wt:1.
Other REC Limits:NONE GIVEN
* Hazards Identification *
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:CORROSIVE! CONTAINS DICHROMATE
CARCINOGEN. CORROSIVE DAMAGE POSSIBLE ON ALL EXPOSE TISSUES;
ORGANIC VAPORS MAY CAUSE HEDACHES & DIZZINESS. CHROMATES ATE SKIN
SENSITIZERS. METHYLENE CHLORIDE IS SUSPECT ED HUMAN CARCINOGEN.
Explanation of Carcinogenicity:HEXAVALENT CHROMIUM IS A CONFIRMED HUMAN
CARCINOGEN. METHYLENE CHLORIDE IS A SUSPECTED HUMAN CARCINOGEN.
Effects of Overexposure:EYE:SEVERE IRRITATION POSSIBLE, EXPOSURE TO
LIQUID MAY CAUSE BLINDNESS. SKIN:BURNS, NECROSIS, DEFATTING,
ABSORPTION, SENSITIZATION. INHALE: DIZZINESS, HEADACHE, INTOX,
CORROSIVE DAMAGE TO RESP TRACT. INGESTION: SEVERE GI TRACT
IRRITATION, DELAYED TOXIC EFFECTS, POSSIBLY FATAL.
Medical Cond Aggravated by Exposure:IMPAIRED CARDIO.PULMONARY FUNCTION
MAY BE FURTHER AGGRAVATED BY METHYLE CHLORIDE METABOLISM.
* First Aid Measures *
WASH SOAP & WATER AND RINSE. INHALE: REMOVE TO FRESH AIR, GIVE
OXGEN OR ARTIFICIALS RESP AS REQUIRED. INGESTION: DO NOT INDUCE
VOMITING. IF CO NSCIOUS, GIVE LARGE QUANTITY WATER OR MILK. GET
PROMPT MEDICAL ATTENTION IN ALL CASES. TRY TO DETERMINE EXPOSURE
DOSAGE.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:CARBON DIOXIDE, FOAM, WATER FOG.
Fire Fighting Procedures:USE SCBA PP MODE WHEN FIGHTING FIRES. RUNOFF
WATER MAY CONTAIN HEXAVALENT CHROME AND MUST NOT ENTER SEWER OR
WATERWAYS.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN SPILL, STOP LEAK, VENTILATE AREA,
EVACUATE NONESSENTIAL PERSONNEL. SHOVEL OR PUMP SPILLAGE INTO
CLOSABLE DRUMS. COLLECT REMAINDER W/ABSORBENT, PLACE IN DRUMS.
WASHDOWN SPILL AREA, COLLECT WAS HWATER AND DON'T ALLOW ENTRY INTO
SEWEROR STREAMS
Neutralizing Agent:NONE GIVEN
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, SHADED, DRY AREA.
VAPORS ARE HEAVIER THAN AIR, MAY COLLECT IN LOW AREAS-ASPHYXIATION
HAZARD.
Other Precautions:FOLLOW ALL NOTMAL SAFETY PROCEDURES WHEN ENTERING
CONFINED AREAS: USE RESPIRATORY PROTECTION,SAFETY LINE, WORK IN
PAIRS.
* Physical/Chemical Properties *
HCC:C2
Vapor Density:>1
Evaporation Rate & Reference:(BUAC = 1), <1.
Solubility in Water:APPRECIABLE
Appearance and Odor:TWO LAYER LIQUID, PHENOLIC ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, OXIDIZERS.
Stability Condition to Avoid:EXCESS HEAT, OPEN FLAMES
Hazardous Decomposition Products:CARBON OXIDES, PHOSGENE,ACID
GASES,OTHER VOLATILE TOXIC ORGANICS.
* Disposal Considerations *
Waste Disposal Methods:RECLAIM AND RECYCLE FOR SOLVENT RECOVERY OR
CHEMICALLY TREAT BY LICENSED CONTRACTOR. ORGANICS DISPOSAL BY
INCINERATION AND/OR CARBON TREATMENT.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE ONLY NIOSH/MSHA APPROVED RESPIRATORS
MASK TO AVOID BREATHING OF SANDING DUST.
Ventilation:DILUTION/LOCAL EXHAUST TO PREVENT BUILDUP OF VAPORS.
Other Protective Equipment:EYE WASH, SAFETY SHOWER
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE
CONTENTS MAY BE HARMFUL/FATAL.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL
Fraction by Wt: 1-5%
Ingred Name:RED IRON OXIDE/IRON (III) OXIDE/FERRIC OXIDE/YELLOW FERRIC
OXIDE/YELLOW IRON OXIDE/IRON OXIDE PIGMENT
Fraction by Wt: 1-5%
ACGIH TLV:5 MG/CUM (FE)
Fraction by Wt: 1-5%
Fraction by Wt: 1-5%
Ingred Name:VOLATILE ORGANIC CONTENT: 8.6 LBS/GAL
Ingred Name:FATTY ACIDS, TALL-OIL, POLYMER W/GLYCEROL, PENTAERYTHRITOL
Ingred Name:TALC (POWDER), (ASBESTOS FREE), TALCUM; HYDROUS MAGNESIUM
OSHA PEL:2 MG/CUM (RESP DUST)
ACGIH TLV:2 MG/CUM (RESP DUST)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: RESPIRATORY TRACT
IRRITANT. CNS DEPRESSION/ANESTHETIC EFFECT. SKIN:
IRRITATION/DERMATITIS. EYES: SEVERE IRRITANT, BLURRED VISION.
INGESTION: LARGE AMOUNTS CAUSE LUNG INFLAMMATION & DAMAGE DUE TO
ASPIRATION. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENT MAY CAUSE
PERMANENT BRAIN/NERVOUS SYSTEM DAMAGE. (SEE SUPP
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION, FATIGUE, DROWSINESS, DIZZINESS,
LIGHTHEADEDNESS, HEADACHE, UNCOORDINATION, NAUSEA, NARCOSIS,
DEFATTING OF SKIN, BLURRED VISION, TEARING, REDNESS, INFLAMMATION
Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN, RESPIRATORY
& LUNG DISORDERS, ASTHMA-LIKE CONDITIONS.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED
BREATHING. HAVE TRAINED PERSON GIVE OXYGEN IF NEEDED. SKIN: WASH
OFF QUICKLY W/PLENTY OF WATER, THEN SOAP & WATER. EYES: FLUSH
ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:CC
Lower Limits:1
Extinguishing Media:DRY CHEMICAL/FOAM
Fire Fighting Procedures:WATER MAY BE USED TO COOL & PROTECT EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT/FIRE. VAPORS CAN FORM EXPLOSIVE MIXTURES IN
AIR AT ELEVATED TEMPS. EMITS TOXIC GASES UNDER FIRE.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. VENTILATE
AREA. MAY BE COLLECTED W/NONCOMBUSTIBLE ABSORBENT MATERIALS.
*Handling and Storage *
SPARKS & OPEN FLAME. KEEP CONTAINERS TIGHTLY CLOSED & UPRIGHT WHEN
NOT IN USE. USE ONLY W/ADEQUATE VENTILATION.
Other Precautions:GROUND EQUIPMENT WHEN TRANSFERRING TO PREVENT
ACCUMULATION OF STATIC CHARGE. DON'T TAKE INTERNALLY. KEEP OUT OF
REACH OF CHILDREN. AVOID CONTACT W/SKIN & EYES & BREATHING OF
VAPORS. EMPTY CONTAINERS M AY CONTAIN HAZARDOUS RESIDUES.
* Physical/Chemical Properties *
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS, BASES, AMINES
Stability Condition to Avoid:EXTREME HEAT/FIRE/OPEN
FLAMES/SPARKS/ELEVATED TEMPERATURES.
Hazardous Decomposition Products:CO, CO2
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
COMBUSTIBLE LIQUID.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:DISPOSABLE TOXIC DUST/MIST RESPIRATORS;SELF-
CONTAINED BREATHING AIR SUPPLY(IN CASE OF EMERGENCY).
Ventilation:USE SUFFICIENT VENTI TO KEEP EMPLOYEE EXPO BELOW
RECOMMENDED LIMITS.
Other Protective Equipment:FCSHIELD,RUBB SUIT/APRON/BOOTS;DISPO TOXIC
DUST/MIST RESP;SCBA(EMERG);HYDROGEN CYANIDE DETECTOR;1STAID/MED
TREAT SUPPLY.
Work Hygienic Practices:TRAIN PERSON W/POT FOR CYANIDE POIS IN 1STAID
W/ OXY/AMYL NITRITE.PLAN/PRACT ACTIONS IN CASE OF POIS BEF WORK
W/CYANIDE.
Supplemental Safety and Health
ARREST,CYANOSIS THEN CARDIOVASCULAR COLLAPSE, APNEA,HYPOXIC.SIGNS
IPECAC/OHTER EMETICS.CALL DR.
* Product Identification *
Product ID:CYANOBRIK, SODIUM CYANIDE
Preparer's Name:HMIS-VBA
* Composition/Information on Ingredients *
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG(CN)/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY BE FATAL IF INHAL/INGEST/ABSORB
THRU SKIN.CONTACT W/ACIDS,WATER,OR WEAK ALKALIES LIBERATES
POISONOUS HYDROGEN CYANIDE GAS. CAUSES EYE BURNS. MAY SKIN
IRRITATIONS. TARGET ORGANS: LIVER, SYSTEMIC SY STEM.
Explanation of Carcinogenicity:PER MSDS:NONE OF COMPO PRESENT IN MATL
@CONCEN =/> 0.1% ARE LISTED BY IARC/NTP/OSHA/ACGIH AS CARCINOGEN.
Effects of Overexposure:BURNS,SKIN/EYE IRRIT W/DISCOMFT,RASH, EYE
BURNS,TEAR,BLURR VISION.EXCESS/PROL CONTACT MAY RESULT IN PERM EYE
DMG. OVEREXPO CHARACTERIZED BY CNS EXCITATION FOLLOWED BY
DEPRESSION.SYMPT:RED EYES,IRRIT T HROAT,PALPITATION,DIFF
BREATH,SALIVATION,NUMB,NAU,HEAD,WEAK IN
ARMS/LEGS,GIDDINESS,COLLAPSE,CONVULS.CONVL/COMA(SU
Medical Cond Aggravated by Exposure:INDIVIDUALS W/PRE-EXISTING DISEASES
OF CENTRAL NERVOUS SYSTEM MAY HAVE INCREASED SUSCEPTIBILITY TO
TOXICITY OF EXCESSIVE EXPOSURES.
* First Aid Measures *
First Aid:RECOMMEND STEP-WISE PROCEDURE OF 1STAID(OXY, AMYL NITRITE) &
MED TREATMENT(INTRAVENOUS INJECTIONS OF SODIUM NITRITE & SODIUM
THIOSULFATE BY QUAL MED PERSON,FOR LG POISONINGS).START 1STAID
IMMED.CALL D R.REMOVE FROM EXPO.REMOVE CONTAMIN CLOTH.IMMED FLUSH
W/LG QUANT OF WATER UP TO 5MINS.EYE:FLUSH W/LG QUANT OF WATER UP TO
5MINS,HOLD OPN EYELIDS.DON'T NEUTRA W/ACID/ALKLIS.SEE
DR.INGEST:CONSC GIVE(SUPP
* Fire Fighting Measures *
Flash Point:WILL NOT BURN
Autoignition Temp:Autoignition Temp Text:NA
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:USE WATER ON FIRE NEAR CYANIDE BUT MIN AMT IF CNTRN
CYANIDE)
Fire Fighting Procedures:RUNOFF SHOUDLB E CONTAINED TO AVOID ENVIRO/
SAF PROBLEMS;DETOXIFIED W/HYPOCHLORITE.SOME CASES LET FIRE BURN OUT
BY ITSELF.
Unusual Fire/Explosion Hazard:FOLLOW APPROPRIATE NFPA CODES.CYANIDE MAY
NOT BE COMPLETELY DESTROYED IN ORDINARY FIRE.SODIUM CYANIDE DOESNT'
SUPPORT COMBUST,CAN OXIDIZE IN FIRE.
* Accidental Release Measures *
Spill Release Procedures:REVIEW FIREFIGHT/HDNGL SECS.USE APPROPRIATE
PPE.SHOVEL/SWEEP INTO COVERED CNTNR/PLASTIC BAG.COVER/KEEP
DRY.FLUSH AREA W/DIL SOLN OF SODIUM HYPOCHLORITE OR CALCIUM
HYPOCHLORITE.CALL DUPONT FOR GUIDANCE .COMPLY W/FED/STATE/LOC
Neutralizing Agent:DESTROY CYANIDE W/DIL SOLN OF SODIUM HYPOCHLORITE OR
CALDIUM HYPOCHLORITE.
*Handling and Storage *
Handling and Storage Precautions:STORE IN PROPERLY LABEL CNTNR IN DRY
VENTI SECURED AREA.KEEP CLSD/DRY.DON'T STORE W/ACID,ACID
SALT,H2O,WEEK ALKALI, OXID AGENT.STORE AWAY FROM FOOD,ET
Other Precautions:ADEQUA 1STAID SUPPLY CONVENIENTLY PLACE THRUOUT
AREAS/ IMMED ACCESSIBLE/SECURED.ROUTINELY INSPECT SUPPLY.ADHERE TO
PROPER STORAGE/ INSPECT REPALCE.SUPPLY:OXY RESUSCITATOR,AMYL
NITRITE AMPOULES(ANTIDOT E)(NOT STABLE,REPLACE 1-2 YRS),INSTRUCTI
* Physical/Chemical Properties *
HCC:T2
Decomp Temp:Decomp Text:NP
Vapor Pres:NEGLIGIBLE
Vapor Density:NIL
Spec Gravity:1.6
pH:SUPPLE
Viscosity:N/RP
Evaporation Rate & Reference:NP
Appearance and Odor:SOLID,GRANULAR,BRIQUETTES,WHITE.SOLID NO ODOR,DAMP
SLIGHT AMMONI &/OR HNC ODOR.
Percent Volatiles by Volume:NP
Corrosion Rate:NP
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS,STRONG OXIDIZING AGENTS,WATER,WEAK ALKALINE SOLUITONS,MOISTURE.
Stability Condition to Avoid:CONTACT W/ACIDS-LG AMTS FO POS FLAMM HCN
GAS.RXS VIOLENTLY W/STRONG OXIDIZ WHEN HEAT.WATER/WEAK ALKALINE
SOLN GIVES HCN.
Hazardous Decomposition Products:MOISTURE WILL CAUSE SLOW
DECOMPOSITION, RELEASING POISONOUS HYDROGEN CYANIDE(HCN) & AMMONIA
GASES.
* Disposal Considerations *
Waste Disposal Methods:EXTREMELY AQUATIC TOXICITY.MAY BE RCRA HAZ
WASTE. DON'T FLUSH INTO SEWERS-MAY CONTAIN ACID.DETOXIFY W/DIL
SODIUM HYPOCHLORITE,HYDROGEN PEROXIDE,OR CALCIUM
HYPOCHLORITE.COMPLY W/FED/STATE/ LOC REGS.TRA NSFER TO LIC DISPO
CONTRACTOR.SARA/CERCLA CHEM.
| 1 | gloves_mandatory |
Control Measures
*
Cage: 0FTT5
*
Preparer Co. when other than Responsible Party Co.
*
Cage: 0FTT5
*
Contractor Summary
*
Cage: 0FTT5
*
Item Description Information
*
Item Manager: GSA
Item Name: ENAMEL
Type/Grade/Class: TYPE I
Unit of Issue: BX
UI Container Qty: 0
*
Ingredients
*
Other REC Limits: NONE RECOMMENDED
------------------------------
Other REC Limits: NONE RECOMMENDED
------------------------------
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Other REC Limits: NONE RECOMMENDED
------------------------------
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
------------------------------
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: 5 PPM
------------------------------
Other REC Limits: NONE RECOMMENDED
------------------------------
Other REC Limits: NONE RECOMMENDED
------------------------------
Other REC Limits: NONE RECOMMENDED
------------------------------
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
------------------------------
Other REC Limits: NONE RECOMMENDED
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE: IRRIT. SKIN: IRRIT. INHAL: HARMFUL, FATAL, BRAIN/NS
DAMAGE, ANESTHETIC, IRRIT TO RESPIRATORY TRACT, LIGHTHEADED, STAGGERING GAIT,
GIDDY, NAUSEA, THROAT IRRIT, VOMITING, HEADACHE. INGEST: HARMFUL.
Explanation Of Carcinogenicity: NO
Medical Cond Aggravated By Exposure: RESPIRATORY AILMENTS
WASH CLOTHES BEFORE REUSE. INHAL: REMOVE TO FRESH AIR. ARTIF RESP IF NEEDED.
INGEST: DONT INDUCE VOMIT. IN ALL CASES, GET MED AID.
*
Handling and Disposal
*
Spill Release Procedures: REMOVE IGNITS. VENT AREA. MOP SPILLS W/INERT
ABSORBENT. AVOID BREATHING VAPORS.
Waste Disposal Methods: IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
EXPOSURE TO SUN MAY CAUSE CAN TO BURST. DISCARD EMPTY CAN IN TRASH PICK-UP.
DONT PLACE IN HOME TRASH COMPACTOR.
Handling And Storage Precautions: KEEP OUT OF REACH OF CHILDREN. CAUTION:
Other Precautions: USE W/GOOD VENTILATION. READ ENTIRE LABEL BEFORE USING.
FOLLOW ALL LABEL DIRECTIONS.
*
Fire and Explosion Hazard Information
*
Lower Limits: 2.2
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM, SAND, WATER SPRAY.
AVOID SPREADING ANY BURNING LIQUID W/WATER SPRAY.
Fire Fighting Procedures: WATER MAY BE INEFFECTIVE. USE WATER TO COOL
CONTAINERS. USE SCBA. USE SHIELDING TO PROTECT PERSONNEL AGAINST BURSTING,
RUPTURING, VENTING OF CONTAINERS.
CONTAINERS MAY VENT, RUPTURE, BURST. AEROSOL CONTAINERS: DO NOT EXPOSE TO
*
*
Respiratory Protection: USE NIOSH/MSHA APPROVED MASK ABOVE TLV.
Ventilation: LOCAL EXHAUST PREFFERED. MECHANICAL (GENERAL) ACCEPTABLE AT POINT
OF MIST OR SPRAY RELEASE.
Other Protective Equipment: IMPRVIOUS CLOTHES TO PROTECT SKIN, EYEWASH STATION.
Work Hygienic Practices: DONT EAT, DRINK OR SMOKE WHILE USING THIS PRODUCT.
*
Physical/Chemical Properties
*
B.P. Text: NA
M.P/F.P Text: NA
Decomp Text: NA
PH: NA
Viscosity: NA
Solubility in Water: INSOLUBLE
Appearance and Odor: BROWN PAINT
Corrosion Rate: NA
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: EXTREME HEAT
Materials To Avoid: NA
Hazardous Decomposition Products: CARBON MONOXIDE
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NA
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
Transportation Information
*
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: BX
Container QTY: 0
*
Detail DOT Information
*
DOT PSN Code: DTJ
Symbols: D
DOT Proper Shipping Name: CONSUMER COMMODITY
Hazard Class: ORM-D
Label: NONE
Bulk Pack: NONE
Vessel Stow Req: A
*
Detail IMO Information
*
IMO PSN Code: AKH
IMO Proper Shipping Name: AEROSOLS/AEROSOL PRODUCT ?
UN Hazard Class: 9?
IMO Packaging Group: -
Subsidiary Risk Label: -
*
Detail IATA Information
*
IATA PSN Code: ALS
IATA Proper Shipping Name: AEROSOLS, FLAMMABLE
IATA PSN Modifier: (EACH NOT EXCEEDING 1 L CAPACITY)
IATA UN Class: 2.1
IATA Label: FLAMMABLE GAS
*
Detail AFI Information
*
AFI PSN Code: ALR
AFI Symbols: *
AFI Proper Shipping Name: AEROSOLS, FLAMMABLE, N.O.S.
AFI PSN Modifier: (EACH NOT EXCEEDING 1L CAPACITY)
AFI Hazard Class: 2.1
Special Provisions: P4
Back Pack Reference: A6.3
*
HAZCOM Label
*
Cage: 0FTT5
Company Name: LHB INDUSTRIES
Label Required IND: Y
Status Code: A
Origination Code: G
Hazard And Precautions: EYE: IRRIT. SKIN: IRRIT. INHAL: HARMFUL, FATAL,
BRAIN/NS DAMAGE, ANESTHETIC, IRRIT TO RESPIRATORY TRACT, LIGHTHEADED,
STAGGERING GAIT, GIDDY, NAUSEA, THROAT IRRIT, VOMITING, HEADACHE. INGEST:
HARMFUL.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGE OR AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS
Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO
MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:RUBBER BOOTS AND APRON RECOMMENDED.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
NON-REGULATED CLEANING COMPOUND.
* Product Identification *
CAGE:0SPP4
CAGE:0SPP4
* Composition/Information on Ingredients *
Ingred Name:2-PYRROLIDIONE OR N-METHYLPYRROLIDONE
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
Ingred Name:PENTANEDIOIC ACID, DIMETHYL ESTER (MIXED WITH INGREDIENT #4
Other REC Limits:NONE RECOMMENDED
Ingred Name:DIMETHYL ADIPATE, METHYL ADIPATE, HEXANEDIOIC ACID DIMETHYL
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE SKIN AND EYE IRRITATION.
INHALATION MAY CAUSE IRRITATION TO MUCOUS MEMBRANES IF INHALED.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION. INHALATION:
IRRITATION OF MUCOUS MEMBRANES.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:IN ALL CASES GET MEDICAL ATTENTION. EYES-FLUSH WITH WATER FOR
WATER. INHALED-REMOVE TO FRESH AIR. INGESTED-DO NOT INDUCE
VOMITING! I F CONSCIOUS, GIVE MILK OR WATER.
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE.
Fire Fighting Procedures:USE BLANKET OR SMOTHER AFFECT TO PUT OUT FIRE.
WATER IS MOST EFFECTIVE WHEN USED IN A MIST.
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:CLEANUP PERSONNEL MUST WEAR PROPER PROTECTIVE
EQUIPMENT. RECLAIM MATERIAL INTO CLOSED CONTAINER FOR POSSIBLE
NORMAL USE OR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL PLACE AWAY FROM HEAT
AND FLAMES. PRODUCT MAY CAUSE SOME AFFECT TO PAINTED SURFACES. USE
SOLVENT RESISTANT EQUIPMENT.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.
* Physical/Chemical Properties *
HCC:N1
Vapor Density:<1 (AIR=1)
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR LIQUID. FAINT PINE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED RESPIRATOR IN NONVENTILATED AREAS
AND/OR FOR EXPOSURE ABOVE THE ACGIH TLV.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SILICA, AMOPHOUS FUMED; (SILICA FUMED)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF INHALED. MAY BE
HARMFUL IF SWALLOWED. CAUSES EYE IRRITAITON. MATERIAL IS IRRITATING
TO MUCOUS MEMEBRANES AND UPPER RESPIRATORY TRACT. MAY CAUSE SKIN
IRRITATION. CHRONIC: TARGET ORGAN (S): LUNGS. (TOXIC INFO)
Effects of Overexposure:SEE HEALTH HAZARD.
* First Aid Measures *
First Aid:EYES: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS
OF THE EYES BY SEPARATING THE EYELIDS WITH FINGERS. SKIN: IN CASE
OF CO NTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF
WATER. INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT
BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. INGESTION: IF SWALLOWED, WASH OUT MOUTH WITH WATER
PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN.
* Fire Fighting Measures *
Extinguishing Media:NONCOMBSUTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE
TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
* Accidental Release Measures *
Spill Release Procedures:WEAR NIOSH APPROVED RESPIRATOR, CHEMICAL
PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST.
VENTILATE AREA AND WASH SPILL S ITE AFTER MATERIAL PICKUP IS
COMPLETE.
*Handling and Storage *
Handling and Storage Precautions:AVOID CONTACT AND INHALATION. HARMFUL
DUST. IRRITANT. KEEP CONTAINER CLOSED. STORE IN A COOL DRY PLACE.
* Physical/Chemical Properties *
Appearance and Odor:SOLID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS. PROTECT FROM MOISTURE.
Hazardous Decomposition Products:NATURE OF DECOMPOSITION PRODUCTS NOT
KNOWN.
* Toxicological Information*
OR RESPIRATION (ACUTE P ULMONARY EDEMA) ONLY SELECTED REGISTRY OF
TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED
HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION.
* Ecological Information *
Ecological:DATA NOT YET AVAILABLE.
* Disposal Considerations *
Waste Disposal Methods:BURY IN A LANDFILL SITE APPROVED FOR THE
DISPOSAL OF CHEMICAL AND HAZARDOUS WASTES. OBSERVE ALL FEDERAL,
STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
* MSDS Transport Information *
Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
* Regulatory Information *
Federal Regulatory Information:EUROPEAN INFORMATION: CAUTION: SUBSTANCE
WITH EYES, RINSE IMMEDIATE LY WITH PLENTY OF WATER AND SEEK MEDICAL
DUST.
State Regulatory Information:REVIEWS, STANDARDS, AND REGULATIONS:
OEL=MAK. IARC CANCER REVIEW: ANIMAL INADEQUATE EVIDENCE IMEMDT
* Other Information *
| 1 | gloves_mandatory |
Subsets and Splits