Abstract
Magnesium hydride is regarded as one of the most ideal candidates for hydrogen storage, but its relatively high operating temperatures and slow kinetics always hinder its commercial applications. Herein, we first fabricated hard-carbon-sphere-wrapped Ni (Ni/HCS) via a mild chemical method; subsequently, the asprepared additive was introduced to fabricate an Mg-Ni/HCS composite by using hydriding combustion synthesis. Hard carbon spheres (HCS) effectively inhibited the agglomeration of hydride particles during hydrogen storage cycling; they could also provide active sites to promote the nucleation of Mg-based hydrides. During the hydriding combustion synthesis procedure, in situ-formed Mg 2 NiH 4 could induce the absorption of MgH 2 , thus triggering its hydrogen properties. Remarkable enhancement in hydrogen absorption properties of the composite was found. The composite absorbed 6.0 wt% H 2 within 5 min at 275 C; moreover, even at 75 C, it could still absorb 3. ).
Introduction
One of the most technically challenging issues anticipated for future hydrogen economy is the development of safe and efficient onboard hydrogen storage materials.
1 A variety of materials that satisfy the requirements of sufficient storage density, benecial thermodynamics, desirable kinetics, and low cost have been studied in pursuit of a suitable hydrogen storage system.
2,3
Among solid-state hydrogen storage systems, magnesium-based hydrides have been proposed to be promising candidates for effective hydrogen storage due to their high volumetric and gravimetric hydrogen storage capacities, high abundance, low cost, nontoxicity, and high safety. 4 However, their unfavorable thermodynamic stability and slow kinetic behavior signicantly obstruct their commercial use, and proper strategies are required to overcome these problems. During the past decade, many methods have been discovered and proven to be effective for magnesium hydride systems, and they include both chemical and physical methods. [5] [6] [7] [8] [9] [10] [11] One of these methods involves alloying with transition metal elements (e.g., Mg 2 Ni); Mg-based alloys exhibit better thermal instability of hydrides than pure magnesium.
12-15
However, the unavoidable loss of hydrogen storage capacity is the major drawback of the alloying route due to the addition of a transition metal. To solve this problem, a benecial solution is to build MgH 2 -rich complex hydrides, 16 i.e., MgH 2 -Mg 2 NiH 4 composites, which exhibit a considerable reduction in stability without a clear loss in capacity. 14, 17 Recently, the introduction of various novel catalysts has been used as another strategy to relieve the kinetic barrier and thermodynamic stability of magnesium hydride systems. [18] [19] [20] [21] [22] [23] [24] Catalysts are usually supposed to function as activation agents, forming intermediate metastable states, facilitating dynamics, and destabilizing the Mg-H bonding energy. Furthermore, another very effective technique to relieve the kinetic barrier and thermodynamic stability of Mgbased hydrides is nanostructuring, 25 which can directly result in larger surface-to-volume ratio of the particles and shorter solidstate diffusion distances for hydrogen. Recently, extensive experimental and theoretical studies have demonstrated that decreasing the particle size is an efficient way to destabilize Mgbased hydrides, leading to further enhancement in hydrogen storage performances. [26] [27] [28] [29] [30] However, high reactivity of Mg-based hydrides restricts the synthetic methods for nanostructuring because of severe agglomeration. Meanwhile, owing to high surface energy, the original hydride nanoparticles always tend to aggregate based on the solid-state reactions, leading to rapid loss of the initial morphology and continual reduction in storage capacities. 31 Previously, Imamura and coworkers had reported studies on catalyzing MgH 2 with graphite; 32,33 since then, many carbon materials, including multiwalled carbon nanotubes (MWCNT), 34 single-walled carbon nanotubes (SWCNT), [35] [36] [37] graphene nanosheets (GNS), 38 and activated carbon, 39 have been extensively studied to promote the hydrogen storage properties of MgH 2 . Although these issues can be solved by dispersing MgH 2 into porous carbon hosts, these strategies unfortunately suffer from irregular spatial distributions and low inltration efficiency.
40,41
As the demand for renewable energy continues to grow, efforts toward improving the efficiency of carbon materials are getting more and more attention. Yuan et al. 42 studied Mg-based hydrides associated with carbon-based catalysts; by focusing on the roles of metal-assisted MWCNT hybrids, they revealed that MWCNTs and supporting metallic particles have a synergetic catalytic effect. Meanwhile, Yao et al. 43 also reported the synergistic effect of metallic couple and carbon nanotubes on Mg, yielding ultrafast kinetics due to metal-H atomic interactions at the Mg surface. In addition, Ismail and coworkers 44 showed that 10 wt% K 2 NbF 7 and 5 wt% MWCNT milled with MgH 2 signi-cantly reduced the initial decomposition temperature to 248 C with a capacity of 6.2 wt%; they also found that co-doping FeCl 3 and CNTs with MgH 2 resulted in both decreased desorption temperature and improved sorption kinetics when compared to those of the undoped MgH 2 -FeCl 3 composite. 45 Amirkhiz et al.
46
examined the effect of SWCNT-metallic nanoparticle additions on the hydrogen desorption behavior of MgH 2 ; aer highenergy co-milling, they found that SWCNT-nanoparticle additions have benecial inuence on the desorption kinetics. Furthermore, in the carbon family, hard carbon spheres (HCS) have attracted tremendous attention due to their notable physical and chemical properties. For example, Yang et al.
47
studied monodispersed hard carbon spherules as a catalyst support for the electrooxidation of methanol. Moreover, because of their superior surface area and controllable homogeneous structure, carbon spheres can provide several promising applications in energy storage. Therefore, the introduction of HCS as a support in Mg-based hydride systems has considerable potential for signicantly enhancing the de/absorption properties. Herein, we controllably fabricate hard carbon spherewrapped Ni additives by a chemical method and then, we introduce these materials into Mg-based hydride systems; signicant enhancement in their de/absorption behaviors has been observed. Moreover, a possible mechanism for the catalytic phase in the system has been proposed.
Experimental

Synthesis of Ni/HCS and Mg-Ni/HCS
All chemicals were of analytical grade and used without any further purication. The typical preparation process of HCS was based on a solvothermal method followed by a calcination procedure at high temperatures. During the hydrothermal process, we selected sucrose (Aladdin, AR, 0.28$0.90 mm) as the precursor; then, the precursor was subjected to a dewatering process, yielding carbon spheres. An aqueous sucrose solution of 0.2 mol L À1 was lled in a Teon-lined autoclave at a ll rate of 80%, which was heated gradually to 190 C and maintained at this temperature for 5 h. The obtained black precipitated particles were separated by ltration and washed with deionized water and ethanol (Aladdin, AR, S99.5%), and this process was repeated several times. The prepared black powders were fully dried in vacuum at 60 C for 24 h to obtain a solid product, namely, carbon spheres (CS). Then, the as-prepared CS were further carbonized at 950 C for 4 h under an argon atmosphere in a tube furnace. Then, the product was naturally cooled and transferred into a glovebox for further handling; the obtained nal product was denoted as HCS. Then, HCS were initially treated with concentrated nitric acid (Aladdin, AR, 65-68%) to introduce carbonyl, carboxylic, and hydroxyl groups onto the surfaces; these functional groups may provide nucleation sites for metal species. To synthesize Ni/HCS, we mixed HCS and Ni(NO 3 ) 2 $6H 2 O (Aladdin, AR, 98%) at a mass ratio of 6 : 4 (Ni : HCS) in 50 mL acetone (Sigma-Aladdin, AR, S99.5%); this mixture was subjected to ultrasonic treatment for half an hour and dried in a blowing dry oven at 50 C for 8 h. Aerwards, the product was heat-treated in a tube furnace at 400 C for 4 h under an Ar atmosphere. Finally, the products were reduced under an H 2 atmosphere at 450 C for 24 h.
The Mg-Ni/HCS composite was synthesized via hydriding combustion synthesis of Mg powder (Shanghai Pantian nano Materials Co., 99.9%, 1 mm), yielding Ni/HCS with a mass ratio of 5 : 1. In the hydriding combustion synthesis process, 0.75 g of crude magnesium powder and 0.15 g Ni/HCS were mixed in a pressure reactor vessel and heated to 400 C under a hydrogen pressure of 4 MPa for 40 h. Subsequently, the sample was mechanically milled in a stainless steel vial with a ball-topowder weight ratio of 30 : 1 under an Ar atmosphere. The ball milling process was paused for 15 min aer each 15 min of milling to avoid increasing the temperature of the sample. For comparison, an Mg-HCS composite was synthesized under the same conditions, and pure MgH 2 (Aldrich, 95%) was also prepared by a planetary ball mill under the same conditions. All the materials were handled in a glove box lled with puried argon (99.999%), which could maintain the water vapor and oxygen levels below 1 ppm by recycling the purication system to avoid oxidation.
Structural analysis and hydrogen desorption experiments
A Rigaku SmartLab X-ray diffractometer (XRD) with Cu Ka radiation was used to complete phase analysis. During the sample transfer and scanning process, an argon-lled container was used to prevent the samples from contacting air and moisture. The microstructure was further examined by transmission electron microscopy (TEM, JEM-2010, working at 120 kV) equipped with energy dispersive analysis by X-ray spectroscopy (EDAX). A scanning electron microscope (SEM, S-3400) was used to observe the surface morphology, and nitrogen ow was applied to prevent H 2 O/O 2 contamination during the transfer process. The specic surface areas and porous nature of the as-prepared HCS were further, investigated by nitrogen adsorption/desorption measurements (ASAP 2020 Plus).
Brunauer-Emmett-Teller (BET) and Barrett-Joyner-Halenda (BJH) methods were used to calculate the surface area and pore size distribution, respectively, based on the desorption data. The thermal behavior of the sample was investigated by thermal analysis (DTG-60A) from room temperature to 500 C at different heating rates (5, 10, 15, 20 C min À1 ). The valence states and structural information of the synthesized Ni/HCS were determined using an X-ray photoelectron spectrometer (XPS).
The hydrogen desorption and absorption properties of the as-synthesized Mg-Ni/HCS and Mg-HCS were determined using Sieverts-type pressure-composition-temperature (PCT). During isothermal rehydrogenation experiments, the composites were pressurized at 3 MPa. For the cyclic stability measurements of the composite, we performed dehydrogenation under 0.001 MPa for 2 h, and the hydrogenation process was carried out at 3 MPa for 1 h. (002) and (100) reections of the graphite layers are observed aer carbonization in the tube furnace, indicating that the second process yields graphitization of HCS. Moreover, the peak of (002) shis slightly to a higher 2q value aer the second carbonization process. The specic surface areas and features of HCS are further investigated by nitrogen adsorption/desorption measurements. BET analysis (Fig. 1b) indicates that the asprepared HCS have a specic surface area and pore volume up to 623 m 2 g À1 and 0.22 cm 3 g À1 , respectively. The pore size distributions are calculated from the desorption isotherms by the BJH method, and the peak in the BJH pore distribution is at 40 nm, exhibiting the characteristics of a mesoporous material. This is in good agreement with the following microscopy nd-ings (Fig. 3d) . The high surface area of HCS with mesoporous materials can undertake the role of a mechanical support, and it is believed that HCS can easily anchor and load Ni-and Mgbased composites with uniform dispersion; this indicates that it can play an important role in mediating the nucleation and growth of Mg-based particles coupled with this hydrogenation process strategy. Fig. 2a shows the XRD patterns of Ni/HCS, Mg-Ni/HCS, and Mg-HCS composites before ball milling. As shown in Fig. 2a To obtain additional information on the valence states of Ni and HCS in Ni/HCS particles, X-ray photoelectron spectroscopy (XPS) was used ( Fig. 2b-d) . From the full spectrum (Fig. 2b) , it is evident that the peaks of Ni were dominant; the peak observed at 854 eV corresponded to the bond of Ni 2p (Fig. 2c) , demonstrating the existence of Ni. 48 In addition, the bonding energy of 285 eV is generally assigned to the characteristic peak of C 1s (Fig. 2d) .
Results and discussion

Characterization of Mg-Ni/HCS and Mg-HCS
To explore the microstructure of the products, SEM and TEM characterizations of HCS and Ni/HCS are further applied. The SEM images shown in Fig. 3a, c and d show micrographs that clearly reveal the spherical characteristics of HCS aer the second carbonization process, and the majority of the particles are AE1.7 mm in diameter; some particles are fused together to form a pearl necklace, as shown in Fig. 3b . In addition, from the corresponding selected area electron diffraction (SAED) pattern (inset of Fig. 3b) , we can see a dispersion center, suggesting the amorphous nature of HCS and conrming the XRD result (Fig. 1a) . The surface of HCS is not smooth, and many pores (ca. 40 nm) can be observed on the surface of the spherules (Fig. 3c) . The surface roughness increases the specic surface area of HCS, which facilitates the adsorption of Mg and Ni. This is further utilized to fabricate MgH 2 particles or Ni/HCS. SEM observations show wire-like clusters of NiO with an average length of 500 nm and width of 50 nm, and these are uniformly anchored on the surface of HCS (Fig. 3e and f) . In the solvent, HCS are assumed to act as nucleation sites, and the particles coalesce and grow, leading to the formation of NiO in the next step. However, aer the reduction procedure in an H 2 atmosphere, the wire-like clusters of NiO are converted to hexagonal Ni particles with size of around 400-500 nm ( Fig. 2g and h) , and HCS burst into small particles covered on the surface of Ni, reducing the agglomeration of Ni particles during the dehydrogenation process.
SEM examinations were used to characterize the structure and distribution of the products. Interestingly, the element mapping images of the Mg-Ni/HCS composite, as shown in Fig. 4b , demonstrated that the distribution of C, Mg, and Ni was uniform without any detectable aggregation, proving that the distribution of C, Mg, and Ni composite could exhibit the entire distribution in the Mg-Ni/HCS matrix. From Fig. 4a , it can also be seen that Mg-HCS exhibited extremely ne particles on the surface of HCS, and the homogeneous anchoring was due to the favorable absorption of MgH 2 particles on HCS. Furthermore, no aggregation was observed due to high surface area of HCS, which also acted as the structural support. Furthermore, the elemental distributions of the hydrogenated products conrmed the existence of Mg, C, and O. The results suggested that the formed MgH 2 was well distributed and anchored on HCS owing to the favorable adsorption of Mg on HCS, which was easily realized by treatment with hydrogen. Therefore, the above analysis strongly suggested that MgH 2 has been successfully incorporated onto the surface of HCS. One of the biggest challenges is the fabrication of Mg-based hydride composites that are highly reactive and well dispersed. Here, we use Mg as the original material and maintain the growth of Mg-based hydrides by hydriding combustion synthesis. Fig. 5 shows a schematic illustration of the synthesis processes for Mg-Ni/HCS and Mg-HCS. For the Mg-Ni/HCS sample, we select sucrose as the precursor and obtain HCS via the carbonation process. The Ni/HCS additive is synthesized through a chemical method. During the hydriding combustion synthesis process, Mg 2 NiH 4 particles are formed in situ and homogenously distributed onto the Mg/MgH 2 matrix with the existence of HCS. In the case of Mg-HCS, Mg powder and HCS are used as the starting materials to fabricate Mg-HCS. HCS with defective domains and mesoporous characteristics favors the nucleation and growth of MgH 2 particles. Aer the hydriding combustion synthesis process, MgH 2 particles are believed to be generated on the surface of HCS, and it can easily capture hydrogen molecules and dissociate H 2 to atomic H in the hydrogenation process aer ball milling.
Hydrogen storage properties of Mg-Ni/HCS and Mg-HCS
To investigate the hydrogen storage properties of the obtained Mg-Ni/HCS and Mg-HCS composites, the cyclic stability and dehydrogenation kinetic measurements are performed using PCT. First, a total of 50 cycles are performed, and the results are shown in Fig. 6a . This shows that there is no clear reduction in the capacity aer 50 cycles of both Mg-Ni/HCS and Mg-HCS composites, indicating that the composites have excellent cyclic stabilities. The Mg-Ni/HCS and Mg-HCS systems are able to absorb 6.2 wt% of hydrogen within 5 min during the de/ rehydrogenation process, exhibiting favourable hydrogenabsorbing dynamic performance. Meanwhile, for the MgH 2 -HCS composite, the cycling hydrogen desorption capacity is clearly lower than the absorption capacity, mainly because of the barrier induced by the breakage of the Mg-H bonds during the dehydrogenation process; therefore, for the cyclic stability measurements, between dehydrogenation and hydrogenation of each cycle, a 30 min evacuation process is conducted to ensure complete dehydrogenation reaction of the sample. Fig. 6b shows the XRD patterns of Mg-HCS and Mg-Ni/HCS composites before and aer dehydrogenation aer cycling. As shown in Fig. 6b (I) and Fig. 6b (III) , the two samples mainly contain Mg phase aer dehydrogenation, and the Mg 2 Ni phase is detected for the Mg-Ni/HCS composite, which reveals that the addition of Ni changes the path of dehydrogenation. The XRD patterns of the cycled Mg-HCS and Mg-Ni/HCS composites aer hydrogen absorption are shown in Fig. 6b (II) and Fig. 6b (IV). The diffraction intensity of the MgH 2 phase is detected, and the Mg 2 NiH 4 phase is detected for the Mg-Ni/HCS composite. More importantly, the diffraction peaks of Mg can be detected in Fig. 6b (IV) , which reveals incomplete hydrogenation of Mg. This also proves the reduction of hydrogen storage capacity during hydrogen desorption/absorption cycling. In contrast, no Mg diffraction peaks are observed for the Mg-HCS composite aer hydrogenation, implying complete hydrogenation of Mg. Mao et al. 49 investigated the hydrogen sorption properties of MgH 2 doped with NiCl 2 and CoCl 2 ; they found that the MgH 2 /NiCl 2 sample showed better sorption properties than the CoCl 2 -doped sample. As reported by Zhang et al., 50 it is experimentally conrmed that the MgH 2 -Ni 3 C composites exhibit the best hydrogen storage properties as compared to MgH 2 -Ni 3 N, MgH 2 -NiO, and MgH 2 -Ni 2 P. They suspected that Ni binding with an element having low electronegativity is favorable for the dehydrogenation of Mg-based composites, which is consistent with our nding. Moreover, Sulaiman et al. 51 showed that 5 wt% of K 2 NiF 6 had a favourable catalytic effect in the context of MgH 2 hydrogen storage properties, which can be due to the in situ-formed KF, KH, and Mg 2 Ni; these active species can provide a synergetic catalytic effect in enhancing the hydrogen sorption properties of MgH 2 . Furthermore, Yahya et al. 52 studied the synergistic catalytic effect of SrTiO 3 and Ni on the improvement of the hydrogen storage properties of the MgH 2 system; the composite can absorb 2.9 wt% of hydrogen in 10 min under pressure of 2.7 MPa of hydrogen.
It is noteworthy that with regard to the as-prepared composites, there are no indications of the formation of any metastable phases under the current experimental conditions based on XRD analysis (Fig. 6b) . Furthermore, the XRD results show that no reaction occurs between Mg-based hydrides and HCS. Therefore, it is reasonable to assume that HCS with a mesoporous and defective structure may function as a dispersant, serving as the center for nucleation and growth of the magnesium hydride phase. However, a broad diffraction peak at around 42.9 can be assigned to MgO, which is consistent with the SAED results (Fig. 5) . House et al. found that during the ball milling process, an ultrane-grained MgO layer can be formed. 53 Alternatively, the appearance of MgO may be ascribed to exposure to air during the measurement. It is also found that MgH 2 is covered with oxides during desorption, demonstrating that MgO can recombine atomic hydrogen. Therefore, the existence of MgO can provide small surface vacancies, which are countered by a very high turnover frequency due to small activation energy for dissociation of hydrogen.
54
To investigate the hydrogen storage properties of Mg-Ni/ HCS and Mg-HCS composites, dehydrogenation and hydrogenation measurements under different conditions are obtained using PCT. TPD experiments can provide a clear comparison of the desorption kinetics; thus, we rst obtain TPD measurements to study the kinetics and overall hydrogen storage behavior. Fig. 7a shows the TPD proles of the as-prepared Mg- Ni/HCS and Mg-HCS and milled as-received commercial MgH 2 . The dehydrogenation of Mg-Ni/HCS composite starts at about 230 C, which is much lower than those of Mg-HCS (320 C) and commercial MgH 2 (425 C). In particular, both Mg-Ni/HCS and Mg-HCS composites show a drastically faster dehydrogenation rate than primary MgH 2 . As illustrated in Fig. 7a and b, a total mass loss of 5.9 wt% is observed for the primary MgH 2 composite with a desorption peak at 484 C. However, the desorption peaks of Mg-Ni/HCS and Mg-HCS shi downward to 290 C and 348 C, respectively; both of these materials exhibit H 2 capacity of 6.2 wt%, which is fairly close to the theoretical value of the composite (7.6 wt% Â 5/6 ¼ 6.33 wt%). This suggests that the Mg phase can completely transform into the MgH 2 or Mg 2 NiH 4 phase during the hydrogenation process, which agrees with the XRD results (Fig. 6b) . The isothermal hydrogenation curves of the Mg-Ni/HCS composite (Fig. 7c) reveal that the hydrogenation process of the composite can be implemented within 30 min at 250 C, and there can be 3.5 wt% hydrogen uptake even at 75 C within 200 min. In the case of dehydrogenation plots (Fig. 7d) , the temperatures increase from 275 to 350 C; the dehydrogenation rates and capacities increase remarkably, and the excellent absorption rate remains almost unchanged. For instance, the composite can release 3.8 wt% H 2 at 300 C within 30 min. The hydrogen desorption behaviors of the Mg-HCS composite are also given (inset in Fig. 7 (c) and (d)). For hydrogen absorption, the Mg-HCS composite can reach the maximum value in less than 5 min; for example, it can uptake 2.5 wt% H 2 at 150 C. Although this value is enhanced when compared with that of pure MgH 2 , it is much lower than that for the Mg-Ni/HCS composite. Therefore, the absorption properties are clearly improved by introducing Ni/ HCS, suggesting the prominent effect on the hydrogenation reaction of Mg. By further increasing the applied temperature, the desorbed hydrogen capacity signicantly increases (Fig. 7d) , indicating that the performance of dehydrogenation is considerably inuenced by the temperatures of both Mg-Ni/HCS and Mg-HCS composites.
To further understand the hydrogenation kinetics mechanism, we also analyzed the DTA proles at different ramping rates and estimated the activation energies (E a ) of the dehydrogenation processes of Mg-Ni/HCS and Mg-HCS based on the Kissinger method according to eqn (1) . Here, a is the heating rate, T m is the peak temperature, and R is the gas constant. In addition, T m was obtained at a values of 5, 10, 15, and 20 C min À1 , as shown in Fig. 8a and c. Fig. 8b and d lower than that for pure MgH 2 , respectively, which provided further evidence for the correlation between the presence of HCS and hydrogen desorption kinetics as well as the synergistic catalysis between HCS and Ni.
To further study the hydrogen absorption and desorption thermodynamics, the pressure-composition (P-C) isotherms of Mg-Ni/HCS and Mg-HCS are measured at 350, 330, and 310 C, as shown in Fig. 9a and c, respectively. The Van't Hoff plots derived from the P-C isotherms are shown in Fig. 9b and d . For the Mg-Ni/HCS composite, two plateaus are clearly visible for 
Mechanism
The above performances of Mg-Ni/HCS and Mg-HCS composites prepared by hydriding combustion synthesis and ball milling reveal considerably enhanced hydrogen storage properties of Mg hydrides. Nevertheless, the PCT measurement results exhibited marginal differences in the thermodynamic properties. We highlight the excellent kinetic improvements in the as-prepared Mg-Ni/HCS composite in the dispersity of HCS and the in situ-formed Mg 2 NiH 4 . The particular distribution of the Mg 2 NiH 4 phase is assumed to play a critical role in triggering de/absorption of MgH 2 . Zhang et al. 57 found that in Nicontaining Mg-based systems, Ni always transforms into Mg 2 NiH 4 during the hydriding combustion synthesis process, and it changes to Mg 2 Ni aer desorption; the Mg 2 Ni phase can act as a porthole to adsorb H 2 and dissociate H 2 into H atoms. This yields more signicant reduction in the hydrogenation barrier as compared to that for pure Mg and triggers its hydrogen performances. Please note that HCS burst and wrap onto Ni; therefore, the existence of HCS causes a sufficient dispersion effect in the hybrid. The active sites of carbon materials are also crucial for facilitating the nucleation of Mg 2 Ni/Mg 2 NiH 4 particles.
Conclusions
We have prepared an Mg-Ni/HCS composite by hydriding combustion synthesis and mechanical milling process involving Mg powder and carbon-wrapped Ni additive as the raw materials. Microstructural characterization reveals that the in situ-formed Mg 2 NiH 4 particles are evenly distributed into the matrix of the composite and play a key role in signicant enhancement of hydrogen desorption kinetics. HCS assume an important role as a support material in providing nucleation sites for MgH 2 and Mg 2 NiH 4 and act as an inhibitor for the agglomeration of hydrides to enhance the dehydrogenation performances. The Mg-Ni/HCS composite absorbs 3.5 wt% of hydrogen in 200 min at 75 C and desorbs 2.7 wt% of hydrogen in 120 min at 275
C. The E a value of the composite for the dehydrogenation of MgH 2 is 65.9 kJ mol À1 , indicating sharp reduction in the barrier to dehydrogenation when compared with that of commercial MgH 2 . Our results demonstrate that the carbon-wrapped Ni additive can greatly improve the hydrogen performances of the Mg-based hydride system and provide considerable potential for practical applications.
Conflicts of interest
There are no conicts to declare.

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