Title of Invention: In lavatory dispensing devices Abstract: The present invention relates to improved toilet dispensing devices for use in conjunction with a sanitary appliance, particularly a toilet. The toilet dispensing devices devices are adapted to be used in the cistern or tank of a toilet or other lavatory device. Detailed Description: Part general_description_paragraphs: This is an application filed under 35 USC 371 of PCT/EP2010/057264. The present invention relates to improved lavatory dispensing devices. More particularly the present invention relates to improved lavatory dispensing devices which are useful in conjunction with a toilet cistern, as well as a method for delivering a treatment composition to a toilet bowl in toilets provided with a cistern. The said treatment composition contains one or more chemical constituents e.g., coloring agents, cleaning agents, disinfecting agents, anti-lime scale agents which are provided with the dispensing devices. The treatment composition is formed by water contacting the chemical constituents of the device coming into contact with the one or more chemical constituents, which are released into the bowl of the toilet. Since the advent of sanitary appliances and in particular modern flush toilets, there has been a continuing need in the art to provide effective ways to maintain these appliances in a satisfactory condition between uses. The art is replete with devices which are intended to be used as “in the bowl” (or ITB) or “in the cistern” (or ITC) in order to provide a coloring and/or cleaning and/or fragrancing and/or sanitizing effect to such sanitary devices, particularly toilet bowls. One common approach known to the art is to provide a device which is at least immersed within the cistern or tank of a toilet, which may be either placed wholly within the interior of the toilet such as by placement at the bottom of a toilet tank so that the entire device is wholly immersed in water when the tank is full, or is at least partially immersed within the water present in a toilet tank, such as wherein such a device is suspended from a part of the toilet tank, such as a lip or rim of the tank. Such are generally referred to as ITC devices. A shortcoming of such ITC devices known to the art resides in the fact that they are frequently totally immersed in the water present in the cistern. Two technical shortcomings frequently result from such immersed ITCs. First, the compositions of an ITC are difficult to formulate as many constituents which are desirably present in such lavatory blocks such as many surfactants, particularly higher foaming surfactants including anionic surfactants, are also water soluble or water dispersible. Thus when a solid lavatory block containing surfactants, particularly higher foaming surfactants are immersed in water for a period of time, often the presence of such surfactants undesirably softens the immersed block and reduces the performance characteristics of the block over time, and may even lead to diminish lifespan due to premature dissolution of the solid lavatory block. While this problem may be addressed by the use of different surfactants which are more hydrophobic, such more hydrophobic surfactants are also recognized in the art as having reduced cleaning and/or foaming. Further, the compositions of an ITC block may include constituents such as an active source of oxygen, such as an oxidant compound or composition such as bleach, the presence of the oxidant in the standing water of the toilet cistern frequently chemically attacks any metal parts which are also present in the standing water of the cistern and may induce corrosion, and premature failure of any mechanism which comprises such metal parts. Prominently, flushing mechanisms for releasing or dispensing water to be flushed from the cistern to the toilet, and/or cistern refill devices for refilling the toilet cistern following a flush cycle come into consideration. While this problem may be addressed by the inclusion of corrosion inhibiting compounds or compositions in lavatory block composition adapted to be used in an ITC, or as an ITC, such increases the complexity of such a lavatory block formulation as well as its cost. A further technical problem in the art resides in the fact that during the flush cycle of a toilet, the quantity of water present in the cistern is released into the toilet bowl via one or more fluid passages which provide a fluid conduit between, which while effective in providing a treatment composition such as it intended to provide a general cleaning and/or sanitizing/disinfecting benefit to the toilet bowl consequence from the contact of the water provided by the flush cycle, this lime of water containing such a treatment composition or forming a treatment composition is essentially evacuated at the conclusion of the flush cycle and passes to the drain lines, with little if any essentially remaining within the interior of the toilet bowl. Add her to the conclusion of the flush cycle, and during the refilling of the cistern, typical devices provide water to fill the bottom of the toilet bowl, also referred to as the “sump” was a quantity of fresh water which supplied via a refill device. Such a refill device is well known in the art comment typically resides within the interior of the cistern. The refill device typically includes a float mechanism which rises or falls with the level of water within the cistern, which float mechanism is usually affixed via an intermediate linkage to a cutoff for a fill valve. When the cistern is emptied of its contents, the float drops, actuating the refill device such that a major proportion of water from a supply line is directed to the interior of the cistern, while at a secondary minor proportion of the water being supplied it is passed through an overflow conduit, said overflow tube having one and inserted into the standpipe of a flush valve, also known as the overflow tube. This secondary minor proportion of water is supplied to the interior of the standpipe of the flush valve, and passes through the base of the flush valve and into the toilet bowl. As the refill device operates, water is supplied to the interior of the cistern as well as to the overflow conduit and into the standpipe of the flush valve, during which process, referred to as a “refill cycle”, the rising level of water within the cistern closes the float mechanism to rise due to its buoyancy with respect to this water, and ultimately when an appropriate level of water is supplied to the cistern, the cutoff for the fill valve operates and terminates the flow of water to both the interior of the cistern, as well as through the overflow tube. Typically, the appropriate level of water is a sufficient volume of water wherein the top level or top surface of the water within the cistern is below the open end at the top of the overflow tube. During this process, it is to be appreciated in that a major proportion of the water being supplied via the overflow conduit and downwardly through the overflow tube is retained within the sump of the toilet bowl. U.S. Pat. No. 6,240,572 provides a device useful in the sanitization of a toilet. As it is seen from that document, the main body of said device is substantially cylindrical and comprises a plurality of stacked sanitizing tablets therein. Further, the inlet to the main body is at the base thereof, and as can be seen from the figure this impedes the flow of water being provided from a conduit which must then pass about the peripheral margins of the stacked sanitizing tablets and operate against the force of gravity. Thus the interior of the device is pressurized during the flow of water through the main body of the device else it would not flow upwardly. As a visible from the depiction, the stacked sanitizing tablets have essentially the same cross-sectional diameter as the interior cross-sectional diameter of the substantially cylindrical main body of said device, and it is foreseen that such will deleteriously affect the fluid flow of water being supplied to the interior of said device. It is expected that any erosion of said stack of sanitizing tablets will occur beginning with the base tablet and as the stack of sanitizing tablets are sequentially eroded, the next vertically positioned tablet will fall downwards to the bottom of the device and continue to block the inlet to the main body. Such impedes the fluid flow passing through this prior art device in an unsatisfactory manner, and requires pressurization. Thus, there exists a real and urgent need in the art for improved lavatory dispensing devices which are particularly well adapted to be positioned in a toilet cistern, viz., an ITC device, as well as a method of making such an ITC device as well as methods for the treatment of a toilet bowl via the use of such an improved ITC device. The present invention, in its various aspects, provides a lavatory dispensing device useful for the delivery of at least one treatment composition, preferably a cleaning composition and/or a sanitizing composition to a sanitary appliance, e.g. a toilet bowl. The device is used as an ITC type device. According to a first aspect of the invention there is provided an improved lavatory dispensing device comprising a treatment composition adapted to be mounted on the overflow tube of a toilet or other lavatory appliance. In a second aspect of the invention there is provided a process for treating a sanitary appliance, especially a toilet, with the improved lavatory dispensing device described herein. In a third aspect there is provided a method for the manufacture of the improved lavatory dispensing devices described herein. These and other aspects of the invention will be more evident from a reading of the following specification. Accordingly, according to certain particularly preferred embodiments, the siphon means present within, or as part of the device according to the invention operates to essentially drain all of the liquid (<90% volume, preferably 95% volume, but preferably yet more) or lavatory treatment composition present within the device from within the interior of the hollow cavity of the device, and deliver it to the exterior of the device. Such can be simply attained by ensuring that the outlet of the siphon means is at a horizontal level or point lower than the inlet of the siphon means. Preferably, such delivery of the liquid is directed into the interior of the overflow tube, but it is also contemplated that the liquid can be delivered elsewhere, such as to the interior of the tank or cistern. Such may be advantageous particularly where the lavatory treatment composition might include a visible indicator such as a dyestuff, or may include a suitable treatment agent which can be delivered into the cistern between flushes. For example, it may be advantageous to provide a small quantity of the laboratory treatment composition such as an antibacterial agent, e.g., a bleach, oxidizing agent, or quaternary ammonium compound in order to control the undesired growth of microorganisms within the tank, which may also be advantageous in reducing malodorous, etc. Thus, a device according to the invention can be configured whereby a chemical treatment composition is contained within the interior of the device, during the flush cycle a major volume of the lavatory treatment composition formed passes through the outlet of the device and downwardly through the overflow tube and into the sump of the toilet bowl, while a minor volume of the lavatory treatment composition he's delivered into the tank or cistern, particularly to the quantity of water contained therein. Alternately, according to further preferred embodiments, the siphon means present within, or as part of the device according to the invention operates to drain some, but not all of the liquid, particularly the lavatory treatment composition, from within the interior of the hollow cavity of the device and deliver it to the exterior of the device, while at the same time allowing for the retention of a quantity of liquid within the interior of the device between flush cycles. This can be very simply achieved by ensuring that the outlet of the siphon means is at a horizontal level or point lower than the inlet of the siphon means, or the converse. Such a configuration ensures that some of the liquid present within the interior of the device is not drained or transferred out by the siphon means. The interior cavity of the device, interchangeably referred to as the hollow cavity of the lavatory dispensing device should have an adequate volume which is sufficient to contain within its interior both a chemical treatment composition as well as a sufficient quantity of a liquid, e.g., water, which may be retained within the hollow cavity and in intimate contact with the chemical treatment composition. Such contact permits for the formation of a lavatory treatment composition in situ within the device, which is formed by the dilution, dissolution, diffusion, elution and/or solubilization of at least one or more chemical compounds from the chemical treatment composition which is at least partially or wholly immersed within liquid, or water contained within the device between flush cycles, namely the liquid present within the hollow cavity of the device below the inlet of the siphon means. The retention of water in intimate contact with the chemical treatment composition between flush cycles also allows for the formation of the lavatory treatment composition. Upon the actuation of the refill device of the lavatory appliance, when a quantity of water is supplied to the interior of the lavatory dispensing device via its inlet, water flows into the hollow cavity and forces the lavatory treatment composition outwardly through the outlet of the lavatory treatment device. During the refilling of the tank or cistern, the refill device acts to continuously provide a quantity of water which passes via the inlet of the device and into the hollow cavity where it comes into contact with at least one chemical treatment composition and forms an effective lavatory treatment composition which flows outwardly through the outlet ending to the overflow tube and into the sump of the toilet bowl during the operation of the refill device. In certain embodiments of the invention, namely wherein not all of the lavatory treatment is removed form the device via the outlet or the siphon means, the at least part of the water provided through the inlet retained within the interior of the hollow cavity and in contact with a chemical treatment composition, wherein it forms a further quantity of a lavatory treatment composition which will be released upon the next flush cycle of the toilet. This quantity or volume of the lavatory treatment composition is within the hollow cavity of the device at a point below the inlet of the siphon means. Concurrently any quantity or volume of a treatment composition within the hollow cavity of the device, which is present within the device but present within a region of the hollow cavity but vertically above the inlet of the siphon means is drained, or transferred out from the interior of the device to the exterior of the device via the siphon means and advantageously the outlet of the siphon means is directed to supply said lavatory treatment composition into the interior of the overflow tube from whence it passes to the sump of the toilet bowl. This foregoing process repeats itself continuously upon each flush cycle until the chemical treatment composition or compositions present within the device is or are fully exhausted or consumed. According to this embodiment of the invention, it is contemplated that the device can contain an upper part and the lower part of the hollow cavity separated by a divider means or element which can for example be a mesh, screen, perforated plate, membrane or any other element or material which permits for the flow of liquids such as water but especially the flow of lavatory treatment composition between the upper and lower parts of the device. Concurrently, in this embodiment the inlet of the siphon means is advantageously positioned at a level vertically above, or approximately coincident with the base of the upper part such that, between flush cycles, any liquid, especially lavatory treatment composition contained within the hollow cavity of the device is drained from the upper part of the device, but a further volume of liquid which may be present in the lower part of the hollow cavity is retained within the hollow cavity of the device between flush cycles. In this manner, two (or more) chemical treatment compositions can be provided within the hollow cavity of the device, one being positioned vertically above the other within the upper part, the other being retained within the lower part of the hollow cavity. In a further embodiment of the invention, there is provided a device similar to that as described immediately above, wherein however the hollow cavity of the device is divided into at least an upper part which contains at least one chemical treatment composition, and a lower part which is empty of any chemical treatment composition and which lower part functions as a collection basin of the device. According to this embodiment, it is preferred that the inlet of the siphon means is present within, but preferably coincident with the lowest point of this collection basin, but may be above, and the upper part and lower parts are separated by a porous element or member, such as a screen, perforated plate, membrane, and the like. In such an embodiment, a quantity of the chemical treatment composition is retained in the upper part of the hollow cavity, during the flush cycle is washed with liquid, preferably water, and due to contact therewith forms a lavatory treatment composition but upon the cessation of the supply of water into the device, the volume of the liquid contained within both the upper part and lower parts of the device, especially a lavatory treatment composition, is transferred or drained therefrom by virtue of the siphon means. The siphon means can have an outlet which is within the interior of the overflow tube, or the placement of the outlet of the siphon means can direct the supply of lavatory treatment composition to any other point as may be desired, e.g. into the tank or cistern. Such an embodiment can be used with one or more chemical treatment compositions present within the hollow cavity. Advantageously according to the instant embodiment, any chemical treatment composition present within the upper part of hollow cavity of the device are allowed to at least partially dry between flush cycles with the use of a device according to this embodiment. In a yet further embodiment of the invention, there is provided a device which comprises two abutting or adjoining chambers contained within, or forming the hollow cavity of device according to the invention wherein a vertical divider wall or other element is present which separates a least a portion of the hollow cavity into a first containment chamber, and at least a second containment chamber. At least a first chemical treatment composition can be contained within the first containment chamber, at least a second chemical treatment composition can be contained within the second containment chamber. Such a device according to the invention also necessarily includes at least one, but may include more than one siphon means which are fluid communications with at least the first containment chamber or the at least second containment chamber or both, which at least one siphon means are also in fluid communication with one or more points exterior of the device, or alternately are in fluid communication with an outlet of the device. The vertical divider wall or other element present may be arranged such that a liquid, such as water provided via the inlet of the device is divided into two separate streams, a first passing into the first containment chamber, and the second passing into the second containment chamber, forms, by virtue of contact with the respective chemical treatment compositions contained within separate chambers, lavatory treatment compositions which are kept separate from one another until there delivered outwardly from the device, such as into the interior of an overflow tube or to some other point in the laboratory appliance, e.g. the interior of the tank or cistern. The inclusion of a siphon means in fluid communication with one, or with both of these containment chambers allows for the prolonged or delayed delivery of a lavatory treatment composition in according to the manner described above. Alternately, the vertical divider wall or other element present may be arranged such that a liquid, such as water provided via an inlet of the device passes into a first of the containment chambers where contacts a first chemical treatment composition, and thereby forms a first lavatory treatment composition which then sequentially flows into the second of the containment chambers wherein it contacts the second chemical treatment composition and thereby forms a further lavatory treatment composition which may then be directed via an outlet and thus exit the device. The inclusion of at least one siphon means in fluid communication with at least one of the containment chambers permits for either the partial, or complete drainage or transfer of any liquid contained within one or both of the containment chambers to the exterior of the device subsequent to the cessation of the supply of water into the interior of the device, such as via the refill means. In accordance with such an embodiment, the first laboratory treatment composition contacts the second chemical composition to form the final laboratory treatment composition which may be advantageous where a chemical reaction is expected to occur due to this sequential contact. Alternately or in addition thereto, in accordance with such an embodiment, a chemical treatment composition which would otherwise be considered unsuitable for use as being too soft, too soluble in the liquid, especially water, or which would be considered subject to premature erosion or solubilization could be used in such a device were a siphon means are provided in fluid communication with the containment chamber containing said chemical treatment composition. Including such a siphon means would provide for the drainage, preferably essentially complete drainage of any liquid treatment composition contained within the containment chamber between flush cycles and allow said chemical treatment composition to a least partially dry and thereby reduce its undesirably rapid dissolution and prolong its useful service life. The inventors have found that desirably, at least a minimum volumetric ratio or volumetric proportion between the chemical treatment composition present within the interior of the device, particularly within the hollow cavity, and the quantity of water which is retained within the hollow cavity and in contact with the chemical treatment composition preferably be maintained in order to ensure the delivery of an effective lavatory treatment composition to the sump of the toilet (or other lavatory appliance) during the flush cycle. In accordance with preferred embodiments of the invention, the water passing through the inlet and into the interior of the hollow cavity enters the hollow cavity at a point above the quantity of a chemical treatment composition present and is not required to pass this mass or body of the chemical treatment composition before exiting via the outlet of the device. Rather, the flow of water passes into the filled volume of the cavity within the interior of the device. This filled volume is as the maximum quantity of the liquid, namely water, which may be contained within the interior of the lavatory treatment device when it is appropriately mounted upon an overflow tube, and any flow outward from any siphon means is blocked. Typically, this filled volume corresponds to the volume of the hollow cavity which exists between the base of the device and extends upward towards the top of the device to the level of the base of the outlet of the lavatory treatment device. This filled volume can be readily determined by mounting the lavatory treatment device onto an overflow tube in its normal operating position, and filling the hollow cavity up to the point with liquid in an amount sufficient to fill the bottom part of the hollow cavity but not in amount wherein said liquid flows out through the outlet of the device. As will be appreciated, this bottom part of the hollow cavity defines the maximum volume of water which can be contained within the lavatory treatment device, while the upper part of the cavity defines the headspace of the hollow cavity which is open to the ambient atmosphere within the interior of the cistern before, during, and after a flush cycle of the toilet. In preferred embodiments, the respective volumetric ratio between the chemical treatment composition, and the water which may be retained within the interior of a hollow cavity wherein both are simultaneously present is at least 1:2 and preferably is at least 1:1. The inventors of found that an insufficient respective volumetric ratio between the chemical treatment composition and the static water may result in the formation of an insufficiently effective lavatory treatment composition which is released and later retained within the sump of the toilet bowl. Such is particularly true wherein a sanitizing benefit is intended to be provided to the toilet bowl. It is to be appreciated that during its operation, the interior volume of the device, that is to say the total interior volume of the inlet, hollow cavity, and outlet are not sufficiently sealed so to be pressurized by the flow of water being provided by the overflow conduit. Rather, both the force of gravity, as well as the dynamic flow force of the liquid, e.g., water, are the motive forces in the directional flow of the liquid being supplied to the device is essentially in a downward direction. Thus, the device does not require pressure-tight seals or pressure-tight connections in order to ensure its reliable operation, such as might be required if the flow of water from the overflow conduit were to be used to provide a pressurized, upward flow through the device. Furthermore, as the device is essentially unpressurized and as the connection between the outlet of the overflow conduit and the inlet to the lavatory treatment device taught herein are not via a pressure tight seal or pressure tight connection or fitting, should any unexpected and undesirable blockage or failure of the lavatory treatment device occur, such as by a blockage which would interrupt flow between the inlet and the outlet of the lavatory treatment device, then water exiting the overflow conduit would merely flow and overflow the inlet to the lavatory treatment device and into the cistern. Such provides a “fail-save” mode of operation. Such is particularly advantageous as, according to preferred embodiments, the open end of the inlet of the lavatory treatment devices taught herein are above the maximum water level of water contained within the cistern and, preferably are generally at least 1 centimeter, preferably at least 2 cm, still more preferably at least about 3 cm above the open end of the overflow tube when the device is mounted thereon. Optionally but preferably the device according to the invention may additionally include an air treatment element. For example, such may be a reservoir comprising a quantity of an air treatment composition and/or fragrance composition which may form part of or be used with the lavatory treatment device. Exemplary air treatment constituents include a material which is useful in providing treatment of ambient air, such as a sanitizing agents. e.g., one or more glycols or alcohols, or materials which are intended to counteract, neutralize, or mask odors in the absence of, or in conjunction with, the fragrance composition of the present invention. Alternatively, the air treatment constituent may be one or more materials which provide and effective insecticide repelling or insecticidal benefit. Exemplary fragrance compositions include naturally derived or synthetically produced chemical compounds and chemical species, such as essential oils, derivatives thereof, and synthetically produced chemical compounds which may be used singly but are more frequently used as blends or mixtures. The air treatment element may include a reservoir can take any shape or suitable form, and can be included within the interior of the device, or on the exterior of the device, or may be even be separate from the device but provided as a separate article or element which is separate or separable from the device but intended to be placed in the near proximity of the device, e.g. attached to another part of the toilet or lavatory appliance or nearby to the toilet or lavatory appliance. An air treatment element may include carrier or substrate for the air treatment composition or fragrance composition which may be a porous material such as a pad or tablet which is impregnated with, or upon which is absorbed a volatile composition useful in providing an air treatment benefit, a gel or a solid composition which also contains a volatile air treatment composition which may emanate from the air treatment element and/or reservoir. Alternately the air treatment element and/or reservoir may contain a quantity of a particulate material in the form of a single body, e.g. plate, or as a plurality of spheres, or beads which function as a reservoir for an air treatment composition and/or fragrance composition, and from whence they may be delivered to the ambient environment. Non-limiting examples of such materials include those currently marketed under the tradename Auracell® (ex. Rotuba Extruders) which are based on fragranced cellulosic polymers, as well as PolyIFF® (ex. International Flavors and Fragrances Inc.), as well as Tenite® (ex. Eastman Chemical Co.). It is contemplated that part of the device may be formed of one or more of the foregoing materials, particularly one or more which may be injection molded to form part of the housing of the device. The air treatment element may be used to provide an air treatment composition and/or a fragrance composition to the ambient environment of the device, e.g., within the interior of the tank or cistern, or to the near proximity of the lavatory appliance with which the device of the invention is mounted or used. The lavatory dispensing device whether formed from a single unitary piece or assembled from a plurality of discrete pieces or elements may be formed from any of a variety of materials which can be used for the purpose described herein. Exemplary and preferred materials include metals such as coated papers which are at least for a time essentially impervious to water, metal sheets or metal foils, non-metallic materials any of a number of thermosettable or thermoformable synthetic polymers such as are widely used in casting or injection molding. Exemplary synthetic polymers such as polyamides, polyolefins (e.g., polypropylene, polyethylene) as well as polyalkyleneterephalates (i.e., polyethylene terephthalate, polybutylene terephthalate), polystyrenes, polysulfones, polycarbonates as well as copolymers formed from monomers of one or more of the foregoing being several nonlimiting examples of useful synthetic polymers. Preferably the material of construction is at least somewhat flexible. As to the material of construction of the lavatory dispensing device, the only criteria being that the selected materials used to fabricate device are not deleteriously affected by the chemical constituents of the chemical composition contained within device or the lavatory treatment compositions forums using the device, and that they are impervious to water. Is appreciated that is too more different materials of construction can be used to form the to retrieve and devices according to the invention. The dispensing devices according to the invention necessarily also comprise a chemical treatment composition comprising at least one or more chemical constituents such that when the chemical treatment composition is rinsed or washed with water, one or more chemical compounds or chemical constituents are eluted from a mass of the chemical treatment composition and dispersed or dissolved into said water and thereby forms a treatment composition which is useful in treating a sanitary appliance, particularly a toilet bowl. The treatment composition advantageously provides a cleaning and/or sanitizing benefit to the treated sanitary appliance. The chemical treatment composition of the invention may include any known art cleaning agents or cleaning constituents known to those of ordinary skill in the relevant art, and without limitation include one or more detersive surfactants selected from anionic, cationic, nonionic as well as amphoteric or zwitterionic surfactants. Certain detersive surfactants may also provide a dual role in providing detergency as well as a disinfecting effect, viz, certain cationic surfactants, which are described hereinafter as a disinfecting agent. These one or more cleaning agents or cleaning constituents may be used with or without other constituents being present in the chemical treatment compositions of the invention. In certain embodiments, the chemical treatment composition of the invention desirably comprises a surfactant constituent which may be one or more detersive surfactants, especially one or more surfactants selected from: anionic surfactants, nonionic surfactants, cationic surfactants, zwitterionic surfactants and amphoteric surfactants. Exemplary useful anionic surfactants are alpha olefin sulfonates, as well as salts thereof, e.g., alkali metal salts. Preferred are C8 through C22 alpha olefin sulfonates, particularly C12 through C18, and especially C14, and C16 alpha olefin sulfonates as well as blends of two or more thereof. Exemplary useful nonionic surfactants include polyalkylene oxide condensates of alkyl phenols, condensation products of aliphatic alcohols with an alkylene oxide, especially an ethylene oxide, especially primary and secondary linear and branched alcohol ethoxylates, nonionic surfactants containing alkylene oxide, especially in which the major portion of the molecule is made up of block polymeric C2-C4 alkylene oxides, alkoxylated alkanolamides, preferably C8-C24 alkyl di(C2-C3 alkanol amides), as well as amine oxides. Exemplary useful cationic surfactants include those which provide a germicidal effect to the concentrate compositions, and especially preferred are quaternary ammonium compounds and salts thereof, which may be characterized by the general where at least one of R1, R2, R3 and R4 is a alkyl, aryl or alkylaryl substituent of from 6 to 26 carbon atoms, and the entire cation portion of the molecule has a molecular weight of at least 165. The alkyl substituents may be long-chain alkyl, long-chain alkoxyaryl, long-chain alkylaryl, halogen-substituted long-chain alkylaryl, long-chain alkylphenoxyalkyl, arylalkyl, etc. The remaining substituents on the nitrogen atoms other than the abovementioned alkyl substituents are hydrocarbons usually containing no more than 12 carbon atoms. The substituents R1, R2, R3 and R4 may be straight-chained or may be branched, but are preferably straight-chained, and may include one or more amide, ether or ester linkages. The counterion X may be any salt-forming anion which permits water solubility of the quaternary ammonium complex. Exemplary amphoteric and zwitterionic surfactants include alkylbetaines, especially amidoalkylbetaines, and sarcosinates. The chemical treatment compositions may include one or more sanitizing agents or germicides, including one or more of those known to those of ordinary skill in the relevant art, and without limitation, alkyl halohydantoins, alkali metal haloisocyanurates, bleach, essential oils, non-quaternary ammonium based germicidal compounds as well as quaternary ammonium germicidal compounds. The chemical treatment composition may also include compounds or constituents which on contact with water, releases oxygen, hypohalite or a halogen and especially chlorine. Representative examples of typical oxygen-release bleaching agents, suitable for incorporation in the chemical treatment composition include the alkali metal perborates, e.g., sodium perborate, and alkali metal monopersulfates, e.g., sodium monopersulfates, potassium monopersulfate, alkali metal monoperphosphates, e.g., disodium monoperphosphate and dipotassium monoperphosphate, as well as other conventional bleaching agents capable of liberating hypohalite, e.g., hypo chlorite and/or hypobromite, include heterocyclic N-bromo- and N-chloro-cyanurates such as trichloroisocyanuric and tribromoiscyanuric acid, dibromocyanuric acid, dichlorocyanuric acid, N-monobromo-N-mono-chlorocyanuric acid and N-monobromo-N,N-dichlorocyanuric acid, as well as the salts thereof with water solubilizing cations such as potassium and sodium, e.g., sodium N-monobromo-N-monochlorocyanurate, potassium dichlorocyanurate, sodium dichlorocyanurate, as well as other N-bromo and N-chloro-imides, such as N-brominated and N-chlorinated succinimide, malonimide, phthalimide and naphthalimide. The chemical treatment compositions may also include halohydantoins which may be represented by the general structure: wherein: X1 and X2 are independently hydrogen, chlorine or bromine; and, R1 and R2 are independently alkyl groups having from 1 to 6 carbon atoms. Examples of halohydantoins include, for example, N,N′-dichloro-dimethyl-hydantoin, N-bromo-N-chloro-dimethyl-hydantoin, N,N′-dibromo-dimethyl-hydantoin, 1,4-dichloro, 5,5-dialkyl substituted hydantoin, wherein each alkyl group independently has 1 to 6 carbon atoms, N-monohalogenated hydantoins such as chlorodimethylhydantoin (MCDMH) and N-bromo-dimethylhydantoin (MBDMH); dihalogenated hydantoins such as dichlorodimethylhydantoin (DCDMH), dibromodimethylhydantoin (DBDMH), and 1-bromo-3-chloro-5,5,-dimethylhydantoin (BCDMH); and halogenated methylethylhydantoins such as chloromethylethylhydantion (MCMEH), dichloromethylethylhydantoin (DCMEH), bromomethylethylhydantoin (MBMEH), dibromomethylethylhydantoin (DBMEH), and bromochloromethylethylhydantoin (BCMEH), and mixtures thereof. Other suitable organic hypohalite liberating bleaching agents include halogenated melamines such as tribromomelamine and trichloromelamine. Suitable inorganic hypohalite-releasing bleaching agents include lithium and calcium hypochlorites and hypobromites. The various chlorine, bromine or hypohalite liberating agents may, if desired, be provided in the form of stable, solid complexes or hydrates, such as sodium p-toluene sulfobromamine trihydrate; calcium hypobromite tetrahydrate; and calcium hypochlorite tetrahydrate. Brominated and chlorinated trisodium phosphates formed by the reaction of the corresponding sodium hypohalite solution with trisodium orthophosphate (and water, as necessary) likewise comprise useful inorganic bleaching agents for incorporation into the inventive chemical treatment composition and the treatment blocks formed therefrom. When present, preferably the bleach constituent is a hypohalite liberating compound and more preferably is a hypohalite liberating compound in the form of a solid complex or hydrate thereof. Particularly preferred are chloroisocynanuric acids and alkali metal salts thereof, preferably potassium, and especially sodium salts thereof. Examples of such compounds include trichloroisocyananuric acid, dichloroisocyanuric acid, sodium dichloroisocyanurate, potassium dichloroisocyanurate, and trichloro-potassium dichloroisocynanurate complex. The most preferred chlorine bleach material is sodium dichloroisocyanurate. When present, the bleach constituent may be present in any effective amount and may comprise up to about 90% wt., preferably at least about 0.01-100% wt of the chemical treatment composition. Other germicidally effective agents useful as sanitizing agents include sodium dichloroisocyanurate (DCCNa) and sodium dibromoisocyanurate. Further examples of non-quaternary ammonium based sanitizing agents include pyrithiones, dimethyldimethylol hydantoin, methylchloroisothiazolinone/methylisothiazolinone sodium sulfite, sodium bisulfite, imidazolidinyl urea, diazolidinyl urea, benzyl alcohol, 2-bromo-2-nitropropane-1,3-diol, formalin (formaldehyde), iodopropenyl butylcarbamate, chloroacetamide, methanamine, methyldibromonitrile glutaronitrile, glutaraldehyde, 5-bromo-5-nitro-1,3-dioxane, phenethyl alcohol, o-phenylphenol/sodium o-phenylphenol, sodium hydroxymethylglycinate, polymethoxy bicyclic oxazolidine, dimethoxane, thimersal dichlorobenzyl alcohol, captan, chlorphenenesin, dichlorophene, chlorbutanol, glyceryl laurate, halogenated diphenyl ethers, phenolic compounds, mono- and poly-alkyl and aromatic halophenols, resorcinol and its derivatives, bisphenolic compounds, benzoic esters (parabens), halogenated carbanilides, 3-trifluoromethyl-4,4′-dichlorocarbanilide, and 3,3′,4-trichlorocarbanilide. More preferably, the non-cationic antimicrobial agent is a mono- and poly-alkyl and aromatic halophenol selected from the group p-chlorophenol, methyl p-chlorophenol, ethyl p-chlorophenol, n-propyl p-chlorophenol, n-butyl p-chlorophenol, n-amyl p-chlorophenol, sec-amyl p-chlorophenol, n-hexyl p-chlorophenol, cyclohexyl p-chlorophenol, n-heptyl p-chlorophenol, n-octyl p-chlorophenol, o-chlorophenol, methyl o-chlorophenol, ethyl o-chlorophenol, n-propyl o-chlorophenol, n-butyl o-chlorophenol, n-amyl o-chlorophenol, tert-amyl o-chlorophenol, n-hexyl o-chlorophenol, n-heptyl o-chlorophenol, o-benzyl p-chlorophenol, o-benzyl-m-methyl p-chlorophenol, o-benzyl-m, m-dimethyl p-chlorophenol, o-phenylethyl p-chlorophenol, o-phenylethyl-m-methyl p-chlorophenol, 3-methyl p-chlorophenol, 3,5-dimethyl p-chlorophenol, 6-ethyl-3-methyl p-chlorophenol, 6-n-propyl-3-methyl p-chlorophenol, 6-iso-propyl-3-methyl p-chlorophenol, 2-ethyl-3,5-dimethyl p-chlorophenol, 6-sec-butyl-3-methyl p-chlorophenol, 2-iso-propyl-3,5-dimethyl p-chlorophenol, 6-diethylmethyl-3-methyl p-chlorophenol, 6-iso-propyl-2-ethyl-3-methyl p-chlorophenol, 2-sec-amyl-3,5-dimethyl p-chlorophenol 2-diethylmethyl-3,5-dimethyl p-chlorophenol, 6-sec-octyl-3-methyl p-chlorophenol, p-chloro-m-cresol, p-bromophenol, methyl p-bromophenol, ethyl p-bromophenol, n-propyl p-bromophenol, n-butyl p-bromophenol, n-amyl p-bromophenol, sec-amyl p-bromophenol, n-hexyl p-bromophenol, cyclohexyl p-bromophenol, o-bromophenol, tert-amyl o-bromophenol, n-hexyl o-bromophenol, n-propyl-m,m-dimethyl o-bromophenol, 2-phenyl phenol, 4-chloro-2-methyl phenol, 4-chloro-3-methyl phenol, 4-chloro-3,5-dimethyl phenol, 2,4-dichloro-3,5-dimethylphenol, 3,4,5,6-terabromo-2-methylphenol, 5-methyl-2-pentylphenol, 4-isopropyl-3-methylphenol, para-chloro-meta-xylenol, dichloro meta xylenol, chlorothymol, and 5-chloro-2-hydroxydiphenylmethane. Quaternary ammonium based sanitizing agents include any cationic surfactant which is known or may be found to provide a broad antibacterial or sanitizing function; these have been described above with reference to detersive surfactants. As a further chemical constituent, the chemical treatment compositions of the invention may also comprise a coloring agent which imparts either a color to chemical treatment compositions and/or to the water in which it comes into contact, but especially the coloring agent imparts a color to the water contained within the toilet bowl particularly following the flush cycle of a toilet. Colorants, especially dyes, are preferred when formulated as dry powders to enable direct incorporation into chemical treatment compositions of the invention, however, liquid colorants may be employed in conjunction with suitable carriers. When a bleach constituent is included in the chemical treatment composition, the colorant, e.g., dye, should be selected so to ensure the compatibility of the colorant with the bleach constituent, or so that its color persists despite the presence in the toilet bowl of a concentration of hypochlorite which is effective to maintain sanitary conditions. The chemical treatment compositions may also include a fragrance or other air treatment constituent. The fragrance may be any composition which is known to the art to provide a perceptible fragrancing benefit, any may be based on naturally occurring materials such as one or more essential oils, or may be based on synthetically produced compounds as well. Exemplary air treatment constituents include a material which is useful in providing treatment of ambient air, such as a sanitizing agents. e.g., one or more glycols or alcohols, or materials which are intended to counteract, neutralize, or mask odors in the absence of, or in conjunction with, the fragrance composition of the present invention. Alternatively, the air treatment constituent may be one or more materials which provide and effective insecticide repelling or insecticidal benefit; such would be particularly useful in climates or environments where insects present a nuisance or health hazard. As further chemical constituents, the chemical treatment compositions of the invention may comprise an anti-limescale agent, which can be generally classified as a cleaning agent in that it provides a cleaning effect to treated lavatory device surfaces. The anti-limescale agent can virtually any known anti-limescale agent compositions known to those of ordinary skill in the relevant art, e.g., amidosulfonic acid, bisulfate salts, organic acids, sulfonic, and sulfamic acids and their salts, bisulfate salts, organic phosphoric salts, alkali metal polyphosphates, EDTA, and the like. Examples of anti-limescale agent compositions can be found in, for example, U.S. Pat. Nos. 5,759,974; 4,460,490; and 4578207, the contents of which are herein incorporated by reference. The chemical treatment compositions may comprise stain inhibiting materials, such as a manganese stain inhibiting agent, such as a partially hydrolyzed polyacrylamide having a molecular weight of about 2000 to about 10,000, a polyacrylate with a molecular weight of about 2000 to about 10,000, and/or copolymers of ethylene and maleic acid anhydride with a molecular weight of from about 20,000 to about 100,000. The chemical treatment compositions of the invention may include one or more preservatives, which are primarily included to reduce the growth of undesired microorganisms within the chemical treatment compositions during storage prior to use or while used, although it is expected that the such a preservative may impart a beneficial antimicrobial effect to the water in the sanitary appliance to which the treatment block is provided. Exemplary useful preservatives include compositions which include parabens, glutaraldehyde, formaldehyde, 2-bromo-2-nitropropoane-1,3-diol, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-methyl-4-isothiazoline-3-one, and mixtures thereof. Examples of commercially available preservatives which may be used include KATHON® CG/ICP and KATHON® CG/ICP II (ex. Rohm and Haas) PROXEL® (ex. Zeneca Biocides) SUTTOCIDE® A (ex. Sutton Laboratories) as well as TEXTAMER® 38AD (ex. Calgon Corp.) The chemical treatment compositions may include a binder constituent, particularly when the chemical treatment composition is formed into a solid or sem-solid mass such as a cake, tablet, block, briquette, densified powder, prill, or other configuration. The binder may function in part controlling the rate of dissolution of the tablet. The binder constituent may be a clay, or a water-soluble or water-dispersible gel-forming organic polymer, examples of which include chemically modified celluloses such as ethyl cellulose, methyl cellulose, sodium carboxymethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, ethyl hydroxyethyl cellulose, carboxymethyl hydroxyethyl cellulose, and hydroxyethyl cellulose, naturally derived or manufactured (fermented) polymeric materials such as alginates and carageenan, as well as water-soluble starches and gelatin. The optional binder constituent may also be one or more synthetic polymers e.g, polyvinyl alcohols; water-soluble partially hydrolyzed polyvinyl acetates; polyacrylonitriles; polyvinyl pyrrolidones; water-soluble polymers of ethylenically unsaturated carboxylic acids, such as acrylic acid and methacrylic acid, and salts thereof; base-hydrolysed starch-polyacrylonitrile copolymers; polyacrylamides; ethylene oxide polymers and copolymers; as well as carboxypolymethylenes. The chemical treatment composition may optionally include one or more dissolution control agents, which are materials which provide a degree of hydrophobicity to a treatment block formed from the chemical treatment composition. The inclusion of a dissolution control agent in treatment block or other mass formed from a chemical treatment composition contributes to the slow uniform dissolution of the treatment block when contacted with water, and simultaneously the controlled release of the active constituents of the chemical treatment composition. Exemplary dissolution control agents are mono- or di-alkanol amides derived from C8-C16 fatty acids, especially C12-C14 fatty acids having a C2-C6 monoamine or diamine moiety. The chemical treatment compositions may optionally include one or more water-softening agents or one or more chelating agents, for example inorganic water-softening agents such as sodium hexametaphosphate or other alkali metal polyphosphates or organic water-softening agents such as ethylenediaminetetraacetic acid and nitrilotriacetic acid and alkali metal salts thereof. The chemical treatment composition may optionally include one or more solid water-soluble acids or acid-release agents such as sulfamic acid, citric acid or sodium hydrogen sulfate. The chemical treatment composition may include diluent materials to provide additional bulk of the product chemical treatment composition and may enhance leaching out of the surfactant constituent when the chemical treatment composition is placed in water. Exemplary diluent materials include any soluble inorganic alkali, alkaline earth metal salt or hydrate thereof, for example, chlorides such as sodium chloride, magnesium chloride and the like, carbonates and bicarbonates such as sodium carbonate, sodium bicarbonate and the like, sulfates such as magnesium sulfate, copper sulfate, sodium sulfate, zinc sulfate and the like, borax, borates such as sodium borate and the like, as well as others known to the art but not particularly recited herein. The chemical treatment composition and blocks or other masses formed therefrom may include one or more fillers. Such fillers are typically particulate solid water-insoluble materials which may be based on inorganic materials such as talc or silica, particulate organic polymeric materials such as finely comminuted water insoluble synthetic polymers. The chemical treatment composition and treatment blocks formed therefrom may include one or more further processing aids such as binders or plasticizers serving to assist in the manufacture thereof, for example, polypropylene glycol, pine oil fractions, d-limonene, dipentene and the ethylene oxide-propylene oxide block copolymers. Other useful processing aids include tabletting lubricants such as metallic stearates, stearic acid, paraffin oils or waxes or sodium borate which facilitate in the formation of the treatment blocks in a tabletting press or die. Further useful processing aids include certain diester constituents, as disclosed in published US patent application US 2007-0092477 A1, the contents of which are herein incorporated by reference in its entirety. Certain hydrocarbon solvents are also useful as processing aids and may form part of the chemical treatment compositions of the device according to the invention. Exemplary hydrocarbon solvents include those disclosed in published US patent application 2007/0003500 A1 the contents of which are incorporated by reference in its entirety. Mineral oil is may also be advantageously used as a processing aid. An exemplary and preferred lavatory treatment composition is a compressed solid block of a chemical treatment composition commercially available as (ex. Lonza) having the following composition: 98% wt. of a mixture of 3-Bromo-1-Chloro-5,5-dimethylhydantoin, bromochloro-5,5-dimethylhydantoin, 1,3-dichloro-5,5-dimethylhydantoin, 1,3-dichloro-5-ethyl-5-methylhydantoin 1.5% wt. sodium chloride 0.5% wt. moisture. The chemical treatment compositions may be provided in any of a number of forms. In certain preferred embodiments the chemical treatment composition may be provided in the form of at tablet or cake which is formed by extrusion and/or tabletting of the chemical treatment composition into suitably sized tablets, cakes, bricks, briquettes, blocks, prills, pearls, or alternately the chemical treatment compositions may be formed in situ within the devices of the invention, for example by providing a molten or flowable quantity of the chemical treatment composition to the hollow cavity of the device and permitting it to set or hard within the cavity, e.g. by cooling, where it forms a mass of the chemical treatment composition. Ideally the chemical treatment composition exhibit a density greater than that of water which ensures that they will sink when suspended in a body of water, e.g., the water present within the hollow cavity. While the mass of the chemical treatment compositions formed from the chemical treatment compositions may vary, and amount of up to an including 500 grams may be practiced, generally the mass of the chemical treatment compositions do not exceed about 250 grams. Advantageously the mass of the chemical treatment compositions is between about 50 and 150 grams. It is appreciated that chemical treatment compositions having great mass should provide a longer useful service life of the lavatory dispensing devices, with the converse being equally true. The chemical treatment compositions according to the present invention may also be provided with a coating of a water-soluble film, such as polyvinyl acetate following the formation of the treatment blocks from the recited chemical treatment composition. Such may be desired for improved handling, however such is often unnecessary as preferred embodiments of the blocks exhibit a lower likelihood of sticking to one another following manufacture than many prior art treatment block compositions. It will be appreciated by those of ordinary skill in the art that several of the components which are directed to provide a chemical composition can be blended into one chemical composition with the additional appreciation that potential
{'bibliographic_information': "{'country': 'US', 'doc-number': '13375806', 'kind': 'B2', 'date': '20100526', 'extension': '390', 'invention_title': 'In lavatory dispensing devices'}", 'source_file': './grant/2015/ipg150106.xml', 'source_data': 'USPTO-Grant'}