Title of Invention: SELECTIVE CATALYTIC REDUCTION ARTICLES AND SYSTEMS Abstract: The present disclosure relates to copper-containing molecular sieve catalysts that are highly suitable for the treatment of exhaust containing NOx pollutants. The copper-containing molecular sieve catalysts contain ion-exchanged copper as Cu+2 and Cu(OH)+1, and DRIFT spectroscopy of the catalyst exhibits perturbed T-O-T vibrational peaks corresponding to the Cu+2 and Cu(OH)+1. In spectra taken of the catalytic materials, a ratio of the Cu+2 to the Cu(OH)+1 peak integration areas preferably can be ≥1. The copper-containing molecular sieve catalysts are aging stable such that the peak integration area percentage of the Cu+2 peak (area Cu+2/(area Cu+2+area Cu(OH)+1)) increases by ≤20% upon aging at 800° C. for 16 hours in the presence of 10% H2O/air, compared to the fresh state. Detailed Description: FIELD OF THE DISCLOSURE The present disclosure relates to selective catalytic reduction (SCR) catalysts, catalytic articles, systems and methods suitable for treating exhaust of an internal combustion engine. BACKGROUND Molecular sieves such as zeolites are employed in the catalysis of certain chemical reactions for example the selective catalytic reduction (SCR) of nitrogen oxides with a reductant such as ammonia, urea or hydrocarbons. Zeolites are crystalline materials having rather uniform pore sizes which range from about 3 to about 25 Angstroms in diameter, depending upon the type of zeolite. Catalysts employed in the SCR process must be able to retain good catalytic activity over the wide range of temperatures found in practical applications, including hydrothermal conditions with temperatures ranging, for example, from about 150° C. to about 800° C. or higher. Hydrothermal conditions are encountered by SCR catalysts, as water is a byproduct of fuel combustion. High temperature hydrothermal conditions occur in exhaust applications, for example, during the regeneration of a diesel particulate filter (DPF) or catalyzed soot filter (CSF), a component of exhaust gas treatment systems used for the removal of carbonaceous particles. The SCR process converts nitrogen oxides (NOx) to nitrogen (N2) and water (H2O). Nitrogen oxides (NOx) may include N2O, NO, N2O3, NO2, N2O4, N2O5 or HNO3. It would be desirable to have improved articles, systems and processes to convert NOx selectively within internal combustion engine exhaust streams to N2. Improvements in high temperature hydrothermal durability are required for short duration transients where exhaust temperatures may reach 750° C., 800° C., 850° C. or even 900° C. Particularly important are improvements in low temperature NOx performance, for example from about 150° C. to about 300° C., after high temperature hydrothermal aging. SUMMARY OF THE DISCLOSURE The present disclosure provides, in some embodiments, a copper-containing molecular sieve catalyst, wherein the catalyst in a fresh state contains ion-exchanged copper wherein 50 at % (atomic percent) of the ion-exchanged copper is Cu+2. In further embodiments, the present disclosure can provide a copper-containing molecular sieve catalyst having a silica-to-alumina ratio (SAR) of about 5 to about 35 or about 14 to about 28 and a Cu/AI atomic ratio of about 0.20 to about 0.50. In other embodiments, the present disclosure can provide a copper-containing molecular sieve catalyst, wherein the catalyst in a fresh state contains ion-exchanged copper as Cu+2 and Cu(OH)+1 and where, in a DRIFT spectrum of the catalyst exhibiting a perturbed T-O-T asymmetric stretching vibrational peak corresponding to Cu+2 cations and a perturbed T-O-T asymmetric stretching vibrational peak corresponding to Cu(OH)+1 cations, the ratio of the peak integration area for the respective Cu+2 and Cu(OH)+1 peaks is 1. In yet other embodiments, the present disclosure can provide a copper-containing catalyst wherein the catalyst in a fresh state contains ion-exchanged copper as Cu+2 and Cu(OH)+1 and where, in a DRIFT spectrum of the catalyst exhibiting a T-O-T asymmetric stretching vibrational peak corresponding to Cu+2 and a T-O-T asymmetric stretching vibrational peak corresponding to Cu(OH)+1, the percent of integrated peak area of the T-O-T asymmetric stretching vibrational peak corresponding to Cu+2 relative to the total integrated areas of the T-O-T asymmetric stretching vibrational peaks corresponding to both Cu+2 and Cu(OH)+1 (i.e., area Cu+2/(area Cu+2+area Cu(OH)+1)) increases by 20%, 15%, 10%, or 5% upon aging at 800° C. for 16 hours in the presence of 10% H2O/air, compared to the fresh state. The present disclosure also can provide a catalytic article comprising a catalytic coating disposed over a substrate, where the catalytic coating comprises one or more coating layers, wherein at least one coating layer is a catalytic coating layer comprising a copper-containing molecular sieve catalyst as described above. The present disclosure further can provide an exhaust gas treatment system comprising the catalytic article, as well as a method for treating an exhaust stream containing NOx, the method comprising passing the exhaust stream through the catalytic article or treatment system. The present catalysts, catalytic articles, systems and methods are particularly suitable for the treatment of exhaust gases generated from diesel or gasoline engines, especially those which operate under “lean” combustion conditions with air present in excess of that required for stoichiometric combustion. The invention includes, without limitation, the following embodiments. Embodiment 1 A selective catalytic reduction article comprising a substrate having a catalytic coating on at least a portion of a surface thereof, the catalytic coating including a copper-containing molecular sieve containing ion-exchanged copper as Cu+2 cations and as Cu(OH)+1 cations, wherein the copper-containing molecular sieve exhibits a perturbed T-O-T asymmetric stretching vibrational peak corresponding to the Cu+2 cations and a perturbed T-O-T asymmetric stretching vibrational peak corresponding to the Cu(OH)+1 cations, and wherein an integrated peak area of the perturbed T-O-T asymmetric stretching vibrational peak corresponding to the Cu+2 cations and an integrated peak area of the perturbed T-O-T asymmetric stretching vibrational peak corresponding to the Cu(OH)+1 cations have a ratio of as measured using Diffuse Reflectance Infrared Fourier Transform (DRIFT) spectroscopy. Embodiment 2 The selective catalytic reduction article of any preceding embodiment, wherein the copper-containing molecular sieve exhibits the perturbed T-O-T asymmetric stretching vibrational peaks corresponding to the Cu+2 cations and the Cu(OH)+1 cations at about 900 cm−1 and about 950 cm−1, respectively, in the infrared spectrum, or wherein the copper-containing molecular sieve exhibits the perturbed T-O-T asymmetric stretching vibrational peaks corresponding to the Cu+2 cations and the Cu(OH)+1 cations at about 900 cm−1 and about 970 cm−1, respectively, in the infrared spectrum. Embodiment 3 The selective catalytic reduction article of any preceding embodiment, wherein a percentage of the total integrated peak area that is attributable to the perturbed T-O-T asymmetric stretching vibrational peak corresponding to the Cu+2 cations is calculated by dividing the integrated peak area for the perturbed T-O-T asymmetric stretching vibrational peak corresponding to the Cu+2 cations by the integrated peak areas for the perturbed T-O-T asymmetric stretching vibrational peaks corresponding to the Cu+2 cations and Cu(OH)+1 cations combined, and wherein the percentage of the total integrated peak area that is attributable to the perturbed T-O-T asymmetric stretching vibrational peak for Cu+2 cations is 50%. Embodiment 4 The selective catalytic reduction article of any preceding embodiment, wherein the contribution by the perturbed T-O-T asymmetric stretching vibrational peak corresponding to the Cu+2 cations to the combined integrated peak areas for the perturbed T-O-T asymmetric stretching vibrational peaks of the Cu+2 cations and Cu(OH)+1 cations for the copper-containing molecular sieve in an aged state is increased by 20% relative to the contribution for the copper-containing molecular sieve in the fresh state, wherein the aged state is defined by having aged the selective catalytic reduction article at a temperature of about 800° C. for a time of about 16 hours in the presence of air with an H2O content of about 10 mol. %. Embodiment 5 The selective catalytic reduction article of any preceding embodiment, wherein the total amount of copper in the copper-containing molecular sieve, calculated as copper oxide, is about 1.0 wt. % to about 10 wt. %, based on the total weight of the copper-containing molecular sieve. Embodiment 6 The selective catalytic reduction article of any preceding embodiment, wherein the copper-containing molecular sieve comprises crystals or agglomerates having a mean size 2.0 microns. Embodiment 7 The selective catalytic reduction article of any preceding embodiment, wherein the copper-containing molecular sieve comprises a small pore molecular sieve selected from the group consisting of framework types AEI, AFT, AFV, AFX, AVL, CHA, DDR, EAB, EEI, ERI, IFY, IRN, KFI, LEV, LTA, LTN, MER, MWF, NPT, PAU, RHO, RTE, RTH, SAS, SAT, SAV, SFW, TSC, UFI, mixtures thereof, and intergrowths thereof. Embodiment 8 The selective catalytic reduction article of any preceding embodiment, wherein the molecular sieve comprises a medium pore molecular sieve selected from the group consisting of framework types AEL, AFO, AHT, BOF, BOZ, CGF, CGS, CHI, DAC, EUO, FER, HEU, IMF, ITH, ITR, JRY, JSR, JST, LAU, LOV, MEL, MFI, MFS, MRE, MTT, MW, MWW, NAB, NAT, NES, OBW, PAR, PCR, PON, PUN, RRO, RSN, SFF, SFG, STF, STI, STT, STW, SVR, SZR, TER, TON, TUN, UOS, VSV, WEI, WEN, mixtures thereof, and intergrowths thereof. Embodiment 9 The selective catalytic reduction article of any preceding embodiment, wherein the molecular sieve comprises a large pore molecular sieve selected from the group consisting of framework types AFI, AFR, AFS, AFY, ASV, ATO, ATS, BEA, BEC, BOG, BPH, BSV, CAN, CON, CZP, DFO, EMT, EON, EZT, FAU, GME, GON, IFR, ISV, ITG, IWR, IWS, IWV, IWW, JSR, LTF, LTL, MAZ, MEI, MOR, MOZ, MSE, MTW, NPO, OFF, OKO, OSI, RON, RWY, SAF, SAO, SBE, SBS, SBT, SEW, SFE, SFO, SFS, SFV, SOF, SOS, STO, SSF, SSY, USI, UWY, VET, mixtures thereof, and intergrowths thereof. Embodiment 10 The selective catalytic reduction article of any preceding embodiment, wherein the molecular sieve is selected from the group consisting of aluminosilicate zeolites, borosilicates, gallosilicates, SAPOs, AIPOs, MeAPSOs, MeAPOs, and combinations thereof. Embodiment 11 The selective catalytic reduction article of any preceding claim, wherein the molecular sieve has CHA cages and double-six ring building units and is selected from the group consisting of Cu-CHA, Cu-SAPO-34, AEI, Cu-SAPO-18, and combinations thereof. Embodiment 12 The selective catalytic reduction article of any preceding embodiment, wherein the selective catalytic reduction article further comprises one or more catalytically active metals selected from the group consisting of manganese, iron, cobalt, nickel, cerium, platinum, palladium and rhodium; or containing one or more base metals selected from the group consisting of sodium, potassium, magnesium, calcium, strontium, barium, and combinations thereof. Embodiment 13 The selective catalytic reduction article of any preceding embodiment, wherein the catalytic coating comprises: a first catalytic coating comprising the copper-containing molecular sieve, and a second catalytic coating that is different from the first catalytic coating. Embodiment 14 The selective catalytic reduction article of any preceding embodiment, wherein the second catalytic coating comprises a copper-containing molecular sieve that is different from the copper-containing molecular sieve in the first coating. Embodiment 15 The selective catalytic reduction article of any preceding embodiment, wherein the second catalytic coating comprises a platinum group metal on a refractory metal oxide support. Embodiment 16 The selective catalytic reduction article of any preceding embodiment, wherein the platinum group metal is present in an amount of about 0.5 g/ft3 to about 30 g/ft3, based on the total volume of the substrate. Embodiment 17 The selective catalytic reduction article of any preceding embodiment, wherein the catalytic coating including the copper-containing molecular sieve is present in an amount of about 0.1 g/in3 to about 4.5 g/in3, based on the total volume of the substrate. Embodiment 18 The selective catalytic reduction article of any preceding embodiment, wherein the first catalytic coating and the second catalytic coating are in a layered configuration or zoned configuration. Embodiment 19 The selective catalytic reduction article of any preceding embodiment, wherein the substrate is a porous wall-flow filter or a flow-through monolith. Embodiment 20 An exhaust gas treatment system comprising: a selective catalytic reduction article according to any preceding embodiment; and a reductant injector in fluid communication with and upstream of the selective catalytic reduction article. Embodiment 21 The exhaust gas treatment system of any preceding embodiment, further comprising one or more of a diesel oxidation catalyst, a soot filter, a lean NOx trap (LNT), and an ammonia oxidation catalyst. Embodiment 22 A method for treating an exhaust stream containing NOx, comprising passing the exhaust stream through a selective catalytic reduction article or an exhaust gas treatment system of any preceding embodiment. Embodiment 23 A method for identifying a catalytic material that is stable towards aging, the method comprising: providing a plurality of samples that each comprise particles of a copper-containing molecular sieve containing ion-exchanged copper as Cu+2 cations and as Cu(OH)+1 cations; subjecting the particles of the copper-containing molecular sieve to Diffuse Reflectance Infrared Fourier Transform (DRIFT) spectroscopy so as to evaluate perturbed T-O-T asymmetric stretching vibrational peaks corresponding to the Cu+2 cations in the copper-containing molecular sieve and perturbed T-O-T asymmetric stretching vibrational peaks corresponding to the Cu(OH)+1 cations in the copper-containing molecular sieve; and selecting one or more of the samples wherein the copper-containing molecular sieve exhibits a ratio for an integrated peak area of the perturbed T-O-T asymmetric stretching vibrational peak corresponding to the Cu+2 cations to an integrated peak area of the perturbed T-O-T asymmetric stretching vibrational peak corresponding to the Cu(OH)+1 cations that is ≥1. Embodiment 24 The method of any preceding embodiment, wherein a percentage of the total integrated peak area that is attributable to the perturbed T-O-T bond vibrational peak corresponding to the Cu+2 cations is calculated by dividing the integrated peak area for the perturbed T-O-T bond vibrational peak corresponding to the Cu+2 cations by the integrated peak areas for the perturbed T-O-T bond vibrational peak corresponding to the Cu+2 cations and the perturbed T-O-T bond vibrational peak corresponding to the Cu(OH)+1 cations combined, and wherein the method comprises selecting one or more samples wherein the percentage of the total integrated peak area that is attributable to the perturbed T-O-T bond vibrational peak for Cu+2 cations is ≥50%. Embodiment 25 The method of any preceding embodiment, wherein the plurality of copper-containing molecular sieve samples is subjected to the DRIFT spectroscopy in a fresh state, and wherein the method further comprises: aging the plurality of samples at a temperature of about 800° C. for a time of about 16 hours in the presence of air with an H2O content of about 10 mol. % to form aged samples; subjecting the aged samples to the DRIFT spectroscopy; and selecting one or more of the samples wherein the contribution to the total integrated peak area by the perturbed T-O-T asymmetric stretching vibrational peak corresponding to the Cu+2 cations for the one or more samples in an aged state is increased by 20% relative to the contribution to the total integrated peak area by the perturbed T-O-T asymmetric stretching vibrational peak corresponding to the Cu+2 cations for the one or more samples in the fresh state. Embodiment 26 A method of manufacturing a catalytic article, the method comprising: developing a process for preparing a first composition comprising copper-containing molecular sieves; analyzing at least a sample of the first composition using DRIFT spectroscopy to determine the relative amount of Cu+2 and Cu(OH)+1 in the first composition based on a comparison of intensities of perturbed T-O-T asymmetric stretching vibrational peaks corresponding to the Cu+2 and Cu(OH)+1; selecting the process for commercial manufacturing of the first composition if the contribution by the perturbed T-O-T asymmetric stretching vibrational peak corresponding to Cu+2 to the total integrated peak areas of the perturbed T-O-T asymmetric stretching vibrational peaks is ≥50%; and applying the commercially manufactured first composition made by the process to a substrate to produce the catalytic article. These and other features, aspects, and advantages of the disclosure will be apparent from a reading of the following detailed description together with the accompanying drawings, which are briefly described below. The invention includes any combination of two, three, four, or more of the above-noted embodiments as well as combinations of any two, three, four, or more features or elements set forth in this disclosure, regardless of whether such features or elements are expressly combined in a specific embodiment description herein. This disclosure is intended to be read holistically such that any separable features or elements of the disclosed invention, in any of its various aspects and embodiments, should be viewed as intended to be combinable unless the context clearly dictates otherwise. Other aspects and advantages of the present invention will become apparent from the following. BRIEF DESCRIPTION OF THE DRAWINGS The disclosure described herein is illustrated by way of example and not by way of limitation in the accompanying figures. For simplicity and clarity of illustration, features illustrated in the figures are not necessarily drawn to scale. For example, the dimensions of some features may be exaggerated relative to other features for clarity. Further, where considered appropriate, reference labels have been repeated among the figures to indicate corresponding or analogous elements. FIG. 1 is a perspective view of a honeycomb-type substrate carrier which may comprise a catalyst article in the form of a washcoat composition in accordance with the present disclosure. FIG. 2 is a partial cross-sectional view enlarged relative to FIG. 1 and taken along a plane parallel to the end faces of the substrate carrier of FIG. 1, which shows an enlarged view of a plurality of the gas flow passages shown in FIG. 1, in an embodiment wherein the substrate carrier is a monolithic flow-through substrate. FIG. 3 is a cutaway view of a section enlarged relative to FIG. 1, wherein the honeycomb-type substrate carrier in FIG. 1 represents a wall flow filter substrate monolith. FIG. 4a is a cross-section showing coating layers and/or coating zones on one or more substrates according to exemplary embodiments of the present disclosure. FIG. 4b is a cross-section showing coating layers and/or coating zones on one or more substrates according to exemplary embodiments of the present disclosure FIG. 5 is a graph showing NOx conversion of catalytic coating samples as described in Example 1 and Example 2. FIG. 6 is a graph showing NOx conversion of catalytic coating samples as described in Example 1 and Example 3. FIG. 7 illustrates the DRIFT spectra of catalytic coating samples as described in Examples 1 through 3 in the fresh state. FIG. 8 illustrates the DRIFT spectra of catalytic coating samples as described in Example 1 in a fresh state and an aged state. FIG. 9 illustrates the DRIFT spectra of catalytic coating samples as described in Example 3 in a fresh state and an aged state. FIG. 10 is a graph showing NOx conversion of catalytic coating samples as described in Example 3 and Example 6. FIG. 11 illustrates the DRIFT spectra of catalytic coating samples as described in Example 6 in a fresh state and an aged state. DETAILED DESCRIPTION The present catalyst compositions are suitable for treatment of exhaust gas streams of internal combustion engines, for example gasoline, light-duty diesel and heavy duty diesel engines. The catalyst compositions are also suitable for treatment of emissions from stationary industrial processes or for catalysis in chemical reaction processes. High surface area refractory metal oxide supports are materials used as catalyst supports that receive precious metals, stabilizers, promoters, binders and the like through association, dispersion, impregnation or other suitable methods. High surface area refractory metal oxide supports can comprise an activated compound selected from the group consisting of alumina, zirconia, silica, titania, ceria, lanthana, baria and combinations thereof. Molecular Sieves Molecular sieves refer to materials having an extensive three-dimensional network of oxygen ions containing generally tetrahedral type sites and having a pore distribution of relatively uniform pore size. A zeolite is a specific example of a molecular sieve, further including silicon and aluminum. Reference to a “non-zeolite-support” or “non-zeolitic support” in a catalyst layer refers to a material that is not a zeolite. Examples of such non-zeolitic supports include, but are not limited to, high surface area refractory metal oxides. Molecular sieves comprise small pore, medium pore, and large pore molecular sieves or combinations thereof. A small pore molecular sieve contains channels defined by up to eight tetrahedral atoms. A medium pore molecular sieve contains channels defined by ten-membered rings. A large pore molecular sieve contains channels defined by rings of at least twelve tetrahedral atoms. Small pore molecular sieves have an 8-ring opening and may have for instance a double 6-ring (D6R) or 6-ring structural unit. The cage building units include the CHA cage, various modifications of the CHA cage, LTA cage, GME cage and the like. Small pore molecular sieves are selected from the group consisting of aluminosilicate molecular sieves, metal-containing aluminosilicate molecular sieves, aluminophosphate (ALPO) molecular sieves, metal-containing aluminophosphate (MeALPO) molecular sieves, silico-aluminophosphate (SAPO) molecular sieves, and metal-containing silico-aluminophosphate (MeSAPO) molecular sieves and mixtures thereof. For example, small pore molecular sieves are selected from the group consisting of framework types AEI, AFT, AFV, AFX, AVL, CHA, DDR, EAB, EEI, ERI, IFY, IRN, KFI, LEV, LTA, LTN, MER, MWF, NPT, PAU, RHO, RTE, RTH, SAS, SAT, SAV, SFW, TSC, UFI and mixtures or intergrowths thereof. For instance, the small pore molecular sieve is selected from the group of framework types CHA, LEV, AEI, AFT, AFX, ERI, LTA, SFW, KFI and DDR. Medium pore molecular sieves are selected from the group consisting of framework types AEL, AFO, AHT, BOF, BOZ, CGF, CGS, CHI, DAC, EUO, FER, HEU, IMF, ITH, ITR, JRY, JSR, JST, LAU, LOV, MEL, MFI, MFS, MRE, MTT, MVY, MVWV, NAB, NAT, NES, OBW, PAR, PCR, PON, PUN, RRO, RSN, SFF, SFG, STF, STI, STT, STW, SVR, SZR, TER, TON, TUN, UOS, VSV, WEI, WEN and mixtures or intergrowths thereof. For instance, the medium pore molecular sieves are selected from the group consisting of framework types FER, MEL, MFI and STT. Large pore molecular sieves are selected from the group consisting of framework types AFI, AFR, AFS, AFY, ASV, ATO, ATS, BEA, BEC, BOG, BPH, BSV, CAN, CON, CZP, DFO, EMT, EON, EZT, FAU, GME, GON, IFR, ISV, ITG, IWR, IWS, IWV, IWW, JSR, LTF, LTL, MAZ, MEI, MOR, MOZ, MSE, MTW, NPO, OFF, OKO, OSI, RON, RWY, SAF, SAO, SBE, SBS, SBT, SEW, SFE, SFO, SFS, SFV, SOF, SOS, STO, SSF, SSY, USI, UWY, VET and mixtures or intergrowths thereof. For instance, the large pore molecular sieves are selected from the group consisting of framework types AFI, BEA, FAU, MAZ, MOR and OFF. For example, molecular sieves comprise a framework type selected from the group consisting of AEI, BEA (beta zeolites), CHA (chabazite), FAU (zeolite Y), FER (ferrierite), MFI (ZSM-5) and MOR (mordenite). Non-limiting examples of zeolites having these structures include chabazite, faujasite, zeolite Y, ultrastable zeolite Y, beta zeolite, mordenite, silicalite, zeolite X and ZSM-5. Useful molecular sieves have 8-ring pore openings and double-six ring secondary building units, for example, those having structure types AEI, AFT, AFX, CHA, EAB, ERI, KFI, LEV, SAS, SAT or SAV. Included are any and all isotopic framework materials such as SAPO, ALPO and MeAPO materials having the same structure type. Aluminosilicate zeolite structures do not include phosphorus or other metals isomorphically substituted in the framework. That is, “aluminosilicate zeolite” excludes aluminophosphate materials such as SAPO, ALPO and MeAPO materials, while the broader term “zeolite” includes aluminosilicates and aluminophosphates. In one or more embodiments, the 8-ring small pore molecular sieve has the CHA crystal structure. Copper-containing chabazite is abbreviated as CuCHA. In further embodiments, the molecular sieve can have the SAPO crystal structure—i.e., CuSAPO. A synthetic 8-ring small pore molecular sieve (for example having the CHA structure) may be prepared via mixing a source of silica, a source of alumina and a structure directing agent under alkaline aqueous conditions. Typical silica sources include various types of fumed silica, precipitated silica and colloidal silica, as well as silicon alkoxides. Typical alumina sources include boehmites, pseudo-boehmites, aluminum hydroxides, aluminum salts such as aluminum sulfite or sodium aluminate and aluminum alkoxides. Sodium hydroxide is typically added to the reaction mixture. A typical structure directing agent for this synthesis is adamantyltrimethyl ammonium hydroxide, although other amines and/or quaternary ammonium salts may be substituted or added. The reaction mixture is heated in a pressure vessel with stirring to yield a crystalline product. Typical reaction temperatures are in the range of from about 100° C. to about 200° C., for instance from about 135° C. to about 170° C. Typical reaction times are between 1 hr and 30 days and in some embodiments, from 10 hours to 3 days. At the conclusion of the reaction, the pH is optionally adjusted to between 6 and 10, for example between 7 and 7.5 and the product is filtered and washed with water. Any acid can be used for pH adjustment, for instance nitric acid. Optionally, the product may be centrifuged. Organic additives may be used to help with the handling and isolation of the solid product. Spray-drying is an optional step in the processing of the product. The solid product is thermally treated in air or nitrogen. Alternatively, each gas treatment can be applied in various sequences or mixtures of gases can be applied. Typical calcination temperatures are in from about 400° C. to about 850° C. Molecular sieves having a CHA structure may be prepared for instance according to methods disclosed in U.S. Pat. Nos. 4,544,538 and 6,709,644, the disclosures of which are incorporated herein by reference. The molecular sieves may have a silica-to-alumina ratio (SAR) of about 1 to about 1000. In some embodiments, the molecular sieve may have an SAR of about 2 to about 750, about 5 to about 250, or about 5 to about 50. Advantageously, the molecular sieves of the present catalyst compositions are small pore, medium pore or large pore molecular sieves. Catalytic Molecular Sieves The catalyst for example contains ion-exchanged copper where the atomic percentage (atomic % or at %) of ion-exchanged copper in a Cu+2 state in a fresh sample compared to the atomic % of ion-exchanged copper in a Cu+2 state in the sample aged at 800° C. for 16 hours in the presence of 10% H2O/air remains stable. As further described herein, such stability has been found to be highly desirable in identifying catalytic materials with improved NOx conversion activity. Preferably, the atomic percentages for a fresh sample versus an aged sample are within 20%, within 15%, within 10%, or within 5% of each other. The atomic percentage of ion-exchanged copper in Cu+2 state means relative to all ion-exchanged copper. In the present invention, the copper present in the ion-exchange sites (ion-exchanged copper) of the molecular sieves is 50 at % (atomic percent) Cu+2. Other ion-exchanged copper is in the form of, for example, Cu(OH)+1. This is after exposure to air and/or moisture and thus after oxidation. The Cu+2 atomic percentage is determined based upon analysis of infrared spectra of fresh and aged samples that allow for identification of the relative copper species present in the copper-exchanged catalytic material. In some embodiments, the ion-exchanged copper may be identified for instance via DRIFT spectroscopy (Diffuse Reflectance Infrared Fourier Transform spectroscopy) carried out using known methods. Copper species may be detected by monitoring perturbed T-O-T bond (Si—O—Al and Si—O—Si) vibrations of a molecular sieve. Structural vibrations of T-O-T bonds of molecular sieves exhibit absorption peaks from about 1350 cm−1 to about 920 cm−1 and about 850 cm−1 to about 620 cm−1 for asymmetric and symmetric vibration modes, respectively. Perturbed T-O-T bond vibrations are observed when copper ions are exchanged into cationic positions of a molecular sieve, due to strong interactions between copper ions and framework oxygen. Peak positions depend on the nature of the copper ions and the structure of the molecular sieve framework. Peak intensity and peak integrated area can depend on the quantity of copper ions in the exchange sites. Accordingly, DRIFT spectroscopy is effective for qualitative analysis of the nature of the copper-exchanged molecular sieve catalytic material. In general, this invention contemplates using for characterization any vibrational modes that are perturbed (i.e., shifted) due to the presence of different species of metallic ions interacting with the T-O-T framework of the molecular sieves. For example, as disclosed herein, copper species may be detected by monitoring perturbed T-O-T asymmetric stretching vibrational modes by using DRIFT spectroscopy. DRIFT spectroscopy may be performed as in the present Examples. See, also, Luo et al., “Identification of two types of Cu sites in Cu/SSZ-13 and their unique responses to hydrothermal aging and sulfur poisoning,” Catalysis Today, 267 (2016), 3-9; and Kwak et al., “two different cationic positions in Cu-SSZ-13?,” Chem. Commun., 2012, 48, 4758-4760. In DRIFT spectra of aluminosilicate chabazite CuCHA, in addition to the asymmetric and symmetric vibrations of unperturbed T-O-T (Si—O—Al) johnsonreginald@example.org. 1040 and ca. 810 cm−1, two absorptions are johnsonreginald@example.org. 900 cm−1 and ca. 950 cm−1, attributed to a perturbed T-O-T asymmetric stretching vibration with Cu+2 associated with an Al pair and a perturbed T-O-T asymmetric stretching vibration with Cu(OH)+1 associated with a single Al, respectively. In the present disclosure, the term “exhibiting a Cu+2 peak and a Cu(OH)+1 peak” refers to the perturbed absorptions that are identified in the DRIFT spectra. For example, in the case of a copper chabazite catalytic material, infrared johnsonreginald@example.org. 900 cm−1 and ca. 950 cm−1 corresponding to perturbed T-O-T asymmetric stretching vibrations can be correlated to the presence of Cu+2 and Cu(OH)+1, respectively. Similarly, in the case of a copper SAPO catalytic material, infrared johnsonreginald@example.org. 900 cm−1 and ca. 970 cm−1 corresponding to perturbed asymmetric stretching vibrations can be correlated to the presence of Cu+2 and Cu(OH)+1, respectively. Without being bound by theory, it is believed that Cu+2 balancing the charge of an Al pair is more hydrothermally stable than Cu(OH)+1 associated with a single Al, thus providing catalysts capable of high NOx reduction activity and high hydrothermal stability. Also without being bound by theory, it is believed that Cu cations balance the charge created by Si substituting for P in a SAPO molecular sieve. The perturbed T-O-T bond vibrations for SAPO are related to the structural vibrations due to the Si, Al and P in the tetrahedral “T” sites. As such, catalysts with a higher relative percentage of Cu+2 in the molecular sieve framework (as determined via DRIFT analysis as discussed above through identification of perturbed T-O-T bonds, such as those corresponding to perturbed T-O-T asymmetric stretching vibrations) can be identified and can provide improved catalytic performance and aging stability. In some embodiments, preferred stability can be associated with a defined ratio between the integrated peak area of the perturbed T-O-T asymmetric stretching peak corresponding to the Cu+2 cations (e.g., the peak for perturbed T-O-T bonds at about 900 cm−1 in a DRIFT spectrum) and the integrated peak area of the perturbed T-O-T asymmetric stretching peak corresponding to the Cu(OH)+1 cations (e.g., the peak for perturbed T-O-T bonds at about 950 cm−1 in a DRIFT spectrum for CuCHA or at about 970 cm−1 in a DRIFT spectrum for CuSAPO). For example, the ratio of the integrated peak area for perturbed T-O-T asymmetric stretching peaks corresponding to Cu+2 relative to peaks corresponding to Cu(OH)−1 can be or For example, the ratio of the integrated peak areas can be about 1 to about 5 about 1.2 to about 4, or about 1.5 to about 3. In further embodiments, suitable copper-exchanged molecular sieves can be identified in relation to the contribution to the total peak area of the perturbed T-O-T asymmetric stretching vibrational peaks by the perturbed T-O-T asymmetric stretching vibrational peak for Cu+2. This can be calculated using the formula provided below, wherein “area Cu+2” is the integrated peak area perturbed T-O-T asymmetric stretching vibrational peaks corresponding to Cu+2 (i.e., the peak at about 900 cm−1 in the DRIFT spectrum), and “area Cu(OH)+1” is the integrated peak area for perturbed T-O-T asymmetric stretching vibrational peaks corresponding to Cu(OH)+1 (i.e., the peak at about 950 cm−1 in the DRIFT spectrum for CuCHA and at about 970 cm−1 in the DRIFT spectrum for CuSAPO). ( area   Cu + 2 ) ( area   Cu + 2 + area   Cu  ( OH ) + 1 ) Preferably, the percentage of the total peak area that is attributable to the perturbed T-O-T asymmetric stretching vibrational peak for Cu+2 is at least 50%, at least 55%, or at least 60%, such as about 55% to about 95%, about 60% to about 90%, or about 65% to about 85%. While the integrated area under the respective curves for the perturbed absorptions presently has not been correlated to an amount of the relative atomic % of the individual copper species present, maintenance of the ratio with aging is clearly indicative of a stable structure and has been correlated to a material with stable catalytic activity. In some embodiments, the foregoing ratio and percentage may be substantially unchanged between the fresh state and the aged state for the copper-exchanged molecular sieve. For example, after the copper-exchanged molecular sieve has been aged at a temperature of about 800° C. for a time of about 16 hours in the presence of air with an H2O content of about 10 mol %, the percentage of the total peak area corresponding to perturbed T-O-T asymmetric stretching vibrations that is attributable to the perturbed T-O-T asymmetric stretching vibrational peak for Cu+2 can be increased by ≤30%, ≤20%, or ≤10%. Without being bound by theory, it is believed that all molecular sieves constructed from CHA and double-six rings will exhibit similar vibrational modes, and that Cu cations will perturb the vibrational spectra in a similar manner. Such molecular sieves are CHA, SAPO-34, AEI and SAPO-18. Other small, medium and large molecular sieves will exhibit their own unique vibrational spectra, and Cu cations will perturb the vibrational modes in a similar manner. The copper-containing molecular sieves are prepared for example via ion-exchange from for example a Na+ containing molecular sieve (Na+ form). The Na+ form generally refers to the calcined form without any ion exchange. In this form, the molecular sieve generally contains a mixture of Na+ and H+ cations in the exchange sites. The fraction of sites occupied by Na+ cations varies depending on the specific zeolite batch and recipe. Optionally, the alkali metal molecular sieves are NH4+-exchanged and the NH4+ form is employed for ion-exchange with copper. Optionally, the NH4+-exchanged molecular sieve is calcined to the H+-form which may also be employed for ion-exchange with copper. Copper is ion-exchanged into molecular sieves with alkali metal, NH4+ or H+ forms with copper salts such as copper acetate, copper sulfate and the like, for example as disclosed in U.S. Pat. No. 9,242,238, the disclosure of which is incorporated herein by reference. For instance a Na+, NH4+ or H+ form of a molecular sieve is mixed with an aqueous salt solution and agitated at an elevated temperature for a suitable time. The slurry is filtered and the filter cake is washed and dried. Further, at least a portion of a catalytically active metal may be included during a molecular sieve synthetic process such that a tailored colloid contains a structure directing agent, a silica source, an alumina source and a metal ion (e.g. copper) source, as disclosed in U.S. Pat. No. 9,272,272, the disclosure of which is incorporated herein by reference. The total amount of copper in the molecular sieve is for example about 1.0 wt. % to about 10 wt. %, based on the total weight of the copper-containing molecular sieve. In some embodiments, the total amount of copper in the molecular sieve can be about 1.5 wt. % to about 9 wt. %, about 2.0 wt. % to about 8 wt. %, or about 3.0 wt. % to about 7 wt. %, based on the total weight of the copper-containing molecular sieve. The total amount of copper includes ion-exchanged copper and copper associated with the molecular sieve but not ion-exchanged. Amounts of copper in a molecular sieve are reported as the oxide, CuO. The total dry weight of the molecular sieve includes the any added/exchanged metals like copper. The total amount of copper in a molecular sieve, for example an aluminosilicate zeolite, may also be defined by the copper-to-aluminum atomic ratio. For example, the Cu/AI atomic ratio may be about 0.20 to about 0.50. In some embodiments, the Cu/AI atomic ratio can be about 0.25 to about 0.50, about 0.3 to about 0.50, or about 0.35 to about 0.50. The molecular sieves containing copper may each have a sodium content (reported as Na2O on a volatile free basis) of below 2 wt. %, based on the total weight of the catalyst composition. In more specific embodiments, sodium content is below 2500 ppm. The molecular sieves may each have an atomic sodium-to-aluminum ratio of less than about 0.7, for example about 0.02 to about 0.7. The molecular sieves may each have an atomic copper to sodium ratio of greater than about 0.5, for example about 0.5 to about 50. The present copper-containing molecular sieves may exhibit a BET surface area, determined according to DIN 66131, of at least about 400 m2/g, at least about 550 m2/g, or at least about 650 m2/g, for example, about 400 to about 750 m2/g or, about 500 to about 750 m2/g. The present molecular sieves may have a mean crystal size of about 10 nanometers to about 20 microns, preferably about 0.1 microns to about 2.0 microns as determined via Scanning Electron Microscopy (SEM). Advantageously, the mean crystal size is 0.5 microns or 2.0 microns. Catalytic Coating/Substrate The molecular sieves may be provided in the form of a powder or a spray-dried material which is admixed with or coated with suitable modifiers. Modifiers include silica, alumina, titania, zirconia and refractory metal oxide binders (for example a zirconium precursor). The powder or the sprayed material, optionally after admixing or coating by suitable modifiers, may be formed into a slurry, for example with water, which is deposited upon a suitable substrate as part of a catalytic coating, disclosed for example in U.S. Pat. No. 8,404,203, the disclosure of which is incorporated herein by reference. A catalytic coating contains one or more carriers containing active catalytic species. A catalytic coating may typically be applied in the form of a washcoat containing carriers having catalytically active species thereon. A washcoat is formed by preparing a slurry containing a specified solids content (e.g., 10-60% by weight) of carriers in a liquid vehicle, which is then coated onto a substrate and dried and calcined to provide a coating layer. When multiple coating layers are applied, the substrate is dried and/or calcined after each layer is applied. A final calcination step is performed after the number of desired multiple layers are applied. Coating layers of molecular sieves may be prepared using a binder, for example, a ZrO2 binder derived from a suitable precursor such as zirconyl acetate or any other suitable zirconium precursor such as zirconyl nitrate. Zirconyl acetate binder provides a catalytic coating that remains homogeneous and intact after thermal aging, for example, when the catalyst is exposed to high temperatures of at least about 600° C., for example, about 800° C. and higher, and high water vapor environments of about 5% or 10% or more. Other potentially suitable binders include, but are not limited to, alumina and silica. Alumina binders include aluminum oxides, aluminum hydroxides, and aluminum oxyhydroxides. Aluminum salts and colloidal forms of alumina many also be used. Silica binders include various forms of SiO2, including colloidal silica. Binder compositions may include any combination of zirconia, alumina, and silica. Any of present coating layers may contain ZrO2 and/or Al2O3 binders. The term “catalyst” or “catalyst composition” refers to a material that promotes a chemical reaction. The catalyst includes the “catalytically active species” and the “carrier” that carries or supports the active species. For example, molecular sieves including zeolites are carriers/supports for present copper active catalytic species. Likewise, refractory metal oxide particles may be a carrier for platinum group metal catalytic species. Present copper-containing catalysts are highly effective as selective catalytic reduction (SCR) catalysts of nitrogen oxides (NOx) to N2. Typically, a reductant such as ammonia is employed. Urea may be employed as an ammonia precursor. The catalytically active species are also termed “promoters” as they promote chemical reactions. For instance, the present copper-containing molecular sieves may be termed copper-promoted molecular sieves. A “promoted molecular sieve” refers to a molecular sieve to which catalytically active species are intentionally added. The term “substrate” refers in general to a monolithic material onto which a catalytic coating is disposed, for example a flow-through monolith or monolithic wall-flow filter. In one or more embodiments, the substrate is a ceramic or metal having a honeycomb structure. Any suitable substrate may be employed, such as a monolithic substrate of the type having fine, parallel gas flow passages extending from an inlet end to an outlet end of the substrate such that passages are open to fluid flow. The passages, which are essentially straight paths from their fluid inlet to their fluid outlet, are defined by walls on which a catalytic coating is disposed so that gases flowing through the passages contact the catalytic material. The flow passages of the monolithic substrate are thin-walled channels, which can be of any suitable cross-sectional shape and size such as trapezoidal, rectangular, square, sinusoidal, hexagonal, oval, circular, etc. Such structures may contain from about 60 to about 900 or more gas inlet openings (i.e. cells) per square inch of cross-section. Present substrates are 3-dimensional having a length and a diameter and a volume, similar to a cylinder. The shape does not necessarily have to conform to a cylinder. The length is an axial length defined by an inlet end and an outlet end. Flow-through monolith substrates for example have a volume of about 50 in3 to about 1200 in3, a cell density of about 60 cells per square inch (cpsi) to about 500 cpsi or up to about 900 cpsi, for example about 200 to about 400 cpsi and a wall thickness of about 50 to about 150 microns or about 200 microns. The substrate may be a “flow-through” monolith as described above. Alternatively, a catalytic coating may be disposed on a wall-flow diesel particulate filter (DPF), thus producing a catalyzed soot filter (CSF) or Catalyzed DPF (CDPF). If a wall-flow substrate is utilized, the resulting system will be able to remove particulate matter along with gaseous pollutants. The wall-flow filter substrate can be made from materials commonly known in the art, such as cordierite, aluminum titanate or silicon carbide. Loading of the catalytic coating on a wall-flow substrate will depend on substrate properties such as porosity and wall thickness and typically will be lower than the catalyst loading on a flow-through substrate. Wall-flow filter substrates useful for supporting the SCR catalytic coatings have a plurality of fine, substantially parallel gas flow passages extending along the longitudinal axis of the substrate. Typically, each passage is blocked at one end of the substrate body, with alternate passages blocked at opposite end-faces. Such monolithic carriers may contain up to about 700 or more flow passages (or “cells”) per square inch of cross-section, although far fewer may be used. For example, the typical carrier usually has from about 100 to about 300, cells per square inch (“cpsi”). The cells can have cross-sections that are rectangular, square, circular, oval, triangular, hexagonal, or are of other polygonal shapes. Wall-flow substrates typically have a wall thickness from about 150 microns to about 500 microns, for example from about 200 microns to about 350 microns. Wall-flow filters will generally have a wall porosity of at least 40% with an average pore size of at least 10 microns prior to disposition of the catalytic coating. For instance, wall-flow filters will have a wall porosity of from about 50 to about 75% and an average pore size of from about 10 to about 30 microns prior to disposition of a catalytic coating. FIGS. 1 and 2 illustrate an exemplary substrate 2 in the form of a flow-through substrate coated with a washcoat composition as described herein. Referring to FIG. 1, the exemplary substrate 2 has a cylindrical shape and a cylindrical outer surface 4, an upstream end face 6 and a corresponding downstream end face 8, which is identical to end face 6. Substrate 2 has a plurality of fine, parallel gas flow passages 10 formed therein. As seen in FIG. 2, flow passages 10 are formed by walls 12 and extend through carrier 2 from upstream end face 6 to downstream end face 8, the passages 10 being unobstructed so as to permit the flow of a fluid, e.g., a gas stream, longitudinally through carrier 2 via gas flow passages 10 thereof. As more easily seen in FIG. 2, walls 12 are so dimensioned and configured that gas flow passages 10 have a substantially regular polygonal shape. As shown, the washcoat composition can be applied in multiple, distinct layers if desired. In the illustrated embodiment, the washcoat consists of both a discrete bottom washcoat layer 14 adhered to the walls 12 of the carrier member and a second discrete top washcoat layer 16 coated over the bottom washcoat layer 14. The present invention can be practiced with one or more (e.g., 2, 3, or 4) washcoat layers and is not limited to the illustrated two-layer embodiment. Alternatively, FIGS. 1 and 3 can illustrate an exemplary substrate 2 in the form a wall flow filter substrate coated with a washcoat composition as described herein. As seen in FIG. 3, the exemplary substrate 2 has a plurality of passages 52. The passages are tubularly enclosed by the internal walls 53 of the filter substrate. The substrate has an inlet end 54 and an outlet end 56. Alternate passages are plugged at the inlet end with inlet plugs 58, and at the outlet end with outlet plugs 60 to form opposing checkerboard patterns at the inlet 54 and outlet 56. A gas stream 62 enters through the unplugged channel inlet 64, is stopped by outlet plug 60 and diffuses through channel walls 53 (which are porous) to the outlet side 66. The gas cannot pass back to the inlet side of walls because of inlet plugs 58. The porous wall flow filter used in this invention is catalyzed in that the wall of said element has thereon or contained therein one or more catalytic materials. Catalytic materials may be present on the inlet side of the element wall alone, the outlet side alone, both the inlet and outlet sides, or the wall itself may consist all, or in part, of the catalytic material. This invention includes the use of one or more layers of catalytic material on the inlet and/or outlet walls of the element. Catalyzed wall-flow filters are disclosed for instance in U.S. Pat. No. 7,229,597, the disclosure of which is incorporated here by reference. This reference teaches a method of applying a catalytic coating such that the coating permeates the porous walls, that is, is dispersed throughout the walls. Flow-through and wall-flow substrates are also taught for example in U.S. Pat. app. No. 62/072,687, published as WO2016/070090. The present catalytic coating may be on the wall surface and/or in the pores of the walls, that is “in” and/or “on” the filter walls. Thus, the phrase “having a catalytic coating thereon” means on any surface, for example on a wall surface and/or on a pore surface. The inlet end of a substrate is synonymous with the “upstream” end or “front” end. The outlet end is synonymous with the “downstream” end or “rear” end. A substrate will have a length and a width. The ceramic substrate may be made of any suitable refractory material, e.g. cordierite, cordierite-α-alumina, aluminum titanate, silicon carbide, silicon nitride, zircon mullite, spodumene, alumina-silica-magnesia, zircon silicate, sillimanite, a magnesium silicate, zircon, petalite, α-alumina, an aluminosilicate and the like. Substrates useful in the present invention may also be metallic, comprising one or more metals or metal alloys. The metallic substrates may be employed in various shapes such as pellets, corrugated sheet or monolithic foam. Specific examples of metallic substrates include heat-resistant, base-metal alloys, especially those in which iron is a substantial or major component. Such alloys may contain one or more of nickel, chromium, and aluminum, and the total of these metals may advantageously comprise at least about 15 wt. % (weight percent) of the alloy, for instance, about 10 to about 25 wt. % chromium, about 1 to about 8 wt. % of aluminum, and from 0 to about 20 wt. % of nickel. The catalytic coating comprises one or more thin adherent coating layers, where at least one coating layer comprises the copper-containing catalyst. The coating is disposed on and in adherence to the substrate. The entire coating comprises the individual “coating layers”. The catalytic coating may be “zoned”, comprising zoned catalyst layers. This may also be described as “laterally zoned”. For example, a first layer may extend from the inlet end towards the outlet end extending from about 10 to about 90%, about 10% to about 50%, or about 10% to about 25% of the substrate length. A second layer may extend from the outlet end towards the inlet end extending from about 10% to about 90%, about 10% to about 50%, or about 10% to about 25%
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