Produced by Jon Richfield ON LABORATORY ARTS BY RICHARD THRELFALL, M.A. PROFESSOR OF PHYSICS IN THE UNIVERSITY OF SYDNEY; MEMBER OF THE INSTITUTE OF ELECTRICAL ENGINEERS; ASSOCIATE-MEMBER OF THE INSTITUTE OF CIVIL ENGINEERS; MEMBER OF THE PHYSICAL SOCIETY London MACMILLAN AND CO, LIMITED NEW YORK: THE MACMILLAN COMPANY 1898 All rights reserved PREFACE 5 CHAPTER I 8 HINTS ON THE MANIPULATION OF GLASS AND ON GLASS-BLOWING FOR LABORATORY PURPOSES 8 § 4. Soft Soda Glass. § 6. Flint Glass. § 9. Hard or Bohemian, Glass. § 10. On the Choice of Sizes of Glass Tube. § 11. Testing Glass. § 13. Cleaning Glass Tubes. § 14. The Blow-pipe. § 18. The Table. § 19. Special Operations. § 20. Closing and blowing out the End of a Tube. § 21. To make a Weld. § 22. To weld two Tubes of different Sizes. § 24. To weld Tubes of very small Bore. § 30. To cut very thick Tubes. § 31. To blow a Bulb at the End of a Tube. § 32. To blow a bulb in the middle of a tube. § 33. To make a side Weld. § 34. Inserted Joints. § 35. Bending Tubes. § 36. Spiral Tubes. § 37. On Auxiliary Operations on Glass. § 38. Boring small Holes. § 39. For boring large holes through thick glass sheets. § 41. Operations depending on Grinding: Ground-in Joints. § 42. Use of the Lathe in Glass-working. § 46. Making Ground Glass. § 47. Glass-cutting. § 48. Cementing. § 49. Fusing Electrodes into Glass. § 51. The Art of making Air-light Joints. APPENDIX TO CHAPTER I. ON THE PREPARATION OF VACUUM TUBES FOR THE PRODUCTION OF PROFESSOR ROENTGEN'S RADIATION. CHAPTER II. GLASS-GRINDING AND OPTICIANS' WORK. § 61. Details of the Process of Fine Grinding. § 62. Polishing. § 63. Centering. § 65. Preparing Small Mirrors for Galvanometers. § 66. Preparation of Large Mirrors or Lenses for Telescopes. § 69. The Preparation of Flat Surfaces of Rock Salt. § 70. Casting Specula for Mirrors. § 71. Grinding and polishing Specula. § 72. Preparation of Flat Surfaces. § 73. Polishing Flat Surfaces on Glass or on Speculum Metal. CHAPTER III. MISCELLANEOUS PROCESSES. § 74. Coating Glass with Aluminium and Soldering Aluminium. § 75. The Use of the Diamond-cutting Wheel. § 76. Arming a Wheel. § 77. Cutting a Section. § 78. Grinding Rock Sections, or Thin Slips of any Hard Material. § 79. Cutting Sections of Soft Substances. § 80. On the Production of Quartz Threads. § 84. Drawing Quartz Threads. § 86. Drawing Threads by the Catapult. § 87. Drawing Threads by the Flame alone. § 88. Properties of Threads. § 90. On the Attachment of Quartz Fibres. § 91. Other Modes of soldering Quartz. § 92. Soldering. § 94. Preparing a Soldering Bit. § 95. Soft Soldering. § 97. Soldering Zinc. § 98. Soldering other Metals. § 99. Brazing. § 100. Silver Soldering. § 101. On the Construction of Electrical Apparatus--Insulators. § 102. Sulphur. § 103. Fused Quartz. § 104. Glass. § 105. Ebonite or Hard Rubber. § 106. Mica. § 107. Use of Mica in Condensers. § 108. Micanite. § 109. Celluloid. § 110. Paper. § 111. Paraffined Paper. § 112. Paraffin. § 113. Vaseline, Vaseline Oil, and Kerosene Oil. § 114. Imperfect Conductors. § 116. Conductors. § 117. Platinoid. § 119. Platinum Silver. § 120. Platinum Iridium. § 121. Manganin. § 122. Other Alloys. § 123. Nickelin. § 124. Patent Nickel. § 125. Constantin. 126. Nickel Manganese Copper. CHAPTER IV. ELECTROPLATING AND ALLIED ARTS. § 127. Electroplating. § 128. The Dipping Bath. § 130. Scratch-brushing. § 131. Burnishing. § 132. Silver-plating. § 133. Cold Silvering. § 134. Gilding. § 135. Preparing Surfaces for Gilding. § 136. Gilding Solutions. § 137. Plating with Copper. § 138. Coppering Aluminium. § 140. Alkaline Coppering Solution. § 141. Nickel-plating. 142. Miscellaneous Notes on Electroplating. § 143. Blacking Brass Surfaces. § 144. Sieves. § 145. Pottery making in the Laboratory. APPENDIX. PLATINISING GLASS. PREFACE EXPERIMENTAL work in physical science rests ultimately upon the mechanical arts. It is true that in a well-appointed laboratory, where apparatus is collected together in greater or less profusion, the appeal is often very indirect, and to a student carrying out a set experiment with apparatus provided to his hand, the temptation to ignore the mechanical basis of his work is often irresistible. It often happens that young physicists are to be found whose mathematical attainments are adequate, whose observational powers are perfectly trained, and whose general capacity is unquestioned, but who are quite unable to design or construct the simplest apparatus with due regard to the facility with which it ought to be constructed. That ultimate knowledge of materials and of processes which by long experience becomes intuitive in the mind of a great inventor of course cannot be acquired from books or from any set course of instruction. There are, however, many steps between absolute ignorance and consummate knowledge of the mechanical arts, and it is the object of the following pages to assist the young physicist in making his first steps towards acquiring a working knowledge of "laboratory arts." However humble the ambition may be, no one can be more keenly alive than the writer to the inadequacy of his attempt; and it is only from a profound sense of the necessity which exists for some beginning to be made, that he has had the courage to air his views on matters about which there are probably hundreds or thousands of people whose knowledge is superior to his own. Moreover, nothing has been further from the writer's mind than any idea of "instructing" any one; his desire is--if happily it may so befall--to be of assistance, especially to young physicists or inventors who wish to attain definite mechanical ends with the minimum expenditure of time. Most people will agree that one condition essential to success in such an undertaking is brevity, and it is for this reason that alternative methods as a rule have not been given, which, of course, deprives the book of any pretence to being a "treatise." The writer, therefore, is responsible for exercising a certain amount of discretion in the selection he has made, and it is hardly to be hoped that he has in all--or even in the majority of cases--succeeded in recommending absolutely the best method of procedure. This brings another point into view. Before all things the means indicated must be definite and reliable. It is for this reason that the writer has practically confined himself to matters lying within his own immediate experience, and has never recommended any process (with one or two minor exceptions, which he has noted) which he has not actually and personally carried through to a successful issue. This, although it is a matter which he considers of the highest importance, and which is his only title to a hearing, has unfortunately led to a very personal tone in the book. With regard to the arts treated of in the following pages, matters about which information is easily acquired--such as carpentering, blacksmithing, turning, and the arts of the watchmaker--have been left on one side. With regard to the last, which is of immense use in the laboratory, there happen to be at least two excellent and handy books, viz. Saunier's Watchmakers' Handbook, Tripplin, London, 1892; and Britton's Watchmakers' Dictionary and Guide. With regard to carpentering, turning, and blacksmithing, almost any one who so desires can obtain a little practical experience in any village. A short chapter has been devoted to glass-blowing, in spite of there being an excellent and handy book by Mr. Shenstone (The Methods of Glass-blowing, Rivington) on the subject already in existence. The reason for this exception lies in the fact that the writer's methods differ considerably from those advocated by Mr. Shenstone. The chapter on opticians' work has had to be compressed to an extent which is undesirable in dealing with so complex and delicate an art, but it is hoped that it will prove a sufficient introduction for laboratory purposes. In this matter the writer is under great obligations to his friend and assistant, Mr. James Cook, F.R.A.S, who gave him his first lessons in lens-making some twenty years ago. To Mr. John A. Brashear of Allegheny, Pa, thanks are due for much miscellaneous information on optical work, which is included verbatim in the text, some of it contained originally in printed papers, and some most kindly communicated to the writer for the purpose of this book. In particular, the writer would thank Mr. Brashear for his generously accorded information as to the production of those "flat" surfaces for which he is so justly famous. The writer is also indebted to Mr. A. E. Kennelly for some information as to American practice in the use of insulating material for electrical work, and to his friends Mr. J. A. Pollock and Dr. C. J. Martin for many valuable suggestions. For the illustrations thanks are due to Mrs. Threlfall and Mr. James Cook. With regard to matters which have come to the writer's knowledge by his being specifically instructed in them from time to time, due acknowledgment is, it is hoped, made in the text. With regard to the question as to what matters might be included and what omitted, the general rule has been to include information which the author has obtained with difficulty, and to leave on one side that which he has more easily attained. All the "unities" have been consistently outraged by a deliberate use of the English and metric systems side by side. So long as all the materials for mechanical processes have to be purchased to specifications in inches and feet, it is impossible to use the centimetre consistently without introducing inconvenience. However, everybody ought to, and probably does, use either system with equal facility. No attempt has been made at showing how work can be done without tools. Though, no doubt, a great deal can be done with inferior appliances where great economy of money and none of time is an object, the writer has long felt very strongly that English physical laboratory practice has gone too far in the direction of starving the workshop, and he does not wish, even indirectly, 'to give any countenance to such a mistaken policy. Physical research is too difficult in itself, and students' time is too valuable, for it to be remunerative to work with insufficient appliances. In conclusion, the writer would ask his readers to regard the book to some extent as tentative, and as a means to the procuring and organising of information bearing upon laboratory arts. Any information which can be given will be always thankfully received, and the author hereby requests any reader who may happen to learn something of value from the book to communicate any special information he may possess, so that it may be of use to others should another edition ever be called for. CHAPTER I HINTS ON THE MANIPULATION OF GLASS AND ON GLASS-BLOWING FOR LABORATORY PURPOSES § 1. THE art of glass-blowing has the conspicuous advantage, from the point of view of literary presentation, of being to a great extent incommunicable. As in the case of other delightful arts--such as those treated of in the Badminton Library, for instance--the most that can be done by writing is to indicate suitable methods and to point out precautions which experience has shown to be necessary, and which are not always obvious when the art is first approached. It is not the object of this work to deal with the art of glass-blowing or any other art after the manner befitting a complete treatise, in which every form of practice is rightly included. On the contrary, it is my wish to avoid the presentation of alternative methods. I consider that the presentation of alternative methods would, for my present purpose, be a positive disadvantage, for it would swell this book to an outrageous size; and to beginners--I speak from experience--too lavish a treatment acts rather by way of obscuring the points to be aimed at than as a means of enlightenment. The student often does not know which particular bit of advice to follow, and obtains the erroneous idea that great art has to be brought to bear to enable him to accomplish what is, after all, most likely a perfectly simple and straightforward operation. This being understood, it might perhaps be expected that I should describe nothing but the very best methods for obtaining any proposed result. Such, of course, has been my aim, but it is not likely that I have succeeded in every case, or even in the majority of cases, for I have confined myself to giving such directions as I know from my own personal experience will, if properly carried out, lead to the result claimed. In the few cases in which I have to refer to methods of which I have no personal experience, I have endeavoured to give references (usually taking the form of an acknowledgment), so that an idea of their value may be formed. All methods not particularised may be assumed by the reader to have come within my personal experience. § 2. Returning to glass-blowing, we may note that two forms of glass-blowing are known in the arts, "Pot" blowing and "Table" blowing. In the former case large quantities of fluid "metal" (technical term for melted glass) are assumed to be available, and as this is seldom the case in the laboratory, and as I have not yet felt the want of such a supply, I shall deal only with "table" blowing. Fortunately there is a convenient book on this subject, by Dr. Shenstone (Rivingtons), so that what I have to say will be as brief as possible, consistent with sufficiency for everyday work. As a matter of fact there is not very much to say, for if ever there was an art in which manual dexterity is of the first and last importance, that art is glass-working. I do not think that a man can become an accomplished glass-blower from book instructions merely--at all events, not without much unnecessary labour,--but he can learn to do a number of simple things which will make an enormous difference to him both as regards the progress of his work and the state of his pocket. § 3. The first thing is to select the glass. In general, it will suffice to purchase tubes and rods; in the case where large pieces (such as the bulbs of Geissler pumps) have to be specially prepared by pot-blowing, the student will have to observe precautions to be mentioned later on. There are three kinds of glass most generally employed in laboratories. § 4. Soft Soda Glass, obtained for the most part from factories in Thuringia, and generally used in assembling chemical apparatus.--This glass is cheap, and easily obtainable from any large firm of apparatus dealers or chemists. It should on no account be purchased from small druggists, for the following reasons:- (a) It is usually absurdly dear when obtained in this way. (b) It is generally made up of selections of different age and different composition, and pieces of different composition, even if the difference is slight, will not fuse together and remain together unless joined in a special manner. (c) It is generally old, and this kind of glass often devitrifies with age, and is then useless for blowpipe work, though it may be bent sufficiently for assembling chemical apparatus. Devitrified glass looks frosty, or, in the earlier stages, appears to be covered by cobwebs, and is easily picked out and rejected. § 5. It might be imagined that the devitrification would disappear when the glass is heated to the fusing point; and so it does to a great extent, but for many operations one only requires to soften the glass, and the devitrification often persists up to this temperature. My experience is that denitrified glass is also more likely to crack in the flame than good new glass, though the difference in this respect is not very strongly marked with narrow tubes. § 6. Flint Glass. Magnificent flint glass is made both in England and France. The English experimenter will probably prefer to use English glass, and, if he is wise, will buy a good deal at a time, since it does not appear to devitrify with age, and uniformity is thereby more likely to be secured. I have obtained uniformly good results with glass made by Messrs. Powell of Whitefriars, but I daresay equally good glass may be obtained elsewhere. For general purposes flint glass is vastly superior to the soft soda mentioned above. In the first place, it is very much stronger, and also less liable to crack when heated--not alone when it is new, but also, and especially, after it has been partly worked. Apparatus made of flint glass is less liable to crack and break at places of unequal thickness than if made of soda glass. This is not of much importance where small pieces of apparatus only are concerned, because these can generally be fairly annealed; and if the work is well done, the thickness will not be uneven. It is a different matter where large pieces of apparatus, such as connections to Geissler pumps, are concerned, for the glass has often to be worked partly in situ, and can only be imperfectly annealed. Joints made between specimens of different composition are much more likely to stand than when fashioned in soda glass. Indeed, if it is necessary to join two bits of soda glass of different kinds, it is better to separate them by a short length of flint glass; they are more likely to remain joined to it than to each other. A particular variety of flint glass, known as white enamel, is particularly suitable for this purpose, and, indeed, may be used practically as a cement. § 7, It is, however, when the necessity of altering or repairing apparatus complicated by joints arises that the advantage of flint glass is most apparent. A crack anywhere near to a side, or inserted joint, can scarcely ever be repaired in the case of soda glass apparatus, even when the glass is quite thin and the dimensions small. It should also be mentioned that flint glass has a much more brilliant appearance than soda glass. Of course, there is a considerable difference between different kinds of flint glass as to the melting point, and this may account for the divergency of the statements usually met with as to its fusibility compared with that of soda glass. The kind of flint glass made by Messrs. Powell becomes distinctly soft soon after it is hot enough to be appreciably luminous in a darkened room, and at a white heat is very fluid. This fluidity, though of advantage to the practised worker, is likely to give a beginner some trouble. § 8. As against the advantages enumerated, there are some drawbacks. The one which will first strike the student is the tendency of the glass to become reduced in the flame of the blow-pipe. This can be got over by proper adjustment of the flame, as will be explained later on. A more serious drawback in exact work is the following. In making a joint with lead glass it is quite possible to neglect to fuse the glass completely together at every point; in fact, the joint will stand perfectly well even if it be left with a hole at one side, a thing which is quite impossible with soft soda glass, or is at least exceedingly unusual. An accident of this kind is particularly likely to happen if the glass be at all reduced. Hence, if a joint does not crack when cold, the presumption is, in the case of soda glass, that the joint is perfectly made, and will not allow of any leak; but this is not the case with flint glass, for which reason all joints between flint glass tubes require the most minute examination before they are passed. If there are any air bubbles in the glass, especial care must be exercised. § 9. Hard or Bohemian, Glass. This is, of course, used where high temperatures are to be employed, and also in certain cases where its comparative insolubility in water is of importance. It is very unusual for the investigator to have to make complicated apparatus from this glass. Fused joints may be made between hard glass and flint glass without using enamel, and though they often break in the course of time, still there is no reason against their employment, provided the work be done properly, and they are not required to last too long. § 10. On the Choice of Sizes of Glass Tube. It will be found that for general purposes tubes about one-quarter inch in inside diameter, and from one-twentieth to one-fortieth of an inch thick, are most in demand. Some very thin soda glass of these dimensions (so-called "cylinder" tubes) will be found very handy for many purposes. For physico-chemical work a good supply of tubing, from one-half to three-quarters of an inch inside diameter, and from one-twentieth to one-eighth inch thick, is very necessary. A few tubes up to three inches diameter, and of various thicknesses, will also be required for special purposes. Thermometer and "barometer" tubing is occasionally required, the latter, by the way, making particularly bad barometers. The thermometer tubing should be of all sizes of bore, from the finest obtainable up to that which has a bore of about one-sixteenth of an inch. Glass rods varying from about one-twentieth of an inch in diameter up to, say, half an inch will be required, also two or three sticks of white enamel glass for making joints. To facilitate choice, there is appended a diagram of sizes from the catalogue of a reliable German firm, Messrs. Desaga of Heidelberg, and the experimenter will be able to see at a glance what sizes of glass to order. It is a good plan to stock the largest and smallest size of each material as well as the most useful working sizes. Fig. 1. § 11. Testing Glass. "Reject glass which has lumps or knots, is obviously conical, or has long drawn-out bubbles running through the substance." If a scratch be made on the surface of a glass tube, and one end of the scratch be touched by a very fine point of fused glass, say not more than one-sixteenth inch in diameter, the tube, however large it is (within reason), ought to crack in the direction of the scratch. If a big crack forms and does not run straight, but tends to turn longitudinally, it is a sign that the glass is ill annealed, and nothing can be done with it. If such glass be hit upon in the course of blow-pipe work, it is inadvisable to waste time upon it; the best plan is to reject it at once, and save it for some experiment where it will not have to be heated. The shortest way of selecting glass is to go to a good firm, and let it be understood that if the glass proves to be badly annealed it will be returned. Though it was stated above that the glass should not be distinctly conical, of course allowance must be made for the length of the pieces, and, on the other hand, a few highly conical tubes will be of immense service in special cases, and a small supply of such should be included. The glass, as it is obtained, should be placed in a rack, and covered by a cloth to reduce the quantity of dust finding its way into the tubes. It has been stated by Professor Ostwald that tubes when reared up on end tend to bend permanently. I have not noticed this with lead glass well supported. Each different supply should be kept by itself and carefully described on a label pasted on to the rack, and tubes from different lots should not be used for critical welds. This remark is more important in the case of soda than of lead glass. In the case of very fine thermometer tubes it will be advisable to cover the ends with a little melted shellac, or, in special cases, to obtain the tubes sealed from the works. Soda glass can generally be got in rather longer lengths than lead glass; the longer the lengths are the better, for the waste is less. It is useful to be able to distinguish the different kinds of glass by the colour. This is best observed by looking towards a bright surface along the whole length of the tube and through the glass. Lead glass is yellow, soda glass is green, and hard glass purple in the samples in my laboratory, and I expect this is practically true of most samples. [Footnote: Some new lead glass I have is also almost purple in hue. If any doubt exists as to the kind of glass, it may be tested at once in the blow-pipe flame, or by a mixture of oils of different refractive indices, as will be explained later.] § 12. The question of the solubility of glass in reagents is one of great importance in accurate work, though it does not always meet with the attention it deserves. It is impossible here to go into the matter with sufficient detail, and the reader is therefore referred to the Abstracts of the Chemical Society, particularly for the years 1889 and 1892. The memoir by F. Kohlrausch, Wied. Ann. xliv, should be consulted in the original. The following points may be noted. A method of testing the quality of glass is given by Mylius (C. S. J. Abstracts, 1889, p. 549), and it is stated that the resistance of glass to the action of water can generally be much increased by leaving it in contact with cold water for several days, and then heating it to 300° to 400° C. This improvement seems to be due to the formation of a layer of moist silica on the surface, and its subsequent condensation into a resisting layer by the heating. Mylius (C. S. J. Abstracts, 1892, p. 411), and Weber, and Sauer (C. S. J. Abstracts, 1892, p. 410) have also shown that the best glass for general chemical purposes consists of: Silica, 7 to 8 parts Lime, 1 part Alkali, 1.5 to 1.1 parts. This is practically "Bohemian" tube glass. The exact results are given in the Berichte of the German Chemical Society, vol. xxv. An excellent account of the properties of glass will be found in Grove's edition of Miller's Elements of Chemistry. § 13. Cleaning Glass Tubes. This is one of the most important arts in chemistry. If the tubes are new, they are generally only soiled by dust, and can be cleaned fairly easily--first by pushing a bit of cotton waste through with a cane, or pulling a rag through with string--and then washing with sand and commercial hydrochloric acid. I have heard of glass becoming scratched by this process, and breaking in consequence when heated, but have never myself experienced this inconvenience. In German laboratories little bits of bibulous paper are sometimes used instead of sand; they soon break into a pulp, and this pulp has a slightly scouring action. As soon as the visible impurities are removed and the tube when washed looks bright and clean, it may be wiped on the outside and held perpendicularly so as to allow the water film to drain down. If the tube be greasy (and perhaps in other cases) it will be observed that as the film gets thinner the water begins to break away and leave dry spots. For accurate work this grease, or whatever it is, must be removed; and after trying many plans for many years, I have come back to the method I first employed, viz. boiling out with aqua regia. For this purpose, close one end of the tube by a cork (better than a rubber bung, because cheaper), and half fill the tube with aqua regia; then, having noted the greasy places, proceed to boil the liquid in contact with the glass at these points, and in the case of very obstinate dirt--such as lingers round a fused joint which has been made between undusted tubes--leave the whole affair for twelve hours. If the greasiness is only slight, then simply shaking with hot aqua regia will often remove it, and the aqua regia is conveniently heated in this case by the addition of a little strong sulphuric acid. The spent aqua regia may be put into a bottle. It is generally quite good enough for the purpose of washing glass vessels with sand, as above explained. However carefully a tube is cleaned before being subjected to blowpipe operations, it will be fouled wherever there is an opening during the process of heating, unless the extreme tip only of an oxidising flame be employed. Even this should not be trusted too implicitly unless an oxygas or hydrogen flame is employed. When a tube or piece of apparatus has been cleaned by acid, so that on clamping it vertically, dry spaces do not appear, it may be rinsed with platinum distilled water and left to drain, the dust being, of course, kept out by placing a bit of paper round the top. For accurate work water thus prepared is to be preferred to anything else. When the glass is very clean interference colours will be noticed as the water dries away. Carefully-purified alcohol may in some cases be employed where it is desired to dry the tube or apparatus quickly. In this case an alcohol wash bottle should be used, and a little alcohol squirted into the top of the tube all round the circumference. The water film drags the alcohol after it, and by waiting a few minutes and then adding a few more drops of alcohol, the water may be practically entirely removed, especially if a bit of filter paper be held against the lower end of the tube. It is customary in some laboratories to use ether for a final rinse, but unless the ether is freshly distilled and very pure, it leaves a distinct organic residue. When no more liquid can be caused to drain away, the tube may be dried by heating it along its length, beginning at the top (to get the advantage of the reduction of surface tension), and so on all down. It will then be possible to mop up a little more of the rinsing liquid. When the tube is nearly dry a loose plug of cotton wool may be inserted at the bottom. The wool must be put in so that the fibres lie on an even surface inside the tube, and the wool must be blown free from dust. Ordinary cotton wool is useless, from being dusty and the fibres short, and the same remark applies to wadding. Use nothing but what is known as "medicated" cotton wool with a good long fibre. The tube will usually soon dry of itself when the cover is lifted an inch or so. If water has been used, the air-current may be assisted by means of the water-pump, the air being sucked from the top, so that the wool has an opportunity of acting as a dust filter; a very slow stream of air only must be employed. For connecting the tube to the pump, a bit of India-rubber tube about an inch in diameter, with a bore of about one-eighth of an inch, may be employed. The end of the rubber tube is merely pressed against the edge of the glass. These remarks apply, with suitable modification, to all kinds of finished apparatus having two openings. For flasks and so on, it is convenient to employ a blowing apparatus, dust being avoided by inserting a permanent plug of cotton wool in one of the leading tubes. The efficiency of this method is greatly increased by using about one foot of thin copper tube, bent into a helix, and heated by means of a Bunsen burner; the hot air (previously filtered) is passed directly into the flask, bottle, or whatever the apparatus may be. This has proved so convenient that a copper coil is now permanently fastened to the wall in one of the rooms of my laboratory. The above instructions indicate greater refinement than is in general necessary or proper for tubes that have to be afterwards worked by the blow-pipe. In the majority of cases all that is necessary is to remove the dust, and this is preferably done by a wad of cotton waste (which does not leave shreds like cotton wool), followed by a bit of bibulous filter paper. I would especially warn a beginner against neglecting this precaution, for in the process of blowing, the dust undergoes some change at the heated parts of the apparatus, and forms a particularly obstinate kind of dirt. In special cases the methods I have advocated for removing dirt and drying without covering the damp surfaces with dust are inadequate, but an experimenter who has got to that stage will have nothing to learn from such a work as this. § 14. The Blow-pipe. I suppose a small book might easily be written on this subject but what I have to say--in accordance with the limitation imposed--will be brief. For working lead glass I never use anything but an oxygas blow-pipe, except for very large work, and should never dream of using anything else. Of course, to a student who requires practice in order to attain dexterity this plan would be a good deal too dear. My advice to such a one is--procure good soda glass, and work it by means of a modification of a gas blow-pipe, to be described directly. The Fletcher's blow-pipes on long stems are generally very inconvenient. The flame should not be more than 5 or 6 inches from the working table at most, especially for a beginner, who needs to rest his arms on the edge of the table to secure steadiness. The kind of oxygas blow-pipe I find most convenient is indicated in the sketch. (Fig. 2) I like to have two nozzles, which will slip on and off, one with a jet of about 0.035 inch in diameter, the other of about double this dimension. The oxygen is led into the main tube of the blow-pipe by another tube of much smaller diameter, concentric with the main tube (Fig. 3, at A). The oxygen is mixed with the gas during its escape from the inner tube, which is pierced by a number of fine holes for the purpose, the extreme end being closed up. The inner tube may run up to within half an inch of the point where the cap carrying the nozzle joins the larger tube. Fig. 2. Fig. 3. If it is desired to use the blow-pipe for working glass which is already fixed in position to a support, it will be found very advantageous to use a hooked nozzle. The nozzle shown in the sketch is not hooked enough for this work, which requires that the flame be directed 'backwards towards the worker. With a little practice such a flame may be used perfectly well for blowing operations on the table, as well as for getting at the back of fixed tubes. To warm up the glass, the gas supply is turned full on, and enough oxygen is allowed to pass in to clear the flame. The work is held in front of, but not touching, the flame, until it is sufficiently hot to bear moving into the flame itself. The, work is exposed to this flame until, in the case of lead glass, traces of reduction begin to appear. When this point is reached the oxygen tap is thrown wide open. I generally regulate the pressure on the bags, so that under these circumstances the flame is rather overfed with oxygen. This condition is easily recognised, as follows. The flame shrinks down to a very small compass, and the inner blue cone almost disappears; also flashes of yellow light begin to show themselves--a thing which does not occur when the proportions of the gases are adjusted for maximum heating effect. For many purposes the small dimensions of the flame render it very convenient, and the high temperature which can be attained at exact spots enables glass to be fused together after a certain amount of mixing, which is an enormous advantage in fusing lead glass on to hard glass. The lead glass should not be heated hot enough to burn, but, short of this, the more fluid it is the better for joints between dissimilar samples. It will be noticed that the blow-pipe can be rotated about a vertical axis so as to throw the flame in various directions. This is often indispensable. § 15. In general the oxygen flame does not require to be delivered under so high a pressure as for the production of a lime light. In England, I presume, most experimenters will obtain their oxygen ready prepared in bottles, and will not have to undergo the annoyance of filling a bag. If, however, a bag is used, and it has some advantages (the valves of bottles being generally stiff), I find that a pressure produced by placing about two hundredweight (conveniently divided into four fifty-six pound weights) on bags measuring 3' x 2'6" x 2' (at the thicker end) does very well. To fill such a bag with oxygen, about 700 grms of potassium chlorate is required. If the experimenter desires to keep his bag in good order, he must purify his oxygen by washing it with a solution of caustic soda, and then passing it through a "tower" of potash or soda in sticks, and, finally, through a calcium chloride tower. This purifying apparatus should be permanently set up on a board, so that it may be carried about by the attendant to wherever it is required. Oxygen thus purified does not seem to injure a good bag--at least during the first six or seven years: In order to reduce the annoyance of preparing oxygen, the use of the usual thin copper conical bottle should be avoided. The makers of steel gas bottles provide retorts of wrought iron or steel for oxygen-making, and these do very well. They have the incidental advantage of being strong enough to resist the attacks of a servant when a spent charge is being removed. The form of retort referred to is merely a large tube, closed at one end, and with a screw coupling at the other; the dimensions may be conveniently about 5 inches by 10. The screw threads should be filled with fireclay (as recommended by Faraday) before the joint is screwed up. Before purchasing a bottle the experimenter will do well to remember that unless it is of sufficiently small diameter to go into his largest vice, he will be inconvenienced in screwing the top on and off. Why these affairs are not made with union joints, as they should be, is a question which will perhaps be answered when we learn why cork borers are still generally made of brass, though steel tube has long been available. Fig. 4. These little matters may appear very trivial--and so they are--but the purchaser of apparatus will generally find that unless he looks after details himself, they will not be attended to for him. Whether a union joint is provided or not, let it be seen that the end of the delivery tube is either small enough to fit a large rubber tube connection going to the wash-bottle, or large enough to allow of a cork carrying a bit of glass tube for the same purpose to be inserted. This tube should not be less than half an inch in inside diameter. Never use a new bottle before it has been heated sufficiently to get rid of grease and carbonaceous dirt. A convenient oxygen-making apparatus is shown in Fig. 4, which is drawn from "life." § 16. For large blow-pipe work with lead glass I recommend a system of four simple blow-pipes, in accordance with the sketch annexed. I first saw this system in operation in the lamp factory of the Westinghouse Electric Company at Pittsburg in 1889, and since then I have seen it used by an exceedingly clever "trick" glass-worker at a show. After trying both this arrangement and the "brush flame" recommended by Mr. Shenstone, I consider the former the more convenient; however, I daresay that either can be made to work in competent hands, but I shall here describe only my own choice. [Footnote: A brush flame is one which issues from the blow-pipe nozzle shaped like a brush, i.e. it expands on leaving the jet. It is produced by using a cylindrical air jet or a conical jet with a large aperture, say one-eighth of an inch. See Fig. 25.] As will be seen, the blow-pipe really consists of four simple brass tube blow-pipes about three-eighths of an inch internal diameter and 3 inches long, each with its gas and air tap and appropriate nozzle. Each blowpipe can turn about its support (the gas-entry pipe) to some extent, and this possibility of adjustment is of importance, The air jets are merely bits of very even three-sixteenths inch glass tubing, drawn down to conical points, the jets themselves being about 0.035 inch diameter. Fig. 5. The flames produced are the long narrow blow-pipe flames used in blow-pipe analysis, and arranged so as to consist mostly of oxidising flame. The air-supply does not require to be large, nor the pressure high--5 to 10 inches of water will do--but it must be very regular. The "trick" glass-blower I referred to employed a foot bellows in connection with a small weighted gasometer, the Westinghouse Company used their ordinary air-blast, and I have generally used a large gas-holder with which I am provided, which is supplied by a Roots blower worked by an engine. I have also used a "velocity pump" blower, which may be purchased amongst others from Gerhardt of Bonn. The arrangement acts both as a sucking and blowing apparatus, and is furnished with two manometers and proper taps, etc. As I have reason to know that arrangements of this kind work very ill unless really well made, I venture to add that the Gerhardt arrangement to which I refer is No. 239 in his catalogue, and costs about three pounds. It hardly gives enough air, however, to work four blow-pipes, and the blast requires to be steadied by passing the air through a vessel covered with a rubber sheet. In default of any of these means being available, one of Fletcher's foot-blowers may be employed, but it must be worked very regularly. A table mounted with one blow-pipe made on this plan, and worked by a double-acting bellows, is recommended for students' use. For working flint glass, the air jet may be one-eighth of an inch in diameter and the pressure higher--this will give a brush flame. See Fig. 25. It will be seen, on looking at the sketch of the blowpipe system, that the pair of blow-pipes farther from the observer can be caused to approach or recede at will by means of a handle working a block on a slide. It often happens that after using all four blow-pipes at once it is necessary to have recourse to one blow-pipe only, and to do this conveniently and quickly is rather an object. Now, in my arrangement I have to turn off both the gas and air from the farther system, and then put in a bit of asbestos board to prevent the nozzles being damaged by the flame or flames kept alight. As I said before, when some experience is gained, glassblowing, becomes a very simple art, and work can be done under circumstances so disadvantageous that they would entirely frustrate the efforts of a beginner. This is not any excuse, however, for recommending inferior arrangements. Consequently, I say that the pipes leading in gas and air should be all branches of one gas and one air pipe, in so far as the two remote and one proximate blow-pipe are concerned, and these pipes should come up to the table to the right hand of the operator, and should have main taps at that point, each with a handle at least 2 inches long. By this arrangement the operator can instantly turn down all the blow-pipes but one, while, if the inverse operation is required, all the three pipes can be started at once. [Footnote: I find, since writing the above, that I have been anticipated in this recommendation by Mr. G. S. Ram, The Incandescent Lamp and its Manufacture, p. 114.] The separate air and gas taps must be left for permanent regulation, and must not be used to turn the supply on or cut it off. In some respects this blow-pipe will be found more easy to manage than an oxygas blow-pipe, for the glass is not so readily brought to the very fluid state, and this will often enable a beginner who proceeds cautiously to do more than he could with the more powerful instrument. Though I have mentioned glass nozzles for the air supply, there is no difficulty in making nozzles of brass. For this purpose let the end of a brass tube of about one-eighth of an inch diameter be closed by a bit of brass wire previously turned to a section as shown (Fig. 6), and then bored by a drill of the required diameter, say -.035 inch. It is most convenient to use too small a drill, and to gradually open the hole by means of that beautiful tool, the watchmaker's "broach." The edges of the jet should be freed from burr by means of a watchmaker's chamfering tool (see Saunier's Watchmaker's Hand-book, Tripplin, 1882, p. 232, § 342), or by the alternate use of a slip of Kansas stone and the broach. Fig. 6. The construction of this blow-pipe is so simple, that in case any one wishes to use a brush flame, he can easily produce one simply by changing his air jets to bits of the same size (say one-eighth to one-sixteenth of an inch) tubing, cut off clean. To insure success, the ends of the tubes must be absolutely plane and regular; the slightest inequality makes all the difference in the action of the instrument. If a jet is found to be defective, cut it down a little and try again; a clean-cut end is better than one which has been ground flat on a stone. The end of a tube may, however, be turned in a manner hereafter to be described so as to make an efficient jet. Several trials by cutting will probably have to be made before success is attained. For this kind of jet the air-pressure must be greatly increased, and a large Fletcher's foot-blower or, better still, a small double-action bellows worked with vigour will be found very suitable. A fitting for this auxiliary blow-pipe is shown in Fig. 5 at B. Professor Roentgen's discovery has recently made it necessary to give more particular attention to the working of soft soda glass, and I have been obliged to supplement the arrangements described by a table especially intended for work with glass of this character. The arrangement has proved so convenient for general work that I give the following particulars. The table measures 5 feet long, 2 feet 11 inches wide, and is 2 feet 9 inches high. Fig. 7. It is provided with a single gas socket, into which either a large or small gas tube may be screwed. The larger tube is 5.5 inches long and 0.75 of an inch in diameter. The smaller tube is the same length, and half an inch in diameter. The axis of the larger tube is 3.5 inches above the table at the point of support, and is inclined to the horizontal at an angle of 12°. The axis of the smaller tube is 2.5 inches above the surface of the table, and is inclined to the horizontal at the same angle as the larger one. The air jets are simply pieces of glass tube held in position by corks. The gas supply is regulated by a well-bored tap. The air supply is regulated by treading the bellows--no tap is requisite. The bellows employed are ordinary smiths' bellows, measuring 22 inches long by 13 inches wide in the widest part. They are weighted by lead weights, weighing 26 lbs. The treadle is connected to the bellows by a small steel chain, for the length requires to be invariable. As the treadle only acts in forcing air from the lower into the upper chamber of the bellows, a weight of 13 lbs. is
{'title': 'On Laboratory Arts by Richard Threlfall', 'source': 'Project Gutenberg', 'lang': 'en'}