CREATE TABLE table_79872 ("Pick #" TEXT, "Player" TEXT, "Position" TEXT, "Nationality" TEXT, "NHL team" TEXT, "College/junior/club team" TEXT)

Which Pick # has an NHL team of detroit red wings?
SELECT "Pick #" FROM table_79872 WHERE "NHL team" = 'detroit red wings'
SELECT "Pick #" FROM "table_79872" WHERE "NHL team" = 'detroit red wings'