CREATE TABLE table_45114 ("Res." CLOB, "Record" CLOB, "Opponent" CLOB, "Method" CLOB, "Round" FLOAT, "Time" CLOB, "Location" CLOB)

What is the method when the time was 5:00, and the round higher than 4?
SELECT "Method" FROM table_45114 WHERE "Time" = '5:00' AND "Round" > '4'
SELECT "Method" FROM "table_45114" WHERE "Round" > '4' AND "Time" = '5:00'