One of the benefits of the web of trust, such as in PGP, is that it can interoperate with a PKI CA fully trusted by all parties in a domain (such as an internal CA in a company) that is willing to guarantee certificates, as a trusted introducer.
Another alternative, which does not deal with public authentication of public key information, is the simple public key infrastructure (SPKI) that grew out of three independent efforts to overcome the complexities of X.509 and PGP's web of trust.