Roughly, fluoride volatility can be used to remove elements with a valence of 5 or greater: uranium, neptunium, plutonium, metalloids (tellurium, antimony), nonmetals (selenium), halogens (iodine, bromine), and the middle transition metals (niobium, molybdenum, technetium, ruthenium, and possibly rhodium).
Left behind are alkali metals (caesium, rubidium), alkaline earth metals (strontium, barium), lanthanides, the remaining actinides (americium, curium), remaining transition metals (yttrium, zirconium, palladium, silver, cadmium) and other metals (tin, indium).