Having married by proxy in Madrid on 12 April 1750 she was married in person at Oulx on 31 May 1750[REF] to Victor Amadeus, "Duke of Savoy", the eldest son of Charles Emmanuel III of Sardinia and his late wife Polyxena of Hesse-Rotenburg.
At the death of her father-in-law Charles Emmanuel III of Sardinia in 1773, her husband succeeded him as Victor Amadeus III.