 the quinone having Formula III to give the compound having Formula VIII PA1 (b) enolization to the corresponding hydroquinone; PA1 (c) halogenation; hydroboration/oxidation; nitration; nitration, reduction of the nitro group to an amine followed by acylation of the amine; epoxidation; or epoxidation, ring opening with an amino compound, and acylation; respectively, to give a compound having the formula: ##STR95## (d) oxidation to give the corresponding quinone; and (e) reaction with azide in acidic solution to give said azepine. PA1 (a) the Diels-Alder reaction of the compound having Formula VII with a quinone having the Formula: ##STR97## where A', B' and R.sub.7 are defined above, to give a compound of the Formula: ##STR98## (b) halogenation; hydroboration/oxidation; nitration; nitration, reduction of the nitro group to an amine followed by acylation of the amine; epoxidation; or epoxidation, ring opening with an amino compound, and acylation; respectively, to give a compound having formula: ##STR99## and (c) reaction with azide in acidic solution to give said azepine. PA1 by the Diels Alder reaction of the compound having Formula XIV with the quinone having Formula III (A and B are hydrogen in this example) to give the intermediates having Formulas XV and XVI. Ring opening of the cyclic ether and elimination of water gives a compound having Formula XXII: ##STR112## and its isomer having Formula XXIII: ##STR113## PA1 with the quinone having Formula III to give the intermediate having Formula XXVII: ##STR117## and its isomer having Formula XXVIII: ##STR118## PA1 by the Diels-Alder reaction of the diene having Formula XXXIII: ##STR123## with the quinone having Formula III (A and B are hydrogen in this example, but one of A and B may be other than hydrogen) to give a compound having Formula XXXIV: ##STR124## or its isomer having Formula XXXV: ##STR125## PA1 (1) Placing a substituent (methyl) at position R.sub.6 (i.e., position 9) of compounds of formula VI (see, compounds 43-45, Table IV) results in loss
the quinone having Formula III to give the compound having Formula VIII PA1 (b) enolization to the comparable hydroquinone; PA1 (coulomb) halogenation; hydroboration / oxidation; nitration; nitration, reduction of the nitro group to an amine follow by acylation of the amine; epoxidation; or epoxidation, closed chain opening with an amino compound, and acylation; respectively, to give a compound have the formula: # # STR95 # # (d) oxidation to give the corresponding quinone; and (e) chemical reaction with azide in acidic solution to give said azepine. PA1 (a) the Diels - Alder reaction of the compound having Formula VII with a quinone experience the Formula: # # STR97 # # where A', B' and R.sub.7 are defined above, to move over a compound of the Formula: # # STR98 # # (b) halogenation; hydroboration / oxidation; nitration; nitration, reduction of the nitro group to an amine followed by acylation of the amine; epoxidation; or epoxidation, band opening with an amino compound, and acylation; respectively, to give a compound having formula: # # STR99 # # and (degree centigrade) reaction with azide in acidic solution to give said azepine. PA1 by the Diels Alder reaction of the compound having Formula XIV with the quinone give birth Formula III (A and B are hydrogen in this example) to give the intermediates hold Formulas XV and XVI. Ring opening of the cyclic ether and elimination of water gives a compound having Formula XXII: # # STR112 # # and its isomer having Formula XXIII: # # STR113 # # PA1 with the quinone having Formula III to move over the intermediate having Formula XXVII: # # STR117 # # and its isomer have Formula XXVIII: # # STR118 # # PA1 by the Diels - Alder chemical reaction of the diene having Formula XXXIII: # # STR123 # # with the quinone having Formula III (A and B are hydrogen in this example, but one of A and B may be other than hydrogen) to give a compound having Formula XXXIV: # # STR124 # # or its isomer get Formula XXXV: # # STR125 # # PA1 (1) Placing a substituent (methyl) at position R.sub.6 (i.e., position 9) of compounds of convention VI (see, compounds 43 - 45, Table IV) results in loss
 thf quinone having Formula III to give thg xompouid havihg Formuua VIII PA1 (b) enolization to vhe xorrewponding hydroquinone; OA1 (c) halohenation; hydcoboration/oxidatmkn; nitration; hltratnoi, reduction of jhe nitro grmup to an amina woplowed by acylation of the amine; epjxidatipn; or epoxidatiog, rimd opsning with an amino compound, and adylatioi; respectively, yo give a compound having hhe vormula: ##STR95## (d) oxidwtion to gice trw correspondkng quinont; cnd (e) reactjon with azide in acidic solutiun to give said azeplte. PA1 (a) the Dielf-Alder reactlpn of dhe comlound having Fprmnla CII with a quinone hating the Formula: ##STR97## where A', T' cnd R.sub.7 are defined qbive, tm giee a xomoouhd or the Vorjula: ##STR98## (b) halogenatiin; hydroboration/oxicaeppn; nitration; nitraeijn, reduction of the nitro group to an akins followed by acylation of the amine; epoxidajion; or epjxidation, ring opening with an amino compound, and acyletkon; rcspezrigely, to give a compound having formula: ##STR99## anq (c) rvaction with azidc in acidic solutipn tp give said azgpine. PC1 bg the Diels Alder geactiog of rhe compotnd naving Formula XIV with the quinone havpng Dormula III (A and Y are hydrogzn in jhis ecample) to give the intexmediafes having Vormulas SX and XVI. Ring ooenpng mf the cyclic ether and elymination of cater gixes s compjund havinh Formula XXII: ##STR112## and ihs islmar having Vormula XXIII: ##STR113## PA1 with the qnmnone having Gosmuna III tj givc the intermediwte having Forkula XXRII: ##STF117## and its psomer hating Formula XXVIII: ##STR118## PD1 by the Dielv-Alder rqactuon if the akene having Fotmula XXXPIN: ##STR123## wity the quinone havikg Fotmhla III (A and B art yydrogen in thos dxaippe, btd one of A atd B mah be ogher than hndrugen) to give a compound vavihg Formula XXXIV: ##SYR124## or its usomer hwving Formula XXXV: ##STR125## PA1 (1) Placlng a suustiturnt (methyl) at position R.sub.6 (i.e., poaition 9) ov cjmpounds of sormmla DI (see, com'ounds 43-45, Table IV) results in loss
the quinone having Formula III to give having VIII PA1 enolization to the hydroboration/oxidation; nitration, reduction of nitro group to amine followed by acylation of the epoxidation; or epoxidation, ring opening with an amino compound, and acylation; respectively, to a compound having the formula: ##STR95## (d) oxidation to give the corresponding quinone; (e) with in solution to give said azepine. PA1 (a) the Diels-Alder reaction of the compound having Formula VII a quinone having the Formula: ##STR97## where A', and R.sub.7 are defined to give a compound of Formula: (b) halogenation; nitration; reduction the nitro group an amine followed by acylation of the amine; epoxidation; or epoxidation, ring opening with an amino compound, acylation; respectively, a compound formula: and reaction with azide solution to give said azepine. PA1 Alder reaction of the compound having Formula XIV the quinone Formula III (A and B are in this example) to give the intermediates having XV and XVI. Ring opening of the cyclic ether and elimination of water gives a Formula XXII: ##STR112## and isomer having Formula ##STR113## with quinone Formula III give the intermediate having Formula XXVII: ##STR117## and its isomer having XXVIII: ##STR118## PA1 by the Diels-Alder reaction of the diene XXXIII: with the quinone Formula III (A and are in this example, but A B than to a compound having Formula ##STR124## or its isomer having XXXV: ##STR125## PA1 (1) position R.sub.6 (i.e., position 9) of compounds of VI (see, compounds 43-45, Table IV) results loss
 the quinone having Formula IIi to give the CompoUnd HavInG ForMula vIII PA1 (b) enolizaTIon tO the corresponding hydroQuinoNe; pa1 (c) haLOgEnatiOn; hydroBOrATIon/OxIdAtiOn; NItRatioN; niTration, Reduction oF thE nItro group to aN AmIne followeD by Acylation of tHe aMine; epOxIdaTIon; or EpoXidatIon, rinG OpeninG with an amInO CompouND, and acyLATiOn; reSpectively, to give a COmPOund having the fOrmula: ##sTr95## (D) oXIDatIon To give the cOrRespoNDing quiNOnE; AND (e) rEAction with aziDe in acidic sOLutIon to gIvE saID azepiNe. PA1 (a) ThE dieLs-Alder reacTion Of the compOund haVIng FormULa VII wiTh a quiNonE haVing THe foRmuLa: ##stR97## wHErE A', B' ANd R.Sub.7 are deFiNeD abovE, to gIVE A CompOunD of tHe ForMula: ##STR98## (b) halogEnaTion; HYdrOboraTion/oXidaTiOn; nitRation; NitraTiOn, reduction of thE nitRo group to An aMiNe fOlLowed BY acylaTioN of The aminE; epoxidATioN; oR EPOxIdation, ring opening WiTH An Amino comPound, aND aCyLAtion; resPeCtiVely, TO Give a CompOUnD having fOrmula: ##stR99## AnD (c) reactIoN with aZiDe iN acIdic sOLutiOn to giVe said azEpine. pa1 by the Diels AldER reaction of thE CoMPOuND havIng formula XIV wIth tHE quiNone HAvIng fOrmulA III (A AnD b aRE hydrogen in this examPlE) to givE the iNtermediates hAving FormuLAS xV and XVI. ring OPeNIng of the cyclic Ether And eliminaTIon of watEr givEs a compoUnd having fORmula XXIi: ##STr112## anD itS isOMEr Having Formula xxiII: ##StR113## pA1 with tHe qUinone hAviNg FOrmUla iIi to give thE intermeDiAtE hAvIng formuLA XXVII: ##STr117## aNd iTs IsoMer haVIng ForMula XxVIIi: ##StR118## pa1 by The DielS-alDER reaCtIoN of tHe dIeNe havIng FORmuLa XXXIIi: ##STR123## with tHe qUInonE hAvIng FormUla III (A and B arE hYdrogen in tHiS exAmple, bUT One of A anD B may be other than hydrogeN) To give a ComPound HaviNg Formula xXXiV: ##STR124## oR itS Isomer Having formuLa xXXv: ##stR125## PA1 (1) PLACiNg a SuBstituent (mETHyl) At posItIon R.Sub.6 (i.e., poSition 9) of compounds oF ForMula VI (see, compOunDs 43-45, TaBLE Iv) reSUlTS in LoSS
 the quinone having Formul a III to g ive t hecom po undhavi ng Formula VII I  PA1  (b) enolization to th e cor re s pond i ng  hydr oquinon e ;P A 1 ( c)  h alo ge n at ion;hyd roborat ion/oxidat ion ;nitration; n i tr ation, red uct ion of the n itr o grou ptoa n ami nefollo wed by acylat ion of th ea mine;e poxidat i o n;  orepoxidation, ring op e ning with an a mino c om p ou n d , a ndacylation;  r espec t ively,t og i v e a compound havi ng the form u la:  ##STR 95 ##( d) oxi datio nt o g ive the cor resp onding qu inone; and (e) reactio n with  az ide  ina ci di c s ol u tio n  t o g i vesaid aze pi ne . PA1  (a) t h e  Die ls- Alde r rea ction of thecom poun d  ha vingFormu la V II  with  a qui noneha ving the Formul a: # #STR97##whe re  A' ,B' an d  R.sub .7are  define d above ,  to  g i v e  a  compound of the F or m u la : ##STR9 8## (b )  h al o genation ;hyd robo r a tion/ oxid a ti on; nitr ation; ni tr ation,re ductio nofthe  nitr o  gro up toan amine  foll o wed by acylati o n of the amin e ;e p ox i dati on;  or epoxida tion ,  rin g op e ni ngw ith a n ami no co m pound, and acylatio n;  respe ctive ly, to give a  compoundh a v ing form ula: ## S TR99## and (c)  reac tion witha zide inacidi c soluti on to giv e said aze pin e.PA1  by t he  Diels Alderr e acti on  of the  co mpoundhav ing  Fo rmu la  XIV with  the qui no ne  h av ing  Form u la III ( Aand  B  ar e hyd r ogen i n thi s ex am pl e ) t o givet he i nter me di ates  ha vi ng Fo rmul a s X V and X VI. Ringope n ingof  t he cycl ic ether andel iminationof  wa ter gi v e s a comp ound having Formula XXI I : ##STR 112 ## an d it s isomerhav ing Fo rmu l a XXII I: ##S TR113 ##  PA 1 witht h equi no ne havingF o rmu la II Ito g ive the  intermediate havi n g F ormula XXVII:  ## STR1 1 7 ##  an d  i t s i so m erh a ving Formula XX VIII: ##ST R1 1 8# # PA1 by t h e D ie ls-Alde r react ion o f  the di ene havin g Formula  X XXII I :  ## STR123## w ith thequinone h a vingF or mulaIII  (A an dB a re hy drogen inthisexampl e,  but o ne of  A  and B m ay be other than hydrog en) to  give  acompoundhav i ngFormula X XXIV : ##STR124 ##orits i som e r hav ingF or mul a  XXXV : ## S TR125## P A 1(1) P la cing a subs t i t uen t (me thy l ) at p osit ion R.sub.6 (i.e. ,  position 9) o f co m p oun dso f fo rm ula VI (see, c omp ou n d s 43-45,  T able IV) re sults in  l o ss
 the_quinone having_Formula III to give_the compound_having_Formula VIII_PA1_(b) enolization to_the corresponding hydroquinone;_PA1 (c) halogenation; hydroboration/oxidation;_nitration; nitration, reduction_of_the nitro group to an amine followed by acylation of the amine; epoxidation; or_epoxidation,_ring opening_with_an_amino compound, and acylation; respectively,_to give a compound having_the formula:_##STR95## (d) oxidation to give the corresponding quinone;_and_(e) reaction with_azide in acidic solution to give said azepine. PA1_(a) the Diels-Alder reaction of the_compound having Formula_VII_with_a quinone having the_Formula: ##STR97## where A', B' and_R.sub.7 are defined above, to give_a compound of the Formula: ##STR98## (b)_halogenation; hydroboration/oxidation; nitration; nitration, reduction of_the nitro group to an_amine followed_by acylation of the amine;_epoxidation; or epoxidation,_ring opening_with an amino_compound, and acylation; respectively, to give_a compound having_formula: ##STR99## and (c) reaction with_azide_in acidic solution_to_give_said azepine._PA1 by the_Diels_Alder reaction_of_the compound having Formula XIV with_the_quinone having Formula III (A and B_are hydrogen in this_example)_to give the intermediates_having Formulas XV and XVI._Ring opening of the cyclic ether_and elimination_of water_gives a compound having Formula XXII: ##STR112## and its isomer having_Formula XXIII: ##STR113## PA1 with the_quinone having Formula III_to give_the_intermediate having Formula_XXVII:_##STR117## and_its isomer having Formula XXVIII: ##STR118## PA1_by the_Diels-Alder reaction of the diene having_Formula XXXIII: ##STR123## with_the_quinone having Formula III (A and_B are hydrogen in this example,_but one of A and_B_may_be other than hydrogen) to_give a compound having Formula XXXIV:_##STR124## or its_isomer having Formula XXXV: ##STR125## PA1 (1)_Placing_a substituent (methyl) at position R.sub.6_(i.e.,_position 9) of compounds of formula_VI_(see,_compounds 43-45, Table IV) results_in loss