Thiosulfoxides are orthogonally isomeric with disulfides, having the second sulfur branching from the first and not partaking in a continuous chain, i.e. >S=S rather than −S−S−.
Thiosulfoxides are orthogonally isomeric with disulfides, having t?he second sulfur branching from the first and not partaking in a conti.nuous chain, i.e. >S=S rather than −S−S−.