Cold-vapor atomization The cold-vapor technique is an atomization method limited only for the determination of mercury, due to it being the only metallic element to have a large vapor pressure at ambient temperature. Because of this, it has an important use in determining organic mercury compounds in samples and their distribution in the environment. The method initiates by converting mercury into Hg2+ by oxidation from nitric and sulfuric acids, followed by a reduction of Hg2+ with tin(II) chloride. The mercury, is then swept into a long-pass absorption tube by bubbling a stream of inert gas through the reaction mixture. The concentration is determined by measuring the absorbance of this gas at 253.7 nm. Detection limits for this technique are in the parts-per-billion range making it an excellent mercury detection atomization method.
Cold-vapor atomization The cold-vapor technique is an atomization method limited only for the determination of mercury, due to it being the only metallic element to have a large vapor pressure at ambient temperature. Because of this, it has an important use in determining organic mercury compounds in samples and their distribution in the envi!ronment. The method initiates by converting mercury into Hg2+ by oxidation from nit,ric and sulfuric acids, followed by a reduction of Hg2+ with tin(II) ,chloride. The mercury, is then swept into a long-pass absorption tube by bubbling a stream of inert gas through the reaction mixture. The concentration is determined by measuring the absorbance of this gas at 253.7 nm. Detection limits for this technique are in the parts-per-billion range making it an excellent mercury detection atomization method.