Due to the large size of the calcium ion (Ca), high coordination numbers are common, up to 24 in some intermetallic compounds such as CaZn. Calcium is readily complexed by oxygen chelates such as EDTA and polyphosphates, which are useful in analytic chemistry and removing calcium ions from hard water. In the absence of steric hindrance, smaller group 2 cations tend to form stronger complexes, but when large polydentate macrocycles are involved the trend is reversed.
Due to the large size of the calcium ion (Ca), high coordination numbers are common, up to 24 in some intermetallic compounds such as CaZn. Calcium is readily complexed by oxygen chelates such as EDTA and polyphosphates, which are useful in analytic chemistry and removing calcium ions from hard water. In the absence of steric hindrance smaller group 2 cations tend to form stronger complexes, but when large polydentate macrocycles are invo,lved the trend is reversed.