Measuring the specific heat capacity at constant volume can be prohibitively difficult for liquids and solids. That is, small temperature changes typically require large pressures to maintain a liquid or solid at constant volume, implying that the containing vessel must be nearly rigid or at least very strong (see coefficient of thermal expansion and compressibility). Instead, it is easier to measure the heat capacity at constant pressure (allowing the material to expand or contract freely) and solve for the heat capacity at constant volume using mathematical relationships derived from the basic thermodynamic laws.
Measuring the specific heat capacity at constant volume can be prohibitively difficult for liquids and solids That is small temperature changes typically require large pressures to maintain a liquid or solid at constant volume implying that the containing vessel must be nearly. rigid or at least very strong (see coefficient of thermal expansion and compressibility) Instead it is easier to measure the heat capacity at constant pressure (allowing the material to expand or contract freely) and solve for the heat capacity at constant volume using mathematical relationships derived from the basic thermodynamic laws