data_In2BRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.6
_cell_length_b   3.6
_cell_length_c   13.41
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.73
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In2BRh
_chemical_formula_sum   'In4 B2 Rh2'
_cell_volume   149.22
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In2  1  0.78  0.03  0.95  1.0
  In  In3  1  0.78  0.97  0.25  1.0
  In  In4  1  0.78  0.03  0.17  1.0
  In  In5  1  0.78  0.97  0.46  1.0
  B  B0  1  0.78  0.02  0.06  1.0
  B  B1  1  0.78  0.98  0.35  1.0
  Rh  Rh6  1  0.78  0.2  0.06  1.0
  Rh  Rh7  1  0.78  0.8  0.35  1.0

data_In2BRh
_symmetry_space_group_name_H-M   C2/m
_cell_length_a   3.6
_cell_length_b   6.19
_cell_length_c   13.41
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   12
_chemical_formula_structural   In2BRh
_chemical_formula_sum   'In8 B4 Rh4'
_cell_volume   298.46
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
  3  '-x, y, -z'
  4  'x, -y, z'
  5  'x+1/2, y+1/2, z'
  6  '-x+1/2, -y+1/2, -z'
  7  '-x+1/2, y+1/2, -z'
  8  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  4  0.03  0.0  0.25  1.0
  In  In1  4  0.03  0.0  0.46  1.0
  B  B2  4  0.02  0.0  0.35  1.0
  Rh  Rh3  4  0.2  0.0  0.35  1.0

In In In In B B Rh Rh
In In In In B B Rh Rh 0 6 o o + 0 4 o o + 1 2 o + o 3 5 o o o 3 7 o o o 4 6 o o o 5 7 o o o 
RhIn2B crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one RhIn2B cluster. Rh(1) is bonded in a single-bond geometry to one In(1), one In(2), and one B(1) atom. The Rh(1)-In(1) bond length is 1.56 Å. The Rh(1)-In(2) bond length is 1.56 Å. The Rh(1)-B(1) bond length is 0.65 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 2-coordinate geometry to one Rh(1) and one B(1) atom. The In(1)-B(1) bond length is 1.43 Å. In the second In site, In(2) is bonded in a 3-coordinate geometry to one Rh(1), one In(2), and one B(1) atom. The In(2)-In(2) bond length is 1.10 Å. The In(2)-B(1) bond length is 1.43 Å. B(1) is bonded in a distorted single-bond geometry to one Rh(1), one In(1), and one In(2) atom.