data_Ge2SbPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.48
_cell_length_b   6.48
_cell_length_c   6.48
_cell_angle_alpha   149.79
_cell_angle_beta   142.63
_cell_angle_gamma   48.78
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ge2SbPd
_chemical_formula_sum   'Ge2 Sb1 Pd1'
_cell_volume   82.75
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.0  0.0  0.07  1.0
  Ge  Ge1  1  0.0  0.08  0.14  1.0
  Sb  Sb3  1  0.69  0.0  0.65  1.0
  Pd  Pd2  1  0.0  0.0  0.95  1.0

data_Ge2SbPd
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.38
_cell_length_b   4.15
_cell_length_c   6.48
_cell_angle_alpha   108.68
_cell_angle_beta   105.11
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ge2SbPd
_chemical_formula_sum   'Ge2 Sb1 Pd1'
_cell_volume   82.75
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.86  0.93  0.93  1.0
  Ge  Ge1  1  0.93  0.93  0.93  1.0
  Sb  Sb2  1  0.04  0.35  0.04  1.0
  Pd  Pd3  1  0.05  0.05  0.05  1.0

Ge Ge Sb Pd
Ge Ge Sb Pd 0 1 o o o 0 3 o o - 1 3 o o - 2 3 + o o 
PdGe2Sb is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one PdGe2Sb cluster. Pd(1) is bonded in a distorted single-bond geometry to one Ge(1) and one Sb(1) atom. The Pd(1)-Ge(1) bond length is 0.78 Å. The Pd(1)-Sb(1) bond length is 1.27 Å. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a water-like geometry to one Pd(1) and one Ge(2) atom. The Ge(1)-Ge(2) bond length is 0.26 Å. In the second Ge site, Ge(2) is bonded in a distorted single-bond geometry to one Ge(1) atom. Sb(1) is bonded in a single-bond geometry to one Pd(1) atom.