data_Ho4CdCo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.43
_cell_length_b   9.43
_cell_length_c   9.43
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ho4CdCo
_chemical_formula_sum   'Ho16 Cd4 Co4'
_cell_volume   592.73
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho8  1  0.62  0.62  0.62  1.0
  Ho  Ho9  1  0.0  0.49  0.0  1.0
  Ho  Ho10  1  0.49  0.0  0.0  1.0
  Ho  Ho11  1  0.0  0.0  0.49  1.0
  Ho  Ho12  1  0.51  0.67  0.67  1.0
  Ho  Ho13  1  0.67  0.67  0.51  1.0
  Ho  Ho14  1  0.67  0.51  0.67  1.0
  Ho  Ho15  1  0.0  0.0  0.51  1.0
  Ho  Ho16  1  0.51  0.0  0.0  1.0
  Ho  Ho17  1  0.0  0.51  0.0  1.0
  Ho  Ho18  1  0.62  0.71  0.71  1.0
  Ho  Ho19  1  0.71  0.71  0.62  1.0
  Ho  Ho20  1  0.71  0.62  0.71  1.0
  Ho  Ho21  1  0.67  0.67  0.82  1.0
  Ho  Ho22  1  0.82  0.67  0.67  1.0
  Ho  Ho23  1  0.67  0.82  0.67  1.0
  Cd  Cd0  1  0.59  0.74  0.59  1.0
  Cd  Cd1  1  0.59  0.59  0.74  1.0
  Cd  Cd2  1  0.74  0.59  0.59  1.0
  Cd  Cd3  1  0.74  0.74  0.74  1.0
  Co  Co4  1  0.88  0.88  0.88  1.0
  Co  Co5  1  0.78  0.88  0.78  1.0
  Co  Co6  1  0.88  0.78  0.78  1.0
  Co  Co7  1  0.78  0.78  0.88  1.0

data_Ho4CdCo
_symmetry_space_group_name_H-M   R3m
_cell_length_a   9.43
_cell_length_b   9.43
_cell_length_c   23.1
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   Ho4CdCo
_chemical_formula_sum   'Ho48 Cd12 Co12'
_cell_volume   1778.19
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  9  0.01  0.5  0.5  1.0
  Ho  Ho1  9  0.05  0.1  0.28  1.0
  Ho  Ho2  9  0.06  0.03  0.32  1.0
  Ho  Ho3  9  0.1  0.05  0.39  1.0
  Ho  Ho4  9  0.17  0.34  0.83  1.0
  Ho  Ho5  3  0.0  0.0  0.38  1.0
  Cd  Cd6  9  0.05  0.1  0.36  1.0
  Cd  Cd7  3  0.0  0.0  0.26  1.0
  Co  Co8  9  0.03  0.07  0.18  1.0
  Co  Co9  3  0.0  0.0  0.12  1.0

Ho Ho Ho Ho Ho Ho Ho Ho Ho Ho Ho Ho Ho Ho Ho Ho Cd Cd Cd Cd Co Co Co Co
Ho Ho Ho Ho Ho Ho Ho Ho Ho Ho Ho Ho Ho Ho Ho Ho Cd Cd Cd Cd Co Co Co Co 0 17 o o o 0 4 o o o 0 18 o o o 0 6 o o o 0 5 o o o 0 16 o o o 1 9 o o o 2 8 o o o 3 7 o o o 4 17 o o o 4 16 o o o 5 16 o o o 5 18 o o o 6 17 o o o 6 18 o o o 10 12 o o o 10 11 o o o 10 13 o o o 10 15 o o o 10 16 o o o 10 17 o o o 11 12 o o o 11 14 o o o 11 15 o o o 11 16 o o o 11 18 o o o 12 13 o o o 12 14 o o o 12 17 o o o 12 18 o o o 13 19 o o o 14 19 o o o 15 19 o o o 20 23 o o o 20 22 o o o 20 21 o o o 21 23 o o o 21 22 o o o 22 23 o o o 
Ho4CoCd is Cyanogen Chloride-derived structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three Ho3Cd clusters, three Ho3Co2 clusters, and three Ho7Cd3 clusters. In each Ho3Cd cluster, Ho(6) is bonded in a single-bond geometry to one Cd(2) atom. The Ho(6)-Cd(2) bond length is 1.02 Å. Cd(2) is bonded in a 3-coordinate geometry to three equivalent Ho(6) atoms. In each Ho3Co2 cluster, there are two inequivalent Ho sites. In the first Ho site, Ho(2) is bonded in a single-bond geometry to one Ho(4) atom. The Ho(2)-Ho(4) bond length is 0.17 Å. In the second Ho site, Ho(4) is bonded in a distorted single-bond geometry to one Ho(2) and one Co(1) atom. The Ho(4)-Co(1) bond length is 2.87 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 6-coordinate geometry to three equivalent Ho(4) and three equivalent Co(2) atoms. All Co(1)-Co(2) bond lengths are 1.60 Å. In the second Co site, Co(2) is bonded in a 2-coordinate geometry to one Co(1) and two equivalent Co(2) atoms. Both Co(2)-Co(2) bond lengths are 0.92 Å. In each Ho7Cd3 cluster, there are three inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 3-coordinate geometry to three equivalent Ho(3) and three equivalent Cd(1) atoms. All Ho(1)-Ho(3) bond lengths are 0.86 Å. All Ho(1)-Cd(1) bond lengths are 0.96 Å. In the second Ho site, Ho(5) is bonded in a 4-coordinate geometry to two equivalent Ho(5) and two equivalent Cd(1) atoms. Both Ho(5)-Ho(5) bond lengths are 0.87 Å. Both Ho(5)-Cd(1) bond lengths are 1.19 Å. In the third Ho site, Ho(3) is bonded in a 3-coordinate geometry to one Ho(1) and two equivalent Cd(1) atoms. Both Ho(3)-Cd(1) bond lengths are 1.05 Å. Cd(1) is bonded in a distorted single-bond geometry to one Ho(1), two equivalent Ho(3), and two equivalent Ho(5) atoms.