data_Ti2GaMo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.32
_cell_length_b   4.32
_cell_length_c   3.38
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ti2GaMo
_chemical_formula_sum   'Ti2 Ga1 Mo1'
_cell_volume   63.05
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti2  1  0.16  0.0  0.69  1.0
  Ti  Ti3  1  0.0  0.16  0.69  1.0
  Ga  Ga0  1  0.0  0.0  0.0  1.0
  Mo  Mo1  1  0.16  0.16  0.0  1.0

data_Ti2GaMo
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.1
_cell_length_b   6.1
_cell_length_c   3.38
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Ti2GaMo
_chemical_formula_sum   'Ti4 Ga2 Mo2'
_cell_volume   126.09
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  4  0.08  0.08  0.69  1.0
  Ga  Ga1  2  0.0  0.0  0.0  1.0
  Mo  Mo2  2  0.16  0.0  0.0  1.0

Ti Ti Ga Mo
Ti Ti Ga Mo 0 1 o o o 2 3 o o o 
Ti2MoGa is alpha Po structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Ti2MoGa clusters. Ti(1) is bonded in a 3-coordinate geometry to one Ti(1), one Mo(1), and one Ga(1) atom. The Ti(1)-Ti(1) bond length is 0.97 Å. The Ti(1)-Mo(1) bond length is 1.25 Å. The Ti(1)-Ga(1) bond length is 1.25 Å. Mo(1) is bonded in a distorted single-bond geometry to two equivalent Ti(1) and one Ga(1) atom. The Mo(1)-Ga(1) bond length is 0.97 Å. Ga(1) is bonded in a distorted single-bond geometry to two equivalent Ti(1) and one Mo(1) atom.