data_CaInTc
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.84
_cell_length_b   5.84
_cell_length_c   5.84
_cell_angle_alpha   143.98
_cell_angle_beta   143.98
_cell_angle_gamma   51.86
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CaInTc
_chemical_formula_sum   'Ca1 In1 Tc1'
_cell_volume   68.42
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.0  0.0  0.06  1.0
  In  In1  1  0.0  0.0  0.1  1.0
  Tc  Tc2  1  0.0  0.0  0.34  1.0

data_CaInTc
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.11
_cell_length_b   5.11
_cell_length_c   5.84
_cell_angle_alpha   90.0
_cell_angle_beta   115.93
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   CaInTc
_chemical_formula_sum   'Ca2 In2 Tc2'
_cell_volume   136.85
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  2  0.0  0.0  0.94  1.0
  In  In1  2  0.0  0.0  0.9  1.0
  Tc  Tc2  2  0.0  0.0  0.66  1.0

Ca In Tc
Ca In Tc 0 1 o o o 0 2 o o o 1 2 o o o 
CaTcIn crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two CaTcIn clusters. Ca(1) is bonded in a single-bond geometry to one In(1) atom. The Ca(1)-In(1) bond length is 0.19 Å. Tc(1) is bonded in a single-bond geometry to one In(1) atom. The Tc(1)-In(1) bond length is 1.44 Å. In(1) is bonded in a distorted single-bond geometry to one Ca(1) and one Tc(1) atom.