data_Cs(TeO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.46
_cell_length_b   7.46
_cell_length_c   7.46
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cs(TeO3)2
_chemical_formula_sum   'Cs2 Te4 O12'
_cell_volume   294.06
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.64  0.64  0.64  1.0
  Cs  Cs1  1  0.0  0.0  0.0  1.0
  Te  Te14  1  0.96  0.6  0.96  1.0
  Te  Te15  1  0.6  0.6  0.6  1.0
  Te  Te16  1  0.96  0.96  0.6  1.0
  Te  Te17  1  0.6  0.96  0.96  1.0
  O  O2  1  0.92  0.92  0.87  1.0
  O  O3  1  0.92  0.92  0.96  1.0
  O  O4  1  0.87  0.92  0.92  1.0
  O  O5  1  0.92  0.87  0.92  1.0
  O  O6  1  0.96  0.92  0.92  1.0
  O  O7  1  0.92  0.96  0.92  1.0
  O  O8  1  0.28  0.28  0.32  1.0
  O  O9  1  0.28  0.28  0.24  1.0
  O  O10  1  0.28  0.32  0.28  1.0
  O  O11  1  0.32  0.28  0.28  1.0
  O  O12  1  0.28  0.24  0.28  1.0
  O  O13  1  0.24  0.28  0.28  1.0

data_Cs(TeO3)2
_symmetry_space_group_name_H-M   R3m
_cell_length_a   7.46
_cell_length_b   7.46
_cell_length_c   18.28
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   Cs(TeO3)2
_chemical_formula_sum   'Cs6 Te12 O36'
_cell_volume   882.17
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  3  0.0  0.0  -0.0  1.0
  Cs  Cs1  3  0.0  0.0  0.36  1.0
  Te  Te2  9  0.21  0.43  0.83  1.0
  Te  Te3  3  0.0  0.0  0.4  1.0
  O  O4  9  0.01  0.03  0.07  1.0
  O  O5  9  0.01  0.03  0.71  1.0
  O  O6  9  0.03  0.01  0.74  1.0
  O  O7  9  0.03  0.01  0.1  1.0

Cs Cs Te Te Te Te O O O O O O O O O O O O
Cs Cs Te Te Te Te O O O O O O O O O O O O 0 3 o o o 1 11 - - - 1 10 - - - 1 7 - - - 2 10 o o o 2 9 o o o 2 8 o o o 2 7 o o o 2 6 o o o 4 10 o o o 4 9 o o o 4 8 o o o 4 6 o o o 4 11 o o o 5 9 o o o 5 8 o o o 5 7 o o o 5 6 o o o 5 11 o o o 6 9 o o o 6 8 o o o 7 11 o o o 7 10 o o o 8 9 o o o 10 11 o o o 12 15 o o o 12 14 o o o 13 16 o o o 13 17 o o o 14 15 o o o 16 17 o o o 
CsTeCsO3(TeO)3(O2)3 crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three CsO3 clusters, three CsTe clusters, three O2 clusters, and three TeO clusters. In each CsO3 cluster, Cs(2) is bonded in a 3-coordinate geometry to three equivalent O(2) atoms. All Cs(2)-O(2) bond lengths are 1.27 Å. O(2) is bonded in a 2-coordinate geometry to one Cs(2) and two equivalent O(2) atoms. Both O(2)-O(2) bond lengths are 0.32 Å. In each CsTe cluster, Cs(1) is bonded in a single-bond geometry to one Te(2) atom. The Cs(1)-Te(2) bond length is 0.76 Å. Te(2) is bonded in a single-bond geometry to one Cs(1) atom. In each O2 cluster, there are two inequivalent O sites. In the first O site, O(3) is bonded in a 4-coordinate geometry to two equivalent O(3) and two equivalent O(4) atoms. Both O(3)-O(3) bond lengths are 0.32 Å. Both O(3)-O(4) bond lengths are 0.55 Å. In the second O site, O(4) is bonded in a 2-coordinate geometry to two equivalent O(3) and two equivalent O(4) atoms. Both O(4)-O(4) bond lengths are 0.32 Å. In each TeO cluster, Te(1) is bonded in a single-bond geometry to one O(1) atom. The Te(1)-O(1) bond length is 1.81 Å. O(1) is bonded in a 3-coordinate geometry to one Te(1) and two equivalent O(1) atoms. Both O(1)-O(1) bond lengths are 0.32 Å.