data_V2ZnRe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.89
_cell_length_b   4.89
_cell_length_c   4.89
_cell_angle_alpha   141.51
_cell_angle_beta   128.6
_cell_angle_gamma   66.01
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2ZnRe
_chemical_formula_sum   'V2 Zn1 Re1'
_cell_volume   55.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V1  1  0.61  0.0  0.15  1.0
  V  V2  1  0.0  0.12  0.95  1.0
  Zn  Zn3  1  0.0  0.0  0.0  1.0
  Re  Re0  1  0.0  0.0  0.1  1.0

data_V2ZnRe
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.22
_cell_length_b   4.24
_cell_length_c   4.89
_cell_angle_alpha   115.7
_cell_angle_beta   109.24
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2ZnRe
_chemical_formula_sum   'V2 Zn1 Re1'
_cell_volume   55.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.05  0.17  0.17  1.0
  V  V1  1  0.46  0.85  0.46  1.0
  Zn  Zn2  1  0.0  0.0  0.0  1.0
  Re  Re3  1  0.9  0.9  0.9  1.0

V V Zn Re
V V Zn Re 0 2 o o o 0 2 + o o 0 1 o o - 0 1 + o o 0 3 + o o 1 2 o o + 2 3 o o o 
V2ReZn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one V2ReZn cluster. There are two inequivalent V sites. In the first V site, V(1) is bonded in a single-bond geometry to one Re(1) atom. The V(1)-Re(1) bond length is 2.08 Å. In the second V site, V(2) is bonded in a single-bond geometry to one Zn(1) atom. The V(2)-Zn(1) bond length is 0.80 Å. Re(1) is bonded in a distorted single-bond geometry to one V(1) and one Zn(1) atom. The Re(1)-Zn(1) bond length is 0.48 Å. Zn(1) is bonded in a distorted bent 150 degrees geometry to one V(2) and one Re(1) atom.