data_LaAlIn2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.66
_cell_length_b   4.66
_cell_length_c   4.72
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaAlIn2
_chemical_formula_sum   'La1 Al1 In2'
_cell_volume   102.4
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La3  1  0.33  0.33  0.0  1.0
  Al  Al0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.0  0.33  0.36  1.0
  In  In2  1  0.33  0.0  0.36  1.0

data_LaAlIn2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.58
_cell_length_b   6.58
_cell_length_c   4.72
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LaAlIn2
_chemical_formula_sum   'La2 Al2 In4'
_cell_volume   204.79
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  2  0.33  0.0  0.0  1.0
  Al  Al1  2  0.0  0.0  0.0  1.0
  In  In2  4  0.16  0.16  0.36  1.0

La Al In In
La Al In In 0 1 o o o 0 2 o o o 0 3 o o o 1 3 o o o 1 2 o o o 2 3 o o o 
LaIn2Al crystallizes in the monoclinic Cm space group. La(1) is bonded in a 3-coordinate geometry to six equivalent In(1) and one Al(1) atom. There are a spread of La(1)-In(1) bond distances ranging from 2.29-3.57 Å. The La(1)-Al(1) bond length is 2.16 Å. In(1) is bonded in a 5-coordinate geometry to three equivalent La(1), one In(1), and one Al(1) atom. The In(1)-In(1) bond length is 2.16 Å. The In(1)-Al(1) bond length is 2.29 Å. Al(1) is bonded in a 3-coordinate geometry to one La(1) and two equivalent In(1) atoms.