data_GeIrRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.85
_cell_length_b   2.85
_cell_length_c   7.13
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GeIrRh2
_chemical_formula_sum   'Ge1 Ir1 Rh2'
_cell_volume   57.87
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.0  0.0  0.54  1.0
  Ir  Ir1  1  0.42  0.42  0.23  1.0
  Rh  Rh2  1  0.0  0.0  0.12  1.0
  Rh  Rh3  1  0.42  0.42  0.93  1.0

data_GeIrRh2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.03
_cell_length_b   4.03
_cell_length_c   7.13
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   GeIrRh2
_chemical_formula_sum   'Ge2 Ir2 Rh4'
_cell_volume   115.73
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  2  0.0  0.0  0.54  1.0
  Ir  Ir1  2  0.42  0.0  0.23  1.0
  Rh  Rh2  2  0.0  0.0  0.12  1.0
  Rh  Rh3  2  0.42  0.0  0.93  1.0

Ge Ir Rh Rh
Ge Ir Rh Rh 0 1 - - o 0 1 - o o 0 1 o - o 0 1 o o o 0 3 - o o 0 3 o - o 0 3 o o o 0 0 + o o 0 0 o + o 0 2 o o o 1 2 o o o 1 2 o + o 1 2 + o o 1 2 + + o 1 3 o o - 2 3 - o - 2 3 o - - 2 3 o o - 2 3 - - - 
IrRh2Ge crystallizes in the monoclinic Cm space group. Ir(1) is bonded in a 1-coordinate geometry to one Rh(2), three equivalent Rh(1), and four equivalent Ge(1) atoms. The Ir(1)-Rh(2) bond length is 2.14 Å. There is one shorter (1.89 Å) and two longer (2.19 Å) Ir(1)-Rh(1) bond lengths. There are a spread of Ir(1)-Ge(1) bond distances ranging from 2.80-3.21 Å. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 3-coordinate geometry to three equivalent Ir(1); four Rh(2,2); and one Ge(1) atom. There are a spread of Rh(1)-Rh(2,2) bond distances ranging from 2.17-2.68 Å. The Rh(1)-Ge(1) bond length is 3.03 Å. In the second Rh site, Rh(2) is bonded in a 10-coordinate geometry to one Ir(1), four equivalent Rh(1), four equivalent Rh(2), and one Ge(1) atom. All Rh(2)-Rh(2) bond lengths are 2.85 Å. The Rh(2)-Ge(1) bond length is 3.25 Å. In the third Rh site, Rh(2) is bonded in a 10-coordinate geometry to one Ir(1), four equivalent Rh(1), four equivalent Rh(2), and one Ge(1) atom. The Rh(2)-Ir(1) bond length is 2.14 Å. The Rh(2)-Ge(1) bond length is 3.25 Å. Ge(1) is bonded in a 10-coordinate geometry to four equivalent Ir(1), one Rh(1), one Rh(2), and four equivalent Ge(1) atoms. All Ge(1)-Ge(1) bond lengths are 2.85 Å.