data_VZnBiMo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.64
_cell_length_b   4.64
_cell_length_c   4.64
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VZnBiMo
_chemical_formula_sum   'V1 Zn1 Bi1 Mo1'
_cell_volume   70.46
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  Zn  Zn3  1  0.64  0.64  0.64  1.0
  Bi  Bi2  1  0.28  0.28  0.28  1.0
  Mo  Mo1  1  0.92  0.92  0.92  1.0

data_VZnBiMo
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.64
_cell_length_b   4.64
_cell_length_c   11.36
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   VZnBiMo
_chemical_formula_sum   'V3 Zn3 Bi3 Mo3'
_cell_volume   211.39
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  3  0.0  0.0  0.0  1.0
  Zn  Zn1  3  0.0  0.0  0.36  1.0
  Bi  Bi2  3  0.0  0.0  0.72  1.0
  Mo  Mo3  3  0.0  0.0  0.08  1.0

V Zn Bi Mo
V Zn Bi Mo 0 3 - - - 0 1 o - - 0 1 - o - 0 1 - - o 0 2 o o o 0 2 o o - 0 2 o - o 0 2 - o o 1 2 o o + 1 2 o + o 1 2 + o o 1 3 - o o 1 3 o - o 1 3 o o - 1 3 o o o 2 3 - - o 2 3 - o - 2 3 o - - 
VMoZnBi crystallizes in the trigonal R3m space group. V(1) is bonded in a single-bond geometry to one Mo(1), three equivalent Zn(1), and four equivalent Bi(1) atoms. The V(1)-Mo(1) bond length is 0.94 Å. All V(1)-Zn(1) bond lengths are 2.69 Å. There are three shorter (2.75 Å) and one longer (3.16 Å) V(1)-Bi(1) bond length. Mo(1) is bonded in a single-bond geometry to one V(1), four equivalent Zn(1), and three equivalent Bi(1) atoms. There are three shorter (2.75 Å) and one longer (3.16 Å) Mo(1)-Zn(1) bond length. All Mo(1)-Bi(1) bond lengths are 2.69 Å. Zn(1) is bonded in a 10-coordinate geometry to three equivalent V(1), four equivalent Mo(1), and three equivalent Bi(1) atoms. All Zn(1)-Bi(1) bond lengths are 2.69 Å. Bi(1) is bonded in a 10-coordinate geometry to four equivalent V(1), three equivalent Mo(1), and three equivalent Zn(1) atoms.