data_BiTeP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.19
_cell_length_b   6.19
_cell_length_c   6.19
_cell_angle_alpha   144.96
_cell_angle_beta   144.96
_cell_angle_gamma   50.39
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BiTeP
_chemical_formula_sum   'Bi1 Te1 P1'
_cell_volume   77.62
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.0  0.0  0.84  1.0
  Te  Te2  1  0.0  0.0  0.59  1.0
  P  P1  1  0.0  0.0  0.97  1.0

data_BiTeP
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.27
_cell_length_b   5.27
_cell_length_c   6.19
_cell_angle_alpha   90.0
_cell_angle_beta   115.19
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   BiTeP
_chemical_formula_sum   'Bi2 Te2 P2'
_cell_volume   155.25
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  2  0.0  0.0  0.16  1.0
  Te  Te1  2  0.0  0.0  0.41  1.0
  P  P2  2  0.0  0.0  0.03  1.0

Bi Te P
Bi Te P 0 2 o o o 0 1 o o o 
BiPTe is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two BiPTe clusters. Bi(1) is bonded in a linear geometry to one P(1) and one Te(1) atom. The Bi(1)-P(1) bond length is 0.80 Å. The Bi(1)-Te(1) bond length is 1.56 Å. P(1) is bonded in a single-bond geometry to one Bi(1) atom. Te(1) is bonded in a single-bond geometry to one Bi(1) atom.