data_NbSb2Te
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.41
_cell_length_b   5.41
_cell_length_c   5.48
_cell_angle_alpha   100.14
_cell_angle_beta   100.14
_cell_angle_gamma   38.56
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NbSb2Te
_chemical_formula_sum   'Nb1 Sb2 Te1'
_cell_volume   98.23
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.0  0.0  0.0  1.0
  Sb  Sb1  1  0.05  0.0  0.28  1.0
  Sb  Sb2  1  0.13  0.0  0.11  1.0
  Te  Te3  1  0.59  0.0  0.69  1.0

data_NbSb2Te
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.57
_cell_length_b   5.41
_cell_length_c   5.48
_cell_angle_alpha   100.14
_cell_angle_beta   90.0
_cell_angle_gamma   109.28
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NbSb2Te
_chemical_formula_sum   'Nb1 Sb2 Te1'
_cell_volume   98.23
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.0  0.0  0.0  1.0
  Sb  Sb1  1  0.0  0.87  0.89  1.0
  Sb  Sb2  1  0.0  0.95  0.72  1.0
  Te  Te3  1  0.0  0.41  0.31  1.0

Nb Sb Sb Te
Nb Sb Sb Te 0 2 o o o 0 3 - o - 1 2 o o o 
NbSb2Te crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one NbSb2Te cluster. Nb(1) is bonded in a single-bond geometry to one Sb(2) and one Te(1) atom. The Nb(1)-Sb(2) bond length is 0.85 Å. The Nb(1)-Te(1) bond length is 2.52 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 1-coordinate geometry to one Sb(2) atom. The Sb(1)-Sb(2) bond length is 1.09 Å. In the second Sb site, Sb(2) is bonded in a distorted single-bond geometry to one Nb(1) and one Sb(1) atom. Te(1) is bonded in a single-bond geometry to one Nb(1) atom.