data_SnPt2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.5
_cell_length_b   5.5
_cell_length_c   5.5
_cell_angle_alpha   147.37
_cell_angle_beta   122.08
_cell_angle_gamma   68.08
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SnPt2Cl
_chemical_formula_sum   'Sn1 Pt2 Cl1'
_cell_volume   75.08
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn3  1  0.0  0.0  0.56  1.0
  Pt  Pt1  1  0.55  0.0  0.39  1.0
  Pt  Pt2  1  0.0  0.66  0.17  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_SnPt2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.09
_cell_length_b   5.33
_cell_length_c   5.5
_cell_angle_alpha   118.96
_cell_angle_beta   106.31
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SnPt2Cl
_chemical_formula_sum   'Sn1 Pt2 Cl1'
_cell_volume   75.08
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.0  0.56  0.56  1.0
  Pt  Pt1  1  0.0  0.39  0.84  1.0
  Pt  Pt2  1  0.34  0.51  0.51  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Sn Pt Pt Cl
Sn Pt Pt Cl 0 2 o - o 0 1 - o o 0 3 o o + 0 3 o o o 1 3 o o o 1 3 + o + 1 2 + - o 1 2 + o + 2 3 o o o 2 3 o + + 2 3 o + o 3 3 o + + 
Pt2SnCl crystallizes in the triclinic P1 space group. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 2-coordinate geometry to one Sn(1) and one Cl(1) atom. The Pt(1)-Sn(1) bond length is 2.16 Å. The Pt(1)-Cl(1) bond length is 2.60 Å. In the second Pt site, Pt(2) is bonded in a 1-coordinate geometry to two equivalent Sn(1) and one Cl(1) atom. There is one shorter (1.16 Å) and one longer (1.99 Å) Pt(2)-Sn(1) bond length. The Pt(2)-Cl(1) bond length is 2.68 Å. Sn(1) is bonded in a 4-coordinate geometry to one Pt(1), two equivalent Pt(2), and one Cl(1) atom. The Sn(1)-Cl(1) bond length is 2.43 Å. Cl(1) is bonded in a 3-coordinate geometry to one Pt(1), one Pt(2), and one Sn(1) atom.