data_Cu2SbCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.87
_cell_length_b   4.87
_cell_length_c   3.08
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cu2SbCl
_chemical_formula_sum   'Cu2 Sb1 Cl1'
_cell_volume   73.27
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu1  1  0.0  0.44  0.54  1.0
  Cu  Cu2  1  0.44  0.0  0.54  1.0
  Sb  Sb3  1  0.44  0.44  0.0  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Cu2SbCl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.89
_cell_length_b   6.89
_cell_length_c   3.08
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Cu2SbCl
_chemical_formula_sum   'Cu4 Sb2 Cl2'
_cell_volume   146.55
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  4  0.22  0.22  0.54  1.0
  Sb  Sb1  2  0.44  0.0  0.0  1.0
  Cl  Cl2  2  0.0  0.0  0.0  1.0

Cu Cu Sb Cl
Cu Cu Sb Cl 0 2 - o o 0 2 - o + 0 2 o o o 0 2 o o + 0 3 o o o 0 3 o o + 0 3 o + o 0 3 o + + 0 1 o o o 0 0 o o + 1 3 o o o 1 3 o o + 1 3 + o o 1 3 + o + 1 2 o - o 1 2 o - + 1 2 o o o 1 2 o o + 1 1 o o + 2 3 o o o 2 2 o o + 3 3 o o + 
Cu2SbCl crystallizes in the monoclinic Cm space group. Cu(1) is bonded in a 2-coordinate geometry to four equivalent Sb(1) and two equivalent Cl(1) atoms. There are a spread of Cu(1)-Sb(1) bond distances ranging from 2.56-3.21 Å. There is one shorter (2.56 Å) and one longer (2.71 Å) Cu(1)-Cl(1) bond length. Sb(1) is bonded in a 11-coordinate geometry to eight equivalent Cu(1), two equivalent Sb(1), and one Cl(1) atom. Both Sb(1)-Sb(1) bond lengths are 3.08 Å. The Sb(1)-Cl(1) bond length is 3.02 Å. Cl(1) is bonded in a 4-coordinate geometry to four equivalent Cu(1) and one Sb(1) atom.