data_SrAsRu4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.31
_cell_length_b   5.31
_cell_length_c   5.31
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SrAsRu4
_chemical_formula_sum   'Sr1 As1 Ru4'
_cell_volume   105.98
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr5  1  0.63  0.63  0.63  1.0
  As  As0  1  0.0  0.0  0.0  1.0
  Ru  Ru1  1  0.71  0.71  0.81  1.0
  Ru  Ru2  1  0.71  0.81  0.71  1.0
  Ru  Ru3  1  0.81  0.71  0.71  1.0
  Ru  Ru4  1  0.81  0.81  0.81  1.0

data_SrAsRu4
_symmetry_space_group_name_H-M   R3m
_cell_length_a   5.31
_cell_length_b   5.31
_cell_length_c   13.01
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   SrAsRu4
_chemical_formula_sum   'Sr3 As3 Ru12'
_cell_volume   317.95
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  3  0.0  0.0  0.37  1.0
  As  As1  3  0.0  0.0  0.0  1.0
  Ru  Ru2  9  0.03  0.07  0.26  1.0
  Ru  Ru3  3  0.0  0.0  0.19  1.0

Sr As Ru Ru Ru Ru
Sr As Ru Ru Ru Ru 0 4 o o o 0 3 o o o 0 2 o o o 0 1 + + o 0 1 + o + 0 1 o + + 1 5 - - - 1 5 - - o 1 5 o - - 1 5 - o - 1 4 - - - 1 4 - - o 1 4 o - - 1 4 - o - 1 3 - - - 1 3 - - o 1 3 - o - 1 3 o - - 1 2 - - - 1 2 - - o 1 2 - o - 1 2 o - - 2 4 o o o 2 3 o o o 2 5 o o o 3 4 o o o 3 5 o o o 4 5 o o o 
SrRu4As crystallizes in the trigonal R3m space group. Sr(1) is bonded in a 3-coordinate geometry to three equivalent Ru(1), three equivalent Ru(2), and three equivalent As(1) atoms. All Sr(1)-Ru(1) bond lengths are 1.40 Å. All Sr(1)-Ru(2) bond lengths are 3.72 Å. All Sr(1)-As(1) bond lengths are 3.10 Å. There are two inequivalent Ru sites. In the first Ru site, Ru(2) is bonded in a 7-coordinate geometry to three equivalent Sr(1), three equivalent Ru(1), and one As(1) atom. All Ru(2)-Ru(1) bond lengths are 0.92 Å. The Ru(2)-As(1) bond length is 2.52 Å. In the second Ru site, Ru(1) is bonded in a 2-coordinate geometry to one Sr(1), one Ru(2), and two equivalent Ru(1) atoms. Both Ru(1)-Ru(1) bond lengths are 0.53 Å. As(1) is bonded to three equivalent Sr(1) and one Ru(2) atom to form distorted corner-sharing AsSr3Ru trigonal pyramids.