data_BaIn2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.17
_cell_length_b   8.17
_cell_length_c   8.17
_cell_angle_alpha   157.97
_cell_angle_beta   145.73
_cell_angle_gamma   41.11
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaIn2W
_chemical_formula_sum   'Ba1 In2 W1'
_cell_volume   114.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.0  0.0  0.79  1.0
  In  In1  1  0.56  0.0  0.06  1.0
  In  In2  1  0.0  0.0  0.23  1.0
  W  W3  1  0.0  0.41  0.22  1.0

data_BaIn2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.12
_cell_length_b   4.81
_cell_length_c   8.17
_cell_angle_alpha   107.14
_cell_angle_beta   101.01
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaIn2W
_chemical_formula_sum   'Ba1 In2 W1'
_cell_volume   114.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.0  0.79  0.79  1.0
  In  In1  1  0.0  0.06  0.5  1.0
  In  In2  1  0.0  0.23  0.23  1.0
  W  W3  1  0.59  0.81  0.81  1.0

Ba In In W
Ba In In W 0 3 o o + 0 1 o o + 1 3 o - - 1 1 o + + 1 2 + o o 2 2 o + + 
BaWIn2 crystallizes in the triclinic P1 space group. Ba(1) is bonded in a distorted linear geometry to two equivalent W(1), one In(2), and two equivalent In(1) atoms. There is one shorter (1.31 Å) and one longer (1.83 Å) Ba(1)-W(1) bond length. The Ba(1)-In(2) bond length is 3.58 Å. There is one shorter (3.04 Å) and one longer (3.63 Å) Ba(1)-In(1) bond length. W(1) is bonded in a distorted linear geometry to two equivalent Ba(1), one In(1), and one In(2) atom. The W(1)-In(1) bond length is 3.37 Å. The W(1)-In(2) bond length is 3.42 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 6-coordinate geometry to two equivalent Ba(1), one W(1), one In(2), and two equivalent In(1) atoms. The In(1)-In(2) bond length is 2.56 Å. Both In(1)-In(1) bond lengths are 3.12 Å. In the second In site, In(2) is bonded to one Ba(1), one W(1), one In(1), and two equivalent In(2) atoms to form distorted corner-sharing InBaIn3W trigonal bipyramids. Both In(2)-In(2) bond lengths are 3.12 Å.