data_ZnCdW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.93
_cell_length_b   4.93
_cell_length_c   5.22
_cell_angle_alpha   95.02
_cell_angle_beta   95.02
_cell_angle_gamma   32.08
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnCdW2
_chemical_formula_sum   'Zn1 Cd1 W2'
_cell_volume   67.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.54  0.0  0.57  1.0
  Cd  Cd0  1  0.97  0.0  0.39  1.0
  W  W1  1  0.0  0.0  0.06  1.0
  W  W2  1  0.97  0.0  0.98  1.0

data_ZnCdW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.72
_cell_length_b   4.93
_cell_length_c   5.22
_cell_angle_alpha   95.02
_cell_angle_beta   90.0
_cell_angle_gamma   106.04
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnCdW2
_chemical_formula_sum   'Zn1 Cd1 W2'
_cell_volume   67.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.0  0.46  0.43  1.0
  Cd  Cd1  1  0.0  0.03  0.61  1.0
  W  W2  1  0.0  0.03  0.02  1.0
  W  W3  1  0.0  1.0  0.94  1.0

Zn Cd W W
Zn Cd W W 0 1 - o o 0 1 o o o 0 1 - + o 0 0 + - o 0 3 o o o 1 2 + o o 2 3 - o - 
W2CdZn crystallizes in the triclinic P1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded in a bent 150 degrees geometry to one W(2) and one Cd(1) atom. The W(1)-W(2) bond length is 0.43 Å. The W(1)-Cd(1) bond length is 1.76 Å. In the second W site, W(2) is bonded in a distorted single-bond geometry to one W(1) and one Zn(1) atom. The W(2)-Zn(1) bond length is 2.88 Å. Cd(1) is bonded in a distorted single-bond geometry to one W(1) and two equivalent Zn(1) atoms. There is one shorter (2.39 Å) and one longer (2.86 Å) Cd(1)-Zn(1) bond length. Zn(1) is bonded in a 5-coordinate geometry to one W(2), two equivalent Cd(1), and two equivalent Zn(1) atoms. Both Zn(1)-Zn(1) bond lengths are 2.72 Å.