data_VBiRu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.12
_cell_length_b   3.12
_cell_length_c   6.98
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VBiRu2
_chemical_formula_sum   'V1 Bi1 Ru2'
_cell_volume   67.76
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Bi  Bi0  1  0.0  0.0  0.49  1.0
  Ru  Ru1  1  0.56  0.56  0.59  1.0
  Ru  Ru2  1  0.56  0.56  0.39  1.0

data_VBiRu2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.41
_cell_length_b   4.41
_cell_length_c   6.98
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VBiRu2
_chemical_formula_sum   'V2 Bi2 Ru4'
_cell_volume   135.51
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.0  1.0
  Bi  Bi1  2  0.0  0.0  0.49  1.0
  Ru  Ru2  2  0.06  0.5  0.39  1.0
  Ru  Ru3  2  0.06  0.5  0.59  1.0

V Bi Ru Ru
V Bi Ru Ru 0 2 - - - 0 2 - o - 0 2 o - - 0 2 o o - 0 3 - - o 0 3 - o o 0 3 o - o 0 3 o o o 0 0 + o o 0 0 o + o 0 1 o o - 0 1 o o o 1 3 - - o 1 3 - o o 1 3 o - o 1 3 o o o 1 2 - - o 1 2 - o o 1 2 o - o 1 2 o o o 2 3 o o o 
VRu2Bi crystallizes in the monoclinic Cm space group. V(1) is bonded in a 13-coordinate geometry to four equivalent V(1), three equivalent Ru(1), four equivalent Ru(2), and two equivalent Bi(1) atoms. All V(1)-V(1) bond lengths are 3.12 Å. There is one shorter (3.48 Å) and two longer (3.64 Å) V(1)-Ru(1) bond lengths. There are a spread of V(1)-Ru(2) bond distances ranging from 3.36-3.68 Å. There is one shorter (3.41 Å) and one longer (3.56 Å) V(1)-Bi(1) bond length. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a 1-coordinate geometry to three equivalent V(1), one Ru(2), and four equivalent Bi(1) atoms. The Ru(1)-Ru(2) bond length is 1.36 Å. There are a spread of Ru(1)-Bi(1) bond distances ranging from 2.06-2.55 Å. In the second Ru site, Ru(2) is bonded in a 1-coordinate geometry to four equivalent V(1), one Ru(1), and four equivalent Bi(1) atoms. There are a spread of Ru(2)-Bi(1) bond distances ranging from 2.06-2.55 Å. Bi(1) is bonded in a 8-coordinate geometry to two equivalent V(1), four equivalent Ru(1), and four equivalent Ru(2) atoms.