data_La(P3Ru)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.02
_cell_length_b   7.02
_cell_length_c   7.02
_cell_angle_alpha   109.47
_cell_angle_beta   109.47
_cell_angle_gamma   109.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   La(P3Ru)4
_chemical_formula_sum   'La1 P12 Ru4'
_cell_volume   266.86
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.0  0.0  1.0
  P  P1  1  0.21  0.0  0.17  1.0
  P  P2  1  0.91  0.0  0.17  1.0
  P  P3  1  0.15  0.06  0.89  1.0
  P  P4  1  0.17  0.91  0.0  1.0
  P  P5  1  0.0  0.17  0.21  1.0
  P  P6  1  0.85  0.06  0.89  1.0
  P  P7  1  0.17  0.21  0.0  1.0
  P  P8  1  0.06  0.89  0.15  1.0
  P  P9  1  0.89  0.15  0.06  1.0
  P  P10  1  0.0  0.17  0.91  1.0
  P  P11  1  0.89  0.85  0.06  1.0
  P  P12  1  0.06  0.89  0.85  1.0
  Ru  Ru13  1  0.97  0.03  0.03  1.0
  Ru  Ru14  1  0.03  0.03  0.03  1.0
  Ru  Ru15  1  0.03  0.97  0.03  1.0
  Ru  Ru16  1  0.03  0.03  0.97  1.0

data_La(P3Ru)4
_symmetry_space_group_name_H-M   R3
_cell_length_a   11.47
_cell_length_b   11.47
_cell_length_c   7.02
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   146
_chemical_formula_structural   La(P3Ru)4
_chemical_formula_sum   'La3 P36 Ru12'
_cell_volume   800.57
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  'x+2/3, y+1/3, z+1/3'
  5  '-y+2/3, x-y+1/3, z+1/3'
  6  '-x+y+2/3, -x+1/3, z+1/3'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  3  0.0  0.0  0.0  1.0
  P  P1  9  0.02  0.88  0.03  1.0
  P  P2  9  0.04  0.12  0.12  1.0
  P  P3  9  0.12  0.08  0.93  1.0
  P  P4  9  0.14  0.02  0.02  1.0
  Ru  Ru5  9  0.02  0.04  0.01  1.0
  Ru  Ru6  3  0.0  0.0  0.03  1.0

La P P P P P P P P P P P P Ru Ru Ru Ru
La P P P P P P P P P P P P Ru Ru Ru Ru 0 14 o o o 0 13 - o o 0 15 o - o 0 16 o o - 1 15 o - o 1 8 o - o 1 4 o - o 2 11 o - o 2 5 + o o 3 16 o o o 3 12 o - o 3 7 o o + 4 12 o o - 5 9 - o o 5 13 - o o 6 9 o o + 6 13 o o + 6 10 + o o 7 10 o o - 7 16 o o - 8 11 - o o 8 15 o o o 9 13 o o o 11 15 + o o 12 16 o + o 13 14 + o o 14 15 o - o 14 16 o o - 
LaRu4P12 is Tungsten structured and crystallizes in the trigonal R3 space group. The structure is zero-dimensional and consists of three LaRu4P12 clusters. La(1) is bonded in a single-bond geometry to one Ru(2) and three equivalent Ru(1) atoms. The La(1)-Ru(2) bond length is 0.20 Å. All La(1)-Ru(1) bond lengths are 0.38 Å. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a single-bond geometry to one La(1), one P(1), one P(2), one P(3), and two equivalent P(4) atoms. The Ru(1)-P(1) bond length is 1.21 Å. The Ru(1)-P(2) bond length is 1.27 Å. The Ru(1)-P(3) bond length is 1.20 Å. There is one shorter (1.20 Å) and one longer (1.31 Å) Ru(1)-P(4) bond length. In the second Ru site, Ru(2) is bonded in a single-bond geometry to one La(1) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded in a 3-coordinate geometry to one Ru(1), one P(2), and one P(3) atom. The P(1)-P(2) bond length is 1.03 Å. The P(1)-P(3) bond length is 1.02 Å. In the second P site, P(2) is bonded in a 3-coordinate geometry to one Ru(1), one P(1), and one P(4) atom. The P(2)-P(4) bond length is 1.02 Å. In the third P site, P(3) is bonded in a 3-coordinate geometry to one Ru(1), one P(1), and one P(4) atom. The P(3)-P(4) bond length is 1.03 Å. In the fourth P site, P(4) is bonded in a 4-coordinate geometry to two equivalent Ru(1), one P(2), and one P(3) atom.