data_CaTlW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.94
_cell_length_b   5.94
_cell_length_c   5.94
_cell_angle_alpha   149.63
_cell_angle_beta   139.33
_cell_angle_gamma   51.59
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CaTlW
_chemical_formula_sum   'Ca1 Tl1 W1'
_cell_volume   68.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.0  0.0  0.66  1.0
  Tl  Tl1  1  0.0  0.0  0.34  1.0
  W  W2  1  0.0  0.0  0.38  1.0

data_CaTlW
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.11
_cell_length_b   4.13
_cell_length_c   5.94
_cell_angle_alpha   110.34
_cell_angle_beta   105.18
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CaTlW
_chemical_formula_sum   'Ca1 Tl1 W1'
_cell_volume   68.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.0  0.66  0.66  1.0
  Tl  Tl1  1  0.0  0.34  0.34  1.0
  W  W2  1  0.0  0.38  0.38  1.0

Ca Tl W
Ca Tl W 0 2 o o o 0 1 o o o 1 2 o o o 
CaWTl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one CaWTl cluster. Ca(1) is bonded in a single-bond geometry to one W(1) atom. The Ca(1)-W(1) bond length is 1.66 Å. W(1) is bonded in a distorted linear geometry to one Ca(1) and one Tl(1) atom. The W(1)-Tl(1) bond length is 0.26 Å. Tl(1) is bonded in a single-bond geometry to one W(1) atom.