data_Y6Co7Sn23
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.29
_cell_length_b   9.29
_cell_length_c   11.55
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Y6Co7Sn23
_chemical_formula_sum   'Y6 Co7 Sn23'
_cell_volume   863.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y30  1  0.15  0.01  0.6  1.0
  Y  Y31  1  0.0  0.07  0.6  1.0
  Y  Y32  1  0.85  0.01  0.6  1.0
  Y  Y33  1  0.79  0.04  0.96  1.0
  Y  Y34  1  0.64  0.97  0.96  1.0
  Y  Y35  1  0.5  0.04  0.96  1.0
  Co  Co0  1  0.0  0.0  0.0  1.0
  Co  Co1  1  0.64  0.08  0.37  1.0
  Co  Co2  1  0.9  0.98  0.37  1.0
  Co  Co3  1  0.39  0.98  0.37  1.0
  Co  Co4  1  0.0  0.96  0.19  1.0
  Co  Co5  1  0.25  0.06  0.19  1.0
  Co  Co6  1  0.75  0.06  0.19  1.0
  Sn  Sn7  1  0.0  0.0  0.78  1.0
  Sn  Sn8  1  0.32  0.33  0.07  1.0
  Sn  Sn9  1  0.0  0.42  0.07  1.0
  Sn  Sn10  1  0.68  0.33  0.07  1.0
  Sn  Sn11  1  0.96  0.71  0.48  1.0
  Sn  Sn12  1  0.64  0.62  0.48  1.0
  Sn  Sn13  1  0.32  0.71  0.48  1.0
  Sn  Sn14  1  0.9  0.37  0.0  1.0
  Sn  Sn15  1  0.54  0.68  0.0  1.0
  Sn  Sn16  1  0.2  0.0  0.0  1.0
  Sn  Sn17  1  0.46  0.68  0.0  1.0
  Sn  Sn18  1  0.1  0.37  0.0  1.0
  Sn  Sn19  1  0.09  0.0  0.0  1.0
  Sn  Sn20  1  0.13  0.81  0.35  1.0
  Sn  Sn21  1  0.15  0.81  0.35  1.0
  Sn  Sn22  1  0.64  0.42  0.35  1.0
  Sn  Sn23  1  0.49  0.23  0.2  1.0
  Sn  Sn24  1  0.51  0.23  0.2  1.0
  Sn  Sn25  1  0.0  0.62  0.2  1.0
  Sn  Sn26  1  0.64  0.68  0.14  1.0
  Sn  Sn27  1  0.0  0.36  0.41  1.0
  Sn  Sn28  1  0.64  0.68  0.22  1.0
  Sn  Sn29  1  0.0  0.36  0.33  1.0

data_Y6Co7Sn23
_symmetry_space_group_name_H-M   P1
_cell_length_a   9.29
_cell_length_b   9.29
_cell_length_c   11.55
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Y6Co7Sn23
_chemical_formula_sum   'Y6 Co7 Sn23'
_cell_volume   863.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.0  0.07  0.6  1.0
  Y  Y1  1  0.15  0.01  0.6  1.0
  Y  Y2  1  0.5  0.04  0.96  1.0
  Y  Y3  1  0.64  0.97  0.96  1.0
  Y  Y4  1  0.79  0.04  0.96  1.0
  Y  Y5  1  0.85  0.01  0.6  1.0
  Co  Co6  1  0.0  0.0  0.0  1.0
  Co  Co7  1  0.0  0.96  0.19  1.0
  Co  Co8  1  0.25  0.06  0.19  1.0
  Co  Co9  1  0.39  0.98  0.37  1.0
  Co  Co10  1  0.64  0.08  0.37  1.0
  Co  Co11  1  0.75  0.06  0.19  1.0
  Co  Co12  1  0.9  0.98  0.37  1.0
  Sn  Sn13  1  0.0  0.0  0.78  1.0
  Sn  Sn14  1  0.0  0.36  0.33  1.0
  Sn  Sn15  1  0.0  0.36  0.41  1.0
  Sn  Sn16  1  0.0  0.42  0.07  1.0
  Sn  Sn17  1  0.0  0.62  0.2  1.0
  Sn  Sn18  1  0.09  0.0  0.0  1.0
  Sn  Sn19  1  0.1  0.37  0.0  1.0
  Sn  Sn20  1  0.13  0.81  0.35  1.0
  Sn  Sn21  1  0.15  0.81  0.35  1.0
  Sn  Sn22  1  0.2  0.0  0.0  1.0
  Sn  Sn23  1  0.32  0.33  0.07  1.0
  Sn  Sn24  1  0.32  0.71  0.48  1.0
  Sn  Sn25  1  0.46  0.68  0.0  1.0
  Sn  Sn26  1  0.49  0.23  0.2  1.0
  Sn  Sn27  1  0.51  0.23  0.2  1.0
  Sn  Sn28  1  0.54  0.68  0.0  1.0
  Sn  Sn29  1  0.64  0.42  0.35  1.0
  Sn  Sn30  1  0.64  0.62  0.48  1.0
  Sn  Sn31  1  0.64  0.68  0.14  1.0
  Sn  Sn32  1  0.64  0.68  0.22  1.0
  Sn  Sn33  1  0.68  0.33  0.07  1.0
  Sn  Sn34  1  0.9  0.37  0.0  1.0
  Sn  Sn35  1  0.96  0.71  0.48  1.0

Y Y Y Y Y Y Co Co Co Co Co Co Co Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn
Y Y Y Y Y Y Co Co Co Co Co Co Co Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn Sn 0 1 o o o 0 13 o o o 1 2 - o o 1 8 - - o 1 13 o o o 2 8 o - o 2 13 + o o 3 4 o - o 3 12 o o + 4 5 o + o 4 12 o + + 6 25 o o o 6 10 o - o 6 13 o o - 6 14 o o o 7 9 o - o 7 12 o o o 7 8 o - o 8 34 o o o 8 35 + + o 8 12 o + o 8 33 + + o 8 10 + o o 8 17 o o o 9 27 o o o 9 26 o o o 9 19 o o o 10 25 o + o 10 11 o + o 10 12 - + o 11 22 o o o 11 30 o o o 11 29 o o o 11 14 o o o 12 16 o o o 12 32 o - o 12 34 o - o 12 15 + o o 12 20 o o o 12 35 + o o 13 25 o o + 14 25 o o o 14 24 o o o 14 23 o o o 14 22 o o o 14 30 o o o 14 29 o o o 14 21 o o o 15 20 - o o 15 24 o o o 15 31 o o o 16 30 o o o 16 29 o o o 16 20 o o o 17 27 + o o 17 26 + o o 17 18 o o o 18 28 o o o 19 33 o o o 19 27 o o o 19 26 o o o 21 23 o o o 22 25 o o o 26 27 o o o 26 31 o o o 27 31 o o o 28 30 o o o 28 29 o o o 29 30 o o o 32 34 o o o 33 35 o o o 
Y6Co7Sn23 crystallizes in the triclinic P1 space group. There are six inequivalent Y sites. In the first Y site, Y(1) is bonded in a 3-coordinate geometry to one Y(2), one Sn(1), and one Sn(5) atom. The Y(1)-Y(2) bond length is 1.74 Å. The Y(1)-Sn(1) bond length is 2.48 Å. The Y(1)-Sn(5) bond length is 2.76 Å. In the second Y site, Y(2) is bonded in a 5-coordinate geometry to one Y(1), one Y(3), one Co(3), one Sn(1), and one Sn(21) atom. The Y(2)-Y(3) bond length is 1.20 Å. The Y(2)-Co(3) bond length is 2.81 Å. The Y(2)-Sn(1) bond length is 2.19 Å. The Y(2)-Sn(21) bond length is 3.44 Å. In the third Y site, Y(3) is bonded in a 1-coordinate geometry to one Y(2), one Co(3), one Sn(1), and one Sn(6) atom. The Y(3)-Co(3) bond length is 2.72 Å. The Y(3)-Sn(1) bond length is 2.53 Å. The Y(3)-Sn(6) bond length is 3.38 Å. In the fourth Y site, Y(4) is bonded in a 2-coordinate geometry to one Y(5), one Co(1), one Co(7), and one Sn(1) atom. The Y(4)-Y(5) bond length is 1.20 Å. The Y(4)-Co(1) bond length is 2.16 Å. The Y(4)-Co(7) bond length is 2.72 Å. The Y(4)-Sn(1) bond length is 2.97 Å. In the fifth Y site, Y(5) is bonded in a 5-coordinate geometry to one Y(4), one Y(6), one Co(7), one Sn(11), and one Sn(9) atom. The Y(5)-Y(6) bond length is 1.74 Å. The Y(5)-Co(7) bond length is 2.81 Å. The Y(5)-Sn(11) bond length is 2.47 Å. The Y(5)-Sn(9) bond length is 2.49 Å. In the sixth Y site, Y(6) is bonded in a 3-coordinate geometry to one Y(5), one Sn(10), and one Sn(4) atom. The Y(6)-Sn(10) bond length is 2.65 Å. The Y(6)-Sn(4) bond length is 2.76 Å. There are seven inequivalent Co sites. In the first Co site, Co(1) is bonded in a 2-coordinate geometry to one Y(4), one Co(5), one Sn(1), and one Sn(13) atom. The Co(1)-Co(5) bond length is 2.20 Å. The Co(1)-Sn(1) bond length is 2.58 Å. The Co(1)-Sn(13) bond length is 0.83 Å. In the second Co site, Co(2) is bonded in a 2-coordinate geometry to one Co(4), one Co(7), and one Sn(16) atom. The Co(2)-Co(4) bond length is 2.04 Å. The Co(2)-Co(7) bond length is 2.32 Å. The Co(2)-Sn(16) bond length is 3.19 Å. In the third Co site, Co(3) is bonded in a 3-coordinate geometry to one Y(2), one Y(3), one Co(5), and one Sn(6) atom. The Co(3)-Co(5) bond length is 2.32 Å. The Co(3)-Sn(6) bond length is 3.25 Å. In the fourth Co site, Co(4) is bonded in a 1-coordinate geometry to one Co(2), one Sn(15), and one Sn(7) atom. The Co(4)-Sn(15) bond length is 1.99 Å. The Co(4)-Sn(7) bond length is 2.63 Å. In the fifth Co site, Co(5) is bonded in a 9-coordinate geometry to one Co(1), one Co(3), one Co(6), one Co(7), one Sn(13), one Sn(14), one Sn(19), one Sn(20), and one Sn(22) atom. The Co(5)-Co(6) bond length is 2.04 Å. The Co(5)-Co(7) bond length is 2.91 Å. The Co(5)-Sn(13) bond length is 2.29 Å. The Co(5)-Sn(14) bond length is 2.98 Å. The Co(5)-Sn(19) bond length is 3.19 Å. The Co(5)-Sn(20) bond length is 3.07 Å. The Co(5)-Sn(22) bond length is 3.05 Å. In the sixth Co site, Co(6) is bonded in a 3-coordinate geometry to one Co(5), one Sn(10), one Sn(17), and one Sn(2) atom. The Co(6)-Sn(10) bond length is 2.24 Å. The Co(6)-Sn(17) bond length is 1.99 Å. The Co(6)-Sn(2) bond length is 2.63 Å. In the seventh Co site, Co(7) is bonded in a 3-coordinate geometry to one Y(4), one Y(5), one Co(2), and one Co(5) atom. There are twenty-three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 5-coordinate geometry to one Y(1), one Y(2), one Y(3), one Y(4), and one Co(1) atom. In the second Sn site, Sn(2) is bonded in a 3-coordinate geometry to one Co(6), one Sn(12), and one Sn(17) atom. The Sn(2)-Sn(12) bond length is 2.37 Å. The Sn(2)-Sn(17) bond length is 2.68 Å. In the third Sn site, Sn(3) is bonded in a 2-coordinate geometry to one Sn(12), one Sn(19), and one Sn(8) atom. The Sn(3)-Sn(12) bond length is 1.50 Å. The Sn(3)-Sn(19) bond length is 2.39 Å. The Sn(3)-Sn(8) bond length is 1.15 Å. In the fourth Sn site, Sn(4) is bonded in a 3-coordinate geometry to one Y(6), one Sn(18), one Sn(19), and one Sn(8) atom. The Sn(4)-Sn(18) bond length is 2.06 Å. The Sn(4)-Sn(19) bond length is 3.21 Å. The Sn(4)-Sn(8) bond length is 2.07 Å. In the fifth Sn site, Sn(5) is bonded in a distorted L-shaped geometry to one Y(1), one Sn(14), one Sn(16), and one Sn(6) atom. The Sn(5)-Sn(14) bond length is 2.06 Å. The Sn(5)-Sn(16) bond length is 3.21 Å. The Sn(5)-Sn(6) bond length is 2.65 Å. In the sixth Sn site, Sn(6) is bonded in a 6-coordinate geometry to one Y(3), one Co(3), one Sn(16), one Sn(22), one Sn(5), and one Sn(7) atom. The Sn(6)-Sn(16) bond length is 2.39 Å. The Sn(6)-Sn(22) bond length is 3.02 Å. The Sn(6)-Sn(7) bond length is 3.45 Å. In the seventh Sn site, Sn(7) is bonded in a 1-coordinate geometry to one Co(4) and one Sn(6) atom. In the eighth Sn site, Sn(8) is bonded in a 1-coordinate geometry to one Sn(3) and one Sn(4) atom. In the ninth Sn site, Sn(9) is bonded in a 3-coordinate geometry to one Y(5), one Sn(11), and one Sn(20) atom. The Sn(9)-Sn(11) bond length is 0.83 Å. The Sn(9)-Sn(20) bond length is 1.85 Å. In the tenth Sn site, Sn(10) is bonded in a distorted T-shaped geometry to one Y(6), one Co(6), and one Sn(13) atom. The Sn(10)-Sn(13) bond length is 1.01 Å. In the eleventh Sn site, Sn(11) is bonded in a 1-coordinate geometry to one Y(5) and one Sn(9) atom. In the twelfth Sn site, Sn(12) is bonded in a 1-coordinate geometry to one Sn(2) and one Sn(3) atom. In the thirteenth Sn site, Sn(13) is bonded in a distorted linear geometry to one Co(1), one Co(5), and one Sn(10) atom. In the fourteenth Sn site, Sn(14) is bonded in a single-bond geometry to one Co(5), one Sn(15), one Sn(19), and one Sn(5) atom. The Sn(14)-Sn(15) bond length is 0.17 Å. The Sn(14)-Sn(19) bond length is 2.30 Å. In the fifteenth Sn site, Sn(15) is bonded in a single-bond geometry to one Co(4), one Sn(14), and one Sn(19) atom. The Sn(15)-Sn(19) bond length is 2.34 Å. In the sixteenth Sn site, Sn(16) is bonded in a 7-coordinate geometry to one Co(2), one Sn(17), one Sn(18), one Sn(19), one Sn(22), one Sn(5), and one Sn(6) atom. The Sn(16)-Sn(17) bond length is 2.34 Å. The Sn(16)-Sn(18) bond length is 2.30 Å. The Sn(16)-Sn(19) bond length is 3.33 Å. The Sn(16)-Sn(22) bond length is 2.79 Å. In the seventeenth Sn site, Sn(17) is bonded in a single-bond geometry to one Co(6), one Sn(16), one Sn(18), and one Sn(2) atom. The Sn(17)-Sn(18) bond length is 0.17 Å. In the eighteenth Sn site, Sn(18) is bonded in a single-bond geometry to one Sn(16), one Sn(17), and one Sn(4) atom. In the nineteenth Sn site, Sn(19) is bonded in a 7-coordinate geometry to one Co(5), one Sn(14), one Sn(15), one Sn(16), one Sn(23), one Sn(3), and one Sn(4) atom. The Sn(19)-Sn(23) bond length is 2.79 Å. In the twentieth Sn site, Sn(20) is bonded in a distorted bent 150 degrees geometry to one Co(5), one Sn(22), and one Sn(9) atom. The Sn(20)-Sn(22) bond length is 0.97 Å. In the twenty-first Sn site, Sn(21) is bonded in a single-bond geometry to one Y(2) and one Sn(23) atom. The Sn(21)-Sn(23) bond length is 0.97 Å. In the twenty-second Sn site, Sn(22) is bonded in a single-bond geometry to one Co(5), one Sn(16), one Sn(20), and one Sn(6) atom. In the twenty-third Sn site, Sn(23) is bonded in a single-bond geometry to one Sn(19) and one Sn(21) atom.