data_YMo2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.92
_cell_length_b   4.97
_cell_length_c   5.01
_cell_angle_alpha   90.0
_cell_angle_beta   100.15
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   YMo2Rh
_chemical_formula_sum   'Y1 Mo2 Rh1'
_cell_volume   71.68
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y3  1  0.0  0.0  0.0  1.0
  Mo  Mo0  1  0.86  0.48  0.21  1.0
  Mo  Mo1  1  0.18  0.48  0.73  1.0
  Rh  Rh2  1  0.02  0.0  0.47  1.0

data_YMo2Rh
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.92
_cell_length_b   4.97
_cell_length_c   5.01
_cell_angle_alpha   90.0
_cell_angle_beta   100.15
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   YMo2Rh
_chemical_formula_sum   'Y1 Mo2 Rh1'
_cell_volume   71.68
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.0  0.0  0.0  1.0
  Mo  Mo1  1  0.18  0.48  0.73  1.0
  Mo  Mo2  1  0.86  0.48  0.21  1.0
  Rh  Rh3  1  0.02  0.0  0.47  1.0

Y Mo Mo Rh
Y Mo Mo Rh 0 1 - - o 0 1 - o o 0 0 + o o 0 2 o - - 0 2 o o - 0 3 o o - 0 3 o o o 1 2 o o - 1 2 + o - 1 2 + o o 1 1 + o o 1 3 + o o 1 3 + + o 2 3 o o o 2 3 o + o 2 2 + o o 3 3 + o o 
YMo2Rh crystallizes in the triclinic P1 space group. Y(1) is bonded in a 6-coordinate geometry to two equivalent Mo(1), two equivalent Mo(2), and two equivalent Rh(1) atoms. There is one shorter (2.68 Å) and one longer (2.83 Å) Y(1)-Mo(1) bond length. There is one shorter (2.86 Å) and one longer (2.99 Å) Y(1)-Mo(2) bond length. There is one shorter (2.34 Å) and one longer (2.68 Å) Y(1)-Rh(1) bond length. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 2-coordinate geometry to two equivalent Y(1) and three equivalent Mo(2) atoms. There are a spread of Mo(1)-Mo(2) bond distances ranging from 2.61-2.84 Å. In the second Mo site, Mo(2) is bonded in a 9-coordinate geometry to two equivalent Y(1), two equivalent Mo(2), three equivalent Mo(1), and two equivalent Rh(1) atoms. Both Mo(2)-Mo(2) bond lengths are 2.92 Å. There is one shorter (2.73 Å) and one longer (2.88 Å) Mo(2)-Rh(1) bond length. Rh(1) is bonded in a 2-coordinate geometry to two equivalent Y(1) and two equivalent Mo(2) atoms.