data_Cd2MoW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.77
_cell_length_b   2.77
_cell_length_c   9.47
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2MoW
_chemical_formula_sum   'Cd2 Mo1 W1'
_cell_volume   72.58
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.0  0.36  1.0
  Cd  Cd1  1  0.38  0.38  0.48  1.0
  Mo  Mo2  1  0.0  0.0  0.79  1.0
  W  W3  1  0.38  0.38  0.04  1.0

data_Cd2MoW
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.92
_cell_length_b   3.92
_cell_length_c   9.47
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Cd2MoW
_chemical_formula_sum   'Cd4 Mo2 W2'
_cell_volume   145.17
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  2  0.0  0.0  0.36  1.0
  Cd  Cd1  2  0.38  0.0  0.48  1.0
  Mo  Mo2  2  0.0  0.0  0.79  1.0
  W  W3  2  0.38  0.0  0.04  1.0

Cd Cd Mo W
Cd Cd Mo W 0 1 - o o 0 1 o - o 0 1 o o o 0 3 o o o 1 2 o o o 2 3 - o + 2 3 o - + 2 3 o o + 2 2 + o o 2 2 o + o 3 3 + o o 3 3 o + o 
WMoCd2 crystallizes in the monoclinic Cm space group. W(1) is bonded in a 11-coordinate geometry to four equivalent W(1), four equivalent Mo(1), and three equivalent Cd(1) atoms. All W(1)-W(1) bond lengths are 2.77 Å. There are a spread of W(1)-Mo(1) bond distances ranging from 2.82-3.39 Å. There is one shorter (3.37 Å) and two longer (3.62 Å) W(1)-Cd(1) bond lengths. Mo(1) is bonded in a 11-coordinate geometry to four equivalent W(1), four equivalent Mo(1), and three equivalent Cd(2) atoms. All Mo(1)-Mo(1) bond lengths are 2.77 Å. There is one shorter (3.33 Å) and two longer (3.59 Å) Mo(1)-Cd(2) bond lengths. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 1-coordinate geometry to three equivalent W(1) and one Cd(2) atom. The Cd(1)-Cd(2) bond length is 1.86 Å. In the second Cd site, Cd(2) is bonded in a 1-coordinate geometry to three equivalent Mo(1) and one Cd(1) atom.