data_Al24Rh5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.52
_cell_length_b   8.52
_cell_length_c   8.52
_cell_angle_alpha   109.47
_cell_angle_beta   109.47
_cell_angle_gamma   109.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Al24Rh5
_chemical_formula_sum   'Al24 Rh5'
_cell_volume   476.41
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.86  0.14  0.74  1.0
  Al  Al1  1  0.14  0.86  0.74  1.0
  Al  Al2  1  0.86  0.86  0.1  1.0
  Al  Al3  1  0.06  0.06  0.18  1.0
  Al  Al4  1  0.86  0.1  0.86  1.0
  Al  Al5  1  0.06  0.18  0.06  1.0
  Al  Al6  1  0.14  0.74  0.86  1.0
  Al  Al7  1  0.86  0.74  0.14  1.0
  Al  Al8  1  0.74  0.14  0.86  1.0
  Al  Al9  1  0.74  0.86  0.14  1.0
  Al  Al10  1  0.18  0.06  0.06  1.0
  Al  Al11  1  0.1  0.86  0.86  1.0
  Al  Al12  1  0.67  0.33  0.37  1.0
  Al  Al13  1  0.33  0.67  0.37  1.0
  Al  Al14  1  0.59  0.59  0.55  1.0
  Al  Al15  1  0.33  0.33  0.47  1.0
  Al  Al16  1  0.59  0.55  0.59  1.0
  Al  Al17  1  0.33  0.47  0.33  1.0
  Al  Al18  1  0.33  0.37  0.67  1.0
  Al  Al19  1  0.67  0.37  0.33  1.0
  Al  Al20  1  0.37  0.33  0.67  1.0
  Al  Al21  1  0.37  0.67  0.33  1.0
  Al  Al22  1  0.47  0.33  0.33  1.0
  Al  Al23  1  0.55  0.59  0.59  1.0
  Rh  Rh24  1  0.62  0.38  0.62  1.0
  Rh  Rh25  1  0.38  0.62  0.62  1.0
  Rh  Rh26  1  0.62  0.62  0.38  1.0
  Rh  Rh27  1  0.3  0.3  0.3  1.0
  Rh  Rh28  1  0.0  0.0  0.0  1.0

data_Al24Rh5
_symmetry_space_group_name_H-M   R3m
_cell_length_a   13.92
_cell_length_b   13.92
_cell_length_c   8.52
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   Al24Rh5
_chemical_formula_sum   'Al72 Rh15'
_cell_volume   1429.24
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+2/3, y+1/3, z+1/3'
  8  '-y+2/3, x-y+1/3, z+1/3'
  9  '-x+y+2/3, -x+1/3, z+1/3'
  10  '-y+2/3, -x+1/3, z+1/3'
  11  '-x+y+2/3, y+1/3, z+1/3'
  12  'x+2/3, x-y+1/3, z+1/3'
  13  'x+1/3, y+2/3, z+2/3'
  14  '-y+1/3, x-y+2/3, z+2/3'
  15  '-x+y+1/3, -x+2/3, z+2/3'
  16  '-y+1/3, -x+2/3, z+2/3'
  17  '-x+y+1/3, y+2/3, z+2/3'
  18  'x+1/3, x-y+2/3, z+2/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  18  0.16  0.44  0.58  1.0
  Al  Al1  18  0.21  0.46  0.12  1.0
  Al  Al2  9  0.01  0.03  0.57  1.0
  Al  Al3  9  0.08  0.04  0.1  1.0
  Al  Al4  9  0.09  0.04  0.38  1.0
  Al  Al5  9  0.16  0.08  0.94  1.0
  Rh  Rh6  9  0.08  0.17  0.54  1.0
  Rh  Rh7  3  0.0  0.0  -0.0  1.0
  Rh  Rh8  3  0.0  0.0  0.3  1.0

Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Rh Rh Rh Rh Rh
Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Rh Rh Rh Rh Rh 0 4 o o o 1 11 o o o 2 9 o o o 2 7 o o o 3 28 o o o 4 8 o o o 5 28 o o o 6 11 o o o 10 28 o o o 12 19 o o o 12 24 o o o 13 21 o o o 13 25 o o o 14 23 o o o 14 16 o o o 14 24 o o o 14 25 o o o 14 26 o o o 15 27 o o o 15 24 o o o 15 25 o o o 16 23 o o o 16 24 o o o 16 25 o o o 16 26 o o o 17 27 o o o 17 25 o o o 17 26 o o o 18 20 o o o 18 25 o o o 19 26 o o o 20 24 o o o 21 26 o o o 22 27 o o o 22 24 o o o 22 26 o o o 23 24 o o o 23 25 o o o 23 26 o o o 
RhAl12(Al3Rh)4 is Indium-like structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three Al3Rh clusters and three RhAl12 clusters. In each Al3Rh cluster, there are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted single-bond geometry to one Al(5) and two equivalent Al(4) atoms. The Rh(1)-Al(5) bond length is 1.69 Å. Both Rh(1)-Al(4) bond lengths are 2.22 Å. In the second Rh site, Rh(2) is bonded in a 3-coordinate geometry to three equivalent Al(6) atoms. All Rh(2)-Al(6) bond lengths are 1.28 Å. There are three inequivalent Al sites. In the first Al site, Al(4) is bonded in a 3-coordinate geometry to one Rh(1), one Al(4), and one Al(6) atom. The Al(4)-Al(4) bond length is 0.56 Å. The Al(4)-Al(6) bond length is 1.62 Å. In the second Al site, Al(5) is bonded in a 3-coordinate geometry to one Rh(1) and two equivalent Al(5) atoms. Both Al(5)-Al(5) bond lengths are 0.56 Å. In the third Al site, Al(6) is bonded in a single-bond geometry to one Rh(2) and two equivalent Al(4) atoms. In each RhAl12 cluster, Rh(3) is bonded in a 3-coordinate geometry to three equivalent Al(2) and three equivalent Al(3) atoms. All Rh(3)-Al(2) bond lengths are 1.98 Å. All Rh(3)-Al(3) bond lengths are 1.29 Å. There are three inequivalent Al sites. In the first Al site, Al(1) is bonded in a single-bond geometry to one Al(2) atom. The Al(1)-Al(2) bond length is 1.18 Å. In the second Al site, Al(2) is bonded in a distorted rectangular see-saw-like geometry to one Rh(3), one Al(3), and two equivalent Al(1) atoms. The Al(2)-Al(3) bond length is 1.64 Å. In the third Al site, Al(3) is bonded in a distorted single-bond geometry to one Rh(3) and one Al(2) atom.