data_LaPdCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.04
_cell_length_b   6.04
_cell_length_c   6.04
_cell_angle_alpha   144.64
_cell_angle_beta   144.64
_cell_angle_gamma   50.86
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaPdCl
_chemical_formula_sum   'La1 Pd1 Cl1'
_cell_volume   73.45
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La1  1  0.0  0.0  0.54  1.0
  Pd  Pd2  1  0.0  0.0  0.49  1.0
  Cl  Cl0  1  0.0  0.0  0.79  1.0

data_LaPdCl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.19
_cell_length_b   5.19
_cell_length_c   6.04
_cell_angle_alpha   90.0
_cell_angle_beta   115.43
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LaPdCl
_chemical_formula_sum   'La2 Pd2 Cl2'
_cell_volume   146.9
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  2  0.0  0.0  0.46  1.0
  Pd  Pd1  2  0.0  0.0  0.51  1.0
  Cl  Cl2  2  0.0  0.0  0.21  1.0

La Pd Cl
La Pd Cl 0 1 o o o 0 2 o o o 1 2 o o o 
LaPdCl is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two LaPdCl clusters. La(1) is bonded in a linear geometry to one Pd(1) and one Cl(1) atom. The La(1)-Pd(1) bond length is 0.29 Å. The La(1)-Cl(1) bond length is 1.52 Å. Pd(1) is bonded in a single-bond geometry to one La(1) atom. Cl(1) is bonded in a single-bond geometry to one La(1) atom.