data_SnCS(NCl)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.02
_cell_length_b   15.4
_cell_length_c   8.65
_cell_angle_alpha   90.0
_cell_angle_beta   105.66
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SnCS(NCl)2
_chemical_formula_sum   'Sn4 C4 S4 N8 Cl8'
_cell_volume   771.93
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.09  0.64  0.07  1.0
  Sn  Sn1  1  0.76  0.94  0.09  1.0
  Sn  Sn2  1  0.6  0.76  0.26  1.0
  Sn  Sn3  1  0.92  0.46  0.24  1.0
  C  C4  1  0.68  0.49  0.52  1.0
  C  C5  1  0.18  0.79  0.64  1.0
  C  C6  1  0.01  0.91  0.81  1.0
  C  C7  1  0.51  0.61  0.69  1.0
  S  S8  1  0.88  0.31  0.19  1.0
  S  S9  1  0.97  0.61  0.97  1.0
  S  S10  1  0.8  0.09  0.14  1.0
  S  S11  1  0.72  0.79  0.36  1.0
  N  N12  1  0.21  0.42  0.75  1.0
  N  N13  1  0.64  0.12  0.41  1.0
  N  N14  1  0.47  0.98  0.58  1.0
  N  N15  1  0.04  0.28  0.92  1.0
  N  N16  1  0.33  0.27  0.22  1.0
  N  N17  1  0.52  0.57  0.95  1.0
  N  N18  1  0.35  0.13  0.11  1.0
  N  N19  1  0.17  0.83  0.38  1.0
  Cl  Cl20  1  0.21  0.82  0.65  1.0
  Cl  Cl21  1  0.31  0.12  0.85  1.0
  Cl  Cl22  1  0.48  0.58  0.68  1.0
  Cl  Cl23  1  0.38  0.28  0.48  1.0
  Cl  Cl24  1  0.7  0.76  0.44  1.0
  Cl  Cl25  1  0.15  0.06  0.72  1.0
  Cl  Cl26  1  0.98  0.64  0.89  1.0
  Cl  Cl27  1  0.54  0.34  0.61  1.0

data_SnCS(NCl)2
_symmetry_space_group_name_H-M   P-1
_cell_length_a   6.02
_cell_length_b   8.65
_cell_length_c   15.4
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   105.66
_symmetry_Int_Tables_number   2
_chemical_formula_structural   SnCS(NCl)2
_chemical_formula_sum   'Sn4 C4 S4 N8 Cl8'
_cell_volume   771.93
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  2  0.08  0.57  0.76  1.0
  Sn  Sn1  2  0.25  0.41  0.94  1.0
  C  C2  2  0.17  0.14  0.21  1.0
  C  C3  2  0.33  0.98  0.09  1.0
  S  S4  2  0.04  0.53  0.61  1.0
  S  S5  2  0.13  0.31  0.91  1.0
  N  N6  2  0.2  0.25  0.58  1.0
  N  N7  2  0.32  0.72  0.13  1.0
  N  N8  2  0.37  0.09  0.72  1.0
  N  N9  2  0.49  0.55  0.57  1.0
  Cl  Cl10  2  0.14  0.22  0.94  1.0
  Cl  Cl11  2  0.31  0.06  0.36  1.0
  Cl  Cl12  2  0.37  0.98  0.12  1.0
  Cl  Cl13  2  0.47  0.18  0.42  1.0

Sn Sn Sn Sn C C C C S S S S N N N N N N N N Cl Cl Cl Cl Cl Cl Cl Cl
Sn Sn Sn Sn C C C C S S S S N N N N N N N N Cl Cl Cl Cl Cl Cl Cl Cl 0 9 - o - 1 10 o + o 2 11 o o o 3 8 o o o 4 27 o o o 4 22 o o o 4 7 o o o 4 12 + o o 5 20 o o o 5 6 o o o 5 14 o o o 5 19 o o o 6 20 o o o 6 25 o + o 6 14 - o o 7 22 o o o 7 12 o o o 7 17 o o o 8 16 + o o 8 15 + o - 9 26 o o o 10 18 o o o 10 13 o o o 11 24 o o o 12 15 o o o 12 27 o o o 12 23 o o o 12 22 o o o 12 17 o o o 13 14 o - o 13 18 o o o 13 16 o o o 13 23 o o o 14 19 o o o 14 20 o o o 14 25 o + o 14 21 o + o 15 21 o o o 15 18 o o + 15 16 o o + 16 18 o o o 16 23 o o o 17 22 o o o 18 21 o o - 19 20 o o o 21 25 o o o 23 27 o o o 
SnSN2ClCCNSnSClNCl2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonia atoms, two ClCCN clusters, two NCl2 clusters, two SnS clusters, and two SnSCl clusters. In each ClCCN cluster, there are two inequivalent C sites. In the first C site, C(2) is bonded in a single-bond geometry to one Cl(1) atom. The C(2)-Cl(1) bond length is 0.50 Å. In the second C site, C(1) is bonded in a distorted single-bond geometry to one Cl(1) atom. The C(1)-Cl(1) bond length is 2.49 Å. N(4) is bonded in a single-bond geometry to one Cl(1) atom. The N(4)-Cl(1) bond length is 2.25 Å. Cl(1) is bonded in a single-bond geometry to one C(1), one C(2), and one N(4) atom. In each NCl2 cluster, N(3) is bonded in a single-bond geometry to one Cl(2) atom. The N(3)-Cl(2) bond length is 2.25 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Cl(2) atom. The Cl(4)-Cl(2) bond length is 1.55 Å. In the second Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one N(3) and one Cl(4) atom. In each SnS cluster, Sn(2) is bonded in a single-bond geometry to one S(1) atom. The Sn(2)-S(1) bond length is 2.35 Å. S(1) is bonded in a single-bond geometry to one Sn(2) atom. In each SnSCl cluster, Sn(1) is bonded in a single-bond geometry to one S(2) atom. The Sn(1)-S(2) bond length is 1.07 Å. S(2) is bonded in a water-like geometry to one Sn(1) and one Cl(3) atom. The S(2)-Cl(3) bond length is 0.92 Å. Cl(3) is bonded in a single-bond geometry to one S(2) atom.