data_NbNiP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.2
_cell_length_b   4.02
_cell_length_c   4.17
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NbNiP2
_chemical_formula_sum   'Nb1 Ni1 P2'
_cell_volume   53.68
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.6  0.01  0.0  1.0
  Ni  Ni1  1  0.6  0.0  0.09  1.0
  P  P2  1  0.0  0.0  0.0  1.0
  P  P3  1  0.0  0.01  0.09  1.0

data_NbNiP2
_symmetry_space_group_name_H-M   Pm
_cell_length_a   3.2
_cell_length_b   4.02
_cell_length_c   4.17
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   NbNiP2
_chemical_formula_sum   'Nb1 Ni1 P2'
_cell_volume   53.68
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.6  0.0  0.0  1.0
  Ni  Ni1  1  0.6  0.0  0.09  1.0
  P  P2  1  0.0  0.0  0.0  1.0
  P  P3  1  0.0  0.0  0.09  1.0

Nb Ni P P
Nb Ni P P 0 1 o o o 2 3 o o o 
NiNb(P)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 12034-55-8 molecule and one phosphane molecule.