data_RuOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.62
_cell_length_b   9.51
_cell_length_c   12.83
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   RuOF4
_chemical_formula_sum   'Ru8 O8 F32'
_cell_volume   685.76
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.22  0.29  0.78  1.0
  Ru  Ru1  1  0.6  0.21  0.2  1.0
  Ru  Ru2  1  0.83  0.58  0.24  1.0
  Ru  Ru3  1  0.79  0.34  0.18  1.0
  Ru  Ru4  1  0.64  0.17  0.59  1.0
  Ru  Ru5  1  0.98  0.92  0.66  1.0
  Ru  Ru6  1  0.03  0.97  0.05  1.0
  Ru  Ru7  1  0.41  0.54  0.64  1.0
  O  O8  1  0.81  0.77  0.42  1.0
  O  O9  1  0.09  0.76  0.03  1.0
  O  O10  1  0.53  0.51  0.39  1.0
  O  O11  1  0.34  0.75  0.45  1.0
  O  O12  1  0.81  0.01  0.83  1.0
  O  O13  1  1.0  0.74  0.0  1.0
  O  O14  1  0.28  1.0  0.8  1.0
  O  O15  1  0.63  0.49  0.41  1.0
  F  F16  1  0.71  0.55  0.76  1.0
  F  F17  1  0.87  0.27  0.33  1.0
  F  F18  1  0.85  0.13  0.37  1.0
  F  F19  1  0.91  0.3  0.66  1.0
  F  F20  1  0.67  0.99  0.77  1.0
  F  F21  1  0.94  0.24  0.91  1.0
  F  F22  1  0.31  0.48  0.13  1.0
  F  F23  1  0.95  0.74  0.48  1.0
  F  F24  1  0.54  0.05  0.24  1.0
  F  F25  1  0.15  0.89  0.63  1.0
  F  F26  1  0.5  0.03  0.72  1.0
  F  F27  1  0.14  0.51  0.35  1.0
  F  F28  1  0.04  0.13  0.46  1.0
  F  F29  1  0.89  0.46  0.83  1.0
  F  F30  1  0.66  0.61  0.04  1.0
  F  F31  1  0.47  0.64  0.79  1.0
  F  F32  1  0.48  0.76  0.06  1.0
  F  F33  1  0.23  0.35  0.93  1.0
  F  F34  1  0.42  0.41  0.9  1.0
  F  F35  1  0.96  0.86  0.2  1.0
  F  F36  1  0.73  0.7  0.59  1.0
  F  F37  1  0.13  0.78  0.7  1.0
  F  F38  1  0.08  0.8  0.01  1.0
  F  F39  1  0.39  0.1  0.32  1.0
  F  F40  1  0.21  0.16  0.52  1.0
  F  F41  1  0.75  0.02  0.92  1.0
  F  F42  1  0.58  0.38  0.96  1.0
  F  F43  1  0.68  0.49  0.51  1.0
  F  F44  1  0.77  0.37  0.88  1.0
  F  F45  1  0.31  0.73  0.12  1.0
  F  F46  1  0.72  0.95  0.17  1.0
  F  F47  1  0.9  0.2  0.08  1.0

data_RuOF4
_symmetry_space_group_name_H-M   P1
_cell_length_a   5.62
_cell_length_b   9.51
_cell_length_c   12.83
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   RuOF4
_chemical_formula_sum   'Ru8 O8 F32'
_cell_volume   685.76
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.03  0.97  0.05  1.0
  Ru  Ru1  1  0.22  0.29  0.78  1.0
  Ru  Ru2  1  0.41  0.54  0.64  1.0
  Ru  Ru3  1  0.6  0.21  0.2  1.0
  Ru  Ru4  1  0.64  0.17  0.59  1.0
  Ru  Ru5  1  0.79  0.34  0.18  1.0
  Ru  Ru6  1  0.83  0.58  0.24  1.0
  Ru  Ru7  1  0.98  0.92  0.66  1.0
  O  O8  1  0.09  0.76  0.03  1.0
  O  O9  1  0.28  1.0  0.8  1.0
  O  O10  1  0.34  0.75  0.45  1.0
  O  O11  1  0.53  0.51  0.39  1.0
  O  O12  1  0.63  0.49  0.41  1.0
  O  O13  1  0.81  0.01  0.83  1.0
  O  O14  1  0.81  0.77  0.42  1.0
  O  O15  1  1.0  0.74  0.0  1.0
  F  F16  1  0.04  0.13  0.46  1.0
  F  F17  1  0.08  0.8  0.01  1.0
  F  F18  1  0.13  0.78  0.7  1.0
  F  F19  1  0.14  0.51  0.35  1.0
  F  F20  1  0.15  0.89  0.63  1.0
  F  F21  1  0.21  0.16  0.52  1.0
  F  F22  1  0.23  0.35  0.93  1.0
  F  F23  1  0.31  0.73  0.12  1.0
  F  F24  1  0.31  0.48  0.13  1.0
  F  F25  1  0.39  0.1  0.32  1.0
  F  F26  1  0.42  0.41  0.9  1.0
  F  F27  1  0.47  0.64  0.79  1.0
  F  F28  1  0.48  0.76  0.06  1.0
  F  F29  1  0.5  0.03  0.72  1.0
  F  F30  1  0.54  0.05  0.24  1.0
  F  F31  1  0.58  0.38  0.96  1.0
  F  F32  1  0.66  0.61  0.04  1.0
  F  F33  1  0.67  0.99  0.77  1.0
  F  F34  1  0.68  0.49  0.51  1.0
  F  F35  1  0.71  0.55  0.76  1.0
  F  F36  1  0.72  0.95  0.17  1.0
  F  F37  1  0.73  0.7  0.59  1.0
  F  F38  1  0.75  0.02  0.92  1.0
  F  F39  1  0.77  0.37  0.88  1.0
  F  F40  1  0.85  0.13  0.37  1.0
  F  F41  1  0.87  0.27  0.33  1.0
  F  F42  1  0.89  0.46  0.83  1.0
  F  F43  1  0.9  0.2  0.08  1.0
  F  F44  1  0.91  0.3  0.66  1.0
  F  F45  1  0.94  0.24  0.91  1.0
  F  F46  1  0.95  0.74  0.48  1.0
  F  F47  1  0.96  0.86  0.2  1.0

Ru Ru Ru Ru Ru Ru Ru Ru O O O O O O O O F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F
Ru Ru Ru Ru Ru Ru Ru Ru O O O O O O O O F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F 0 21 - o o 0 19 - o o 0 29 - o o 0 34 o o o 0 33 o o o 1 24 o o o 1 3 o o o 1 22 o o o 1 47 o o o 2 3 o o o 2 15 o o o 2 10 o o o 2 30 o o o 2 8 o o o 2 27 + o o 2 35 o o o 2 22 + o o 3 47 o o o 3 22 + o o 3 22 o o o 4 40 o o o 4 26 o o o 4 19 o o o 5 25 + o o 5 37 + o o 6 35 - o o 6 38 o o o 6 9 o o o 6 47 - + o 7 43 o o o 7 36 o o o 7 31 o o o 7 16 o o o 8 23 o o o 8 11 + o o 8 11 o o o 8 36 o o o 9 13 - o o 9 38 o o o 9 22 o o o 10 15 o o o 10 11 o o o 10 27 o o o 11 27 o o o 11 23 - o o 11 25 o o o 11 15 o o o 11 36 o o o 12 20 o - o 12 41 o o o 13 38 + o o 14 26 o + o 15 27 o o o 15 43 o o o 16 31 o o o 16 29 o o o 17 18 o o o 17 27 + o o 18 28 + o o 19 29 o o o 20 26 o + o 21 44 o o o 21 33 + o o 21 47 o o + 22 33 o o - 22 45 o o o 22 27 o o o 22 42 o o - 22 34 o o - 22 32 o o o 22 30 o o o 23 36 o o o 24 39 o o o 24 46 o - o 25 37 o o o 28 40 o o o 29 44 o o o 30 32 o o o 32 45 o o o 33 34 o o o 34 42 o o o 35 46 o o o 36 43 o o o 42 44 o o o 
(Ru4(OF5)3)4O2(OF)2F2 crystallizes in the triclinic P1 space group. The structure consists of one hydrofluoric acid atom, one hypofluorous acid molecule, and one water atom inside a Ru4(OF5)3 framework. In the Ru4(OF5)3 framework, there are eight inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a 5-coordinate geometry to one F(14), one F(18), one F(19), one F(4), and one F(6) atom. The Ru(1)-F(14) bond length is 2.47 Å. The Ru(1)-F(18) bond length is 2.05 Å. The Ru(1)-F(19) bond length is 2.19 Å. The Ru(1)-F(4) bond length is 2.29 Å. The Ru(1)-F(6) bond length is 2.33 Å. In the second Ru site, Ru(2) is bonded in a distorted single-bond geometry to one F(2), one F(24), one F(32), and one F(9) atom. The Ru(2)-F(2) bond length is 2.33 Å. The Ru(2)-F(24) bond length is 2.19 Å. The Ru(2)-F(32) bond length is 2.29 Å. The Ru(2)-F(9) bond length is 1.70 Å. In the third Ru site, Ru(3) is bonded in a 1-coordinate geometry to one F(12), one F(15), and one F(20) atom. The Ru(3)-F(12) bond length is 2.34 Å. The Ru(3)-F(15) bond length is 2.70 Å. The Ru(3)-F(20) bond length is 2.79 Å. In the fourth Ru site, Ru(4) is bonded in a 2-coordinate geometry to one F(2) and one F(32) atom. The Ru(4)-F(2) bond length is 2.09 Å. The Ru(4)-F(32) bond length is 1.89 Å. In the fifth Ru site, Ru(5) is bonded in a 3-coordinate geometry to one F(11), one F(25), and one F(4) atom. The Ru(5)-F(11) bond length is 2.26 Å. The Ru(5)-F(25) bond length is 2.66 Å. The Ru(5)-F(4) bond length is 2.15 Å. In the sixth Ru site, Ru(6) is bonded in a distorted single-bond geometry to one F(10), one F(21), one F(22), and one F(5) atom. The Ru(6)-F(10) bond length is 1.07 Å. The Ru(6)-F(21) bond length is 2.66 Å. The Ru(6)-F(22) bond length is 1.69 Å. The Ru(6)-F(5) bond length is 2.34 Å. In the seventh Ru site, Ru(7) is bonded in a 5-coordinate geometry to one F(20), one F(23), one F(26), one F(31), and one F(32) atom. The Ru(7)-F(20) bond length is 2.22 Å. The Ru(7)-F(23) bond length is 1.70 Å. The Ru(7)-F(26) bond length is 2.33 Å. The Ru(7)-F(31) bond length is 2.29 Å. The Ru(7)-F(32) bond length is 2.37 Å. In the eighth Ru site, Ru(8) is bonded in a 4-coordinate geometry to one F(1), one F(16), one F(21), and one F(28) atom. The Ru(8)-F(1) bond length is 2.29 Å. The Ru(8)-F(16) bond length is 2.22 Å. The Ru(8)-F(21) bond length is 2.47 Å. The Ru(8)-F(28) bond length is 2.33 Å. There are six inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one O(6), one F(23), and one F(30) atom. The O(2)-O(6) bond length is 0.65 Å. The O(2)-F(23) bond length is 0.56 Å. The O(2)-F(30) bond length is 1.66 Å. In the second O site, O(3) is bonded in a distorted single-bond geometry to one O(8) atom. The O(3)-O(8) bond length is 0.65 Å. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one F(26) and one F(5) atom. The O(5)-F(26) bond length is 1.25 Å. The O(5)-F(5) bond length is 1.13 Å. In the fourth O site, O(6) is bonded in a 2-coordinate geometry to one O(2) and one F(23) atom. The O(6)-F(23) bond length is 0.77 Å. In the fifth O site, O(7) is bonded in a single-bond geometry to one F(11) atom. The O(7)-F(11) bond length is 1.66 Å. In the sixth O site, O(8) is bonded in a 2-coordinate geometry to one O(3) and one F(28) atom. The O(8)-F(28) bond length is 1.25 Å. There are thirty inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Ru(8), one F(14), and one F(16) atom. The F(1)-F(14) bond length is 1.65 Å. The F(1)-F(16) bond length is 1.65 Å. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Ru(2), one Ru(4), and one F(3) atom. The F(2)-F(3) bond length is 1.47 Å. In the third F site, F(3) is bonded in a water-like geometry to one F(13) and one F(2) atom. The F(3)-F(13) bond length is 1.54 Å. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one Ru(1) and one Ru(5) atom. In the fifth F site, F(5) is bonded in a distorted single-bond geometry to one Ru(6), one O(5), and one F(11) atom. The F(5)-F(11) bond length is 1.21 Å. In the sixth F site, F(6) is bonded in an L-shaped geometry to one Ru(1) and one F(29) atom. The F(6)-F(29) bond length is 1.63 Å. In the seventh F site, F(9) is bonded in a distorted single-bond geometry to one Ru(2), one F(24), and one F(31) atom. The F(9)-F(24) bond length is 1.32 Å. The F(9)-F(31) bond length is 1.65 Å. In the eighth F site, F(10) is bonded in a single-bond geometry to one Ru(6) and one F(22) atom. The F(10)-F(22) bond length is 1.40 Å. In the ninth F site, F(11) is bonded in a 3-coordinate geometry to one Ru(5), one O(7), and one F(5) atom. In the tenth F site, F(12) is bonded in a single-bond geometry to one Ru(3) atom. In the eleventh F site, F(13) is bonded in a distorted linear geometry to one F(25) and one F(3) atom. The F(13)-F(25) bond length is 1.20 Å. In the twelfth F site, F(14) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one F(1), and one F(29) atom. The F(14)-F(29) bond length is 1.22 Å. In the thirteenth F site, F(15) is bonded in a water-like geometry to one Ru(3) and one F(17) atom. The F(15)-F(17) bond length is 1.76 Å. In the fourteenth F site, F(16) is bonded in a 2-coordinate geometry to one Ru(8) and one F(1) atom. In the fifteenth F site, F(17) is bonded in a water-like geometry to one F(15) and one F(30) atom. The F(17)-F(30) bond length is 1.21 Å. In the sixteenth F site, F(18) is bonded in a distorted L-shaped geometry to one Ru(1) and one F(19) atom. The F(18)-F(19) bond length is 1.27 Å. In the seventeenth F site, F(19) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one F(18), and one F(27) atom. The F(19)-F(27) bond length is 1.20 Å. In the eighteenth F site, F(20) is bonded in a 3-coordinate geometry to one Ru(3), one Ru(7), and one F(31) atom. The F(20)-F(31) bond length is 1.65 Å. In the nineteenth F site, F(21) is bonded in a 2-coordinate geometry to one Ru(6) and one Ru(8) atom. In the twentieth F site, F(22) is bonded in a 2-coordinate geometry to one Ru(6) and one F(10) atom. In the twenty-first F site, F(23) is bonded in a distorted single-bond geometry to one Ru(7), one O(2), and one O(6) atom. In the twenty-second F site, F(24) is bonded in a 2-coordinate geometry to one Ru(2) and one F(9) atom. In the twenty-third F site, F(25) is bonded in a bent 150 degrees geometry to one Ru(5) and one F(13) atom. In the twenty-fourth F site, F(26) is bonded in a bent 120 degrees geometry to one Ru(7) and one O(5) atom. In the twenty-fifth F site, F(27) is bonded in a water-like geometry to one F(19) and one F(29) atom. The F(27)-F(29) bond length is 1.48 Å. In the twenty-sixth F site, F(28) is bonded in a bent 120 degrees geometry to one Ru(8) and one O(8) atom. In the twenty-seventh F site, F(29) is bonded in a distorted trigonal non-coplanar geometry to one F(14), one F(27), and one F(6) atom. In the twenty-eighth F site, F(30) is bonded in a water-like geometry to one O(2) and one F(17) atom. In the twenty-ninth F site, F(31) is bonded in a 3-coordinate geometry to one Ru(7), one F(20), and one F(9) atom. In the thirtieth F site, F(32) is bonded in a 3-coordinate geometry to one Ru(2), one Ru(4), and one Ru(7) atom.