data_La2OsCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.65
_cell_length_b   5.65
_cell_length_c   5.65
_cell_angle_alpha   140.32
_cell_angle_beta   118.93
_cell_angle_gamma   75.32
_symmetry_Int_Tables_number   1
_chemical_formula_structural   La2OsCl
_chemical_formula_sum   'La2 Os1 Cl1'
_cell_volume   98.44
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La1  1  0.0  0.87  0.27  1.0
  La  La2  1  0.92  0.0  0.21  1.0
  Os  Os3  1  0.0  0.0  0.47  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_La2OsCl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.83
_cell_length_b   5.65
_cell_length_c   5.65
_cell_angle_alpha   61.07
_cell_angle_beta   70.16
_cell_angle_gamma   70.16
_symmetry_Int_Tables_number   1
_chemical_formula_structural   La2OsCl
_chemical_formula_sum   'La2 Os1 Cl1'
_cell_volume   98.44
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.08  0.21  1.0
  La  La1  1  0.87  -0.0  0.4  1.0
  Os  Os2  1  0.0  0.0  0.47  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

La La Os Cl
La La Os Cl 0 2 o + o 0 1 - + o 1 3 + o o 
LaOsLaCl is beta oxygen-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LaCl cluster and one LaOs cluster. In the LaCl cluster, La(2) is bonded in a distorted single-bond geometry to one Cl(1) atom. The La(2)-Cl(1) bond length is 1.45 Å. Cl(1) is bonded in a single-bond geometry to one La(2) atom. In the LaOs cluster, La(1) is bonded in a distorted single-bond geometry to one Os(1) atom. The La(1)-Os(1) bond length is 0.76 Å. Os(1) is bonded in a single-bond geometry to one La(1) atom.