data_Mn2InW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.73
_cell_length_b   8.73
_cell_length_c   8.73
_cell_angle_alpha   19.55
_cell_angle_beta   19.55
_cell_angle_gamma   19.55
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mn2InW
_chemical_formula_sum   'Mn2 In1 W1'
_cell_volume   65.04
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn1  1  0.0  0.0  0.23  1.0
  Mn  Mn2  1  0.0  0.0  0.43  1.0
  In  In0  1  0.0  0.0  0.0  1.0
  W  W3  1  0.0  0.0  0.83  1.0

data_Mn2InW
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.13
_cell_length_b   2.96
_cell_length_c   8.73
_cell_angle_alpha   90.0
_cell_angle_beta   101.31
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Mn2InW
_chemical_formula_sum   'Mn4 In2 W2'
_cell_volume   130.08
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  2  0.0  0.0  0.57  1.0
  Mn  Mn1  2  0.0  0.0  0.77  1.0
  In  In2  2  0.0  0.0  0.0  1.0
  W  W3  2  0.0  0.0  0.17  1.0

Mn Mn In W
Mn Mn In W 0 2 o o o 0 1 o o o 2 3 o o - 
WMn2In crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two WMn2In clusters. W(1) is bonded in a single-bond geometry to one In(1) atom. The W(1)-In(1) bond length is 1.45 Å. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted linear geometry to one Mn(2) and one In(1) atom. The Mn(1)-Mn(2) bond length is 1.76 Å. The Mn(1)-In(1) bond length is 2.03 Å. In the second Mn site, Mn(2) is bonded in a 1-coordinate geometry to one Mn(1) atom. In(1) is bonded in a distorted linear geometry to one W(1) and one Mn(1) atom.