data_VMoIr2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.79
_cell_length_b   4.79
_cell_length_c   4.79
_cell_angle_alpha   132.74
_cell_angle_beta   132.74
_cell_angle_gamma   69.07
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VMoIr2
_chemical_formula_sum   'V1 Mo1 Ir2'
_cell_volume   58.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Mo  Mo2  1  0.92  0.0  0.97  1.0
  Ir  Ir0  1  0.0  0.92  0.97  1.0
  Ir  Ir1  1  0.0  0.0  0.95  1.0

data_VMoIr2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.84
_cell_length_b   3.84
_cell_length_c   4.79
_cell_angle_alpha   113.63
_cell_angle_beta   113.63
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VMoIr2
_chemical_formula_sum   'V1 Mo1 Ir2'
_cell_volume   58.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  Mo  Mo1  1  0.03  0.0  0.95  1.0
  Ir  Ir2  1  0.05  0.0  0.05  1.0
  Ir  Ir3  1  0.95  0.92  0.95  1.0

V Mo Ir Ir
V Mo Ir Ir 0 1 - o - 0 2 o - - 0 3 o o - 
VMoIr2 is Ammonia-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VMoIr2 cluster. V(1) is bonded in a trigonal non-coplanar geometry to one Mo(1), one Ir(1), and one Ir(2) atom. The V(1)-Mo(1) bond length is 0.31 Å. The V(1)-Ir(1) bond length is 0.31 Å. The V(1)-Ir(2) bond length is 0.26 Å. Mo(1) is bonded in a single-bond geometry to one V(1) atom. There are two inequivalent Ir sites. In the first Ir site, Ir(1) is bonded in a single-bond geometry to one V(1) atom. In the second Ir site, Ir(2) is bonded in a single-bond geometry to one V(1) atom.