data_BaSbP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.31
_cell_length_b   6.31
_cell_length_c   6.31
_cell_angle_alpha   139.82
_cell_angle_beta   139.82
_cell_angle_gamma   58.12
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaSbP2
_chemical_formula_sum   'Ba1 Sb1 P2'
_cell_volume   103.41
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.0  0.17  0.76  1.0
  Sb  Sb3  1  0.0  0.0  0.51  1.0
  P  P1  1  0.0  0.0  0.0  1.0
  P  P2  1  0.17  0.0  0.76  1.0

data_BaSbP2
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.33
_cell_length_b   4.33
_cell_length_c   6.31
_cell_angle_alpha   110.09
_cell_angle_beta   110.09
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaSbP2
_chemical_formula_sum   'Ba1 Sb1 P2'
_cell_volume   103.41
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.41  0.17  0.41  1.0
  Sb  Sb1  1  0.49  0.0  0.49  1.0
  P  P2  1  0.0  0.0  0.0  1.0
  P  P3  1  0.24  0.0  0.41  1.0

Ba Sb P P
Ba Sb P P 0 1 o o o 0 3 o o o 0 2 o o + 1 3 o o o 2 3 o o - 
BaSbP2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one BaSbP2 cluster. Ba(1) is bonded in a 2-coordinate geometry to one Sb(1), one P(1), and one P(2) atom. The Ba(1)-Sb(1) bond length is 1.00 Å. The Ba(1)-P(1) bond length is 2.43 Å. The Ba(1)-P(2) bond length is 1.02 Å. Sb(1) is bonded in a 2-coordinate geometry to one Ba(1) and one P(2) atom. The Sb(1)-P(2) bond length is 1.00 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one Ba(1) atom. In the second P site, P(2) is bonded in a 2-coordinate geometry to one Ba(1) and one Sb(1) atom.