data_TeMo2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.89
_cell_length_b   2.89
_cell_length_c   9.36
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   111.87
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TeMo2W
_chemical_formula_sum   'Te1 Mo2 W1'
_cell_volume   72.56
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te2  1  0.0  0.0  0.71  1.0
  Mo  Mo0  1  0.0  0.0  0.36  1.0
  Mo  Mo1  1  0.62  0.0  0.25  1.0
  W  W3  1  0.62  0.0  0.09  1.0

data_TeMo2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.89
_cell_length_b   2.89
_cell_length_c   9.36
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   111.87
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TeMo2W
_chemical_formula_sum   'Te1 Mo2 W1'
_cell_volume   72.56
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.0  0.0  0.71  1.0
  Mo  Mo1  1  0.0  0.0  0.36  1.0
  Mo  Mo2  1  0.62  0.0  0.25  1.0
  W  W3  1  0.62  0.0  0.09  1.0

Te Mo Mo W
Te Mo Mo W 0 0 + + o 0 0 o + o 0 0 + o o 0 1 o o o 1 2 - o o 2 3 o o o 
WMo2Te crystallizes in the triclinic P1 space group. W(1) is bonded in a single-bond geometry to one Mo(2) and one Te(1) atom. The W(1)-Mo(2) bond length is 1.49 Å. The W(1)-Te(1) bond length is 3.77 Å. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 2-coordinate geometry to two equivalent Mo(2) and one Te(1) atom. There is one shorter (1.48 Å) and one longer (2.04 Å) Mo(1)-Mo(2) bond length. The Mo(1)-Te(1) bond length is 3.27 Å. In the second Mo site, Mo(2) is bonded in a 3-coordinate geometry to one W(1) and two equivalent Mo(1) atoms. Te(1) is bonded in a 8-coordinate geometry to one W(1), one Mo(1), and six equivalent Te(1) atoms. There are four shorter (2.89 Å) and two longer (3.24 Å) Te(1)-Te(1) bond lengths.