data_Mn2SbW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.93
_cell_length_b   4.93
_cell_length_c   4.93
_cell_angle_alpha   138.4
_cell_angle_beta   129.85
_cell_angle_gamma   67.14
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mn2SbW
_chemical_formula_sum   'Mn2 Sb1 W1'
_cell_volume   60.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.0  0.0  0.05  1.0
  Mn  Mn1  1  0.75  0.0  0.02  1.0
  Sb  Sb2  1  0.0  0.0  0.06  1.0
  W  W3  1  0.0  0.09  0.09  1.0

data_Mn2SbW
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.5
_cell_length_b   4.18
_cell_length_c   4.93
_cell_angle_alpha   115.08
_cell_angle_beta   110.8
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mn2SbW
_chemical_formula_sum   'Mn2 Sb1 W1'
_cell_volume   60.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.0  0.02  0.27  1.0
  Mn  Mn1  1  0.0  0.05  0.05  1.0
  Sb  Sb2  1  0.0  0.06  0.06  1.0
  W  W3  1  0.91  1.0  1.0  1.0

Mn Mn Sb W
Mn Mn Sb W 0 2 o o o 0 1 - o o 0 3 o o o 1 3 + o o 1 2 + o o 2 3 o o o 
WMn2Sb crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one WMn2Sb cluster. W(1) is bonded in a single-bond geometry to one Mn(1) and one Mn(2) atom. The W(1)-Mn(1) bond length is 0.33 Å. The W(1)-Mn(2) bond length is 1.22 Å. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted bent 120 degrees geometry to one W(1) and one Sb(1) atom. The Mn(1)-Sb(1) bond length is 0.07 Å. In the second Mn site, Mn(2) is bonded in a 2-coordinate geometry to one W(1) and one Sb(1) atom. The Mn(2)-Sb(1) bond length is 1.10 Å. Sb(1) is bonded in a single-bond geometry to one Mn(1) and one Mn(2) atom.