data_VMo2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.08
_cell_length_b   3.08
_cell_length_c   6.27
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VMo2Rh
_chemical_formula_sum   'V1 Mo2 Rh1'
_cell_volume   59.47
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Mo  Mo0  1  0.54  0.54  0.46  1.0
  Mo  Mo1  1  0.54  0.54  0.82  1.0
  Rh  Rh2  1  0.0  0.0  0.14  1.0

data_VMo2Rh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.35
_cell_length_b   4.35
_cell_length_c   6.27
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VMo2Rh
_chemical_formula_sum   'V2 Mo4 Rh2'
_cell_volume   118.93
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.0  1.0
  Mo  Mo1  2  0.04  0.5  0.46  1.0
  Mo  Mo2  2  0.04  0.5  0.82  1.0
  Rh  Rh3  2  0.0  0.0  0.14  1.0

V Mo Mo Rh
V Mo Mo Rh 0 3 o o o 0 2 o o - 0 2 o - - 0 2 - o - 0 2 - - - 1 3 o o o 1 3 o + o 1 3 + o o 1 3 + + o 1 1 + o o 1 1 o + o 1 2 o o o 2 3 + + + 
VMo2Rh crystallizes in the monoclinic Cm space group. V(1) is bonded in a single-bond geometry to four equivalent Mo(2) and one Rh(1) atom. There are a spread of V(1)-Mo(2) bond distances ranging from 2.32-2.62 Å. The V(1)-Rh(1) bond length is 0.86 Å. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 9-coordinate geometry to one Mo(2), four equivalent Mo(1), and four equivalent Rh(1) atoms. The Mo(1)-Mo(2) bond length is 2.23 Å. All Mo(1)-Mo(1) bond lengths are 3.08 Å. There are a spread of Mo(1)-Rh(1) bond distances ranging from 2.85-3.10 Å. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to four equivalent V(1) and one Mo(1) atom. Rh(1) is bonded in a single-bond geometry to one V(1) and four equivalent Mo(1) atoms.