data_BiMoP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.19
_cell_length_b   3.19
_cell_length_c   7.1
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BiMoP2
_chemical_formula_sum   'Bi1 Mo1 P2'
_cell_volume   72.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.0  0.0  0.55  1.0
  Mo  Mo1  1  0.0  0.0  0.0  1.0
  P  P2  1  0.59  0.59  0.28  1.0
  P  P3  1  0.59  0.59  0.82  1.0

data_BiMoP2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.51
_cell_length_b   4.51
_cell_length_c   7.1
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   BiMoP2
_chemical_formula_sum   'Bi2 Mo2 P4'
_cell_volume   144.43
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  2  0.0  0.0  0.55  1.0
  Mo  Mo1  2  0.0  0.0  0.0  1.0
  P  P2  2  0.09  0.5  0.28  1.0
  P  P3  2  0.09  0.5  0.82  1.0

Bi Mo P P
Bi Mo P P 0 2 - - o 0 2 - o o 0 2 o - o 0 2 o o o 0 3 - - o 0 3 - o o 0 3 o - o 0 3 o o o 0 0 + o o 0 0 o + o 0 1 o o + 1 3 - - - 1 3 - o - 1 3 o - - 1 3 o o - 1 2 - - o 1 2 - o o 1 2 o - o 1 2 o o o 2 2 + o o 2 2 o + o 2 3 o o - 
MoBiP2 crystallizes in the monoclinic Cm space group. Mo(1) is bonded in a 1-coordinate geometry to three equivalent P(1) and four equivalent P(2) atoms. There is one shorter (2.72 Å) and two longer (3.05 Å) Mo(1)-P(1) bond lengths. There are a spread of Mo(1)-P(2) bond distances ranging from 2.22-2.96 Å. Bi(1) is bonded in a 6-coordinate geometry to three equivalent P(1) and three equivalent P(2) atoms. There is one shorter (2.65 Å) and two longer (2.99 Å) Bi(1)-P(1) bond lengths. There is one shorter (2.65 Å) and two longer (2.99 Å) Bi(1)-P(2) bond lengths. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to three equivalent Mo(1) and three equivalent Bi(1) atoms. In the second P site, P(2) is bonded in a 7-coordinate geometry to four equivalent Mo(1) and three equivalent Bi(1) atoms.