data_V2CuOs
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.07
_cell_length_b   3.07
_cell_length_c   5.64
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2CuOs
_chemical_formula_sum   'V2 Cu1 Os1'
_cell_volume   53.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.0  0.63  1.0
  V  V3  1  0.54  0.54  0.47  1.0
  Cu  Cu0  1  0.0  0.0  0.76  1.0
  Os  Os1  1  0.54  0.54  0.26  1.0

data_V2CuOs
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.34
_cell_length_b   4.34
_cell_length_c   5.64
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   V2CuOs
_chemical_formula_sum   'V4 Cu2 Os2'
_cell_volume   106.48
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.63  1.0
  V  V1  2  0.04  0.5  0.47  1.0
  Cu  Cu2  2  0.0  0.0  0.76  1.0
  Os  Os3  2  0.04  0.5  0.26  1.0

V V Cu Os
V V Cu Os 0 2 o o o 1 3 o o o 
VOsVCu is Cubic alpha N2-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two VCu clusters and two VOs clusters. In each VCu cluster, V(1) is bonded in a single-bond geometry to one Cu(1) atom. The V(1)-Cu(1) bond length is 0.73 Å. Cu(1) is bonded in a single-bond geometry to one V(1) atom. In each VOs cluster, V(2) is bonded in a single-bond geometry to one Os(1) atom. The V(2)-Os(1) bond length is 1.22 Å. Os(1) is bonded in a single-bond geometry to one V(2) atom.