data_KAgPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.02
_cell_length_b   6.02
_cell_length_c   6.02
_cell_angle_alpha   151.49
_cell_angle_beta   128.26
_cell_angle_gamma   60.14
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KAgPd2
_chemical_formula_sum   'K1 Ag1 Pd2'
_cell_volume   81.0
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K1  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.0  0.0  0.21  1.0
  Pd  Pd2  1  0.0  0.63  0.36  1.0
  Pd  Pd3  1  0.48  0.0  0.84  1.0

data_KAgPd2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.96
_cell_length_b   5.25
_cell_length_c   6.02
_cell_angle_alpha   115.87
_cell_angle_beta   104.26
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KAgPd2
_chemical_formula_sum   'K1 Ag1 Pd2'
_cell_volume   81.0
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.0  0.0  1.0
  Ag  Ag1  1  0.79  0.79  0.79  1.0
  Pd  Pd2  1  0.64  0.26  0.26  1.0
  Pd  Pd3  1  0.64  0.16  0.64  1.0

K Ag Pd Pd
K Ag Pd Pd 0 1 o o o 0 2 o - - 0 2 o o o 0 3 - o - 1 3 o o o 1 3 - o - 2 3 o + o 3 3 o + + 
KPd2Ag crystallizes in the triclinic P1 space group. K(1) is bonded in a 3-coordinate geometry to one Pd(2), two equivalent Pd(1), and one Ag(1) atom. The K(1)-Pd(2) bond length is 2.64 Å. There is one shorter (2.12 Å) and one longer (2.14 Å) K(1)-Pd(1) bond length. The K(1)-Ag(1) bond length is 1.24 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in an L-shaped geometry to two equivalent K(1) and one Pd(2) atom. The Pd(1)-Pd(2) bond length is 2.55 Å. In the second Pd site, Pd(2) is bonded in a 6-coordinate geometry to one K(1), one Pd(1), two equivalent Pd(2), and two equivalent Ag(1) atoms. Both Pd(2)-Pd(2) bond lengths are 2.96 Å. There is one shorter (2.46 Å) and one longer (3.05 Å) Pd(2)-Ag(1) bond length. Ag(1) is bonded in a single-bond geometry to one K(1) and two equivalent Pd(2) atoms.