data_MnV2Sb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.43
_cell_length_b   4.43
_cell_length_c   3.1
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   105.86
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnV2Sb
_chemical_formula_sum   'Mn1 V2 Sb1'
_cell_volume   58.58
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.0  0.0  0.0  1.0
  V  V2  1  0.34  0.77  0.55  1.0
  V  V3  1  0.34  0.23  0.55  1.0
  Sb  Sb1  1  0.67  0.0  0.0  1.0

data_MnV2Sb
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.1
_cell_length_b   4.43
_cell_length_c   4.43
_cell_angle_alpha   105.86
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnV2Sb
_chemical_formula_sum   'Mn1 V2 Sb1'
_cell_volume   58.58
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.0  0.0  0.0  1.0
  V  V1  1  0.55  0.34  0.23  1.0
  V  V2  1  0.55  0.34  0.77  1.0
  Sb  Sb3  1  0.0  0.67  0.0  1.0

Mn V V Sb
Mn V V Sb 0 3 - o o 0 1 o - - 0 2 o o o 0 2 o o - 1 2 o + o 1 2 o o o 1 3 o + o 1 3 o + + 2 3 o o + 
V2MnSb crystallizes in the triclinic P1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 2-coordinate geometry to two equivalent V(2) and two equivalent Sb(1) atoms. There is one shorter (2.06 Å) and one longer (2.37 Å) V(1)-V(2) bond length. There is one shorter (2.09 Å) and one longer (2.32 Å) V(1)-Sb(1) bond length. In the second V site, V(2) is bonded in a 6-coordinate geometry to two equivalent V(1), two equivalent Mn(1), and two equivalent Sb(1) atoms. There is one shorter (2.09 Å) and one longer (2.32 Å) V(2)-Mn(1) bond length. There is one shorter (2.46 Å) and one longer (2.65 Å) V(2)-Sb(1) bond length. Mn(1) is bonded in a distorted single-bond geometry to two equivalent V(2) and one Sb(1) atom. The Mn(1)-Sb(1) bond length is 1.46 Å. Sb(1) is bonded in a 1-coordinate geometry to two equivalent V(1), two equivalent V(2), and one Mn(1) atom.