data_Co5P24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.5
_cell_length_b   8.5
_cell_length_c   8.5
_cell_angle_alpha   109.47
_cell_angle_beta   109.47
_cell_angle_gamma   109.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Co5P24
_chemical_formula_sum   'Co5 P24'
_cell_volume   472.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.49  0.51  0.49  1.0
  Co  Co1  1  0.51  0.49  0.49  1.0
  Co  Co2  1  0.49  0.49  0.51  1.0
  Co  Co3  1  0.42  0.42  0.42  1.0
  Co  Co4  1  0.0  0.0  0.0  1.0
  P  P5  1  0.08  0.92  0.95  1.0
  P  P6  1  0.92  0.08  0.95  1.0
  P  P7  1  0.08  0.08  0.87  1.0
  P  P8  1  0.83  0.83  0.96  1.0
  P  P9  1  0.08  0.87  0.08  1.0
  P  P10  1  0.83  0.96  0.83  1.0
  P  P11  1  0.92  0.95  0.08  1.0
  P  P12  1  0.08  0.95  0.92  1.0
  P  P13  1  0.95  0.92  0.08  1.0
  P  P14  1  0.95  0.08  0.92  1.0
  P  P15  1  0.96  0.83  0.83  1.0
  P  P16  1  0.87  0.08  0.08  1.0
  P  P17  1  0.4  0.6  0.19  1.0
  P  P18  1  0.6  0.4  0.19  1.0
  P  P19  1  0.31  0.31  0.71  1.0
  P  P20  1  0.6  0.6  0.62  1.0
  P  P21  1  0.31  0.71  0.31  1.0
  P  P22  1  0.6  0.62  0.6  1.0
  P  P23  1  0.6  0.19  0.4  1.0
  P  P24  1  0.4  0.19  0.6  1.0
  P  P25  1  0.19  0.6  0.4  1.0
  P  P26  1  0.19  0.4  0.6  1.0
  P  P27  1  0.62  0.6  0.6  1.0
  P  P28  1  0.71  0.31  0.31  1.0

data_Co5P24
_symmetry_space_group_name_H-M   R3m
_cell_length_a   13.88
_cell_length_b   13.88
_cell_length_c   8.5
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   Co5P24
_chemical_formula_sum   'Co15 P72'
_cell_volume   1418.78
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+2/3, y+1/3, z+1/3'
  8  '-y+2/3, x-y+1/3, z+1/3'
  9  '-x+y+2/3, -x+1/3, z+1/3'
  10  '-y+2/3, -x+1/3, z+1/3'
  11  '-x+y+2/3, y+1/3, z+1/3'
  12  'x+2/3, x-y+1/3, z+1/3'
  13  'x+1/3, y+2/3, z+2/3'
  14  '-y+1/3, x-y+2/3, z+2/3'
  15  '-x+y+1/3, -x+2/3, z+2/3'
  16  '-y+1/3, -x+2/3, z+2/3'
  17  '-x+y+1/3, y+2/3, z+2/3'
  18  'x+1/3, x-y+2/3, z+2/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  9  0.01  0.01  0.5  1.0
  Co  Co1  3  0.0  0.0  0.0  1.0
  Co  Co2  3  0.0  0.0  0.42  1.0
  P  P3  18  0.1  0.04  0.98  1.0
  P  P4  18  0.13  0.46  0.06  1.0
  P  P5  9  0.01  0.01  0.61  1.0
  P  P6  9  0.07  0.14  0.01  1.0
  P  P7  9  0.09  0.04  0.87  1.0
  P  P8  9  0.2  0.39  0.11  1.0

Co Co Co Co Co P P P P P P P P P P P P P P P P P P P P P P P P
Co Co Co Co Co P P P P P P P P P P P P P P P P P P P P P P P P 0 2 o o o 0 1 o o o 0 3 o o o 1 2 o o o 1 3 o o o 2 3 o o o 4 13 - - o 4 11 - - o 4 14 - o - 4 6 - o - 4 12 o - - 4 5 o - - 5 12 o o o 5 9 o o + 5 15 - o o 6 14 o o o 6 10 o - o 6 16 o o + 7 14 - o o 7 12 o - o 8 13 o o + 8 11 o o + 9 13 - o o 10 14 o + o 11 13 o o o 11 16 o + o 12 15 - o o 17 21 o o o 18 28 o o o 19 26 o o o 19 24 o o o 20 22 o o o 20 27 o o o 21 25 o o o 22 27 o o o 23 28 o o o 
Co4P3CoP12(P)9 is Ammonia-like structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of nine triphosph-1-ene molecules, three Co4P3 clusters, and three CoP12 clusters. In each Co4P3 cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 2-coordinate geometry to one Co(2), two equivalent Co(1), and one P(6) atom. The Co(1)-Co(2) bond length is 0.69 Å. Both Co(1)-Co(1) bond lengths are 0.28 Å. The Co(1)-P(6) bond length is 0.95 Å. In the second Co site, Co(2) is bonded in a 3-coordinate geometry to three equivalent Co(1) atoms. P(6) is bonded in a 3-coordinate geometry to one Co(1) and two equivalent P(6) atoms. Both P(6)-P(6) bond lengths are 0.26 Å. In each CoP12 cluster, Co(3) is bonded in a 9-coordinate geometry to three equivalent P(3) and six equivalent P(1) atoms. All Co(3)-P(3) bond lengths are 1.53 Å. All Co(3)-P(1) bond lengths are 1.21 Å. There are three inequivalent P sites. In the first P site, P(2) is bonded in a distorted L-shaped geometry to two equivalent P(1) atoms. Both P(2)-P(1) bond lengths are 1.34 Å. In the second P site, P(3) is bonded in a 3-coordinate geometry to one Co(3) and two equivalent P(1) atoms. Both P(3)-P(1) bond lengths are 0.97 Å. In the third P site, P(1) is bonded in a 4-coordinate geometry to one Co(3), one P(1), one P(2), and one P(3) atom. The P(1)-P(1) bond length is 0.39 Å.