data_TiRePb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.38
_cell_length_b   5.38
_cell_length_c   5.38
_cell_angle_alpha   143.3
_cell_angle_beta   143.3
_cell_angle_gamma   52.87
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiRePb
_chemical_formula_sum   'Ti1 Re1 Pb1'
_cell_volume   55.27
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti2  1  0.0  0.0  0.63  1.0
  Re  Re1  1  0.0  0.0  0.02  1.0
  Pb  Pb0  1  0.0  0.0  0.62  1.0

data_TiRePb
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.79
_cell_length_b   4.79
_cell_length_c   5.38
_cell_angle_alpha   90.0
_cell_angle_beta   116.44
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TiRePb
_chemical_formula_sum   'Ti2 Re2 Pb2'
_cell_volume   110.54
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  2  0.0  0.0  0.37  1.0
  Re  Re1  2  0.0  0.0  0.98  1.0
  Pb  Pb2  2  0.0  0.0  0.38  1.0

Ti Re Pb
Ti Re Pb 0 2 o o o 0 1 o o + 1 2 o o - 
TiRePb crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two TiRePb clusters. Ti(1) is bonded in a single-bond geometry to one Re(1) and one Pb(1) atom. The Ti(1)-Re(1) bond length is 2.09 Å. The Ti(1)-Pb(1) bond length is 0.03 Å. Re(1) is bonded in a distorted single-bond geometry to one Ti(1) atom. Pb(1) is bonded in a single-bond geometry to one Ti(1) atom.