data_TlZn2Pt
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.03
_cell_length_b   5.03
_cell_length_c   5.03
_cell_angle_alpha   131.74
_cell_angle_beta   131.74
_cell_angle_gamma   70.64
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlZn2Pt
_chemical_formula_sum   'Tl1 Zn2 Pt1'
_cell_volume   69.55
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl1  1  0.0  0.06  0.05  1.0
  Zn  Zn2  1  0.0  0.0  0.0  1.0
  Zn  Zn3  1  0.06  0.0  0.05  1.0
  Pt  Pt0  1  0.0  0.0  0.11  1.0

data_TlZn2Pt
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.12
_cell_length_b   4.12
_cell_length_c   5.03
_cell_angle_alpha   114.13
_cell_angle_beta   114.13
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlZn2Pt
_chemical_formula_sum   'Tl1 Zn2 Pt1'
_cell_volume   69.55
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.0  0.06  0.0  1.0
  Zn  Zn1  1  0.0  0.0  0.0  1.0
  Zn  Zn2  1  0.95  0.0  0.0  1.0
  Pt  Pt3  1  0.89  0.0  0.89  1.0

Tl Zn Zn Pt
Tl Zn Zn Pt 0 1 o o o 0 3 o o o 1 2 o o o 1 3 o o o 2 3 o o o 
PtZn2Tl is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one PtZn2Tl cluster. Pt(1) is bonded in a 2-coordinate geometry to one Zn(2) and one Tl(1) atom. The Pt(1)-Zn(2) bond length is 0.51 Å. The Pt(1)-Tl(1) bond length is 0.51 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted L-shaped geometry to one Zn(2) and one Tl(1) atom. The Zn(1)-Zn(2) bond length is 0.23 Å. The Zn(1)-Tl(1) bond length is 0.23 Å. In the second Zn site, Zn(2) is bonded in a distorted L-shaped geometry to one Pt(1) and one Zn(1) atom. Tl(1) is bonded in a distorted L-shaped geometry to one Pt(1) and one Zn(1) atom.