data_CdCoAu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.92
_cell_length_b   4.92
_cell_length_c   5.13
_cell_angle_alpha   100.78
_cell_angle_beta   100.78
_cell_angle_gamma   34.2
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdCoAu2
_chemical_formula_sum   'Cd1 Co1 Au2'
_cell_volume   68.52
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd2  1  0.2  0.0  0.52  1.0
  Co  Co3  1  0.0  0.0  0.0  1.0
  Au  Au0  1  0.69  0.0  0.18  1.0
  Au  Au1  1  0.71  0.0  0.86  1.0

data_CdCoAu2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.89
_cell_length_b   4.92
_cell_length_c   5.13
_cell_angle_alpha   100.78
_cell_angle_beta   90.0
_cell_angle_gamma   107.1
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdCoAu2
_chemical_formula_sum   'Cd1 Co1 Au2'
_cell_volume   68.52
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.8  0.48  1.0
  Co  Co1  1  0.0  0.0  0.0  1.0
  Au  Au2  1  0.0  0.29  0.14  1.0
  Au  Au3  1  0.0  0.31  0.82  1.0

Cd Co Au Au
Cd Co Au Au 0 1 o o o 0 1 o o + 0 2 - o o 0 2 o o o 0 0 + - o 0 3 - o o 0 3 o o o 1 3 - o - 1 2 - o o 2 3 o o - 
CoAu2Cd crystallizes in the triclinic P1 space group. Co(1) is bonded in a 2-coordinate geometry to one Au(1), one Au(2), and two equivalent Cd(1) atoms. The Co(1)-Au(1) bond length is 1.90 Å. The Co(1)-Au(2) bond length is 1.49 Å. There is one shorter (2.65 Å) and one longer (2.83 Å) Co(1)-Cd(1) bond length. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a 1-coordinate geometry to one Co(1) and three equivalent Cd(1) atoms. There are a spread of Au(1)-Cd(1) bond distances ranging from 2.76-3.43 Å. In the second Au site, Au(2) is bonded in a distorted single-bond geometry to one Co(1) and three equivalent Cd(1) atoms. There are a spread of Au(2)-Cd(1) bond distances ranging from 2.76-3.43 Å. Cd(1) is bonded in a 10-coordinate geometry to two equivalent Co(1), three equivalent Au(1), three equivalent Au(2), and two equivalent Cd(1) atoms. Both Cd(1)-Cd(1) bond lengths are 2.89 Å.