data_Ta2InMo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.37
_cell_length_b   3.37
_cell_length_c   6.45
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ta2InMo
_chemical_formula_sum   'Ta2 In1 Mo1'
_cell_volume   73.44
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta2  1  0.69  0.69  0.44  1.0
  Ta  Ta3  1  0.69  0.69  0.01  1.0
  In  In0  1  0.0  0.0  0.23  1.0
  Mo  Mo1  1  0.0  0.0  0.0  1.0

data_Ta2InMo
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.77
_cell_length_b   4.77
_cell_length_c   6.45
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Ta2InMo
_chemical_formula_sum   'Ta4 In2 Mo2'
_cell_volume   146.87
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  2  0.19  0.5  0.01  1.0
  Ta  Ta1  2  0.19  0.5  0.44  1.0
  In  In2  2  0.0  0.0  0.23  1.0
  Mo  Mo3  2  0.0  0.0  0.0  1.0

Ta Ta In Mo
Ta Ta In Mo 0 2 + + o 1 3 + + o 2 3 o o o 
Ta2MoIn crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Ta2MoIn clusters. There are two inequivalent Ta sites. In the first Ta site, Ta(1) is bonded in a distorted single-bond geometry to one In(1) atom. The Ta(1)-In(1) bond length is 2.03 Å. In the second Ta site, Ta(2) is bonded in a distorted single-bond geometry to one Mo(1) atom. The Ta(2)-Mo(1) bond length is 1.50 Å. Mo(1) is bonded in a distorted L-shaped geometry to one Ta(2) and one In(1) atom. The Mo(1)-In(1) bond length is 1.46 Å. In(1) is bonded in a 1-coordinate geometry to one Ta(1) and one Mo(1) atom.