data_Ca3(GaPt)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.81
_cell_length_b   7.93
_cell_length_c   13.91
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ca3(GaPt)2
_chemical_formula_sum   'Ca12 Ga8 Pt8'
_cell_volume   640.81
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.83  0.81  0.37  1.0
  Ca  Ca1  1  0.83  0.08  0.54  1.0
  Ca  Ca2  1  0.98  0.85  0.59  1.0
  Ca  Ca3  1  0.98  0.12  0.33  1.0
  Ca  Ca4  1  0.98  0.12  0.54  1.0
  Ca  Ca5  1  0.98  0.85  0.37  1.0
  Ca  Ca6  1  0.83  0.08  0.33  1.0
  Ca  Ca7  1  0.83  0.81  0.59  1.0
  Ca  Ca8  1  0.15  0.04  0.48  1.0
  Ca  Ca9  1  0.15  0.92  0.44  1.0
  Ca  Ca10  1  0.65  0.0  0.48  1.0
  Ca  Ca11  1  0.65  0.89  0.44  1.0
  Ga  Ga12  1  0.2  0.98  0.0  1.0
  Ga  Ga13  1  0.61  0.95  0.96  1.0
  Ga  Ga14  1  0.61  0.95  0.0  1.0
  Ga  Ga15  1  0.2  0.98  0.96  1.0
  Ga  Ga16  1  0.98  0.24  0.48  1.0
  Ga  Ga17  1  0.98  0.73  0.44  1.0
  Ga  Ga18  1  0.82  0.2  0.48  1.0
  Ga  Ga19  1  0.82  0.69  0.44  1.0
  Pt  Pt20  1  0.71  0.71  0.31  1.0
  Pt  Pt21  1  0.71  0.25  0.6  1.0
  Pt  Pt22  1  0.1  0.68  0.65  1.0
  Pt  Pt23  1  0.1  0.21  0.27  1.0
  Pt  Pt24  1  0.1  0.21  0.6  1.0
  Pt  Pt25  1  0.1  0.68  0.31  1.0
  Pt  Pt26  1  0.71  0.25  0.27  1.0
  Pt  Pt27  1  0.71  0.71  0.65  1.0

data_Ca3(GaPt)2
_symmetry_space_group_name_H-M   P1
_cell_length_a   5.81
_cell_length_b   7.93
_cell_length_c   13.91
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ca3(GaPt)2
_chemical_formula_sum   'Ca12 Ga8 Pt8'
_cell_volume   640.81
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.15  0.04  0.48  1.0
  Ca  Ca1  1  0.15  0.92  0.44  1.0
  Ca  Ca2  1  0.65  0.0  0.48  1.0
  Ca  Ca3  1  0.65  0.89  0.44  1.0
  Ca  Ca4  1  0.83  0.08  0.33  1.0
  Ca  Ca5  1  0.83  0.08  0.54  1.0
  Ca  Ca6  1  0.83  0.81  0.37  1.0
  Ca  Ca7  1  0.83  0.81  0.59  1.0
  Ca  Ca8  1  0.98  0.12  0.33  1.0
  Ca  Ca9  1  0.98  0.12  0.54  1.0
  Ca  Ca10  1  0.98  0.85  0.37  1.0
  Ca  Ca11  1  0.98  0.85  0.59  1.0
  Ga  Ga12  1  0.2  0.98  0.0  1.0
  Ga  Ga13  1  0.2  0.98  0.96  1.0
  Ga  Ga14  1  0.61  0.95  0.0  1.0
  Ga  Ga15  1  0.61  0.95  0.96  1.0
  Ga  Ga16  1  0.82  0.2  0.48  1.0
  Ga  Ga17  1  0.82  0.69  0.44  1.0
  Ga  Ga18  1  0.98  0.24  0.48  1.0
  Ga  Ga19  1  0.98  0.73  0.44  1.0
  Pt  Pt20  1  0.1  0.21  0.27  1.0
  Pt  Pt21  1  0.1  0.21  0.6  1.0
  Pt  Pt22  1  0.1  0.68  0.31  1.0
  Pt  Pt23  1  0.1  0.68  0.65  1.0
  Pt  Pt24  1  0.71  0.25  0.27  1.0
  Pt  Pt25  1  0.71  0.25  0.6  1.0
  Pt  Pt26  1  0.71  0.71  0.31  1.0
  Pt  Pt27  1  0.71  0.71  0.65  1.0

Ca Ca Ca Ca Ca Ca Ca Ca Ca Ca Ca Ca Ga Ga Ga Ga Ga Ga Ga Ga Pt Pt Pt Pt Pt Pt Pt Pt
Ca Ca Ca Ca Ca Ca Ca Ca Ca Ca Ca Ca Ga Ga Ga Ga Ga Ga Ga Ga Pt Pt Pt Pt Pt Pt Pt Pt 0 5 o o o 0 20 o o o 0 25 + o o 1 4 o o o 1 21 o o o 2 7 o o o 2 22 + o o 3 6 o o o 3 23 + o o 3 26 o o o 4 21 o o o 4 24 + o o 5 25 + o o 6 26 o o o 7 22 + o o 7 27 o o o 8 9 o - o 10 11 o - o 12 15 o o - 13 14 o o + 16 18 o o o 17 19 o o o 17 25 + o o 18 21 o o o 
CaPtCa2PtGaGa is Cyanogen Chloride-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two digallane molecules, one Ca2PtGa cluster, and two CaPt clusters. In the Ca2PtGa cluster, there are four inequivalent Ca sites. In the first Ca site, Ca(1,5) is bonded in a 3-coordinate geometry to one Ca(2,6); one Ca(9,12); one Pt(1,5); and one Ga(5,8) atom. The Ca(1,5)-Ca(2,6) bond length is 0.90 Å. The Ca(1,5)-Ca(9,12) bond length is 1.50 Å. The Ca(1,5)-Pt(1,5) bond length is 1.34 Å. The Ca(1,5)-Ga(5,8) bond length is 1.32 Å. In the second Ca site, Ca(2,6) is bonded in a 4-coordinate geometry to one Ca(1,5); one Ca(10,11); one Pt(2,6); and one Ga(6,7) atom. The Ca(2,6)-Ca(10,11) bond length is 1.50 Å. The Ca(2,6)-Pt(2,6) bond length is 1.72 Å. The Ca(2,6)-Ga(6,7) bond length is 1.32 Å. In the third Ca site, Ca(9,12) is bonded in a 3-coordinate geometry to one Ca(1,5); one Ca(10,11); and one Ga(5,8) atom. The Ca(9,12)-Ca(10,11) bond length is 1.09 Å. The Ca(9,12)-Ga(5,8) bond length is 1.85 Å. In the fourth Ca site, Ca(10,11) is bonded in a 3-coordinate geometry to one Ca(2,6); one Ca(9,12); and one Ga(6,7) atom. The Ca(10,11)-Ga(6,7) bond length is 1.85 Å. There are two inequivalent Pt sites. In the first Pt site, Pt(1,5) is bonded in a single-bond geometry to one Ca(1,5) atom. In the second Pt site, Pt(2,6) is bonded in a distorted single-bond geometry to one Ca(2,6) atom. There are two inequivalent Ga sites. In the first Ga site, Ga(5,8) is bonded in a distorted single-bond geometry to one Ca(1,5) and one Ca(9,12) atom. In the second Ga site, Ga(6,7) is bonded in a 1-coordinate geometry to one Ca(10,11) and one Ca(2,6) atom. In each CaPt cluster, there are two inequivalent Ca sites. In the first Ca site, Ca(3) is bonded in a 2-coordinate geometry to one Ca(8) and one Pt(3) atom. The Ca(3)-Ca(8) bond length is 0.90 Å. The Ca(3)-Pt(3) bond length is 1.72 Å. In the second Ca site, Ca(8) is bonded in a 2-coordinate geometry to one Ca(3) and one Pt(8) atom. The Ca(8)-Pt(8) bond length is 1.34 Å. There are two inequivalent Pt sites. In the first Pt site, Pt(8) is bonded in a single-bond geometry to one Ca(8) atom. In the second Pt site, Pt(3) is bonded in a single-bond geometry to one Ca(3) atom.