data_SrVMo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.73
_cell_length_b   5.73
_cell_length_c   5.73
_cell_angle_alpha   149.71
_cell_angle_beta   124.96
_cell_angle_gamma   64.12
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SrVMo2
_chemical_formula_sum   'Sr1 V1 Mo2'
_cell_volume   76.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr2  1  0.0  0.0  0.86  1.0
  V  V3  1  0.0  0.0  0.0  1.0
  Mo  Mo0  1  0.0  0.65  0.76  1.0
  Mo  Mo1  1  0.5  0.0  0.09  1.0

data_SrVMo2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.99
_cell_length_b   5.29
_cell_length_c   5.73
_cell_angle_alpha   117.52
_cell_angle_beta   105.14
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SrVMo2
_chemical_formula_sum   'Sr1 V1 Mo2'
_cell_volume   76.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.0  0.86  0.86  1.0
  V  V1  1  0.0  0.0  0.0  1.0
  Mo  Mo2  1  0.0  0.09  0.6  1.0
  Mo  Mo3  1  0.35  0.12  0.12  1.0

Sr V Mo Mo
Sr V Mo Mo 0 1 o o + 0 3 o o + 1 2 o - - 1 3 o o o 2 3 o + + 2 3 - o o 3 3 o + + 
SrVMo2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one SrVMo2 cluster. Sr(1) is bonded in a single-bond geometry to one V(1) and one Mo(2) atom. The Sr(1)-V(1) bond length is 0.82 Å. The Sr(1)-Mo(2) bond length is 2.35 Å. V(1) is bonded in a 2-coordinate geometry to one Sr(1) and one Mo(1) atom. The V(1)-Mo(1) bond length is 1.09 Å. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a distorted single-bond geometry to one V(1) atom. In the second Mo site, Mo(2) is bonded in a distorted single-bond geometry to one Sr(1) atom.