data_Zn2OsW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.66
_cell_length_b   4.66
_cell_length_c   4.81
_cell_angle_alpha   97.46
_cell_angle_beta   97.46
_cell_angle_gamma   34.91
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zn2OsW
_chemical_formula_sum   'Zn2 Os1 W1'
_cell_volume   59.33
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn2  1  0.88  0.0  0.1  1.0
  Zn  Zn3  1  0.56  0.0  0.1  1.0
  Os  Os0  1  0.09  0.0  0.48  1.0
  W  W1  1  0.73  0.0  0.47  1.0

data_Zn2OsW
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.8
_cell_length_b   4.66
_cell_length_c   4.81
_cell_angle_alpha   97.46
_cell_angle_beta   90.0
_cell_angle_gamma   107.46
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zn2OsW
_chemical_formula_sum   'Zn2 Os1 W1'
_cell_volume   59.33
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.0  0.12  0.9  1.0
  Zn  Zn1  1  0.0  0.44  0.9  1.0
  Os  Os2  1  0.0  0.91  0.52  1.0
  W  W3  1  0.0  0.27  0.53  1.0

Zn Zn Os W
Zn Zn Os W 0 1 o o o 0 2 + o o 0 3 o o o 1 3 o o o 2 3 - o o 
WOsZn2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one WOsZn2 cluster. W(1) is bonded in a 3-coordinate geometry to one Os(1), one Zn(1), and one Zn(2) atom. The W(1)-Os(1) bond length is 1.71 Å. The W(1)-Zn(1) bond length is 1.97 Å. The W(1)-Zn(2) bond length is 1.84 Å. Os(1) is bonded in a 2-coordinate geometry to one W(1) and one Zn(1) atom. The Os(1)-Zn(1) bond length is 1.96 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 3-coordinate geometry to one W(1), one Os(1), and one Zn(2) atom. The Zn(1)-Zn(2) bond length is 1.45 Å. In the second Zn site, Zn(2) is bonded in a 2-coordinate geometry to one W(1) and one Zn(1) atom.