data_LiLaV2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.61
_cell_length_b   5.61
_cell_length_c   2.72
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   121.75
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiLaV2
_chemical_formula_sum   'Li1 La1 V2'
_cell_volume   72.73
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.0  0.0  0.0  1.0
  La  La0  1  0.73  0.0  0.0  1.0
  V  V2  1  0.37  0.45  0.36  1.0
  V  V3  1  0.37  0.55  0.36  1.0

data_LiLaV2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.72
_cell_length_b   5.46
_cell_length_c   5.61
_cell_angle_alpha   119.12
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiLaV2
_chemical_formula_sum   'Li1 La1 V2'
_cell_volume   72.73
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.0  1.0
  La  La1  1  0.0  0.0  0.73  1.0
  V  V2  1  0.36  0.45  0.82  1.0
  V  V3  1  0.36  0.55  0.91  1.0

Li La V V
Li La V V 0 1 - o o 2 3 o o o 
LiLaV2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LiLaV2 cluster. Li(1) is bonded in a 2-coordinate geometry to one La(1) and one V(1) atom. The Li(1)-La(1) bond length is 1.51 Å. The Li(1)-V(1) bond length is 2.47 Å. La(1) is bonded in a 1-coordinate geometry to one Li(1) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted single-bond geometry to one Li(1) and one V(2) atom. The V(1)-V(2) bond length is 0.56 Å. In the second V site, V(2) is bonded in a distorted single-bond geometry to one V(1) atom.