data_InTcNi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.22
_cell_length_b   5.22
_cell_length_c   5.22
_cell_angle_alpha   149.01
_cell_angle_beta   129.21
_cell_angle_gamma   60.7
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InTcNi2
_chemical_formula_sum   'In1 Tc1 Ni2'
_cell_volume   56.41
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.0  0.24  0.35  1.0
  Tc  Tc3  1  0.0  0.0  0.36  1.0
  Ni  Ni1  1  0.0  0.0  0.13  1.0
  Ni  Ni2  1  0.4  0.0  0.17  1.0

data_InTcNi2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.79
_cell_length_b   4.48
_cell_length_c   5.22
_cell_angle_alpha   115.4
_cell_angle_beta   105.49
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InTcNi2
_chemical_formula_sum   'In1 Tc1 Ni2'
_cell_volume   56.41
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.65  0.89  0.89  1.0
  Tc  Tc1  1  0.64  0.64  0.64  1.0
  Ni  Ni2  1  0.22  0.83  0.22  1.0
  Ni  Ni3  1  0.87  0.87  0.87  1.0

In Tc Ni Ni
In Tc Ni Ni 0 2 o o o 0 1 o o o 0 3 o o o 1 2 o o o 2 3 o o o 
TcNi2In crystallizes in the triclinic P1 space group. Tc(1) is bonded in a 2-coordinate geometry to one Ni(1), two equivalent Ni(2), and one In(1) atom. The Tc(1)-Ni(1) bond length is 1.25 Å. There is one shorter (2.64 Å) and one longer (3.34 Å) Tc(1)-Ni(2) bond length. The Tc(1)-In(1) bond length is 1.30 Å. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a distorted single-bond geometry to one Tc(1), one Ni(2), and one In(1) atom. The Ni(1)-Ni(2) bond length is 1.92 Å. The Ni(1)-In(1) bond length is 0.66 Å. In the second Ni site, Ni(2) is bonded in a 7-coordinate geometry to two equivalent Tc(1), one Ni(1), two equivalent Ni(2), and two equivalent In(1) atoms. Both Ni(2)-Ni(2) bond lengths are 2.79 Å. There is one shorter (2.15 Å) and one longer (2.46 Å) Ni(2)-In(1) bond length. In(1) is bonded in a distorted single-bond geometry to one Tc(1), one Ni(1), and two equivalent Ni(2) atoms.