data_TlVW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.35
_cell_length_b   5.35
_cell_length_c   5.35
_cell_angle_alpha   144.51
_cell_angle_beta   130.13
_cell_angle_gamma   62.7
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlVW2
_chemical_formula_sum   'Tl1 V1 W2'
_cell_volume   67.3
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.0  0.0  0.57  1.0
  V  V1  1  0.0  0.0  0.0  1.0
  W  W2  1  0.63  0.0  0.12  1.0
  W  W3  1  0.0  0.26  0.45  1.0

data_TlVW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.26
_cell_length_b   4.51
_cell_length_c   5.35
_cell_angle_alpha   114.94
_cell_angle_beta   107.75
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlVW2
_chemical_formula_sum   'Tl1 V1 W2'
_cell_volume   67.3
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.0  0.57  0.57  1.0
  V  V1  1  0.0  0.0  0.0  1.0
  W  W2  1  0.0  0.12  0.49  1.0
  W  W3  1  0.74  0.19  0.19  1.0

Tl V W W
Tl V W W 0 3 o o o 0 2 - o o 1 3 o o o 2 3 + o o 
VW2Tl crystallizes in the triclinic P1 space group. V(1) is bonded in a 2-coordinate geometry to two equivalent W(2) and one Tl(1) atom. There is one shorter (1.52 Å) and one longer (2.33 Å) V(1)-W(2) bond length. The V(1)-Tl(1) bond length is 2.30 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 1-coordinate geometry to one W(2) and two equivalent Tl(1) atoms. The W(1)-W(2) bond length is 1.71 Å. There is one shorter (1.89 Å) and one longer (2.69 Å) W(1)-Tl(1) bond length. In the second W site, W(2) is bonded in a 4-coordinate geometry to two equivalent V(1), one W(1), and one Tl(1) atom. The W(2)-Tl(1) bond length is 1.93 Å. Tl(1) is bonded in a 4-coordinate geometry to one V(1), one W(2), and two equivalent W(1) atoms.