data_ZrTlCd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.71
_cell_length_b   5.71
_cell_length_c   3.16
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   114.82
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrTlCd2
_chemical_formula_sum   'Zr1 Tl1 Cd2'
_cell_volume   93.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr3  1  0.0  0.0  0.0  1.0
  Tl  Tl2  1  0.08  0.0  0.0  1.0
  Cd  Cd0  1  0.54  0.41  0.58  1.0
  Cd  Cd1  1  0.54  0.59  0.58  1.0

data_ZrTlCd2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.16
_cell_length_b   5.71
_cell_length_c   5.71
_cell_angle_alpha   114.82
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrTlCd2
_chemical_formula_sum   'Zr1 Tl1 Cd2'
_cell_volume   93.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.0  0.0  0.0  1.0
  Tl  Tl1  1  0.0  0.08  0.0  1.0
  Cd  Cd2  1  0.58  0.54  0.41  1.0
  Cd  Cd3  1  0.58  0.54  0.59  1.0

Zr Tl Cd Cd
Zr Tl Cd Cd 0 1 o o o 2 3 o o o 
ZrTl(Cd)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Cd cluster and one ZrTl cluster. In the Cd cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted single-bond geometry to one Cd(2) atom. The Cd(1)-Cd(2) bond length is 1.06 Å. In the second Cd site, Cd(2) is bonded in a distorted single-bond geometry to one Cd(1) atom. In the ZrTl cluster, Zr(1) is bonded in a single-bond geometry to one Tl(1) atom. The Zr(1)-Tl(1) bond length is 0.45 Å. Tl(1) is bonded in a single-bond geometry to one Zr(1) atom.