data_RePd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.06
_cell_length_b   6.06
_cell_length_c   6.06
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   RePd2
_chemical_formula_sum   'Re4 Pd8'
_cell_volume   222.68
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re8  1  0.0  0.0  0.0  1.0
  Re  Re9  1  0.0  0.03  0.03  1.0
  Re  Re10  1  0.03  0.0  0.03  1.0
  Re  Re11  1  0.03  0.03  0.0  1.0
  Pd  Pd0  1  0.75  0.78  0.31  1.0
  Pd  Pd1  1  0.75  0.31  0.28  1.0
  Pd  Pd2  1  0.28  0.75  0.31  1.0
  Pd  Pd3  1  0.28  0.28  0.28  1.0
  Pd  Pd4  1  0.78  0.78  0.78  1.0
  Pd  Pd5  1  0.78  0.31  0.75  1.0
  Pd  Pd6  1  0.31  0.75  0.78  1.0
  Pd  Pd7  1  0.31  0.28  0.75  1.0

data_RePd2
_symmetry_space_group_name_H-M   R3
_cell_length_a   8.57
_cell_length_b   8.57
_cell_length_c   10.5
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   146
_chemical_formula_structural   RePd2
_chemical_formula_sum   'Re12 Pd24'
_cell_volume   668.04
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  'x+1/3, y+2/3, z+2/3'
  5  '-y+1/3, x-y+2/3, z+2/3'
  6  '-x+y+1/3, -x+2/3, z+2/3'
  7  'x+2/3, y+1/3, z+1/3'
  8  '-y+2/3, x-y+1/3, z+1/3'
  9  '-x+y+2/3, -x+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  9  0.01  0.02  0.02  1.0
  Re  Re1  3  0.0  0.0  0.0  1.0
  Pd  Pd2  9  0.03  0.5  0.28  1.0
  Pd  Pd3  9  0.16  0.8  0.11  1.0
  Pd  Pd4  3  0.0  0.0  0.28  1.0
  Pd  Pd5  3  0.0  0.0  0.78  1.0

Re Re Re Re Pd Pd Pd Pd Pd Pd Pd Pd
Re Re Re Re Pd Pd Pd Pd Pd Pd Pd Pd 0 2 o o o 0 1 o o o 0 3 o o o 0 4 - - o 0 5 - o o 0 6 o - o 0 7 o o o 0 8 - - - 0 9 - o - 0 10 o - - 0 11 o o - 1 2 o o o 1 3 o o o 1 4 - - o 1 5 - o o 1 6 o - o 1 7 o o o 1 8 - - - 1 9 - o - 1 10 o - - 1 11 o o - 2 3 o o o 2 4 - - o 2 5 - o o 2 6 o - o 2 7 o o o 2 8 - - - 2 9 - o - 2 10 o - - 2 11 o o - 3 4 - - o 3 5 - o o 3 6 o - o 3 7 o o o 3 8 - - - 3 9 - o - 3 10 o - - 3 11 o o - 4 6 o o o 4 6 + o o 4 5 o o o 4 5 o + o 4 8 o o - 4 8 o o o 5 7 o o o 5 7 + o o 5 9 o o - 5 9 o o o 6 7 o o o 6 7 o + o 6 10 o o - 6 10 o o o 7 11 o o - 7 11 o o o 8 10 o o o 8 10 + o o 8 9 o o o 8 9 o + o 9 11 o o o 9 11 + o o 10 11 o o o 10 11 o + o 
RePd2 crystallizes in the trigonal R3 space group. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 4-coordinate geometry to three equivalent Re(2), one Pd(4), and three equivalent Pd(1) atoms. All Re(1)-Re(2) bond lengths are 0.26 Å. The Re(1)-Pd(4) bond length is 2.27 Å. All Re(1)-Pd(1) bond lengths are 2.73 Å. In the second Re site, Re(2) is bonded in a 3-coordinate geometry to one Re(1), two equivalent Re(2), one Pd(2), one Pd(3), and two equivalent Pd(1) atoms. Both Re(2)-Re(2) bond lengths are 0.26 Å. The Re(2)-Pd(2) bond length is 2.70 Å. The Re(2)-Pd(3) bond length is 2.70 Å. There is one shorter (2.70 Å) and one longer (2.72 Å) Re(2)-Pd(1) bond length. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to one Re(1), two equivalent Re(2), two equivalent Pd(4), and four equivalent Pd(2) atoms. There is one shorter (2.89 Å) and one longer (3.18 Å) Pd(1)-Pd(4) bond length. There are two shorter (2.89 Å) and two longer (3.18 Å) Pd(1)-Pd(2) bond lengths. In the second Pd site, Pd(2) is bonded in a 7-coordinate geometry to one Re(2), two equivalent Pd(3), and four equivalent Pd(1) atoms. There is one shorter (2.89 Å) and one longer (3.18 Å) Pd(2)-Pd(3) bond length. In the third Pd site, Pd(3) is bonded in a 9-coordinate geometry to three equivalent Re(2) and six equivalent Pd(2) atoms. In the fourth Pd site, Pd(4) is bonded in a distorted single-bond geometry to one Re(1) and six equivalent Pd(1) atoms.