data_V2GeMo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.64
_cell_length_b   2.64
_cell_length_c   8.45
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2GeMo
_chemical_formula_sum   'V2 Ge1 Mo1'
_cell_volume   59.01
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.0  0.07  1.0
  V  V3  1  0.32  0.32  0.15  1.0
  Ge  Ge0  1  0.0  0.0  0.13  1.0
  Mo  Mo1  1  0.32  0.32  0.32  1.0

data_V2GeMo
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.74
_cell_length_b   3.74
_cell_length_c   8.45
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   V2GeMo
_chemical_formula_sum   'V4 Ge2 Mo2'
_cell_volume   118.02
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.07  1.0
  V  V1  2  0.32  0.0  0.15  1.0
  Ge  Ge2  2  0.0  0.0  0.13  1.0
  Mo  Mo3  2  0.32  0.0  0.32  1.0

V V Ge Mo
V V Ge Mo 0 2 o o o 0 1 o o o 1 2 o o o 1 3 o o o 
V2MoGe crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two V2MoGe clusters. There are two inequivalent V sites. In the first V site, V(1) is bonded in a single-bond geometry to one Ge(1) atom. The V(1)-Ge(1) bond length is 0.51 Å. In the second V site, V(2) is bonded in a distorted L-shaped geometry to one Mo(1) and one Ge(1) atom. The V(2)-Mo(1) bond length is 1.47 Å. The V(2)-Ge(1) bond length is 1.20 Å. Mo(1) is bonded in a single-bond geometry to one V(2) atom. Ge(1) is bonded in a distorted single-bond geometry to one V(1) and one V(2) atom.