data_LiCd2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.06
_cell_length_b   5.06
_cell_length_c   2.84
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiCd2W
_chemical_formula_sum   'Li1 Cd2 W1'
_cell_volume   72.89
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li2  1  0.0  0.0  0.0  1.0
  Cd  Cd0  1  0.53  0.0  0.42  1.0
  Cd  Cd1  1  0.0  0.53  0.42  1.0
  W  W3  1  0.53  0.53  0.0  1.0

data_LiCd2W
_symmetry_space_group_name_H-M   Cm
_cell_length_a   7.16
_cell_length_b   7.16
_cell_length_c   2.84
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LiCd2W
_chemical_formula_sum   'Li2 Cd4 W2'
_cell_volume   145.77
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.0  1.0
  Cd  Cd1  4  0.27  0.27  0.42  1.0
  W  W2  2  0.03  0.5  0.0  1.0

Li Cd Cd W
Li Cd Cd W 0 3 - - o 0 1 - o - 0 1 - o o 0 1 o o - 0 1 o o o 0 2 o - - 0 2 o - o 0 2 o o - 0 2 o o o 0 0 o o + 1 3 o - o 1 3 o - + 1 3 o o o 1 3 o o + 1 2 + - o 1 1 o o + 2 3 - o o 2 3 - o + 2 3 o o o 2 3 o o + 2 2 o o + 3 3 o o + 
LiWCd2 crystallizes in the monoclinic Cm space group. Li(1) is bonded in a 8-coordinate geometry to eight equivalent Cd(1) atoms. There are a spread of Li(1)-Cd(1) bond distances ranging from 2.65-3.16 Å. W(1) is bonded in a 8-coordinate geometry to eight equivalent Cd(1) atoms. There are a spread of W(1)-Cd(1) bond distances ranging from 2.65-3.16 Å. Cd(1) is bonded in a 10-coordinate geometry to four equivalent Li(1), four equivalent W(1), and two equivalent Cd(1) atoms. Both Cd(1)-Cd(1) bond lengths are 2.84 Å.