data_NaMnMo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.56
_cell_length_b   4.56
_cell_length_c   2.51
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaMnMo
_chemical_formula_sum   'Na1 Mn1 Mo1'
_cell_volume   45.16
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na2  1  0.0  0.0  0.7  1.0
  Mn  Mn0  1  1.0  0.63  0.09  1.0
  Mo  Mo1  1  0.28  0.32  0.72  1.0

data_NaMnMo
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.51
_cell_length_b   4.56
_cell_length_c   4.56
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaMnMo
_chemical_formula_sum   'Na1 Mn1 Mo1'
_cell_volume   45.16
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.7  0.0  0.0  1.0
  Mn  Mn1  1  0.09  1.0  0.63  1.0
  Mo  Mo2  1  0.72  0.28  0.32  1.0

Na Mn Mo
Na Mn Mo 0 2 o o o 0 1 - - + 0 1 - - o 1 1 o o + 
NaMoMn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one NaMoMn cluster. Na(1) is bonded in a distorted single-bond geometry to one Mo(1) and one Mn(1) atom. The Na(1)-Mo(1) bond length is 1.36 Å. The Na(1)-Mn(1) bond length is 1.94 Å. Mo(1) is bonded in a single-bond geometry to one Na(1) atom. Mn(1) is bonded in a 1-coordinate geometry to one Na(1) atom.