data_SbRhW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.07
_cell_length_b   3.07
_cell_length_c   7.08
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SbRhW2
_chemical_formula_sum   'Sb1 Rh1 W2'
_cell_volume   66.74
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb1  1  0.0  0.0  0.54  1.0
  Rh  Rh0  1  0.0  0.0  0.0  1.0
  W  W2  1  0.53  0.53  0.34  1.0
  W  W3  1  0.53  0.53  0.75  1.0

data_SbRhW2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.34
_cell_length_b   4.34
_cell_length_c   7.08
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   SbRhW2
_chemical_formula_sum   'Sb2 Rh2 W4'
_cell_volume   133.49
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  2  0.0  0.0  0.54  1.0
  Rh  Rh1  2  0.0  0.0  0.0  1.0
  W  W2  2  0.03  0.5  0.34  1.0
  W  W3  2  0.03  0.5  0.75  1.0

Sb Rh W W
Sb Rh W W 0 2 - - o 0 2 - o o 0 2 o - o 0 2 o o o 0 3 - - o 0 3 - o o 0 3 o - o 0 3 o o o 0 0 + o o 0 0 o + o 0 1 o o + 1 3 - - - 1 3 - o - 1 3 o - - 1 3 o o - 1 2 - - o 1 2 - o o 1 2 o - o 1 2 o o o 1 1 + o o 1 1 o + o 2 2 + o o 2 2 o + o 2 3 o o o 3 3 + o o 3 3 o + o 
W2RhSb crystallizes in the monoclinic Cm space group. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 4-coordinate geometry to four equivalent Rh(1) and four equivalent Sb(1) atoms. There are a spread of W(1)-Rh(1) bond distances ranging from 3.14-3.34 Å. There are a spread of W(1)-Sb(1) bond distances ranging from 2.48-2.73 Å. In the second W site, W(2) is bonded in a 8-coordinate geometry to four equivalent Rh(1) and four equivalent Sb(1) atoms. There are a spread of W(2)-Rh(1) bond distances ranging from 2.71-2.94 Å. There are a spread of W(2)-Sb(1) bond distances ranging from 2.48-2.73 Å. Rh(1) is bonded in a 13-coordinate geometry to four equivalent W(1), four equivalent W(2), four equivalent Rh(1), and one Sb(1) atom. All Rh(1)-Rh(1) bond lengths are 3.07 Å. The Rh(1)-Sb(1) bond length is 3.24 Å. Sb(1) is bonded in a distorted body-centered cubic geometry to four equivalent W(1), four equivalent W(2), and one Rh(1) atom.