data_Na2VRe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.88
_cell_length_b   5.88
_cell_length_c   4.39
_cell_angle_alpha   102.7
_cell_angle_beta   102.7
_cell_angle_gamma   28.21
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na2VRe
_chemical_formula_sum   'Na2 V1 Re1'
_cell_volume   69.8
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.33  0.0  0.09  1.0
  Na  Na1  1  0.08  0.0  0.19  1.0
  V  V3  1  0.0  0.0  0.0  1.0
  Re  Re2  1  0.2  0.0  0.14  1.0

data_Na2VRe
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.86
_cell_length_b   4.39
_cell_length_c   5.88
_cell_angle_alpha   102.7
_cell_angle_beta   104.1
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na2VRe
_chemical_formula_sum   'Na2 V1 Re1'
_cell_volume   69.8
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.09  0.33  1.0
  Na  Na1  1  0.0  0.19  0.08  1.0
  V  V2  1  0.0  0.0  0.0  1.0
  Re  Re3  1  0.0  0.14  0.2  1.0

Na Na V Re
Na Na V Re 0 3 o o o 1 2 o o o 1 3 o o o 
Na2VRe crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Na2VRe cluster. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a single-bond geometry to one Re(1) atom. The Na(1)-Re(1) bond length is 0.82 Å. In the second Na site, Na(2) is bonded in an L-shaped geometry to one V(1) and one Re(1) atom. The Na(2)-V(1) bond length is 0.85 Å. The Na(2)-Re(1) bond length is 0.82 Å. V(1) is bonded in a distorted single-bond geometry to one Na(2) atom. Re(1) is bonded in a linear geometry to one Na(1) and one Na(2) atom.