data_MnZnRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.64
_cell_length_b   4.64
_cell_length_c   4.49
_cell_angle_alpha   101.26
_cell_angle_beta   101.26
_cell_angle_gamma   34.1
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnZnRh2
_chemical_formula_sum   'Mn1 Zn1 Rh2'
_cell_volume   53.0
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.4  0.0  0.97  1.0
  Zn  Zn3  1  0.95  0.0  0.3  1.0
  Rh  Rh1  1  0.01  0.0  0.17  1.0
  Rh  Rh2  1  0.57  0.0  0.14  1.0

data_MnZnRh2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.72
_cell_length_b   4.49
_cell_length_c   4.64
_cell_angle_alpha   101.26
_cell_angle_beta   107.05
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnZnRh2
_chemical_formula_sum   'Mn1 Zn1 Rh2'
_cell_volume   53.0
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.0  0.97  0.4  1.0
  Zn  Zn1  1  0.0  0.3  0.95  1.0
  Rh  Rh2  1  0.0  0.14  0.57  1.0
  Rh  Rh3  1  0.0  0.17  0.01  1.0

Mn Zn Rh Rh
Mn Zn Rh Rh 0 3 o o + 1 2 + o o 
MnRhRhZn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one MnRh cluster and one RhZn cluster. In the MnRh cluster, Mn(1) is bonded in a distorted single-bond geometry to one Rh(2) atom. The Mn(1)-Rh(2) bond length is 0.99 Å. Rh(2) is bonded in a distorted single-bond geometry to one Mn(1) atom. In the RhZn cluster, Rh(1) is bonded in a single-bond geometry to one Zn(1) atom. The Rh(1)-Zn(1) bond length is 0.67 Å. Zn(1) is bonded in a distorted single-bond geometry to one Rh(1) atom.