data_TiTeW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.68
_cell_length_b   4.68
_cell_length_c   2.95
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiTeW
_chemical_formula_sum   'Ti1 Te1 W1'
_cell_volume   55.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti1  1  0.0  0.0  0.0  1.0
  Te  Te0  1  0.34  0.35  0.48  1.0
  W  W2  1  0.0  0.7  0.48  1.0

data_TiTeW
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.95
_cell_length_b   4.68
_cell_length_c   4.68
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiTeW
_chemical_formula_sum   'Ti1 Te1 W1'
_cell_volume   55.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.0  0.0  0.0  1.0
  Te  Te1  1  0.48  0.34  0.35  1.0
  W  W2  1  0.48  0.0  0.7  1.0

Ti Te W
Ti Te W 0 2 o - - 0 2 o - o 0 1 o o - 0 1 o o o 1 2 o - o 
TiWTe crystallizes in the triclinic P1 space group. Ti(1) is bonded in a 4-coordinate geometry to two equivalent W(1) and two equivalent Te(1) atoms. There is one shorter (1.99 Å) and one longer (2.09 Å) Ti(1)-W(1) bond length. There is one shorter (2.14 Å) and one longer (2.23 Å) Ti(1)-Te(1) bond length. W(1) is bonded in a distorted L-shaped geometry to two equivalent Ti(1) and two equivalent Te(1) atoms. There is one shorter (2.68 Å) and one longer (2.79 Å) W(1)-Te(1) bond length. Te(1) is bonded in a 4-coordinate geometry to two equivalent Ti(1) and two equivalent W(1) atoms.