data_Ta2PRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.52
_cell_length_b   4.52
_cell_length_c   3.17
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   103.39
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ta2PRh
_chemical_formula_sum   'Ta2 P1 Rh1'
_cell_volume   62.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta2  1  0.4  0.23  0.58  1.0
  Ta  Ta3  1  0.4  0.77  0.58  1.0
  P  P0  1  0.0  0.0  0.0  1.0
  Rh  Rh1  1  0.8  0.0  0.0  1.0

data_Ta2PRh
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.17
_cell_length_b   4.52
_cell_length_c   4.52
_cell_angle_alpha   103.39
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ta2PRh
_chemical_formula_sum   'Ta2 P1 Rh1'
_cell_volume   62.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  1  0.58  0.4  0.23  1.0
  Ta  Ta1  1  0.58  0.4  0.77  1.0
  P  P2  1  0.0  0.0  0.0  1.0
  Rh  Rh3  1  0.0  0.8  0.0  1.0

Ta Ta P Rh
Ta Ta P Rh 0 2 o o o 0 2 o o + 0 1 o o o 0 1 o - o 0 3 o o + 1 2 o + + 1 3 o + o 1 3 o + + 2 3 - o o 
Ta2RhP crystallizes in the triclinic P1 space group. There are two inequivalent Ta sites. In the first Ta site, Ta(1) is bonded in a 6-coordinate geometry to two equivalent Ta(2), two equivalent Rh(1), and two equivalent P(1) atoms. There is one shorter (2.06 Å) and one longer (2.46 Å) Ta(1)-Ta(2) bond length. There is one shorter (2.63 Å) and one longer (2.93 Å) Ta(1)-Rh(1) bond length. There is one shorter (2.28 Å) and one longer (2.62 Å) Ta(1)-P(1) bond length. In the second Ta site, Ta(2) is bonded in a 6-coordinate geometry to two equivalent Ta(1), two equivalent Rh(1), and two equivalent P(1) atoms. There is one shorter (2.28 Å) and one longer (2.62 Å) Ta(2)-Rh(1) bond length. There is one shorter (2.63 Å) and one longer (2.93 Å) Ta(2)-P(1) bond length. Rh(1) is bonded in a 5-coordinate geometry to two equivalent Ta(1), two equivalent Ta(2), and one P(1) atom. The Rh(1)-P(1) bond length is 0.90 Å. P(1) is bonded in a 5-coordinate geometry to two equivalent Ta(1), two equivalent Ta(2), and one Rh(1) atom.