data_LaRhCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.8
_cell_length_b   5.8
_cell_length_c   5.8
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaRhCl4
_chemical_formula_sum   'La1 Rh1 Cl4'
_cell_volume   137.62
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La4  1  0.15  0.15  0.15  1.0
  Rh  Rh5  1  0.0  0.0  0.0  1.0
  Cl  Cl0  1  0.12  0.12  0.07  1.0
  Cl  Cl1  1  0.12  0.07  0.12  1.0
  Cl  Cl2  1  0.07  0.12  0.12  1.0
  Cl  Cl3  1  0.07  0.07  0.07  1.0

data_LaRhCl4
_symmetry_space_group_name_H-M   R3m
_cell_length_a   5.8
_cell_length_b   5.8
_cell_length_c   14.2
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   LaRhCl4
_chemical_formula_sum   'La3 Rh3 Cl12'
_cell_volume   412.85
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  3  0.0  0.0  0.85  1.0
  Rh  Rh1  3  0.0  0.0  0.0  1.0
  Cl  Cl2  9  0.03  0.02  0.89  1.0
  Cl  Cl3  3  0.0  0.0  0.93  1.0

La Rh Cl Cl Cl Cl
La Rh Cl Cl Cl Cl 0 4 o o o 0 3 o o o 0 2 o o o 1 5 o o o 2 3 o o o 2 4 o o o 2 5 o o o 3 4 o o o 3 5 o o o 4 5 o o o 
LaCl3RhCl is Zincblende, Sphalerite structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three LaCl3 clusters and three RhCl clusters. In each LaCl3 cluster, La(1) is bonded in a 3-coordinate geometry to three equivalent Cl(1) atoms. All La(1)-Cl(1) bond lengths are 0.60 Å. Cl(1) is bonded in a 3-coordinate geometry to one La(1) and two equivalent Cl(1) atoms. Both Cl(1)-Cl(1) bond lengths are 0.27 Å. In each RhCl cluster, Rh(1) is bonded in a single-bond geometry to one Cl(2) atom. The Rh(1)-Cl(2) bond length is 1.05 Å. Cl(2) is bonded in a single-bond geometry to one Rh(1) atom.