data_InBiRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.76
_cell_length_b   4.76
_cell_length_c   3.31
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   95.13
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InBiRh2
_chemical_formula_sum   'In1 Bi1 Rh2'
_cell_volume   74.86
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In1  1  0.0  0.0  0.0  1.0
  Bi  Bi0  1  0.21  0.0  0.0  1.0
  Rh  Rh2  1  0.61  0.76  0.66  1.0
  Rh  Rh3  1  0.61  0.24  0.66  1.0

data_InBiRh2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.31
_cell_length_b   4.76
_cell_length_c   4.76
_cell_angle_alpha   95.13
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InBiRh2
_chemical_formula_sum   'In1 Bi1 Rh2'
_cell_volume   74.86
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.0  0.0  0.0  1.0
  Bi  Bi1  1  0.0  0.21  0.0  1.0
  Rh  Rh2  1  0.66  0.61  0.24  1.0
  Rh  Rh3  1  0.66  0.61  0.76  1.0

In Bi Rh Rh
In Bi Rh Rh 0 1 o o o 0 2 - - - 0 3 - o - 1 2 o - - 1 3 o o - 2 3 o + o 2 3 o o o 
Rh2InBi crystallizes in the triclinic P1 space group. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 6-coordinate geometry to two equivalent Rh(2), two equivalent In(1), and two equivalent Bi(1) atoms. There is one shorter (2.31 Å) and one longer (2.46 Å) Rh(1)-Rh(2) bond length. There is one shorter (2.40 Å) and one longer (3.03 Å) Rh(1)-In(1) bond length. There is one shorter (2.55 Å) and one longer (3.15 Å) Rh(1)-Bi(1) bond length. In the second Rh site, Rh(2) is bonded in a 6-coordinate geometry to two equivalent Rh(1), two equivalent In(1), and two equivalent Bi(1) atoms. There is one shorter (2.55 Å) and one longer (3.15 Å) Rh(2)-In(1) bond length. There is one shorter (2.40 Å) and one longer (3.03 Å) Rh(2)-Bi(1) bond length. In(1) is bonded in a 1-coordinate geometry to two equivalent Rh(1), two equivalent Rh(2), and one Bi(1) atom. The In(1)-Bi(1) bond length is 1.02 Å. Bi(1) is bonded in a distorted single-bond geometry to two equivalent Rh(1), two equivalent Rh(2), and one In(1) atom.