data_LiAgCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.59
_cell_length_b   4.59
_cell_length_c   3.44
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiAgCl
_chemical_formula_sum   'Li1 Ag1 Cl1'
_cell_volume   62.82
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li2  1  0.0  0.0  0.88  1.0
  Ag  Ag0  1  0.3  0.33  0.32  1.0
  Cl  Cl1  1  0.0  0.65  0.24  1.0

data_LiAgCl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.44
_cell_length_b   4.59
_cell_length_c   4.59
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiAgCl
_chemical_formula_sum   'Li1 Ag1 Cl1'
_cell_volume   62.82
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.88  0.0  0.0  1.0
  Ag  Ag1  1  0.32  0.3  0.33  1.0
  Cl  Cl2  1  0.24  0.0  0.65  1.0

Li Ag Cl
Li Ag Cl 0 2 o - + 0 1 o o o 0 1 o o + 1 2 o o o 
LiAgCl crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Cl(1) atoms. There is one shorter (2.08 Å) and one longer (2.41 Å) Li(1)-Ag(1) bond length. There is one shorter (2.03 Å) and one longer (2.71 Å) Li(1)-Cl(1) bond length. Ag(1) is bonded in a 5-coordinate geometry to two equivalent Li(1) and three equivalent Cl(1) atoms. There are a spread of Ag(1)-Cl(1) bond distances ranging from 2.49-2.81 Å. Cl(1) is bonded in a 1-coordinate geometry to two equivalent Li(1) and three equivalent Ag(1) atoms.