data_Ti2TcTe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.08
_cell_length_b   4.08
_cell_length_c   4.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ti2TcTe
_chemical_formula_sum   'Ti2 Tc1 Te1'
_cell_volume   67.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti2  1  0.04  0.0  0.02  1.0
  Ti  Ti3  1  0.0  0.04  0.02  1.0
  Tc  Tc0  1  0.0  0.0  0.0  1.0
  Te  Te1  1  0.04  0.04  0.0  1.0

data_Ti2TcTe
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.76
_cell_length_b   5.76
_cell_length_c   4.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Ti2TcTe
_chemical_formula_sum   'Ti4 Tc2 Te2'
_cell_volume   134.48
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  4  0.02  0.02  0.02  1.0
  Tc  Tc1  2  0.0  0.0  0.0  1.0
  Te  Te2  2  0.04  0.0  -0.0  1.0

Ti Ti Tc Te
Ti Ti Tc Te 0 2 o o o 0 3 o o o 1 2 o o o 1 3 o o o 
Ti2TcTe is alpha Po structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Ti2TcTe clusters. Ti(1) is bonded in a 2-coordinate geometry to one Tc(1) and one Te(1) atom. The Ti(1)-Tc(1) bond length is 0.18 Å. The Ti(1)-Te(1) bond length is 0.18 Å. Tc(1) is bonded in a 3-coordinate geometry to two equivalent Ti(1) and one Te(1) atom. The Tc(1)-Te(1) bond length is 0.22 Å. Te(1) is bonded in a 3-coordinate geometry to two equivalent Ti(1) and one Tc(1) atom.