data_Li2BiRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.16
_cell_length_b   5.16
_cell_length_c   5.16
_cell_angle_alpha   137.26
_cell_angle_beta   132.29
_cell_angle_gamma   65.96
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2BiRh
_chemical_formula_sum   'Li2 Bi1 Rh1'
_cell_volume   68.12
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.88  0.0  0.08  1.0
  Li  Li2  1  0.0  0.09  0.25  1.0
  Bi  Bi0  1  0.0  0.0  0.33  1.0
  Rh  Rh3  1  0.0  0.0  0.0  1.0

data_Li2BiRh
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.76
_cell_length_b   4.18
_cell_length_c   5.16
_cell_angle_alpha   113.85
_cell_angle_beta   111.37
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2BiRh
_chemical_formula_sum   'Li2 Bi1 Rh1'
_cell_volume   68.12
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.75  0.83  0.83  1.0
  Li  Li1  1  0.8  0.92  0.8  1.0
  Bi  Bi2  1  0.67  0.67  0.67  1.0
  Rh  Rh3  1  0.0  0.0  0.0  1.0

Li Li Bi Rh
Li Li Bi Rh 0 1 + o o 0 3 + o o 1 2 o o o 1 3 o o o 
Li2RhBi is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Li2RhBi cluster. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted L-shaped geometry to one Li(2) and one Rh(1) atom. The Li(1)-Li(2) bond length is 0.53 Å. The Li(1)-Rh(1) bond length is 0.93 Å. In the second Li site, Li(2) is bonded in a 3-coordinate geometry to one Li(1), one Rh(1), and one Bi(1) atom. The Li(2)-Rh(1) bond length is 1.02 Å. The Li(2)-Bi(1) bond length is 0.80 Å. Rh(1) is bonded in a 2-coordinate geometry to one Li(1) and one Li(2) atom. Bi(1) is bonded in a distorted single-bond geometry to one Li(2) atom.