data_AlInAgW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.66
_cell_length_b   4.66
_cell_length_c   4.66
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AlInAgW
_chemical_formula_sum   'Al1 In1 Ag1 W1'
_cell_volume   71.53
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al1  1  0.0  0.0  0.0  1.0
  In  In2  1  0.65  0.65  0.65  1.0
  Ag  Ag0  1  0.29  0.29  0.29  1.0
  W  W3  1  0.94  0.94  0.94  1.0

data_AlInAgW
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.66
_cell_length_b   4.66
_cell_length_c   11.41
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   AlInAgW
_chemical_formula_sum   'Al3 In3 Ag3 W3'
_cell_volume   214.59
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  3  0.0  0.0  0.0  1.0
  In  In1  3  0.0  0.0  0.35  1.0
  Ag  Ag2  3  0.0  0.0  0.71  1.0
  W  W3  3  0.0  0.0  0.06  1.0

Al In Ag W
Al In Ag W 0 3 - - - 0 1 o - - 0 1 - o - 0 1 - - o 0 2 o o - 0 2 o - o 0 2 - o o 1 2 o o + 1 2 o + o 1 2 + o o 1 3 - o o 1 3 o - o 1 3 o o - 2 3 - - o 2 3 - o - 2 3 o - - 
WAgInAl crystallizes in the trigonal R3m space group. W(1) is bonded in a single-bond geometry to three equivalent Ag(1), four equivalent In(1), and one Al(1) atom. All W(1)-Ag(1) bond lengths are 2.70 Å. There are three shorter (2.73 Å) and one longer (3.36 Å) W(1)-In(1) bond length. The W(1)-Al(1) bond length is 0.66 Å. Ag(1) is bonded in a 10-coordinate geometry to three equivalent W(1), three equivalent In(1), and four equivalent Al(1) atoms. All Ag(1)-In(1) bond lengths are 2.70 Å. There are three shorter (2.73 Å) and one longer (3.36 Å) Ag(1)-Al(1) bond length. In(1) is bonded in a distorted q6 geometry to four equivalent W(1), three equivalent Ag(1), and three equivalent Al(1) atoms. All In(1)-Al(1) bond lengths are 2.70 Å. Al(1) is bonded in a single-bond geometry to one W(1), four equivalent Ag(1), and three equivalent In(1) atoms.