data_TlMo2Pt
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.92
_cell_length_b   4.92
_cell_length_c   2.87
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlMo2Pt
_chemical_formula_sum   'Tl1 Mo2 Pt1'
_cell_volume   69.51
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl3  1  0.46  0.46  0.0  1.0
  Mo  Mo0  1  0.46  0.0  0.44  1.0
  Mo  Mo1  1  0.0  0.46  0.44  1.0
  Pt  Pt2  1  0.0  0.0  0.0  1.0

data_TlMo2Pt
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.96
_cell_length_b   6.96
_cell_length_c   2.87
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TlMo2Pt
_chemical_formula_sum   'Tl2 Mo4 Pt2'
_cell_volume   139.01
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  2  0.46  0.0  0.0  1.0
  Mo  Mo1  4  0.23  0.23  0.44  1.0
  Pt  Pt2  2  0.0  0.0  0.0  1.0

Tl Mo Mo Pt
Tl Mo Mo Pt 0 3 o o o 0 2 o o - 0 2 o o o 0 2 + o - 0 2 + o o 0 1 o o - 0 1 o o o 0 1 o + - 0 1 o + o 0 0 o o + 1 3 o o o 1 3 o o + 1 3 + o o 1 3 + o + 1 2 o o o 1 1 o o + 2 3 o o o 2 3 o o + 2 3 o + o 2 3 o + + 2 2 o o + 3 3 o o + 
Mo2PtTl crystallizes in the monoclinic Cm space group. Mo(1) is bonded in a 10-coordinate geometry to two equivalent Mo(1), four equivalent Pt(1), and four equivalent Tl(1) atoms. Both Mo(1)-Mo(1) bond lengths are 2.87 Å. There are a spread of Mo(1)-Pt(1) bond distances ranging from 2.59-3.11 Å. There are a spread of Mo(1)-Tl(1) bond distances ranging from 2.59-3.11 Å. Pt(1) is bonded in a 11-coordinate geometry to eight equivalent Mo(1), two equivalent Pt(1), and one Tl(1) atom. Both Pt(1)-Pt(1) bond lengths are 2.87 Å. The Pt(1)-Tl(1) bond length is 3.20 Å. Tl(1) is bonded in a 8-coordinate geometry to eight equivalent Mo(1) and one Pt(1) atom.