data_SrRh4Au
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.34
_cell_length_b   5.34
_cell_length_c   5.34
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SrRh4Au
_chemical_formula_sum   'Sr1 Rh4 Au1'
_cell_volume   107.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr5  1  0.0  0.0  0.0  1.0
  Rh  Rh1  1  0.84  0.84  0.72  1.0
  Rh  Rh2  1  0.84  0.72  0.84  1.0
  Rh  Rh3  1  0.72  0.84  0.84  1.0
  Rh  Rh4  1  0.72  0.72  0.72  1.0
  Au  Au0  1  0.89  0.89  0.89  1.0

data_SrRh4Au
_symmetry_space_group_name_H-M   R3m
_cell_length_a   5.34
_cell_length_b   5.34
_cell_length_c   13.09
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   SrRh4Au
_chemical_formula_sum   'Sr3 Rh12 Au3'
_cell_volume   323.91
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  3  0.0  0.0  0.0  1.0
  Rh  Rh1  9  0.08  0.04  0.2  1.0
  Rh  Rh2  3  0.0  0.0  0.28  1.0
  Au  Au3  3  0.0  0.0  0.11  1.0

Sr Rh Rh Rh Rh Au
Sr Rh Rh Rh Rh Au 0 5 - - - 1 2 o o o 1 3 o o o 1 4 o o o 1 5 o o o 2 3 o o o 2 4 o o o 2 5 o o o 3 4 o o o 3 5 o o o 
SrRh4Au crystallizes in the trigonal R3m space group. Sr(1) is bonded in a single-bond geometry to three equivalent Rh(1), three equivalent Rh(2), and one Au(1) atom. All Sr(1)-Rh(1) bond lengths are 3.22 Å. All Sr(1)-Rh(2) bond lengths are 3.16 Å. The Sr(1)-Au(1) bond length is 1.44 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 5-coordinate geometry to one Sr(1), one Rh(2), two equivalent Rh(1), and one Au(1) atom. The Rh(1)-Rh(2) bond length is 1.13 Å. Both Rh(1)-Rh(1) bond lengths are 0.65 Å. The Rh(1)-Au(1) bond length is 1.24 Å. In the second Rh site, Rh(2) is bonded in a 6-coordinate geometry to three equivalent Sr(1) and three equivalent Rh(1) atoms. Au(1) is bonded in a single-bond geometry to one Sr(1) and three equivalent Rh(1) atoms.