data_ReBSb2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.23
_cell_length_b   3.23
_cell_length_c   6.83
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ReBSb2
_chemical_formula_sum   'Re1 B1 Sb2'
_cell_volume   71.48
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re1  1  0.0  0.0  0.42  1.0
  B  B0  1  0.0  0.0  0.0  1.0
  Sb  Sb2  1  0.62  0.62  0.11  1.0
  Sb  Sb3  1  0.62  0.62  0.73  1.0

data_ReBSb2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.57
_cell_length_b   4.57
_cell_length_c   6.83
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ReBSb2
_chemical_formula_sum   'Re2 B2 Sb4'
_cell_volume   142.97
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  2  0.0  0.0  0.42  1.0
  B  B1  2  0.0  0.0  0.0  1.0
  Sb  Sb2  2  0.12  0.5  0.11  1.0
  Sb  Sb3  2  0.12  0.5  0.73  1.0

Re B Sb Sb
Re B Sb Sb 0 2 - - o 0 2 - o o 0 2 o - o 0 2 o o o 0 3 - - o 0 3 - o o 0 3 o - o 0 3 o o o 0 0 + o o 0 0 o + o 0 1 o o o 1 2 - - o 1 3 o - - 1 3 - o - 1 3 - - - 2 3 o o - 3 3 + o o 3 3 o + o 
ReBSb2 crystallizes in the monoclinic Cm space group. Re(1) is bonded in a 13-coordinate geometry to four equivalent Re(1), one B(1), four equivalent Sb(1), and four equivalent Sb(2) atoms. All Re(1)-Re(1) bond lengths are 3.23 Å. The Re(1)-B(1) bond length is 2.85 Å. There are a spread of Re(1)-Sb(1) bond distances ranging from 2.75-3.53 Å. There are a spread of Re(1)-Sb(2) bond distances ranging from 2.75-3.53 Å. B(1) is bonded in a 1-coordinate geometry to one Re(1), one Sb(1), and one Sb(2) atom. The B(1)-Sb(1) bond length is 1.89 Å. The B(1)-Sb(2) bond length is 2.56 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 1-coordinate geometry to four equivalent Re(1), one B(1), and one Sb(2) atom. The Sb(1)-Sb(2) bond length is 2.58 Å. In the second Sb site, Sb(2) is bonded in a 5-coordinate geometry to four equivalent Re(1), one B(1), and one Sb(1) atom.