data_TcAgAu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.75
_cell_length_b   4.21
_cell_length_c   5.91
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TcAgAu2
_chemical_formula_sum   'Tc1 Ag1 Au2'
_cell_volume   68.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc3  1  0.0  0.0  0.9  1.0
  Ag  Ag0  1  0.37  0.11  0.42  1.0
  Au  Au1  1  0.0  0.0  0.86  1.0
  Au  Au2  1  0.37  0.11  0.6  1.0

data_TcAgAu2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.75
_cell_length_b   4.21
_cell_length_c   5.91
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TcAgAu2
_chemical_formula_sum   'Tc1 Ag1 Au2'
_cell_volume   68.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.0  0.0  0.9  1.0
  Ag  Ag1  1  0.37  0.11  0.42  1.0
  Au  Au2  1  0.0  0.0  0.86  1.0
  Au  Au3  1  0.37  0.11  0.6  1.0

Tc Ag Au Au
Tc Ag Au Au 0 2 o o o 1 3 o o o 
TcAuAuAg is beta oxygen-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one AuAg cluster and one TcAu cluster. In the AuAg cluster, Au(2) is bonded in a single-bond geometry to one Ag(1) atom. The Au(2)-Ag(1) bond length is 1.06 Å. Ag(1) is bonded in a single-bond geometry to one Au(2) atom. In the TcAu cluster, Tc(1) is bonded in a single-bond geometry to one Au(1) atom. The Tc(1)-Au(1) bond length is 0.21 Å. Au(1) is bonded in a single-bond geometry to one Tc(1) atom.