data_SmIn5Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.7
_cell_length_b   4.7
_cell_length_c   7.57
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SmIn5Rh
_chemical_formula_sum   'Sm1 In5 Rh1'
_cell_volume   167.19
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.0  0.0  0.79  1.0
  In  In1  1  0.0  0.35  0.08  1.0
  In  In2  1  0.0  0.35  0.49  1.0
  In  In3  1  0.35  0.0  0.08  1.0
  In  In4  1  0.35  0.0  0.49  1.0
  In  In5  1  0.35  0.35  0.79  1.0
  Rh  Rh6  1  0.0  0.0  0.0  1.0

data_SmIn5Rh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.64
_cell_length_b   6.64
_cell_length_c   7.57
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   SmIn5Rh
_chemical_formula_sum   'Sm2 In10 Rh2'
_cell_volume   334.37
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  2  0.0  0.0  0.79  1.0
  In  In1  4  0.17  0.17  0.08  1.0
  In  In2  4  0.17  0.17  0.49  1.0
  In  In3  2  0.35  0.0  0.79  1.0
  Rh  Rh4  2  0.0  0.0  0.0  1.0

Sm In In In In In Rh
Sm In In In In In Rh 0 6 o o + 0 2 o o o 0 4 o o o 0 5 o o o 1 6 o o o 1 5 o o - 2 4 o o o 2 5 o o o 3 6 o o o 3 5 o o - 4 5 o o o 5 6 o o + 
SmRhIn5 crystallizes in the monoclinic Cm space group. Sm(1) is bonded in a distorted single-bond geometry to one Rh(1), one In(3), and four equivalent In(2) atoms. The Sm(1)-Rh(1) bond length is 1.61 Å. The Sm(1)-In(3) bond length is 2.32 Å. There are two shorter (2.76 Å) and two longer (3.78 Å) Sm(1)-In(2) bond lengths. Rh(1) is bonded in a distorted trigonal non-coplanar geometry to one Sm(1) and two equivalent In(1) atoms. Both Rh(1)-In(1) bond lengths are 1.75 Å. There are three inequivalent In sites. In the first In site, In(1) is bonded in a single-bond geometry to one Rh(1) and one In(2) atom. The In(1)-In(2) bond length is 3.13 Å. In the second In site, In(2) is bonded in a 7-coordinate geometry to two equivalent Sm(1), one In(1), one In(3), and three equivalent In(2) atoms. The In(2)-In(3) bond length is 2.76 Å. There is one shorter (2.32 Å) and two longer (3.47 Å) In(2)-In(2) bond lengths. In the third In site, In(3) is bonded in a distorted single-bond geometry to one Sm(1) and two equivalent In(2) atoms.