data_NaRuCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.38
_cell_length_b   6.38
_cell_length_c   6.38
_cell_angle_alpha   152.16
_cell_angle_beta   152.16
_cell_angle_gamma   39.77
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaRuCl
_chemical_formula_sum   'Na1 Ru1 Cl1'
_cell_volume   56.58
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na1  1  0.0  0.0  0.14  1.0
  Ru  Ru2  1  0.0  0.0  0.78  1.0
  Cl  Cl0  1  0.0  0.0  0.08  1.0

data_NaRuCl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.34
_cell_length_b   4.34
_cell_length_c   6.38
_cell_angle_alpha   90.0
_cell_angle_beta   109.89
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   NaRuCl
_chemical_formula_sum   'Na2 Ru2 Cl2'
_cell_volume   113.16
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  2  0.0  0.0  0.86  1.0
  Ru  Ru1  2  0.0  0.0  0.22  1.0
  Cl  Cl2  2  0.0  0.0  0.92  1.0

Na Ru Cl
Na Ru Cl 0 2 o o o 0 1 o o - 1 2 o o + 
NaRuCl is alpha oxygen-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two NaRuCl clusters. Na(1) is bonded in a single-bond geometry to one Cl(1) atom. The Na(1)-Cl(1) bond length is 0.37 Å. Ru(1) is bonded in a single-bond geometry to one Cl(1) atom. The Ru(1)-Cl(1) bond length is 1.94 Å. Cl(1) is bonded in a single-bond geometry to one Na(1) and one Ru(1) atom.