data_NaTiPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.92
_cell_length_b   3.14
_cell_length_c   7.11
_cell_angle_alpha   90.0
_cell_angle_beta   98.8
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaTiPd2
_chemical_formula_sum   'Na1 Ti1 Pd2'
_cell_volume   64.41
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.0  1.0
  Ti  Ti3  1  0.46  0.0  0.51  1.0
  Pd  Pd1  1  0.34  0.57  0.07  1.0
  Pd  Pd2  1  0.5  0.57  0.96  1.0

data_NaTiPd2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.92
_cell_length_b   3.14
_cell_length_c   7.11
_cell_angle_alpha   90.0
_cell_angle_beta   98.8
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaTiPd2
_chemical_formula_sum   'Na1 Ti1 Pd2'
_cell_volume   64.41
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.0  1.0
  Ti  Ti1  1  0.46  0.0  0.51  1.0
  Pd  Pd2  1  0.34  0.57  0.07  1.0
  Pd  Pd3  1  0.5  0.57  0.96  1.0

Na Ti Pd Pd
Na Ti Pd Pd 0 3 - - - 0 3 o - - 0 2 o - o 0 2 o o o 0 1 o o o 0 1 - o - 1 2 o - o 1 2 o o o 1 1 + o o 1 1 o + o 1 3 o - o 1 3 o o o 2 3 o o - 
NaTiPd2 crystallizes in the triclinic P1 space group. Na(1) is bonded in a 4-coordinate geometry to two equivalent Ti(1), two equivalent Pd(1), and two equivalent Pd(2) atoms. There is one shorter (3.58 Å) and one longer (3.69 Å) Na(1)-Ti(1) bond length. There is one shorter (1.70 Å) and one longer (2.05 Å) Na(1)-Pd(1) bond length. There is one shorter (1.98 Å) and one longer (2.30 Å) Na(1)-Pd(2) bond length. Ti(1) is bonded in a 10-coordinate geometry to two equivalent Na(1), four equivalent Ti(1), two equivalent Pd(1), and two equivalent Pd(2) atoms. There are two shorter (2.92 Å) and two longer (3.14 Å) Ti(1)-Ti(1) bond lengths. There is one shorter (3.43 Å) and one longer (3.62 Å) Ti(1)-Pd(1) bond length. There is one shorter (3.44 Å) and one longer (3.63 Å) Ti(1)-Pd(2) bond length. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 3-coordinate geometry to two equivalent Na(1), two equivalent Ti(1), and one Pd(2) atom. The Pd(1)-Pd(2) bond length is 0.94 Å. In the second Pd site, Pd(2) is bonded in a 3-coordinate geometry to two equivalent Na(1), two equivalent Ti(1), and one Pd(1) atom.