data_ZnAg13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.34
_cell_length_b   9.34
_cell_length_c   9.34
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnAg13
_chemical_formula_sum   'Zn2 Ag26'
_cell_volume   576.95
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn26  1  0.91  0.91  0.91  1.0
  Zn  Zn27  1  0.3  0.3  0.3  1.0
  Ag  Ag0  1  0.05  0.99  0.61  1.0
  Ag  Ag1  1  0.17  0.99  0.61  1.0
  Ag  Ag2  1  0.05  0.22  0.61  1.0
  Ag  Ag3  1  0.17  0.22  0.61  1.0
  Ag  Ag4  1  0.61  0.17  0.22  1.0
  Ag  Ag5  1  0.61  0.05  0.22  1.0
  Ag  Ag6  1  0.61  0.17  0.99  1.0
  Ag  Ag7  1  0.61  0.05  0.99  1.0
  Ag  Ag8  1  0.22  0.61  0.05  1.0
  Ag  Ag9  1  0.22  0.61  0.17  1.0
  Ag  Ag10  1  0.99  0.61  0.05  1.0
  Ag  Ag11  1  0.99  0.61  0.17  1.0
  Ag  Ag12  1  0.61  0.83  0.05  1.0
  Ag  Ag13  1  0.61  0.83  0.17  1.0
  Ag  Ag14  1  0.61  0.38  0.05  1.0
  Ag  Ag15  1  0.61  0.38  0.17  1.0
  Ag  Ag16  1  0.83  0.05  0.61  1.0
  Ag  Ag17  1  0.83  0.17  0.61  1.0
  Ag  Ag18  1  0.38  0.05  0.61  1.0
  Ag  Ag19  1  0.38  0.17  0.61  1.0
  Ag  Ag20  1  0.05  0.61  0.83  1.0
  Ag  Ag21  1  0.17  0.61  0.83  1.0
  Ag  Ag22  1  0.05  0.61  0.38  1.0
  Ag  Ag23  1  0.17  0.61  0.38  1.0
  Ag  Ag24  1  0.61  0.61  0.61  1.0
  Ag  Ag25  1  0.0  0.0  0.0  1.0

data_ZnAg13
_symmetry_space_group_name_H-M   R3
_cell_length_a   9.34
_cell_length_b   9.34
_cell_length_c   22.89
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   146
_chemical_formula_structural   ZnAg13
_chemical_formula_sum   'Zn6 Ag78'
_cell_volume   1730.85
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  'x+1/3, y+2/3, z+2/3'
  5  '-y+1/3, x-y+2/3, z+2/3'
  6  '-x+y+1/3, -x+2/3, z+2/3'
  7  'x+2/3, y+1/3, z+1/3'
  8  '-y+2/3, x-y+1/3, z+1/3'
  9  '-x+y+2/3, -x+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  3  0.0  0.0  0.09  1.0
  Zn  Zn1  3  0.0  0.0  0.7  1.0
  Ag  Ag2  9  0.0  0.78  0.61  1.0
  Ag  Ag3  9  0.02  0.42  0.37  1.0
  Ag  Ag4  9  0.04  0.41  0.8  1.0
  Ag  Ag5  9  0.06  0.5  0.33  1.0
  Ag  Ag6  9  0.07  0.7  0.32  1.0
  Ag  Ag7  9  0.09  0.74  0.74  1.0
  Ag  Ag8  9  0.11  0.45  0.84  1.0
  Ag  Ag9  9  0.17  0.78  0.78  1.0
  Ag  Ag10  3  0.0  0.0  0.0  1.0
  Ag  Ag11  3  0.0  0.0  0.39  1.0

Zn Zn Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag
Zn Zn Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag 0 14 o o + 0 13 o o + 0 12 o o + 0 18 o + o 0 9 o + o 0 8 o + o 0 22 + o o 0 3 + o o 0 2 + o o 0 27 + + + 1 20 o o o 1 5 o o o 1 4 o o o 1 25 o o o 1 24 o o o 1 7 o o o 1 21 o o o 1 6 o o o 1 16 o o o 1 11 o o o 1 10 o o o 1 17 o o o 2 3 o o o 3 26 o o o 4 5 o o o 4 26 - o o 6 7 o o o 7 26 o - o 8 9 o o o 8 26 o o o 10 11 o o o 10 26 o o - 12 13 o o o 13 26 o o o 14 15 o o o 15 26 o o o 16 17 o o o 16 26 o o - 18 19 o o o 19 26 o o o 20 21 o o o 20 26 o - o 22 23 o o o 23 26 o o o 24 25 o o o 24 26 - o o 
(Ag)13Ag7ZnAg6Zn is Fluorite structured and crystallizes in the trigonal R3 space group. The structure is zero-dimensional and consists of three Ag clusters, three Ag6Zn clusters, and three Ag7Zn clusters. In each Ag cluster, there are five inequivalent Ag sites. In the first Ag site, Ag(5) is bonded in a distorted single-bond geometry to one Ag(6) atom. The Ag(5)-Ag(6) bond length is 1.10 Å. In the second Ag site, Ag(6) is bonded in a distorted single-bond geometry to one Ag(5) and one Ag(9) atom. The Ag(6)-Ag(9) bond length is 3.57 Å. In the third Ag site, Ag(7) is bonded in a distorted single-bond geometry to one Ag(8) and one Ag(9) atom. The Ag(7)-Ag(8) bond length is 1.10 Å. The Ag(7)-Ag(9) bond length is 3.57 Å. In the fourth Ag site, Ag(8) is bonded in a distorted single-bond geometry to one Ag(7) atom. In the fifth Ag site, Ag(9) is bonded in a distorted octahedral geometry to three equivalent Ag(6) and three equivalent Ag(7) atoms. In each Ag6Zn cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(3) is bonded in a distorted single-bond geometry to one Ag(4) atom. The Ag(3)-Ag(4) bond length is 1.10 Å. In the second Ag site, Ag(4) is bonded in a 1-coordinate geometry to one Ag(3) and one Zn(2) atom. The Ag(4)-Zn(2) bond length is 2.34 Å. Zn(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Ag(4) atoms. In each Ag7Zn cluster, there are three inequivalent Ag sites. In the first Ag site, Ag(10) is bonded in a single-bond geometry to one Zn(1) atom. The Ag(10)-Zn(1) bond length is 2.03 Å. In the second Ag site, Ag(1) is bonded in a 2-coordinate geometry to one Ag(2) and one Zn(1) atom. The Ag(1)-Ag(2) bond length is 1.10 Å. The Ag(1)-Zn(1) bond length is 2.34 Å. In the third Ag site, Ag(2) is bonded in a 1-coordinate geometry to one Ag(1) atom. Zn(1) is bonded in a distorted tetrahedral geometry to one Ag(10) and three equivalent Ag(1) atoms.