data_YV2Tc
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.95
_cell_length_b   8.95
_cell_length_c   8.95
_cell_angle_alpha   19.62
_cell_angle_beta   19.62
_cell_angle_gamma   19.62
_symmetry_Int_Tables_number   1
_chemical_formula_structural   YV2Tc
_chemical_formula_sum   'Y1 V2 Tc1'
_cell_volume   70.67
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y3  1  0.0  0.0  0.0  1.0
  V  V1  1  0.0  0.0  0.14  1.0
  V  V2  1  0.0  0.0  0.18  1.0
  Tc  Tc0  1  0.0  0.0  0.16  1.0

data_YV2Tc
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.28
_cell_length_b   3.05
_cell_length_c   8.95
_cell_angle_alpha   90.0
_cell_angle_beta   101.35
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   YV2Tc
_chemical_formula_sum   'Y2 V4 Tc2'
_cell_volume   141.34
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  2  0.0  0.0  0.0  1.0
  V  V1  2  -0.0  0.0  0.82  1.0
  V  V2  2  -0.0  0.0  0.86  1.0
  Tc  Tc3  2  -0.0  0.0  0.84  1.0

Y V V Tc
Y V V Tc 0 3 o o o 0 1 o o o 1 3 o o o 2 3 o o o 
YV2Tc is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two YV2Tc clusters. Y(1) is bonded in a single-bond geometry to one V(1) atom. The Y(1)-V(1) bond length is 1.24 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded in a linear geometry to one Y(1) and one Tc(1) atom. The V(1)-Tc(1) bond length is 0.20 Å. In the second V site, V(2) is bonded in a single-bond geometry to one Tc(1) atom. The V(2)-Tc(1) bond length is 0.20 Å. Tc(1) is bonded in a linear geometry to one V(1) and one V(2) atom.