data_CaLa2Co
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.2
_cell_length_b   10.2
_cell_length_c   10.2
_cell_angle_alpha   22.63
_cell_angle_beta   22.63
_cell_angle_gamma   22.63
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CaLa2Co
_chemical_formula_sum   'Ca1 La2 Co1'
_cell_volume   137.76
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.0  0.0  0.0  1.0
  La  La2  1  0.0  0.0  0.33  1.0
  La  La3  1  0.0  0.0  0.47  1.0
  Co  Co1  1  0.0  0.0  0.9  1.0

data_CaLa2Co
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.93
_cell_length_b   4.0
_cell_length_c   10.2
_cell_angle_alpha   90.0
_cell_angle_beta   103.1
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   CaLa2Co
_chemical_formula_sum   'Ca2 La4 Co2'
_cell_volume   275.51
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  2  0.0  0.0  0.0  1.0
  La  La1  2  0.0  0.0  0.53  1.0
  La  La2  2  0.0  0.0  0.67  1.0
  Co  Co3  2  -0.0  0.0  0.1  1.0

Ca La La Co
Ca La La Co 0 3 o o - 1 2 o o o 
CaCo(La)2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two lanthanum molecules and two CaCo clusters. In each CaCo cluster, Ca(1) is bonded in a single-bond geometry to one Co(1) atom. The Ca(1)-Co(1) bond length is 1.04 Å. Co(1) is bonded in a single-bond geometry to one Ca(1) atom.