data_CdP4Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.13
_cell_length_b   5.13
_cell_length_c   5.13
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdP4Rh
_chemical_formula_sum   'Cd1 P4 Rh1'
_cell_volume   95.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.81  0.81  0.81  1.0
  P  P1  1  0.72  0.72  0.53  1.0
  P  P2  1  0.72  0.53  0.72  1.0
  P  P3  1  0.53  0.72  0.72  1.0
  P  P4  1  0.53  0.53  0.53  1.0
  Rh  Rh5  1  0.0  0.0  0.0  1.0

data_CdP4Rh
_symmetry_space_group_name_H-M   R3m
_cell_length_a   5.13
_cell_length_b   5.13
_cell_length_c   12.56
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   CdP4Rh
_chemical_formula_sum   'Cd3 P12 Rh3'
_cell_volume   285.71
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  3  0.0  0.0  0.19  1.0
  P  P1  9  0.13  0.06  0.34  1.0
  P  P2  3  0.0  0.0  0.47  1.0
  Rh  Rh3  3  0.0  0.0  -0.0  1.0

Cd P P P P Rh
Cd P P P P Rh 0 3 o o o 0 2 o o o 0 1 o o o 0 5 + + + 1 2 o o o 1 3 o o o 1 4 o o o 1 5 + + o 2 3 o o o 2 4 o o o 2 5 + o + 3 4 o o o 3 5 o + + 
RhCdP4 crystallizes in the trigonal R3m space group. Rh(1) is bonded in a trigonal pyramidal geometry to one Cd(1) and three equivalent P(1) atoms. The Rh(1)-Cd(1) bond length is 2.36 Å. All Rh(1)-P(1) bond lengths are 2.40 Å. Cd(1) is bonded in a 7-coordinate geometry to one Rh(1), three equivalent P(1), and three equivalent P(2) atoms. All Cd(1)-P(1) bond lengths are 2.04 Å. All Cd(1)-P(2) bond lengths are 3.03 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 5-coordinate geometry to one Rh(1), one Cd(1), one P(2), and two equivalent P(1) atoms. The P(1)-P(2) bond length is 1.69 Å. Both P(1)-P(1) bond lengths are 0.98 Å. In the second P site, P(2) is bonded in a 6-coordinate geometry to three equivalent Cd(1) and three equivalent P(1) atoms.