data_InGe2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.92
_cell_length_b   8.92
_cell_length_c   8.92
_cell_angle_alpha   20.56
_cell_angle_beta   20.56
_cell_angle_gamma   20.56
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InGe2Rh
_chemical_formula_sum   'In1 Ge2 Rh1'
_cell_volume   76.62
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In2  1  0.0  0.0  0.09  1.0
  Ge  Ge0  1  0.0  0.0  0.93  1.0
  Ge  Ge1  1  0.0  0.0  0.26  1.0
  Rh  Rh3  1  0.0  0.0  0.0  1.0

data_InGe2Rh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.51
_cell_length_b   3.18
_cell_length_c   8.92
_cell_angle_alpha   90.0
_cell_angle_beta   101.89
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   InGe2Rh
_chemical_formula_sum   'In2 Ge4 Rh2'
_cell_volume   153.25
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  0.0  0.0  0.91  1.0
  Ge  Ge1  2  -0.0  0.0  0.07  1.0
  Ge  Ge2  2  0.0  0.0  0.74  1.0
  Rh  Rh3  2  0.0  0.0  0.0  1.0

In Ge Ge Rh
In Ge Ge Rh 0 3 o o o 0 2 o o o 1 3 o o + 
RhInGe2 is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two RhInGe2 clusters. Rh(1) is bonded in a linear geometry to one In(1) and one Ge(1) atom. The Rh(1)-In(1) bond length is 0.83 Å. The Rh(1)-Ge(1) bond length is 0.64 Å. In(1) is bonded in a distorted linear geometry to one Rh(1) and one Ge(2) atom. The In(1)-Ge(2) bond length is 1.48 Å. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a single-bond geometry to one Rh(1) atom. In the second Ge site, Ge(2) is bonded in a single-bond geometry to one In(1) atom.