data_VAgHgOs
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.53
_cell_length_b   4.53
_cell_length_c   4.53
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VAgHgOs
_chemical_formula_sum   'V1 Ag1 Hg1 Os1'
_cell_volume   65.67
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.6  0.6  0.6  1.0
  Hg  Hg1  1  0.8  0.8  0.8  1.0
  Os  Os2  1  0.2  0.2  0.2  1.0

data_VAgHgOs
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.53
_cell_length_b   4.53
_cell_length_c   11.09
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   VAgHgOs
_chemical_formula_sum   'V3 Ag3 Hg3 Os3'
_cell_volume   197.02
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  3  0.0  0.0  0.0  1.0
  Ag  Ag1  3  0.0  0.0  0.4  1.0
  Hg  Hg2  3  0.0  0.0  0.2  1.0
  Os  Os3  3  0.0  0.0  0.8  1.0

V Ag Hg Os
V Ag Hg Os 0 2 - - - 0 1 - - o 0 1 - o - 0 1 o - - 0 3 o o o 0 3 o o - 0 3 - o o 0 3 o - o 1 2 o - o 1 2 - o o 1 2 o o - 1 2 o o o 1 3 o o + 1 3 o + o 1 3 + o o 2 3 o + + 2 3 + o + 2 3 + + o 
VOsAgHg crystallizes in the trigonal R3m space group. V(1) is bonded in a distorted linear geometry to one Os(1), three equivalent Ag(1), and one Hg(1) atom. The V(1)-Os(1) bond length is 2.24 Å. All V(1)-Ag(1) bond lengths are 2.71 Å. The V(1)-Hg(1) bond length is 2.18 Å. Os(1) is bonded in a distorted single-bond geometry to one V(1) and three equivalent Ag(1) atoms. All Os(1)-Ag(1) bond lengths are 2.71 Å. Ag(1) is bonded in a 7-coordinate geometry to three equivalent V(1), three equivalent Os(1), and one Hg(1) atom. The Ag(1)-Hg(1) bond length is 2.24 Å. Hg(1) is bonded in a 2-coordinate geometry to one V(1) and one Ag(1) atom.