data_Li2SbP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.09
_cell_length_b   3.09
_cell_length_c   8.13
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2SbP
_chemical_formula_sum   'Li2 Sb1 P1'
_cell_volume   77.75
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.41  1.0
  Li  Li1  1  0.55  0.55  0.01  1.0
  Sb  Sb3  1  0.55  0.55  0.61  1.0
  P  P2  1  0.0  0.0  0.16  1.0

data_Li2SbP
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.37
_cell_length_b   4.37
_cell_length_c   8.13
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Li2SbP
_chemical_formula_sum   'Li4 Sb2 P2'
_cell_volume   155.5
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.41  1.0
  Li  Li1  2  0.05  0.5  0.01  1.0
  Sb  Sb2  2  0.05  0.5  0.61  1.0
  P  P3  2  0.0  0.0  0.16  1.0

Li Li Sb P
Li Li Sb P 0 3 o o o 0 2 o o o 0 2 o - o 0 2 - o o 0 2 - - o 1 3 o o o 1 3 o + o 1 3 + o o 1 3 + + o 1 2 o o - 2 2 + o o 2 2 o + o 
Li2SbP crystallizes in the monoclinic Cm space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to four equivalent Sb(1) and one P(1) atom. There are a spread of Li(1)-Sb(1) bond distances ranging from 2.56-2.89 Å. The Li(1)-P(1) bond length is 2.03 Å. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one Sb(1) and four equivalent P(1) atoms. The Li(2)-Sb(1) bond length is 3.23 Å. There are a spread of Li(2)-P(1) bond distances ranging from 2.34-2.69 Å. Sb(1) is bonded in a 5-coordinate geometry to one Li(2) and four equivalent Li(1) atoms. P(1) is bonded in a 5-coordinate geometry to one Li(1) and four equivalent Li(2) atoms.