data_InRhCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.29
_cell_length_b   3.29
_cell_length_c   7.72
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InRhCl2
_chemical_formula_sum   'In1 Rh1 Cl2'
_cell_volume   83.59
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In2  1  0.0  0.0  0.86  1.0
  Rh  Rh3  1  0.0  0.0  0.0  1.0
  Cl  Cl0  1  0.65  0.65  0.51  1.0
  Cl  Cl1  1  0.65  0.65  0.21  1.0

data_InRhCl2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.65
_cell_length_b   4.65
_cell_length_c   7.72
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   InRhCl2
_chemical_formula_sum   'In2 Rh2 Cl4'
_cell_volume   167.17
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  0.0  0.0  0.86  1.0
  Rh  Rh1  2  0.0  0.0  0.0  1.0
  Cl  Cl2  2  0.15  0.5  0.21  1.0
  Cl  Cl3  2  0.15  0.5  0.51  1.0

In Rh Cl Cl
In Rh Cl Cl 0 1 o o + 1 3 - - o 2 3 o o o 
RhInCl2 crystallizes in the monoclinic Cm space group. Rh(1) is bonded in a 1-coordinate geometry to one In(1) and three equivalent Cl(2) atoms. The Rh(1)-In(1) bond length is 1.07 Å. There is one shorter (2.32 Å) and two longer (2.92 Å) Rh(1)-Cl(2) bond lengths. In(1) is bonded in a single-bond geometry to one Rh(1) and one Cl(1) atom. The In(1)-Cl(1) bond length is 3.16 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a bent 150 degrees geometry to one In(1) and one Cl(2) atom. The Cl(1)-Cl(2) bond length is 2.32 Å. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to three equivalent Rh(1) and one Cl(1) atom.