data_Ga24C5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.91
_cell_length_b   8.91
_cell_length_c   8.91
_cell_angle_alpha   109.47
_cell_angle_beta   109.47
_cell_angle_gamma   109.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ga24C5
_chemical_formula_sum   'Ga24 C5'
_cell_volume   543.9
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga5  1  0.03  0.95  0.97  1.0
  Ga  Ga6  1  0.97  0.95  0.03  1.0
  Ga  Ga7  1  0.97  0.33  0.97  1.0
  Ga  Ga8  1  0.17  0.19  0.17  1.0
  Ga  Ga9  1  0.33  0.97  0.97  1.0
  Ga  Ga10  1  0.19  0.17  0.17  1.0
  Ga  Ga11  1  0.95  0.97  0.03  1.0
  Ga  Ga12  1  0.95  0.03  0.97  1.0
  Ga  Ga13  1  0.03  0.97  0.95  1.0
  Ga  Ga14  1  0.97  0.03  0.95  1.0
  Ga  Ga15  1  0.17  0.17  0.19  1.0
  Ga  Ga16  1  0.97  0.97  0.33  1.0
  Ga  Ga17  1  0.44  0.39  0.56  1.0
  Ga  Ga18  1  0.56  0.39  0.44  1.0
  Ga  Ga19  1  0.7  0.75  0.7  1.0
  Ga  Ga20  1  0.44  0.89  0.44  1.0
  Ga  Ga21  1  0.75  0.7  0.7  1.0
  Ga  Ga22  1  0.89  0.44  0.44  1.0
  Ga  Ga23  1  0.39  0.56  0.44  1.0
  Ga  Ga24  1  0.39  0.44  0.56  1.0
  Ga  Ga25  1  0.44  0.56  0.39  1.0
  Ga  Ga26  1  0.56  0.44  0.39  1.0
  Ga  Ga27  1  0.44  0.44  0.89  1.0
  Ga  Ga28  1  0.7  0.7  0.75  1.0
  C  C0  1  0.48  0.52  0.52  1.0
  C  C1  1  0.52  0.52  0.48  1.0
  C  C2  1  0.52  0.48  0.52  1.0
  C  C3  1  0.63  0.63  0.63  1.0
  C  C4  1  0.0  0.0  0.0  1.0

data_Ga24C5
_symmetry_space_group_name_H-M   R3m
_cell_length_a   14.54
_cell_length_b   14.54
_cell_length_c   8.91
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   Ga24C5
_chemical_formula_sum   'Ga72 C15'
_cell_volume   1631.69
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+2/3, y+1/3, z+1/3'
  8  '-y+2/3, x-y+1/3, z+1/3'
  9  '-x+y+2/3, -x+1/3, z+1/3'
  10  '-y+2/3, -x+1/3, z+1/3'
  11  '-x+y+2/3, y+1/3, z+1/3'
  12  'x+2/3, x-y+1/3, z+1/3'
  13  'x+1/3, y+2/3, z+2/3'
  14  '-y+1/3, x-y+2/3, z+2/3'
  15  '-x+y+1/3, -x+2/3, z+2/3'
  16  '-y+1/3, -x+2/3, z+2/3'
  17  '-x+y+1/3, y+2/3, z+2/3'
  18  'x+1/3, x-y+2/3, z+2/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  18  0.05  0.02  0.98  1.0
  Ga  Ga1  18  0.09  0.02  0.46  1.0
  Ga  Ga2  9  0.01  0.01  0.18  1.0
  Ga  Ga3  9  0.04  0.02  0.72  1.0
  Ga  Ga4  9  0.18  0.37  0.26  1.0
  Ga  Ga5  9  0.21  0.42  0.76  1.0
  C  C6  9  0.01  0.02  0.51  1.0
  C  C7  3  0.0  0.0  0.0  1.0
  C  C8  3  0.0  0.0  0.63  1.0

Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga C C C C C
Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga Ga C C C C C 0 8 o o o 0 4 o o o 0 28 o + + 1 6 o o o 1 11 o o o 1 28 + + o 2 28 + o + 2 10 + o + 2 5 + o + 2 3 + o + 2 9 o o o 2 7 o o o 3 10 o o o 3 5 o o o 3 4 o - - 3 11 - - o 4 28 o + + 4 10 o + + 4 5 o + + 4 8 o o o 5 10 o o o 5 11 - - o 6 11 o o o 6 28 + + o 7 9 o o o 7 28 + o + 8 28 o + + 9 28 + o + 10 11 - - o 11 28 + + o 12 19 o o o 12 22 o o o 13 21 o o o 13 17 o o o 14 27 o o o 14 23 o o o 14 16 o o o 14 15 o o o 15 20 o o o 15 18 o o o 16 27 o o o 16 23 o o o 16 17 o o o 17 21 o o o 18 20 o o o 19 22 o o o 22 23 o o o 23 27 o o o 24 26 o o o 24 25 o o o 24 27 o o o 25 26 o o o 25 27 o o o 26 27 o o o 
Ga12C(Ga3C)4 is Cyanogen Chloride-derived structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three Ga12C clusters and six Ga3C clusters. In each Ga12C cluster, there are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a distorted L-shaped geometry to one Ga(1), one Ga(2), and one C(3) atom. The Ga(1)-Ga(1) bond length is 0.22 Å. The Ga(1)-Ga(2) bond length is 2.63 Å. The Ga(1)-C(3) bond length is 0.62 Å. In the second Ga site, Ga(2) is bonded in a 3-coordinate geometry to one Ga(3) and two equivalent Ga(1) atoms. The Ga(2)-Ga(3) bond length is 3.03 Å. In the third Ga site, Ga(3) is bonded in a 2-coordinate geometry to one Ga(2) and two equivalent Ga(3) atoms. Both Ga(3)-Ga(3) bond lengths are 0.22 Å. C(3) is bonded in a 6-coordinate geometry to six equivalent Ga(1) atoms. In three of the Ga3C clusters, there are two inequivalent Ga sites. In the first Ga site, Ga(4) is bonded in a distorted single-bond geometry to one Ga(4), one Ga(6), and one C(1) atom. The Ga(4)-Ga(4) bond length is 0.78 Å. The Ga(4)-Ga(6) bond length is 2.89 Å. The Ga(4)-C(1) bond length is 1.10 Å. In the second Ga site, Ga(6) is bonded in a 2-coordinate geometry to two equivalent Ga(4) atoms. C(1) is bonded in a 4-coordinate geometry to two equivalent Ga(4) and two equivalent C(1) atoms. Both C(1)-C(1) bond lengths are 0.49 Å. In three of the Ga3C clusters, Ga(5) is bonded in a distorted single-bond geometry to one C(2) atom. The Ga(5)-C(2) bond length is 0.92 Å. C(2) is bonded in a 3-coordinate geometry to three equivalent Ga(5) atoms.