data_K2MoIr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.62
_cell_length_b   5.62
_cell_length_c   5.64
_cell_angle_alpha   99.2
_cell_angle_beta   99.2
_cell_angle_gamma   34.9
_symmetry_Int_Tables_number   1
_chemical_formula_structural   K2MoIr
_chemical_formula_sum   'K2 Mo1 Ir1'
_cell_volume   100.37
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K1  1  0.81  0.0  0.41  1.0
  K  K2  1  0.96  0.0  0.16  1.0
  Mo  Mo3  1  0.0  0.0  0.0  1.0
  Ir  Ir0  1  0.89  0.0  0.78  1.0

data_K2MoIr
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.37
_cell_length_b   5.62
_cell_length_c   5.64
_cell_angle_alpha   99.2
_cell_angle_beta   90.0
_cell_angle_gamma   107.45
_symmetry_Int_Tables_number   1
_chemical_formula_structural   K2MoIr
_chemical_formula_sum   'K2 Mo1 Ir1'
_cell_volume   100.37
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.04  0.84  1.0
  K  K1  1  0.0  0.19  0.59  1.0
  Mo  Mo2  1  0.0  0.0  0.0  1.0
  Ir  Ir3  1  0.0  0.11  0.22  1.0

K K Mo Ir
K K Mo Ir 0 1 o o o 0 3 o o o 1 2 + o o 2 3 - o - 
K2MoIr crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one K2MoIr cluster. There are two inequivalent K sites. In the first K site, K(1) is bonded in a distorted single-bond geometry to one Ir(1) atom. The K(1)-Ir(1) bond length is 2.09 Å. In the second K site, K(2) is bonded in a single-bond geometry to one Mo(1) atom. The K(2)-Mo(1) bond length is 0.93 Å. Mo(1) is bonded in a distorted single-bond geometry to one K(2) and one Ir(1) atom. The Mo(1)-Ir(1) bond length is 1.30 Å. Ir(1) is bonded in a distorted linear geometry to one K(1) and one Mo(1) atom.