data_CdOs2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.92
_cell_length_b   2.92
_cell_length_c   8.16
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdOs2Cl
_chemical_formula_sum   'Cd1 Os2 Cl1'
_cell_volume   69.41
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.46  0.46  0.84  1.0
  Os  Os2  1  0.46  0.46  0.18  1.0
  Os  Os3  1  0.0  0.0  0.77  1.0
  Cl  Cl1  1  0.0  0.0  0.45  1.0

data_CdOs2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.13
_cell_length_b   4.13
_cell_length_c   8.16
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   CdOs2Cl
_chemical_formula_sum   'Cd2 Os4 Cl2'
_cell_volume   138.82
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  2  0.46  0.0  0.84  1.0
  Os  Os1  2  0.0  0.0  0.77  1.0
  Os  Os2  2  0.46  0.0  0.18  1.0
  Cl  Cl3  2  0.0  0.0  0.45  1.0

Cd Os Os Cl
Cd Os Os Cl 0 2 o o o 0 2 o + o 0 2 + o o 0 2 + + o 0 1 o o + 1 3 o o o 1 3 o + o 1 3 + o o 1 3 + + o 1 1 + o o 1 1 o + o 2 3 o o o 3 3 + o o 3 3 o + o 
Os2CdCl crystallizes in the monoclinic Cm space group. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 9-coordinate geometry to four equivalent Os(1), one Cd(1), and four equivalent Cl(1) atoms. All Os(1)-Os(1) bond lengths are 2.92 Å. The Os(1)-Cd(1) bond length is 2.83 Å. There are a spread of Os(1)-Cl(1) bond distances ranging from 2.85-3.09 Å. In the second Os site, Os(2) is bonded to four equivalent Cd(1) and one Cl(1) atom to form a mixture of distorted corner and edge-sharing OsCd4Cl trigonal bipyramids. There are a spread of Os(2)-Cd(1) bond distances ranging from 1.97-2.30 Å. The Os(2)-Cl(1) bond length is 2.65 Å. Cd(1) is bonded in a 5-coordinate geometry to one Os(1) and four equivalent Os(2) atoms. Cl(1) is bonded in a 5-coordinate geometry to one Os(2) and four equivalent Os(1) atoms.