data_In5Re4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.61
_cell_length_b   6.61
_cell_length_c   6.61
_cell_angle_alpha   96.3
_cell_angle_beta   96.3
_cell_angle_gamma   141.3
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In5Re4
_chemical_formula_sum   'In5 Re4'
_cell_volume   170.51
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.47  0.53  0.19  1.0
  In  In2  1  0.53  0.47  0.19  1.0
  In  In3  1  0.88  0.88  0.0  1.0
  In  In4  1  0.53  0.53  0.19  1.0
  Re  Re5  1  0.0  0.64  0.0  1.0
  Re  Re6  1  0.0  0.19  0.0  1.0
  Re  Re7  1  0.19  0.0  0.0  1.0
  Re  Re8  1  0.64  0.0  0.0  1.0

data_In5Re4
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.38
_cell_length_b   12.48
_cell_length_c   6.61
_cell_angle_alpha   90.0
_cell_angle_beta   109.35
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   In5Re4
_chemical_formula_sum   'In10 Re8'
_cell_volume   341.03
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  4  0.0  0.47  0.81  1.0
  In  In1  2  0.0  0.0  0.0  1.0
  In  In2  2  0.12  0.0  0.0  1.0
  In  In3  2  0.47  0.0  0.81  1.0
  Re  Re4  4  0.18  0.18  0.0  1.0
  Re  Re5  4  0.41  0.41  0.0  1.0

In In In In In Re Re Re Re
In In In In In Re Re Re Re 0 3 - - o 0 6 o o o 0 7 o o o 1 4 o o o 2 4 o o o 3 6 + + o 3 7 + + o 5 7 o + o 6 8 - o o 
(Re2In)2(In)3 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two In clusters and two Re2In clusters. In each In cluster, there are two inequivalent In sites. In the first In site, In(2) is bonded in a distorted single-bond geometry to one In(4) atom. The In(2)-In(4) bond length is 0.41 Å. In the second In site, In(4) is bonded in a bent 150 degrees geometry to two equivalent In(2) atoms. In each Re2In cluster, there are two inequivalent Re sites. In the first Re site, Re(2) is bonded in a 1-coordinate geometry to one Re(1) and one In(1) atom. The Re(2)-Re(1) bond length is 1.64 Å. The Re(2)-In(1) bond length is 1.24 Å. In the second Re site, Re(1) is bonded in a distorted single-bond geometry to one Re(2) atom. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 3-coordinate geometry to two equivalent Re(2) and one In(3) atom. The In(1)-In(3) bond length is 0.52 Å. In the second In site, In(3) is bonded in a single-bond geometry to one In(1) atom.