data_In2AgPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.22
_cell_length_b   9.22
_cell_length_c   9.22
_cell_angle_alpha   20.03
_cell_angle_beta   20.03
_cell_angle_gamma   20.03
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In2AgPd
_chemical_formula_sum   'In2 Ag1 Pd1'
_cell_volume   80.56
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In1  1  0.0  0.0  0.9  1.0
  In  In2  1  0.0  0.0  0.21  1.0
  Ag  Ag0  1  0.0  0.0  0.55  1.0
  Pd  Pd3  1  0.0  0.0  0.0  1.0

data_In2AgPd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.56
_cell_length_b   3.21
_cell_length_c   9.22
_cell_angle_alpha   90.0
_cell_angle_beta   101.59
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   In2AgPd
_chemical_formula_sum   'In4 Ag2 Pd2'
_cell_volume   161.11
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  -0.0  0.0  0.79  1.0
  In  In1  2  -0.0  0.0  0.1  1.0
  Ag  Ag2  2  -0.0  0.0  0.45  1.0
  Pd  Pd3  2  -0.0  0.0  0.0  1.0

In In Ag Pd
In In Ag Pd 0 3 o o + 0 2 o o o 1 3 o o o 1 2 o o o 2 2 o + - 2 2 + - o 2 2 + o - 
PdAgIn2 crystallizes in the monoclinic Cm space group. Pd(1) is bonded in a distorted linear geometry to one In(1) and one In(2) atom. The Pd(1)-In(1) bond length is 0.90 Å. The Pd(1)-In(2) bond length is 1.90 Å. Ag(1) is bonded to six equivalent Ag(1), one In(1), and one In(2) atom to form a mixture of distorted corner and edge-sharing AgIn2Ag6 hexagonal bipyramids. All Ag(1)-Ag(1) bond lengths are 3.21 Å. The Ag(1)-In(1) bond length is 3.21 Å. The Ag(1)-In(2) bond length is 3.21 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a single-bond geometry to one Pd(1) and one Ag(1) atom. In the second In site, In(2) is bonded in a single-bond geometry to one Pd(1) and one Ag(1) atom.