data_LiCd2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.34
_cell_length_b   9.34
_cell_length_c   9.34
_cell_angle_alpha   18.82
_cell_angle_beta   18.82
_cell_angle_gamma   18.82
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiCd2Pd
_chemical_formula_sum   'Li1 Cd2 Pd1'
_cell_volume   74.01
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li2  1  0.0  0.0  0.0  1.0
  Cd  Cd0  1  0.0  0.0  0.68  1.0
  Cd  Cd1  1  0.0  0.0  0.83  1.0
  Pd  Pd3  1  0.0  0.0  0.76  1.0

data_LiCd2Pd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.29
_cell_length_b   3.05
_cell_length_c   9.34
_cell_angle_alpha   90.0
_cell_angle_beta   100.88
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LiCd2Pd
_chemical_formula_sum   'Li2 Cd4 Pd2'
_cell_volume   148.03
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.0  1.0
  Cd  Cd1  2  0.0  0.0  0.17  1.0
  Cd  Cd2  2  0.0  0.0  0.32  1.0
  Pd  Pd3  2  0.0  0.0  0.24  1.0

Li Cd Cd Pd
Li Cd Cd Pd 0 2 o o - 1 3 o o o 2 3 o o o 
LiPdCd2 is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two LiPdCd2 clusters. Li(1) is bonded in a single-bond geometry to one Cd(2) atom. The Li(1)-Cd(2) bond length is 1.60 Å. Pd(1) is bonded in a linear geometry to one Cd(1) and one Cd(2) atom. The Pd(1)-Cd(1) bond length is 0.69 Å. The Pd(1)-Cd(2) bond length is 0.69 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a single-bond geometry to one Pd(1) atom. In the second Cd site, Cd(2) is bonded in a linear geometry to one Li(1) and one Pd(1) atom.