data_KLa2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.46
_cell_length_b   11.46
_cell_length_c   11.46
_cell_angle_alpha   20.84
_cell_angle_beta   20.84
_cell_angle_gamma   20.84
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KLa2P
_chemical_formula_sum   'K1 La2 P1'
_cell_volume   166.77
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.0  0.81  1.0
  La  La1  1  0.0  0.0  0.6  1.0
  La  La2  1  0.0  0.0  0.02  1.0
  P  P3  1  0.0  0.0  0.0  1.0

data_KLa2P
_symmetry_space_group_name_H-M   Cm
_cell_length_a   7.18
_cell_length_b   4.15
_cell_length_c   11.46
_cell_angle_alpha   90.0
_cell_angle_beta   102.05
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   KLa2P
_chemical_formula_sum   'K2 La4 P2'
_cell_volume   333.53
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  2  -0.0  0.0  0.19  1.0
  La  La1  2  -0.0  0.0  0.98  1.0
  La  La2  2  -0.0  0.0  0.4  1.0
  P  P3  2  0.0  0.0  0.0  1.0

K La La P
K La La P 0 1 o o o 0 3 o o + 0 2 o o + 2 3 o o o 
KLa2P crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two KLa2P clusters. K(1) is bonded in a distorted linear geometry to one La(1) and one P(1) atom. The K(1)-La(1) bond length is 2.42 Å. The K(1)-P(1) bond length is 2.17 Å. There are two inequivalent La sites. In the first La site, La(1) is bonded in a single-bond geometry to one K(1) atom. In the second La site, La(2) is bonded in a single-bond geometry to one P(1) atom. The La(2)-P(1) bond length is 0.25 Å. P(1) is bonded in a distorted single-bond geometry to one K(1) and one La(2) atom.