data_ScGa5Co
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.16
_cell_length_b   4.16
_cell_length_c   6.62
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScGa5Co
_chemical_formula_sum   'Sc1 Ga5 Co1'
_cell_volume   114.41
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.0  0.0  0.0  1.0
  Ga  Ga1  1  0.0  0.08  0.0  1.0
  Ga  Ga2  1  0.0  0.08  0.62  1.0
  Ga  Ga3  1  0.08  0.0  0.0  1.0
  Ga  Ga4  1  0.08  0.0  0.62  1.0
  Ga  Ga5  1  0.08  0.08  0.0  1.0
  Co  Co6  1  0.0  0.0  0.31  1.0

data_ScGa5Co
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.88
_cell_length_b   5.88
_cell_length_c   6.62
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ScGa5Co
_chemical_formula_sum   'Sc2 Ga10 Co2'
_cell_volume   228.83
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  2  0.0  0.0  0.0  1.0
  Ga  Ga1  4  0.04  0.04  0.0  1.0
  Ga  Ga2  4  0.04  0.04  0.62  1.0
  Ga  Ga3  2  0.08  0.0  0.0  1.0
  Co  Co4  2  0.0  0.0  0.31  1.0

Sc Ga Ga Ga Ga Ga Co
Sc Ga Ga Ga Ga Ga Co 0 3 o o o 0 1 o o o 0 6 o o o 1 5 o o o 1 6 o o o 2 4 o o o 2 6 o o o 3 5 o o o 3 6 o o o 4 6 o o o 5 6 o o o 
ScCoGa5 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ScCoGa5 clusters. Sc(1) is bonded in an L-shaped geometry to one Co(1) and two equivalent Ga(1) atoms. The Sc(1)-Co(1) bond length is 2.07 Å. Both Sc(1)-Ga(1) bond lengths are 0.33 Å. Co(1) is bonded in a 5-coordinate geometry to one Sc(1), two equivalent Ga(1), and two equivalent Ga(2) atoms. Both Co(1)-Ga(1) bond lengths are 2.06 Å. Both Co(1)-Ga(2) bond lengths are 2.06 Å. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a distorted L-shaped geometry to one Sc(1), one Co(1), and one Ga(3) atom. The Ga(1)-Ga(3) bond length is 0.33 Å. In the second Ga site, Ga(2) is bonded in a single-bond geometry to one Co(1) and one Ga(2) atom. The Ga(2)-Ga(2) bond length is 0.46 Å. In the third Ga site, Ga(3) is bonded in an L-shaped geometry to two equivalent Ga(1) atoms.