data_VAgRu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.76
_cell_length_b   3.89
_cell_length_c   5.54
_cell_angle_alpha   90.0
_cell_angle_beta   92.63
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VAgRu2
_chemical_formula_sum   'V1 Ag1 Ru2'
_cell_volume   59.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.56  0.0  0.6  1.0
  Ag  Ag0  1  0.17  0.95  0.15  1.0
  Ru  Ru1  1  1.0  0.0  0.19  1.0
  Ru  Ru2  1  0.41  0.95  0.37  1.0

data_VAgRu2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.76
_cell_length_b   3.89
_cell_length_c   5.54
_cell_angle_alpha   90.0
_cell_angle_beta   92.63
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VAgRu2
_chemical_formula_sum   'V1 Ag1 Ru2'
_cell_volume   59.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.56  0.0  0.6  1.0
  Ag  Ag1  1  0.17  0.95  0.15  1.0
  Ru  Ru2  1  0.41  0.95  0.37  1.0
  Ru  Ru3  1  1.0  0.0  0.19  1.0

V Ag Ru Ru
V Ag Ru Ru 0 3 o - o 1 2 - + o 1 3 o o o 2 3 + - o 
VRu2Ag crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VRu2Ag cluster. V(1) is bonded in a single-bond geometry to one Ru(2) atom. The V(1)-Ru(2) bond length is 1.35 Å. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a single-bond geometry to one Ag(1) atom. The Ru(1)-Ag(1) bond length is 0.59 Å. In the second Ru site, Ru(2) is bonded in a 2-coordinate geometry to one V(1) and one Ag(1) atom. The Ru(2)-Ag(1) bond length is 1.38 Å. Ag(1) is bonded in a distorted single-bond geometry to one Ru(1) and one Ru(2) atom.