data_LaV2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.43
_cell_length_b   9.43
_cell_length_c   9.43
_cell_angle_alpha   18.7
_cell_angle_beta   18.7
_cell_angle_gamma   18.7
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaV2W
_chemical_formula_sum   'La1 V2 W1'
_cell_volume   75.25
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.0  0.0  1.0
  V  V1  1  0.0  0.0  0.27  1.0
  V  V2  1  0.0  0.0  0.51  1.0
  W  W3  1  0.0  0.0  0.89  1.0

data_LaV2W
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.31
_cell_length_b   3.06
_cell_length_c   9.43
_cell_angle_alpha   90.0
_cell_angle_beta   100.81
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LaV2W
_chemical_formula_sum   'La2 V4 W2'
_cell_volume   150.5
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  2  0.0  0.0  0.0  1.0
  V  V1  2  0.0  0.0  0.49  1.0
  V  V2  2  0.0  0.0  0.73  1.0
  W  W3  2  0.0  0.0  0.11  1.0

La V V W
La V V W 0 3 o o - 0 1 o o o 1 2 o o o 2 2 o + - 2 2 + - o 2 2 + o - 
LaV2W crystallizes in the monoclinic Cm space group. La(1) is bonded in a single-bond geometry to one V(1) and one W(1) atom. The La(1)-V(1) bond length is 2.51 Å. The La(1)-W(1) bond length is 1.05 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 2-coordinate geometry to one La(1) and one V(2) atom. The V(1)-V(2) bond length is 2.30 Å. In the second V site, V(2) is bonded in a 8-coordinate geometry to one V(1), six equivalent V(2), and one W(1) atom. All V(2)-V(2) bond lengths are 3.06 Å. The V(2)-W(1) bond length is 3.56 Å. W(1) is bonded in a single-bond geometry to one La(1) and one V(2) atom.