data_Na2TeP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.84
_cell_length_b   5.84
_cell_length_c   5.84
_cell_angle_alpha   136.03
_cell_angle_beta   136.03
_cell_angle_gamma   63.94
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na2TeP
_chemical_formula_sum   'Na2 Te1 P1'
_cell_volume   94.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.0  1.0
  Na  Na1  1  0.19  0.0  0.48  1.0
  Te  Te3  1  0.0  0.19  0.48  1.0
  P  P2  1  0.0  0.0  0.95  1.0

data_Na2TeP
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.37
_cell_length_b   4.37
_cell_length_c   5.84
_cell_angle_alpha   111.99
_cell_angle_beta   111.99
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na2TeP
_chemical_formula_sum   'Na2 Te1 P1'
_cell_volume   94.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.0  1.0
  Na  Na1  1  0.52  0.0  0.71  1.0
  Te  Te2  1  0.71  0.19  0.71  1.0
  P  P3  1  0.05  0.0  0.05  1.0

Na Na Te P
Na Na Te P 0 3 o o - 1 2 o o o 
NaPNaTe is BCT5 structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one lambda1-tellanylsodium molecule and one NaP cluster. In the NaP cluster, Na(1) is bonded in a single-bond geometry to one P(1) atom. The Na(1)-P(1) bond length is 0.28 Å. P(1) is bonded in a single-bond geometry to one Na(1) atom.