data_CoRe2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.95
_cell_length_b   4.95
_cell_length_c   4.95
_cell_angle_alpha   141.7
_cell_angle_beta   128.95
_cell_angle_gamma   65.59
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CoRe2W
_chemical_formula_sum   'Co1 Re2 W1'
_cell_volume   57.83
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.0  0.0  1.0
  Re  Re1  1  0.0  0.14  0.07  1.0
  Re  Re2  1  0.63  0.0  0.09  1.0
  W  W3  1  0.0  0.0  0.17  1.0

data_CoRe2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.25
_cell_length_b   4.27
_cell_length_c   4.95
_cell_angle_alpha   115.53
_cell_angle_beta   109.15
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CoRe2W
_chemical_formula_sum   'Co1 Re2 W1'
_cell_volume   57.83
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.0  0.0  1.0
  Re  Re1  1  0.54  0.91  0.54  1.0
  Re  Re2  1  0.93  0.06  0.06  1.0
  W  W3  1  0.83  0.83  0.83  1.0

Co Re Re W
Co Re Re W 0 1 o o o 0 3 o o o 2 3 + o o 
WRe2Co crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one WRe2Co cluster. W(1) is bonded in a 1-coordinate geometry to one Re(2) and one Co(1) atom. The W(1)-Re(2) bond length is 1.65 Å. The W(1)-Co(1) bond length is 0.82 Å. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a single-bond geometry to one Co(1) atom. The Re(1)-Co(1) bond length is 0.44 Å. In the second Re site, Re(2) is bonded in a single-bond geometry to one W(1) atom. Co(1) is bonded in a water-like geometry to one W(1) and one Re(1) atom.