data_TlZnPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.47
_cell_length_b   4.47
_cell_length_c   3.32
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlZnPd
_chemical_formula_sum   'Tl1 Zn1 Pd1'
_cell_volume   57.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl1  1  0.24  0.29  0.12  1.0
  Zn  Zn2  1  0.0  0.0  0.6  1.0
  Pd  Pd0  1  1.0  0.58  0.93  1.0

data_TlZnPd
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.32
_cell_length_b   4.47
_cell_length_c   4.47
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlZnPd
_chemical_formula_sum   'Tl1 Zn1 Pd1'
_cell_volume   57.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.12  0.24  0.29  1.0
  Zn  Zn1  1  0.6  0.0  0.0  1.0
  Pd  Pd2  1  0.93  1.0  0.58  1.0

Tl Zn Pd
Tl Zn Pd 0 1 o o - 0 1 o o o 0 2 - o - 1 2 - - o 
PdZnTl crystallizes in the triclinic P1 space group. Pd(1) is bonded in a distorted bent 150 degrees geometry to three equivalent Zn(1) and two equivalent Tl(1) atoms. There are a spread of Pd(1)-Zn(1) bond distances ranging from 2.17-2.90 Å. There is one shorter (2.14 Å) and one longer (3.05 Å) Pd(1)-Tl(1) bond length. Zn(1) is bonded in a 5-coordinate geometry to three equivalent Pd(1) and two equivalent Tl(1) atoms. There is one shorter (1.98 Å) and one longer (2.12 Å) Zn(1)-Tl(1) bond length. Tl(1) is bonded in a 4-coordinate geometry to two equivalent Pd(1) and two equivalent Zn(1) atoms.