data_YCoTc
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.78
_cell_length_b   5.78
_cell_length_c   5.78
_cell_angle_alpha   148.27
_cell_angle_beta   148.27
_cell_angle_gamma   45.49
_symmetry_Int_Tables_number   1
_chemical_formula_structural   YCoTc
_chemical_formula_sum   'Y1 Co1 Tc1'
_cell_volume   53.2
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y2  1  0.0  0.0  0.09  1.0
  Co  Co0  1  0.0  0.0  0.29  1.0
  Tc  Tc1  1  0.0  0.0  0.94  1.0

data_YCoTc
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.47
_cell_length_b   4.47
_cell_length_c   5.78
_cell_angle_alpha   90.0
_cell_angle_beta   112.74
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   YCoTc
_chemical_formula_sum   'Y2 Co2 Tc2'
_cell_volume   106.4
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  2  0.09  0.0  0.09  1.0
  Co  Co1  2  0.29  0.0  0.29  1.0
  Tc  Tc2  2  0.44  0.5  0.94  1.0

Y Co Tc
Y Co Tc 0 2 o o - 0 1 o o o 
YTcCo is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two YTcCo clusters. Y(1) is bonded in a linear geometry to one Tc(1) and one Co(1) atom. The Y(1)-Tc(1) bond length is 0.86 Å. The Y(1)-Co(1) bond length is 1.21 Å. Tc(1) is bonded in a single-bond geometry to one Y(1) atom. Co(1) is bonded in a single-bond geometry to one Y(1) atom.