data_PRhPb2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.32
_cell_length_b   3.32
_cell_length_c   7.7
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   92.4
_symmetry_Int_Tables_number   1
_chemical_formula_structural   PRhPb2
_chemical_formula_sum   'P1 Rh1 Pb2'
_cell_volume   84.65
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.0  0.0  0.0  1.0
  Rh  Rh3  1  0.0  0.0  0.85  1.0
  Pb  Pb1  1  0.3  0.0  0.04  1.0
  Pb  Pb2  1  0.3  0.0  0.65  1.0

data_PRhPb2
_symmetry_space_group_name_H-M   Pm
_cell_length_a   3.32
_cell_length_b   3.32
_cell_length_c   7.7
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   PRhPb2
_chemical_formula_sum   'P1 Rh1 Pb2'
_cell_volume   84.72
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.0  0.0  0.0  1.0
  Rh  Rh1  1  0.0  0.0  0.85  1.0
  Pb  Pb2  1  0.3  0.0  0.04  1.0
  Pb  Pb3  1  0.3  0.0  0.65  1.0

P Rh Pb Pb
P Rh Pb Pb 0 1 o o - 0 2 o o o 1 3 o o o 
RhPb2P is Indium-like structured and crystallizes in the monoclinic Pm space group. The structure is zero-dimensional and consists of one RhPb2P cluster. Rh(1) is bonded in a 2-coordinate geometry to one Pb(2) and one P(1) atom. The Rh(1)-Pb(2) bond length is 1.80 Å. The Rh(1)-P(1) bond length is 1.17 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a distorted single-bond geometry to one P(1) atom. The Pb(1)-P(1) bond length is 1.04 Å. In the second Pb site, Pb(2) is bonded in a distorted single-bond geometry to one Rh(1) atom. P(1) is bonded in a distorted water-like geometry to one Rh(1) and one Pb(1) atom.