data_KLaGa2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.83
_cell_length_b   4.94
_cell_length_c   6.13
_cell_angle_alpha   90.0
_cell_angle_beta   94.27
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KLaGa2
_chemical_formula_sum   'K1 La1 Ga2'
_cell_volume   115.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K2  1  0.42  0.0  0.65  1.0
  La  La3  1  0.88  0.47  0.18  1.0
  Ga  Ga0  1  0.84  0.0  0.93  1.0
  Ga  Ga1  1  0.29  0.47  0.53  1.0

data_KLaGa2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.83
_cell_length_b   4.94
_cell_length_c   6.13
_cell_angle_alpha   90.0
_cell_angle_beta   94.27
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KLaGa2
_chemical_formula_sum   'K1 La1 Ga2'
_cell_volume   115.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.42  0.0  0.65  1.0
  La  La1  1  0.88  0.47  0.18  1.0
  Ga  Ga2  1  0.29  0.47  0.53  1.0
  Ga  Ga3  1  0.84  0.0  0.93  1.0

K La Ga Ga
K La Ga Ga 0 3 o - o 0 3 o o o 0 2 o o o 1 2 o o - 1 2 o + - 1 3 o o o 1 3 + o o 
KLaGa2 crystallizes in the triclinic P1 space group. K(1) is bonded to two equivalent Ga(1) and two equivalent Ga(2) atoms to form corner-sharing KGa4 trigonal pyramids. There is one shorter (2.26 Å) and one longer (2.88 Å) K(1)-Ga(1) bond length. There is one shorter (2.46 Å) and one longer (2.75 Å) K(1)-Ga(2) bond length. La(1) is bonded in a 4-coordinate geometry to two equivalent Ga(1) and two equivalent Ga(2) atoms. There is one shorter (2.77 Å) and one longer (3.03 Å) La(1)-Ga(1) bond length. There is one shorter (2.61 Å) and one longer (3.25 Å) La(1)-Ga(2) bond length. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to two equivalent K(1) and two equivalent La(1) atoms to form distorted corner-sharing GaK2La2 tetrahedra. In the second Ga site, Ga(2) is bonded to two equivalent K(1) and two equivalent La(1) atoms to form distorted corner-sharing GaK2La2 trigonal pyramids.