data_Sb2OsRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.67
_cell_length_b   4.67
_cell_length_c   3.3
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   94.61
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sb2OsRh
_chemical_formula_sum   'Sb2 Os1 Rh1'
_cell_volume   71.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb2  1  0.58  0.72  0.65  1.0
  Sb  Sb3  1  0.58  0.28  0.65  1.0
  Os  Os0  1  0.17  0.0  0.0  1.0
  Rh  Rh1  1  0.0  0.0  0.0  1.0

data_Sb2OsRh
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.3
_cell_length_b   4.67
_cell_length_c   4.67
_cell_angle_alpha   94.61
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sb2OsRh
_chemical_formula_sum   'Sb2 Os1 Rh1'
_cell_volume   71.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.65  0.58  0.28  1.0
  Sb  Sb1  1  0.65  0.58  0.72  1.0
  Os  Os2  1  0.0  0.17  0.0  1.0
  Rh  Rh3  1  0.0  0.0  0.0  1.0

Sb Sb Os Rh
Sb Sb Os Rh 0 1 o o o 2 3 o o o 
OsRhSb2 crystallizes in the triclinic P1 space group. Os(1) is bonded in a distorted single-bond geometry to one Rh(1), one Sb(2), and two equivalent Sb(1) atoms. The Os(1)-Rh(1) bond length is 0.78 Å. The Os(1)-Sb(2) bond length is 2.54 Å. There is one shorter (2.70 Å) and one longer (3.24 Å) Os(1)-Sb(1) bond length. Rh(1) is bonded in a distorted single-bond geometry to one Os(1), one Sb(2), and two equivalent Sb(1) atoms. The Rh(1)-Sb(2) bond length is 2.70 Å. There is one shorter (2.54 Å) and one longer (3.11 Å) Rh(1)-Sb(1) bond length. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to two equivalent Os(1), two equivalent Rh(1), two equivalent Sb(1), and two equivalent Sb(2) atoms. Both Sb(1)-Sb(1) bond lengths are 3.30 Å. There is one shorter (2.02 Å) and one longer (2.65 Å) Sb(1)-Sb(2) bond length. In the second Sb site, Sb(2) is bonded in a 3-coordinate geometry to one Os(1), one Rh(1), and two equivalent Sb(1) atoms.