data_KPdW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.44
_cell_length_b   5.44
_cell_length_c   3.03
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   112.82
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KPdW2
_chemical_formula_sum   'K1 Pd1 W2'
_cell_volume   82.59
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.0  0.0  1.0
  Pd  Pd1  1  0.01  0.0  0.0  1.0
  W  W2  1  0.5  0.74  0.52  1.0
  W  W3  1  0.5  0.26  0.52  1.0

data_KPdW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.03
_cell_length_b   5.44
_cell_length_c   5.44
_cell_angle_alpha   112.82
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KPdW2
_chemical_formula_sum   'K1 Pd1 W2'
_cell_volume   82.59
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.0  0.0  1.0
  Pd  Pd1  1  0.0  0.01  0.0  1.0
  W  W2  1  0.52  0.5  0.26  1.0
  W  W3  1  0.52  0.5  0.74  1.0

K Pd W W
K Pd W W 0 1 o o o 0 2 - - o 0 2 - - - 0 3 o o o 0 3 o o - 1 2 - - o 1 2 - - - 1 3 o o o 1 3 o o - 2 3 o + o 2 3 o o o 2 2 o o + 3 3 o o + 
KW2Pd crystallizes in the triclinic P1 space group. K(1) is bonded in a single-bond geometry to two equivalent W(1), two equivalent W(2), and one Pd(1) atom. There is one shorter (2.91 Å) and one longer (2.96 Å) K(1)-W(1) bond length. There is one shorter (3.81 Å) and one longer (3.85 Å) K(1)-W(2) bond length. The K(1)-Pd(1) bond length is 0.05 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 2-coordinate geometry to two equivalent K(1) and two equivalent W(2) atoms. There is one shorter (2.56 Å) and one longer (2.88 Å) W(1)-W(2) bond length. In the second W site, W(2) is bonded in a 8-coordinate geometry to two equivalent K(1), two equivalent W(1), two equivalent W(2), and two equivalent Pd(1) atoms. Both W(2)-W(2) bond lengths are 3.03 Å. There is one shorter (2.91 Å) and one longer (2.96 Å) W(2)-Pd(1) bond length. Pd(1) is bonded in a single-bond geometry to one K(1) and two equivalent W(2) atoms.