data_VCd2Mo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.76
_cell_length_b   2.76
_cell_length_c   9.08
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCd2Mo
_chemical_formula_sum   'V1 Cd2 Mo1'
_cell_volume   69.01
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Cd  Cd0  1  0.38  0.38  0.21  1.0
  Cd  Cd1  1  0.38  0.38  0.86  1.0
  Mo  Mo2  1  0.0  0.0  0.54  1.0

data_VCd2Mo
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.9
_cell_length_b   3.9
_cell_length_c   9.08
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VCd2Mo
_chemical_formula_sum   'V2 Cd4 Mo2'
_cell_volume   138.01
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.0  1.0
  Cd  Cd1  2  0.38  0.0  0.21  1.0
  Cd  Cd2  2  0.38  0.0  0.86  1.0
  Mo  Mo3  2  0.0  0.0  0.54  1.0

V Cd Cd Mo
V Cd Cd Mo 0 2 - o - 0 2 o - - 0 2 o o - 0 1 o o o 0 1 o - o 0 1 - o o 0 1 - - o 1 1 + o o 1 1 o + o 1 2 o o - 1 3 o o o 2 3 o o o 3 3 + o o 3 3 o + o 
VMoCd2 crystallizes in the monoclinic Cm space group. V(1) is bonded in a 1-coordinate geometry to one Cd(2) and four equivalent Cd(1) atoms. The V(1)-Cd(2) bond length is 1.92 Å. There are a spread of V(1)-Cd(1) bond distances ranging from 2.44-3.11 Å. Mo(1) is bonded in a 10-coordinate geometry to four equivalent Mo(1), three equivalent Cd(1), and three equivalent Cd(2) atoms. All Mo(1)-Mo(1) bond lengths are 2.76 Å. There is one shorter (3.30 Å) and two longer (3.57 Å) Mo(1)-Cd(1) bond lengths. There is one shorter (3.30 Å) and two longer (3.57 Å) Mo(1)-Cd(2) bond lengths. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 11-coordinate geometry to four equivalent V(1), three equivalent Mo(1), and four equivalent Cd(1) atoms. All Cd(1)-Cd(1) bond lengths are 2.76 Å. In the second Cd site, Cd(2) is bonded in a 1-coordinate geometry to one V(1) and three equivalent Mo(1) atoms.