data_VCd2In
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.32
_cell_length_b   5.32
_cell_length_c   3.14
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   112.94
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCd2In
_chemical_formula_sum   'V1 Cd2 In1'
_cell_volume   81.88
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Cd  Cd0  1  0.47  0.22  0.57  1.0
  Cd  Cd1  1  0.47  0.78  0.57  1.0
  In  In2  1  0.94  0.0  0.0  1.0

data_VCd2In
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.14
_cell_length_b   5.32
_cell_length_c   5.32
_cell_angle_alpha   112.94
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCd2In
_chemical_formula_sum   'V1 Cd2 In1'
_cell_volume   81.88
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  Cd  Cd1  1  0.57  0.47  0.22  1.0
  Cd  Cd2  1  0.57  0.47  0.78  1.0
  In  In3  1  -0.0  0.94  0.0  1.0

V Cd Cd In
V Cd Cd In 0 3 - o o 0 1 o o o 0 1 o o - 0 2 - - o 0 2 - - - 1 3 - o o 1 3 - o + 1 2 o o o 1 2 o - o 1 1 o o + 2 3 o + o 2 3 o + + 2 2 o o + 
VCd2In crystallizes in the triclinic P1 space group. V(1) is bonded in a single-bond geometry to two equivalent Cd(1), two equivalent Cd(2), and one In(1) atom. There is one shorter (2.68 Å) and one longer (2.92 Å) V(1)-Cd(1) bond length. There is one shorter (3.42 Å) and one longer (3.62 Å) V(1)-Cd(2) bond length. The V(1)-In(1) bond length is 0.32 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 7-coordinate geometry to two equivalent V(1), two equivalent Cd(1), two equivalent Cd(2), and one In(1) atom. Both Cd(1)-Cd(1) bond lengths are 3.14 Å. There is one shorter (2.33 Å) and one longer (3.00 Å) Cd(1)-Cd(2) bond length. The Cd(1)-In(1) bond length is 3.42 Å. In the second Cd site, Cd(2) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent Cd(1), two equivalent Cd(2), and two equivalent In(1) atoms. Both Cd(2)-Cd(2) bond lengths are 3.14 Å. There is one shorter (2.68 Å) and one longer (2.92 Å) Cd(2)-In(1) bond length. In(1) is bonded in a single-bond geometry to one V(1), one Cd(1), and two equivalent Cd(2) atoms.