data_Sn3Rh5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.58
_cell_length_b   7.58
_cell_length_c   5.5
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sn3Rh5
_chemical_formula_sum   'Sn6 Rh10'
_cell_volume   273.79
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn10  1  0.5  0.59  0.12  1.0
  Sn  Sn11  1  0.71  0.97  0.37  1.0
  Sn  Sn12  1  0.29  0.97  0.12  1.0
  Sn  Sn13  1  0.99  0.0  0.12  1.0
  Sn  Sn14  1  0.59  0.0  0.37  1.0
  Sn  Sn15  1  0.5  0.59  0.37  1.0
  Rh  Rh0  1  0.79  0.19  0.75  1.0
  Rh  Rh1  1  0.0  0.38  0.0  1.0
  Rh  Rh2  1  0.0  0.38  0.75  1.0
  Rh  Rh3  1  0.79  0.19  0.0  1.0
  Rh  Rh4  1  0.12  0.99  0.12  1.0
  Rh  Rh5  1  0.09  0.58  0.37  1.0
  Rh  Rh6  1  0.91  0.58  0.12  1.0
  Rh  Rh7  1  0.76  0.0  0.12  1.0
  Rh  Rh8  1  0.82  0.0  0.37  1.0
  Rh  Rh9  1  0.88  0.99  0.37  1.0

data_Sn3Rh5
_symmetry_space_group_name_H-M   P1
_cell_length_a   5.5
_cell_length_b   7.58
_cell_length_c   7.58
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sn3Rh5
_chemical_formula_sum   'Sn6 Rh10'
_cell_volume   273.79
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.12  0.29  0.97  1.0
  Sn  Sn1  1  0.12  0.5  0.59  1.0
  Sn  Sn2  1  0.12  0.99  0.0  1.0
  Sn  Sn3  1  0.37  0.5  0.59  1.0
  Sn  Sn4  1  0.37  0.59  0.0  1.0
  Sn  Sn5  1  0.37  0.71  0.97  1.0
  Rh  Rh6  1  -0.0  0.0  0.38  1.0
  Rh  Rh7  1  -0.0  0.79  0.19  1.0
  Rh  Rh8  1  0.12  0.12  0.99  1.0
  Rh  Rh9  1  0.12  0.76  0.0  1.0
  Rh  Rh10  1  0.12  0.91  0.58  1.0
  Rh  Rh11  1  0.37  0.09  0.58  1.0
  Rh  Rh12  1  0.37  0.82  0.0  1.0
  Rh  Rh13  1  0.37  0.88  0.99  1.0
  Rh  Rh14  1  0.75  0.0  0.38  1.0
  Rh  Rh15  1  0.75  0.79  0.19  1.0

Sn Sn Sn Sn Sn Sn Rh Rh Rh Rh Rh Rh Rh Rh Rh Rh
Sn Sn Sn Sn Sn Sn Rh Rh Rh Rh Rh Rh Rh Rh Rh Rh 0 5 o o o 1 14 o + o 1 4 o + o 1 13 o + o 2 10 o o o 3 10 + - o 3 13 o o o 6 8 + o o 6 9 o o + 7 9 - o o 7 8 o o - 7 12 - o o 9 13 o o o 11 12 - o o 13 15 o - o 13 14 o o o 14 15 o - o 
Rh5Sn3 crystallizes in the triclinic P1 space group. There are ten inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 2-coordinate geometry to one Rh(3) and one Rh(4) atom. The Rh(1)-Rh(3) bond length is 1.51 Å. The Rh(1)-Rh(4) bond length is 1.38 Å. In the second Rh site, Rh(2) is bonded in a 6-coordinate geometry to one Rh(3), one Rh(4), one Rh(6), one Rh(7), one Sn(1), and one Sn(4) atom. The Rh(2)-Rh(3) bond length is 1.38 Å. The Rh(2)-Rh(4) bond length is 1.51 Å. The Rh(2)-Rh(6) bond length is 2.44 Å. The Rh(2)-Rh(7) bond length is 2.05 Å. The Rh(2)-Sn(1) bond length is 3.38 Å. The Rh(2)-Sn(4) bond length is 2.93 Å. In the third Rh site, Rh(3) is bonded in a 3-coordinate geometry to one Rh(1), one Rh(2), and one Rh(6) atom. The Rh(3)-Rh(6) bond length is 2.44 Å. In the fourth Rh site, Rh(4) is bonded in a 3-coordinate geometry to one Rh(1), one Rh(2), and one Rh(8) atom. The Rh(4)-Rh(8) bond length is 1.50 Å. In the fifth Rh site, Rh(5) is bonded in a distorted linear geometry to one Sn(3) and one Sn(4) atom. The Rh(5)-Sn(3) bond length is 1.40 Å. The Rh(5)-Sn(4) bond length is 0.98 Å. In the sixth Rh site, Rh(6) is bonded in a 5-coordinate geometry to one Rh(2), one Rh(3), one Rh(7), one Sn(3), and one Sn(6) atom. The Rh(6)-Rh(7) bond length is 1.94 Å. The Rh(6)-Sn(3) bond length is 2.96 Å. The Rh(6)-Sn(6) bond length is 3.03 Å. In the seventh Rh site, Rh(7) is bonded in a 3-coordinate geometry to one Rh(2), one Rh(6), and one Sn(1) atom. The Rh(7)-Sn(1) bond length is 3.15 Å. In the eighth Rh site, Rh(8) is bonded in a 3-coordinate geometry to one Rh(4), one Sn(2), and one Sn(4) atom. The Rh(8)-Sn(2) bond length is 1.44 Å. The Rh(8)-Sn(4) bond length is 1.75 Å. In the ninth Rh site, Rh(9) is bonded in a 2-coordinate geometry to one Rh(10) and one Sn(2) atom. The Rh(9)-Rh(10) bond length is 0.50 Å. The Rh(9)-Sn(2) bond length is 0.80 Å. In the tenth Rh site, Rh(10) is bonded in a bent 120 degrees geometry to one Rh(9) and one Sn(4) atom. The Rh(10)-Sn(4) bond length is 1.61 Å. There are six inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 1-coordinate geometry to one Rh(2), one Rh(7), and one Sn(6) atom. The Sn(1)-Sn(6) bond length is 1.38 Å. In the second Sn site, Sn(2) is bonded in a distorted single-bond geometry to one Rh(8), one Rh(9), and one Sn(5) atom. The Sn(2)-Sn(5) bond length is 0.98 Å. In the third Sn site, Sn(3) is bonded in a single-bond geometry to one Rh(5) and one Rh(6) atom. In the fourth Sn site, Sn(4) is bonded in a 3-coordinate geometry to one Rh(10), one Rh(2), one Rh(5), and one Rh(8) atom. In the fifth Sn site, Sn(5) is bonded in a single-bond geometry to one Sn(2) atom. In the sixth Sn site, Sn(6) is bonded in a distorted single-bond geometry to one Rh(6) and one Sn(1) atom.