data_V2CrIn
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.73
_cell_length_b   4.73
_cell_length_c   4.93
_cell_angle_alpha   93.46
_cell_angle_beta   93.46
_cell_angle_gamma   33.17
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2CrIn
_chemical_formula_sum   'V2 Cr1 In1'
_cell_volume   60.19
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.78  0.0  0.09  1.0
  V  V3  1  0.97  0.0  0.83  1.0
  Cr  Cr0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.37  0.0  0.46  1.0

data_V2CrIn
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.7
_cell_length_b   4.73
_cell_length_c   4.93
_cell_angle_alpha   93.46
_cell_angle_beta   90.0
_cell_angle_gamma   106.58
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2CrIn
_chemical_formula_sum   'V2 Cr1 In1'
_cell_volume   60.19
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.03  0.17  1.0
  V  V1  1  0.0  0.22  0.91  1.0
  Cr  Cr2  1  0.0  0.0  0.0  1.0
  In  In3  1  0.0  0.63  0.54  1.0

V V Cr In
V V Cr In 0 2 + o o 0 3 + o o 0 3 o o o 1 2 + o + 1 3 + o o 1 3 o o o 2 3 o o o 2 3 o o - 3 3 + - o 
V2CrIn crystallizes in the triclinic P1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a single-bond geometry to one Cr(1) and one In(1) atom. The V(1)-Cr(1) bond length is 1.16 Å. The V(1)-In(1) bond length is 2.73 Å. In the second V site, V(2) is bonded in a single-bond geometry to one Cr(1) and two equivalent In(1) atoms. The V(2)-Cr(1) bond length is 0.83 Å. There is one shorter (2.73 Å) and one longer (3.26 Å) V(2)-In(1) bond length. Cr(1) is bonded in a water-like geometry to one V(1), one V(2), and one In(1) atom. The Cr(1)-In(1) bond length is 2.80 Å. In(1) is bonded in a 6-coordinate geometry to one V(1), two equivalent V(2), one Cr(1), and two equivalent In(1) atoms. Both In(1)-In(1) bond lengths are 2.70 Å.