data_ReTc2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.1
_cell_length_b   5.1
_cell_length_c   5.1
_cell_angle_alpha   146.96
_cell_angle_beta   129.22
_cell_angle_gamma   61.92
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ReTc2P
_chemical_formula_sum   'Re1 Tc2 P1'
_cell_volume   55.42
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re1  1  0.0  0.19  0.92  1.0
  Tc  Tc2  1  0.0  0.0  0.74  1.0
  Tc  Tc3  1  0.45  0.0  0.46  1.0
  P  P0  1  0.0  0.0  0.37  1.0

data_ReTc2P
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.9
_cell_length_b   4.37
_cell_length_c   5.1
_cell_angle_alpha   115.39
_cell_angle_beta   106.52
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ReTc2P
_chemical_formula_sum   'Re1 Tc2 P1'
_cell_volume   55.42
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.08  0.27  0.27  1.0
  Tc  Tc1  1  0.26  0.26  0.26  1.0
  Tc  Tc2  1  0.99  0.54  0.99  1.0
  P  P3  1  0.63  0.63  0.63  1.0

Re Tc Tc P
Re Tc Tc P 0 1 o o o 0 2 - o o 0 3 o o o 1 2 - o o 1 3 o o o 2 3 o o o 
ReTc2P crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ReTc2P cluster. Re(1) is bonded in a single-bond geometry to one Tc(1) atom. The Re(1)-Tc(1) bond length is 0.53 Å. There are two inequivalent Tc sites. In the first Tc site, Tc(1) is bonded in a 2-coordinate geometry to one Re(1) and one P(1) atom. The Tc(1)-P(1) bond length is 1.89 Å. In the second Tc site, Tc(2) is bonded in a single-bond geometry to one P(1) atom. The Tc(2)-P(1) bond length is 2.02 Å. P(1) is bonded in a distorted bent 120 degrees geometry to one Tc(1) and one Tc(2) atom.