data_InAg2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.55
_cell_length_b   6.55
_cell_length_c   6.55
_cell_angle_alpha   149.48
_cell_angle_beta   139.78
_cell_angle_gamma   51.32
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InAg2Cl
_chemical_formula_sum   'In1 Ag2 Cl1'
_cell_volume   91.79
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In3  1  0.0  0.25  0.7  1.0
  Ag  Ag0  1  0.0  0.0  0.66  1.0
  Ag  Ag1  1  0.72  0.0  0.93  1.0
  Cl  Cl2  1  0.0  0.0  0.52  1.0

data_InAg2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.45
_cell_length_b   4.51
_cell_length_c   6.55
_cell_angle_alpha   110.11
_cell_angle_beta   105.26
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InAg2Cl
_chemical_formula_sum   'In1 Ag2 Cl1'
_cell_volume   91.79
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.3  0.55  0.55  1.0
  Ag  Ag1  1  0.34  0.34  0.34  1.0
  Ag  Ag2  1  0.79  0.07  0.79  1.0
  Cl  Cl3  1  0.48  0.48  0.48  1.0

In Ag Ag Cl
In Ag Ag Cl 0 3 o o o 0 2 o o o 0 2 - + o 0 2 - o - 1 3 o o o 1 2 - o o 2 2 o + + 2 3 o o o 2 3 + o + 
Ag2InCl crystallizes in the triclinic P1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a single-bond geometry to one Ag(2) and one Cl(1) atom. The Ag(1)-Ag(2) bond length is 3.42 Å. The Ag(1)-Cl(1) bond length is 0.87 Å. In the second Ag site, Ag(2) is bonded in a 8-coordinate geometry to one Ag(1), two equivalent Ag(2), three equivalent In(1), and two equivalent Cl(1) atoms. Both Ag(2)-Ag(2) bond lengths are 3.45 Å. There are a spread of Ag(2)-In(1) bond distances ranging from 2.60-3.33 Å. There is one shorter (2.73 Å) and one longer (3.20 Å) Ag(2)-Cl(1) bond length. In(1) is bonded in a single-bond geometry to three equivalent Ag(2) and one Cl(1) atom. The In(1)-Cl(1) bond length is 0.88 Å. Cl(1) is bonded in a distorted water-like geometry to one Ag(1), two equivalent Ag(2), and one In(1) atom.