data_Li2VTe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.0
_cell_length_b   5.0
_cell_length_c   5.0
_cell_angle_alpha   134.1
_cell_angle_beta   134.1
_cell_angle_gamma   66.93
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2VTe
_chemical_formula_sum   'Li2 V1 Te1'
_cell_volume   63.53
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.95  0.09  1.0
  Li  Li1  1  0.0  0.0  0.0  1.0
  V  V3  1  0.0  0.0  0.17  1.0
  Te  Te2  1  0.95  0.0  0.09  1.0

data_Li2VTe
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.9
_cell_length_b   3.9
_cell_length_c   5.0
_cell_angle_alpha   112.95
_cell_angle_beta   112.95
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2VTe
_chemical_formula_sum   'Li2 V1 Te1'
_cell_volume   63.53
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.0  1.0
  Li  Li1  1  0.14  0.09  0.14  1.0
  V  V2  1  0.17  0.17  0.17  1.0
  Te  Te3  1  0.09  0.14  0.14  1.0

Li Li V Te
Li Li V Te 0 2 o + o 0 3 - + o 0 1 o + o 1 3 - o o 2 3 - o o 
Li2VTe is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Li2VTe cluster. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted single-bond geometry to one V(1) and one Te(1) atom. The Li(1)-V(1) bond length is 0.32 Å. The Li(1)-Te(1) bond length is 0.27 Å. In the second Li site, Li(2) is bonded in a distorted single-bond geometry to one Te(1) atom. The Li(2)-Te(1) bond length is 0.63 Å. V(1) is bonded in a 2-coordinate geometry to one Li(1) and one Te(1) atom. The V(1)-Te(1) bond length is 0.32 Å. Te(1) is bonded in a distorted single-bond geometry to one Li(1), one Li(2), and one V(1) atom.