data_ZrCd2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.34
_cell_length_b   3.45
_cell_length_c   6.94
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrCd2Rh
_chemical_formula_sum   'Zr1 Cd2 Rh1'
_cell_volume   80.0
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr3  1  0.0  0.0  0.02  1.0
  Cd  Cd0  1  0.67  0.73  0.01  1.0
  Cd  Cd1  1  0.0  0.0  0.1  1.0
  Rh  Rh2  1  0.67  0.73  0.27  1.0

data_ZrCd2Rh
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.34
_cell_length_b   3.45
_cell_length_c   6.94
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrCd2Rh
_chemical_formula_sum   'Zr1 Cd2 Rh1'
_cell_volume   80.0
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.0  0.0  0.02  1.0
  Cd  Cd1  1  0.0  0.0  0.1  1.0
  Cd  Cd2  1  0.67  0.73  0.01  1.0
  Rh  Rh3  1  0.67  0.73  0.27  1.0

Zr Cd Cd Rh
Zr Cd Cd Rh 0 2 o o o 0 1 - - o 1 2 + + o 1 3 o o o 2 3 - - o 
ZrRhCd2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ZrRhCd2 cluster. Zr(1) is bonded in a single-bond geometry to one Cd(1) and one Cd(2) atom. The Zr(1)-Cd(1) bond length is 1.45 Å. The Zr(1)-Cd(2) bond length is 0.51 Å. Rh(1) is bonded in a 2-coordinate geometry to one Cd(1) and one Cd(2) atom. The Rh(1)-Cd(1) bond length is 1.80 Å. The Rh(1)-Cd(2) bond length is 1.91 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 2-coordinate geometry to one Zr(1) and one Rh(1) atom. In the second Cd site, Cd(2) is bonded in a single-bond geometry to one Zr(1) and one Rh(1) atom.