data_MnCdW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.32
_cell_length_b   5.32
_cell_length_c   5.32
_cell_angle_alpha   146.14
_cell_angle_beta   130.39
_cell_angle_gamma   61.42
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnCdW2
_chemical_formula_sum   'Mn1 Cd1 W2'
_cell_volume   63.34
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn1  1  0.0  0.0  0.0  1.0
  Cd  Cd0  1  0.0  0.0  0.58  1.0
  W  W2  1  0.0  0.23  0.46  1.0
  W  W3  1  0.55  0.0  0.12  1.0

data_MnCdW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.1
_cell_length_b   4.47
_cell_length_c   5.32
_cell_angle_alpha   114.81
_cell_angle_beta   106.93
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnCdW2
_chemical_formula_sum   'Mn1 Cd1 W2'
_cell_volume   63.34
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.0  0.0  0.0  1.0
  Cd  Cd1  1  0.42  0.42  0.42  1.0
  W  W2  1  0.43  0.88  0.43  1.0
  W  W3  1  0.54  0.77  0.77  1.0

Mn Cd W W
Mn Cd W W 0 2 o o o 1 2 o o o 1 3 - o o 2 3 - o o 
W2MnCd crystallizes in the triclinic P1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 3-coordinate geometry to one W(2), two equivalent Mn(1), and one Cd(1) atom. The W(1)-W(2) bond length is 2.00 Å. There is one shorter (1.58 Å) and one longer (2.33 Å) W(1)-Mn(1) bond length. The W(1)-Cd(1) bond length is 1.78 Å. In the second W site, W(2) is bonded in a 4-coordinate geometry to one W(1), one Mn(1), and two equivalent Cd(1) atoms. The W(2)-Mn(1) bond length is 2.57 Å. There is one shorter (2.03 Å) and one longer (2.43 Å) W(2)-Cd(1) bond length. Mn(1) is bonded in a 1-coordinate geometry to one W(2), two equivalent W(1), and one Cd(1) atom. The Mn(1)-Cd(1) bond length is 2.26 Å. Cd(1) is bonded in a 4-coordinate geometry to one W(1), two equivalent W(2), and one Mn(1) atom.