data_ScV
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.11
_cell_length_b   3.11
_cell_length_c   8.99
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScV
_chemical_formula_sum   'Sc2 V2'
_cell_volume   75.1
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.0  0.79  0.59  1.0
  Sc  Sc1  1  0.55  0.9  0.4  1.0
  V  V2  1  0.0  0.79  0.67  1.0
  V  V3  1  0.55  0.9  0.32  1.0

data_ScV
_symmetry_space_group_name_H-M   C2/m
_cell_length_a   5.38
_cell_length_b   3.11
_cell_length_c   8.99
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   12
_chemical_formula_structural   ScV
_chemical_formula_sum   'Sc4 V4'
_cell_volume   150.2
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
  3  '-x, y, -z'
  4  'x, -y, z'
  5  'x+1/2, y+1/2, z'
  6  '-x+1/2, -y+1/2, -z'
  7  '-x+1/2, y+1/2, -z'
  8  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  4  0.22  0.5  0.09  1.0
  V  V1  4  0.22  0.5  0.18  1.0

Sc Sc V V
Sc Sc V V 0 2 o o o 1 3 o o o 
ScV is alpha carbon monoxide-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four scandium;vanadium molecules. Sc(1) is bonded in a single-bond geometry to one V(1) atom. The Sc(1)-V(1) bond length is 0.76 Å. V(1) is bonded in a single-bond geometry to one Sc(1) atom.