data_Co6RePd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.25
_cell_length_b   6.25
_cell_length_c   10.23
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   109.53
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Co6RePd
_chemical_formula_sum   'Co24 Re4 Pd4'
_cell_volume   376.31
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.6  0.52  0.6  1.0
  Co  Co1  1  0.37  0.71  0.88  1.0
  Co  Co2  1  0.84  0.29  0.88  1.0
  Co  Co3  1  0.6  0.48  0.6  1.0
  Co  Co4  1  0.84  0.71  0.88  1.0
  Co  Co5  1  0.37  0.29  0.88  1.0
  Co  Co6  1  0.6  0.0  0.0  1.0
  Co  Co7  1  0.83  0.26  0.31  1.0
  Co  Co8  1  0.83  0.74  0.31  1.0
  Co  Co9  1  0.6  0.52  0.64  1.0
  Co  Co10  1  0.38  0.74  0.92  1.0
  Co  Co11  1  0.83  0.26  0.92  1.0
  Co  Co12  1  0.6  0.48  0.64  1.0
  Co  Co13  1  0.83  0.74  0.92  1.0
  Co  Co14  1  0.38  0.26  0.92  1.0
  Co  Co15  1  0.6  0.0  0.12  1.0
  Co  Co16  1  0.84  0.29  0.36  1.0
  Co  Co17  1  0.84  0.71  0.36  1.0
  Co  Co18  1  0.0  0.0  0.0  1.0
  Co  Co19  1  0.38  0.26  0.31  1.0
  Co  Co20  1  0.38  0.74  0.31  1.0
  Co  Co21  1  0.0  0.0  0.12  1.0
  Co  Co22  1  0.37  0.29  0.36  1.0
  Co  Co23  1  0.37  0.71  0.36  1.0
  Re  Re28  1  0.6  0.53  0.12  1.0
  Re  Re29  1  0.6  0.47  0.12  1.0
  Re  Re30  1  0.6  0.0  0.57  1.0
  Re  Re31  1  0.6  0.0  0.67  1.0
  Pd  Pd24  1  0.6  0.57  0.0  1.0
  Pd  Pd25  1  0.6  0.43  0.0  1.0
  Pd  Pd26  1  0.0  0.0  0.56  1.0
  Pd  Pd27  1  0.0  0.0  0.67  1.0

data_Co6RePd
_symmetry_space_group_name_H-M   P1
_cell_length_a   6.25
_cell_length_b   6.25
_cell_length_c   10.23
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   109.53
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Co6RePd
_chemical_formula_sum   'Co24 Re4 Pd4'
_cell_volume   376.31
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.0  0.0  1.0
  Co  Co1  1  0.0  0.0  0.12  1.0
  Co  Co2  1  0.37  0.71  0.36  1.0
  Co  Co3  1  0.37  0.71  0.88  1.0
  Co  Co4  1  0.37  0.29  0.36  1.0
  Co  Co5  1  0.37  0.29  0.88  1.0
  Co  Co6  1  0.38  0.74  0.31  1.0
  Co  Co7  1  0.38  0.74  0.92  1.0
  Co  Co8  1  0.38  0.26  0.31  1.0
  Co  Co9  1  0.38  0.26  0.92  1.0
  Co  Co10  1  0.6  0.0  -0.0  1.0
  Co  Co11  1  0.6  0.0  0.12  1.0
  Co  Co12  1  0.6  0.48  0.6  1.0
  Co  Co13  1  0.6  0.48  0.64  1.0
  Co  Co14  1  0.6  0.52  0.6  1.0
  Co  Co15  1  0.6  0.52  0.64  1.0
  Co  Co16  1  0.83  0.26  0.31  1.0
  Co  Co17  1  0.83  0.26  0.92  1.0
  Co  Co18  1  0.83  0.74  0.31  1.0
  Co  Co19  1  0.83  0.74  0.92  1.0
  Co  Co20  1  0.84  0.29  0.36  1.0
  Co  Co21  1  0.84  0.29  0.88  1.0
  Co  Co22  1  0.84  0.71  0.36  1.0
  Co  Co23  1  0.84  0.71  0.88  1.0
  Re  Re24  1  0.6  0.0  0.57  1.0
  Re  Re25  1  0.6  0.0  0.67  1.0
  Re  Re26  1  0.6  0.47  0.12  1.0
  Re  Re27  1  0.6  0.53  0.12  1.0
  Pd  Pd28  1  0.0  0.0  0.56  1.0
  Pd  Pd29  1  0.0  0.0  0.67  1.0
  Pd  Pd30  1  0.6  0.43  -0.0  1.0
  Pd  Pd31  1  0.6  0.57  -0.0  1.0

Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Re Re Re Re Pd Pd Pd Pd
Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Re Re Re Re Pd Pd Pd Pd 0 3 o o o 0 9 o o o 1 10 o o o 2 11 o o o 3 12 o o o 4 13 o o o 5 14 o o o 6 15 o o o 7 16 o o o 8 17 o o o 9 12 o o o 18 21 o o o 19 22 o o o 20 23 o o o 24 25 o o o 26 27 o o o 28 29 o o o 30 31 o o o 
ReCo4Pd(Co)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four Co clusters and one ReCo4Pd cluster. In each Co cluster, there are two inequivalent Co sites. In the first Co site, Co(2) is bonded in a single-bond geometry to one Co(11) atom. The Co(2)-Co(11) bond length is 0.54 Å. In the second Co site, Co(11) is bonded in a distorted single-bond geometry to one Co(2) atom. In the ReCo4Pd cluster, there are four inequivalent Re sites. In the first Re site, Re(1) is bonded in a water-like geometry to one Re(2) and one Pd(1) atom. The Re(1)-Re(2) bond length is 0.42 Å. The Re(1)-Pd(1) bond length is 1.22 Å. In the second Re site, Re(2) is bonded in a water-like geometry to one Re(1) and one Pd(2) atom. The Re(2)-Pd(2) bond length is 1.22 Å. In the third Re site, Re(3) is bonded in a 1-coordinate geometry to one Re(4) and one Pd(3) atom. The Re(3)-Re(4) bond length is 1.00 Å. The Re(3)-Pd(3) bond length is 2.48 Å. In the fourth Re site, Re(4) is bonded in a 1-coordinate geometry to one Re(3) and one Pd(4) atom. The Re(4)-Pd(4) bond length is 2.48 Å. There are sixteen inequivalent Co sites. In the first Co site, Co(1) is bonded in an L-shaped geometry to one Co(10), one Co(4), and one Pd(3) atom. The Co(1)-Co(10) bond length is 0.38 Å. The Co(1)-Co(4) bond length is 0.31 Å. The Co(1)-Pd(3) bond length is 3.19 Å. In the second Co site, Co(4) is bonded in an L-shaped geometry to one Co(1) and one Co(13) atom. The Co(4)-Co(13) bond length is 0.38 Å. In the third Co site, Co(5) is bonded in a single-bond geometry to one Co(14) and one Pd(4) atom. The Co(5)-Co(14) bond length is 0.55 Å. The Co(5)-Pd(4) bond length is 2.74 Å. In the fourth Co site, Co(6) is bonded in a single-bond geometry to one Co(15) atom. The Co(6)-Co(15) bond length is 0.55 Å. In the fifth Co site, Co(8) is bonded in a single-bond geometry to one Co(17) atom. The Co(8)-Co(17) bond length is 0.54 Å. In the sixth Co site, Co(9) is bonded in a single-bond geometry to one Co(18) atom. The Co(9)-Co(18) bond length is 0.55 Å. In the seventh Co site, Co(10) is bonded in an L-shaped geometry to one Co(1) and one Co(13) atom. The Co(10)-Co(13) bond length is 0.31 Å. In the eighth Co site, Co(13) is bonded in an L-shaped geometry to one Co(10) and one Co(4) atom. In the ninth Co site, Co(14) is bonded in a 2-coordinate geometry to one Co(19), one Co(5), and one Pd(1) atom. The Co(14)-Co(19) bond length is 1.79 Å. The Co(14)-Pd(1) bond length is 1.65 Å. In the tenth Co site, Co(15) is bonded in a distorted water-like geometry to one Co(6) and one Pd(2) atom. The Co(15)-Pd(2) bond length is 1.65 Å. In the eleventh Co site, Co(17) is bonded in a single-bond geometry to one Co(8) and one Pd(3) atom. The Co(17)-Pd(3) bond length is 3.15 Å. In the twelfth Co site, Co(18) is bonded in a distorted single-bond geometry to one Co(9) and one Pd(3) atom. The Co(18)-Pd(3) bond length is 2.74 Å. In the thirteenth Co site, Co(19) is bonded in a 2-coordinate geometry to one Co(14) and one Co(22) atom. The Co(19)-Co(22) bond length is 1.19 Å. In the fourteenth Co site, Co(20) is bonded in a single-bond geometry to one Co(23) atom. The Co(20)-Co(23) bond length is 0.55 Å. In the fifteenth Co site, Co(22) is bonded in a single-bond geometry to one Co(19) atom. In the sixteenth Co site, Co(23) is bonded in a single-bond geometry to one Co(20) and one Pd(3) atom. The Co(23)-Pd(3) bond length is 3.19 Å. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 3-coordinate geometry to one Re(1), one Co(14), and one Pd(2) atom. The Pd(1)-Pd(2) bond length is 0.88 Å. In the second Pd site, Pd(2) is bonded in a 3-coordinate geometry to one Re(2), one Co(15), and one Pd(1) atom. In the third Pd site, Pd(3) is bonded in a 6-coordinate geometry to one Re(3), one Co(1), one Co(17), one Co(18), one Co(23), and one Pd(4) atom. The Pd(3)-Pd(4) bond length is 1.09 Å. In the fourth Pd site, Pd(4) is bonded in a 3-coordinate geometry to one Re(4), one Co(5), and one Pd(3) atom.