data_Hf2InOs
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.93
_cell_length_b   4.93
_cell_length_c   3.24
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   101.73
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Hf2InOs
_chemical_formula_sum   'Hf2 In1 Os1'
_cell_volume   77.07
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.56  0.09  0.62  1.0
  Hf  Hf1  1  0.56  0.91  0.62  1.0
  In  In2  1  0.0  0.0  0.0  1.0
  Os  Os3  1  0.11  0.0  0.0  1.0

data_Hf2InOs
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.24
_cell_length_b   4.93
_cell_length_c   4.93
_cell_angle_alpha   101.73
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Hf2InOs
_chemical_formula_sum   'Hf2 In1 Os1'
_cell_volume   77.07
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.62  0.56  0.09  1.0
  Hf  Hf1  1  0.62  0.56  0.91  1.0
  In  In2  1  0.0  0.0  0.0  1.0
  Os  Os3  1  -0.0  0.11  0.0  1.0

Hf Hf In Os
Hf Hf In Os 0 1 o - o 2 3 o o o 
(Hf)2OsIn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Hf cluster and one OsIn cluster. In the Hf cluster, there are two inequivalent Hf sites. In the first Hf site, Hf(1) is bonded in a distorted single-bond geometry to one Hf(2) atom. The Hf(1)-Hf(2) bond length is 0.87 Å. In the second Hf site, Hf(2) is bonded in a distorted single-bond geometry to one Hf(1) atom. In the OsIn cluster, Os(1) is bonded in a distorted single-bond geometry to one In(1) atom. The Os(1)-In(1) bond length is 0.55 Å. In(1) is bonded in a single-bond geometry to one Os(1) atom.