data_ZnInBr2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.57
_cell_length_b   3.57
_cell_length_c   8.63
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnInBr2
_chemical_formula_sum   'Zn1 In1 Br2'
_cell_volume   109.81
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.0  0.67  1.0
  In  In2  1  0.78  0.78  0.36  1.0
  Br  Br0  1  0.78  0.78  0.95  1.0
  Br  Br1  1  0.0  0.0  0.59  1.0

data_ZnInBr2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.05
_cell_length_b   5.05
_cell_length_c   8.63
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZnInBr2
_chemical_formula_sum   'Zn2 In2 Br4'
_cell_volume   219.62
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  2  0.0  0.0  0.67  1.0
  In  In1  2  0.28  0.5  0.36  1.0
  Br  Br2  2  0.0  0.0  0.59  1.0
  Br  Br3  2  0.28  0.5  0.95  1.0

Zn In Br Br
Zn In Br Br 0 3 o o o 0 2 - - o 1 3 + + o 1 2 o o - 2 2 + o o 2 2 o + o 2 3 + + o 
ZnInBr2 is Indium-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ZnInBr2 clusters. Zn(1) is bonded in a single-bond geometry to one Br(1) and one Br(2) atom. The Zn(1)-Br(1) bond length is 2.62 Å. The Zn(1)-Br(2) bond length is 0.74 Å. In(1) is bonded in a single-bond geometry to one Br(2) atom. The In(1)-Br(2) bond length is 2.29 Å. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Br site, Br(2) is bonded in a distorted single-bond geometry to one Zn(1) and one In(1) atom.