data_La2InPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.73
_cell_length_b   3.73
_cell_length_c   8.02
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   La2InPd
_chemical_formula_sum   'La2 In1 Pd1'
_cell_volume   111.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La1  1  0.87  0.87  0.24  1.0
  La  La2  1  0.87  0.87  0.78  1.0
  In  In0  1  0.0  0.0  0.01  1.0
  Pd  Pd3  1  0.0  0.0  0.0  1.0

data_La2InPd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.28
_cell_length_b   5.28
_cell_length_c   8.02
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   La2InPd
_chemical_formula_sum   'La4 In2 Pd2'
_cell_volume   223.43
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  2  0.37  0.5  0.24  1.0
  La  La1  2  0.37  0.5  0.78  1.0
  In  In2  2  0.0  0.0  0.01  1.0
  Pd  Pd3  2  0.0  0.0  0.0  1.0

La La In Pd
La La In Pd 0 3 + + o 0 2 + + o 1 3 + + + 1 2 + + + 2 3 o o o 
La2PdIn crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two La2PdIn clusters. There are two inequivalent La sites. In the first La site, La(1) is bonded in a single-bond geometry to one In(1) atom. The La(1)-In(1) bond length is 1.96 Å. In the second La site, La(2) is bonded in a single-bond geometry to one Pd(1) atom. The La(2)-Pd(1) bond length is 1.89 Å. Pd(1) is bonded in a distorted bent 150 degrees geometry to one La(2) and one In(1) atom. The Pd(1)-In(1) bond length is 0.08 Å. In(1) is bonded in a distorted single-bond geometry to one La(1) and one Pd(1) atom.