data_ZnRhW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.22
_cell_length_b   3.22
_cell_length_c   5.85
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnRhW2
_chemical_formula_sum   'Zn1 Rh1 W2'
_cell_volume   60.83
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.0  0.97  1.0
  Rh  Rh0  1  0.61  0.61  0.29  1.0
  W  W1  1  0.0  0.0  0.06  1.0
  W  W2  1  0.61  0.61  0.46  1.0

data_ZnRhW2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.56
_cell_length_b   4.56
_cell_length_c   5.85
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZnRhW2
_chemical_formula_sum   'Zn2 Rh2 W4'
_cell_volume   121.66
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  2  0.0  0.0  0.97  1.0
  Rh  Rh1  2  0.11  0.5  0.29  1.0
  W  W2  2  0.0  0.0  0.06  1.0
  W  W3  2  0.11  0.5  0.46  1.0

Zn Rh W W
Zn Rh W W 0 2 o o + 1 3 o o o 
RhWWZn is High Pressure Cadmuum Telluride structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two RhW clusters and two WZn clusters. In each RhW cluster, W(2) is bonded in a single-bond geometry to one Rh(1) atom. The W(2)-Rh(1) bond length is 1.02 Å. Rh(1) is bonded in a distorted single-bond geometry to one W(2) atom. In each WZn cluster, W(1) is bonded in a single-bond geometry to one Zn(1) atom. The W(1)-Zn(1) bond length is 0.52 Å. Zn(1) is bonded in a single-bond geometry to one W(1) atom.