data_ZnCdCo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.78
_cell_length_b   8.78
_cell_length_c   8.78
_cell_angle_alpha   18.0
_cell_angle_beta   18.0
_cell_angle_gamma   18.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnCdCo2
_chemical_formula_sum   'Zn1 Cd1 Co2'
_cell_volume   56.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.0  0.0  1.0
  Cd  Cd0  1  0.0  0.0  0.96  1.0
  Co  Co1  1  0.0  0.0  0.29  1.0
  Co  Co2  1  0.0  0.0  0.63  1.0

data_ZnCdCo2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.76
_cell_length_b   2.75
_cell_length_c   8.78
_cell_angle_alpha   90.0
_cell_angle_beta   100.41
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZnCdCo2
_chemical_formula_sum   'Zn2 Cd2 Co4'
_cell_volume   113.0
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  2  0.0  0.0  0.0  1.0
  Cd  Cd1  2  0.0  0.0  0.04  1.0
  Co  Co2  2  0.0  0.0  0.37  1.0
  Co  Co3  2  0.0  0.0  0.71  1.0

Zn Cd Co Co
Zn Cd Co Co 0 1 o o - 0 2 o o o 0 3 o o - 1 2 o o + 1 3 o o o 2 2 o + - 2 2 + - o 2 2 + o - 2 3 o o o 3 3 o + - 3 3 + - o 3 3 + o - 
Co2CdZn crystallizes in the monoclinic Cm space group. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted single-bond geometry to one Co(2) and one Zn(1) atom. The Co(1)-Co(2) bond length is 2.99 Å. The Co(1)-Zn(1) bond length is 2.52 Å. In the second Co site, Co(2) is bonded to one Co(1), six equivalent Co(2), and one Cd(1) atom to form a mixture of distorted corner and edge-sharing CoCdCo7 hexagonal bipyramids. All Co(2)-Co(2) bond lengths are 2.75 Å. The Co(2)-Cd(1) bond length is 2.90 Å. Cd(1) is bonded in a single-bond geometry to one Co(2) and one Zn(1) atom. The Cd(1)-Zn(1) bond length is 0.38 Å. Zn(1) is bonded in a single-bond geometry to one Co(1) and one Cd(1) atom.