data_ZnInCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.81
_cell_length_b   10.81
_cell_length_c   10.81
_cell_angle_alpha   18.69
_cell_angle_beta   18.69
_cell_angle_gamma   18.69
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnInCl2
_chemical_formula_sum   'Zn1 In1 Cl2'
_cell_volume   113.32
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.0  0.0  1.0
  In  In2  1  0.0  0.0  0.93  1.0
  Cl  Cl0  1  0.0  0.0  0.2  1.0
  Cl  Cl1  1  0.0  0.0  0.65  1.0

data_ZnInCl2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.08
_cell_length_b   3.51
_cell_length_c   10.81
_cell_angle_alpha   90.0
_cell_angle_beta   100.81
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZnInCl2
_chemical_formula_sum   'Zn2 In2 Cl4'
_cell_volume   226.64
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  2  0.0  0.0  0.0  1.0
  In  In1  2  0.0  0.0  0.07  1.0
  Cl  Cl2  2  0.0  0.0  0.35  1.0
  Cl  Cl3  2  0.0  0.0  0.8  1.0

Zn In Cl Cl
Zn In Cl Cl 0 1 o o - 0 2 o o o 0 3 o o - 1 3 o o o 3 3 o + - 3 3 + - o 3 3 + o - 
ZnInCl2 is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ZnInCl2 clusters. Zn(1) is bonded in a linear geometry to one In(1) and one Cl(1) atom. The Zn(1)-In(1) bond length is 0.80 Å. The Zn(1)-Cl(1) bond length is 2.18 Å. In(1) is bonded in a distorted single-bond geometry to one Zn(1) and one Cl(2) atom. The In(1)-Cl(2) bond length is 2.98 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one In(1) atom.