data_CrCdRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.83
_cell_length_b   4.83
_cell_length_c   4.76
_cell_angle_alpha   101.83
_cell_angle_beta   101.83
_cell_angle_gamma   33.81
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CrCdRh2
_chemical_formula_sum   'Cr1 Cd1 Rh2'
_cell_volume   60.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr1  1  0.63  0.0  0.77  1.0
  Cd  Cd0  1  0.15  0.0  0.25  1.0
  Rh  Rh2  1  0.18  0.0  0.5  1.0
  Rh  Rh3  1  0.62  0.0  0.12  1.0

data_CrCdRh2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.81
_cell_length_b   4.76
_cell_length_c   4.83
_cell_angle_alpha   101.83
_cell_angle_beta   106.9
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CrCdRh2
_chemical_formula_sum   'Cr1 Cd1 Rh2'
_cell_volume   60.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.0  0.77  0.63  1.0
  Cd  Cd1  1  0.0  0.25  0.15  1.0
  Rh  Rh2  1  0.0  0.12  0.62  1.0
  Rh  Rh3  1  0.0  0.5  0.18  1.0

Cr Cd Rh Rh
Cr Cd Rh Rh 0 3 o o + 1 2 o o o 
CrRh2Cd crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one CrRh2Cd cluster. Cr(1) is bonded in a 2-coordinate geometry to one Rh(1) and one Rh(2) atom. The Cr(1)-Rh(1) bond length is 2.28 Å. The Cr(1)-Rh(2) bond length is 1.67 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted single-bond geometry to one Cr(1) and one Cd(1) atom. The Rh(1)-Cd(1) bond length is 1.14 Å. In the second Rh site, Rh(2) is bonded in a distorted single-bond geometry to one Cr(1) atom. Cd(1) is bonded in a distorted single-bond geometry to one Rh(1) atom.