data_La2SbPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.85
_cell_length_b   3.9
_cell_length_c   7.43
_cell_angle_alpha   90.0
_cell_angle_beta   94.95
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   La2SbPd
_chemical_formula_sum   'La2 Sb1 Pd1'
_cell_volume   111.22
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.5  0.95  0.63  1.0
  La  La1  1  0.71  0.95  0.77  1.0
  Sb  Sb3  1  0.68  0.0  0.7  1.0
  Pd  Pd2  1  0.0  0.0  0.0  1.0

data_La2SbPd
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.85
_cell_length_b   3.9
_cell_length_c   7.43
_cell_angle_alpha   90.0
_cell_angle_beta   94.95
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   La2SbPd
_chemical_formula_sum   'La2 Sb1 Pd1'
_cell_volume   111.22
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.5  0.95  0.63  1.0
  La  La1  1  0.71  0.95  0.77  1.0
  Sb  Sb2  1  0.68  0.0  0.7  1.0
  Pd  Pd3  1  0.0  0.0  0.0  1.0

La La Sb Pd
La La Sb Pd 0 2 o + o 1 2 o + o 1 3 + + + 
La2PdSb crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one La2PdSb cluster. There are two inequivalent La sites. In the first La site, La(1) is bonded in a single-bond geometry to one Sb(1) atom. The La(1)-Sb(1) bond length is 0.84 Å. In the second La site, La(2) is bonded in a distorted single-bond geometry to one Pd(1) and one Sb(1) atom. The La(2)-Pd(1) bond length is 1.96 Å. The La(2)-Sb(1) bond length is 0.55 Å. Pd(1) is bonded in a single-bond geometry to one La(2) atom. Sb(1) is bonded in a distorted bent 120 degrees geometry to one La(1) and one La(2) atom.