data_TcSb2Pt
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.93
_cell_length_b   4.93
_cell_length_c   4.93
_cell_angle_alpha   127.39
_cell_angle_beta   125.44
_cell_angle_gamma   79.22
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TcSb2Pt
_chemical_formula_sum   'Tc1 Sb2 Pt1'
_cell_volume   74.87
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc3  1  0.0  0.0  0.0  1.0
  Sb  Sb1  1  0.0  0.26  0.88  1.0
  Sb  Sb2  1  0.18  0.0  0.92  1.0
  Pt  Pt0  1  0.0  0.0  0.8  1.0

data_TcSb2Pt
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.37
_cell_length_b   4.52
_cell_length_c   4.93
_cell_angle_alpha   117.28
_cell_angle_beta   116.31
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TcSb2Pt
_chemical_formula_sum   'Tc1 Sb2 Pt1'
_cell_volume   74.87
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.0  0.0  0.0  1.0
  Sb  Sb1  1  0.0  0.92  0.74  1.0
  Sb  Sb2  1  0.74  0.62  0.62  1.0
  Pt  Pt3  1  0.0  0.8  0.8  1.0

Tc Sb Sb Pt
Tc Sb Sb Pt 0 3 o o - 0 2 o o - 1 3 o o o 2 3 o o o 
TcPtSb2 is Copper structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one TcPtSb2 cluster. Tc(1) is bonded in a distorted single-bond geometry to one Pt(1) atom. The Tc(1)-Pt(1) bond length is 1.01 Å. Pt(1) is bonded in a distorted trigonal non-coplanar geometry to one Tc(1), one Sb(1), and one Sb(2) atom. The Pt(1)-Sb(1) bond length is 1.08 Å. The Pt(1)-Sb(2) bond length is 0.74 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second Sb site, Sb(2) is bonded in a single-bond geometry to one Pt(1) atom.