data_InBW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.89
_cell_length_b   2.89
_cell_length_c   7.15
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InBW2
_chemical_formula_sum   'In1 B1 W2'
_cell_volume   59.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In1  1  0.0  0.0  0.58  1.0
  B  B0  1  0.0  0.0  0.0  1.0
  W  W2  1  0.44  0.44  0.89  1.0
  W  W3  1  0.44  0.44  0.26  1.0

data_InBW2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.08
_cell_length_b   4.08
_cell_length_c   7.15
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   InBW2
_chemical_formula_sum   'In2 B2 W4'
_cell_volume   119.08
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  0.0  0.0  0.58  1.0
  B  B1  2  0.0  0.0  0.0  1.0
  W  W2  2  0.44  0.0  0.26  1.0
  W  W3  2  0.44  0.0  0.89  1.0

In B W W
In B W W 0 3 - - o 0 3 - o o 0 3 o - o 0 3 o o o 0 2 - - o 0 2 - o o 0 2 o - o 0 2 o o o 0 0 + o o 0 0 o + o 0 1 o o + 1 2 - - - 1 2 - o - 1 2 o - - 1 2 o o - 1 3 o o o 1 3 o - o 1 3 - o o 1 3 - - o 2 3 o o + 3 3 + o o 3 3 o + o 
W2InB crystallizes in the monoclinic Cm space group. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 4-coordinate geometry to one W(2), four equivalent In(1), and four equivalent B(1) atoms. The W(1)-W(2) bond length is 2.70 Å. There are a spread of W(1)-In(1) bond distances ranging from 2.87-3.18 Å. There are a spread of W(1)-B(1) bond distances ranging from 1.98-2.41 Å. In the second W site, W(2) is bonded in a 13-coordinate geometry to one W(1), four equivalent W(2), four equivalent In(1), and four equivalent B(1) atoms. All W(2)-W(2) bond lengths are 2.89 Å. There are a spread of W(2)-In(1) bond distances ranging from 2.87-3.18 Å. There are a spread of W(2)-B(1) bond distances ranging from 2.61-2.96 Å. In(1) is bonded in a 12-coordinate geometry to four equivalent W(1), four equivalent W(2), and four equivalent In(1) atoms. All In(1)-In(1) bond lengths are 2.89 Å. B(1) is bonded in a 8-coordinate geometry to four equivalent W(1) and four equivalent W(2) atoms.