data_ReAg2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.85
_cell_length_b   2.85
_cell_length_c   9.25
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   114.33
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ReAg2P
_chemical_formula_sum   'Re1 Ag2 P1'
_cell_volume   68.47
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re3  1  0.55  0.0  0.59  1.0
  Ag  Ag0  1  0.0  0.0  0.09  1.0
  Ag  Ag1  1  0.55  0.0  0.91  1.0
  P  P2  1  0.0  0.0  0.29  1.0

data_ReAg2P
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.85
_cell_length_b   2.85
_cell_length_c   9.25
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   114.33
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ReAg2P
_chemical_formula_sum   'Re1 Ag2 P1'
_cell_volume   68.47
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.55  0.0  0.59  1.0
  Ag  Ag1  1  0.0  0.0  0.09  1.0
  Ag  Ag2  1  0.55  0.0  0.91  1.0
  P  P3  1  0.0  0.0  0.29  1.0

Re Ag Ag P
Re Ag Ag P 0 0 + + o 0 0 o + o 0 0 + o o 0 3 o o o 0 3 + o o 0 2 o o o 1 2 - o - 1 2 o o - 1 3 o o o 
ReAg2P crystallizes in the triclinic P1 space group. Re(1) is bonded in a 9-coordinate geometry to six equivalent Re(1), one Ag(2), and two equivalent P(1) atoms. There are four shorter (2.85 Å) and two longer (3.09 Å) Re(1)-Re(1) bond lengths. The Re(1)-Ag(2) bond length is 2.97 Å. There is one shorter (3.08 Å) and one longer (3.20 Å) Re(1)-P(1) bond length. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one P(1) atom. There is one shorter (2.07 Å) and one longer (2.24 Å) Ag(1)-Ag(2) bond length. The Ag(1)-P(1) bond length is 1.88 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one Re(1) and two equivalent Ag(1) atoms. P(1) is bonded in a single-bond geometry to two equivalent Re(1) and one Ag(1) atom.