data_ReAsPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.74
_cell_length_b   2.74
_cell_length_c   8.93
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   109.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ReAsPd2
_chemical_formula_sum   'Re1 As1 Pd2'
_cell_volume   63.18
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re3  1  0.0  0.0  0.47  1.0
  As  As0  1  0.0  0.0  0.0  1.0
  Pd  Pd1  1  0.58  0.0  0.24  1.0
  Pd  Pd2  1  0.58  0.0  0.69  1.0

data_ReAsPd2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.74
_cell_length_b   2.74
_cell_length_c   8.93
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   109.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ReAsPd2
_chemical_formula_sum   'Re1 As1 Pd2'
_cell_volume   63.18
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.0  0.0  0.47  1.0
  As  As1  1  0.0  0.0  0.0  1.0
  Pd  Pd2  1  0.58  0.0  0.24  1.0
  Pd  Pd3  1  0.58  0.0  0.69  1.0

Re As Pd Pd
Re As Pd Pd 0 2 - o o 0 2 o o o 0 0 o + o 0 0 + o o 0 3 - o o 0 3 o o o 1 1 + + o 1 1 o + o 1 1 + o o 1 3 - o - 1 3 o o - 1 2 - o o 1 2 o o o 2 2 o + o 2 2 + o o 3 3 o + o 3 3 + o o 
RePd2As crystallizes in the triclinic P1 space group. Re(1) is bonded in a 4-coordinate geometry to two equivalent Pd(1) and two equivalent Pd(2) atoms. There is one shorter (2.33 Å) and one longer (2.58 Å) Re(1)-Pd(1) bond length. There is one shorter (2.33 Å) and one longer (2.58 Å) Re(1)-Pd(2) bond length. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 3-coordinate geometry to two equivalent Re(1) and two equivalent As(1) atoms. There is one shorter (2.42 Å) and one longer (2.66 Å) Pd(1)-As(1) bond length. In the second Pd site, Pd(2) is bonded in a 2-coordinate geometry to two equivalent Re(1) and two equivalent As(1) atoms. There is one shorter (2.97 Å) and one longer (3.17 Å) Pd(2)-As(1) bond length. As(1) is bonded in a 8-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), and four equivalent As(1) atoms. All As(1)-As(1) bond lengths are 2.74 Å.