data_Mn2SnCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.08
_cell_length_b   5.08
_cell_length_c   3.02
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mn2SnCl
_chemical_formula_sum   'Mn2 Sn1 Cl1'
_cell_volume   78.02
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn1  1  0.0  0.54  0.51  1.0
  Mn  Mn2  1  0.54  0.0  0.51  1.0
  Sn  Sn3  1  0.54  0.54  0.0  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Mn2SnCl
_symmetry_space_group_name_H-M   Amm2
_cell_length_a   3.02
_cell_length_b   7.19
_cell_length_c   7.19
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   38
_chemical_formula_structural   Mn2SnCl
_chemical_formula_sum   'Mn4 Sn2 Cl2'
_cell_volume   156.04
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, z'
  3  '-x, y, z'
  4  'x, -y, z'
  5  'x, y+1/2, z+1/2'
  6  '-x, -y+1/2, z+1/2'
  7  '-x, y+1/2, z+1/2'
  8  'x, -y+1/2, z+1/2'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  4  0.5  0.23  0.77  1.0
  Sn  Sn1  2  0.0  0.0  0.54  1.0
  Cl  Cl2  2  0.0  0.0  0.0  1.0

Mn Mn Sn Cl
Mn Mn Sn Cl 0 2 - o o 0 2 - o + 0 2 o o o 0 2 o o + 0 1 - + o 0 3 o o o 0 3 o o + 0 3 o + o 0 3 o + + 0 0 o o + 1 3 o o o 1 3 o o + 1 3 + o o 1 3 + o + 1 2 o - o 1 2 o - + 1 2 o o o 1 2 o o + 1 1 o o + 2 2 o o + 2 3 + + o 3 3 o o + 
Mn2SnCl crystallizes in the monoclinic Cm space group. Mn(1) is bonded in a 8-coordinate geometry to four equivalent Sn(1) and four equivalent Cl(1) atoms. There are a spread of Mn(1)-Sn(1) bond distances ranging from 2.76-3.15 Å. There are a spread of Mn(1)-Cl(1) bond distances ranging from 2.76-3.15 Å. Sn(1) is bonded in a 8-coordinate geometry to eight equivalent Mn(1) atoms. Cl(1) is bonded in a distorted body-centered cubic geometry to eight equivalent Mn(1) atoms.