data_LiIn2Tc
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.44
_cell_length_b   5.44
_cell_length_c   5.44
_cell_angle_alpha   137.96
_cell_angle_beta   137.96
_cell_angle_gamma   60.97
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiIn2Tc
_chemical_formula_sum   'Li1 In2 Tc1'
_cell_volume   71.56
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li2  1  0.0  0.0  0.0  1.0
  In  In0  1  0.0  0.0  0.69  1.0
  In  In1  1  0.0  0.95  0.35  1.0
  Tc  Tc3  1  0.95  0.0  0.35  1.0

data_LiIn2Tc
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.91
_cell_length_b   3.91
_cell_length_c   5.44
_cell_angle_alpha   111.02
_cell_angle_beta   111.02
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiIn2Tc
_chemical_formula_sum   'Li1 In2 Tc1'
_cell_volume   71.56
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.31  0.0  0.31  1.0
  In  In2  1  0.61  0.95  0.61  1.0
  Tc  Tc3  1  0.65  0.0  0.61  1.0

Li In In Tc
Li In In Tc 0 3 - o o 0 2 o - o 0 1 o o - 1 3 - o o 1 2 o - o 2 3 - + o 
LiTcIn2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LiTcIn2 cluster. Li(1) is bonded in a distorted single-bond geometry to one Tc(1), one In(1), and one In(2) atom. The Li(1)-Tc(1) bond length is 2.08 Å. The Li(1)-In(1) bond length is 1.68 Å. The Li(1)-In(2) bond length is 2.08 Å. Tc(1) is bonded in a single-bond geometry to one Li(1) and one In(2) atom. The Tc(1)-In(2) bond length is 0.26 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a distorted single-bond geometry to one Li(1) atom. In the second In site, In(2) is bonded in a single-bond geometry to one Li(1) and one Tc(1) atom.