data_KVAg
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.05
_cell_length_b   7.05
_cell_length_c   7.05
_cell_angle_alpha   151.08
_cell_angle_beta   151.08
_cell_angle_gamma   41.36
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KVAg
_chemical_formula_sum   'K1 V1 Ag1'
_cell_volume   81.59
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K1  1  0.0  0.0  0.47  1.0
  V  V2  1  0.0  0.0  0.23  1.0
  Ag  Ag0  1  0.0  0.0  0.48  1.0

data_KVAg
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.98
_cell_length_b   4.98
_cell_length_c   7.05
_cell_angle_alpha   90.0
_cell_angle_beta   110.68
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   KVAg
_chemical_formula_sum   'K2 V2 Ag2'
_cell_volume   163.19
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  2  0.47  0.0  0.47  1.0
  V  V1  2  0.23  0.0  0.23  1.0
  Ag  Ag2  2  0.48  0.0  0.48  1.0

K V Ag
K V Ag 0 2 o o o 0 1 o o o 1 2 o o o 
KVAg crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two KVAg clusters. K(1) is bonded in a distorted single-bond geometry to one V(1) and one Ag(1) atom. The K(1)-V(1) bond length is 1.67 Å. The K(1)-Ag(1) bond length is 0.07 Å. V(1) is bonded in a single-bond geometry to one K(1) atom. Ag(1) is bonded in a single-bond geometry to one K(1) atom.