data_CrInCo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.99
_cell_length_b   2.99
_cell_length_c   6.13
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CrInCo2
_chemical_formula_sum   'Cr1 In1 Co2'
_cell_volume   54.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr2  1  0.0  0.0  0.74  1.0
  In  In3  1  0.49  0.49  0.66  1.0
  Co  Co0  1  0.0  0.0  0.26  1.0
  Co  Co1  1  0.49  0.49  0.54  1.0

data_CrInCo2
_symmetry_space_group_name_H-M   P4mm
_cell_length_a   2.99
_cell_length_b   2.99
_cell_length_c   6.13
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   99
_chemical_formula_structural   CrInCo2
_chemical_formula_sum   'Cr1 In1 Co2'
_cell_volume   54.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x, z'
  3  '-x, -y, z'
  4  'y, -x, z'
  5  '-x, y, z'
  6  'y, x, z'
  7  'x, -y, z'
  8  '-y, -x, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.0  0.0  0.74  1.0
  In  In1  1  0.5  0.5  0.66  1.0
  Co  Co2  1  0.0  0.0  0.26  1.0
  Co  Co3  1  0.5  0.5  0.54  1.0

Cr In Co Co
Cr In Co Co 0 3 - - o 0 3 - o o 0 3 o - o 0 3 o o o 0 1 - - o 0 1 - o o 0 1 o - o 0 1 o o o 0 2 o o + 0 2 o o o 1 3 o o o 1 2 + + o 1 2 + o o 1 2 o + o 1 2 o o o 2 3 - - o 2 3 - o o 2 3 o - o 2 3 o o o 2 2 + o o 2 2 o + o 
Co2CrIn crystallizes in the monoclinic Cm space group. Cr(1) is bonded in a 5-coordinate geometry to two equivalent Co(1) and four equivalent In(1) atoms. There is one shorter (2.95 Å) and one longer (3.18 Å) Cr(1)-Co(1) bond length. There are a spread of Cr(1)-In(1) bond distances ranging from 2.14-2.20 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 10-coordinate geometry to two equivalent Cr(1), four equivalent Co(1), and four equivalent Co(2) atoms. All Co(1)-Co(1) bond lengths are 2.99 Å. There are a spread of Co(1)-Co(2) bond distances ranging from 2.69-2.74 Å. In the second Co site, Co(2) is bonded in a single-bond geometry to four equivalent Co(1) and one In(1) atom. The Co(2)-In(1) bond length is 0.73 Å. In(1) is bonded in a single-bond geometry to four equivalent Cr(1) and one Co(2) atom.