data_ZnCoTc2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.84
_cell_length_b   4.84
_cell_length_c   4.84
_cell_angle_alpha   141.64
_cell_angle_beta   129.38
_cell_angle_gamma   65.26
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnCoTc2
_chemical_formula_sum   'Zn1 Co1 Tc2'
_cell_volume   53.68
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.07  0.08  1.0
  Co  Co0  1  0.0  0.0  0.08  1.0
  Tc  Tc1  1  0.0  0.07  0.04  1.0
  Tc  Tc2  1  0.0  0.0  0.02  1.0

data_ZnCoTc2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.18
_cell_length_b   4.14
_cell_length_c   4.84
_cell_angle_alpha   115.31
_cell_angle_beta   109.18
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnCoTc2
_chemical_formula_sum   'Zn1 Co1 Tc2'
_cell_volume   53.68
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.92  0.99  0.99  1.0
  Co  Co1  1  0.92  0.92  0.92  1.0
  Tc  Tc2  1  0.96  0.03  0.03  1.0
  Tc  Tc3  1  0.98  0.98  0.98  1.0

Zn Co Tc Tc
Zn Co Tc Tc 0 3 o o o 0 2 o o o 0 1 o o o 1 3 o o o 
Tc2CoZn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Tc2CoZn cluster. There are two inequivalent Tc sites. In the first Tc site, Tc(1) is bonded in a single-bond geometry to one Zn(1) atom. The Tc(1)-Zn(1) bond length is 0.20 Å. In the second Tc site, Tc(2) is bonded in a single-bond geometry to one Co(1) and one Zn(1) atom. The Tc(2)-Co(1) bond length is 0.27 Å. The Tc(2)-Zn(1) bond length is 0.21 Å. Co(1) is bonded in a 2-coordinate geometry to one Tc(2) and one Zn(1) atom. The Co(1)-Zn(1) bond length is 0.32 Å. Zn(1) is bonded in a single-bond geometry to one Tc(1), one Tc(2), and one Co(1) atom.