data_Re2PIr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.03
_cell_length_b   5.03
_cell_length_c   4.28
_cell_angle_alpha   90.49
_cell_angle_beta   90.49
_cell_angle_gamma   33.63
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Re2PIr
_chemical_formula_sum   'Re2 P1 Ir1'
_cell_volume   59.9
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re2  1  0.53  0.0  0.17  1.0
  Re  Re3  1  0.06  0.0  0.11  1.0
  P  P1  1  0.0  0.0  0.0  1.0
  Ir  Ir0  1  0.79  0.0  0.14  1.0

data_Re2PIr
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.91
_cell_length_b   4.28
_cell_length_c   5.03
_cell_angle_alpha   90.49
_cell_angle_beta   106.81
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Re2PIr
_chemical_formula_sum   'Re2 P1 Ir1'
_cell_volume   59.9
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.0  0.11  0.06  1.0
  Re  Re1  1  0.0  0.17  0.53  1.0
  P  P2  1  0.0  0.0  0.0  1.0
  Ir  Ir3  1  0.0  0.14  0.79  1.0

Re Re P Ir
Re Re P Ir 0 3 o o o 1 2 o o o 1 3 - o o 2 3 - o o 
Re2IrP crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Re2IrP cluster. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a single-bond geometry to one Ir(1) atom. The Re(1)-Ir(1) bond length is 1.32 Å. In the second Re site, Re(2) is bonded in a single-bond geometry to one Ir(1) and one P(1) atom. The Re(2)-Ir(1) bond length is 1.32 Å. The Re(2)-P(1) bond length is 0.56 Å. Ir(1) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one P(1) atom. The Ir(1)-P(1) bond length is 1.20 Å. P(1) is bonded in a single-bond geometry to one Re(2) and one Ir(1) atom.