data_Zn(AgO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.39
_cell_length_b   6.39
_cell_length_c   15.49
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zn(AgO2)2
_chemical_formula_sum   'Zn6 Ag12 O24'
_cell_volume   548.15
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.0  0.69  0.78  1.0
  Zn  Zn1  1  0.0  0.0  0.66  1.0
  Zn  Zn2  1  0.0  0.0  0.46  1.0
  Zn  Zn3  1  0.2  0.85  0.47  1.0
  Zn  Zn4  1  0.0  0.69  1.0  1.0
  Zn  Zn5  1  0.0  0.0  0.84  1.0
  Ag  Ag6  1  0.2  0.72  0.91  1.0
  Ag  Ag7  1  0.57  0.91  0.91  1.0
  Ag  Ag8  1  0.0  0.54  0.75  1.0
  Ag  Ag9  1  0.82  0.91  0.91  1.0
  Ag  Ag10  1  0.2  0.85  0.33  1.0
  Ag  Ag11  1  0.4  0.77  0.75  1.0
  Ag  Ag12  1  0.0  0.83  0.58  1.0
  Ag  Ag13  1  0.6  0.77  0.75  1.0
  Ag  Ag14  1  0.39  0.62  0.58  1.0
  Ag  Ag15  1  0.0  0.69  0.17  1.0
  Ag  Ag16  1  0.61  0.62  0.58  1.0
  Ag  Ag17  1  0.2  0.85  0.65  1.0
  O  O18  1  0.69  0.67  0.21  1.0
  O  O19  1  0.0  0.0  0.68  1.0
  O  O20  1  0.31  0.67  0.21  1.0
  O  O21  1  0.0  0.73  0.21  1.0
  O  O22  1  0.2  0.06  0.67  1.0
  O  O23  1  0.64  0.95  0.01  1.0
  O  O24  1  0.65  0.74  0.67  1.0
  O  O25  1  0.2  0.85  0.98  1.0
  O  O26  1  0.75  0.95  0.01  1.0
  O  O27  1  0.2  0.85  0.48  1.0
  O  O28  1  0.74  0.74  0.67  1.0
  O  O29  1  0.2  0.64  0.01  1.0
  O  O30  1  0.0  0.9  0.49  1.0
  O  O31  1  0.48  0.81  0.77  1.0
  O  O32  1  0.45  0.59  0.49  1.0
  O  O33  1  0.0  0.69  0.99  1.0
  O  O34  1  0.0  0.69  0.28  1.0
  O  O35  1  0.52  0.81  0.77  1.0
  O  O36  1  0.55  0.59  0.49  1.0
  O  O37  1  0.0  0.45  0.77  1.0
  O  O38  1  0.2  0.92  0.4  1.0
  O  O39  1  0.0  0.0  0.89  1.0
  O  O40  1  1.0  0.81  0.4  1.0
  O  O41  1  0.4  0.81  0.4  1.0

data_Zn(AgO2)2
_symmetry_space_group_name_H-M   P1
_cell_length_a   6.39
_cell_length_b   6.39
_cell_length_c   15.49
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zn(AgO2)2
_chemical_formula_sum   'Zn6 Ag12 O24'
_cell_volume   548.15
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  -0.0  0.69  0.78  1.0
  Zn  Zn1  1  -0.0  0.69  1.0  1.0
  Zn  Zn2  1  0.0  0.0  0.46  1.0
  Zn  Zn3  1  0.0  0.0  0.66  1.0
  Zn  Zn4  1  0.0  0.0  0.84  1.0
  Zn  Zn5  1  0.2  0.85  0.47  1.0
  Ag  Ag6  1  -0.0  0.83  0.58  1.0
  Ag  Ag7  1  -0.0  0.69  0.17  1.0
  Ag  Ag8  1  -0.0  0.54  0.75  1.0
  Ag  Ag9  1  0.2  0.85  0.33  1.0
  Ag  Ag10  1  0.2  0.85  0.65  1.0
  Ag  Ag11  1  0.2  0.72  0.91  1.0
  Ag  Ag12  1  0.39  0.62  0.58  1.0
  Ag  Ag13  1  0.4  0.77  0.75  1.0
  Ag  Ag14  1  0.57  0.91  0.91  1.0
  Ag  Ag15  1  0.6  0.77  0.75  1.0
  Ag  Ag16  1  0.61  0.62  0.58  1.0
  Ag  Ag17  1  0.82  0.91  0.91  1.0
  O  O18  1  -0.0  0.45  0.77  1.0
  O  O19  1  -0.0  0.9  0.49  1.0
  O  O20  1  -0.0  0.73  0.21  1.0
  O  O21  1  -0.0  0.69  0.28  1.0
  O  O22  1  -0.0  0.69  0.99  1.0
  O  O23  1  0.0  0.0  0.68  1.0
  O  O24  1  0.0  0.0  0.89  1.0
  O  O25  1  0.2  0.85  0.48  1.0
  O  O26  1  0.2  0.85  0.98  1.0
  O  O27  1  0.2  0.92  0.4  1.0
  O  O28  1  0.2  0.06  0.67  1.0
  O  O29  1  0.2  0.64  0.01  1.0
  O  O30  1  0.31  0.67  0.21  1.0
  O  O31  1  0.4  0.81  0.4  1.0
  O  O32  1  0.45  0.59  0.49  1.0
  O  O33  1  0.48  0.81  0.77  1.0
  O  O34  1  0.52  0.81  0.77  1.0
  O  O35  1  0.55  0.59  0.49  1.0
  O  O36  1  0.64  0.95  0.01  1.0
  O  O37  1  0.65  0.74  0.67  1.0
  O  O38  1  0.69  0.67  0.21  1.0
  O  O39  1  0.74  0.74  0.67  1.0
  O  O40  1  0.75  0.95  0.01  1.0
  O  O41  1  1.0  0.81  0.4  1.0

Zn Zn Zn Zn Zn Zn Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag O O O O O O O O O O O O O O O O O O O O O O O O
Zn Zn Zn Zn Zn Zn Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag Ag O O O O O O O O O O O O O O O O O O O O O O O O 0 8 o o o 1 19 o o o 1 12 o - o 1 22 o o o 2 30 o - o 3 27 o o o 3 38 o o o 3 41 o o o 4 33 o o o 4 25 o o o 4 29 o o + 5 39 o o o 6 33 o o o 6 25 o o o 6 29 o o + 7 26 o o + 7 23 o o + 7 9 o o o 8 37 o o o 9 39 + + o 10 34 o o o 10 38 o o o 10 20 o o o 10 41 o o o 11 31 o o o 12 30 o o o 12 27 o o o 12 17 o o o 13 35 o o o 14 32 o o o 14 16 o o o 15 21 o o o 15 18 - o o 15 20 o o o 16 36 o o o 16 32 o o o 16 24 o o o 16 28 o o o 17 22 o + o 18 34 + o o 18 21 + o o 18 20 o o o 19 22 o o o 20 34 o o o 20 21 o o o 21 34 o o o 23 26 o o o 24 28 o o o 25 33 o o o 25 29 o o + 27 38 o o o 27 41 o o o 29 33 o o - 31 35 o o o 32 36 o o o 32 41 o o o 38 40 - o o 38 41 o o o 
AgZnOAgZnO2Zn2(AgO3)3AgZnO3Ag2ZnO3(Ag2O3)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Ag2O3 cluster, one Ag2ZnO3 cluster, one AgZnO cluster, one AgZnO2 cluster, one AgZnO3 cluster, and one Zn2(AgO3)3 cluster. In the Ag2O3 cluster, there are four inequivalent Ag sites. In the first Ag site, Ag(6) is bonded in a single-bond geometry to one O(14) atom. The Ag(6)-O(14) bond length is 0.51 Å. In the second Ag site, Ag(8) is bonded in a 2-coordinate geometry to one O(18) and one O(7) atom. The Ag(8)-O(18) bond length is 0.72 Å. The Ag(8)-O(7) bond length is 1.32 Å. In the third Ag site, Ag(9) is bonded in a distorted single-bond geometry to one Ag(11) and one O(15) atom. The Ag(9)-Ag(11) bond length is 1.45 Å. The Ag(9)-O(15) bond length is 1.47 Å. In the fourth Ag site, Ag(11) is bonded in a 4-coordinate geometry to one Ag(9), one O(11), one O(19), and one O(7) atom. The Ag(11)-O(11) bond length is 1.61 Å. The Ag(11)-O(19) bond length is 1.41 Å. The Ag(11)-O(7) bond length is 1.55 Å. There are six inequivalent O sites. In the first O site, O(15) is bonded in a distorted water-like geometry to one Ag(9) and one O(19) atom. The O(15)-O(19) bond length is 0.66 Å. In the second O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Ag(8) and one O(14) atom. The O(18)-O(14) bond length is 0.31 Å. In the third O site, O(19) is bonded in a water-like geometry to one Ag(11) and one O(15) atom. In the fourth O site, O(7) is bonded in a 3-coordinate geometry to one Ag(11), one Ag(8), and one O(11) atom. The O(7)-O(11) bond length is 0.62 Å. In the fifth O site, O(11) is bonded in a 1-coordinate geometry to one Ag(11) and one O(7) atom. In the sixth O site, O(14) is bonded in a distorted single-bond geometry to one Ag(6) and one O(18) atom. In the Ag2ZnO3 cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(2) is bonded in a distorted single-bond geometry to one O(6) atom. The Ag(2)-O(6) bond length is 1.59 Å. In the second Ag site, Ag(4) is bonded in a 2-coordinate geometry to one O(22) and one O(9) atom. The Ag(4)-O(22) bond length is 1.03 Å. The Ag(4)-O(9) bond length is 1.65 Å. Zn(6) is bonded in a single-bond geometry to one O(22) atom. The Zn(6)-O(22) bond length is 0.81 Å. There are three inequivalent O sites. In the first O site, O(22) is bonded in a water-like geometry to one Ag(4) and one Zn(6) atom. In the second O site, O(6) is bonded in a water-like geometry to one Ag(2) and one O(9) atom. The O(6)-O(9) bond length is 0.74 Å. In the third O site, O(9) is bonded in a distorted water-like geometry to one Ag(4) and one O(6) atom. In the AgZnO cluster, Ag(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one O(20) atom. The Ag(3)-Zn(1) bond length is 1.12 Å. The Ag(3)-O(20) bond length is 0.63 Å. Zn(1) is bonded in a single-bond geometry to one Ag(3) atom. O(20) is bonded in a single-bond geometry to one Ag(3) atom. In the AgZnO2 cluster, Ag(12) is bonded in a single-bond geometry to one O(5) atom. The Ag(12)-O(5) bond length is 1.38 Å. Zn(2) is bonded in a single-bond geometry to one O(2) and one O(5) atom. The Zn(2)-O(2) bond length is 0.27 Å. The Zn(2)-O(5) bond length is 1.12 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Zn(2) atom. In the second O site, O(5) is bonded in a water-like geometry to one Ag(12) and one Zn(2) atom. In the AgZnO3 cluster, Ag(1) is bonded in a 1-coordinate geometry to one O(12) and one O(8) atom. The Ag(1)-O(12) bond length is 1.62 Å. The Ag(1)-O(8) bond length is 1.40 Å. Zn(5) is bonded in a single-bond geometry to one O(12) and one O(16) atom. The Zn(5)-O(12) bond length is 1.44 Å. The Zn(5)-O(16) bond length is 0.14 Å. There are three inequivalent O sites. In the first O site, O(16) is bonded in a single-bond geometry to one Zn(5) atom. In the second O site, O(8) is bonded in a 1-coordinate geometry to one Ag(1) and one O(12) atom. The O(8)-O(12) bond length is 1.35 Å. In the third O site, O(12) is bonded in a 3-coordinate geometry to one Ag(1), one Zn(5), and one O(8) atom. In the Zn2(AgO3)3 cluster, there are three inequivalent Ag sites. In the first Ag site, Ag(5) is bonded in a 2-coordinate geometry to one O(17), one O(21), one O(23), one O(24), and one O(3) atom. The Ag(5)-O(17) bond length is 1.35 Å. The Ag(5)-O(21) bond length is 1.26 Å. The Ag(5)-O(23) bond length is 1.64 Å. The Ag(5)-O(24) bond length is 1.83 Å. The Ag(5)-O(3) bond length is 2.40 Å. In the second Ag site, Ag(7) is bonded in a distorted single-bond geometry to one O(13) atom. The Ag(7)-O(13) bond length is 1.44 Å. In the third Ag site, Ag(10) is bonded in a single-bond geometry to one O(1), one O(3), and one O(4) atom. The Ag(10)-O(1) bond length is 1.98 Å. The Ag(10)-O(3) bond length is 2.11 Å. The Ag(10)-O(4) bond length is 0.65 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(3) is bonded in a single-bond geometry to one O(13) and one O(23) atom. The Zn(3)-O(13) bond length is 0.80 Å. The Zn(3)-O(23) bond length is 1.50 Å. In the second Zn site, Zn(4) is bonded in a distorted single-bond geometry to one O(10), one O(21), one O(23), and one O(24) atom. The Zn(4)-O(10) bond length is 0.15 Å. The Zn(4)-O(21) bond length is 1.24 Å. The Zn(4)-O(23) bond length is 1.63 Å. The Zn(4)-O(24) bond length is 1.82 Å. There are nine inequivalent O sites. In the first O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Ag(5) and one O(4) atom. The O(17)-O(4) bond length is 1.11 Å. In the second O site, O(21) is bonded in a 3-coordinate geometry to one Ag(5), one Zn(4), and one O(23) atom. The O(21)-O(23) bond length is 1.11 Å. In the third O site, O(23) is bonded in a 5-coordinate geometry to one Ag(5), one Zn(3), one Zn(4), one O(13), and one O(21) atom. The O(23)-O(13) bond length is 1.45 Å. In the fourth O site, O(24) is bonded in a distorted L-shaped geometry to one Ag(5) and one Zn(4) atom. In the fifth O site, O(1) is bonded in a 2-coordinate geometry to one Ag(10) and one O(4) atom. The O(1)-O(4) bond length is 1.78 Å. In the sixth O site, O(3) is bonded in a 2-coordinate geometry to one Ag(10) and one Ag(5) atom. In the seventh O site, O(4) is bonded in a distorted single-bond geometry to one Ag(10), one O(1), and one O(17) atom. In the eighth O site, O(10) is bonded in a single-bond geometry to one Zn(4) atom. In the ninth O site, O(13) is bonded in a 1-coordinate geometry to one Ag(7), one Zn(3), and one O(23) atom.