data_LiVTe2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.87
_cell_length_b   4.87
_cell_length_c   3.41
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiVTe2
_chemical_formula_sum   'Li1 V1 Te2'
_cell_volume   80.91
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.0  1.0
  V  V3  1  0.44  0.44  0.0  1.0
  Te  Te1  1  0.0  0.44  0.7  1.0
  Te  Te2  1  0.44  0.0  0.7  1.0

data_LiVTe2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.89
_cell_length_b   6.89
_cell_length_c   3.41
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LiVTe2
_chemical_formula_sum   'Li2 V2 Te4'
_cell_volume   161.81
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.0  1.0
  V  V1  2  0.44  0.0  0.0  1.0
  Te  Te2  4  0.22  0.22  0.7  1.0

Li V Te Te
Li V Te Te 0 3 o o - 0 2 o o - 1 2 o o - 1 3 o o - 
LiVTe2 crystallizes in the monoclinic Cm space group. Li(1) is bonded in a 2-coordinate geometry to six equivalent Te(1) atoms. There are a spread of Li(1)-Te(1) bond distances ranging from 2.35-3.21 Å. V(1) is bonded in a 2-coordinate geometry to six equivalent Te(1) atoms. There are a spread of V(1)-Te(1) bond distances ranging from 2.35-3.21 Å. Te(1) is bonded in a 6-coordinate geometry to three equivalent Li(1) and three equivalent V(1) atoms.