data_V2GaOs
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.99
_cell_length_b   4.99
_cell_length_c   4.99
_cell_angle_alpha   144.5
_cell_angle_beta   129.13
_cell_angle_gamma   63.56
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2GaOs
_chemical_formula_sum   'V2 Ga1 Os1'
_cell_volume   55.2
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.0  0.03  1.0
  V  V3  1  0.52  0.0  0.02  1.0
  Ga  Ga0  1  0.0  0.0  0.23  1.0
  Os  Os1  1  0.0  0.14  0.21  1.0

data_V2GaOs
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.04
_cell_length_b   4.28
_cell_length_c   4.99
_cell_angle_alpha   115.44
_cell_angle_beta   107.75
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2GaOs
_chemical_formula_sum   'V2 Ga1 Os1'
_cell_volume   55.2
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.5  0.98  0.5  1.0
  V  V1  1  0.97  0.97  0.97  1.0
  Ga  Ga2  1  0.77  0.77  0.77  1.0
  Os  Os3  1  0.79  0.93  0.93  1.0

V V Ga Os
V V Ga Os 0 3 o o o 0 1 - o o 1 2 + o o 1 3 + o o 2 3 o o o 
V2OsGa crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one V2OsGa cluster. There are two inequivalent V sites. In the first V site, V(1) is bonded in a single-bond geometry to one Os(1) atom. The V(1)-Os(1) bond length is 0.52 Å. In the second V site, V(2) is bonded in a distorted single-bond geometry to one Ga(1) atom. The V(2)-Ga(1) bond length is 1.91 Å. Os(1) is bonded in a distorted water-like geometry to one V(1) and one Ga(1) atom. The Os(1)-Ga(1) bond length is 0.80 Å. Ga(1) is bonded in a distorted single-bond geometry to one V(2) and one Os(1) atom.