data_LaReBi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.95
_cell_length_b   4.69
_cell_length_c   5.89
_cell_angle_alpha   90.0
_cell_angle_beta   100.6
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaReBi2
_chemical_formula_sum   'La1 Re1 Bi2'
_cell_volume   107.45
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La2  1  0.0  0.0  0.0  1.0
  Re  Re3  1  0.43  0.0  0.9  1.0
  Bi  Bi0  1  0.58  0.35  0.23  1.0
  Bi  Bi1  1  0.29  0.35  0.56  1.0

data_LaReBi2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.95
_cell_length_b   4.69
_cell_length_c   5.89
_cell_angle_alpha   90.0
_cell_angle_beta   100.6
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaReBi2
_chemical_formula_sum   'La1 Re1 Bi2'
_cell_volume   107.45
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.0  0.0  1.0
  Re  Re1  1  0.43  0.0  0.9  1.0
  Bi  Bi2  1  0.29  0.35  0.56  1.0
  Bi  Bi3  1  0.58  0.35  0.23  1.0

La Re Bi Bi
La Re Bi Bi 0 1 - o - 0 1 o o - 0 2 o o o 0 2 - o o 1 2 o o + 1 3 o o o 2 3 o o o 
LaReBi2 crystallizes in the triclinic P1 space group. La(1) is bonded in a 2-coordinate geometry to two equivalent Re(1) and four equivalent Bi(1) atoms. There is one shorter (1.92 Å) and one longer (2.21 Å) La(1)-Re(1) bond length. There are a spread of La(1)-Bi(1) bond distances ranging from 2.85-3.91 Å. Re(1) is bonded in a 2-coordinate geometry to two equivalent La(1), one Bi(2), and two equivalent Bi(1) atoms. The Re(1)-Bi(2) bond length is 2.53 Å. There is one shorter (2.53 Å) and one longer (3.63 Å) Re(1)-Bi(1) bond length. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 8-coordinate geometry to four equivalent La(1), two equivalent Re(1), and two equivalent Bi(2) atoms. There is one shorter (2.45 Å) and one longer (3.13 Å) Bi(1)-Bi(2) bond length. In the second Bi site, Bi(2) is bonded in a 2-coordinate geometry to one Re(1) and two equivalent Bi(1) atoms.