data_MnP2Pt
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.96
_cell_length_b   2.96
_cell_length_c   5.97
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnP2Pt
_chemical_formula_sum   'Mn1 P2 Pt1'
_cell_volume   52.49
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.0  0.0  0.0  1.0
  P  P1  1  0.48  0.48  0.29  1.0
  P  P2  1  0.48  0.48  0.69  1.0
  Pt  Pt3  1  0.0  0.0  0.99  1.0

data_MnP2Pt
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.19
_cell_length_b   4.19
_cell_length_c   5.97
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   MnP2Pt
_chemical_formula_sum   'Mn2 P4 Pt2'
_cell_volume   104.98
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  2  0.0  0.0  0.0  1.0
  P  P1  2  0.48  0.0  0.29  1.0
  P  P2  2  0.48  0.0  0.69  1.0
  Pt  Pt3  2  0.0  0.0  0.99  1.0

Mn P P Pt
Mn P P Pt 0 3 o o - 0 1 o o o 0 1 o - o 0 1 - o o 0 1 - - o 0 2 o o - 0 2 o - - 0 2 - o - 0 2 - - - 1 3 o o - 1 3 o + - 1 3 + o - 1 3 + + - 1 1 + o o 1 1 o + o 1 2 o o o 2 3 o o o 2 3 o + o 2 3 + o o 2 3 + + o 2 2 + o o 2 2 o + o 
MnPtP2 crystallizes in the monoclinic Cm space group. Mn(1) is bonded in a single-bond geometry to one Pt(1) and four equivalent P(1) atoms. The Mn(1)-Pt(1) bond length is 0.07 Å. There are a spread of Mn(1)-P(1) bond distances ranging from 2.66-2.78 Å. Pt(1) is bonded in a single-bond geometry to one Mn(1) and four equivalent P(2) atoms. There are a spread of Pt(1)-P(2) bond distances ranging from 2.71-2.82 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 5-coordinate geometry to four equivalent Mn(1) and one P(2) atom. The P(1)-P(2) bond length is 2.36 Å. In the second P site, P(2) is bonded in a 5-coordinate geometry to four equivalent Pt(1) and one P(1) atom.