data_AgOs2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.42
_cell_length_b   9.42
_cell_length_c   9.42
_cell_angle_alpha   16.7
_cell_angle_beta   16.7
_cell_angle_gamma   16.7
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgOs2Rh
_chemical_formula_sum   'Ag1 Os2 Rh1'
_cell_volume   60.13
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.0  0.0  0.92  1.0
  Os  Os1  1  0.0  0.0  0.09  1.0
  Os  Os2  1  0.0  0.0  0.75  1.0
  Rh  Rh3  1  0.0  0.0  0.0  1.0

data_AgOs2Rh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.74
_cell_length_b   2.73
_cell_length_c   9.42
_cell_angle_alpha   90.0
_cell_angle_beta   99.65
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   AgOs2Rh
_chemical_formula_sum   'Ag2 Os4 Rh2'
_cell_volume   120.25
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  2  0.0  0.0  0.08  1.0
  Os  Os1  2  -0.0  0.0  0.91  1.0
  Os  Os2  2  -0.0  0.0  0.25  1.0
  Rh  Rh3  2  0.0  0.0  0.0  1.0

Ag Os Os Rh
Ag Os Os Rh 0 3 o o + 0 2 o o o 1 3 o o o 
Os2RhAg is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Os2RhAg clusters. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a single-bond geometry to one Rh(1) atom. The Os(1)-Rh(1) bond length is 0.89 Å. In the second Os site, Os(2) is bonded in a single-bond geometry to one Ag(1) atom. The Os(2)-Ag(1) bond length is 1.60 Å. Rh(1) is bonded in a linear geometry to one Os(1) and one Ag(1) atom. The Rh(1)-Ag(1) bond length is 0.71 Å. Ag(1) is bonded in a distorted single-bond geometry to one Os(2) and one Rh(1) atom.