data_TiP2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.82
_cell_length_b   2.82
_cell_length_c   8.02
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   93.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiP2Rh
_chemical_formula_sum   'Ti1 P2 Rh1'
_cell_volume   63.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti3  1  0.0  0.0  0.06  1.0
  P  P0  1  0.93  0.0  0.33  1.0
  P  P1  1  0.0  0.0  0.52  1.0
  Rh  Rh2  1  0.93  0.0  0.12  1.0

data_TiP2Rh
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.82
_cell_length_b   2.82
_cell_length_c   8.02
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   93.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiP2Rh
_chemical_formula_sum   'Ti1 P2 Rh1'
_cell_volume   63.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.0  0.0  0.06  1.0
  P  P1  1  0.0  0.0  0.52  1.0
  P  P2  1  0.93  0.0  0.33  1.0
  Rh  Rh3  1  0.93  0.0  0.12  1.0

Ti P P Rh
Ti P P Rh 0 3 - o o 1 3 o o o 1 2 + o o 
TiRhP2 is alpha Niobium phosphide-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one TiRhP2 cluster. Ti(1) is bonded in a single-bond geometry to one Rh(1) atom. The Ti(1)-Rh(1) bond length is 0.50 Å. Rh(1) is bonded in a single-bond geometry to one Ti(1) and one P(1) atom. The Rh(1)-P(1) bond length is 1.74 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a linear geometry to one Rh(1) and one P(2) atom. The P(1)-P(2) bond length is 1.49 Å. In the second P site, P(2) is bonded in a single-bond geometry to one P(1) atom.