data_V2SnSb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.74
_cell_length_b   4.74
_cell_length_c   3.24
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   95.1
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2SnSb
_chemical_formula_sum   'V2 Sn1 Sb1'
_cell_volume   72.45
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.6  0.75  0.62  1.0
  V  V3  1  0.6  0.25  0.62  1.0
  Sn  Sn1  1  0.0  0.0  0.0  1.0
  Sb  Sb0  1  0.2  0.0  0.0  1.0

data_V2SnSb
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.24
_cell_length_b   4.74
_cell_length_c   4.74
_cell_angle_alpha   95.1
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2SnSb
_chemical_formula_sum   'V2 Sn1 Sb1'
_cell_volume   72.45
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.62  0.6  0.25  1.0
  V  V1  1  0.62  0.6  0.75  1.0
  Sn  Sn2  1  0.0  0.0  0.0  1.0
  Sb  Sb3  1  0.0  0.2  0.0  1.0

V V Sn Sb
V V Sn Sb 0 3 o + + 0 1 o + o 0 1 o o o 0 2 + + + 1 3 o o + 1 2 + o + 2 3 o o o 
V2SnSb crystallizes in the triclinic P1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to two equivalent V(2), two equivalent Sn(1), and two equivalent Sb(1) atoms. There is one shorter (2.34 Å) and one longer (2.39 Å) V(1)-V(2) bond length. There is one shorter (2.48 Å) and one longer (2.95 Å) V(1)-Sn(1) bond length. There is one shorter (2.64 Å) and one longer (3.09 Å) V(1)-Sb(1) bond length. In the second V site, V(2) is bonded in a 6-coordinate geometry to two equivalent V(1), two equivalent Sn(1), and two equivalent Sb(1) atoms. There is one shorter (2.64 Å) and one longer (3.09 Å) V(2)-Sn(1) bond length. There is one shorter (2.48 Å) and one longer (2.95 Å) V(2)-Sb(1) bond length. Sn(1) is bonded in a distorted single-bond geometry to two equivalent V(1), two equivalent V(2), and one Sb(1) atom. The Sn(1)-Sb(1) bond length is 0.93 Å. Sb(1) is bonded in a 1-coordinate geometry to two equivalent V(1), two equivalent V(2), and one Sn(1) atom.