data_VRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.39
_cell_length_b   7.08
_cell_length_c   2.73
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VRh2
_chemical_formula_sum   'V2 Rh4'
_cell_volume   84.87
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V4  1  0.0  0.0  0.0  1.0
  V  V5  1  0.2  0.54  0.37  1.0
  Rh  Rh0  1  0.42  0.32  0.0  1.0
  Rh  Rh1  1  0.77  0.86  0.37  1.0
  Rh  Rh2  1  0.62  0.22  0.37  1.0
  Rh  Rh3  1  0.97  0.76  0.0  1.0

data_VRh2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.73
_cell_length_b   4.39
_cell_length_c   7.08
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VRh2
_chemical_formula_sum   'V2 Rh4'
_cell_volume   84.87
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  V  V1  1  0.37  0.2  0.54  1.0
  Rh  Rh2  1  -0.0  0.42  0.32  1.0
  Rh  Rh3  1  -0.0  0.97  0.76  1.0
  Rh  Rh4  1  0.37  0.62  0.22  1.0
  Rh  Rh5  1  0.37  0.77  0.86  1.0

V V Rh Rh Rh Rh
V V Rh Rh Rh Rh 0 3 - - o 0 5 - - o 1 5 - o o 1 5 - o + 1 2 o o o 1 2 o o + 2 4 o o o 3 5 o o o 
VRh2 crystallizes in the triclinic P1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 2-coordinate geometry to one Rh(1), one Rh(2), one Rh(3), and one Rh(4) atom. The V(1)-Rh(1) bond length is 2.92 Å. The V(1)-Rh(2) bond length is 1.73 Å. The V(1)-Rh(3) bond length is 2.49 Å. The V(1)-Rh(4) bond length is 1.71 Å. In the second V site, V(2) is bonded in a 2-coordinate geometry to two equivalent Rh(1) and two equivalent Rh(4) atoms. There is one shorter (2.10 Å) and one longer (2.53 Å) V(2)-Rh(1) bond length. There is one shorter (2.10 Å) and one longer (2.53 Å) V(2)-Rh(4) bond length. There are four inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 5-coordinate geometry to one V(1), two equivalent V(2), and two equivalent Rh(3) atoms. There is one shorter (1.49 Å) and one longer (2.06 Å) Rh(1)-Rh(3) bond length. In the second Rh site, Rh(2) is bonded in a 1-coordinate geometry to one V(1) and two equivalent Rh(4) atoms. There is one shorter (1.49 Å) and one longer (2.06 Å) Rh(2)-Rh(4) bond length. In the third Rh site, Rh(3) is bonded in a 2-coordinate geometry to one V(1) and two equivalent Rh(1) atoms. In the fourth Rh site, Rh(4) is bonded in a 5-coordinate geometry to one V(1), two equivalent V(2), and two equivalent Rh(2) atoms.