data_In(CoP)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.11
_cell_length_b   7.11
_cell_length_c   2.84
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In(CoP)2
_chemical_formula_sum   'In2 Co4 P4'
_cell_volume   143.54
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In4  1  0.0  0.0  0.0  1.0
  In  In5  1  0.56  0.56  0.0  1.0
  Co  Co0  1  0.66  0.22  0.0  1.0
  Co  Co1  1  0.45  0.89  0.0  1.0
  Co  Co2  1  0.89  0.66  0.0  1.0
  Co  Co3  1  0.22  0.45  0.0  1.0
  P  P6  1  0.94  0.5  0.42  1.0
  P  P7  1  0.17  0.62  0.42  1.0
  P  P8  1  0.62  0.94  0.42  1.0
  P  P9  1  0.5  0.17  0.42  1.0

data_In(CoP)2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.84
_cell_length_b   7.11
_cell_length_c   7.11
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In(CoP)2
_chemical_formula_sum   'In2 Co4 P4'
_cell_volume   143.54
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.0  0.56  0.56  1.0
  Co  Co2  1  0.0  0.22  0.45  1.0
  Co  Co3  1  0.0  0.45  0.89  1.0
  Co  Co4  1  0.0  0.66  0.22  1.0
  Co  Co5  1  0.0  0.89  0.66  1.0
  P  P6  1  0.42  0.17  0.62  1.0
  P  P7  1  0.42  0.5  0.17  1.0
  P  P8  1  0.42  0.62  0.94  1.0
  P  P9  1  0.42  0.94  0.5  1.0

In In Co Co Co Co P P P P
In In Co Co Co Co P P P P 0 8 - - - 0 8 - - o 0 4 - - o 0 2 - o o 0 7 o - o 0 3 o - o 0 0 o o + 1 9 o o o 1 5 o o o 1 7 o o o 1 3 o o o 1 6 o o o 1 2 o o o 1 1 o o + 1 8 o o o 1 4 o o o 2 9 o o - 2 9 o o o 3 8 o o - 3 8 o o o 4 6 o o - 4 6 o o o 5 7 o o - 5 7 o o o 6 7 + o o 8 9 o + o 
In(CoP)2 crystallizes in the triclinic P1 space group. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a 2-coordinate geometry to one In(1), one In(2), and two equivalent P(4) atoms. The Co(1)-In(1) bond length is 2.86 Å. The Co(1)-In(2) bond length is 2.51 Å. There is one shorter (1.73 Å) and one longer (2.07 Å) Co(1)-P(4) bond length. In the second Co site, Co(2) is bonded in a 2-coordinate geometry to one In(1), one In(2), and two equivalent P(3) atoms. The Co(2)-In(1) bond length is 3.28 Å. The Co(2)-In(2) bond length is 2.51 Å. There is one shorter (1.73 Å) and one longer (2.07 Å) Co(2)-P(3) bond length. In the third Co site, Co(3) is bonded in a 2-coordinate geometry to one In(1), one In(2), and two equivalent P(1) atoms. The Co(3)-In(1) bond length is 2.51 Å. The Co(3)-In(2) bond length is 2.51 Å. There is one shorter (1.73 Å) and one longer (2.07 Å) Co(3)-P(1) bond length. In the fourth Co site, Co(4) is bonded in a 2-coordinate geometry to one In(2) and two equivalent P(2) atoms. The Co(4)-In(2) bond length is 2.51 Å. There is one shorter (1.73 Å) and one longer (2.07 Å) Co(4)-P(2) bond length. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 6-coordinate geometry to one Co(1), one Co(2), one Co(3), two equivalent In(1), and one P(3) atom. Both In(1)-In(1) bond lengths are 2.84 Å. The In(1)-P(3) bond length is 3.00 Å. In the second In site, In(2) is bonded in a distorted rectangular see-saw-like geometry to one Co(1), one Co(2), one Co(3), and one Co(4) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded in a 2-coordinate geometry to two equivalent Co(3) atoms. In the second P site, P(2) is bonded in a 2-coordinate geometry to two equivalent Co(4) atoms. In the third P site, P(3) is bonded in a 2-coordinate geometry to two equivalent Co(2) and one In(1) atom. In the fourth P site, P(4) is bonded in a 2-coordinate geometry to two equivalent Co(1) atoms.