data_LaInPb2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.95
_cell_length_b   4.95
_cell_length_c   4.8
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaInPb2
_chemical_formula_sum   'La1 In1 Pb2'
_cell_volume   117.58
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La1  1  0.47  0.47  0.0  1.0
  In  In0  1  0.0  0.0  0.0  1.0
  Pb  Pb2  1  0.47  0.0  0.4  1.0
  Pb  Pb3  1  0.0  0.47  0.4  1.0

data_LaInPb2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   7.0
_cell_length_b   7.0
_cell_length_c   4.8
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LaInPb2
_chemical_formula_sum   'La2 In2 Pb4'
_cell_volume   235.15
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  2  0.47  0.0  0.0  1.0
  In  In1  2  0.0  0.0  0.0  1.0
  Pb  Pb2  4  0.24  0.24  0.4  1.0

La In Pb Pb
La In Pb Pb 0 1 o o o 0 1 o + o 0 1 + o o 0 1 + + o 0 3 o o - 0 3 o o o 0 3 + o - 0 3 + o o 0 2 o o - 0 2 o o o 0 2 o + - 0 2 o + o 1 2 - o - 1 2 - o o 1 2 o o - 1 2 o o o 1 3 o - - 1 3 o - o 1 3 o o - 1 3 o o o 2 3 o - o 2 3 o o o 2 3 + - o 2 3 + o o 
LaInPb2 crystallizes in the monoclinic Cm space group. La(1) is bonded to four equivalent In(1) and eight equivalent Pb(1) atoms to form a mixture of distorted face and corner-sharing LaIn4Pb8 cuboctahedra. There are a spread of La(1)-In(1) bond distances ranging from 3.31-3.68 Å. There are a spread of La(1)-Pb(1) bond distances ranging from 3.04-3.88 Å. In(1) is bonded in a 8-coordinate geometry to four equivalent La(1) and four equivalent Pb(1) atoms. There are two shorter (3.04 Å) and two longer (3.24 Å) In(1)-Pb(1) bond lengths. Pb(1) is bonded in a 6-coordinate geometry to four equivalent La(1) and two equivalent In(1) atoms.