data_TlSbPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.86
_cell_length_b   4.86
_cell_length_c   4.86
_cell_angle_alpha   121.51
_cell_angle_beta   121.51
_cell_angle_gamma   87.4
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlSbPd2
_chemical_formula_sum   'Tl1 Sb1 Pd2'
_cell_volume   79.18
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl3  1  0.0  0.0  0.51  1.0
  Sb  Sb2  1  0.0  0.0  0.0  1.0
  Pd  Pd0  1  0.0  0.37  0.76  1.0
  Pd  Pd1  1  0.37  0.0  0.76  1.0

data_TlSbPd2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.71
_cell_length_b   6.71
_cell_length_c   4.86
_cell_angle_alpha   90.0
_cell_angle_beta   133.7
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TlSbPd2
_chemical_formula_sum   'Tl2 Sb2 Pd4'
_cell_volume   158.35
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  2  0.49  0.0  0.49  1.0
  Sb  Sb1  2  0.0  0.0  0.0  1.0
  Pd  Pd2  4  0.43  0.19  0.62  1.0

Tl Sb Pd Pd
Tl Sb Pd Pd 0 2 o o o 0 3 o o o 0 1 o o + 0 1 o o o 1 2 o o - 1 2 o - - 1 3 - o - 1 3 o o - 
Pd2TlSb crystallizes in the monoclinic Cm space group. Pd(1) is bonded in a single-bond geometry to one Tl(1) and two equivalent Sb(1) atoms. The Pd(1)-Tl(1) bond length is 1.57 Å. There is one shorter (2.63 Å) and one longer (2.64 Å) Pd(1)-Sb(1) bond length. Tl(1) is bonded in a distorted water-like geometry to two equivalent Pd(1) and two equivalent Sb(1) atoms. There is one shorter (2.37 Å) and one longer (2.49 Å) Tl(1)-Sb(1) bond length. Sb(1) is bonded in a 6-coordinate geometry to four equivalent Pd(1) and two equivalent Tl(1) atoms.