data_KInCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.84
_cell_length_b   3.84
_cell_length_c   7.75
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KInCl2
_chemical_formula_sum   'K1 In1 Cl2'
_cell_volume   114.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K3  1  0.0  0.0  0.0  1.0
  In  In2  1  0.0  0.0  0.88  1.0
  Cl  Cl0  1  0.92  0.92  0.9  1.0
  Cl  Cl1  1  0.92  0.92  0.85  1.0

data_KInCl2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.43
_cell_length_b   5.43
_cell_length_c   7.75
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   KInCl2
_chemical_formula_sum   'K2 In2 Cl4'
_cell_volume   228.13
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  2  0.0  0.0  0.0  1.0
  In  In1  2  0.0  0.0  0.88  1.0
  Cl  Cl2  2  0.42  0.5  0.85  1.0
  Cl  Cl3  2  0.42  0.5  0.9  1.0

K In Cl Cl
K In Cl Cl 0 2 - - - 0 1 o o - 1 3 - - o 1 2 - - o 2 3 o o o 
KInCl2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two KInCl2 clusters. K(1) is bonded in a 2-coordinate geometry to one In(1) and one Cl(1) atom. The K(1)-In(1) bond length is 0.96 Å. The K(1)-Cl(1) bond length is 0.92 Å. In(1) is bonded in a single-bond geometry to one K(1), one Cl(1), and one Cl(2) atom. The In(1)-Cl(1) bond length is 0.47 Å. The In(1)-Cl(2) bond length is 0.47 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one K(1), one In(1), and one Cl(2) atom. The Cl(1)-Cl(2) bond length is 0.32 Å. In the second Cl site, Cl(2) is bonded in a 2-coordinate geometry to one In(1) and one Cl(1) atom.