data_TeOsRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.1
_cell_length_b   9.1
_cell_length_c   9.1
_cell_angle_alpha   18.2
_cell_angle_beta   18.2
_cell_angle_gamma   18.2
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TeOsRh2
_chemical_formula_sum   'Te1 Os1 Rh2'
_cell_volume   64.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te3  1  0.0  0.0  0.43  1.0
  Os  Os0  1  0.0  0.0  0.73  1.0
  Rh  Rh1  1  0.0  0.0  0.83  1.0
  Rh  Rh2  1  0.0  0.0  0.13  1.0

data_TeOsRh2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.99
_cell_length_b   2.88
_cell_length_c   9.1
_cell_angle_alpha   90.0
_cell_angle_beta   100.52
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TeOsRh2
_chemical_formula_sum   'Te2 Os2 Rh4'
_cell_volume   128.43
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  2  0.0  0.0  0.57  1.0
  Os  Os1  2  0.0  0.0  0.27  1.0
  Rh  Rh2  2  0.0  0.0  0.17  1.0
  Rh  Rh3  2  0.0  0.0  0.87  1.0

Te Os Rh Rh
Te Os Rh Rh 0 0 o + - 0 0 + - o 0 0 + o - 0 3 o o o 0 1 o o o 1 2 o o o 2 3 o o + 3 3 o + - 3 3 + - o 3 3 + o - 
OsRh2Te crystallizes in the monoclinic Cm space group. Os(1) is bonded in a single-bond geometry to one Rh(1) and one Te(1) atom. The Os(1)-Rh(1) bond length is 0.92 Å. The Os(1)-Te(1) bond length is 2.75 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a single-bond geometry to one Os(1) and one Rh(2) atom. The Rh(1)-Rh(2) bond length is 2.72 Å. In the second Rh site, Rh(2) is bonded to one Rh(1), six equivalent Rh(2), and one Te(1) atom to form distorted RhTeRh7 hexagonal bipyramids that share corners with six equivalent Rh(2)TeRh7 hexagonal bipyramids, edges with six equivalent Te(1)Te6OsRh hexagonal bipyramids, and edges with twelve equivalent Rh(2)TeRh7 hexagonal bipyramids. All Rh(2)-Rh(2) bond lengths are 2.88 Å. The Rh(2)-Te(1) bond length is 2.71 Å. Te(1) is bonded to one Os(1), one Rh(2), and six equivalent Te(1) atoms to form distorted TeTe6OsRh hexagonal bipyramids that share corners with six equivalent Te(1)Te6OsRh hexagonal bipyramids, edges with six equivalent Rh(2)TeRh7 hexagonal bipyramids, and edges with twelve equivalent Te(1)Te6OsRh hexagonal bipyramids. All Te(1)-Te(1) bond lengths are 2.88 Å.