data_Mo3PPt2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.2
_cell_length_b   7.2
_cell_length_c   7.2
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mo3PPt2
_chemical_formula_sum   'Mo12 P4 Pt8'
_cell_volume   373.87
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.41  0.21  0.5  1.0
  Mo  Mo1  1  0.2  1.0  0.9  1.0
  Mo  Mo2  1  0.8  0.61  0.3  1.0
  Mo  Mo3  1  0.01  0.6  0.7  1.0
  Mo  Mo4  1  0.5  0.41  0.21  1.0
  Mo  Mo5  1  0.9  0.2  1.0  1.0
  Mo  Mo6  1  0.3  0.8  0.61  1.0
  Mo  Mo7  1  0.7  0.01  0.6  1.0
  Mo  Mo8  1  0.21  0.5  0.41  1.0
  Mo  Mo9  1  1.0  0.9  0.2  1.0
  Mo  Mo10  1  0.61  0.3  0.8  1.0
  Mo  Mo11  1  0.6  0.7  0.01  1.0
  P  P12  1  0.7  0.7  0.7  1.0
  P  P13  1  0.9  0.5  0.3  1.0
  P  P14  1  0.5  0.3  0.9  1.0
  P  P15  1  0.3  0.9  0.5  1.0
  Pt  Pt16  1  0.07  0.07  0.07  1.0
  Pt  Pt17  1  0.73  0.13  0.47  1.0
  Pt  Pt18  1  0.13  0.47  0.73  1.0
  Pt  Pt19  1  0.47  0.73  0.13  1.0
  Pt  Pt20  1  0.27  0.87  0.93  1.0
  Pt  Pt21  1  0.33  0.33  0.33  1.0
  Pt  Pt22  1  0.87  0.93  0.27  1.0
  Pt  Pt23  1  0.93  0.27  0.87  1.0

data_Mo3PPt2
_symmetry_space_group_name_H-M   R3
_cell_length_a   10.19
_cell_length_b   10.19
_cell_length_c   12.48
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   146
_chemical_formula_structural   Mo3PPt2
_chemical_formula_sum   'Mo36 P12 Pt24'
_cell_volume   1121.62
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  'x+1/3, y+2/3, z+2/3'
  5  '-y+1/3, x-y+2/3, z+2/3'
  6  '-x+y+1/3, -x+2/3, z+2/3'
  7  'x+2/3, y+1/3, z+1/3'
  8  '-y+2/3, x-y+1/3, z+1/3'
  9  '-x+y+2/3, -x+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  9  0.03  0.87  0.37  1.0
  Mo  Mo1  9  0.04  0.77  0.57  1.0
  Mo  Mo2  9  0.16  0.43  0.44  1.0
  Mo  Mo3  9  0.16  0.13  0.03  1.0
  P  P4  9  0.07  0.73  0.24  1.0
  P  P5  3  0.0  0.0  0.7  1.0
  Pt  Pt6  9  0.02  0.38  0.11  1.0
  Pt  Pt7  9  0.18  0.42  0.69  1.0
  Pt  Pt8  3  0.0  0.0  0.07  1.0
  Pt  Pt9  3  0.0  0.0  0.33  1.0

Mo Mo Mo Mo Mo Mo Mo Mo Mo Mo Mo Mo P P P P Pt Pt Pt Pt Pt Pt Pt Pt
Mo Mo Mo Mo Mo Mo Mo Mo Mo Mo Mo Mo P P P P Pt Pt Pt Pt Pt Pt Pt Pt 0 21 o o o 1 20 o o o 1 16 o + + 2 13 o o o 3 18 o o o 3 12 - o o 4 21 o o o 5 23 o o o 5 16 + o + 6 15 o o o 7 17 o o o 7 12 o - o 8 21 o o o 9 22 o o o 9 16 + + o 10 14 o o o 11 19 o o o 11 12 o o - 
PtMo3Mo3Pt4Mo6Pt3P4 is Indium-like structured and crystallizes in the trigonal R3 space group. The structure is zero-dimensional and consists of three Mo3Pt4 clusters, three Mo6Pt3P4 clusters, and three PtMo3 clusters. In each Mo3Pt4 cluster, Mo(2) is bonded in a distorted bent 120 degrees geometry to one Pt(1) and one Pt(3) atom. The Mo(2)-Pt(1) bond length is 1.62 Å. The Mo(2)-Pt(3) bond length is 1.07 Å. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a trigonal non-coplanar geometry to three equivalent Mo(2) atoms. In the second Pt site, Pt(3) is bonded in a single-bond geometry to one Mo(2) atom. In each Mo6Pt3P4 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(3) is bonded in a distorted single-bond geometry to one P(1) and one P(2) atom. The Mo(3)-P(1) bond length is 3.03 Å. The Mo(3)-P(2) bond length is 1.05 Å. In the second Mo site, Mo(4) is bonded in a distorted single-bond geometry to one Pt(2) and one P(1) atom. The Mo(4)-Pt(2) bond length is 1.31 Å. The Mo(4)-P(1) bond length is 2.33 Å. Pt(2) is bonded in a single-bond geometry to one Mo(4) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to three equivalent Mo(3) and three equivalent Mo(4) atoms. In the second P site, P(2) is bonded in a distorted single-bond geometry to one Mo(3) atom. In each PtMo3 cluster, Mo(1) is bonded in a distorted single-bond geometry to one Pt(4) atom. The Mo(1)-Pt(4) bond length is 1.62 Å. Pt(4) is bonded in a trigonal non-coplanar geometry to three equivalent Mo(1) atoms.