data_VOs2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.68
_cell_length_b   2.68
_cell_length_c   8.81
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   115.28
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VOs2Rh
_chemical_formula_sum   'V1 Os2 Rh1'
_cell_volume   57.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Os  Os0  1  0.43  0.0  0.08  1.0
  Os  Os1  1  0.43  0.0  0.73  1.0
  Rh  Rh2  1  0.0  0.0  0.4  1.0

data_VOs2Rh
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.68
_cell_length_b   2.68
_cell_length_c   8.81
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   115.28
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VOs2Rh
_chemical_formula_sum   'V1 Os2 Rh1'
_cell_volume   57.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  Os  Os1  1  0.43  0.0  0.08  1.0
  Os  Os2  1  0.43  0.0  0.73  1.0
  Rh  Rh3  1  0.0  0.0  0.4  1.0

V Os Os Rh
V Os Os Rh 0 1 o o o 0 2 o o - 0 2 - o - 1 2 o o - 1 3 + o o 1 3 o o o 2 2 + + o 2 2 o + o 2 2 + o o 2 3 o o o 2 3 + o o 3 3 + + o 3 3 o + o 3 3 + o o 
VOs2Rh crystallizes in the triclinic P1 space group. V(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Os(1) and two equivalent Os(2) atoms. There is one shorter (1.35 Å) and one longer (1.66 Å) V(1)-Os(1) bond length. There is one shorter (2.66 Å) and one longer (2.83 Å) V(1)-Os(2) bond length. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a distorted bent 120 degrees geometry to two equivalent V(1) and two equivalent Rh(1) atoms. There is one shorter (3.09 Å) and one longer (3.24 Å) Os(1)-Rh(1) bond length. In the second Os site, Os(2) is bonded in a 2-coordinate geometry to two equivalent V(1) and two equivalent Rh(1) atoms. There is one shorter (3.09 Å) and one longer (3.24 Å) Os(2)-Rh(1) bond length. Rh(1) is bonded in a distorted q6 geometry to two equivalent Os(1), two equivalent Os(2), and six equivalent Rh(1) atoms. There are four shorter (2.68 Å) and two longer (2.87 Å) Rh(1)-Rh(1) bond lengths.