data_ZnP2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.37
_cell_length_b   4.94
_cell_length_c   4.94
_cell_angle_alpha   62.93
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnP2Cl
_chemical_formula_sum   'Zn1 P2 Cl1'
_cell_volume   73.28
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.69  0.0  0.13  1.0
  P  P1  1  0.69  0.0  0.46  1.0
  P  P2  1  0.0  0.0  0.95  1.0
  Cl  Cl0  1  0.0  0.0  0.15  1.0

data_ZnP2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.37
_cell_length_b   4.94
_cell_length_c   4.94
_cell_angle_alpha   117.07
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnP2Cl
_chemical_formula_sum   'Zn1 P2 Cl1'
_cell_volume   73.28
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.31  0.0  0.87  1.0
  P  P1  1  0.0  0.0  0.05  1.0
  P  P2  1  0.31  0.0  0.54  1.0
  Cl  Cl3  1  0.0  0.0  0.85  1.0

Zn P P Cl
Zn P P Cl 0 3 + o o 0 1 o o o 1 3 + o o 2 3 o o + 
ZnP2Cl is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ZnP2Cl cluster. Zn(1) is bonded in a distorted single-bond geometry to one P(1) and one Cl(1) atom. The Zn(1)-P(1) bond length is 1.66 Å. The Zn(1)-Cl(1) bond length is 1.06 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 2-coordinate geometry to one Zn(1) and one Cl(1) atom. The P(1)-Cl(1) bond length is 1.88 Å. In the second P site, P(2) is bonded in a distorted single-bond geometry to one Cl(1) atom. The P(2)-Cl(1) bond length is 1.00 Å. Cl(1) is bonded in a distorted L-shaped geometry to one Zn(1), one P(1), and one P(2) atom.