data_InBOs2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.82
_cell_length_b   2.82
_cell_length_c   6.93
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InBOs2
_chemical_formula_sum   'In1 B1 Os2'
_cell_volume   55.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In1  1  0.0  0.0  0.46  1.0
  B  B0  1  0.0  0.0  0.0  1.0
  Os  Os2  1  0.41  0.41  0.66  1.0
  Os  Os3  1  0.41  0.41  0.26  1.0

data_InBOs2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.99
_cell_length_b   3.99
_cell_length_c   6.93
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   InBOs2
_chemical_formula_sum   'In2 B2 Os4'
_cell_volume   110.47
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  0.0  0.0  0.46  1.0
  B  B1  2  0.0  0.0  0.0  1.0
  Os  Os2  2  0.41  0.0  0.26  1.0
  Os  Os3  2  0.41  0.0  0.66  1.0

In B Os Os
In B Os Os 0 3 - - o 0 3 - o o 0 3 o - o 0 3 o o o 0 2 - - o 0 2 - o o 0 2 o - o 0 2 o o o 0 1 o o o 1 3 - - o 1 3 - o o 1 3 o - o 1 3 o o o 1 2 - o - 1 2 o - - 1 2 o o - 1 1 + o o 1 1 o + o 2 2 + o o 2 2 o + o 2 3 o o o 3 3 + o o 3 3 o + o 
Os2InB crystallizes in the monoclinic Cm space group. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 3-coordinate geometry to four equivalent In(1) and one B(1) atom. There are a spread of Os(1)-In(1) bond distances ranging from 2.16-2.73 Å. The Os(1)-B(1) bond length is 2.85 Å. In the second Os site, Os(2) is bonded in a 7-coordinate geometry to four equivalent In(1) and three equivalent B(1) atoms. There are a spread of Os(2)-In(1) bond distances ranging from 2.16-2.73 Å. There is one shorter (2.45 Å) and two longer (2.72 Å) Os(2)-B(1) bond lengths. In(1) is bonded in a 8-coordinate geometry to four equivalent Os(1) and four equivalent Os(2) atoms. B(1) is bonded in a 4-coordinate geometry to one Os(1) and three equivalent Os(2) atoms.