data_ReRhCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.6
_cell_length_b   4.6
_cell_length_c   2.94
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   100.3
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ReRhCl2
_chemical_formula_sum   'Re1 Rh1 Cl2'
_cell_volume   61.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re2  1  0.95  0.0  0.0  1.0
  Rh  Rh3  1  0.0  0.0  0.0  1.0
  Cl  Cl0  1  0.47  0.77  0.47  1.0
  Cl  Cl1  1  0.47  0.23  0.47  1.0

data_ReRhCl2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.94
_cell_length_b   4.6
_cell_length_c   4.6
_cell_angle_alpha   100.3
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ReRhCl2
_chemical_formula_sum   'Re1 Rh1 Cl2'
_cell_volume   61.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.0  0.95  0.0  1.0
  Rh  Rh1  1  0.0  0.0  0.0  1.0
  Cl  Cl2  1  0.47  0.47  0.23  1.0
  Cl  Cl3  1  0.47  0.47  0.77  1.0

Re Rh Cl Cl
Re Rh Cl Cl 0 1 + o o 0 2 o - o 0 2 o - - 0 3 + o o 0 3 + o - 0 3 o o o 1 2 o - o 1 2 - - o 1 2 - - - 1 3 o o o 1 3 o o - 2 3 o + o 2 3 o o o 2 2 o o + 3 3 o o + 
ReRhCl2 crystallizes in the triclinic P1 space group. Re(1) is bonded in a single-bond geometry to one Rh(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. The Re(1)-Rh(1) bond length is 0.24 Å. There is one shorter (2.64 Å) and one longer (2.74 Å) Re(1)-Cl(1) bond length. There is one shorter (2.94 Å) and one longer (3.03 Å) Re(1)-Cl(2) bond length. Rh(1) is bonded in a single-bond geometry to one Re(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. There is one shorter (2.94 Å) and one longer (3.03 Å) Rh(1)-Cl(1) bond length. There is one shorter (2.64 Å) and one longer (2.74 Å) Rh(1)-Cl(2) bond length. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 6-coordinate geometry to two equivalent Re(1), two equivalent Rh(1), and two equivalent Cl(2) atoms. There is one shorter (2.16 Å) and one longer (2.44 Å) Cl(1)-Cl(2) bond length. In the second Cl site, Cl(2) is bonded in a 6-coordinate geometry to two equivalent Re(1), two equivalent Rh(1), and two equivalent Cl(1) atoms.