data_InTe2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.32
_cell_length_b   3.32
_cell_length_c   9.32
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InTe2W
_chemical_formula_sum   'In1 Te2 W1'
_cell_volume   102.86
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.0  0.0  0.0  1.0
  Te  Te1  1  0.66  0.66  1.0  1.0
  Te  Te2  1  0.66  0.66  0.32  1.0
  W  W3  1  0.0  0.0  0.66  1.0

data_InTe2W
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.7
_cell_length_b   4.7
_cell_length_c   9.32
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   InTe2W
_chemical_formula_sum   'In2 Te4 W2'
_cell_volume   205.71
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  0.0  0.0  0.0  1.0
  Te  Te1  2  0.16  0.5  0.32  1.0
  Te  Te2  2  0.16  0.5  1.0  1.0
  W  W3  2  0.0  0.0  0.66  1.0

In Te Te W
In Te Te W 0 1 - - - 0 2 o - o 0 2 - o o 0 2 - - o 0 3 o o - 1 2 o o + 1 3 + + o 2 2 + o o 2 2 o + o 2 3 + + o 3 3 + o o 3 3 o + o 
WInTe2 crystallizes in the monoclinic Cm space group. W(1) is bonded in a 7-coordinate geometry to four equivalent W(1), one In(1), one Te(1), and one Te(2) atom. All W(1)-W(1) bond lengths are 3.32 Å. The W(1)-In(1) bond length is 3.15 Å. The W(1)-Te(1) bond length is 3.53 Å. The W(1)-Te(2) bond length is 3.53 Å. In(1) is bonded in a 1-coordinate geometry to one W(1), one Te(1), and one Te(2) atom. The In(1)-Te(1) bond length is 1.59 Å. The In(1)-Te(2) bond length is 3.41 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 1-coordinate geometry to one W(1), one In(1), and one Te(2) atom. The Te(1)-Te(2) bond length is 3.02 Å. In the second Te site, Te(2) is bonded in a 7-coordinate geometry to one W(1), one In(1), one Te(1), and four equivalent Te(2) atoms. All Te(2)-Te(2) bond lengths are 3.32 Å.