data_Te7Rh6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.61
_cell_length_b   9.61
_cell_length_c   9.61
_cell_angle_alpha   38.81
_cell_angle_beta   38.81
_cell_angle_gamma   38.81
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Te7Rh6
_chemical_formula_sum   'Te7 Rh6'
_cell_volume   313.09
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te6  1  0.46  0.11  0.2  1.0
  Te  Te7  1  0.0  0.78  0.2  1.0
  Te  Te8  1  0.54  0.11  0.2  1.0
  Te  Te9  1  0.54  0.89  0.42  1.0
  Te  Te10  1  0.46  0.89  0.42  1.0
  Te  Te11  1  0.0  0.22  0.42  1.0
  Te  Te12  1  0.0  0.0  0.0  1.0
  Rh  Rh0  1  0.0  0.0  0.01  1.0
  Rh  Rh1  1  0.0  0.0  0.61  1.0
  Rh  Rh2  1  0.0  0.0  0.42  1.0
  Rh  Rh3  1  0.0  0.0  0.2  1.0
  Rh  Rh4  1  0.0  0.0  0.46  1.0
  Rh  Rh5  1  0.0  0.0  0.16  1.0

data_Te7Rh6
_symmetry_space_group_name_H-M   P1
_cell_length_a   6.38
_cell_length_b   6.38
_cell_length_c   9.61
_cell_angle_alpha   70.6
_cell_angle_beta   70.6
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Te7Rh6
_chemical_formula_sum   'Te7 Rh6'
_cell_volume   313.09
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.0  0.0  0.0  1.0
  Te  Te1  1  0.11  0.58  0.77  1.0
  Te  Te2  1  0.11  0.58  0.85  1.0
  Te  Te3  1  0.22  0.8  0.98  1.0
  Te  Te4  1  0.78  0.58  0.64  1.0
  Te  Te5  1  0.89  0.8  0.77  1.0
  Te  Te6  1  0.89  0.8  0.85  1.0
  Rh  Rh7  1  0.0  0.39  0.61  1.0
  Rh  Rh8  1  0.0  0.54  0.46  1.0
  Rh  Rh9  1  0.0  0.58  0.42  1.0
  Rh  Rh10  1  0.0  0.8  0.2  1.0
  Rh  Rh11  1  0.0  0.84  0.16  1.0
  Rh  Rh12  1  0.0  0.99  0.01  1.0

Te Te Te Te Te Te Te Rh Rh Rh Rh Rh Rh
Te Te Te Te Te Te Te Rh Rh Rh Rh Rh Rh 0 2 o o o 1 7 o + o 1 6 o + o 3 4 o o o 5 8 o o o 6 7 o o o 8 11 o o o 9 11 o o o 10 12 o o o 
Rh3Te5Rh3Te2 is beta oxygen structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Rh3Te2 cluster and one Rh3Te5 cluster. In the Rh3Te2 cluster, there are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted single-bond geometry to one Rh(6), one Te(2), and one Te(7) atom. The Rh(1)-Rh(6) bond length is 1.44 Å. The Rh(1)-Te(2) bond length is 1.34 Å. The Rh(1)-Te(7) bond length is 0.06 Å. In the second Rh site, Rh(4) is bonded in a distorted single-bond geometry to one Rh(6) atom. The Rh(4)-Rh(6) bond length is 0.41 Å. In the third Rh site, Rh(6) is bonded in a 3-coordinate geometry to one Rh(1), one Rh(4), and one Te(2) atom. The Rh(6)-Te(2) bond length is 1.82 Å. There are two inequivalent Te sites. In the first Te site, Te(2) is bonded in a 2-coordinate geometry to one Rh(1) and one Rh(6) atom. In the second Te site, Te(7) is bonded in a single-bond geometry to one Rh(1) atom. In the Rh3Te5 cluster, there are three inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a distorted single-bond geometry to one Rh(5), one Te(5), and one Te(6) atom. The Rh(2)-Rh(5) bond length is 1.44 Å. The Rh(2)-Te(5) bond length is 2.66 Å. The Rh(2)-Te(6) bond length is 1.34 Å. In the second Rh site, Rh(3) is bonded in a distorted single-bond geometry to one Rh(5) atom. The Rh(3)-Rh(5) bond length is 0.41 Å. In the third Rh site, Rh(5) is bonded in a 3-coordinate geometry to one Rh(2), one Rh(3), and one Te(6) atom. The Rh(5)-Te(6) bond length is 1.82 Å. There are five inequivalent Te sites. In the first Te site, Te(1) is bonded in a 2-coordinate geometry to one Te(3) and one Te(5) atom. The Te(1)-Te(3) bond length is 0.80 Å. The Te(1)-Te(5) bond length is 1.41 Å. In the second Te site, Te(3) is bonded in a distorted L-shaped geometry to one Te(1) and one Te(4) atom. The Te(3)-Te(4) bond length is 1.41 Å. In the third Te site, Te(4) is bonded in a 2-coordinate geometry to one Te(3) and one Te(5) atom. The Te(4)-Te(5) bond length is 0.80 Å. In the fourth Te site, Te(5) is bonded in a 3-coordinate geometry to one Rh(2), one Te(1), and one Te(4) atom. In the fifth Te site, Te(6) is bonded in a distorted single-bond geometry to one Rh(2) and one Rh(5) atom.