data_Ga2WCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.04
_cell_length_b   3.04
_cell_length_c   7.68
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ga2WCl
_chemical_formula_sum   'Ga2 W1 Cl1'
_cell_volume   71.08
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga1  1  0.52  0.52  0.18  1.0
  Ga  Ga2  1  0.52  0.52  0.49  1.0
  W  W3  1  0.0  0.0  0.84  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Ga2WCl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.3
_cell_length_b   4.3
_cell_length_c   7.68
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Ga2WCl
_chemical_formula_sum   'Ga4 W2 Cl2'
_cell_volume   142.17
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  2  0.02  0.5  0.18  1.0
  Ga  Ga1  2  0.02  0.5  0.49  1.0
  W  W2  2  0.0  0.0  0.84  1.0
  Cl  Cl3  2  0.0  0.0  0.0  1.0

Ga Ga W Cl
Ga Ga W Cl 0 3 o o o 0 3 o + o 0 3 + o o 0 3 + + o 0 1 o o o 1 1 + o o 1 1 o + o 2 3 o o + 
WGa2Cl crystallizes in the monoclinic Cm space group. W(1) is bonded in a single-bond geometry to four equivalent Ga(2) and one Cl(1) atom. There are a spread of W(1)-Ga(2) bond distances ranging from 3.36-3.47 Å. The W(1)-Cl(1) bond length is 1.24 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 4-coordinate geometry to one Ga(2) and four equivalent Cl(1) atoms. The Ga(1)-Ga(2) bond length is 2.38 Å. There are a spread of Ga(1)-Cl(1) bond distances ranging from 2.49-2.65 Å. In the second Ga site, Ga(2) is bonded in a 9-coordinate geometry to four equivalent W(1), one Ga(1), and four equivalent Ga(2) atoms. All Ga(2)-Ga(2) bond lengths are 3.04 Å. Cl(1) is bonded in a distorted single-bond geometry to one W(1) and four equivalent Ga(1) atoms.