data_ZnInP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.09
_cell_length_b   4.09
_cell_length_c   9.14
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnInP
_chemical_formula_sum   'Zn2 In2 P2'
_cell_volume   132.64
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn4  1  0.0  0.36  0.86  1.0
  Zn  Zn5  1  0.05  0.18  0.29  1.0
  In  In0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.0  0.0  0.57  1.0
  P  P2  1  0.0  0.36  0.29  1.0
  P  P3  1  0.05  0.18  0.86  1.0

data_ZnInP
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.09
_cell_length_b   4.09
_cell_length_c   9.14
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnInP
_chemical_formula_sum   'Zn2 In2 P2'
_cell_volume   132.64
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  -0.0  0.36  0.86  1.0
  Zn  Zn1  1  0.05  0.18  0.29  1.0
  In  In2  1  0.0  0.0  0.0  1.0
  In  In3  1  0.0  0.0  0.57  1.0
  P  P4  1  -0.0  0.36  0.29  1.0
  P  P5  1  0.05  0.18  0.86  1.0

Zn Zn In In P P
Zn Zn In In P P 0 5 o o o 0 3 o o o 1 4 o o o 1 3 o o o 2 5 o o - 3 4 o o o 3 5 o o o 
InZnP is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one InZnP cluster. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a single-bond geometry to one P(2) atom. The Zn(1)-P(2) bond length is 0.85 Å. In the second Zn site, Zn(2) is bonded in a single-bond geometry to one In(2) and one P(1) atom. The Zn(2)-In(2) bond length is 2.70 Å. The Zn(2)-P(1) bond length is 0.85 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a single-bond geometry to one P(2) atom. The In(1)-P(2) bond length is 1.47 Å. In the second In site, In(2) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one P(2) atom. The In(2)-P(2) bond length is 2.70 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a single-bond geometry to one Zn(2) atom. In the second P site, P(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1), one In(1), and one In(2) atom.