data_SbP2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.17
_cell_length_b   3.17
_cell_length_c   7.2
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   91.64
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SbP2Pd
_chemical_formula_sum   'Sb1 P2 Pd1'
_cell_volume   72.35
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb3  1  0.21  0.0  0.08  1.0
  P  P0  1  0.0  0.0  0.48  1.0
  P  P1  1  0.21  0.0  0.61  1.0
  Pd  Pd2  1  0.0  0.0  0.84  1.0

data_SbP2Pd
_symmetry_space_group_name_H-M   Pm
_cell_length_a   3.17
_cell_length_b   3.17
_cell_length_c   7.2
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   SbP2Pd
_chemical_formula_sum   'Sb1 P2 Pd1'
_cell_volume   72.38
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.21  0.0  0.08  1.0
  P  P1  1  0.0  0.0  0.48  1.0
  P  P2  1  0.21  0.0  0.61  1.0
  Pd  Pd3  1  0.0  0.0  0.84  1.0

Sb P P Pd
Sb P P Pd 0 3 o o - 1 2 o o o 2 3 o o o 
PdSbP2 crystallizes in the monoclinic Pm space group. The structure is zero-dimensional and consists of one PdSbP2 cluster. Pd(1) is bonded in a 2-coordinate geometry to one Sb(1) and one P(2) atom. The Pd(1)-Sb(1) bond length is 1.81 Å. The Pd(1)-P(2) bond length is 1.82 Å. Sb(1) is bonded in a distorted single-bond geometry to one Pd(1) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one P(2) atom. The P(1)-P(2) bond length is 1.10 Å. In the second P site, P(2) is bonded in a distorted bent 120 degrees geometry to one Pd(1) and one P(1) atom.