data_InW2Au
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.38
_cell_length_b   3.38
_cell_length_c   6.32
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InW2Au
_chemical_formula_sum   'In1 W2 Au1'
_cell_volume   72.33
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In1  1  0.0  0.0  0.7  1.0
  W  W2  1  0.69  0.69  0.23  1.0
  W  W3  1  0.0  0.0  0.39  1.0
  Au  Au0  1  0.69  0.69  0.15  1.0

data_InW2Au
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.78
_cell_length_b   4.78
_cell_length_c   6.32
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   InW2Au
_chemical_formula_sum   'In2 W4 Au2'
_cell_volume   144.66
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  0.0  0.0  0.7  1.0
  W  W1  2  0.0  0.0  0.39  1.0
  W  W2  2  0.19  0.5  0.23  1.0
  Au  Au3  2  0.19  0.5  0.15  1.0

In W W Au
In W W Au 0 2 o o o 1 3 o o o 1 2 + + o 2 3 - - o 
W2AuIn crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two W2AuIn clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded in a single-bond geometry to one W(2) and one Au(1) atom. The W(1)-W(2) bond length is 1.79 Å. The W(1)-Au(1) bond length is 0.50 Å. In the second W site, W(2) is bonded in a 2-coordinate geometry to one W(1) and one In(1) atom. The W(2)-In(1) bond length is 1.96 Å. Au(1) is bonded in a single-bond geometry to one W(1) atom. In(1) is bonded in a distorted single-bond geometry to one W(2) atom.