data_KCd2Co
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.95
_cell_length_b   2.95
_cell_length_c   9.2
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   105.91
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KCd2Co
_chemical_formula_sum   'K1 Cd2 Co1'
_cell_volume   77.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K3  1  0.0  0.0  0.0  1.0
  Cd  Cd0  1  0.78  0.0  0.3  1.0
  Cd  Cd1  1  0.78  0.0  0.91  1.0
  Co  Co2  1  0.0  0.0  0.6  1.0

data_KCd2Co
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.95
_cell_length_b   2.95
_cell_length_c   9.2
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   105.91
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KCd2Co
_chemical_formula_sum   'K1 Cd2 Co1'
_cell_volume   77.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.0  0.0  1.0
  Cd  Cd1  1  0.78  0.0  0.3  1.0
  Cd  Cd2  1  0.78  0.0  0.91  1.0
  Co  Co3  1  0.0  0.0  0.6  1.0

K Cd Cd Co
K Cd Cd Co 0 2 - o - 0 1 - o o 1 1 o + o 1 1 + o o 1 3 + o o 2 3 + o o 3 3 o + o 3 3 + o o 
KCoCd2 crystallizes in the triclinic P1 space group. K(1) is bonded in a single-bond geometry to one Cd(1) and one Cd(2) atom. The K(1)-Cd(1) bond length is 2.81 Å. The K(1)-Cd(2) bond length is 1.08 Å. Co(1) is bonded in a 6-coordinate geometry to four equivalent Co(1), one Cd(1), and one Cd(2) atom. All Co(1)-Co(1) bond lengths are 2.95 Å. The Co(1)-Cd(1) bond length is 2.87 Å. The Co(1)-Cd(2) bond length is 2.87 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 2-coordinate geometry to one K(1) and one Co(1) atom. In the second Cd site, Cd(2) is bonded in a single-bond geometry to one K(1) and one Co(1) atom.