data_ZnBr2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.7
_cell_length_b   3.7
_cell_length_c   11.12
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   125.39
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnBr2Cl
_chemical_formula_sum   'Zn1 Br2 Cl1'
_cell_volume   123.86
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.7  0.0  0.87  1.0
  Br  Br0  1  0.0  0.0  0.06  1.0
  Br  Br1  1  0.7  0.0  0.29  1.0
  Cl  Cl2  1  0.0  0.0  0.47  1.0

data_ZnBr2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.39
_cell_length_b   3.7
_cell_length_c   11.12
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   117.3
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnBr2Cl
_chemical_formula_sum   'Zn1 Br2 Cl1'
_cell_volume   123.86
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.0  0.7  0.87  1.0
  Br  Br1  1  0.0  0.0  0.06  1.0
  Br  Br2  1  0.0  0.7  0.29  1.0
  Cl  Cl3  1  0.0  0.0  0.47  1.0

Zn Br Br Cl
Zn Br Br Cl 0 1 + o + 1 2 - o o 2 3 + o o 
ZnBrBrCl is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one bromine chloride molecule and one ZnBr cluster. In the ZnBr cluster, Zn(1) is bonded in a single-bond geometry to one Br(1) atom. The Zn(1)-Br(1) bond length is 2.42 Å. Br(1) is bonded in a single-bond geometry to one Zn(1) atom.