data_RePdAu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.73
_cell_length_b   4.78
_cell_length_c   5.08
_cell_angle_alpha   90.0
_cell_angle_beta   91.95
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   RePdAu2
_chemical_formula_sum   'Re1 Pd1 Au2'
_cell_volume   66.37
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re3  1  0.28  0.0  0.54  1.0
  Pd  Pd2  1  0.0  0.0  0.0  1.0
  Au  Au0  1  0.5  0.39  0.8  1.0
  Au  Au1  1  0.06  0.39  0.28  1.0

data_RePdAu2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.73
_cell_length_b   4.78
_cell_length_c   5.08
_cell_angle_alpha   90.0
_cell_angle_beta   91.95
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   RePdAu2
_chemical_formula_sum   'Re1 Pd1 Au2'
_cell_volume   66.37
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.28  0.0  0.54  1.0
  Pd  Pd1  1  0.0  0.0  0.0  1.0
  Au  Au2  1  0.06  0.39  0.28  1.0
  Au  Au3  1  0.5  0.39  0.8  1.0

Re Pd Au Au
Re Pd Au Au 0 3 o o o 0 1 o o o 0 1 o o + 0 1 + o + 0 0 + o o 0 2 o o o 1 2 - o - 1 2 o o - 1 1 + o o 1 3 o o o 2 3 o o o 2 3 o o + 2 3 + o o 2 3 + o + 2 2 + o o 3 3 + o o 
RePdAu2 is beta Plutonium-derived structured and crystallizes in the triclinic P1 space group. Re(1) is bonded in a 3-coordinate geometry to four equivalent Pd(1), one Au(1), and one Au(2) atom. There are a spread of Re(1)-Pd(1) bond distances ranging from 2.49-3.42 Å. The Re(1)-Au(1) bond length is 2.34 Å. The Re(1)-Au(2) bond length is 2.34 Å. Pd(1) is bonded in a 12-coordinate geometry to four equivalent Re(1), two equivalent Pd(1), two equivalent Au(2), and four equivalent Au(1) atoms. Both Pd(1)-Pd(1) bond lengths are 2.73 Å. There is one shorter (2.35 Å) and one longer (3.25 Å) Pd(1)-Au(2) bond length. There are a spread of Pd(1)-Au(1) bond distances ranging from 2.52-3.40 Å. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a 1-coordinate geometry to one Re(1) and four equivalent Pd(1) atoms. In the second Au site, Au(2) is bonded in a 2-coordinate geometry to one Re(1) and two equivalent Pd(1) atoms.