data_BeRhCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.79
_cell_length_b   3.62
_cell_length_c   6.03
_cell_angle_alpha   90.0
_cell_angle_beta   102.68
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BeRhCl2
_chemical_formula_sum   'Be1 Rh1 Cl2'
_cell_volume   80.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Be  Be0  1  0.71  0.0  0.16  1.0
  Rh  Rh3  1  0.45  0.81  0.14  1.0
  Cl  Cl1  1  0.28  0.81  0.76  1.0
  Cl  Cl2  1  0.05  0.0  0.76  1.0

data_BeRhCl2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.62
_cell_length_b   3.79
_cell_length_c   6.03
_cell_angle_alpha   102.68
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BeRhCl2
_chemical_formula_sum   'Be1 Rh1 Cl2'
_cell_volume   80.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Be  Be0  1  0.0  0.29  0.84  1.0
  Rh  Rh1  1  0.19  0.55  0.86  1.0
  Cl  Cl2  1  0.0  0.95  0.24  1.0
  Cl  Cl3  1  0.19  0.72  0.24  1.0

Be Rh Cl Cl
Be Rh Cl Cl 0 1 o - o 2 3 o + o 
BeRhCl2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one BeRhCl2 cluster. Be(1) is bonded in a single-bond geometry to one Rh(1) atom. The Be(1)-Rh(1) bond length is 1.20 Å. Rh(1) is bonded in a distorted single-bond geometry to one Be(1), one Cl(1), and one Cl(2) atom. The Rh(1)-Cl(1) bond length is 2.26 Å. The Rh(1)-Cl(2) bond length is 2.55 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in an L-shaped geometry to one Rh(1) and one Cl(2) atom. The Cl(1)-Cl(2) bond length is 1.11 Å. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Rh(1) and one Cl(1) atom.