data_TlGaOsRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.51
_cell_length_b   4.51
_cell_length_c   4.51
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlGaOsRh
_chemical_formula_sum   'Tl1 Ga1 Os1 Rh1'
_cell_volume   65.03
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl3  1  0.19  0.19  0.19  1.0
  Ga  Ga0  1  0.0  0.0  0.0  1.0
  Os  Os1  1  0.6  0.6  0.6  1.0
  Rh  Rh2  1  0.79  0.79  0.79  1.0

data_TlGaOsRh
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.51
_cell_length_b   4.51
_cell_length_c   11.06
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   TlGaOsRh
_chemical_formula_sum   'Tl3 Ga3 Os3 Rh3'
_cell_volume   195.1
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  3  0.0  0.0  0.81  1.0
  Ga  Ga1  3  0.0  0.0  0.0  1.0
  Os  Os2  3  0.0  0.0  0.4  1.0
  Rh  Rh3  3  0.0  0.0  0.21  1.0

Tl Ga Os Rh
Tl Ga Os Rh 0 1 o o o 0 3 - - o 0 3 - o - 0 3 o - - 0 2 - o o 0 2 o - o 0 2 o o - 1 3 - - - 1 2 - - o 1 2 - o - 1 2 o - - 2 3 o o o 
OsRhTlGa crystallizes in the trigonal R3m space group. Os(1) is bonded in a 7-coordinate geometry to one Rh(1), three equivalent Tl(1), and three equivalent Ga(1) atoms. The Os(1)-Rh(1) bond length is 2.12 Å. All Os(1)-Tl(1) bond lengths are 2.72 Å. All Os(1)-Ga(1) bond lengths are 2.72 Å. Rh(1) is bonded in a 5-coordinate geometry to one Os(1), three equivalent Tl(1), and one Ga(1) atom. All Rh(1)-Tl(1) bond lengths are 2.72 Å. The Rh(1)-Ga(1) bond length is 2.35 Å. Tl(1) is bonded in a 7-coordinate geometry to three equivalent Os(1), three equivalent Rh(1), and one Ga(1) atom. The Tl(1)-Ga(1) bond length is 2.12 Å. Ga(1) is bonded in a 2-coordinate geometry to three equivalent Os(1), one Rh(1), and one Tl(1) atom.