data_PRhAu4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.42
_cell_length_b   5.42
_cell_length_c   5.42
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   PRhAu4
_chemical_formula_sum   'P1 Rh1 Au4'
_cell_volume   112.88
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P4  1  0.0  0.0  0.0  1.0
  Rh  Rh5  1  0.92  0.92  0.92  1.0
  Au  Au0  1  0.88  0.88  0.79  1.0
  Au  Au1  1  0.88  0.79  0.88  1.0
  Au  Au2  1  0.79  0.88  0.88  1.0
  Au  Au3  1  0.79  0.79  0.79  1.0

data_PRhAu4
_symmetry_space_group_name_H-M   R3m
_cell_length_a   5.42
_cell_length_b   5.42
_cell_length_c   13.29
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   PRhAu4
_chemical_formula_sum   'P3 Rh3 Au12'
_cell_volume   338.65
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  3  0.0  0.0  0.0  1.0
  Rh  Rh1  3  0.0  0.0  0.08  1.0
  Au  Au2  9  0.06  0.03  0.15  1.0
  Au  Au3  3  0.0  0.0  0.21  1.0

P Rh Au Au Au Au
RhAu4P is Copper structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three RhAu4P clusters. Rh(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Au(1) and one P(1) atom. All Rh(1)-Au(1) bond lengths are 0.94 Å. The Rh(1)-P(1) bond length is 1.09 Å. There are two inequivalent Au sites. In the first Au site, Au(2) is bonded in a 3-coordinate geometry to three equivalent Au(1) atoms. All Au(2)-Au(1) bond lengths are 0.79 Å. In the second Au site, Au(1) is bonded in a 2-coordinate geometry to one Rh(1), one Au(2), and two equivalent Au(1) atoms. Both Au(1)-Au(1) bond lengths are 0.46 Å. P(1) is bonded in a single-bond geometry to one Rh(1) atom.