data_VSn2Pt
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.47
_cell_length_b   4.47
_cell_length_c   3.7
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VSn2Pt
_chemical_formula_sum   'V1 Sn2 Pt1'
_cell_volume   73.85
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Sn  Sn1  1  0.23  0.0  0.85  1.0
  Sn  Sn2  1  0.0  0.23  0.85  1.0
  Pt  Pt0  1  0.23  0.23  0.0  1.0

data_VSn2Pt
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.32
_cell_length_b   6.32
_cell_length_c   3.7
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VSn2Pt
_chemical_formula_sum   'V2 Sn4 Pt2'
_cell_volume   147.69
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.0  1.0
  Sn  Sn1  4  0.12  0.12  0.85  1.0
  Pt  Pt2  2  0.23  0.0  0.0  1.0

V Sn Sn Pt
VPtSn2 is alpha Po structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two VPtSn2 clusters. V(1) is bonded in a 3-coordinate geometry to one Pt(1) and two equivalent Sn(1) atoms. The V(1)-Pt(1) bond length is 1.48 Å. Both V(1)-Sn(1) bond lengths are 1.19 Å. Pt(1) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Sn(1) atoms. Both Pt(1)-Sn(1) bond lengths are 1.19 Å. Sn(1) is bonded in a distorted L-shaped geometry to one V(1) and one Pt(1) atom.