data_Ga2SbPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.09
_cell_length_b   3.19
_cell_length_c   7.8
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ga2SbPd
_chemical_formula_sum   'Ga2 Sb1 Pd1'
_cell_volume   76.95
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.55  0.6  0.23  1.0
  Ga  Ga1  1  0.55  0.6  0.56  1.0
  Sb  Sb3  1  0.0  0.0  0.9  1.0
  Pd  Pd2  1  0.0  0.0  0.0  1.0

data_Ga2SbPd
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.09
_cell_length_b   3.19
_cell_length_c   7.8
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ga2SbPd
_chemical_formula_sum   'Ga2 Sb1 Pd1'
_cell_volume   76.95
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.55  0.6  0.23  1.0
  Ga  Ga1  1  0.55  0.6  0.56  1.0
  Sb  Sb2  1  0.0  0.0  0.9  1.0
  Pd  Pd3  1  0.0  0.0  0.0  1.0

Ga Ga Sb Pd
PdGa2Sb crystallizes in the triclinic P1 space group. Pd(1) is bonded in a single-bond geometry to four equivalent Ga(1) and one Sb(1) atom. There are a spread of Pd(1)-Ga(1) bond distances ranging from 2.64-3.13 Å. The Pd(1)-Sb(1) bond length is 0.79 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 5-coordinate geometry to four equivalent Pd(1) and one Ga(2) atom. The Ga(1)-Ga(2) bond length is 2.58 Å. In the second Ga site, Ga(2) is bonded in a 7-coordinate geometry to one Ga(1), four equivalent Ga(2), and two equivalent Sb(1) atoms. There are two shorter (3.09 Å) and two longer (3.19 Å) Ga(2)-Ga(2) bond lengths. There is one shorter (3.23 Å) and one longer (3.37 Å) Ga(2)-Sb(1) bond length. Sb(1) is bonded in a single-bond geometry to one Pd(1) and two equivalent Ga(2) atoms.