data_CdTc2Ir
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.89
_cell_length_b   4.89
_cell_length_c   4.89
_cell_angle_alpha   132.31
_cell_angle_beta   132.31
_cell_angle_gamma   69.75
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdTc2Ir
_chemical_formula_sum   'Cd1 Tc2 Ir1'
_cell_volume   62.57
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.0  0.01  1.0
  Tc  Tc2  1  0.0  0.0  0.0  1.0
  Tc  Tc3  1  0.98  0.0  0.0  1.0
  Ir  Ir1  1  0.0  0.98  0.0  1.0

data_CdTc2Ir
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.59
_cell_length_b   5.59
_cell_length_c   4.89
_cell_angle_alpha   90.0
_cell_angle_beta   124.87
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   CdTc2Ir
_chemical_formula_sum   'Cd2 Tc4 Ir2'
_cell_volume   125.15
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  2  0.01  0.0  0.01  1.0
  Tc  Tc1  2  0.0  0.0  0.0  1.0
  Tc  Tc2  2  0.01  0.0  0.03  1.0
  Ir  Ir3  2  0.03  0.0  0.03  1.0

Cd Tc Tc Ir
Tc2IrCd is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Tc2IrCd cluster. There are two inequivalent Tc sites. In the first Tc site, Tc(1) is bonded in a single-bond geometry to one Cd(1) atom. The Tc(1)-Cd(1) bond length is 0.04 Å. In the second Tc site, Tc(2) is bonded in a single-bond geometry to one Cd(1) atom. The Tc(2)-Cd(1) bond length is 0.11 Å. Ir(1) is bonded in a single-bond geometry to one Cd(1) atom. The Ir(1)-Cd(1) bond length is 0.11 Å. Cd(1) is bonded in a 3-coordinate geometry to one Tc(1), one Tc(2), and one Ir(1) atom.