data_VIn3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.06
_cell_length_b   5.16
_cell_length_c   5.33
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VIn3
_chemical_formula_sum   'V1 In3'
_cell_volume   84.18
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.74  1.0
  In  In0  1  0.0  0.58  0.06  1.0
  In  In1  1  0.53  0.58  0.62  1.0
  In  In2  1  0.53  0.0  0.45  1.0

data_VIn3
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.06
_cell_length_b   5.16
_cell_length_c   5.33
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VIn3
_chemical_formula_sum   'V1 In3'
_cell_volume   84.18
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.74  1.0
  In  In1  1  -0.0  0.58  0.06  1.0
  In  In2  1  0.53  0.0  0.45  1.0
  In  In3  1  0.53  0.58  0.62  1.0

V In In In
VIn3 crystallizes in the triclinic P1 space group. V(1) is bonded in a 2-coordinate geometry to two equivalent In(1), two equivalent In(3), and four equivalent In(2) atoms. There is one shorter (2.74 Å) and one longer (3.43 Å) V(1)-In(1) bond length. There is one shorter (2.12 Å) and one longer (2.25 Å) V(1)-In(3) bond length. There are a spread of V(1)-In(2) bond distances ranging from 2.68-3.47 Å. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 10-coordinate geometry to two equivalent V(1), two equivalent In(1), two equivalent In(3), and four equivalent In(2) atoms. Both In(1)-In(1) bond lengths are 3.06 Å. There is one shorter (3.34 Å) and one longer (3.42 Å) In(1)-In(3) bond length. There are a spread of In(1)-In(2) bond distances ranging from 2.74-3.40 Å. In the second In site, In(2) is bonded in a 12-coordinate geometry to four equivalent V(1), two equivalent In(2), two equivalent In(3), and four equivalent In(1) atoms. Both In(2)-In(2) bond lengths are 3.06 Å. There is one shorter (2.35 Å) and one longer (3.12 Å) In(2)-In(3) bond length. In the third In site, In(3) is bonded in a 2-coordinate geometry to two equivalent V(1), two equivalent In(1), and two equivalent In(2) atoms.