data_SrNbV
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.7
_cell_length_b   4.7
_cell_length_c   4.7
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SrNbV
_chemical_formula_sum   'Sr1 Nb1 V1'
_cell_volume   73.57
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr1  1  0.33  0.33  0.33  1.0
  Nb  Nb0  1  0.66  0.66  0.66  1.0
  V  V2  1  0.0  0.0  0.0  1.0

data_SrNbV
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.7
_cell_length_b   4.7
_cell_length_c   11.52
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   SrNbV
_chemical_formula_sum   'Sr3 Nb3 V3'
_cell_volume   220.71
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  3  0.0  0.0  0.67  1.0
  Nb  Nb1  3  0.0  0.0  0.34  1.0
  V  V2  3  0.0  0.0  0.0  1.0

Sr Nb V
SrNbV crystallizes in the trigonal R3m space group. Sr(1) is bonded to four equivalent Nb(1) and four equivalent V(1) atoms to form distorted SrNb4V4 hexagonal bipyramids that share corners with six equivalent V(1)Sr4Nb3 hexagonal pyramids, edges with twelve equivalent Sr(1)Nb4V4 hexagonal bipyramids, and edges with three equivalent V(1)Sr4Nb3 hexagonal pyramids. There are three shorter (2.72 Å) and one longer (3.88 Å) Sr(1)-Nb(1) bond length. There are three shorter (2.72 Å) and one longer (3.75 Å) Sr(1)-V(1) bond length. Nb(1) is bonded in a 7-coordinate geometry to four equivalent Sr(1) and three equivalent V(1) atoms. All Nb(1)-V(1) bond lengths are 2.72 Å. V(1) is bonded to four equivalent Sr(1) and three equivalent Nb(1) atoms to form distorted VSr4Nb3 hexagonal pyramids that share corners with six equivalent Sr(1)Nb4V4 hexagonal bipyramids, corners with six equivalent V(1)Sr4Nb3 hexagonal pyramids, edges with three equivalent Sr(1)Nb4V4 hexagonal bipyramids, and edges with six equivalent V(1)Sr4Nb3 hexagonal pyramids.