data_LaTiP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.74
_cell_length_b   3.74
_cell_length_c   6.32
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   92.19
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaTiP2
_chemical_formula_sum   'La1 Ti1 P2'
_cell_volume   88.25
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.59  0.0  0.03  1.0
  Ti  Ti3  1  0.0  0.0  0.23  1.0
  P  P1  1  0.0  0.0  0.2  1.0
  P  P2  1  0.59  0.0  0.03  1.0

data_LaTiP2
_symmetry_space_group_name_H-M   Pm
_cell_length_a   3.74
_cell_length_b   3.74
_cell_length_c   6.32
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   LaTiP2
_chemical_formula_sum   'La1 Ti1 P2'
_cell_volume   88.31
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.59  0.0  0.03  1.0
  Ti  Ti1  1  0.0  0.0  0.23  1.0
  P  P2  1  0.0  0.0  0.2  1.0
  P  P3  1  0.59  0.0  0.03  1.0

LaPTiP is beta oxygen-derived structured and crystallizes in the monoclinic Pm space group. The structure is zero-dimensional and consists of one lanthanum;phosphane molecule and one phosphane;titanium molecule.