data_HfIn2Ag
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.41
_cell_length_b   5.41
_cell_length_c   3.06
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   107.07
_symmetry_Int_Tables_number   1
_chemical_formula_structural   HfIn2Ag
_chemical_formula_sum   'Hf1 In2 Ag1'
_cell_volume   85.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf1  1  0.22  0.0  0.0  1.0
  In  In2  1  0.61  0.82  0.53  1.0
  In  In3  1  0.61  0.18  0.53  1.0
  Ag  Ag0  1  0.0  0.0  0.0  1.0

data_HfIn2Ag
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.06
_cell_length_b   5.41
_cell_length_c   5.41
_cell_angle_alpha   107.07
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   HfIn2Ag
_chemical_formula_sum   'Hf1 In2 Ag1'
_cell_volume   85.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.0  0.22  0.0  1.0
  In  In1  1  0.53  0.61  0.18  1.0
  In  In2  1  0.53  0.61  0.82  1.0
  Ag  Ag3  1  0.0  0.0  0.0  1.0

Hf In In Ag
HfAgIn2 crystallizes in the triclinic P1 space group. Hf(1) is bonded in a distorted single-bond geometry to one Ag(1), two equivalent In(1), and two equivalent In(2) atoms. The Hf(1)-Ag(1) bond length is 1.17 Å. There is one shorter (2.94 Å) and one longer (3.04 Å) Hf(1)-In(1) bond length. There is one shorter (2.51 Å) and one longer (2.62 Å) Hf(1)-In(2) bond length. Ag(1) is bonded in a single-bond geometry to one Hf(1) and two equivalent In(1) atoms. There is one shorter (2.51 Å) and one longer (2.62 Å) Ag(1)-In(1) bond length. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 8-coordinate geometry to two equivalent Hf(1), two equivalent Ag(1), two equivalent In(1), and two equivalent In(2) atoms. Both In(1)-In(1) bond lengths are 3.06 Å. There is one shorter (1.91 Å) and one longer (3.50 Å) In(1)-In(2) bond length. In the second In site, In(2) is bonded in a 3-coordinate geometry to two equivalent Hf(1) and two equivalent In(1) atoms.