data_ZnTeMo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.23
_cell_length_b   5.23
_cell_length_c   5.23
_cell_angle_alpha   142.44
_cell_angle_beta   126.81
_cell_angle_gamma   66.93
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnTeMo2
_chemical_formula_sum   'Zn1 Te1 Mo2'
_cell_volume   68.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.0  0.0  1.0
  Te  Te2  1  0.0  0.0  0.36  1.0
  Mo  Mo0  1  0.0  0.34  0.21  1.0
  Mo  Mo1  1  0.68  0.0  0.15  1.0

data_ZnTeMo2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.37
_cell_length_b   4.68
_cell_length_c   5.23
_cell_angle_alpha   116.6
_cell_angle_beta   108.78
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnTeMo2
_chemical_formula_sum   'Zn1 Te1 Mo2'
_cell_volume   68.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.0  0.0  0.0  1.0
  Te  Te1  1  0.0  0.36  0.36  1.0
  Mo  Mo2  1  0.0  0.15  0.46  1.0
  Mo  Mo3  1  0.66  0.87  0.87  1.0

Zn Te Mo Mo
Mo2ZnTe is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Mo2ZnTe cluster. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a distorted single-bond geometry to one Zn(1) atom. The Mo(1)-Zn(1) bond length is 1.12 Å. In the second Mo site, Mo(2) is bonded in a distorted single-bond geometry to one Te(1) atom. The Mo(2)-Te(1) bond length is 1.33 Å. Zn(1) is bonded in a distorted single-bond geometry to one Mo(1) and one Te(1) atom. The Zn(1)-Te(1) bond length is 1.89 Å. Te(1) is bonded in a distorted L-shaped geometry to one Mo(2) and one Zn(1) atom.