data_ScAg2Bi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.59
_cell_length_b   3.59
_cell_length_c   6.79
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScAg2Bi
_chemical_formula_sum   'Sc1 Ag2 Bi1'
_cell_volume   87.34
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc3  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.79  0.79  0.51  1.0
  Ag  Ag1  1  0.79  0.79  0.27  1.0
  Bi  Bi2  1  0.0  0.0  0.39  1.0

data_ScAg2Bi
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.07
_cell_length_b   5.07
_cell_length_c   6.79
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ScAg2Bi
_chemical_formula_sum   'Sc2 Ag4 Bi2'
_cell_volume   174.67
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  2  0.0  0.0  0.0  1.0
  Ag  Ag1  2  0.29  0.5  0.27  1.0
  Ag  Ag2  2  0.29  0.5  0.51  1.0
  Bi  Bi3  2  0.0  0.0  0.39  1.0

Sc Ag Ag Bi
ScAg2Bi crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ScAg2Bi clusters. Sc(1) is bonded in a distorted single-bond geometry to one Ag(2) atom. The Sc(1)-Ag(2) bond length is 2.13 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted single-bond geometry to one Bi(1) atom. The Ag(1)-Bi(1) bond length is 1.33 Å. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one Sc(1) and one Bi(1) atom. The Ag(2)-Bi(1) bond length is 1.33 Å. Bi(1) is bonded in a 2-coordinate geometry to one Ag(1) and one Ag(2) atom.