data_LaScVRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.91
_cell_length_b   4.91
_cell_length_c   4.91
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaScVRh
_chemical_formula_sum   'La1 Sc1 V1 Rh1'
_cell_volume   83.75
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.47  0.47  0.47  1.0
  Sc  Sc2  1  0.0  0.0  0.0  1.0
  V  V3  1  0.21  0.21  0.21  1.0
  Rh  Rh1  1  0.74  0.74  0.74  1.0

data_LaScVRh
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.91
_cell_length_b   4.91
_cell_length_c   12.03
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   LaScVRh
_chemical_formula_sum   'La3 Sc3 V3 Rh3'
_cell_volume   251.26
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  3  0.0  0.0  0.53  1.0
  Sc  Sc1  3  0.0  0.0  -0.0  1.0
  V  V2  3  0.0  0.0  0.79  1.0
  Rh  Rh3  3  0.0  0.0  0.26  1.0

La Sc V Rh
LaScVRh crystallizes in the trigonal R3m space group. La(1) is bonded in a 8-coordinate geometry to four equivalent V(1) and four equivalent Rh(1) atoms. There are three shorter (2.96 Å) and one longer (3.17 Å) La(1)-V(1) bond length. There are three shorter (2.96 Å) and one longer (3.17 Å) La(1)-Rh(1) bond length. Sc(1) is bonded in a 8-coordinate geometry to four equivalent V(1) and four equivalent Rh(1) atoms. There is one shorter (2.51 Å) and three longer (3.21 Å) Sc(1)-V(1) bond lengths. There are three shorter (2.96 Å) and one longer (3.17 Å) Sc(1)-Rh(1) bond length. V(1) is bonded in a 11-coordinate geometry to four equivalent La(1), four equivalent Sc(1), and three equivalent Rh(1) atoms. All V(1)-Rh(1) bond lengths are 3.29 Å. Rh(1) is bonded in a 8-coordinate geometry to four equivalent La(1), four equivalent Sc(1), and three equivalent V(1) atoms.