data_V2RhBr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.54
_cell_length_b   4.54
_cell_length_c   2.86
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.71
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2RhBr
_chemical_formula_sum   'V2 Rh1 Br1'
_cell_volume   58.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.59  0.39  0.43  1.0
  V  V3  1  0.59  0.61  0.43  1.0
  Rh  Rh1  1  0.19  0.0  0.0  1.0
  Br  Br0  1  0.0  0.0  0.0  1.0

data_V2RhBr
_symmetry_space_group_name_H-M   Pm
_cell_length_a   2.86
_cell_length_b   4.54
_cell_length_c   4.54
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   V2RhBr
_chemical_formula_sum   'V2 Rh1 Br1'
_cell_volume   58.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.43  0.39  0.59  1.0
  Rh  Rh1  1  -0.0  0.0  0.19  1.0
  Br  Br2  1  0.0  0.0  0.0  1.0

V V Rh Br
V2RhBr crystallizes in the monoclinic Pm space group. V(1) is bonded in a 5-coordinate geometry to one V(1), two equivalent Rh(1), and two equivalent Br(1) atoms. The V(1)-V(1) bond length is 1.03 Å. There is one shorter (2.83 Å) and one longer (3.02 Å) V(1)-Rh(1) bond length. There is one shorter (2.83 Å) and one longer (3.02 Å) V(1)-Br(1) bond length. Rh(1) is bonded in a single-bond geometry to four equivalent V(1) and one Br(1) atom. The Rh(1)-Br(1) bond length is 0.85 Å. Br(1) is bonded in a single-bond geometry to four equivalent V(1) and one Rh(1) atom.