data_B2POs
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.9
_cell_length_b   3.9
_cell_length_c   3.9
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   B2POs
_chemical_formula_sum   'B2 P1 Os1'
_cell_volume   41.99
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.14  0.14  0.14  1.0
  B  B1  1  0.0  0.0  0.0  1.0
  P  P3  1  0.76  0.76  0.76  1.0
  Os  Os2  1  0.38  0.38  0.38  1.0

data_B2POs
_symmetry_space_group_name_H-M   R3m
_cell_length_a   3.9
_cell_length_b   3.9
_cell_length_c   9.56
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   B2POs
_chemical_formula_sum   'B6 P3 Os3'
_cell_volume   125.98
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  3  0.0  0.0  0.0  1.0
  B  B1  3  0.0  0.0  0.86  1.0
  P  P2  3  0.0  0.0  0.24  1.0
  Os  Os3  3  0.0  0.0  0.62  1.0

B B P Os
OsB2P crystallizes in the trigonal R3m space group. Os(1) is bonded in a 10-coordinate geometry to three equivalent B(2), four equivalent B(1), and three equivalent P(1) atoms. All Os(1)-B(2) bond lengths are 2.30 Å. There is one shorter (2.31 Å) and three longer (2.42 Å) Os(1)-B(1) bond lengths. All Os(1)-P(1) bond lengths are 2.30 Å. There are two inequivalent B sites. In the first B site, B(1) is bonded in a 1-coordinate geometry to four equivalent Os(1), one B(2), and three equivalent P(1) atoms. The B(1)-B(2) bond length is 1.32 Å. All B(1)-P(1) bond lengths are 2.30 Å. In the second B site, B(2) is bonded in a 1-coordinate geometry to three equivalent Os(1), one B(1), and four equivalent P(1) atoms. There is one shorter (2.31 Å) and three longer (2.42 Å) B(2)-P(1) bond lengths. P(1) is bonded in a 10-coordinate geometry to three equivalent Os(1), three equivalent B(1), and four equivalent B(2) atoms.