data_LaVOsW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.61
_cell_length_b   4.61
_cell_length_c   4.61
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaVOsW
_chemical_formula_sum   'La1 V1 Os1 W1'
_cell_volume   69.13
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.63  0.63  0.63  1.0
  V  V2  1  0.0  0.0  0.0  1.0
  Os  Os1  1  0.89  0.89  0.89  1.0
  W  W3  1  0.26  0.26  0.26  1.0

data_LaVOsW
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.61
_cell_length_b   4.61
_cell_length_c   11.28
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   LaVOsW
_chemical_formula_sum   'La3 V3 Os3 W3'
_cell_volume   207.38
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  3  0.0  0.0  0.37  1.0
  V  V1  3  0.0  0.0  0.0  1.0
  Os  Os2  3  0.0  0.0  0.11  1.0
  W  W3  3  0.0  0.0  0.74  1.0

La V Os W
LaVWOs crystallizes in the trigonal R3m space group. La(1) is bonded in a 10-coordinate geometry to three equivalent V(1), three equivalent W(1), and four equivalent Os(1) atoms. All La(1)-V(1) bond lengths are 2.69 Å. All La(1)-W(1) bond lengths are 2.69 Å. There are three shorter (2.79 Å) and one longer (2.90 Å) La(1)-Os(1) bond length. V(1) is bonded in a single-bond geometry to three equivalent La(1), four equivalent W(1), and one Os(1) atom. There are three shorter (2.79 Å) and one longer (2.90 Å) V(1)-W(1) bond length. The V(1)-Os(1) bond length is 1.28 Å. W(1) is bonded in a 10-coordinate geometry to three equivalent La(1), four equivalent V(1), and three equivalent Os(1) atoms. All W(1)-Os(1) bond lengths are 2.69 Å. Os(1) is bonded in a single-bond geometry to four equivalent La(1), one V(1), and three equivalent W(1) atoms.