data_K2GaCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.92
_cell_length_b   5.92
_cell_length_c   3.79
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   96.85
_symmetry_Int_Tables_number   1
_chemical_formula_structural   K2GaCl
_chemical_formula_sum   'K2 Ga1 Cl1'
_cell_volume   131.9
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K2  1  0.96  0.21  0.9  1.0
  K  K3  1  0.96  0.79  0.9  1.0
  Ga  Ga1  1  0.93  0.0  0.0  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_K2GaCl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.79
_cell_length_b   5.92
_cell_length_c   5.92
_cell_angle_alpha   96.85
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   K2GaCl
_chemical_formula_sum   'K2 Ga1 Cl1'
_cell_volume   131.9
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.9  0.96  0.21  1.0
  K  K1  1  0.9  0.96  0.79  1.0
  Ga  Ga2  1  0.0  0.93  0.0  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

K K Ga Cl
K2GaCl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one K2GaCl cluster. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 2-coordinate geometry to one Ga(1) and one Cl(1) atom. The K(1)-Ga(1) bond length is 1.32 Å. The K(1)-Cl(1) bond length is 1.37 Å. In the second K site, K(2) is bonded in a 2-coordinate geometry to one Ga(1) and one Cl(1) atom. The K(2)-Ga(1) bond length is 1.37 Å. The K(2)-Cl(1) bond length is 1.32 Å. Ga(1) is bonded in a single-bond geometry to one K(1), one K(2), and one Cl(1) atom. The Ga(1)-Cl(1) bond length is 0.43 Å. Cl(1) is bonded in a single-bond geometry to one K(1), one K(2), and one Ga(1) atom.