data_CdNi2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.52
_cell_length_b   4.52
_cell_length_c   2.73
_cell_angle_alpha   92.25
_cell_angle_beta   92.25
_cell_angle_gamma   105.07
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdNi2P
_chemical_formula_sum   'Cd1 Ni2 P1'
_cell_volume   53.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.75  0.0  0.0  1.0
  Ni  Ni1  1  0.29  0.21  0.36  1.0
  Ni  Ni2  1  0.29  0.79  0.36  1.0
  P  P3  1  0.0  0.0  0.0  1.0

data_CdNi2P
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.73
_cell_length_b   4.52
_cell_length_c   4.52
_cell_angle_alpha   105.07
_cell_angle_beta   92.25
_cell_angle_gamma   92.25
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdNi2P
_chemical_formula_sum   'Cd1 Ni2 P1'
_cell_volume   53.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.75  0.0  1.0
  Ni  Ni1  1  0.36  0.29  0.79  1.0
  Ni  Ni2  1  0.36  0.29  0.21  1.0
  P  P3  1  0.0  0.0  0.0  1.0

Cd Ni Ni P
Ni2CdP crystallizes in the triclinic P1 space group. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a distorted single-bond geometry to two equivalent Ni(2) and one P(1) atom. There is one shorter (1.86 Å) and one longer (2.66 Å) Ni(1)-Ni(2) bond length. The Ni(1)-P(1) bond length is 1.65 Å. In the second Ni site, Ni(2) is bonded in a 8-coordinate geometry to two equivalent Ni(1), two equivalent Ni(2), two equivalent Cd(1), and two equivalent P(1) atoms. Both Ni(2)-Ni(2) bond lengths are 2.73 Å. There is one shorter (2.33 Å) and one longer (2.62 Å) Ni(2)-Cd(1) bond length. There is one shorter (2.03 Å) and one longer (2.50 Å) Ni(2)-P(1) bond length. Cd(1) is bonded in a single-bond geometry to two equivalent Ni(2) and one P(1) atom. The Cd(1)-P(1) bond length is 1.13 Å. P(1) is bonded in a 2-coordinate geometry to one Ni(1), two equivalent Ni(2), and one Cd(1) atom.