data_Li2VAu
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.78
_cell_length_b   2.78
_cell_length_c   8.39
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2VAu
_chemical_formula_sum   'Li2 V1 Au1'
_cell_volume   64.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.0  0.0  0.2  1.0
  Li  Li2  1  0.39  0.39  0.16  1.0
  V  V3  1  0.0  0.0  0.3  1.0
  Au  Au0  1  0.39  0.39  0.32  1.0

data_Li2VAu
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.93
_cell_length_b   3.93
_cell_length_c   8.39
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Li2VAu
_chemical_formula_sum   'Li4 V2 Au2'
_cell_volume   129.41
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.2  1.0
  Li  Li1  2  0.39  0.0  0.16  1.0
  V  V2  2  0.0  0.0  0.3  1.0
  Au  Au3  2  0.39  0.0  0.32  1.0

Li Li V Au
VLiLiAu crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two LiAu clusters and two VLi clusters. In each LiAu cluster, Li(2) is bonded in a single-bond geometry to one Au(1) atom. The Li(2)-Au(1) bond length is 1.30 Å. Au(1) is bonded in a distorted single-bond geometry to one Li(2) atom. In each VLi cluster, Li(1) is bonded in a single-bond geometry to one V(1) atom. The Li(1)-V(1) bond length is 0.83 Å. V(1) is bonded in a single-bond geometry to one Li(1) atom.