data_Ba2RhW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.34
_cell_length_b   3.36
_cell_length_c   9.39
_cell_angle_alpha   90.0
_cell_angle_beta   93.2
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ba2RhW
_chemical_formula_sum   'Ba2 Rh1 W1'
_cell_volume   105.07
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.26  0.68  0.25  1.0
  Ba  Ba1  1  0.55  0.68  0.13  1.0
  Rh  Rh2  1  0.0  0.0  0.0  1.0
  W  W3  1  0.74  0.0  0.69  1.0

data_Ba2RhW
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.34
_cell_length_b   3.36
_cell_length_c   9.39
_cell_angle_alpha   90.0
_cell_angle_beta   93.2
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ba2RhW
_chemical_formula_sum   'Ba2 Rh1 W1'
_cell_volume   105.07
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.26  0.68  0.25  1.0
  Ba  Ba1  1  0.55  0.68  0.13  1.0
  Rh  Rh2  1  0.0  0.0  0.0  1.0
  W  W3  1  0.74  0.0  0.69  1.0

Ba Ba Rh W
Ba2WRh crystallizes in the triclinic P1 space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 1-coordinate geometry to two equivalent Ba(2) and one W(1) atom. There is one shorter (1.57 Å) and one longer (2.57 Å) Ba(1)-Ba(2) bond length. The Ba(1)-W(1) bond length is 4.46 Å. In the second Ba site, Ba(2) is bonded in a 6-coordinate geometry to two equivalent Ba(1) and four equivalent Rh(1) atoms. There are a spread of Ba(2)-Rh(1) bond distances ranging from 2.24-3.13 Å. W(1) is bonded in a 6-coordinate geometry to one Ba(1), four equivalent W(1), and one Rh(1) atom. There are two shorter (3.34 Å) and two longer (3.36 Å) W(1)-W(1) bond lengths. The W(1)-Rh(1) bond length is 3.00 Å. Rh(1) is bonded in a 2-coordinate geometry to four equivalent Ba(2) and one W(1) atom.