data_BaVTe2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.1
_cell_length_b   4.1
_cell_length_c   8.23
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   93.9
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaVTe2
_chemical_formula_sum   'Ba1 V1 Te2'
_cell_volume   137.74
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.8  0.0  0.65  1.0
  V  V3  1  0.0  0.0  0.54  1.0
  Te  Te1  1  0.0  0.0  0.02  1.0
  Te  Te2  1  0.8  0.0  0.13  1.0

data_BaVTe2
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.1
_cell_length_b   4.1
_cell_length_c   8.23
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   93.9
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaVTe2
_chemical_formula_sum   'Ba1 V1 Te2'
_cell_volume   137.74
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.8  0.0  0.65  1.0
  V  V1  1  0.0  0.0  0.54  1.0
  Te  Te2  1  0.0  0.0  0.02  1.0
  Te  Te3  1  0.8  0.0  0.13  1.0

Ba V Te Te
BaVTe2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one BaVTe2 cluster. Ba(1) is bonded in a distorted single-bond geometry to one V(1) and one Te(1) atom. The Ba(1)-V(1) bond length is 1.21 Å. The Ba(1)-Te(1) bond length is 3.17 Å. V(1) is bonded in a single-bond geometry to one Ba(1) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a bent 120 degrees geometry to one Ba(1) and one Te(2) atom. The Te(1)-Te(2) bond length is 1.20 Å. In the second Te site, Te(2) is bonded in a 1-coordinate geometry to one Te(1) atom.