data_Ga3Ag5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.81
_cell_length_b   5.81
_cell_length_c   4.19
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   92.72
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ga3Ag5
_chemical_formula_sum   'Ga3 Ag5'
_cell_volume   141.4
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga5  1  0.0  0.0  0.0  1.0
  Ga  Ga6  1  0.01  0.97  0.1  1.0
  Ga  Ga7  1  0.01  0.03  0.1  1.0
  Ag  Ag0  1  0.01  0.0  0.0  1.0
  Ag  Ag1  1  0.01  0.9  0.0  1.0
  Ag  Ag2  1  0.01  0.1  0.0  1.0
  Ag  Ag3  1  0.14  0.0  0.1  1.0
  Ag  Ag4  1  0.88  0.0  0.1  1.0

data_Ga3Ag5
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.19
_cell_length_b   5.81
_cell_length_c   5.81
_cell_angle_alpha   92.72
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ga3Ag5
_chemical_formula_sum   'Ga3 Ag5'
_cell_volume   141.4
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.0  0.0  0.0  1.0
  Ga  Ga1  1  0.1  0.01  0.97  1.0
  Ga  Ga2  1  0.1  0.01  0.03  1.0
  Ag  Ag3  1  0.0  0.01  0.9  1.0
  Ag  Ag4  1  0.0  0.01  0.1  1.0
  Ag  Ag5  1  0.0  0.01  0.0  1.0
  Ag  Ag6  1  0.1  0.14  0.0  1.0
  Ag  Ag7  1  0.1  0.88  0.0  1.0

Ga Ga Ga Ag Ag Ag Ag Ag
Ag5Ga3 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Ag5Ga3 cluster. There are five inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted single-bond geometry to one Ag(2), one Ag(4), one Ga(1), one Ga(2), and one Ga(3) atom. The Ag(1)-Ag(2) bond length is 0.60 Å. The Ag(1)-Ag(4) bond length is 0.85 Å. The Ag(1)-Ga(1) bond length is 0.06 Å. The Ag(1)-Ga(2) bond length is 0.44 Å. The Ag(1)-Ga(3) bond length is 0.44 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one Ag(1), one Ga(1), and one Ga(2) atom. The Ag(2)-Ga(1) bond length is 0.60 Å. The Ag(2)-Ga(2) bond length is 0.58 Å. In the third Ag site, Ag(3) is bonded in a 2-coordinate geometry to one Ga(1) and one Ga(3) atom. The Ag(3)-Ga(1) bond length is 0.60 Å. The Ag(3)-Ga(3) bond length is 0.58 Å. In the fourth Ag site, Ag(4) is bonded in a 3-coordinate geometry to one Ag(1), one Ga(2), and one Ga(3) atom. The Ag(4)-Ga(2) bond length is 0.76 Å. The Ag(4)-Ga(3) bond length is 0.78 Å. In the fifth Ag site, Ag(5) is bonded in a 3-coordinate geometry to one Ga(1), one Ga(2), and one Ga(3) atom. The Ag(5)-Ga(1) bond length is 0.80 Å. The Ag(5)-Ga(2) bond length is 0.78 Å. The Ag(5)-Ga(3) bond length is 0.76 Å. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a single-bond geometry to one Ag(1), one Ag(2), one Ag(3), one Ag(5), and one Ga(3) atom. The Ga(1)-Ga(3) bond length is 0.45 Å. In the second Ga site, Ga(2) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), one Ag(4), one Ag(5), and one Ga(3) atom. The Ga(2)-Ga(3) bond length is 0.37 Å. In the third Ga site, Ga(3) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(3), one Ag(4), one Ag(5), one Ga(1), and one Ga(2) atom.