data_VC
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.92
_cell_length_b   2.92
_cell_length_c   5.12
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VC
_chemical_formula_sum   'V2 C2'
_cell_volume   37.74
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.0  0.56  1.0
  V  V3  1  0.0  0.0  0.0  1.0
  C  C0  1  0.46  0.84  0.84  1.0
  C  C1  1  0.0  0.68  0.28  1.0

data_VC
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.92
_cell_length_b   2.92
_cell_length_c   5.12
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VC
_chemical_formula_sum   'V2 C2'
_cell_volume   37.74
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  V  V1  1  0.0  0.0  0.56  1.0
  C  C2  1  0.0  0.68  0.28  1.0
  C  C3  1  0.46  0.84  0.84  1.0

V V C C
VC crystallizes in the triclinic P1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 1-coordinate geometry to one C(2) and three equivalent C(1) atoms. The V(1)-C(2) bond length is 1.71 Å. There are a spread of V(1)-C(1) bond distances ranging from 2.01-2.57 Å. In the second V site, V(2) is bonded in a 3-coordinate geometry to one C(2) and three equivalent C(1) atoms. The V(2)-C(2) bond length is 1.71 Å. There are a spread of V(2)-C(1) bond distances ranging from 1.62-2.27 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a 6-coordinate geometry to three equivalent V(1) and three equivalent V(2) atoms. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one V(1) and one V(2) atom.