data_VFe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.27
_cell_length_b   3.27
_cell_length_c   5.69
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VFe
_chemical_formula_sum   'V2 Fe2'
_cell_volume   52.52
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.89  0.96  1.0
  V  V3  1  0.63  0.94  0.73  1.0
  Fe  Fe0  1  0.0  0.89  0.91  1.0
  Fe  Fe1  1  0.63  0.94  0.78  1.0

data_VFe
_symmetry_space_group_name_H-M   P-1
_cell_length_a   3.27
_cell_length_b   3.27
_cell_length_c   5.69
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   2
_chemical_formula_structural   VFe
_chemical_formula_sum   'V2 Fe2'
_cell_volume   52.52
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.32  0.53  0.38  1.0
  Fe  Fe1  2  0.32  0.53  0.43  1.0

V V Fe Fe
FeV is alpha carbon monoxide-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ferrovanadium molecules. V(1) is bonded in a single-bond geometry to one Fe(1) atom. The V(1)-Fe(1) bond length is 0.30 Å. Fe(1) is bonded in a single-bond geometry to one V(1) atom.