data_ZnInBi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.5
_cell_length_b   4.21
_cell_length_c   7.53
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnInBi2
_chemical_formula_sum   'Zn1 In1 Bi2'
_cell_volume   110.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.0  0.0  1.0
  In  In2  1  0.0  0.0  0.76  1.0
  Bi  Bi0  1  0.75  0.1  0.63  1.0
  Bi  Bi1  1  0.75  0.1  0.89  1.0

data_ZnInBi2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.5
_cell_length_b   4.21
_cell_length_c   7.53
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnInBi2
_chemical_formula_sum   'Zn1 In1 Bi2'
_cell_volume   110.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.0  0.0  0.76  1.0
  Bi  Bi2  1  0.75  0.1  0.63  1.0
  Bi  Bi3  1  0.75  0.1  0.89  1.0

Zn In Bi Bi
ZnInBi2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ZnInBi2 cluster. Zn(1) is bonded in a distorted single-bond geometry to one Bi(2) atom. The Zn(1)-Bi(2) bond length is 1.25 Å. In(1) is bonded in a distorted L-shaped geometry to one Bi(1) and one Bi(2) atom. The In(1)-Bi(1) bond length is 1.38 Å. The In(1)-Bi(2) bond length is 1.38 Å. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a single-bond geometry to one In(1) atom. In the second Bi site, Bi(2) is bonded in a distorted L-shaped geometry to one Zn(1) and one In(1) atom.