data_Li2CdRe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.69
_cell_length_b   2.69
_cell_length_c   9.16
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2CdRe
_chemical_formula_sum   'Li2 Cd1 Re1'
_cell_volume   66.47
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.35  0.35  0.12  1.0
  Li  Li2  1  0.0  0.0  0.4  1.0
  Cd  Cd0  1  0.0  0.0  0.88  1.0
  Re  Re3  1  0.35  0.35  0.49  1.0

data_Li2CdRe
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.81
_cell_length_b   3.81
_cell_length_c   9.16
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Li2CdRe
_chemical_formula_sum   'Li4 Cd2 Re2'
_cell_volume   132.93
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.4  1.0
  Li  Li1  2  0.35  0.0  0.12  1.0
  Cd  Cd2  2  0.0  0.0  0.88  1.0
  Re  Re3  2  0.35  0.0  0.49  1.0

Li Li Cd Re
LiReLiCd crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two lithium;rhenium molecules and two LiCd clusters. In each LiCd cluster, Li(1) is bonded in a distorted single-bond geometry to one Cd(1) atom. The Li(1)-Cd(1) bond length is 2.56 Å. Cd(1) is bonded in a distorted single-bond geometry to one Li(1) atom.