data_Mn2RhCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.65
_cell_length_b   4.65
_cell_length_c   3.0
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.95
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mn2RhCl
_chemical_formula_sum   'Mn2 Rh1 Cl1'
_cell_volume   64.86
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn1  1  0.63  0.66  0.5  1.0
  Mn  Mn2  1  0.63  0.34  0.5  1.0
  Rh  Rh3  1  0.26  0.0  0.0  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Mn2RhCl
_symmetry_space_group_name_H-M   Pmm2
_cell_length_a   3.0
_cell_length_b   4.65
_cell_length_c   4.65
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   25
_chemical_formula_structural   Mn2RhCl
_chemical_formula_sum   'Mn2 Rh1 Cl1'
_cell_volume   64.87
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, z'
  3  '-x, y, z'
  4  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  2  0.5  0.34  0.37  1.0
  Rh  Rh1  1  0.0  0.0  0.74  1.0
  Cl  Cl2  1  0.0  0.0  0.0  1.0

Mn Mn Rh Cl
Mn2RhCl crystallizes in the orthorhombic Pmm2 space group. Mn(1) is bonded in a 5-coordinate geometry to one Mn(1), two equivalent Rh(1), and two equivalent Cl(1) atoms. The Mn(1)-Mn(1) bond length is 1.47 Å. Both Mn(1)-Rh(1) bond lengths are 2.78 Å. Both Mn(1)-Cl(1) bond lengths are 2.78 Å. Rh(1) is bonded in a single-bond geometry to four equivalent Mn(1) and one Cl(1) atom. The Rh(1)-Cl(1) bond length is 1.22 Å. Cl(1) is bonded in a distorted single-bond geometry to four equivalent Mn(1) and one Rh(1) atom.