data_V2InNi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.42
_cell_length_b   8.42
_cell_length_c   8.42
_cell_angle_alpha   20.09
_cell_angle_beta   20.09
_cell_angle_gamma   20.09
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2InNi
_chemical_formula_sum   'V2 In1 Ni1'
_cell_volume   61.61
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.0  0.04  1.0
  V  V3  1  0.0  0.0  0.46  1.0
  In  In0  1  0.0  0.0  0.27  1.0
  Ni  Ni1  1  0.0  0.0  0.35  1.0

data_V2InNi
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.09
_cell_length_b   2.94
_cell_length_c   8.42
_cell_angle_alpha   90.0
_cell_angle_beta   101.62
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   V2InNi
_chemical_formula_sum   'V4 In2 Ni2'
_cell_volume   123.22
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  -0.0  0.0  0.96  1.0
  V  V1  2  -0.0  0.0  0.54  1.0
  In  In2  2  -0.0  0.0  0.73  1.0
  Ni  Ni3  2  -0.0  0.0  0.65  1.0

V V In Ni
V2NiIn is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two V2NiIn clusters. There are two inequivalent V sites. In the first V site, V(1) is bonded in a single-bond geometry to one In(1) atom. The V(1)-In(1) bond length is 1.94 Å. In the second V site, V(2) is bonded in a single-bond geometry to one Ni(1) atom. The V(2)-Ni(1) bond length is 0.90 Å. Ni(1) is bonded in a linear geometry to one V(2) and one In(1) atom. The Ni(1)-In(1) bond length is 0.68 Å. In(1) is bonded in a distorted single-bond geometry to one V(1) and one Ni(1) atom.