data_FeAu2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.42
_cell_length_b   3.27
_cell_length_c   6.95
_cell_angle_alpha   90.0
_cell_angle_beta   98.19
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   FeAu2Cl
_chemical_formula_sum   'Fe1 Au2 Cl1'
_cell_volume   76.96
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe3  1  0.58  0.64  0.46  1.0
  Au  Au0  1  0.29  0.0  0.16  1.0
  Au  Au1  1  0.59  0.64  0.53  1.0
  Cl  Cl2  1  0.6  0.0  0.17  1.0

data_FeAu2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.27
_cell_length_b   3.42
_cell_length_c   6.95
_cell_angle_alpha   98.19
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   FeAu2Cl
_chemical_formula_sum   'Fe1 Au2 Cl1'
_cell_volume   76.96
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.36  0.42  0.54  1.0
  Au  Au1  1  0.0  0.71  0.84  1.0
  Au  Au2  1  0.36  0.41  0.47  1.0
  Cl  Cl3  1  0.0  0.4  0.83  1.0

Fe Au Au Cl
AuFeAuCl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one gold(i) chloride molecule and one AuFe cluster. In the AuFe cluster, Fe(1) is bonded in a single-bond geometry to one Au(2) atom. The Fe(1)-Au(2) bond length is 0.44 Å. Au(2) is bonded in a single-bond geometry to one Fe(1) atom.