data_TiGa2Re
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.86
_cell_length_b   2.86
_cell_length_c   8.55
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   112.14
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiGa2Re
_chemical_formula_sum   'Ti1 Ga2 Re1'
_cell_volume   64.83
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti3  1  0.0  0.0  0.24  1.0
  Ga  Ga0  1  0.6  0.0  0.03  1.0
  Ga  Ga1  1  0.0  0.0  0.33  1.0
  Re  Re2  1  0.6  0.0  0.22  1.0

data_TiGa2Re
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.86
_cell_length_b   2.86
_cell_length_c   8.55
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   112.14
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiGa2Re
_chemical_formula_sum   'Ti1 Ga2 Re1'
_cell_volume   64.83
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.0  0.0  0.24  1.0
  Ga  Ga1  1  0.0  0.0  0.33  1.0
  Ga  Ga2  1  0.6  0.0  0.03  1.0
  Re  Re3  1  0.6  0.0  0.22  1.0

Ti Ga Ga Re
TiReGa2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one TiReGa2 cluster. Ti(1) is bonded in a 2-coordinate geometry to one Re(1) and one Ga(2) atom. The Ti(1)-Re(1) bond length is 1.16 Å. The Ti(1)-Ga(2) bond length is 0.81 Å. Re(1) is bonded in a 1-coordinate geometry to one Ti(1) and one Ga(1) atom. The Re(1)-Ga(1) bond length is 1.60 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a distorted single-bond geometry to one Re(1) atom. In the second Ga site, Ga(2) is bonded in a single-bond geometry to one Ti(1) atom.