data_TiSbAu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.17
_cell_length_b   3.17
_cell_length_c   7.91
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   94.21
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiSbAu2
_chemical_formula_sum   'Ti1 Sb1 Au2'
_cell_volume   79.35
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti3  1  0.0  0.0  0.76  1.0
  Sb  Sb2  1  0.16  0.0  0.8  1.0
  Au  Au0  1  0.16  0.0  0.14  1.0
  Au  Au1  1  0.0  0.0  0.16  1.0

data_TiSbAu2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.17
_cell_length_b   3.17
_cell_length_c   7.91
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   94.21
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiSbAu2
_chemical_formula_sum   'Ti1 Sb1 Au2'
_cell_volume   79.35
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.0  0.0  0.76  1.0
  Sb  Sb1  1  0.16  0.0  0.8  1.0
  Au  Au2  1  0.0  0.0  0.16  1.0
  Au  Au3  1  0.16  0.0  0.14  1.0

Ti Sb Au Au
TiSb(Au)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Au cluster and one TiSb cluster. In the Au cluster, there are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted single-bond geometry to one Au(2) atom. The Au(1)-Au(2) bond length is 0.52 Å. In the second Au site, Au(2) is bonded in a single-bond geometry to one Au(1) atom. In the TiSb cluster, Ti(1) is bonded in a single-bond geometry to one Sb(1) atom. The Ti(1)-Sb(1) bond length is 0.60 Å. Sb(1) is bonded in a single-bond geometry to one Ti(1) atom.