data_TlAgCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.59
_cell_length_b   6.59
_cell_length_c   6.59
_cell_angle_alpha   142.74
_cell_angle_beta   142.74
_cell_angle_gamma   53.72
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlAgCl2
_chemical_formula_sum   'Tl1 Ag1 Cl2'
_cell_volume   104.13
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl3  1  0.1  0.0  0.94  1.0
  Ag  Ag0  1  0.0  0.0  0.88  1.0
  Cl  Cl1  1  0.0  0.1  0.94  1.0
  Cl  Cl2  1  0.0  0.0  0.0  1.0

data_TlAgCl2
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.21
_cell_length_b   4.21
_cell_length_c   6.59
_cell_angle_alpha   108.63
_cell_angle_beta   108.63
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlAgCl2
_chemical_formula_sum   'Tl1 Ag1 Cl2'
_cell_volume   104.13
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.06  0.0  0.17  1.0
  Ag  Ag1  1  0.12  0.0  0.12  1.0
  Cl  Cl2  1  0.0  0.0  0.0  1.0
  Cl  Cl3  1  0.17  0.1  0.17  1.0

Tl Ag Cl Cl
AgTlCl2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one AgTlCl2 cluster. Ag(1) is bonded in a distorted trigonal non-coplanar geometry to one Tl(1), one Cl(1), and one Cl(2) atom. The Ag(1)-Tl(1) bond length is 0.44 Å. The Ag(1)-Cl(1) bond length is 0.44 Å. The Ag(1)-Cl(2) bond length is 0.81 Å. Tl(1) is bonded in a single-bond geometry to one Ag(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ag(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ag(1) atom.