data_Sc2VP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.41
_cell_length_b   3.41
_cell_length_c   5.95
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sc2VP
_chemical_formula_sum   'Sc2 V1 P1'
_cell_volume   69.07
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc1  1  0.7  0.7  0.41  1.0
  Sc  Sc2  1  0.7  0.7  0.55  1.0
  V  V3  1  0.0  0.0  0.98  1.0
  P  P0  1  0.0  0.0  0.0  1.0

data_Sc2VP
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.82
_cell_length_b   4.82
_cell_length_c   5.95
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Sc2VP
_chemical_formula_sum   'Sc4 V2 P2'
_cell_volume   138.14
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  2  0.2  0.5  0.41  1.0
  Sc  Sc1  2  0.2  0.5  0.55  1.0
  V  V2  2  0.0  0.0  0.98  1.0
  P  P3  2  0.0  0.0  0.0  1.0

Sc Sc V P
Sc2VP crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Sc2VP clusters. There are two inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in a bent 150 degrees geometry to one Sc(2) and one P(1) atom. The Sc(1)-Sc(2) bond length is 0.83 Å. The Sc(1)-P(1) bond length is 2.81 Å. In the second Sc site, Sc(2) is bonded in a distorted single-bond geometry to one Sc(1) atom. V(1) is bonded in a single-bond geometry to one P(1) atom. The V(1)-P(1) bond length is 0.14 Å. P(1) is bonded in a single-bond geometry to one Sc(1) and one V(1) atom.