data_CdPt2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.73
_cell_length_b   8.73
_cell_length_c   8.73
_cell_angle_alpha   20.29
_cell_angle_beta   20.29
_cell_angle_gamma   20.29
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdPt2Cl
_chemical_formula_sum   'Cd1 Pt2 Cl1'
_cell_volume   69.99
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.0  0.82  1.0
  Pt  Pt2  1  0.0  0.0  0.46  1.0
  Pt  Pt3  1  0.0  0.0  0.18  1.0
  Cl  Cl1  1  0.0  0.0  0.0  1.0

data_CdPt2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.33
_cell_length_b   3.08
_cell_length_c   8.73
_cell_angle_alpha   90.0
_cell_angle_beta   101.74
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   CdPt2Cl
_chemical_formula_sum   'Cd2 Pt4 Cl2'
_cell_volume   139.99
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  2  0.0  0.0  0.18  1.0
  Pt  Pt1  2  0.0  0.0  0.54  1.0
  Pt  Pt2  2  0.0  0.0  0.82  1.0
  Cl  Cl3  2  0.0  0.0  0.0  1.0

Cd Pt Pt Cl
Pt2CdCl crystallizes in the monoclinic Cm space group. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a distorted linear geometry to one Pt(2), six equivalent Pt(1), and one Cd(1) atom. The Pt(1)-Pt(2) bond length is 2.39 Å. All Pt(1)-Pt(1) bond lengths are 3.08 Å. The Pt(1)-Cd(1) bond length is 3.17 Å. In the second Pt site, Pt(2) is bonded in a single-bond geometry to one Pt(1) and one Cl(1) atom. The Pt(2)-Cl(1) bond length is 1.58 Å. Cd(1) is bonded in a single-bond geometry to one Pt(1) and one Cl(1) atom. The Cd(1)-Cl(1) bond length is 1.59 Å. Cl(1) is bonded in a linear geometry to one Pt(2) and one Cd(1) atom.