data_AlSb3Os
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.08
_cell_length_b   5.08
_cell_length_c   5.08
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AlSb3Os
_chemical_formula_sum   'Al1 Sb3 Os1'
_cell_volume   131.35
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al4  1  0.0  0.0  0.0  1.0
  Sb  Sb0  1  0.0  0.54  0.0  1.0
  Sb  Sb1  1  0.0  0.0  0.54  1.0
  Sb  Sb2  1  0.54  0.0  0.0  1.0
  Os  Os3  1  0.54  0.54  0.54  1.0

data_AlSb3Os
_symmetry_space_group_name_H-M   R3m
_cell_length_a   7.19
_cell_length_b   7.19
_cell_length_c   8.8
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   AlSb3Os
_chemical_formula_sum   'Al3 Sb9 Os3'
_cell_volume   394.05
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  3  0.0  0.0  0.0  1.0
  Sb  Sb1  9  0.03  0.51  0.51  1.0
  Os  Os2  3  0.0  0.0  0.54  1.0

Al Sb Sb Sb Os
OsAlSb3 is (Cubic) Perovskite structured and crystallizes in the trigonal R3m space group. Os(1) is bonded in a 3-coordinate geometry to three equivalent Sb(1) atoms. All Os(1)-Sb(1) bond lengths are 3.30 Å. Al(1) is bonded to six equivalent Sb(1) atoms to form corner-sharing AlSb6 octahedra. The corner-sharing octahedra are not tilted. There are three shorter (2.33 Å) and three longer (2.75 Å) Al(1)-Sb(1) bond lengths. Sb(1) is bonded in a distorted linear geometry to one Os(1) and two equivalent Al(1) atoms.