data_Sc2VZn
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.66
_cell_length_b   4.66
_cell_length_c   3.5
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sc2VZn
_chemical_formula_sum   'Sc2 V1 Zn1'
_cell_volume   76.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.33  0.0  0.75  1.0
  Sc  Sc1  1  0.0  0.33  0.75  1.0
  V  V2  1  0.0  0.0  0.0  1.0
  Zn  Zn3  1  0.33  0.33  0.0  1.0

data_Sc2VZn
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.59
_cell_length_b   6.59
_cell_length_c   3.5
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Sc2VZn
_chemical_formula_sum   'Sc4 V2 Zn2'
_cell_volume   152.34
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  4  0.17  0.17  0.75  1.0
  V  V1  2  0.0  0.0  0.0  1.0
  Zn  Zn2  2  0.33  0.0  0.0  1.0

Sc Sc V Zn
Sc2VZn crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Sc2VZn clusters. Sc(1) is bonded in a 2-coordinate geometry to one V(1) and one Zn(1) atom. The Sc(1)-V(1) bond length is 1.77 Å. The Sc(1)-Zn(1) bond length is 1.77 Å. V(1) is bonded in a 2-coordinate geometry to two equivalent Sc(1) atoms. Zn(1) is bonded in a 2-coordinate geometry to two equivalent Sc(1) atoms.