data_ZrSbOs2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.76
_cell_length_b   8.76
_cell_length_c   8.76
_cell_angle_alpha   20.67
_cell_angle_beta   20.67
_cell_angle_gamma   20.67
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrSbOs2
_chemical_formula_sum   'Zr1 Sb1 Os2'
_cell_volume   73.38
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr3  1  0.0  0.0  0.0  1.0
  Sb  Sb2  1  0.0  0.0  0.86  1.0
  Os  Os0  1  0.0  0.0  0.27  1.0
  Os  Os1  1  0.0  0.0  0.45  1.0

data_ZrSbOs2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.45
_cell_length_b   3.14
_cell_length_c   8.76
_cell_angle_alpha   90.0
_cell_angle_beta   101.96
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZrSbOs2
_chemical_formula_sum   'Zr2 Sb2 Os4'
_cell_volume   146.76
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  2  0.0  0.0  0.0  1.0
  Sb  Sb1  2  0.0  0.0  0.14  1.0
  Os  Os2  2  0.0  0.0  0.55  1.0
  Os  Os3  2  0.0  0.0  0.73  1.0

Zr Sb Os Os
ZrOs2Sb crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ZrOs2Sb clusters. Zr(1) is bonded in a distorted single-bond geometry to one Os(1) and one Sb(1) atom. The Zr(1)-Os(1) bond length is 2.33 Å. The Zr(1)-Sb(1) bond length is 1.24 Å. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a linear geometry to one Zr(1) and one Os(2) atom. The Os(1)-Os(2) bond length is 1.62 Å. In the second Os site, Os(2) is bonded in a single-bond geometry to one Os(1) atom. Sb(1) is bonded in a single-bond geometry to one Zr(1) atom.