data_Ba5Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.34
_cell_length_b   4.34
_cell_length_c   15.18
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ba5Rh
_chemical_formula_sum   'Ba5 Rh1'
_cell_volume   285.43
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.17  0.17  0.76  1.0
  Ba  Ba1  1  0.17  0.17  0.42  1.0
  Ba  Ba2  1  0.0  0.0  0.01  1.0
  Ba  Ba3  1  0.0  0.0  0.17  1.0
  Ba  Ba4  1  0.17  0.17  0.59  1.0
  Rh  Rh5  1  0.0  0.0  0.0  1.0

data_Ba5Rh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.13
_cell_length_b   6.13
_cell_length_c   15.18
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Ba5Rh
_chemical_formula_sum   'Ba10 Rh2'
_cell_volume   570.86
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  2  0.0  0.0  0.01  1.0
  Ba  Ba1  2  0.0  0.0  0.17  1.0
  Ba  Ba2  2  0.17  0.0  0.42  1.0
  Ba  Ba3  2  0.17  0.0  0.59  1.0
  Ba  Ba4  2  0.17  0.0  0.76  1.0
  Rh  Rh5  2  0.0  0.0  0.0  1.0

Ba Ba Ba Ba Ba Rh
Ba5Rh crystallizes in the monoclinic Cm space group. There are five inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 2-coordinate geometry to one Ba(5) and one Rh(1) atom. The Ba(1)-Ba(5) bond length is 2.60 Å. The Ba(1)-Rh(1) bond length is 3.80 Å. In the second Ba site, Ba(2) is bonded in a distorted single-bond geometry to one Ba(4), one Ba(5), and four equivalent Ba(2) atoms. The Ba(2)-Ba(4) bond length is 3.92 Å. The Ba(2)-Ba(5) bond length is 2.60 Å. All Ba(2)-Ba(2) bond lengths are 4.34 Å. In the third Ba site, Ba(3) is bonded in a single-bond geometry to one Ba(4) and one Rh(1) atom. The Ba(3)-Ba(4) bond length is 2.41 Å. The Ba(3)-Rh(1) bond length is 0.12 Å. In the fourth Ba site, Ba(4) is bonded in a distorted single-bond geometry to one Ba(2) and one Ba(3) atom. In the fifth Ba site, Ba(5) is bonded in a distorted linear geometry to one Ba(1) and one Ba(2) atom. Rh(1) is bonded in a single-bond geometry to one Ba(1) and one Ba(3) atom.