data_Cd2IrCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.07
_cell_length_b   4.83
_cell_length_c   5.08
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2IrCl
_chemical_formula_sum   'Cd2 Ir1 Cl1'
_cell_volume   75.42
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.54  0.0  0.54  1.0
  Cd  Cd1  1  0.0  0.42  0.54  1.0
  Ir  Ir3  1  0.54  0.42  0.0  1.0
  Cl  Cl2  1  0.0  0.0  0.0  1.0

data_Cd2IrCl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.07
_cell_length_b   4.83
_cell_length_c   5.08
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2IrCl
_chemical_formula_sum   'Cd2 Ir1 Cl1'
_cell_volume   75.42
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  -0.0  0.42  0.54  1.0
  Cd  Cd1  1  0.54  0.0  0.54  1.0
  Ir  Ir2  1  0.54  0.42  0.0  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Cd Cd Ir Cl
IrCd2Cl crystallizes in the triclinic P1 space group. Ir(1) is bonded in a 2-coordinate geometry to four equivalent Cd(2) and two equivalent Cl(1) atoms. There are a spread of Ir(1)-Cd(2) bond distances ranging from 2.74-3.20 Å. There is one shorter (2.46 Å) and one longer (2.60 Å) Ir(1)-Cl(1) bond length. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 2-coordinate geometry to four equivalent Cd(2) and three equivalent Cl(1) atoms. There are a spread of Cd(1)-Cd(2) bond distances ranging from 2.46-3.27 Å. There are a spread of Cd(1)-Cl(1) bond distances ranging from 2.74-3.09 Å. In the second Cd site, Cd(2) is bonded in a 11-coordinate geometry to four equivalent Ir(1), two equivalent Cd(2), four equivalent Cd(1), and one Cl(1) atom. Both Cd(2)-Cd(2) bond lengths are 3.07 Å. The Cd(2)-Cl(1) bond length is 3.08 Å. Cl(1) is bonded in a 5-coordinate geometry to two equivalent Ir(1), one Cd(2), and three equivalent Cd(1) atoms.