data_BRhPb2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.12
_cell_length_b   5.12
_cell_length_c   5.12
_cell_angle_alpha   137.75
_cell_angle_beta   116.82
_cell_angle_gamma   78.96
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BRhPb2
_chemical_formula_sum   'B1 Rh1 Pb2'
_cell_volume   78.32
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.0  0.0  0.0  1.0
  Rh  Rh3  1  0.0  0.0  0.95  1.0
  Pb  Pb1  1  0.0  0.68  0.2  1.0
  Pb  Pb2  1  0.85  0.0  0.75  1.0

data_BRhPb2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.69
_cell_length_b   5.12
_cell_length_c   5.12
_cell_angle_alpha   63.18
_cell_angle_beta   68.88
_cell_angle_gamma   68.88
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BRhPb2
_chemical_formula_sum   'B1 Rh1 Pb2'
_cell_volume   78.32
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.0  0.0  0.0  1.0
  Rh  Rh1  1  0.95  0.0  0.05  1.0
  Pb  Pb2  1  0.2  0.0  0.48  1.0
  Pb  Pb3  1  0.91  0.85  0.25  1.0

B Rh Pb Pb
RhBPb2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one RhBPb2 cluster. Rh(1) is bonded in a distorted bent 120 degrees geometry to one B(1) and one Pb(2) atom. The Rh(1)-B(1) bond length is 0.24 Å. The Rh(1)-Pb(2) bond length is 0.97 Å. B(1) is bonded in a single-bond geometry to one Rh(1) and one Pb(1) atom. The B(1)-Pb(1) bond length is 2.48 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 1-coordinate geometry to one B(1) atom. In the second Pb site, Pb(2) is bonded in a single-bond geometry to one Rh(1) atom.