data_Ga2WAu
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.34
_cell_length_b   5.34
_cell_length_c   2.84
_cell_angle_alpha   105.09
_cell_angle_beta   105.09
_cell_angle_gamma   112.21
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ga2WAu
_chemical_formula_sum   'Ga2 W1 Au1'
_cell_volume   66.33
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga1  1  0.83  0.78  0.26  1.0
  Ga  Ga2  1  0.83  0.22  0.26  1.0
  W  W3  1  0.0  0.0  0.0  1.0
  Au  Au0  1  0.98  0.0  0.0  1.0

data_Ga2WAu
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.84
_cell_length_b   5.27
_cell_length_c   5.34
_cell_angle_alpha   119.35
_cell_angle_beta   105.09
_cell_angle_gamma   90.64
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ga2WAu
_chemical_formula_sum   'Ga2 W1 Au1'
_cell_volume   66.33
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.04  0.78  0.61  1.0
  Ga  Ga1  1  0.47  0.22  0.04  1.0
  W  W2  1  0.0  0.0  0.0  1.0
  Au  Au3  1  0.0  0.0  0.98  1.0

Ga Ga W Au
WAuGa2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one WAuGa2 cluster. W(1) is bonded in a single-bond geometry to one Au(1) atom. The W(1)-Au(1) bond length is 0.12 Å. Au(1) is bonded in a single-bond geometry to one W(1), one Ga(1), and one Ga(2) atom. The Au(1)-Ga(1) bond length is 1.60 Å. The Au(1)-Ga(2) bond length is 1.76 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a distorted single-bond geometry to one Au(1) atom. In the second Ga site, Ga(2) is bonded in a single-bond geometry to one Au(1) atom.