data_TcSb2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.1
_cell_length_b   5.1
_cell_length_c   5.1
_cell_angle_alpha   125.69
_cell_angle_beta   125.69
_cell_angle_gamma   80.4
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TcSb2Cl
_chemical_formula_sum   'Tc1 Sb2 Cl1'
_cell_volume   84.27
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc3  1  0.0  0.0  0.89  1.0
  Sb  Sb1  1  0.33  0.0  0.95  1.0
  Sb  Sb2  1  0.0  0.33  0.95  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_TcSb2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.58
_cell_length_b   6.58
_cell_length_c   5.1
_cell_angle_alpha   90.0
_cell_angle_beta   130.2
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TcSb2Cl
_chemical_formula_sum   'Tc2 Sb4 Cl2'
_cell_volume   168.54
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  2  0.11  0.0  0.11  1.0
  Sb  Sb1  4  0.22  0.16  0.38  1.0
  Cl  Cl2  2  0.0  0.0  0.0  1.0

Tc Sb Sb Cl
TcSb2Cl is Copper structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two TcSb2Cl clusters. Tc(1) is bonded in a single-bond geometry to two equivalent Sb(1) and one Cl(1) atom. Both Tc(1)-Sb(1) bond lengths are 1.52 Å. The Tc(1)-Cl(1) bond length is 0.54 Å. Sb(1) is bonded in a single-bond geometry to one Tc(1) atom. Cl(1) is bonded in a single-bond geometry to one Tc(1) atom.