data_LiIn2Bi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.78
_cell_length_b   5.78
_cell_length_c   5.78
_cell_angle_alpha   131.63
_cell_angle_beta   131.63
_cell_angle_gamma   70.81
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiIn2Bi
_chemical_formula_sum   'Li1 In2 Bi1'
_cell_volume   105.4
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li3  1  0.0  0.0  0.0  1.0
  In  In1  1  0.0  0.0  0.71  1.0
  In  In2  1  0.0  0.37  0.35  1.0
  Bi  Bi0  1  0.37  0.0  0.35  1.0

data_LiIn2Bi
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.73
_cell_length_b   4.73
_cell_length_c   5.78
_cell_angle_alpha   114.18
_cell_angle_beta   114.18
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiIn2Bi
_chemical_formula_sum   'Li1 In2 Bi1'
_cell_volume   105.4
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.01  0.37  0.01  1.0
  In  In2  1  0.29  0.0  0.29  1.0
  Bi  Bi3  1  0.65  0.0  0.01  1.0

Li In In Bi
LiIn2Bi is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LiIn2Bi cluster. Li(1) is bonded in a distorted trigonal non-coplanar geometry to one In(1), one In(2), and one Bi(1) atom. The Li(1)-In(1) bond length is 1.69 Å. The Li(1)-In(2) bond length is 1.70 Å. The Li(1)-Bi(1) bond length is 1.70 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a single-bond geometry to one Li(1) atom. In the second In site, In(2) is bonded in a single-bond geometry to one Li(1) atom. Bi(1) is bonded in a single-bond geometry to one Li(1) atom.