data_Li(SbPd)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.47
_cell_length_b   6.47
_cell_length_c   6.47
_cell_angle_alpha   139.18
_cell_angle_beta   139.18
_cell_angle_gamma   59.1
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li(SbPd)2
_chemical_formula_sum   'Li1 Sb2 Pd2'
_cell_volume   114.48
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.0  1.0
  Sb  Sb3  1  0.0  0.0  0.05  1.0
  Sb  Sb4  1  0.0  0.0  0.2  1.0
  Pd  Pd1  1  0.0  0.26  0.81  1.0
  Pd  Pd2  1  0.26  0.0  0.81  1.0

data_Li(SbPd)2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.38
_cell_length_b   6.38
_cell_length_c   6.47
_cell_angle_alpha   90.0
_cell_angle_beta   119.55
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Li(SbPd)2
_chemical_formula_sum   'Li2 Sb4 Pd4'
_cell_volume   228.96
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.0  1.0
  Sb  Sb1  2  0.05  0.0  0.05  1.0
  Sb  Sb2  2  0.2  0.0  0.2  1.0
  Pd  Pd3  4  0.19  0.37  0.56  1.0

Li Sb Sb Pd Pd
Li(PdSb)2 crystallizes in the monoclinic Cm space group. Li(1) is bonded in a single-bond geometry to two equivalent Pd(1) and one Sb(1) atom. Both Li(1)-Pd(1) bond lengths are 2.69 Å. The Li(1)-Sb(1) bond length is 0.31 Å. Pd(1) is bonded in a 4-coordinate geometry to one Li(1), one Pd(1), and two equivalent Sb(2) atoms. The Pd(1)-Pd(1) bond length is 1.63 Å. There is one shorter (2.90 Å) and one longer (3.34 Å) Pd(1)-Sb(2) bond length. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a single-bond geometry to one Li(1) and one Sb(2) atom. The Sb(1)-Sb(2) bond length is 1.00 Å. In the second Sb site, Sb(2) is bonded in a distorted single-bond geometry to four equivalent Pd(1) and one Sb(1) atom.