data_VCrCd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.72
_cell_length_b   2.72
_cell_length_c   7.1
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCrCd
_chemical_formula_sum   'V1 Cr1 Cd1'
_cell_volume   45.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.0  0.62  1.0
  Cr  Cr1  1  0.0  0.57  0.46  1.0
  Cd  Cd0  1  0.36  0.79  0.03  1.0

data_VCrCd
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.72
_cell_length_b   2.72
_cell_length_c   7.1
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCrCd
_chemical_formula_sum   'V1 Cr1 Cd1'
_cell_volume   45.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.62  1.0
  Cr  Cr1  1  0.0  0.57  0.46  1.0
  Cd  Cd2  1  0.36  0.79  0.03  1.0

V Cr Cd
VCrCd crystallizes in the triclinic P1 space group. V(1) is bonded in a distorted water-like geometry to two equivalent Cr(1) and three equivalent Cd(1) atoms. There is one shorter (1.62 Å) and one longer (1.93 Å) V(1)-Cr(1) bond length. There are a spread of V(1)-Cd(1) bond distances ranging from 3.21-3.45 Å. Cr(1) is bonded in a distorted water-like geometry to two equivalent V(1) and one Cd(1) atom. The Cr(1)-Cd(1) bond length is 3.19 Å. Cd(1) is bonded in a 10-coordinate geometry to three equivalent V(1), one Cr(1), and six equivalent Cd(1) atoms. All Cd(1)-Cd(1) bond lengths are 2.72 Å.