data_Mn2PdCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.73
_cell_length_b   4.73
_cell_length_c   3.02
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   92.86
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mn2PdCl
_chemical_formula_sum   'Mn2 Pd1 Cl1'
_cell_volume   67.4
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn1  1  0.63  0.29  0.51  1.0
  Mn  Mn2  1  0.63  0.71  0.51  1.0
  Pd  Pd3  1  0.26  0.0  0.0  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Mn2PdCl
_symmetry_space_group_name_H-M   Pm
_cell_length_a   4.73
_cell_length_b   3.02
_cell_length_c   4.73
_cell_angle_alpha   90.0
_cell_angle_beta   92.86
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   Mn2PdCl
_chemical_formula_sum   'Mn2 Pd1 Cl1'
_cell_volume   67.4
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.63  0.5  0.29  1.0
  Mn  Mn1  1  0.63  0.5  0.71  1.0
  Pd  Pd2  1  0.26  0.0  0.0  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Mn Mn Pd Cl
Mn2PdCl crystallizes in the triclinic P1 space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 5-coordinate geometry to one Mn(2), two equivalent Pd(1), and two equivalent Cl(1) atoms. The Mn(1)-Mn(2) bond length is 2.01 Å. There is one shorter (2.62 Å) and one longer (2.65 Å) Mn(1)-Pd(1) bond length. There is one shorter (2.71 Å) and one longer (2.74 Å) Mn(1)-Cl(1) bond length. In the second Mn site, Mn(2) is bonded in a 5-coordinate geometry to one Mn(1), two equivalent Pd(1), and two equivalent Cl(1) atoms. There is one shorter (2.71 Å) and one longer (2.74 Å) Mn(2)-Pd(1) bond length. There is one shorter (2.62 Å) and one longer (2.65 Å) Mn(2)-Cl(1) bond length. Pd(1) is bonded in a single-bond geometry to two equivalent Mn(1), two equivalent Mn(2), and one Cl(1) atom. The Pd(1)-Cl(1) bond length is 1.23 Å. Cl(1) is bonded in a distorted single-bond geometry to two equivalent Mn(1), two equivalent Mn(2), and one Pd(1) atom.