data_LaRe2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.19
_cell_length_b   3.19
_cell_length_c   8.41
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaRe2Cl
_chemical_formula_sum   'La1 Re2 Cl1'
_cell_volume   85.69
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La1  1  0.6  0.6  0.36  1.0
  Re  Re2  1  0.0  0.0  0.31  1.0
  Re  Re3  1  0.6  0.6  0.56  1.0
  Cl  Cl0  1  0.0  0.0  0.38  1.0

data_LaRe2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.51
_cell_length_b   4.51
_cell_length_c   8.41
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LaRe2Cl
_chemical_formula_sum   'La2 Re4 Cl2'
_cell_volume   171.38
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  2  0.1  0.5  0.36  1.0
  Re  Re1  2  0.0  0.0  0.31  1.0
  Re  Re2  2  0.1  0.5  0.56  1.0
  Cl  Cl3  2  0.0  0.0  0.38  1.0

La Re Re Cl
LaRe2Cl crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two LaRe2Cl clusters. La(1) is bonded in a 2-coordinate geometry to one Re(2) and one Cl(1) atom. The La(1)-Re(2) bond length is 1.63 Å. The La(1)-Cl(1) bond length is 1.83 Å. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a single-bond geometry to one Cl(1) atom. The Re(1)-Cl(1) bond length is 0.57 Å. In the second Re site, Re(2) is bonded in a single-bond geometry to one La(1) atom. Cl(1) is bonded in a single-bond geometry to one La(1) and one Re(1) atom.