data_GaB2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.04
_cell_length_b   2.96
_cell_length_c   5.25
_cell_angle_alpha   90.0
_cell_angle_beta   90.23
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaB2W
_chemical_formula_sum   'Ga1 B2 W1'
_cell_volume   47.3
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga2  1  0.8  0.0  0.73  1.0
  B  B0  1  0.72  0.0  0.15  1.0
  B  B1  1  0.73  0.48  0.42  1.0
  W  W3  1  0.27  0.48  0.84  1.0

data_GaB2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.96
_cell_length_b   3.04
_cell_length_c   5.25
_cell_angle_alpha   90.23
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaB2W
_chemical_formula_sum   'Ga1 B2 W1'
_cell_volume   47.3
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.0  0.2  0.27  1.0
  B  B1  1  0.0  0.28  0.85  1.0
  B  B2  1  0.52  0.27  0.58  1.0
  W  W3  1  0.52  0.73  0.16  1.0

Ga B B W
WGaB2 crystallizes in the triclinic P1 space group. W(1) is bonded in a 4-coordinate geometry to four equivalent Ga(1), two equivalent B(2), and four equivalent B(1) atoms. There are a spread of W(1)-Ga(1) bond distances ranging from 2.08-2.32 Å. There is one shorter (2.60 Å) and one longer (2.73 Å) W(1)-B(2) bond length. There are a spread of W(1)-B(1) bond distances ranging from 2.55-2.79 Å. Ga(1) is bonded to four equivalent W(1), one B(1), and two equivalent B(2) atoms to form a mixture of distorted corner, edge, and face-sharing GaB3W4 pentagonal bipyramids. The Ga(1)-B(1) bond length is 2.20 Å. There is one shorter (2.16 Å) and one longer (2.24 Å) Ga(1)-B(2) bond length. There are two inequivalent B sites. In the first B site, B(1) is bonded in a 7-coordinate geometry to four equivalent W(1), one Ga(1), and two equivalent B(2) atoms. There is one shorter (2.03 Å) and one longer (2.12 Å) B(1)-B(2) bond length. In the second B site, B(2) is bonded in a 6-coordinate geometry to two equivalent W(1), two equivalent Ga(1), and two equivalent B(1) atoms.