data_W2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.88
_cell_length_b   2.88
_cell_length_c   6.63
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   W2Cl
_chemical_formula_sum   'W2 Cl1'
_cell_volume   47.78
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W1  1  0.44  0.83  0.47  1.0
  W  W2  1  0.0  0.67  0.17  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_W2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.88
_cell_length_b   2.88
_cell_length_c   6.63
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   W2Cl
_chemical_formula_sum   'W2 Cl1'
_cell_volume   47.78
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.0  0.67  0.17  1.0
  W  W1  1  0.44  0.83  0.47  1.0
  Cl  Cl2  1  0.0  0.0  0.0  1.0

W W Cl
W2Cl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one W2Cl cluster. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted single-bond geometry to one W(2) atom. The W(1)-W(2) bond length is 2.28 Å. In the second W site, W(2) is bonded in a distorted single-bond geometry to one W(1) and one Cl(1) atom. The W(2)-Cl(1) bond length is 1.46 Å. Cl(1) is bonded in a distorted single-bond geometry to one W(2) atom.