data_AgMo2As
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.27
_cell_length_b   4.4
_cell_length_c   4.58
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgMo2As
_chemical_formula_sum   'Ag1 Mo2 As1'
_cell_volume   66.0
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.64  0.2  0.0  1.0
  Mo  Mo2  1  0.0  0.2  0.29  1.0
  Mo  Mo3  1  0.64  0.0  0.29  1.0
  As  As1  1  0.0  0.0  0.0  1.0

data_AgMo2As
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.27
_cell_length_b   4.4
_cell_length_c   4.58
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgMo2As
_chemical_formula_sum   'Ag1 Mo2 As1'
_cell_volume   66.0
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.64  0.2  -0.0  1.0
  Mo  Mo1  1  0.0  0.2  0.29  1.0
  Mo  Mo2  1  0.64  0.0  0.29  1.0
  As  As3  1  0.0  0.0  0.0  1.0

Ag Mo Mo As
Mo2AgAs crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Mo2AgAs cluster. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 3-coordinate geometry to one Mo(2), one Ag(1), and one As(1) atom. The Mo(1)-Mo(2) bond length is 1.49 Å. The Mo(1)-Ag(1) bond length is 1.78 Å. The Mo(1)-As(1) bond length is 1.60 Å. In the second Mo site, Mo(2) is bonded in a 1-coordinate geometry to one Mo(1) and one Ag(1) atom. The Mo(2)-Ag(1) bond length is 1.60 Å. Ag(1) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(2), and one As(1) atom. The Ag(1)-As(1) bond length is 1.49 Å. As(1) is bonded in a 2-coordinate geometry to one Mo(1) and one Ag(1) atom.