data_LiSbBr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.47
_cell_length_b   7.47
_cell_length_c   7.47
_cell_angle_alpha   154.04
_cell_angle_beta   154.04
_cell_angle_gamma   37.04
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiSbBr
_chemical_formula_sum   'Li1 Sb1 Br1'
_cell_volume   79.77
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.0  0.0  0.29  1.0
  Sb  Sb2  1  0.0  0.0  0.81  1.0
  Br  Br0  1  0.0  0.0  0.24  1.0

data_LiSbBr
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.75
_cell_length_b   4.75
_cell_length_c   7.47
_cell_angle_alpha   90.0
_cell_angle_beta   108.52
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LiSbBr
_chemical_formula_sum   'Li2 Sb2 Br2'
_cell_volume   159.54
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.29  0.0  0.29  1.0
  Sb  Sb1  2  0.31  0.5  0.81  1.0
  Br  Br2  2  0.24  0.0  0.24  1.0

Li Sb Br
LiSbBr crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two LiSbBr clusters. Li(1) is bonded in a single-bond geometry to one Br(1) atom. The Li(1)-Br(1) bond length is 0.34 Å. Sb(1) is bonded in a distorted single-bond geometry to one Br(1) atom. The Sb(1)-Br(1) bond length is 3.24 Å. Br(1) is bonded in a single-bond geometry to one Li(1) and one Sb(1) atom.