data_YSb2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.74
_cell_length_b   5.74
_cell_length_c   5.74
_cell_angle_alpha   135.62
_cell_angle_beta   135.62
_cell_angle_gamma   64.56
_symmetry_Int_Tables_number   1
_chemical_formula_structural   YSb2W
_chemical_formula_sum   'Y1 Sb2 W1'
_cell_volume   91.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y3  1  0.0  0.0  0.0  1.0
  Sb  Sb0  1  0.17  0.0  0.43  1.0
  Sb  Sb1  1  0.0  0.0  0.85  1.0
  W  W2  1  0.0  0.17  0.43  1.0

data_YSb2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.34
_cell_length_b   4.34
_cell_length_c   5.74
_cell_angle_alpha   112.19
_cell_angle_beta   112.19
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   YSb2W
_chemical_formula_sum   'Y1 Sb2 W1'
_cell_volume   91.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.0  0.0  0.0  1.0
  Sb  Sb1  1  0.15  0.0  0.15  1.0
  Sb  Sb2  1  0.57  0.0  0.74  1.0
  W  W3  1  0.74  0.17  0.74  1.0

Y Sb Sb W
YWSb2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one YWSb2 cluster. Y(1) is bonded in a distorted single-bond geometry to one W(1), one Sb(1), and one Sb(2) atom. The Y(1)-W(1) bond length is 1.88 Å. The Y(1)-Sb(1) bond length is 1.88 Å. The Y(1)-Sb(2) bond length is 0.85 Å. W(1) is bonded in a 2-coordinate geometry to one Y(1) and one Sb(1) atom. The W(1)-Sb(1) bond length is 1.03 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 2-coordinate geometry to one Y(1) and one W(1) atom. In the second Sb site, Sb(2) is bonded in a single-bond geometry to one Y(1) atom.