data_NaSiPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.93
_cell_length_b   5.93
_cell_length_c   5.93
_cell_angle_alpha   148.67
_cell_angle_beta   148.67
_cell_angle_gamma   44.9
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaSiPd
_chemical_formula_sum   'Na1 Si1 Pd1'
_cell_volume   56.08
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.02  1.0
  Si  Si2  1  0.0  0.0  0.7  1.0
  Pd  Pd1  1  0.0  0.0  0.23  1.0

data_NaSiPd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.53
_cell_length_b   4.53
_cell_length_c   5.93
_cell_angle_alpha   90.0
_cell_angle_beta   112.45
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   NaSiPd
_chemical_formula_sum   'Na2 Si2 Pd2'
_cell_volume   112.16
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  2  0.0  0.0  0.98  1.0
  Si  Si1  2  0.0  0.0  0.3  1.0
  Pd  Pd2  2  0.0  0.0  0.77  1.0

Na Si Pd
NaPdSi crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two NaPdSi clusters. Na(1) is bonded in a distorted linear geometry to one Pd(1) and one Si(1) atom. The Na(1)-Pd(1) bond length is 1.28 Å. The Na(1)-Si(1) bond length is 1.88 Å. Pd(1) is bonded in a single-bond geometry to one Na(1) atom. Si(1) is bonded in a distorted single-bond geometry to one Na(1) atom.