data_VAgCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.57
_cell_length_b   3.57
_cell_length_c   6.58
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VAgCl2
_chemical_formula_sum   'V1 Ag1 Cl2'
_cell_volume   83.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.5  1.0
  Ag  Ag0  1  0.78  0.78  0.17  1.0
  Cl  Cl1  1  0.0  0.0  0.58  1.0
  Cl  Cl2  1  0.78  0.78  0.2  1.0

data_VAgCl2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.04
_cell_length_b   5.04
_cell_length_c   6.58
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VAgCl2
_chemical_formula_sum   'V2 Ag2 Cl4'
_cell_volume   167.28
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.5  1.0
  Ag  Ag1  2  0.28  0.5  0.17  1.0
  Cl  Cl2  2  0.0  0.0  0.58  1.0
  Cl  Cl3  2  0.28  0.5  0.2  1.0

V Ag Cl Cl
VClAgCl is High Pressure Cadmuum Telluride structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two hydrochloric acid silver molecules and two VCl clusters. In each VCl cluster, V(1) is bonded in a distorted single-bond geometry to one Cl(1) atom. The V(1)-Cl(1) bond length is 0.47 Å. Cl(1) is bonded in a single-bond geometry to one V(1) atom.