data_CoGePd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.9
_cell_length_b   2.9
_cell_length_c   6.97
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CoGePd2
_chemical_formula_sum   'Co1 Ge1 Pd2'
_cell_volume   58.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.0  0.0  1.0
  Ge  Ge1  1  0.0  0.0  0.49  1.0
  Pd  Pd2  1  0.45  0.45  0.26  1.0
  Pd  Pd3  1  0.45  0.45  0.72  1.0

data_CoGePd2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.1
_cell_length_b   4.1
_cell_length_c   6.97
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   CoGePd2
_chemical_formula_sum   'Co2 Ge2 Pd4'
_cell_volume   117.07
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  2  0.0  0.0  0.0  1.0
  Ge  Ge1  2  0.0  0.0  0.49  1.0
  Pd  Pd2  2  0.45  0.0  0.26  1.0
  Pd  Pd3  2  0.45  0.0  0.72  1.0

Co Ge Pd Pd
CoPd2Ge crystallizes in the monoclinic Cm space group. Co(1) is bonded in a 12-coordinate geometry to four equivalent Co(1), four equivalent Pd(1), and four equivalent Pd(2) atoms. All Co(1)-Co(1) bond lengths are 2.90 Å. There are a spread of Co(1)-Pd(1) bond distances ranging from 2.56-2.88 Å. There are a spread of Co(1)-Pd(2) bond distances ranging from 2.69-3.00 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 8-coordinate geometry to four equivalent Co(1) and four equivalent Ge(1) atoms. There are a spread of Pd(1)-Ge(1) bond distances ranging from 2.44-2.77 Å. In the second Pd site, Pd(2) is bonded in a 8-coordinate geometry to four equivalent Co(1) and four equivalent Ge(1) atoms. There are a spread of Pd(2)-Ge(1) bond distances ranging from 2.44-2.77 Å. Ge(1) is bonded in a 8-coordinate geometry to four equivalent Pd(1) and four equivalent Pd(2) atoms.