data_Zn2PAu
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.91
_cell_length_b   4.91
_cell_length_c   2.72
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   93.11
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zn2PAu
_chemical_formula_sum   'Zn2 P1 Au1'
_cell_volume   65.4
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn2  1  0.69  0.78  0.36  1.0
  Zn  Zn3  1  0.69  0.22  0.36  1.0
  P  P1  1  0.0  0.0  0.0  1.0
  Au  Au0  1  0.38  0.0  0.0  1.0

data_Zn2PAu
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.72
_cell_length_b   4.91
_cell_length_c   4.91
_cell_angle_alpha   93.11
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zn2PAu
_chemical_formula_sum   'Zn2 P1 Au1'
_cell_volume   65.4
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.36  0.69  0.22  1.0
  Zn  Zn1  1  0.36  0.69  0.78  1.0
  P  P2  1  0.0  0.0  0.0  1.0
  Au  Au3  1  0.0  0.38  0.0  1.0

Zn Zn P Au
AuZn2P crystallizes in the triclinic P1 space group. Au(1) is bonded in a 5-coordinate geometry to two equivalent Zn(1), two equivalent Zn(2), and one P(1) atom. There is one shorter (2.15 Å) and one longer (2.59 Å) Au(1)-Zn(1) bond length. There is one shorter (2.07 Å) and one longer (2.52 Å) Au(1)-Zn(2) bond length. The Au(1)-P(1) bond length is 1.84 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 2-coordinate geometry to two equivalent Au(1), two equivalent Zn(2), and two equivalent P(1) atoms. There is one shorter (2.14 Å) and one longer (2.77 Å) Zn(1)-Zn(2) bond length. There is one shorter (2.07 Å) and one longer (2.52 Å) Zn(1)-P(1) bond length. In the second Zn site, Zn(2) is bonded in a 8-coordinate geometry to two equivalent Au(1), two equivalent Zn(1), two equivalent Zn(2), and two equivalent P(1) atoms. Both Zn(2)-Zn(2) bond lengths are 2.72 Å. There is one shorter (2.15 Å) and one longer (2.59 Å) Zn(2)-P(1) bond length. P(1) is bonded in a 5-coordinate geometry to one Au(1), two equivalent Zn(1), and two equivalent Zn(2) atoms.