data_V2ZnIn
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.74
_cell_length_b   4.21
_cell_length_c   5.41
_cell_angle_alpha   90.0
_cell_angle_beta   93.8
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2ZnIn
_chemical_formula_sum   'V2 Zn1 In1'
_cell_volume   62.11
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V1  1  0.16  0.1  0.18  1.0
  V  V2  1  0.22  0.1  0.22  1.0
  Zn  Zn3  1  0.0  0.0  0.0  1.0
  In  In0  1  0.82  0.0  0.7  1.0

data_V2ZnIn
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.74
_cell_length_b   4.21
_cell_length_c   5.41
_cell_angle_alpha   90.0
_cell_angle_beta   93.8
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2ZnIn
_chemical_formula_sum   'V2 Zn1 In1'
_cell_volume   62.11
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.16  0.1  0.18  1.0
  V  V1  1  0.22  0.1  0.22  1.0
  Zn  Zn2  1  0.0  0.0  0.0  1.0
  In  In3  1  0.82  0.0  0.7  1.0

V V Zn In
V2ZnIn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one V2ZnIn cluster. There are two inequivalent V sites. In the first V site, V(1) is bonded in a bent 150 degrees geometry to one V(2) and one Zn(1) atom. The V(1)-V(2) bond length is 0.29 Å. The V(1)-Zn(1) bond length is 1.11 Å. In the second V site, V(2) is bonded in a single-bond geometry to one V(1) atom. Zn(1) is bonded in a bent 150 degrees geometry to one V(1) and one In(1) atom. The Zn(1)-In(1) bond length is 1.67 Å. In(1) is bonded in a distorted single-bond geometry to one Zn(1) atom.