data_Cd5Ru
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.82
_cell_length_b   5.82
_cell_length_c   7.28
_cell_angle_alpha   105.28
_cell_angle_beta   105.28
_cell_angle_gamma   30.18
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd5Ru
_chemical_formula_sum   'Cd5 Ru1'
_cell_volume   119.28
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.14  0.0  0.96  1.0
  Cd  Cd1  1  0.8  0.0  0.79  1.0
  Cd  Cd2  1  0.88  0.0  0.3  1.0
  Cd  Cd3  1  0.4  0.0  0.32  1.0
  Cd  Cd4  1  0.26  0.0  0.83  1.0
  Ru  Ru5  1  0.24  0.0  0.67  1.0

data_Cd5Ru
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.03
_cell_length_b   5.82
_cell_length_c   7.28
_cell_angle_alpha   105.28
_cell_angle_beta   90.0
_cell_angle_gamma   105.09
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd5Ru
_chemical_formula_sum   'Cd5 Ru1'
_cell_volume   119.28
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.12  0.7  1.0
  Cd  Cd1  1  0.0  0.2  0.21  1.0
  Cd  Cd2  1  0.0  0.6  0.68  1.0
  Cd  Cd3  1  0.0  0.74  0.17  1.0
  Cd  Cd4  1  0.0  0.86  0.04  1.0
  Ru  Ru5  1  0.0  0.76  0.33  1.0

Cd Cd Cd Cd Cd Ru
RuCd5 crystallizes in the triclinic P1 space group. Ru(1) is bonded in a single-bond geometry to one Cd(3), one Cd(4), and one Cd(5) atom. The Ru(1)-Cd(3) bond length is 2.93 Å. The Ru(1)-Cd(4) bond length is 2.91 Å. The Ru(1)-Cd(5) bond length is 1.14 Å. There are five inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 1-coordinate geometry to one Cd(2), one Cd(4), and one Cd(5) atom. The Cd(1)-Cd(2) bond length is 2.04 Å. The Cd(1)-Cd(4) bond length is 2.66 Å. The Cd(1)-Cd(5) bond length is 1.29 Å. In the second Cd site, Cd(2) is bonded in a 1-coordinate geometry to one Cd(1) atom. In the third Cd site, Cd(3) is bonded in a 1-coordinate geometry to one Ru(1) and two equivalent Cd(4) atoms. There is one shorter (2.84 Å) and one longer (2.99 Å) Cd(3)-Cd(4) bond length. In the fourth Cd site, Cd(4) is bonded in a 6-coordinate geometry to one Ru(1), one Cd(1), two equivalent Cd(3), and two equivalent Cd(4) atoms. Both Cd(4)-Cd(4) bond lengths are 3.03 Å. In the fifth Cd site, Cd(5) is bonded in a distorted single-bond geometry to one Ru(1) and one Cd(1) atom.