data_Zr2InAu
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.15
_cell_length_b   3.15
_cell_length_c   8.45
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zr2InAu
_chemical_formula_sum   'Zr2 In1 Au1'
_cell_volume   83.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr2  1  0.58  0.58  0.23  1.0
  Zr  Zr3  1  0.58  0.58  0.22  1.0
  In  In1  1  0.0  0.0  0.0  1.0
  Au  Au0  1  0.0  0.0  0.22  1.0

data_Zr2InAu
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.46
_cell_length_b   4.46
_cell_length_c   8.45
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Zr2InAu
_chemical_formula_sum   'Zr4 In2 Au2'
_cell_volume   167.94
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  2  0.08  0.5  0.22  1.0
  Zr  Zr1  2  0.08  0.5  0.23  1.0
  In  In2  2  0.0  0.0  0.0  1.0
  Au  Au3  2  0.0  0.0  0.22  1.0

Zr Zr In Au
(Zr)2AuIn crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two AuIn clusters and two zirconium molecules. In each AuIn cluster, Au(1) is bonded in a 1-coordinate geometry to one In(1) atom. The Au(1)-In(1) bond length is 1.88 Å. In(1) is bonded in a single-bond geometry to one Au(1) atom.