data_Sc2BiW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.17
_cell_length_b   4.95
_cell_length_c   5.42
_cell_angle_alpha   90.0
_cell_angle_beta   95.53
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sc2BiW
_chemical_formula_sum   'Sc2 Bi1 W1'
_cell_volume   84.79
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc1  1  0.52  0.0  0.18  1.0
  Sc  Sc2  1  0.4  0.48  0.66  1.0
  Bi  Bi0  1  0.81  0.48  0.22  1.0
  W  W3  1  0.89  0.0  0.44  1.0

data_Sc2BiW
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.17
_cell_length_b   4.95
_cell_length_c   5.42
_cell_angle_alpha   90.0
_cell_angle_beta   95.53
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sc2BiW
_chemical_formula_sum   'Sc2 Bi1 W1'
_cell_volume   84.79
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.4  0.48  0.66  1.0
  Sc  Sc1  1  0.52  0.0  0.18  1.0
  Bi  Bi2  1  0.81  0.48  0.22  1.0
  W  W3  1  0.89  0.0  0.44  1.0

Sc Sc Bi W
Sc2WBi crystallizes in the triclinic P1 space group. There are two inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in a distorted single-bond geometry to one W(1) and four equivalent Bi(1) atoms. The Sc(1)-W(1) bond length is 1.72 Å. There are a spread of Sc(1)-Bi(1) bond distances ranging from 2.53-3.44 Å. In the second Sc site, Sc(2) is bonded in a 7-coordinate geometry to four equivalent W(1) and four equivalent Bi(1) atoms. There are a spread of Sc(2)-W(1) bond distances ranging from 3.03-3.32 Å. There are a spread of Sc(2)-Bi(1) bond distances ranging from 2.83-3.71 Å. W(1) is bonded in a distorted single-bond geometry to one Sc(1), four equivalent Sc(2), and two equivalent Bi(1) atoms. There is one shorter (2.64 Å) and one longer (2.86 Å) W(1)-Bi(1) bond length. Bi(1) is bonded in a 12-coordinate geometry to four equivalent Sc(1), four equivalent Sc(2), two equivalent W(1), and two equivalent Bi(1) atoms. Both Bi(1)-Bi(1) bond lengths are 3.17 Å.