data_ScVTe2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.9
_cell_length_b   4.9
_cell_length_c   4.9
_cell_angle_alpha   121.2
_cell_angle_beta   121.2
_cell_angle_gamma   87.93
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScVTe2
_chemical_formula_sum   'Sc1 V1 Te2'
_cell_volume   81.59
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.0  0.0  0.0  1.0
  V  V3  1  0.0  0.0  0.53  1.0
  Te  Te1  1  0.41  0.0  0.76  1.0
  Te  Te2  1  0.0  0.41  0.76  1.0

data_ScVTe2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.8
_cell_length_b   6.8
_cell_length_c   4.9
_cell_angle_alpha   90.0
_cell_angle_beta   133.96
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ScVTe2
_chemical_formula_sum   'Sc2 V2 Te4'
_cell_volume   163.18
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  2  0.0  0.0  0.0  1.0
  V  V1  2  0.0  0.0  0.53  1.0
  Te  Te2  4  0.3  0.3  0.36  1.0

Sc V Te Te
ScVTe2 crystallizes in the monoclinic Cm space group. Sc(1) is bonded in a 6-coordinate geometry to two equivalent V(1) and four equivalent Te(1) atoms. There is one shorter (2.32 Å) and one longer (2.58 Å) Sc(1)-V(1) bond length. There are two shorter (2.52 Å) and two longer (2.77 Å) Sc(1)-Te(1) bond lengths. V(1) is bonded in a distorted water-like geometry to two equivalent Sc(1) and two equivalent Te(1) atoms. Both V(1)-Te(1) bond lengths are 1.70 Å. Te(1) is bonded in a 2-coordinate geometry to two equivalent Sc(1) and one V(1) atom.