data_MnAs2Pt
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.1
_cell_length_b   3.1
_cell_length_c   6.18
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnAs2Pt
_chemical_formula_sum   'Mn1 As2 Pt1'
_cell_volume   59.52
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn2  1  0.0  0.0  0.0  1.0
  As  As0  1  0.55  0.55  0.78  1.0
  As  As1  1  0.55  0.55  0.4  1.0
  Pt  Pt3  1  0.0  0.0  0.09  1.0

data_MnAs2Pt
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.39
_cell_length_b   4.39
_cell_length_c   6.18
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   MnAs2Pt
_chemical_formula_sum   'Mn2 As4 Pt2'
_cell_volume   119.04
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  2  0.0  0.0  0.0  1.0
  As  As1  2  0.05  0.5  0.4  1.0
  As  As2  2  0.05  0.5  0.78  1.0
  Pt  Pt3  2  0.0  0.0  0.09  1.0

Mn As As Pt
MnPtAs2 crystallizes in the monoclinic Cm space group. Mn(1) is bonded in a single-bond geometry to one Pt(1) and four equivalent As(1) atoms. The Mn(1)-Pt(1) bond length is 0.55 Å. There are a spread of Mn(1)-As(1) bond distances ranging from 2.40-2.78 Å. Pt(1) is bonded in a single-bond geometry to one Mn(1) and four equivalent As(2) atoms. There are a spread of Pt(1)-As(2) bond distances ranging from 2.75-3.09 Å. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 5-coordinate geometry to four equivalent Mn(1) and one As(2) atom. The As(1)-As(2) bond length is 2.33 Å. In the second As site, As(2) is bonded in a 5-coordinate geometry to four equivalent Pt(1) and one As(1) atom.