data_Tl2GaMo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.34
_cell_length_b   5.34
_cell_length_c   3.11
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   109.11
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Tl2GaMo
_chemical_formula_sum   'Tl2 Ga1 Mo1'
_cell_volume   83.62
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl2  1  0.55  0.83  0.55  1.0
  Tl  Tl3  1  0.55  0.17  0.55  1.0
  Ga  Ga0  1  0.0  0.0  0.0  1.0
  Mo  Mo1  1  0.09  0.0  0.0  1.0

data_Tl2GaMo
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.11
_cell_length_b   5.34
_cell_length_c   5.34
_cell_angle_alpha   109.11
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Tl2GaMo
_chemical_formula_sum   'Tl2 Ga1 Mo1'
_cell_volume   83.62
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.55  0.55  0.17  1.0
  Tl  Tl1  1  0.55  0.55  0.83  1.0
  Ga  Ga2  1  0.0  0.0  0.0  1.0
  Mo  Mo3  1  0.0  0.09  0.0  1.0

Tl Tl Ga Mo
MoTl2Ga crystallizes in the triclinic P1 space group. Mo(1) is bonded in a single-bond geometry to two equivalent Tl(1), two equivalent Tl(2), and one Ga(1) atom. There is one shorter (3.18 Å) and one longer (3.33 Å) Mo(1)-Tl(1) bond length. There is one shorter (2.67 Å) and one longer (2.86 Å) Mo(1)-Tl(2) bond length. The Mo(1)-Ga(1) bond length is 0.51 Å. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 8-coordinate geometry to two equivalent Mo(1), two equivalent Tl(1), two equivalent Tl(2), and two equivalent Ga(1) atoms. Both Tl(1)-Tl(1) bond lengths are 3.11 Å. There is one shorter (1.85 Å) and one longer (3.48 Å) Tl(1)-Tl(2) bond length. There is one shorter (2.67 Å) and one longer (2.86 Å) Tl(1)-Ga(1) bond length. In the second Tl site, Tl(2) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and two equivalent Tl(1) atoms. Ga(1) is bonded in a single-bond geometry to one Mo(1) and two equivalent Tl(1) atoms.