data_KTiInRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.83
_cell_length_b   4.83
_cell_length_c   4.83
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KTiInRh
_chemical_formula_sum   'K1 Ti1 In1 Rh1'
_cell_volume   79.58
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K1  1  0.0  0.0  0.0  1.0
  Ti  Ti3  1  0.12  0.12  0.12  1.0
  In  In0  1  0.71  0.71  0.71  1.0
  Rh  Rh2  1  0.41  0.41  0.41  1.0

data_KTiInRh
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.83
_cell_length_b   4.83
_cell_length_c   11.83
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   KTiInRh
_chemical_formula_sum   'K3 Ti3 In3 Rh3'
_cell_volume   238.73
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  3  0.0  0.0  0.0  1.0
  Ti  Ti1  3  0.0  0.0  0.88  1.0
  In  In2  3  0.0  0.0  0.29  1.0
  Rh  Rh3  3  0.0  0.0  0.59  1.0

K Ti In Rh
KTiRhIn crystallizes in the trigonal R3m space group. K(1) is bonded in a single-bond geometry to one Ti(1), three equivalent Rh(1), and four equivalent In(1) atoms. The K(1)-Ti(1) bond length is 1.43 Å. All K(1)-Rh(1) bond lengths are 2.95 Å. There are three shorter (2.83 Å) and one longer (3.47 Å) K(1)-In(1) bond length. Ti(1) is bonded in a single-bond geometry to one K(1), four equivalent Rh(1), and three equivalent In(1) atoms. There are three shorter (2.83 Å) and one longer (3.47 Å) Ti(1)-Rh(1) bond length. All Ti(1)-In(1) bond lengths are 2.95 Å. Rh(1) is bonded in a 11-coordinate geometry to three equivalent K(1), four equivalent Ti(1), and four equivalent In(1) atoms. There are three shorter (2.83 Å) and one longer (3.47 Å) Rh(1)-In(1) bond length. In(1) is bonded in a 11-coordinate geometry to four equivalent K(1), three equivalent Ti(1), and four equivalent Rh(1) atoms.