data_CsTeRh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.0
_cell_length_b   5.0
_cell_length_c   5.0
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CsTeRh3
_chemical_formula_sum   'Cs1 Te1 Rh3'
_cell_volume   125.13
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.5  0.5  0.5  1.0
  Te  Te1  1  0.0  0.0  0.0  1.0
  Rh  Rh2  1  0.5  0.0  0.5  1.0
  Rh  Rh3  1  0.5  0.5  0.0  1.0
  Rh  Rh4  1  0.0  0.5  0.5  1.0

data_CsTeRh3
_symmetry_space_group_name_H-M   Pm-3m
_cell_length_a   5.0
_cell_length_b   5.0
_cell_length_c   5.0
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   221
_chemical_formula_structural   CsTeRh3
_chemical_formula_sum   'Cs1 Te1 Rh3'
_cell_volume   125.13
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
  3  '-y, x, z'
  4  'y, -x, -z'
  5  '-x, -y, z'
  6  'x, y, -z'
  7  'y, -x, z'
  8  '-y, x, -z'
  9  'x, -y, -z'
  10  '-x, y, z'
  11  '-y, -x, -z'
  12  'y, x, z'
  13  '-x, y, -z'
  14  'x, -y, z'
  15  'y, x, -z'
  16  '-y, -x, z'
  17  'z, x, y'
  18  '-z, -x, -y'
  19  'z, -y, x'
  20  '-z, y, -x'
  21  'z, -x, -y'
  22  '-z, x, y'
  23  'z, y, -x'
  24  '-z, -y, x'
  25  '-z, x, -y'
  26  'z, -x, y'
  27  '-z, -y, -x'
  28  'z, y, x'
  29  '-z, -x, y'
  30  'z, x, -y'
  31  '-z, y, x'
  32  'z, -y, -x'
  33  'y, z, x'
  34  '-y, -z, -x'
  35  'x, z, -y'
  36  '-x, -z, y'
  37  '-y, z, -x'
  38  'y, -z, x'
  39  '-x, z, y'
  40  'x, -z, -y'
  41  '-y, -z, x'
  42  'y, z, -x'
  43  '-x, -z, -y'
  44  'x, z, y'
  45  'y, -z, -x'
  46  '-y, z, x'
  47  'x, -z, y'
  48  '-x, z, -y'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.5  0.5  0.5  1.0
  Te  Te1  1  0.0  0.0  0.0  1.0
  Rh  Rh2  3  0.0  0.5  0.5  1.0

Cs Te Rh Rh Rh
CsRh3Te is (Cubic) Perovskite structured and crystallizes in the trigonal R3m space group. Cs(1) is bonded to six equivalent Rh(1) atoms to form CsRh6 octahedra that share corners with six equivalent Cs(1)Rh6 octahedra and faces with eight equivalent Te(1)Rh12 cuboctahedra. The corner-sharing octahedra are not tilted. There are three shorter (2.50 Å) and three longer (2.51 Å) Cs(1)-Rh(1) bond lengths. Rh(1) is bonded in a linear geometry to two equivalent Cs(1) and four equivalent Te(1) atoms. There is one shorter (3.53 Å) and three longer (3.54 Å) Rh(1)-Te(1) bond lengths. Te(1) is bonded to twelve equivalent Rh(1) atoms to form TeRh12 cuboctahedra that share corners with twelve equivalent Te(1)Rh12 cuboctahedra, faces with six equivalent Te(1)Rh12 cuboctahedra, and faces with eight equivalent Cs(1)Rh6 octahedra.