data_Re2SbCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.62
_cell_length_b   4.62
_cell_length_c   4.62
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Re2SbCl
_chemical_formula_sum   'Re2 Sb1 Cl1'
_cell_volume   69.95
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re1  1  0.27  0.27  0.27  1.0
  Re  Re2  1  0.64  0.64  0.64  1.0
  Sb  Sb3  1  0.91  0.91  0.91  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Re2SbCl
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.62
_cell_length_b   4.62
_cell_length_c   11.33
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   Re2SbCl
_chemical_formula_sum   'Re6 Sb3 Cl3'
_cell_volume   209.84
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  3  0.0  0.0  0.36  1.0
  Re  Re1  3  0.0  0.0  0.73  1.0
  Sb  Sb2  3  0.0  0.0  0.09  1.0
  Cl  Cl3  3  0.0  0.0  0.0  1.0

Re Re Sb Cl
Re2SbCl crystallizes in the trigonal R3m space group. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 10-coordinate geometry to three equivalent Re(2), three equivalent Sb(1), and four equivalent Cl(1) atoms. All Re(1)-Re(2) bond lengths are 2.69 Å. All Re(1)-Sb(1) bond lengths are 2.69 Å. There are three shorter (2.76 Å) and one longer (3.06 Å) Re(1)-Cl(1) bond length. In the second Re site, Re(2) is bonded in a 10-coordinate geometry to three equivalent Re(1), four equivalent Sb(1), and three equivalent Cl(1) atoms. There are three shorter (2.76 Å) and one longer (3.06 Å) Re(2)-Sb(1) bond length. All Re(2)-Cl(1) bond lengths are 2.69 Å. Sb(1) is bonded in a single-bond geometry to three equivalent Re(1), four equivalent Re(2), and one Cl(1) atom. The Sb(1)-Cl(1) bond length is 1.07 Å. Cl(1) is bonded in a single-bond geometry to three equivalent Re(2), four equivalent Re(1), and one Sb(1) atom.