data_Na2MnSn
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.33
_cell_length_b   3.33
_cell_length_c   9.21
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na2MnSn
_chemical_formula_sum   'Na2 Mn1 Sn1'
_cell_volume   102.16
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na1  1  0.67  0.67  0.86  1.0
  Na  Na2  1  0.0  0.0  0.59  1.0
  Mn  Mn0  1  0.0  0.0  0.59  1.0
  Sn  Sn3  1  0.67  0.67  0.98  1.0

data_Na2MnSn
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.71
_cell_length_b   4.71
_cell_length_c   9.21
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Na2MnSn
_chemical_formula_sum   'Na4 Mn2 Sn2'
_cell_volume   204.33
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  2  0.0  0.0  0.59  1.0
  Na  Na1  2  0.17  0.5  0.86  1.0
  Mn  Mn2  2  0.0  0.0  0.59  1.0
  Sn  Sn3  2  0.17  0.5  0.98  1.0

NaMnNaSn is beta oxygen-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two manganese;sodium molecules and two sodium stannanide molecules.