data_Ho(Ge2Rh3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.24
_cell_length_b   7.24
_cell_length_c   3.84
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ho(Ge2Rh3)2
_chemical_formula_sum   'Ho1 Ge4 Rh6'
_cell_volume   174.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.62  0.09  0.0  1.0
  Ge  Ge1  1  0.49  0.32  0.92  1.0
  Ge  Ge2  1  0.0  0.89  0.92  1.0
  Ge  Ge3  1  0.51  0.32  0.92  1.0
  Ge  Ge4  1  0.0  0.0  0.0  1.0
  Rh  Rh5  1  0.55  0.01  0.0  1.0
  Rh  Rh6  1  0.0  0.51  0.0  1.0
  Rh  Rh7  1  0.45  0.01  0.0  1.0
  Rh  Rh8  1  0.77  0.84  0.92  1.0
  Rh  Rh9  1  0.62  0.58  0.92  1.0
  Rh  Rh10  1  0.46  0.84  0.92  1.0

data_Ho(Ge2Rh3)2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.84
_cell_length_b   7.24
_cell_length_c   7.24
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ho(Ge2Rh3)2
_chemical_formula_sum   'Ho1 Ge4 Rh6'
_cell_volume   174.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  -0.0  0.62  0.09  1.0
  Ge  Ge1  1  0.0  0.0  0.0  1.0
  Ge  Ge2  1  0.92  0.0  0.89  1.0
  Ge  Ge3  1  0.92  0.49  0.32  1.0
  Ge  Ge4  1  0.92  0.51  0.32  1.0
  Rh  Rh5  1  -0.0  0.45  0.01  1.0
  Rh  Rh6  1  -0.0  0.55  0.01  1.0
  Rh  Rh7  1  -0.0  0.0  0.51  1.0
  Rh  Rh8  1  0.92  0.46  0.84  1.0
  Rh  Rh9  1  0.92  0.62  0.58  1.0
  Rh  Rh10  1  0.92  0.77  0.84  1.0

Ho Ge Ge Ge Ge Rh Rh Rh Rh Rh Rh
Ho(Rh3Ge2)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Ho(Rh3Ge2)2 cluster. Ho(1) is bonded in a single-bond geometry to one Rh(1) and one Rh(2) atom. The Ho(1)-Rh(1) bond length is 0.51 Å. The Ho(1)-Rh(2) bond length is 2.91 Å. There are six inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted single-bond geometry to one Ho(1), one Rh(3), and one Rh(6) atom. The Rh(1)-Rh(3) bond length is 0.78 Å. The Rh(1)-Rh(6) bond length is 1.10 Å. In the second Rh site, Rh(2) is bonded in a 2-coordinate geometry to one Ho(1) and one Ge(2) atom. The Rh(2)-Ge(2) bond length is 2.81 Å. In the third Rh site, Rh(3) is bonded in a distorted single-bond geometry to one Rh(1) atom. In the fourth Rh site, Rh(4) is bonded in a 3-coordinate geometry to one Rh(5), one Ge(2), and one Ge(4) atom. The Rh(4)-Rh(5) bond length is 1.68 Å. The Rh(4)-Ge(2) bond length is 1.50 Å. The Rh(4)-Ge(4) bond length is 1.49 Å. In the fifth Rh site, Rh(5) is bonded in a 3-coordinate geometry to one Rh(4), one Ge(1), and one Ge(3) atom. The Rh(5)-Ge(1) bond length is 1.62 Å. The Rh(5)-Ge(3) bond length is 1.63 Å. In the sixth Rh site, Rh(6) is bonded in a distorted single-bond geometry to one Rh(1) atom. There are four inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a single-bond geometry to one Rh(5) and one Ge(3) atom. The Ge(1)-Ge(3) bond length is 0.19 Å. In the second Ge site, Ge(2) is bonded in a 2-coordinate geometry to one Rh(2), one Rh(4), and one Ge(4) atom. The Ge(2)-Ge(4) bond length is 0.82 Å. In the third Ge site, Ge(3) is bonded in a single-bond geometry to one Rh(5) and one Ge(1) atom. In the fourth Ge site, Ge(4) is bonded in a 2-coordinate geometry to one Rh(4) and one Ge(2) atom.