data_Co2TcAg
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.08
_cell_length_b   5.17
_cell_length_c   5.17
_cell_angle_alpha   29.65
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Co2TcAg
_chemical_formula_sum   'Co2 Tc1 Ag1'
_cell_volume   53.86
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co1  1  0.0  0.0  0.16  1.0
  Co  Co2  1  0.04  0.0  0.43  1.0
  Tc  Tc3  1  0.0  0.0  0.39  1.0
  Ag  Ag0  1  0.04  0.0  0.03  1.0

data_Co2TcAg
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.64
_cell_length_b   4.08
_cell_length_c   5.17
_cell_angle_alpha   90.0
_cell_angle_beta   104.83
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Co2TcAg
_chemical_formula_sum   'Co2 Tc1 Ag1'
_cell_volume   53.86
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.57  0.04  0.57  1.0
  Co  Co1  1  0.84  0.0  0.84  1.0
  Tc  Tc2  1  0.61  0.0  0.61  1.0
  Ag  Ag3  1  0.97  0.04  0.97  1.0

Co Co Tc Ag
TcCo2Ag crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one TcCo2Ag cluster. Tc(1) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one Co(2) atom. The Tc(1)-Co(1) bond length is 1.16 Å. The Tc(1)-Co(2) bond length is 0.27 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted linear geometry to one Tc(1) and one Ag(1) atom. The Co(1)-Ag(1) bond length is 0.71 Å. In the second Co site, Co(2) is bonded in a single-bond geometry to one Tc(1) atom. Ag(1) is bonded in a single-bond geometry to one Co(1) atom.