data_Li2PtCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.52
_cell_length_b   4.52
_cell_length_c   3.01
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   101.04
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2PtCl
_chemical_formula_sum   'Li2 Pt1 Cl1'
_cell_volume   60.48
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.44  0.75  0.51  1.0
  Li  Li2  1  0.44  0.25  0.51  1.0
  Pt  Pt3  1  0.88  0.0  0.0  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Li2PtCl
_symmetry_space_group_name_H-M   Pm
_cell_length_a   4.52
_cell_length_b   3.01
_cell_length_c   4.52
_cell_angle_alpha   90.0
_cell_angle_beta   101.04
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   Li2PtCl
_chemical_formula_sum   'Li2 Pt1 Cl1'
_cell_volume   60.48
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.44  0.5  0.25  1.0
  Li  Li1  1  0.44  0.5  0.75  1.0
  Pt  Pt2  1  0.88  0.0  0.0  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Li Li Pt Cl
Li2PtCl crystallizes in the triclinic P1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to two equivalent Li(2), two equivalent Pt(1), and two equivalent Cl(1) atoms. There is one shorter (2.22 Å) and one longer (2.30 Å) Li(1)-Li(2) bond length. There is one shorter (2.57 Å) and one longer (2.59 Å) Li(1)-Pt(1) bond length. There is one shorter (2.89 Å) and one longer (2.91 Å) Li(1)-Cl(1) bond length. In the second Li site, Li(2) is bonded in a 2-coordinate geometry to two equivalent Li(1) and two equivalent Cl(1) atoms. There is one shorter (2.57 Å) and one longer (2.59 Å) Li(2)-Cl(1) bond length. Pt(1) is bonded in a single-bond geometry to two equivalent Li(1) and one Cl(1) atom. The Pt(1)-Cl(1) bond length is 0.56 Å. Cl(1) is bonded in a single-bond geometry to two equivalent Li(1), two equivalent Li(2), and one Pt(1) atom.