data_V2Co
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.8
_cell_length_b   4.8
_cell_length_c   4.8
_cell_angle_alpha   146.78
_cell_angle_beta   142.01
_cell_angle_gamma   51.34
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2Co
_chemical_formula_sum   'V2 Co1'
_cell_volume   37.11
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V1  1  0.0  0.0  0.74  1.0
  V  V2  1  0.0  0.0  0.91  1.0
  Co  Co0  1  0.0  0.0  0.0  1.0

data_V2Co
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.74
_cell_length_b   3.13
_cell_length_c   4.8
_cell_angle_alpha   109.0
_cell_angle_beta   106.61
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2Co
_chemical_formula_sum   'V2 Co1'
_cell_volume   37.11
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.74  0.74  1.0
  V  V1  1  0.0  0.91  0.91  1.0
  Co  Co2  1  0.0  0.0  0.0  1.0

V V Co
VVCo is alpha Niobium phosphide-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VVCo cluster. There are two inequivalent V sites. In the first V site, V(1) is bonded in a single-bond geometry to one V(2) atom. The V(1)-V(2) bond length is 0.84 Å. In the second V site, V(2) is bonded in a distorted single-bond geometry to one V(1) and one Co(1) atom. The V(2)-Co(1) bond length is 0.41 Å. Co(1) is bonded in a single-bond geometry to one V(2) atom.