data_LaBMo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.26
_cell_length_b   4.26
_cell_length_c   3.58
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaBMo2
_chemical_formula_sum   'La1 B1 Mo2'
_cell_volume   64.98
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La1  1  0.13  0.13  0.0  1.0
  B  B0  1  0.0  0.0  0.0  1.0
  Mo  Mo2  1  0.13  0.0  0.79  1.0
  Mo  Mo3  1  0.0  0.13  0.79  1.0

data_LaBMo2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.03
_cell_length_b   6.03
_cell_length_c   3.58
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LaBMo2
_chemical_formula_sum   'La2 B2 Mo4'
_cell_volume   129.95
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  2  0.13  0.0  0.0  1.0
  B  B1  2  0.0  0.0  0.0  1.0
  Mo  Mo2  4  0.07  0.07  0.79  1.0

La B Mo Mo
LaMo2B is alpha Po structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two LaMo2B clusters. La(1) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one B(1) atom. Both La(1)-Mo(1) bond lengths are 0.94 Å. The La(1)-B(1) bond length is 0.79 Å. Mo(1) is bonded in a 3-coordinate geometry to one La(1), one Mo(1), and one B(1) atom. The Mo(1)-Mo(1) bond length is 0.79 Å. The Mo(1)-B(1) bond length is 0.94 Å. B(1) is bonded in a single-bond geometry to one La(1) and two equivalent Mo(1) atoms.