data_Mg2CdRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.46
_cell_length_b   9.46
_cell_length_c   9.46
_cell_angle_alpha   18.57
_cell_angle_beta   18.57
_cell_angle_gamma   18.57
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mg2CdRh
_chemical_formula_sum   'Mg2 Cd1 Rh1'
_cell_volume   75.02
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg1  1  0.0  0.0  0.29  1.0
  Mg  Mg2  1  0.0  0.0  0.6  1.0
  Cd  Cd0  1  0.0  0.0  0.94  1.0
  Rh  Rh3  1  0.0  0.0  0.0  1.0

data_Mg2CdRh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.29
_cell_length_b   3.05
_cell_length_c   9.46
_cell_angle_alpha   90.0
_cell_angle_beta   100.73
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Mg2CdRh
_chemical_formula_sum   'Mg4 Cd2 Rh2'
_cell_volume   150.05
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  2  -0.0  0.0  0.4  1.0
  Mg  Mg1  2  0.0  0.0  0.71  1.0
  Cd  Cd2  2  -0.0  0.0  0.06  1.0
  Rh  Rh3  2  -0.0  0.0  0.0  1.0

Mg Mg Cd Rh
Mg2RhCd crystallizes in the monoclinic Cm space group. There are two inequivalent Mg sites. In the first Mg site, Mg(1) is bonded in a single-bond geometry to one Mg(2) and one Rh(1) atom. The Mg(1)-Mg(2) bond length is 2.99 Å. The Mg(1)-Rh(1) bond length is 2.71 Å. In the second Mg site, Mg(2) is bonded to one Mg(1), six equivalent Mg(2), and one Cd(1) atom to form a mixture of distorted edge and corner-sharing MgMg7Cd hexagonal bipyramids. All Mg(2)-Mg(2) bond lengths are 3.05 Å. The Mg(2)-Cd(1) bond length is 3.23 Å. Rh(1) is bonded in a single-bond geometry to one Mg(1) and one Cd(1) atom. The Rh(1)-Cd(1) bond length is 0.52 Å. Cd(1) is bonded in a single-bond geometry to one Mg(2) and one Rh(1) atom.