data_In2AsIr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.35
_cell_length_b   8.35
_cell_length_c   8.35
_cell_angle_alpha   24.94
_cell_angle_beta   24.94
_cell_angle_gamma   24.94
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In2AsIr
_chemical_formula_sum   'In2 As1 Ir1'
_cell_volume   91.09
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In1  1  0.0  0.0  0.06  1.0
  In  In2  1  0.0  0.0  0.72  1.0
  As  As0  1  0.0  0.0  0.74  1.0
  Ir  Ir3  1  0.0  0.0  0.88  1.0

data_In2AsIr
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.25
_cell_length_b   3.61
_cell_length_c   8.35
_cell_angle_alpha   90.0
_cell_angle_beta   104.44
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   In2AsIr
_chemical_formula_sum   'In4 As2 Ir2'
_cell_volume   182.19
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  0.0  0.0  0.28  1.0
  In  In1  2  0.0  0.0  0.94  1.0
  As  As2  2  0.0  0.0  0.26  1.0
  Ir  Ir3  2  0.0  0.0  0.12  1.0

In In As Ir
IrIn2As is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two IrIn2As clusters. Ir(1) is bonded in a linear geometry to one In(1) and one As(1) atom. The Ir(1)-In(1) bond length is 1.51 Å. The Ir(1)-As(1) bond length is 1.22 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second In site, In(2) is bonded in a single-bond geometry to one As(1) atom. The In(2)-As(1) bond length is 0.15 Å. As(1) is bonded in a distorted single-bond geometry to one Ir(1) and one In(2) atom.