data_TiReTc2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.75
_cell_length_b   4.35
_cell_length_c   5.1
_cell_angle_alpha   90.0
_cell_angle_beta   101.47
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiReTc2
_chemical_formula_sum   'Ti1 Re1 Tc2'
_cell_volume   59.82
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti3  1  0.88  0.0  0.48  1.0
  Re  Re0  1  0.96  0.18  0.75  1.0
  Tc  Tc1  1  0.01  0.0  0.96  1.0
  Tc  Tc2  1  0.75  0.18  0.3  1.0

data_TiReTc2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.75
_cell_length_b   4.35
_cell_length_c   5.1
_cell_angle_alpha   90.0
_cell_angle_beta   101.47
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiReTc2
_chemical_formula_sum   'Ti1 Re1 Tc2'
_cell_volume   59.82
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.88  0.0  0.48  1.0
  Tc  Tc1  1  0.01  0.0  0.96  1.0
  Tc  Tc2  1  0.75  0.18  0.3  1.0
  Re  Re3  1  0.96  0.18  0.75  1.0

Ti Re Tc Tc
TiReTc2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one TiReTc2 cluster. Ti(1) is bonded in a water-like geometry to one Re(1) and one Tc(2) atom. The Ti(1)-Re(1) bond length is 1.56 Å. The Ti(1)-Tc(2) bond length is 1.19 Å. Re(1) is bonded in a distorted bent 120 degrees geometry to one Ti(1) and one Tc(1) atom. The Re(1)-Tc(1) bond length is 1.32 Å. There are two inequivalent Tc sites. In the first Tc site, Tc(1) is bonded in a distorted single-bond geometry to one Re(1) atom. In the second Tc site, Tc(2) is bonded in a single-bond geometry to one Ti(1) atom.