data_CrInW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.3
_cell_length_b   5.3
_cell_length_c   5.3
_cell_angle_alpha   145.0
_cell_angle_beta   130.35
_cell_angle_gamma   62.19
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CrInW2
_chemical_formula_sum   'Cr1 In1 W2'
_cell_volume   64.42
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.0  0.0  0.54  1.0
  W  W2  1  0.0  0.23  0.42  1.0
  W  W3  1  0.59  0.0  0.11  1.0

data_CrInW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.19
_cell_length_b   4.45
_cell_length_c   5.3
_cell_angle_alpha   114.83
_cell_angle_beta   107.5
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CrInW2
_chemical_formula_sum   'Cr1 In1 W2'
_cell_volume   64.42
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.46  0.46  0.46  1.0
  W  W2  1  0.48  0.89  0.48  1.0
  W  W3  1  0.58  0.8  0.8  1.0

Cr In W W
W2CrIn crystallizes in the triclinic P1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 4-coordinate geometry to one W(2), two equivalent Cr(1), and one In(1) atom. The W(1)-W(2) bond length is 1.84 Å. There is one shorter (1.44 Å) and one longer (2.37 Å) W(1)-Cr(1) bond length. The W(1)-In(1) bond length is 1.73 Å. In the second W site, W(2) is bonded in a 4-coordinate geometry to one W(1), one Cr(1), and two equivalent In(1) atoms. The W(2)-Cr(1) bond length is 2.79 Å. There is one shorter (1.85 Å) and one longer (2.60 Å) W(2)-In(1) bond length. Cr(1) is bonded in a 1-coordinate geometry to one W(2), two equivalent W(1), and one In(1) atom. The Cr(1)-In(1) bond length is 2.44 Å. In(1) is bonded in a 4-coordinate geometry to one W(1), two equivalent W(2), and one Cr(1) atom.