data_NbCoTc
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.26
_cell_length_b   6.22
_cell_length_c   2.69
_cell_angle_alpha   78.4
_cell_angle_beta   76.71
_cell_angle_gamma   24.89
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NbCoTc
_chemical_formula_sum   'Nb1 Co1 Tc1'
_cell_volume   42.96
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb1  1  0.84  0.97  0.83  1.0
  Co  Co0  1  0.84  0.97  0.77  1.0
  Tc  Tc2  1  0.84  0.97  0.18  1.0

data_NbCoTc
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.67
_cell_length_b   11.89
_cell_length_c   2.69
_cell_angle_alpha   90.0
_cell_angle_beta   132.99
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   NbCoTc
_chemical_formula_sum   'Nb2 Co2 Tc2'
_cell_volume   85.93
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  2  0.47  0.5  0.33  1.0
  Co  Co1  2  0.47  0.5  0.39  1.0
  Tc  Tc2  2  0.47  0.5  0.98  1.0

Nb Co Tc
NbTcCo is alpha Niobium phosphide-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two NbTcCo clusters. Nb(1) is bonded in a linear geometry to one Tc(1) and one Co(1) atom. The Nb(1)-Tc(1) bond length is 0.94 Å. The Nb(1)-Co(1) bond length is 0.16 Å. Tc(1) is bonded in a distorted single-bond geometry to one Nb(1) atom. Co(1) is bonded in a single-bond geometry to one Nb(1) atom.