data_SbRhW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.25
_cell_length_b   5.25
_cell_length_c   5.25
_cell_angle_alpha   140.43
_cell_angle_beta   132.8
_cell_angle_gamma   63.24
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SbRhW2
_chemical_formula_sum   'Sb1 Rh1 W2'
_cell_volume   66.65
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb1  1  0.0  0.0  0.47  1.0
  Rh  Rh0  1  0.0  0.0  0.0  1.0
  W  W2  1  0.78  0.0  0.27  1.0
  W  W3  1  0.0  0.1  0.2  1.0

data_SbRhW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.55
_cell_length_b   4.2
_cell_length_c   5.25
_cell_angle_alpha   113.6
_cell_angle_beta   109.79
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SbRhW2
_chemical_formula_sum   'Sb1 Rh1 W2'
_cell_volume   66.65
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.53  0.53  0.53  1.0
  Rh  Rh1  1  0.0  0.0  0.0  1.0
  W  W2  1  0.51  0.73  0.51  1.0
  W  W3  1  0.8  0.9  0.9  1.0

Sb Rh W W
RhWWSb crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one RhW cluster and one WSb cluster. In the RhW cluster, W(2) is bonded in a distorted single-bond geometry to one Rh(1) atom. The W(2)-Rh(1) bond length is 0.71 Å. Rh(1) is bonded in a single-bond geometry to one W(2) atom. In the WSb cluster, W(1) is bonded in a single-bond geometry to one Sb(1) atom. The W(1)-Sb(1) bond length is 0.90 Å. Sb(1) is bonded in a single-bond geometry to one W(1) atom.