data_CoPd2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.91
_cell_length_b   2.91
_cell_length_c   7.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CoPd2Cl
_chemical_formula_sum   'Co1 Pd2 Cl1'
_cell_volume   59.91
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co1  1  0.46  0.46  0.23  1.0
  Pd  Pd2  1  0.0  0.0  0.85  1.0
  Pd  Pd3  1  0.46  0.46  0.66  1.0
  Cl  Cl0  1  0.0  0.0  0.89  1.0

data_CoPd2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.12
_cell_length_b   4.12
_cell_length_c   7.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   CoPd2Cl
_chemical_formula_sum   'Co2 Pd4 Cl2'
_cell_volume   119.81
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  2  0.46  0.0  0.23  1.0
  Pd  Pd1  2  0.0  0.0  0.85  1.0
  Pd  Pd2  2  0.46  0.0  0.66  1.0
  Cl  Cl3  2  0.0  0.0  0.89  1.0

Co Pd Pd Cl
CoPd2Cl crystallizes in the monoclinic Cm space group. Co(1) is bonded in a 6-coordinate geometry to four equivalent Co(1), one Pd(2), and one Cl(1) atom. All Co(1)-Co(1) bond lengths are 2.91 Å. The Co(1)-Pd(2) bond length is 3.00 Å. The Co(1)-Cl(1) bond length is 3.09 Å. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a single-bond geometry to four Pd(2,2) and one Cl(1) atom. There are a spread of Pd(1)-Pd(2,2) bond distances ranging from 2.34-2.63 Å. The Pd(1)-Cl(1) bond length is 0.22 Å. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to one Co(1), four equivalent Pd(1), and four equivalent Pd(2) atoms. All Pd(2)-Pd(2) bond lengths are 2.91 Å. In the third Pd site, Pd(2) is bonded in a 9-coordinate geometry to one Co(1), four equivalent Pd(1), and four equivalent Pd(2) atoms. The Pd(2)-Co(1) bond length is 3.00 Å. Cl(1) is bonded in a single-bond geometry to one Co(1) and one Pd(1) atom.