data_TlRhW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.59
_cell_length_b   4.59
_cell_length_c   2.85
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlRhW
_chemical_formula_sum   'Tl1 Rh1 W1'
_cell_volume   51.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl1  1  0.29  0.32  0.64  1.0
  Rh  Rh0  1  0.0  0.0  0.31  1.0
  W  W2  1  0.0  0.65  0.9  1.0

data_TlRhW
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.85
_cell_length_b   4.59
_cell_length_c   4.59
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlRhW
_chemical_formula_sum   'Tl1 Rh1 W1'
_cell_volume   51.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.64  0.29  0.32  1.0
  Rh  Rh1  1  0.31  0.0  0.0  1.0
  W  W2  1  0.9  -0.0  0.65  1.0

Tl Rh W
WRhTl crystallizes in the triclinic P1 space group. W(1) is bonded in a 4-coordinate geometry to two equivalent Rh(1) and two equivalent Tl(1) atoms. There is one shorter (1.98 Å) and one longer (2.34 Å) W(1)-Rh(1) bond length. There is one shorter (2.57 Å) and one longer (2.91 Å) W(1)-Tl(1) bond length. Rh(1) is bonded in a distorted single-bond geometry to two equivalent W(1) and one Tl(1) atom. The Rh(1)-Tl(1) bond length is 1.70 Å. Tl(1) is bonded in a distorted single-bond geometry to two equivalent W(1) and one Rh(1) atom.