data_TaInPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.03
_cell_length_b   5.03
_cell_length_c   4.95
_cell_angle_alpha   99.51
_cell_angle_beta   99.51
_cell_angle_gamma   34.21
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TaInPd2
_chemical_formula_sum   'Ta1 In1 Pd2'
_cell_volume   69.3
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta3  1  0.38  0.0  0.22  1.0
  In  In0  1  0.75  0.0  0.83  1.0
  Pd  Pd1  1  0.16  0.0  0.77  1.0
  Pd  Pd2  1  0.97  0.0  0.38  1.0

data_TaInPd2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.96
_cell_length_b   4.95
_cell_length_c   5.03
_cell_angle_alpha   99.51
_cell_angle_beta   107.1
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TaInPd2
_chemical_formula_sum   'Ta1 In1 Pd2'
_cell_volume   69.3
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  1  0.0  0.22  0.38  1.0
  In  In1  1  0.0  0.83  0.75  1.0
  Pd  Pd2  1  0.0  0.38  0.97  1.0
  Pd  Pd3  1  0.0  0.77  0.16  1.0

Ta In Pd Pd
TaPd2In crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one TaPd2In cluster. Ta(1) is bonded in a distorted L-shaped geometry to one Pd(1) and one Pd(2) atom. The Ta(1)-Pd(1) bond length is 2.33 Å. The Ta(1)-Pd(2) bond length is 2.32 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 2-coordinate geometry to one Ta(1) and one In(1) atom. The Pd(1)-In(1) bond length is 2.15 Å. In the second Pd site, Pd(2) is bonded in a 1-coordinate geometry to one Ta(1) atom. In(1) is bonded in a 1-coordinate geometry to one Pd(1) atom.