data_VRh2Pb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.97
_cell_length_b   4.97
_cell_length_c   4.97
_cell_angle_alpha   132.99
_cell_angle_beta   132.99
_cell_angle_gamma   68.67
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VRh2Pb
_chemical_formula_sum   'V1 Rh2 Pb1'
_cell_volume   64.46
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Rh  Rh1  1  0.0  0.0  0.1  1.0
  Rh  Rh2  1  0.0  0.98  0.05  1.0
  Pb  Pb0  1  0.98  0.0  0.05  1.0

data_VRh2Pb
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.96
_cell_length_b   3.96
_cell_length_c   4.97
_cell_angle_alpha   113.51
_cell_angle_beta   113.51
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VRh2Pb
_chemical_formula_sum   'V1 Rh2 Pb1'
_cell_volume   64.46
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  Rh  Rh1  1  0.07  0.05  0.07  1.0
  Rh  Rh2  1  0.1  0.1  0.1  1.0
  Pb  Pb3  1  0.05  0.07  0.07  1.0

V Rh Rh Pb
VRh2Pb is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VRh2Pb cluster. V(1) is bonded in a 2-coordinate geometry to one Rh(2) and one Pb(1) atom. The V(1)-Rh(2) bond length is 0.32 Å. The V(1)-Pb(1) bond length is 0.32 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 2-coordinate geometry to one Rh(2) and one Pb(1) atom. The Rh(1)-Rh(2) bond length is 0.21 Å. The Rh(1)-Pb(1) bond length is 0.21 Å. In the second Rh site, Rh(2) is bonded in a single-bond geometry to one V(1), one Rh(1), and one Pb(1) atom. The Rh(2)-Pb(1) bond length is 0.10 Å. Pb(1) is bonded in a single-bond geometry to one V(1), one Rh(1), and one Rh(2) atom.