data_Cs3SbAu
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.7
_cell_length_b   6.7
_cell_length_c   6.7
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cs3SbAu
_chemical_formula_sum   'Cs3 Sb1 Au1'
_cell_volume   300.87
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.35  0.0  0.35  1.0
  Cs  Cs1  1  0.35  0.35  0.0  1.0
  Cs  Cs2  1  0.0  0.35  0.35  1.0
  Sb  Sb3  1  0.0  0.0  0.0  1.0
  Au  Au4  1  0.35  0.35  0.35  1.0

data_Cs3SbAu
_symmetry_space_group_name_H-M   R3m
_cell_length_a   9.48
_cell_length_b   9.48
_cell_length_c   11.61
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   Cs3SbAu
_chemical_formula_sum   'Cs9 Sb3 Au3'
_cell_volume   902.6
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  9  0.1  0.55  0.9  1.0
  Sb  Sb1  3  0.0  0.0  0.0  1.0
  Au  Au2  3  0.0  0.0  0.35  1.0

Cs Cs Cs Sb Au
Cs3AuSb is Pb (Zr_0.50 Ti_0.48) O_3 structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three Cs3AuSb clusters. Cs(1) is bonded in a distorted single-bond geometry to one Au(1) and one Sb(1) atom. The Cs(1)-Au(1) bond length is 2.35 Å. The Cs(1)-Sb(1) bond length is 3.32 Å. Au(1) is bonded in a 3-coordinate geometry to three equivalent Cs(1) atoms. Sb(1) is bonded in a 3-coordinate geometry to three equivalent Cs(1) atoms.