data_SrMg2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.47
_cell_length_b   3.47
_cell_length_c   7.83
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SrMg2Rh
_chemical_formula_sum   'Sr1 Mg2 Rh1'
_cell_volume   94.56
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr3  1  0.0  0.0  0.52  1.0
  Mg  Mg0  1  0.74  0.74  0.48  1.0
  Mg  Mg1  1  0.0  0.0  0.36  1.0
  Rh  Rh2  1  0.74  0.74  0.39  1.0

data_SrMg2Rh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.91
_cell_length_b   4.91
_cell_length_c   7.83
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   SrMg2Rh
_chemical_formula_sum   'Sr2 Mg4 Rh2'
_cell_volume   189.12
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  2  0.0  0.0  0.52  1.0
  Mg  Mg1  2  0.0  0.0  0.36  1.0
  Mg  Mg2  2  0.24  0.5  0.48  1.0
  Rh  Rh3  2  0.24  0.5  0.39  1.0

Sr Mg Mg Rh
SrMg2Rh crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two SrMg2Rh clusters. Sr(1) is bonded in a 2-coordinate geometry to one Mg(1) and one Mg(2) atom. The Sr(1)-Mg(1) bond length is 1.32 Å. The Sr(1)-Mg(2) bond length is 1.24 Å. There are two inequivalent Mg sites. In the first Mg site, Mg(1) is bonded in a single-bond geometry to one Sr(1) and one Rh(1) atom. The Mg(1)-Rh(1) bond length is 0.76 Å. In the second Mg site, Mg(2) is bonded in a 2-coordinate geometry to one Sr(1) and one Rh(1) atom. The Mg(2)-Rh(1) bond length is 1.31 Å. Rh(1) is bonded in a distorted single-bond geometry to one Mg(1) and one Mg(2) atom.