data_YGaW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.95
_cell_length_b   4.96
_cell_length_c   5.16
_cell_angle_alpha   90.0
_cell_angle_beta   94.82
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   YGaW2
_chemical_formula_sum   'Y1 Ga1 W2'
_cell_volume   75.23
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y3  1  0.26  0.0  0.57  1.0
  Ga  Ga0  1  0.0  0.0  0.0  1.0
  W  W1  1  0.38  0.48  0.31  1.0
  W  W2  1  0.14  0.48  0.83  1.0

data_YGaW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.95
_cell_length_b   4.96
_cell_length_c   5.16
_cell_angle_alpha   90.0
_cell_angle_beta   94.82
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   YGaW2
_chemical_formula_sum   'Y1 Ga1 W2'
_cell_volume   75.23
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.26  0.0  0.57  1.0
  Ga  Ga1  1  0.0  0.0  0.0  1.0
  W  W2  1  0.14  0.48  0.83  1.0
  W  W3  1  0.38  0.48  0.31  1.0

Y Ga W W
YW2Ga crystallizes in the triclinic P1 space group. Y(1) is bonded in a 7-coordinate geometry to two equivalent W(1), two equivalent W(2), and three equivalent Ga(1) atoms. There is one shorter (2.77 Å) and one longer (2.95 Å) Y(1)-W(1) bond length. There is one shorter (2.77 Å) and one longer (2.95 Å) Y(1)-W(2) bond length. There is one shorter (2.41 Å) and two longer (2.98 Å) Y(1)-Ga(1) bond lengths. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 2-coordinate geometry to two equivalent Y(1) and three equivalent Ga(1) atoms. There are a spread of W(1)-Ga(1) bond distances ranging from 3.02-3.47 Å. In the second W site, W(2) is bonded in a 4-coordinate geometry to two equivalent Y(1) and two equivalent Ga(1) atoms. There is one shorter (2.58 Å) and one longer (2.77 Å) W(2)-Ga(1) bond length. Ga(1) is bonded in a 10-coordinate geometry to three equivalent Y(1), two equivalent W(2), three equivalent W(1), and two equivalent Ga(1) atoms. Both Ga(1)-Ga(1) bond lengths are 2.95 Å.