data_VBP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.09
_cell_length_b   4.09
_cell_length_c   3.09
_cell_angle_alpha   95.69
_cell_angle_beta   95.69
_cell_angle_gamma   110.92
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VBP2
_chemical_formula_sum   'V1 B1 P2'
_cell_volume   47.49
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.32  0.0  0.0  1.0
  B  B0  1  0.0  0.0  0.0  1.0
  P  P1  1  0.89  0.32  0.52  1.0
  P  P2  1  0.89  0.68  0.52  1.0

data_VBP2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.09
_cell_length_b   4.09
_cell_length_c   4.09
_cell_angle_alpha   110.92
_cell_angle_beta   95.69
_cell_angle_gamma   95.69
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VBP2
_chemical_formula_sum   'V1 B1 P2'
_cell_volume   47.49
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  -0.0  0.32  0.0  1.0
  B  B1  1  0.0  0.0  0.0  1.0
  P  P2  1  0.52  0.89  0.32  1.0
  P  P3  1  0.52  0.89  0.68  1.0

V B P P
P2VB crystallizes in the triclinic P1 space group. V(1) is bonded in a distorted single-bond geometry to one B(1), one P(2), and two equivalent P(1) atoms. The V(1)-B(1) bond length is 1.31 Å. The V(1)-P(2) bond length is 2.11 Å. There is one shorter (2.53 Å) and one longer (2.87 Å) V(1)-P(1) bond length. B(1) is bonded in a distorted single-bond geometry to one V(1), two equivalent P(1), and two equivalent P(2) atoms. There is one shorter (2.14 Å) and one longer (2.17 Å) B(1)-P(1) bond length. There is one shorter (1.77 Å) and one longer (2.14 Å) B(1)-P(2) bond length. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 5-coordinate geometry to two equivalent V(1), two equivalent B(1), and one P(2) atom. The P(1)-P(2) bond length is 1.51 Å. In the second P site, P(2) is bonded in a 4-coordinate geometry to one V(1), two equivalent B(1), and one P(1) atom.