data_VCoW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.91
_cell_length_b   4.91
_cell_length_c   4.91
_cell_angle_alpha   147.86
_cell_angle_beta   139.74
_cell_angle_gamma   52.42
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCoW
_chemical_formula_sum   'V1 Co1 W1'
_cell_volume   40.38
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V1  1  0.0  0.0  0.02  1.0
  Co  Co0  1  0.0  0.0  0.75  1.0
  W  W2  1  0.0  0.0  0.83  1.0

data_VCoW
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.72
_cell_length_b   3.38
_cell_length_c   4.91
_cell_angle_alpha   110.13
_cell_angle_beta   106.07
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCoW
_chemical_formula_sum   'V1 Co1 W1'
_cell_volume   40.38
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.02  0.02  1.0
  Co  Co1  1  0.0  0.75  0.75  1.0
  W  W2  1  0.0  0.83  0.83  1.0

V Co W
VWCo is Cyanogen Chloride-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VWCo cluster. V(1) is bonded in a single-bond geometry to one W(1) atom. The V(1)-W(1) bond length is 0.90 Å. W(1) is bonded in a linear geometry to one V(1) and one Co(1) atom. The W(1)-Co(1) bond length is 0.40 Å. Co(1) is bonded in a single-bond geometry to one W(1) atom.