data_CoOs2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.62
_cell_length_b   4.62
_cell_length_c   4.63
_cell_angle_alpha   99.55
_cell_angle_beta   99.55
_cell_angle_gamma   33.72
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CoOs2Rh
_chemical_formula_sum   'Co1 Os2 Rh1'
_cell_volume   53.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.41  0.0  0.12  1.0
  Os  Os1  1  0.01  0.0  0.0  1.0
  Os  Os2  1  0.61  0.0  0.47  1.0
  Rh  Rh3  1  0.03  0.0  0.24  1.0

data_CoOs2Rh
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.68
_cell_length_b   4.62
_cell_length_c   4.63
_cell_angle_alpha   99.55
_cell_angle_beta   90.0
_cell_angle_gamma   106.86
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CoOs2Rh
_chemical_formula_sum   'Co1 Os2 Rh1'
_cell_volume   53.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.59  0.88  1.0
  Os  Os1  1  0.0  0.39  0.53  1.0
  Os  Os2  1  0.0  0.99  1.0  1.0
  Rh  Rh3  1  0.0  0.97  0.76  1.0

Co Os Os Rh
Os2RhCo crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Os2RhCo cluster. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a distorted single-bond geometry to one Rh(1) and one Co(1) atom. The Os(1)-Rh(1) bond length is 1.07 Å. The Os(1)-Co(1) bond length is 1.83 Å. In the second Os site, Os(2) is bonded in a distorted single-bond geometry to one Co(1) atom. The Os(2)-Co(1) bond length is 1.71 Å. Rh(1) is bonded in a distorted single-bond geometry to one Os(1) and one Co(1) atom. The Rh(1)-Co(1) bond length is 1.90 Å. Co(1) is bonded in a 3-coordinate geometry to one Os(1), one Os(2), and one Rh(1) atom.