data_NaLiAg2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.91
_cell_length_b   4.81
_cell_length_c   5.65
_cell_angle_alpha   90.0
_cell_angle_beta   99.11
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaLiAg2
_chemical_formula_sum   'Na1 Li1 Ag2'
_cell_volume   78.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na3  1  0.18  0.4  0.27  1.0
  Li  Li2  1  0.01  0.0  0.53  1.0
  Ag  Ag0  1  0.77  0.0  0.06  1.0
  Ag  Ag1  1  0.96  0.4  0.5  1.0

data_NaLiAg2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.91
_cell_length_b   4.81
_cell_length_c   5.65
_cell_angle_alpha   90.0
_cell_angle_beta   99.11
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaLiAg2
_chemical_formula_sum   'Na1 Li1 Ag2'
_cell_volume   78.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.18  0.4  0.27  1.0
  Li  Li1  1  0.01  0.0  0.53  1.0
  Ag  Ag2  1  0.77  0.0  0.06  1.0
  Ag  Ag3  1  0.96  0.4  0.5  1.0

Na Li Ag Ag
NaLiAg2 crystallizes in the triclinic P1 space group. Na(1) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and four equivalent Ag(1) atoms. There is one shorter (1.54 Å) and one longer (2.44 Å) Na(1)-Ag(2) bond length. There are a spread of Na(1)-Ag(1) bond distances ranging from 2.48-3.64 Å. Li(1) is bonded in a 1-coordinate geometry to two equivalent Ag(2) and three equivalent Ag(1) atoms. There is one shorter (1.95 Å) and one longer (2.87 Å) Li(1)-Ag(2) bond length. There are a spread of Li(1)-Ag(1) bond distances ranging from 2.64-3.44 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 9-coordinate geometry to four equivalent Na(1), three equivalent Li(1), and two equivalent Ag(1) atoms. Both Ag(1)-Ag(1) bond lengths are 2.91 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent Na(1) and two equivalent Li(1) atoms.