data_ZnCdOs2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.69
_cell_length_b   4.69
_cell_length_c   5.05
_cell_angle_alpha   97.76
_cell_angle_beta   97.76
_cell_angle_gamma   35.19
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnCdOs2
_chemical_formula_sum   'Zn1 Cd1 Os2'
_cell_volume   63.27
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.16  0.0  0.5  1.0
  Cd  Cd0  1  0.49  0.0  0.35  1.0
  Os  Os1  1  0.19  0.0  0.76  1.0
  Os  Os2  1  0.71  0.0  0.89  1.0

data_ZnCdOs2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.83
_cell_length_b   4.69
_cell_length_c   5.05
_cell_angle_alpha   97.76
_cell_angle_beta   90.0
_cell_angle_gamma   107.59
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnCdOs2
_chemical_formula_sum   'Zn1 Cd1 Os2'
_cell_volume   63.27
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.0  0.84  0.5  1.0
  Cd  Cd1  1  0.0  0.51  0.65  1.0
  Os  Os2  1  0.0  0.29  0.11  1.0
  Os  Os3  1  0.0  0.81  0.24  1.0

Zn Cd Os Os
Os2CdZn crystallizes in the triclinic P1 space group. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a single-bond geometry to two equivalent Os(2) and one Zn(1) atom. There is one shorter (2.42 Å) and one longer (2.44 Å) Os(1)-Os(2) bond length. The Os(1)-Zn(1) bond length is 1.34 Å. In the second Os site, Os(2) is bonded in a 6-coordinate geometry to two equivalent Os(1), two equivalent Os(2), and two equivalent Cd(1) atoms. Both Os(2)-Os(2) bond lengths are 2.83 Å. There is one shorter (2.68 Å) and one longer (2.75 Å) Os(2)-Cd(1) bond length. Cd(1) is bonded in a 3-coordinate geometry to two equivalent Os(2) and one Zn(1) atom. The Cd(1)-Zn(1) bond length is 1.78 Å. Zn(1) is bonded in a distorted single-bond geometry to one Os(1) and one Cd(1) atom.