data_LiIrRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.68
_cell_length_b   2.68
_cell_length_c   9.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   118.9
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiIrRh2
_chemical_formula_sum   'Li1 Ir1 Rh2'
_cell_volume   57.0
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.0  0.0  0.26  1.0
  Ir  Ir0  1  0.36  0.0  0.49  1.0
  Rh  Rh2  1  0.36  0.0  0.04  1.0
  Rh  Rh3  1  0.0  0.0  0.8  1.0

data_LiIrRh2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   2.68
_cell_length_b   4.7
_cell_length_c   9.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LiIrRh2
_chemical_formula_sum   'Li2 Ir2 Rh4'
_cell_volume   114.01
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.26  1.0
  Ir  Ir1  2  0.36  0.0  0.49  1.0
  Rh  Rh2  2  0.0  0.0  0.8  1.0
  Rh  Rh3  2  0.36  0.0  0.04  1.0

Li Ir Rh Rh
LiIrRh2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 2-coordinate geometry to one Ir(1) and one Rh(1) atom. The Li(1)-Ir(1) bond length is 2.35 Å. The Li(1)-Rh(1) bond length is 2.22 Å. Ir(1) is bonded in a 1-coordinate geometry to one Li(1) and two equivalent Rh(2) atoms. There is one shorter (2.94 Å) and one longer (3.26 Å) Ir(1)-Rh(2) bond length. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 1-coordinate geometry to one Li(1) and two equivalent Rh(2) atoms. There is one shorter (2.35 Å) and one longer (2.74 Å) Rh(1)-Rh(2) bond length. In the second Rh site, Rh(2) is bonded in a 10-coordinate geometry to two equivalent Ir(1), two equivalent Rh(1), and six equivalent Rh(2) atoms. There are four shorter (2.68 Å) and two longer (2.73 Å) Rh(2)-Rh(2) bond lengths.