data_NiBiRuW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.51
_cell_length_b   4.51
_cell_length_c   4.51
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NiBiRuW
_chemical_formula_sum   'Ni1 Bi1 Ru1 W1'
_cell_volume   65.05
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni1  1  0.0  0.0  0.0  1.0
  Bi  Bi0  1  0.19  0.19  0.19  1.0
  Ru  Ru2  1  0.6  0.6  0.6  1.0
  W  W3  1  0.79  0.79  0.79  1.0

data_NiBiRuW
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.51
_cell_length_b   4.51
_cell_length_c   11.06
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   NiBiRuW
_chemical_formula_sum   'Ni3 Bi3 Ru3 W3'
_cell_volume   195.15
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  3  0.0  0.0  0.0  1.0
  Bi  Bi1  3  0.0  0.0  0.81  1.0
  Ru  Ru2  3  0.0  0.0  0.4  1.0
  W  W3  3  0.0  0.0  0.21  1.0

Ni Bi Ru W
WRuNiBi crystallizes in the trigonal R3m space group. W(1) is bonded in a 2-coordinate geometry to one Ru(1), one Ni(1), and three equivalent Bi(1) atoms. The W(1)-Ru(1) bond length is 2.12 Å. The W(1)-Ni(1) bond length is 2.34 Å. All W(1)-Bi(1) bond lengths are 2.72 Å. Ru(1) is bonded in a 1-coordinate geometry to one W(1) and three equivalent Bi(1) atoms. All Ru(1)-Bi(1) bond lengths are 2.72 Å. Ni(1) is bonded in a 2-coordinate geometry to one W(1) and one Bi(1) atom. The Ni(1)-Bi(1) bond length is 2.12 Å. Bi(1) is bonded in a 7-coordinate geometry to three equivalent W(1), three equivalent Ru(1), and one Ni(1) atom.