data_TlTeAu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.48
_cell_length_b   4.04
_cell_length_c   6.74
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlTeAu2
_chemical_formula_sum   'Tl1 Te1 Au2'
_cell_volume   94.81
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl3  1  0.0  0.0  0.37  1.0
  Te  Te2  1  0.0  0.0  0.0  1.0
  Au  Au0  1  0.74  0.02  0.18  1.0
  Au  Au1  1  0.74  0.02  0.56  1.0

data_TlTeAu2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.48
_cell_length_b   4.04
_cell_length_c   6.74
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlTeAu2
_chemical_formula_sum   'Tl1 Te1 Au2'
_cell_volume   94.81
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.0  0.0  0.37  1.0
  Te  Te1  1  0.0  0.0  0.0  1.0
  Au  Au2  1  0.74  0.02  0.18  1.0
  Au  Au3  1  0.74  0.02  0.56  1.0

Tl Te Au Au
Au2TlTe crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Au2TlTe cluster. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted water-like geometry to one Tl(1) and one Te(1) atom. The Au(1)-Tl(1) bond length is 1.56 Å. The Au(1)-Te(1) bond length is 1.52 Å. In the second Au site, Au(2) is bonded in a distorted single-bond geometry to one Tl(1) atom. The Au(2)-Tl(1) bond length is 1.56 Å. Tl(1) is bonded in a distorted water-like geometry to one Au(1) and one Au(2) atom. Te(1) is bonded in a distorted single-bond geometry to one Au(1) atom.