data_La2NbIn
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.79
_cell_length_b   3.79
_cell_length_c   7.64
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   La2NbIn
_chemical_formula_sum   'La2 Nb1 In1'
_cell_volume   109.61
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La1  1  0.0  0.0  0.36  1.0
  La  La2  1  0.89  0.89  0.17  1.0
  Nb  Nb3  1  0.0  0.0  0.17  1.0
  In  In0  1  0.89  0.89  0.4  1.0

data_La2NbIn
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.36
_cell_length_b   5.36
_cell_length_c   7.64
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   La2NbIn
_chemical_formula_sum   'La4 Nb2 In2'
_cell_volume   219.23
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  2  0.0  0.0  0.36  1.0
  La  La1  2  0.39  0.5  0.17  1.0
  Nb  Nb2  2  0.0  0.0  0.17  1.0
  In  In3  2  0.39  0.5  0.4  1.0

La La Nb In
La2NbIn crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two La2NbIn clusters. There are two inequivalent La sites. In the first La site, La(1) is bonded in a distorted bent 120 degrees geometry to one Nb(1) and one In(1) atom. The La(1)-Nb(1) bond length is 1.41 Å. The La(1)-In(1) bond length is 0.66 Å. In the second La site, La(2) is bonded in a single-bond geometry to one Nb(1) atom. The La(2)-Nb(1) bond length is 0.57 Å. Nb(1) is bonded in a distorted L-shaped geometry to one La(1) and one La(2) atom. In(1) is bonded in a single-bond geometry to one La(1) atom.