data_CrIn2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.4
_cell_length_b   7.4
_cell_length_c   7.4
_cell_angle_alpha   155.57
_cell_angle_beta   145.68
_cell_angle_gamma   42.58
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CrIn2Cl
_chemical_formula_sum   'Cr1 In2 Cl1'
_cell_volume   94.39
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr1  1  0.0  0.0  0.9  1.0
  In  In2  1  0.57  0.0  0.31  1.0
  In  In3  1  0.0  0.18  0.59  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_CrIn2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.13
_cell_length_b   4.37
_cell_length_c   7.4
_cell_angle_alpha   107.16
_cell_angle_beta   102.22
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CrIn2Cl
_chemical_formula_sum   'Cr1 In2 Cl1'
_cell_volume   94.39
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.1  0.1  0.1  1.0
  In  In1  1  0.25  0.69  0.25  1.0
  In  In2  1  0.41  0.6  0.6  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Cr In In Cl
CrIn2Cl crystallizes in the triclinic P1 space group. Cr(1) is bonded in a single-bond geometry to two equivalent In(1) and one Cl(1) atom. There is one shorter (2.40 Å) and one longer (2.47 Å) Cr(1)-In(1) bond length. The Cr(1)-Cl(1) bond length is 0.76 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 6-coordinate geometry to two equivalent Cr(1), one In(2), two equivalent In(1), and one Cl(1) atom. The In(1)-In(2) bond length is 2.63 Å. Both In(1)-In(1) bond lengths are 3.13 Å. The In(1)-Cl(1) bond length is 2.63 Å. In the second In site, In(2) is bonded in a 4-coordinate geometry to one In(1), two equivalent In(2), and one Cl(1) atom. Both In(2)-In(2) bond lengths are 3.13 Å. The In(2)-Cl(1) bond length is 3.15 Å. Cl(1) is bonded in a single-bond geometry to one Cr(1), one In(1), and one In(2) atom.