data_VFeGe2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.53
_cell_length_b   3.57
_cell_length_c   4.42
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VFeGe2
_chemical_formula_sum   'V1 Fe1 Ge2'
_cell_volume   55.63
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Fe  Fe0  1  0.76  0.0  0.21  1.0
  Ge  Ge1  1  0.76  0.79  0.0  1.0
  Ge  Ge2  1  0.0  0.79  0.21  1.0

data_VFeGe2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.53
_cell_length_b   3.57
_cell_length_c   4.42
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VFeGe2
_chemical_formula_sum   'V1 Fe1 Ge2'
_cell_volume   55.63
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  Fe  Fe1  1  0.76  0.0  0.21  1.0
  Ge  Ge2  1  0.0  0.79  0.21  1.0
  Ge  Ge3  1  0.76  0.79  -0.0  1.0

V Fe Ge Ge
VFeGe2 is alpha Po structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VFeGe2 cluster. V(1) is bonded in a 3-coordinate geometry to one Fe(1), one Ge(1), and one Ge(2) atom. The V(1)-Fe(1) bond length is 1.24 Å. The V(1)-Ge(1) bond length is 1.13 Å. The V(1)-Ge(2) bond length is 1.20 Å. Fe(1) is bonded in a 3-coordinate geometry to one V(1), one Ge(1), and one Ge(2) atom. The Fe(1)-Ge(1) bond length is 1.20 Å. The Fe(1)-Ge(2) bond length is 1.13 Å. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 2-coordinate geometry to one V(1), one Fe(1), and one Ge(2) atom. The Ge(1)-Ge(2) bond length is 1.24 Å. In the second Ge site, Ge(2) is bonded in a 3-coordinate geometry to one V(1), one Fe(1), and one Ge(1) atom.