data_VCd2In
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.2
_cell_length_b   4.2
_cell_length_c   4.38
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCd2In
_chemical_formula_sum   'V1 Cd2 In1'
_cell_volume   77.34
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Cd  Cd0  1  0.0  0.1  0.19  1.0
  Cd  Cd1  1  0.1  0.0  0.19  1.0
  In  In2  1  0.1  0.1  0.0  1.0

data_VCd2In
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.94
_cell_length_b   5.94
_cell_length_c   4.38
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VCd2In
_chemical_formula_sum   'V2 Cd4 In2'
_cell_volume   154.67
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.0  1.0
  Cd  Cd1  4  0.05  0.05  0.19  1.0
  In  In2  2  0.1  0.0  -0.0  1.0

V Cd Cd In
VCd2In is alpha Po structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two VCd2In clusters. V(1) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one In(1) atom. Both V(1)-Cd(1) bond lengths are 0.94 Å. The V(1)-In(1) bond length is 0.60 Å. Cd(1) is bonded in a 3-coordinate geometry to one V(1), one Cd(1), and one In(1) atom. The Cd(1)-Cd(1) bond length is 0.60 Å. The Cd(1)-In(1) bond length is 0.94 Å. In(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Cd(1) atoms.