data_SnBPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.84
_cell_length_b   3.14
_cell_length_c   5.67
_cell_angle_alpha   90.0
_cell_angle_beta   101.09
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SnBPd2
_chemical_formula_sum   'Sn1 B1 Pd2'
_cell_volume   67.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn3  1  0.37  0.0  0.78  1.0
  B  B0  1  0.0  0.0  0.0  1.0
  Pd  Pd1  1  1.0  0.57  0.08  1.0
  Pd  Pd2  1  0.75  0.57  0.49  1.0

data_SnBPd2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.14
_cell_length_b   3.84
_cell_length_c   5.67
_cell_angle_alpha   101.09
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SnBPd2
_chemical_formula_sum   'Sn1 B1 Pd2'
_cell_volume   67.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.0  0.63  0.22  1.0
  B  B1  1  0.0  0.0  0.0  1.0
  Pd  Pd2  1  0.43  0.0  0.92  1.0
  Pd  Pd3  1  0.43  0.25  0.51  1.0

Sn B Pd Pd
Pd2BSn crystallizes in the triclinic P1 space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Pd(2) and two equivalent B(1) atoms. There is one shorter (2.66 Å) and one longer (3.33 Å) Pd(1)-Pd(2) bond length. There is one shorter (1.42 Å) and one longer (1.86 Å) Pd(1)-B(1) bond length. In the second Pd site, Pd(2) is bonded in a 8-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), and four equivalent Sn(1) atoms. Both Pd(2)-Pd(2) bond lengths are 3.14 Å. There are a spread of Pd(2)-Sn(1) bond distances ranging from 2.77-3.21 Å. B(1) is bonded in a 4-coordinate geometry to two equivalent Pd(1) and two equivalent Sn(1) atoms. There is one shorter (2.05 Å) and one longer (2.48 Å) B(1)-Sn(1) bond length. Sn(1) is bonded in a 1-coordinate geometry to four equivalent Pd(2) and two equivalent B(1) atoms.