data_VHgOsAu
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.55
_cell_length_b   4.55
_cell_length_c   4.55
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VHgOsAu
_chemical_formula_sum   'V1 Hg1 Os1 Au1'
_cell_volume   66.78
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Hg  Hg1  1  0.61  0.61  0.61  1.0
  Os  Os2  1  0.83  0.83  0.83  1.0
  Au  Au0  1  0.22  0.22  0.22  1.0

data_VHgOsAu
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.55
_cell_length_b   4.55
_cell_length_c   11.15
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   VHgOsAu
_chemical_formula_sum   'V3 Hg3 Os3 Au3'
_cell_volume   200.34
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  3  0.0  0.0  0.0  1.0
  Hg  Hg1  3  0.0  0.0  0.39  1.0
  Os  Os2  3  0.0  0.0  0.17  1.0
  Au  Au3  3  0.0  0.0  0.78  1.0

V Hg Os Au
VOsAuHg crystallizes in the trigonal R3m space group. V(1) is bonded in a 2-coordinate geometry to one Os(1), four equivalent Au(1), and three equivalent Hg(1) atoms. The V(1)-Os(1) bond length is 1.89 Å. There is one shorter (2.46 Å) and three longer (2.92 Å) V(1)-Au(1) bond lengths. All V(1)-Hg(1) bond lengths are 2.70 Å. Os(1) is bonded in a distorted single-bond geometry to one V(1), three equivalent Au(1), and four equivalent Hg(1) atoms. All Os(1)-Au(1) bond lengths are 2.70 Å. There is one shorter (2.46 Å) and three longer (2.92 Å) Os(1)-Hg(1) bond lengths. Au(1) is bonded in a 10-coordinate geometry to four equivalent V(1), three equivalent Os(1), and three equivalent Hg(1) atoms. All Au(1)-Hg(1) bond lengths are 2.70 Å. Hg(1) is bonded in a 10-coordinate geometry to three equivalent V(1), four equivalent Os(1), and three equivalent Au(1) atoms.