data_CrInRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.7
_cell_length_b   8.7
_cell_length_c   8.7
_cell_angle_alpha   19.29
_cell_angle_beta   19.29
_cell_angle_gamma   19.29
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CrInRh2
_chemical_formula_sum   'Cr1 In1 Rh2'
_cell_volume   62.91
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.0  0.0  0.81  1.0
  Rh  Rh2  1  0.0  0.0  0.56  1.0
  Rh  Rh3  1  0.0  0.0  0.05  1.0

data_CrInRh2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.05
_cell_length_b   2.92
_cell_length_c   8.7
_cell_angle_alpha   90.0
_cell_angle_beta   101.16
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   CrInRh2
_chemical_formula_sum   'Cr2 In2 Rh4'
_cell_volume   125.83
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  2  0.0  0.0  0.0  1.0
  In  In1  2  -0.0  0.0  0.19  1.0
  Rh  Rh2  2  -0.0  0.0  0.95  1.0
  Rh  Rh3  2  -0.0  0.0  0.44  1.0

Cr In Rh Rh
CrRh2In is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two CrRh2In clusters. Cr(1) is bonded in a single-bond geometry to one Rh(2) and one In(1) atom. The Cr(1)-Rh(2) bond length is 0.46 Å. The Cr(1)-In(1) bond length is 1.67 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a single-bond geometry to one In(1) atom. The Rh(1)-In(1) bond length is 2.13 Å. In the second Rh site, Rh(2) is bonded in a single-bond geometry to one Cr(1) atom. In(1) is bonded in a linear geometry to one Cr(1) and one Rh(1) atom.