data_Co2BiP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.94
_cell_length_b   2.94
_cell_length_c   6.94
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Co2BiP
_chemical_formula_sum   'Co2 Bi1 P1'
_cell_volume   60.19
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co1  1  0.47  0.47  0.74  1.0
  Co  Co2  1  0.47  0.47  0.2  1.0
  Bi  Bi0  1  0.0  0.0  0.47  1.0
  P  P3  1  0.0  0.0  0.0  1.0

data_Co2BiP
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.16
_cell_length_b   4.16
_cell_length_c   6.94
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Co2BiP
_chemical_formula_sum   'Co4 Bi2 P2'
_cell_volume   120.38
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  2  0.47  0.0  0.2  1.0
  Co  Co1  2  0.47  0.0  0.74  1.0
  Bi  Bi2  2  0.0  0.0  0.47  1.0
  P  P3  2  0.0  0.0  0.0  1.0

Co Co Bi P
Co2BiP crystallizes in the monoclinic Cm space group. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 8-coordinate geometry to four equivalent Bi(1) and four equivalent P(1) atoms. There are a spread of Co(1)-Bi(1) bond distances ranging from 2.70-2.87 Å. There are a spread of Co(1)-P(1) bond distances ranging from 2.68-2.85 Å. In the second Co site, Co(2) is bonded in a 8-coordinate geometry to four equivalent Bi(1) and four equivalent P(1) atoms. There are a spread of Co(2)-Bi(1) bond distances ranging from 2.70-2.87 Å. There are a spread of Co(2)-P(1) bond distances ranging from 2.43-2.62 Å. Bi(1) is bonded in a 8-coordinate geometry to four equivalent Co(1) and four equivalent Co(2) atoms. P(1) is bonded in a distorted body-centered cubic geometry to four equivalent Co(1) and four equivalent Co(2) atoms.