data_CdInP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.96
_cell_length_b   4.96
_cell_length_c   4.96
_cell_angle_alpha   124.61
_cell_angle_beta   124.61
_cell_angle_gamma   82.19
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdInP2
_chemical_formula_sum   'Cd1 In1 P2'
_cell_volume   79.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.0  0.0  0.73  1.0
  P  P2  1  0.0  0.3  0.87  1.0
  P  P3  1  0.3  0.0  0.87  1.0

data_CdInP2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.51
_cell_length_b   6.51
_cell_length_c   4.96
_cell_angle_alpha   90.0
_cell_angle_beta   131.09
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   CdInP2
_chemical_formula_sum   'Cd2 In2 P4'
_cell_volume   158.48
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  2  0.0  0.0  0.0  1.0
  In  In1  2  0.0  0.0  0.73  1.0
  P  P2  4  0.35  0.35  0.56  1.0

Cd In P P
CdInP2 is Copper structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two CdInP2 clusters. Cd(1) is bonded in a distorted single-bond geometry to one In(1) atom. The Cd(1)-In(1) bond length is 1.32 Å. In(1) is bonded in a distorted trigonal non-coplanar geometry to one Cd(1) and two equivalent P(1) atoms. Both In(1)-P(1) bond lengths are 1.25 Å. P(1) is bonded in a single-bond geometry to one In(1) atom.