data_CaLaW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.25
_cell_length_b   6.25
_cell_length_c   6.25
_cell_angle_alpha   147.04
_cell_angle_beta   130.24
_cell_angle_gamma   60.99
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CaLaW2
_chemical_formula_sum   'Ca1 La1 W2'
_cell_volume   100.37
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.0  0.0  0.23  1.0
  La  La1  1  0.0  0.63  0.84  1.0
  W  W2  1  0.0  0.0  0.49  1.0
  W  W3  1  0.77  0.0  0.21  1.0

data_CaLaW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.55
_cell_length_b   5.26
_cell_length_c   6.25
_cell_angle_alpha   114.88
_cell_angle_beta   106.48
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CaLaW2
_chemical_formula_sum   'Ca1 La1 W2'
_cell_volume   100.37
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.77  0.77  0.77  1.0
  La  La1  1  0.16  0.79  0.79  1.0
  W  W2  1  0.51  0.51  0.51  1.0
  W  W3  1  0.56  0.79  0.56  1.0

Ca La W W
CaLaW2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one CaLaW2 cluster. Ca(1) is bonded in a 3-coordinate geometry to one La(1), one W(1), and one W(2) atom. The Ca(1)-La(1) bond length is 1.36 Å. The Ca(1)-W(1) bond length is 1.60 Å. The Ca(1)-W(2) bond length is 1.34 Å. La(1) is bonded in a 1-coordinate geometry to one Ca(1) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted single-bond geometry to one Ca(1) atom. In the second W site, W(2) is bonded in a single-bond geometry to one Ca(1) atom.