data_Cd5Pt3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.11
_cell_length_b   8.11
_cell_length_c   5.47
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd5Pt3
_chemical_formula_sum   'Cd10 Pt6'
_cell_volume   311.68
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.99  0.75  0.37  1.0
  Cd  Cd1  1  0.96  0.27  0.11  1.0
  Cd  Cd2  1  0.02  0.0  0.37  1.0
  Cd  Cd3  1  0.01  0.75  0.11  1.0
  Cd  Cd4  1  0.0  0.68  0.0  1.0
  Cd  Cd5  1  0.0  0.68  0.74  1.0
  Cd  Cd6  1  0.05  0.34  0.0  1.0
  Cd  Cd7  1  0.05  0.34  0.74  1.0
  Cd  Cd8  1  0.09  0.0  0.11  1.0
  Cd  Cd9  1  0.04  0.27  0.37  1.0
  Pt  Pt10  1  0.42  0.74  0.11  1.0
  Pt  Pt11  1  0.53  0.29  0.37  1.0
  Pt  Pt12  1  0.16  0.0  0.11  1.0
  Pt  Pt13  1  0.58  0.74  0.37  1.0
  Pt  Pt14  1  0.95  0.0  0.37  1.0
  Pt  Pt15  1  0.47  0.29  0.11  1.0

data_Cd5Pt3
_symmetry_space_group_name_H-M   P1
_cell_length_a   5.47
_cell_length_b   8.11
_cell_length_c   8.11
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd5Pt3
_chemical_formula_sum   'Cd10 Pt6'
_cell_volume   311.68
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.0  0.68  1.0
  Cd  Cd1  1  0.0  0.05  0.34  1.0
  Cd  Cd2  1  0.11  0.01  0.75  1.0
  Cd  Cd3  1  0.11  0.09  0.0  1.0
  Cd  Cd4  1  0.11  0.96  0.27  1.0
  Cd  Cd5  1  0.37  0.02  0.0  1.0
  Cd  Cd6  1  0.37  0.04  0.27  1.0
  Cd  Cd7  1  0.37  0.99  0.75  1.0
  Cd  Cd8  1  0.74  0.0  0.68  1.0
  Cd  Cd9  1  0.74  0.05  0.34  1.0
  Pt  Pt10  1  0.11  0.16  0.0  1.0
  Pt  Pt11  1  0.11  0.42  0.74  1.0
  Pt  Pt12  1  0.11  0.47  0.29  1.0
  Pt  Pt13  1  0.37  0.53  0.29  1.0
  Pt  Pt14  1  0.37  0.58  0.74  1.0
  Pt  Pt15  1  0.37  0.95  0.0  1.0

Cd Cd Cd Cd Cd Cd Cd Cd Cd Cd Pt Pt Pt Pt Pt Pt
Pt3Cd5 crystallizes in the triclinic P1 space group. There are six inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 3-coordinate geometry to one Pt(4), one Cd(5), and one Cd(7) atom. The Pt(1)-Pt(4) bond length is 1.94 Å. The Pt(1)-Cd(5) bond length is 3.26 Å. The Pt(1)-Cd(7) bond length is 3.15 Å. In the second Pt site, Pt(2) is bonded in a single-bond geometry to one Pt(6) atom. The Pt(2)-Pt(6) bond length is 1.50 Å. In the third Pt site, Pt(3) is bonded in a single-bond geometry to one Pt(6), one Cd(4), and one Cd(9) atom. The Pt(3)-Pt(6) bond length is 2.44 Å. The Pt(3)-Cd(4) bond length is 1.76 Å. The Pt(3)-Cd(9) bond length is 0.60 Å. In the fourth Pt site, Pt(4) is bonded in a 3-coordinate geometry to one Pt(1), one Pt(5), and one Cd(1) atom. The Pt(4)-Pt(5) bond length is 2.67 Å. The Pt(4)-Cd(1) bond length is 3.26 Å. In the fifth Pt site, Pt(5) is bonded in a single-bond geometry to one Pt(4), one Cd(10), and one Cd(3) atom. The Pt(5)-Cd(10) bond length is 1.93 Å. The Pt(5)-Cd(3) bond length is 0.60 Å. In the sixth Pt site, Pt(6) is bonded in a distorted water-like geometry to one Pt(2) and one Pt(3) atom. There are ten inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 3-coordinate geometry to one Pt(4), one Cd(3), one Cd(4), and one Cd(6) atom. The Cd(1)-Cd(3) bond length is 1.90 Å. The Cd(1)-Cd(4) bond length is 1.45 Å. The Cd(1)-Cd(6) bond length is 2.11 Å. In the second Cd site, Cd(2) is bonded in a distorted single-bond geometry to one Cd(10) and one Cd(7) atom. The Cd(2)-Cd(10) bond length is 1.60 Å. The Cd(2)-Cd(7) bond length is 0.91 Å. In the third Cd site, Cd(3) is bonded in a single-bond geometry to one Pt(5) and one Cd(1) atom. In the fourth Cd site, Cd(4) is bonded in a 3-coordinate geometry to one Pt(3), one Cd(1), and one Cd(5) atom. The Cd(4)-Cd(5) bond length is 0.78 Å. In the fifth Cd site, Cd(5) is bonded in a 2-coordinate geometry to one Pt(1), one Cd(4), and one Cd(6) atom. The Cd(5)-Cd(6) bond length is 1.44 Å. In the sixth Cd site, Cd(6) is bonded in a 2-coordinate geometry to one Cd(1) and one Cd(5) atom. In the seventh Cd site, Cd(7) is bonded in a 2-coordinate geometry to one Pt(1), one Cd(2), and one Cd(8) atom. The Cd(7)-Cd(8) bond length is 1.44 Å. In the eighth Cd site, Cd(8) is bonded in a 2-coordinate geometry to one Cd(10) and one Cd(7) atom. The Cd(8)-Cd(10) bond length is 2.08 Å. In the ninth Cd site, Cd(9) is bonded in a single-bond geometry to one Pt(3) atom. In the tenth Cd site, Cd(10) is bonded in a 3-coordinate geometry to one Pt(5), one Cd(2), and one Cd(8) atom.