data_K2TiRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.96
_cell_length_b   3.96
_cell_length_c   5.94
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   K2TiRh
_chemical_formula_sum   'K2 Ti1 Rh1'
_cell_volume   93.09
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.98  0.97  1.0
  K  K1  1  0.98  0.0  0.97  1.0
  Ti  Ti3  1  0.0  0.0  0.0  1.0
  Rh  Rh2  1  0.98  0.98  0.0  1.0

data_K2TiRh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.6
_cell_length_b   5.6
_cell_length_c   5.94
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   K2TiRh
_chemical_formula_sum   'K4 Ti2 Rh2'
_cell_volume   186.17
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  4  0.49  0.49  0.97  1.0
  Ti  Ti1  2  0.0  0.0  0.0  1.0
  Rh  Rh2  2  0.48  0.5  0.0  1.0

K K Ti Rh
K2TiRh crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two K2TiRh clusters. K(1) is bonded in a 3-coordinate geometry to one K(1), one Ti(1), and one Rh(1) atom. The K(1)-K(1) bond length is 0.12 Å. The K(1)-Ti(1) bond length is 0.19 Å. The K(1)-Rh(1) bond length is 0.19 Å. Ti(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Rh(1) atom. The Ti(1)-Rh(1) bond length is 0.12 Å. Rh(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Ti(1) atom.