data_TaSb2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.45
_cell_length_b   4.94
_cell_length_c   5.13
_cell_angle_alpha   90.0
_cell_angle_beta   103.19
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TaSb2W
_chemical_formula_sum   'Ta1 Sb2 W1'
_cell_volume   85.22
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta2  1  0.21  0.0  0.74  1.0
  Sb  Sb0  1  0.41  0.0  0.9  1.0
  Sb  Sb1  1  0.71  0.47  0.35  1.0
  W  W3  1  0.91  0.47  0.49  1.0

data_TaSb2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.45
_cell_length_b   4.94
_cell_length_c   5.13
_cell_angle_alpha   90.0
_cell_angle_beta   103.19
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TaSb2W
_chemical_formula_sum   'Ta1 Sb2 W1'
_cell_volume   85.22
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  1  0.21  0.0  0.74  1.0
  Sb  Sb1  1  0.41  0.0  0.9  1.0
  Sb  Sb2  1  0.71  0.47  0.35  1.0
  W  W3  1  0.91  0.47  0.49  1.0

Ta Sb Sb W
TaSbWSb crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one TaSb cluster and one WSb cluster. In the TaSb cluster, Ta(1) is bonded in a distorted single-bond geometry to one Sb(1) atom. The Ta(1)-Sb(1) bond length is 0.96 Å. Sb(1) is bonded in a single-bond geometry to one Ta(1) atom. In the WSb cluster, W(1) is bonded in a distorted single-bond geometry to one Sb(2) atom. The W(1)-Sb(2) bond length is 0.86 Å. Sb(2) is bonded in a single-bond geometry to one W(1) atom.