data_SbAu2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.39
_cell_length_b   3.39
_cell_length_c   7.54
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SbAu2Cl
_chemical_formula_sum   'Sb1 Au2 Cl1'
_cell_volume   86.85
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb3  1  0.0  0.0  0.77  1.0
  Au  Au0  1  0.7  0.7  0.54  1.0
  Au  Au1  1  0.7  0.7  1.0  1.0
  Cl  Cl2  1  0.0  0.0  0.0  1.0

data_SbAu2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.8
_cell_length_b   4.8
_cell_length_c   7.54
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   SbAu2Cl
_chemical_formula_sum   'Sb2 Au4 Cl2'
_cell_volume   173.71
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  2  0.0  0.0  0.77  1.0
  Au  Au1  2  0.2  0.5  0.54  1.0
  Au  Au2  2  0.2  0.5  1.0  1.0
  Cl  Cl3  2  0.0  0.0  0.0  1.0

Sb Au Au Cl
Au2SbCl crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Au2SbCl clusters. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted single-bond geometry to one Sb(1) atom. The Au(1)-Sb(1) bond length is 2.25 Å. In the second Au site, Au(2) is bonded in a distorted single-bond geometry to one Cl(1) atom. The Au(2)-Cl(1) bond length is 1.46 Å. Sb(1) is bonded in a 1-coordinate geometry to one Au(1) and one Cl(1) atom. The Sb(1)-Cl(1) bond length is 1.72 Å. Cl(1) is bonded in a distorted L-shaped geometry to one Au(2) and one Sb(1) atom.