data_LiGa2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.31
_cell_length_b   3.31
_cell_length_c   5.55
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiGa2Pd
_chemical_formula_sum   'Li1 Ga2 Pd1'
_cell_volume   60.81
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li2  1  0.0  0.0  0.79  1.0
  Ga  Ga0  1  0.0  0.0  0.43  1.0
  Ga  Ga1  1  0.65  0.65  0.48  1.0
  Pd  Pd3  1  0.65  0.65  0.18  1.0

data_LiGa2Pd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.68
_cell_length_b   4.68
_cell_length_c   5.55
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LiGa2Pd
_chemical_formula_sum   'Li2 Ga4 Pd2'
_cell_volume   121.62
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.79  1.0
  Ga  Ga1  2  0.0  0.0  0.43  1.0
  Ga  Ga2  2  0.15  0.5  0.48  1.0
  Pd  Pd3  2  0.15  0.5  0.18  1.0

Li Ga Ga Pd
LiPdGa2 crystallizes in the monoclinic Cm space group. Li(1) is bonded in a 7-coordinate geometry to three equivalent Pd(1), one Ga(1), and three equivalent Ga(2) atoms. There is one shorter (2.67 Å) and two longer (3.24 Å) Li(1)-Pd(1) bond lengths. The Li(1)-Ga(1) bond length is 2.02 Å. There is one shorter (2.39 Å) and two longer (3.02 Å) Li(1)-Ga(2) bond lengths. Pd(1) is bonded in a 1-coordinate geometry to three equivalent Li(1) and one Ga(2) atom. The Pd(1)-Ga(2) bond length is 1.67 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 1-coordinate geometry to one Li(1) atom. In the second Ga site, Ga(2) is bonded in a 1-coordinate geometry to three equivalent Li(1) and one Pd(1) atom.