data_TcBiMo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.39
_cell_length_b   5.39
_cell_length_c   5.39
_cell_angle_alpha   143.26
_cell_angle_beta   131.58
_cell_angle_gamma   62.28
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TcBiMo2
_chemical_formula_sum   'Tc1 Bi1 Mo2'
_cell_volume   69.4
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc3  1  0.0  0.0  0.61  1.0
  Bi  Bi0  1  0.0  0.21  0.3  1.0
  Mo  Mo1  1  0.0  0.0  0.04  1.0
  Mo  Mo2  1  0.7  0.0  0.29  1.0

data_TcBiMo2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.4
_cell_length_b   4.42
_cell_length_c   5.39
_cell_angle_alpha   114.21
_cell_angle_beta   108.37
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TcBiMo2
_chemical_formula_sum   'Tc1 Bi1 Mo2'
_cell_volume   69.4
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.0  0.61  0.61  1.0
  Bi  Bi1  1  0.79  0.09  0.09  1.0
  Mo  Mo2  1  0.0  0.04  0.04  1.0
  Mo  Mo3  1  0.0  0.29  0.59  1.0

Tc Bi Mo Mo
MoTcBiMo crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one BiMo cluster and one MoTc cluster. In the BiMo cluster, Mo(1) is bonded in a distorted single-bond geometry to one Bi(1) atom. The Mo(1)-Bi(1) bond length is 0.84 Å. Bi(1) is bonded in a single-bond geometry to one Mo(1) atom. In the MoTc cluster, Mo(2) is bonded in a distorted single-bond geometry to one Tc(1) atom. The Mo(2)-Tc(1) bond length is 1.37 Å. Tc(1) is bonded in a distorted single-bond geometry to one Mo(2) atom.