data_V2ReAg
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.04
_cell_length_b   3.04
_cell_length_c   6.47
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2ReAg
_chemical_formula_sum   'V2 Re1 Ag1'
_cell_volume   59.78
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.0  0.02  1.0
  V  V3  1  0.52  0.52  0.41  1.0
  Re  Re1  1  0.52  0.52  0.12  1.0
  Ag  Ag0  1  0.0  0.0  0.16  1.0

data_V2ReAg
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.3
_cell_length_b   4.3
_cell_length_c   6.47
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   V2ReAg
_chemical_formula_sum   'V4 Re2 Ag2'
_cell_volume   119.56
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.02  1.0
  V  V1  2  0.02  0.5  0.41  1.0
  Re  Re2  2  0.02  0.5  0.12  1.0
  Ag  Ag3  2  0.0  0.0  0.16  1.0

V V Re Ag
ReVVAg is alpha Niobium phosphide-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ReV clusters and two VAg clusters. In each ReV cluster, V(2) is bonded in a single-bond geometry to one Re(1) atom. The V(2)-Re(1) bond length is 1.89 Å. Re(1) is bonded in a distorted single-bond geometry to one V(2) atom. In each VAg cluster, V(1) is bonded in a single-bond geometry to one Ag(1) atom. The V(1)-Ag(1) bond length is 0.89 Å. Ag(1) is bonded in a single-bond geometry to one V(1) atom.