data_CdBi2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.32
_cell_length_b   3.32
_cell_length_c   8.82
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdBi2Rh
_chemical_formula_sum   'Cd1 Bi2 Rh1'
_cell_volume   97.43
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd2  1  0.66  0.66  0.89  1.0
  Bi  Bi0  1  0.66  0.66  0.18  1.0
  Bi  Bi1  1  0.0  0.0  0.42  1.0
  Rh  Rh3  1  0.0  0.0  0.57  1.0

data_CdBi2Rh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.7
_cell_length_b   4.7
_cell_length_c   8.82
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   CdBi2Rh
_chemical_formula_sum   'Cd2 Bi4 Rh2'
_cell_volume   194.87
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  2  0.16  0.5  0.89  1.0
  Bi  Bi1  2  0.0  0.0  0.42  1.0
  Bi  Bi2  2  0.16  0.5  0.18  1.0
  Rh  Rh3  2  0.0  0.0  0.57  1.0

Cd Bi Bi Rh
RhCdBi2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two RhCdBi2 clusters. Rh(1) is bonded in a single-bond geometry to one Cd(1) and one Bi(2) atom. The Rh(1)-Cd(1) bond length is 3.21 Å. The Rh(1)-Bi(2) bond length is 1.32 Å. Cd(1) is bonded in a distorted bent 150 degrees geometry to one Rh(1) and one Bi(1) atom. The Cd(1)-Bi(1) bond length is 2.62 Å. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 1-coordinate geometry to one Cd(1) atom. In the second Bi site, Bi(2) is bonded in a single-bond geometry to one Rh(1) atom.