data_Co2GeW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.58
_cell_length_b   4.58
_cell_length_c   4.58
_cell_angle_alpha   132.74
_cell_angle_beta   132.74
_cell_angle_gamma   69.07
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Co2GeW
_chemical_formula_sum   'Co2 Ge1 W1'
_cell_volume   50.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.0  0.0  1.0
  Co  Co1  1  0.84  0.0  0.89  1.0
  Ge  Ge2  1  0.0  0.0  0.77  1.0
  W  W3  1  0.0  0.84  0.89  1.0

data_Co2GeW
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.67
_cell_length_b   3.67
_cell_length_c   4.58
_cell_angle_alpha   113.63
_cell_angle_beta   113.63
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Co2GeW
_chemical_formula_sum   'Co2 Ge1 W1'
_cell_volume   50.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.0  0.0  1.0
  Co  Co1  1  0.11  0.0  0.95  1.0
  Ge  Ge2  1  0.23  0.0  0.23  1.0
  W  W3  1  0.95  0.84  0.95  1.0

Co Co Ge W
WCo2Ge is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one WCo2Ge cluster. W(1) is bonded in a single-bond geometry to one Co(1) and one Ge(1) atom. The W(1)-Co(1) bond length is 0.55 Å. The W(1)-Ge(1) bond length is 1.16 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted single-bond geometry to one W(1), one Co(2), and one Ge(1) atom. The Co(1)-Co(2) bond length is 0.55 Å. The Co(1)-Ge(1) bond length is 1.03 Å. In the second Co site, Co(2) is bonded in a distorted single-bond geometry to one Co(1) and one Ge(1) atom. The Co(2)-Ge(1) bond length is 1.16 Å. Ge(1) is bonded in a 3-coordinate geometry to one W(1), one Co(1), and one Co(2) atom.