data_SnB2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.39
_cell_length_b   3.22
_cell_length_c   5.19
_cell_angle_alpha   90.0
_cell_angle_beta   97.07
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SnB2Pd
_chemical_formula_sum   'Sn1 B2 Pd1'
_cell_volume   56.22
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn3  1  0.37  0.0  0.58  1.0
  B  B0  1  0.07  0.61  0.35  1.0
  B  B1  1  0.68  0.61  0.8  1.0
  Pd  Pd2  1  0.0  0.0  0.0  1.0

data_SnB2Pd
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.22
_cell_length_b   3.39
_cell_length_c   5.19
_cell_angle_alpha   97.07
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SnB2Pd
_chemical_formula_sum   'Sn1 B2 Pd1'
_cell_volume   56.22
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.0  0.63  0.42  1.0
  B  B1  1  0.39  0.32  0.2  1.0
  B  B2  1  0.39  0.93  0.65  1.0
  Pd  Pd3  1  0.0  0.0  0.0  1.0

Sn B B Pd
PdB2Sn crystallizes in the triclinic P1 space group. Pd(1) is bonded in a 5-coordinate geometry to two equivalent B(1), two equivalent B(2), and one Sn(1) atom. There is one shorter (2.21 Å) and one longer (2.67 Å) Pd(1)-B(1) bond length. There is one shorter (1.88 Å) and one longer (2.41 Å) Pd(1)-B(2) bond length. The Pd(1)-Sn(1) bond length is 2.67 Å. There are two inequivalent B sites. In the first B site, B(1) is bonded in a 4-coordinate geometry to two equivalent Pd(1) and two equivalent Sn(1) atoms. There is one shorter (1.93 Å) and one longer (2.45 Å) B(1)-Sn(1) bond length. In the second B site, B(2) is bonded in a 4-coordinate geometry to two equivalent Pd(1) and two equivalent Sn(1) atoms. There is one shorter (1.93 Å) and one longer (2.45 Å) B(2)-Sn(1) bond length. Sn(1) is bonded in a 5-coordinate geometry to one Pd(1), two equivalent B(1), and two equivalent B(2) atoms.