data_LaIn2B
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.31
_cell_length_b   7.31
_cell_length_c   7.31
_cell_angle_alpha   32.12
_cell_angle_beta   32.12
_cell_angle_gamma   32.12
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaIn2B
_chemical_formula_sum   'La1 In2 B1'
_cell_volume   98.13
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La3  1  0.0  0.0  0.96  1.0
  In  In1  1  0.0  0.0  0.21  1.0
  In  In2  1  0.0  0.0  0.23  1.0
  B  B0  1  0.0  0.0  0.42  1.0

data_LaIn2B
_symmetry_space_group_name_H-M   Cm
_cell_length_a   7.01
_cell_length_b   4.04
_cell_length_c   7.31
_cell_angle_alpha   90.0
_cell_angle_beta   108.63
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LaIn2B
_chemical_formula_sum   'La2 In4 B2'
_cell_volume   196.26
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  2  0.0  0.0  0.04  1.0
  In  In1  2  0.0  0.0  0.77  1.0
  In  In2  2  0.0  0.0  0.79  1.0
  B  B3  2  0.0  0.0  0.58  1.0

La In In B
LaIn2B is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two LaIn2B clusters. La(1) is bonded in a single-bond geometry to one In(1) atom. The La(1)-In(1) bond length is 1.83 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a linear geometry to one La(1) and one In(2) atom. The In(1)-In(2) bond length is 0.15 Å. In the second In site, In(2) is bonded in a linear geometry to one In(1) and one B(1) atom. The In(2)-B(1) bond length is 1.37 Å. B(1) is bonded in a single-bond geometry to one In(2) atom.