data_Tl2BiMo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.03
_cell_length_b   11.03
_cell_length_c   11.03
_cell_angle_alpha   16.96
_cell_angle_beta   16.96
_cell_angle_gamma   16.96
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Tl2BiMo
_chemical_formula_sum   'Tl2 Bi1 Mo1'
_cell_volume   99.49
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl2  1  0.0  0.0  0.5  1.0
  Tl  Tl3  1  0.0  0.0  0.1  1.0
  Bi  Bi0  1  0.0  0.0  0.3  1.0
  Mo  Mo1  1  0.0  0.0  0.0  1.0

data_Tl2BiMo
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.63
_cell_length_b   3.25
_cell_length_c   11.03
_cell_angle_alpha   90.0
_cell_angle_beta   99.8
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Tl2BiMo
_chemical_formula_sum   'Tl4 Bi2 Mo2'
_cell_volume   198.98
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  2  -0.0  0.0  0.9  1.0
  Tl  Tl1  2  0.0  0.0  0.5  1.0
  Bi  Bi2  2  -0.0  0.0  0.7  1.0
  Mo  Mo3  2  0.0  0.0  0.0  1.0

Tl Tl Bi Mo
MoTl2Bi is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two MoTl2Bi clusters. Mo(1) is bonded in a single-bond geometry to one Tl(2) atom. The Mo(1)-Tl(2) bond length is 1.10 Å. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a single-bond geometry to one Bi(1) atom. The Tl(1)-Bi(1) bond length is 2.19 Å. In the second Tl site, Tl(2) is bonded in a distorted single-bond geometry to one Mo(1) and one Bi(1) atom. The Tl(2)-Bi(1) bond length is 2.19 Å. Bi(1) is bonded in a linear geometry to one Tl(1) and one Tl(2) atom.