data_Na2ScAg
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.42
_cell_length_b   4.97
_cell_length_c   5.73
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na2ScAg
_chemical_formula_sum   'Na2 Sc1 Ag1'
_cell_volume   97.25
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na1  1  0.0  0.0  0.0  1.0
  Na  Na2  1  0.71  0.48  0.0  1.0
  Sc  Sc3  1  0.71  0.0  0.86  1.0
  Ag  Ag0  1  0.0  0.48  0.86  1.0

data_Na2ScAg
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.42
_cell_length_b   4.97
_cell_length_c   5.73
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na2ScAg
_chemical_formula_sum   'Na2 Sc1 Ag1'
_cell_volume   97.25
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.0  1.0
  Na  Na1  1  0.71  0.48  0.0  1.0
  Sc  Sc2  1  0.71  0.0  0.86  1.0
  Ag  Ag3  1  -0.0  0.48  0.86  1.0

Na Na Sc Ag
NaScAgNa crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one AgNa cluster and one NaSc cluster. In the AgNa cluster, Na(2) is bonded in a distorted single-bond geometry to one Ag(1) atom. The Na(2)-Ag(1) bond length is 1.27 Å. Ag(1) is bonded in a distorted single-bond geometry to one Na(2) atom. In the NaSc cluster, Na(1) is bonded in a distorted single-bond geometry to one Sc(1) atom. The Na(1)-Sc(1) bond length is 1.27 Å. Sc(1) is bonded in a distorted single-bond geometry to one Na(1) atom.