data_ScRhCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.35
_cell_length_b   4.35
_cell_length_c   3.53
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScRhCl2
_chemical_formula_sum   'Sc1 Rh1 Cl2'
_cell_volume   66.77
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc3  1  0.0  0.0  0.0  1.0
  Rh  Rh2  1  0.17  0.17  0.0  1.0
  Cl  Cl0  1  0.0  0.17  0.77  1.0
  Cl  Cl1  1  0.17  0.0  0.77  1.0

data_ScRhCl2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.15
_cell_length_b   6.15
_cell_length_c   3.53
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ScRhCl2
_chemical_formula_sum   'Sc2 Rh2 Cl4'
_cell_volume   133.55
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  2  0.0  0.0  0.0  1.0
  Rh  Rh1  2  0.17  0.0  0.0  1.0
  Cl  Cl2  4  0.09  0.09  0.77  1.0

Sc Rh Cl Cl
ScRhCl2 is alpha Po structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ScRhCl2 clusters. Sc(1) is bonded in a 3-coordinate geometry to one Rh(1) and two equivalent Cl(1) atoms. The Sc(1)-Rh(1) bond length is 1.07 Å. Both Sc(1)-Cl(1) bond lengths are 1.12 Å. Rh(1) is bonded in a 3-coordinate geometry to one Sc(1) and two equivalent Cl(1) atoms. Both Rh(1)-Cl(1) bond lengths are 1.12 Å. Cl(1) is bonded in a 3-coordinate geometry to one Sc(1), one Rh(1), and one Cl(1) atom. The Cl(1)-Cl(1) bond length is 1.07 Å.