data_NiRhCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.92
_cell_length_b   5.92
_cell_length_c   5.92
_cell_angle_alpha   146.32
_cell_angle_beta   146.32
_cell_angle_gamma   48.38
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NiRhCl2
_chemical_formula_sum   'Ni1 Rh1 Cl2'
_cell_volume   63.69
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni2  1  0.0  0.0  0.4  1.0
  Rh  Rh3  1  0.0  0.72  0.7  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0
  Cl  Cl1  1  0.72  0.0  0.7  1.0

data_NiRhCl2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.43
_cell_length_b   3.43
_cell_length_c   5.92
_cell_angle_alpha   106.84
_cell_angle_beta   106.84
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NiRhCl2
_chemical_formula_sum   'Ni1 Rh1 Cl2'
_cell_volume   63.69
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.4  0.4  0.4  1.0
  Rh  Rh1  1  0.99  0.7  0.99  1.0
  Cl  Cl2  1  0.0  0.0  0.0  1.0
  Cl  Cl3  1  0.7  0.99  0.99  1.0

Ni Rh Cl Cl
RhNiCl2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one RhNiCl2 cluster. Rh(1) is bonded in a distorted single-bond geometry to one Cl(1) and one Cl(2) atom. The Rh(1)-Cl(1) bond length is 1.00 Å. The Rh(1)-Cl(2) bond length is 1.38 Å. Ni(1) is bonded in a distorted single-bond geometry to one Cl(1) atom. The Ni(1)-Cl(1) bond length is 2.40 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Rh(1), one Ni(1), and one Cl(2) atom. The Cl(1)-Cl(2) bond length is 1.00 Å. In the second Cl site, Cl(2) is bonded in a 2-coordinate geometry to one Rh(1) and one Cl(1) atom.