data_Cd2BiPt
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.42
_cell_length_b   3.42
_cell_length_c   7.77
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2BiPt
_chemical_formula_sum   'Cd2 Bi1 Pt1'
_cell_volume   90.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd1  1  0.0  0.0  0.28  1.0
  Cd  Cd2  1  0.71  0.71  0.16  1.0
  Bi  Bi0  1  0.71  0.71  0.46  1.0
  Pt  Pt3  1  0.0  0.0  0.75  1.0

data_Cd2BiPt
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.83
_cell_length_b   4.83
_cell_length_c   7.77
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Cd2BiPt
_chemical_formula_sum   'Cd4 Bi2 Pt2'
_cell_volume   181.29
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  2  0.0  0.0  0.28  1.0
  Cd  Cd1  2  0.21  0.5  0.16  1.0
  Bi  Bi2  2  0.21  0.5  0.46  1.0
  Pt  Pt3  2  0.0  0.0  0.75  1.0

Cd Cd Bi Pt
PtCd2Bi crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two PtCd2Bi clusters. Pt(1) is bonded in a distorted single-bond geometry to one Bi(1) atom. The Pt(1)-Bi(1) bond length is 2.66 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 2-coordinate geometry to one Cd(2) and one Bi(1) atom. The Cd(1)-Cd(2) bond length is 1.71 Å. The Cd(1)-Bi(1) bond length is 1.96 Å. In the second Cd site, Cd(2) is bonded in a 2-coordinate geometry to one Cd(1) and one Bi(1) atom. The Cd(2)-Bi(1) bond length is 2.33 Å. Bi(1) is bonded in a 1-coordinate geometry to one Pt(1), one Cd(1), and one Cd(2) atom.