data_B(TeP)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.34
_cell_length_b   5.34
_cell_length_c   5.34
_cell_angle_alpha   113.8
_cell_angle_beta   113.8
_cell_angle_gamma   101.12
_symmetry_Int_Tables_number   1
_chemical_formula_structural   B(TeP)2
_chemical_formula_sum   'B1 Te2 P2'
_cell_volume   115.62
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.0  0.0  0.0  1.0
  Te  Te3  1  0.0  0.92  0.7  1.0
  Te  Te4  1  0.92  0.0  0.7  1.0
  P  P1  1  0.0  0.0  0.98  1.0
  P  P2  1  0.0  0.0  0.81  1.0

data_B(TeP)2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.79
_cell_length_b   8.25
_cell_length_c   5.34
_cell_angle_alpha   90.0
_cell_angle_beta   129.44
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   B(TeP)2
_chemical_formula_sum   'B2 Te4 P4'
_cell_volume   231.23
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  2  0.0  0.0  0.0  1.0
  Te  Te1  4  0.04  0.04  0.3  1.0
  P  P2  2  0.0  0.0  0.02  1.0
  P  P3  2  0.0  0.0  0.19  1.0

B Te Te P P
B(PTe)2 is Indium structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two B(PTe)2 clusters. B(1) is bonded in a single-bond geometry to one P(1) atom. The B(1)-P(1) bond length is 0.13 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a linear geometry to one B(1) and one P(2) atom. The P(1)-P(2) bond length is 0.87 Å. In the second P site, P(2) is bonded in a 3-coordinate geometry to one P(1) and two equivalent Te(1) atoms. Both P(2)-Te(1) bond lengths are 0.60 Å. Te(1) is bonded in a distorted single-bond geometry to one P(2) atom.