data_Zn2SbCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.95
_cell_length_b   4.95
_cell_length_c   4.95
_cell_angle_alpha   121.28
_cell_angle_beta   121.28
_cell_angle_gamma   87.79
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zn2SbCl
_chemical_formula_sum   'Zn2 Sb1 Cl1'
_cell_volume   83.91
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn2  1  0.0  0.43  0.78  1.0
  Zn  Zn3  1  0.43  0.0  0.78  1.0
  Sb  Sb1  1  0.0  0.0  0.57  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Zn2SbCl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.86
_cell_length_b   6.86
_cell_length_c   4.95
_cell_angle_alpha   90.0
_cell_angle_beta   133.9
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Zn2SbCl
_chemical_formula_sum   'Zn4 Sb2 Cl2'
_cell_volume   167.82
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  4  0.29  0.29  0.36  1.0
  Sb  Sb1  2  0.0  0.0  0.57  1.0
  Cl  Cl2  2  0.0  0.0  0.0  1.0

Zn Zn Sb Cl
Zn2SbCl crystallizes in the monoclinic Cm space group. Zn(1) is bonded in a distorted linear geometry to one Sb(1) and two equivalent Cl(1) atoms. The Zn(1)-Sb(1) bond length is 1.80 Å. There is one shorter (2.46 Å) and one longer (2.82 Å) Zn(1)-Cl(1) bond length. Sb(1) is bonded in a distorted see-saw-like geometry to two equivalent Zn(1) and two equivalent Cl(1) atoms. There is one shorter (2.15 Å) and one longer (2.80 Å) Sb(1)-Cl(1) bond length. Cl(1) is bonded in a 6-coordinate geometry to four equivalent Zn(1) and two equivalent Sb(1) atoms.