data_LiTePb2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.1
_cell_length_b   7.1
_cell_length_c   4.48
_cell_angle_alpha   105.19
_cell_angle_beta   105.19
_cell_angle_gamma   33.1
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiTePb2
_chemical_formula_sum   'Li1 Te1 Pb2'
_cell_volume   118.68
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.0  1.0
  Te  Te3  1  0.19  0.0  0.16  1.0
  Pb  Pb1  1  0.84  0.0  0.03  1.0
  Pb  Pb2  1  0.54  0.0  0.28  1.0

data_LiTePb2
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.04
_cell_length_b   4.48
_cell_length_c   7.1
_cell_angle_alpha   105.19
_cell_angle_beta   106.55
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiTePb2
_chemical_formula_sum   'Li1 Te1 Pb2'
_cell_volume   118.68
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.0  1.0
  Te  Te1  1  0.0  0.16  0.19  1.0
  Pb  Pb2  1  0.0  0.03  0.84  1.0
  Pb  Pb3  1  0.0  0.28  0.54  1.0

Li Te Pb Pb
LiPb2Te is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LiPb2Te cluster. Li(1) is bonded in a bent 150 degrees geometry to one Pb(1) and one Te(1) atom. The Li(1)-Pb(1) bond length is 1.16 Å. The Li(1)-Te(1) bond length is 1.36 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a single-bond geometry to one Li(1) atom. In the second Pb site, Pb(2) is bonded in a 1-coordinate geometry to one Te(1) atom. The Pb(2)-Te(1) bond length is 2.40 Å. Te(1) is bonded in a distorted single-bond geometry to one Li(1) and one Pb(2) atom.