data_Ba2MnV
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.82
_cell_length_b   10.82
_cell_length_c   10.82
_cell_angle_alpha   20.61
_cell_angle_beta   20.61
_cell_angle_gamma   20.61
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ba2MnV
_chemical_formula_sum   'Ba2 Mn1 V1'
_cell_volume   137.34
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.0  0.0  0.86  1.0
  Ba  Ba1  1  0.0  0.0  0.89  1.0
  Mn  Mn2  1  0.0  0.0  0.88  1.0
  V  V3  1  0.0  0.0  0.0  1.0

data_Ba2MnV
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.7
_cell_length_b   3.87
_cell_length_c   10.82
_cell_angle_alpha   90.0
_cell_angle_beta   101.92
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Ba2MnV
_chemical_formula_sum   'Ba4 Mn2 V2'
_cell_volume   274.68
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  2  -0.0  0.0  0.14  1.0
  Ba  Ba1  2  -0.0  0.0  0.11  1.0
  Mn  Mn2  2  -0.0  0.0  0.12  1.0
  V  V3  2  0.0  0.0  0.0  1.0

Ba Ba Mn V
Ba2VMn is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Ba2VMn clusters. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a single-bond geometry to one Mn(1) atom. The Ba(1)-Mn(1) bond length is 0.17 Å. In the second Ba site, Ba(2) is bonded in a linear geometry to one V(1) and one Mn(1) atom. The Ba(2)-V(1) bond length is 1.15 Å. The Ba(2)-Mn(1) bond length is 0.17 Å. V(1) is bonded in a single-bond geometry to one Ba(2) atom. Mn(1) is bonded in a linear geometry to one Ba(1) and one Ba(2) atom.