data_Y(TeRh)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.69
_cell_length_b   5.69
_cell_length_c   5.69
_cell_angle_alpha   127.79
_cell_angle_beta   127.79
_cell_angle_gamma   76.97
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Y(TeRh)2
_chemical_formula_sum   'Y1 Te2 Rh2'
_cell_volume   111.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y4  1  0.0  0.0  0.0  1.0
  Te  Te2  1  0.0  0.5  0.23  1.0
  Te  Te3  1  0.5  0.0  0.23  1.0
  Rh  Rh0  1  0.0  0.0  0.78  1.0
  Rh  Rh1  1  0.0  0.0  0.13  1.0

data_Y(TeRh)2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   7.08
_cell_length_b   7.08
_cell_length_c   5.69
_cell_angle_alpha   90.0
_cell_angle_beta   128.48
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Y(TeRh)2
_chemical_formula_sum   'Y2 Te4 Rh4'
_cell_volume   223.39
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  2  0.0  0.0  0.0  1.0
  Te  Te1  4  0.02  0.25  0.28  1.0
  Rh  Rh2  2  0.22  0.0  0.22  1.0
  Rh  Rh3  2  0.37  0.5  0.87  1.0

Y Te Te Rh Rh
Y(RhTe)2 crystallizes in the monoclinic Cm space group. Y(1) is bonded in a distorted linear geometry to one Rh(1), one Rh(2), and two equivalent Te(1) atoms. The Y(1)-Rh(1) bond length is 1.27 Å. The Y(1)-Rh(2) bond length is 0.75 Å. Both Y(1)-Te(1) bond lengths are 2.31 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a single-bond geometry to one Y(1) and four equivalent Te(1) atoms. There are two shorter (2.41 Å) and two longer (2.63 Å) Rh(1)-Te(1) bond lengths. In the second Rh site, Rh(2) is bonded in a single-bond geometry to one Y(1) and four equivalent Te(1) atoms. There are two shorter (2.57 Å) and two longer (3.18 Å) Rh(2)-Te(1) bond lengths. Te(1) is bonded in a 5-coordinate geometry to one Y(1), two equivalent Rh(1), and two equivalent Rh(2) atoms.