data_AgGeW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.78
_cell_length_b   2.78
_cell_length_c   8.99
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   108.95
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgGeW2
_chemical_formula_sum   'Ag1 Ge1 W2'
_cell_volume   65.52
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.0  0.0  0.49  1.0
  Ge  Ge1  1  0.0  0.0  0.0  1.0
  W  W2  1  0.61  0.0  0.1  1.0
  W  W3  1  0.61  0.0  0.89  1.0

data_AgGeW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.78
_cell_length_b   2.78
_cell_length_c   8.99
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   108.95
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgGeW2
_chemical_formula_sum   'Ag1 Ge1 W2'
_cell_volume   65.52
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.0  0.0  0.49  1.0
  Ge  Ge1  1  0.0  0.0  0.0  1.0
  W  W2  1  0.61  0.0  0.1  1.0
  W  W3  1  0.61  0.0  0.89  1.0

Ag Ge W W
W2AgGe crystallizes in the triclinic P1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 2-coordinate geometry to one Ag(1) and two equivalent Ge(1) atoms. The W(1)-Ag(1) bond length is 3.74 Å. There is one shorter (1.37 Å) and one longer (1.91 Å) W(1)-Ge(1) bond length. In the second W site, W(2) is bonded in a 2-coordinate geometry to one Ag(1) and two equivalent Ge(1) atoms. The W(2)-Ag(1) bond length is 3.74 Å. There is one shorter (1.45 Å) and one longer (1.96 Å) W(2)-Ge(1) bond length. Ag(1) is bonded in a 8-coordinate geometry to one W(1), one W(2), and six equivalent Ag(1) atoms. There are four shorter (2.78 Å) and two longer (3.23 Å) Ag(1)-Ag(1) bond lengths. Ge(1) is bonded in a 4-coordinate geometry to two equivalent W(1) and two equivalent W(2) atoms.