data_Co2MoRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.68
_cell_length_b   2.68
_cell_length_c   7.2
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   91.28
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Co2MoRh
_chemical_formula_sum   'Co2 Mo1 Rh1'
_cell_volume   51.67
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.0  0.08  1.0
  Co  Co1  1  0.87  0.0  0.54  1.0
  Mo  Mo2  1  0.0  0.0  0.69  1.0
  Rh  Rh3  1  0.87  0.0  0.69  1.0

data_Co2MoRh
_symmetry_space_group_name_H-M   Pm
_cell_length_a   2.68
_cell_length_b   2.68
_cell_length_c   7.2
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   Co2MoRh
_chemical_formula_sum   'Co2 Mo1 Rh1'
_cell_volume   51.68
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.0  0.08  1.0
  Co  Co1  1  0.87  0.0  0.54  1.0
  Mo  Mo2  1  0.0  0.0  0.69  1.0
  Rh  Rh3  1  0.87  0.0  0.69  1.0

Co Co Mo Rh
MoRhCo2 crystallizes in the monoclinic Pm space group. Mo(1) is bonded in a single-bond geometry to one Rh(1), one Co(1), and one Co(2) atom. The Mo(1)-Rh(1) bond length is 0.34 Å. The Mo(1)-Co(1) bond length is 2.75 Å. The Mo(1)-Co(2) bond length is 1.18 Å. Rh(1) is bonded in a distorted single-bond geometry to one Mo(1), one Co(1), and one Co(2) atom. The Rh(1)-Co(1) bond length is 2.80 Å. The Rh(1)-Co(2) bond length is 1.10 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one Mo(1), one Rh(1), one Co(2), and four equivalent Co(1) atoms to form a mixture of distorted corner and edge-sharing CoCo5MoRh pentagonal bipyramids. The Co(1)-Co(2) bond length is 3.33 Å. All Co(1)-Co(1) bond lengths are 2.68 Å. In the second Co site, Co(2) is bonded in a 2-coordinate geometry to one Mo(1), one Rh(1), and one Co(1) atom.