data_CoGe2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.18
_cell_length_b   4.18
_cell_length_c   5.16
_cell_angle_alpha   101.32
_cell_angle_beta   101.32
_cell_angle_gamma   41.12
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CoGe2Pd
_chemical_formula_sum   'Co1 Ge2 Pd1'
_cell_volume   57.98
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.0  0.0  1.0
  Ge  Ge1  1  0.19  0.0  0.94  1.0
  Ge  Ge2  1  0.56  0.0  0.1  1.0
  Pd  Pd3  1  0.38  0.0  0.52  1.0

data_CoGe2Pd
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.94
_cell_length_b   4.18
_cell_length_c   5.16
_cell_angle_alpha   101.32
_cell_angle_beta   90.0
_cell_angle_gamma   110.56
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CoGe2Pd
_chemical_formula_sum   'Co1 Ge2 Pd1'
_cell_volume   57.98
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.0  0.0  1.0
  Ge  Ge1  1  0.0  0.44  0.9  1.0
  Ge  Ge2  1  0.0  0.81  0.06  1.0
  Pd  Pd3  1  0.0  0.62  0.48  1.0

Co Ge Ge Pd
CoPdGe2 crystallizes in the triclinic P1 space group. Co(1) is bonded in a distorted single-bond geometry to two equivalent Pd(1), one Ge(1), and one Ge(2) atom. There is one shorter (2.83 Å) and one longer (3.23 Å) Co(1)-Pd(1) bond length. The Co(1)-Ge(1) bond length is 0.91 Å. The Co(1)-Ge(2) bond length is 2.01 Å. Pd(1) is bonded in a 7-coordinate geometry to two equivalent Co(1), two equivalent Pd(1), one Ge(1), and two equivalent Ge(2) atoms. Both Pd(1)-Pd(1) bond lengths are 2.94 Å. The Pd(1)-Ge(1) bond length is 2.43 Å. There is one shorter (2.43 Å) and one longer (2.95 Å) Pd(1)-Ge(2) bond length. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a distorted single-bond geometry to one Co(1), one Pd(1), and one Ge(2) atom. The Ge(1)-Ge(2) bond length is 1.61 Å. In the second Ge site, Ge(2) is bonded in a 3-coordinate geometry to one Co(1), two equivalent Pd(1), and one Ge(1) atom.