data_VCo2Re
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.6
_cell_length_b   2.6
_cell_length_c   7.3
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCo2Re
_chemical_formula_sum   'V1 Co2 Re1'
_cell_volume   49.23
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Co  Co0  1  0.3  0.3  0.82  1.0
  Co  Co1  1  0.3  0.3  0.48  1.0
  Re  Re2  1  0.0  0.0  0.65  1.0

data_VCo2Re
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.67
_cell_length_b   3.67
_cell_length_c   7.3
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VCo2Re
_chemical_formula_sum   'V2 Co4 Re2'
_cell_volume   98.46
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.0  1.0
  Co  Co1  2  0.3  0.0  0.48  1.0
  Co  Co2  2  0.3  0.0  0.82  1.0
  Re  Re3  2  0.0  0.0  0.65  1.0

V Co Co Re
VReCo2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two VReCo2 clusters. V(1) is bonded in a distorted single-bond geometry to one Co(1) atom. The V(1)-Co(1) bond length is 1.69 Å. Re(1) is bonded in a distorted water-like geometry to one Co(1) and one Co(2) atom. The Re(1)-Co(1) bond length is 1.67 Å. The Re(1)-Co(2) bond length is 1.67 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 2-coordinate geometry to one V(1) and one Re(1) atom. In the second Co site, Co(2) is bonded in a distorted single-bond geometry to one Re(1) atom.