data_GeOs2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.28
_cell_length_b   8.28
_cell_length_c   8.28
_cell_angle_alpha   20.36
_cell_angle_beta   20.36
_cell_angle_gamma   20.36
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GeOs2Cl
_chemical_formula_sum   'Ge1 Os2 Cl1'
_cell_volume   60.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge1  1  0.0  0.0  0.16  1.0
  Os  Os2  1  0.0  0.0  0.33  1.0
  Os  Os3  1  0.0  0.0  0.98  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_GeOs2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.07
_cell_length_b   2.93
_cell_length_c   8.28
_cell_angle_alpha   90.0
_cell_angle_beta   101.77
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   GeOs2Cl
_chemical_formula_sum   'Ge2 Os4 Cl2'
_cell_volume   120.12
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  2  0.0  0.0  0.84  1.0
  Os  Os1  2  0.0  0.0  0.67  1.0
  Os  Os2  2  0.0  0.0  0.02  1.0
  Cl  Cl3  2  0.0  0.0  0.0  1.0

Ge Os Os Cl
Os2GeCl is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Os2GeCl clusters. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a single-bond geometry to one Ge(1) atom. The Os(1)-Ge(1) bond length is 1.43 Å. In the second Os site, Os(2) is bonded in a single-bond geometry to one Cl(1) atom. The Os(2)-Cl(1) bond length is 0.14 Å. Ge(1) is bonded in a distorted linear geometry to one Os(1) and one Cl(1) atom. The Ge(1)-Cl(1) bond length is 1.29 Å. Cl(1) is bonded in a distorted linear geometry to one Os(2) and one Ge(1) atom.