data_LaCoBi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.63
_cell_length_b   3.76
_cell_length_c   7.84
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaCoBi2
_chemical_formula_sum   'La1 Co1 Bi2'
_cell_volume   106.99
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La3  1  0.81  0.88  0.65  1.0
  Co  Co2  1  0.0  0.0  0.63  1.0
  Bi  Bi0  1  0.0  0.0  0.12  1.0
  Bi  Bi1  1  0.81  0.88  0.37  1.0

data_LaCoBi2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.63
_cell_length_b   3.76
_cell_length_c   7.84
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaCoBi2
_chemical_formula_sum   'La1 Co1 Bi2'
_cell_volume   106.99
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.81  0.88  0.65  1.0
  Co  Co1  1  0.0  0.0  0.63  1.0
  Bi  Bi2  1  0.0  0.0  0.12  1.0
  Bi  Bi3  1  0.81  0.88  0.37  1.0

La Co Bi Bi
LaCoBi2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LaCoBi2 cluster. La(1) is bonded in a single-bond geometry to one Co(1) and one Bi(2) atom. The La(1)-Co(1) bond length is 0.82 Å. The La(1)-Bi(2) bond length is 2.17 Å. Co(1) is bonded in a single-bond geometry to one La(1) and one Bi(2) atom. The Co(1)-Bi(2) bond length is 2.23 Å. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 1-coordinate geometry to one Bi(2) atom. The Bi(1)-Bi(2) bond length is 2.15 Å. In the second Bi site, Bi(2) is bonded in a 3-coordinate geometry to one La(1), one Co(1), and one Bi(1) atom.