data_ZrTlPt2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.44
_cell_length_b   9.44
_cell_length_c   9.44
_cell_angle_alpha   18.91
_cell_angle_beta   18.91
_cell_angle_gamma   18.91
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrTlPt2
_chemical_formula_sum   'Zr1 Tl1 Pt2'
_cell_volume   77.32
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr3  1  0.0  0.0  0.7  1.0
  Tl  Tl2  1  0.0  0.0  0.06  1.0
  Pt  Pt0  1  0.0  0.0  0.79  1.0
  Pt  Pt1  1  0.0  0.0  1.0  1.0

data_ZrTlPt2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.37
_cell_length_b   3.1
_cell_length_c   9.44
_cell_angle_alpha   90.0
_cell_angle_beta   100.94
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZrTlPt2
_chemical_formula_sum   'Zr2 Tl2 Pt4'
_cell_volume   154.63
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  2  -0.0  0.0  0.3  1.0
  Tl  Tl1  2  -0.0  0.0  0.94  1.0
  Pt  Pt2  2  -0.0  0.0  0.21  1.0
  Pt  Pt3  2  -0.0  0.0  0.0  1.0

Zr Tl Pt Pt
ZrPtPtTl is alpha oxygen-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two PtTl clusters and two ZrPt clusters. In each PtTl cluster, Pt(2) is bonded in a single-bond geometry to one Tl(1) atom. The Pt(2)-Tl(1) bond length is 0.58 Å. Tl(1) is bonded in a single-bond geometry to one Pt(2) atom. In each ZrPt cluster, Zr(1) is bonded in a single-bond geometry to one Pt(1) atom. The Zr(1)-Pt(1) bond length is 0.87 Å. Pt(1) is bonded in a single-bond geometry to one Zr(1) atom.