data_YV2Sb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.59
_cell_length_b   5.59
_cell_length_c   3.17
_cell_angle_alpha   104.91
_cell_angle_beta   104.91
_cell_angle_gamma   115.86
_symmetry_Int_Tables_number   1
_chemical_formula_structural   YV2Sb
_chemical_formula_sum   'Y1 V2 Sb1'
_cell_volume   78.12
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y3  1  0.0  0.0  0.0  1.0
  V  V1  1  0.72  0.63  0.39  1.0
  V  V2  1  0.72  0.37  0.39  1.0
  Sb  Sb0  1  0.97  0.0  0.0  1.0

data_YV2Sb
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.17
_cell_length_b   5.2
_cell_length_c   5.59
_cell_angle_alpha   116.69
_cell_angle_beta   104.91
_cell_angle_gamma   93.25
_symmetry_Int_Tables_number   1
_chemical_formula_structural   YV2Sb
_chemical_formula_sum   'Y1 V2 Sb1'
_cell_volume   78.12
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.0  0.0  0.0  1.0
  V  V1  1  0.02  0.63  0.35  1.0
  V  V2  1  0.76  0.37  0.09  1.0
  Sb  Sb3  1  0.0  0.0  0.97  1.0

Y V V Sb
V2YSb crystallizes in the triclinic P1 space group. Y(1) is bonded in a single-bond geometry to one V(1), one V(2), and one Sb(1) atom. The Y(1)-V(1) bond length is 2.01 Å. The Y(1)-V(2) bond length is 3.28 Å. The Y(1)-Sb(1) bond length is 0.17 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 4-coordinate geometry to one Y(1), one V(2), and two equivalent Sb(1) atoms. The V(1)-V(2) bond length is 1.46 Å. There is one shorter (2.00 Å) and one longer (2.73 Å) V(1)-Sb(1) bond length. In the second V site, V(2) is bonded in a 3-coordinate geometry to one Y(1), one V(1), and one Sb(1) atom. The V(2)-Sb(1) bond length is 3.15 Å. Sb(1) is bonded in a single-bond geometry to one Y(1), one V(2), and two equivalent V(1) atoms.