data_La2IrRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.17
_cell_length_b   6.17
_cell_length_c   6.17
_cell_angle_alpha   141.25
_cell_angle_beta   140.42
_cell_angle_gamma   56.59
_symmetry_Int_Tables_number   1
_chemical_formula_structural   La2IrRh
_chemical_formula_sum   'La2 Ir1 Rh1'
_cell_volume   93.02
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La1  1  0.0  0.0  0.84  1.0
  La  La2  1  0.05  0.0  0.72  1.0
  Ir  Ir0  1  0.0  0.09  0.66  1.0
  Rh  Rh3  1  0.0  0.0  0.52  1.0

data_La2IrRh
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.1
_cell_length_b   4.18
_cell_length_c   6.17
_cell_angle_alpha   109.79
_cell_angle_beta   109.37
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   La2IrRh
_chemical_formula_sum   'La2 Ir1 Rh1'
_cell_volume   93.02
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.16  0.16  0.16  1.0
  La  La1  1  0.33  0.28  0.33  1.0
  Ir  Ir2  1  0.34  0.43  0.43  1.0
  Rh  Rh3  1  0.48  0.48  0.48  1.0

La La Ir Rh
La2IrRh crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one La2IrRh cluster. There are two inequivalent La sites. In the first La site, La(1) is bonded in a single-bond geometry to one La(2) atom. The La(1)-La(2) bond length is 1.00 Å. In the second La site, La(2) is bonded in a single-bond geometry to one La(1) and one Ir(1) atom. The La(2)-Ir(1) bond length is 0.69 Å. Ir(1) is bonded in a distorted water-like geometry to one La(2) and one Rh(1) atom. The Ir(1)-Rh(1) bond length is 0.56 Å. Rh(1) is bonded in a distorted single-bond geometry to one Ir(1) atom.