data_BaPPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.12
_cell_length_b   6.12
_cell_length_c   6.12
_cell_angle_alpha   145.71
_cell_angle_beta   145.71
_cell_angle_gamma   49.28
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaPPd
_chemical_formula_sum   'Ba1 P1 Pd1'
_cell_volume   72.37
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.0  0.0  0.11  1.0
  P  P1  1  0.0  0.0  0.08  1.0
  Pd  Pd2  1  0.0  0.0  0.06  1.0

data_BaPPd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.1
_cell_length_b   5.1
_cell_length_c   6.12
_cell_angle_alpha   90.0
_cell_angle_beta   114.64
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   BaPPd
_chemical_formula_sum   'Ba2 P2 Pd2'
_cell_volume   144.74
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  2  0.0  0.0  0.89  1.0
  P  P1  2  0.0  0.0  0.92  1.0
  Pd  Pd2  2  0.0  0.0  0.94  1.0

Ba P Pd
BaPdP crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two BaPdP clusters. Ba(1) is bonded in a single-bond geometry to one P(1) atom. The Ba(1)-P(1) bond length is 0.15 Å. Pd(1) is bonded in a single-bond geometry to one P(1) atom. The Pd(1)-P(1) bond length is 0.17 Å. P(1) is bonded in a distorted single-bond geometry to one Ba(1) and one Pd(1) atom.