data_LiYTl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.57
_cell_length_b   3.57
_cell_length_c   7.28
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiYTl
_chemical_formula_sum   'Li1 Y1 Tl1'
_cell_volume   80.53
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.19  1.0
  Y  Y2  1  0.0  0.06  0.84  1.0
  Tl  Tl1  1  0.79  0.03  0.24  1.0

data_LiYTl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.57
_cell_length_b   3.57
_cell_length_c   7.28
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiYTl
_chemical_formula_sum   'Li1 Y1 Tl1'
_cell_volume   80.53
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.19  1.0
  Y  Y1  1  0.0  0.06  0.84  1.0
  Tl  Tl2  1  0.79  0.03  0.24  1.0

Li Y Tl
LiYTl is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LiYTl cluster. Li(1) is bonded in a single-bond geometry to one Y(1) and one Tl(1) atom. The Li(1)-Y(1) bond length is 2.59 Å. The Li(1)-Tl(1) bond length is 0.90 Å. Y(1) is bonded in a single-bond geometry to one Li(1) atom. Tl(1) is bonded in a single-bond geometry to one Li(1) atom.