data_CrBP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.09
_cell_length_b   2.89
_cell_length_c   5.01
_cell_angle_alpha   90.0
_cell_angle_beta   104.32
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CrBP2
_chemical_formula_sum   'Cr1 B1 P2'
_cell_volume   43.48
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr1  1  0.38  0.0  0.43  1.0
  B  B0  1  0.0  0.0  0.0  1.0
  P  P2  1  0.97  0.45  0.73  1.0
  P  P3  1  0.89  0.45  0.13  1.0

data_CrBP2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.89
_cell_length_b   3.09
_cell_length_c   5.01
_cell_angle_alpha   104.32
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CrBP2
_chemical_formula_sum   'Cr1 B1 P2'
_cell_volume   43.48
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.0  0.62  0.57  1.0
  B  B1  1  0.0  0.0  0.0  1.0
  P  P2  1  0.55  0.03  0.27  1.0
  P  P3  1  0.55  0.11  0.87  1.0

Cr B P P
CrBP2 crystallizes in the triclinic P1 space group. Cr(1) is bonded in a 9-coordinate geometry to one B(1), four equivalent P(1), and four equivalent P(2) atoms. The Cr(1)-B(1) bond length is 2.17 Å. There are a spread of Cr(1)-P(1) bond distances ranging from 2.42-2.72 Å. There are a spread of Cr(1)-P(2) bond distances ranging from 2.26-2.90 Å. B(1) is bonded in a 5-coordinate geometry to one Cr(1), two equivalent P(1), and two equivalent P(2) atoms. There is one shorter (1.87 Å) and one longer (2.10 Å) B(1)-P(1) bond length. There is one shorter (1.52 Å) and one longer (1.79 Å) B(1)-P(2) bond length. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 7-coordinate geometry to four equivalent Cr(1), two equivalent B(1), and one P(2) atom. The P(1)-P(2) bond length is 2.09 Å. In the second P site, P(2) is bonded in a 2-coordinate geometry to four equivalent Cr(1), two equivalent B(1), and one P(1) atom.