data_LaInSn2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.42
_cell_length_b   10.42
_cell_length_c   10.42
_cell_angle_alpha   20.08
_cell_angle_beta   20.08
_cell_angle_gamma   20.08
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaInSn2
_chemical_formula_sum   'La1 In1 Sn2'
_cell_volume   116.61
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La1  1  0.0  0.0  0.31  1.0
  In  In0  1  0.0  0.0  0.0  1.0
  Sn  Sn2  1  0.0  0.0  0.78  1.0
  Sn  Sn3  1  0.0  0.0  0.83  1.0

data_LaInSn2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.29
_cell_length_b   3.63
_cell_length_c   10.42
_cell_angle_alpha   90.0
_cell_angle_beta   101.61
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LaInSn2
_chemical_formula_sum   'La2 In2 Sn4'
_cell_volume   233.22
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  2  -0.0  0.0  0.69  1.0
  In  In1  2  0.0  0.0  0.0  1.0
  Sn  Sn2  2  0.0  0.0  0.17  1.0
  Sn  Sn3  2  0.0  0.0  0.22  1.0

La In Sn Sn
LaInSn2 is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two LaInSn2 clusters. La(1) is bonded in a single-bond geometry to one In(1) atom. The La(1)-In(1) bond length is 3.19 Å. In(1) is bonded in a distorted linear geometry to one La(1) and one Sn(2) atom. The In(1)-Sn(2) bond length is 1.78 Å. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a single-bond geometry to one Sn(2) atom. The Sn(1)-Sn(2) bond length is 0.48 Å. In the second Sn site, Sn(2) is bonded in a linear geometry to one In(1) and one Sn(1) atom.