data_V2MoPb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.95
_cell_length_b   2.95
_cell_length_c   8.65
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   113.14
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2MoPb
_chemical_formula_sum   'V2 Mo1 Pb1'
_cell_volume   69.19
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.62  0.0  0.72  1.0
  V  V3  1  0.62  0.0  0.94  1.0
  Mo  Mo0  1  0.0  0.0  0.0  1.0
  Pb  Pb1  1  0.0  0.0  0.33  1.0

data_V2MoPb
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.95
_cell_length_b   2.95
_cell_length_c   8.65
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   113.14
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2MoPb
_chemical_formula_sum   'V2 Mo1 Pb1'
_cell_volume   69.19
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.62  0.0  0.72  1.0
  V  V1  1  0.62  0.0  0.94  1.0
  Mo  Mo2  1  0.0  0.0  0.0  1.0
  Pb  Pb3  1  0.0  0.0  0.33  1.0

V V Mo Pb
V2MoPb crystallizes in the triclinic P1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 1-coordinate geometry to one V(2) and one Pb(1) atom. The V(1)-V(2) bond length is 1.92 Å. The V(1)-Pb(1) bond length is 3.54 Å. In the second V site, V(2) is bonded in a 2-coordinate geometry to one V(1) and two equivalent Mo(1) atoms. There is one shorter (1.23 Å) and one longer (1.92 Å) V(2)-Mo(1) bond length. Mo(1) is bonded in a 2-coordinate geometry to two equivalent V(2) and one Pb(1) atom. The Mo(1)-Pb(1) bond length is 2.82 Å. Pb(1) is bonded in a 8-coordinate geometry to one V(1), one Mo(1), and six equivalent Pb(1) atoms. There are four shorter (2.95 Å) and two longer (3.25 Å) Pb(1)-Pb(1) bond lengths.