data_V2Mo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.11
_cell_length_b   4.4
_cell_length_c   7.66
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2Mo
_chemical_formula_sum   'V8 Mo4'
_cell_volume   172.35
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V4  1  0.06  0.1  0.86  1.0
  V  V5  1  0.89  0.1  0.33  1.0
  V  V6  1  0.67  0.3  0.5  1.0
  V  V7  1  0.5  0.3  0.69  1.0
  V  V8  1  0.62  0.1  0.97  1.0
  V  V9  1  0.45  0.1  0.16  1.0
  V  V10  1  0.22  0.3  0.33  1.0
  V  V11  1  0.06  0.3  0.8  1.0
  Mo  Mo0  1  0.89  0.1  0.97  1.0
  Mo  Mo1  1  0.67  0.3  0.14  1.0
  Mo  Mo2  1  0.45  0.1  0.52  1.0
  Mo  Mo3  1  0.22  0.3  0.69  1.0

data_V2Mo
_symmetry_space_group_name_H-M   P-1
_cell_length_a   4.4
_cell_length_b   5.11
_cell_length_c   7.66
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   2
_chemical_formula_structural   V2Mo
_chemical_formula_sum   'V8 Mo4'
_cell_volume   172.35
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.4  0.06  0.14  1.0
  V  V1  2  0.4  0.33  0.5  1.0
  V  V2  2  0.4  0.5  0.03  1.0
  V  V3  2  0.4  0.89  0.33  1.0
  Mo  Mo4  2  0.4  0.33  0.14  1.0
  Mo  Mo5  2  0.4  0.89  0.69  1.0

V V V V V V V V Mo Mo Mo Mo
V2Mo is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one V2Mo cluster. There are four inequivalent V sites. In the first V site, V(1) is bonded in a distorted water-like geometry to one V(1) and one Mo(1) atom. The V(1)-V(1) bond length is 1.01 Å. The V(1)-Mo(1) bond length is 1.16 Å. In the second V site, V(2) is bonded in a 1-coordinate geometry to one Mo(2) atom. The V(2)-Mo(2) bond length is 2.10 Å. In the third V site, V(3) is bonded in a single-bond geometry to one Mo(2) atom. The V(3)-Mo(2) bond length is 1.43 Å. In the fourth V site, V(4) is bonded in a 2-coordinate geometry to one Mo(1) and one Mo(2) atom. The V(4)-Mo(1) bond length is 1.41 Å. The V(4)-Mo(2) bond length is 1.58 Å. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a distorted bent 150 degrees geometry to one V(1) and one V(4) atom. In the second Mo site, Mo(2) is bonded in a 3-coordinate geometry to one V(2), one V(3), and one V(4) atom.