data_PrSbPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.66
_cell_length_b   4.66
_cell_length_c   7.88
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   PrSbPd
_chemical_formula_sum   'Pr2 Sb2 Pd2'
_cell_volume   148.27
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.0  0.0  0.8  1.0
  Pr  Pr1  1  0.0  0.0  0.86  1.0
  Sb  Sb2  1  0.33  0.35  0.69  1.0
  Sb  Sb3  1  0.0  0.69  0.75  1.0
  Pd  Pd4  1  0.33  0.35  0.34  1.0
  Pd  Pd5  1  0.0  0.69  0.28  1.0

data_PrSbPd
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.66
_cell_length_b   4.66
_cell_length_c   7.88
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   PrSbPd
_chemical_formula_sum   'Pr2 Sb2 Pd2'
_cell_volume   148.27
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.0  0.0  0.8  1.0
  Pr  Pr1  1  0.0  0.0  0.86  1.0
  Sb  Sb2  1  0.0  0.69  0.75  1.0
  Sb  Sb3  1  0.33  0.35  0.69  1.0
  Pd  Pd4  1  0.0  0.69  0.28  1.0
  Pd  Pd5  1  0.33  0.35  0.34  1.0

Pr Pr Sb Sb Pd Pd
PrPdSb crystallizes in the triclinic P1 space group. There are two inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a trigonal non-coplanar geometry to one Pr(2), one Sb(1), and one Sb(2) atom. The Pr(1)-Pr(2) bond length is 0.49 Å. The Pr(1)-Sb(1) bond length is 1.79 Å. The Pr(1)-Sb(2) bond length is 1.48 Å. In the second Pr site, Pr(2) is bonded in a single-bond geometry to one Pr(1) and one Pd(2) atom. The Pr(2)-Pd(2) bond length is 3.60 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 4-coordinate geometry to three equivalent Pd(2) and one Sb(1) atom. There are a spread of Pd(1)-Pd(2) bond distances ranging from 2.69-2.78 Å. The Pd(1)-Sb(1) bond length is 2.75 Å. In the second Pd site, Pd(2) is bonded to one Pr(2) and three equivalent Pd(1) atoms to form distorted corner-sharing PdPrPd3 tetrahedra. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted single-bond geometry to one Pr(1) and one Pd(1) atom. In the second Sb site, Sb(2) is bonded in a single-bond geometry to one Pr(1) atom.