data_AlRe2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.2
_cell_length_b   8.2
_cell_length_c   8.2
_cell_angle_alpha   20.17
_cell_angle_beta   20.17
_cell_angle_gamma   20.17
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AlRe2P
_chemical_formula_sum   'Al1 Re2 P1'
_cell_volume   57.35
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.0  0.0  0.0  1.0
  Re  Re2  1  0.0  0.0  0.26  1.0
  Re  Re3  1  0.0  0.0  0.83  1.0
  P  P1  1  0.0  0.0  0.05  1.0

data_AlRe2P
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.97
_cell_length_b   2.87
_cell_length_c   8.2
_cell_angle_alpha   90.0
_cell_angle_beta   101.66
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   AlRe2P
_chemical_formula_sum   'Al2 Re4 P2'
_cell_volume   114.69
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  2  0.0  0.0  0.0  1.0
  Re  Re1  2  0.0  0.0  0.17  1.0
  Re  Re2  2  0.0  0.0  0.74  1.0
  P  P3  2  0.0  0.0  0.95  1.0

Al Re Re P
Re2AlP crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Re2AlP clusters. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a single-bond geometry to one P(1) atom. The Re(1)-P(1) bond length is 1.77 Å. In the second Re site, Re(2) is bonded in a single-bond geometry to one Al(1) atom. The Re(2)-Al(1) bond length is 1.38 Å. Al(1) is bonded in a distorted single-bond geometry to one Re(2) and one P(1) atom. The Al(1)-P(1) bond length is 0.39 Å. P(1) is bonded in a single-bond geometry to one Re(1) and one Al(1) atom.