data_ZrMnTc2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.02
_cell_length_b   5.02
_cell_length_c   4.63
_cell_angle_alpha   110.2
_cell_angle_beta   110.2
_cell_angle_gamma   34.79
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrMnTc2
_chemical_formula_sum   'Zr1 Mn1 Tc2'
_cell_volume   61.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr3  1  0.95  0.0  0.16  1.0
  Mn  Mn0  1  0.0  0.0  0.0  1.0
  Tc  Tc1  1  0.33  0.0  0.43  1.0
  Tc  Tc2  1  0.57  0.0  0.89  1.0

data_ZrMnTc2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.0
_cell_length_b   4.63
_cell_length_c   5.02
_cell_angle_alpha   110.2
_cell_angle_beta   107.4
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrMnTc2
_chemical_formula_sum   'Zr1 Mn1 Tc2'
_cell_volume   61.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.0  0.16  0.95  1.0
  Mn  Mn1  1  0.0  0.0  0.0  1.0
  Tc  Tc2  1  0.0  0.43  0.33  1.0
  Tc  Tc3  1  0.0  0.89  0.57  1.0

Zr Mn Tc Tc
ZrTc2Mn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ZrTc2Mn cluster. Zr(1) is bonded in a distorted single-bond geometry to one Tc(1), one Tc(2), and one Mn(1) atom. The Zr(1)-Tc(1) bond length is 1.89 Å. The Zr(1)-Tc(2) bond length is 1.89 Å. The Zr(1)-Mn(1) bond length is 0.85 Å. There are two inequivalent Tc sites. In the first Tc site, Tc(1) is bonded in a distorted single-bond geometry to one Zr(1) atom. In the second Tc site, Tc(2) is bonded in a 1-coordinate geometry to one Zr(1) atom. Mn(1) is bonded in a single-bond geometry to one Zr(1) atom.