data_TcMoPt2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.77
_cell_length_b   2.77
_cell_length_c   8.03
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TcMoPt2
_chemical_formula_sum   'Tc1 Mo1 Pt2'
_cell_volume   61.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc3  1  0.38  0.38  0.01  1.0
  Mo  Mo0  1  0.0  0.0  0.01  1.0
  Pt  Pt1  1  0.38  0.38  0.96  1.0
  Pt  Pt2  1  0.0  0.0  0.1  1.0

data_TcMoPt2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.91
_cell_length_b   3.91
_cell_length_c   8.03
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TcMoPt2
_chemical_formula_sum   'Tc2 Mo2 Pt4'
_cell_volume   123.08
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  2  0.38  0.0  0.01  1.0
  Mo  Mo1  2  0.0  0.0  0.01  1.0
  Pt  Pt2  2  0.0  0.0  0.1  1.0
  Pt  Pt3  2  0.38  0.0  0.96  1.0

Tc Mo Pt Pt
PtMoTcPt is beta oxygen-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two platinum;technetium molecules and two PtMo clusters. In each PtMo cluster, Mo(1) is bonded in a single-bond geometry to one Pt(2) atom. The Mo(1)-Pt(2) bond length is 0.69 Å. Pt(2) is bonded in a single-bond geometry to one Mo(1) atom.