data_V2PtRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.67
_cell_length_b   4.67
_cell_length_c   4.67
_cell_angle_alpha   131.55
_cell_angle_beta   131.55
_cell_angle_gamma   70.95
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2PtRh
_chemical_formula_sum   'V2 Pt1 Rh1'
_cell_volume   55.94
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.92  0.0  0.9  1.0
  V  V3  1  0.0  0.92  0.9  1.0
  Pt  Pt0  1  0.0  0.0  0.8  1.0
  Rh  Rh1  1  0.0  0.0  0.0  1.0

data_V2PtRh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.42
_cell_length_b   5.42
_cell_length_c   4.67
_cell_angle_alpha   90.0
_cell_angle_beta   125.47
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   V2PtRh
_chemical_formula_sum   'V4 Pt2 Rh2'
_cell_volume   111.88
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  4  0.06  0.04  0.01  1.0
  Rh  Rh1  2  0.0  0.0  0.0  1.0
  Pt  Pt2  2  0.2  0.0  0.2  1.0

V V Pt Rh
V2RhPt crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two V2RhPt clusters. V(1) is bonded in a 1-coordinate geometry to one Rh(1) and one Pt(1) atom. The V(1)-Rh(1) bond length is 0.35 Å. The V(1)-Pt(1) bond length is 0.77 Å. Rh(1) is bonded in an L-shaped geometry to two equivalent V(1) atoms. Pt(1) is bonded in a 2-coordinate geometry to two equivalent V(1) atoms.