data_TlOs2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.1
_cell_length_b   5.1
_cell_length_c   5.1
_cell_angle_alpha   134.9
_cell_angle_beta   134.9
_cell_angle_gamma   65.69
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlOs2W
_chemical_formula_sum   'Tl1 Os2 W1'
_cell_volume   65.73
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl2  1  0.0  0.96  0.14  1.0
  Os  Os0  1  0.96  0.0  0.14  1.0
  Os  Os1  1  0.0  0.0  0.29  1.0
  W  W3  1  0.0  0.0  0.0  1.0

data_TlOs2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.92
_cell_length_b   3.92
_cell_length_c   5.1
_cell_angle_alpha   112.55
_cell_angle_beta   112.55
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlOs2W
_chemical_formula_sum   'Tl1 Os2 W1'
_cell_volume   65.73
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.81  0.96  0.81  1.0
  Os  Os1  1  0.71  0.0  0.71  1.0
  Os  Os2  1  0.86  0.0  0.81  1.0
  W  W3  1  0.0  0.0  0.0  1.0

Tl Os Os W
WOs2Tl is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one WOs2Tl cluster. W(1) is bonded in a 2-coordinate geometry to one Os(1) and one Tl(1) atom. The W(1)-Os(1) bond length is 0.90 Å. The W(1)-Tl(1) bond length is 0.90 Å. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a single-bond geometry to one W(1) and one Tl(1) atom. The Os(1)-Tl(1) bond length is 0.24 Å. In the second Os site, Os(2) is bonded in a distorted single-bond geometry to one Tl(1) atom. The Os(2)-Tl(1) bond length is 0.60 Å. Tl(1) is bonded in a single-bond geometry to one W(1), one Os(1), and one Os(2) atom.