data_TcAgOs2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.75
_cell_length_b   2.75
_cell_length_c   8.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TcAgOs2
_chemical_formula_sum   'Tc1 Ag1 Os2'
_cell_volume   60.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc3  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.0  0.0  0.02  1.0
  Os  Os1  1  0.37  0.37  0.19  1.0
  Os  Os2  1  0.37  0.37  0.86  1.0

data_TcAgOs2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.89
_cell_length_b   3.89
_cell_length_c   8.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TcAgOs2
_chemical_formula_sum   'Tc2 Ag2 Os4'
_cell_volume   121.69
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  2  0.0  0.0  0.0  1.0
  Ag  Ag1  2  0.0  0.0  0.02  1.0
  Os  Os2  2  0.37  0.0  0.19  1.0
  Os  Os3  2  0.37  0.0  0.86  1.0

Tc Ag Os Os
TcOs2Ag crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two TcOs2Ag clusters. Tc(1) is bonded in a distorted single-bond geometry to one Os(2) and one Ag(1) atom. The Tc(1)-Os(2) bond length is 1.85 Å. The Tc(1)-Ag(1) bond length is 0.19 Å. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 1-coordinate geometry to one Ag(1) atom. The Os(1)-Ag(1) bond length is 1.98 Å. In the second Os site, Os(2) is bonded in a 1-coordinate geometry to one Tc(1) atom. Ag(1) is bonded in a single-bond geometry to one Tc(1) and one Os(1) atom.