data_GaP2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.82
_cell_length_b   5.82
_cell_length_c   7.35
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   145.66
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaP2Pd
_chemical_formula_sum   'Ga2 P4 Pd2'
_cell_volume   140.31
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.72  0.64  0.84  1.0
  Ga  Ga1  1  0.72  0.36  0.52  1.0
  P  P2  1  0.72  0.53  0.53  1.0
  P  P3  1  0.72  0.47  0.21  1.0
  P  P4  1  0.72  0.53  0.15  1.0
  P  P5  1  0.72  0.47  0.82  1.0
  Pd  Pd6  1  0.72  0.35  0.84  1.0
  Pd  Pd7  1  0.72  0.65  0.52  1.0

data_GaP2Pd
_symmetry_space_group_name_H-M   P-1
_cell_length_a   3.43
_cell_length_b   5.82
_cell_length_c   7.35
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   107.17
_symmetry_Int_Tables_number   2
_chemical_formula_structural   GaP2Pd
_chemical_formula_sum   'Ga2 P4 Pd2'
_cell_volume   140.31
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  2  0.36  0.86  0.66  1.0
  P  P1  2  0.47  0.97  0.97  1.0
  P  P2  2  0.47  0.97  0.35  1.0
  Pd  Pd3  2  0.35  0.85  0.34  1.0

Ga Ga P P P P Pd Pd
PdGaPP crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one diphosphorus molecule and two PdGaP clusters. In each PdGaP cluster, Pd(1) is bonded in a single-bond geometry to one P(1) atom. The Pd(1)-P(1) bond length is 0.66 Å. Ga(1) is bonded in a single-bond geometry to one P(1) atom. The Ga(1)-P(1) bond length is 1.03 Å. P(1) is bonded in a distorted linear geometry to one Pd(1) and one Ga(1) atom.