data_V2PdRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.7
_cell_length_b   4.7
_cell_length_c   4.7
_cell_angle_alpha   131.88
_cell_angle_beta   131.88
_cell_angle_gamma   70.42
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2PdRh
_chemical_formula_sum   'V2 Pd1 Rh1'
_cell_volume   56.4
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.92  0.92  1.0
  V  V3  1  0.0  0.0  0.0  1.0
  Pd  Pd0  1  0.92  0.0  0.92  1.0
  Rh  Rh1  1  0.0  0.0  0.84  1.0

data_V2PdRh
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.83
_cell_length_b   3.83
_cell_length_c   4.7
_cell_angle_alpha   114.06
_cell_angle_beta   114.06
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2PdRh
_chemical_formula_sum   'V2 Pd1 Rh1'
_cell_volume   56.4
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  V  V1  1  0.0  0.92  0.0  1.0
  Pd  Pd2  1  0.92  0.0  0.0  1.0
  Rh  Rh3  1  0.84  0.84  0.84  1.0

V V Pd Rh
V2RhPd crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one V2RhPd cluster. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 3-coordinate geometry to one V(2), one Rh(1), and one Pd(1) atom. The V(1)-V(2) bond length is 0.31 Å. The V(1)-Rh(1) bond length is 0.70 Å. The V(1)-Pd(1) bond length is 0.45 Å. In the second V site, V(2) is bonded in a distorted single-bond geometry to one V(1), one Rh(1), and one Pd(1) atom. The V(2)-Rh(1) bond length is 0.75 Å. The V(2)-Pd(1) bond length is 0.31 Å. Rh(1) is bonded in a 3-coordinate geometry to one V(1), one V(2), and one Pd(1) atom. The Rh(1)-Pd(1) bond length is 0.70 Å. Pd(1) is bonded in a single-bond geometry to one V(1), one V(2), and one Rh(1) atom.