data_Co(B5Pb)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.75
_cell_length_b   11.43
_cell_length_c   4.27
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Co(B5Pb)2
_chemical_formula_sum   'Co2 B20 Pb4'
_cell_volume   280.59
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co20  1  0.0  0.0  0.0  1.0
  Co  Co21  1  0.87  0.71  0.0  1.0
  B  B0  1  0.16  0.13  0.0  1.0
  B  B1  1  0.59  0.3  0.0  1.0
  B  B2  1  0.72  0.41  0.27  1.0
  B  B3  1  0.03  0.01  0.27  1.0
  B  B4  1  0.59  0.3  0.27  1.0
  B  B5  1  0.16  0.13  0.27  1.0
  B  B6  1  0.03  0.01  0.0  1.0
  B  B7  1  0.72  0.41  0.0  1.0
  B  B8  1  0.19  0.27  0.0  1.0
  B  B9  1  0.55  0.15  0.0  1.0
  B  B10  1  0.68  0.56  0.0  1.0
  B  B11  1  0.07  0.86  0.0  1.0
  B  B12  1  0.95  0.18  0.0  1.0
  B  B13  1  0.8  0.25  0.0  1.0
  B  B14  1  0.92  0.46  0.0  1.0
  B  B15  1  0.82  0.96  0.0  1.0
  B  B16  1  0.15  0.94  0.0  1.0
  B  B17  1  0.6  0.48  0.0  1.0
  B  B18  1  0.72  0.23  0.0  1.0
  B  B19  1  0.02  0.2  0.0  1.0
  Pb  Pb22  1  0.28  0.15  0.14  1.0
  Pb  Pb23  1  0.47  0.28  0.14  1.0
  Pb  Pb24  1  0.59  0.44  0.14  1.0
  Pb  Pb25  1  0.15  0.99  0.14  1.0

data_Co(B5Pb)2
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.27
_cell_length_b   5.75
_cell_length_c   11.43
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Co(B5Pb)2
_chemical_formula_sum   'Co2 B20 Pb4'
_cell_volume   280.59
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.0  0.0  1.0
  Co  Co1  1  0.0  0.87  0.71  1.0
  B  B2  1  0.0  0.02  0.2  1.0
  B  B3  1  0.0  0.55  0.15  1.0
  B  B4  1  0.0  0.07  0.86  1.0
  B  B5  1  0.0  0.6  0.48  1.0
  B  B6  1  0.0  0.15  0.94  1.0
  B  B7  1  0.0  0.68  0.56  1.0
  B  B8  1  0.0  0.19  0.27  1.0
  B  B9  1  0.0  0.72  0.23  1.0
  B  B10  1  0.0  0.8  0.25  1.0
  B  B11  1  0.0  0.82  0.96  1.0
  B  B12  1  0.0  0.92  0.46  1.0
  B  B13  1  0.0  0.95  0.18  1.0
  B  B14  1  0.0  0.03  0.01  1.0
  B  B15  1  0.0  0.16  0.13  1.0
  B  B16  1  0.0  0.59  0.3  1.0
  B  B17  1  0.0  0.72  0.41  1.0
  B  B18  1  0.27  0.03  0.01  1.0
  B  B19  1  0.27  0.16  0.13  1.0
  B  B20  1  0.27  0.59  0.3  1.0
  B  B21  1  0.27  0.72  0.41  1.0
  Pb  Pb22  1  0.14  0.15  0.99  1.0
  Pb  Pb23  1  0.14  0.28  0.15  1.0
  Pb  Pb24  1  0.14  0.47  0.28  1.0
  Pb  Pb25  1  0.14  0.59  0.44  1.0

Co Co B B B B B B B B B B B B B B B B B B B B Pb Pb Pb Pb
CoB5PbB5Pb is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one B5Pb cluster and one CoB5Pb cluster. In the B5Pb cluster, there are five inequivalent B sites. In the first B site, B(1,2) is bonded in a distorted single-bond geometry to one B(5,6) and one Pb(1,2) atom. The B(1,2)-B(5,6) bond length is 1.13 Å. The B(1,2)-Pb(1,2) bond length is 0.94 Å. In the second B site, B(5,6) is bonded in a 2-coordinate geometry to one B(1,2) and one Pb(1,2) atom. The B(5,6)-Pb(1,2) bond length is 0.94 Å. In the third B site, B(9,10) is bonded in a 3-coordinate geometry to one B(19,20) and two equivalent Pb(1,2) atoms. The B(9,10)-B(19,20) bond length is 1.34 Å. There is one shorter (1.63 Å) and one longer (1.67 Å) B(9,10)-Pb(1,2) bond length. In the fourth B site, B(13,14) is bonded in a single-bond geometry to one B(19,20) atom. The B(13,14)-B(19,20) bond length is 0.47 Å. In the fifth B site, B(19,20) is bonded in a distorted single-bond geometry to one B(13,14) and one B(9,10) atom. Pb(1,2) is bonded in a 2-coordinate geometry to one B(1,2); one B(5,6); and two equivalent B(9,10) atoms. In the CoB5Pb cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a single-bond geometry to one B(12), one B(16), and one B(7) atom. The Co(1)-B(12) bond length is 1.61 Å. The Co(1)-B(16) bond length is 1.12 Å. The Co(1)-B(7) bond length is 0.22 Å. In the second Co site, Co(2) is bonded in a linear geometry to one B(11) and one B(12) atom. The Co(2)-B(11) bond length is 2.04 Å. The Co(2)-B(12) bond length is 2.04 Å. There are ten inequivalent B sites. In the first B site, B(3) is bonded in a 1-coordinate geometry to one Pb(3) atom. The B(3)-Pb(3) bond length is 0.94 Å. In the second B site, B(4) is bonded in a distorted single-bond geometry to one Pb(4) atom. The B(4)-Pb(4) bond length is 0.94 Å. In the third B site, B(7) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one Pb(4) atom. The B(7)-Pb(4) bond length is 0.94 Å. In the fourth B site, B(8) is bonded in a single-bond geometry to one B(15) and one Pb(3) atom. The B(8)-B(15) bond length is 1.34 Å. The B(8)-Pb(3) bond length is 0.94 Å. In the fifth B site, B(11) is bonded in a distorted T-shaped geometry to one Co(2), one B(15), and one B(18) atom. The B(11)-B(15) bond length is 1.80 Å. The B(11)-B(18) bond length is 1.02 Å. In the sixth B site, B(12) is bonded in a 4-coordinate geometry to one Co(1), one Co(2), one B(16), and one B(17) atom. The B(12)-B(16) bond length is 1.80 Å. The B(12)-B(17) bond length is 1.02 Å. In the seventh B site, B(15) is bonded in a distorted single-bond geometry to one B(11) and one B(8) atom. In the eighth B site, B(16) is bonded in a single-bond geometry to one Co(1) and one B(12) atom. In the ninth B site, B(17) is bonded in a distorted single-bond geometry to one B(12) and one Pb(4) atom. The B(17)-Pb(4) bond length is 0.79 Å. In the tenth B site, B(18) is bonded in a distorted single-bond geometry to one B(11) and one Pb(3) atom. The B(18)-Pb(3) bond length is 0.79 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(3) is bonded in a 3-coordinate geometry to one B(18), one B(3), and one B(8) atom. In the second Pb site, Pb(4) is bonded in a 3-coordinate geometry to one B(17), one B(4), and one B(7) atom.