data_NbGaTe2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.49
_cell_length_b   3.49
_cell_length_c   7.9
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NbGaTe2
_chemical_formula_sum   'Nb1 Ga1 Te2'
_cell_volume   96.15
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb1  1  0.74  0.74  0.62  1.0
  Ga  Ga0  1  0.0  0.0  0.25  1.0
  Te  Te2  1  0.0  0.0  0.24  1.0
  Te  Te3  1  0.74  0.74  0.64  1.0

data_NbGaTe2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.93
_cell_length_b   4.93
_cell_length_c   7.9
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   NbGaTe2
_chemical_formula_sum   'Nb2 Ga2 Te4'
_cell_volume   192.29
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  2  0.24  0.5  0.62  1.0
  Ga  Ga1  2  0.0  0.0  0.25  1.0
  Te  Te2  2  0.0  0.0  0.24  1.0
  Te  Te3  2  0.24  0.5  0.64  1.0

Nb Ga Te Te
NbTeGaTe is beta oxygen-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two gallium(ii)telluride molecules and two NbTe clusters. In each NbTe cluster, Nb(1) is bonded in a single-bond geometry to one Te(2) atom. The Nb(1)-Te(2) bond length is 0.17 Å. Te(2) is bonded in a single-bond geometry to one Nb(1) atom.