data_Na2LiTi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.96
_cell_length_b   5.43
_cell_length_c   6.32
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na2LiTi
_chemical_formula_sum   'Na2 Li1 Ti1'
_cell_volume   101.45
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na1  1  0.48  0.71  0.58  1.0
  Na  Na2  1  0.48  0.71  0.74  1.0
  Li  Li0  1  0.0  0.0  0.0  1.0
  Ti  Ti3  1  0.0  0.0  0.16  1.0

data_Na2LiTi
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.96
_cell_length_b   5.43
_cell_length_c   6.32
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na2LiTi
_chemical_formula_sum   'Na2 Li1 Ti1'
_cell_volume   101.45
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.48  0.71  0.58  1.0
  Na  Na1  1  0.48  0.71  0.74  1.0
  Li  Li2  1  0.0  0.0  0.0  1.0
  Ti  Ti3  1  0.0  0.0  0.16  1.0

Na Na Li Ti
(Na)2LiTi crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one disodium molecule and one LiTi cluster. In the LiTi cluster, Li(1) is bonded in a single-bond geometry to one Ti(1) atom. The Li(1)-Ti(1) bond length is 1.01 Å. Ti(1) is bonded in a single-bond geometry to one Li(1) atom.