data_Sc2InGe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.64
_cell_length_b   8.64
_cell_length_c   8.64
_cell_angle_alpha   23.58
_cell_angle_beta   23.58
_cell_angle_gamma   23.58
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sc2InGe
_chemical_formula_sum   'Sc2 In1 Ge1'
_cell_volume   90.79
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc2  1  0.0  0.0  0.57  1.0
  Sc  Sc3  1  0.0  0.0  0.64  1.0
  In  In1  1  0.0  0.0  0.6  1.0
  Ge  Ge0  1  0.0  0.0  0.0  1.0

data_Sc2InGe
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.12
_cell_length_b   3.53
_cell_length_c   8.64
_cell_angle_alpha   90.0
_cell_angle_beta   103.65
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Sc2InGe
_chemical_formula_sum   'Sc4 In2 Ge2'
_cell_volume   181.58
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  2  0.0  0.0  0.36  1.0
  Sc  Sc1  2  0.0  0.0  0.43  1.0
  In  In2  2  0.0  0.0  0.4  1.0
  Ge  Ge3  2  0.0  0.0  0.0  1.0

Sc Sc In Ge
Sc2InGe is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Sc2InGe clusters. There are two inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in a single-bond geometry to one In(1) atom. The Sc(1)-In(1) bond length is 0.30 Å. In the second Sc site, Sc(2) is bonded in a single-bond geometry to one In(1) and one Ge(1) atom. The Sc(2)-In(1) bond length is 0.30 Å. The Sc(2)-Ge(1) bond length is 3.15 Å. In(1) is bonded in a linear geometry to one Sc(1) and one Sc(2) atom. Ge(1) is bonded in a single-bond geometry to one Sc(2) atom.