data_Zr2GaW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.46
_cell_length_b   3.46
_cell_length_c   6.31
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zr2GaW
_chemical_formula_sum   'Zr2 Ga1 W1'
_cell_volume   75.61
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr2  1  0.0  0.0  0.18  1.0
  Zr  Zr3  1  0.73  0.73  0.73  1.0
  Ga  Ga0  1  0.0  0.0  0.29  1.0
  W  W1  1  0.73  0.73  0.58  1.0

data_Zr2GaW
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.9
_cell_length_b   4.9
_cell_length_c   6.31
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Zr2GaW
_chemical_formula_sum   'Zr4 Ga2 W2'
_cell_volume   151.22
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  2  0.0  0.0  0.18  1.0
  Zr  Zr1  2  0.23  0.5  0.73  1.0
  Ga  Ga2  2  0.0  0.0  0.29  1.0
  W  W3  2  0.23  0.5  0.58  1.0

Zr Zr Ga W
WZrZrGa crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two WZr clusters and two ZrGa clusters. In each WZr cluster, Zr(2) is bonded in a single-bond geometry to one W(1) atom. The Zr(2)-W(1) bond length is 1.00 Å. W(1) is bonded in a distorted single-bond geometry to one Zr(2) atom. In each ZrGa cluster, Zr(1) is bonded in a single-bond geometry to one Ga(1) atom. The Zr(1)-Ga(1) bond length is 0.69 Å. Ga(1) is bonded in a distorted single-bond geometry to one Zr(1) atom.