data_Sc2PdCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.41
_cell_length_b   3.23
_cell_length_c   7.45
_cell_angle_alpha   90.0
_cell_angle_beta   92.24
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sc2PdCl
_chemical_formula_sum   'Sc2 Pd1 Cl1'
_cell_volume   81.95
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc2  1  0.85  0.61  0.32  1.0
  Sc  Sc3  1  0.27  0.61  0.12  1.0
  Pd  Pd1  1  0.56  0.0  0.72  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Sc2PdCl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.23
_cell_length_b   3.41
_cell_length_c   7.45
_cell_angle_alpha   92.24
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sc2PdCl
_chemical_formula_sum   'Sc2 Pd1 Cl1'
_cell_volume   81.95
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.39  0.15  0.68  1.0
  Sc  Sc1  1  0.39  0.73  0.88  1.0
  Pd  Pd2  1  0.0  0.44  0.28  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Sc Sc Pd Cl
Sc2PdCl crystallizes in the triclinic P1 space group. There are two inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in a 4-coordinate geometry to two equivalent Sc(2), one Pd(1), and one Cl(1) atom. There is one shorter (2.07 Å) and one longer (2.37 Å) Sc(1)-Sc(2) bond length. The Sc(1)-Pd(1) bond length is 3.44 Å. The Sc(1)-Cl(1) bond length is 2.73 Å. In the second Sc site, Sc(2) is bonded in a 2-coordinate geometry to two equivalent Sc(1) and two equivalent Cl(1) atoms. There is one shorter (1.80 Å) and one longer (2.37 Å) Sc(2)-Cl(1) bond length. Pd(1) is bonded in a 2-coordinate geometry to one Sc(1) and two equivalent Cl(1) atoms. There is one shorter (2.52 Å) and one longer (2.88 Å) Pd(1)-Cl(1) bond length. Cl(1) is bonded in a 1-coordinate geometry to one Sc(1), two equivalent Sc(2), and two equivalent Pd(1) atoms.