data_SrV2Co
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.28
_cell_length_b   3.28
_cell_length_c   7.18
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SrV2Co
_chemical_formula_sum   'Sr1 V2 Co1'
_cell_volume   77.48
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr1  1  0.0  0.0  0.59  1.0
  V  V2  1  0.64  0.64  0.19  1.0
  V  V3  1  0.64  0.64  0.99  1.0
  Co  Co0  1  0.0  0.0  0.0  1.0

data_SrV2Co
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.64
_cell_length_b   4.64
_cell_length_c   7.18
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   SrV2Co
_chemical_formula_sum   'Sr2 V4 Co2'
_cell_volume   154.97
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  2  0.0  0.0  0.59  1.0
  V  V1  2  0.14  0.5  0.19  1.0
  V  V2  2  0.14  0.5  0.99  1.0
  Co  Co3  2  0.0  0.0  0.0  1.0

Sr V V Co
SrV2Co crystallizes in the monoclinic Cm space group. Sr(1) is bonded in a 2-coordinate geometry to one V(1) and one Co(1) atom. The Sr(1)-V(1) bond length is 3.32 Å. The Sr(1)-Co(1) bond length is 2.93 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted single-bond geometry to one Sr(1) and one V(2) atom. The V(1)-V(2) bond length is 1.44 Å. In the second V site, V(2) is bonded in a 4-coordinate geometry to one V(1) and three equivalent Co(1) atoms. There is one shorter (1.66 Å) and two longer (2.42 Å) V(2)-Co(1) bond lengths. Co(1) is bonded in a 1-coordinate geometry to one Sr(1) and three equivalent V(2) atoms.