data_Na4PtO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.83
_cell_length_b   5.83
_cell_length_c   9.97
_cell_angle_alpha   91.7
_cell_angle_beta   91.7
_cell_angle_gamma   45.83
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na4PtO4
_chemical_formula_sum   'Na8 Pt2 O8'
_cell_volume   243.01
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.44  0.0  0.53  1.0
  Na  Na1  1  0.99  0.0  0.44  1.0
  Na  Na2  1  0.88  0.0  0.72  1.0
  Na  Na3  1  0.72  0.0  0.77  1.0
  Na  Na4  1  0.43  0.0  0.51  1.0
  Na  Na5  1  0.99  0.0  0.45  1.0
  Na  Na6  1  0.7  0.0  0.2  1.0
  Na  Na7  1  0.54  0.0  0.24  1.0
  Pt  Pt8  1  0.74  0.0  0.44  1.0
  Pt  Pt9  1  0.68  0.0  0.53  1.0
  O  O10  1  0.79  0.0  0.63  1.0
  O  O11  1  0.03  0.0  0.41  1.0
  O  O12  1  0.95  0.0  0.44  1.0
  O  O13  1  0.93  0.0  0.34  1.0
  O  O14  1  0.49  0.0  0.63  1.0
  O  O15  1  0.47  0.0  0.53  1.0
  O  O16  1  0.39  0.0  0.56  1.0
  O  O17  1  0.64  0.0  0.33  1.0

data_Na4PtO4
_symmetry_space_group_name_H-M   P-1
_cell_length_a   4.54
_cell_length_b   5.83
_cell_length_c   9.97
_cell_angle_alpha   91.7
_cell_angle_beta   90.0
_cell_angle_gamma   112.91
_symmetry_Int_Tables_number   2
_chemical_formula_structural   Na4PtO4
_chemical_formula_sum   'Na8 Pt2 O8'
_cell_volume   243.01
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  2  0.0  0.01  0.78  1.0
  Na  Na1  2  0.0  0.17  0.74  1.0
  Na  Na2  2  0.0  0.27  0.46  1.0
  Na  Na3  2  0.0  0.28  0.47  1.0
  Pt  Pt4  2  0.0  0.03  0.46  1.0
  O  O5  2  0.0  0.08  0.65  1.0
  O  O6  2  0.0  0.22  0.36  1.0
  O  O7  2  0.0  0.24  0.46  1.0
  O  O8  2  0.0  0.32  0.42  1.0

Na Na Na Na Na Na Na Na Pt Pt O O O O O O O O
Na4PtO4 is Cubic alpha N2-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Na4PtO4 clusters. There are four inequivalent Na sites. In the first Na site, Na(1) is bonded in a 3-coordinate geometry to one Na(4), one O(2), and one O(3) atom. The Na(1)-Na(4) bond length is 0.15 Å. The Na(1)-O(2) bond length is 0.44 Å. The Na(1)-O(3) bond length is 0.22 Å. In the second Na site, Na(2) is bonded in a single-bond geometry to one Na(3) and one O(1) atom. The Na(2)-Na(3) bond length is 1.05 Å. The Na(2)-O(1) bond length is 1.07 Å. In the third Na site, Na(3) is bonded in a 3-coordinate geometry to one Na(2), one O(1), and one O(4) atom. The Na(3)-O(1) bond length is 1.41 Å. The Na(3)-O(4) bond length is 1.90 Å. In the fourth Na site, Na(4) is bonded in a distorted single-bond geometry to one Na(1) atom. Pt(1) is bonded in a distorted bent 120 degrees geometry to one O(1), one O(3), and one O(4) atom. The Pt(1)-O(1) bond length is 1.21 Å. The Pt(1)-O(3) bond length is 1.19 Å. The Pt(1)-O(4) bond length is 1.50 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(2), one Na(3), one Pt(1), and one O(4) atom. The O(1)-O(4) bond length is 1.71 Å. In the second O site, O(2) is bonded in a single-bond geometry to one Na(1) and one O(4) atom. The O(2)-O(4) bond length is 0.90 Å. In the third O site, O(3) is bonded in a single-bond geometry to one Na(1), one Pt(1), and one O(4) atom. The O(3)-O(4) bond length is 1.01 Å. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Na(3), one Pt(1), one O(1), one O(2), and one O(3) atom.