data_Na2TiOs
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.02
_cell_length_b   6.02
_cell_length_c   2.62
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   128.97
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na2TiOs
_chemical_formula_sum   'Na2 Ti1 Os1'
_cell_volume   73.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.3  0.72  0.31  1.0
  Na  Na1  1  0.3  0.28  0.31  1.0
  Ti  Ti3  1  0.0  0.0  0.0  1.0
  Os  Os2  1  0.59  0.0  0.0  1.0

data_Na2TiOs
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.62
_cell_length_b   5.19
_cell_length_c   6.02
_cell_angle_alpha   115.51
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na2TiOs
_chemical_formula_sum   'Na2 Ti1 Os1'
_cell_volume   73.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.31  0.28  0.58  1.0
  Na  Na1  1  0.31  0.72  0.02  1.0
  Ti  Ti2  1  0.0  0.0  0.0  1.0
  Os  Os3  1  0.0  0.0  0.59  1.0

Na Na Ti Os
NaTiNaOs crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one NaOs cluster and one NaTi cluster. In the NaOs cluster, Na(1) is bonded in a distorted single-bond geometry to one Os(1) atom. The Na(1)-Os(1) bond length is 1.71 Å. Os(1) is bonded in a distorted single-bond geometry to one Na(1) atom. In the NaTi cluster, Na(2) is bonded in a distorted single-bond geometry to one Ti(1) atom. The Na(2)-Ti(1) bond length is 1.71 Å. Ti(1) is bonded in a 1-coordinate geometry to one Na(2) atom.