data_V7Pd6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.31
_cell_length_b   9.31
_cell_length_c   9.31
_cell_angle_alpha   30.46
_cell_angle_beta   30.46
_cell_angle_gamma   30.46
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V7Pd6
_chemical_formula_sum   'V7 Pd6'
_cell_volume   183.85
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V6  1  0.78  0.29  0.8  1.0
  V  V7  1  0.0  0.41  0.8  1.0
  V  V8  1  0.22  0.29  0.8  1.0
  V  V9  1  0.22  0.71  0.81  1.0
  V  V10  1  0.78  0.71  0.81  1.0
  V  V11  1  0.0  0.59  0.81  1.0
  V  V12  1  0.0  0.0  0.0  1.0
  Pd  Pd0  1  0.0  0.0  0.05  1.0
  Pd  Pd1  1  0.0  0.0  0.57  1.0
  Pd  Pd2  1  0.0  0.0  0.26  1.0
  Pd  Pd3  1  0.0  0.0  0.36  1.0
  Pd  Pd4  1  0.0  0.0  0.46  1.0
  Pd  Pd5  1  0.0  0.0  0.16  1.0

data_V7Pd6
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.89
_cell_length_b   4.89
_cell_length_c   9.31
_cell_angle_alpha   74.77
_cell_angle_beta   74.77
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V7Pd6
_chemical_formula_sum   'V7 Pd6'
_cell_volume   183.85
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  V  V1  1  0.29  0.19  0.3  1.0
  V  V2  1  0.29  0.19  0.75  1.0
  V  V3  1  0.41  0.19  0.4  1.0
  V  V4  1  0.59  0.2  0.22  1.0
  V  V5  1  0.71  0.2  0.32  1.0
  V  V6  1  0.71  0.2  0.87  1.0
  Pd  Pd7  1  0.0  0.43  0.57  1.0
  Pd  Pd8  1  0.0  0.54  0.46  1.0
  Pd  Pd9  1  0.0  0.64  0.36  1.0
  Pd  Pd10  1  0.0  0.74  0.26  1.0
  Pd  Pd11  1  0.0  0.84  0.16  1.0
  Pd  Pd12  1  0.0  0.95  0.05  1.0

V V V V V V V Pd Pd Pd Pd Pd Pd
V7Pd6 crystallizes in the triclinic P1 space group. There are seven inequivalent V sites. In the first V site, V(1) is bonded in a 3-coordinate geometry to one V(4), one V(7), and one Pd(2) atom. The V(1)-V(4) bond length is 2.62 Å. The V(1)-V(7) bond length is 1.82 Å. The V(1)-Pd(2) bond length is 3.03 Å. In the second V site, V(2) is bonded in a 4-coordinate geometry to one V(3), one V(5), one Pd(1), and one Pd(6) atom. The V(2)-V(3) bond length is 1.26 Å. The V(2)-V(5) bond length is 1.45 Å. The V(2)-Pd(1) bond length is 2.21 Å. The V(2)-Pd(6) bond length is 1.95 Å. In the third V site, V(3) is bonded in a 3-coordinate geometry to one V(2), one V(6), and one Pd(3) atom. The V(3)-V(6) bond length is 1.45 Å. The V(3)-Pd(3) bond length is 2.10 Å. In the fourth V site, V(4) is bonded in a distorted single-bond geometry to one V(1) and one Pd(2) atom. The V(4)-Pd(2) bond length is 2.17 Å. In the fifth V site, V(5) is bonded in a 3-coordinate geometry to one V(2), one V(6), and one Pd(4) atom. The V(5)-V(6) bond length is 1.26 Å. The V(5)-Pd(4) bond length is 2.10 Å. In the sixth V site, V(6) is bonded in a 4-coordinate geometry to one V(3), one V(5), one Pd(2), and one Pd(5) atom. The V(6)-Pd(2) bond length is 2.21 Å. The V(6)-Pd(5) bond length is 1.95 Å. In the seventh V site, V(7) is bonded in a single-bond geometry to one V(1) and one Pd(1) atom. The V(7)-Pd(1) bond length is 0.47 Å. There are six inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a single-bond geometry to one V(2), one V(7), and one Pd(6) atom. The Pd(1)-Pd(6) bond length is 1.05 Å. In the second Pd site, Pd(2) is bonded in a 4-coordinate geometry to one V(1), one V(4), one V(6), and one Pd(5) atom. The Pd(2)-Pd(5) bond length is 1.05 Å. In the third Pd site, Pd(3) is bonded in a 2-coordinate geometry to one V(3), one Pd(4), and one Pd(6) atom. The Pd(3)-Pd(4) bond length is 1.00 Å. The Pd(3)-Pd(6) bond length is 0.86 Å. In the fourth Pd site, Pd(4) is bonded in a 2-coordinate geometry to one V(5), one Pd(3), and one Pd(5) atom. The Pd(4)-Pd(5) bond length is 0.86 Å. In the fifth Pd site, Pd(5) is bonded in a distorted T-shaped geometry to one V(6), one Pd(2), and one Pd(4) atom. In the sixth Pd site, Pd(6) is bonded in a distorted T-shaped geometry to one V(2), one Pd(1), and one Pd(3) atom.