data_ZnP2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.35
_cell_length_b   4.35
_cell_length_c   3.36
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   107.67
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnP2Pd
_chemical_formula_sum   'Zn1 P2 Pd1'
_cell_volume   60.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.0  0.0  1.0
  P  P0  1  0.28  0.75  0.68  1.0
  P  P1  1  0.28  0.25  0.68  1.0
  Pd  Pd2  1  0.56  0.0  0.0  1.0

data_ZnP2Pd
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.36
_cell_length_b   4.35
_cell_length_c   4.35
_cell_angle_alpha   107.67
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnP2Pd
_chemical_formula_sum   'Zn1 P2 Pd1'
_cell_volume   60.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.0  0.0  0.0  1.0
  P  P1  1  0.68  0.28  0.25  1.0
  P  P2  1  0.68  0.28  0.75  1.0
  Pd  Pd3  1  0.0  0.56  0.0  1.0

Zn P P Pd
PdZnP2 crystallizes in the triclinic P1 space group. Pd(1) is bonded in a 2-coordinate geometry to one Zn(1) and two equivalent P(1) atoms. The Pd(1)-Zn(1) bond length is 1.89 Å. There is one shorter (1.73 Å) and one longer (2.66 Å) Pd(1)-P(1) bond length. Zn(1) is bonded in a 2-coordinate geometry to one Pd(1), one P(2), and two equivalent P(1) atoms. The Zn(1)-P(2) bond length is 1.73 Å. There is one shorter (2.14 Å) and one longer (2.94 Å) Zn(1)-P(1) bond length. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to two equivalent Pd(1), two equivalent Zn(1), and two equivalent P(2) atoms. There is one shorter (2.13 Å) and one longer (2.21 Å) P(1)-P(2) bond length. In the second P site, P(2) is bonded in a distorted single-bond geometry to one Zn(1) and two equivalent P(1) atoms.