data_LaVCr2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.97
_cell_length_b   3.77
_cell_length_c   6.56
_cell_angle_alpha   90.0
_cell_angle_beta   101.27
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaVCr2
_chemical_formula_sum   'La1 V1 Cr2'
_cell_volume   72.08
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La2  1  0.84  0.0  0.22  1.0
  V  V3  1  0.0  0.0  0.0  1.0
  Cr  Cr0  1  0.82  0.89  0.98  1.0
  Cr  Cr1  1  0.86  0.89  0.46  1.0

data_LaVCr2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.97
_cell_length_b   3.77
_cell_length_c   6.56
_cell_angle_alpha   90.0
_cell_angle_beta   101.27
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaVCr2
_chemical_formula_sum   'La1 V1 Cr2'
_cell_volume   72.08
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.84  0.0  0.22  1.0
  V  V1  1  0.0  0.0  0.0  1.0
  Cr  Cr2  1  0.82  0.89  0.98  1.0
  Cr  Cr3  1  0.86  0.89  0.46  1.0

La V Cr Cr
LaVCr2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LaVCr2 cluster. La(1) is bonded in a 3-coordinate geometry to one V(1), one Cr(1), and one Cr(2) atom. The La(1)-V(1) bond length is 1.59 Å. The La(1)-Cr(1) bond length is 1.62 Å. The La(1)-Cr(2) bond length is 1.62 Å. V(1) is bonded in a 2-coordinate geometry to one La(1) and one Cr(1) atom. The V(1)-Cr(1) bond length is 0.67 Å. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a 2-coordinate geometry to one La(1) and one V(1) atom. In the second Cr site, Cr(2) is bonded in a single-bond geometry to one La(1) atom.