data_MnCo2Tc
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.78
_cell_length_b   4.78
_cell_length_c   4.78
_cell_angle_alpha   144.36
_cell_angle_beta   129.16
_cell_angle_gamma   63.63
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnCo2Tc
_chemical_formula_sum   'Mn1 Co2 Tc1'
_cell_volume   48.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn2  1  0.0  0.0  0.02  1.0
  Co  Co0  1  0.0  0.0  0.03  1.0
  Co  Co1  1  0.46  0.0  0.07  1.0
  Tc  Tc3  1  0.0  0.05  0.99  1.0

data_MnCo2Tc
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.92
_cell_length_b   4.1
_cell_length_c   4.78
_cell_angle_alpha   115.42
_cell_angle_beta   107.82
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnCo2Tc
_chemical_formula_sum   'Mn1 Co2 Tc1'
_cell_volume   48.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.0  0.02  0.02  1.0
  Co  Co1  1  0.0  0.03  0.03  1.0
  Co  Co2  1  0.0  0.07  0.61  1.0
  Tc  Tc3  1  0.95  0.94  0.94  1.0

Mn Co Co Tc
TcMnCo2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one TcMnCo2 cluster. Tc(1) is bonded in a single-bond geometry to one Mn(1) and one Co(2) atom. The Tc(1)-Mn(1) bond length is 0.37 Å. The Tc(1)-Co(2) bond length is 1.91 Å. Mn(1) is bonded in a bent 150 degrees geometry to one Tc(1) and one Co(1) atom. The Mn(1)-Co(1) bond length is 0.06 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a single-bond geometry to one Mn(1) atom. In the second Co site, Co(2) is bonded in a 1-coordinate geometry to one Tc(1) atom.