data_AgSb2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.64
_cell_length_b   5.45
_cell_length_c   5.45
_cell_angle_alpha   37.11
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgSb2W
_chemical_formula_sum   'Ag1 Sb2 W1'
_cell_volume   83.18
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.0  0.0  0.98  1.0
  Sb  Sb1  1  0.0  0.0  0.22  1.0
  Sb  Sb2  1  0.32  0.0  0.62  1.0
  W  W3  1  0.32  0.0  0.69  1.0

data_AgSb2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.47
_cell_length_b   4.64
_cell_length_c   5.45
_cell_angle_alpha   90.0
_cell_angle_beta   108.56
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgSb2W
_chemical_formula_sum   'Ag1 Sb2 W1'
_cell_volume   83.18
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.02  0.0  0.02  1.0
  Sb  Sb1  1  0.38  0.32  0.38  1.0
  Sb  Sb2  1  0.78  0.0  0.78  1.0
  W  W3  1  0.31  0.32  0.31  1.0

Ag Sb Sb W
WAgSb2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one WAgSb2 cluster. W(1) is bonded in a distorted single-bond geometry to one Ag(1) and one Sb(2) atom. The W(1)-Ag(1) bond length is 2.17 Å. The W(1)-Sb(2) bond length is 0.34 Å. Ag(1) is bonded in a 2-coordinate geometry to one W(1) and one Sb(1) atom. The Ag(1)-Sb(1) bond length is 1.35 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a single-bond geometry to one Ag(1) atom. In the second Sb site, Sb(2) is bonded in a single-bond geometry to one W(1) atom.