data_V2ZnRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.04
_cell_length_b   5.04
_cell_length_c   5.04
_cell_angle_alpha   146.44
_cell_angle_beta   128.07
_cell_angle_gamma   63.26
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2ZnRh
_chemical_formula_sum   'V2 Zn1 Rh1'
_cell_volume   55.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V1  1  0.0  0.0  0.54  1.0
  V  V2  1  0.0  0.21  0.28  1.0
  Zn  Zn3  1  0.0  0.0  0.3  1.0
  Rh  Rh0  1  0.46  0.0  0.06  1.0

data_V2ZnRh
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.91
_cell_length_b   4.42
_cell_length_c   5.04
_cell_angle_alpha   115.97
_cell_angle_beta   106.78
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2ZnRh
_chemical_formula_sum   'V2 Zn1 Rh1'
_cell_volume   55.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.54  0.54  1.0
  V  V1  1  0.79  0.07  0.07  1.0
  Zn  Zn2  1  0.0  0.3  0.3  1.0
  Rh  Rh3  1  0.0  0.06  0.6  1.0

V V Zn Rh
V2RhZn crystallizes in the triclinic P1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 3-coordinate geometry to two equivalent Rh(1) and one Zn(1) atom. There is one shorter (2.18 Å) and one longer (2.28 Å) V(1)-Rh(1) bond length. The V(1)-Zn(1) bond length is 1.21 Å. In the second V site, V(2) is bonded in a 1-coordinate geometry to two equivalent Rh(1) and one Zn(1) atom. There is one shorter (2.57 Å) and one longer (2.76 Å) V(2)-Rh(1) bond length. The V(2)-Zn(1) bond length is 1.16 Å. Rh(1) is bonded in a 5-coordinate geometry to two equivalent V(1), two equivalent V(2), and one Zn(1) atom. The Rh(1)-Zn(1) bond length is 2.21 Å. Zn(1) is bonded in a 3-coordinate geometry to one V(1), one V(2), and one Rh(1) atom.