data_AgMo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.18
_cell_length_b   5.18
_cell_length_c   5.18
_cell_angle_alpha   104.06
_cell_angle_beta   104.06
_cell_angle_gamma   120.93
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgMo2
_chemical_formula_sum   'Ag2 Mo4'
_cell_volume   103.71
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.0  0.0  0.83  1.0
  Ag  Ag1  1  0.0  0.0  0.28  1.0
  Mo  Mo2  1  0.36  0.82  0.55  1.0
  Mo  Mo3  1  0.18  0.36  0.55  1.0
  Mo  Mo4  1  0.01  0.82  0.0  1.0
  Mo  Mo5  1  0.82  0.36  0.0  1.0

data_AgMo2
_symmetry_space_group_name_H-M   P1
_cell_length_a   5.11
_cell_length_b   5.18
_cell_length_c   5.18
_cell_angle_alpha   75.94
_cell_angle_beta   60.47
_cell_angle_gamma   60.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgMo2
_chemical_formula_sum   'Ag2 Mo4'
_cell_volume   103.71
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.17  0.83  0.0  1.0
  Ag  Ag1  1  0.72  0.28  0.0  1.0
  Mo  Mo2  1  0.27  0.55  0.54  1.0
  Mo  Mo3  1  0.36  -0.0  0.46  1.0
  Mo  Mo4  1  0.81  0.55  0.81  1.0
  Mo  Mo5  1  0.82  0.0  0.19  1.0

Ag Ag Mo Mo Mo Mo
Mo2Ag crystallizes in the triclinic P1 space group. There are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one Mo(2), two equivalent Mo(4), one Ag(2), and two equivalent Ag(1) atoms. The Mo(1)-Mo(2) bond length is 2.07 Å. There is one shorter (2.48 Å) and one longer (2.76 Å) Mo(1)-Mo(4) bond length. The Mo(1)-Ag(2) bond length is 2.74 Å. There is one shorter (2.79 Å) and one longer (2.97 Å) Mo(1)-Ag(1) bond length. In the second Mo site, Mo(2) is bonded in a distorted single-bond geometry to one Mo(1) and one Ag(2) atom. The Mo(2)-Ag(2) bond length is 1.65 Å. In the third Mo site, Mo(3) is bonded in a distorted water-like geometry to one Mo(4), one Ag(1), and one Ag(2) atom. The Mo(3)-Mo(4) bond length is 2.07 Å. The Mo(3)-Ag(1) bond length is 1.42 Å. The Mo(3)-Ag(2) bond length is 1.53 Å. In the fourth Mo site, Mo(4) is bonded in a 3-coordinate geometry to one Mo(3), two equivalent Mo(1), and one Ag(1) atom. The Mo(4)-Ag(1) bond length is 2.54 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted single-bond geometry to one Mo(3), one Mo(4), and two equivalent Mo(1) atoms. In the second Ag site, Ag(2) is bonded in a distorted bent 150 degrees geometry to one Mo(1), one Mo(2), and one Mo(3) atom.