data_Ti2PbCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.92
_cell_length_b   4.92
_cell_length_c   3.17
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ti2PbCl
_chemical_formula_sum   'Ti2 Pb1 Cl1'
_cell_volume   76.69
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti2  1  0.46  0.0  0.58  1.0
  Ti  Ti3  1  0.0  0.46  0.58  1.0
  Pb  Pb1  1  0.46  0.46  0.0  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Ti2PbCl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.96
_cell_length_b   6.96
_cell_length_c   3.17
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Ti2PbCl
_chemical_formula_sum   'Ti4 Pb2 Cl2'
_cell_volume   153.39
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  4  0.23  0.23  0.58  1.0
  Pb  Pb1  2  0.46  0.0  -0.0  1.0
  Cl  Cl2  2  0.0  0.0  0.0  1.0

Ti Ti Pb Cl
Ti2PbCl crystallizes in the monoclinic Cm space group. Ti(1) is bonded in a 8-coordinate geometry to four equivalent Pb(1) and four equivalent Cl(1) atoms. There are a spread of Ti(1)-Pb(1) bond distances ranging from 2.62-3.24 Å. There are a spread of Ti(1)-Cl(1) bond distances ranging from 2.62-3.24 Å. Pb(1) is bonded in a 8-coordinate geometry to eight equivalent Ti(1) atoms. Cl(1) is bonded in a 8-coordinate geometry to eight equivalent Ti(1) atoms.