data_LaVAg2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.29
_cell_length_b   3.29
_cell_length_c   7.74
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaVAg2
_chemical_formula_sum   'La1 V1 Ag2'
_cell_volume   83.56
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La2  1  0.0  0.0  0.87  1.0
  V  V3  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.64  0.64  0.52  1.0
  Ag  Ag1  1  0.64  0.64  0.22  1.0

data_LaVAg2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.65
_cell_length_b   4.65
_cell_length_c   7.74
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LaVAg2
_chemical_formula_sum   'La2 V2 Ag4'
_cell_volume   167.11
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  2  0.0  0.0  0.87  1.0
  V  V1  2  0.0  0.0  0.0  1.0
  Ag  Ag2  2  0.14  0.5  0.22  1.0
  Ag  Ag3  2  0.14  0.5  0.52  1.0

La V Ag Ag
LaVAg2 crystallizes in the monoclinic Cm space group. La(1) is bonded in a single-bond geometry to one V(1) and four equivalent Ag(1) atoms. The La(1)-V(1) bond length is 1.00 Å. There are a spread of La(1)-Ag(1) bond distances ranging from 3.16-4.02 Å. V(1) is bonded in a distorted single-bond geometry to one La(1) and one Ag(2) atom. The V(1)-Ag(2) bond length is 2.37 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 9-coordinate geometry to four equivalent La(1), one Ag(2), and four equivalent Ag(1) atoms. The Ag(1)-Ag(2) bond length is 2.35 Å. All Ag(1)-Ag(1) bond lengths are 3.29 Å. In the second Ag site, Ag(2) is bonded in a 1-coordinate geometry to one V(1) and one Ag(1) atom.