data_K2InRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.2
_cell_length_b   3.2
_cell_length_c   11.19
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   91.15
_symmetry_Int_Tables_number   1
_chemical_formula_structural   K2InRh
_chemical_formula_sum   'K2 In1 Rh1'
_cell_volume   114.37
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K1  1  0.24  0.0  0.85  1.0
  K  K2  1  0.24  0.0  0.34  1.0
  In  In0  1  0.0  0.0  0.6  1.0
  Rh  Rh3  1  0.0  0.0  0.0  1.0

data_K2InRh
_symmetry_space_group_name_H-M   Pm
_cell_length_a   3.2
_cell_length_b   3.2
_cell_length_c   11.19
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   K2InRh
_chemical_formula_sum   'K2 In1 Rh1'
_cell_volume   114.39
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.24  0.0  0.34  1.0
  K  K1  1  0.24  0.0  0.85  1.0
  In  In2  1  0.0  0.0  0.6  1.0
  Rh  Rh3  1  0.0  0.0  0.0  1.0

K K In Rh
K2RhIn crystallizes in the monoclinic Pm space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a distorted single-bond geometry to one Rh(1) and one In(1) atom. The K(1)-Rh(1) bond length is 1.81 Å. The K(1)-In(1) bond length is 2.98 Å. In the second K site, K(2) is bonded in a 7-coordinate geometry to four equivalent K(2), one Rh(1), and two equivalent In(1) atoms. All K(2)-K(2) bond lengths are 3.20 Å. The K(2)-Rh(1) bond length is 3.85 Å. There is one shorter (2.98 Å) and one longer (3.77 Å) K(2)-In(1) bond length. Rh(1) is bonded in a single-bond geometry to one K(1) and one K(2) atom. In(1) is bonded in a distorted bent 150 degrees geometry to one K(1) and two equivalent K(2) atoms.