data_B4PRu4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.22
_cell_length_b   7.22
_cell_length_c   4.15
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   B4PRu4
_chemical_formula_sum   'B8 P2 Ru8'
_cell_volume   216.14
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.87  0.91  0.66  1.0
  B  B1  1  0.35  0.3  0.66  1.0
  B  B2  1  0.91  0.26  0.59  1.0
  B  B3  1  0.31  0.96  0.59  1.0
  B  B4  1  0.96  0.91  0.57  1.0
  B  B5  1  0.26  0.31  0.57  1.0
  B  B6  1  0.91  0.35  0.49  1.0
  B  B7  1  0.3  0.87  0.49  1.0
  P  P8  1  0.61  0.61  0.08  1.0
  P  P9  1  0.0  0.0  0.0  1.0
  Ru  Ru10  1  0.49  0.45  0.65  1.0
  Ru  Ru11  1  0.73  0.77  0.65  1.0
  Ru  Ru12  1  0.16  0.88  0.57  1.0
  Ru  Ru13  1  0.05  0.34  0.57  1.0
  Ru  Ru14  1  0.34  0.16  0.58  1.0
  Ru  Ru15  1  0.88  0.05  0.58  1.0
  Ru  Ru16  1  0.45  0.73  0.51  1.0
  Ru  Ru17  1  0.77  0.49  0.51  1.0

data_B4PRu4
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.15
_cell_length_b   7.22
_cell_length_c   7.22
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   B4PRu4
_chemical_formula_sum   'B8 P2 Ru8'
_cell_volume   216.14
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.49  0.3  0.87  1.0
  B  B1  1  0.49  0.91  0.35  1.0
  B  B2  1  0.57  0.26  0.31  1.0
  B  B3  1  0.57  0.96  0.91  1.0
  B  B4  1  0.59  0.31  0.96  1.0
  B  B5  1  0.59  0.91  0.26  1.0
  B  B6  1  0.66  0.35  0.3  1.0
  B  B7  1  0.66  0.87  0.91  1.0
  P  P8  1  0.0  0.0  0.0  1.0
  P  P9  1  0.08  0.61  0.61  1.0
  Ru  Ru10  1  0.51  0.45  0.73  1.0
  Ru  Ru11  1  0.51  0.77  0.49  1.0
  Ru  Ru12  1  0.57  0.05  0.34  1.0
  Ru  Ru13  1  0.57  0.16  0.88  1.0
  Ru  Ru14  1  0.58  0.34  0.16  1.0
  Ru  Ru15  1  0.58  0.88  0.05  1.0
  Ru  Ru16  1  0.65  0.49  0.45  1.0
  Ru  Ru17  1  0.65  0.73  0.77  1.0

B B B B B B B B P P Ru Ru Ru Ru Ru Ru Ru Ru
Ru4B4P crystallizes in the triclinic P1 space group. There are eight inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a distorted single-bond geometry to one B(2) and one P(1) atom. The Ru(1)-B(2) bond length is 1.45 Å. The Ru(1)-P(1) bond length is 2.30 Å. In the second Ru site, Ru(2) is bonded in a distorted single-bond geometry to one B(1) and one P(1) atom. The Ru(2)-B(1) bond length is 1.45 Å. The Ru(2)-P(1) bond length is 2.30 Å. In the third Ru site, Ru(3) is bonded in a 3-coordinate geometry to one B(4), one B(5), and one B(8) atom. The Ru(3)-B(4) bond length is 1.18 Å. The Ru(3)-B(5) bond length is 1.51 Å. The Ru(3)-B(8) bond length is 1.06 Å. In the fourth Ru site, Ru(4) is bonded in a 3-coordinate geometry to one B(3), one B(6), and one B(7) atom. The Ru(4)-B(3) bond length is 1.18 Å. The Ru(4)-B(6) bond length is 1.51 Å. The Ru(4)-B(7) bond length is 1.06 Å. In the fifth Ru site, Ru(5) is bonded in a 3-coordinate geometry to one B(2), one B(4), and one B(6) atom. The Ru(5)-B(2) bond length is 1.06 Å. The Ru(5)-B(4) bond length is 1.51 Å. The Ru(5)-B(6) bond length is 1.18 Å. In the sixth Ru site, Ru(6) is bonded in a 3-coordinate geometry to one B(1), one B(3), and one B(5) atom. The Ru(6)-B(1) bond length is 1.06 Å. The Ru(6)-B(3) bond length is 1.51 Å. The Ru(6)-B(5) bond length is 1.18 Å. In the seventh Ru site, Ru(7) is bonded in a distorted single-bond geometry to one B(8) and one P(1) atom. The Ru(7)-B(8) bond length is 1.45 Å. The Ru(7)-P(1) bond length is 2.30 Å. In the eighth Ru site, Ru(8) is bonded in a distorted single-bond geometry to one B(7) and one P(1) atom. The Ru(8)-B(7) bond length is 1.45 Å. The Ru(8)-P(1) bond length is 2.30 Å. There are eight inequivalent B sites. In the first B site, B(1) is bonded in a 4-coordinate geometry to one Ru(2), one Ru(6), one B(5), and one P(2) atom. The B(1)-B(5) bond length is 0.74 Å. The B(1)-P(2) bond length is 1.81 Å. In the second B site, B(2) is bonded in a distorted trigonal planar geometry to one Ru(1), one Ru(5), and one B(6) atom. The B(2)-B(6) bond length is 0.74 Å. In the third B site, B(3) is bonded in a 3-coordinate geometry to one Ru(4), one Ru(6), and one B(7) atom. The B(3)-B(7) bond length is 0.74 Å. In the fourth B site, B(4) is bonded in a 3-coordinate geometry to one Ru(3), one Ru(5), and one B(8) atom. The B(4)-B(8) bond length is 0.74 Å. In the fifth B site, B(5) is bonded in a 3-coordinate geometry to one Ru(3), one Ru(6), and one B(1) atom. In the sixth B site, B(6) is bonded in a 3-coordinate geometry to one Ru(4), one Ru(5), and one B(2) atom. In the seventh B site, B(7) is bonded in a distorted trigonal planar geometry to one Ru(4), one Ru(8), and one B(3) atom. In the eighth B site, B(8) is bonded in a distorted trigonal planar geometry to one Ru(3), one Ru(7), and one B(4) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 4-coordinate geometry to one Ru(1), one Ru(2), one Ru(7), and one Ru(8) atom. In the second P site, P(2) is bonded in a 1-coordinate geometry to one B(1) atom.