data_NaAgW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.64
_cell_length_b   4.35
_cell_length_c   6.33
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaAgW2
_chemical_formula_sum   'Na1 Ag1 W2'
_cell_volume   72.75
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na1  1  0.0  0.0  0.64  1.0
  Ag  Ag0  1  0.32  0.18  0.16  1.0
  W  W2  1  0.32  0.18  0.25  1.0
  W  W3  1  0.0  0.0  0.44  1.0

data_NaAgW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.64
_cell_length_b   4.35
_cell_length_c   6.33
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaAgW2
_chemical_formula_sum   'Na1 Ag1 W2'
_cell_volume   72.75
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.64  1.0
  Ag  Ag1  1  0.32  0.18  0.16  1.0
  W  W2  1  0.0  0.0  0.44  1.0
  W  W3  1  0.32  0.18  0.25  1.0

Na Ag W W
NaWAg(W) crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Ag(W) cluster and one NaW cluster. In the Ag(W) cluster, W(1) is bonded in a single-bond geometry to one Ag(1) atom. The W(1)-Ag(1) bond length is 0.56 Å. Ag(1) is bonded in a single-bond geometry to one W(1) atom. In the NaW cluster, Na(1) is bonded in a single-bond geometry to one W(2) atom. The Na(1)-W(2) bond length is 1.25 Å. W(2) is bonded in a single-bond geometry to one Na(1) atom.