data_AlIn2Mo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.94
_cell_length_b   5.07
_cell_length_c   5.2
_cell_angle_alpha   90.0
_cell_angle_beta   92.81
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AlIn2Mo
_chemical_formula_sum   'Al1 In2 Mo1'
_cell_volume   77.47
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.12  0.54  0.87  1.0
  In  In2  1  0.56  0.54  0.33  1.0
  Mo  Mo3  1  0.34  0.0  0.6  1.0

data_AlIn2Mo
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.94
_cell_length_b   5.07
_cell_length_c   5.2
_cell_angle_alpha   90.0
_cell_angle_beta   92.81
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AlIn2Mo
_chemical_formula_sum   'Al1 In2 Mo1'
_cell_volume   77.47
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.12  0.54  0.87  1.0
  In  In2  1  0.56  0.54  0.33  1.0
  Mo  Mo3  1  0.34  0.0  0.6  1.0

Al In In Mo
MoIn2Al crystallizes in the triclinic P1 space group. Mo(1) is bonded in a 1-coordinate geometry to two equivalent In(2) and three equivalent Al(1) atoms. There is one shorter (2.84 Å) and one longer (3.15 Å) Mo(1)-In(2) bond length. There are a spread of Mo(1)-Al(1) bond distances ranging from 2.37-3.22 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 1-coordinate geometry to one In(2) and two equivalent Al(1) atoms. The In(1)-In(2) bond length is 2.65 Å. There is one shorter (2.48 Å) and one longer (2.83 Å) In(1)-Al(1) bond length. In the second In site, In(2) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one In(1) atom. Al(1) is bonded in a 5-coordinate geometry to three equivalent Mo(1) and two equivalent In(1) atoms.