data_Re(AgCl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.04
_cell_length_b   7.04
_cell_length_c   7.04
_cell_angle_alpha   56.8
_cell_angle_beta   56.8
_cell_angle_gamma   56.8
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Re(AgCl3)2
_chemical_formula_sum   'Re1 Ag2 Cl6'
_cell_volume   228.99
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re8  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.0  0.0  0.69  1.0
  Ag  Ag1  1  0.0  0.0  0.97  1.0
  Cl  Cl2  1  0.79  0.63  0.4  1.0
  Cl  Cl3  1  0.42  0.27  0.4  1.0
  Cl  Cl4  1  0.79  0.1  0.4  1.0
  Cl  Cl5  1  0.21  0.37  0.26  1.0
  Cl  Cl6  1  0.58  0.73  0.26  1.0
  Cl  Cl7  1  0.21  0.9  0.26  1.0

data_Re(AgCl3)2
_symmetry_space_group_name_H-M   P1
_cell_length_a   6.7
_cell_length_b   6.7
_cell_length_c   7.04
_cell_angle_alpha   61.6
_cell_angle_beta   61.6
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Re(AgCl3)2
_chemical_formula_sum   'Re1 Ag2 Cl6'
_cell_volume   228.99
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.0  0.0  0.0  1.0
  Ag  Ag1  1  0.0  0.03  0.97  1.0
  Ag  Ag2  1  0.0  0.31  0.69  1.0
  Cl  Cl3  1  0.1  0.74  0.38  1.0
  Cl  Cl4  1  0.27  0.74  0.57  1.0
  Cl  Cl5  1  0.37  0.6  0.82  1.0
  Cl  Cl6  1  0.63  0.74  0.84  1.0
  Cl  Cl7  1  0.73  0.6  0.09  1.0
  Cl  Cl8  1  0.9  0.6  0.28  1.0

Re Ag Ag Cl Cl Cl Cl Cl Cl
Re(AgCl3)2 crystallizes in the triclinic P1 space group. Re(1) is bonded in a distorted single-bond geometry to one Ag(2), one Cl(1), one Cl(3), and one Cl(6) atom. The Re(1)-Ag(2) bond length is 0.22 Å. The Re(1)-Cl(1) bond length is 2.90 Å. The Re(1)-Cl(3) bond length is 2.64 Å. The Re(1)-Cl(6) bond length is 2.58 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one Ag(2), one Cl(3), one Cl(4), and one Cl(6) atom. The Ag(1)-Ag(2) bond length is 1.95 Å. The Ag(1)-Cl(3) bond length is 2.78 Å. The Ag(1)-Cl(4) bond length is 2.95 Å. The Ag(1)-Cl(6) bond length is 2.83 Å. In the second Ag site, Ag(2) is bonded in a distorted single-bond geometry to one Re(1) and one Ag(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to one Re(1), one Cl(4), and one Cl(5) atom. The Cl(1)-Cl(4) bond length is 2.44 Å. The Cl(1)-Cl(5) bond length is 1.84 Å. In the second Cl site, Cl(2) is bonded in a bent 150 degrees geometry to one Cl(3) and one Cl(4) atom. The Cl(2)-Cl(3) bond length is 2.17 Å. The Cl(2)-Cl(4) bond length is 1.84 Å. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to one Re(1), one Ag(1), one Cl(2), and one Cl(6) atom. The Cl(3)-Cl(6) bond length is 2.36 Å. In the fourth Cl site, Cl(4) is bonded in a distorted T-shaped geometry to one Ag(1), one Cl(1), and one Cl(2) atom. In the fifth Cl site, Cl(5) is bonded in a bent 150 degrees geometry to one Cl(1) and one Cl(6) atom. The Cl(5)-Cl(6) bond length is 2.17 Å. In the sixth Cl site, Cl(6) is bonded in a distorted rectangular see-saw-like geometry to one Re(1), one Ag(1), one Cl(3), and one Cl(5) atom.