data_VFeOs2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.67
_cell_length_b   2.67
_cell_length_c   7.46
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VFeOs2
_chemical_formula_sum   'V1 Fe1 Os2'
_cell_volume   53.15
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Fe  Fe0  1  0.0  0.0  0.73  1.0
  Os  Os1  1  0.33  0.33  0.5  1.0
  Os  Os2  1  0.33  0.33  0.97  1.0

data_VFeOs2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.77
_cell_length_b   3.77
_cell_length_c   7.46
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VFeOs2
_chemical_formula_sum   'V2 Fe2 Os4'
_cell_volume   106.3
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.0  1.0
  Fe  Fe1  2  0.0  0.0  0.73  1.0
  Os  Os2  2  0.33  0.0  0.5  1.0
  Os  Os3  2  0.33  0.0  0.97  1.0

V Fe Os Os
VOs2Fe crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two VOs2Fe clusters. V(1) is bonded in a 1-coordinate geometry to one Os(2) and one Fe(1) atom. The V(1)-Os(2) bond length is 1.29 Å. The V(1)-Fe(1) bond length is 2.01 Å. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a distorted single-bond geometry to one Fe(1) atom. The Os(1)-Fe(1) bond length is 2.17 Å. In the second Os site, Os(2) is bonded in a 1-coordinate geometry to one V(1) and one Fe(1) atom. The Os(2)-Fe(1) bond length is 2.17 Å. Fe(1) is bonded in a 3-coordinate geometry to one V(1), one Os(1), and one Os(2) atom.