data_Cu(ReP)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.84
_cell_length_b   6.84
_cell_length_c   2.91
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cu(ReP)2
_chemical_formula_sum   'Cu2 Re4 P4'
_cell_volume   136.0
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.0  0.0  0.0  1.0
  Cu  Cu1  1  0.42  0.42  0.0  1.0
  Re  Re6  1  0.02  0.44  0.45  1.0
  Re  Re7  1  0.82  0.4  0.45  1.0
  Re  Re8  1  0.4  0.02  0.45  1.0
  Re  Re9  1  0.44  0.82  0.45  1.0
  P  P2  1  0.41  0.83  0.0  1.0
  P  P3  1  0.43  0.01  0.0  1.0
  P  P4  1  0.01  0.41  0.0  1.0
  P  P5  1  0.83  0.43  0.0  1.0

data_Cu(ReP)2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.91
_cell_length_b   6.84
_cell_length_c   6.84
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cu(ReP)2
_chemical_formula_sum   'Cu2 Re4 P4'
_cell_volume   136.0
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.0  0.0  0.0  1.0
  Cu  Cu1  1  0.0  0.42  0.42  1.0
  Re  Re2  1  0.45  0.02  0.44  1.0
  Re  Re3  1  0.45  0.4  0.02  1.0
  Re  Re4  1  0.45  0.44  0.82  1.0
  Re  Re5  1  0.45  0.82  0.4  1.0
  P  P6  1  0.0  0.01  0.41  1.0
  P  P7  1  0.0  0.43  0.01  1.0
  P  P8  1  0.0  0.41  0.83  1.0
  P  P9  1  0.0  0.83  0.43  1.0

Cu Cu Re Re Re Re P P P P
Cu(ReP)2 crystallizes in the triclinic P1 space group. There are four inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted T-shaped geometry to one Re(2), two equivalent Cu(2), and two equivalent P(3) atoms. The Re(1)-Re(2) bond length is 1.45 Å. There is one shorter (3.02 Å) and one longer (3.15 Å) Re(1)-Cu(2) bond length. There is one shorter (1.34 Å) and one longer (1.61 Å) Re(1)-P(3) bond length. In the second Re site, Re(2) is bonded in a distorted T-shaped geometry to one Re(1), two equivalent Cu(2), and two equivalent P(4) atoms. There is one shorter (3.02 Å) and one longer (3.15 Å) Re(2)-Cu(2) bond length. There is one shorter (1.34 Å) and one longer (1.61 Å) Re(2)-P(4) bond length. In the third Re site, Re(3) is bonded in a 3-coordinate geometry to one Re(4), two equivalent Cu(2), and two equivalent P(2) atoms. The Re(3)-Re(4) bond length is 1.45 Å. There is one shorter (3.02 Å) and one longer (3.15 Å) Re(3)-Cu(2) bond length. There is one shorter (1.34 Å) and one longer (1.61 Å) Re(3)-P(2) bond length. In the fourth Re site, Re(4) is bonded in a distorted T-shaped geometry to one Re(3), two equivalent Cu(2), and two equivalent P(1) atoms. There is one shorter (3.02 Å) and one longer (3.15 Å) Re(4)-Cu(2) bond length. There is one shorter (1.34 Å) and one longer (1.61 Å) Re(4)-P(1) bond length. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 1-coordinate geometry to one P(3) atom. The Cu(1)-P(3) bond length is 2.83 Å. In the second Cu site, Cu(2) is bonded in a 14-coordinate geometry to two equivalent Re(1), two equivalent Re(2), two equivalent Re(3), two equivalent Re(4), two equivalent Cu(2), one P(1), one P(2), one P(3), and one P(4) atom. Both Cu(2)-Cu(2) bond lengths are 2.91 Å. The Cu(2)-P(1) bond length is 2.83 Å. The Cu(2)-P(2) bond length is 2.83 Å. The Cu(2)-P(3) bond length is 2.83 Å. The Cu(2)-P(4) bond length is 2.83 Å. There are four inequivalent P sites. In the first P site, P(1) is bonded in a distorted T-shaped geometry to two equivalent Re(4), one Cu(2), and one P(2) atom. The P(1)-P(2) bond length is 1.18 Å. In the second P site, P(2) is bonded in a distorted T-shaped geometry to two equivalent Re(3), one Cu(2), and one P(1) atom. In the third P site, P(3) is bonded in a distorted T-shaped geometry to two equivalent Re(1), one Cu(1), one Cu(2), and one P(4) atom. The P(3)-P(4) bond length is 1.18 Å. In the fourth P site, P(4) is bonded in a distorted T-shaped geometry to two equivalent Re(2), one Cu(2), and one P(3) atom.