data_SrV2Br
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.28
_cell_length_b   6.28
_cell_length_c   3.43
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   125.25
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SrV2Br
_chemical_formula_sum   'Sr1 V2 Br1'
_cell_volume   110.46
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr1  1  0.89  0.0  0.0  1.0
  V  V2  1  0.44  0.21  0.71  1.0
  V  V3  1  0.44  0.79  0.71  1.0
  Br  Br0  1  0.0  0.0  0.0  1.0

data_SrV2Br
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.43
_cell_length_b   5.78
_cell_length_c   6.28
_cell_angle_alpha   117.38
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SrV2Br
_chemical_formula_sum   'Sr1 V2 Br1'
_cell_volume   110.46
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.0  0.0  0.89  1.0
  V  V1  1  0.71  0.21  0.66  1.0
  V  V2  1  0.71  0.79  0.23  1.0
  Br  Br3  1  0.0  0.0  0.0  1.0

Sr V V Br
SrV2Br crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one SrV2Br cluster. Sr(1) is bonded in a single-bond geometry to one V(2) and one Br(1) atom. The Sr(1)-V(2) bond length is 2.50 Å. The Sr(1)-Br(1) bond length is 0.70 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded in a single-bond geometry to one Br(1) atom. The V(1)-Br(1) bond length is 2.50 Å. In the second V site, V(2) is bonded in a distorted single-bond geometry to one Sr(1) atom. Br(1) is bonded in a single-bond geometry to one Sr(1) and one V(1) atom.