data_VB2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.45
_cell_length_b   4.45
_cell_length_c   4.45
_cell_angle_alpha   139.69
_cell_angle_beta   139.69
_cell_angle_gamma   58.32
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VB2P
_chemical_formula_sum   'V1 B2 P1'
_cell_volume   36.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.53  0.95  1.0
  B  B0  1  0.0  0.0  0.0  1.0
  B  B1  1  0.53  0.0  0.95  1.0
  P  P2  1  0.0  0.0  0.89  1.0

data_VB2P
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.07
_cell_length_b   3.07
_cell_length_c   4.45
_cell_angle_alpha   110.15
_cell_angle_beta   110.15
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VB2P
_chemical_formula_sum   'V1 B2 P1'
_cell_volume   36.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.41  0.95  0.41  1.0
  B  B1  1  0.0  0.0  0.0  1.0
  B  B2  1  0.95  0.41  0.41  1.0
  P  P3  1  0.89  0.89  0.89  1.0

V B B P
VB2P crystallizes in the triclinic P1 space group. V(1) is bonded in a 6-coordinate geometry to one B(1), four equivalent B(2), and one P(1) atom. The V(1)-B(1) bond length is 1.89 Å. There are a spread of V(1)-B(2) bond distances ranging from 2.02-2.32 Å. The V(1)-P(1) bond length is 2.20 Å. There are two inequivalent B sites. In the first B site, B(1) is bonded in a distorted single-bond geometry to one V(1), one B(2), and one P(1) atom. The B(1)-B(2) bond length is 1.89 Å. The B(1)-P(1) bond length is 0.49 Å. In the second B site, B(2) is bonded to four equivalent V(1), one B(1), and one P(1) atom to form a mixture of distorted edge and corner-sharing BV4BP octahedra. The corner-sharing octahedral tilt angles range from 0-8°. The B(2)-P(1) bond length is 2.20 Å. P(1) is bonded in a distorted single-bond geometry to one V(1), one B(1), and one B(2) atom.