data_MgPPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.97
_cell_length_b   4.97
_cell_length_c   4.97
_cell_angle_alpha   135.1
_cell_angle_beta   135.1
_cell_angle_gamma   65.38
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MgPPd2
_chemical_formula_sum   'Mg1 P1 Pd2'
_cell_volume   60.11
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.0  0.0  0.0  1.0
  P  P1  1  0.9  0.0  0.09  1.0
  Pd  Pd2  1  0.0  0.0  0.18  1.0
  Pd  Pd3  1  0.0  0.9  0.09  1.0

data_MgPPd2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.79
_cell_length_b   3.79
_cell_length_c   4.97
_cell_angle_alpha   112.45
_cell_angle_beta   112.45
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MgPPd2
_chemical_formula_sum   'Mg1 P1 Pd2'
_cell_volume   60.11
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.0  0.0  0.0  1.0
  P  P1  1  0.09  0.19  0.19  1.0
  Pd  Pd2  1  0.18  0.18  0.18  1.0
  Pd  Pd3  1  0.19  0.09  0.19  1.0

Mg P Pd Pd
MgPd2P is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one MgPd2P cluster. Mg(1) is bonded in a 3-coordinate geometry to one Pd(1), one Pd(2), and one P(1) atom. The Mg(1)-Pd(1) bond length is 0.89 Å. The Mg(1)-Pd(2) bond length is 0.89 Å. The Mg(1)-P(1) bond length is 0.89 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 2-coordinate geometry to one Mg(1), one Pd(2), and one P(1) atom. The Pd(1)-Pd(2) bond length is 0.37 Å. The Pd(1)-P(1) bond length is 0.37 Å. In the second Pd site, Pd(2) is bonded in a 2-coordinate geometry to one Mg(1) and one Pd(1) atom. P(1) is bonded in a 2-coordinate geometry to one Mg(1) and one Pd(1) atom.