data_ZnNi2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.16
_cell_length_b   4.16
_cell_length_c   2.94
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnNi2Pd
_chemical_formula_sum   'Zn1 Ni2 Pd1'
_cell_volume   50.95
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.0  0.0  1.0
  Ni  Ni0  1  0.0  0.08  0.47  1.0
  Ni  Ni1  1  0.08  0.0  0.47  1.0
  Pd  Pd2  1  0.08  0.08  0.0  1.0

data_ZnNi2Pd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.88
_cell_length_b   5.88
_cell_length_c   2.94
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZnNi2Pd
_chemical_formula_sum   'Zn2 Ni4 Pd2'
_cell_volume   101.9
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  2  0.0  0.0  0.0  1.0
  Ni  Ni1  4  0.04  0.04  0.47  1.0
  Pd  Pd2  2  0.08  0.0  0.0  1.0

Zn Ni Ni Pd
(Ni)2PdZn crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Ni clusters and two PdZn clusters. In each Ni cluster, Ni(1) is bonded in a single-bond geometry to one Ni(1) atom. The Ni(1)-Ni(1) bond length is 0.47 Å. In each PdZn cluster, Pd(1) is bonded in a single-bond geometry to one Zn(1) atom. The Pd(1)-Zn(1) bond length is 0.47 Å. Zn(1) is bonded in a single-bond geometry to one Pd(1) atom.