data_ScBiOs2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.9
_cell_length_b   4.9
_cell_length_c   5.22
_cell_angle_alpha   101.12
_cell_angle_beta   101.12
_cell_angle_gamma   36.94
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScBiOs2
_chemical_formula_sum   'Sc1 Bi1 Os2'
_cell_volume   73.63
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc3  1  0.0  0.0  0.0  1.0
  Bi  Bi0  1  0.11  0.0  0.55  1.0
  Os  Os1  1  0.65  0.0  0.1  1.0
  Os  Os2  1  0.58  0.0  0.01  1.0

data_ScBiOs2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.1
_cell_length_b   4.9
_cell_length_c   5.22
_cell_angle_alpha   101.12
_cell_angle_beta   90.0
_cell_angle_gamma   108.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScBiOs2
_chemical_formula_sum   'Sc1 Bi1 Os2'
_cell_volume   73.63
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.0  0.0  0.0  1.0
  Bi  Bi1  1  0.0  0.89  0.45  1.0
  Os  Os2  1  0.0  0.35  0.9  1.0
  Os  Os3  1  0.0  0.42  0.99  1.0

Sc Bi Os Os
ScOs2Bi crystallizes in the triclinic P1 space group. Sc(1) is bonded in a 1-coordinate geometry to one Os(1) and two equivalent Bi(1) atoms. The Sc(1)-Os(1) bond length is 1.89 Å. There is one shorter (2.49 Å) and one longer (2.84 Å) Sc(1)-Bi(1) bond length. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a water-like geometry to one Sc(1), one Os(2), and one Bi(1) atom. The Os(1)-Os(2) bond length is 0.49 Å. The Os(1)-Bi(1) bond length is 2.97 Å. In the second Os site, Os(2) is bonded in a distorted single-bond geometry to one Os(1) and one Bi(1) atom. The Os(2)-Bi(1) bond length is 2.97 Å. Bi(1) is bonded in a 6-coordinate geometry to two equivalent Sc(1), one Os(1), one Os(2), and two equivalent Bi(1) atoms. Both Bi(1)-Bi(1) bond lengths are 3.10 Å.