data_Te2PRu
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.29
_cell_length_b   3.29
_cell_length_c   7.36
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Te2PRu
_chemical_formula_sum   'Te2 P1 Ru1'
_cell_volume   79.56
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te2  1  0.64  0.64  0.37  1.0
  Te  Te3  1  0.64  0.64  0.99  1.0
  P  P0  1  0.0  0.0  0.0  1.0
  Ru  Ru1  1  0.0  0.0  0.68  1.0

data_Te2PRu
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.65
_cell_length_b   4.65
_cell_length_c   7.36
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Te2PRu
_chemical_formula_sum   'Te4 P2 Ru2'
_cell_volume   159.12
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  2  0.14  0.5  0.37  1.0
  Te  Te1  2  0.14  0.5  0.99  1.0
  P  P2  2  0.0  0.0  0.0  1.0
  Ru  Ru3  2  0.0  0.0  0.68  1.0

Te Te P Ru
RuPTe2 crystallizes in the monoclinic Cm space group. Ru(1) is bonded in a 2-coordinate geometry to one P(1) and three equivalent Te(1) atoms. The Ru(1)-P(1) bond length is 2.36 Å. There is one shorter (2.83 Å) and two longer (3.34 Å) Ru(1)-Te(1) bond lengths. P(1) is bonded in a 1-coordinate geometry to one Ru(1), one Te(1), and one Te(2) atom. The P(1)-Te(1) bond length is 3.17 Å. The P(1)-Te(2) bond length is 1.66 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 9-coordinate geometry to three equivalent Ru(1), one P(1), one Te(2), and four equivalent Te(1) atoms. The Te(1)-Te(2) bond length is 2.76 Å. All Te(1)-Te(1) bond lengths are 3.29 Å. In the second Te site, Te(2) is bonded in a 1-coordinate geometry to one P(1) and one Te(1) atom.