data_ZnOs2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.87
_cell_length_b   2.87
_cell_length_c   7.88
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnOs2Cl
_chemical_formula_sum   'Zn1 Os2 Cl1'
_cell_volume   64.76
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.43  0.43  0.6  1.0
  Os  Os1  1  0.43  0.43  0.18  1.0
  Os  Os2  1  0.0  0.0  0.84  1.0
  Cl  Cl0  1  0.0  0.0  0.21  1.0

data_ZnOs2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.05
_cell_length_b   4.05
_cell_length_c   7.88
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZnOs2Cl
_chemical_formula_sum   'Zn2 Os4 Cl2'
_cell_volume   129.52
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  2  0.43  0.0  0.6  1.0
  Os  Os1  2  0.0  0.0  0.84  1.0
  Os  Os2  2  0.43  0.0  0.18  1.0
  Cl  Cl3  2  0.0  0.0  0.21  1.0

Zn Os Os Cl
Os2ZnCl crystallizes in the monoclinic Cm space group. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 4-coordinate geometry to one Zn(1) and four equivalent Cl(1) atoms. The Os(1)-Zn(1) bond length is 3.28 Å. There are a spread of Os(1)-Cl(1) bond distances ranging from 1.76-2.30 Å. In the second Os site, Os(2) is bonded in a 5-coordinate geometry to four equivalent Zn(1) and one Cl(1) atom. There are a spread of Os(2)-Zn(1) bond distances ranging from 2.55-2.95 Å. The Os(2)-Cl(1) bond length is 2.92 Å. Zn(1) is bonded in a 9-coordinate geometry to one Os(1), four equivalent Os(2), and four equivalent Zn(1) atoms. All Zn(1)-Zn(1) bond lengths are 2.87 Å. Cl(1) is bonded in a 5-coordinate geometry to one Os(2) and four equivalent Os(1) atoms.