data_Tl2RhW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.91
_cell_length_b   4.91
_cell_length_c   3.12
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Tl2RhW
_chemical_formula_sum   'Tl2 Rh1 W1'
_cell_volume   75.28
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl1  1  0.0  0.46  0.56  1.0
  Tl  Tl2  1  0.46  0.0  0.56  1.0
  Rh  Rh0  1  0.0  0.0  0.0  1.0
  W  W3  1  0.46  0.46  0.0  1.0

data_Tl2RhW
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.95
_cell_length_b   6.95
_cell_length_c   3.12
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Tl2RhW
_chemical_formula_sum   'Tl4 Rh2 W2'
_cell_volume   150.55
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  4  0.23  0.23  0.56  1.0
  Rh  Rh1  2  0.0  0.0  0.0  1.0
  W  W2  2  0.46  0.0  -0.0  1.0

Tl Tl Rh W
WRhTl2 is alpha iridium vanadium-derived structured and crystallizes in the monoclinic Cm space group. W(1) is bonded in a 8-coordinate geometry to eight equivalent Tl(1) atoms. There are a spread of W(1)-Tl(1) bond distances ranging from 2.63-3.19 Å. Rh(1) is bonded in a 8-coordinate geometry to eight equivalent Tl(1) atoms. There are a spread of Rh(1)-Tl(1) bond distances ranging from 2.63-3.19 Å. Tl(1) is bonded in a 8-coordinate geometry to four equivalent W(1) and four equivalent Rh(1) atoms.