data_K2NiPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.09
_cell_length_b   3.09
_cell_length_c   9.84
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   K2NiPd
_chemical_formula_sum   'K2 Ni1 Pd1'
_cell_volume   94.02
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.55  0.55  0.37  1.0
  K  K1  1  0.55  0.55  0.47  1.0
  Ni  Ni2  1  0.0  0.0  0.0  1.0
  Pd  Pd3  1  0.0  0.0  0.92  1.0

data_K2NiPd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.37
_cell_length_b   4.37
_cell_length_c   9.84
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   K2NiPd
_chemical_formula_sum   'K4 Ni2 Pd2'
_cell_volume   188.05
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  2  0.05  0.5  0.37  1.0
  K  K1  2  0.05  0.5  0.47  1.0
  Ni  Ni2  2  0.0  0.0  0.0  1.0
  Pd  Pd3  2  0.0  0.0  0.92  1.0

K K Ni Pd
(K)2PdNi is gamma nitrogen-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two potassio-kalium molecules and two PdNi clusters. In each PdNi cluster, Pd(1) is bonded in a single-bond geometry to one Ni(1) atom. The Pd(1)-Ni(1) bond length is 0.78 Å. Ni(1) is bonded in a single-bond geometry to one Pd(1) atom.