data_ZrZnRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.96
_cell_length_b   4.96
_cell_length_c   4.96
_cell_angle_alpha   139.44
_cell_angle_beta   139.44
_cell_angle_gamma   58.7
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrZnRh
_chemical_formula_sum   'Zr1 Zn1 Rh1'
_cell_volume   51.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr2  1  0.0  0.0  0.71  1.0
  Zn  Zn1  1  0.0  0.0  0.93  1.0
  Rh  Rh0  1  0.0  0.0  0.02  1.0

data_ZrZnRh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.87
_cell_length_b   4.87
_cell_length_c   4.96
_cell_angle_alpha   90.0
_cell_angle_beta   119.35
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZrZnRh
_chemical_formula_sum   'Zr2 Zn2 Rh2'
_cell_volume   102.47
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  2  0.0  0.0  0.29  1.0
  Zn  Zn1  2  0.0  0.0  0.07  1.0
  Rh  Rh2  2  0.0  0.0  0.98  1.0

Zr Zn Rh
ZrRhZn crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ZrRhZn clusters. Zr(1) is bonded in a single-bond geometry to one Zn(1) atom. The Zr(1)-Zn(1) bond length is 1.10 Å. Rh(1) is bonded in a single-bond geometry to one Zn(1) atom. The Rh(1)-Zn(1) bond length is 0.43 Å. Zn(1) is bonded in a linear geometry to one Zr(1) and one Rh(1) atom.