data_V2TcP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.09
_cell_length_b   3.09
_cell_length_c   5.51
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2TcP
_chemical_formula_sum   'V2 Tc1 P1'
_cell_volume   52.45
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.0  0.17  1.0
  V  V3  1  0.54  0.54  0.39  1.0
  Tc  Tc1  1  0.54  0.54  0.97  1.0
  P  P0  1  0.0  0.0  0.73  1.0

data_V2TcP
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.36
_cell_length_b   4.36
_cell_length_c   5.51
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   V2TcP
_chemical_formula_sum   'V4 Tc2 P2'
_cell_volume   104.9
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.17  1.0
  V  V1  2  0.04  0.5  0.39  1.0
  Tc  Tc2  2  0.04  0.5  0.97  1.0
  P  P3  2  0.0  0.0  0.73  1.0

V V Tc P
V2TcP is gamma CuTi-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 10-coordinate geometry to four equivalent V(2), four equivalent Tc(1), and two equivalent P(1) atoms. There are a spread of V(1)-V(2) bond distances ranging from 2.33-2.65 Å. There are a spread of V(1)-Tc(1) bond distances ranging from 2.28-2.61 Å. There is one shorter (2.42 Å) and one longer (3.09 Å) V(1)-P(1) bond length. In the second V site, V(2) is bonded in a 9-coordinate geometry to four equivalent V(1), one Tc(1), and four equivalent P(1) atoms. The V(2)-Tc(1) bond length is 2.30 Å. There are a spread of V(2)-P(1) bond distances ranging from 2.75-3.03 Å. Tc(1) is bonded in a 9-coordinate geometry to one V(2), four equivalent V(1), and four equivalent P(1) atoms. There are a spread of Tc(1)-P(1) bond distances ranging from 2.39-2.71 Å. P(1) is bonded in a 10-coordinate geometry to two equivalent V(1), four equivalent V(2), and four equivalent Tc(1) atoms.