data_NaAgBi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.94
_cell_length_b   5.94
_cell_length_c   5.94
_cell_angle_alpha   133.88
_cell_angle_beta   133.88
_cell_angle_gamma   67.28
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaAgBi2
_chemical_formula_sum   'Na1 Ag1 Bi2'
_cell_volume   106.83
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na3  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.32  0.0  0.47  1.0
  Bi  Bi1  1  0.0  0.0  0.94  1.0
  Bi  Bi2  1  0.0  0.32  0.47  1.0

data_NaAgBi2
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.65
_cell_length_b   4.65
_cell_length_c   5.94
_cell_angle_alpha   113.06
_cell_angle_beta   113.06
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaAgBi2
_chemical_formula_sum   'Na1 Ag1 Bi2'
_cell_volume   106.83
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.0  1.0
  Ag  Ag1  1  0.47  0.15  0.15  1.0
  Bi  Bi2  1  0.15  0.47  0.15  1.0
  Bi  Bi3  1  0.94  0.94  0.94  1.0

Na Ag Bi Bi
NaAgBi2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one NaAgBi2 cluster. Na(1) is bonded in a single-bond geometry to one Ag(1), one Bi(1), and one Bi(2) atom. The Na(1)-Ag(1) bond length is 2.01 Å. The Na(1)-Bi(1) bond length is 0.35 Å. The Na(1)-Bi(2) bond length is 2.01 Å. Ag(1) is bonded in a distorted single-bond geometry to one Na(1) atom. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a single-bond geometry to one Na(1) atom. In the second Bi site, Bi(2) is bonded in a distorted single-bond geometry to one Na(1) atom.