data_NiMo2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.75
_cell_length_b   4.75
_cell_length_c   4.55
_cell_angle_alpha   100.59
_cell_angle_beta   100.59
_cell_angle_gamma   34.57
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NiMo2Rh
_chemical_formula_sum   'Ni1 Mo2 Rh1'
_cell_volume   57.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni2  1  0.0  0.0  0.0  1.0
  Mo  Mo0  1  0.57  0.0  0.09  1.0
  Mo  Mo1  1  0.64  0.0  0.37  1.0
  Rh  Rh3  1  0.1  0.0  0.23  1.0

data_NiMo2Rh
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.82
_cell_length_b   4.55
_cell_length_c   4.75
_cell_angle_alpha   100.59
_cell_angle_beta   107.28
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NiMo2Rh
_chemical_formula_sum   'Ni1 Mo2 Rh1'
_cell_volume   57.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.0  0.0  0.0  1.0
  Mo  Mo1  1  0.0  0.09  0.57  1.0
  Mo  Mo2  1  0.0  0.37  0.64  1.0
  Rh  Rh3  1  0.0  0.23  0.1  1.0

Ni Mo Mo Rh
Mo2RhNi crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Mo2RhNi cluster. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 2-coordinate geometry to one Mo(2) and one Ni(1) atom. The Mo(1)-Mo(2) bond length is 1.24 Å. The Mo(1)-Ni(1) bond length is 2.17 Å. In the second Mo site, Mo(2) is bonded in a distorted single-bond geometry to one Mo(1) atom. Rh(1) is bonded in a single-bond geometry to one Ni(1) atom. The Rh(1)-Ni(1) bond length is 1.07 Å. Ni(1) is bonded in a single-bond geometry to one Mo(1) and one Rh(1) atom.