data_BaP2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.54
_cell_length_b   3.54
_cell_length_c   6.85
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaP2Pd
_chemical_formula_sum   'Ba1 P2 Pd1'
_cell_volume   85.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.77  0.77  0.3  1.0
  P  P1  1  0.0  0.0  0.42  1.0
  P  P2  1  0.77  0.77  0.82  1.0
  Pd  Pd3  1  0.0  0.0  0.74  1.0

data_BaP2Pd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.0
_cell_length_b   5.0
_cell_length_c   6.85
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   BaP2Pd
_chemical_formula_sum   'Ba2 P4 Pd2'
_cell_volume   171.41
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  2  0.27  0.5  0.3  1.0
  P  P1  2  0.0  0.0  0.42  1.0
  P  P2  2  0.27  0.5  0.82  1.0
  Pd  Pd3  2  0.0  0.0  0.74  1.0

Ba P P Pd
BaPdP2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two BaPdP2 clusters. Ba(1) is bonded in a single-bond geometry to one P(1) and one P(2) atom. The Ba(1)-P(1) bond length is 1.44 Å. The Ba(1)-P(2) bond length is 3.24 Å. Pd(1) is bonded in a 1-coordinate geometry to one P(2) atom. The Pd(1)-P(2) bond length is 1.28 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a single-bond geometry to one Ba(1) atom. In the second P site, P(2) is bonded in a 2-coordinate geometry to one Ba(1) and one Pd(1) atom.