data_NaTlRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.28
_cell_length_b   5.28
_cell_length_c   4.9
_cell_angle_alpha   103.62
_cell_angle_beta   103.62
_cell_angle_gamma   33.02
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaTlRh2
_chemical_formula_sum   'Na1 Tl1 Rh2'
_cell_volume   72.2
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.24  0.0  0.16  1.0
  Tl  Tl3  1  0.61  0.0  0.43  1.0
  Rh  Rh1  1  0.74  0.0  0.64  1.0
  Rh  Rh2  1  0.71  0.0  0.65  1.0

data_NaTlRh2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.0
_cell_length_b   4.9
_cell_length_c   5.28
_cell_angle_alpha   103.62
_cell_angle_beta   106.51
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaTlRh2
_chemical_formula_sum   'Na1 Tl1 Rh2'
_cell_volume   72.2
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.16  0.24  1.0
  Tl  Tl1  1  0.0  0.43  0.61  1.0
  Rh  Rh2  1  0.0  0.64  0.74  1.0
  Rh  Rh3  1  0.0  0.65  0.71  1.0

Na Tl Rh Rh
NaRh2Tl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one NaRh2Tl cluster. Na(1) is bonded in a distorted single-bond geometry to one Tl(1) atom. The Na(1)-Tl(1) bond length is 2.06 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 1-coordinate geometry to one Rh(2) and one Tl(1) atom. The Rh(1)-Rh(2) bond length is 0.21 Å. The Rh(1)-Tl(1) bond length is 1.12 Å. In the second Rh site, Rh(2) is bonded in a distorted single-bond geometry to one Rh(1) and one Tl(1) atom. The Rh(2)-Tl(1) bond length is 1.12 Å. Tl(1) is bonded in a 3-coordinate geometry to one Na(1), one Rh(1), and one Rh(2) atom.