data_Ru24W5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.18
_cell_length_b   8.18
_cell_length_c   8.18
_cell_angle_alpha   109.47
_cell_angle_beta   109.47
_cell_angle_gamma   109.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ru24W5
_chemical_formula_sum   'Ru24 W5'
_cell_volume   421.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.86  0.14  0.66  1.0
  Ru  Ru1  1  0.14  0.86  0.66  1.0
  Ru  Ru2  1  0.86  0.86  0.78  1.0
  Ru  Ru3  1  0.87  0.87  0.06  1.0
  Ru  Ru4  1  0.86  0.78  0.86  1.0
  Ru  Ru5  1  0.87  0.06  0.87  1.0
  Ru  Ru6  1  0.14  0.66  0.86  1.0
  Ru  Ru7  1  0.86  0.66  0.14  1.0
  Ru  Ru8  1  0.66  0.14  0.86  1.0
  Ru  Ru9  1  0.66  0.86  0.14  1.0
  Ru  Ru10  1  0.06  0.87  0.87  1.0
  Ru  Ru11  1  0.78  0.86  0.86  1.0
  Ru  Ru12  1  0.66  0.34  0.12  1.0
  Ru  Ru13  1  0.34  0.66  0.12  1.0
  Ru  Ru14  1  0.38  0.38  0.6  1.0
  Ru  Ru15  1  0.34  0.34  0.32  1.0
  Ru  Ru16  1  0.38  0.6  0.38  1.0
  Ru  Ru17  1  0.34  0.32  0.34  1.0
  Ru  Ru18  1  0.34  0.12  0.66  1.0
  Ru  Ru19  1  0.66  0.12  0.34  1.0
  Ru  Ru20  1  0.12  0.34  0.66  1.0
  Ru  Ru21  1  0.12  0.66  0.34  1.0
  Ru  Ru22  1  0.32  0.34  0.34  1.0
  Ru  Ru23  1  0.6  0.38  0.38  1.0
  W  W24  1  0.06  0.94  0.06  1.0
  W  W25  1  0.94  0.06  0.06  1.0
  W  W26  1  0.06  0.06  0.94  1.0
  W  W27  1  0.66  0.66  0.66  1.0
  W  W28  1  0.0  0.0  0.0  1.0

data_Ru24W5
_symmetry_space_group_name_H-M   R3m
_cell_length_a   13.36
_cell_length_b   13.36
_cell_length_c   8.18
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   Ru24W5
_chemical_formula_sum   'Ru72 W15'
_cell_volume   1263.71
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+2/3, y+1/3, z+1/3'
  8  '-y+2/3, x-y+1/3, z+1/3'
  9  '-x+y+2/3, -x+1/3, z+1/3'
  10  '-y+2/3, -x+1/3, z+1/3'
  11  '-x+y+2/3, y+1/3, z+1/3'
  12  'x+2/3, x-y+1/3, z+1/3'
  13  'x+1/3, y+2/3, z+2/3'
  14  '-y+1/3, x-y+2/3, z+2/3'
  15  '-x+y+1/3, -x+2/3, z+2/3'
  16  '-y+1/3, -x+2/3, z+2/3'
  17  '-x+y+1/3, y+2/3, z+2/3'
  18  'x+1/3, x-y+2/3, z+2/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  18  0.08  0.38  0.04  1.0
  Ru  Ru1  18  0.11  0.41  0.55  1.0
  Ru  Ru2  9  0.01  0.01  0.33  1.0
  Ru  Ru3  9  0.02  0.05  0.83  1.0
  Ru  Ru4  9  0.13  0.06  0.93  1.0
  Ru  Ru5  9  0.15  0.07  0.46  1.0
  W  W6  9  0.04  0.08  0.02  1.0
  W  W7  3  0.0  0.0  0.0  1.0
  W  W8  3  0.0  0.0  0.66  1.0

Ru Ru Ru Ru Ru Ru Ru Ru Ru Ru Ru Ru Ru Ru Ru Ru Ru Ru Ru Ru Ru Ru Ru Ru W W W W W
W5Ru24 crystallizes in the trigonal R3m space group. There are three inequivalent W sites. In the first W site, W(1) is bonded in a distorted single-bond geometry to one W(3) and two equivalent Ru(3) atoms. The W(1)-W(3) bond length is 0.94 Å. Both W(1)-Ru(3) bond lengths are 1.50 Å. In the second W site, W(2) is bonded in a 6-coordinate geometry to three equivalent Ru(2) and three equivalent Ru(5) atoms. All W(2)-Ru(2) bond lengths are 1.50 Å. All W(2)-Ru(5) bond lengths are 2.39 Å. In the third W site, W(3) is bonded in a distorted trigonal planar geometry to three equivalent W(1) and three equivalent Ru(3) atoms. All W(3)-Ru(3) bond lengths are 1.60 Å. There are six inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a 3-coordinate geometry to one Ru(3) and two equivalent Ru(4) atoms. The Ru(1)-Ru(3) bond length is 1.99 Å. There is one shorter (2.23 Å) and one longer (2.49 Å) Ru(1)-Ru(4) bond length. In the second Ru site, Ru(2) is bonded in a 2-coordinate geometry to one W(2), two equivalent Ru(2), and two equivalent Ru(3) atoms. Both Ru(2)-Ru(2) bond lengths are 0.98 Å. Both Ru(2)-Ru(3) bond lengths are 1.54 Å. In the third Ru site, Ru(3) is bonded in a 7-coordinate geometry to one W(3), two equivalent W(1), two equivalent Ru(1), and two equivalent Ru(2) atoms. In the fourth Ru site, Ru(4) is bonded in a 3-coordinate geometry to one Ru(5) and two equivalent Ru(1) atoms. The Ru(4)-Ru(5) bond length is 2.29 Å. In the fifth Ru site, Ru(5) is bonded in a 5-coordinate geometry to one W(2), two equivalent Ru(4), and two equivalent Ru(6) atoms. Both Ru(5)-Ru(6) bond lengths are 1.91 Å. In the sixth Ru site, Ru(6) is bonded in a 2-coordinate geometry to two equivalent Ru(5) and two equivalent Ru(6) atoms. Both Ru(6)-Ru(6) bond lengths are 0.20 Å.