data_In(CuMo)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.58
_cell_length_b   6.58
_cell_length_c   6.58
_cell_angle_alpha   146.79
_cell_angle_beta   146.79
_cell_angle_gamma   47.68
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In(CuMo)2
_chemical_formula_sum   'In1 Cu2 Mo2'
_cell_volume   85.23
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In2  1  0.0  0.0  0.0  1.0
  Cu  Cu0  1  0.0  0.88  0.01  1.0
  Cu  Cu1  1  0.88  0.0  0.01  1.0
  Mo  Mo3  1  0.0  0.0  0.2  1.0
  Mo  Mo4  1  0.0  0.0  0.84  1.0

data_In(CuMo)2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.32
_cell_length_b   5.32
_cell_length_c   6.58
_cell_angle_alpha   90.0
_cell_angle_beta   113.84
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   In(CuMo)2
_chemical_formula_sum   'In2 Cu4 Mo4'
_cell_volume   170.46
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  0.0  0.0  0.0  1.0
  Cu  Cu1  4  0.07  0.06  0.13  1.0
  Mo  Mo2  2  0.2  0.0  0.2  1.0
  Mo  Mo3  2  0.34  0.5  0.84  1.0

In Cu Cu Mo Mo
In(MoCu)2 is Indium-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two In(MoCu)2 clusters. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Both Mo(1)-Cu(1) bond lengths are 0.73 Å. In the second Mo site, Mo(2) is bonded in a single-bond geometry to one In(1) atom. The Mo(2)-In(1) bond length is 1.04 Å. Cu(1) is bonded in a 3-coordinate geometry to one Mo(1), one Cu(1), and one In(1) atom. The Cu(1)-Cu(1) bond length is 0.63 Å. The Cu(1)-In(1) bond length is 0.84 Å. In(1) is bonded in a 3-coordinate geometry to one Mo(2) and two equivalent Cu(1) atoms.