data_VGa2Te
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.55
_cell_length_b   5.55
_cell_length_c   4.22
_cell_angle_alpha   90.0
_cell_angle_beta   90.24
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VGa2Te
_chemical_formula_sum   'V1 Ga2 Te1'
_cell_volume   83.1
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Ga  Ga0  1  0.81  0.78  0.2  1.0
  Ga  Ga1  1  0.72  0.78  0.02  1.0
  Te  Te2  1  0.76  0.0  0.11  1.0

data_VGa2Te
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.55
_cell_length_b   4.22
_cell_length_c   5.55
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.24
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VGa2Te
_chemical_formula_sum   'V1 Ga2 Te1'
_cell_volume   83.1
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  Ga  Ga1  1  0.19  0.8  0.22  1.0
  Ga  Ga2  1  0.28  0.98  0.22  1.0
  Te  Te3  1  0.24  0.89  0.0  1.0

V Ga Ga Te
VGa2Te crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VGa2Te cluster. V(1) is bonded in a single-bond geometry to one Te(1) atom. The V(1)-Te(1) bond length is 0.96 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 2-coordinate geometry to one Ga(2) and one Te(1) atom. The Ga(1)-Ga(2) bond length is 0.82 Å. The Ga(1)-Te(1) bond length is 1.31 Å. In the second Ga site, Ga(2) is bonded in a 2-coordinate geometry to one Ga(1) and one Te(1) atom. The Ga(2)-Te(1) bond length is 1.31 Å. Te(1) is bonded in a 3-coordinate geometry to one V(1), one Ga(1), and one Ga(2) atom.