data_LiP5W3O19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.78
_cell_length_b   8.78
_cell_length_c   6.56
_cell_angle_alpha   98.8
_cell_angle_beta   98.8
_cell_angle_gamma   113.76
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiP5W3O19
_chemical_formula_sum   'Li1 P5 W3 O19'
_cell_volume   443.88
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.83  0.0  0.94  1.0
  P  P1  1  0.82  0.0  0.38  1.0
  P  P2  1  0.69  0.82  0.71  1.0
  P  P3  1  0.69  0.18  0.71  1.0
  P  P4  1  0.8  0.39  0.02  1.0
  P  P5  1  0.8  0.61  0.02  1.0
  W  W6  1  0.99  0.0  1.0  1.0
  W  W7  1  0.56  0.15  0.16  1.0
  W  W8  1  0.56  0.85  0.16  1.0
  O  O9  1  0.55  0.0  0.29  1.0
  O  O10  1  0.25  0.0  0.92  1.0
  O  O11  1  0.69  0.89  0.56  1.0
  O  O12  1  0.69  0.11  0.56  1.0
  O  O13  1  0.61  0.7  0.62  1.0
  O  O14  1  0.61  0.3  0.62  1.0
  O  O15  1  0.37  0.48  0.41  1.0
  O  O16  1  0.37  0.52  0.41  1.0
  O  O17  1  0.94  0.17  0.44  1.0
  O  O18  1  0.94  0.83  0.44  1.0
  O  O19  1  0.44  0.72  0.33  1.0
  O  O20  1  0.44  0.28  0.33  1.0
  O  O21  1  0.08  0.81  0.18  1.0
  O  O22  1  0.08  0.19  0.18  1.0
  O  O23  1  0.99  0.0  0.07  1.0
  O  O24  1  0.35  0.91  0.61  1.0
  O  O25  1  0.35  0.09  0.61  1.0
  O  O26  1  0.9  0.35  0.92  1.0
  O  O27  1  0.9  0.65  0.92  1.0

data_LiP5W3O19
_symmetry_space_group_name_H-M   P1
_cell_length_a   6.56
_cell_length_b   8.78
_cell_length_c   8.78
_cell_angle_alpha   113.76
_cell_angle_beta   98.8
_cell_angle_gamma   98.8
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiP5W3O19
_chemical_formula_sum   'Li1 P5 W3 O19'
_cell_volume   443.88
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.94  0.83  0.0  1.0
  P  P1  1  0.02  0.8  0.61  1.0
  P  P2  1  0.02  0.8  0.39  1.0
  P  P3  1  0.38  0.82  0.0  1.0
  P  P4  1  0.71  0.69  0.18  1.0
  P  P5  1  0.71  0.69  0.82  1.0
  W  W6  1  0.16  0.56  0.15  1.0
  W  W7  1  0.16  0.56  0.85  1.0
  W  W8  1  1.0  0.99  0.0  1.0
  O  O9  1  0.07  0.99  0.0  1.0
  O  O10  1  0.18  0.08  0.19  1.0
  O  O11  1  0.18  0.08  0.81  1.0
  O  O12  1  0.29  0.55  0.0  1.0
  O  O13  1  0.33  0.44  0.72  1.0
  O  O14  1  0.33  0.44  0.28  1.0
  O  O15  1  0.41  0.37  0.52  1.0
  O  O16  1  0.41  0.37  0.48  1.0
  O  O17  1  0.44  0.94  0.17  1.0
  O  O18  1  0.44  0.94  0.83  1.0
  O  O19  1  0.56  0.69  0.11  1.0
  O  O20  1  0.56  0.69  0.89  1.0
  O  O21  1  0.61  0.35  0.09  1.0
  O  O22  1  0.61  0.35  0.91  1.0
  O  O23  1  0.62  0.61  0.3  1.0
  O  O24  1  0.62  0.61  0.7  1.0
  O  O25  1  0.92  0.9  0.35  1.0
  O  O26  1  0.92  0.9  0.65  1.0
  O  O27  1  0.92  0.25  0.0  1.0

Li P P P P P W W W O O O O O O O O O O O O O O O O O O O
LiW3P2O10P2O3PO2(O2)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one oxido-oxo-phosphanyloxyphosphanium molecule, one oxophosphane;hydrate molecule, two water dimer molecules, and one LiW3P2O10 cluster. In the LiW3P2O10 cluster, Li(1) is bonded in a 2-coordinate geometry to one W(1), one P(2), and one O(14) atom. The Li(1)-W(1) bond length is 1.40 Å. The Li(1)-P(2) bond length is 1.81 Å. The Li(1)-O(14) bond length is 2.30 Å. There are three inequivalent W sites. In the first W site, W(1) is bonded in a single-bond geometry to one Li(1), one O(14), one O(15), and one O(2) atom. The W(1)-O(14) bond length is 1.69 Å. The W(1)-O(15) bond length is 0.44 Å. The W(1)-O(2) bond length is 2.38 Å. In the second W site, W(2) is bonded in a 1-coordinate geometry to one O(1), one O(12), and one O(2) atom. The W(2)-O(1) bond length is 1.64 Å. The W(2)-O(12) bond length is 2.07 Å. The W(2)-O(2) bond length is 2.61 Å. In the third W site, W(3) is bonded in a distorted single-bond geometry to one O(1) and one O(11) atom. The W(3)-O(1) bond length is 1.47 Å. The W(3)-O(11) bond length is 1.78 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 1-coordinate geometry to one O(10), one O(3), and one O(9) atom. The P(1)-O(10) bond length is 2.21 Å. The P(1)-O(3) bond length is 1.89 Å. The P(1)-O(9) bond length is 1.39 Å. In the second P site, P(2) is bonded in a distorted T-shaped geometry to one Li(1), one O(3), and one O(5) atom. The P(2)-O(3) bond length is 1.22 Å. The P(2)-O(5) bond length is 1.02 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one W(2) and one W(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one W(1) and one W(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(2) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one P(2) atom. In the fifth O site, O(9) is bonded in a single-bond geometry to one P(1) atom. In the sixth O site, O(10) is bonded in a single-bond geometry to one P(1) atom. In the seventh O site, O(11) is bonded in a distorted single-bond geometry to one W(3) atom. In the eighth O site, O(12) is bonded in a single-bond geometry to one W(2) atom. In the ninth O site, O(14) is bonded in a 3-coordinate geometry to one Li(1), one W(1), and one O(15) atom. The O(14)-O(15) bond length is 1.53 Å. In the tenth O site, O(15) is bonded in a single-bond geometry to one W(1) and one O(14) atom.