data_ScFeBi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.08
_cell_length_b   6.08
_cell_length_c   6.08
_cell_angle_alpha   148.93
_cell_angle_beta   148.93
_cell_angle_gamma   44.51
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScFeBi
_chemical_formula_sum   'Sc1 Fe1 Bi1'
_cell_volume   59.78
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc2  1  0.0  0.0  0.85  1.0
  Fe  Fe1  1  0.0  0.0  0.71  1.0
  Bi  Bi0  1  0.0  0.0  0.96  1.0

data_ScFeBi
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.61
_cell_length_b   4.61
_cell_length_c   6.08
_cell_angle_alpha   90.0
_cell_angle_beta   112.26
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ScFeBi
_chemical_formula_sum   'Sc2 Fe2 Bi2'
_cell_volume   119.56
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  2  0.35  0.5  0.85  1.0
  Fe  Fe1  2  0.21  0.5  0.71  1.0
  Bi  Bi2  2  0.46  0.5  0.96  1.0

Sc Fe Bi
ScFeBi is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ScFeBi clusters. Sc(1) is bonded in a linear geometry to one Fe(1) and one Bi(1) atom. The Sc(1)-Fe(1) bond length is 0.84 Å. The Sc(1)-Bi(1) bond length is 0.66 Å. Fe(1) is bonded in a single-bond geometry to one Sc(1) atom. Bi(1) is bonded in a single-bond geometry to one Sc(1) atom.