data_Mn2BiMo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.71
_cell_length_b   4.71
_cell_length_c   3.19
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   107.28
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mn2BiMo
_chemical_formula_sum   'Mn2 Bi1 Mo1'
_cell_volume   67.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn1  1  0.4  0.1  0.59  1.0
  Mn  Mn2  1  0.4  0.9  0.59  1.0
  Bi  Bi0  1  0.8  0.0  0.0  1.0
  Mo  Mo3  1  0.0  0.0  0.0  1.0

data_Mn2BiMo
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.19
_cell_length_b   4.71
_cell_length_c   4.71
_cell_angle_alpha   107.28
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mn2BiMo
_chemical_formula_sum   'Mn2 Bi1 Mo1'
_cell_volume   67.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.59  0.4  0.1  1.0
  Mn  Mn1  1  0.59  0.4  0.9  1.0
  Bi  Bi2  1  0.0  0.8  0.0  1.0
  Mo  Mo3  1  0.0  0.0  0.0  1.0

Mn Mn Bi Mo
(Mn)2BiMo crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one manganese molecule and one BiMo cluster. In the BiMo cluster, Mo(1) is bonded in a 1-coordinate geometry to one Bi(1) atom. The Mo(1)-Bi(1) bond length is 0.97 Å. Bi(1) is bonded in a 1-coordinate geometry to one Mo(1) atom.