data_V3Te
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.12
_cell_length_b   4.12
_cell_length_c   3.55
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V3Te
_chemical_formula_sum   'V3 Te1'
_cell_volume   60.43
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V1  1  0.0  0.06  0.78  1.0
  V  V2  1  0.06  0.0  0.78  1.0
  V  V3  1  0.0  0.0  0.0  1.0
  Te  Te0  1  0.06  0.06  0.0  1.0

data_V3Te
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.83
_cell_length_b   5.83
_cell_length_c   3.55
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   V3Te
_chemical_formula_sum   'V6 Te2'
_cell_volume   120.85
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  4  0.03  0.03  0.78  1.0
  V  V1  2  0.0  0.0  0.0  1.0
  Te  Te2  2  0.06  0.0  0.0  1.0

V V V Te
(V)2TeV crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two vanadium molecules and two TeV clusters. In each TeV cluster, V(2) is bonded in a single-bond geometry to one Te(1) atom. The V(2)-Te(1) bond length is 0.36 Å. Te(1) is bonded in a single-bond geometry to one V(2) atom.