data_Zr2CdOs
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.28
_cell_length_b   3.35
_cell_length_c   7.14
_cell_angle_alpha   90.0
_cell_angle_beta   92.23
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zr2CdOs
_chemical_formula_sum   'Zr2 Cd1 Os1'
_cell_volume   78.34
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr2  1  0.41  0.68  0.17  1.0
  Zr  Zr3  1  0.59  0.68  0.96  1.0
  Cd  Cd0  1  0.0  0.0  0.0  1.0
  Os  Os1  1  0.86  0.0  0.57  1.0

data_Zr2CdOs
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.28
_cell_length_b   3.35
_cell_length_c   7.14
_cell_angle_alpha   90.0
_cell_angle_beta   92.23
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zr2CdOs
_chemical_formula_sum   'Zr2 Cd1 Os1'
_cell_volume   78.34
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.41  0.68  0.17  1.0
  Zr  Zr1  1  0.59  0.68  0.96  1.0
  Cd  Cd2  1  0.0  0.0  0.0  1.0
  Os  Os3  1  0.86  0.0  0.57  1.0

Zr Zr Cd Os
Zr2OsCd crystallizes in the triclinic P1 space group. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 2-coordinate geometry to one Zr(2), three equivalent Os(1), and one Cd(1) atom. The Zr(1)-Zr(2) bond length is 1.63 Å. There are a spread of Zr(1)-Os(1) bond distances ranging from 3.33-3.88 Å. The Zr(1)-Cd(1) bond length is 2.07 Å. In the second Zr site, Zr(2) is bonded in a 1-coordinate geometry to one Zr(1), three equivalent Os(1), and one Cd(1) atom. There are a spread of Zr(2)-Os(1) bond distances ranging from 3.19-3.80 Å. The Zr(2)-Cd(1) bond length is 1.73 Å. Os(1) is bonded in a 11-coordinate geometry to three equivalent Zr(1), three equivalent Zr(2), four equivalent Os(1), and one Cd(1) atom. There are two shorter (3.28 Å) and two longer (3.35 Å) Os(1)-Os(1) bond lengths. The Os(1)-Cd(1) bond length is 3.11 Å. Cd(1) is bonded in a 1-coordinate geometry to one Zr(1), one Zr(2), and one Os(1) atom.