data_ScBi2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.05
_cell_length_b   7.05
_cell_length_c   5.64
_cell_angle_alpha   103.93
_cell_angle_beta   103.93
_cell_angle_gamma   27.72
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScBi2Cl
_chemical_formula_sum   'Sc1 Bi2 Cl1'
_cell_volume   126.31
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc3  1  0.22  0.0  0.49  1.0
  Bi  Bi0  1  0.98  0.0  0.22  1.0
  Bi  Bi1  1  0.19  0.0  0.22  1.0
  Cl  Cl2  1  0.05  0.0  0.26  1.0

data_ScBi2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.38
_cell_length_b   5.64
_cell_length_c   7.05
_cell_angle_alpha   103.93
_cell_angle_beta   103.86
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScBi2Cl
_chemical_formula_sum   'Sc1 Bi2 Cl1'
_cell_volume   126.31
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.0  0.49  0.22  1.0
  Bi  Bi1  1  0.0  0.22  0.98  1.0
  Bi  Bi2  1  0.0  0.22  0.19  1.0
  Cl  Cl3  1  0.0  0.26  0.05  1.0

Sc Bi Bi Cl
ScBi2Cl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ScBi2Cl cluster. Sc(1) is bonded in a 2-coordinate geometry to one Bi(2) and one Cl(1) atom. The Sc(1)-Bi(2) bond length is 1.50 Å. The Sc(1)-Cl(1) bond length is 1.53 Å. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a single-bond geometry to one Cl(1) atom. The Bi(1)-Cl(1) bond length is 0.49 Å. In the second Bi site, Bi(2) is bonded in a single-bond geometry to one Sc(1) and one Cl(1) atom. The Bi(2)-Cl(1) bond length is 1.08 Å. Cl(1) is bonded in a 2-coordinate geometry to one Sc(1), one Bi(1), and one Bi(2) atom.