data_InPCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.41
_cell_length_b   5.41
_cell_length_c   5.41
_cell_angle_alpha   131.6
_cell_angle_beta   131.6
_cell_angle_gamma   70.86
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InPCl2
_chemical_formula_sum   'In1 P1 Cl2'
_cell_volume   86.63
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In2  1  0.0  0.0  0.41  1.0
  P  P3  1  0.0  0.0  0.0  1.0
  Cl  Cl0  1  0.22  0.0  0.2  1.0
  Cl  Cl1  1  0.0  0.22  0.2  1.0

data_InPCl2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.27
_cell_length_b   6.27
_cell_length_c   5.41
_cell_angle_alpha   90.0
_cell_angle_beta   125.43
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   InPCl2
_chemical_formula_sum   'In2 P2 Cl4'
_cell_volume   173.25
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  0.0  0.0  0.41  1.0
  P  P1  2  0.0  0.0  0.0  1.0
  Cl  Cl2  4  0.39  0.39  0.99  1.0

In P Cl Cl
InPCl2 is Indium-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two InPCl2 clusters. In(1) is bonded in a 2-coordinate geometry to two equivalent Cl(1) atoms. Both In(1)-Cl(1) bond lengths are 2.07 Å. P(1) is bonded in an L-shaped geometry to two equivalent Cl(1) atoms. Both P(1)-Cl(1) bond lengths are 0.93 Å. Cl(1) is bonded in a single-bond geometry to one In(1) and one P(1) atom.