data_Cd2PtCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.1
_cell_length_b   4.1
_cell_length_c   8.14
_cell_angle_alpha   109.76
_cell_angle_beta   109.76
_cell_angle_gamma   46.72
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2PtCl
_chemical_formula_sum   'Cd2 Pt1 Cl1'
_cell_volume   92.82
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.99  0.0  0.41  1.0
  Cd  Cd1  1  0.54  0.0  0.16  1.0
  Pt  Pt3  1  0.27  0.0  0.78  1.0
  Cl  Cl2  1  0.0  0.0  0.0  1.0

data_Cd2PtCl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.25
_cell_length_b   4.1
_cell_length_c   7.78
_cell_angle_alpha   79.99
_cell_angle_beta   77.93
_cell_angle_gamma   66.64
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2PtCl
_chemical_formula_sum   'Cd2 Pt1 Cl1'
_cell_volume   92.82
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.39  0.16  1.0
  Cd  Cd1  1  0.0  0.58  0.41  1.0
  Pt  Pt2  1  0.0  0.48  0.78  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Cd Cd Pt Cl
PtCd2Cl crystallizes in the triclinic P1 space group. Pt(1) is bonded in a 4-coordinate geometry to one Cd(1), one Cd(2), and two equivalent Cl(1) atoms. The Pt(1)-Cd(1) bond length is 2.85 Å. The Pt(1)-Cd(2) bond length is 2.85 Å. There is one shorter (2.37 Å) and one longer (2.92 Å) Pt(1)-Cl(1) bond length. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted bent 150 degrees geometry to one Pt(1) and one Cd(2) atom. The Cd(1)-Cd(2) bond length is 2.28 Å. In the second Cd site, Cd(2) is bonded in a distorted bent 120 degrees geometry to one Pt(1), one Cd(1), and three equivalent Cl(1) atoms. There are a spread of Cd(2)-Cl(1) bond distances ranging from 2.16-3.08 Å. Cl(1) is bonded in a 5-coordinate geometry to two equivalent Pt(1) and three equivalent Cd(2) atoms.