data_Bi5Pd3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.51
_cell_length_b   6.51
_cell_length_c   4.67
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   97.97
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Bi5Pd3
_chemical_formula_sum   'Bi5 Pd3'
_cell_volume   196.02
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.27  0.0  0.0  1.0
  Bi  Bi1  1  0.14  0.54  0.0  1.0
  Bi  Bi2  1  0.14  0.46  0.0  1.0
  Bi  Bi3  1  0.82  0.0  0.34  1.0
  Bi  Bi4  1  0.72  0.0  0.34  1.0
  Pd  Pd5  1  0.0  0.0  0.0  1.0
  Pd  Pd6  1  0.27  0.47  0.34  1.0
  Pd  Pd7  1  0.27  0.53  0.34  1.0

data_Bi5Pd3
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.67
_cell_length_b   6.51
_cell_length_c   6.51
_cell_angle_alpha   97.97
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Bi5Pd3
_chemical_formula_sum   'Bi5 Pd3'
_cell_volume   196.02
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.0  0.14  0.54  1.0
  Bi  Bi1  1  0.0  0.14  0.46  1.0
  Bi  Bi2  1  0.0  0.27  0.0  1.0
  Bi  Bi3  1  0.34  0.72  0.0  1.0
  Bi  Bi4  1  0.34  0.82  0.0  1.0
  Pd  Pd5  1  0.0  0.0  0.0  1.0
  Pd  Pd6  1  0.34  0.27  0.47  1.0
  Pd  Pd7  1  0.34  0.27  0.53  1.0

Bi Bi Bi Bi Bi Pd Pd Pd
PdBi3(PdBi)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one PdBi cluster and one PdBi3 cluster. In the PdBi cluster, there are two inequivalent Pd sites. In the first Pd site, Pd(2) is bonded in a 1-coordinate geometry to one Pd(3) atom. The Pd(2)-Pd(3) bond length is 0.36 Å. In the second Pd site, Pd(3) is bonded in a distorted single-bond geometry to one Pd(2) and one Bi(2) atom. The Pd(3)-Bi(2) bond length is 1.81 Å. There are two inequivalent Bi sites. In the first Bi site, Bi(2) is bonded in a 2-coordinate geometry to one Pd(3) and one Bi(3) atom. The Bi(2)-Bi(3) bond length is 0.58 Å. In the second Bi site, Bi(3) is bonded in a 1-coordinate geometry to one Bi(2) atom. In the PdBi3 cluster, Pd(1) is bonded in a distorted bent 120 degrees geometry to one Bi(1) and one Bi(4) atom. The Pd(1)-Bi(1) bond length is 1.77 Å. The Pd(1)-Bi(4) bond length is 1.96 Å. There are three inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a single-bond geometry to one Pd(1) atom. In the second Bi site, Bi(4) is bonded in a distorted bent 120 degrees geometry to one Pd(1) and one Bi(5) atom. The Bi(4)-Bi(5) bond length is 0.62 Å. In the third Bi site, Bi(5) is bonded in a single-bond geometry to one Bi(4) atom.