data_In2CoBi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.42
_cell_length_b   5.42
_cell_length_c   3.46
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   111.88
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In2CoBi
_chemical_formula_sum   'In2 Co1 Bi1'
_cell_volume   94.07
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In2  1  0.52  0.24  0.73  1.0
  In  In3  1  0.52  0.76  0.73  1.0
  Co  Co1  1  0.0  0.0  0.0  1.0
  Bi  Bi0  1  0.03  0.0  0.0  1.0

data_In2CoBi
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.46
_cell_length_b   5.42
_cell_length_c   5.42
_cell_angle_alpha   111.88
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In2CoBi
_chemical_formula_sum   'In2 Co1 Bi1'
_cell_volume   94.07
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.73  0.52  0.24  1.0
  In  In1  1  0.73  0.52  0.76  1.0
  Co  Co2  1  0.0  0.0  0.0  1.0
  Bi  Bi3  1  0.0  0.03  0.0  1.0

In In Co Bi
CoIn2Bi crystallizes in the triclinic P1 space group. Co(1) is bonded in a single-bond geometry to two equivalent In(2) and one Bi(1) atom. There is one shorter (2.63 Å) and one longer (3.51 Å) Co(1)-In(2) bond length. The Co(1)-Bi(1) bond length is 0.18 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 1-coordinate geometry to two equivalent In(2) and one Bi(1) atom. There is one shorter (2.64 Å) and one longer (2.78 Å) In(1)-In(2) bond length. The In(1)-Bi(1) bond length is 2.63 Å. In the second In site, In(2) is bonded in a 7-coordinate geometry to two equivalent Co(1), two equivalent In(1), two equivalent In(2), and one Bi(1) atom. Both In(2)-In(2) bond lengths are 3.46 Å. The In(2)-Bi(1) bond length is 3.47 Å. Bi(1) is bonded in a single-bond geometry to one Co(1), one In(1), and one In(2) atom.