data_ZrRh2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.98
_cell_length_b   4.98
_cell_length_c   4.98
_cell_angle_alpha   131.85
_cell_angle_beta   131.85
_cell_angle_gamma   70.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrRh2Cl
_chemical_formula_sum   'Zr1 Rh2 Cl1'
_cell_volume   66.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr3  1  0.0  0.03  0.03  1.0
  Rh  Rh1  1  0.03  0.0  0.03  1.0
  Rh  Rh2  1  0.0  0.0  0.06  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_ZrRh2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.06
_cell_length_b   4.06
_cell_length_c   4.98
_cell_angle_alpha   114.08
_cell_angle_beta   114.08
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrRh2Cl
_chemical_formula_sum   'Zr1 Rh2 Cl1'
_cell_volume   66.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.0  0.03  0.0  1.0
  Rh  Rh1  1  0.03  0.0  0.0  1.0
  Rh  Rh2  1  0.06  0.06  0.06  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Zr Rh Rh Cl
ZrRh2Cl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ZrRh2Cl cluster. Zr(1) is bonded in a distorted single-bond geometry to one Rh(2) and one Cl(1) atom. The Zr(1)-Rh(2) bond length is 0.28 Å. The Zr(1)-Cl(1) bond length is 0.13 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted single-bond geometry to one Cl(1) atom. The Rh(1)-Cl(1) bond length is 0.13 Å. In the second Rh site, Rh(2) is bonded in a distorted single-bond geometry to one Zr(1) atom. Cl(1) is bonded in an L-shaped geometry to one Zr(1) and one Rh(1) atom.