data_VRePd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.71
_cell_length_b   2.71
_cell_length_c   8.01
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VRePd2
_chemical_formula_sum   'V1 Re1 Pd2'
_cell_volume   58.69
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.04  1.0
  Re  Re2  1  0.35  0.35  0.02  1.0
  Pd  Pd0  1  0.35  0.35  0.89  1.0
  Pd  Pd1  1  0.0  0.0  0.06  1.0

data_VRePd2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.83
_cell_length_b   3.83
_cell_length_c   8.01
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VRePd2
_chemical_formula_sum   'V2 Re2 Pd4'
_cell_volume   117.39
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.04  1.0
  Re  Re1  2  0.35  0.0  0.02  1.0
  Pd  Pd2  2  0.0  0.0  0.06  1.0
  Pd  Pd3  2  0.35  0.0  0.89  1.0

V Re Pd Pd
VPdPdRe crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two palladium;vanadium molecules and two PdRe clusters. In each PdRe cluster, Re(1) is bonded in a distorted single-bond geometry to one Pd(1) atom. The Re(1)-Pd(1) bond length is 0.99 Å. Pd(1) is bonded in a single-bond geometry to one Re(1) atom.