data_HfGeP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.52
_cell_length_b   3.79
_cell_length_c   5.24
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   HfGeP2
_chemical_formula_sum   'Hf1 Ge1 P2'
_cell_volume   69.82
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf1  1  0.76  0.89  0.0  1.0
  Ge  Ge0  1  0.76  0.0  0.62  1.0
  P  P2  1  0.0  0.89  0.62  1.0
  P  P3  1  0.0  0.0  0.0  1.0

data_HfGeP2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.52
_cell_length_b   3.79
_cell_length_c   5.24
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   HfGeP2
_chemical_formula_sum   'Hf1 Ge1 P2'
_cell_volume   69.82
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.76  0.89  -0.0  1.0
  Ge  Ge1  1  0.76  0.0  0.62  1.0
  P  P2  1  0.0  0.0  0.0  1.0
  P  P3  1  0.0  0.89  0.62  1.0

Hf Ge P P
HfPGeP is High Pressure Cadmuum Telluride structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one phosphanylidynegermanium molecule and one HfP cluster. In the HfP cluster, Hf(1) is bonded in a single-bond geometry to one P(2) atom. The Hf(1)-P(2) bond length is 0.94 Å. P(2) is bonded in a single-bond geometry to one Hf(1) atom.