data_VAgW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.85
_cell_length_b   4.85
_cell_length_c   5.14
_cell_angle_alpha   95.66
_cell_angle_beta   95.66
_cell_angle_gamma   31.91
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VAgW2
_chemical_formula_sum   'V1 Ag1 W2'
_cell_volume   63.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V1  1  0.91  0.0  0.82  1.0
  Ag  Ag0  1  0.4  0.0  0.6  1.0
  W  W2  1  0.32  0.0  0.0  1.0
  W  W3  1  0.9  0.0  0.25  1.0

data_VAgW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.67
_cell_length_b   4.85
_cell_length_c   5.14
_cell_angle_alpha   95.66
_cell_angle_beta   90.0
_cell_angle_gamma   105.95
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VAgW2
_chemical_formula_sum   'V1 Ag1 W2'
_cell_volume   63.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.09  0.18  1.0
  Ag  Ag1  1  0.0  0.6  0.4  1.0
  W  W2  1  0.0  0.1  0.75  1.0
  W  W3  1  0.0  0.68  1.0  1.0

V Ag W W
VW2Ag crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VW2Ag cluster. V(1) is bonded in a 2-coordinate geometry to one W(1) and one W(2) atom. The V(1)-W(1) bond length is 2.12 Å. The V(1)-W(2) bond length is 2.22 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 2-coordinate geometry to one V(1) and one Ag(1) atom. The W(1)-Ag(1) bond length is 2.16 Å. In the second W site, W(2) is bonded in a distorted single-bond geometry to one V(1) atom. Ag(1) is bonded in a 1-coordinate geometry to one W(1) atom.