data_Cr2SiPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.64
_cell_length_b   4.64
_cell_length_c   2.66
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   116.97
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cr2SiPd
_chemical_formula_sum   'Cr2 Si1 Pd1'
_cell_volume   51.02
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.21  0.98  0.33  1.0
  Cr  Cr1  1  0.21  0.02  0.33  1.0
  Si  Si3  1  0.0  0.0  0.0  1.0
  Pd  Pd2  1  0.43  0.0  0.0  1.0

data_Cr2SiPd
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.66
_cell_length_b   4.64
_cell_length_c   4.64
_cell_angle_alpha   116.97
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cr2SiPd
_chemical_formula_sum   'Cr2 Si1 Pd1'
_cell_volume   51.02
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.33  0.21  0.98  1.0
  Cr  Cr1  1  0.33  0.21  0.02  1.0
  Si  Si2  1  0.0  0.0  0.0  1.0
  Pd  Pd3  1  -0.0  0.43  0.0  1.0

Cr Cr Si Pd
Cr2PdSi crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Cr2PdSi cluster. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a single-bond geometry to one Cr(2) and one Pd(1) atom. The Cr(1)-Cr(2) bond length is 0.21 Å. The Cr(1)-Pd(1) bond length is 1.29 Å. In the second Cr site, Cr(2) is bonded in a single-bond geometry to one Cr(1) and one Si(1) atom. The Cr(2)-Si(1) bond length is 1.29 Å. Pd(1) is bonded in a distorted single-bond geometry to one Cr(1) atom. Si(1) is bonded in a distorted single-bond geometry to one Cr(2) atom.