data_FePd2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.74
_cell_length_b   2.74
_cell_length_c   7.83
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   FePd2W
_chemical_formula_sum   'Fe1 Pd2 W1'
_cell_volume   58.91
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.0  0.0  0.0  1.0
  Pd  Pd1  1  0.37  0.37  0.89  1.0
  Pd  Pd2  1  0.37  0.37  0.94  1.0
  W  W3  1  0.0  0.0  0.91  1.0

data_FePd2W
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.88
_cell_length_b   3.88
_cell_length_c   7.83
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   FePd2W
_chemical_formula_sum   'Fe2 Pd4 W2'
_cell_volume   117.82
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  2  0.0  0.0  0.0  1.0
  Pd  Pd1  2  0.37  0.0  0.89  1.0
  Pd  Pd2  2  0.37  0.0  0.94  1.0
  W  W3  2  0.0  0.0  0.91  1.0

Fe Pd Pd W
FeW(Pd)2 is alpha oxygen-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two FeW clusters and two Pd clusters. In each FeW cluster, W(1) is bonded in a single-bond geometry to one Fe(1) atom. The W(1)-Fe(1) bond length is 0.67 Å. Fe(1) is bonded in a single-bond geometry to one W(1) atom. In each Pd cluster, there are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a single-bond geometry to one Pd(2) atom. The Pd(1)-Pd(2) bond length is 0.37 Å. In the second Pd site, Pd(2) is bonded in a single-bond geometry to one Pd(1) atom.