data_Li2TcOs
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.64
_cell_length_b   4.16
_cell_length_c   5.33
_cell_angle_alpha   90.0
_cell_angle_beta   100.25
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2TcOs
_chemical_formula_sum   'Li2 Tc1 Os1'
_cell_volume   57.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.97  0.08  0.19  1.0
  Li  Li1  1  0.75  0.0  0.16  1.0
  Tc  Tc3  1  0.81  0.0  0.69  1.0
  Os  Os2  1  0.01  0.08  0.83  1.0

data_Li2TcOs
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.64
_cell_length_b   4.16
_cell_length_c   5.33
_cell_angle_alpha   90.0
_cell_angle_beta   100.25
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2TcOs
_chemical_formula_sum   'Li2 Tc1 Os1'
_cell_volume   57.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.75  0.0  0.16  1.0
  Li  Li1  1  0.97  0.08  0.19  1.0
  Tc  Tc2  1  0.81  0.0  0.69  1.0
  Os  Os3  1  0.01  0.08  0.83  1.0

Li Li Tc Os
Li2TcOs crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Li2TcOs cluster. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted L-shaped geometry to one Li(2) and one Os(1) atom. The Li(1)-Li(2) bond length is 0.68 Å. The Li(1)-Os(1) bond length is 1.90 Å. In the second Li site, Li(2) is bonded in a 1-coordinate geometry to one Li(1) atom. Tc(1) is bonded in a single-bond geometry to one Os(1) atom. The Tc(1)-Os(1) bond length is 0.93 Å. Os(1) is bonded in a 1-coordinate geometry to one Li(1) and one Tc(1) atom.