data_CoCuAgBi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.65
_cell_length_b   4.65
_cell_length_c   4.65
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CoCuAgBi
_chemical_formula_sum   'Co1 Cu1 Ag1 Bi1'
_cell_volume   70.91
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co2  1  0.0  0.0  0.0  1.0
  Cu  Cu3  1  0.64  0.64  0.64  1.0
  Ag  Ag0  1  0.93  0.93  0.93  1.0
  Bi  Bi1  1  0.29  0.29  0.29  1.0

data_CoCuAgBi
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.65
_cell_length_b   4.65
_cell_length_c   11.38
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   CoCuAgBi
_chemical_formula_sum   'Co3 Cu3 Ag3 Bi3'
_cell_volume   212.74
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  3  0.0  0.0  0.0  1.0
  Cu  Cu1  3  0.0  0.0  0.36  1.0
  Ag  Ag2  3  0.0  0.0  0.07  1.0
  Bi  Bi3  3  0.0  0.0  0.71  1.0

Co Cu Ag Bi
CoAgCuBi crystallizes in the trigonal R3m space group. Co(1) is bonded in a single-bond geometry to one Ag(1), three equivalent Cu(1), and four equivalent Bi(1) atoms. The Co(1)-Ag(1) bond length is 0.82 Å. All Co(1)-Cu(1) bond lengths are 2.70 Å. There are three shorter (2.74 Å) and one longer (3.25 Å) Co(1)-Bi(1) bond length. Ag(1) is bonded in a single-bond geometry to one Co(1), four equivalent Cu(1), and three equivalent Bi(1) atoms. There are three shorter (2.74 Å) and one longer (3.25 Å) Ag(1)-Cu(1) bond length. All Ag(1)-Bi(1) bond lengths are 2.70 Å. Cu(1) is bonded in a 10-coordinate geometry to three equivalent Co(1), four equivalent Ag(1), and three equivalent Bi(1) atoms. All Cu(1)-Bi(1) bond lengths are 2.70 Å. Bi(1) is bonded in a distorted q6 geometry to four equivalent Co(1), three equivalent Ag(1), and three equivalent Cu(1) atoms.