data_Ag2AsRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.52
_cell_length_b   5.52
_cell_length_c   5.52
_cell_angle_alpha   146.12
_cell_angle_beta   133.97
_cell_angle_gamma   58.37
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ag2AsRh
_chemical_formula_sum   'Ag2 As1 Rh1'
_cell_volume   66.85
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.61  0.0  0.27  1.0
  Ag  Ag1  1  0.0  0.16  0.54  1.0
  As  As2  1  0.0  0.0  0.0  1.0
  Rh  Rh3  1  0.0  0.0  0.82  1.0

data_Ag2AsRh
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.22
_cell_length_b   4.31
_cell_length_c   5.52
_cell_angle_alpha   113.01
_cell_angle_beta   106.94
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ag2AsRh
_chemical_formula_sum   'Ag2 As1 Rh1'
_cell_volume   66.85
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.33  0.73  0.33  1.0
  Ag  Ag1  1  0.46  0.61  0.61  1.0
  As  As2  1  0.0  0.0  0.0  1.0
  Rh  Rh3  1  0.18  0.18  0.18  1.0

Ag Ag As Rh
RhAg2As crystallizes in the triclinic P1 space group. Rh(1) is bonded in a distorted single-bond geometry to one Ag(2), two equivalent Ag(1), and one As(1) atom. The Rh(1)-Ag(2) bond length is 2.28 Å. There is one shorter (2.16 Å) and one longer (2.42 Å) Rh(1)-Ag(1) bond length. The Rh(1)-As(1) bond length is 1.01 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent Rh(1), one Ag(2), and one As(1) atom. The Ag(1)-Ag(2) bond length is 1.73 Å. The Ag(1)-As(1) bond length is 2.55 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one Rh(1), one Ag(1), and two equivalent As(1) atoms. There is one shorter (2.34 Å) and one longer (2.92 Å) Ag(2)-As(1) bond length. As(1) is bonded in a distorted single-bond geometry to one Rh(1), one Ag(1), and two equivalent Ag(2) atoms.