data_In24Tc5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.77
_cell_length_b   9.77
_cell_length_c   9.77
_cell_angle_alpha   109.47
_cell_angle_beta   109.47
_cell_angle_gamma   109.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In24Tc5
_chemical_formula_sum   'In24 Tc5'
_cell_volume   718.63
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.13  0.03  0.97  1.0
  In  In1  1  0.13  0.97  0.03  1.0
  In  In2  1  0.51  0.61  0.61  1.0
  In  In3  1  0.15  0.03  0.03  1.0
  In  In4  1  0.61  0.51  0.61  1.0
  In  In5  1  0.03  0.15  0.03  1.0
  In  In6  1  0.97  0.13  0.03  1.0
  In  In7  1  0.03  0.13  0.97  1.0
  In  In8  1  0.97  0.03  0.13  1.0
  In  In9  1  0.03  0.97  0.13  1.0
  In  In10  1  0.03  0.03  0.15  1.0
  In  In11  1  0.61  0.61  0.51  1.0
  In  In12  1  0.85  0.41  0.59  1.0
  In  In13  1  0.85  0.59  0.41  1.0
  In  In14  1  0.44  0.59  0.59  1.0
  In  In15  1  0.79  0.06  0.06  1.0
  In  In16  1  0.59  0.44  0.59  1.0
  In  In17  1  0.06  0.79  0.06  1.0
  In  In18  1  0.59  0.85  0.41  1.0
  In  In19  1  0.41  0.85  0.59  1.0
  In  In20  1  0.59  0.41  0.85  1.0
  In  In21  1  0.41  0.59  0.85  1.0
  In  In22  1  0.06  0.06  0.79  1.0
  In  In23  1  0.59  0.59  0.44  1.0
  Tc  Tc24  1  0.4  0.6  0.4  1.0
  Tc  Tc25  1  0.4  0.4  0.6  1.0
  Tc  Tc26  1  0.6  0.4  0.4  1.0
  Tc  Tc27  1  0.25  0.25  0.25  1.0
  Tc  Tc28  1  0.0  0.0  0.0  1.0

data_In24Tc5
_symmetry_space_group_name_H-M   R3m
_cell_length_a   15.96
_cell_length_b   15.96
_cell_length_c   9.77
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   In24Tc5
_chemical_formula_sum   'In72 Tc15'
_cell_volume   2155.9
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+2/3, y+1/3, z+1/3'
  8  '-y+2/3, x-y+1/3, z+1/3'
  9  '-x+y+2/3, -x+1/3, z+1/3'
  10  '-y+2/3, -x+1/3, z+1/3'
  11  '-x+y+2/3, y+1/3, z+1/3'
  12  'x+2/3, x-y+1/3, z+1/3'
  13  'x+1/3, y+2/3, z+2/3'
  14  '-y+1/3, x-y+2/3, z+2/3'
  15  '-x+y+1/3, -x+2/3, z+2/3'
  16  '-y+1/3, -x+2/3, z+2/3'
  17  '-x+y+1/3, y+2/3, z+2/3'
  18  'x+1/3, x-y+2/3, z+2/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  18  0.09  0.01  0.04  1.0
  In  In1  18  0.13  0.43  0.28  1.0
  In  In2  9  0.03  0.97  0.58  1.0
  In  In3  9  0.05  0.95  0.54  1.0
  In  In4  9  0.08  0.04  0.07  1.0
  In  In5  9  0.09  0.17  0.97  1.0
  Tc  Tc6  9  0.14  0.07  0.47  1.0
  Tc  Tc7  3  0.0  0.0  0.0  1.0
  Tc  Tc8  3  0.0  0.0  0.25  1.0

In In In In In In In In In In In In In In In In In In In In In In In In Tc Tc Tc Tc Tc
Tc5In24 is Tungsten structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three Tc5In24 clusters. There are three inequivalent Tc sites. In the first Tc site, Tc(1) is bonded in a 7-coordinate geometry to one Tc(2), two equivalent In(2), two equivalent In(4), and two equivalent In(5) atoms. The Tc(1)-Tc(2) bond length is 2.87 Å. Both Tc(1)-In(2) bond lengths are 1.99 Å. Both Tc(1)-In(4) bond lengths are 2.40 Å. Both Tc(1)-In(5) bond lengths are 1.86 Å. In the second Tc site, Tc(2) is bonded in a 3-coordinate geometry to three equivalent Tc(1) and three equivalent In(3) atoms. All Tc(2)-In(3) bond lengths are 2.04 Å. In the third Tc site, Tc(3) is bonded in a 9-coordinate geometry to three equivalent In(3) and six equivalent In(1) atoms. All Tc(3)-In(3) bond lengths are 1.31 Å. All Tc(3)-In(1) bond lengths are 1.40 Å. There are six inequivalent In sites. In the first In site, In(1) is bonded in a distorted single-bond geometry to one Tc(3), one In(3), and one In(6) atom. The In(1)-In(3) bond length is 0.59 Å. The In(1)-In(6) bond length is 1.73 Å. In the second In site, In(2) is bonded in a single-bond geometry to two equivalent Tc(1) and one In(5) atom. The In(2)-In(5) bond length is 0.59 Å. In the third In site, In(3) is bonded in a 3-coordinate geometry to one Tc(2), one Tc(3), and two equivalent In(1) atoms. In the fourth In site, In(4) is bonded in a distorted single-bond geometry to one Tc(1) atom. In the fifth In site, In(5) is bonded in a single-bond geometry to two equivalent Tc(1) and one In(2) atom. In the sixth In site, In(6) is bonded in a 2-coordinate geometry to two equivalent In(1) atoms.