data_NbInCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.72
_cell_length_b   6.72
_cell_length_c   6.72
_cell_angle_alpha   153.3
_cell_angle_beta   153.3
_cell_angle_gamma   38.12
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NbInCl
_chemical_formula_sum   'Nb1 In1 Cl1'
_cell_volume   61.13
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb2  1  0.0  0.0  0.42  1.0
  In  In1  1  0.0  0.0  0.72  1.0
  Cl  Cl0  1  0.0  0.0  0.26  1.0

data_NbInCl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.39
_cell_length_b   4.39
_cell_length_c   6.72
_cell_angle_alpha   90.0
_cell_angle_beta   109.06
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   NbInCl
_chemical_formula_sum   'Nb2 In2 Cl2'
_cell_volume   122.26
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  2  0.42  0.0  0.42  1.0
  In  In1  2  0.22  0.5  0.72  1.0
  Cl  Cl2  2  0.26  0.0  0.26  1.0

Nb In Cl
NbInCl crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two NbInCl clusters. Nb(1) is bonded in a single-bond geometry to one In(1) and one Cl(1) atom. The Nb(1)-In(1) bond length is 2.04 Å. The Nb(1)-Cl(1) bond length is 1.05 Å. In(1) is bonded in a single-bond geometry to one Nb(1) atom. Cl(1) is bonded in a single-bond geometry to one Nb(1) atom.