data_KPdBr2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.39
_cell_length_b   7.39
_cell_length_c   7.39
_cell_angle_alpha   34.29
_cell_angle_beta   34.29
_cell_angle_gamma   34.29
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KPdBr2
_chemical_formula_sum   'K1 Pd1 Br2'
_cell_volume   114.07
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K2  1  0.0  0.0  0.45  1.0
  Pd  Pd3  1  0.0  0.0  0.82  1.0
  Br  Br0  1  0.0  0.0  0.56  1.0
  Br  Br1  1  0.0  0.0  0.26  1.0

data_KPdBr2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   7.54
_cell_length_b   4.35
_cell_length_c   7.39
_cell_angle_alpha   90.0
_cell_angle_beta   109.9
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   KPdBr2
_chemical_formula_sum   'K2 Pd2 Br4'
_cell_volume   228.13
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  2  0.0  0.0  0.55  1.0
  Pd  Pd1  2  0.0  0.0  0.18  1.0
  Br  Br2  2  0.0  0.0  0.44  1.0
  Br  Br3  2  0.0  0.0  0.74  1.0

K Pd Br Br
KPdBr2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two KPdBr2 clusters. K(1) is bonded in a linear geometry to one Br(1) and one Br(2) atom. The K(1)-Br(1) bond length is 0.77 Å. The K(1)-Br(2) bond length is 1.37 Å. Pd(1) is bonded in a single-bond geometry to one Br(1) atom. The Pd(1)-Br(1) bond length is 1.93 Å. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a distorted single-bond geometry to one K(1) and one Pd(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one K(1) atom.