data_RhW2Au
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.6
_cell_length_b   9.6
_cell_length_c   9.6
_cell_angle_alpha   16.83
_cell_angle_beta   16.83
_cell_angle_gamma   16.83
_symmetry_Int_Tables_number   1
_chemical_formula_structural   RhW2Au
_chemical_formula_sum   'Rh1 W2 Au1'
_cell_volume   64.73
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh1  1  0.0  0.0  0.17  1.0
  W  W2  1  0.0  0.0  0.11  1.0
  W  W3  1  0.0  0.0  0.13  1.0
  Au  Au0  1  0.0  0.0  0.16  1.0

data_RhW2Au
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.87
_cell_length_b   2.81
_cell_length_c   9.6
_cell_angle_alpha   90.0
_cell_angle_beta   99.73
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   RhW2Au
_chemical_formula_sum   'Rh2 W4 Au2'
_cell_volume   129.47
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  2  -0.0  0.0  0.83  1.0
  W  W1  2  -0.0  0.0  0.87  1.0
  W  W2  2  -0.0  0.0  0.89  1.0
  Au  Au3  2  -0.0  0.0  0.84  1.0

Rh W W Au
W2RhAu is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two W2RhAu clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded in a single-bond geometry to one W(2) atom. The W(1)-W(2) bond length is 0.17 Å. In the second W site, W(2) is bonded in a linear geometry to one W(1) and one Au(1) atom. The W(2)-Au(1) bond length is 0.29 Å. Rh(1) is bonded in a single-bond geometry to one Au(1) atom. The Rh(1)-Au(1) bond length is 0.08 Å. Au(1) is bonded in a linear geometry to one W(2) and one Rh(1) atom.