data_Zn2BiPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.21
_cell_length_b   3.38
_cell_length_c   7.09
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zn2BiPd
_chemical_formula_sum   'Zn2 Bi1 Pd1'
_cell_volume   77.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn2  1  0.61  0.69  0.31  1.0
  Zn  Zn3  1  0.61  0.69  0.78  1.0
  Bi  Bi0  1  0.0  0.0  0.55  1.0
  Pd  Pd1  1  0.0  0.0  0.0  1.0

data_Zn2BiPd
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.21
_cell_length_b   3.38
_cell_length_c   7.09
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zn2BiPd
_chemical_formula_sum   'Zn2 Bi1 Pd1'
_cell_volume   77.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.61  0.69  0.31  1.0
  Zn  Zn1  1  0.61  0.69  0.78  1.0
  Bi  Bi2  1  0.0  0.0  0.55  1.0
  Pd  Pd3  1  0.0  0.0  0.0  1.0

Zn Zn Bi Pd
PdZn2Bi crystallizes in the triclinic P1 space group. Pd(1) is bonded in a 5-coordinate geometry to two equivalent Zn(1) and three equivalent Zn(2) atoms. There is one shorter (2.76 Å) and one longer (3.13 Å) Pd(1)-Zn(1) bond length. There are a spread of Pd(1)-Zn(2) bond distances ranging from 2.27-3.09 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to two equivalent Pd(1) and three equivalent Bi(1) atoms. There are a spread of Zn(1)-Bi(1) bond distances ranging from 2.33-3.13 Å. In the second Zn site, Zn(2) is bonded in a 6-coordinate geometry to three equivalent Pd(1) and three equivalent Bi(1) atoms. There are a spread of Zn(2)-Bi(1) bond distances ranging from 2.33-3.13 Å. Bi(1) is bonded in a 6-coordinate geometry to three equivalent Zn(1) and three equivalent Zn(2) atoms.