data_CdTcTe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.58
_cell_length_b   4.58
_cell_length_c   4.58
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdTcTe
_chemical_formula_sum   'Cd1 Tc1 Te1'
_cell_volume   68.03
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.24  0.24  0.24  1.0
  Tc  Tc1  1  0.0  0.0  0.0  1.0
  Te  Te2  1  0.86  0.86  0.86  1.0

data_CdTcTe
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.58
_cell_length_b   4.58
_cell_length_c   11.22
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   CdTcTe
_chemical_formula_sum   'Cd3 Tc3 Te3'
_cell_volume   204.1
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  3  0.0  0.0  0.76  1.0
  Tc  Tc1  3  0.0  0.0  -0.0  1.0
  Te  Te2  3  0.0  0.0  0.14  1.0

Cd Tc Te
TcCdTe crystallizes in the trigonal R3m space group. Tc(1) is bonded in a distorted single-bond geometry to four equivalent Cd(1) and one Te(1) atom. There is one shorter (2.70 Å) and three longer (2.84 Å) Tc(1)-Cd(1) bond lengths. The Tc(1)-Te(1) bond length is 1.57 Å. Cd(1) is bonded to four equivalent Tc(1) and three equivalent Te(1) atoms to form a mixture of distorted corner and edge-sharing CdTc4Te3 hexagonal pyramids. All Cd(1)-Te(1) bond lengths are 2.70 Å. Te(1) is bonded in a distorted single-bond geometry to one Tc(1) and three equivalent Cd(1) atoms.