data_GaFe2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.73
_cell_length_b   4.73
_cell_length_c   4.2
_cell_angle_alpha   108.58
_cell_angle_beta   108.58
_cell_angle_gamma   36.06
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaFe2W
_chemical_formula_sum   'Ga1 Fe2 W1'
_cell_volume   51.99
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga2  1  0.82  0.0  0.13  1.0
  Fe  Fe0  1  0.92  0.0  0.09  1.0
  Fe  Fe1  1  0.26  0.0  0.87  1.0
  W  W3  1  0.37  0.0  0.85  1.0

data_GaFe2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.93
_cell_length_b   4.2
_cell_length_c   4.73
_cell_angle_alpha   108.58
_cell_angle_beta   108.03
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaFe2W
_chemical_formula_sum   'Ga1 Fe2 W1'
_cell_volume   51.99
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.0  0.13  0.82  1.0
  Fe  Fe1  1  0.0  0.09  0.92  1.0
  Fe  Fe2  1  0.0  0.87  0.26  1.0
  W  W3  1  0.0  0.85  0.37  1.0

Ga Fe Fe W
WFe2Ga crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one WFe2Ga cluster. W(1) is bonded in a distorted single-bond geometry to one Fe(2) and one Ga(1) atom. The W(1)-Fe(2) bond length is 0.59 Å. The W(1)-Ga(1) bond length is 2.05 Å. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a single-bond geometry to one Ga(1) atom. The Fe(1)-Ga(1) bond length is 0.54 Å. In the second Fe site, Fe(2) is bonded in a single-bond geometry to one W(1) atom. Ga(1) is bonded in a 2-coordinate geometry to one W(1) and one Fe(1) atom.