data_LiVRu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.91
_cell_length_b   4.91
_cell_length_c   4.91
_cell_angle_alpha   138.11
_cell_angle_beta   138.11
_cell_angle_gamma   60.73
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiVRu2
_chemical_formula_sum   'Li1 V1 Ru2'
_cell_volume   52.29
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.0  1.0
  V  V3  1  0.0  0.76  0.12  1.0
  Ru  Ru1  1  0.76  0.0  0.12  1.0
  Ru  Ru2  1  0.0  0.0  0.24  1.0

data_LiVRu2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.51
_cell_length_b   3.51
_cell_length_c   4.91
_cell_angle_alpha   110.94
_cell_angle_beta   110.94
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiVRu2
_chemical_formula_sum   'Li1 V1 Ru2'
_cell_volume   52.29
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.0  1.0
  V  V1  1  0.36  0.12  0.36  1.0
  Ru  Ru2  1  0.12  0.36  0.36  1.0
  Ru  Ru3  1  0.24  0.24  0.24  1.0

Li V Ru Ru
LiVRu2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LiVRu2 cluster. Li(1) is bonded in a single-bond geometry to one Ru(2) atom. The Li(1)-Ru(2) bond length is 1.17 Å. V(1) is bonded in a single-bond geometry to one Ru(1) and one Ru(2) atom. The V(1)-Ru(1) bond length is 1.21 Å. The V(1)-Ru(2) bond length is 0.86 Å. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a 2-coordinate geometry to one V(1) and one Ru(2) atom. The Ru(1)-Ru(2) bond length is 0.86 Å. In the second Ru site, Ru(2) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one Ru(1) atom.