data_CdTeRh4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.28
_cell_length_b   5.28
_cell_length_c   5.28
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdTeRh4
_chemical_formula_sum   'Cd1 Te1 Rh4'
_cell_volume   103.8
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.0  0.0  1.0
  Te  Te5  1  0.6  0.6  0.6  1.0
  Rh  Rh1  1  0.66  0.66  0.8  1.0
  Rh  Rh2  1  0.66  0.8  0.66  1.0
  Rh  Rh3  1  0.8  0.66  0.66  1.0
  Rh  Rh4  1  0.8  0.8  0.8  1.0

data_CdTeRh4
_symmetry_space_group_name_H-M   R3m
_cell_length_a   5.28
_cell_length_b   5.28
_cell_length_c   12.92
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   CdTeRh4
_chemical_formula_sum   'Cd3 Te3 Rh12'
_cell_volume   311.4
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  3  0.0  0.0  0.0  1.0
  Te  Te1  3  0.0  0.0  0.4  1.0
  Rh  Rh2  9  0.04  0.96  0.29  1.0
  Rh  Rh3  3  0.0  0.0  0.2  1.0

Cd Te Rh Rh Rh Rh
Rh4CdTe is Copper structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three Rh4CdTe clusters. There are two inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a 4-coordinate geometry to three equivalent Rh(1) and one Cd(1) atom. All Rh(2)-Rh(1) bond lengths are 1.23 Å. The Rh(2)-Cd(1) bond length is 2.62 Å. In the second Rh site, Rh(1) is bonded in a 2-coordinate geometry to one Rh(2), two equivalent Rh(1), and one Te(1) atom. Both Rh(1)-Rh(1) bond lengths are 0.71 Å. The Rh(1)-Te(1) bond length is 1.51 Å. Cd(1) is bonded in a distorted single-bond geometry to one Rh(2) atom. Te(1) is bonded in a 3-coordinate geometry to three equivalent Rh(1) atoms.