data_BRhPb2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.31
_cell_length_b   7.31
_cell_length_c   7.31
_cell_angle_alpha   28.28
_cell_angle_beta   28.28
_cell_angle_gamma   28.28
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BRhPb2
_chemical_formula_sum   'B1 Rh1 Pb2'
_cell_volume   77.45
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.0  0.0  0.0  1.0
  Rh  Rh3  1  0.0  0.0  0.52  1.0
  Pb  Pb1  1  0.0  0.0  0.43  1.0
  Pb  Pb2  1  0.0  0.0  0.61  1.0

data_BRhPb2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.19
_cell_length_b   3.57
_cell_length_c   7.31
_cell_angle_alpha   90.0
_cell_angle_beta   106.38
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   BRhPb2
_chemical_formula_sum   'B2 Rh2 Pb4'
_cell_volume   154.91
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  2  0.0  0.0  0.0  1.0
  Rh  Rh1  2  -0.0  0.0  0.48  1.0
  Pb  Pb2  2  -0.0  0.0  0.39  1.0
  Pb  Pb3  2  0.0  0.0  0.57  1.0

B Rh Pb Pb
RhBPb2 is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two RhBPb2 clusters. Rh(1) is bonded in a linear geometry to one Pb(1) and one Pb(2) atom. The Rh(1)-Pb(1) bond length is 0.69 Å. The Rh(1)-Pb(2) bond length is 0.69 Å. B(1) is bonded in a single-bond geometry to one Pb(2) atom. The B(1)-Pb(2) bond length is 2.82 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a single-bond geometry to one Rh(1) atom. In the second Pb site, Pb(2) is bonded in a single-bond geometry to one Rh(1) and one B(1) atom.