data_Na2VTe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.47
_cell_length_b   5.47
_cell_length_c   5.47
_cell_angle_alpha   130.81
_cell_angle_beta   130.81
_cell_angle_gamma   72.11
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na2VTe
_chemical_formula_sum   'Na2 V1 Te1'
_cell_volume   91.77
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.28  0.21  1.0
  Na  Na1  1  0.0  0.0  0.0  1.0
  V  V3  1  0.0  0.0  0.42  1.0
  Te  Te2  1  0.28  0.0  0.21  1.0

data_Na2VTe
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.55
_cell_length_b   4.55
_cell_length_c   5.47
_cell_angle_alpha   114.59
_cell_angle_beta   114.59
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na2VTe
_chemical_formula_sum   'Na2 V1 Te1'
_cell_volume   91.77
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.0  1.0
  Na  Na1  1  0.07  0.28  0.07  1.0
  V  V2  1  0.58  0.0  0.58  1.0
  Te  Te3  1  0.79  0.0  0.07  1.0

Na Na V Te
Na2VTe crystallizes in the triclinic P1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 1-coordinate geometry to one Na(2) and two equivalent V(1) atoms. The Na(1)-Na(2) bond length is 1.16 Å. There is one shorter (2.44 Å) and one longer (3.31 Å) Na(1)-V(1) bond length. In the second Na site, Na(2) is bonded in a distorted single-bond geometry to one Na(1), two equivalent V(1), and one Te(1) atom. There is one shorter (2.32 Å) and one longer (3.15 Å) Na(2)-V(1) bond length. The Na(2)-Te(1) bond length is 1.16 Å. V(1) is bonded in a distorted hexagonal planar geometry to two equivalent Na(1), two equivalent Na(2), and two equivalent Te(1) atoms. There is one shorter (2.44 Å) and one longer (3.31 Å) V(1)-Te(1) bond length. Te(1) is bonded in a single-bond geometry to one Na(2) and two equivalent V(1) atoms.