data_Sb2OsW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.09
_cell_length_b   5.09
_cell_length_c   5.09
_cell_angle_alpha   130.36
_cell_angle_beta   130.36
_cell_angle_gamma   72.83
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sb2OsW
_chemical_formula_sum   'Sb2 Os1 W1'
_cell_volume   74.91
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb1  1  0.0  0.0  0.0  1.0
  Sb  Sb2  1  0.14  0.0  0.05  1.0
  Os  Os0  1  0.0  0.14  0.05  1.0
  W  W3  1  0.0  0.0  0.1  1.0

data_Sb2OsW
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.28
_cell_length_b   4.28
_cell_length_c   5.09
_cell_angle_alpha   114.82
_cell_angle_beta   114.82
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sb2OsW
_chemical_formula_sum   'Sb2 Os1 W1'
_cell_volume   74.91
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.0  0.0  0.0  1.0
  Sb  Sb1  1  0.95  0.0  0.09  1.0
  Os  Os2  1  0.09  0.14  0.09  1.0
  W  W3  1  0.9  0.0  0.9  1.0

Sb Sb Os W
WOsSb2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one WOsSb2 cluster. W(1) is bonded in a single-bond geometry to one Sb(1) atom. The W(1)-Sb(1) bond length is 0.50 Å. Os(1) is bonded in a single-bond geometry to one Sb(1) atom. The Os(1)-Sb(1) bond length is 0.57 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted trigonal non-coplanar geometry to one W(1), one Os(1), and one Sb(2) atom. The Sb(1)-Sb(2) bond length is 0.57 Å. In the second Sb site, Sb(2) is bonded in a distorted single-bond geometry to one Sb(1) atom.