data_TlCuW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.62
_cell_length_b   5.62
_cell_length_c   5.62
_cell_angle_alpha   150.59
_cell_angle_beta   142.6
_cell_angle_gamma   48.27
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlCuW
_chemical_formula_sum   'Tl1 Cu1 W1'
_cell_volume   52.81
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl1  1  0.0  0.0  0.49  1.0
  Cu  Cu0  1  0.0  0.0  0.18  1.0
  W  W2  1  0.0  0.0  0.59  1.0

data_TlCuW
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.85
_cell_length_b   3.61
_cell_length_c   5.62
_cell_angle_alpha   108.7
_cell_angle_beta   104.7
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlCuW
_chemical_formula_sum   'Tl1 Cu1 W1'
_cell_volume   52.81
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.51  0.51  0.51  1.0
  Cu  Cu1  1  0.82  0.82  0.82  1.0
  W  W2  1  0.41  0.41  0.41  1.0

Tl Cu W
WCuTl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one WCuTl cluster. W(1) is bonded in a single-bond geometry to one Tl(1) atom. The W(1)-Tl(1) bond length is 0.54 Å. Cu(1) is bonded in a single-bond geometry to one Tl(1) atom. The Cu(1)-Tl(1) bond length is 1.76 Å. Tl(1) is bonded in a distorted single-bond geometry to one W(1) and one Cu(1) atom.