data_YRhCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.56
_cell_length_b   6.56
_cell_length_c   4.37
_cell_angle_alpha   93.04
_cell_angle_beta   93.04
_cell_angle_gamma   32.57
_symmetry_Int_Tables_number   1
_chemical_formula_structural   YRhCl2
_chemical_formula_sum   'Y1 Rh1 Cl2'
_cell_volume   101.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y3  1  0.0  0.0  0.0  1.0
  Rh  Rh2  1  0.18  0.0  0.18  1.0
  Cl  Cl0  1  0.17  0.0  0.93  1.0
  Cl  Cl1  1  0.19  0.0  0.43  1.0

data_YRhCl2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.68
_cell_length_b   4.37
_cell_length_c   6.56
_cell_angle_alpha   93.04
_cell_angle_beta   106.29
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   YRhCl2
_chemical_formula_sum   'Y1 Rh1 Cl2'
_cell_volume   101.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.0  0.0  0.0  1.0
  Rh  Rh1  1  0.0  0.18  0.18  1.0
  Cl  Cl2  1  0.0  0.43  0.19  1.0
  Cl  Cl3  1  0.0  0.93  0.17  1.0

Y Rh Cl Cl
YRhCl2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one YRhCl2 cluster. Y(1) is bonded in a 2-coordinate geometry to one Rh(1) and one Cl(1) atom. The Y(1)-Rh(1) bond length is 1.39 Å. The Y(1)-Cl(1) bond length is 1.16 Å. Rh(1) is bonded in a 3-coordinate geometry to one Y(1), one Cl(1), and one Cl(2) atom. The Rh(1)-Cl(1) bond length is 1.09 Å. The Rh(1)-Cl(2) bond length is 1.09 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 2-coordinate geometry to one Y(1) and one Rh(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Rh(1) atom.