data_BaLi2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.95
_cell_length_b   2.95
_cell_length_c   10.9
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   110.94
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaLi2W
_chemical_formula_sum   'Ba1 Li2 W1'
_cell_volume   88.57
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.0  0.0  0.0  1.0
  Li  Li1  1  0.67  0.0  0.19  1.0
  Li  Li2  1  0.67  0.0  0.71  1.0
  W  W3  1  0.0  0.0  0.45  1.0

data_BaLi2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.95
_cell_length_b   2.95
_cell_length_c   10.9
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   110.94
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaLi2W
_chemical_formula_sum   'Ba1 Li2 W1'
_cell_volume   88.57
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.0  0.0  0.0  1.0
  Li  Li1  1  0.67  0.0  0.19  1.0
  Li  Li2  1  0.67  0.0  0.71  1.0
  W  W3  1  0.0  0.0  0.45  1.0

Ba Li Li W
Li2BaW crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Li2BaW cluster. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 2-coordinate geometry to one Ba(1) and one W(1) atom. The Li(1)-Ba(1) bond length is 2.32 Å. The Li(1)-W(1) bond length is 2.95 Å. In the second Li site, Li(2) is bonded in a distorted single-bond geometry to one W(1) atom. The Li(2)-W(1) bond length is 2.95 Å. Ba(1) is bonded in a distorted single-bond geometry to one Li(1) atom. W(1) is bonded in a 2-coordinate geometry to one Li(1) and one Li(2) atom.