data_SrTl2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.39
_cell_length_b   5.39
_cell_length_c   5.82
_cell_angle_alpha   109.58
_cell_angle_beta   109.58
_cell_angle_gamma   43.84
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SrTl2Pd
_chemical_formula_sum   'Sr1 Tl2 Pd1'
_cell_volume   109.35
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr1  1  0.0  0.0  0.0  1.0
  Tl  Tl2  1  0.18  0.0  0.7  1.0
  Tl  Tl3  1  0.72  0.0  0.72  1.0
  Pd  Pd0  1  0.95  0.0  0.71  1.0

data_SrTl2Pd
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.03
_cell_length_b   5.39
_cell_length_c   5.82
_cell_angle_alpha   109.58
_cell_angle_beta   90.0
_cell_angle_gamma   111.92
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SrTl2Pd
_chemical_formula_sum   'Sr1 Tl2 Pd1'
_cell_volume   109.35
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.0  0.0  0.0  1.0
  Tl  Tl1  1  0.0  0.28  0.28  1.0
  Tl  Tl2  1  0.0  0.82  0.3  1.0
  Pd  Pd3  1  0.0  0.05  0.29  1.0

Sr Tl Tl Pd
SrPdTl2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one SrPdTl2 cluster. Sr(1) is bonded in a distorted single-bond geometry to one Pd(1) and one Tl(2) atom. The Sr(1)-Pd(1) bond length is 1.59 Å. The Sr(1)-Tl(2) bond length is 1.80 Å. Pd(1) is bonded in a distorted T-shaped geometry to one Sr(1), one Tl(1), and one Tl(2) atom. The Pd(1)-Tl(1) bond length is 1.28 Å. The Pd(1)-Tl(2) bond length is 1.28 Å. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a single-bond geometry to one Pd(1) atom. In the second Tl site, Tl(2) is bonded in a 2-coordinate geometry to one Sr(1) and one Pd(1) atom.