data_GdV
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.37
_cell_length_b   3.37
_cell_length_c   4.73
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GdV
_chemical_formula_sum   'Gd1 V1'
_cell_volume   46.36
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.0  0.94  0.36  1.0
  V  V1  1  0.0  0.0  0.0  1.0

data_GdV
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.37
_cell_length_b   5.83
_cell_length_c   4.73
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   GdV
_chemical_formula_sum   'Gd2 V2'
_cell_volume   92.73
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  2  0.44  0.5  0.36  1.0
  V  V1  2  0.5  0.5  0.0  1.0

Gd V
GdV crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two gadolinium;vanadium molecules. Gd(1) is bonded in a distorted single-bond geometry to one V(1) atom. The Gd(1)-V(1) bond length is 1.73 Å. V(1) is bonded in a distorted single-bond geometry to one Gd(1) atom.