data_GeAsPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.4
_cell_length_b   4.4
_cell_length_c   5.35
_cell_angle_alpha   101.85
_cell_angle_beta   101.85
_cell_angle_gamma   40.3
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GeAsPd2
_chemical_formula_sum   'Ge1 As1 Pd2'
_cell_volume   65.49
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge1  1  0.0  0.0  0.0  1.0
  As  As0  1  0.55  0.0  0.61  1.0
  Pd  Pd2  1  0.89  0.0  0.24  1.0
  Pd  Pd3  1  0.2  0.0  0.98  1.0

data_GeAsPd2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.03
_cell_length_b   4.4
_cell_length_c   5.35
_cell_angle_alpha   101.85
_cell_angle_beta   90.0
_cell_angle_gamma   110.15
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GeAsPd2
_chemical_formula_sum   'Ge1 As1 Pd2'
_cell_volume   65.49
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.0  0.0  0.0  1.0
  As  As1  1  0.0  0.45  0.39  1.0
  Pd  Pd2  1  0.0  0.11  0.76  1.0
  Pd  Pd3  1  0.0  0.8  0.02  1.0

Ge As Pd Pd
Pd2GeAs crystallizes in the triclinic P1 space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a single-bond geometry to one Ge(1) and two equivalent As(1) atoms. The Pd(1)-Ge(1) bond length is 1.47 Å. There is one shorter (2.73 Å) and one longer (3.14 Å) Pd(1)-As(1) bond length. In the second Pd site, Pd(2) is bonded in a single-bond geometry to one Ge(1) and one As(1) atom. The Pd(2)-Ge(1) bond length is 0.91 Å. The Pd(2)-As(1) bond length is 2.73 Å. Ge(1) is bonded in a distorted bent 120 degrees geometry to one Pd(1), one Pd(2), and one As(1) atom. The Ge(1)-As(1) bond length is 2.57 Å. As(1) is bonded in a 6-coordinate geometry to one Pd(2), two equivalent Pd(1), one Ge(1), and two equivalent As(1) atoms. Both As(1)-As(1) bond lengths are 3.03 Å.