data_TeAuCl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.98
_cell_length_b   8.37
_cell_length_c   9.53
_cell_angle_alpha   101.29
_cell_angle_beta   95.17
_cell_angle_gamma   90.31
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TeAuCl7
_chemical_formula_sum   'Te2 Au2 Cl14'
_cell_volume   621.51
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.73  0.47  0.14  1.0
  Te  Te1  1  0.34  0.03  0.17  1.0
  Au  Au2  1  0.07  0.66  0.21  1.0
  Au  Au3  1  0.0  0.85  0.09  1.0
  Cl  Cl4  1  0.7  0.56  0.05  1.0
  Cl  Cl5  1  0.37  0.95  0.25  1.0
  Cl  Cl6  1  0.74  0.37  0.22  1.0
  Cl  Cl7  1  0.33  0.13  0.09  1.0
  Cl  Cl8  1  0.06  0.46  0.33  1.0
  Cl  Cl9  1  0.01  0.04  0.97  1.0
  Cl  Cl10  1  0.31  0.25  0.96  1.0
  Cl  Cl11  1  0.77  0.25  0.34  1.0
  Cl  Cl12  1  0.94  0.21  0.86  1.0
  Cl  Cl13  1  0.13  0.3  0.44  1.0
  Cl  Cl14  1  0.75  0.81  0.24  1.0
  Cl  Cl15  1  0.32  0.69  0.06  1.0
  Cl  Cl16  1  0.46  0.85  0.27  1.0
  Cl  Cl17  1  0.61  0.65  0.03  1.0

data_TeAuCl7
_symmetry_space_group_name_H-M   P-1
_cell_length_a   7.98
_cell_length_b   8.37
_cell_length_c   9.53
_cell_angle_alpha   101.29
_cell_angle_beta   95.17
_cell_angle_gamma   90.31
_symmetry_Int_Tables_number   2
_chemical_formula_structural   TeAuCl7
_chemical_formula_sum   'Te2 Au2 Cl14'
_cell_volume   621.51
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  2  0.3  0.78  0.01  1.0
  Au  Au1  2  0.03  0.41  0.06  1.0
  Cl  Cl2  2  0.02  0.21  0.18  1.0
  Cl  Cl3  2  0.09  0.05  0.29  1.0
  Cl  Cl4  2  0.27  1.0  0.81  1.0
  Cl  Cl5  2  0.28  0.44  0.91  1.0
  Cl  Cl6  2  0.3  0.88  0.93  1.0
  Cl  Cl7  2  0.33  0.69  0.1  1.0
  Cl  Cl8  2  0.42  0.6  0.12  1.0

Te Te Au Au Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl
AuTeCl7 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one AuTeCl7 cluster. Au(1) is bonded in a 5-coordinate geometry to one Au(1), one Te(1), one Cl(3), and two equivalent Cl(6) atoms. The Au(1)-Au(1) bond length is 2.16 Å. The Au(1)-Te(1) bond length is 3.05 Å. The Au(1)-Cl(3) bond length is 2.19 Å. There is one shorter (2.61 Å) and one longer (2.87 Å) Au(1)-Cl(6) bond length. Te(1) is bonded in a linear geometry to one Au(1), one Cl(1), and one Cl(2) atom. The Te(1)-Cl(1) bond length is 1.22 Å. The Te(1)-Cl(2) bond length is 1.25 Å. There are seven inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Te(1) and one Cl(7) atom. The Cl(1)-Cl(7) bond length is 1.08 Å. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Te(1) and one Cl(4) atom. The Cl(2)-Cl(4) bond length is 1.67 Å. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Au(1) and one Cl(5) atom. The Cl(3)-Cl(5) bond length is 1.93 Å. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Cl(2) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Cl(3) atom. In the sixth Cl site, Cl(6) is bonded in a 1-coordinate geometry to two equivalent Au(1) atoms. In the seventh Cl site, Cl(7) is bonded in a distorted single-bond geometry to one Cl(1) atom.