data_GaCo6W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.19
_cell_length_b   6.19
_cell_length_c   10.13
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   109.71
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaCo6W
_chemical_formula_sum   'Ga4 Co24 W4'
_cell_volume   365.49
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga24  1  0.56  0.49  0.0  1.0
  Ga  Ga25  1  0.56  0.51  0.0  1.0
  Ga  Ga26  1  0.0  0.0  0.51  1.0
  Ga  Ga27  1  0.0  0.0  0.62  1.0
  Co  Co0  1  0.56  0.52  0.54  1.0
  Co  Co1  1  0.35  0.74  0.8  1.0
  Co  Co2  1  0.78  0.26  0.8  1.0
  Co  Co3  1  0.56  0.48  0.54  1.0
  Co  Co4  1  0.78  0.74  0.8  1.0
  Co  Co5  1  0.35  0.26  0.8  1.0
  Co  Co6  1  0.56  0.0  0.0  1.0
  Co  Co7  1  0.77  0.27  0.28  1.0
  Co  Co8  1  0.77  0.73  0.28  1.0
  Co  Co9  1  0.56  0.52  0.59  1.0
  Co  Co10  1  0.36  0.73  0.85  1.0
  Co  Co11  1  0.77  0.27  0.85  1.0
  Co  Co12  1  0.56  0.48  0.59  1.0
  Co  Co13  1  0.77  0.73  0.85  1.0
  Co  Co14  1  0.36  0.27  0.85  1.0
  Co  Co15  1  0.56  0.0  0.06  1.0
  Co  Co16  1  0.78  0.26  0.32  1.0
  Co  Co17  1  0.78  0.74  0.32  1.0
  Co  Co18  1  0.0  0.0  0.0  1.0
  Co  Co19  1  0.36  0.27  0.28  1.0
  Co  Co20  1  0.36  0.73  0.28  1.0
  Co  Co21  1  0.0  0.0  0.06  1.0
  Co  Co22  1  0.35  0.26  0.32  1.0
  Co  Co23  1  0.35  0.74  0.32  1.0
  W  W28  1  0.56  0.49  0.06  1.0
  W  W29  1  0.56  0.51  0.06  1.0
  W  W30  1  0.56  0.0  0.49  1.0
  W  W31  1  0.56  0.0  0.64  1.0

data_GaCo6W
_symmetry_space_group_name_H-M   P1
_cell_length_a   6.19
_cell_length_b   6.19
_cell_length_c   10.13
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   109.71
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaCo6W
_chemical_formula_sum   'Ga4 Co24 W4'
_cell_volume   365.49
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.0  0.0  0.51  1.0
  Ga  Ga1  1  0.0  0.0  0.62  1.0
  Ga  Ga2  1  0.56  0.49  0.0  1.0
  Ga  Ga3  1  0.56  0.51  0.0  1.0
  Co  Co4  1  0.0  0.0  0.0  1.0
  Co  Co5  1  0.0  0.0  0.06  1.0
  Co  Co6  1  0.35  0.26  0.32  1.0
  Co  Co7  1  0.35  0.26  0.8  1.0
  Co  Co8  1  0.35  0.74  0.32  1.0
  Co  Co9  1  0.35  0.74  0.8  1.0
  Co  Co10  1  0.36  0.27  0.28  1.0
  Co  Co11  1  0.36  0.27  0.85  1.0
  Co  Co12  1  0.36  0.73  0.28  1.0
  Co  Co13  1  0.36  0.73  0.85  1.0
  Co  Co14  1  0.56  0.0  0.0  1.0
  Co  Co15  1  0.56  0.0  0.06  1.0
  Co  Co16  1  0.56  0.48  0.54  1.0
  Co  Co17  1  0.56  0.48  0.59  1.0
  Co  Co18  1  0.56  0.52  0.54  1.0
  Co  Co19  1  0.56  0.52  0.59  1.0
  Co  Co20  1  0.77  0.27  0.28  1.0
  Co  Co21  1  0.77  0.27  0.85  1.0
  Co  Co22  1  0.77  0.73  0.28  1.0
  Co  Co23  1  0.77  0.73  0.85  1.0
  Co  Co24  1  0.78  0.26  0.32  1.0
  Co  Co25  1  0.78  0.26  0.8  1.0
  Co  Co26  1  0.78  0.74  0.32  1.0
  Co  Co27  1  0.78  0.74  0.8  1.0
  W  W28  1  0.56  0.0  0.49  1.0
  W  W29  1  0.56  0.0  0.64  1.0
  W  W30  1  0.56  0.49  0.06  1.0
  W  W31  1  0.56  0.51  0.06  1.0

Ga Ga Ga Ga Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co W W W W
WCo4(Co)8WGaGa crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one digallane molecule, seven Co clusters, one WCo4 cluster, and one WGa cluster. In one of the Co clusters, there are two inequivalent Co sites. In the first Co site, Co(1,10) is bonded in a distorted L-shaped geometry to one Co(1,10) and one Co(4,13) atom. The Co(1,10)-Co(1,10) bond length is 0.49 Å. The Co(1,10)-Co(4,13) bond length is 0.31 Å. In the second Co site, Co(4,13) is bonded in a distorted single-bond geometry to one Co(1,10) atom. In six of the Co clusters, there are two inequivalent Co sites. In the first Co site, Co(5) is bonded in a single-bond geometry to one Co(14) atom. The Co(5)-Co(14) bond length is 0.49 Å. In the second Co site, Co(14) is bonded in a distorted single-bond geometry to one Co(5) atom. In the WCo4 cluster, there are two inequivalent W sites. In the first W site, W(3) is bonded in a 3-coordinate geometry to one W(4), one Co(17), and one Co(24) atom. The W(3)-W(4) bond length is 1.53 Å. The W(3)-Co(17) bond length is 2.39 Å. The W(3)-Co(24) bond length is 2.39 Å. In the second W site, W(4) is bonded in a 3-coordinate geometry to one W(3), one Co(2), and one Co(3) atom. The W(4)-Co(2) bond length is 2.39 Å. The W(4)-Co(3) bond length is 2.39 Å. There are eight inequivalent Co sites. In the first Co site, Co(2) is bonded in a distorted single-bond geometry to one W(4) and one Co(11) atom. The Co(2)-Co(11) bond length is 0.49 Å. In the second Co site, Co(3) is bonded in a distorted single-bond geometry to one W(4) and one Co(12) atom. The Co(3)-Co(12) bond length is 0.49 Å. In the third Co site, Co(8) is bonded in a single-bond geometry to one Co(17) atom. The Co(8)-Co(17) bond length is 0.49 Å. In the fourth Co site, Co(11) is bonded in a single-bond geometry to one Co(2) atom. In the fifth Co site, Co(12) is bonded in a single-bond geometry to one Co(3) atom. In the sixth Co site, Co(17) is bonded in a 2-coordinate geometry to one W(3) and one Co(8) atom. In the seventh Co site, Co(21) is bonded in a single-bond geometry to one Co(24) atom. The Co(21)-Co(24) bond length is 0.49 Å. In the eighth Co site, Co(24) is bonded in a distorted single-bond geometry to one W(3) and one Co(21) atom. In the WGa cluster, there are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted L-shaped geometry to one W(2) and one Ga(1) atom. The W(1)-W(2) bond length is 0.18 Å. The W(1)-Ga(1) bond length is 0.64 Å. In the second W site, W(2) is bonded in a distorted L-shaped geometry to one W(1) and one Ga(2) atom. The W(2)-Ga(2) bond length is 0.64 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a distorted L-shaped geometry to one W(1) and one Ga(2) atom. The Ga(1)-Ga(2) bond length is 0.16 Å. In the second Ga site, Ga(2) is bonded in a distorted L-shaped geometry to one W(2) and one Ga(1) atom.