data_ReW2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.94
_cell_length_b   2.94
_cell_length_c   7.09
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ReW2Cl
_chemical_formula_sum   'Re1 W2 Cl1'
_cell_volume   61.48
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re1  1  0.0  0.0  0.55  1.0
  W  W2  1  0.47  0.47  0.31  1.0
  W  W3  1  0.47  0.47  0.78  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_ReW2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.16
_cell_length_b   4.16
_cell_length_c   7.09
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ReW2Cl
_chemical_formula_sum   'Re2 W4 Cl2'
_cell_volume   122.96
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  2  0.0  0.0  0.55  1.0
  W  W1  2  0.47  0.0  0.31  1.0
  W  W2  2  0.47  0.0  0.78  1.0
  Cl  Cl3  2  0.0  0.0  0.0  1.0

Re W W Cl
W2ReCl crystallizes in the monoclinic Cm space group. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 8-coordinate geometry to four equivalent Re(1) and four equivalent Cl(1) atoms. There are a spread of W(1)-Re(1) bond distances ranging from 2.57-2.75 Å. There are a spread of W(1)-Cl(1) bond distances ranging from 2.97-3.13 Å. In the second W site, W(2) is bonded in a distorted body-centered cubic geometry to four equivalent Re(1) and four equivalent Cl(1) atoms. There are a spread of W(2)-Re(1) bond distances ranging from 2.57-2.75 Å. There are a spread of W(2)-Cl(1) bond distances ranging from 2.51-2.70 Å. Re(1) is bonded in a distorted body-centered cubic geometry to four equivalent W(1) and four equivalent W(2) atoms. Cl(1) is bonded in a 8-coordinate geometry to four equivalent W(1) and four equivalent W(2) atoms.