data_Tl2OsCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.97
_cell_length_b   6.97
_cell_length_c   6.97
_cell_angle_alpha   146.01
_cell_angle_beta   146.01
_cell_angle_gamma   48.83
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Tl2OsCl
_chemical_formula_sum   'Tl2 Os1 Cl1'
_cell_volume   105.56
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl2  1  0.0  0.0  0.35  1.0
  Tl  Tl3  1  0.0  0.04  0.18  1.0
  Os  Os1  1  0.04  0.0  0.18  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Tl2OsCl
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.08
_cell_length_b   4.08
_cell_length_c   6.97
_cell_angle_alpha   106.99
_cell_angle_beta   106.99
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Tl2OsCl
_chemical_formula_sum   'Tl2 Os1 Cl1'
_cell_volume   105.56
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.65  0.0  0.65  1.0
  Tl  Tl1  1  0.86  0.04  0.86  1.0
  Os  Os2  1  0.82  0.0  0.86  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Tl Tl Os Cl
OsTl2Cl is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one OsTl2Cl cluster. Os(1) is bonded in a single-bond geometry to one Tl(1), one Tl(2), and one Cl(1) atom. The Os(1)-Tl(1) bond length is 1.45 Å. The Os(1)-Tl(2) bond length is 0.22 Å. The Os(1)-Cl(1) bond length is 1.01 Å. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a distorted single-bond geometry to one Os(1) and one Tl(2) atom. The Tl(1)-Tl(2) bond length is 1.45 Å. In the second Tl site, Tl(2) is bonded in a single-bond geometry to one Os(1), one Tl(1), and one Cl(1) atom. The Tl(2)-Cl(1) bond length is 1.01 Å. Cl(1) is bonded in a 2-coordinate geometry to one Os(1) and one Tl(2) atom.