data_AgP7W3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.57
_cell_length_b   14.24
_cell_length_c   7.81
_cell_angle_alpha   90.0
_cell_angle_beta   114.16
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgP7W3
_chemical_formula_sum   'Ag4 P28 W12'
_cell_volume   768.11
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.69  0.08  0.71  1.0
  Ag  Ag1  1  0.08  0.2  0.98  1.0
  Ag  Ag2  1  0.68  0.16  0.42  1.0
  Ag  Ag3  1  0.29  0.04  0.14  1.0
  P  P4  1  0.62  0.24  0.31  1.0
  P  P5  1  0.35  0.36  0.25  1.0
  P  P6  1  0.75  1.0  0.81  1.0
  P  P7  1  0.02  0.88  0.88  1.0
  P  P8  1  0.26  0.41  0.54  1.0
  P  P9  1  0.71  0.29  0.03  1.0
  P  P10  1  0.11  0.83  0.59  1.0
  P  P11  1  0.66  0.95  0.1  1.0
  P  P12  1  0.68  0.64  0.24  1.0
  P  P13  1  0.09  0.76  0.45  1.0
  P  P14  1  0.69  0.6  0.89  1.0
  P  P15  1  0.28  0.48  0.67  1.0
  P  P16  1  0.94  0.48  0.25  1.0
  P  P17  1  0.83  0.6  0.44  1.0
  P  P18  1  0.43  0.76  0.88  1.0
  P  P19  1  0.54  0.64  0.68  1.0
  P  P20  1  0.58  0.01  0.58  1.0
  P  P21  1  0.39  0.13  0.99  1.0
  P  P22  1  0.79  0.23  0.55  1.0
  P  P23  1  0.98  0.11  0.14  1.0
  P  P24  1  0.77  0.04  0.26  1.0
  P  P25  1  0.19  0.16  0.31  1.0
  P  P26  1  0.59  0.2  0.87  1.0
  P  P27  1  0.18  0.08  0.82  1.0
  P  P28  1  0.53  0.79  0.64  1.0
  P  P29  1  0.44  0.91  0.92  1.0
  P  P30  1  0.84  0.45  0.49  1.0
  P  P31  1  0.93  0.33  0.21  1.0
  W  W32  1  0.02  0.52  0.35  1.0
  W  W33  1  0.95  0.64  0.22  1.0
  W  W34  1  0.35  0.72  0.78  1.0
  W  W35  1  0.42  0.6  0.91  1.0
  W  W36  1  0.06  0.05  0.6  1.0
  W  W37  1  0.91  0.17  0.97  1.0
  W  W38  1  0.31  0.19  0.53  1.0
  W  W39  1  0.46  0.07  0.16  1.0
  W  W40  1  0.42  0.61  0.09  1.0
  W  W41  1  0.35  0.73  0.6  1.0
  W  W42  1  0.95  0.63  0.04  1.0
  W  W43  1  0.02  0.51  0.52  1.0

data_AgP7W3
_symmetry_space_group_name_H-M   P-1
_cell_length_a   7.57
_cell_length_b   7.81
_cell_length_c   14.24
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   114.16
_symmetry_Int_Tables_number   2
_chemical_formula_structural   AgP7W3
_chemical_formula_sum   'Ag4 P28 W12'
_cell_volume   768.11
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  2  0.0  0.14  0.46  1.0
  Ag  Ag1  2  0.4  0.42  0.58  1.0
  P  P2  2  0.01  0.33  0.98  1.0
  P  P3  2  0.03  0.46  0.67  1.0
  P  P4  2  0.07  0.25  0.38  1.0
  P  P5  2  0.09  0.69  0.42  1.0
  P  P6  2  0.1  0.99  0.61  1.0
  P  P7  2  0.15  0.88  0.98  1.0
  P  P8  2  0.15  0.92  0.83  1.0
  P  P9  2  0.25  0.64  0.71  1.0
  P  P10  2  0.25  0.68  0.86  1.0
  P  P11  2  0.3  0.58  0.49  1.0
  P  P12  2  0.33  0.31  0.26  1.0
  P  P13  2  0.41  0.89  0.14  1.0
  P  P14  2  0.43  0.03  0.21  1.0
  P  P15  2  0.49  0.26  0.46  1.0
  W  W16  2  0.22  0.4  0.55  1.0
  W  W17  2  0.27  0.48  0.01  1.0
  W  W18  2  0.27  0.65  0.02  1.0
  W  W19  2  0.33  0.78  0.9  1.0
  W  W20  2  0.33  0.96  0.89  1.0
  W  W21  2  0.37  0.03  0.43  1.0

Ag Ag Ag Ag P P P P P P P P P P P P P P P P P P P P P P P P P P P P W W W W W W W W W W W W
W3AgP7 crystallizes in the triclinic P-1 space group. There are six inequivalent W sites. In the first W site, W(1) is bonded in a distorted single-bond geometry to one W(2), one W(6), one P(7), and one P(8) atom. The W(1)-W(2) bond length is 1.94 Å. The W(1)-W(6) bond length is 1.38 Å. The W(1)-P(7) bond length is 0.99 Å. The W(1)-P(8) bond length is 2.13 Å. In the second W site, W(2) is bonded in a 5-coordinate geometry to one W(1), one W(5), one P(5), one P(6), and one P(8) atom. The W(2)-W(5) bond length is 1.38 Å. The W(2)-P(5) bond length is 2.16 Å. The W(2)-P(6) bond length is 2.40 Å. The W(2)-P(8) bond length is 2.41 Å. In the third W site, W(3) is bonded in a distorted single-bond geometry to one P(11), one P(12), and one P(2) atom. The W(3)-P(11) bond length is 2.66 Å. The W(3)-P(12) bond length is 1.66 Å. The W(3)-P(2) bond length is 3.36 Å. In the fourth W site, W(4) is bonded in a 2-coordinate geometry to one Ag(2), one P(10), one P(11), and one P(4) atom. The W(4)-Ag(2) bond length is 1.32 Å. The W(4)-P(10) bond length is 1.53 Å. The W(4)-P(11) bond length is 2.23 Å. The W(4)-P(4) bond length is 2.47 Å. In the fifth W site, W(5) is bonded in a water-like geometry to one W(2) and one P(5) atom. The W(5)-P(5) bond length is 1.87 Å. In the sixth W site, W(6) is bonded in a 4-coordinate geometry to one W(1), one P(13), one P(6), and one P(8) atom. The W(6)-P(13) bond length is 1.53 Å. The W(6)-P(6) bond length is 1.87 Å. The W(6)-P(8) bond length is 1.79 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 2-coordinate geometry to one P(1), one P(11), and one P(9) atom. The Ag(1)-P(1) bond length is 1.38 Å. The Ag(1)-P(11) bond length is 2.42 Å. The Ag(1)-P(9) bond length is 1.40 Å. In the second Ag site, Ag(2) is bonded in a single-bond geometry to one W(4), one P(2), and two equivalent P(12) atoms. The Ag(2)-P(2) bond length is 3.20 Å. There is one shorter (2.39 Å) and one longer (2.40 Å) Ag(2)-P(12) bond length. There are fourteen inequivalent P sites. In the first P site, P(1) is bonded in a single-bond geometry to one Ag(1), one P(2), and one P(4) atom. The P(1)-P(2) bond length is 2.51 Å. The P(1)-P(4) bond length is 2.73 Å. In the second P site, P(2) is bonded in a 4-coordinate geometry to one W(3), one Ag(2), one P(1), and one P(3) atom. The P(2)-P(3) bond length is 2.73 Å. In the third P site, P(3) is bonded in a 1-coordinate geometry to one P(2) and one P(6) atom. The P(3)-P(6) bond length is 1.42 Å. In the fourth P site, P(4) is bonded in a 4-coordinate geometry to one W(4), one P(1), one P(11), and one P(14) atom. The P(4)-P(11) bond length is 1.76 Å. The P(4)-P(14) bond length is 1.74 Å. In the fifth P site, P(5) is bonded in a 3-coordinate geometry to one W(2), one W(5), and one P(8) atom. The P(5)-P(8) bond length is 1.67 Å. In the sixth P site, P(6) is bonded in a 3-coordinate geometry to one W(2), one W(6), and one P(3) atom. In the seventh P site, P(7) is bonded in a single-bond geometry to one W(1) and one P(14) atom. The P(7)-P(14) bond length is 2.13 Å. In the eighth P site, P(8) is bonded in a 5-coordinate geometry to one W(1), one W(2), one W(6), one P(13), and one P(5) atom. The P(8)-P(13) bond length is 2.13 Å. In the ninth P site, P(9) is bonded in a single-bond geometry to one Ag(1) atom. In the tenth P site, P(10) is bonded in a distorted single-bond geometry to one W(4), one P(11), and one P(12) atom. The P(10)-P(11) bond length is 2.32 Å. The P(10)-P(12) bond length is 1.75 Å. In the eleventh P site, P(11) is bonded in a 5-coordinate geometry to one W(3), one W(4), one Ag(1), one P(10), and one P(4) atom. In the twelfth P site, P(12) is bonded in a 4-coordinate geometry to one W(3), two equivalent Ag(2), and one P(10) atom. In the thirteenth P site, P(13) is bonded in a single-bond geometry to one W(6) and one P(8) atom. In the fourteenth P site, P(14) is bonded in a 2-coordinate geometry to one P(4) and one P(7) atom.