data_TePd2Br
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.9
_cell_length_b   4.9
_cell_length_c   3.32
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TePd2Br
_chemical_formula_sum   'Te1 Pd2 Br1'
_cell_volume   79.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te3  1  0.45  0.45  0.0  1.0
  Pd  Pd1  1  0.0  0.45  0.66  1.0
  Pd  Pd2  1  0.45  0.0  0.66  1.0
  Br  Br0  1  0.0  0.0  0.0  1.0

data_TePd2Br
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.92
_cell_length_b   6.92
_cell_length_c   3.32
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TePd2Br
_chemical_formula_sum   'Te2 Pd4 Br2'
_cell_volume   159.09
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  2  0.45  0.0  0.0  1.0
  Pd  Pd1  4  0.22  0.22  0.66  1.0
  Br  Br2  2  0.0  0.0  0.0  1.0

Te Pd Pd Br
Pd2TeBr crystallizes in the monoclinic Cm space group. Pd(1) is bonded in a 1-coordinate geometry to one Te(1) and three equivalent Br(1) atoms. The Pd(1)-Te(1) bond length is 2.47 Å. There are a spread of Pd(1)-Br(1) bond distances ranging from 2.47-3.10 Å. Te(1) is bonded in a 2-coordinate geometry to two equivalent Pd(1) atoms. Br(1) is bonded in a 6-coordinate geometry to six equivalent Pd(1) atoms.