data_YTlCu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.53
_cell_length_b   4.53
_cell_length_c   3.88
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   YTlCu2
_chemical_formula_sum   'Y1 Tl1 Cu2'
_cell_volume   79.77
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y3  1  0.0  0.0  0.0  1.0
  Tl  Tl2  1  0.27  0.27  0.0  1.0
  Cu  Cu0  1  0.0  0.27  0.94  1.0
  Cu  Cu1  1  0.27  0.0  0.94  1.0

data_YTlCu2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.41
_cell_length_b   6.41
_cell_length_c   3.88
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   YTlCu2
_chemical_formula_sum   'Y2 Tl2 Cu4'
_cell_volume   159.54
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  2  0.0  0.0  0.0  1.0
  Tl  Tl1  2  0.27  0.0  0.0  1.0
  Cu  Cu2  4  0.13  0.13  0.94  1.0

Y Tl Cu Cu
YCu2Tl is alpha Po structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two YCu2Tl clusters. Y(1) is bonded in an L-shaped geometry to two equivalent Cu(1) atoms. Both Y(1)-Cu(1) bond lengths are 1.23 Å. Cu(1) is bonded in an L-shaped geometry to one Y(1) and one Tl(1) atom. The Cu(1)-Tl(1) bond length is 1.23 Å. Tl(1) is bonded in an L-shaped geometry to two equivalent Cu(1) atoms.