data_ZrCd2Os
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.26
_cell_length_b   3.26
_cell_length_c   7.67
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrCd2Os
_chemical_formula_sum   'Zr1 Cd2 Os1'
_cell_volume   81.49
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr3  1  0.0  0.0  0.38  1.0
  Cd  Cd0  1  0.63  0.63  0.03  1.0
  Cd  Cd1  1  0.0  0.0  0.13  1.0
  Os  Os2  1  0.63  0.63  0.96  1.0

data_ZrCd2Os
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.61
_cell_length_b   4.61
_cell_length_c   7.67
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZrCd2Os
_chemical_formula_sum   'Zr2 Cd4 Os2'
_cell_volume   162.99
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  2  0.0  0.0  0.38  1.0
  Cd  Cd1  2  0.0  0.0  0.13  1.0
  Cd  Cd2  2  0.13  0.5  0.03  1.0
  Os  Os3  2  0.13  0.5  0.96  1.0

Zr Cd Cd Os
ZrCdOsCd crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two OsCd clusters and two ZrCd clusters. In each OsCd cluster, Os(1) is bonded in a single-bond geometry to one Cd(1) atom. The Os(1)-Cd(1) bond length is 0.59 Å. Cd(1) is bonded in a single-bond geometry to one Os(1) atom. In each ZrCd cluster, Zr(1) is bonded in a single-bond geometry to one Cd(2) atom. The Zr(1)-Cd(2) bond length is 1.98 Å. Cd(2) is bonded in a 1-coordinate geometry to one Zr(1) atom.