data_InTcAg2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.2
_cell_length_b   5.2
_cell_length_c   5.2
_cell_angle_alpha   133.54
_cell_angle_beta   133.54
_cell_angle_gamma   67.8
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InTcAg2
_chemical_formula_sum   'In1 Tc1 Ag2'
_cell_volume   72.8
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In2  1  0.0  0.0  0.32  1.0
  Tc  Tc3  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.05  0.0  0.16  1.0
  Ag  Ag1  1  0.0  0.05  0.16  1.0

data_InTcAg2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.81
_cell_length_b   5.81
_cell_length_c   5.2
_cell_angle_alpha   90.0
_cell_angle_beta   123.9
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   InTcAg2
_chemical_formula_sum   'In2 Tc2 Ag4'
_cell_volume   145.59
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  0.18  0.5  0.68  1.0
  Tc  Tc1  2  0.0  0.0  0.0  1.0
  Ag  Ag2  4  0.37  0.47  0.89  1.0

In Tc Ag Ag
TcAg2In is Indium-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two TcAg2In clusters. Tc(1) is bonded in a 2-coordinate geometry to two equivalent Ag(1) atoms. Both Tc(1)-Ag(1) bond lengths are 0.67 Å. Ag(1) is bonded in a single-bond geometry to one Tc(1), one Ag(1), and one In(1) atom. The Ag(1)-Ag(1) bond length is 0.31 Å. The Ag(1)-In(1) bond length is 1.04 Å. In(1) is bonded in a 2-coordinate geometry to two equivalent Ag(1) atoms.