data_NaTeMo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.3
_cell_length_b   3.3
_cell_length_c   8.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaTeMo2
_chemical_formula_sum   'Na1 Te1 Mo2'
_cell_volume   87.77
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na2  1  0.0  0.0  0.85  1.0
  Te  Te3  1  0.65  0.65  0.51  1.0
  Mo  Mo0  1  0.0  0.0  0.24  1.0
  Mo  Mo1  1  0.65  0.65  0.47  1.0

data_NaTeMo2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.67
_cell_length_b   4.67
_cell_length_c   8.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   NaTeMo2
_chemical_formula_sum   'Na2 Te2 Mo4'
_cell_volume   175.55
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  2  0.0  0.0  0.85  1.0
  Te  Te1  2  0.15  0.5  0.51  1.0
  Mo  Mo2  2  0.0  0.0  0.24  1.0
  Mo  Mo3  2  0.15  0.5  0.47  1.0

Na Te Mo Mo
NaMo2Te crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two NaMo2Te clusters. Na(1) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Te(1) atom. The Na(1)-Mo(1) bond length is 3.13 Å. The Na(1)-Te(1) bond length is 3.19 Å. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 1-coordinate geometry to one Na(1) atom. In the second Mo site, Mo(2) is bonded in a single-bond geometry to one Te(1) atom. The Mo(2)-Te(1) bond length is 0.32 Å. Te(1) is bonded in a single-bond geometry to one Na(1) and one Mo(2) atom.