data_Cd2CoSb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.83
_cell_length_b   6.83
_cell_length_c   4.15
_cell_angle_alpha   106.21
_cell_angle_beta   106.21
_cell_angle_gamma   25.5
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2CoSb
_chemical_formula_sum   'Cd2 Co1 Sb1'
_cell_volume   79.89
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.93  0.0  0.75  1.0
  Cd  Cd1  1  0.2  0.0  0.23  1.0
  Co  Co2  1  0.0  0.0  0.0  1.0
  Sb  Sb3  1  0.07  0.0  0.99  1.0

data_Cd2CoSb
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.01
_cell_length_b   4.15
_cell_length_c   6.83
_cell_angle_alpha   106.21
_cell_angle_beta   102.75
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2CoSb
_chemical_formula_sum   'Cd2 Co1 Sb1'
_cell_volume   79.89
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.23  0.2  1.0
  Cd  Cd1  1  0.0  0.75  0.93  1.0
  Co  Co2  1  0.0  0.0  0.0  1.0
  Sb  Sb3  1  0.0  0.99  0.07  1.0

Cd Cd Co Sb
CoCd2Sb crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one CoCd2Sb cluster. Co(1) is bonded in a single-bond geometry to one Cd(1) and one Sb(1) atom. The Co(1)-Cd(1) bond length is 1.02 Å. The Co(1)-Sb(1) bond length is 0.46 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 2-coordinate geometry to one Co(1) and one Sb(1) atom. The Cd(1)-Sb(1) bond length is 1.17 Å. In the second Cd site, Cd(2) is bonded in a single-bond geometry to one Sb(1) atom. The Cd(2)-Sb(1) bond length is 1.17 Å. Sb(1) is bonded in a distorted single-bond geometry to one Co(1), one Cd(1), and one Cd(2) atom.