data_ScCrRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.95
_cell_length_b   4.95
_cell_length_c   4.95
_cell_angle_alpha   134.96
_cell_angle_beta   134.96
_cell_angle_gamma   65.59
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScCrRh2
_chemical_formula_sum   'Sc1 Cr1 Rh2'
_cell_volume   59.69
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc3  1  0.0  0.0  0.0  1.0
  Cr  Cr0  1  0.89  0.0  0.08  1.0
  Rh  Rh1  1  0.0  0.0  0.16  1.0
  Rh  Rh2  1  0.0  0.89  0.08  1.0

data_ScCrRh2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.79
_cell_length_b   3.79
_cell_length_c   4.95
_cell_angle_alpha   112.52
_cell_angle_beta   112.52
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScCrRh2
_chemical_formula_sum   'Sc1 Cr1 Rh2'
_cell_volume   59.69
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.0  0.0  0.0  1.0
  Cr  Cr1  1  0.92  0.0  0.82  1.0
  Rh  Rh2  1  0.82  0.89  0.82  1.0
  Rh  Rh3  1  0.84  0.0  0.84  1.0

Sc Cr Rh Rh
ScCrRh2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ScCrRh2 cluster. Sc(1) is bonded in a 3-coordinate geometry to one Cr(1), one Rh(1), and one Rh(2) atom. The Sc(1)-Cr(1) bond length is 0.84 Å. The Sc(1)-Rh(1) bond length is 0.78 Å. The Sc(1)-Rh(2) bond length is 0.84 Å. Cr(1) is bonded in a single-bond geometry to one Sc(1), one Rh(1), and one Rh(2) atom. The Cr(1)-Rh(1) bond length is 0.37 Å. The Cr(1)-Rh(2) bond length is 0.57 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted single-bond geometry to one Sc(1), one Cr(1), and one Rh(2) atom. The Rh(1)-Rh(2) bond length is 0.37 Å. In the second Rh site, Rh(2) is bonded in a 3-coordinate geometry to one Sc(1), one Cr(1), and one Rh(1) atom.