data_Sb(Cl3O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.18
_cell_length_b   7.18
_cell_length_c   12.86
_cell_angle_alpha   110.58
_cell_angle_beta   110.58
_cell_angle_gamma   53.3
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sb(Cl3O)2
_chemical_formula_sum   'Sb2 Cl12 O4'
_cell_volume   488.2
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.0  0.0  0.0  1.0
  Sb  Sb1  1  0.47  0.0  0.91  1.0
  Cl  Cl2  1  0.56  0.73  0.79  1.0
  Cl  Cl3  1  0.74  0.73  0.12  1.0
  Cl  Cl4  1  0.21  0.27  0.03  1.0
  Cl  Cl5  1  0.03  0.27  0.7  1.0
  Cl  Cl6  1  0.55  0.0  0.92  1.0
  Cl  Cl7  1  0.69  0.0  0.82  1.0
  Cl  Cl8  1  0.22  1.0  0.91  1.0
  Cl  Cl9  1  0.08  1.0  0.0  1.0
  Cl  Cl10  1  0.99  0.34  0.59  1.0
  Cl  Cl11  1  0.25  0.34  0.14  1.0
  Cl  Cl12  1  0.78  0.66  0.23  1.0
  Cl  Cl13  1  0.52  0.66  0.68  1.0
  O  O14  1  0.51  0.67  0.11  1.0
  O  O15  1  0.79  0.67  0.8  1.0
  O  O16  1  0.26  0.33  0.71  1.0
  O  O17  1  0.98  0.33  0.02  1.0

data_Sb(Cl3O)2
_symmetry_space_group_name_H-M   P1
_cell_length_a   6.44
_cell_length_b   7.18
_cell_length_c   12.33
_cell_angle_alpha   77.55
_cell_angle_beta   74.86
_cell_angle_gamma   63.35
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sb(Cl3O)2
_chemical_formula_sum   'Sb2 Cl12 O4'
_cell_volume   488.2
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.0  0.0  0.0  1.0
  Sb  Sb1  1  0.0  0.56  0.91  1.0
  Cl  Cl2  1  0.0  0.07  0.0  1.0
  Cl  Cl3  1  0.0  0.31  0.91  1.0
  Cl  Cl4  1  0.27  0.35  0.12  1.0
  Cl  Cl5  1  0.27  0.49  0.79  1.0
  Cl  Cl6  1  0.34  0.2  0.23  1.0
  Cl  Cl7  1  0.34  0.5  0.68  1.0
  Cl  Cl8  1  0.66  0.45  0.14  1.0
  Cl  Cl9  1  0.66  0.75  0.59  1.0
  Cl  Cl10  1  0.73  0.46  0.03  1.0
  Cl  Cl11  1  0.73  0.6  0.7  1.0
  Cl  Cl12  1  1.0  0.64  0.92  1.0
  Cl  Cl13  1  1.0  0.88  0.82  1.0
  O  O14  1  0.33  0.06  0.11  1.0
  O  O15  1  0.33  0.66  0.8  1.0
  O  O16  1  0.67  0.29  0.02  1.0
  O  O17  1  0.67  0.89  0.71  1.0

Sb Sb Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl O O O O
SbOCl4Cl2O is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Cl2O cluster and one SbOCl4 cluster. In the Cl2O cluster, there are two inequivalent O sites. In the first O site, O(1,3) is bonded in a 2-coordinate geometry to one Cl(2) and one Cl(9,11) atom. The O(1,3)-Cl(2) bond length is 1.94 Å. The O(1,3)-Cl(9,11) bond length is 2.00 Å. In the second O site, O(4) is bonded in a 1-coordinate geometry to one Cl(10), one Cl(2), and one Cl(3) atom. The O(4)-Cl(10) bond length is 2.04 Å. The O(4)-Cl(2) bond length is 2.37 Å. The O(4)-Cl(3) bond length is 1.44 Å. There are four inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a 3-coordinate geometry to one O(1,3); one O(4); and one Cl(9,11) atom. The Cl(2)-Cl(9,11) bond length is 1.63 Å. In the second Cl site, Cl(3) is bonded in a 1-coordinate geometry to one O(4) and one Cl(10) atom. The Cl(3)-Cl(10) bond length is 1.39 Å. In the third Cl site, Cl(9,11) is bonded in a 2-coordinate geometry to one O(1,3) and one Cl(4) atom. The Cl(9,11)-Cl(4) bond length is 1.63 Å. In the fourth Cl site, Cl(10) is bonded in a 2-coordinate geometry to one O(4) and one Cl(3) atom. In the SbOCl4 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a single-bond geometry to one Cl(6) and one Cl(8) atom. The Sb(1)-Cl(6) bond length is 2.59 Å. The Sb(1)-Cl(8) bond length is 0.53 Å. In the second Sb site, Sb(2) is bonded in a distorted single-bond geometry to one Cl(1), one Cl(5), and one Cl(7) atom. The Sb(2)-Cl(1) bond length is 1.90 Å. The Sb(2)-Cl(5) bond length is 0.55 Å. The Sb(2)-Cl(7) bond length is 1.78 Å. There are two inequivalent O sites. In the first O site, O(1,3) is bonded in a 2-coordinate geometry to one Cl(2) and one Cl(9,11) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one Cl(1), one Cl(12), one Cl(4), and one Cl(6) atom. The O(2)-Cl(1) bond length is 1.44 Å. The O(2)-Cl(12) bond length is 2.04 Å. The O(2)-Cl(4) bond length is 2.37 Å. The O(2)-Cl(6) bond length is 2.02 Å. There are eight inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to one Sb(2), one O(2), and one Cl(12) atom. The Cl(1)-Cl(12) bond length is 1.39 Å. In the second Cl site, Cl(4) is bonded in a 3-coordinate geometry to one O(1,3); one O(2); and one Cl(9,11) atom. The Cl(4)-O(1,3) bond length is 1.94 Å. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(2) and one Cl(6) atom. The Cl(5)-Cl(6) bond length is 1.89 Å. In the fourth Cl site, Cl(6) is bonded in a 3-coordinate geometry to one Sb(1), one O(2), and one Cl(5) atom. In the fifth Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(2) atom. In the sixth Cl site, Cl(8) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh Cl site, Cl(9,11) is bonded in a 2-coordinate geometry to one O(1,3) and one Cl(4) atom. In the eighth Cl site, Cl(12) is bonded in a 2-coordinate geometry to one O(2) and one Cl(1) atom.