data_Bi2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.96
_cell_length_b   6.96
_cell_length_c   6.96
_cell_angle_alpha   151.61
_cell_angle_beta   151.61
_cell_angle_gamma   40.58
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Bi2Pd
_chemical_formula_sum   'Bi2 Pd1'
_cell_volume   76.04
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.0  0.0  0.75  1.0
  Bi  Bi1  1  0.0  0.0  0.31  1.0
  Pd  Pd2  1  0.0  0.0  0.0  1.0

data_Bi2Pd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.83
_cell_length_b   4.83
_cell_length_c   6.96
_cell_angle_alpha   90.0
_cell_angle_beta   110.29
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Bi2Pd
_chemical_formula_sum   'Bi4 Pd2'
_cell_volume   152.08
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  2  0.0  0.0  0.25  1.0
  Bi  Bi1  2  0.0  0.0  0.69  1.0
  Pd  Pd2  2  0.0  0.0  0.0  1.0

Bi Bi Pd
PdBi2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two PdBi2 clusters. Pd(1) is bonded in a linear geometry to one Bi(1) and one Bi(2) atom. The Pd(1)-Bi(1) bond length is 1.75 Å. The Pd(1)-Bi(2) bond length is 2.14 Å. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a single-bond geometry to one Pd(1) atom. In the second Bi site, Bi(2) is bonded in a single-bond geometry to one Pd(1) atom.