data_CdReBi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.36
_cell_length_b   3.36
_cell_length_c   9.03
_cell_angle_alpha   90.0
_cell_angle_beta   91.76
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdReBi2
_chemical_formula_sum   'Cd1 Re1 Bi2'
_cell_volume   101.87
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd2  1  0.0  0.0  0.0  1.0
  Re  Re3  1  0.86  0.0  0.51  1.0
  Bi  Bi0  1  0.54  0.68  0.24  1.0
  Bi  Bi1  1  0.54  0.68  0.79  1.0

data_CdReBi2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.36
_cell_length_b   3.36
_cell_length_c   9.03
_cell_angle_alpha   90.0
_cell_angle_beta   91.76
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdReBi2
_chemical_formula_sum   'Cd1 Re1 Bi2'
_cell_volume   101.87
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.0  0.0  1.0
  Re  Re1  1  0.86  0.0  0.51  1.0
  Bi  Bi2  1  0.54  0.68  0.79  1.0
  Bi  Bi3  1  0.54  0.68  0.24  1.0

Cd Re Bi Bi
ReCdBi2 crystallizes in the triclinic P1 space group. Re(1) is bonded in a distorted bent 120 degrees geometry to one Bi(1) and three equivalent Bi(2) atoms. The Re(1)-Bi(1) bond length is 2.92 Å. There are a spread of Re(1)-Bi(2) bond distances ranging from 2.98-3.60 Å. Cd(1) is bonded in a 4-coordinate geometry to two equivalent Bi(1) and four equivalent Bi(2) atoms. There is one shorter (2.87 Å) and one longer (2.95 Å) Cd(1)-Bi(1) bond length. There are a spread of Cd(1)-Bi(2) bond distances ranging from 2.61-3.49 Å. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 3-coordinate geometry to one Re(1) and two equivalent Cd(1) atoms. In the second Bi site, Bi(2) is bonded in a 11-coordinate geometry to three equivalent Re(1), four equivalent Cd(1), and four equivalent Bi(2) atoms. All Bi(2)-Bi(2) bond lengths are 3.36 Å.