data_LiAgPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.87
_cell_length_b   2.87
_cell_length_c   7.45
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiAgPd2
_chemical_formula_sum   'Li1 Ag1 Pd2'
_cell_volume   61.31
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.0  0.0  0.69  1.0
  Ag  Ag0  1  0.43  0.43  0.82  1.0
  Pd  Pd2  1  0.43  0.43  0.3  1.0
  Pd  Pd3  1  0.0  0.0  0.81  1.0

data_LiAgPd2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.06
_cell_length_b   4.06
_cell_length_c   7.45
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LiAgPd2
_chemical_formula_sum   'Li2 Ag2 Pd4'
_cell_volume   122.63
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.69  1.0
  Ag  Ag1  2  0.43  0.0  0.82  1.0
  Pd  Pd2  2  0.0  0.0  0.81  1.0
  Pd  Pd3  2  0.43  0.0  0.3  1.0

Li Ag Pd Pd
LiPd2Ag crystallizes in the monoclinic Cm space group. Li(1) is bonded in a single-bond geometry to one Pd(1), one Pd(2), and four equivalent Ag(1) atoms. The Li(1)-Pd(1) bond length is 3.40 Å. The Li(1)-Pd(2) bond length is 0.90 Å. There are a spread of Li(1)-Ag(1) bond distances ranging from 2.01-2.49 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 6-coordinate geometry to one Li(1), four equivalent Pd(1), and one Ag(1) atom. All Pd(1)-Pd(1) bond lengths are 2.87 Å. The Pd(1)-Ag(1) bond length is 3.57 Å. In the second Pd site, Pd(2) is bonded in a single-bond geometry to one Li(1) and four equivalent Ag(1) atoms. There are a spread of Pd(2)-Ag(1) bond distances ranging from 1.77-2.29 Å. Ag(1) is bonded in a 8-coordinate geometry to four equivalent Li(1), one Pd(1), and four equivalent Pd(2) atoms.