data_YV2Au
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.41
_cell_length_b   3.41
_cell_length_c   6.33
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   YV2Au
_chemical_formula_sum   'Y1 V2 Au1'
_cell_volume   73.59
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y3  1  0.0  0.0  0.0  1.0
  V  V1  1  0.7  0.7  0.29  1.0
  V  V2  1  0.7  0.7  0.05  1.0
  Au  Au0  1  0.0  0.0  0.17  1.0

data_YV2Au
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.82
_cell_length_b   4.82
_cell_length_c   6.33
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   YV2Au
_chemical_formula_sum   'Y2 V4 Au2'
_cell_volume   147.18
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  2  0.0  0.0  0.0  1.0
  V  V1  2  0.2  0.5  0.05  1.0
  V  V2  2  0.2  0.5  0.29  1.0
  Au  Au3  2  0.0  0.0  0.17  1.0

Y V V Au
YV2Au crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two YV2Au clusters. Y(1) is bonded in a single-bond geometry to one V(2) and one Au(1) atom. The Y(1)-V(2) bond length is 1.46 Å. The Y(1)-Au(1) bond length is 1.06 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 1-coordinate geometry to one V(2) and one Au(1) atom. The V(1)-V(2) bond length is 1.52 Å. The V(1)-Au(1) bond length is 1.62 Å. In the second V site, V(2) is bonded in a 3-coordinate geometry to one Y(1), one V(1), and one Au(1) atom. The V(2)-Au(1) bond length is 1.62 Å. Au(1) is bonded in a distorted single-bond geometry to one Y(1), one V(1), and one V(2) atom.