data_LiVZn
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.62
_cell_length_b   2.62
_cell_length_c   7.15
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiVZn
_chemical_formula_sum   'Li1 V1 Zn1'
_cell_volume   42.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.12  1.0
  V  V1  1  0.0  0.51  0.42  1.0
  Zn  Zn2  1  0.31  0.76  0.77  1.0

data_LiVZn
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.62
_cell_length_b   2.62
_cell_length_c   7.15
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiVZn
_chemical_formula_sum   'Li1 V1 Zn1'
_cell_volume   42.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.12  1.0
  V  V1  1  0.0  0.51  0.42  1.0
  Zn  Zn2  1  0.31  0.76  0.77  1.0

Li V Zn
LiVZn crystallizes in the triclinic P1 space group. Li(1) is bonded in a 13-coordinate geometry to six equivalent Li(1), four equivalent V(1), and three equivalent Zn(1) atoms. All Li(1)-Li(1) bond lengths are 2.62 Å. There are a spread of Li(1)-V(1) bond distances ranging from 2.54-3.16 Å. There are a spread of Li(1)-Zn(1) bond distances ranging from 2.80-3.04 Å. V(1) is bonded in a 2-coordinate geometry to four equivalent Li(1) and one Zn(1) atom. The V(1)-Zn(1) bond length is 2.57 Å. Zn(1) is bonded in a 10-coordinate geometry to three equivalent Li(1), one V(1), and six equivalent Zn(1) atoms. All Zn(1)-Zn(1) bond lengths are 2.62 Å.