data_NaRuCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.56
_cell_length_b   6.56
_cell_length_c   3.98
_cell_angle_alpha   90.76
_cell_angle_beta   90.76
_cell_angle_gamma   29.2
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaRuCl2
_chemical_formula_sum   'Na1 Ru1 Cl2'
_cell_volume   83.67
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na2  1  0.95  0.0  0.52  1.0
  Ru  Ru3  1  0.9  0.0  0.45  1.0
  Cl  Cl0  1  0.34  0.0  0.51  1.0
  Cl  Cl1  1  0.73  0.0  0.47  1.0

data_NaRuCl2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.31
_cell_length_b   3.98
_cell_length_c   6.56
_cell_angle_alpha   90.76
_cell_angle_beta   104.6
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaRuCl2
_chemical_formula_sum   'Na1 Ru1 Cl2'
_cell_volume   83.67
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.52  0.95  1.0
  Ru  Ru1  1  0.0  0.45  0.9  1.0
  Cl  Cl2  1  0.0  0.47  0.73  1.0
  Cl  Cl3  1  0.0  0.51  0.34  1.0

Na Ru Cl Cl
NaRuCl2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one NaRuCl2 cluster. Na(1) is bonded in a single-bond geometry to one Ru(1) and one Cl(1) atom. The Na(1)-Ru(1) bond length is 0.47 Å. The Na(1)-Cl(1) bond length is 2.51 Å. Ru(1) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one Cl(2) atom. The Ru(1)-Cl(2) bond length is 1.07 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Na(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom.