data_TlPdCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.18
_cell_length_b   8.18
_cell_length_c   8.18
_cell_angle_alpha   155.0
_cell_angle_beta   153.86
_cell_angle_gamma   36.48
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlPdCl2
_chemical_formula_sum   'Tl1 Pd1 Cl2'
_cell_volume   101.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl3  1  0.0  0.85  0.07  1.0
  Pd  Pd2  1  0.0  0.0  0.79  1.0
  Cl  Cl0  1  0.0  0.0  0.04  1.0
  Cl  Cl1  1  0.77  0.0  0.64  1.0

data_TlPdCl2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.54
_cell_length_b   3.7
_cell_length_c   8.18
_cell_angle_alpha   103.07
_cell_angle_beta   102.5
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlPdCl2
_chemical_formula_sum   'Tl1 Pd1 Cl2'
_cell_volume   101.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.15  0.22  0.22  1.0
  Pd  Pd1  1  0.0  0.79  0.79  1.0
  Cl  Cl2  1  0.0  0.04  0.04  1.0
  Cl  Cl3  1  0.0  0.64  0.87  1.0

Tl Pd Cl Cl
PdClTlCl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one thallium chloride molecule and one PdCl cluster. In the PdCl cluster, Pd(1) is bonded in a single-bond geometry to one Cl(2) atom. The Pd(1)-Cl(2) bond length is 0.95 Å. Cl(2) is bonded in a single-bond geometry to one Pd(1) atom.