data_VBi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.04
_cell_length_b   4.04
_cell_length_c   4.04
_cell_angle_alpha   123.25
_cell_angle_beta   117.17
_cell_angle_gamma   89.71
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VBi
_chemical_formula_sum   'V1 Bi1'
_cell_volume   46.23
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V1  1  0.0  0.0  0.0  1.0
  Bi  Bi0  1  0.0  0.0  0.86  1.0

data_VBi
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.84
_cell_length_b   4.04
_cell_length_c   4.04
_cell_angle_alpha   62.83
_cell_angle_beta   61.62
_cell_angle_gamma   61.62
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VBi
_chemical_formula_sum   'V1 Bi1'
_cell_volume   46.23
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  Bi  Bi1  1  -0.0  -0.0  0.86  1.0

V Bi
BiV is alpha carbon monoxide-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one bismuth;vanadium molecule. V(1) is bonded in a single-bond geometry to one Bi(1) atom. The V(1)-Bi(1) bond length is 0.56 Å. Bi(1) is bonded in a single-bond geometry to one V(1) atom.