data_AgIr2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.64
_cell_length_b   5.64
_cell_length_c   5.64
_cell_angle_alpha   151.27
_cell_angle_beta   127.3
_cell_angle_gamma   61.13
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgIr2Cl
_chemical_formula_sum   'Ag1 Ir2 Cl1'
_cell_volume   68.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.4  0.0  0.8  1.0
  Ir  Ir2  1  0.4  0.0  0.0  1.0
  Ir  Ir3  1  0.0  0.0  0.14  1.0
  Cl  Cl1  1  0.0  0.0  0.64  1.0

data_AgIr2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.8
_cell_length_b   5.01
_cell_length_c   5.64
_cell_angle_alpha   116.35
_cell_angle_beta   104.37
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgIr2Cl
_chemical_formula_sum   'Ag1 Ir2 Cl1'
_cell_volume   68.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.61  0.2  0.61  1.0
  Ir  Ir1  1  0.4  1.0  0.4  1.0
  Ir  Ir2  1  0.86  0.86  0.86  1.0
  Cl  Cl3  1  0.36  0.36  0.36  1.0

Ag Ir Ir Cl
Ir2AgCl crystallizes in the triclinic P1 space group. There are two inequivalent Ir sites. In the first Ir site, Ir(1) is bonded in a 2-coordinate geometry to one Ir(2), one Ag(1), and one Cl(1) atom. The Ir(1)-Ir(2) bond length is 2.80 Å. The Ir(1)-Ag(1) bond length is 1.18 Å. The Ir(1)-Cl(1) bond length is 1.92 Å. In the second Ir site, Ir(2) is bonded in a 7-coordinate geometry to one Ir(1), two equivalent Ir(2), two equivalent Ag(1), and two equivalent Cl(1) atoms. Both Ir(2)-Ir(2) bond lengths are 2.80 Å. There is one shorter (2.69 Å) and one longer (2.93 Å) Ir(2)-Ag(1) bond length. There is one shorter (2.81 Å) and one longer (2.83 Å) Ir(2)-Cl(1) bond length. Ag(1) is bonded in a 2-coordinate geometry to one Ir(1), two equivalent Ir(2), and one Cl(1) atom. The Ag(1)-Cl(1) bond length is 1.86 Å. Cl(1) is bonded in a 2-coordinate geometry to one Ir(1), two equivalent Ir(2), and one Ag(1) atom.