data_AlCo6Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.2
_cell_length_b   6.2
_cell_length_c   10.16
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   109.74
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AlCo6Rh
_chemical_formula_sum   'Al4 Co24 Rh4'
_cell_volume   367.81
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.57  0.47  0.0  1.0
  Al  Al1  1  0.57  0.53  0.0  1.0
  Al  Al2  1  0.0  0.0  0.68  1.0
  Al  Al3  1  0.0  0.0  0.48  1.0
  Co  Co4  1  0.57  0.46  0.62  1.0
  Co  Co5  1  0.79  0.73  0.92  1.0
  Co  Co6  1  0.35  0.27  0.92  1.0
  Co  Co7  1  0.57  0.54  0.62  1.0
  Co  Co8  1  0.35  0.73  0.92  1.0
  Co  Co9  1  0.79  0.27  0.92  1.0
  Co  Co10  1  0.0  0.0  0.08  1.0
  Co  Co11  1  0.36  0.26  0.37  1.0
  Co  Co12  1  0.36  0.74  0.37  1.0
  Co  Co13  1  0.57  0.46  0.54  1.0
  Co  Co14  1  0.77  0.74  0.79  1.0
  Co  Co15  1  0.36  0.26  0.79  1.0
  Co  Co16  1  0.57  0.54  0.54  1.0
  Co  Co17  1  0.36  0.74  0.79  1.0
  Co  Co18  1  0.77  0.26  0.79  1.0
  Co  Co19  1  0.0  0.0  0.0  1.0
  Co  Co20  1  0.35  0.27  0.24  1.0
  Co  Co21  1  0.35  0.73  0.24  1.0
  Co  Co22  1  0.57  0.0  0.08  1.0
  Co  Co23  1  0.77  0.26  0.37  1.0
  Co  Co24  1  0.77  0.74  0.37  1.0
  Co  Co25  1  0.57  0.0  0.0  1.0
  Co  Co26  1  0.79  0.27  0.24  1.0
  Co  Co27  1  0.79  0.73  0.24  1.0
  Rh  Rh28  1  0.57  0.47  0.08  1.0
  Rh  Rh29  1  0.57  0.53  0.08  1.0
  Rh  Rh30  1  0.57  0.0  0.64  1.0
  Rh  Rh31  1  0.57  0.0  0.52  1.0

data_AlCo6Rh
_symmetry_space_group_name_H-M   P1
_cell_length_a   6.2
_cell_length_b   6.2
_cell_length_c   10.16
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   109.74
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AlCo6Rh
_chemical_formula_sum   'Al4 Co24 Rh4'
_cell_volume   367.81
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.0  0.0  0.48  1.0
  Al  Al1  1  0.0  0.0  0.68  1.0
  Al  Al2  1  0.57  0.47  -0.0  1.0
  Al  Al3  1  0.57  0.53  -0.0  1.0
  Co  Co4  1  0.0  0.0  0.0  1.0
  Co  Co5  1  0.0  0.0  0.08  1.0
  Co  Co6  1  0.35  0.73  0.24  1.0
  Co  Co7  1  0.35  0.73  0.92  1.0
  Co  Co8  1  0.35  0.27  0.24  1.0
  Co  Co9  1  0.35  0.27  0.92  1.0
  Co  Co10  1  0.36  0.74  0.37  1.0
  Co  Co11  1  0.36  0.74  0.79  1.0
  Co  Co12  1  0.36  0.26  0.37  1.0
  Co  Co13  1  0.36  0.26  0.79  1.0
  Co  Co14  1  0.57  0.0  -0.0  1.0
  Co  Co15  1  0.57  0.0  0.08  1.0
  Co  Co16  1  0.57  0.46  0.54  1.0
  Co  Co17  1  0.57  0.46  0.62  1.0
  Co  Co18  1  0.57  0.54  0.54  1.0
  Co  Co19  1  0.57  0.54  0.62  1.0
  Co  Co20  1  0.77  0.26  0.37  1.0
  Co  Co21  1  0.77  0.26  0.79  1.0
  Co  Co22  1  0.77  0.74  0.37  1.0
  Co  Co23  1  0.77  0.74  0.79  1.0
  Co  Co24  1  0.79  0.27  0.24  1.0
  Co  Co25  1  0.79  0.27  0.92  1.0
  Co  Co26  1  0.79  0.73  0.24  1.0
  Co  Co27  1  0.79  0.73  0.92  1.0
  Rh  Rh28  1  0.57  0.0  0.52  1.0
  Rh  Rh29  1  0.57  0.0  0.64  1.0
  Rh  Rh30  1  0.57  0.47  0.08  1.0
  Rh  Rh31  1  0.57  0.53  0.08  1.0

Al Al Al Al Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Co Rh Rh Rh Rh
RhCo6Al crystallizes in the triclinic P1 space group. There are four inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in an L-shaped geometry to one Rh(2), one Co(17), and one Al(1) atom. The Rh(1)-Rh(2) bond length is 0.33 Å. The Rh(1)-Co(17) bond length is 2.21 Å. The Rh(1)-Al(1) bond length is 0.81 Å. In the second Rh site, Rh(2) is bonded in an L-shaped geometry to one Rh(1), one Co(24), and one Al(2) atom. The Rh(2)-Co(24) bond length is 2.21 Å. The Rh(2)-Al(2) bond length is 0.81 Å. In the third Rh site, Rh(3) is bonded in a 8-coordinate geometry to one Rh(4), one Co(1), one Co(11), one Co(12), one Co(14), one Co(15), one Co(4), and one Al(3) atom. The Rh(3)-Rh(4) bond length is 1.30 Å. The Rh(3)-Co(1) bond length is 2.88 Å. The Rh(3)-Co(11) bond length is 2.80 Å. The Rh(3)-Co(12) bond length is 2.80 Å. The Rh(3)-Co(14) bond length is 2.24 Å. The Rh(3)-Co(15) bond length is 2.24 Å. The Rh(3)-Co(4) bond length is 2.88 Å. The Rh(3)-Al(3) bond length is 2.71 Å. In the fourth Rh site, Rh(4) is bonded in a 8-coordinate geometry to one Rh(3), one Co(10), one Co(13), one Co(20), one Co(21), one Co(8), one Co(9), and one Al(4) atom. The Rh(4)-Co(10) bond length is 2.88 Å. The Rh(4)-Co(13) bond length is 2.88 Å. The Rh(4)-Co(20) bond length is 2.24 Å. The Rh(4)-Co(21) bond length is 2.80 Å. The Rh(4)-Co(8) bond length is 2.80 Å. The Rh(4)-Co(9) bond length is 2.24 Å. The Rh(4)-Al(4) bond length is 2.71 Å. There are twenty-four inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted single-bond geometry to one Rh(3) and one Co(4) atom. The Co(1)-Co(4) bond length is 0.47 Å. In the second Co site, Co(2) is bonded in a 3-coordinate geometry to one Co(11), one Co(16), and one Al(2) atom. The Co(2)-Co(11) bond length is 1.34 Å. The Co(2)-Co(16) bond length is 1.93 Å. The Co(2)-Al(2) bond length is 1.70 Å. In the third Co site, Co(3) is bonded in a distorted bent 120 degrees geometry to one Co(12) and one Al(1) atom. The Co(3)-Co(12) bond length is 1.34 Å. The Co(3)-Al(1) bond length is 1.70 Å. In the fourth Co site, Co(4) is bonded in a distorted single-bond geometry to one Rh(3) and one Co(1) atom. In the fifth Co site, Co(5) is bonded in a distorted trigonal non-coplanar geometry to one Co(14), one Co(22), and one Al(2) atom. The Co(5)-Co(14) bond length is 1.34 Å. The Co(5)-Co(22) bond length is 1.94 Å. The Co(5)-Al(2) bond length is 2.27 Å. In the sixth Co site, Co(6) is bonded in a 3-coordinate geometry to one Co(15), one Co(22), and one Al(1) atom. The Co(6)-Co(15) bond length is 1.34 Å. The Co(6)-Co(22) bond length is 1.94 Å. The Co(6)-Al(1) bond length is 2.27 Å. In the seventh Co site, Co(7) is bonded in a single-bond geometry to one Co(16) atom. The Co(7)-Co(16) bond length is 0.81 Å. In the eighth Co site, Co(8) is bonded in a 2-coordinate geometry to one Rh(4), one Co(17), and one Al(4) atom. The Co(8)-Co(17) bond length is 1.34 Å. The Co(8)-Al(4) bond length is 2.53 Å. In the ninth Co site, Co(9) is bonded in a 2-coordinate geometry to one Rh(4) and one Co(18) atom. The Co(9)-Co(18) bond length is 1.34 Å. In the tenth Co site, Co(10) is bonded in a distorted single-bond geometry to one Rh(4) and one Co(13) atom. The Co(10)-Co(13) bond length is 0.47 Å. In the eleventh Co site, Co(11) is bonded in a distorted bent 120 degrees geometry to one Rh(3), one Co(2), and one Al(3) atom. The Co(11)-Al(3) bond length is 2.05 Å. In the twelfth Co site, Co(12) is bonded in a 2-coordinate geometry to one Rh(3), one Co(3), and one Al(3) atom. The Co(12)-Al(3) bond length is 2.53 Å. In the thirteenth Co site, Co(13) is bonded in a distorted single-bond geometry to one Rh(4) and one Co(10) atom. In the fourteenth Co site, Co(14) is bonded in a 2-coordinate geometry to one Rh(3) and one Co(5) atom. In the fifteenth Co site, Co(15) is bonded in a 2-coordinate geometry to one Rh(3), one Co(6), and one Al(3) atom. The Co(15)-Al(3) bond length is 2.70 Å. In the sixteenth Co site, Co(16) is bonded in a distorted single-bond geometry to one Co(2) and one Co(7) atom. In the seventeenth Co site, Co(17) is bonded in a 2-coordinate geometry to one Rh(1) and one Co(8) atom. In the eighteenth Co site, Co(18) is bonded in a 1-coordinate geometry to one Co(9) atom. In the nineteenth Co site, Co(19) is bonded in a single-bond geometry to one Co(22) atom. The Co(19)-Co(22) bond length is 0.81 Å. In the twentieth Co site, Co(20) is bonded in a 2-coordinate geometry to one Rh(4), one Co(23), and one Al(4) atom. The Co(20)-Co(23) bond length is 1.34 Å. The Co(20)-Al(4) bond length is 2.70 Å. In the twenty-first Co site, Co(21) is bonded in a distorted bent 120 degrees geometry to one Rh(4), one Co(24), and one Al(4) atom. The Co(21)-Co(24) bond length is 1.34 Å. The Co(21)-Al(4) bond length is 2.05 Å. In the twenty-second Co site, Co(22) is bonded in a distorted single-bond geometry to one Co(19), one Co(5), and one Co(6) atom. In the twenty-third Co site, Co(23) is bonded in a distorted single-bond geometry to one Co(20) atom. In the twenty-fourth Co site, Co(24) is bonded in a 2-coordinate geometry to one Rh(2) and one Co(21) atom. There are four inequivalent Al sites. In the first Al site, Al(1) is bonded in a distorted L-shaped geometry to one Rh(1), one Co(3), one Co(6), and one Al(2) atom. The Al(1)-Al(2) bond length is 0.37 Å. In the second Al site, Al(2) is bonded in a distorted L-shaped geometry to one Rh(2), one Co(2), one Co(5), and one Al(1) atom. In the third Al site, Al(3) is bonded in a 5-coordinate geometry to one Rh(3), one Co(11), one Co(12), one Co(15), and one Al(4) atom. The Al(3)-Al(4) bond length is 2.13 Å. In the fourth Al site, Al(4) is bonded in a 5-coordinate geometry to one Rh(4), one Co(20), one Co(21), one Co(8), and one Al(3) atom.