data_TiInTc2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.85
_cell_length_b   2.85
_cell_length_c   8.8
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   112.95
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiInTc2
_chemical_formula_sum   'Ti1 In1 Tc2'
_cell_volume   65.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti3  1  0.0  0.0  0.0  1.0
  In  In0  1  0.0  0.0  0.4  1.0
  Tc  Tc1  1  0.58  0.0  0.76  1.0
  Tc  Tc2  1  0.58  0.0  0.04  1.0

data_TiInTc2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.85
_cell_length_b   2.85
_cell_length_c   8.8
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   112.95
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiInTc2
_chemical_formula_sum   'Ti1 In1 Tc2'
_cell_volume   65.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.0  0.0  0.4  1.0
  Tc  Tc2  1  0.58  0.0  0.04  1.0
  Tc  Tc3  1  0.58  0.0  0.76  1.0

Ti In Tc Tc
TiTc2In crystallizes in the triclinic P1 space group. Ti(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Tc(1), two equivalent Tc(2), and one In(1) atom. There is one shorter (2.42 Å) and one longer (2.66 Å) Ti(1)-Tc(1) bond length. There is one shorter (1.26 Å) and one longer (1.68 Å) Ti(1)-Tc(2) bond length. The Ti(1)-In(1) bond length is 3.53 Å. There are two inequivalent Tc sites. In the first Tc site, Tc(1) is bonded in a 2-coordinate geometry to two equivalent Ti(1) and two equivalent In(1) atoms. There is one shorter (3.40 Å) and one longer (3.58 Å) Tc(1)-In(1) bond length. In the second Tc site, Tc(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Ti(1) and two equivalent In(1) atoms. There is one shorter (3.40 Å) and one longer (3.58 Å) Tc(2)-In(1) bond length. In(1) is bonded in a 11-coordinate geometry to one Ti(1), two equivalent Tc(1), two equivalent Tc(2), and six equivalent In(1) atoms. There are four shorter (2.85 Å) and two longer (3.15 Å) In(1)-In(1) bond lengths.