data_VAg2Te
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.03
_cell_length_b   3.03
_cell_length_c   9.03
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   92.49
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VAg2Te
_chemical_formula_sum   'V1 Ag2 Te1'
_cell_volume   82.62
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.09  0.0  0.89  1.0
  Ag  Ag1  1  0.09  0.0  0.14  1.0
  Te  Te2  1  0.0  0.0  0.51  1.0

data_VAg2Te
_symmetry_space_group_name_H-M   Pm
_cell_length_a   3.03
_cell_length_b   3.03
_cell_length_c   9.03
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   VAg2Te
_chemical_formula_sum   'V1 Ag2 Te1'
_cell_volume   82.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  Ag  Ag1  1  0.09  0.0  0.14  1.0
  Ag  Ag2  1  0.09  0.0  0.89  1.0
  Te  Te3  1  0.0  0.0  0.51  1.0

V Ag Ag Te
VAg2Te crystallizes in the monoclinic Pm space group. V(1) is bonded in a bent 150 degrees geometry to one Ag(1) and one Ag(2) atom. The V(1)-Ag(1) bond length is 1.07 Å. The V(1)-Ag(2) bond length is 1.29 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a single-bond geometry to one V(1) and one Te(1) atom. The Ag(1)-Te(1) bond length is 3.38 Å. In the second Ag site, Ag(2) is bonded in a single-bond geometry to one V(1) and one Te(1) atom. The Ag(2)-Te(1) bond length is 3.38 Å. Te(1) is bonded to one Ag(1), one Ag(2), and four equivalent Te(1) atoms to form a mixture of edge and corner-sharing TeAg2Te4 octahedra. The corner-sharing octahedra are not tilted. All Te(1)-Te(1) bond lengths are 3.03 Å.