data_LiTiV
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.17
_cell_length_b   5.17
_cell_length_c   5.17
_cell_angle_alpha   149.14
_cell_angle_beta   140.84
_cell_angle_gamma   50.67
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiTiV
_chemical_formula_sum   'Li1 Ti1 V1'
_cell_volume   44.55
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.32  1.0
  Ti  Ti1  1  0.0  0.0  0.3  1.0
  V  V2  1  0.0  0.0  0.08  1.0

data_LiTiV
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.75
_cell_length_b   3.47
_cell_length_c   5.17
_cell_angle_alpha   109.58
_cell_angle_beta   105.43
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiTiV
_chemical_formula_sum   'Li1 Ti1 V1'
_cell_volume   44.55
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.68  0.68  0.68  1.0
  Ti  Ti1  1  0.7  0.7  0.7  1.0
  V  V2  1  0.92  0.92  0.92  1.0

Li Ti V
LiVTi crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LiVTi cluster. Li(1) is bonded in a single-bond geometry to one Ti(1) atom. The Li(1)-Ti(1) bond length is 0.10 Å. Ti(1) is bonded in a distorted single-bond geometry to one Li(1) and one V(1) atom. The Ti(1)-V(1) bond length is 1.14 Å. V(1) is bonded in a single-bond geometry to one Ti(1) atom.