data_ZnCdSn2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.27
_cell_length_b   3.27
_cell_length_c   9.6
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   110.6
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnCdSn2
_chemical_formula_sum   'Zn1 Cd1 Sn2'
_cell_volume   96.12
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.0  0.73  1.0
  Cd  Cd0  1  0.86  0.0  0.65  1.0
  Sn  Sn1  1  0.0  0.0  0.08  1.0
  Sn  Sn2  1  0.86  0.0  0.94  1.0

data_ZnCdSn2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.27
_cell_length_b   3.27
_cell_length_c   9.6
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   110.6
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnCdSn2
_chemical_formula_sum   'Zn1 Cd1 Sn2'
_cell_volume   96.12
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.0  0.0  0.73  1.0
  Cd  Cd1  1  0.86  0.0  0.65  1.0
  Sn  Sn2  1  0.0  0.0  0.08  1.0
  Sn  Sn3  1  0.86  0.0  0.94  1.0

Zn Cd Sn Sn
CdZnSn2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one CdZnSn2 cluster. Cd(1) is bonded in a single-bond geometry to one Zn(1) atom. The Cd(1)-Zn(1) bond length is 0.90 Å. Zn(1) is bonded in a 2-coordinate geometry to one Cd(1) and one Sn(2) atom. The Zn(1)-Sn(2) bond length is 2.07 Å. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a single-bond geometry to one Sn(2) atom. The Sn(1)-Sn(2) bond length is 1.43 Å. In the second Sn site, Sn(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sn(1) atom.