data_TiRe2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.19
_cell_length_b   6.05
_cell_length_c   6.05
_cell_angle_alpha   30.22
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiRe2P
_chemical_formula_sum   'Ti1 Re2 P1'
_cell_volume   58.67
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti3  1  0.59  0.0  0.34  1.0
  Re  Re1  1  0.59  0.0  0.2  1.0
  Re  Re2  1  0.0  0.0  0.52  1.0
  P  P0  1  0.0  0.0  0.42  1.0

data_TiRe2P
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.15
_cell_length_b   3.19
_cell_length_c   6.05
_cell_angle_alpha   90.0
_cell_angle_beta   105.11
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiRe2P
_chemical_formula_sum   'Ti1 Re2 P1'
_cell_volume   58.67
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.66  0.59  0.66  1.0
  Re  Re1  1  0.48  0.0  0.48  1.0
  Re  Re2  1  0.8  0.59  0.8  1.0
  P  P3  1  0.58  0.0  0.58  1.0

Ti Re Re P
TiRe2P crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one TiRe2P cluster. Ti(1) is bonded in a 2-coordinate geometry to one Re(1) and one P(1) atom. The Ti(1)-Re(1) bond length is 0.85 Å. The Ti(1)-P(1) bond length is 1.37 Å. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a single-bond geometry to one Ti(1) atom. In the second Re site, Re(2) is bonded in a single-bond geometry to one P(1) atom. The Re(2)-P(1) bond length is 0.64 Å. P(1) is bonded in a 2-coordinate geometry to one Ti(1) and one Re(2) atom.