data_LaVPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.41
_cell_length_b   3.75
_cell_length_c   6.34
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaVPd2
_chemical_formula_sum   'La1 V1 Pd2'
_cell_volume   80.95
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.7  0.88  0.89  1.0
  V  V3  1  0.0  0.0  0.73  1.0
  Pd  Pd1  1  0.0  0.0  0.12  1.0
  Pd  Pd2  1  0.7  0.88  0.77  1.0

data_LaVPd2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.41
_cell_length_b   3.75
_cell_length_c   6.34
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaVPd2
_chemical_formula_sum   'La1 V1 Pd2'
_cell_volume   80.95
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.7  0.88  0.89  1.0
  V  V1  1  0.0  0.0  0.73  1.0
  Pd  Pd2  1  0.0  0.0  0.12  1.0
  Pd  Pd3  1  0.7  0.88  0.77  1.0

La V Pd Pd
LaVPd2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LaVPd2 cluster. La(1) is bonded in a distorted single-bond geometry to one Pd(1) and one Pd(2) atom. The La(1)-Pd(1) bond length is 1.82 Å. The La(1)-Pd(2) bond length is 0.76 Å. V(1) is bonded in a distorted single-bond geometry to one Pd(2) atom. The V(1)-Pd(2) bond length is 1.15 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted single-bond geometry to one La(1) atom. In the second Pd site, Pd(2) is bonded in a distorted single-bond geometry to one La(1) and one V(1) atom.