data_Pd2AuCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.31
_cell_length_b   5.31
_cell_length_c   5.31
_cell_angle_alpha   146.66
_cell_angle_beta   119.92
_cell_angle_gamma   70.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Pd2AuCl
_chemical_formula_sum   'Pd2 Au1 Cl1'
_cell_volume   70.08
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd2  1  0.52  0.0  0.04  1.0
  Pd  Pd3  1  0.0  0.66  0.29  1.0
  Au  Au0  1  0.0  0.0  0.33  1.0
  Cl  Cl1  1  0.0  0.0  0.0  1.0

data_Pd2AuCl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.04
_cell_length_b   5.31
_cell_length_c   5.31
_cell_angle_alpha   60.08
_cell_angle_beta   73.33
_cell_angle_gamma   73.33
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Pd2AuCl
_chemical_formula_sum   'Pd2 Au1 Cl1'
_cell_volume   70.08
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.29  0.0  0.37  1.0
  Pd  Pd1  1  0.52  0.52  0.96  1.0
  Au  Au2  1  0.33  0.0  0.67  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Pd Pd Au Cl
Pd2AuCl crystallizes in the triclinic P1 space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 3-coordinate geometry to one Au(1) and two equivalent Cl(1) atoms. The Pd(1)-Au(1) bond length is 2.21 Å. Both Pd(1)-Cl(1) bond lengths are 2.66 Å. In the second Pd site, Pd(2) is bonded in a 3-coordinate geometry to one Au(1) and two equivalent Cl(1) atoms. The Pd(2)-Au(1) bond length is 1.63 Å. There is one shorter (2.36 Å) and one longer (2.46 Å) Pd(2)-Cl(1) bond length. Au(1) is bonded in a 3-coordinate geometry to one Pd(1), one Pd(2), and one Cl(1) atom. The Au(1)-Cl(1) bond length is 1.77 Å. Cl(1) is bonded in a 5-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), and one Au(1) atom.