data_ScInRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.26
_cell_length_b   3.26
_cell_length_c   6.35
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScInRh2
_chemical_formula_sum   'Sc1 In1 Rh2'
_cell_volume   67.3
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc3  1  0.0  0.0  0.0  1.0
  In  In0  1  0.0  0.0  0.17  1.0
  Rh  Rh1  1  0.63  0.63  0.78  1.0
  Rh  Rh2  1  0.63  0.63  0.57  1.0

data_ScInRh2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.6
_cell_length_b   4.6
_cell_length_c   6.35
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ScInRh2
_chemical_formula_sum   'Sc2 In2 Rh4'
_cell_volume   134.6
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  2  0.0  0.0  0.0  1.0
  In  In1  2  0.0  0.0  0.17  1.0
  Rh  Rh2  2  0.13  0.5  0.57  1.0
  Rh  Rh3  2  0.13  0.5  0.78  1.0

Sc In Rh Rh
ScRh2In crystallizes in the monoclinic Cm space group. Sc(1) is bonded in a 2-coordinate geometry to three equivalent Rh(1) and one In(1) atom. There is one shorter (2.20 Å) and two longer (2.75 Å) Sc(1)-Rh(1) bond lengths. The Sc(1)-In(1) bond length is 1.10 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 4-coordinate geometry to three equivalent Sc(1) and one Rh(2) atom. The Rh(1)-Rh(2) bond length is 1.38 Å. In the second Rh site, Rh(2) is bonded in a 2-coordinate geometry to one Rh(1) and one In(1) atom. The Rh(2)-In(1) bond length is 3.02 Å. In(1) is bonded in a single-bond geometry to one Sc(1) and one Rh(2) atom.