data_FeSbCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.97
_cell_length_b   3.61
_cell_length_c   6.29
_cell_angle_alpha   90.0
_cell_angle_beta   103.02
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   FeSbCl2
_chemical_formula_sum   'Fe1 Sb1 Cl2'
_cell_volume   87.82
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe2  1  0.07  0.0  0.61  1.0
  Sb  Sb3  1  0.18  0.8  0.77  1.0
  Cl  Cl0  1  0.52  0.0  0.92  1.0
  Cl  Cl1  1  0.59  0.8  0.02  1.0

data_FeSbCl2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.61
_cell_length_b   3.97
_cell_length_c   6.29
_cell_angle_alpha   103.02
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   FeSbCl2
_chemical_formula_sum   'Fe1 Sb1 Cl2'
_cell_volume   87.82
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.0  0.93  0.39  1.0
  Sb  Sb1  1  0.2  0.82  0.23  1.0
  Cl  Cl2  1  0.0  0.48  0.08  1.0
  Cl  Cl3  1  0.2  0.41  0.98  1.0

Fe Sb Cl Cl
FeSbCl2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one FeSbCl2 cluster. Fe(1) is bonded in a single-bond geometry to one Sb(1) atom. The Fe(1)-Sb(1) bond length is 1.23 Å. Sb(1) is bonded in a distorted water-like geometry to one Fe(1), one Cl(1), and one Cl(2) atom. The Sb(1)-Cl(1) bond length is 1.60 Å. The Sb(1)-Cl(2) bond length is 1.99 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 2-coordinate geometry to one Sb(1) and one Cl(2) atom. The Cl(1)-Cl(2) bond length is 0.96 Å. In the second Cl site, Cl(2) is bonded in a 2-coordinate geometry to one Sb(1) and one Cl(1) atom.