data_RhW2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.35
_cell_length_b   5.35
_cell_length_c   5.35
_cell_angle_alpha   148.16
_cell_angle_beta   129.74
_cell_angle_gamma   60.74
_symmetry_Int_Tables_number   1
_chemical_formula_structural   RhW2Cl
_chemical_formula_sum   'Rh1 W2 Cl1'
_cell_volume   61.52
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh1  1  0.0  0.0  0.61  1.0
  W  W2  1  0.47  0.0  0.11  1.0
  W  W3  1  0.0  0.27  0.5  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_RhW2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.93
_cell_length_b   4.54
_cell_length_c   5.35
_cell_angle_alpha   115.13
_cell_angle_beta   105.92
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   RhW2Cl
_chemical_formula_sum   'Rh1 W2 Cl1'
_cell_volume   61.52
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.0  0.61  0.61  1.0
  W  W1  1  0.0  0.11  0.64  1.0
  W  W2  1  0.73  0.23  0.23  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Rh W W Cl
W2RhCl crystallizes in the triclinic P1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 1-coordinate geometry to two equivalent Rh(1) and one Cl(1) atom. There is one shorter (2.19 Å) and one longer (2.36 Å) W(1)-Rh(1) bond length. The W(1)-Cl(1) bond length is 2.17 Å. In the second W site, W(2) is bonded in a 3-coordinate geometry to one Rh(1) and two equivalent Cl(1) atoms. The W(2)-Rh(1) bond length is 1.98 Å. There is one shorter (1.65 Å) and one longer (2.16 Å) W(2)-Cl(1) bond length. Rh(1) is bonded in a 4-coordinate geometry to one W(2), two equivalent W(1), and one Cl(1) atom. The Rh(1)-Cl(1) bond length is 2.06 Å. Cl(1) is bonded in a 4-coordinate geometry to one W(1), two equivalent W(2), and one Rh(1) atom.