data_KV2Mo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.21
_cell_length_b   5.21
_cell_length_c   2.6
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KV2Mo
_chemical_formula_sum   'K1 V2 Mo1'
_cell_volume   70.52
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.0  0.0  1.0
  V  V2  1  0.61  0.0  0.3  1.0
  V  V3  1  0.0  0.61  0.3  1.0
  Mo  Mo1  1  0.61  0.61  0.0  1.0

data_KV2Mo
_symmetry_space_group_name_H-M   Cm
_cell_length_a   7.37
_cell_length_b   7.37
_cell_length_c   2.6
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   KV2Mo
_chemical_formula_sum   'K2 V4 Mo2'
_cell_volume   141.05
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  2  0.0  0.0  0.0  1.0
  V  V1  4  0.3  0.3  0.3  1.0
  Mo  Mo2  2  0.11  0.5  0.0  1.0

K V V Mo
KV2Mo crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two KV2Mo clusters. K(1) is bonded in a distorted L-shaped geometry to two equivalent V(1) atoms. Both K(1)-V(1) bond lengths are 2.20 Å. V(1) is bonded in a 2-coordinate geometry to one K(1) and one Mo(1) atom. The V(1)-Mo(1) bond length is 2.20 Å. Mo(1) is bonded in a distorted L-shaped geometry to two equivalent V(1) atoms.