data_SbIr2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.7
_cell_length_b   4.7
_cell_length_c   3.13
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   94.23
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SbIr2Cl
_chemical_formula_sum   'Sb1 Ir2 Cl1'
_cell_volume   68.88
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb3  1  0.2  0.0  0.0  1.0
  Ir  Ir1  1  0.6  0.72  0.56  1.0
  Ir  Ir2  1  0.6  0.28  0.56  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_SbIr2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.13
_cell_length_b   4.7
_cell_length_c   4.7
_cell_angle_alpha   94.23
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SbIr2Cl
_chemical_formula_sum   'Sb1 Ir2 Cl1'
_cell_volume   68.88
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  -0.0  0.2  0.0  1.0
  Ir  Ir1  1  0.56  0.6  0.28  1.0
  Ir  Ir2  1  0.56  0.6  0.72  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Sb Ir Ir Cl
Ir2SbCl crystallizes in the triclinic P1 space group. There are two inequivalent Ir sites. In the first Ir site, Ir(1) is bonded in a 8-coordinate geometry to two equivalent Ir(1), two equivalent Ir(2), two equivalent Sb(1), and two equivalent Cl(1) atoms. Both Ir(1)-Ir(1) bond lengths are 3.13 Å. There is one shorter (2.08 Å) and one longer (2.62 Å) Ir(1)-Ir(2) bond length. There is one shorter (2.74 Å) and one longer (2.96 Å) Ir(1)-Sb(1) bond length. There is one shorter (2.60 Å) and one longer (2.83 Å) Ir(1)-Cl(1) bond length. In the second Ir site, Ir(2) is bonded in a 8-coordinate geometry to two equivalent Ir(1), two equivalent Ir(2), two equivalent Sb(1), and two equivalent Cl(1) atoms. Both Ir(2)-Ir(2) bond lengths are 3.13 Å. There is one shorter (2.60 Å) and one longer (2.83 Å) Ir(2)-Sb(1) bond length. There is one shorter (2.74 Å) and one longer (2.96 Å) Ir(2)-Cl(1) bond length. Sb(1) is bonded in a single-bond geometry to two equivalent Ir(1), two equivalent Ir(2), and one Cl(1) atom. The Sb(1)-Cl(1) bond length is 0.93 Å. Cl(1) is bonded in a single-bond geometry to two equivalent Ir(1), two equivalent Ir(2), and one Sb(1) atom.