data_NaPdRu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.92
_cell_length_b   9.92
_cell_length_c   9.92
_cell_angle_alpha   15.85
_cell_angle_beta   15.85
_cell_angle_gamma   15.85
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaPdRu2
_chemical_formula_sum   'Na1 Pd1 Ru2'
_cell_volume   63.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.0  1.0
  Pd  Pd1  1  0.0  0.0  0.7  1.0
  Ru  Ru2  1  0.0  0.0  0.25  1.0
  Ru  Ru3  1  0.0  0.0  0.14  1.0

data_NaPdRu2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.74
_cell_length_b   2.74
_cell_length_c   9.92
_cell_angle_alpha   90.0
_cell_angle_beta   99.16
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   NaPdRu2
_chemical_formula_sum   'Na2 Pd2 Ru4'
_cell_volume   127.08
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  2  0.0  0.0  0.0  1.0
  Pd  Pd1  2  0.0  0.0  0.3  1.0
  Ru  Ru2  2  0.0  0.0  0.75  1.0
  Ru  Ru3  2  0.0  0.0  0.86  1.0

Na Pd Ru Ru
NaRu2Pd crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two NaRu2Pd clusters. Na(1) is bonded in a single-bond geometry to one Ru(2) and one Pd(1) atom. The Na(1)-Ru(2) bond length is 1.40 Å. The Na(1)-Pd(1) bond length is 3.03 Å. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a single-bond geometry to one Ru(2) atom. The Ru(1)-Ru(2) bond length is 1.07 Å. In the second Ru site, Ru(2) is bonded in a distorted linear geometry to one Na(1) and one Ru(1) atom. Pd(1) is bonded in a distorted single-bond geometry to one Na(1) atom.