data_Cr2InTc
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.83
_cell_length_b   4.83
_cell_length_c   4.83
_cell_angle_alpha   133.53
_cell_angle_beta   133.53
_cell_angle_gamma   67.82
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cr2InTc
_chemical_formula_sum   'Cr2 In1 Tc1'
_cell_volume   58.31
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.0  0.91  0.01  1.0
  Cr  Cr1  1  0.0  0.0  0.0  1.0
  In  In2  1  0.91  0.0  0.01  1.0
  Tc  Tc3  1  0.0  0.0  0.01  1.0

data_Cr2InTc
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.39
_cell_length_b   5.39
_cell_length_c   4.83
_cell_angle_alpha   90.0
_cell_angle_beta   123.91
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Cr2InTc
_chemical_formula_sum   'Cr4 In2 Tc2'
_cell_volume   116.61
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  2  0.0  0.0  0.0  1.0
  Cr  Cr1  2  0.41  0.5  0.9  1.0
  In  In2  2  0.0  0.0  0.9  1.0
  Tc  Tc3  2  0.5  0.5  0.99  1.0

Cr Cr In Tc
Cr2TcIn is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Cr2TcIn cluster. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a distorted single-bond geometry to one Tc(1) atom. The Cr(1)-Tc(1) bond length is 0.43 Å. In the second Cr site, Cr(2) is bonded in a single-bond geometry to one Tc(1) atom. The Cr(2)-Tc(1) bond length is 0.05 Å. Tc(1) is bonded in a distorted single-bond geometry to one Cr(1), one Cr(2), and one In(1) atom. The Tc(1)-In(1) bond length is 0.43 Å. In(1) is bonded in a distorted single-bond geometry to one Tc(1) atom.