data_CaLaCo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.79
_cell_length_b   4.79
_cell_length_c   3.48
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CaLaCo2
_chemical_formula_sum   'Ca1 La1 Co2'
_cell_volume   79.96
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.0  0.0  0.0  1.0
  La  La3  1  0.4  0.4  0.0  1.0
  Co  Co1  1  0.0  0.4  0.74  1.0
  Co  Co2  1  0.4  0.0  0.74  1.0

data_CaLaCo2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.78
_cell_length_b   6.78
_cell_length_c   3.48
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   CaLaCo2
_chemical_formula_sum   'Ca2 La2 Co4'
_cell_volume   159.92
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  2  0.0  0.0  0.0  1.0
  La  La1  2  0.4  0.0  -0.0  1.0
  Co  Co2  4  0.2  0.2  0.74  1.0

Ca La Co Co
CaLaCo2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two CaLaCo2 clusters. Ca(1) is bonded in a 2-coordinate geometry to two equivalent Co(1) atoms. Both Ca(1)-Co(1) bond lengths are 2.11 Å. La(1) is bonded in a 2-coordinate geometry to two equivalent Co(1) atoms. Both La(1)-Co(1) bond lengths are 2.11 Å. Co(1) is bonded in a 2-coordinate geometry to one Ca(1) and one La(1) atom.