data_LaPPt
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.25
_cell_length_b   4.25
_cell_length_c   8.15
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaPPt
_chemical_formula_sum   'La2 P2 Pt2'
_cell_volume   127.4
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.0  0.0  1.0
  La  La1  1  0.0  0.0  0.07  1.0
  P  P2  1  0.12  0.23  0.11  1.0
  P  P3  1  0.0  0.45  0.04  1.0
  Pt  Pt4  1  0.0  0.45  0.11  1.0
  Pt  Pt5  1  0.12  0.23  0.04  1.0

data_LaPPt
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.25
_cell_length_b   4.25
_cell_length_c   8.15
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaPPt
_chemical_formula_sum   'La2 P2 Pt2'
_cell_volume   127.4
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.0  0.0  1.0
  La  La1  1  0.0  0.0  0.07  1.0
  P  P2  1  0.0  0.45  0.04  1.0
  P  P3  1  0.12  0.23  0.11  1.0
  Pt  Pt4  1  0.0  0.45  0.11  1.0
  Pt  Pt5  1  0.12  0.23  0.04  1.0

La La P P Pt Pt
LaPtP crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one La2PtP cluster and one PtP cluster. In the La2PtP cluster, there are two inequivalent La sites. In the first La site, La(1) is bonded in a 2-coordinate geometry to one La(2) and one Pt(2) atom. The La(1)-La(2) bond length is 0.59 Å. The La(1)-Pt(2) bond length is 0.89 Å. In the second La site, La(2) is bonded in a 3-coordinate geometry to one La(1), one Pt(2), and one P(1) atom. The La(2)-Pt(2) bond length is 0.89 Å. The La(2)-P(1) bond length is 0.89 Å. Pt(2) is bonded in a 2-coordinate geometry to one La(1), one La(2), and one P(1) atom. The Pt(2)-P(1) bond length is 0.59 Å. P(1) is bonded in a distorted single-bond geometry to one La(2) and one Pt(2) atom. In the PtP cluster, Pt(1) is bonded in a single-bond geometry to one P(2) atom. The Pt(1)-P(2) bond length is 0.59 Å. P(2) is bonded in a single-bond geometry to one Pt(1) atom.