data_Li2TcRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.68
_cell_length_b   2.68
_cell_length_c   9.4
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   116.6
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2TcRh
_chemical_formula_sum   'Li2 Tc1 Rh1'
_cell_volume   60.23
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.41  0.0  0.13  1.0
  Li  Li1  1  0.0  0.0  0.85  1.0
  Tc  Tc3  1  0.0  0.0  0.46  1.0
  Rh  Rh2  1  0.41  0.0  0.67  1.0

data_Li2TcRh
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.68
_cell_length_b   2.68
_cell_length_c   9.4
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   116.6
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2TcRh
_chemical_formula_sum   'Li2 Tc1 Rh1'
_cell_volume   60.23
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.85  1.0
  Li  Li1  1  0.41  0.0  0.13  1.0
  Tc  Tc2  1  0.0  0.0  0.46  1.0
  Rh  Rh3  1  0.41  0.0  0.67  1.0

Li Li Tc Rh
Li2TcRh crystallizes in the triclinic P1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 10-coordinate geometry to two equivalent Li(2), six equivalent Li(1), and two equivalent Tc(1) atoms. There is one shorter (2.80 Å) and one longer (3.03 Å) Li(1)-Li(2) bond length. There are four shorter (2.68 Å) and two longer (2.81 Å) Li(1)-Li(1) bond lengths. There is one shorter (3.32 Å) and one longer (3.51 Å) Li(1)-Tc(1) bond length. In the second Li site, Li(2) is bonded in a 2-coordinate geometry to two equivalent Li(1) and two equivalent Rh(1) atoms. There is one shorter (2.03 Å) and one longer (2.34 Å) Li(2)-Rh(1) bond length. Tc(1) is bonded in a 2-coordinate geometry to two equivalent Li(1) and two equivalent Rh(1) atoms. There is one shorter (2.25 Å) and one longer (2.53 Å) Tc(1)-Rh(1) bond length. Rh(1) is bonded in a 4-coordinate geometry to two equivalent Li(2) and two equivalent Tc(1) atoms.