data_TiAg2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.82
_cell_length_b   4.82
_cell_length_c   2.83
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiAg2
_chemical_formula_sum   'Ti1 Ag2'
_cell_volume   65.61
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti2  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.0  0.41  0.41  1.0
  Ag  Ag1  1  0.41  0.0  0.41  1.0

data_TiAg2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.81
_cell_length_b   6.81
_cell_length_c   2.83
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TiAg2
_chemical_formula_sum   'Ti2 Ag4'
_cell_volume   131.23
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  2  0.0  0.0  0.0  1.0
  Ag  Ag1  4  0.2  0.2  0.41  1.0

Ti Ag Ag
TiAg2 crystallizes in the monoclinic Cm space group. Ti(1) is bonded in a 10-coordinate geometry to two equivalent Ti(1) and eight equivalent Ag(1) atoms. Both Ti(1)-Ti(1) bond lengths are 2.83 Å. There are a spread of Ti(1)-Ag(1) bond distances ranging from 2.29-3.29 Å. Ag(1) is bonded in a 2-coordinate geometry to four equivalent Ti(1) atoms.