data_Cd2CoRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.57
_cell_length_b   4.57
_cell_length_c   3.12
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   95.85
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2CoRh
_chemical_formula_sum   'Cd2 Co1 Rh1'
_cell_volume   64.88
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.53  0.7  0.56  1.0
  Cd  Cd1  1  0.53  0.3  0.56  1.0
  Co  Co2  1  0.0  0.0  0.0  1.0
  Rh  Rh3  1  0.06  0.0  0.0  1.0

data_Cd2CoRh
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.12
_cell_length_b   4.57
_cell_length_c   4.57
_cell_angle_alpha   95.85
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2CoRh
_chemical_formula_sum   'Cd2 Co1 Rh1'
_cell_volume   64.88
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.56  0.53  0.3  1.0
  Cd  Cd1  1  0.56  0.53  0.7  1.0
  Co  Co2  1  0.0  0.0  0.0  1.0
  Rh  Rh3  1  0.0  0.06  0.0  1.0

Cd Cd Co Rh
RhCoCd2 crystallizes in the triclinic P1 space group. Rh(1) is bonded in a single-bond geometry to one Co(1), two equivalent Cd(1), and two equivalent Cd(2) atoms. The Rh(1)-Co(1) bond length is 0.29 Å. There is one shorter (3.00 Å) and one longer (3.18 Å) Rh(1)-Cd(1) bond length. There is one shorter (2.79 Å) and one longer (2.99 Å) Rh(1)-Cd(2) bond length. Co(1) is bonded in a single-bond geometry to one Rh(1), two equivalent Cd(1), and two equivalent Cd(2) atoms. There is one shorter (2.79 Å) and one longer (2.99 Å) Co(1)-Cd(1) bond length. There is one shorter (3.00 Å) and one longer (3.18 Å) Co(1)-Cd(2) bond length. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 8-coordinate geometry to two equivalent Rh(1), two equivalent Co(1), two equivalent Cd(1), and two equivalent Cd(2) atoms. Both Cd(1)-Cd(1) bond lengths are 3.12 Å. There is one shorter (1.80 Å) and one longer (2.77 Å) Cd(1)-Cd(2) bond length. In the second Cd site, Cd(2) is bonded in a 8-coordinate geometry to two equivalent Rh(1), two equivalent Co(1), two equivalent Cd(1), and two equivalent Cd(2) atoms. Both Cd(2)-Cd(2) bond lengths are 3.12 Å.