data_Sn2BRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.67
_cell_length_b   4.67
_cell_length_c   4.67
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sn2BRh
_chemical_formula_sum   'Sn2 B1 Rh1'
_cell_volume   71.79
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn2  1  0.3  0.3  0.3  1.0
  Sn  Sn3  1  0.65  0.65  0.65  1.0
  B  B0  1  0.0  0.0  0.0  1.0
  Rh  Rh1  1  0.95  0.95  0.95  1.0

data_Sn2BRh
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.67
_cell_length_b   4.67
_cell_length_c   11.43
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   Sn2BRh
_chemical_formula_sum   'Sn6 B3 Rh3'
_cell_volume   215.38
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  3  0.0  0.0  0.35  1.0
  Sn  Sn1  3  0.0  0.0  0.7  1.0
  B  B2  3  0.0  0.0  0.0  1.0
  Rh  Rh3  3  0.0  0.0  0.05  1.0

Sn Sn B Rh
RhBSn2 crystallizes in the trigonal R3m space group. Rh(1) is bonded in a single-bond geometry to one B(1), three equivalent Sn(1), and four equivalent Sn(2) atoms. The Rh(1)-B(1) bond length is 0.59 Å. All Rh(1)-Sn(1) bond lengths are 2.70 Å. There are three shorter (2.72 Å) and one longer (3.41 Å) Rh(1)-Sn(2) bond length. B(1) is bonded in a single-bond geometry to one Rh(1), three equivalent Sn(1), and three equivalent Sn(2) atoms. All B(1)-Sn(1) bond lengths are 2.72 Å. All B(1)-Sn(2) bond lengths are 2.70 Å. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a distorted q6 geometry to three equivalent Rh(1), three equivalent B(1), and three equivalent Sn(2) atoms. All Sn(1)-Sn(2) bond lengths are 2.70 Å. In the second Sn site, Sn(2) is bonded in a distorted q6 geometry to four equivalent Rh(1), three equivalent B(1), and three equivalent Sn(1) atoms.