data_V2RhSe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.41
_cell_length_b   4.41
_cell_length_c   2.95
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   97.81
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2RhSe
_chemical_formula_sum   'V2 Rh1 Se1'
_cell_volume   56.94
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.45  0.66  0.48  1.0
  V  V3  1  0.45  0.34  0.48  1.0
  Rh  Rh0  1  0.9  0.0  0.0  1.0
  Se  Se1  1  0.0  0.0  0.0  1.0

data_V2RhSe
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.95
_cell_length_b   4.41
_cell_length_c   4.41
_cell_angle_alpha   97.81
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2RhSe
_chemical_formula_sum   'V2 Rh1 Se1'
_cell_volume   56.94
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.48  0.45  0.34  1.0
  V  V1  1  0.48  0.45  0.66  1.0
  Rh  Rh2  1  0.0  0.9  0.0  1.0
  Se  Se3  1  0.0  0.0  0.0  1.0

V V Rh Se
V2RhSe crystallizes in the triclinic P1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one V(2), two equivalent Rh(1), and two equivalent Se(1) atoms. The V(1)-V(2) bond length is 1.43 Å. There is one shorter (2.71 Å) and one longer (2.78 Å) V(1)-Rh(1) bond length. There is one shorter (2.99 Å) and one longer (3.06 Å) V(1)-Se(1) bond length. In the second V site, V(2) is bonded in a 5-coordinate geometry to one V(1), two equivalent Rh(1), and two equivalent Se(1) atoms. There is one shorter (2.99 Å) and one longer (3.06 Å) V(2)-Rh(1) bond length. There is one shorter (2.71 Å) and one longer (2.78 Å) V(2)-Se(1) bond length. Rh(1) is bonded in a single-bond geometry to two equivalent V(1), two equivalent V(2), and one Se(1) atom. The Rh(1)-Se(1) bond length is 0.45 Å. Se(1) is bonded in a single-bond geometry to two equivalent V(1), two equivalent V(2), and one Rh(1) atom.