data_Sc2SnCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.43
_cell_length_b   3.59
_cell_length_c   7.32
_cell_angle_alpha   90.0
_cell_angle_beta   91.88
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sc2SnCl
_chemical_formula_sum   'Sc2 Sn1 Cl1'
_cell_volume   89.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc1  1  0.29  0.79  0.85  1.0
  Sc  Sc2  1  0.9  0.79  0.47  1.0
  Sn  Sn3  1  0.59  0.0  0.66  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Sc2SnCl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.43
_cell_length_b   3.59
_cell_length_c   7.32
_cell_angle_alpha   90.0
_cell_angle_beta   91.88
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sc2SnCl
_chemical_formula_sum   'Sc2 Sn1 Cl1'
_cell_volume   89.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.29  0.79  0.85  1.0
  Sc  Sc1  1  0.9  0.79  0.47  1.0
  Sn  Sn2  1  0.59  0.0  0.66  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Sc Sc Sn Cl
Sc2SnCl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Sc2SnCl cluster. There are two inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in a 2-coordinate geometry to one Sn(1) and one Cl(1) atom. The Sc(1)-Sn(1) bond length is 1.92 Å. The Sc(1)-Cl(1) bond length is 1.68 Å. In the second Sc site, Sc(2) is bonded in a distorted single-bond geometry to one Sn(1) atom. The Sc(2)-Sn(1) bond length is 1.92 Å. Sn(1) is bonded in a 2-coordinate geometry to one Sc(1) and one Sc(2) atom. Cl(1) is bonded in a distorted single-bond geometry to one Sc(1) atom.