data_VSnSb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.47
_cell_length_b   7.33
_cell_length_c   3.11
_cell_angle_alpha   80.27
_cell_angle_beta   75.5
_cell_angle_gamma   24.23
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VSnSb
_chemical_formula_sum   'V1 Sn1 Sb1'
_cell_volume   66.88
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.96  0.41  0.75  1.0
  Sn  Sn1  1  0.96  0.41  0.8  1.0
  Sb  Sb0  1  0.96  0.41  0.72  1.0

data_VSnSb
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.93
_cell_length_b   14.13
_cell_length_c   3.11
_cell_angle_alpha   90.0
_cell_angle_beta   129.16
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VSnSb
_chemical_formula_sum   'V2 Sn2 Sb2'
_cell_volume   133.77
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.46  0.5  0.71  1.0
  Sn  Sn1  2  0.46  0.5  0.76  1.0
  Sb  Sb2  2  0.46  0.5  0.68  1.0

V Sn Sb
VSnSb is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two VSnSb clusters. V(1) is bonded in a linear geometry to one Sn(1) and one Sb(1) atom. The V(1)-Sn(1) bond length is 0.17 Å. The V(1)-Sb(1) bond length is 0.08 Å. Sn(1) is bonded in a single-bond geometry to one V(1) atom. Sb(1) is bonded in a single-bond geometry to one V(1) atom.