data_Ti2SbP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.67
_cell_length_b   6.67
_cell_length_c   6.67
_cell_angle_alpha   150.92
_cell_angle_beta   149.22
_cell_angle_gamma   42.86
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ti2SbP
_chemical_formula_sum   'Ti2 Sb1 P1'
_cell_volume   73.69
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti2  1  0.0  0.0  0.13  1.0
  Ti  Ti3  1  0.0  0.77  0.28  1.0
  Sb  Sb1  1  0.67  0.0  0.73  1.0
  P  P0  1  0.0  0.0  0.7  1.0

data_Ti2SbP
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.35
_cell_length_b   3.54
_cell_length_c   6.67
_cell_angle_alpha   105.39
_cell_angle_beta   104.54
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ti2SbP
_chemical_formula_sum   'Ti2 Sb1 P1'
_cell_volume   73.69
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.72  0.49  0.49  1.0
  Ti  Ti1  1  0.87  0.87  0.87  1.0
  Sb  Sb2  1  0.95  0.27  0.95  1.0
  P  P3  1  0.3  0.3  0.3  1.0

Ti Ti Sb P
TiSbTiP crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one titanium phosphide molecule and one TiSb cluster. In the TiSb cluster, Ti(1) is bonded in a 1-coordinate geometry to one Sb(1) atom. The Ti(1)-Sb(1) bond length is 1.37 Å. Sb(1) is bonded in a 1-coordinate geometry to one Ti(1) atom.