data_Ti2AgCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.82
_cell_length_b   4.82
_cell_length_c   2.92
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   95.48
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ti2AgCl
_chemical_formula_sum   'Ti2 Ag1 Cl1'
_cell_volume   67.55
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti2  1  0.62  0.78  0.46  1.0
  Ti  Ti3  1  0.62  0.22  0.46  1.0
  Ag  Ag0  1  0.24  0.0  0.0  1.0
  Cl  Cl1  1  0.0  0.0  0.0  1.0

data_Ti2AgCl
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.92
_cell_length_b   4.82
_cell_length_c   4.82
_cell_angle_alpha   95.48
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ti2AgCl
_chemical_formula_sum   'Ti2 Ag1 Cl1'
_cell_volume   67.55
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.46  0.62  0.22  1.0
  Ti  Ti1  1  0.46  0.62  0.78  1.0
  Ag  Ag2  1  0.0  0.24  0.0  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Ti Ti Ag Cl
Ti2AgCl crystallizes in the triclinic P1 space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 2-coordinate geometry to two equivalent Ti(2) and two equivalent Cl(1) atoms. There is one shorter (2.09 Å) and one longer (2.73 Å) Ti(1)-Ti(2) bond length. There is one shorter (2.43 Å) and one longer (2.56 Å) Ti(1)-Cl(1) bond length. In the second Ti site, Ti(2) is bonded in a 8-coordinate geometry to two equivalent Ti(1), two equivalent Ti(2), two equivalent Ag(1), and two equivalent Cl(1) atoms. Both Ti(2)-Ti(2) bond lengths are 2.92 Å. There is one shorter (2.43 Å) and one longer (2.56 Å) Ti(2)-Ag(1) bond length. There is one shorter (2.58 Å) and one longer (2.70 Å) Ti(2)-Cl(1) bond length. Ag(1) is bonded in a single-bond geometry to two equivalent Ti(2) and one Cl(1) atom. The Ag(1)-Cl(1) bond length is 1.16 Å. Cl(1) is bonded in a distorted single-bond geometry to two equivalent Ti(1), two equivalent Ti(2), and one Ag(1) atom.