data_TiB2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.0
_cell_length_b   3.13
_cell_length_c   5.08
_cell_angle_alpha   90.0
_cell_angle_beta   99.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiB2W
_chemical_formula_sum   'Ti1 B2 W1'
_cell_volume   47.03
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti2  1  0.0  0.0  0.0  1.0
  B  B0  1  0.64  0.56  0.4  1.0
  B  B1  1  0.57  0.56  0.62  1.0
  W  W3  1  0.1  0.0  0.51  1.0

data_TiB2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.0
_cell_length_b   3.13
_cell_length_c   5.08
_cell_angle_alpha   90.0
_cell_angle_beta   99.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiB2W
_chemical_formula_sum   'Ti1 B2 W1'
_cell_volume   47.03
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.0  0.0  0.0  1.0
  B  B1  1  0.57  0.56  0.62  1.0
  B  B2  1  0.64  0.56  0.4  1.0
  W  W3  1  0.1  0.0  0.51  1.0

Ti B B W
TiWB2 crystallizes in the triclinic P1 space group. Ti(1) is bonded in a 3-coordinate geometry to two equivalent W(1) and one B(2) atom. There is one shorter (2.55 Å) and one longer (2.57 Å) Ti(1)-W(1) bond length. The Ti(1)-B(2) bond length is 2.56 Å. W(1) is bonded in a 10-coordinate geometry to two equivalent Ti(1), four equivalent B(1), and four equivalent B(2) atoms. There are a spread of W(1)-B(1) bond distances ranging from 1.97-2.50 Å. There are a spread of W(1)-B(2) bond distances ranging from 1.97-2.50 Å. There are two inequivalent B sites. In the first B site, B(1) is bonded in a 3-coordinate geometry to four equivalent W(1) and one B(2) atom. The B(1)-B(2) bond length is 1.17 Å. In the second B site, B(2) is bonded in a 2-coordinate geometry to one Ti(1), four equivalent W(1), and one B(1) atom.