data_MnCd2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.2
_cell_length_b   5.2
_cell_length_c   3.12
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnCd2Cl
_chemical_formula_sum   'Mn1 Cd2 Cl1'
_cell_volume   84.46
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn3  1  0.6  0.6  0.0  1.0
  Cd  Cd0  1  0.6  0.0  0.56  1.0
  Cd  Cd1  1  0.0  0.6  0.56  1.0
  Cl  Cl2  1  0.0  0.0  0.0  1.0

data_MnCd2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   7.35
_cell_length_b   7.35
_cell_length_c   3.12
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   MnCd2Cl
_chemical_formula_sum   'Mn2 Cd4 Cl2'
_cell_volume   168.92
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  2  0.1  0.5  0.0  1.0
  Cd  Cd1  4  0.3  0.3  0.56  1.0
  Cl  Cl2  2  0.0  0.0  0.0  1.0

Mn Cd Cd Cl
MnCd2Cl crystallizes in the monoclinic Cm space group. Mn(1) is bonded in a 11-coordinate geometry to two equivalent Mn(1), eight equivalent Cd(1), and one Cl(1) atom. Both Mn(1)-Mn(1) bond lengths are 3.12 Å. There are a spread of Mn(1)-Cd(1) bond distances ranging from 2.49-3.58 Å. The Mn(1)-Cl(1) bond length is 2.94 Å. Cd(1) is bonded in a 4-coordinate geometry to four equivalent Mn(1) and two equivalent Cl(1) atoms. There is one shorter (2.49 Å) and one longer (2.72 Å) Cd(1)-Cl(1) bond length. Cl(1) is bonded in a 4-coordinate geometry to one Mn(1) and four equivalent Cd(1) atoms.