data_V3P2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.72
_cell_length_b   3.72
_cell_length_c   5.92
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V3P2
_chemical_formula_sum   'V3 P2'
_cell_volume   70.9
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.0  0.0  1.0
  V  V3  1  0.86  0.07  0.75  1.0
  V  V4  1  0.0  0.15  0.18  1.0
  P  P0  1  0.86  0.07  0.31  1.0
  P  P1  1  0.0  0.15  0.61  1.0

data_V3P2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.72
_cell_length_b   3.72
_cell_length_c   5.92
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V3P2
_chemical_formula_sum   'V3 P2'
_cell_volume   70.9
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  -0.0  0.15  0.18  1.0
  V  V1  1  0.0  0.0  0.0  1.0
  V  V2  1  0.86  0.07  0.75  1.0
  P  P3  1  -0.0  0.15  0.61  1.0
  P  P4  1  0.86  0.07  0.31  1.0

V V V P P
V3P2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one V3P2 cluster. There are three inequivalent V sites. In the first V site, V(1) is bonded in a distorted bent 120 degrees geometry to one V(2) and one V(3) atom. The V(1)-V(2) bond length is 1.66 Å. The V(1)-V(3) bond length is 1.17 Å. In the second V site, V(2) is bonded in a single-bond geometry to one V(1) and one P(2) atom. The V(2)-P(2) bond length is 0.94 Å. In the third V site, V(3) is bonded in a distorted single-bond geometry to one V(1) and one P(1) atom. The V(3)-P(1) bond length is 0.94 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a single-bond geometry to one V(3) atom. In the second P site, P(2) is bonded in a single-bond geometry to one V(2) atom.