data_La2PdAu
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.73
_cell_length_b   3.73
_cell_length_c   7.49
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   La2PdAu
_chemical_formula_sum   'La2 Pd1 Au1'
_cell_volume   104.26
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La1  1  0.87  0.87  0.67  1.0
  La  La2  1  0.87  0.87  0.82  1.0
  Pd  Pd3  1  0.0  0.0  0.0  1.0
  Au  Au0  1  0.0  0.0  0.74  1.0

data_La2PdAu
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.28
_cell_length_b   5.28
_cell_length_c   7.49
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   La2PdAu
_chemical_formula_sum   'La4 Pd2 Au2'
_cell_volume   208.51
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  2  0.37  0.5  0.67  1.0
  La  La1  2  0.37  0.5  0.82  1.0
  Pd  Pd2  2  0.0  0.0  0.0  1.0
  Au  Au3  2  0.0  0.0  0.74  1.0

La La Pd Au
La2PdAu crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two La2PdAu clusters. There are two inequivalent La sites. In the first La site, La(1) is bonded in a single-bond geometry to one Au(1) atom. The La(1)-Au(1) bond length is 0.89 Å. In the second La site, La(2) is bonded in a distorted single-bond geometry to one Pd(1) and one Au(1) atom. The La(2)-Pd(1) bond length is 1.56 Å. The La(2)-Au(1) bond length is 0.89 Å. Pd(1) is bonded in a single-bond geometry to one La(2) atom. Au(1) is bonded in a 2-coordinate geometry to one La(1) and one La(2) atom.