data_La2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.08
_cell_length_b   6.08
_cell_length_c   8.5
_cell_angle_alpha   90.87
_cell_angle_beta   90.87
_cell_angle_gamma   35.45
_symmetry_Int_Tables_number   1
_chemical_formula_structural   La2Cl
_chemical_formula_sum   'La4 Cl2'
_cell_volume   182.23
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La2  1  0.19  0.0  0.03  1.0
  La  La3  1  0.01  0.0  0.29  1.0
  La  La4  1  0.44  0.0  0.21  1.0
  La  La5  1  0.25  0.0  0.47  1.0
  Cl  Cl0  1  0.46  0.0  0.13  1.0
  Cl  Cl1  1  0.99  0.0  0.37  1.0

data_La2Cl
_symmetry_space_group_name_H-M   P-1
_cell_length_a   3.7
_cell_length_b   6.08
_cell_length_c   8.5
_cell_angle_alpha   90.87
_cell_angle_beta   90.0
_cell_angle_gamma   107.73
_symmetry_Int_Tables_number   2
_chemical_formula_structural   La2Cl
_chemical_formula_sum   'La4 Cl2'
_cell_volume   182.23
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  2  0.0  0.28  0.54  1.0
  La  La1  2  0.0  0.47  0.28  1.0
  Cl  Cl2  2  0.0  0.26  0.62  1.0

La La La La Cl Cl
La2Cl crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two La2Cl clusters. There are two inequivalent La sites. In the first La site, La(1) is bonded in a single-bond geometry to one Cl(1) atom. The La(1)-Cl(1) bond length is 1.82 Å. In the second La site, La(2) is bonded in a single-bond geometry to one Cl(1) atom. The La(2)-Cl(1) bond length is 0.69 Å. Cl(1) is bonded in a single-bond geometry to one La(1) and one La(2) atom.