data_Sb2MoCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.46
_cell_length_b   5.76
_cell_length_c   5.76
_cell_angle_alpha   55.86
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sb2MoCl
_chemical_formula_sum   'Sb2 Mo1 Cl1'
_cell_volume   94.99
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb2  1  0.0  0.0  0.67  1.0
  Sb  Sb3  1  0.73  0.0  0.4  1.0
  Mo  Mo1  1  0.73  0.0  0.61  1.0
  Cl  Cl0  1  0.0  0.0  0.72  1.0

data_Sb2MoCl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.46
_cell_length_b   5.4
_cell_length_c   5.76
_cell_angle_alpha   117.93
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sb2MoCl
_chemical_formula_sum   'Sb2 Mo1 Cl1'
_cell_volume   94.99
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.0  0.67  0.67  1.0
  Sb  Sb1  1  0.27  0.4  0.4  1.0
  Mo  Mo2  1  0.27  0.61  0.61  1.0
  Cl  Cl3  1  0.0  0.72  0.72  1.0

Sb Sb Mo Cl
MoSb2Cl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one MoSb2Cl cluster. Mo(1) is bonded in a distorted water-like geometry to one Sb(1) and one Sb(2) atom. The Mo(1)-Sb(1) bond length is 0.99 Å. The Mo(1)-Sb(2) bond length is 1.20 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a single-bond geometry to one Mo(1) and one Cl(1) atom. The Sb(1)-Cl(1) bond length is 0.31 Å. In the second Sb site, Sb(2) is bonded in a single-bond geometry to one Mo(1) atom. Cl(1) is bonded in a single-bond geometry to one Sb(1) atom.