data_V2CdMo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.85
_cell_length_b   4.85
_cell_length_c   5.14
_cell_angle_alpha   94.42
_cell_angle_beta   94.42
_cell_angle_gamma   31.69
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2CdMo
_chemical_formula_sum   'V2 Cd1 Mo1'
_cell_volume   63.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.89  0.0  0.12  1.0
  V  V3  1  1.0  0.0  0.9  1.0
  Cd  Cd0  1  0.46  0.0  0.6  1.0
  Mo  Mo1  1  0.93  0.0  0.19  1.0

data_V2CdMo
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.65
_cell_length_b   4.85
_cell_length_c   5.14
_cell_angle_alpha   94.42
_cell_angle_beta   90.0
_cell_angle_gamma   105.84
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2CdMo
_chemical_formula_sum   'V2 Cd1 Mo1'
_cell_volume   63.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.1  1.0
  V  V1  1  0.0  0.11  0.88  1.0
  Cd  Cd2  1  0.0  0.54  0.4  1.0
  Mo  Mo3  1  0.0  0.07  0.81  1.0

V V Cd Mo
V2MoCd crystallizes in the triclinic P1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a single-bond geometry to one V(2) and one Mo(1) atom. The V(1)-V(2) bond length is 1.27 Å. The V(1)-Mo(1) bond length is 0.40 Å. In the second V site, V(2) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Cd(1) atoms. There is one shorter (2.86 Å) and one longer (2.91 Å) V(2)-Cd(1) bond length. Mo(1) is bonded in a single-bond geometry to one V(1) and two equivalent Cd(1) atoms. There is one shorter (3.18 Å) and one longer (3.20 Å) Mo(1)-Cd(1) bond length. Cd(1) is bonded in a 6-coordinate geometry to two equivalent V(2), two equivalent Mo(1), and two equivalent Cd(1) atoms. Both Cd(1)-Cd(1) bond lengths are 2.65 Å.