data_AgGe2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.6
_cell_length_b   4.6
_cell_length_c   3.11
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.93
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgGe2Rh
_chemical_formula_sum   'Ag1 Ge2 Rh1'
_cell_volume   65.77
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.23  0.0  0.0  1.0
  Ge  Ge1  1  0.61  0.36  0.55  1.0
  Ge  Ge2  1  0.61  0.64  0.55  1.0
  Rh  Rh3  1  0.0  0.0  0.0  1.0

data_AgGe2Rh
_symmetry_space_group_name_H-M   Pm
_cell_length_a   3.11
_cell_length_b   4.6
_cell_length_c   4.6
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   AgGe2Rh
_chemical_formula_sum   'Ag1 Ge2 Rh1'
_cell_volume   65.78
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  -0.0  0.0  0.23  1.0
  Ge  Ge1  2  0.55  0.36  0.61  1.0
  Rh  Rh2  1  0.0  0.0  0.0  1.0

Ag Ge Ge Rh
RhAgGe2 crystallizes in the monoclinic Pm space group. Rh(1) is bonded in a single-bond geometry to one Ag(1) and four equivalent Ge(1) atoms. The Rh(1)-Ag(1) bond length is 1.05 Å. There are two shorter (2.80 Å) and two longer (2.97 Å) Rh(1)-Ge(1) bond lengths. Ag(1) is bonded in a single-bond geometry to one Rh(1) and four equivalent Ge(1) atoms. There are two shorter (2.80 Å) and two longer (2.97 Å) Ag(1)-Ge(1) bond lengths. Ge(1) is bonded in a 5-coordinate geometry to two equivalent Rh(1), two equivalent Ag(1), and one Ge(1) atom. The Ge(1)-Ge(1) bond length is 1.29 Å.