data_GaSb2Br
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.56
_cell_length_b   3.56
_cell_length_c   8.01
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   94.04
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaSb2Br
_chemical_formula_sum   'Ga1 Sb2 Br1'
_cell_volume   101.6
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga1  1  0.0  0.0  0.0  1.0
  Sb  Sb2  1  0.43  0.0  0.62  1.0
  Sb  Sb3  1  0.43  0.0  0.39  1.0
  Br  Br0  1  0.0  0.0  0.01  1.0

data_GaSb2Br
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.56
_cell_length_b   3.56
_cell_length_c   8.01
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   94.04
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaSb2Br
_chemical_formula_sum   'Ga1 Sb2 Br1'
_cell_volume   101.6
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.0  0.0  0.0  1.0
  Sb  Sb1  1  0.43  0.0  0.39  1.0
  Sb  Sb2  1  0.43  0.0  0.62  1.0
  Br  Br3  1  0.0  0.0  0.01  1.0

Ga Sb Sb Br
(Sb)2GaBr is alpha carbon monoxide-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one diantimony molecule and one GaBr cluster. In the GaBr cluster, Ga(1) is bonded in a single-bond geometry to one Br(1) atom. The Ga(1)-Br(1) bond length is 0.06 Å. Br(1) is bonded in a single-bond geometry to one Ga(1) atom.