data_CoTe4Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.11
_cell_length_b   6.11
_cell_length_c   6.11
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CoTe4Rh
_chemical_formula_sum   'Co1 Te4 Rh1'
_cell_volume   161.61
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.0  0.0  1.0
  Te  Te2  1  0.24  0.24  0.4  1.0
  Te  Te3  1  0.24  0.4  0.24  1.0
  Te  Te4  1  0.4  0.24  0.24  1.0
  Te  Te5  1  0.4  0.4  0.4  1.0
  Rh  Rh1  1  0.16  0.16  0.16  1.0

data_CoTe4Rh
_symmetry_space_group_name_H-M   R3m
_cell_length_a   6.11
_cell_length_b   6.11
_cell_length_c   14.98
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   CoTe4Rh
_chemical_formula_sum   'Co3 Te12 Rh3'
_cell_volume   484.83
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  3  0.0  0.0  0.0  1.0
  Te  Te1  9  0.05  0.1  0.7  1.0
  Te  Te2  3  0.0  0.0  0.6  1.0
  Rh  Rh3  3  0.0  0.0  0.84  1.0

Co Te Te Te Te Rh
RhCoTe4 crystallizes in the trigonal R3m space group. Rh(1) is bonded in a 4-coordinate geometry to one Co(1) and three equivalent Te(1) atoms. The Rh(1)-Co(1) bond length is 2.42 Å. All Rh(1)-Te(1) bond lengths are 2.10 Å. Co(1) is bonded in a distorted trigonal pyramidal geometry to one Rh(1) and three equivalent Te(1) atoms. All Co(1)-Te(1) bond lengths are 3.02 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one Rh(1), one Co(1), one Te(2), and two equivalent Te(1) atoms. The Te(1)-Te(2) bond length is 1.67 Å. Both Te(1)-Te(1) bond lengths are 0.96 Å. In the second Te site, Te(2) is bonded in a 3-coordinate geometry to three equivalent Te(1) atoms.