data_Sb2PdBr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.47
_cell_length_b   7.47
_cell_length_c   4.16
_cell_angle_alpha   102.23
_cell_angle_beta   102.23
_cell_angle_gamma   28.97
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sb2PdBr
_chemical_formula_sum   'Sb2 Pd1 Br1'
_cell_volume   109.67
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb2  1  0.05  0.0  0.59  1.0
  Sb  Sb3  1  0.86  0.0  0.93  1.0
  Pd  Pd1  1  0.32  0.0  0.82  1.0
  Br  Br0  1  0.11  0.0  0.75  1.0

data_Sb2PdBr
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.74
_cell_length_b   4.16
_cell_length_c   7.47
_cell_angle_alpha   102.23
_cell_angle_beta   104.49
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sb2PdBr
_chemical_formula_sum   'Sb2 Pd1 Br1'
_cell_volume   109.67
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.0  0.59  0.05  1.0
  Sb  Sb1  1  0.0  0.93  0.86  1.0
  Pd  Pd2  1  0.0  0.82  0.32  1.0
  Br  Br3  1  0.0  0.75  0.11  1.0

Sb Sb Pd Br
PdSb2Br is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one PdSb2Br cluster. Pd(1) is bonded in a single-bond geometry to one Br(1) atom. The Pd(1)-Br(1) bond length is 1.52 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a single-bond geometry to one Br(1) atom. The Sb(1)-Br(1) bond length is 0.74 Å. In the second Sb site, Sb(2) is bonded in a distorted single-bond geometry to one Br(1) atom. The Sb(2)-Br(1) bond length is 2.17 Å. Br(1) is bonded in a distorted single-bond geometry to one Pd(1), one Sb(1), and one Sb(2) atom.