data_KRe2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.6
_cell_length_b   5.3
_cell_length_c   6.86
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KRe2Cl
_chemical_formula_sum   'K1 Re2 Cl1'
_cell_volume   94.42
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K1  1  0.0  0.65  0.0  1.0
  Re  Re2  1  0.3  0.47  0.43  1.0
  Re  Re3  1  0.3  0.82  0.43  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_KRe2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.6
_cell_length_b   5.3
_cell_length_c   6.86
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KRe2Cl
_chemical_formula_sum   'K1 Re2 Cl1'
_cell_volume   94.42
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.65  -0.0  1.0
  Re  Re1  1  0.3  0.47  0.43  1.0
  Re  Re2  1  0.3  0.82  0.43  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

K Re Re Cl
KRe2Cl crystallizes in the triclinic P1 space group. K(1) is bonded in a single-bond geometry to three equivalent Re(1) and one Cl(1) atom. There are a spread of K(1)-Re(1) bond distances ranging from 3.19-4.09 Å. The K(1)-Cl(1) bond length is 1.86 Å. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 7-coordinate geometry to three equivalent K(1), two equivalent Re(1), and two equivalent Re(2) atoms. Both Re(1)-Re(1) bond lengths are 2.60 Å. There is one shorter (1.86 Å) and one longer (3.44 Å) Re(1)-Re(2) bond length. In the second Re site, Re(2) is bonded in a 1-coordinate geometry to two equivalent Re(1) atoms. Cl(1) is bonded in a single-bond geometry to one K(1) atom.