data_ZnOs2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.87
_cell_length_b   4.6
_cell_length_c   4.74
_cell_angle_alpha   90.0
_cell_angle_beta   94.25
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnOs2Cl
_chemical_formula_sum   'Zn1 Os2 Cl1'
_cell_volume   62.32
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.26  0.0  0.37  1.0
  Os  Os1  1  0.03  0.3  0.45  1.0
  Os  Os2  1  0.49  0.3  0.28  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_ZnOs2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.87
_cell_length_b   4.6
_cell_length_c   4.74
_cell_angle_alpha   90.0
_cell_angle_beta   94.25
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnOs2Cl
_chemical_formula_sum   'Zn1 Os2 Cl1'
_cell_volume   62.32
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.26  0.0  0.37  1.0
  Os  Os1  1  0.03  0.3  0.45  1.0
  Os  Os2  1  0.49  0.3  0.28  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Zn Os Os Cl
Os2ZnCl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Os2ZnCl cluster. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a distorted single-bond geometry to one Zn(1) atom. The Os(1)-Zn(1) bond length is 1.58 Å. In the second Os site, Os(2) is bonded in a distorted single-bond geometry to one Zn(1) atom. The Os(2)-Zn(1) bond length is 1.58 Å. Zn(1) is bonded in a distorted T-shaped geometry to one Os(1), one Os(2), and one Cl(1) atom. The Zn(1)-Cl(1) bond length is 1.83 Å. Cl(1) is bonded in a distorted single-bond geometry to one Zn(1) atom.