data_CdSnGe2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.48
_cell_length_b   5.48
_cell_length_c   3.18
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   109.22
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdSnGe2
_chemical_formula_sum   'Cd1 Sn1 Ge2'
_cell_volume   90.2
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.0  0.0  1.0
  Sn  Sn3  1  0.18  0.0  0.0  1.0
  Ge  Ge1  1  0.59  0.24  0.59  1.0
  Ge  Ge2  1  0.59  0.76  0.59  1.0

data_CdSnGe2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.18
_cell_length_b   5.48
_cell_length_c   5.48
_cell_angle_alpha   109.22
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdSnGe2
_chemical_formula_sum   'Cd1 Sn1 Ge2'
_cell_volume   90.2
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.0  0.0  1.0
  Sn  Sn1  1  0.0  0.18  0.0  1.0
  Ge  Ge2  1  0.59  0.59  0.24  1.0
  Ge  Ge3  1  0.59  0.59  0.76  1.0

Cd Sn Ge Ge
CdSnGe2 crystallizes in the triclinic P1 space group. Cd(1) is bonded in a distorted single-bond geometry to one Sn(1), one Ge(1), and two equivalent Ge(2) atoms. The Cd(1)-Sn(1) bond length is 0.96 Å. The Cd(1)-Ge(1) bond length is 3.23 Å. There is one shorter (2.56 Å) and one longer (2.89 Å) Cd(1)-Ge(2) bond length. Sn(1) is bonded in a single-bond geometry to one Cd(1) and two equivalent Ge(1) atoms. There is one shorter (2.56 Å) and one longer (2.89 Å) Sn(1)-Ge(1) bond length. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 5-coordinate geometry to one Cd(1), two equivalent Sn(1), and two equivalent Ge(2) atoms. There is one shorter (2.58 Å) and one longer (2.90 Å) Ge(1)-Ge(2) bond length. In the second Ge site, Ge(2) is bonded in a 4-coordinate geometry to two equivalent Cd(1) and two equivalent Ge(1) atoms.