data_AlTe2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.37
_cell_length_b   3.37
_cell_length_c   7.51
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AlTe2Rh
_chemical_formula_sum   'Al1 Te2 Rh1'
_cell_volume   85.04
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.0  0.0  0.0  1.0
  Te  Te2  1  0.68  0.68  0.44  1.0
  Te  Te3  1  0.68  0.68  0.07  1.0
  Rh  Rh1  1  0.0  0.0  0.75  1.0

data_AlTe2Rh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.76
_cell_length_b   4.76
_cell_length_c   7.51
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   AlTe2Rh
_chemical_formula_sum   'Al2 Te4 Rh2'
_cell_volume   170.09
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  2  0.0  0.0  0.0  1.0
  Te  Te1  2  0.18  0.5  0.07  1.0
  Te  Te2  2  0.18  0.5  0.44  1.0
  Rh  Rh3  2  0.0  0.0  0.75  1.0

Al Te Te Rh
RhAlTe2 crystallizes in the monoclinic Cm space group. Rh(1) is bonded in a distorted single-bond geometry to one Al(1) and three equivalent Te(1) atoms. The Rh(1)-Al(1) bond length is 1.85 Å. There is one shorter (2.79 Å) and two longer (3.45 Å) Rh(1)-Te(1) bond lengths. Al(1) is bonded in a distorted water-like geometry to one Rh(1) and one Te(2) atom. The Al(1)-Te(2) bond length is 1.59 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 8-coordinate geometry to three equivalent Rh(1), one Te(2), and four equivalent Te(1) atoms. The Te(1)-Te(2) bond length is 2.83 Å. All Te(1)-Te(1) bond lengths are 3.37 Å. In the second Te site, Te(2) is bonded in a distorted single-bond geometry to one Al(1) and one Te(1) atom.