data_LiTePb2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.07
_cell_length_b   4.05
_cell_length_c   6.98
_cell_angle_alpha   90.0
_cell_angle_beta   91.29
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiTePb2
_chemical_formula_sum   'Li1 Te1 Pb2'
_cell_volume   115.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.02  0.0  0.11  1.0
  Te  Te3  1  0.99  0.02  0.1  1.0
  Pb  Pb1  1  0.02  0.02  0.04  1.0
  Pb  Pb2  1  0.88  0.0  0.22  1.0

data_LiTePb2
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.05
_cell_length_b   4.07
_cell_length_c   6.98
_cell_angle_alpha   91.29
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiTePb2
_chemical_formula_sum   'Li1 Te1 Pb2'
_cell_volume   115.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.98  0.89  1.0
  Te  Te1  1  0.98  0.01  0.9  1.0
  Pb  Pb2  1  0.0  0.12  0.78  1.0
  Pb  Pb3  1  0.98  0.98  0.96  1.0

Li Te Pb Pb
LiPb2Te is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LiPb2Te cluster. Li(1) is bonded in a single-bond geometry to one Pb(1), one Pb(2), and one Te(1) atom. The Li(1)-Pb(1) bond length is 0.47 Å. The Li(1)-Pb(2) bond length is 0.98 Å. The Li(1)-Te(1) bond length is 0.18 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a distorted single-bond geometry to one Li(1) and one Te(1) atom. The Pb(1)-Te(1) bond length is 0.37 Å. In the second Pb site, Pb(2) is bonded in a distorted single-bond geometry to one Li(1) atom. Te(1) is bonded in a single-bond geometry to one Li(1) and one Pb(1) atom.