data_VAgW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.75
_cell_length_b   2.75
_cell_length_c   7.3
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VAgW
_chemical_formula_sum   'V1 Ag1 W1'
_cell_volume   47.79
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V1  1  0.0  0.0  0.44  1.0
  Ag  Ag0  1  1.0  0.59  0.05  1.0
  W  W2  1  0.37  0.79  0.81  1.0

data_VAgW
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.75
_cell_length_b   2.75
_cell_length_c   7.3
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VAgW
_chemical_formula_sum   'V1 Ag1 W1'
_cell_volume   47.79
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.44  1.0
  Ag  Ag1  1  1.0  0.59  0.05  1.0
  W  W2  1  0.37  0.79  0.81  1.0

V Ag W
VWAg crystallizes in the triclinic P1 space group. V(1) is bonded in a 11-coordinate geometry to six equivalent V(1), three equivalent W(1), and two equivalent Ag(1) atoms. All V(1)-V(1) bond lengths are 2.75 Å. There are a spread of V(1)-W(1) bond distances ranging from 3.04-3.29 Å. There is one shorter (3.12 Å) and one longer (3.33 Å) V(1)-Ag(1) bond length. W(1) is bonded in a distorted single-bond geometry to three equivalent V(1) and one Ag(1) atom. The W(1)-Ag(1) bond length is 1.92 Å. Ag(1) is bonded in a distorted single-bond geometry to two equivalent V(1) and one W(1) atom.