data_AlIn2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.97
_cell_length_b   4.95
_cell_length_c   5.22
_cell_angle_alpha   90.0
_cell_angle_beta   90.59
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AlIn2W
_chemical_formula_sum   'Al1 In2 W1'
_cell_volume   76.75
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.08  0.0  0.25  1.0
  In  In1  1  0.57  0.48  0.17  1.0
  In  In2  1  0.59  0.0  0.73  1.0
  W  W3  1  0.1  0.48  0.68  1.0

data_AlIn2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.97
_cell_length_b   4.95
_cell_length_c   5.22
_cell_angle_alpha   90.0
_cell_angle_beta   90.59
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AlIn2W
_chemical_formula_sum   'Al1 In2 W1'
_cell_volume   76.75
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.08  0.0  0.25  1.0
  In  In1  1  0.57  0.48  0.17  1.0
  In  In2  1  0.59  0.0  0.73  1.0
  W  W3  1  0.1  0.48  0.68  1.0

Al In In W
WIn2Al crystallizes in the triclinic P1 space group. W(1) is bonded to two equivalent W(1), four equivalent In(1), four equivalent In(2), and two equivalent Al(1) atoms to form distorted WAl2In8W2 cuboctahedra that share corners with ten equivalent W(1)Al2In8W2 cuboctahedra, edges with two equivalent W(1)Al2In8W2 cuboctahedra, edges with four equivalent Al(1)Al2In8W2 cuboctahedra, faces with four equivalent W(1)Al2In8W2 cuboctahedra, and faces with eight equivalent Al(1)Al2In8W2 cuboctahedra. Both W(1)-W(1) bond lengths are 2.97 Å. There are a spread of W(1)-In(1) bond distances ranging from 2.90-3.08 Å. There are a spread of W(1)-In(2) bond distances ranging from 2.79-3.02 Å. There is one shorter (3.23 Å) and one longer (3.40 Å) W(1)-Al(1) bond length. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 8-coordinate geometry to four equivalent W(1) and four equivalent Al(1) atoms. There are a spread of In(1)-Al(1) bond distances ranging from 2.81-3.03 Å. In the second In site, In(2) is bonded in a 10-coordinate geometry to four equivalent W(1), two equivalent In(2), and four equivalent Al(1) atoms. Both In(2)-In(2) bond lengths are 2.97 Å. There are a spread of In(2)-Al(1) bond distances ranging from 2.88-3.15 Å. Al(1) is bonded to two equivalent W(1), four equivalent In(1), four equivalent In(2), and two equivalent Al(1) atoms to form distorted AlAl2In8W2 cuboctahedra that share corners with ten equivalent Al(1)Al2In8W2 cuboctahedra, edges with two equivalent Al(1)Al2In8W2 cuboctahedra, edges with four equivalent W(1)Al2In8W2 cuboctahedra, faces with four equivalent Al(1)Al2In8W2 cuboctahedra, and faces with eight equivalent W(1)Al2In8W2 cuboctahedra. Both Al(1)-Al(1) bond lengths are 2.97 Å.