data_RePdW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.41
_cell_length_b   9.41
_cell_length_c   9.41
_cell_angle_alpha   17.09
_cell_angle_beta   17.09
_cell_angle_gamma   17.09
_symmetry_Int_Tables_number   1
_chemical_formula_structural   RePdW2
_chemical_formula_sum   'Re1 Pd1 W2'
_cell_volume   62.73
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re1  1  0.0  0.0  0.9  1.0
  Pd  Pd0  1  0.0  0.0  0.0  1.0
  W  W2  1  0.0  0.0  0.87  1.0
  W  W3  1  0.0  0.0  0.93  1.0

data_RePdW2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.84
_cell_length_b   2.8
_cell_length_c   9.41
_cell_angle_alpha   90.0
_cell_angle_beta   99.88
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   RePdW2
_chemical_formula_sum   'Re2 Pd2 W4'
_cell_volume   125.46
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  2  0.0  0.0  0.1  1.0
  Pd  Pd1  2  0.0  0.0  0.0  1.0
  W  W2  2  0.0  0.0  0.07  1.0
  W  W3  2  0.0  0.0  0.13  1.0

Re Pd W W
W2RePd is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two W2RePd clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded in a single-bond geometry to one Re(1) atom. The W(1)-Re(1) bond length is 0.26 Å. In the second W site, W(2) is bonded in a linear geometry to one Re(1) and one Pd(1) atom. The W(2)-Re(1) bond length is 0.26 Å. The W(2)-Pd(1) bond length is 0.68 Å. Re(1) is bonded in a linear geometry to one W(1) and one W(2) atom. Pd(1) is bonded in a single-bond geometry to one W(2) atom.