data_La2SiPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.21
_cell_length_b   5.21
_cell_length_c   3.73
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   La2SiPd
_chemical_formula_sum   'La2 Si1 Pd1'
_cell_volume   101.27
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.61  0.86  1.0
  La  La1  1  0.61  0.0  0.86  1.0
  Si  Si3  1  0.0  0.0  0.0  1.0
  Pd  Pd2  1  0.61  0.61  0.0  1.0

data_La2SiPd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   7.37
_cell_length_b   7.37
_cell_length_c   3.73
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   La2SiPd
_chemical_formula_sum   'La4 Si2 Pd2'
_cell_volume   202.54
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  4  0.3  0.3  0.86  1.0
  Si  Si1  2  0.0  0.0  0.0  1.0
  Pd  Pd2  2  0.11  0.5  -0.0  1.0

La La Si Pd
La2PdSi crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two La2PdSi clusters. La(1) is bonded in a distorted L-shaped geometry to one Pd(1) and one Si(1) atom. The La(1)-Pd(1) bond length is 2.11 Å. The La(1)-Si(1) bond length is 2.11 Å. Pd(1) is bonded in a distorted L-shaped geometry to two equivalent La(1) atoms. Si(1) is bonded in a distorted L-shaped geometry to two equivalent La(1) atoms.