data_BaCo2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.75
_cell_length_b   4.75
_cell_length_c   3.21
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   98.17
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaCo2Rh
_chemical_formula_sum   'Ba1 Co2 Rh1'
_cell_volume   71.61
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.11  0.0  0.0  1.0
  Co  Co1  1  0.56  0.21  0.6  1.0
  Co  Co2  1  0.56  0.79  0.6  1.0
  Rh  Rh3  1  0.0  0.0  0.0  1.0

data_BaCo2Rh
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.21
_cell_length_b   4.75
_cell_length_c   4.75
_cell_angle_alpha   98.17
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaCo2Rh
_chemical_formula_sum   'Ba1 Co2 Rh1'
_cell_volume   71.61
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.0  0.11  0.0  1.0
  Co  Co1  1  0.6  0.56  0.21  1.0
  Co  Co2  1  0.6  0.56  0.79  1.0
  Rh  Rh3  1  0.0  0.0  0.0  1.0

Ba Co Co Rh
BaRhCo2 crystallizes in the triclinic P1 space group. Ba(1) is bonded in a single-bond geometry to one Rh(1), two equivalent Co(1), and two equivalent Co(2) atoms. The Ba(1)-Rh(1) bond length is 0.53 Å. There is one shorter (2.54 Å) and one longer (2.92 Å) Ba(1)-Co(1) bond length. There is one shorter (2.76 Å) and one longer (3.12 Å) Ba(1)-Co(2) bond length. Rh(1) is bonded in a single-bond geometry to one Ba(1), two equivalent Co(1), and two equivalent Co(2) atoms. There is one shorter (2.76 Å) and one longer (3.12 Å) Rh(1)-Co(1) bond length. There is one shorter (2.54 Å) and one longer (2.92 Å) Rh(1)-Co(2) bond length. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 8-coordinate geometry to two equivalent Ba(1), two equivalent Rh(1), two equivalent Co(1), and two equivalent Co(2) atoms. Both Co(1)-Co(1) bond lengths are 3.21 Å. There is one shorter (1.95 Å) and one longer (2.80 Å) Co(1)-Co(2) bond length. In the second Co site, Co(2) is bonded in a 6-coordinate geometry to two equivalent Ba(1), two equivalent Rh(1), and two equivalent Co(1) atoms.