data_BaCaW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.01
_cell_length_b   6.01
_cell_length_c   6.01
_cell_angle_alpha   150.1
_cell_angle_beta   128.54
_cell_angle_gamma   60.66
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaCaW
_chemical_formula_sum   'Ba1 Ca1 W1'
_cell_volume   83.86
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.0  0.0  0.28  1.0
  Ca  Ca1  1  0.0  0.0  0.04  1.0
  W  W2  1  0.0  0.0  0.42  1.0

data_BaCaW
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.1
_cell_length_b   5.22
_cell_length_c   6.01
_cell_angle_alpha   115.73
_cell_angle_beta   104.95
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaCaW
_chemical_formula_sum   'Ba1 Ca1 W1'
_cell_volume   83.86
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.72  0.72  0.72  1.0
  Ca  Ca1  1  0.96  0.96  0.96  1.0
  W  W2  1  0.58  0.58  0.58  1.0

Ba Ca W
BaCaW crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one BaCaW cluster. Ba(1) is bonded in a distorted single-bond geometry to one Ca(1) and one W(1) atom. The Ba(1)-Ca(1) bond length is 1.42 Å. The Ba(1)-W(1) bond length is 0.86 Å. Ca(1) is bonded in a distorted single-bond geometry to one Ba(1) atom. W(1) is bonded in a single-bond geometry to one Ba(1) atom.