data_VGa2Sb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.34
_cell_length_b   5.34
_cell_length_c   5.34
_cell_angle_alpha   142.13
_cell_angle_beta   129.05
_cell_angle_gamma   65.2
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VGa2Sb
_chemical_formula_sum   'V1 Ga2 Sb1'
_cell_volume   71.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Ga  Ga0  1  0.0  0.3  0.39  1.0
  Ga  Ga1  1  0.73  0.0  0.1  1.0
  Sb  Sb2  1  0.0  0.0  0.5  1.0

data_VGa2Sb
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.46
_cell_length_b   4.59
_cell_length_c   5.34
_cell_angle_alpha   115.47
_cell_angle_beta   108.93
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VGa2Sb
_chemical_formula_sum   'V1 Ga2 Sb1'
_cell_volume   71.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  Ga  Ga1  1  0.61  0.9  0.9  1.0
  Ga  Ga2  1  0.63  0.9  0.63  1.0
  Sb  Sb3  1  0.5  0.5  0.5  1.0

V Ga Ga Sb
VGaGaSb crystallizes in the triclinic P1 space group. V(1) is bonded in a 4-coordinate geometry to one Ga(2), two equivalent Ga(1), and one Sb(1) atom. The V(1)-Ga(2) bond length is 1.83 Å. There is one shorter (1.29 Å) and one longer (2.32 Å) V(1)-Ga(1) bond length. The V(1)-Sb(1) bond length is 2.69 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 4-coordinate geometry to two equivalent V(1), one Ga(2), and one Sb(1) atom. The Ga(1)-Ga(2) bond length is 1.48 Å. The Ga(1)-Sb(1) bond length is 2.04 Å. In the second Ga site, Ga(2) is bonded in a 4-coordinate geometry to one V(1), one Ga(1), and two equivalent Sb(1) atoms. There is one shorter (1.63 Å) and one longer (3.13 Å) Ga(2)-Sb(1) bond length. Sb(1) is bonded in a 4-coordinate geometry to one V(1), one Ga(1), and two equivalent Ga(2) atoms.