data_LaTc2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.34
_cell_length_b   4.47
_cell_length_c   5.02
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaTc2Pd
_chemical_formula_sum   'La1 Tc2 Pd1'
_cell_volume   74.83
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.24  0.51  1.0
  Tc  Tc2  1  0.67  0.24  0.0  1.0
  Tc  Tc3  1  0.0  0.0  0.0  1.0
  Pd  Pd1  1  0.67  0.0  0.51  1.0

data_LaTc2Pd
_symmetry_space_group_name_H-M   Pm
_cell_length_a   3.34
_cell_length_b   5.02
_cell_length_c   4.47
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   LaTc2Pd
_chemical_formula_sum   'La1 Tc2 Pd1'
_cell_volume   74.83
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.0  0.24  1.0
  Tc  Tc1  1  0.0  0.5  0.0  1.0
  Tc  Tc2  1  0.67  0.5  0.24  1.0
  Pd  Pd3  1  0.67  0.0  0.0  1.0

La Tc Tc Pd
LaPd(Tc)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LaPd cluster and one Tc cluster. In the LaPd cluster, La(1) is bonded in a distorted single-bond geometry to one Pd(1) atom. The La(1)-Pd(1) bond length is 1.53 Å. Pd(1) is bonded in a distorted single-bond geometry to one La(1) atom. In the Tc cluster, there are two inequivalent Tc sites. In the first Tc site, Tc(1) is bonded in a distorted single-bond geometry to one Tc(2) atom. The Tc(1)-Tc(2) bond length is 1.53 Å. In the second Tc site, Tc(2) is bonded in a 1-coordinate geometry to one Tc(1) atom.