data_Tl2ReCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.01
_cell_length_b   5.13
_cell_length_c   5.87
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Tl2ReCl
_chemical_formula_sum   'Tl2 Re1 Cl1'
_cell_volume   90.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl2  1  0.0  0.0  0.93  1.0
  Tl  Tl3  1  0.5  0.57  0.0  1.0
  Re  Re1  1  0.5  0.57  0.93  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Tl2ReCl
_symmetry_space_group_name_H-M   Pm
_cell_length_a   5.13
_cell_length_b   3.01
_cell_length_c   5.87
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   Tl2ReCl
_chemical_formula_sum   'Tl2 Re1 Cl1'
_cell_volume   90.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.0  0.5  0.93  1.0
  Tl  Tl1  1  0.57  0.0  0.0  1.0
  Re  Re2  1  0.57  0.0  0.93  1.0
  Cl  Cl3  1  0.0  0.5  0.0  1.0

Tl Tl Re Cl
ReTlTlCl is gamma nitrogen-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ReTl cluster and one TlCl cluster. In the ReTl cluster, Re(1) is bonded in a single-bond geometry to one Tl(2) atom. The Re(1)-Tl(2) bond length is 0.39 Å. Tl(2) is bonded in a single-bond geometry to one Re(1) atom. In the TlCl cluster, Tl(1) is bonded in a single-bond geometry to one Cl(1) atom. The Tl(1)-Cl(1) bond length is 0.39 Å. Cl(1) is bonded in a single-bond geometry to one Tl(1) atom.