data_VBiB
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.76
_cell_length_b   3.76
_cell_length_c   4.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VBiB
_chemical_formula_sum   'V1 Bi1 B1'
_cell_volume   49.45
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.17  0.36  1.0
  Bi  Bi1  1  0.88  0.08  0.33  1.0
  B  B0  1  0.0  0.0  0.4  1.0

data_VBiB
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.76
_cell_length_b   3.76
_cell_length_c   4.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VBiB
_chemical_formula_sum   'V1 Bi1 B1'
_cell_volume   49.45
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.17  0.36  1.0
  Bi  Bi1  1  0.88  0.08  0.33  1.0
  B  B2  1  0.0  0.0  0.4  1.0

V Bi B
VBBi is Hg_xSn structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VBBi cluster. V(1) is bonded in a distorted L-shaped geometry to one B(1) and one Bi(1) atom. The V(1)-B(1) bond length is 0.66 Å. The V(1)-Bi(1) bond length is 0.43 Å. B(1) is bonded in a distorted single-bond geometry to one V(1) atom. Bi(1) is bonded in a single-bond geometry to one V(1) atom.