data_ReSiPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.83
_cell_length_b   4.83
_cell_length_c   4.83
_cell_angle_alpha   133.68
_cell_angle_beta   133.68
_cell_angle_gamma   67.58
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ReSiPd2
_chemical_formula_sum   'Re1 Si1 Pd2'
_cell_volume   58.05
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re2  1  0.0  0.0  0.02  1.0
  Si  Si3  1  0.0  0.0  0.0  1.0
  Pd  Pd0  1  0.9  0.0  0.01  1.0
  Pd  Pd1  1  0.0  0.9  0.01  1.0

data_ReSiPd2
_symmetry_space_group_name_H-M   Fmm2
_cell_length_a   5.38
_cell_length_b   5.38
_cell_length_c   8.03
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   42
_chemical_formula_structural   ReSiPd2
_chemical_formula_sum   'Re4 Si4 Pd8'
_cell_volume   232.2
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, z'
  3  '-x, y, z'
  4  'x, -y, z'
  5  'x+1/2, y, z+1/2'
  6  '-x+1/2, -y, z+1/2'
  7  '-x+1/2, y, z+1/2'
  8  'x+1/2, -y, z+1/2'
  9  'x+1/2, y+1/2, z'
  10  '-x+1/2, -y+1/2, z'
  11  '-x+1/2, y+1/2, z'
  12  'x+1/2, -y+1/2, z'
  13  'x, y+1/2, z+1/2'
  14  '-x, -y+1/2, z+1/2'
  15  '-x, y+1/2, z+1/2'
  16  'x, -y+1/2, z+1/2'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Si  Si0  4  0.0  0.0  0.01  1.0
  Re  Re1  4  0.0  0.0  0.02  1.0
  Pd  Pd2  8  0.05  0.0  0.06  1.0

Re Si Pd Pd
RePd2Si crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two RePd2Si clusters. Re(1) is bonded in a 3-coordinate geometry to two equivalent Pd(1) and one Si(1) atom. Both Re(1)-Pd(1) bond lengths are 0.45 Å. The Re(1)-Si(1) bond length is 0.08 Å. Pd(1) is bonded in a single-bond geometry to one Re(1) atom. Si(1) is bonded in a single-bond geometry to one Re(1) atom.