data_BaVCo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.51
_cell_length_b   6.51
_cell_length_c   6.51
_cell_angle_alpha   151.13
_cell_angle_beta   151.13
_cell_angle_gamma   41.29
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaVCo
_chemical_formula_sum   'Ba1 V1 Co1'
_cell_volume   64.16
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.0  0.0  0.13  1.0
  V  V2  1  0.0  0.0  0.85  1.0
  Co  Co1  1  0.0  0.0  0.39  1.0

data_BaVCo
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.59
_cell_length_b   4.59
_cell_length_c   6.51
_cell_angle_alpha   90.0
_cell_angle_beta   110.64
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   BaVCo
_chemical_formula_sum   'Ba2 V2 Co2'
_cell_volume   128.33
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  2  0.0  0.0  0.87  1.0
  V  V1  2  0.0  0.0  0.15  1.0
  Co  Co2  2  0.0  0.0  0.61  1.0

Ba V Co
BaVCo crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two BaVCo clusters. Ba(1) is bonded in a linear geometry to one V(1) and one Co(1) atom. The Ba(1)-V(1) bond length is 1.78 Å. The Ba(1)-Co(1) bond length is 1.70 Å. V(1) is bonded in a single-bond geometry to one Ba(1) atom. Co(1) is bonded in a single-bond geometry to one Ba(1) atom.