data_InTc2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.06
_cell_length_b   3.06
_cell_length_c   7.74
_cell_angle_alpha   90.0
_cell_angle_beta   97.29
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InTc2Cl
_chemical_formula_sum   'In1 Tc2 Cl1'
_cell_volume   71.79
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In1  1  0.63  0.53  0.01  1.0
  Tc  Tc2  1  0.09  0.0  0.23  1.0
  Tc  Tc3  1  0.6  0.53  0.68  1.0
  Cl  Cl0  1  0.32  0.0  0.6  1.0

data_InTc2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.06
_cell_length_b   3.06
_cell_length_c   7.74
_cell_angle_alpha   90.0
_cell_angle_beta   97.29
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InTc2Cl
_chemical_formula_sum   'In1 Tc2 Cl1'
_cell_volume   71.79
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.63  0.53  0.01  1.0
  Tc  Tc1  1  0.09  0.0  0.23  1.0
  Tc  Tc2  1  0.6  0.53  0.68  1.0
  Cl  Cl3  1  0.32  0.0  0.6  1.0

In Tc Tc Cl
Tc2InCl crystallizes in the triclinic P1 space group. There are two inequivalent Tc sites. In the first Tc site, Tc(1) is bonded in a 9-coordinate geometry to four equivalent Tc(1), four equivalent In(1), and one Cl(1) atom. All Tc(1)-Tc(1) bond lengths are 3.06 Å. There are a spread of Tc(1)-In(1) bond distances ranging from 2.51-2.98 Å. The Tc(1)-Cl(1) bond length is 2.88 Å. In the second Tc site, Tc(2) is bonded in a distorted bent 120 degrees geometry to one In(1) and two equivalent Cl(1) atoms. The Tc(2)-In(1) bond length is 2.55 Å. There is one shorter (1.74 Å) and one longer (1.90 Å) Tc(2)-Cl(1) bond length. In(1) is bonded in a 9-coordinate geometry to one Tc(2), four equivalent Tc(1), and four equivalent In(1) atoms. All In(1)-In(1) bond lengths are 3.06 Å. Cl(1) is bonded in a distorted bent 120 degrees geometry to one Tc(1) and two equivalent Tc(2) atoms.