data_Ge2AsOs
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.69
_cell_length_b   4.69
_cell_length_c   3.06
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   104.78
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ge2AsOs
_chemical_formula_sum   'Ge2 As1 Os1'
_cell_volume   64.95
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge1  1  0.43  0.86  0.53  1.0
  Ge  Ge2  1  0.43  0.14  0.53  1.0
  As  As0  1  0.0  0.0  0.0  1.0
  Os  Os3  1  0.86  0.0  0.0  1.0

data_Ge2AsOs
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.06
_cell_length_b   4.69
_cell_length_c   4.69
_cell_angle_alpha   104.78
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ge2AsOs
_chemical_formula_sum   'Ge2 As1 Os1'
_cell_volume   64.95
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.53  0.43  0.14  1.0
  Ge  Ge1  1  0.53  0.43  0.86  1.0
  As  As2  1  0.0  0.0  0.0  1.0
  Os  Os3  1  0.0  0.86  0.0  1.0

Ge Ge As Os
OsAs(Ge)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ge2h6 molecule and one OsAs cluster. In the OsAs cluster, Os(1) is bonded in a distorted single-bond geometry to one As(1) atom. The Os(1)-As(1) bond length is 0.66 Å. As(1) is bonded in a distorted single-bond geometry to one Os(1) atom.