data_Ag2RhCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.95
_cell_length_b   4.95
_cell_length_c   2.93
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ag2RhCl
_chemical_formula_sum   'Ag2 Rh1 Cl1'
_cell_volume   71.78
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.47  0.0  0.47  1.0
  Ag  Ag1  1  0.0  0.47  0.47  1.0
  Rh  Rh3  1  0.47  0.47  0.0  1.0
  Cl  Cl2  1  0.0  0.0  0.0  1.0

data_Ag2RhCl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   7.0
_cell_length_b   7.0
_cell_length_c   2.93
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Ag2RhCl
_chemical_formula_sum   'Ag4 Rh2 Cl2'
_cell_volume   143.56
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  4  0.24  0.24  0.47  1.0
  Rh  Rh1  2  0.47  0.0  0.0  1.0
  Cl  Cl2  2  0.0  0.0  0.0  1.0

Ag Ag Rh Cl
RhAg2Cl crystallizes in the monoclinic Cm space group. Rh(1) is bonded in a 8-coordinate geometry to eight equivalent Ag(1) atoms. There are a spread of Rh(1)-Ag(1) bond distances ranging from 2.71-3.04 Å. Ag(1) is bonded in a 8-coordinate geometry to four equivalent Rh(1) and four equivalent Cl(1) atoms. There are a spread of Ag(1)-Cl(1) bond distances ranging from 2.71-3.04 Å. Cl(1) is bonded in a body-centered cubic geometry to eight equivalent Ag(1) atoms.