data_CrSb3Pb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.05
_cell_length_b   6.16
_cell_length_c   6.16
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CrSb3Pb
_chemical_formula_sum   'Cr4 Sb12 Pb4'
_cell_volume   533.01
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.23  0.54  0.0  1.0
  Cr  Cr1  1  0.82  0.62  0.08  1.0
  Cr  Cr2  1  0.82  0.62  0.0  1.0
  Cr  Cr3  1  0.23  0.54  0.08  1.0
  Sb  Sb8  1  0.16  0.68  0.62  1.0
  Sb  Sb9  1  0.89  0.48  0.54  1.0
  Sb  Sb10  1  0.89  0.76  0.62  1.0
  Sb  Sb11  1  0.16  0.4  0.54  1.0
  Sb  Sb12  1  0.21  0.03  0.62  1.0
  Sb  Sb13  1  0.85  0.13  0.54  1.0
  Sb  Sb14  1  0.85  0.11  0.62  1.0
  Sb  Sb15  1  0.21  0.05  0.54  1.0
  Sb  Sb16  1  0.03  0.54  0.0  1.0
  Sb  Sb17  1  0.02  0.62  0.08  1.0
  Sb  Sb18  1  0.02  0.62  0.0  1.0
  Sb  Sb19  1  0.03  0.54  0.08  1.0
  Pb  Pb4  1  0.66  0.0  0.62  1.0
  Pb  Pb5  1  0.39  0.0  0.54  1.0
  Pb  Pb6  1  0.39  0.08  0.62  1.0
  Pb  Pb7  1  0.66  0.08  0.54  1.0

data_CrSb3Pb
_symmetry_space_group_name_H-M   P1
_cell_length_a   6.16
_cell_length_b   6.16
_cell_length_c   14.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CrSb3Pb
_chemical_formula_sum   'Cr4 Sb12 Pb4'
_cell_volume   533.01
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.0  0.38  0.18  1.0
  Cr  Cr1  1  0.0  0.46  0.77  1.0
  Cr  Cr2  1  0.92  0.38  0.18  1.0
  Cr  Cr3  1  0.92  0.46  0.77  1.0
  Sb  Sb4  1  0.0  0.38  0.98  1.0
  Sb  Sb5  1  0.0  0.46  0.97  1.0
  Sb  Sb6  1  0.38  0.24  0.11  1.0
  Sb  Sb7  1  0.38  0.32  0.84  1.0
  Sb  Sb8  1  0.38  0.89  0.15  1.0
  Sb  Sb9  1  0.38  0.97  0.79  1.0
  Sb  Sb10  1  0.46  0.52  0.11  1.0
  Sb  Sb11  1  0.46  0.6  0.84  1.0
  Sb  Sb12  1  0.46  0.87  0.15  1.0
  Sb  Sb13  1  0.46  0.95  0.79  1.0
  Sb  Sb14  1  0.92  0.38  0.98  1.0
  Sb  Sb15  1  0.92  0.46  0.97  1.0
  Pb  Pb16  1  0.38  0.0  0.34  1.0
  Pb  Pb17  1  0.38  0.92  0.61  1.0
  Pb  Pb18  1  0.46  0.0  0.61  1.0
  Pb  Pb19  1  0.46  0.92  0.34  1.0

Cr Cr Cr Cr Sb Sb Sb Sb Sb Sb Sb Sb Sb Sb Sb Sb Pb Pb Pb Pb
CrSb2CrSb(Pb)2(Sb)3 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one diantimony molecule, two diplumbyne molecules, one tetrastibetane molecule, one CrSb cluster, and one CrSb2 cluster. In the CrSb cluster, there are two inequivalent Cr sites. In the first Cr site, Cr(2) is bonded in a 1-coordinate geometry to one Cr(3) atom. The Cr(2)-Cr(3) bond length is 0.49 Å. In the second Cr site, Cr(3) is bonded in a distorted bent 150 degrees geometry to one Cr(2) and one Sb(3) atom. The Cr(3)-Sb(3) bond length is 2.72 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(2) is bonded in a 1-coordinate geometry to one Sb(3) atom. The Sb(2)-Sb(3) bond length is 1.82 Å. In the second Sb site, Sb(3) is bonded in a 2-coordinate geometry to one Cr(3) and one Sb(2) atom. In the CrSb2 cluster, there are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a distorted bent 150 degrees geometry to one Cr(4) and one Sb(1) atom. The Cr(1)-Cr(4) bond length is 0.49 Å. The Cr(1)-Sb(1) bond length is 2.72 Å. In the second Cr site, Cr(4) is bonded in a 1-coordinate geometry to one Cr(1) atom. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one Cr(1), one Sb(4), and one Sb(5) atom. The Sb(1)-Sb(4) bond length is 1.82 Å. The Sb(1)-Sb(5) bond length is 2.27 Å. In the second Sb site, Sb(4) is bonded in a 1-coordinate geometry to one Sb(1) atom. In the third Sb site, Sb(5) is bonded in a single-bond geometry to one Sb(1) and one Sb(8) atom. The Sb(5)-Sb(8) bond length is 0.49 Å. In the fourth Sb site, Sb(8) is bonded in a single-bond geometry to one Sb(5) atom.