data_KLi2La
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.35
_cell_length_b   12.35
_cell_length_c   12.35
_cell_angle_alpha   17.23
_cell_angle_beta   17.23
_cell_angle_gamma   17.23
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KLi2La
_chemical_formula_sum   'K1 Li2 La1'
_cell_volume   144.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.0  0.0  1.0
  Li  Li2  1  0.0  0.0  0.87  1.0
  Li  Li3  1  0.0  0.0  0.62  1.0
  La  La1  1  0.0  0.0  0.24  1.0

data_KLi2La
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.41
_cell_length_b   3.7
_cell_length_c   12.35
_cell_angle_alpha   90.0
_cell_angle_beta   99.96
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   KLi2La
_chemical_formula_sum   'K2 Li4 La2'
_cell_volume   288.35
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  2  0.0  0.0  0.0  1.0
  Li  Li1  2  -0.0  0.0  0.38  1.0
  Li  Li2  2  0.0  0.0  0.13  1.0
  La  La3  2  -0.0  0.0  0.76  1.0

K Li Li La
KLi2La crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two KLi2La clusters. K(1) is bonded in a distorted single-bond geometry to one Li(1) and one La(1) atom. The K(1)-Li(1) bond length is 1.65 Å. The K(1)-La(1) bond length is 2.97 Å. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a single-bond geometry to one K(1) and one Li(2) atom. The Li(1)-Li(2) bond length is 3.10 Å. In the second Li site, Li(2) is bonded in a single-bond geometry to one Li(1) atom. La(1) is bonded in a single-bond geometry to one K(1) atom.