data_Ta5Rh4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.12
_cell_length_b   8.12
_cell_length_c   5.27
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ta5Rh4
_chemical_formula_sum   'Ta10 Rh8'
_cell_volume   300.63
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta8  1  0.35  0.0  0.95  1.0
  Ta  Ta9  1  0.83  0.04  0.95  1.0
  Ta  Ta10  1  0.88  1.0  0.95  1.0
  Ta  Ta11  1  0.77  0.0  0.32  1.0
  Ta  Ta12  1  0.12  1.0  0.32  1.0
  Ta  Ta13  1  0.17  0.04  0.32  1.0
  Ta  Ta14  1  0.0  0.69  0.63  1.0
  Ta  Ta15  1  0.06  0.34  0.0  1.0
  Ta  Ta16  1  0.06  0.34  0.63  1.0
  Ta  Ta17  1  0.0  0.69  0.0  1.0
  Rh  Rh0  1  0.0  0.0  0.63  1.0
  Rh  Rh1  1  0.0  0.0  0.0  1.0
  Rh  Rh2  1  0.97  0.0  0.95  1.0
  Rh  Rh3  1  0.52  0.3  0.95  1.0
  Rh  Rh4  1  0.58  0.73  0.95  1.0
  Rh  Rh5  1  0.15  0.0  0.32  1.0
  Rh  Rh6  1  0.42  0.73  0.32  1.0
  Rh  Rh7  1  0.48  0.3  0.32  1.0

data_Ta5Rh4
_symmetry_space_group_name_H-M   P1
_cell_length_a   5.27
_cell_length_b   8.12
_cell_length_c   8.12
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ta5Rh4
_chemical_formula_sum   'Ta10 Rh8'
_cell_volume   300.63
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  1  0.0  0.0  0.69  1.0
  Ta  Ta1  1  0.0  0.06  0.34  1.0
  Ta  Ta2  1  0.32  0.12  1.0  1.0
  Ta  Ta3  1  0.32  0.17  0.04  1.0
  Ta  Ta4  1  0.32  0.77  0.0  1.0
  Ta  Ta5  1  0.63  0.0  0.69  1.0
  Ta  Ta6  1  0.63  0.06  0.34  1.0
  Ta  Ta7  1  0.95  0.35  0.0  1.0
  Ta  Ta8  1  0.95  0.83  0.04  1.0
  Ta  Ta9  1  0.95  0.88  1.0  1.0
  Rh  Rh10  1  0.0  0.0  0.0  1.0
  Rh  Rh11  1  0.32  0.15  0.0  1.0
  Rh  Rh12  1  0.32  0.42  0.73  1.0
  Rh  Rh13  1  0.32  0.48  0.3  1.0
  Rh  Rh14  1  0.63  0.0  0.0  1.0
  Rh  Rh15  1  0.95  0.52  0.3  1.0
  Rh  Rh16  1  0.95  0.58  0.73  1.0
  Rh  Rh17  1  0.95  0.97  0.0  1.0

Ta Ta Ta Ta Ta Ta Ta Ta Ta Ta Rh Rh Rh Rh Rh Rh Rh Rh
Ta5Rh4 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Ta5Rh4 cluster. There are ten inequivalent Ta sites. In the first Ta site, Ta(1) is bonded in a distorted single-bond geometry to one Rh(4) atom. The Ta(1)-Rh(4) bond length is 2.12 Å. In the second Ta site, Ta(2) is bonded in a distorted single-bond geometry to one Ta(3) and one Rh(5) atom. The Ta(2)-Ta(3) bond length is 0.70 Å. The Ta(2)-Rh(5) bond length is 2.28 Å. In the third Ta site, Ta(3) is bonded in a distorted single-bond geometry to one Ta(2), one Rh(3), and one Rh(5) atom. The Ta(3)-Rh(3) bond length is 0.65 Å. The Ta(3)-Rh(5) bond length is 2.35 Å. In the fourth Ta site, Ta(4) is bonded in a 2-coordinate geometry to one Rh(1) and one Rh(7) atom. The Ta(4)-Rh(1) bond length is 2.51 Å. The Ta(4)-Rh(7) bond length is 2.55 Å. In the fifth Ta site, Ta(5) is bonded in a single-bond geometry to one Rh(1) and one Rh(6) atom. The Ta(5)-Rh(1) bond length is 1.92 Å. The Ta(5)-Rh(6) bond length is 0.28 Å. In the sixth Ta site, Ta(6) is bonded in a single-bond geometry to one Rh(6) and one Rh(8) atom. The Ta(6)-Rh(6) bond length is 0.25 Å. The Ta(6)-Rh(8) bond length is 2.35 Å. In the seventh Ta site, Ta(7) is bonded in a 2-coordinate geometry to one Ta(10) and one Rh(1) atom. The Ta(7)-Ta(10) bond length is 1.93 Å. The Ta(7)-Rh(1) bond length is 2.54 Å. In the eighth Ta site, Ta(8) is bonded in a 1-coordinate geometry to one Ta(9) atom. The Ta(8)-Ta(9) bond length is 1.93 Å. In the ninth Ta site, Ta(9) is bonded in a 2-coordinate geometry to one Ta(8) and one Rh(1) atom. The Ta(9)-Rh(1) bond length is 2.58 Å. In the tenth Ta site, Ta(10) is bonded in a distorted L-shaped geometry to one Ta(7) and one Rh(2) atom. The Ta(10)-Rh(2) bond length is 2.54 Å. There are eight inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 1-coordinate geometry to one Ta(4), one Ta(5), one Ta(7), and one Ta(9) atom. In the second Rh site, Rh(2) is bonded in a distorted single-bond geometry to one Ta(10) and one Rh(3) atom. The Rh(2)-Rh(3) bond length is 0.38 Å. In the third Rh site, Rh(3) is bonded in a 2-coordinate geometry to one Ta(3) and one Rh(2) atom. In the fourth Rh site, Rh(4) is bonded in a distorted single-bond geometry to one Ta(1) and one Rh(8) atom. The Rh(4)-Rh(8) bond length is 1.95 Å. In the fifth Rh site, Rh(5) is bonded in a 2-coordinate geometry to one Ta(2) and one Ta(3) atom. In the sixth Rh site, Rh(6) is bonded in a water-like geometry to one Ta(5) and one Ta(6) atom. In the seventh Rh site, Rh(7) is bonded in a 1-coordinate geometry to one Ta(4) atom. In the eighth Rh site, Rh(8) is bonded in a 2-coordinate geometry to one Ta(6) and one Rh(4) atom.