data_Zr2RhCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.32
_cell_length_b   3.32
_cell_length_c   8.3
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zr2RhCl
_chemical_formula_sum   'Zr2 Rh1 Cl1'
_cell_volume   91.62
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr2  1  0.0  0.0  0.16  1.0
  Zr  Zr3  1  0.66  0.66  0.01  1.0
  Rh  Rh1  1  0.66  0.66  0.95  1.0
  Cl  Cl0  1  0.0  0.0  0.63  1.0

data_Zr2RhCl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.7
_cell_length_b   4.7
_cell_length_c   8.3
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Zr2RhCl
_chemical_formula_sum   'Zr4 Rh2 Cl2'
_cell_volume   183.25
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  2  0.0  0.0  0.16  1.0
  Zr  Zr1  2  0.16  0.5  0.01  1.0
  Rh  Rh2  2  0.16  0.5  0.95  1.0
  Cl  Cl3  2  0.0  0.0  0.63  1.0

Zr Zr Rh Cl
Zr2RhCl crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Zr2RhCl clusters. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a distorted single-bond geometry to one Zr(2) atom. The Zr(1)-Zr(2) bond length is 1.99 Å. In the second Zr site, Zr(2) is bonded in a single-bond geometry to one Zr(1) and one Rh(1) atom. The Zr(2)-Rh(1) bond length is 0.52 Å. Rh(1) is bonded in a single-bond geometry to one Zr(2) and one Cl(1) atom. The Rh(1)-Cl(1) bond length is 3.09 Å. Cl(1) is bonded in a single-bond geometry to one Rh(1) atom.