data_VTeAu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.05
_cell_length_b   5.05
_cell_length_c   5.05
_cell_angle_alpha   129.22
_cell_angle_beta   129.22
_cell_angle_gamma   74.66
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VTeAu2
_chemical_formula_sum   'V1 Te1 Au2'
_cell_volume   75.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Te  Te2  1  0.16  0.0  0.01  1.0
  Au  Au0  1  0.0  0.16  0.01  1.0
  Au  Au1  1  0.0  0.0  0.01  1.0

data_VTeAu2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.12
_cell_length_b   6.12
_cell_length_c   5.05
_cell_angle_alpha   90.0
_cell_angle_beta   127.33
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VTeAu2
_chemical_formula_sum   'V2 Te2 Au4'
_cell_volume   150.33
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.0  1.0
  Te  Te1  2  0.0  0.0  0.84  1.0
  Au  Au2  2  0.01  0.0  0.01  1.0
  Au  Au3  2  0.34  0.5  0.84  1.0

V Te Au Au
VAu2Te is Copper structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VAu2Te cluster. V(1) is bonded in a distorted single-bond geometry to one Au(1), one Au(2), and one Te(1) atom. The V(1)-Au(1) bond length is 0.81 Å. The V(1)-Au(2) bond length is 0.06 Å. The V(1)-Te(1) bond length is 0.81 Å. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted single-bond geometry to one V(1) atom. In the second Au site, Au(2) is bonded in a single-bond geometry to one V(1) atom. Te(1) is bonded in a distorted single-bond geometry to one V(1) atom.