data_In2TcPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.25
_cell_length_b   3.36
_cell_length_c   6.46
_cell_angle_alpha   90.0
_cell_angle_beta   90.95
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In2TcPd
_chemical_formula_sum   'In2 Tc1 Pd1'
_cell_volume   70.53
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.6  0.68  0.58  1.0
  In  In1  1  0.54  0.68  0.88  1.0
  Tc  Tc3  1  0.0  0.0  0.0  1.0
  Pd  Pd2  1  0.95  0.0  0.23  1.0

data_In2TcPd
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.25
_cell_length_b   3.36
_cell_length_c   6.46
_cell_angle_alpha   90.0
_cell_angle_beta   90.95
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In2TcPd
_chemical_formula_sum   'In2 Tc1 Pd1'
_cell_volume   70.53
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.54  0.68  0.88  1.0
  In  In1  1  0.6  0.68  0.58  1.0
  Tc  Tc2  1  0.0  0.0  0.0  1.0
  Pd  Pd3  1  0.95  0.0  0.23  1.0

In In Tc Pd
TcPdIn2 crystallizes in the triclinic P1 space group. Tc(1) is bonded in a 1-coordinate geometry to one Pd(1) and four equivalent In(2) atoms. The Tc(1)-Pd(1) bond length is 1.49 Å. There are a spread of Tc(1)-In(2) bond distances ranging from 1.99-2.99 Å. Pd(1) is bonded in a distorted single-bond geometry to one Tc(1) and one In(1) atom. The Pd(1)-In(1) bond length is 2.74 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 2-coordinate geometry to one Pd(1) and one In(2) atom. The In(1)-In(2) bond length is 1.98 Å. In the second In site, In(2) is bonded in a 5-coordinate geometry to four equivalent Tc(1) and one In(1) atom.