data_CdWAu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.89
_cell_length_b   4.89
_cell_length_c   5.55
_cell_angle_alpha   96.99
_cell_angle_beta   96.99
_cell_angle_gamma   33.52
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdWAu2
_chemical_formula_sum   'Cd1 W1 Au2'
_cell_volume   72.62
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd2  1  0.0  0.0  0.0  1.0
  W  W3  1  0.33  0.0  0.75  1.0
  Au  Au0  1  0.88  0.0  0.47  1.0
  Au  Au1  1  0.78  0.0  0.03  1.0

data_CdWAu2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.82
_cell_length_b   4.89
_cell_length_c   5.55
_cell_angle_alpha   96.99
_cell_angle_beta   90.0
_cell_angle_gamma   106.76
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdWAu2
_chemical_formula_sum   'Cd1 W1 Au2'
_cell_volume   72.62
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.0  0.0  1.0
  W  W1  1  0.0  0.67  0.25  1.0
  Au  Au2  1  0.0  0.12  0.53  1.0
  Au  Au3  1  0.0  0.22  0.97  1.0

Cd W Au Au
WAu2Cd crystallizes in the triclinic P1 space group. W(1) is bonded in a 3-coordinate geometry to one Au(2), two equivalent Au(1), and one Cd(1) atom. The W(1)-Au(2) bond length is 2.51 Å. There is one shorter (2.51 Å) and one longer (3.27 Å) W(1)-Au(1) bond length. The W(1)-Cd(1) bond length is 2.25 Å. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a 7-coordinate geometry to two equivalent W(1), one Au(2), two equivalent Au(1), and two equivalent Cd(1) atoms. The Au(1)-Au(2) bond length is 2.48 Å. Both Au(1)-Au(1) bond lengths are 2.82 Å. There is one shorter (2.76 Å) and one longer (2.90 Å) Au(1)-Cd(1) bond length. In the second Au site, Au(2) is bonded in a single-bond geometry to one W(1), one Au(1), and one Cd(1) atom. The Au(2)-Cd(1) bond length is 1.13 Å. Cd(1) is bonded in a distorted single-bond geometry to one W(1), one Au(2), and two equivalent Au(1) atoms.