data_ZnCd2Tc
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.83
_cell_length_b   2.83
_cell_length_c   9.41
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   108.88
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnCd2Tc
_chemical_formula_sum   'Zn1 Cd2 Tc1'
_cell_volume   71.32
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.0  0.0  1.0
  Cd  Cd0  1  0.65  0.0  0.37  1.0
  Cd  Cd1  1  0.65  0.0  0.04  1.0
  Tc  Tc2  1  0.0  0.0  0.71  1.0

data_ZnCd2Tc
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.83
_cell_length_b   2.83
_cell_length_c   9.41
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   108.88
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnCd2Tc
_chemical_formula_sum   'Zn1 Cd2 Tc1'
_cell_volume   71.32
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.0  0.0  0.0  1.0
  Cd  Cd1  1  0.65  0.0  0.04  1.0
  Cd  Cd2  1  0.65  0.0  0.37  1.0
  Tc  Tc3  1  0.0  0.0  0.71  1.0

Zn Cd Cd Tc
TcCd2Zn crystallizes in the triclinic P1 space group. Tc(1) is bonded in a 6-coordinate geometry to four equivalent Tc(1), two equivalent Cd(1), and one Zn(1) atom. All Tc(1)-Tc(1) bond lengths are 2.83 Å. There is one shorter (3.27 Å) and one longer (3.61 Å) Tc(1)-Cd(1) bond length. The Tc(1)-Zn(1) bond length is 2.77 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 9-coordinate geometry to two equivalent Tc(1), one Cd(2), and six equivalent Cd(1) atoms. The Cd(1)-Cd(2) bond length is 3.18 Å. There are four shorter (2.83 Å) and two longer (3.29 Å) Cd(1)-Cd(1) bond lengths. In the second Cd site, Cd(2) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and two equivalent Zn(1) atoms. There is one shorter (1.06 Å) and one longer (1.86 Å) Cd(2)-Zn(1) bond length. Zn(1) is bonded in a 1-coordinate geometry to one Tc(1) and two equivalent Cd(2) atoms.