data_Li2LaMn
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.2
_cell_length_b   3.2
_cell_length_c   8.82
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   109.83
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2LaMn
_chemical_formula_sum   'Li2 La1 Mn1'
_cell_volume   84.87
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.0  0.0  0.59  1.0
  Li  Li2  1  0.84  0.0  0.27  1.0
  La  La0  1  0.84  0.0  0.77  1.0
  Mn  Mn3  1  0.0  0.0  0.42  1.0

data_Li2LaMn
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.2
_cell_length_b   3.2
_cell_length_c   8.82
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   109.83
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2LaMn
_chemical_formula_sum   'Li2 La1 Mn1'
_cell_volume   84.87
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.59  1.0
  Li  Li1  1  0.84  0.0  0.27  1.0
  La  La2  1  0.84  0.0  0.77  1.0
  Mn  Mn3  1  0.0  0.0  0.42  1.0

Li Li La Mn
Li2LaMn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Li2LaMn cluster. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted bent 150 degrees geometry to one La(1) and one Mn(1) atom. The Li(1)-La(1) bond length is 1.62 Å. The Li(1)-Mn(1) bond length is 1.55 Å. In the second Li site, Li(2) is bonded in a single-bond geometry to one Mn(1) atom. The Li(2)-Mn(1) bond length is 1.39 Å. La(1) is bonded in a single-bond geometry to one Li(1) atom. Mn(1) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one Li(2) atom.