data_PPtAu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.94
_cell_length_b   4.94
_cell_length_c   2.81
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   PPtAu2
_chemical_formula_sum   'P1 Pt1 Au2'
_cell_volume   68.41
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P2  1  0.0  0.0  0.0  1.0
  Pt  Pt3  1  0.47  0.47  0.0  1.0
  Au  Au0  1  0.47  0.0  0.4  1.0
  Au  Au1  1  0.0  0.47  0.4  1.0

data_PPtAu2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.98
_cell_length_b   6.98
_cell_length_c   2.81
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   PPtAu2
_chemical_formula_sum   'P2 Pt2 Au4'
_cell_volume   136.82
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  2  0.0  0.0  0.0  1.0
  Pt  Pt1  2  0.47  0.0  -0.0  1.0
  Au  Au2  4  0.23  0.23  0.4  1.0

P Pt Au Au
PtAu2P crystallizes in the monoclinic Cm space group. Pt(1) is bonded in a 10-coordinate geometry to two equivalent Pt(1) and eight equivalent Au(1) atoms. Both Pt(1)-Pt(1) bond lengths are 2.81 Å. There are a spread of Pt(1)-Au(1) bond distances ranging from 2.57-3.11 Å. Au(1) is bonded in a 10-coordinate geometry to four equivalent Pt(1), two equivalent Au(1), and four equivalent P(1) atoms. Both Au(1)-Au(1) bond lengths are 2.81 Å. There are a spread of Au(1)-P(1) bond distances ranging from 2.57-3.11 Å. P(1) is bonded in a 6-coordinate geometry to eight equivalent Au(1) atoms.