data_V2GaCo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.64
_cell_length_b   2.64
_cell_length_c   7.42
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   91.88
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2GaCo
_chemical_formula_sum   'V2 Ga1 Co1'
_cell_volume   51.82
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.0  0.02  1.0
  V  V3  1  0.84  0.0  0.36  1.0
  Ga  Ga1  1  0.84  0.0  0.03  1.0
  Co  Co0  1  0.0  0.0  0.7  1.0

data_V2GaCo
_symmetry_space_group_name_H-M   Pm
_cell_length_a   2.64
_cell_length_b   2.64
_cell_length_c   7.42
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   V2GaCo
_chemical_formula_sum   'V2 Ga1 Co1'
_cell_volume   51.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.02  1.0
  V  V1  1  0.84  0.0  0.36  1.0
  Ga  Ga2  1  0.84  0.0  0.03  1.0
  Co  Co3  1  0.0  0.0  0.7  1.0

V V Ga Co
V2CoGa crystallizes in the monoclinic Pm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a single-bond geometry to one Co(1) and one Ga(1) atom. The V(1)-Co(1) bond length is 2.41 Å. The V(1)-Ga(1) bond length is 0.43 Å. In the second V site, V(2) is bonded in a 6-coordinate geometry to four equivalent V(2), one Co(1), and one Ga(1) atom. All V(2)-V(2) bond lengths are 2.64 Å. The V(2)-Co(1) bond length is 2.53 Å. The V(2)-Ga(1) bond length is 2.44 Å. Co(1) is bonded in a 2-coordinate geometry to one V(1) and one V(2) atom. Ga(1) is bonded in a single-bond geometry to one V(1) and one V(2) atom.