data_LaVZn2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.29
_cell_length_b   5.29
_cell_length_c   5.29
_cell_angle_alpha   132.29
_cell_angle_beta   132.29
_cell_angle_gamma   69.78
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaVZn2
_chemical_formula_sum   'La1 V1 Zn2'
_cell_volume   79.25
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.14  0.17  1.0
  V  V1  1  0.0  0.0  0.0  1.0
  Zn  Zn2  1  0.14  0.0  0.17  1.0
  Zn  Zn3  1  0.0  0.0  0.34  1.0

data_LaVZn2
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.28
_cell_length_b   4.28
_cell_length_c   5.29
_cell_angle_alpha   113.86
_cell_angle_beta   113.86
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaVZn2
_chemical_formula_sum   'La1 V1 Zn2'
_cell_volume   79.25
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.03  0.17  0.03  1.0
  V  V1  1  0.0  0.0  0.0  1.0
  Zn  Zn2  1  0.17  0.03  0.03  1.0
  Zn  Zn3  1  0.34  0.34  0.34  1.0

La V Zn Zn
LaVZn2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LaVZn2 cluster. La(1) is bonded in a 3-coordinate geometry to one V(1), one Zn(1), and one Zn(2) atom. The La(1)-V(1) bond length is 0.67 Å. The La(1)-Zn(1) bond length is 0.83 Å. The La(1)-Zn(2) bond length is 1.48 Å. V(1) is bonded in a 2-coordinate geometry to one La(1) and one Zn(1) atom. The V(1)-Zn(1) bond length is 0.67 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 2-coordinate geometry to one La(1) and one V(1) atom. In the second Zn site, Zn(2) is bonded in a distorted single-bond geometry to one La(1) atom.