data_TlPdW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.21
_cell_length_b   5.21
_cell_length_c   4.69
_cell_angle_alpha   101.6
_cell_angle_beta   101.6
_cell_angle_gamma   33.93
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlPdW2
_chemical_formula_sum   'Tl1 Pd1 W2'
_cell_volume   69.49
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl1  1  0.49  0.0  0.29  1.0
  Pd  Pd0  1  0.0  0.0  0.0  1.0
  W  W2  1  0.19  0.0  0.08  1.0
  W  W3  1  0.8  0.0  0.5  1.0

data_TlPdW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.04
_cell_length_b   4.69
_cell_length_c   5.21
_cell_angle_alpha   101.6
_cell_angle_beta   106.96
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlPdW2
_chemical_formula_sum   'Tl1 Pd1 W2'
_cell_volume   69.49
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.0  0.29  0.49  1.0
  Pd  Pd1  1  0.0  0.0  0.0  1.0
  W  W2  1  0.0  0.08  0.19  1.0
  W  W3  1  0.0  0.5  0.8  1.0

Tl Pd W W
W2PdTl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one W2PdTl cluster. There are two inequivalent W sites. In the first W site, W(1) is bonded in a linear geometry to one Pd(1) and one Tl(1) atom. The W(1)-Pd(1) bond length is 1.00 Å. The W(1)-Tl(1) bond length is 1.68 Å. In the second W site, W(2) is bonded in a distorted single-bond geometry to one Tl(1) atom. The W(2)-Tl(1) bond length is 1.68 Å. Pd(1) is bonded in a distorted single-bond geometry to one W(1) atom. Tl(1) is bonded in a linear geometry to one W(1) and one W(2) atom.