data_Zr2BiRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.34
_cell_length_b   5.34
_cell_length_c   5.34
_cell_angle_alpha   135.27
_cell_angle_beta   127.25
_cell_angle_gamma   71.59
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zr2BiRh
_chemical_formula_sum   'Zr2 Bi1 Rh1'
_cell_volume   83.43
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr2  1  0.0  0.37  0.3  1.0
  Zr  Zr3  1  0.03  0.0  0.03  1.0
  Bi  Bi0  1  0.0  0.0  0.33  1.0
  Rh  Rh1  1  0.0  0.0  0.0  1.0

data_Zr2BiRh
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.06
_cell_length_b   4.74
_cell_length_c   5.34
_cell_angle_alpha   116.37
_cell_angle_beta   112.36
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zr2BiRh
_chemical_formula_sum   'Zr2 Bi1 Rh1'
_cell_volume   83.43
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.0  0.03  0.0  1.0
  Zr  Zr1  1  0.63  0.93  0.93  1.0
  Bi  Bi2  1  0.0  0.33  0.33  1.0
  Rh  Rh3  1  0.0  0.0  0.0  1.0

Zr Zr Bi Rh
Zr2RhBi crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Zr2RhBi cluster. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 1-coordinate geometry to one Rh(1) atom. The Zr(1)-Rh(1) bond length is 1.41 Å. In the second Zr site, Zr(2) is bonded in a single-bond geometry to one Rh(1) and one Bi(1) atom. The Zr(2)-Rh(1) bond length is 0.15 Å. The Zr(2)-Bi(1) bond length is 1.69 Å. Rh(1) is bonded in a single-bond geometry to one Zr(1) and one Zr(2) atom. Bi(1) is bonded in a 1-coordinate geometry to one Zr(2) atom.