data_TiCoP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.69
_cell_length_b   3.17
_cell_length_c   5.92
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiCoP2
_chemical_formula_sum   'Ti1 Co1 P2'
_cell_volume   50.55
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti3  1  0.0  0.0  0.0  1.0
  Co  Co0  1  0.0  0.0  0.96  1.0
  P  P1  1  0.35  0.59  0.33  1.0
  P  P2  1  0.35  0.59  0.59  1.0

data_TiCoP2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.69
_cell_length_b   3.17
_cell_length_c   5.92
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiCoP2
_chemical_formula_sum   'Ti1 Co1 P2'
_cell_volume   50.55
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.0  0.0  0.0  1.0
  Co  Co1  1  0.0  0.0  0.96  1.0
  P  P2  1  0.35  0.59  0.33  1.0
  P  P3  1  0.35  0.59  0.59  1.0

Ti Co P P
TiCoP2 crystallizes in the triclinic P1 space group. Ti(1) is bonded in a single-bond geometry to one Co(1) and four equivalent P(1) atoms. The Ti(1)-Co(1) bond length is 0.24 Å. There are a spread of Ti(1)-P(1) bond distances ranging from 2.53-3.22 Å. Co(1) is bonded in a single-bond geometry to one Ti(1) and three equivalent P(2) atoms. There are a spread of Co(1)-P(2) bond distances ranging from 2.72-3.11 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 7-coordinate geometry to four equivalent Ti(1), one P(2), and two equivalent P(1) atoms. The P(1)-P(2) bond length is 1.52 Å. Both P(1)-P(1) bond lengths are 2.69 Å. In the second P site, P(2) is bonded in a 6-coordinate geometry to three equivalent Co(1), one P(1), and two equivalent P(2) atoms. Both P(2)-P(2) bond lengths are 2.69 Å.