data_Cd2PW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.84
_cell_length_b   4.88
_cell_length_c   5.26
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2PW
_chemical_formula_sum   'Cd2 P1 W1'
_cell_volume   72.83
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.42  0.44  0.93  1.0
  Cd  Cd1  1  0.42  0.44  0.33  1.0
  P  P2  1  0.0  0.0  0.0  1.0
  W  W3  1  0.0  0.0  0.63  1.0

data_Cd2PW
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.84
_cell_length_b   4.88
_cell_length_c   5.26
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2PW
_chemical_formula_sum   'Cd2 P1 W1'
_cell_volume   72.83
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.42  0.44  0.33  1.0
  Cd  Cd1  1  0.42  0.44  0.93  1.0
  P  P2  1  0.0  0.0  0.0  1.0
  W  W3  1  0.0  0.0  0.63  1.0

Cd Cd P W
WCd2P crystallizes in the triclinic P1 space group. W(1) is bonded in a 1-coordinate geometry to four equivalent Cd(1), four equivalent Cd(2), and one P(1) atom. There are a spread of W(1)-Cd(1) bond distances ranging from 2.91-3.56 Å. There are a spread of W(1)-Cd(2) bond distances ranging from 2.91-3.56 Å. The W(1)-P(1) bond length is 1.95 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 12-coordinate geometry to four equivalent W(1), two equivalent Cd(1), two equivalent Cd(2), and four equivalent P(1) atoms. Both Cd(1)-Cd(1) bond lengths are 2.84 Å. There is one shorter (2.14 Å) and one longer (3.12 Å) Cd(1)-Cd(2) bond length. There are a spread of Cd(1)-P(1) bond distances ranging from 2.48-3.22 Å. In the second Cd site, Cd(2) is bonded in a 10-coordinate geometry to four equivalent W(1), two equivalent Cd(1), two equivalent Cd(2), and two equivalent P(1) atoms. Both Cd(2)-Cd(2) bond lengths are 2.84 Å. There is one shorter (3.01 Å) and one longer (3.21 Å) Cd(2)-P(1) bond length. P(1) is bonded in a 2-coordinate geometry to one W(1), two equivalent Cd(2), and four equivalent Cd(1) atoms.