data_DyClO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.79
_cell_length_b   4.19
_cell_length_c   9.47
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   DyClO
_chemical_formula_sum   'Dy2 Cl2 O2'
_cell_volume   150.59
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.9  0.0  0.07  1.0
  Dy  Dy1  1  0.0  0.1  0.41  1.0
  Cl  Cl2  1  0.0  0.0  0.97  1.0
  Cl  Cl3  1  0.9  0.1  0.5  1.0
  O  O4  1  0.0  0.0  0.22  1.0
  O  O5  1  0.9  0.1  0.25  1.0

data_DyClO
_symmetry_space_group_name_H-M   P-1
_cell_length_a   3.79
_cell_length_b   4.19
_cell_length_c   9.47
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   2
_chemical_formula_structural   DyClO
_chemical_formula_sum   'Dy2 Cl2 O2'
_cell_volume   150.59
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  2  0.45  0.95  0.83  1.0
  Cl  Cl1  2  0.45  0.05  0.26  1.0
  O  O2  2  0.45  0.05  0.02  1.0

Dy Dy Cl Cl O O
DyOCl crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one DyOCl cluster. Dy(1) is bonded in a distorted bent 150 degrees geometry to one O(1) and one Cl(1) atom. The Dy(1)-O(1) bond length is 1.50 Å. The Dy(1)-Cl(1) bond length is 0.96 Å. O(1) is bonded in a distorted water-like geometry to one Dy(1) and one O(1) atom. The O(1)-O(1) bond length is 0.64 Å. Cl(1) is bonded in a single-bond geometry to one Dy(1) atom.