data_Zn2BPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.68
_cell_length_b   4.68
_cell_length_c   4.68
_cell_angle_alpha   135.14
_cell_angle_beta   135.14
_cell_angle_gamma   65.31
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zn2BPd
_chemical_formula_sum   'Zn2 B1 Pd1'
_cell_volume   50.1
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn2  1  0.0  0.78  0.97  1.0
  Zn  Zn3  1  0.78  0.0  0.97  1.0
  B  B0  1  0.0  0.0  0.0  1.0
  Pd  Pd1  1  0.0  0.0  0.94  1.0

data_Zn2BPd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.05
_cell_length_b   5.05
_cell_length_c   4.68
_cell_angle_alpha   90.0
_cell_angle_beta   122.66
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Zn2BPd
_chemical_formula_sum   'Zn4 B2 Pd2'
_cell_volume   100.19
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  4  0.42  0.39  0.82  1.0
  B  B1  2  0.0  0.0  0.0  1.0
  Pd  Pd2  2  0.06  0.0  0.06  1.0

Zn Zn B Pd
PdZn2B is Indium-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two PdZn2B clusters. Pd(1) is bonded in a single-bond geometry to one B(1) atom. The Pd(1)-B(1) bond length is 0.30 Å. Zn(1) is bonded in a single-bond geometry to one B(1) atom. The Zn(1)-B(1) bond length is 0.91 Å. B(1) is bonded in a 3-coordinate geometry to one Pd(1) and two equivalent Zn(1) atoms.