data_TcRu2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.59
_cell_length_b   4.59
_cell_length_c   2.81
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   95.39
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TcRu2Cl
_chemical_formula_sum   'Tc1 Ru2 Cl1'
_cell_volume   59.0
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc3  1  0.09  0.0  0.0  1.0
  Ru  Ru1  1  0.54  0.7  0.41  1.0
  Ru  Ru2  1  0.54  0.3  0.41  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_TcRu2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.81
_cell_length_b   4.59
_cell_length_c   4.59
_cell_angle_alpha   95.39
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TcRu2Cl
_chemical_formula_sum   'Tc1 Ru2 Cl1'
_cell_volume   59.0
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.0  0.09  0.0  1.0
  Ru  Ru1  1  0.41  0.54  0.3  1.0
  Ru  Ru2  1  0.41  0.54  0.7  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Tc Ru Ru Cl
TcRu2Cl crystallizes in the triclinic P1 space group. Tc(1) is bonded in a single-bond geometry to two equivalent Ru(1), two equivalent Ru(2), and one Cl(1) atom. There is one shorter (2.85 Å) and one longer (3.10 Å) Tc(1)-Ru(1) bond length. There is one shorter (2.65 Å) and one longer (2.92 Å) Tc(1)-Ru(2) bond length. The Tc(1)-Cl(1) bond length is 0.41 Å. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a 8-coordinate geometry to two equivalent Tc(1), two equivalent Ru(1), two equivalent Ru(2), and two equivalent Cl(1) atoms. Both Ru(1)-Ru(1) bond lengths are 2.81 Å. There is one shorter (1.81 Å) and one longer (2.78 Å) Ru(1)-Ru(2) bond length. There is one shorter (2.65 Å) and one longer (2.92 Å) Ru(1)-Cl(1) bond length. In the second Ru site, Ru(2) is bonded in a 8-coordinate geometry to two equivalent Tc(1), two equivalent Ru(1), two equivalent Ru(2), and two equivalent Cl(1) atoms. Both Ru(2)-Ru(2) bond lengths are 2.81 Å. There is one shorter (2.85 Å) and one longer (3.10 Å) Ru(2)-Cl(1) bond length. Cl(1) is bonded in a single-bond geometry to one Tc(1), two equivalent Ru(1), and two equivalent Ru(2) atoms.