data_V2CrW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.69
_cell_length_b   4.69
_cell_length_c   4.69
_cell_angle_alpha   131.8
_cell_angle_beta   131.8
_cell_angle_gamma   70.54
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2CrW
_chemical_formula_sum   'V2 Cr1 W1'
_cell_volume   56.26
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V1  1  0.0  0.92  0.92  1.0
  V  V2  1  0.0  0.0  0.0  1.0
  Cr  Cr0  1  0.0  0.0  0.83  1.0
  W  W3  1  0.92  0.0  0.92  1.0

data_V2CrW
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.83
_cell_length_b   3.83
_cell_length_c   4.69
_cell_angle_alpha   114.1
_cell_angle_beta   114.1
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2CrW
_chemical_formula_sum   'V2 Cr1 W1'
_cell_volume   56.26
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  V  V1  1  0.0  0.92  0.0  1.0
  Cr  Cr2  1  0.17  0.0  0.17  1.0
  W  W3  1  0.08  0.0  0.0  1.0

V V Cr W
V2WCr crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one V2WCr cluster. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 3-coordinate geometry to one V(2), one W(1), and one Cr(1) atom. The V(1)-V(2) bond length is 0.32 Å. The V(1)-W(1) bond length is 0.46 Å. The V(1)-Cr(1) bond length is 0.72 Å. In the second V site, V(2) is bonded in a distorted single-bond geometry to one V(1) and one W(1) atom. The V(2)-W(1) bond length is 0.32 Å. W(1) is bonded in a distorted single-bond geometry to one V(1), one V(2), and one Cr(1) atom. The W(1)-Cr(1) bond length is 0.72 Å. Cr(1) is bonded in a 2-coordinate geometry to one V(1) and one W(1) atom.