data_SbOs2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.16
_cell_length_b   9.16
_cell_length_c   9.16
_cell_angle_alpha   18.3
_cell_angle_beta   18.3
_cell_angle_gamma   18.3
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SbOs2Pd
_chemical_formula_sum   'Sb1 Os2 Pd1'
_cell_volume   66.07
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb3  1  0.0  0.0  0.24  1.0
  Os  Os0  1  0.0  0.0  0.87  1.0
  Os  Os1  1  0.0  0.0  0.85  1.0
  Pd  Pd2  1  0.0  0.0  0.54  1.0

data_SbOs2Pd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.04
_cell_length_b   2.91
_cell_length_c   9.16
_cell_angle_alpha   90.0
_cell_angle_beta   100.58
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   SbOs2Pd
_chemical_formula_sum   'Sb2 Os4 Pd2'
_cell_volume   132.13
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  2  0.0  0.0  0.76  1.0
  Os  Os1  2  0.0  0.0  0.13  1.0
  Os  Os2  2  0.0  0.0  0.15  1.0
  Pd  Pd3  2  0.0  0.0  0.46  1.0

Sb Os Os Pd
Os2PdSb crystallizes in the monoclinic Cm space group. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a single-bond geometry to one Os(2) and one Sb(1) atom. The Os(1)-Os(2) bond length is 0.19 Å. The Os(1)-Sb(1) bond length is 3.36 Å. In the second Os site, Os(2) is bonded in a single-bond geometry to one Os(1) and one Pd(1) atom. The Os(2)-Pd(1) bond length is 2.87 Å. Pd(1) is bonded to one Os(2), six equivalent Pd(1), and one Sb(1) atom to form distorted PdSbOsPd6 hexagonal bipyramids that share corners with six equivalent Pd(1)SbOsPd6 hexagonal bipyramids, edges with six equivalent Sb(1)Sb6OsPd hexagonal bipyramids, and edges with twelve equivalent Pd(1)SbOsPd6 hexagonal bipyramids. All Pd(1)-Pd(1) bond lengths are 2.91 Å. The Pd(1)-Sb(1) bond length is 2.73 Å. Sb(1) is bonded to one Os(1), one Pd(1), and six equivalent Sb(1) atoms to form distorted SbSb6OsPd hexagonal bipyramids that share corners with six equivalent Sb(1)Sb6OsPd hexagonal bipyramids, edges with six equivalent Pd(1)SbOsPd6 hexagonal bipyramids, and edges with twelve equivalent Sb(1)Sb6OsPd hexagonal bipyramids. All Sb(1)-Sb(1) bond lengths are 2.91 Å.