data_ZrTcAg2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.59
_cell_length_b   5.59
_cell_length_c   2.79
_cell_angle_alpha   97.97
_cell_angle_beta   97.97
_cell_angle_gamma   121.83
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrTcAg2
_chemical_formula_sum   'Zr1 Tc1 Ag2'
_cell_volume   71.13
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr3  1  0.0  0.0  0.0  1.0
  Tc  Tc2  1  0.72  0.0  0.0  1.0
  Ag  Ag0  1  0.96  0.44  0.34  1.0
  Ag  Ag1  1  0.96  0.56  0.34  1.0

data_ZrTcAg2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.79
_cell_length_b   5.36
_cell_length_c   5.59
_cell_angle_alpha   114.91
_cell_angle_beta   97.97
_cell_angle_gamma   103.38
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrTcAg2
_chemical_formula_sum   'Zr1 Tc1 Ag2'
_cell_volume   71.13
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.0  0.0  0.0  1.0
  Tc  Tc1  1  -0.0  0.0  0.72  1.0
  Ag  Ag2  1  0.78  0.44  0.41  1.0
  Ag  Ag3  1  0.89  0.56  0.52  1.0

Zr Tc Ag Ag
ZrTc(Ag)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Ag cluster and one ZrTc cluster. In the Ag cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted single-bond geometry to one Ag(2) atom. The Ag(1)-Ag(2) bond length is 0.62 Å. In the second Ag site, Ag(2) is bonded in a distorted single-bond geometry to one Ag(1) atom. In the ZrTc cluster, Zr(1) is bonded in a distorted single-bond geometry to one Tc(1) atom. The Zr(1)-Tc(1) bond length is 1.57 Å. Tc(1) is bonded in a distorted single-bond geometry to one Zr(1) atom.