data_V2GaGe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.82
_cell_length_b   4.82
_cell_length_c   4.82
_cell_angle_alpha   139.79
_cell_angle_beta   126.38
_cell_angle_gamma   69.09
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2GaGe
_chemical_formula_sum   'V2 Ga1 Ge1'
_cell_volume   57.16
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.66  0.0  0.02  1.0
  V  V3  1  0.0  0.17  0.95  1.0
  Ga  Ga0  1  0.0  0.0  0.0  1.0
  Ge  Ge1  1  0.0  0.0  0.97  1.0

data_V2GaGe
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.31
_cell_length_b   4.35
_cell_length_c   4.82
_cell_angle_alpha   116.81
_cell_angle_beta   110.11
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2GaGe
_chemical_formula_sum   'V2 Ga1 Ge1'
_cell_volume   57.16
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.02  0.36  1.0
  V  V1  1  0.83  0.78  0.78  1.0
  Ga  Ga2  1  0.0  0.0  0.0  1.0
  Ge  Ge3  1  0.0  0.97  0.97  1.0

V V Ga Ge
V2GaGe crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one V2GaGe cluster. There are two inequivalent V sites. In the first V site, V(1) is bonded in a single-bond geometry to one Ga(1) atom. The V(1)-Ga(1) bond length is 1.70 Å. In the second V site, V(2) is bonded in a single-bond geometry to one Ge(1) atom. The V(2)-Ge(1) bond length is 0.90 Å. Ga(1) is bonded in a single-bond geometry to one V(1) and one Ge(1) atom. The Ga(1)-Ge(1) bond length is 0.15 Å. Ge(1) is bonded in a distorted bent 150 degrees geometry to one V(2) and one Ga(1) atom.