data_TlTc2Mo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.14
_cell_length_b   5.14
_cell_length_c   5.14
_cell_angle_alpha   135.41
_cell_angle_beta   135.41
_cell_angle_gamma   64.89
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlTc2Mo
_chemical_formula_sum   'Tl1 Tc2 Mo1'
_cell_volume   65.95
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl3  1  0.0  0.95  0.17  1.0
  Tc  Tc1  1  0.95  0.0  0.17  1.0
  Tc  Tc2  1  0.0  0.0  0.34  1.0
  Mo  Mo0  1  0.0  0.0  0.0  1.0

data_TlTc2Mo
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.9
_cell_length_b   3.9
_cell_length_c   5.14
_cell_angle_alpha   112.29
_cell_angle_beta   112.29
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlTc2Mo
_chemical_formula_sum   'Tl1 Tc2 Mo1'
_cell_volume   65.95
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.22  0.17  0.22  1.0
  Tc  Tc1  1  0.17  0.22  0.22  1.0
  Tc  Tc2  1  0.34  0.34  0.34  1.0
  Mo  Mo3  1  0.0  0.0  0.0  1.0

Tl Tc Tc Mo
MoTc2Tl is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one MoTc2Tl cluster. Mo(1) is bonded in a 2-coordinate geometry to one Tc(1) and one Tl(1) atom. The Mo(1)-Tc(1) bond length is 1.07 Å. The Mo(1)-Tl(1) bond length is 1.07 Å. There are two inequivalent Tc sites. In the first Tc site, Tc(1) is bonded in a single-bond geometry to one Mo(1) and one Tl(1) atom. The Tc(1)-Tl(1) bond length is 0.28 Å. In the second Tc site, Tc(2) is bonded in a 1-coordinate geometry to one Tl(1) atom. The Tc(2)-Tl(1) bond length is 0.71 Å. Tl(1) is bonded in a single-bond geometry to one Mo(1), one Tc(1), and one Tc(2) atom.