data_Re2MoIr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.81
_cell_length_b   4.81
_cell_length_c   4.83
_cell_angle_alpha   99.3
_cell_angle_beta   99.3
_cell_angle_gamma   33.3
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Re2MoIr
_chemical_formula_sum   'Re2 Mo1 Ir1'
_cell_volume   60.39
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re2  1  0.39  0.0  0.72  1.0
  Re  Re3  1  0.67  0.0  0.58  1.0
  Mo  Mo1  1  0.72  0.0  0.21  1.0
  Ir  Ir0  1  0.22  0.0  0.39  1.0

data_Re2MoIr
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.75
_cell_length_b   4.81
_cell_length_c   4.83
_cell_angle_alpha   99.3
_cell_angle_beta   90.0
_cell_angle_gamma   106.65
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Re2MoIr
_chemical_formula_sum   'Re2 Mo1 Ir1'
_cell_volume   60.39
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.0  0.33  0.42  1.0
  Re  Re1  1  0.0  0.61  0.28  1.0
  Mo  Mo2  1  0.0  0.28  0.79  1.0
  Ir  Ir3  1  0.0  0.78  0.61  1.0

Re Re Mo Ir
MoReReIr crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one MoRe cluster and one ReIr cluster. In the MoRe cluster, Mo(1) is bonded in a distorted single-bond geometry to one Re(2) atom. The Mo(1)-Re(2) bond length is 1.81 Å. Re(2) is bonded in a 1-coordinate geometry to one Mo(1) atom. In the ReIr cluster, Re(1) is bonded in a 1-coordinate geometry to one Ir(1) atom. The Re(1)-Ir(1) bond length is 1.66 Å. Ir(1) is bonded in a distorted single-bond geometry to one Re(1) atom.