data_GaAg2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.39
_cell_length_b   5.39
_cell_length_c   5.39
_cell_angle_alpha   144.89
_cell_angle_beta   131.63
_cell_angle_gamma   61.16
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaAg2Pd
_chemical_formula_sum   'Ga1 Ag2 Pd1'
_cell_volume   66.49
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga2  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.62  0.0  0.19  1.0
  Ag  Ag1  1  0.0  0.21  0.45  1.0
  Pd  Pd3  1  0.0  0.0  0.64  1.0

data_GaAg2Pd
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.25
_cell_length_b   4.41
_cell_length_c   5.39
_cell_angle_alpha   114.19
_cell_angle_beta   107.55
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaAg2Pd
_chemical_formula_sum   'Ga1 Ag2 Pd1'
_cell_volume   66.49
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.0  0.0  0.0  1.0
  Ag  Ag1  1  0.44  0.81  0.44  1.0
  Ag  Ag2  1  0.55  0.76  0.76  1.0
  Pd  Pd3  1  0.36  0.36  0.36  1.0

Ga Ag Ag Pd
PdAg2Ga crystallizes in the triclinic P1 space group. Pd(1) is bonded in a 4-coordinate geometry to one Ag(2), two equivalent Ag(1), and one Ga(1) atom. The Pd(1)-Ag(2) bond length is 2.02 Å. There is one shorter (1.86 Å) and one longer (2.62 Å) Pd(1)-Ag(1) bond length. The Pd(1)-Ga(1) bond length is 1.95 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to two equivalent Pd(1) and one Ag(2) atom. The Ag(1)-Ag(2) bond length is 1.76 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one Pd(1), one Ag(1), and two equivalent Ga(1) atoms. There is one shorter (1.65 Å) and one longer (2.52 Å) Ag(2)-Ga(1) bond length. Ga(1) is bonded in a 2-coordinate geometry to one Pd(1) and two equivalent Ag(2) atoms.