data_TiPtW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.54
_cell_length_b   6.54
_cell_length_c   6.54
_cell_angle_alpha   155.61
_cell_angle_beta   155.61
_cell_angle_gamma   34.76
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiPtW
_chemical_formula_sum   'Ti1 Pt1 W1'
_cell_volume   47.74
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti1  1  0.0  0.0  0.3  1.0
  Pt  Pt0  1  0.0  0.0  0.49  1.0
  W  W2  1  0.0  0.0  0.2  1.0

data_TiPtW
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.91
_cell_length_b   3.91
_cell_length_c   6.54
_cell_angle_alpha   90.0
_cell_angle_beta   107.38
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TiPtW
_chemical_formula_sum   'Ti2 Pt2 W2'
_cell_volume   95.48
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  2  0.3  0.0  0.3  1.0
  Pt  Pt1  2  0.49  0.0  0.49  1.0
  W  W2  2  0.2  0.0  0.2  1.0

Ti Pt W
TiWPt is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two TiWPt clusters. Ti(1) is bonded in a linear geometry to one W(1) and one Pt(1) atom. The Ti(1)-W(1) bond length is 0.62 Å. The Ti(1)-Pt(1) bond length is 1.23 Å. W(1) is bonded in a single-bond geometry to one Ti(1) atom. Pt(1) is bonded in a single-bond geometry to one Ti(1) atom.