data_Ti2SbOs
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.76
_cell_length_b   4.76
_cell_length_c   3.12
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   108.11
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ti2SbOs
_chemical_formula_sum   'Ti2 Sb1 Os1'
_cell_volume   67.12
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti2  1  0.4  0.93  0.56  1.0
  Ti  Ti3  1  0.4  0.07  0.56  1.0
  Sb  Sb1  1  0.0  0.0  0.0  1.0
  Os  Os0  1  0.79  0.0  0.0  1.0

data_Ti2SbOs
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.12
_cell_length_b   4.76
_cell_length_c   4.76
_cell_angle_alpha   108.11
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ti2SbOs
_chemical_formula_sum   'Ti2 Sb1 Os1'
_cell_volume   67.12
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.56  0.4  0.93  1.0
  Ti  Ti1  1  0.56  0.4  0.07  1.0
  Sb  Sb2  1  0.0  0.0  0.0  1.0
  Os  Os3  1  0.0  0.79  0.0  1.0

Ti Ti Sb Os
(Ti)2OsSb crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one OsSb cluster and one Ti cluster. In the OsSb cluster, Os(1) is bonded in a 1-coordinate geometry to one Sb(1) atom. The Os(1)-Sb(1) bond length is 0.99 Å. Sb(1) is bonded in a 1-coordinate geometry to one Os(1) atom. In the Ti cluster, there are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a distorted single-bond geometry to one Ti(2) atom. The Ti(1)-Ti(2) bond length is 0.70 Å. In the second Ti site, Ti(2) is bonded in a distorted single-bond geometry to one Ti(1) atom.