data_GaSb2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.3
_cell_length_b   3.3
_cell_length_c   8.14
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaSb2Pd
_chemical_formula_sum   'Ga1 Sb2 Pd1'
_cell_volume   88.65
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.0  0.0  0.0  1.0
  Sb  Sb2  1  0.65  0.65  0.85  1.0
  Sb  Sb3  1  0.65  0.65  0.29  1.0
  Pd  Pd1  1  0.0  0.0  0.07  1.0

data_GaSb2Pd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.67
_cell_length_b   4.67
_cell_length_c   8.14
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   GaSb2Pd
_chemical_formula_sum   'Ga2 Sb4 Pd2'
_cell_volume   177.31
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  2  0.0  0.0  0.0  1.0
  Sb  Sb1  2  0.15  0.5  0.29  1.0
  Sb  Sb2  2  0.15  0.5  0.85  1.0
  Pd  Pd3  2  0.0  0.0  0.07  1.0

Ga Sb Sb Pd
PdGaSb2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two PdGaSb2 clusters. Pd(1) is bonded in a single-bond geometry to one Ga(1) and one Sb(2) atom. The Pd(1)-Ga(1) bond length is 0.59 Å. The Pd(1)-Sb(2) bond length is 2.42 Å. Ga(1) is bonded in a single-bond geometry to one Pd(1) and one Sb(1) atom. The Ga(1)-Sb(1) bond length is 2.02 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted single-bond geometry to one Ga(1) atom. In the second Sb site, Sb(2) is bonded in a distorted single-bond geometry to one Pd(1) atom.