data_GaSiAg2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.03
_cell_length_b   5.03
_cell_length_c   5.03
_cell_angle_alpha   131.93
_cell_angle_beta   131.93
_cell_angle_gamma   70.33
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaSiAg2
_chemical_formula_sum   'Ga1 Si1 Ag2'
_cell_volume   69.11
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga2  1  0.0  0.05  0.06  1.0
  Si  Si3  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.05  0.0  0.06  1.0
  Ag  Ag1  1  0.0  0.0  0.11  1.0

data_GaSiAg2
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.1
_cell_length_b   4.1
_cell_length_c   5.03
_cell_angle_alpha   114.03
_cell_angle_beta   114.03
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaSiAg2
_chemical_formula_sum   'Ga1 Si1 Ag2'
_cell_volume   69.11
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.99  0.05  0.99  1.0
  Si  Si1  1  0.0  0.0  0.0  1.0
  Ag  Ag2  1  0.89  0.0  0.89  1.0
  Ag  Ag3  1  0.94  0.0  0.99  1.0

Ga Si Ag Ag
Ag2GaSi is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Ag2GaSi cluster. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one Ag(2), one Ga(1), and one Si(1) atom. The Ag(1)-Ag(2) bond length is 0.49 Å. The Ag(1)-Ga(1) bond length is 0.29 Å. The Ag(1)-Si(1) bond length is 0.22 Å. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one Ag(1) and one Ga(1) atom. The Ag(2)-Ga(1) bond length is 0.49 Å. Ga(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one Si(1) atom. The Ga(1)-Si(1) bond length is 0.22 Å. Si(1) is bonded in an L-shaped geometry to one Ag(1) and one Ga(1) atom.