data_ScGe2Os
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.24
_cell_length_b   3.24
_cell_length_c   6.38
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScGe2Os
_chemical_formula_sum   'Sc1 Ge2 Os1'
_cell_volume   67.01
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc3  1  0.0  0.0  0.77  1.0
  Ge  Ge0  1  0.62  0.62  0.13  1.0
  Ge  Ge1  1  0.0  0.0  0.73  1.0
  Os  Os2  1  0.62  0.62  0.94  1.0

data_ScGe2Os
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.58
_cell_length_b   4.58
_cell_length_c   6.38
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ScGe2Os
_chemical_formula_sum   'Sc2 Ge4 Os2'
_cell_volume   134.02
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  2  0.0  0.0  0.77  1.0
  Ge  Ge1  2  0.0  0.0  0.73  1.0
  Ge  Ge2  2  0.12  0.5  0.13  1.0
  Os  Os3  2  0.12  0.5  0.94  1.0

Sc Ge Ge Os
ScOsGe2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ScOsGe2 clusters. Sc(1) is bonded in a single-bond geometry to one Os(1) and one Ge(2) atom. The Sc(1)-Os(1) bond length is 2.07 Å. The Sc(1)-Ge(2) bond length is 0.20 Å. Os(1) is bonded in a 2-coordinate geometry to one Sc(1) and one Ge(1) atom. The Os(1)-Ge(1) bond length is 1.19 Å. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a single-bond geometry to one Os(1) atom. In the second Ge site, Ge(2) is bonded in a single-bond geometry to one Sc(1) atom.