data_Y2VSn
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.58
_cell_length_b   5.58
_cell_length_c   4.92
_cell_angle_alpha   115.98
_cell_angle_beta   115.98
_cell_angle_gamma   44.15
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Y2VSn
_chemical_formula_sum   'Y2 V1 Sn1'
_cell_volume   94.15
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y2  1  0.86  0.0  0.37  1.0
  Y  Y3  1  0.16  0.0  0.97  1.0
  V  V1  1  0.0  0.0  0.0  1.0
  Sn  Sn0  1  0.01  0.0  0.17  1.0

data_Y2VSn
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.2
_cell_length_b   4.92
_cell_length_c   5.58
_cell_angle_alpha   115.98
_cell_angle_beta   112.08
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Y2VSn
_chemical_formula_sum   'Y2 V1 Sn1'
_cell_volume   94.15
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.0  0.37  0.86  1.0
  Y  Y1  1  0.0  0.97  0.16  1.0
  V  V2  1  0.0  0.0  0.0  1.0
  Sn  Sn3  1  0.0  0.17  0.01  1.0

Y Y V Sn
Y2VSn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Y2VSn cluster. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded in a single-bond geometry to one Sn(1) atom. The Y(1)-Sn(1) bond length is 1.56 Å. In the second Y site, Y(2) is bonded in a single-bond geometry to one V(1) atom. The Y(2)-V(1) bond length is 0.97 Å. V(1) is bonded in a bent 120 degrees geometry to one Y(2) and one Sn(1) atom. The V(1)-Sn(1) bond length is 0.81 Å. Sn(1) is bonded in a bent 150 degrees geometry to one Y(1) and one V(1) atom.