data_VP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.43
_cell_length_b   4.43
_cell_length_c   4.07
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   140.28
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VP
_chemical_formula_sum   'V2 P2'
_cell_volume   51.13
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.51  0.92  0.05  1.0
  V  V3  1  0.51  0.08  0.02  1.0
  P  P0  1  0.51  0.25  0.05  1.0
  P  P1  1  0.51  0.75  0.02  1.0

data_VP
_symmetry_space_group_name_H-M   P-1
_cell_length_a   3.01
_cell_length_b   4.07
_cell_length_c   4.43
_cell_angle_alpha   90.0
_cell_angle_beta   109.86
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   2
_chemical_formula_structural   VP
_chemical_formula_sum   'V2 P2'
_cell_volume   51.13
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.08  0.52  0.08  1.0
  P  P1  2  0.25  0.48  0.25  1.0

V V P P
VP1 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one VP1 cluster. V(1) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(1) atom. The V(1)-V(1) bond length is 0.71 Å. The V(1)-P(1) bond length is 0.76 Å. P(1) is bonded in a single-bond geometry to one V(1) atom.