data_ZrMoP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.35
_cell_length_b   5.35
_cell_length_c   5.35
_cell_angle_alpha   144.83
_cell_angle_beta   144.83
_cell_angle_gamma   50.58
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrMoP
_chemical_formula_sum   'Zr1 Mo1 P1'
_cell_volume   50.4
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr2  1  0.0  0.0  0.49  1.0
  Mo  Mo0  1  0.0  0.0  0.34  1.0
  P  P1  1  0.0  0.0  0.5  1.0

data_ZrMoP
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.57
_cell_length_b   4.57
_cell_length_c   5.35
_cell_angle_alpha   90.0
_cell_angle_beta   115.29
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZrMoP
_chemical_formula_sum   'Zr2 Mo2 P2'
_cell_volume   100.81
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  2  0.0  0.0  0.51  1.0
  Mo  Mo1  2  0.0  0.0  0.66  1.0
  P  P2  2  0.0  0.0  0.5  1.0

Zr Mo P
ZrMoP is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ZrMoP clusters. Zr(1) is bonded in a linear geometry to one Mo(1) and one P(1) atom. The Zr(1)-Mo(1) bond length is 0.79 Å. The Zr(1)-P(1) bond length is 0.04 Å. Mo(1) is bonded in a single-bond geometry to one Zr(1) atom. P(1) is bonded in a single-bond geometry to one Zr(1) atom.