data_NaLaSc
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.48
_cell_length_b   9.23
_cell_length_c   3.39
_cell_angle_alpha   83.72
_cell_angle_beta   75.48
_cell_angle_gamma   20.8
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaLaSc
_chemical_formula_sum   'Na1 La1 Sc1'
_cell_volume   94.83
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na1  1  0.85  0.84  0.18  1.0
  La  La0  1  0.85  0.84  0.86  1.0
  Sc  Sc2  1  0.85  0.84  0.12  1.0

data_NaLaSc
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.7
_cell_length_b   18.08
_cell_length_c   3.39
_cell_angle_alpha   90.0
_cell_angle_beta   123.11
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   NaLaSc
_chemical_formula_sum   'Na2 La2 Sc2'
_cell_volume   189.66
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  2  0.13  0.0  0.97  1.0
  La  La1  2  0.45  0.0  0.29  1.0
  Sc  Sc2  2  0.19  0.0  0.03  1.0

Na La Sc
NaLaSc crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two NaLaSc clusters. Na(1) is bonded in a single-bond geometry to one Sc(1) atom. The Na(1)-Sc(1) bond length is 0.21 Å. La(1) is bonded in a distorted single-bond geometry to one Sc(1) atom. The La(1)-Sc(1) bond length is 0.87 Å. Sc(1) is bonded in a linear geometry to one Na(1) and one La(1) atom.