data_KGaRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.32
_cell_length_b   9.32
_cell_length_c   9.32
_cell_angle_alpha   18.61
_cell_angle_beta   18.61
_cell_angle_gamma   18.61
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KGaRh2
_chemical_formula_sum   'K1 Ga1 Rh2'
_cell_volume   72.05
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K1  1  0.0  0.0  0.0  1.0
  Ga  Ga0  1  0.0  0.0  0.74  1.0
  Rh  Rh2  1  0.0  0.0  0.06  1.0
  Rh  Rh3  1  0.0  0.0  0.41  1.0

data_KGaRh2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.22
_cell_length_b   3.01
_cell_length_c   9.32
_cell_angle_alpha   90.0
_cell_angle_beta   100.76
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   KGaRh2
_chemical_formula_sum   'K2 Ga2 Rh4'
_cell_volume   144.1
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  2  0.0  0.0  0.0  1.0
  Ga  Ga1  2  -0.0  0.0  0.26  1.0
  Rh  Rh2  2  0.0  0.0  0.59  1.0
  Rh  Rh3  2  0.0  0.0  0.94  1.0

K Ga Rh Rh
KRh2Ga crystallizes in the monoclinic Cm space group. K(1) is bonded in a single-bond geometry to one Rh(1) and one Ga(1) atom. The K(1)-Rh(1) bond length is 0.60 Å. The K(1)-Ga(1) bond length is 2.47 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a single-bond geometry to one K(1) and one Rh(2) atom. The Rh(1)-Rh(2) bond length is 3.20 Å. In the second Rh site, Rh(2) is bonded in a distorted single-bond geometry to one Rh(1), six equivalent Rh(2), and one Ga(1) atom. All Rh(2)-Rh(2) bond lengths are 3.01 Å. The Rh(2)-Ga(1) bond length is 3.06 Å. Ga(1) is bonded in a distorted single-bond geometry to one K(1) and one Rh(2) atom.