data_VTe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.56
_cell_length_b   3.36
_cell_length_c   5.04
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VTe
_chemical_formula_sum   'V2 Te2'
_cell_volume   77.17
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.42  0.0  0.9  1.0
  V  V3  1  0.14  0.0  0.14  1.0
  Te  Te0  1  0.42  0.68  0.78  1.0
  Te  Te1  1  0.14  0.68  0.26  1.0

data_VTe
_symmetry_space_group_name_H-M   P2
_cell_length_a   4.56
_cell_length_b   3.36
_cell_length_c   5.04
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   3
_chemical_formula_structural   VTe
_chemical_formula_sum   'V2 Te2'
_cell_volume   77.17
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.14  0.0  0.88  1.0
  Te  Te1  2  0.14  0.68  0.76  1.0

V V Te Te
TeV crystallizes in the monoclinic P2 space group. The structure is zero-dimensional and consists of two vanadium monotelluride molecules. V(1) is bonded in a distorted single-bond geometry to one Te(1) atom. The V(1)-Te(1) bond length is 1.23 Å. Te(1) is bonded in a distorted single-bond geometry to one V(1) atom.