data_BAsIr2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.13
_cell_length_b   6.13
_cell_length_c   6.13
_cell_angle_alpha   31.64
_cell_angle_beta   31.64
_cell_angle_gamma   31.64
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BAsIr2
_chemical_formula_sum   'B1 As1 Ir2'
_cell_volume   56.18
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B1  1  0.0  0.0  0.0  1.0
  As  As0  1  0.0  0.0  0.72  1.0
  Ir  Ir2  1  0.0  0.0  0.64  1.0
  Ir  Ir3  1  0.0  0.0  0.81  1.0

data_BAsIr2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.79
_cell_length_b   3.34
_cell_length_c   6.13
_cell_angle_alpha   90.0
_cell_angle_beta   108.35
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   BAsIr2
_chemical_formula_sum   'B2 As2 Ir4'
_cell_volume   112.37
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  2  0.0  0.0  0.0  1.0
  As  As1  2  -0.0  0.0  0.28  1.0
  Ir  Ir2  2  -0.0  0.0  0.36  1.0
  Ir  Ir3  2  -0.0  0.0  0.19  1.0

B As Ir Ir
Ir2BAs is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Ir2BAs clusters. There are two inequivalent Ir sites. In the first Ir site, Ir(1) is bonded in a single-bond geometry to one As(1) atom. The Ir(1)-As(1) bond length is 0.53 Å. In the second Ir site, Ir(2) is bonded in a linear geometry to one B(1) and one As(1) atom. The Ir(2)-B(1) bond length is 1.17 Å. The Ir(2)-As(1) bond length is 0.53 Å. B(1) is bonded in a single-bond geometry to one Ir(2) atom. As(1) is bonded in a linear geometry to one Ir(1) and one Ir(2) atom.