data_Ag3Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.49
_cell_length_b   3.56
_cell_length_c   6.85
_cell_angle_alpha   90.0
_cell_angle_beta   94.27
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ag3Cl
_chemical_formula_sum   'Ag3 Cl1'
_cell_volume   84.94
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.75  0.78  0.83  1.0
  Ag  Ag1  1  0.49  0.0  0.42  1.0
  Ag  Ag2  1  0.23  0.78  0.0  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

data_Ag3Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.49
_cell_length_b   3.56
_cell_length_c   6.85
_cell_angle_alpha   90.0
_cell_angle_beta   94.27
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ag3Cl
_chemical_formula_sum   'Ag3 Cl1'
_cell_volume   84.94
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.23  0.78  0.0  1.0
  Ag  Ag1  1  0.49  0.0  0.42  1.0
  Ag  Ag2  1  0.75  0.78  0.83  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Ag Ag Ag Cl
Ag3Cl crystallizes in the triclinic P1 space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a single-bond geometry to one Ag(2) and one Cl(1) atom. The Ag(1)-Ag(2) bond length is 3.02 Å. The Ag(1)-Cl(1) bond length is 1.60 Å. In the second Ag site, Ag(2) is bonded in a 7-coordinate geometry to one Ag(1), one Ag(3), four equivalent Ag(2), and one Cl(1) atom. The Ag(2)-Ag(3) bond length is 3.02 Å. There are two shorter (3.49 Å) and two longer (3.56 Å) Ag(2)-Ag(2) bond lengths. The Ag(2)-Cl(1) bond length is 3.21 Å. In the third Ag site, Ag(3) is bonded in a single-bond geometry to one Ag(2) and one Cl(1) atom. The Ag(3)-Cl(1) bond length is 1.13 Å. Cl(1) is bonded in a distorted L-shaped geometry to one Ag(1), one Ag(2), and one Ag(3) atom.