data_AlZnBi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.57
_cell_length_b   6.57
_cell_length_c   6.57
_cell_angle_alpha   150.85
_cell_angle_beta   150.85
_cell_angle_gamma   41.7
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AlZnBi
_chemical_formula_sum   'Al1 Zn1 Bi1'
_cell_volume   67.04
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.0  0.0  0.29  1.0
  Zn  Zn2  1  0.0  0.0  0.88  1.0
  Bi  Bi1  1  0.0  0.0  0.11  1.0

data_AlZnBi
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.67
_cell_length_b   4.67
_cell_length_c   6.57
_cell_angle_alpha   90.0
_cell_angle_beta   110.85
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   AlZnBi
_chemical_formula_sum   'Al2 Zn2 Bi2'
_cell_volume   134.08
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  2  0.29  0.0  0.29  1.0
  Zn  Zn1  2  0.38  0.5  0.88  1.0
  Bi  Bi2  2  0.11  0.0  0.11  1.0

Al Zn Bi
ZnAlBi is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ZnAlBi clusters. Zn(1) is bonded in a single-bond geometry to one Bi(1) atom. The Zn(1)-Bi(1) bond length is 1.49 Å. Al(1) is bonded in a single-bond geometry to one Bi(1) atom. The Al(1)-Bi(1) bond length is 1.18 Å. Bi(1) is bonded in a linear geometry to one Zn(1) and one Al(1) atom.