data_TlTeRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.26
_cell_length_b   3.26
_cell_length_c   7.0
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   91.82
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlTeRh2
_chemical_formula_sum   'Tl1 Te1 Rh2'
_cell_volume   74.55
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl3  1  0.0  0.0  0.5  1.0
  Te  Te2  1  0.0  0.0  0.0  1.0
  Rh  Rh0  1  0.27  0.0  0.4  1.0
  Rh  Rh1  1  0.27  0.0  0.59  1.0

data_TlTeRh2
_symmetry_space_group_name_H-M   Pmm2
_cell_length_a   3.26
_cell_length_b   7.0
_cell_length_c   3.26
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   25
_chemical_formula_structural   TlTeRh2
_chemical_formula_sum   'Tl1 Te1 Rh2'
_cell_volume   74.58
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, z'
  3  '-x, y, z'
  4  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.0  0.0  0.0  1.0
  Te  Te1  1  0.0  0.5  0.0  1.0
  Rh  Rh2  2  0.0  0.1  0.27  1.0

Tl Te Rh Rh
Rh2TlTe crystallizes in the monoclinic Pm space group. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted single-bond geometry to one Tl(1) and one Te(1) atom. The Rh(1)-Tl(1) bond length is 1.11 Å. The Rh(1)-Te(1) bond length is 2.96 Å. In the second Rh site, Rh(2) is bonded in a distorted single-bond geometry to one Tl(1) and one Te(1) atom. The Rh(2)-Tl(1) bond length is 1.11 Å. The Rh(2)-Te(1) bond length is 2.98 Å. Tl(1) is bonded in a 2-coordinate geometry to one Rh(1) and one Rh(2) atom. Te(1) is bonded to one Rh(1), one Rh(2), and four equivalent Te(1) atoms to form a mixture of distorted edge and corner-sharing TeTe4Rh2 octahedra. The corner-sharing octahedra are not tilted. All Te(1)-Te(1) bond lengths are 3.26 Å.