data_RbN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.7
_cell_length_b   5.7
_cell_length_c   5.7
_cell_angle_alpha   113.86
_cell_angle_beta   113.86
_cell_angle_gamma   101.02
_symmetry_Int_Tables_number   1
_chemical_formula_structural   RbN3
_chemical_formula_sum   'Rb2 N6'
_cell_volume   140.33
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb6  1  0.0  0.0  0.81  1.0
  Rb  Rb7  1  0.0  0.0  0.44  1.0
  N  N0  1  0.11  0.0  0.0  1.0
  N  N1  1  0.27  0.84  0.0  1.0
  N  N2  1  0.27  0.16  0.63  1.0
  N  N3  1  0.0  0.11  0.0  1.0
  N  N4  1  0.84  0.95  0.0  1.0
  N  N5  1  0.84  0.27  0.63  1.0

data_RbN3
_symmetry_space_group_name_H-M   P1
_cell_length_a   5.7
_cell_length_b   5.7
_cell_length_c   5.7
_cell_angle_alpha   101.02
_cell_angle_beta   113.86
_cell_angle_gamma   113.86
_symmetry_Int_Tables_number   1
_chemical_formula_structural   RbN3
_chemical_formula_sum   'Rb2 N6'
_cell_volume   140.33
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.44  0.44  0.44  1.0
  Rb  Rb1  1  0.81  0.81  0.81  1.0
  N  N2  1  -0.0  0.0  0.89  1.0
  N  N3  1  -0.0  0.73  0.16  1.0
  N  N4  1  -0.0  0.16  0.05  1.0
  N  N5  1  0.0  0.89  0.0  1.0
  N  N6  1  0.63  0.36  0.47  1.0
  N  N7  1  0.63  0.78  0.36  1.0

Rb Rb N N N N N N
RbN3 is Indium structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one RbN3 cluster. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 2-coordinate geometry to one N(1), one N(4), and one N(6) atom. The Rb(1)-N(1) bond length is 1.00 Å. The Rb(1)-N(4) bond length is 1.00 Å. The Rb(1)-N(6) bond length is 2.33 Å. In the second Rb site, Rb(2) is bonded in a 3-coordinate geometry to one N(3), one N(5), and one N(6) atom. The Rb(2)-N(3) bond length is 1.30 Å. The Rb(2)-N(5) bond length is 2.16 Å. The Rb(2)-N(6) bond length is 2.08 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Rb(1) and one N(2) atom. The N(1)-N(2) bond length is 1.40 Å. In the second N site, N(2) is bonded in a single-bond geometry to one N(1) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Rb(2) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one Rb(1) atom. In the fifth N site, N(5) is bonded in a 1-coordinate geometry to one Rb(2) atom. In the sixth N site, N(6) is bonded in a 2-coordinate geometry to one Rb(1) and one Rb(2) atom.