data_TlRuPt2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.8
_cell_length_b   4.8
_cell_length_c   5.18
_cell_angle_alpha   99.9
_cell_angle_beta   99.9
_cell_angle_gamma   35.43
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlRuPt2
_chemical_formula_sum   'Tl1 Ru1 Pt2'
_cell_volume   68.05
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl3  1  0.56  0.0  0.84  1.0
  Ru  Ru2  1  0.12  0.0  0.36  1.0
  Pt  Pt0  1  0.99  0.0  0.09  1.0
  Pt  Pt1  1  0.65  0.0  0.35  1.0

data_TlRuPt2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.92
_cell_length_b   4.8
_cell_length_c   5.18
_cell_angle_alpha   99.9
_cell_angle_beta   90.0
_cell_angle_gamma   107.72
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlRuPt2
_chemical_formula_sum   'Tl1 Ru1 Pt2'
_cell_volume   68.05
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.0  0.44  0.16  1.0
  Ru  Ru1  1  0.0  0.88  0.64  1.0
  Pt  Pt2  1  0.0  0.01  0.91  1.0
  Pt  Pt3  1  0.0  0.35  0.65  1.0

Tl Ru Pt Pt
RuPt2Tl crystallizes in the triclinic P1 space group. Ru(1) is bonded in a distorted single-bond geometry to one Pt(1), two equivalent Pt(2), and one Tl(1) atom. The Ru(1)-Pt(1) bond length is 1.42 Å. There is one shorter (2.24 Å) and one longer (2.57 Å) Ru(1)-Pt(2) bond length. The Ru(1)-Tl(1) bond length is 2.94 Å. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 2-coordinate geometry to one Ru(1) and three equivalent Tl(1) atoms. There are a spread of Pt(1)-Tl(1) bond distances ranging from 2.28-3.22 Å. In the second Pt site, Pt(2) is bonded in a 4-coordinate geometry to two equivalent Ru(1) and two equivalent Tl(1) atoms. There is one shorter (2.61 Å) and one longer (2.65 Å) Pt(2)-Tl(1) bond length. Tl(1) is bonded in a 8-coordinate geometry to one Ru(1), two equivalent Pt(2), three equivalent Pt(1), and two equivalent Tl(1) atoms. Both Tl(1)-Tl(1) bond lengths are 2.92 Å.