data_LaV2Ga
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.32
_cell_length_b   4.32
_cell_length_c   6.5
_cell_angle_alpha   93.8
_cell_angle_beta   93.8
_cell_angle_gamma   42.24
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaV2Ga
_chemical_formula_sum   'La1 V2 Ga1'
_cell_volume   81.39
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La1  1  0.11  0.0  0.57  1.0
  V  V2  1  0.57  0.0  0.81  1.0
  V  V3  1  0.5  0.0  0.13  1.0
  Ga  Ga0  1  0.83  0.0  0.7  1.0

data_LaV2Ga
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.11
_cell_length_b   4.32
_cell_length_c   6.5
_cell_angle_alpha   93.8
_cell_angle_beta   90.0
_cell_angle_gamma   111.12
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaV2Ga
_chemical_formula_sum   'La1 V2 Ga1'
_cell_volume   81.39
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.89  0.43  1.0
  V  V1  1  0.0  0.43  0.19  1.0
  V  V2  1  0.0  0.5  0.87  1.0
  Ga  Ga3  1  0.0  0.17  0.3  1.0

La V V Ga
LaV2Ga crystallizes in the triclinic P1 space group. La(1) is bonded in a distorted single-bond geometry to one V(1), two equivalent V(2), and one Ga(1) atom. The La(1)-V(1) bond length is 2.43 Å. There is one shorter (3.39 Å) and one longer (3.76 Å) La(1)-V(2) bond length. The La(1)-Ga(1) bond length is 1.53 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 2-coordinate geometry to one La(1), one V(2), and one Ga(1) atom. The V(1)-V(2) bond length is 2.15 Å. The V(1)-Ga(1) bond length is 1.36 Å. In the second V site, V(2) is bonded in a 5-coordinate geometry to two equivalent La(1), one V(1), and two equivalent V(2) atoms. Both V(2)-V(2) bond lengths are 3.11 Å. Ga(1) is bonded in a linear geometry to one La(1) and one V(1) atom.