data_ZrTePd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.22
_cell_length_b   5.22
_cell_length_c   5.22
_cell_angle_alpha   132.56
_cell_angle_beta   132.56
_cell_angle_gamma   69.35
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrTePd2
_chemical_formula_sum   'Zr1 Te1 Pd2'
_cell_volume   75.74
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr3  1  0.0  0.0  0.0  1.0
  Te  Te2  1  0.0  0.0  0.29  1.0
  Pd  Pd0  1  0.1  0.0  0.15  1.0
  Pd  Pd1  1  0.0  0.1  0.15  1.0

data_ZrTePd2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.94
_cell_length_b   5.94
_cell_length_c   5.22
_cell_angle_alpha   90.0
_cell_angle_beta   124.67
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZrTePd2
_chemical_formula_sum   'Zr2 Te2 Pd4'
_cell_volume   151.48
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  2  0.0  0.0  0.0  1.0
  Te  Te1  2  0.21  0.5  0.71  1.0
  Pd  Pd2  4  0.4  0.45  0.95  1.0

Zr Te Pd Pd
ZrPd2Te is alpha Niobium phosphide-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ZrPd2Te clusters. Zr(1) is bonded in a 2-coordinate geometry to two equivalent Pd(1) atoms. Both Zr(1)-Pd(1) bond lengths are 0.56 Å. Pd(1) is bonded in a distorted single-bond geometry to one Zr(1) and one Te(1) atom. The Pd(1)-Te(1) bond length is 1.18 Å. Te(1) is bonded in a 2-coordinate geometry to two equivalent Pd(1) atoms.