data_KCr2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.3
_cell_length_b   10.3
_cell_length_c   10.3
_cell_angle_alpha   17.47
_cell_angle_beta   17.47
_cell_angle_gamma   17.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KCr2Pd
_chemical_formula_sum   'K1 Cr2 Pd1'
_cell_volume   86.01
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K2  1  0.0  0.0  0.0  1.0
  Cr  Cr0  1  0.0  0.0  0.06  1.0
  Cr  Cr1  1  0.0  0.0  0.37  1.0
  Pd  Pd3  1  0.0  0.0  0.22  1.0

data_KCr2Pd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.42
_cell_length_b   3.13
_cell_length_c   10.3
_cell_angle_alpha   90.0
_cell_angle_beta   100.1
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   KCr2Pd
_chemical_formula_sum   'K2 Cr4 Pd2'
_cell_volume   172.02
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  2  0.0  0.0  0.0  1.0
  Cr  Cr1  2  -0.0  0.0  0.63  1.0
  Cr  Cr2  2  -0.0  0.0  0.94  1.0
  Pd  Pd3  2  -0.0  0.0  0.78  1.0

K Cr Cr Pd
KCr2Pd is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two KCr2Pd clusters. K(1) is bonded in a single-bond geometry to one Cr(1) atom. The K(1)-Cr(1) bond length is 0.61 Å. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a distorted single-bond geometry to one K(1) and one Pd(1) atom. The Cr(1)-Pd(1) bond length is 1.61 Å. In the second Cr site, Cr(2) is bonded in a single-bond geometry to one Pd(1) atom. The Cr(2)-Pd(1) bond length is 1.61 Å. Pd(1) is bonded in a linear geometry to one Cr(1) and one Cr(2) atom.