data_Li2ReW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.94
_cell_length_b   9.94
_cell_length_c   9.94
_cell_angle_alpha   15.5
_cell_angle_beta   15.5
_cell_angle_gamma   15.5
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2ReW
_chemical_formula_sum   'Li2 Re1 W1'
_cell_volume   61.19
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.18  1.0
  Li  Li1  1  0.0  0.0  0.29  1.0
  Re  Re2  1  0.0  0.0  0.73  1.0
  W  W3  1  0.0  0.0  0.0  1.0

data_Li2ReW
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.65
_cell_length_b   2.68
_cell_length_c   9.94
_cell_angle_alpha   90.0
_cell_angle_beta   98.96
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Li2ReW
_chemical_formula_sum   'Li4 Re2 W2'
_cell_volume   122.38
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.71  1.0
  Li  Li1  2  0.0  0.0  0.82  1.0
  Re  Re2  2  0.0  0.0  0.27  1.0
  W  W3  2  0.0  0.0  0.0  1.0

Li Li Re W
Li2WRe crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Li2WRe clusters. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a linear geometry to one Li(2) and one W(1) atom. The Li(1)-Li(2) bond length is 1.08 Å. The Li(1)-W(1) bond length is 1.78 Å. In the second Li site, Li(2) is bonded in a single-bond geometry to one Li(1) atom. W(1) is bonded in a single-bond geometry to one Li(1) and one Re(1) atom. The W(1)-Re(1) bond length is 2.65 Å. Re(1) is bonded in a distorted single-bond geometry to one W(1) atom.