data_S3N3ClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.08
_cell_length_b   9.08
_cell_length_c   11.8
_cell_angle_alpha   112.03
_cell_angle_beta   112.03
_cell_angle_gamma   42.93
_symmetry_Int_Tables_number   1
_chemical_formula_structural   S3N3ClO2
_chemical_formula_sum   'S12 N12 Cl4 O8'
_cell_volume   606.41
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S24  1  0.06  0.04  0.19  1.0
  S  S25  1  0.84  0.5  0.91  1.0
  S  S26  1  0.1  0.05  0.53  1.0
  S  S27  1  0.66  0.05  0.67  1.0
  S  S28  1  0.92  0.5  0.29  1.0
  S  S29  1  0.71  0.04  0.01  1.0
  S  S30  1  0.44  0.96  0.79  1.0
  S  S31  1  0.22  0.5  0.51  1.0
  S  S32  1  0.48  0.95  0.13  1.0
  S  S33  1  0.04  0.95  0.27  1.0
  S  S34  1  0.3  0.5  0.89  1.0
  S  S35  1  0.08  0.96  0.61  1.0
  N  N4  1  0.91  0.16  0.99  1.0
  N  N5  1  0.47  0.87  0.33  1.0
  N  N6  1  0.02  0.17  0.78  1.0
  N  N7  1  0.74  0.17  0.42  1.0
  N  N8  1  0.29  0.87  0.87  1.0
  N  N9  1  0.85  0.16  0.21  1.0
  N  N10  1  0.29  0.84  0.59  1.0
  N  N11  1  0.85  0.13  0.93  1.0
  N  N12  1  0.4  0.83  0.38  1.0
  N  N13  1  0.12  0.83  0.02  1.0
  N  N14  1  0.67  0.13  0.47  1.0
  N  N15  1  0.23  0.84  0.81  1.0
  Cl  Cl0  1  0.42  0.14  0.49  1.0
  Cl  Cl1  1  0.35  0.14  0.71  1.0
  Cl  Cl2  1  0.8  0.86  0.09  1.0
  Cl  Cl3  1  0.72  0.86  0.31  1.0
  O  O16  1  0.32  0.59  0.43  1.0
  O  O17  1  0.58  0.22  0.37  1.0
  O  O18  1  0.19  0.22  0.84  1.0
  O  O19  1  0.45  0.59  0.77  1.0
  O  O20  1  0.69  0.41  0.03  1.0
  O  O21  1  0.96  0.78  0.97  1.0
  O  O22  1  0.56  0.78  0.44  1.0
  O  O23  1  0.83  0.41  0.37  1.0

data_S3N3ClO2
_symmetry_space_group_name_H-M   P-1
_cell_length_a   6.65
_cell_length_b   9.08
_cell_length_c   11.8
_cell_angle_alpha   112.03
_cell_angle_beta   90.0
_cell_angle_gamma   111.47
_symmetry_Int_Tables_number   2
_chemical_formula_structural   S3N3ClO2
_chemical_formula_sum   'S12 N12 Cl4 O8'
_cell_volume   606.41
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  2  0.04  0.18  0.11  1.0
  S  S1  2  0.04  0.53  0.29  1.0
  S  S2  2  0.05  0.14  0.77  1.0
  S  S3  2  0.05  0.58  0.63  1.0
  S  S4  2  0.5  0.77  0.01  1.0
  S  S5  2  0.5  0.84  0.39  1.0
  N  N6  2  0.13  0.22  0.57  1.0
  N  N7  2  0.13  0.41  0.03  1.0
  N  N8  2  0.16  0.44  0.31  1.0
  N  N9  2  0.16  0.51  0.09  1.0
  N  N10  2  0.17  0.34  0.52  1.0
  N  N11  2  0.17  0.62  0.88  1.0
  Cl  Cl12  2  0.14  0.92  0.81  1.0
  Cl  Cl13  2  0.14  0.99  0.59  1.0
  O  O14  2  0.22  0.23  0.47  1.0
  O  O15  2  0.22  0.83  0.94  1.0
  O  O16  2  0.41  0.53  0.13  1.0
  O  O17  2  0.41  0.67  0.47  1.0

S S S S S S S S S S S S N N N N N N N N N N N N Cl Cl Cl Cl O O O O O O O O
N2ON4S6O3Cl2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrazino alcohol molecules and one N4S6O3Cl2 cluster. In the N4S6O3Cl2 cluster, there are four inequivalent N sites. In the first N site, N(2) is bonded in a distorted single-bond geometry to one O(2) and two equivalent Cl(1) atoms. The N(2)-O(2) bond length is 1.39 Å. There is one shorter (2.24 Å) and one longer (2.26 Å) N(2)-Cl(1) bond length. In the second N site, N(3) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one O(3) atom. The N(3)-S(1) bond length is 2.15 Å. The N(3)-S(2) bond length is 2.28 Å. The N(3)-O(3) bond length is 1.72 Å. In the third N site, N(4) is bonded in a distorted single-bond geometry to one O(2) atom. The N(4)-O(2) bond length is 1.17 Å. In the fourth N site, N(6) is bonded in a 2-coordinate geometry to one S(1) and one S(3) atom. The N(6)-S(1) bond length is 1.37 Å. The N(6)-S(3) bond length is 1.58 Å. There are six inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(3) and one N(6) atom. In the second S site, S(2) is bonded in a 2-coordinate geometry to one N(3) and one O(3) atom. The S(2)-O(3) bond length is 2.40 Å. In the third S site, S(3) is bonded in a distorted single-bond geometry to one N(6) atom. In the fourth S site, S(4) is bonded in a distorted L-shaped geometry to one Cl(1) and one Cl(2) atom. The S(4)-Cl(1) bond length is 2.31 Å. The S(4)-Cl(2) bond length is 2.55 Å. In the fifth S site, S(5) is bonded in a bent 120 degrees geometry to one O(1) and one Cl(1) atom. The S(5)-O(1) bond length is 2.07 Å. The S(5)-Cl(1) bond length is 2.28 Å. In the sixth S site, S(6) is bonded in a 2-coordinate geometry to one O(3) and one Cl(2) atom. The S(6)-O(3) bond length is 1.77 Å. The S(6)-Cl(2) bond length is 1.70 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(5) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one N(2), one N(4), and one Cl(1) atom. The O(2)-Cl(1) bond length is 2.36 Å. In the third O site, O(3) is bonded in a 2-coordinate geometry to one N(3), one S(2), one S(6), and one Cl(2) atom. The O(3)-Cl(2) bond length is 1.99 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 5-coordinate geometry to two equivalent N(2), one S(4), one S(5), and one O(2) atom. In the second Cl site, Cl(2) is bonded in a 3-coordinate geometry to one S(4), one S(6), and one O(3) atom.