data_AgSn2Os
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.68
_cell_length_b   4.68
_cell_length_c   5.61
_cell_angle_alpha   100.17
_cell_angle_beta   100.17
_cell_angle_gamma   41.39
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgSn2Os
_chemical_formula_sum   'Ag1 Sn2 Os1'
_cell_volume   79.79
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.0  0.0  0.0  1.0
  Sn  Sn2  1  0.32  0.0  0.98  1.0
  Sn  Sn3  1  0.38  0.0  0.53  1.0
  Os  Os1  1  0.85  0.0  0.75  1.0

data_AgSn2Os
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.31
_cell_length_b   4.68
_cell_length_c   5.61
_cell_angle_alpha   100.17
_cell_angle_beta   90.0
_cell_angle_gamma   110.69
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgSn2Os
_chemical_formula_sum   'Ag1 Sn2 Os1'
_cell_volume   79.79
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.0  0.0  0.0  1.0
  Sn  Sn1  1  0.0  0.62  0.47  1.0
  Sn  Sn2  1  0.0  0.68  0.02  1.0
  Os  Os3  1  0.0  0.15  0.25  1.0

Ag Sn Sn Os
OsAgSn2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one OsAgSn2 cluster. Os(1) is bonded in a distorted single-bond geometry to one Ag(1) and one Sn(2) atom. The Os(1)-Ag(1) bond length is 1.43 Å. The Os(1)-Sn(2) bond length is 2.36 Å. Ag(1) is bonded in a water-like geometry to one Os(1) and one Sn(1) atom. The Ag(1)-Sn(1) bond length is 1.53 Å. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a single-bond geometry to one Ag(1) atom. In the second Sn site, Sn(2) is bonded in a 1-coordinate geometry to one Os(1) atom.