data_LiInW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.04
_cell_length_b   10.04
_cell_length_c   10.04
_cell_angle_alpha   16.4
_cell_angle_beta   16.4
_cell_angle_gamma   16.4
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiInW2
_chemical_formula_sum   'Li1 In1 W2'
_cell_volume   70.37
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.0  0.0  0.0  1.0
  In  In0  1  0.0  0.0  0.86  1.0
  W  W2  1  0.0  0.0  0.29  1.0
  W  W3  1  0.0  0.0  0.42  1.0

data_LiInW2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.96
_cell_length_b   2.86
_cell_length_c   10.04
_cell_angle_alpha   90.0
_cell_angle_beta   99.48
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LiInW2
_chemical_formula_sum   'Li2 In2 W4'
_cell_volume   140.75
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.0  1.0
  In  In1  2  0.0  0.0  0.14  1.0
  W  W2  2  0.0  0.0  0.71  1.0
  W  W3  2  0.0  0.0  0.58  1.0

Li In W W
LiW2In crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two LiW2In clusters. Li(1) is bonded in a single-bond geometry to one W(1) and one In(1) atom. The Li(1)-W(1) bond length is 2.94 Å. The Li(1)-In(1) bond length is 1.42 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted linear geometry to one Li(1) and one W(2) atom. The W(1)-W(2) bond length is 1.32 Å. In the second W site, W(2) is bonded in a single-bond geometry to one W(1) atom. In(1) is bonded in a single-bond geometry to one Li(1) atom.