data_NaLiSnRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.63
_cell_length_b   4.63
_cell_length_c   4.63
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaLiSnRh
_chemical_formula_sum   'Na1 Li1 Sn1 Rh1'
_cell_volume   70.07
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na1  1  0.64  0.64  0.64  1.0
  Li  Li0  1  0.0  0.0  0.0  1.0
  Sn  Sn3  1  0.91  0.91  0.91  1.0
  Rh  Rh2  1  0.27  0.27  0.27  1.0

data_NaLiSnRh
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.63
_cell_length_b   4.63
_cell_length_c   11.34
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   NaLiSnRh
_chemical_formula_sum   'Na3 Li3 Sn3 Rh3'
_cell_volume   210.22
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  3  0.0  0.0  0.36  1.0
  Li  Li1  3  0.0  0.0  0.0  1.0
  Sn  Sn2  3  0.0  0.0  0.09  1.0
  Rh  Rh3  3  0.0  0.0  0.73  1.0

Na Li Sn Rh
NaLiRhSn crystallizes in the trigonal R3m space group. Na(1) is bonded in a 10-coordinate geometry to three equivalent Li(1), three equivalent Rh(1), and four equivalent Sn(1) atoms. All Na(1)-Li(1) bond lengths are 2.69 Å. All Na(1)-Rh(1) bond lengths are 2.69 Å. There are three shorter (2.76 Å) and one longer (3.09 Å) Na(1)-Sn(1) bond length. Li(1) is bonded in a single-bond geometry to three equivalent Na(1), four equivalent Rh(1), and one Sn(1) atom. There are three shorter (2.76 Å) and one longer (3.09 Å) Li(1)-Rh(1) bond length. The Li(1)-Sn(1) bond length is 1.04 Å. Rh(1) is bonded in a 10-coordinate geometry to three equivalent Na(1), four equivalent Li(1), and three equivalent Sn(1) atoms. All Rh(1)-Sn(1) bond lengths are 2.69 Å. Sn(1) is bonded in a single-bond geometry to four equivalent Na(1), one Li(1), and three equivalent Rh(1) atoms.