data_Mn2VW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.62
_cell_length_b   4.12
_cell_length_c   4.84
_cell_angle_alpha   90.0
_cell_angle_beta   100.91
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mn2VW
_chemical_formula_sum   'Mn2 V1 W1'
_cell_volume   51.31
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.13  0.0  0.75  1.0
  Mn  Mn1  1  0.69  0.06  0.25  1.0
  V  V2  1  0.87  0.0  0.26  1.0
  W  W3  1  0.95  0.06  0.62  1.0

data_Mn2VW
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.62
_cell_length_b   4.12
_cell_length_c   4.84
_cell_angle_alpha   90.0
_cell_angle_beta   100.91
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mn2VW
_chemical_formula_sum   'Mn2 V1 W1'
_cell_volume   51.31
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.13  0.0  0.75  1.0
  Mn  Mn1  1  0.69  0.06  0.25  1.0
  V  V2  1  0.87  0.0  0.26  1.0
  W  W3  1  0.95  0.06  0.62  1.0

Mn Mn V W
VMnW(Mn) crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VMn cluster and one W(Mn) cluster. In the VMn cluster, V(1) is bonded in a 1-coordinate geometry to one Mn(2) atom. The V(1)-Mn(2) bond length is 0.55 Å. Mn(2) is bonded in a distorted single-bond geometry to one V(1) atom. In the W(Mn) cluster, W(1) is bonded in a distorted single-bond geometry to one Mn(1) atom. The W(1)-Mn(1) bond length is 0.75 Å. Mn(1) is bonded in a single-bond geometry to one W(1) atom.