data_TlBi2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.51
_cell_length_b   10.51
_cell_length_c   10.51
_cell_angle_alpha   19.25
_cell_angle_beta   19.25
_cell_angle_gamma   19.25
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlBi2Pd
_chemical_formula_sum   'Tl1 Bi2 Pd1'
_cell_volume   110.31
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl3  1  0.0  0.0  0.47  1.0
  Bi  Bi0  1  0.0  0.0  0.28  1.0
  Bi  Bi1  1  0.0  0.0  0.66  1.0
  Pd  Pd2  1  0.0  0.0  0.0  1.0

data_TlBi2Pd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.09
_cell_length_b   3.51
_cell_length_c   10.51
_cell_angle_alpha   90.0
_cell_angle_beta   101.13
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TlBi2Pd
_chemical_formula_sum   'Tl2 Bi4 Pd2'
_cell_volume   220.62
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  2  0.0  0.0  0.53  1.0
  Bi  Bi1  2  0.0  0.0  0.34  1.0
  Bi  Bi2  2  0.0  0.0  0.72  1.0
  Pd  Pd3  2  0.0  0.0  0.0  1.0

Tl Bi Bi Pd
PdTlBi2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two PdTlBi2 clusters. Pd(1) is bonded in a distorted single-bond geometry to one Bi(1) atom. The Pd(1)-Bi(1) bond length is 2.93 Å. Tl(1) is bonded in a linear geometry to one Bi(1) and one Bi(2) atom. The Tl(1)-Bi(1) bond length is 2.01 Å. The Tl(1)-Bi(2) bond length is 2.01 Å. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a distorted single-bond geometry to one Pd(1) and one Tl(1) atom. In the second Bi site, Bi(2) is bonded in a single-bond geometry to one Tl(1) atom.