data_InTcBr2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.47
_cell_length_b   3.47
_cell_length_c   8.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InTcBr2
_chemical_formula_sum   'In1 Tc1 Br2'
_cell_volume   96.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In2  1  0.73  0.73  0.29  1.0
  Tc  Tc3  1  0.0  0.0  0.89  1.0
  Br  Br0  1  0.73  0.73  0.45  1.0
  Br  Br1  1  0.0  0.0  0.5  1.0

data_InTcBr2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.9
_cell_length_b   4.9
_cell_length_c   8.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   InTcBr2
_chemical_formula_sum   'In2 Tc2 Br4'
_cell_volume   193.39
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  0.23  0.5  0.29  1.0
  Tc  Tc1  2  0.0  0.0  0.89  1.0
  Br  Br2  2  0.0  0.0  0.5  1.0
  Br  Br3  2  0.23  0.5  0.45  1.0

In Tc Br Br
TcInBr2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two TcInBr2 clusters. Tc(1) is bonded in a distorted single-bond geometry to one Br(2) atom. The Tc(1)-Br(2) bond length is 3.14 Å. In(1) is bonded in a single-bond geometry to one Br(1) atom. The In(1)-Br(1) bond length is 1.30 Å. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one In(1) and one Br(2) atom. The Br(1)-Br(2) bond length is 1.36 Å. In the second Br site, Br(2) is bonded in a 2-coordinate geometry to one Tc(1) and one Br(1) atom.