data_ZnGa2Mo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.38
_cell_length_b   3.38
_cell_length_c   5.45
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnGa2Mo
_chemical_formula_sum   'Zn1 Ga2 Mo1'
_cell_volume   62.44
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.0  0.0  1.0
  Ga  Ga0  1  0.69  0.69  0.41  1.0
  Ga  Ga1  1  0.69  0.69  0.04  1.0
  Mo  Mo2  1  0.0  0.0  0.73  1.0

data_ZnGa2Mo
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.79
_cell_length_b   4.79
_cell_length_c   5.45
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZnGa2Mo
_chemical_formula_sum   'Zn2 Ga4 Mo2'
_cell_volume   124.87
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  2  0.0  0.0  0.0  1.0
  Ga  Ga1  2  0.19  0.5  0.04  1.0
  Ga  Ga2  2  0.19  0.5  0.41  1.0
  Mo  Mo3  2  0.0  0.0  0.73  1.0

Zn Ga Ga Mo
MoZnGa2 is Indium-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two MoZnGa2 clusters. Mo(1) is bonded in a distorted single-bond geometry to one Zn(1) and one Ga(1) atom. The Mo(1)-Zn(1) bond length is 1.50 Å. The Mo(1)-Ga(1) bond length is 2.25 Å. Zn(1) is bonded in a distorted water-like geometry to one Mo(1) and one Ga(2) atom. The Zn(1)-Ga(2) bond length is 1.49 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 1-coordinate geometry to one Mo(1) atom. In the second Ga site, Ga(2) is bonded in a distorted single-bond geometry to one Zn(1) atom.