data_CdPt2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.71
_cell_length_b   4.71
_cell_length_c   4.71
_cell_angle_alpha   121.48
_cell_angle_beta   121.48
_cell_angle_gamma   87.45
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdPt2Cl
_chemical_formula_sum   'Cd1 Pt2 Cl1'
_cell_volume   71.96
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.3  0.7  1.0
  Pt  Pt2  1  0.3  0.0  0.7  1.0
  Pt  Pt3  1  0.0  0.0  0.4  1.0
  Cl  Cl1  1  0.0  0.0  0.0  1.0

data_CdPt2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.6
_cell_length_b   4.6
_cell_length_c   4.71
_cell_angle_alpha   119.26
_cell_angle_beta   119.26
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdPt2Cl
_chemical_formula_sum   'Cd1 Pt2 Cl1'
_cell_volume   71.96
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.6  0.3  0.6  1.0
  Pt  Pt1  1  0.3  0.0  0.6  1.0
  Pt  Pt2  1  0.6  0.0  0.6  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Cd Pt Pt Cl
Pt2CdCl crystallizes in the triclinic P1 space group. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 4-coordinate geometry to one Pt(2), one Cd(1), and two equivalent Cl(1) atoms. The Pt(1)-Pt(2) bond length is 1.38 Å. The Pt(1)-Cd(1) bond length is 1.95 Å. There is one shorter (2.46 Å) and one longer (2.83 Å) Pt(1)-Cl(1) bond length. In the second Pt site, Pt(2) is bonded in a 3-coordinate geometry to one Pt(1), one Cd(1), and one Cl(1) atom. The Pt(2)-Cd(1) bond length is 1.38 Å. The Pt(2)-Cl(1) bond length is 1.89 Å. Cd(1) is bonded in a distorted single-bond geometry to one Pt(1), one Pt(2), and two equivalent Cl(1) atoms. There is one shorter (2.46 Å) and one longer (2.83 Å) Cd(1)-Cl(1) bond length. Cl(1) is bonded in a 5-coordinate geometry to one Pt(2), two equivalent Pt(1), and two equivalent Cd(1) atoms.