data_Cr3TeRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.02
_cell_length_b   5.02
_cell_length_c   5.02
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cr3TeRh
_chemical_formula_sum   'Cr3 Te1 Rh1'
_cell_volume   126.25
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.51  0.0  0.51  1.0
  Cr  Cr1  1  0.51  0.51  0.0  1.0
  Cr  Cr2  1  0.0  0.51  0.51  1.0
  Te  Te3  1  0.51  0.51  0.51  1.0
  Rh  Rh4  1  0.0  0.0  0.0  1.0

data_Cr3TeRh
_symmetry_space_group_name_H-M   R3m
_cell_length_a   7.09
_cell_length_b   7.09
_cell_length_c   8.69
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   Cr3TeRh
_chemical_formula_sum   'Cr9 Te3 Rh3'
_cell_volume   378.74
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  9  0.17  0.34  0.34  1.0
  Te  Te1  3  0.0  0.0  0.51  1.0
  Rh  Rh2  3  0.0  0.0  0.0  1.0

Cr Cr Cr Te Rh
Cr3RhTe is (Cubic) Perovskite structured and crystallizes in the trigonal R3m space group. Cr(1) is bonded in a linear geometry to four equivalent Rh(1) and two equivalent Te(1) atoms. There are a spread of Cr(1)-Rh(1) bond distances ranging from 3.49-3.61 Å. There is one shorter (2.47 Å) and one longer (2.55 Å) Cr(1)-Te(1) bond length. Rh(1) is bonded in a 12-coordinate geometry to twelve equivalent Cr(1) atoms. Te(1) is bonded to six equivalent Cr(1) atoms to form corner-sharing TeCr6 octahedra. The corner-sharing octahedra are not tilted.