data_Sc2TcP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.88
_cell_length_b   5.88
_cell_length_c   5.88
_cell_angle_alpha   147.39
_cell_angle_beta   138.35
_cell_angle_gamma   53.87
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sc2TcP
_chemical_formula_sum   'Sc2 Tc1 P1'
_cell_volume   72.18
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc1  1  0.65  0.0  0.05  1.0
  Sc  Sc2  1  0.0  0.0  0.81  1.0
  Tc  Tc3  1  0.0  0.09  0.31  1.0
  P  P0  1  0.0  0.0  0.3  1.0

data_Sc2TcP
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.3
_cell_length_b   4.18
_cell_length_c   5.88
_cell_angle_alpha   110.82
_cell_angle_beta   106.3
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sc2TcP
_chemical_formula_sum   'Sc2 Tc1 P1'
_cell_volume   72.18
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.19  0.19  0.19  1.0
  Sc  Sc1  1  0.6  0.95  0.6  1.0
  Tc  Tc2  1  0.69  0.78  0.78  1.0
  P  P3  1  0.7  0.7  0.7  1.0

Sc Sc Tc P
Sc2TcP crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Sc2TcP cluster. There are two inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in a 1-coordinate geometry to one P(1) atom. The Sc(1)-P(1) bond length is 1.37 Å. In the second Sc site, Sc(2) is bonded in a 1-coordinate geometry to one Tc(1) atom. The Sc(2)-Tc(1) bond length is 2.52 Å. Tc(1) is bonded in a single-bond geometry to one Sc(2) and one P(1) atom. The Tc(1)-P(1) bond length is 0.47 Å. P(1) is bonded in a distorted single-bond geometry to one Sc(1) and one Tc(1) atom.