data_LaTlV2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.04
_cell_length_b   3.04
_cell_length_c   9.39
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   111.1
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaTlV2
_chemical_formula_sum   'La1 Tl1 V2'
_cell_volume   81.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.0  0.0  1.0
  Tl  Tl1  1  0.0  0.0  0.69  1.0
  V  V2  1  0.72  0.0  0.96  1.0
  V  V3  1  0.72  0.0  0.43  1.0

data_LaTlV2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.04
_cell_length_b   3.04
_cell_length_c   9.39
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   111.1
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaTlV2
_chemical_formula_sum   'La1 Tl1 V2'
_cell_volume   81.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.0  0.0  1.0
  Tl  Tl1  1  0.0  0.0  0.69  1.0
  V  V2  1  0.72  0.0  0.43  1.0
  V  V3  1  0.72  0.0  0.96  1.0

La Tl V V
LaV2Tl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LaV2Tl cluster. La(1) is bonded in a distorted single-bond geometry to one V(1) atom. The La(1)-V(1) bond length is 0.94 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted single-bond geometry to one La(1) and one Tl(1) atom. The V(1)-Tl(1) bond length is 2.59 Å. In the second V site, V(2) is bonded in a 1-coordinate geometry to one Tl(1) atom. The V(2)-Tl(1) bond length is 2.59 Å. Tl(1) is bonded in a 2-coordinate geometry to one V(1) and one V(2) atom.