data_CdTe5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.12
_cell_length_b   7.12
_cell_length_c   4.22
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdTe5
_chemical_formula_sum   'Cd1 Te5'
_cell_volume   185.28
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.0  0.0  1.0
  Te  Te1  1  0.79  0.0  0.11  1.0
  Te  Te2  1  0.17  0.02  0.11  1.0
  Te  Te3  1  0.61  0.15  0.11  1.0
  Te  Te4  1  0.56  0.06  0.0  1.0
  Te  Te5  1  0.0  0.11  0.0  1.0

data_CdTe5
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.22
_cell_length_b   7.12
_cell_length_c   7.12
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdTe5
_chemical_formula_sum   'Cd1 Te5'
_cell_volume   185.28
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.0  0.0  1.0
  Te  Te1  1  -0.0  0.0  0.11  1.0
  Te  Te2  1  -0.0  0.56  0.06  1.0
  Te  Te3  1  0.11  0.17  0.02  1.0
  Te  Te4  1  0.11  0.61  0.15  1.0
  Te  Te5  1  0.11  0.79  0.0  1.0

Cd Te Te Te Te Te
CdTe5 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one CdTe5 cluster. Cd(1) is bonded in a distorted single-bond geometry to one Te(1), one Te(2), and one Te(5) atom. The Cd(1)-Te(1) bond length is 1.57 Å. The Cd(1)-Te(2) bond length is 1.21 Å. The Cd(1)-Te(5) bond length is 0.80 Å. There are five inequivalent Te sites. In the first Te site, Te(1) is bonded in a 4-coordinate geometry to one Cd(1), one Te(3), one Te(4), and one Te(5) atom. The Te(1)-Te(3) bond length is 2.04 Å. The Te(1)-Te(4) bond length is 1.91 Å. The Te(1)-Te(5) bond length is 1.38 Å. In the second Te site, Te(2) is bonded in a single-bond geometry to one Cd(1) atom. In the third Te site, Te(3) is bonded in a single-bond geometry to one Te(1) and one Te(4) atom. The Te(3)-Te(4) bond length is 0.72 Å. In the fourth Te site, Te(4) is bonded in a single-bond geometry to one Te(1) and one Te(3) atom. In the fifth Te site, Te(5) is bonded in a single-bond geometry to one Cd(1) and one Te(1) atom.