data_InCoP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.53
_cell_length_b   6.53
_cell_length_c   6.53
_cell_angle_alpha   31.58
_cell_angle_beta   31.58
_cell_angle_gamma   31.58
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InCoP2
_chemical_formula_sum   'In1 Co1 P2'
_cell_volume   67.85
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In1  1  0.0  0.0  0.3  1.0
  Co  Co0  1  0.0  0.0  0.0  1.0
  P  P2  1  0.0  0.0  0.36  1.0
  P  P3  1  0.0  0.0  0.25  1.0

data_InCoP2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.16
_cell_length_b   3.55
_cell_length_c   6.53
_cell_angle_alpha   90.0
_cell_angle_beta   108.31
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   InCoP2
_chemical_formula_sum   'In2 Co2 P4'
_cell_volume   135.71
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  0.0  0.0  0.7  1.0
  Co  Co1  2  0.0  0.0  0.0  1.0
  P  P2  2  0.0  0.0  0.64  1.0
  P  P3  2  0.0  0.0  0.75  1.0

In Co P P
CoInP2 is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two CoInP2 clusters. Co(1) is bonded in a single-bond geometry to one P(2) atom. The Co(1)-P(2) bond length is 1.62 Å. In(1) is bonded in a linear geometry to one P(1) and one P(2) atom. The In(1)-P(1) bond length is 0.35 Å. The In(1)-P(2) bond length is 0.35 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a single-bond geometry to one In(1) atom. In the second P site, P(2) is bonded in a distorted linear geometry to one Co(1) and one In(1) atom.