data_InTcP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.91
_cell_length_b   5.91
_cell_length_c   5.91
_cell_angle_alpha   151.61
_cell_angle_beta   130.83
_cell_angle_gamma   57.76
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InTcP2
_chemical_formula_sum   'In1 Tc1 P2'
_cell_volume   73.77
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.0  0.0  0.17  1.0
  Tc  Tc3  1  0.0  0.0  0.0  1.0
  P  P1  1  0.45  0.0  0.98  1.0
  P  P2  1  0.0  0.46  0.19  1.0

data_InTcP2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.9
_cell_length_b   4.92
_cell_length_c   5.91
_cell_angle_alpha   114.59
_cell_angle_beta   104.2
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InTcP2
_chemical_formula_sum   'In1 Tc1 P2'
_cell_volume   73.77
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.0  0.17  0.17  1.0
  Tc  Tc1  1  0.0  0.0  0.0  1.0
  P  P2  1  0.0  0.98  0.53  1.0
  P  P3  1  0.54  0.74  0.74  1.0

In Tc P P
TcInP2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one TcInP2 cluster. Tc(1) is bonded in a 2-coordinate geometry to one In(1) and one P(2) atom. The Tc(1)-In(1) bond length is 1.03 Å. The Tc(1)-P(2) bond length is 1.79 Å. In(1) is bonded in a distorted single-bond geometry to one Tc(1) and one P(1) atom. The In(1)-P(1) bond length is 2.65 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 1-coordinate geometry to one In(1) atom. In the second P site, P(2) is bonded in a distorted single-bond geometry to one Tc(1) atom.