data_GaBRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.08
_cell_length_b   5.08
_cell_length_c   5.08
_cell_angle_alpha   141.1
_cell_angle_beta   141.1
_cell_angle_gamma   56.19
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaBRh2
_chemical_formula_sum   'Ga1 B1 Rh2'
_cell_volume   51.3
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga1  1  0.69  0.0  0.24  1.0
  B  B0  1  0.0  0.0  0.0  1.0
  Rh  Rh2  1  0.0  0.0  0.48  1.0
  Rh  Rh3  1  0.0  0.69  0.24  1.0

data_GaBRh2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.38
_cell_length_b   3.38
_cell_length_c   5.08
_cell_angle_alpha   109.45
_cell_angle_beta   109.45
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaBRh2
_chemical_formula_sum   'Ga1 B1 Rh2'
_cell_volume   51.3
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.24  0.55  0.55  1.0
  B  B1  1  0.0  0.0  0.0  1.0
  Rh  Rh2  1  0.48  0.48  0.48  1.0
  Rh  Rh3  1  0.55  0.24  0.55  1.0

Ga B Rh Rh
Rh2GaB crystallizes in the triclinic P1 space group. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted single-bond geometry to one Rh(2), one Ga(1), and two equivalent B(1) atoms. The Rh(1)-Rh(2) bond length is 0.98 Å. The Rh(1)-Ga(1) bond length is 0.98 Å. There is one shorter (2.45 Å) and one longer (2.63 Å) Rh(1)-B(1) bond length. In the second Rh site, Rh(2) is bonded in a distorted single-bond geometry to one Rh(1) and three equivalent B(1) atoms. There are a spread of Rh(2)-B(1) bond distances ranging from 2.63-2.82 Å. Ga(1) is bonded in a single-bond geometry to one Rh(1) and three equivalent B(1) atoms. There are a spread of Ga(1)-B(1) bond distances ranging from 2.63-2.82 Å. B(1) is bonded in a 8-coordinate geometry to two equivalent Rh(1), three equivalent Rh(2), and three equivalent Ga(1) atoms.