data_Mn2MoW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.99
_cell_length_b   4.99
_cell_length_c   4.99
_cell_angle_alpha   144.58
_cell_angle_beta   130.19
_cell_angle_gamma   62.59
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mn2MoW
_chemical_formula_sum   'Mn2 Mo1 W1'
_cell_volume   54.34
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.0  0.0  0.45  1.0
  Mn  Mn1  1  0.52  0.0  0.19  1.0
  Mo  Mo2  1  0.0  0.0  0.27  1.0
  W  W3  1  0.0  0.1  0.14  1.0

data_Mn2MoW
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.03
_cell_length_b   4.2
_cell_length_c   4.99
_cell_angle_alpha   114.9
_cell_angle_beta   107.71
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mn2MoW
_chemical_formula_sum   'Mn2 Mo1 W1'
_cell_volume   54.34
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.33  0.81  0.33  1.0
  Mn  Mn1  1  0.55  0.55  0.55  1.0
  Mo  Mo2  1  0.73  0.73  0.73  1.0
  W  W3  1  0.86  0.96  0.96  1.0

Mn Mn Mo W
WMoMn2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one WMoMn2 cluster. W(1) is bonded in a 2-coordinate geometry to one Mo(1) and one Mn(2) atom. The W(1)-Mo(1) bond length is 1.09 Å. The W(1)-Mn(2) bond length is 2.27 Å. Mo(1) is bonded in a distorted linear geometry to one W(1) and one Mn(1) atom. The Mo(1)-Mn(1) bond length is 0.92 Å. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second Mn site, Mn(2) is bonded in a 1-coordinate geometry to one W(1) atom.