data_Li2VGa
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.09
_cell_length_b   5.09
_cell_length_c   4.59
_cell_angle_alpha   102.15
_cell_angle_beta   102.15
_cell_angle_gamma   31.88
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2VGa
_chemical_formula_sum   'Li2 V1 Ga1'
_cell_volume   61.35
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.22  0.0  0.14  1.0
  Li  Li2  1  0.56  0.0  0.34  1.0
  V  V3  1  0.0  0.0  0.0  1.0
  Ga  Ga0  1  0.39  0.0  0.24  1.0

data_Li2VGa
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.8
_cell_length_b   4.59
_cell_length_c   5.09
_cell_angle_alpha   102.15
_cell_angle_beta   105.94
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2VGa
_chemical_formula_sum   'Li2 V1 Ga1'
_cell_volume   61.35
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.14  0.22  1.0
  Li  Li1  1  0.0  0.34  0.56  1.0
  V  V2  1  0.0  0.0  0.0  1.0
  Ga  Ga3  1  0.0  0.24  0.39  1.0

Li Li V Ga
Li2VGa crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Li2VGa cluster. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a linear geometry to one V(1) and one Ga(1) atom. The Li(1)-V(1) bond length is 1.18 Å. The Li(1)-Ga(1) bond length is 0.89 Å. In the second Li site, Li(2) is bonded in a single-bond geometry to one Ga(1) atom. The Li(2)-Ga(1) bond length is 0.89 Å. V(1) is bonded in a single-bond geometry to one Li(1) atom. Ga(1) is bonded in a linear geometry to one Li(1) and one Li(2) atom.