data_In2BiW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.56
_cell_length_b   5.56
_cell_length_c   3.07
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   107.37
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In2BiW
_chemical_formula_sum   'In2 Bi1 W1'
_cell_volume   90.38
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In1  1  0.65  0.76  0.53  1.0
  In  In2  1  0.65  0.24  0.53  1.0
  Bi  Bi0  1  0.29  0.0  0.0  1.0
  W  W3  1  0.0  0.0  0.0  1.0

data_In2BiW
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.07
_cell_length_b   5.56
_cell_length_c   5.56
_cell_angle_alpha   107.37
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In2BiW
_chemical_formula_sum   'In2 Bi1 W1'
_cell_volume   90.38
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.53  0.65  0.24  1.0
  In  In1  1  0.53  0.65  0.76  1.0
  Bi  Bi2  1  0.0  0.29  0.0  1.0
  W  W3  1  0.0  0.0  0.0  1.0

In In Bi W
WIn2Bi crystallizes in the triclinic P1 space group. W(1) is bonded in a 3-coordinate geometry to two equivalent In(1), two equivalent In(2), and one Bi(1) atom. There is one shorter (2.48 Å) and one longer (2.60 Å) W(1)-In(1) bond length. There is one shorter (3.04 Å) and one longer (3.14 Å) W(1)-In(2) bond length. The W(1)-Bi(1) bond length is 1.62 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 2-coordinate geometry to two equivalent W(1) and two equivalent In(2) atoms. There is one shorter (2.65 Å) and one longer (2.90 Å) In(1)-In(2) bond length. In the second In site, In(2) is bonded in a 8-coordinate geometry to two equivalent W(1), two equivalent In(1), two equivalent In(2), and two equivalent Bi(1) atoms. Both In(2)-In(2) bond lengths are 3.07 Å. There is one shorter (2.48 Å) and one longer (2.60 Å) In(2)-Bi(1) bond length. Bi(1) is bonded in a 1-coordinate geometry to one W(1) and two equivalent In(2) atoms.