data_CuSbCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.91
_cell_length_b   3.38
_cell_length_c   5.6
_cell_angle_alpha   90.0
_cell_angle_beta   103.7
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CuSbCl2
_chemical_formula_sum   'Cu1 Sb1 Cl2'
_cell_volume   90.22
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu2  1  0.08  0.0  0.18  1.0
  Sb  Sb3  1  0.84  0.69  0.56  1.0
  Cl  Cl0  1  0.88  0.0  0.05  1.0
  Cl  Cl1  1  0.92  0.69  0.37  1.0

data_CuSbCl2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.38
_cell_length_b   4.91
_cell_length_c   5.6
_cell_angle_alpha   103.7
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CuSbCl2
_chemical_formula_sum   'Cu1 Sb1 Cl2'
_cell_volume   90.22
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.0  0.92  0.82  1.0
  Sb  Sb1  1  0.31  0.16  0.44  1.0
  Cl  Cl2  1  0.0  0.12  0.95  1.0
  Cl  Cl3  1  0.31  0.08  0.63  1.0

Cu Sb Cl Cl
CuSbCl2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one CuSbCl2 cluster. Cu(1) is bonded in a distorted single-bond geometry to one Cl(1) and one Cl(2) atom. The Cu(1)-Cl(1) bond length is 1.08 Å. The Cu(1)-Cl(2) bond length is 1.81 Å. Sb(1) is bonded in a distorted single-bond geometry to one Cl(2) atom. The Sb(1)-Cl(2) bond length is 1.21 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. In the second Cl site, Cl(2) is bonded in a 2-coordinate geometry to one Cu(1) and one Sb(1) atom.