data_NbTe2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.78
_cell_length_b   4.78
_cell_length_c   3.38
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NbTe2W
_chemical_formula_sum   'Nb1 Te2 W1'
_cell_volume   77.32
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.0  0.0  0.0  1.0
  Te  Te1  1  0.0  0.39  0.69  1.0
  Te  Te2  1  0.39  0.0  0.69  1.0
  W  W3  1  0.39  0.39  0.0  1.0

data_NbTe2W
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.76
_cell_length_b   6.76
_cell_length_c   3.38
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   NbTe2W
_chemical_formula_sum   'Nb2 Te4 W2'
_cell_volume   154.65
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  2  0.0  0.0  0.0  1.0
  Te  Te1  4  0.2  0.2  0.69  1.0
  W  W2  2  0.39  0.0  0.0  1.0

Nb Te Te W
NbWTe2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two NbWTe2 clusters. Nb(1) is bonded in a 2-coordinate geometry to two equivalent Te(1) atoms. Both Nb(1)-Te(1) bond lengths are 2.14 Å. W(1) is bonded in a 2-coordinate geometry to two equivalent Te(1) atoms. Both W(1)-Te(1) bond lengths are 2.14 Å. Te(1) is bonded in a 2-coordinate geometry to one Nb(1) and one W(1) atom.