data_LiTl2Au
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.5
_cell_length_b   3.5
_cell_length_c   7.59
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiTl2Au
_chemical_formula_sum   'Li1 Tl2 Au1'
_cell_volume   92.76
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.0  0.0  0.31  1.0
  Tl  Tl2  1  0.75  0.75  0.26  1.0
  Tl  Tl3  1  0.0  0.0  0.2  1.0
  Au  Au0  1  0.75  0.75  0.21  1.0

data_LiTl2Au
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.94
_cell_length_b   4.94
_cell_length_c   7.59
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LiTl2Au
_chemical_formula_sum   'Li2 Tl4 Au2'
_cell_volume   185.52
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.31  1.0
  Tl  Tl1  2  0.0  0.0  0.2  1.0
  Tl  Tl2  2  0.25  0.5  0.26  1.0
  Au  Au3  2  0.25  0.5  0.21  1.0

Li Tl Tl Au
LiTlAuTl crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two AuTl clusters and two LiTl clusters. In each AuTl cluster, Au(1) is bonded in a single-bond geometry to one Tl(1) atom. The Au(1)-Tl(1) bond length is 0.37 Å. Tl(1) is bonded in a single-bond geometry to one Au(1) atom. In each LiTl cluster, Li(1) is bonded in a single-bond geometry to one Tl(2) atom. The Li(1)-Tl(2) bond length is 0.87 Å. Tl(2) is bonded in a single-bond geometry to one Li(1) atom.