data_Tl2ReBr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.02
_cell_length_b   5.91
_cell_length_c   5.91
_cell_angle_alpha   32.35
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Tl2ReBr
_chemical_formula_sum   'Tl2 Re1 Br1'
_cell_volume   93.78
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl2  1  0.0  0.0  0.16  1.0
  Tl  Tl3  1  0.51  0.0  0.24  1.0
  Re  Re1  1  0.51  0.0  0.34  1.0
  Br  Br0  1  0.0  0.0  0.21  1.0

data_Tl2ReBr
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.29
_cell_length_b   5.02
_cell_length_c   5.91
_cell_angle_alpha   90.0
_cell_angle_beta   106.18
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Tl2ReBr
_chemical_formula_sum   'Tl2 Re1 Br1'
_cell_volume   93.78
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.76  0.51  0.76  1.0
  Tl  Tl1  1  0.84  0.0  0.84  1.0
  Re  Re2  1  0.66  0.51  0.66  1.0
  Br  Br3  1  0.79  0.0  0.79  1.0

Tl Tl Re Br
ReTlTlBr is gamma nitrogen-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ReTl cluster and one TlBr cluster. In the ReTl cluster, Re(1) is bonded in a single-bond geometry to one Tl(2) atom. The Re(1)-Tl(2) bond length is 0.58 Å. Tl(2) is bonded in a single-bond geometry to one Re(1) atom. In the TlBr cluster, Tl(1) is bonded in a single-bond geometry to one Br(1) atom. The Tl(1)-Br(1) bond length is 0.30 Å. Br(1) is bonded in a single-bond geometry to one Tl(1) atom.