data_Cd2Pb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.53
_cell_length_b   14.53
_cell_length_c   14.53
_cell_angle_alpha   161.39
_cell_angle_beta   161.39
_cell_angle_gamma   26.43
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2Pb
_chemical_formula_sum   'Cd8 Pb4'
_cell_volume   312.27
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.35  0.14  1.0
  Cd  Cd1  1  0.0  0.35  0.01  1.0
  Cd  Cd2  1  0.0  0.0  0.07  1.0
  Cd  Cd3  1  0.0  0.0  0.22  1.0
  Cd  Cd4  1  0.35  0.0  0.8  1.0
  Cd  Cd5  1  0.35  0.0  0.34  1.0
  Cd  Cd6  1  0.0  0.0  0.87  1.0
  Cd  Cd7  1  0.0  0.0  0.42  1.0
  Pb  Pb8  1  0.0  0.35  0.35  1.0
  Pb  Pb9  1  0.0  0.35  0.8  1.0
  Pb  Pb10  1  0.0  0.0  0.27  1.0
  Pb  Pb11  1  0.0  0.0  0.02  1.0

data_Cd2Pb
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.7
_cell_length_b   4.7
_cell_length_c   14.53
_cell_angle_alpha   99.3
_cell_angle_beta   99.3
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2Pb
_chemical_formula_sum   'Cd8 Pb4'
_cell_volume   312.27
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.07  0.07  0.07  1.0
  Cd  Cd1  1  0.22  0.22  0.22  1.0
  Cd  Cd2  1  0.34  0.99  0.99  1.0
  Cd  Cd3  1  0.42  0.42  0.42  1.0
  Cd  Cd4  1  0.66  0.01  0.66  1.0
  Cd  Cd5  1  0.79  0.14  0.79  1.0
  Cd  Cd6  1  0.8  0.45  0.45  1.0
  Cd  Cd7  1  0.87  0.87  0.87  1.0
  Pb  Pb8  1  0.02  0.02  0.02  1.0
  Pb  Pb9  1  0.27  0.27  0.27  1.0
  Pb  Pb10  1  0.45  0.8  0.45  1.0
  Pb  Pb11  1  1.0  0.35  1.0  1.0

Cd Cd Cd Cd Cd Cd Cd Cd Pb Pb Pb Pb
Cd2Pb is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Cd2Pb cluster. There are eight inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted trigonal planar geometry to one Cd(2), one Cd(7), and one Pb(1) atom. The Cd(1)-Cd(2) bond length is 1.95 Å. The Cd(1)-Cd(7) bond length is 1.88 Å. The Cd(1)-Pb(1) bond length is 3.01 Å. In the second Cd site, Cd(2) is bonded in a linear geometry to one Cd(1) and one Pb(2) atom. The Cd(2)-Pb(2) bond length is 3.01 Å. In the third Cd site, Cd(3) is bonded in a single-bond geometry to one Pb(1) and one Pb(4) atom. The Cd(3)-Pb(1) bond length is 1.78 Å. The Cd(3)-Pb(4) bond length is 0.74 Å. In the fourth Cd site, Cd(4) is bonded in a single-bond geometry to one Pb(3) atom. The Cd(4)-Pb(3) bond length is 0.74 Å. In the fifth Cd site, Cd(5) is bonded in a 2-coordinate geometry to one Cd(8) and one Pb(2) atom. The Cd(5)-Cd(8) bond length is 1.80 Å. The Cd(5)-Pb(2) bond length is 2.32 Å. In the sixth Cd site, Cd(6) is bonded in a single-bond geometry to one Pb(4) atom. The Cd(6)-Pb(4) bond length is 1.62 Å. In the seventh Cd site, Cd(7) is bonded in a distorted single-bond geometry to one Cd(1) and one Pb(4) atom. The Cd(7)-Pb(4) bond length is 2.07 Å. In the eighth Cd site, Cd(8) is bonded in a 2-coordinate geometry to one Cd(5), one Pb(2), and one Pb(3) atom. The Cd(8)-Pb(2) bond length is 1.78 Å. The Cd(8)-Pb(3) bond length is 2.07 Å. There are four inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 2-coordinate geometry to one Cd(1), one Cd(3), and one Pb(4) atom. The Pb(1)-Pb(4) bond length is 1.62 Å. In the second Pb site, Pb(2) is bonded in a distorted single-bond geometry to one Cd(2), one Cd(5), and one Cd(8) atom. In the third Pb site, Pb(3) is bonded in a linear geometry to one Cd(4) and one Cd(8) atom. In the fourth Pb site, Pb(4) is bonded in a distorted single-bond geometry to one Cd(3), one Cd(6), one Cd(7), and one Pb(1) atom.