data_NiP2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.68
_cell_length_b   5.68
_cell_length_c   5.68
_cell_angle_alpha   151.52
_cell_angle_beta   134.4
_cell_angle_gamma   54.65
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NiP2Cl
_chemical_formula_sum   'Ni1 P2 Cl1'
_cell_volume   62.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni1  1  0.0  0.0  0.05  1.0
  P  P2  1  0.0  0.2  0.94  1.0
  P  P3  1  0.4  0.0  0.11  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_NiP2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.8
_cell_length_b   4.4
_cell_length_c   5.68
_cell_angle_alpha   112.8
_cell_angle_beta   104.24
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NiP2Cl
_chemical_formula_sum   'Ni1 P2 Cl1'
_cell_volume   62.17
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.0  0.05  0.05  1.0
  P  P1  1  0.0  0.11  0.71  1.0
  P  P2  1  0.8  0.74  0.74  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Ni P P Cl
NiP2Cl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one NiP2Cl cluster. Ni(1) is bonded in a single-bond geometry to one Cl(1) atom. The Ni(1)-Cl(1) bond length is 0.27 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a single-bond geometry to one Cl(1) atom. The P(1)-Cl(1) bond length is 1.46 Å. In the second P site, P(2) is bonded in a distorted single-bond geometry to one Cl(1) atom. The P(2)-Cl(1) bond length is 1.88 Å. Cl(1) is bonded in a distorted single-bond geometry to one Ni(1), one P(1), and one P(2) atom.