data_TlGeCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.33
_cell_length_b   5.33
_cell_length_c   5.32
_cell_angle_alpha   90.77
_cell_angle_beta   90.77
_cell_angle_gamma   89.16
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlGeCl3
_chemical_formula_sum   'Tl1 Ge1 Cl3'
_cell_volume   151.04
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.08  0.0  0.05  1.0
  Ge  Ge1  1  0.9  0.0  0.49  1.0
  Cl  Cl2  1  0.58  0.22  0.54  1.0
  Cl  Cl3  1  0.77  0.0  0.03  1.0
  Cl  Cl4  1  0.58  0.78  0.54  1.0

data_TlGeCl3
_symmetry_space_group_name_H-M   Pm
_cell_length_a   5.32
_cell_length_b   5.33
_cell_length_c   5.33
_cell_angle_alpha   90.0
_cell_angle_beta   90.77
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   TlGeCl3
_chemical_formula_sum   'Tl1 Ge1 Cl3'
_cell_volume   151.07
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.05  0.0  0.08  1.0
  Ge  Ge1  1  0.49  0.0  0.9  1.0
  Cl  Cl2  2  0.54  0.22  0.58  1.0
  Cl  Cl3  1  0.03  0.0  0.77  1.0

Tl Ge Cl Cl Cl
TlClGeCl2 crystallizes in the monoclinic Pm space group. The structure is zero-dimensional and consists of one 10060-11-4 molecule and one thallium chloride molecule.