data_CoSnPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.02
_cell_length_b   3.02
_cell_length_c   7.03
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   92.44
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CoSnPd2
_chemical_formula_sum   'Co1 Sn1 Pd2'
_cell_volume   63.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.0  0.0  1.0
  Sn  Sn3  1  0.0  0.0  0.51  1.0
  Pd  Pd1  1  0.09  0.0  0.59  1.0
  Pd  Pd2  1  0.09  0.0  0.43  1.0

data_CoSnPd2
_symmetry_space_group_name_H-M   Pm
_cell_length_a   3.02
_cell_length_b   3.02
_cell_length_c   7.03
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   CoSnPd2
_chemical_formula_sum   'Co1 Sn1 Pd2'
_cell_volume   63.99
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.0  0.0  1.0
  Sn  Sn1  1  0.0  0.0  0.51  1.0
  Pd  Pd2  1  0.09  0.0  0.43  1.0
  Pd  Pd3  1  0.09  0.0  0.59  1.0

Co Sn Pd Pd
CoPd2Sn crystallizes in the monoclinic Pm space group. Co(1) is bonded to four equivalent Co(1), one Pd(1), and one Pd(2) atom to form a mixture of distorted corner and edge-sharing CoCo4Pd2 octahedra. The corner-sharing octahedra are not tilted. All Co(1)-Co(1) bond lengths are 3.02 Å. The Co(1)-Pd(1) bond length is 2.87 Å. The Co(1)-Pd(2) bond length is 3.07 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a single-bond geometry to one Co(1) and one Sn(1) atom. The Pd(1)-Sn(1) bond length is 0.62 Å. In the second Pd site, Pd(2) is bonded in a single-bond geometry to one Co(1) and one Sn(1) atom. The Pd(2)-Sn(1) bond length is 0.62 Å. Sn(1) is bonded in a bent 120 degrees geometry to one Pd(1) and one Pd(2) atom.