data_Ag5Pt7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.38
_cell_length_b   6.38
_cell_length_c   4.93
_cell_angle_alpha   97.16
_cell_angle_beta   97.16
_cell_angle_gamma   84.21
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ag5Pt7
_chemical_formula_sum   'Ag5 Pt7'
_cell_volume   196.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.73  0.73  0.0  1.0
  Ag  Ag1  1  0.16  0.41  0.21  1.0
  Ag  Ag2  1  0.73  0.99  0.62  1.0
  Ag  Ag3  1  0.48  0.41  0.65  1.0
  Ag  Ag4  1  0.91  0.99  0.23  1.0
  Pt  Pt5  1  0.32  0.82  0.43  1.0
  Pt  Pt6  1  0.73  0.47  0.0  1.0
  Pt  Pt7  1  0.17  0.54  0.22  1.0
  Pt  Pt8  1  0.32  0.97  0.43  1.0
  Pt  Pt9  1  0.73  0.63  0.0  1.0
  Pt  Pt10  1  0.32  0.23  0.43  1.0
  Pt  Pt11  1  0.46  0.54  0.64  1.0

data_Ag5Pt7
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.93
_cell_length_b   6.38
_cell_length_c   6.38
_cell_angle_alpha   84.21
_cell_angle_beta   82.84
_cell_angle_gamma   82.84
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ag5Pt7
_chemical_formula_sum   'Ag5 Pt7'
_cell_volume   196.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  -0.0  0.27  0.27  1.0
  Ag  Ag1  1  0.21  0.84  0.59  1.0
  Ag  Ag2  1  0.23  0.09  0.01  1.0
  Ag  Ag3  1  0.62  0.27  0.01  1.0
  Ag  Ag4  1  0.65  0.52  0.59  1.0
  Pt  Pt5  1  -0.0  0.27  0.53  1.0
  Pt  Pt6  1  -0.0  0.27  0.37  1.0
  Pt  Pt7  1  0.22  0.83  0.46  1.0
  Pt  Pt8  1  0.43  0.68  0.03  1.0
  Pt  Pt9  1  0.43  0.68  0.18  1.0
  Pt  Pt10  1  0.43  0.68  0.77  1.0
  Pt  Pt11  1  0.64  0.54  0.46  1.0

Ag Ag Ag Ag Ag Pt Pt Pt Pt Pt Pt Pt
Pt7Ag5 crystallizes in the triclinic P1 space group. There are seven inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a distorted single-bond geometry to one Pt(4), one Ag(3), and one Ag(5) atom. The Pt(1)-Pt(4) bond length is 0.96 Å. The Pt(1)-Ag(3) bond length is 2.94 Å. The Pt(1)-Ag(5) bond length is 2.83 Å. In the second Pt site, Pt(2) is bonded in a 1-coordinate geometry to one Pt(5), one Ag(3), and one Ag(5) atom. The Pt(2)-Pt(5) bond length is 1.03 Å. The Pt(2)-Ag(3) bond length is 3.36 Å. The Pt(2)-Ag(5) bond length is 3.42 Å. In the third Pt site, Pt(3) is bonded in a single-bond geometry to one Ag(2) and one Ag(5) atom. The Pt(3)-Ag(2) bond length is 0.88 Å. The Pt(3)-Ag(5) bond length is 3.18 Å. In the fourth Pt site, Pt(4) is bonded in a distorted rectangular see-saw-like geometry to one Pt(1), one Pt(6), one Ag(3), and one Ag(5) atom. The Pt(4)-Pt(6) bond length is 1.67 Å. The Pt(4)-Ag(3) bond length is 2.67 Å. The Pt(4)-Ag(5) bond length is 2.65 Å. In the fifth Pt site, Pt(5) is bonded in a distorted single-bond geometry to one Pt(2) and one Ag(1) atom. The Pt(5)-Ag(1) bond length is 0.65 Å. In the sixth Pt site, Pt(6) is bonded in a 3-coordinate geometry to one Pt(4), one Ag(2), one Ag(3), one Ag(4), and one Ag(5) atom. The Pt(6)-Ag(2) bond length is 1.82 Å. The Pt(6)-Ag(3) bond length is 2.97 Å. The Pt(6)-Ag(4) bond length is 1.78 Å. The Pt(6)-Ag(5) bond length is 3.11 Å. In the seventh Pt site, Pt(7) is bonded in a single-bond geometry to one Ag(4) atom. The Pt(7)-Ag(4) bond length is 0.87 Å. There are five inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a single-bond geometry to one Pt(5), one Ag(3), and one Ag(5) atom. The Ag(1)-Ag(3) bond length is 2.63 Å. The Ag(1)-Ag(5) bond length is 2.23 Å. In the second Ag site, Ag(2) is bonded in a 1-coordinate geometry to one Pt(3), one Pt(6), and one Ag(5) atom. The Ag(2)-Ag(5) bond length is 3.22 Å. In the third Ag site, Ag(3) is bonded in a 8-coordinate geometry to one Pt(1), one Pt(2), one Pt(4), one Pt(6), one Ag(1), one Ag(4), and two equivalent Ag(5) atoms. The Ag(3)-Ag(4) bond length is 2.92 Å. There is one shorter (2.39 Å) and one longer (3.08 Å) Ag(3)-Ag(5) bond length. In the fourth Ag site, Ag(4) is bonded in a 1-coordinate geometry to one Pt(6), one Pt(7), and one Ag(3) atom. In the fifth Ag site, Ag(5) is bonded in a 9-coordinate geometry to one Pt(1), one Pt(2), one Pt(3), one Pt(4), one Pt(6), one Ag(1), one Ag(2), and two equivalent Ag(3) atoms.