data_In2BiPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.23
_cell_length_b   3.5
_cell_length_c   7.8
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In2BiPd
_chemical_formula_sum   'In2 Bi1 Pd1'
_cell_volume   88.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In1  1  0.61  0.75  0.25  1.0
  In  In2  1  0.61  0.75  0.55  1.0
  Bi  Bi0  1  0.0  0.0  0.9  1.0
  Pd  Pd3  1  0.0  0.0  0.0  1.0

data_In2BiPd
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.23
_cell_length_b   3.5
_cell_length_c   7.8
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In2BiPd
_chemical_formula_sum   'In2 Bi1 Pd1'
_cell_volume   88.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.61  0.75  0.25  1.0
  In  In1  1  0.61  0.75  0.55  1.0
  Bi  Bi2  1  0.0  0.0  0.9  1.0
  Pd  Pd3  1  0.0  0.0  0.0  1.0

In In Bi Pd
PdIn2Bi crystallizes in the triclinic P1 space group. Pd(1) is bonded in a distorted single-bond geometry to two equivalent In(1) and one Bi(1) atom. There is one shorter (2.47 Å) and one longer (2.92 Å) Pd(1)-In(1) bond length. The Pd(1)-Bi(1) bond length is 0.79 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 3-coordinate geometry to two equivalent Pd(1) and one In(2) atom. The In(1)-In(2) bond length is 2.31 Å. In the second In site, In(2) is bonded in a 7-coordinate geometry to one In(1), four equivalent In(2), and two equivalent Bi(1) atoms. There are two shorter (3.23 Å) and two longer (3.50 Å) In(2)-In(2) bond lengths. There is one shorter (3.14 Å) and one longer (3.50 Å) In(2)-Bi(1) bond length. Bi(1) is bonded in a single-bond geometry to one Pd(1) and two equivalent In(2) atoms.