data_Te4Rh5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.33
_cell_length_b   7.33
_cell_length_c   7.33
_cell_angle_alpha   93.53
_cell_angle_beta   93.53
_cell_angle_gamma   151.27
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Te4Rh5
_chemical_formula_sum   'Te4 Rh5'
_cell_volume   183.57
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te5  1  0.0  0.37  0.0  1.0
  Te  Te6  1  0.0  0.68  0.0  1.0
  Te  Te7  1  0.68  0.0  0.0  1.0
  Te  Te8  1  0.37  0.0  0.0  1.0
  Rh  Rh0  1  0.0  0.0  0.0  1.0
  Rh  Rh1  1  0.23  0.77  0.82  1.0
  Rh  Rh2  1  0.77  0.23  0.82  1.0
  Rh  Rh3  1  0.25  0.25  0.0  1.0
  Rh  Rh4  1  0.77  0.77  0.82  1.0

data_Te4Rh5
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.64
_cell_length_b   14.21
_cell_length_c   7.33
_cell_angle_alpha   90.0
_cell_angle_beta   104.36
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Te4Rh5
_chemical_formula_sum   'Te8 Rh10'
_cell_volume   367.14
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  4  0.16  0.16  -0.0  1.0
  Te  Te1  4  0.32  0.32  0.0  1.0
  Rh  Rh2  4  0.32  0.27  0.82  1.0
  Rh  Rh3  2  0.0  0.0  0.0  1.0
  Rh  Rh4  2  0.04  0.0  0.82  1.0
  Rh  Rh5  2  0.25  0.5  0.0  1.0

Te Te Te Te Rh Rh Rh Rh Rh
(Rh)3(RhTe2)2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Rh clusters and four RhTe2 clusters. In each Rh cluster, there are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted water-like geometry to one Rh(3) and one Rh(4) atom. The Rh(1)-Rh(3) bond length is 0.90 Å. The Rh(1)-Rh(4) bond length is 1.38 Å. In the second Rh site, Rh(3) is bonded in a single-bond geometry to one Rh(1) atom. In the third Rh site, Rh(4) is bonded in a single-bond geometry to one Rh(1) atom. In each RhTe2 cluster, Rh(2) is bonded in a distorted single-bond geometry to one Te(1) and one Te(2) atom. The Rh(2)-Te(1) bond length is 1.45 Å. The Rh(2)-Te(2) bond length is 1.82 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted single-bond geometry to one Rh(2) and one Te(2) atom. The Te(1)-Te(2) bond length is 1.30 Å. In the second Te site, Te(2) is bonded in a 2-coordinate geometry to one Rh(2) and one Te(1) atom.