data_BaTcMo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.83
_cell_length_b   4.83
_cell_length_c   3.22
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaTcMo2
_chemical_formula_sum   'Ba1 Tc1 Mo2'
_cell_volume   75.12
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.42  0.42  0.0  1.0
  Tc  Tc3  1  0.0  0.0  0.0  1.0
  Mo  Mo1  1  0.42  0.0  0.61  1.0
  Mo  Mo2  1  0.0  0.42  0.61  1.0

data_BaTcMo2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.83
_cell_length_b   6.83
_cell_length_c   3.22
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   BaTcMo2
_chemical_formula_sum   'Ba2 Tc2 Mo4'
_cell_volume   150.25
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  2  0.42  0.0  -0.0  1.0
  Tc  Tc1  2  0.0  0.0  0.0  1.0
  Mo  Mo2  4  0.21  0.21  0.61  1.0

Ba Tc Mo Mo
BaMo2Tc crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two BaMo2Tc clusters. Ba(1) is bonded in a 2-coordinate geometry to two equivalent Mo(1) atoms. Both Ba(1)-Mo(1) bond lengths are 2.37 Å. Mo(1) is bonded in a 1-coordinate geometry to one Ba(1) and one Tc(1) atom. The Mo(1)-Tc(1) bond length is 2.37 Å. Tc(1) is bonded in a 2-coordinate geometry to two equivalent Mo(1) atoms.