data_VSiB
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.8
_cell_length_b   3.8
_cell_length_c   2.49
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VSiB
_chemical_formula_sum   'V1 Si1 B1'
_cell_volume   31.22
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.2  0.25  1.0
  Si  Si1  1  0.9  0.1  0.0  1.0
  B  B0  1  0.0  0.0  0.0  1.0

data_VSiB
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.49
_cell_length_b   3.8
_cell_length_c   3.8
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VSiB
_chemical_formula_sum   'V1 Si1 B1'
_cell_volume   31.22
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.25  -0.0  0.2  1.0
  Si  Si1  1  0.0  0.9  0.1  1.0
  B  B2  1  0.0  0.0  0.0  1.0

V Si B
VBSi crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VBSi cluster. V(1) is bonded in a 1-coordinate geometry to one Si(1) atom. The V(1)-Si(1) bond length is 0.72 Å. B(1) is bonded in a distorted single-bond geometry to one Si(1) atom. The B(1)-Si(1) bond length is 0.65 Å. Si(1) is bonded in a distorted L-shaped geometry to one V(1) and one B(1) atom.