data_TaMo2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.02
_cell_length_b   5.02
_cell_length_c   5.02
_cell_angle_alpha   133.58
_cell_angle_beta   133.58
_cell_angle_gamma   67.74
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TaMo2Pd
_chemical_formula_sum   'Ta1 Mo2 Pd1'
_cell_volume   65.34
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta3  1  0.0  0.0  0.17  1.0
  Mo  Mo0  1  0.98  0.0  0.08  1.0
  Mo  Mo1  1  0.0  0.98  0.08  1.0
  Pd  Pd2  1  0.0  0.0  0.0  1.0

data_TaMo2Pd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.6
_cell_length_b   5.6
_cell_length_c   5.02
_cell_angle_alpha   90.0
_cell_angle_beta   123.87
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TaMo2Pd
_chemical_formula_sum   'Ta2 Mo4 Pd2'
_cell_volume   130.68
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  2  0.0  0.0  0.17  1.0
  Mo  Mo1  4  0.01  0.99  0.11  1.0
  Pd  Pd2  2  0.0  0.0  0.0  1.0

Ta Mo Mo Pd
TaMo2Pd crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two TaMo2Pd clusters. Ta(1) is bonded in a 2-coordinate geometry to two equivalent Mo(1) atoms. Both Ta(1)-Mo(1) bond lengths are 0.36 Å. Mo(1) is bonded in a single-bond geometry to one Ta(1), one Mo(1), and one Pd(1) atom. The Mo(1)-Mo(1) bond length is 0.12 Å. The Mo(1)-Pd(1) bond length is 0.50 Å. Pd(1) is bonded in a 2-coordinate geometry to two equivalent Mo(1) atoms.