data_NaTePd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.41
_cell_length_b   4.89
_cell_length_c   5.05
_cell_angle_alpha   90.0
_cell_angle_beta   102.22
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaTePd2
_chemical_formula_sum   'Na1 Te1 Pd2'
_cell_volume   82.23
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.02  0.0  0.78  1.0
  Te  Te3  1  0.58  0.44  0.23  1.0
  Pd  Pd1  1  0.2  0.44  0.07  1.0
  Pd  Pd2  1  0.12  0.0  0.33  1.0

data_NaTePd2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.41
_cell_length_b   4.89
_cell_length_c   5.05
_cell_angle_alpha   90.0
_cell_angle_beta   102.22
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaTePd2
_chemical_formula_sum   'Na1 Te1 Pd2'
_cell_volume   82.23
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.02  0.0  0.78  1.0
  Te  Te1  1  0.58  0.44  0.23  1.0
  Pd  Pd2  1  0.12  0.0  0.33  1.0
  Pd  Pd3  1  0.2  0.44  0.07  1.0

Na Te Pd Pd
NaPd2Te crystallizes in the triclinic P1 space group. Na(1) is bonded in a 4-coordinate geometry to two equivalent Pd(1) and two equivalent Pd(2) atoms. There is one shorter (2.60 Å) and one longer (3.07 Å) Na(1)-Pd(1) bond length. There is one shorter (2.41 Å) and one longer (2.69 Å) Na(1)-Pd(2) bond length. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 4-coordinate geometry to two equivalent Na(1) and two equivalent Te(1) atoms. There is one shorter (1.40 Å) and one longer (2.39 Å) Pd(1)-Te(1) bond length. In the second Pd site, Pd(2) is bonded in a 2-coordinate geometry to two equivalent Na(1) atoms. Te(1) is bonded in a distorted single-bond geometry to two equivalent Pd(1) atoms.