data_Li2VCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.6
_cell_length_b   4.06
_cell_length_c   4.78
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2VCl
_chemical_formula_sum   'Li2 V1 Cl1'
_cell_volume   69.82
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.8  0.0  0.39  1.0
  Li  Li2  1  0.0  0.0  0.0  1.0
  V  V3  1  0.0  0.03  0.39  1.0
  Cl  Cl0  1  0.8  0.03  0.0  1.0

data_Li2VCl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.6
_cell_length_b   4.06
_cell_length_c   4.78
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2VCl
_chemical_formula_sum   'Li2 V1 Cl1'
_cell_volume   69.82
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.0  1.0
  Li  Li1  1  0.8  0.0  0.39  1.0
  V  V2  1  0.0  0.03  0.39  1.0
  Cl  Cl3  1  0.8  0.03  0.0  1.0

Li Li V Cl
VLiLiCl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one lithium chloride molecule and one VLi cluster. In the VLi cluster, Li(1) is bonded in a distorted single-bond geometry to one V(1) atom. The Li(1)-V(1) bond length is 0.73 Å. V(1) is bonded in a single-bond geometry to one Li(1) atom.