data_NaSc2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.99
_cell_length_b   2.99
_cell_length_c   10.54
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   105.67
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaSc2W
_chemical_formula_sum   'Na1 Sc2 W1'
_cell_volume   90.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.0  1.0
  Sc  Sc1  1  0.81  0.0  0.13  1.0
  Sc  Sc2  1  0.81  0.0  0.41  1.0
  W  W3  1  0.0  0.0  0.27  1.0

data_NaSc2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.99
_cell_length_b   2.99
_cell_length_c   10.54
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   105.67
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaSc2W
_chemical_formula_sum   'Na1 Sc2 W1'
_cell_volume   90.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.0  1.0
  Sc  Sc1  1  0.81  0.0  0.13  1.0
  Sc  Sc2  1  0.81  0.0  0.41  1.0
  W  W3  1  0.0  0.0  0.27  1.0

Na Sc Sc W
NaSc2W crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one NaSc2W cluster. Na(1) is bonded in a single-bond geometry to one Sc(1) atom. The Na(1)-Sc(1) bond length is 1.52 Å. There are two inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in a 2-coordinate geometry to one Na(1) and one W(1) atom. The Sc(1)-W(1) bond length is 1.58 Å. In the second Sc site, Sc(2) is bonded in a single-bond geometry to one W(1) atom. The Sc(2)-W(1) bond length is 1.58 Å. W(1) is bonded in a distorted bent 150 degrees geometry to one Sc(1) and one Sc(2) atom.