data_NaIn2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.3
_cell_length_b   5.3
_cell_length_c   5.3
_cell_angle_alpha   131.04
_cell_angle_beta   131.04
_cell_angle_gamma   71.75
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaIn2Pd
_chemical_formula_sum   'Na1 In2 Pd1'
_cell_volume   83.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na2  1  0.0  0.0  0.0  1.0
  In  In0  1  0.0  0.2  0.15  1.0
  In  In1  1  0.2  0.0  0.15  1.0
  Pd  Pd3  1  0.0  0.0  0.3  1.0

data_NaIn2Pd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.22
_cell_length_b   6.22
_cell_length_c   5.3
_cell_angle_alpha   90.0
_cell_angle_beta   125.87
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   NaIn2Pd
_chemical_formula_sum   'Na2 In4 Pd2'
_cell_volume   166.12
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  2  0.0  0.0  0.0  1.0
  In  In1  4  0.45  0.4  0.05  1.0
  Pd  Pd2  2  0.2  0.5  0.7  1.0

Na In In Pd
NaPdIn2 is Indium-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two NaPdIn2 clusters. Na(1) is bonded in a water-like geometry to one Pd(1) and two equivalent In(1) atoms. The Na(1)-Pd(1) bond length is 1.58 Å. Both Na(1)-In(1) bond lengths are 0.80 Å. Pd(1) is bonded in a 3-coordinate geometry to one Na(1) and two equivalent In(1) atoms. Both Pd(1)-In(1) bond lengths are 1.68 Å. In(1) is bonded in a single-bond geometry to one Na(1) and one Pd(1) atom.