data_VSiBi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.51
_cell_length_b   5.51
_cell_length_c   5.51
_cell_angle_alpha   144.34
_cell_angle_beta   144.34
_cell_angle_gamma   51.32
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VSiBi
_chemical_formula_sum   'V1 Si1 Bi1'
_cell_volume   56.44
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.0  0.0  1.0
  Si  Si1  1  0.0  0.0  0.88  1.0
  Bi  Bi0  1  0.0  0.0  0.05  1.0

data_VSiBi
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.77
_cell_length_b   4.77
_cell_length_c   5.51
_cell_angle_alpha   90.0
_cell_angle_beta   115.66
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VSiBi
_chemical_formula_sum   'V2 Si2 Bi2'
_cell_volume   112.87
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.0  1.0
  Si  Si1  2  0.38  0.5  0.88  1.0
  Bi  Bi2  2  0.05  0.0  0.05  1.0

V Si Bi
VSiBi is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two VSiBi clusters. V(1) is bonded in a linear geometry to one Si(1) and one Bi(1) atom. The V(1)-Si(1) bond length is 0.69 Å. The V(1)-Bi(1) bond length is 0.28 Å. Si(1) is bonded in a single-bond geometry to one V(1) atom. Bi(1) is bonded in a single-bond geometry to one V(1) atom.