data_VCdAg2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.86
_cell_length_b   2.86
_cell_length_c   8.93
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   94.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCdAg2
_chemical_formula_sum   'V1 Cd1 Ag2'
_cell_volume   72.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.19  1.0
  Cd  Cd2  1  0.94  0.0  0.36  1.0
  Ag  Ag0  1  0.94  0.0  0.1  1.0
  Ag  Ag1  1  0.0  0.0  0.75  1.0

data_VCdAg2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.86
_cell_length_b   2.86
_cell_length_c   8.93
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   94.47
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCdAg2
_chemical_formula_sum   'V1 Cd1 Ag2'
_cell_volume   72.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.19  1.0
  Cd  Cd1  1  0.94  0.0  0.36  1.0
  Ag  Ag2  1  0.0  0.0  0.75  1.0
  Ag  Ag3  1  0.94  0.0  0.1  1.0

V Cd Ag Ag
VAg2Cd crystallizes in the triclinic P1 space group. V(1) is bonded in a distorted single-bond geometry to one Ag(1) and one Cd(1) atom. The V(1)-Ag(1) bond length is 0.86 Å. The V(1)-Cd(1) bond length is 1.48 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a single-bond geometry to one V(1) and one Ag(2) atom. The Ag(1)-Ag(2) bond length is 3.16 Å. In the second Ag site, Ag(2) is bonded to one Ag(1), four equivalent Ag(2), and one Cd(1) atom to form a mixture of edge and corner-sharing AgCdAg5 octahedra. The corner-sharing octahedra are not tilted. All Ag(2)-Ag(2) bond lengths are 2.86 Å. The Ag(2)-Cd(1) bond length is 3.48 Å. Cd(1) is bonded in a single-bond geometry to one V(1) and one Ag(2) atom.