data_TiPdW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.54
_cell_length_b   4.54
_cell_length_c   2.68
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiPdW
_chemical_formula_sum   'Ti1 Pd1 W1'
_cell_volume   47.78
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti1  1  0.0  0.0  0.84  1.0
  Pd  Pd0  1  1.0  0.62  0.01  1.0
  W  W2  1  0.27  0.31  0.83  1.0

data_TiPdW
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.68
_cell_length_b   4.54
_cell_length_c   4.54
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiPdW
_chemical_formula_sum   'Ti1 Pd1 W1'
_cell_volume   47.78
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.84  0.0  0.0  1.0
  Pd  Pd1  1  0.01  1.0  0.62  1.0
  W  W2  1  0.83  0.27  0.31  1.0

Ti Pd W
TiWPd crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one TiWPd cluster. Ti(1) is bonded in a distorted bent 120 degrees geometry to one W(1) and one Pd(1) atom. The Ti(1)-W(1) bond length is 1.33 Å. The Ti(1)-Pd(1) bond length is 1.78 Å. W(1) is bonded in a single-bond geometry to one Ti(1) atom. Pd(1) is bonded in a distorted single-bond geometry to one Ti(1) atom.