data_VSb2Pt
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.95
_cell_length_b   4.95
_cell_length_c   4.95
_cell_angle_alpha   125.37
_cell_angle_beta   125.37
_cell_angle_gamma   80.93
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VSb2Pt
_chemical_formula_sum   'V1 Sb2 Pt1'
_cell_volume   77.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Sb  Sb1  1  0.0  0.27  0.88  1.0
  Sb  Sb2  1  0.27  0.0  0.88  1.0
  Pt  Pt0  1  0.0  0.0  0.77  1.0

data_VSb2Pt
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.43
_cell_length_b   6.43
_cell_length_c   4.95
_cell_angle_alpha   90.0
_cell_angle_beta   130.46
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VSb2Pt
_chemical_formula_sum   'V2 Sb4 Pt2'
_cell_volume   155.68
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.0  1.0
  Sb  Sb1  4  0.36  0.36  0.61  1.0
  Pt  Pt2  2  0.0  0.0  0.77  1.0

V Sb Sb Pt
VPtSb2 is Copper structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two VPtSb2 clusters. V(1) is bonded in a single-bond geometry to one Pt(1) atom. The V(1)-Pt(1) bond length is 1.15 Å. Pt(1) is bonded in a trigonal non-coplanar geometry to one V(1) and two equivalent Sb(1) atoms. Both Pt(1)-Sb(1) bond lengths are 1.12 Å. Sb(1) is bonded in a single-bond geometry to one Pt(1) atom.