data_LiZnTc2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.66
_cell_length_b   2.66
_cell_length_c   9.12
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   113.85
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiZnTc2
_chemical_formula_sum   'Li1 Zn1 Tc2'
_cell_volume   58.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.27  1.0
  Zn  Zn3  1  0.45  0.0  0.56  1.0
  Tc  Tc1  1  0.45  0.0  0.06  1.0
  Tc  Tc2  1  0.0  0.0  0.9  1.0

data_LiZnTc2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.66
_cell_length_b   2.66
_cell_length_c   9.12
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   113.85
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiZnTc2
_chemical_formula_sum   'Li1 Zn1 Tc2'
_cell_volume   58.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.27  1.0
  Zn  Zn1  1  0.45  0.0  0.56  1.0
  Tc  Tc2  1  0.0  0.0  0.9  1.0
  Tc  Tc3  1  0.45  0.0  0.06  1.0

Li Zn Tc Tc
LiTc2Zn crystallizes in the triclinic P1 space group. Li(1) is bonded in a 2-coordinate geometry to two equivalent Tc(1) and two equivalent Zn(1) atoms. There is one shorter (2.25 Å) and one longer (2.40 Å) Li(1)-Tc(1) bond length. There is one shorter (2.94 Å) and one longer (3.05 Å) Li(1)-Zn(1) bond length. There are two inequivalent Tc sites. In the first Tc site, Tc(1) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent Tc(2) atoms. There is one shorter (1.88 Å) and one longer (2.05 Å) Tc(1)-Tc(2) bond length. In the second Tc site, Tc(2) is bonded in a distorted L-shaped geometry to two equivalent Tc(1) and two equivalent Zn(1) atoms. There is one shorter (3.32 Å) and one longer (3.42 Å) Tc(2)-Zn(1) bond length. Zn(1) is bonded in a 10-coordinate geometry to two equivalent Li(1), two equivalent Tc(2), and six equivalent Zn(1) atoms. There are four shorter (2.66 Å) and two longer (2.90 Å) Zn(1)-Zn(1) bond lengths.