data_VCd2In
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.28
_cell_length_b   10.28
_cell_length_c   10.28
_cell_angle_alpha   17.21
_cell_angle_beta   17.21
_cell_angle_gamma   17.21
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCd2In
_chemical_formula_sum   'V1 Cd2 In1'
_cell_volume   82.96
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Cd  Cd0  1  0.0  0.0  0.53  1.0
  Cd  Cd1  1  0.0  0.0  0.85  1.0
  In  In2  1  0.0  0.0  0.19  1.0

data_VCd2In
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.33
_cell_length_b   3.08
_cell_length_c   10.28
_cell_angle_alpha   90.0
_cell_angle_beta   99.95
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VCd2In
_chemical_formula_sum   'V2 Cd4 In2'
_cell_volume   165.93
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.0  1.0
  Cd  Cd1  2  -0.0  0.0  0.47  1.0
  Cd  Cd2  2  -0.0  0.0  0.15  1.0
  In  In3  2  -0.0  0.0  0.81  1.0

V Cd Cd In
VCd2In crystallizes in the monoclinic Cm space group. V(1) is bonded in a linear geometry to one Cd(2) and one In(1) atom. The V(1)-Cd(2) bond length is 1.57 Å. The V(1)-In(1) bond length is 1.92 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one Cd(2), six equivalent Cd(1), and one In(1) atom to form a mixture of edge and corner-sharing CdCd7In hexagonal bipyramids. The Cd(1)-Cd(2) bond length is 3.31 Å. All Cd(1)-Cd(1) bond lengths are 3.08 Å. The Cd(1)-In(1) bond length is 3.49 Å. In the second Cd site, Cd(2) is bonded in a single-bond geometry to one V(1) and one Cd(1) atom. In(1) is bonded in a single-bond geometry to one V(1) and one Cd(1) atom.