data_ZnMoAu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.82
_cell_length_b   4.89
_cell_length_c   4.9
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnMoAu2
_chemical_formula_sum   'Zn1 Mo1 Au2'
_cell_volume   67.51
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.0  0.0  1.0
  Mo  Mo2  1  0.41  0.0  0.45  1.0
  Au  Au0  1  0.0  0.45  0.45  1.0
  Au  Au1  1  0.41  0.45  0.0  1.0

data_ZnMoAu2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.82
_cell_length_b   4.89
_cell_length_c   4.9
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnMoAu2
_chemical_formula_sum   'Zn1 Mo1 Au2'
_cell_volume   67.51
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.0  0.0  0.0  1.0
  Mo  Mo1  1  0.41  0.0  0.45  1.0
  Au  Au2  1  -0.0  0.45  0.45  1.0
  Au  Au3  1  0.41  0.45  -0.0  1.0

Zn Mo Au Au
MoAu2Zn crystallizes in the triclinic P1 space group. Mo(1) is bonded in a 2-coordinate geometry to one Au(1) and four equivalent Zn(1) atoms. The Mo(1)-Au(1) bond length is 2.47 Å. There are a spread of Mo(1)-Zn(1) bond distances ranging from 2.49-3.17 Å. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a 1-coordinate geometry to one Mo(1) and one Zn(1) atom. The Au(1)-Zn(1) bond length is 3.10 Å. In the second Au site, Au(2) is bonded in a 3-coordinate geometry to four equivalent Zn(1) atoms. There are a spread of Au(2)-Zn(1) bond distances ranging from 2.47-3.18 Å. Zn(1) is bonded in a 11-coordinate geometry to four equivalent Mo(1), one Au(1), four equivalent Au(2), and two equivalent Zn(1) atoms. Both Zn(1)-Zn(1) bond lengths are 2.82 Å.