data_LaCdInTc
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.07
_cell_length_b   5.07
_cell_length_c   5.07
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaCdInTc
_chemical_formula_sum   'La1 Cd1 In1 Tc1'
_cell_volume   92.41
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La2  1  0.79  0.79  0.79  1.0
  Cd  Cd0  1  0.38  0.38  0.38  1.0
  In  In1  1  0.59  0.59  0.59  1.0
  Tc  Tc3  1  0.0  0.0  0.0  1.0

data_LaCdInTc
_symmetry_space_group_name_H-M   R3m
_cell_length_a   5.07
_cell_length_b   5.07
_cell_length_c   12.43
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   LaCdInTc
_chemical_formula_sum   'La3 Cd3 In3 Tc3'
_cell_volume   277.24
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  3  0.0  0.0  0.21  1.0
  Cd  Cd1  3  0.0  0.0  0.62  1.0
  In  In2  3  0.0  0.0  0.41  1.0
  Tc  Tc3  3  0.0  0.0  0.0  1.0

La Cd In Tc
LaTcCdIn crystallizes in the trigonal R3m space group. La(1) is bonded in a distorted linear geometry to one Tc(1), three equivalent Cd(1), and one In(1) atom. The La(1)-Tc(1) bond length is 2.56 Å. All La(1)-Cd(1) bond lengths are 3.09 Å. The La(1)-In(1) bond length is 2.56 Å. Tc(1) is bonded in a distorted single-bond geometry to one La(1) and three equivalent Cd(1) atoms. All Tc(1)-Cd(1) bond lengths are 2.99 Å. Cd(1) is bonded in a 7-coordinate geometry to three equivalent La(1), three equivalent Tc(1), and one In(1) atom. The Cd(1)-In(1) bond length is 2.56 Å. In(1) is bonded in a 2-coordinate geometry to one La(1) and one Cd(1) atom.