data_Li2LaCd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.51
_cell_length_b   3.51
_cell_length_c   7.9
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2LaCd
_chemical_formula_sum   'Li2 La1 Cd1'
_cell_volume   97.53
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li2  1  0.0  0.0  0.48  1.0
  Li  Li3  1  0.76  0.76  0.03  1.0
  La  La1  1  0.76  0.76  0.82  1.0
  Cd  Cd0  1  0.0  0.0  0.51  1.0

data_Li2LaCd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.97
_cell_length_b   4.97
_cell_length_c   7.9
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Li2LaCd
_chemical_formula_sum   'Li4 La2 Cd2'
_cell_volume   195.06
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.48  1.0
  Li  Li1  2  0.26  0.5  0.03  1.0
  La  La2  2  0.26  0.5  0.82  1.0
  Cd  Cd3  2  0.0  0.0  0.51  1.0

Li Li La Cd
Li2LaCd is Indium-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Li2LaCd clusters. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a single-bond geometry to one Cd(1) atom. The Li(1)-Cd(1) bond length is 0.25 Å. In the second Li site, Li(2) is bonded in a single-bond geometry to one La(1) atom. The Li(2)-La(1) bond length is 1.68 Å. La(1) is bonded in a distorted bent 150 degrees geometry to one Li(2) and one Cd(1) atom. The La(1)-Cd(1) bond length is 2.72 Å. Cd(1) is bonded in a single-bond geometry to one Li(1) and one La(1) atom.