data_TiTlTc
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.33
_cell_length_b   5.33
_cell_length_c   5.33
_cell_angle_alpha   143.46
_cell_angle_beta   143.46
_cell_angle_gamma   52.64
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiTlTc
_chemical_formula_sum   'Ti1 Tl1 Tc1'
_cell_volume   53.31
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti1  1  0.0  0.0  0.4  1.0
  Tl  Tl2  1  0.0  0.0  0.36  1.0
  Tc  Tc0  1  0.0  0.0  0.34  1.0

data_TiTlTc
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.72
_cell_length_b   4.72
_cell_length_c   5.33
_cell_angle_alpha   90.0
_cell_angle_beta   116.32
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TiTlTc
_chemical_formula_sum   'Ti2 Tl2 Tc2'
_cell_volume   106.61
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  2  0.0  0.0  0.6  1.0
  Tl  Tl1  2  0.0  0.0  0.64  1.0
  Tc  Tc2  2  0.0  0.0  0.66  1.0

Ti Tl Tc
TiTcTl is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two TiTcTl clusters. Ti(1) is bonded in a single-bond geometry to one Tl(1) atom. The Ti(1)-Tl(1) bond length is 0.24 Å. Tc(1) is bonded in a single-bond geometry to one Tl(1) atom. The Tc(1)-Tl(1) bond length is 0.07 Å. Tl(1) is bonded in a linear geometry to one Ti(1) and one Tc(1) atom.