data_LiSnRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.91
_cell_length_b   4.47
_cell_length_c   4.81
_cell_angle_alpha   90.0
_cell_angle_beta   97.55
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiSnRh2
_chemical_formula_sum   'Li1 Sn1 Rh2'
_cell_volume   62.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.24  0.0  0.68  1.0
  Sn  Sn3  1  0.09  0.23  0.37  1.0
  Rh  Rh1  1  0.51  0.23  0.66  1.0
  Rh  Rh2  1  0.95  0.0  0.21  1.0

data_LiSnRh2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.91
_cell_length_b   4.47
_cell_length_c   4.81
_cell_angle_alpha   90.0
_cell_angle_beta   97.55
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiSnRh2
_chemical_formula_sum   'Li1 Sn1 Rh2'
_cell_volume   62.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.24  0.0  0.68  1.0
  Sn  Sn1  1  0.09  0.23  0.37  1.0
  Rh  Rh2  1  0.51  0.23  0.66  1.0
  Rh  Rh3  1  0.95  0.0  0.21  1.0

Li Sn Rh Rh
LiRh2Sn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LiRh2Sn cluster. Li(1) is bonded in a distorted single-bond geometry to one Rh(1) and one Sn(1) atom. The Li(1)-Rh(1) bond length is 1.32 Å. The Li(1)-Sn(1) bond length is 1.84 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted single-bond geometry to one Li(1) and one Sn(1) atom. The Rh(1)-Sn(1) bond length is 1.76 Å. In the second Rh site, Rh(2) is bonded in a distorted single-bond geometry to one Sn(1) atom. The Rh(2)-Sn(1) bond length is 1.33 Å. Sn(1) is bonded in a 3-coordinate geometry to one Li(1), one Rh(1), and one Rh(2) atom.