data_V2InGa
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.18
_cell_length_b   9.18
_cell_length_c   9.18
_cell_angle_alpha   18.15
_cell_angle_beta   18.15
_cell_angle_gamma   18.15
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2InGa
_chemical_formula_sum   'V2 In1 Ga1'
_cell_volume   65.51
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.0  0.89  1.0
  V  V3  1  0.0  0.0  0.19  1.0
  In  In1  1  0.0  0.0  0.54  1.0
  Ga  Ga0  1  0.0  0.0  0.0  1.0

data_V2InGa
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.01
_cell_length_b   2.89
_cell_length_c   9.18
_cell_angle_alpha   90.0
_cell_angle_beta   100.49
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   V2InGa
_chemical_formula_sum   'V4 In2 Ga2'
_cell_volume   131.02
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.11  1.0
  V  V1  2  0.0  0.0  0.81  1.0
  In  In2  2  0.0  0.0  0.46  1.0
  Ga  Ga3  2  0.0  0.0  0.0  1.0

V V In Ga
V2InGa crystallizes in the monoclinic Cm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a single-bond geometry to one In(1) and one Ga(1) atom. The V(1)-In(1) bond length is 3.18 Å. The V(1)-Ga(1) bond length is 1.05 Å. In the second V site, V(2) is bonded in a single-bond geometry to one In(1) and one Ga(1) atom. The V(2)-In(1) bond length is 3.18 Å. The V(2)-Ga(1) bond length is 1.77 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded to one V(1); one V(2); and six In(1,1) atoms to form a mixture of corner and edge-sharing InV2In6 hexagonal bipyramids. All In(1)-In(1,1) bond lengths are 2.89 Å. In the second In site, In(1) is bonded to one V(1); one V(2); and six In(1,1) atoms to form a mixture of corner and edge-sharing InV2In6 hexagonal bipyramids. The In(1)-V(1) bond length is 3.18 Å. The In(1)-V(2) bond length is 3.18 Å. Both In(1)-In(1) bond lengths are 2.89 Å. Ga(1) is bonded in a distorted linear geometry to one V(1) and one V(2) atom.