data_CdGaW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.88
_cell_length_b   4.88
_cell_length_c   4.88
_cell_angle_alpha   129.78
_cell_angle_beta   129.78
_cell_angle_gamma   73.76
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdGaW2
_chemical_formula_sum   'Cd1 Ga1 W2'
_cell_volume   67.12
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.07  0.95  1.0
  Ga  Ga1  1  0.0  0.0  0.0  1.0
  W  W2  1  0.07  0.0  0.95  1.0
  W  W3  1  0.0  0.0  0.91  1.0

data_CdGaW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.14
_cell_length_b   4.14
_cell_length_c   4.88
_cell_angle_alpha   115.11
_cell_angle_beta   115.11
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdGaW2
_chemical_formula_sum   'Cd1 Ga1 W2'
_cell_volume   67.12
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.88  0.95  0.88  1.0
  Ga  Ga1  1  0.0  0.0  0.0  1.0
  W  W2  1  0.91  0.91  0.91  1.0
  W  W3  1  0.95  0.88  0.88  1.0

Cd Ga W W
W2CdGa is Copper structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one W2CdGa cluster. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 3-coordinate geometry to one W(2), one Cd(1), and one Ga(1) atom. The W(1)-W(2) bond length is 0.27 Å. The W(1)-Cd(1) bond length is 0.42 Å. The W(1)-Ga(1) bond length is 0.53 Å. In the second W site, W(2) is bonded in a distorted single-bond geometry to one W(1), one Cd(1), and one Ga(1) atom. The W(2)-Cd(1) bond length is 0.27 Å. The W(2)-Ga(1) bond length is 0.46 Å. Cd(1) is bonded in a single-bond geometry to one W(1), one W(2), and one Ga(1) atom. The Cd(1)-Ga(1) bond length is 0.53 Å. Ga(1) is bonded in a 3-coordinate geometry to one W(1), one W(2), and one Cd(1) atom.