data_V2CdAg
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.74
_cell_length_b   2.74
_cell_length_c   8.71
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   93.28
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2CdAg
_chemical_formula_sum   'V2 Cd1 Ag1'
_cell_volume   65.37
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.88  0.0  0.61  1.0
  V  V3  1  0.88  0.0  0.1  1.0
  Cd  Cd1  1  0.0  0.0  0.35  1.0
  Ag  Ag0  1  0.0  0.0  0.0  1.0

data_V2CdAg
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.74
_cell_length_b   2.74
_cell_length_c   8.71
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   93.28
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2CdAg
_chemical_formula_sum   'V2 Cd1 Ag1'
_cell_volume   65.37
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.88  0.0  0.1  1.0
  V  V1  1  0.88  0.0  0.61  1.0
  Cd  Cd2  1  0.0  0.0  0.35  1.0
  Ag  Ag3  1  0.0  0.0  0.0  1.0

V V Cd Ag
V2AgCd crystallizes in the triclinic P1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to four equivalent V(1), one Ag(1), and one Cd(1) atom. All V(1)-V(1) bond lengths are 2.74 Å. The V(1)-Ag(1) bond length is 3.41 Å. The V(1)-Cd(1) bond length is 2.25 Å. In the second V site, V(2) is bonded in a single-bond geometry to one Ag(1) and one Cd(1) atom. The V(2)-Ag(1) bond length is 0.92 Å. The V(2)-Cd(1) bond length is 2.25 Å. Ag(1) is bonded in a single-bond geometry to one V(1) and one V(2) atom. Cd(1) is bonded in a 2-coordinate geometry to one V(1) and one V(2) atom.