data_Ga2POs
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.9
_cell_length_b   2.9
_cell_length_c   7.41
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ga2POs
_chemical_formula_sum   'Ga2 P1 Os1'
_cell_volume   62.29
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.45  0.45  0.04  1.0
  Ga  Ga1  1  0.45  0.45  0.37  1.0
  P  P3  1  0.0  0.0  0.0  1.0
  Os  Os2  1  0.0  0.0  0.7  1.0

data_Ga2POs
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.1
_cell_length_b   4.1
_cell_length_c   7.41
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Ga2POs
_chemical_formula_sum   'Ga4 P2 Os2'
_cell_volume   124.58
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  2  0.45  0.0  0.04  1.0
  Ga  Ga1  2  0.45  0.0  0.37  1.0
  P  P2  2  0.0  0.0  0.0  1.0
  Os  Os3  2  0.0  0.0  0.7  1.0

Ga Ga P Os
OsGa2P crystallizes in the monoclinic Cm space group. Os(1) is bonded in a 1-coordinate geometry to four equivalent Ga(2) and one P(1) atom. There are a spread of Os(1)-Ga(2) bond distances ranging from 3.08-3.34 Å. The Os(1)-P(1) bond length is 2.20 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 4-coordinate geometry to one Ga(2) and four equivalent P(1) atoms. The Ga(1)-Ga(2) bond length is 2.47 Å. There are a spread of Ga(1)-P(1) bond distances ranging from 1.87-2.27 Å. In the second Ga site, Ga(2) is bonded in a 9-coordinate geometry to four equivalent Os(1), one Ga(1), and four equivalent Ga(2) atoms. All Ga(2)-Ga(2) bond lengths are 2.90 Å. P(1) is bonded to one Os(1) and four equivalent Ga(1) atoms to form a mixture of distorted corner and edge-sharing PGa4Os square pyramids.