data_MoPt2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.01
_cell_length_b   5.01
_cell_length_c   5.01
_cell_angle_alpha   133.58
_cell_angle_beta   133.58
_cell_angle_gamma   67.75
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MoPt2Cl
_chemical_formula_sum   'Mo1 Pt2 Cl1'
_cell_volume   64.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo1  1  0.0  0.0  0.16  1.0
  Pt  Pt2  1  0.0  0.98  0.08  1.0
  Pt  Pt3  1  0.98  0.0  0.08  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_MoPt2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.59
_cell_length_b   5.59
_cell_length_c   5.01
_cell_angle_alpha   90.0
_cell_angle_beta   123.87
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   MoPt2Cl
_chemical_formula_sum   'Mo2 Pt4 Cl2'
_cell_volume   129.87
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  2  0.34  0.5  0.84  1.0
  Pt  Pt1  4  0.41  0.49  0.89  1.0
  Cl  Cl2  2  0.0  0.0  0.0  1.0

Mo Pt Pt Cl
MoPt2Cl is Indium-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two MoPt2Cl clusters. Mo(1) is bonded in a 2-coordinate geometry to two equivalent Pt(1) atoms. Both Mo(1)-Pt(1) bond lengths are 0.33 Å. Pt(1) is bonded in a single-bond geometry to one Mo(1), one Pt(1), and one Cl(1) atom. The Pt(1)-Pt(1) bond length is 0.14 Å. The Pt(1)-Cl(1) bond length is 0.50 Å. Cl(1) is bonded in a 2-coordinate geometry to two equivalent Pt(1) atoms.