data_Cu2RhCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.95
_cell_length_b   2.97
_cell_length_c   7.04
_cell_angle_alpha   90.0
_cell_angle_beta   90.96
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cu2RhCl
_chemical_formula_sum   'Cu2 Rh1 Cl1'
_cell_volume   61.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu1  1  0.89  0.49  0.91  1.0
  Cu  Cu2  1  0.94  0.49  0.12  1.0
  Rh  Rh3  1  0.42  0.0  0.52  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Cu2RhCl
_symmetry_space_group_name_H-M   Pm
_cell_length_a   2.95
_cell_length_b   2.97
_cell_length_c   7.04
_cell_angle_alpha   90.0
_cell_angle_beta   90.96
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   Cu2RhCl
_chemical_formula_sum   'Cu2 Rh1 Cl1'
_cell_volume   61.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.89  0.5  0.91  1.0
  Cu  Cu1  1  0.94  0.5  0.12  1.0
  Rh  Rh2  1  0.42  0.0  0.52  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Cu Cu Rh Cl
RhCu2Cl crystallizes in the triclinic P1 space group. Rh(1) is bonded in a 12-coordinate geometry to four equivalent Rh(1), four equivalent Cu(1), and four equivalent Cu(2) atoms. There are two shorter (2.95 Å) and two longer (2.97 Å) Rh(1)-Rh(1) bond lengths. There are a spread of Rh(1)-Cu(1) bond distances ranging from 3.40-3.54 Å. There are a spread of Rh(1)-Cu(2) bond distances ranging from 3.40-3.54 Å. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 2-coordinate geometry to four equivalent Rh(1), one Cu(2), and two equivalent Cl(1) atoms. The Cu(1)-Cu(2) bond length is 1.51 Å. There is one shorter (1.60 Å) and one longer (1.68 Å) Cu(1)-Cl(1) bond length. In the second Cu site, Cu(2) is bonded in a 3-coordinate geometry to four equivalent Rh(1), one Cu(1), and two equivalent Cl(1) atoms. There is one shorter (1.70 Å) and one longer (1.77 Å) Cu(2)-Cl(1) bond length. Cl(1) is bonded in a 4-coordinate geometry to two equivalent Cu(1) and two equivalent Cu(2) atoms.