data_BaRhW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.96
_cell_length_b   2.96
_cell_length_c   9.38
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   102.44
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaRhW2
_chemical_formula_sum   'Ba1 Rh1 W2'
_cell_volume   80.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.86  0.0  0.58  1.0
  Rh  Rh1  1  0.0  0.0  0.87  1.0
  W  W2  1  0.86  0.0  0.1  1.0
  W  W3  1  0.0  0.0  0.52  1.0

data_BaRhW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.96
_cell_length_b   2.96
_cell_length_c   9.38
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   102.44
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaRhW2
_chemical_formula_sum   'Ba1 Rh1 W2'
_cell_volume   80.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.86  0.0  0.58  1.0
  Rh  Rh1  1  0.0  0.0  0.87  1.0
  W  W2  1  0.0  0.0  0.52  1.0
  W  W3  1  0.86  0.0  0.1  1.0

Ba Rh W W
BaW2Rh crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one BaW2Rh cluster. Ba(1) is bonded in a single-bond geometry to one W(2) and one Rh(1) atom. The Ba(1)-W(2) bond length is 0.73 Å. The Ba(1)-Rh(1) bond length is 2.78 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted single-bond geometry to one Rh(1) atom. The W(1)-Rh(1) bond length is 2.21 Å. In the second W site, W(2) is bonded in a single-bond geometry to one Ba(1) atom. Rh(1) is bonded in a distorted bent 150 degrees geometry to one Ba(1) and one W(1) atom.