data_Be2ZnAs
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.57
_cell_length_b   4.57
_cell_length_c   4.57
_cell_angle_alpha   131.41
_cell_angle_beta   131.41
_cell_angle_gamma   71.17
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Be2ZnAs
_chemical_formula_sum   'Be2 Zn1 As1'
_cell_volume   52.52
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Be  Be1  1  0.0  0.88  0.86  1.0
  Be  Be2  1  0.88  0.0  0.86  1.0
  Zn  Zn3  1  0.0  0.0  0.0  1.0
  As  As0  1  0.0  0.0  0.72  1.0

data_Be2ZnAs
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.32
_cell_length_b   5.32
_cell_length_c   4.57
_cell_angle_alpha   90.0
_cell_angle_beta   125.58
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Be2ZnAs
_chemical_formula_sum   'Be4 Zn2 As2'
_cell_volume   105.05
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Be  Be0  4  0.06  0.06  0.98  1.0
  Zn  Zn1  2  0.0  0.0  0.0  1.0
  As  As2  2  0.0  0.0  0.72  1.0

Be Be Zn As
Be2ZnAs is Indium-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Be2ZnAs clusters. Be(1) is bonded in a 3-coordinate geometry to one Be(1), one Zn(1), and one As(1) atom. The Be(1)-Be(1) bond length is 0.64 Å. The Be(1)-Zn(1) bond length is 0.50 Å. The Be(1)-As(1) bond length is 1.09 Å. Zn(1) is bonded in a distorted L-shaped geometry to two equivalent Be(1) atoms. As(1) is bonded in a 2-coordinate geometry to two equivalent Be(1) atoms.