data_ZrPb2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.72
_cell_length_b   5.72
_cell_length_c   5.72
_cell_angle_alpha   131.43
_cell_angle_beta   131.43
_cell_angle_gamma   71.13
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrPb2Cl
_chemical_formula_sum   'Zr1 Pb2 Cl1'
_cell_volume   103.07
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr3  1  0.0  0.35  0.33  1.0
  Pb  Pb1  1  0.35  0.0  0.33  1.0
  Pb  Pb2  1  0.0  0.0  0.65  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_ZrPb2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.71
_cell_length_b   4.71
_cell_length_c   5.72
_cell_angle_alpha   114.29
_cell_angle_beta   114.29
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrPb2Cl
_chemical_formula_sum   'Zr1 Pb2 Cl1'
_cell_volume   103.07
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.03  0.35  0.03  1.0
  Pb  Pb1  1  0.35  0.0  0.35  1.0
  Pb  Pb2  1  0.67  0.0  0.03  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Zr Pb Pb Cl
ZrPb2Cl is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ZrPb2Cl cluster. Zr(1) is bonded in a single-bond geometry to one Cl(1) atom. The Zr(1)-Cl(1) bond length is 1.61 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a single-bond geometry to one Cl(1) atom. The Pb(1)-Cl(1) bond length is 1.61 Å. In the second Pb site, Pb(2) is bonded in a distorted single-bond geometry to one Cl(1) atom. The Pb(2)-Cl(1) bond length is 1.98 Å. Cl(1) is bonded in a distorted trigonal non-coplanar geometry to one Zr(1), one Pb(1), and one Pb(2) atom.