data_MnTlTc
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.92
_cell_length_b   2.92
_cell_length_c   6.71
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnTlTc
_chemical_formula_sum   'Mn1 Tl1 Tc1'
_cell_volume   49.41
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.0  0.0  0.2  1.0
  Tl  Tl2  1  0.46  0.84  0.53  1.0
  Tc  Tc1  1  0.0  0.68  0.98  1.0

data_MnTlTc
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.92
_cell_length_b   2.92
_cell_length_c   6.71
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnTlTc
_chemical_formula_sum   'Mn1 Tl1 Tc1'
_cell_volume   49.41
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.0  0.0  0.2  1.0
  Tl  Tl1  1  0.46  0.84  0.53  1.0
  Tc  Tc2  1  0.0  0.68  0.98  1.0

Mn Tl Tc
TcMnTl crystallizes in the triclinic P1 space group. Tc(1) is bonded in a distorted single-bond geometry to one Mn(1) and two equivalent Tl(1) atoms. The Tc(1)-Mn(1) bond length is 1.73 Å. There is one shorter (3.22 Å) and one longer (3.53 Å) Tc(1)-Tl(1) bond length. Mn(1) is bonded in a distorted single-bond geometry to one Tc(1) and three equivalent Tl(1) atoms. There are a spread of Mn(1)-Tl(1) bond distances ranging from 2.65-3.10 Å. Tl(1) is bonded in a 11-coordinate geometry to two equivalent Tc(1), three equivalent Mn(1), and six equivalent Tl(1) atoms. All Tl(1)-Tl(1) bond lengths are 2.92 Å.