data_SrLi2V
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.5
_cell_length_b   10.5
_cell_length_c   10.5
_cell_angle_alpha   17.45
_cell_angle_beta   17.45
_cell_angle_gamma   17.45
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SrLi2V
_chemical_formula_sum   'Sr1 Li2 V1'
_cell_volume   90.78
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr2  1  0.0  0.0  0.51  1.0
  Li  Li0  1  0.0  0.0  0.87  1.0
  Li  Li1  1  0.0  0.0  0.14  1.0
  V  V3  1  0.0  0.0  0.0  1.0

data_SrLi2V
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.52
_cell_length_b   3.18
_cell_length_c   10.5
_cell_angle_alpha   90.0
_cell_angle_beta   100.09
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   SrLi2V
_chemical_formula_sum   'Sr2 Li4 V2'
_cell_volume   181.56
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  2  0.0  0.0  0.49  1.0
  Li  Li1  2  0.0  0.0  0.13  1.0
  Li  Li2  2  0.0  0.0  0.86  1.0
  V  V3  2  0.0  0.0  0.0  1.0

Sr Li Li V
Li2SrV crystallizes in the monoclinic Cm space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a single-bond geometry to one Sr(1) and one V(1) atom. The Li(1)-Sr(1) bond length is 3.85 Å. The Li(1)-V(1) bond length is 1.35 Å. In the second Li site, Li(2) is bonded in a single-bond geometry to one Sr(1) and one V(1) atom. The Li(2)-Sr(1) bond length is 3.85 Å. The Li(2)-V(1) bond length is 1.46 Å. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one Li(1); one Li(2); and six Sr(1,1) atoms to form a mixture of edge and corner-sharing SrSr6Li2 hexagonal bipyramids. All Sr(1)-Sr(1,1) bond lengths are 3.18 Å. In the second Sr site, Sr(1) is bonded to one Li(1); one Li(2); and six Sr(1,1) atoms to form a mixture of edge and corner-sharing SrSr6Li2 hexagonal bipyramids. The Sr(1)-Li(1) bond length is 3.85 Å. The Sr(1)-Li(2) bond length is 3.85 Å. Both Sr(1)-Sr(1) bond lengths are 3.18 Å. V(1) is bonded in a linear geometry to one Li(1) and one Li(2) atom.