data_VBMo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.45
_cell_length_b   3.76
_cell_length_c   3.99
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VBMo2
_chemical_formula_sum   'V1 B1 Mo2'
_cell_volume   51.65
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.73  0.0  0.99  1.0
  B  B0  1  0.0  0.0  0.0  1.0
  Mo  Mo1  1  0.0  0.88  0.99  1.0
  Mo  Mo2  1  0.73  0.88  0.0  1.0

data_VBMo2
_symmetry_space_group_name_H-M   Pm
_cell_length_a   3.45
_cell_length_b   3.99
_cell_length_c   3.76
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   VBMo2
_chemical_formula_sum   'V1 B1 Mo2'
_cell_volume   51.65
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.73  0.0  0.0  1.0
  B  B1  1  0.0  0.0  0.0  1.0
  Mo  Mo2  1  -0.0  0.0  0.88  1.0
  Mo  Mo3  1  0.73  0.0  0.88  1.0

V B Mo Mo
VMo2B is alpha Po structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VMo2B cluster. V(1) is bonded in a distorted single-bond geometry to one Mo(2) and one B(1) atom. The V(1)-Mo(2) bond length is 0.46 Å. The V(1)-B(1) bond length is 0.95 Å. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a single-bond geometry to one B(1) atom. The Mo(1)-B(1) bond length is 0.46 Å. In the second Mo site, Mo(2) is bonded in a single-bond geometry to one V(1) atom. B(1) is bonded in a distorted L-shaped geometry to one V(1) and one Mo(1) atom.