data_KLiAu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.36
_cell_length_b   5.36
_cell_length_c   3.33
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KLiAu2
_chemical_formula_sum   'K1 Li1 Au2'
_cell_volume   95.79
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K2  1  0.68  0.68  0.0  1.0
  Li  Li3  1  0.0  0.0  0.0  1.0
  Au  Au0  1  0.0  0.68  0.66  1.0
  Au  Au1  1  0.68  0.0  0.66  1.0

data_KLiAu2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   7.59
_cell_length_b   7.59
_cell_length_c   3.33
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   KLiAu2
_chemical_formula_sum   'K2 Li2 Au4'
_cell_volume   191.57
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  2  0.18  0.5  0.0  1.0
  Li  Li1  2  0.0  0.0  0.0  1.0
  Au  Au2  4  0.34  0.34  0.66  1.0

K Li Au Au
KLiAu2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two KLiAu2 clusters. K(1) is bonded in a 2-coordinate geometry to two equivalent Au(1) atoms. Both K(1)-Au(1) bond lengths are 2.04 Å. Li(1) is bonded in a 2-coordinate geometry to two equivalent Au(1) atoms. Both Li(1)-Au(1) bond lengths are 2.04 Å. Au(1) is bonded in a 2-coordinate geometry to one K(1) and one Li(1) atom.