data_CdTcPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.8
_cell_length_b   4.8
_cell_length_c   5.14
_cell_angle_alpha   97.0
_cell_angle_beta   97.0
_cell_angle_gamma   33.5
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdTcPd2
_chemical_formula_sum   'Cd1 Tc1 Pd2'
_cell_volume   64.83
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.27  0.0  0.55  1.0
  Tc  Tc3  1  0.0  0.0  0.0  1.0
  Pd  Pd1  1  0.83  0.0  0.91  1.0
  Pd  Pd2  1  0.71  0.0  0.19  1.0

data_CdTcPd2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.77
_cell_length_b   4.8
_cell_length_c   5.14
_cell_angle_alpha   97.0
_cell_angle_beta   90.0
_cell_angle_gamma   106.75
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdTcPd2
_chemical_formula_sum   'Cd1 Tc1 Pd2'
_cell_volume   64.83
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.73  0.45  1.0
  Tc  Tc1  1  0.0  0.0  0.0  1.0
  Pd  Pd2  1  0.0  0.17  0.09  1.0
  Pd  Pd3  1  0.0  0.29  0.81  1.0

Cd Tc Pd Pd
TcPd2Cd crystallizes in the triclinic P1 space group. Tc(1) is bonded in a single-bond geometry to one Pd(1), one Pd(2), and two equivalent Cd(1) atoms. The Tc(1)-Pd(1) bond length is 0.88 Å. The Tc(1)-Pd(2) bond length is 1.80 Å. There is one shorter (2.79 Å) and one longer (2.96 Å) Tc(1)-Cd(1) bond length. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a single-bond geometry to one Tc(1), one Pd(2), and two equivalent Cd(1) atoms. The Pd(1)-Pd(2) bond length is 1.59 Å. There is one shorter (2.98 Å) and one longer (3.09 Å) Pd(1)-Cd(1) bond length. In the second Pd site, Pd(2) is bonded in a 3-coordinate geometry to one Tc(1), one Pd(1), and two equivalent Cd(1) atoms. There is one shorter (2.98 Å) and one longer (3.09 Å) Pd(2)-Cd(1) bond length. Cd(1) is bonded in a 8-coordinate geometry to two equivalent Tc(1), two equivalent Pd(1), two equivalent Pd(2), and two equivalent Cd(1) atoms. Both Cd(1)-Cd(1) bond lengths are 2.77 Å.