data_CdMo2Os
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.68
_cell_length_b   9.68
_cell_length_c   9.68
_cell_angle_alpha   16.74
_cell_angle_beta   16.74
_cell_angle_gamma   16.74
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdMo2Os
_chemical_formula_sum   'Cd1 Mo2 Os1'
_cell_volume   65.74
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.0  0.0  1.0
  Mo  Mo1  1  0.0  0.0  0.98  1.0
  Mo  Mo2  1  0.0  0.0  0.66  1.0
  Os  Os3  1  0.0  0.0  0.32  1.0

data_CdMo2Os
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.88
_cell_length_b   2.82
_cell_length_c   9.68
_cell_angle_alpha   90.0
_cell_angle_beta   99.68
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   CdMo2Os
_chemical_formula_sum   'Cd2 Mo4 Os2'
_cell_volume   131.48
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  2  0.0  0.0  0.0  1.0
  Mo  Mo1  2  0.0  0.0  0.02  1.0
  Mo  Mo2  2  0.0  0.0  0.34  1.0
  Os  Os3  2  0.0  0.0  0.68  1.0

Cd Mo Mo Os
Mo2OsCd crystallizes in the monoclinic Cm space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a single-bond geometry to one Mo(2) and one Cd(1) atom. The Mo(1)-Mo(2) bond length is 3.10 Å. The Mo(1)-Cd(1) bond length is 0.19 Å. In the second Mo site, Mo(2) is bonded to one Mo(1), six equivalent Mo(2), and one Os(1) atom to form MoMo7Os hexagonal bipyramids that share corners with six equivalent Mo(2)Mo7Os hexagonal bipyramids, edges with six equivalent Os(1)CdMoOs6 hexagonal bipyramids, and edges with twelve equivalent Mo(2)Mo7Os hexagonal bipyramids. All Mo(2)-Mo(2) bond lengths are 2.82 Å. The Mo(2)-Os(1) bond length is 3.29 Å. Os(1) is bonded to one Mo(2), six equivalent Os(1), and one Cd(1) atom to form distorted OsCdMoOs6 hexagonal bipyramids that share corners with six equivalent Os(1)CdMoOs6 hexagonal bipyramids, edges with six equivalent Mo(2)Mo7Os hexagonal bipyramids, and edges with twelve equivalent Os(1)CdMoOs6 hexagonal bipyramids. All Os(1)-Os(1) bond lengths are 2.82 Å. The Os(1)-Cd(1) bond length is 3.10 Å. Cd(1) is bonded in a single-bond geometry to one Mo(1) and one Os(1) atom.