data_CdPdCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.63
_cell_length_b   4.63
_cell_length_c   4.63
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdPdCl
_chemical_formula_sum   'Cd1 Pd1 Cl1'
_cell_volume   70.08
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.64  0.64  0.64  1.0
  Pd  Pd2  1  0.27  0.27  0.27  1.0
  Cl  Cl1  1  0.0  0.0  0.0  1.0

data_CdPdCl
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.63
_cell_length_b   4.63
_cell_length_c   11.34
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   CdPdCl
_chemical_formula_sum   'Cd3 Pd3 Cl3'
_cell_volume   210.23
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  3  0.0  0.0  0.36  1.0
  Pd  Pd1  3  0.0  0.0  0.73  1.0
  Cl  Cl2  3  0.0  0.0  0.0  1.0

Cd Pd Cl
PdCdCl crystallizes in the trigonal R3m space group. Pd(1) is bonded to three equivalent Cd(1) and four equivalent Cl(1) atoms to form PdCd3Cl4 hexagonal pyramids that share corners with three equivalent Cl(1)Cd3Pd4 hexagonal pyramids, corners with six equivalent Pd(1)Cd3Cl4 hexagonal pyramids, edges with three equivalent Cl(1)Cd3Pd4 hexagonal pyramids, and edges with six equivalent Pd(1)Cd3Cl4 hexagonal pyramids. All Pd(1)-Cd(1) bond lengths are 2.69 Å. There are three shorter (2.76 Å) and one longer (3.09 Å) Pd(1)-Cl(1) bond length. Cd(1) is bonded in a hexagonal planar geometry to three equivalent Pd(1) and three equivalent Cl(1) atoms. All Cd(1)-Cl(1) bond lengths are 2.69 Å. Cl(1) is bonded to four equivalent Pd(1) and three equivalent Cd(1) atoms to form distorted ClCd3Pd4 hexagonal pyramids that share corners with three equivalent Pd(1)Cd3Cl4 hexagonal pyramids, corners with six equivalent Cl(1)Cd3Pd4 hexagonal pyramids, edges with three equivalent Pd(1)Cd3Cl4 hexagonal pyramids, and edges with six equivalent Cl(1)Cd3Pd4 hexagonal pyramids.