data_Cd3Re5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.41
_cell_length_b   8.41
_cell_length_c   4.77
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd3Re5
_chemical_formula_sum   'Cd6 Re10'
_cell_volume   291.76
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.34  0.87  0.58  1.0
  Cd  Cd1  1  0.45  0.41  0.19  1.0
  Cd  Cd2  1  0.31  0.0  0.58  1.0
  Cd  Cd3  1  0.66  0.87  0.19  1.0
  Cd  Cd4  1  0.09  0.0  0.19  1.0
  Cd  Cd5  1  0.55  0.41  0.58  1.0
  Re  Re6  1  0.26  0.28  0.19  1.0
  Re  Re7  1  0.54  1.0  0.58  1.0
  Re  Re8  1  0.48  0.0  0.19  1.0
  Re  Re9  1  0.74  0.28  0.58  1.0
  Re  Re10  1  0.0  0.85  0.0  1.0
  Re  Re11  1  0.0  0.85  0.38  1.0
  Re  Re12  1  0.2  0.43  0.0  1.0
  Re  Re13  1  0.2  0.43  0.38  1.0
  Re  Re14  1  0.93  0.0  0.58  1.0
  Re  Re15  1  0.46  1.0  0.19  1.0

data_Cd3Re5
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.77
_cell_length_b   8.41
_cell_length_c   8.41
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd3Re5
_chemical_formula_sum   'Cd6 Re10'
_cell_volume   291.76
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.19  0.09  0.0  1.0
  Cd  Cd1  1  0.19  0.45  0.41  1.0
  Cd  Cd2  1  0.19  0.66  0.87  1.0
  Cd  Cd3  1  0.58  0.31  0.0  1.0
  Cd  Cd4  1  0.58  0.34  0.87  1.0
  Cd  Cd5  1  0.58  0.55  0.41  1.0
  Re  Re6  1  0.0  0.0  0.85  1.0
  Re  Re7  1  0.0  0.2  0.43  1.0
  Re  Re8  1  0.19  0.26  0.28  1.0
  Re  Re9  1  0.19  0.46  1.0  1.0
  Re  Re10  1  0.19  0.48  0.0  1.0
  Re  Re11  1  0.38  0.0  0.85  1.0
  Re  Re12  1  0.38  0.2  0.43  1.0
  Re  Re13  1  0.58  0.54  1.0  1.0
  Re  Re14  1  0.58  0.74  0.28  1.0
  Re  Re15  1  0.58  0.93  0.0  1.0

Cd Cd Cd Cd Cd Cd Re Re Re Re Re Re Re Re Re Re
Re5Cd3 crystallizes in the triclinic P1 space group. There are ten inequivalent Re sites. In the first Re site, Re(1) is bonded in a 4-coordinate geometry to one Re(7), one Re(8), one Cd(2), and one Cd(5) atom. The Re(1)-Re(7) bond length is 1.78 Å. The Re(1)-Re(8) bond length is 1.78 Å. The Re(1)-Cd(2) bond length is 1.44 Å. The Re(1)-Cd(5) bond length is 2.06 Å. In the second Re site, Re(2) is bonded in a distorted single-bond geometry to one Re(4), one Cd(1), and one Cd(4) atom. The Re(2)-Re(4) bond length is 2.12 Å. The Re(2)-Cd(1) bond length is 1.44 Å. The Re(2)-Cd(4) bond length is 2.57 Å. In the third Re site, Re(3) is bonded in a distorted single-bond geometry to one Re(10) and one Cd(4) atom. The Re(3)-Re(10) bond length is 0.13 Å. The Re(3)-Cd(4) bond length is 2.25 Å. In the fourth Re site, Re(4) is bonded in a distorted water-like geometry to one Re(2), one Re(8), and one Cd(6) atom. The Re(4)-Re(8) bond length is 3.57 Å. The Re(4)-Cd(6) bond length is 2.36 Å. In the fifth Re site, Re(5) is bonded in a single-bond geometry to one Re(9) and one Cd(5) atom. The Re(5)-Re(9) bond length is 2.60 Å. The Re(5)-Cd(5) bond length is 1.42 Å. In the sixth Re site, Re(6) is bonded in a distorted single-bond geometry to one Re(9) and one Cd(5) atom. The Re(6)-Re(9) bond length is 1.87 Å. The Re(6)-Cd(5) bond length is 1.42 Å. In the seventh Re site, Re(7) is bonded in a 4-coordinate geometry to one Re(1), two equivalent Re(8), and one Cd(2) atom. There is one shorter (1.83 Å) and one longer (2.94 Å) Re(7)-Re(8) bond length. The Re(7)-Cd(2) bond length is 2.38 Å. In the eighth Re site, Re(8) is bonded in a 8-coordinate geometry to one Re(1), one Re(4), one Re(9), two equivalent Re(7), one Cd(1), one Cd(2), and one Cd(6) atom. The Re(8)-Re(9) bond length is 3.28 Å. The Re(8)-Cd(1) bond length is 3.43 Å. The Re(8)-Cd(2) bond length is 2.38 Å. The Re(8)-Cd(6) bond length is 3.10 Å. In the ninth Re site, Re(9) is bonded in a 4-coordinate geometry to one Re(5), one Re(6), one Re(8), one Cd(4), and one Cd(5) atom. The Re(9)-Cd(4) bond length is 2.68 Å. The Re(9)-Cd(5) bond length is 2.29 Å. In the tenth Re site, Re(10) is bonded in a single-bond geometry to one Re(3) atom. There are six inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted L-shaped geometry to one Re(2), one Re(8), and one Cd(3) atom. The Cd(1)-Cd(3) bond length is 1.22 Å. In the second Cd site, Cd(2) is bonded in a distorted single-bond geometry to one Re(1), one Re(7), one Re(8), and one Cd(6) atom. The Cd(2)-Cd(6) bond length is 1.98 Å. In the third Cd site, Cd(3) is bonded in a distorted single-bond geometry to one Cd(1) atom. In the fourth Cd site, Cd(4) is bonded in a 3-coordinate geometry to one Re(2), one Re(3), and one Re(9) atom. In the fifth Cd site, Cd(5) is bonded in a 3-coordinate geometry to one Re(1), one Re(5), one Re(6), and one Re(9) atom. In the sixth Cd site, Cd(6) is bonded in a distorted water-like geometry to one Re(4), one Re(8), and one Cd(2) atom.