data_InTcSn2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.14
_cell_length_b   5.14
_cell_length_c   5.24
_cell_angle_alpha   98.61
_cell_angle_beta   98.61
_cell_angle_gamma   38.49
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InTcSn2
_chemical_formula_sum   'In1 Tc1 Sn2'
_cell_volume   85.16
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.44  0.0  0.59  1.0
  Tc  Tc3  1  0.0  0.0  0.0  1.0
  Sn  Sn1  1  0.92  0.0  0.14  1.0
  Sn  Sn2  1  0.97  0.0  0.03  1.0

data_InTcSn2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.39
_cell_length_b   5.14
_cell_length_c   5.24
_cell_angle_alpha   98.61
_cell_angle_beta   90.0
_cell_angle_gamma   109.25
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InTcSn2
_chemical_formula_sum   'In1 Tc1 Sn2'
_cell_volume   85.16
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.0  0.56  0.41  1.0
  Tc  Tc1  1  0.0  0.0  0.0  1.0
  Sn  Sn2  1  0.0  0.03  0.97  1.0
  Sn  Sn3  1  0.0  0.08  0.86  1.0

In Tc Sn Sn
TcInSn2 crystallizes in the triclinic P1 space group. Tc(1) is bonded in a single-bond geometry to one In(1) and one Sn(2) atom. The Tc(1)-In(1) bond length is 3.37 Å. The Tc(1)-Sn(2) bond length is 0.24 Å. In(1) is bonded in a 5-coordinate geometry to one Tc(1), two equivalent In(1), one Sn(1), and one Sn(2) atom. Both In(1)-In(1) bond lengths are 3.39 Å. The In(1)-Sn(1) bond length is 3.28 Å. The In(1)-Sn(2) bond length is 3.28 Å. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a single-bond geometry to one In(1) and one Sn(2) atom. The Sn(1)-Sn(2) bond length is 0.70 Å. In the second Sn site, Sn(2) is bonded in a distorted bent 150 degrees geometry to one Tc(1), one In(1), and one Sn(1) atom.