data_TlTcRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.83
_cell_length_b   4.83
_cell_length_c   2.88
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   107.04
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlTcRh2
_chemical_formula_sum   'Tl1 Tc1 Rh2'
_cell_volume   64.3
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl3  1  0.87  0.0  0.0  1.0
  Tc  Tc2  1  0.0  0.0  0.0  1.0
  Rh  Rh0  1  0.44  0.94  0.44  1.0
  Rh  Rh1  1  0.44  0.06  0.44  1.0

data_TlTcRh2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.88
_cell_length_b   4.83
_cell_length_c   4.83
_cell_angle_alpha   107.04
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlTcRh2
_chemical_formula_sum   'Tl1 Tc1 Rh2'
_cell_volume   64.3
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  -0.0  0.87  0.0  1.0
  Tc  Tc1  1  0.0  0.0  0.0  1.0
  Rh  Rh2  1  0.44  0.44  0.06  1.0
  Rh  Rh3  1  0.44  0.44  0.94  1.0

Tl Tc Rh Rh
(Rh)2TcTl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Rh cluster and one TcTl cluster. In the Rh cluster, there are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a single-bond geometry to one Rh(2) atom. The Rh(1)-Rh(2) bond length is 0.56 Å. In the second Rh site, Rh(2) is bonded in a single-bond geometry to one Rh(1) atom. In the TcTl cluster, Tc(1) is bonded in a single-bond geometry to one Tl(1) atom. The Tc(1)-Tl(1) bond length is 0.62 Å. Tl(1) is bonded in a single-bond geometry to one Tc(1) atom.