data_VCr2Te
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.02
_cell_length_b   3.02
_cell_length_c   6.52
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   95.5
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCr2Te
_chemical_formula_sum   'V1 Cr2 Te1'
_cell_volume   59.18
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.38  1.0
  Cr  Cr0  1  0.03  0.0  0.44  1.0
  Cr  Cr1  1  0.0  0.0  0.15  1.0
  Te  Te2  1  0.03  0.0  0.32  1.0

data_VCr2Te
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.02
_cell_length_b   3.02
_cell_length_c   6.52
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   95.5
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCr2Te
_chemical_formula_sum   'V1 Cr2 Te1'
_cell_volume   59.18
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.38  1.0
  Cr  Cr1  1  0.0  0.0  0.15  1.0
  Cr  Cr2  1  0.03  0.0  0.44  1.0
  Te  Te3  1  0.03  0.0  0.32  1.0

V Cr Cr Te
VCr2Te crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VCr2Te cluster. V(1) is bonded in a bent 150 degrees geometry to one Cr(1) and one Te(1) atom. The V(1)-Cr(1) bond length is 0.38 Å. The V(1)-Te(1) bond length is 0.41 Å. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a single-bond geometry to one V(1) atom. In the second Cr site, Cr(2) is bonded in a single-bond geometry to one Te(1) atom. The Cr(2)-Te(1) bond length is 1.11 Å. Te(1) is bonded in a 2-coordinate geometry to one V(1) and one Cr(2) atom.