data_ZnCo2Re
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.4
_cell_length_b   4.4
_cell_length_c   2.63
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   104.45
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnCo2Re
_chemical_formula_sum   'Zn1 Co2 Re1'
_cell_volume   49.43
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.0  0.0  1.0
  Co  Co0  1  0.35  0.74  0.32  1.0
  Co  Co1  1  0.35  0.26  0.32  1.0
  Re  Re2  1  0.7  0.0  0.0  1.0

data_ZnCo2Re
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.63
_cell_length_b   4.4
_cell_length_c   4.4
_cell_angle_alpha   104.45
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnCo2Re
_chemical_formula_sum   'Zn1 Co2 Re1'
_cell_volume   49.43
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.0  0.0  0.0  1.0
  Co  Co1  1  0.32  0.35  0.26  1.0
  Co  Co2  1  0.32  0.35  0.74  1.0
  Re  Re3  1  0.0  0.7  0.0  1.0

Zn Co Co Re
ReCo2Zn crystallizes in the triclinic P1 space group. Re(1) is bonded in a distorted single-bond geometry to two equivalent Co(1) and one Zn(1) atom. There is one shorter (1.87 Å) and one longer (2.46 Å) Re(1)-Co(1) bond length. The Re(1)-Zn(1) bond length is 1.33 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 8-coordinate geometry to two equivalent Re(1), two equivalent Co(1), two equivalent Co(2), and two equivalent Zn(1) atoms. Both Co(1)-Co(1) bond lengths are 2.63 Å. There is one shorter (2.12 Å) and one longer (2.29 Å) Co(1)-Co(2) bond length. There is one shorter (2.29 Å) and one longer (2.79 Å) Co(1)-Zn(1) bond length. In the second Co site, Co(2) is bonded in a distorted single-bond geometry to two equivalent Co(1) and one Zn(1) atom. The Co(2)-Zn(1) bond length is 1.87 Å. Zn(1) is bonded in a 2-coordinate geometry to one Re(1), one Co(2), and two equivalent Co(1) atoms.