data_Zr2SbRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.17
_cell_length_b   3.17
_cell_length_c   8.07
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zr2SbRh
_chemical_formula_sum   'Zr2 Sb1 Rh1'
_cell_volume   81.18
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr2  1  0.59  0.59  0.29  1.0
  Zr  Zr3  1  0.59  0.59  0.78  1.0
  Sb  Sb1  1  0.0  0.0  0.04  1.0
  Rh  Rh0  1  0.0  0.0  0.0  1.0

data_Zr2SbRh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.48
_cell_length_b   4.48
_cell_length_c   8.07
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Zr2SbRh
_chemical_formula_sum   'Zr4 Sb2 Rh2'
_cell_volume   162.35
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  2  0.09  0.5  0.29  1.0
  Zr  Zr1  2  0.09  0.5  0.78  1.0
  Sb  Sb2  2  0.0  0.0  0.04  1.0
  Rh  Rh3  2  0.0  0.0  0.0  1.0

Zr Zr Sb Rh
Zr2RhSb crystallizes in the monoclinic Cm space group. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 9-coordinate geometry to one Zr(2), four equivalent Zr(1), and four equivalent Sb(1) atoms. The Zr(1)-Zr(2) bond length is 3.95 Å. All Zr(1)-Zr(1) bond lengths are 3.17 Å. There are a spread of Zr(1)-Sb(1) bond distances ranging from 2.78-3.34 Å. In the second Zr site, Zr(2) is bonded in a 4-coordinate geometry to one Zr(1) and four equivalent Rh(1) atoms. There are a spread of Zr(2)-Rh(1) bond distances ranging from 2.56-3.16 Å. Rh(1) is bonded in a single-bond geometry to four equivalent Zr(2) and one Sb(1) atom. The Rh(1)-Sb(1) bond length is 0.30 Å. Sb(1) is bonded in a single-bond geometry to four equivalent Zr(1) and one Rh(1) atom.