data_BaInW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.36
_cell_length_b   5.12
_cell_length_c   6.57
_cell_angle_alpha   90.0
_cell_angle_beta   99.24
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaInW2
_chemical_formula_sum   'Ba1 In1 W2'
_cell_volume   111.37
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.15  0.0  0.24  1.0
  In  In1  1  0.0  0.0  0.0  1.0
  W  W2  1  0.53  0.56  0.89  1.0
  W  W3  1  0.77  0.56  0.6  1.0

data_BaInW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.36
_cell_length_b   5.12
_cell_length_c   6.57
_cell_angle_alpha   90.0
_cell_angle_beta   99.24
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaInW2
_chemical_formula_sum   'Ba1 In1 W2'
_cell_volume   111.37
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.15  0.0  0.24  1.0
  In  In1  1  0.0  0.0  0.0  1.0
  W  W2  1  0.53  0.56  0.89  1.0
  W  W3  1  0.77  0.56  0.6  1.0

Ba In W W
BaW2In crystallizes in the triclinic P1 space group. Ba(1) is bonded in a single-bond geometry to four equivalent W(2) and one In(1) atom. There are a spread of Ba(1)-W(2) bond distances ranging from 3.61-4.04 Å. The Ba(1)-In(1) bond length is 1.60 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 4-coordinate geometry to two equivalent W(2) and three equivalent In(1) atoms. There is one shorter (2.23 Å) and one longer (2.92 Å) W(1)-W(2) bond length. There are a spread of W(1)-In(1) bond distances ranging from 2.79-3.29 Å. In the second W site, W(2) is bonded in a 9-coordinate geometry to four equivalent Ba(1), two equivalent W(1), two equivalent W(2), and one In(1) atom. Both W(2)-W(2) bond lengths are 3.36 Å. The W(2)-In(1) bond length is 3.48 Å. In(1) is bonded in a distorted single-bond geometry to one Ba(1), one W(2), and three equivalent W(1) atoms.