data_AgAsPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.06
_cell_length_b   3.06
_cell_length_c   7.01
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   93.65
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgAsPd2
_chemical_formula_sum   'Ag1 As1 Pd2'
_cell_volume   65.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.0  0.0  0.5  1.0
  As  As1  1  0.0  0.0  0.0  1.0
  Pd  Pd2  1  0.1  0.0  0.57  1.0
  Pd  Pd3  1  0.1  0.0  0.44  1.0

data_AgAsPd2
_symmetry_space_group_name_H-M   Pm
_cell_length_a   3.06
_cell_length_b   7.01
_cell_length_c   3.06
_cell_angle_alpha   90.0
_cell_angle_beta   93.65
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   AgAsPd2
_chemical_formula_sum   'Ag1 As1 Pd2'
_cell_volume   65.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.0  0.0  0.0  1.0
  As  As1  1  0.0  0.5  0.0  1.0
  Pd  Pd2  2  0.1  0.07  0.0  1.0

Ag As Pd Pd
Pd2AgAs crystallizes in the triclinic P1 space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a single-bond geometry to one Ag(1) and one As(1) atom. The Pd(1)-Ag(1) bond length is 0.55 Å. The Pd(1)-As(1) bond length is 3.03 Å. In the second Pd site, Pd(2) is bonded in a single-bond geometry to one Ag(1) and one As(1) atom. The Pd(2)-Ag(1) bond length is 0.55 Å. The Pd(2)-As(1) bond length is 3.09 Å. Ag(1) is bonded in a bent 120 degrees geometry to one Pd(1) and one Pd(2) atom. As(1) is bonded to one Pd(1), one Pd(2), and four equivalent As(1) atoms to form a mixture of corner and edge-sharing AsAs4Pd2 octahedra. The corner-sharing octahedra are not tilted. All As(1)-As(1) bond lengths are 3.06 Å.