data_GaAg2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.47
_cell_length_b   5.47
_cell_length_c   4.44
_cell_angle_alpha   112.97
_cell_angle_beta   112.97
_cell_angle_gamma   32.1
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaAg2Rh
_chemical_formula_sum   'Ga1 Ag2 Rh1'
_cell_volume   64.56
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga2  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.32  0.0  0.96  1.0
  Ag  Ag1  1  0.39  0.0  0.09  1.0
  Rh  Rh3  1  0.36  0.0  0.03  1.0

data_GaAg2Rh
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.03
_cell_length_b   4.44
_cell_length_c   5.47
_cell_angle_alpha   112.97
_cell_angle_beta   106.05
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaAg2Rh
_chemical_formula_sum   'Ga1 Ag2 Rh1'
_cell_volume   64.56
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.0  0.0  0.0  1.0
  Ag  Ag1  1  0.0  0.09  0.39  1.0
  Ag  Ag2  1  0.0  0.96  0.32  1.0
  Rh  Rh3  1  0.0  0.03  0.36  1.0

Ga Ag Ag Rh
RhAg2Ga is Cyanogen Chloride-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one RhAg2Ga cluster. Rh(1) is bonded in a linear geometry to one Ag(1) and one Ag(2) atom. The Rh(1)-Ag(1) bond length is 0.28 Å. The Rh(1)-Ag(2) bond length is 0.28 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a single-bond geometry to one Rh(1) and one Ga(1) atom. The Ag(1)-Ga(1) bond length is 1.82 Å. In the second Ag site, Ag(2) is bonded in a single-bond geometry to one Rh(1) atom. Ga(1) is bonded in a distorted single-bond geometry to one Ag(1) atom.