data_TiZnPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.89
_cell_length_b   4.89
_cell_length_c   4.6
_cell_angle_alpha   101.15
_cell_angle_beta   101.15
_cell_angle_gamma   34.46
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiZnPd2
_chemical_formula_sum   'Ti1 Zn1 Pd2'
_cell_volume   60.92
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti2  1  0.21  0.0  0.1  1.0
  Zn  Zn3  1  0.64  0.0  0.54  1.0
  Pd  Pd0  1  0.42  0.0  0.34  1.0
  Pd  Pd1  1  0.75  0.0  0.28  1.0

data_TiZnPd2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.9
_cell_length_b   4.6
_cell_length_c   4.89
_cell_angle_alpha   101.15
_cell_angle_beta   107.23
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiZnPd2
_chemical_formula_sum   'Ti1 Zn1 Pd2'
_cell_volume   60.92
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.0  0.1  0.21  1.0
  Zn  Zn1  1  0.0  0.54  0.64  1.0
  Pd  Pd2  1  0.0  0.28  0.75  1.0
  Pd  Pd3  1  0.0  0.34  0.42  1.0

Ti Zn Pd Pd
TiPd2Zn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one TiPd2Zn cluster. Ti(1) is bonded in a distorted single-bond geometry to one Pd(1) atom. The Ti(1)-Pd(1) bond length is 1.33 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a linear geometry to one Ti(1) and one Zn(1) atom. The Pd(1)-Zn(1) bond length is 1.25 Å. In the second Pd site, Pd(2) is bonded in a distorted single-bond geometry to one Zn(1) atom. The Pd(2)-Zn(1) bond length is 1.40 Å. Zn(1) is bonded in a distorted L-shaped geometry to one Pd(1) and one Pd(2) atom.