data_MnAg2Bi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.27
_cell_length_b   5.27
_cell_length_c   5.27
_cell_angle_alpha   130.89
_cell_angle_beta   130.89
_cell_angle_gamma   71.98
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnAg2Bi
_chemical_formula_sum   'Mn1 Ag2 Bi1'
_cell_volume   81.92
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn3  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.19  0.0  0.13  1.0
  Ag  Ag1  1  0.0  0.0  0.27  1.0
  Bi  Bi2  1  0.0  0.19  0.13  1.0

data_MnAg2Bi
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.38
_cell_length_b   4.38
_cell_length_c   5.27
_cell_angle_alpha   114.55
_cell_angle_beta   114.55
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnAg2Bi
_chemical_formula_sum   'Mn1 Ag2 Bi1'
_cell_volume   81.92
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.0  0.0  0.0  1.0
  Ag  Ag1  1  0.13  0.94  0.94  1.0
  Ag  Ag2  1  0.27  0.27  0.27  1.0
  Bi  Bi3  1  0.94  0.13  0.94  1.0

Mn Ag Ag Bi
MnAg2Bi is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one MnAg2Bi cluster. Mn(1) is bonded in a water-like geometry to one Ag(1), one Ag(2), and one Bi(1) atom. The Mn(1)-Ag(1) bond length is 0.76 Å. The Mn(1)-Ag(2) bond length is 1.40 Å. The Mn(1)-Bi(1) bond length is 0.76 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a single-bond geometry to one Mn(1) and one Ag(2) atom. The Ag(1)-Ag(2) bond length is 1.56 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one Mn(1), one Ag(1), and one Bi(1) atom. The Ag(2)-Bi(1) bond length is 1.56 Å. Bi(1) is bonded in a single-bond geometry to one Mn(1) and one Ag(2) atom.