data_LiInRu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.21
_cell_length_b   3.21
_cell_length_c   5.83
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiInRu2
_chemical_formula_sum   'Li1 In1 Ru2'
_cell_volume   59.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.0  0.0  0.0  1.0
  In  In0  1  0.0  0.0  0.92  1.0
  Ru  Ru2  1  0.6  0.6  0.22  1.0
  Ru  Ru3  1  0.6  0.6  0.61  1.0

data_LiInRu2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.53
_cell_length_b   4.53
_cell_length_c   5.83
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LiInRu2
_chemical_formula_sum   'Li2 In2 Ru4'
_cell_volume   119.86
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.0  1.0
  In  In1  2  0.0  0.0  0.92  1.0
  Ru  Ru2  2  0.1  0.5  0.22  1.0
  Ru  Ru3  2  0.1  0.5  0.61  1.0

Li In Ru Ru
LiRu2In crystallizes in the monoclinic Cm space group. Li(1) is bonded in a single-bond geometry to four equivalent Ru(1) and one In(1) atom. There are a spread of Li(1)-Ru(1) bond distances ranging from 2.22-3.03 Å. The Li(1)-In(1) bond length is 0.49 Å. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a 5-coordinate geometry to four equivalent Li(1) and one Ru(2) atom. The Ru(1)-Ru(2) bond length is 2.25 Å. In the second Ru site, Ru(2) is bonded in a 4-coordinate geometry to one Ru(1) and three equivalent In(1) atoms. There is one shorter (2.54 Å) and two longer (2.93 Å) Ru(2)-In(1) bond lengths. In(1) is bonded in a single-bond geometry to one Li(1) and three equivalent Ru(2) atoms.