data_VMoPt2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.22
_cell_length_b   9.22
_cell_length_c   9.22
_cell_angle_alpha   17.28
_cell_angle_beta   17.28
_cell_angle_gamma   17.28
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VMoPt2
_chemical_formula_sum   'V1 Mo1 Pt2'
_cell_volume   60.33
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Mo  Mo0  1  0.0  0.0  0.62  1.0
  Pt  Pt1  1  0.0  0.0  0.36  1.0
  Pt  Pt2  1  0.0  0.0  0.88  1.0

data_VMoPt2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.8
_cell_length_b   2.77
_cell_length_c   9.22
_cell_angle_alpha   90.0
_cell_angle_beta   99.99
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VMoPt2
_chemical_formula_sum   'V2 Mo2 Pt4'
_cell_volume   120.66
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.0  1.0
  Mo  Mo1  2  0.0  0.0  0.38  1.0
  Pt  Pt2  2  0.0  0.0  0.12  1.0
  Pt  Pt3  2  0.0  0.0  0.64  1.0

V Mo Pt Pt
VMoPt2 crystallizes in the monoclinic Cm space group. V(1) is bonded in a single-bond geometry to one Pt(1) and one Pt(2) atom. The V(1)-Pt(1) bond length is 3.33 Å. The V(1)-Pt(2) bond length is 1.11 Å. Mo(1) is bonded in a distorted linear geometry to one Pt(1) and one Pt(2) atom. The Mo(1)-Pt(1) bond length is 2.39 Å. The Mo(1)-Pt(2) bond length is 2.39 Å. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 8-coordinate geometry to one V(1), one Mo(1), and six equivalent Pt(1) atoms. All Pt(1)-Pt(1) bond lengths are 2.77 Å. In the second Pt site, Pt(2) is bonded in a single-bond geometry to one V(1) and one Mo(1) atom.