data_LiZnRe2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.6
_cell_length_b   4.6
_cell_length_c   4.98
_cell_angle_alpha   95.05
_cell_angle_beta   95.05
_cell_angle_gamma   33.54
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiZnRe2
_chemical_formula_sum   'Li1 Zn1 Re2'
_cell_volume   57.92
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.84  0.0  0.6  1.0
  Zn  Zn3  1  0.08  0.0  0.63  1.0
  Re  Re1  1  0.03  0.0  0.1  1.0
  Re  Re2  1  0.56  0.0  0.11  1.0

data_LiZnRe2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.65
_cell_length_b   4.6
_cell_length_c   4.98
_cell_angle_alpha   95.05
_cell_angle_beta   90.0
_cell_angle_gamma   106.77
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiZnRe2
_chemical_formula_sum   'Li1 Zn1 Re2'
_cell_volume   57.92
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.16  0.4  1.0
  Zn  Zn1  1  0.0  0.92  0.37  1.0
  Re  Re2  1  0.0  0.44  0.89  1.0
  Re  Re3  1  0.0  0.97  0.9  1.0

Li Zn Re Re
LiRe2Zn crystallizes in the triclinic P1 space group. Li(1) is bonded in a single-bond geometry to two equivalent Re(1), two equivalent Re(2), and one Zn(1) atom. There is one shorter (2.57 Å) and one longer (2.69 Å) Li(1)-Re(1) bond length. There is one shorter (2.69 Å) and one longer (2.94 Å) Li(1)-Re(2) bond length. The Li(1)-Zn(1) bond length is 1.08 Å. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 8-coordinate geometry to two equivalent Li(1), two equivalent Re(1), two equivalent Re(2), and two equivalent Zn(1) atoms. Both Re(1)-Re(1) bond lengths are 2.65 Å. There is one shorter (2.16 Å) and one longer (2.44 Å) Re(1)-Re(2) bond length. There is one shorter (2.39 Å) and one longer (2.61 Å) Re(1)-Zn(1) bond length. In the second Re site, Re(2) is bonded in a 7-coordinate geometry to two equivalent Li(1), two equivalent Re(1), two equivalent Re(2), and one Zn(1) atom. Both Re(2)-Re(2) bond lengths are 2.65 Å. The Re(2)-Zn(1) bond length is 3.10 Å. Zn(1) is bonded in a single-bond geometry to one Li(1), one Re(2), and two equivalent Re(1) atoms.