data_LiIn2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.95
_cell_length_b   4.95
_cell_length_c   3.04
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiIn2W
_chemical_formula_sum   'Li1 In2 W1'
_cell_volume   74.65
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li2  1  0.0  0.0  0.0  1.0
  In  In0  1  0.48  0.0  0.52  1.0
  In  In1  1  0.0  0.48  0.52  1.0
  W  W3  1  0.48  0.48  0.0  1.0

data_LiIn2W
_symmetry_space_group_name_H-M   Cm
_cell_length_a   7.01
_cell_length_b   7.01
_cell_length_c   3.04
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LiIn2W
_chemical_formula_sum   'Li2 In4 W2'
_cell_volume   149.3
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.0  1.0
  In  In1  4  0.24  0.24  0.52  1.0
  W  W2  2  0.48  0.0  -0.0  1.0

Li In In W
LiWIn2 is alpha iridium vanadium-derived structured and crystallizes in the monoclinic Cm space group. Li(1) is bonded in a distorted body-centered cubic geometry to eight equivalent In(1) atoms. There are a spread of Li(1)-In(1) bond distances ranging from 2.78-3.04 Å. W(1) is bonded in a distorted body-centered cubic geometry to eight equivalent In(1) atoms. There are a spread of W(1)-In(1) bond distances ranging from 2.78-3.04 Å. In(1) is bonded in a distorted body-centered cubic geometry to four equivalent Li(1) and four equivalent W(1) atoms.