data_AlV2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.32
_cell_length_b   4.32
_cell_length_c   2.96
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   105.18
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AlV2P
_chemical_formula_sum   'Al1 V2 P1'
_cell_volume   53.35
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.0  0.0  0.0  1.0
  V  V2  1  0.31  0.28  0.48  1.0
  V  V3  1  0.31  0.72  0.48  1.0
  P  P1  1  0.63  0.0  0.0  1.0

data_AlV2P
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.96
_cell_length_b   4.32
_cell_length_c   4.32
_cell_angle_alpha   105.18
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AlV2P
_chemical_formula_sum   'Al1 V2 P1'
_cell_volume   53.35
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.0  0.0  0.0  1.0
  V  V1  1  0.48  0.31  0.28  1.0
  V  V2  1  0.48  0.31  0.72  1.0
  P  P3  1  0.0  0.63  0.0  1.0

Al V V P
V2AlP crystallizes in the triclinic P1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one V(2), two equivalent Al(1), and two equivalent P(1) atoms. The V(1)-V(2) bond length is 1.88 Å. There is one shorter (2.11 Å) and one longer (2.20 Å) V(1)-Al(1) bond length. There is one shorter (2.49 Å) and one longer (2.56 Å) V(1)-P(1) bond length. In the second V site, V(2) is bonded in a 2-coordinate geometry to one V(1) and two equivalent P(1) atoms. There is one shorter (2.11 Å) and one longer (2.20 Å) V(2)-P(1) bond length. Al(1) is bonded in a distorted single-bond geometry to two equivalent V(1) and one P(1) atom. The Al(1)-P(1) bond length is 1.61 Å. P(1) is bonded in a 3-coordinate geometry to two equivalent V(1), two equivalent V(2), and one Al(1) atom.