data_NaLaCd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.45
_cell_length_b   5.45
_cell_length_c   3.4
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaLaCd
_chemical_formula_sum   'Na1 La1 Cd1'
_cell_volume   87.43
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na2  1  0.0  0.0  0.79  1.0
  La  La1  1  0.72  0.57  0.13  1.0
  Cd  Cd0  1  1.0  0.14  0.88  1.0

data_NaLaCd
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.4
_cell_length_b   5.45
_cell_length_c   5.45
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaLaCd
_chemical_formula_sum   'Na1 La1 Cd1'
_cell_volume   87.43
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.79  0.0  0.0  1.0
  La  La1  1  0.13  0.72  0.57  1.0
  Cd  Cd2  1  0.88  1.0  0.14  1.0

Na La Cd
NaLaCd crystallizes in the triclinic P1 space group. Na(1) is bonded in a single-bond geometry to two equivalent La(1) and one Cd(1) atom. There is one shorter (2.35 Å) and one longer (3.04 Å) Na(1)-La(1) bond length. The Na(1)-Cd(1) bond length is 0.84 Å. La(1) is bonded in a 4-coordinate geometry to two equivalent Na(1) and two equivalent Cd(1) atoms. There is one shorter (3.46 Å) and one longer (3.54 Å) La(1)-Cd(1) bond length. Cd(1) is bonded in a single-bond geometry to one Na(1) and two equivalent La(1) atoms.