data_NbGeP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.24
_cell_length_b   3.26
_cell_length_c   6.35
_cell_angle_alpha   90.0
_cell_angle_beta   101.67
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NbGeP2
_chemical_formula_sum   'Nb1 Ge1 P2'
_cell_volume   65.57
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb1  1  0.36  0.0  0.11  1.0
  Ge  Ge0  1  0.0  0.0  0.0  1.0
  P  P2  1  0.98  0.63  0.41  1.0
  P  P3  1  0.97  0.63  0.8  1.0

data_NbGeP2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.24
_cell_length_b   3.26
_cell_length_c   6.35
_cell_angle_alpha   90.0
_cell_angle_beta   101.67
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NbGeP2
_chemical_formula_sum   'Nb1 Ge1 P2'
_cell_volume   65.57
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.36  0.0  0.11  1.0
  Ge  Ge1  1  0.0  0.0  0.0  1.0
  P  P2  1  0.97  0.63  0.8  1.0
  P  P3  1  0.98  0.63  0.41  1.0

Nb Ge P P
NbGeP2 crystallizes in the triclinic P1 space group. Nb(1) is bonded in a distorted single-bond geometry to one Ge(1) and four equivalent P(1) atoms. The Nb(1)-Ge(1) bond length is 1.22 Å. There are a spread of Nb(1)-P(1) bond distances ranging from 2.77-3.23 Å. Ge(1) is bonded in a 1-coordinate geometry to one Nb(1), one P(1), and one P(2) atom. The Ge(1)-P(1) bond length is 2.90 Å. The Ge(1)-P(2) bond length is 1.74 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to four equivalent Nb(1), one Ge(1), and one P(2) atom. The P(1)-P(2) bond length is 2.47 Å. In the second P site, P(2) is bonded in a 1-coordinate geometry to one Ge(1) and one P(1) atom.