data_Cr2CdOs
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.62
_cell_length_b   4.62
_cell_length_c   2.9
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   101.42
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cr2CdOs
_chemical_formula_sum   'Cr2 Cd1 Os1'
_cell_volume   60.53
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr1  1  0.46  0.79  0.45  1.0
  Cr  Cr2  1  0.46  0.21  0.45  1.0
  Cd  Cd0  1  0.0  0.0  0.0  1.0
  Os  Os3  1  0.92  0.0  0.0  1.0

data_Cr2CdOs
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.9
_cell_length_b   4.62
_cell_length_c   4.62
_cell_angle_alpha   101.42
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cr2CdOs
_chemical_formula_sum   'Cr2 Cd1 Os1'
_cell_volume   60.53
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.45  0.46  0.21  1.0
  Cr  Cr1  1  0.45  0.46  0.79  1.0
  Cd  Cd2  1  0.0  0.0  0.0  1.0
  Os  Os3  1  0.0  0.92  0.0  1.0

Cr Cr Cd Os
Cr2OsCd crystallizes in the triclinic P1 space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a 8-coordinate geometry to two equivalent Cr(1), two equivalent Cr(2), two equivalent Os(1), and two equivalent Cd(1) atoms. Both Cr(1)-Cr(1) bond lengths are 2.90 Å. There is one shorter (1.97 Å) and one longer (2.64 Å) Cr(1)-Cr(2) bond length. There is one shorter (2.52 Å) and one longer (2.69 Å) Cr(1)-Os(1) bond length. There is one shorter (2.84 Å) and one longer (2.98 Å) Cr(1)-Cd(1) bond length. In the second Cr site, Cr(2) is bonded in a 8-coordinate geometry to two equivalent Cr(1), two equivalent Cr(2), two equivalent Os(1), and two equivalent Cd(1) atoms. Both Cr(2)-Cr(2) bond lengths are 2.90 Å. There is one shorter (2.84 Å) and one longer (2.98 Å) Cr(2)-Os(1) bond length. There is one shorter (2.52 Å) and one longer (2.69 Å) Cr(2)-Cd(1) bond length. Os(1) is bonded in a single-bond geometry to two equivalent Cr(1), two equivalent Cr(2), and one Cd(1) atom. The Os(1)-Cd(1) bond length is 0.36 Å. Cd(1) is bonded in a single-bond geometry to two equivalent Cr(1), two equivalent Cr(2), and one Os(1) atom.