data_ScCo2Sb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.16
_cell_length_b   3.16
_cell_length_c   6.67
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   93.58
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScCo2Sb
_chemical_formula_sum   'Sc1 Co2 Sb1'
_cell_volume   66.56
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc3  1  0.0  0.0  0.34  1.0
  Co  Co0  1  0.17  0.0  0.37  1.0
  Co  Co1  1  0.0  0.0  0.31  1.0
  Sb  Sb2  1  0.17  0.0  0.65  1.0

data_ScCo2Sb
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.16
_cell_length_b   3.16
_cell_length_c   6.67
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   93.58
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScCo2Sb
_chemical_formula_sum   'Sc1 Co2 Sb1'
_cell_volume   66.56
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.0  0.0  0.34  1.0
  Co  Co1  1  0.0  0.0  0.31  1.0
  Co  Co2  1  0.17  0.0  0.37  1.0
  Sb  Sb3  1  0.17  0.0  0.65  1.0

Sc Co Co Sb
Co2ScSb crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Co2ScSb cluster. Sc(1) is bonded in a distorted water-like geometry to one Co(1) and one Co(2) atom. The Sc(1)-Co(1) bond length is 0.56 Å. The Sc(1)-Co(2) bond length is 0.18 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a single-bond geometry to one Sc(1) and one Sb(1) atom. The Co(1)-Sb(1) bond length is 1.88 Å. In the second Co site, Co(2) is bonded in a single-bond geometry to one Sc(1) atom. Sb(1) is bonded in a single-bond geometry to one Co(1) atom.