data_Ti2GeP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.81
_cell_length_b   4.92
_cell_length_c   4.92
_cell_angle_alpha   41.41
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ti2GeP
_chemical_formula_sum   'Ti2 Ge1 P1'
_cell_volume   61.07
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti2  1  0.0  0.0  0.1  1.0
  Ti  Ti3  1  0.91  0.0  0.4  1.0
  Ge  Ge0  1  0.91  0.0  0.92  1.0
  P  P1  1  0.0  0.0  0.61  1.0

data_Ti2GeP
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.48
_cell_length_b   3.81
_cell_length_c   4.92
_cell_angle_alpha   90.0
_cell_angle_beta   110.7
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ti2GeP
_chemical_formula_sum   'Ti2 Ge1 P1'
_cell_volume   61.07
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.6  0.91  0.6  1.0
  Ti  Ti1  1  0.9  0.0  0.9  1.0
  Ge  Ge2  1  0.08  0.91  0.08  1.0
  P  P3  1  0.39  0.0  0.39  1.0

Ti Ti Ge P
Ti2GeP is alpha Niobium phosphide-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Ti2GeP cluster. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a distorted single-bond geometry to one Ge(1) atom. The Ti(1)-Ge(1) bond length is 0.95 Å. In the second Ti site, Ti(2) is bonded in a distorted single-bond geometry to one P(1) atom. The Ti(2)-P(1) bond length is 1.07 Å. Ge(1) is bonded in a distorted bent 150 degrees geometry to one Ti(1) and one P(1) atom. The Ge(1)-P(1) bond length is 1.58 Å. P(1) is bonded in a distorted bent 150 degrees geometry to one Ti(2) and one Ge(1) atom.