data_Y5Tm11O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.14
_cell_length_b   9.14
_cell_length_c   10.55
_cell_angle_alpha   125.29
_cell_angle_beta   125.29
_cell_angle_gamma   70.51
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Y5Tm11O24
_chemical_formula_sum   'Y5 Tm11 O24'
_cell_volume   586.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.87  0.64  0.87  1.0
  Y  Y1  1  0.46  0.06  0.0  1.0
  Y  Y2  1  0.13  0.63  0.59  1.0
  Y  Y3  1  0.33  0.63  0.87  1.0
  Y  Y4  1  0.59  0.64  0.59  1.0
  Tm  Tm5  1  0.84  0.37  0.11  1.0
  Tm  Tm6  1  0.62  0.37  0.34  1.0
  Tm  Tm7  1  0.76  0.0  0.98  1.0
  Tm  Tm8  1  0.5  1.0  0.24  1.0
  Tm  Tm9  1  0.73  0.65  0.73  1.0
  Tm  Tm10  1  0.46  0.35  0.0  1.0
  Tm  Tm11  1  0.97  1.0  0.21  1.0
  Tm  Tm12  1  0.71  0.0  0.48  1.0
  Tm  Tm13  1  0.35  0.63  0.62  1.0
  Tm  Tm14  1  0.11  0.63  0.83  1.0
  Tm  Tm15  1  0.73  0.93  0.73  1.0
  O  O16  1  0.63  0.87  0.58  1.0
  O  O17  1  0.15  0.15  0.12  1.0
  O  O18  1  0.78  0.69  0.9  1.0
  O  O19  1  0.48  0.32  0.18  1.0
  O  O20  1  0.17  0.59  0.51  1.0
  O  O21  1  0.91  0.42  0.78  1.0
  O  O22  1  0.31  0.15  0.33  1.0
  O  O23  1  0.83  0.87  0.88  1.0
  O  O24  1  0.94  0.74  0.91  1.0
  O  O25  1  0.27  0.98  0.79  1.0
  O  O26  1  0.03  1.0  0.06  1.0
  O  O27  1  0.67  0.26  0.19  1.0
  O  O28  1  0.43  1.0  0.4  1.0
  O  O29  1  0.19  0.98  0.67  1.0
  O  O30  1  0.79  0.26  0.27  1.0
  O  O31  1  0.52  0.74  0.54  1.0
  O  O32  1  0.9  0.13  0.31  1.0
  O  O33  1  0.42  0.87  0.82  1.0
  O  O34  1  0.29  0.59  0.95  1.0
  O  O35  1  0.55  0.42  0.67  1.0
  O  O36  1  0.68  0.69  0.55  1.0
  O  O37  1  0.98  0.32  0.28  1.0
  O  O38  1  0.56  0.13  0.14  1.0
  O  O39  1  0.05  0.87  0.63  1.0

data_Y5Tm11O24
_symmetry_space_group_name_H-M   P1
_cell_length_a   9.13
_cell_length_b   9.13
_cell_length_c   9.14
_cell_angle_alpha   109.47
_cell_angle_beta   109.47
_cell_angle_gamma   109.45
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Y5Tm11O24
_chemical_formula_sum   'Y5 Tm11 O24'
_cell_volume   586.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.04  0.63  0.17  1.0
  Y  Y1  1  0.05  0.64  0.65  1.0
  Y  Y2  1  0.06  0.06  0.53  1.0
  Y  Y3  1  0.76  0.63  0.1  1.0
  Y  Y4  1  0.77  0.64  0.64  1.0
  Tm  Tm5  1  0.01  0.63  0.35  1.0
  Tm  Tm6  1  0.02  0.0  0.78  1.0
  Tm  Tm7  1  0.03  0.37  0.65  1.0
  Tm  Tm8  1  0.2  0.93  0.93  1.0
  Tm  Tm9  1  0.26  0.37  0.09  1.0
  Tm  Tm10  1  0.35  0.35  0.81  1.0
  Tm  Tm11  1  0.52  0.0  0.23  1.0
  Tm  Tm12  1  0.75  1.0  0.25  1.0
  Tm  Tm13  1  0.79  1.0  0.75  1.0
  Tm  Tm14  1  0.8  0.63  0.91  1.0
  Tm  Tm15  1  0.93  0.65  0.66  1.0
  O  O16  1  0.03  0.15  0.18  1.0
  O  O17  1  0.05  0.87  0.46  1.0
  O  O18  1  0.05  0.32  0.03  1.0
  O  O19  1  0.07  0.26  0.74  1.0
  O  O20  1  0.08  0.59  0.26  1.0
  O  O21  1  0.14  0.69  0.82  1.0
  O  O22  1  0.14  0.32  0.63  1.0
  O  O23  1  0.2  0.98  0.47  1.0
  O  O24  1  0.2  0.74  0.72  1.0
  O  O25  1  0.23  0.87  0.28  1.0
  O  O26  1  0.29  0.87  0.92  1.0
  O  O27  1  0.31  0.98  0.5  1.0
  O  O28  1  0.6  1.0  0.03  1.0
  O  O29  1  0.63  0.42  0.54  1.0
  O  O30  1  0.64  0.59  0.93  1.0
  O  O31  1  0.75  0.42  0.3  1.0
  O  O32  1  0.78  0.69  0.56  1.0
  O  O33  1  0.82  0.13  0.72  1.0
  O  O34  1  0.82  0.15  0.13  1.0
  O  O35  1  0.83  0.74  0.77  1.0
  O  O36  1  0.94  1.0  0.97  1.0
  O  O37  1  0.98  0.13  0.54  1.0
  O  O38  1  0.99  0.26  0.78  1.0
  O  O39  1  0.99  0.87  0.82  1.0

Y Y Y Y Y Tm Tm Tm Tm Tm Tm Tm Tm Tm Tm Tm O O O O O O O O O O O O O O O O O O O O O O O O
Tm11Y5O24 crystallizes in the triclinic P1 space group. There are eleven inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a single-bond geometry to one O(12), one O(2), and one O(22) atom. The Tm(1)-O(12) bond length is 2.70 Å. The Tm(1)-O(2) bond length is 2.85 Å. The Tm(1)-O(22) bond length is 1.63 Å. In the second Tm site, Tm(2) is bonded in a 2-coordinate geometry to one O(12), one O(15), and one O(4) atom. The Tm(2)-O(12) bond length is 1.60 Å. The Tm(2)-O(15) bond length is 1.84 Å. The Tm(2)-O(4) bond length is 1.32 Å. In the third Tm site, Tm(3) is bonded in a single-bond geometry to one O(12) and one O(8) atom. The Tm(3)-O(12) bond length is 2.38 Å. The Tm(3)-O(8) bond length is 1.38 Å. In the fourth Tm site, Tm(4) is bonded in a 3-coordinate geometry to one O(13), one O(2), one O(23), and one O(7) atom. The Tm(4)-O(13) bond length is 2.00 Å. The Tm(4)-O(2) bond length is 2.84 Å. The Tm(4)-O(23) bond length is 2.32 Å. The Tm(4)-O(7) bond length is 2.09 Å. In the fifth Tm site, Tm(5) is bonded in a 5-coordinate geometry to one Y(1), one Y(5), one O(21), one O(3), and one O(8) atom. The Tm(5)-Y(1) bond length is 1.32 Å. The Tm(5)-Y(5) bond length is 1.24 Å. The Tm(5)-O(21) bond length is 1.86 Å. The Tm(5)-O(3) bond length is 1.50 Å. The Tm(5)-O(8) bond length is 1.77 Å. In the sixth Tm site, Tm(6) is bonded in a 3-coordinate geometry to one O(12), one O(19), and one O(4) atom. The Tm(6)-O(12) bond length is 2.16 Å. The Tm(6)-O(19) bond length is 2.41 Å. The Tm(6)-O(4) bond length is 1.91 Å. In the seventh Tm site, Tm(7) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(17) atom. The Tm(7)-O(11) bond length is 2.02 Å. The Tm(7)-O(17) bond length is 1.27 Å. In the eighth Tm site, Tm(8) is bonded in a 3-coordinate geometry to one O(1), one O(13), and one O(24) atom. The Tm(8)-O(1) bond length is 2.47 Å. The Tm(8)-O(13) bond length is 2.14 Å. The Tm(8)-O(24) bond length is 2.78 Å. In the ninth Tm site, Tm(9) is bonded in a distorted trigonal planar geometry to one O(18), one O(20), and one O(5) atom. The Tm(9)-O(18) bond length is 1.91 Å. The Tm(9)-O(20) bond length is 2.28 Å. The Tm(9)-O(5) bond length is 1.34 Å. In the tenth Tm site, Tm(10) is bonded in a bent 120 degrees geometry to one O(19) and one O(9) atom. The Tm(10)-O(19) bond length is 1.44 Å. The Tm(10)-O(9) bond length is 1.94 Å. In the eleventh Tm site, Tm(11) is bonded in a 2-coordinate geometry to one O(1) and one O(8) atom. The Tm(11)-O(1) bond length is 1.13 Å. The Tm(11)-O(8) bond length is 1.62 Å. There are five inequivalent Y sites. In the first Y site, Y(1) is bonded in a 2-coordinate geometry to one Tm(5), one O(3), one O(6), and one O(9) atom. The Y(1)-O(3) bond length is 0.99 Å. The Y(1)-O(6) bond length is 1.71 Å. The Y(1)-O(9) bond length is 1.03 Å. In the second Y site, Y(2) is bonded in a 1-coordinate geometry to one O(10), one O(12), one O(18), and one O(23) atom. The Y(2)-O(10) bond length is 1.74 Å. The Y(2)-O(12) bond length is 2.13 Å. The Y(2)-O(18) bond length is 1.62 Å. The Y(2)-O(23) bond length is 1.10 Å. In the third Y site, Y(3) is bonded in a distorted single-bond geometry to one O(24) and one O(5) atom. The Y(3)-O(24) bond length is 1.92 Å. The Y(3)-O(5) bond length is 1.02 Å. In the fourth Y site, Y(4) is bonded in a single-bond geometry to one O(19) atom. The Y(4)-O(19) bond length is 1.41 Å. In the fifth Y site, Y(5) is bonded in a 2-coordinate geometry to one Tm(5), one O(16), and one O(21) atom. The Y(5)-O(16) bond length is 1.13 Å. The Y(5)-O(21) bond length is 1.36 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Tm(11) and one Tm(8) atom. In the second O site, O(2) is bonded in a distorted trigonal pyramidal geometry to one Tm(1), one Tm(4), one O(11), and one O(7) atom. The O(2)-O(11) bond length is 1.64 Å. The O(2)-O(7) bond length is 1.79 Å. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Tm(5) and one Y(1) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one Tm(2), one Tm(6), and one O(12) atom. The O(4)-O(12) bond length is 1.60 Å. In the fifth O site, O(5) is bonded in a water-like geometry to one Tm(9) and one Y(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Y(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Tm(4), one O(13), and one O(2) atom. The O(7)-O(13) bond length is 1.70 Å. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Tm(11), one Tm(3), and one Tm(5) atom. In the ninth O site, O(9) is bonded in a 1-coordinate geometry to one Tm(10) and one Y(1) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Y(2), one O(14), and one O(18) atom. The O(10)-O(14) bond length is 1.01 Å. The O(10)-O(18) bond length is 1.38 Å. In the eleventh O site, O(11) is bonded in a 1-coordinate geometry to one Tm(7) and one O(2) atom. In the twelfth O site, O(12) is bonded in a 8-coordinate geometry to one Tm(1), one Tm(2), one Tm(3), one Tm(6), one Y(2), one O(15), one O(23), and one O(4) atom. The O(12)-O(15) bond length is 0.92 Å. The O(12)-O(23) bond length is 1.54 Å. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Tm(4), one Tm(8), and one O(7) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one O(10) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Tm(2), one O(12), and one O(17) atom. The O(15)-O(17) bond length is 1.39 Å. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Y(5) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Tm(7) and one O(15) atom. In the eighteenth O site, O(18) is bonded in a distorted linear geometry to one Tm(9), one Y(2), and one O(10) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Tm(10), one Tm(6), and one Y(4) atom. In the twentieth O site, O(20) is bonded in a distorted single-bond geometry to one Tm(9) atom. In the twenty-first O site, O(21) is bonded in a single-bond geometry to one Tm(5) and one Y(5) atom. In the twenty-second O site, O(22) is bonded in a single-bond geometry to one Tm(1) atom. In the twenty-third O site, O(23) is bonded in a single-bond geometry to one Tm(4), one Y(2), and one O(12) atom. In the twenty-fourth O site, O(24) is bonded in a 1-coordinate geometry to one Tm(8) and one Y(3) atom.