data_Tc2PdCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.6
_cell_length_b   4.6
_cell_length_c   2.83
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.69
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Tc2PdCl
_chemical_formula_sum   'Tc2 Pd1 Cl1'
_cell_volume   59.76
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc2  1  0.61  0.37  0.41  1.0
  Tc  Tc3  1  0.61  0.63  0.41  1.0
  Pd  Pd1  1  0.23  0.0  0.0  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Tc2PdCl
_symmetry_space_group_name_H-M   Pm
_cell_length_a   2.83
_cell_length_b   4.6
_cell_length_c   4.6
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   Tc2PdCl
_chemical_formula_sum   'Tc2 Pd1 Cl1'
_cell_volume   59.76
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  2  0.41  0.37  0.61  1.0
  Pd  Pd1  1  0.0  0.0  0.23  1.0
  Cl  Cl2  1  0.0  0.0  0.0  1.0

Tc Tc Pd Cl
Tc2PdCl crystallizes in the monoclinic Pm space group. Tc(1) is bonded in a 5-coordinate geometry to one Tc(1), two equivalent Pd(1), and two equivalent Cl(1) atoms. The Tc(1)-Tc(1) bond length is 1.24 Å. There is one shorter (2.71 Å) and one longer (2.95 Å) Tc(1)-Pd(1) bond length. There is one shorter (2.71 Å) and one longer (2.95 Å) Tc(1)-Cl(1) bond length. Pd(1) is bonded in a single-bond geometry to four equivalent Tc(1) and one Cl(1) atom. The Pd(1)-Cl(1) bond length is 1.06 Å. Cl(1) is bonded in a distorted single-bond geometry to four equivalent Tc(1) and one Pd(1) atom.