data_In2IrCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.1
_cell_length_b   5.1
_cell_length_c   3.03
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In2IrCl
_chemical_formula_sum   'In2 Ir1 Cl1'
_cell_volume   78.8
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In1  1  0.0  0.55  0.51  1.0
  In  In2  1  0.55  0.0  0.51  1.0
  Ir  Ir3  1  0.55  0.55  0.0  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_In2IrCl
_symmetry_space_group_name_H-M   Amm2
_cell_length_a   3.03
_cell_length_b   7.21
_cell_length_c   7.21
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   38
_chemical_formula_structural   In2IrCl
_chemical_formula_sum   'In4 Ir2 Cl2'
_cell_volume   157.6
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, z'
  3  '-x, y, z'
  4  'x, -y, z'
  5  'x, y+1/2, z+1/2'
  6  '-x, -y+1/2, z+1/2'
  7  '-x, y+1/2, z+1/2'
  8  'x, -y+1/2, z+1/2'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  4  0.5  0.22  0.78  1.0
  Ir  Ir1  2  0.0  0.0  0.55  1.0
  Cl  Cl2  2  0.0  0.0  0.0  1.0

In In Ir Cl
IrIn2Cl crystallizes in the monoclinic Cm space group. Ir(1) is bonded in a 8-coordinate geometry to eight equivalent In(1) atoms. There are a spread of Ir(1)-In(1) bond distances ranging from 2.72-3.21 Å. In(1) is bonded in a 4-coordinate geometry to four equivalent Ir(1) and two equivalent Cl(1) atoms. There is one shorter (2.72 Å) and one longer (2.77 Å) In(1)-Cl(1) bond length. Cl(1) is bonded in a 4-coordinate geometry to four equivalent In(1) atoms.