data_LiAg2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.86
_cell_length_b   4.86
_cell_length_c   5.41
_cell_angle_alpha   95.48
_cell_angle_beta   95.48
_cell_angle_gamma   31.84
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiAg2W
_chemical_formula_sum   'Li1 Ag2 W1'
_cell_volume   66.98
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li2  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.89  0.0  0.34  1.0
  Ag  Ag1  1  0.92  0.0  0.04  1.0
  W  W3  1  0.4  0.0  0.69  1.0

data_LiAg2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.66
_cell_length_b   4.86
_cell_length_c   5.41
_cell_angle_alpha   95.48
_cell_angle_beta   90.0
_cell_angle_gamma   105.92
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiAg2W
_chemical_formula_sum   'Li1 Ag2 W1'
_cell_volume   66.98
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.0  1.0
  Ag  Ag1  1  0.0  0.08  0.96  1.0
  Ag  Ag2  1  0.0  0.11  0.66  1.0
  W  W3  1  0.0  0.6  0.31  1.0

Li Ag Ag W
LiWAg2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a single-bond geometry to one W(1) and one Ag(2) atom. The Li(1)-W(1) bond length is 2.70 Å. The Li(1)-Ag(2) bond length is 0.47 Å. W(1) is bonded in a 1-coordinate geometry to one Li(1) and two equivalent Ag(1) atoms. There is one shorter (2.99 Å) and one longer (3.16 Å) W(1)-Ag(1) bond length. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to two equivalent W(1), one Ag(2), and two equivalent Ag(1) atoms. The Ag(1)-Ag(2) bond length is 1.64 Å. Both Ag(1)-Ag(1) bond lengths are 2.66 Å. In the second Ag site, Ag(2) is bonded in a single-bond geometry to one Li(1) and one Ag(1) atom.