data_VRuPt2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.25
_cell_length_b   3.25
_cell_length_c   5.63
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VRuPt2
_chemical_formula_sum   'V1 Ru1 Pt2'
_cell_volume   59.3
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.17  1.0
  Ru  Ru2  1  0.62  0.62  0.91  1.0
  Pt  Pt0  1  0.62  0.62  0.56  1.0
  Pt  Pt1  1  0.0  0.0  0.44  1.0

data_VRuPt2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.59
_cell_length_b   4.59
_cell_length_c   5.63
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VRuPt2
_chemical_formula_sum   'V2 Ru2 Pt4'
_cell_volume   118.6
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.17  1.0
  Ru  Ru1  2  0.12  0.5  0.91  1.0
  Pt  Pt2  2  0.0  0.0  0.44  1.0
  Pt  Pt3  2  0.12  0.5  0.56  1.0

V Ru Pt Pt
VRuPt2 crystallizes in the monoclinic Cm space group. V(1) is bonded in a 1-coordinate geometry to three equivalent Ru(1) and one Pt(2) atom. There is one shorter (2.26 Å) and two longer (2.78 Å) V(1)-Ru(1) bond lengths. The V(1)-Pt(2) bond length is 1.54 Å. Ru(1) is bonded in a 4-coordinate geometry to three equivalent V(1) and one Pt(1) atom. The Ru(1)-Pt(1) bond length is 1.96 Å. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 2-coordinate geometry to one Ru(1) and one Pt(2) atom. The Pt(1)-Pt(2) bond length is 1.85 Å. In the second Pt site, Pt(2) is bonded in a distorted single-bond geometry to one V(1) and one Pt(1) atom.