data_V2SbP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.0
_cell_length_b   5.0
_cell_length_c   5.0
_cell_angle_alpha   134.56
_cell_angle_beta   134.56
_cell_angle_gamma   66.21
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2SbP
_chemical_formula_sum   'V2 Sb1 P1'
_cell_volume   62.32
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.0  0.19  1.0
  V  V3  1  0.0  0.93  0.09  1.0
  Sb  Sb1  1  0.93  0.0  0.09  1.0
  P  P0  1  0.0  0.0  0.0  1.0

data_V2SbP
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.86
_cell_length_b   3.86
_cell_length_c   5.0
_cell_angle_alpha   112.72
_cell_angle_beta   112.72
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2SbP
_chemical_formula_sum   'V2 Sb1 P1'
_cell_volume   62.32
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.16  0.09  0.16  1.0
  V  V1  1  0.19  0.19  0.19  1.0
  Sb  Sb2  1  0.09  0.16  0.16  1.0
  P  P3  1  0.0  0.0  0.0  1.0

V V Sb P
V2SbP crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one V2SbP cluster. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted single-bond geometry to one V(2) and one Sb(1) atom. The V(1)-V(2) bond length is 0.33 Å. The V(1)-Sb(1) bond length is 0.33 Å. In the second V site, V(2) is bonded in a 3-coordinate geometry to one V(1), one Sb(1), and one P(1) atom. The V(2)-Sb(1) bond length is 0.38 Å. The V(2)-P(1) bond length is 0.75 Å. Sb(1) is bonded in a 3-coordinate geometry to one V(1), one V(2), and one P(1) atom. The Sb(1)-P(1) bond length is 0.75 Å. P(1) is bonded in a 2-coordinate geometry to one V(2) and one Sb(1) atom.