data_NaCdIr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.9
_cell_length_b   2.9
_cell_length_c   7.62
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaCdIr
_chemical_formula_sum   'Na1 Cd1 Ir1'
_cell_volume   55.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na2  1  0.0  0.0  0.94  1.0
  Cd  Cd0  1  1.0  0.67  0.16  1.0
  Ir  Ir1  1  0.45  0.84  0.52  1.0

data_NaCdIr
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.9
_cell_length_b   2.9
_cell_length_c   7.62
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaCdIr
_chemical_formula_sum   'Na1 Cd1 Ir1'
_cell_volume   55.5
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.94  1.0
  Cd  Cd1  1  1.0  0.67  0.16  1.0
  Ir  Ir2  1  0.45  0.84  0.52  1.0

Na Cd Ir
NaIrCd crystallizes in the triclinic P1 space group. Na(1) is bonded in a distorted single-bond geometry to two equivalent Ir(1) and one Cd(1) atom. There is one shorter (3.52 Å) and one longer (3.59 Å) Na(1)-Ir(1) bond length. The Na(1)-Cd(1) bond length is 1.90 Å. Ir(1) is bonded in a 10-coordinate geometry to two equivalent Na(1), six equivalent Ir(1), and two equivalent Cd(1) atoms. All Ir(1)-Ir(1) bond lengths are 2.90 Å. There is one shorter (2.98 Å) and one longer (3.33 Å) Ir(1)-Cd(1) bond length. Cd(1) is bonded in a distorted single-bond geometry to one Na(1) and two equivalent Ir(1) atoms.