data_SbWAu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.88
_cell_length_b   4.97
_cell_length_c   5.31
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SbWAu2
_chemical_formula_sum   'Sb1 W1 Au2'
_cell_volume   76.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb2  1  0.0  0.0  0.65  1.0
  W  W3  1  0.0  0.49  0.2  1.0
  Au  Au0  1  0.44  0.0  0.15  1.0
  Au  Au1  1  0.44  0.49  0.96  1.0

data_SbWAu2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.88
_cell_length_b   4.97
_cell_length_c   5.31
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SbWAu2
_chemical_formula_sum   'Sb1 W1 Au2'
_cell_volume   76.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.0  0.0  0.65  1.0
  W  W1  1  0.0  0.49  0.2  1.0
  Au  Au2  1  0.44  0.0  0.15  1.0
  Au  Au3  1  0.44  0.49  0.96  1.0

Sb W Au Au
WAu2Sb crystallizes in the triclinic P1 space group. W(1) is bonded in a distorted L-shaped geometry to two equivalent Au(2), four equivalent Au(1), and two equivalent Sb(1) atoms. There is one shorter (1.80 Å) and one longer (2.05 Å) W(1)-Au(2) bond length. There are a spread of W(1)-Au(1) bond distances ranging from 2.74-3.03 Å. There is one shorter (3.40 Å) and one longer (3.51 Å) W(1)-Sb(1) bond length. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded to four equivalent W(1), two equivalent Au(1), two equivalent Au(2), and four equivalent Sb(1) atoms to form distorted AuSb4W4Au4 cuboctahedra that share corners with eight equivalent Sb(1)Sb2W2Au8 cuboctahedra, corners with ten equivalent Au(1)Sb4W4Au4 cuboctahedra, edges with two equivalent Au(1)Sb4W4Au4 cuboctahedra, edges with four equivalent Sb(1)Sb2W2Au8 cuboctahedra, faces with four equivalent Au(1)Sb4W4Au4 cuboctahedra, and faces with four equivalent Sb(1)Sb2W2Au8 cuboctahedra. Both Au(1)-Au(1) bond lengths are 2.88 Å. There is one shorter (2.62 Å) and one longer (2.75 Å) Au(1)-Au(2) bond length. There are a spread of Au(1)-Sb(1) bond distances ranging from 2.94-3.11 Å. In the second Au site, Au(2) is bonded in a distorted L-shaped geometry to two equivalent W(1), two equivalent Au(1), and four equivalent Sb(1) atoms. There are a spread of Au(2)-Sb(1) bond distances ranging from 3.18-3.44 Å. Sb(1) is bonded to two equivalent W(1), four equivalent Au(1), four equivalent Au(2), and two equivalent Sb(1) atoms to form distorted SbSb2W2Au8 cuboctahedra that share corners with eight equivalent Au(1)Sb4W4Au4 cuboctahedra, corners with ten equivalent Sb(1)Sb2W2Au8 cuboctahedra, edges with two equivalent Sb(1)Sb2W2Au8 cuboctahedra, edges with four equivalent Au(1)Sb4W4Au4 cuboctahedra, faces with four equivalent Au(1)Sb4W4Au4 cuboctahedra, and faces with four equivalent Sb(1)Sb2W2Au8 cuboctahedra. Both Sb(1)-Sb(1) bond lengths are 2.88 Å.