data_TlInBiW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.19
_cell_length_b   5.19
_cell_length_c   5.19
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlInBiW
_chemical_formula_sum   'Tl1 In1 Bi1 W1'
_cell_volume   99.01
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl2  1  0.51  0.51  0.51  1.0
  In  In1  1  0.0  0.0  0.0  1.0
  Bi  Bi0  1  0.84  0.84  0.84  1.0
  W  W3  1  0.67  0.67  0.67  1.0

data_TlInBiW
_symmetry_space_group_name_H-M   R3m
_cell_length_a   5.19
_cell_length_b   5.19
_cell_length_c   12.72
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   TlInBiW
_chemical_formula_sum   'Tl3 In3 Bi3 W3'
_cell_volume   297.03
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  3  0.0  0.0  0.49  1.0
  In  In1  3  0.0  0.0  0.0  1.0
  Bi  Bi2  3  0.0  0.0  0.16  1.0
  W  W3  3  0.0  0.0  0.33  1.0

Tl In Bi W
WTlInBi crystallizes in the trigonal R3m space group. W(1) is bonded to one Tl(1), three equivalent In(1), and one Bi(1) atom to form distorted WTlIn3Bi trigonal bipyramids that share corners with six equivalent W(1)TlIn3Bi trigonal bipyramids,  a cornercorner with one In(1)BiW3 trigonal pyramid, and edges with three equivalent Bi(1)Tl3InW trigonal bipyramids. The W(1)-Tl(1) bond length is 2.09 Å. All W(1)-In(1) bond lengths are 3.00 Å. The W(1)-Bi(1) bond length is 2.09 Å. Tl(1) is bonded in a distorted single-bond geometry to one W(1) and three equivalent Bi(1) atoms. All Tl(1)-Bi(1) bond lengths are 3.00 Å. In(1) is bonded to three equivalent W(1) and one Bi(1) atom to form InBiW3 trigonal pyramids that share  a cornercorner with one W(1)TlIn3Bi trigonal bipyramid, corners with three equivalent Bi(1)Tl3InW trigonal bipyramids, and corners with six equivalent In(1)BiW3 trigonal pyramids. The In(1)-Bi(1) bond length is 2.09 Å. Bi(1) is bonded to one W(1), three equivalent Tl(1), and one In(1) atom to form distorted BiTl3InW trigonal bipyramids that share corners with six equivalent Bi(1)Tl3InW trigonal bipyramids, corners with three equivalent In(1)BiW3 trigonal pyramids, and edges with three equivalent W(1)TlIn3Bi trigonal bipyramids.