data_Zn2CdOs
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.52
_cell_length_b   4.52
_cell_length_c   3.09
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   100.96
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zn2CdOs
_chemical_formula_sum   'Zn2 Cd1 Os1'
_cell_volume   62.11
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn2  1  0.44  0.26  0.55  1.0
  Zn  Zn3  1  0.44  0.74  0.55  1.0
  Cd  Cd0  1  0.0  0.0  0.0  1.0
  Os  Os1  1  0.88  0.0  0.0  1.0

data_Zn2CdOs
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.09
_cell_length_b   4.52
_cell_length_c   4.52
_cell_angle_alpha   100.96
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zn2CdOs
_chemical_formula_sum   'Zn2 Cd1 Os1'
_cell_volume   62.11
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.55  0.44  0.26  1.0
  Zn  Zn1  1  0.55  0.44  0.74  1.0
  Cd  Cd2  1  0.0  0.0  0.0  1.0
  Os  Os3  1  0.0  0.88  0.0  1.0

Zn Zn Cd Os
OsCdZn2 crystallizes in the triclinic P1 space group. Os(1) is bonded in a single-bond geometry to one Cd(1), two equivalent Zn(1), and two equivalent Zn(2) atoms. The Os(1)-Cd(1) bond length is 0.55 Å. There is one shorter (2.85 Å) and one longer (3.00 Å) Os(1)-Zn(1) bond length. There is one shorter (2.53 Å) and one longer (2.69 Å) Os(1)-Zn(2) bond length. Cd(1) is bonded in a single-bond geometry to one Os(1) and two equivalent Zn(1) atoms. There is one shorter (2.53 Å) and one longer (2.69 Å) Cd(1)-Zn(1) bond length. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to two equivalent Os(1), two equivalent Cd(1), and two equivalent Zn(2) atoms. There is one shorter (2.22 Å) and one longer (2.31 Å) Zn(1)-Zn(2) bond length. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to two equivalent Os(1) and two equivalent Zn(1) atoms.