data_TeP2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.23
_cell_length_b   7.23
_cell_length_c   7.23
_cell_angle_alpha   30.94
_cell_angle_beta   30.94
_cell_angle_gamma   30.94
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TeP2Cl
_chemical_formula_sum   'Te1 P2 Cl1'
_cell_volume   88.55
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te3  1  0.0  0.0  0.32  1.0
  P  P1  1  0.0  0.0  0.04  1.0
  P  P2  1  0.0  0.0  0.59  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_TeP2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.68
_cell_length_b   3.86
_cell_length_c   7.23
_cell_angle_alpha   90.0
_cell_angle_beta   107.94
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TeP2Cl
_chemical_formula_sum   'Te2 P4 Cl2'
_cell_volume   177.11
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  2  0.0  0.0  0.68  1.0
  P  P1  2  0.0  0.0  0.41  1.0
  P  P2  2  0.0  0.0  0.96  1.0
  Cl  Cl3  2  0.0  0.0  0.0  1.0

Te P P Cl
P2TeCl is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two P2TeCl clusters. There are two inequivalent P sites. In the first P site, P(1) is bonded in a single-bond geometry to one Te(1) and one Cl(1) atom. The P(1)-Te(1) bond length is 1.99 Å. The P(1)-Cl(1) bond length is 0.29 Å. In the second P site, P(2) is bonded in a single-bond geometry to one Te(1) atom. The P(2)-Te(1) bond length is 1.99 Å. Te(1) is bonded in a linear geometry to one P(1) and one P(2) atom. Cl(1) is bonded in a single-bond geometry to one P(1) atom.