data_MnSn2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.29
_cell_length_b   3.44
_cell_length_c   6.65
_cell_angle_alpha   90.0
_cell_angle_beta   100.14
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnSn2P
_chemical_formula_sum   'Mn1 Sn2 P1'
_cell_volume   74.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.41  0.0  0.27  1.0
  Sn  Sn2  1  0.15  0.72  0.77  1.0
  Sn  Sn3  1  0.97  0.72  0.78  1.0
  P  P1  1  0.0  0.0  0.0  1.0

data_MnSn2P
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.29
_cell_length_b   3.44
_cell_length_c   6.65
_cell_angle_alpha   90.0
_cell_angle_beta   100.14
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnSn2P
_chemical_formula_sum   'Mn1 Sn2 P1'
_cell_volume   74.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.41  0.0  0.27  1.0
  Sn  Sn1  1  0.15  0.72  0.77  1.0
  Sn  Sn2  1  0.97  0.72  0.78  1.0
  P  P3  1  0.0  0.0  0.0  1.0

Mn Sn Sn P
MnSn2P crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one MnSn2P cluster. Mn(1) is bonded in a distorted single-bond geometry to one P(1) atom. The Mn(1)-P(1) bond length is 2.07 Å. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a single-bond geometry to one Sn(2) atom. The Sn(1)-Sn(2) bond length is 0.61 Å. In the second Sn site, Sn(2) is bonded in a distorted water-like geometry to one Sn(1) and one P(1) atom. The Sn(2)-P(1) bond length is 1.75 Å. P(1) is bonded in a 2-coordinate geometry to one Mn(1) and one Sn(2) atom.