data_VCrFe2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.47
_cell_length_b   2.47
_cell_length_c   8.07
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   107.79
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCrFe2
_chemical_formula_sum   'V1 Cr1 Fe2'
_cell_volume   47.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.05  1.0
  Cr  Cr0  1  0.46  0.0  0.97  1.0
  Fe  Fe1  1  0.0  0.0  0.06  1.0
  Fe  Fe2  1  0.46  0.0  0.09  1.0

data_VCrFe2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.47
_cell_length_b   2.47
_cell_length_c   8.07
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   107.79
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCrFe2
_chemical_formula_sum   'V1 Cr1 Fe2'
_cell_volume   47.06
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.05  1.0
  Cr  Cr1  1  0.46  0.0  0.97  1.0
  Fe  Fe2  1  0.0  0.0  0.06  1.0
  Fe  Fe3  1  0.46  0.0  0.09  1.0

V Cr Fe Fe
FeVFeCr crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ferrovanadium molecule and one FeCr cluster. In the FeCr cluster, Cr(1) is bonded in a distorted single-bond geometry to one Fe(2) atom. The Cr(1)-Fe(2) bond length is 1.02 Å. Fe(2) is bonded in a single-bond geometry to one Cr(1) atom.