data_ZnW2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.65
_cell_length_b   9.65
_cell_length_c   9.65
_cell_angle_alpha   17.25
_cell_angle_beta   17.25
_cell_angle_gamma   17.25
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnW2Cl
_chemical_formula_sum   'Zn1 W2 Cl1'
_cell_volume   69.03
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.0  1.0  1.0
  W  W1  1  0.0  0.0  0.44  1.0
  W  W2  1  0.0  0.0  0.3  1.0
  Cl  Cl0  1  0.0  0.0  0.56  1.0

data_ZnW2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.02
_cell_length_b   2.9
_cell_length_c   9.65
_cell_angle_alpha   90.0
_cell_angle_beta   99.97
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZnW2Cl
_chemical_formula_sum   'Zn2 W4 Cl2'
_cell_volume   138.06
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  2  0.0  0.0  0.0  1.0
  W  W1  2  0.0  0.0  0.56  1.0
  W  W2  2  0.0  0.0  0.7  1.0
  Cl  Cl3  2  0.0  0.0  0.44  1.0

Zn W W Cl
W2ZnCl crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two W2ZnCl clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted single-bond geometry to one W(2) and one Cl(1) atom. The W(1)-W(2) bond length is 1.30 Å. The W(1)-Cl(1) bond length is 1.18 Å. In the second W site, W(2) is bonded in a distorted linear geometry to one W(1) and one Zn(1) atom. The W(2)-Zn(1) bond length is 2.92 Å. Zn(1) is bonded in a distorted single-bond geometry to one W(2) atom. Cl(1) is bonded in a single-bond geometry to one W(1) atom.