data_NaGePd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.9
_cell_length_b   5.9
_cell_length_c   5.9
_cell_angle_alpha   147.7
_cell_angle_beta   147.7
_cell_angle_gamma   46.33
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaGePd
_chemical_formula_sum   'Na1 Ge1 Pd1'
_cell_volume   58.56
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na1  1  0.0  0.0  0.6  1.0
  Ge  Ge0  1  0.0  0.0  0.36  1.0
  Pd  Pd2  1  0.0  0.0  0.89  1.0

data_NaGePd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.65
_cell_length_b   4.65
_cell_length_c   5.9
_cell_angle_alpha   90.0
_cell_angle_beta   113.17
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   NaGePd
_chemical_formula_sum   'Na2 Ge2 Pd2'
_cell_volume   117.11
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  2  0.0  0.0  0.4  1.0
  Ge  Ge1  2  0.0  0.0  0.64  1.0
  Pd  Pd2  2  0.0  0.0  0.11  1.0

Na Ge Pd
NaPdGe crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two NaPdGe clusters. Na(1) is bonded in a linear geometry to one Pd(1) and one Ge(1) atom. The Na(1)-Pd(1) bond length is 1.68 Å. The Na(1)-Ge(1) bond length is 1.43 Å. Pd(1) is bonded in a single-bond geometry to one Na(1) atom. Ge(1) is bonded in a single-bond geometry to one Na(1) atom.