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1
1605-1608
7 A solution is obtained by mixing 300 g of 25% solution and 400 g of 40% solution by mass Calculate the mass percentage of the resulting solution 1 8 An antifreeze solution is prepared from 222
1
1606-1609
Calculate the mass percentage of the resulting solution 1 8 An antifreeze solution is prepared from 222 6 g of ethylene glycol (C2H6O2) and 200 g of water
1
1607-1610
1 8 An antifreeze solution is prepared from 222 6 g of ethylene glycol (C2H6O2) and 200 g of water Calculate the molality of the solution
1
1608-1611
8 An antifreeze solution is prepared from 222 6 g of ethylene glycol (C2H6O2) and 200 g of water Calculate the molality of the solution If the density of the solution is 1
1
1609-1612
6 g of ethylene glycol (C2H6O2) and 200 g of water Calculate the molality of the solution If the density of the solution is 1 072 g mL–1, then what shall be the molarity of the solution
1
1610-1613
Calculate the molality of the solution If the density of the solution is 1 072 g mL–1, then what shall be the molarity of the solution 1
1
1611-1614
If the density of the solution is 1 072 g mL–1, then what shall be the molarity of the solution 1 9 A sample of drinking water was found to be severely contaminated with chloroform (CHCl3) supposed to be a carcinogen
1
1612-1615
072 g mL–1, then what shall be the molarity of the solution 1 9 A sample of drinking water was found to be severely contaminated with chloroform (CHCl3) supposed to be a carcinogen The level of contamination was 15 ppm (by mass): (i) express this in percent by mass (ii) determine the molality of chloroform in the water sample
1
1613-1616
1 9 A sample of drinking water was found to be severely contaminated with chloroform (CHCl3) supposed to be a carcinogen The level of contamination was 15 ppm (by mass): (i) express this in percent by mass (ii) determine the molality of chloroform in the water sample 1
1
1614-1617
9 A sample of drinking water was found to be severely contaminated with chloroform (CHCl3) supposed to be a carcinogen The level of contamination was 15 ppm (by mass): (i) express this in percent by mass (ii) determine the molality of chloroform in the water sample 1 10 What role does the molecular interaction play in a solution of alcohol and water
1
1615-1618
The level of contamination was 15 ppm (by mass): (i) express this in percent by mass (ii) determine the molality of chloroform in the water sample 1 10 What role does the molecular interaction play in a solution of alcohol and water 1
1
1616-1619
1 10 What role does the molecular interaction play in a solution of alcohol and water 1 11 Why do gases always tend to be less soluble in liquids as the temperature is raised
1
1617-1620
10 What role does the molecular interaction play in a solution of alcohol and water 1 11 Why do gases always tend to be less soluble in liquids as the temperature is raised 1
1
1618-1621
1 11 Why do gases always tend to be less soluble in liquids as the temperature is raised 1 12 State Henry’s law and mention some important applications
1
1619-1622
11 Why do gases always tend to be less soluble in liquids as the temperature is raised 1 12 State Henry’s law and mention some important applications 1
1
1620-1623
1 12 State Henry’s law and mention some important applications 1 13 The partial pressure of ethane over a solution containing 6
1
1621-1624
12 State Henry’s law and mention some important applications 1 13 The partial pressure of ethane over a solution containing 6 56 × 10–3 g of ethane is 1 bar
1
1622-1625
1 13 The partial pressure of ethane over a solution containing 6 56 × 10–3 g of ethane is 1 bar If the solution contains 5
1
1623-1626
13 The partial pressure of ethane over a solution containing 6 56 × 10–3 g of ethane is 1 bar If the solution contains 5 00 × 10–2 g of ethane, then what shall be the partial pressure of the gas
1
1624-1627
56 × 10–3 g of ethane is 1 bar If the solution contains 5 00 × 10–2 g of ethane, then what shall be the partial pressure of the gas 1
1
1625-1628
If the solution contains 5 00 × 10–2 g of ethane, then what shall be the partial pressure of the gas 1 14 What is meant by positive and negative deviations from Raoult's law and how is the sign of DmixH related to positive and negative deviations from Raoult's law
1
1626-1629
00 × 10–2 g of ethane, then what shall be the partial pressure of the gas 1 14 What is meant by positive and negative deviations from Raoult's law and how is the sign of DmixH related to positive and negative deviations from Raoult's law 1
1
1627-1630
1 14 What is meant by positive and negative deviations from Raoult's law and how is the sign of DmixH related to positive and negative deviations from Raoult's law 1 15 An aqueous solution of 2% non-volatile solute exerts a pressure of 1
1
1628-1631
14 What is meant by positive and negative deviations from Raoult's law and how is the sign of DmixH related to positive and negative deviations from Raoult's law 1 15 An aqueous solution of 2% non-volatile solute exerts a pressure of 1 004 bar at the normal boiling point of the solvent
1
1629-1632
1 15 An aqueous solution of 2% non-volatile solute exerts a pressure of 1 004 bar at the normal boiling point of the solvent What is the molar mass of the solute
1
1630-1633
15 An aqueous solution of 2% non-volatile solute exerts a pressure of 1 004 bar at the normal boiling point of the solvent What is the molar mass of the solute 1
1
1631-1634
004 bar at the normal boiling point of the solvent What is the molar mass of the solute 1 16 Heptane and octane form an ideal solution
1
1632-1635
What is the molar mass of the solute 1 16 Heptane and octane form an ideal solution At 373 K, the vapour pressures of the two liquid components are 105
1
1633-1636
1 16 Heptane and octane form an ideal solution At 373 K, the vapour pressures of the two liquid components are 105 2 kPa and 46
1
1634-1637
16 Heptane and octane form an ideal solution At 373 K, the vapour pressures of the two liquid components are 105 2 kPa and 46 8 kPa respectively
1
1635-1638
At 373 K, the vapour pressures of the two liquid components are 105 2 kPa and 46 8 kPa respectively What will be the vapour pressure of a mixture of 26
1
1636-1639
2 kPa and 46 8 kPa respectively What will be the vapour pressure of a mixture of 26 0 g of heptane and 35 g of octane
1
1637-1640
8 kPa respectively What will be the vapour pressure of a mixture of 26 0 g of heptane and 35 g of octane 1
1
1638-1641
What will be the vapour pressure of a mixture of 26 0 g of heptane and 35 g of octane 1 17 The vapour pressure of water is 12
1
1639-1642
0 g of heptane and 35 g of octane 1 17 The vapour pressure of water is 12 3 kPa at 300 K
1
1640-1643
1 17 The vapour pressure of water is 12 3 kPa at 300 K Calculate vapour pressure of 1 molal solution of a non-volatile solute in it
1
1641-1644
17 The vapour pressure of water is 12 3 kPa at 300 K Calculate vapour pressure of 1 molal solution of a non-volatile solute in it 1
1
1642-1645
3 kPa at 300 K Calculate vapour pressure of 1 molal solution of a non-volatile solute in it 1 18 Calculate the mass of a non-volatile solute (molar mass 40 g mol–1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%
1
1643-1646
Calculate vapour pressure of 1 molal solution of a non-volatile solute in it 1 18 Calculate the mass of a non-volatile solute (molar mass 40 g mol–1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80% 1
1
1644-1647
1 18 Calculate the mass of a non-volatile solute (molar mass 40 g mol–1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80% 1 19 A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2
1
1645-1648
18 Calculate the mass of a non-volatile solute (molar mass 40 g mol–1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80% 1 19 A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2 8 kPa at 298 K
1
1646-1649
1 19 A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2 8 kPa at 298 K Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2
1
1647-1650
19 A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2 8 kPa at 298 K Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2 9 kPa at 298 K
1
1648-1651
8 kPa at 298 K Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2 9 kPa at 298 K Calculate: (i) molar mass of the solute (ii) vapour pressure of water at 298 K
1
1649-1652
Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2 9 kPa at 298 K Calculate: (i) molar mass of the solute (ii) vapour pressure of water at 298 K 1
1
1650-1653
9 kPa at 298 K Calculate: (i) molar mass of the solute (ii) vapour pressure of water at 298 K 1 20 A 5% solution (by mass) of cane sugar in water has freezing point of 271K
1
1651-1654
Calculate: (i) molar mass of the solute (ii) vapour pressure of water at 298 K 1 20 A 5% solution (by mass) of cane sugar in water has freezing point of 271K Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273
1
1652-1655
1 20 A 5% solution (by mass) of cane sugar in water has freezing point of 271K Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273 15 K
1
1653-1656
20 A 5% solution (by mass) of cane sugar in water has freezing point of 271K Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273 15 K 1
1
1654-1657
Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273 15 K 1 21 Two elements A and B form compounds having formula AB2 and AB4
1
1655-1658
15 K 1 21 Two elements A and B form compounds having formula AB2 and AB4 When dissolved in 20 g of benzene (C6H6), 1 g of AB2 lowers the freezing point by 2
1
1656-1659
1 21 Two elements A and B form compounds having formula AB2 and AB4 When dissolved in 20 g of benzene (C6H6), 1 g of AB2 lowers the freezing point by 2 3 K whereas 1
1
1657-1660
21 Two elements A and B form compounds having formula AB2 and AB4 When dissolved in 20 g of benzene (C6H6), 1 g of AB2 lowers the freezing point by 2 3 K whereas 1 0 g of AB4 lowers it by 1
1
1658-1661
When dissolved in 20 g of benzene (C6H6), 1 g of AB2 lowers the freezing point by 2 3 K whereas 1 0 g of AB4 lowers it by 1 3 K
1
1659-1662
3 K whereas 1 0 g of AB4 lowers it by 1 3 K The molar depression constant for benzene is 5
1
1660-1663
0 g of AB4 lowers it by 1 3 K The molar depression constant for benzene is 5 1 K kg mol–1
1
1661-1664
3 K The molar depression constant for benzene is 5 1 K kg mol–1 Calculate atomic masses of A and B
1
1662-1665
The molar depression constant for benzene is 5 1 K kg mol–1 Calculate atomic masses of A and B Rationalised 2023-24 29 Solutions 1
1
1663-1666
1 K kg mol–1 Calculate atomic masses of A and B Rationalised 2023-24 29 Solutions 1 22 At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4
1
1664-1667
Calculate atomic masses of A and B Rationalised 2023-24 29 Solutions 1 22 At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4 98 bar
1
1665-1668
Rationalised 2023-24 29 Solutions 1 22 At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4 98 bar If the osmotic pressure of the solution is 1
1
1666-1669
22 At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4 98 bar If the osmotic pressure of the solution is 1 52 bars at the same temperature, what would be its concentration
1
1667-1670
98 bar If the osmotic pressure of the solution is 1 52 bars at the same temperature, what would be its concentration 1
1
1668-1671
If the osmotic pressure of the solution is 1 52 bars at the same temperature, what would be its concentration 1 23 Suggest the most important type of intermolecular attractive interaction in the following pairs
1
1669-1672
52 bars at the same temperature, what would be its concentration 1 23 Suggest the most important type of intermolecular attractive interaction in the following pairs (i) n-hexane and n-octane (ii) I2 and CCl4 (iii) NaClO4 and water (iv) methanol and acetone (v) acetonitrile (CH3CN) and acetone (C3H6O)
1
1670-1673
1 23 Suggest the most important type of intermolecular attractive interaction in the following pairs (i) n-hexane and n-octane (ii) I2 and CCl4 (iii) NaClO4 and water (iv) methanol and acetone (v) acetonitrile (CH3CN) and acetone (C3H6O) 1
1
1671-1674
23 Suggest the most important type of intermolecular attractive interaction in the following pairs (i) n-hexane and n-octane (ii) I2 and CCl4 (iii) NaClO4 and water (iv) methanol and acetone (v) acetonitrile (CH3CN) and acetone (C3H6O) 1 24 Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-octane and explain
1
1672-1675
(i) n-hexane and n-octane (ii) I2 and CCl4 (iii) NaClO4 and water (iv) methanol and acetone (v) acetonitrile (CH3CN) and acetone (C3H6O) 1 24 Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-octane and explain Cyclohexane, KCl, CH3OH, CH3CN
1
1673-1676
1 24 Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-octane and explain Cyclohexane, KCl, CH3OH, CH3CN 1
1
1674-1677
24 Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-octane and explain Cyclohexane, KCl, CH3OH, CH3CN 1 25 Amongst the following compounds, identify which are insoluble, partially soluble and highly soluble in water
1
1675-1678
Cyclohexane, KCl, CH3OH, CH3CN 1 25 Amongst the following compounds, identify which are insoluble, partially soluble and highly soluble in water (i) phenol (ii) toluene (iii) formic acid (iv) ethylene glycol (v) chloroform (vi) pentanol
1
1676-1679
1 25 Amongst the following compounds, identify which are insoluble, partially soluble and highly soluble in water (i) phenol (ii) toluene (iii) formic acid (iv) ethylene glycol (v) chloroform (vi) pentanol 1
1
1677-1680
25 Amongst the following compounds, identify which are insoluble, partially soluble and highly soluble in water (i) phenol (ii) toluene (iii) formic acid (iv) ethylene glycol (v) chloroform (vi) pentanol 1 26 If the density of some lake water is 1
1
1678-1681
(i) phenol (ii) toluene (iii) formic acid (iv) ethylene glycol (v) chloroform (vi) pentanol 1 26 If the density of some lake water is 1 25g mL–1 and contains 92 g of Na+ ions per kg of water, calculate the molarity of Na+ ions in the lake
1
1679-1682
1 26 If the density of some lake water is 1 25g mL–1 and contains 92 g of Na+ ions per kg of water, calculate the molarity of Na+ ions in the lake 1
1
1680-1683
26 If the density of some lake water is 1 25g mL–1 and contains 92 g of Na+ ions per kg of water, calculate the molarity of Na+ ions in the lake 1 27 If the solubility product of CuS is 6 × 10–16, calculate the maximum molarity of CuS in aqueous solution
1
1681-1684
25g mL–1 and contains 92 g of Na+ ions per kg of water, calculate the molarity of Na+ ions in the lake 1 27 If the solubility product of CuS is 6 × 10–16, calculate the maximum molarity of CuS in aqueous solution 1
1
1682-1685
1 27 If the solubility product of CuS is 6 × 10–16, calculate the maximum molarity of CuS in aqueous solution 1 28 Calculate the mass percentage of aspirin (C9H8O4) in acetonitrile (CH3CN) when 6
1
1683-1686
27 If the solubility product of CuS is 6 × 10–16, calculate the maximum molarity of CuS in aqueous solution 1 28 Calculate the mass percentage of aspirin (C9H8O4) in acetonitrile (CH3CN) when 6 5 g of C9H8O4 is dissolved in 450 g of CH3CN
1
1684-1687
1 28 Calculate the mass percentage of aspirin (C9H8O4) in acetonitrile (CH3CN) when 6 5 g of C9H8O4 is dissolved in 450 g of CH3CN 1
1
1685-1688
28 Calculate the mass percentage of aspirin (C9H8O4) in acetonitrile (CH3CN) when 6 5 g of C9H8O4 is dissolved in 450 g of CH3CN 1 29 Nalorphene (C19H21NO3), similar to morphine, is used to combat withdrawal symptoms in narcotic users
1
1686-1689
5 g of C9H8O4 is dissolved in 450 g of CH3CN 1 29 Nalorphene (C19H21NO3), similar to morphine, is used to combat withdrawal symptoms in narcotic users Dose of nalorphene generally given is 1
1
1687-1690
1 29 Nalorphene (C19H21NO3), similar to morphine, is used to combat withdrawal symptoms in narcotic users Dose of nalorphene generally given is 1 5 mg
1
1688-1691
29 Nalorphene (C19H21NO3), similar to morphine, is used to combat withdrawal symptoms in narcotic users Dose of nalorphene generally given is 1 5 mg Calculate the mass of 1
1
1689-1692
Dose of nalorphene generally given is 1 5 mg Calculate the mass of 1 5 ´ 10–3 m aqueous solution required for the above dose
1
1690-1693
5 mg Calculate the mass of 1 5 ´ 10–3 m aqueous solution required for the above dose 1
1
1691-1694
Calculate the mass of 1 5 ´ 10–3 m aqueous solution required for the above dose 1 30 Calculate the amount of benzoic acid (C6H5COOH) required for preparing 250 mL of 0
1
1692-1695
5 ´ 10–3 m aqueous solution required for the above dose 1 30 Calculate the amount of benzoic acid (C6H5COOH) required for preparing 250 mL of 0 15 M solution in methanol
1
1693-1696
1 30 Calculate the amount of benzoic acid (C6H5COOH) required for preparing 250 mL of 0 15 M solution in methanol 1
1
1694-1697
30 Calculate the amount of benzoic acid (C6H5COOH) required for preparing 250 mL of 0 15 M solution in methanol 1 31 The depression in freezing point of water observed for the same amount of acetic acid, trichloroacetic acid and trifluoroacetic acid increases in the order given above
1
1695-1698
15 M solution in methanol 1 31 The depression in freezing point of water observed for the same amount of acetic acid, trichloroacetic acid and trifluoroacetic acid increases in the order given above Explain briefly
1
1696-1699
1 31 The depression in freezing point of water observed for the same amount of acetic acid, trichloroacetic acid and trifluoroacetic acid increases in the order given above Explain briefly 1
1
1697-1700
31 The depression in freezing point of water observed for the same amount of acetic acid, trichloroacetic acid and trifluoroacetic acid increases in the order given above Explain briefly 1 32 Calculate the depression in the freezing point of water when 10 g of CH3CH2CHClCOOH is added to 250 g of water
1
1698-1701
Explain briefly 1 32 Calculate the depression in the freezing point of water when 10 g of CH3CH2CHClCOOH is added to 250 g of water Ka = 1
1
1699-1702
1 32 Calculate the depression in the freezing point of water when 10 g of CH3CH2CHClCOOH is added to 250 g of water Ka = 1 4 × 10–3, Kf = 1
1
1700-1703
32 Calculate the depression in the freezing point of water when 10 g of CH3CH2CHClCOOH is added to 250 g of water Ka = 1 4 × 10–3, Kf = 1 86 K kg mol–1
1
1701-1704
Ka = 1 4 × 10–3, Kf = 1 86 K kg mol–1 1
1
1702-1705
4 × 10–3, Kf = 1 86 K kg mol–1 1 33 19
1
1703-1706
86 K kg mol–1 1 33 19 5 g of CH2FCOOH is dissolved in 500 g of water
1
1704-1707
1 33 19 5 g of CH2FCOOH is dissolved in 500 g of water The depression in the freezing point of water observed is 1