Cd2C4H4S3(N3O2)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one N(1), one N(2), one N(6), one S(1), and one O(3) atom to form distorted CdSN3O trigonal bipyramids that share  a cornercorner with one S(2)O4 tetrahedra. The Cd(1)-N(1) bond length is 2.30 Å. The Cd(1)-N(2) bond length is 2.35 Å. The Cd(1)-N(6) bond length is 2.28 Å. The Cd(1)-S(1) bond length is 2.67 Å. The Cd(1)-O(3) bond length is 2.37 Å. In the second Cd site, Cd(2) is bonded in a 5-coordinate geometry to one N(4), one S(1), one S(3), one O(1), and one O(4) atom. The Cd(2)-N(4) bond length is 2.34 Å. The Cd(2)-S(1) bond length is 2.69 Å. The Cd(2)-S(3) bond length is 2.50 Å. The Cd(2)-O(1) bond length is 2.30 Å. The Cd(2)-O(4) bond length is 2.31 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-N(3) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one N(2), one N(3), and one S(1) atom. The C(2)-N(2) bond length is 1.34 Å. The C(2)-N(3) bond length is 1.37 Å. The C(2)-S(1) bond length is 1.72 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one N(5), one N(6), and one S(3) atom. The C(3)-N(5) bond length is 1.35 Å. The C(3)-N(6) bond length is 1.37 Å. The C(3)-S(3) bond length is 1.72 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(4) atom. The C(4)-N(4) bond length is 1.33 Å. The C(4)-N(6) bond length is 1.36 Å. The C(4)-H(4) bond length is 1.08 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.38 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Cd(1), one C(2), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one H(2) atom. The N(3)-H(2) bond length is 1.05 Å. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one Cd(2), one C(4), and one N(5) atom. The N(4)-N(5) bond length is 1.36 Å. In the fifth N site, N(5) is bonded in a 2-coordinate geometry to one C(3), one N(4), and one H(3) atom. The N(5)-H(3) bond length is 1.05 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(3), and one C(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) and one O(2) atom. The H(2)-O(2) bond length is 1.73 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one N(5) and one O(2) atom. The H(3)-O(2) bond length is 1.67 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Cd(1), one Cd(2), and one C(2) atom. In the second S site, S(2) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(1)SN3O trigonal bipyramid. The S(2)-O(1) bond length is 1.50 Å. The S(2)-O(2) bond length is 1.50 Å. The S(2)-O(3) bond length is 1.49 Å. The S(2)-O(4) bond length is 1.47 Å. In the third S site, S(3) is bonded in a water-like geometry to one Cd(2) and one C(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one S(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one H(2), one H(3), and one S(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Cd(1) and one S(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Cd(2) and one S(2) atom. Linkers: 4 S=C1[N]N=CN1 ,4 S=C1N=C[N]N1. Metal clusters: 8 [Cd]. The MOF has largest included sphere 1.86 A, density 3.01 g/cm3, surface area 2375.93 m2/g, accessible volume 0.05 cm3/g