LiC5N2H10(CH2)3(CH3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, four 02329_fluka molecules, and one LiC5N2H10 cluster. In the LiC5N2H10 cluster, Li(1) is bonded in a trigonal planar geometry to one N(2) and two equivalent N(1) atoms. The Li(1)-N(2) bond length is 2.12 Å. There is one shorter (2.02 Å) and one longer (2.04 Å) Li(1)-N(1) bond length. There are five inequivalent C sites. In the first C site, C(10) is bonded to one N(2), one H(20), one H(21), and one H(22) atom to form corner-sharing CH3N tetrahedra. The C(10)-N(2) bond length is 1.47 Å. The C(10)-H(20) bond length is 1.10 Å. The C(10)-H(21) bond length is 1.10 Å. The C(10)-H(22) bond length is 1.11 Å. In the second C site, C(1) is bonded in a 2-coordinate geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.46 Å. The C(1)-H(1) bond length is 1.12 Å. In the third C site, C(5) is bonded in a distorted water-like geometry to one N(1) and one H(8) atom. The C(5)-N(1) bond length is 1.46 Å. The C(5)-H(8) bond length is 1.12 Å. In the fourth C site, C(9) is bonded to one N(2), one H(17), one H(18), and one H(19) atom to form corner-sharing CH3N tetrahedra. The C(9)-N(2) bond length is 1.47 Å. The C(9)-H(17) bond length is 1.10 Å. The C(9)-H(18) bond length is 1.11 Å. The C(9)-H(19) bond length is 1.10 Å. In the fifth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(15), and one H(16) atom. The C(8)-N(2) bond length is 1.47 Å. The C(8)-H(15) bond length is 1.10 Å. The C(8)-H(16) bond length is 1.11 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent Li(1), one C(1), and one C(5) atom to form NLi2C2 tetrahedra that share corners with two equivalent N(2)LiC3 tetrahedra and  an edgeedge with one N(1)Li2C2 tetrahedra. In the second N site, N(2) is bonded to one Li(1), one C(10), one C(8), and one C(9) atom to form corner-sharing NLiC3 tetrahedra. There are ten inequivalent H sites. In the first H site, H(16) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(17) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(18) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(19) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(21) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(22) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(8) atom. Linkers: 1 CN(C)CCN(C)C. Metal clusters: 2 [Li]. The MOF has largest included sphere 2.06 A, density 1.09 g/cm3, surface area 7271.72 m2/g, accessible volume 0.13 cm3/g