LaC21H18(NO2)6LaC21H21(NO2)6(CH)6(CH3)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, six 02329_fluka molecules, two LaC21H18(NO2)6 clusters, and two LaC21H21(NO2)6 clusters. In each LaC21H18(NO2)6 cluster, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The La(1)-O(1) bond length is 2.43 Å. The La(1)-O(10) bond length is 2.64 Å. The La(1)-O(11) bond length is 2.64 Å. The La(1)-O(12) bond length is 2.64 Å. The La(1)-O(2) bond length is 2.43 Å. The La(1)-O(3) bond length is 2.43 Å. The La(1)-O(4) bond length is 2.61 Å. The La(1)-O(5) bond length is 2.61 Å. The La(1)-O(6) bond length is 2.61 Å. There are fifteen inequivalent C sites. In the first C site, C(10) is bonded in a distorted trigonal planar geometry to one C(13,15); one C(7,9); and one H(7,9) atom. The C(10)-C(13,15) bond length is 1.38 Å. The C(10)-C(7,9) bond length is 1.41 Å. The C(10)-H(7,9) bond length is 1.09 Å. In the second C site, C(11,12) is bonded in a distorted trigonal planar geometry to one C(14), one C(8), and one H(8) atom. The C(11,12)-C(14) bond length is 1.38 Å. The C(11,12)-C(8) bond length is 1.41 Å. The C(11,12)-H(8) bond length is 1.09 Å. In the third C site, C(13,15) is bonded in a distorted trigonal planar geometry to one C(10), one C(16), and one H(10) atom. The C(13,15)-C(16) bond length is 1.42 Å. The C(13,15)-H(10) bond length is 1.09 Å. In the fourth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(17,18); and one H(11,12) atom. The C(14)-C(17,18) bond length is 1.42 Å. The C(14)-H(11,12) bond length is 1.09 Å. In the fifth C site, C(16) is bonded in a trigonal planar geometry to one C(1,3); one C(13,15); and one C(19) atom. The C(16)-C(1,3) bond length is 1.44 Å. The C(16)-C(19) bond length is 1.42 Å. In the sixth C site, C(17,18) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(20) atom. The C(17,18)-C(2) bond length is 1.44 Å. The C(17,18)-C(20) bond length is 1.42 Å. In the seventh C site, C(19) is bonded in a distorted trigonal planar geometry to one C(16); one N(4,5,6); and one H(13,14,15) atom. The C(19)-N(4,5,6) bond length is 1.31 Å. The C(19)-H(13,14,15) bond length is 1.10 Å. In the eighth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(17,18); one N(4,5,6); and one H(13,14,15) atom. The C(20)-N(4,5,6) bond length is 1.31 Å. The C(20)-H(13,14,15) bond length is 1.10 Å. In the ninth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(17,18); one N(4,5,6); and one H(13,14,15) atom. The C(21)-C(17,18) bond length is 1.42 Å. The C(21)-N(4,5,6) bond length is 1.31 Å. The C(21)-H(13,14,15) bond length is 1.10 Å. In the tenth C site, C(22) is bonded in a distorted water-like geometry to one N(4,5,6) and one H(16,17,18) atom. The C(22)-N(4,5,6) bond length is 1.46 Å. The C(22)-H(16,17,18) bond length is 1.10 Å. In the eleventh C site, C(23,24) is bonded in a distorted water-like geometry to one N(4,5,6) and one H(16,17,18) atom. The C(23,24)-N(4,5,6) bond length is 1.46 Å. The C(23,24)-H(16,17,18) bond length is 1.10 Å. In the twelfth C site, C(1,3) is bonded in a distorted single-bond geometry to one C(16) and one O(1) atom. The C(1,3)-O(1) bond length is 1.31 Å. In the thirteenth C site, C(2) is bonded in a distorted single-bond geometry to one C(17,18) and one O(2) atom. The C(2)-O(2) bond length is 1.31 Å. In the fourteenth C site, C(7,9) is bonded in a distorted single-bond geometry to one C(10) and one H(4) atom. The C(7,9)-H(4) bond length is 1.09 Å. In the fifteenth C site, C(8) is bonded in a distorted single-bond geometry to one C(11,12) and one H(5,6) atom. The C(8)-H(5,6) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1,2,3) is bonded in a trigonal planar geometry to one O(10); one O(4); and one O(7,8) atom. The N(1,2,3)-O(10) bond length is 1.29 Å. The N(1,2,3)-O(4) bond length is 1.29 Å. The N(1,2,3)-O(7,8) bond length is 1.23 Å. In the second N site, N(4,5,6) is bonded in a trigonal planar geometry to one C(19), one C(22), and one H(49) atom. The N(4,5,6)-H(49) bond length is 1.04 Å. There are ten inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(7,9) atom. In the second H site, H(5,6) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(7,9) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(11,12) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(13,15) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(13,14,15) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(16,17,18) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(49) is bonded in a single-bond geometry to one N(4,5,6) atom. In the tenth H site, H(50,51) is bonded in a single-bond geometry to one N(4,5,6) atom. The H(50,51)-N(4,5,6) bond length is 1.04 Å. There are eleven inequivalent O sites. In the first O site, O(10) is bonded in a distorted single-bond geometry to one La(1) and one N(1,2,3) atom. In the second O site, O(12) is bonded in a distorted single-bond geometry to one La(1) and one N(1,2,3) atom. The O(12)-N(1,2,3) bond length is 1.29 Å. In the third O site, O(11) is bonded in a distorted single-bond geometry to one La(1) and one N(1,2,3) atom. The O(11)-N(1,2,3) bond length is 1.29 Å. In the fourth O site, O(1) is bonded in a distorted single-bond geometry to one La(1) and one C(1,3) atom. In the fifth O site, O(2) is bonded in a distorted single-bond geometry to one La(1) and one C(2) atom. In the sixth O site, O(3) is bonded in a distorted single-bond geometry to one La(1) and one C(1,3) atom. The O(3)-C(1,3) bond length is 1.31 Å. In the seventh O site, O(4) is bonded in a distorted single-bond geometry to one La(1) and one N(1,2,3) atom. In the eighth O site, O(5) is bonded in a distorted single-bond geometry to one La(1) and one N(1,2,3) atom. The O(5)-N(1,2,3) bond length is 1.29 Å. In the ninth O site, O(6) is bonded in a distorted single-bond geometry to one La(1) and one N(1,2,3) atom. The O(6)-N(1,2,3) bond length is 1.29 Å. In the tenth O site, O(7,8) is bonded in a single-bond geometry to one N(1,2,3) atom. In the eleventh O site, O(9) is bonded in a single-bond geometry to one N(1,2,3) atom. The O(9)-N(1,2,3) bond length is 1.23 Å. In each LaC21H21(NO2)6 cluster, La(2) is bonded in a 9-coordinate geometry to one O(13), one O(14), one O(15), one O(16), one O(17), one O(18), one O(22), one O(23), and one O(24) atom. The La(2)-O(13) bond length is 2.41 Å. The La(2)-O(14) bond length is 2.41 Å. The La(2)-O(15) bond length is 2.41 Å. The La(2)-O(16) bond length is 2.64 Å. The La(2)-O(17) bond length is 2.64 Å. The La(2)-O(18) bond length is 2.64 Å. The La(2)-O(22) bond length is 2.66 Å. The La(2)-O(23) bond length is 2.66 Å. The La(2)-O(24) bond length is 2.66 Å. There are eleven inequivalent C sites. In the first C site, C(28,29) is bonded in a distorted trigonal non-coplanar geometry to one N(7,8,9); one H(28,29,30); and one H(31,32,33) atom. The C(28,29)-N(7,8,9) bond length is 1.45 Å. The C(28,29)-H(28,29,30) bond length is 1.10 Å. The C(28,29)-H(31,32,33) bond length is 1.10 Å. In the second C site, C(30) is bonded in a distorted trigonal non-coplanar geometry to one N(7,8,9); one H(28,29,30); and one H(31,32,33) atom. The C(30)-N(7,8,9) bond length is 1.45 Å. The C(30)-H(28,29,30) bond length is 1.10 Å. The C(30)-H(31,32,33) bond length is 1.10 Å. In the third C site, C(31,32) is bonded in a distorted bent 120 degrees geometry to one C(34,35,36); one N(7,8,9); and one H(34,35,36) atom. The C(31,32)-C(34,35,36) bond length is 1.42 Å. The C(31,32)-N(7,8,9) bond length is 1.31 Å. The C(31,32)-H(34,35,36) bond length is 1.10 Å. In the fourth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(34,35,36); one N(7,8,9); and one H(34,35,36) atom. The C(33)-C(34,35,36) bond length is 1.42 Å. The C(33)-N(7,8,9) bond length is 1.31 Å. The C(33)-H(34,35,36) bond length is 1.10 Å. In the fifth C site, C(34,35,36) is bonded in a trigonal planar geometry to one C(31,32); one C(37,38); and one C(49,50,51) atom. The C(34,35,36)-C(37,38) bond length is 1.42 Å. The C(34,35,36)-C(49,50,51) bond length is 1.44 Å. In the sixth C site, C(37,38) is bonded in a distorted single-bond geometry to one C(34,35,36); one C(40,41,42); and one H(37,38,39) atom. The C(37,38)-C(40,41,42) bond length is 1.38 Å. The C(37,38)-H(37,38,39) bond length is 1.09 Å. In the seventh C site, C(39) is bonded in a distorted single-bond geometry to one C(34,35,36); one C(40,41,42); and one H(37,38,39) atom. The C(39)-C(34,35,36) bond length is 1.42 Å. The C(39)-C(40,41,42) bond length is 1.38 Å. The C(39)-H(37,38,39) bond length is 1.09 Å. In the eighth C site, C(40,41,42) is bonded in a distorted trigonal planar geometry to one C(37,38); one C(43,44); and one H(40,41) atom. The C(40,41,42)-C(43,44) bond length is 1.41 Å. The C(40,41,42)-H(40,41) bond length is 1.09 Å. In the ninth C site, C(43,44) is bonded in a distorted single-bond geometry to one C(40,41,42) and one H(43,44,45) atom. The C(43,44)-H(43,44,45) bond length is 1.09 Å. In the tenth C site, C(45) is bonded in a distorted single-bond geometry to one C(40,41,42) and one H(43,44,45) atom. The C(45)-C(40,41,42) bond length is 1.41 Å. The C(45)-H(43,44,45) bond length is 1.09 Å. In the eleventh C site, C(49,50,51) is bonded in a distorted single-bond geometry to one C(34,35,36) and one O(13) atom. The C(49,50,51)-O(13) bond length is 1.31 Å. There are two inequivalent N sites. In the first N site, N(7,8,9) is bonded in a trigonal planar geometry to one C(28,29); one C(31,32); and one H(52,53) atom. The N(7,8,9)-H(52,53) bond length is 1.03 Å. In the second N site, N(10,11,12) is bonded in a trigonal planar geometry to one O(16), one O(19), and one O(22) atom. The N(10,11,12)-O(16) bond length is 1.28 Å. The N(10,11,12)-O(19) bond length is 1.24 Å. The N(10,11,12)-O(22) bond length is 1.29 Å. There are nine inequivalent H sites. In the first H site, H(28,29,30) is bonded in a single-bond geometry to one C(28,29) atom. In the second H site, H(31,32,33) is bonded in a single-bond geometry to one C(28,29) atom. In the third H site, H(34,35,36) is bonded in a single-bond geometry to one C(31,32) atom. In the fourth H site, H(37,38,39) is bonded in a single-bond geometry to one C(37,38) atom. In the fifth H site, H(40,41) is bonded in a single-bond geometry to one C(40,41,42) atom. In the sixth H site, H(42) is bonded in a single-bond geometry to one C(40,41,42) atom. The H(42)-C(40,41,42) bond length is 1.09 Å. In the seventh H site, H(43,44,45) is bonded in a single-bond geometry to one C(43,44) atom. In the eighth H site, H(52,53) is bonded in a single-bond geometry to one N(7,8,9) atom. In the ninth H site, H(54) is bonded in a single-bond geometry to one N(7,8,9) atom. The H(54)-N(7,8,9) bond length is 1.03 Å. There are twelve inequivalent O sites. In the first O site, O(13) is bonded in a 2-coordinate geometry to one La(2) and one C(49,50,51) atom. In the second O site, O(14) is bonded in a 2-coordinate geometry to one La(2) and one C(49,50,51) atom. The O(14)-C(49,50,51) bond length is 1.31 Å. In the third O site, O(15) is bonded in a 2-coordinate geometry to one La(2) and one C(49,50,51) atom. The O(15)-C(49,50,51) bond length is 1.31 Å. In the fourth O site, O(16) is bonded in a distorted single-bond geometry to one La(2) and one N(10,11,12) atom. In the fifth O site, O(17) is bonded in a distorted single-bond geometry to one La(2) and one N(10,11,12) atom. The O(17)-N(10,11,12) bond length is 1.28 Å. In the sixth O site, O(18) is bonded in a distorted single-bond geometry to one La(2) and one N(10,11,12) atom. The O(18)-N(10,11,12) bond length is 1.28 Å. In the seventh O site, O(19) is bonded in a single-bond geometry to one N(10,11,12) atom. In the eighth O site, O(20) is bonded in a single-bond geometry to one N(10,11,12) atom. The O(20)-N(10,11,12) bond length is 1.24 Å. In the ninth O site, O(21) is bonded in a single-bond geometry to one N(10,11,12) atom. The O(21)-N(10,11,12) bond length is 1.24 Å. In the tenth O site, O(22) is bonded in a distorted single-bond geometry to one La(2) and one N(10,11,12) atom. In the eleventh O site, O(23) is bonded in a distorted single-bond geometry to one La(2) and one N(10,11,12) atom. The O(23)-N(10,11,12) bond length is 1.29 Å. In the twelfth O site, O(24) is bonded in a distorted single-bond geometry to one La(2) and one N(10,11,12) atom. The O(24)-N(10,11,12) bond length is 1.29 Å. Linkers: 3 C[C@H](/[NH]=C/c1ccccc1[O])C/[NH]=C/c1ccccc1[O] ,3 C[C@@H](/[NH]=C/c1ccccc1[O])C/[NH]=C/c1ccccc1[O]. Metal clusters: 4 [O]N1O[La]23([O])([O])([O])(O1)(ON([O])O2)ON([O])O3. RCSR code: hcb. The MOF has largest included sphere 7.96 A, density 1.25 g/cm3, surface area 4475.85 m2/g, accessible volume 0.27 cm3/g