ZnC22H16(NO)4(CH3)2(CH)12 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight 02329_fluka molecules, eight isobutylene molecules, and four ZnC22H16(NO)4 clusters. In each ZnC22H16(NO)4 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent O(2) atoms. Both Zn(1)-N(1) bond lengths are 2.07 Å. Both Zn(1)-O(2) bond lengths are 1.98 Å. There are eleven inequivalent C sites. In the first C site, C(2) is bonded in a distorted water-like geometry to one C(3), one H(4), and one H(5) atom. The C(2)-C(3) bond length is 1.49 Å. The C(2)-H(4) bond length is 1.10 Å. The C(2)-H(5) bond length is 1.10 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one N(2) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-N(2) bond length is 1.37 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one N(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(9) bond length is 1.42 Å. The C(4)-N(1) bond length is 1.39 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(5)-H(6) bond length is 1.09 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(9) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(9) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one N(2) atom. The C(9)-N(2) bond length is 1.39 Å. In the seventh C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one N(2), one H(10), and one H(11) atom. The C(10)-C(11) bond length is 1.51 Å. The C(10)-N(2) bond length is 1.46 Å. The C(10)-H(10) bond length is 1.10 Å. The C(10)-H(11) bond length is 1.10 Å. In the eighth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(13) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(13) bond length is 1.40 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(12) atom. The C(12)-H(12) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(11) and one H(13) atom. The C(13)-H(13) bond length is 1.09 Å. In the eleventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(14)-O(1) bond length is 1.25 Å. The C(14)-O(2) bond length is 1.30 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(3), and one C(9) atom. There are eight inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(14) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(14) atom. Linkers: 2 CCc1nc2ccccc2n1Cc1ccc(Cn2c(CC)nc3ccccc32)cc1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.05 A, density 1.31 g/cm3, surface area 5479.24 m2/g, accessible volume 0.23 cm3/g