CdC20N2H14(O3F2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CdC20N2H14(O3F2)2 cluster. Cd(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(3) atoms. Both Cd(1)-N(1) bond lengths are 2.32 Å. Both Cd(1)-O(1) bond lengths are 2.34 Å. Both Cd(1)-O(3) bond lengths are 2.41 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(3) atom. The C(1)-C(5) bond length is 1.41 Å. The C(1)-C(7) bond length is 1.39 Å. The C(1)-H(3) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(2)-C(5) bond length is 1.46 Å. The C(2)-H(4) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(5), one C(9), and one H(5) atom. The C(3)-C(5) bond length is 1.41 Å. The C(3)-C(9) bond length is 1.39 Å. The C(3)-H(5) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(10) and one F(1,2) atom. The C(4)-C(10) bond length is 1.39 Å. The C(4)-F(1,2) bond length is 1.36 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(1), and one O(2) atom. The C(6)-C(10) bond length is 1.52 Å. The C(6)-O(1) bond length is 1.27 Å. The C(6)-O(2) bond length is 1.26 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one H(6) atom. The C(7)-N(1) bond length is 1.35 Å. The C(7)-H(6) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(10) and one F(1,2) atom. The C(8)-C(10) bond length is 1.39 Å. The C(8)-F(1,2) bond length is 1.36 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(7) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(7), and one C(9) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. The H(1)-O(3) bond length is 1.00 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. The H(2)-O(3) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(6) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(1), one H(1), and one H(2) atom. F(1,2) is bonded in a single-bond geometry to one C(8) atom. Linkers: 1 C(=C/c1ccncc1)\c1ccncc1 ,2 [c]1cc(/C=C/c2ccncc2)ccn1 ,1 [O]C(=O)c1c(F)c(F)c(C([O])=O)c(F)c1F. Metal clusters: 1 O.O.O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 1.70 A, density 1.92 g/cm3, surface area 3890.44 m2/g, accessible volume 0.12 cm3/g