Zn3C8H16(N10F)2 crystallizes in the tetragonal P4/nnc space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to four equivalent N(2) atoms. All Zn(1)-N(2) bond lengths are 1.99 Å. In the second Zn site, Zn(2) is bonded in an octahedral geometry to four equivalent N(1) and two equivalent F(1) atoms. All Zn(2)-N(1) bond lengths are 2.14 Å. Both Zn(2)-F(1) bond lengths are 2.19 Å. C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-N(3) bond length is 1.36 Å. There are three inequivalent N sites. In the first N site, N(3) is bonded in a distorted trigonal planar geometry to one C(1), one H(1), and one H(2) atom. The N(3)-H(1) bond length is 1.01 Å. The N(3)-H(2) bond length is 1.03 Å. In the second N site, N(1) is bonded in a trigonal planar geometry to one Zn(2) and two equivalent C(1) atoms. In the third N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(1), and one N(2) atom. The N(2)-N(2) bond length is 1.41 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. F(1) is bonded in a single-bond geometry to one Zn(2) atom. Linkers: 2 Nc1nnc(N)n1[Zn](F)(F)(n1c(N)nnc1N)(n1c(N)nnc1N)n1c(N)nnc1N. Metal clusters: 4 [Zn]. The MOF has largest included sphere 1.79 A, density 2.10 g/cm3, surface area 3603.73 m2/g, accessible volume 0.11 cm3/g