AgC19H15(N2O)2(CH)5(CH3)2(CH2)2CH3CO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules, four 02329_fluka molecules, four 02329_fluka molecules, two dimethyl ether molecules, and two AgC19H15(N2O)2 clusters. In each AgC19H15(N2O)2 cluster, Ag(1) is bonded in a 3-coordinate geometry to one N(1), one N(4), and one O(2) atom. The Ag(1)-N(1) bond length is 2.21 Å. The Ag(1)-N(4) bond length is 2.17 Å. The Ag(1)-O(2) bond length is 2.38 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one N(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(2) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted water-like geometry to one C(24), one H(5), and one H(6) atom. The C(7)-C(24) bond length is 1.49 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one N(3) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(14) bond length is 1.40 Å. The C(9)-N(3) bond length is 1.39 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one N(4) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-N(4) bond length is 1.39 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(10) atom. The C(11)-H(10) bond length is 1.09 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(13) atom. The C(14)-H(13) bond length is 1.09 Å. In the tenth C site, C(15) is bonded in a distorted water-like geometry to one C(23), one H(14), and one H(15) atom. The C(15)-C(23) bond length is 1.49 Å. The C(15)-H(14) bond length is 1.10 Å. The C(15)-H(15) bond length is 1.10 Å. In the eleventh C site, C(17) is bonded in a trigonal planar geometry to one C(18), one C(19), and one C(25) atom. The C(17)-C(18) bond length is 1.51 Å. The C(17)-C(19) bond length is 1.41 Å. The C(17)-C(25) bond length is 1.40 Å. In the twelfth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(2), and one O(3) atom. The C(18)-O(2) bond length is 1.29 Å. The C(18)-O(3) bond length is 1.27 Å. In the thirteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(17) and one H(19) atom. The C(19)-H(19) bond length is 1.09 Å. In the fourteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(25) and one H(21) atom. The C(22)-C(25) bond length is 1.40 Å. The C(22)-H(21) bond length is 1.09 Å. In the fifteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(15), one N(3), and one N(4) atom. The C(23)-N(3) bond length is 1.37 Å. The C(23)-N(4) bond length is 1.34 Å. In the sixteenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one N(2) atom. The C(24)-N(1) bond length is 1.34 Å. The C(24)-N(2) bond length is 1.37 Å. In the seventeenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(17), one C(22), and one H(22) atom. The C(25)-H(22) bond length is 1.09 Å. In the eighteenth C site, C(27) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(26), and one H(27) atom. The C(27)-N(2) bond length is 1.46 Å. The C(27)-H(26) bond length is 1.10 Å. The C(27)-H(27) bond length is 1.10 Å. In the nineteenth C site, C(29) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(30), and one H(31) atom. The C(29)-N(3) bond length is 1.45 Å. The C(29)-H(30) bond length is 1.10 Å. The C(29)-H(31) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(24) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(24), and one C(27) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(23), one C(29), and one C(9) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(10), and one C(23) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(21) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(22) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(26) is bonded in a single-bond geometry to one C(27) atom. In the thirteenth H site, H(27) is bonded in a single-bond geometry to one C(27) atom. In the fourteenth H site, H(30) is bonded in a single-bond geometry to one C(29) atom. In the fifteenth H site, H(31) is bonded in a single-bond geometry to one C(29) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one C(18) atom. In the second O site, O(3) is bonded in a single-bond geometry to one C(18) atom. Linkers: 2 CCc1nc2ccccc2n1CCCCn1c(CC)nc2ccccc21 ,2 [CH]=Cc1[c]nc(CC)n1CCCCn1c(CC)nc2ccccc21. Metal clusters: 2 [Ag]. The MOF has largest included sphere 4.63 A, density 1.31 g/cm3, surface area 5319.39 m2/g, accessible volume 0.23 cm3/g