Ag3C12H6(NO3)2CH crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a Ag3C12H6(NO3)2 framework. In the Ag3C12H6(NO3)2 framework, there are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one O(6), one O(7), one O(8), and one O(9) atom. The Ag(1)-O(6) bond length is 2.22 Å. The Ag(1)-O(7) bond length is 2.56 Å. The Ag(1)-O(8) bond length is 2.21 Å. The Ag(1)-O(9) bond length is 2.69 Å. In the second Ag site, Ag(2) is bonded to one N(3), one O(12), and two equivalent O(3) atoms to form distorted edge-sharing AgNO3 trigonal pyramids. The Ag(2)-N(3) bond length is 2.20 Å. The Ag(2)-O(12) bond length is 2.21 Å. There is one shorter (2.51 Å) and one longer (2.63 Å) Ag(2)-O(3) bond length. In the third Ag site, Ag(3) is bonded in a distorted T-shaped geometry to one O(2), one O(4), and one O(5) atom. The Ag(3)-O(2) bond length is 2.30 Å. The Ag(3)-O(4) bond length is 2.28 Å. The Ag(3)-O(5) bond length is 2.34 Å. In the fourth Ag site, Ag(4) is bonded in a rectangular see-saw-like geometry to one N(2), one N(4), one O(6), and one O(9) atom. The Ag(4)-N(2) bond length is 2.22 Å. The Ag(4)-N(4) bond length is 2.29 Å. The Ag(4)-O(6) bond length is 2.65 Å. The Ag(4)-O(9) bond length is 2.47 Å. In the fifth Ag site, Ag(5) is bonded in a 2-coordinate geometry to one N(1) and one O(1) atom. The Ag(5)-N(1) bond length is 2.16 Å. The Ag(5)-O(1) bond length is 2.15 Å. In the sixth Ag site, Ag(6) is bonded in a distorted bent 150 degrees geometry to one O(10) and one O(11) atom. The Ag(6)-O(10) bond length is 2.11 Å. The Ag(6)-O(11) bond length is 2.14 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(15), one C(4), and one C(8) atom. The C(1)-C(15) bond length is 1.50 Å. The C(1)-C(4) bond length is 1.40 Å. The C(1)-C(8) bond length is 1.41 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(10), one N(3), and one H(2) atom. The C(3)-C(10) bond length is 1.40 Å. The C(3)-N(3) bond length is 1.34 Å. The C(3)-H(2) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(1), one C(6), and one H(3) atom. The C(4)-C(6) bond length is 1.40 Å. The C(4)-H(3) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(26), one N(4), and one H(4) atom. The C(5)-C(26) bond length is 1.40 Å. The C(5)-N(4) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(4), and one C(9) atom. The C(6)-C(11) bond length is 1.40 Å. The C(6)-C(9) bond length is 1.49 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5) atom. The C(7)-N(2) bond length is 1.34 Å. The C(7)-H(5) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(1), one C(12), and one H(6) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-H(6) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(11) atom. The C(9)-O(1) bond length is 1.28 Å. The C(9)-O(11) bond length is 1.27 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(3) and one H(7) atom. The C(10)-H(7) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(12), one C(6), and one H(8) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(8) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(18), and one C(8) atom. The C(12)-C(18) bond length is 1.51 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(13)-N(1) bond length is 1.34 Å. The C(13)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(19), one C(24), and one H(10) atom. The C(14)-C(19) bond length is 1.40 Å. The C(14)-C(24) bond length is 1.40 Å. The C(14)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(5), and one O(8) atom. The C(15)-O(5) bond length is 1.28 Å. The C(15)-O(8) bond length is 1.28 Å. In the fifteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(10), and one O(7) atom. The C(16)-C(22) bond length is 1.50 Å. The C(16)-O(10) bond length is 1.29 Å. The C(16)-O(7) bond length is 1.26 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(19), one C(22), and one H(11) atom. The C(17)-C(19) bond length is 1.40 Å. The C(17)-C(22) bond length is 1.40 Å. The C(17)-H(11) bond length is 1.09 Å. In the seventeenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(2), and one O(3) atom. The C(18)-O(2) bond length is 1.28 Å. The C(18)-O(3) bond length is 1.27 Å. In the eighteenth C site, C(19) is bonded in a trigonal planar geometry to one C(14), one C(17), and one C(23) atom. The C(19)-C(23) bond length is 1.50 Å. In the nineteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(12), and one O(9) atom. The C(20)-C(24) bond length is 1.50 Å. The C(20)-O(12) bond length is 1.27 Å. The C(20)-O(9) bond length is 1.27 Å. In the twentieth C site, C(21) is bonded in a distorted single-bond geometry to one C(22), one C(24), and one H(12) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(24) bond length is 1.40 Å. The C(21)-H(12) bond length is 1.09 Å. In the twenty-first C site, C(22) is bonded in a trigonal planar geometry to one C(16), one C(17), and one C(21) atom. In the twenty-second C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(4), and one O(6) atom. The C(23)-O(4) bond length is 1.27 Å. The C(23)-O(6) bond length is 1.29 Å. In the twenty-third C site, C(24) is bonded in a trigonal planar geometry to one C(14), one C(20), and one C(21) atom. In the twenty-fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(5) and one H(14) atom. The C(26)-H(14) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(5), one C(13), and one N(4) atom. The N(1)-N(4) bond length is 1.34 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(4), one C(7), and one N(3) atom. The N(2)-N(3) bond length is 1.34 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(3), and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(4), one C(5), and one N(1) atom. There are twelve inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(26) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(5) and one C(9) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one C(18) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one C(18) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Ag(3) and one C(23) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Ag(3) and one C(15) atom. In the sixth O site, O(6) is bonded in a 1-coordinate geometry to one Ag(1), one Ag(4), and one C(23) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Ag(1) and one C(16) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Ag(1) and one C(15) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(4), and one C(20) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Ag(6) and one C(16) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Ag(6) and one C(9) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one C(20) atom. Linkers: 4 c1ccnnc1 ,4 [O]C(=O)c1cc(C([O])=O)cc(C([O])=O)c1. Metal clusters: 12 [Ag]. The MOF has largest included sphere 1.71 A, density 2.99 g/cm3, surface area 2168.58 m2/g, accessible volume 0.03 cm3/g