ZnC14N3H10O4(CH)9 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four m-xylene molecules, and four ZnC14N3H10O4 clusters. In each ZnC14N3H10O4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-N(3) bond length is 2.09 Å. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(3) bond length is 1.97 Å. There are fourteen inequivalent C sites. In the first C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(13)-C(12) bond length is 1.40 Å. The C(13)-H(10) bond length is 1.09 Å. In the second C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(12) bond length is 1.09 Å. In the third C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one H(13) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(13) bond length is 1.09 Å. In the fourth C site, C(17) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one N(2) atom. The C(17)-C(12) bond length is 1.42 Å. The C(17)-N(2) bond length is 1.39 Å. In the fifth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one C(19), one N(2), one H(14), and one H(15) atom. The C(18)-C(19) bond length is 1.51 Å. The C(18)-N(2) bond length is 1.45 Å. The C(18)-H(14) bond length is 1.10 Å. The C(18)-H(15) bond length is 1.10 Å. In the sixth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(23) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-C(23) bond length is 1.40 Å. In the seventh C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(16) atom. The C(20)-H(16) bond length is 1.09 Å. In the eighth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(21)-N(3) bond length is 1.35 Å. The C(21)-H(17) bond length is 1.09 Å. In the ninth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(18) atom. The C(22)-N(3) bond length is 1.35 Å. The C(22)-H(18) bond length is 1.09 Å. In the tenth C site, C(23) is bonded in a distorted single-bond geometry to one C(19) and one H(19) atom. The C(23)-H(19) bond length is 1.09 Å. In the eleventh C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.24 Å. In the twelfth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(10)-O(3) bond length is 1.31 Å. The C(10)-O(4) bond length is 1.25 Å. In the thirteenth C site, C(11) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(9) atom. The C(11)-N(1) bond length is 1.33 Å. The C(11)-N(2) bond length is 1.36 Å. The C(11)-H(9) bond length is 1.09 Å. In the fourteenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one C(17), and one N(1) atom. The C(12)-N(1) bond length is 1.39 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(12) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(17), and one C(18) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(21), and one C(22) atom. There are ten inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(10) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(10) atom. Linkers: 2 c1ccc2c(c1)ncn2Cc1ccncc1 ,4 [O]C(=O)Cc1cccc(CC([O])=O)c1. Metal clusters: 4 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.28 A, density 1.40 g/cm3, surface area 4705.87 m2/g, accessible volume 0.23 cm3/g