CuC8H8(NCl)2CuC10H10(NCl)2(CH)34(CH3)6(C4H4N)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules, six 02329_fluka molecules, two hexamethylbenzene molecules, two n-prop-1-en-2-ylmethanimine molecules, one CuC10H10(NCl)2 cluster, and one CuC8H8(NCl)2 cluster. In the CuC10H10(NCl)2 cluster, Cu(2) is bonded in a square co-planar geometry to two equivalent N(3) and two equivalent Cl(2) atoms. Both Cu(2)-N(3) bond lengths are 1.99 Å. Both Cu(2)-Cl(2) bond lengths are 2.29 Å. There are five inequivalent C sites. In the first C site, C(28) is bonded in a distorted water-like geometry to one C(29), one H(34), and one H(35) atom. The C(28)-C(29) bond length is 1.50 Å. The C(28)-H(34) bond length is 1.10 Å. The C(28)-H(35) bond length is 1.10 Å. In the second C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one C(30), and one N(3) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-N(3) bond length is 1.35 Å. In the third C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(36) atom. The C(30)-H(36) bond length is 1.09 Å. In the fourth C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(38) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-H(38) bond length is 1.09 Å. In the fifth C site, C(33) is bonded in a distorted trigonal planar geometry to one C(32), one N(3), and one H(39) atom. The C(33)-N(3) bond length is 1.35 Å. The C(33)-H(39) bond length is 1.09 Å. N(3) is bonded in a trigonal planar geometry to one Cu(2), one C(29), and one C(33) atom. There are five inequivalent H sites. In the first H site, H(34) is bonded in a single-bond geometry to one C(28) atom. In the second H site, H(35) is bonded in a single-bond geometry to one C(28) atom. In the third H site, H(36) is bonded in a single-bond geometry to one C(30) atom. In the fourth H site, H(38) is bonded in a single-bond geometry to one C(32) atom. In the fifth H site, H(39) is bonded in a single-bond geometry to one C(33) atom. Cl(2) is bonded in a single-bond geometry to one Cu(2) atom. In the CuC8H8(NCl)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent Cl(1) atoms. Both Cu(1)-N(2) bond lengths are 1.99 Å. Both Cu(1)-Cl(1) bond lengths are 2.30 Å. There are four inequivalent C sites. In the first C site, C(26) is bonded in a distorted trigonal planar geometry to one N(2) and one H(31) atom. The C(26)-N(2) bond length is 1.35 Å. The C(26)-H(31) bond length is 1.09 Å. In the second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one N(2) atom. The C(22)-C(21) bond length is 1.50 Å. The C(22)-C(23) bond length is 1.40 Å. The C(22)-N(2) bond length is 1.35 Å. In the third C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(28) atom. The C(23)-H(28) bond length is 1.09 Å. In the fourth C site, C(21) is bonded in a distorted water-like geometry to one C(22), one H(26), and one H(27) atom. The C(21)-H(26) bond length is 1.10 Å. The C(21)-H(27) bond length is 1.10 Å. N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(22), and one C(26) atom. There are four inequivalent H sites. In the first H site, H(26) is bonded in a single-bond geometry to one C(21) atom. In the second H site, H(27) is bonded in a single-bond geometry to one C(21) atom. In the third H site, H(28) is bonded in a single-bond geometry to one C(23) atom. In the fourth H site, H(31) is bonded in a single-bond geometry to one C(26) atom. Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 1 CCc1c(CCc2ccccn2)c(CC)c(CCc2ccccn2)c(CC)c1CCc1ccccn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 4.17 A, density 1.26 g/cm3, surface area 5207.91 m2/g, accessible volume 0.17 cm3/g