CuC11N6H9I(CH)3(CH2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, six 02329_fluka molecules, and one CuC11N6H9I cluster. In the CuC11N6H9I cluster, Cu(1) is bonded in a 2-coordinate geometry to one N(1), one N(6), and two equivalent I(1) atoms. The Cu(1)-N(1) bond length is 2.02 Å. The Cu(1)-N(6) bond length is 2.03 Å. There is one shorter (2.63 Å) and one longer (2.68 Å) Cu(1)-I(1) bond length. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-N(1) bond length is 1.38 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one N(3) atom. The C(6)-N(3) bond length is 1.36 Å. In the fifth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(5), and one H(6) atom. The C(7)-N(3) bond length is 1.45 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. In the sixth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(13), and one H(14) atom. The C(11)-N(4) bond length is 1.46 Å. The C(11)-H(13) bond length is 1.10 Å. The C(11)-H(14) bond length is 1.10 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one N(4) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(17) bond length is 1.41 Å. The C(12)-N(4) bond length is 1.37 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(15) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(15) bond length is 1.09 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(16) atom. The C(14)-H(16) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(18) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(18) bond length is 1.09 Å. In the eleventh C site, C(17) is bonded in a distorted trigonal planar geometry to one C(12), one C(16), and one N(6) atom. The C(17)-N(6) bond length is 1.38 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.32 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.35 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(11), one C(12), and one N(5) atom. The N(4)-N(5) bond length is 1.35 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.31 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(17), and one N(5) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 2 c1ccc2c(c1)nnn2CCCCCn1nnc2ccccc21. Metal clusters: 1 I[Cu][Cu]I. The MOF has largest included sphere 2.48 A, density 1.88 g/cm3, surface area 4111.21 m2/g, accessible volume 0.15 cm3/g