Zn3C17H14(NO5)2(CH3)2 crystallizes in the monoclinic Cc space group. The structure consists of sixteen 02329_fluka molecules inside a Zn3C17H14(NO5)2 framework. In the Zn3C17H14(NO5)2 framework, there are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(11), one O(15), and one O(3) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(11) bond length is 1.98 Å. The Zn(1)-O(15) bond length is 1.97 Å. The Zn(1)-O(3) bond length is 1.94 Å. In the second Zn site, Zn(2) is bonded to one O(12), one O(16), one O(2), and one O(4) atom to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(12) bond length is 1.98 Å. The Zn(2)-O(16) bond length is 1.97 Å. The Zn(2)-O(2) bond length is 1.96 Å. The Zn(2)-O(4) bond length is 1.94 Å. In the third Zn site, Zn(3) is bonded to one N(1), one O(1), one O(13), one O(17), and one O(7) atom to form corner-sharing ZnNO4 trigonal bipyramids. The Zn(3)-N(1) bond length is 2.14 Å. The Zn(3)-O(1) bond length is 2.03 Å. The Zn(3)-O(13) bond length is 2.12 Å. The Zn(3)-O(17) bond length is 2.03 Å. The Zn(3)-O(7) bond length is 2.01 Å. In the fourth Zn site, Zn(4) is bonded to one N(2), one O(14), one O(18), one O(2), and one O(8) atom to form corner-sharing ZnNO4 trigonal bipyramids. The Zn(4)-N(2) bond length is 2.14 Å. The Zn(4)-O(14) bond length is 2.13 Å. The Zn(4)-O(18) bond length is 2.03 Å. The Zn(4)-O(2) bond length is 2.03 Å. The Zn(4)-O(8) bond length is 2.01 Å. In the fifth Zn site, Zn(5) is bonded to one N(3), one O(20), one O(3), one O(6), and one O(9) atom to form corner-sharing ZnNO4 trigonal bipyramids. The Zn(5)-N(3) bond length is 2.12 Å. The Zn(5)-O(20) bond length is 2.03 Å. The Zn(5)-O(3) bond length is 2.03 Å. The Zn(5)-O(6) bond length is 2.02 Å. The Zn(5)-O(9) bond length is 2.10 Å. In the sixth Zn site, Zn(6) is bonded to one N(4), one O(10), one O(19), one O(4), and one O(5) atom to form corner-sharing ZnNO4 trigonal bipyramids. The Zn(6)-N(4) bond length is 2.12 Å. The Zn(6)-O(10) bond length is 2.10 Å. The Zn(6)-O(19) bond length is 2.03 Å. The Zn(6)-O(4) bond length is 2.03 Å. The Zn(6)-O(5) bond length is 2.02 Å. There are thirty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(1) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one H(2) atom. The C(2)-C(4) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one H(3) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(4) atom. The C(4)-C(6) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(5,6) atom. The C(5)-H(5,6) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(5,6) atom. The C(6)-H(5,6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(9) and one H(7,8) atom. The C(7)-C(9) bond length is 1.39 Å. The C(7)-H(7,8) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(10) and one H(7,8) atom. The C(8)-C(10) bond length is 1.39 Å. The C(8)-H(7,8) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(11), one C(7), and one N(1) atom. The C(9)-C(11) bond length is 1.54 Å. The C(9)-N(1) bond length is 1.34 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(8), and one N(2) atom. The C(10)-C(11) bond length is 1.54 Å. The C(10)-N(2) bond length is 1.34 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(10), one C(9), one O(1), and one O(2) atom. The C(11)-O(1) bond length is 1.40 Å. The C(11)-O(2) bond length is 1.40 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14); one N(3); and one H(9,10) atom. The C(12)-C(14) bond length is 1.39 Å. The C(12)-N(3) bond length is 1.35 Å. The C(12)-H(9,10) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(15); one N(4); and one H(9,10) atom. The C(13)-C(15) bond length is 1.39 Å. The C(13)-N(4) bond length is 1.35 Å. The C(13)-H(9,10) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one H(11) atom. The C(14)-C(16) bond length is 1.40 Å. The C(14)-H(11) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one H(12) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-H(12) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one H(13) atom. The C(16)-C(18) bond length is 1.39 Å. The C(16)-H(13) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(15), one C(19), and one H(14) atom. The C(17)-C(19) bond length is 1.39 Å. The C(17)-H(14) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one H(15) atom. The C(18)-C(20) bond length is 1.40 Å. The C(18)-H(15) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(17), one C(21), and one H(16) atom. The C(19)-C(21) bond length is 1.40 Å. The C(19)-H(16) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(18), one C(22), and one N(3) atom. The C(20)-C(22) bond length is 1.55 Å. The C(20)-N(3) bond length is 1.34 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(19), one C(22), and one N(4) atom. The C(21)-C(22) bond length is 1.55 Å. The C(21)-N(4) bond length is 1.34 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(20), one C(21), one O(3), and one O(4) atom. The C(22)-O(3) bond length is 1.40 Å. The C(22)-O(4) bond length is 1.40 Å. In the twenty-third C site, C(23) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(7) atom. The C(23)-O(5) bond length is 1.27 Å. The C(23)-O(7) bond length is 1.28 Å. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(8) atom. The C(24)-O(6) bond length is 1.27 Å. The C(24)-O(8) bond length is 1.28 Å. In the twenty-fifth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(29), one O(11), and one O(9) atom. The C(27)-C(29) bond length is 1.52 Å. The C(27)-O(11) bond length is 1.28 Å. The C(27)-O(9) bond length is 1.26 Å. In the twenty-sixth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(30), one O(10), and one O(12) atom. The C(28)-C(30) bond length is 1.52 Å. The C(28)-O(10) bond length is 1.26 Å. The C(28)-O(12) bond length is 1.28 Å. In the twenty-seventh C site, C(29) is bonded in a trigonal non-coplanar geometry to one C(27); one H(23,24); one H(25,26); and one H(27,28) atom. The C(29)-H(23,24) bond length is 1.09 Å. The C(29)-H(25,26) bond length is 1.10 Å. The C(29)-H(27,28) bond length is 1.10 Å. In the twenty-eighth C site, C(30) is bonded in a trigonal non-coplanar geometry to one C(28); one H(23,24); one H(25,26); and one H(27,28) atom. The C(30)-H(23,24) bond length is 1.09 Å. The C(30)-H(25,26) bond length is 1.10 Å. The C(30)-H(27,28) bond length is 1.10 Å. In the twenty-ninth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(15) atom. The C(31)-O(13) bond length is 1.27 Å. The C(31)-O(15) bond length is 1.28 Å. In the thirtieth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one O(14) and one O(16) atom. The C(32)-O(14) bond length is 1.27 Å. The C(32)-O(16) bond length is 1.28 Å. In the thirty-first C site, C(35) is bonded in a distorted trigonal planar geometry to one C(37), one O(17), and one O(19) atom. The C(35)-C(37) bond length is 1.51 Å. The C(35)-O(17) bond length is 1.28 Å. The C(35)-O(19) bond length is 1.27 Å. In the thirty-second C site, C(36) is bonded in a distorted trigonal planar geometry to one C(38), one O(18), and one O(20) atom. The C(36)-C(38) bond length is 1.51 Å. The C(36)-O(18) bond length is 1.28 Å. The C(36)-O(20) bond length is 1.27 Å. In the thirty-third C site, C(37) is bonded in a trigonal non-coplanar geometry to one C(35); one H(35,36); one H(37,38); and one H(39,40) atom. The C(37)-H(35,36) bond length is 1.09 Å. The C(37)-H(37,38) bond length is 1.10 Å. The C(37)-H(39,40) bond length is 1.10 Å. In the thirty-fourth C site, C(38) is bonded in a trigonal non-coplanar geometry to one C(36); one H(35,36); one H(37,38); and one H(39,40) atom. The C(38)-H(35,36) bond length is 1.09 Å. The C(38)-H(37,38) bond length is 1.10 Å. The C(38)-H(39,40) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(3), one C(1), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(4), one C(10), and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(5), one C(12), and one C(20) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(6), one C(13), and one C(21) atom. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(23,24) is bonded in a single-bond geometry to one C(29) atom. In the fifteenth H site, H(25,26) is bonded in a single-bond geometry to one C(29) atom. In the sixteenth H site, H(27,28) is bonded in a single-bond geometry to one C(29) atom. In the seventeenth H site, H(35,36) is bonded in a single-bond geometry to one C(37) atom. In the eighteenth H site, H(37,38) is bonded in a single-bond geometry to one C(37) atom. In the nineteenth H site, H(39,40) is bonded in a single-bond geometry to one C(37) atom. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Zn(1), one Zn(3), and one C(11) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Zn(2), one Zn(4), and one C(11) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Zn(1), one Zn(5), and one C(22) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Zn(2), one Zn(6), and one C(22) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(23) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(24) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(23) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(24) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Zn(5) and one C(27) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Zn(6) and one C(28) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(27) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(28) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Zn(3) and one C(31) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Zn(4) and one C(32) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(31) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(32) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(35) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(36) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(35) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(36) atom. Linkers: 4 [O]C([O])(c1ccccn1)c1ccccn1. Metal clusters: 12 [Zn]. The MOF has largest included sphere 5.15 A, density 1.37 g/cm3, surface area 4203.04 m2/g, accessible volume 0.32 cm3/g