CdC16H10(NO2)2(CH)6(C3NH2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, four propylene molecules, four C3NH2 clusters, and four CdC16H10(NO2)2 clusters. In each C3NH2 cluster, there are four inequivalent C sites. In the first C site, C(14) is bonded in a distorted trigonal planar geometry to one N(2) and one H(9) atom. The C(14)-N(2) bond length is 1.34 Å. The C(14)-H(9) bond length is 1.09 Å. In the second C site, C(10) is bonded in a trigonal planar geometry to one C(11) and two equivalent C(12) atoms. The C(10)-C(11) bond length is 1.48 Å. Both C(10)-C(12) bond lengths are 1.40 Å. In the third C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10) and two equivalent N(2) atoms. Both C(11)-N(2) bond lengths are 1.35 Å. In the fourth C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(12)-H(7) bond length is 1.09 Å. N(2) is bonded in a bent 120 degrees geometry to one C(11) and one C(14) atom. There are two inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In each CdC16H10(NO2)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. Both Cd(1)-N(1) bond lengths are 2.33 Å. Both Cd(1)-O(1) bond lengths are 2.30 Å. Both Cd(1)-O(2) bond lengths are 2.46 Å. There are eight inequivalent C sites. In the first C site, C(4) is bonded in a distorted trigonal planar geometry to one C(4), one C(7), and one N(1) atom. The C(4)-C(4) bond length is 1.49 Å. The C(4)-C(7) bond length is 1.40 Å. The C(4)-N(1) bond length is 1.35 Å. In the second C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(2) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(2) bond length is 1.09 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the fifth C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one H(1,6) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-H(1,6) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(2) and one H(1,6) atom. The C(9)-C(2) bond length is 1.40 Å. The C(9)-H(1,6) bond length is 1.09 Å. In the seventh C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(9) atom. The C(2)-C(3) bond length is 1.49 Å. In the eighth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(3)-O(1) bond length is 1.29 Å. The C(3)-O(2) bond length is 1.27 Å. N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(4), and one C(5) atom. There are four inequivalent H sites. In the first H site, H(1,6) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(3) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(3) atom. Linkers: 2 c1ccc(-c2ccccn2)nc1 ,2 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 1.55 A, density 1.71 g/cm3, surface area 4708.00 m2/g, accessible volume 0.13 cm3/g