CuC28H20(N4O7)2(CH2)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and one CuC28H20(N4O7)2 cluster. In the CuC28H20(N4O7)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(2) atoms. Both Cu(1)-N(1) bond lengths are 1.96 Å. Both Cu(1)-O(2) bond lengths are 2.02 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(2) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(2) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(5) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(2), and one O(1) atom. The C(6)-C(7) bond length is 1.51 Å. The C(6)-N(2) bond length is 1.38 Å. The C(6)-O(1) bond length is 1.24 Å. In the seventh C site, C(7) is bonded in a distorted water-like geometry to one C(6), one H(6), and one H(7) atom. The C(7)-H(6) bond length is 1.10 Å. The C(7)-H(7) bond length is 1.10 Å. In the eighth C site, C(11) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(17) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(16) bond length is 1.40 Å. The C(11)-C(17) bond length is 1.51 Å. In the ninth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(14) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(14) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one N(3) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-N(3) bond length is 1.48 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(15) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(15) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one N(4) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-N(4) bond length is 1.47 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(11), one C(15), and one H(16) atom. The C(16)-H(16) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(2), and one O(3) atom. The C(17)-O(2) bond length is 1.28 Å. The C(17)-O(3) bond length is 1.26 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(6), and one H(1) atom. The N(2)-H(1) bond length is 1.03 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(13), one O(6), and one O(7) atom. The N(3)-O(6) bond length is 1.24 Å. The N(3)-O(7) bond length is 1.24 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(15), one O(4), and one O(5) atom. The N(4)-O(4) bond length is 1.24 Å. The N(4)-O(5) bond length is 1.24 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cu(1) and one C(17) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(17) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one N(3) atom. Linkers: 2 [N][CH]/C(=[NH]/C(=O)CCCCCCCCC(=O)Nc1cccnc1)/[CH]. Metal clusters: 1 [Cu]. The MOF has largest included sphere 2.17 A, density 1.53 g/cm3, surface area 4908.65 m2/g, accessible volume 0.15 cm3/g