CdC12H8(NO2)2(CH)4(C4H3O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; two 2,3-bis(methoxymethyl)buta-1,3-diene molecules; and one CdC12H8(NO2)2 cluster. In the CdC12H8(NO2)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(2), one O(4), and two equivalent O(1) atoms. The Cd(1)-N(1) bond length is 2.31 Å. The Cd(1)-N(2) bond length is 2.36 Å. The Cd(1)-O(2) bond length is 2.56 Å. The Cd(1)-O(4) bond length is 2.20 Å. There is one shorter (2.40 Å) and one longer (2.56 Å) Cd(1)-O(1) bond length. There are twelve inequivalent C sites. In the first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(3)-O(1) bond length is 1.28 Å. The C(3)-O(2) bond length is 1.27 Å. In the second C site, C(5) is bonded in a distorted trigonal planar geometry to one C(21), one C(7), and one N(1) atom. The C(5)-C(21) bond length is 1.40 Å. The C(5)-C(7) bond length is 1.49 Å. The C(5)-N(1) bond length is 1.35 Å. In the third C site, C(7) is bonded in a distorted trigonal planar geometry to one C(12), one C(5), and one N(2) atom. The C(7)-C(12) bond length is 1.40 Å. The C(7)-N(2) bond length is 1.35 Å. In the fourth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. The C(8)-O(4) bond length is 1.28 Å. The C(8)-O(6) bond length is 1.26 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(23) and one H(4) atom. The C(10)-C(23) bond length is 1.39 Å. The C(10)-H(4) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(12)-H(7) bond length is 1.09 Å. In the seventh C site, C(14) is bonded in a distorted single-bond geometry to one C(20) and one H(8) atom. The C(14)-C(20) bond length is 1.39 Å. The C(14)-H(8) bond length is 1.09 Å. In the eighth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(20), one N(1), and one H(9) atom. The C(15)-C(20) bond length is 1.39 Å. The C(15)-N(1) bond length is 1.34 Å. The C(15)-H(9) bond length is 1.09 Å. In the ninth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(23), one N(2), and one H(10) atom. The C(16)-C(23) bond length is 1.39 Å. The C(16)-N(2) bond length is 1.34 Å. The C(16)-H(10) bond length is 1.09 Å. In the tenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(14), one C(15), and one H(14) atom. The C(20)-H(14) bond length is 1.09 Å. In the eleventh C site, C(21) is bonded in a distorted single-bond geometry to one C(5) and one H(15) atom. The C(21)-H(15) bond length is 1.09 Å. In the twelfth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(10), one C(16), and one H(17) atom. The C(23)-H(17) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(15), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(16), and one C(7) atom. There are eight inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(3) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(3) atom. In the third O site, O(4) is bonded in a distorted water-like geometry to one Cd(1) and one C(8) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(8) atom. Linkers: 2 [O]C(=O)COc1cccc2c(OCC([O])=O)cccc12 ,2 c1ccc(-c2ccccn2)nc1. Metal clusters: 1 O=[C]O[Cd]O[C]=O.O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 3.48 A, density 1.65 g/cm3, surface area 4337.32 m2/g, accessible volume 0.17 cm3/g