Cu4C10N8H10O9(CH2)2H2O crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules and four water molecules inside a Cu4C10N8H10O9 framework. In the Cu4C10N8H10O9 framework, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one N(1), one N(2), one N(7), one O(1), and one O(3) atom to form distorted corner-sharing CuN3O2 trigonal bipyramids. The Cu(1)-N(1) bond length is 1.99 Å. The Cu(1)-N(2) bond length is 1.98 Å. The Cu(1)-N(7) bond length is 2.02 Å. The Cu(1)-O(1) bond length is 2.49 Å. The Cu(1)-O(3) bond length is 2.00 Å. In the second Cu site, Cu(2) is bonded to one N(1), one N(3), one O(10), one O(5), and one O(7) atom to form distorted corner-sharing CuN2O3 square pyramids. The Cu(2)-N(1) bond length is 1.97 Å. The Cu(2)-N(3) bond length is 1.96 Å. The Cu(2)-O(10) bond length is 2.48 Å. The Cu(2)-O(5) bond length is 1.96 Å. The Cu(2)-O(7) bond length is 2.08 Å. In the third Cu site, Cu(3) is bonded in a distorted square pyramidal geometry to one N(4), one N(5), one N(8), one O(4), and one O(8) atom. The Cu(3)-N(4) bond length is 1.97 Å. The Cu(3)-N(5) bond length is 1.99 Å. The Cu(3)-N(8) bond length is 1.95 Å. The Cu(3)-O(4) bond length is 2.44 Å. The Cu(3)-O(8) bond length is 1.98 Å. In the fourth Cu site, Cu(4) is bonded in a 5-coordinate geometry to one N(6), one N(8), one O(5), one O(6), and one O(9) atom. The Cu(4)-N(6) bond length is 2.00 Å. The Cu(4)-N(8) bond length is 1.94 Å. The Cu(4)-O(5) bond length is 2.51 Å. The Cu(4)-O(6) bond length is 2.03 Å. The Cu(4)-O(9) bond length is 1.99 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(1)-O(3) bond length is 1.30 Å. The C(1)-O(4) bond length is 1.25 Å. In the second C site, C(2) is bonded in a 2-coordinate geometry to one N(1) and one H(7) atom. The C(2)-N(1) bond length is 1.46 Å. The C(2)-H(7) bond length is 1.10 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(4)-O(5) bond length is 1.28 Å. The C(4)-O(6) bond length is 1.27 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(10) atom. The C(5)-N(3) bond length is 1.33 Å. The C(5)-N(4) bond length is 1.35 Å. The C(5)-H(10) bond length is 1.08 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one N(2), one N(4), and one H(11) atom. The C(6)-N(2) bond length is 1.33 Å. The C(6)-N(4) bond length is 1.35 Å. The C(6)-H(11) bond length is 1.08 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one N(6), one N(7), and one H(12) atom. The C(7)-N(6) bond length is 1.33 Å. The C(7)-N(7) bond length is 1.36 Å. The C(7)-H(12) bond length is 1.08 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one N(5), one N(7), and one H(13) atom. The C(8)-N(5) bond length is 1.33 Å. The C(8)-N(7) bond length is 1.36 Å. The C(8)-H(13) bond length is 1.08 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(9)-O(7) bond length is 1.26 Å. The C(9)-O(8) bond length is 1.28 Å. In the ninth C site, C(10) is bonded in a 2-coordinate geometry to one N(8) and one H(14) atom. The C(10)-N(8) bond length is 1.47 Å. The C(10)-H(14) bond length is 1.10 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(12)-O(10) bond length is 1.25 Å. The C(12)-O(9) bond length is 1.31 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Cu(1), one Cu(2), one C(2), and one H(1) atom. The N(1)-H(1) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(6), and one N(3) atom. The N(2)-N(3) bond length is 1.37 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(5), and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(3), one C(5), and one C(6) atom. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one Cu(3), one C(8), and one N(6) atom. The N(5)-N(6) bond length is 1.36 Å. In the sixth N site, N(6) is bonded in a 3-coordinate geometry to one Cu(4), one C(7), and one N(5) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(7), and one C(8) atom. In the eighth N site, N(8) is bonded in a distorted tetrahedral geometry to one Cu(3), one Cu(4), one C(10), and one H(2) atom. The N(8)-H(2) bond length is 1.03 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. The H(3)-O(1) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(1) atom. The H(4)-O(1) bond length is 0.97 Å. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1), one H(3), and one H(4) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(4) is bonded in a distorted single-bond geometry to one Cu(3) and one C(1) atom. In the fourth O site, O(5) is bonded in a 2-coordinate geometry to one Cu(2), one Cu(4), and one C(4) atom. In the fifth O site, O(6) is bonded in a water-like geometry to one Cu(4) and one C(4) atom. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(9) atom. In the seventh O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(9) atom. In the eighth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one C(12) atom. In the ninth O site, O(10) is bonded in a distorted single-bond geometry to one Cu(2) and one C(12) atom. Linkers: 4 [NH][C@@H](CC([O])=O)C([O])=O ,4 [NH][C@H](CC([O])=O)C([O])=O ,8 C1=NN=C[N]1. Metal clusters: 16 [Cu]. The MOF has largest included sphere 4.13 A, density 1.95 g/cm3, surface area 3129.31 m2/g, accessible volume 0.14 cm3/g