CuC16H14(NO)4(CH3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CuC16H14(NO)4 clusters. In one of the CuC16H14(NO)4 clusters, Cu(1) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent O(2) atoms. Both Cu(1)-N(2) bond lengths are 2.00 Å. Both Cu(1)-O(2) bond lengths are 1.99 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(2), and one H(1) atom. The C(1)-C(9) bond length is 1.37 Å. The C(1)-N(2) bond length is 1.38 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(2)-C(4) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.50 Å. The C(4)-C(6) bond length is 1.40 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(5)-O(1) bond length is 1.26 Å. The C(5)-O(2) bond length is 1.30 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(6)-H(6) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a 3-coordinate geometry to one N(1), one H(7), and one H(8) atom. The C(7)-N(1) bond length is 1.47 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.10 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(9) atom. The C(8)-N(1) bond length is 1.35 Å. The C(8)-N(2) bond length is 1.34 Å. The C(8)-H(9) bond length is 1.08 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one H(10) atom. The C(9)-N(1) bond length is 1.38 Å. The C(9)-H(10) bond length is 1.08 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(7), one C(8), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(8) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(9) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(5) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cu(1) and one C(5) atom. In one of the CuC16H14(NO)4 clusters, Cu(2) is bonded in a square co-planar geometry to two equivalent N(4) and two equivalent O(4) atoms. Both Cu(2)-N(4) bond lengths are 1.97 Å. Both Cu(2)-O(4) bond lengths are 2.02 Å. There are eight inequivalent C sites. In the first C site, C(11) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(16) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-C(14) bond length is 1.40 Å. The C(11)-C(16) bond length is 1.50 Å. In the second C site, C(12) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(14) atom. The C(12)-N(3) bond length is 1.35 Å. The C(12)-N(4) bond length is 1.34 Å. The C(12)-H(14) bond length is 1.08 Å. In the third C site, C(13) is bonded in a distorted single-bond geometry to one C(11) and one H(15) atom. The C(13)-H(15) bond length is 1.09 Å. In the fourth C site, C(14) is bonded in a distorted single-bond geometry to one C(11) and one H(16) atom. The C(14)-H(16) bond length is 1.09 Å. In the fifth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(4), and one H(17) atom. The C(15)-C(17) bond length is 1.37 Å. The C(15)-N(4) bond length is 1.38 Å. The C(15)-H(17) bond length is 1.08 Å. In the sixth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(3), and one O(4) atom. The C(16)-O(3) bond length is 1.26 Å. The C(16)-O(4) bond length is 1.30 Å. In the seventh C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(3), and one H(18) atom. The C(17)-N(3) bond length is 1.38 Å. The C(17)-H(18) bond length is 1.08 Å. In the eighth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one N(3) and two equivalent H(19,20) atoms. The C(18)-N(3) bond length is 1.46 Å. Both C(18)-H(19,20) bond lengths are 1.10 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one C(12), one C(17), and one C(18) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(12), and one C(15) atom. There are six inequivalent H sites. In the first H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(19,20) is bonded in a single-bond geometry to one C(18) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(16) atom. In the second O site, O(4) is bonded in a water-like geometry to one Cu(2) and one C(16) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 1.96 A, density 1.56 g/cm3, surface area 5001.16 m2/g, accessible volume 0.18 cm3/g