CuC8H14(NO)6(CH2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and four CuC8H14(NO)6 clusters. In each CuC8H14(NO)6 cluster, Cu(1) is bonded in an octahedral geometry to two equivalent N(3), one O(1), one O(2), and two equivalent O(3) atoms. Both Cu(1)-N(3) bond lengths are 1.97 Å. The Cu(1)-O(1) bond length is 2.42 Å. The Cu(1)-O(2) bond length is 2.36 Å. Both Cu(1)-O(3) bond lengths are 2.06 Å. There are four inequivalent C sites. In the first C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(3), and one H(4) atom. The C(2)-N(1) bond length is 1.46 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(5) atom. The C(3)-N(2) bond length is 1.33 Å. The C(3)-N(3) bond length is 1.36 Å. The C(3)-H(5) bond length is 1.08 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(6) atom. The C(4)-N(1) bond length is 1.34 Å. The C(4)-N(3) bond length is 1.34 Å. The C(4)-H(6) bond length is 1.08 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one H(7), one O(3), and one O(4) atom. The C(5)-H(7) bond length is 1.11 Å. The C(5)-O(3) bond length is 1.28 Å. The C(5)-O(4) bond length is 1.26 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(3) and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(4) atom. There are seven inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one O(1) atom. The H(8)-O(1) bond length is 0.99 Å. In the seventh H site, H(9) is bonded in a single-bond geometry to one O(2) atom. The H(9)-O(2) bond length is 0.99 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and two equivalent H(8) atoms. In the second O site, O(2) is bonded in a water-like geometry to one Cu(1) and two equivalent H(9) atoms. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(5) atom. Linkers: 1 [CH]1N=C[N]N1CCCCn1cncn1 ,1 c1ncn(CCCCn2cncn2)n1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 1.81 A, density 1.63 g/cm3, surface area 4694.94 m2/g, accessible volume 0.15 cm3/g