CoC19H15(N3Br)2CH is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one CoC19H15(N3Br)2 cluster. In the CoC19H15(N3Br)2 cluster, Co(1) is bonded in a tetrahedral geometry to one N(1), one N(4), one Br(1), and one Br(2) atom. The Co(1)-N(1) bond length is 1.98 Å. The Co(1)-N(4) bond length is 1.98 Å. The Co(1)-Br(1) bond length is 2.36 Å. The Co(1)-Br(2) bond length is 2.36 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(4), one C(9), and one H(1) atom. The C(1)-C(4) bond length is 1.40 Å. The C(1)-C(9) bond length is 1.39 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(12), one C(2), and one C(6) atom. The C(3)-C(12) bond length is 1.50 Å. The C(3)-C(6) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(14), and one C(9) atom. The C(4)-C(14) bond length is 1.51 Å. The C(4)-C(9) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(16) and one H(3) atom. The C(5)-C(16) bond length is 1.39 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(13), one C(17), and one N(1) atom. The C(7)-C(13) bond length is 1.41 Å. The C(7)-C(17) bond length is 1.40 Å. The C(7)-N(1) bond length is 1.38 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(15), one C(18), and one N(4) atom. The C(8)-C(15) bond length is 1.40 Å. The C(8)-C(18) bond length is 1.41 Å. The C(8)-N(4) bond length is 1.39 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(1), one C(4), and one H(5) atom. The C(9)-H(5) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-H(6) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(20), and one H(7) atom. The C(11)-C(20) bond length is 1.39 Å. The C(11)-H(7) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a 3-coordinate geometry to one C(3), one N(6), one H(8), and one H(9) atom. The C(12)-N(6) bond length is 1.47 Å. The C(12)-H(8) bond length is 1.10 Å. The C(12)-H(9) bond length is 1.10 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(16), one C(7), and one N(6) atom. The C(13)-C(16) bond length is 1.40 Å. The C(13)-N(6) bond length is 1.37 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one N(3), one H(10), and one H(11) atom. The C(14)-N(3) bond length is 1.46 Å. The C(14)-H(10) bond length is 1.10 Å. The C(14)-H(11) bond length is 1.10 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(8) and one H(12) atom. The C(15)-H(12) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(13), one C(5), and one H(13) atom. The C(16)-H(13) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(7) and one H(14) atom. The C(17)-H(14) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(20), one C(8), and one N(3) atom. The C(18)-C(20) bond length is 1.40 Å. The C(18)-N(3) bond length is 1.37 Å. In the nineteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(11), one C(18), and one H(16) atom. The C(20)-H(16) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Co(1), one C(7), and one N(2) atom. The N(1)-N(2) bond length is 1.32 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(1) and one N(6) atom. The N(2)-N(6) bond length is 1.34 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one N(5) atom. The N(3)-N(5) bond length is 1.34 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Co(1), one C(8), and one N(5) atom. The N(4)-N(5) bond length is 1.32 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one N(3) and one N(4) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one C(12), one C(13), and one N(2) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Co(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Co(1) atom. Linkers: 2 c1ccc2c(c1)nnn2Cc1ccc(Cn2nnc3ccccc32)cc1. Metal clusters: 2 [Co]. The MOF has largest included sphere 1.89 A, density 1.89 g/cm3, surface area 4057.13 m2/g, accessible volume 0.10 cm3/g