(CH)2PbC12H14S2O17 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a PbC12H14S2O17 framework. In the PbC12H14S2O17 framework, Pb(1) is bonded in a 6-coordinate geometry to one O(12), one O(16), one O(2), one O(3), one O(4), and one O(6) atom. The Pb(1)-O(12) bond length is 2.66 Å. The Pb(1)-O(16) bond length is 2.59 Å. The Pb(1)-O(2) bond length is 2.73 Å. The Pb(1)-O(3) bond length is 2.77 Å. The Pb(1)-O(4) bond length is 2.70 Å. The Pb(1)-O(6) bond length is 2.41 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one O(7) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-O(7) bond length is 1.37 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one S(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-S(1) bond length is 1.77 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(13) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(13) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-C(7) bond length is 1.46 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one O(10) atom. The C(5)-O(10) bond length is 1.34 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(8), and one O(9) atom. The C(7)-O(8) bond length is 1.32 Å. The C(7)-O(9) bond length is 1.26 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(9), and one S(2) atom. The C(8)-C(13) bond length is 1.38 Å. The C(8)-C(9) bond length is 1.42 Å. The C(8)-S(2) bond length is 1.78 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one O(17) atom. The C(9)-O(17) bond length is 1.36 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one O(14) atom. The C(11)-C(12) bond length is 1.42 Å. The C(11)-O(14) bond length is 1.34 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-C(14) bond length is 1.46 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(16) atom. The C(13)-H(16) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(15), and one O(16) atom. The C(14)-O(15) bond length is 1.32 Å. The C(14)-O(16) bond length is 1.27 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(13) and one O(4) atom. The H(3)-O(13) bond length is 1.69 Å. The H(3)-O(4) bond length is 1.00 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(4) atom. The H(4)-O(4) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(6) atom. The H(5)-O(6) bond length is 0.99 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(1) and one O(6) atom. The H(6)-O(1) bond length is 1.70 Å. The H(6)-O(6) bond length is 0.99 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(7) atom. The H(7)-O(7) bond length is 0.98 Å. In the eighth H site, H(8) is bonded in a linear geometry to one O(4) and one O(8) atom. The H(8)-O(4) bond length is 1.53 Å. The H(8)-O(8) bond length is 1.03 Å. In the ninth H site, H(9) is bonded in a distorted bent 150 degrees geometry to one O(10) and one O(9) atom. The H(9)-O(10) bond length is 1.01 Å. The H(9)-O(9) bond length is 1.62 Å. In the tenth H site, H(10) is bonded in a distorted bent 150 degrees geometry to one O(14) and one O(16) atom. The H(10)-O(14) bond length is 1.00 Å. The H(10)-O(16) bond length is 1.67 Å. In the eleventh H site, H(11) is bonded in a distorted linear geometry to one O(15) and one O(2) atom. The H(11)-O(15) bond length is 1.01 Å. The H(11)-O(2) bond length is 1.65 Å. In the twelfth H site, H(12) is bonded in a distorted linear geometry to one O(17) and one O(5) atom. The H(12)-O(17) bond length is 1.01 Å. The H(12)-O(5) bond length is 1.57 Å. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(3) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one O(1), one O(3), and one O(5) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.48 Å. The S(1)-O(5) bond length is 1.47 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one C(8), one O(11), one O(12), and one O(13) atom. The S(2)-O(11) bond length is 1.49 Å. The S(2)-O(12) bond length is 1.47 Å. The S(2)-O(13) bond length is 1.47 Å. There are seventeen inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one H(6) and one S(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Pb(1), one H(1), one H(11), and one H(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Pb(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Pb(1), one H(3), one H(4), and one H(8) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one H(12) and one S(1) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Pb(1), one H(5), and one H(6) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one C(1) and one H(7) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one C(7) and one H(8) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one C(7) and one H(9) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one C(5) and one H(9) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one S(2) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Pb(1) and one S(2) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one H(3) and one S(2) atom. In the fourteenth O site, O(14) is bonded in a water-like geometry to one C(11) and one H(10) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one C(14) and one H(11) atom. In the sixteenth O site, O(16) is bonded in a 1-coordinate geometry to one Pb(1), one C(14), and one H(10) atom. In the seventeenth O site, O(17) is bonded in a water-like geometry to one C(9) and one H(12) atom. Linkers: 4 [O]S([O])([O])c1cc(C(=O)O)c(O)cc1O. Metal clusters: 2 O.O.O.O=S(=O)=O.O=S(=O)=O.O=[C]O.O=[C]O.[OH].[OH].[Pb]. The MOF has largest included sphere 2.46 A, density 2.35 g/cm3, surface area 2879.84 m2/g, accessible volume 0.09 cm3/g