Zn3C14H18(NO7)2(CH)16(CH2)4(C8NH5)2(C7NH4)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, four 02329_fluka molecules, two C7NH4 clusters, one C8NH5 cluster, and one Zn3C14H18(NO7)2 cluster. In one of the C7NH4 clusters, there are seven inequivalent C sites. In the first C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(12), and one H(13) atom. The C(15)-N(2) bond length is 1.45 Å. The C(15)-H(12) bond length is 1.10 Å. The C(15)-H(13) bond length is 1.10 Å. In the second C site, C(16) is bonded in a distorted single-bond geometry to one C(21) and one N(2) atom. The C(16)-C(21) bond length is 1.43 Å. The C(16)-N(2) bond length is 1.39 Å. In the third C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(17) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(17) bond length is 1.09 Å. In the fourth C site, C(21) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(22) atom. The C(21)-C(22) bond length is 1.44 Å. In the fifth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(24) atom. The C(22)-C(23) bond length is 1.44 Å. The C(22)-C(24) bond length is 1.40 Å. In the sixth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one N(2) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-N(2) bond length is 1.39 Å. In the seventh C site, C(24) is bonded in a distorted single-bond geometry to one C(22), one C(23), and one H(18) atom. The C(24)-H(18) bond length is 1.09 Å. N(2) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(23) atom. There are four inequivalent H sites. In the first H site, H(17) is bonded in a single-bond geometry to one C(20) atom. In the second H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In one of the C7NH4 clusters, there are seven inequivalent C sites. In the first C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(26) atom. The C(32)-C(33) bond length is 1.40 Å. The C(32)-H(26) bond length is 1.09 Å. In the second C site, C(33) is bonded in a trigonal planar geometry to one C(28), one C(32), and one C(34) atom. The C(33)-C(28) bond length is 1.43 Å. The C(33)-C(34) bond length is 1.45 Å. In the third C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(36) atom. The C(34)-C(35) bond length is 1.44 Å. The C(34)-C(36) bond length is 1.40 Å. In the fourth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(34), one C(36), and one N(3) atom. The C(35)-C(36) bond length is 1.40 Å. The C(35)-N(3) bond length is 1.39 Å. In the fifth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(34), one C(35), and one H(27) atom. The C(36)-H(27) bond length is 1.09 Å. In the sixth C site, C(27) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(21), and one H(22) atom. The C(27)-N(3) bond length is 1.45 Å. The C(27)-H(21) bond length is 1.10 Å. The C(27)-H(22) bond length is 1.10 Å. In the seventh C site, C(28) is bonded in a distorted single-bond geometry to one C(33) and one N(3) atom. The C(28)-N(3) bond length is 1.39 Å. N(3) is bonded in a trigonal planar geometry to one C(27), one C(28), and one C(35) atom. There are four inequivalent H sites. In the first H site, H(21) is bonded in a single-bond geometry to one C(27) atom. In the second H site, H(22) is bonded in a single-bond geometry to one C(27) atom. In the third H site, H(26) is bonded in a single-bond geometry to one C(32) atom. In the fourth H site, H(27) is bonded in a single-bond geometry to one C(36) atom. In the C8NH5 cluster, there are eight inequivalent C sites. In the first C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(3), and one H(4) atom. The C(3)-N(1) bond length is 1.45 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(4) bond length is 1.10 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(9) and one N(1) atom. The C(4)-C(9) bond length is 1.43 Å. The C(4)-N(1) bond length is 1.39 Å. In the third C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(7) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(8) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(8) bond length is 1.09 Å. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(8) atom. The C(9)-C(10) bond length is 1.44 Å. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.43 Å. The C(10)-C(12) bond length is 1.40 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one N(1) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(1) bond length is 1.39 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(10), one C(11), and one H(9) atom. The C(12)-H(9) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(4) atom. There are five inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the Zn3C14H18(NO7)2 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(5), and one O(7) atom. The Zn(1)-O(1) bond length is 2.01 Å. The Zn(1)-O(3) bond length is 1.94 Å. The Zn(1)-O(5) bond length is 1.96 Å. The Zn(1)-O(7) bond length is 2.03 Å. In the second Zn site, Zn(2) is bonded in an octahedral geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. Both Zn(2)-O(2) bond lengths are 2.11 Å. Both Zn(2)-O(4) bond lengths are 2.08 Å. Both Zn(2)-O(6) bond lengths are 2.14 Å. There are seven inequivalent C sites. In the first C site, C(37) is bonded in a trigonal planar geometry to one N(4), one H(28), and one O(7) atom. The C(37)-N(4) bond length is 1.33 Å. The C(37)-H(28) bond length is 1.10 Å. The C(37)-O(7) bond length is 1.26 Å. In the second C site, C(38) is bonded to one N(4), one H(29), one H(30), and one H(31) atom to form corner-sharing CH3N tetrahedra. The C(38)-N(4) bond length is 1.47 Å. The C(38)-H(29) bond length is 1.09 Å. The C(38)-H(30) bond length is 1.10 Å. The C(38)-H(31) bond length is 1.10 Å. In the third C site, C(39) is bonded to one N(4), one H(32), one H(33), and one H(34) atom to form corner-sharing CH3N tetrahedra. The C(39)-N(4) bond length is 1.47 Å. The C(39)-H(32) bond length is 1.09 Å. The C(39)-H(33) bond length is 1.10 Å. The C(39)-H(34) bond length is 1.10 Å. In the fourth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.27 Å. In the fifth C site, C(2) is bonded in a distorted water-like geometry to one C(1), one H(1), and one H(2) atom. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. In the sixth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(13)-O(3) bond length is 1.28 Å. The C(13)-O(4) bond length is 1.26 Å. In the seventh C site, C(25) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(25)-O(5) bond length is 1.29 Å. The C(25)-O(6) bond length is 1.26 Å. N(4) is bonded in a trigonal planar geometry to one C(37), one C(38), and one C(39) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(28) is bonded in a single-bond geometry to one C(37) atom. In the fourth H site, H(29) is bonded in a single-bond geometry to one C(38) atom. In the fifth H site, H(30) is bonded in a single-bond geometry to one C(38) atom. In the sixth H site, H(31) is bonded in a single-bond geometry to one C(38) atom. In the seventh H site, H(32) is bonded in a single-bond geometry to one C(39) atom. In the eighth H site, H(33) is bonded in a single-bond geometry to one C(39) atom. In the ninth H site, H(34) is bonded in a single-bond geometry to one C(39) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(13) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(25) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(37) atom. Linkers: 3 [O]C(=O)CCn1c2ccccc2c2cc3c(cc21)c1ccccc1n3CCC([O])=O ,2 [O]C(=O)CCn1c2c[c]ccc2c2cc3c(cc21)c1ccccc1n3CCC([O])=O. Metal clusters: 3 [Zn]. The MOF has largest included sphere 5.63 A, density 1.20 g/cm3, surface area 4899.46 m2/g, accessible volume 0.33 cm3/g