CdC12H8S2(NO2)2 crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded to four equivalent S(1) and two equivalent O(2) atoms to form distorted edge-sharing CdS4O2 octahedra. There are two shorter (2.62 Å) and two longer (2.81 Å) Cd(1)-S(1) bond lengths. Both Cd(1)-O(2) bond lengths are 2.32 Å. There are six inequivalent C sites. In the first C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one S(1) atom. The C(5)-C(6) bond length is 1.42 Å. The C(5)-N(1) bond length is 1.37 Å. The C(5)-S(1) bond length is 1.73 Å. In the second C site, C(6) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(5) atom. The C(6)-C(3) bond length is 1.51 Å. The C(6)-C(4) bond length is 1.40 Å. In the third C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-H(1) bond length is 1.09 Å. In the fourth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one H(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the fifth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(2) atom. The C(3)-O(1) bond length is 1.27 Å. The C(3)-O(2) bond length is 1.27 Å. In the sixth C site, C(4) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one C(2), one C(5), and one H(4) atom. The N(1)-H(4) bond length is 1.07 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a distorted linear geometry to one N(1) and one O(1) atom. The H(4)-O(1) bond length is 1.60 Å. S(1) is bonded in a distorted T-shaped geometry to two equivalent Cd(1) and one C(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(3) and one H(4) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(3) atom. Linkers: 4 [O]C(=O)c1ccc[nH]c1=S. Metal clusters: 2 [Cd]. The MOF has largest included sphere 1.85 A, density 2.19 g/cm3, surface area 3257.35 m2/g, accessible volume 0.09 cm3/g