CuC13NH13O7CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a CuC13NH13O7 framework. In the CuC13NH13O7 framework, Cu(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(7) atom. The Cu(1)-N(1) bond length is 2.00 Å. The Cu(1)-O(1) bond length is 1.97 Å. The Cu(1)-O(2) bond length is 1.98 Å. The Cu(1)-O(3) bond length is 1.97 Å. The Cu(1)-O(7) bond length is 2.45 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(4) and one H(5) atom. The C(1)-C(4) bond length is 1.40 Å. The C(1)-H(5) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(11) and one O(5) atom. The C(2)-C(11) bond length is 1.42 Å. The C(2)-O(5) bond length is 1.35 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(7), one C(8), and one C(9) atom. The C(3)-C(7) bond length is 1.40 Å. The C(3)-C(8) bond length is 1.40 Å. The C(3)-C(9) bond length is 1.49 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(4) atom. The C(4)-C(13) bond length is 1.40 Å. The C(4)-C(4) bond length is 1.48 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(1), and one O(6) atom. The C(6)-C(11) bond length is 1.50 Å. The C(6)-O(1) bond length is 1.28 Å. The C(6)-O(6) bond length is 1.27 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(11), one C(3), and one H(7) atom. The C(7)-C(11) bond length is 1.39 Å. The C(7)-H(7) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(3) and one H(8) atom. The C(8)-H(8) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(4) atom. The C(9)-O(3) bond length is 1.29 Å. The C(9)-O(4) bond length is 1.27 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(1), and one H(9) atom. The C(10)-C(13) bond length is 1.39 Å. The C(10)-N(1) bond length is 1.35 Å. The C(10)-H(9) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. In the eleventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(10) atom. The C(12)-N(1) bond length is 1.35 Å. The C(12)-H(10) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(10), one C(4), and one H(11) atom. The C(13)-H(11) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a tetrahedral geometry to one H(12), one H(13), one H(14), and one O(5) atom. The C(14)-H(12) bond length is 1.09 Å. The C(14)-H(13) bond length is 1.09 Å. The C(14)-H(14) bond length is 1.10 Å. The C(14)-O(5) bond length is 1.44 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(12) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(2) and one O(4) atom. The H(1)-O(2) bond length is 1.03 Å. The H(1)-O(4) bond length is 1.55 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(2) and one O(6) atom. The H(2)-O(2) bond length is 1.00 Å. The H(2)-O(6) bond length is 1.65 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(6) and one O(7) atom. The H(3)-O(6) bond length is 1.75 Å. The H(3)-O(7) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(7) atom. The H(4)-O(7) bond length is 0.97 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(6) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one H(1), and one H(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(9) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(9) and one H(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(14) and one C(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one C(6), one H(2), and one H(3) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Cu(1), one H(3), and one H(4) atom. Linkers: 2 COc1ccc(C([O])=O)cc1C([O])=O ,1 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 O.O.O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 2.53 A, density 1.68 g/cm3, surface area 4314.32 m2/g, accessible volume 0.11 cm3/g