CuH14(C8N5)2(CH2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CuH14(C8N5)2 clusters. In each CuH14(C8N5)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(5) atoms. Both Cu(1)-N(1) bond lengths are 2.03 Å. Both Cu(1)-N(5) bond lengths are 1.95 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one C(3), one H(1), and one H(2) atom. The C(1)-C(3) bond length is 1.48 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(1), one N(4), and one N(5) atom. The C(3)-N(4) bond length is 1.36 Å. The C(3)-N(5) bond length is 1.34 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one N(5) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-C(9) bond length is 1.40 Å. The C(4)-N(5) bond length is 1.39 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(4) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(4) bond length is 1.39 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(6) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(6) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(7) atom. The C(7)-H(7) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(8) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(4), one C(8), and one H(9) atom. The C(9)-H(9) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one N(2) atom. The N(1)-N(2) bond length is 1.20 Å. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.17 Å. In the third N site, N(3) is bonded in a distorted single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one H(5) atom. The N(4)-H(5) bond length is 1.03 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(4) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. Linkers: 2 c1ccc2[nH]c(CCCCc3nc4ccccc4[nH]3)nc2c1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 1.98 A, density 1.58 g/cm3, surface area 4933.86 m2/g, accessible volume 0.11 cm3/g