ZnC11H9(NO)4CH crystallizes in the tetragonal I4_1/a space group. The structure consists of sixteen 02329_fluka molecules inside a ZnC11H9(NO)4 framework. In the ZnC11H9(NO)4 framework, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 1.99 Å. The Zn(1)-N(3) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 2.00 Å. The Zn(1)-O(3) bond length is 1.97 Å. There are eleven inequivalent C sites. In the first C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(8) atom. The C(11)-C(10) bond length is 1.35 Å. The C(11)-C(12) bond length is 1.48 Å. The C(11)-H(8) bond length is 1.09 Å. In the second C site, C(12) is bonded in a bent 120 degrees geometry to one C(11), one O(3), and one O(4) atom. The C(12)-O(3) bond length is 1.30 Å. The C(12)-O(4) bond length is 1.27 Å. In the third C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.08 Å. In the fourth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-N(1) bond length is 1.37 Å. The C(2)-H(2) bond length is 1.08 Å. In the fifth C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one N(2) atom. The C(3)-C(4) bond length is 1.43 Å. The C(3)-N(2) bond length is 1.39 Å. In the sixth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the seventh C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(6)-O(1) bond length is 1.31 Å. The C(6)-O(2) bond length is 1.25 Å. In the eighth C site, C(7) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(5) atom. The C(7)-N(3) bond length is 1.34 Å. The C(7)-N(4) bond length is 1.35 Å. The C(7)-H(5) bond length is 1.09 Å. In the ninth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(3), and one H(6) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-N(3) bond length is 1.37 Å. The C(8)-H(6) bond length is 1.08 Å. In the tenth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one N(4) atom. The C(9)-C(10) bond length is 1.44 Å. The C(9)-N(4) bond length is 1.39 Å. In the eleventh C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(7) atom. The C(10)-H(7) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(7), and one C(8) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(7), one C(9), and one H(10) atom. The N(4)-H(10) bond length is 1.05 Å. In the third N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one H(9) atom. The N(2)-H(9) bond length is 1.05 Å. In the fourth N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a distorted single-bond geometry to one N(2) and one O(1) atom. The H(9)-O(1) bond length is 1.68 Å. In the ninth H site, H(10) is bonded in a distorted linear geometry to one N(4) and one O(4) atom. The H(10)-O(4) bond length is 1.66 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(6), and one H(9) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(6) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(12) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one C(12) and one H(10) atom. Linkers: 16 [O]C(=O)/C=C/c1cnc[nH]1. Metal clusters: 8 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 7.38 A, density 1.18 g/cm3, surface area 4692.30 m2/g, accessible volume 0.43 cm3/g