Cu(H2NC6H4COO)2(CH3)4(CHO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four methanol molecules, and one Cu(H2NC6H4COO)2 cluster. In the Cu(H2NC6H4COO)2 cluster, Cu(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(2), and one O(4) atom. The Cu(1)-N(1) bond length is 2.02 Å. The Cu(1)-N(2) bond length is 2.00 Å. The Cu(1)-O(1) bond length is 1.99 Å. The Cu(1)-O(2) bond length is 2.29 Å. The Cu(1)-O(4) bond length is 2.02 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(5)-O(4) bond length is 1.29 Å. The C(5)-O(5) bond length is 1.25 Å. In the third C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(14) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(14) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(15) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(15) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(14) bond length is 1.50 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(16) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(16) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one N(1), and one H(17) atom. The C(13)-N(1) bond length is 1.35 Å. The C(13)-H(17) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a distorted water-like geometry to one C(11), one H(18), and one H(19) atom. The C(14)-H(18) bond length is 1.10 Å. The C(14)-H(19) bond length is 1.10 Å. In the ninth C site, C(15) is bonded in a distorted water-like geometry to one C(16), one H(20), and one H(21) atom. The C(15)-C(16) bond length is 1.50 Å. The C(15)-H(20) bond length is 1.10 Å. The C(15)-H(21) bond length is 1.10 Å. In the tenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(19) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(19) bond length is 1.40 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(22) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(22) bond length is 1.09 Å. In the twelfth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one N(2), and one H(23) atom. The C(18)-N(2) bond length is 1.35 Å. The C(18)-H(23) bond length is 1.09 Å. In the thirteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one H(24) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-H(24) bond length is 1.09 Å. In the fourteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one N(2), and one H(25) atom. The C(20)-N(2) bond length is 1.35 Å. The C(20)-H(25) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(18), and one C(20) atom. There are twelve inequivalent H sites. In the first H site, H(14) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(15) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(21) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(22) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(23) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(24) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(25) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(5) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. Linkers: 2 CC(C)(O)C([O])=O. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.73 A, density 1.43 g/cm3, surface area 5262.13 m2/g, accessible volume 0.14 cm3/g