(CH3)2CuC8H8S2I is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two CuC8H8S2I clusters. In each CuC8H8S2I cluster, Cu(1) is bonded to two equivalent S(1) and two equivalent I(1) atoms to form distorted edge-sharing CuS2I2 tetrahedra. Both Cu(1)-S(1) bond lengths are 2.30 Å. Both Cu(1)-I(1) bond lengths are 2.65 Å. There are four inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one S(1) atom. The C(2)-C(1) bond length is 1.40 Å. The C(2)-C(3) bond length is 1.40 Å. The C(2)-S(1) bond length is 1.78 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1,2) atom. The C(3)-H(1,2) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted water-like geometry to one H(3), one H(4), and one S(1) atom. The C(4)-H(3) bond length is 1.10 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-S(1) bond length is 1.83 Å. In the fourth C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one H(1,2) atom. The C(1)-H(1,2) bond length is 1.09 Å. There are three inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. S(1) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(2), and one C(4) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 4 [CH2]CSc1ccc(SCC)cc1 ,2 CCSc1ccc(SCC)cc1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.07 A, density 2.02 g/cm3, surface area 3835.54 m2/g, accessible volume 0.08 cm3/g