HgC12H10(NCl)2(CH)2(CH2)2(CH3)4(C5H4O)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; four 02329_fluka molecules; eight 02329_fluka molecules; four 1-propene, 1-methoxy-2-methyl- molecules; and two HgC12H10(NCl)2 clusters. In each HgC12H10(NCl)2 cluster, Hg(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(4), one Cl(1), and one Cl(2) atom. The Hg(1)-N(1) bond length is 2.45 Å. The Hg(1)-N(4) bond length is 2.45 Å. The Hg(1)-Cl(1) bond length is 2.43 Å. The Hg(1)-Cl(2) bond length is 2.40 Å. There are twelve inequivalent C sites. In the first C site, C(56) is bonded in a trigonal planar geometry to one C(55), one C(57), and one C(60) atom. The C(56)-C(55) bond length is 1.45 Å. The C(56)-C(57) bond length is 1.41 Å. The C(56)-C(60) bond length is 1.41 Å. In the second C site, C(57) is bonded in a distorted single-bond geometry to one C(56), one C(58), and one H(69) atom. The C(57)-C(58) bond length is 1.39 Å. The C(57)-H(69) bond length is 1.09 Å. In the third C site, C(58) is bonded in a distorted trigonal planar geometry to one C(57), one N(4), and one H(70) atom. The C(58)-N(4) bond length is 1.34 Å. The C(58)-H(70) bond length is 1.09 Å. In the fourth C site, C(59) is bonded in a distorted trigonal planar geometry to one C(60), one N(4), and one H(71) atom. The C(59)-C(60) bond length is 1.39 Å. The C(59)-N(4) bond length is 1.35 Å. The C(59)-H(71) bond length is 1.09 Å. In the fifth C site, C(60) is bonded in a distorted single-bond geometry to one C(56), one C(59), and one H(72) atom. The C(60)-H(72) bond length is 1.09 Å. In the sixth C site, C(55) is bonded in a distorted single-bond geometry to one C(56) and one H(68) atom. The C(55)-H(68) bond length is 1.09 Å. In the seventh C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the eighth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the ninth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.45 Å. In the tenth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the eleventh C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the twelfth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Hg(1), one C(1), and one C(5) atom. In the second N site, N(4) is bonded in a distorted trigonal planar geometry to one Hg(1), one C(58), and one C(59) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(68) is bonded in a single-bond geometry to one C(55) atom. In the seventh H site, H(69) is bonded in a single-bond geometry to one C(57) atom. In the eighth H site, H(70) is bonded in a single-bond geometry to one C(58) atom. In the ninth H site, H(71) is bonded in a single-bond geometry to one C(59) atom. In the tenth H site, H(72) is bonded in a single-bond geometry to one C(60) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Hg(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Hg(1) atom. Linkers: 1 CC[C@H](C)COc1cc(/C=C/c2ccncc2)c(OC[C@@H](C)CC)cc1/C=C/c1ccncc1 ,1 [C]/C=C(/C=C/c1ccncc1)C(=[CH])OC[C@@H](C)CC ,1 [C]/C=C/c1cc(OC[C@@H](C)CC)c(/C=C/c2ccncc2)cc1OC[C@@H](C)CC. Metal clusters: . The MOF has largest included sphere 4.55 A, density 1.47 g/cm3, surface area 4847.98 m2/g, accessible volume 0.25 cm3/g