MnC40H22(N4O3)2(CH)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and one MnC40H22(N4O3)2 cluster. In the MnC40H22(N4O3)2 cluster, Mn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent O(2) atoms. Both Mn(1)-N(1) bond lengths are 2.07 Å. Both Mn(1)-N(2) bond lengths are 2.07 Å. Both Mn(1)-O(2) bond lengths are 2.09 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-C(9) bond length is 1.43 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.43 Å. The C(5)-N(1) bond length is 1.37 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.43 Å. The C(6)-N(2) bond length is 1.37 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(17), one C(6), and one C(8) atom. The C(7)-C(17) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.42 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one N(4) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-N(4) bond length is 1.37 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(4), one C(8), and one N(3) atom. The C(9)-N(3) bond length is 1.37 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one N(3), and one N(4) atom. The C(10)-C(11) bond length is 1.45 Å. The C(10)-N(3) bond length is 1.34 Å. The C(10)-N(4) bond length is 1.38 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(16) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-C(16) bond length is 1.41 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(4) atom. The C(12)-H(4) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one O(1) atom. The C(14)-O(1) bond length is 1.36 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(16)-H(7) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(7) and one H(8) atom. The C(17)-H(8) bond length is 1.09 Å. In the sixteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(2), and one O(3) atom. The C(19)-C(20) bond length is 1.50 Å. The C(19)-O(2) bond length is 1.31 Å. The C(19)-O(3) bond length is 1.25 Å. In the seventeenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(23) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(23) bond length is 1.40 Å. In the eighteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(10) atom. The C(21)-H(10) bond length is 1.09 Å. In the nineteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(11) atom. The C(22)-N(2) bond length is 1.34 Å. The C(22)-H(11) bond length is 1.08 Å. In the twentieth C site, C(23) is bonded in a distorted single-bond geometry to one C(20) and one H(12) atom. The C(23)-H(12) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(1), one C(22), and one C(6) atom. In the third N site, N(3) is bonded in a water-like geometry to one C(10) and one C(9) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(8), and one H(13) atom. The N(4)-H(13) bond length is 1.03 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one N(4) atom. In the eleventh H site, H(14) is bonded in a distorted linear geometry to one O(1) and one O(2) atom. The H(14)-O(1) bond length is 1.01 Å. The H(14)-O(2) bond length is 1.64 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(14) and one H(14) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one C(19), and one H(14) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one C(19) atom. Linkers: 1 [O]C(=O)c1ccc(C([O])=O)cc1 ,1 Oc1ccc(-c2nc3c4cccnc4c4ncccc4c3[nH]2)cc1. Metal clusters: 1 [Mn]. The MOF has largest included sphere 2.41 A, density 1.58 g/cm3, surface area 4184.81 m2/g, accessible volume 0.15 cm3/g