(CH3)4ZnC8H8(SO5)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two ZnC8H8(SO5)2 clusters. In each ZnC8H8(SO5)2 cluster, Zn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms. Both Zn(1)-O(1) bond lengths are 2.12 Å. Both Zn(1)-O(2) bond lengths are 2.13 Å. Both Zn(1)-O(5) bond lengths are 2.14 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.49 Å. The C(2)-C(4) bond length is 1.42 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(4), and one O(5) atom. The C(3)-O(4) bond length is 1.29 Å. The C(3)-O(5) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one O(3) atom. The C(4)-O(3) bond length is 1.36 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a bent 150 degrees geometry to one O(3) and one O(4) atom. The H(1)-O(3) bond length is 1.02 Å. The H(1)-O(4) bond length is 1.57 Å. In the second H site, H(9) is bonded in a single-bond geometry to one O(2) atom. The H(9)-O(2) bond length is 0.99 Å. In the third H site, H(10) is bonded in a distorted single-bond geometry to one O(2) and one O(4) atom. The H(10)-O(2) bond length is 1.01 Å. The H(10)-O(4) bond length is 1.62 Å. In the fourth H site, H(2) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted single-bond geometry to one O(1) atom. The S(1)-O(1) bond length is 1.53 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Zn(1), one H(10), and one H(9) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(4) and one H(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one H(1), and one H(10) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(3) atom. Linkers: 1 [O]C(=O)c1cc(O)c(C([O])=O)cc1O. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.68 A, density 1.77 g/cm3, surface area 4372.94 m2/g, accessible volume 0.07 cm3/g