AgC17H16(N2O)2(CH2)2(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four 02329_fluka molecules, and one AgC17H16(N2O)2 cluster. In the AgC17H16(N2O)2 cluster, Ag(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(3), one O(1), and one O(2) atom. The Ag(1)-N(1) bond length is 2.18 Å. The Ag(1)-N(3) bond length is 2.25 Å. The Ag(1)-O(1) bond length is 2.39 Å. The Ag(1)-O(2) bond length is 2.40 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one N(2) atom. The C(1)-C(10) bond length is 1.48 Å. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.38 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one N(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.42 Å. The C(2)-N(2) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(7)-N(1) bond length is 1.39 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(5), and one H(6) atom. The C(8)-N(2) bond length is 1.46 Å. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.10 Å. In the ninth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one H(10), one H(11), and one H(9) atom. The C(10)-H(10) bond length is 1.10 Å. The C(10)-H(11) bond length is 1.10 Å. The C(10)-H(9) bond length is 1.10 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(20), one N(3), and one N(4) atom. The C(11)-C(20) bond length is 1.48 Å. The C(11)-N(3) bond length is 1.34 Å. The C(11)-N(4) bond length is 1.38 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one N(4) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-C(17) bond length is 1.42 Å. The C(12)-N(4) bond length is 1.38 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(12) atom. The C(13)-H(12) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(15) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(15) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one N(3) atom. The C(17)-N(3) bond length is 1.39 Å. In the fifteenth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(16), and one H(17) atom. The C(18)-N(4) bond length is 1.46 Å. The C(18)-H(16) bond length is 1.10 Å. The C(18)-H(17) bond length is 1.10 Å. In the sixteenth C site, C(20) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one H(20), one H(21), and one H(22) atom. The C(20)-H(20) bond length is 1.10 Å. The C(20)-H(21) bond length is 1.10 Å. The C(20)-H(22) bond length is 1.10 Å. In the seventeenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(21)-O(1) bond length is 1.27 Å. The C(21)-O(2) bond length is 1.27 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(8) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(11), and one C(17) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(18) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(20) atom. In the sixteenth H site, H(22) is bonded in a single-bond geometry to one C(20) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one C(21) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one C(21) atom. Linkers: 2 Cc1nc2ccccc2n1CCCCn1c(C)nc2ccccc21 ,2 Cc1nc2c[c][c]cc2n1CCCCn1c(C)nc2ccccc21. Metal clusters: 1 O1[Ag]OC2=C1O[Ag]O2. The MOF has largest included sphere 2.68 A, density 1.61 g/cm3, surface area 4560.68 m2/g, accessible volume 0.16 cm3/g