ZnC12H10(N3O)4(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two ZnC12H10(N3O)4 clusters. In each ZnC12H10(N3O)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(5), one N(6), one O(1), and one O(2) atom. The Zn(1)-N(5) bond length is 2.01 Å. The Zn(1)-N(6) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 1.98 Å. The Zn(1)-O(2) bond length is 1.98 Å. There are six inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1,2)-O(1) bond length is 1.30 Å. The C(1,2)-O(3) bond length is 1.25 Å. In the second C site, C(5,6) is bonded in a distorted trigonal non-coplanar geometry to one N(3,4); one N(9,10); and one H(5,6) atom. The C(5,6)-N(3,4) bond length is 1.47 Å. The C(5,6)-N(9,10) bond length is 1.45 Å. The C(5,6)-H(5,6) bond length is 1.10 Å. In the third C site, C(7,8) is bonded in a trigonal planar geometry to one N(3,4); one N(5); and one H(7,8) atom. The C(7,8)-N(3,4) bond length is 1.34 Å. The C(7,8)-N(5) bond length is 1.34 Å. The C(7,8)-H(7,8) bond length is 1.08 Å. In the fourth C site, C(9,10) is bonded in a trigonal planar geometry to one N(1,2); one N(5); and one H(9,10) atom. The C(9,10)-N(1,2) bond length is 1.32 Å. The C(9,10)-N(5) bond length is 1.37 Å. The C(9,10)-H(9,10) bond length is 1.08 Å. In the fifth C site, C(11,12) is bonded in a trigonal planar geometry to one N(11,12); one N(7,8); and one H(11,12) atom. The C(11,12)-N(11,12) bond length is 1.37 Å. The C(11,12)-N(7,8) bond length is 1.33 Å. The C(11,12)-H(11,12) bond length is 1.09 Å. In the sixth C site, C(13,14) is bonded in a trigonal planar geometry to one N(11,12); one N(9,10); and one H(13,14) atom. The C(13,14)-N(11,12) bond length is 1.33 Å. The C(13,14)-N(9,10) bond length is 1.35 Å. The C(13,14)-H(13,14) bond length is 1.09 Å. There are seven inequivalent N sites. In the first N site, N(1,2) is bonded in a distorted water-like geometry to one C(9,10) and one N(3,4) atom. The N(1,2)-N(3,4) bond length is 1.36 Å. In the second N site, N(3,4) is bonded in a distorted trigonal planar geometry to one C(5,6); one C(7,8); and one N(1,2) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Zn(1); one C(7,8); and one C(9,10) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one Zn(1); one C(7,8); and one C(9,10) atom. The N(6)-C(7,8) bond length is 1.34 Å. The N(6)-C(9,10) bond length is 1.37 Å. In the fifth N site, N(7,8) is bonded in a distorted water-like geometry to one C(11,12) and one N(9,10) atom. The N(7,8)-N(9,10) bond length is 1.37 Å. In the sixth N site, N(9,10) is bonded in a 3-coordinate geometry to one C(13,14); one C(5,6); and one N(7,8) atom. In the seventh N site, N(11,12) is bonded in a water-like geometry to one C(11,12) and one C(13,14) atom. There are five inequivalent H sites. In the first H site, H(5,6) is bonded in a single-bond geometry to one C(5,6) atom. In the second H site, H(7,8) is bonded in a single-bond geometry to one C(7,8) atom. In the third H site, H(9,10) is bonded in a single-bond geometry to one C(9,10) atom. In the fourth H site, H(11,12) is bonded in a single-bond geometry to one C(11,12) atom. In the fifth H site, H(13,14) is bonded in a single-bond geometry to one C(13,14) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1,2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1,2) atom. The O(2)-C(1,2) bond length is 1.30 Å. In the third O site, O(3) is bonded in a single-bond geometry to one C(1,2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(1,2) atom. The O(4)-C(1,2) bond length is 1.25 Å. Linkers: 3 [O]C(=O)CC(n1cncn1)n1cncn1 ,1 [O]C(=O)C[C@@H](N1[CH]N=C[N]1)n1cncn1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.02 A, density 1.69 g/cm3, surface area 4271.44 m2/g, accessible volume 0.15 cm3/g