ZnC24N3H17O4 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two ZnC24N3H17O4 clusters. Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(4), one O(1), and one O(4) atom. The Zn(1)-N(1) bond length is 2.05 Å. The Zn(1)-N(4) bond length is 2.05 Å. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(4) bond length is 1.96 Å. There are twenty-four inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one C(19,20); one C(37,38); and one C(6) atom. The C(2)-C(19,20) bond length is 1.40 Å. The C(2)-C(37,38) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.51 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(15), one C(35), and one C(7) atom. The C(3)-C(15) bond length is 1.40 Å. The C(3)-C(35) bond length is 1.40 Å. The C(3)-C(7) bond length is 1.51 Å. In the third C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(4), and one O(8) atom. The C(6)-O(4) bond length is 1.31 Å. The C(6)-O(8) bond length is 1.25 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(5) atom. The C(7)-O(1) bond length is 1.31 Å. The C(7)-O(5) bond length is 1.25 Å. In the fifth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(1,2) atom. The C(10)-N(4) bond length is 1.35 Å. The C(10)-H(1,2) bond length is 1.09 Å. In the sixth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(31,32); one N(1); and one H(3,4) atom. The C(11)-C(31,32) bond length is 1.39 Å. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(3,4) bond length is 1.09 Å. In the seventh C site, C(13,14) is bonded in a trigonal planar geometry to one C(27,28); one C(31,32); and one C(47,48) atom. The C(13,14)-C(27,28) bond length is 1.47 Å. The C(13,14)-C(31,32) bond length is 1.40 Å. The C(13,14)-C(47,48) bond length is 1.40 Å. In the eighth C site, C(15) is bonded in a distorted single-bond geometry to one C(3) and one H(5,6) atom. The C(15)-H(5,6) bond length is 1.09 Å. In the ninth C site, C(17,18) is bonded in a distorted trigonal planar geometry to one C(27,28); one C(45,46); and one H(7,8) atom. The C(17,18)-C(27,28) bond length is 1.41 Å. The C(17,18)-C(45,46) bond length is 1.39 Å. The C(17,18)-H(7,8) bond length is 1.09 Å. In the tenth C site, C(19,20) is bonded in a distorted single-bond geometry to one C(1) and one H(9) atom. The C(19,20)-C(1) bond length is 1.40 Å. The C(19,20)-H(9) bond length is 1.08 Å. In the eleventh C site, C(21,22) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(33) atom. The C(21,22)-C(23) bond length is 1.41 Å. The C(21,22)-C(25) bond length is 1.48 Å. The C(21,22)-C(33) bond length is 1.41 Å. In the twelfth C site, C(23) is bonded in a distorted single-bond geometry to one C(21,22) and one H(11,12) atom. The C(23)-H(11,12) bond length is 1.09 Å. In the thirteenth C site, C(25) is bonded in a trigonal planar geometry to one C(21,22); one C(29,30); and one C(45,46) atom. The C(25)-C(29,30) bond length is 1.43 Å. The C(25)-C(45,46) bond length is 1.41 Å. In the fourteenth C site, C(27,28) is bonded in a trigonal planar geometry to one C(13,14); one C(17,18); and one C(43) atom. The C(27,28)-C(43) bond length is 1.39 Å. In the fifteenth C site, C(29,30) is bonded in a distorted trigonal planar geometry to one C(25), one C(43), and one N(5) atom. The C(29,30)-C(43) bond length is 1.41 Å. The C(29,30)-N(5) bond length is 1.37 Å. In the sixteenth C site, C(31,32) is bonded in a distorted single-bond geometry to one C(11); one C(13,14); and one H(13,14) atom. The C(31,32)-H(13,14) bond length is 1.09 Å. In the seventeenth C site, C(33) is bonded in a distorted single-bond geometry to one C(21,22) and one H(15,16) atom. The C(33)-H(15,16) bond length is 1.09 Å. In the eighteenth C site, C(35) is bonded in a distorted single-bond geometry to one C(3) and one H(17,18) atom. The C(35)-H(17,18) bond length is 1.09 Å. In the nineteenth C site, C(37,38) is bonded in a distorted single-bond geometry to one C(1) and one H(19) atom. The C(37,38)-C(1) bond length is 1.40 Å. The C(37,38)-H(19) bond length is 1.09 Å. In the twentieth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(21,22) atom. The C(40)-N(4) bond length is 1.35 Å. The C(40)-H(21,22) bond length is 1.09 Å. In the twenty-first C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(23,24) atom. The C(41)-N(1) bond length is 1.35 Å. The C(41)-H(23,24) bond length is 1.09 Å. In the twenty-second C site, C(43) is bonded in a distorted trigonal planar geometry to one C(27,28); one C(29,30); and one H(25,26) atom. The C(43)-H(25,26) bond length is 1.09 Å. In the twenty-third C site, C(45,46) is bonded in a distorted single-bond geometry to one C(17,18); one C(25); and one H(27,28) atom. The C(45,46)-H(27,28) bond length is 1.09 Å. In the twenty-fourth C site, C(47,48) is bonded in a distorted single-bond geometry to one C(13,14) and one H(29,30) atom. The C(47,48)-H(29,30) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(41) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(40) atom. In the third N site, N(5) is bonded in a distorted trigonal planar geometry to one C(29,30); one H(31,32); and one H(33,34) atom. The N(5)-H(31,32) bond length is 1.01 Å. The N(5)-H(33,34) bond length is 1.02 Å. There are seventeen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(9) atom. The H(1,2)-C(9) bond length is 1.09 Å. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(17,18) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(19,20) atom. The H(10)-C(19,20) bond length is 1.08 Å. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(13,14) is bonded in a single-bond geometry to one C(31,32) atom. In the eighth H site, H(15,16) is bonded in a single-bond geometry to one C(33) atom. In the ninth H site, H(17,18) is bonded in a single-bond geometry to one C(35) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(37,38) atom. The H(20)-C(37,38) bond length is 1.09 Å. In the eleventh H site, H(21,22) is bonded in a single-bond geometry to one C(39) atom. The H(21,22)-C(39) bond length is 1.09 Å. In the twelfth H site, H(23,24) is bonded in a single-bond geometry to one C(41) atom. In the thirteenth H site, H(25,26) is bonded in a single-bond geometry to one C(43) atom. In the fourteenth H site, H(27,28) is bonded in a single-bond geometry to one C(45,46) atom. In the fifteenth H site, H(29,30) is bonded in a single-bond geometry to one C(47,48) atom. In the sixteenth H site, H(31,32) is bonded in a single-bond geometry to one N(5) atom. In the seventeenth H site, H(33,34) is bonded in a single-bond geometry to one N(5) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the third O site, O(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one C(6) atom. Linkers: 1 [CH]=CC(=[CH])c1ccc(C2=C[CH]N([Zn](OC(=O)c3ccc(C([O])=O)cc3)(OC(=O)c3ccc(C([O])=O)cc3)N3[CH]C=C(c4ccc(-c5ccncc5)c(N)c4)C=C3)C=C2)c(N)c1 ,1 [NH]c1[c]ccc(C2=C[CH]N([Zn](OC(=O)c3ccc(C([O])=O)cc3)(OC(=O)c3ccc(C([O])=O)cc3)N3[CH]C=[C][C]=C3)C=C2)c1 ,1 Nc1cc(-c2ccncc2)ccc1C1=C[CH]N([Zn](O[C]=O)N2[CH]C=C(c3ccc(-c4ccncc4)c(N)c3)C=C2)C=C1. Metal clusters: 1 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.31 A, density 1.34 g/cm3, surface area 4498.75 m2/g, accessible volume 0.24 cm3/g