Zn3C52H34(N5O2)4(CH)4(CH2)8 crystallizes in the monoclinic C2/c space group. The structure consists of sixteen 02329_fluka molecules and thirty-two 02329_fluka molecules inside a Zn3C52H34(N5O2)4 framework. In the Zn3C52H34(N5O2)4 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(10), one N(9), and one O(1) atom. The Zn(1)-N(1) bond length is 2.05 Å. The Zn(1)-N(10) bond length is 2.04 Å. The Zn(1)-N(9) bond length is 2.02 Å. The Zn(1)-O(1) bond length is 1.93 Å. In the second Zn site, Zn(2) is bonded in a distorted tetrahedral geometry to two equivalent N(6) and two equivalent O(3) atoms. Both Zn(2)-N(6) bond lengths are 2.04 Å. Both Zn(2)-O(3) bond lengths are 1.96 Å. There are twenty-six inequivalent C sites. In the first C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.29 Å. The C(8)-O(4) bond length is 1.26 Å. In the second C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(12) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(12) bond length is 1.09 Å. In the third C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(13) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(13) bond length is 1.09 Å. In the fourth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(14) bond length is 1.45 Å. In the fifth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(14) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(14) bond length is 1.09 Å. In the sixth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one N(1), and one H(15) atom. The C(13)-N(1) bond length is 1.35 Å. The C(13)-H(15) bond length is 1.09 Å. In the seventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one N(4) atom. The C(14)-N(2) bond length is 1.36 Å. The C(14)-N(4) bond length is 1.35 Å. In the eighth C site, C(15) is bonded in a distorted water-like geometry to one C(16), one N(2), and one N(3) atom. The C(15)-C(16) bond length is 1.46 Å. The C(15)-N(2) bond length is 1.34 Å. The C(15)-N(3) bond length is 1.36 Å. In the ninth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(20) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(20) bond length is 1.40 Å. In the tenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(16) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(16) bond length is 1.09 Å. In the eleventh C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one N(5), and one H(17) atom. The C(18)-N(5) bond length is 1.34 Å. The C(18)-H(17) bond length is 1.09 Å. In the twelfth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(20), one N(5), and one H(18) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-N(5) bond length is 1.34 Å. The C(19)-H(18) bond length is 1.09 Å. In the thirteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(16), one C(19), and one H(19) atom. The C(20)-H(19) bond length is 1.09 Å. In the fourteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one N(6), and one H(20) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-N(6) bond length is 1.35 Å. The C(21)-H(20) bond length is 1.09 Å. In the fifteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(21) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(21) bond length is 1.09 Å. In the sixteenth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(26) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(26) bond length is 1.45 Å. In the seventeenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one C(25), and one H(22) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(22) bond length is 1.09 Å. In the eighteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one N(6), and one H(23) atom. The C(25)-N(6) bond length is 1.35 Å. The C(25)-H(23) bond length is 1.09 Å. In the nineteenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(23), one N(7), and one N(8) atom. The C(26)-N(7) bond length is 1.35 Å. The C(26)-N(8) bond length is 1.35 Å. In the twentieth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(28), one N(7), and one N(9) atom. The C(27)-C(28) bond length is 1.46 Å. The C(27)-N(7) bond length is 1.35 Å. The C(27)-N(9) bond length is 1.37 Å. In the twenty-first C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(32) atom. The C(28)-C(29) bond length is 1.41 Å. The C(28)-C(32) bond length is 1.40 Å. In the twenty-second C site, C(29) is bonded in a distorted single-bond geometry to one C(28), one C(30), and one H(24) atom. The C(29)-C(30) bond length is 1.38 Å. The C(29)-H(24) bond length is 1.09 Å. In the twenty-third C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one N(10), and one H(25) atom. The C(30)-N(10) bond length is 1.35 Å. The C(30)-H(25) bond length is 1.09 Å. In the twenty-fourth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(32), one N(10), and one H(26) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-N(10) bond length is 1.35 Å. The C(31)-H(26) bond length is 1.09 Å. In the twenty-fifth C site, C(32) is bonded in a distorted single-bond geometry to one C(28), one C(31), and one H(27) atom. The C(32)-H(27) bond length is 1.09 Å. In the twenty-sixth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.31 Å. The C(1)-O(2) bond length is 1.25 Å. There are ten inequivalent N sites. In the first N site, N(8) is bonded in a distorted water-like geometry to one C(26) and one N(9) atom. The N(8)-N(9) bond length is 1.35 Å. In the second N site, N(9) is bonded in a 3-coordinate geometry to one Zn(1), one C(27), and one N(8) atom. In the third N site, N(10) is bonded in a trigonal planar geometry to one Zn(1), one C(30), and one C(31) atom. In the fourth N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(9) atom. In the fifth N site, N(2) is bonded in a water-like geometry to one C(14) and one C(15) atom. In the sixth N site, N(3) is bonded in a 3-coordinate geometry to one C(15), one N(4), and one H(1) atom. The N(3)-N(4) bond length is 1.34 Å. The N(3)-H(1) bond length is 1.05 Å. In the seventh N site, N(4) is bonded in a distorted water-like geometry to one C(14) and one N(3) atom. In the eighth N site, N(5) is bonded in a bent 120 degrees geometry to one C(18) and one C(19) atom. In the ninth N site, N(6) is bonded in a trigonal planar geometry to one Zn(2), one C(21), and one C(25) atom. In the tenth N site, N(7) is bonded in a water-like geometry to one C(26) and one C(27) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one N(3) and one O(4) atom. The H(1)-O(4) bond length is 1.61 Å. In the second H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(24) atom. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one C(25) atom. In the fourteenth H site, H(24) is bonded in a single-bond geometry to one C(29) atom. In the fifteenth H site, H(25) is bonded in a single-bond geometry to one C(30) atom. In the sixteenth H site, H(26) is bonded in a single-bond geometry to one C(31) atom. In the seventeenth H site, H(27) is bonded in a single-bond geometry to one C(32) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(8) and one H(1) atom. Linkers: 1 [O]C(=O)[C@@H]1CCCC[C@@H]1C(=O)O[Zn@](N1[CH]C=C(C=C1)C1=[N]=C(N=N1)c1ccncc1)(N1[CH]C=C(C=C1)C1=N[N]C(=N1)c1ccncc1)OC(=O)[C@H]1CCCC[C@H]1C(=O)[O] ,1 [O]C(=O)[C@H]1CCCC[C@H]1C(=O)O[Zn@](N1[CH]C=C(C=C1)C1=[N]=C(N=N1)c1ccncc1)(N1[CH]C=C(C=C1)C1=N[N]C(=N1)c1ccncc1)OC(=O)[C@@H]1CCCC[C@@H]1C(=O)[O]. Metal clusters: 4 [Zn]. The MOF has largest included sphere 4.07 A, density 1.38 g/cm3, surface area 4835.60 m2/g, accessible volume 0.24 cm3/g