ZnC18N4H28S2(O5F2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two ZnC18N4H28S2(O5F2)2 clusters. Zn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms. Both Zn(1)-O(1) bond lengths are 2.14 Å. Both Zn(1)-O(4) bond lengths are 2.10 Å. Both Zn(1)-O(5) bond lengths are 2.11 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one S(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(3) bond length is 1.40 Å. The C(1)-S(1) bond length is 1.82 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one F(1) atom. The C(2)-F(1) bond length is 1.35 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1) and one F(2) atom. The C(3)-F(2) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(1), one H(1), and one O(4) atom. The C(4)-N(1) bond length is 1.33 Å. The C(4)-H(1) bond length is 1.10 Å. The C(4)-O(4) bond length is 1.26 Å. In the fifth C site, C(5) is bonded to one N(1); one H(2); one H(3); and one H(4,5) atom to form corner-sharing CH3N tetrahedra. The C(5)-N(1) bond length is 1.45 Å. The C(5)-H(2) bond length is 1.10 Å. The C(5)-H(3) bond length is 1.10 Å. The C(5)-H(4,5) bond length is 1.10 Å. In the sixth C site, C(6) is bonded to one N(1); one H(4,5); one H(6); and one H(7) atom to form corner-sharing CH3N tetrahedra. The C(6)-N(1) bond length is 1.45 Å. The C(6)-H(4,5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. The C(6)-H(7) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one N(2), one H(8), and one O(5) atom. The C(7)-N(2) bond length is 1.33 Å. The C(7)-H(8) bond length is 1.10 Å. The C(7)-O(5) bond length is 1.26 Å. In the eighth C site, C(8) is bonded to one N(2), one H(10), one H(11), and one H(9) atom to form corner-sharing CH3N tetrahedra. The C(8)-N(2) bond length is 1.46 Å. The C(8)-H(10) bond length is 1.09 Å. The C(8)-H(11) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. In the ninth C site, C(9) is bonded to one N(2), one H(12), one H(13), and one H(14) atom to form corner-sharing CH3N tetrahedra. The C(9)-N(2) bond length is 1.46 Å. The C(9)-H(12) bond length is 1.10 Å. The C(9)-H(13) bond length is 1.09 Å. The C(9)-H(14) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(7), one C(8), and one C(9) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4,5) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(9) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(2) bond length is 1.46 Å. The S(1)-O(3) bond length is 1.45 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one C(3) atom. In the second F site, F(1) is bonded in a single-bond geometry to one C(2) atom. Linkers: 2 [O]S([O])([O])c1c(F)c(F)c(S([O])([O])[O])c(F)c1F. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.04 A, density 1.65 g/cm3, surface area 4648.03 m2/g, accessible volume 0.14 cm3/g