Au2CdH6(C2N)6(CH)2 crystallizes in the trigonal P3_112 space group. The structure consists of six 02329_fluka molecules inside a Au2CdH6(C2N)6 framework. In the Au2CdH6(C2N)6 framework, Au(1) is bonded in a linear geometry to one C(1) and one C(2) atom. The Au(1)-C(1) bond length is 1.97 Å. The Au(1)-C(2) bond length is 1.97 Å. Cd(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. Both Cd(1)-N(1) bond lengths are 2.36 Å. Both Cd(1)-N(2) bond lengths are 2.29 Å. Both Cd(1)-N(3) bond lengths are 2.35 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one Au(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. In the second C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one N(3) atom. The C(7)-C(6) bond length is 1.40 Å. The C(7)-C(7) bond length is 1.49 Å. The C(7)-N(3) bond length is 1.35 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one Au(1) and one N(2) atom. The C(2)-N(2) bond length is 1.17 Å. In the fourth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(3), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-N(3) bond length is 1.34 Å. The C(3)-H(1) bond length is 1.09 Å. In the fifth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(4)-H(2) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted linear geometry to one Cd(1) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Cd(1) and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(3), and one C(7) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. Linkers: 12 [C]#N. Metal clusters: 3 [Cd] ,6 [Au]. The MOF has largest included sphere 2.77 A, density 2.78 g/cm3, surface area 2647.84 m2/g, accessible volume 0.10 cm3/g