CdC15H9(NO3)2(C2NH2S)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two C2NH2S clusters and one CdC15H9(NO3)2 cluster. In each C2NH2S cluster, there are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(3), and one S(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(3) bond length is 1.35 Å. The C(1)-S(1) bond length is 1.74 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-S(2) bond length is 1.75 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one N(2), one N(3), and one S(3) atom. The C(3)-N(2) bond length is 1.35 Å. The C(3)-N(3) bond length is 1.34 Å. The C(3)-S(3) bond length is 1.75 Å. In the fourth C site, C(4) is bonded in a distorted water-like geometry to one H(1), one H(2), and one S(1) atom. The C(4)-H(1) bond length is 1.10 Å. The C(4)-H(2) bond length is 1.10 Å. The C(4)-S(1) bond length is 1.80 Å. In the fifth C site, C(6) is bonded in a distorted water-like geometry to one H(3), one H(4), and one S(2) atom. The C(6)-H(3) bond length is 1.10 Å. The C(6)-H(4) bond length is 1.10 Å. The C(6)-S(2) bond length is 1.80 Å. In the sixth C site, C(8) is bonded in a distorted water-like geometry to one H(5), one H(6), and one S(3) atom. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-S(3) bond length is 1.81 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(3) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(1) and one C(4) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(2) and one C(6) atom. In the third S site, S(3) is bonded in a water-like geometry to one C(3) and one C(8) atom. In the CdC15H9(NO3)2 cluster, Cd(1) is bonded in a 7-coordinate geometry to one N(4), one N(5), one O(2), one O(4), one O(5), and two equivalent O(1) atoms. The Cd(1)-N(4) bond length is 2.34 Å. The Cd(1)-N(5) bond length is 2.33 Å. The Cd(1)-O(2) bond length is 2.77 Å. The Cd(1)-O(4) bond length is 2.60 Å. The Cd(1)-O(5) bond length is 2.31 Å. There is one shorter (2.28 Å) and one longer (2.50 Å) Cd(1)-O(1) bond length. There are fifteen inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(5)-O(1) bond length is 1.29 Å. The C(5)-O(2) bond length is 1.25 Å. In the second C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(7)-O(3) bond length is 1.31 Å. The C(7)-O(4) bond length is 1.24 Å. In the third C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(9)-O(5) bond length is 1.26 Å. The C(9)-O(6) bond length is 1.28 Å. In the fourth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(4), and one H(7) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-N(4) bond length is 1.33 Å. The C(10)-H(7) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(8) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-H(8) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(9) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-H(9) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(21) atom. The C(13)-C(14) bond length is 1.43 Å. The C(13)-C(21) bond length is 1.42 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(14)-H(10) bond length is 1.09 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(15)-C(16) bond length is 1.43 Å. The C(15)-H(11) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(20) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(20) bond length is 1.42 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(17)-H(12) bond length is 1.09 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(13) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-H(13) bond length is 1.09 Å. In the thirteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(5), and one H(14) atom. The C(19)-N(5) bond length is 1.33 Å. The C(19)-H(14) bond length is 1.09 Å. In the fourteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(16), one C(21), and one N(5) atom. The C(20)-C(21) bond length is 1.45 Å. The C(20)-N(5) bond length is 1.36 Å. In the fifteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(13), one C(20), and one N(4) atom. The C(21)-N(4) bond length is 1.35 Å. There are two inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(21) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Cd(1), one C(19), and one C(20) atom. There are nine inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(15) is bonded in a linear geometry to one O(3) and one O(6) atom. The H(15)-O(3) bond length is 1.10 Å. The H(15)-O(6) bond length is 1.37 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cd(1) and one C(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cd(1) and one C(5) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(7) and one H(15) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(7) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(9) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one C(9) and one H(15) atom. Linkers: 2 c1cnc2c(c1)ccc1cccnc12 ,2 [O]C(=O)CSC1=NC(=[N]=C([N]1)SCC(=O)[O])SCC(=O)O. Metal clusters: 1 O=[C]O.O=[C]O.O=[C]O[Cd]O[C]=O.O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 2.99 A, density 1.86 g/cm3, surface area 3896.04 m2/g, accessible volume 0.11 cm3/g