CoC14H12(N2O)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CoC14H12(N2O)2 clusters. Co(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Co(1)-N(1) bond length is 2.01 Å. The Co(1)-N(2) bond length is 2.01 Å. The Co(1)-N(3) bond length is 1.89 Å. The Co(1)-N(4) bond length is 1.89 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(1) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one H(2) atom. The C(2)-C(4) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1); one C(5); and one H(3,4) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-H(3,4) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2); one C(6); and one H(3,4) atom. The C(4)-C(6) bond length is 1.40 Å. The C(4)-H(3,4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(7) atom. The C(5)-C(11) bond length is 1.50 Å. The C(5)-C(7) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(12), one C(4), and one C(8) atom. The C(6)-C(12) bond length is 1.50 Å. The C(6)-C(8) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(5); one C(9); and one H(5,6) atom. The C(7)-C(9) bond length is 1.39 Å. The C(7)-H(5,6) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(10); one C(6); and one H(5,6) atom. The C(8)-C(10) bond length is 1.39 Å. The C(8)-H(5,6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one H(7) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted water-like geometry to one C(5); one H(11); and one H(9,10) atom. The C(11)-H(11) bond length is 1.10 Å. The C(11)-H(9,10) bond length is 1.10 Å. In the twelfth C site, C(12) is bonded in a distorted water-like geometry to one C(6); one H(12); and one H(9,10) atom. The C(12)-H(12) bond length is 1.10 Å. The C(12)-H(9,10) bond length is 1.10 Å. In the thirteenth C site, C(13) is bonded in a linear geometry to one N(3) and one O(1) atom. The C(13)-N(3) bond length is 1.20 Å. The C(13)-O(1) bond length is 1.21 Å. In the fourteenth C site, C(14) is bonded in a linear geometry to one N(4) and one O(2) atom. The C(14)-N(4) bond length is 1.20 Å. The C(14)-O(2) bond length is 1.21 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(10), and one C(2) atom. In the third N site, N(3) is bonded in a linear geometry to one Co(1) and one C(13) atom. In the fourth N site, N(4) is bonded in a linear geometry to one Co(1) and one C(14) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(13) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(14) atom. Linkers: 4 [c]1cc(CCc2ccncc2)ccn1 ,2 c1cc(CCc2ccncc2)ccn1. Metal clusters: 2 [Co]. The MOF has largest included sphere 2.23 A, density 1.55 g/cm3, surface area 4827.50 m2/g, accessible volume 0.12 cm3/g