AgH8(C4N)2Ag2C19H20(NO)4Ag2C15H16(NO)4AgC13H12(NO)2(CH)16(CH2)5CO2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules, two formic acid molecules, eight isobutylene molecules, two Ag2C15H16(NO)4 clusters, two Ag2C19H20(NO)4 clusters, two AgC13H12(NO)2 clusters, and two AgH8(C4N)2 clusters. In each Ag2C15H16(NO)4 cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(3) is bonded in a 4-coordinate geometry to one N(2), one N(8), one O(12), and one O(5) atom. The Ag(3)-N(2) bond length is 2.37 Å. The Ag(3)-N(8) bond length is 2.19 Å. The Ag(3)-O(12) bond length is 2.57 Å. The Ag(3)-O(5) bond length is 2.48 Å. In the second Ag site, Ag(4) is bonded in a 4-coordinate geometry to one N(12), one N(5), one O(11), and one O(12) atom. The Ag(4)-N(12) bond length is 2.17 Å. The Ag(4)-N(5) bond length is 2.16 Å. The Ag(4)-O(11) bond length is 2.76 Å. The Ag(4)-O(12) bond length is 2.65 Å. There are fifteen inequivalent C sites. In the first C site, C(42) is bonded in a distorted single-bond geometry to one C(55), one C(71), and one H(48) atom. The C(42)-C(55) bond length is 1.40 Å. The C(42)-C(71) bond length is 1.39 Å. The C(42)-H(48) bond length is 1.09 Å. In the second C site, C(49) is bonded in a distorted water-like geometry to one C(55), one H(54), and one H(55) atom. The C(49)-C(55) bond length is 1.50 Å. The C(49)-H(54) bond length is 1.10 Å. The C(49)-H(55) bond length is 1.10 Å. In the third C site, C(55) is bonded in a trigonal planar geometry to one C(19), one C(42), and one C(49) atom. The C(55)-C(19) bond length is 1.40 Å. In the fourth C site, C(58) is bonded in a distorted trigonal planar geometry to one N(12) and one H(12,63) atom. The C(58)-N(12) bond length is 1.35 Å. The C(58)-H(12,63) bond length is 1.09 Å. In the fifth C site, C(66) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(72), and one H(73) atom. The C(66)-N(2) bond length is 1.46 Å. The C(66)-H(72) bond length is 1.10 Å. The C(66)-H(73) bond length is 1.11 Å. In the sixth C site, C(69) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(5) atom. The C(69)-O(2) bond length is 1.26 Å. The C(69)-O(5) bond length is 1.28 Å. In the seventh C site, C(71) is bonded in a distorted trigonal planar geometry to one C(42), one N(5), and one H(76) atom. The C(71)-N(5) bond length is 1.35 Å. The C(71)-H(76) bond length is 1.09 Å. In the eighth C site, C(72) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. The C(72)-O(11) bond length is 1.27 Å. The C(72)-O(12) bond length is 1.27 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one N(12) and one H(12,63) atom. The C(10)-N(12) bond length is 1.35 Å. The C(10)-H(12,63) bond length is 1.09 Å. In the tenth C site, C(74) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(79) atom. The C(74)-N(5) bond length is 1.35 Å. The C(74)-H(79) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(13), and one H(14) atom. The C(11)-N(2) bond length is 1.47 Å. The C(11)-H(13) bond length is 1.10 Å. The C(11)-H(14) bond length is 1.11 Å. In the twelfth C site, C(19) is bonded in a distorted single-bond geometry to one C(55) and one H(22) atom. The C(19)-H(22) bond length is 1.10 Å. In the thirteenth C site, C(29) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(35), and one H(36) atom. The C(29)-N(2) bond length is 1.46 Å. The C(29)-H(35) bond length is 1.10 Å. The C(29)-H(36) bond length is 1.11 Å. In the fourteenth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(42) atom. The C(35)-N(8) bond length is 1.35 Å. The C(35)-H(42) bond length is 1.09 Å. In the fifteenth C site, C(39) is bonded in a distorted trigonal planar geometry to one N(8) and one H(28,44) atom. The C(39)-N(8) bond length is 1.35 Å. The C(39)-H(28,44) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(2) is bonded in a distorted tetrahedral geometry to one Ag(3), one C(11), one C(29), and one C(66) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Ag(4), one C(71), and one C(74) atom. In the third N site, N(8) is bonded in a trigonal planar geometry to one Ag(3), one C(35), and one C(39) atom. In the fourth N site, N(12) is bonded in a trigonal planar geometry to one Ag(4), one C(10), and one C(58) atom. There are fifteen inequivalent H sites. In the first H site, H(72) is bonded in a single-bond geometry to one C(66) atom. In the second H site, H(73) is bonded in a single-bond geometry to one C(66) atom. In the third H site, H(12,63) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(76) is bonded in a single-bond geometry to one C(71) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(79) is bonded in a single-bond geometry to one C(74) atom. In the eighth H site, H(22) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(28,44) is bonded in a single-bond geometry to one C(24) atom. The H(28,44)-C(24) bond length is 1.09 Å. In the tenth H site, H(35) is bonded in a single-bond geometry to one C(29) atom. In the eleventh H site, H(36) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(55) is bonded in a single-bond geometry to one C(49) atom. In the thirteenth H site, H(42) is bonded in a single-bond geometry to one C(35) atom. In the fourteenth H site, H(48) is bonded in a single-bond geometry to one C(42) atom. In the fifteenth H site, H(54) is bonded in a single-bond geometry to one C(49) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one C(69) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to one Ag(3) and one C(69) atom. In the third O site, O(11) is bonded in a single-bond geometry to one Ag(4) and one C(72) atom. In the fourth O site, O(12) is bonded in a distorted single-bond geometry to one Ag(3), one Ag(4), and one C(72) atom. In each Ag2C19H20(NO)4 cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(6), one O(1), and one O(10) atom. The Ag(1)-N(1) bond length is 2.36 Å. The Ag(1)-N(6) bond length is 2.19 Å. The Ag(1)-O(1) bond length is 2.53 Å. The Ag(1)-O(10) bond length is 2.50 Å. In the second Ag site, Ag(5) is bonded in a 3-coordinate geometry to one N(11), one N(3), and one O(9) atom. The Ag(5)-N(11) bond length is 2.15 Å. The Ag(5)-N(3) bond length is 2.15 Å. The Ag(5)-O(9) bond length is 2.67 Å. There are nineteen inequivalent C sites. In the first C site, C(41) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(46), and one H(47) atom. The C(41)-N(1) bond length is 1.47 Å. The C(41)-H(46) bond length is 1.10 Å. The C(41)-H(47) bond length is 1.11 Å. In the second C site, C(46) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(4) atom. The C(46)-O(10) bond length is 1.28 Å. The C(46)-O(4) bond length is 1.26 Å. In the third C site, C(47) is bonded in a distorted trigonal planar geometry to one N(3) and one H(51,61) atom. The C(47)-N(3) bond length is 1.35 Å. The C(47)-H(51,61) bond length is 1.09 Å. In the fourth C site, C(51) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(9) atom. The C(51)-O(1) bond length is 1.28 Å. The C(51)-O(9) bond length is 1.27 Å. In the fifth C site, C(52) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(57) atom. The C(52)-N(11) bond length is 1.35 Å. The C(52)-H(57) bond length is 1.09 Å. In the sixth C site, C(54) is bonded in a distorted trigonal planar geometry to one C(8), one N(6), and one H(60) atom. The C(54)-C(8) bond length is 1.39 Å. The C(54)-N(6) bond length is 1.35 Å. The C(54)-H(60) bond length is 1.09 Å. In the seventh C site, C(64) is bonded in a distorted single-bond geometry to one C(68), one C(70), and one H(70) atom. The C(64)-C(68) bond length is 1.39 Å. The C(64)-C(70) bond length is 1.40 Å. The C(64)-H(70) bond length is 1.09 Å. In the eighth C site, C(3) is bonded in a trigonal planar geometry to one C(18), one C(21), and one C(8) atom. The C(3)-C(18) bond length is 1.51 Å. The C(3)-C(21) bond length is 1.40 Å. The C(3)-C(8) bond length is 1.40 Å. In the ninth C site, C(68) is bonded in a distorted bent 120 degrees geometry to one C(64), one N(11), and one H(75) atom. The C(68)-N(11) bond length is 1.35 Å. The C(68)-H(75) bond length is 1.09 Å. In the tenth C site, C(70) is bonded in a trigonal planar geometry to one C(28), one C(6), and one C(64) atom. The C(70)-C(28) bond length is 1.40 Å. The C(70)-C(6) bond length is 1.50 Å. In the eleventh C site, C(6) is bonded in a distorted water-like geometry to one C(70), one H(6), and one H(7) atom. The C(6)-H(6) bond length is 1.10 Å. The C(6)-H(7) bond length is 1.10 Å. In the twelfth C site, C(8) is bonded in a distorted single-bond geometry to one C(3), one C(54), and one H(9) atom. The C(8)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(16) atom. The C(14)-N(3) bond length is 1.35 Å. The C(14)-H(16) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(17), and one H(18) atom. The C(16)-N(1) bond length is 1.46 Å. The C(16)-H(17) bond length is 1.10 Å. The C(16)-H(18) bond length is 1.11 Å. In the fifteenth C site, C(18) is bonded in a distorted water-like geometry to one C(3), one H(20), and one H(21) atom. The C(18)-H(20) bond length is 1.10 Å. The C(18)-H(21) bond length is 1.10 Å. In the sixteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(3) and one H(24) atom. The C(21)-H(24) bond length is 1.09 Å. In the seventeenth C site, C(22) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(25), and one H(26) atom. The C(22)-N(1) bond length is 1.48 Å. The C(22)-H(25) bond length is 1.10 Å. The C(22)-H(26) bond length is 1.11 Å. In the eighteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(27) atom. The C(23)-N(6) bond length is 1.35 Å. The C(23)-H(27) bond length is 1.09 Å. In the nineteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(70) and one H(34) atom. The C(28)-H(34) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted tetrahedral geometry to one Ag(1), one C(16), one C(22), and one C(41) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Ag(5), one C(14), and one C(47) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Ag(1), one C(23), and one C(54) atom. In the fourth N site, N(11) is bonded in a trigonal planar geometry to one Ag(5), one C(52), and one C(68) atom. There are twenty inequivalent H sites. In the first H site, H(60) is bonded in a single-bond geometry to one C(54) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(70) is bonded in a single-bond geometry to one C(64) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(75) is bonded in a single-bond geometry to one C(68) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(25) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(26) is bonded in a single-bond geometry to one C(22) atom. In the fifteenth H site, H(27) is bonded in a single-bond geometry to one C(23) atom. In the sixteenth H site, H(34) is bonded in a single-bond geometry to one C(28) atom. In the seventeenth H site, H(46) is bonded in a single-bond geometry to one C(41) atom. In the eighteenth H site, H(47) is bonded in a single-bond geometry to one C(41) atom. In the nineteenth H site, H(51,61) is bonded in a single-bond geometry to one C(47) atom. In the twentieth H site, H(57) is bonded in a single-bond geometry to one C(52) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ag(1) and one C(51) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(46) atom. In the third O site, O(9) is bonded in a single-bond geometry to one Ag(5) and one C(51) atom. In the fourth O site, O(10) is bonded in a distorted single-bond geometry to one Ag(1) and one C(46) atom. In each AgC13H12(NO)2 cluster, Ag(6) is bonded in a 4-coordinate geometry to one N(7), one N(9), one O(3), and one O(7) atom. The Ag(6)-N(7) bond length is 2.18 Å. The Ag(6)-N(9) bond length is 2.17 Å. The Ag(6)-O(3) bond length is 2.62 Å. The Ag(6)-O(7) bond length is 2.63 Å. There are thirteen inequivalent C sites. In the first C site, C(56) is bonded in a distorted trigonal planar geometry to one N(9) and one H(51,61) atom. The C(56)-N(9) bond length is 1.35 Å. The C(56)-H(51,61) bond length is 1.09 Å. In the second C site, C(61) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(7) atom. The C(61)-O(3) bond length is 1.28 Å. The C(61)-O(7) bond length is 1.27 Å. In the third C site, C(65) is bonded in a distorted trigonal planar geometry to one C(67), one N(7), and one H(71) atom. The C(65)-C(67) bond length is 1.39 Å. The C(65)-N(7) bond length is 1.35 Å. The C(65)-H(71) bond length is 1.09 Å. In the fourth C site, C(1) is bonded in a distorted water-like geometry to one C(12), one H(1), and one H(2) atom. The C(1)-C(12) bond length is 1.50 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the fifth C site, C(67) is bonded in a distorted trigonal planar geometry to one C(30), one C(65), and one H(74) atom. The C(67)-C(30) bond length is 1.40 Å. The C(67)-H(74) bond length is 1.09 Å. In the sixth C site, C(75) is bonded in a distorted bent 120 degrees geometry to one C(25), one N(9), and one H(80) atom. The C(75)-C(25) bond length is 1.39 Å. The C(75)-N(9) bond length is 1.35 Å. The C(75)-H(80) bond length is 1.09 Å. In the seventh C site, C(12) is bonded in a trigonal planar geometry to one C(1), one C(25), and one C(32) atom. The C(12)-C(25) bond length is 1.40 Å. The C(12)-C(32) bond length is 1.40 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(30) and one H(15) atom. The C(13)-C(30) bond length is 1.40 Å. The C(13)-H(15) bond length is 1.09 Å. In the ninth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(28,44) atom. The C(24)-N(7) bond length is 1.35 Å. In the tenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(12), one C(75), and one H(29) atom. The C(25)-H(29) bond length is 1.09 Å. In the eleventh C site, C(26) is bonded in a distorted water-like geometry to one C(30), one H(30), and one H(31) atom. The C(26)-C(30) bond length is 1.50 Å. The C(26)-H(30) bond length is 1.10 Å. The C(26)-H(31) bond length is 1.10 Å. In the twelfth C site, C(30) is bonded in a trigonal planar geometry to one C(13), one C(26), and one C(67) atom. In the thirteenth C site, C(32) is bonded in a distorted single-bond geometry to one C(12) and one H(38) atom. The C(32)-H(38) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(7) is bonded in a trigonal planar geometry to one Ag(6), one C(24), and one C(65) atom. In the second N site, N(9) is bonded in a trigonal planar geometry to one Ag(6), one C(56), and one C(75) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(71) is bonded in a single-bond geometry to one C(65) atom. In the fourth H site, H(74) is bonded in a single-bond geometry to one C(67) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(80) is bonded in a single-bond geometry to one C(75) atom. In the seventh H site, H(28,44) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(29) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(30) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(31) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(38) is bonded in a single-bond geometry to one C(32) atom. In the twelfth H site, H(51,61) is bonded in a single-bond geometry to one C(47) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Ag(6) and one C(61) atom. In the second O site, O(7) is bonded in a single-bond geometry to one Ag(6) and one C(61) atom. In each AgH8(C4N)2 cluster, Ag(2) is bonded in a distorted linear geometry to one N(10) and one N(4) atom. The Ag(2)-N(10) bond length is 2.13 Å. The Ag(2)-N(4) bond length is 2.13 Å. There are eight inequivalent C sites. In the first C site, C(44) is bonded in a trigonal planar geometry to one C(31), one C(48), and one C(57) atom. The C(44)-C(31) bond length is 1.40 Å. The C(44)-C(48) bond length is 1.50 Å. The C(44)-C(57) bond length is 1.40 Å. In the second C site, C(45) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(50) atom. The C(45)-N(4) bond length is 1.35 Å. The C(45)-H(50) bond length is 1.09 Å. In the third C site, C(48) is bonded in a distorted water-like geometry to one C(44), one H(52), and one H(53) atom. The C(48)-H(52) bond length is 1.10 Å. The C(48)-H(53) bond length is 1.10 Å. In the fourth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(56) atom. The C(50)-N(10) bond length is 1.35 Å. The C(50)-H(56) bond length is 1.09 Å. In the fifth C site, C(57) is bonded in a distorted single-bond geometry to one C(44) and one H(62) atom. The C(57)-H(62) bond length is 1.09 Å. In the sixth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(31), one N(10), and one H(19) atom. The C(17)-C(31) bond length is 1.39 Å. The C(17)-N(10) bond length is 1.35 Å. The C(17)-H(19) bond length is 1.09 Å. In the seventh C site, C(31) is bonded in a distorted single-bond geometry to one C(17), one C(44), and one H(37) atom. The C(31)-H(37) bond length is 1.09 Å. In the eighth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(43) atom. The C(36)-N(4) bond length is 1.35 Å. The C(36)-H(43) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Ag(2), one C(36), and one C(45) atom. In the second N site, N(10) is bonded in a trigonal planar geometry to one Ag(2), one C(17), and one C(50) atom. There are eight inequivalent H sites. In the first H site, H(62) is bonded in a single-bond geometry to one C(57) atom. In the second H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the third H site, H(37) is bonded in a single-bond geometry to one C(31) atom. In the fourth H site, H(43) is bonded in a single-bond geometry to one C(36) atom. In the fifth H site, H(50) is bonded in a single-bond geometry to one C(45) atom. In the sixth H site, H(52) is bonded in a single-bond geometry to one C(48) atom. In the seventh H site, H(53) is bonded in a single-bond geometry to one C(48) atom. In the eighth H site, H(56) is bonded in a single-bond geometry to one C(50) atom. Linkers: 10 c1cc(CCCc2ccncc2)ccn1. Metal clusters: 12 [Ag]. The MOF has largest included sphere 5.96 A, density 1.47 g/cm3, surface area 4239.99 m2/g, accessible volume 0.29 cm3/g