ZnC10H7(NO2)2C4H3(CH)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two isobutylene molecules, and two ZnC10H7(NO2)2 clusters. In each ZnC10H7(NO2)2 cluster, Zn(1,2) is bonded in a 4-coordinate geometry to one N(2), one N(3), one O(1), and one O(8) atom. The Zn(1,2)-N(2) bond length is 2.07 Å. The Zn(1,2)-N(3) bond length is 2.02 Å. The Zn(1,2)-O(1) bond length is 2.04 Å. The Zn(1,2)-O(8) bond length is 1.96 Å. There are ten inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1) atom. The C(1,2)-N(1) bond length is 1.35 Å. The C(1,2)-H(1) bond length is 1.09 Å. In the second C site, C(9,10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(7) atom. The C(9,10)-N(1) bond length is 1.35 Å. The C(9,10)-H(7) bond length is 1.09 Å. In the third C site, C(15,16) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(15,16)-O(1) bond length is 1.30 Å. The C(15,16)-O(3) bond length is 1.26 Å. In the fourth C site, C(17,18) is bonded in a distorted trigonal planar geometry to one C(19), one N(3), and one H(13) atom. The C(17,18)-C(19) bond length is 1.39 Å. The C(17,18)-N(3) bond length is 1.35 Å. The C(17,18)-H(13) bond length is 1.09 Å. In the fifth C site, C(19) is bonded in a distorted single-bond geometry to one C(17,18); one C(21,22); and one H(15,16) atom. The C(19)-C(21,22) bond length is 1.40 Å. The C(19)-H(15,16) bond length is 1.09 Å. In the sixth C site, C(21,22) is bonded in a trigonal planar geometry to one C(19), one C(23), and one C(27) atom. The C(21,22)-C(23) bond length is 1.41 Å. The C(21,22)-C(27) bond length is 1.46 Å. In the seventh C site, C(23) is bonded in a distorted trigonal planar geometry to one C(21,22); one C(25,26); and one H(17,18) atom. The C(23)-C(25,26) bond length is 1.39 Å. The C(23)-H(17,18) bond length is 1.09 Å. In the eighth C site, C(25,26) is bonded in a distorted bent 120 degrees geometry to one C(23); one N(3); and one H(19,20) atom. The C(25,26)-N(3) bond length is 1.35 Å. The C(25,26)-H(19,20) bond length is 1.09 Å. In the ninth C site, C(27) is bonded in a distorted single-bond geometry to one C(21,22) and one H(21,22) atom. The C(27)-H(21,22) bond length is 1.09 Å. In the tenth C site, C(31,32) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(7) atom. The C(31,32)-O(5) bond length is 1.25 Å. The C(31,32)-O(7) bond length is 1.31 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Zn(1,2); one C(1,2); and one C(9,10) atom. The N(2)-C(1,2) bond length is 1.35 Å. The N(2)-C(9,10) bond length is 1.35 Å. In the second N site, N(3) is bonded in a trigonal planar geometry to one Zn(1,2); one C(17,18); and one C(25,26) atom. There are seven inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(1,2) atom. The H(2)-C(1,2) bond length is 1.09 Å. In the second H site, H(8) is bonded in a single-bond geometry to one C(9,10) atom. The H(8)-C(9,10) bond length is 1.09 Å. In the third H site, H(13) is bonded in a single-bond geometry to one C(17,18) atom. In the fourth H site, H(15,16) is bonded in a single-bond geometry to one C(19) atom. In the fifth H site, H(17,18) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(19,20) is bonded in a single-bond geometry to one C(25,26) atom. In the seventh H site, H(21,22) is bonded in a single-bond geometry to one C(27) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1,2) and one C(15,16) atom. In the second O site, O(3) is bonded in a single-bond geometry to one C(15,16) atom. In the third O site, O(6) is bonded in a single-bond geometry to one C(31,32) atom. The O(6)-C(31,32) bond length is 1.25 Å. In the fourth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1,2) and one C(31,32) atom. The O(8)-C(31,32) bond length is 1.31 Å. Linkers: 4 [O]C(=O)/C=C/c1ccncc1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.14 A, density 1.43 g/cm3, surface area 4879.85 m2/g, accessible volume 0.22 cm3/g