ZnC23H16Br(NO2)2C3H2Br is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 2-bromopropene molecules and two ZnC23H16Br(NO2)2 clusters. In each ZnC23H16Br(NO2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-N(2) bond length is 2.06 Å. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(3) bond length is 1.98 Å. There are twenty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.45 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one H(6) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-N(2) bond length is 1.35 Å. The C(7)-H(6) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(7) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-H(7) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(8) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(12) bond length is 1.45 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(10)-H(8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one N(2) and one H(9) atom. The C(11)-N(2) bond length is 1.35 Å. The C(11)-H(9) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(9) and one H(10) atom. The C(12)-H(10) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(1), and one O(2) atom. The C(13)-C(14) bond length is 1.50 Å. The C(13)-O(1) bond length is 1.31 Å. The C(13)-O(2) bond length is 1.25 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(19) bond length is 1.40 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(15)-H(11) bond length is 1.09 Å. In the sixteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(14) atom. The C(19)-H(14) bond length is 1.09 Å. In the seventeenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(3), and one O(4) atom. The C(20)-C(21) bond length is 1.50 Å. The C(20)-O(3) bond length is 1.31 Å. The C(20)-O(4) bond length is 1.25 Å. In the eighteenth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(26) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(26) bond length is 1.40 Å. In the nineteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(15) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-H(15) bond length is 1.09 Å. In the twentieth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one H(16) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-H(16) bond length is 1.09 Å. In the twenty-first C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one Br(2) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-Br(2) bond length is 1.91 Å. In the twenty-second C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(17) atom. The C(25)-H(17) bond length is 1.09 Å. In the twenty-third C site, C(26) is bonded in a distorted single-bond geometry to one C(21) and one H(18) atom. The C(26)-H(18) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(7) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(13) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(20) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(20) atom. Br(2) is bonded in a single-bond geometry to one C(24) atom. Linkers: 2 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 3.09 A, density 1.69 g/cm3, surface area 4269.26 m2/g, accessible volume 0.18 cm3/g