Ag2C17P2H17(NO2)3(CH)10 crystallizes in the monoclinic Cc space group. The structure consists of forty 02329_fluka molecules inside a Ag2C17P2H17(NO2)3 framework. In the Ag2C17P2H17(NO2)3 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one P(1), one O(1), and one O(2) atom. The Ag(1)-P(1) bond length is 2.33 Å. The Ag(1)-O(1) bond length is 2.51 Å. The Ag(1)-O(2) bond length is 2.23 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one P(2), one O(4), and one O(5) atom. The Ag(2)-P(2) bond length is 2.34 Å. The Ag(2)-O(4) bond length is 2.49 Å. The Ag(2)-O(5) bond length is 2.28 Å. There are seventeen inequivalent C sites. In the first C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(6)-C(1) bond length is 1.41 Å. The C(6)-H(5) bond length is 1.09 Å. In the second C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(8), and one P(1) atom. The C(7)-C(12) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.40 Å. The C(7)-P(1) bond length is 1.82 Å. In the third C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(8) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(9) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(9) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(7), and one H(10) atom. The C(12)-H(10) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a 4-coordinate geometry to one C(14), one C(15), one N(2), and one H(11) atom. The C(13)-C(14) bond length is 1.52 Å. The C(13)-C(15) bond length is 1.53 Å. The C(13)-N(2) bond length is 1.51 Å. The C(13)-H(11) bond length is 1.10 Å. In the eighth C site, C(14) is bonded in a trigonal non-coplanar geometry to one C(13), one H(12), one H(13), and one H(14) atom. The C(14)-H(12) bond length is 1.10 Å. The C(14)-H(13) bond length is 1.10 Å. The C(14)-H(14) bond length is 1.10 Å. In the ninth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one C(13), one H(15), one H(16), and one H(17) atom. The C(15)-H(15) bond length is 1.10 Å. The C(15)-H(16) bond length is 1.10 Å. The C(15)-H(17) bond length is 1.10 Å. In the tenth C site, C(16) is bonded in a trigonal planar geometry to one C(17), one C(21), and one P(2) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.40 Å. The C(16)-P(2) bond length is 1.82 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(18) atom. The C(17)-H(18) bond length is 1.09 Å. In the twelfth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(22) atom. The C(21)-H(22) bond length is 1.09 Å. In the thirteenth C site, C(22) is bonded in a trigonal planar geometry to one C(23), one C(27), and one P(2) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(27) bond length is 1.41 Å. The C(22)-P(2) bond length is 1.83 Å. In the fourteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(23) atom. The C(23)-H(23) bond length is 1.09 Å. In the fifteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(22) and one H(27) atom. The C(27)-H(27) bond length is 1.09 Å. In the sixteenth C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one P(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-P(1) bond length is 1.82 Å. In the seventeenth C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one Ag(1), one C(1), one C(7), and one N(2) atom to form distorted corner-sharing PAgC2N tetrahedra. The P(1)-N(2) bond length is 1.71 Å. In the second P site, P(2) is bonded to one Ag(2), one C(16), one C(22), and one N(2) atom to form distorted corner-sharing PAgC2N tetrahedra. The P(2)-N(2) bond length is 1.72 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(4) atom. The N(1)-O(2) bond length is 1.29 Å. The N(1)-O(3) bond length is 1.26 Å. The N(1)-O(4) bond length is 1.26 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(13), one P(1), and one P(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(6) atom. The N(3)-O(1) bond length is 1.28 Å. The N(3)-O(5) bond length is 1.29 Å. The N(3)-O(6) bond length is 1.25 Å. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(21) atom. In the sixteenth H site, H(23) is bonded in a single-bond geometry to one C(23) atom. In the seventeenth H site, H(27) is bonded in a single-bond geometry to one C(27) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one N(3) atom. In the second O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one N(3) atom. In the third O site, O(2) is bonded in a water-like geometry to one Ag(1) and one N(1) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the sixth O site, O(4) is bonded in a distorted water-like geometry to one Ag(2) and one N(1) atom. Linkers: 2 CC(C)N(P(c1ccccc1)c1ccccc1)P(c1ccccc1)c1ccccc1 ,4 [O][N+](=O)[O-]. Metal clusters: 4 [Ag]. RCSR code: ths. The MOF has largest included sphere 2.52 A, density 1.81 g/cm3, surface area 4086.49 m2/g, accessible volume 0.07 cm3/g