Cd3C52H36(NO2)8(CH)6(CH2)2 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, four 02329_fluka molecules, and two Cd3C52H36(NO2)8 clusters. In each Cd3C52H36(NO2)8 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 7-coordinate geometry to one N(2), one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom. The Cd(1)-N(2) bond length is 2.31 Å. The Cd(1)-O(1) bond length is 2.43 Å. The Cd(1)-O(2) bond length is 2.35 Å. The Cd(1)-O(5) bond length is 2.49 Å. The Cd(1)-O(6) bond length is 2.54 Å. The Cd(1)-O(7) bond length is 2.35 Å. The Cd(1)-O(8) bond length is 2.56 Å. In the second Cd site, Cd(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent N(3) and two equivalent O(8) atoms. Both Cd(2)-N(3) bond lengths are 2.19 Å. Both Cd(2)-O(8) bond lengths are 2.32 Å. There are twenty-six inequivalent C sites. In the first C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(7), and one H(9) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(7) bond length is 1.39 Å. The C(10)-H(9) bond length is 1.09 Å. In the second C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one O(3) atom. The C(11)-O(3) bond length is 1.39 Å. In the third C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one C(14), and one H(10) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(14) bond length is 1.40 Å. The C(12)-H(10) bond length is 1.09 Å. In the fourth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one O(3) atom. The C(13)-O(3) bond length is 1.37 Å. In the fifth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one O(4) atom. The C(14)-O(4) bond length is 1.38 Å. In the sixth C site, C(15) is bonded in a distorted single-bond geometry to one C(17) and one H(11) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-H(11) bond length is 1.09 Å. In the seventh C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(12) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(12) bond length is 1.09 Å. In the eighth C site, C(17) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(18) atom. The C(17)-C(18) bond length is 1.50 Å. In the ninth C site, C(18) is bonded in a bent 120 degrees geometry to one C(17), one O(5), and one O(6) atom. The C(18)-O(5) bond length is 1.28 Å. The C(18)-O(6) bond length is 1.27 Å. In the tenth C site, C(19) is bonded in a distorted single-bond geometry to one O(4) atom. The C(19)-O(4) bond length is 1.39 Å. In the eleventh C site, C(22) is bonded in a distorted single-bond geometry to one C(24) and one H(15) atom. The C(22)-C(24) bond length is 1.40 Å. The C(22)-H(15) bond length is 1.09 Å. In the twelfth C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(16) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-H(16) bond length is 1.09 Å. In the thirteenth C site, C(24) is bonded in a trigonal planar geometry to one C(22), one C(23), and one C(25) atom. The C(24)-C(25) bond length is 1.49 Å. In the fourteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(7), and one O(8) atom. The C(25)-O(7) bond length is 1.27 Å. The C(25)-O(8) bond length is 1.29 Å. In the fifteenth C site, C(26) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(17) atom. The C(26)-N(3) bond length is 1.34 Å. The C(26)-N(4) bond length is 1.35 Å. The C(26)-H(17) bond length is 1.08 Å. In the sixteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(28), one N(4), and one H(18) atom. The C(27)-C(28) bond length is 1.37 Å. The C(27)-N(4) bond length is 1.38 Å. The C(27)-H(18) bond length is 1.08 Å. In the seventeenth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(27), one N(3), and one H(19) atom. The C(28)-N(3) bond length is 1.38 Å. The C(28)-H(19) bond length is 1.09 Å. In the eighteenth C site, C(29) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(20), and one H(21) atom. The C(29)-N(4) bond length is 1.46 Å. The C(29)-H(20) bond length is 1.10 Å. The C(29)-H(21) bond length is 1.09 Å. In the nineteenth C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(1)-N(1) bond length is 1.46 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the twentieth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(3) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-N(1) bond length is 1.38 Å. The C(2)-H(3) bond length is 1.08 Å. In the twenty-first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(4) atom. The C(3)-N(2) bond length is 1.38 Å. The C(3)-H(4) bond length is 1.08 Å. In the twenty-second C site, C(4) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(5) atom. The C(4)-N(1) bond length is 1.36 Å. The C(4)-N(2) bond length is 1.33 Å. The C(4)-H(5) bond length is 1.09 Å. In the twenty-third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(2) atom. The C(5)-C(6) bond length is 1.50 Å. The C(5)-O(1) bond length is 1.27 Å. The C(5)-O(2) bond length is 1.29 Å. In the twenty-fourth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-C(8) bond length is 1.40 Å. In the twenty-fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(10), one C(6), and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. In the twenty-sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one H(7) atom. The C(8)-H(7) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(2), one C(26), and one C(28) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(26), one C(27), and one C(29) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(28) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(29) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. There are eight inequivalent O sites. In the first O site, O(7) is bonded in a distorted water-like geometry to one Cd(1) and one C(25) atom. In the second O site, O(8) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(2), and one C(25) atom. In the third O site, O(6) is bonded in a distorted single-bond geometry to one Cd(1) and one C(18) atom. In the fourth O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(5) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one C(18) atom. In the sixth O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(5) atom. In the seventh O site, O(3) is bonded in a bent 120 degrees geometry to one C(11) and one C(13) atom. In the eighth O site, O(4) is bonded in a bent 120 degrees geometry to one C(14) and one C(19) atom. Linkers: 4 c1cn(CCCn2ccnc2)cn1 ,4 [O]C(=O)c1ccc(Oc2cc(Oc3ccc(C([O])=O)cc3)cc(C([O])=O)c2)cc1. Metal clusters: 2 [C](O[Cd]O[C]O[Cd]12(O[C]O1)O[C]O2)O[Cd]12(O[C]O1)O[C]O2. The MOF has largest included sphere 4.72 A, density 1.56 g/cm3, surface area 4043.09 m2/g, accessible volume 0.24 cm3/g