La2C24H18(N2O5)3 crystallizes in the triclinic P-1 space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one N(2), one O(1), one O(11), one O(13), one O(4), one O(7), one O(8), and two equivalent O(3) atoms. The La(1)-N(2) bond length is 2.72 Å. The La(1)-O(1) bond length is 2.41 Å. The La(1)-O(11) bond length is 2.56 Å. The La(1)-O(13) bond length is 2.57 Å. The La(1)-O(4) bond length is 2.62 Å. The La(1)-O(7) bond length is 2.55 Å. The La(1)-O(8) bond length is 2.58 Å. There is one shorter (2.58 Å) and one longer (2.75 Å) La(1)-O(3) bond length. In the second La site, La(2) is bonded in a 9-coordinate geometry to one N(1), one O(10), one O(14), one O(15), one O(2), one O(5), one O(9), and two equivalent O(6) atoms. The La(2)-N(1) bond length is 2.67 Å. The La(2)-O(10) bond length is 2.44 Å. The La(2)-O(14) bond length is 2.58 Å. The La(2)-O(15) bond length is 2.67 Å. The La(2)-O(2) bond length is 2.50 Å. The La(2)-O(5) bond length is 2.46 Å. The La(2)-O(9) bond length is 2.55 Å. There is one shorter (2.74 Å) and one longer (2.76 Å) La(2)-O(6) bond length. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(6) atom. The C(1)-O(11) bond length is 1.26 Å. The C(1)-O(6) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(2)-O(2) bond length is 1.26 Å. The C(2)-O(3) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(4), and one O(8) atom. The C(3)-C(19) bond length is 1.51 Å. The C(3)-O(4) bond length is 1.27 Å. The C(3)-O(8) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(17), and one C(5) atom. The C(4)-C(12) bond length is 1.41 Å. The C(4)-C(17) bond length is 1.40 Å. The C(4)-C(5) bond length is 1.51 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(12), and one O(5) atom. The C(5)-O(12) bond length is 1.26 Å. The C(5)-O(5) bond length is 1.27 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(7) atom. The C(6)-C(14) bond length is 1.40 Å. The C(6)-C(16) bond length is 1.40 Å. The C(6)-H(7) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(7) atom. The C(7)-O(13) bond length is 1.27 Å. The C(7)-O(7) bond length is 1.26 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(1), one N(4), and one H(8) atom. The C(8)-N(1) bond length is 1.32 Å. The C(8)-N(4) bond length is 1.36 Å. The C(8)-H(8) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(23), one N(5), and one H(9) atom. The C(9)-C(23) bond length is 1.37 Å. The C(9)-N(5) bond length is 1.39 Å. The C(9)-H(9) bond length is 1.08 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(10) atom. The C(10)-N(2) bond length is 1.32 Å. The C(10)-N(3) bond length is 1.37 Å. The C(10)-H(10) bond length is 1.08 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(1), and one H(11) atom. The C(11)-C(22) bond length is 1.37 Å. The C(11)-N(1) bond length is 1.39 Å. The C(11)-H(11) bond length is 1.08 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(17), one C(4), and one N(3) atom. The C(12)-C(17) bond length is 1.39 Å. The C(12)-N(3) bond length is 1.42 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one N(4) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(18) bond length is 1.39 Å. The C(13)-N(4) bond length is 1.42 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(6) atom. The C(14)-C(15) bond length is 1.52 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(1), and one O(9) atom. The C(15)-O(1) bond length is 1.27 Å. The C(15)-O(9) bond length is 1.26 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(19), one C(6), and one N(5) atom. The C(16)-C(19) bond length is 1.41 Å. The C(16)-N(5) bond length is 1.43 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(12), one C(4), and one H(12) atom. The C(17)-H(12) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(13), one C(19), and one H(13) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-H(13) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(3) atom. In the twentieth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(2), and one H(14) atom. The C(20)-C(21) bond length is 1.37 Å. The C(20)-N(2) bond length is 1.39 Å. The C(20)-H(14) bond length is 1.08 Å. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(3), and one H(15) atom. The C(21)-N(3) bond length is 1.39 Å. The C(21)-H(15) bond length is 1.08 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(4), and one H(16) atom. The C(22)-N(4) bond length is 1.39 Å. The C(22)-H(16) bond length is 1.08 Å. In the twenty-third C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(6), and one H(17) atom. The C(23)-N(6) bond length is 1.39 Å. The C(23)-H(17) bond length is 1.08 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(18) atom. The C(24)-N(5) bond length is 1.37 Å. The C(24)-N(6) bond length is 1.33 Å. The C(24)-H(18) bond length is 1.08 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one La(2), one C(11), and one C(8) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one La(1), one C(10), and one C(20) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(21) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(13), one C(22), and one C(8) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(16), one C(24), and one C(9) atom. In the sixth N site, N(6) is bonded in a distorted water-like geometry to one C(23), one C(24), and one H(1) atom. The N(6)-H(1) bond length is 1.77 Å. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(6) and one O(10) atom. The H(1)-O(10) bond length is 1.00 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. The H(2)-O(10) bond length is 1.00 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(14) atom. The H(3)-O(14) bond length is 0.98 Å. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(13) and one O(14) atom. The H(4)-O(13) bond length is 1.67 Å. The H(4)-O(14) bond length is 1.00 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(15) atom. The H(5)-O(15) bond length is 0.98 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(15) atom. The H(6)-O(15) bond length is 0.99 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. There are fifteen inequivalent O sites. In the first O site, O(15) is bonded in a water-like geometry to one La(2), one H(5), and one H(6) atom. In the second O site, O(1) is bonded in a distorted linear geometry to one La(1) and one C(15) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one La(2) and one C(2) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent La(1) and one C(2) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one La(1) and one C(3) atom. In the sixth O site, O(5) is bonded in a distorted single-bond geometry to one La(2) and one C(5) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to two equivalent La(2) and one C(1) atom. In the eighth O site, O(7) is bonded in a distorted single-bond geometry to one La(1) and one C(7) atom. In the ninth O site, O(8) is bonded in a distorted single-bond geometry to one La(1) and one C(3) atom. In the tenth O site, O(9) is bonded in a distorted single-bond geometry to one La(2) and one C(15) atom. In the eleventh O site, O(10) is bonded in a distorted water-like geometry to one La(2), one H(1), and one H(2) atom. In the twelfth O site, O(11) is bonded in a distorted single-bond geometry to one La(1) and one C(1) atom. In the thirteenth O site, O(12) is bonded in a distorted single-bond geometry to one C(5) atom. In the fourteenth O site, O(13) is bonded in a distorted trigonal planar geometry to one La(1), one C(7), and one H(4) atom. In the fifteenth O site, O(14) is bonded in a water-like geometry to one La(2), one H(3), and one H(4) atom. Linkers: 2 [O]C(=O)c1cc(-n2ccnc2)c(C([O])=O)cc1-n1c[c]nc1 ,3 [O]C(=O)c1cc(-n2ccnc2)c(C([O])=O)cc1-n1ccnc1 ,2 [O]C(=O)C([O])=O. Metal clusters: 4 [La]. The MOF has largest included sphere 2.05 A, density 2.17 g/cm3, surface area 3057.18 m2/g, accessible volume 0.10 cm3/g