TbAg3C32H18(NO)8 crystallizes in the monoclinic P2_1/c space group. Tb(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. Both Tb(1)-O(1) bond lengths are 2.27 Å. Both Tb(1)-O(3) bond lengths are 2.24 Å. Both Tb(1)-O(4) bond lengths are 2.28 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one N(2) and one N(3) atom. The Ag(1)-N(2) bond length is 2.08 Å. The Ag(1)-N(3) bond length is 2.07 Å. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent N(4) atoms. Both Ag(2)-N(4) bond lengths are 2.07 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(1) atom. The C(1)-C(5) bond length is 1.39 Å. The C(1)-C(7) bond length is 1.39 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(1), and one O(4) atom. The C(2)-C(7) bond length is 1.50 Å. The C(2)-O(1) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.27 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(6), one C(7), and one H(2) atom. The C(3)-C(6) bond length is 1.39 Å. The C(3)-C(7) bond length is 1.41 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5), one C(6), and one N(1) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-C(6) bond length is 1.40 Å. The C(4)-N(1) bond length is 1.38 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(1), one C(4), and one N(2) atom. The C(5)-N(2) bond length is 1.39 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(3), one C(4), and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(5) atom. The C(8)-N(1) bond length is 1.35 Å. The C(8)-N(2) bond length is 1.34 Å. The C(8)-H(5) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(2), and one O(3) atom. The C(9)-C(16) bond length is 1.50 Å. The C(9)-O(2) bond length is 1.27 Å. The C(9)-O(3) bond length is 1.29 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(6) atom. The C(10)-C(14) bond length is 1.39 Å. The C(10)-C(16) bond length is 1.42 Å. The C(10)-H(6) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(12), one C(13), and one N(3) atom. The C(11)-C(12) bond length is 1.42 Å. The C(11)-C(13) bond length is 1.40 Å. The C(11)-N(3) bond length is 1.39 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(14), and one N(4) atom. The C(12)-C(14) bond length is 1.40 Å. The C(12)-N(4) bond length is 1.38 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(11), one C(16), and one H(7) atom. The C(13)-C(16) bond length is 1.40 Å. The C(13)-H(7) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(8) atom. The C(14)-H(8) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(9) atom. The C(15)-N(3) bond length is 1.35 Å. The C(15)-N(4) bond length is 1.35 Å. The C(15)-H(9) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(9) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(4), one C(8), and one H(4) atom. The N(1)-H(4) bond length is 1.08 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(5), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(11), and one C(15) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(2), one C(12), and one C(15) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a distorted linear geometry to one N(1) and one O(2) atom. The H(4)-O(2) bond length is 1.58 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one C(9) and one H(4) atom. In the second O site, O(3) is bonded in a bent 150 degrees geometry to one Tb(1) and one C(9) atom. In the third O site, O(4) is bonded in a bent 150 degrees geometry to one Tb(1) and one C(2) atom. In the fourth O site, O(1) is bonded in a bent 150 degrees geometry to one Tb(1) and one C(2) atom. Linkers: 4 [O]C(=O)c1ccc2[nH]cnc2c1 ,2 [O]C(=O)c1ccc2c(c1)[N]C=N2 ,2 [O]C(=O)c1ccc2c(c1)N=C[N]2. Metal clusters: 2 [Tb] ,6 [Ag]. The MOF has largest included sphere 4.56 A, density 2.06 g/cm3, surface area 3047.05 m2/g, accessible volume 0.14 cm3/g