CuC13P2NH10O6(CH)2 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a CuC13P2NH10O6 framework. In the CuC13P2NH10O6 framework, Cu(1) is bonded to one N(1), one O(1), one O(3), one O(4), and one O(5) atom to form distorted CuNO4 trigonal bipyramids that share corners with two equivalent P(1)CO3 tetrahedra and corners with two equivalent P(2)CO3 tetrahedra. The Cu(1)-N(1) bond length is 2.01 Å. The Cu(1)-O(1) bond length is 1.94 Å. The Cu(1)-O(3) bond length is 2.42 Å. The Cu(1)-O(4) bond length is 1.94 Å. The Cu(1)-O(5) bond length is 2.00 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(3) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(3) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(4) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(4) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. The C(3)-C(3) bond length is 1.48 Å. The C(3)-C(4) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(5) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(5) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(6) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(6) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(15), one C(7), and one P(1) atom. The C(6)-C(15) bond length is 1.43 Å. The C(6)-C(7) bond length is 1.38 Å. The C(6)-P(1) bond length is 1.82 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(7) atom. The C(7)-H(7) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(8)-C(9) bond length is 1.38 Å. The C(8)-H(8) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(8), and one P(2) atom. The C(9)-C(10) bond length is 1.44 Å. The C(9)-P(2) bond length is 1.82 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-C(15) bond length is 1.44 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(9) atom. The C(11)-H(9) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(12) atom. The C(14)-C(15) bond length is 1.42 Å. The C(14)-H(12) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(6) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one C(6), one O(1), one O(2), and one O(3) atom to form PCO3 tetrahedra that share corners with two equivalent Cu(1)NO4 trigonal bipyramids. The P(1)-O(1) bond length is 1.53 Å. The P(1)-O(2) bond length is 1.58 Å. The P(1)-O(3) bond length is 1.52 Å. In the second P site, P(2) is bonded to one C(9), one O(4), one O(5), and one O(6) atom to form PCO3 tetrahedra that share corners with two equivalent Cu(1)NO4 trigonal bipyramids. The P(2)-O(4) bond length is 1.52 Å. The P(2)-O(5) bond length is 1.54 Å. The P(2)-O(6) bond length is 1.56 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(5) atom. The H(1)-O(2) bond length is 1.01 Å. The H(1)-O(5) bond length is 1.63 Å. In the second H site, H(2) is bonded in a linear geometry to one O(3) and one O(6) atom. The H(2)-O(3) bond length is 1.46 Å. The H(2)-O(6) bond length is 1.04 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1), one P(1), and one H(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Cu(1), one P(2), and one H(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one P(2) and one H(2) atom. Linkers: 2 [O]P(=O)(O)c1ccc(P([O])(=O)O)c2ccccc12 ,1 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Cu]. RCSR code: sql. The MOF has largest included sphere 3.76 A, density 1.65 g/cm3, surface area 3668.47 m2/g, accessible volume 0.16 cm3/g