ZnC19NH13O5(CH2)4CH3C6H4SO2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, eight 02329_fluka molecules, eight di-isopropenylsulfon molecules, and four ZnC19NH13O5 clusters. In each ZnC19NH13O5 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(7) atom. The Zn(1)-N(1) bond length is 2.02 Å. The Zn(1)-O(1) bond length is 2.09 Å. The Zn(1)-O(2) bond length is 2.08 Å. The Zn(1)-O(3) bond length is 2.06 Å. The Zn(1)-O(7) bond length is 2.08 Å. There are nineteen inequivalent C sites. In the first C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(7) atom. The C(7)-C(10) bond length is 1.50 Å. The C(7)-O(3) bond length is 1.28 Å. The C(7)-O(7) bond length is 1.27 Å. In the second C site, C(8) is bonded in a trigonal planar geometry to one C(18), one C(19), and one C(24) atom. The C(8)-C(18) bond length is 1.41 Å. The C(8)-C(19) bond length is 1.45 Å. The C(8)-C(24) bond length is 1.41 Å. In the third C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(5) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a trigonal planar geometry to one C(15), one C(7), and one C(9) atom. The C(10)-C(15) bond length is 1.40 Å. In the fifth C site, C(13) is bonded in a distorted single-bond geometry to one C(21) and one H(7) atom. The C(13)-C(21) bond length is 1.41 Å. The C(13)-H(7) bond length is 1.09 Å. In the sixth C site, C(14) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(8) atom. The C(14)-C(19) bond length is 1.36 Å. The C(14)-C(21) bond length is 1.44 Å. The C(14)-H(8) bond length is 1.09 Å. In the seventh C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one H(9) atom. The C(15)-H(9) bond length is 1.09 Å. In the eighth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(24), one N(1), and one H(10) atom. The C(16)-C(24) bond length is 1.38 Å. The C(16)-N(1) bond length is 1.35 Å. The C(16)-H(10) bond length is 1.09 Å. In the ninth C site, C(17) is bonded in a distorted single-bond geometry to one C(21) and one O(5) atom. The C(17)-C(21) bond length is 1.43 Å. The C(17)-O(5) bond length is 1.36 Å. In the tenth C site, C(18) is bonded in a distorted single-bond geometry to one C(20), one C(8), and one H(11) atom. The C(18)-C(20) bond length is 1.39 Å. The C(18)-H(11) bond length is 1.09 Å. In the eleventh C site, C(19) is bonded in a distorted single-bond geometry to one C(14), one C(8), and one H(12) atom. The C(19)-H(12) bond length is 1.09 Å. In the twelfth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(18), one N(1), and one H(13) atom. The C(20)-N(1) bond length is 1.35 Å. The C(20)-H(13) bond length is 1.09 Å. In the thirteenth C site, C(21) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(17) atom. In the fourteenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(16), one C(8), and one H(15) atom. The C(24)-H(15) bond length is 1.09 Å. In the fifteenth C site, C(25) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(16,17) and one O(5) atom. Both C(25)-H(16,17) bond lengths are 1.10 Å. The C(25)-O(5) bond length is 1.44 Å. In the sixteenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the seventeenth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.40 Å. In the eighteenth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the nineteenth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(4)-H(2) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(16), and one C(20) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(24) atom. In the twelfth H site, H(16,17) is bonded in a single-bond geometry to one C(25) atom. There are five inequivalent O sites. In the first O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(7) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(17) and one C(25) atom. Linkers: 4 [O]C(=O)c1ccc(S(=O)(=O)c2ccc(C([O])=O)cc2)cc1 ,2 CCCCCCOc1cc(/C=C/c2ccncc2)c(OCCCCCC)cc1/C=C/c1ccncc1. Metal clusters: 2 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 5.35 A, density 1.25 g/cm3, surface area 5158.89 m2/g, accessible volume 0.24 cm3/g