CdC23H21(N2Cl)2CH is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and four CdC23H21(N2Cl)2 clusters. In each CdC23H21(N2Cl)2 cluster, Cd(1) is bonded in a tetrahedral geometry to one N(2), one N(3), one Cl(1), and one Cl(2) atom. The Cd(1)-N(2) bond length is 2.26 Å. The Cd(1)-N(3) bond length is 2.29 Å. The Cd(1)-Cl(1) bond length is 2.46 Å. The Cd(1)-Cl(2) bond length is 2.45 Å. There are twenty-three inequivalent C sites. In the first C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(10) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(10) bond length is 1.09 Å. In the second C site, C(11) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(15) atom. The C(11)-C(1) bond length is 1.51 Å. The C(11)-C(15) bond length is 1.40 Å. In the third C site, C(12) is bonded in a distorted single-bond geometry to one C(21), one C(7), and one H(11) atom. The C(12)-C(21) bond length is 1.40 Å. The C(12)-C(7) bond length is 1.40 Å. The C(12)-H(11) bond length is 1.09 Å. In the fourth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(20), one C(7), and one N(3) atom. The C(13)-C(20) bond length is 1.40 Å. The C(13)-C(7) bond length is 1.42 Å. The C(13)-N(3) bond length is 1.39 Å. In the fifth C site, C(14) is bonded in a distorted single-bond geometry to one C(2) and one H(12) atom. The C(14)-C(2) bond length is 1.40 Å. The C(14)-H(12) bond length is 1.09 Å. In the sixth C site, C(15) is bonded in a distorted single-bond geometry to one C(11) and one H(13) atom. The C(15)-H(13) bond length is 1.09 Å. In the seventh C site, C(16) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one N(2) atom. The C(16)-C(6) bond length is 1.48 Å. The C(16)-N(1) bond length is 1.37 Å. The C(16)-N(2) bond length is 1.34 Å. In the eighth C site, C(17) is bonded in a distorted single-bond geometry to one C(9) and one H(14) atom. The C(17)-C(9) bond length is 1.40 Å. The C(17)-H(14) bond length is 1.09 Å. In the ninth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(23), one N(3), and one N(4) atom. The C(18)-C(23) bond length is 1.48 Å. The C(18)-N(3) bond length is 1.34 Å. The C(18)-N(4) bond length is 1.37 Å. In the tenth C site, C(19) is bonded in a distorted single-bond geometry to one C(2) and one H(15) atom. The C(19)-C(2) bond length is 1.40 Å. The C(19)-H(15) bond length is 1.09 Å. In the eleventh C site, C(20) is bonded in a distorted single-bond geometry to one C(13) and one H(16) atom. The C(20)-H(16) bond length is 1.09 Å. In the twelfth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(12), one C(24), and one H(17) atom. The C(21)-C(24) bond length is 1.41 Å. The C(21)-H(17) bond length is 1.09 Å. In the thirteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(5) and one H(18) atom. The C(22)-C(5) bond length is 1.39 Å. The C(22)-H(18) bond length is 1.09 Å. In the fourteenth C site, C(23) is bonded in a distorted trigonal non-coplanar geometry to one C(18), one H(19), one H(20), and one H(21) atom. The C(23)-H(19) bond length is 1.10 Å. The C(23)-H(20) bond length is 1.10 Å. The C(23)-H(21) bond length is 1.10 Å. In the fifteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(21) and one H(22) atom. The C(24)-H(22) bond length is 1.09 Å. In the sixteenth C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one N(4), one H(1), and one H(2) atom. The C(1)-N(4) bond length is 1.46 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the seventeenth C site, C(2) is bonded in a trigonal planar geometry to one C(14), one C(19), and one C(3) atom. The C(2)-C(3) bond length is 1.51 Å. In the eighteenth C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one N(1), one H(3), and one H(4) atom. The C(3)-N(1) bond length is 1.45 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(4) bond length is 1.10 Å. In the nineteenth C site, C(4) is bonded in a distorted single-bond geometry to one C(5), one C(9), and one N(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(9) bond length is 1.41 Å. The C(4)-N(1) bond length is 1.39 Å. In the twentieth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(22), one C(4), and one H(5) atom. The C(5)-H(5) bond length is 1.09 Å. In the twenty-first C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(16), one H(6), one H(7), and one H(8) atom. The C(6)-H(6) bond length is 1.10 Å. The C(6)-H(7) bond length is 1.10 Å. The C(6)-H(8) bond length is 1.10 Å. In the twenty-second C site, C(7) is bonded in a distorted single-bond geometry to one C(12), one C(13), and one N(4) atom. The C(7)-N(4) bond length is 1.39 Å. In the twenty-third C site, C(9) is bonded in a distorted trigonal planar geometry to one C(17), one C(4), and one N(2) atom. The C(9)-N(2) bond length is 1.39 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(16), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(16), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(18) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one C(18), and one C(7) atom. There are twenty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(23) atom. In the twentieth H site, H(21) is bonded in a single-bond geometry to one C(23) atom. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one C(24) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cd(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cd(1) atom. Linkers: 4 Cc1nc2ccccc2n1Cc1ccc(Cn2c(C)nc3ccccc32)cc1. Metal clusters: 4 Cl[Cd]Cl. The MOF has largest included sphere 3.96 A, density 1.41 g/cm3, surface area 4721.92 m2/g, accessible volume 0.27 cm3/g