CuC32H20(NO2)4(CH)8 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and one CuC32H20(NO2)4 cluster. In the CuC32H20(NO2)4 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent O(1) atoms. Both Cu(1)-N(2) bond lengths are 1.96 Å. Both Cu(1)-O(1) bond lengths are 2.01 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.50 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(3) atom. The C(2)-C(13) bond length is 1.50 Å. The C(2)-C(3) bond length is 1.41 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(1), one C(12), and one C(8) atom. The C(7)-C(12) bond length is 1.40 Å. The C(7)-C(8) bond length is 1.41 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(14), one C(7), and one C(9) atom. The C(8)-C(14) bond length is 1.50 Å. The C(8)-C(9) bond length is 1.40 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(9)-H(6) bond length is 1.09 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(9) atom. The C(12)-H(9) bond length is 1.09 Å. In the ninth C site, C(13) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(13)-O(1) bond length is 1.29 Å. The C(13)-O(2) bond length is 1.27 Å. In the tenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.32 Å. The C(14)-O(4) bond length is 1.24 Å. In the eleventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one C(17), and one N(1) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(17) bond length is 1.40 Å. The C(15)-N(1) bond length is 1.42 Å. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(10,11) atom. The C(16)-H(10,11) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one H(10,11) atom. The C(17)-H(10,11) bond length is 1.09 Å. In the fourteenth C site, C(18) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(12) atom. The C(18)-N(1) bond length is 1.36 Å. The C(18)-N(2) bond length is 1.33 Å. The C(18)-H(12) bond length is 1.09 Å. In the fifteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(2), and one H(13) atom. The C(19)-C(20) bond length is 1.37 Å. The C(19)-N(2) bond length is 1.38 Å. The C(19)-H(13) bond length is 1.08 Å. In the sixteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(1), and one H(14) atom. The C(20)-N(1) bond length is 1.39 Å. The C(20)-H(14) bond length is 1.08 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(15), one C(18), and one C(20) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(18), and one C(19) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(3) atom. The H(1)-O(2) bond length is 1.45 Å. The H(1)-O(3) bond length is 1.05 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(10,11) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(13) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(13) and one H(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(14) and one H(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(14) atom. Linkers: 2 [c]1cn(-c2ccc(-n3ccnc3)cc2)cn1 ,1 c1cn(-c2ccc(-n3ccnc3)cc2)cn1. Metal clusters: 1 [Cu]. The MOF has largest included sphere 2.25 A, density 1.55 g/cm3, surface area 4491.79 m2/g, accessible volume 0.19 cm3/g