NiC12H10(NO)4NiC14H12(NO)4(CH3)8(CH)2(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, eight 02329_fluka molecules, sixteen 02329_fluka molecules, two NiC12H10(NO)4 clusters, and two NiC14H12(NO)4 clusters. In each NiC12H10(NO)4 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. Both Ni(1)-N(1) bond lengths are 2.05 Å. Both Ni(1)-O(1) bond lengths are 2.06 Å. Both Ni(1)-O(2) bond lengths are 2.05 Å. There are six inequivalent C sites. In the first C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(2), and one H(9) atom. The C(7)-C(8) bond length is 1.38 Å. The C(7)-N(2) bond length is 1.38 Å. The C(7)-H(9) bond length is 1.08 Å. In the second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(1), and one H(10) atom. The C(8)-N(1) bond length is 1.37 Å. The C(8)-H(10) bond length is 1.08 Å. In the third C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(11), and one H(12) atom. The C(9)-N(2) bond length is 1.45 Å. The C(9)-H(11) bond length is 1.10 Å. The C(9)-H(12) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one O(2) atom. The C(4)-O(2) bond length is 1.28 Å. In the fifth C site, C(2) is bonded in a distorted single-bond geometry to one O(1) atom. The C(2)-O(1) bond length is 1.27 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(8) atom. The C(6)-N(1) bond length is 1.33 Å. The C(6)-N(2) bond length is 1.36 Å. The C(6)-H(8) bond length is 1.08 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(6), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(6), one C(7), and one C(9) atom. There are five inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(4) atom. In each NiC14H12(NO)4 cluster, Ni(2) is bonded in an octahedral geometry to one N(4), one N(5), one O(3), one O(4), one O(5), and one O(6) atom. The Ni(2)-N(4) bond length is 2.07 Å. The Ni(2)-N(5) bond length is 2.08 Å. The Ni(2)-O(3) bond length is 2.03 Å. The Ni(2)-O(4) bond length is 2.07 Å. The Ni(2)-O(5) bond length is 2.06 Å. The Ni(2)-O(6) bond length is 2.05 Å. There are fourteen inequivalent C sites. In the first C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one N(3); one H(17); and one H(18,39,40) atom. The C(12)-N(3) bond length is 1.46 Å. The C(12)-H(17) bond length is 1.10 Å. The C(12)-H(18,39,40) bond length is 1.10 Å. In the second C site, C(13) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(19) atom. The C(13)-N(3) bond length is 1.36 Å. The C(13)-N(4) bond length is 1.33 Å. The C(13)-H(19) bond length is 1.09 Å. In the third C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(3), and one H(20) atom. The C(14)-C(15) bond length is 1.38 Å. The C(14)-N(3) bond length is 1.38 Å. The C(14)-H(20) bond length is 1.08 Å. In the fourth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(4), and one H(21) atom. The C(15)-N(4) bond length is 1.38 Å. The C(15)-H(21) bond length is 1.08 Å. In the fifth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one O(3) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-O(3) bond length is 1.27 Å. In the sixth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(25) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-H(25) bond length is 1.09 Å. In the seventh C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one O(4) atom. The C(19)-O(4) bond length is 1.28 Å. In the eighth C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one O(5) atom. The C(22)-C(23) bond length is 1.41 Å. The C(22)-O(5) bond length is 1.28 Å. In the ninth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one H(32) atom. The C(23)-C(24) bond length is 1.41 Å. The C(23)-H(32) bond length is 1.09 Å. In the tenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one O(6) atom. The C(24)-O(6) bond length is 1.28 Å. In the eleventh C site, C(26) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(36) atom. The C(26)-N(5) bond length is 1.33 Å. The C(26)-N(6) bond length is 1.36 Å. The C(26)-H(36) bond length is 1.09 Å. In the twelfth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(28), one N(6), and one H(37) atom. The C(27)-C(28) bond length is 1.38 Å. The C(27)-N(6) bond length is 1.38 Å. The C(27)-H(37) bond length is 1.08 Å. In the thirteenth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one N(5), and one H(38) atom. The C(28)-N(5) bond length is 1.38 Å. The C(28)-H(38) bond length is 1.08 Å. In the fourteenth C site, C(29) is bonded in a distorted trigonal non-coplanar geometry to one N(6) and two equivalent H(18,39,40) atoms. The C(29)-N(6) bond length is 1.47 Å. Both C(29)-H(18,39,40) bond lengths are 1.10 Å. There are four inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(14) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Ni(2), one C(13), and one C(15) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Ni(2), one C(26), and one C(28) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one C(26), one C(27), and one C(29) atom. There are ten inequivalent H sites. In the first H site, H(17) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(18,39,40) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(20) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(21) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(25) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(32) is bonded in a single-bond geometry to one C(23) atom. In the eighth H site, H(36) is bonded in a single-bond geometry to one C(26) atom. In the ninth H site, H(37) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(38) is bonded in a single-bond geometry to one C(28) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Ni(2) and one C(17) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one Ni(2) and one C(19) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Ni(2) and one C(22) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one Ni(2) and one C(24) atom. Linkers: 4 CC(=O)[CH]C(C)=O ,4 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 4 [Ni]. The MOF has largest included sphere 5.40 A, density 0.83 g/cm3, surface area 5688.02 m2/g, accessible volume 0.64 cm3/g