CdC17H11(NO)4(CH)3 is Indium-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and four CdC17H11(NO)4 clusters. In each CdC17H11(NO)4 cluster, Cd(1) is bonded in a distorted octahedral geometry to one N(1), one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.28 Å. The Cd(1)-N(3) bond length is 2.28 Å. The Cd(1)-O(1) bond length is 2.35 Å. The Cd(1)-O(2) bond length is 2.45 Å. The Cd(1)-O(3) bond length is 2.48 Å. The Cd(1)-O(4) bond length is 2.34 Å. There are seventeen inequivalent C sites. In the first C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(13) atom. The C(18)-C(17) bond length is 1.40 Å. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(13) bond length is 1.09 Å. In the second C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(14) atom. The C(19)-H(14) bond length is 1.09 Å. In the third C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(3), and one O(4) atom. The C(20)-C(17) bond length is 1.50 Å. The C(20)-O(3) bond length is 1.28 Å. The C(20)-O(4) bond length is 1.28 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-N(1) bond length is 1.38 Å. The C(1)-H(1) bond length is 1.08 Å. In the fifth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(2), and one H(2) atom. The C(2)-N(2) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.09 Å. In the sixth C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. The C(3)-N(1) bond length is 1.33 Å. The C(3)-N(2) bond length is 1.37 Å. The C(3)-H(3) bond length is 1.08 Å. In the seventh C site, C(4) is bonded in a distorted single-bond geometry to one N(2) atom. The C(4)-N(2) bond length is 1.42 Å. In the eighth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(5) bond length is 1.09 Å. In the ninth C site, C(7) is bonded in a trigonal planar geometry to one C(10), one C(6), and one C(8) atom. The C(7)-C(10) bond length is 1.50 Å. The C(7)-C(8) bond length is 1.40 Å. In the tenth C site, C(8) is bonded in a single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the eleventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(1), and one O(2) atom. The C(10)-O(1) bond length is 1.28 Å. The C(10)-O(2) bond length is 1.28 Å. In the twelfth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(3), and one H(8) atom. The C(11)-C(12) bond length is 1.37 Å. The C(11)-N(3) bond length is 1.38 Å. The C(11)-H(8) bond length is 1.08 Å. In the thirteenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(4), and one H(9) atom. The C(12)-N(4) bond length is 1.39 Å. The C(12)-H(9) bond length is 1.08 Å. In the fourteenth C site, C(13) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(10) atom. The C(13)-N(3) bond length is 1.33 Å. The C(13)-N(4) bond length is 1.36 Å. The C(13)-H(10) bond length is 1.08 Å. In the fifteenth C site, C(14) is bonded in a distorted single-bond geometry to one N(4) atom. The C(14)-N(4) bond length is 1.42 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(12) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(12) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one C(13) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(14) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(19) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Cd(1) and one C(10) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(10) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(20) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Cd(1) and one C(20) atom. Linkers: 1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=N[Cd].[CH]=N[Cd].[CH]=[CH].[CH]=[CH].[CH]=[N].[CH]=[N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=N[Cd].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]C(=O)O[Cd]([N])([N])[O].[C]C([O])=O.[C][CH].[C][CH].[C][CH][C].[C][CH][C].[C][CH][C].[C][C].[C][C]/[C]=[C]\[C][N][C].[C][N].[C][N].[C][N][CH][C][N].[C][N][C].[Cd].[Cd].[Cd].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=C[N].[CH]=C[N].[CH]=C[N].[CH]=C[N].[CH]=[CH].[CH]=[N].[CH]=[N].[CH]=[N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/[C]=C\[C]=C/[C].[C]=N[Cd].[C]=N[Cd][N].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C][CH].[C][C].[C][C]=[CH].[C][C][N][C].[C][N].[C][N].[Cd].[Cd].[Cd].[Cd].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][Cd].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O ,1 [CH]=C[C]N1[CH]N([Cd]23(N4[CH]N(c5ccc(C([O])=O)cc5)C=C4)(O[C](c4ccc(-n5ccnc5)cc4)O2)OC(=[C]C=[CH])O3)C=C1 ,1 [CH][C]=C1O[Cd]2(N3[CH]N(C(=[CH])C=[CH])C=C3)(N3[CH]N(c4ccc(C([O])=O)cc4)C=C3)(O[C](c3ccc(-n4ccnc4)cc3)O2)O1. Metal clusters: 1 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 5.84 A, density 1.15 g/cm3, surface area 4425.31 m2/g, accessible volume 0.43 cm3/g