CH3CdC8N3H4S2O crystallizes in the monoclinic Pc space group. The structure consists of two 02329_fluka molecules inside a CdC8N3H4S2O framework. In the CdC8N3H4S2O framework, Cd(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one S(1), one S(2), and one O(1) atom. The Cd(1)-N(1) bond length is 2.28 Å. The Cd(1)-N(2) bond length is 2.26 Å. The Cd(1)-N(3) bond length is 2.37 Å. The Cd(1)-S(1) bond length is 2.70 Å. The Cd(1)-S(2) bond length is 2.73 Å. The Cd(1)-O(1) bond length is 2.52 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.63 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(2) atom. The C(2)-N(2) bond length is 1.18 Å. The C(2)-S(2) bond length is 1.63 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(3), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-N(3) bond length is 1.35 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-C(8) bond length is 1.49 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one N(3), and one H(4) atom. The C(7)-N(3) bond length is 1.34 Å. The C(7)-H(4) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one O(1) atom. The C(8)-O(1) bond length is 1.24 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(1) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(3), and one C(7) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Cd(1) and one C(2) atom. O(1) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(8) atom. Linkers: 2 CC(=O)c1cccnc1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 1.81 A, density 2.05 g/cm3, surface area 4066.62 m2/g, accessible volume 0.11 cm3/g