NaMo2C14H22(NO5)3 crystallizes in the triclinic P1 space group. Na(1) is bonded in a 5-coordinate geometry to one O(11), one O(14), one O(3), one O(6), and one O(9) atom. The Na(1)-O(11) bond length is 2.32 Å. The Na(1)-O(14) bond length is 2.25 Å. The Na(1)-O(3) bond length is 2.41 Å. The Na(1)-O(6) bond length is 2.37 Å. The Na(1)-O(9) bond length is 2.27 Å. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one N(1), one O(1), one O(2), one O(4), one O(5), and one O(7) atom. The Mo(1)-N(1) bond length is 2.45 Å. The Mo(1)-O(1) bond length is 1.94 Å. The Mo(1)-O(2) bond length is 1.95 Å. The Mo(1)-O(4) bond length is 1.70 Å. The Mo(1)-O(5) bond length is 2.12 Å. The Mo(1)-O(7) bond length is 2.11 Å. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one N(2), one N(3), one O(1), one O(10), one O(2), and one O(3) atom. The Mo(2)-N(2) bond length is 2.43 Å. The Mo(2)-N(3) bond length is 2.37 Å. The Mo(2)-O(1) bond length is 1.93 Å. The Mo(2)-O(10) bond length is 2.11 Å. The Mo(2)-O(2) bond length is 1.93 Å. The Mo(2)-O(3) bond length is 1.71 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(1)-O(5) bond length is 1.29 Å. The C(1)-O(6) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(2)-N(1) bond length is 1.48 Å. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(3)-O(7) bond length is 1.29 Å. The C(3)-O(8) bond length is 1.25 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(3), and one H(4) atom. The C(4)-N(1) bond length is 1.47 Å. The C(4)-H(3) bond length is 1.10 Å. The C(4)-H(4) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a 3-coordinate geometry to one N(1), one H(5), and one H(6) atom. The C(5)-N(1) bond length is 1.50 Å. The C(5)-H(5) bond length is 1.10 Å. The C(5)-H(6) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a 3-coordinate geometry to one N(2), one H(7), and one H(8) atom. The C(6)-N(2) bond length is 1.50 Å. The C(6)-H(7) bond length is 1.10 Å. The C(6)-H(8) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(10), and one H(9) atom. The C(7)-N(2) bond length is 1.48 Å. The C(7)-H(10) bond length is 1.10 Å. The C(7)-H(9) bond length is 1.10 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(8)-O(10) bond length is 1.30 Å. The C(8)-O(9) bond length is 1.24 Å. In the ninth C site, C(9) is bonded in a 4-coordinate geometry to one C(10), one N(2), one H(11), and one H(12) atom. The C(9)-C(10) bond length is 1.51 Å. The C(9)-N(2) bond length is 1.50 Å. The C(9)-H(11) bond length is 1.10 Å. The C(9)-H(12) bond length is 1.10 Å. In the tenth C site, C(10) is bonded in a 4-coordinate geometry to one C(9), one N(3), one H(13), and one H(14) atom. The C(10)-N(3) bond length is 1.50 Å. The C(10)-H(13) bond length is 1.10 Å. The C(10)-H(14) bond length is 1.10 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(15), and one H(16) atom. The C(11)-N(3) bond length is 1.49 Å. The C(11)-H(15) bond length is 1.10 Å. The C(11)-H(16) bond length is 1.10 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(14) atom. The C(12)-O(13) bond length is 1.35 Å. The C(12)-O(14) bond length is 1.22 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(17), and one H(18) atom. The C(13)-N(3) bond length is 1.50 Å. The C(13)-H(17) bond length is 1.09 Å. The C(13)-H(18) bond length is 1.10 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. The C(14)-O(11) bond length is 1.24 Å. The C(14)-O(12) bond length is 1.32 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one C(2), one C(4), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Mo(2), one C(6), one C(7), and one C(9) atom. In the third N site, N(3) is bonded in a distorted tetrahedral geometry to one Mo(2), one C(10), one C(11), and one C(13) atom. There are twenty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(11) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(13) atom. In the nineteenth H site, H(19) is bonded in a linear geometry to one O(12) and one O(15) atom. The H(19)-O(12) bond length is 1.05 Å. The H(19)-O(15) bond length is 1.48 Å. In the twentieth H site, H(20) is bonded in a single-bond geometry to one O(13) atom. The H(20)-O(13) bond length is 0.99 Å. In the twenty-first H site, H(21) is bonded in a distorted linear geometry to one O(15) and one O(8) atom. The H(21)-O(15) bond length is 1.01 Å. The H(21)-O(8) bond length is 1.62 Å. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one O(15) atom. The H(22)-O(15) bond length is 0.98 Å. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Mo(1) and one Mo(2) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Mo(1) and one Mo(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one Mo(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mo(1) and one C(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Na(1) and one C(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one C(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one C(3) and one H(21) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one C(8) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Mo(2) and one C(8) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one C(14) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one C(14) and one H(19) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one C(12) and one H(20) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one C(12) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one H(19), one H(21), and one H(22) atom. Linkers: 1 [O]C(=O)CN(CCN(CC([O])=O)CC([O])=O)CCN(CC(=O)O)CC(=O)O. Metal clusters: 1 [Na] ,2 [Mo]. The MOF has largest included sphere 2.74 A, density 1.99 g/cm3, surface area 3057.77 m2/g, accessible volume 0.12 cm3/g