CuC14N3H8O4(CH)3C2H4S is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two dimethyl sulfide molecules, and two CuC14N3H8O4 clusters. In each CuC14N3H8O4 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1); one N(2); one N(3); and two equivalent O(1,2) atoms. The Cu(1)-N(1) bond length is 2.01 Å. The Cu(1)-N(2) bond length is 2.01 Å. The Cu(1)-N(3) bond length is 1.95 Å. Both Cu(1)-O(1,2) bond lengths are 2.12 Å. There are nine inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal planar geometry to one C(3,4); one N(1); and one H(1,2) atom. The C(1,2)-C(3,4) bond length is 1.39 Å. The C(1,2)-N(1) bond length is 1.34 Å. The C(1,2)-H(1,2) bond length is 1.09 Å. In the second C site, C(3,4) is bonded in a distorted single-bond geometry to one C(1,2) and one H(3,4) atom. The C(3,4)-H(3,4) bond length is 1.09 Å. In the third C site, C(7) is bonded in a distorted single-bond geometry to one C(9,10) and one H(7,8) atom. The C(7)-C(9,10) bond length is 1.40 Å. The C(7)-H(7,8) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one C(9,10) and one H(7,8) atom. The C(8)-C(9,10) bond length is 1.40 Å. The C(8)-H(7,8) bond length is 1.09 Å. In the fifth C site, C(9,10) is bonded in a distorted trigonal planar geometry to one C(11), one C(7), and one N(1) atom. The C(9,10)-C(11) bond length is 1.47 Å. The C(9,10)-N(1) bond length is 1.36 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(13,14); one C(9,10); and one N(3) atom. The C(11)-C(13,14) bond length is 1.40 Å. The C(11)-N(3) bond length is 1.34 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13,14); one C(9,10); and one N(3) atom. The C(12)-C(13,14) bond length is 1.40 Å. The C(12)-C(9,10) bond length is 1.47 Å. The C(12)-N(3) bond length is 1.34 Å. In the eighth C site, C(13,14) is bonded in a distorted single-bond geometry to one C(11) and one H(9,10) atom. The C(13,14)-H(9,10) bond length is 1.09 Å. In the ninth C site, C(16,17) is bonded in a distorted bent 120 degrees geometry to one O(1,2) and one O(3,4) atom. The C(16,17)-O(1,2) bond length is 1.28 Å. The C(16,17)-O(3,4) bond length is 1.26 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1); one C(1,2); and one C(9,10) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1); one C(1,2); and one C(9,10) atom. The N(2)-C(1,2) bond length is 1.34 Å. The N(2)-C(9,10) bond length is 1.36 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(12) atom. There are four inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(3,4) atom. In the third H site, H(7,8) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(9,10) is bonded in a single-bond geometry to one C(13,14) atom. There are two inequivalent O sites. In the first O site, O(1,2) is bonded in a water-like geometry to one Cu(1) and one C(16,17) atom. In the second O site, O(3,4) is bonded in a single-bond geometry to one C(16,17) atom. Linkers: 2 [O]C(=O)CSCC([O])=O. Metal clusters: 2 [Cu]. The MOF has largest included sphere 1.82 A, density 1.67 g/cm3, surface area 4675.12 m2/g, accessible volume 0.12 cm3/g