ZnC16H15(NO3)2(CH2)4C5H4NO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two n-methylmethacrylamide molecules, and one ZnC16H15(NO3)2 cluster. In the ZnC16H15(NO3)2 cluster, Zn(1) is bonded in a square pyramidal geometry to one O(1), one O(2), one O(5), one O(6), and one O(7) atom. The Zn(1)-O(1) bond length is 2.03 Å. The Zn(1)-O(2) bond length is 2.09 Å. The Zn(1)-O(5) bond length is 2.05 Å. The Zn(1)-O(6) bond length is 2.06 Å. The Zn(1)-O(7) bond length is 2.05 Å. There are sixteen inequivalent C sites. In the first C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(2), and one O(6) atom. The C(2)-C(5) bond length is 1.50 Å. The C(2)-O(2) bond length is 1.27 Å. The C(2)-O(6) bond length is 1.28 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(3), and one O(4) atom. The C(3)-C(7) bond length is 1.50 Å. The C(3)-N(3) bond length is 1.35 Å. The C(3)-O(4) bond length is 1.25 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one C(14), one C(17), and one C(2) atom. The C(5)-C(14) bond length is 1.40 Å. The C(5)-C(17) bond length is 1.40 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(4) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(3), one C(6), and one C(9) atom. The C(7)-C(9) bond length is 1.40 Å. In the sixth C site, C(8) is bonded in a distorted water-like geometry to one N(3) and one H(5) atom. The C(8)-N(3) bond length is 1.45 Å. The C(8)-H(5) bond length is 1.10 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(17), one C(7), and one H(6) atom. The C(9)-C(17) bond length is 1.39 Å. The C(9)-H(6) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a trigonal planar geometry to one N(1), one H(8), and one O(1) atom. The C(11)-N(1) bond length is 1.33 Å. The C(11)-H(8) bond length is 1.10 Å. The C(11)-O(1) bond length is 1.26 Å. In the ninth C site, C(12) is bonded to one N(1), one H(10), one H(11), and one H(9) atom to form corner-sharing CH3N tetrahedra. The C(12)-N(1) bond length is 1.46 Å. The C(12)-H(10) bond length is 1.10 Å. The C(12)-H(11) bond length is 1.09 Å. The C(12)-H(9) bond length is 1.10 Å. In the tenth C site, C(14) is bonded in a distorted single-bond geometry to one C(5) and one H(13) atom. The C(14)-H(13) bond length is 1.09 Å. In the eleventh C site, C(16) is bonded in a distorted single-bond geometry to one C(25) and one H(14) atom. The C(16)-C(25) bond length is 1.40 Å. The C(16)-H(14) bond length is 1.09 Å. In the twelfth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one H(15) atom. The C(17)-H(15) bond length is 1.09 Å. In the thirteenth C site, C(18) is bonded to one N(1), one H(16), one H(17), and one H(18) atom to form corner-sharing CH3N tetrahedra. The C(18)-N(1) bond length is 1.45 Å. The C(18)-H(16) bond length is 1.10 Å. The C(18)-H(17) bond length is 1.10 Å. The C(18)-H(18) bond length is 1.10 Å. In the fourteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(25) and one H(21) atom. The C(20)-C(25) bond length is 1.40 Å. The C(20)-H(21) bond length is 1.09 Å. In the fifteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(5), and one O(7) atom. The C(24)-C(25) bond length is 1.50 Å. The C(24)-O(5) bond length is 1.27 Å. The C(24)-O(7) bond length is 1.27 Å. In the sixteenth C site, C(25) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(24) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(18) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(3), one C(8), and one H(2) atom. The N(3)-H(2) bond length is 1.03 Å. There are fifteen inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(20) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(11) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the third O site, O(4) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(24) atom. In the fifth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(24) atom. Linkers: 1 [O]C(=O)c1ccc(C(=O)N[C@@H]2CCCC[C@H]2NC(=O)c2ccc(C([O])=O)cc2)cc1 ,1 [O]C(=O)c1ccc(C(=O)N[C@H]2CCCC[C@@H]2NC(=O)c2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 5.72 A, density 1.01 g/cm3, surface area 5174.98 m2/g, accessible volume 0.41 cm3/g