(PtAuC8H18(NS)2)2Zn(CO2)4 is Indium-derived structured and crystallizes in the hexagonal P6_422 space group. The structure is zero-dimensional and consists of three PtAuC8H18(NS)2 clusters and three Zn(CO2)4 clusters. In each PtAuC8H18(NS)2 cluster, Pt(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent S(1) atoms. Both Pt(1)-N(1) bond lengths are 2.06 Å. Both Pt(1)-S(1) bond lengths are 2.31 Å. Au(1) is bonded in a linear geometry to two equivalent S(1) atoms. Both Au(1)-S(1) bond lengths are 2.31 Å. There are four inequivalent C sites. In the first C site, C(2) is bonded in a 2-coordinate geometry to one C(1), one N(1), and one H(3) atom. The C(2)-C(1) bond length is 1.54 Å. The C(2)-N(1) bond length is 1.50 Å. The C(2)-H(3) bond length is 1.10 Å. In the second C site, C(3) is bonded in a trigonal non-coplanar geometry to one C(1), one H(4), one H(5), and one H(6) atom. The C(3)-C(1) bond length is 1.53 Å. The C(3)-H(4) bond length is 1.10 Å. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(6) bond length is 1.10 Å. In the third C site, C(1) is bonded in a tetrahedral geometry to one C(2), one C(3), one C(4), and one S(1) atom. The C(1)-C(4) bond length is 1.53 Å. The C(1)-S(1) bond length is 1.87 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one H(7), one H(8), and one H(9) atom. The C(4)-H(7) bond length is 1.10 Å. The C(4)-H(8) bond length is 1.10 Å. The C(4)-H(9) bond length is 1.10 Å. N(1) is bonded in a 4-coordinate geometry to one Pt(1), one C(2), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.03 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the seventh H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one Au(1), and one C(1) atom. In each Zn(CO2)4 cluster, Zn(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. All Zn(1)-O(1) bond lengths are 1.98 Å. C(5) is bonded in a distorted trigonal planar geometry to one O(1) and one O(2) atom. The C(5)-O(1) bond length is 1.29 Å. The C(5)-O(2) bond length is 1.24 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one C(5) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. Linkers: 12 CC(C)([S])[C@@H](N)C([O])=O. Metal clusters: 3 [Zn] ,6 [Pt] ,6 [Au]. The MOF has largest included sphere 4.23 A, density 2.16 g/cm3, surface area 2603.20 m2/g, accessible volume 0.22 cm3/g