Cd3H22(CN)26(CH)2 crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a Cd3H22(CN)26 framework. In the Cd3H22(CN)26 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to two equivalent N(10), two equivalent N(3), and two equivalent N(7) atoms to form corner-sharing CdN6 octahedra. The corner-sharing octahedral tilt angles are 76°. Both Cd(1)-N(10) bond lengths are 2.31 Å. Both Cd(1)-N(3) bond lengths are 2.40 Å. Both Cd(1)-N(7) bond lengths are 2.36 Å. In the second Cd site, Cd(2) is bonded to one N(1), one N(10), one N(13), one N(2), one N(8), and one N(9) atom to form corner-sharing CdN6 octahedra. The corner-sharing octahedral tilt angles are 76°. The Cd(2)-N(1) bond length is 2.35 Å. The Cd(2)-N(10) bond length is 2.38 Å. The Cd(2)-N(13) bond length is 2.38 Å. The Cd(2)-N(2) bond length is 2.34 Å. The Cd(2)-N(8) bond length is 2.52 Å. The Cd(2)-N(9) bond length is 2.33 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(7), one C(8), and one H(1) atom. The C(1)-C(7) bond length is 1.40 Å. The C(1)-C(8) bond length is 1.39 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(13), one N(6), and one N(7) atom. The C(2)-C(13) bond length is 1.50 Å. The C(2)-N(6) bond length is 1.34 Å. The C(2)-N(7) bond length is 1.35 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(4), and one N(5) atom. The C(3)-C(4) bond length is 1.49 Å. The C(3)-N(4) bond length is 1.35 Å. The C(3)-N(5) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a water-like geometry to one C(3), one C(5), one H(2), and one H(3) atom. The C(4)-C(5) bond length is 1.51 Å. The C(4)-H(2) bond length is 1.11 Å. The C(4)-H(3) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(7) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(13), and one H(4) atom. The C(6)-N(13) bond length is 1.34 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(1), one N(13), and one H(6) atom. The C(8)-N(13) bond length is 1.34 Å. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(1), and one H(7) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(13) bond length is 1.51 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(11)-H(8) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(12)-N(1) bond length is 1.34 Å. The C(12)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted water-like geometry to one C(10), one C(2), one H(10), and one H(11) atom. The C(13)-H(10) bond length is 1.10 Å. The C(13)-H(11) bond length is 1.10 Å. There are thirteen inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(2), one C(12), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(2), one N(3), and one N(5) atom. The N(2)-N(3) bond length is 1.33 Å. The N(2)-N(5) bond length is 1.34 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one N(2), and one N(4) atom. The N(3)-N(4) bond length is 1.33 Å. In the fourth N site, N(4) is bonded in a distorted water-like geometry to one C(3) and one N(3) atom. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(3) and one N(2) atom. In the sixth N site, N(6) is bonded in a distorted water-like geometry to one C(2) and one N(9) atom. The N(6)-N(9) bond length is 1.34 Å. In the seventh N site, N(7) is bonded in a 3-coordinate geometry to one Cd(1), one C(2), and one N(8) atom. The N(7)-N(8) bond length is 1.34 Å. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Cd(2), one N(7), and one N(9) atom. The N(8)-N(9) bond length is 1.32 Å. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Cd(2), one N(6), and one N(8) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Cd(1), one Cd(2), and one N(11) atom. The N(10)-N(11) bond length is 1.21 Å. In the eleventh N site, N(11) is bonded in a linear geometry to one N(10) and one N(12) atom. The N(11)-N(12) bond length is 1.17 Å. In the twelfth N site, N(12) is bonded in a single-bond geometry to one N(11) atom. In the thirteenth N site, N(13) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(6), and one C(8) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. Linkers: 1 c1cncc(CC2=N[N]N=N2)c1 ,3 c1cncc(CC2=NN=N[N]2)c1. Metal clusters: 3 [Cd]. The MOF has largest included sphere 2.80 A, density 1.92 g/cm3, surface area 3801.36 m2/g, accessible volume 0.14 cm3/g