Na2C12H24S2O17 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Na2C12H24S2O17 cluster. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(15), one O(17), one O(2), one O(3), one O(4), and one O(6) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(2)O6 octahedra,  a cornercorner with one C(6)H3O tetrahedra,  a cornercorner with one S(1)O4 tetrahedra, and  a cornercorner with one S(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 73°. The Na(1)-O(15) bond length is 2.29 Å. The Na(1)-O(17) bond length is 2.36 Å. The Na(1)-O(2) bond length is 2.44 Å. The Na(1)-O(3) bond length is 2.40 Å. The Na(1)-O(4) bond length is 2.42 Å. The Na(1)-O(6) bond length is 2.35 Å. In the second Na site, Na(2) is bonded to one O(10), one O(11), one O(12), one O(14), one O(17), and one O(7) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one C(12)H3O tetrahedra,  a cornercorner with one S(1)O4 tetrahedra, and  a cornercorner with one S(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 73°. The Na(2)-O(10) bond length is 2.49 Å. The Na(2)-O(11) bond length is 2.40 Å. The Na(2)-O(12) bond length is 2.43 Å. The Na(2)-O(14) bond length is 2.35 Å. The Na(2)-O(17) bond length is 2.37 Å. The Na(2)-O(7) bond length is 2.32 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one O(1), and one O(2) atom. The C(1)-H(3) bond length is 1.11 Å. The C(1)-O(1) bond length is 1.44 Å. The C(1)-O(2) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one H(4) and one O(3) atom. The C(2)-H(4) bond length is 1.10 Å. The C(2)-O(3) bond length is 1.43 Å. In the third C site, C(3) is bonded in a distorted water-like geometry to one H(5) and one O(4) atom. The C(3)-H(5) bond length is 1.11 Å. The C(3)-O(4) bond length is 1.43 Å. In the fourth C site, C(4) is bonded in a distorted water-like geometry to one H(6) and one O(5) atom. The C(4)-H(6) bond length is 1.10 Å. The C(4)-O(5) bond length is 1.46 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one H(7), one H(8), and one O(1) atom. The C(5)-H(7) bond length is 1.10 Å. The C(5)-H(8) bond length is 1.09 Å. The C(5)-O(1) bond length is 1.44 Å. In the sixth C site, C(6) is bonded to one H(10), one H(11), one H(9), and one O(2) atom to form CH3O tetrahedra that share  a cornercorner with one Na(1)O6 octahedra. The corner-sharing octahedral tilt angles are 68°. The C(6)-H(10) bond length is 1.10 Å. The C(6)-H(11) bond length is 1.10 Å. The C(6)-H(9) bond length is 1.09 Å. The C(6)-O(2) bond length is 1.45 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one H(14), one O(10), and one O(9) atom. The C(7)-H(14) bond length is 1.11 Å. The C(7)-O(10) bond length is 1.39 Å. The C(7)-O(9) bond length is 1.45 Å. In the eighth C site, C(8) is bonded in a distorted water-like geometry to one H(15) and one O(11) atom. The C(8)-H(15) bond length is 1.10 Å. The C(8)-O(11) bond length is 1.42 Å. In the ninth C site, C(9) is bonded in a distorted water-like geometry to one H(16) and one O(12) atom. The C(9)-H(16) bond length is 1.11 Å. The C(9)-O(12) bond length is 1.43 Å. In the tenth C site, C(10) is bonded in a distorted water-like geometry to one H(17) and one O(13) atom. The C(10)-H(17) bond length is 1.10 Å. The C(10)-O(13) bond length is 1.45 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one H(18), one H(19), and one O(9) atom. The C(11)-H(18) bond length is 1.11 Å. The C(11)-H(19) bond length is 1.10 Å. The C(11)-O(9) bond length is 1.44 Å. In the twelfth C site, C(12) is bonded to one H(20), one H(21), one H(22), and one O(10) atom to form CH3O tetrahedra that share  a cornercorner with one Na(2)O6 octahedra. The corner-sharing octahedral tilt angles are 69°. The C(12)-H(20) bond length is 1.09 Å. The C(12)-H(21) bond length is 1.10 Å. The C(12)-H(22) bond length is 1.10 Å. The C(12)-O(10) bond length is 1.45 Å. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. The H(1)-O(3) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) atom. The H(2)-O(4) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(11) atom. The H(12)-O(11) bond length is 0.99 Å. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one O(12) atom. The H(13)-O(12) bond length is 0.99 Å. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(7) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(8) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(9) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(10) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(11) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(11) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(12) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(12) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(12) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one O(17) atom. The H(23)-O(17) bond length is 0.99 Å. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one O(17) atom. The H(24)-O(17) bond length is 0.99 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form SO4 tetrahedra that share  a cornercorner with one Na(1)O6 octahedra and  a cornercorner with one Na(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-62°. The S(1)-O(5) bond length is 1.63 Å. The S(1)-O(6) bond length is 1.46 Å. The S(1)-O(7) bond length is 1.46 Å. The S(1)-O(8) bond length is 1.47 Å. In the second S site, S(2) is bonded to one O(13), one O(14), one O(15), and one O(16) atom to form SO4 tetrahedra that share  a cornercorner with one Na(1)O6 octahedra and  a cornercorner with one Na(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-62°. The S(2)-O(13) bond length is 1.63 Å. The S(2)-O(14) bond length is 1.46 Å. The S(2)-O(15) bond length is 1.46 Å. The S(2)-O(16) bond length is 1.47 Å. There are seventeen inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(1) and one C(5) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one C(1), and one C(6) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one C(2), and one H(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Na(1), one C(3), and one H(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(4) and one S(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Na(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Na(2) and one S(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one S(1) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one C(11) and one C(7) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Na(2), one C(12), and one C(7) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one Na(2), one C(8), and one H(12) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Na(2), one C(9), and one H(13) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one C(10) and one S(2) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Na(2) and one S(2) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one S(2) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one S(2) atom. In the seventeenth O site, O(17) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(23), and one H(24) atom. Linkers: 2 CO[C@@H]1OC[C@@H](OS([O])([O])[O])[C@H](O)[C@H]1O ,1 [O]S([O])([O])O[C@@H]1CO[CH][C@H](O)[C@H]1O ,1 CO[C@@H]1OC[C@@H](O[S@@]([O])=O)[C@H](O)[C@H]1O. Metal clusters: 2 [Na]. The MOF has largest included sphere 2.21 A, density 1.70 g/cm3, surface area 3511.52 m2/g, accessible volume 0.14 cm3/g