CdC2H8(NI)2CH2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and four CdC2H8(NI)2 clusters. In each CdC2H8(NI)2 cluster, Cd(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(2), one I(1), and one I(2) atom. The Cd(1)-N(1) bond length is 2.29 Å. The Cd(1)-N(2) bond length is 2.28 Å. The Cd(1)-I(1) bond length is 2.81 Å. The Cd(1)-I(2) bond length is 2.85 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(5), and one H(6) atom. The C(1)-N(1) bond length is 1.48 Å. The C(1)-H(5) bond length is 1.10 Å. The C(1)-H(6) bond length is 1.10 Å. In the second C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(10), and one H(9) atom. The C(3)-N(2) bond length is 1.48 Å. The C(3)-H(10) bond length is 1.10 Å. The C(3)-H(9) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Cd(1), one C(1), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.03 Å. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Cd(1), one C(3), one H(3), and one H(4) atom. The N(2)-H(3) bond length is 1.03 Å. The N(2)-H(4) bond length is 1.03 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the eighth H site, H(6) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Cd(1) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Cd(1) atom. Linkers: 4 NCCCN. Metal clusters: 4 [Cd]. The MOF has largest included sphere 1.90 A, density 3.21 g/cm3, surface area 2704.94 m2/g, accessible volume 0.06 cm3/g