La2C51H24(O2F3)6 crystallizes in the orthorhombic Pnna space group. La(1) is bonded in a 9-coordinate geometry to one O(1), one O(4), one O(5), two equivalent O(2), two equivalent O(3), and two equivalent O(6) atoms. The La(1)-O(1) bond length is 2.49 Å. The La(1)-O(4) bond length is 2.48 Å. The La(1)-O(5) bond length is 2.54 Å. There is one shorter (2.49 Å) and one longer (2.64 Å) La(1)-O(2) bond length. There is one shorter (2.47 Å) and one longer (2.74 Å) La(1)-O(3) bond length. There is one shorter (2.45 Å) and one longer (2.71 Å) La(1)-O(6) bond length. There are twenty-six inequivalent C sites. In the first C site, C(4) is bonded in a distorted trigonal planar geometry to one C(2), one C(5), and one H(2) atom. The C(4)-C(2) bond length is 1.40 Å. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2) bond length is 1.09 Å. In the second C site, C(20) is bonded in a tetrahedral geometry to two equivalent C(18) and two equivalent C(25) atoms. Both C(20)-C(18) bond lengths are 1.54 Å. Both C(20)-C(25) bond lengths are 1.56 Å. In the third C site, C(21) is bonded in a bent 120 degrees geometry to one C(11), one O(3), and one O(4) atom. The C(21)-C(11) bond length is 1.48 Å. The C(21)-O(3) bond length is 1.30 Å. The C(21)-O(4) bond length is 1.27 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(3) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(3) bond length is 1.09 Å. In the fifth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(15), one C(19), and one H(11) atom. The C(22)-C(15) bond length is 1.40 Å. The C(22)-C(19) bond length is 1.39 Å. The C(22)-H(11) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(23), one C(26), and one C(5) atom. The C(6)-C(23) bond length is 1.41 Å. The C(6)-C(26) bond length is 1.54 Å. In the seventh C site, C(23) is bonded in a distorted single-bond geometry to one C(3), one C(6), and one H(12) atom. The C(23)-C(3) bond length is 1.39 Å. The C(23)-H(12) bond length is 1.09 Å. In the eighth C site, C(7) is bonded in a trigonal non-coplanar geometry to one C(26); one F(6); and two equivalent F(3,4,5) atoms. The C(7)-C(26) bond length is 1.57 Å. The C(7)-F(6) bond length is 1.36 Å. There is one shorter (1.36 Å) and one longer (1.37 Å) C(7)-F(3,4,5) bond length. In the ninth C site, C(24) is bonded in a trigonal non-coplanar geometry to one C(26); one F(1); one F(2); and one F(3,4,5) atom. The C(24)-C(26) bond length is 1.56 Å. The C(24)-F(1) bond length is 1.37 Å. The C(24)-F(2) bond length is 1.36 Å. The C(24)-F(3,4,5) bond length is 1.36 Å. In the tenth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(26), and one C(9) atom. The C(8)-C(13) bond length is 1.41 Å. The C(8)-C(26) bond length is 1.54 Å. The C(8)-C(9) bond length is 1.40 Å. In the eleventh C site, C(25) is bonded in a trigonal non-coplanar geometry to one C(20), one F(7), one F(8), and one F(9) atom. The C(25)-F(7) bond length is 1.36 Å. The C(25)-F(8) bond length is 1.36 Å. The C(25)-F(9) bond length is 1.36 Å. In the twelfth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(4) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(4) bond length is 1.09 Å. In the thirteenth C site, C(26) is bonded in a tetrahedral geometry to one C(24), one C(6), one C(7), and one C(8) atom. In the fourteenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(5) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(5) bond length is 1.09 Å. In the fifteenth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(21) atom. The C(11)-C(12) bond length is 1.40 Å. In the sixteenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(6) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(6) bond length is 1.09 Å. In the seventeenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(7) atom. The C(13)-H(7) bond length is 1.09 Å. In the eighteenth C site, C(14) is bonded in a bent 120 degrees geometry to one C(15), one O(2), and one O(5) atom. The C(14)-C(15) bond length is 1.48 Å. The C(14)-O(2) bond length is 1.30 Å. The C(14)-O(5) bond length is 1.26 Å. In the nineteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(22) atom. The C(15)-C(16) bond length is 1.40 Å. In the twentieth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(8) atom. The C(16)-H(8) bond length is 1.09 Å. In the twenty-first C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(22), and one H(10) atom. The C(19)-C(18) bond length is 1.41 Å. The C(19)-H(10) bond length is 1.09 Å. In the twenty-second C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(6) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(6) bond length is 1.30 Å. In the twenty-third C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(9) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(9) bond length is 1.09 Å. In the twenty-fourth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.40 Å. In the twenty-fifth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(20) atom. In the twenty-sixth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(23), and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(23) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one La(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent La(1) and one C(14) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to two equivalent La(1) and one C(21) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one La(1) and one C(21) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one La(1) and one C(14) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to two equivalent La(1) and one C(1) atom. There are seven inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one C(7) atom. In the second F site, F(7) is bonded in a single-bond geometry to one C(25) atom. In the third F site, F(8) is bonded in a single-bond geometry to one C(25) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one C(25) atom. In the fifth F site, F(1) is bonded in a single-bond geometry to one C(24) atom. In the sixth F site, F(2) is bonded in a single-bond geometry to one C(24) atom. In the seventh F site, F(3,4,5) is bonded in a single-bond geometry to one C(7) atom. Linkers: 12 [O]C(=O)c1ccc(C(c2ccc(C([O])=O)cc2)(C(F)(F)F)C(F)(F)F)cc1. Metal clusters: 8 [La]. The MOF has largest included sphere 5.37 A, density 1.59 g/cm3, surface area 3549.64 m2/g, accessible volume 0.13 cm3/g