CoC7H7(NO2)2(CH)8CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two p-xylene molecules, and one CoC7H7(NO2)2 cluster. In the CoC7H7(NO2)2 cluster, Co(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Co(1)-N(1) bond length is 2.19 Å. The Co(1)-O(1) bond length is 1.95 Å. The Co(1)-O(2) bond length is 1.95 Å. The Co(1)-O(3) bond length is 1.96 Å. The Co(1)-O(4) bond length is 1.98 Å. There are seven inequivalent C sites. In the first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(3)-O(2) bond length is 1.28 Å. The C(3)-O(3) bond length is 1.28 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(1), and one H(3) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-N(1) bond length is 1.38 Å. The C(4)-H(3) bond length is 1.08 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(4) atom. The C(5)-N(2) bond length is 1.38 Å. The C(5)-H(4) bond length is 1.08 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(6)-O(1) bond length is 1.28 Å. The C(6)-O(4) bond length is 1.28 Å. In the fifth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14), one N(1), and one N(2) atom. The C(12)-C(14) bond length is 1.49 Å. The C(12)-N(1) bond length is 1.34 Å. The C(12)-N(2) bond length is 1.37 Å. In the sixth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(10), and one H(11) atom. The C(13)-N(2) bond length is 1.46 Å. The C(13)-H(10) bond length is 1.10 Å. The C(13)-H(11) bond length is 1.10 Å. In the seventh C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one C(12), one H(12), one H(13), and one H(14) atom. The C(14)-H(12) bond length is 1.09 Å. The C(14)-H(13) bond length is 1.10 Å. The C(14)-H(14) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Co(1), one C(12), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(5) atom. There are seven inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(14) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(6) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one C(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one C(6) atom. Linkers: 2 [O]C(=O)Cc1ccc(CC([O])=O)cc1 ,1 Cc1nccn1CCCCn1ccnc1C. Metal clusters: 1 [C]1O[Co]234O[C]O[Co]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 2.46 A, density 1.51 g/cm3, surface area 4515.65 m2/g, accessible volume 0.19 cm3/g