CdC18N3H23O5CH2(CH)4 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two 02329_fluka molecules, and two CdC18N3H23O5 clusters. In one of the CdC18N3H23O5 clusters, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.37 Å. The Cd(1)-N(2) bond length is 2.37 Å. The Cd(1)-O(1) bond length is 2.48 Å. The Cd(1)-O(2) bond length is 2.25 Å. The Cd(1)-O(3) bond length is 2.38 Å. The Cd(1)-O(4) bond length is 2.52 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one C(2), one C(4), one C(6), and one C(9) atom. The C(1)-C(2) bond length is 1.59 Å. The C(1)-C(4) bond length is 1.54 Å. The C(1)-C(6) bond length is 1.53 Å. The C(1)-C(9) bond length is 1.54 Å. In the second C site, C(2) is bonded in a tetrahedral geometry to one C(1), one C(3), one C(7), and one C(8) atom. The C(2)-C(3) bond length is 1.57 Å. The C(2)-C(7) bond length is 1.54 Å. The C(2)-C(8) bond length is 1.53 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted water-like geometry to one C(1), one H(2), and one H(3) atom. The C(4)-H(2) bond length is 1.10 Å. The C(4)-H(3) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a trigonal non-coplanar geometry to one C(1), one H(6), one H(7), and one H(8) atom. The C(6)-H(6) bond length is 1.10 Å. The C(6)-H(7) bond length is 1.10 Å. The C(6)-H(8) bond length is 1.10 Å. In the sixth C site, C(7) is bonded in a trigonal non-coplanar geometry to one C(2), one H(10), one H(11), and one H(9) atom. The C(7)-H(10) bond length is 1.10 Å. The C(7)-H(11) bond length is 1.10 Å. The C(7)-H(9) bond length is 1.10 Å. In the seventh C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(2), one H(12), one H(13), and one H(14) atom. The C(8)-H(12) bond length is 1.10 Å. The C(8)-H(13) bond length is 1.10 Å. The C(8)-H(14) bond length is 1.10 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(2), and one O(5) atom. The C(9)-O(2) bond length is 1.29 Å. The C(9)-O(5) bond length is 1.26 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(10)-O(3) bond length is 1.28 Å. The C(10)-O(4) bond length is 1.27 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(16), and one N(1) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(16) bond length is 1.49 Å. The C(11)-N(1) bond length is 1.35 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(15) atom. The C(12)-H(15) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(18) atom. The C(15)-N(1) bond length is 1.34 Å. The C(15)-H(18) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(11), one C(17), and one N(2) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-N(2) bond length is 1.35 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(19) atom. The C(17)-H(19) bond length is 1.09 Å. In the fifteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one N(2) and one H(22) atom. The C(20)-N(2) bond length is 1.34 Å. The C(20)-H(22) bond length is 1.09 Å. In the sixteenth C site, C(21) is bonded to one N(3), one H(23), one H(24), and one H(25) atom to form corner-sharing CH3N tetrahedra. The C(21)-N(3) bond length is 1.45 Å. The C(21)-H(23) bond length is 1.09 Å. The C(21)-H(24) bond length is 1.10 Å. The C(21)-H(25) bond length is 1.10 Å. In the seventeenth C site, C(22) is bonded in a trigonal planar geometry to one N(3), one H(26), and one O(1) atom. The C(22)-N(3) bond length is 1.34 Å. The C(22)-H(26) bond length is 1.10 Å. The C(22)-O(1) bond length is 1.25 Å. In the eighteenth C site, C(23) is bonded to one N(3), one H(27), one H(28), and one H(29) atom to form corner-sharing CH3N tetrahedra. The C(23)-N(3) bond length is 1.45 Å. The C(23)-H(27) bond length is 1.09 Å. The C(23)-H(28) bond length is 1.10 Å. The C(23)-H(29) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(15) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(16), and one C(20) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(21), one C(22), and one C(23) atom. There are twenty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(8) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(8) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(12) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(15) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the sixteenth H site, H(22) is bonded in a single-bond geometry to one C(20) atom. In the seventeenth H site, H(23) is bonded in a single-bond geometry to one C(21) atom. In the eighteenth H site, H(24) is bonded in a single-bond geometry to one C(21) atom. In the nineteenth H site, H(25) is bonded in a single-bond geometry to one C(21) atom. In the twentieth H site, H(26) is bonded in a single-bond geometry to one C(22) atom. In the twenty-first H site, H(27) is bonded in a single-bond geometry to one C(23) atom. In the twenty-second H site, H(28) is bonded in a single-bond geometry to one C(23) atom. In the twenty-third H site, H(29) is bonded in a single-bond geometry to one C(23) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(22) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1) and one C(9) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(10) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cd(1) and one C(10) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(9) atom. In one of the CdC18N3H23O5 clusters, Cd(2) is bonded in a 6-coordinate geometry to one N(4), one N(5), one O(10), one O(6), one O(8), and one O(9) atom. The Cd(2)-N(4) bond length is 2.36 Å. The Cd(2)-N(5) bond length is 2.36 Å. The Cd(2)-O(10) bond length is 2.35 Å. The Cd(2)-O(6) bond length is 2.45 Å. The Cd(2)-O(8) bond length is 2.21 Å. The Cd(2)-O(9) bond length is 2.55 Å. There are eighteen inequivalent C sites. In the first C site, C(24) is bonded in a distorted trigonal planar geometry to one C(25), one C(29), and one N(4) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-C(29) bond length is 1.49 Å. The C(24)-N(4) bond length is 1.35 Å. In the second C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(30) atom. The C(25)-H(30) bond length is 1.09 Å. In the third C site, C(28) is bonded in a distorted trigonal planar geometry to one N(4) and one H(33) atom. The C(28)-N(4) bond length is 1.34 Å. The C(28)-H(33) bond length is 1.09 Å. In the fourth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(24), one C(30), and one N(5) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-N(5) bond length is 1.35 Å. In the fifth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(34) atom. The C(30)-H(34) bond length is 1.09 Å. In the sixth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(37) atom. The C(33)-N(5) bond length is 1.34 Å. The C(33)-H(37) bond length is 1.09 Å. In the seventh C site, C(34) is bonded in a tetrahedral geometry to one C(35), one C(38), one C(39), and one C(42) atom. The C(34)-C(35) bond length is 1.58 Å. The C(34)-C(38) bond length is 1.54 Å. The C(34)-C(39) bond length is 1.54 Å. The C(34)-C(42) bond length is 1.54 Å. In the eighth C site, C(35) is bonded in a tetrahedral geometry to one C(34), one C(36), one C(40), and one C(41) atom. The C(35)-C(36) bond length is 1.57 Å. The C(35)-C(40) bond length is 1.53 Å. The C(35)-C(41) bond length is 1.54 Å. In the ninth C site, C(36) is bonded in a single-bond geometry to one C(35) and one H(38) atom. The C(36)-H(38) bond length is 1.10 Å. In the tenth C site, C(38) is bonded in a distorted water-like geometry to one C(34), one H(41), and one H(42) atom. The C(38)-H(41) bond length is 1.10 Å. The C(38)-H(42) bond length is 1.10 Å. In the eleventh C site, C(39) is bonded in a trigonal non-coplanar geometry to one C(34), one H(43), one H(44), and one H(45) atom. The C(39)-H(43) bond length is 1.09 Å. The C(39)-H(44) bond length is 1.10 Å. The C(39)-H(45) bond length is 1.10 Å. In the twelfth C site, C(40) is bonded in a trigonal non-coplanar geometry to one C(35), one H(46), one H(47), and one H(48) atom. The C(40)-H(46) bond length is 1.10 Å. The C(40)-H(47) bond length is 1.10 Å. The C(40)-H(48) bond length is 1.10 Å. In the thirteenth C site, C(41) is bonded in a trigonal non-coplanar geometry to one C(35), one H(49), one H(50), and one H(51) atom. The C(41)-H(49) bond length is 1.10 Å. The C(41)-H(50) bond length is 1.10 Å. The C(41)-H(51) bond length is 1.10 Å. In the fourteenth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(34), one O(10), and one O(9) atom. The C(42)-O(10) bond length is 1.29 Å. The C(42)-O(9) bond length is 1.27 Å. In the fifteenth C site, C(43) is bonded to one N(6), one H(52), one H(53), and one H(54) atom to form corner-sharing CH3N tetrahedra. The C(43)-N(6) bond length is 1.45 Å. The C(43)-H(52) bond length is 1.10 Å. The C(43)-H(53) bond length is 1.10 Å. The C(43)-H(54) bond length is 1.10 Å. In the sixteenth C site, C(44) is bonded to one N(6), one H(55), one H(56), and one H(57) atom to form corner-sharing CH3N tetrahedra. The C(44)-N(6) bond length is 1.45 Å. The C(44)-H(55) bond length is 1.09 Å. The C(44)-H(56) bond length is 1.10 Å. The C(44)-H(57) bond length is 1.10 Å. In the seventeenth C site, C(45) is bonded in a trigonal planar geometry to one N(6), one H(58), and one O(6) atom. The C(45)-N(6) bond length is 1.34 Å. The C(45)-H(58) bond length is 1.10 Å. The C(45)-O(6) bond length is 1.25 Å. In the eighteenth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(46)-O(7) bond length is 1.26 Å. The C(46)-O(8) bond length is 1.29 Å. There are three inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Cd(2), one C(24), and one C(28) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Cd(2), one C(29), and one C(33) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one C(43), one C(44), and one C(45) atom. There are twenty-three inequivalent H sites. In the first H site, H(30) is bonded in a single-bond geometry to one C(25) atom. In the second H site, H(33) is bonded in a single-bond geometry to one C(28) atom. In the third H site, H(34) is bonded in a single-bond geometry to one C(30) atom. In the fourth H site, H(37) is bonded in a single-bond geometry to one C(33) atom. In the fifth H site, H(38) is bonded in a single-bond geometry to one C(36) atom. In the sixth H site, H(41) is bonded in a single-bond geometry to one C(38) atom. In the seventh H site, H(42) is bonded in a single-bond geometry to one C(38) atom. In the eighth H site, H(43) is bonded in a single-bond geometry to one C(39) atom. In the ninth H site, H(44) is bonded in a single-bond geometry to one C(39) atom. In the tenth H site, H(45) is bonded in a single-bond geometry to one C(39) atom. In the eleventh H site, H(46) is bonded in a single-bond geometry to one C(40) atom. In the twelfth H site, H(47) is bonded in a single-bond geometry to one C(40) atom. In the thirteenth H site, H(48) is bonded in a single-bond geometry to one C(40) atom. In the fourteenth H site, H(49) is bonded in a single-bond geometry to one C(41) atom. In the fifteenth H site, H(50) is bonded in a single-bond geometry to one C(41) atom. In the sixteenth H site, H(51) is bonded in a single-bond geometry to one C(41) atom. In the seventeenth H site, H(52) is bonded in a single-bond geometry to one C(43) atom. In the eighteenth H site, H(53) is bonded in a single-bond geometry to one C(43) atom. In the nineteenth H site, H(54) is bonded in a single-bond geometry to one C(43) atom. In the twentieth H site, H(55) is bonded in a single-bond geometry to one C(44) atom. In the twenty-first H site, H(56) is bonded in a single-bond geometry to one C(44) atom. In the twenty-second H site, H(57) is bonded in a single-bond geometry to one C(44) atom. In the twenty-third H site, H(58) is bonded in a single-bond geometry to one C(45) atom. There are five inequivalent O sites. In the first O site, O(6) is bonded in a distorted single-bond geometry to one Cd(2) and one C(45) atom. In the second O site, O(7) is bonded in a single-bond geometry to one C(46) atom. In the third O site, O(8) is bonded in a bent 120 degrees geometry to one Cd(2) and one C(46) atom. In the fourth O site, O(9) is bonded in a single-bond geometry to one Cd(2) and one C(42) atom. In the fifth O site, O(10) is bonded in a distorted single-bond geometry to one Cd(2) and one C(42) atom. Linkers: 2 CC1(C)[C@@H](C([O])=O)CC[C@@]1(C)C([O])=O ,1 c1ccc(-c2ccccn2)nc1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 2.17 A, density 1.62 g/cm3, surface area 4617.75 m2/g, accessible volume 0.11 cm3/g