(CuC11N4H15Cl)2CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and two CuC11N4H15Cl clusters. In each CuC11N4H15Cl cluster, Cu(1) is bonded to one N(1), one N(5), and two equivalent Cl(1) atoms to form edge-sharing CuN2Cl2 tetrahedra. The Cu(1)-N(1) bond length is 2.02 Å. The Cu(1)-N(5) bond length is 2.07 Å. There is one shorter (2.30 Å) and one longer (2.39 Å) Cu(1)-Cl(1) bond length. There are eleven inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal non-coplanar geometry to one C(3); one H(1,2); one H(3,4); and one H(5,6) atom. The C(1,2)-C(3) bond length is 1.48 Å. The C(1,2)-H(1,2) bond length is 1.09 Å. The C(1,2)-H(3,4) bond length is 1.10 Å. The C(1,2)-H(5,6) bond length is 1.10 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(1,2); one C(5,6); and one N(7) atom. The C(3)-C(5,6) bond length is 1.39 Å. The C(3)-N(7) bond length is 1.37 Å. In the third C site, C(5,6) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(7) atom. The C(5,6)-C(7) bond length is 1.41 Å. The C(5,6)-H(7) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5,6); one C(9,10); and one N(5) atom. The C(7)-C(9,10) bond length is 1.49 Å. The C(7)-N(5) bond length is 1.35 Å. In the fifth C site, C(9,10) is bonded in a distorted trigonal non-coplanar geometry to one C(7), one H(11), one H(13), and one H(9) atom. The C(9,10)-H(11) bond length is 1.10 Å. The C(9,10)-H(13) bond length is 1.10 Å. The C(9,10)-H(9) bond length is 1.10 Å. In the sixth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one C(13); one H(15,16); one H(17,18); and one H(19,20) atom. The C(11)-C(13) bond length is 1.49 Å. The C(11)-H(15,16) bond length is 1.10 Å. The C(11)-H(17,18) bond length is 1.10 Å. The C(11)-H(19,20) bond length is 1.10 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(11), one C(15), and one N(3) atom. The C(13)-C(15) bond length is 1.39 Å. The C(13)-N(3) bond length is 1.37 Å. In the eighth C site, C(15) is bonded in a distorted single-bond geometry to one C(13); one C(17); and one H(21,22) atom. The C(15)-C(17) bond length is 1.41 Å. The C(15)-H(21,22) bond length is 1.08 Å. In the ninth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(15), one C(19), and one N(1) atom. The C(17)-C(19) bond length is 1.49 Å. The C(17)-N(1) bond length is 1.35 Å. In the tenth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one C(17); one H(23,24); one H(25,26); and one H(27,28) atom. The C(19)-H(23,24) bond length is 1.10 Å. The C(19)-H(25,26) bond length is 1.10 Å. The C(19)-H(27,28) bond length is 1.10 Å. In the eleventh C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one N(3); one N(7); and one H(29,30) atom. The C(21)-N(3) bond length is 1.46 Å. The C(21)-N(7) bond length is 1.45 Å. The C(21)-H(29,30) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(17), and one N(3) atom. The N(1)-N(3) bond length is 1.36 Å. In the second N site, N(3) is bonded in a distorted trigonal planar geometry to one C(13), one C(21), and one N(1) atom. In the third N site, N(5) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one C(7), and one N(7) atom. The N(5)-N(7) bond length is 1.37 Å. In the fourth N site, N(7) is bonded in a distorted trigonal planar geometry to one C(21), one C(3), and one N(5) atom. There are fifteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(1,2) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(1,2) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(5,6) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(9,10) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(9,10) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(9,10) atom. In the eighth H site, H(15,16) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(17,18) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(19,20) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(21,22) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(23,24) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(25,26) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(27,28) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(29,30) is bonded in a single-bond geometry to one C(21) atom. Cl(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 2 Cc1cc(C)n(C(CC(n2nc(C)cc2C)n2nc(C)cc2C)n2nc(C)cc2C)n1. Metal clusters: 2 Cl[Cu][Cu]Cl. The MOF has largest included sphere 4.45 A, density 1.38 g/cm3, surface area 4886.37 m2/g, accessible volume 0.24 cm3/g