CuC16N2H8S2(ClF2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CuC16N2H8S2(ClF2)2 cluster. Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent Cl(1) atoms. Both Cu(1)-N(1) bond lengths are 2.00 Å. Both Cu(1)-Cl(1) bond lengths are 2.26 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one S(1) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-S(1) bond length is 1.77 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(7), one C(8), and one S(1) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-C(8) bond length is 1.40 Å. The C(6)-S(1) bond length is 1.76 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one F(1,2) atom. The C(7)-F(1,2) bond length is 1.35 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one F(1,2) atom. The C(8)-F(1,2) bond length is 1.34 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. S(1) is bonded in a water-like geometry to one C(5) and one C(6) atom. Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. F(1,2) is bonded in a single-bond geometry to one C(7) atom. Linkers: 1 Fc1c(F)c(Sc2ccccn2)c(F)c(F)c1Sc1ccccn1. Metal clusters: 1 Cl[Cu]Cl. The MOF has largest included sphere 3.91 A, density 1.47 g/cm3, surface area 4088.59 m2/g, accessible volume 0.25 cm3/g