ZnC5H4(NO2)2(CH2)4(CH)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, thirty-two 02329_fluka molecules, and four ZnC5H4(NO2)2 clusters. In each ZnC5H4(NO2)2 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 2.06 Å. The Zn(1)-O(2) bond length is 2.08 Å. The Zn(1)-O(3) bond length is 2.12 Å. The Zn(1)-O(4) bond length is 2.04 Å. There are five inequivalent C sites. In the first C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(2)-O(1) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.27 Å. In the second C site, C(8) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(10) atom. The C(8)-N(1) bond length is 1.33 Å. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(10) bond length is 1.08 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(1)-O(2) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.28 Å. In the fourth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(10)-N(2) bond length is 1.38 Å. The C(10)-H(12) bond length is 1.08 Å. In the fifth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(11) atom. The C(9)-N(1) bond length is 1.38 Å. The C(9)-H(11) bond length is 1.08 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(8), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(8), and one H(9) atom. The N(2)-H(9) bond length is 1.04 Å. There are four inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. Linkers: 4 [O]C(=O)[C@H]1CC[C@@H](C([O])=O)CC1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 2.73 A, density 1.63 g/cm3, surface area 4553.99 m2/g, accessible volume 0.18 cm3/g