CuC11N4H9ICuC13N4H11I(CH)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, one CuC11N4H9I cluster, and one CuC13N4H11I cluster. In the CuC11N4H9I cluster, Cu(1) is bonded in a distorted water-like geometry to one N(1), one N(3), and two equivalent I(1) atoms. The Cu(1)-N(1) bond length is 2.05 Å. The Cu(1)-N(3) bond length is 2.02 Å. There is one shorter (2.61 Å) and one longer (2.67 Å) Cu(1)-I(1) bond length. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2,15) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2,15) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(6) bond length is 1.50 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one N(2), one H(5), and one H(6) atom. The C(6)-N(2) bond length is 1.45 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(2), and one H(7) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-N(2) bond length is 1.35 Å. The C(7)-H(7) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(4) atom. The C(8)-C(9) bond length is 1.46 Å. The C(8)-N(4) bond length is 1.37 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.40 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(8,12) atom. The C(10)-H(8,12) bond length is 1.09 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(8,12) atom. The C(14)-H(8,12) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one N(3) atom. The N(2)-N(3) bond length is 1.37 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one N(2), and one N(4) atom. The N(3)-N(4) bond length is 1.31 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one C(8) and one N(3) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2,15) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8,12) is bonded in a single-bond geometry to one C(10) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. In the CuC13N4H11I cluster, Cu(2) is bonded in a distorted water-like geometry to one N(5), one N(7), and two equivalent I(2) atoms. The Cu(2)-N(5) bond length is 2.04 Å. The Cu(2)-N(7) bond length is 2.03 Å. There is one shorter (2.62 Å) and one longer (2.64 Å) Cu(2)-I(2) bond length. There are thirteen inequivalent C sites. In the first C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(13,16) atom. The C(15)-N(5) bond length is 1.35 Å. The C(15)-H(13,16) bond length is 1.09 Å. In the second C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(14) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(14) bond length is 1.09 Å. In the third C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(20) bond length is 1.51 Å. In the fourth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(2,15) atom. The C(18)-H(2,15) bond length is 1.09 Å. In the fifth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(13,16) atom. The C(19)-N(5) bond length is 1.35 Å. The C(19)-H(13,16) bond length is 1.09 Å. In the sixth C site, C(20) is bonded in a distorted trigonal non-coplanar geometry to one C(17), one N(6), one H(17), and one H(18) atom. The C(20)-N(6) bond length is 1.45 Å. The C(20)-H(17) bond length is 1.10 Å. The C(20)-H(18) bond length is 1.10 Å. In the seventh C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(6), and one H(19) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-N(6) bond length is 1.35 Å. The C(21)-H(19) bond length is 1.09 Å. In the eighth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one N(8) atom. The C(22)-C(23) bond length is 1.46 Å. The C(22)-N(8) bond length is 1.37 Å. In the ninth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.41 Å. The C(23)-C(28) bond length is 1.40 Å. In the tenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(20) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(20) bond length is 1.09 Å. In the eleventh C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one C(26), and one H(21) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-H(21) bond length is 1.09 Å. In the twelfth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(22) atom. The C(26)-H(22) bond length is 1.09 Å. In the thirteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(23) and one H(24) atom. The C(28)-H(24) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one Cu(2), one C(15), and one C(19) atom. In the second N site, N(6) is bonded in a distorted trigonal planar geometry to one C(20), one C(21), and one N(7) atom. The N(6)-N(7) bond length is 1.37 Å. In the third N site, N(7) is bonded in a trigonal planar geometry to one Cu(2), one N(6), and one N(8) atom. The N(7)-N(8) bond length is 1.32 Å. In the fourth N site, N(8) is bonded in a distorted water-like geometry to one C(22) and one N(7) atom. There are ten inequivalent H sites. In the first H site, H(2,15) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(13,16) is bonded in a single-bond geometry to one C(15) atom. In the third H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(20) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one C(20) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(21) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(22) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(24) is bonded in a single-bond geometry to one C(28) atom. I(2) is bonded in a 2-coordinate geometry to two equivalent Cu(2) atoms. Linkers: 4 c1ccc(-c2cn(Cc3ccncc3)nn2)cc1. Metal clusters: 2 I[Cu][Cu]I. The MOF has largest included sphere 4.58 A, density 1.78 g/cm3, surface area 3717.89 m2/g, accessible volume 0.16 cm3/g