CuC28N10H20(O3F4)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CuC28N10H20(O3F4)2 clusters. Cu(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(6), and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 1.99 Å. Both Cu(1)-N(6) bond lengths are 2.01 Å. Both Cu(1)-O(1) bond lengths are 2.54 Å. There are fourteen inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal non-coplanar geometry to one C(13,14); one N(7,8); one H(1,2); and one H(3,4) atom. The C(1,2)-C(13,14) bond length is 1.50 Å. The C(1,2)-N(7,8) bond length is 1.47 Å. The C(1,2)-H(1,2) bond length is 1.10 Å. The C(1,2)-H(3,4) bond length is 1.10 Å. In the second C site, C(3,4) is bonded in a distorted single-bond geometry to one C(13,14) and one F(3,4) atom. The C(3,4)-C(13,14) bond length is 1.40 Å. The C(3,4)-F(3,4) bond length is 1.35 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(7,8) and one F(1,2) atom. The C(5)-C(7,8) bond length is 1.40 Å. The C(5)-F(1,2) bond length is 1.36 Å. In the fourth C site, C(7,8) is bonded in a trigonal planar geometry to one C(15), one C(5), and one C(9) atom. The C(7,8)-C(15) bond length is 1.50 Å. The C(7,8)-C(9) bond length is 1.40 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(7,8) and one F(7,8) atom. The C(9)-F(7,8) bond length is 1.35 Å. In the sixth C site, C(11,12) is bonded in a distorted single-bond geometry to one C(13,14) and one F(5,6) atom. The C(11,12)-C(13,14) bond length is 1.39 Å. The C(11,12)-F(5,6) bond length is 1.35 Å. In the seventh C site, C(13,14) is bonded in a trigonal planar geometry to one C(1,2); one C(11,12); and one C(3,4) atom. In the eighth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one C(7,8); one N(3); one H(5,6); and one H(7,8) atom. The C(15)-N(3) bond length is 1.47 Å. The C(15)-H(5,6) bond length is 1.10 Å. The C(15)-H(7,8) bond length is 1.10 Å. In the ninth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(3), and one H(9) atom. The C(17)-C(19) bond length is 1.37 Å. The C(17)-N(3) bond length is 1.38 Å. The C(17)-H(9) bond length is 1.08 Å. In the tenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(1), and one H(11) atom. The C(19)-N(1) bond length is 1.38 Å. The C(19)-H(11) bond length is 1.08 Å. In the eleventh C site, C(21) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(13) atom. The C(21)-N(1) bond length is 1.33 Å. The C(21)-N(3) bond length is 1.36 Å. The C(21)-H(13) bond length is 1.09 Å. In the twelfth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(15,16) atom. The C(24)-N(6) bond length is 1.38 Å. The C(24)-H(15,16) bond length is 1.08 Å. In the thirteenth C site, C(25,26) is bonded in a distorted bent 120 degrees geometry to one N(7,8) and one H(17,18) atom. The C(25,26)-N(7,8) bond length is 1.38 Å. The C(25,26)-H(17,18) bond length is 1.09 Å. In the fourteenth C site, C(28) is bonded in a trigonal planar geometry to one N(6); one N(7,8); and one H(19,20) atom. The C(28)-N(6) bond length is 1.33 Å. The C(28)-N(7,8) bond length is 1.36 Å. The C(28)-H(19,20) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(19), and one C(21) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(24), and one C(28) atom. In the fourth N site, N(7,8) is bonded in a trigonal planar geometry to one C(1,2); one C(25,26); and one C(27) atom. The N(7,8)-C(27) bond length is 1.36 Å. In the fifth N site, N(9) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(5) atom. The N(9)-O(1) bond length is 1.28 Å. The N(9)-O(3) bond length is 1.27 Å. The N(9)-O(5) bond length is 1.27 Å. There are ten inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(1,2) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(15,16) is bonded in a single-bond geometry to one C(23) atom. The H(15,16)-C(23) bond length is 1.08 Å. In the ninth H site, H(17,18) is bonded in a single-bond geometry to one C(25,26) atom. In the tenth H site, H(19,20) is bonded in a single-bond geometry to one C(27) atom. The H(19,20)-C(27) bond length is 1.09 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cu(1) and one N(9) atom. In the second O site, O(3) is bonded in a single-bond geometry to one N(9) atom. In the third O site, O(5) is bonded in a single-bond geometry to one N(9) atom. There are four inequivalent F sites. In the first F site, F(1,2) is bonded in a single-bond geometry to one C(5) atom. In the second F site, F(3,4) is bonded in a single-bond geometry to one C(3,4) atom. In the third F site, F(5,6) is bonded in a single-bond geometry to one C(11,12) atom. In the fourth F site, F(7,8) is bonded in a single-bond geometry to one C(9) atom. Linkers: 4 Fc1c(F)c(Cn2ccnc2)c(F)c(F)c1Cn1ccnc1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.18 A, density 1.75 g/cm3, surface area 4329.89 m2/g, accessible volume 0.15 cm3/g