CuC9H5(NO2)2(CH)3(CF2)2 crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules, thirty-two difluoromethane molecules, and eight CuC9H5(NO2)2 clusters. In each CuC9H5(NO2)2 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one N(2), one O(1), one O(3), and one O(4) atom. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-N(2) bond length is 1.98 Å. The Cu(1)-O(1) bond length is 1.96 Å. The Cu(1)-O(3) bond length is 1.98 Å. The Cu(1)-O(4) bond length is 2.33 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(2) and one H(1) atom. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(2) atom. The C(5)-C(6) bond length is 1.47 Å. The C(5)-N(2) bond length is 1.36 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(1) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-N(1) bond length is 1.36 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(7) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(8) atom. The C(10)-N(1) bond length is 1.34 Å. The C(10)-H(8) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(11)-O(1) bond length is 1.29 Å. The C(11)-O(2) bond length is 1.24 Å. In the ninth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(14)-O(3) bond length is 1.28 Å. The C(14)-O(4) bond length is 1.24 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(11) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(11) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(14) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(14) atom. Linkers: 4 [O]C(=O)C(F)(F)C(F)(F)C([O])=O. Metal clusters: 2 O=[C]O[Cu]1O[C]O[Cu](O[C]=O)O[C]O1. RCSR code: dia. The MOF has largest included sphere 2.87 A, density 1.90 g/cm3, surface area 3935.71 m2/g, accessible volume 0.09 cm3/g