(CH2)2NiC18N4H14(OF)4 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two NiC18N4H14(OF)4 clusters. In each NiC18N4H14(OF)4 cluster, Ni(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Ni(1)-N(1) bond lengths are 1.87 Å. Both Ni(1)-O(1) bond lengths are 1.90 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one H(1), one H(2), and one H(3) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one N(2) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-N(2) bond length is 1.36 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(4) atom. The C(3)-C(4) bond length is 1.37 Å. The C(3)-N(1) bond length is 1.38 Å. The C(3)-H(4) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(5) atom. The C(4)-N(2) bond length is 1.38 Å. The C(4)-H(5) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(6), and one H(7) atom. The C(5)-N(2) bond length is 1.46 Å. The C(5)-H(6) bond length is 1.09 Å. The C(5)-H(7) bond length is 1.10 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(1), and one O(2) atom. The C(7)-C(8) bond length is 1.51 Å. The C(7)-O(1) bond length is 1.29 Å. The C(7)-O(2) bond length is 1.25 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one F(1) atom. The C(9)-F(1) bond length is 1.36 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one F(2) atom. The C(10)-F(2) bond length is 1.36 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(5) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ni(1) and one C(7) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(9) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(10) atom. Linkers: 2 Cc1nccn1CCCCn1ccnc1C ,2 [O]C(=O)c1c(F)c(F)c(C([O])=O)c(F)c1F. Metal clusters: 2 O=[C]O[Ni]O[C]=O. The MOF has largest included sphere 2.65 A, density 1.63 g/cm3, surface area 4315.57 m2/g, accessible volume 0.13 cm3/g