(CH3)2(CH)3(CuC8N5H7IF)2CFC6H3OF2C4H2OF is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of three 02329_fluka molecules, two 02329_fluka molecules, one 3-fluoro-2-methylprop-2-en-1-ol molecule, one fluoromethane molecule, one C6H3OF2 cluster, and one CuC8N5H7IF cluster. In the C6H3OF2 cluster, there are six inequivalent C sites. In the first C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one O(1) atom. The C(7)-C(8) bond length is 1.53 Å. The C(7)-O(1) bond length is 1.42 Å. In the second C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(7), and one C(9) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the third C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one F(2) atom. The C(9)-F(2) bond length is 1.37 Å. In the fourth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one F(3) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-F(3) bond length is 1.37 Å. In the fifth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(9) atom. The C(13)-C(12) bond length is 1.39 Å. The C(13)-H(9) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. There are three inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(27) is bonded in a single-bond geometry to one O(1) atom. The H(27)-O(1) bond length is 1.00 Å. O(1) is bonded in a water-like geometry to one C(7) and one H(27) atom. There are two inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one C(11) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(9) atom. In the CuC8N5H7IF cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 2-coordinate geometry to one N(4), one N(8), one I(1), and one I(2) atom. The Cu(1)-N(4) bond length is 2.02 Å. The Cu(1)-N(8) bond length is 2.01 Å. The Cu(1)-I(1) bond length is 2.68 Å. The Cu(1)-I(2) bond length is 2.65 Å. In the second Cu site, Cu(2) is bonded in a 2-coordinate geometry to one N(1), one N(6), one I(1), and one I(2) atom. The Cu(2)-N(1) bond length is 2.00 Å. The Cu(2)-N(6) bond length is 2.01 Å. The Cu(2)-I(1) bond length is 2.69 Å. The Cu(2)-I(2) bond length is 2.64 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(4), one N(4), and one H(1) atom. The C(1)-C(4) bond length is 1.39 Å. The C(1)-N(4) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(2) atom. The C(2)-N(4) bond length is 1.35 Å. The C(2)-N(5) bond length is 1.33 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one C(5), and one N(5) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(5) bond length is 1.51 Å. The C(3)-N(5) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a single-bond geometry to one C(1), one C(3), and one F(1) atom. The C(4)-F(1) bond length is 1.35 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(5)-H(3) bond length is 1.10 Å. In the sixth C site, C(14) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(10) atom. The C(14)-N(1) bond length is 1.37 Å. The C(14)-N(2) bond length is 1.33 Å. The C(14)-H(10) bond length is 1.09 Å. In the seventh C site, C(15) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(11) atom. The C(15)-N(1) bond length is 1.34 Å. The C(15)-N(3) bond length is 1.35 Å. The C(15)-H(11) bond length is 1.09 Å. In the eighth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(12), and one H(13) atom. The C(16)-N(3) bond length is 1.45 Å. The C(16)-H(12) bond length is 1.09 Å. The C(16)-H(13) bond length is 1.10 Å. In the ninth C site, C(17) is bonded in a trigonal planar geometry to one N(6), one N(7), and one H(14) atom. The C(17)-N(6) bond length is 1.35 Å. The C(17)-N(7) bond length is 1.33 Å. The C(17)-H(14) bond length is 1.09 Å. In the tenth C site, C(18) is bonded in a distorted trigonal planar geometry to one N(6) and one H(15) atom. The C(18)-N(6) bond length is 1.35 Å. The C(18)-H(15) bond length is 1.09 Å. In the eleventh C site, C(19) is bonded in a single-bond geometry to one C(20) and one F(4) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-F(4) bond length is 1.35 Å. In the twelfth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one N(7) atom. The C(20)-C(21) bond length is 1.50 Å. The C(20)-N(7) bond length is 1.35 Å. In the thirteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(16) atom. The C(21)-H(16) bond length is 1.10 Å. In the fourteenth C site, C(23) is bonded in a distorted trigonal non-coplanar geometry to one N(9), one H(20), and one H(21) atom. The C(23)-N(9) bond length is 1.45 Å. The C(23)-H(20) bond length is 1.09 Å. The C(23)-H(21) bond length is 1.10 Å. In the fifteenth C site, C(31) is bonded in a trigonal planar geometry to one N(10), one N(8), and one H(25) atom. The C(31)-N(10) bond length is 1.33 Å. The C(31)-N(8) bond length is 1.37 Å. The C(31)-H(25) bond length is 1.09 Å. In the sixteenth C site, C(32) is bonded in a trigonal planar geometry to one N(8), one N(9), and one H(26) atom. The C(32)-N(8) bond length is 1.34 Å. The C(32)-N(9) bond length is 1.35 Å. The C(32)-H(26) bond length is 1.09 Å. There are ten inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(14), and one C(15) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(14) and one N(3) atom. The N(2)-N(3) bond length is 1.36 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(15), one C(16), and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(2), one C(17), and one C(18) atom. In the seventh N site, N(7) is bonded in a bent 120 degrees geometry to one C(17) and one C(20) atom. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(31), and one C(32) atom. In the ninth N site, N(9) is bonded in a distorted trigonal planar geometry to one C(23), one C(32), and one N(10) atom. The N(9)-N(10) bond length is 1.36 Å. In the tenth N site, N(10) is bonded in a distorted water-like geometry to one C(31) and one N(9) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(25) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(26) is bonded in a single-bond geometry to one C(32) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to one Cu(1) and one Cu(2) atom. In the second I site, I(2) is bonded in a 2-coordinate geometry to one Cu(1) and one Cu(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(4) atom. In the second F site, F(4) is bonded in a single-bond geometry to one C(19) atom. Linkers: 2 C[C@@H](c1ncncc1F)[C@](O)(CN1[CH]N=C[N]1)c1ccc(F)cc1F. Metal clusters: 1 I[Cu][Cu]I. The MOF has largest included sphere 3.68 A, density 1.74 g/cm3, surface area 3706.84 m2/g, accessible volume 0.14 cm3/g