ZnC13H11(NO2)2CH crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a ZnC13H11(NO2)2 framework. In the ZnC13H11(NO2)2 framework, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(2), and one O(4) atom. The Zn(1)-N(1) bond length is 2.07 Å. The Zn(1)-N(2) bond length is 2.14 Å. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.00 Å. The Zn(1)-O(4) bond length is 2.05 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.44 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-C(7) bond length is 1.44 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one O(1) atom. The C(2)-O(1) bond length is 1.31 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(8) bond length is 1.49 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one H(6) atom. The C(7)-N(1) bond length is 1.30 Å. The C(7)-H(6) bond length is 1.10 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(2), and one O(3) atom. The C(8)-O(2) bond length is 1.29 Å. The C(8)-O(3) bond length is 1.27 Å. In the eighth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one N(1), one H(7), and one H(8) atom. The C(9)-C(10) bond length is 1.51 Å. The C(9)-N(1) bond length is 1.46 Å. The C(9)-H(7) bond length is 1.10 Å. The C(9)-H(8) bond length is 1.11 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one N(2) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-N(2) bond length is 1.34 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(9) atom. The C(11)-H(9) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(10) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(11) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(11) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(2), and one H(12) atom. The C(14)-N(2) bond length is 1.34 Å. The C(14)-H(12) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(7), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(14) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(1) and one O(4) atom. The H(1)-O(1) bond length is 1.61 Å. The H(1)-O(4) bond length is 1.01 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(3) and one O(4) atom. The H(2)-O(3) bond length is 1.64 Å. The H(2)-O(4) bond length is 1.01 Å. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(14) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted water-like geometry to one Zn(1), one H(1), and one H(2) atom. In the second O site, O(1) is bonded in a trigonal planar geometry to one Zn(1), one C(2), and one H(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one C(8) and one H(2) atom. Linkers: 4 [O]C(=O)c1ccc([O])c(/C=N/Cc2ccccn2)c1. Metal clusters: 4 O.[O][Zn]O[C]=O. The MOF has largest included sphere 2.71 A, density 1.69 g/cm3, surface area 4032.11 m2/g, accessible volume 0.10 cm3/g