ZnC24N2H16O5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ZnC24N2H16O5 clusters. Zn(1) is bonded in a 6-coordinate geometry to one N(4), one O(1), one O(3), one O(6), one O(8), and one O(9) atom. The Zn(1)-N(4) bond length is 2.05 Å. The Zn(1)-O(1) bond length is 2.20 Å. The Zn(1)-O(3) bond length is 2.10 Å. The Zn(1)-O(6) bond length is 2.20 Å. The Zn(1)-O(8) bond length is 2.15 Å. The Zn(1)-O(9) bond length is 2.43 Å. There are twenty-four inequivalent C sites. In the first C site, C(31,32) is bonded in a distorted single-bond geometry to one C(13,14) and one H(13,14) atom. The C(31,32)-C(13,14) bond length is 1.41 Å. The C(31,32)-H(13,14) bond length is 1.09 Å. In the second C site, C(33) is bonded in a distorted single-bond geometry to one C(19) and one H(11,12,15,16) atom. The C(33)-C(19) bond length is 1.40 Å. The C(33)-H(11,12,15,16) bond length is 1.09 Å. In the third C site, C(35,36) is bonded in a distorted single-bond geometry to one C(13,14) and one H(17,18) atom. The C(35,36)-C(13,14) bond length is 1.40 Å. The C(35,36)-H(17,18) bond length is 1.09 Å. In the fourth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(26), one C(28), and one H(20) atom. The C(38)-C(26) bond length is 1.40 Å. The C(38)-C(28) bond length is 1.39 Å. The C(38)-H(20) bond length is 1.09 Å. In the fifth C site, C(40) is bonded in a bent 120 degrees geometry to one C(26), one O(6), and one O(8) atom. The C(40)-C(26) bond length is 1.49 Å. The C(40)-O(6) bond length is 1.29 Å. The C(40)-O(8) bond length is 1.28 Å. In the sixth C site, C(41,42) is bonded in a distorted single-bond geometry to one C(1) and one H(25,26) atom. The C(41,42)-C(1) bond length is 1.41 Å. The C(41,42)-H(25,26) bond length is 1.09 Å. In the seventh C site, C(43,44) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(27,28) atom. The C(43,44)-N(3) bond length is 1.35 Å. The C(43,44)-H(27,28) bond length is 1.09 Å. In the eighth C site, C(45,46) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(29,30) atom. The C(45,46)-N(3) bond length is 1.35 Å. The C(45,46)-H(29,30) bond length is 1.09 Å. In the ninth C site, C(47,48) is bonded in a distorted single-bond geometry to one C(1) and one H(31,32) atom. The C(47,48)-C(1) bond length is 1.40 Å. The C(47,48)-H(31,32) bond length is 1.09 Å. In the tenth C site, C(2) is bonded in a trigonal planar geometry to one C(3,4); one C(41,42); and one C(47,48) atom. The C(2)-C(3,4) bond length is 1.48 Å. The C(2)-C(41,42) bond length is 1.41 Å. The C(2)-C(47,48) bond length is 1.40 Å. In the eleventh C site, C(3,4) is bonded in a trigonal planar geometry to one C(1), one C(15), and one C(9) atom. The C(3,4)-C(1) bond length is 1.48 Å. The C(3,4)-C(15) bond length is 1.40 Å. The C(3,4)-C(9) bond length is 1.40 Å. In the twelfth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(2) atom. The C(6)-C(10) bond length is 1.40 Å. The C(6)-C(12) bond length is 1.48 Å. The C(6)-N(2) bond length is 1.35 Å. In the thirteenth C site, C(7,8) is bonded in a distorted single-bond geometry to one C(13,14) and one N(1) atom. The C(7,8)-C(13,14) bond length is 1.48 Å. The C(7,8)-N(1) bond length is 1.35 Å. In the fourteenth C site, C(10) is bonded in a distorted single-bond geometry to one C(3,4); one C(6); and one H(1,2) atom. The C(10)-C(3,4) bond length is 1.40 Å. The C(10)-H(1,2) bond length is 1.09 Å. In the fifteenth C site, C(12) is bonded in a trigonal planar geometry to one C(24), one C(28), and one C(6) atom. The C(12)-C(24) bond length is 1.40 Å. The C(12)-C(28) bond length is 1.40 Å. In the sixteenth C site, C(13,14) is bonded in a trigonal planar geometry to one C(31,32); one C(35,36); and one C(7,8) atom. In the seventeenth C site, C(16) is bonded in a distorted single-bond geometry to one C(3,4) and one H(3,4) atom. The C(16)-C(3,4) bond length is 1.40 Å. The C(16)-H(3,4) bond length is 1.09 Å. In the eighteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(1), and one O(3) atom. The C(17)-C(19) bond length is 1.49 Å. The C(17)-O(1) bond length is 1.29 Å. The C(17)-O(3) bond length is 1.28 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(17), one C(29), and one C(33) atom. The C(19)-C(29) bond length is 1.40 Å. In the twentieth C site, C(22) is bonded in a distorted single-bond geometry to one C(26) and one H(5,6) atom. The C(22)-C(26) bond length is 1.40 Å. The C(22)-H(5,6) bond length is 1.09 Å. In the twenty-first C site, C(24) is bonded in a single-bond geometry to one C(12) and one H(8) atom. The C(24)-H(8) bond length is 1.09 Å. In the twenty-second C site, C(26) is bonded in a trigonal planar geometry to one C(22), one C(38), and one C(40) atom. In the twenty-third C site, C(28) is bonded in a distorted single-bond geometry to one C(12), one C(38), and one H(10) atom. The C(28)-H(10) bond length is 1.09 Å. In the twenty-fourth C site, C(29) is bonded in a distorted single-bond geometry to one C(19) and one H(11,12,15,16) atom. The C(29)-H(11,12,15,16) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a bent 120 degrees geometry to one C(6) and one C(7,8) atom. The N(2)-C(7,8) bond length is 1.35 Å. In the second N site, N(4) is bonded in a trigonal planar geometry to one Zn(1); one C(43,44); and one C(45,46) atom. The N(4)-C(43,44) bond length is 1.35 Å. The N(4)-C(45,46) bond length is 1.35 Å. There are fifteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(9) atom. The H(1,2)-C(9) bond length is 1.09 Å. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(15) atom. The H(3,4)-C(15) bond length is 1.09 Å. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(21) atom. The H(5,6)-C(21) bond length is 1.09 Å. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(24) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(28) atom. In the sixth H site, H(11,12,15,16) is bonded in a single-bond geometry to one C(29) atom. In the seventh H site, H(13,14) is bonded in a single-bond geometry to one C(31,32) atom. In the eighth H site, H(17,18) is bonded in a single-bond geometry to one C(35,36) atom. In the ninth H site, H(20) is bonded in a single-bond geometry to one C(38) atom. In the tenth H site, H(21) is bonded in a single-bond geometry to one O(9) atom. The H(21)-O(9) bond length is 0.99 Å. In the eleventh H site, H(23) is bonded in a single-bond geometry to one O(9) atom. The H(23)-O(9) bond length is 0.97 Å. In the twelfth H site, H(25,26) is bonded in a single-bond geometry to one C(41,42) atom. In the thirteenth H site, H(27,28) is bonded in a single-bond geometry to one C(43,44) atom. In the fourteenth H site, H(29,30) is bonded in a single-bond geometry to one C(45,46) atom. In the fifteenth H site, H(31,32) is bonded in a single-bond geometry to one C(47,48) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Zn(1) and one C(17) atom. In the second O site, O(3) is bonded in an L-shaped geometry to one Zn(1) and one C(17) atom. In the third O site, O(6) is bonded in an L-shaped geometry to one Zn(1) and one C(40) atom. In the fourth O site, O(8) is bonded in an L-shaped geometry to one Zn(1) and one C(40) atom. In the fifth O site, O(9) is bonded in a distorted water-like geometry to one Zn(1), one H(21), and one H(23) atom. 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Metal clusters: 2 [C]1O[Zn]2(O1)O[C]O2. The MOF has largest included sphere 7.90 A, density 0.80 g/cm3, surface area 4929.82 m2/g, accessible volume 0.69 cm3/g