(CuC3NH3I)4(CH)4C9H8O4 is Indium-derived structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; two 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and two CuC3NH3I clusters. In each CuC3NH3I cluster, Cu(1) is bonded in a 1-coordinate geometry to one N(1) and three equivalent I(1) atoms. The Cu(1)-N(1) bond length is 2.01 Å. There are a spread of Cu(1)-I(1) bond distances ranging from 2.60-2.81 Å. There are three inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the second C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the third C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(6)-N(1) bond length is 1.35 Å. The C(6)-H(5) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(5), and one C(6) atom. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. I(1) is bonded in a 3-coordinate geometry to three equivalent Cu(1) atoms. Linkers: 1 [C][CH]/C(=C\[C])OCC(COc1ccncc1)(COc1ccncc1)COc1ccncc1 ,1 c1cc(OCC(COc2ccncc2)(COc2ccncc2)COc2ccncc2)ccn1 ,1 [CH]=[C]OCC(C[O])(COc1ccncc1)COc1ccncc1. Metal clusters: 1 I[Cu@]12[Cu@]3(I)[Cu@@]1(I)[Cu@]23I. The MOF has largest included sphere 3.33 A, density 2.30 g/cm3, surface area 2941.17 m2/g, accessible volume 0.13 cm3/g