(CH2)4CuC30N6H26(O3F)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two CuC30N6H26(O3F)2 clusters. In each CuC30N6H26(O3F)2 cluster, Cu(1) is bonded in an octahedral geometry to two equivalent N(3), two equivalent O(1), and two equivalent O(3) atoms. Both Cu(1)-N(3) bond lengths are 2.11 Å. Both Cu(1)-O(1) bond lengths are 2.02 Å. Both Cu(1)-O(3) bond lengths are 2.45 Å. There are fifteen inequivalent C sites. In the first C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(3) and two equivalent H(13,14) atoms. The C(16)-N(3) bond length is 1.48 Å. There is one shorter (1.09 Å) and one longer (1.10 Å) C(16)-H(13,14) bond length. In the second C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(15), and one H(16) atom. The C(17)-N(2) bond length is 1.47 Å. The C(17)-H(15) bond length is 1.10 Å. The C(17)-H(16) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the fourth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(3) atom. The C(2)-C(10) bond length is 1.38 Å. The C(2)-C(3) bond length is 1.44 Å. In the fifth C site, C(3) is bonded in a single-bond geometry to one C(2), one C(4), and one O(3) atom. The C(3)-C(4) bond length is 1.47 Å. The C(3)-O(3) bond length is 1.26 Å. In the sixth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(9) bond length is 1.41 Å. In the seventh C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(1) atom. The C(5)-H(1) bond length is 1.08 Å. In the eighth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one F(1) atom. The C(6)-C(7) bond length is 1.42 Å. The C(6)-F(1) bond length is 1.38 Å. In the ninth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(2) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-N(2) bond length is 1.38 Å. In the tenth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(2) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-H(2) bond length is 1.09 Å. In the eleventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(4), one C(8), and one N(1) atom. The C(9)-N(1) bond length is 1.40 Å. In the twelfth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(3) atom. The C(10)-N(1) bond length is 1.36 Å. The C(10)-H(3) bond length is 1.09 Å. In the thirteenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(11)-N(1) bond length is 1.45 Å. The C(11)-H(4) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(10), and one H(9) atom. The C(14)-N(2) bond length is 1.45 Å. The C(14)-H(10) bond length is 1.11 Å. The C(14)-H(9) bond length is 1.10 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(11), and one H(12) atom. The C(15)-N(3) bond length is 1.47 Å. The C(15)-H(11) bond length is 1.09 Å. The C(15)-H(12) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(14), one C(17), and one C(7) atom. In the third N site, N(3) is bonded to one Cu(1), one C(15), one C(16), and one H(17) atom to form distorted corner-sharing NCuHC2 tetrahedra. The N(3)-H(17) bond length is 1.04 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(13,14) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one N(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cu(1) and one C(3) atom. F(1) is bonded in a single-bond geometry to one C(6) atom. Linkers: 4 [O]C(=O)c1cn(C2CC2)c2cc(N3CCNCC3)c(F)cc2c1=O. Metal clusters: 2 [NH][Cu]([NH])(O[C]=O)O[C]=O.[O].[O]. The MOF has largest included sphere 3.49 A, density 1.53 g/cm3, surface area 4282.94 m2/g, accessible volume 0.15 cm3/g