ZnC7N3H7O5CH2 crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of four 02329_fluka molecules inside a ZnC7N3H7O5 framework. In the ZnC7N3H7O5 framework, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(3), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.11 Å. The Zn(1)-N(3) bond length is 2.08 Å. The Zn(1)-O(2) bond length is 2.27 Å. The Zn(1)-O(3) bond length is 2.00 Å. The Zn(1)-O(4) bond length is 2.08 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one C(2), one N(3), and one H(1) atom. The C(1)-C(2) bond length is 1.53 Å. The C(1)-N(3) bond length is 1.49 Å. The C(1)-H(1) bond length is 1.10 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(6) atom. The C(2)-C(4) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(2) atom. The C(3)-C(5) bond length is 1.39 Å. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(5) atom. The C(6)-N(1) bond length is 1.35 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.28 Å. The C(8)-O(4) bond length is 1.27 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(3), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(5) atom. The N(2)-O(1) bond length is 1.27 Å. The N(2)-O(2) bond length is 1.28 Å. The N(2)-O(5) bond length is 1.26 Å. In the third N site, N(3) is bonded in a distorted tetrahedral geometry to one Zn(1), one C(1), one H(6), and one H(7) atom. The N(3)-H(6) bond length is 1.03 Å. The N(3)-H(7) bond length is 1.03 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(3) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one N(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(2) atom. Linkers: 4 N[C@@H](CC([O])=O)c1cccnc1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 1.89 A, density 1.90 g/cm3, surface area 3795.54 m2/g, accessible volume 0.10 cm3/g