V4Ag2C16N8H20O11(CH2)4 crystallizes in the monoclinic C2/c space group. The structure consists of sixteen 02329_fluka molecules inside a V4Ag2C16N8H20O11 framework. In the V4Ag2C16N8H20O11 framework, there are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form corner-sharing VO4 tetrahedra. The V(1)-O(1) bond length is 1.64 Å. The V(1)-O(2) bond length is 1.64 Å. The V(1)-O(3) bond length is 1.84 Å. The V(1)-O(5) bond length is 1.85 Å. In the second V site, V(2) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing VO4 tetrahedra. The V(2)-O(3) bond length is 1.75 Å. The V(2)-O(4) bond length is 1.79 Å. The V(2)-O(5) bond length is 1.75 Å. The V(2)-O(6) bond length is 1.62 Å. Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(3), and two equivalent O(1) atoms. The Ag(1)-N(1) bond length is 2.10 Å. The Ag(1)-N(3) bond length is 2.10 Å. There is one shorter (2.61 Å) and one longer (2.76 Å) Ag(1)-O(1) bond length. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(1) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.38 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(4), and one H(5) atom. The C(4)-N(2) bond length is 1.46 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(8) atom. The C(6)-N(3) bond length is 1.33 Å. The C(6)-N(4) bond length is 1.36 Å. The C(6)-H(8) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(3), and one H(9) atom. The C(7)-C(8) bond length is 1.38 Å. The C(7)-N(3) bond length is 1.38 Å. The C(7)-H(9) bond length is 1.08 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(4), and one H(10) atom. The C(8)-N(4) bond length is 1.38 Å. The C(8)-H(10) bond length is 1.08 Å. In the eighth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(11), and one H(12) atom. The C(9)-N(4) bond length is 1.46 Å. The C(9)-H(11) bond length is 1.10 Å. The C(9)-H(12) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(6), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the second O site, O(4) is bonded in a linear geometry to two equivalent V(2) atoms. In the third O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one V(2) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Ag(1) atoms. In the sixth O site, O(2) is bonded in a single-bond geometry to one V(1) atom. Linkers: 4 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 8 [V] ,4 [Ag]. The MOF has largest included sphere 1.90 A, density 2.07 g/cm3, surface area 3700.02 m2/g, accessible volume 0.11 cm3/g