CuC6H5(NO2)2(CH3)2CH is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, four 02329_fluka molecules, and one CuC6H5(NO2)2 cluster. In the CuC6H5(NO2)2 cluster, Cu(1) is bonded in a square pyramidal geometry to one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-N(2) bond length is 2.18 Å. The Cu(1)-O(1) bond length is 2.02 Å. The Cu(1)-O(2) bond length is 2.00 Å. The Cu(1)-O(3) bond length is 2.01 Å. The Cu(1)-O(4) bond length is 2.00 Å. There are six inequivalent C sites. In the first C site, C(5) is bonded in a distorted water-like geometry to one N(1) and one N(2) atom. The C(5)-N(1) bond length is 1.38 Å. The C(5)-N(2) bond length is 1.35 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(1), and one H(7) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-N(1) bond length is 1.38 Å. The C(6)-H(7) bond length is 1.08 Å. In the third C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one N(2), and one H(8) atom. The C(7)-N(2) bond length is 1.37 Å. The C(7)-H(8) bond length is 1.08 Å. In the fourth C site, C(8) is bonded in a tetrahedral geometry to one N(1), one H(10), one H(11), and one H(9) atom. The C(8)-N(1) bond length is 1.45 Å. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(11) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. In the fifth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.27 Å. In the sixth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(3)-O(3) bond length is 1.27 Å. The C(3)-O(4) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(5), and one C(7) atom. There are five inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(8) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. Linkers: 1 Cn1ccnc1/C=C/c1nccn1C ,2 [CH2]n1[c]cnc1/C=C/c1nccn1C. Metal clusters: 2 [Cu]. The MOF has largest included sphere 3.76 A, density 1.55 g/cm3, surface area 4615.54 m2/g, accessible volume 0.17 cm3/g