AgC6N3H9O4Cl is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AgC6N3H9O4Cl clusters. Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one N(3), and one O(2) atom. The Ag(1)-N(1) bond length is 2.33 Å. The Ag(1)-N(2) bond length is 2.18 Å. The Ag(1)-N(3) bond length is 2.15 Å. The Ag(1)-O(2) bond length is 2.70 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(1)-N(1) bond length is 1.48 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one C(3), one H(3), and one H(4) atom. The C(2)-C(3) bond length is 1.45 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted linear geometry to one C(2) and one N(2) atom. The C(3)-N(2) bond length is 1.16 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(5), and one H(6) atom. The C(4)-N(1) bond length is 1.47 Å. The C(4)-H(5) bond length is 1.09 Å. The C(4)-H(6) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a distorted water-like geometry to one C(6), one H(7), and one H(8) atom. The C(5)-C(6) bond length is 1.44 Å. The C(5)-H(7) bond length is 1.10 Å. The C(5)-H(8) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted linear geometry to one C(5) and one N(3) atom. The C(6)-N(3) bond length is 1.16 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Ag(1), one C(1), one C(4), and one H(9) atom. The N(1)-H(9) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one C(3) atom. In the third N site, N(3) is bonded in a distorted linear geometry to one Ag(1) and one C(6) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(1) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. The O(1)-Cl(1) bond length is 1.46 Å. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one Cl(1) atom. The O(2)-Cl(1) bond length is 1.47 Å. In the third O site, O(3) is bonded in a single-bond geometry to one Cl(1) atom. The O(3)-Cl(1) bond length is 1.46 Å. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cl(1) atom. The O(4)-Cl(1) bond length is 1.46 Å. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Linkers: 4 N#CCCNCCC#N. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.88 A, density 2.15 g/cm3, surface area 3576.56 m2/g, accessible volume 0.08 cm3/g