ZnC8NH5O4(CH)2(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, eight 02329_fluka molecules, and one ZnC8NH5O4 cluster. In the ZnC8NH5O4 cluster, Zn(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.06 Å. The Zn(1)-O(1) bond length is 2.06 Å. The Zn(1)-O(2) bond length is 2.13 Å. The Zn(1)-O(3) bond length is 2.07 Å. The Zn(1)-O(4) bond length is 2.04 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.27 Å. In the third C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(11) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(11) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(12) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-H(12) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-C(14) bond length is 1.46 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(13) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(13) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one N(1), and one H(14) atom. The C(13)-N(1) bond length is 1.35 Å. The C(13)-H(14) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(11) and one H(15) atom. The C(14)-H(15) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(9) atom. There are five inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. Linkers: 2 [O]C(=O)[C@H]1CCCC[C@H]1C([O])=O ,1 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 1 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 2.51 A, density 1.62 g/cm3, surface area 4451.31 m2/g, accessible volume 0.15 cm3/g