LiAlC24H12(NO)4(CH)4 crystallizes in the triclinic P1 space group. The structure consists of four 02329_fluka molecules inside a LiAlC24H12(NO)4 framework. In the LiAlC24H12(NO)4 framework, Li(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Li(1)-N(1) bond length is 2.03 Å. The Li(1)-N(2) bond length is 2.03 Å. The Li(1)-N(3) bond length is 2.03 Å. The Li(1)-N(4) bond length is 2.03 Å. Al(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Al(1)-O(1) bond length is 1.75 Å. The Al(1)-O(2) bond length is 1.75 Å. The Al(1)-O(3) bond length is 1.75 Å. The Al(1)-O(4) bond length is 1.75 Å. There are fourteen inequivalent C sites. In the first C site, C(1,2,3,4) is bonded in a distorted single-bond geometry to one C(5,8) and one O(1) atom. The C(1,2,3,4)-C(5,8) bond length is 1.41 Å. The C(1,2,3,4)-O(1) bond length is 1.34 Å. In the second C site, C(5,8) is bonded in a distorted trigonal planar geometry to one C(1,2,3,4); one C(9,10,12); and one H(1,2,3,4) atom. The C(5,8)-C(9,10,12) bond length is 1.38 Å. The C(5,8)-H(1,2,3,4) bond length is 1.09 Å. In the third C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1,2,3,4); one C(9,10,12); and one H(1,2,3,4) atom. The C(6)-C(1,2,3,4) bond length is 1.41 Å. The C(6)-C(9,10,12) bond length is 1.38 Å. The C(6)-H(1,2,3,4) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(1,2,3,4); one C(11); and one H(1,2,3,4) atom. The C(7)-C(1,2,3,4) bond length is 1.41 Å. The C(7)-C(11) bond length is 1.38 Å. The C(7)-H(1,2,3,4) bond length is 1.09 Å. In the fifth C site, C(9,10,12) is bonded in a distorted single-bond geometry to one C(13,15); one C(5,8); and one H(5,6,7,8) atom. The C(9,10,12)-C(13,15) bond length is 1.41 Å. The C(9,10,12)-H(5,6,7,8) bond length is 1.09 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(13,15); one C(7); and one H(5,6,7,8) atom. The C(11)-C(13,15) bond length is 1.41 Å. The C(11)-H(5,6,7,8) bond length is 1.09 Å. In the seventh C site, C(13,15) is bonded in a trigonal planar geometry to one C(17,18,20); one C(25,28); and one C(9,10,12) atom. The C(13,15)-C(17,18,20) bond length is 1.41 Å. The C(13,15)-C(25,28) bond length is 1.41 Å. In the eighth C site, C(14) is bonded in a trigonal planar geometry to one C(17,18,20); one C(26); and one C(9,10,12) atom. The C(14)-C(17,18,20) bond length is 1.41 Å. The C(14)-C(26) bond length is 1.41 Å. The C(14)-C(9,10,12) bond length is 1.41 Å. In the ninth C site, C(16) is bonded in a trigonal planar geometry to one C(17,18,20); one C(25,28); and one C(9,10,12) atom. The C(16)-C(17,18,20) bond length is 1.41 Å. The C(16)-C(25,28) bond length is 1.41 Å. The C(16)-C(9,10,12) bond length is 1.41 Å. In the tenth C site, C(17,18,20) is bonded in a distorted single-bond geometry to one C(13,15) and one H(9,10,11,12) atom. The C(17,18,20)-H(9,10,11,12) bond length is 1.09 Å. In the eleventh C site, C(19) is bonded in a distorted single-bond geometry to one C(13,15) and one H(9,10,11,12) atom. The C(19)-C(13,15) bond length is 1.41 Å. The C(19)-H(9,10,11,12) bond length is 1.09 Å. In the twelfth C site, C(25,28) is bonded in a distorted linear geometry to one C(13,15) and one N(1) atom. The C(25,28)-N(1) bond length is 1.17 Å. In the thirteenth C site, C(26) is bonded in a distorted linear geometry to one C(14) and one N(2) atom. The C(26)-N(2) bond length is 1.17 Å. In the fourteenth C site, C(27) is bonded in a distorted linear geometry to one C(13,15) and one N(3) atom. The C(27)-C(13,15) bond length is 1.41 Å. The C(27)-N(3) bond length is 1.17 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Li(1) and one C(25,28) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Li(1) and one C(26) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one Li(1) and one C(27) atom. In the fourth N site, N(4) is bonded in a bent 150 degrees geometry to one Li(1) and one C(25,28) atom. The N(4)-C(25,28) bond length is 1.17 Å. There are three inequivalent H sites. In the first H site, H(1,2,3,4) is bonded in a single-bond geometry to one C(5,8) atom. In the second H site, H(5,6,7,8) is bonded in a single-bond geometry to one C(9,10,12) atom. In the third H site, H(9,10,11,12) is bonded in a single-bond geometry to one C(17,18,20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Al(1) and one C(1,2,3,4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Al(1) and one C(1,2,3,4) atom. The O(2)-C(1,2,3,4) bond length is 1.34 Å. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Al(1) and one C(1,2,3,4) atom. The O(3)-C(1,2,3,4) bond length is 1.34 Å. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Al(1) and one C(1,2,3,4) atom. The O(4)-C(1,2,3,4) bond length is 1.34 Å. Linkers: 4 N#Cc1ccc([O])cc1. Metal clusters: 1 [Li] ,1 [Al]. The MOF has largest included sphere 2.55 A, density 1.38 g/cm3, surface area 5212.00 m2/g, accessible volume 0.14 cm3/g