C3H2CuC9N3H10SO5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one 2,3-dimethyl-1,3-butadiene molecule and one CuC9N3H10SO5 cluster. In the CuC9N3H10SO5 cluster, Cu(1) is bonded to one N(1), one N(2), one N(3), one O(1), and one O(2) atom to form CuN3O2 square pyramids that share  a cornercorner with one S(1)CNO2 tetrahedra. The Cu(1)-N(1) bond length is 2.03 Å. The Cu(1)-N(2) bond length is 1.99 Å. The Cu(1)-N(3) bond length is 2.01 Å. The Cu(1)-O(1) bond length is 2.35 Å. The Cu(1)-O(2) bond length is 2.00 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(3), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(3) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one S(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-S(1) bond length is 1.79 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(3), and one H(4) atom. The C(5)-N(3) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(5), and one H(6) atom. The C(6)-N(2) bond length is 1.46 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(7)-O(2) bond length is 1.31 Å. The C(7)-O(3) bond length is 1.24 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(7) atom. The C(8)-N(1) bond length is 1.35 Å. The C(8)-H(7) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(10) atom. The C(12)-N(1) bond length is 1.35 Å. The C(12)-H(10) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(12), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(6), and one S(1) atom. The N(2)-S(1) bond length is 1.58 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one O(1) atom. The H(11)-O(1) bond length is 0.98 Å. In the tenth H site, H(12) is bonded in a single-bond geometry to one O(1) atom. The H(12)-O(1) bond length is 0.99 Å. S(1) is bonded to one C(2), one N(2), one O(4), and one O(5) atom to form distorted SCNO2 tetrahedra that share  a cornercorner with one Cu(1)N3O2 square pyramid. The S(1)-O(4) bond length is 1.45 Å. The S(1)-O(5) bond length is 1.46 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cu(1), one H(11), and one H(12) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(1) atom. Linkers: 2 [O]C(=O)C[N]S(=O)(=O)c1cccnc1 ,1 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 3.38 A, density 1.64 g/cm3, surface area 3884.75 m2/g, accessible volume 0.15 cm3/g