CuC4NH9OICH3CHO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dimethyl ether molecules and one CuC4NH9OI cluster. In the CuC4NH9OI cluster, Cu(1) is bonded in a 5-coordinate geometry to one Cu(1), one N(1), one O(1), and two equivalent I(1) atoms. The Cu(1)-Cu(1) bond length is 2.44 Å. The Cu(1)-N(1) bond length is 2.05 Å. The Cu(1)-O(1) bond length is 2.40 Å. There is one shorter (2.52 Å) and one longer (2.71 Å) Cu(1)-I(1) bond length. There are four inequivalent C sites. In the first C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one H(6), one H(7), and one O(1) atom. The C(3)-H(6) bond length is 1.10 Å. The C(3)-H(7) bond length is 1.10 Å. The C(3)-O(1) bond length is 1.43 Å. In the second C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(12), and one H(13) atom. The C(6)-N(1) bond length is 1.48 Å. The C(6)-H(12) bond length is 1.10 Å. The C(6)-H(13) bond length is 1.10 Å. In the third C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(2), and one H(3) atom. The C(1)-N(1) bond length is 1.48 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.11 Å. In the fourth C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one H(4), one H(5), and one O(1) atom. The C(2)-H(4) bond length is 1.10 Å. The C(2)-H(5) bond length is 1.11 Å. The C(2)-O(1) bond length is 1.43 Å. N(1) is bonded in a distorted tetrahedral geometry to one Cu(1), one C(1), one C(6), and one H(1) atom. The N(1)-H(1) bond length is 1.03 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(6) atom. O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1), one C(2), and one C(3) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 2 [CH]1COCCOCCNCCOCCOCCN1 ,2 [CH]1CNCCOCCOCCNCCOCCO1 ,1 C1COCCOCCNCCOCCOCCN1. Metal clusters: 1 [NH][Cu](I)[Cu]([NH])I. The MOF has largest included sphere 1.80 A, density 2.31 g/cm3, surface area 3572.61 m2/g, accessible volume 0.09 cm3/g