(CdC20H14(NO)6)2(C5H3)3C14NH8 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six isopropenylacetylene molecules, two C14NH8 clusters, and four CdC20H14(NO)6 clusters. In each C14NH8 cluster, there are twelve inequivalent C sites. In the first C site, C(3,4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(3,4)-C(5) bond length is 1.40 Å. The C(3,4)-H(3) bond length is 1.09 Å. In the second C site, C(5) is bonded in a trigonal planar geometry to one C(11); one C(3,4); and one C(7,8) atom. The C(5)-C(11) bond length is 1.48 Å. The C(5)-C(7,8) bond length is 1.40 Å. In the third C site, C(6) is bonded in a trigonal planar geometry to one C(12); one C(3,4); and one C(7,8) atom. The C(6)-C(12) bond length is 1.48 Å. The C(6)-C(3,4) bond length is 1.40 Å. The C(6)-C(7,8) bond length is 1.40 Å. In the fourth C site, C(7,8) is bonded in a distorted single-bond geometry to one C(5) and one H(5) atom. The C(7,8)-H(5) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(13), one C(5), and one N(3) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-N(3) bond length is 1.35 Å. In the sixth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14), one C(6), and one N(3) atom. The C(12)-C(14) bond length is 1.40 Å. The C(12)-N(3) bond length is 1.35 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(11); one C(15); and one H(9,10) atom. The C(13)-C(15) bond length is 1.40 Å. The C(13)-H(9,10) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(12); one C(15); and one H(9,10) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(9,10) bond length is 1.09 Å. In the ninth C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(16) atom. The C(15)-C(16) bond length is 1.47 Å. In the tenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(18) bond length is 1.41 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(11,12) atom. The C(17)-H(11,12) bond length is 1.09 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(16) and one H(11,12) atom. The C(18)-H(11,12) bond length is 1.09 Å. N(3) is bonded in a bent 120 degrees geometry to one C(11) and one C(12) atom. There are six inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(3,4) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(3,4) atom. The H(4)-C(3,4) bond length is 1.09 Å. In the third H site, H(5) is bonded in a single-bond geometry to one C(7,8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7,8) atom. The H(6)-C(7,8) bond length is 1.09 Å. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(17) atom. In each CdC20H14(NO)6 cluster, Cd(1) is bonded in a distorted pentagonal bipyramidal geometry to one N(1), one N(4), one N(9), one O(1), one O(3), one O(7), and one O(9) atom. The Cd(1)-N(1) bond length is 2.34 Å. The Cd(1)-N(4) bond length is 2.37 Å. The Cd(1)-N(9) bond length is 2.38 Å. The Cd(1)-O(1) bond length is 2.40 Å. The Cd(1)-O(3) bond length is 2.50 Å. The Cd(1)-O(7) bond length is 2.39 Å. The Cd(1)-O(9) bond length is 2.62 Å. There are twenty inequivalent C sites. In the first C site, C(24) is bonded in a distorted trigonal planar geometry to one C(26), one N(4), and one H(15) atom. The C(24)-C(26) bond length is 1.39 Å. The C(24)-N(4) bond length is 1.34 Å. The C(24)-H(15) bond length is 1.09 Å. In the second C site, C(26) is bonded in a distorted single-bond geometry to one C(24); one C(28); and one H(17,18) atom. The C(26)-C(28) bond length is 1.40 Å. The C(26)-H(17,18) bond length is 1.09 Å. In the third C site, C(28) is bonded in a trigonal planar geometry to one C(26), one C(30), and one C(34) atom. The C(28)-C(30) bond length is 1.40 Å. The C(28)-C(34) bond length is 1.48 Å. In the fourth C site, C(30) is bonded in a distorted single-bond geometry to one C(28) and one H(19) atom. The C(30)-H(19) bond length is 1.09 Å. In the fifth C site, C(32) is bonded in a distorted trigonal planar geometry to one N(4) and one H(21) atom. The C(32)-N(4) bond length is 1.35 Å. The C(32)-H(21) bond length is 1.09 Å. In the sixth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(28), one C(36), and one N(6) atom. The C(34)-C(36) bond length is 1.40 Å. The C(34)-N(6) bond length is 1.35 Å. In the seventh C site, C(36) is bonded in a distorted trigonal planar geometry to one C(34), one C(38), and one H(23) atom. The C(36)-C(38) bond length is 1.40 Å. The C(36)-H(23) bond length is 1.09 Å. In the eighth C site, C(38) is bonded in a trigonal planar geometry to one C(36), one C(40), and one C(54) atom. The C(38)-C(40) bond length is 1.40 Å. The C(38)-C(54) bond length is 1.47 Å. In the ninth C site, C(40) is bonded in a distorted single-bond geometry to one C(38); one C(42); and one H(25,26) atom. The C(40)-C(42) bond length is 1.40 Å. The C(40)-H(25,26) bond length is 1.09 Å. In the tenth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(40), one C(48), and one N(6) atom. The C(42)-C(48) bond length is 1.48 Å. The C(42)-N(6) bond length is 1.35 Å. In the eleventh C site, C(45) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(27,28) atom. The C(45)-N(9) bond length is 1.35 Å. The C(45)-H(27,28) bond length is 1.09 Å. In the twelfth C site, C(46) is bonded in a distorted single-bond geometry to one C(48) and one H(29,30) atom. The C(46)-C(48) bond length is 1.40 Å. The C(46)-H(29,30) bond length is 1.09 Å. In the thirteenth C site, C(48) is bonded in a trigonal planar geometry to one C(42), one C(46), and one C(50) atom. The C(48)-C(50) bond length is 1.40 Å. In the fourteenth C site, C(50) is bonded in a distorted single-bond geometry to one C(48) and one H(31,32) atom. The C(50)-H(31,32) bond length is 1.09 Å. In the fifteenth C site, C(53) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(33,34) atom. The C(53)-N(9) bond length is 1.35 Å. The C(53)-H(33,34) bond length is 1.09 Å. In the sixteenth C site, C(54) is bonded in a trigonal planar geometry to one C(38); one C(56,57); and one C(64,65) atom. The C(54)-C(56,57) bond length is 1.41 Å. The C(54)-C(64,65) bond length is 1.41 Å. In the seventeenth C site, C(56,57) is bonded in a distorted single-bond geometry to one C(54) and one H(35,36) atom. The C(56,57)-H(35,36) bond length is 1.09 Å. In the eighteenth C site, C(64,65) is bonded in a distorted single-bond geometry to one C(54) and one H(41,42) atom. The C(64,65)-H(41,42) bond length is 1.09 Å. In the nineteenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,2) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1,2) bond length is 1.09 Å. In the twentieth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(7,8) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(7,8) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(9) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(24), and one C(32) atom. In the third N site, N(6) is bonded in a bent 120 degrees geometry to one C(34) and one C(42) atom. In the fourth N site, N(9) is bonded in a trigonal planar geometry to one Cd(1), one C(45), and one C(53) atom. In the fifth N site, N(10) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(5) atom. The N(10)-O(1) bond length is 1.30 Å. The N(10)-O(3) bond length is 1.28 Å. The N(10)-O(5) bond length is 1.24 Å. In the sixth N site, N(12) is bonded in a trigonal planar geometry to one O(11), one O(7), and one O(9) atom. The N(12)-O(11) bond length is 1.24 Å. The N(12)-O(7) bond length is 1.30 Å. The N(12)-O(9) bond length is 1.27 Å. There are fourteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(7,8) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(24) atom. In the fourth H site, H(17,18) is bonded in a single-bond geometry to one C(26) atom. In the fifth H site, H(19) is bonded in a single-bond geometry to one C(30) atom. In the sixth H site, H(21) is bonded in a single-bond geometry to one C(32) atom. In the seventh H site, H(23) is bonded in a single-bond geometry to one C(36) atom. In the eighth H site, H(25,26) is bonded in a single-bond geometry to one C(40) atom. In the ninth H site, H(27,28) is bonded in a single-bond geometry to one C(44) atom. The H(27,28)-C(44) bond length is 1.09 Å. In the tenth H site, H(29,30) is bonded in a single-bond geometry to one C(46) atom. In the eleventh H site, H(31,32) is bonded in a single-bond geometry to one C(50) atom. In the twelfth H site, H(33,34) is bonded in a single-bond geometry to one C(52) atom. The H(33,34)-C(52) bond length is 1.09 Å. In the thirteenth H site, H(35,36) is bonded in a single-bond geometry to one C(56,57) atom. In the fourteenth H site, H(41,42) is bonded in a single-bond geometry to one C(64,65) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1) and one N(10) atom. In the second O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one N(10) atom. In the third O site, O(5) is bonded in a single-bond geometry to one N(10) atom. In the fourth O site, O(7) is bonded in a water-like geometry to one Cd(1) and one N(12) atom. In the fifth O site, O(9) is bonded in a distorted single-bond geometry to one Cd(1) and one N(12) atom. In the sixth O site, O(11) is bonded in a single-bond geometry to one N(12) atom. Linkers: 6 C#Cc1ccc(-c2cc(-c3ccncc3)nc(-c3ccncc3)c2)cc1. Metal clusters: 4 [O]N1O[Cd](O[N+](=O)[O-])O1. The MOF has largest included sphere 4.70 A, density 1.34 g/cm3, surface area 4561.81 m2/g, accessible volume 0.25 cm3/g