CuC22H16(NO3)2(CH)2 crystallizes in the monoclinic C2/c space group. The structure consists of eight 02329_fluka molecules inside a CuC22H16(NO3)2 framework. In the CuC22H16(NO3)2 framework, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(3) atoms. Both Cu(1)-N(1) bond lengths are 2.00 Å. Both Cu(1)-O(3) bond lengths are 1.96 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(6) atom. The C(1)-C(1) bond length is 1.48 Å. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.41 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(4), and one H(2) atom. The C(2)-C(4) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(4) atom. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(7) atom. The C(5)-C(11) bond length is 1.41 Å. The C(5)-C(7) bond length is 1.49 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(10), and one H(5) atom. The C(6)-C(10) bond length is 1.39 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(2), and one O(3) atom. The C(7)-O(2) bond length is 1.26 Å. The C(7)-O(3) bond length is 1.30 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(12) and one O(1) atom. The C(8)-C(12) bond length is 1.41 Å. The C(8)-O(1) bond length is 1.34 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(8) atom. The C(10)-N(1) bond length is 1.35 Å. The C(10)-H(8) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(12), one C(5), and one H(9) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(9) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(8), and one H(6) atom. The C(12)-H(6) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(4) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(2) atom. The H(1)-O(1) bond length is 1.03 Å. The H(1)-O(2) bond length is 1.57 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(8) and one H(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(7) and one H(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(7) atom. Linkers: 1 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.67 A, density 1.55 g/cm3, surface area 4311.20 m2/g, accessible volume 0.15 cm3/g