UC12H9S(NO3)2CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one UC12H9S(NO3)2 cluster. In the UC12H9S(NO3)2 cluster, U(1) is bonded in a 7-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and two equivalent O(6) atoms. The U(1)-N(1) bond length is 2.63 Å. The U(1)-N(2) bond length is 2.63 Å. The U(1)-O(1) bond length is 1.81 Å. The U(1)-O(2) bond length is 1.81 Å. The U(1)-O(3) bond length is 2.33 Å. There is one shorter (2.34 Å) and one longer (2.39 Å) U(1)-O(6) bond length. There are twelve inequivalent C sites. In the first C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(4) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(1) bond length is 1.34 Å. The C(2)-H(4) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(3)-H(5) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(6,8) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(6,8) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(6) atom. The C(5)-C(10) bond length is 1.43 Å. The C(5)-C(6) bond length is 1.42 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(1) atom. The C(6)-C(7) bond length is 1.44 Å. The C(6)-N(1) bond length is 1.36 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(2) atom. The C(7)-C(8) bond length is 1.42 Å. The C(7)-N(2) bond length is 1.36 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(7), and one C(9) atom. The C(8)-C(11) bond length is 1.41 Å. The C(8)-C(9) bond length is 1.43 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(5) and one H(6,8) atom. The C(10)-H(6,8) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(8) and one H(9) atom. The C(11)-H(9) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(10) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(11) atom. The C(13)-N(2) bond length is 1.34 Å. The C(13)-H(11) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one U(1), one C(2), and one C(6) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one U(1), one C(13), and one C(7) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(6) atom. The H(1)-O(6) bond length is 0.98 Å. In the second H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(6,8) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(3), one O(4), and one O(5) atom. The S(1)-O(3) bond length is 1.53 Å. The S(1)-O(4) bond length is 1.46 Å. The S(1)-O(5) bond length is 1.45 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one U(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one U(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to two equivalent U(1) and one H(1) atom. Linkers: 1 [O]S([O])([O])CCS([O])([O])[O]. Metal clusters: 1 [O][S@](=O)O[U]([O])([O])O.[O][S@](=O)O[U]([O])([O])O. The MOF has largest included sphere 2.98 A, density 2.44 g/cm3, surface area 2657.44 m2/g, accessible volume 0.09 cm3/g