AgC5NH6S4O3 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a 6-coordinate geometry to one S(1), one S(2), one O(1), one O(2), and two equivalent O(3) atoms. The Ag(1)-S(1) bond length is 2.63 Å. The Ag(1)-S(2) bond length is 2.58 Å. The Ag(1)-O(1) bond length is 2.82 Å. The Ag(1)-O(2) bond length is 2.74 Å. There is one shorter (2.36 Å) and one longer (2.59 Å) Ag(1)-O(3) bond length. There are five inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(1) atom. The C(1)-H(1) bond length is 1.09 Å. The C(1)-H(2) bond length is 1.09 Å. The C(1)-H(3) bond length is 1.09 Å. The C(1)-S(1) bond length is 1.81 Å. In the second C site, C(2) is bonded in a trigonal non-coplanar geometry to one H(4), one H(5), one H(6), and one S(2) atom. The C(2)-H(4) bond length is 1.09 Å. The C(2)-H(5) bond length is 1.09 Å. The C(2)-H(6) bond length is 1.09 Å. The C(2)-S(2) bond length is 1.81 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(4), one S(2), and one S(4) atom. The C(3)-C(4) bond length is 1.37 Å. The C(3)-S(2) bond length is 1.75 Å. The C(3)-S(4) bond length is 1.76 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one S(1), and one S(3) atom. The C(4)-S(1) bond length is 1.74 Å. The C(4)-S(3) bond length is 1.76 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(5), one S(3), and one S(4) atom. The C(5)-C(5) bond length is 1.36 Å. The C(5)-S(3) bond length is 1.76 Å. The C(5)-S(4) bond length is 1.76 Å. N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(1)-O(1) bond length is 1.27 Å. The N(1)-O(2) bond length is 1.26 Å. The N(1)-O(3) bond length is 1.28 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(1), and one C(4) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(2), and one C(3) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one C(4) and one C(5) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one C(3) and one C(5) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ag(1) and one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Ag(1) and one N(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one N(1) atom. Linkers: 2 CSC1=C(SC)SC(=C2SC(SC)=C(SC)S2)S1 ,2 CSC1=[C]SC(=C2SC(SC)=C(SC)S2)S1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.55 A, density 2.39 g/cm3, surface area 3057.05 m2/g, accessible volume 0.08 cm3/g