ZnC6N3H4O4C4N3H4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1-vinyl-1,2,4-triazole molecules and one ZnC6N3H4O4 cluster. In the ZnC6N3H4O4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(6), one O(1), one O(2), and one O(3) atom. The Zn(1)-N(6) bond length is 1.99 Å. The Zn(1)-O(1) bond length is 1.99 Å. The Zn(1)-O(2) bond length is 2.04 Å. The Zn(1)-O(3) bond length is 1.94 Å. There are six inequivalent C sites. In the first C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one N(4), and one H(6) atom. The C(8)-C(7) bond length is 1.34 Å. The C(8)-N(4) bond length is 1.40 Å. The C(8)-H(6) bond length is 1.09 Å. In the second C site, C(9) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(7) atom. The C(9)-N(5) bond length is 1.32 Å. The C(9)-N(6) bond length is 1.38 Å. The C(9)-H(7) bond length is 1.09 Å. In the third C site, C(10) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(8) atom. The C(10)-N(4) bond length is 1.35 Å. The C(10)-N(6) bond length is 1.33 Å. The C(10)-H(8) bond length is 1.09 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.29 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(6)-O(3) bond length is 1.30 Å. The C(6)-O(4) bond length is 1.25 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(4) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the second N site, N(5) is bonded in a distorted water-like geometry to one C(9) and one N(4) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(9) atom. There are four inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(6) atom. Linkers: 2 [O]C(=O)/C=C/n1cncn1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.47 A, density 1.95 g/cm3, surface area 3741.15 m2/g, accessible volume 0.06 cm3/g