Tb2Co2C45N8H33(O11Cl)2(CH)3(H2O)2 crystallizes in the triclinic P-1 space group. The structure consists of six 02329_fluka molecules and four water molecules inside a Tb2Co2C45N8H33(O11Cl)2 framework. In the Tb2Co2C45N8H33(O11Cl)2 framework, there are two inequivalent Tb sites. In the first Tb site, Tb(1) is bonded in a 8-coordinate geometry to one O(11), one O(15), one O(17), one O(21), one O(6), one O(9), and two equivalent O(1) atoms. The Tb(1)-O(11) bond length is 2.31 Å. The Tb(1)-O(15) bond length is 2.34 Å. The Tb(1)-O(17) bond length is 2.39 Å. The Tb(1)-O(21) bond length is 2.28 Å. The Tb(1)-O(6) bond length is 2.36 Å. The Tb(1)-O(9) bond length is 2.42 Å. There is one shorter (2.45 Å) and one longer (2.55 Å) Tb(1)-O(1) bond length. In the second Tb site, Tb(2) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(16), one O(18), one O(22), one O(5), and two equivalent O(2) atoms. The Tb(2)-O(10) bond length is 2.42 Å. The Tb(2)-O(12) bond length is 2.31 Å. The Tb(2)-O(16) bond length is 2.34 Å. The Tb(2)-O(18) bond length is 2.40 Å. The Tb(2)-O(22) bond length is 2.28 Å. The Tb(2)-O(5) bond length is 2.36 Å. There is one shorter (2.45 Å) and one longer (2.54 Å) Tb(2)-O(2) bond length. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(3), one N(5), one N(7), and one Cl(1) atom. The Co(1)-N(1) bond length is 1.99 Å. The Co(1)-N(3) bond length is 1.91 Å. The Co(1)-N(5) bond length is 1.90 Å. The Co(1)-N(7) bond length is 1.93 Å. The Co(1)-Cl(1) bond length is 2.23 Å. In the second Co site, Co(2) is bonded in a trigonal bipyramidal geometry to one N(2), one N(4), one N(6), one N(8), and one Cl(2) atom. The Co(2)-N(2) bond length is 1.99 Å. The Co(2)-N(4) bond length is 1.91 Å. The Co(2)-N(6) bond length is 1.90 Å. The Co(2)-N(8) bond length is 1.93 Å. The Co(2)-Cl(2) bond length is 2.23 Å. There are thirty-two inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(13) atom. The C(1,2)-C(3) bond length is 1.39 Å. The C(1,2)-N(1) bond length is 1.34 Å. The C(1,2)-H(13) bond length is 1.09 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(1,2); one C(19,20); and one C(9,10) atom. The C(3)-C(19,20) bond length is 1.51 Å. The C(3)-C(9,10) bond length is 1.40 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(1,2); one C(19,20); and one C(9,10) atom. The C(4)-C(1,2) bond length is 1.39 Å. The C(4)-C(19,20) bond length is 1.51 Å. The C(4)-C(9,10) bond length is 1.40 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(17,18); one C(7,8); and one N(5) atom. The C(5)-C(17,18) bond length is 1.40 Å. The C(5)-C(7,8) bond length is 1.46 Å. The C(5)-N(5) bond length is 1.37 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(17,18); one C(7,8); and one N(6) atom. The C(6)-C(17,18) bond length is 1.40 Å. The C(6)-C(7,8) bond length is 1.46 Å. The C(6)-N(6) bond length is 1.37 Å. In the sixth C site, C(7,8) is bonded in a distorted trigonal planar geometry to one C(29), one C(5), and one N(1) atom. The C(7,8)-C(29) bond length is 1.40 Å. The C(7,8)-N(1) bond length is 1.36 Å. In the seventh C site, C(9,10) is bonded in a distorted single-bond geometry to one C(29); one C(3); and one H(15,16) atom. The C(9,10)-C(29) bond length is 1.39 Å. The C(9,10)-H(15,16) bond length is 1.09 Å. In the eighth C site, C(11,12) is bonded in a distorted trigonal planar geometry to one C(17,18); one C(21); and one H(17,18) atom. The C(11,12)-C(17,18) bond length is 1.39 Å. The C(11,12)-C(21) bond length is 1.40 Å. The C(11,12)-H(17,18) bond length is 1.09 Å. In the ninth C site, C(13,14) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(15), and one O(23) atom. The C(13,14)-C(21) bond length is 1.51 Å. The C(13,14)-O(15) bond length is 1.28 Å. The C(13,14)-O(23) bond length is 1.27 Å. In the tenth C site, C(15,16) is bonded in a distorted bent 120 degrees geometry to one C(39); one N(7); and one H(19,20) atom. The C(15,16)-C(39) bond length is 1.39 Å. The C(15,16)-N(7) bond length is 1.35 Å. The C(15,16)-H(19,20) bond length is 1.09 Å. In the eleventh C site, C(17,18) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(5); and one H(21,22) atom. The C(17,18)-H(21,22) bond length is 1.09 Å. In the twelfth C site, C(19,20) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(11), and one O(3) atom. The C(19,20)-O(11) bond length is 1.27 Å. The C(19,20)-O(3) bond length is 1.27 Å. In the thirteenth C site, C(21) is bonded in a trigonal planar geometry to one C(11,12); one C(13,14); and one C(25,26) atom. The C(21)-C(25,26) bond length is 1.40 Å. In the fourteenth C site, C(22) is bonded in a trigonal planar geometry to one C(11,12); one C(13,14); and one C(25,26) atom. The C(22)-C(11,12) bond length is 1.40 Å. The C(22)-C(13,14) bond length is 1.51 Å. The C(22)-C(25,26) bond length is 1.40 Å. In the fifteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(41,42); one N(3); and one H(23,24) atom. The C(23)-C(41,42) bond length is 1.39 Å. The C(23)-N(3) bond length is 1.35 Å. The C(23)-H(23,24) bond length is 1.09 Å. In the sixteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(41,42); one N(4); and one H(23,24) atom. The C(24)-C(41,42) bond length is 1.39 Å. The C(24)-N(4) bond length is 1.35 Å. The C(24)-H(23,24) bond length is 1.09 Å. In the seventeenth C site, C(25,26) is bonded in a distorted bent 120 degrees geometry to one C(21); one N(5); and one H(25,26) atom. The C(25,26)-N(5) bond length is 1.35 Å. The C(25,26)-H(25,26) bond length is 1.09 Å. In the eighteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(41,42); one O(5); and one O(7) atom. The C(27)-C(41,42) bond length is 1.51 Å. The C(27)-O(5) bond length is 1.27 Å. The C(27)-O(7) bond length is 1.26 Å. In the nineteenth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(41,42); one O(6); and one O(8) atom. The C(28)-C(41,42) bond length is 1.51 Å. The C(28)-O(6) bond length is 1.27 Å. The C(28)-O(8) bond length is 1.26 Å. In the twentieth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(7,8); one C(9,10); and one H(27,28) atom. The C(29)-H(27,28) bond length is 1.09 Å. In the twenty-first C site, C(30) is bonded in a distorted trigonal planar geometry to one C(7,8); one C(9,10); and one H(27,28) atom. The C(30)-C(7,8) bond length is 1.40 Å. The C(30)-C(9,10) bond length is 1.39 Å. The C(30)-H(27,28) bond length is 1.09 Å. In the twenty-second C site, C(31,32) is bonded in a distorted bent 120 degrees geometry to one C(39), one O(19), and one O(21) atom. The C(31,32)-C(39) bond length is 1.51 Å. The C(31,32)-O(19) bond length is 1.26 Å. The C(31,32)-O(21) bond length is 1.28 Å. In the twenty-third C site, C(33,34) is bonded in a distorted single-bond geometry to one C(39) and one H(29,30) atom. The C(33,34)-C(39) bond length is 1.40 Å. The C(33,34)-H(29,30) bond length is 1.09 Å. In the twenty-fourth C site, C(35) is bonded in a distorted single-bond geometry to one C(43) and one N(7) atom. The C(35)-C(43) bond length is 1.45 Å. The C(35)-N(7) bond length is 1.37 Å. In the twenty-fifth C site, C(36) is bonded in a distorted single-bond geometry to one N(8) atom. The C(36)-N(8) bond length is 1.37 Å. In the twenty-sixth C site, C(39) is bonded in a trigonal planar geometry to one C(15,16); one C(31,32); and one C(33,34) atom. In the twenty-seventh C site, C(40) is bonded in a trigonal planar geometry to one C(15,16); one C(31,32); and one C(33,34) atom. The C(40)-C(15,16) bond length is 1.39 Å. The C(40)-C(31,32) bond length is 1.51 Å. The C(40)-C(33,34) bond length is 1.40 Å. In the twenty-eighth C site, C(41,42) is bonded in a trigonal planar geometry to one C(23); one C(27); and one C(45,46) atom. The C(41,42)-C(45,46) bond length is 1.40 Å. In the twenty-ninth C site, C(43) is bonded in a distorted single-bond geometry to one C(35), one C(47), and one N(3) atom. The C(43)-C(47) bond length is 1.40 Å. The C(43)-N(3) bond length is 1.37 Å. In the thirtieth C site, C(44) is bonded in a distorted single-bond geometry to one N(4) atom. The C(44)-N(4) bond length is 1.37 Å. In the thirty-first C site, C(45,46) is bonded in a distorted single-bond geometry to one C(41,42) and one H(33,34) atom. The C(45,46)-H(33,34) bond length is 1.09 Å. In the thirty-second C site, C(47) is bonded in a distorted single-bond geometry to one C(43) and one H(35) atom. The C(47)-H(35) bond length is 1.09 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1); one C(1,2); and one C(7,8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(2); one C(1,2); and one C(7,8) atom. The N(2)-C(1,2) bond length is 1.34 Å. The N(2)-C(7,8) bond length is 1.36 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(23), and one C(43) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(2), one C(24), and one C(44) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(1); one C(25,26); and one C(5) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Co(2); one C(25,26); and one C(6) atom. The N(6)-C(25,26) bond length is 1.35 Å. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Co(1); one C(15,16); and one C(35) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Co(2); one C(15,16); and one C(36) atom. The N(8)-C(15,16) bond length is 1.35 Å. There are twenty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(9) atom. The H(1)-O(9) bond length is 0.97 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. The H(2)-O(10) bond length is 0.97 Å. In the third H site, H(3) is bonded in a distorted linear geometry to one O(8) and one O(9) atom. The H(3)-O(8) bond length is 1.59 Å. The H(3)-O(9) bond length is 1.02 Å. In the fourth H site, H(4) is bonded in a distorted linear geometry to one O(10) and one O(7) atom. The H(4)-O(10) bond length is 1.02 Å. The H(4)-O(7) bond length is 1.59 Å. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one O(17) atom. The H(9,10)-O(17) bond length is 0.97 Å. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one O(17) and one O(19) atom. The H(11,12)-O(17) bond length is 1.01 Å. The H(11,12)-O(19) bond length is 1.64 Å. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(1,2) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(1,2) atom. The H(14)-C(1,2) bond length is 1.09 Å. In the ninth H site, H(15,16) is bonded in a single-bond geometry to one C(9,10) atom. In the tenth H site, H(17,18) is bonded in a single-bond geometry to one C(11,12) atom. In the eleventh H site, H(19,20) is bonded in a single-bond geometry to one C(15,16) atom. In the twelfth H site, H(21,22) is bonded in a single-bond geometry to one C(17,18) atom. In the thirteenth H site, H(23,24) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(25,26) is bonded in a single-bond geometry to one C(25,26) atom. In the fifteenth H site, H(27,28) is bonded in a single-bond geometry to one C(29) atom. In the sixteenth H site, H(29,30) is bonded in a single-bond geometry to one C(33,34) atom. In the seventeenth H site, H(33,34) is bonded in a single-bond geometry to one C(45,46) atom. In the eighteenth H site, H(35) is bonded in a single-bond geometry to one C(47) atom. In the nineteenth H site, H(37) is bonded in a single-bond geometry to one O(1) atom. The H(37)-O(1) bond length is 1.00 Å. In the twentieth H site, H(38) is bonded in a single-bond geometry to one O(2) atom. The H(38)-O(2) bond length is 1.00 Å. In the twenty-first H site, H(39) is bonded in a distorted single-bond geometry to one O(1) and one O(3) atom. The H(39)-O(1) bond length is 1.04 Å. The H(39)-O(3) bond length is 1.55 Å. In the twenty-second H site, H(40) is bonded in a distorted single-bond geometry to one O(2) and one O(4) atom. The H(40)-O(2) bond length is 1.04 Å. The H(40)-O(4) bond length is 1.55 Å. There are twenty-two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent Tb(1), one H(37), and one H(39) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to two equivalent Tb(2), one H(38), and one H(40) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(19,20) and one H(39) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(19,20) and one H(40) atom. The O(4)-C(19,20) bond length is 1.27 Å. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Tb(2) and one C(27) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Tb(1) and one C(28) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one C(27) and one H(4) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one C(28) and one H(3) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Tb(1), one H(1), and one H(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one Tb(2), one H(2), and one H(4) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Tb(1) and one C(19,20) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Tb(2) and one C(19,20) atom. The O(12)-C(19,20) bond length is 1.27 Å. In the thirteenth O site, O(15) is bonded in a 2-coordinate geometry to one Tb(1) and one C(13,14) atom. In the fourteenth O site, O(16) is bonded in a 2-coordinate geometry to one Tb(2) and one C(13,14) atom. The O(16)-C(13,14) bond length is 1.28 Å. In the fifteenth O site, O(17) is bonded in a 3-coordinate geometry to one Tb(1); one H(11,12); and one H(9,10) atom. In the sixteenth O site, O(18) is bonded in a 3-coordinate geometry to one Tb(2); one H(11,12); and one H(9,10) atom. The O(18)-H(11,12) bond length is 1.01 Å. The O(18)-H(9,10) bond length is 0.97 Å. In the seventeenth O site, O(19) is bonded in a distorted water-like geometry to one C(31,32) and one H(11,12) atom. In the eighteenth O site, O(20) is bonded in a distorted water-like geometry to one C(31,32) and one H(11,12) atom. The O(20)-C(31,32) bond length is 1.26 Å. The O(20)-H(11,12) bond length is 1.64 Å. In the nineteenth O site, O(21) is bonded in a bent 150 degrees geometry to one Tb(1) and one C(31,32) atom. In the twentieth O site, O(22) is bonded in a bent 150 degrees geometry to one Tb(2) and one C(31,32) atom. The O(22)-C(31,32) bond length is 1.28 Å. In the twenty-first O site, O(23) is bonded in a single-bond geometry to one C(13,14) atom. In the twenty-second O site, O(24) is bonded in a single-bond geometry to one C(13,14) atom. The O(24)-C(13,14) bond length is 1.27 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Co(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Co(2) atom. Linkers: 4 [O]C(=O)C1=CC=C2[C]3C=CC(C([O])=O)=CN3[Co]3(Cl)(N2[CH]1)N1[CH]C(C([O])=O)=CC=C1C1=CC=C(C([O])=O)[CH]N13. Metal clusters: 2 O.O.O.O.O.O.O=[C]O[Tb](O[C]=O)(O[C]=O)O[C]=O.O=[C]O[Tb](O[C]=O)(O[C]=O)O[C]=O. RCSR code: flu. The MOF has largest included sphere 6.98 A, density 1.32 g/cm3, surface area 3476.63 m2/g, accessible volume 0.36 cm3/g