Co2C25P4H20O12 crystallizes in the triclinic P1 space group. There are eight inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(13), one O(25), one O(39), and one O(8) atom to form CoO4 tetrahedra that share  a cornercorner with one P(11)CO3 tetrahedra,  a cornercorner with one P(13)CO3 tetrahedra,  a cornercorner with one P(4)CO3 tetrahedra, and  a cornercorner with one P(5)CO3 tetrahedra. The Co(1)-O(13) bond length is 1.93 Å. The Co(1)-O(25) bond length is 1.95 Å. The Co(1)-O(39) bond length is 1.97 Å. The Co(1)-O(8) bond length is 1.92 Å. In the second Co site, Co(2) is bonded to one O(14), one O(26), one O(40), and one O(7) atom to form CoO4 tetrahedra that share  a cornercorner with one P(12)CO3 tetrahedra,  a cornercorner with one P(14)CO3 tetrahedra,  a cornercorner with one P(3)CO3 tetrahedra, and  a cornercorner with one P(6)CO3 tetrahedra. The Co(2)-O(14) bond length is 1.93 Å. The Co(2)-O(26) bond length is 1.95 Å. The Co(2)-O(40) bond length is 1.97 Å. The Co(2)-O(7) bond length is 1.92 Å. In the third Co site, Co(3) is bonded to one O(15), one O(27), one O(37), and one O(6) atom to form CoO4 tetrahedra that share  a cornercorner with one P(15)CO3 tetrahedra,  a cornercorner with one P(2)CO3 tetrahedra,  a cornercorner with one P(7)CO3 tetrahedra, and  a cornercorner with one P(9)CO3 tetrahedra. The Co(3)-O(15) bond length is 1.93 Å. The Co(3)-O(27) bond length is 1.95 Å. The Co(3)-O(37) bond length is 1.97 Å. The Co(3)-O(6) bond length is 1.92 Å. In the fourth Co site, Co(4) is bonded to one O(16), one O(28), one O(38), and one O(5) atom to form CoO4 tetrahedra that share  a cornercorner with one P(1)CO3 tetrahedra,  a cornercorner with one P(10)CO3 tetrahedra,  a cornercorner with one P(16)CO3 tetrahedra, and  a cornercorner with one P(8)CO3 tetrahedra. The Co(4)-O(16) bond length is 1.93 Å. The Co(4)-O(28) bond length is 1.95 Å. The Co(4)-O(38) bond length is 1.98 Å. The Co(4)-O(5) bond length is 1.92 Å. In the fifth Co site, Co(5) is bonded to one O(11), one O(21), one O(29), and one O(48) atom to form CoO4 tetrahedra that share  a cornercorner with one P(12)CO3 tetrahedra,  a cornercorner with one P(13)CO3 tetrahedra,  a cornercorner with one P(3)CO3 tetrahedra, and  a cornercorner with one P(5)CO3 tetrahedra. The Co(5)-O(11) bond length is 1.94 Å. The Co(5)-O(21) bond length is 1.93 Å. The Co(5)-O(29) bond length is 1.95 Å. The Co(5)-O(48) bond length is 1.95 Å. In the sixth Co site, Co(6) is bonded to one O(12), one O(22), one O(30), and one O(47) atom to form CoO4 tetrahedra that share  a cornercorner with one P(11)CO3 tetrahedra,  a cornercorner with one P(14)CO3 tetrahedra,  a cornercorner with one P(4)CO3 tetrahedra, and  a cornercorner with one P(6)CO3 tetrahedra. The Co(6)-O(12) bond length is 1.94 Å. The Co(6)-O(22) bond length is 1.93 Å. The Co(6)-O(30) bond length is 1.95 Å. The Co(6)-O(47) bond length is 1.95 Å. In the seventh Co site, Co(7) is bonded to one O(23), one O(31), one O(46), and one O(9) atom to form CoO4 tetrahedra that share  a cornercorner with one P(1)CO3 tetrahedra,  a cornercorner with one P(10)CO3 tetrahedra,  a cornercorner with one P(15)CO3 tetrahedra, and  a cornercorner with one P(7)CO3 tetrahedra. The Co(7)-O(23) bond length is 1.93 Å. The Co(7)-O(31) bond length is 1.95 Å. The Co(7)-O(46) bond length is 1.95 Å. The Co(7)-O(9) bond length is 1.94 Å. In the eighth Co site, Co(8) is bonded to one O(10), one O(24), one O(32), and one O(45) atom to form CoO4 tetrahedra that share  a cornercorner with one P(16)CO3 tetrahedra,  a cornercorner with one P(2)CO3 tetrahedra,  a cornercorner with one P(8)CO3 tetrahedra, and  a cornercorner with one P(9)CO3 tetrahedra. The Co(8)-O(10) bond length is 1.94 Å. The Co(8)-O(24) bond length is 1.93 Å. The Co(8)-O(32) bond length is 1.95 Å. The Co(8)-O(45) bond length is 1.95 Å. There are ninety-nine inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one C(29), one C(5), one C(53), and one C(77) atom. The C(1)-C(29) bond length is 1.54 Å. The C(1)-C(5) bond length is 1.54 Å. The C(1)-C(53) bond length is 1.54 Å. The C(1)-C(77) bond length is 1.55 Å. In the second C site, C(2) is bonded in a tetrahedral geometry to one C(30), one C(54), one C(6), and one C(78) atom. The C(2)-C(30) bond length is 1.54 Å. The C(2)-C(54) bond length is 1.54 Å. The C(2)-C(6) bond length is 1.54 Å. The C(2)-C(78) bond length is 1.55 Å. In the third C site, C(3) is bonded in a tetrahedral geometry to one C(31), one C(55), one C(7), and one C(79) atom. The C(3)-C(31) bond length is 1.54 Å. The C(3)-C(55) bond length is 1.54 Å. The C(3)-C(7) bond length is 1.54 Å. The C(3)-C(79) bond length is 1.55 Å. In the fourth C site, C(4) is bonded in a tetrahedral geometry to one C(32), one C(56), one C(8), and one C(80) atom. The C(4)-C(32) bond length is 1.54 Å. The C(4)-C(56) bond length is 1.54 Å. The C(4)-C(8) bond length is 1.54 Å. The C(4)-C(80) bond length is 1.55 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(25), and one C(9) atom. The C(5)-C(25) bond length is 1.41 Å. The C(5)-C(9) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(26) atom. The C(6)-C(10) bond length is 1.40 Å. The C(6)-C(26) bond length is 1.41 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(27), and one C(3) atom. The C(7)-C(11) bond length is 1.40 Å. The C(7)-C(27) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(28), and one C(4) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(28) bond length is 1.41 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(13); one C(5); and one H(1,4) atom. The C(9)-C(13) bond length is 1.40 Å. The C(9)-H(1,4) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(14), one C(6), and one H(2) atom. The C(10)-C(14) bond length is 1.40 Å. The C(10)-H(2) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(15), one C(7), and one H(3) atom. The C(11)-C(15) bond length is 1.40 Å. The C(11)-H(3) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(16); one C(8); and one H(1,4) atom. The C(12)-C(16) bond length is 1.40 Å. The C(12)-H(1,4) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(17), one C(9), and one H(5) atom. The C(13)-C(17) bond length is 1.40 Å. The C(13)-H(5) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(10); one C(18); and one H(6,8) atom. The C(14)-C(18) bond length is 1.40 Å. The C(14)-H(6,8) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(11), one C(19), and one H(7) atom. The C(15)-C(19) bond length is 1.40 Å. The C(15)-H(7) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(12); one C(20); and one H(6,8) atom. The C(16)-C(20) bond length is 1.40 Å. The C(16)-H(6,8) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(13), one C(21), and one P(5) atom. The C(17)-C(21) bond length is 1.41 Å. The C(17)-P(5) bond length is 1.80 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(14), one C(22), and one P(6) atom. The C(18)-C(22) bond length is 1.41 Å. The C(18)-P(6) bond length is 1.80 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(15), one C(23), and one P(7) atom. The C(19)-C(23) bond length is 1.41 Å. The C(19)-P(7) bond length is 1.80 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(16), one C(24), and one P(8) atom. The C(20)-C(24) bond length is 1.41 Å. The C(20)-P(8) bond length is 1.80 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(17), one C(25), and one H(9) atom. The C(21)-C(25) bond length is 1.39 Å. The C(21)-H(9) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(18); one C(26); and one H(10,12) atom. The C(22)-C(26) bond length is 1.39 Å. The C(22)-H(10,12) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted trigonal planar geometry to one C(19), one C(27), and one H(11) atom. The C(23)-C(27) bond length is 1.39 Å. The C(23)-H(11) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(20); one C(28); and one H(10,12) atom. The C(24)-C(28) bond length is 1.39 Å. The C(24)-H(10,12) bond length is 1.09 Å. In the twenty-fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(21), one C(5), and one H(13) atom. The C(25)-H(13) bond length is 1.09 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(22), one C(6), and one H(14) atom. The C(26)-H(14) bond length is 1.09 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(23), one C(7), and one H(15) atom. The C(27)-H(15) bond length is 1.09 Å. In the twenty-eighth C site, C(28) is bonded in a distorted single-bond geometry to one C(24), one C(8), and one H(16) atom. The C(28)-H(16) bond length is 1.09 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(1), one C(33), and one C(49) atom. The C(29)-C(33) bond length is 1.41 Å. The C(29)-C(49) bond length is 1.40 Å. In the thirtieth C site, C(30) is bonded in a trigonal planar geometry to one C(2), one C(34), and one C(50) atom. The C(30)-C(34) bond length is 1.41 Å. The C(30)-C(50) bond length is 1.40 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one C(3), one C(35), and one C(51) atom. The C(31)-C(35) bond length is 1.41 Å. The C(31)-C(51) bond length is 1.40 Å. In the thirty-second C site, C(32) is bonded in a trigonal planar geometry to one C(36), one C(4), and one C(52) atom. The C(32)-C(36) bond length is 1.41 Å. The C(32)-C(52) bond length is 1.40 Å. In the thirty-third C site, C(33) is bonded in a distorted single-bond geometry to one C(29), one C(37), and one H(17) atom. The C(33)-C(37) bond length is 1.39 Å. The C(33)-H(17) bond length is 1.09 Å. In the thirty-fourth C site, C(34) is bonded in a distorted single-bond geometry to one C(30), one C(38), and one H(18) atom. The C(34)-C(38) bond length is 1.39 Å. The C(34)-H(18) bond length is 1.09 Å. In the thirty-fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(31), one C(39), and one H(19) atom. The C(35)-C(39) bond length is 1.39 Å. The C(35)-H(19) bond length is 1.09 Å. In the thirty-sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(32), one C(40), and one H(20) atom. The C(36)-C(40) bond length is 1.39 Å. The C(36)-H(20) bond length is 1.09 Å. In the thirty-seventh C site, C(37) is bonded in a distorted trigonal planar geometry to one C(33); one C(41); and one H(21,22) atom. The C(37)-C(41) bond length is 1.41 Å. The C(37)-H(21,22) bond length is 1.09 Å. In the thirty-eighth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(34); one C(42); and one H(21,22) atom. The C(38)-C(42) bond length is 1.41 Å. The C(38)-H(21,22) bond length is 1.09 Å. In the thirty-ninth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(35); one C(43); and one H(23,24) atom. The C(39)-C(43) bond length is 1.41 Å. The C(39)-H(23,24) bond length is 1.09 Å. In the fortieth C site, C(40) is bonded in a distorted trigonal planar geometry to one C(36); one C(44); and one H(23,24) atom. The C(40)-C(44) bond length is 1.41 Å. The C(40)-H(23,24) bond length is 1.09 Å. In the forty-first C site, C(41) is bonded in a trigonal planar geometry to one C(37); one C(45,47); and one P(13) atom. The C(41)-C(45,47) bond length is 1.40 Å. The C(41)-P(13) bond length is 1.79 Å. In the forty-second C site, C(42) is bonded in a trigonal planar geometry to one C(38), one C(46), and one P(14) atom. The C(42)-C(46) bond length is 1.40 Å. The C(42)-P(14) bond length is 1.79 Å. In the forty-third C site, C(43) is bonded in a trigonal planar geometry to one C(39); one C(45,47); and one P(15) atom. The C(43)-C(45,47) bond length is 1.40 Å. The C(43)-P(15) bond length is 1.79 Å. In the forty-fourth C site, C(44) is bonded in a trigonal planar geometry to one C(40), one C(48), and one P(16) atom. The C(44)-C(48) bond length is 1.40 Å. The C(44)-P(16) bond length is 1.79 Å. In the forty-fifth C site, C(45,47) is bonded in a distorted single-bond geometry to one C(41) and one H(25,26) atom. The C(45,47)-H(25,26) bond length is 1.09 Å. In the forty-sixth C site, C(46) is bonded in a distorted single-bond geometry to one C(42) and one H(25,26) atom. The C(46)-H(25,26) bond length is 1.09 Å. In the forty-seventh C site, C(48) is bonded in a distorted single-bond geometry to one C(44) and one H(27,28) atom. The C(48)-H(27,28) bond length is 1.09 Å. In the forty-eighth C site, C(49) is bonded in a distorted single-bond geometry to one C(29) and one H(29,30,32) atom. The C(49)-H(29,30,32) bond length is 1.09 Å. In the forty-ninth C site, C(50) is bonded in a distorted single-bond geometry to one C(30) and one H(29,30,32) atom. The C(50)-H(29,30,32) bond length is 1.09 Å. In the fiftieth C site, C(51) is bonded in a distorted single-bond geometry to one C(31) and one H(31) atom. The C(51)-H(31) bond length is 1.09 Å. In the fifty-first C site, C(52) is bonded in a distorted single-bond geometry to one C(32) and one H(29,30,32) atom. The C(52)-H(29,30,32) bond length is 1.09 Å. In the fifty-second C site, C(53) is bonded in a trigonal planar geometry to one C(1), one C(57), and one C(73) atom. The C(53)-C(57) bond length is 1.40 Å. The C(53)-C(73) bond length is 1.41 Å. In the fifty-third C site, C(54) is bonded in a trigonal planar geometry to one C(2), one C(58), and one C(74) atom. The C(54)-C(58) bond length is 1.40 Å. The C(54)-C(74) bond length is 1.41 Å. In the fifty-fourth C site, C(55) is bonded in a trigonal planar geometry to one C(3), one C(59), and one C(75) atom. The C(55)-C(59) bond length is 1.40 Å. The C(55)-C(75) bond length is 1.41 Å. In the fifty-fifth C site, C(56) is bonded in a trigonal planar geometry to one C(4), one C(60), and one C(76) atom. The C(56)-C(60) bond length is 1.40 Å. The C(56)-C(76) bond length is 1.41 Å. In the fifty-sixth C site, C(57) is bonded in a distorted single-bond geometry to one C(53) and one H(33) atom. The C(57)-H(33) bond length is 1.09 Å. In the fifty-seventh C site, C(58) is bonded in a distorted single-bond geometry to one C(54) and one H(34,36) atom. The C(58)-H(34,36) bond length is 1.09 Å. In the fifty-eighth C site, C(59) is bonded in a distorted single-bond geometry to one C(55) and one H(35) atom. The C(59)-H(35) bond length is 1.09 Å. In the fifty-ninth C site, C(60) is bonded in a distorted single-bond geometry to one C(56) and one H(34,36) atom. The C(60)-H(34,36) bond length is 1.09 Å. In the sixtieth C site, C(61) is bonded in a distorted single-bond geometry to one C(65) and one H(37,38) atom. The C(61)-C(65) bond length is 1.40 Å. The C(61)-H(37,38) bond length is 1.09 Å. In the sixty-first C site, C(62) is bonded in a distorted single-bond geometry to one C(66) and one H(37,38) atom. The C(62)-C(66) bond length is 1.40 Å. The C(62)-H(37,38) bond length is 1.09 Å. In the sixty-second C site, C(63) is bonded in a distorted single-bond geometry to one C(67) and one H(39) atom. The C(63)-C(67) bond length is 1.40 Å. The C(63)-H(39) bond length is 1.09 Å. In the sixty-third C site, C(64) is bonded in a distorted single-bond geometry to one C(68) and one H(40) atom. The C(64)-C(68) bond length is 1.40 Å. The C(64)-H(40) bond length is 1.09 Å. In the sixty-fourth C site, C(65) is bonded in a trigonal planar geometry to one C(61), one C(69), and one P(9) atom. The C(65)-C(69) bond length is 1.41 Å. The C(65)-P(9) bond length is 1.79 Å. In the sixty-fifth C site, C(66) is bonded in a trigonal planar geometry to one C(62), one C(70), and one P(10) atom. The C(66)-C(70) bond length is 1.41 Å. The C(66)-P(10) bond length is 1.79 Å. In the sixty-sixth C site, C(67) is bonded in a trigonal planar geometry to one C(63), one C(71), and one P(11) atom. The C(67)-C(71) bond length is 1.41 Å. The C(67)-P(11) bond length is 1.79 Å. In the sixty-seventh C site, C(68) is bonded in a trigonal planar geometry to one C(64), one C(72), and one P(12) atom. The C(68)-C(72) bond length is 1.41 Å. The C(68)-P(12) bond length is 1.79 Å. In the sixty-eighth C site, C(69) is bonded in a distorted single-bond geometry to one C(65) and one H(41,42) atom. The C(69)-H(41,42) bond length is 1.09 Å. In the sixty-ninth C site, C(70) is bonded in a distorted single-bond geometry to one C(66) and one H(41,42) atom. The C(70)-H(41,42) bond length is 1.09 Å. In the seventieth C site, C(71) is bonded in a distorted trigonal planar geometry to one C(67), one C(75), and one H(43) atom. The C(71)-C(75) bond length is 1.38 Å. The C(71)-H(43) bond length is 1.09 Å. In the seventy-first C site, C(72) is bonded in a distorted trigonal planar geometry to one C(68), one C(76), and one H(44) atom. The C(72)-C(76) bond length is 1.39 Å. The C(72)-H(44) bond length is 1.09 Å. In the seventy-second C site, C(73) is bonded in a distorted single-bond geometry to one C(53) and one H(45) atom. The C(73)-H(45) bond length is 1.09 Å. In the seventy-third C site, C(74) is bonded in a distorted single-bond geometry to one C(54) and one H(46) atom. The C(74)-H(46) bond length is 1.09 Å. In the seventy-fourth C site, C(75) is bonded in a distorted single-bond geometry to one C(55), one C(71), and one H(47) atom. The C(75)-H(47) bond length is 1.09 Å. In the seventy-fifth C site, C(76) is bonded in a distorted single-bond geometry to one C(56), one C(72), and one H(48) atom. The C(76)-H(48) bond length is 1.09 Å. In the seventy-sixth C site, C(77) is bonded in a trigonal planar geometry to one C(1), one C(81), and one C(97) atom. The C(77)-C(81) bond length is 1.40 Å. The C(77)-C(97) bond length is 1.41 Å. In the seventy-seventh C site, C(78) is bonded in a trigonal planar geometry to one C(2), one C(82), and one C(98) atom. The C(78)-C(82) bond length is 1.40 Å. The C(78)-C(98) bond length is 1.41 Å. In the seventy-eighth C site, C(79) is bonded in a trigonal planar geometry to one C(3), one C(83), and one C(99) atom. The C(79)-C(83) bond length is 1.40 Å. The C(79)-C(99) bond length is 1.41 Å. In the seventy-ninth C site, C(80) is bonded in a trigonal planar geometry to one C(100), one C(4), and one C(84) atom. The C(80)-C(100) bond length is 1.41 Å. The C(80)-C(84) bond length is 1.40 Å. In the eightieth C site, C(81) is bonded in a distorted single-bond geometry to one C(77); one C(85); and one H(49,50) atom. The C(81)-C(85) bond length is 1.40 Å. The C(81)-H(49,50) bond length is 1.09 Å. In the eighty-first C site, C(82) is bonded in a distorted single-bond geometry to one C(78); one C(86); and one H(49,50) atom. The C(82)-C(86) bond length is 1.39 Å. The C(82)-H(49,50) bond length is 1.09 Å. In the eighty-second C site, C(83) is bonded in a distorted single-bond geometry to one C(79), one C(87), and one H(51) atom. The C(83)-C(87) bond length is 1.39 Å. The C(83)-H(51) bond length is 1.09 Å. In the eighty-third C site, C(84) is bonded in a distorted single-bond geometry to one C(80), one C(88), and one H(52) atom. The C(84)-C(88) bond length is 1.39 Å. The C(84)-H(52) bond length is 1.09 Å. In the eighty-fourth C site, C(85) is bonded in a distorted trigonal planar geometry to one C(81), one C(89), and one H(53) atom. The C(85)-C(89) bond length is 1.40 Å. The C(85)-H(53) bond length is 1.09 Å. In the eighty-fifth C site, C(86) is bonded in a distorted trigonal planar geometry to one C(82), one C(90), and one H(54) atom. The C(86)-C(90) bond length is 1.40 Å. The C(86)-H(54) bond length is 1.09 Å. In the eighty-sixth C site, C(87) is bonded in a distorted trigonal planar geometry to one C(83), one C(91), and one H(55) atom. The C(87)-C(91) bond length is 1.40 Å. The C(87)-H(55) bond length is 1.09 Å. In the eighty-seventh C site, C(88) is bonded in a distorted trigonal planar geometry to one C(84), one C(92), and one H(56) atom. The C(88)-C(92) bond length is 1.40 Å. The C(88)-H(56) bond length is 1.09 Å. In the eighty-eighth C site, C(89) is bonded in a trigonal planar geometry to one C(85), one C(93), and one P(1) atom. The C(89)-C(93) bond length is 1.40 Å. The C(89)-P(1) bond length is 1.79 Å. In the eighty-ninth C site, C(90) is bonded in a trigonal planar geometry to one C(86), one C(94), and one P(2) atom. The C(90)-C(94) bond length is 1.40 Å. The C(90)-P(2) bond length is 1.80 Å. In the ninetieth C site, C(91) is bonded in a trigonal planar geometry to one C(87), one C(95), and one P(3) atom. The C(91)-C(95) bond length is 1.40 Å. The C(91)-P(3) bond length is 1.79 Å. In the ninety-first C site, C(92) is bonded in a trigonal planar geometry to one C(88), one C(96), and one P(4) atom. The C(92)-C(96) bond length is 1.40 Å. The C(92)-P(4) bond length is 1.79 Å. In the ninety-second C site, C(93) is bonded in a distorted single-bond geometry to one C(89) and one H(57) atom. The C(93)-H(57) bond length is 1.09 Å. In the ninety-third C site, C(94) is bonded in a distorted single-bond geometry to one C(90) and one H(58) atom. The C(94)-H(58) bond length is 1.09 Å. In the ninety-fourth C site, C(95) is bonded in a distorted single-bond geometry to one C(91) and one H(59) atom. The C(95)-H(59) bond length is 1.09 Å. In the ninety-fifth C site, C(96) is bonded in a distorted single-bond geometry to one C(92) and one H(60) atom. The C(96)-H(60) bond length is 1.09 Å. In the ninety-sixth C site, C(97) is bonded in a distorted single-bond geometry to one C(77) and one H(61,62,64) atom. The C(97)-H(61,62,64) bond length is 1.09 Å. In the ninety-seventh C site, C(98) is bonded in a distorted single-bond geometry to one C(78) and one H(61,62,64) atom. The C(98)-H(61,62,64) bond length is 1.09 Å. In the ninety-eighth C site, C(99) is bonded in a distorted single-bond geometry to one C(79) and one H(63) atom. The C(99)-H(63) bond length is 1.09 Å. In the ninety-ninth C site, C(100) is bonded in a distorted single-bond geometry to one C(80) and one H(61,62,64) atom. The C(100)-H(61,62,64) bond length is 1.09 Å. There are sixteen inequivalent P sites. In the first P site, P(1) is bonded to one C(89), one O(1), one O(5), and one O(9) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(4)O4 tetrahedra and  a cornercorner with one Co(7)O4 tetrahedra. The P(1)-O(1) bond length is 1.59 Å. The P(1)-O(5) bond length is 1.53 Å. The P(1)-O(9) bond length is 1.53 Å. In the second P site, P(2) is bonded to one C(90), one O(10), one O(2), and one O(6) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(3)O4 tetrahedra and  a cornercorner with one Co(8)O4 tetrahedra. The P(2)-O(10) bond length is 1.53 Å. The P(2)-O(2) bond length is 1.59 Å. The P(2)-O(6) bond length is 1.53 Å. In the third P site, P(3) is bonded to one C(91), one O(11), one O(3), and one O(7) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(2)O4 tetrahedra and  a cornercorner with one Co(5)O4 tetrahedra. The P(3)-O(11) bond length is 1.53 Å. The P(3)-O(3) bond length is 1.59 Å. The P(3)-O(7) bond length is 1.53 Å. In the fourth P site, P(4) is bonded to one C(92), one O(12), one O(4), and one O(8) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(1)O4 tetrahedra and  a cornercorner with one Co(6)O4 tetrahedra. The P(4)-O(12) bond length is 1.53 Å. The P(4)-O(4) bond length is 1.59 Å. The P(4)-O(8) bond length is 1.53 Å. In the fifth P site, P(5) is bonded to one C(17), one O(13), one O(17), and one O(21) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(1)O4 tetrahedra and  a cornercorner with one Co(5)O4 tetrahedra. The P(5)-O(13) bond length is 1.52 Å. The P(5)-O(17) bond length is 1.61 Å. The P(5)-O(21) bond length is 1.52 Å. In the sixth P site, P(6) is bonded to one C(18), one O(14), one O(18), and one O(22) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(2)O4 tetrahedra and  a cornercorner with one Co(6)O4 tetrahedra. The P(6)-O(14) bond length is 1.52 Å. The P(6)-O(18) bond length is 1.61 Å. The P(6)-O(22) bond length is 1.52 Å. In the seventh P site, P(7) is bonded to one C(19), one O(15), one O(19), and one O(23) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(3)O4 tetrahedra and  a cornercorner with one Co(7)O4 tetrahedra. The P(7)-O(15) bond length is 1.52 Å. The P(7)-O(19) bond length is 1.61 Å. The P(7)-O(23) bond length is 1.52 Å. In the eighth P site, P(8) is bonded to one C(20), one O(16), one O(20), and one O(24) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(4)O4 tetrahedra and  a cornercorner with one Co(8)O4 tetrahedra. The P(8)-O(16) bond length is 1.52 Å. The P(8)-O(20) bond length is 1.61 Å. The P(8)-O(24) bond length is 1.52 Å. In the ninth P site, P(9) is bonded to one C(65), one O(37), one O(41), and one O(45) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(3)O4 tetrahedra and  a cornercorner with one Co(8)O4 tetrahedra. The P(9)-O(37) bond length is 1.53 Å. The P(9)-O(41) bond length is 1.65 Å. The P(9)-O(45) bond length is 1.51 Å. In the tenth P site, P(10) is bonded to one C(66), one O(38), one O(42), and one O(46) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(4)O4 tetrahedra and  a cornercorner with one Co(7)O4 tetrahedra. The P(10)-O(38) bond length is 1.53 Å. The P(10)-O(42) bond length is 1.65 Å. The P(10)-O(46) bond length is 1.50 Å. In the eleventh P site, P(11) is bonded to one C(67), one O(39), one O(43), and one O(47) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(1)O4 tetrahedra and  a cornercorner with one Co(6)O4 tetrahedra. The P(11)-O(39) bond length is 1.53 Å. The P(11)-O(43) bond length is 1.65 Å. The P(11)-O(47) bond length is 1.51 Å. In the twelfth P site, P(12) is bonded to one C(68), one O(40), one O(44), and one O(48) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(2)O4 tetrahedra and  a cornercorner with one Co(5)O4 tetrahedra. The P(12)-O(40) bond length is 1.53 Å. The P(12)-O(44) bond length is 1.65 Å. The P(12)-O(48) bond length is 1.51 Å. In the thirteenth P site, P(13) is bonded to one C(41), one O(25), one O(29), and one O(33) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(1)O4 tetrahedra and  a cornercorner with one Co(5)O4 tetrahedra. The P(13)-O(25) bond length is 1.52 Å. The P(13)-O(29) bond length is 1.51 Å. The P(13)-O(33) bond length is 1.63 Å. In the fourteenth P site, P(14) is bonded to one C(42), one O(26), one O(30), and one O(34) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(2)O4 tetrahedra and  a cornercorner with one Co(6)O4 tetrahedra. The P(14)-O(26) bond length is 1.52 Å. The P(14)-O(30) bond length is 1.51 Å. The P(14)-O(34) bond length is 1.63 Å. In the fifteenth P site, P(15) is bonded to one C(43), one O(27), one O(31), and one O(35) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(3)O4 tetrahedra and  a cornercorner with one Co(7)O4 tetrahedra. The P(15)-O(27) bond length is 1.52 Å. The P(15)-O(31) bond length is 1.51 Å. The P(15)-O(35) bond length is 1.63 Å. In the sixteenth P site, P(16) is bonded to one C(44), one O(28), one O(32), and one O(36) atom to form PCO3 tetrahedra that share  a cornercorner with one Co(4)O4 tetrahedra and  a cornercorner with one Co(8)O4 tetrahedra. The P(16)-O(28) bond length is 1.52 Å. The P(16)-O(32) bond length is 1.51 Å. The P(16)-O(36) bond length is 1.63 Å. There are sixty-two inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(6,8) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(10,12) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(25) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(26) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(27) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(28) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(33) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(34) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(35) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(36) atom. In the eighteenth H site, H(21,22) is bonded in a single-bond geometry to one C(37) atom. In the nineteenth H site, H(23,24) is bonded in a single-bond geometry to one C(39) atom. In the twentieth H site, H(25,26) is bonded in a single-bond geometry to one C(45,47) atom. In the twenty-first H site, H(27,28) is bonded in a single-bond geometry to one C(45,47) atom. The H(27,28)-C(45,47) bond length is 1.09 Å. In the twenty-second H site, H(29,30,32) is bonded in a single-bond geometry to one C(49) atom. In the twenty-third H site, H(31) is bonded in a single-bond geometry to one C(51) atom. In the twenty-fourth H site, H(33) is bonded in a single-bond geometry to one C(57) atom. In the twenty-fifth H site, H(34,36) is bonded in a single-bond geometry to one C(58) atom. In the twenty-sixth H site, H(35) is bonded in a single-bond geometry to one C(59) atom. In the twenty-seventh H site, H(37,38) is bonded in a single-bond geometry to one C(61) atom. In the twenty-eighth H site, H(39) is bonded in a single-bond geometry to one C(63) atom. In the twenty-ninth H site, H(40) is bonded in a single-bond geometry to one C(64) atom. In the thirtieth H site, H(41,42) is bonded in a single-bond geometry to one C(69) atom. In the thirty-first H site, H(43) is bonded in a single-bond geometry to one C(71) atom. In the thirty-second H site, H(44) is bonded in a single-bond geometry to one C(72) atom. In the thirty-third H site, H(45) is bonded in a single-bond geometry to one C(73) atom. In the thirty-fourth H site, H(46) is bonded in a single-bond geometry to one C(74) atom. In the thirty-fifth H site, H(47) is bonded in a single-bond geometry to one C(75) atom. In the thirty-sixth H site, H(48) is bonded in a single-bond geometry to one C(76) atom. In the thirty-seventh H site, H(49,50) is bonded in a single-bond geometry to one C(81) atom. In the thirty-eighth H site, H(51) is bonded in a single-bond geometry to one C(83) atom. In the thirty-ninth H site, H(52) is bonded in a single-bond geometry to one C(84) atom. In the fortieth H site, H(53) is bonded in a single-bond geometry to one C(85) atom. In the forty-first H site, H(54) is bonded in a single-bond geometry to one C(86) atom. In the forty-second H site, H(55) is bonded in a single-bond geometry to one C(87) atom. In the forty-third H site, H(56) is bonded in a single-bond geometry to one C(88) atom. In the forty-fourth H site, H(57) is bonded in a single-bond geometry to one C(93) atom. In the forty-fifth H site, H(58) is bonded in a single-bond geometry to one C(94) atom. In the forty-sixth H site, H(59) is bonded in a single-bond geometry to one C(95) atom. In the forty-seventh H site, H(60) is bonded in a single-bond geometry to one C(96) atom. In the forty-eighth H site, H(61,62,64) is bonded in a single-bond geometry to one C(97) atom. In the forty-ninth H site, H(63) is bonded in a single-bond geometry to one C(99) atom. In the fiftieth H site, H(65) is bonded in a distorted single-bond geometry to one O(1) atom. The H(65)-O(1) bond length is 1.00 Å. In the fifty-first H site, H(66) is bonded in a distorted single-bond geometry to one O(2) atom. The H(66)-O(2) bond length is 1.00 Å. In the fifty-second H site, H(67) is bonded in a distorted single-bond geometry to one O(3) atom. The H(67)-O(3) bond length is 1.00 Å. In the fifty-third H site, H(68) is bonded in a distorted single-bond geometry to one O(4) atom. The H(68)-O(4) bond length is 1.00 Å. In the fifty-fourth H site, H(69,71) is bonded in a single-bond geometry to one O(17) atom. The H(69,71)-O(17) bond length is 0.97 Å. In the fifty-fifth H site, H(70) is bonded in a single-bond geometry to one O(18) atom. The H(70)-O(18) bond length is 0.97 Å. In the fifty-sixth H site, H(72) is bonded in a single-bond geometry to one O(20) atom. The H(72)-O(20) bond length is 0.97 Å. In the fifty-seventh H site, H(73) is bonded in a single-bond geometry to one O(33) atom. The H(73)-O(33) bond length is 0.99 Å. In the fifty-eighth H site, H(74) is bonded in a single-bond geometry to one O(34) atom. The H(74)-O(34) bond length is 0.99 Å. In the fifty-ninth H site, H(75) is bonded in a single-bond geometry to one O(35) atom. The H(75)-O(35) bond length is 0.99 Å. In the sixtieth H site, H(76) is bonded in a single-bond geometry to one O(36) atom. The H(76)-O(36) bond length is 0.99 Å. In the sixty-first H site, H(77,79) is bonded in a single-bond geometry to one O(41) atom. The H(77,79)-O(41) bond length is 0.98 Å. In the sixty-second H site, H(78,80) is bonded in a single-bond geometry to one O(42) atom. The H(78,80)-O(42) bond length is 0.98 Å. There are forty-eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one H(65) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(2) and one H(66) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(3) and one H(67) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(4) and one H(68) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Co(4) and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Co(3) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one P(4) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Co(7) and one P(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Co(8) and one P(2) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Co(5) and one P(3) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Co(6) and one P(4) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Co(1) and one P(5) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Co(2) and one P(6) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Co(3) and one P(7) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Co(4) and one P(8) atom. In the seventeenth O site, O(17) is bonded in a water-like geometry to one P(5) and one H(69,71) atom. In the eighteenth O site, O(18) is bonded in a water-like geometry to one P(6) and one H(70) atom. In the nineteenth O site, O(19) is bonded in a water-like geometry to one P(7) and one H(69,71) atom. The O(19)-H(69,71) bond length is 0.97 Å. In the twentieth O site, O(20) is bonded in a water-like geometry to one P(8) and one H(72) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 120 degrees geometry to one Co(5) and one P(5) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Co(6) and one P(6) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 120 degrees geometry to one Co(7) and one P(7) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 120 degrees geometry to one Co(8) and one P(8) atom. In the twenty-fifth O site, O(25) is bonded in a bent 120 degrees geometry to one Co(1) and one P(13) atom. In the twenty-sixth O site, O(26) is bonded in a bent 120 degrees geometry to one Co(2) and one P(14) atom. In the twenty-seventh O site, O(27) is bonded in a bent 120 degrees geometry to one Co(3) and one P(15) atom. In the twenty-eighth O site, O(28) is bonded in a bent 120 degrees geometry to one Co(4) and one P(16) atom. In the twenty-ninth O site, O(29) is bonded in a distorted bent 150 degrees geometry to one Co(5) and one P(13) atom. In the thirtieth O site, O(30) is bonded in a distorted bent 150 degrees geometry to one Co(6) and one P(14) atom. In the thirty-first O site, O(31) is bonded in a distorted bent 150 degrees geometry to one Co(7) and one P(15) atom. In the thirty-second O site, O(32) is bonded in a distorted bent 150 degrees geometry to one Co(8) and one P(16) atom. In the thirty-third O site, O(33) is bonded in a distorted bent 120 degrees geometry to one P(13) and one H(73) atom. In the thirty-fourth O site, O(34) is bonded in a distorted bent 120 degrees geometry to one P(14) and one H(74) atom. In the thirty-fifth O site, O(35) is bonded in a distorted bent 120 degrees geometry to one P(15) and one H(75) atom. In the thirty-sixth O site, O(36) is bonded in a distorted bent 120 degrees geometry to one P(16) and one H(76) atom. In the thirty-seventh O site, O(37) is bonded in a bent 120 degrees geometry to one Co(3) and one P(9) atom. In the thirty-eighth O site, O(38) is bonded in a bent 120 degrees geometry to one Co(4) and one P(10) atom. In the thirty-ninth O site, O(39) is bonded in a bent 120 degrees geometry to one Co(1) and one P(11) atom. In the fortieth O site, O(40) is bonded in a bent 120 degrees geometry to one Co(2) and one P(12) atom. In the forty-first O site, O(41) is bonded in a water-like geometry to one P(9) and one H(77,79) atom. In the forty-second O site, O(42) is bonded in a water-like geometry to one P(10) and one H(78,80) atom. In the forty-third O site, O(43) is bonded in a water-like geometry to one P(11) and one H(77,79) atom. The O(43)-H(77,79) bond length is 0.98 Å. In the forty-fourth O site, O(44) is bonded in a water-like geometry to one P(12) and one H(78,80) atom. The O(44)-H(78,80) bond length is 0.98 Å. In the forty-fifth O site, O(45) is bonded in a bent 150 degrees geometry to one Co(8) and one P(9) atom. In the forty-sixth O site, O(46) is bonded in a bent 150 degrees geometry to one Co(7) and one P(10) atom. In the forty-seventh O site, O(47) is bonded in a bent 150 degrees geometry to one Co(6) and one P(11) atom. In the forty-eighth O site, O(48) is bonded in a bent 150 degrees geometry to one Co(5) and one P(12) atom. Linkers: 4 [O]P(=O)(O)c1ccc(C(c2ccc(P([O])(=O)O)cc2)(c2ccc(P([O])(=O)O)cc2)c2ccc(P([O])(=O)O)cc2)cc1. Metal clusters: 8 [Co]. The MOF has largest included sphere 5.17 A, density 1.23 g/cm3, surface area 3904.21 m2/g, accessible volume 0.40 cm3/g