CdC15H9(N3O2)2(CH)3 is Indium-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and four CdC15H9(N3O2)2 clusters. In each CdC15H9(N3O2)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(4), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.29 Å. The Cd(1)-N(4) bond length is 2.29 Å. The Cd(1)-O(1) bond length is 2.25 Å. The Cd(1)-O(2) bond length is 2.59 Å. The Cd(1)-O(3) bond length is 2.60 Å. The Cd(1)-O(4) bond length is 2.29 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-N(3) bond length is 1.32 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(2) atom. The C(2)-N(1) bond length is 1.33 Å. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one N(2) atom. The C(3)-N(2) bond length is 1.42 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-C(9) bond length is 1.50 Å. In the sixth C site, C(7) is bonded in a single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(2) atom. The C(9)-O(1) bond length is 1.28 Å. The C(9)-O(2) bond length is 1.27 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(7) atom. The C(10)-N(4) bond length is 1.37 Å. The C(10)-N(6) bond length is 1.33 Å. The C(10)-H(7) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(8) atom. The C(11)-N(4) bond length is 1.33 Å. The C(11)-N(5) bond length is 1.35 Å. The C(11)-H(8) bond length is 1.08 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one N(5) atom. The C(12)-N(5) bond length is 1.42 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(10) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(10) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(18) bond length is 1.50 Å. In the thirteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(11) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(11) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(17)-H(12) bond length is 1.09 Å. In the fifteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(3), and one O(4) atom. The C(18)-O(3) bond length is 1.27 Å. The C(18)-O(4) bond length is 1.28 Å. There are six inequivalent N sites. In the first N site, N(2) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one N(3) atom. The N(2)-N(3) bond length is 1.37 Å. In the second N site, N(3) is bonded in a distorted water-like geometry to one C(1) and one N(2) atom. In the third N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one C(11) atom. In the fourth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(11), one C(12), and one N(6) atom. The N(5)-N(6) bond length is 1.37 Å. In the fifth N site, N(6) is bonded in a distorted single-bond geometry to one C(10) and one N(5) atom. In the sixth N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cd(1) and one C(9) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cd(1) and one C(9) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cd(1) and one C(18) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cd(1) and one C(18) atom. Linkers: 1 O=[C]O[Cd].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH][N].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/[C]=C\[C].[C]1=N[N]C=N1.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]C=[CH].[C][CH].[C][CH][C].[C][C].[C][C]O[Cd].[C][C]O[Cd].[C][N][C][N].[C][N][N].[C][N][N].[Cd].[Cd].[Cd].[Cd].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][Cd] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[N].[CH][N].[CH][N].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/[C]=[C]\[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C][CH].[C][C].[C][C].[C][C]/[C]=[C]\[C].[C][C][C].[C][C][C].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[Cd].[Cd].[Cd].[Cd].[Cd].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][N].[N][N].[N][N].[N][N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][Cd].[O][Cd].[O][Cd] ,1 [CH]=C[C]C(=O)O[Cd@](OC(=O)c1ccc(N2[CH]N=C[N]2)cc1)(N1[CH]N([C]C=[CH])N=C1)N1[CH]N(c2ccc(C([O])=O)cc2)N=C1 ,1 [C][C](C=[CH])N1[CH]N([Cd@@](OC(=O)[C]=[CH])(OC(=O)c2ccc(N3[CH]N=C[N]3)cc2)N2[CH]N(c3ccc(C([O])=O)cc3)N=C2)C=N1. Metal clusters: 1 O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 5.91 A, density 1.14 g/cm3, surface area 4347.86 m2/g, accessible volume 0.45 cm3/g