CuC8H9(NO2)2(CH3)2C2H4S is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two dimethyl sulfide molecules, and one CuC8H9(NO2)2 cluster. In the CuC8H9(NO2)2 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-N(2) bond length is 2.24 Å. The Cu(1)-O(1) bond length is 2.02 Å. The Cu(1)-O(2) bond length is 2.01 Å. The Cu(1)-O(3) bond length is 2.01 Å. The Cu(1)-O(4) bond length is 2.00 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(2) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.49 Å. The C(3)-N(2) bond length is 1.35 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(7) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(7) bond length is 1.08 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(7), and one N(1) atom. The C(5)-C(7) bond length is 1.49 Å. The C(5)-N(1) bond length is 1.36 Å. In the fifth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one H(10), one H(8), and one H(9) atom. The C(6)-H(10) bond length is 1.10 Å. The C(6)-H(8) bond length is 1.10 Å. The C(6)-H(9) bond length is 1.10 Å. In the sixth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one H(11), one H(12), and one H(13) atom. The C(7)-H(11) bond length is 1.09 Å. The C(7)-H(12) bond length is 1.10 Å. The C(7)-H(13) bond length is 1.10 Å. In the seventh C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(14), and one H(15) atom. The C(8)-N(1) bond length is 1.45 Å. The C(8)-H(14) bond length is 1.10 Å. The C(8)-H(15) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(10)-O(3) bond length is 1.27 Å. The C(10)-O(4) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(5), one C(8), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(3), and one N(1) atom. There are nine inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(8) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(10) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(10) atom. Linkers: 1 Cc1cc(C)n(CCSCCSCCn2nc(C)cc2C)n1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.21 A, density 1.58 g/cm3, surface area 5174.12 m2/g, accessible volume 0.15 cm3/g