Zn2C14H15O11(CH3)4C2H5O2 crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of sixteen 02329_fluka molecules and four meoh methanol molecules inside a Zn2C14H15O11 framework. In the Zn2C14H15O11 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing ZnO6 octahedra. The Zn(1)-O(2) bond length is 2.04 Å. The Zn(1)-O(3) bond length is 2.28 Å. The Zn(1)-O(5) bond length is 2.14 Å. The Zn(1)-O(6) bond length is 2.03 Å. The Zn(1)-O(7) bond length is 2.01 Å. The Zn(1)-O(8) bond length is 2.20 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(11), one O(4), one O(5), and one O(7) atom to form distorted corner-sharing ZnO5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 62-75°. The Zn(2)-O(1) bond length is 1.96 Å. The Zn(2)-O(11) bond length is 2.27 Å. The Zn(2)-O(4) bond length is 2.02 Å. The Zn(2)-O(5) bond length is 2.21 Å. The Zn(2)-O(7) bond length is 1.94 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.49 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.28 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(9)-O(5) bond length is 1.29 Å. The C(9)-O(6) bond length is 1.26 Å. In the tenth C site, C(10) is bonded in a distorted water-like geometry to one H(5) and one O(7) atom. The C(10)-H(5) bond length is 1.11 Å. The C(10)-O(7) bond length is 1.41 Å. In the eleventh C site, C(13) is bonded in a distorted water-like geometry to one H(11) and one O(8) atom. The C(13)-H(11) bond length is 1.10 Å. The C(13)-O(8) bond length is 1.44 Å. In the twelfth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one H(17), one H(18), and one O(11) atom. The C(15)-H(17) bond length is 1.10 Å. The C(15)-H(18) bond length is 1.10 Å. The C(15)-O(11) bond length is 1.43 Å. In the thirteenth C site, C(16) is bonded in a distorted water-like geometry to one H(19) and one O(10) atom. The C(16)-H(19) bond length is 1.10 Å. The C(16)-O(10) bond length is 1.43 Å. In the fourteenth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one H(25), one H(26), and one O(13) atom. The C(18)-H(25) bond length is 1.10 Å. The C(18)-H(26) bond length is 1.10 Å. The C(18)-O(13) bond length is 1.43 Å. There are fifteen inequivalent H sites. In the first H site, H(32) is bonded in a single-bond geometry to one O(13) and one O(3) atom. The H(32)-O(13) bond length is 1.00 Å. The H(32)-O(3) bond length is 1.72 Å. In the second H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one O(8) atom. The H(15)-O(8) bond length is 0.99 Å. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(23) is bonded in a distorted single-bond geometry to one O(10) and one O(13) atom. The H(23)-O(10) bond length is 1.00 Å. The H(23)-O(13) bond length is 1.67 Å. In the thirteenth H site, H(24) is bonded in a single-bond geometry to one O(11) atom. The H(24)-O(11) bond length is 1.00 Å. In the fourteenth H site, H(25) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(26) is bonded in a single-bond geometry to one C(18) atom. There are eleven inequivalent O sites. In the first O site, O(11) is bonded in a 3-coordinate geometry to one Zn(2), one C(15), and one H(24) atom. In the second O site, O(13) is bonded in a 3-coordinate geometry to one C(18), one H(23), and one H(32) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the fourth O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the fifth O site, O(3) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(8), and one H(32) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(8) atom. In the seventh O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(2), and one C(9) atom. In the eighth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the ninth O site, O(7) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one C(10) atom. In the tenth O site, O(8) is bonded in a 3-coordinate geometry to one Zn(1), one C(13), and one H(15) atom. In the eleventh O site, O(10) is bonded in a 2-coordinate geometry to one C(16) and one H(23) atom. Linkers: 4 [O]C(=O)c1ccc(C([O])=O)cc1 ,4 C[C@H]([O])C([O])=O. Metal clusters: 8 [Zn]. The MOF has largest included sphere 2.27 A, density 1.67 g/cm3, surface area 4521.94 m2/g, accessible volume 0.17 cm3/g