NaC6H8SO8CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a NaC6H8SO8 framework. In the NaC6H8SO8 framework, Na(1) is bonded in a 6-coordinate geometry to one O(5), one O(7), two equivalent O(1), and two equivalent O(8) atoms. The Na(1)-O(5) bond length is 2.36 Å. The Na(1)-O(7) bond length is 2.45 Å. There is one shorter (2.43 Å) and one longer (2.44 Å) Na(1)-O(1) bond length. There is one shorter (2.39 Å) and one longer (2.50 Å) Na(1)-O(8) bond length. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-S(1) bond length is 1.77 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(3) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(7) atom. The C(3)-C(4) bond length is 1.42 Å. The C(3)-C(7) bond length is 1.47 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one O(6) atom. The C(4)-O(6) bond length is 1.34 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(4), and one O(5) atom. The C(7)-O(4) bond length is 1.32 Å. The C(7)-O(5) bond length is 1.26 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(4) and one O(7) atom. The H(1)-O(4) bond length is 1.04 Å. The H(1)-O(7) bond length is 1.55 Å. In the second H site, H(2) is bonded in a distorted bent 150 degrees geometry to one O(5) and one O(6) atom. The H(2)-O(5) bond length is 1.59 Å. The H(2)-O(6) bond length is 1.02 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one O(7) atom. The H(6)-O(7) bond length is 0.99 Å. In the sixth H site, H(7) is bonded in a single-bond geometry to one O(3) and one O(7) atom. The H(7)-O(3) bond length is 1.72 Å. The H(7)-O(7) bond length is 0.99 Å. In the seventh H site, H(8) is bonded in a single-bond geometry to one O(3) and one O(8) atom. The H(8)-O(3) bond length is 1.72 Å. The H(8)-O(8) bond length is 0.99 Å. In the eighth H site, H(9) is bonded in a single-bond geometry to one O(8) atom. The H(9)-O(8) bond length is 0.98 Å. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.49 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one H(7), one H(8), and one S(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(7) and one H(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Na(1), one C(7), and one H(2) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one C(4) and one H(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Na(1), one H(1), one H(6), and one H(7) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to two equivalent Na(1), one H(8), and one H(9) atom. Linkers: 2 [O]S([O])([O])c1ccc(O)c(C(=O)O)c1. Metal clusters: 2 [Na]. The MOF has largest included sphere 1.75 A, density 1.79 g/cm3, surface area 3303.47 m2/g, accessible volume 0.09 cm3/g