MnC6NH4O3Cl crystallizes in the triclinic P1 space group. There are seven inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(15), one O(17), one O(24), one O(3), one Cl(1), and one Cl(8) atom to form distorted edge-sharing MnCl2O4 octahedra. The Mn(1)-O(15) bond length is 2.07 Å. The Mn(1)-O(17) bond length is 2.24 Å. The Mn(1)-O(24) bond length is 2.22 Å. The Mn(1)-O(3) bond length is 2.13 Å. The Mn(1)-Cl(1) bond length is 2.57 Å. The Mn(1)-Cl(8) bond length is 2.46 Å. In the second Mn site, Mn(2,7) is bonded to one O(16), one O(18), one O(23), one O(4), one Cl(2), and one Cl(7) atom to form distorted edge-sharing MnCl2O4 octahedra. The Mn(2,7)-O(16) bond length is 2.07 Å. The Mn(2,7)-O(18) bond length is 2.25 Å. The Mn(2,7)-O(23) bond length is 2.22 Å. The Mn(2,7)-O(4) bond length is 2.13 Å. The Mn(2,7)-Cl(2) bond length is 2.57 Å. The Mn(2,7)-Cl(7) bond length is 2.46 Å. In the third Mn site, Mn(3) is bonded to one O(1), one O(13), one O(19), one O(22), one Cl(3), and one Cl(6) atom to form distorted edge-sharing MnCl2O4 octahedra. The Mn(3)-O(1) bond length is 2.12 Å. The Mn(3)-O(13) bond length is 2.06 Å. The Mn(3)-O(19) bond length is 2.23 Å. The Mn(3)-O(22) bond length is 2.21 Å. The Mn(3)-Cl(3) bond length is 2.58 Å. The Mn(3)-Cl(6) bond length is 2.47 Å. In the fourth Mn site, Mn(4) is bonded to one O(14), one O(2), one O(20), one O(21), one Cl(4), and one Cl(5) atom to form distorted edge-sharing MnCl2O4 octahedra. The Mn(4)-O(14) bond length is 2.07 Å. The Mn(4)-O(2) bond length is 2.13 Å. The Mn(4)-O(20) bond length is 2.25 Å. The Mn(4)-O(21) bond length is 2.22 Å. The Mn(4)-Cl(4) bond length is 2.57 Å. The Mn(4)-Cl(5) bond length is 2.47 Å. In the fifth Mn site, Mn(5) is bonded to one O(11), one O(20), one O(21), one O(7), one Cl(4), and one Cl(5) atom to form distorted edge-sharing MnCl2O4 octahedra. The Mn(5)-O(11) bond length is 2.06 Å. The Mn(5)-O(20) bond length is 2.22 Å. The Mn(5)-O(21) bond length is 2.24 Å. The Mn(5)-O(7) bond length is 2.13 Å. The Mn(5)-Cl(4) bond length is 2.46 Å. The Mn(5)-Cl(5) bond length is 2.57 Å. In the sixth Mn site, Mn(6) is bonded to one O(12), one O(19), one O(22), one O(8), one Cl(3), and one Cl(6) atom to form distorted edge-sharing MnCl2O4 octahedra. The Mn(6)-O(12) bond length is 2.06 Å. The Mn(6)-O(19) bond length is 2.21 Å. The Mn(6)-O(22) bond length is 2.23 Å. The Mn(6)-O(8) bond length is 2.13 Å. The Mn(6)-Cl(3) bond length is 2.47 Å. The Mn(6)-Cl(6) bond length is 2.58 Å. In the seventh Mn site, Mn(8) is bonded to one O(10), one O(17), one O(24), one O(6), one Cl(1), and one Cl(8) atom to form distorted edge-sharing MnCl2O4 octahedra. The Mn(8)-O(10) bond length is 2.07 Å. The Mn(8)-O(17) bond length is 2.22 Å. The Mn(8)-O(24) bond length is 2.25 Å. The Mn(8)-O(6) bond length is 2.13 Å. The Mn(8)-Cl(1) bond length is 2.46 Å. The Mn(8)-Cl(8) bond length is 2.57 Å. There are thirty-eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(1), and one O(9) atom. The C(1)-C(25) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(9) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(26,31); one O(10); and one O(2) atom. The C(2)-C(26,31) bond length is 1.50 Å. The C(2)-O(10) bond length is 1.27 Å. The C(2)-O(2) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(11), and one O(3) atom. The C(3)-C(27) bond length is 1.50 Å. The C(3)-O(11) bond length is 1.27 Å. The C(3)-O(3) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(28,29); one O(12); and one O(4) atom. The C(4)-C(28,29) bond length is 1.50 Å. The C(4)-O(12) bond length is 1.27 Å. The C(4)-O(4) bond length is 1.28 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(28,29); one O(13); and one O(5) atom. The C(5)-C(28,29) bond length is 1.50 Å. The C(5)-O(13) bond length is 1.27 Å. The C(5)-O(5) bond length is 1.28 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(14), and one O(6) atom. The C(6)-C(30) bond length is 1.50 Å. The C(6)-O(14) bond length is 1.27 Å. The C(6)-O(6) bond length is 1.28 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(26,31); one O(15); and one O(7) atom. The C(7)-C(26,31) bond length is 1.50 Å. The C(7)-O(15) bond length is 1.27 Å. The C(7)-O(7) bond length is 1.28 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(16), and one O(8) atom. The C(8)-C(32) bond length is 1.50 Å. The C(8)-O(16) bond length is 1.27 Å. The C(8)-O(8) bond length is 1.28 Å. In the ninth C site, C(9,13) is bonded in a distorted trigonal planar geometry to one C(17); one C(25); and one H(1,2,4,5,6,7,8) atom. The C(9,13)-C(17) bond length is 1.38 Å. The C(9,13)-C(25) bond length is 1.40 Å. The C(9,13)-H(1,2,4,5,6,7,8) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(18); one C(26,31); and one H(1,2,4,5,6,7,8) atom. The C(10)-C(18) bond length is 1.38 Å. The C(10)-C(26,31) bond length is 1.40 Å. The C(10)-H(1,2,4,5,6,7,8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(19), one C(27), and one H(3) atom. The C(11)-C(19) bond length is 1.38 Å. The C(11)-C(27) bond length is 1.40 Å. The C(11)-H(3) bond length is 1.09 Å. In the twelfth C site, C(12,14,15,16) is bonded in a distorted trigonal planar geometry to one C(20); one C(28,29); and one H(1,2,4,5,6,7,8) atom. The C(12,14,15,16)-C(20) bond length is 1.38 Å. The C(12,14,15,16)-C(28,29) bond length is 1.40 Å. The C(12,14,15,16)-H(1,2,4,5,6,7,8) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(9,13); one N(1); and one H(9,10,13) atom. The C(17)-N(1) bond length is 1.36 Å. The C(17)-H(9,10,13) bond length is 1.09 Å. In the fourteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(10); one N(2,5); and one H(9,10,13) atom. The C(18)-N(2,5) bond length is 1.36 Å. The C(18)-H(9,10,13) bond length is 1.09 Å. In the fifteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(11); one N(3); and one H(11,12,14,15,16) atom. The C(19)-N(3) bond length is 1.36 Å. The C(19)-H(11,12,14,15,16) bond length is 1.09 Å. In the sixteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(12,14,15,16); one N(4,7); and one H(11,12,14,15,16) atom. The C(20)-N(4,7) bond length is 1.36 Å. The C(20)-H(11,12,14,15,16) bond length is 1.09 Å. In the seventeenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(9,13); one N(2,5); and one H(9,10,13) atom. The C(21)-C(9,13) bond length is 1.38 Å. The C(21)-N(2,5) bond length is 1.36 Å. The C(21)-H(9,10,13) bond length is 1.09 Å. In the eighteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(12,14,15,16); one N(6); and one H(11,12,14,15,16) atom. The C(22)-C(12,14,15,16) bond length is 1.38 Å. The C(22)-N(6) bond length is 1.36 Å. The C(22)-H(11,12,14,15,16) bond length is 1.09 Å. In the nineteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(12,14,15,16); one N(4,7); and one H(11,12,14,15,16) atom. The C(23)-C(12,14,15,16) bond length is 1.38 Å. The C(23)-N(4,7) bond length is 1.36 Å. The C(23)-H(11,12,14,15,16) bond length is 1.09 Å. In the twentieth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(12,14,15,16); one N(8); and one H(11,12,14,15,16) atom. The C(24)-C(12,14,15,16) bond length is 1.38 Å. The C(24)-N(8) bond length is 1.36 Å. The C(24)-H(11,12,14,15,16) bond length is 1.09 Å. In the twenty-first C site, C(25) is bonded in a trigonal planar geometry to one C(1); one C(33,37); and one C(9,13) atom. The C(25)-C(33,37) bond length is 1.40 Å. In the twenty-second C site, C(26,31) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(34) atom. The C(26,31)-C(34) bond length is 1.40 Å. In the twenty-third C site, C(27) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(35) atom. The C(27)-C(35) bond length is 1.40 Å. In the twenty-fourth C site, C(28,29) is bonded in a trigonal planar geometry to one C(12,14,15,16); one C(36,38,39,40); and one C(4) atom. The C(28,29)-C(36,38,39,40) bond length is 1.40 Å. In the twenty-fifth C site, C(30) is bonded in a trigonal planar geometry to one C(12,14,15,16); one C(36,38,39,40); and one C(6) atom. The C(30)-C(12,14,15,16) bond length is 1.40 Å. The C(30)-C(36,38,39,40) bond length is 1.40 Å. In the twenty-sixth C site, C(32) is bonded in a trigonal planar geometry to one C(12,14,15,16); one C(36,38,39,40); and one C(8) atom. The C(32)-C(12,14,15,16) bond length is 1.40 Å. The C(32)-C(36,38,39,40) bond length is 1.40 Å. In the twenty-seventh C site, C(33,37) is bonded in a distorted trigonal planar geometry to one C(25); one C(41); and one H(17,19,20,21,23) atom. The C(33,37)-C(41) bond length is 1.38 Å. The C(33,37)-H(17,19,20,21,23) bond length is 1.09 Å. In the twenty-eighth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(26,31); one C(42); and one H(18,22,24) atom. The C(34)-C(42) bond length is 1.38 Å. The C(34)-H(18,22,24) bond length is 1.09 Å. In the twenty-ninth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(27); one C(43); and one H(17,19,20,21,23) atom. The C(35)-C(43) bond length is 1.38 Å. The C(35)-H(17,19,20,21,23) bond length is 1.09 Å. In the thirtieth C site, C(36,38,39,40) is bonded in a distorted trigonal planar geometry to one C(28,29); one C(44); and one H(17,19,20,21,23) atom. The C(36,38,39,40)-C(44) bond length is 1.38 Å. The C(36,38,39,40)-H(17,19,20,21,23) bond length is 1.09 Å. In the thirty-first C site, C(41) is bonded in a distorted trigonal planar geometry to one C(33,37); one N(1); and one H(25,26,28,29,30,31,32) atom. The C(41)-N(1) bond length is 1.36 Å. The C(41)-H(25,26,28,29,30,31,32) bond length is 1.09 Å. In the thirty-second C site, C(42) is bonded in a distorted trigonal planar geometry to one C(34); one N(2,5); and one H(25,26,28,29,30,31,32) atom. The C(42)-N(2,5) bond length is 1.36 Å. The C(42)-H(25,26,28,29,30,31,32) bond length is 1.09 Å. In the thirty-third C site, C(43) is bonded in a distorted trigonal planar geometry to one C(35), one N(3), and one H(27) atom. The C(43)-N(3) bond length is 1.36 Å. The C(43)-H(27) bond length is 1.09 Å. In the thirty-fourth C site, C(44) is bonded in a distorted trigonal planar geometry to one C(36,38,39,40); one N(4,7); and one H(25,26,28,29,30,31,32) atom. The C(44)-N(4,7) bond length is 1.36 Å. The C(44)-H(25,26,28,29,30,31,32) bond length is 1.09 Å. In the thirty-fifth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(33,37); one N(2,5); and one H(25,26,28,29,30,31,32) atom. The C(45)-C(33,37) bond length is 1.38 Å. The C(45)-N(2,5) bond length is 1.36 Å. The C(45)-H(25,26,28,29,30,31,32) bond length is 1.09 Å. In the thirty-sixth C site, C(46) is bonded in a distorted trigonal planar geometry to one C(36,38,39,40); one N(6); and one H(25,26,28,29,30,31,32) atom. The C(46)-C(36,38,39,40) bond length is 1.38 Å. The C(46)-N(6) bond length is 1.36 Å. The C(46)-H(25,26,28,29,30,31,32) bond length is 1.09 Å. In the thirty-seventh C site, C(47) is bonded in a distorted trigonal planar geometry to one C(36,38,39,40); one N(4,7); and one H(25,26,28,29,30,31,32) atom. The C(47)-C(36,38,39,40) bond length is 1.38 Å. The C(47)-N(4,7) bond length is 1.36 Å. The C(47)-H(25,26,28,29,30,31,32) bond length is 1.09 Å. In the thirty-eighth C site, C(48) is bonded in a distorted trigonal planar geometry to one C(36,38,39,40); one N(8); and one H(25,26,28,29,30,31,32) atom. The C(48)-C(36,38,39,40) bond length is 1.38 Å. The C(48)-N(8) bond length is 1.36 Å. The C(48)-H(25,26,28,29,30,31,32) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(17), one C(41), and one O(17) atom. The N(1)-O(17) bond length is 1.33 Å. In the second N site, N(2,5) is bonded in a trigonal planar geometry to one C(18), one C(42), and one O(18) atom. The N(2,5)-O(18) bond length is 1.33 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(19), one C(43), and one O(19) atom. The N(3)-O(19) bond length is 1.33 Å. In the fourth N site, N(4,7) is bonded in a trigonal planar geometry to one C(20), one C(44), and one O(20) atom. The N(4,7)-O(20) bond length is 1.33 Å. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one C(22), one C(46), and one O(22) atom. The N(6)-O(22) bond length is 1.33 Å. In the sixth N site, N(8) is bonded in a trigonal planar geometry to one C(24), one C(48), and one O(24) atom. The N(8)-O(24) bond length is 1.33 Å. There are eight inequivalent H sites. In the first H site, H(1,2,4,5,6,7,8) is bonded in a single-bond geometry to one C(9,13) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(9,10,13) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(11,12,14,15,16) is bonded in a single-bond geometry to one C(19) atom. In the fifth H site, H(17,19,20,21,23) is bonded in a single-bond geometry to one C(33,37) atom. In the sixth H site, H(18,22,24) is bonded in a single-bond geometry to one C(34) atom. In the seventh H site, H(25,26,28,29,30,31,32) is bonded in a single-bond geometry to one C(41) atom. In the eighth H site, H(27) is bonded in a single-bond geometry to one C(43) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(4) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(2,7) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(2,7) and one C(5) atom. The O(5)-Mn(2,7) bond length is 2.12 Å. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(8) and one C(6) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Mn(5) and one C(7) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(6) and one C(8) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mn(2,7) and one C(1) atom. The O(9)-Mn(2,7) bond length is 2.06 Å. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mn(8) and one C(2) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mn(5) and one C(3) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Mn(6) and one C(4) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Mn(3) and one C(5) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Mn(4) and one C(6) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(7) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Mn(2,7) and one C(8) atom. In the seventeenth O site, O(17) is bonded in a trigonal planar geometry to one Mn(1), one Mn(8), and one N(1) atom. In the eighteenth O site, O(18) is bonded in a trigonal planar geometry to two equivalent Mn(2,7) and one N(2,5) atom. In the nineteenth O site, O(19) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one N(3) atom. In the twentieth O site, O(20) is bonded in a trigonal planar geometry to one Mn(4); one Mn(5); and one N(4,7) atom. In the twenty-first O site, O(21) is bonded in a trigonal planar geometry to one Mn(4); one Mn(5); and one N(2,5) atom. The O(21)-N(2,5) bond length is 1.33 Å. In the twenty-second O site, O(22) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one N(6) atom. In the twenty-third O site, O(23) is bonded in a trigonal planar geometry to two equivalent Mn(2,7) and one N(4,7) atom. The O(23)-N(4,7) bond length is 1.33 Å. In the twenty-fourth O site, O(24) is bonded in a trigonal planar geometry to one Mn(1), one Mn(8), and one N(8) atom. There are eight inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in an L-shaped geometry to one Mn(1) and one Mn(8) atom. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to two equivalent Mn(2,7) atoms. In the third Cl site, Cl(3) is bonded in an L-shaped geometry to one Mn(3) and one Mn(6) atom. In the fourth Cl site, Cl(4) is bonded in an L-shaped geometry to one Mn(4) and one Mn(5) atom. In the fifth Cl site, Cl(5) is bonded in an L-shaped geometry to one Mn(4) and one Mn(5) atom. In the sixth Cl site, Cl(6) is bonded in an L-shaped geometry to one Mn(3) and one Mn(6) atom. In the seventh Cl site, Cl(7) is bonded in an L-shaped geometry to two equivalent Mn(2,7) atoms. In the eighth Cl site, Cl(8) is bonded in an L-shaped geometry to one Mn(1) and one Mn(8) atom. Linkers: 8 [O]C(=O)c1cc[n+]([O-])cc1. Metal clusters: 8 [Mn]. The MOF has largest included sphere 1.52 A, density 2.20 g/cm3, surface area 2904.28 m2/g, accessible volume 0.05 cm3/g