CdC23H15(NO2)2CH crystallizes in the orthorhombic Pbca space group. The structure consists of eight 02329_fluka molecules inside a CdC23H15(NO2)2 framework. In the CdC23H15(NO2)2 framework, Cd(1) is bonded to one N(1), one N(2), one O(1), one O(3), one O(4), and two equivalent O(2) atoms to form distorted edge-sharing CdN2O5 pentagonal bipyramids. The Cd(1)-N(1) bond length is 2.31 Å. The Cd(1)-N(2) bond length is 2.34 Å. The Cd(1)-O(1) bond length is 2.37 Å. The Cd(1)-O(3) bond length is 2.48 Å. The Cd(1)-O(4) bond length is 2.42 Å. There is one shorter (2.36 Å) and one longer (2.74 Å) Cd(1)-O(2) bond length. There are twenty-three inequivalent C sites. In the first C site, C(16) is bonded in a distorted single-bond geometry to one C(17), one C(8), and one H(9) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(8) bond length is 1.40 Å. The C(16)-H(9) bond length is 1.09 Å. In the second C site, C(1) is bonded in a distorted single-bond geometry to one C(5) and one H(1) atom. The C(1)-C(5) bond length is 1.41 Å. The C(1)-H(1) bond length is 1.09 Å. In the third C site, C(17) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(16) atom. The C(17)-C(14) bond length is 1.40 Å. The C(17)-C(15) bond length is 1.50 Å. In the fourth C site, C(2) is bonded in a trigonal planar geometry to one C(10), one C(3), and one C(9) atom. The C(2)-C(10) bond length is 1.40 Å. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(9) bond length is 1.50 Å. In the fifth C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(2) bond length is 1.09 Å. In the sixth C site, C(19) is bonded in a distorted single-bond geometry to one C(12), one C(5), and one H(11) atom. The C(19)-C(12) bond length is 1.39 Å. The C(19)-C(5) bond length is 1.41 Å. The C(19)-H(11) bond length is 1.09 Å. In the seventh C site, C(4) is bonded in a trigonal planar geometry to one C(22), one C(3), and one C(5) atom. The C(4)-C(22) bond length is 1.41 Å. The C(4)-C(5) bond length is 1.48 Å. In the eighth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(11), one C(23), and one H(12) atom. The C(20)-C(11) bond length is 1.41 Å. The C(20)-C(23) bond length is 1.39 Å. The C(20)-H(12) bond length is 1.09 Å. In the ninth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(19), and one C(4) atom. In the tenth C site, C(21) is bonded in a distorted single-bond geometry to one C(7), one C(8), and one H(13) atom. The C(21)-C(7) bond length is 1.41 Å. The C(21)-C(8) bond length is 1.39 Å. The C(21)-H(13) bond length is 1.09 Å. In the eleventh C site, C(6) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(3) atom. The C(6)-C(11) bond length is 1.41 Å. The C(6)-C(13) bond length is 1.39 Å. The C(6)-H(3) bond length is 1.09 Å. In the twelfth C site, C(22) is bonded in a distorted single-bond geometry to one C(4) and one H(14) atom. The C(22)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(21) atom. The C(7)-C(11) bond length is 1.47 Å. The C(7)-C(14) bond length is 1.40 Å. In the fourteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(20), one N(2), and one H(15) atom. The C(23)-N(2) bond length is 1.35 Å. The C(23)-H(15) bond length is 1.09 Å. In the fifteenth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(16), one C(21), and one H(4) atom. The C(8)-H(4) bond length is 1.09 Å. In the sixteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(16) atom. The C(24)-N(1) bond length is 1.35 Å. The C(24)-H(16) bond length is 1.09 Å. In the seventeenth C site, C(9) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(9)-O(1) bond length is 1.28 Å. The C(9)-O(2) bond length is 1.27 Å. In the eighteenth C site, C(10) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(10)-H(5) bond length is 1.09 Å. In the nineteenth C site, C(11) is bonded in a trigonal planar geometry to one C(20), one C(6), and one C(7) atom. In the twentieth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(19), one N(1), and one H(6) atom. The C(12)-N(1) bond length is 1.35 Å. The C(12)-H(6) bond length is 1.09 Å. In the twenty-first C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(3), and one O(4) atom. The C(15)-O(3) bond length is 1.28 Å. The C(15)-O(4) bond length is 1.28 Å. In the twenty-second C site, C(13) is bonded in a distorted trigonal planar geometry to one C(6), one N(2), and one H(7) atom. The C(13)-N(2) bond length is 1.34 Å. The C(13)-H(7) bond length is 1.09 Å. In the twenty-third C site, C(14) is bonded in a distorted single-bond geometry to one C(17), one C(7), and one H(8) atom. The C(14)-H(8) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(12), and one C(24) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(23) atom. There are fifteen inequivalent H sites. In the first H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1) and one C(9) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(9) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(15) atom. Linkers: 16 [O]C(=O)c1cccc(-c2ccncc2)c1. Metal clusters: 4 [C]1O[Cd]2(O1)O[C]O[Cd]1(O[C]O1)O[C]O2. The MOF has largest included sphere 5.85 A, density 1.31 g/cm3, surface area 4391.58 m2/g, accessible volume 0.24 cm3/g