CHCuC23N2H17SO7 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and four CuC23N2H17SO7 clusters. In each CuC23N2H17SO7 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one N(2), one O(1), one O(5), and one O(7) atom. The Cu(1)-N(1) bond length is 2.01 Å. The Cu(1)-N(2) bond length is 2.00 Å. The Cu(1)-O(1) bond length is 1.97 Å. The Cu(1)-O(5) bond length is 1.97 Å. The Cu(1)-O(7) bond length is 2.27 Å. There are twenty-three inequivalent C sites. In the first C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(10) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(10) bond length is 1.09 Å. In the second C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one S(1) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-S(1) bond length is 1.77 Å. In the third C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(11) atom. The C(16)-H(11) bond length is 1.09 Å. In the fourth C site, C(17) is bonded in a distorted single-bond geometry to one C(12) and one H(12) atom. The C(17)-C(12) bond length is 1.40 Å. The C(17)-H(12) bond length is 1.09 Å. In the fifth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(5), and one O(6) atom. The C(18)-C(19) bond length is 1.51 Å. The C(18)-O(5) bond length is 1.29 Å. The C(18)-O(6) bond length is 1.26 Å. In the sixth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-C(24) bond length is 1.40 Å. In the seventh C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one H(13) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(13) bond length is 1.09 Å. In the eighth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one H(14) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-H(14) bond length is 1.09 Å. In the ninth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one S(1) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-S(1) bond length is 1.78 Å. In the tenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(15) atom. The C(23)-H(15) bond length is 1.09 Å. In the eleventh C site, C(24) is bonded in a distorted single-bond geometry to one C(19) and one H(16) atom. The C(24)-H(16) bond length is 1.09 Å. In the twelfth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the thirteenth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.09 Å. In the fourteenth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(3)-H(3) bond length is 1.09 Å. In the fifteenth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the sixteenth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.47 Å. The C(5)-N(1) bond length is 1.35 Å. In the seventeenth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-N(2) bond length is 1.36 Å. In the eighteenth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the nineteenth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(7) bond length is 1.09 Å. In the twentieth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(8) bond length is 1.09 Å. In the twenty-first C site, C(11) is bonded in a bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-O(1) bond length is 1.29 Å. The C(11)-O(2) bond length is 1.26 Å. In the twenty-second C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.40 Å. In the twenty-third C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(9) atom. The C(13)-H(9) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(6) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one O(7) atom. The H(17)-O(7) bond length is 1.00 Å. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one O(7) atom. The H(18)-O(7) bond length is 0.99 Å. S(1) is bonded in a distorted bent 120 degrees geometry to one C(15), one C(22), one O(3), and one O(4) atom. The S(1)-O(3) bond length is 1.46 Å. The S(1)-O(4) bond length is 1.45 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(11) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(11) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(18) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one C(18) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Cu(1), one H(17), and one H(18) atom. Linkers: 4 [O]C(=O)c1ccc(S(=O)(=O)c2ccc(C([O])=O)cc2)cc1 ,2 c1ccc(-c2ccccn2)nc1. Metal clusters: 4 O.O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 4.60 A, density 1.39 g/cm3, surface area 4519.32 m2/g, accessible volume 0.31 cm3/g