(CH)4PbC16H10(N2O3)3 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four PbC16H10(N2O3)3 clusters. In each PbC16H10(N2O3)3 cluster, Pb(1) is bonded in a distorted T-shaped geometry to one N(1), one N(2), and one O(9) atom. The Pb(1)-N(1) bond length is 2.64 Å. The Pb(1)-N(2) bond length is 2.63 Å. The Pb(1)-O(9) bond length is 2.44 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one N(1) atom. The C(1)-C(3) bond length is 1.40 Å. The C(1)-C(5) bond length is 1.47 Å. The C(1)-N(1) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one N(2) atom. The C(2)-C(4) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.47 Å. The C(2)-N(2) bond length is 1.36 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(7), and one N(3) atom. The C(3)-C(7) bond length is 1.48 Å. The C(3)-N(3) bond length is 1.37 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2), one C(8), and one N(4) atom. The C(4)-C(8) bond length is 1.48 Å. The C(4)-N(4) bond length is 1.37 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(3) atom. The C(5)-O(1) bond length is 1.25 Å. The C(5)-O(3) bond length is 1.31 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(4) atom. The C(6)-O(2) bond length is 1.25 Å. The C(6)-O(4) bond length is 1.31 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(5), and one O(7) atom. The C(7)-O(5) bond length is 1.29 Å. The C(7)-O(7) bond length is 1.26 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(6), and one O(8) atom. The C(8)-O(6) bond length is 1.29 Å. The C(8)-O(8) bond length is 1.26 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one N(3) atom. The C(9)-C(11) bond length is 1.46 Å. The C(9)-N(1) bond length is 1.34 Å. The C(9)-N(3) bond length is 1.37 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one N(4) atom. The C(10)-C(12) bond length is 1.46 Å. The C(10)-N(2) bond length is 1.33 Å. The C(10)-N(4) bond length is 1.37 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one N(5) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-N(5) bond length is 1.36 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(10), one C(14), and one N(6) atom. The C(12)-C(14) bond length is 1.40 Å. The C(12)-N(6) bond length is 1.36 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(11) and one H(1) atom. The C(13)-H(1) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(2) atom. The C(14)-H(2) bond length is 1.09 Å. In the fifteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(7) atom. The C(19)-N(5) bond length is 1.34 Å. The C(19)-H(7) bond length is 1.09 Å. In the sixteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(8) atom. The C(20)-N(6) bond length is 1.34 Å. The C(20)-H(8) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one Pb(1), one C(1), and one C(9) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one Pb(1), one C(10), and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(3), one C(9), and one H(9) atom. The N(3)-H(9) bond length is 1.05 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(4), and one H(10) atom. The N(4)-H(10) bond length is 1.05 Å. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(11) and one C(19) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one C(12) and one C(20) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(20) atom. In the fifth H site, H(9) is bonded in a distorted single-bond geometry to one N(3) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one O(9) atom. The H(11)-O(9) bond length is 0.99 Å. In the eighth H site, H(12) is bonded in a single-bond geometry to one O(9) atom. The H(12)-O(9) bond length is 1.00 Å. In the ninth H site, H(13) is bonded in a linear geometry to one O(3) and one O(5) atom. The H(13)-O(3) bond length is 1.12 Å. The H(13)-O(5) bond length is 1.32 Å. In the tenth H site, H(14) is bonded in a linear geometry to one O(4) and one O(6) atom. The H(14)-O(4) bond length is 1.12 Å. The H(14)-O(6) bond length is 1.32 Å. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one C(5) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(6) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(5) and one H(13) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(6) and one H(14) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(7) and one H(13) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one C(8) and one H(14) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one C(7) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one C(8) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Pb(1), one H(11), and one H(12) atom. Linkers: 3 [O]C(=O)c1[nH]c(-c2ccccn2)nc1C(=O)O. Metal clusters: 2 [Pb]. The MOF has largest included sphere 2.02 A, density 2.18 g/cm3, surface area 2848.03 m2/g, accessible volume 0.10 cm3/g