ZnC10NH6O4(C3H2)2 is Indium-derived structured and crystallizes in the orthorhombic Ccce space group. The structure is zero-dimensional and consists of eight 2,3-dimethyl-1,3-butadiene molecules and four ZnC10NH6O4 clusters. In each ZnC10NH6O4 cluster, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), two equivalent O(1), and two equivalent O(2) atoms. The Zn(1)-N(1) bond length is 2.05 Å. Both Zn(1)-O(1) bond lengths are 2.11 Å. Both Zn(1)-O(2) bond lengths are 2.03 Å. There are five inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(1) bond length is 1.50 Å. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.40 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(4)-H(2) bond length is 1.09 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(3) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1) and two equivalent C(5) atoms. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. Linkers: 2 c1cc(-c2ccc(-c3ccncc3)cc2)ccn1 ,4 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 4.56 A, density 1.17 g/cm3, surface area 4602.38 m2/g, accessible volume 0.38 cm3/g