CoC30H22(N2O3)2(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a CoC30H22(N2O3)2 framework. In the CoC30H22(N2O3)2 framework, Co(1) is bonded in a distorted octahedral geometry to one N(2), one N(4), one O(3), one O(4), one O(5), and one O(6) atom. The Co(1)-N(2) bond length is 2.11 Å. The Co(1)-N(4) bond length is 2.08 Å. The Co(1)-O(3) bond length is 2.04 Å. The Co(1)-O(4) bond length is 1.96 Å. The Co(1)-O(5) bond length is 2.22 Å. The Co(1)-O(6) bond length is 2.14 Å. There are thirty inequivalent C sites. In the first C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(6) atom. The C(8)-C(10) bond length is 1.38 Å. The C(8)-C(11) bond length is 1.50 Å. The C(8)-C(6) bond length is 1.43 Å. In the second C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(7), and one H(7) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(7) bond length is 1.39 Å. The C(9)-H(7) bond length is 1.09 Å. In the third C site, C(10) is bonded in a distorted single-bond geometry to one C(8), one C(9), and one H(8) atom. The C(10)-H(8) bond length is 1.09 Å. In the fourth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(1), and one O(1) atom. The C(11)-N(1) bond length is 1.34 Å. The C(11)-O(1) bond length is 1.25 Å. In the fifth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(13), one N(1), one H(10), and one H(9) atom. The C(12)-C(13) bond length is 1.51 Å. The C(12)-N(1) bond length is 1.45 Å. The C(12)-H(10) bond length is 1.10 Å. The C(12)-H(9) bond length is 1.10 Å. In the sixth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(16) bond length is 1.40 Å. In the seventh C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(14)-H(11) bond length is 1.09 Å. In the eighth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(15)-N(2) bond length is 1.35 Å. The C(15)-H(12) bond length is 1.09 Å. In the ninth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(13), one C(17), and one H(13) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(13) bond length is 1.09 Å. In the tenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(2), and one H(14) atom. The C(17)-N(2) bond length is 1.35 Å. The C(17)-H(14) bond length is 1.09 Å. In the eleventh C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(3), and one O(2) atom. The C(18)-C(7) bond length is 1.49 Å. The C(18)-N(3) bond length is 1.35 Å. The C(18)-O(2) bond length is 1.25 Å. In the twelfth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one C(20), one N(3), one H(15), and one H(16) atom. The C(19)-C(20) bond length is 1.51 Å. The C(19)-N(3) bond length is 1.46 Å. The C(19)-H(15) bond length is 1.10 Å. The C(19)-H(16) bond length is 1.10 Å. In the thirteenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(24) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(24) bond length is 1.40 Å. In the fourteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one H(17) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(17) bond length is 1.09 Å. In the fifteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one N(4), and one H(18) atom. The C(22)-N(4) bond length is 1.35 Å. The C(22)-H(18) bond length is 1.09 Å. In the sixteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(24), one N(4), and one H(19) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-N(4) bond length is 1.35 Å. The C(23)-H(19) bond length is 1.09 Å. In the seventeenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(20), one C(23), and one H(20) atom. The C(24)-H(20) bond length is 1.09 Å. In the eighteenth C site, C(25) is bonded in a trigonal planar geometry to one C(26), one C(30), and one C(32) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(30) bond length is 1.41 Å. The C(25)-C(32) bond length is 1.49 Å. In the nineteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(25), one C(27), and one H(21) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-H(21) bond length is 1.09 Å. In the twentieth C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(31) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-C(31) bond length is 1.49 Å. In the twenty-first C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one C(29), and one H(22) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-H(22) bond length is 1.09 Å. In the twenty-second C site, C(29) is bonded in a distorted single-bond geometry to one C(28), one C(30), and one H(23) atom. The C(29)-C(30) bond length is 1.39 Å. The C(29)-H(23) bond length is 1.09 Å. In the twenty-third C site, C(30) is bonded in a distorted trigonal planar geometry to one C(25), one C(29), and one H(24) atom. The C(30)-H(24) bond length is 1.09 Å. In the twenty-fourth C site, C(31) is bonded in a bent 120 degrees geometry to one C(27), one O(3), and one O(4) atom. The C(31)-O(3) bond length is 1.28 Å. The C(31)-O(4) bond length is 1.27 Å. In the twenty-fifth C site, C(32) is bonded in a bent 120 degrees geometry to one C(25), one O(5), and one O(6) atom. The C(32)-O(5) bond length is 1.28 Å. The C(32)-O(6) bond length is 1.28 Å. In the twenty-sixth C site, C(3) is bonded in a distorted single-bond geometry to one C(5) and one H(5,6) atom. The C(3)-C(5) bond length is 1.42 Å. The C(3)-H(5,6) bond length is 1.09 Å. In the twenty-seventh C site, C(4) is bonded in a distorted single-bond geometry to one C(6) and one H(5,6) atom. The C(4)-C(6) bond length is 1.42 Å. The C(4)-H(5,6) bond length is 1.09 Å. In the twenty-eighth C site, C(5) is bonded in a trigonal planar geometry to one C(3), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.44 Å. The C(5)-C(7) bond length is 1.43 Å. In the twenty-ninth C site, C(6) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(8) atom. In the thirtieth C site, C(7) is bonded in a trigonal planar geometry to one C(18), one C(5), and one C(9) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(11), one C(12), and one H(1) atom. The N(1)-H(1) bond length is 1.03 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(15), and one C(17) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(18), one C(19), and one H(4) atom. The N(3)-H(4) bond length is 1.03 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(22), and one C(23) atom. There are twenty-one inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one N(1) and one O(2) atom. The H(1)-O(2) bond length is 1.69 Å. In the second H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the nineteenth H site, H(22) is bonded in a single-bond geometry to one C(28) atom. In the twentieth H site, H(23) is bonded in a single-bond geometry to one C(29) atom. In the twenty-first H site, H(24) is bonded in a single-bond geometry to one C(30) atom. There are six inequivalent O sites. In the first O site, O(4) is bonded in a linear geometry to one Co(1) and one C(31) atom. In the second O site, O(5) is bonded in a distorted L-shaped geometry to one Co(1) and one C(32) atom. In the third O site, O(6) is bonded in a distorted L-shaped geometry to one Co(1) and one C(32) atom. In the fourth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one C(18) and one H(1) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one C(11) atom. In the sixth O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one C(31) atom. Linkers: 4 [O]C(=O)c1cccc(C([O])=O)c1 ,4 O=C(NCc1ccncc1)c1ccc(C(=O)NCc2ccncc2)c2ccccc12. Metal clusters: 2 [C]1O[Co]2(O1)O[C]O[Co]1(O[C]O1)O[C]O2. RCSR code: sql. The MOF has largest included sphere 4.11 A, density 1.31 g/cm3, surface area 4727.31 m2/g, accessible volume 0.22 cm3/g