ZnC22H16(N2O3)2(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two ZnC22H16(N2O3)2 clusters. In each ZnC22H16(N2O3)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-N(2) bond length is 2.07 Å. The Zn(1)-O(1) bond length is 1.95 Å. The Zn(1)-O(3) bond length is 1.97 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(4) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.50 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(6) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(6) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(3), and one O(5) atom. The C(6)-N(3) bond length is 1.35 Å. The C(6)-O(5) bond length is 1.25 Å. In the seventh C site, C(7) is bonded in a distorted water-like geometry to one N(3) and one H(7) atom. The C(7)-N(3) bond length is 1.47 Å. The C(7)-H(7) bond length is 1.10 Å. In the eighth C site, C(12) is bonded in a distorted water-like geometry to one N(4) and one H(16) atom. The C(12)-N(4) bond length is 1.46 Å. The C(12)-H(16) bond length is 1.10 Å. In the ninth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(4), and one O(6) atom. The C(13)-C(14) bond length is 1.50 Å. The C(13)-N(4) bond length is 1.34 Å. The C(13)-O(6) bond length is 1.25 Å. In the tenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(18) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(18) bond length is 1.40 Å. In the eleventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(2), and one H(17) atom. The C(15)-N(2) bond length is 1.34 Å. The C(15)-H(17) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one C(18), and one H(18) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-C(18) bond length is 1.39 Å. The C(16)-H(18) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(2), and one H(19) atom. The C(17)-N(2) bond length is 1.35 Å. The C(17)-H(19) bond length is 1.09 Å. In the fourteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(20) atom. The C(18)-H(20) bond length is 1.09 Å. In the fifteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(1), and one O(2) atom. The C(19)-C(20) bond length is 1.50 Å. The C(19)-O(1) bond length is 1.30 Å. The C(19)-O(2) bond length is 1.25 Å. In the sixteenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(22) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(22) bond length is 1.40 Å. In the seventeenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(21) atom. The C(21)-H(21) bond length is 1.09 Å. In the eighteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(20) and one H(22) atom. The C(22)-H(22) bond length is 1.09 Å. In the nineteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(3), and one O(4) atom. The C(23)-C(24) bond length is 1.49 Å. The C(23)-O(3) bond length is 1.31 Å. The C(23)-O(4) bond length is 1.25 Å. In the twentieth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(26) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-C(26) bond length is 1.40 Å. In the twenty-first C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(23) atom. The C(25)-H(23) bond length is 1.09 Å. In the twenty-second C site, C(26) is bonded in a distorted single-bond geometry to one C(24) and one H(24) atom. The C(26)-H(24) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(17) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(6), one C(7), and one H(3) atom. The N(3)-H(3) bond length is 1.03 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(12), one C(13), and one H(5) atom. The N(4)-H(5) bond length is 1.03 Å. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(21) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(22) atom. In the fifteenth H site, H(23) is bonded in a single-bond geometry to one C(25) atom. In the sixteenth H site, H(24) is bonded in a single-bond geometry to one C(26) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(19) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(19) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(23) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(23) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(13) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)cc1 ,1 O=C(N[C@H]1CCCC[C@@H]1NC(=O)c1cccnc1)c1cccnc1 ,1 O=C(N[C@@H]1CCCC[C@H]1NC(=O)c1cccnc1)c1cccnc1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.07 A, density 1.53 g/cm3, surface area 4578.88 m2/g, accessible volume 0.18 cm3/g