NaC8N2H11S3O3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two NaC8N2H11S3O3 clusters. Na(1) is bonded in a 5-coordinate geometry to one N(1), one O(1), one O(2), and two equivalent O(3) atoms. The Na(1)-N(1) bond length is 2.61 Å. The Na(1)-O(1) bond length is 2.35 Å. The Na(1)-O(2) bond length is 2.44 Å. There is one shorter (2.32 Å) and one longer (2.47 Å) Na(1)-O(3) bond length. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(3) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-N(2) bond length is 1.38 Å. The C(1)-S(3) bond length is 1.75 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3), one C(8), and one H(6) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(8) bond length is 1.39 Å. The C(2)-H(6) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(1) atom. The C(3)-C(4) bond length is 1.42 Å. The C(3)-N(1) bond length is 1.39 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(6), and one S(3) atom. The C(4)-C(6) bond length is 1.40 Å. The C(4)-S(3) bond length is 1.74 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(2), one S(1), and one S(2) atom. The C(5)-N(2) bond length is 1.37 Å. The C(5)-S(1) bond length is 1.70 Å. The C(5)-S(2) bond length is 1.71 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(7) atom. The C(6)-H(7) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-H(8) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(2), one C(7), and one H(9) atom. The C(8)-H(9) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Na(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one H(5) atom. The N(2)-H(5) bond length is 1.02 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 1.00 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 1.00 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. The H(3)-O(2) bond length is 1.00 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(3) atom. The H(10)-O(3) bond length is 0.99 Å. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(3) atom. The H(11)-O(3) bond length is 0.99 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one C(5) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one C(5) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one C(1) and one C(4) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Na(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Na(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to two equivalent Na(1), one H(10), and one H(11) atom. Linkers: 4 [S]C(=S)Nc1nc2ccccc2s1. Metal clusters: 2 O.O.O.O.O.O.[Na].[Na].[S][C][S].[S][C][S]. The MOF has largest included sphere 1.80 A, density 1.62 g/cm3, surface area 4231.70 m2/g, accessible volume 0.07 cm3/g