ZnC25N3H20O4(CH)3 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules and four ZnC25N3H20O4 clusters. In each ZnC25N3H20O4 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(2) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 2.06 Å. The Zn(1)-O(2) bond length is 2.07 Å. The Zn(1)-O(3) bond length is 2.08 Å. The Zn(1)-O(4) bond length is 2.06 Å. There are twenty-five inequivalent C sites. In the first C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(16) bond length is 1.40 Å. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(20) bond length is 1.50 Å. In the second C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(12) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(12) bond length is 1.09 Å. In the third C site, C(19) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one H(13) atom. The C(19)-C(14) bond length is 1.40 Å. The C(19)-H(13) bond length is 1.09 Å. In the fourth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(1), and one O(2) atom. The C(20)-O(1) bond length is 1.28 Å. The C(20)-O(2) bond length is 1.27 Å. In the fifth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(2), and one H(14) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-N(2) bond length is 1.34 Å. The C(21)-H(14) bond length is 1.09 Å. In the sixth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one H(15) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-H(15) bond length is 1.09 Å. In the seventh C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(28) bond length is 1.51 Å. In the eighth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(16) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(16) bond length is 1.09 Å. In the ninth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one N(2), and one H(17) atom. The C(25)-N(2) bond length is 1.35 Å. The C(25)-H(17) bond length is 1.09 Å. In the tenth C site, C(26) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(18), and one H(19) atom. The C(26)-N(3) bond length is 1.46 Å. The C(26)-H(18) bond length is 1.10 Å. The C(26)-H(19) bond length is 1.11 Å. In the eleventh C site, C(27) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(20), and one H(21) atom. The C(27)-N(3) bond length is 1.46 Å. The C(27)-H(20) bond length is 1.10 Å. The C(27)-H(21) bond length is 1.11 Å. In the twelfth C site, C(28) is bonded in a distorted trigonal non-coplanar geometry to one C(23), one N(3), one H(22), and one H(23) atom. The C(28)-N(3) bond length is 1.45 Å. The C(28)-H(22) bond length is 1.10 Å. The C(28)-H(23) bond length is 1.11 Å. In the thirteenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(3) bond length is 1.27 Å. The C(1)-O(4) bond length is 1.28 Å. In the fourteenth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the fifteenth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the sixteenth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2,3) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(2,3) bond length is 1.09 Å. In the seventeenth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-N(1) bond length is 1.40 Å. In the eighteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(2,3) atom. The C(6)-H(2,3) bond length is 1.09 Å. In the nineteenth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the twentieth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one N(1) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.41 Å. The C(8)-N(1) bond length is 1.42 Å. In the twenty-first C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5,9) atom. The C(9)-H(5,9) bond length is 1.09 Å. In the twenty-second C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(5,9) atom. The C(13)-H(5,9) bond length is 1.09 Å. In the twenty-third C site, C(14) is bonded in a distorted trigonal planar geometry to one C(15), one C(19), and one N(1) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-N(1) bond length is 1.42 Å. In the twenty-fourth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(10) atom. The C(15)-H(10) bond length is 1.09 Å. In the twenty-fifth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(11) atom. The C(16)-H(11) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(14), one C(5), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(21), and one C(25) atom. In the third N site, N(3) is bonded in a trigonal non-coplanar geometry to one C(26), one C(27), and one C(28) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5,9) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(26) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(21) is bonded in a single-bond geometry to one C(27) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one C(28) atom. In the eighteenth H site, H(23) is bonded in a single-bond geometry to one C(28) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(20) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(20) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. Linkers: 4 [O]C(=O)c1ccc(N(c2ccccc2)c2ccc(C([O])=O)cc2)cc1 ,2 c1cc(CN2CCN(Cc3ccncc3)CC2)ccn1. Metal clusters: 2 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 4.77 A, density 1.28 g/cm3, surface area 5001.10 m2/g, accessible volume 0.28 cm3/g