ZnC6H4(NO2)2(CH2)4(CH)8 is Indium-derived structured and crystallizes in the orthorhombic Pnna space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight isobutylene molecules, and four ZnC6H4(NO2)2 clusters. In each ZnC6H4(NO2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Zn(1)-N(1) bond lengths are 2.05 Å. Both Zn(1)-O(1) bond lengths are 1.95 Å. There are three inequivalent C sites. In the first C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5,8) atom. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(5,8) bond length is 1.09 Å. In the second C site, C(8) is bonded in a distorted trigonal planar geometry to one N(1) and one H(5,8) atom. The C(8)-N(1) bond length is 1.35 Å. The C(8)-H(5,8) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.31 Å. The C(1)-O(2) bond length is 1.25 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(4), and one C(8) atom. H(5,8) is bonded in a single-bond geometry to one C(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Linkers: 4 c1cc(CCc2ccncc2)ccn1 ,4 [O]C(=O)CCCCC([O])=O. Metal clusters: 4 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.32 A, density 1.29 g/cm3, surface area 5476.79 m2/g, accessible volume 0.28 cm3/g