NiC28H26(NO)4(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four NiC28H26(NO)4 clusters. In each NiC28H26(NO)4 cluster, Ni(1) is bonded in a distorted octahedral geometry to one N(2), one N(5), one O(1), one O(3), one O(5), and one O(7) atom. The Ni(1)-N(2) bond length is 2.02 Å. The Ni(1)-N(5) bond length is 2.01 Å. The Ni(1)-O(1) bond length is 2.07 Å. The Ni(1)-O(3) bond length is 2.14 Å. The Ni(1)-O(5) bond length is 2.15 Å. The Ni(1)-O(7) bond length is 2.29 Å. There are twenty-eight inequivalent C sites. In the first C site, C(59) is bonded in a trigonal planar geometry to one C(39), one C(57), and one C(63) atom. The C(59)-C(39) bond length is 1.39 Å. The C(59)-C(57) bond length is 1.43 Å. The C(59)-C(63) bond length is 1.51 Å. In the second C site, C(61) is bonded in a distorted trigonal non-coplanar geometry to one C(57); one H(57,58); one H(59,60); and one H(61,62) atom. The C(61)-C(57) bond length is 1.50 Å. The C(61)-H(57,58) bond length is 1.10 Å. The C(61)-H(59,60) bond length is 1.10 Å. The C(61)-H(61,62) bond length is 1.10 Å. In the third C site, C(63) is bonded in a distorted trigonal non-coplanar geometry to one C(59); one H(63,64); one H(65,66); and one H(67,68) atom. The C(63)-H(63,64) bond length is 1.10 Å. The C(63)-H(65,66) bond length is 1.10 Å. The C(63)-H(67,68) bond length is 1.10 Å. In the fourth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(10), one C(18), and one N(2) atom. The C(2)-C(10) bond length is 1.42 Å. The C(2)-C(18) bond length is 1.40 Å. The C(2)-N(2) bond length is 1.39 Å. In the fifth C site, C(3) is bonded in a trigonal planar geometry to one C(13); one C(15,16); and one C(19,20) atom. The C(3)-C(13) bond length is 1.49 Å. The C(3)-C(15,16) bond length is 1.40 Å. The C(3)-C(19,20) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(2); one N(3,4); and one H(1,2) atom. The C(6)-N(2) bond length is 1.33 Å. The C(6)-N(3,4) bond length is 1.36 Å. The C(6)-H(1,2) bond length is 1.08 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(3), and one O(5) atom. The C(7)-C(11) bond length is 1.49 Å. The C(7)-O(3) bond length is 1.28 Å. The C(7)-O(5) bond length is 1.28 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(2); one C(23,24); and one N(3,4) atom. The C(10)-C(23,24) bond length is 1.39 Å. The C(10)-N(3,4) bond length is 1.39 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(41), one C(44), and one C(7) atom. The C(11)-C(41) bond length is 1.40 Å. The C(11)-C(44) bond length is 1.40 Å. In the tenth C site, C(13) is bonded in a bent 120 degrees geometry to one C(3), one O(1), and one O(7) atom. The C(13)-O(1) bond length is 1.29 Å. The C(13)-O(7) bond length is 1.27 Å. In the eleventh C site, C(15,16) is bonded in a distorted single-bond geometry to one C(3) and one H(3,4,7,8) atom. The C(15,16)-H(3,4,7,8) bond length is 1.09 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(2); one C(21,22); and one H(5,6) atom. The C(18)-C(21,22) bond length is 1.40 Å. The C(18)-H(5,6) bond length is 1.09 Å. In the thirteenth C site, C(19,20) is bonded in a distorted single-bond geometry to one C(3) and one H(3,4,7,8) atom. The C(19,20)-H(3,4,7,8) bond length is 1.09 Å. In the fourteenth C site, C(21,22) is bonded in a trigonal planar geometry to one C(17), one C(31), and one C(45) atom. The C(21,22)-C(17) bond length is 1.40 Å. The C(21,22)-C(31) bond length is 1.43 Å. The C(21,22)-C(45) bond length is 1.50 Å. In the fifteenth C site, C(23,24) is bonded in a distorted trigonal planar geometry to one C(31); one C(9); and one H(9,10) atom. The C(23,24)-C(31) bond length is 1.39 Å. The C(23,24)-C(9) bond length is 1.39 Å. The C(23,24)-H(9,10) bond length is 1.09 Å. In the sixteenth C site, C(25,26) is bonded in a distorted trigonal non-coplanar geometry to one N(3,4) and two equivalent H(11,12,13,14) atoms. The C(25,26)-N(3,4) bond length is 1.46 Å. Both C(25,26)-H(11,12,13,14) bond lengths are 1.10 Å. In the seventeenth C site, C(27) is bonded in a trigonal planar geometry to one N(5); one N(7); and one H(15,16) atom. The C(27)-N(5) bond length is 1.33 Å. The C(27)-N(7) bond length is 1.36 Å. The C(27)-H(15,16) bond length is 1.08 Å. In the eighteenth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(33), one C(39), and one N(5) atom. The C(29)-C(33) bond length is 1.42 Å. The C(29)-C(39) bond length is 1.40 Å. The C(29)-N(5) bond length is 1.39 Å. In the nineteenth C site, C(32) is bonded in a trigonal planar geometry to one C(21,22); one C(23,24); and one C(49,50) atom. The C(32)-C(21,22) bond length is 1.43 Å. The C(32)-C(23,24) bond length is 1.39 Å. The C(32)-C(49,50) bond length is 1.50 Å. In the twentieth C site, C(33) is bonded in a distorted single-bond geometry to one C(29), one C(53), and one N(7) atom. The C(33)-C(53) bond length is 1.40 Å. The C(33)-N(7) bond length is 1.39 Å. In the twenty-first C site, C(39) is bonded in a distorted single-bond geometry to one C(29); one C(59); and one H(25,26) atom. The C(39)-H(25,26) bond length is 1.09 Å. In the twenty-second C site, C(41) is bonded in a distorted single-bond geometry to one C(11) and one H(27,28) atom. The C(41)-H(27,28) bond length is 1.09 Å. In the twenty-third C site, C(44) is bonded in a distorted single-bond geometry to one C(11) and one H(29,30) atom. The C(44)-H(29,30) bond length is 1.09 Å. In the twenty-fourth C site, C(46) is bonded in a distorted trigonal non-coplanar geometry to one C(21,22); one H(31,32); one H(33,34); and one H(35,36) atom. The C(46)-C(21,22) bond length is 1.50 Å. The C(46)-H(31,32) bond length is 1.10 Å. The C(46)-H(33,34) bond length is 1.10 Å. The C(46)-H(35,36) bond length is 1.10 Å. In the twenty-fifth C site, C(49,50) is bonded in a distorted trigonal non-coplanar geometry to one C(31); one H(41,42); one H(43,44); and one H(45,46) atom. The C(49,50)-C(31) bond length is 1.50 Å. The C(49,50)-H(41,42) bond length is 1.10 Å. The C(49,50)-H(43,44) bond length is 1.10 Å. The C(49,50)-H(45,46) bond length is 1.10 Å. In the twenty-sixth C site, C(53) is bonded in a distorted single-bond geometry to one C(33); one C(57); and one H(51,52) atom. The C(53)-C(57) bond length is 1.40 Å. The C(53)-H(51,52) bond length is 1.09 Å. In the twenty-seventh C site, C(55) is bonded in a distorted trigonal non-coplanar geometry to one N(7); one H(53,54); and one H(55,56) atom. The C(55)-N(7) bond length is 1.46 Å. The C(55)-H(53,54) bond length is 1.10 Å. The C(55)-H(55,56) bond length is 1.10 Å. In the twenty-eighth C site, C(57) is bonded in a trigonal planar geometry to one C(53), one C(59), and one C(61) atom. There are four inequivalent N sites. In the first N site, N(2) is bonded in a distorted trigonal planar geometry to one Ni(1), one C(2), and one C(6) atom. In the second N site, N(3,4) is bonded in a trigonal planar geometry to one C(25,26); one C(5); and one C(9) atom. The N(3,4)-C(5) bond length is 1.36 Å. The N(3,4)-C(9) bond length is 1.39 Å. In the third N site, N(5) is bonded in a distorted trigonal planar geometry to one Ni(1), one C(27), and one C(29) atom. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one C(27), one C(33), and one C(55) atom. There are twenty-four inequivalent H sites. In the first H site, H(63,64) is bonded in a single-bond geometry to one C(63) atom. In the second H site, H(65,66) is bonded in a single-bond geometry to one C(63) atom. In the third H site, H(1,2) is bonded in a single-bond geometry to one C(5) atom. The H(1,2)-C(5) bond length is 1.08 Å. In the fourth H site, H(67,68) is bonded in a single-bond geometry to one C(63) atom. In the fifth H site, H(3,4,7,8) is bonded in a single-bond geometry to one C(15,16) atom. In the sixth H site, H(5,6) is bonded in a single-bond geometry to one C(17) atom. The H(5,6)-C(17) bond length is 1.09 Å. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(23,24) atom. In the eighth H site, H(11,12,13,14) is bonded in a single-bond geometry to one C(25,26) atom. In the ninth H site, H(15,16) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(25,26) is bonded in a single-bond geometry to one C(39) atom. In the eleventh H site, H(27,28) is bonded in a single-bond geometry to one C(41) atom. In the twelfth H site, H(29,30) is bonded in a single-bond geometry to one C(43) atom. The H(29,30)-C(43) bond length is 1.09 Å. In the thirteenth H site, H(31,32) is bonded in a single-bond geometry to one C(45) atom. The H(31,32)-C(45) bond length is 1.10 Å. In the fourteenth H site, H(33,34) is bonded in a single-bond geometry to one C(45) atom. The H(33,34)-C(45) bond length is 1.10 Å. In the fifteenth H site, H(35,36) is bonded in a single-bond geometry to one C(45) atom. The H(35,36)-C(45) bond length is 1.10 Å. In the sixteenth H site, H(41,42) is bonded in a single-bond geometry to one C(49,50) atom. In the seventeenth H site, H(43,44) is bonded in a single-bond geometry to one C(49,50) atom. In the eighteenth H site, H(45,46) is bonded in a single-bond geometry to one C(49,50) atom. In the nineteenth H site, H(59,60) is bonded in a single-bond geometry to one C(61) atom. In the twentieth H site, H(51,52) is bonded in a single-bond geometry to one C(53) atom. In the twenty-first H site, H(53,54) is bonded in a single-bond geometry to one C(55) atom. In the twenty-second H site, H(55,56) is bonded in a single-bond geometry to one C(55) atom. In the twenty-third H site, H(61,62) is bonded in a single-bond geometry to one C(61) atom. In the twenty-fourth H site, H(57,58) is bonded in a single-bond geometry to one C(61) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Ni(1) and one C(13) atom. In the second O site, O(3) is bonded in an L-shaped geometry to one Ni(1) and one C(7) atom. In the third O site, O(5) is bonded in an L-shaped geometry to one Ni(1) and one C(7) atom. In the fourth O site, O(7) is bonded in a distorted single-bond geometry to one Ni(1) and one C(13) atom. Linkers: 2 [CH]C(=[CH])[C]1O[Ni]2(N3[CH]N(CCC[CH]C[CH][N]C=[N])c4cc(C)c(C)cc43)(N3[CH]N(CCCCCCn4cnc5cc(C)c(C)cc54)c4cc(C)c(C)cc43)(O1)O[C](c1ccc([C]3O[Ni]4(N5[CH]N(CCCCCCn6cnc7cc(C)c(C)cc76)c6cc(C)c(C)cc65)(N5[CH]N(CCCCCCn6cnc7cc(C)c(C)cc76)c6cc(C)c(C)cc65)(O3)O[C](c3ccc(C([O])=O)cc3)O4)cc1)O2 ,2 Cc1cc2c(cc1C)N([Ni]13(N4[CH]N(CCCCCCn5cnc6cc(C)c(C)cc65)c5cc(C)c(C)cc54)(O[C](c4ccc([C]5O[Ni]6(N7[CH]N(CCCCCCn8cnc9cc(C)c(C)cc98)c8cc(C)c(C)cc87)(N7[CH]N(CCCCCCn8cnc9cc(C)c(C)cc98)c8cc(C)c(C)cc87)(O5)O[C](c5ccc(C([O])=O)cc5)O6)cc4)O1)O[C](c1ccc(C([O])=O)cc1)O3)[CH]N2CCC[CH]C[CH][N]C=[N] ,2 [CH]N(/[C]=C/[C][CH2])CCCCCCN1[CH]N([Ni]23(N4[CH]N(CCCCCCn5cnc6cc(C)c(C)cc65)c5cc(C)c(C)cc54)(O[C](c4ccc(C([O])=O)cc4)O2)OC(=[C]C=[CH])O3)c2cc(C)c(C)cc21 ,1 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 [C]1O[Ni]2(O1)O[C]O2. The MOF has largest included sphere 4.29 A, density 1.27 g/cm3, surface area 5338.80 m2/g, accessible volume 0.23 cm3/g