NiC6H4(NO2)2(C3H2)2(CH)10(CH3)2(C2HO)2(H2O)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; four 02329_fluka molecules; two 2,3-dimethyl-1,3-butadiene molecules; four dimethyl ether molecules; four propylene molecules; four water molecules; and two NiC6H4(NO2)2 clusters. In each NiC6H4(NO2)2 cluster, Ni(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Ni(1)-N(1) bond lengths are 1.93 Å. Both Ni(1)-O(1) bond lengths are 1.90 Å. There are three inequivalent C sites. In the first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(3) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(4)-O(1) bond length is 1.29 Å. The C(4)-O(3) bond length is 1.25 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(3), and one C(5) atom. There are two inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one C(4) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(4) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Ni]. The MOF has largest included sphere 2.95 A, density 1.43 g/cm3, surface area 5321.34 m2/g, accessible volume 0.22 cm3/g