(CuC5NH4O5)2(CH2)5C2NH2OC3NH4O is Indium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of twenty 02329_fluka molecules, four n-methylacetamide molecules, four n-methylformamide molecules, and four CuC5NH4O5 clusters. In each CuC5NH4O5 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square pyramidal geometry to one O(1), one O(10), one O(12), one O(4), and one O(8) atom. The Cu(1)-O(1) bond length is 1.99 Å. The Cu(1)-O(10) bond length is 2.02 Å. The Cu(1)-O(12) bond length is 2.27 Å. The Cu(1)-O(4) bond length is 1.99 Å. The Cu(1)-O(8) bond length is 2.04 Å. In the second Cu site, Cu(2) is bonded in a square pyramidal geometry to one O(11), one O(2), one O(5), one O(6), and one O(7) atom. The Cu(2)-O(11) bond length is 2.01 Å. The Cu(2)-O(2) bond length is 2.00 Å. The Cu(2)-O(5) bond length is 1.98 Å. The Cu(2)-O(6) bond length is 2.11 Å. The Cu(2)-O(7) bond length is 2.04 Å. There are ten inequivalent C sites. In the first C site, C(7) is bonded in a distorted water-like geometry to one C(6), one H(6), and one H(7) atom. The C(7)-C(6) bond length is 1.52 Å. The C(7)-H(6) bond length is 1.10 Å. The C(7)-H(7) bond length is 1.10 Å. In the second C site, C(9) is bonded in a distorted water-like geometry to one N(2) and one H(10) atom. The C(9)-N(2) bond length is 1.44 Å. The C(9)-H(10) bond length is 1.10 Å. In the third C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(10)-O(4) bond length is 1.27 Å. The C(10)-O(5) bond length is 1.27 Å. In the fourth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(15)-O(7) bond length is 1.26 Å. The C(15)-O(8) bond length is 1.27 Å. In the fifth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one N(4), and one O(12) atom. The C(16)-C(17) bond length is 1.52 Å. The C(16)-N(4) bond length is 1.35 Å. The C(16)-O(12) bond length is 1.25 Å. In the sixth C site, C(17) is bonded in a distorted water-like geometry to one C(16), one H(16), and one H(17) atom. The C(17)-H(16) bond length is 1.10 Å. The C(17)-H(17) bond length is 1.10 Å. In the seventh C site, C(19) is bonded in a distorted water-like geometry to one N(4) and one H(20) atom. The C(19)-N(4) bond length is 1.44 Å. The C(19)-H(20) bond length is 1.10 Å. In the eighth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(11) atom. The C(20)-O(10) bond length is 1.27 Å. The C(20)-O(11) bond length is 1.27 Å. In the ninth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(5)-O(1) bond length is 1.28 Å. The C(5)-O(2) bond length is 1.27 Å. In the tenth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(2), and one O(6) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-O(6) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one C(6), one C(9), and one H(22) atom. The N(2)-H(22) bond length is 1.03 Å. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(16), one C(19), and one H(24) atom. The N(4)-H(24) bond length is 1.02 Å. There are eight inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one N(2) atom. In the eighth H site, H(24) is bonded in a single-bond geometry to one N(4) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(5) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(5) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(10) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(10) atom. In the fifth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(6) atom. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(15) atom. In the seventh O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(15) atom. In the eighth O site, O(10) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(20) atom. In the ninth O site, O(11) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(20) atom. In the tenth O site, O(12) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(16) atom. Linkers: 8 [O]C(=O)[C@@H]1CCC(=O)N1. Metal clusters: 8 [Cu]. The MOF has largest included sphere 4.53 A, density 1.25 g/cm3, surface area 4252.75 m2/g, accessible volume 0.33 cm3/g