ZnC28H34(N2O3)2(CH2)2 is Calaverite structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one ZnC28H34(N2O3)2 cluster. In the ZnC28H34(N2O3)2 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1,2); one O(3); and one O(4) atom. Both Zn(1)-N(1,2) bond lengths are 2.06 Å. The Zn(1)-O(3) bond length is 1.94 Å. The Zn(1)-O(4) bond length is 1.94 Å. There are eighteen inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal planar geometry to one C(3), one C(9), and one H(3) atom. The C(1,2)-C(3) bond length is 1.39 Å. The C(1,2)-C(9) bond length is 1.41 Å. The C(1,2)-H(3) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(1,2); one N(1,2); and one H(5,6) atom. The C(3)-N(1,2) bond length is 1.35 Å. The C(3)-H(5,6) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(1,2); one N(1,2); and one H(5,6) atom. The C(4)-C(1,2) bond length is 1.39 Å. The C(4)-N(1,2) bond length is 1.35 Å. The C(4)-H(5,6) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(7,8); one N(1,2); and one H(7,8) atom. The C(5)-C(7,8) bond length is 1.38 Å. The C(5)-N(1,2) bond length is 1.35 Å. The C(5)-H(7,8) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7,8); one N(1,2); and one H(7,8) atom. The C(6)-C(7,8) bond length is 1.38 Å. The C(6)-N(1,2) bond length is 1.35 Å. The C(6)-H(7,8) bond length is 1.09 Å. In the sixth C site, C(7,8) is bonded in a distorted single-bond geometry to one C(5), one C(9), and one H(9) atom. The C(7,8)-C(9) bond length is 1.41 Å. The C(7,8)-H(9) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(1,2); one C(7,8); and one N(3,4) atom. The C(9)-N(3,4) bond length is 1.38 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(1,2); one C(7,8); and one N(3,4) atom. The C(10)-C(1,2) bond length is 1.41 Å. The C(10)-C(7,8) bond length is 1.41 Å. The C(10)-N(3,4) bond length is 1.38 Å. In the ninth C site, C(11,12) is bonded in a distorted bent 120 degrees geometry to one N(3,4) and one O(1,2) atom. The C(11,12)-N(3,4) bond length is 1.39 Å. The C(11,12)-O(1,2) bond length is 1.23 Å. In the tenth C site, C(13,14) is bonded in a single-bond geometry to one C(21,22) and one H(11,12) atom. The C(13,14)-C(21,22) bond length is 1.58 Å. The C(13,14)-H(11,12) bond length is 1.10 Å. In the eleventh C site, C(17,18) is bonded in a distorted water-like geometry to one C(19); one H(17,18); and one H(19,20) atom. The C(17,18)-C(19) bond length is 1.54 Å. The C(17,18)-H(17,18) bond length is 1.10 Å. The C(17,18)-H(19,20) bond length is 1.10 Å. In the twelfth C site, C(19) is bonded in a tetrahedral geometry to one C(17,18); one C(21,22); one C(27,28); and one C(29,30) atom. The C(19)-C(21,22) bond length is 1.58 Å. The C(19)-C(27,28) bond length is 1.54 Å. The C(19)-C(29,30) bond length is 1.54 Å. In the thirteenth C site, C(20) is bonded in a tetrahedral geometry to one C(17,18); one C(21,22); one C(27,28); and one C(29,30) atom. The C(20)-C(17,18) bond length is 1.54 Å. The C(20)-C(21,22) bond length is 1.58 Å. The C(20)-C(27,28) bond length is 1.54 Å. The C(20)-C(29,30) bond length is 1.54 Å. In the fourteenth C site, C(21,22) is bonded in a tetrahedral geometry to one C(13,14); one C(19); one C(23,24); and one C(25,26) atom. The C(21,22)-C(23,24) bond length is 1.54 Å. The C(21,22)-C(25,26) bond length is 1.53 Å. In the fifteenth C site, C(23,24) is bonded in a trigonal non-coplanar geometry to one C(21,22); one H(21,22); one H(23,24); and one H(25,26) atom. The C(23,24)-H(21,22) bond length is 1.10 Å. The C(23,24)-H(23,24) bond length is 1.10 Å. The C(23,24)-H(25,26) bond length is 1.10 Å. In the sixteenth C site, C(25,26) is bonded in a trigonal non-coplanar geometry to one C(21,22); one H(27,28); one H(29,30); and one H(31,32) atom. The C(25,26)-H(27,28) bond length is 1.10 Å. The C(25,26)-H(29,30) bond length is 1.10 Å. The C(25,26)-H(31,32) bond length is 1.10 Å. In the seventeenth C site, C(27,28) is bonded in a trigonal non-coplanar geometry to one C(19); one H(33,34); one H(35,36); and one H(37,38) atom. The C(27,28)-H(33,34) bond length is 1.09 Å. The C(27,28)-H(35,36) bond length is 1.10 Å. The C(27,28)-H(37,38) bond length is 1.10 Å. In the eighteenth C site, C(29,30) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(3), and one O(5) atom. The C(29,30)-O(3) bond length is 1.30 Å. The C(29,30)-O(5) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(1,2) is bonded in a trigonal planar geometry to one Zn(1), one C(3), and one C(5) atom. In the second N site, N(3,4) is bonded in a trigonal planar geometry to one C(11,12); one C(9); and one H(1,2) atom. The N(3,4)-H(1,2) bond length is 1.02 Å. There are nineteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one N(3,4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(1,2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(1,2) atom. The H(4)-C(1,2) bond length is 1.09 Å. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7,8) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(7,8) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(7,8) atom. The H(10)-C(7,8) bond length is 1.09 Å. In the eighth H site, H(11,12) is bonded in a single-bond geometry to one C(13,14) atom. In the ninth H site, H(17,18) is bonded in a single-bond geometry to one C(17,18) atom. In the tenth H site, H(19,20) is bonded in a single-bond geometry to one C(17,18) atom. In the eleventh H site, H(21,22) is bonded in a single-bond geometry to one C(23,24) atom. In the twelfth H site, H(23,24) is bonded in a single-bond geometry to one C(23,24) atom. In the thirteenth H site, H(25,26) is bonded in a single-bond geometry to one C(23,24) atom. In the fourteenth H site, H(27,28) is bonded in a single-bond geometry to one C(25,26) atom. In the fifteenth H site, H(29,30) is bonded in a single-bond geometry to one C(25,26) atom. In the sixteenth H site, H(31,32) is bonded in a single-bond geometry to one C(25,26) atom. In the seventeenth H site, H(33,34) is bonded in a single-bond geometry to one C(27,28) atom. In the eighteenth H site, H(35,36) is bonded in a single-bond geometry to one C(27,28) atom. In the nineteenth H site, H(37,38) is bonded in a single-bond geometry to one C(27,28) atom. There are five inequivalent O sites. In the first O site, O(1,2) is bonded in a single-bond geometry to one C(11,12) atom. In the second O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(29,30) atom. In the third O site, O(4) is bonded in a water-like geometry to one Zn(1) and one C(29,30) atom. The O(4)-C(29,30) bond length is 1.30 Å. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(29,30) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(29,30) atom. The O(6)-C(29,30) bond length is 1.25 Å. Linkers: 2 CC1(C)[C@@H](C(=O)Nc2ccncc2)C[CH][C@@]1(C)[C][O] ,2 CC1(C)[C@@H](C(=O)Nc2ccncc2)CC[C@@]1(C)C([O])=O ,2 CC1(C)[C@@H](C(=O)Nc2c[c]ncc2)CC[C@@]1(C)C([O])=O. Metal clusters: 1 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.30 A, density 1.33 g/cm3, surface area 5279.79 m2/g, accessible volume 0.23 cm3/g