AgC8NH6O7 crystallizes in the triclinic P-1 space group. Ag(1) is bonded in a 5-coordinate geometry to one N(1), one O(1), one O(7), and two equivalent O(4) atoms. The Ag(1)-N(1) bond length is 2.29 Å. The Ag(1)-O(1) bond length is 2.57 Å. The Ag(1)-O(7) bond length is 2.28 Å. There is one shorter (2.44 Å) and one longer (2.80 Å) Ag(1)-O(4) bond length. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(1) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-N(1) bond length is 1.35 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(5) atom. The C(3)-C(4) bond length is 1.50 Å. The C(3)-C(5) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(4) atom. The C(4)-O(3) bond length is 1.32 Å. The C(4)-O(4) bond length is 1.24 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3), one C(6), and one H(1) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(1) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. The C(6)-C(7) bond length is 1.49 Å. The C(6)-C(8) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(5), and one O(6) atom. The C(7)-O(5) bond length is 1.31 Å. The C(7)-O(6) bond length is 1.25 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(2) atom. The C(8)-N(1) bond length is 1.34 Å. The C(8)-H(2) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(2), and one C(8) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(7) atom. The H(3)-O(7) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(7) atom. The H(4)-O(7) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a linear geometry to one O(1) and one O(5) atom. The H(5)-O(1) bond length is 1.43 Å. The H(5)-O(5) bond length is 1.07 Å. In the sixth H site, H(6) is bonded in a distorted bent 150 degrees geometry to one O(2) and one O(3) atom. The H(6)-O(2) bond length is 1.57 Å. The H(6)-O(3) bond length is 1.02 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one C(1), and one H(5) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one C(1) and one H(6) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(4) and one H(6) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(7) and one H(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Ag(1), one H(3), and one H(4) atom. Linkers: 1 [O]C(=O)c1ncc(C(=O)O)cc1C(=O)O. Metal clusters: 2 [Ag]. The MOF has largest included sphere 1.91 A, density 2.40 g/cm3, surface area 2900.74 m2/g, accessible volume 0.08 cm3/g