Zn3C24H22S2(N2O)8 crystallizes in the monoclinic C2/c space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(1), one N(3), one N(5), one N(7), and one O(2) atom to form distorted ZnN4O trigonal bipyramids that share  a cornercorner with one S(1)O4 tetrahedra. The Zn(1)-N(1) bond length is 2.07 Å. The Zn(1)-N(3) bond length is 2.29 Å. The Zn(1)-N(5) bond length is 2.04 Å. The Zn(1)-N(7) bond length is 2.11 Å. The Zn(1)-O(2) bond length is 2.03 Å. In the second Zn site, Zn(2) is bonded to two equivalent N(8) and two equivalent O(4) atoms to form ZnN2O2 tetrahedra that share corners with two equivalent S(1)O4 tetrahedra. Both Zn(2)-N(8) bond lengths are 1.97 Å. Both Zn(2)-O(4) bond lengths are 1.99 Å. There are twelve inequivalent C sites. In the first C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(6), and one H(9) atom. The C(8)-C(7) bond length is 1.37 Å. The C(8)-N(6) bond length is 1.38 Å. The C(8)-H(9) bond length is 1.08 Å. In the second C site, C(9) is bonded in a distorted water-like geometry to one C(10), one N(5), and one N(6) atom. The C(9)-C(10) bond length is 1.45 Å. The C(9)-N(5) bond length is 1.35 Å. The C(9)-N(6) bond length is 1.36 Å. In the third C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(7), and one N(8) atom. The C(10)-N(7) bond length is 1.35 Å. The C(10)-N(8) bond length is 1.36 Å. In the fourth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(8), and one H(10) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-N(8) bond length is 1.38 Å. The C(11)-H(10) bond length is 1.09 Å. In the fifth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(7), and one H(11) atom. The C(12)-N(7) bond length is 1.37 Å. The C(12)-H(11) bond length is 1.08 Å. In the sixth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(4) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.37 Å. The C(1)-H(4) bond length is 1.08 Å. In the seventh C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(2), and one H(5) atom. The C(2)-N(2) bond length is 1.38 Å. The C(2)-H(5) bond length is 1.08 Å. In the eighth C site, C(3) is bonded in a distorted water-like geometry to one C(4), one N(1), and one N(2) atom. The C(3)-C(4) bond length is 1.44 Å. The C(3)-N(1) bond length is 1.34 Å. The C(3)-N(2) bond length is 1.35 Å. In the ninth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one N(3), and one N(4) atom. The C(4)-N(3) bond length is 1.34 Å. The C(4)-N(4) bond length is 1.36 Å. In the tenth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(4), and one H(6) atom. The C(5)-C(6) bond length is 1.38 Å. The C(5)-N(4) bond length is 1.38 Å. The C(5)-H(6) bond length is 1.08 Å. In the eleventh C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(3), and one H(7) atom. The C(6)-N(3) bond length is 1.37 Å. The C(6)-H(7) bond length is 1.09 Å. In the twelfth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(5), and one H(8) atom. The C(7)-N(5) bond length is 1.37 Å. The C(7)-H(8) bond length is 1.08 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(3), and one H(1) atom. The N(2)-H(1) bond length is 1.05 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Zn(1), one C(4), and one C(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(4), one C(5), and one H(2) atom. The N(4)-H(2) bond length is 1.04 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(7), and one C(9) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(8), one C(9), and one H(3) atom. The N(6)-H(3) bond length is 1.03 Å. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(10), and one C(12) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Zn(2), one C(10), and one C(11) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one N(2) and one O(3) atom. The H(1)-O(3) bond length is 1.62 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one N(4) and one O(2) atom. The H(2)-O(2) bond length is 1.72 Å. In the third H site, H(3) is bonded in a single-bond geometry to one N(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(12) atom. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share  a cornercorner with one Zn(2)N2O2 tetrahedra and  a cornercorner with one Zn(1)N4O trigonal bipyramid. The S(1)-O(1) bond length is 1.46 Å. The S(1)-O(2) bond length is 1.53 Å. The S(1)-O(3) bond length is 1.48 Å. The S(1)-O(4) bond length is 1.51 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one H(2), and one S(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one H(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one S(1) atom. Linkers: 3 C1=CN=C(c2ncc[nH]2)[N]1 ,1 [CH]1C=NC(c2ncc[nH]2)=N1 ,2 c1c[nH]c(-c2ncc[nH]2)n1. Metal clusters: 2 [O]S([O])(O[Zn])O[Zn]OS([O])([O])O[Zn]. The MOF has largest included sphere 2.17 A, density 1.95 g/cm3, surface area 3920.37 m2/g, accessible volume 0.08 cm3/g