SnC5NH11SO2 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four SnC5NH11SO2 clusters. Sn(1) is bonded in a trigonal bipyramidal geometry to one C(4), one C(5), one N(1), one S(1), and one O(1) atom. The Sn(1)-C(4) bond length is 2.15 Å. The Sn(1)-C(5) bond length is 2.15 Å. The Sn(1)-N(1) bond length is 2.37 Å. The Sn(1)-S(1) bond length is 2.45 Å. The Sn(1)-O(1) bond length is 2.24 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a 2-coordinate geometry to one N(1) and one H(3) atom. The C(2)-N(1) bond length is 1.47 Å. The C(2)-H(3) bond length is 1.11 Å. In the third C site, C(3) is bonded in a distorted water-like geometry to one H(4), one H(5), and one S(1) atom. The C(3)-H(4) bond length is 1.10 Å. The C(3)-H(5) bond length is 1.10 Å. The C(3)-S(1) bond length is 1.83 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(6), one H(7), and one H(8) atom. The C(4)-H(6) bond length is 1.10 Å. The C(4)-H(7) bond length is 1.10 Å. The C(4)-H(8) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(10), one H(11), and one H(9) atom. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(11) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. N(1) is bonded in a 4-coordinate geometry to one Sn(1), one C(2), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.04 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(5) atom. S(1) is bonded in an L-shaped geometry to one Sn(1) and one C(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Sn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Linkers: 4 N[C@@H](C[S])C([O])=O. Metal clusters: 4 [Sn]. The MOF has largest included sphere 3.79 A, density 1.59 g/cm3, surface area 3829.87 m2/g, accessible volume 0.23 cm3/g