Mn2C12N5H8O8CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a Mn2C12N5H8O8 framework. In the Mn2C12N5H8O8 framework, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one N(2), one O(1), one O(2), one O(3), one O(6), and one O(8) atom to form MnNO5 octahedra that share  a cornercorner with one Mn(2)O6 octahedra and  an edgeedge with one Mn(3)N2O4 octahedra. The corner-sharing octahedral tilt angles are 61°. The Mn(1)-N(2) bond length is 2.19 Å. The Mn(1)-O(1) bond length is 2.16 Å. The Mn(1)-O(2) bond length is 2.26 Å. The Mn(1)-O(3) bond length is 2.10 Å. The Mn(1)-O(6) bond length is 2.14 Å. The Mn(1)-O(8) bond length is 2.16 Å. In the second Mn site, Mn(2) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles are 61°. Both Mn(2)-O(1) bond lengths are 2.16 Å. Both Mn(2)-O(4) bond lengths are 2.16 Å. Both Mn(2)-O(5) bond lengths are 2.14 Å. In the third Mn site, Mn(3) is bonded to two equivalent N(2), two equivalent O(2), and two equivalent O(7) atoms to form edge-sharing MnN2O4 octahedra. Both Mn(3)-N(2) bond lengths are 2.24 Å. Both Mn(3)-O(2) bond lengths are 2.20 Å. Both Mn(3)-O(7) bond lengths are 2.11 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(12), one C(4), and one C(5) atom. The C(1)-C(12) bond length is 1.50 Å. The C(1)-C(4) bond length is 1.39 Å. The C(1)-C(5) bond length is 1.40 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(13), one C(3), and one C(8) atom. The C(2)-C(13) bond length is 1.39 Å. The C(2)-C(3) bond length is 1.51 Å. The C(2)-C(8) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(3)-O(3) bond length is 1.27 Å. The C(3)-O(4) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one H(1) atom. The C(4)-N(1) bond length is 1.36 Å. The C(4)-H(1) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(5)-H(2) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(7)-N(1) bond length is 1.36 Å. The C(7)-H(4) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(10), one C(2), and one H(5) atom. The C(8)-C(10) bond length is 1.39 Å. The C(8)-H(5) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one H(9), one O(2), and one O(5) atom. The C(9)-H(9) bond length is 1.11 Å. The C(9)-O(2) bond length is 1.28 Å. The C(9)-O(5) bond length is 1.25 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(10)-H(6) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(7) atom. The C(11)-N(5) bond length is 1.37 Å. The C(11)-H(7) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(6), and one O(7) atom. The C(12)-O(6) bond length is 1.27 Å. The C(12)-O(7) bond length is 1.27 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(5), and one H(8) atom. The C(13)-N(5) bond length is 1.36 Å. The C(13)-H(8) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(4), one C(7), and one O(1) atom. The N(1)-O(1) bond length is 1.34 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one N(3) atom. The N(2)-N(3) bond length is 1.22 Å. In the third N site, N(3) is bonded in a linear geometry to one N(2) and one N(4) atom. The N(3)-N(4) bond length is 1.16 Å. In the fourth N site, N(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(11), one C(13), and one O(8) atom. The N(5)-O(8) bond length is 1.32 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one N(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(3), and one C(9) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Mn(2) and one C(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(9) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(12) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mn(3) and one C(12) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(1) and one N(5) atom. Linkers: 4 [O]C(=O)c1ccc[n+]([O-])c1. Metal clusters: 4 [Mn]. The MOF has largest included sphere 3.75 A, density 1.70 g/cm3, surface area 3364.84 m2/g, accessible volume 0.16 cm3/g