(AgC5N5H7O2)2(CH2)3 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and two AgC5N5H7O2 clusters. In each AgC5N5H7O2 cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted T-shaped geometry to one N(1), one O(2), and one O(3) atom. The Ag(1)-N(1) bond length is 2.40 Å. The Ag(1)-O(2) bond length is 2.22 Å. The Ag(1)-O(3) bond length is 2.21 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one N(6), one O(1), and one O(4) atom. The Ag(2)-N(6) bond length is 2.36 Å. The Ag(2)-O(1) bond length is 2.26 Å. The Ag(2)-O(4) bond length is 2.24 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(4) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-N(2) bond length is 1.37 Å. The C(1)-N(4) bond length is 1.33 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one N(3) atom. The C(2)-C(4) bond length is 1.49 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-N(3) bond length is 1.33 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(3), and one N(5) atom. The C(3)-N(1) bond length is 1.36 Å. The C(3)-N(3) bond length is 1.36 Å. The C(3)-N(5) bond length is 1.33 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one H(1), one H(2), and one H(3) atom. The C(4)-H(1) bond length is 1.09 Å. The C(4)-H(2) bond length is 1.09 Å. The C(4)-H(3) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(10), one N(6), and one N(7) atom. The C(5)-N(10) bond length is 1.34 Å. The C(5)-N(6) bond length is 1.36 Å. The C(5)-N(7) bond length is 1.36 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(8), one N(7), and one N(8) atom. The C(6)-C(8) bond length is 1.49 Å. The C(6)-N(7) bond length is 1.34 Å. The C(6)-N(8) bond length is 1.33 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one N(6), one N(8), and one N(9) atom. The C(7)-N(6) bond length is 1.36 Å. The C(7)-N(8) bond length is 1.36 Å. The C(7)-N(9) bond length is 1.34 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one H(4), one H(5), and one H(6) atom. The C(8)-H(4) bond length is 1.09 Å. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.10 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(9)-O(1) bond length is 1.27 Å. The C(9)-O(2) bond length is 1.28 Å. In the tenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(13)-O(3) bond length is 1.27 Å. The C(13)-O(4) bond length is 1.27 Å. There are ten inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one H(13), and one H(14) atom. The N(4)-H(13) bond length is 1.02 Å. The N(4)-H(14) bond length is 1.03 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(3), one H(15), and one H(16) atom. The N(5)-H(15) bond length is 1.03 Å. The N(5)-H(16) bond length is 1.02 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Ag(2), one C(5), and one C(7) atom. In the seventh N site, N(7) is bonded in a bent 120 degrees geometry to one C(5) and one C(6) atom. In the eighth N site, N(8) is bonded in a bent 120 degrees geometry to one C(6) and one C(7) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(7), one H(17), and one H(18) atom. The N(9)-H(17) bond length is 1.04 Å. The N(9)-H(18) bond length is 1.02 Å. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one C(5), one H(19), and one H(20) atom. The N(10)-H(19) bond length is 1.03 Å. The N(10)-H(20) bond length is 1.03 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one N(4) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one N(5) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one N(5) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one N(9) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one N(9) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one N(10) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one N(10) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(2) and one C(9) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one C(9) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one C(13) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one Ag(2) and one C(13) atom. Linkers: 2 [O]C(=O)CCCC([O])=O. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.93 A, density 2.21 g/cm3, surface area 3383.71 m2/g, accessible volume 0.08 cm3/g