ZnC33PN4H23O7 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ZnC33PN4H23O7 clusters. Zn(1) is bonded in a tetrahedral geometry to one N(6), one N(7), one O(1), and one O(3) atom. The Zn(1)-N(6) bond length is 1.99 Å. The Zn(1)-N(7) bond length is 2.02 Å. The Zn(1)-O(1) bond length is 1.98 Å. The Zn(1)-O(3) bond length is 1.97 Å. There are thirty-three inequivalent C sites. In the first C site, C(15,16) is bonded in a distorted single-bond geometry to one C(1) and one H(5,6) atom. The C(15,16)-C(1) bond length is 1.40 Å. The C(15,16)-H(5,6) bond length is 1.09 Å. In the second C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(7) atom. The C(17)-C(7) bond length is 1.51 Å. The C(17)-O(3) bond length is 1.30 Å. The C(17)-O(7) bond length is 1.25 Å. In the third C site, C(20) is bonded in a trigonal planar geometry to one N(2); one N(6); and one H(7,8) atom. The C(20)-N(2) bond length is 1.36 Å. The C(20)-N(6) bond length is 1.33 Å. The C(20)-H(7,8) bond length is 1.09 Å. In the fourth C site, C(21,22) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(9) atom. The C(21,22)-C(1) bond length is 1.40 Å. The C(21,22)-C(5) bond length is 1.39 Å. The C(21,22)-H(9) bond length is 1.09 Å. In the fifth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(37,38); one C(43,44); and one N(3,4) atom. The C(23)-C(37,38) bond length is 1.40 Å. The C(23)-C(43,44) bond length is 1.40 Å. The C(23)-N(3,4) bond length is 1.42 Å. In the sixth C site, C(25) is bonded in a trigonal planar geometry to one N(3,4); one N(7); and one H(11,12) atom. The C(25)-N(3,4) bond length is 1.36 Å. The C(25)-N(7) bond length is 1.33 Å. The C(25)-H(11,12) bond length is 1.08 Å. In the seventh C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(30); one N(2); and one H(13,14) atom. The C(28)-C(30) bond length is 1.37 Å. The C(28)-N(2) bond length is 1.39 Å. The C(28)-H(13,14) bond length is 1.09 Å. In the eighth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(28); one N(6); and one H(15,16) atom. The C(30)-N(6) bond length is 1.38 Å. The C(30)-H(15,16) bond length is 1.08 Å. In the ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(3) and one H(17,18) atom. The C(31)-C(3) bond length is 1.40 Å. The C(31)-H(17,18) bond length is 1.09 Å. In the tenth C site, C(33,34) is bonded in a trigonal planar geometry to one C(47,48); one C(57,58); and one P(1) atom. The C(33,34)-C(47,48) bond length is 1.40 Å. The C(33,34)-C(57,58) bond length is 1.40 Å. The C(33,34)-P(1) bond length is 1.81 Å. In the eleventh C site, C(35) is bonded in a distorted single-bond geometry to one C(9,10) and one H(19,20) atom. The C(35)-C(9,10) bond length is 1.40 Å. The C(35)-H(19,20) bond length is 1.09 Å. In the twelfth C site, C(37,38) is bonded in a distorted single-bond geometry to one C(23) and one H(21,22) atom. The C(37,38)-H(21,22) bond length is 1.09 Å. In the thirteenth C site, C(39) is bonded in a distorted single-bond geometry to one C(9,10) and one H(23,24) atom. The C(39)-C(9,10) bond length is 1.40 Å. The C(39)-H(23,24) bond length is 1.09 Å. In the fourteenth C site, C(41) is bonded in a distorted single-bond geometry to one C(7) and one H(27,28) atom. The C(41)-C(7) bond length is 1.40 Å. The C(41)-H(27,28) bond length is 1.09 Å. In the fifteenth C site, C(43,44) is bonded in a distorted single-bond geometry to one C(23) and one H(29,30) atom. The C(43,44)-H(29,30) bond length is 1.09 Å. In the sixteenth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(13); one N(7); and one H(31,32) atom. The C(45)-C(13) bond length is 1.37 Å. The C(45)-N(7) bond length is 1.38 Å. The C(45)-H(31,32) bond length is 1.08 Å. In the seventeenth C site, C(47,48) is bonded in a distorted single-bond geometry to one C(33,34) and one H(33,34) atom. The C(47,48)-H(33,34) bond length is 1.09 Å. In the eighteenth C site, C(49,50) is bonded in a distorted bent 120 degrees geometry to one C(53), one O(11), and one O(13) atom. The C(49,50)-C(53) bond length is 1.49 Å. The C(49,50)-O(11) bond length is 1.33 Å. The C(49,50)-O(13) bond length is 1.23 Å. In the nineteenth C site, C(51,52) is bonded in a distorted single-bond geometry to one C(53) and one H(35) atom. The C(51,52)-C(53) bond length is 1.40 Å. The C(51,52)-H(35) bond length is 1.09 Å. In the twentieth C site, C(53) is bonded in a trigonal planar geometry to one C(49,50); one C(51,52); and one C(55,56) atom. The C(53)-C(55,56) bond length is 1.40 Å. In the twenty-first C site, C(55,56) is bonded in a distorted single-bond geometry to one C(53) and one H(37) atom. The C(55,56)-H(37) bond length is 1.09 Å. In the twenty-second C site, C(57,58) is bonded in a distorted single-bond geometry to one C(33,34) and one H(39,40) atom. The C(57,58)-H(39,40) bond length is 1.09 Å. In the twenty-third C site, C(60) is bonded in a distorted trigonal planar geometry to one C(62), one C(66), and one N(2) atom. The C(60)-C(62) bond length is 1.39 Å. The C(60)-C(66) bond length is 1.39 Å. The C(60)-N(2) bond length is 1.43 Å. In the twenty-fourth C site, C(62) is bonded in a distorted single-bond geometry to one C(60) and one H(42) atom. The C(62)-H(42) bond length is 1.09 Å. In the twenty-fifth C site, C(63) is bonded in a distorted single-bond geometry to one C(7) and one H(43,44) atom. The C(63)-C(7) bond length is 1.40 Å. The C(63)-H(43,44) bond length is 1.09 Å. In the twenty-sixth C site, C(1) is bonded in a trigonal planar geometry to one C(15,16); one C(21,22); and one P(1) atom. The C(1)-P(1) bond length is 1.81 Å. In the twenty-seventh C site, C(66) is bonded in a distorted single-bond geometry to one C(60) and one H(46) atom. The C(66)-H(46) bond length is 1.09 Å. In the twenty-eighth C site, C(3) is bonded in a trigonal planar geometry to one C(11), one C(31), and one C(5) atom. The C(3)-C(11) bond length is 1.50 Å. The C(3)-C(5) bond length is 1.40 Å. In the twenty-ninth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(21,22); one C(3); and one H(1,2) atom. The C(5)-H(1,2) bond length is 1.09 Å. In the thirtieth C site, C(7) is bonded in a trigonal planar geometry to one C(17), one C(41), and one C(63) atom. In the thirty-first C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(45); one N(3,4); and one H(3,4) atom. The C(13)-N(3,4) bond length is 1.39 Å. The C(13)-H(3,4) bond length is 1.08 Å. In the thirty-second C site, C(9,10) is bonded in a trigonal planar geometry to one C(35), one C(39), and one P(1) atom. The C(9,10)-P(1) bond length is 1.81 Å. In the thirty-third C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(9) atom. The C(11)-O(1) bond length is 1.29 Å. The C(11)-O(9) bond length is 1.26 Å. P(1) is bonded in a tetrahedral geometry to one C(1); one C(33,34); one C(9,10); and one O(5,6) atom. The P(1)-O(5,6) bond length is 1.50 Å. There are four inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one C(20), one C(28), and one C(60) atom. In the second N site, N(3,4) is bonded in a trigonal planar geometry to one C(13), one C(23), and one C(25) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Zn(1), one C(20), and one C(30) atom. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one Zn(1), one C(25), and one C(45) atom. There are twenty-three inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(15,16) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(19) atom. The H(7,8)-C(19) bond length is 1.09 Å. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(21,22) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(25) atom. In the seventh H site, H(13,14) is bonded in a single-bond geometry to one C(27) atom. The H(13,14)-C(27) bond length is 1.09 Å. In the eighth H site, H(15,16) is bonded in a single-bond geometry to one C(29) atom. The H(15,16)-C(29) bond length is 1.08 Å. In the ninth H site, H(17,18) is bonded in a single-bond geometry to one C(31) atom. In the tenth H site, H(19,20) is bonded in a single-bond geometry to one C(35) atom. In the eleventh H site, H(21,22) is bonded in a single-bond geometry to one C(37,38) atom. In the twelfth H site, H(23,24) is bonded in a single-bond geometry to one C(39) atom. In the thirteenth H site, H(25) is bonded in a linear geometry to one O(11) and one O(9) atom. The H(25)-O(11) bond length is 1.02 Å. The H(25)-O(9) bond length is 1.55 Å. In the fourteenth H site, H(27,28) is bonded in a single-bond geometry to one C(41) atom. In the fifteenth H site, H(29,30) is bonded in a single-bond geometry to one C(43,44) atom. In the sixteenth H site, H(31,32) is bonded in a single-bond geometry to one C(45) atom. In the seventeenth H site, H(33,34) is bonded in a single-bond geometry to one C(47,48) atom. In the eighteenth H site, H(35) is bonded in a single-bond geometry to one C(51,52) atom. In the nineteenth H site, H(37) is bonded in a single-bond geometry to one C(55,56) atom. In the twentieth H site, H(39,40) is bonded in a single-bond geometry to one C(57,58) atom. In the twenty-first H site, H(42) is bonded in a single-bond geometry to one C(62) atom. In the twenty-second H site, H(43,44) is bonded in a single-bond geometry to one C(63) atom. In the twenty-third H site, H(46) is bonded in a single-bond geometry to one C(66) atom. There are seven inequivalent O sites. In the first O site, O(5,6) is bonded in a single-bond geometry to one P(1) atom. In the second O site, O(7) is bonded in a single-bond geometry to one C(17) atom. In the third O site, O(9) is bonded in a bent 150 degrees geometry to one C(11) and one H(25) atom. In the fourth O site, O(11) is bonded in a water-like geometry to one C(49,50) and one H(25) atom. In the fifth O site, O(13) is bonded in a single-bond geometry to one C(49,50) atom. In the sixth O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(11) atom. In the seventh O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. Linkers: 1 O=[P].O=[P].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[N].[CH][N].[CH][N]/C=N/[Zn][O].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]C(=O)O[Zn].[C][CH]/C=[C]/[N].[C][C]=[CH].[C][N].[C][N].[C][N].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[OH].[OH].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[P].[Zn].[Zn].[c]1cc[c]cc1 ,1 O=[P].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C][N].[CH]=[N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]=[CH].[C]C=[CH].[C][CH].[C][CH].[C][CH].[C][CH][C].[C][CH][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][Zn].[P].[P].[Zn].[Zn].[Zn] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C]N=[CH].[CH]=[C][P].[CH]=[N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/C=C\[C]P([C])[C].[C]=O.[C]=O.[C]=O.[C]=[CH].[C]N=[CH].[C][CH].[C][C]/[C]=C\[C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][Zn].[OH].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[P].[P].[Zn].[Zn] ,1 O=[C]O[Zn].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/N=[C]/C=C\[C][N].[C]/[C]=[C]\[C](/C=C\[C])[P][C].[C]=O.[C]=O.[C][CH].[C][CH][C].[C][C](/C=C\[C][N])N=[CH].[C][N].[C][P].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[P].[P].[Zn].[Zn]. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.88 A, density 1.31 g/cm3, surface area 4886.87 m2/g, accessible volume 0.28 cm3/g