Co2C19NH11O8CH crystallizes in the triclinic P1 space group. The structure consists of two 02329_fluka molecules inside a Co2C19NH11O8 framework. In the Co2C19NH11O8 framework, there are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(15), one O(16), one O(3), one O(5), and one O(7) atom to form distorted CoO6 octahedra that share  a cornercorner with one Co(3)NO3 tetrahedra,  a cornercorner with one Co(4)NO3 tetrahedra, and  an edgeedge with one Co(2)O6 octahedra. The Co(1)-O(14) bond length is 1.92 Å. The Co(1)-O(15) bond length is 2.12 Å. The Co(1)-O(16) bond length is 1.98 Å. The Co(1)-O(3) bond length is 2.31 Å. The Co(1)-O(5) bond length is 1.97 Å. The Co(1)-O(7) bond length is 1.92 Å. In the second Co site, Co(2) is bonded to one O(13), one O(15), one O(16), one O(4), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Co(3)NO3 tetrahedra,  a cornercorner with one Co(4)NO3 tetrahedra, and  an edgeedge with one Co(1)O6 octahedra. The Co(2)-O(13) bond length is 2.01 Å. The Co(2)-O(15) bond length is 2.03 Å. The Co(2)-O(16) bond length is 2.11 Å. The Co(2)-O(4) bond length is 2.16 Å. The Co(2)-O(6) bond length is 2.16 Å. The Co(2)-O(8) bond length is 2.03 Å. In the third Co site, Co(3) is bonded to one N(1), one O(12), one O(15), and one O(9) atom to form corner-sharing CoNO3 tetrahedra. The corner-sharing octahedral tilt angles range from 50-86°. The Co(3)-N(1) bond length is 1.97 Å. The Co(3)-O(12) bond length is 1.95 Å. The Co(3)-O(15) bond length is 1.90 Å. The Co(3)-O(9) bond length is 1.97 Å. In the fourth Co site, Co(4) is bonded to one N(2), one O(10), one O(11), and one O(16) atom to form corner-sharing CoNO3 tetrahedra. The corner-sharing octahedral tilt angles range from 45-87°. The Co(4)-N(2) bond length is 1.98 Å. The Co(4)-O(10) bond length is 1.95 Å. The Co(4)-O(11) bond length is 1.96 Å. The Co(4)-O(16) bond length is 1.93 Å. There are thirty-eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(7), and one O(9) atom. The C(1)-C(3) bond length is 1.49 Å. The C(1)-O(7) bond length is 1.28 Å. The C(1)-O(9) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(10), and one O(8) atom. The C(2)-C(4) bond length is 1.49 Å. The C(2)-O(10) bond length is 1.28 Å. The C(2)-O(8) bond length is 1.27 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(5) atom. The C(3)-C(13) bond length is 1.40 Å. The C(3)-C(5) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(6) atom. The C(4)-C(14) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(1) atom. The C(5)-C(7) bond length is 1.40 Å. The C(5)-H(1) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one H(2) atom. The C(6)-C(8) bond length is 1.40 Å. The C(6)-H(2) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(15), one C(5), and one C(9) atom. The C(7)-C(15) bond length is 1.50 Å. The C(7)-C(9) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(16), and one C(6) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-C(16) bond length is 1.49 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(7) and one H(3) atom. The C(9)-H(3) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one H(4) atom. The C(10)-C(12) bond length is 1.39 Å. The C(10)-H(4) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one O(1) atom. The C(11)-O(1) bond length is 1.40 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one O(2) atom. The C(12)-O(2) bond length is 1.40 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(13)-H(5) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(14)-H(6) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(5) atom. The C(15)-O(3) bond length is 1.27 Å. The C(15)-O(5) bond length is 1.30 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(4), and one O(6) atom. The C(16)-O(4) bond length is 1.28 Å. The C(16)-O(6) bond length is 1.28 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(19) and one O(1) atom. The C(17)-C(19) bond length is 1.39 Å. The C(17)-O(1) bond length is 1.40 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(20) and one O(2) atom. The C(18)-C(20) bond length is 1.39 Å. The C(18)-O(2) bond length is 1.40 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(17), one C(21), and one H(7) atom. The C(19)-C(21) bond length is 1.39 Å. The C(19)-H(7) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(18), one C(22), and one H(8) atom. The C(20)-C(22) bond length is 1.39 Å. The C(20)-H(8) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(19), one C(23), and one H(9) atom. The C(21)-C(23) bond length is 1.40 Å. The C(21)-H(9) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(20), one C(24), and one H(10) atom. The C(22)-C(24) bond length is 1.40 Å. The C(22)-H(10) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(29) atom. The C(23)-C(25) bond length is 1.41 Å. The C(23)-C(29) bond length is 1.49 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(22), one C(26), and one C(30) atom. The C(24)-C(26) bond length is 1.41 Å. The C(24)-C(30) bond length is 1.48 Å. In the twenty-fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(23) and one H(11) atom. The C(25)-H(11) bond length is 1.09 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(24) and one H(12) atom. The C(26)-H(12) bond length is 1.09 Å. In the twenty-seventh C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(11), and one O(13) atom. The C(29)-O(11) bond length is 1.29 Å. The C(29)-O(13) bond length is 1.27 Å. In the twenty-eighth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(12), and one O(14) atom. The C(30)-O(12) bond length is 1.28 Å. The C(30)-O(14) bond length is 1.28 Å. In the twenty-ninth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(33), one N(1), and one H(15) atom. The C(31)-C(33) bond length is 1.38 Å. The C(31)-N(1) bond length is 1.35 Å. The C(31)-H(15) bond length is 1.09 Å. In the thirtieth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(34), one N(2), and one H(16) atom. The C(32)-C(34) bond length is 1.38 Å. The C(32)-N(2) bond length is 1.35 Å. The C(32)-H(16) bond length is 1.09 Å. In the thirty-first C site, C(33) is bonded in a distorted single-bond geometry to one C(31), one C(35), and one H(17) atom. The C(33)-C(35) bond length is 1.40 Å. The C(33)-H(17) bond length is 1.08 Å. In the thirty-second C site, C(34) is bonded in a distorted single-bond geometry to one C(32), one C(36), and one H(18) atom. The C(34)-C(36) bond length is 1.40 Å. The C(34)-H(18) bond length is 1.09 Å. In the thirty-third C site, C(35) is bonded in a trigonal planar geometry to one C(33), one C(36), and one C(37) atom. The C(35)-C(36) bond length is 1.47 Å. The C(35)-C(37) bond length is 1.41 Å. In the thirty-fourth C site, C(36) is bonded in a trigonal planar geometry to one C(34), one C(35), and one C(38) atom. The C(36)-C(38) bond length is 1.41 Å. In the thirty-fifth C site, C(37) is bonded in a distorted single-bond geometry to one C(35), one C(39), and one H(19) atom. The C(37)-C(39) bond length is 1.39 Å. The C(37)-H(19) bond length is 1.09 Å. In the thirty-sixth C site, C(38) is bonded in a distorted single-bond geometry to one C(36), one C(40), and one H(20) atom. The C(38)-C(40) bond length is 1.39 Å. The C(38)-H(20) bond length is 1.09 Å. In the thirty-seventh C site, C(39) is bonded in a distorted trigonal planar geometry to one C(37), one N(1), and one H(21) atom. The C(39)-N(1) bond length is 1.35 Å. The C(39)-H(21) bond length is 1.09 Å. In the thirty-eighth C site, C(40) is bonded in a distorted trigonal planar geometry to one C(38), one N(2), and one H(22) atom. The C(40)-N(2) bond length is 1.35 Å. The C(40)-H(22) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(3), one C(31), and one C(39) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(4), one C(32), and one C(40) atom. There are twenty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(26) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(32) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(33) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(34) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(37) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(38) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(39) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(40) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one O(15) atom. The H(23)-O(15) bond length is 0.98 Å. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one O(16) atom. The H(24)-O(16) bond length is 0.99 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(11) and one C(17) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(12) and one C(18) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Co(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Co(2) and one C(16) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Co(1) and one C(15) atom. In the sixth O site, O(6) is bonded in an L-shaped geometry to one Co(2) and one C(16) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Co(3) and one C(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Co(4) and one C(2) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Co(4) and one C(29) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Co(3) and one C(30) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(29) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(30) atom. In the fifteenth O site, O(15) is bonded in a distorted tetrahedral geometry to one Co(1), one Co(2), one Co(3), and one H(23) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one Co(1), one Co(2), one Co(4), and one H(24) atom. Linkers: 2 [O]C(=O)c1ccc(Oc2cc(C([O])=O)cc(C([O])=O)c2)cc1 ,1 c1cc(-c2ccncc2)ccn1. Metal clusters: 1 O[Co]1O[C]O[Co]2(O[C]O1)O[C]O2.O[Co]1O[C]O[Co]2(O[C]O1)O[C]O2. RCSR code: kgd. The MOF has largest included sphere 2.42 A, density 1.90 g/cm3, surface area 3560.95 m2/g, accessible volume 0.07 cm3/g