AgC8H11S(NO)2 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a 5-coordinate geometry to one H(4), two equivalent S(1), one O(1), and one O(2) atom. The Ag(1)-H(4) bond length is 2.46 Å. There is one shorter (2.47 Å) and one longer (2.51 Å) Ag(1)-S(1) bond length. The Ag(1)-O(1) bond length is 2.42 Å. The Ag(1)-O(2) bond length is 2.47 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-S(1) bond length is 1.73 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one O(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(2) bond length is 1.44 Å. The C(2)-O(1) bond length is 1.26 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one O(2) atom. The C(4)-N(1) bond length is 1.43 Å. The C(4)-O(2) bond length is 1.26 Å. In the fifth C site, C(5) is bonded in a 4-coordinate geometry to one C(8), one N(1), one H(2), and one H(3) atom. The C(5)-C(8) bond length is 1.52 Å. The C(5)-N(1) bond length is 1.48 Å. The C(5)-H(2) bond length is 1.09 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a 4-coordinate geometry to one C(7), one N(2), one H(4), and one H(5) atom. The C(6)-C(7) bond length is 1.52 Å. The C(6)-N(2) bond length is 1.48 Å. The C(6)-H(4) bond length is 1.10 Å. The C(6)-H(5) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one H(6), one H(7), and one H(8) atom. The C(7)-H(6) bond length is 1.10 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.10 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one H(10), one H(11), and one H(9) atom. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(11) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(6) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one Ag(1) and one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(8) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one C(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one C(4) atom. Linkers: 4 CCN1C(=O)[CH]C(=O)N(CC)C1=S. Metal clusters: 4 [Ag]. RCSR code: sra. The MOF has largest included sphere 1.65 A, density 2.13 g/cm3, surface area 3455.79 m2/g, accessible volume 0.10 cm3/g