Zn4C47NH43O23(CH3)2(C5H6O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two C5H6O2 clusters, and two Zn4C47NH43O23 clusters. In each C5H6O2 cluster, there are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(16) and one O(17) atom. The C(1)-C(16) bond length is 1.41 Å. The C(1)-O(17) bond length is 1.37 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(21) and one O(21) atom. The C(3)-C(21) bond length is 1.40 Å. The C(3)-O(21) bond length is 1.37 Å. In the third C site, C(16) is bonded in a trigonal planar geometry to one C(1), one C(21), and one C(29) atom. The C(16)-C(21) bond length is 1.48 Å. The C(16)-C(29) bond length is 1.41 Å. In the fourth C site, C(21) is bonded in a trigonal planar geometry to one C(16), one C(3), and one C(49) atom. The C(21)-C(49) bond length is 1.41 Å. In the fifth C site, C(29) is bonded in a distorted single-bond geometry to one C(16) and one O(15) atom. The C(29)-O(15) bond length is 1.37 Å. In the sixth C site, C(31) is bonded in a tetrahedral geometry to one H(14), one H(15), one H(16), and one O(17) atom. The C(31)-H(14) bond length is 1.10 Å. The C(31)-H(15) bond length is 1.10 Å. The C(31)-H(16) bond length is 1.10 Å. The C(31)-O(17) bond length is 1.43 Å. In the seventh C site, C(33) is bonded in a tetrahedral geometry to one H(17), one H(18), one H(19), and one O(15) atom. The C(33)-H(17) bond length is 1.09 Å. The C(33)-H(18) bond length is 1.10 Å. The C(33)-H(19) bond length is 1.10 Å. The C(33)-O(15) bond length is 1.44 Å. In the eighth C site, C(37) is bonded in a tetrahedral geometry to one H(29); two equivalent H(30,31); and one O(21) atom. The C(37)-H(29) bond length is 1.10 Å. Both C(37)-H(30,31) bond lengths are 1.10 Å. The C(37)-O(21) bond length is 1.42 Å. In the ninth C site, C(49) is bonded in a distorted single-bond geometry to one C(21) and one O(26) atom. The C(49)-O(26) bond length is 1.37 Å. In the tenth C site, C(54) is bonded in a tetrahedral geometry to one H(46), one H(47), one H(48), and one O(26) atom. The C(54)-H(46) bond length is 1.09 Å. The C(54)-H(47) bond length is 1.10 Å. The C(54)-H(48) bond length is 1.10 Å. The C(54)-O(26) bond length is 1.43 Å. There are eleven inequivalent H sites. In the first H site, H(14) is bonded in a single-bond geometry to one C(31) atom. In the second H site, H(15) is bonded in a single-bond geometry to one C(31) atom. In the third H site, H(16) is bonded in a single-bond geometry to one C(31) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(33) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one C(33) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(33) atom. In the seventh H site, H(29) is bonded in a single-bond geometry to one C(37) atom. In the eighth H site, H(30,31) is bonded in a single-bond geometry to one C(37) atom. In the ninth H site, H(46) is bonded in a single-bond geometry to one C(54) atom. In the tenth H site, H(47) is bonded in a single-bond geometry to one C(54) atom. In the eleventh H site, H(48) is bonded in a single-bond geometry to one C(54) atom. There are four inequivalent O sites. In the first O site, O(15) is bonded in a bent 120 degrees geometry to one C(29) and one C(33) atom. In the second O site, O(17) is bonded in a bent 120 degrees geometry to one C(1) and one C(31) atom. In the third O site, O(21) is bonded in a bent 120 degrees geometry to one C(3) and one C(37) atom. In the fourth O site, O(26) is bonded in a bent 120 degrees geometry to one C(49) and one C(54) atom. In each Zn4C47NH43O23 cluster, there are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(10), one O(13), and one O(14) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.94 Å. The Zn(1)-O(10) bond length is 1.95 Å. The Zn(1)-O(13) bond length is 1.98 Å. The Zn(1)-O(14) bond length is 1.98 Å. In the second Zn site, Zn(2) is bonded in a 6-coordinate geometry to one O(1), one O(16), one O(22), one O(27), one O(4), and one O(6) atom. The Zn(2)-O(1) bond length is 1.98 Å. The Zn(2)-O(16) bond length is 2.29 Å. The Zn(2)-O(22) bond length is 2.14 Å. The Zn(2)-O(27) bond length is 2.32 Å. The Zn(2)-O(4) bond length is 2.02 Å. The Zn(2)-O(6) bond length is 2.12 Å. In the third Zn site, Zn(3) is bonded to one O(1), one O(2), one O(3), and one O(7) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(1) bond length is 1.96 Å. The Zn(3)-O(2) bond length is 1.96 Å. The Zn(3)-O(3) bond length is 1.98 Å. The Zn(3)-O(7) bond length is 1.98 Å. In the fourth Zn site, Zn(4) is bonded to one O(1), one O(11), one O(12), and one O(5) atom to form corner-sharing ZnO4 tetrahedra. The Zn(4)-O(1) bond length is 1.94 Å. The Zn(4)-O(11) bond length is 1.97 Å. The Zn(4)-O(12) bond length is 1.97 Å. The Zn(4)-O(5) bond length is 1.96 Å. There are forty-seven inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(12) and one H(1) atom. The C(2)-C(12) bond length is 1.40 Å. The C(2)-H(1) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(13), and one O(7) atom. The C(4)-C(12) bond length is 1.49 Å. The C(4)-O(13) bond length is 1.28 Å. The C(4)-O(7) bond length is 1.28 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(2), and one O(6) atom. The C(5)-C(11) bond length is 1.49 Å. The C(5)-O(2) bond length is 1.28 Å. The C(5)-O(6) bond length is 1.27 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(26), one C(43), and one O(20) atom. The C(6)-C(26) bond length is 1.41 Å. The C(6)-C(43) bond length is 1.40 Å. The C(6)-O(20) bond length is 1.37 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(19) and one O(18) atom. The C(7)-C(19) bond length is 1.41 Å. The C(7)-O(18) bond length is 1.36 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(12), one C(28), and one H(2) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(28) bond length is 1.40 Å. The C(8)-H(2) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(24) and one O(24) atom. The C(9)-C(24) bond length is 1.41 Å. The C(9)-O(24) bond length is 1.37 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(19), one C(28), and one C(32) atom. The C(10)-C(19) bond length is 1.48 Å. The C(10)-C(28) bond length is 1.40 Å. The C(10)-C(32) bond length is 1.41 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(13), one C(30), and one C(5) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-C(30) bond length is 1.40 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(11) and one H(3) atom. The C(13)-H(3) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(23) atom. The C(14)-C(17) bond length is 1.40 Å. The C(14)-C(18) bond length is 1.40 Å. The C(14)-C(23) bond length is 1.49 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(24) and one O(9) atom. The C(15)-C(24) bond length is 1.41 Å. The C(15)-O(9) bond length is 1.37 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(14) and one H(4) atom. The C(17)-H(4) bond length is 1.09 Å. In the fifteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(14) and one H(5) atom. The C(18)-H(5) bond length is 1.09 Å. In the sixteenth C site, C(19) is bonded in a trigonal planar geometry to one C(10), one C(20), and one C(7) atom. The C(19)-C(20) bond length is 1.40 Å. In the seventeenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one O(19) atom. The C(20)-O(19) bond length is 1.37 Å. In the eighteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(40) and one H(6) atom. The C(22)-C(40) bond length is 1.40 Å. The C(22)-H(6) bond length is 1.09 Å. In the nineteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(10), and one O(4) atom. The C(23)-O(10) bond length is 1.28 Å. The C(23)-O(4) bond length is 1.27 Å. In the twentieth C site, C(24) is bonded in a trigonal planar geometry to one C(15), one C(26), and one C(9) atom. The C(24)-C(26) bond length is 1.48 Å. In the twenty-first C site, C(25) is bonded in a tetrahedral geometry to one H(7), one H(8), one H(9), and one O(24) atom. The C(25)-H(7) bond length is 1.10 Å. The C(25)-H(8) bond length is 1.10 Å. The C(25)-H(9) bond length is 1.10 Å. The C(25)-O(24) bond length is 1.43 Å. In the twenty-second C site, C(26) is bonded in a trigonal planar geometry to one C(24), one C(47), and one C(6) atom. The C(26)-C(47) bond length is 1.41 Å. In the twenty-third C site, C(27) is bonded in a tetrahedral geometry to one H(10), one H(11), one H(12), and one O(18) atom. The C(27)-H(10) bond length is 1.09 Å. The C(27)-H(11) bond length is 1.10 Å. The C(27)-H(12) bond length is 1.10 Å. The C(27)-O(18) bond length is 1.43 Å. In the twenty-fourth C site, C(28) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one O(23) atom. The C(28)-O(23) bond length is 1.37 Å. In the twenty-fifth C site, C(30) is bonded in a distorted single-bond geometry to one C(11) and one H(13) atom. The C(30)-H(13) bond length is 1.09 Å. In the twenty-sixth C site, C(32) is bonded in a distorted single-bond geometry to one C(10) and one O(8) atom. The C(32)-O(8) bond length is 1.36 Å. In the twenty-seventh C site, C(34) is bonded in a tetrahedral geometry to one H(20), one H(21), one H(22), and one O(8) atom. The C(34)-H(20) bond length is 1.09 Å. The C(34)-H(21) bond length is 1.10 Å. The C(34)-H(22) bond length is 1.10 Å. The C(34)-O(8) bond length is 1.43 Å. In the twenty-eighth C site, C(35) is bonded in a tetrahedral geometry to one H(23); two equivalent H(24,25); and one O(19) atom. The C(35)-H(23) bond length is 1.10 Å. Both C(35)-H(24,25) bond lengths are 1.10 Å. The C(35)-O(19) bond length is 1.43 Å. In the twenty-ninth C site, C(36) is bonded in a tetrahedral geometry to one H(26), one H(27), one H(28), and one O(20) atom. The C(36)-H(26) bond length is 1.09 Å. The C(36)-H(27) bond length is 1.10 Å. The C(36)-H(28) bond length is 1.10 Å. The C(36)-O(20) bond length is 1.43 Å. In the thirtieth C site, C(38) is bonded in a tetrahedral geometry to one H(32), one H(33), one H(34), and one O(9) atom. The C(38)-H(32) bond length is 1.09 Å. The C(38)-H(33) bond length is 1.10 Å. The C(38)-H(34) bond length is 1.10 Å. The C(38)-O(9) bond length is 1.43 Å. In the thirty-first C site, C(39) is bonded in a tetrahedral geometry to one H(35), one H(36), one H(37), and one O(23) atom. The C(39)-H(35) bond length is 1.10 Å. The C(39)-H(36) bond length is 1.10 Å. The C(39)-H(37) bond length is 1.10 Å. The C(39)-O(23) bond length is 1.42 Å. In the thirty-second C site, C(40) is bonded in a trigonal planar geometry to one C(22), one C(41), and one C(42) atom. The C(40)-C(41) bond length is 1.49 Å. The C(40)-C(42) bond length is 1.40 Å. In the thirty-third C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(40), one O(12), and one O(16) atom. The C(41)-O(12) bond length is 1.29 Å. The C(41)-O(16) bond length is 1.27 Å. In the thirty-fourth C site, C(42) is bonded in a distorted single-bond geometry to one C(40) and one H(38) atom. The C(42)-H(38) bond length is 1.09 Å. In the thirty-fifth C site, C(43) is bonded in a distorted trigonal planar geometry to one C(44), one C(6), and one H(39) atom. The C(43)-C(44) bond length is 1.40 Å. The C(43)-H(39) bond length is 1.09 Å. In the thirty-sixth C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(46) atom. The C(44)-C(45) bond length is 1.49 Å. The C(44)-C(46) bond length is 1.40 Å. In the thirty-seventh C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(44), one O(11), and one O(3) atom. The C(45)-O(11) bond length is 1.28 Å. The C(45)-O(3) bond length is 1.28 Å. In the thirty-eighth C site, C(46) is bonded in a distorted trigonal planar geometry to one C(44), one C(47), and one H(40) atom. The C(46)-C(47) bond length is 1.39 Å. The C(46)-H(40) bond length is 1.09 Å. In the thirty-ninth C site, C(47) is bonded in a distorted single-bond geometry to one C(26), one C(46), and one O(25) atom. The C(47)-O(25) bond length is 1.37 Å. In the fortieth C site, C(48) is bonded in a tetrahedral geometry to one H(41), one H(42), one H(43), and one O(25) atom. The C(48)-H(41) bond length is 1.10 Å. The C(48)-H(42) bond length is 1.10 Å. The C(48)-H(43) bond length is 1.10 Å. The C(48)-O(25) bond length is 1.42 Å. In the forty-first C site, C(50) is bonded in a distorted single-bond geometry to one C(52) and one H(44) atom. The C(50)-C(52) bond length is 1.40 Å. The C(50)-H(44) bond length is 1.09 Å. In the forty-second C site, C(51) is bonded in a distorted single-bond geometry to one C(52) and one H(45) atom. The C(51)-C(52) bond length is 1.40 Å. The C(51)-H(45) bond length is 1.09 Å. In the forty-third C site, C(52) is bonded in a trigonal planar geometry to one C(50), one C(51), and one C(53) atom. The C(52)-C(53) bond length is 1.49 Å. In the forty-fourth C site, C(53) is bonded in a distorted bent 120 degrees geometry to one C(52), one O(14), and one O(5) atom. The C(53)-O(14) bond length is 1.28 Å. The C(53)-O(5) bond length is 1.28 Å. In the forty-fifth C site, C(55) is bonded in a trigonal planar geometry to one N(1), one H(51), and one O(22) atom. The C(55)-N(1) bond length is 1.34 Å. The C(55)-H(51) bond length is 1.10 Å. The C(55)-O(22) bond length is 1.25 Å. In the forty-sixth C site, C(56) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(52), and one H(53) atom. The C(56)-N(1) bond length is 1.47 Å. The C(56)-H(52) bond length is 1.10 Å. The C(56)-H(53) bond length is 1.10 Å. In the forty-seventh C site, C(57) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(54), and one H(55) atom. The C(57)-N(1) bond length is 1.46 Å. The C(57)-H(54) bond length is 1.10 Å. The C(57)-H(55) bond length is 1.10 Å. N(1) is bonded in a trigonal planar geometry to one C(55), one C(56), and one C(57) atom. There are forty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(22) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(25) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(27) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(27) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(27) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(30) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(34) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(34) atom. In the sixteenth H site, H(22) is bonded in a single-bond geometry to one C(34) atom. In the seventeenth H site, H(23) is bonded in a single-bond geometry to one C(35) atom. In the eighteenth H site, H(24,25) is bonded in a single-bond geometry to one C(35) atom. In the nineteenth H site, H(26) is bonded in a single-bond geometry to one C(36) atom. In the twentieth H site, H(27) is bonded in a single-bond geometry to one C(36) atom. In the twenty-first H site, H(28) is bonded in a single-bond geometry to one C(36) atom. In the twenty-second H site, H(32) is bonded in a single-bond geometry to one C(38) atom. In the twenty-third H site, H(33) is bonded in a single-bond geometry to one C(38) atom. In the twenty-fourth H site, H(34) is bonded in a single-bond geometry to one C(38) atom. In the twenty-fifth H site, H(35) is bonded in a single-bond geometry to one C(39) atom. In the twenty-sixth H site, H(36) is bonded in a single-bond geometry to one C(39) atom. In the twenty-seventh H site, H(37) is bonded in a single-bond geometry to one C(39) atom. In the twenty-eighth H site, H(38) is bonded in a single-bond geometry to one C(42) atom. In the twenty-ninth H site, H(39) is bonded in a single-bond geometry to one C(43) atom. In the thirtieth H site, H(40) is bonded in a single-bond geometry to one C(46) atom. In the thirty-first H site, H(41) is bonded in a single-bond geometry to one C(48) atom. In the thirty-second H site, H(42) is bonded in a single-bond geometry to one C(48) atom. In the thirty-third H site, H(43) is bonded in a single-bond geometry to one C(48) atom. In the thirty-fourth H site, H(44) is bonded in a single-bond geometry to one C(50) atom. In the thirty-fifth H site, H(45) is bonded in a single-bond geometry to one C(51) atom. In the thirty-sixth H site, H(49) is bonded in a single-bond geometry to one O(27) atom. The H(49)-O(27) bond length is 0.99 Å. In the thirty-seventh H site, H(50) is bonded in a single-bond geometry to one O(27) atom. The H(50)-O(27) bond length is 0.98 Å. In the thirty-eighth H site, H(51) is bonded in a single-bond geometry to one C(55) atom. In the thirty-ninth H site, H(52) is bonded in a single-bond geometry to one C(56) atom. In the fortieth H site, H(53) is bonded in a single-bond geometry to one C(56) atom. In the forty-first H site, H(54) is bonded in a single-bond geometry to one C(57) atom. In the forty-second H site, H(55) is bonded in a single-bond geometry to one C(57) atom. There are twenty-three inequivalent O sites. In the first O site, O(1) is bonded in a tetrahedral geometry to one Zn(1), one Zn(2), one Zn(3), and one Zn(4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(5) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(45) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(23) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(53) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(5) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(4) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one C(32) and one C(34) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one C(15) and one C(38) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(23) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(45) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(41) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(53) atom. In the fifteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(41) atom. In the sixteenth O site, O(18) is bonded in a bent 120 degrees geometry to one C(27) and one C(7) atom. In the seventeenth O site, O(19) is bonded in a bent 120 degrees geometry to one C(20) and one C(35) atom. In the eighteenth O site, O(20) is bonded in a bent 120 degrees geometry to one C(36) and one C(6) atom. In the nineteenth O site, O(22) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(55) atom. In the twentieth O site, O(23) is bonded in a bent 120 degrees geometry to one C(28) and one C(39) atom. In the twenty-first O site, O(24) is bonded in a bent 120 degrees geometry to one C(25) and one C(9) atom. In the twenty-second O site, O(25) is bonded in a bent 120 degrees geometry to one C(47) and one C(48) atom. In the twenty-third O site, O(27) is bonded in a water-like geometry to one Zn(2), one H(49), and one H(50) atom. Linkers: 6 COc1cc(C([O])=O)cc(OC)c1-c1c(OC)cc(C([O])=O)cc1OC. Metal clusters: 8 [Zn]. RCSR code: bor. The MOF has largest included sphere 5.81 A, density 1.01 g/cm3, surface area 4974.64 m2/g, accessible volume 0.50 cm3/g