HgC8H8(N2S)2 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four HgC8H8(N2S)2 clusters. Hg(1) is bonded in a 3-coordinate geometry to one N(3), one S(1), and one S(2) atom. The Hg(1)-N(3) bond length is 2.72 Å. The Hg(1)-S(1) bond length is 2.46 Å. The Hg(1)-S(2) bond length is 2.46 Å. There are six inequivalent C sites. In the first C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(2) atom. The C(2)-N(2) bond length is 1.18 Å. The C(2)-S(2) bond length is 1.66 Å. In the second C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.65 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5,6); one N(3); and one H(1,2) atom. The C(4)-C(5,6) bond length is 1.40 Å. The C(4)-N(3) bond length is 1.34 Å. The C(4)-H(1,2) bond length is 1.09 Å. In the fourth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(5,6); one N(3); and one H(1,2) atom. The C(3)-C(5,6) bond length is 1.40 Å. The C(3)-N(3) bond length is 1.34 Å. The C(3)-H(1,2) bond length is 1.09 Å. In the fifth C site, C(5,6) is bonded in a distorted trigonal planar geometry to one C(3); one C(7,8); and one N(4) atom. The C(5,6)-C(7,8) bond length is 1.49 Å. The C(5,6)-N(4) bond length is 1.35 Å. In the sixth C site, C(7,8) is bonded in a distorted trigonal non-coplanar geometry to one C(5,6); one H(3,4); one H(5,6); and one H(7,8) atom. The C(7,8)-H(3,4) bond length is 1.10 Å. The C(7,8)-H(5,6) bond length is 1.10 Å. The C(7,8)-H(7,8) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one C(2) atom. In the second N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one Hg(1), one C(3), and one C(4) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to two equivalent C(5,6) atoms. There are four inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(7,8) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(7,8) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(7,8) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a water-like geometry to one Hg(1) and one C(2) atom. In the second S site, S(1) is bonded in a water-like geometry to one Hg(1) and one C(1) atom. Linkers: 1 Cc1cncc(C)n1. Metal clusters: . The MOF has largest included sphere 1.58 A, density 2.50 g/cm3, surface area 3425.63 m2/g, accessible volume 0.05 cm3/g