Cd3C56H38(N3O4)4(CH)4 crystallizes in the triclinic P1 space group. The structure consists of four 02329_fluka molecules inside a Cd3C56H38(N3O4)4 framework. In the Cd3C56H38(N3O4)4 framework, there are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted pentagonal bipyramidal geometry to one N(1), one N(12), one O(1), one O(15), one O(3), one O(6), and one O(8) atom. The Cd(1)-N(1) bond length is 2.39 Å. The Cd(1)-N(12) bond length is 2.37 Å. The Cd(1)-O(1) bond length is 2.35 Å. The Cd(1)-O(15) bond length is 2.41 Å. The Cd(1)-O(3) bond length is 2.57 Å. The Cd(1)-O(6) bond length is 2.32 Å. The Cd(1)-O(8) bond length is 2.66 Å. In the second Cd site, Cd(2) is bonded in a distorted pentagonal bipyramidal geometry to one N(11), one N(2), one O(16), one O(2), one O(4), one O(5), and one O(7) atom. The Cd(2)-N(11) bond length is 2.37 Å. The Cd(2)-N(2) bond length is 2.39 Å. The Cd(2)-O(16) bond length is 2.42 Å. The Cd(2)-O(2) bond length is 2.35 Å. The Cd(2)-O(4) bond length is 2.57 Å. The Cd(2)-O(5) bond length is 2.32 Å. The Cd(2)-O(7) bond length is 2.66 Å. In the third Cd site, Cd(3) is bonded in a distorted octahedral geometry to one N(7), one N(8), one O(11), one O(12), one O(13), and one O(14) atom. The Cd(3)-N(7) bond length is 2.30 Å. The Cd(3)-N(8) bond length is 2.30 Å. The Cd(3)-O(11) bond length is 2.41 Å. The Cd(3)-O(12) bond length is 2.41 Å. The Cd(3)-O(13) bond length is 2.35 Å. The Cd(3)-O(14) bond length is 2.34 Å. There are fifty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(3) atom. The C(1)-C(5) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(2), and one O(4) atom. The C(2)-C(6) bond length is 1.50 Å. The C(2)-O(2) bond length is 1.28 Å. The C(2)-O(4) bond length is 1.27 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(5), and one O(7) atom. The C(3)-C(7) bond length is 1.51 Å. The C(3)-O(5) bond length is 1.29 Å. The C(3)-O(7) bond length is 1.26 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(6), and one O(8) atom. The C(4)-C(8) bond length is 1.51 Å. The C(4)-O(6) bond length is 1.29 Å. The C(4)-O(8) bond length is 1.26 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(15), and one C(7) atom. The C(5)-C(15) bond length is 1.40 Å. The C(5)-C(7) bond length is 1.41 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(16), one C(2), and one C(8) atom. The C(6)-C(16) bond length is 1.40 Å. The C(6)-C(8) bond length is 1.41 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(7)-C(9) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(6) atom. The C(8)-C(10) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(7) and one O(9) atom. The C(9)-O(9) bond length is 1.39 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one O(10) atom. The C(10)-O(10) bond length is 1.39 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(5) and one H(5,6) atom. The C(15)-H(5,6) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(6) and one H(5,6) atom. The C(16)-H(5,6) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(27) and one O(9) atom. The C(17)-C(27) bond length is 1.40 Å. The C(17)-O(9) bond length is 1.38 Å. In the fourteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(28) and one O(10) atom. The C(18)-C(28) bond length is 1.40 Å. The C(18)-O(10) bond length is 1.38 Å. In the fifteenth C site, C(19,20) is bonded in a distorted single-bond geometry to one C(21,22) and one H(7,8) atom. The C(19,20)-C(21,22) bond length is 1.39 Å. The C(19,20)-H(7,8) bond length is 1.09 Å. In the sixteenth C site, C(21,22) is bonded in a distorted trigonal planar geometry to one C(19,20); one C(23); and one H(9,10) atom. The C(21,22)-C(23) bond length is 1.40 Å. The C(21,22)-H(9,10) bond length is 1.09 Å. In the seventeenth C site, C(23) is bonded in a trigonal planar geometry to one C(21,22); one C(25); and one C(29) atom. The C(23)-C(25) bond length is 1.40 Å. The C(23)-C(29) bond length is 1.49 Å. In the eighteenth C site, C(24) is bonded in a trigonal planar geometry to one C(21,22); one C(26); and one C(30) atom. The C(24)-C(21,22) bond length is 1.40 Å. The C(24)-C(26) bond length is 1.40 Å. The C(24)-C(30) bond length is 1.49 Å. In the nineteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(23); one C(27); and one H(11,12) atom. The C(25)-C(27) bond length is 1.39 Å. The C(25)-H(11,12) bond length is 1.09 Å. In the twentieth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(24); one C(28); and one H(11,12) atom. The C(26)-C(28) bond length is 1.39 Å. The C(26)-H(11,12) bond length is 1.09 Å. In the twenty-first C site, C(27) is bonded in a distorted trigonal planar geometry to one C(17), one C(25), and one H(13) atom. The C(27)-H(13) bond length is 1.09 Å. In the twenty-second C site, C(28) is bonded in a distorted trigonal planar geometry to one C(18), one C(26), and one H(14) atom. The C(28)-H(14) bond length is 1.09 Å. In the twenty-third C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(11), and one O(13) atom. The C(29)-O(11) bond length is 1.28 Å. The C(29)-O(13) bond length is 1.28 Å. In the twenty-fourth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(12), and one O(14) atom. The C(30)-O(12) bond length is 1.28 Å. The C(30)-O(14) bond length is 1.28 Å. In the twenty-fifth C site, C(31) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(15) atom. The C(31)-N(1) bond length is 1.32 Å. The C(31)-N(3) bond length is 1.37 Å. The C(31)-H(15) bond length is 1.08 Å. In the twenty-sixth C site, C(32) is bonded in a trigonal planar geometry to one N(2), one N(4), and one H(16) atom. The C(32)-N(2) bond length is 1.32 Å. The C(32)-N(4) bond length is 1.37 Å. The C(32)-H(16) bond length is 1.08 Å. In the twenty-seventh C site, C(33) is bonded in a distorted trigonal planar geometry to one C(35), one N(1), and one H(17) atom. The C(33)-C(35) bond length is 1.37 Å. The C(33)-N(1) bond length is 1.39 Å. The C(33)-H(17) bond length is 1.09 Å. In the twenty-eighth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(36), one N(2), and one H(18) atom. The C(34)-C(36) bond length is 1.37 Å. The C(34)-N(2) bond length is 1.39 Å. The C(34)-H(18) bond length is 1.09 Å. In the twenty-ninth C site, C(35) is bonded in a 3-coordinate geometry to one C(33); one N(3); and one H(19,20) atom. The C(35)-N(3) bond length is 1.39 Å. The C(35)-H(19,20) bond length is 1.09 Å. In the thirtieth C site, C(36) is bonded in a 3-coordinate geometry to one C(34); one N(4); and one H(19,20) atom. The C(36)-N(4) bond length is 1.39 Å. The C(36)-H(19,20) bond length is 1.09 Å. In the thirty-first C site, C(37) is bonded in a distorted trigonal planar geometry to one C(39), one C(47), and one N(3) atom. The C(37)-C(39) bond length is 1.40 Å. The C(37)-C(47) bond length is 1.40 Å. The C(37)-N(3) bond length is 1.41 Å. In the thirty-second C site, C(38) is bonded in a distorted trigonal planar geometry to one C(40), one C(48), and one N(4) atom. The C(38)-C(40) bond length is 1.40 Å. The C(38)-C(48) bond length is 1.40 Å. The C(38)-N(4) bond length is 1.41 Å. In the thirty-third C site, C(39) is bonded in a distorted single-bond geometry to one C(37), one C(41), and one H(21) atom. The C(39)-C(41) bond length is 1.40 Å. The C(39)-H(21) bond length is 1.09 Å. In the thirty-fourth C site, C(40) is bonded in a distorted single-bond geometry to one C(38), one C(42), and one H(22) atom. The C(40)-C(42) bond length is 1.40 Å. The C(40)-H(22) bond length is 1.09 Å. In the thirty-fifth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(39), one C(43), and one N(9) atom. The C(41)-C(43) bond length is 1.39 Å. The C(41)-N(9) bond length is 1.42 Å. In the thirty-sixth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(40), one C(44), and one N(10) atom. The C(42)-C(44) bond length is 1.39 Å. The C(42)-N(10) bond length is 1.42 Å. In the thirty-seventh C site, C(43) is bonded in a distorted single-bond geometry to one C(41), one C(45), and one H(23) atom. The C(43)-C(45) bond length is 1.40 Å. The C(43)-H(23) bond length is 1.09 Å. In the thirty-eighth C site, C(44) is bonded in a distorted single-bond geometry to one C(42), one C(46), and one H(24) atom. The C(44)-C(46) bond length is 1.40 Å. The C(44)-H(24) bond length is 1.09 Å. In the thirty-ninth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(43), one C(47), and one N(5) atom. The C(45)-C(47) bond length is 1.40 Å. The C(45)-N(5) bond length is 1.41 Å. In the fortieth C site, C(46) is bonded in a distorted trigonal planar geometry to one C(44), one C(48), and one N(6) atom. The C(46)-C(48) bond length is 1.40 Å. The C(46)-N(6) bond length is 1.41 Å. In the forty-first C site, C(47) is bonded in a distorted single-bond geometry to one C(37), one C(45), and one H(25) atom. The C(47)-H(25) bond length is 1.09 Å. In the forty-second C site, C(48) is bonded in a distorted single-bond geometry to one C(38), one C(46), and one H(26) atom. The C(48)-H(26) bond length is 1.09 Å. In the forty-third C site, C(49) is bonded in a trigonal planar geometry to one N(5); one N(7); and one H(27,28) atom. The C(49)-N(5) bond length is 1.37 Å. The C(49)-N(7) bond length is 1.32 Å. The C(49)-H(27,28) bond length is 1.08 Å. In the forty-fourth C site, C(50) is bonded in a trigonal planar geometry to one N(6); one N(8); and one H(27,28) atom. The C(50)-N(6) bond length is 1.37 Å. The C(50)-N(8) bond length is 1.32 Å. The C(50)-H(27,28) bond length is 1.08 Å. In the forty-fifth C site, C(51) is bonded in a distorted trigonal planar geometry to one C(53); one N(7); and one H(29,30) atom. The C(51)-C(53) bond length is 1.37 Å. The C(51)-N(7) bond length is 1.38 Å. The C(51)-H(29,30) bond length is 1.08 Å. In the forty-sixth C site, C(52) is bonded in a distorted trigonal planar geometry to one C(54); one N(8); and one H(29,30) atom. The C(52)-C(54) bond length is 1.37 Å. The C(52)-N(8) bond length is 1.38 Å. The C(52)-H(29,30) bond length is 1.08 Å. In the forty-seventh C site, C(53) is bonded in a distorted bent 120 degrees geometry to one C(51); one N(5); and one H(31,32) atom. The C(53)-N(5) bond length is 1.39 Å. The C(53)-H(31,32) bond length is 1.08 Å. In the forty-eighth C site, C(54) is bonded in a distorted bent 120 degrees geometry to one C(52); one N(6); and one H(31,32) atom. The C(54)-N(6) bond length is 1.39 Å. The C(54)-H(31,32) bond length is 1.08 Å. In the forty-ninth C site, C(55) is bonded in a trigonal planar geometry to one N(11), one N(9), and one H(33) atom. The C(55)-N(11) bond length is 1.32 Å. The C(55)-N(9) bond length is 1.37 Å. The C(55)-H(33) bond length is 1.08 Å. In the fiftieth C site, C(56) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(34) atom. The C(56)-N(10) bond length is 1.37 Å. The C(56)-N(12) bond length is 1.32 Å. The C(56)-H(34) bond length is 1.08 Å. In the fifty-first C site, C(57) is bonded in a distorted bent 120 degrees geometry to one C(59); one N(9); and one H(35,36) atom. The C(57)-C(59) bond length is 1.37 Å. The C(57)-N(9) bond length is 1.39 Å. The C(57)-H(35,36) bond length is 1.08 Å. In the fifty-second C site, C(58) is bonded in a distorted bent 120 degrees geometry to one C(60); one N(10); and one H(35,36) atom. The C(58)-C(60) bond length is 1.37 Å. The C(58)-N(10) bond length is 1.39 Å. The C(58)-H(35,36) bond length is 1.08 Å. In the fifty-third C site, C(59) is bonded in a distorted bent 120 degrees geometry to one C(57), one N(11), and one H(37) atom. The C(59)-N(11) bond length is 1.38 Å. The C(59)-H(37) bond length is 1.08 Å. In the fifty-fourth C site, C(60) is bonded in a distorted bent 120 degrees geometry to one C(58), one N(12), and one H(38) atom. The C(60)-N(12) bond length is 1.38 Å. The C(60)-H(38) bond length is 1.08 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(31), and one C(33) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(32), and one C(34) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(31), one C(35), and one C(37) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(32), one C(36), and one C(38) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(45), one C(49), and one C(53) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(46), one C(50), and one C(54) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Cd(3), one C(49), and one C(51) atom. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Cd(3), one C(50), and one C(52) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(41), one C(55), and one C(57) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one C(42), one C(56), and one C(58) atom. In the eleventh N site, N(11) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(55), and one C(59) atom. In the twelfth N site, N(12) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(56), and one C(60) atom. There are twenty-nine inequivalent H sites. In the first H site, H(5,6) is bonded in a single-bond geometry to one C(15) atom. In the second H site, H(7,8) is bonded in a single-bond geometry to one C(19,20) atom. In the third H site, H(9,10) is bonded in a single-bond geometry to one C(21,22) atom. In the fourth H site, H(11,12) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(27) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(28) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(31) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(32) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(33) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(34) atom. In the eleventh H site, H(19,20) is bonded in a single-bond geometry to one C(35) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(39) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(40) atom. In the fourteenth H site, H(23) is bonded in a single-bond geometry to one C(43) atom. In the fifteenth H site, H(24) is bonded in a single-bond geometry to one C(44) atom. In the sixteenth H site, H(25) is bonded in a single-bond geometry to one C(47) atom. In the seventeenth H site, H(26) is bonded in a single-bond geometry to one C(48) atom. In the eighteenth H site, H(27,28) is bonded in a single-bond geometry to one C(49) atom. In the nineteenth H site, H(29,30) is bonded in a single-bond geometry to one C(51) atom. In the twentieth H site, H(31,32) is bonded in a single-bond geometry to one C(53) atom. In the twenty-first H site, H(33) is bonded in a single-bond geometry to one C(55) atom. In the twenty-second H site, H(34) is bonded in a single-bond geometry to one C(56) atom. In the twenty-third H site, H(35,36) is bonded in a single-bond geometry to one C(57) atom. In the twenty-fourth H site, H(37) is bonded in a single-bond geometry to one C(59) atom. In the twenty-fifth H site, H(38) is bonded in a single-bond geometry to one C(60) atom. In the twenty-sixth H site, H(39) is bonded in a single-bond geometry to one O(15) atom. The H(39)-O(15) bond length is 0.97 Å. In the twenty-seventh H site, H(40) is bonded in a single-bond geometry to one O(16) atom. The H(40)-O(16) bond length is 0.97 Å. In the twenty-eighth H site, H(41) is bonded in a distorted single-bond geometry to one O(15) and one O(5) atom. The H(41)-O(15) bond length is 1.01 Å. The H(41)-O(5) bond length is 1.70 Å. In the twenty-ninth H site, H(42) is bonded in a distorted single-bond geometry to one O(16) and one O(6) atom. The H(42)-O(16) bond length is 1.00 Å. The H(42)-O(6) bond length is 1.71 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cd(2) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cd(2), one C(3), and one H(41) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Cd(1), one C(4), and one H(42) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Cd(2) and one C(3) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cd(1) and one C(4) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one C(17) and one C(9) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one C(10) and one C(18) atom. In the eleventh O site, O(11) is bonded in a distorted L-shaped geometry to one Cd(3) and one C(29) atom. In the twelfth O site, O(12) is bonded in a distorted L-shaped geometry to one Cd(3) and one C(30) atom. In the thirteenth O site, O(13) is bonded in an L-shaped geometry to one Cd(3) and one C(29) atom. In the fourteenth O site, O(14) is bonded in an L-shaped geometry to one Cd(3) and one C(30) atom. In the fifteenth O site, O(15) is bonded in a distorted water-like geometry to one Cd(1), one H(39), and one H(41) atom. In the sixteenth O site, O(16) is bonded in a distorted water-like geometry to one Cd(2), one H(40), and one H(42) atom. Linkers: 2 [O]C(=O)c1ccc(Oc2cccc(C([O])=O)c2C([O])=O)cc1 ,1 [c]1cn(-c2cc(-n3ccnc3)cc(-n3ccnc3)c2)cn1 ,2 c1cn(-c2cc(-n3ccnc3)cc(-n3ccnc3)c2)cn1 ,1 [CH]N([CH])c1cc(-n2ccnc2)cc(-n2ccnc2)c1. Metal clusters: 2 O.O=[C]O[Cd]O[C]=O ,1 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 3.13 A, density 1.66 g/cm3, surface area 4191.50 m2/g, accessible volume 0.17 cm3/g