(CH2)4HgC30N6H22(O2Cl)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two HgC30N6H22(O2Cl)2 clusters. In each HgC30N6H22(O2Cl)2 cluster, Hg(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent Cl(1) atoms. Both Hg(1)-N(1) bond lengths are 2.47 Å. Both Hg(1)-Cl(1) bond lengths are 2.41 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.48 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(7) atom. The C(6)-C(11) bond length is 1.40 Å. The C(6)-C(7) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.50 Å. The C(8)-C(9) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(6) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(6) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one N(3) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-N(3) bond length is 1.42 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(6), and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(2), and one O(1) atom. The C(12)-N(2) bond length is 1.36 Å. The C(12)-O(1) bond length is 1.25 Å. In the thirteenth C site, C(13) is bonded in a 2-coordinate geometry to one N(2) and one H(8) atom. The C(13)-N(2) bond length is 1.47 Å. The C(13)-H(8) bond length is 1.10 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(13), and one H(14) atom. The C(16)-N(2) bond length is 1.47 Å. The C(16)-H(13) bond length is 1.09 Å. The C(16)-H(14) bond length is 1.10 Å. In the fifteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(3) and one O(2) atom. The C(17)-N(3) bond length is 1.35 Å. The C(17)-O(2) bond length is 1.24 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Hg(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(16) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(17), and one H(15) atom. The N(3)-H(15) bond length is 1.03 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(12) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(17) atom. Cl(1) is bonded in a single-bond geometry to one Hg(1) atom. Linkers: 1 O=C1Nc2cc(cc(-c3ccncc3)c2)C(=O)N2CCC[C@H]2C(=O)Nc2cc(cc(-c3c[c]ncc3)c2)C(=O)N2CCC[C@@H]12 ,1 [NH]c1[c]c([C]N2[CH][CH]C[C@H]2[C]Nc2[c][c]cc(-c3ccncc3)c2)cc(-c2ccncc2)c1 ,1 O=C1Nc2cc(cc(-c3ccncc3)c2)C(=O)N2CCC[C@H]2C(=O)Nc2cc(cc(-c3ccncc3)c2)C(=O)N2CCC[C@@H]12 ,1 [NH]c1[c]c([C]N2[CH][CH]C[C@H]2[C]Nc2[c][c]cc(-c3c[c]ncc3)c2)cc(-c2ccncc2)c1 ,1 [C]/C=C(\C=[CH])c1cc2cc(c1)C(=O)N1CCC[C@H]1C(=O)Nc1cc(C(=[CH])C=[CH])cc(c1)C(=O)N1CCC[C@H]1C(=O)N2. Metal clusters: . The MOF has largest included sphere 4.63 A, density 1.60 g/cm3, surface area 4095.57 m2/g, accessible volume 0.21 cm3/g