FeAg2H8(C3N)6(C8H5)2CHC7H4 crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules; one 1,4,5,8-tetramethylnaphthalene molecule; and two pyrene molecules inside a FeAg2H8(C3N)6 framework. In each FeAg2H8(C3N)6 framework, Fe(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one N(5), and one N(6) atom. The Fe(1)-N(1) bond length is 2.22 Å. The Fe(1)-N(2) bond length is 2.18 Å. The Fe(1)-N(3) bond length is 2.09 Å. The Fe(1)-N(4) bond length is 2.12 Å. The Fe(1)-N(5) bond length is 2.09 Å. The Fe(1)-N(6) bond length is 2.12 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one C(17) and one C(18) atom. The Ag(1)-C(17) bond length is 2.03 Å. The Ag(1)-C(18) bond length is 2.03 Å. In the second Ag site, Ag(2) is bonded in a linear geometry to one C(15) and one C(16) atom. The Ag(2)-C(15) bond length is 2.03 Å. The Ag(2)-C(16) bond length is 2.03 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a linear geometry to one C(3) and one C(7) atom. The C(6)-C(7) bond length is 1.23 Å. In the seventh C site, C(7) is bonded in a linear geometry to one C(6) and one C(8) atom. The C(7)-C(8) bond length is 1.34 Å. In the eighth C site, C(8) is bonded in a linear geometry to one C(7) and one C(9) atom. The C(8)-C(9) bond length is 1.23 Å. In the ninth C site, C(9) is bonded in a linear geometry to one C(10) and one C(8) atom. The C(9)-C(10) bond length is 1.41 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(9) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-C(14) bond length is 1.41 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(5) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(5) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one H(6) atom. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(6) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(2), and one H(7) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-N(2) bond length is 1.35 Å. The C(13)-H(7) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(10), one C(13), and one H(8) atom. The C(14)-H(8) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a linear geometry to one Ag(2) and one N(3) atom. The C(15)-N(3) bond length is 1.17 Å. In the sixteenth C site, C(16) is bonded in a linear geometry to one Ag(2) and one N(5) atom. The C(16)-N(5) bond length is 1.17 Å. In the seventeenth C site, C(17) is bonded in a linear geometry to one Ag(1) and one N(4) atom. The C(17)-N(4) bond length is 1.17 Å. In the eighteenth C site, C(18) is bonded in a linear geometry to one Ag(1) and one N(6) atom. The C(18)-N(6) bond length is 1.17 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Fe(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Fe(1), one C(12), and one C(13) atom. In the third N site, N(3) is bonded in a linear geometry to one Fe(1) and one C(15) atom. In the fourth N site, N(4) is bonded in a linear geometry to one Fe(1) and one C(17) atom. In the fifth N site, N(5) is bonded in a linear geometry to one Fe(1) and one C(16) atom. In the sixth N site, N(6) is bonded in a distorted linear geometry to one Fe(1) and one C(18) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. Linkers: 2 C(C#Cc1ccncc1)#Cc1ccncc1. Metal clusters: 2 [Fe]. The MOF has largest included sphere 2.72 A, density 1.65 g/cm3, surface area 4315.47 m2/g, accessible volume 0.16 cm3/g