(CH)8PbC20H10(NO2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and two PbC20H10(NO2)2 clusters. In each PbC20H10(NO2)2 cluster, Pb(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Pb(1)-N(1) bond length is 2.63 Å. The Pb(1)-N(2) bond length is 2.68 Å. The Pb(1)-O(1) bond length is 2.52 Å. The Pb(1)-O(2) bond length is 2.76 Å. The Pb(1)-O(3) bond length is 2.41 Å. The Pb(1)-O(4) bond length is 2.72 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(3)-O(3) bond length is 1.29 Å. The C(3)-O(4) bond length is 1.27 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(3) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(3) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(4) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(4) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(23), one C(6), and one C(8) atom. The C(7)-C(23) bond length is 1.47 Å. The C(7)-C(8) bond length is 1.43 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(16), one C(7), and one C(9) atom. The C(8)-C(16) bond length is 1.43 Å. The C(8)-C(9) bond length is 1.42 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(1) atom. The C(9)-C(10) bond length is 1.45 Å. The C(9)-N(1) bond length is 1.36 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(14), one C(9), and one N(2) atom. The C(10)-C(14) bond length is 1.43 Å. The C(10)-N(2) bond length is 1.36 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(5) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-N(2) bond length is 1.33 Å. The C(11)-H(5) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(6) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(6) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(17) atom. The C(13)-C(14) bond length is 1.43 Å. The C(13)-C(17) bond length is 1.48 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(15) atom. The C(14)-C(15) bond length is 1.43 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(7) atom. The C(15)-H(7) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(16)-H(8) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(13), one C(18), and one C(22) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-C(22) bond length is 1.41 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(9) atom. The C(18)-H(9) bond length is 1.09 Å. In the seventeenth C site, C(22) is bonded in a distorted single-bond geometry to one C(17) and one H(13) atom. The C(22)-H(13) bond length is 1.09 Å. In the eighteenth C site, C(23) is bonded in a trigonal planar geometry to one C(24), one C(28), and one C(7) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(28) bond length is 1.41 Å. In the nineteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(14) atom. The C(24)-H(14) bond length is 1.09 Å. In the twentieth C site, C(28) is bonded in a distorted single-bond geometry to one C(23) and one H(18) atom. The C(28)-H(18) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Pb(1), one C(5), and one C(9) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one Pb(1), one C(10), and one C(11) atom. There are ten inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(28) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pb(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Pb(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Pb(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Pb(1) and one C(3) atom. Linkers: 2 c1ccc(-c2ccnc3c2ccc2c(-c4ccccc4)ccnc23)cc1 ,2 [O]C(=O)/C=C/C([O])=O. Metal clusters: 1 O=[C]O[Pb]O[C]=O.O=[C]O[Pb]O[C]=O. The MOF has largest included sphere 2.31 A, density 1.94 g/cm3, surface area 3615.91 m2/g, accessible volume 0.12 cm3/g