MnC16N4H14O5(CH2)4 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two MnC16N4H14O5 clusters. In each MnC16N4H14O5 cluster, Mn(1) is bonded in a 5-coordinate geometry to one N(5), one N(6), one O(1), one O(3), and one O(4) atom. The Mn(1)-N(5) bond length is 2.02 Å. The Mn(1)-N(6) bond length is 2.02 Å. The Mn(1)-O(1) bond length is 2.01 Å. The Mn(1)-O(3) bond length is 2.06 Å. The Mn(1)-O(4) bond length is 2.07 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(5), and one H(5) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-N(5) bond length is 1.34 Å. The C(1)-H(5) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(6), and one H(6) atom. The C(2)-N(2) bond length is 1.36 Å. The C(2)-N(6) bond length is 1.34 Å. The C(2)-H(6) bond length is 1.08 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(25), one C(9), and one H(9) atom. The C(5)-C(25) bond length is 1.40 Å. The C(5)-C(9) bond length is 1.39 Å. The C(5)-H(9) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(10); one C(26); and one H(10,12) atom. The C(6)-C(10) bond length is 1.39 Å. The C(6)-C(26) bond length is 1.40 Å. The C(6)-H(10,12) bond length is 1.09 Å. In the fifth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(13), one C(5), and one H(13) atom. The C(9)-C(13) bond length is 1.41 Å. The C(9)-H(13) bond length is 1.09 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(14), one C(6), and one H(14) atom. The C(10)-C(14) bond length is 1.41 Å. The C(10)-H(14) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(17), one C(9), and one H(17) atom. The C(13)-C(17) bond length is 1.39 Å. The C(13)-H(17) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(10), one C(18), and one H(18) atom. The C(14)-C(18) bond length is 1.39 Å. The C(14)-H(18) bond length is 1.09 Å. In the ninth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(13); one C(21); and one H(21,23) atom. The C(17)-C(21) bond length is 1.40 Å. The C(17)-H(21,23) bond length is 1.09 Å. In the tenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(14), one C(22), and one H(22) atom. The C(18)-C(22) bond length is 1.40 Å. The C(18)-H(22) bond length is 1.09 Å. In the eleventh C site, C(21) is bonded in a distorted trigonal planar geometry to one C(17), one C(25), and one N(1) atom. The C(21)-C(25) bond length is 1.42 Å. The C(21)-N(1) bond length is 1.38 Å. In the twelfth C site, C(22) is bonded in a distorted single-bond geometry to one C(18), one C(26), and one N(2) atom. The C(22)-C(26) bond length is 1.42 Å. The C(22)-N(2) bond length is 1.38 Å. In the thirteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(21), one C(5), and one N(5) atom. The C(25)-N(5) bond length is 1.40 Å. In the fourteenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(22), one C(6), and one N(6) atom. The C(26)-N(6) bond length is 1.40 Å. In the fifteenth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(7) atom. The C(29)-O(3) bond length is 1.30 Å. The C(29)-O(7) bond length is 1.26 Å. In the sixteenth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(8) atom. The C(30)-O(4) bond length is 1.29 Å. The C(30)-O(8) bond length is 1.27 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(21), and one H(1) atom. The N(1)-H(1) bond length is 1.04 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(22), and one H(2) atom. The N(2)-H(2) bond length is 1.04 Å. In the third N site, N(5) is bonded in a trigonal planar geometry to one Mn(1), one C(1), and one C(25) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one Mn(1), one C(2), and one C(26) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one N(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(10,12) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(21,23) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(41) is bonded in a single-bond geometry to one O(1) atom. The H(41)-O(1) bond length is 1.00 Å. In the fourteenth H site, H(42) is bonded in a single-bond geometry to one O(1) atom. The H(42)-O(1) bond length is 1.00 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one H(41), and one H(42) atom. In the second O site, O(3) is bonded in a 2-coordinate geometry to one Mn(1) and one C(29) atom. In the third O site, O(4) is bonded in a 2-coordinate geometry to one Mn(1) and one C(30) atom. In the fourth O site, O(7) is bonded in a distorted single-bond geometry to one C(29) atom. In the fifth O site, O(8) is bonded in a single-bond geometry to one C(30) atom. Linkers: 2 [O]C(=O)CCCCC([O])=O. Metal clusters: 2 [Mn]. The MOF has largest included sphere 2.00 A, density 1.58 g/cm3, surface area 4405.68 m2/g, accessible volume 0.17 cm3/g