CuC12NH6O4CH2(CH3)2CF crystallizes in the triclinic P-1 space group. The structure consists of twelve 02329_fluka molecules, twenty-four 02329_fluka molecules, and twelve fluoromethane molecules inside a CuC12NH6O4 framework. In the CuC12NH6O4 framework, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square pyramidal geometry to one N(4), one O(15), one O(4), one O(6), and one O(7) atom. The Cu(1)-N(4) bond length is 2.17 Å. The Cu(1)-O(15) bond length is 2.00 Å. The Cu(1)-O(4) bond length is 2.00 Å. The Cu(1)-O(6) bond length is 2.00 Å. The Cu(1)-O(7) bond length is 1.99 Å. In the second Cu site, Cu(2) is bonded in a square pyramidal geometry to one N(3), one O(16), one O(3), one O(5), and one O(8) atom. The Cu(2)-N(3) bond length is 2.18 Å. The Cu(2)-O(16) bond length is 2.00 Å. The Cu(2)-O(3) bond length is 2.00 Å. The Cu(2)-O(5) bond length is 2.00 Å. The Cu(2)-O(8) bond length is 1.99 Å. In the third Cu site, Cu(3,4) is bonded in a square pyramidal geometry to one N(1,2); one O(1,2); one O(13,14); one O(17,18); and one O(21,22) atom. The Cu(3,4)-N(1,2) bond length is 2.17 Å. The Cu(3,4)-O(1,2) bond length is 2.01 Å. The Cu(3,4)-O(13,14) bond length is 1.99 Å. The Cu(3,4)-O(17,18) bond length is 1.99 Å. The Cu(3,4)-O(21,22) bond length is 1.99 Å. In the fourth Cu site, Cu(5,6) is bonded in a square pyramidal geometry to one N(5,6); one O(11,12); one O(19,20); one O(23,24); and one O(9,10) atom. The Cu(5,6)-N(5,6) bond length is 2.18 Å. The Cu(5,6)-O(11,12) bond length is 2.00 Å. The Cu(5,6)-O(19,20) bond length is 2.00 Å. The Cu(5,6)-O(23,24) bond length is 2.00 Å. The Cu(5,6)-O(9,10) bond length is 1.99 Å. There are forty-seven inequivalent C sites. In the first C site, C(1,2) is bonded in a trigonal planar geometry to one C(35,36); one C(5); and one C(53,54) atom. The C(1,2)-C(35,36) bond length is 1.40 Å. The C(1,2)-C(5) bond length is 1.48 Å. The C(1,2)-C(53,54) bond length is 1.40 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(25); one C(57,58); and one H(1,2) atom. The C(3)-C(25) bond length is 1.40 Å. The C(3)-C(57,58) bond length is 1.40 Å. The C(3)-H(1,2) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(26); one C(57,58); and one H(1,2) atom. The C(4)-C(26) bond length is 1.40 Å. The C(4)-C(57,58) bond length is 1.40 Å. The C(4)-H(1,2) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(1,2); one C(23); and one C(43,44) atom. The C(5)-C(23) bond length is 1.40 Å. The C(5)-C(43,44) bond length is 1.40 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(1,2); one C(24); and one C(43,44) atom. The C(6)-C(1,2) bond length is 1.48 Å. The C(6)-C(24) bond length is 1.40 Å. The C(6)-C(43,44) bond length is 1.40 Å. In the sixth C site, C(7,8) is bonded in a distorted single-bond geometry to one C(19,20); one C(37,38); and one H(3,4) atom. The C(7,8)-C(19,20) bond length is 1.40 Å. The C(7,8)-C(37,38) bond length is 1.40 Å. The C(7,8)-H(3,4) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(15), and one O(7) atom. The C(9)-C(15) bond length is 1.50 Å. The C(9)-O(15) bond length is 1.27 Å. The C(9)-O(7) bond length is 1.27 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(16), and one O(8) atom. The C(10)-C(16) bond length is 1.50 Å. The C(10)-O(16) bond length is 1.27 Å. The C(10)-O(8) bond length is 1.28 Å. In the ninth C site, C(11,12) is bonded in a distorted bent 120 degrees geometry to one C(69,70); one O(1,2); and one O(9,10) atom. The C(11,12)-C(69,70) bond length is 1.50 Å. The C(11,12)-O(1,2) bond length is 1.27 Å. The C(11,12)-O(9,10) bond length is 1.27 Å. In the tenth C site, C(13,14) is bonded in a distorted bent 120 degrees geometry to one C(63,64); one O(11,12); and one O(13,14) atom. The C(13,14)-C(63,64) bond length is 1.49 Å. The C(13,14)-O(11,12) bond length is 1.27 Å. The C(13,14)-O(13,14) bond length is 1.27 Å. In the eleventh C site, C(15) is bonded in a trigonal planar geometry to one C(21), one C(47), and one C(9) atom. The C(15)-C(21) bond length is 1.40 Å. The C(15)-C(47) bond length is 1.40 Å. In the twelfth C site, C(16) is bonded in a trigonal planar geometry to one C(10), one C(22), and one C(48) atom. The C(16)-C(22) bond length is 1.40 Å. The C(16)-C(48) bond length is 1.40 Å. In the thirteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(3), and one O(5) atom. The C(17)-C(25) bond length is 1.49 Å. The C(17)-O(3) bond length is 1.27 Å. The C(17)-O(5) bond length is 1.27 Å. In the fourteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(4), and one O(6) atom. The C(18)-C(26) bond length is 1.50 Å. The C(18)-O(4) bond length is 1.27 Å. The C(18)-O(6) bond length is 1.27 Å. In the fifteenth C site, C(19,20) is bonded in a trigonal planar geometry to one C(27,28); one C(59,60); and one C(7,8) atom. The C(19,20)-C(27,28) bond length is 1.40 Å. The C(19,20)-C(59,60) bond length is 1.48 Å. In the sixteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(15); one C(25); and one H(5,6) atom. The C(21)-C(25) bond length is 1.40 Å. The C(21)-H(5,6) bond length is 1.09 Å. In the seventeenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(16); one C(26); and one H(5,6) atom. The C(22)-C(26) bond length is 1.40 Å. The C(22)-H(5,6) bond length is 1.09 Å. In the eighteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(5), one N(3), and one H(7) atom. The C(23)-N(3) bond length is 1.34 Å. The C(23)-H(7) bond length is 1.09 Å. In the nineteenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(6), one N(4), and one H(8) atom. The C(24)-N(4) bond length is 1.34 Å. The C(24)-H(8) bond length is 1.09 Å. In the twentieth C site, C(25) is bonded in a trigonal planar geometry to one C(17), one C(21), and one C(3) atom. In the twenty-first C site, C(26) is bonded in a trigonal planar geometry to one C(18), one C(22), and one C(4) atom. In the twenty-second C site, C(27,28) is bonded in a distorted single-bond geometry to one C(19,20); one C(63,64); and one H(9,10) atom. The C(27,28)-C(63,64) bond length is 1.40 Å. The C(27,28)-H(9,10) bond length is 1.09 Å. In the twenty-third C site, C(29,30) is bonded in a distorted trigonal planar geometry to one C(49,50); one C(69,70); and one H(11,12) atom. The C(29,30)-C(49,50) bond length is 1.40 Å. The C(29,30)-C(69,70) bond length is 1.40 Å. The C(29,30)-H(11,12) bond length is 1.09 Å. In the twenty-fourth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(13) atom. The C(31)-N(3) bond length is 1.34 Å. The C(31)-H(13) bond length is 1.09 Å. In the twenty-fifth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(14) atom. The C(32)-N(4) bond length is 1.34 Å. The C(32)-H(14) bond length is 1.09 Å. In the twenty-sixth C site, C(33) is bonded in a trigonal planar geometry to one C(41,42); one C(45,46); and one C(57,58) atom. The C(33)-C(41,42) bond length is 1.40 Å. The C(33)-C(45,46) bond length is 1.40 Å. The C(33)-C(57,58) bond length is 1.48 Å. In the twenty-seventh C site, C(34) is bonded in a trigonal planar geometry to one C(41,42); one C(45,46); and one C(57,58) atom. The C(34)-C(41,42) bond length is 1.40 Å. The C(34)-C(45,46) bond length is 1.40 Å. The C(34)-C(57,58) bond length is 1.48 Å. In the twenty-eighth C site, C(35,36) is bonded in a distorted single-bond geometry to one C(1,2); one C(49,50); and one H(15,16) atom. The C(35,36)-C(49,50) bond length is 1.40 Å. The C(35,36)-H(15,16) bond length is 1.09 Å. In the twenty-ninth C site, C(37,38) is bonded in a trigonal planar geometry to one C(39,40); one C(61,62); and one C(7,8) atom. The C(37,38)-C(39,40) bond length is 1.40 Å. The C(37,38)-C(61,62) bond length is 1.50 Å. In the thirtieth C site, C(39,40) is bonded in a distorted trigonal planar geometry to one C(37,38); one C(63,64); and one H(17,18) atom. The C(39,40)-C(63,64) bond length is 1.40 Å. The C(39,40)-H(17,18) bond length is 1.09 Å. In the thirty-first C site, C(41,42) is bonded in a distorted single-bond geometry to one C(33) and one H(19,20,21,22) atom. The C(41,42)-H(19,20,21,22) bond length is 1.09 Å. In the thirty-second C site, C(43,44) is bonded in a distorted single-bond geometry to one C(5) and one H(19,20,21,22) atom. The C(43,44)-H(19,20,21,22) bond length is 1.09 Å. In the thirty-third C site, C(45,46) is bonded in a distorted trigonal planar geometry to one C(33); one N(5,6); and one H(23,24) atom. The C(45,46)-N(5,6) bond length is 1.34 Å. The C(45,46)-H(23,24) bond length is 1.09 Å. In the thirty-fourth C site, C(47) is bonded in a distorted single-bond geometry to one C(15); one C(57,58); and one H(25,26) atom. The C(47)-C(57,58) bond length is 1.40 Å. The C(47)-H(25,26) bond length is 1.09 Å. In the thirty-fifth C site, C(48) is bonded in a distorted single-bond geometry to one C(16); one C(57,58); and one H(25,26) atom. The C(48)-C(57,58) bond length is 1.40 Å. The C(48)-H(25,26) bond length is 1.09 Å. In the thirty-sixth C site, C(49,50) is bonded in a trigonal planar geometry to one C(29,30); one C(35,36); and one C(67,68) atom. The C(49,50)-C(67,68) bond length is 1.50 Å. In the thirty-seventh C site, C(53,54) is bonded in a distorted single-bond geometry to one C(1,2); one C(69,70); and one H(27,28) atom. The C(53,54)-C(69,70) bond length is 1.40 Å. The C(53,54)-H(27,28) bond length is 1.09 Å. In the thirty-eighth C site, C(57,58) is bonded in a trigonal planar geometry to one C(3), one C(33), and one C(47) atom. In the thirty-ninth C site, C(59,60) is bonded in a trigonal planar geometry to one C(19,20); one C(71,72); and one C(77,78) atom. The C(59,60)-C(71,72) bond length is 1.40 Å. The C(59,60)-C(77,78) bond length is 1.40 Å. In the fortieth C site, C(61,62) is bonded in a distorted bent 120 degrees geometry to one C(37,38); one O(19,20); and one O(21,22) atom. The C(61,62)-O(19,20) bond length is 1.28 Å. The C(61,62)-O(21,22) bond length is 1.27 Å. In the forty-first C site, C(63,64) is bonded in a trigonal planar geometry to one C(13,14); one C(27,28); and one C(39,40) atom. In the forty-second C site, C(65,66) is bonded in a distorted bent 120 degrees geometry to one N(5,6) and one H(29,30,33,34) atom. The C(65,66)-N(5,6) bond length is 1.34 Å. The C(65,66)-H(29,30,33,34) bond length is 1.09 Å. In the forty-third C site, C(67,68) is bonded in a distorted bent 120 degrees geometry to one C(49,50); one O(17,18); and one O(23,24) atom. The C(67,68)-O(17,18) bond length is 1.27 Å. The C(67,68)-O(23,24) bond length is 1.27 Å. In the forty-fourth C site, C(69,70) is bonded in a trigonal planar geometry to one C(11,12); one C(29,30); and one C(53,54) atom. In the forty-fifth C site, C(71,72) is bonded in a distorted single-bond geometry to one C(59,60) and one H(31,32) atom. The C(71,72)-H(31,32) bond length is 1.09 Å. In the forty-sixth C site, C(73,74) is bonded in a distorted bent 120 degrees geometry to one N(1,2) and one H(29,30,33,34) atom. The C(73,74)-N(1,2) bond length is 1.34 Å. The C(73,74)-H(29,30,33,34) bond length is 1.09 Å. In the forty-seventh C site, C(77,78) is bonded in a distorted trigonal planar geometry to one C(59,60); one N(1,2); and one H(35,36) atom. The C(77,78)-N(1,2) bond length is 1.34 Å. The C(77,78)-H(35,36) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1,2) is bonded in a trigonal planar geometry to one Cu(3,4); one C(73,74); and one C(77,78) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cu(2), one C(23), and one C(31) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(24), and one C(32) atom. In the fourth N site, N(5,6) is bonded in a trigonal planar geometry to one Cu(5,6); one C(45,46); and one C(65,66) atom. There are eighteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(7,8) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(21) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(23) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(24) atom. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(27,28) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(29,30) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(31) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(32) atom. In the tenth H site, H(15,16) is bonded in a single-bond geometry to one C(35,36) atom. In the eleventh H site, H(17,18) is bonded in a single-bond geometry to one C(39,40) atom. In the twelfth H site, H(19,20,21,22) is bonded in a single-bond geometry to one C(41,42) atom. In the thirteenth H site, H(23,24) is bonded in a single-bond geometry to one C(45,46) atom. In the fourteenth H site, H(25,26) is bonded in a single-bond geometry to one C(47) atom. In the fifteenth H site, H(27,28) is bonded in a single-bond geometry to one C(53,54) atom. In the sixteenth H site, H(29,30,33,34) is bonded in a single-bond geometry to one C(65,66) atom. In the seventeenth H site, H(31,32) is bonded in a single-bond geometry to one C(71,72) atom. In the eighteenth H site, H(35,36) is bonded in a single-bond geometry to one C(77,78) atom. There are sixteen inequivalent O sites. In the first O site, O(1,2) is bonded in a bent 120 degrees geometry to one Cu(3,4) and one C(11,12) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(17) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(18) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(17) atom. In the fifth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(18) atom. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(9) atom. In the seventh O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(10) atom. In the eighth O site, O(9,10) is bonded in a bent 120 degrees geometry to one Cu(5,6) and one C(11,12) atom. In the ninth O site, O(11,12) is bonded in a bent 120 degrees geometry to one Cu(5,6) and one C(13,14) atom. In the tenth O site, O(13,14) is bonded in a bent 120 degrees geometry to one Cu(3,4) and one C(13,14) atom. In the eleventh O site, O(15) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(9) atom. In the twelfth O site, O(16) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(10) atom. In the thirteenth O site, O(17,18) is bonded in a bent 120 degrees geometry to one Cu(3,4) and one C(67,68) atom. In the fourteenth O site, O(19,20) is bonded in a bent 120 degrees geometry to one Cu(5,6) and one C(61,62) atom. In the fifteenth O site, O(21,22) is bonded in a bent 120 degrees geometry to one Cu(3,4) and one C(61,62) atom. In the sixteenth O site, O(23,24) is bonded in a bent 120 degrees geometry to one Cu(5,6) and one C(67,68) atom. Linkers: 12 [O]C(=O)c1cc(C([O])=O)cc(-c2cncc(F)c2)c1. Metal clusters: 6 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 3.18 A, density 1.51 g/cm3, surface area 4830.82 m2/g, accessible volume 0.15 cm3/g