NiC28H24(NO2)2(CH2)2(C7NH7O2)2(H2O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two water molecules, two C7NH7O2 clusters, and one NiC28H24(NO2)2 cluster. In each C7NH7O2 cluster, there are seven inequivalent C sites. In the first C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(10)-O(3) bond length is 1.26 Å. The C(10)-O(4) bond length is 1.29 Å. In the second C site, C(17) is bonded in a distorted trigonal planar geometry to one C(18), one N(2), and one H(18) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-N(2) bond length is 1.35 Å. The C(17)-H(18) bond length is 1.09 Å. In the third C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(21), and one H(19) atom. The C(18)-C(21) bond length is 1.41 Å. The C(18)-H(19) bond length is 1.09 Å. In the fourth C site, C(19) is bonded in a distorted single-bond geometry to one C(20), one C(21), and one H(20) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-C(21) bond length is 1.40 Å. The C(19)-H(20) bond length is 1.09 Å. In the fifth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one N(2), and one H(21) atom. The C(20)-N(2) bond length is 1.34 Å. The C(20)-H(21) bond length is 1.09 Å. In the sixth C site, C(21) is bonded in a trigonal planar geometry to one C(18), one C(19), and one C(22) atom. The C(21)-C(22) bond length is 1.50 Å. In the seventh C site, C(22) is bonded in a distorted water-like geometry to one C(21), one H(22), and one H(23) atom. The C(22)-H(22) bond length is 1.10 Å. The C(22)-H(23) bond length is 1.11 Å. N(2) is bonded in a trigonal planar geometry to one C(17), one C(20), and one H(1) atom. The N(2)-H(1) bond length is 1.15 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one N(2) and one O(4) atom. The H(1)-O(4) bond length is 1.39 Å. In the second H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the fourth H site, H(20) is bonded in a single-bond geometry to one C(19) atom. In the fifth H site, H(21) is bonded in a single-bond geometry to one C(20) atom. In the sixth H site, H(22) is bonded in a single-bond geometry to one C(22) atom. In the seventh H site, H(23) is bonded in a single-bond geometry to one C(22) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one C(10) atom. In the second O site, O(4) is bonded in a water-like geometry to one C(10) and one H(1) atom. In the NiC28H24(NO2)2 cluster, Ni(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Ni(1)-N(1) bond lengths are 1.94 Å. Both Ni(1)-O(1) bond lengths are 1.93 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(4) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(4) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(5) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(5) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-C(8) bond length is 1.50 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(6) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(7) atom. The C(7)-H(7) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted water-like geometry to one C(5) and two equivalent H(8,9) atoms. Both C(8)-H(8,9) bond lengths are 1.10 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(1), and one H(12) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(12) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(13) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(13) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(16) bond length is 1.50 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(14) atom. The C(14)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(15) atom. The C(15)-N(1) bond length is 1.35 Å. The C(15)-H(15) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted water-like geometry to one C(13), one H(16), and one H(17) atom. The C(16)-H(16) bond length is 1.10 Å. The C(16)-H(17) bond length is 1.10 Å. N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(11), and one C(15) atom. There are eleven inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(8,9) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(16) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. Linkers: 2 [c]1cc(CCc2ccncc2)ccn1 ,1 c1cc(CCc2ccncc2)ccn1. Metal clusters: 1 [Ni]. The MOF has largest included sphere 2.03 A, density 1.45 g/cm3, surface area 5114.88 m2/g, accessible volume 0.12 cm3/g