CuC34P2NH26ClCH crystallizes in the monoclinic C2 space group. The structure consists of twelve 02329_fluka molecules inside a CuC34P2NH26Cl framework. In the CuC34P2NH26Cl framework, there are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a tetrahedral geometry to one P(1); one P(6); one N(2); and one Cl(1,2) atom. The Cu(1)-P(1) bond length is 2.25 Å. The Cu(1)-P(6) bond length is 2.24 Å. The Cu(1)-N(2) bond length is 2.05 Å. The Cu(1)-Cl(1,2) bond length is 2.31 Å. In the second Cu site, Cu(2) is bonded in a tetrahedral geometry to one P(2); one P(4); one N(1); and one Cl(1,2) atom. The Cu(2)-P(2) bond length is 2.25 Å. The Cu(2)-P(4) bond length is 2.24 Å. The Cu(2)-N(1) bond length is 2.05 Å. The Cu(2)-Cl(1,2) bond length is 2.31 Å. In the third Cu site, Cu(3) is bonded in a tetrahedral geometry to one P(3), one P(5), one N(3), and one Cl(3) atom. The Cu(3)-P(3) bond length is 2.25 Å. The Cu(3)-P(5) bond length is 2.24 Å. The Cu(3)-N(3) bond length is 2.05 Å. The Cu(3)-Cl(3) bond length is 2.31 Å. There are sixty-seven inequivalent C sites. In the first C site, C(79,80,81) is bonded in a distorted single-bond geometry to one C(76,78); one C(82,84); and one H(58,60) atom. The C(79,80,81)-C(76,78) bond length is 1.40 Å. The C(79,80,81)-C(82,84) bond length is 1.40 Å. The C(79,80,81)-H(58,60) bond length is 1.09 Å. In the second C site, C(82,84) is bonded in a distorted trigonal planar geometry to one C(79,80,81); one C(85,87); and one H(61,62,63) atom. The C(82,84)-C(85,87) bond length is 1.40 Å. The C(82,84)-H(61,62,63) bond length is 1.09 Å. In the third C site, C(83) is bonded in a distorted trigonal planar geometry to one C(79,80,81); one C(86); and one H(61,62,63) atom. The C(83)-C(79,80,81) bond length is 1.40 Å. The C(83)-C(86) bond length is 1.40 Å. The C(83)-H(61,62,63) bond length is 1.09 Å. In the fourth C site, C(85,87) is bonded in a distorted single-bond geometry to one C(70,72); one C(82,84); and one H(64,66) atom. The C(85,87)-C(70,72) bond length is 1.40 Å. The C(85,87)-H(64,66) bond length is 1.09 Å. In the fifth C site, C(86) is bonded in a distorted single-bond geometry to one C(71), one C(83), and one H(65) atom. The C(86)-C(71) bond length is 1.40 Å. The C(86)-H(65) bond length is 1.09 Å. In the sixth C site, C(88) is bonded in a trigonal planar geometry to one C(103), one C(91), and one P(4) atom. The C(88)-C(103) bond length is 1.41 Å. The C(88)-C(91) bond length is 1.40 Å. The C(88)-P(4) bond length is 1.83 Å. In the seventh C site, C(89) is bonded in a trigonal planar geometry to one C(104,105); one C(92,93); and one P(5) atom. The C(89)-C(104,105) bond length is 1.41 Å. The C(89)-C(92,93) bond length is 1.40 Å. The C(89)-P(5) bond length is 1.83 Å. In the eighth C site, C(90) is bonded in a trigonal planar geometry to one C(104,105); one C(92,93); and one P(6) atom. The C(90)-C(104,105) bond length is 1.41 Å. The C(90)-C(92,93) bond length is 1.40 Å. The C(90)-P(6) bond length is 1.83 Å. In the ninth C site, C(91) is bonded in a distorted trigonal planar geometry to one C(88), one C(94), and one H(67) atom. The C(91)-C(94) bond length is 1.40 Å. The C(91)-H(67) bond length is 1.09 Å. In the tenth C site, C(92,93) is bonded in a distorted trigonal planar geometry to one C(89); one C(95,96); and one H(68,69) atom. The C(92,93)-C(95,96) bond length is 1.40 Å. The C(92,93)-H(68,69) bond length is 1.09 Å. In the eleventh C site, C(94) is bonded in a distorted single-bond geometry to one C(91); one C(97); and one H(70,71,72) atom. The C(94)-C(97) bond length is 1.40 Å. The C(94)-H(70,71,72) bond length is 1.09 Å. In the twelfth C site, C(95,96) is bonded in a distorted single-bond geometry to one C(92,93); one C(98,99); and one H(70,71,72) atom. The C(95,96)-C(98,99) bond length is 1.40 Å. The C(95,96)-H(70,71,72) bond length is 1.09 Å. In the thirteenth C site, C(97) is bonded in a distorted trigonal planar geometry to one C(100), one C(94), and one H(73) atom. The C(97)-C(100) bond length is 1.40 Å. The C(97)-H(73) bond length is 1.09 Å. In the fourteenth C site, C(98,99) is bonded in a distorted trigonal planar geometry to one C(101,102); one C(95,96); and one H(74,75) atom. The C(98,99)-C(101,102) bond length is 1.40 Å. The C(98,99)-H(74,75) bond length is 1.09 Å. In the fifteenth C site, C(100) is bonded in a distorted trigonal planar geometry to one C(103), one C(97), and one H(76) atom. The C(100)-C(103) bond length is 1.39 Å. The C(100)-H(76) bond length is 1.09 Å. In the sixteenth C site, C(101,102) is bonded in a distorted trigonal planar geometry to one C(104,105); one C(98,99); and one H(77,78) atom. The C(101,102)-C(104,105) bond length is 1.39 Å. The C(101,102)-H(77,78) bond length is 1.09 Å. In the seventeenth C site, C(103) is bonded in a distorted trigonal planar geometry to one C(100); one C(88); and one H(79,80,81) atom. The C(103)-H(79,80,81) bond length is 1.09 Å. In the eighteenth C site, C(104,105) is bonded in a distorted trigonal planar geometry to one C(101,102); one C(89); and one H(79,80,81) atom. The C(104,105)-H(79,80,81) bond length is 1.09 Å. In the nineteenth C site, C(1,2,3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,2) atom. The C(1,2,3)-N(1) bond length is 1.35 Å. The C(1,2,3)-H(1,2) bond length is 1.09 Å. In the twentieth C site, C(4,5,6) is bonded in a distorted single-bond geometry to one C(7,8) and one H(4,5,6) atom. The C(4,5,6)-C(7,8) bond length is 1.40 Å. The C(4,5,6)-H(4,5,6) bond length is 1.09 Å. In the twenty-first C site, C(7,8) is bonded in a trigonal planar geometry to one C(10,11); one C(16,17,18); and one C(4,5,6) atom. The C(7,8)-C(10,11) bond length is 1.40 Å. The C(7,8)-C(16,17,18) bond length is 1.47 Å. In the twenty-second C site, C(9) is bonded in a trigonal planar geometry to one C(12); one C(16,17,18); and one C(4,5,6) atom. The C(9)-C(12) bond length is 1.40 Å. The C(9)-C(16,17,18) bond length is 1.47 Å. The C(9)-C(4,5,6) bond length is 1.40 Å. In the twenty-third C site, C(10,11) is bonded in a distorted trigonal planar geometry to one C(13,14,15); one C(7,8); and one H(7,8,9) atom. The C(10,11)-C(13,14,15) bond length is 1.39 Å. The C(10,11)-H(7,8,9) bond length is 1.09 Å. In the twenty-fourth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13,14,15); one C(9); and one H(7,8,9) atom. The C(12)-C(13,14,15) bond length is 1.39 Å. The C(12)-H(7,8,9) bond length is 1.09 Å. In the twenty-fifth C site, C(13,14,15) is bonded in a distorted bent 120 degrees geometry to one C(10,11); one N(1); and one H(10,11) atom. The C(13,14,15)-N(1) bond length is 1.35 Å. The C(13,14,15)-H(10,11) bond length is 1.09 Å. In the twenty-sixth C site, C(16,17,18) is bonded in a trigonal planar geometry to one C(19,20); one C(31); and one C(7,8) atom. The C(16,17,18)-C(19,20) bond length is 1.41 Å. The C(16,17,18)-C(31) bond length is 1.40 Å. In the twenty-seventh C site, C(19,20) is bonded in a distorted single-bond geometry to one C(16,17,18); one C(22); and one H(13,14,15) atom. The C(19,20)-C(22) bond length is 1.39 Å. The C(19,20)-H(13,14,15) bond length is 1.09 Å. In the twenty-eighth C site, C(21) is bonded in a distorted single-bond geometry to one C(16,17,18); one C(23,24); and one H(13,14,15) atom. The C(21)-C(16,17,18) bond length is 1.41 Å. The C(21)-C(23,24) bond length is 1.39 Å. The C(21)-H(13,14,15) bond length is 1.09 Å. In the twenty-ninth C site, C(22) is bonded in a trigonal planar geometry to one C(19,20); one C(25); and one P(1) atom. The C(22)-C(25) bond length is 1.41 Å. The C(22)-P(1) bond length is 1.84 Å. In the thirtieth C site, C(23,24) is bonded in a trigonal planar geometry to one C(19,20); one C(26); and one P(2) atom. The C(23,24)-C(19,20) bond length is 1.39 Å. The C(23,24)-C(26) bond length is 1.41 Å. The C(23,24)-P(2) bond length is 1.84 Å. In the thirty-first C site, C(25) is bonded in a distorted single-bond geometry to one C(22); one C(28,30); and one H(16,17,18) atom. The C(25)-C(28,30) bond length is 1.40 Å. The C(25)-H(16,17,18) bond length is 1.09 Å. In the thirty-second C site, C(26) is bonded in a distorted single-bond geometry to one C(23,24); one C(29); and one H(16,17,18) atom. The C(26)-C(29) bond length is 1.40 Å. The C(26)-H(16,17,18) bond length is 1.09 Å. In the thirty-third C site, C(27) is bonded in a distorted single-bond geometry to one C(23,24); one C(28,30); and one H(16,17,18) atom. The C(27)-C(23,24) bond length is 1.41 Å. The C(27)-C(28,30) bond length is 1.40 Å. The C(27)-H(16,17,18) bond length is 1.09 Å. In the thirty-fourth C site, C(28,30) is bonded in a trigonal planar geometry to one C(25), one C(31), and one P(4) atom. The C(28,30)-C(31) bond length is 1.40 Å. The C(28,30)-P(4) bond length is 1.83 Å. In the thirty-fifth C site, C(29) is bonded in a trigonal planar geometry to one C(26), one C(32), and one P(5) atom. The C(29)-C(32) bond length is 1.40 Å. The C(29)-P(5) bond length is 1.83 Å. In the thirty-sixth C site, C(31) is bonded in a distorted single-bond geometry to one C(16,17,18); one C(28,30); and one H(19,20,21) atom. The C(31)-H(19,20,21) bond length is 1.09 Å. In the thirty-seventh C site, C(32) is bonded in a distorted single-bond geometry to one C(16,17,18); one C(29); and one H(19,20,21) atom. The C(32)-C(16,17,18) bond length is 1.40 Å. The C(32)-H(19,20,21) bond length is 1.09 Å. In the thirty-eighth C site, C(33) is bonded in a distorted single-bond geometry to one C(16,17,18); one C(28,30); and one H(19,20,21) atom. The C(33)-C(16,17,18) bond length is 1.40 Å. The C(33)-C(28,30) bond length is 1.40 Å. The C(33)-H(19,20,21) bond length is 1.09 Å. In the thirty-ninth C site, C(34) is bonded in a trigonal planar geometry to one C(37,38,39); one C(49,50,51); and one P(1) atom. The C(34)-C(37,38,39) bond length is 1.40 Å. The C(34)-C(49,50,51) bond length is 1.40 Å. The C(34)-P(1) bond length is 1.83 Å. In the fortieth C site, C(35,36) is bonded in a trigonal planar geometry to one C(37,38,39); one C(49,50,51); and one P(2) atom. The C(35,36)-C(37,38,39) bond length is 1.40 Å. The C(35,36)-C(49,50,51) bond length is 1.40 Å. The C(35,36)-P(2) bond length is 1.83 Å. In the forty-first C site, C(37,38,39) is bonded in a distorted single-bond geometry to one C(34) and one H(22) atom. The C(37,38,39)-H(22) bond length is 1.09 Å. In the forty-second C site, C(43,44,45) is bonded in a distorted single-bond geometry to one C(46) and one H(28,29,30) atom. The C(43,44,45)-C(46) bond length is 1.40 Å. The C(43,44,45)-H(28,29,30) bond length is 1.09 Å. In the forty-third C site, C(46) is bonded in a distorted trigonal planar geometry to one C(43,44,45); one C(49,50,51); and one H(31,32,33) atom. The C(46)-C(49,50,51) bond length is 1.39 Å. The C(46)-H(31,32,33) bond length is 1.09 Å. In the forty-fourth C site, C(47,48) is bonded in a distorted trigonal planar geometry to one C(43,44,45); one C(49,50,51); and one H(31,32,33) atom. The C(47,48)-C(43,44,45) bond length is 1.40 Å. The C(47,48)-C(49,50,51) bond length is 1.39 Å. The C(47,48)-H(31,32,33) bond length is 1.09 Å. In the forty-fifth C site, C(49,50,51) is bonded in a distorted single-bond geometry to one C(34), one C(46), and one H(34) atom. The C(49,50,51)-H(34) bond length is 1.09 Å. In the forty-sixth C site, C(52) is bonded in a trigonal planar geometry to one C(55), one C(67), and one P(1) atom. The C(52)-C(55) bond length is 1.41 Å. The C(52)-C(67) bond length is 1.41 Å. The C(52)-P(1) bond length is 1.82 Å. In the forty-seventh C site, C(53) is bonded in a trigonal planar geometry to one C(56), one C(68), and one P(2) atom. The C(53)-C(56) bond length is 1.41 Å. The C(53)-C(68) bond length is 1.41 Å. The C(53)-P(2) bond length is 1.82 Å. In the forty-eighth C site, C(54) is bonded in a trigonal planar geometry to one C(57), one C(69), and one P(3) atom. The C(54)-C(57) bond length is 1.41 Å. The C(54)-C(69) bond length is 1.41 Å. The C(54)-P(3) bond length is 1.82 Å. In the forty-ninth C site, C(55) is bonded in a distorted single-bond geometry to one C(52); one C(58,60); and one H(37,39) atom. The C(55)-C(58,60) bond length is 1.39 Å. The C(55)-H(37,39) bond length is 1.09 Å. In the fiftieth C site, C(56) is bonded in a distorted single-bond geometry to one C(53), one C(59), and one H(38) atom. The C(56)-C(59) bond length is 1.39 Å. The C(56)-H(38) bond length is 1.09 Å. In the fifty-first C site, C(57) is bonded in a distorted single-bond geometry to one C(54); one C(58,60); and one H(37,39) atom. The C(57)-C(58,60) bond length is 1.39 Å. The C(57)-H(37,39) bond length is 1.09 Å. In the fifty-second C site, C(58,60) is bonded in a distorted trigonal planar geometry to one C(55), one C(61), and one H(40) atom. The C(58,60)-C(61) bond length is 1.40 Å. The C(58,60)-H(40) bond length is 1.09 Å. In the fifty-third C site, C(59) is bonded in a distorted trigonal planar geometry to one C(56), one C(62), and one H(41) atom. The C(59)-C(62) bond length is 1.40 Å. The C(59)-H(41) bond length is 1.09 Å. In the fifty-fourth C site, C(61) is bonded in a distorted single-bond geometry to one C(58,60); one C(64,66); and one H(43,45) atom. The C(61)-C(64,66) bond length is 1.40 Å. The C(61)-H(43,45) bond length is 1.09 Å. In the fifty-fifth C site, C(62) is bonded in a distorted single-bond geometry to one C(59), one C(65), and one H(44) atom. The C(62)-C(65) bond length is 1.40 Å. The C(62)-H(44) bond length is 1.09 Å. In the fifty-sixth C site, C(63) is bonded in a distorted single-bond geometry to one C(58,60); one C(64,66); and one H(43,45) atom. The C(63)-C(58,60) bond length is 1.40 Å. The C(63)-C(64,66) bond length is 1.40 Å. The C(63)-H(43,45) bond length is 1.09 Å. In the fifty-seventh C site, C(64,66) is bonded in a distorted trigonal planar geometry to one C(61), one C(67), and one H(46) atom. The C(64,66)-C(67) bond length is 1.40 Å. The C(64,66)-H(46) bond length is 1.09 Å. In the fifty-eighth C site, C(65) is bonded in a distorted trigonal planar geometry to one C(62); one C(68); and one H(47,48) atom. The C(65)-C(68) bond length is 1.40 Å. The C(65)-H(47,48) bond length is 1.09 Å. In the fifty-ninth C site, C(67) is bonded in a distorted single-bond geometry to one C(52); one C(64,66); and one H(49,51) atom. The C(67)-H(49,51) bond length is 1.09 Å. In the sixtieth C site, C(68) is bonded in a distorted single-bond geometry to one C(53), one C(65), and one H(50) atom. The C(68)-H(50) bond length is 1.09 Å. In the sixty-first C site, C(69) is bonded in a distorted single-bond geometry to one C(54); one C(64,66); and one H(49,51) atom. The C(69)-C(64,66) bond length is 1.40 Å. The C(69)-H(49,51) bond length is 1.09 Å. In the sixty-second C site, C(70,72) is bonded in a trigonal planar geometry to one C(73,75); one C(85,87); and one P(4) atom. The C(70,72)-C(73,75) bond length is 1.40 Å. The C(70,72)-P(4) bond length is 1.83 Å. In the sixty-third C site, C(71) is bonded in a trigonal planar geometry to one C(74), one C(86), and one P(5) atom. The C(71)-C(74) bond length is 1.40 Å. The C(71)-P(5) bond length is 1.83 Å. In the sixty-fourth C site, C(73,75) is bonded in a distorted single-bond geometry to one C(70,72); one C(76,78); and one H(52,54) atom. The C(73,75)-C(76,78) bond length is 1.40 Å. The C(73,75)-H(52,54) bond length is 1.09 Å. In the sixty-fifth C site, C(74) is bonded in a distorted single-bond geometry to one C(71), one C(77), and one H(53) atom. The C(74)-C(77) bond length is 1.40 Å. The C(74)-H(53) bond length is 1.09 Å. In the sixty-sixth C site, C(76,78) is bonded in a distorted trigonal planar geometry to one C(73,75); one C(79,80,81); and one H(55,56,57) atom. The C(76,78)-H(55,56,57) bond length is 1.09 Å. In the sixty-seventh C site, C(77) is bonded in a distorted trigonal planar geometry to one C(74); one C(79,80,81); and one H(55,56,57) atom. The C(77)-C(79,80,81) bond length is 1.40 Å. The C(77)-H(55,56,57) bond length is 1.09 Å. There are six inequivalent P sites. In the first P site, P(1) is bonded to one Cu(1), one C(22), one C(34), and one C(52) atom to form corner-sharing PCuC3 tetrahedra. In the second P site, P(2) is bonded to one Cu(2); one C(23,24); one C(35,36); and one C(53) atom to form corner-sharing PCuC3 tetrahedra. In the third P site, P(3) is bonded to one Cu(3); one C(23,24); one C(35,36); and one C(54) atom to form corner-sharing PCuC3 tetrahedra. The P(3)-C(23,24) bond length is 1.84 Å. The P(3)-C(35,36) bond length is 1.83 Å. In the fourth P site, P(4) is bonded to one Cu(2); one C(28,30); one C(70,72); and one C(88) atom to form corner-sharing PCuC3 tetrahedra. In the fifth P site, P(5) is bonded to one Cu(3), one C(29), one C(71), and one C(89) atom to form corner-sharing PCuC3 tetrahedra. In the sixth P site, P(6) is bonded to one Cu(1); one C(28,30); one C(70,72); and one C(90) atom to form corner-sharing PCuC3 tetrahedra. The P(6)-C(28,30) bond length is 1.83 Å. The P(6)-C(70,72) bond length is 1.83 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(2); one C(1,2,3); and one C(13,14,15) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1); one C(1,2,3); and one C(13,14,15) atom. The N(2)-C(1,2,3) bond length is 1.35 Å. The N(2)-C(13,14,15) bond length is 1.35 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(3); one C(1,2,3); and one C(13,14,15) atom. The N(3)-C(1,2,3) bond length is 1.35 Å. The N(3)-C(13,14,15) bond length is 1.35 Å. There are forty-two inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2,3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(1,2,3) atom. The H(3)-C(1,2,3) bond length is 1.09 Å. In the third H site, H(4,5,6) is bonded in a single-bond geometry to one C(4,5,6) atom. In the fourth H site, H(7,8,9) is bonded in a single-bond geometry to one C(10,11) atom. In the fifth H site, H(10,11) is bonded in a single-bond geometry to one C(13,14,15) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(13,14,15) atom. The H(12)-C(13,14,15) bond length is 1.09 Å. In the seventh H site, H(13,14,15) is bonded in a single-bond geometry to one C(19,20) atom. In the eighth H site, H(16,17,18) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(19,20,21) is bonded in a single-bond geometry to one C(31) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(37,38,39) atom. In the eleventh H site, H(23,24) is bonded in a single-bond geometry to one C(37,38,39) atom. The H(23,24)-C(37,38,39) bond length is 1.09 Å. In the twelfth H site, H(28,29,30) is bonded in a single-bond geometry to one C(43,44,45) atom. In the thirteenth H site, H(31,32,33) is bonded in a single-bond geometry to one C(46) atom. In the fourteenth H site, H(34) is bonded in a single-bond geometry to one C(49,50,51) atom. In the fifteenth H site, H(35,36) is bonded in a single-bond geometry to one C(49,50,51) atom. The H(35,36)-C(49,50,51) bond length is 1.09 Å. In the sixteenth H site, H(37,39) is bonded in a single-bond geometry to one C(55) atom. In the seventeenth H site, H(38) is bonded in a single-bond geometry to one C(56) atom. In the eighteenth H site, H(40) is bonded in a single-bond geometry to one C(58,60) atom. In the nineteenth H site, H(41) is bonded in a single-bond geometry to one C(59) atom. In the twentieth H site, H(42) is bonded in a single-bond geometry to one C(58,60) atom. The H(42)-C(58,60) bond length is 1.09 Å. In the twenty-first H site, H(43,45) is bonded in a single-bond geometry to one C(61) atom. In the twenty-second H site, H(44) is bonded in a single-bond geometry to one C(62) atom. In the twenty-third H site, H(46) is bonded in a single-bond geometry to one C(64,66) atom. In the twenty-fourth H site, H(47,48) is bonded in a single-bond geometry to one C(65) atom. In the twenty-fifth H site, H(49,51) is bonded in a single-bond geometry to one C(67) atom. In the twenty-sixth H site, H(50) is bonded in a single-bond geometry to one C(68) atom. In the twenty-seventh H site, H(52,54) is bonded in a single-bond geometry to one C(73,75) atom. In the twenty-eighth H site, H(53) is bonded in a single-bond geometry to one C(74) atom. In the twenty-ninth H site, H(55,56,57) is bonded in a single-bond geometry to one C(76,78) atom. In the thirtieth H site, H(58,60) is bonded in a single-bond geometry to one C(79,80,81) atom. In the thirty-first H site, H(59) is bonded in a single-bond geometry to one C(79,80,81) atom. The H(59)-C(79,80,81) bond length is 1.09 Å. In the thirty-second H site, H(61,62,63) is bonded in a single-bond geometry to one C(82,84) atom. In the thirty-third H site, H(64,66) is bonded in a single-bond geometry to one C(85,87) atom. In the thirty-fourth H site, H(65) is bonded in a single-bond geometry to one C(86) atom. In the thirty-fifth H site, H(67) is bonded in a single-bond geometry to one C(91) atom. In the thirty-sixth H site, H(68,69) is bonded in a single-bond geometry to one C(92,93) atom. In the thirty-seventh H site, H(70,71,72) is bonded in a single-bond geometry to one C(94) atom. In the thirty-eighth H site, H(73) is bonded in a single-bond geometry to one C(97) atom. In the thirty-ninth H site, H(74,75) is bonded in a single-bond geometry to one C(98,99) atom. In the fortieth H site, H(76) is bonded in a single-bond geometry to one C(100) atom. In the forty-first H site, H(77,78) is bonded in a single-bond geometry to one C(101,102) atom. In the forty-second H site, H(79,80,81) is bonded in a single-bond geometry to one C(103) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1,2) is bonded in a single-bond geometry to one Cu(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Cu(3) atom. Linkers: 6 c1ccc(P(c2ccccc2)c2cc(-c3ccncc3)cc(P(c3ccccc3)c3ccccc3)c2)cc1. Metal clusters: 6 [Cu]. The MOF has largest included sphere 6.46 A, density 1.00 g/cm3, surface area 5053.44 m2/g, accessible volume 0.50 cm3/g