CuC14H14(N5O3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CuC14H14(N5O3)2 clusters. Cu(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 2.03 Å. Both Cu(1)-N(3) bond lengths are 2.02 Å. Both Cu(1)-O(1) bond lengths are 2.46 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one N(4), and one H(1) atom. The C(1)-N(2) bond length is 1.44 Å. The C(1)-N(4) bond length is 1.44 Å. The C(1)-H(1) bond length is 1.11 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(4), and one H(2) atom. The C(2)-C(6) bond length is 1.39 Å. The C(2)-N(4) bond length is 1.36 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(2), and one H(3) atom. The C(3)-C(7) bond length is 1.38 Å. The C(3)-N(2) bond length is 1.36 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(4) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(3), and one H(5) atom. The C(5)-C(7) bond length is 1.40 Å. The C(5)-N(3) bond length is 1.35 Å. The C(5)-H(5) bond length is 1.08 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(2) and one H(6) atom. The C(6)-H(6) bond length is 1.08 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(7) atom. The C(7)-H(7) bond length is 1.08 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(4), and one N(4) atom. The N(1)-N(4) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(3) atom. The N(2)-N(3) bond length is 1.36 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(5), and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(1), one C(2), and one N(1) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(5)-O(1) bond length is 1.29 Å. The N(5)-O(2) bond length is 1.26 Å. The N(5)-O(3) bond length is 1.26 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cu(1) and one N(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(5) atom. Linkers: 1 c1cnn(C(C(n2cccn2)n2cccn2)n2cccn2)c1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.03 A, density 1.75 g/cm3, surface area 4009.49 m2/g, accessible volume 0.10 cm3/g