ZnC16H12(N3O4)2CH3CHO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dimethyl ether molecules and one ZnC16H12(N3O4)2 cluster. In the ZnC16H12(N3O4)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(3), one N(5), one O(2), and one O(6) atom. The Zn(1)-N(3) bond length is 2.01 Å. The Zn(1)-N(5) bond length is 2.01 Å. The Zn(1)-O(2) bond length is 1.99 Å. The Zn(1)-O(6) bond length is 2.00 Å. There are sixteen inequivalent C sites. In the first C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(6) and two equivalent H(3,4) atoms. The C(2)-N(6) bond length is 1.46 Å. There is one shorter (1.09 Å) and one longer (1.10 Å) C(2)-H(3,4) bond length. In the second C site, C(4) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(7) atom. The C(4)-N(5) bond length is 1.34 Å. The C(4)-N(6) bond length is 1.35 Å. The C(4)-H(7) bond length is 1.08 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(8) atom. The C(5)-N(3) bond length is 1.33 Å. The C(5)-N(4) bond length is 1.35 Å. The C(5)-H(8) bond length is 1.08 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(7) atom. The C(6)-C(11) bond length is 1.41 Å. The C(6)-C(12) bond length is 1.41 Å. The C(6)-C(7) bond length is 1.52 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.24 Å. The C(7)-O(2) bond length is 1.29 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(11), one C(18), and one H(9) atom. The C(8)-C(11) bond length is 1.40 Å. The C(8)-C(18) bond length is 1.39 Å. The C(8)-H(9) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(4) and two equivalent H(10,11) atoms. The C(9)-N(4) bond length is 1.46 Å. Both C(9)-H(10,11) bond lengths are 1.10 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(6), and one O(7) atom. The C(10)-C(11) bond length is 1.52 Å. The C(10)-O(6) bond length is 1.29 Å. The C(10)-O(7) bond length is 1.25 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(6), and one C(8) atom. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14), one C(6), and one N(1) atom. The C(12)-C(14) bond length is 1.39 Å. The C(12)-N(1) bond length is 1.47 Å. In the eleventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(4), and one H(12) atom. The C(13)-C(17) bond length is 1.37 Å. The C(13)-N(4) bond length is 1.38 Å. The C(13)-H(12) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(12), one C(18), and one H(13) atom. The C(14)-C(18) bond length is 1.39 Å. The C(14)-H(13) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(5), and one H(14) atom. The C(15)-C(16) bond length is 1.37 Å. The C(15)-N(5) bond length is 1.38 Å. The C(15)-H(14) bond length is 1.08 Å. In the fourteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(6), and one H(15) atom. The C(16)-N(6) bond length is 1.38 Å. The C(16)-H(15) bond length is 1.08 Å. In the fifteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(13), one N(3), and one H(16) atom. The C(17)-N(3) bond length is 1.38 Å. The C(17)-H(16) bond length is 1.08 Å. In the sixteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(14), one C(8), and one N(2) atom. The C(18)-N(2) bond length is 1.46 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(12), one O(3), and one O(4) atom. The N(1)-O(3) bond length is 1.24 Å. The N(1)-O(4) bond length is 1.24 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(18), one O(8), and one O(9) atom. The N(2)-O(8) bond length is 1.24 Å. The N(2)-O(9) bond length is 1.24 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(17), and one C(5) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(13), one C(5), and one C(9) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(16), one C(2), and one C(4) atom. There are ten inequivalent H sites. In the first H site, H(3,4) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(10,11) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(6) is bonded in a water-like geometry to one Zn(1) and one C(10) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one N(2) atom. In the eighth O site, O(9) is bonded in a single-bond geometry to one N(2) atom. Linkers: 2 [O]C(=O)c1cc([N+](=O)[O-])cc([N+](=O)[O-])c1C([O])=O ,2 c1cn(CCOCCn2ccnc2)cn1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.18 A, density 1.70 g/cm3, surface area 4560.20 m2/g, accessible volume 0.13 cm3/g