ZnC14H12(N3O2)2(CH2)2ZnC10N6H10O2Cl is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two ZnC10N6H10O2Cl clusters, and one ZnC14H12(N3O2)2 cluster. In each ZnC10N6H10O2Cl cluster, Zn(2) is bonded in a tetrahedral geometry to one N(12), one N(9), one O(5), and one Cl(1) atom. The Zn(2)-N(12) bond length is 2.04 Å. The Zn(2)-N(9) bond length is 2.07 Å. The Zn(2)-O(5) bond length is 1.97 Å. The Zn(2)-Cl(1) bond length is 2.21 Å. There are ten inequivalent C sites. In the first C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(7), one H(15), and one H(16) atom. The C(16)-N(7) bond length is 1.46 Å. The C(16)-H(15) bond length is 1.10 Å. The C(16)-H(16) bond length is 1.10 Å. In the second C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one N(10), one H(19), and one H(20) atom. The C(18)-N(10) bond length is 1.46 Å. The C(18)-H(19) bond length is 1.10 Å. The C(18)-H(20) bond length is 1.10 Å. In the third C site, C(19) is bonded in a trigonal planar geometry to one N(8), one N(9), and one H(21) atom. The C(19)-N(8) bond length is 1.33 Å. The C(19)-N(9) bond length is 1.37 Å. The C(19)-H(21) bond length is 1.09 Å. In the fourth C site, C(20) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(22) atom. The C(20)-N(7) bond length is 1.34 Å. The C(20)-N(9) bond length is 1.34 Å. The C(20)-H(22) bond length is 1.09 Å. In the fifth C site, C(21) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(23) atom. The C(21)-N(11) bond length is 1.33 Å. The C(21)-N(12) bond length is 1.37 Å. The C(21)-H(23) bond length is 1.09 Å. In the sixth C site, C(22) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(24) atom. The C(22)-N(10) bond length is 1.34 Å. The C(22)-N(12) bond length is 1.34 Å. The C(22)-H(24) bond length is 1.08 Å. In the seventh C site, C(23) is bonded in a trigonal planar geometry to one C(24), one C(25), and one C(26) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(25) bond length is 1.40 Å. The C(23)-C(26) bond length is 1.50 Å. In the eighth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(25) atom. The C(24)-H(25) bond length is 1.09 Å. In the ninth C site, C(25) is bonded in a distorted single-bond geometry to one C(23) and one H(26) atom. The C(25)-H(26) bond length is 1.09 Å. In the tenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(5), and one O(6) atom. The C(26)-O(5) bond length is 1.30 Å. The C(26)-O(6) bond length is 1.25 Å. There are six inequivalent N sites. In the first N site, N(11) is bonded in a distorted water-like geometry to one C(21) and one N(10) atom. The N(11)-N(10) bond length is 1.36 Å. In the second N site, N(12) is bonded in a trigonal planar geometry to one Zn(2), one C(21), and one C(22) atom. In the third N site, N(7) is bonded in a distorted trigonal planar geometry to one C(16), one C(20), and one N(8) atom. The N(7)-N(8) bond length is 1.37 Å. In the fourth N site, N(8) is bonded in a distorted water-like geometry to one C(19) and one N(7) atom. In the fifth N site, N(9) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(19), and one C(20) atom. In the sixth N site, N(10) is bonded in a distorted trigonal planar geometry to one C(18), one C(22), and one N(11) atom. There are ten inequivalent H sites. In the first H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the second H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the fourth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(21) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(22) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(23) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(24) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(25) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(26) is bonded in a single-bond geometry to one C(25) atom. There are two inequivalent O sites. In the first O site, O(5) is bonded in a water-like geometry to one Zn(2) and one C(26) atom. In the second O site, O(6) is bonded in a single-bond geometry to one C(26) atom. Cl(1) is bonded in a single-bond geometry to one Zn(2) atom. In the ZnC14H12(N3O2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(3), one N(6), one O(1), and one O(3) atom. The Zn(1)-N(3) bond length is 2.03 Å. The Zn(1)-N(6) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(3) bond length is 1.94 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(1)-N(1) bond length is 1.46 Å. The C(1)-H(1) bond length is 1.09 Å. The C(1)-H(2) bond length is 1.10 Å. In the second C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(5), and one H(6) atom. The C(3)-N(4) bond length is 1.46 Å. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(6) bond length is 1.10 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(7) atom. The C(4)-N(1) bond length is 1.34 Å. The C(4)-N(3) bond length is 1.34 Å. The C(4)-H(7) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(8) atom. The C(5)-N(2) bond length is 1.33 Å. The C(5)-N(3) bond length is 1.37 Å. The C(5)-H(8) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(9) atom. The C(6)-N(5) bond length is 1.33 Å. The C(6)-N(6) bond length is 1.37 Å. The C(6)-H(9) bond length is 1.08 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(10) atom. The C(7)-N(4) bond length is 1.34 Å. The C(7)-N(6) bond length is 1.34 Å. The C(7)-H(10) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(9) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-C(11) bond length is 1.50 Å. The C(8)-C(9) bond length is 1.40 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(11) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(11) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(8), one C(9), and one H(12) atom. The C(10)-H(12) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(1), and one O(2) atom. The C(11)-O(1) bond length is 1.29 Å. The C(11)-O(2) bond length is 1.26 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(15) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(14) bond length is 1.40 Å. The C(12)-C(15) bond length is 1.50 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(13) atom. The C(13)-H(13) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(14) atom. The C(14)-H(14) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(3), and one O(4) atom. The C(15)-O(3) bond length is 1.30 Å. The C(15)-O(4) bond length is 1.25 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(1), one C(4), and one N(2) atom. The N(1)-N(2) bond length is 1.37 Å. In the second N site, N(2) is bonded in a water-like geometry to one C(5) and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(4), and one C(5) atom. In the fourth N site, N(4) is bonded in a 2-coordinate geometry to one C(3), one C(7), and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(6) and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(1), one C(6), and one C(7) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(11) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(11) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(15) atom. Linkers: 2 c1ncn(CCCn2cncn2)n1 ,2 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.70 A, density 1.54 g/cm3, surface area 4689.57 m2/g, accessible volume 0.27 cm3/g