(CH)3CdC18N3H10SO4 crystallizes in the monoclinic P2/c space group. The structure consists of twelve 02329_fluka molecules inside a CdC18N3H10SO4 framework. In the CdC18N3H10SO4 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 6-coordinate geometry to two equivalent N(3), two equivalent O(1), and two equivalent O(2) atoms. Both Cd(1)-N(3) bond lengths are 2.33 Å. Both Cd(1)-O(1) bond lengths are 2.50 Å. Both Cd(1)-O(2) bond lengths are 2.30 Å. In the second Cd site, Cd(2) is bonded in a 6-coordinate geometry to two equivalent N(1), two equivalent O(3), and two equivalent O(4) atoms. Both Cd(2)-N(1) bond lengths are 2.33 Å. Both Cd(2)-O(3) bond lengths are 2.46 Å. Both Cd(2)-O(4) bond lengths are 2.31 Å. There are eighteen inequivalent C sites. In the first C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(19), and one C(20) atom. The C(19)-C(18) bond length is 1.41 Å. The C(19)-C(19) bond length is 1.49 Å. The C(19)-C(20) bond length is 1.41 Å. In the second C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(12) atom. The C(20)-H(12) bond length is 1.09 Å. In the third C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(13) atom. The C(21)-N(3) bond length is 1.35 Å. The C(21)-H(13) bond length is 1.09 Å. In the fourth C site, C(1) is bonded in a distorted water-like geometry to one C(2), one H(1), one H(2), and one S(1) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.82 Å. In the fifth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.40 Å. In the sixth C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the seventh C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(8) bond length is 1.50 Å. In the eighth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the ninth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-C(9) bond length is 1.49 Å. In the tenth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the eleventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(8)-O(1) bond length is 1.27 Å. The C(8)-O(2) bond length is 1.29 Å. In the twelfth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(3), and one O(4) atom. The C(9)-O(3) bond length is 1.27 Å. The C(9)-O(4) bond length is 1.28 Å. In the thirteenth C site, C(10) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. The C(10)-N(1) bond length is 1.39 Å. The C(10)-N(2) bond length is 1.35 Å. The C(10)-S(1) bond length is 1.70 Å. In the fourteenth C site, C(11) is bonded in a distorted single-bond geometry to one C(16) and one N(1) atom. The C(11)-C(16) bond length is 1.47 Å. The C(11)-N(1) bond length is 1.35 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(9) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(9) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(11), one C(15), and one N(2) atom. The C(16)-N(2) bond length is 1.36 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(3), and one H(10) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-N(3) bond length is 1.35 Å. The C(17)-H(10) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(11) atom. The C(18)-H(11) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(10), and one C(11) atom. In the second N site, N(2) is bonded in a water-like geometry to one C(10) and one C(16) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(17), and one C(21) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. S(1) is bonded in a water-like geometry to one C(1) and one C(10) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(8) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(8) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(9) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Cd(2) and one C(9) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1 ,4 [O]C(=O)c1cc(CSC2=Nc3ccccc3[N]2)cc(C([O])=O)c1. Metal clusters: 4 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 3.75 A, density 1.64 g/cm3, surface area 3871.83 m2/g, accessible volume 0.17 cm3/g