(CH2)2CHCH3SnC7NH11SO3 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, eight 02329_fluka molecules, four 02329_fluka molecules, and four SnC7NH11SO3 clusters. In each SnC7NH11SO3 cluster, Sn(1) is bonded in a distorted trigonal bipyramidal geometry to one C(10), one C(11), one S(1), one O(1), and one O(3) atom. The Sn(1)-C(10) bond length is 2.15 Å. The Sn(1)-C(11) bond length is 2.14 Å. The Sn(1)-S(1) bond length is 2.45 Å. The Sn(1)-O(1) bond length is 2.18 Å. The Sn(1)-O(3) bond length is 2.42 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one N(1) and one H(1) atom. The C(2)-N(1) bond length is 1.47 Å. The C(2)-H(1) bond length is 1.10 Å. In the third C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(6), and one H(7) atom. The C(5)-N(1) bond length is 1.47 Å. The C(5)-H(6) bond length is 1.10 Å. The C(5)-H(7) bond length is 1.10 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(3) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-O(3) bond length is 1.27 Å. In the fifth C site, C(8) is bonded in a distorted water-like geometry to one H(10), one H(9), and one S(1) atom. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. The C(8)-S(1) bond length is 1.82 Å. In the sixth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(14), one H(15), and one H(16) atom. The C(10)-H(14) bond length is 1.10 Å. The C(10)-H(15) bond length is 1.09 Å. The C(10)-H(16) bond length is 1.10 Å. In the seventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(17), one H(18), and one H(19) atom. The C(11)-H(17) bond length is 1.09 Å. The C(11)-H(18) bond length is 1.09 Å. The C(11)-H(19) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(6) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(11) atom. S(1) is bonded in a water-like geometry to one Sn(1) and one C(8) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Sn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sn(1) and one C(6) atom. Linkers: 4 C[C@H](C[S])C(=O)N1CCC[C@H]1C([O])=O. Metal clusters: 4 [CH2]S[Sn]([O])O[C]=O. The MOF has largest included sphere 2.72 A, density 1.64 g/cm3, surface area 4439.28 m2/g, accessible volume 0.18 cm3/g