Zn5C35N11H32O13CNH2C2NH7 crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of four dimethylamine molecules and four methylamine molecules inside a Zn5C35N11H32O13 framework. In the Zn5C35N11H32O13 framework, there are five inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(1), one N(7), one O(1), and one O(13) atom to form distorted ZnN2O2 tetrahedra that share  a cornercorner with one Zn(3)N3O tetrahedra and  a cornercorner with one Zn(2)N2O3 trigonal bipyramid. The Zn(1)-N(1) bond length is 2.02 Å. The Zn(1)-N(7) bond length is 1.99 Å. The Zn(1)-O(1) bond length is 1.94 Å. The Zn(1)-O(13) bond length is 2.04 Å. In the second Zn site, Zn(2) is bonded to one N(2), one N(4), one O(13), one O(5), and one O(6) atom to form ZnN2O3 trigonal bipyramids that share  a cornercorner with one Zn(1)N2O2 tetrahedra and  a cornercorner with one Zn(3)N3O tetrahedra. The Zn(2)-N(2) bond length is 2.03 Å. The Zn(2)-N(4) bond length is 2.01 Å. The Zn(2)-O(13) bond length is 2.10 Å. The Zn(2)-O(5) bond length is 2.07 Å. The Zn(2)-O(6) bond length is 2.24 Å. In the third Zn site, Zn(3) is bonded to one N(3), one N(5), one N(8), and one O(13) atom to form ZnN3O tetrahedra that share  a cornercorner with one Zn(1)N2O2 tetrahedra and  a cornercorner with one Zn(2)N2O3 trigonal bipyramid. The Zn(3)-N(3) bond length is 1.95 Å. The Zn(3)-N(5) bond length is 1.98 Å. The Zn(3)-N(8) bond length is 1.97 Å. The Zn(3)-O(13) bond length is 2.00 Å. In the fourth Zn site, Zn(4) is bonded in a square pyramidal geometry to one N(6), one O(12), one O(3), one O(8), and one O(9) atom. The Zn(4)-N(6) bond length is 2.04 Å. The Zn(4)-O(12) bond length is 2.05 Å. The Zn(4)-O(3) bond length is 2.07 Å. The Zn(4)-O(8) bond length is 2.10 Å. The Zn(4)-O(9) bond length is 2.08 Å. In the fifth Zn site, Zn(5) is bonded in a square pyramidal geometry to one N(9), one O(10), one O(11), one O(4), and one O(7) atom. The Zn(5)-N(9) bond length is 2.03 Å. The Zn(5)-O(10) bond length is 2.07 Å. The Zn(5)-O(11) bond length is 2.08 Å. The Zn(5)-O(4) bond length is 2.08 Å. The Zn(5)-O(7) bond length is 2.09 Å. There are thirty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one H(1), one H(2), and one H(3) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one N(3) atom. The C(2)-N(1) bond length is 1.33 Å. The C(2)-N(3) bond length is 1.36 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one N(3) atom. The C(3)-C(4) bond length is 1.48 Å. The C(3)-N(2) bond length is 1.33 Å. The C(3)-N(3) bond length is 1.36 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one H(4), one H(5), and one H(6) atom. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. The C(4)-H(6) bond length is 1.09 Å. In the fifth C site, C(5,8) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one H(7), one H(8), and one H(9) atom. The C(5,8)-C(6) bond length is 1.48 Å. The C(5,8)-H(7) bond length is 1.10 Å. The C(5,8)-H(8) bond length is 1.10 Å. The C(5,8)-H(9) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5,8); one N(4); and one N(6) atom. The C(6)-N(4) bond length is 1.34 Å. The C(6)-N(6) bond length is 1.36 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5,8); one N(5); and one N(6) atom. The C(7)-C(5,8) bond length is 1.48 Å. The C(7)-N(5) bond length is 1.33 Å. The C(7)-N(6) bond length is 1.35 Å. In the eighth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one H(13), one H(14), and one H(15) atom. The C(9)-C(10) bond length is 1.48 Å. The C(9)-H(13) bond length is 1.10 Å. The C(9)-H(14) bond length is 1.10 Å. The C(9)-H(15) bond length is 1.10 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(9), one N(7), and one N(9) atom. The C(10)-N(7) bond length is 1.34 Å. The C(10)-N(9) bond length is 1.36 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(8), and one N(9) atom. The C(11)-C(12) bond length is 1.48 Å. The C(11)-N(8) bond length is 1.34 Å. The C(11)-N(9) bond length is 1.35 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one H(16), one H(17), and one H(18) atom. The C(12)-H(16) bond length is 1.10 Å. The C(12)-H(17) bond length is 1.10 Å. The C(12)-H(18) bond length is 1.10 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(1), and one O(2) atom. The C(13)-C(14) bond length is 1.49 Å. The C(13)-O(1) bond length is 1.31 Å. The C(13)-O(2) bond length is 1.26 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(20) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(20) bond length is 1.40 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(19) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(19) bond length is 1.09 Å. In the fifteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. The C(16)-C(17) bond length is 1.50 Å. The C(16)-C(18) bond length is 1.40 Å. In the sixteenth C site, C(17) is bonded in a bent 120 degrees geometry to one C(16), one O(3), and one O(4) atom. The C(17)-O(3) bond length is 1.27 Å. The C(17)-O(4) bond length is 1.28 Å. In the seventeenth C site, C(18) is bonded in a distorted single-bond geometry to one C(16) and one H(20) atom. The C(18)-H(20) bond length is 1.09 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(14) and one H(21) atom. The C(20)-H(21) bond length is 1.09 Å. In the nineteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(5), and one O(6) atom. The C(21)-C(22) bond length is 1.49 Å. The C(21)-O(5) bond length is 1.29 Å. The C(21)-O(6) bond length is 1.28 Å. In the twentieth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(28) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(28) bond length is 1.40 Å. In the twenty-first C site, C(23) is bonded in a distorted single-bond geometry to one C(22), one C(24), and one H(22) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-H(22) bond length is 1.09 Å. In the twenty-second C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(26) atom. The C(24)-C(25) bond length is 1.51 Å. The C(24)-C(26) bond length is 1.40 Å. In the twenty-third C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(7), and one O(8) atom. The C(25)-O(7) bond length is 1.27 Å. The C(25)-O(8) bond length is 1.27 Å. In the twenty-fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(24), one C(27), and one H(23) atom. The C(26)-C(27) bond length is 1.41 Å. The C(26)-H(23) bond length is 1.09 Å. In the twenty-fifth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(26), one C(28), and one N(11) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-N(11) bond length is 1.39 Å. In the twenty-sixth C site, C(28) is bonded in a distorted single-bond geometry to one C(22), one C(27), and one H(24) atom. The C(28)-H(24) bond length is 1.09 Å. In the twenty-seventh C site, C(29) is bonded in a bent 120 degrees geometry to one C(30), one O(10), and one O(9) atom. The C(29)-C(30) bond length is 1.50 Å. The C(29)-O(10) bond length is 1.28 Å. The C(29)-O(9) bond length is 1.27 Å. In the twenty-eighth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(36) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-C(36) bond length is 1.40 Å. In the twenty-ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(30), one C(32), and one H(25) atom. The C(31)-C(32) bond length is 1.40 Å. The C(31)-H(25) bond length is 1.09 Å. In the thirtieth C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(34) atom. The C(32)-C(33) bond length is 1.50 Å. The C(32)-C(34) bond length is 1.40 Å. In the thirty-first C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(11), and one O(12) atom. The C(33)-O(11) bond length is 1.27 Å. The C(33)-O(12) bond length is 1.28 Å. In the thirty-second C site, C(34) is bonded in a distorted single-bond geometry to one C(32), one C(35), and one H(26) atom. The C(34)-C(35) bond length is 1.40 Å. The C(34)-H(26) bond length is 1.09 Å. In the thirty-third C site, C(35) is bonded in a trigonal planar geometry to one C(34), one C(36), and one N(12) atom. The C(35)-C(36) bond length is 1.40 Å. The C(35)-N(12) bond length is 1.39 Å. In the thirty-fourth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(30), one C(35), and one H(27) atom. The C(36)-H(27) bond length is 1.09 Å. There are eleven inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one Zn(2) and one C(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(3), one C(2), and one C(3) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one Zn(2), one C(6), and one N(5) atom. The N(4)-N(5) bond length is 1.38 Å. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one Zn(3), one C(7), and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(4), one C(6), and one C(7) atom. In the seventh N site, N(7) is bonded in a 3-coordinate geometry to one Zn(1), one C(10), and one N(8) atom. The N(7)-N(8) bond length is 1.38 Å. In the eighth N site, N(8) is bonded in a 3-coordinate geometry to one Zn(3), one C(11), and one N(7) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Zn(5), one C(10), and one C(11) atom. In the tenth N site, N(11) is bonded in a distorted trigonal non-coplanar geometry to one C(27), one H(30), and one H(31) atom. The N(11)-H(30) bond length is 1.01 Å. The N(11)-H(31) bond length is 1.01 Å. In the eleventh N site, N(12) is bonded in a distorted trigonal non-coplanar geometry to one C(35) and two equivalent H(32,33) atoms. Both N(12)-H(32,33) bond lengths are 1.01 Å. There are thirty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5,8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5,8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5,8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5,8) atom. The H(10)-C(5,8) bond length is 1.10 Å. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(5,8) atom. The H(11)-C(5,8) bond length is 1.10 Å. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(5,8) atom. The H(12)-C(5,8) bond length is 1.10 Å. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(9) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(9) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(12) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(12) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(15) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(20) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(23) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(26) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(28) atom. In the twenty-fifth H site, H(25) is bonded in a single-bond geometry to one C(31) atom. In the twenty-sixth H site, H(26) is bonded in a single-bond geometry to one C(34) atom. In the twenty-seventh H site, H(27) is bonded in a single-bond geometry to one C(36) atom. In the twenty-eighth H site, H(30) is bonded in a single-bond geometry to one N(11) atom. In the twenty-ninth H site, H(31) is bonded in a single-bond geometry to one N(11) atom. In the thirtieth H site, H(32,33) is bonded in a single-bond geometry to one N(12) atom. In the thirty-first H site, H(34) is bonded in a single-bond geometry to one O(13) atom. The H(34)-O(13) bond length is 0.98 Å. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(13) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(13) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(17) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(17) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Zn(2) and one C(21) atom. In the sixth O site, O(6) is bonded in an L-shaped geometry to one Zn(2) and one C(21) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(25) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(25) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(29) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(29) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(33) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(33) atom. In the thirteenth O site, O(13) is bonded in a distorted tetrahedral geometry to one Zn(1), one Zn(2), one Zn(3), and one H(34) atom. Linkers: 8 CC1=NN=C(C)[N]1 ,12 Nc1cc(C([O])=O)cc(C([O])=O)c1 ,4 CC1=[N]=C(N=N1)C. Metal clusters: 4 O=[C]O[Zn]1/N=N\[Zn](O)/N=N\[Zn]2(/N=N\1)O[C]O2 ,4 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 6.10 A, density 1.07 g/cm3, surface area 4419.17 m2/g, accessible volume 0.51 cm3/g