(CH2)12(CH3)6CHSn3C26H20(NO4)3 crystallizes in the monoclinic Cc space group. The structure consists of four 02329_fluka molecules, forty-eight 02329_fluka molecules, and twenty-four 02329_fluka molecules inside a Sn3C26H20(NO4)3 framework. In the Sn3C26H20(NO4)3 framework, there are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a pentagonal bipyramidal geometry to one C(12), one C(8), one N(1), one O(1), one O(11), one O(12), and one O(6) atom. The Sn(1)-C(12) bond length is 2.15 Å. The Sn(1)-C(8) bond length is 2.15 Å. The Sn(1)-N(1) bond length is 2.46 Å. The Sn(1)-O(1) bond length is 2.30 Å. The Sn(1)-O(11) bond length is 2.36 Å. The Sn(1)-O(12) bond length is 2.56 Å. The Sn(1)-O(6) bond length is 2.27 Å. In the second Sn site, Sn(2) is bonded in a pentagonal bipyramidal geometry to one C(23), one C(27), one N(2), one O(10), one O(3), one O(4), and one O(5) atom. The Sn(2)-C(23) bond length is 2.16 Å. The Sn(2)-C(27) bond length is 2.16 Å. The Sn(2)-N(2) bond length is 2.45 Å. The Sn(2)-O(10) bond length is 2.29 Å. The Sn(2)-O(3) bond length is 2.47 Å. The Sn(2)-O(4) bond length is 2.45 Å. The Sn(2)-O(5) bond length is 2.28 Å. In the third Sn site, Sn(3) is bonded in a pentagonal bipyramidal geometry to one C(38), one C(42), one N(3), one O(2), one O(7), one O(8), and one O(9) atom. The Sn(3)-C(38) bond length is 2.17 Å. The Sn(3)-C(42) bond length is 2.14 Å. The Sn(3)-N(3) bond length is 2.44 Å. The Sn(3)-O(2) bond length is 2.35 Å. The Sn(3)-O(7) bond length is 2.41 Å. The Sn(3)-O(8) bond length is 2.50 Å. The Sn(3)-O(9) bond length is 2.30 Å. There are twenty-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.50 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.51 Å. The C(5)-N(1) bond length is 1.35 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.27 Å. The C(6)-O(2) bond length is 1.27 Å. In the seventh C site, C(7) is bonded in a bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(7)-O(3) bond length is 1.27 Å. The C(7)-O(4) bond length is 1.28 Å. In the eighth C site, C(8) is bonded in a distorted water-like geometry to one Sn(1), one H(4), and one H(5) atom. The C(8)-H(4) bond length is 1.10 Å. The C(8)-H(5) bond length is 1.10 Å. In the ninth C site, C(12) is bonded in a distorted water-like geometry to one Sn(1), one H(13), and one H(14) atom. The C(12)-H(13) bond length is 1.10 Å. The C(12)-H(14) bond length is 1.10 Å. In the tenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one N(2), and one H(22) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-N(2) bond length is 1.34 Å. The C(16)-H(22) bond length is 1.09 Å. In the eleventh C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(22) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(22) bond length is 1.50 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(23) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(23) bond length is 1.09 Å. In the thirteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(24) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-H(24) bond length is 1.09 Å. In the fourteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one N(2) atom. The C(20)-N(2) bond length is 1.35 Å. In the fifteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(21)-O(5) bond length is 1.27 Å. The C(21)-O(6) bond length is 1.27 Å. In the sixteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(7), and one O(8) atom. The C(22)-O(7) bond length is 1.28 Å. The C(22)-O(8) bond length is 1.27 Å. In the seventeenth C site, C(23) is bonded in a distorted water-like geometry to one Sn(2), one H(25), and one H(26) atom. The C(23)-H(25) bond length is 1.10 Å. The C(23)-H(26) bond length is 1.10 Å. In the eighteenth C site, C(27) is bonded in a distorted water-like geometry to one Sn(2), one H(34), and one H(35) atom. The C(27)-H(34) bond length is 1.10 Å. The C(27)-H(35) bond length is 1.10 Å. In the nineteenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(32), one N(3), and one H(43) atom. The C(31)-C(32) bond length is 1.40 Å. The C(31)-N(3) bond length is 1.34 Å. The C(31)-H(43) bond length is 1.09 Å. In the twentieth C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(37) atom. The C(32)-C(33) bond length is 1.40 Å. The C(32)-C(37) bond length is 1.50 Å. In the twenty-first C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(44) atom. The C(33)-H(44) bond length is 1.09 Å. In the twenty-second C site, C(35) is bonded in a distorted single-bond geometry to one N(3) atom. The C(35)-N(3) bond length is 1.35 Å. In the twenty-third C site, C(36) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(36)-O(10) bond length is 1.27 Å. The C(36)-O(9) bond length is 1.27 Å. In the twenty-fourth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(11), and one O(12) atom. The C(37)-O(11) bond length is 1.28 Å. The C(37)-O(12) bond length is 1.27 Å. In the twenty-fifth C site, C(38) is bonded in a distorted water-like geometry to one Sn(3), one H(46), and one H(47) atom. The C(38)-H(46) bond length is 1.10 Å. The C(38)-H(47) bond length is 1.10 Å. In the twenty-sixth C site, C(42) is bonded in a distorted water-like geometry to one Sn(3), one H(55), and one H(56) atom. The C(42)-H(55) bond length is 1.10 Å. The C(42)-H(56) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Sn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Sn(2), one C(16), and one C(20) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Sn(3), one C(31), and one C(35) atom. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(22) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(23) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(24) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(25) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(26) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(34) is bonded in a single-bond geometry to one C(27) atom. In the fourteenth H site, H(35) is bonded in a single-bond geometry to one C(27) atom. In the fifteenth H site, H(43) is bonded in a single-bond geometry to one C(31) atom. In the sixteenth H site, H(44) is bonded in a single-bond geometry to one C(33) atom. In the seventeenth H site, H(46) is bonded in a single-bond geometry to one C(38) atom. In the eighteenth H site, H(47) is bonded in a single-bond geometry to one C(38) atom. In the nineteenth H site, H(55) is bonded in a single-bond geometry to one C(42) atom. In the twentieth H site, H(56) is bonded in a single-bond geometry to one C(42) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sn(1) and one C(6) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Sn(3) and one C(6) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sn(2) and one C(7) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Sn(2) and one C(7) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Sn(2) and one C(21) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Sn(1) and one C(21) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Sn(3) and one C(22) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Sn(3) and one C(22) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Sn(3) and one C(36) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Sn(2) and one C(36) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Sn(1) and one C(37) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Sn(1) and one C(37) atom. Linkers: 6 [O]C(=O)c1ccc(C([O])=O)nc1. Metal clusters: 6 [Sn]. The MOF has largest included sphere 4.66 A, density 1.41 g/cm3, surface area 4565.50 m2/g, accessible volume 0.23 cm3/g