ReAgC4H10(NO2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ReAgC4H10(NO2)2 clusters. Re(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Re(1)-O(1) bond length is 1.76 Å. The Re(1)-O(2) bond length is 1.76 Å. The Re(1)-O(3) bond length is 1.76 Å. The Re(1)-O(4) bond length is 1.75 Å. Ag(1) is bonded in a T-shaped geometry to one N(1), one N(2), and one O(3) atom. The Ag(1)-N(1) bond length is 2.16 Å. The Ag(1)-N(2) bond length is 2.16 Å. The Ag(1)-O(3) bond length is 2.68 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(3), and one H(4) atom. The C(1)-N(1) bond length is 1.48 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-H(4) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(5), and one H(6) atom. The C(2)-N(2) bond length is 1.48 Å. The C(2)-H(5) bond length is 1.10 Å. The C(2)-H(6) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(7), and one H(8) atom. The C(3)-N(1) bond length is 1.48 Å. The C(3)-H(7) bond length is 1.10 Å. The C(3)-H(8) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(10), and one H(9) atom. The C(4)-N(2) bond length is 1.48 Å. The C(4)-H(10) bond length is 1.10 Å. The C(4)-H(9) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted tetrahedral geometry to one Ag(1), one C(1), one C(3), and one H(1) atom. The N(1)-H(1) bond length is 1.03 Å. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Ag(1), one C(2), one C(4), and one H(2) atom. The N(2)-H(2) bond length is 1.03 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Re(1) and one Ag(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Re(1) atom. Linkers: 3 C1CNCCN1. Metal clusters: 2 [Re] ,2 [Ag] ,2 [NH][Ag][NH].[O][Re]([O])([O])[O]. The MOF has largest included sphere 1.42 A, density 3.44 g/cm3, surface area 2304.59 m2/g, accessible volume 0.05 cm3/g