Mn2C8H10O13 crystallizes in the triclinic P1 space group. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted octahedral geometry to one O(15), one O(17), one O(24), one O(25), one O(3), and one O(5) atom. The Mn(1)-O(15) bond length is 2.13 Å. The Mn(1)-O(17) bond length is 2.35 Å. The Mn(1)-O(24) bond length is 2.10 Å. The Mn(1)-O(25) bond length is 2.07 Å. The Mn(1)-O(3) bond length is 2.15 Å. The Mn(1)-O(5) bond length is 2.32 Å. In the second Mn site, Mn(2) is bonded in a distorted octahedral geometry to one O(16), one O(18), one O(23), one O(26), one O(4), and one O(6) atom. The Mn(2)-O(16) bond length is 2.13 Å. The Mn(2)-O(18) bond length is 2.34 Å. The Mn(2)-O(23) bond length is 2.10 Å. The Mn(2)-O(26) bond length is 2.07 Å. The Mn(2)-O(4) bond length is 2.15 Å. The Mn(2)-O(6) bond length is 2.33 Å. In the third Mn site, Mn(3) is bonded in a distorted octahedral geometry to one O(14), one O(19), one O(2), one O(21), one O(7), and one O(9) atom. The Mn(3)-O(14) bond length is 2.15 Å. The Mn(3)-O(19) bond length is 2.29 Å. The Mn(3)-O(2) bond length is 2.14 Å. The Mn(3)-O(21) bond length is 2.20 Å. The Mn(3)-O(7) bond length is 2.29 Å. The Mn(3)-O(9) bond length is 2.13 Å. In the fourth Mn site, Mn(4) is bonded in a distorted octahedral geometry to one O(1), one O(10), one O(13), one O(20), one O(22), and one O(8) atom. The Mn(4)-O(1) bond length is 2.14 Å. The Mn(4)-O(10) bond length is 2.13 Å. The Mn(4)-O(13) bond length is 2.14 Å. The Mn(4)-O(20) bond length is 2.29 Å. The Mn(4)-O(22) bond length is 2.20 Å. The Mn(4)-O(8) bond length is 2.29 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(2)-O(2) bond length is 1.28 Å. The C(2)-O(4) bond length is 1.26 Å. In the third C site, C(3,4) is bonded in a distorted water-like geometry to one H(9) and one O(5) atom. The C(3,4)-H(9) bond length is 1.10 Å. The C(3,4)-O(5) bond length is 1.44 Å. In the fourth C site, C(5,6) is bonded in a distorted water-like geometry to one H(11) and one O(7) atom. The C(5,6)-H(11) bond length is 1.10 Å. The C(5,6)-O(7) bond length is 1.44 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(9) atom. The C(7)-O(11) bond length is 1.26 Å. The C(7)-O(9) bond length is 1.28 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(12) atom. The C(8)-O(10) bond length is 1.28 Å. The C(8)-O(12) bond length is 1.26 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(15) atom. The C(9)-O(13) bond length is 1.26 Å. The C(9)-O(15) bond length is 1.28 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(14) and one O(16) atom. The C(10)-O(14) bond length is 1.26 Å. The C(10)-O(16) bond length is 1.28 Å. In the ninth C site, C(11) is bonded in a distorted water-like geometry to one H(13) and one O(17) atom. The C(11)-H(13) bond length is 1.10 Å. The C(11)-O(17) bond length is 1.44 Å. In the tenth C site, C(12) is bonded in a distorted water-like geometry to one H(14) and one O(18) atom. The C(12)-H(14) bond length is 1.10 Å. The C(12)-O(18) bond length is 1.44 Å. In the eleventh C site, C(13) is bonded in a distorted water-like geometry to one H(15,16) and one O(19) atom. The C(13)-H(15,16) bond length is 1.10 Å. The C(13)-O(19) bond length is 1.43 Å. In the twelfth C site, C(14) is bonded in a distorted water-like geometry to one H(15,16) and one O(20) atom. The C(14)-H(15,16) bond length is 1.10 Å. The C(14)-O(20) bond length is 1.43 Å. In the thirteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(21) and one O(23) atom. The C(15)-O(21) bond length is 1.28 Å. The C(15)-O(23) bond length is 1.26 Å. In the fourteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one O(22) and one O(24) atom. The C(16)-O(22) bond length is 1.28 Å. The C(16)-O(24) bond length is 1.26 Å. There are eighteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one O(5) atom. The H(1,2)-O(5) bond length is 0.99 Å. In the second H site, H(3) is bonded in a single-bond geometry to one O(7) atom. The H(3)-O(7) bond length is 0.98 Å. In the third H site, H(4) is bonded in a single-bond geometry to one O(8) atom. The H(4)-O(8) bond length is 0.98 Å. In the fourth H site, H(5) is bonded in a single-bond geometry to one O(17) atom. The H(5)-O(17) bond length is 1.01 Å. In the fifth H site, H(6) is bonded in a single-bond geometry to one O(18) atom. The H(6)-O(18) bond length is 1.01 Å. In the sixth H site, H(7) is bonded in a distorted single-bond geometry to one O(16) and one O(19) atom. The H(7)-O(16) bond length is 1.67 Å. The H(7)-O(19) bond length is 1.00 Å. In the seventh H site, H(8) is bonded in a distorted single-bond geometry to one O(15) and one O(20) atom. The H(8)-O(15) bond length is 1.67 Å. The H(8)-O(20) bond length is 1.00 Å. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(3,4) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(3,4) atom. The H(10)-C(3,4) bond length is 1.10 Å. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(5,6) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(5,6) atom. The H(12)-C(5,6) bond length is 1.10 Å. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the fourteenth H site, H(15,16) is bonded in a single-bond geometry to one C(13) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one O(2) and one O(25) atom. The H(17)-O(2) bond length is 1.73 Å. The H(17)-O(25) bond length is 0.99 Å. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one O(1) and one O(26) atom. The H(18)-O(1) bond length is 1.73 Å. The H(18)-O(26) bond length is 0.99 Å. In the seventeenth H site, H(19) is bonded in a linear geometry to one O(12) and one O(25) atom. The H(19)-O(12) bond length is 1.51 Å. The H(19)-O(25) bond length is 1.01 Å. In the eighteenth H site, H(20) is bonded in a linear geometry to one O(11) and one O(26) atom. The H(20)-O(11) bond length is 1.51 Å. The H(20)-O(26) bond length is 1.01 Å. There are twenty-six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mn(4), one C(1), and one H(18) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mn(3), one C(2), and one H(17) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1); one C(3,4); and one H(1,2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2); one C(3,4); and one H(1,2) atom. The O(6)-C(3,4) bond length is 1.44 Å. The O(6)-H(1,2) bond length is 0.99 Å. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Mn(3); one C(5,6); and one H(3) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Mn(4); one C(5,6); and one H(4) atom. The O(8)-C(5,6) bond length is 1.44 Å. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(7) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Mn(4) and one C(8) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one C(7) and one H(20) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one C(8) and one H(19) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Mn(4) and one C(9) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Mn(3) and one C(10) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(9), and one H(8) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Mn(2), one C(10), and one H(7) atom. In the seventeenth O site, O(17) is bonded in a distorted water-like geometry to one Mn(1), one C(11), and one H(5) atom. In the eighteenth O site, O(18) is bonded in a distorted water-like geometry to one Mn(2), one C(12), and one H(6) atom. In the nineteenth O site, O(19) is bonded in a distorted water-like geometry to one Mn(3), one C(13), and one H(7) atom. In the twentieth O site, O(20) is bonded in a distorted water-like geometry to one Mn(4), one C(14), and one H(8) atom. In the twenty-first O site, O(21) is bonded in a 2-coordinate geometry to one Mn(3) and one C(15) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Mn(4) and one C(16) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(15) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(16) atom. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one H(17), and one H(19) atom. In the twenty-sixth O site, O(26) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one H(18), and one H(20) atom. Linkers: 4 [O]C(=O)[C@H](O)[C@@H](O)C([O])=O. Metal clusters: 4 [Mn]. The MOF has largest included sphere 3.52 A, density 1.96 g/cm3, surface area 2715.10 m2/g, accessible volume 0.13 cm3/g