ZnC4H8(NO2)2(CH)12(C2NH2O)2(CHO)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two isobutylene molecules, two methanol molecules, two n-methylformamide molecules, and one ZnC4H8(NO2)2 cluster. In the ZnC4H8(NO2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Zn(1)-N(1) bond length is 2.07 Å. The Zn(1)-N(2) bond length is 2.07 Å. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.04 Å. There are four inequivalent C sites. In the first C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(1); one H(11,12); and one H(9,10) atom. The C(7)-N(1) bond length is 1.47 Å. The C(7)-H(11,12) bond length is 1.10 Å. The C(7)-H(9,10) bond length is 1.10 Å. In the second C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2); one H(11,12); and one H(9,10) atom. The C(8)-N(2) bond length is 1.47 Å. The C(8)-H(11,12) bond length is 1.10 Å. The C(8)-H(9,10) bond length is 1.10 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3,4) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(3,4) bond length is 1.26 Å. In the fourth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3,4) atom. The C(2)-O(2) bond length is 1.29 Å. The C(2)-O(3,4) bond length is 1.26 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Zn(1), one C(7), one H(3), and one H(5) atom to form distorted corner-sharing NZnH2C tetrahedra. The N(1)-H(3) bond length is 1.03 Å. The N(1)-H(5) bond length is 1.03 Å. In the second N site, N(2) is bonded to one Zn(1), one C(8), one H(4), and one H(6) atom to form distorted corner-sharing NZnH2C tetrahedra. The N(2)-H(4) bond length is 1.03 Å. The N(2)-H(6) bond length is 1.03 Å. There are six inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(7) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(2) atom. In the third O site, O(3,4) is bonded in a distorted single-bond geometry to one C(1) atom. Linkers: 1 NCC(=O)N[C@@H](Cc1ccc(O)cc1)C([O])=O. Metal clusters: 1 [Zn]. The MOF has largest included sphere 1.96 A, density 1.63 g/cm3, surface area 4409.02 m2/g, accessible volume 0.13 cm3/g