CoC12H8(NO2)2C5H8(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two neopentane molecules, and one CoC12H8(NO2)2 cluster. In the CoC12H8(NO2)2 cluster, Co(1) is bonded in an octahedral geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Co(1)-N(1) bond length is 2.08 Å. The Co(1)-N(2) bond length is 2.07 Å. The Co(1)-O(1) bond length is 2.05 Å. The Co(1)-O(2) bond length is 1.98 Å. The Co(1)-O(3) bond length is 2.18 Å. The Co(1)-O(4) bond length is 2.24 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(6) atom. The C(3)-C(5) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.47 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(8) atom. The C(6)-C(7) bond length is 1.41 Å. The C(6)-C(8) bond length is 1.41 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(9), and one H(5) atom. The C(7)-C(9) bond length is 1.39 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(10), one C(6), and one H(6) atom. The C(8)-C(10) bond length is 1.39 Å. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(7), one N(2), and one H(7) atom. The C(9)-N(2) bond length is 1.35 Å. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(11)-O(1) bond length is 1.27 Å. The C(11)-O(2) bond length is 1.27 Å. In the twelfth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(19)-O(3) bond length is 1.28 Å. The C(19)-O(4) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(10), and one C(9) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(11) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Co(1) and one C(11) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Co(1) and one C(19) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Co(1) and one C(19) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1 ,2 [O]C(=O)CC1(CC([O])=O)CCCC1. Metal clusters: 1 [C]1O[Co]2(O1)O[C]O[Co]1(O[C]O1)O[C]O2. The MOF has largest included sphere 1.91 A, density 1.58 g/cm3, surface area 4287.74 m2/g, accessible volume 0.13 cm3/g