AgSiC12N3H14O2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four AgSiC12N3H14O2 clusters. Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(4), one O(1), and one O(3) atom. The Ag(1)-N(1) bond length is 2.22 Å. The Ag(1)-N(4) bond length is 2.26 Å. The Ag(1)-O(1) bond length is 2.47 Å. The Ag(1)-O(3) bond length is 2.71 Å. Si(1) is bonded in a tetrahedral geometry to one C(15); one C(21,22); one C(23); and one C(5,6) atom. The Si(1)-C(15) bond length is 1.89 Å. The Si(1)-C(21,22) bond length is 1.87 Å. The Si(1)-C(23) bond length is 1.86 Å. The Si(1)-C(5,6) bond length is 1.89 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3); one N(1); and one H(1,2) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1,2) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(1); one C(5,6); and one H(3,4) atom. The C(3)-C(5,6) bond length is 1.40 Å. The C(3)-H(3,4) bond length is 1.09 Å. In the third C site, C(5,6) is bonded in a trigonal planar geometry to one Si(1), one C(3), and one C(7) atom. The C(5,6)-C(7) bond length is 1.40 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(5,6) and one H(5,6) atom. The C(7)-H(5,6) bond length is 1.09 Å. In the fifth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(7,8) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(7,8) bond length is 1.09 Å. In the sixth C site, C(11,12) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9,10) atom. The C(11,12)-N(3) bond length is 1.35 Å. The C(11,12)-H(9,10) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(15) and one H(11,12) atom. The C(13)-C(15) bond length is 1.40 Å. The C(13)-H(11,12) bond length is 1.09 Å. In the eighth C site, C(15) is bonded in a trigonal planar geometry to one Si(1), one C(13), and one C(17) atom. The C(15)-C(17) bond length is 1.41 Å. In the ninth C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one H(13,14) atom. The C(17)-H(13,14) bond length is 1.09 Å. In the tenth C site, C(19,20) is bonded in a distorted trigonal planar geometry to one N(3) and one H(15,16) atom. The C(19,20)-N(3) bond length is 1.35 Å. The C(19,20)-H(15,16) bond length is 1.09 Å. In the eleventh C site, C(21,22) is bonded to one Si(1), one H(17), one H(19), and one H(21) atom to form corner-sharing CSiH3 tetrahedra. The C(21,22)-H(17) bond length is 1.10 Å. The C(21,22)-H(19) bond length is 1.10 Å. The C(21,22)-H(21) bond length is 1.10 Å. In the twelfth C site, C(23) is bonded to one Si(1), one H(23), one H(25), and one H(27) atom to form corner-sharing CSiH3 tetrahedra. The C(23)-H(23) bond length is 1.10 Å. The C(23)-H(25) bond length is 1.10 Å. The C(23)-H(27) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(9) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Ag(1); one C(11,12); and one C(19,20) atom. The N(4)-C(11,12) bond length is 1.35 Å. The N(4)-C(19,20) bond length is 1.35 Å. In the third N site, N(5) is bonded in a bent 120 degrees geometry to one O(1) and one O(3) atom. The N(5)-O(1) bond length is 1.28 Å. The N(5)-O(3) bond length is 1.26 Å. There are fourteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(11,12) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(13,14) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(15,16) is bonded in a single-bond geometry to one C(19,20) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(21,22) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(21,22) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(21,22) atom. In the twelfth H site, H(23) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(25) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(27) is bonded in a single-bond geometry to one C(23) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Ag(1) and one N(5) atom. In the second O site, O(1) is bonded in a distorted water-like geometry to one Ag(1) and one N(5) atom. Linkers: 4 C[Si](C)(c1ccncc1)c1ccncc1. Metal clusters: 2 [O][N]O[Ag][Ag]O[N][O]. The MOF has largest included sphere 2.05 A, density 1.72 g/cm3, surface area 4453.38 m2/g, accessible volume 0.16 cm3/g