NiC12H14(NO3)2(CH2)2(CH)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four 02329_fluka molecules, and two NiC12H14(NO3)2 clusters. In each NiC12H14(NO3)2 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(3) atoms. Both Ni(1)-N(1) bond lengths are 2.05 Å. Both Ni(1)-O(1) bond lengths are 2.07 Å. Both Ni(1)-O(3) bond lengths are 2.14 Å. There are six inequivalent C sites. In the first C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one H(13), one H(15), and one O(3) atom. The C(11)-H(13) bond length is 1.10 Å. The C(11)-H(15) bond length is 1.10 Å. The C(11)-O(3) bond length is 1.44 Å. In the second C site, C(7) is bonded in a distorted water-like geometry to one C(9), one H(11), and one H(9) atom. The C(7)-C(9) bond length is 1.50 Å. The C(7)-H(11) bond length is 1.10 Å. The C(7)-H(9) bond length is 1.10 Å. In the third C site, C(15) is bonded in a distorted single-bond geometry to one C(9) and one H(19) atom. The C(15)-C(9) bond length is 1.40 Å. The C(15)-H(19) bond length is 1.09 Å. In the fourth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(7) atom. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(7) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(5) atom. The C(5)-O(1) bond length is 1.27 Å. The C(5)-O(5) bond length is 1.28 Å. In the sixth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(15), one C(7), and one N(1) atom. The C(9)-N(1) bond length is 1.36 Å. N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(3), and one C(9) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(3) and one O(5) atom. The H(1)-O(3) bond length is 1.03 Å. The H(1)-O(5) bond length is 1.51 Å. In the second H site, H(19) is bonded in a single-bond geometry to one C(15) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(11) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a 3-coordinate geometry to one Ni(1), one C(11), and one H(1) atom. In the second O site, O(5) is bonded in a water-like geometry to one C(5) and one H(1) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(5) atom. Linkers: 2 OCCc1ccccn1 ,2 [O]C(=O)CCC([O])=O. Metal clusters: 1 O=[C]O[Ni]O[C]=O.[CH2]O.[CH2]O ,1 [Ni]. The MOF has largest included sphere 1.97 A, density 1.53 g/cm3, surface area 4855.87 m2/g, accessible volume 0.20 cm3/g