(CH2)4CuC14H10S2(N3O)2(C3NH7O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; two n,n-dimethylformamide molecules; and one CuC14H10S2(N3O)2 cluster. In the CuC14H10S2(N3O)2 cluster, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Cu(1)-N(1) bond lengths are 1.94 Å. Both Cu(1)-N(2) bond lengths are 2.04 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.62 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(6), and one N(3) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(6) bond length is 1.40 Å. The C(2)-N(3) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(2) atom. The C(3)-N(2) bond length is 1.34 Å. The C(3)-H(2) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one N(2), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-N(2) bond length is 1.34 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(3) and one O(1) atom. The C(7)-N(3) bond length is 1.37 Å. The C(7)-O(1) bond length is 1.24 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Cu(1) and one C(1) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(2), one C(7), and one H(1) atom. The N(3)-H(1) bond length is 1.03 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. O(1) is bonded in a single-bond geometry to one C(7) atom. Linkers: 1 O=C(CCCCC(=O)Nc1cccnc1)Nc1cccnc1. Metal clusters: 1 [Cu]. The MOF has largest included sphere 1.94 A, density 1.53 g/cm3, surface area 5465.71 m2/g, accessible volume 0.09 cm3/g