HgBr2HgC15H16(S2Br)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two mercuric bromide molecules and one HgC15H16(S2Br)2 cluster. In the HgC15H16(S2Br)2 cluster, Hg(1) is bonded in a 4-coordinate geometry to one S(1), one S(4), one Br(2), and one Br(3) atom. The Hg(1)-S(1) bond length is 3.01 Å. The Hg(1)-S(4) bond length is 2.98 Å. The Hg(1)-Br(2) bond length is 2.49 Å. The Hg(1)-Br(3) bond length is 2.50 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(5), and one S(3) atom. The C(2)-C(5) bond length is 1.40 Å. The C(2)-S(3) bond length is 1.77 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(10) and one H(2) atom. The C(3)-C(10) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(10), one C(5), and one H(3) atom. The C(4)-C(10) bond length is 1.41 Å. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(6)-C(9) bond length is 1.40 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(7)-C(11) bond length is 1.40 Å. The C(7)-H(6) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted water-like geometry to one H(7), one H(8), one S(3), and one S(4) atom. The C(8)-H(7) bond length is 1.10 Å. The C(8)-H(8) bond length is 1.10 Å. The C(8)-S(3) bond length is 1.80 Å. The C(8)-S(4) bond length is 1.82 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(12), one C(6), and one S(4) atom. The C(9)-C(12) bond length is 1.40 Å. The C(9)-S(4) bond length is 1.77 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(3), one C(4), and one S(2) atom. The C(10)-S(2) bond length is 1.75 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(13), one C(7), and one S(1) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-S(1) bond length is 1.76 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one H(9) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(11), one C(12), and one H(10) atom. The C(13)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a trigonal non-coplanar geometry to one H(11), one H(12), one H(13), and one S(2) atom. The C(14)-H(11) bond length is 1.10 Å. The C(14)-H(12) bond length is 1.10 Å. The C(14)-H(13) bond length is 1.10 Å. The C(14)-S(2) bond length is 1.80 Å. In the fifteenth C site, C(15) is bonded in a trigonal non-coplanar geometry to one H(14), one H(15), one H(16), and one S(1) atom. The C(15)-H(14) bond length is 1.10 Å. The C(15)-H(15) bond length is 1.10 Å. The C(15)-H(16) bond length is 1.10 Å. The C(15)-S(1) bond length is 1.80 Å. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(15) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one Hg(1), one C(11), and one C(15) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(10) and one C(14) atom. In the third S site, S(3) is bonded in a water-like geometry to one C(2) and one C(8) atom. In the fourth S site, S(4) is bonded in a distorted trigonal non-coplanar geometry to one Hg(1), one C(8), and one C(9) atom. There are two inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one Hg(1) atom. In the second Br site, Br(3) is bonded in a single-bond geometry to one Hg(1) atom. Linkers: 2 [C]Sc1ccc(SCSc2ccc(S[C])cc2)cc1. Metal clusters: 2 Br[Hg]Br.C[S] ,1 Br[Hg]Br.Br[Hg]Br.C[S].C[S]. The MOF has largest included sphere 2.38 A, density 3.01 g/cm3, surface area 2732.11 m2/g, accessible volume 0.07 cm3/g