CdC8H8(N2Br)2(C5H2)2(C9H6N)2 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two diisopropenyldiacetylene molecules, four schembl1705614 molecules, and two CdC8H8(N2Br)2 clusters. In each CdC8H8(N2Br)2 cluster, Cd(1) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(3), and two equivalent Br(1) atoms. Both Cd(1)-N(2) bond lengths are 2.41 Å. Both Cd(1)-N(3) bond lengths are 2.39 Å. Both Cd(1)-Br(1) bond lengths are 2.77 Å. There are four inequivalent C sites. In the first C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5,8) atom. The C(13)-N(2) bond length is 1.34 Å. The C(13)-H(5,8) bond length is 1.09 Å. In the second C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(14)-N(3) bond length is 1.35 Å. The C(14)-H(9) bond length is 1.09 Å. In the third C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5,8) atom. The C(9)-N(2) bond length is 1.34 Å. The C(9)-H(5,8) bond length is 1.09 Å. In the fourth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(12) atom. The C(18)-N(3) bond length is 1.34 Å. The C(18)-H(12) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(9) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(14), and one C(18) atom. There are three inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the third H site, H(5,8) is bonded in a single-bond geometry to one C(9) atom. Br(1) is bonded in a single-bond geometry to one Cd(1) atom. Linkers: 2 [CH]C(=[CH])C#CC#Cc1ccc(N(c2ccncc2)c2ccncc2)cc1 ,2 [CH]C(=[CH])N([C]C=[CH])c1ccc(C#CC#Cc2ccc(N(c3ccncc3)c3ccncc3)cc2)cc1 ,1 C(C#Cc1ccc(N(c2ccncc2)c2ccncc2)cc1)#Cc1ccc(N(c2ccncc2)c2ccncc2)cc1 ,2 [C]#Cc1ccc(N(c2ccncc2)c2ccncc2)cc1. Metal clusters: 2 Br[Cd]Br. The MOF has largest included sphere 4.71 A, density 1.45 g/cm3, surface area 4350.26 m2/g, accessible volume 0.26 cm3/g