Zn2C26H15(N3O4)2(CH)2C4H3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, one isobutylene molecule, and one Zn2C26H15(N3O4)2 cluster. In the Zn2C26H15(N3O4)2 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a square pyramidal geometry to one N(6), one O(2), one O(4), one O(6), and one O(8) atom. The Zn(1)-N(6) bond length is 2.05 Å. The Zn(1)-O(2) bond length is 2.09 Å. The Zn(1)-O(4) bond length is 2.10 Å. The Zn(1)-O(6) bond length is 2.05 Å. The Zn(1)-O(8) bond length is 2.06 Å. In the second Zn site, Zn(2) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(3), one O(5), and one O(7) atom. The Zn(2)-N(1) bond length is 2.05 Å. The Zn(2)-O(1) bond length is 2.08 Å. The Zn(2)-O(3) bond length is 2.06 Å. The Zn(2)-O(5) bond length is 2.05 Å. The Zn(2)-O(7) bond length is 2.05 Å. There are twenty-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-C(8) bond length is 1.46 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(5) and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(10)-O(3) bond length is 1.28 Å. The C(10)-O(4) bond length is 1.27 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(11)-O(5) bond length is 1.28 Å. The C(11)-O(6) bond length is 1.28 Å. In the eleventh C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(10) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(10) bond length is 1.09 Å. In the twelfth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(19) atom. The C(17)-C(18) bond length is 1.49 Å. The C(17)-C(19) bond length is 1.40 Å. In the thirteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(7), and one O(8) atom. The C(18)-O(7) bond length is 1.28 Å. The C(18)-O(8) bond length is 1.27 Å. In the fourteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(17) and one H(11) atom. The C(19)-H(11) bond length is 1.09 Å. In the fifteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(21)-N(1) bond length is 1.35 Å. The C(21)-H(13) bond length is 1.09 Å. In the sixteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(14) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(14) bond length is 1.09 Å. In the seventeenth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(26) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(26) bond length is 1.47 Å. In the eighteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(15) atom. The C(24)-H(15) bond length is 1.09 Å. In the nineteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(16) atom. The C(25)-N(1) bond length is 1.34 Å. The C(25)-H(16) bond length is 1.09 Å. In the twentieth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(23), one N(2), and one N(5) atom. The C(26)-N(2) bond length is 1.35 Å. The C(26)-N(5) bond length is 1.35 Å. In the twenty-first C site, C(27) is bonded in a distorted trigonal planar geometry to one C(28), one N(3), and one N(4) atom. The C(27)-C(28) bond length is 1.47 Å. The C(27)-N(3) bond length is 1.35 Å. The C(27)-N(4) bond length is 1.35 Å. In the twenty-second C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(32) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-C(32) bond length is 1.40 Å. In the twenty-third C site, C(29) is bonded in a distorted single-bond geometry to one C(28), one C(30), and one H(17) atom. The C(29)-C(30) bond length is 1.39 Å. The C(29)-H(17) bond length is 1.09 Å. In the twenty-fourth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one N(6), and one H(18) atom. The C(30)-N(6) bond length is 1.34 Å. The C(30)-H(18) bond length is 1.09 Å. In the twenty-fifth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(32), one N(6), and one H(19) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-N(6) bond length is 1.35 Å. The C(31)-H(19) bond length is 1.09 Å. In the twenty-sixth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(28), one C(31), and one H(20) atom. The C(32)-H(20) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(21), and one C(25) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(26) and one N(3) atom. The N(2)-N(3) bond length is 1.32 Å. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one C(27) and one N(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(27) and one N(5) atom. The N(4)-N(5) bond length is 1.32 Å. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(26) and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(1), one C(30), and one C(31) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(29) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(31) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(32) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(10) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(10) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(11) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(11) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(18) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(18) atom. Linkers: 1 c1cc(-c2nnc(-c3ccncc3)nn2)ccn1 ,2 [O]C(=O)/C=C/c1ccc(C([O])=O)cc1. Metal clusters: 1 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 4.82 A, density 1.26 g/cm3, surface area 4388.59 m2/g, accessible volume 0.29 cm3/g