AgC7N2H7SO3(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one AgC7N2H7SO3 cluster. In the AgC7N2H7SO3 cluster, Ag(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one O(3) atom. The Ag(1)-N(1) bond length is 2.17 Å. The Ag(1)-N(2) bond length is 2.40 Å. The Ag(1)-O(3) bond length is 2.28 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-S(1) bond length is 1.77 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.49 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one O(3) atom. The C(7)-N(1) bond length is 1.36 Å. The C(7)-O(3) bond length is 1.25 Å. In the sixth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(5), and one H(6) atom. The C(8)-N(2) bond length is 1.47 Å. The C(8)-H(5) bond length is 1.09 Å. The C(8)-H(6) bond length is 1.11 Å. In the seventh C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(7), and one H(8) atom. The C(9)-N(2) bond length is 1.47 Å. The C(9)-H(7) bond length is 1.09 Å. The C(9)-H(8) bond length is 1.11 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(7), and one S(1) atom. The N(1)-S(1) bond length is 1.66 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Ag(1), one C(8), one C(9), and one H(9) atom. The N(2)-H(9) bond length is 1.02 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a distorted tetrahedral geometry to one C(1), one N(1), one O(1), and one O(2) atom. The S(1)-O(1) bond length is 1.46 Å. The S(1)-O(2) bond length is 1.45 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Ag(1) and one C(7) atom. Linkers: 1 C1CNCCN1. Metal clusters: 2 [Ag]. The MOF has largest included sphere 1.69 A, density 2.23 g/cm3, surface area 3450.59 m2/g, accessible volume 0.09 cm3/g