CHCuC9NH9SI is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CuC9NH9SI clusters. In each CuC9NH9SI cluster, Cu(1) is bonded in a 4-coordinate geometry to one N(1), one S(1), and two equivalent I(1) atoms. The Cu(1)-N(1) bond length is 2.05 Å. The Cu(1)-S(1) bond length is 2.33 Å. There is one shorter (2.60 Å) and one longer (2.64 Å) Cu(1)-I(1) bond length. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(5) atom. The C(2)-C(3) bond length is 1.50 Å. The C(2)-C(5) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted water-like geometry to one C(2), one H(2), one H(3), and one S(1) atom. The C(3)-H(2) bond length is 1.10 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-S(1) bond length is 1.82 Å. In the fourth C site, C(4) is bonded in a distorted water-like geometry to one C(6), one H(4), one H(5), and one S(1) atom. The C(4)-C(6) bond length is 1.50 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. The C(4)-S(1) bond length is 1.81 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(2) and one H(6) atom. The C(5)-H(6) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(4), one C(8), and one N(1) atom. The C(6)-C(8) bond length is 1.40 Å. The C(6)-N(1) bond length is 1.35 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(7) atom. The C(7)-C(9) bond length is 1.39 Å. The C(7)-N(1) bond length is 1.35 Å. The C(7)-H(7) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one H(8) atom. The C(8)-H(8) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(7) and one H(9) atom. The C(9)-H(9) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(6), and one C(7) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one C(3), and one C(4) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 2 c1ccc(CSCc2ccc(CSCc3ccccn3)cc2)nc1 ,2 [CH]=[C]CSCc1ccc(CSCc2ccccn2)cc1. Metal clusters: 2 I[Cu][Cu]I. The MOF has largest included sphere 2.19 A, density 2.15 g/cm3, surface area 3442.93 m2/g, accessible volume 0.11 cm3/g