ZnC24H16(NO4)2(CH)2 crystallizes in the monoclinic C2/c space group. The structure consists of eight 02329_fluka molecules inside a ZnC24H16(NO4)2 framework. In the ZnC24H16(NO4)2 framework, Zn(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent O(2) atoms. Both Zn(1)-N(1) bond lengths are 2.05 Å. Both Zn(1)-O(2) bond lengths are 1.98 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(13), one C(3), and one H(1) atom. The C(1)-C(13) bond length is 1.39 Å. The C(1)-C(3) bond length is 1.41 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(12), one N(1), and one H(2) atom. The C(2)-C(12) bond length is 1.39 Å. The C(2)-N(1) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(12), and one C(3) atom. The C(3)-C(12) bond length is 1.40 Å. The C(3)-C(3) bond length is 1.48 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(10) and one H(4) atom. The C(4)-C(10) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(4) atom. The C(5)-C(10) bond length is 1.49 Å. The C(5)-O(3) bond length is 1.33 Å. The C(5)-O(4) bond length is 1.24 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(1), and one O(2) atom. The C(6)-C(8) bond length is 1.49 Å. The C(6)-O(1) bond length is 1.27 Å. The C(6)-O(2) bond length is 1.29 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(6), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.39 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(6) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(6) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(9) atom. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one H(9) atom. The C(13)-N(1) bond length is 1.35 Å. The C(13)-H(9) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(2) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(1) and one O(3) atom. The H(3)-O(1) bond length is 1.66 Å. The H(3)-O(3) bond length is 1.01 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one C(6) and one H(3) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(6) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(5) and one H(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(5) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.43 A, density 1.52 g/cm3, surface area 4810.66 m2/g, accessible volume 0.16 cm3/g