CuC26H32(N3O4)2(CH)2(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, four 02329_fluka molecules, and one CuC26H32(N3O4)2 cluster. In the CuC26H32(N3O4)2 cluster, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent N(1), two equivalent O(3), and two equivalent O(4) atoms. Both Cu(1)-N(1) bond lengths are 1.98 Å. Both Cu(1)-O(3) bond lengths are 2.54 Å. Both Cu(1)-O(4) bond lengths are 2.01 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(6) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(5) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.45 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(1), one C(4), and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one C(1), one N(2), and one N(3) atom. The C(6)-N(2) bond length is 1.36 Å. The C(6)-N(3) bond length is 1.36 Å. In the seventh C site, C(7) is bonded in a distorted tetrahedral geometry to one C(10), one C(8), one C(9), and one N(2) atom. The C(7)-C(10) bond length is 1.56 Å. The C(7)-C(8) bond length is 1.53 Å. The C(7)-C(9) bond length is 1.52 Å. The C(7)-N(2) bond length is 1.51 Å. In the eighth C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(7), one H(5), one H(6), and one H(7) atom. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-H(7) bond length is 1.10 Å. In the ninth C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(7); one H(10); and two equivalent H(8,9) atoms. The C(9)-H(10) bond length is 1.09 Å. Both C(9)-H(8,9) bond lengths are 1.10 Å. In the tenth C site, C(10) is bonded in a distorted tetrahedral geometry to one C(11), one C(12), one C(7), and one N(3) atom. The C(10)-C(11) bond length is 1.53 Å. The C(10)-C(12) bond length is 1.52 Å. The C(10)-N(3) bond length is 1.52 Å. In the eleventh C site, C(11) is bonded in a trigonal non-coplanar geometry to one C(10), one H(11), one H(12), and one H(13) atom. The C(11)-H(11) bond length is 1.10 Å. The C(11)-H(12) bond length is 1.10 Å. The C(11)-H(13) bond length is 1.10 Å. In the twelfth C site, C(12) is bonded in a trigonal non-coplanar geometry to one C(10), one H(14), one H(15), and one H(16) atom. The C(12)-H(14) bond length is 1.10 Å. The C(12)-H(15) bond length is 1.10 Å. The C(12)-H(16) bond length is 1.10 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(13)-O(3) bond length is 1.25 Å. The C(13)-O(4) bond length is 1.30 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(6), one C(7), and one O(1) atom. The N(2)-O(1) bond length is 1.28 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(6), and one O(2) atom. The N(3)-O(2) bond length is 1.28 Å. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8,9) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(12) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cu(1) and one C(13) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cu(1) and one C(13) atom. Linkers: 1 [O]C(=O)[C@H]1CC[C@H](C([O])=O)CC1. Metal clusters: 1 [Cu]. The MOF has largest included sphere 2.40 A, density 1.43 g/cm3, surface area 5366.18 m2/g, accessible volume 0.18 cm3/g