ZnC17PH12(NO2)2CH2(CH)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, four 02329_fluka molecules, and two ZnC17PH12(NO2)2 clusters. In each ZnC17PH12(NO2)2 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(1), one N(3), one O(4), one O(5), and one O(8) atom to form distorted ZnN2O3 trigonal bipyramids that share  a cornercorner with one P(1)C2O2 tetrahedra and  a cornercorner with one P(2)C2O2 tetrahedra. The Zn(1)-N(1) bond length is 2.27 Å. The Zn(1)-N(3) bond length is 2.13 Å. The Zn(1)-O(4) bond length is 2.00 Å. The Zn(1)-O(5) bond length is 2.01 Å. The Zn(1)-O(8) bond length is 2.08 Å. In the second Zn site, Zn(2) is bonded to one N(2), one N(4), one O(3), one O(6), and one O(7) atom to form distorted ZnN2O3 trigonal bipyramids that share  a cornercorner with one P(1)C2O2 tetrahedra and  a cornercorner with one P(2)C2O2 tetrahedra. The Zn(2)-N(2) bond length is 2.27 Å. The Zn(2)-N(4) bond length is 2.13 Å. The Zn(2)-O(3) bond length is 2.00 Å. The Zn(2)-O(6) bond length is 2.01 Å. The Zn(2)-O(7) bond length is 2.08 Å. There are twenty-nine inequivalent C sites. In the first C site, C(28) is bonded in a distorted trigonal planar geometry to one C(26), one C(30), and one N(2) atom. The C(28)-C(26) bond length is 1.42 Å. The C(28)-C(30) bond length is 1.44 Å. The C(28)-N(2) bond length is 1.35 Å. In the second C site, C(27) is bonded in a distorted trigonal planar geometry to one C(25), one C(29), and one N(1) atom. The C(27)-C(25) bond length is 1.42 Å. The C(27)-C(29) bond length is 1.44 Å. The C(27)-N(1) bond length is 1.35 Å. In the third C site, C(29) is bonded in a distorted trigonal planar geometry to one C(27), one C(31), and one N(3) atom. The C(29)-C(31) bond length is 1.42 Å. The C(29)-N(3) bond length is 1.35 Å. In the fourth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(28), one C(32), and one N(4) atom. The C(30)-C(32) bond length is 1.42 Å. The C(30)-N(4) bond length is 1.35 Å. In the fifth C site, C(31) is bonded in a trigonal planar geometry to one C(29), one C(33), and one C(41) atom. The C(31)-C(33) bond length is 1.41 Å. The C(31)-C(41) bond length is 1.43 Å. In the sixth C site, C(32) is bonded in a trigonal planar geometry to one C(30), one C(34), and one C(42) atom. The C(32)-C(34) bond length is 1.41 Å. The C(32)-C(42) bond length is 1.43 Å. In the seventh C site, C(33) is bonded in a distorted single-bond geometry to one C(31), one C(35), and one H(25) atom. The C(33)-C(35) bond length is 1.38 Å. The C(33)-H(25) bond length is 1.09 Å. In the eighth C site, C(34) is bonded in a distorted single-bond geometry to one C(32), one C(36), and one H(26) atom. The C(34)-C(36) bond length is 1.38 Å. The C(34)-H(26) bond length is 1.09 Å. In the ninth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(33); one C(37); and one H(27,28) atom. The C(35)-C(37) bond length is 1.41 Å. The C(35)-H(27,28) bond length is 1.09 Å. In the tenth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(34); one C(38); and one H(27,28) atom. The C(36)-C(38) bond length is 1.41 Å. The C(36)-H(27,28) bond length is 1.09 Å. In the eleventh C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(35), one N(3), and one H(29) atom. The C(37)-N(3) bond length is 1.33 Å. The C(37)-H(29) bond length is 1.09 Å. In the twelfth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(36), one N(4), and one H(30) atom. The C(38)-N(4) bond length is 1.33 Å. The C(38)-H(30) bond length is 1.09 Å. In the thirteenth C site, C(39,40) is bonded in a distorted single-bond geometry to one C(25) and one H(31,32) atom. The C(39,40)-C(25) bond length is 1.43 Å. The C(39,40)-H(31,32) bond length is 1.09 Å. In the fourteenth C site, C(41) is bonded in a distorted single-bond geometry to one C(31) and one H(33,34) atom. The C(41)-H(33,34) bond length is 1.09 Å. In the fifteenth C site, C(42) is bonded in a distorted single-bond geometry to one C(32) and one H(33,34) atom. The C(42)-H(33,34) bond length is 1.09 Å. In the sixteenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(3) bond length is 1.30 Å. In the seventeenth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(2)-O(2) bond length is 1.25 Å. The C(2)-O(4) bond length is 1.30 Å. In the eighteenth C site, C(5) is bonded in a distorted water-like geometry to one P(1); one H(5,6); and one H(7,8) atom. The C(5)-P(1) bond length is 1.81 Å. The C(5)-H(5,6) bond length is 1.10 Å. The C(5)-H(7,8) bond length is 1.10 Å. In the nineteenth C site, C(6) is bonded in a distorted water-like geometry to one P(2); one H(5,6); and one H(7,8) atom. The C(6)-P(2) bond length is 1.81 Å. The C(6)-H(5,6) bond length is 1.10 Å. The C(6)-H(7,8) bond length is 1.10 Å. In the twentieth C site, C(7) is bonded in a trigonal planar geometry to one C(17,18); one C(9,10); and one P(1) atom. The C(7)-C(17,18) bond length is 1.40 Å. The C(7)-C(9,10) bond length is 1.40 Å. The C(7)-P(1) bond length is 1.83 Å. In the twenty-first C site, C(8) is bonded in a trigonal planar geometry to one C(17,18); one C(9,10); and one P(2) atom. The C(8)-C(17,18) bond length is 1.40 Å. The C(8)-C(9,10) bond length is 1.40 Å. The C(8)-P(2) bond length is 1.83 Å. In the twenty-second C site, C(9,10) is bonded in a distorted single-bond geometry to one C(7) and one H(9,10) atom. The C(9,10)-H(9,10) bond length is 1.09 Å. In the twenty-third C site, C(15,16) is bonded in a distorted single-bond geometry to one C(17,18) and one H(15,16) atom. The C(15,16)-C(17,18) bond length is 1.40 Å. The C(15,16)-H(15,16) bond length is 1.09 Å. In the twenty-fourth C site, C(17,18) is bonded in a distorted trigonal planar geometry to one C(15,16); one C(7); and one H(17,18) atom. The C(17,18)-H(17,18) bond length is 1.09 Å. In the twenty-fifth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(19) atom. The C(19)-N(1) bond length is 1.33 Å. The C(19)-H(19) bond length is 1.09 Å. In the twenty-sixth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(20) atom. The C(20)-N(2) bond length is 1.33 Å. The C(20)-H(20) bond length is 1.09 Å. In the twenty-seventh C site, C(23,24) is bonded in a distorted single-bond geometry to one C(25) and one H(23,24) atom. The C(23,24)-C(25) bond length is 1.41 Å. The C(23,24)-H(23,24) bond length is 1.09 Å. In the twenty-eighth C site, C(25) is bonded in a trigonal planar geometry to one C(23,24); one C(27); and one C(39,40) atom. In the twenty-ninth C site, C(26) is bonded in a trigonal planar geometry to one C(23,24); one C(28); and one C(39,40) atom. The C(26)-C(23,24) bond length is 1.41 Å. The C(26)-C(39,40) bond length is 1.43 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one C(5), one C(7), one O(5), and one O(7) atom to form PC2O2 tetrahedra that share  a cornercorner with one Zn(1)N2O3 trigonal bipyramid and  a cornercorner with one Zn(2)N2O3 trigonal bipyramid. The P(1)-O(5) bond length is 1.53 Å. The P(1)-O(7) bond length is 1.52 Å. In the second P site, P(2) is bonded to one C(6), one C(8), one O(6), and one O(8) atom to form PC2O2 tetrahedra that share  a cornercorner with one Zn(1)N2O3 trigonal bipyramid and  a cornercorner with one Zn(2)N2O3 trigonal bipyramid. The P(2)-O(6) bond length is 1.53 Å. The P(2)-O(8) bond length is 1.52 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(19), and one C(27) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(20), and one C(28) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(29), and one C(37) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(2), one C(30), and one C(38) atom. There are fifteen inequivalent H sites. In the first H site, H(5,6) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(7,8) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(9,10) is bonded in a single-bond geometry to one C(9,10) atom. In the fourth H site, H(15,16) is bonded in a single-bond geometry to one C(15,16) atom. In the fifth H site, H(17,18) is bonded in a single-bond geometry to one C(17,18) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(23,24) is bonded in a single-bond geometry to one C(23,24) atom. In the ninth H site, H(25) is bonded in a single-bond geometry to one C(33) atom. In the tenth H site, H(26) is bonded in a single-bond geometry to one C(34) atom. In the eleventh H site, H(27,28) is bonded in a single-bond geometry to one C(35) atom. In the twelfth H site, H(29) is bonded in a single-bond geometry to one C(37) atom. In the thirteenth H site, H(30) is bonded in a single-bond geometry to one C(38) atom. In the fourteenth H site, H(31,32) is bonded in a single-bond geometry to one C(39,40) atom. In the fifteenth H site, H(33,34) is bonded in a single-bond geometry to one C(41) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zn(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one P(1) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(2) atom. Linkers: 2 [O]C(=O)CC[P@]([O])(=O)c1ccccc1 ,2 [O]C(=O)CC[P@@]([O])(=O)c1ccccc1 ,2 c1cnc2c(c1)ccc1cccnc12. Metal clusters: 4 [Zn]. The MOF has largest included sphere 4.54 A, density 1.26 g/cm3, surface area 4706.72 m2/g, accessible volume 0.33 cm3/g