SrC6H14(NO5)2(C6N5H8O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four C6N5H8O2 clusters and two SrC6H14(NO5)2 clusters. In each C6N5H8O2 cluster, there are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one N(7) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(3) bond length is 1.34 Å. The C(1)-N(7) bond length is 1.39 Å. In the second C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(3), and one H(5) atom. The C(3)-N(3) bond length is 1.45 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(5) bond length is 1.10 Å. In the third C site, C(11,12) is bonded in a tetrahedral geometry to one N(7); one H(13,14); one H(15,16); and one H(17,18) atom. The C(11,12)-N(7) bond length is 1.47 Å. The C(11,12)-H(13,14) bond length is 1.10 Å. The C(11,12)-H(15,16) bond length is 1.09 Å. The C(11,12)-H(17,18) bond length is 1.09 Å. In the fourth C site, C(13,14) is bonded in a distorted bent 120 degrees geometry to one N(7) and one O(7) atom. The C(13,14)-N(7) bond length is 1.40 Å. The C(13,14)-O(7) bond length is 1.24 Å. In the fifth C site, C(15) is bonded in a distorted single-bond geometry to one C(17) and one N(9) atom. The C(15)-C(17) bond length is 1.45 Å. The C(15)-N(9) bond length is 1.35 Å. In the sixth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(15); one N(1); and one N(11,12) atom. The C(17)-N(1) bond length is 1.34 Å. The C(17)-N(11,12) bond length is 1.33 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(17) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The N(3)-H(1) bond length is 1.04 Å. In the third N site, N(7) is bonded in a trigonal planar geometry to one C(1); one C(11,12); and one C(13,14) atom. In the fourth N site, N(9) is bonded in a bent 120 degrees geometry to one C(15) and one O(9) atom. The N(9)-O(9) bond length is 1.29 Å. In the fifth N site, N(11,12) is bonded in a trigonal planar geometry to one C(17), one H(19), and one H(21) atom. The N(11,12)-H(19) bond length is 1.03 Å. The N(11,12)-H(21) bond length is 1.03 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(13,14) is bonded in a single-bond geometry to one C(11,12) atom. In the fifth H site, H(15,16) is bonded in a single-bond geometry to one C(11,12) atom. In the sixth H site, H(17,18) is bonded in a single-bond geometry to one C(11,12) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one N(11,12) atom. In the eighth H site, H(21) is bonded in a single-bond geometry to one N(11,12) atom. There are two inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one C(13,14) atom. In the second O site, O(9) is bonded in a distorted single-bond geometry to one N(9) atom. In each SrC6H14(NO5)2 cluster, Sr(1) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(12), one O(13), one O(14), one O(2), one O(5), and one O(6) atom. The Sr(1)-O(1) bond length is 2.58 Å. The Sr(1)-O(11) bond length is 2.61 Å. The Sr(1)-O(12) bond length is 2.61 Å. The Sr(1)-O(13) bond length is 2.53 Å. The Sr(1)-O(14) bond length is 2.53 Å. The Sr(1)-O(2) bond length is 2.58 Å. The Sr(1)-O(5) bond length is 2.68 Å. The Sr(1)-O(6) bond length is 2.67 Å. There are five inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(5) and one O(1) atom. The C(5)-N(5) bond length is 1.33 Å. The C(5)-O(1) bond length is 1.25 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(6) and one O(2) atom. The C(6)-N(6) bond length is 1.33 Å. The C(6)-O(2) bond length is 1.25 Å. In the third C site, C(7,8) is bonded in a distorted trigonal non-coplanar geometry to one N(5) and two equivalent H(9,10,11,12) atoms. The C(7,8)-N(5) bond length is 1.44 Å. Both C(7,8)-H(9,10,11,12) bond lengths are 1.10 Å. In the fourth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(5) atom. The C(9)-O(3) bond length is 1.28 Å. The C(9)-O(5) bond length is 1.26 Å. In the fifth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. The C(10)-O(4) bond length is 1.28 Å. The C(10)-O(6) bond length is 1.26 Å. There are two inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one C(5); one C(7,8); and one H(7,8) atom. The N(5)-H(7,8) bond length is 1.02 Å. In the second N site, N(6) is bonded in a trigonal planar geometry to one C(6); one C(7,8); and one H(7,8) atom. The N(6)-C(7,8) bond length is 1.44 Å. The N(6)-H(7,8) bond length is 1.02 Å. There are ten inequivalent H sites. In the first H site, H(7,8) is bonded in a single-bond geometry to one N(5) atom. In the second H site, H(9,10,11,12) is bonded in a single-bond geometry to one C(7,8) atom. In the third H site, H(23) is bonded in a single-bond geometry to one O(11) atom. The H(23)-O(11) bond length is 0.99 Å. In the fourth H site, H(24) is bonded in a single-bond geometry to one O(12) atom. The H(24)-O(12) bond length is 0.99 Å. In the fifth H site, H(25) is bonded in a single-bond geometry to one O(11) atom. The H(25)-O(11) bond length is 0.98 Å. In the sixth H site, H(26) is bonded in a single-bond geometry to one O(12) atom. The H(26)-O(12) bond length is 0.98 Å. In the seventh H site, H(27) is bonded in a single-bond geometry to one O(13) atom. The H(27)-O(13) bond length is 0.99 Å. In the eighth H site, H(28) is bonded in a single-bond geometry to one O(14) atom. The H(28)-O(14) bond length is 0.99 Å. In the ninth H site, H(29) is bonded in a single-bond geometry to one O(13) atom. The H(29)-O(13) bond length is 0.99 Å. In the tenth H site, H(30) is bonded in a single-bond geometry to one O(14) atom. The H(30)-O(14) bond length is 0.99 Å. There are ten inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Sr(1) and one C(9) atom. In the second O site, O(6) is bonded in a distorted single-bond geometry to one Sr(1) and one C(10) atom. In the third O site, O(11) is bonded in a distorted water-like geometry to one Sr(1), one H(23), and one H(25) atom. In the fourth O site, O(12) is bonded in a distorted water-like geometry to one Sr(1), one H(24), and one H(26) atom. In the fifth O site, O(13) is bonded in a distorted water-like geometry to one Sr(1), one H(27), and one H(29) atom. In the sixth O site, O(14) is bonded in a distorted water-like geometry to one Sr(1), one H(28), and one H(30) atom. In the seventh O site, O(1) is bonded in a distorted single-bond geometry to one Sr(1) and one C(5) atom. In the eighth O site, O(2) is bonded in a distorted single-bond geometry to one Sr(1) and one C(6) atom. In the ninth O site, O(3) is bonded in a single-bond geometry to one C(9) atom. In the tenth O site, O(4) is bonded in a single-bond geometry to one C(10) atom. Linkers: 4 CN1[C](NCC(=O)NCC([O])=O)N=C(N)/C(=N\[O])C1=O. Metal clusters: 2 [Sr]. The MOF has largest included sphere 1.77 A, density 1.84 g/cm3, surface area 3995.80 m2/g, accessible volume 0.08 cm3/g