CdC14H15(N3O2)2(CH2)10 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty 02329_fluka molecules and two CdC14H15(N3O2)2 clusters. In each CdC14H15(N3O2)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(3), one N(5), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.35 Å. The Cd(1)-N(3) bond length is 2.37 Å. The Cd(1)-N(5) bond length is 2.33 Å. The Cd(1)-O(2) bond length is 2.35 Å. The Cd(1)-O(3) bond length is 2.35 Å. The Cd(1)-O(4) bond length is 2.67 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.29 Å. In the second C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(9)-O(3) bond length is 1.28 Å. The C(9)-O(4) bond length is 1.27 Å. In the third C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(1), and one H(15) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-N(1) bond length is 1.38 Å. The C(10)-H(15) bond length is 1.08 Å. In the fourth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(16) atom. The C(11)-N(2) bond length is 1.38 Å. The C(11)-H(16) bond length is 1.08 Å. In the fifth C site, C(12) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(17) atom. The C(12)-N(1) bond length is 1.33 Å. The C(12)-N(2) bond length is 1.36 Å. The C(12)-H(17) bond length is 1.08 Å. In the sixth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(18), and one H(19) atom. The C(13)-N(2) bond length is 1.46 Å. The C(13)-H(18) bond length is 1.10 Å. The C(13)-H(19) bond length is 1.10 Å. In the seventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(3), and one H(22) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-N(3) bond length is 1.38 Å. The C(15)-H(22) bond length is 1.08 Å. In the eighth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(4), and one H(23) atom. The C(16)-N(4) bond length is 1.38 Å. The C(16)-H(23) bond length is 1.08 Å. In the ninth C site, C(17) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(24) atom. The C(17)-N(3) bond length is 1.33 Å. The C(17)-N(4) bond length is 1.36 Å. The C(17)-H(24) bond length is 1.09 Å. In the tenth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(25), and one H(26) atom. The C(18)-N(4) bond length is 1.46 Å. The C(18)-H(25) bond length is 1.10 Å. The C(18)-H(26) bond length is 1.10 Å. In the eleventh C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(5), and one H(29) atom. The C(20)-C(21) bond length is 1.38 Å. The C(20)-N(5) bond length is 1.38 Å. The C(20)-H(29) bond length is 1.08 Å. In the twelfth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(6), and one H(30) atom. The C(21)-N(6) bond length is 1.38 Å. The C(21)-H(30) bond length is 1.08 Å. In the thirteenth C site, C(22) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(31) atom. The C(22)-N(5) bond length is 1.33 Å. The C(22)-N(6) bond length is 1.36 Å. The C(22)-H(31) bond length is 1.09 Å. In the fourteenth C site, C(23) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(32), and one H(33) atom. The C(23)-N(6) bond length is 1.46 Å. The C(23)-H(32) bond length is 1.10 Å. The C(23)-H(33) bond length is 1.10 Å. There are six inequivalent N sites. In the first N site, N(5) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(20), and one C(22) atom. In the second N site, N(6) is bonded in a trigonal planar geometry to one C(21), one C(22), and one C(23) atom. In the third N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one C(12) atom. In the fourth N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(13) atom. In the fifth N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(15), and one C(17) atom. In the sixth N site, N(4) is bonded in a trigonal planar geometry to one C(16), one C(17), and one C(18) atom. There are fifteen inequivalent H sites. In the first H site, H(15) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(16) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(17) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(18) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(19) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(22) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(23) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(24) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(25) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(26) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(29) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(30) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(31) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(32) is bonded in a single-bond geometry to one C(23) atom. In the fifteenth H site, H(33) is bonded in a single-bond geometry to one C(23) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(1) and one C(9) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cd(1) and one C(9) atom. Linkers: 3 c1cn(CCCCn2ccnc2)cn1 ,2 [O]C(=O)CCCCCCCC([O])=O. Metal clusters: 2 O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 3.53 A, density 1.34 g/cm3, surface area 5383.92 m2/g, accessible volume 0.28 cm3/g