Ag3C7H4(NS)3 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted tetrahedral geometry to one N(1), one S(1), one S(2), and one S(3) atom. The Ag(1)-N(1) bond length is 2.29 Å. The Ag(1)-S(1) bond length is 2.68 Å. The Ag(1)-S(2) bond length is 2.53 Å. The Ag(1)-S(3) bond length is 2.53 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one N(2), one S(1), and two equivalent S(2) atoms. The Ag(2)-N(2) bond length is 2.22 Å. The Ag(2)-S(1) bond length is 2.48 Å. There is one shorter (2.62 Å) and one longer (2.73 Å) Ag(2)-S(2) bond length. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to one N(3), one S(1), and two equivalent S(3) atoms. The Ag(3)-N(3) bond length is 2.17 Å. The Ag(3)-S(1) bond length is 2.48 Å. There is one shorter (2.59 Å) and one longer (2.77 Å) Ag(3)-S(3) bond length. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one S(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-S(1) bond length is 1.76 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one N(2) and one S(2) atom. The C(6)-N(2) bond length is 1.18 Å. The C(6)-S(2) bond length is 1.65 Å. In the seventh C site, C(7) is bonded in a distorted linear geometry to one N(3) and one S(3) atom. The C(7)-N(3) bond length is 1.18 Å. The C(7)-S(3) bond length is 1.65 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one Ag(2) and one C(6) atom. In the third N site, N(3) is bonded in a distorted bent 150 degrees geometry to one Ag(3) and one C(7) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded to one Ag(1), one Ag(2), one Ag(3), and one C(3) atom to form corner-sharing SAg3C tetrahedra. In the second S site, S(2) is bonded to one Ag(1), two equivalent Ag(2), and one C(6) atom to form distorted corner-sharing SAg3C trigonal pyramids. In the third S site, S(3) is bonded to one Ag(1), two equivalent Ag(3), and one C(7) atom to form distorted corner-sharing SAg3C tetrahedra. Linkers: 4 [S]c1ccncc1. Metal clusters: 12 [Ag]. The MOF has largest included sphere 1.89 A, density 3.22 g/cm3, surface area 2153.54 m2/g, accessible volume 0.05 cm3/g