AgC10H7S2(NO)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one N(1), one N(4), and two equivalent O(2) atoms to form distorted edge-sharing AgN2O2 trigonal pyramids. The Ag(1)-N(1) bond length is 2.26 Å. The Ag(1)-N(4) bond length is 2.25 Å. There is one shorter (2.25 Å) and one longer (2.67 Å) Ag(1)-O(2) bond length. In the second Ag site, Ag(2) is bonded in a distorted trigonal pyramidal geometry to one N(2), one N(3), one O(3), and one O(4) atom. The Ag(2)-N(2) bond length is 2.25 Å. The Ag(2)-N(3) bond length is 2.29 Å. The Ag(2)-O(3) bond length is 2.23 Å. The Ag(2)-O(4) bond length is 2.77 Å. There are twenty inequivalent C sites. In the first C site, C(17) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(17)-C(12) bond length is 1.40 Å. The C(17)-H(11) bond length is 1.09 Å. In the second C site, C(18) is bonded in a distorted water-like geometry to one C(15), one H(12), one H(13), and one S(3) atom. The C(18)-C(15) bond length is 1.50 Å. The C(18)-H(12) bond length is 1.10 Å. The C(18)-H(13) bond length is 1.10 Å. The C(18)-S(3) bond length is 1.83 Å. In the third C site, C(19) is bonded in a distorted single-bond geometry to one N(3), one S(3), and one S(4) atom. The C(19)-N(3) bond length is 1.33 Å. The C(19)-S(3) bond length is 1.72 Å. The C(19)-S(4) bond length is 1.74 Å. In the fourth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4), one H(14), and one S(4) atom. The C(20)-N(4) bond length is 1.31 Å. The C(20)-H(14) bond length is 1.09 Å. The C(20)-S(4) bond length is 1.72 Å. In the fifth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.30 Å. In the sixth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the seventh C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the eighth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(2) bond length is 1.09 Å. In the ninth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.51 Å. In the tenth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the eleventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the twelfth C site, C(8) is bonded in a distorted water-like geometry to one C(5), one H(5), one H(6), and one S(1) atom. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-S(1) bond length is 1.83 Å. In the thirteenth C site, C(9) is bonded in a distorted single-bond geometry to one N(1), one S(1), and one S(2) atom. The C(9)-N(1) bond length is 1.32 Å. The C(9)-S(1) bond length is 1.72 Å. The C(9)-S(2) bond length is 1.74 Å. In the fourteenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2), one H(7), and one S(2) atom. The C(10)-N(2) bond length is 1.31 Å. The C(10)-H(7) bond length is 1.09 Å. The C(10)-S(2) bond length is 1.72 Å. In the fifteenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(3), and one O(4) atom. The C(11)-C(12) bond length is 1.51 Å. The C(11)-O(3) bond length is 1.28 Å. The C(11)-O(4) bond length is 1.27 Å. In the sixteenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.40 Å. In the seventeenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(8) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(8) bond length is 1.09 Å. In the eighteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(9) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(9) bond length is 1.09 Å. In the nineteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.41 Å. In the twentieth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(10) atom. The C(16)-H(10) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(9), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(10), and one N(1) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(19), and one N(4) atom. The N(3)-N(4) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(20), and one N(3) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(8) and one C(9) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one C(10) and one C(9) atom. In the third S site, S(3) is bonded in a water-like geometry to one C(18) and one C(19) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one C(19) and one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one C(11) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Ag(2) and one C(11) atom. Linkers: 8 [O]C(=O)c1ccc(CSc2nncs2)cc1. Metal clusters: 8 [Ag]. The MOF has largest included sphere 2.96 A, density 1.98 g/cm3, surface area 3434.49 m2/g, accessible volume 0.15 cm3/g