ZnC9N2H7SO3F crystallizes in the triclinic P1 space group. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(5), one O(4), one O(8), one O(9), one F(1), and one F(3) atom to form distorted corner-sharing ZnNO3F2 octahedra. The corner-sharing octahedral tilt angles range from 15-16°. The Zn(1)-N(5) bond length is 2.09 Å. The Zn(1)-O(4) bond length is 2.23 Å. The Zn(1)-O(8) bond length is 2.33 Å. The Zn(1)-O(9) bond length is 2.04 Å. The Zn(1)-F(1) bond length is 2.03 Å. The Zn(1)-F(3) bond length is 2.05 Å. In the second Zn site, Zn(2) is bonded to one N(6), one O(10), one O(3), one O(7), one F(2), and one F(4) atom to form distorted corner-sharing ZnNO3F2 octahedra. The corner-sharing octahedral tilt angles are 16°. The Zn(2)-N(6) bond length is 2.09 Å. The Zn(2)-O(10) bond length is 2.04 Å. The Zn(2)-O(3) bond length is 2.23 Å. The Zn(2)-O(7) bond length is 2.33 Å. The Zn(2)-F(2) bond length is 2.03 Å. The Zn(2)-F(4) bond length is 2.05 Å. In the third Zn site, Zn(3) is bonded to one N(7), one O(11), one O(2), one O(6), one F(1), and one F(3) atom to form distorted corner-sharing ZnNO3F2 octahedra. The corner-sharing octahedral tilt angles range from 15-16°. The Zn(3)-N(7) bond length is 2.09 Å. The Zn(3)-O(11) bond length is 2.04 Å. The Zn(3)-O(2) bond length is 2.23 Å. The Zn(3)-O(6) bond length is 2.34 Å. The Zn(3)-F(1) bond length is 2.05 Å. The Zn(3)-F(3) bond length is 2.03 Å. In the fourth Zn site, Zn(4) is bonded to one N(8), one O(1), one O(12), one O(5), one F(2), and one F(4) atom to form distorted corner-sharing ZnNO3F2 octahedra. The corner-sharing octahedral tilt angles are 16°. The Zn(4)-N(8) bond length is 2.09 Å. The Zn(4)-O(1) bond length is 2.22 Å. The Zn(4)-O(12) bond length is 2.04 Å. The Zn(4)-O(5) bond length is 2.34 Å. The Zn(4)-F(2) bond length is 2.05 Å. The Zn(4)-F(4) bond length is 2.03 Å. There are twenty-six inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(5,6,8); one O(1); and one O(5) atom. The C(1)-C(5,6,8) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(5) bond length is 1.30 Å. In the second C site, C(2) is bonded in a bent 120 degrees geometry to one C(5,6,8); one O(2); and one O(6) atom. The C(2)-C(5,6,8) bond length is 1.48 Å. The C(2)-O(2) bond length is 1.26 Å. The C(2)-O(6) bond length is 1.30 Å. In the third C site, C(3) is bonded in a bent 120 degrees geometry to one C(7), one O(3), and one O(7) atom. The C(3)-C(7) bond length is 1.48 Å. The C(3)-O(3) bond length is 1.26 Å. The C(3)-O(7) bond length is 1.30 Å. In the fourth C site, C(4) is bonded in a bent 120 degrees geometry to one C(5,6,8); one O(4); and one O(8) atom. The C(4)-C(5,6,8) bond length is 1.48 Å. The C(4)-O(4) bond length is 1.26 Å. The C(4)-O(8) bond length is 1.30 Å. In the fifth C site, C(5,6,8) is bonded in a distorted trigonal planar geometry to one C(1), one C(9), and one N(1) atom. The C(5,6,8)-C(9) bond length is 1.39 Å. The C(5,6,8)-N(1) bond length is 1.37 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(11), one C(3), and one N(3) atom. The C(7)-C(11) bond length is 1.39 Å. The C(7)-N(3) bond length is 1.37 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(5,6,8); one H(1,2,4); and one S(1,2,4) atom. The C(9)-H(1,2,4) bond length is 1.09 Å. The C(9)-S(1,2,4) bond length is 1.70 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(5,6,8); one H(1,2,4); and one S(1,2,4) atom. The C(10)-C(5,6,8) bond length is 1.39 Å. The C(10)-H(1,2,4) bond length is 1.09 Å. The C(10)-S(1,2,4) bond length is 1.70 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(7), one H(3), and one S(3) atom. The C(11)-H(3) bond length is 1.09 Å. The C(11)-S(3) bond length is 1.70 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(5,6,8); one H(1,2,4); and one S(1,2,4) atom. The C(12)-C(5,6,8) bond length is 1.39 Å. The C(12)-H(1,2,4) bond length is 1.09 Å. The C(12)-S(1,2,4) bond length is 1.70 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(17,18,19,20); one N(1); and one S(1,2,4) atom. The C(13)-C(17,18,19,20) bond length is 1.46 Å. The C(13)-N(1) bond length is 1.32 Å. The C(13)-S(1,2,4) bond length is 1.75 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(17,18,19,20); one N(2); and one S(1,2,4) atom. The C(14)-C(17,18,19,20) bond length is 1.46 Å. The C(14)-N(2) bond length is 1.32 Å. The C(14)-S(1,2,4) bond length is 1.75 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(17,18,19,20); one N(3); and one S(3) atom. The C(15)-C(17,18,19,20) bond length is 1.46 Å. The C(15)-N(3) bond length is 1.32 Å. The C(15)-S(3) bond length is 1.75 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17,18,19,20); one N(4); and one S(1,2,4) atom. The C(16)-C(17,18,19,20) bond length is 1.46 Å. The C(16)-N(4) bond length is 1.32 Å. The C(16)-S(1,2,4) bond length is 1.75 Å. In the fifteenth C site, C(17,18,19,20) is bonded in a trigonal planar geometry to one C(13); one C(21,23,24); and one C(33,35) atom. The C(17,18,19,20)-C(21,23,24) bond length is 1.40 Å. The C(17,18,19,20)-C(33,35) bond length is 1.40 Å. In the sixteenth C site, C(21,23,24) is bonded in a distorted single-bond geometry to one C(17,18,19,20) and one H(5,6,7,8) atom. The C(21,23,24)-H(5,6,7,8) bond length is 1.09 Å. In the seventeenth C site, C(22) is bonded in a distorted single-bond geometry to one C(17,18,19,20) and one H(5,6,7,8) atom. The C(22)-C(17,18,19,20) bond length is 1.40 Å. The C(22)-H(5,6,7,8) bond length is 1.09 Å. In the eighteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(9,10,11) atom. The C(25)-N(5) bond length is 1.35 Å. The C(25)-H(9,10,11) bond length is 1.09 Å. In the nineteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(9,10,11) atom. The C(26)-N(6) bond length is 1.35 Å. The C(26)-H(9,10,11) bond length is 1.09 Å. In the twentieth C site, C(27,28) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(9,10,11) atom. The C(27,28)-N(7) bond length is 1.35 Å. The C(27,28)-H(9,10,11) bond length is 1.09 Å. In the twenty-first C site, C(29) is bonded in a distorted trigonal planar geometry to one C(33,35); one N(5); and one H(13,15) atom. The C(29)-C(33,35) bond length is 1.39 Å. The C(29)-N(5) bond length is 1.35 Å. The C(29)-H(13,15) bond length is 1.09 Å. In the twenty-second C site, C(30) is bonded in a distorted trigonal planar geometry to one C(34), one N(6), and one H(14) atom. The C(30)-C(34) bond length is 1.39 Å. The C(30)-N(6) bond length is 1.35 Å. The C(30)-H(14) bond length is 1.09 Å. In the twenty-third C site, C(31,32) is bonded in a distorted trigonal planar geometry to one C(33,35); one N(7); and one H(13,15) atom. The C(31,32)-C(33,35) bond length is 1.39 Å. The C(31,32)-N(7) bond length is 1.35 Å. The C(31,32)-H(13,15) bond length is 1.09 Å. In the twenty-fourth C site, C(33,35) is bonded in a distorted single-bond geometry to one C(17,18,19,20); one C(29); and one H(17,18,19,20) atom. The C(33,35)-H(17,18,19,20) bond length is 1.09 Å. In the twenty-fifth C site, C(34) is bonded in a distorted single-bond geometry to one C(17,18,19,20); one C(30); and one H(17,18,19,20) atom. The C(34)-C(17,18,19,20) bond length is 1.40 Å. The C(34)-H(17,18,19,20) bond length is 1.09 Å. In the twenty-sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(17,18,19,20); one C(31,32); and one H(17,18,19,20) atom. The C(36)-C(17,18,19,20) bond length is 1.40 Å. The C(36)-C(31,32) bond length is 1.39 Å. The C(36)-H(17,18,19,20) bond length is 1.09 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one C(13) and one C(5,6,8) atom. In the second N site, N(2) is bonded in a water-like geometry to one C(14) and one C(5,6,8) atom. The N(2)-C(5,6,8) bond length is 1.37 Å. In the third N site, N(3) is bonded in a water-like geometry to one C(15) and one C(7) atom. In the fourth N site, N(4) is bonded in a water-like geometry to one C(16) and one C(5,6,8) atom. The N(4)-C(5,6,8) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(1), one C(25), and one C(29) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(2), one C(26), and one C(30) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Zn(3); one C(27,28); and one C(31,32) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Zn(4); one C(27,28); and one C(31,32) atom. The N(8)-C(27,28) bond length is 1.35 Å. The N(8)-C(31,32) bond length is 1.35 Å. There are seventeen inequivalent H sites. In the first H site, H(1,2,4) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(5,6,7,8) is bonded in a single-bond geometry to one C(21,23,24) atom. In the fourth H site, H(9,10,11) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(27,28) atom. The H(12)-C(27,28) bond length is 1.09 Å. In the sixth H site, H(13,15) is bonded in a single-bond geometry to one C(29) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(30) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(31,32) atom. The H(16)-C(31,32) bond length is 1.09 Å. In the ninth H site, H(17,18,19,20) is bonded in a single-bond geometry to one C(33,35) atom. In the tenth H site, H(21) is bonded in a distorted single-bond geometry to one O(8) and one O(9) atom. The H(21)-O(8) bond length is 1.68 Å. The H(21)-O(9) bond length is 0.99 Å. In the eleventh H site, H(22) is bonded in a distorted single-bond geometry to one O(10) and one O(7) atom. The H(22)-O(10) bond length is 0.99 Å. The H(22)-O(7) bond length is 1.68 Å. In the twelfth H site, H(23) is bonded in a distorted single-bond geometry to one O(11) and one O(6) atom. The H(23)-O(11) bond length is 1.00 Å. The H(23)-O(6) bond length is 1.68 Å. In the thirteenth H site, H(24) is bonded in a distorted single-bond geometry to one O(12) and one O(5) atom. The H(24)-O(12) bond length is 1.00 Å. The H(24)-O(5) bond length is 1.68 Å. In the fourteenth H site, H(25) is bonded in a distorted linear geometry to one O(6) and one O(9) atom. The H(25)-O(6) bond length is 1.65 Å. The H(25)-O(9) bond length is 1.00 Å. In the fifteenth H site, H(26) is bonded in a distorted linear geometry to one O(10) and one O(5) atom. The H(26)-O(10) bond length is 1.00 Å. The H(26)-O(5) bond length is 1.66 Å. In the sixteenth H site, H(27) is bonded in a distorted linear geometry to one O(11) and one O(8) atom. The H(27)-O(11) bond length is 1.00 Å. The H(27)-O(8) bond length is 1.66 Å. In the seventeenth H site, H(28) is bonded in a distorted linear geometry to one O(12) and one O(7) atom. The H(28)-O(12) bond length is 1.00 Å. The H(28)-O(7) bond length is 1.66 Å. There are two inequivalent S sites. In the first S site, S(1,2,4) is bonded in an L-shaped geometry to one C(13) and one C(9) atom. In the second S site, S(3) is bonded in an L-shaped geometry to one C(11) and one C(15) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Zn(4) and one C(1) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Zn(3) and one C(2) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Zn(2) and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Zn(1) and one C(4) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Zn(4), one C(1), one H(24), and one H(26) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Zn(3), one C(2), one H(23), and one H(25) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Zn(2), one C(3), one H(22), and one H(28) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Zn(1), one C(4), one H(21), and one H(27) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Zn(1), one H(21), and one H(25) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Zn(2), one H(22), and one H(26) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Zn(3), one H(23), and one H(27) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Zn(4), one H(24), and one H(28) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Zn(1) and one Zn(3) atom. In the second F site, F(2) is bonded in a linear geometry to one Zn(2) and one Zn(4) atom. In the third F site, F(3) is bonded in a linear geometry to one Zn(1) and one Zn(3) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zn(2) and one Zn(4) atom. Linkers: 4 [O]C(=O)c1csc(-c2ccncc2)n1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 1.99 A, density 1.94 g/cm3, surface area 3731.73 m2/g, accessible volume 0.10 cm3/g