UC8NH6O6(CH2)7 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of fourteen 02329_fluka molecules and one UC8NH6O6 cluster. In the UC8NH6O6 cluster, U(1) is bonded in a distorted pentagonal bipyramidal geometry to one N(1), one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The U(1)-N(1) bond length is 2.56 Å. The U(1)-O(1) bond length is 1.81 Å. The U(1)-O(2) bond length is 1.81 Å. The U(1)-O(3) bond length is 2.43 Å. The U(1)-O(4) bond length is 2.47 Å. The U(1)-O(5) bond length is 2.35 Å. The U(1)-O(6) bond length is 2.27 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(1) atom. The C(1)-C(4) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(3) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.50 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one C(5), one H(5), and one H(6) atom. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(7)-O(3) bond length is 1.28 Å. The C(7)-O(4) bond length is 1.28 Å. In the eighth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(15)-O(5) bond length is 1.27 Å. The C(15)-O(6) bond length is 1.28 Å. N(1) is bonded in a distorted trigonal planar geometry to one U(1), one C(1), and one C(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one U(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one U(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one U(1) and one C(7) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one U(1) and one C(15) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one U(1) and one C(15) atom. Linkers: 2 [O]C(=O)CCCCCCCC([O])=O ,1 c1cc(CCc2ccncc2)ccn1. Metal clusters: 1 [O][U]12([O])(O[C]O1)O[C]O[U]1([O])([O])(O[C]O1)O[C]O2. The MOF has largest included sphere 2.49 A, density 2.16 g/cm3, surface area 3476.04 m2/g, accessible volume 0.11 cm3/g