ZnC26H16(NO2)6 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC26H16(NO2)6 clusters. Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-N(2) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 1.98 Å. The Zn(1)-O(2) bond length is 1.98 Å. There are twenty inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(3); and one N(5,6) atom. The C(1,2)-C(11,12) bond length is 1.39 Å. The C(1,2)-C(3) bond length is 1.40 Å. The C(1,2)-N(5,6) bond length is 1.47 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(1,2); one C(13,14); and one C(9) atom. The C(3)-C(13,14) bond length is 1.40 Å. The C(3)-C(9) bond length is 1.51 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(1,2); one C(10); and one C(13,14) atom. The C(4)-C(1,2) bond length is 1.40 Å. The C(4)-C(10) bond length is 1.51 Å. The C(4)-C(13,14) bond length is 1.40 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(17,18) and one H(15,16) atom. The C(5)-C(17,18) bond length is 1.46 Å. The C(5)-H(15,16) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(17,18) and one H(15,16) atom. The C(6)-C(17,18) bond length is 1.46 Å. The C(6)-H(15,16) bond length is 1.09 Å. In the sixth C site, C(7,8) is bonded in a distorted single-bond geometry to one C(25,26) and one H(1,2) atom. The C(7,8)-C(25,26) bond length is 1.39 Å. The C(7,8)-H(1,2) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(9)-O(1) bond length is 1.29 Å. The C(9)-O(3) bond length is 1.25 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(4) atom. The C(10)-O(2) bond length is 1.29 Å. The C(10)-O(4) bond length is 1.25 Å. In the ninth C site, C(11,12) is bonded in a distorted single-bond geometry to one C(1,2); one C(25,26); and one H(7,8) atom. The C(11,12)-C(25,26) bond length is 1.39 Å. The C(11,12)-H(7,8) bond length is 1.09 Å. In the tenth C site, C(13,14) is bonded in a distorted single-bond geometry to one C(3) and one H(13,14) atom. The C(13,14)-H(13,14) bond length is 1.09 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(17,18); one C(19); and one H(5,6) atom. The C(15)-C(17,18) bond length is 1.41 Å. The C(15)-C(19) bond length is 1.39 Å. The C(15)-H(5,6) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(17,18); one C(20); and one H(5,6) atom. The C(16)-C(17,18) bond length is 1.41 Å. The C(16)-C(20) bond length is 1.39 Å. The C(16)-H(5,6) bond length is 1.09 Å. In the thirteenth C site, C(17,18) is bonded in a trigonal planar geometry to one C(15), one C(23), and one C(5) atom. The C(17,18)-C(23) bond length is 1.41 Å. In the fourteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(15); one N(1); and one H(3,4) atom. The C(19)-N(1) bond length is 1.35 Å. The C(19)-H(3,4) bond length is 1.09 Å. In the fifteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(16); one N(2); and one H(3,4) atom. The C(20)-N(2) bond length is 1.35 Å. The C(20)-H(3,4) bond length is 1.09 Å. In the sixteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9,10) atom. The C(21)-N(1) bond length is 1.35 Å. The C(21)-H(9,10) bond length is 1.09 Å. In the seventeenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9,10) atom. The C(22)-N(2) bond length is 1.35 Å. The C(22)-H(9,10) bond length is 1.09 Å. In the eighteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(17,18) and one H(11,12) atom. The C(23)-H(11,12) bond length is 1.09 Å. In the nineteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(17,18) and one H(11,12) atom. The C(24)-C(17,18) bond length is 1.41 Å. The C(24)-H(11,12) bond length is 1.09 Å. In the twentieth C site, C(25,26) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(7,8); and one N(3,4) atom. The C(25,26)-N(3,4) bond length is 1.47 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(19), and one C(21) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(20), and one C(22) atom. In the third N site, N(3,4) is bonded in a trigonal planar geometry to one C(25,26); one O(5,6); and one O(9,10) atom. The N(3,4)-O(5,6) bond length is 1.24 Å. The N(3,4)-O(9,10) bond length is 1.24 Å. In the fourth N site, N(5,6) is bonded in a trigonal planar geometry to one C(1,2); one O(11,12); and one O(7,8) atom. The N(5,6)-O(11,12) bond length is 1.24 Å. The N(5,6)-O(7,8) bond length is 1.24 Å. There are eight inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(7,8) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(19) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(11,12) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(13,14) is bonded in a single-bond geometry to one C(13,14) atom. In the eighth H site, H(15,16) is bonded in a single-bond geometry to one C(5) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(10) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth O site, O(5,6) is bonded in a single-bond geometry to one N(3,4) atom. In the sixth O site, O(7,8) is bonded in a single-bond geometry to one N(5,6) atom. In the seventh O site, O(9,10) is bonded in a single-bond geometry to one N(3,4) atom. In the eighth O site, O(11,12) is bonded in a single-bond geometry to one N(5,6) atom. Linkers: 2 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.96 A, density 1.69 g/cm3, surface area 4334.40 m2/g, accessible volume 0.11 cm3/g