ZnC17NH10O6C5H5NCH3 crystallizes in the triclinic P-1 space group. The structure consists of two allylamine, n,n,2-trimethyl- molecules inside a ZnC17NH10O6 framework. In the ZnC17NH10O6 framework, Zn(1) is bonded in a distorted trigonal bipyramidal geometry to one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(2) bond length is 2.05 Å. The Zn(1)-O(1) bond length is 2.16 Å. The Zn(1)-O(2) bond length is 1.95 Å. The Zn(1)-O(3) bond length is 1.98 Å. The Zn(1)-O(4) bond length is 2.45 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(6), one C(7), and one C(8) atom. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.48 Å. The C(1)-C(8) bond length is 1.40 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(2) atom. The C(2)-C(5) bond length is 1.50 Å. The C(2)-O(1) bond length is 1.27 Å. The C(2)-O(2) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4), one C(5), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(5) bond length is 1.40 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(6), and one C(9) atom. The C(4)-C(6) bond length is 1.40 Å. The C(4)-C(9) bond length is 1.50 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(8) atom. The C(5)-C(8) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(4), and one H(2) atom. The C(6)-H(2) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(17) atom. The C(7)-C(10) bond length is 1.41 Å. The C(7)-C(17) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(3) atom. The C(8)-H(3) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(9)-O(3) bond length is 1.29 Å. The C(9)-O(4) bond length is 1.26 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(10)-H(4) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(13) and one H(5) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-H(5) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(5), and one O(6) atom. The C(12)-C(13) bond length is 1.47 Å. The C(12)-O(5) bond length is 1.26 Å. The C(12)-O(6) bond length is 1.32 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(18) atom. The C(13)-C(18) bond length is 1.41 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6,16) atom. The C(14)-N(2) bond length is 1.35 Å. The C(14)-H(6,16) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18), one C(7), and one H(9) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(9) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(13), one C(17), and one H(10) atom. The C(18)-H(10) bond length is 1.09 Å. In the seventeenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6,16) atom. The C(22)-N(2) bond length is 1.35 Å. The C(22)-H(6,16) bond length is 1.09 Å. N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(14), and one C(22) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6,16) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(18) is bonded in a linear geometry to one O(5) and one O(6) atom. The H(18)-O(5) bond length is 1.52 Å. The H(18)-O(6) bond length is 1.04 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(9) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Zn(1) and one C(9) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(12) and one H(18) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one C(12) and one H(18) atom. Linkers: 1 c1cc(CN2CCN(Cc3ccncc3)CC2)ccn1 ,2 [O]C(=O)c1cc(C([O])=O)cc(-c2ccc(C(=O)O)cc2)c1. Metal clusters: 1 O=[C]O[Zn]1O[C]O[Zn](O[C]=O)O[C]O1. The MOF has largest included sphere 2.80 A, density 1.58 g/cm3, surface area 4343.72 m2/g, accessible volume 0.18 cm3/g