CoC40H50(NO2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoC40H50(NO2)2 cluster. Co(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. Both Co(1)-N(1) bond lengths are 1.92 Å. Both Co(1)-O(1) bond lengths are 1.88 Å. Both Co(1)-O(2) bond lengths are 1.88 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.45 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one O(2) atom. The C(7)-O(2) bond length is 1.33 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one O(1) atom. The C(8)-C(9) bond length is 1.42 Å. The C(8)-O(1) bond length is 1.34 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(8) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(13) bond length is 1.53 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(6) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-H(6) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(17) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(17) bond length is 1.53 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a tetrahedral geometry to one C(14), one C(15), one C(16), and one C(9) atom. The C(13)-C(14) bond length is 1.54 Å. The C(13)-C(15) bond length is 1.54 Å. The C(13)-C(16) bond length is 1.54 Å. In the fourteenth C site, C(14) is bonded in a trigonal non-coplanar geometry to one C(13), one H(10), one H(8), and one H(9) atom. The C(14)-H(10) bond length is 1.10 Å. The C(14)-H(8) bond length is 1.10 Å. The C(14)-H(9) bond length is 1.10 Å. In the fifteenth C site, C(15) is bonded in a trigonal non-coplanar geometry to one C(13), one H(11), one H(12), and one H(13) atom. The C(15)-H(11) bond length is 1.10 Å. The C(15)-H(12) bond length is 1.10 Å. The C(15)-H(13) bond length is 1.10 Å. In the sixteenth C site, C(16) is bonded in a trigonal non-coplanar geometry to one C(13), one H(14), one H(15), and one H(16) atom. The C(16)-H(14) bond length is 1.10 Å. The C(16)-H(15) bond length is 1.10 Å. The C(16)-H(16) bond length is 1.10 Å. In the seventeenth C site, C(17) is bonded in a tetrahedral geometry to one C(11), one C(18), one C(19), and one C(20) atom. The C(17)-C(18) bond length is 1.54 Å. The C(17)-C(19) bond length is 1.54 Å. The C(17)-C(20) bond length is 1.53 Å. In the eighteenth C site, C(18) is bonded in a trigonal non-coplanar geometry to one C(17), one H(17), one H(18), and one H(19) atom. The C(18)-H(17) bond length is 1.10 Å. The C(18)-H(18) bond length is 1.10 Å. The C(18)-H(19) bond length is 1.10 Å. In the nineteenth C site, C(19) is bonded in a trigonal non-coplanar geometry to one C(17), one H(20), one H(21), and one H(22) atom. The C(19)-H(20) bond length is 1.10 Å. The C(19)-H(21) bond length is 1.10 Å. The C(19)-H(22) bond length is 1.10 Å. In the twentieth C site, C(20) is bonded in a trigonal non-coplanar geometry to one C(17), one H(23), one H(24), and one H(25) atom. The C(20)-H(23) bond length is 1.10 Å. The C(20)-H(24) bond length is 1.10 Å. The C(20)-H(25) bond length is 1.10 Å. N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(5) atom. There are twenty-five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(18) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(19) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(19) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(19) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(20) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(20) atom. In the twenty-fifth H site, H(25) is bonded in a single-bond geometry to one C(20) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Co(1) and one C(8) atom. In the second O site, O(2) is bonded in a water-like geometry to one Co(1) and one C(7) atom. Linkers: 2 [c]1cc(/C=C/c2ccncc2)ccn1 ,1 C(=C/c1ccncc1)\c1ccncc1 ,2 CC(C)(C)c1cc([O])c([O])c(C(C)(C)C)c1. Metal clusters: 1 [C]1=[C]O[Co]2(O1)O[C]=[C]O2. The MOF has largest included sphere 3.90 A, density 1.11 g/cm3, surface area 5899.50 m2/g, accessible volume 0.36 cm3/g