(CH2)4CuC12H14S2(NO4)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two CuC12H14S2(NO4)2 clusters. In each CuC12H14S2(NO4)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(4) atoms. Both Cu(1)-O(1) bond lengths are 1.97 Å. Both Cu(1)-O(4) bond lengths are 1.96 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one S(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(3) bond length is 1.40 Å. The C(1)-S(1) bond length is 1.78 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(4) atom. The C(4)-N(1) bond length is 1.33 Å. The C(4)-O(4) bond length is 1.27 Å. In the fifth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(7), and one H(8) atom. The C(7)-N(1) bond length is 1.46 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.10 Å. In the sixth C site, C(8) is bonded in a tetrahedral geometry to one N(1), one H(10), one H(11), and one H(9) atom. The C(8)-N(1) bond length is 1.45 Å. The C(8)-H(10) bond length is 1.09 Å. The C(8)-H(11) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. N(1) is bonded in a trigonal planar geometry to one C(4), one C(7), and one C(8) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(8) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.52 Å. The S(1)-O(2) bond length is 1.46 Å. The S(1)-O(3) bond length is 1.46 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(4) atom. Linkers: 2 [O]S([O])([O])c1ccc(S([O])([O])[O])cc1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 1.52 A, density 1.76 g/cm3, surface area 4551.23 m2/g, accessible volume 0.12 cm3/g