CoH8(CO3)4(NCH2(CH2)3CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dimethyl(propan-2-yl)azanium molecules and one CoH8(CO3)4 cluster. In the CoH8(CO3)4 cluster, Co(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(5), and two equivalent O(6) atoms. Both Co(1)-O(1) bond lengths are 1.90 Å. Both Co(1)-O(5) bond lengths are 1.96 Å. Both Co(1)-O(6) bond lengths are 2.42 Å. There are two inequivalent C sites. In the first C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(4)-O(3) bond length is 1.27 Å. The C(4)-O(4) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(2)-O(1) bond length is 1.28 Å. The C(2)-O(2) bond length is 1.26 Å. There are four inequivalent H sites. In the first H site, H(11) is bonded in a distorted linear geometry to one O(3) and one O(5) atom. The H(11)-O(3) bond length is 1.59 Å. The H(11)-O(5) bond length is 1.02 Å. In the second H site, H(12) is bonded in a single-bond geometry to one O(5) atom. The H(12)-O(5) bond length is 0.99 Å. In the third H site, H(13) is bonded in a single-bond geometry to one O(6) atom. The H(13)-O(6) bond length is 1.00 Å. In the fourth H site, H(14) is bonded in a single-bond geometry to one O(6) atom. The H(14)-O(6) bond length is 0.98 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(4) and one H(11) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one C(4) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Co(1), one H(11), and one H(12) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Co(1), one H(13), and one H(14) atom. Linkers: 2 O=[C]C[NH]([C@@H]1CC[C@H](CC1)[NH](CC(=O)[O])CC(=O)[O])CC(=O)[O] ,1 [O]C(=O)C[NH]([C@@H]1CC[C@H](CC1)[NH](CC(=O)[O])CC(=O)[O])CC(=O)[O]. Metal clusters: 1 O.O.O=[C]O[Co]O[C]=O. The MOF has largest included sphere 2.20 A, density 1.62 g/cm3, surface area 3691.26 m2/g, accessible volume 0.15 cm3/g