AgC3H5(NO)2 is Cubic alpha N2-like structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of four AgC3H5(NO)2 clusters. Ag(1) is bonded in a 2-coordinate geometry to one N(1) and one N(2) atom. The Ag(1)-N(1) bond length is 2.18 Å. The Ag(1)-N(2) bond length is 2.10 Å. There are three inequivalent C sites. In the first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(1) atom. The C(3)-N(2) bond length is 1.33 Å. The C(3)-O(1) bond length is 1.27 Å. In the second C site, C(1) is bonded in a distorted water-like geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.46 Å. The C(1)-H(1) bond length is 1.10 Å. In the third C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one H(2), one H(3), and one O(2) atom. The C(2)-H(2) bond length is 1.09 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-O(2) bond length is 1.45 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Ag(1), one C(1), one H(4), and one H(5) atom. The N(1)-H(4) bond length is 1.04 Å. The N(1)-H(5) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(3), and one O(2) atom. The N(2)-O(2) bond length is 1.45 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(2) and one N(2) atom. Linkers: 4 N[C@H]1CO[N]C1=O. Metal clusters: 4 [Ag]. The MOF has largest included sphere 2.16 A, density 2.80 g/cm3, surface area 2598.39 m2/g, accessible volume 0.06 cm3/g