CdC8H8(NO)4(CH)4(CH2CO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four dimethyl ether molecules, and one CdC8H8(NO)4 cluster. In the CdC8H8(NO)4 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(3), one O(1), one O(2), and two equivalent O(6) atoms. The Cd(1)-N(1) bond length is 2.26 Å. The Cd(1)-N(3) bond length is 2.30 Å. The Cd(1)-O(1) bond length is 2.53 Å. The Cd(1)-O(2) bond length is 2.42 Å. There is one shorter (2.29 Å) and one longer (2.63 Å) Cd(1)-O(6) bond length. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(10)-O(5) bond length is 1.26 Å. The C(10)-O(6) bond length is 1.28 Å. In the third C site, C(11) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(9) atom. The C(11)-N(1) bond length is 1.33 Å. The C(11)-N(2) bond length is 1.35 Å. The C(11)-H(9) bond length is 1.08 Å. In the fourth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(2), and one H(10) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-N(2) bond length is 1.38 Å. The C(12)-H(10) bond length is 1.08 Å. In the fifth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(1), and one H(11) atom. The C(13)-N(1) bond length is 1.38 Å. The C(13)-H(11) bond length is 1.09 Å. In the sixth C site, C(14) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(12) atom. The C(14)-N(3) bond length is 1.34 Å. The C(14)-N(4) bond length is 1.35 Å. The C(14)-H(12) bond length is 1.08 Å. In the seventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(4), and one H(13) atom. The C(15)-C(16) bond length is 1.37 Å. The C(15)-N(4) bond length is 1.38 Å. The C(15)-H(13) bond length is 1.08 Å. In the eighth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(3), and one H(14) atom. The C(16)-N(3) bond length is 1.38 Å. The C(16)-H(14) bond length is 1.08 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(13) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(11), one C(12), and one H(15) atom. The N(2)-H(15) bond length is 1.04 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(14), and one C(16) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(14), one C(15), and one H(16) atom. The N(4)-H(16) bond length is 1.04 Å. There are eight inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(15) is bonded in a distorted single-bond geometry to one N(2) atom. In the eighth H site, H(16) is bonded in a distorted single-bond geometry to one N(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to one C(10) atom. In the fourth O site, O(6) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one C(10) atom. Linkers: 2 [O]C(=O)COc1cccc(OCC([O])=O)c1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 2.45 A, density 1.75 g/cm3, surface area 4308.22 m2/g, accessible volume 0.14 cm3/g