AgC9H5(NO2)2(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a AgC9H5(NO2)2 framework. In the AgC9H5(NO2)2 framework, Ag(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(3), and one O(4) atom. The Ag(1)-N(1) bond length is 2.33 Å. The Ag(1)-N(2) bond length is 2.21 Å. The Ag(1)-O(1) bond length is 2.62 Å. The Ag(1)-O(3) bond length is 2.52 Å. The Ag(1)-O(4) bond length is 2.51 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.49 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.22 Å. The C(6)-O(2) bond length is 1.36 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one O(2) atom. The C(9)-C(10) bond length is 1.42 Å. The C(9)-O(2) bond length is 1.41 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(9) atom. The C(10)-C(10) bond length is 1.44 Å. The C(10)-C(11) bond length is 1.42 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one O(3), and one O(4) atom. The N(2)-O(3) bond length is 1.27 Å. The N(2)-O(4) bond length is 1.26 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ag(1) and one C(6) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(6) and one C(9) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(1) and one N(2) atom. Linkers: 2 O=C(Oc1cccc2c(OC(=O)c3ccncc3)cccc12)c1ccncc1 ,2 [C]/C=C(\C=[CH])C(=O)Oc1cccc2c(OC(=O)c3ccncc3)cccc12. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.72 A, density 2.12 g/cm3, surface area 3492.97 m2/g, accessible volume 0.09 cm3/g