ZnC15H14(NO2)2(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one ZnC15H14(NO2)2 cluster. In the ZnC15H14(NO2)2 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 2.07 Å. The Zn(1)-O(2) bond length is 2.07 Å. The Zn(1)-O(3) bond length is 2.09 Å. The Zn(1)-O(4) bond length is 2.08 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(9) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(9) bond length is 1.50 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.51 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted water-like geometry to one C(2), one H(5), and one H(6) atom. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(8)-O(1) bond length is 1.27 Å. The C(8)-O(2) bond length is 1.27 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(3), and one O(4) atom. The C(9)-O(3) bond length is 1.27 Å. The C(9)-O(4) bond length is 1.28 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one H(7) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-N(1) bond length is 1.34 Å. The C(10)-H(7) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(15) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(15) bond length is 1.51 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(9) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(9) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(1), and one H(10) atom. The C(14)-N(1) bond length is 1.35 Å. The C(14)-H(10) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one N(2), one H(11), and one H(12) atom. The C(15)-N(2) bond length is 1.46 Å. The C(15)-H(11) bond length is 1.11 Å. The C(15)-H(12) bond length is 1.10 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(13), and one H(14) atom. The C(16)-N(2) bond length is 1.46 Å. The C(16)-H(13) bond length is 1.11 Å. The C(16)-H(14) bond length is 1.10 Å. In the fifteenth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(15), and one H(16) atom. The C(17)-N(2) bond length is 1.46 Å. The C(17)-H(15) bond length is 1.10 Å. The C(17)-H(16) bond length is 1.11 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(14) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one C(15), one C(16), and one C(17) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(9) atom. Linkers: 1 c1cncc(CN2CCN(Cc3cccnc3)CC2)c1 ,2 [O]C(=O)Cc1ccccc1C([O])=O. Metal clusters: 1 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 2.41 A, density 1.66 g/cm3, surface area 4410.74 m2/g, accessible volume 0.14 cm3/g