(CH)2HgC30H20I2(N2O)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and eight HgC30H20I2(N2O)2 clusters. In each HgC30H20I2(N2O)2 cluster, Hg(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(4), one I(1), and one I(2) atom. The Hg(1)-N(1) bond length is 2.52 Å. The Hg(1)-N(4) bond length is 2.49 Å. The Hg(1)-I(1) bond length is 2.70 Å. The Hg(1)-I(2) bond length is 2.68 Å. There are thirty inequivalent C sites. In the first C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(12) atom. The C(19)-C(18) bond length is 1.42 Å. The C(19)-H(12) bond length is 1.09 Å. In the second C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(15) atom. The C(22)-C(23) bond length is 1.42 Å. The C(22)-H(15) bond length is 1.09 Å. In the third C site, C(23) is bonded in a trigonal planar geometry to one C(18), one C(22), and one C(24) atom. The C(23)-C(18) bond length is 1.44 Å. The C(23)-C(24) bond length is 1.42 Å. In the fourth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one C(25), and one H(16) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-H(16) bond length is 1.09 Å. In the fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(17) atom. The C(25)-H(17) bond length is 1.09 Å. In the sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(17) and one N(3) atom. The C(26)-C(17) bond length is 1.39 Å. The C(26)-N(3) bond length is 1.42 Å. In the seventh C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(28), one N(3), and one O(2) atom. The C(27)-C(28) bond length is 1.50 Å. The C(27)-N(3) bond length is 1.35 Å. The C(27)-O(2) bond length is 1.25 Å. In the eighth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(32) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-C(32) bond length is 1.40 Å. In the ninth C site, C(29) is bonded in a distorted single-bond geometry to one C(28), one C(30), and one H(19) atom. The C(29)-C(30) bond length is 1.39 Å. The C(29)-H(19) bond length is 1.09 Å. In the tenth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one N(4), and one H(20) atom. The C(30)-N(4) bond length is 1.34 Å. The C(30)-H(20) bond length is 1.09 Å. In the eleventh C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(21) atom. The C(31)-N(4) bond length is 1.34 Å. The C(31)-H(21) bond length is 1.09 Å. In the twelfth C site, C(32) is bonded in a distorted single-bond geometry to one C(28) and one H(22) atom. The C(32)-H(22) bond length is 1.09 Å. In the thirteenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the fourteenth C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the fifteenth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.50 Å. In the sixteenth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the seventeenth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the eighteenth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one O(1) atom. The C(6)-N(2) bond length is 1.35 Å. The C(6)-O(1) bond length is 1.25 Å. In the nineteenth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(16), one C(8), and one N(2) atom. The C(7)-C(16) bond length is 1.39 Å. The C(7)-C(8) bond length is 1.42 Å. The C(7)-N(2) bond length is 1.43 Å. In the twentieth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the twenty-first C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(9)-C(10) bond length is 1.42 Å. The C(9)-H(7) bond length is 1.09 Å. In the twenty-second C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-C(15) bond length is 1.44 Å. In the twenty-third C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(8) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-H(8) bond length is 1.09 Å. In the twenty-fourth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(9) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-H(9) bond length is 1.09 Å. In the twenty-fifth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(13)-H(10) bond length is 1.09 Å. In the twenty-sixth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(11) atom. The C(14)-C(15) bond length is 1.42 Å. The C(14)-H(11) bond length is 1.09 Å. In the twenty-seventh C site, C(15) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(16) atom. The C(15)-C(16) bond length is 1.43 Å. In the twenty-eighth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(7) atom. The C(16)-C(17) bond length is 1.49 Å. In the twenty-ninth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(26) atom. The C(17)-C(18) bond length is 1.43 Å. In the thirtieth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(23) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Hg(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(6), one C(7), and one H(5) atom. The N(2)-H(5) bond length is 1.03 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(26), one C(27), and one H(18) atom. The N(3)-H(18) bond length is 1.03 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Hg(1), one C(30), and one C(31) atom. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one N(3) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(30) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(31) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(32) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(27) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Hg(1) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Hg(1) atom. Linkers: 1 O=C(Nc1ccc2ccccc2c1-c1c(NC(=O)c2ccncc2)ccc2ccccc12)c1ccncc1. Metal clusters: . The MOF has largest included sphere 4.82 A, density 1.70 g/cm3, surface area 3553.37 m2/g, accessible volume 0.25 cm3/g