CdC12H9(N2O)3CH3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and four CdC12H9(N2O)3 clusters. In each CdC12H9(N2O)3 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(4), one N(6), one O(1), one O(2), and one O(3) atom. The Cd(1)-N(1) bond length is 2.44 Å. The Cd(1)-N(4) bond length is 2.25 Å. The Cd(1)-N(6) bond length is 2.26 Å. The Cd(1)-O(1) bond length is 2.45 Å. The Cd(1)-O(2) bond length is 2.28 Å. The Cd(1)-O(3) bond length is 2.73 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.34 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one N(2) atom. The C(4)-C(5) bond length is 1.48 Å. The C(4)-N(1) bond length is 1.35 Å. The C(4)-N(2) bond length is 1.34 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(3), and one N(4) atom. The C(5)-N(3) bond length is 1.35 Å. The C(5)-N(4) bond length is 1.31 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(5), and one O(1) atom. The C(6)-C(7) bond length is 1.49 Å. The C(6)-N(5) bond length is 1.34 Å. The C(6)-O(1) bond length is 1.28 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.40 Å. The C(7)-C(8) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(8)-H(4) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(5) atom. The C(9)-N(6) bond length is 1.35 Å. The C(9)-H(5) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one N(6) and one H(6) atom. The C(10)-N(6) bond length is 1.35 Å. The C(10)-H(6) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(12)-O(2) bond length is 1.29 Å. The C(12)-O(3) bond length is 1.26 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(3) and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(5), one H(11), and one H(12) atom. The N(3)-H(11) bond length is 1.03 Å. The N(3)-H(12) bond length is 1.01 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(5), and one N(5) atom. The N(4)-N(5) bond length is 1.35 Å. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one C(6) and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(9) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one N(3) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one N(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(6) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1) and one C(12) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cd(1) and one C(12) atom. Linkers: 2 CC(=O)O[Cd]12(OC(=NN2[C](C2=NC=C[CH]N12)N)c1ccncc1)N1[CH]C=C(C=C1)C(=O)[N][N]C(=[NH2])c1ncccn1. Metal clusters: 2 CC(=O)O[Cd][O]. The MOF has largest included sphere 1.98 A, density 1.95 g/cm3, surface area 3860.61 m2/g, accessible volume 0.10 cm3/g