ZnC9H6(N3O)2CHCH3 crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of four 02329_fluka molecules and four 02329_fluka molecules inside a ZnC9H6(N3O)2 framework. In the ZnC9H6(N3O)2 framework, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one N(6), and one O(1) atom. The Zn(1)-N(1) bond length is 2.00 Å. The Zn(1)-N(3) bond length is 2.01 Å. The Zn(1)-N(6) bond length is 2.02 Å. The Zn(1)-O(1) bond length is 1.96 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(7) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-C(3) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.41 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(2)-O(1) bond length is 1.30 Å. The C(2)-O(2) bond length is 1.26 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-N(1) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one N(2) atom. The C(5)-N(2) bond length is 1.38 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(7)-H(3) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(4) atom. The C(8)-N(1) bond length is 1.33 Å. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(4) bond length is 1.08 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(3), and one N(6) atom. The C(9)-C(10) bond length is 1.49 Å. The C(9)-N(3) bond length is 1.35 Å. The C(9)-N(6) bond length is 1.35 Å. In the ninth C site, C(10) is bonded in a distorted water-like geometry to one C(9), one H(5), and one H(6) atom. The C(10)-H(5) bond length is 1.10 Å. The C(10)-H(6) bond length is 1.10 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(4), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(5), one C(8), and one H(10) atom. The N(2)-H(10) bond length is 1.03 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Zn(1), one C(9), and one N(4) atom. The N(3)-N(4) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one N(3) and one N(5) atom. The N(4)-N(5) bond length is 1.30 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.36 Å. In the sixth N site, N(6) is bonded in a 3-coordinate geometry to one Zn(1), one C(9), and one N(5) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one N(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. Linkers: 4 [O]C(=O)c1ccc2[nH]cnc2c1 ,4 CCC1=NN=N[N]1. Metal clusters: 4 O=[C]O[Zn]. The MOF has largest included sphere 2.57 A, density 1.68 g/cm3, surface area 4189.97 m2/g, accessible volume 0.14 cm3/g