ReAgC10N2H18S2O5 is Indium-like structured and crystallizes in the orthorhombic C222_1 space group. The structure is zero-dimensional and consists of four ReAgC10N2H18S2O5 clusters. Re(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one S(1), one S(2), one O(1), and one O(2) atom. The Re(1)-N(1) bond length is 2.24 Å. The Re(1)-N(2) bond length is 2.16 Å. The Re(1)-S(1) bond length is 2.30 Å. The Re(1)-S(2) bond length is 2.27 Å. The Re(1)-O(1) bond length is 1.71 Å. The Re(1)-O(2) bond length is 2.22 Å. Ag(1) is bonded in a distorted trigonal planar geometry to one S(1), one S(2), and one O(4) atom. The Ag(1)-S(1) bond length is 2.47 Å. The Ag(1)-S(2) bond length is 2.47 Å. The Ag(1)-O(4) bond length is 2.30 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one C(2), one C(3), one C(4), and one S(1) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-C(3) bond length is 1.53 Å. The C(1)-C(4) bond length is 1.55 Å. The C(1)-S(1) bond length is 1.87 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one H(5), one H(6), and one H(7) atom. The C(2)-H(5) bond length is 1.10 Å. The C(2)-H(6) bond length is 1.10 Å. The C(2)-H(7) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one H(10), one H(8), and one H(9) atom. The C(3)-H(10) bond length is 1.10 Å. The C(3)-H(8) bond length is 1.10 Å. The C(3)-H(9) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a 2-coordinate geometry to one C(1), one N(1), and one H(11) atom. The C(4)-N(1) bond length is 1.48 Å. The C(4)-H(11) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(5)-O(2) bond length is 1.29 Å. The C(5)-O(3) bond length is 1.25 Å. In the sixth C site, C(6) is bonded in a tetrahedral geometry to one C(7), one C(8), one C(9), and one S(2) atom. The C(6)-C(7) bond length is 1.53 Å. The C(6)-C(8) bond length is 1.53 Å. The C(6)-C(9) bond length is 1.54 Å. The C(6)-S(2) bond length is 1.88 Å. In the seventh C site, C(7) is bonded in a trigonal non-coplanar geometry to one C(6), one H(12), one H(13), and one H(14) atom. The C(7)-H(12) bond length is 1.10 Å. The C(7)-H(13) bond length is 1.10 Å. The C(7)-H(14) bond length is 1.10 Å. In the eighth C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(6), one H(15), one H(16), and one H(17) atom. The C(8)-H(15) bond length is 1.10 Å. The C(8)-H(16) bond length is 1.10 Å. The C(8)-H(17) bond length is 1.10 Å. In the ninth C site, C(9) is bonded in a 2-coordinate geometry to one C(6), one N(2), and one H(18) atom. The C(9)-N(2) bond length is 1.50 Å. The C(9)-H(18) bond length is 1.10 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(10)-O(4) bond length is 1.27 Å. The C(10)-O(5) bond length is 1.26 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Re(1), one C(4), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.03 Å. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Re(1), one C(9), one H(3), and one H(4) atom. The N(2)-H(3) bond length is 1.03 Å. The N(2)-H(4) bond length is 1.04 Å. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(3) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(3) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(4) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(7) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(7) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(7) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(8) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(8) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(8) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(9) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Re(1), one Ag(1), and one C(1) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one Re(1), one Ag(1), and one C(6) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Re(1) and one C(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(1) and one C(10) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(10) atom. Linkers: 8 CC(C)([S])[C@@H](N)C([O])=O. Metal clusters: 4 [Re] ,4 [Ag]. The MOF has largest included sphere 4.70 A, density 1.91 g/cm3, surface area 2820.95 m2/g, accessible volume 0.22 cm3/g