CoC20H12(N3O)4(CH)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CoC20H12(N3O)4 clusters. In each CoC20H12(N3O)4 cluster, Co(1) is bonded in an octahedral geometry to two equivalent N(3), two equivalent N(6), and two equivalent O(1) atoms. Both Co(1)-N(3) bond lengths are 2.16 Å. Both Co(1)-N(6) bond lengths are 2.12 Å. Both Co(1)-O(1) bond lengths are 2.05 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(1) atom. The C(1)-N(2) bond length is 1.32 Å. The C(1)-N(3) bond length is 1.37 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(2) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-N(3) bond length is 1.33 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one N(1) atom. The C(3)-N(1) bond length is 1.42 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one N(4) atom. The C(5)-N(4) bond length is 1.42 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(4) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.51 Å. The C(7)-C(8) bond length is 1.40 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(6) atom. The C(9)-N(4) bond length is 1.35 Å. The C(9)-N(6) bond length is 1.33 Å. The C(9)-H(6) bond length is 1.08 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(7) atom. The C(10)-N(5) bond length is 1.33 Å. The C(10)-N(6) bond length is 1.37 Å. The C(10)-H(7) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(1), and one O(2) atom. The C(11)-O(1) bond length is 1.29 Å. The C(11)-O(2) bond length is 1.25 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one N(2) atom. The N(1)-N(2) bond length is 1.37 Å. In the second N site, N(2) is bonded in a distorted single-bond geometry to one C(1) and one N(1) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Co(1), one C(1), and one C(2) atom. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one C(9), and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(10) and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Co(1), one C(10), and one C(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Co(1) and one C(11) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(11) atom. Linkers: 3 [O]C(=O)c1cc(-n2cncn2)cc(-n2cncn2)c1 ,1 [O]C(=O)c1cc(N2[CH]N=C[N]2)cc(-n2cncn2)c1. Metal clusters: 2 O=[C]O[Co]O[C]=O. The MOF has largest included sphere 5.48 A, density 0.97 g/cm3, surface area 4439.72 m2/g, accessible volume 0.54 cm3/g