Mo4Ag2C12N4H8O13(CH)4 crystallizes in the triclinic P-1 space group. The structure consists of eight 02329_fluka molecules inside a Mo4Ag2C12N4H8O13 framework. In the Mo4Ag2C12N4H8O13 framework, there are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(1), one O(12), one O(13), one O(2), and one O(9) atom. The Mo(1)-O(1) bond length is 1.95 Å. The Mo(1)-O(12) bond length is 1.71 Å. The Mo(1)-O(13) bond length is 2.19 Å. The Mo(1)-O(2) bond length is 1.73 Å. The Mo(1)-O(9) bond length is 1.92 Å. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(1), one O(13), one O(4), one O(8), and two equivalent O(11) atoms. The Mo(2)-O(1) bond length is 2.14 Å. The Mo(2)-O(13) bond length is 1.90 Å. The Mo(2)-O(4) bond length is 1.76 Å. The Mo(2)-O(8) bond length is 1.73 Å. There is one shorter (1.93 Å) and one longer (2.54 Å) Mo(2)-O(11) bond length. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(10), one O(13), one O(5), one O(6), one O(7), and one O(9) atom. The Mo(3)-O(10) bond length is 1.95 Å. The Mo(3)-O(13) bond length is 2.27 Å. The Mo(3)-O(5) bond length is 2.37 Å. The Mo(3)-O(6) bond length is 1.71 Å. The Mo(3)-O(7) bond length is 1.73 Å. The Mo(3)-O(9) bond length is 1.94 Å. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(3), one O(4), and one O(5) atom. The Mo(4)-O(1) bond length is 2.16 Å. The Mo(4)-O(10) bond length is 1.86 Å. The Mo(4)-O(11) bond length is 2.06 Å. The Mo(4)-O(3) bond length is 1.73 Å. The Mo(4)-O(4) bond length is 2.25 Å. The Mo(4)-O(5) bond length is 1.75 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(4), one O(3), and one O(8) atom. The Ag(1)-N(1) bond length is 2.20 Å. The Ag(1)-N(4) bond length is 2.17 Å. The Ag(1)-O(3) bond length is 2.55 Å. The Ag(1)-O(8) bond length is 2.60 Å. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one N(2), one N(3), one O(2), and one O(7) atom. The Ag(2)-N(2) bond length is 2.18 Å. The Ag(2)-N(3) bond length is 2.20 Å. The Ag(2)-O(2) bond length is 2.49 Å. The Ag(2)-O(7) bond length is 2.48 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(2) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.44 Å. The C(1)-N(2) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one N(1) atom. The C(6)-N(1) bond length is 1.37 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(1), and one H(5) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-N(1) bond length is 1.33 Å. The C(7)-H(5) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one N(2), and one H(6) atom. The C(8)-N(2) bond length is 1.33 Å. The C(8)-H(6) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(14), and one N(4) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(14) bond length is 1.44 Å. The C(9)-N(4) bond length is 1.37 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(7) atom. The C(10)-H(7) bond length is 1.09 Å. In the ninth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(10) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-H(10) bond length is 1.09 Å. In the tenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one N(3) atom. The C(14)-N(3) bond length is 1.37 Å. In the eleventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one N(3), and one H(11) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-N(3) bond length is 1.32 Å. The C(15)-H(11) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one N(4), and one H(12) atom. The C(16)-N(4) bond length is 1.33 Å. The C(16)-H(12) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(6), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(2), one C(1), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(2), one C(14), and one C(15) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(1), one C(16), and one C(9) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Mo(1), one Mo(2), and one Mo(4) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Ag(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Mo(4) and one Ag(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Mo(2) and one Mo(4) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Mo(3) and one Mo(4) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Mo(3) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Mo(3) and one Ag(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Mo(2) and one Ag(1) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mo(3) and one Mo(4) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Mo(4) and two equivalent Mo(2) atoms. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Mo(1) atom. In the thirteenth O site, O(13) is bonded in a distorted T-shaped geometry to one Mo(1), one Mo(2), and one Mo(3) atom. Linkers: 4 c1ccc2nccnc2c1. Metal clusters: 4 [Ag] ,8 [Mo]. The MOF has largest included sphere 1.88 A, density 3.12 g/cm3, surface area 2052.17 m2/g, accessible volume 0.05 cm3/g