CoC26H20(N7S)2(CH)4(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 02329_fluka molecules, and one CoC26H20(N7S)2 cluster. In the CoC26H20(N7S)2 cluster, Co(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(4), and two equivalent N(7) atoms. Both Co(1)-N(1) bond lengths are 1.93 Å. Both Co(1)-N(4) bond lengths are 2.26 Å. Both Co(1)-N(7) bond lengths are 1.88 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one N(3) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-N(3) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one N(1) atom. The C(6)-N(1) bond length is 1.39 Å. In the fifth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(5), and one H(6) atom. The C(7)-N(3) bond length is 1.45 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one N(4) atom. The C(8)-C(13) bond length is 1.41 Å. The C(8)-C(9) bond length is 1.41 Å. The C(8)-N(4) bond length is 1.38 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(7) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(7) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(8) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-H(8) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(9) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(9) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(10) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(10) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one N(6) atom. The C(13)-N(6) bond length is 1.37 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(11), and one H(12) atom. The C(14)-N(6) bond length is 1.45 Å. The C(14)-H(11) bond length is 1.10 Å. The C(14)-H(12) bond length is 1.10 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one N(7) and one S(1) atom. The C(16)-N(7) bond length is 1.19 Å. The C(16)-S(1) bond length is 1.62 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Co(1), one C(6), and one N(2) atom. The N(1)-N(2) bond length is 1.31 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.34 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(1), one C(7), and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Co(1), one C(8), and one N(5) atom. The N(4)-N(5) bond length is 1.31 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.35 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one C(13), one C(14), and one N(5) atom. In the seventh N site, N(7) is bonded in a bent 150 degrees geometry to one Co(1) and one C(16) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. S(1) is bonded in a single-bond geometry to one C(16) atom. Linkers: 2 [CH]=[C]N(CCCn1nnc2ccccc21)[N][N] ,2 c1ccc2c(c1)nnn2CCCn1nnc2ccccc21 ,2 [CH]=Cc1[c]nnn1CCCn1nnc2ccccc21. Metal clusters: 1 [Co]. The MOF has largest included sphere 3.44 A, density 1.43 g/cm3, surface area 4810.49 m2/g, accessible volume 0.22 cm3/g