CHSn2C9H14O4CH3CO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four dimethyl ether molecules, and two Sn2C9H14O4 clusters. In each Sn2C9H14O4 cluster, there are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 5-coordinate geometry to one C(10), one C(9), one O(2), one O(4), and one O(5) atom. The Sn(1)-C(10) bond length is 2.13 Å. The Sn(1)-C(9) bond length is 2.13 Å. The Sn(1)-O(2) bond length is 2.20 Å. The Sn(1)-O(4) bond length is 2.41 Å. The Sn(1)-O(5) bond length is 2.06 Å. In the second Sn site, Sn(2) is bonded to one C(11), one C(12), one O(4), and two equivalent O(5) atoms to form distorted edge-sharing SnC2O3 trigonal bipyramids. The Sn(2)-C(11) bond length is 2.13 Å. The Sn(2)-C(12) bond length is 2.13 Å. The Sn(2)-O(4) bond length is 2.30 Å. There is one shorter (2.06 Å) and one longer (2.13 Å) Sn(2)-O(5) bond length. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.31 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one O(4) atom. The C(5)-O(4) bond length is 1.33 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(7)-H(3) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(7), one H(8), and one H(9) atom. The C(9)-H(7) bond length is 1.09 Å. The C(9)-H(8) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(10), one H(11), and one H(12) atom. The C(10)-H(10) bond length is 1.10 Å. The C(10)-H(11) bond length is 1.09 Å. The C(10)-H(12) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one Sn(2), one H(13), one H(14), and one H(15) atom. The C(11)-H(13) bond length is 1.09 Å. The C(11)-H(14) bond length is 1.09 Å. The C(11)-H(15) bond length is 1.10 Å. In the ninth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one Sn(2), one H(16), one H(17), and one H(18) atom. The C(12)-H(16) bond length is 1.10 Å. The C(12)-H(17) bond length is 1.09 Å. The C(12)-H(18) bond length is 1.09 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(12) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Sn(1) and one C(1) atom. In the third O site, O(4) is bonded in a distorted single-bond geometry to one Sn(1), one Sn(2), and one C(5) atom. In the fourth O site, O(5) is bonded in a trigonal planar geometry to one Sn(1) and two equivalent Sn(2) atoms. Linkers: 4 COc1cc(C([O])=O)ccc1[O]. Metal clusters: 2 O=[C]O[Sn]1O[Sn]O1.O=[C]O[Sn]1O[Sn]O1. RCSR code: sql. The MOF has largest included sphere 2.73 A, density 1.97 g/cm3, surface area 3500.79 m2/g, accessible volume 0.17 cm3/g