C3H2CdC11P2H18S4(NO2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one 2,3-dimethyl-1,3-butadiene molecule and one CdC11P2H18S4(NO2)2 cluster. In the CdC11P2H18S4(NO2)2 cluster, Cd(1) is bonded to one N(1), one N(2), one S(1), one S(2), one S(3), and one S(4) atom to form distorted CdS4N2 octahedra that share  an edgeedge with one P(1)S2O2 tetrahedra and  an edgeedge with one P(2)S2O2 tetrahedra. The Cd(1)-N(1) bond length is 2.38 Å. The Cd(1)-N(2) bond length is 2.39 Å. The Cd(1)-S(1) bond length is 2.70 Å. The Cd(1)-S(2) bond length is 2.73 Å. The Cd(1)-S(3) bond length is 2.72 Å. The Cd(1)-S(4) bond length is 2.71 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. The C(3)-C(3) bond length is 1.48 Å. The C(3)-C(4) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(8) bond length is 1.09 Å. In the eighth C site, C(11) is bonded to one H(10), one H(11), one H(9), and one O(1) atom to form CH3O tetrahedra that share  a cornercorner with one P(1)S2O2 tetrahedra. The C(11)-H(10) bond length is 1.10 Å. The C(11)-H(11) bond length is 1.10 Å. The C(11)-H(9) bond length is 1.09 Å. The C(11)-O(1) bond length is 1.45 Å. In the ninth C site, C(12) is bonded to one H(12), one H(13), one H(14), and one O(2) atom to form CH3O tetrahedra that share  a cornercorner with one P(1)S2O2 tetrahedra. The C(12)-H(12) bond length is 1.09 Å. The C(12)-H(13) bond length is 1.10 Å. The C(12)-H(14) bond length is 1.10 Å. The C(12)-O(2) bond length is 1.45 Å. In the tenth C site, C(13) is bonded to one H(15), one H(16), one H(17), and one O(3) atom to form CH3O tetrahedra that share  a cornercorner with one P(2)S2O2 tetrahedra. The C(13)-H(15) bond length is 1.09 Å. The C(13)-H(16) bond length is 1.10 Å. The C(13)-H(17) bond length is 1.10 Å. The C(13)-O(3) bond length is 1.45 Å. In the eleventh C site, C(14) is bonded to one H(18), one H(19), one H(20), and one O(4) atom to form CH3O tetrahedra that share  a cornercorner with one P(2)S2O2 tetrahedra. The C(14)-H(18) bond length is 1.10 Å. The C(14)-H(19) bond length is 1.10 Å. The C(14)-H(20) bond length is 1.10 Å. The C(14)-O(4) bond length is 1.45 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one S(2), one O(1), and one O(2) atom to form distorted PS2O2 tetrahedra that share  a cornercorner with one C(11)H3O tetrahedra,  a cornercorner with one C(12)H3O tetrahedra, and  an edgeedge with one Cd(1)S4N2 octahedra. The P(1)-S(1) bond length is 1.99 Å. The P(1)-S(2) bond length is 1.99 Å. The P(1)-O(1) bond length is 1.62 Å. The P(1)-O(2) bond length is 1.61 Å. In the second P site, P(2) is bonded to one S(3), one S(4), one O(3), and one O(4) atom to form distorted PS2O2 tetrahedra that share  a cornercorner with one C(13)H3O tetrahedra,  a cornercorner with one C(14)H3O tetrahedra, and  an edgeedge with one Cd(1)S4N2 octahedra. The P(2)-S(3) bond length is 2.00 Å. The P(2)-S(4) bond length is 1.99 Å. The P(2)-O(3) bond length is 1.62 Å. The P(2)-O(4) bond length is 1.61 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(6) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(13) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(14) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(14) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(14) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Cd(1) and one P(1) atom. In the second S site, S(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one P(1) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one Cd(1) and one P(2) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one Cd(1) and one P(2) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(11) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(12) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(13) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(14) and one P(2) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 2.10 A, density 1.71 g/cm3, surface area 4566.45 m2/g, accessible volume 0.09 cm3/g