CuC18N4H14O5(CH2)2(CH)4C8NH7O is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 02329_fluka molecules, one n-methylbenzamide molecule, and one CuC18N4H14O5 cluster. In the CuC18N4H14O5 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(2), one N(3), one O(2), one O(4), and one O(6) atom. The Cu(1)-N(2) bond length is 2.01 Å. The Cu(1)-N(3) bond length is 2.00 Å. The Cu(1)-O(2) bond length is 2.01 Å. The Cu(1)-O(4) bond length is 2.04 Å. The Cu(1)-O(6) bond length is 2.31 Å. There are eighteen inequivalent C sites. In the first C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(9)-O(2) bond length is 1.29 Å. The C(9)-O(3) bond length is 1.25 Å. In the second C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(12)-O(4) bond length is 1.29 Å. The C(12)-O(5) bond length is 1.26 Å. In the third C site, C(13) is bonded in a distorted trigonal planar geometry to one N(2) and one H(11) atom. The C(13)-N(2) bond length is 1.35 Å. The C(13)-H(11) bond length is 1.09 Å. In the fourth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(12) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(12) bond length is 1.09 Å. In the fifth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(18) bond length is 1.48 Å. In the sixth C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one H(13) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(13) bond length is 1.09 Å. In the seventh C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(2), and one H(14) atom. The C(17)-N(2) bond length is 1.34 Å. The C(17)-H(14) bond length is 1.09 Å. In the eighth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(15), one C(19), and one N(5) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-N(5) bond length is 1.35 Å. In the ninth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(15) atom. The C(19)-H(15) bond length is 1.09 Å. In the tenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(18) atom. The C(22)-N(5) bond length is 1.34 Å. The C(22)-H(18) bond length is 1.09 Å. In the eleventh C site, C(23) is bonded in a distorted trigonal planar geometry to one C(24), one N(3), and one H(19) atom. The C(23)-C(24) bond length is 1.38 Å. The C(23)-N(3) bond length is 1.35 Å. The C(23)-H(19) bond length is 1.09 Å. In the twelfth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(20) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-H(20) bond length is 1.09 Å. In the thirteenth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(28) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(28) bond length is 1.48 Å. In the fourteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(25), one C(27), and one H(21) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-H(21) bond length is 1.09 Å. In the fifteenth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(26), one N(3), and one H(24) atom. The C(27)-N(3) bond length is 1.35 Å. The C(27)-H(24) bond length is 1.09 Å. In the sixteenth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(25), one C(29), and one N(4) atom. The C(28)-C(29) bond length is 1.41 Å. The C(28)-N(4) bond length is 1.35 Å. In the seventeenth C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(25) atom. The C(29)-H(25) bond length is 1.09 Å. In the eighteenth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(28) atom. The C(32)-N(4) bond length is 1.34 Å. The C(32)-H(28) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(17) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(23), and one C(27) atom. In the third N site, N(4) is bonded in a bent 120 degrees geometry to one C(28) and one C(32) atom. In the fourth N site, N(5) is bonded in a bent 120 degrees geometry to one C(18) and one C(22) atom. There are fourteen inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one O(6) atom. The H(22)-O(6) bond length is 0.99 Å. In the eleventh H site, H(23) is bonded in a single-bond geometry to one O(6) atom. The H(23)-O(6) bond length is 0.99 Å. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(27) atom. In the thirteenth H site, H(25) is bonded in a single-bond geometry to one C(29) atom. In the fourteenth H site, H(28) is bonded in a single-bond geometry to one C(32) atom. There are five inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(9) atom. In the second O site, O(3) is bonded in a single-bond geometry to one C(9) atom. In the third O site, O(4) is bonded in a water-like geometry to one Cu(1) and one C(12) atom. In the fourth O site, O(5) is bonded in a distorted single-bond geometry to one C(12) atom. In the fifth O site, O(6) is bonded in a distorted water-like geometry to one Cu(1), one H(22), and one H(23) atom. Linkers: 1 [O]C(=O)CC[C@H](NC(=O)c1ccccc1)C([O])=O. Metal clusters: 1 [Cu]. The MOF has largest included sphere 2.93 A, density 1.44 g/cm3, surface area 4908.70 m2/g, accessible volume 0.19 cm3/g