CdH8(C4O3)2(CH)4(CH2CO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four dimethyl ether molecules, and two CdH8(C4O3)2 clusters. In each CdH8(C4O3)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom. The Cd(1)-O(1) bond length is 2.28 Å. The Cd(1)-O(2) bond length is 2.28 Å. The Cd(1)-O(3) bond length is 2.57 Å. The Cd(1)-O(4) bond length is 2.57 Å. The Cd(1)-O(7) bond length is 2.30 Å. The Cd(1)-O(8) bond length is 2.30 Å. There are five inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1,2)-C(3) bond length is 1.48 Å. The C(1,2)-O(1) bond length is 1.30 Å. The C(1,2)-O(3) bond length is 1.28 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(1,2); one C(13,14); and one C(5,6) atom. The C(3)-C(13,14) bond length is 1.41 Å. The C(3)-C(5,6) bond length is 1.40 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(1,2); one C(13,14); and one C(5,6) atom. The C(4)-C(1,2) bond length is 1.48 Å. The C(4)-C(13,14) bond length is 1.41 Å. The C(4)-C(5,6) bond length is 1.40 Å. In the fourth C site, C(5,6) is bonded in a distorted single-bond geometry to one C(3) and one H(5,6) atom. The C(5,6)-H(5,6) bond length is 1.09 Å. In the fifth C site, C(13,14) is bonded in a distorted single-bond geometry to one C(3) and one H(11,12) atom. The C(13,14)-H(11,12) bond length is 1.09 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. The H(1)-O(7) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(8) atom. The H(2)-O(8) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(7) atom. The H(3)-O(7) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(8) atom. The H(4)-O(8) bond length is 0.99 Å. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(5,6) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(13,14) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1,2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1,2) atom. The O(2)-C(1,2) bond length is 1.30 Å. In the third O site, O(3) is bonded in a single-bond geometry to one Cd(1) and one C(1,2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cd(1) and one C(1,2) atom. The O(4)-C(1,2) bond length is 1.28 Å. In the fifth O site, O(7) is bonded in a distorted water-like geometry to one Cd(1), one H(1), and one H(3) atom. In the sixth O site, O(8) is bonded in a distorted water-like geometry to one Cd(1), one H(2), and one H(4) atom. Linkers: 2 [O]C(=O)c1ccc(OCCOc2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 O.O.O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 1.87 A, density 1.85 g/cm3, surface area 4096.45 m2/g, accessible volume 0.15 cm3/g