CoC16H14(NO)4CH2CH is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, eight 02329_fluka molecules, and eight CoC16H14(NO)4 clusters. In four of the CoC16H14(NO)4 clusters, Co(1) is bonded in a 5-coordinate geometry to one N(7), one N(8), one O(1), one O(7), and one O(8) atom. The Co(1)-N(7) bond length is 1.98 Å. The Co(1)-N(8) bond length is 2.00 Å. The Co(1)-O(1) bond length is 1.96 Å. The Co(1)-O(7) bond length is 2.50 Å. The Co(1)-O(8) bond length is 1.99 Å. There are sixteen inequivalent C sites. In the first C site, C(32) is bonded in a distorted single-bond geometry to one C(21) and one H(31,32) atom. The C(32)-C(21) bond length is 1.40 Å. The C(32)-H(31,32) bond length is 1.09 Å. In the second C site, C(33) is bonded in a distorted single-bond geometry to one C(21) and one H(31,32) atom. The C(33)-C(21) bond length is 1.40 Å. The C(33)-H(31,32) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the fourth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(8)-O(7) bond length is 1.26 Å. The C(8)-O(8) bond length is 1.30 Å. In the fifth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(7), and one H(17) atom. The C(17)-C(18) bond length is 1.37 Å. The C(17)-N(7) bond length is 1.39 Å. The C(17)-H(17) bond length is 1.08 Å. In the sixth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(3), and one H(18) atom. The C(18)-N(3) bond length is 1.38 Å. The C(18)-H(18) bond length is 1.08 Å. In the seventh C site, C(19) is bonded in a trigonal planar geometry to one N(3), one N(7), and one H(19) atom. The C(19)-N(3) bond length is 1.35 Å. The C(19)-N(7) bond length is 1.34 Å. The C(19)-H(19) bond length is 1.08 Å. In the eighth C site, C(20) is bonded in a distorted trigonal non-coplanar geometry to one C(21), one N(3), one H(20), and one H(21) atom. The C(20)-C(21) bond length is 1.51 Å. The C(20)-N(3) bond length is 1.46 Å. The C(20)-H(20) bond length is 1.10 Å. The C(20)-H(21) bond length is 1.09 Å. In the ninth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(32), and one C(33) atom. In the tenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(23), one N(8), and one H(22) atom. The C(22)-C(23) bond length is 1.37 Å. The C(22)-N(8) bond length is 1.39 Å. The C(22)-H(22) bond length is 1.08 Å. In the eleventh C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(4), and one H(23) atom. The C(23)-N(4) bond length is 1.38 Å. The C(23)-H(23) bond length is 1.08 Å. In the twelfth C site, C(24) is bonded in a trigonal planar geometry to one N(4), one N(8), and one H(24) atom. The C(24)-N(4) bond length is 1.35 Å. The C(24)-N(8) bond length is 1.34 Å. The C(24)-H(24) bond length is 1.09 Å. In the thirteenth C site, C(25) is bonded in a distorted trigonal non-coplanar geometry to one C(26), one N(4), one H(25), and one H(26) atom. The C(25)-C(26) bond length is 1.51 Å. The C(25)-N(4) bond length is 1.45 Å. The C(25)-H(25) bond length is 1.10 Å. The C(25)-H(26) bond length is 1.10 Å. In the fourteenth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(28) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-C(28) bond length is 1.40 Å. In the fifteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(27,28) atom. The C(27)-H(27,28) bond length is 1.09 Å. In the sixteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(26) and one H(27,28) atom. The C(28)-H(27,28) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one C(18), one C(19), and one C(20) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(23), one C(24), and one C(25) atom. In the third N site, N(7) is bonded in a trigonal planar geometry to one Co(1), one C(17), and one C(19) atom. In the fourth N site, N(8) is bonded in a trigonal planar geometry to one Co(1), one C(22), and one C(24) atom. There are twelve inequivalent H sites. In the first H site, H(31,32) is bonded in a single-bond geometry to one C(32) atom. In the second H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the third H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the sixth H site, H(21) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(24) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(25) is bonded in a single-bond geometry to one C(25) atom. In the eleventh H site, H(26) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(27,28) is bonded in a single-bond geometry to one C(27) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(7) is bonded in a single-bond geometry to one Co(1) and one C(8) atom. In the fourth O site, O(8) is bonded in a water-like geometry to one Co(1) and one C(8) atom. In four of the CoC16H14(NO)4 clusters, Co(2) is bonded in a tetrahedral geometry to one N(5), one N(6), one O(4), and one O(5) atom. The Co(2)-N(5) bond length is 2.00 Å. The Co(2)-N(6) bond length is 1.99 Å. The Co(2)-O(4) bond length is 1.97 Å. The Co(2)-O(5) bond length is 1.95 Å. There are sixteen inequivalent C sites. In the first C site, C(29) is bonded in a distorted single-bond geometry to one C(30) and one H(29) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-H(29) bond length is 1.09 Å. In the second C site, C(30) is bonded in a trigonal planar geometry to one C(12), one C(29), and one C(31) atom. The C(30)-C(12) bond length is 1.51 Å. The C(30)-C(31) bond length is 1.40 Å. In the third C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(30) atom. The C(31)-H(30) bond length is 1.09 Å. In the fourth C site, C(34) is bonded in a trigonal planar geometry to one C(16), one C(35), and one C(36) atom. The C(34)-C(16) bond length is 1.51 Å. The C(34)-C(35) bond length is 1.40 Å. The C(34)-C(36) bond length is 1.40 Å. In the fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(34) and one H(33) atom. The C(35)-H(33) bond length is 1.09 Å. In the sixth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(4)-O(3) bond length is 1.26 Å. The C(4)-O(4) bond length is 1.30 Å. In the seventh C site, C(36) is bonded in a distorted single-bond geometry to one C(34) and one H(34) atom. The C(36)-H(34) bond length is 1.09 Å. In the eighth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(7)-O(5) bond length is 1.30 Å. The C(7)-O(6) bond length is 1.25 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(5), and one H(7) atom. The C(9)-N(1) bond length is 1.36 Å. The C(9)-N(5) bond length is 1.34 Å. The C(9)-H(7) bond length is 1.08 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(1), and one H(8) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-N(1) bond length is 1.38 Å. The C(10)-H(8) bond length is 1.08 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(5), and one H(9) atom. The C(11)-N(5) bond length is 1.38 Å. The C(11)-H(9) bond length is 1.08 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(30), one N(1), one H(10), and one H(11) atom. The C(12)-N(1) bond length is 1.47 Å. The C(12)-H(10) bond length is 1.10 Å. The C(12)-H(11) bond length is 1.10 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(6), and one H(12) atom. The C(13)-C(14) bond length is 1.37 Å. The C(13)-N(6) bond length is 1.39 Å. The C(13)-H(12) bond length is 1.08 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(2), and one H(13) atom. The C(14)-N(2) bond length is 1.38 Å. The C(14)-H(13) bond length is 1.08 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one N(2), one N(6), and one H(14) atom. The C(15)-N(2) bond length is 1.36 Å. The C(15)-N(6) bond length is 1.33 Å. The C(15)-H(14) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one C(34), one N(2), one H(15), and one H(16) atom. The C(16)-N(2) bond length is 1.46 Å. The C(16)-H(15) bond length is 1.10 Å. The C(16)-H(16) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(16) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Co(2), one C(11), and one C(9) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one Co(2), one C(13), and one C(15) atom. There are fourteen inequivalent H sites. In the first H site, H(33) is bonded in a single-bond geometry to one C(35) atom. In the second H site, H(34) is bonded in a single-bond geometry to one C(36) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(29) is bonded in a single-bond geometry to one C(29) atom. In the fourteenth H site, H(30) is bonded in a single-bond geometry to one C(31) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(4) atom. In the second O site, O(4) is bonded in a water-like geometry to one Co(2) and one C(4) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Co(2) and one C(7) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(7) atom. Linkers: 4 [O]C(=O)C[C@H](C([O])=O)[C@@H](CC([O])=O)C([O])=O ,8 c1cn(Cc2ccc(Cn3ccnc3)cc2)cn1. Metal clusters: 8 O=[C]O[Co]O[C]=O. The MOF has largest included sphere 5.88 A, density 1.28 g/cm3, surface area 4534.69 m2/g, accessible volume 0.23 cm3/g