ZnC10H9(NO2)2(CH)2 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four ZnC10H9(NO2)2 clusters. In each ZnC10H9(NO2)2 cluster, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 2.07 Å. The Zn(1)-O(2) bond length is 2.12 Å. The Zn(1)-O(3) bond length is 2.08 Å. The Zn(1)-O(4) bond length is 2.06 Å. There are ten inequivalent C sites. In the first C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one N(2), one H(8), and one H(9) atom. The C(9)-C(10) bond length is 1.51 Å. The C(9)-N(2) bond length is 1.45 Å. The C(9)-H(8) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. In the second C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(12) bond length is 1.40 Å. In the third C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(10) atom. The C(11)-H(10) bond length is 1.09 Å. In the fourth C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one H(11) atom. The C(12)-H(11) bond length is 1.09 Å. In the fifth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.27 Å. In the sixth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(4)-O(3) bond length is 1.27 Å. The C(4)-O(4) bond length is 1.28 Å. In the seventh C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one H(3) atom. The C(5)-C(6) bond length is 1.37 Å. The C(5)-N(1) bond length is 1.38 Å. The C(5)-H(3) bond length is 1.08 Å. In the eighth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(2), and one H(4) atom. The C(6)-N(2) bond length is 1.38 Å. The C(6)-H(4) bond length is 1.08 Å. In the ninth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(1), and one N(2) atom. The C(7)-C(8) bond length is 1.48 Å. The C(7)-N(1) bond length is 1.34 Å. The C(7)-N(2) bond length is 1.36 Å. In the tenth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(7), one H(5), one H(6), and one H(7) atom. The C(8)-H(5) bond length is 1.09 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-H(7) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(5), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(6), one C(7), and one C(9) atom. There are nine inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. Linkers: 2 Cc1nccn1Cc1ccc(Cn2ccnc2C)cc1 ,4 [O]C(=O)/C=C/C([O])=O. Metal clusters: 2 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 4.23 A, density 1.51 g/cm3, surface area 4636.11 m2/g, accessible volume 0.21 cm3/g