MnC12H16S2(NO4)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two MnC12H16S2(NO4)2 clusters. In one of the MnC12H16S2(NO4)2 clusters, Mn(1) is bonded in an octahedral geometry to two equivalent N(2), two equivalent O(1), and two equivalent O(7) atoms. Both Mn(1)-N(2) bond lengths are 2.24 Å. Both Mn(1)-O(1) bond lengths are 2.18 Å. Both Mn(1)-O(7) bond lengths are 2.21 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(11), one C(3), and one S(1) atom. The C(1)-C(11) bond length is 1.40 Å. The C(1)-C(3) bond length is 1.40 Å. The C(1)-S(1) bond length is 1.78 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(1) and one H(9) atom. The C(3)-H(9) bond length is 1.09 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(8) and one H(12) atom. The C(6)-C(8) bond length is 1.40 Å. The C(6)-H(12) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one N(2) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-N(2) bond length is 1.42 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(14) atom. The C(10)-H(14) bond length is 1.09 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(1) and one H(15) atom. The C(11)-H(15) bond length is 1.09 Å. N(2) is bonded in a 4-coordinate geometry to one Mn(1), one C(8), one H(6), and one H(8) atom. The N(2)-H(6) bond length is 1.03 Å. The N(2)-H(8) bond length is 1.03 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. The H(1)-O(7) bond length is 0.99 Å. In the second H site, H(3) is bonded in a single-bond geometry to one O(7) atom. The H(3)-O(7) bond length is 0.98 Å. In the third H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(3), and one O(5) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.47 Å. The S(1)-O(5) bond length is 1.48 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one S(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to one S(1) atom. In the fourth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mn(1), one H(1), and one H(3) atom. In one of the MnC12H16S2(NO4)2 clusters, Mn(2) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(2), and two equivalent O(8) atoms. Both Mn(2)-N(1) bond lengths are 2.29 Å. Both Mn(2)-O(2) bond lengths are 2.19 Å. Both Mn(2)-O(8) bond lengths are 2.19 Å. There are six inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one C(12), one C(4), and one S(2) atom. The C(2)-C(12) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.40 Å. The C(2)-S(2) bond length is 1.77 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(10) atom. The C(4)-H(10) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(7) and one H(11) atom. The C(5)-C(7) bond length is 1.40 Å. The C(5)-H(11) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one N(1) atom. The C(7)-C(9) bond length is 1.40 Å. The C(7)-N(1) bond length is 1.42 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(7) and one H(13) atom. The C(9)-H(13) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(2) and one H(16) atom. The C(12)-H(16) bond length is 1.09 Å. N(1) is bonded in a 2-coordinate geometry to one Mn(2), one C(7), one H(5), and one H(7) atom. The N(1)-H(5) bond length is 1.03 Å. The N(1)-H(7) bond length is 1.03 Å. There are eight inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(8) atom. The H(2)-O(8) bond length is 0.99 Å. In the second H site, H(4) is bonded in a single-bond geometry to one O(8) atom. The H(4)-O(8) bond length is 0.98 Å. In the third H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(12) atom. S(2) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one O(2), one O(4), and one O(6) atom. The S(2)-O(2) bond length is 1.49 Å. The S(2)-O(4) bond length is 1.47 Å. The S(2)-O(6) bond length is 1.47 Å. There are four inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(2) and one S(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(6) is bonded in a single-bond geometry to one S(2) atom. In the fourth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one H(2), and one H(4) atom. Linkers: 4 Nc1ccc(S([O])([O])[O])cc1. Metal clusters: 2 N[Mn](N)(O[S@]([O])=O)O[S@]([O])=O.O.O. RCSR code: sql. The MOF has largest included sphere 2.38 A, density 1.75 g/cm3, surface area 3672.06 m2/g, accessible volume 0.17 cm3/g