(ZnC8NH6O4)2(CH2)7 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twenty-eight 02329_fluka molecules and four ZnC8NH6O4 clusters. In each ZnC8NH6O4 cluster, Zn(1) is bonded in a distorted trigonal pyramidal geometry to one N(1), one O(1), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(3) bond length is 1.97 Å. The Zn(1)-O(4) bond length is 2.01 Å. There are eight inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(5)-O(3) bond length is 1.28 Å. The C(5)-O(4) bond length is 1.27 Å. In the second C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one H(7) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-N(1) bond length is 1.35 Å. The C(6)-H(7) bond length is 1.09 Å. In the third C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(8) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(8) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(7), and one C(9) atom. The C(8)-C(11) bond length is 1.50 Å. The C(8)-C(9) bond length is 1.40 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(9) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(9) bond length is 1.09 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(10) atom. The C(10)-N(1) bond length is 1.35 Å. The C(10)-H(10) bond length is 1.09 Å. In the seventh C site, C(11) is bonded in a distorted water-like geometry to one C(8), one H(11), and one H(12) atom. The C(11)-H(11) bond length is 1.10 Å. The C(11)-H(12) bond length is 1.10 Å. In the eighth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(6) atom. There are six inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(5) atom. Linkers: 2 c1cc(CCCc2ccncc2)ccn1 ,4 [O]C(=O)CCCC([O])=O. Metal clusters: 2 O=[C]O[Zn]1O[C]O[Zn](O[C]=O)O[C]O1. The MOF has largest included sphere 2.11 A, density 1.62 g/cm3, surface area 4787.99 m2/g, accessible volume 0.15 cm3/g