CdC14H16(NO)6(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one CdC14H16(NO)6 cluster. In the CdC14H16(NO)6 cluster, Cd(1) is bonded in an octahedral geometry to two equivalent N(2), two equivalent O(1), and two equivalent O(3) atoms. Both Cd(1)-N(2) bond lengths are 2.36 Å. Both Cd(1)-O(1) bond lengths are 2.37 Å. Both Cd(1)-O(3) bond lengths are 2.35 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(1)-C(4) bond length is 1.40 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(2)-C(4) bond length is 1.40 Å. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(3)-C(4) bond length is 1.50 Å. The C(3)-O(1) bond length is 1.29 Å. The C(3)-O(2) bond length is 1.26 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(8) atom. The C(7)-N(1) bond length is 1.34 Å. The C(7)-N(2) bond length is 1.34 Å. The C(7)-H(8) bond length is 1.08 Å. In the sixth C site, C(8) is bonded in a 3-coordinate geometry to one N(1), one H(10), and one H(9) atom. The C(8)-N(1) bond length is 1.46 Å. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(11) atom. The C(9)-N(2) bond length is 1.37 Å. The C(9)-N(3) bond length is 1.33 Å. The C(9)-H(11) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(7), one C(8), and one N(3) atom. The N(1)-N(3) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(7), and one C(9) atom. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(9) and one N(1) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(2) and one O(3) atom. The H(1)-O(2) bond length is 1.60 Å. The H(1)-O(3) bond length is 1.01 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one O(3) atom. The H(12)-O(3) bond length is 1.00 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(3) and one H(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cd(1), one H(1), and one H(12) atom. Linkers: 2 [O][C]c1ccc(C([O])=O)cc1 ,1 [CH]1N=C[N]N1CCCCCCN1[CH]N=C[N]1 ,1 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 1 O.O.O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 1.43 A, density 1.82 g/cm3, surface area 4109.96 m2/g, accessible volume 0.13 cm3/g