CdC9N6H6ClCH crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a CdC9N6H6Cl framework. In the CdC9N6H6Cl framework, Cd(1) is bonded in a 5-coordinate geometry to one N(1), one N(3), one N(6), and two equivalent Cl(1) atoms. The Cd(1)-N(1) bond length is 2.25 Å. The Cd(1)-N(3) bond length is 2.28 Å. The Cd(1)-N(6) bond length is 2.38 Å. There is one shorter (2.48 Å) and one longer (2.89 Å) Cd(1)-Cl(1) bond length. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(1) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one N(2) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(9) bond length is 1.39 Å. The C(4)-N(2) bond length is 1.42 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(6) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.46 Å. The C(8)-C(9) bond length is 1.40 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(8), one N(3), and one N(6) atom. The C(10)-N(3) bond length is 1.35 Å. The C(10)-N(6) bond length is 1.35 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one N(4) atom. The N(3)-N(4) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one N(3) and one N(5) atom. The N(4)-N(5) bond length is 1.31 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.36 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one N(5) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. Cl(1) is bonded in an L-shaped geometry to two equivalent Cd(1) atoms. Linkers: 3 c1cc(C2=NN=N[N]2)cc(-n2ccnc2)c1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 1.58 A, density 2.17 g/cm3, surface area 3535.43 m2/g, accessible volume 0.06 cm3/g