(CH)2ZnC28H24S2(N5O2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and four ZnC28H24S2(N5O2)2 clusters. In each ZnC28H24S2(N5O2)2 cluster, Zn(1) is bonded to one N(5), one N(6), two equivalent N(1), and two equivalent N(3) atoms to form ZnN6 octahedra that share corners with two equivalent S(1)CNO2 tetrahedra. The Zn(1)-N(5) bond length is 2.14 Å. The Zn(1)-N(6) bond length is 2.13 Å. Both Zn(1)-N(1) bond lengths are 2.21 Å. Both Zn(1)-N(3) bond lengths are 2.18 Å. There are fifteen inequivalent C sites. In the first C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(8) atom. The C(6)-C(5) bond length is 1.40 Å. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(8) bond length is 1.09 Å. In the second C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(1) atom. The C(7)-C(8) bond length is 1.42 Å. The C(7)-H(1) bond length is 1.09 Å. In the third C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(4) atom. The C(8)-C(9) bond length is 1.42 Å. The C(8)-N(4) bond length is 1.36 Å. In the fourth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(9) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(9) bond length is 1.09 Å. In the fifth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one H(7) atom. The C(10)-C(5) bond length is 1.40 Å. The C(10)-H(7) bond length is 1.09 Å. In the sixth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(5), and one H(2) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(5) bond length is 1.35 Å. The C(11)-H(2) bond length is 1.09 Å. In the seventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(6) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(6) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a trigonal planar geometry to one C(14) and two equivalent C(12) atoms. The C(13)-C(14) bond length is 1.47 Å. In the ninth C site, C(14) is bonded in a trigonal planar geometry to one C(13) and two equivalent C(15) atoms. Both C(14)-C(15) bond lengths are 1.40 Å. In the tenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(3) atom. The C(15)-H(3) bond length is 1.09 Å. In the eleventh C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(4) atom. The C(16)-N(6) bond length is 1.34 Å. The C(16)-H(4) bond length is 1.09 Å. In the twelfth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(11) atom. The C(4)-N(2) bond length is 1.34 Å. The C(4)-H(11) bond length is 1.09 Å. In the thirteenth C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. The C(1)-N(1) bond length is 1.38 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-N(3) bond length is 1.35 Å. In the fourteenth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(2)-N(1) bond length is 1.33 Å. The C(2)-H(5) bond length is 1.09 Å. In the fifteenth C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(6), and one S(1) atom. The C(5)-S(1) bond length is 1.77 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Zn(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one C(4) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Zn(1), one C(1), and one S(1) atom. The N(3)-S(1) bond length is 1.62 Å. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one Zn(1) and two equivalent C(11) atoms. In the fifth N site, N(4) is bonded in a trigonal planar geometry to one C(8), one H(12), and one H(13) atom. The N(4)-H(12) bond length is 1.03 Å. The N(4)-H(13) bond length is 1.01 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(1) and two equivalent C(16) atoms. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(4) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one N(4) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one N(4) atom. S(1) is bonded to one C(5), one N(3), one O(1), and one O(2) atom to form distorted SCNO2 tetrahedra that share  a cornercorner with one Zn(1)N6 octahedra. The corner-sharing octahedral tilt angles are 43°. The S(1)-O(1) bond length is 1.46 Å. The S(1)-O(2) bond length is 1.45 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 4.33 A, density 1.43 g/cm3, surface area 4846.97 m2/g, accessible volume 0.24 cm3/g