ZnC8H12(N2O3)2(CH)14 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two isobutylene molecules, and one ZnC8H12(N2O3)2 cluster. In the ZnC8H12(N2O3)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(5), and one O(6) atom. The Zn(1)-N(1) bond length is 2.08 Å. The Zn(1)-N(2) bond length is 2.08 Å. The Zn(1)-O(5) bond length is 2.04 Å. The Zn(1)-O(6) bond length is 2.04 Å. There are seven inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal non-coplanar geometry to one C(3); one N(1); one H(1,2); and one H(3,4) atom. The C(1,2)-C(3) bond length is 1.52 Å. The C(1,2)-N(1) bond length is 1.47 Å. The C(1,2)-H(1,2) bond length is 1.10 Å. The C(1,2)-H(3,4) bond length is 1.10 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(1,2); one N(3,4); and one O(1,2) atom. The C(3)-N(3,4) bond length is 1.35 Å. The C(3)-O(1,2) bond length is 1.25 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(1,2); one N(3,4); and one O(1,2) atom. The C(4)-C(1,2) bond length is 1.52 Å. The C(4)-N(3,4) bond length is 1.35 Å. The C(4)-O(1,2) bond length is 1.25 Å. In the fourth C site, C(5) is bonded in a distorted water-like geometry to one N(3,4) and one H(5,6) atom. The C(5)-N(3,4) bond length is 1.45 Å. The C(5)-H(5,6) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a distorted water-like geometry to one N(3,4) and one H(5,6) atom. The C(6)-N(3,4) bond length is 1.45 Å. The C(6)-H(5,6) bond length is 1.10 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(5) atom. The C(7)-O(3) bond length is 1.26 Å. The C(7)-O(5) bond length is 1.29 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. The C(8)-O(4) bond length is 1.26 Å. The C(8)-O(6) bond length is 1.29 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded to one Zn(1); one C(1,2); one H(21,22); and one H(23,24) atom to form distorted corner-sharing NZnH2C tetrahedra. The N(1)-H(21,22) bond length is 1.02 Å. The N(1)-H(23,24) bond length is 1.03 Å. In the second N site, N(2) is bonded to one Zn(1); one C(1,2); one H(21,22); and one H(23,24) atom to form distorted corner-sharing NZnH2C tetrahedra. The N(2)-C(1,2) bond length is 1.47 Å. The N(2)-H(21,22) bond length is 1.02 Å. The N(2)-H(23,24) bond length is 1.03 Å. In the third N site, N(3,4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one H(25) atom. The N(3,4)-H(25) bond length is 1.04 Å. There are seven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(1,2) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(21,22) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(23,24) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(25) is bonded in a distorted single-bond geometry to one N(3,4) atom. In the seventh H site, H(26) is bonded in a distorted single-bond geometry to one N(3,4) atom. The H(26)-N(3,4) bond length is 1.04 Å. There are five inequivalent O sites. In the first O site, O(1,2) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(3) is bonded in a distorted single-bond geometry to one C(7) atom. In the third O site, O(4) is bonded in a distorted single-bond geometry to one C(8) atom. In the fourth O site, O(5) is bonded in a water-like geometry to one Zn(1) and one C(7) atom. In the fifth O site, O(6) is bonded in a water-like geometry to one Zn(1) and one C(8) atom. Linkers: 2 NCC(=O)N[C@@H](Cc1ccccc1)C([O])=O. Metal clusters: 1 [Zn]. RCSR code: sql. The MOF has largest included sphere 2.10 A, density 1.58 g/cm3, surface area 4570.52 m2/g, accessible volume 0.11 cm3/g