CuC2H2O5O2NC6H4OHCH2CO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dimethyl ether molecules, one CuC2H2O5 cluster, and two O2NC6H4OH clusters. In the CuC2H2O5 cluster, Cu(1) is bonded in a square pyramidal geometry to one O(1), one O(2), one O(5), one O(6), and one O(9) atom. The Cu(1)-O(1) bond length is 2.01 Å. The Cu(1)-O(2) bond length is 1.99 Å. The Cu(1)-O(5) bond length is 1.99 Å. The Cu(1)-O(6) bond length is 1.99 Å. The Cu(1)-O(9) bond length is 2.22 Å. There are two inequivalent C sites. In the first C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(10)-O(5) bond length is 1.27 Å. The C(10)-O(6) bond length is 1.27 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.26 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(9) atom. The H(1)-O(9) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(9) atom. The H(2)-O(9) bond length is 0.99 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(10) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(10) atom. In the fifth O site, O(9) is bonded in a distorted water-like geometry to one Cu(1), one H(1), and one H(2) atom. In each O2NC6H4OH cluster, there are six inequivalent C sites. In the first C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(1) atom. The C(7)-C(6) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(1) bond length is 1.44 Å. In the second C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(8)-H(7) bond length is 1.09 Å. In the third C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one H(8), one H(9), and one O(4) atom. The C(9)-H(8) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. The C(9)-O(4) bond length is 1.43 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(5) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(5) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(6) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(6) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one O(4) atom. The C(6)-O(4) bond length is 1.37 Å. N(1) is bonded in a trigonal planar geometry to one C(7), one O(7), and one O(8) atom. The N(1)-O(7) bond length is 1.24 Å. The N(1)-O(8) bond length is 1.26 Å. There are five inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. There are three inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one C(6) and one C(9) atom. In the second O site, O(7) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(8) is bonded in a single-bond geometry to one N(1) atom. Linkers: 2 [O]C(=O)COc1ccc(OCC([O])=O)c([N+](=O)[O-])c1. Metal clusters: 1 O.O.[C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 2.55 A, density 1.92 g/cm3, surface area 3768.42 m2/g, accessible volume 0.10 cm3/g