Zn4C63N9H55O17 crystallizes in the monoclinic Cc space group. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(2), one O(10), one O(2), one O(5), and one O(6) atom to form ZnNO4 square pyramids that share  a cornercorner with one C(4)H2N2 tetrahedra,  a cornercorner with one C(5)H2N2 tetrahedra, and  a cornercorner with one C(6)H2N2 tetrahedra. The Zn(1)-N(2) bond length is 2.09 Å. The Zn(1)-O(10) bond length is 2.05 Å. The Zn(1)-O(2) bond length is 2.07 Å. The Zn(1)-O(5) bond length is 2.09 Å. The Zn(1)-O(6) bond length is 2.04 Å. In the second Zn site, Zn(2) is bonded to one N(6), one O(15), one O(3), one O(4), and one O(7) atom to form ZnNO4 square pyramids that share  a cornercorner with one C(10)H2N2 tetrahedra,  a cornercorner with one C(11)H2N2 tetrahedra, and  a cornercorner with one C(12)H2N2 tetrahedra. The Zn(2)-N(6) bond length is 2.09 Å. The Zn(2)-O(15) bond length is 2.05 Å. The Zn(2)-O(3) bond length is 2.08 Å. The Zn(2)-O(4) bond length is 2.07 Å. The Zn(2)-O(7) bond length is 2.05 Å. In the third Zn site, Zn(3) is bonded to one N(3), one O(12), one O(13), and one O(9) atom to form distorted ZnNO3 trigonal pyramids that share  a cornercorner with one C(4)H2N2 tetrahedra,  a cornercorner with one C(7)H2N2 tetrahedra, and  a cornercorner with one C(9)H2N2 tetrahedra. The Zn(3)-N(3) bond length is 2.12 Å. The Zn(3)-O(12) bond length is 1.99 Å. The Zn(3)-O(13) bond length is 1.96 Å. The Zn(3)-O(9) bond length is 1.96 Å. In the fourth Zn site, Zn(4) is bonded to one N(7), one O(1), one O(11), one O(14), one O(16), and one O(17) atom to form distorted ZnNO5 octahedra that share  a cornercorner with one C(10)H2N2 tetrahedra,  a cornercorner with one C(13)H2N2 tetrahedra, and  a cornercorner with one C(15)H2N2 tetrahedra. The Zn(4)-N(7) bond length is 2.21 Å. The Zn(4)-O(1) bond length is 2.23 Å. The Zn(4)-O(11) bond length is 2.03 Å. The Zn(4)-O(14) bond length is 2.04 Å. The Zn(4)-O(16) bond length is 2.35 Å. The Zn(4)-O(17) bond length is 2.11 Å. There are sixty-three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one H(1), and one O(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-O(1) bond length is 1.26 Å. In the second C site, C(2) is bonded to one N(1), one H(2), one H(3), and one H(4) atom to form corner-sharing CH3N tetrahedra. The C(2)-N(1) bond length is 1.47 Å. The C(2)-H(2) bond length is 1.09 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. In the third C site, C(3) is bonded to one N(1), one H(5), one H(6), and one H(7) atom to form corner-sharing CH3N tetrahedra. The C(3)-N(1) bond length is 1.46 Å. The C(3)-H(5) bond length is 1.09 Å. The C(3)-H(6) bond length is 1.10 Å. The C(3)-H(7) bond length is 1.10 Å. In the fourth C site, C(4) is bonded to one N(2), one N(3), one H(8), and one H(9) atom to form CH2N2 tetrahedra that share  a cornercorner with one Zn(1)NO4 square pyramid,  a cornercorner with one C(5)H2N2 tetrahedra,  a cornercorner with one C(6)H2N2 tetrahedra,  a cornercorner with one C(7)H2N2 tetrahedra,  a cornercorner with one C(9)H2N2 tetrahedra, and  a cornercorner with one Zn(3)NO3 trigonal pyramid. The C(4)-N(2) bond length is 1.48 Å. The C(4)-N(3) bond length is 1.48 Å. The C(4)-H(8) bond length is 1.10 Å. The C(4)-H(9) bond length is 1.10 Å. In the fifth C site, C(5) is bonded to one N(2), one N(4), one H(10), and one H(11) atom to form CH2N2 tetrahedra that share  a cornercorner with one Zn(1)NO4 square pyramid,  a cornercorner with one C(4)H2N2 tetrahedra,  a cornercorner with one C(6)H2N2 tetrahedra,  a cornercorner with one C(7)H2N2 tetrahedra, and  a cornercorner with one C(8)H2N2 tetrahedra. The C(5)-N(2) bond length is 1.50 Å. The C(5)-N(4) bond length is 1.46 Å. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(11) bond length is 1.10 Å. In the sixth C site, C(6) is bonded to one N(2), one N(5), one H(12), and one H(13) atom to form CH2N2 tetrahedra that share  a cornercorner with one Zn(1)NO4 square pyramid,  a cornercorner with one C(4)H2N2 tetrahedra,  a cornercorner with one C(5)H2N2 tetrahedra,  a cornercorner with one C(8)H2N2 tetrahedra, and  a cornercorner with one C(9)H2N2 tetrahedra. The C(6)-N(2) bond length is 1.50 Å. The C(6)-N(5) bond length is 1.46 Å. The C(6)-H(12) bond length is 1.10 Å. The C(6)-H(13) bond length is 1.10 Å. In the seventh C site, C(7) is bonded to one N(3), one N(4), one H(14), and one H(15) atom to form CH2N2 tetrahedra that share  a cornercorner with one C(4)H2N2 tetrahedra,  a cornercorner with one C(5)H2N2 tetrahedra,  a cornercorner with one C(8)H2N2 tetrahedra,  a cornercorner with one C(9)H2N2 tetrahedra, and  a cornercorner with one Zn(3)NO3 trigonal pyramid. The C(7)-N(3) bond length is 1.50 Å. The C(7)-N(4) bond length is 1.46 Å. The C(7)-H(14) bond length is 1.10 Å. The C(7)-H(15) bond length is 1.10 Å. In the eighth C site, C(8) is bonded to one N(4), one N(5), one H(16), and one H(17) atom to form corner-sharing CH2N2 tetrahedra. The C(8)-N(4) bond length is 1.47 Å. The C(8)-N(5) bond length is 1.48 Å. The C(8)-H(16) bond length is 1.10 Å. The C(8)-H(17) bond length is 1.10 Å. In the ninth C site, C(9) is bonded to one N(3), one N(5), one H(18), and one H(19) atom to form CH2N2 tetrahedra that share  a cornercorner with one C(4)H2N2 tetrahedra,  a cornercorner with one C(6)H2N2 tetrahedra,  a cornercorner with one C(7)H2N2 tetrahedra,  a cornercorner with one C(8)H2N2 tetrahedra, and  a cornercorner with one Zn(3)NO3 trigonal pyramid. The C(9)-N(3) bond length is 1.50 Å. The C(9)-N(5) bond length is 1.46 Å. The C(9)-H(18) bond length is 1.10 Å. The C(9)-H(19) bond length is 1.10 Å. In the tenth C site, C(10) is bonded to one N(6), one N(7), one H(20), and one H(21) atom to form CH2N2 tetrahedra that share  a cornercorner with one Zn(4)NO5 octahedra,  a cornercorner with one Zn(2)NO4 square pyramid,  a cornercorner with one C(11)H2N2 tetrahedra,  a cornercorner with one C(12)H2N2 tetrahedra,  a cornercorner with one C(13)H2N2 tetrahedra, and  a cornercorner with one C(15)H2N2 tetrahedra. The corner-sharing octahedral tilt angles are 70°. The C(10)-N(6) bond length is 1.49 Å. The C(10)-N(7) bond length is 1.48 Å. The C(10)-H(20) bond length is 1.10 Å. The C(10)-H(21) bond length is 1.10 Å. In the eleventh C site, C(11) is bonded to one N(6); one N(8); and two equivalent H(22,23) atoms to form CH2N2 tetrahedra that share  a cornercorner with one Zn(2)NO4 square pyramid,  a cornercorner with one C(10)H2N2 tetrahedra,  a cornercorner with one C(12)H2N2 tetrahedra,  a cornercorner with one C(13)H2N2 tetrahedra, and  a cornercorner with one C(14)H2N2 tetrahedra. The C(11)-N(6) bond length is 1.50 Å. The C(11)-N(8) bond length is 1.46 Å. Both C(11)-H(22,23) bond lengths are 1.10 Å. In the twelfth C site, C(12) is bonded to one N(6), one N(9), one H(24), and one H(25) atom to form CH2N2 tetrahedra that share  a cornercorner with one Zn(2)NO4 square pyramid,  a cornercorner with one C(10)H2N2 tetrahedra,  a cornercorner with one C(11)H2N2 tetrahedra,  a cornercorner with one C(14)H2N2 tetrahedra, and  a cornercorner with one C(15)H2N2 tetrahedra. The C(12)-N(6) bond length is 1.50 Å. The C(12)-N(9) bond length is 1.46 Å. The C(12)-H(24) bond length is 1.10 Å. The C(12)-H(25) bond length is 1.10 Å. In the thirteenth C site, C(13) is bonded to one N(7), one N(8), one H(26), and one H(27) atom to form CH2N2 tetrahedra that share  a cornercorner with one Zn(4)NO5 octahedra,  a cornercorner with one C(10)H2N2 tetrahedra,  a cornercorner with one C(11)H2N2 tetrahedra,  a cornercorner with one C(14)H2N2 tetrahedra, and  a cornercorner with one C(15)H2N2 tetrahedra. The corner-sharing octahedral tilt angles are 67°. The C(13)-N(7) bond length is 1.50 Å. The C(13)-N(8) bond length is 1.46 Å. The C(13)-H(26) bond length is 1.10 Å. The C(13)-H(27) bond length is 1.10 Å. In the fourteenth C site, C(14) is bonded to one N(8), one N(9), one H(28), and one H(29) atom to form corner-sharing CH2N2 tetrahedra. The C(14)-N(8) bond length is 1.47 Å. The C(14)-N(9) bond length is 1.48 Å. The C(14)-H(28) bond length is 1.10 Å. The C(14)-H(29) bond length is 1.10 Å. In the fifteenth C site, C(15) is bonded to one N(7), one N(9), one H(30), and one H(31) atom to form CH2N2 tetrahedra that share  a cornercorner with one Zn(4)NO5 octahedra,  a cornercorner with one C(10)H2N2 tetrahedra,  a cornercorner with one C(12)H2N2 tetrahedra,  a cornercorner with one C(13)H2N2 tetrahedra, and  a cornercorner with one C(14)H2N2 tetrahedra. The corner-sharing octahedral tilt angles are 70°. The C(15)-N(7) bond length is 1.50 Å. The C(15)-N(9) bond length is 1.46 Å. The C(15)-H(30) bond length is 1.10 Å. The C(15)-H(31) bond length is 1.10 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(2), and one O(3) atom. The C(16)-C(17) bond length is 1.50 Å. The C(16)-O(2) bond length is 1.28 Å. The C(16)-O(3) bond length is 1.28 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(22) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-C(22) bond length is 1.42 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(32) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-H(32) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(23) atom. The C(19)-C(20) bond length is 1.44 Å. The C(19)-C(23) bond length is 1.42 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(26) atom. The C(20)-C(21) bond length is 1.42 Å. The C(20)-C(26) bond length is 1.42 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one H(33) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-H(33) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(17), one C(21), and one H(34) atom. The C(22)-H(34) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(19) and one H(35) atom. The C(23)-H(35) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a single-bond geometry to one C(25) and one H(36) atom. The C(24)-C(25) bond length is 1.42 Å. The C(24)-H(36) bond length is 1.09 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(27) atom. The C(25)-C(26) bond length is 1.38 Å. The C(25)-C(27) bond length is 1.50 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(20), one C(25), and one H(37) atom. The C(26)-H(37) bond length is 1.09 Å. In the twenty-seventh C site, C(27) is bonded in a bent 120 degrees geometry to one C(25), one O(4), and one O(5) atom. The C(27)-O(4) bond length is 1.28 Å. The C(27)-O(5) bond length is 1.27 Å. In the twenty-eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(6), and one O(7) atom. The C(28)-C(29) bond length is 1.49 Å. The C(28)-O(6) bond length is 1.28 Å. The C(28)-O(7) bond length is 1.28 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(34) atom. The C(29)-C(30) bond length is 1.42 Å. The C(29)-C(34) bond length is 1.38 Å. In the thirtieth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one C(31), and one H(38) atom. The C(30)-C(31) bond length is 1.38 Å. The C(30)-H(38) bond length is 1.09 Å. In the thirty-first C site, C(31) is bonded in a distorted trigonal planar geometry to one C(30), one C(32), and one H(39) atom. The C(31)-C(32) bond length is 1.42 Å. The C(31)-H(39) bond length is 1.09 Å. In the thirty-second C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(35) atom. The C(32)-C(33) bond length is 1.44 Å. The C(32)-C(35) bond length is 1.41 Å. In the thirty-third C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(38) atom. The C(33)-C(34) bond length is 1.41 Å. The C(33)-C(38) bond length is 1.42 Å. In the thirty-fourth C site, C(34) is bonded in a distorted single-bond geometry to one C(29), one C(33), and one H(40) atom. The C(34)-H(40) bond length is 1.09 Å. In the thirty-fifth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(32), one C(36), and one H(41) atom. The C(35)-C(36) bond length is 1.38 Å. The C(35)-H(41) bond length is 1.09 Å. In the thirty-sixth C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(39) atom. The C(36)-C(37) bond length is 1.42 Å. The C(36)-C(39) bond length is 1.50 Å. In the thirty-seventh C site, C(37) is bonded in a distorted single-bond geometry to one C(36) and one H(42) atom. The C(37)-H(42) bond length is 1.09 Å. In the thirty-eighth C site, C(38) is bonded in a distorted single-bond geometry to one C(33) and one H(43) atom. The C(38)-H(43) bond length is 1.09 Å. In the thirty-ninth C site, C(39) is bonded in a bent 120 degrees geometry to one C(36), one O(8), and one O(9) atom. The C(39)-O(8) bond length is 1.25 Å. The C(39)-O(9) bond length is 1.31 Å. In the fortieth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(41), one O(11), and one O(12) atom. The C(40)-C(41) bond length is 1.49 Å. The C(40)-O(11) bond length is 1.27 Å. The C(40)-O(12) bond length is 1.28 Å. In the forty-first C site, C(41) is bonded in a trigonal planar geometry to one C(40), one C(42), and one C(46) atom. The C(41)-C(42) bond length is 1.38 Å. The C(41)-C(46) bond length is 1.42 Å. In the forty-second C site, C(42) is bonded in a distorted single-bond geometry to one C(41), one C(43), and one H(44) atom. The C(42)-C(43) bond length is 1.41 Å. The C(42)-H(44) bond length is 1.09 Å. In the forty-third C site, C(43) is bonded in a trigonal planar geometry to one C(42), one C(44), and one C(47) atom. The C(43)-C(44) bond length is 1.44 Å. The C(43)-C(47) bond length is 1.42 Å. In the forty-fourth C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(50) atom. The C(44)-C(45) bond length is 1.42 Å. The C(44)-C(50) bond length is 1.41 Å. In the forty-fifth C site, C(45) is bonded in a distorted single-bond geometry to one C(44) and one H(45) atom. The C(45)-H(45) bond length is 1.09 Å. In the forty-sixth C site, C(46) is bonded in a distorted single-bond geometry to one C(41) and one H(46) atom. The C(46)-H(46) bond length is 1.09 Å. In the forty-seventh C site, C(47) is bonded in a distorted trigonal planar geometry to one C(43), one C(48), and one H(47) atom. The C(47)-C(48) bond length is 1.37 Å. The C(47)-H(47) bond length is 1.09 Å. In the forty-eighth C site, C(48) is bonded in a distorted trigonal planar geometry to one C(47), one C(49), and one H(48) atom. The C(48)-C(49) bond length is 1.42 Å. The C(48)-H(48) bond length is 1.09 Å. In the forty-ninth C site, C(49) is bonded in a trigonal planar geometry to one C(48), one C(50), and one C(51) atom. The C(49)-C(50) bond length is 1.38 Å. The C(49)-C(51) bond length is 1.49 Å. In the fiftieth C site, C(50) is bonded in a distorted single-bond geometry to one C(44), one C(49), and one H(49) atom. The C(50)-H(49) bond length is 1.09 Å. In the fifty-first C site, C(51) is bonded in a distorted bent 120 degrees geometry to one C(49), one O(13), and one O(14) atom. The C(51)-O(13) bond length is 1.28 Å. The C(51)-O(14) bond length is 1.27 Å. In the fifty-second C site, C(52) is bonded in a bent 120 degrees geometry to one C(53), one O(10), and one O(15) atom. The C(52)-C(53) bond length is 1.49 Å. The C(52)-O(10) bond length is 1.28 Å. The C(52)-O(15) bond length is 1.28 Å. In the fifty-third C site, C(53) is bonded in a trigonal planar geometry to one C(52), one C(54), and one C(58) atom. The C(53)-C(54) bond length is 1.38 Å. The C(53)-C(58) bond length is 1.42 Å. In the fifty-fourth C site, C(54) is bonded in a distorted single-bond geometry to one C(53), one C(55), and one H(50) atom. The C(54)-C(55) bond length is 1.41 Å. The C(54)-H(50) bond length is 1.09 Å. In the fifty-fifth C site, C(55) is bonded in a trigonal planar geometry to one C(54), one C(56), and one C(59) atom. The C(55)-C(56) bond length is 1.43 Å. The C(55)-C(59) bond length is 1.42 Å. In the fifty-sixth C site, C(56) is bonded in a trigonal planar geometry to one C(55), one C(57), and one C(62) atom. The C(56)-C(57) bond length is 1.42 Å. The C(56)-C(62) bond length is 1.41 Å. In the fifty-seventh C site, C(57) is bonded in a distorted trigonal planar geometry to one C(56), one C(58), and one H(51) atom. The C(57)-C(58) bond length is 1.38 Å. The C(57)-H(51) bond length is 1.09 Å. In the fifty-eighth C site, C(58) is bonded in a distorted single-bond geometry to one C(53), one C(57), and one H(52) atom. The C(58)-H(52) bond length is 1.09 Å. In the fifty-ninth C site, C(59) is bonded in a distorted single-bond geometry to one C(55) and one H(53) atom. The C(59)-H(53) bond length is 1.09 Å. In the sixtieth C site, C(60) is bonded in a distorted single-bond geometry to one C(61) and one H(54) atom. The C(60)-C(61) bond length is 1.42 Å. The C(60)-H(54) bond length is 1.09 Å. In the sixty-first C site, C(61) is bonded in a trigonal planar geometry to one C(60), one C(62), and one C(63) atom. The C(61)-C(62) bond length is 1.38 Å. The C(61)-C(63) bond length is 1.49 Å. In the sixty-second C site, C(62) is bonded in a distorted trigonal planar geometry to one C(56), one C(61), and one H(55) atom. The C(62)-H(55) bond length is 1.09 Å. In the sixty-third C site, C(63) is bonded in a bent 120 degrees geometry to one C(61), one O(16), and one O(17) atom. The C(63)-O(16) bond length is 1.27 Å. The C(63)-O(17) bond length is 1.29 Å. There are nine inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. In the second N site, N(2) is bonded to one Zn(1), one C(4), one C(5), and one C(6) atom to form corner-sharing NZnC3 tetrahedra. In the third N site, N(3) is bonded to one Zn(3), one C(4), one C(7), and one C(9) atom to form corner-sharing NZnC3 tetrahedra. In the fourth N site, N(4) is bonded in a trigonal non-coplanar geometry to one C(5), one C(7), and one C(8) atom. In the fifth N site, N(5) is bonded in a trigonal non-coplanar geometry to one C(6), one C(8), and one C(9) atom. In the sixth N site, N(6) is bonded to one Zn(2), one C(10), one C(11), and one C(12) atom to form corner-sharing NZnC3 tetrahedra. In the seventh N site, N(7) is bonded to one Zn(4), one C(10), one C(13), and one C(15) atom to form corner-sharing NZnC3 tetrahedra. In the eighth N site, N(8) is bonded in a trigonal non-coplanar geometry to one C(11), one C(13), and one C(14) atom. In the ninth N site, N(9) is bonded in a trigonal non-coplanar geometry to one C(12), one C(14), and one C(15) atom. There are fifty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(5) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(6) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(7) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(7) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(8) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(8) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(9) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(9) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(10) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(10) atom. In the twenty-second H site, H(22,23) is bonded in a single-bond geometry to one C(11) atom. In the twenty-third H site, H(24) is bonded in a single-bond geometry to one C(12) atom. In the twenty-fourth H site, H(25) is bonded in a single-bond geometry to one C(12) atom. In the twenty-fifth H site, H(26) is bonded in a single-bond geometry to one C(13) atom. In the twenty-sixth H site, H(27) is bonded in a single-bond geometry to one C(13) atom. In the twenty-seventh H site, H(28) is bonded in a single-bond geometry to one C(14) atom. In the twenty-eighth H site, H(29) is bonded in a single-bond geometry to one C(14) atom. In the twenty-ninth H site, H(30) is bonded in a single-bond geometry to one C(15) atom. In the thirtieth H site, H(31) is bonded in a single-bond geometry to one C(15) atom. In the thirty-first H site, H(32) is bonded in a single-bond geometry to one C(18) atom. In the thirty-second H site, H(33) is bonded in a single-bond geometry to one C(21) atom. In the thirty-third H site, H(34) is bonded in a single-bond geometry to one C(22) atom. In the thirty-fourth H site, H(35) is bonded in a single-bond geometry to one C(23) atom. In the thirty-fifth H site, H(36) is bonded in a single-bond geometry to one C(24) atom. In the thirty-sixth H site, H(37) is bonded in a single-bond geometry to one C(26) atom. In the thirty-seventh H site, H(38) is bonded in a single-bond geometry to one C(30) atom. In the thirty-eighth H site, H(39) is bonded in a single-bond geometry to one C(31) atom. In the thirty-ninth H site, H(40) is bonded in a single-bond geometry to one C(34) atom. In the fortieth H site, H(41) is bonded in a single-bond geometry to one C(35) atom. In the forty-first H site, H(42) is bonded in a single-bond geometry to one C(37) atom. In the forty-second H site, H(43) is bonded in a single-bond geometry to one C(38) atom. In the forty-third H site, H(44) is bonded in a single-bond geometry to one C(42) atom. In the forty-fourth H site, H(45) is bonded in a single-bond geometry to one C(45) atom. In the forty-fifth H site, H(46) is bonded in a single-bond geometry to one C(46) atom. In the forty-sixth H site, H(47) is bonded in a single-bond geometry to one C(47) atom. In the forty-seventh H site, H(48) is bonded in a single-bond geometry to one C(48) atom. In the forty-eighth H site, H(49) is bonded in a single-bond geometry to one C(50) atom. In the forty-ninth H site, H(50) is bonded in a single-bond geometry to one C(54) atom. In the fiftieth H site, H(51) is bonded in a single-bond geometry to one C(57) atom. In the fifty-first H site, H(52) is bonded in a single-bond geometry to one C(58) atom. In the fifty-second H site, H(53) is bonded in a single-bond geometry to one C(59) atom. In the fifty-third H site, H(54) is bonded in a single-bond geometry to one C(60) atom. In the fifty-fourth H site, H(55) is bonded in a single-bond geometry to one C(62) atom. There are seventeen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(16) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(16) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(27) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(27) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(28) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(28) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(39) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Zn(3) and one C(39) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(52) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(40) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(40) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(51) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(51) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(52) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one Zn(4) and one C(63) atom. In the seventeenth O site, O(17) is bonded in an L-shaped geometry to one Zn(4) and one C(63) atom. Linkers: 8 [O]C(=O)c1ccc2cc(C([O])=O)ccc2c1 ,4 C1N2CN3CN1CN(C2)C3. Metal clusters: 2 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4 ,4 [Zn]. The MOF has largest included sphere 11.39 A, density 1.03 g/cm3, surface area 4417.62 m2/g, accessible volume 0.53 cm3/g