CoC30H28(N5S)2 is Indium structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two CoC30H28(N5S)2 clusters. Co(1) is bonded in an octahedral geometry to one N(1), one N(2), two equivalent N(5), and two equivalent N(6) atoms. The Co(1)-N(1) bond length is 1.87 Å. The Co(1)-N(2) bond length is 1.85 Å. Both Co(1)-N(5) bond lengths are 1.96 Å. Both Co(1)-N(6) bond lengths are 2.25 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.19 Å. The C(1)-S(1) bond length is 1.62 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2) and one S(2) atom. The C(2)-N(2) bond length is 1.19 Å. The C(2)-S(2) bond length is 1.62 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(1), and one H(3) atom. The C(3)-N(3) bond length is 1.44 Å. The C(3)-H(1) bond length is 1.10 Å. The C(3)-H(3) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(2), and one H(4) atom. The C(4)-N(4) bond length is 1.44 Å. The C(4)-H(2) bond length is 1.10 Å. The C(4)-H(4) bond length is 1.11 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(3), and one H(5) atom. The C(5)-C(7) bond length is 1.47 Å. The C(5)-N(3) bond length is 1.28 Å. The C(5)-H(5) bond length is 1.11 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(4), and one H(6) atom. The C(6)-C(8) bond length is 1.47 Å. The C(6)-N(4) bond length is 1.28 Å. The C(6)-H(6) bond length is 1.11 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(15), one C(5), and one C(9) atom. The C(7)-C(15) bond length is 1.40 Å. The C(7)-C(9) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(16), and one C(6) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-C(16) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(5), and one H(7) atom. The C(9)-N(5) bond length is 1.34 Å. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(6), and one H(8) atom. The C(10)-N(6) bond length is 1.34 Å. The C(10)-H(8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(13), one N(5), and one H(9) atom. The C(11)-C(13) bond length is 1.39 Å. The C(11)-N(5) bond length is 1.36 Å. The C(11)-H(9) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14), one N(6), and one H(10) atom. The C(12)-C(14) bond length is 1.39 Å. The C(12)-N(6) bond length is 1.35 Å. The C(12)-H(10) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(11) and one H(11) atom. The C(13)-H(11) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(12) atom. The C(14)-H(12) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(7) and one H(13) atom. The C(15)-H(13) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(8) and one H(14) atom. The C(16)-H(14) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one Co(1), one C(11), and one C(9) atom. In the second N site, N(6) is bonded in a trigonal planar geometry to one Co(1), one C(10), and one C(12) atom. In the third N site, N(1) is bonded in a linear geometry to one Co(1) and one C(1) atom. In the fourth N site, N(2) is bonded in a linear geometry to one Co(1) and one C(2) atom. In the fifth N site, N(3) is bonded in a bent 120 degrees geometry to one C(3) and one C(5) atom. In the sixth N site, N(4) is bonded in a bent 120 degrees geometry to one C(4) and one C(6) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one C(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(2) atom. Linkers: 2 C(=N/CC/N=C/c1cccnc1)\c1cccnc1 ,2 [C][CH]C(/C=N/CC/N=C/c1cccnc1)=C\[N]. Metal clusters: 1 [Co]. The MOF has largest included sphere 2.55 A, density 1.36 g/cm3, surface area 5073.39 m2/g, accessible volume 0.23 cm3/g