CdC4H4(NI)2(C9H6N)2(C2NH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four n-methyl methanimine molecules, four schembl1705614 molecules, and two CdC4H4(NI)2 clusters. In each CdC4H4(NI)2 cluster, Cd(1) is bonded in a distorted trigonal pyramidal geometry to two equivalent N(1,2) and two equivalent I(1,2) atoms. Both Cd(1)-N(1,2) bond lengths are 2.31 Å. Both Cd(1)-I(1,2) bond lengths are 2.73 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1,2) and one H(1,2) atom. The C(1)-N(1,2) bond length is 1.35 Å. The C(1)-H(1,2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1,2) and one H(1,2) atom. The C(2)-N(1,2) bond length is 1.35 Å. The C(2)-H(1,2) bond length is 1.09 Å. In the third C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1,2) and one H(7,8) atom. The C(9)-N(1,2) bond length is 1.35 Å. The C(9)-H(7,8) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1,2) and one H(7,8) atom. The C(10)-N(1,2) bond length is 1.35 Å. The C(10)-H(7,8) bond length is 1.09 Å. N(1,2) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(9) atom. There are two inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(7,8) is bonded in a single-bond geometry to one C(9) atom. I(1,2) is bonded in a single-bond geometry to one Cd(1) atom. Linkers: 2 c1cc(N(c2ccncc2)c2ccc(N(c3ccncc3)c3ccncc3)cc2)ccn1. Metal clusters: 2 I[Cd]I. The MOF has largest included sphere 2.41 A, density 1.98 g/cm3, surface area 3793.55 m2/g, accessible volume 0.14 cm3/g