Ag2C6H3SO6CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a Ag2C6H3SO6 framework. In the Ag2C6H3SO6 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(5), and one O(6) atom. The Ag(1)-O(1) bond length is 2.36 Å. The Ag(1)-O(2) bond length is 2.67 Å. The Ag(1)-O(5) bond length is 2.35 Å. The Ag(1)-O(6) bond length is 2.19 Å. In the second Ag site, Ag(2) is bonded to one O(1), one O(2), one O(4), and two equivalent O(5) atoms to form distorted edge-sharing AgO5 trigonal bipyramids. The Ag(2)-O(1) bond length is 2.42 Å. The Ag(2)-O(2) bond length is 2.35 Å. The Ag(2)-O(4) bond length is 2.55 Å. There is one shorter (2.45 Å) and one longer (2.50 Å) Ag(2)-O(5) bond length. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-S(1) bond length is 1.77 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one O(4) atom. The C(2)-O(4) bond length is 1.35 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(3) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(7) bond length is 1.49 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(5), and one O(6) atom. The C(7)-O(5) bond length is 1.29 Å. The C(7)-O(6) bond length is 1.27 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(3) and one O(4) atom. The H(1)-O(3) bond length is 1.61 Å. The H(1)-O(4) bond length is 1.00 Å. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(2) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.46 Å. There are six inequivalent O sites. In the first O site, O(3) is bonded in a bent 150 degrees geometry to one H(1) and one S(1) atom. In the second O site, O(4) is bonded in a distorted water-like geometry to one Ag(2), one C(2), and one H(1) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to one Ag(1), two equivalent Ag(2), and one C(7) atom. In the fourth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one C(7) atom. In the fifth O site, O(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one Ag(2), and one S(1) atom. In the sixth O site, O(2) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one S(1) atom. Linkers: 2 [O]C(=O)c1ccc(O)c(S([O])([O])[O])c1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.84 A, density 3.18 g/cm3, surface area 2132.50 m2/g, accessible volume 0.03 cm3/g