CuC19PNH16BrC3H2CH is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules; one 2,3-dimethyl-1,3-butadiene molecule; and one CuC19PNH16Br cluster. In the CuC19PNH16Br cluster, Cu(1) is bonded to one P(1), one N(1), and two equivalent Br(1) atoms to form distorted edge-sharing CuPBr2N tetrahedra. The Cu(1)-P(1) bond length is 2.19 Å. The Cu(1)-N(1) bond length is 2.02 Å. There is one shorter (2.51 Å) and one longer (2.58 Å) Cu(1)-Br(1) bond length. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the third C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(7), and one P(1) atom. The C(6)-C(11) bond length is 1.40 Å. The C(6)-C(7) bond length is 1.40 Å. The C(6)-P(1) bond length is 1.83 Å. In the fourth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(5) bond length is 1.09 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(6) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(6) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(6) and one H(9) atom. The C(11)-H(9) bond length is 1.09 Å. In the eighth C site, C(12) is bonded in a trigonal planar geometry to one C(13), one C(17), and one P(1) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(17) bond length is 1.40 Å. The C(12)-P(1) bond length is 1.83 Å. In the ninth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(10) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-H(10) bond length is 1.09 Å. In the tenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(11) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(11) bond length is 1.09 Å. In the eleventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(12) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(12) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(13) atom. The C(16)-H(13) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(12) and one H(14) atom. The C(17)-H(14) bond length is 1.09 Å. In the fourteenth C site, C(18) is bonded in a trigonal planar geometry to one C(19), one C(23), and one P(1) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(23) bond length is 1.40 Å. The C(18)-P(1) bond length is 1.83 Å. In the fifteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(15) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(15) bond length is 1.09 Å. In the sixteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one H(16) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(16) bond length is 1.09 Å. In the seventeenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one H(17) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-H(17) bond length is 1.09 Å. In the eighteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(18) atom. The C(22)-H(18) bond length is 1.09 Å. In the nineteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(19) atom. The C(23)-H(19) bond length is 1.09 Å. P(1) is bonded in a tetrahedral geometry to one Cu(1), one C(12), one C(18), and one C(6) atom. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. Br(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 1 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.20 A, density 1.66 g/cm3, surface area 4525.06 m2/g, accessible volume 0.16 cm3/g