AgC15PNH14Cl(CH)3CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two 02329_fluka molecules, and one AgC15PNH14Cl cluster. In the AgC15PNH14Cl cluster, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one P(1), one N(1), and two equivalent Cl(1) atoms. The Ag(1)-P(1) bond length is 2.36 Å. The Ag(1)-N(1) bond length is 2.32 Å. There is one shorter (2.63 Å) and one longer (2.70 Å) Ag(1)-Cl(1) bond length. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(5) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted water-like geometry to one P(1), one H(6), and one H(7) atom. The C(6)-P(1) bond length is 1.84 Å. The C(6)-H(6) bond length is 1.10 Å. The C(6)-H(7) bond length is 1.10 Å. In the fifth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(9), and one P(1) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. The C(8)-P(1) bond length is 1.84 Å. In the sixth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(10) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(10) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(11) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(11) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(12) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(12) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(13) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(13) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one H(14) atom. The C(13)-H(14) bond length is 1.09 Å. In the eleventh C site, C(14) is bonded in a trigonal planar geometry to one C(15), one C(19), and one P(1) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(19) bond length is 1.40 Å. The C(14)-P(1) bond length is 1.83 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(15) atom. The C(15)-H(15) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(17) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(17) bond length is 1.09 Å. In the fourteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(18) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-H(18) bond length is 1.09 Å. In the fifteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one H(19) atom. The C(19)-H(19) bond length is 1.09 Å. P(1) is bonded in a distorted tetrahedral geometry to one Ag(1), one C(14), one C(6), and one C(8) atom. N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. Cl(1) is bonded in an L-shaped geometry to two equivalent Ag(1) atoms. Linkers: 1 c1ccc(P(CCCCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1. Metal clusters: 2 [Ag]. The MOF has largest included sphere 2.21 A, density 1.64 g/cm3, surface area 4655.86 m2/g, accessible volume 0.14 cm3/g