CuC12NH12O5CuC13NH13O5(CH)5(C2O)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of forty 02329_fluka molecules, sixteen dimethyl ether molecules, four CuC12NH12O5 clusters, and four CuC13NH13O5 clusters. In each CuC12NH12O5 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one O(1), one O(11), one O(13), one O(15), and one O(3) atom. The Cu(1)-O(1) bond length is 1.96 Å. The Cu(1)-O(11) bond length is 1.96 Å. The Cu(1)-O(13) bond length is 2.30 Å. The Cu(1)-O(15) bond length is 2.02 Å. The Cu(1)-O(3) bond length is 2.03 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.28 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(9) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-C(9) bond length is 1.40 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(1,2) atom. The C(5)-H(1,2) bond length is 1.09 Å. In the fourth C site, C(9) is bonded in a distorted single-bond geometry to one C(3) and one H(5,6) atom. The C(9)-H(5,6) bond length is 1.09 Å. In the fifth C site, C(19,20) is bonded to one N(1,2); one H(11,12); one H(13,14); and one H(15,16) atom to form corner-sharing CH3N tetrahedra. The C(19,20)-N(1,2) bond length is 1.45 Å. The C(19,20)-H(11,12) bond length is 1.10 Å. The C(19,20)-H(13,14) bond length is 1.10 Å. The C(19,20)-H(15,16) bond length is 1.10 Å. In the sixth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(11), and one O(15) atom. The C(21)-C(29) bond length is 1.48 Å. The C(21)-O(11) bond length is 1.28 Å. The C(21)-O(15) bond length is 1.28 Å. In the seventh C site, C(29) is bonded in a trigonal planar geometry to one C(21), one C(43), and one C(45) atom. The C(29)-C(43) bond length is 1.41 Å. The C(29)-C(45) bond length is 1.40 Å. In the eighth C site, C(43) is bonded in a distorted trigonal planar geometry to one C(29), one C(59), and one H(25) atom. The C(43)-C(59) bond length is 1.39 Å. The C(43)-H(25) bond length is 1.09 Å. In the ninth C site, C(45) is bonded in a distorted single-bond geometry to one C(29) and one H(27,28) atom. The C(45)-H(27,28) bond length is 1.09 Å. In the tenth C site, C(49) is bonded in a trigonal planar geometry to one N(1,2); one H(31,32); and one O(13) atom. The C(49)-N(1,2) bond length is 1.34 Å. The C(49)-H(31,32) bond length is 1.11 Å. The C(49)-O(13) bond length is 1.25 Å. In the eleventh C site, C(59) is bonded in a distorted single-bond geometry to one C(43) and one H(39) atom. The C(59)-H(39) bond length is 1.09 Å. In the twelfth C site, C(61,62) is bonded to one N(1,2); one H(41,42); one H(43,44); and one H(45,46) atom to form corner-sharing CH3N tetrahedra. The C(61,62)-N(1,2) bond length is 1.46 Å. The C(61,62)-H(41,42) bond length is 1.09 Å. The C(61,62)-H(43,44) bond length is 1.10 Å. The C(61,62)-H(45,46) bond length is 1.10 Å. N(1,2) is bonded in a trigonal planar geometry to one C(19,20); one C(49); and one C(61,62) atom. There are twelve inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(5,6) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(11,12) is bonded in a single-bond geometry to one C(19,20) atom. In the fourth H site, H(13,14) is bonded in a single-bond geometry to one C(19,20) atom. In the fifth H site, H(15,16) is bonded in a single-bond geometry to one C(19,20) atom. In the sixth H site, H(25) is bonded in a single-bond geometry to one C(43) atom. In the seventh H site, H(27,28) is bonded in a single-bond geometry to one C(45) atom. In the eighth H site, H(31,32) is bonded in a single-bond geometry to one C(49) atom. In the ninth H site, H(39) is bonded in a single-bond geometry to one C(59) atom. In the tenth H site, H(41,42) is bonded in a single-bond geometry to one C(61,62) atom. In the eleventh H site, H(43,44) is bonded in a single-bond geometry to one C(61,62) atom. In the twelfth H site, H(45,46) is bonded in a single-bond geometry to one C(61,62) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(11) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(21) atom. In the fourth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(49) atom. In the fifth O site, O(15) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(21) atom. In each CuC13NH13O5 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(3) is bonded in a square pyramidal geometry to one O(10), one O(17), one O(20), one O(21), and one O(7) atom. The Cu(3)-O(10) bond length is 2.01 Å. The Cu(3)-O(17) bond length is 2.01 Å. The Cu(3)-O(20) bond length is 1.99 Å. The Cu(3)-O(21) bond length is 2.21 Å. The Cu(3)-O(7) bond length is 1.97 Å. In the second Cu site, Cu(4) is bonded in a square pyramidal geometry to one O(18), one O(19), one O(22), one O(8), and one O(9) atom. The Cu(4)-O(18) bond length is 2.01 Å. The Cu(4)-O(19) bond length is 1.99 Å. The Cu(4)-O(22) bond length is 2.21 Å. The Cu(4)-O(8) bond length is 1.97 Å. The Cu(4)-O(9) bond length is 2.01 Å. There are sixteen inequivalent C sites. In the first C site, C(65,66) is bonded to one N(3); one H(49,50); one H(51,52); and one H(53,54) atom to form corner-sharing CH3N tetrahedra. The C(65,66)-N(3) bond length is 1.46 Å. The C(65,66)-H(49,50) bond length is 1.10 Å. The C(65,66)-H(51,52) bond length is 1.10 Å. The C(65,66)-H(53,54) bond length is 1.10 Å. In the second C site, C(67,68) is bonded to one N(3); one H(55,56); one H(57,58); and one H(59,60) atom to form corner-sharing CH3N tetrahedra. The C(67,68)-N(3) bond length is 1.45 Å. The C(67,68)-H(55,56) bond length is 1.09 Å. The C(67,68)-H(57,58) bond length is 1.10 Å. The C(67,68)-H(59,60) bond length is 1.10 Å. In the third C site, C(17,18) is bonded in a distorted single-bond geometry to one C(53) and one H(9,10) atom. The C(17,18)-C(53) bond length is 1.39 Å. The C(17,18)-H(9,10) bond length is 1.09 Å. In the fourth C site, C(23) is bonded in a distorted single-bond geometry to one C(41,42) and one H(17,18) atom. The C(23)-C(41,42) bond length is 1.40 Å. The C(23)-H(17,18) bond length is 1.09 Å. In the fifth C site, C(24) is bonded in a distorted single-bond geometry to one C(41,42) and one H(17,18) atom. The C(24)-C(41,42) bond length is 1.40 Å. The C(24)-H(17,18) bond length is 1.09 Å. In the sixth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(41,42); one O(17); and one O(9) atom. The C(25)-C(41,42) bond length is 1.49 Å. The C(25)-O(17) bond length is 1.28 Å. The C(25)-O(9) bond length is 1.28 Å. In the seventh C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(41,42); one O(10); and one O(18) atom. The C(26)-C(41,42) bond length is 1.49 Å. The C(26)-O(10) bond length is 1.28 Å. The C(26)-O(18) bond length is 1.28 Å. In the eighth C site, C(27,28) is bonded in a distorted bent 120 degrees geometry to one C(39,40); one O(19); and one O(7) atom. The C(27,28)-C(39,40) bond length is 1.49 Å. The C(27,28)-O(19) bond length is 1.28 Å. The C(27,28)-O(7) bond length is 1.28 Å. In the ninth C site, C(37,38) is bonded in a distorted single-bond geometry to one C(39,40) and one H(23,24) atom. The C(37,38)-C(39,40) bond length is 1.40 Å. The C(37,38)-H(23,24) bond length is 1.09 Å. In the tenth C site, C(39,40) is bonded in a trigonal planar geometry to one C(27,28); one C(37,38); and one C(55,56) atom. The C(39,40)-C(55,56) bond length is 1.40 Å. In the eleventh C site, C(41,42) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(53) atom. The C(41,42)-C(53) bond length is 1.40 Å. In the twelfth C site, C(51,52) is bonded in a distorted single-bond geometry to one C(55,56) and one H(33,34) atom. The C(51,52)-C(55,56) bond length is 1.39 Å. The C(51,52)-H(33,34) bond length is 1.09 Å. In the thirteenth C site, C(53) is bonded in a distorted trigonal planar geometry to one C(17,18); one C(41,42); and one H(35,36) atom. The C(53)-H(35,36) bond length is 1.09 Å. In the fourteenth C site, C(54) is bonded in a distorted trigonal planar geometry to one C(17,18); one C(41,42); and one H(35,36) atom. The C(54)-C(17,18) bond length is 1.39 Å. The C(54)-C(41,42) bond length is 1.40 Å. The C(54)-H(35,36) bond length is 1.09 Å. In the fifteenth C site, C(55,56) is bonded in a distorted trigonal planar geometry to one C(39,40); one C(51,52); and one H(37,38) atom. The C(55,56)-H(37,38) bond length is 1.09 Å. In the sixteenth C site, C(63,64) is bonded in a trigonal planar geometry to one N(3), one H(47), and one O(21) atom. The C(63,64)-N(3) bond length is 1.34 Å. The C(63,64)-H(47) bond length is 1.11 Å. The C(63,64)-O(21) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one C(63,64); one C(65,66); and one C(67,68) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(63,64); one C(65,66); and one C(67,68) atom. The N(4)-C(63,64) bond length is 1.34 Å. The N(4)-C(65,66) bond length is 1.46 Å. The N(4)-C(67,68) bond length is 1.45 Å. There are fourteen inequivalent H sites. In the first H site, H(57,58) is bonded in a single-bond geometry to one C(67,68) atom. In the second H site, H(59,60) is bonded in a single-bond geometry to one C(67,68) atom. In the third H site, H(9,10) is bonded in a single-bond geometry to one C(17,18) atom. In the fourth H site, H(17,18) is bonded in a single-bond geometry to one C(23) atom. In the fifth H site, H(23,24) is bonded in a single-bond geometry to one C(37,38) atom. In the sixth H site, H(33,34) is bonded in a single-bond geometry to one C(51,52) atom. In the seventh H site, H(35,36) is bonded in a single-bond geometry to one C(53) atom. In the eighth H site, H(37,38) is bonded in a single-bond geometry to one C(55,56) atom. In the ninth H site, H(47) is bonded in a single-bond geometry to one C(63,64) atom. In the tenth H site, H(48) is bonded in a single-bond geometry to one C(63,64) atom. The H(48)-C(63,64) bond length is 1.11 Å. In the eleventh H site, H(49,50) is bonded in a single-bond geometry to one C(65,66) atom. In the twelfth H site, H(55,56) is bonded in a single-bond geometry to one C(67,68) atom. In the thirteenth H site, H(51,52) is bonded in a single-bond geometry to one C(65,66) atom. In the fourteenth H site, H(53,54) is bonded in a single-bond geometry to one C(65,66) atom. There are ten inequivalent O sites. In the first O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(27,28) atom. In the second O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(27,28) atom. The O(8)-C(27,28) bond length is 1.28 Å. In the third O site, O(10) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(26) atom. In the fourth O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(25) atom. In the fifth O site, O(17) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(25) atom. In the sixth O site, O(18) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(26) atom. In the seventh O site, O(19) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(27,28) atom. In the eighth O site, O(20) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(27,28) atom. The O(20)-C(27,28) bond length is 1.28 Å. In the ninth O site, O(21) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one C(63,64) atom. In the tenth O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one C(63,64) atom. The O(22)-C(63,64) bond length is 1.25 Å. Linkers: 8 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 8 [Cu]. The MOF has largest included sphere 6.32 A, density 1.20 g/cm3, surface area 4623.35 m2/g, accessible volume 0.30 cm3/g