ZnC20H14(NO2)2(C4H5)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four isobutylene molecules and one ZnC20H14(NO2)2 cluster. In the ZnC20H14(NO2)2 cluster, Zn(1) is bonded in a distorted pentagonal pyramidal geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.13 Å. The Zn(1)-N(2) bond length is 2.14 Å. The Zn(1)-O(1) bond length is 2.32 Å. The Zn(1)-O(2) bond length is 2.24 Å. The Zn(1)-O(3) bond length is 2.12 Å. The Zn(1)-O(4) bond length is 2.11 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(11), one C(2), and one C(4) atom. The C(3)-C(11) bond length is 1.46 Å. The C(3)-C(4) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(2), and one H(5) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-N(2) bond length is 1.35 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(6) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-H(6) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.45 Å. The C(8)-C(9) bond length is 1.41 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(7) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(3) and one H(9) atom. The C(11)-H(9) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(8) and one H(10) atom. The C(12)-H(10) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(1), and one O(2) atom. The C(13)-C(14) bond length is 1.49 Å. The C(13)-O(1) bond length is 1.28 Å. The C(13)-O(2) bond length is 1.28 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(19) bond length is 1.40 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(15)-H(11) bond length is 1.09 Å. In the sixteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(14) atom. The C(19)-H(14) bond length is 1.09 Å. In the seventeenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(3), and one O(4) atom. The C(21)-C(22) bond length is 1.49 Å. The C(21)-O(3) bond length is 1.27 Å. The C(21)-O(4) bond length is 1.28 Å. In the eighteenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(27) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(27) bond length is 1.41 Å. In the nineteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(18) atom. The C(23)-H(18) bond length is 1.09 Å. In the twentieth C site, C(27) is bonded in a distorted single-bond geometry to one C(22) and one H(21) atom. The C(27)-H(21) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(6) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(27) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Zn(1) and one C(13) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Zn(1) and one C(13) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Zn(1) and one C(21) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zn(1) and one C(21) atom. Linkers: 2 Cc1ccc(C([O])=O)cc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.76 A, density 1.47 g/cm3, surface area 5032.78 m2/g, accessible volume 0.17 cm3/g