CuC26H22(NO)4(CH)4(CH2)2(CH3CO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 02329_fluka molecules, two dimethyl ether molecules, and one CuC26H22(NO)4 cluster. In the CuC26H22(NO)4 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 1.96 Å. Both Cu(1)-O(1) bond lengths are 2.01 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.41 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the fifth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one H(10), one H(8), and one H(9) atom. The C(9)-C(10) bond length is 1.48 Å. The C(9)-H(10) bond length is 1.10 Å. The C(9)-H(8) bond length is 1.09 Å. The C(9)-H(9) bond length is 1.10 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one N(2) atom. The C(10)-N(1) bond length is 1.34 Å. The C(10)-N(2) bond length is 1.37 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one N(2) atom. The C(11)-C(12) bond length is 1.42 Å. The C(11)-C(16) bond length is 1.40 Å. The C(11)-N(2) bond length is 1.39 Å. In the eighth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one N(1) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-N(1) bond length is 1.39 Å. In the ninth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(11) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(11) bond length is 1.09 Å. In the tenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(12) atom. The C(14)-H(12) bond length is 1.09 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(13) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(13) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(11), one C(15), and one H(14) atom. The C(16)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(15), and one H(16) atom. The C(17)-N(2) bond length is 1.46 Å. The C(17)-H(15) bond length is 1.10 Å. The C(17)-H(16) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(12) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(17) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(17) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Linkers: 1 Cc1nc2ccccc2n1CCCCn1c(C)nc2ccccc21. Metal clusters: 1 [Cu]. The MOF has largest included sphere 1.95 A, density 1.42 g/cm3, surface area 5356.35 m2/g, accessible volume 0.21 cm3/g