ZnC10H8(NO2)2(CH)8CH2(CH2CO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two 02329_fluka molecules, four dimethyl ether molecules, two isobutylene molecules, and two ZnC10H8(NO2)2 clusters. In each ZnC10H8(NO2)2 cluster, Zn(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.09 Å. The Zn(1)-N(2) bond length is 2.03 Å. The Zn(1)-O(3) bond length is 1.97 Å. The Zn(1)-O(4) bond length is 1.98 Å. There are ten inequivalent C sites. In the first C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(5) atom. The C(7)-O(3) bond length is 1.30 Å. The C(7)-O(5) bond length is 1.25 Å. In the second C site, C(8) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(5) atom. The C(8)-C(11) bond length is 1.39 Å. The C(8)-C(13) bond length is 1.40 Å. The C(8)-H(5) bond length is 1.09 Å. In the third C site, C(11) is bonded in a distorted trigonal planar geometry to one C(8), one N(1), and one H(8) atom. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(8) bond length is 1.09 Å. In the fourth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(1), and one H(9) atom. The C(12)-C(20) bond length is 1.39 Å. The C(12)-N(1) bond length is 1.35 Å. The C(12)-H(9) bond length is 1.09 Å. In the fifth C site, C(13) is bonded in a trigonal planar geometry to one C(19), one C(20), and one C(8) atom. The C(13)-C(19) bond length is 1.50 Å. The C(13)-C(20) bond length is 1.40 Å. In the sixth C site, C(14) is bonded in a distorted trigonal planar geometry to one N(2) and one H(10) atom. The C(14)-N(2) bond length is 1.35 Å. The C(14)-H(10) bond length is 1.09 Å. In the seventh C site, C(19) is bonded in a distorted water-like geometry to one C(13), one H(17), and one H(18) atom. The C(19)-H(17) bond length is 1.10 Å. The C(19)-H(18) bond length is 1.10 Å. In the eighth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(12), one C(13), and one H(19) atom. The C(20)-H(19) bond length is 1.09 Å. In the ninth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(22) atom. The C(22)-N(2) bond length is 1.35 Å. The C(22)-H(22) bond length is 1.09 Å. In the tenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. The C(23)-O(4) bond length is 1.29 Å. The C(23)-O(6) bond length is 1.24 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(12) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(14), and one C(22) atom. There are eight inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(22) is bonded in a single-bond geometry to one C(22) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(23) atom. In the third O site, O(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(23) atom. Linkers: 2 [O]C(=O)COc1ccc(OCC([O])=O)cc1 ,2 [O][C]COc1ccc(OCC([O])=O)cc1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.24 A, density 1.55 g/cm3, surface area 4852.37 m2/g, accessible volume 0.17 cm3/g