CuC8H10(N2Cl)2CH2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CuC8H10(N2Cl)2 clusters. In each CuC8H10(N2Cl)2 cluster, Cu(1) is bonded to two equivalent N(1), one Cl(2), and two equivalent Cl(1) atoms to form distorted edge-sharing CuN2Cl3 square pyramids. Both Cu(1)-N(1) bond lengths are 1.96 Å. The Cu(1)-Cl(2) bond length is 2.33 Å. There is one shorter (2.44 Å) and one longer (2.61 Å) Cu(1)-Cl(1) bond length. There are four inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(6) atom. The C(5)-C(4) bond length is 1.40 Å. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(6) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent H(2,3) atoms. The C(2)-N(2) bond length is 1.46 Å. Both C(2)-H(2,3) bond lengths are 1.10 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(4) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-N(2) bond length is 1.36 Å. The C(3)-H(4) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(5) atom. The C(4)-H(5) bond length is 1.08 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(5), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one N(1) atom. There are four inequivalent H sites. In the first H site, H(2,3) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in an L-shaped geometry to two equivalent Cu(1) atoms. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 2 c1cnn(CCCn2cccn2)c1. Metal clusters: 1 Cl[Cu]Cl.Cl[Cu]Cl. The MOF has largest included sphere 2.09 A, density 1.82 g/cm3, surface area 4158.58 m2/g, accessible volume 0.08 cm3/g