CoC14H14(N2Cl)2 is Indium-like structured and crystallizes in the orthorhombic Pbcn space group. The structure is zero-dimensional and consists of four CoC14H14(N2Cl)2 clusters. Co(1) is bonded in a tetrahedral geometry to two equivalent N(2) and two equivalent Cl(1) atoms. Both Co(1)-N(2) bond lengths are 1.96 Å. Both Co(1)-Cl(1) bond lengths are 2.25 Å. There are seven inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(5) atom. The C(2)-C(3) bond length is 1.51 Å. The C(2)-C(4) bond length is 1.40 Å. The C(2)-C(5) bond length is 1.40 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(1), and one H(6) atom. The C(6)-C(7) bond length is 1.37 Å. The C(6)-N(1) bond length is 1.38 Å. The C(6)-H(6) bond length is 1.08 Å. In the third C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(2) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(2) bond length is 1.09 Å. In the fourth C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one N(1), one H(1), and one H(7) atom. The C(3)-N(1) bond length is 1.47 Å. The C(3)-H(1) bond length is 1.10 Å. The C(3)-H(7) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(2), and one H(4) atom. The C(7)-N(2) bond length is 1.38 Å. The C(7)-H(4) bond length is 1.08 Å. In the seventh C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(4)-H(5) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(7) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(4) is bonded in a single-bond geometry to one C(7) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom. Linkers: 4 c1cn(Cc2ccc(Cn3ccnc3)cc2)cn1. Metal clusters: 4 Cl[Co]Cl. The MOF has largest included sphere 2.75 A, density 1.49 g/cm3, surface area 4884.73 m2/g, accessible volume 0.17 cm3/g