Y2C37H25(NO5)3(CH)2 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a Y2C37H25(NO5)3 framework. In the Y2C37H25(NO5)3 framework, there are two inequivalent Y sites. In the first Y site, Y(1) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(13), one O(4), one O(5), one O(6), and two equivalent O(3) atoms. The Y(1)-O(1) bond length is 2.27 Å. The Y(1)-O(11) bond length is 2.21 Å. The Y(1)-O(13) bond length is 2.37 Å. The Y(1)-O(4) bond length is 2.42 Å. The Y(1)-O(5) bond length is 2.40 Å. The Y(1)-O(6) bond length is 2.38 Å. There is one shorter (2.36 Å) and one longer (2.48 Å) Y(1)-O(3) bond length. In the second Y site, Y(2) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(14), one O(15), one O(2), one O(7), one O(8), and one O(9) atom. The Y(2)-O(10) bond length is 2.47 Å. The Y(2)-O(12) bond length is 2.30 Å. The Y(2)-O(14) bond length is 2.38 Å. The Y(2)-O(15) bond length is 2.44 Å. The Y(2)-O(2) bond length is 2.24 Å. The Y(2)-O(7) bond length is 2.32 Å. The Y(2)-O(8) bond length is 2.39 Å. The Y(2)-O(9) bond length is 2.40 Å. There are thirty-seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(7) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-H(7) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(8) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(8) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(7) bond length is 1.48 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(2), one C(5), and one H(9) atom. The C(6)-H(9) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(5), and one C(8) atom. The C(7)-C(12) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(10) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(10) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(11) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(11) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(12) atom. The C(10)-H(12) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(13) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(13) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(7) atom. The C(12)-C(13) bond length is 1.49 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(3), and one O(4) atom. The C(13)-O(3) bond length is 1.30 Å. The C(13)-O(4) bond length is 1.26 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(5), and one O(6) atom. The C(14)-C(15) bond length is 1.50 Å. The C(14)-O(5) bond length is 1.28 Å. The C(14)-O(6) bond length is 1.27 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(19) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(19) bond length is 1.40 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one N(2), and one H(14) atom. The C(16)-N(2) bond length is 1.34 Å. The C(16)-H(14) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(18), one N(2), and one H(15) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-N(2) bond length is 1.35 Å. The C(17)-H(15) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(20) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(20) bond length is 1.48 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(15), one C(18), and one H(16) atom. The C(19)-H(16) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(18), one C(21), and one C(25) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(25) bond length is 1.42 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(17) atom. The C(21)-H(17) bond length is 1.09 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(20) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-H(20) bond length is 1.09 Å. In the twenty-third C site, C(25) is bonded in a trigonal planar geometry to one C(20), one C(24), and one C(26) atom. The C(25)-C(26) bond length is 1.50 Å. In the twenty-fourth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(7), and one O(8) atom. The C(26)-O(7) bond length is 1.28 Å. The C(26)-O(8) bond length is 1.27 Å. In the twenty-fifth C site, C(27) is bonded in a bent 120 degrees geometry to one C(28), one O(10), and one O(9) atom. The C(27)-C(28) bond length is 1.50 Å. The C(27)-O(10) bond length is 1.28 Å. The C(27)-O(9) bond length is 1.28 Å. In the twenty-sixth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(33) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-C(33) bond length is 1.41 Å. In the twenty-seventh C site, C(29) is bonded in a distorted single-bond geometry to one C(28), one C(30), and one H(21) atom. The C(29)-C(30) bond length is 1.39 Å. The C(29)-H(21) bond length is 1.09 Å. In the twenty-eighth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one C(31), and one H(22) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-H(22) bond length is 1.09 Å. In the twenty-ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(23) atom. The C(31)-H(23) bond length is 1.09 Å. In the thirtieth C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(24) atom. The C(32)-C(33) bond length is 1.40 Å. The C(32)-H(24) bond length is 1.09 Å. In the thirty-first C site, C(33) is bonded in a trigonal planar geometry to one C(28), one C(32), and one C(34) atom. The C(33)-C(34) bond length is 1.48 Å. In the thirty-second C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(38) atom. The C(34)-C(35) bond length is 1.41 Å. The C(34)-C(38) bond length is 1.40 Å. In the thirty-third C site, C(35) is bonded in a distorted trigonal planar geometry to one C(34), one N(3), and one H(25) atom. The C(35)-N(3) bond length is 1.34 Å. The C(35)-H(25) bond length is 1.09 Å. In the thirty-fourth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(37), one N(3), and one H(26) atom. The C(36)-C(37) bond length is 1.39 Å. The C(36)-N(3) bond length is 1.34 Å. The C(36)-H(26) bond length is 1.09 Å. In the thirty-fifth C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one C(39) atom. The C(37)-C(38) bond length is 1.40 Å. The C(37)-C(39) bond length is 1.49 Å. In the thirty-sixth C site, C(38) is bonded in a distorted single-bond geometry to one C(34), one C(37), and one H(27) atom. The C(38)-H(27) bond length is 1.09 Å. In the thirty-seventh C site, C(39) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(11), and one O(12) atom. The C(39)-O(11) bond length is 1.27 Å. The C(39)-O(12) bond length is 1.26 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(3) and one C(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(16) and one C(17) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(35), one C(36), and one H(2) atom. The N(3)-H(2) bond length is 1.64 Å. There are twenty-five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(13) atom. The H(1)-O(13) bond length is 0.97 Å. In the second H site, H(2) is bonded in a distorted linear geometry to one N(3) and one O(13) atom. The H(2)-O(13) bond length is 1.03 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(14) atom. The H(3)-O(14) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(14) atom. The H(4)-O(14) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(15) atom. The H(5)-O(15) bond length is 0.97 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(15) atom. The H(6)-O(15) bond length is 0.98 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(30) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(32) atom. In the twenty-third H site, H(25) is bonded in a single-bond geometry to one C(35) atom. In the twenty-fourth H site, H(26) is bonded in a single-bond geometry to one C(36) atom. In the twenty-fifth H site, H(27) is bonded in a single-bond geometry to one C(38) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Y(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Y(2) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Y(1) and one C(13) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Y(1) and one C(13) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Y(1) and one C(14) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one C(14) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Y(2) and one C(26) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Y(2) and one C(26) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Y(2) and one C(27) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Y(2) and one C(27) atom. In the eleventh O site, O(11) is bonded in a linear geometry to one Y(1) and one C(39) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Y(2) and one C(39) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one Y(1), one H(1), and one H(2) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Y(2), one H(3), and one H(4) atom. In the fifteenth O site, O(15) is bonded in a distorted water-like geometry to one Y(2), one H(5), and one H(6) atom. Linkers: 6 [O]C(=O)c1cncc(-c2ccccc2C([O])=O)c1. Metal clusters: 4 [Y]. The MOF has largest included sphere 3.97 A, density 1.57 g/cm3, surface area 3754.82 m2/g, accessible volume 0.17 cm3/g