ZnC10NH3(OF)4(C3F2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four C3F2 clusters and two ZnC10NH3(OF)4 clusters. In each C3F2 cluster, there are six inequivalent C sites. In the first C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(7) atom. The C(9)-C(10) bond length is 1.47 Å. The C(9)-C(11) bond length is 1.40 Å. The C(9)-C(7) bond length is 1.40 Å. In the second C site, C(10) is bonded in a trigonal planar geometry to one C(12), one C(8), and one C(9) atom. The C(10)-C(12) bond length is 1.40 Å. The C(10)-C(8) bond length is 1.40 Å. In the third C site, C(11) is bonded in a distorted single-bond geometry to one C(9) and one F(3,4,5,6) atom. The C(11)-F(3,4,5,6) bond length is 1.36 Å. In the fourth C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one F(3,4,5,6) atom. The C(12)-F(3,4,5,6) bond length is 1.36 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(9) and one F(3,4,5,6) atom. The C(7)-F(3,4,5,6) bond length is 1.36 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(10) and one F(3,4,5,6) atom. The C(8)-F(3,4,5,6) bond length is 1.36 Å. F(3,4,5,6) is bonded in a single-bond geometry to one C(7) atom. In each ZnC10NH3(OF)4 cluster, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one O(1), one O(3), one O(5), and one O(7) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 2.06 Å. The Zn(1)-O(3) bond length is 2.05 Å. The Zn(1)-O(5) bond length is 2.07 Å. The Zn(1)-O(7) bond length is 2.08 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(3) bond length is 1.27 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(5) atom. The C(3)-C(13) bond length is 1.39 Å. The C(3)-C(5) bond length is 1.39 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one F(1,2,7,8) atom. The C(5)-F(1,2,7,8) bond length is 1.35 Å. In the fourth C site, C(13) is bonded in a distorted single-bond geometry to one C(3) and one F(1,2,7,8) atom. The C(13)-F(1,2,7,8) bond length is 1.35 Å. In the fifth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(5), and one O(7) atom. The C(15)-C(17) bond length is 1.51 Å. The C(15)-O(5) bond length is 1.27 Å. The C(15)-O(7) bond length is 1.26 Å. In the sixth C site, C(17) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(27) atom. The C(17)-C(19) bond length is 1.40 Å. The C(17)-C(27) bond length is 1.40 Å. In the seventh C site, C(19) is bonded in a distorted single-bond geometry to one C(17) and one F(9,10) atom. The C(19)-F(9,10) bond length is 1.35 Å. In the eighth C site, C(27) is bonded in a single-bond geometry to one C(17) and one F(15,16) atom. The C(27)-F(15,16) bond length is 1.35 Å. In the ninth C site, C(29) is bonded in a distorted trigonal non-coplanar geometry to one C(31,32); one H(1,2); one H(3,4); and one H(5,6) atom. The C(29)-C(31,32) bond length is 1.44 Å. The C(29)-H(1,2) bond length is 1.10 Å. The C(29)-H(3,4) bond length is 1.10 Å. The C(29)-H(5,6) bond length is 1.10 Å. In the tenth C site, C(31,32) is bonded in a linear geometry to one C(29) and one N(1) atom. The C(31,32)-N(1) bond length is 1.16 Å. N(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(31,32) atom. There are three inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(29) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(29) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(29) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(15) atom. In the fourth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(15) atom. There are three inequivalent F sites. In the first F site, F(15,16) is bonded in a single-bond geometry to one C(27) atom. In the second F site, F(1,2,7,8) is bonded in a single-bond geometry to one C(5) atom. In the third F site, F(9,10) is bonded in a single-bond geometry to one C(19) atom. Linkers: 4 [O]C(=O)c1c(F)c(F)c(-c2c(F)c(F)c(C([O])=O)c(F)c2F)c(F)c1F. Metal clusters: 4 [Zn]. The MOF has largest included sphere 4.21 A, density 1.44 g/cm3, surface area 4004.42 m2/g, accessible volume 0.28 cm3/g