(C6H5NH)2Cd3C24H24Br6(N2O)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one schembl659509 molecule and one Cd3C24H24Br6(N2O)4 cluster. In the Cd3C24H24Br6(N2O)4 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to two equivalent N(1), two equivalent N(3), and two equivalent Br(1) atoms to form distorted corner-sharing CdBr2N4 octahedra. Both Cd(1)-N(1) bond lengths are 2.31 Å. Both Cd(1)-N(3) bond lengths are 2.35 Å. Both Cd(1)-Br(1) bond lengths are 2.95 Å. In the second Cd site, Cd(2) is bonded to one O(1), one Br(1), one Br(2), and one Br(3) atom to form corner-sharing CdBr3O tetrahedra. The corner-sharing octahedral tilt angles are 69°. The Cd(2)-O(1) bond length is 2.27 Å. The Cd(2)-Br(1) bond length is 2.65 Å. The Cd(2)-Br(2) bond length is 2.63 Å. The Cd(2)-Br(3) bond length is 2.61 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(1) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(4), and one H(5) atom. The C(4)-N(2) bond length is 1.46 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(6) atom. The C(5)-N(3) bond length is 1.33 Å. The C(5)-N(4) bond length is 1.36 Å. The C(5)-H(6) bond length is 1.08 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(3), and one H(7) atom. The C(6)-C(7) bond length is 1.37 Å. The C(6)-N(3) bond length is 1.38 Å. The C(6)-H(7) bond length is 1.08 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(4), and one H(8) atom. The C(7)-N(4) bond length is 1.38 Å. The C(7)-H(8) bond length is 1.08 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(10), and one H(9) atom. The C(8)-N(4) bond length is 1.46 Å. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(1), and one O(2) atom. The C(9)-C(10) bond length is 1.51 Å. The C(9)-O(1) bond length is 1.28 Å. The C(9)-O(2) bond length is 1.25 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(18), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(18) bond length is 1.39 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(11) atom. The C(11)-H(11) bond length is 1.09 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(10) and one H(18) atom. The C(18)-H(18) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(5), and one C(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cd(2) and one C(9) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(9) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a water-like geometry to one Cd(1) and one Cd(2) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Cd(2) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Cd(2) atom. Linkers: 1 [O]C(=O)C1=C[CH]N(Cc2ccc(CN3[CH]C=C(C([O])=O)C=C3)cc2)C=C1. Metal clusters: 1 O=[C]O[Cd](Br)(Br)Br.O=[C]O[Cd](Br)(Br)Br.[Cd]. The MOF has largest included sphere 4.34 A, density 1.98 g/cm3, surface area 3434.76 m2/g, accessible volume 0.11 cm3/g