ZnC14H10(NO2)2(CH)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two ZnC14H10(NO2)2 clusters. In each ZnC14H10(NO2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Zn(1)-N(1) bond length is 2.06 Å. The Zn(1)-N(2) bond length is 2.06 Å. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(2) bond length is 1.97 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(7,8) and one H(1,2) atom. The C(1)-C(7,8) bond length is 1.41 Å. The C(1)-H(1,2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(7,8) and one H(1,2) atom. The C(2)-C(7,8) bond length is 1.41 Å. The C(2)-H(1,2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(3) atom. The C(3)-C(9) bond length is 1.38 Å. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(10), one N(2), and one H(4) atom. The C(4)-C(10) bond length is 1.38 Å. The C(4)-N(2) bond length is 1.35 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(5)-O(1) bond length is 1.31 Å. The C(5)-O(3) bond length is 1.25 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(6)-O(2) bond length is 1.31 Å. The C(6)-O(4) bond length is 1.25 Å. In the seventh C site, C(7,8) is bonded in a trigonal planar geometry to one C(1), one C(17), and one C(9) atom. The C(7,8)-C(17) bond length is 1.46 Å. The C(7,8)-C(9) bond length is 1.41 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(3); one C(7,8); and one H(5,6) atom. The C(9)-H(5,6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(4); one C(7,8); and one H(5,6) atom. The C(10)-C(7,8) bond length is 1.41 Å. The C(10)-H(5,6) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(7,8) atom. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(7,8) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7,8) atom. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(7,8) bond length is 1.09 Å. In the twelfth C site, C(17) is bonded in a distorted single-bond geometry to one C(7,8) and one H(11,12) atom. The C(17)-H(11,12) bond length is 1.09 Å. In the thirteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(7,8) and one H(11,12) atom. The C(18)-C(7,8) bond length is 1.46 Å. The C(18)-H(11,12) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(12), and one C(4) atom. There are six inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7,8) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(17) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(6) atom. Linkers: 2 [O]C(=O)/C=C/C=C/C([O])=O ,2 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.22 A, density 1.44 g/cm3, surface area 4587.17 m2/g, accessible volume 0.26 cm3/g