Ag2C8H8S(NO)4 crystallizes in the monoclinic C2/c space group. Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Ag(1)-N(1) bond length is 2.21 Å. The Ag(1)-N(2) bond length is 2.21 Å. The Ag(1)-O(1) bond length is 2.54 Å. The Ag(1)-O(2) bond length is 2.60 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(2), and one H(2) atom. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-N(2) bond length is 1.35 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(4) atom. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(4) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(2), and one C(3) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. S(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Both S(1)-O(1) bond lengths are 1.49 Å. Both S(1)-O(2) bond lengths are 1.50 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one S(1) atom. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one S(1) atom. Linkers: 4 c1cnccn1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.81 A, density 2.75 g/cm3, surface area 2299.52 m2/g, accessible volume 0.05 cm3/g