CuC14NH6O4(CH)3 crystallizes in the orthorhombic Pbca space group. The structure consists of twenty-four 02329_fluka molecules inside a CuC14NH6O4 framework. In the CuC14NH6O4 framework, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-N(1) bond length is 2.22 Å. The Cu(1)-O(1) bond length is 1.99 Å. The Cu(1)-O(2) bond length is 1.99 Å. The Cu(1)-O(3) bond length is 2.01 Å. The Cu(1)-O(4) bond length is 2.00 Å. There are fourteen inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(9)-C(4) bond length is 1.42 Å. The C(9)-H(6) bond length is 1.09 Å. In the second C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(3) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.40 Å. The C(10)-C(3) bond length is 1.48 Å. In the third C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(7) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(7) bond length is 1.09 Å. In the fourth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(16) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(16) bond length is 1.50 Å. In the fifth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(8) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-H(8) bond length is 1.09 Å. In the sixth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(17) bond length is 1.50 Å. In the seventh C site, C(15) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one H(9) atom. The C(15)-H(9) bond length is 1.09 Å. In the eighth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(16)-O(1) bond length is 1.28 Å. The C(16)-O(2) bond length is 1.27 Å. In the ninth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the tenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(3), and one O(4) atom. The C(17)-O(3) bond length is 1.27 Å. The C(17)-O(4) bond length is 1.27 Å. In the eleventh C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.09 Å. In the twelfth C site, C(3) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(4) atom. The C(3)-C(4) bond length is 1.43 Å. In the thirteenth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(4)-C(5) bond length is 1.44 Å. In the fourteenth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one N(1) atom. The C(5)-N(1) bond length is 1.37 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(16) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(16) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(17) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(17) atom. Linkers: 8 [O]C(=O)c1cc(C([O])=O)cc(-c2ccnc3ccccc23)c1. Metal clusters: 4 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 4.51 A, density 1.27 g/cm3, surface area 4021.16 m2/g, accessible volume 0.28 cm3/g