CuC12H6(N3O)2(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one CuC12H6(N3O)2 cluster. In the CuC12H6(N3O)2 cluster, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Cu(1)-N(1) bond lengths are 2.05 Å. Both Cu(1)-N(2) bond lengths are 2.00 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(7), and one N(1) atom. The C(1)-C(2) bond length is 1.46 Å. The C(1)-C(7) bond length is 1.41 Å. The C(1)-N(1) bond length is 1.34 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(6), and one N(2) atom. The C(2)-C(6) bond length is 1.40 Å. The C(2)-N(2) bond length is 1.36 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one H(3) atom. The C(5)-N(2) bond length is 1.34 Å. The C(5)-H(3) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(1) and one N(3) atom. The C(7)-N(3) bond length is 1.17 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one O(1) atom. The N(1)-O(1) bond length is 1.28 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(2), and one C(5) atom. In the third N site, N(3) is bonded in a single-bond geometry to one C(7) atom. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. Linkers: 2 N#C/C(=N\[O])c1ccccn1. Metal clusters: 1 [Cu]. The MOF has largest included sphere 1.62 A, density 1.81 g/cm3, surface area 4226.68 m2/g, accessible volume 0.08 cm3/g