(CH3)4CdC18P2H22S4(NO)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one CdC18P2H22S4(NO)4 cluster. In the CdC18P2H22S4(NO)4 cluster, Cd(1) is bonded to two equivalent N(1), two equivalent S(1), and two equivalent S(2) atoms to form distorted CdS4N2 octahedra that share edges with two equivalent P(1)S2O2 tetrahedra. Both Cd(1)-N(1) bond lengths are 2.34 Å. Both Cd(1)-S(1) bond lengths are 2.71 Å. Both Cd(1)-S(2) bond lengths are 2.82 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(1) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.38 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one N(2), one H(4), and one H(5) atom. The C(4)-C(5) bond length is 1.51 Å. The C(4)-N(2) bond length is 1.46 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(7) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(6) atom. The C(6)-H(6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one H(7) atom. The C(7)-H(7) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one H(8), one H(9), and one O(1) atom. The C(8)-H(8) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. The C(8)-O(1) bond length is 1.46 Å. In the ninth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one H(13), one H(14), and one O(2) atom. The C(10)-H(13) bond length is 1.10 Å. The C(10)-H(14) bond length is 1.10 Å. The C(10)-O(2) bond length is 1.46 Å. P(1) is bonded to one S(1), one S(2), one O(1), and one O(2) atom to form distorted PS2O2 tetrahedra that share  an edgeedge with one Cd(1)S4N2 octahedra. The P(1)-S(1) bond length is 1.99 Å. The P(1)-S(2) bond length is 1.99 Å. The P(1)-O(1) bond length is 1.63 Å. The P(1)-O(2) bond length is 1.61 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Cd(1) and one P(1) atom. In the second S site, S(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one P(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(8) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(10) and one P(1) atom. Linkers: 1 c1cn(Cc2ccc(Cn3ccnc3)cc2)cn1. Metal clusters: 1 [Cd]. The MOF has largest included sphere 2.38 A, density 1.61 g/cm3, surface area 5086.36 m2/g, accessible volume 0.14 cm3/g