Cd7C64H48(N8O13)2 crystallizes in the triclinic P-1 space group. There are four inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to two equivalent O(12), two equivalent O(13), and two equivalent O(6) atoms to form CdO6 octahedra that share corners with two equivalent Cd(2)NO4 trigonal bipyramids and edges with two equivalent Cd(4)NO5 octahedra. Both Cd(1)-O(12) bond lengths are 2.29 Å. Both Cd(1)-O(13) bond lengths are 2.30 Å. Both Cd(1)-O(6) bond lengths are 2.41 Å. In the second Cd site, Cd(2) is bonded to one N(1), one O(13), one O(5), one O(7), and one O(9) atom to form distorted CdNO4 trigonal bipyramids that share  a cornercorner with one Cd(4)NO5 octahedra and  a cornercorner with one Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 64-73°. The Cd(2)-N(1) bond length is 2.36 Å. The Cd(2)-O(13) bond length is 2.23 Å. The Cd(2)-O(5) bond length is 2.26 Å. The Cd(2)-O(7) bond length is 2.37 Å. The Cd(2)-O(9) bond length is 2.25 Å. In the third Cd site, Cd(3) is bonded to one N(5), one N(7), one O(2), two equivalent O(1), and two equivalent O(4) atoms to form distorted edge-sharing CdN2O5 pentagonal bipyramids. The Cd(3)-N(5) bond length is 2.37 Å. The Cd(3)-N(7) bond length is 2.30 Å. The Cd(3)-O(2) bond length is 2.38 Å. There is one shorter (2.43 Å) and one longer (2.71 Å) Cd(3)-O(1) bond length. There is one shorter (2.32 Å) and one longer (2.45 Å) Cd(3)-O(4) bond length. In the fourth Cd site, Cd(4) is bonded to one N(4), one O(10), one O(11), one O(13), one O(6), and one O(8) atom to form CdNO5 octahedra that share  a cornercorner with one Cd(2)NO4 trigonal bipyramid and  an edgeedge with one Cd(1)O6 octahedra. The Cd(4)-N(4) bond length is 2.38 Å. The Cd(4)-O(10) bond length is 2.27 Å. The Cd(4)-O(11) bond length is 2.25 Å. The Cd(4)-O(13) bond length is 2.34 Å. The Cd(4)-O(6) bond length is 2.42 Å. The Cd(4)-O(8) bond length is 2.28 Å. There are thirty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-N(1) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one N(2), one H(4), and one H(5) atom. The C(4)-C(5) bond length is 1.57 Å. The C(4)-N(2) bond length is 1.46 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a tetrahedral geometry to one C(10), one C(17), one C(4), and one C(6) atom. The C(5)-C(10) bond length is 1.56 Å. The C(5)-C(17) bond length is 1.56 Å. The C(5)-C(6) bond length is 1.55 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one N(8), one H(6), and one H(7) atom. The C(6)-N(8) bond length is 1.46 Å. The C(6)-H(6) bond length is 1.10 Å. The C(6)-H(7) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(8), and one H(8) atom. The C(7)-C(8) bond length is 1.37 Å. The C(7)-N(8) bond length is 1.39 Å. The C(7)-H(8) bond length is 1.08 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(7), and one H(9) atom. The C(8)-N(7) bond length is 1.38 Å. The C(8)-H(9) bond length is 1.08 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(10) atom. The C(9)-N(7) bond length is 1.32 Å. The C(9)-N(8) bond length is 1.36 Å. The C(9)-H(10) bond length is 1.08 Å. In the tenth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one N(3), one H(11), and one H(12) atom. The C(10)-N(3) bond length is 1.46 Å. The C(10)-H(11) bond length is 1.10 Å. The C(10)-H(12) bond length is 1.10 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(3), and one H(13) atom. The C(11)-C(13) bond length is 1.37 Å. The C(11)-N(3) bond length is 1.39 Å. The C(11)-H(13) bond length is 1.08 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(14) atom. The C(12)-N(3) bond length is 1.37 Å. The C(12)-N(4) bond length is 1.33 Å. The C(12)-H(14) bond length is 1.08 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(4), and one H(15) atom. The C(13)-N(4) bond length is 1.38 Å. The C(13)-H(15) bond length is 1.08 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(16) atom. The C(14)-N(5) bond length is 1.33 Å. The C(14)-N(6) bond length is 1.37 Å. The C(14)-H(16) bond length is 1.08 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(5), and one H(17) atom. The C(15)-C(16) bond length is 1.37 Å. The C(15)-N(5) bond length is 1.38 Å. The C(15)-H(17) bond length is 1.08 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(6), and one H(18) atom. The C(16)-N(6) bond length is 1.39 Å. The C(16)-H(18) bond length is 1.08 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one N(6), one H(19), and one H(20) atom. The C(17)-N(6) bond length is 1.46 Å. The C(17)-H(19) bond length is 1.10 Å. The C(17)-H(20) bond length is 1.10 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(3), and one O(4) atom. The C(18)-C(19) bond length is 1.51 Å. The C(18)-O(3) bond length is 1.24 Å. The C(18)-O(4) bond length is 1.30 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-C(24) bond length is 1.40 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(27) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-C(27) bond length is 1.51 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one H(21) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-H(21) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(26) atom. The C(22)-C(23) bond length is 1.41 Å. The C(22)-C(26) bond length is 1.50 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(25) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(25) bond length is 1.51 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(19), one C(23), and one H(22) atom. The C(24)-H(22) bond length is 1.09 Å. In the twenty-fifth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(7), and one O(8) atom. The C(25)-O(7) bond length is 1.28 Å. The C(25)-O(8) bond length is 1.27 Å. In the twenty-sixth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(5), and one O(6) atom. The C(26)-O(5) bond length is 1.26 Å. The C(26)-O(6) bond length is 1.28 Å. In the twenty-seventh C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(1), and one O(2) atom. The C(27)-O(1) bond length is 1.28 Å. The C(27)-O(2) bond length is 1.27 Å. In the twenty-eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(10), and one O(9) atom. The C(28)-C(29) bond length is 1.50 Å. The C(28)-O(10) bond length is 1.27 Å. The C(28)-O(9) bond length is 1.27 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(31) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-C(31) bond length is 1.39 Å. In the thirtieth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(32) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-C(32) bond length is 1.50 Å. In the thirty-first C site, C(31) is bonded in a distorted single-bond geometry to one C(29), one C(30), and one H(23) atom. The C(31)-H(23) bond length is 1.09 Å. In the thirty-second C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(11), and one O(12) atom. The C(32)-O(11) bond length is 1.27 Å. The C(32)-O(12) bond length is 1.27 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(12) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(4), one C(12), and one C(13) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cd(3), one C(14), and one C(15) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(17) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Cd(3), one C(8), and one C(9) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(6), one C(7), and one C(9) atom. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(17) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(21) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(24) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one O(13) atom. The H(24)-O(13) bond length is 0.98 Å. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Cd(3) and one C(27) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(3) and one C(27) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(18) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Cd(3) and one C(18) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Cd(2) and one C(26) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(4), and one C(26) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Cd(2) and one C(25) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Cd(4) and one C(25) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Cd(2) and one C(28) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Cd(4) and one C(28) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Cd(4) and one C(32) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(32) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), one Cd(4), and one H(24) atom. Linkers: 3 [O]C(=O)c1cc(C([O])=O)c(C([O])=O)cc1C([O])=O ,2 c1cn(CC(Cn2ccnc2)(Cn2ccnc2)Cn2ccnc2)cn1. Metal clusters: 7 [Cd]. The MOF has largest included sphere 3.43 A, density 2.06 g/cm3, surface area 3101.57 m2/g, accessible volume 0.14 cm3/g