CdC16H14(N2O3)2(CH2)2(C3H2Cl)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four 2-chloropropene molecules, and two CdC16H14(N2O3)2 clusters. In each CdC16H14(N2O3)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to two N(1,1); two O(1,1); and two O(2,2) atoms. Both Cd(1)-N(1,1) bond lengths are 2.24 Å. Both Cd(1)-O(1,1) bond lengths are 2.31 Å. Both Cd(1)-O(2,2) bond lengths are 2.63 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(2) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(3) atom. The C(3)-N(1) bond length is 1.38 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(4), and one H(5) atom. The C(4)-N(2) bond length is 1.46 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(7) atom. The C(6)-C(11) bond length is 1.40 Å. The C(6)-C(12) bond length is 1.48 Å. The C(6)-C(7) bond length is 1.42 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(7) atom. The C(6)-C(11) bond length is 1.40 Å. The C(6)-C(12) bond length is 1.48 Å. The C(6)-C(7) bond length is 1.42 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one O(3) atom. The C(7)-O(3) bond length is 1.35 Å. In the eighth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one O(3) atom. The C(7)-O(3) bond length is 1.35 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(6) and one H(10) atom. The C(11)-H(10) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(6) and one H(10) atom. The C(11)-H(10) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(2) atom. The C(12)-O(1) bond length is 1.28 Å. The C(12)-O(2) bond length is 1.29 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(2) atom. The C(12)-O(1) bond length is 1.28 Å. The C(12)-O(2) bond length is 1.29 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(3) atom. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(3) atom. The N(1)-C(1) bond length is 1.33 Å. The N(1)-C(3) bond length is 1.38 Å. In the third N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(4) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(11) is bonded in a bent 150 degrees geometry to one O(2) and one O(3) atom. The H(11)-O(2) bond length is 1.53 Å. The H(11)-O(3) bond length is 1.03 Å. In the eighth H site, H(11) is bonded in a bent 150 degrees geometry to one O(2) and one O(3) atom. The H(11)-O(2) bond length is 1.53 Å. The H(11)-O(3) bond length is 1.03 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1) and one C(12) atom. In the second O site, O(1) is bonded in a distorted water-like geometry to one Cd(1) and one C(12) atom. In the third O site, O(2) is bonded in a distorted water-like geometry to one Cd(1), one C(12), and one H(11) atom. In the fourth O site, O(2) is bonded in a distorted water-like geometry to one Cd(1), one C(12), and one H(11) atom. In the fifth O site, O(3) is bonded in a water-like geometry to one C(7) and one H(11) atom. In the sixth O site, O(3) is bonded in a water-like geometry to one C(7) and one H(11) atom. Linkers: 2 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 2.41 A, density 1.71 g/cm3, surface area 4724.60 m2/g, accessible volume 0.12 cm3/g