(CH)2(CH2)4CuC10H12S2I is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, thirty-two 02329_fluka molecules, and two CuC10H12S2I clusters. In each CuC10H12S2I cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one S(2), one S(4), one I(1), and one I(2) atom to form distorted edge-sharing CuS2I2 tetrahedra. The Cu(1)-S(2) bond length is 2.30 Å. The Cu(1)-S(4) bond length is 2.33 Å. The Cu(1)-I(1) bond length is 2.64 Å. The Cu(1)-I(2) bond length is 2.64 Å. In the second Cu site, Cu(2) is bonded to one S(1), one S(3), one I(1), and one I(2) atom to form distorted edge-sharing CuS2I2 tetrahedra. The Cu(2)-S(1) bond length is 2.27 Å. The Cu(2)-S(3) bond length is 2.30 Å. The Cu(2)-I(1) bond length is 2.63 Å. The Cu(2)-I(2) bond length is 2.63 Å. There are twenty inequivalent C sites. In the first C site, C(24) is bonded in a distorted water-like geometry to one H(35), one H(36), and one S(4) atom. The C(24)-H(35) bond length is 1.10 Å. The C(24)-H(36) bond length is 1.10 Å. The C(24)-S(4) bond length is 1.82 Å. In the second C site, C(25) is bonded in a distorted water-like geometry to one C(26), one H(37), one H(38), and one S(4) atom. The C(25)-C(26) bond length is 1.50 Å. The C(25)-H(37) bond length is 1.10 Å. The C(25)-H(38) bond length is 1.10 Å. The C(25)-S(4) bond length is 1.83 Å. In the third C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(31) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-C(31) bond length is 1.40 Å. In the fourth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(26), one C(28), and one H(39) atom. The C(27)-C(28) bond length is 1.39 Å. The C(27)-H(39) bond length is 1.09 Å. In the fifth C site, C(28) is bonded in a distorted single-bond geometry to one C(27), one C(29), and one H(40) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-H(40) bond length is 1.09 Å. In the sixth C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(32) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-C(32) bond length is 1.50 Å. In the seventh C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(41) atom. The C(30)-H(41) bond length is 1.09 Å. In the eighth C site, C(31) is bonded in a distorted single-bond geometry to one C(26) and one H(42) atom. The C(31)-H(42) bond length is 1.09 Å. In the ninth C site, C(32) is bonded in a distorted water-like geometry to one C(29), one H(43), one H(44), and one S(1) atom. The C(32)-H(43) bond length is 1.10 Å. The C(32)-H(44) bond length is 1.10 Å. The C(32)-S(1) bond length is 1.84 Å. In the tenth C site, C(1) is bonded in a distorted water-like geometry to one H(1), one H(2), and one S(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.82 Å. In the eleventh C site, C(8) is bonded in a distorted water-like geometry to one H(13), one H(14), and one S(2) atom. The C(8)-H(13) bond length is 1.10 Å. The C(8)-H(14) bond length is 1.10 Å. The C(8)-S(2) bond length is 1.82 Å. In the twelfth C site, C(9) is bonded in a distorted water-like geometry to one C(10), one H(15), one H(16), and one S(2) atom. The C(9)-C(10) bond length is 1.50 Å. The C(9)-H(15) bond length is 1.10 Å. The C(9)-H(16) bond length is 1.10 Å. The C(9)-S(2) bond length is 1.84 Å. In the thirteenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.40 Å. In the fourteenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(17) atom. The C(11)-H(17) bond length is 1.09 Å. In the fifteenth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(18) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(18) bond length is 1.09 Å. In the sixteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(16) bond length is 1.50 Å. In the seventeenth C site, C(14) is bonded in a single-bond geometry to one C(13) and one H(19) atom. The C(14)-H(19) bond length is 1.09 Å. In the eighteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one H(20) atom. The C(15)-H(20) bond length is 1.09 Å. In the nineteenth C site, C(16) is bonded in a distorted water-like geometry to one C(13), one H(21), one H(22), and one S(3) atom. The C(16)-H(21) bond length is 1.10 Å. The C(16)-H(22) bond length is 1.10 Å. The C(16)-S(3) bond length is 1.84 Å. In the twentieth C site, C(17) is bonded in a distorted water-like geometry to one H(23), one H(24), and one S(3) atom. The C(17)-H(23) bond length is 1.10 Å. The C(17)-H(24) bond length is 1.10 Å. The C(17)-S(3) bond length is 1.82 Å. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(35) is bonded in a single-bond geometry to one C(24) atom. In the fourth H site, H(36) is bonded in a single-bond geometry to one C(24) atom. In the fifth H site, H(37) is bonded in a single-bond geometry to one C(25) atom. In the sixth H site, H(38) is bonded in a single-bond geometry to one C(25) atom. In the seventh H site, H(39) is bonded in a single-bond geometry to one C(27) atom. In the eighth H site, H(40) is bonded in a single-bond geometry to one C(28) atom. In the ninth H site, H(41) is bonded in a single-bond geometry to one C(30) atom. In the tenth H site, H(42) is bonded in a single-bond geometry to one C(31) atom. In the eleventh H site, H(43) is bonded in a single-bond geometry to one C(32) atom. In the twelfth H site, H(44) is bonded in a single-bond geometry to one C(32) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(8) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(8) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(9) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(9) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(11) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(12) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(14) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(15) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(16) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(16) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(17) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(17) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Cu(2), one C(1), and one C(32) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(8), and one C(9) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Cu(2), one C(16), and one C(17) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(24), and one C(25) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to one Cu(1) and one Cu(2) atom. In the second I site, I(2) is bonded in a 2-coordinate geometry to one Cu(1) and one Cu(2) atom. Linkers: 4 c1cc2ccc1CSC[C@H]1CC[C@@H](CC1)CSCc1ccc(cc1)CSC[C@H]1CC[C@@H](CC1)CSC2. Metal clusters: 4 [Cu][Cu](I)I. The MOF has largest included sphere 5.04 A, density 1.57 g/cm3, surface area 4026.46 m2/g, accessible volume 0.20 cm3/g