ZnC17H10O4C6H4SO2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two di-isopropenylsulfon molecules and one ZnC17H10O4 cluster. In the ZnC17H10O4 cluster, Zn(1) is bonded in a 5-coordinate geometry to one C(2), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-C(2) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.13 Å. The Zn(1)-O(3) bond length is 2.03 Å. The Zn(1)-O(4) bond length is 2.25 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(1), and one O(3) atom. The C(1)-C(8) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one Zn(1), one C(17), and one C(18) atom. The C(2)-C(17) bond length is 1.40 Å. The C(2)-C(18) bond length is 1.40 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(22), one C(23), and one C(4) atom. The C(3)-C(22) bond length is 1.42 Å. The C(3)-C(23) bond length is 1.42 Å. The C(3)-C(4) bond length is 1.46 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(6), and one C(7) atom. The C(4)-C(6) bond length is 1.42 Å. The C(4)-C(7) bond length is 1.42 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(8) and one H(1) atom. The C(5)-C(8) bond length is 1.40 Å. The C(5)-H(1) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(17), one C(4), and one H(2) atom. The C(6)-C(17) bond length is 1.39 Å. The C(6)-H(2) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(7)-H(3) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(1), one C(16), and one C(5) atom. The C(8)-C(16) bond length is 1.40 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(13) and one H(4) atom. The C(10)-C(13) bond length is 1.40 Å. The C(10)-H(4) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(20) atom. The C(13)-C(14) bond length is 1.50 Å. The C(13)-C(20) bond length is 1.40 Å. In the eleventh C site, C(14) is bonded in a bent 120 degrees geometry to one C(13), one O(2), and one O(4) atom. The C(14)-O(2) bond length is 1.28 Å. The C(14)-O(4) bond length is 1.27 Å. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(16)-H(7) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(8) atom. The C(17)-H(8) bond length is 1.09 Å. In the fourteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(2) and one H(9) atom. The C(18)-H(9) bond length is 1.09 Å. In the fifteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(20)-H(11) bond length is 1.09 Å. In the sixteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(3) and one H(13) atom. The C(22)-H(13) bond length is 1.09 Å. In the seventeenth C site, C(23) is bonded in a distorted single-bond geometry to one C(3) and one H(14) atom. The C(23)-H(14) bond length is 1.09 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(23) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(14) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Zn(1) and one C(14) atom. Linkers: 1 [c]1ccc(-c2ccc(-c3cc[c]cc3)cc2)cc1 ,2 [O]C(=O)c1ccc(S(=O)(=O)c2ccc(C([O])=O)cc2)cc1. Metal clusters: 1 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 4.66 A, density 1.47 g/cm3, surface area 4064.81 m2/g, accessible volume 0.21 cm3/g