(CH)4(CH2)3HgC12H14(SBr)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, six 02329_fluka molecules, and two HgC12H14(SBr)2 clusters. In each HgC12H14(SBr)2 cluster, Hg(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one Br(1), and one Br(2) atom. The Hg(1)-S(1) bond length is 2.66 Å. The Hg(1)-S(2) bond length is 2.67 Å. The Hg(1)-Br(1) bond length is 2.60 Å. The Hg(1)-Br(2) bond length is 2.58 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one H(1) atom. The C(1)-C(6) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(5) bond length is 1.09 Å. In the third C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.50 Å. In the fourth C site, C(7) is bonded in a distorted water-like geometry to one C(6), one H(6), one H(7), and one S(1) atom. The C(7)-H(6) bond length is 1.10 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-S(1) bond length is 1.84 Å. In the fifth C site, C(8) is bonded in a distorted water-like geometry to one H(8), one H(9), and one S(1) atom. The C(8)-H(8) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. The C(8)-S(1) bond length is 1.82 Å. In the sixth C site, C(12) is bonded in a distorted water-like geometry to one H(16), one H(17), and one S(2) atom. The C(12)-H(16) bond length is 1.10 Å. The C(12)-H(17) bond length is 1.10 Å. The C(12)-S(2) bond length is 1.82 Å. In the seventh C site, C(13) is bonded in a distorted water-like geometry to one C(14), one H(18), one H(19), and one S(2) atom. The C(13)-C(14) bond length is 1.50 Å. The C(13)-H(18) bond length is 1.10 Å. The C(13)-H(19) bond length is 1.10 Å. The C(13)-S(2) bond length is 1.82 Å. In the eighth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(19) bond length is 1.40 Å. In the ninth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(20) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(20) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(21) atom. The C(16)-H(21) bond length is 1.09 Å. In the eleventh C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(23) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(23) bond length is 1.09 Å. In the twelfth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one H(24) atom. The C(19)-H(24) bond length is 1.09 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(24) is bonded in a single-bond geometry to one C(19) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Hg(1), one C(7), and one C(8) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one Hg(1), one C(12), and one C(13) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Hg(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Hg(1) atom. Linkers: 2 [CH]CCCCSCc1ccccc1 ,2 c1ccc(CSCCCCCSCc2ccccc2)cc1 ,2 [CH]=[C]CSCCCCCSCc1ccccc1. Metal clusters: 2 [Hg]. The MOF has largest included sphere 2.11 A, density 2.15 g/cm3, surface area 3845.27 m2/g, accessible volume 0.14 cm3/g