CHZnC11N4H14O2Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and four ZnC11N4H14O2Cl clusters. In each ZnC11N4H14O2Cl cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one O(1), and one Cl(1) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-N(3) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 1.98 Å. The Zn(1)-Cl(1) bond length is 2.27 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(3) is bonded in a distorted water-like geometry to one C(9) and two equivalent H(2,3) atoms. The C(3)-C(9) bond length is 1.49 Å. Both C(3)-H(2,3) bond lengths are 1.10 Å. In the third C site, C(4) is bonded in a distorted water-like geometry to one C(5), one H(4), and one H(5) atom. The C(4)-C(5) bond length is 1.48 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one N(2) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-N(2) bond length is 1.36 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(1), and one H(6) atom. The C(6)-C(7) bond length is 1.37 Å. The C(6)-N(1) bond length is 1.38 Å. The C(6)-H(6) bond length is 1.08 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(2), and one H(7) atom. The C(7)-N(2) bond length is 1.39 Å. The C(7)-H(7) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a tetrahedral geometry to one N(2), one H(10), one H(8), and one H(9) atom. The C(8)-N(2) bond length is 1.46 Å. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(8) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(3), one N(3), and one N(4) atom. The C(9)-N(3) bond length is 1.35 Å. The C(9)-N(4) bond length is 1.36 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(3), and one H(11) atom. The C(10)-C(11) bond length is 1.37 Å. The C(10)-N(3) bond length is 1.38 Å. The C(10)-H(11) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(4), and one H(12) atom. The C(11)-N(4) bond length is 1.38 Å. The C(11)-H(12) bond length is 1.08 Å. In the eleventh C site, C(12) is bonded in a tetrahedral geometry to one N(4), one H(13), one H(14), and one H(15) atom. The C(12)-N(4) bond length is 1.46 Å. The C(12)-H(13) bond length is 1.10 Å. The C(12)-H(14) bond length is 1.09 Å. The C(12)-H(15) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(5), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(9) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. There are thirteen inequivalent H sites. In the first H site, H(2,3) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 4 Cn1ccnc1CC(Cc1nccn1C)C([O])=O. Metal clusters: 4 O=[C]O[Zn]Cl. The MOF has largest included sphere 2.16 A, density 1.65 g/cm3, surface area 4537.21 m2/g, accessible volume 0.13 cm3/g