Mo4Ag2C13N8H10O13(CH)2 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a Mo4Ag2C13N8H10O13 framework. In the Mo4Ag2C13N8H10O13 framework, there are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(2), one O(3), one O(4), and one O(8) atom. The Mo(1)-O(1) bond length is 1.72 Å. The Mo(1)-O(11) bond length is 1.97 Å. The Mo(1)-O(2) bond length is 2.44 Å. The Mo(1)-O(3) bond length is 1.72 Å. The Mo(1)-O(4) bond length is 1.91 Å. The Mo(1)-O(8) bond length is 2.34 Å. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(10), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. The Mo(2)-O(10) bond length is 2.19 Å. The Mo(2)-O(4) bond length is 1.93 Å. The Mo(2)-O(5) bond length is 1.72 Å. The Mo(2)-O(6) bond length is 1.76 Å. The Mo(2)-O(7) bond length is 1.91 Å. The Mo(2)-O(8) bond length is 2.49 Å. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(2), one O(9), and two equivalent O(8) atoms. The Mo(3)-O(10) bond length is 1.78 Å. The Mo(3)-O(11) bond length is 1.96 Å. The Mo(3)-O(2) bond length is 1.96 Å. The Mo(3)-O(9) bond length is 1.70 Å. There is one shorter (2.11 Å) and one longer (2.49 Å) Mo(3)-O(8) bond length. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(11), one O(12), one O(13), one O(2), one O(7), and one O(8) atom. The Mo(4)-O(11) bond length is 2.50 Å. The Mo(4)-O(12) bond length is 1.72 Å. The Mo(4)-O(13) bond length is 1.73 Å. The Mo(4)-O(2) bond length is 1.97 Å. The Mo(4)-O(7) bond length is 1.91 Å. The Mo(4)-O(8) bond length is 2.32 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one N(1), one O(12), one O(13), one O(3), and one O(6) atom. The Ag(1)-N(1) bond length is 2.18 Å. The Ag(1)-O(12) bond length is 2.66 Å. The Ag(1)-O(13) bond length is 2.65 Å. The Ag(1)-O(3) bond length is 2.69 Å. The Ag(1)-O(6) bond length is 2.18 Å. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one N(3), one N(7), one O(1), and one O(5) atom. The Ag(2)-N(3) bond length is 2.19 Å. The Ag(2)-N(7) bond length is 2.19 Å. The Ag(2)-O(1) bond length is 2.49 Å. The Ag(2)-O(5) bond length is 2.63 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(6) bond length is 1.46 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one N(3) atom. The C(6)-N(2) bond length is 1.36 Å. The C(6)-N(3) bond length is 1.35 Å. In the seventh C site, C(7) is bonded in a tetrahedral geometry to one N(4), one N(5), one H(5), and one H(6) atom. The C(7)-N(4) bond length is 1.46 Å. The C(7)-N(5) bond length is 1.45 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(5), one N(7), and one H(7) atom. The C(8)-N(5) bond length is 1.35 Å. The C(8)-N(7) bond length is 1.33 Å. The C(8)-H(7) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one N(6), one N(7), and one H(8) atom. The C(9)-N(6) bond length is 1.32 Å. The C(9)-N(7) bond length is 1.37 Å. The C(9)-H(8) bond length is 1.08 Å. In the tenth C site, C(10) is bonded in a distorted water-like geometry to one C(11), one N(2), and one N(4) atom. The C(10)-C(11) bond length is 1.47 Å. The C(10)-N(2) bond length is 1.34 Å. The C(10)-N(4) bond length is 1.37 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(8) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-N(8) bond length is 1.35 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(9) atom. The C(12)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one N(8) and one H(12) atom. The C(15)-N(8) bond length is 1.34 Å. The C(15)-H(12) bond length is 1.09 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a water-like geometry to one C(10) and one C(6) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(6), and one N(4) atom. The N(3)-N(4) bond length is 1.37 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(10), one C(7), and one N(3) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(7), one C(8), and one N(6) atom. The N(5)-N(6) bond length is 1.36 Å. In the sixth N site, N(6) is bonded in a distorted water-like geometry to one C(9) and one N(5) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(8), and one C(9) atom. In the eighth N site, N(8) is bonded in a bent 120 degrees geometry to one C(11) and one C(15) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Ag(2) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(3), and one Mo(4) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Mo(1) and one Ag(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Mo(2) and one Ag(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Mo(2) and one Ag(1) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(4) atom. In the eighth O site, O(8) is bonded to one Mo(1), one Mo(2), one Mo(4), and two equivalent Mo(3) atoms to form distorted edge-sharing OMo5 square pyramids. In the ninth O site, O(9) is bonded in a single-bond geometry to one Mo(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(3), and one Mo(4) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Mo(4) and one Ag(1) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Mo(4) and one Ag(1) atom. Linkers: 2 c1ccc(-c2nc(-c3cccnc3)nn2Cn2cncn2)nc1. Metal clusters: 4 [Ag] ,8 [Mo]. The MOF has largest included sphere 2.24 A, density 2.91 g/cm3, surface area 2259.50 m2/g, accessible volume 0.05 cm3/g