ZnC15NH11O4(CH)3(C5H4O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules; two 1,4-bis(methoxymethyl)benzene molecules; and one ZnC15NH11O4 cluster. In the ZnC15NH11O4 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(3), one O(4), and one O(5) atom. The Zn(1)-N(1) bond length is 2.06 Å. The Zn(1)-O(1) bond length is 2.07 Å. The Zn(1)-O(3) bond length is 2.07 Å. The Zn(1)-O(4) bond length is 2.06 Å. The Zn(1)-O(5) bond length is 2.07 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(3) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.41 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(3) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(3) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the sixth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(4), and one O(5) atom. The C(15)-C(16) bond length is 1.49 Å. The C(15)-O(4) bond length is 1.28 Å. The C(15)-O(5) bond length is 1.27 Å. In the seventh C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.41 Å. In the eighth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(17)-H(11) bond length is 1.09 Å. In the ninth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(14) atom. The C(21)-H(14) bond length is 1.09 Å. In the tenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(24), one N(1), and one H(17) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-N(1) bond length is 1.35 Å. The C(23)-H(17) bond length is 1.09 Å. In the eleventh C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(18) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-H(18) bond length is 1.09 Å. In the twelfth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(28) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(28) bond length is 1.51 Å. In the thirteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(25), one C(27), and one H(19) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-H(19) bond length is 1.09 Å. In the fourteenth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(26), one N(1), and one H(20) atom. The C(27)-N(1) bond length is 1.35 Å. The C(27)-H(20) bond length is 1.09 Å. In the fifteenth C site, C(28) is bonded in a distorted water-like geometry to one C(25), one H(21), and one H(22) atom. The C(28)-H(21) bond length is 1.10 Å. The C(28)-H(22) bond length is 1.10 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(23), and one C(27) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(26) atom. In the ninth H site, H(20) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(21) is bonded in a single-bond geometry to one C(28) atom. In the eleventh H site, H(22) is bonded in a single-bond geometry to one C(28) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(15) atom. In the fourth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(15) atom. Linkers: 2 [O]C(=O)c1ccc(OCc2ccc(COc3ccc(C([O])=O)cc3)cc2)cc1 ,1 c1cc(CCc2ccncc2)ccn1. Metal clusters: 1 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 2.30 A, density 1.52 g/cm3, surface area 4816.67 m2/g, accessible volume 0.16 cm3/g