Zn3C24H18(N3O7)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted tetrahedral geometry to one N(1), one O(11), one O(3), and one O(9) atom. The Zn(1)-N(1) bond length is 2.09 Å. The Zn(1)-O(11) bond length is 2.07 Å. The Zn(1)-O(3) bond length is 1.92 Å. The Zn(1)-O(9) bond length is 1.95 Å. In the second Zn site, Zn(2) is bonded in an octahedral geometry to one N(2), one N(4), one O(1), one O(14), one O(2), and one O(4) atom. The Zn(2)-N(2) bond length is 2.23 Å. The Zn(2)-N(4) bond length is 2.16 Å. The Zn(2)-O(1) bond length is 2.09 Å. The Zn(2)-O(14) bond length is 2.08 Å. The Zn(2)-O(2) bond length is 2.08 Å. The Zn(2)-O(4) bond length is 2.15 Å. In the third Zn site, Zn(3) is bonded in a 5-coordinate geometry to one N(5), one O(13), one O(5), one O(6), and one O(7) atom. The Zn(3)-N(5) bond length is 2.09 Å. The Zn(3)-O(13) bond length is 1.95 Å. The Zn(3)-O(5) bond length is 2.09 Å. The Zn(3)-O(6) bond length is 2.33 Å. The Zn(3)-O(7) bond length is 2.02 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(5) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-N(3) bond length is 1.36 Å. The C(1)-H(5) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(6) atom. The C(2)-N(2) bond length is 1.32 Å. The C(2)-N(3) bond length is 1.37 Å. The C(2)-H(6) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(7), and one H(8) atom. The C(3)-N(3) bond length is 1.46 Å. The C(3)-H(7) bond length is 1.09 Å. The C(3)-H(8) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(9) atom. The C(4)-N(4) bond length is 1.32 Å. The C(4)-N(6) bond length is 1.37 Å. The C(4)-H(9) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(10) atom. The C(5)-N(5) bond length is 1.32 Å. The C(5)-N(6) bond length is 1.36 Å. The C(5)-H(10) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(11), and one H(12) atom. The C(6)-N(6) bond length is 1.46 Å. The C(6)-H(11) bond length is 1.10 Å. The C(6)-H(12) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(8) atom. The C(7)-C(12) bond length is 1.40 Å. The C(7)-C(13) bond length is 1.50 Å. The C(7)-C(8) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(13) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(13) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.49 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(14) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(14) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(15) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(15) bond length is 1.50 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(7), and one H(15) atom. The C(12)-H(15) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(4) atom. The C(13)-O(3) bond length is 1.29 Å. The C(13)-O(4) bond length is 1.26 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(5), and one O(6) atom. The C(14)-O(5) bond length is 1.29 Å. The C(14)-O(6) bond length is 1.26 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(7), and one O(8) atom. The C(15)-O(7) bond length is 1.29 Å. The C(15)-O(8) bond length is 1.27 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(17), one C(21), and one C(22) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.40 Å. The C(16)-C(22) bond length is 1.49 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(16) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(16) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(23) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(23) bond length is 1.49 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(17) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(17) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(24) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(24) bond length is 1.50 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one H(18) atom. The C(21)-H(18) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(10), and one O(9) atom. The C(22)-O(10) bond length is 1.25 Å. The C(22)-O(9) bond length is 1.31 Å. In the twenty-third C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(11), and one O(12) atom. The C(23)-O(11) bond length is 1.31 Å. The C(23)-O(12) bond length is 1.25 Å. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(13), and one O(14) atom. The C(24)-O(13) bond length is 1.28 Å. The C(24)-O(14) bond length is 1.26 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.37 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(2), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(4), and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Zn(3), one C(5), and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(6) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(1) and one O(11) atom. The H(1)-O(1) bond length is 1.01 Å. The H(1)-O(11) bond length is 1.63 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(1) and one O(12) atom. The H(2)-O(1) bond length is 1.00 Å. The H(2)-O(12) bond length is 1.67 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. The H(3)-O(2) bond length is 1.00 Å. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(8) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(12) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(21) atom. There are fourteen inequivalent O sites. In the first O site, O(14) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(24) atom. In the second O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one H(1), and one H(2) atom. In the third O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one H(3), and one H(4) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the fifth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(13) atom. In the sixth O site, O(5) is bonded in an L-shaped geometry to one Zn(3) and one C(14) atom. In the seventh O site, O(6) is bonded in a distorted single-bond geometry to one Zn(3) and one C(14) atom. In the eighth O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(15) atom. In the ninth O site, O(8) is bonded in a distorted single-bond geometry to one C(15) atom. In the tenth O site, O(9) is bonded in a water-like geometry to one Zn(1) and one C(22) atom. In the eleventh O site, O(10) is bonded in a single-bond geometry to one C(22) atom. In the twelfth O site, O(11) is bonded in a trigonal non-coplanar geometry to one Zn(1), one C(23), and one H(1) atom. In the thirteenth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one C(23) and one H(2) atom. In the fourteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(24) atom. Linkers: 4 [O]C(=O)c1cc(C([O])=O)cc(C([O])=O)c1 ,2 c1nncn1CCn1cnnc1. Metal clusters: 1 O.O.O=[C]O[Zn]1(O[C]=O)[N][N][Zn@]2(=N[N][Zn](O[C]=O)(O[C]=O)O[C]O2)O[C]O1 ,1 O.O.O=[C]O[Zn]1(O[C]=O)[N][N][Zn@@]2(=N[N][Zn](O[C]=O)(O[C]=O)O[C]O2)O[C]O1. RCSR code: kgd. The MOF has largest included sphere 2.83 A, density 1.94 g/cm3, surface area 3587.79 m2/g, accessible volume 0.06 cm3/g