CdC8H10(N2O3)2(CH3)6(C2NH2O)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two n-methylformamide molecules, and one CdC8H10(N2O3)2 cluster. In the CdC8H10(N2O3)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(5), one N(6), one O(1), one O(2), one O(7), and one O(8) atom. The Cd(1)-N(5) bond length is 2.34 Å. The Cd(1)-N(6) bond length is 2.34 Å. The Cd(1)-O(1) bond length is 2.27 Å. The Cd(1)-O(2) bond length is 2.27 Å. The Cd(1)-O(7) bond length is 2.72 Å. The Cd(1)-O(8) bond length is 2.72 Å. There are six inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1,2)-O(1) bond length is 1.29 Å. The C(1,2)-O(3) bond length is 1.25 Å. In the second C site, C(9) is bonded in a distorted water-like geometry to one N(3) and one H(17,18) atom. The C(9)-N(3) bond length is 1.45 Å. The C(9)-H(17,18) bond length is 1.10 Å. In the third C site, C(10) is bonded in a distorted water-like geometry to one N(4) and one H(17,18) atom. The C(10)-N(4) bond length is 1.45 Å. The C(10)-H(17,18) bond length is 1.10 Å. In the fourth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(3) and one O(7) atom. The C(13)-N(3) bond length is 1.35 Å. The C(13)-O(7) bond length is 1.25 Å. In the fifth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(4) and one O(8) atom. The C(14)-N(4) bond length is 1.35 Å. The C(14)-O(8) bond length is 1.25 Å. In the sixth C site, C(15,16) is bonded in a 2-coordinate geometry to one N(5) and one H(25,26) atom. The C(15,16)-N(5) bond length is 1.46 Å. The C(15,16)-H(25,26) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one C(13), one C(9), and one H(3) atom. The N(3)-H(3) bond length is 1.03 Å. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(14), and one H(4) atom. The N(4)-H(4) bond length is 1.03 Å. In the third N site, N(5) is bonded in a 4-coordinate geometry to one Cd(1); one C(15,16); one H(5,6); and one H(7,8) atom. The N(5)-H(5,6) bond length is 1.03 Å. The N(5)-H(7,8) bond length is 1.03 Å. In the fourth N site, N(6) is bonded in a 4-coordinate geometry to one Cd(1); one C(15,16); one H(5,6); and one H(7,8) atom. The N(6)-C(15,16) bond length is 1.46 Å. The N(6)-H(5,6) bond length is 1.03 Å. The N(6)-H(7,8) bond length is 1.03 Å. There are six inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one N(5) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one N(5) atom. In the fifth H site, H(17,18) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(25,26) is bonded in a single-bond geometry to one C(15,16) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1) and one C(1,2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1) and one C(1,2) atom. The O(2)-C(1,2) bond length is 1.29 Å. In the third O site, O(3) is bonded in a single-bond geometry to one C(1,2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(1,2) atom. The O(4)-C(1,2) bond length is 1.25 Å. In the fifth O site, O(7) is bonded in a single-bond geometry to one Cd(1) and one C(13) atom. In the sixth O site, O(8) is bonded in a single-bond geometry to one Cd(1) and one C(14) atom. Linkers: 2 C[C@H](N)C(=O)N[C@@H](C)C(=O)N[C@@H](C)C([O])=O. Metal clusters: 1 [Cd]. The MOF has largest included sphere 2.37 A, density 1.57 g/cm3, surface area 4460.68 m2/g, accessible volume 0.17 cm3/g