AgC18H10(NO)3(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two AgC18H10(NO)3 clusters. In each AgC18H10(NO)3 cluster, Ag(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Ag(1)-N(1) bond length is 2.21 Å. The Ag(1)-N(2) bond length is 2.21 Å. The Ag(1)-O(1) bond length is 2.67 Å. The Ag(1)-O(2) bond length is 2.66 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(1) atom. The C(1)-C(3) bond length is 1.41 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one H(2) atom. The C(2)-C(4) bond length is 1.41 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(5) atom. The C(3)-C(11) bond length is 1.42 Å. The C(3)-C(5) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(2), and one C(6) atom. The C(4)-C(12) bond length is 1.42 Å. The C(4)-C(6) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(7) atom. The C(5)-H(7) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(8) atom. The C(6)-H(8) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5,6) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(5,6) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5,6) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(5,6) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a linear geometry to one C(13) and one C(3) atom. The C(11)-C(13) bond length is 1.22 Å. In the tenth C site, C(12) is bonded in a linear geometry to one C(14) and one C(4) atom. The C(12)-C(14) bond length is 1.22 Å. In the eleventh C site, C(13) is bonded in a linear geometry to one C(11) and one C(15,16) atom. The C(13)-C(15,16) bond length is 1.42 Å. In the twelfth C site, C(14) is bonded in a linear geometry to one C(12) and one C(15,16) atom. The C(14)-C(15,16) bond length is 1.42 Å. In the thirteenth C site, C(15,16) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(19) atom. The C(15,16)-C(17) bond length is 1.41 Å. The C(15,16)-C(19) bond length is 1.41 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(15,16) and one H(9,10) atom. The C(17)-H(9,10) bond length is 1.09 Å. In the fifteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(15,16) and one H(9,10) atom. The C(18)-C(15,16) bond length is 1.41 Å. The C(18)-H(9,10) bond length is 1.09 Å. In the sixteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(15,16) and one H(3,4) atom. The C(19)-H(3,4) bond length is 1.09 Å. In the seventeenth C site, C(20) is bonded in a distorted single-bond geometry to one C(15,16) and one H(3,4) atom. The C(20)-C(15,16) bond length is 1.41 Å. The C(20)-H(3,4) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(10), and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(3)-O(1) bond length is 1.28 Å. The N(3)-O(2) bond length is 1.28 Å. The N(3)-O(3) bond length is 1.26 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(17) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one N(3) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(3) atom. Linkers: 2 [N]/C=[C]/C#Cc1ccc(C#Cc2cccnc2)cc1 ,1 C(#Cc1cccnc1)c1ccc(C#Cc2cccnc2)cc1. Metal clusters: 2 [Ag].[O][N+](=O)[O-]. The MOF has largest included sphere 2.41 A, density 1.78 g/cm3, surface area 4158.09 m2/g, accessible volume 0.17 cm3/g