AgC12H13S2(NO)3CF3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two trifluoromethane molecules and one AgC12H13S2(NO)3 cluster. In the AgC12H13S2(NO)3 cluster, Ag(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one S(1), one O(1), and one O(2) atom. The Ag(1)-N(1) bond length is 2.19 Å. The Ag(1)-N(2) bond length is 2.15 Å. The Ag(1)-S(1) bond length is 2.95 Å. The Ag(1)-O(1) bond length is 2.69 Å. The Ag(1)-O(2) bond length is 2.62 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.50 Å. The C(5)-N(1) bond length is 1.35 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one C(5), one H(5), and one H(6) atom. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(7), and one H(8) atom. The C(7)-N(2) bond length is 1.46 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.10 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(2), and one H(9) atom. The C(8)-C(9) bond length is 1.44 Å. The C(8)-N(2) bond length is 1.29 Å. The C(8)-H(9) bond length is 1.10 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(8), and one S(1) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-S(1) bond length is 1.72 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(10) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-H(10) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(3) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-N(3) bond length is 1.34 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one H(11), one H(12), and one H(13) atom. The C(12)-H(11) bond length is 1.10 Å. The C(12)-H(12) bond length is 1.10 Å. The C(12)-H(13) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(7), and one C(8) atom. In the third N site, N(3) is bonded in a water-like geometry to one C(11) and one S(1) atom. The N(3)-S(1) bond length is 1.65 Å. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Ag(1), one C(9), and one N(3) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. The S(2)-O(1) bond length is 1.46 Å. The S(2)-O(2) bond length is 1.46 Å. The S(2)-O(3) bond length is 1.46 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ag(1) and one S(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one S(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(2) atom. Linkers: 2 Cc1cc(/C=N/CCc2ccccn2)sn1. Metal clusters: 1 [Ag].[Ag].[O]S([O])([O])C(F)(F)F.[O]S([O])([O])C(F)(F)F. The MOF has largest included sphere 1.82 A, density 1.97 g/cm3, surface area 3977.38 m2/g, accessible volume 0.12 cm3/g