Ti2Si3H36(C7O2)6(CH)4(CH3)4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, sixteen 02329_fluka molecules, and four Ti2Si3H36(C7O2)6 clusters. In each Ti2Si3H36(C7O2)6 cluster, Ti(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted TiO6 octahedra that share  a cornercorner with one Si(1)C2O2 tetrahedra and corners with two equivalent Si(2)C2O2 tetrahedra. The Ti(1)-O(1) bond length is 2.07 Å. The Ti(1)-O(2) bond length is 2.08 Å. The Ti(1)-O(3) bond length is 1.82 Å. The Ti(1)-O(4) bond length is 1.86 Å. The Ti(1)-O(5) bond length is 1.86 Å. The Ti(1)-O(6) bond length is 2.25 Å. There are two inequivalent Si sites. In the first Si site, Si(1) is bonded to two equivalent C(6) and two equivalent O(5) atoms to form SiC2O2 tetrahedra that share corners with two equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. Both Si(1)-C(6) bond lengths are 1.88 Å. Both Si(1)-O(5) bond lengths are 1.64 Å. In the second Si site, Si(2) is bonded to one C(12), one C(18), one O(3), and one O(4) atom to form SiC2O2 tetrahedra that share corners with two equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-35°. The Si(2)-C(12) bond length is 1.87 Å. The Si(2)-C(18) bond length is 1.87 Å. The Si(2)-O(3) bond length is 1.65 Å. The Si(2)-O(4) bond length is 1.63 Å. There are twenty-one inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(10) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(10) bond length is 1.09 Å. In the second C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(11) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(11) bond length is 1.09 Å. In the third C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one H(12) atom. The C(11)-C(6) bond length is 1.41 Å. The C(11)-H(12) bond length is 1.09 Å. In the fourth C site, C(12) is bonded in a trigonal planar geometry to one Si(2), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-C(17) bond length is 1.40 Å. In the fifth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(13) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-H(13) bond length is 1.09 Å. In the sixth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(14) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(14) bond length is 1.09 Å. In the seventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(15) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(15) bond length is 1.09 Å. In the eighth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(16) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(16) bond length is 1.09 Å. In the ninth C site, C(17) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one H(17) atom. The C(17)-H(17) bond length is 1.09 Å. In the tenth C site, C(18) is bonded in a trigonal planar geometry to one Si(2), one C(19), and one C(23) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-C(23) bond length is 1.41 Å. In the eleventh C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(18) atom. The C(19)-H(18) bond length is 1.09 Å. In the twelfth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(19) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(19) bond length is 1.09 Å. In the thirteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one H(20) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-H(20) bond length is 1.09 Å. In the fourteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(21) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(21) bond length is 1.09 Å. In the fifteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(18), one C(22), and one H(22) atom. The C(23)-H(22) bond length is 1.09 Å. In the sixteenth C site, C(24) is bonded in a distorted trigonal non-coplanar geometry to one H(23), one H(24), and one O(6) atom. The C(24)-H(23) bond length is 1.10 Å. The C(24)-H(24) bond length is 1.10 Å. The C(24)-O(6) bond length is 1.44 Å. In the seventeenth C site, C(25) is bonded in a distorted trigonal non-coplanar geometry to one H(25), one H(26), and one O(6) atom. The C(25)-H(25) bond length is 1.10 Å. The C(25)-H(26) bond length is 1.10 Å. The C(25)-O(6) bond length is 1.44 Å. In the eighteenth C site, C(6) is bonded in a trigonal planar geometry to one Si(1), one C(11), and one C(7) atom. The C(6)-C(7) bond length is 1.41 Å. In the nineteenth C site, C(1) is bonded in a distorted single-bond geometry to one O(1) atom. The C(1)-O(1) bond length is 1.28 Å. In the twentieth C site, C(3) is bonded in a distorted single-bond geometry to one O(2) atom. The C(3)-O(2) bond length is 1.28 Å. In the twenty-first C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(8) atom. The C(7)-H(8) bond length is 1.09 Å. There are eighteen inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(23) atom. In the fifteenth H site, H(23) is bonded in a single-bond geometry to one C(24) atom. In the sixteenth H site, H(24) is bonded in a single-bond geometry to one C(24) atom. In the seventeenth H site, H(25) is bonded in a single-bond geometry to one C(25) atom. In the eighteenth H site, H(26) is bonded in a single-bond geometry to one C(25) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ti(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ti(1) and one C(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Ti(1) and one Si(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Ti(1) and one Si(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Ti(1) and one Si(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Ti(1), one C(24), and one C(25) atom. Linkers: 2 C1COCCO1 ,4 CC(=O)[CH]C(C)=O. Metal clusters: 4 [Ti]. The MOF has largest included sphere 5.30 A, density 1.16 g/cm3, surface area 5342.47 m2/g, accessible volume 0.33 cm3/g