ZnC26H18(NO2)6CH2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and two ZnC26H18(NO2)6 clusters. In each ZnC26H18(NO2)6 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Zn(1)-N(1) bond lengths are 2.04 Å. Both Zn(1)-O(1) bond lengths are 2.01 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(5) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one H(2) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(3) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.51 Å. In the sixth C site, C(6) is bonded in a water-like geometry to one C(5), one H(5), and one H(6) atom. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(1), and one O(2) atom. The C(8)-C(9) bond length is 1.51 Å. The C(8)-O(1) bond length is 1.30 Å. The C(8)-O(2) bond length is 1.25 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.40 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(8) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(8) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(2) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(2) bond length is 1.47 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(9) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(9) bond length is 1.08 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one N(3) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-N(3) bond length is 1.47 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(9), and one H(10) atom. The C(14)-H(10) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one O(5), and one O(6) atom. The N(2)-O(5) bond length is 1.24 Å. The N(2)-O(6) bond length is 1.24 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(13), one O(3), and one O(4) atom. The N(3)-O(3) bond length is 1.24 Å. The N(3)-O(4) bond length is 1.24 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(8) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(2) atom. Linkers: 1 c1cc(CCCc2ccncc2)ccn1. Metal clusters: 1 [Zn]. The MOF has largest included sphere 1.77 A, density 1.73 g/cm3, surface area 4509.16 m2/g, accessible volume 0.09 cm3/g