Pd2C7H5O6(CH)2CH3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 02329_fluka molecules, and one Pd2C7H5O6 cluster. In the Pd2C7H5O6 cluster, there are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a rectangular see-saw-like geometry to one C(1), one C(2), one O(3), and one O(5) atom. The Pd(1)-C(1) bond length is 1.98 Å. The Pd(1)-C(2) bond length is 1.98 Å. The Pd(1)-O(3) bond length is 2.11 Å. The Pd(1)-O(5) bond length is 2.12 Å. In the second Pd site, Pd(2) is bonded in a rectangular see-saw-like geometry to one C(1), one C(2), one O(4), and one O(6) atom. The Pd(2)-C(1) bond length is 1.99 Å. The Pd(2)-C(2) bond length is 1.99 Å. The Pd(2)-O(4) bond length is 2.12 Å. The Pd(2)-O(6) bond length is 2.12 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one Pd(1), one Pd(2), and one O(1) atom. The C(1)-O(1) bond length is 1.17 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one Pd(1), one Pd(2), and one O(2) atom. The C(2)-O(2) bond length is 1.17 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(3)-C(4) bond length is 1.47 Å. The C(3)-O(3) bond length is 1.29 Å. The C(3)-O(4) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(1) atom. The C(4)-C(5) bond length is 1.34 Å. The C(4)-H(1) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(2) atom. The C(5)-C(6) bond length is 1.49 Å. The C(5)-H(2) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one H(3), one H(4), and one H(5) atom. The C(6)-H(3) bond length is 1.10 Å. The C(6)-H(4) bond length is 1.10 Å. The C(6)-H(5) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(7)-O(5) bond length is 1.29 Å. The C(7)-O(6) bond length is 1.28 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Pd(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Pd(2) and one C(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Pd(1) and one C(7) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Pd(2) and one C(7) atom. Linkers: 4 C/C=C/C([O])=O ,4 [C]=O. Metal clusters: 4 [Pd]. The MOF has largest included sphere 4.79 A, density 1.93 g/cm3, surface area 3322.87 m2/g, accessible volume 0.24 cm3/g