MnC24H24(N2Cl)2MnC16H16(N2Cl)2(CH2)4(CH)8 is Indium-derived structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, sixteen isobutylene molecules, eight MnC16H16(N2Cl)2 clusters, and eight MnC24H24(N2Cl)2 clusters. In each MnC16H16(N2Cl)2 cluster, Mn(2) is bonded in an octahedral geometry to two equivalent N(3), two equivalent N(4), and two equivalent Cl(2) atoms. Both Mn(2)-N(3) bond lengths are 2.27 Å. Both Mn(2)-N(4) bond lengths are 2.26 Å. Both Mn(2)-Cl(2) bond lengths are 2.52 Å. There are eight inequivalent C sites. In the first C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(26) atom. The C(24)-N(4) bond length is 1.35 Å. The C(24)-H(26) bond length is 1.09 Å. In the second C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(27) atom. The C(25)-N(4) bond length is 1.35 Å. The C(25)-H(27) bond length is 1.09 Å. In the third C site, C(14) is bonded in a distorted trigonal planar geometry to one C(15), one N(3), and one H(15) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-N(3) bond length is 1.34 Å. The C(14)-H(15) bond length is 1.09 Å. In the fourth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(16) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(16) bond length is 1.09 Å. In the fifth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(19) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(19) bond length is 1.50 Å. In the sixth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(17) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(17) bond length is 1.09 Å. In the seventh C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one N(3), and one H(18) atom. The C(18)-N(3) bond length is 1.35 Å. The C(18)-H(18) bond length is 1.09 Å. In the eighth C site, C(19) is bonded in a distorted water-like geometry to one C(16), one H(19), and one H(20) atom. The C(19)-H(19) bond length is 1.10 Å. The C(19)-H(20) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Mn(2), one C(14), and one C(18) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Mn(2), one C(24), and one C(25) atom. There are eight inequivalent H sites. In the first H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the second H site, H(16) is bonded in a single-bond geometry to one C(15) atom. In the third H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(26) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(27) is bonded in a single-bond geometry to one C(25) atom. Cl(2) is bonded in a single-bond geometry to one Mn(2) atom. In each MnC24H24(N2Cl)2 cluster, Mn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent Cl(1) atoms. Both Mn(1)-N(1) bond lengths are 2.25 Å. Both Mn(1)-N(2) bond lengths are 2.26 Å. Both Mn(1)-Cl(1) bond lengths are 2.51 Å. There are twelve inequivalent C sites. In the first C site, C(8) is bonded in a distorted water-like geometry to one C(9), one H(10), and one H(9) atom. The C(8)-C(9) bond length is 1.50 Å. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. In the second C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(13) bond length is 1.40 Å. In the third C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(11) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(11) bond length is 1.09 Å. In the fourth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(12) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(12) bond length is 1.09 Å. In the fifth C site, C(12) is bonded in a distorted trigonal planar geometry to one N(2) and one H(13) atom. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(13) bond length is 1.09 Å. In the sixth C site, C(13) is bonded in a distorted single-bond geometry to one C(9) and one H(14) atom. The C(13)-H(14) bond length is 1.09 Å. In the seventh C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the eighth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the ninth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.50 Å. In the tenth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the eleventh C site, C(6) is bonded in a distorted water-like geometry to one C(3), one H(5), and one H(6) atom. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the twelfth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(1), one C(11), and one C(12) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(12) atom. Cl(1) is bonded in a single-bond geometry to one Mn(1) atom. Linkers: 2 c1cc(CCCc2ccncc2)ccn1. Metal clusters: 2 [Mn]. The MOF has largest included sphere 7.41 A, density 1.10 g/cm3, surface area 5431.70 m2/g, accessible volume 0.32 cm3/g