CdC18H20(NO)4(CH2)2(CH)8 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two isobutylene molecules, one p-xylene molecule, and two CdC18H20(NO)4 clusters. In each CdC18H20(NO)4 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.31 Å. The Cd(1)-N(3) bond length is 2.35 Å. The Cd(1)-O(1) bond length is 2.32 Å. The Cd(1)-O(2) bond length is 2.48 Å. The Cd(1)-O(3) bond length is 2.25 Å. The Cd(1)-O(4) bond length is 2.68 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.50 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one N(2), one H(5), and one H(6) atom. The C(6)-N(2) bond length is 1.46 Å. The C(6)-H(5) bond length is 1.11 Å. The C(6)-H(6) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(7), and one H(8) atom. The C(7)-N(2) bond length is 1.46 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.11 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(10), and one H(9) atom. The C(8)-N(2) bond length is 1.46 Å. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.11 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(9)-O(1) bond length is 1.28 Å. The C(9)-O(2) bond length is 1.27 Å. In the tenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(15)-O(3) bond length is 1.29 Å. The C(15)-O(4) bond length is 1.26 Å. In the eleventh C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one N(3), and one H(23) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-N(3) bond length is 1.35 Å. The C(21)-H(23) bond length is 1.09 Å. In the twelfth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(24) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(24) bond length is 1.09 Å. In the thirteenth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(26) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(26) bond length is 1.51 Å. In the fourteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(25) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(25) bond length is 1.09 Å. In the fifteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one N(3), and one H(26) atom. The C(25)-N(3) bond length is 1.35 Å. The C(25)-H(26) bond length is 1.09 Å. In the sixteenth C site, C(26) is bonded in a distorted trigonal non-coplanar geometry to one C(23), one N(4), one H(27), and one H(28) atom. The C(26)-N(4) bond length is 1.46 Å. The C(26)-H(27) bond length is 1.10 Å. The C(26)-H(28) bond length is 1.11 Å. In the seventeenth C site, C(27) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(29), and one H(30) atom. The C(27)-N(4) bond length is 1.46 Å. The C(27)-H(29) bond length is 1.10 Å. The C(27)-H(30) bond length is 1.12 Å. In the eighteenth C site, C(28) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(31), and one H(32) atom. The C(28)-N(4) bond length is 1.46 Å. The C(28)-H(31) bond length is 1.11 Å. The C(28)-H(32) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(4) is bonded in a trigonal non-coplanar geometry to one C(26), one C(27), and one C(28) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the third N site, N(2) is bonded in a trigonal non-coplanar geometry to one C(6), one C(7), and one C(8) atom. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(21), and one C(25) atom. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(23) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(25) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(26) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(27) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(28) is bonded in a single-bond geometry to one C(26) atom. In the seventeenth H site, H(29) is bonded in a single-bond geometry to one C(27) atom. In the eighteenth H site, H(30) is bonded in a single-bond geometry to one C(27) atom. In the nineteenth H site, H(31) is bonded in a single-bond geometry to one C(28) atom. In the twentieth H site, H(32) is bonded in a single-bond geometry to one C(28) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(9) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(9) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cd(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cd(1) and one C(15) atom. Linkers: 2 c1cc(CN2CCN(Cc3ccncc3)CC2)ccn1 ,2 [O]C(=O)CCc1ccc(CCC([O])=O)cc1. Metal clusters: 2 O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 3.58 A, density 1.35 g/cm3, surface area 4923.46 m2/g, accessible volume 0.25 cm3/g