(C3H2)2CdC16P2H18S4(NO)2(CH3CO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 2,3-dimethyl-1,3-butadiene molecules; four dimethyl ether molecules; and two CdC16P2H18S4(NO)2 clusters. In each CdC16P2H18S4(NO)2 cluster, Cd(1) is bonded to two equivalent N(1), two equivalent S(1), and two equivalent S(2) atoms to form CdS4N2 octahedra that share edges with two equivalent P(1)CS2O tetrahedra. Both Cd(1)-N(1) bond lengths are 2.43 Å. Both Cd(1)-S(1) bond lengths are 2.71 Å. Both Cd(1)-S(2) bond lengths are 2.69 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded to one H(1), one H(2), one H(3), and one O(1) atom to form CH3O tetrahedra that share  a cornercorner with one P(1)CS2O tetrahedra. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.09 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-O(1) bond length is 1.44 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(3), one C(7), and one P(1) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(7) bond length is 1.40 Å. The C(2)-P(1) bond length is 1.80 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(4) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(4) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(4)-H(5) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(6) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(7) atom. The C(7)-H(7) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(11) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-H(11) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(14) atom. The C(13)-N(1) bond length is 1.34 Å. The C(13)-H(14) bond length is 1.09 Å. P(1) is bonded to one C(2), one S(1), one S(2), and one O(1) atom to form distorted PCS2O tetrahedra that share  a cornercorner with one C(1)H3O tetrahedra and  an edgeedge with one Cd(1)S4N2 octahedra. The P(1)-S(1) bond length is 2.00 Å. The P(1)-S(2) bond length is 2.02 Å. The P(1)-O(1) bond length is 1.62 Å. N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(9) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Cd(1) and one P(1) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Cd(1) and one P(1) atom. O(1) is bonded in a bent 120 degrees geometry to one C(1) and one P(1) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 1.83 A, density 1.69 g/cm3, surface area 4791.12 m2/g, accessible volume 0.08 cm3/g