CuC13NH6O4F(CO2)2 crystallizes in the triclinic P-1 space group. The structure consists of eight carbon dioxide molecules inside a CuC13NH6O4F framework. In the CuC13NH6O4F framework, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(3), one O(6), and one O(8) atom. The Cu(1)-N(1) bond length is 2.18 Å. The Cu(1)-O(1) bond length is 1.99 Å. The Cu(1)-O(3) bond length is 2.00 Å. The Cu(1)-O(6) bond length is 1.99 Å. The Cu(1)-O(8) bond length is 2.00 Å. In the second Cu site, Cu(2) is bonded in a distorted square pyramidal geometry to one N(2), one O(2), one O(4), one O(5), and one O(7) atom. The Cu(2)-N(2) bond length is 2.19 Å. The Cu(2)-O(2) bond length is 2.00 Å. The Cu(2)-O(4) bond length is 2.00 Å. The Cu(2)-O(5) bond length is 1.99 Å. The Cu(2)-O(7) bond length is 2.00 Å. There are twenty-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(4) atom. The C(2)-C(4) bond length is 1.49 Å. The C(2)-O(2) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.28 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(7), and one C(9) atom. The C(3)-C(7) bond length is 1.40 Å. The C(3)-C(9) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(8) atom. The C(4)-C(10) bond length is 1.40 Å. The C(4)-C(8) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(7) atom. The C(5)-C(11) bond length is 1.40 Å. The C(5)-C(15) bond length is 1.49 Å. The C(5)-C(7) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(8) atom. The C(6)-C(12) bond length is 1.40 Å. The C(6)-C(16) bond length is 1.50 Å. The C(6)-C(8) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(1) atom. The C(7)-H(1) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(2) atom. The C(8)-H(2) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(13), one C(3), and one H(3) atom. The C(9)-C(13) bond length is 1.40 Å. The C(9)-H(3) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(14), one C(4), and one H(4) atom. The C(10)-C(14) bond length is 1.40 Å. The C(10)-H(4) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(13); one C(5); and one H(5,6) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-H(5,6) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(14); one C(6); and one H(5,6) atom. The C(12)-C(14) bond length is 1.40 Å. The C(12)-H(5,6) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(17), and one C(9) atom. The C(13)-C(17) bond length is 1.48 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(18) atom. The C(14)-C(18) bond length is 1.48 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(5), and one O(7) atom. The C(15)-O(5) bond length is 1.27 Å. The C(15)-O(7) bond length is 1.28 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(6), and one O(8) atom. The C(16)-O(6) bond length is 1.27 Å. The C(16)-O(8) bond length is 1.28 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(13); one C(19,20); and one C(21) atom. The C(17)-C(19,20) bond length is 1.40 Å. The C(17)-C(21) bond length is 1.40 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(14); one C(19,20); and one C(22) atom. The C(18)-C(19,20) bond length is 1.40 Å. The C(18)-C(22) bond length is 1.40 Å. In the nineteenth C site, C(19,20) is bonded in a distorted single-bond geometry to one C(17) and one H(7,8) atom. The C(19,20)-H(7,8) bond length is 1.09 Å. In the twentieth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(17), one N(1), and one H(9) atom. The C(21)-N(1) bond length is 1.34 Å. The C(21)-H(9) bond length is 1.09 Å. In the twenty-first C site, C(22) is bonded in a distorted trigonal planar geometry to one C(18), one N(2), and one H(10) atom. The C(22)-N(2) bond length is 1.34 Å. The C(22)-H(10) bond length is 1.09 Å. In the twenty-second C site, C(23) is bonded in a distorted single-bond geometry to one C(25) and one F(1,2) atom. The C(23)-C(25) bond length is 1.39 Å. The C(23)-F(1,2) bond length is 1.36 Å. In the twenty-third C site, C(24) is bonded in a distorted single-bond geometry to one C(26) and one F(1,2) atom. The C(24)-C(26) bond length is 1.39 Å. The C(24)-F(1,2) bond length is 1.36 Å. In the twenty-fourth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(23), one N(1), and one H(11) atom. The C(25)-N(1) bond length is 1.34 Å. The C(25)-H(11) bond length is 1.09 Å. In the twenty-fifth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(24), one N(2), and one H(12) atom. The C(26)-N(2) bond length is 1.34 Å. The C(26)-H(12) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(21), and one C(25) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(22), and one C(26) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(19,20) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(26) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(15) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(16) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(15) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(16) atom. F(1,2) is bonded in a single-bond geometry to one C(23) atom. Linkers: 4 [O]C(=O)c1cc(C([O])=O)cc(-c2cncc(F)c2)c1. Metal clusters: 2 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 2.63 A, density 1.67 g/cm3, surface area 4578.38 m2/g, accessible volume 0.14 cm3/g