CoC18H14(NO)4(CH)4 is Indium-derived structured and crystallizes in the tetragonal P42_12 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four CoC18H14(NO)4 clusters. In each CoC18H14(NO)4 cluster, Co(1) is bonded in a distorted octahedral geometry to two equivalent N(2), two equivalent O(1), and two equivalent O(2) atoms. Both Co(1)-N(2) bond lengths are 2.08 Å. Both Co(1)-O(1) bond lengths are 2.25 Å. Both Co(1)-O(2) bond lengths are 2.10 Å. There are nine inequivalent C sites. In the first C site, C(8) is bonded in a 3-coordinate geometry to one C(11), one N(1), and one H(5) atom. The C(8)-C(11) bond length is 1.37 Å. The C(8)-N(1) bond length is 1.39 Å. The C(8)-H(5) bond length is 1.08 Å. In the second C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one N(2) atom. The C(9)-C(10) bond length is 1.48 Å. The C(9)-N(1) bond length is 1.37 Å. The C(9)-N(2) bond length is 1.34 Å. In the third C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(6), one H(7), and one H(8) atom. The C(10)-H(6) bond length is 1.09 Å. The C(10)-H(7) bond length is 1.10 Å. The C(10)-H(8) bond length is 1.10 Å. In the fourth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(2), and one H(9) atom. The C(11)-N(2) bond length is 1.38 Å. The C(11)-H(9) bond length is 1.08 Å. In the fifth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.29 Å. In the sixth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.40 Å. In the seventh C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the eighth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(4)-H(2) bond length is 1.09 Å. In the ninth C site, C(7) is bonded in a distorted single-bond geometry to one N(1) atom. The C(7)-N(1) bond length is 1.43 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(7), one C(8), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(11), and one C(9) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Co(1) and one C(1) atom. Linkers: 8 Cc1nccn1-c1ccc(C([O])=O)cc1. Metal clusters: 4 [C]1O[Co]2(O1)O[C]O2. The MOF has largest included sphere 6.08 A, density 1.15 g/cm3, surface area 4774.21 m2/g, accessible volume 0.31 cm3/g