CdC20H22(N2I)2(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CdC20H22(N2I)2 clusters. In each CdC20H22(N2I)2 cluster, Cd(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(3), one I(1), and one I(2) atom. The Cd(1)-N(1) bond length is 2.27 Å. The Cd(1)-N(3) bond length is 2.29 Å. The Cd(1)-I(1) bond length is 2.76 Å. The Cd(1)-I(2) bond length is 2.76 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one N(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(7) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-N(1) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(20), one C(4), and one C(6) atom. The C(5)-C(20) bond length is 1.51 Å. The C(5)-C(6) bond length is 1.43 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(19), one C(5), and one C(7) atom. The C(6)-C(19) bond length is 1.50 Å. The C(6)-C(7) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(3) atom. The C(7)-H(3) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(4), and one H(5) atom. The C(8)-N(2) bond length is 1.46 Å. The C(8)-H(4) bond length is 1.10 Å. The C(8)-H(5) bond length is 1.10 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(6) atom. The C(9)-N(3) bond length is 1.33 Å. The C(9)-N(4) bond length is 1.36 Å. The C(9)-H(6) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(15), and one N(4) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-C(15) bond length is 1.40 Å. The C(10)-N(4) bond length is 1.39 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(3) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-N(3) bond length is 1.39 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(7) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(7) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(21) atom. The C(13)-C(14) bond length is 1.43 Å. The C(13)-C(21) bond length is 1.50 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(16) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(16) bond length is 1.50 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one H(8) atom. The C(15)-H(8) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one C(14), one H(10), one H(11), and one H(9) atom. The C(16)-H(10) bond length is 1.10 Å. The C(16)-H(11) bond length is 1.10 Å. The C(16)-H(9) bond length is 1.10 Å. In the seventeenth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(14), and one H(15) atom. The C(18)-N(4) bond length is 1.46 Å. The C(18)-H(14) bond length is 1.10 Å. The C(18)-H(15) bond length is 1.10 Å. In the eighteenth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one H(16), one H(17), and one H(18) atom. The C(19)-H(16) bond length is 1.10 Å. The C(19)-H(17) bond length is 1.10 Å. The C(19)-H(18) bond length is 1.10 Å. In the nineteenth C site, C(20) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one H(19), one H(20), and one H(21) atom. The C(20)-H(19) bond length is 1.10 Å. The C(20)-H(20) bond length is 1.10 Å. The C(20)-H(21) bond length is 1.10 Å. In the twentieth C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one C(13), one H(22), one H(23), and one H(24) atom. The C(21)-H(22) bond length is 1.10 Å. The C(21)-H(23) bond length is 1.10 Å. The C(21)-H(24) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(8) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one C(9) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(18), and one C(9) atom. There are twenty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(20) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(21) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(21) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(21) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Cd(1) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Cd(1) atom. Linkers: 2 [C][CH]c1c([CH])ncn1CCCCn1cnc2cc(C)c(C)cc21 ,2 Cc1cc2ncn(CCCCn3cnc4cc(C)c(C)cc43)c2cc1C ,2 [CH2]c1[c]cc2ncn(CCCCn3cnc4cc(C)c(C)cc43)c2c1. Metal clusters: 2 I[Cd]I. The MOF has largest included sphere 2.89 A, density 1.90 g/cm3, surface area 3929.47 m2/g, accessible volume 0.17 cm3/g