AgC5H10(SO)2CH2(CF2)2CF3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, four difluoromethane molecules, two trifluoromethane molecules, and one AgC5H10(SO)2 cluster. In the AgC5H10(SO)2 cluster, Ag(1) is bonded in a 4-coordinate geometry to one S(2), two equivalent S(1), and one O(1) atom. The Ag(1)-S(2) bond length is 2.46 Å. There is one shorter (2.49 Å) and one longer (2.93 Å) Ag(1)-S(1) bond length. The Ag(1)-O(1) bond length is 2.42 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(5) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(1) atom. The C(5)-H(1) bond length is 1.10 Å. The C(5)-H(2) bond length is 1.10 Å. The C(5)-H(3) bond length is 1.10 Å. The C(5)-S(1) bond length is 1.81 Å. In the third C site, C(6) is bonded in a distorted water-like geometry to one H(4), one H(5), and one S(1) atom. The C(6)-H(4) bond length is 1.10 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-S(1) bond length is 1.82 Å. In the fourth C site, C(8) is bonded in a distorted water-like geometry to one H(8), one H(9), and one S(2) atom. The C(8)-H(8) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. The C(8)-S(2) bond length is 1.82 Å. In the fifth C site, C(9) is bonded in a trigonal non-coplanar geometry to one H(10), one H(11), one H(12), and one S(2) atom. The C(9)-H(10) bond length is 1.10 Å. The C(9)-H(11) bond length is 1.10 Å. The C(9)-H(12) bond length is 1.09 Å. The C(9)-S(2) bond length is 1.81 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Ag(1), one C(5), and one C(6) atom to form distorted edge-sharing SAg2C2 tetrahedra. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(8), and one C(9) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Linkers: 2 CSCCCSC. Metal clusters: 2 [Ag]. The MOF has largest included sphere 2.32 A, density 2.09 g/cm3, surface area 3841.44 m2/g, accessible volume 0.12 cm3/g