FeC10H8(N3S)2(CH)8C9H8O4 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules; two 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and two FeC10H8(N3S)2 clusters. In each FeC10H8(N3S)2 cluster, Fe(1) is bonded in an octahedral geometry to one N(1), one N(11), one N(3), one N(5), one N(7), and one N(9) atom. The Fe(1)-N(1) bond length is 2.32 Å. The Fe(1)-N(11) bond length is 2.01 Å. The Fe(1)-N(3) bond length is 2.01 Å. The Fe(1)-N(5) bond length is 1.90 Å. The Fe(1)-N(7) bond length is 1.91 Å. The Fe(1)-N(9) bond length is 2.23 Å. There are ten inequivalent C sites. In the first C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(11)-N(1) bond length is 1.33 Å. The C(11)-H(9) bond length is 1.09 Å. In the second C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(11) atom. The C(13)-N(3) bond length is 1.35 Å. The C(13)-H(11) bond length is 1.09 Å. In the third C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(17) atom. The C(19)-N(9) bond length is 1.34 Å. The C(19)-H(17) bond length is 1.09 Å. In the fourth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(19) atom. The C(21)-N(11) bond length is 1.36 Å. The C(21)-H(19) bond length is 1.08 Å. In the fifth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(25) atom. The C(31)-N(1) bond length is 1.35 Å. The C(31)-H(25) bond length is 1.09 Å. In the sixth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(27) atom. The C(33)-N(3) bond length is 1.36 Å. The C(33)-H(27) bond length is 1.09 Å. In the seventh C site, C(35) is bonded in a single-bond geometry to one N(5) and one S(1) atom. The C(35)-N(5) bond length is 1.19 Å. The C(35)-S(1) bond length is 1.62 Å. In the eighth C site, C(37) is bonded in a single-bond geometry to one N(7) and one S(3) atom. The C(37)-N(7) bond length is 1.19 Å. The C(37)-S(3) bond length is 1.62 Å. In the ninth C site, C(47) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(41) atom. The C(47)-N(9) bond length is 1.34 Å. The C(47)-H(41) bond length is 1.09 Å. In the tenth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(43) atom. The C(49)-N(11) bond length is 1.35 Å. The C(49)-H(43) bond length is 1.08 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Fe(1), one C(11), and one C(31) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Fe(1), one C(13), and one C(33) atom. In the third N site, N(5) is bonded in a linear geometry to one Fe(1) and one C(35) atom. In the fourth N site, N(7) is bonded in a linear geometry to one Fe(1) and one C(37) atom. In the fifth N site, N(9) is bonded in a trigonal planar geometry to one Fe(1), one C(19), and one C(47) atom. In the sixth N site, N(11) is bonded in a trigonal planar geometry to one Fe(1), one C(21), and one C(49) atom. There are eight inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(21) atom. In the fifth H site, H(25) is bonded in a single-bond geometry to one C(31) atom. In the sixth H site, H(27) is bonded in a single-bond geometry to one C(33) atom. In the seventh H site, H(41) is bonded in a single-bond geometry to one C(47) atom. In the eighth H site, H(43) is bonded in a single-bond geometry to one C(49) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one C(35) atom. In the second S site, S(3) is bonded in a single-bond geometry to one C(37) atom. Linkers: 4 [CH]/C(=C\[N])OCC(COc1cccnc1)(COc1cccnc1)COc1cccnc1 ,4 [CH]=[C]OCC(COc1cc[c]nc1)(COc1cccnc1)COc1cccnc1 ,2 c1cncc(OCC(COc2cccnc2)(COc2cccnc2)COc2cccnc2)c1 ,2 [CH]/C(=C\[N])OCC(CO/C([CH])=C/[N])(COc1cccnc1)COc1cccnc1. Metal clusters: 2 [Fe]. The MOF has largest included sphere 3.72 A, density 1.28 g/cm3, surface area 4652.39 m2/g, accessible volume 0.30 cm3/g