ZnC33H27(NO2)2(CH3)2C3NH5O crystallizes in the triclinic P-1 space group. The structure consists of eight 02329_fluka molecules and four n,n-dimethylformamide molecules inside a ZnC33H27(NO2)2 framework. In the ZnC33H27(NO2)2 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to one N(1), one O(1), one O(4), one O(5), and one O(8) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 2.20 Å. The Zn(1)-O(4) bond length is 2.12 Å. The Zn(1)-O(5) bond length is 2.03 Å. The Zn(1)-O(8) bond length is 2.04 Å. In the second Zn site, Zn(2) is bonded in a 5-coordinate geometry to one N(2), one O(2), one O(3), one O(6), and one O(7) atom. The Zn(2)-N(2) bond length is 2.01 Å. The Zn(2)-O(2) bond length is 2.20 Å. The Zn(2)-O(3) bond length is 2.12 Å. The Zn(2)-O(6) bond length is 2.03 Å. The Zn(2)-O(7) bond length is 2.04 Å. There are fifty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(3) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(4) atom. The C(2)-C(4) bond length is 1.49 Å. The C(2)-O(2) bond length is 1.26 Å. The C(2)-O(4) bond length is 1.28 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1); one C(13,14); and one C(5,6) atom. The C(3)-C(13,14) bond length is 1.40 Å. The C(3)-C(5,6) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(13,14); one C(2); and one C(5,6) atom. The C(4)-C(13,14) bond length is 1.40 Å. The C(4)-C(5,6) bond length is 1.40 Å. In the fifth C site, C(5,6) is bonded in a distorted single-bond geometry to one C(3) and one H(1,2) atom. The C(5,6)-H(1,2) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(9,10) and one H(3,4) atom. The C(7)-C(9,10) bond length is 1.40 Å. The C(7)-H(3,4) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(9,10) and one H(3,4) atom. The C(8)-C(9,10) bond length is 1.40 Å. The C(8)-H(3,4) bond length is 1.09 Å. In the eighth C site, C(9,10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(7) atom. The C(9,10)-C(11) bond length is 1.40 Å. The C(9,10)-C(15) bond length is 1.49 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(13,14); one C(9,10); and one H(5,6) atom. The C(11)-C(13,14) bond length is 1.39 Å. The C(11)-H(5,6) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13,14); one C(9,10); and one H(5,6) atom. The C(12)-C(13,14) bond length is 1.39 Å. The C(12)-C(9,10) bond length is 1.40 Å. The C(12)-H(5,6) bond length is 1.09 Å. In the eleventh C site, C(13,14) is bonded in a distorted single-bond geometry to one C(11), one C(3), and one H(7) atom. The C(13,14)-H(7) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a trigonal planar geometry to one C(17,18); one C(19,20); and one C(9,10) atom. The C(15)-C(17,18) bond length is 1.41 Å. The C(15)-C(19,20) bond length is 1.41 Å. In the thirteenth C site, C(16) is bonded in a trigonal planar geometry to one C(17,18); one C(19,20); and one C(9,10) atom. The C(16)-C(17,18) bond length is 1.41 Å. The C(16)-C(19,20) bond length is 1.41 Å. The C(16)-C(9,10) bond length is 1.49 Å. In the fourteenth C site, C(17,18) is bonded in a trigonal planar geometry to one C(15); one C(19,20); and one C(21,22) atom. The C(17,18)-C(19,20) bond length is 1.41 Å. The C(17,18)-C(21,22) bond length is 1.51 Å. In the fifteenth C site, C(19,20) is bonded in a trigonal planar geometry to one C(15); one C(17,18); and one C(23,24) atom. The C(19,20)-C(23,24) bond length is 1.51 Å. In the sixteenth C site, C(21,22) is bonded in a distorted trigonal non-coplanar geometry to one C(17,18); one H(11,12); one H(13,14); and one H(9,10) atom. The C(21,22)-H(11,12) bond length is 1.10 Å. The C(21,22)-H(13,14) bond length is 1.10 Å. The C(21,22)-H(9,10) bond length is 1.10 Å. In the seventeenth C site, C(23,24) is bonded in a distorted trigonal non-coplanar geometry to one C(19,20); one H(15,16); one H(17,18); and one H(19,20) atom. The C(23,24)-H(15,16) bond length is 1.09 Å. The C(23,24)-H(17,18) bond length is 1.10 Å. The C(23,24)-H(19,20) bond length is 1.10 Å. In the eighteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(5), and one O(6) atom. The C(25)-C(26) bond length is 1.49 Å. The C(25)-O(5) bond length is 1.28 Å. The C(25)-O(6) bond length is 1.28 Å. In the nineteenth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(28) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-C(28) bond length is 1.40 Å. In the twentieth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(21,22) atom. The C(27)-H(21,22) bond length is 1.09 Å. In the twenty-first C site, C(28) is bonded in a distorted single-bond geometry to one C(26) and one H(21,22) atom. The C(28)-H(21,22) bond length is 1.09 Å. In the twenty-second C site, C(29) is bonded in a distorted single-bond geometry to one C(31) and one H(23,24) atom. The C(29)-C(31) bond length is 1.40 Å. The C(29)-H(23,24) bond length is 1.09 Å. In the twenty-third C site, C(30) is bonded in a distorted single-bond geometry to one C(31) and one H(23,24) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-H(23,24) bond length is 1.09 Å. In the twenty-fourth C site, C(31) is bonded in a trigonal planar geometry to one C(29), one C(30), and one C(32) atom. The C(31)-C(32) bond length is 1.49 Å. In the twenty-fifth C site, C(32) is bonded in a trigonal planar geometry to one C(31) and two equivalent C(33,34) atoms. Both C(32)-C(33,34) bond lengths are 1.41 Å. In the twenty-sixth C site, C(33,34) is bonded in a trigonal planar geometry to one C(32); one C(35,36); and one C(38,39) atom. The C(33,34)-C(35,36) bond length is 1.41 Å. The C(33,34)-C(38,39) bond length is 1.51 Å. In the twenty-seventh C site, C(35,36) is bonded in a trigonal planar geometry to one C(33,34); one C(37); and one C(40,41) atom. The C(35,36)-C(37) bond length is 1.41 Å. The C(35,36)-C(40,41) bond length is 1.51 Å. In the twenty-eighth C site, C(37) is bonded in a trigonal planar geometry to one C(42) and two equivalent C(35,36) atoms. The C(37)-C(42) bond length is 1.49 Å. In the twenty-ninth C site, C(38,39) is bonded in a distorted trigonal non-coplanar geometry to one C(33,34); one H(25,26); one H(27,28); and one H(29,30) atom. The C(38,39)-H(25,26) bond length is 1.10 Å. The C(38,39)-H(27,28) bond length is 1.09 Å. The C(38,39)-H(29,30) bond length is 1.10 Å. In the thirtieth C site, C(40,41) is bonded in a distorted trigonal non-coplanar geometry to one C(35,36); one H(31,32); one H(33,34); and one H(35,36) atom. The C(40,41)-H(31,32) bond length is 1.10 Å. The C(40,41)-H(33,34) bond length is 1.10 Å. The C(40,41)-H(35,36) bond length is 1.10 Å. In the thirty-first C site, C(42) is bonded in a trigonal planar geometry to one C(37) and two equivalent C(43,44) atoms. Both C(42)-C(43,44) bond lengths are 1.40 Å. In the thirty-second C site, C(43,44) is bonded in a distorted single-bond geometry to one C(42); one C(45,46); and one H(37,38) atom. The C(43,44)-C(45,46) bond length is 1.39 Å. The C(43,44)-H(37,38) bond length is 1.09 Å. In the thirty-third C site, C(45,46) is bonded in a distorted trigonal planar geometry to one C(43,44); one C(47); and one H(39,40) atom. The C(45,46)-C(47) bond length is 1.40 Å. The C(45,46)-H(39,40) bond length is 1.09 Å. In the thirty-fourth C site, C(47) is bonded in a trigonal planar geometry to one C(48) and two equivalent C(45,46) atoms. The C(47)-C(48) bond length is 1.50 Å. In the thirty-fifth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(47), one O(7), and one O(8) atom. The C(48)-O(7) bond length is 1.27 Å. The C(48)-O(8) bond length is 1.27 Å. In the thirty-sixth C site, C(49) is bonded in a trigonal planar geometry to one N(1); one N(3); and one H(41,42) atom. The C(49)-N(1) bond length is 1.32 Å. The C(49)-N(3) bond length is 1.36 Å. The C(49)-H(41,42) bond length is 1.08 Å. In the thirty-seventh C site, C(50) is bonded in a trigonal planar geometry to one N(2); one N(4); and one H(41,42) atom. The C(50)-N(2) bond length is 1.32 Å. The C(50)-N(4) bond length is 1.36 Å. The C(50)-H(41,42) bond length is 1.08 Å. In the thirty-eighth C site, C(51) is bonded in a distorted trigonal planar geometry to one C(53,54); one N(3); and one H(43,44) atom. The C(51)-C(53,54) bond length is 1.37 Å. The C(51)-N(3) bond length is 1.39 Å. The C(51)-H(43,44) bond length is 1.08 Å. In the thirty-ninth C site, C(52) is bonded in a distorted trigonal planar geometry to one C(53,54); one N(4); and one H(43,44) atom. The C(52)-C(53,54) bond length is 1.37 Å. The C(52)-N(4) bond length is 1.39 Å. The C(52)-H(43,44) bond length is 1.08 Å. In the fortieth C site, C(53,54) is bonded in a distorted bent 120 degrees geometry to one C(51), one N(1), and one H(45) atom. The C(53,54)-N(1) bond length is 1.38 Å. The C(53,54)-H(45) bond length is 1.08 Å. In the forty-first C site, C(55) is bonded in a distorted trigonal planar geometry to one C(57), one C(65), and one N(3) atom. The C(55)-C(57) bond length is 1.40 Å. The C(55)-C(65) bond length is 1.40 Å. The C(55)-N(3) bond length is 1.42 Å. In the forty-second C site, C(56) is bonded in a distorted trigonal planar geometry to one C(58), one C(66), and one N(4) atom. The C(56)-C(58) bond length is 1.40 Å. The C(56)-C(66) bond length is 1.40 Å. The C(56)-N(4) bond length is 1.42 Å. In the forty-third C site, C(57) is bonded in a distorted single-bond geometry to one C(55) and one H(47,48) atom. The C(57)-H(47,48) bond length is 1.09 Å. In the forty-fourth C site, C(58) is bonded in a distorted single-bond geometry to one C(56) and one H(47,48) atom. The C(58)-H(47,48) bond length is 1.09 Å. In the forty-fifth C site, C(59,60) is bonded in a distorted single-bond geometry to one C(61) and one H(49,50) atom. The C(59,60)-C(61) bond length is 1.41 Å. The C(59,60)-H(49,50) bond length is 1.09 Å. In the forty-sixth C site, C(61) is bonded in a trigonal planar geometry to one C(59,60); one C(61); and one C(63,64) atom. The C(61)-C(61) bond length is 1.48 Å. The C(61)-C(63,64) bond length is 1.41 Å. In the forty-seventh C site, C(62) is bonded in a trigonal planar geometry to one C(59,60); one C(62); and one C(63,64) atom. The C(62)-C(59,60) bond length is 1.41 Å. The C(62)-C(62) bond length is 1.48 Å. The C(62)-C(63,64) bond length is 1.41 Å. In the forty-eighth C site, C(63,64) is bonded in a distorted trigonal planar geometry to one C(61), one C(65), and one H(51) atom. The C(63,64)-C(65) bond length is 1.39 Å. The C(63,64)-H(51) bond length is 1.09 Å. In the forty-ninth C site, C(65) is bonded in a distorted single-bond geometry to one C(55); one C(63,64); and one H(53,54) atom. The C(65)-H(53,54) bond length is 1.09 Å. In the fiftieth C site, C(66) is bonded in a distorted single-bond geometry to one C(56); one C(63,64); and one H(53,54) atom. The C(66)-C(63,64) bond length is 1.39 Å. The C(66)-H(53,54) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1); one C(49); and one C(53,54) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2); one C(50); and one C(53,54) atom. The N(2)-C(53,54) bond length is 1.38 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(49), one C(51), and one C(55) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(50), one C(52), and one C(56) atom. There are thirty inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(5,6) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(13,14) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(13,14) atom. The H(8)-C(13,14) bond length is 1.09 Å. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(21,22) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(21,22) atom. In the eighth H site, H(13,14) is bonded in a single-bond geometry to one C(21,22) atom. In the ninth H site, H(15,16) is bonded in a single-bond geometry to one C(23,24) atom. In the tenth H site, H(17,18) is bonded in a single-bond geometry to one C(23,24) atom. In the eleventh H site, H(19,20) is bonded in a single-bond geometry to one C(23,24) atom. In the twelfth H site, H(21,22) is bonded in a single-bond geometry to one C(27) atom. In the thirteenth H site, H(23,24) is bonded in a single-bond geometry to one C(29) atom. In the fourteenth H site, H(25,26) is bonded in a single-bond geometry to one C(38,39) atom. In the fifteenth H site, H(27,28) is bonded in a single-bond geometry to one C(38,39) atom. In the sixteenth H site, H(29,30) is bonded in a single-bond geometry to one C(38,39) atom. In the seventeenth H site, H(31,32) is bonded in a single-bond geometry to one C(40,41) atom. In the eighteenth H site, H(33,34) is bonded in a single-bond geometry to one C(40,41) atom. In the nineteenth H site, H(35,36) is bonded in a single-bond geometry to one C(40,41) atom. In the twentieth H site, H(37,38) is bonded in a single-bond geometry to one C(43,44) atom. In the twenty-first H site, H(39,40) is bonded in a single-bond geometry to one C(45,46) atom. In the twenty-second H site, H(41,42) is bonded in a single-bond geometry to one C(49) atom. In the twenty-third H site, H(43,44) is bonded in a single-bond geometry to one C(51) atom. In the twenty-fourth H site, H(45) is bonded in a single-bond geometry to one C(53,54) atom. In the twenty-fifth H site, H(46) is bonded in a single-bond geometry to one C(53,54) atom. The H(46)-C(53,54) bond length is 1.08 Å. In the twenty-sixth H site, H(47,48) is bonded in a single-bond geometry to one C(57) atom. In the twenty-seventh H site, H(49,50) is bonded in a single-bond geometry to one C(59,60) atom. In the twenty-eighth H site, H(51) is bonded in a single-bond geometry to one C(63,64) atom. In the twenty-ninth H site, H(52) is bonded in a single-bond geometry to one C(63,64) atom. The H(52)-C(63,64) bond length is 1.09 Å. In the thirtieth H site, H(53,54) is bonded in a single-bond geometry to one C(65) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(2) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zn(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(25) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(48) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(48) atom. Linkers: 2 c1cn(-c2ccc(-c3ccc(-n4ccnc4)cc3)cc2)cn1 ,4 Cc1c(C)c(-c2ccc(C([O])=O)cc2)c(C)c(C)c1-c1ccc(C([O])=O)cc1. Metal clusters: 2 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: sql. The MOF has largest included sphere 2.71 A, density 1.33 g/cm3, surface area 5441.05 m2/g, accessible volume 0.24 cm3/g