ZnC8N3H6O5(CH)2(CH2)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, twelve 02329_fluka molecules, and one ZnC8N3H6O5 cluster. In the ZnC8N3H6O5 cluster, Zn(1) is bonded in a distorted pentagonal planar geometry to one N(1), one N(2), one O(1), one O(2), and one O(5) atom. The Zn(1)-N(1) bond length is 2.18 Å. The Zn(1)-N(2) bond length is 2.11 Å. The Zn(1)-O(1) bond length is 2.22 Å. The Zn(1)-O(2) bond length is 1.99 Å. The Zn(1)-O(5) bond length is 1.97 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.46 Å. The C(5)-N(1) bond length is 1.36 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(2), and one H(5) atom. The C(6)-N(2) bond length is 1.29 Å. The C(6)-H(5) bond length is 1.10 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(3), and one O(1) atom. The C(7)-C(8) bond length is 1.50 Å. The C(7)-N(3) bond length is 1.38 Å. The C(7)-O(1) bond length is 1.25 Å. In the sixth C site, C(8) is bonded in a distorted water-like geometry to one C(7), one H(6), and one H(7) atom. The C(8)-H(6) bond length is 1.11 Å. The C(8)-H(7) bond length is 1.10 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(10)-O(2) bond length is 1.29 Å. The C(10)-O(3) bond length is 1.27 Å. In the eighth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(16)-O(4) bond length is 1.26 Å. The C(16)-O(5) bond length is 1.30 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(6), and one N(3) atom. The N(2)-N(3) bond length is 1.34 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one C(7), one N(2), and one H(10) atom. The N(3)-H(10) bond length is 1.07 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(10) is bonded in a distorted bent 150 degrees geometry to one N(3) and one O(3) atom. The H(10)-O(3) bond length is 1.59 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(10) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one C(10) and one H(10) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(16) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(16) atom. Linkers: 1 O=C(CCCCC(=O)N/N=C/c1ccccn1)N/N=C/c1ccccn1 ,2 [N]NC(=O)CCCCC(=O)N/N=C/c1ccccn1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.41 A, density 1.55 g/cm3, surface area 4737.24 m2/g, accessible volume 0.15 cm3/g