NiC13N2H11O5(CH)4C4H3H2O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two isobutylene molecules, two isobutylene molecules, two water molecules, and one NiC13N2H11O5 cluster. In the NiC13N2H11O5 cluster, Ni(1) is bonded in a square co-planar geometry to one N(1), one N(2), one O(1), and one O(5) atom. The Ni(1)-N(1) bond length is 1.89 Å. The Ni(1)-N(2) bond length is 1.91 Å. The Ni(1)-O(1) bond length is 1.94 Å. The Ni(1)-O(5) bond length is 1.98 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(8) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(8) bond length is 1.09 Å. In the third C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-C(9) bond length is 1.51 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(9) atom. The C(7)-H(9) bond length is 1.09 Å. In the fifth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(3), and one O(4) atom. The C(9)-O(3) bond length is 1.27 Å. The C(9)-O(4) bond length is 1.28 Å. In the sixth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(11) atom. The C(10)-N(1) bond length is 1.35 Å. The C(10)-H(11) bond length is 1.09 Å. In the seventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(14) atom. The C(14)-N(1) bond length is 1.35 Å. The C(14)-H(14) bond length is 1.09 Å. In the eighth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(16) atom. The C(16)-C(17) bond length is 1.45 Å. The C(16)-H(16) bond length is 1.09 Å. In the ninth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(21) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-C(21) bond length is 1.41 Å. In the tenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(17) atom. The C(18)-C(19) bond length is 1.38 Å. The C(18)-H(17) bond length is 1.09 Å. In the eleventh C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(2), and one H(18) atom. The C(19)-N(2) bond length is 1.36 Å. The C(19)-H(18) bond length is 1.09 Å. In the twelfth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(21), one N(2), and one H(19) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-N(2) bond length is 1.35 Å. The C(20)-H(19) bond length is 1.09 Å. In the thirteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(17), one C(20), and one H(20) atom. The C(21)-H(20) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(10), and one C(14) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ni(1), one C(19), and one C(20) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(4) and one O(5) atom. The H(1)-O(4) bond length is 1.57 Å. The H(1)-O(5) bond length is 1.03 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(2) and one O(5) atom. The H(2)-O(2) bond length is 1.66 Å. The H(2)-O(5) bond length is 1.01 Å. In the third H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(21) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ni(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one C(1) and one H(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one C(9) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(9) and one H(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Ni(1), one H(1), and one H(2) atom. Linkers: 2 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 2 [Ni]. The MOF has largest included sphere 2.58 A, density 1.58 g/cm3, surface area 4757.85 m2/g, accessible volume 0.14 cm3/g