TiC8H4(NO2)2(CH)14(C3H2)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules; four 2,3-dimethyl-1,3-butadiene molecules; four propylene molecules; and two TiC8H4(NO2)2 clusters. In each TiC8H4(NO2)2 cluster, Ti(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. Both Ti(1)-N(1) bond lengths are 2.21 Å. Both Ti(1)-O(1) bond lengths are 1.90 Å. Both Ti(1)-O(2) bond lengths are 1.92 Å. There are four inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one O(2) atom. The C(4)-O(2) bond length is 1.34 Å. In the second C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(7)-N(1) bond length is 1.35 Å. The C(7)-H(5) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted single-bond geometry to one O(1) atom. The C(1)-O(1) bond length is 1.34 Å. In the fourth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(12) atom. The C(17)-N(1) bond length is 1.35 Å. The C(17)-H(12) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Ti(1), one C(17), and one C(7) atom. There are two inequivalent H sites. In the first H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 150 degrees geometry to one Ti(1) and one C(4) atom. In the second O site, O(1) is bonded in a bent 150 degrees geometry to one Ti(1) and one C(1) atom. Linkers: 4 [O]c1ccc([O])cc1. Metal clusters: 2 [O][Ti]([O])([O])=O. RCSR code: sql. The MOF has largest included sphere 2.04 A, density 1.42 g/cm3, surface area 5168.44 m2/g, accessible volume 0.12 cm3/g