MnH4(C5O2)2(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a MnH4(C5O2)2 framework. In the MnH4(C5O2)2 framework, Mn(1) is bonded to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms to form edge-sharing MnO6 octahedra. The Mn(1)-O(2) bond length is 2.09 Å. The Mn(1)-O(3) bond length is 2.09 Å. There is one shorter (2.20 Å) and one longer (2.25 Å) Mn(1)-O(1) bond length. There is one shorter (2.18 Å) and one longer (2.27 Å) Mn(1)-O(4) bond length. There are ten inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(1) bond length is 1.49 Å. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.43 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the third C site, C(11) is bonded in a distorted single-bond geometry to one C(7) and one H(2,6) atom. The C(11)-C(7) bond length is 1.42 Å. The C(11)-H(2,6) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2,6) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2,6) bond length is 1.09 Å. In the fifth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(3), and one O(4) atom. The C(12)-C(5) bond length is 1.49 Å. The C(12)-O(3) bond length is 1.27 Å. The C(12)-O(4) bond length is 1.29 Å. In the sixth C site, C(5) is bonded in a trigonal planar geometry to one C(12), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.43 Å. In the seventh C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. The C(6)-C(7) bond length is 1.44 Å. The C(6)-C(8) bond length is 1.42 Å. In the eighth C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(2), and one C(6) atom. In the ninth C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(8)-H(3) bond length is 1.09 Å. In the tenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.27 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2,6) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Mn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(12) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Mn(1) and one C(12) atom. Linkers: 4 [O][C]c1ccc(C([O])=O)c2ccccc12 ,4 [O]C(=O)c1ccc(C([O])=O)c2ccccc12. Metal clusters: 4 [Mn]. The MOF has largest included sphere 2.34 A, density 1.84 g/cm3, surface area 3341.60 m2/g, accessible volume 0.11 cm3/g