CuC14H18(N3S)2(CH2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CuC14H18(N3S)2 clusters. In each CuC14H18(N3S)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(3) atoms. Both Cu(1)-N(1) bond lengths are 1.99 Å. Both Cu(1)-N(3) bond lengths are 1.95 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(3) and one S(1) atom. The C(1)-N(3) bond length is 1.19 Å. The C(1)-S(1) bond length is 1.61 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3), one C(4), and one N(2) atom. The C(2)-C(3) bond length is 1.49 Å. The C(2)-C(4) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.36 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one H(1), one H(2), and one H(3) atom. The C(3)-H(1) bond length is 1.10 Å. The C(3)-H(2) bond length is 1.10 Å. The C(3)-H(3) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(4) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.49 Å. The C(5)-N(1) bond length is 1.35 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one H(5), one H(6), and one H(7) atom. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. The C(6)-H(7) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(8), and one H(9) atom. The C(7)-N(2) bond length is 1.46 Å. The C(7)-H(8) bond length is 1.10 Å. The C(7)-H(9) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(5), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(2), one C(7), and one N(1) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one Cu(1) and one C(1) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. Linkers: 1 Cc1cc(C)n(CCCCn2nc(C)cc2C)n1. Metal clusters: 1 [Cu]. The MOF has largest included sphere 1.66 A, density 1.51 g/cm3, surface area 5407.76 m2/g, accessible volume 0.15 cm3/g