CdC12N3H10O4(CH)9(CH2CO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, four dimethyl ether molecules, two propylene molecules, and two CdC12N3H10O4 clusters. In each CdC12N3H10O4 cluster, Cd(1) is bonded in a distorted pentagonal bipyramidal geometry to one N(1), one N(2), one N(3), one O(1), one O(2), one O(4), and one O(5) atom. The Cd(1)-N(1) bond length is 2.43 Å. The Cd(1)-N(2) bond length is 2.36 Å. The Cd(1)-N(3) bond length is 2.42 Å. The Cd(1)-O(1) bond length is 2.44 Å. The Cd(1)-O(2) bond length is 2.52 Å. The Cd(1)-O(4) bond length is 2.34 Å. The Cd(1)-O(5) bond length is 2.66 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(6)-O(4) bond length is 1.28 Å. The C(6)-O(5) bond length is 1.26 Å. In the third C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(1), and one H(9) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(9) bond length is 1.09 Å. In the fourth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(10) atom. The C(12)-H(10) bond length is 1.09 Å. In the fifth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(15)-N(1) bond length is 1.34 Å. The C(15)-H(13) bond length is 1.09 Å. In the sixth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(14) atom. The C(16)-N(2) bond length is 1.35 Å. The C(16)-H(14) bond length is 1.09 Å. In the seventh C site, C(20) is bonded in a distorted trigonal planar geometry to one N(2) and one H(18) atom. The C(20)-N(2) bond length is 1.34 Å. The C(20)-H(18) bond length is 1.09 Å. In the eighth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one N(3), and one H(19) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-N(3) bond length is 1.34 Å. The C(21)-H(19) bond length is 1.09 Å. In the ninth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one H(20) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(20) bond length is 1.09 Å. In the tenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22), one C(24), and one H(21) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-H(21) bond length is 1.09 Å. In the eleventh C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one C(25), and one H(22) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(22) bond length is 1.09 Å. In the twelfth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one N(3), and one H(23) atom. The C(25)-N(3) bond length is 1.35 Å. The C(25)-H(23) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(15) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(16), and one C(20) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(21), and one C(25) atom. There are ten inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one C(20) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(21) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(22) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(23) is bonded in a single-bond geometry to one C(25) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the third O site, O(4) is bonded in a distorted water-like geometry to one Cd(1) and one C(6) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one Cd(1) and one C(6) atom. Linkers: 2 [O]C(=O)COc1ccc(OCC([O])=O)cc1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 3.31 A, density 1.56 g/cm3, surface area 4700.49 m2/g, accessible volume 0.13 cm3/g