MnC32H44(NO2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one MnC32H44(NO2)2 cluster. Mn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. Both Mn(1)-N(1) bond lengths are 2.39 Å. Both Mn(1)-O(1) bond lengths are 1.88 Å. Both Mn(1)-O(2) bond lengths are 1.89 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one O(1) atom. The C(1)-C(6) bond length is 1.41 Å. The C(1)-O(1) bond length is 1.34 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one O(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-O(2) bond length is 1.34 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(7) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(7) bond length is 1.53 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(1) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(1) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(2) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(2) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(5) atom. The C(6)-C(10) bond length is 1.53 Å. In the seventh C site, C(7) is bonded in a tetrahedral geometry to one C(3), one C(8), and two equivalent C(9) atoms. The C(7)-C(8) bond length is 1.53 Å. Both C(7)-C(9) bond lengths are 1.54 Å. In the eighth C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(7), one H(3), and two equivalent H(4) atoms. The C(8)-H(3) bond length is 1.10 Å. Both C(8)-H(4) bond lengths are 1.10 Å. In the ninth C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(7); one H(5); one H(6,11); and one H(7) atom. The C(9)-H(5) bond length is 1.10 Å. The C(9)-H(6,11) bond length is 1.10 Å. The C(9)-H(7) bond length is 1.10 Å. In the tenth C site, C(10) is bonded in a tetrahedral geometry to one C(11), one C(6), and two equivalent C(12) atoms. The C(10)-C(11) bond length is 1.53 Å. Both C(10)-C(12) bond lengths are 1.54 Å. In the eleventh C site, C(11) is bonded in a trigonal non-coplanar geometry to one C(10), one H(8), and two equivalent H(9) atoms. The C(11)-H(8) bond length is 1.10 Å. Both C(11)-H(9) bond lengths are 1.10 Å. In the twelfth C site, C(12) is bonded in a trigonal non-coplanar geometry to one C(10), one H(10), one H(11), and one H(12) atom. The C(12)-H(10) bond length is 1.10 Å. The C(12)-H(11) bond length is 1.10 Å. The C(12)-H(12) bond length is 1.10 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(13)-N(1) bond length is 1.34 Å. The C(13)-H(13) bond length is 1.09 Å. In the fourteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(13)-N(1) bond length is 1.34 Å. The C(13)-H(13) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Mn(1) and two C(13,13) atoms. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6,11) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(2) atom. Linkers: 2 CC(C)(C)c1ccc(C(C)(C)C)c([O])c1[O]. Metal clusters: 1 [Mn]. The MOF has largest included sphere 5.28 A, density 0.98 g/cm3, surface area 5996.20 m2/g, accessible volume 0.43 cm3/g