(CH)2CdC8N6H7OCl crystallizes in the triclinic P-1 space group. The structure consists of eight 02329_fluka molecules inside a CdC8N6H7OCl framework. In the CdC8N6H7OCl framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one N(1), one N(12), one N(3), one O(1), and two equivalent Cl(1) atoms to form edge-sharing CdN3Cl2O octahedra. The Cd(1)-N(1) bond length is 2.39 Å. The Cd(1)-N(12) bond length is 2.29 Å. The Cd(1)-N(3) bond length is 2.27 Å. The Cd(1)-O(1) bond length is 2.48 Å. There is one shorter (2.55 Å) and one longer (2.84 Å) Cd(1)-Cl(1) bond length. In the second Cd site, Cd(2) is bonded to one N(11), one N(2), one N(4), one O(2), and two equivalent Cl(2) atoms to form edge-sharing CdN3Cl2O octahedra. The Cd(2)-N(11) bond length is 2.29 Å. The Cd(2)-N(2) bond length is 2.39 Å. The Cd(2)-N(4) bond length is 2.27 Å. The Cd(2)-O(2) bond length is 2.48 Å. There is one shorter (2.54 Å) and one longer (2.85 Å) Cd(2)-Cl(2) bond length. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2) atom. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(7) is bonded in a distorted single-bond geometry to one C(9) and one H(7) atom. The C(7)-C(9) bond length is 1.40 Å. The C(7)-H(7) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-H(8) bond length is 1.09 Å. In the fifth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(11), one C(7), and one N(1) atom. The C(9)-C(11) bond length is 1.46 Å. The C(9)-N(1) bond length is 1.36 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one N(2) atom. The C(10)-C(12) bond length is 1.46 Å. The C(10)-N(2) bond length is 1.36 Å. In the seventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(9), one N(3), and one N(7) atom. The C(11)-N(3) bond length is 1.35 Å. The C(11)-N(7) bond length is 1.35 Å. In the eighth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(10), one N(4), and one N(8) atom. The C(12)-N(4) bond length is 1.35 Å. The C(12)-N(8) bond length is 1.35 Å. In the ninth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(15), one N(5), and one N(7) atom. The C(13)-C(15) bond length is 1.45 Å. The C(13)-N(5) bond length is 1.36 Å. The C(13)-N(7) bond length is 1.36 Å. In the tenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(16), one N(6), and one N(8) atom. The C(14)-C(16) bond length is 1.45 Å. The C(14)-N(6) bond length is 1.36 Å. The C(14)-N(8) bond length is 1.36 Å. In the eleventh C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(19) atom. The C(15)-C(17) bond length is 1.41 Å. The C(15)-C(19) bond length is 1.40 Å. In the twelfth C site, C(16) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(20) atom. The C(16)-C(18) bond length is 1.41 Å. The C(16)-C(20) bond length is 1.40 Å. In the thirteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(15); one N(11); and one H(9,10) atom. The C(17)-N(11) bond length is 1.34 Å. The C(17)-H(9,10) bond length is 1.08 Å. In the fourteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(16); one N(12); and one H(9,10) atom. The C(18)-N(12) bond length is 1.34 Å. The C(18)-H(9,10) bond length is 1.08 Å. In the fifteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(9), and one H(11) atom. The C(19)-N(9) bond length is 1.35 Å. The C(19)-H(11) bond length is 1.08 Å. In the sixteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(10), and one H(12) atom. The C(20)-N(10) bond length is 1.35 Å. The C(20)-H(12) bond length is 1.08 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(2), one C(10), and one C(2) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one N(5) atom. The N(3)-N(5) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(12), and one N(6) atom. The N(4)-N(6) bond length is 1.35 Å. In the fifth N site, N(5) is bonded in a distorted single-bond geometry to one C(13) and one N(3) atom. In the sixth N site, N(6) is bonded in a distorted single-bond geometry to one C(14) and one N(4) atom. In the seventh N site, N(7) is bonded in a water-like geometry to one C(11) and one C(13) atom. In the eighth N site, N(8) is bonded in a water-like geometry to one C(12) and one C(14) atom. In the ninth N site, N(9) is bonded in a 2-coordinate geometry to one C(19), one N(11), and one H(13) atom. The N(9)-N(11) bond length is 1.35 Å. The N(9)-H(13) bond length is 1.05 Å. In the tenth N site, N(10) is bonded in a 2-coordinate geometry to one C(20), one N(12), and one H(14) atom. The N(10)-N(12) bond length is 1.35 Å. The N(10)-H(14) bond length is 1.05 Å. In the eleventh N site, N(11) is bonded in a 3-coordinate geometry to one Cd(2), one C(17), and one N(9) atom. In the twelfth N site, N(12) is bonded in a 3-coordinate geometry to one Cd(1), one C(18), and one N(10) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one N(9) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one N(10) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one O(1) and one Cl(2) atom. The H(15)-O(1) bond length is 0.99 Å. The H(15)-Cl(2) bond length is 2.11 Å. In the eleventh H site, H(16) is bonded in a single-bond geometry to one O(2) and one Cl(1) atom. The H(16)-O(2) bond length is 0.99 Å. The H(16)-Cl(1) bond length is 2.12 Å. In the twelfth H site, H(17) is bonded in a single-bond geometry to one O(1) atom. The H(17)-O(1) bond length is 0.97 Å. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one O(2) atom. The H(18)-O(2) bond length is 0.97 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1), one H(15), and one H(17) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(2), one H(16), and one H(18) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one H(16) atom. In the second Cl site, Cl(2) is bonded in a 3-coordinate geometry to two equivalent Cd(2) and one H(15) atom. Linkers: 3 c1ccc(C2=NN=C(c3cn[nH]c3)[N]2)nc1 ,1 c1ccc(C2=N[N]C(c3cn[nH]c3)=N2)nc1. Metal clusters: 2 Cl[Cd].Cl[Cd].O.O. The MOF has largest included sphere 2.08 A, density 1.87 g/cm3, surface area 3979.46 m2/g, accessible volume 0.11 cm3/g