GdZnC23N2H13O11Cl(CH)3 crystallizes in the triclinic P-1 space group. The structure consists of six 02329_fluka molecules inside a GdZnC23N2H13O11Cl framework. In the GdZnC23N2H13O11Cl framework, Gd(1) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(3), one O(6), one O(8), two equivalent O(2), and two equivalent O(7) atoms. The Gd(1)-O(1) bond length is 2.50 Å. The Gd(1)-O(11) bond length is 2.38 Å. The Gd(1)-O(3) bond length is 2.43 Å. The Gd(1)-O(6) bond length is 2.48 Å. The Gd(1)-O(8) bond length is 2.40 Å. There is one shorter (2.44 Å) and one longer (2.48 Å) Gd(1)-O(2) bond length. There is one shorter (2.35 Å) and one longer (2.58 Å) Gd(1)-O(7) bond length. Zn(1) is bonded in a tetrahedral geometry to one N(2), one O(4), one O(9), and one Cl(1) atom. The Zn(1)-N(2) bond length is 2.04 Å. The Zn(1)-O(4) bond length is 1.99 Å. The Zn(1)-O(9) bond length is 2.00 Å. The Zn(1)-Cl(1) bond length is 2.22 Å. There are twenty-three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.49 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(8) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(8) bond length is 1.51 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one O(5) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-O(5) bond length is 1.38 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.26 Å. The C(7)-O(2) bond length is 1.31 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.27 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(6) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-N(1) bond length is 1.34 Å. The C(9)-H(6) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one O(5) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-O(5) bond length is 1.39 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(7) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(7) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(13)-N(1) bond length is 1.34 Å. The C(13)-H(9) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(20) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-C(19) bond length is 1.40 Å. The C(14)-C(20) bond length is 1.49 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(21) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(21) bond length is 1.51 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one O(10) atom. The C(16)-O(10) bond length is 1.40 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(12) atom. The C(19)-H(12) bond length is 1.09 Å. In the eighteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(6), and one O(7) atom. The C(20)-O(6) bond length is 1.26 Å. The C(20)-O(7) bond length is 1.29 Å. In the nineteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(8), and one O(9) atom. The C(21)-O(8) bond length is 1.26 Å. The C(21)-O(9) bond length is 1.28 Å. In the twentieth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(23), one N(2), and one H(13) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-N(2) bond length is 1.34 Å. The C(22)-H(13) bond length is 1.09 Å. In the twenty-first C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one O(10) atom. The C(23)-O(10) bond length is 1.38 Å. In the twenty-second C site, C(25) is bonded in a distorted single-bond geometry to one C(26) and one H(15) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-H(15) bond length is 1.09 Å. In the twenty-third C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one N(2), and one H(16) atom. The C(26)-N(2) bond length is 1.35 Å. The C(26)-H(16) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one H(2) atom. The N(1)-H(2) bond length is 1.69 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(22), and one C(26) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(11) atom. The H(1)-O(11) bond length is 0.99 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one N(1) and one O(11) atom. The H(2)-O(11) bond length is 1.02 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(26) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Gd(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Gd(1) and one C(7) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Gd(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(10) and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Gd(1) and one C(20) atom. In the seventh O site, O(7) is bonded in a 1-coordinate geometry to two equivalent Gd(1) and one C(20) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Gd(1) and one C(21) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(21) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one C(16) and one C(23) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Gd(1), one H(1), and one H(2) atom. Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 4 [O]C(=O)c1cccc(Oc2cccnc2)c1C([O])=O. Metal clusters: 2 [Gd] ,2 [Zn]. The MOF has largest included sphere 2.69 A, density 2.02 g/cm3, surface area 3252.03 m2/g, accessible volume 0.11 cm3/g