ZnC24H22(NO)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC24H22(NO)4 clusters. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(7), one O(2), and one O(6) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-N(7) bond length is 1.99 Å. The Zn(1)-O(2) bond length is 1.95 Å. The Zn(1)-O(6) bond length is 1.96 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one N(2), one N(8), one O(3), and one O(4) atom. The Zn(2)-N(2) bond length is 2.01 Å. The Zn(2)-N(8) bond length is 1.99 Å. The Zn(2)-O(3) bond length is 1.95 Å. The Zn(2)-O(4) bond length is 1.96 Å. In the third Zn site, Zn(3) is bonded in a tetrahedral geometry to one N(3), one N(9), one O(1), and one O(5) atom. The Zn(3)-N(3) bond length is 2.01 Å. The Zn(3)-N(9) bond length is 1.99 Å. The Zn(3)-O(1) bond length is 1.95 Å. The Zn(3)-O(5) bond length is 1.96 Å. There are forty-nine inequivalent C sites. In the first C site, C(1,2) is bonded in a trigonal planar geometry to one C(10); one C(37,38,39); and one C(4,5,6) atom. The C(1,2)-C(10) bond length is 1.41 Å. The C(1,2)-C(37,38,39) bond length is 1.46 Å. The C(1,2)-C(4,5,6) bond length is 1.42 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(12); one C(37,38,39); and one C(4,5,6) atom. The C(3)-C(12) bond length is 1.41 Å. The C(3)-C(37,38,39) bond length is 1.46 Å. The C(3)-C(4,5,6) bond length is 1.42 Å. In the third C site, C(4,5,6) is bonded in a distorted single-bond geometry to one C(1,2); one C(49,50); and one N(1) atom. The C(4,5,6)-C(49,50) bond length is 1.49 Å. The C(4,5,6)-N(1) bond length is 1.35 Å. In the fourth C site, C(7) is bonded in a trigonal planar geometry to one C(22), one C(28), and one C(40) atom. The C(7)-C(22) bond length is 1.40 Å. The C(7)-C(28) bond length is 1.40 Å. The C(7)-C(40) bond length is 1.49 Å. In the fifth C site, C(8) is bonded in a trigonal planar geometry to one C(23), one C(29), and one C(41) atom. The C(8)-C(23) bond length is 1.40 Å. The C(8)-C(29) bond length is 1.40 Å. The C(8)-C(41) bond length is 1.49 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(24), one C(30), and one C(42) atom. The C(9)-C(24) bond length is 1.40 Å. The C(9)-C(30) bond length is 1.40 Å. The C(9)-C(42) bond length is 1.49 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(1,2); one C(61,62,63); and one N(10,11) atom. The C(10)-C(61,62,63) bond length is 1.49 Å. The C(10)-N(10,11) bond length is 1.35 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(1,2); one C(61,62,63); and one N(10,11) atom. The C(11)-C(1,2) bond length is 1.41 Å. The C(11)-C(61,62,63) bond length is 1.49 Å. The C(11)-N(10,11) bond length is 1.35 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(3); one C(61,62,63); and one N(12) atom. The C(12)-C(61,62,63) bond length is 1.49 Å. The C(12)-N(12) bond length is 1.35 Å. In the tenth C site, C(13) is bonded in a trigonal planar geometry to one C(19); one C(31,32); and one C(34,35,36) atom. The C(13)-C(19) bond length is 1.40 Å. The C(13)-C(31,32) bond length is 1.41 Å. The C(13)-C(34,35,36) bond length is 1.47 Å. In the eleventh C site, C(14) is bonded in a trigonal planar geometry to one C(20); one C(31,32); and one C(34,35,36) atom. The C(14)-C(20) bond length is 1.40 Å. The C(14)-C(31,32) bond length is 1.41 Å. The C(14)-C(34,35,36) bond length is 1.47 Å. In the twelfth C site, C(15) is bonded in a trigonal planar geometry to one C(21); one C(33); and one C(34,35,36) atom. The C(15)-C(21) bond length is 1.40 Å. The C(15)-C(33) bond length is 1.41 Å. The C(15)-C(34,35,36) bond length is 1.47 Å. In the thirteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(1), and one O(10) atom. The C(16)-C(25) bond length is 1.50 Å. The C(16)-O(1) bond length is 1.30 Å. The C(16)-O(10) bond length is 1.26 Å. In the fourteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(11), and one O(2) atom. The C(17)-C(26) bond length is 1.50 Å. The C(17)-O(11) bond length is 1.26 Å. The C(17)-O(2) bond length is 1.30 Å. In the fifteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(12), and one O(3) atom. The C(18)-C(27) bond length is 1.50 Å. The C(18)-O(12) bond length is 1.26 Å. The C(18)-O(3) bond length is 1.30 Å. In the sixteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(13); one C(52,53,54); and one N(4) atom. The C(19)-C(52,53,54) bond length is 1.49 Å. The C(19)-N(4) bond length is 1.35 Å. In the seventeenth C site, C(20) is bonded in a distorted single-bond geometry to one C(14); one C(52,53,54); and one N(5) atom. The C(20)-C(52,53,54) bond length is 1.49 Å. The C(20)-N(5) bond length is 1.35 Å. In the eighteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(15); one C(52,53,54); and one N(6) atom. The C(21)-C(52,53,54) bond length is 1.49 Å. The C(21)-N(6) bond length is 1.35 Å. In the nineteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(7) and one H(1,2,3,4,5,6) atom. The C(22)-H(1,2,3,4,5,6) bond length is 1.09 Å. In the twentieth C site, C(23) is bonded in a distorted single-bond geometry to one C(8) and one H(1,2,3,4,5,6) atom. The C(23)-H(1,2,3,4,5,6) bond length is 1.09 Å. In the twenty-first C site, C(24) is bonded in a distorted single-bond geometry to one C(9) and one H(1,2,3,4,5,6) atom. The C(24)-H(1,2,3,4,5,6) bond length is 1.09 Å. In the twenty-second C site, C(25) is bonded in a trigonal planar geometry to one C(16); one C(64,65,66); and one C(67,68,69) atom. The C(25)-C(64,65,66) bond length is 1.40 Å. The C(25)-C(67,68,69) bond length is 1.40 Å. In the twenty-third C site, C(26) is bonded in a trigonal planar geometry to one C(17); one C(64,65,66); and one C(67,68,69) atom. The C(26)-C(64,65,66) bond length is 1.40 Å. The C(26)-C(67,68,69) bond length is 1.40 Å. In the twenty-fourth C site, C(27) is bonded in a trigonal planar geometry to one C(18); one C(64,65,66); and one C(67,68,69) atom. The C(27)-C(64,65,66) bond length is 1.40 Å. The C(27)-C(67,68,69) bond length is 1.40 Å. In the twenty-fifth C site, C(28) is bonded in a distorted single-bond geometry to one C(7) and one H(1,2,3,4,5,6) atom. The C(28)-H(1,2,3,4,5,6) bond length is 1.09 Å. In the twenty-sixth C site, C(29) is bonded in a distorted single-bond geometry to one C(8) and one H(1,2,3,4,5,6) atom. The C(29)-H(1,2,3,4,5,6) bond length is 1.09 Å. In the twenty-seventh C site, C(30) is bonded in a distorted single-bond geometry to one C(9) and one H(1,2,3,4,5,6) atom. The C(30)-H(1,2,3,4,5,6) bond length is 1.09 Å. In the twenty-eighth C site, C(31,32) is bonded in a distorted single-bond geometry to one C(13), one C(58), and one N(7) atom. The C(31,32)-C(58) bond length is 1.49 Å. The C(31,32)-N(7) bond length is 1.35 Å. In the twenty-ninth C site, C(33) is bonded in a distorted single-bond geometry to one C(15), one C(60), and one N(9) atom. The C(33)-C(60) bond length is 1.49 Å. The C(33)-N(9) bond length is 1.35 Å. In the thirtieth C site, C(34,35,36) is bonded in a trigonal planar geometry to one C(13), one C(55), and one C(70) atom. The C(34,35,36)-C(55) bond length is 1.40 Å. The C(34,35,36)-C(70) bond length is 1.40 Å. In the thirty-first C site, C(37,38,39) is bonded in a trigonal planar geometry to one C(1,2); one C(43,44,45); and one C(46,47,48) atom. The C(37,38,39)-C(43,44,45) bond length is 1.41 Å. The C(37,38,39)-C(46,47,48) bond length is 1.41 Å. In the thirty-second C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(4), and one O(7) atom. The C(40)-O(4) bond length is 1.29 Å. The C(40)-O(7) bond length is 1.26 Å. In the thirty-third C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(5), and one O(8) atom. The C(41)-O(5) bond length is 1.29 Å. The C(41)-O(8) bond length is 1.26 Å. In the thirty-fourth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(6), and one O(9) atom. The C(42)-O(6) bond length is 1.29 Å. The C(42)-O(9) bond length is 1.26 Å. In the thirty-fifth C site, C(43,44,45) is bonded in a distorted single-bond geometry to one C(37,38,39) and one H(7,8,9,10,11,12) atom. The C(43,44,45)-H(7,8,9,10,11,12) bond length is 1.09 Å. In the thirty-sixth C site, C(46,47,48) is bonded in a distorted single-bond geometry to one C(37,38,39) and one H(7,8,9,10,11,12) atom. The C(46,47,48)-H(7,8,9,10,11,12) bond length is 1.09 Å. In the thirty-seventh C site, C(49,50) is bonded in a distorted trigonal non-coplanar geometry to one C(4,5,6); one H(13,14,15); one H(16,17,18); and one H(19,20,21) atom. The C(49,50)-H(13,14,15) bond length is 1.10 Å. The C(49,50)-H(16,17,18) bond length is 1.10 Å. The C(49,50)-H(19,20,21) bond length is 1.10 Å. In the thirty-eighth C site, C(51) is bonded in a distorted trigonal non-coplanar geometry to one C(4,5,6); one H(13,14,15); one H(16,17,18); and one H(19,20,21) atom. The C(51)-C(4,5,6) bond length is 1.49 Å. The C(51)-H(13,14,15) bond length is 1.09 Å. The C(51)-H(16,17,18) bond length is 1.10 Å. The C(51)-H(19,20,21) bond length is 1.10 Å. In the thirty-ninth C site, C(52,53,54) is bonded in a distorted trigonal non-coplanar geometry to one C(19); one H(22,23,24); one H(25,26,27); and one H(28,29,30) atom. The C(52,53,54)-H(22,23,24) bond length is 1.10 Å. The C(52,53,54)-H(25,26,27) bond length is 1.10 Å. The C(52,53,54)-H(28,29,30) bond length is 1.10 Å. In the fortieth C site, C(55) is bonded in a distorted trigonal planar geometry to one C(34,35,36); one C(64,65,66); and one H(31,32,33) atom. The C(55)-C(64,65,66) bond length is 1.39 Å. The C(55)-H(31,32,33) bond length is 1.09 Å. In the forty-first C site, C(56,57) is bonded in a distorted trigonal planar geometry to one C(34,35,36); one C(64,65,66); and one H(31,32,33) atom. The C(56,57)-C(34,35,36) bond length is 1.40 Å. The C(56,57)-C(64,65,66) bond length is 1.39 Å. The C(56,57)-H(31,32,33) bond length is 1.09 Å. In the forty-second C site, C(58) is bonded in a distorted trigonal non-coplanar geometry to one C(31,32); one H(34,35,36); one H(37,38,39); and one H(40,41,42) atom. The C(58)-H(34,35,36) bond length is 1.10 Å. The C(58)-H(37,38,39) bond length is 1.10 Å. The C(58)-H(40,41,42) bond length is 1.10 Å. In the forty-third C site, C(59) is bonded in a distorted trigonal non-coplanar geometry to one C(31,32); one H(34,35,36); one H(37,38,39); and one H(40,41,42) atom. The C(59)-C(31,32) bond length is 1.49 Å. The C(59)-H(34,35,36) bond length is 1.10 Å. The C(59)-H(37,38,39) bond length is 1.10 Å. The C(59)-H(40,41,42) bond length is 1.10 Å. In the forty-fourth C site, C(60) is bonded in a distorted trigonal non-coplanar geometry to one C(33); one H(34,35,36); one H(37,38,39); and one H(40,41,42) atom. The C(60)-H(34,35,36) bond length is 1.10 Å. The C(60)-H(37,38,39) bond length is 1.10 Å. The C(60)-H(40,41,42) bond length is 1.10 Å. In the forty-fifth C site, C(61,62,63) is bonded in a distorted trigonal non-coplanar geometry to one C(10); one H(43,44,45); one H(46,47,48); and one H(49,50,51) atom. The C(61,62,63)-H(43,44,45) bond length is 1.10 Å. The C(61,62,63)-H(46,47,48) bond length is 1.10 Å. The C(61,62,63)-H(49,50,51) bond length is 1.10 Å. In the forty-sixth C site, C(64,65,66) is bonded in a distorted single-bond geometry to one C(25); one C(55); and one H(52,53,54) atom. The C(64,65,66)-H(52,53,54) bond length is 1.09 Å. In the forty-seventh C site, C(67,68,69) is bonded in a distorted single-bond geometry to one C(25) and one H(55,56,57) atom. The C(67,68,69)-H(55,56,57) bond length is 1.09 Å. In the forty-eighth C site, C(70) is bonded in a distorted single-bond geometry to one C(34,35,36) and one H(58,59,60) atom. The C(70)-H(58,59,60) bond length is 1.09 Å. In the forty-ninth C site, C(71,72) is bonded in a distorted single-bond geometry to one C(34,35,36) and one H(58,59,60) atom. The C(71,72)-C(34,35,36) bond length is 1.40 Å. The C(71,72)-H(58,59,60) bond length is 1.09 Å. There are eleven inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1); one C(4,5,6); and one N(10,11) atom. The N(1)-N(10,11) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(2); one C(4,5,6); and one N(10,11) atom. The N(2)-C(4,5,6) bond length is 1.35 Å. The N(2)-N(10,11) bond length is 1.36 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Zn(3); one C(4,5,6); and one N(12) atom. The N(3)-C(4,5,6) bond length is 1.35 Å. The N(3)-N(12) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one C(19), one N(7), and one H(64) atom. The N(4)-N(7) bond length is 1.35 Å. The N(4)-H(64) bond length is 1.06 Å. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one C(20), one N(8), and one H(65) atom. The N(5)-N(8) bond length is 1.35 Å. The N(5)-H(65) bond length is 1.06 Å. In the sixth N site, N(6) is bonded in a 3-coordinate geometry to one C(21), one N(9), and one H(66) atom. The N(6)-N(9) bond length is 1.35 Å. The N(6)-H(66) bond length is 1.06 Å. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Zn(1); one C(31,32); and one N(4) atom. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Zn(2); one C(31,32); and one N(5) atom. The N(8)-C(31,32) bond length is 1.35 Å. In the ninth N site, N(9) is bonded in a distorted trigonal planar geometry to one Zn(3), one C(33), and one N(6) atom. In the tenth N site, N(10,11) is bonded in a 2-coordinate geometry to one C(10), one N(1), and one H(61) atom. The N(10,11)-H(61) bond length is 1.05 Å. In the eleventh N site, N(12) is bonded in a 2-coordinate geometry to one C(12), one N(3), and one H(63) atom. The N(12)-H(63) bond length is 1.05 Å. There are twenty-four inequivalent H sites. In the first H site, H(1,2,3,4,5,6) is bonded in a single-bond geometry to one C(22) atom. In the second H site, H(7,8,9,10,11,12) is bonded in a single-bond geometry to one C(43,44,45) atom. In the third H site, H(13,14,15) is bonded in a single-bond geometry to one C(49,50) atom. In the fourth H site, H(16,17,18) is bonded in a single-bond geometry to one C(49,50) atom. In the fifth H site, H(19,20,21) is bonded in a single-bond geometry to one C(49,50) atom. In the sixth H site, H(22,23,24) is bonded in a single-bond geometry to one C(52,53,54) atom. In the seventh H site, H(25,26,27) is bonded in a single-bond geometry to one C(52,53,54) atom. In the eighth H site, H(28,29,30) is bonded in a single-bond geometry to one C(52,53,54) atom. In the ninth H site, H(31,32,33) is bonded in a single-bond geometry to one C(55) atom. In the tenth H site, H(34,35,36) is bonded in a single-bond geometry to one C(58) atom. In the eleventh H site, H(37,38,39) is bonded in a single-bond geometry to one C(58) atom. In the twelfth H site, H(40,41,42) is bonded in a single-bond geometry to one C(58) atom. In the thirteenth H site, H(43,44,45) is bonded in a single-bond geometry to one C(61,62,63) atom. In the fourteenth H site, H(46,47,48) is bonded in a single-bond geometry to one C(61,62,63) atom. In the fifteenth H site, H(49,50,51) is bonded in a single-bond geometry to one C(61,62,63) atom. In the sixteenth H site, H(52,53,54) is bonded in a single-bond geometry to one C(64,65,66) atom. In the seventeenth H site, H(55,56,57) is bonded in a single-bond geometry to one C(67,68,69) atom. In the eighteenth H site, H(58,59,60) is bonded in a single-bond geometry to one C(70) atom. In the nineteenth H site, H(61) is bonded in a distorted single-bond geometry to one N(10,11) and one O(11) atom. The H(61)-O(11) bond length is 1.66 Å. In the twentieth H site, H(62) is bonded in a distorted single-bond geometry to one N(10,11) and one O(12) atom. The H(62)-N(10,11) bond length is 1.05 Å. The H(62)-O(12) bond length is 1.66 Å. In the twenty-first H site, H(63) is bonded in a distorted single-bond geometry to one N(12) and one O(10) atom. The H(63)-O(10) bond length is 1.65 Å. In the twenty-second H site, H(64) is bonded in a distorted single-bond geometry to one N(4) and one O(9) atom. The H(64)-O(9) bond length is 1.63 Å. In the twenty-third H site, H(65) is bonded in a distorted single-bond geometry to one N(5) and one O(7) atom. The H(65)-O(7) bond length is 1.63 Å. In the twenty-fourth H site, H(66) is bonded in a distorted single-bond geometry to one N(6) and one O(8) atom. The H(66)-O(8) bond length is 1.63 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(16) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(18) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(40) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(41) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(42) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one C(40) and one H(65) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one C(41) and one H(66) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one C(42) and one H(64) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one C(16) and one H(63) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one C(17) and one H(61) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one C(18) and one H(62) atom. Linkers: 12 Cc1n[nH]c(C)c1-c1ccc(C([O])=O)cc1. Metal clusters: 6 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 6.63 A, density 1.18 g/cm3, surface area 5262.93 m2/g, accessible volume 0.25 cm3/g