AgC7N5H6O2CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one AgC7N5H6O2 cluster. In the AgC7N5H6O2 cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one N(7) and one N(9) atom. The Ag(1)-N(7) bond length is 2.08 Å. The Ag(1)-N(9) bond length is 2.08 Å. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one N(4), one O(1), one O(3), and one O(4) atom. The Ag(2)-N(4) bond length is 2.44 Å. The Ag(2)-O(1) bond length is 2.36 Å. The Ag(2)-O(3) bond length is 2.45 Å. The Ag(2)-O(4) bond length is 2.41 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one N(6) atom. The C(1)-C(5) bond length is 1.41 Å. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(6) bond length is 1.38 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(14), one C(3), and one N(7) atom. The C(2)-C(14) bond length is 1.39 Å. The C(2)-C(3) bond length is 1.41 Å. The C(2)-N(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one N(8) atom. The C(3)-N(2) bond length is 1.33 Å. The C(3)-N(8) bond length is 1.38 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(2), one N(3), and one N(4) atom. The C(4)-N(2) bond length is 1.36 Å. The C(4)-N(3) bond length is 1.35 Å. The C(4)-N(4) bond length is 1.37 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(1), one C(7), and one N(9) atom. The C(5)-C(7) bond length is 1.40 Å. The C(5)-N(9) bond length is 1.39 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(1), one N(10), and one N(5) atom. The C(6)-N(1) bond length is 1.37 Å. The C(6)-N(10) bond length is 1.35 Å. The C(6)-N(5) bond length is 1.37 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5), one N(5), and one H(3) atom. The C(7)-N(5) bond length is 1.33 Å. The C(7)-H(3) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(6), and one H(7) atom. The C(8)-N(6) bond length is 1.46 Å. The C(8)-H(6) bond length is 1.09 Å. The C(8)-H(7) bond length is 1.10 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(10)-O(2) bond length is 1.27 Å. The C(10)-O(3) bond length is 1.28 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one N(6), one N(9), and one H(10) atom. The C(11)-N(6) bond length is 1.37 Å. The C(11)-N(9) bond length is 1.33 Å. The C(11)-H(10) bond length is 1.08 Å. In the eleventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(12)-O(1) bond length is 1.27 Å. The C(12)-O(4) bond length is 1.27 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(2), one N(4), and one H(13) atom. The C(14)-N(4) bond length is 1.34 Å. The C(14)-H(13) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one N(8), one H(14), and one H(15) atom. The C(15)-N(8) bond length is 1.46 Å. The C(15)-H(14) bond length is 1.09 Å. The C(15)-H(15) bond length is 1.10 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(16) atom. The C(16)-N(7) bond length is 1.33 Å. The C(16)-N(8) bond length is 1.37 Å. The C(16)-H(16) bond length is 1.08 Å. There are ten inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(6) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(3) and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(4), one H(1), and one H(2) atom. The N(3)-H(1) bond length is 1.03 Å. The N(3)-H(2) bond length is 1.02 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(14), and one C(4) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(6) and one C(7) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(8) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(16), and one C(2) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(3) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Ag(1), one C(11), and one C(5) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one C(6), one H(4), and one H(5) atom. The N(10)-H(4) bond length is 1.02 Å. The N(10)-H(5) bond length is 1.03 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(10) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(10) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(2) and one C(12) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(10) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(2) and one C(10) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(2) and one C(12) atom. Linkers: 1 NC1=N[CH]c2ncn(CCC([O])=O)c2[N]1 ,3 Nc1ncc2ncn(CCC([O])=O)c2n1. Metal clusters: 2 [Ag] ,1 O=[C]O[Ag@]12O[C]O[Ag@]1(O[C]=O)O[C]O2. The MOF has largest included sphere 2.87 A, density 2.15 g/cm3, surface area 3380.75 m2/g, accessible volume 0.09 cm3/g