Ag3C13H7(NO3)2 crystallizes in the monoclinic C2/c space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted T-shaped geometry to one N(1), one O(2), and one O(3) atom. The Ag(1)-N(1) bond length is 2.30 Å. The Ag(1)-O(2) bond length is 2.23 Å. The Ag(1)-O(3) bond length is 2.26 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one N(2), one O(1), and one O(6) atom. The Ag(2)-N(2) bond length is 2.33 Å. The Ag(2)-O(1) bond length is 2.28 Å. The Ag(2)-O(6) bond length is 2.21 Å. In the third Ag site, Ag(3) is bonded in a 2-coordinate geometry to one O(4) and one O(5) atom. The Ag(3)-O(4) bond length is 2.20 Å. The Ag(3)-O(5) bond length is 2.19 Å. There are thirteen inequivalent C sites. In the first C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(7) atom. The C(13)-C(12) bond length is 1.39 Å. The C(13)-N(2) bond length is 1.34 Å. The C(13)-H(7) bond length is 1.09 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(3) atom. The C(1)-C(4) bond length is 1.50 Å. The C(1)-O(2) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.28 Å. In the third C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(4) atom. The C(2)-C(6) bond length is 1.50 Å. The C(2)-O(1) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.28 Å. In the fourth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(5), and one O(6) atom. The C(3)-C(8) bond length is 1.50 Å. The C(3)-O(5) bond length is 1.28 Å. The C(3)-O(6) bond length is 1.28 Å. In the fifth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(9) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(9) bond length is 1.40 Å. In the sixth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(1) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(1) bond length is 1.09 Å. In the seventh C site, C(6) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.40 Å. In the eighth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(2) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(2) bond length is 1.09 Å. In the ninth C site, C(8) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.40 Å. In the tenth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(4), one C(8), and one H(3) atom. The C(9)-H(3) bond length is 1.09 Å. In the eleventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(10)-N(1) bond length is 1.34 Å. The C(10)-H(4) bond length is 1.09 Å. In the twelfth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(11)-N(1) bond length is 1.34 Å. The C(11)-H(5) bond length is 1.09 Å. In the thirteenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one N(2), and one H(6) atom. The C(12)-N(2) bond length is 1.34 Å. The C(12)-H(6) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(10), and one C(11) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(2), one C(12), and one C(13) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(13) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one C(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ag(1) and one C(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Ag(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one Ag(3) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Ag(3) and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one C(3) atom. Linkers: 3 c1cnccn1 ,4 [O]C(=O)c1cc(C([O])=O)cc(C([O])=O)c1. Metal clusters: 12 [Ag]. The MOF has largest included sphere 2.68 A, density 2.73 g/cm3, surface area 2207.72 m2/g, accessible volume 0.07 cm3/g