AgC14N5H8 crystallizes in the triclinic P-1 space group. The structure consists of a AgC14N5H8 framework. Ag(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(2), one N(3), one N(4), and one N(5) atom. The Ag(1)-N(1) bond length is 2.73 Å. The Ag(1)-N(2) bond length is 2.74 Å. The Ag(1)-N(3) bond length is 2.79 Å. The Ag(1)-N(4) bond length is 2.18 Å. The Ag(1)-N(5) bond length is 2.18 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(4) and one N(1) atom. The C(1)-C(4) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.18 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(4) and one N(2) atom. The C(2)-C(4) bond length is 1.40 Å. The C(2)-N(2) bond length is 1.18 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one N(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-N(3) bond length is 1.17 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(7), one N(4), and one H(1) atom. The C(5)-C(7) bond length is 1.39 Å. The C(5)-N(4) bond length is 1.35 Å. The C(5)-H(1) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(8), one N(5), and one H(2) atom. The C(6)-C(8) bond length is 1.39 Å. The C(6)-N(5) bond length is 1.35 Å. The C(6)-H(2) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(5), one C(9), and one H(3) atom. The C(7)-C(9) bond length is 1.40 Å. The C(7)-H(3) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(10), one C(6), and one H(4) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-H(4) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(7) atom. The C(9)-C(10) bond length is 1.47 Å. The C(9)-C(11) bond length is 1.40 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(12), one C(8), and one C(9) atom. The C(10)-C(12) bond length is 1.40 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(9) and one H(5,6) atom. The C(11)-H(5,6) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one H(5,6) atom. The C(12)-H(5,6) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one N(4) and one H(7,8) atom. The C(13)-N(4) bond length is 1.35 Å. The C(13)-H(7,8) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one N(5) and one H(7,8) atom. The C(14)-N(5) bond length is 1.35 Å. The C(14)-H(7,8) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ag(1) and one C(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ag(1) and one C(2) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Ag(1) and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(1), one C(13), and one C(5) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Ag(1), one C(14), and one C(6) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(13) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Ag]. The MOF has largest included sphere 1.57 A, density 1.92 g/cm3, surface area 3980.97 m2/g, accessible volume 0.09 cm3/g