Mn2C36N6H30S4O11CH2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a Mn2C36N6H30S4O11 framework. In the Mn2C36N6H30S4O11 framework, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one N(4), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form distorted corner-sharing MnNO5 octahedra. The corner-sharing octahedral tilt angles are 74°. The Mn(1)-N(4) bond length is 2.20 Å. The Mn(1)-O(2) bond length is 2.09 Å. The Mn(1)-O(3) bond length is 2.15 Å. The Mn(1)-O(5) bond length is 2.23 Å. The Mn(1)-O(7) bond length is 2.06 Å. The Mn(1)-O(9) bond length is 2.30 Å. In the second Mn site, Mn(2) is bonded to one N(5), one O(10), one O(11), one O(4), one O(8), and one O(9) atom to form corner-sharing MnNO5 octahedra. The corner-sharing octahedral tilt angles are 74°. The Mn(2)-N(5) bond length is 2.28 Å. The Mn(2)-O(10) bond length is 2.19 Å. The Mn(2)-O(11) bond length is 2.39 Å. The Mn(2)-O(4) bond length is 2.16 Å. The Mn(2)-O(8) bond length is 2.14 Å. The Mn(2)-O(9) bond length is 2.25 Å. There are thirty-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(35) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(35) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one N(1), and one S(1) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-S(1) bond length is 1.78 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(5), and one O(6) atom. The C(6)-C(7) bond length is 1.49 Å. The C(6)-O(5) bond length is 1.26 Å. The C(6)-O(6) bond length is 1.30 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.40 Å. The C(7)-C(8) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(3) atom. The C(8)-H(3) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(4) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(4) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(9), one N(6), and one S(2) atom. The C(10)-N(6) bond length is 1.34 Å. The C(10)-S(2) bond length is 1.77 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(6), and one H(5) atom. The C(11)-N(6) bond length is 1.34 Å. The C(11)-H(5) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(3), and one O(4) atom. The C(12)-C(13) bond length is 1.50 Å. The C(12)-O(3) bond length is 1.27 Å. The C(12)-O(4) bond length is 1.28 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(36) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(36) bond length is 1.40 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(6) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(6) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(7) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(7) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one N(2), and one S(3) atom. The C(16)-N(2) bond length is 1.34 Å. The C(16)-S(3) bond length is 1.79 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(7), and one O(8) atom. The C(17)-C(18) bond length is 1.49 Å. The C(17)-O(7) bond length is 1.27 Å. The C(17)-O(8) bond length is 1.27 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(37) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(37) bond length is 1.40 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(8) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-H(8) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(9) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(9) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one N(3), and one S(4) atom. The C(21)-N(3) bond length is 1.34 Å. The C(21)-S(4) bond length is 1.78 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(10) atom. The C(22)-N(4) bond length is 1.35 Å. The C(22)-H(10) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(11) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-H(11) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(27) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-C(27) bond length is 1.50 Å. In the twenty-fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(24), one C(26), and one H(12) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-H(12) bond length is 1.09 Å. In the twenty-sixth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one N(4), and one H(13) atom. The C(26)-N(4) bond length is 1.35 Å. The C(26)-H(13) bond length is 1.09 Å. In the twenty-seventh C site, C(27) is bonded in a distorted water-like geometry to one C(24), one H(14), and one H(15) atom. The C(27)-H(14) bond length is 1.10 Å. The C(27)-H(15) bond length is 1.10 Å. In the twenty-eighth C site, C(29) is bonded in a distorted water-like geometry to one C(30), one H(18), and one H(19) atom. The C(29)-C(30) bond length is 1.50 Å. The C(29)-H(18) bond length is 1.10 Å. The C(29)-H(19) bond length is 1.10 Å. In the twenty-ninth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(34) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-C(34) bond length is 1.40 Å. In the thirtieth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(20) atom. The C(31)-H(20) bond length is 1.09 Å. In the thirty-first C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(21) atom. The C(32)-N(5) bond length is 1.35 Å. The C(32)-H(21) bond length is 1.09 Å. In the thirty-second C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(34), one N(5), and one H(22) atom. The C(33)-C(34) bond length is 1.39 Å. The C(33)-N(5) bond length is 1.35 Å. The C(33)-H(22) bond length is 1.09 Å. In the thirty-third C site, C(34) is bonded in a distorted trigonal planar geometry to one C(30), one C(33), and one H(23) atom. The C(34)-H(23) bond length is 1.09 Å. In the thirty-fourth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(24) atom. The C(35)-N(1) bond length is 1.34 Å. The C(35)-H(24) bond length is 1.09 Å. In the thirty-fifth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(13), one N(2), and one H(25) atom. The C(36)-N(2) bond length is 1.34 Å. The C(36)-H(25) bond length is 1.09 Å. In the thirty-sixth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(3), and one H(26) atom. The C(37)-N(3) bond length is 1.33 Å. The C(37)-H(26) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(35) and one C(5) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(16) and one C(36) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(21) and one C(37) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Mn(1), one C(22), and one C(26) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Mn(2), one C(32), and one C(33) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one C(10) and one C(11) atom. There are thirty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(26) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(27) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(29) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(31) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(32) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(33) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(34) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(35) atom. In the twenty-third H site, H(25) is bonded in a single-bond geometry to one C(36) atom. In the twenty-fourth H site, H(26) is bonded in a single-bond geometry to one C(37) atom. In the twenty-fifth H site, H(27) is bonded in a distorted linear geometry to one O(1) and one O(9) atom. The H(27)-O(1) bond length is 1.57 Å. The H(27)-O(9) bond length is 1.04 Å. In the twenty-sixth H site, H(28) is bonded in a single-bond geometry to one O(6) and one O(9) atom. The H(28)-O(6) bond length is 1.68 Å. The H(28)-O(9) bond length is 1.00 Å. In the twenty-seventh H site, H(29) is bonded in a distorted linear geometry to one O(10) and one O(6) atom. The H(29)-O(10) bond length is 1.00 Å. The H(29)-O(6) bond length is 1.62 Å. In the twenty-eighth H site, H(30) is bonded in a single-bond geometry to one O(10) atom. The H(30)-O(10) bond length is 0.99 Å. In the twenty-ninth H site, H(31) is bonded in a single-bond geometry to one O(11) and one O(6) atom. The H(31)-O(11) bond length is 0.99 Å. The H(31)-O(6) bond length is 1.75 Å. In the thirtieth H site, H(32) is bonded in a single-bond geometry to one O(11) atom. The H(32)-O(11) bond length is 0.98 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(5) and one S(2) atom. The S(1)-S(2) bond length is 2.03 Å. In the second S site, S(2) is bonded in a water-like geometry to one C(10) and one S(1) atom. In the third S site, S(3) is bonded in a water-like geometry to one C(16) and one S(4) atom. The S(3)-S(4) bond length is 2.04 Å. In the fourth S site, S(4) is bonded in a water-like geometry to one C(21) and one S(3) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(1) and one H(27) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(12) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(12) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(6) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one C(6), one H(28), one H(29), and one H(31) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(17) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(17) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Mn(1), one Mn(2), one H(27), and one H(28) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Mn(2), one H(29), and one H(30) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Mn(2), one H(31), and one H(32) atom. Linkers: 8 [O]C(=O)c1ccc(SSc2ccc(C([O])=O)cn2)nc1 ,4 c1cc(CCCc2ccncc2)ccn1. Metal clusters: 4 O.O.O.[O][C]O[Mn]1(O[C]=O)O[C]O[Mn]O[C]O1. RCSR code: hcb. The MOF has largest included sphere 3.50 A, density 1.54 g/cm3, surface area 4218.10 m2/g, accessible volume 0.15 cm3/g