ZnC16NH10O4C6H4SO2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two di-isopropenylsulfon molecules and one ZnC16NH10O4 cluster. In the ZnC16NH10O4 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 2.08 Å. The Zn(1)-O(2) bond length is 2.06 Å. The Zn(1)-O(3) bond length is 2.06 Å. The Zn(1)-O(4) bond length is 2.09 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(2), and one O(3) atom. The C(1)-C(22) bond length is 1.50 Å. The C(1)-O(2) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(17) atom. The C(2)-C(14) bond length is 1.41 Å. The C(2)-C(16) bond length is 1.40 Å. The C(2)-C(17) bond length is 1.47 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(17), one C(4), and one H(1) atom. The C(3)-C(17) bond length is 1.40 Å. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(2) atom. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(17), one C(18), and one H(3) atom. The C(5)-C(17) bond length is 1.40 Å. The C(5)-C(18) bond length is 1.38 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(1), and one O(4) atom. The C(7)-C(15) bond length is 1.50 Å. The C(7)-O(1) bond length is 1.28 Å. The C(7)-O(4) bond length is 1.27 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(15) and one H(7,14) atom. The C(11)-C(15) bond length is 1.40 Å. The C(11)-H(7,14) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(2) and one H(9) atom. The C(14)-H(9) bond length is 1.09 Å. In the ninth C site, C(15) is bonded in a trigonal planar geometry to one C(11), one C(21), and one C(7) atom. The C(15)-C(21) bond length is 1.40 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(2) and one H(10) atom. The C(16)-H(10) bond length is 1.09 Å. In the eleventh C site, C(17) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(5) atom. In the twelfth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(1), and one H(11) atom. The C(18)-N(1) bond length is 1.35 Å. The C(18)-H(11) bond length is 1.09 Å. In the thirteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(22) and one H(12) atom. The C(19)-C(22) bond length is 1.40 Å. The C(19)-H(12) bond length is 1.09 Å. In the fourteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(22) and one H(13) atom. The C(20)-C(22) bond length is 1.40 Å. The C(20)-H(13) bond length is 1.09 Å. In the fifteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(15) and one H(7,14) atom. The C(21)-H(7,14) bond length is 1.09 Å. In the sixteenth C site, C(22) is bonded in a trigonal planar geometry to one C(1), one C(19), and one C(20) atom. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(18), and one C(4) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(7,14) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(7) atom. Linkers: 1 c1cc(-c2ccc(-c3ccncc3)cc2)ccn1 ,2 [O]C(=O)c1ccc(S(=O)(=O)c2ccc(C([O])=O)cc2)cc1. Metal clusters: 1 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 4.83 A, density 1.30 g/cm3, surface area 4386.54 m2/g, accessible volume 0.25 cm3/g