NaC7N2H9S2O3(CH)3CH3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two 02329_fluka molecules, and one NaC7N2H9S2O3 cluster. In the NaC7N2H9S2O3 cluster, Na(1) is bonded in a 4-coordinate geometry to one N(1), one O(1), one O(2), and one O(3) atom. The Na(1)-N(1) bond length is 2.44 Å. The Na(1)-O(1) bond length is 2.37 Å. The Na(1)-O(2) bond length is 2.35 Å. The Na(1)-O(3) bond length is 2.33 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one O(1) atom. The C(1)-C(2) bond length is 1.47 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-O(1) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(7) bond length is 1.42 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(3)-H(4) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one O(2) atom. The C(7)-O(2) bond length is 1.35 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one N(1), one S(1), and one S(2) atom. The C(8)-N(1) bond length is 1.33 Å. The C(8)-S(1) bond length is 1.70 Å. The C(8)-S(2) bond length is 1.78 Å. In the sixth C site, C(9) is bonded in a trigonal non-coplanar geometry to one H(10), one H(8), one H(9), and one S(2) atom. The C(9)-H(10) bond length is 1.10 Å. The C(9)-H(8) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.09 Å. The C(9)-S(2) bond length is 1.80 Å. In the seventh C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one H(11), one H(12), and one O(3) atom. The C(10)-H(11) bond length is 1.10 Å. The C(10)-H(12) bond length is 1.10 Å. The C(10)-O(3) bond length is 1.44 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Na(1), one C(8), and one N(2) atom. The N(1)-N(2) bond length is 1.37 Å. In the second N site, N(2) is bonded in a 2-coordinate geometry to one C(1), one N(1), and one H(3) atom. The N(2)-H(3) bond length is 1.03 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a bent 150 degrees geometry to one O(1) and one O(2) atom. The H(1)-O(1) bond length is 1.51 Å. The H(1)-O(2) bond length is 1.03 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. The H(2)-O(3) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one C(8) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(8) and one C(9) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one C(1), and one H(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one C(7), and one H(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(1), one C(10), and one H(2) atom. Linkers: 2 CSC(=S)[N]NC(=O)c1ccccc1O. Metal clusters: 2 [Na]. The MOF has largest included sphere 2.84 A, density 1.40 g/cm3, surface area 4848.52 m2/g, accessible volume 0.19 cm3/g