Cu2C17H18(NO)6(CH3)2 crystallizes in the tetragonal P4_32_12 space group. The structure consists of eight 02329_fluka molecules inside a Cu2C17H18(NO)6 framework. In the Cu2C17H18(NO)6 framework, Cu(1) is bonded in a square pyramidal geometry to one N(2), one N(3), one O(1), one O(2), and one O(3) atom. The Cu(1)-N(2) bond length is 1.95 Å. The Cu(1)-N(3) bond length is 1.92 Å. The Cu(1)-O(1) bond length is 2.04 Å. The Cu(1)-O(2) bond length is 2.08 Å. The Cu(1)-O(3) bond length is 2.34 Å. There are nine inequivalent C sites. In the first C site, C(4) is bonded in a distorted trigonal planar geometry to one C(1), one C(9), and one N(2) atom. The C(4)-C(1) bond length is 1.42 Å. The C(4)-C(9) bond length is 1.49 Å. The C(4)-N(2) bond length is 1.35 Å. In the second C site, C(5) is bonded in a water-like geometry to two equivalent C(1) and two equivalent H(2) atoms. Both C(5)-C(1) bond lengths are 1.51 Å. Both C(5)-H(2) bond lengths are 1.10 Å. In the third C site, C(6) is bonded in a 2-coordinate geometry to one N(3) and one H(3) atom. The C(6)-N(3) bond length is 1.44 Å. The C(6)-H(3) bond length is 1.10 Å. In the fourth C site, C(7) is bonded in a 3-coordinate geometry to one C(1), one C(8), and one N(1) atom. The C(7)-C(1) bond length is 1.40 Å. The C(7)-C(8) bond length is 1.49 Å. The C(7)-N(1) bond length is 1.35 Å. In the fifth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(7), one H(4), one H(5), and one H(6) atom. The C(8)-H(4) bond length is 1.10 Å. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.10 Å. In the sixth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one H(7), one H(8), and one H(9) atom. The C(9)-H(7) bond length is 1.10 Å. The C(9)-H(8) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. In the seventh C site, C(1) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(7) atom. In the eighth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(2)-O(1) bond length is 1.30 Å. The C(2)-O(3) bond length is 1.25 Å. In the ninth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(3) and one O(2) atom. The C(3)-N(3) bond length is 1.31 Å. The C(3)-O(2) bond length is 1.28 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one C(7), one N(2), and one H(1) atom. The N(1)-N(2) bond length is 1.35 Å. The N(1)-H(1) bond length is 1.04 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(4), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(6) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one N(1) and one O(1) atom. The H(1)-O(1) bond length is 1.69 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(2), and one H(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cu(1) and one C(3) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(2) atom. Linkers: 4 Cc1n[nH]c(C)c1Cc1c(C)n[nH]c1C ,3 C[C@H]([N]C(=O)C(=O)[N][C@@H](C)C([O])=O)C([O])=O. Metal clusters: 8 [Cu]. The MOF has largest included sphere 5.25 A, density 1.26 g/cm3, surface area 4579.18 m2/g, accessible volume 0.36 cm3/g