SrHgC9N3H9S2O7 crystallizes in the triclinic P-1 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one N(3), one O(11), one O(13), one O(3), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. The Sr(1)-N(3) bond length is 2.78 Å. The Sr(1)-O(11) bond length is 2.57 Å. The Sr(1)-O(13) bond length is 2.79 Å. The Sr(1)-O(3) bond length is 2.85 Å. The Sr(1)-O(5) bond length is 2.55 Å. The Sr(1)-O(6) bond length is 2.80 Å. The Sr(1)-O(7) bond length is 2.54 Å. The Sr(1)-O(8) bond length is 2.70 Å. The Sr(1)-O(9) bond length is 2.67 Å. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one N(4), one O(10), one O(12), one O(14), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. The Sr(2)-N(4) bond length is 2.78 Å. The Sr(2)-O(10) bond length is 2.67 Å. The Sr(2)-O(12) bond length is 2.57 Å. The Sr(2)-O(14) bond length is 2.79 Å. The Sr(2)-O(4) bond length is 2.85 Å. The Sr(2)-O(5) bond length is 2.80 Å. The Sr(2)-O(6) bond length is 2.55 Å. The Sr(2)-O(7) bond length is 2.70 Å. The Sr(2)-O(8) bond length is 2.53 Å. There are two inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(5), one S(1), one S(4), and one O(1) atom. The Hg(1)-N(1) bond length is 2.38 Å. The Hg(1)-N(5) bond length is 2.45 Å. The Hg(1)-S(1) bond length is 2.55 Å. The Hg(1)-S(4) bond length is 2.50 Å. The Hg(1)-O(1) bond length is 2.58 Å. In the second Hg site, Hg(2) is bonded in a distorted trigonal bipyramidal geometry to one N(2), one N(6), one S(2), one S(3), and one O(2) atom. The Hg(2)-N(2) bond length is 2.38 Å. The Hg(2)-N(6) bond length is 2.45 Å. The Hg(2)-S(2) bond length is 2.55 Å. The Hg(2)-S(3) bond length is 2.50 Å. The Hg(2)-O(2) bond length is 2.58 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(3) atom. The C(1)-C(5) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(2), and one O(4) atom. The C(2)-C(6) bond length is 1.51 Å. The C(2)-O(2) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(5), and one O(7) atom. The C(3)-C(7) bond length is 1.51 Å. The C(3)-O(5) bond length is 1.27 Å. The C(3)-O(7) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(6), and one O(8) atom. The C(4)-C(8) bond length is 1.51 Å. The C(4)-O(6) bond length is 1.27 Å. The C(4)-O(8) bond length is 1.27 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(1), one C(7), and one N(1) atom. The C(5)-C(7) bond length is 1.40 Å. The C(5)-N(1) bond length is 1.35 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(2), one C(8), and one N(2) atom. The C(6)-C(8) bond length is 1.40 Å. The C(6)-N(2) bond length is 1.35 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(7)-C(9) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(6) atom. The C(8)-C(10) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(11), one C(7), and one H(13) atom. The C(9)-C(11) bond length is 1.39 Å. The C(9)-H(13) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one H(14) atom. The C(10)-C(12) bond length is 1.39 Å. The C(10)-H(14) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one H(15) atom. The C(11)-C(13) bond length is 1.39 Å. The C(11)-H(15) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(10), one C(14), and one H(16) atom. The C(12)-C(14) bond length is 1.39 Å. The C(12)-H(16) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one H(17) atom. The C(13)-N(1) bond length is 1.34 Å. The C(13)-H(17) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(18) atom. The C(14)-N(2) bond length is 1.34 Å. The C(14)-H(18) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted linear geometry to one N(3) and one S(1) atom. The C(15)-N(3) bond length is 1.18 Å. The C(15)-S(1) bond length is 1.65 Å. In the sixteenth C site, C(16) is bonded in a distorted linear geometry to one N(4) and one S(2) atom. The C(16)-N(4) bond length is 1.18 Å. The C(16)-S(2) bond length is 1.65 Å. In the seventeenth C site, C(17) is bonded in a distorted linear geometry to one N(5) and one S(3) atom. The C(17)-N(5) bond length is 1.18 Å. The C(17)-S(3) bond length is 1.65 Å. In the eighteenth C site, C(18) is bonded in a distorted linear geometry to one N(6) and one S(4) atom. The C(18)-N(6) bond length is 1.18 Å. The C(18)-S(4) bond length is 1.65 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Hg(1), one C(13), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Hg(2), one C(14), and one C(6) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one Sr(1) and one C(15) atom. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one Sr(2) and one C(16) atom. In the fifth N site, N(5) is bonded in a distorted bent 150 degrees geometry to one Hg(1) and one C(17) atom. In the sixth N site, N(6) is bonded in a distorted bent 150 degrees geometry to one Hg(2) and one C(18) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(9) atom. The H(1)-O(9) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. The H(2)-O(10) bond length is 0.98 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(3) and one O(9) atom. The H(3)-O(3) bond length is 1.64 Å. The H(3)-O(9) bond length is 1.01 Å. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(10) and one O(4) atom. The H(4)-O(10) bond length is 1.01 Å. The H(4)-O(4) bond length is 1.64 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(11) atom. The H(5)-O(11) bond length is 0.98 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(12) atom. The H(6)-O(12) bond length is 0.98 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(11) atom. The H(7)-O(11) bond length is 0.99 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(12) atom. The H(8)-O(12) bond length is 0.99 Å. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(13) atom. The H(9)-O(13) bond length is 0.99 Å. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(14) atom. The H(10)-O(14) bond length is 0.99 Å. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(13) atom. The H(11)-O(13) bond length is 0.99 Å. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(14) atom. The H(12)-O(14) bond length is 0.99 Å. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(14) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Hg(1) and one C(15) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Hg(2) and one C(16) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one Hg(2) and one C(17) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one Hg(1) and one C(18) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Hg(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Hg(2) and one C(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Sr(1), one C(1), and one H(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Sr(2), one C(2), and one H(4) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Sr(1), one Sr(2), and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Sr(1), one Sr(2), and one C(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Sr(1), one Sr(2), and one C(3) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Sr(1), one Sr(2), and one C(4) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Sr(1), one H(1), and one H(3) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Sr(2), one H(2), and one H(4) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Sr(1), one H(5), and one H(7) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one Sr(2), one H(6), and one H(8) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one Sr(1), one H(11), and one H(9) atom. In the fourteenth O site, O(14) is bonded in a water-like geometry to one Sr(2), one H(10), and one H(12) atom. Linkers: 4 [O]C(=O)c1cccnc1C([O])=O. Metal clusters: 4 [Sr] ,4 [Hg]. The MOF has largest included sphere 2.54 A, density 2.60 g/cm3, surface area 2655.53 m2/g, accessible volume 0.07 cm3/g