FePdH8(C3N)6(CH)3C3NH2O2C6H5NO2 crystallizes in the triclinic P-1 space group. The structure consists of six 02329_fluka molecules, two 2-nitropropene molecules, and two nitrobenzene molecules inside a FePdH8(C3N)6 framework. In the FePdH8(C3N)6 framework, there are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(6) atoms. Both Fe(1)-N(1) bond lengths are 2.15 Å. Both Fe(1)-N(2) bond lengths are 2.09 Å. Both Fe(1)-N(6) bond lengths are 2.09 Å. In the second Fe site, Fe(2) is bonded in an octahedral geometry to two equivalent N(3), two equivalent N(4), and two equivalent N(5) atoms. Both Fe(2)-N(3) bond lengths are 2.10 Å. Both Fe(2)-N(4) bond lengths are 2.10 Å. Both Fe(2)-N(5) bond lengths are 2.17 Å. Pd(1) is bonded in a rectangular see-saw-like geometry to one C(10), one C(11), one C(8), and one C(9) atom. The Pd(1)-C(10) bond length is 1.97 Å. The Pd(1)-C(11) bond length is 1.97 Å. The Pd(1)-C(8) bond length is 1.97 Å. The Pd(1)-C(9) bond length is 1.97 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a linear geometry to one C(3) and one C(7) atom. The C(6)-C(7) bond length is 1.23 Å. In the seventh C site, C(7) is bonded in a linear geometry to one C(18) and one C(6) atom. The C(7)-C(18) bond length is 1.34 Å. In the eighth C site, C(8) is bonded in a distorted linear geometry to one Pd(1) and one N(2) atom. The C(8)-N(2) bond length is 1.17 Å. In the ninth C site, C(9) is bonded in a linear geometry to one Pd(1) and one N(3) atom. The C(9)-N(3) bond length is 1.17 Å. In the tenth C site, C(10) is bonded in a linear geometry to one Pd(1) and one N(4) atom. The C(10)-N(4) bond length is 1.17 Å. In the eleventh C site, C(11) is bonded in a linear geometry to one Pd(1) and one N(6) atom. The C(11)-N(6) bond length is 1.17 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(5) atom. The C(12)-N(5) bond length is 1.35 Å. The C(12)-H(5) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(6) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-H(6) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-C(17) bond length is 1.41 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(7) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(7) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(5), and one H(8) atom. The C(16)-N(5) bond length is 1.35 Å. The C(16)-H(8) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a linear geometry to one C(14) and one C(18) atom. The C(17)-C(18) bond length is 1.23 Å. In the eighteenth C site, C(18) is bonded in a linear geometry to one C(17) and one C(7) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Fe(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Fe(1) and one C(8) atom. In the third N site, N(3) is bonded in a linear geometry to one Fe(2) and one C(9) atom. In the fourth N site, N(4) is bonded in a linear geometry to one Fe(2) and one C(10) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Fe(2), one C(12), and one C(16) atom. In the sixth N site, N(6) is bonded in a bent 150 degrees geometry to one Fe(1) and one C(11) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. Linkers: 2 C(C#Cc1ccncc1)#Cc1ccncc1. Metal clusters: 2 [Fe] ,2 [Pd]. The MOF has largest included sphere 2.89 A, density 1.54 g/cm3, surface area 4838.64 m2/g, accessible volume 0.16 cm3/g