AgC8N3H6O2CH2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two AgC8N3H6O2 clusters. In each AgC8N3H6O2 cluster, Ag(1) is bonded in a 4-coordinate geometry to one N(2), one N(3), one O(1), and one O(2) atom. The Ag(1)-N(2) bond length is 2.22 Å. The Ag(1)-N(3) bond length is 2.28 Å. The Ag(1)-O(1) bond length is 2.60 Å. The Ag(1)-O(2) bond length is 2.33 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.42 Å. The C(1)-N(1) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one N(3) atom. The C(6)-N(3) bond length is 1.37 Å. In the seventh C site, C(7) is bonded in a 3-coordinate geometry to one N(1), one H(5), and one H(6) atom. The C(7)-N(1) bond length is 1.46 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(9)-O(1) bond length is 1.27 Å. The C(9)-O(2) bond length is 1.28 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(1), one C(7), and one N(2) atom. The N(1)-N(2) bond length is 1.35 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one N(1), and one N(3) atom. The N(2)-N(3) bond length is 1.31 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(6), and one N(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ag(1) and one C(9) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Ag(1) and one C(9) atom. Linkers: 4 [O]C(=O)CCn1nnc2ccccc21. Metal clusters: 2 O=[C]O[Ag]1=NN=[Ag](O[C]=O)N=N1. The MOF has largest included sphere 2.54 A, density 2.06 g/cm3, surface area 3439.22 m2/g, accessible volume 0.14 cm3/g