AgH12(C3N)2AgH8(C2N)2AgC6N2H12SO3AgC4N2H8SO3(CH2)4(SO3)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two sulfur trioxide molecules, one AgC4N2H8SO3 cluster, one AgC6N2H12SO3 cluster, one AgH12(C3N)2 cluster, and one AgH8(C2N)2 cluster. In the AgC4N2H8SO3 cluster, Ag(3) is bonded in a distorted T-shaped geometry to one N(5), one N(7), and one O(5) atom. The Ag(3)-N(5) bond length is 2.12 Å. The Ag(3)-N(7) bond length is 2.13 Å. The Ag(3)-O(5) bond length is 2.65 Å. There are four inequivalent C sites. In the first C site, C(17) is bonded in a trigonal planar geometry to one N(5), one H(33), and one H(35) atom. The C(17)-N(5) bond length is 1.28 Å. The C(17)-H(33) bond length is 1.09 Å. The C(17)-H(35) bond length is 1.10 Å. In the second C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one N(5), one H(37), and one H(39) atom. The C(19)-N(5) bond length is 1.47 Å. The C(19)-H(37) bond length is 1.10 Å. The C(19)-H(39) bond length is 1.10 Å. In the third C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one N(7), one H(41), and one H(43) atom. The C(21)-N(7) bond length is 1.46 Å. The C(21)-H(41) bond length is 1.10 Å. The C(21)-H(43) bond length is 1.11 Å. In the fourth C site, C(23) is bonded in a trigonal planar geometry to one N(7), one H(45), and one H(47) atom. The C(23)-N(7) bond length is 1.28 Å. The C(23)-H(45) bond length is 1.09 Å. The C(23)-H(47) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one Ag(3), one C(17), and one C(19) atom. In the second N site, N(7) is bonded in a trigonal planar geometry to one Ag(3), one C(21), and one C(23) atom. There are eight inequivalent H sites. In the first H site, H(33) is bonded in a single-bond geometry to one C(17) atom. In the second H site, H(35) is bonded in a single-bond geometry to one C(17) atom. In the third H site, H(37) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(39) is bonded in a single-bond geometry to one C(19) atom. In the fifth H site, H(41) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(43) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(45) is bonded in a single-bond geometry to one C(23) atom. In the eighth H site, H(47) is bonded in a single-bond geometry to one C(23) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(3), and one O(5) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.48 Å. The S(1)-O(5) bond length is 1.48 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to one Ag(3) and one S(1) atom. In the AgC6N2H12SO3 cluster, Ag(2) is bonded in a distorted T-shaped geometry to one N(2), one N(4), and one O(8) atom. The Ag(2)-N(2) bond length is 2.19 Å. The Ag(2)-N(4) bond length is 2.21 Å. The Ag(2)-O(8) bond length is 2.61 Å. There are six inequivalent C sites. In the first C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(6), and one H(8) atom. The C(4)-N(2) bond length is 1.49 Å. The C(4)-H(6) bond length is 1.10 Å. The C(4)-H(8) bond length is 1.10 Å. In the second C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(10), and one H(12) atom. The C(6)-N(2) bond length is 1.48 Å. The C(6)-H(10) bond length is 1.10 Å. The C(6)-H(12) bond length is 1.10 Å. In the third C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(14), and one H(16) atom. The C(8)-N(2) bond length is 1.48 Å. The C(8)-H(14) bond length is 1.10 Å. The C(8)-H(16) bond length is 1.09 Å. In the fourth C site, C(12) is bonded in a 3-coordinate geometry to one N(4), one H(22), and one H(24) atom. The C(12)-N(4) bond length is 1.48 Å. The C(12)-H(22) bond length is 1.10 Å. The C(12)-H(24) bond length is 1.10 Å. In the fifth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(26), and one H(28) atom. The C(14)-N(4) bond length is 1.48 Å. The C(14)-H(26) bond length is 1.11 Å. The C(14)-H(28) bond length is 1.09 Å. In the sixth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(30), and one H(32) atom. The C(16)-N(4) bond length is 1.49 Å. The C(16)-H(30) bond length is 1.10 Å. The C(16)-H(32) bond length is 1.11 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded to one Ag(2), one C(4), one C(6), and one C(8) atom to form corner-sharing NAgC3 tetrahedra. In the second N site, N(4) is bonded to one Ag(2), one C(12), one C(14), and one C(16) atom to form corner-sharing NAgC3 tetrahedra. There are twelve inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(24) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(26) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(28) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(30) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(32) is bonded in a single-bond geometry to one C(16) atom. S(4) is bonded in a distorted trigonal non-coplanar geometry to one O(10), one O(12), and one O(8) atom. The S(4)-O(10) bond length is 1.47 Å. The S(4)-O(12) bond length is 1.47 Å. The S(4)-O(8) bond length is 1.48 Å. There are three inequivalent O sites. In the first O site, O(8) is bonded in a distorted single-bond geometry to one Ag(2) and one S(4) atom. In the second O site, O(10) is bonded in a single-bond geometry to one S(4) atom. In the third O site, O(12) is bonded in a single-bond geometry to one S(4) atom. In the AgH12(C3N)2 cluster, Ag(1) is bonded in a 2-coordinate geometry to one N(1) and one N(3) atom. The Ag(1)-N(1) bond length is 2.19 Å. The Ag(1)-N(3) bond length is 2.22 Å. There are six inequivalent C sites. In the first C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(5), and one H(7) atom. The C(3)-N(1) bond length is 1.49 Å. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(7) bond length is 1.10 Å. In the second C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(11), and one H(9) atom. The C(5)-N(1) bond length is 1.49 Å. The C(5)-H(11) bond length is 1.11 Å. The C(5)-H(9) bond length is 1.10 Å. In the third C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(13), and one H(15) atom. The C(7)-N(1) bond length is 1.48 Å. The C(7)-H(13) bond length is 1.11 Å. The C(7)-H(15) bond length is 1.09 Å. In the fourth C site, C(11) is bonded in a 3-coordinate geometry to one N(3), one H(21), and one H(23) atom. The C(11)-N(3) bond length is 1.49 Å. The C(11)-H(21) bond length is 1.10 Å. The C(11)-H(23) bond length is 1.10 Å. In the fifth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(25), and one H(27) atom. The C(13)-N(3) bond length is 1.48 Å. The C(13)-H(25) bond length is 1.11 Å. The C(13)-H(27) bond length is 1.09 Å. In the sixth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(29), and one H(31) atom. The C(15)-N(3) bond length is 1.49 Å. The C(15)-H(29) bond length is 1.10 Å. The C(15)-H(31) bond length is 1.11 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Ag(1), one C(3), one C(5), and one C(7) atom to form corner-sharing NAgC3 tetrahedra. In the second N site, N(3) is bonded to one Ag(1), one C(11), one C(13), and one C(15) atom to form corner-sharing NAgC3 tetrahedra. There are twelve inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(21) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(25) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(27) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(29) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(31) is bonded in a single-bond geometry to one C(15) atom. In the AgH8(C2N)2 cluster, Ag(4) is bonded in a distorted linear geometry to one N(6) and one N(8) atom. The Ag(4)-N(6) bond length is 2.12 Å. The Ag(4)-N(8) bond length is 2.12 Å. There are four inequivalent C sites. In the first C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(34), and one H(36) atom. The C(18)-N(6) bond length is 1.46 Å. The C(18)-H(34) bond length is 1.10 Å. The C(18)-H(36) bond length is 1.10 Å. In the second C site, C(20) is bonded in a trigonal planar geometry to one N(6), one H(38), and one H(40) atom. The C(20)-N(6) bond length is 1.28 Å. The C(20)-H(38) bond length is 1.10 Å. The C(20)-H(40) bond length is 1.09 Å. In the third C site, C(22) is bonded in a trigonal planar geometry to one N(8), one H(42), and one H(44) atom. The C(22)-N(8) bond length is 1.28 Å. The C(22)-H(42) bond length is 1.09 Å. The C(22)-H(44) bond length is 1.09 Å. In the fourth C site, C(24) is bonded in a distorted trigonal non-coplanar geometry to one N(8), one H(46), and one H(48) atom. The C(24)-N(8) bond length is 1.45 Å. The C(24)-H(46) bond length is 1.10 Å. The C(24)-H(48) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(6) is bonded in a trigonal planar geometry to one Ag(4), one C(18), and one C(20) atom. In the second N site, N(8) is bonded in a trigonal planar geometry to one Ag(4), one C(22), and one C(24) atom. There are eight inequivalent H sites. In the first H site, H(34) is bonded in a single-bond geometry to one C(18) atom. In the second H site, H(36) is bonded in a single-bond geometry to one C(18) atom. In the third H site, H(38) is bonded in a single-bond geometry to one C(20) atom. In the fourth H site, H(40) is bonded in a single-bond geometry to one C(20) atom. In the fifth H site, H(42) is bonded in a single-bond geometry to one C(22) atom. In the sixth H site, H(44) is bonded in a single-bond geometry to one C(22) atom. In the seventh H site, H(46) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(48) is bonded in a single-bond geometry to one C(24) atom. Linkers: 1 [H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[C][N]([Ag])([C])[CH].[C][N][C].O=S=O.[N][Ag].[N][Ag].O=S.O=S.O=S.O=S.[CH][CH2].[CH2][N].[CH2][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[S].[S].[S].[S].[S].[S].[S].[Ag].[Ag].[Ag].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH2].[CH2].[CH2] ,2 C=NCCN=C. Metal clusters: 2 [Ag]. RCSR code: hcb. The MOF has largest included sphere 2.86 A, density 2.05 g/cm3, surface area 3354.75 m2/g, accessible volume 0.16 cm3/g