CdC17N3H12O4(CH)4CH2(CH2CO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two 02329_fluka molecules, four dimethyl ether molecules, and one CdC17N3H12O4 cluster. In the CdC17N3H12O4 cluster, Cd(1) is bonded in a 7-coordinate geometry to one N(1), one N(3), one O(1), one O(2), one O(6), and two equivalent O(4) atoms. The Cd(1)-N(1) bond length is 2.29 Å. The Cd(1)-N(3) bond length is 2.47 Å. The Cd(1)-O(1) bond length is 2.47 Å. The Cd(1)-O(2) bond length is 2.32 Å. The Cd(1)-O(6) bond length is 2.63 Å. There is one shorter (2.34 Å) and one longer (2.38 Å) Cd(1)-O(4) bond length. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(2) bond length is 1.38 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one H(2) atom. The C(2)-N(1) bond length is 1.37 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted water-like geometry to one C(4), one N(1), and one N(2) atom. The C(3)-C(4) bond length is 1.47 Å. The C(3)-N(1) bond length is 1.34 Å. The C(3)-N(2) bond length is 1.37 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(3) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(3) bond length is 1.36 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(3) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(4) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one N(3), and one H(6) atom. The C(8)-N(3) bond length is 1.34 Å. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(1), and one O(2) atom. The C(9)-C(10) bond length is 1.49 Å. The C(9)-O(1) bond length is 1.27 Å. The C(9)-O(2) bond length is 1.29 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.41 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one H(10) atom. The C(15)-H(10) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(4), and one O(6) atom. The C(17)-C(18) bond length is 1.49 Å. The C(17)-O(4) bond length is 1.29 Å. The C(17)-O(6) bond length is 1.26 Å. In the fourteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(23) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-C(23) bond length is 1.40 Å. In the fifteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(13) atom. The C(19)-H(13) bond length is 1.09 Å. In the sixteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(16) atom. The C(23)-H(16) bond length is 1.09 Å. In the seventeenth C site, C(26) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(21), and one H(22) atom. The C(26)-N(2) bond length is 1.47 Å. The C(26)-H(21) bond length is 1.10 Å. The C(26)-H(22) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(26), and one C(3) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(4), and one C(8) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(26) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(9) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(9) atom. In the third O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one C(17) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one Cd(1) and one C(17) atom. Linkers: 2 [O]C(=O)c1ccc(OCCOc2ccc(C([O])=O)cc2)cc1 ,1 c1ccc(-c2nccn2CCCCn2ccnc2-c2ccccn2)nc1. Metal clusters: 1 O=[C]O[Cd]1O[C]O1.O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 4.46 A, density 1.36 g/cm3, surface area 4577.02 m2/g, accessible volume 0.22 cm3/g