TbAgC22H10(NO2)4(CH)2 crystallizes in the monoclinic C2/c space group. The structure consists of eight 02329_fluka molecules inside a TbAgC22H10(NO2)4 framework. In the TbAgC22H10(NO2)4 framework, Tb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), and four equivalent O(4) atoms. Both Tb(1)-O(1) bond lengths are 2.51 Å. Both Tb(1)-O(3) bond lengths are 2.21 Å. There are two shorter (2.34 Å) and two longer (2.47 Å) Tb(1)-O(4) bond lengths. Ag(1) is bonded in a linear geometry to two equivalent N(2) atoms. Both Ag(1)-N(2) bond lengths are 2.13 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(1), and one O(4) atom. The C(2)-C(8) bond length is 1.49 Å. The C(2)-O(1) bond length is 1.26 Å. The C(2)-O(4) bond length is 1.30 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(8) and one H(3) atom. The C(4)-C(8) bond length is 1.40 Å. The C(4)-H(3) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one N(2) atom. The C(5)-C(10) bond length is 1.50 Å. The C(5)-C(6) bond length is 1.41 Å. The C(5)-N(2) bond length is 1.35 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(5), and one C(7) atom. The C(6)-C(11) bond length is 1.51 Å. The C(6)-C(7) bond length is 1.40 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(12), one C(6), and one H(4) atom. The C(7)-C(12) bond length is 1.39 Å. The C(7)-H(4) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(4) atom. The C(8)-C(10) bond length is 1.41 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(2), and one H(5) atom. The C(9)-C(12) bond length is 1.39 Å. The C(9)-N(2) bond length is 1.35 Å. The C(9)-H(5) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(5), one C(8), and one N(1) atom. The C(10)-N(1) bond length is 1.35 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(2), and one O(3) atom. The C(11)-O(2) bond length is 1.24 Å. The C(11)-O(3) bond length is 1.29 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(6) atom. The C(12)-H(6) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(10) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(5), and one C(9) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Tb(1) and one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(11) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Tb(1) and one C(11) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Tb(1) and one C(2) atom. Linkers: 2 [C][C](c1ncccc1C([O])=O)N([CH])[Ag]N1[CH]C=CC(C([O])=O)=C1c1ncccc1C([O])=O ,1 [O]C(=O)C1=CC=CN([Ag]N2[CH]C=CC(C([O])=O)=C2c2ncccc2C([O])=O)[C]1c1ncccc1C([O])=O ,1 [O]C(=O)C1=CC=CN([Ag]N2C=CC=C(C([O])=O)[C]2c2ncccc2C([O])=O)[C]1c1ncccc1C([O])=O. Metal clusters: 2 [Tb]. The MOF has largest included sphere 2.00 A, density 2.28 g/cm3, surface area 2944.59 m2/g, accessible volume 0.06 cm3/g