Ag3C12H8(NO2)2AgC12H12S2(NO3)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Ag3C12H8(NO2)2 cluster and one AgC12H12S2(NO3)2 cluster. In the Ag3C12H8(NO2)2 cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(2) is bonded in a distorted linear geometry to one N(1) and one O(4) atom. The Ag(2)-N(1) bond length is 2.14 Å. The Ag(2)-O(4) bond length is 2.10 Å. In the second Ag site, Ag(3) is bonded in a linear geometry to two equivalent O(5) atoms. Both Ag(3)-O(5) bond lengths are 2.14 Å. There are six inequivalent C sites. In the first C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2,4) atom. The C(6)-N(1) bond length is 1.35 Å. The C(6)-H(2,4) bond length is 1.09 Å. In the second C site, C(7) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(8) atom. The C(7)-C(10) bond length is 1.40 Å. The C(7)-C(12) bond length is 1.50 Å. The C(7)-C(8) bond length is 1.40 Å. In the third C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(10)-H(7) bond length is 1.09 Å. In the fifth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(4), and one O(5) atom. The C(12)-O(4) bond length is 1.27 Å. The C(12)-O(5) bond length is 1.28 Å. In the sixth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2,4) atom. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(2,4) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Ag(2), one C(4), and one C(6) atom. There are three inequivalent H sites. In the first H site, H(2,4) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one Ag(3) and one C(12) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one C(12) atom. In the AgC12H12S2(NO3)2 cluster, Ag(1) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent O(1) atoms. Both Ag(1)-N(2) bond lengths are 2.26 Å. Both Ag(1)-O(1) bond lengths are 2.60 Å. There are six inequivalent C sites. In the first C site, C(5) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(5)-C(2) bond length is 1.40 Å. The C(5)-H(3) bond length is 1.09 Å. In the second C site, C(9) is bonded in a distorted single-bond geometry to one C(1) and one H(6) atom. The C(9)-C(1) bond length is 1.40 Å. The C(9)-H(6) bond length is 1.09 Å. In the third C site, C(11) is bonded in a distorted single-bond geometry to one C(1) and one H(8) atom. The C(11)-C(1) bond length is 1.39 Å. The C(11)-H(8) bond length is 1.09 Å. In the fourth C site, C(1) is bonded in a trigonal planar geometry to one C(11), one C(9), and one S(1) atom. The C(1)-S(1) bond length is 1.78 Å. In the fifth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-N(2) bond length is 1.40 Å. In the sixth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. N(2) is bonded in a 2-coordinate geometry to one Ag(1), one C(2), one H(10), and one H(9) atom. The N(2)-H(10) bond length is 1.04 Å. The N(2)-H(9) bond length is 1.04 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.49 Å. The S(1)-O(2) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.46 Å. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one S(1) atom. Linkers: 2 Nc1ccncc1 ,2 [O]C(=O)c1ccc(S([O])([O])[O])cc1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.85 A, density 2.51 g/cm3, surface area 2951.92 m2/g, accessible volume 0.07 cm3/g