CuC10N2H8O5(CH2)4(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, eight 02329_fluka molecules, and two CuC10N2H8O5 clusters. In each CuC10N2H8O5 cluster, Cu(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(2), and one O(4) atom. The Cu(1)-N(1) bond length is 2.01 Å. The Cu(1)-N(2) bond length is 2.03 Å. The Cu(1)-O(1) bond length is 2.28 Å. The Cu(1)-O(2) bond length is 2.02 Å. The Cu(1)-O(4) bond length is 1.98 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(1)-O(2) bond length is 1.29 Å. The C(1)-O(3) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(16), one C(6), and one N(2) atom. The C(2)-C(16) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.47 Å. The C(2)-N(2) bond length is 1.35 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one H(5) atom. The C(5)-C(7) bond length is 1.39 Å. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(5) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(15), one C(2), and one N(1) atom. The C(6)-C(15) bond length is 1.40 Å. The C(6)-N(1) bond length is 1.35 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(12) and one H(9) atom. The C(9)-C(12) bond length is 1.39 Å. The C(9)-H(9) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(10)-O(4) bond length is 1.30 Å. The C(10)-O(5) bond length is 1.26 Å. In the eighth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(11) atom. The C(12)-N(2) bond length is 1.34 Å. The C(12)-H(11) bond length is 1.09 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(6) and one H(15) atom. The C(15)-H(15) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(2) and one H(16) atom. The C(16)-H(16) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(5), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(12), and one C(2) atom. There are eight inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(17) is bonded in a distorted single-bond geometry to one O(1) and one O(5) atom. The H(17)-O(1) bond length is 1.01 Å. The H(17)-O(5) bond length is 1.62 Å. In the eighth H site, H(18) is bonded in a single-bond geometry to one O(1) atom. The H(18)-O(1) bond length is 0.99 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cu(1), one H(17), and one H(18) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(10) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(10) and one H(17) atom. Linkers: 2 [O]C(=O)CCCCC([O])=O. Metal clusters: 2 O.O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 2.64 A, density 1.58 g/cm3, surface area 4400.28 m2/g, accessible volume 0.18 cm3/g