CuC8H9SICH3CHO is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four dimethyl ether molecules and one CuC8H9SI cluster. In the CuC8H9SI cluster, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 4-coordinate geometry to one Cu(3), one S(1), one I(1), one I(3), and one I(4) atom. The Cu(1)-Cu(3) bond length is 2.61 Å. The Cu(1)-S(1) bond length is 2.28 Å. The Cu(1)-I(1) bond length is 2.66 Å. The Cu(1)-I(3) bond length is 2.78 Å. The Cu(1)-I(4) bond length is 2.70 Å. In the second Cu site, Cu(2) is bonded in a 4-coordinate geometry to one Cu(3), one S(2), one I(2), one I(3), and one I(4) atom. The Cu(2)-Cu(3) bond length is 2.60 Å. The Cu(2)-S(2) bond length is 2.27 Å. The Cu(2)-I(2) bond length is 2.65 Å. The Cu(2)-I(3) bond length is 2.71 Å. The Cu(2)-I(4) bond length is 2.78 Å. In the third Cu site, Cu(3) is bonded in a 7-coordinate geometry to one Cu(1), one Cu(2), one Cu(4), one S(3), one I(1), one I(2), and one I(3) atom. The Cu(3)-Cu(4) bond length is 2.61 Å. The Cu(3)-S(3) bond length is 2.27 Å. The Cu(3)-I(1) bond length is 2.71 Å. The Cu(3)-I(2) bond length is 2.80 Å. The Cu(3)-I(3) bond length is 2.65 Å. In the fourth Cu site, Cu(4) is bonded in a 4-coordinate geometry to one Cu(3), one S(4), one I(1), one I(2), and one I(4) atom. The Cu(4)-S(4) bond length is 2.28 Å. The Cu(4)-I(1) bond length is 2.78 Å. The Cu(4)-I(2) bond length is 2.71 Å. The Cu(4)-I(4) bond length is 2.66 Å. There are thirty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(21), one C(5), and one H(1) atom. The C(1)-C(21) bond length is 1.40 Å. The C(1)-C(5) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(22), one C(6), and one H(2) atom. The C(2)-C(22) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(23), one C(7), and one H(3) atom. The C(3)-C(23) bond length is 1.40 Å. The C(3)-C(7) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(24), one C(8), and one H(4) atom. The C(4)-C(24) bond length is 1.40 Å. The C(4)-C(8) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(1), one C(9), and one H(5) atom. The C(5)-C(9) bond length is 1.40 Å. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(10), one C(2), and one H(6) atom. The C(6)-C(10) bond length is 1.40 Å. The C(6)-H(6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(11), one C(3), and one H(7) atom. The C(7)-C(11) bond length is 1.40 Å. The C(7)-H(7) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(12), one C(4), and one H(8) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-H(8) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(13), one C(5), and one H(9) atom. The C(9)-C(13) bond length is 1.40 Å. The C(9)-H(9) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(14), one C(6), and one H(10) atom. The C(10)-C(14) bond length is 1.40 Å. The C(10)-H(10) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(15), one C(7), and one H(11) atom. The C(11)-C(15) bond length is 1.40 Å. The C(11)-H(11) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(16), one C(8), and one H(12) atom. The C(12)-C(16) bond length is 1.40 Å. The C(12)-H(12) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(17), one C(9), and one H(13) atom. The C(13)-C(17) bond length is 1.40 Å. The C(13)-H(13) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(10); one C(18); and one H(14,15) atom. The C(14)-C(18) bond length is 1.39 Å. The C(14)-H(14,15) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(11); one C(19); and one H(14,15) atom. The C(15)-C(19) bond length is 1.39 Å. The C(15)-H(14,15) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(12), one C(20), and one H(16) atom. The C(16)-C(20) bond length is 1.39 Å. The C(16)-H(16) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(13), one C(21), and one H(17) atom. The C(17)-C(21) bond length is 1.40 Å. The C(17)-H(17) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(14), one C(22), and one H(18) atom. The C(18)-C(22) bond length is 1.40 Å. The C(18)-H(18) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(15), one C(23), and one H(19) atom. The C(19)-C(23) bond length is 1.40 Å. The C(19)-H(19) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(16), one C(24), and one H(20) atom. The C(20)-C(24) bond length is 1.40 Å. The C(20)-H(20) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(1), one C(17), and one C(25) atom. The C(21)-C(25) bond length is 1.50 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(18), one C(2), and one C(26) atom. The C(22)-C(26) bond length is 1.50 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(19), one C(27), and one C(3) atom. The C(23)-C(27) bond length is 1.50 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(20), one C(28), and one C(4) atom. The C(24)-C(28) bond length is 1.50 Å. In the twenty-fifth C site, C(25) is bonded in a distorted water-like geometry to one C(21), one H(21), one H(25), and one S(1) atom. The C(25)-H(21) bond length is 1.10 Å. The C(25)-H(25) bond length is 1.10 Å. The C(25)-S(1) bond length is 1.82 Å. In the twenty-sixth C site, C(26) is bonded in a distorted water-like geometry to one C(22), one H(22), one H(26), and one S(2) atom. The C(26)-H(22) bond length is 1.10 Å. The C(26)-H(26) bond length is 1.10 Å. The C(26)-S(2) bond length is 1.82 Å. In the twenty-seventh C site, C(27) is bonded in a distorted water-like geometry to one C(23), one H(23), one H(27), and one S(3) atom. The C(27)-H(23) bond length is 1.10 Å. The C(27)-H(27) bond length is 1.10 Å. The C(27)-S(3) bond length is 1.83 Å. In the twenty-eighth C site, C(28) is bonded in a distorted water-like geometry to one C(24), one H(24), one H(28), and one S(4) atom. The C(28)-H(24) bond length is 1.10 Å. The C(28)-H(28) bond length is 1.10 Å. The C(28)-S(4) bond length is 1.82 Å. In the twenty-ninth C site, C(29) is bonded in a distorted water-like geometry to one H(29), one H(33), and one S(1) atom. The C(29)-H(29) bond length is 1.10 Å. The C(29)-H(33) bond length is 1.10 Å. The C(29)-S(1) bond length is 1.82 Å. In the thirtieth C site, C(30) is bonded in a distorted water-like geometry to one H(30), one H(34), and one S(2) atom. The C(30)-H(30) bond length is 1.10 Å. The C(30)-H(34) bond length is 1.10 Å. The C(30)-S(2) bond length is 1.82 Å. In the thirty-first C site, C(31) is bonded in a distorted water-like geometry to one H(31), one H(35), and one S(3) atom. The C(31)-H(31) bond length is 1.10 Å. The C(31)-H(35) bond length is 1.10 Å. The C(31)-S(3) bond length is 1.82 Å. In the thirty-second C site, C(32) is bonded in a distorted water-like geometry to one H(32), one H(36), and one S(4) atom. The C(32)-H(32) bond length is 1.10 Å. The C(32)-H(36) bond length is 1.10 Å. The C(32)-S(4) bond length is 1.82 Å. There are thirty-five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the fourteenth H site, H(14,15) is bonded in a single-bond geometry to one C(14) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the twentieth H site, H(21) is bonded in a single-bond geometry to one C(25) atom. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one C(26) atom. In the twenty-second H site, H(23) is bonded in a single-bond geometry to one C(27) atom. In the twenty-third H site, H(24) is bonded in a single-bond geometry to one C(28) atom. In the twenty-fourth H site, H(25) is bonded in a single-bond geometry to one C(25) atom. In the twenty-fifth H site, H(26) is bonded in a single-bond geometry to one C(26) atom. In the twenty-sixth H site, H(27) is bonded in a single-bond geometry to one C(27) atom. In the twenty-seventh H site, H(28) is bonded in a single-bond geometry to one C(28) atom. In the twenty-eighth H site, H(29) is bonded in a single-bond geometry to one C(29) atom. In the twenty-ninth H site, H(30) is bonded in a single-bond geometry to one C(30) atom. In the thirtieth H site, H(31) is bonded in a single-bond geometry to one C(31) atom. In the thirty-first H site, H(32) is bonded in a single-bond geometry to one C(32) atom. In the thirty-second H site, H(33) is bonded in a single-bond geometry to one C(29) atom. In the thirty-third H site, H(34) is bonded in a single-bond geometry to one C(30) atom. In the thirty-fourth H site, H(35) is bonded in a single-bond geometry to one C(31) atom. In the thirty-fifth H site, H(36) is bonded in a single-bond geometry to one C(32) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(25), and one C(29) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Cu(2), one C(26), and one C(30) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Cu(3), one C(27), and one C(31) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Cu(4), one C(28), and one C(32) atom. There are four inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(3), and one Cu(4) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one Cu(2), one Cu(3), and one Cu(4) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(2), and one Cu(3) atom. In the fourth I site, I(4) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(2), and one Cu(4) atom. Linkers: 2 [CH]=C/C=[C]/[CH]SCCOCCOCCSCc1ccccc1 ,2 c1ccc(CSCCOCCOCCSCc2ccccc2)cc1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 3.58 A, density 1.98 g/cm3, surface area 3692.90 m2/g, accessible volume 0.17 cm3/g