CuC6NH8I(CH)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and two CuC6NH8I clusters. In each CuC6NH8I cluster, Cu(1) is bonded in a distorted single-bond geometry to one N(1) and two equivalent I(1) atoms. The Cu(1)-N(1) bond length is 2.05 Å. There is one shorter (2.57 Å) and one longer (2.58 Å) Cu(1)-I(1) bond length. There are six inequivalent C sites. In the first C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(7) atom. The C(5)-C(4) bond length is 1.40 Å. The C(5)-H(7) bond length is 1.09 Å. In the second C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(4)-C(3) bond length is 1.50 Å. The C(4)-C(9) bond length is 1.40 Å. In the third C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(1)-N(1) bond length is 1.48 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.11 Å. In the fourth C site, C(9) is bonded in a distorted single-bond geometry to one C(4) and one H(11) atom. The C(9)-H(11) bond length is 1.09 Å. In the fifth C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(3), and one H(4) atom. The C(2)-N(1) bond length is 1.48 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.11 Å. In the sixth C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one N(1), one H(5), and one H(6) atom. The C(3)-N(1) bond length is 1.49 Å. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(6) bond length is 1.10 Å. N(1) is bonded in a tetrahedral geometry to one Cu(1), one C(1), one C(2), and one C(3) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 2 [c]1[c]c(CN2CCN(Cc3ccccc3)CC2)ccc1 ,2 c1ccc(CN2CCN(Cc3ccccc3)CC2)cc1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 1.95 A, density 2.22 g/cm3, surface area 3498.56 m2/g, accessible volume 0.12 cm3/g