ZnC20N4H8(O3F2)2 is Indium-like structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two ZnC20N4H8(O3F2)2 clusters. Zn(1) is bonded in a tetrahedral geometry to two equivalent N(2) and two equivalent O(1) atoms. Both Zn(1)-N(2) bond lengths are 2.02 Å. Both Zn(1)-O(1) bond lengths are 2.01 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(2) atom. The C(2)-C(5) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one H(3) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-N(2) bond length is 1.35 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.41 Å. In the sixth C site, C(6) is bonded in a linear geometry to one C(5) and one C(7) atom. The C(6)-C(7) bond length is 1.22 Å. In the seventh C site, C(7) is bonded in a linear geometry to one C(6) and one C(8) atom. The C(7)-C(8) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.41 Å. The C(8)-C(9) bond length is 1.41 Å. In the ninth C site, C(9) is bonded in a single-bond geometry to one C(8) and one F(1) atom. The C(9)-F(1) bond length is 1.35 Å. In the tenth C site, C(10) is bonded in a single-bond geometry to one C(8) and one F(2) atom. The C(10)-F(2) bond length is 1.35 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(1)-O(1) bond length is 1.32 Å. The N(1)-O(2) bond length is 1.24 Å. The N(1)-O(3) bond length is 1.26 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(3) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(9) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(10) atom. Linkers: 4 [CH]=CC(=[CH])C#Cc1c(F)c(F)c(C#Cc2ccncc2)c(F)c1F ,4 F[C]/C(=[C]/F)C#Cc1ccncc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.57 A, density 1.75 g/cm3, surface area 4232.17 m2/g, accessible volume 0.12 cm3/g