(CH)14PbC4H6(NO2)2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two isobutylene molecules, and one PbC4H6(NO2)2 cluster. In the PbC4H6(NO2)2 cluster, Pb(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Pb(1)-N(1) bond length is 2.53 Å. The Pb(1)-N(2) bond length is 2.53 Å. The Pb(1)-O(1) bond length is 2.43 Å. The Pb(1)-O(2) bond length is 2.43 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(2)-O(2) bond length is 1.28 Å. The C(2)-O(4) bond length is 1.26 Å. In the third C site, C(3,4) is bonded in a distorted water-like geometry to one N(1) and one H(5,6) atom. The C(3,4)-N(1) bond length is 1.47 Å. The C(3,4)-H(5,6) bond length is 1.11 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pb(1); one C(3,4); one H(1,2); and one H(3,4) atom. The N(1)-H(1,2) bond length is 1.03 Å. The N(1)-H(3,4) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Pb(1); one C(3,4); one H(1,2); and one H(3,4) atom. The N(2)-C(3,4) bond length is 1.47 Å. The N(2)-H(1,2) bond length is 1.03 Å. The N(2)-H(3,4) bond length is 1.03 Å. There are three inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(3,4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pb(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Pb(1) and one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(2) atom. Linkers: 2 N[C@@H](Cc1ccccc1)C([O])=O. Metal clusters: 1 [Pb]. The MOF has largest included sphere 1.85 A, density 2.09 g/cm3, surface area 3553.02 m2/g, accessible volume 0.12 cm3/g