CHCdC32N4H25SO5 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a CdC32N4H25SO5 framework. In the CdC32N4H25SO5 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to two equivalent N(1), two equivalent N(3), and two equivalent O(1) atoms to form CdN4O2 octahedra that share corners with two equivalent S(1)O4 tetrahedra. Both Cd(1)-N(1) bond lengths are 2.37 Å. Both Cd(1)-N(3) bond lengths are 2.37 Å. Both Cd(1)-O(1) bond lengths are 2.32 Å. In the second Cd site, Cd(2) is bonded to two equivalent N(2), two equivalent O(2), and two equivalent O(5) atoms to form CdN2O4 octahedra that share corners with two equivalent S(1)O4 tetrahedra. Both Cd(2)-N(2) bond lengths are 2.33 Å. Both Cd(2)-O(2) bond lengths are 2.28 Å. Both Cd(2)-O(5) bond lengths are 2.44 Å. There are thirty-two inequivalent C sites. In the first C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(7) atom. The C(6)-C(11) bond length is 1.41 Å. The C(6)-C(3) bond length is 1.47 Å. The C(6)-C(7) bond length is 1.41 Å. In the second C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the third C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one N(4) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-N(4) bond length is 1.41 Å. In the fourth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(7) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(7) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one H(8) atom. The C(11)-H(8) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(2), and one H(9) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(9) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(10) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-H(10) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-C(17) bond length is 1.47 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(15)-H(11) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(16)-N(2) bond length is 1.34 Å. The C(16)-H(12) bond length is 1.09 Å. In the eleventh C site, C(17) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(22) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-C(22) bond length is 1.41 Å. In the twelfth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(13) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(13) bond length is 1.09 Å. In the thirteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(14) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(14) bond length is 1.09 Å. In the fourteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one N(4) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-N(4) bond length is 1.41 Å. In the fifteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one H(15) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(15) bond length is 1.09 Å. In the sixteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(17), one C(21), and one H(16) atom. The C(22)-H(16) bond length is 1.09 Å. In the seventeenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(23)-N(3) bond length is 1.35 Å. The C(23)-H(17) bond length is 1.09 Å. In the eighteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(18) atom. The C(24)-C(25) bond length is 1.41 Å. The C(24)-H(18) bond length is 1.09 Å. In the nineteenth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(28) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(28) bond length is 1.47 Å. In the twentieth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one C(27), and one H(19) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-H(19) bond length is 1.09 Å. In the twenty-first C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(26), one N(3), and one H(20) atom. The C(27)-N(3) bond length is 1.34 Å. The C(27)-H(20) bond length is 1.09 Å. In the twenty-second C site, C(28) is bonded in a trigonal planar geometry to one C(25), one C(29), and one C(33) atom. The C(28)-C(29) bond length is 1.41 Å. The C(28)-C(33) bond length is 1.41 Å. In the twenty-third C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one C(30), and one H(21) atom. The C(29)-C(30) bond length is 1.39 Å. The C(29)-H(21) bond length is 1.09 Å. In the twenty-fourth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one C(31), and one H(22) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-H(22) bond length is 1.09 Å. In the twenty-fifth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(30), one C(32), and one N(4) atom. The C(31)-C(32) bond length is 1.40 Å. The C(31)-N(4) bond length is 1.42 Å. In the twenty-sixth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31), one C(33), and one H(23) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-H(23) bond length is 1.09 Å. In the twenty-seventh C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the twenty-eighth C site, C(33) is bonded in a distorted trigonal planar geometry to one C(28), one C(32), and one H(24) atom. The C(33)-H(24) bond length is 1.09 Å. In the twenty-ninth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the thirtieth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. In the thirty-first C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the thirty-second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one C(20), one C(31), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(2), one C(12), and one C(16) atom. In the third N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(23), and one C(27) atom. There are twenty-five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(26) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(27) atom. In the twentieth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one C(30) atom. In the twenty-second H site, H(23) is bonded in a single-bond geometry to one C(32) atom. In the twenty-third H site, H(24) is bonded in a single-bond geometry to one C(33) atom. In the twenty-fourth H site, H(25) is bonded in a single-bond geometry to one O(5) atom. The H(25)-O(5) bond length is 0.97 Å. In the twenty-fifth H site, H(26) is bonded in a distorted single-bond geometry to one O(3) and one O(5) atom. The H(26)-O(3) bond length is 1.56 Å. The H(26)-O(5) bond length is 1.03 Å. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(2)N2O4 octahedra and  a cornercorner with one Cd(1)N4O2 octahedra. The corner-sharing octahedral tilt angles range from 43-54°. The S(1)-O(1) bond length is 1.51 Å. The S(1)-O(2) bond length is 1.52 Å. The S(1)-O(3) bond length is 1.49 Å. The S(1)-O(4) bond length is 1.47 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cd(2) and one S(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one H(26) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Cd(2), one H(25), and one H(26) atom. Linkers: 4 c1cc(-c2ccc(N(c3ccc(-c4ccncc4)cc3)c3ccc(-c4ccncc4)cc3)cc2)ccn1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 7.11 A, density 0.80 g/cm3, surface area 4725.34 m2/g, accessible volume 0.68 cm3/g