MoCu2C32H40(N2O)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one MoCu2C32H40(N2O)4 cluster. Mo(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form MoO4 tetrahedra that share corners with two equivalent Cu(2)N2O2 trigonal pyramids. The Mo(1)-O(1) bond length is 1.81 Å. The Mo(1)-O(2) bond length is 1.77 Å. The Mo(1)-O(3) bond length is 1.77 Å. The Mo(1)-O(4) bond length is 1.80 Å. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a T-shaped geometry to one N(2), one N(8), and one O(4) atom. The Cu(1)-N(2) bond length is 1.91 Å. The Cu(1)-N(8) bond length is 1.91 Å. The Cu(1)-O(4) bond length is 2.08 Å. In the second Cu site, Cu(2) is bonded to one N(1), one N(5), and two equivalent O(1) atoms to form CuN2O2 trigonal pyramids that share corners with two equivalent Mo(1)O4 tetrahedra and  an edgeedge with one Cu(2)N2O2 trigonal pyramid. The Cu(2)-N(1) bond length is 1.92 Å. The Cu(2)-N(5) bond length is 1.92 Å. There is one shorter (2.14 Å) and one longer (2.17 Å) Cu(2)-O(1) bond length. There are thirty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(1)-C(3) bond length is 1.40 Å. The C(1)-C(5) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.51 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(5), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-N(5) bond length is 1.35 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(2), and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one N(5) and one H(3) atom. The C(4)-N(5) bond length is 1.35 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one N(3), one H(5), and one H(6) atom. The C(6)-N(3) bond length is 1.46 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.11 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(3); one H(7,12); and one H(8) atom. The C(7)-N(3) bond length is 1.46 Å. The C(7)-H(7,12) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.11 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(10), and one H(9) atom. The C(8)-N(4) bond length is 1.46 Å. The C(8)-H(10) bond length is 1.11 Å. The C(8)-H(9) bond length is 1.10 Å. In the ninth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(3); one H(11); and one H(7,12) atom. The C(9)-N(3) bond length is 1.46 Å. The C(9)-H(11) bond length is 1.11 Å. The C(9)-H(7,12) bond length is 1.10 Å. In the tenth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(13), and one H(14) atom. The C(10)-N(4) bond length is 1.46 Å. The C(10)-H(13) bond length is 1.11 Å. The C(10)-H(14) bond length is 1.10 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one C(12), one N(4), one H(15), and one H(16) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-N(4) bond length is 1.46 Å. The C(11)-H(15) bond length is 1.11 Å. The C(11)-H(16) bond length is 1.10 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(15) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(15) bond length is 1.40 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(17) atom. The C(13)-H(17) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(18) atom. The C(14)-N(1) bond length is 1.35 Å. The C(14)-H(18) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one H(19) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(19) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one N(1), and one H(20) atom. The C(16)-N(1) bond length is 1.36 Å. The C(16)-H(20) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(18), one N(2), and one H(21) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-N(2) bond length is 1.36 Å. The C(17)-H(21) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(21), and one H(22) atom. The C(18)-C(21) bond length is 1.40 Å. The C(18)-H(22) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(23) atom. The C(19)-N(2) bond length is 1.35 Å. The C(19)-H(23) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(24) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(24) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(22) atom. The C(21)-C(22) bond length is 1.50 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal non-coplanar geometry to one C(21), one N(6), one H(25), and one H(26) atom. The C(22)-N(6) bond length is 1.47 Å. The C(22)-H(25) bond length is 1.10 Å. The C(22)-H(26) bond length is 1.11 Å. In the twenty-third C site, C(23) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(27), and one H(28) atom. The C(23)-N(6) bond length is 1.47 Å. The C(23)-H(27) bond length is 1.10 Å. The C(23)-H(28) bond length is 1.11 Å. In the twenty-fourth C site, C(24) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(29), and one H(30) atom. The C(24)-N(6) bond length is 1.46 Å. The C(24)-H(29) bond length is 1.11 Å. The C(24)-H(30) bond length is 1.10 Å. In the twenty-fifth C site, C(25) is bonded in a distorted trigonal non-coplanar geometry to one N(7), one H(31), and one H(32) atom. The C(25)-N(7) bond length is 1.46 Å. The C(25)-H(31) bond length is 1.12 Å. The C(25)-H(32) bond length is 1.10 Å. In the twenty-sixth C site, C(26) is bonded in a distorted trigonal non-coplanar geometry to one N(7), one H(33), and one H(34) atom. The C(26)-N(7) bond length is 1.46 Å. The C(26)-H(33) bond length is 1.10 Å. The C(26)-H(34) bond length is 1.11 Å. In the twenty-seventh C site, C(27) is bonded in a distorted trigonal non-coplanar geometry to one C(28), one N(7), one H(35), and one H(36) atom. The C(27)-C(28) bond length is 1.50 Å. The C(27)-N(7) bond length is 1.46 Å. The C(27)-H(35) bond length is 1.11 Å. The C(27)-H(36) bond length is 1.10 Å. In the twenty-eighth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(30) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-C(30) bond length is 1.40 Å. In the twenty-ninth C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(37) atom. The C(29)-H(37) bond length is 1.09 Å. In the thirtieth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(28), one C(31), and one H(38) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-H(38) bond length is 1.09 Å. In the thirty-first C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(30), one N(8), and one H(39) atom. The C(31)-N(8) bond length is 1.36 Å. The C(31)-H(39) bond length is 1.09 Å. In the thirty-second C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(40) atom. The C(32)-N(8) bond length is 1.36 Å. The C(32)-H(40) bond length is 1.09 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(2), one C(14), and one C(16) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(17), and one C(19) atom. In the third N site, N(3) is bonded in a trigonal non-coplanar geometry to one C(6), one C(7), and one C(9) atom. In the fourth N site, N(4) is bonded in a trigonal non-coplanar geometry to one C(10), one C(11), and one C(8) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(2), one C(2), and one C(4) atom. In the sixth N site, N(6) is bonded in a trigonal non-coplanar geometry to one C(22), one C(23), and one C(24) atom. In the seventh N site, N(7) is bonded in a trigonal non-coplanar geometry to one C(25), one C(26), and one C(27) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Cu(1), one C(31), and one C(32) atom. There are thirty-nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7,12) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(11) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(14) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(15) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(16) atom. In the twentieth H site, H(21) is bonded in a single-bond geometry to one C(17) atom. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one C(18) atom. In the twenty-second H site, H(23) is bonded in a single-bond geometry to one C(19) atom. In the twenty-third H site, H(24) is bonded in a single-bond geometry to one C(20) atom. In the twenty-fourth H site, H(25) is bonded in a single-bond geometry to one C(22) atom. In the twenty-fifth H site, H(26) is bonded in a single-bond geometry to one C(22) atom. In the twenty-sixth H site, H(27) is bonded in a single-bond geometry to one C(23) atom. In the twenty-seventh H site, H(28) is bonded in a single-bond geometry to one C(23) atom. In the twenty-eighth H site, H(29) is bonded in a single-bond geometry to one C(24) atom. In the twenty-ninth H site, H(30) is bonded in a single-bond geometry to one C(24) atom. In the thirtieth H site, H(31) is bonded in a single-bond geometry to one C(25) atom. In the thirty-first H site, H(32) is bonded in a single-bond geometry to one C(25) atom. In the thirty-second H site, H(33) is bonded in a single-bond geometry to one C(26) atom. In the thirty-third H site, H(34) is bonded in a single-bond geometry to one C(26) atom. In the thirty-fourth H site, H(35) is bonded in a single-bond geometry to one C(27) atom. In the thirty-fifth H site, H(36) is bonded in a single-bond geometry to one C(27) atom. In the thirty-sixth H site, H(37) is bonded in a single-bond geometry to one C(29) atom. In the thirty-seventh H site, H(38) is bonded in a single-bond geometry to one C(30) atom. In the thirty-eighth H site, H(39) is bonded in a single-bond geometry to one C(31) atom. In the thirty-ninth H site, H(40) is bonded in a single-bond geometry to one C(32) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Mo(1) and two equivalent Cu(2) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mo(1) and one Cu(1) atom. Linkers: 4 c1cc(CN2CCN(Cc3ccncc3)CC2)ccn1. Metal clusters: 1 [O][Mo]([O])(O[Cu])O[Cu][Cu]O[Mo]([O])([O])O[Cu]. The MOF has largest included sphere 3.79 A, density 1.50 g/cm3, surface area 4461.16 m2/g, accessible volume 0.19 cm3/g