Zn2C24N5H22O13CH crystallizes in the triclinic P1 space group. The structure consists of two 02329_fluka molecules inside a Zn2C24N5H22O13 framework. In the Zn2C24N5H22O13 framework, there are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in an octahedral geometry to one N(1), one N(9), one O(1), one O(11), one O(8), and one O(9) atom. The Zn(1)-N(1) bond length is 2.13 Å. The Zn(1)-N(9) bond length is 2.23 Å. The Zn(1)-O(1) bond length is 2.18 Å. The Zn(1)-O(11) bond length is 2.17 Å. The Zn(1)-O(8) bond length is 2.09 Å. The Zn(1)-O(9) bond length is 2.08 Å. In the second Zn site, Zn(2) is bonded in an octahedral geometry to one N(10), one N(2), one O(10), one O(12), one O(2), and one O(7) atom. The Zn(2)-N(10) bond length is 2.23 Å. The Zn(2)-N(2) bond length is 2.13 Å. The Zn(2)-O(10) bond length is 2.08 Å. The Zn(2)-O(12) bond length is 2.17 Å. The Zn(2)-O(2) bond length is 2.18 Å. The Zn(2)-O(7) bond length is 2.09 Å. In the third Zn site, Zn(3) is bonded in an octahedral geometry to one N(3), one N(5), one O(13), one O(20), one O(21), and one O(23) atom. The Zn(3)-N(3) bond length is 2.13 Å. The Zn(3)-N(5) bond length is 2.24 Å. The Zn(3)-O(13) bond length is 2.19 Å. The Zn(3)-O(20) bond length is 2.10 Å. The Zn(3)-O(21) bond length is 2.08 Å. The Zn(3)-O(23) bond length is 2.14 Å. In the fourth Zn site, Zn(4) is bonded in an octahedral geometry to one N(4), one N(6), one O(14), one O(19), one O(22), and one O(24) atom. The Zn(4)-N(4) bond length is 2.13 Å. The Zn(4)-N(6) bond length is 2.24 Å. The Zn(4)-O(14) bond length is 2.19 Å. The Zn(4)-O(19) bond length is 2.10 Å. The Zn(4)-O(22) bond length is 2.08 Å. The Zn(4)-O(24) bond length is 2.14 Å. There are forty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(5), and one O(7) atom. The C(1)-C(3) bond length is 1.51 Å. The C(1)-O(5) bond length is 1.27 Å. The C(1)-O(7) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(6), and one O(8) atom. The C(2)-C(4) bond length is 1.51 Å. The C(2)-O(6) bond length is 1.27 Å. The C(2)-O(8) bond length is 1.27 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1); one C(11,12); and one C(5,6) atom. The C(3)-C(11,12) bond length is 1.40 Å. The C(3)-C(5,6) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(11,12); one C(2); and one C(5,6) atom. The C(4)-C(11,12) bond length is 1.40 Å. The C(4)-C(5,6) bond length is 1.40 Å. In the fifth C site, C(5,6) is bonded in a distorted trigonal planar geometry to one C(3); one C(7); and one H(19,20) atom. The C(5,6)-C(7) bond length is 1.39 Å. The C(5,6)-H(19,20) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5,6); one N(1); and one H(21,22) atom. The C(7)-N(1) bond length is 1.35 Å. The C(7)-H(21,22) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(5,6); one N(2); and one H(21,22) atom. The C(8)-C(5,6) bond length is 1.39 Å. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(21,22) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(13); and one N(1) atom. The C(9)-C(11,12) bond length is 1.39 Å. The C(9)-C(13) bond length is 1.51 Å. The C(9)-N(1) bond length is 1.35 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(14); and one N(2) atom. The C(10)-C(11,12) bond length is 1.39 Å. The C(10)-C(14) bond length is 1.51 Å. The C(10)-N(2) bond length is 1.35 Å. In the tenth C site, C(11,12) is bonded in a distorted single-bond geometry to one C(3), one C(9), and one H(23) atom. The C(11,12)-H(23) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(1), and one O(3) atom. The C(13)-O(1) bond length is 1.28 Å. The C(13)-O(3) bond length is 1.26 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(2), and one O(4) atom. The C(14)-O(2) bond length is 1.28 Å. The C(14)-O(4) bond length is 1.26 Å. In the thirteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(17), and one O(19) atom. The C(15)-C(17) bond length is 1.51 Å. The C(15)-O(17) bond length is 1.28 Å. The C(15)-O(19) bond length is 1.27 Å. In the fourteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(18), and one O(20) atom. The C(16)-C(18) bond length is 1.51 Å. The C(16)-O(18) bond length is 1.28 Å. The C(16)-O(20) bond length is 1.27 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(25) atom. The C(17)-C(19) bond length is 1.40 Å. The C(17)-C(25) bond length is 1.39 Å. In the sixteenth C site, C(18) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(26) atom. The C(18)-C(20) bond length is 1.40 Å. The C(18)-C(26) bond length is 1.39 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(17); one C(21); and one H(25,26) atom. The C(19)-C(21) bond length is 1.39 Å. The C(19)-H(25,26) bond length is 1.09 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(18); one C(22); and one H(25,26) atom. The C(20)-C(22) bond length is 1.39 Å. The C(20)-H(25,26) bond length is 1.09 Å. In the nineteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(19), one N(3), and one H(27) atom. The C(21)-N(3) bond length is 1.34 Å. The C(21)-H(27) bond length is 1.09 Å. In the twentieth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(20), one N(4), and one H(28) atom. The C(22)-N(4) bond length is 1.35 Å. The C(22)-H(28) bond length is 1.09 Å. In the twenty-first C site, C(23) is bonded in a distorted single-bond geometry to one C(25) and one N(3) atom. The C(23)-C(25) bond length is 1.39 Å. The C(23)-N(3) bond length is 1.35 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(26) and one N(4) atom. The C(24)-C(26) bond length is 1.39 Å. The C(24)-N(4) bond length is 1.35 Å. In the twenty-third C site, C(25) is bonded in a distorted trigonal planar geometry to one C(17); one C(23); and one H(29,30) atom. The C(25)-H(29,30) bond length is 1.09 Å. In the twenty-fourth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(18); one C(24); and one H(29,30) atom. The C(26)-H(29,30) bond length is 1.09 Å. In the twenty-fifth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(15) atom. The C(27)-O(13) bond length is 1.28 Å. The C(27)-O(15) bond length is 1.26 Å. In the twenty-sixth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one O(14) and one O(16) atom. The C(28)-O(14) bond length is 1.28 Å. The C(28)-O(16) bond length is 1.26 Å. In the twenty-seventh C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(31,32) atom. The C(29)-N(5) bond length is 1.34 Å. The C(29)-H(31,32) bond length is 1.09 Å. In the twenty-eighth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(31,32) atom. The C(30)-N(6) bond length is 1.34 Å. The C(30)-H(31,32) bond length is 1.09 Å. In the twenty-ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(33,34) and one H(33,34) atom. The C(31)-C(33,34) bond length is 1.39 Å. The C(31)-H(33,34) bond length is 1.09 Å. In the thirtieth C site, C(32) is bonded in a distorted single-bond geometry to one C(33,34) and one H(33,34) atom. The C(32)-C(33,34) bond length is 1.39 Å. The C(32)-H(33,34) bond length is 1.09 Å. In the thirty-first C site, C(33,34) is bonded in a distorted trigonal planar geometry to one C(31), one C(35), and one H(35) atom. The C(33,34)-C(35) bond length is 1.40 Å. The C(33,34)-H(35) bond length is 1.09 Å. In the thirty-second C site, C(35) is bonded in a distorted trigonal planar geometry to one C(33,34); one C(37); and one N(7) atom. The C(35)-C(37) bond length is 1.40 Å. The C(35)-N(7) bond length is 1.40 Å. In the thirty-third C site, C(36) is bonded in a distorted trigonal planar geometry to one C(33,34); one C(38); and one N(8) atom. The C(36)-C(33,34) bond length is 1.40 Å. The C(36)-C(38) bond length is 1.40 Å. The C(36)-N(8) bond length is 1.40 Å. In the thirty-fourth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(35); one N(5); and one H(37,38) atom. The C(37)-N(5) bond length is 1.34 Å. The C(37)-H(37,38) bond length is 1.09 Å. In the thirty-fifth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(36); one N(6); and one H(37,38) atom. The C(38)-N(6) bond length is 1.34 Å. The C(38)-H(37,38) bond length is 1.09 Å. In the thirty-sixth C site, C(39,40) is bonded in a distorted bent 120 degrees geometry to one C(41), one N(7), and one O(25) atom. The C(39,40)-C(41) bond length is 1.50 Å. The C(39,40)-N(7) bond length is 1.38 Å. The C(39,40)-O(25) bond length is 1.23 Å. In the thirty-seventh C site, C(41) is bonded in a trigonal planar geometry to one C(39,40); one C(43,44); and one C(49) atom. The C(41)-C(43,44) bond length is 1.40 Å. The C(41)-C(49) bond length is 1.40 Å. In the thirty-eighth C site, C(42) is bonded in a trigonal planar geometry to one C(39,40); one C(43,44); and one C(50) atom. The C(42)-C(39,40) bond length is 1.50 Å. The C(42)-C(43,44) bond length is 1.40 Å. The C(42)-C(50) bond length is 1.40 Å. In the thirty-ninth C site, C(43,44) is bonded in a distorted single-bond geometry to one C(41) and one H(39) atom. The C(43,44)-H(39) bond length is 1.09 Å. In the fortieth C site, C(47) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(43) atom. The C(47)-N(9) bond length is 1.34 Å. The C(47)-H(43) bond length is 1.09 Å. In the forty-first C site, C(48) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(44) atom. The C(48)-N(10) bond length is 1.34 Å. The C(48)-H(44) bond length is 1.09 Å. In the forty-second C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(41), one N(9), and one H(45) atom. The C(49)-N(9) bond length is 1.34 Å. The C(49)-H(45) bond length is 1.09 Å. In the forty-third C site, C(50) is bonded in a distorted bent 120 degrees geometry to one C(42), one N(10), and one H(46) atom. The C(50)-N(10) bond length is 1.34 Å. The C(50)-H(46) bond length is 1.09 Å. There are ten inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(7), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(10), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(3), one C(21), and one C(23) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(4), one C(22), and one C(24) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(3), one C(29), and one C(37) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(4), one C(30), and one C(38) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(35); one C(39,40); and one H(17,18) atom. The N(7)-H(17,18) bond length is 1.02 Å. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(36); one C(39,40); and one H(17,18) atom. The N(8)-C(39,40) bond length is 1.38 Å. The N(8)-H(17,18) bond length is 1.02 Å. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Zn(1), one C(47), and one C(49) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Zn(2), one C(48), and one C(50) atom. There are thirty-six inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(9) atom. The H(1)-O(9) bond length is 1.00 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(10) atom. The H(2)-O(10) bond length is 1.00 Å. In the third H site, H(3) is bonded in a distorted linear geometry to one O(3) and one O(9) atom. The H(3)-O(3) bond length is 1.59 Å. The H(3)-O(9) bond length is 1.01 Å. In the fourth H site, H(4) is bonded in a distorted linear geometry to one O(10) and one O(4) atom. The H(4)-O(10) bond length is 1.01 Å. The H(4)-O(4) bond length is 1.59 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(11) atom. The H(5)-O(11) bond length is 0.99 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(12) atom. The H(6)-O(12) bond length is 0.99 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(11) atom. The H(7)-O(11) bond length is 1.00 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(12) atom. The H(8)-O(12) bond length is 1.00 Å. In the ninth H site, H(9) is bonded in a distorted linear geometry to one O(15) and one O(21) atom. The H(9)-O(15) bond length is 1.57 Å. The H(9)-O(21) bond length is 1.01 Å. In the tenth H site, H(10) is bonded in a distorted linear geometry to one O(16) and one O(22) atom. The H(10)-O(16) bond length is 1.57 Å. The H(10)-O(22) bond length is 1.01 Å. In the eleventh H site, H(11) is bonded in a distorted single-bond geometry to one O(21) atom. The H(11)-O(21) bond length is 1.00 Å. In the twelfth H site, H(12) is bonded in a distorted single-bond geometry to one O(22) atom. The H(12)-O(22) bond length is 1.00 Å. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one O(23) atom. The H(13)-O(23) bond length is 0.99 Å. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one O(24) atom. The H(14)-O(24) bond length is 0.99 Å. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one O(2) and one O(23) atom. The H(15)-O(2) bond length is 1.73 Å. The H(15)-O(23) bond length is 1.00 Å. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one O(1) and one O(24) atom. The H(16)-O(1) bond length is 1.74 Å. The H(16)-O(24) bond length is 1.00 Å. In the seventeenth H site, H(17,18) is bonded in a single-bond geometry to one N(7) atom. In the eighteenth H site, H(19,20) is bonded in a single-bond geometry to one C(5,6) atom. In the nineteenth H site, H(21,22) is bonded in a single-bond geometry to one C(7) atom. In the twentieth H site, H(23) is bonded in a single-bond geometry to one C(11,12) atom. In the twenty-first H site, H(24) is bonded in a single-bond geometry to one C(11,12) atom. The H(24)-C(11,12) bond length is 1.09 Å. In the twenty-second H site, H(25,26) is bonded in a single-bond geometry to one C(19) atom. In the twenty-third H site, H(27) is bonded in a single-bond geometry to one C(21) atom. In the twenty-fourth H site, H(28) is bonded in a single-bond geometry to one C(22) atom. In the twenty-fifth H site, H(29,30) is bonded in a single-bond geometry to one C(25) atom. In the twenty-sixth H site, H(31,32) is bonded in a single-bond geometry to one C(29) atom. In the twenty-seventh H site, H(33,34) is bonded in a single-bond geometry to one C(31) atom. In the twenty-eighth H site, H(35) is bonded in a single-bond geometry to one C(33,34) atom. In the twenty-ninth H site, H(36) is bonded in a single-bond geometry to one C(33,34) atom. The H(36)-C(33,34) bond length is 1.09 Å. In the thirtieth H site, H(37,38) is bonded in a single-bond geometry to one C(37) atom. In the thirty-first H site, H(39) is bonded in a single-bond geometry to one C(43,44) atom. In the thirty-second H site, H(40) is bonded in a single-bond geometry to one C(43,44) atom. The H(40)-C(43,44) bond length is 1.09 Å. In the thirty-third H site, H(43) is bonded in a single-bond geometry to one C(47) atom. In the thirty-fourth H site, H(44) is bonded in a single-bond geometry to one C(48) atom. In the thirty-fifth H site, H(45) is bonded in a single-bond geometry to one C(49) atom. In the thirty-sixth H site, H(46) is bonded in a single-bond geometry to one C(50) atom. There are twenty-six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Zn(1), one C(13), and one H(16) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Zn(2), one C(14), and one H(15) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(13) and one H(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(14) and one H(4) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one C(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one C(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one H(1), and one H(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one H(2), and one H(4) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Zn(1), one H(5), and one H(7) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Zn(2), one H(6), and one H(8) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to one Zn(3) and one C(27) atom. In the fourteenth O site, O(14) is bonded in a 2-coordinate geometry to one Zn(4) and one C(28) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one C(27) and one H(9) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one C(28) and one H(10) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one C(15) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one C(16) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(15) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(16) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal non-coplanar geometry to one Zn(3), one H(11), and one H(9) atom. In the twenty-second O site, O(22) is bonded in a distorted trigonal non-coplanar geometry to one Zn(4), one H(10), and one H(12) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal non-coplanar geometry to one Zn(3), one H(13), and one H(15) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal non-coplanar geometry to one Zn(4), one H(14), and one H(16) atom. In the twenty-fifth O site, O(25) is bonded in a single-bond geometry to one C(39,40) atom. In the twenty-sixth O site, O(26) is bonded in a single-bond geometry to one C(39,40) atom. The O(26)-C(39,40) bond length is 1.23 Å. Linkers: 4 [O]C(=O)c1ccnc(C([O])=O)c1 ,2 O=C(Nc1cccnc1)c1cccnc1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 4.48 A, density 1.56 g/cm3, surface area 4004.44 m2/g, accessible volume 0.22 cm3/g