CoC20H20(N7O)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoC20H20(N7O)2 cluster. Co(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(7), and two equivalent O(1) atoms. Both Co(1)-N(1) bond lengths are 1.90 Å. Both Co(1)-N(7) bond lengths are 1.92 Å. Both Co(1)-O(1) bond lengths are 2.27 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(3), and one N(4) atom. The C(1)-C(2) bond length is 1.46 Å. The C(1)-N(3) bond length is 1.36 Å. The C(1)-N(4) bond length is 1.35 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(6) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(7) and one H(2) atom. The C(4)-C(7) bond length is 1.40 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(7) and one H(3) atom. The C(5)-C(7) bond length is 1.40 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(8) atom. The C(7)-C(8) bond length is 1.51 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(7), one N(5), one H(5), and one H(6) atom. The C(8)-N(5) bond length is 1.46 Å. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.10 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one N(5), one N(7), and one H(7) atom. The C(9)-N(5) bond length is 1.34 Å. The C(9)-N(7) bond length is 1.34 Å. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one N(6), one N(7), and one H(8) atom. The C(10)-N(6) bond length is 1.33 Å. The C(10)-N(7) bond length is 1.37 Å. The C(10)-H(8) bond length is 1.08 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Co(1), one N(2), and one N(4) atom. The N(1)-N(2) bond length is 1.33 Å. The N(1)-N(4) bond length is 1.34 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.34 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(1) and one N(2) atom. In the fourth N site, N(4) is bonded in a water-like geometry to one C(1) and one N(1) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(8), one C(9), and one N(6) atom. The N(5)-N(6) bond length is 1.36 Å. In the sixth N site, N(6) is bonded in a distorted water-like geometry to one C(10) and one N(5) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Co(1), one C(10), and one C(9) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(1) atom. The H(9)-O(1) bond length is 0.97 Å. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(1) atom. The H(10)-O(1) bond length is 0.98 Å. O(1) is bonded in a distorted water-like geometry to one Co(1), one H(10), and one H(9) atom. Linkers: 1 c1ncn(Cc2ccc(C3=NN=N[N]3)cc2)n1 ,1 [CH]1N=C[N]N1Cc1ccc(C2=NN=N[N]2)cc1. Metal clusters: 1 O.O.[Co]. The MOF has largest included sphere 3.05 A, density 1.54 g/cm3, surface area 4561.27 m2/g, accessible volume 0.21 cm3/g