ZnC18H14I2(N2O)2 is Indium-like structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two ZnC18H14I2(N2O)2 clusters. Zn(1) is bonded in a distorted tetrahedral geometry to two equivalent N(2) and two equivalent I(1) atoms. Both Zn(1)-N(2) bond lengths are 2.07 Å. Both Zn(1)-I(1) bond lengths are 2.54 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(6) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(5) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.49 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(2), and one H(2) atom. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-N(2) bond length is 1.35 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one O(1) atom. The C(6)-N(1) bond length is 1.38 Å. The C(6)-O(1) bond length is 1.24 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one C(9), and one N(1) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-C(9) bond length is 1.40 Å. The C(7)-N(1) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.08 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(6), one C(7), and one H(1) atom. The N(1)-H(1) bond length is 1.02 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(2), and one C(3) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. O(1) is bonded in a single-bond geometry to one C(6) atom. I(1) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 2 O=C(Nc1ccc(NC(=O)c2cccnc2)cc1)c1cccnc1. Metal clusters: 2 I[Zn]I. The MOF has largest included sphere 2.36 A, density 2.09 g/cm3, surface area 3650.61 m2/g, accessible volume 0.12 cm3/g