CuC14N5H13O6(CH)2C3H2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; one 2,3-dimethyl-1,3-butadiene molecule; and one CuC14N5H13O6 cluster. In the CuC14N5H13O6 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(4), one N(5), one O(2), one O(4), and one O(5) atom. The Cu(1)-N(4) bond length is 2.02 Å. The Cu(1)-N(5) bond length is 2.01 Å. The Cu(1)-O(2) bond length is 2.05 Å. The Cu(1)-O(4) bond length is 2.24 Å. The Cu(1)-O(5) bond length is 2.02 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one N(3) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(3) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(6), and one O(1) atom. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. The C(7)-O(1) bond length is 1.46 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(8)-O(2) bond length is 1.29 Å. The C(8)-O(3) bond length is 1.25 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(7,10) atom. The C(9)-N(4) bond length is 1.35 Å. The C(9)-H(7,10) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(7,10) atom. The C(13)-N(4) bond length is 1.35 Å. The C(13)-H(7,10) bond length is 1.09 Å. In the ninth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(15), one N(5), and one H(11) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-N(5) bond length is 1.34 Å. The C(14)-H(11) bond length is 1.09 Å. In the tenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(12) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(12) bond length is 1.09 Å. In the eleventh C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(17) atom. The C(16)-C(16) bond length is 1.48 Å. The C(16)-C(17) bond length is 1.41 Å. In the twelfth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(13) atom. The C(17)-H(13) bond length is 1.09 Å. In the thirteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one N(5) and one H(14) atom. The C(18)-N(5) bond length is 1.35 Å. The C(18)-H(14) bond length is 1.09 Å. In the fourteenth C site, C(19) is bonded in a trigonal planar geometry to one H(15), one O(5), and one O(6) atom. The C(19)-H(15) bond length is 1.11 Å. The C(19)-O(5) bond length is 1.29 Å. The C(19)-O(6) bond length is 1.25 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(1), one N(2), and one O(1) atom. The N(1)-N(2) bond length is 1.35 Å. The N(1)-O(1) bond length is 1.37 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.31 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(16) atom. The N(3)-H(16) bond length is 1.78 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(9) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(1), one C(14), and one C(18) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7,10) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one N(3) and one O(4) atom. The H(16)-O(4) bond length is 0.99 Å. In the twelfth H site, H(17) is bonded in a single-bond geometry to one O(4) atom. The H(17)-O(4) bond length is 1.00 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(7) and one N(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cu(1) and one C(8) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Cu(1), one H(16), and one H(17) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(19) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one C(19) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 1.92 A, density 1.68 g/cm3, surface area 4535.89 m2/g, accessible volume 0.10 cm3/g