(CH)2(CH2)2ZnC14H12S2(NO3)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four 02329_fluka molecules, and two ZnC14H12S2(NO3)4 clusters. In each ZnC14H12S2(NO3)4 cluster, Zn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(2), and two equivalent O(3) atoms. Both Zn(1)-N(1) bond lengths are 2.16 Å. Both Zn(1)-O(2) bond lengths are 2.24 Å. Both Zn(1)-O(3) bond lengths are 2.06 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one S(1) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-S(1) bond length is 1.76 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded to one N(2) and one H(5) atom to form distorted CHN tetrahedra that share  a cornercorner with one S(1)CNO2 tetrahedra. The C(6)-N(2) bond length is 1.47 Å. The C(6)-H(5) bond length is 1.10 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(7)-O(1) bond length is 1.32 Å. The C(7)-O(2) bond length is 1.23 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(9)-O(3) bond length is 1.28 Å. The C(9)-O(4) bond length is 1.26 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one H(8), and one S(1) atom. The N(2)-H(8) bond length is 1.05 Å. The N(2)-S(1) bond length is 1.65 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one O(1) atom. The H(9)-O(1) bond length is 1.00 Å. S(1) is bonded to one C(4), one N(2), one O(5), and one O(6) atom to form distorted SCNO2 tetrahedra that share  a cornercorner with one C(6)HN tetrahedra. The S(1)-O(5) bond length is 1.45 Å. The S(1)-O(6) bond length is 1.45 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(7) and one H(9) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(9) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. Linkers: 2 [O]C(=O)C[C@@H](NS(=O)(=O)c1cccnc1)C(=O)O ,2 [O]C(=O)C[C@H](NS(=O)(=O)c1cccnc1)C(=O)O. Metal clusters: 2 O=[C]O[Zn](O[C]O)(O[C]O)O[C]=O. RCSR code: sql. The MOF has largest included sphere 2.33 A, density 1.78 g/cm3, surface area 3901.76 m2/g, accessible volume 0.11 cm3/g