CdC19H12(NO3)2(CH)2(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four 02329_fluka molecules, and one CdC19H12(NO3)2 cluster. In the CdC19H12(NO3)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one O(2), one O(3), one O(4), and two equivalent O(1) atoms. The Cd(1)-N(1) bond length is 2.30 Å. The Cd(1)-O(2) bond length is 2.37 Å. The Cd(1)-O(3) bond length is 2.36 Å. The Cd(1)-O(4) bond length is 2.42 Å. There is one shorter (2.29 Å) and one longer (2.50 Å) Cd(1)-O(1) bond length. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one O(5) atom. The C(5)-O(5) bond length is 1.39 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one O(5) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-O(5) bond length is 1.38 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(6) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(6) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(7) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-H(7) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(14) bond length is 1.48 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(8) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(8) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(9) atom. The C(13)-H(9) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.30 Å. The C(14)-O(4) bond length is 1.27 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one N(1), and one H(10) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-N(1) bond length is 1.35 Å. The C(15)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(11) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(11) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(12) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(12) bond length is 1.08 Å. In the sixteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one N(2) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-N(2) bond length is 1.39 Å. In the seventeenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(1), and one H(13) atom. The C(19)-N(1) bond length is 1.34 Å. The C(19)-H(13) bond length is 1.09 Å. In the eighteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(21), one N(2), and one O(6) atom. The C(20)-C(21) bond length is 1.52 Å. The C(20)-N(2) bond length is 1.37 Å. The C(20)-O(6) bond length is 1.24 Å. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(14) atom. The C(21)-H(14) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(15), and one C(19) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(18), one C(20), and one H(1) atom. The N(2)-H(1) bond length is 1.04 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(14) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(14) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(5) and one C(8) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(20) atom. Linkers: 2 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 1 [C]1O[Cd]2(O1)O[C]O[Cd]1(O[C]O1)O[C]O2. The MOF has largest included sphere 2.27 A, density 1.75 g/cm3, surface area 4108.41 m2/g, accessible volume 0.13 cm3/g