CuC14H10(N3O)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CuC14H10(N3O)4 cluster. Cu(1) is bonded in a distorted octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 2.01 Å. Both Cu(1)-N(3) bond lengths are 2.39 Å. Both Cu(1)-O(1) bond lengths are 1.99 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(1), and one H(2) atom. The C(1)-N(2) bond length is 1.45 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one C(3), one N(2), and one N(3) atom. The C(2)-C(3) bond length is 1.46 Å. The C(2)-N(2) bond length is 1.35 Å. The C(2)-N(3) bond length is 1.33 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one N(5) atom. The C(3)-N(1) bond length is 1.35 Å. The C(3)-N(5) bond length is 1.34 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(5), and one H(5) atom. The C(6)-N(5) bond length is 1.34 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(7)-O(1) bond length is 1.28 Å. The C(7)-O(2) bond length is 1.24 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(2), and one N(4) atom. The N(2)-N(4) bond length is 1.35 Å. In the third N site, N(3) is bonded in a distorted single-bond geometry to one Cu(1), one C(2), and one N(6) atom. The N(3)-N(6) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one N(2) and one N(6) atom. The N(4)-N(6) bond length is 1.31 Å. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(3) and one C(6) atom. In the sixth N site, N(6) is bonded in a water-like geometry to one N(3) and one N(4) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(7) atom. Linkers: 2 [O]C(=O)Cn1nnnc1-c1ncccn1. Metal clusters: 1 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 2.77 A, density 1.68 g/cm3, surface area 4076.25 m2/g, accessible volume 0.20 cm3/g