Zn4C76N16H52O13 crystallizes in the triclinic P-1 space group. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one N(10), one N(5), one N(8), and one O(7) atom. The Zn(1)-N(10) bond length is 1.99 Å. The Zn(1)-N(5) bond length is 1.96 Å. The Zn(1)-N(8) bond length is 2.07 Å. The Zn(1)-O(7) bond length is 1.97 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(6), and one O(9) atom. The Zn(2)-N(1) bond length is 2.03 Å. The Zn(2)-N(2) bond length is 2.06 Å. The Zn(2)-O(6) bond length is 1.97 Å. The Zn(2)-O(9) bond length is 1.97 Å. In the third Zn site, Zn(3) is bonded in a tetrahedral geometry to one N(4), one N(6), one O(4), and one O(8) atom. The Zn(3)-N(4) bond length is 2.02 Å. The Zn(3)-N(6) bond length is 2.06 Å. The Zn(3)-O(4) bond length is 1.97 Å. The Zn(3)-O(8) bond length is 1.95 Å. In the fourth Zn site, Zn(4) is bonded in a tetrahedral geometry to one N(7), one N(9), one O(11), and one O(13) atom. The Zn(4)-N(7) bond length is 1.94 Å. The Zn(4)-N(9) bond length is 1.96 Å. The Zn(4)-O(11) bond length is 1.94 Å. The Zn(4)-O(13) bond length is 2.14 Å. There are seventy-six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(10), one N(3), and one N(4) atom. The C(1)-N(10) bond length is 1.33 Å. The C(1)-N(3) bond length is 1.34 Å. The C(1)-N(4) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(12), and one O(9) atom. The C(2)-C(17) bond length is 1.50 Å. The C(2)-O(12) bond length is 1.26 Å. The C(2)-O(9) bond length is 1.30 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(12), and one N(5) atom. The C(3)-N(1) bond length is 1.37 Å. The C(3)-N(12) bond length is 1.34 Å. The C(3)-N(5) bond length is 1.34 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(17) and one H(7) atom. The C(4)-C(17) bond length is 1.40 Å. The C(4)-H(7) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(15) and one H(8) atom. The C(5)-C(15) bond length is 1.40 Å. The C(5)-H(8) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(3), and one O(7) atom. The C(6)-C(15) bond length is 1.50 Å. The C(6)-O(3) bond length is 1.25 Å. The C(6)-O(7) bond length is 1.31 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(59), one O(5), and one O(6) atom. The C(7)-C(59) bond length is 1.50 Å. The C(7)-O(5) bond length is 1.26 Å. The C(7)-O(6) bond length is 1.29 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(9) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(23), one N(6), and one H(10) atom. The C(9)-C(23) bond length is 1.39 Å. The C(9)-N(6) bond length is 1.35 Å. The C(9)-H(10) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(10)-C(14) bond length is 1.41 Å. The C(10)-H(11) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(29) and one H(14,18) atom. The C(11)-C(29) bond length is 1.41 Å. The C(11)-H(14,18) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(18), one C(33), and one C(70) atom. The C(12)-C(18) bond length is 1.40 Å. The C(12)-C(33) bond length is 1.50 Å. The C(12)-C(70) bond length is 1.40 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one N(11), one N(4), and one N(7) atom. The C(13)-N(11) bond length is 1.34 Å. The C(13)-N(4) bond length is 1.37 Å. The C(13)-N(7) bond length is 1.34 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(10), one C(27), and one C(34) atom. The C(14)-C(27) bond length is 1.41 Å. The C(14)-C(34) bond length is 1.48 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(38), one C(5), and one C(6) atom. The C(15)-C(38) bond length is 1.40 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(21), one C(43), and one C(44) atom. The C(16)-C(21) bond length is 1.40 Å. The C(16)-C(43) bond length is 1.48 Å. The C(16)-C(44) bond length is 1.40 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(55) atom. The C(17)-C(55) bond length is 1.40 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(12) and one H(17) atom. The C(18)-H(17) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(45) and one H(14,18) atom. The C(19)-C(45) bond length is 1.41 Å. The C(19)-H(14,18) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(30), one C(32), and one H(19) atom. The C(20)-C(30) bond length is 1.39 Å. The C(20)-C(32) bond length is 1.40 Å. The C(20)-H(19) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(20) atom. The C(21)-H(20) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(58) and one H(21) atom. The C(22)-C(58) bond length is 1.40 Å. The C(22)-H(21) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted trigonal planar geometry to one C(32), one C(9), and one H(22) atom. The C(23)-C(32) bond length is 1.40 Å. The C(23)-H(22) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one N(1), one N(16), and one N(9) atom. The C(24)-N(1) bond length is 1.37 Å. The C(24)-N(16) bond length is 1.36 Å. The C(24)-N(9) bond length is 1.34 Å. In the twenty-fifth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one C(28), and one N(14) atom. The C(25)-C(26) bond length is 1.48 Å. The C(25)-C(28) bond length is 1.40 Å. The C(25)-N(14) bond length is 1.34 Å. In the twenty-sixth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(65), and one C(66) atom. The C(26)-C(65) bond length is 1.41 Å. The C(26)-C(66) bond length is 1.40 Å. In the twenty-seventh C site, C(27) is bonded in a distorted trigonal planar geometry to one C(14), one C(70), and one H(23) atom. The C(27)-C(70) bond length is 1.39 Å. The C(27)-H(23) bond length is 1.09 Å. In the twenty-eighth C site, C(28) is bonded in a distorted single-bond geometry to one C(25), one C(47), and one H(24) atom. The C(28)-C(47) bond length is 1.40 Å. The C(28)-H(24) bond length is 1.09 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(11), one C(31), and one C(40) atom. The C(29)-C(31) bond length is 1.48 Å. The C(29)-C(40) bond length is 1.41 Å. In the thirtieth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(20), one N(6), and one H(25) atom. The C(30)-N(6) bond length is 1.35 Å. The C(30)-H(25) bond length is 1.09 Å. In the thirty-first C site, C(31) is bonded in a distorted single-bond geometry to one C(29) and one N(15) atom. The C(31)-N(15) bond length is 1.34 Å. In the thirty-second C site, C(32) is bonded in a trigonal planar geometry to one C(20), one C(23), and one C(47) atom. The C(32)-C(47) bond length is 1.47 Å. In the thirty-third C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(8) atom. The C(33)-O(1) bond length is 1.26 Å. The C(33)-O(8) bond length is 1.30 Å. In the thirty-fourth C site, C(34) is bonded in a trigonal planar geometry to one C(14), one C(39), and one N(13) atom. The C(34)-C(39) bond length is 1.40 Å. The C(34)-N(13) bond length is 1.34 Å. In the thirty-fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(47), one C(56), and one H(26) atom. The C(35)-C(47) bond length is 1.40 Å. The C(35)-C(56) bond length is 1.40 Å. The C(35)-H(26) bond length is 1.09 Å. In the thirty-sixth C site, C(36) is bonded in a trigonal planar geometry to one C(48), one C(49), and one C(58) atom. The C(36)-C(48) bond length is 1.40 Å. The C(36)-C(49) bond length is 1.40 Å. The C(36)-C(58) bond length is 1.48 Å. In the thirty-seventh C site, C(37) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(27) atom. The C(37)-N(2) bond length is 1.35 Å. The C(37)-H(27) bond length is 1.09 Å. In the thirty-eighth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(15), one C(40), and one H(28) atom. The C(38)-C(40) bond length is 1.39 Å. The C(38)-H(28) bond length is 1.09 Å. In the thirty-ninth C site, C(39) is bonded in a distorted single-bond geometry to one C(34), one C(43), and one H(29) atom. The C(39)-C(43) bond length is 1.40 Å. The C(39)-H(29) bond length is 1.09 Å. In the fortieth C site, C(40) is bonded in a distorted single-bond geometry to one C(29), one C(38), and one H(30) atom. The C(40)-H(30) bond length is 1.09 Å. In the forty-first C site, C(41) is bonded in a distorted single-bond geometry to one C(45), one C(55), and one H(31) atom. The C(41)-C(45) bond length is 1.41 Å. The C(41)-C(55) bond length is 1.39 Å. The C(41)-H(31) bond length is 1.09 Å. In the forty-second C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(57), one N(8), and one H(32) atom. The C(42)-C(57) bond length is 1.39 Å. The C(42)-N(8) bond length is 1.35 Å. The C(42)-H(32) bond length is 1.09 Å. In the forty-third C site, C(43) is bonded in a trigonal planar geometry to one C(16), one C(39), and one C(46) atom. The C(43)-C(46) bond length is 1.40 Å. In the forty-fourth C site, C(44) is bonded in a distorted single-bond geometry to one C(16) and one H(33) atom. The C(44)-H(33) bond length is 1.09 Å. In the forty-fifth C site, C(45) is bonded in a trigonal planar geometry to one C(19), one C(41), and one C(51) atom. The C(45)-C(51) bond length is 1.48 Å. In the forty-sixth C site, C(46) is bonded in a distorted single-bond geometry to one C(43), one C(51), and one H(34) atom. The C(46)-C(51) bond length is 1.40 Å. The C(46)-H(34) bond length is 1.09 Å. In the forty-seventh C site, C(47) is bonded in a trigonal planar geometry to one C(28), one C(32), and one C(35) atom. In the forty-eighth C site, C(48) is bonded in a distorted single-bond geometry to one C(36) and one H(35) atom. The C(48)-H(35) bond length is 1.09 Å. In the forty-ninth C site, C(49) is bonded in a distorted single-bond geometry to one C(36), one C(62), and one H(36) atom. The C(49)-C(62) bond length is 1.40 Å. The C(49)-H(36) bond length is 1.09 Å. In the fiftieth C site, C(50) is bonded in a trigonal planar geometry to one C(56), one C(63), and one C(71) atom. The C(50)-C(56) bond length is 1.48 Å. The C(50)-C(63) bond length is 1.41 Å. The C(50)-C(71) bond length is 1.41 Å. In the fifty-first C site, C(51) is bonded in a distorted trigonal planar geometry to one C(45), one C(46), and one N(13) atom. The C(51)-N(13) bond length is 1.34 Å. In the fifty-second C site, C(52) is bonded in a distorted trigonal planar geometry to one C(53), one C(71), and one H(37) atom. The C(52)-C(53) bond length is 1.40 Å. The C(52)-C(71) bond length is 1.39 Å. The C(52)-H(37) bond length is 1.09 Å. In the fifty-third C site, C(53) is bonded in a trigonal planar geometry to one C(52), one C(54), and one C(60) atom. The C(53)-C(54) bond length is 1.40 Å. The C(53)-C(60) bond length is 1.50 Å. In the fifty-fourth C site, C(54) is bonded in a distorted single-bond geometry to one C(53) and one H(38) atom. The C(54)-H(38) bond length is 1.09 Å. In the fifty-fifth C site, C(55) is bonded in a distorted trigonal planar geometry to one C(17), one C(41), and one H(39) atom. The C(55)-H(39) bond length is 1.09 Å. In the fifty-sixth C site, C(56) is bonded in a distorted trigonal planar geometry to one C(35), one C(50), and one N(14) atom. The C(56)-N(14) bond length is 1.34 Å. In the fifty-seventh C site, C(57) is bonded in a distorted trigonal planar geometry to one C(42), one C(58), and one H(40) atom. The C(57)-C(58) bond length is 1.41 Å. The C(57)-H(40) bond length is 1.09 Å. In the fifty-eighth C site, C(58) is bonded in a trigonal planar geometry to one C(22), one C(36), and one C(57) atom. In the fifty-ninth C site, C(59) is bonded in a trigonal planar geometry to one C(7), one C(74), and one C(75) atom. The C(59)-C(74) bond length is 1.40 Å. The C(59)-C(75) bond length is 1.40 Å. In the sixtieth C site, C(60) is bonded in a distorted bent 120 degrees geometry to one C(53), one O(10), and one O(4) atom. The C(60)-O(10) bond length is 1.26 Å. The C(60)-O(4) bond length is 1.29 Å. In the sixty-first C site, C(61) is bonded in a trigonal planar geometry to one C(62), one C(68), and one C(73) atom. The C(61)-C(62) bond length is 1.48 Å. The C(61)-C(68) bond length is 1.41 Å. The C(61)-C(73) bond length is 1.41 Å. In the sixty-second C site, C(62) is bonded in a distorted trigonal planar geometry to one C(49), one C(61), and one N(15) atom. The C(62)-N(15) bond length is 1.35 Å. In the sixty-third C site, C(63) is bonded in a distorted single-bond geometry to one C(50) and one H(41) atom. The C(63)-H(41) bond length is 1.09 Å. In the sixty-fourth C site, C(64) is bonded in a distorted single-bond geometry to one C(67) and one H(42) atom. The C(64)-C(67) bond length is 1.40 Å. The C(64)-H(42) bond length is 1.09 Å. In the sixty-fifth C site, C(65) is bonded in a distorted single-bond geometry to one C(26) and one H(43) atom. The C(65)-H(43) bond length is 1.09 Å. In the sixty-sixth C site, C(66) is bonded in a distorted trigonal planar geometry to one C(26), one C(72), and one H(44) atom. The C(66)-C(72) bond length is 1.39 Å. The C(66)-H(44) bond length is 1.09 Å. In the sixty-seventh C site, C(67) is bonded in a trigonal planar geometry to one C(64), one C(72), and one C(76) atom. The C(67)-C(72) bond length is 1.41 Å. The C(67)-C(76) bond length is 1.50 Å. In the sixty-eighth C site, C(68) is bonded in a distorted single-bond geometry to one C(61) and one H(45) atom. The C(68)-H(45) bond length is 1.09 Å. In the sixty-ninth C site, C(69) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(46) atom. The C(69)-N(8) bond length is 1.35 Å. The C(69)-H(46) bond length is 1.09 Å. In the seventieth C site, C(70) is bonded in a distorted trigonal planar geometry to one C(12), one C(27), and one H(47) atom. The C(70)-H(47) bond length is 1.09 Å. In the seventy-first C site, C(71) is bonded in a distorted single-bond geometry to one C(50), one C(52), and one H(48) atom. The C(71)-H(48) bond length is 1.09 Å. In the seventy-second C site, C(72) is bonded in a distorted trigonal planar geometry to one C(66), one C(67), and one H(49) atom. The C(72)-H(49) bond length is 1.09 Å. In the seventy-third C site, C(73) is bonded in a distorted trigonal planar geometry to one C(61), one C(75), and one H(50) atom. The C(73)-C(75) bond length is 1.39 Å. The C(73)-H(50) bond length is 1.09 Å. In the seventy-fourth C site, C(74) is bonded in a distorted single-bond geometry to one C(59) and one H(51) atom. The C(74)-H(51) bond length is 1.09 Å. In the seventy-fifth C site, C(75) is bonded in a distorted trigonal planar geometry to one C(59), one C(73), and one H(52) atom. The C(75)-H(52) bond length is 1.09 Å. In the seventy-sixth C site, C(76) is bonded in a distorted bent 120 degrees geometry to one C(67), one O(11), and one O(2) atom. The C(76)-O(11) bond length is 1.30 Å. The C(76)-O(2) bond length is 1.26 Å. There are sixteen inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(24), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(37), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. The N(3)-H(1) bond length is 1.03 Å. The N(3)-H(2) bond length is 1.02 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(3), one C(1), and one C(13) atom. In the fifth N site, N(5) is bonded in a 2-coordinate geometry to one Zn(1), one C(3), and one N(9) atom. The N(5)-N(9) bond length is 1.41 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(3), one C(30), and one C(9) atom. In the seventh N site, N(7) is bonded in a 3-coordinate geometry to one Zn(4), one C(13), and one N(10) atom. The N(7)-N(10) bond length is 1.40 Å. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Zn(1), one C(42), and one C(69) atom. In the ninth N site, N(9) is bonded in a distorted trigonal planar geometry to one Zn(4), one C(24), and one N(5) atom. In the tenth N site, N(10) is bonded in a distorted bent 120 degrees geometry to one Zn(1), one C(1), and one N(7) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one C(13), one H(3), and one H(4) atom. The N(11)-H(3) bond length is 1.02 Å. The N(11)-H(4) bond length is 1.04 Å. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one C(3), one H(5), and one H(6) atom. The N(12)-H(5) bond length is 1.03 Å. The N(12)-H(6) bond length is 1.03 Å. In the thirteenth N site, N(13) is bonded in a bent 120 degrees geometry to one C(34) and one C(51) atom. In the fourteenth N site, N(14) is bonded in a bent 120 degrees geometry to one C(25) and one C(56) atom. In the fifteenth N site, N(15) is bonded in a bent 120 degrees geometry to one C(31) and one C(62) atom. In the sixteenth N site, N(16) is bonded in a distorted trigonal non-coplanar geometry to one C(24), one H(12), and one H(13) atom. The N(16)-H(12) bond length is 1.03 Å. The N(16)-H(13) bond length is 1.02 Å. There are fifty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(11) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one N(11) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(16) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one N(16) atom. In the fourteenth H site, H(14,18) is bonded in a single-bond geometry to one C(11) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one O(13) atom. The H(15)-O(13) bond length is 0.97 Å. In the sixteenth H site, H(16) is bonded in a distorted single-bond geometry to one O(13) and one O(2) atom. The H(16)-O(13) bond length is 1.01 Å. The H(16)-O(2) bond length is 1.69 Å. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(18) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(21) atom. In the twentieth H site, H(21) is bonded in a single-bond geometry to one C(22) atom. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one C(23) atom. In the twenty-second H site, H(23) is bonded in a single-bond geometry to one C(27) atom. In the twenty-third H site, H(24) is bonded in a single-bond geometry to one C(28) atom. In the twenty-fourth H site, H(25) is bonded in a single-bond geometry to one C(30) atom. In the twenty-fifth H site, H(26) is bonded in a single-bond geometry to one C(35) atom. In the twenty-sixth H site, H(27) is bonded in a single-bond geometry to one C(37) atom. In the twenty-seventh H site, H(28) is bonded in a single-bond geometry to one C(38) atom. In the twenty-eighth H site, H(29) is bonded in a single-bond geometry to one C(39) atom. In the twenty-ninth H site, H(30) is bonded in a single-bond geometry to one C(40) atom. In the thirtieth H site, H(31) is bonded in a single-bond geometry to one C(41) atom. In the thirty-first H site, H(32) is bonded in a single-bond geometry to one C(42) atom. In the thirty-second H site, H(33) is bonded in a single-bond geometry to one C(44) atom. In the thirty-third H site, H(34) is bonded in a single-bond geometry to one C(46) atom. In the thirty-fourth H site, H(35) is bonded in a single-bond geometry to one C(48) atom. In the thirty-fifth H site, H(36) is bonded in a single-bond geometry to one C(49) atom. In the thirty-sixth H site, H(37) is bonded in a single-bond geometry to one C(52) atom. In the thirty-seventh H site, H(38) is bonded in a single-bond geometry to one C(54) atom. In the thirty-eighth H site, H(39) is bonded in a single-bond geometry to one C(55) atom. In the thirty-ninth H site, H(40) is bonded in a single-bond geometry to one C(57) atom. In the fortieth H site, H(41) is bonded in a single-bond geometry to one C(63) atom. In the forty-first H site, H(42) is bonded in a single-bond geometry to one C(64) atom. In the forty-second H site, H(43) is bonded in a single-bond geometry to one C(65) atom. In the forty-third H site, H(44) is bonded in a single-bond geometry to one C(66) atom. In the forty-fourth H site, H(45) is bonded in a single-bond geometry to one C(68) atom. In the forty-fifth H site, H(46) is bonded in a single-bond geometry to one C(69) atom. In the forty-sixth H site, H(47) is bonded in a single-bond geometry to one C(70) atom. In the forty-seventh H site, H(48) is bonded in a single-bond geometry to one C(71) atom. In the forty-eighth H site, H(49) is bonded in a single-bond geometry to one C(72) atom. In the forty-ninth H site, H(50) is bonded in a single-bond geometry to one C(73) atom. In the fiftieth H site, H(51) is bonded in a single-bond geometry to one C(74) atom. In the fifty-first H site, H(52) is bonded in a single-bond geometry to one C(75) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one C(33) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one C(76) and one H(16) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(60) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(7) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(33) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(2) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(60) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(76) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one C(2) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Zn(4), one H(15), and one H(16) atom. Linkers: 1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C]C(=O)O[Zn].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/C=C\[C]([C])C(=O)O[Zn].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]C=C([C])[C].[C]C=[CH].[C][C].[C][C].[C][C]=[CH].[C][C][C]/[C]=[C]\[C].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[NH2].[NH2].[NH].[NH].[NH].[NH].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][C][N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][Zn].[O][Zn]O[C]=O.[Zn].[Zn].[Zn].[Zn] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH][N].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/[C]=N/[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C][C].[C][C].[C][C].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[NH].[NH].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][Zn].[O][Zn].[O][Zn] ,1 [O]C(=O)c1ccc(-c2cc(-c3ccncc3)cc(-c3ccc(C([O])=O)cc3)n2)cc1. Metal clusters: 1 O.O=[C]O[Zn]1[N][N][Zn](O[C]=O)[N][N]1 ,3 [Zn]. The MOF has largest included sphere 8.96 A, density 0.93 g/cm3, surface area 4686.49 m2/g, accessible volume 0.67 cm3/g