VC4H4O5Cl2(CH2)2(CH3)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, eight 02329_fluka molecules, and four VC4H4O5Cl2 clusters. In each VC4H4O5Cl2 cluster, V(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), one O(4), one Cl(1), and one Cl(2) atom. The V(1)-O(1) bond length is 1.60 Å. The V(1)-O(2) bond length is 2.04 Å. The V(1)-O(4) bond length is 2.04 Å. The V(1)-Cl(1) bond length is 2.28 Å. The V(1)-Cl(2) bond length is 2.28 Å. There are four inequivalent C sites. In the first C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(4)-O(4) bond length is 1.25 Å. The C(4)-O(5) bond length is 1.32 Å. In the second C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(5,6) and one O(3) atom. Both C(5)-H(5,6) bond lengths are 1.10 Å. The C(5)-O(3) bond length is 1.47 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(1)-O(2) bond length is 1.25 Å. The C(1)-O(3) bond length is 1.32 Å. In the fourth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one H(10), one H(11), and one O(5) atom. The C(7)-H(10) bond length is 1.09 Å. The C(7)-H(11) bond length is 1.10 Å. The C(7)-O(5) bond length is 1.47 Å. There are three inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one V(1) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(4) and one C(7) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one V(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one V(1) atom. Linkers: 2 CCOC(=O)CCC(=O)OCC. Metal clusters: 4 [V]. The MOF has largest included sphere 1.99 A, density 1.62 g/cm3, surface area 5081.30 m2/g, accessible volume 0.17 cm3/g