Co3C47H29(NO3)4(CH3)2 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a Co3C47H29(NO3)4 framework. In the Co3C47H29(NO3)4 framework, there are four inequivalent Co sites. In the first Co site, Co(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(5), and two equivalent O(9) atoms. Both Co(1)-O(1) bond lengths are 2.17 Å. Both Co(1)-O(5) bond lengths are 2.03 Å. Both Co(1)-O(9) bond lengths are 2.14 Å. In the second Co site, Co(2) is bonded in a 5-coordinate geometry to one N(2), one O(1), one O(10), one O(2), and one O(6) atom. The Co(2)-N(2) bond length is 2.01 Å. The Co(2)-O(1) bond length is 2.00 Å. The Co(2)-O(10) bond length is 1.95 Å. The Co(2)-O(2) bond length is 2.41 Å. The Co(2)-O(6) bond length is 1.95 Å. In the third Co site, Co(3) is bonded to one N(3), one N(4), one O(11), one O(3), one O(7), and one O(8) atom to form edge-sharing CoN2O4 octahedra. The Co(3)-N(3) bond length is 2.06 Å. The Co(3)-N(4) bond length is 2.14 Å. The Co(3)-O(11) bond length is 2.08 Å. The Co(3)-O(3) bond length is 2.02 Å. The Co(3)-O(7) bond length is 2.27 Å. The Co(3)-O(8) bond length is 2.17 Å. In the fourth Co site, Co(4) is bonded to two equivalent O(11), two equivalent O(4), and two equivalent O(7) atoms to form edge-sharing CoO6 octahedra. Both Co(4)-O(11) bond lengths are 2.11 Å. Both Co(4)-O(4) bond lengths are 2.03 Å. Both Co(4)-O(7) bond lengths are 2.08 Å. There are forty-seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(4), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(4) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.47 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(4), and one H(4) atom. The C(5)-N(4) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(7) atom. The C(6)-C(11) bond length is 1.41 Å. The C(6)-C(7) bond length is 1.41 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(6) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(12) bond length is 1.47 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(7) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(7) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one H(8) atom. The C(11)-H(8) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(16), one C(9), and one N(1) atom. The C(12)-C(16) bond length is 1.39 Å. The C(12)-N(1) bond length is 1.39 Å. In the thirteenth C site, C(14) is bonded in a 3-coordinate geometry to one N(1), one H(12), and one H(13) atom. The C(14)-N(1) bond length is 1.47 Å. The C(14)-H(12) bond length is 1.10 Å. The C(14)-H(13) bond length is 1.10 Å. In the fourteenth C site, C(15) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(14) atom. The C(15)-N(1) bond length is 1.36 Å. The C(15)-N(2) bond length is 1.33 Å. The C(15)-H(14) bond length is 1.08 Å. In the fifteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(12), one C(17), and one N(2) atom. The C(16)-C(17) bond length is 1.46 Å. The C(16)-N(2) bond length is 1.39 Å. In the sixteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(22) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(22) bond length is 1.41 Å. In the seventeenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(15) atom. The C(18)-H(15) bond length is 1.09 Å. In the eighteenth C site, C(19) is bonded in a single-bond geometry to one C(20) and one H(16) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-H(16) bond length is 1.09 Å. In the nineteenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(23) atom. The C(20)-C(21) bond length is 1.41 Å. The C(20)-C(23) bond length is 1.47 Å. In the twentieth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one H(17) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(17) bond length is 1.09 Å. In the twenty-first C site, C(22) is bonded in a distorted single-bond geometry to one C(17), one C(21), and one H(18) atom. The C(22)-H(18) bond length is 1.09 Å. In the twenty-second C site, C(23) is bonded in a trigonal planar geometry to one C(20), one C(24), and one C(27) atom. The C(23)-C(24) bond length is 1.41 Å. The C(23)-C(27) bond length is 1.41 Å. In the twenty-third C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(19) atom. The C(24)-H(19) bond length is 1.09 Å. In the twenty-fourth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(20) atom. The C(25)-N(3) bond length is 1.35 Å. The C(25)-H(20) bond length is 1.09 Å. In the twenty-fifth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(21) atom. The C(26)-N(3) bond length is 1.35 Å. The C(26)-H(21) bond length is 1.09 Å. In the twenty-sixth C site, C(27) is bonded in a distorted single-bond geometry to one C(23) and one H(22) atom. The C(27)-H(22) bond length is 1.09 Å. In the twenty-seventh C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(1), and one O(2) atom. The C(28)-C(29) bond length is 1.48 Å. The C(28)-O(1) bond length is 1.32 Å. The C(28)-O(2) bond length is 1.25 Å. In the twenty-eighth C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(34) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-C(34) bond length is 1.40 Å. In the twenty-ninth C site, C(30) is bonded in a distorted single-bond geometry to one C(29), one C(31), and one H(23) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-H(23) bond length is 1.09 Å. In the thirtieth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(30), one C(32), and one H(24) atom. The C(31)-C(32) bond length is 1.40 Å. The C(31)-H(24) bond length is 1.09 Å. In the thirty-first C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(35) atom. The C(32)-C(33) bond length is 1.40 Å. The C(32)-C(35) bond length is 1.49 Å. In the thirty-second C site, C(33) is bonded in a distorted trigonal planar geometry to one C(32), one C(34), and one H(25) atom. The C(33)-C(34) bond length is 1.39 Å. The C(33)-H(25) bond length is 1.09 Å. In the thirty-third C site, C(34) is bonded in a distorted single-bond geometry to one C(29), one C(33), and one H(26) atom. The C(34)-H(26) bond length is 1.09 Å. In the thirty-fourth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(3), and one O(4) atom. The C(35)-O(3) bond length is 1.28 Å. The C(35)-O(4) bond length is 1.27 Å. In the thirty-fifth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(10), and one O(9) atom. The C(36)-C(37) bond length is 1.50 Å. The C(36)-O(10) bond length is 1.29 Å. The C(36)-O(9) bond length is 1.27 Å. In the thirty-sixth C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one C(39) atom. The C(37)-C(38) bond length is 1.40 Å. The C(37)-C(39) bond length is 1.40 Å. In the thirty-seventh C site, C(38) is bonded in a distorted trigonal planar geometry to one C(37), one C(39), and one H(27) atom. The C(38)-C(39) bond length is 1.39 Å. The C(38)-H(27) bond length is 1.09 Å. In the thirty-eighth C site, C(39) is bonded in a distorted single-bond geometry to one C(37), one C(38), and one H(28) atom. The C(39)-H(28) bond length is 1.09 Å. In the thirty-ninth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(41), one O(5), and one O(6) atom. The C(40)-C(41) bond length is 1.49 Å. The C(40)-O(5) bond length is 1.27 Å. The C(40)-O(6) bond length is 1.28 Å. In the fortieth C site, C(41) is bonded in a trigonal planar geometry to one C(40), one C(42), and one C(46) atom. The C(41)-C(42) bond length is 1.40 Å. The C(41)-C(46) bond length is 1.40 Å. In the forty-first C site, C(42) is bonded in a distorted single-bond geometry to one C(41) and one H(29) atom. The C(42)-H(29) bond length is 1.09 Å. In the forty-second C site, C(43) is bonded in a distorted single-bond geometry to one C(44) and one H(30) atom. The C(43)-C(44) bond length is 1.40 Å. The C(43)-H(30) bond length is 1.09 Å. In the forty-third C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(47) atom. The C(44)-C(45) bond length is 1.40 Å. The C(44)-C(47) bond length is 1.48 Å. In the forty-fourth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(44), one C(46), and one H(31) atom. The C(45)-C(46) bond length is 1.39 Å. The C(45)-H(31) bond length is 1.09 Å. In the forty-fifth C site, C(46) is bonded in a distorted trigonal planar geometry to one C(41), one C(45), and one H(32) atom. The C(46)-H(32) bond length is 1.09 Å. In the forty-sixth C site, C(47) is bonded in a distorted bent 120 degrees geometry to one C(44), one O(7), and one O(8) atom. The C(47)-O(7) bond length is 1.30 Å. The C(47)-O(8) bond length is 1.27 Å. In the forty-seventh C site, C(48) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. The C(48)-O(11) bond length is 1.32 Å. The C(48)-O(12) bond length is 1.24 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(15) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(2), one C(15), and one C(16) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(3), one C(25), and one C(26) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(3), one C(1), and one C(5) atom. There are twenty-nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(24) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the nineteenth H site, H(22) is bonded in a single-bond geometry to one C(27) atom. In the twentieth H site, H(23) is bonded in a single-bond geometry to one C(30) atom. In the twenty-first H site, H(24) is bonded in a single-bond geometry to one C(31) atom. In the twenty-second H site, H(25) is bonded in a single-bond geometry to one C(33) atom. In the twenty-third H site, H(26) is bonded in a single-bond geometry to one C(34) atom. In the twenty-fourth H site, H(27) is bonded in a single-bond geometry to one C(38) atom. In the twenty-fifth H site, H(28) is bonded in a single-bond geometry to one C(39) atom. In the twenty-sixth H site, H(29) is bonded in a single-bond geometry to one C(42) atom. In the twenty-seventh H site, H(30) is bonded in a single-bond geometry to one C(43) atom. In the twenty-eighth H site, H(31) is bonded in a single-bond geometry to one C(45) atom. In the twenty-ninth H site, H(32) is bonded in a single-bond geometry to one C(46) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Co(1), one Co(2), and one C(28) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Co(2) and one C(28) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(3) and one C(35) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Co(4) and one C(35) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(40) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Co(2) and one C(40) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Co(3), one Co(4), and one C(47) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Co(3) and one C(47) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Co(1) and one C(36) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Co(2) and one C(36) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Co(3), one Co(4), and one C(48) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one C(48) atom. Linkers: 2 CCn1cnc(-c2ccc(-c3ccncc3)cc2)c1-c1ccc(-c2ccncc2)cc1 ,5 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 1 O=[C]O[Co]1O[C]O[Co]2(O[C]O1)O[C]O[Co](O[C]=O)O[C]O2 ,3 [Co]. The MOF has largest included sphere 7.07 A, density 1.10 g/cm3, surface area 4074.79 m2/g, accessible volume 0.39 cm3/g