RuC13N2H4O5F4CHC3HF2(CF)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules; two 1,3-difluoroprop-1-ene molecules; four fluoromethane molecules; and one RuC13N2H4O5F4 cluster. In the RuC13N2H4O5F4 cluster, Ru(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Ru(1)-N(1) bond length is 2.09 Å. The Ru(1)-O(1) bond length is 2.05 Å. The Ru(1)-O(2) bond length is 2.07 Å. The Ru(1)-O(3) bond length is 2.05 Å. The Ru(1)-O(4) bond length is 2.03 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(3) atom. The C(1)-C(4) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(2), and one O(4) atom. The C(2)-C(5) bond length is 1.48 Å. The C(2)-O(2) bond length is 1.28 Å. The C(2)-O(4) bond length is 1.28 Å. In the third C site, C(3) is bonded in a linear geometry to one N(1) and one N(2) atom. The C(3)-N(1) bond length is 1.19 Å. The C(3)-N(2) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(6), and one C(7) atom. The C(4)-C(6) bond length is 1.41 Å. The C(4)-C(7) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(8), and one C(9) atom. The C(5)-C(8) bond length is 1.40 Å. The C(5)-C(9) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a single-bond geometry to one C(4) and one F(1) atom. The C(6)-F(1) bond length is 1.35 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(4) and one F(2) atom. The C(7)-F(2) bond length is 1.35 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(5) and one F(3) atom. The C(8)-F(3) bond length is 1.35 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(5) and one F(4) atom. The C(9)-F(4) bond length is 1.35 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(15), one C(16), and one N(2) atom. The C(10)-C(15) bond length is 1.42 Å. The C(10)-C(16) bond length is 1.45 Å. The C(10)-N(2) bond length is 1.35 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one H(1) atom. The C(15)-H(1) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(10) and one O(5) atom. The C(16)-O(5) bond length is 1.35 Å. In the thirteenth C site, C(19) is bonded in a tetrahedral geometry to one H(4), one H(5), one H(6), and one O(5) atom. The C(19)-H(4) bond length is 1.09 Å. The C(19)-H(5) bond length is 1.10 Å. The C(19)-H(6) bond length is 1.10 Å. The C(19)-O(5) bond length is 1.43 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Ru(1) and one C(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(10) and one C(3) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(15) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(19) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(19) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(16) and one C(19) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(6) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(7) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(9) atom. Linkers: 4 [O]C(=O)c1c(F)c(F)cc(F)c1F ,1 COc1cc([N]C#N)c(OC)cc1[N]C#N. Metal clusters: 2 [Ru]. The MOF has largest included sphere 7.03 A, density 1.23 g/cm3, surface area 3907.20 m2/g, accessible volume 0.43 cm3/g