Zn2C25H16O11(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a Zn2C25H16O11 framework. In the Zn2C25H16O11 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(11), one O(2), one O(6), and one O(7) atom to form corner-sharing ZnO5 trigonal bipyramids. The Zn(1)-O(1) bond length is 2.08 Å. The Zn(1)-O(11) bond length is 2.21 Å. The Zn(1)-O(2) bond length is 1.99 Å. The Zn(1)-O(6) bond length is 1.98 Å. The Zn(1)-O(7) bond length is 2.02 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(10), one O(3), one O(5), and one O(8) atom to form corner-sharing ZnO5 trigonal bipyramids. The Zn(2)-O(1) bond length is 1.98 Å. The Zn(2)-O(10) bond length is 2.35 Å. The Zn(2)-O(3) bond length is 1.99 Å. The Zn(2)-O(5) bond length is 2.00 Å. The Zn(2)-O(8) bond length is 2.09 Å. There are twenty-five inequivalent C sites. In the first C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one H(6) atom. The C(13)-C(12) bond length is 1.40 Å. The C(13)-C(8) bond length is 1.40 Å. The C(13)-H(6) bond length is 1.09 Å. In the second C site, C(14) is bonded in a trigonal planar geometry to one C(10), one C(15), and one C(19) atom. The C(14)-C(10) bond length is 1.48 Å. The C(14)-C(15) bond length is 1.41 Å. The C(14)-C(19) bond length is 1.39 Å. In the third C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(7) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(7) bond length is 1.09 Å. In the fourth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(8) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(8) bond length is 1.09 Å. In the fifth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one O(4) atom. The C(17)-C(18) bond length is 1.42 Å. The C(17)-O(4) bond length is 1.35 Å. In the sixth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(20) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(20) bond length is 1.48 Å. In the seventh C site, C(19) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one H(9) atom. The C(19)-H(9) bond length is 1.09 Å. In the eighth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(5), and one O(6) atom. The C(20)-O(5) bond length is 1.30 Å. The C(20)-O(6) bond length is 1.27 Å. In the ninth C site, C(21) is bonded in a trigonal planar geometry to one C(12), one C(22), and one C(26) atom. The C(21)-C(12) bond length is 1.48 Å. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(26) bond length is 1.41 Å. In the tenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(10) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(10) bond length is 1.09 Å. In the eleventh C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(27) atom. The C(23)-C(24) bond length is 1.42 Å. The C(23)-C(27) bond length is 1.48 Å. In the twelfth C site, C(24) is bonded in a single-bond geometry to one C(23) and one O(9) atom. The C(24)-O(9) bond length is 1.36 Å. In the thirteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(21) and one H(12) atom. The C(26)-H(12) bond length is 1.09 Å. In the fourteenth C site, C(27) is bonded in a bent 120 degrees geometry to one C(23), one O(7), and one O(8) atom. The C(27)-O(7) bond length is 1.27 Å. The C(27)-O(8) bond length is 1.29 Å. In the fifteenth C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(2), and one O(3) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(2) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.29 Å. In the sixteenth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(7) bond length is 1.42 Å. In the seventeenth C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(1) bond length is 1.09 Å. In the eighteenth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(8) bond length is 1.48 Å. In the nineteenth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(5)-H(2) bond length is 1.09 Å. In the twentieth C site, C(7) is bonded in a single-bond geometry to one C(2) and one O(1) atom. The C(7)-O(1) bond length is 1.34 Å. In the twenty-first C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(4), and one C(9) atom. The C(8)-C(9) bond length is 1.41 Å. In the twenty-second C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(4) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(4) bond length is 1.09 Å. In the twenty-third C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(9) atom. The C(10)-C(11) bond length is 1.41 Å. In the twenty-fourth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(5) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(5) bond length is 1.09 Å. In the twenty-fifth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(21) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(13) is bonded in a distorted bent 150 degrees geometry to one O(4) and one O(5) atom. The H(13)-O(4) bond length is 1.00 Å. The H(13)-O(5) bond length is 1.68 Å. In the twelfth H site, H(14) is bonded in a bent 150 degrees geometry to one O(8) and one O(9) atom. The H(14)-O(8) bond length is 1.54 Å. The H(14)-O(9) bond length is 1.02 Å. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one O(10) atom. The H(15)-O(10) bond length is 0.97 Å. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one O(10) atom. The H(16)-O(10) bond length is 0.98 Å. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one O(11) atom. The H(17)-O(11) bond length is 0.97 Å. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one O(11) atom. The H(18)-O(11) bond length is 1.00 Å. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one C(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(17) and one H(13) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(20), and one H(13) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(20) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(27) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Zn(2), one C(27), and one H(14) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one C(24) and one H(14) atom. In the tenth O site, O(10) is bonded in a trigonal non-coplanar geometry to one Zn(2), one H(15), and one H(16) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Zn(1), one H(17), and one H(18) atom. Linkers: 4 [O]C(=O)c1cc(-c2cc(-c3ccc(O)c(C([O])=O)c3)cc(-c3ccc(O)c(C([O])=O)c3)c2)ccc1[O]. Metal clusters: 8 [Zn]. The MOF has largest included sphere 8.09 A, density 0.95 g/cm3, surface area 4206.33 m2/g, accessible volume 0.47 cm3/g