CdC10H6(NO2)2(CH)4(CH2)2CH2CO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four 02329_fluka molecules, two dimethyl ether molecules, and one CdC10H6(NO2)2 cluster. In the CdC10H6(NO2)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(3), one O(4), and two equivalent O(1) atoms. The Cd(1)-N(1) bond length is 2.34 Å. The Cd(1)-N(2) bond length is 2.36 Å. The Cd(1)-O(3) bond length is 2.54 Å. The Cd(1)-O(4) bond length is 2.32 Å. There is one shorter (2.26 Å) and one longer (2.44 Å) Cd(1)-O(1) bond length. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.28 Å. In the third C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(9) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-N(1) bond length is 1.34 Å. The C(9)-H(9) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(10) atom. The C(10)-H(10) bond length is 1.09 Å. In the fifth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(12,13) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(12,13) bond length is 1.09 Å. In the sixth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one N(1) atom. The C(13)-C(14) bond length is 1.49 Å. The C(13)-N(1) bond length is 1.35 Å. In the seventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one N(2) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-N(2) bond length is 1.35 Å. In the eighth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(12,13) atom. The C(15)-H(12,13) bond length is 1.09 Å. In the ninth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(15) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(15) bond length is 1.09 Å. In the tenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one N(2), and one H(16) atom. The C(18)-N(2) bond length is 1.34 Å. The C(18)-H(16) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(14), and one C(18) atom. There are five inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(12,13) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cd(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(8) atom. Linkers: 1 [O]C(=O)[C@H]1[C@H](C([O])=O)[C@H]2CC[C@@H]1O2 ,1 [O]C(=O)[C@@H]1[C@@H](C([O])=O)[C@H]2CC[C@@H]1O2. Metal clusters: 1 O=[C]O[Cd]1O[C]O1.O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 2.99 A, density 1.77 g/cm3, surface area 4018.57 m2/g, accessible volume 0.11 cm3/g