ZnC14N5H12O4CH(CH2)4 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, eight 02329_fluka molecules, and two ZnC14N5H12O4 clusters. In each ZnC14N5H12O4 cluster, Zn(1) is bonded in a 5-coordinate geometry to one N(3), two equivalent N(2), and two equivalent O(1) atoms. The Zn(1)-N(3) bond length is 2.17 Å. Both Zn(1)-N(2) bond lengths are 2.15 Å. Both Zn(1)-O(1) bond lengths are 1.97 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one H(2), one H(3), and one H(4) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-H(4) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one N(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-N(1) bond length is 1.37 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(3)-H(5) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one N(2) atom. The C(4)-C(5) bond length is 1.46 Å. The C(4)-N(2) bond length is 1.35 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one N(3) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-N(3) bond length is 1.34 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(6) atom. The C(6)-H(6) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(8)-O(1) bond length is 1.30 Å. The C(8)-O(2) bond length is 1.25 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one C(2), one N(2), and one H(1) atom. The N(1)-N(2) bond length is 1.34 Å. The N(1)-H(1) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(4), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1) and two equivalent C(5) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(8) atom. Linkers: 2 Cc1cc(-c2cccc(-c3cc(C)[nH]n3)n2)n[nH]1 ,2 [O]C(=O)CCCCC([O])=O. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.82 A, density 1.54 g/cm3, surface area 4844.73 m2/g, accessible volume 0.18 cm3/g