CdC11H8(N4S)2 crystallizes in the triclinic P-1 space group. Cd(1) is bonded in a distorted octahedral geometry to one N(1), one N(4), one N(6), one N(7), one S(1), and one S(2) atom. The Cd(1)-N(1) bond length is 2.37 Å. The Cd(1)-N(4) bond length is 2.50 Å. The Cd(1)-N(6) bond length is 2.31 Å. The Cd(1)-N(7) bond length is 2.25 Å. The Cd(1)-S(1) bond length is 2.74 Å. The Cd(1)-S(2) bond length is 2.76 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(2) atom. The C(1)-N(3) bond length is 1.35 Å. The C(1)-N(4) bond length is 1.33 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one N(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.42 Å. The C(2)-N(2) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(5) atom. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(7)-N(1) bond length is 1.39 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one N(2) atom. The C(8)-C(9) bond length is 1.49 Å. The C(8)-N(1) bond length is 1.33 Å. The C(8)-N(2) bond length is 1.36 Å. In the ninth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(8), one N(3), one H(7), and one H(8) atom. The C(9)-N(3) bond length is 1.46 Å. The C(9)-H(7) bond length is 1.09 Å. The C(9)-H(8) bond length is 1.10 Å. In the tenth C site, C(10) is bonded in a distorted linear geometry to one N(6) and one S(1) atom. The C(10)-N(6) bond length is 1.18 Å. The C(10)-S(1) bond length is 1.63 Å. In the eleventh C site, C(11) is bonded in a distorted linear geometry to one N(7) and one S(2) atom. The C(11)-N(7) bond length is 1.18 Å. The C(11)-S(2) bond length is 1.63 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(7), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(8), and one H(1) atom. The N(2)-H(1) bond length is 1.04 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(1), one C(9), and one N(8) atom. The N(3)-N(8) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one N(5) atom. The N(4)-N(5) bond length is 1.36 Å. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one N(4), one N(8), and one H(1) atom. The N(5)-N(8) bond length is 1.30 Å. The N(5)-H(1) bond length is 1.83 Å. In the sixth N site, N(6) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(10) atom. In the seventh N site, N(7) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(11) atom. In the eighth N site, N(8) is bonded in a water-like geometry to one N(3) and one N(5) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) and one N(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Cd(1) and one C(10) atom. In the second S site, S(2) is bonded in a water-like geometry to one Cd(1) and one C(11) atom. Linkers: 4 N#C[S]. Metal clusters: 2 [Cd]. The MOF has largest included sphere 1.99 A, density 1.94 g/cm3, surface area 3752.70 m2/g, accessible volume 0.09 cm3/g