(CH3)2ZnC8H4S(N2O)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a ZnC8H4S(N2O)2 framework. In the ZnC8H4S(N2O)2 framework, Zn(1) is bonded to one N(1), one N(2), one O(1), and one O(2) atom to form distorted ZnN2O2 tetrahedra that share corners with two equivalent S(1)O2 tetrahedra. The Zn(1)-N(1) bond length is 1.94 Å. The Zn(1)-N(2) bond length is 1.92 Å. The Zn(1)-O(1) bond length is 2.11 Å. The Zn(1)-O(2) bond length is 2.05 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(4), and one H(1) atom. The C(1)-N(1) bond length is 1.38 Å. The C(1)-N(4) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3), one C(4), and one N(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.44 Å. The C(2)-N(1) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one N(4) atom. The C(4)-N(4) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(3) atom. The C(5)-N(2) bond length is 1.37 Å. The C(5)-N(3) bond length is 1.33 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one C(8), and one N(3) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-C(8) bond length is 1.44 Å. The C(6)-N(3) bond length is 1.39 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(4) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(4) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one N(2) atom. The C(8)-N(2) bond length is 1.39 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(5), and one C(8) atom. In the third N site, N(3) is bonded in a water-like geometry to one C(5) and one C(6) atom. In the fourth N site, N(4) is bonded in a water-like geometry to one C(1) and one C(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. S(1) is bonded to one O(1) and one O(2) atom to form distorted SO2 tetrahedra that share corners with two equivalent Zn(1)N2O2 tetrahedra. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(2) bond length is 1.47 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one S(1) atom. Linkers: 1 C1=Nc2cc3c(cc2[N]1)[N]C=N3 ,3 C1=Nc2cc3c(cc2[N]1)N=C[N]3. Metal clusters: 4 [Zn]. The MOF has largest included sphere 4.32 A, density 1.31 g/cm3, surface area 4404.35 m2/g, accessible volume 0.33 cm3/g