CoC23N4H23O5(CH2)3CHCH2CO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, six 02329_fluka molecules, two dimethyl ether molecules, and two CoC23N4H23O5 clusters. In each CoC23N4H23O5 cluster, Co(1) is bonded in a tetrahedral geometry to one N(1), one N(4), one O(1), and one O(3) atom. The Co(1)-N(1) bond length is 1.98 Å. The Co(1)-N(4) bond length is 2.01 Å. The Co(1)-O(1) bond length is 1.94 Å. The Co(1)-O(3) bond length is 1.96 Å. There are twenty-three inequivalent C sites. In the first C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(5), and one H(6) atom. The C(3)-N(3) bond length is 1.46 Å. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(6) bond length is 1.10 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(6) atom. The C(4)-C(5) bond length is 1.50 Å. The C(4)-O(1) bond length is 1.30 Å. The C(4)-O(6) bond length is 1.25 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.40 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(7) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(7) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one H(8) atom. The C(7)-C(10) bond length is 1.40 Å. The C(7)-H(8) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one H(9) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(9) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(10) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-H(10) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one O(2) atom. The C(10)-O(2) bond length is 1.36 Å. In the ninth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one H(11), one H(12), and one O(2) atom. The C(11)-H(11) bond length is 1.10 Å. The C(11)-H(12) bond length is 1.10 Å. The C(11)-O(2) bond length is 1.44 Å. In the tenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(26), one N(2), and one N(4) atom. The C(14)-C(26) bond length is 1.48 Å. The C(14)-N(2) bond length is 1.37 Å. The C(14)-N(4) bond length is 1.34 Å. In the eleventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(3), and one O(4) atom. The C(15)-C(17) bond length is 1.49 Å. The C(15)-O(3) bond length is 1.30 Å. The C(15)-O(4) bond length is 1.26 Å. In the twelfth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one C(23), and one H(17) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(23) bond length is 1.39 Å. The C(16)-H(17) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(18) atom. The C(17)-C(18) bond length is 1.40 Å. In the fourteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(18) atom. The C(18)-H(18) bond length is 1.09 Å. In the fifteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(28), one N(4), and one H(20) atom. The C(21)-C(28) bond length is 1.37 Å. The C(21)-N(4) bond length is 1.39 Å. The C(21)-H(20) bond length is 1.08 Å. In the sixteenth C site, C(22) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent H(21,22) atoms. The C(22)-N(2) bond length is 1.46 Å. Both C(22)-H(21,22) bond lengths are 1.10 Å. In the seventeenth C site, C(23) is bonded in a distorted single-bond geometry to one C(16) and one H(23) atom. The C(23)-H(23) bond length is 1.09 Å. In the eighteenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(29), one N(1), and one N(3) atom. The C(24)-C(29) bond length is 1.48 Å. The C(24)-N(1) bond length is 1.34 Å. The C(24)-N(3) bond length is 1.36 Å. In the nineteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(27), one N(1), and one H(24) atom. The C(25)-C(27) bond length is 1.37 Å. The C(25)-N(1) bond length is 1.39 Å. The C(25)-H(24) bond length is 1.08 Å. In the twentieth C site, C(26) is bonded in a distorted trigonal non-coplanar geometry to one C(14), one H(25), one H(26), and one H(27) atom. The C(26)-H(25) bond length is 1.10 Å. The C(26)-H(26) bond length is 1.10 Å. The C(26)-H(27) bond length is 1.09 Å. In the twenty-first C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(25), one N(3), and one H(28) atom. The C(27)-N(3) bond length is 1.38 Å. The C(27)-H(28) bond length is 1.08 Å. In the twenty-second C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(2), and one H(29) atom. The C(28)-N(2) bond length is 1.38 Å. The C(28)-H(29) bond length is 1.08 Å. In the twenty-third C site, C(29) is bonded in a distorted trigonal non-coplanar geometry to one C(24), one H(30), one H(31), and one H(32) atom. The C(29)-H(30) bond length is 1.09 Å. The C(29)-H(31) bond length is 1.10 Å. The C(29)-H(32) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one C(24), one C(27), and one C(3) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(14), and one C(21) atom. In the third N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(24), and one C(25) atom. In the fourth N site, N(2) is bonded in a trigonal planar geometry to one C(14), one C(22), and one C(28) atom. There are twenty-two inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(21,22) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(24) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(25) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(26) is bonded in a single-bond geometry to one C(26) atom. In the seventeenth H site, H(27) is bonded in a single-bond geometry to one C(26) atom. In the eighteenth H site, H(28) is bonded in a single-bond geometry to one C(27) atom. In the nineteenth H site, H(29) is bonded in a single-bond geometry to one C(28) atom. In the twentieth H site, H(30) is bonded in a single-bond geometry to one C(29) atom. In the twenty-first H site, H(31) is bonded in a single-bond geometry to one C(29) atom. In the twenty-second H site, H(32) is bonded in a single-bond geometry to one C(29) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(10) and one C(11) atom. In the third O site, O(3) is bonded in a water-like geometry to one Co(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(15) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(4) atom. Linkers: 2 Cc1nccn1CCCCn1ccnc1C. Metal clusters: 2 O=[C]O[Co]O[C]=O. The MOF has largest included sphere 2.95 A, density 1.42 g/cm3, surface area 5254.24 m2/g, accessible volume 0.16 cm3/g