CuC18PN2H15I(CH)7(CH2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, six 02329_fluka molecules, two propylene molecules, and one CuC18PN2H15I cluster. In the CuC18PN2H15I cluster, Cu(1) is bonded in a 4-coordinate geometry to one P(1), one N(1), and two equivalent I(1) atoms. The Cu(1)-P(1) bond length is 2.22 Å. The Cu(1)-N(1) bond length is 2.03 Å. There is one shorter (2.66 Å) and one longer (2.69 Å) Cu(1)-I(1) bond length. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one P(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(3) bond length is 1.40 Å. The C(1)-P(1) bond length is 1.83 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(15), one C(5), and one P(1) atom. The C(4)-C(15) bond length is 1.40 Å. The C(4)-C(5) bond length is 1.40 Å. The C(4)-P(1) bond length is 1.83 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(22), one C(8), and one P(1) atom. The C(7)-C(22) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.40 Å. The C(7)-P(1) bond length is 1.83 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(6) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(7) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(7) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(21) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(21) bond length is 1.47 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(8) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(8) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(1), and one H(9) atom. The C(13)-N(1) bond length is 1.35 Å. The C(13)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(4) and one H(11) atom. The C(15)-H(11) bond length is 1.09 Å. In the fourteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(2), and one H(17) atom. The C(21)-N(2) bond length is 1.28 Å. The C(21)-H(17) bond length is 1.10 Å. In the fifteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(23), one C(7), and one H(18) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(18) bond length is 1.09 Å. In the sixteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one H(19) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-H(19) bond length is 1.09 Å. In the seventeenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(20) atom. The C(24)-H(20) bond length is 1.09 Å. In the eighteenth C site, C(28) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(27), and one H(28) atom. The C(28)-N(2) bond length is 1.45 Å. The C(28)-H(27) bond length is 1.10 Å. The C(28)-H(28) bond length is 1.11 Å. P(1) is bonded in a tetrahedral geometry to one Cu(1), one C(1), one C(4), and one C(7) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(9) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(21) and one C(28) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(27) is bonded in a single-bond geometry to one C(28) atom. In the fifteenth H site, H(28) is bonded in a single-bond geometry to one C(28) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 1 C(=N/CCCCCCCC/N=C/c1ccncc1)\c1ccncc1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 5.46 A, density 1.33 g/cm3, surface area 4553.86 m2/g, accessible volume 0.29 cm3/g