ZnC14H12(N3O2)2(CH)2CFC4H2OF is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 3-fluoro-2-methylprop-2-en-1-ol molecules, two fluoromethane molecules, and one ZnC14H12(N3O2)2 cluster. In the ZnC14H12(N3O2)2 cluster, Zn(1) is bonded in a 5-coordinate geometry to one N(1), one N(6), one O(1), one O(2), and one O(3) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-N(6) bond length is 2.02 Å. The Zn(1)-O(1) bond length is 2.47 Å. The Zn(1)-O(2) bond length is 2.01 Å. The Zn(1)-O(3) bond length is 2.00 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(2) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-N(2) bond length is 1.32 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(3) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(3) bond length is 1.34 Å. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(4), and one H(5) atom. The C(3)-N(3) bond length is 1.45 Å. The C(3)-H(4) bond length is 1.10 Å. The C(3)-H(5) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(6), and one H(7) atom. The C(5)-N(4) bond length is 1.46 Å. The C(5)-H(6) bond length is 1.09 Å. The C(5)-H(7) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(8) atom. The C(6)-N(4) bond length is 1.34 Å. The C(6)-N(6) bond length is 1.34 Å. The C(6)-H(8) bond length is 1.08 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(9) atom. The C(7)-N(5) bond length is 1.32 Å. The C(7)-N(6) bond length is 1.37 Å. The C(7)-H(9) bond length is 1.09 Å. In the seventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(3), and one O(4) atom. The C(14)-C(15) bond length is 1.50 Å. The C(14)-O(3) bond length is 1.28 Å. The C(14)-O(4) bond length is 1.26 Å. In the eighth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(17) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(17) bond length is 1.40 Å. In the ninth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(13) atom. The C(16)-H(13) bond length is 1.09 Å. In the tenth C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one H(14) atom. The C(17)-H(14) bond length is 1.09 Å. In the eleventh C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(1), and one O(2) atom. The C(18)-C(19) bond length is 1.49 Å. The C(18)-O(1) bond length is 1.26 Å. The C(18)-O(2) bond length is 1.30 Å. In the twelfth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(21) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-C(21) bond length is 1.40 Å. In the thirteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one H(15) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(15) bond length is 1.09 Å. In the fourteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(19), one C(20), and one H(16) atom. The C(21)-H(16) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(1) and one N(3) atom. The N(2)-N(3) bond length is 1.37 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one N(2) atom. In the fourth N site, N(4) is bonded in a 2-coordinate geometry to one C(5), one C(6), and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(7) and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(1), one C(6), and one C(7) atom. There are twelve inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Zn(1) and one C(18) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(18) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(14) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(14) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.98 A, density 1.65 g/cm3, surface area 4105.03 m2/g, accessible volume 0.16 cm3/g