CuC12H22O5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CuC12H22O5 cluster. Cu(1) is bonded in a square pyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. The Cu(1)-O(1) bond length is 2.00 Å. The Cu(1)-O(2) bond length is 1.99 Å. The Cu(1)-O(3) bond length is 1.98 Å. The Cu(1)-O(4) bond length is 1.99 Å. The Cu(1)-O(5) bond length is 2.25 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.54 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a tetrahedral geometry to one C(1), one C(3), one C(4), and one C(5) atom. The C(2)-C(3) bond length is 1.53 Å. The C(2)-C(4) bond length is 1.54 Å. The C(2)-C(5) bond length is 1.54 Å. In the third C site, C(3) is bonded in a trigonal non-coplanar geometry to one C(2); one H(2); and two equivalent H(1,3) atoms. The C(3)-H(2) bond length is 1.10 Å. Both C(3)-H(1,3) bond lengths are 1.10 Å. In the fourth C site, C(4) is bonded in a trigonal non-coplanar geometry to one C(2), one H(4), one H(5), and one H(6) atom. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. The C(4)-H(6) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a trigonal non-coplanar geometry to one C(2), one H(7), one H(8), and one H(9) atom. The C(5)-H(7) bond length is 1.10 Å. The C(5)-H(8) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(4) atom. The C(6)-C(7) bond length is 1.54 Å. The C(6)-O(3) bond length is 1.27 Å. The C(6)-O(4) bond length is 1.27 Å. In the seventh C site, C(7) is bonded in a tetrahedral geometry to one C(10), one C(6), one C(8), and one C(9) atom. The C(7)-C(10) bond length is 1.54 Å. The C(7)-C(8) bond length is 1.54 Å. The C(7)-C(9) bond length is 1.53 Å. In the eighth C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(7), one H(10), one H(11), and one H(12) atom. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(11) bond length is 1.10 Å. The C(8)-H(12) bond length is 1.10 Å. In the ninth C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(7), one H(13), one H(14), and one H(15) atom. The C(9)-H(13) bond length is 1.10 Å. The C(9)-H(14) bond length is 1.10 Å. The C(9)-H(15) bond length is 1.10 Å. In the tenth C site, C(10) is bonded in a trigonal non-coplanar geometry to one C(7), one H(16), one H(17), and one H(18) atom. The C(10)-H(16) bond length is 1.10 Å. The C(10)-H(17) bond length is 1.10 Å. The C(10)-H(18) bond length is 1.10 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one H(19,21); one H(20,22); and one O(5) atom. The C(11)-H(19,21) bond length is 1.10 Å. The C(11)-H(20,22) bond length is 1.10 Å. The C(11)-O(5) bond length is 1.44 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one H(19,21); one H(20,22); and one O(5) atom. The C(12)-H(19,21) bond length is 1.10 Å. The C(12)-H(20,22) bond length is 1.10 Å. The C(12)-O(5) bond length is 1.44 Å. There are nineteen inequivalent H sites. In the first H site, H(1,3) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(8) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(9) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(9) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(10) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(10) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(10) atom. In the eighteenth H site, H(19,21) is bonded in a single-bond geometry to one C(11) atom. In the nineteenth H site, H(20,22) is bonded in a single-bond geometry to one C(11) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(6) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(6) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(11), and one C(12) atom. Linkers: 1 C1COCCO1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.42 A, density 1.34 g/cm3, surface area 5698.18 m2/g, accessible volume 0.19 cm3/g