CdC19P2H17Cl2(CH)7(CH3)2C3H2O2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of fourteen 02329_fluka molecules; four 02329_fluka molecules; two 1,3-dioxolane molecules; and two CdC19P2H17Cl2 clusters. In each CdC19P2H17Cl2 cluster, Cd(1) is bonded in a tetrahedral geometry to one P(1), one P(2), one Cl(1), and one Cl(2) atom. The Cd(1)-P(1) bond length is 2.63 Å. The Cd(1)-P(2) bond length is 2.58 Å. The Cd(1)-Cl(1) bond length is 2.49 Å. The Cd(1)-Cl(2) bond length is 2.47 Å. There are nineteen inequivalent C sites. In the first C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one C(31), and one H(31) atom. The C(30)-C(29) bond length is 1.40 Å. The C(30)-C(31) bond length is 1.39 Å. The C(30)-H(31) bond length is 1.09 Å. In the second C site, C(31) is bonded in a distorted trigonal planar geometry to one C(26), one C(30), and one H(32) atom. The C(31)-C(26) bond length is 1.41 Å. The C(31)-H(32) bond length is 1.09 Å. In the third C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one P(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-P(1) bond length is 1.82 Å. In the fourth C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(6) atom. The C(7)-C(12) bond length is 1.40 Å. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(6) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(7) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(7) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(9)-H(8) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-H(10) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(7), and one P(1) atom. The C(12)-P(1) bond length is 1.82 Å. In the eleventh C site, C(13) is bonded in a distorted water-like geometry to one P(1), one H(11), and one H(12) atom. The C(13)-P(1) bond length is 1.84 Å. The C(13)-H(11) bond length is 1.10 Å. The C(13)-H(12) bond length is 1.10 Å. In the twelfth C site, C(19) is bonded in a distorted water-like geometry to one P(2), one H(21), and one H(22) atom. The C(19)-P(2) bond length is 1.84 Å. The C(19)-H(21) bond length is 1.10 Å. The C(19)-H(22) bond length is 1.10 Å. In the thirteenth C site, C(20) is bonded in a trigonal planar geometry to one C(21), one C(25), and one P(2) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(25) bond length is 1.40 Å. The C(20)-P(2) bond length is 1.82 Å. In the fourteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(23) atom. The C(21)-H(23) bond length is 1.09 Å. In the fifteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(20) and one H(27) atom. The C(25)-H(27) bond length is 1.09 Å. In the sixteenth C site, C(26) is bonded in a trigonal planar geometry to one C(27), one C(31), and one P(2) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-P(2) bond length is 1.82 Å. In the seventeenth C site, C(27) is bonded in a distorted single-bond geometry to one C(26), one C(28), and one H(28) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-H(28) bond length is 1.09 Å. In the eighteenth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one C(29), and one H(29) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-H(29) bond length is 1.09 Å. In the nineteenth C site, C(29) is bonded in a distorted single-bond geometry to one C(28), one C(30), and one H(30) atom. The C(29)-H(30) bond length is 1.09 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one Cd(1), one C(1), one C(12), and one C(13) atom to form distorted corner-sharing PCdC3 tetrahedra. In the second P site, P(2) is bonded to one Cd(1), one C(19), one C(20), and one C(26) atom to form distorted corner-sharing PCdC3 tetrahedra. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(21) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(23) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(27) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(28) is bonded in a single-bond geometry to one C(27) atom. In the fourteenth H site, H(29) is bonded in a single-bond geometry to one C(28) atom. In the fifteenth H site, H(30) is bonded in a single-bond geometry to one C(29) atom. In the sixteenth H site, H(31) is bonded in a single-bond geometry to one C(30) atom. In the seventeenth H site, H(32) is bonded in a single-bond geometry to one C(31) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cd(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cd(1) atom. Linkers: 2 CC1(C)O[C@@H](CP(c2ccccc2)c2ccccc2)[C@H](CP(c2ccccc2)c2ccccc2)O1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 2.45 A, density 1.54 g/cm3, surface area 4924.95 m2/g, accessible volume 0.19 cm3/g