ZnC7N8H3CH crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a ZnC7N8H3 framework. In the ZnC7N8H3 framework, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one N(5), and one N(8) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-N(3) bond length is 2.02 Å. The Zn(1)-N(5) bond length is 2.00 Å. The Zn(1)-N(8) bond length is 2.01 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.46 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(8) bond length is 1.46 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted water-like geometry to one C(1), one N(1), and one N(4) atom. The C(7)-N(1) bond length is 1.36 Å. The C(7)-N(4) bond length is 1.34 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(3), one N(5), and one N(8) atom. The C(8)-N(5) bond length is 1.35 Å. The C(8)-N(8) bond length is 1.35 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Zn(1), one C(7), and one N(2) atom. The N(1)-N(2) bond length is 1.34 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.32 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Zn(1), one N(2), and one N(4) atom. The N(3)-N(4) bond length is 1.34 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one C(7) and one N(3) atom. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one Zn(1), one C(8), and one N(6) atom. The N(5)-N(6) bond length is 1.36 Å. In the sixth N site, N(6) is bonded in a water-like geometry to one N(5) and one N(7) atom. The N(6)-N(7) bond length is 1.30 Å. In the seventh N site, N(7) is bonded in a water-like geometry to one N(6) and one N(8) atom. The N(7)-N(8) bond length is 1.36 Å. In the eighth N site, N(8) is bonded in a 3-coordinate geometry to one Zn(1), one C(8), and one N(7) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. Linkers: 4 c1cc(C2=NN=N[N]2)cc(C2=NN=N[N]2)c1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 3.13 A, density 1.84 g/cm3, surface area 3863.40 m2/g, accessible volume 0.14 cm3/g