ZnC5H9(NO2)2(CH3)2C3NH6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two trimethylamine molecules, and two ZnC5H9(NO2)2 clusters. In each ZnC5H9(NO2)2 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(3), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 2.12 Å. The Zn(1)-N(3) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 1.99 Å. The Zn(1)-O(3) bond length is 2.02 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(3)-O(3) bond length is 1.30 Å. The C(3)-O(4) bond length is 1.25 Å. In the third C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(7), and one H(8) atom. The C(5)-N(1) bond length is 1.48 Å. The C(5)-H(7) bond length is 1.10 Å. The C(5)-H(8) bond length is 1.10 Å. In the fourth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(13), and one H(14) atom. The C(8)-N(1) bond length is 1.48 Å. The C(8)-H(13) bond length is 1.10 Å. The C(8)-H(14) bond length is 1.09 Å. In the fifth C site, C(10) is bonded in a 3-coordinate geometry to one N(3), one H(17), and one H(18) atom. The C(10)-N(3) bond length is 1.48 Å. The C(10)-H(17) bond length is 1.10 Å. The C(10)-H(18) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Zn(1), one C(5), one C(8), and one H(19) atom. The N(1)-H(19) bond length is 1.04 Å. In the second N site, N(3) is bonded in a distorted tetrahedral geometry to one Zn(1), one C(10), one H(20), and one H(21) atom. The N(3)-H(20) bond length is 1.04 Å. The N(3)-H(21) bond length is 1.03 Å. There are nine inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one N(1) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one N(3) atom. In the ninth H site, H(21) is bonded in a single-bond geometry to one N(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(3) atom. Linkers: 2 NCCN1CCNCC1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.63 A, density 1.64 g/cm3, surface area 5118.70 m2/g, accessible volume 0.10 cm3/g