(MnC2H6O7)4(CH)2C2O(C4H2O)3 crystallizes in the triclinic P1 space group. The structure consists of two 02329_fluka molecules, one dimethyl ether molecule, and three furan molecules inside a MnC2H6O7 framework. In the MnC2H6O7 framework, there are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(1), one O(21), one O(28), one O(29), one O(5), and one O(7) atom. The Mn(1)-O(1) bond length is 2.21 Å. The Mn(1)-O(21) bond length is 2.10 Å. The Mn(1)-O(28) bond length is 2.10 Å. The Mn(1)-O(29) bond length is 2.10 Å. The Mn(1)-O(5) bond length is 2.55 Å. The Mn(1)-O(7) bond length is 2.14 Å. In the second Mn site, Mn(2) is bonded to one O(2), one O(22), one O(27), one O(30), and one O(8) atom to form distorted corner-sharing MnO5 trigonal bipyramids. The Mn(2)-O(2) bond length is 2.13 Å. The Mn(2)-O(22) bond length is 2.09 Å. The Mn(2)-O(27) bond length is 2.09 Å. The Mn(2)-O(30) bond length is 2.11 Å. The Mn(2)-O(8) bond length is 2.18 Å. In the third Mn site, Mn(3) is bonded in a 6-coordinate geometry to one O(23), one O(26), one O(3), one O(31), one O(5), and one O(7) atom. The Mn(3)-O(23) bond length is 2.10 Å. The Mn(3)-O(26) bond length is 2.10 Å. The Mn(3)-O(3) bond length is 2.22 Å. The Mn(3)-O(31) bond length is 2.11 Å. The Mn(3)-O(5) bond length is 2.15 Å. The Mn(3)-O(7) bond length is 2.55 Å. In the fourth Mn site, Mn(4) is bonded to one O(24), one O(25), one O(32), one O(4), one O(6), and one O(8) atom to form distorted corner-sharing MnO6 pentagonal pyramids. The Mn(4)-O(24) bond length is 1.99 Å. The Mn(4)-O(25) bond length is 1.98 Å. The Mn(4)-O(32) bond length is 2.04 Å. The Mn(4)-O(4) bond length is 1.98 Å. The Mn(4)-O(6) bond length is 1.97 Å. The Mn(4)-O(8) bond length is 2.19 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(5) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(5) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(6) atom. The C(2)-O(2) bond length is 1.29 Å. The C(2)-O(6) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(7) atom. The C(3)-O(3) bond length is 1.28 Å. The C(3)-O(7) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(8) atom. The C(4)-O(4) bond length is 1.30 Å. The C(4)-O(8) bond length is 1.30 Å. In the fifth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(9) atom. The C(21)-O(13) bond length is 1.28 Å. The C(21)-O(9) bond length is 1.28 Å. In the sixth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(14) atom. The C(22)-O(10) bond length is 1.29 Å. The C(22)-O(14) bond length is 1.27 Å. In the seventh C site, C(23) is bonded in a bent 120 degrees geometry to one O(11) and one O(15) atom. The C(23)-O(11) bond length is 1.28 Å. The C(23)-O(15) bond length is 1.28 Å. In the eighth C site, C(24) is bonded in a bent 120 degrees geometry to one O(12) and one O(16) atom. The C(24)-O(12) bond length is 1.29 Å. The C(24)-O(16) bond length is 1.28 Å. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(16) and one O(21) atom. The H(1)-O(16) bond length is 1.67 Å. The H(1)-O(21) bond length is 1.00 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(15) and one O(22) atom. The H(2)-O(15) bond length is 1.63 Å. The H(2)-O(22) bond length is 1.00 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(14) and one O(23) atom. The H(3)-O(14) bond length is 1.69 Å. The H(3)-O(23) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(13) and one O(24) atom. The H(4)-O(13) bond length is 1.66 Å. The H(4)-O(24) bond length is 1.00 Å. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one O(13) and one O(25) atom. The H(5)-O(13) bond length is 1.67 Å. The H(5)-O(25) bond length is 1.00 Å. In the sixth H site, H(6) is bonded in a distorted single-bond geometry to one O(14) and one O(26) atom. The H(6)-O(14) bond length is 1.68 Å. The H(6)-O(26) bond length is 0.99 Å. In the seventh H site, H(7) is bonded in a distorted single-bond geometry to one O(15) and one O(27) atom. The H(7)-O(15) bond length is 1.66 Å. The H(7)-O(27) bond length is 0.99 Å. In the eighth H site, H(8) is bonded in a distorted single-bond geometry to one O(16) and one O(28) atom. The H(8)-O(16) bond length is 1.68 Å. The H(8)-O(28) bond length is 1.00 Å. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(21) atom. The H(9)-O(21) bond length is 0.99 Å. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(22) atom. The H(10)-O(22) bond length is 0.99 Å. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(23) atom. The H(11)-O(23) bond length is 0.99 Å. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(24) atom. The H(12)-O(24) bond length is 0.99 Å. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one O(25) atom. The H(13)-O(25) bond length is 0.99 Å. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one O(26) atom. The H(14)-O(26) bond length is 0.99 Å. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one O(27) atom. The H(15)-O(27) bond length is 0.99 Å. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one O(28) atom. The H(16)-O(28) bond length is 0.99 Å. In the seventeenth H site, H(17) is bonded in a distorted single-bond geometry to one O(29) and one O(3) atom. The H(17)-O(29) bond length is 0.99 Å. The H(17)-O(3) bond length is 1.66 Å. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one O(30) and one O(4) atom. The H(18)-O(30) bond length is 0.99 Å. The H(18)-O(4) bond length is 1.72 Å. In the nineteenth H site, H(19) is bonded in a distorted single-bond geometry to one O(1) and one O(31) atom. The H(19)-O(1) bond length is 1.68 Å. The H(19)-O(31) bond length is 0.99 Å. In the twentieth H site, H(20) is bonded in a single-bond geometry to one O(32) atom. The H(20)-O(32) bond length is 0.99 Å. In the twenty-first H site, H(21) is bonded in a distorted single-bond geometry to one O(11) and one O(29) atom. The H(21)-O(11) bond length is 1.67 Å. The H(21)-O(29) bond length is 1.00 Å. In the twenty-second H site, H(22) is bonded in a distorted linear geometry to one O(12) and one O(30) atom. The H(22)-O(12) bond length is 1.64 Å. The H(22)-O(30) bond length is 1.00 Å. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one O(31) atom. The H(23)-O(31) bond length is 0.99 Å. In the twenty-fourth H site, H(24) is bonded in a distorted single-bond geometry to one O(10) and one O(32) atom. The H(24)-O(10) bond length is 1.65 Å. The H(24)-O(32) bond length is 1.01 Å. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mn(1), one C(1), and one H(19) atom. In the second O site, O(2) is bonded in a water-like geometry to one Mn(2) and one C(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mn(3), one C(3), and one H(17) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mn(4), one C(4), and one H(18) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(3), and one C(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mn(4) and one C(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(3), and one C(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Mn(2), one Mn(4), and one C(4) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one C(21) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one C(22) and one H(24) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one C(23) and one H(21) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one C(24) and one H(22) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one C(21), one H(4), and one H(5) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one C(22), one H(3), and one H(6) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one C(23), one H(2), and one H(7) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one C(24), one H(1), and one H(8) atom. In the seventeenth O site, O(21) is bonded in a distorted trigonal planar geometry to one Mn(1), one H(1), and one H(9) atom. In the eighteenth O site, O(22) is bonded in a distorted trigonal planar geometry to one Mn(2), one H(10), and one H(2) atom. In the nineteenth O site, O(23) is bonded in a distorted trigonal planar geometry to one Mn(3), one H(11), and one H(3) atom. In the twentieth O site, O(24) is bonded in a distorted trigonal planar geometry to one Mn(4), one H(12), and one H(4) atom. In the twenty-first O site, O(25) is bonded in a distorted trigonal planar geometry to one Mn(4), one H(13), and one H(5) atom. In the twenty-second O site, O(26) is bonded in a distorted trigonal planar geometry to one Mn(3), one H(14), and one H(6) atom. In the twenty-third O site, O(27) is bonded in a distorted trigonal planar geometry to one Mn(2), one H(15), and one H(7) atom. In the twenty-fourth O site, O(28) is bonded in a distorted trigonal planar geometry to one Mn(1), one H(16), and one H(8) atom. In the twenty-fifth O site, O(29) is bonded in a distorted trigonal planar geometry to one Mn(1), one H(17), and one H(21) atom. In the twenty-sixth O site, O(30) is bonded in a distorted trigonal planar geometry to one Mn(2), one H(18), and one H(22) atom. In the twenty-seventh O site, O(31) is bonded in a distorted trigonal planar geometry to one Mn(3), one H(19), and one H(23) atom. In the twenty-eighth O site, O(32) is bonded in a distorted trigonal planar geometry to one Mn(4), one H(20), and one H(24) atom. Linkers: 4 [O]C(=O)c1ccc(C([O])=O)o1. Metal clusters: 4 [Mn]. The MOF has largest included sphere 2.01 A, density 1.92 g/cm3, surface area 3671.32 m2/g, accessible volume 0.11 cm3/g