ZnC6H4(NO2)2(CH)16 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight isobutylene molecules, four o-xylene molecules, and four ZnC6H4(NO2)2 clusters. In each ZnC6H4(NO2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 2.05 Å. The Zn(1)-N(2) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 1.94 Å. The Zn(1)-O(3) bond length is 1.95 Å. There are six inequivalent C sites. In the first C site, C(21) is bonded in a distorted trigonal planar geometry to one N(2) and one H(18) atom. The C(21)-N(2) bond length is 1.35 Å. The C(21)-H(18) bond length is 1.09 Å. In the second C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(12) atom. The C(15)-N(1) bond length is 1.35 Å. The C(15)-H(12) bond length is 1.09 Å. In the third C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(10)-O(3) bond length is 1.31 Å. The C(10)-O(4) bond length is 1.24 Å. In the fourth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(8)-O(1) bond length is 1.30 Å. The C(8)-O(2) bond length is 1.24 Å. In the fifth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(15) atom. The C(17)-N(2) bond length is 1.35 Å. The C(17)-H(15) bond length is 1.09 Å. In the sixth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(9) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(15) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(17), and one C(21) atom. There are four inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(18) is bonded in a single-bond geometry to one C(21) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one C(10) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(10) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one C(8) atom. Linkers: 4 c1cc(CCc2ccncc2)ccn1 ,4 [O]C(=O)Cc1ccccc1CC([O])=O ,2 [CH]=C(/C=C\[N])CCc1ccncc1. Metal clusters: 4 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.63 A, density 1.34 g/cm3, surface area 5216.23 m2/g, accessible volume 0.28 cm3/g