MnC12H8(NO2)2(CH2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and one MnC12H8(NO2)2 cluster. In the MnC12H8(NO2)2 cluster, Mn(1) is bonded in a distorted pentagonal pyramidal geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Mn(1)-N(1) bond length is 2.23 Å. The Mn(1)-N(2) bond length is 2.24 Å. The Mn(1)-O(1) bond length is 2.11 Å. The Mn(1)-O(2) bond length is 2.15 Å. The Mn(1)-O(3) bond length is 2.18 Å. The Mn(1)-O(4) bond length is 2.45 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(9) atom. The C(3)-C(4) bond length is 1.48 Å. The C(3)-C(9) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(8) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(2), and one H(4) atom. The C(6)-N(2) bond length is 1.35 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one H(5) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-N(2) bond length is 1.35 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(4), one C(7), and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(3) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one N(1) and one H(8) atom. The C(10)-N(1) bond length is 1.35 Å. The C(10)-H(8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(11)-O(1) bond length is 1.27 Å. The C(11)-O(2) bond length is 1.27 Å. In the twelfth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(15)-O(3) bond length is 1.28 Å. The C(15)-O(4) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(1), one C(1), and one C(10) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(1), one C(6), and one C(7) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(11) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(11) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Mn(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Mn(1) and one C(15) atom. Linkers: 2 [O]C(=O)CCCC([O])=O ,2 c1cc(-c2ccncc2)ccn1. Metal clusters: 1 [C]1O[Mn]2(O1)O[C]O[Mn]1(O[C]O1)O[C]O2. The MOF has largest included sphere 2.02 A, density 1.61 g/cm3, surface area 4214.20 m2/g, accessible volume 0.10 cm3/g