(CH2)2ZnC2H8(NCl)2(C3NH6)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, eight trimethylamine molecules, and four ZnC2H8(NCl)2 clusters. In each ZnC2H8(NCl)2 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent Cl(1) atoms. Both Zn(1)-N(1) bond lengths are 2.08 Å. Both Zn(1)-Cl(1) bond lengths are 2.25 Å. C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(6), and one H(9) atom. The C(3)-N(1) bond length is 1.49 Å. The C(3)-H(6) bond length is 1.10 Å. The C(3)-H(9) bond length is 1.10 Å. N(1) is bonded to one Zn(1), one C(3), one H(2), and one H(3) atom to form distorted corner-sharing NZnH2C tetrahedra. The N(1)-H(2) bond length is 1.02 Å. The N(1)-H(3) bond length is 1.03 Å. There are four inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 2 [CH]CCN1CCN(CCCN)CC1 ,2 NCCCN1CCN(CCCN)CC1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.92 A, density 1.47 g/cm3, surface area 5306.59 m2/g, accessible volume 0.15 cm3/g