(CH3CN)2ZnC6N2H5O4Cl is Tenorite structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four 3-methyl-1 h-imidazole molecules and four ZnC6N2H5O4Cl clusters. In each ZnC6N2H5O4Cl cluster, Zn(1) is bonded in a distorted tetrahedral geometry to one N(1), one O(2), one O(3), and one Cl(1) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-O(2) bond length is 2.02 Å. The Zn(1)-O(3) bond length is 1.99 Å. The Zn(1)-Cl(1) bond length is 2.23 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.29 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(2), and one H(3) atom. The C(2)-N(2) bond length is 1.44 Å. The C(2)-H(2) bond length is 1.10 Å. The C(2)-H(3) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(4) atom. The C(3)-C(4) bond length is 1.37 Å. The C(3)-N(2) bond length is 1.38 Å. The C(3)-H(4) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(5) atom. The C(4)-N(1) bond length is 1.39 Å. The C(4)-H(5) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(6) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-N(2) bond length is 1.35 Å. The C(5)-H(6) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(6)-O(3) bond length is 1.29 Å. The C(6)-O(4) bond length is 1.24 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(4), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(5) atom. There are five inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(6) atom. Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 2 [O]C(=O)Cn1ccnc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.76 A, density 1.80 g/cm3, surface area 4618.33 m2/g, accessible volume 0.11 cm3/g