NaZn3C19H13O17 crystallizes in the triclinic P1 space group. Na(1) is bonded to one O(10), one O(12), one O(16), one O(3), one O(4), and one O(9) atom to form distorted NaO6 octahedra that share  an edgeedge with one Zn(2)O5 trigonal bipyramid and  an edgeedge with one Zn(3)O5 trigonal bipyramid. The Na(1)-O(10) bond length is 2.53 Å. The Na(1)-O(12) bond length is 2.47 Å. The Na(1)-O(16) bond length is 2.40 Å. The Na(1)-O(3) bond length is 2.41 Å. The Na(1)-O(4) bond length is 2.29 Å. The Na(1)-O(9) bond length is 2.53 Å. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to one O(1), one O(14), one O(2), one O(6), and one O(7) atom. The Zn(1)-O(1) bond length is 1.99 Å. The Zn(1)-O(14) bond length is 2.06 Å. The Zn(1)-O(2) bond length is 2.02 Å. The Zn(1)-O(6) bond length is 2.12 Å. The Zn(1)-O(7) bond length is 2.23 Å. In the second Zn site, Zn(2) is bonded to one O(10), one O(14), one O(3), one O(5), and one O(7) atom to form ZnO5 trigonal bipyramids that share  an edgeedge with one Na(1)O6 octahedra. The Zn(2)-O(10) bond length is 2.05 Å. The Zn(2)-O(14) bond length is 2.12 Å. The Zn(2)-O(3) bond length is 2.07 Å. The Zn(2)-O(5) bond length is 1.98 Å. The Zn(2)-O(7) bond length is 2.09 Å. In the third Zn site, Zn(3) is bonded to one O(11), one O(12), one O(6), one O(8), and one O(9) atom to form distorted ZnO5 trigonal bipyramids that share  an edgeedge with one Na(1)O6 octahedra. The Zn(3)-O(11) bond length is 2.25 Å. The Zn(3)-O(12) bond length is 2.21 Å. The Zn(3)-O(6) bond length is 2.10 Å. The Zn(3)-O(8) bond length is 1.95 Å. The Zn(3)-O(9) bond length is 2.04 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(7), one C(8), and one C(9) atom. The C(1)-C(7) bond length is 1.49 Å. The C(1)-C(8) bond length is 1.40 Å. The C(1)-C(9) bond length is 1.40 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(10), and one O(2) atom. The C(2)-C(16) bond length is 1.50 Å. The C(2)-O(10) bond length is 1.27 Å. The C(2)-O(2) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(1), and one O(9) atom. The C(3)-C(18) bond length is 1.50 Å. The C(3)-O(1) bond length is 1.27 Å. The C(3)-O(9) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(4), and one O(8) atom. The C(4)-C(14) bond length is 1.50 Å. The C(4)-O(4) bond length is 1.25 Å. The C(4)-O(8) bond length is 1.30 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(15), and one O(7) atom. The C(5)-C(13) bond length is 1.49 Å. The C(5)-O(15) bond length is 1.26 Å. The C(5)-O(7) bond length is 1.30 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(13), one C(16), and one H(7) atom. The C(6)-C(13) bond length is 1.39 Å. The C(6)-C(16) bond length is 1.40 Å. The C(6)-H(7) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(13), and one O(6) atom. The C(7)-O(13) bond length is 1.25 Å. The C(7)-O(6) bond length is 1.31 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(1), one C(14), and one H(8) atom. The C(8)-C(14) bond length is 1.40 Å. The C(8)-H(8) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(1), one C(18), and one H(9) atom. The C(9)-C(18) bond length is 1.40 Å. The C(9)-H(9) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(10) atom. The C(10)-C(13) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.39 Å. The C(10)-H(10) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(15), one C(16), and one H(11) atom. The C(11)-C(15) bond length is 1.40 Å. The C(11)-C(16) bond length is 1.40 Å. The C(11)-H(11) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one H(12) atom. The C(12)-C(14) bond length is 1.40 Å. The C(12)-C(18) bond length is 1.40 Å. The C(12)-H(12) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(10), one C(5), and one C(6) atom. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(4), and one C(8) atom. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(19) atom. The C(15)-C(19) bond length is 1.50 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(11), one C(2), and one C(6) atom. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one H(13), one O(14), and one O(17) atom. The C(17)-H(13) bond length is 1.11 Å. The C(17)-O(14) bond length is 1.29 Å. The C(17)-O(17) bond length is 1.24 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(9) atom. In the nineteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(16), and one O(5) atom. The C(19)-O(16) bond length is 1.27 Å. The C(19)-O(5) bond length is 1.28 Å. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(13) and one O(3) atom. The H(1)-O(13) bond length is 1.63 Å. The H(1)-O(3) bond length is 1.00 Å. In the second H site, H(2) is bonded in a distorted linear geometry to one O(17) and one O(3) atom. The H(2)-O(17) bond length is 1.54 Å. The H(2)-O(3) bond length is 1.03 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(11) atom. The H(3)-O(11) bond length is 0.97 Å. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(11) and one O(16) atom. The H(4)-O(11) bond length is 1.02 Å. The H(4)-O(16) bond length is 1.64 Å. In the fifth H site, H(5) is bonded in a linear geometry to one O(12) and one O(15) atom. The H(5)-O(12) bond length is 1.03 Å. The H(5)-O(15) bond length is 1.53 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(12) atom. The H(6)-O(12) bond length is 0.97 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. There are seventeen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Na(1), one Zn(2), one H(1), and one H(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Na(1) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(19) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(3), and one C(7) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Zn(1), one Zn(2), and one C(5) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(4) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Na(1), one Zn(3), and one C(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Na(1), one Zn(2), and one C(2) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Zn(3), one H(3), and one H(4) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Na(1), one Zn(3), one H(5), and one H(6) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one C(7) and one H(1) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(2), and one C(17) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one C(5) and one H(5) atom. In the sixteenth O site, O(16) is bonded in a trigonal planar geometry to one Na(1), one C(19), and one H(4) atom. In the seventeenth O site, O(17) is bonded in a water-like geometry to one C(17) and one H(2) atom. Linkers: 2 [O]C(=O)c1cc(C([O])=O)cc(C([O])=O)c1. Metal clusters: 1 [Na] ,3 [Zn]. The MOF has largest included sphere 2.51 A, density 2.06 g/cm3, surface area 2910.93 m2/g, accessible volume 0.12 cm3/g