ZnC27N8H24O9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ZnC27N8H24O9 clusters. Zn(1,2) is bonded in a 7-coordinate geometry to one N(12), one N(3), one N(7), one O(11), one O(13), one O(5), and one O(7) atom. The Zn(1,2)-N(12) bond length is 2.10 Å. The Zn(1,2)-N(3) bond length is 2.15 Å. The Zn(1,2)-N(7) bond length is 2.12 Å. The Zn(1,2)-O(11) bond length is 2.24 Å. The Zn(1,2)-O(13) bond length is 2.56 Å. The Zn(1,2)-O(5) bond length is 2.47 Å. The Zn(1,2)-O(7) bond length is 2.23 Å. There are twenty-seven inequivalent C sites. In the first C site, C(15,16) is bonded in a distorted trigonal non-coplanar geometry to one C(17,18); one N(1); one H(13,14); and one H(15,16) atom. The C(15,16)-C(17,18) bond length is 1.51 Å. The C(15,16)-N(1) bond length is 1.46 Å. The C(15,16)-H(13,14) bond length is 1.10 Å. The C(15,16)-H(15,16) bond length is 1.10 Å. In the second C site, C(17,18) is bonded in a trigonal planar geometry to one C(15,16); one C(19,20); and one C(25,26) atom. The C(17,18)-C(19,20) bond length is 1.40 Å. The C(17,18)-C(25,26) bond length is 1.40 Å. In the third C site, C(19,20) is bonded in a distorted trigonal planar geometry to one C(17,18); one C(21,22); and one H(17,18) atom. The C(19,20)-C(21,22) bond length is 1.39 Å. The C(19,20)-H(17,18) bond length is 1.09 Å. In the fourth C site, C(21,22) is bonded in a distorted bent 120 degrees geometry to one C(19,20); one N(3); and one H(19,20) atom. The C(21,22)-N(3) bond length is 1.35 Å. The C(21,22)-H(19,20) bond length is 1.09 Å. In the fifth C site, C(23,24) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(21,22) atom. The C(23,24)-N(3) bond length is 1.35 Å. The C(23,24)-H(21,22) bond length is 1.09 Å. In the sixth C site, C(25,26) is bonded in a distorted single-bond geometry to one C(17,18) and one H(23,24) atom. The C(25,26)-H(23,24) bond length is 1.09 Å. In the seventh C site, C(27,28) is bonded in a distorted bent 120 degrees geometry to one C(5,6); one N(5,6); and one O(1,2) atom. The C(27,28)-C(5,6) bond length is 1.50 Å. The C(27,28)-N(5,6) bond length is 1.36 Å. The C(27,28)-O(1,2) bond length is 1.24 Å. In the eighth C site, C(29) is bonded in a distorted trigonal non-coplanar geometry to one C(31,32); one N(5,6); one H(25,26); and one H(27,28) atom. The C(29)-C(31,32) bond length is 1.51 Å. The C(29)-N(5,6) bond length is 1.45 Å. The C(29)-H(25,26) bond length is 1.10 Å. The C(29)-H(27,28) bond length is 1.10 Å. In the ninth C site, C(31,32) is bonded in a trigonal planar geometry to one C(29), one C(33), and one C(39) atom. The C(31,32)-C(33) bond length is 1.40 Å. The C(31,32)-C(39) bond length is 1.40 Å. In the tenth C site, C(33) is bonded in a distorted single-bond geometry to one C(31,32) and one H(29,30) atom. The C(33)-H(29,30) bond length is 1.09 Å. In the eleventh C site, C(35,36) is bonded in a distorted trigonal planar geometry to one N(7) and one H(31,32) atom. The C(35,36)-N(7) bond length is 1.35 Å. The C(35,36)-H(31,32) bond length is 1.09 Å. In the twelfth C site, C(37,38) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(33,34) atom. The C(37,38)-N(7) bond length is 1.35 Å. The C(37,38)-H(33,34) bond length is 1.09 Å. In the thirteenth C site, C(39) is bonded in a distorted single-bond geometry to one C(31,32) and one H(35,36) atom. The C(39)-H(35,36) bond length is 1.09 Å. In the fourteenth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(9,10); one N(9,10); and one O(3,4) atom. The C(41)-C(9,10) bond length is 1.50 Å. The C(41)-N(9,10) bond length is 1.35 Å. The C(41)-O(3,4) bond length is 1.25 Å. In the fifteenth C site, C(43) is bonded in a distorted trigonal non-coplanar geometry to one C(45,46); one N(9,10); one H(37,38); and one H(39,40) atom. The C(43)-C(45,46) bond length is 1.51 Å. The C(43)-N(9,10) bond length is 1.45 Å. The C(43)-H(37,38) bond length is 1.10 Å. The C(43)-H(39,40) bond length is 1.10 Å. In the sixteenth C site, C(45,46) is bonded in a trigonal planar geometry to one C(43), one C(47), and one C(53) atom. The C(45,46)-C(47) bond length is 1.40 Å. The C(45,46)-C(53) bond length is 1.40 Å. In the seventeenth C site, C(47) is bonded in a distorted single-bond geometry to one C(45,46) and one H(41,42) atom. The C(47)-H(41,42) bond length is 1.09 Å. In the eighteenth C site, C(49,50) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(43,44) atom. The C(49,50)-N(11) bond length is 1.35 Å. The C(49,50)-H(43,44) bond length is 1.09 Å. In the nineteenth C site, C(51,52) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(45,46) atom. The C(51,52)-N(11) bond length is 1.35 Å. The C(51,52)-H(45,46) bond length is 1.09 Å. In the twentieth C site, C(53) is bonded in a distorted single-bond geometry to one C(45,46) and one H(47,48) atom. The C(53)-H(47,48) bond length is 1.09 Å. In the twenty-first C site, C(11) is bonded in a distorted single-bond geometry to one C(1); one C(9,10); and one H(11,12) atom. The C(11)-C(1) bond length is 1.40 Å. The C(11)-C(9,10) bond length is 1.40 Å. The C(11)-H(11,12) bond length is 1.09 Å. In the twenty-second C site, C(1) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(3) atom. The C(1)-C(13) bond length is 1.50 Å. The C(1)-C(3) bond length is 1.40 Å. In the twenty-third C site, C(3) is bonded in a distorted single-bond geometry to one C(1); one C(5,6); and one H(7,8) atom. The C(3)-C(5,6) bond length is 1.40 Å. The C(3)-H(7,8) bond length is 1.09 Å. In the twenty-fourth C site, C(5,6) is bonded in a trigonal planar geometry to one C(27,28); one C(3); and one C(7) atom. The C(5,6)-C(7) bond length is 1.40 Å. In the twenty-fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(5,6); one C(9,10); and one H(9,10) atom. The C(7)-C(9,10) bond length is 1.39 Å. The C(7)-H(9,10) bond length is 1.09 Å. In the twenty-sixth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one O(17) atom. The C(13)-N(1) bond length is 1.35 Å. The C(13)-O(17) bond length is 1.25 Å. In the twenty-seventh C site, C(9,10) is bonded in a trigonal planar geometry to one C(11), one C(41), and one C(7) atom. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(13); one C(15,16); and one H(1,2) atom. The N(1)-H(1,2) bond length is 1.02 Å. In the second N site, N(3) is bonded in a trigonal planar geometry to one Zn(1,2); one C(21,22); and one C(23,24) atom. In the third N site, N(5,6) is bonded in a trigonal planar geometry to one C(27,28); one C(29); and one H(3,4) atom. The N(5,6)-H(3,4) bond length is 1.01 Å. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one Zn(1,2); one C(35,36); and one C(37,38) atom. In the fifth N site, N(9,10) is bonded in a trigonal planar geometry to one C(41), one C(43), and one H(5) atom. The N(9,10)-H(5) bond length is 1.03 Å. In the sixth N site, N(12) is bonded in a trigonal planar geometry to one Zn(1,2); one C(49,50); and one C(51,52) atom. The N(12)-C(49,50) bond length is 1.35 Å. The N(12)-C(51,52) bond length is 1.35 Å. In the seventh N site, N(13,14) is bonded in a trigonal planar geometry to one O(5), one O(7), and one O(9) atom. The N(13,14)-O(5) bond length is 1.27 Å. The N(13,14)-O(7) bond length is 1.30 Å. The N(13,14)-O(9) bond length is 1.24 Å. In the eighth N site, N(15,16) is bonded in a trigonal planar geometry to one O(11), one O(13), and one O(15) atom. The N(15,16)-O(11) bond length is 1.29 Å. The N(15,16)-O(13) bond length is 1.28 Å. The N(15,16)-O(15) bond length is 1.25 Å. There are twenty-four inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one N(5,6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(9,10) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(13,14) is bonded in a single-bond geometry to one C(15,16) atom. In the eighth H site, H(15,16) is bonded in a single-bond geometry to one C(15,16) atom. In the ninth H site, H(17,18) is bonded in a single-bond geometry to one C(19,20) atom. In the tenth H site, H(19,20) is bonded in a single-bond geometry to one C(21,22) atom. In the eleventh H site, H(21,22) is bonded in a single-bond geometry to one C(23,24) atom. In the twelfth H site, H(23,24) is bonded in a single-bond geometry to one C(25,26) atom. In the thirteenth H site, H(25,26) is bonded in a single-bond geometry to one C(29) atom. In the fourteenth H site, H(27,28) is bonded in a single-bond geometry to one C(29) atom. In the fifteenth H site, H(29,30) is bonded in a single-bond geometry to one C(33) atom. In the sixteenth H site, H(31,32) is bonded in a single-bond geometry to one C(35,36) atom. In the seventeenth H site, H(33,34) is bonded in a single-bond geometry to one C(37,38) atom. In the eighteenth H site, H(35,36) is bonded in a single-bond geometry to one C(39) atom. In the nineteenth H site, H(37,38) is bonded in a single-bond geometry to one C(43) atom. In the twentieth H site, H(39,40) is bonded in a single-bond geometry to one C(43) atom. In the twenty-first H site, H(41,42) is bonded in a single-bond geometry to one C(47) atom. In the twenty-second H site, H(43,44) is bonded in a single-bond geometry to one C(49,50) atom. In the twenty-third H site, H(45,46) is bonded in a single-bond geometry to one C(51,52) atom. In the twenty-fourth H site, H(47,48) is bonded in a single-bond geometry to one C(53) atom. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a single-bond geometry to one N(13,14) atom. In the second O site, O(11) is bonded in a water-like geometry to one Zn(1,2) and one N(15,16) atom. In the third O site, O(13) is bonded in a single-bond geometry to one Zn(1,2) and one N(15,16) atom. In the fourth O site, O(15) is bonded in a single-bond geometry to one N(15,16) atom. In the fifth O site, O(17) is bonded in a single-bond geometry to one C(13) atom. In the sixth O site, O(1,2) is bonded in a single-bond geometry to one C(27,28) atom. In the seventh O site, O(3,4) is bonded in a single-bond geometry to one C(41) atom. In the eighth O site, O(5) is bonded in a distorted single-bond geometry to one Zn(1,2) and one N(13,14) atom. In the ninth O site, O(7) is bonded in a water-like geometry to one Zn(1,2) and one N(13,14) atom. Linkers: 4 O=C(NCc1ccncc1)c1cc(C(=O)NCc2ccncc2)cc(C(=O)NCc2ccncc2)c1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 3.87 A, density 1.29 g/cm3, surface area 4674.29 m2/g, accessible volume 0.28 cm3/g