ZnC18NH14O5 crystallizes in the triclinic P-1 space group. There are three inequivalent Zn sites. In the first Zn site, Zn(1,2) is bonded in a square pyramidal geometry to one N(1), one O(14), one O(18), one O(5), and one O(9) atom. The Zn(1,2)-N(1) bond length is 2.10 Å. The Zn(1,2)-O(14) bond length is 2.07 Å. The Zn(1,2)-O(18) bond length is 2.09 Å. The Zn(1,2)-O(5) bond length is 2.06 Å. The Zn(1,2)-O(9) bond length is 2.05 Å. In the second Zn site, Zn(3) is bonded in a square pyramidal geometry to one N(3), one O(11), one O(13), one O(17), and one O(7) atom. The Zn(3)-N(3) bond length is 2.10 Å. The Zn(3)-O(11) bond length is 2.05 Å. The Zn(3)-O(13) bond length is 2.07 Å. The Zn(3)-O(17) bond length is 2.09 Å. The Zn(3)-O(7) bond length is 2.06 Å. In the third Zn site, Zn(4) is bonded in a square pyramidal geometry to one N(4), one O(12), one O(15), one O(19), and one O(8) atom. The Zn(4)-N(4) bond length is 2.10 Å. The Zn(4)-O(12) bond length is 2.05 Å. The Zn(4)-O(15) bond length is 2.07 Å. The Zn(4)-O(19) bond length is 2.09 Å. The Zn(4)-O(8) bond length is 2.05 Å. There are fifty-seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(5,7); one C(65); and one H(1,2,3,4) atom. The C(1)-C(5,7) bond length is 1.39 Å. The C(1)-C(65) bond length is 1.40 Å. The C(1)-H(1,2,3,4) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(6); one C(66); and one H(1,2,3,4) atom. The C(2)-C(6) bond length is 1.39 Å. The C(2)-C(66) bond length is 1.40 Å. The C(2)-H(1,2,3,4) bond length is 1.09 Å. In the third C site, C(3,4) is bonded in a distorted single-bond geometry to one C(5,7); one C(67); and one H(1,2,3,4) atom. The C(3,4)-C(5,7) bond length is 1.39 Å. The C(3,4)-C(67) bond length is 1.40 Å. The C(3,4)-H(1,2,3,4) bond length is 1.09 Å. In the fourth C site, C(5,7) is bonded in a distorted trigonal planar geometry to one C(1), one C(9), and one H(5) atom. The C(5,7)-C(9) bond length is 1.40 Å. The C(5,7)-H(5) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(10), one C(2), and one H(6) atom. The C(6)-C(10) bond length is 1.40 Å. The C(6)-H(6) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(12); one C(3,4); and one H(7,8) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(3,4) bond length is 1.39 Å. The C(8)-H(7,8) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(13,15); one C(45); and one C(5,7) atom. The C(9)-C(13,15) bond length is 1.40 Å. The C(9)-C(45) bond length is 1.49 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(14), one C(46), and one C(6) atom. The C(10)-C(14) bond length is 1.40 Å. The C(10)-C(46) bond length is 1.50 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(13,15); one C(47); and one C(5,7) atom. The C(11)-C(13,15) bond length is 1.40 Å. The C(11)-C(47) bond length is 1.49 Å. The C(11)-C(5,7) bond length is 1.40 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(16), one C(48), and one C(8) atom. The C(12)-C(16) bond length is 1.40 Å. The C(12)-C(48) bond length is 1.49 Å. In the eleventh C site, C(13,15) is bonded in a distorted trigonal planar geometry to one C(17), one C(9), and one H(9) atom. The C(13,15)-C(17) bond length is 1.39 Å. The C(13,15)-H(9) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(10); one C(18); and one H(10,11,12) atom. The C(14)-C(18) bond length is 1.39 Å. The C(14)-H(10,11,12) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(12); one C(19,20); and one H(10,11,12) atom. The C(16)-C(19,20) bond length is 1.39 Å. The C(16)-H(10,11,12) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(13,15); one C(65); and one H(13,14,15,16) atom. The C(17)-C(65) bond length is 1.40 Å. The C(17)-H(13,14,15,16) bond length is 1.09 Å. In the fifteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(14); one C(66); and one H(13,14,15,16) atom. The C(18)-C(66) bond length is 1.40 Å. The C(18)-H(13,14,15,16) bond length is 1.09 Å. In the sixteenth C site, C(19,20) is bonded in a distorted single-bond geometry to one C(13,15); one C(67); and one H(13,14,15,16) atom. The C(19,20)-C(13,15) bond length is 1.39 Å. The C(19,20)-C(67) bond length is 1.40 Å. The C(19,20)-H(13,14,15,16) bond length is 1.09 Å. In the seventeenth C site, C(21) is bonded in a trigonal planar geometry to one C(25,26,27); one C(41,42,43); and one C(69,71) atom. The C(21)-C(25,26,27) bond length is 1.40 Å. The C(21)-C(41,42,43) bond length is 1.40 Å. The C(21)-C(69,71) bond length is 1.50 Å. In the eighteenth C site, C(22) is bonded in a trigonal planar geometry to one C(25,26,27); one C(41,42,43); and one C(70) atom. The C(22)-C(25,26,27) bond length is 1.40 Å. The C(22)-C(41,42,43) bond length is 1.40 Å. The C(22)-C(70) bond length is 1.50 Å. In the nineteenth C site, C(23) is bonded in a trigonal planar geometry to one C(25,26,27); one C(41,42,43); and one C(69,71) atom. The C(23)-C(25,26,27) bond length is 1.40 Å. The C(23)-C(41,42,43) bond length is 1.40 Å. The C(23)-C(69,71) bond length is 1.50 Å. In the twentieth C site, C(24) is bonded in a trigonal planar geometry to one C(28), one C(44), and one C(72) atom. The C(24)-C(28) bond length is 1.40 Å. The C(24)-C(44) bond length is 1.40 Å. The C(24)-C(72) bond length is 1.50 Å. In the twenty-first C site, C(25,26,27) is bonded in a distorted single-bond geometry to one C(21); one C(29); and one H(17,18) atom. The C(25,26,27)-C(29) bond length is 1.39 Å. The C(25,26,27)-H(17,18) bond length is 1.09 Å. In the twenty-second C site, C(28) is bonded in a distorted single-bond geometry to one C(24), one C(32), and one H(20) atom. The C(28)-C(32) bond length is 1.39 Å. The C(28)-H(20) bond length is 1.09 Å. In the twenty-third C site, C(29) is bonded in a distorted trigonal planar geometry to one C(25,26,27); one C(33); and one H(21,22,23) atom. The C(29)-C(33) bond length is 1.40 Å. The C(29)-H(21,22,23) bond length is 1.09 Å. In the twenty-fourth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(25,26,27); one C(34); and one H(21,22,23) atom. The C(30)-C(25,26,27) bond length is 1.39 Å. The C(30)-C(34) bond length is 1.40 Å. The C(30)-H(21,22,23) bond length is 1.09 Å. In the twenty-fifth C site, C(31) is bonded in a distorted single-bond geometry to one C(25,26,27); one C(35); and one H(21,22,23) atom. The C(31)-C(25,26,27) bond length is 1.39 Å. The C(31)-C(35) bond length is 1.40 Å. The C(31)-H(21,22,23) bond length is 1.09 Å. In the twenty-sixth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(28), one C(36), and one H(24) atom. The C(32)-C(36) bond length is 1.40 Å. The C(32)-H(24) bond length is 1.09 Å. In the twenty-seventh C site, C(33) is bonded in a trigonal planar geometry to one C(29), one C(37), and one C(45) atom. The C(33)-C(37) bond length is 1.40 Å. The C(33)-C(45) bond length is 1.50 Å. In the twenty-eighth C site, C(34) is bonded in a trigonal planar geometry to one C(30), one C(38), and one C(46) atom. The C(34)-C(38) bond length is 1.41 Å. The C(34)-C(46) bond length is 1.50 Å. In the twenty-ninth C site, C(35) is bonded in a trigonal planar geometry to one C(31), one C(39), and one C(47) atom. The C(35)-C(39) bond length is 1.41 Å. The C(35)-C(47) bond length is 1.50 Å. In the thirtieth C site, C(36) is bonded in a trigonal planar geometry to one C(32), one C(40), and one C(48) atom. The C(36)-C(40) bond length is 1.41 Å. The C(36)-C(48) bond length is 1.50 Å. In the thirty-first C site, C(37) is bonded in a distorted trigonal planar geometry to one C(33); one C(41,42,43); and one H(25,26,27) atom. The C(37)-C(41,42,43) bond length is 1.39 Å. The C(37)-H(25,26,27) bond length is 1.09 Å. In the thirty-second C site, C(38) is bonded in a distorted trigonal planar geometry to one C(34); one C(41,42,43); and one H(25,26,27) atom. The C(38)-C(41,42,43) bond length is 1.39 Å. The C(38)-H(25,26,27) bond length is 1.09 Å. In the thirty-third C site, C(39) is bonded in a distorted trigonal planar geometry to one C(35); one C(41,42,43); and one H(25,26,27) atom. The C(39)-C(41,42,43) bond length is 1.39 Å. The C(39)-H(25,26,27) bond length is 1.09 Å. In the thirty-fourth C site, C(40) is bonded in a distorted trigonal planar geometry to one C(36), one C(44), and one H(28) atom. The C(40)-C(44) bond length is 1.39 Å. The C(40)-H(28) bond length is 1.09 Å. In the thirty-fifth C site, C(41,42,43) is bonded in a distorted single-bond geometry to one C(21); one C(37); and one H(29,30) atom. The C(41,42,43)-H(29,30) bond length is 1.09 Å. In the thirty-sixth C site, C(44) is bonded in a distorted single-bond geometry to one C(24), one C(40), and one H(32) atom. The C(44)-H(32) bond length is 1.09 Å. In the thirty-seventh C site, C(45) is bonded in a distorted trigonal planar geometry to one C(33), one C(9), and one O(1) atom. The C(45)-O(1) bond length is 1.23 Å. In the thirty-eighth C site, C(46) is bonded in a distorted trigonal planar geometry to one C(10), one C(34), and one O(2) atom. The C(46)-O(2) bond length is 1.23 Å. In the thirty-ninth C site, C(47) is bonded in a distorted trigonal planar geometry to one C(11), one C(35), and one O(3) atom. The C(47)-O(3) bond length is 1.23 Å. In the fortieth C site, C(48) is bonded in a distorted trigonal planar geometry to one C(12), one C(36), and one O(4) atom. The C(48)-O(4) bond length is 1.23 Å. In the forty-first C site, C(49,50) is bonded in a distorted trigonal non-coplanar geometry to one N(1); one H(33,34,35,36); and one H(37,38,39,40) atom. The C(49,50)-N(1) bond length is 1.49 Å. The C(49,50)-H(33,34,35,36) bond length is 1.10 Å. The C(49,50)-H(37,38,39,40) bond length is 1.10 Å. In the forty-second C site, C(51,52) is bonded in a distorted trigonal non-coplanar geometry to one N(3); one H(33,34,35,36); and one H(37,38,39,40) atom. The C(51,52)-N(3) bond length is 1.49 Å. The C(51,52)-H(33,34,35,36) bond length is 1.10 Å. The C(51,52)-H(37,38,39,40) bond length is 1.10 Å. In the forty-third C site, C(53,54) is bonded in a distorted trigonal non-coplanar geometry to one N(1); one H(41,42,43,44,53,54,55); and one H(45,46,47,48,56) atom. The C(53,54)-N(1) bond length is 1.49 Å. The C(53,54)-H(41,42,43,44,53,54,55) bond length is 1.10 Å. The C(53,54)-H(45,46,47,48,56) bond length is 1.10 Å. In the forty-fourth C site, C(55,56) is bonded in a distorted trigonal non-coplanar geometry to one N(3); one H(41,42,43,44,53,54,55); and one H(45,46,47,48,56) atom. The C(55,56)-N(3) bond length is 1.49 Å. The C(55,56)-H(41,42,43,44,53,54,55) bond length is 1.10 Å. The C(55,56)-H(45,46,47,48,56) bond length is 1.10 Å. In the forty-fifth C site, C(57,58) is bonded in a distorted trigonal non-coplanar geometry to one N(1); one H(41,42,43,44,53,54,55); and one H(49,50,51,52) atom. The C(57,58)-N(1) bond length is 1.49 Å. The C(57,58)-H(41,42,43,44,53,54,55) bond length is 1.10 Å. The C(57,58)-H(49,50,51,52) bond length is 1.10 Å. In the forty-sixth C site, C(59,60) is bonded in a distorted trigonal non-coplanar geometry to one N(3); one H(41,42,43,44,53,54,55); and one H(49,50,51,52) atom. The C(59,60)-N(3) bond length is 1.49 Å. The C(59,60)-H(41,42,43,44,53,54,55) bond length is 1.10 Å. The C(59,60)-H(49,50,51,52) bond length is 1.10 Å. In the forty-seventh C site, C(61) is bonded in a bent 120 degrees geometry to one C(65), one O(5), and one O(9) atom. The C(61)-C(65) bond length is 1.50 Å. The C(61)-O(5) bond length is 1.27 Å. The C(61)-O(9) bond length is 1.27 Å. In the forty-eighth C site, C(62) is bonded in a bent 120 degrees geometry to one C(66), one O(10), and one O(6) atom. The C(62)-C(66) bond length is 1.50 Å. The C(62)-O(10) bond length is 1.27 Å. The C(62)-O(6) bond length is 1.27 Å. In the forty-ninth C site, C(63) is bonded in a bent 120 degrees geometry to one C(67), one O(11), and one O(7) atom. The C(63)-C(67) bond length is 1.50 Å. The C(63)-O(11) bond length is 1.27 Å. The C(63)-O(7) bond length is 1.27 Å. In the fiftieth C site, C(64) is bonded in a bent 120 degrees geometry to one C(68), one O(12), and one O(8) atom. The C(64)-C(68) bond length is 1.50 Å. The C(64)-O(12) bond length is 1.27 Å. The C(64)-O(8) bond length is 1.27 Å. In the fifty-first C site, C(65) is bonded in a trigonal planar geometry to one C(1), one C(17), and one C(61) atom. In the fifty-second C site, C(66) is bonded in a trigonal planar geometry to one C(18), one C(2), and one C(62) atom. In the fifty-third C site, C(67) is bonded in a trigonal planar geometry to one C(19,20); one C(3,4); and one C(63) atom. In the fifty-fourth C site, C(68) is bonded in a trigonal planar geometry to one C(19,20); one C(3,4); and one C(64) atom. The C(68)-C(19,20) bond length is 1.40 Å. The C(68)-C(3,4) bond length is 1.40 Å. In the fifty-fifth C site, C(69,71) is bonded in a bent 120 degrees geometry to one C(21), one O(13), and one O(17) atom. The C(69,71)-O(13) bond length is 1.27 Å. The C(69,71)-O(17) bond length is 1.27 Å. In the fifty-sixth C site, C(70) is bonded in a bent 120 degrees geometry to one C(22), one O(14), and one O(18) atom. The C(70)-O(14) bond length is 1.27 Å. The C(70)-O(18) bond length is 1.27 Å. In the fifty-seventh C site, C(72) is bonded in a bent 120 degrees geometry to one C(24), one O(16), and one O(20) atom. The C(72)-O(16) bond length is 1.27 Å. The C(72)-O(20) bond length is 1.27 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a tetrahedral geometry to one Zn(1,2); one C(49,50); one C(53,54); and one C(57,58) atom. In the second N site, N(2) is bonded in a tetrahedral geometry to one Zn(1,2); one C(49,50); one C(53,54); and one C(57,58) atom. The N(2)-Zn(1,2) bond length is 2.10 Å. The N(2)-C(49,50) bond length is 1.49 Å. The N(2)-C(53,54) bond length is 1.49 Å. The N(2)-C(57,58) bond length is 1.49 Å. In the third N site, N(3) is bonded in a tetrahedral geometry to one Zn(3); one C(51,52); one C(55,56); and one C(59,60) atom. In the fourth N site, N(4) is bonded in a tetrahedral geometry to one Zn(4); one C(51,52); one C(55,56); and one C(59,60) atom. The N(4)-C(51,52) bond length is 1.49 Å. The N(4)-C(55,56) bond length is 1.49 Å. The N(4)-C(59,60) bond length is 1.49 Å. There are twenty-two inequivalent H sites. In the first H site, H(1,2,3,4) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(5,7) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(5,7) atom. The H(7,8)-C(5,7) bond length is 1.09 Å. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(13,15) atom. In the sixth H site, H(10,11,12) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(13,14,15,16) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(17,18) is bonded in a single-bond geometry to one C(25,26,27) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(25,26,27) atom. The H(19)-C(25,26,27) bond length is 1.09 Å. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(28) atom. In the eleventh H site, H(21,22,23) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(32) atom. In the thirteenth H site, H(25,26,27) is bonded in a single-bond geometry to one C(37) atom. In the fourteenth H site, H(28) is bonded in a single-bond geometry to one C(40) atom. In the fifteenth H site, H(29,30) is bonded in a single-bond geometry to one C(41,42,43) atom. In the sixteenth H site, H(31) is bonded in a single-bond geometry to one C(41,42,43) atom. The H(31)-C(41,42,43) bond length is 1.09 Å. In the seventeenth H site, H(32) is bonded in a single-bond geometry to one C(44) atom. In the eighteenth H site, H(33,34,35,36) is bonded in a single-bond geometry to one C(49,50) atom. In the nineteenth H site, H(37,38,39,40) is bonded in a single-bond geometry to one C(49,50) atom. In the twentieth H site, H(41,42,43,44,53,54,55) is bonded in a single-bond geometry to one C(53,54) atom. In the twenty-first H site, H(45,46,47,48,56) is bonded in a single-bond geometry to one C(53,54) atom. In the twenty-second H site, H(49,50,51,52) is bonded in a single-bond geometry to one C(57,58) atom. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(45) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(46) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(47) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(48) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1,2) and one C(61) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1,2) and one C(62) atom. The O(6)-Zn(1,2) bond length is 2.06 Å. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(63) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(64) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(1,2) and one C(61) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(1,2) and one C(62) atom. The O(10)-Zn(1,2) bond length is 2.05 Å. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(63) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(64) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(69,71) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(1,2) and one C(70) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(69,71) atom. The O(15)-C(69,71) bond length is 1.27 Å. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Zn(1,2) and one C(72) atom. The O(16)-Zn(1,2) bond length is 2.07 Å. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(69,71) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Zn(1,2) and one C(70) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(69,71) atom. The O(19)-C(69,71) bond length is 1.27 Å. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Zn(1,2) and one C(72) atom. The O(20)-Zn(1,2) bond length is 2.09 Å. Linkers: 8 [O]C(=O)c1ccc(C(=O)c2ccc(C([O])=O)cc2)cc1 ,3 C1CN2CCN1CC2. Metal clusters: 2 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4 ,4 [Zn]. The MOF has largest included sphere 12.12 A, density 0.55 g/cm3, surface area 4642.09 m2/g, accessible volume 1.38 cm3/g