Ag6Zn3C42H50S6(N3O4)4 crystallizes in the triclinic P-1 space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal planar geometry to one N(3), one S(1), and one S(2) atom. The Ag(1)-N(3) bond length is 2.28 Å. The Ag(1)-S(1) bond length is 2.50 Å. The Ag(1)-S(2) bond length is 2.46 Å. In the second Ag site, Ag(2) is bonded in a distorted trigonal planar geometry to one N(2), one S(1), and one S(3) atom. The Ag(2)-N(2) bond length is 2.28 Å. The Ag(2)-S(1) bond length is 2.49 Å. The Ag(2)-S(3) bond length is 2.45 Å. In the third Ag site, Ag(3) is bonded in a distorted trigonal planar geometry to one N(1), one S(2), and one S(3) atom. The Ag(3)-N(1) bond length is 2.27 Å. The Ag(3)-S(2) bond length is 2.46 Å. The Ag(3)-S(3) bond length is 2.48 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in an octahedral geometry to two equivalent N(4), two equivalent N(5), and two equivalent O(7) atoms. Both Zn(1)-N(4) bond lengths are 2.12 Å. Both Zn(1)-N(5) bond lengths are 2.15 Å. Both Zn(1)-O(7) bond lengths are 2.30 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one N(6), one O(3), one O(4), and one O(8) atom. The Zn(2)-N(6) bond length is 2.08 Å. The Zn(2)-O(3) bond length is 1.98 Å. The Zn(2)-O(4) bond length is 1.99 Å. The Zn(2)-O(8) bond length is 1.97 Å. There are twenty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(6) bond length is 1.52 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one S(1) atom. The C(5)-N(1) bond length is 1.36 Å. The C(5)-S(1) bond length is 1.76 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.27 Å. The C(6)-O(2) bond length is 1.27 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(4), and one H(5) atom. The C(7)-N(4) bond length is 1.48 Å. The C(7)-H(4) bond length is 1.10 Å. The C(7)-H(5) bond length is 1.10 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(5), one H(6), and one H(7) atom. The C(8)-N(5) bond length is 1.47 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-H(7) bond length is 1.10 Å. In the ninth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(8), and one H(9) atom. The C(9)-N(6) bond length is 1.48 Å. The C(9)-H(8) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(2), and one H(10) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(10) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(11) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(11) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(12) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(12) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(15) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(15) bond length is 1.50 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(2), and one S(2) atom. The C(14)-N(2) bond length is 1.36 Å. The C(14)-S(2) bond length is 1.75 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(3), and one O(5) atom. The C(15)-O(3) bond length is 1.29 Å. The C(15)-O(5) bond length is 1.25 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one N(3), and one H(13) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-N(3) bond length is 1.34 Å. The C(16)-H(13) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(14) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(14) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(15) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-H(15) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(21) atom. The C(19)-C(20) bond length is 1.42 Å. The C(19)-C(21) bond length is 1.52 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one N(3), and one S(3) atom. The C(20)-N(3) bond length is 1.36 Å. The C(20)-S(3) bond length is 1.75 Å. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(6), and one O(7) atom. The C(21)-O(6) bond length is 1.28 Å. The C(21)-O(7) bond length is 1.26 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(3), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(10), and one C(14) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(16), and one C(20) atom. In the fourth N site, N(4) is bonded to one Zn(1), one C(7), one H(16), and one H(17) atom to form distorted corner-sharing NZnH2C tetrahedra. The N(4)-H(16) bond length is 1.02 Å. The N(4)-H(17) bond length is 1.03 Å. In the fifth N site, N(5) is bonded to one Zn(1), one C(8), one H(18), and one H(19) atom to form distorted corner-sharing NZnH2C tetrahedra. The N(5)-H(18) bond length is 1.03 Å. The N(5)-H(19) bond length is 1.03 Å. In the sixth N site, N(6) is bonded in a distorted tetrahedral geometry to one Zn(2), one C(9), one H(20), and one H(21) atom. The N(6)-H(20) bond length is 1.02 Å. The N(6)-H(21) bond length is 1.04 Å. There are twenty-five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one N(4) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one N(4) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one N(5) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one N(5) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one N(6) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one N(6) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one O(4) atom. The H(22)-O(4) bond length is 0.99 Å. In the twenty-third H site, H(23) is bonded in a distorted linear geometry to one O(2) and one O(4) atom. The H(23)-O(2) bond length is 1.60 Å. The H(23)-O(4) bond length is 1.02 Å. In the twenty-fourth H site, H(24) is bonded in a distorted linear geometry to one O(6) and one O(8) atom. The H(24)-O(6) bond length is 1.67 Å. The H(24)-O(8) bond length is 1.00 Å. In the twenty-fifth H site, H(25) is bonded in a linear geometry to one O(5) and one O(8) atom. The H(25)-O(5) bond length is 1.59 Å. The H(25)-O(8) bond length is 1.02 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one C(5) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(3), and one C(14) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(2), one Ag(3), and one C(20) atom. There are eight inequivalent O sites. In the first O site, O(6) is bonded in a distorted bent 120 degrees geometry to one C(21) and one H(24) atom. In the second O site, O(7) is bonded in a 2-coordinate geometry to one Zn(1) and one C(21) atom. In the third O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one H(24), and one H(25) atom. In the fourth O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the fifth O site, O(2) is bonded in a bent 150 degrees geometry to one C(6) and one H(23) atom. In the sixth O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(15) atom. In the seventh O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one H(22), and one H(23) atom. In the eighth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one C(15) and one H(25) atom. Linkers: 4 [O]C(=O)[C]1C=CC=NC1=S ,3 NCCN. Metal clusters: 3 [Zn] ,6 [Ag]. The MOF has largest included sphere 3.34 A, density 2.14 g/cm3, surface area 3082.59 m2/g, accessible volume 0.14 cm3/g