Ag2C12H14S2O15(CH)2 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a Ag2C12H14S2O15 framework. In the Ag2C12H14S2O15 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(11), one O(13), one O(8), and two equivalent O(1) atoms to form distorted edge-sharing AgO5 trigonal bipyramids. The Ag(1)-O(11) bond length is 2.42 Å. The Ag(1)-O(13) bond length is 2.45 Å. The Ag(1)-O(8) bond length is 2.40 Å. There is one shorter (2.47 Å) and one longer (2.64 Å) Ag(1)-O(1) bond length. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one O(15), one O(2), one O(5), one O(8), and two equivalent O(7) atoms. The Ag(2)-O(15) bond length is 2.41 Å. The Ag(2)-O(2) bond length is 2.45 Å. The Ag(2)-O(5) bond length is 2.43 Å. The Ag(2)-O(8) bond length is 2.65 Å. There is one shorter (2.48 Å) and one longer (2.73 Å) Ag(2)-O(7) bond length. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-S(1) bond length is 1.76 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(11) atom. The C(2)-H(11) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one O(4) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-O(4) bond length is 1.34 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(7) bond length is 1.47 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(13) atom. The C(6)-H(13) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(5), and one O(6) atom. The C(7)-O(5) bond length is 1.26 Å. The C(7)-O(6) bond length is 1.31 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(9), and one S(2) atom. The C(8)-C(13) bond length is 1.39 Å. The C(8)-C(9) bond length is 1.41 Å. The C(8)-S(2) bond length is 1.77 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(14) atom. The C(9)-H(14) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one O(10) atom. The C(11)-C(12) bond length is 1.42 Å. The C(11)-O(10) bond length is 1.34 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(14) bond length is 1.48 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(16) atom. The C(13)-H(16) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(11), and one O(12) atom. The C(14)-O(11) bond length is 1.27 Å. The C(14)-O(12) bond length is 1.30 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted bent 150 degrees geometry to one O(4) and one O(5) atom. The H(1)-O(4) bond length is 1.01 Å. The H(1)-O(5) bond length is 1.63 Å. In the second H site, H(2) is bonded in a linear geometry to one O(15) and one O(6) atom. The H(2)-O(15) bond length is 1.53 Å. The H(2)-O(6) bond length is 1.03 Å. In the third H site, H(3) is bonded in a distorted bent 150 degrees geometry to one O(10) and one O(11) atom. The H(3)-O(10) bond length is 1.01 Å. The H(3)-O(11) bond length is 1.61 Å. In the fourth H site, H(4) is bonded in a linear geometry to one O(12) and one O(14) atom. The H(4)-O(12) bond length is 1.06 Å. The H(4)-O(14) bond length is 1.46 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(13) atom. The H(5)-O(13) bond length is 0.99 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(13) atom. The H(6)-O(13) bond length is 0.99 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(14) atom. The H(7)-O(14) bond length is 0.99 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(14) atom. The H(8)-O(14) bond length is 0.99 Å. In the ninth H site, H(9) is bonded in a distorted linear geometry to one O(15) and one O(9) atom. The H(9)-O(15) bond length is 1.00 Å. The H(9)-O(9) bond length is 1.63 Å. In the tenth H site, H(10) is bonded in a distorted single-bond geometry to one O(15) atom. The H(10)-O(15) bond length is 1.00 Å. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(2) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(6) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(9) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.50 Å. The S(1)-O(2) bond length is 1.46 Å. The S(1)-O(3) bond length is 1.48 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one C(8), one O(7), one O(8), and one O(9) atom. The S(2)-O(7) bond length is 1.49 Å. The S(2)-O(8) bond length is 1.48 Å. The S(2)-O(9) bond length is 1.47 Å. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(4) and one H(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Ag(2), one C(7), and one H(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one C(7) and one H(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one S(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one S(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one H(9) and one S(2) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one C(11) and one H(3) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Ag(1), one C(14), and one H(3) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one C(14) and one H(4) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one Ag(1), one H(5), and one H(6) atom. In the fourteenth O site, O(14) is bonded in a trigonal non-coplanar geometry to one H(4), one H(7), and one H(8) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Ag(2), one H(10), one H(2), and one H(9) atom. Linkers: 4 [O]S([O])([O])c1ccc(O)c(C(=O)O)c1. Metal clusters: 4 [Ag]. RCSR code: sql. The MOF has largest included sphere 1.90 A, density 2.35 g/cm3, surface area 3100.93 m2/g, accessible volume 0.06 cm3/g