HgC14N2H10(O2Cl)2(CH3CO)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of eight dimethyl ether molecules and four HgC14N2H10(O2Cl)2 clusters. In two of the HgC14N2H10(O2Cl)2 clusters, Hg(1) is bonded in a distorted see-saw-like geometry to two equivalent N(1) and two equivalent Cl(2) atoms. Both Hg(1)-N(1) bond lengths are 2.42 Å. Both Hg(1)-Cl(2) bond lengths are 2.42 Å. There are seven inequivalent C sites. In the first C site, C(16) is bonded in a distorted water-like geometry to one H(13) and one O(1) atom. The C(16)-H(13) bond length is 1.10 Å. The C(16)-O(1) bond length is 1.44 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(1)-C(4) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.36 Å. The C(1)-O(2) bond length is 1.22 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-N(1) bond length is 1.34 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(6)-H(2) bond length is 1.09 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one H(6) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-N(1) bond length is 1.34 Å. The C(10)-H(6) bond length is 1.09 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. N(1) is bonded in a distorted trigonal planar geometry to one Hg(1), one C(10), and one C(3) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(16) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Cl(2) is bonded in a single-bond geometry to one Hg(1) atom. In two of the HgC14N2H10(O2Cl)2 clusters, Hg(2) is bonded in a distorted see-saw-like geometry to two equivalent N(2) and two equivalent Cl(1) atoms. Both Hg(2)-N(2) bond lengths are 2.48 Å. Both Hg(2)-Cl(1) bond lengths are 2.41 Å. There are seven inequivalent C sites. In the first C site, C(17) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one H(14) atom. The C(17)-C(8) bond length is 1.40 Å. The C(17)-N(2) bond length is 1.34 Å. The C(17)-H(14) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(3), and one O(5) atom. The C(2)-C(5) bond length is 1.49 Å. The C(2)-O(3) bond length is 1.23 Å. The C(2)-O(5) bond length is 1.35 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(7), and one C(9) atom. The C(5)-C(7) bond length is 1.40 Å. The C(5)-C(9) bond length is 1.40 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(7)-H(3) bond length is 1.09 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(17) and one H(4) atom. The C(8)-H(4) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(5), one N(2), and one H(5) atom. The C(9)-N(2) bond length is 1.34 Å. The C(9)-H(5) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a distorted water-like geometry to one H(10) and one O(5) atom. The C(13)-H(10) bond length is 1.10 Å. The C(13)-O(5) bond length is 1.44 Å. N(2) is bonded in a distorted trigonal planar geometry to one Hg(2), one C(17), and one C(9) atom. There are five inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(5) is bonded in a bent 120 degrees geometry to one C(13) and one C(2) atom. Cl(1) is bonded in a single-bond geometry to one Hg(2) atom. Linkers: 1 O=C(O[C@@H]1CO[C@H]2[C@@H]1OC[C@H]2OC(=O)c1cccnc1)c1cccnc1. Metal clusters: . The MOF has largest included sphere 2.26 A, density 2.09 g/cm3, surface area 3723.42 m2/g, accessible volume 0.12 cm3/g