Zn3C54H34(NO3)4 crystallizes in the triclinic P-1 space group. The structure consists of a Zn3C54H34(NO3)4 framework. There are five inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(15), one O(19), one O(24), one O(6), and one O(9) atom to form corner-sharing ZnO6 octahedra. The Zn(1)-O(1) bond length is 2.07 Å. The Zn(1)-O(15) bond length is 2.15 Å. The Zn(1)-O(19) bond length is 2.08 Å. The Zn(1)-O(24) bond length is 2.11 Å. The Zn(1)-O(6) bond length is 2.08 Å. The Zn(1)-O(9) bond length is 2.22 Å. In the second Zn site, Zn(2) is bonded to one O(10), one O(16), one O(2), one O(20), one O(23), and one O(5) atom to form corner-sharing ZnO6 octahedra. The Zn(2)-O(10) bond length is 2.22 Å. The Zn(2)-O(16) bond length is 2.15 Å. The Zn(2)-O(2) bond length is 2.07 Å. The Zn(2)-O(20) bond length is 2.08 Å. The Zn(2)-O(23) bond length is 2.11 Å. The Zn(2)-O(5) bond length is 2.08 Å. In the third Zn site, Zn(3,4) is bonded in a 5-coordinate geometry to one N(1), one O(11), one O(3), one O(8), and one O(9) atom. The Zn(3,4)-N(1) bond length is 2.03 Å. The Zn(3,4)-O(11) bond length is 2.41 Å. The Zn(3,4)-O(3) bond length is 1.98 Å. The Zn(3,4)-O(8) bond length is 1.95 Å. The Zn(3,4)-O(9) bond length is 2.06 Å. In the fourth Zn site, Zn(5) is bonded to one N(8), one O(13), one O(15), one O(17), and one O(22) atom to form distorted corner-sharing ZnNO4 trigonal bipyramids. The corner-sharing octahedral tilt angles are 76°. The Zn(5)-N(8) bond length is 2.08 Å. The Zn(5)-O(13) bond length is 2.14 Å. The Zn(5)-O(15) bond length is 2.20 Å. The Zn(5)-O(17) bond length is 1.97 Å. The Zn(5)-O(22) bond length is 1.97 Å. In the fifth Zn site, Zn(6) is bonded to one N(7), one O(14), one O(16), one O(18), and one O(21) atom to form distorted corner-sharing ZnNO4 trigonal bipyramids. The corner-sharing octahedral tilt angles are 76°. The Zn(6)-N(7) bond length is 2.08 Å. The Zn(6)-O(14) bond length is 2.14 Å. The Zn(6)-O(16) bond length is 2.20 Å. The Zn(6)-O(18) bond length is 1.97 Å. The Zn(6)-O(21) bond length is 1.97 Å. There are ninety-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.29 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(4) atom. The C(2)-C(4) bond length is 1.49 Å. The C(2)-O(2) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.29 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1); one C(13,14); and one C(5,6) atom. The C(3)-C(13,14) bond length is 1.40 Å. The C(3)-C(5,6) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(13,14); one C(2); and one C(5,6) atom. The C(4)-C(13,14) bond length is 1.40 Å. The C(4)-C(5,6) bond length is 1.40 Å. In the fifth C site, C(5,6) is bonded in a distorted single-bond geometry to one C(3) and one H(1,2) atom. The C(5,6)-H(1,2) bond length is 1.09 Å. In the sixth C site, C(7,8) is bonded in a distorted single-bond geometry to one C(9,10) and one H(3,4) atom. The C(7,8)-C(9,10) bond length is 1.41 Å. The C(7,8)-H(3,4) bond length is 1.09 Å. In the seventh C site, C(9,10) is bonded in a trigonal planar geometry to one C(11,12); one C(15); and one C(7,8) atom. The C(9,10)-C(11,12) bond length is 1.41 Å. The C(9,10)-C(15) bond length is 1.48 Å. In the eighth C site, C(11,12) is bonded in a distorted trigonal planar geometry to one C(13,14); one C(9,10); and one H(5,6) atom. The C(11,12)-C(13,14) bond length is 1.39 Å. The C(11,12)-H(5,6) bond length is 1.09 Å. In the ninth C site, C(13,14) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(3); and one H(7,8) atom. The C(13,14)-H(7,8) bond length is 1.09 Å. In the tenth C site, C(15) is bonded in a trigonal planar geometry to one C(17,18); one C(25,26); and one C(9,10) atom. The C(15)-C(17,18) bond length is 1.41 Å. The C(15)-C(25,26) bond length is 1.41 Å. In the eleventh C site, C(16) is bonded in a trigonal planar geometry to one C(17,18); one C(25,26); and one C(9,10) atom. The C(16)-C(17,18) bond length is 1.41 Å. The C(16)-C(25,26) bond length is 1.41 Å. The C(16)-C(9,10) bond length is 1.48 Å. In the twelfth C site, C(17,18) is bonded in a distorted single-bond geometry to one C(15) and one H(9,10) atom. The C(17,18)-H(9,10) bond length is 1.09 Å. In the thirteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(21) and one H(11,12) atom. The C(19)-C(21) bond length is 1.40 Å. The C(19)-H(11,12) bond length is 1.09 Å. In the fourteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(22) and one H(11,12) atom. The C(20)-C(22) bond length is 1.40 Å. The C(20)-H(11,12) bond length is 1.09 Å. In the fifteenth C site, C(21) is bonded in a trigonal planar geometry to one C(19), one C(23), and one C(27) atom. The C(21)-C(23) bond length is 1.40 Å. The C(21)-C(27) bond length is 1.49 Å. In the sixteenth C site, C(22) is bonded in a trigonal planar geometry to one C(20), one C(24), and one C(28) atom. The C(22)-C(24) bond length is 1.40 Å. The C(22)-C(28) bond length is 1.49 Å. In the seventeenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(21); one C(25,26); and one H(13,14) atom. The C(23)-C(25,26) bond length is 1.39 Å. The C(23)-H(13,14) bond length is 1.09 Å. In the eighteenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(22); one C(25,26); and one H(13,14) atom. The C(24)-C(25,26) bond length is 1.39 Å. The C(24)-H(13,14) bond length is 1.09 Å. In the nineteenth C site, C(25,26) is bonded in a distorted trigonal planar geometry to one C(15), one C(23), and one H(15) atom. The C(25,26)-H(15) bond length is 1.09 Å. In the twentieth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(5), and one O(7) atom. The C(27)-O(5) bond length is 1.27 Å. The C(27)-O(7) bond length is 1.28 Å. In the twenty-first C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(6), and one O(8) atom. The C(28)-O(6) bond length is 1.27 Å. The C(28)-O(8) bond length is 1.28 Å. In the twenty-second C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(11), and one O(9) atom. The C(29)-C(31) bond length is 1.48 Å. The C(29)-O(11) bond length is 1.26 Å. The C(29)-O(9) bond length is 1.31 Å. In the twenty-third C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(10), and one O(12) atom. The C(30)-C(32) bond length is 1.48 Å. The C(30)-O(10) bond length is 1.31 Å. The C(30)-O(12) bond length is 1.26 Å. In the twenty-fourth C site, C(31) is bonded in a trigonal planar geometry to one C(29), one C(33), and one C(41) atom. The C(31)-C(33) bond length is 1.40 Å. The C(31)-C(41) bond length is 1.40 Å. In the twenty-fifth C site, C(32) is bonded in a trigonal planar geometry to one C(30), one C(34), and one C(42) atom. The C(32)-C(34) bond length is 1.40 Å. The C(32)-C(42) bond length is 1.40 Å. In the twenty-sixth C site, C(33) is bonded in a distorted single-bond geometry to one C(31), one C(35), and one H(17) atom. The C(33)-C(35) bond length is 1.39 Å. The C(33)-H(17) bond length is 1.09 Å. In the twenty-seventh C site, C(34) is bonded in a distorted single-bond geometry to one C(32), one C(36), and one H(18) atom. The C(34)-C(36) bond length is 1.39 Å. The C(34)-H(18) bond length is 1.09 Å. In the twenty-eighth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(33), one C(37), and one H(19) atom. The C(35)-C(37) bond length is 1.41 Å. The C(35)-H(19) bond length is 1.09 Å. In the twenty-ninth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(34), one C(38), and one H(20) atom. The C(36)-C(38) bond length is 1.41 Å. The C(36)-H(20) bond length is 1.09 Å. In the thirtieth C site, C(37) is bonded in a trigonal planar geometry to one C(35), one C(39), and one C(43) atom. The C(37)-C(39) bond length is 1.41 Å. The C(37)-C(43) bond length is 1.47 Å. In the thirty-first C site, C(38) is bonded in a trigonal planar geometry to one C(36), one C(40), and one C(44) atom. The C(38)-C(40) bond length is 1.41 Å. The C(38)-C(44) bond length is 1.47 Å. In the thirty-second C site, C(39) is bonded in a distorted single-bond geometry to one C(37) and one H(21,22) atom. The C(39)-H(21,22) bond length is 1.09 Å. In the thirty-third C site, C(40) is bonded in a distorted single-bond geometry to one C(38) and one H(21,22) atom. The C(40)-H(21,22) bond length is 1.09 Å. In the thirty-fourth C site, C(41) is bonded in a distorted single-bond geometry to one C(31) and one H(23,24) atom. The C(41)-H(23,24) bond length is 1.09 Å. In the thirty-fifth C site, C(42) is bonded in a distorted single-bond geometry to one C(32) and one H(23,24) atom. The C(42)-H(23,24) bond length is 1.09 Å. In the thirty-sixth C site, C(43) is bonded in a trigonal planar geometry to one C(37), one C(45), and one C(53) atom. The C(43)-C(45) bond length is 1.41 Å. The C(43)-C(53) bond length is 1.41 Å. In the thirty-seventh C site, C(44) is bonded in a trigonal planar geometry to one C(38), one C(46), and one C(54) atom. The C(44)-C(46) bond length is 1.41 Å. The C(44)-C(54) bond length is 1.41 Å. In the thirty-eighth C site, C(45) is bonded in a distorted single-bond geometry to one C(43); one C(47); and one H(25,26) atom. The C(45)-C(47) bond length is 1.39 Å. The C(45)-H(25,26) bond length is 1.09 Å. In the thirty-ninth C site, C(46) is bonded in a distorted single-bond geometry to one C(44); one C(48); and one H(25,26) atom. The C(46)-C(48) bond length is 1.39 Å. The C(46)-H(25,26) bond length is 1.09 Å. In the fortieth C site, C(47) is bonded in a distorted trigonal planar geometry to one C(45), one C(49), and one H(27) atom. The C(47)-C(49) bond length is 1.40 Å. The C(47)-H(27) bond length is 1.09 Å. In the forty-first C site, C(48) is bonded in a distorted trigonal planar geometry to one C(46), one C(50), and one H(28) atom. The C(48)-C(50) bond length is 1.40 Å. The C(48)-H(28) bond length is 1.09 Å. In the forty-second C site, C(49) is bonded in a trigonal planar geometry to one C(47), one C(51), and one C(55) atom. The C(49)-C(51) bond length is 1.40 Å. The C(49)-C(55) bond length is 1.48 Å. In the forty-third C site, C(50) is bonded in a trigonal planar geometry to one C(48), one C(52), and one C(56) atom. The C(50)-C(52) bond length is 1.40 Å. The C(50)-C(56) bond length is 1.48 Å. In the forty-fourth C site, C(51) is bonded in a distorted single-bond geometry to one C(49) and one H(29,30) atom. The C(51)-H(29,30) bond length is 1.09 Å. In the forty-fifth C site, C(52) is bonded in a distorted single-bond geometry to one C(50) and one H(29,30) atom. The C(52)-H(29,30) bond length is 1.09 Å. In the forty-sixth C site, C(53) is bonded in a distorted single-bond geometry to one C(43) and one H(31,32) atom. The C(53)-H(31,32) bond length is 1.09 Å. In the forty-seventh C site, C(54) is bonded in a distorted single-bond geometry to one C(44) and one H(31,32) atom. The C(54)-H(31,32) bond length is 1.09 Å. In the forty-eighth C site, C(55) is bonded in a distorted bent 120 degrees geometry to one C(49), one O(13), and one O(15) atom. The C(55)-O(13) bond length is 1.28 Å. The C(55)-O(15) bond length is 1.29 Å. In the forty-ninth C site, C(56) is bonded in a distorted bent 120 degrees geometry to one C(50), one O(14), and one O(16) atom. The C(56)-O(14) bond length is 1.28 Å. The C(56)-O(16) bond length is 1.29 Å. In the fiftieth C site, C(57) is bonded in a distorted bent 120 degrees geometry to one C(59), one O(17), and one O(19) atom. The C(57)-C(59) bond length is 1.50 Å. The C(57)-O(17) bond length is 1.29 Å. The C(57)-O(19) bond length is 1.26 Å. In the fifty-first C site, C(58) is bonded in a distorted bent 120 degrees geometry to one C(60), one O(18), and one O(20) atom. The C(58)-C(60) bond length is 1.50 Å. The C(58)-O(18) bond length is 1.29 Å. The C(58)-O(20) bond length is 1.26 Å. In the fifty-second C site, C(59) is bonded in a trigonal planar geometry to one C(57); one C(61,62); and one C(69,70) atom. The C(59)-C(61,62) bond length is 1.40 Å. The C(59)-C(69,70) bond length is 1.40 Å. In the fifty-third C site, C(60) is bonded in a trigonal planar geometry to one C(58); one C(61,62); and one C(69,70) atom. The C(60)-C(61,62) bond length is 1.40 Å. The C(60)-C(69,70) bond length is 1.40 Å. In the fifty-fourth C site, C(61,62) is bonded in a distorted trigonal planar geometry to one C(59); one C(63); and one H(33,34) atom. The C(61,62)-C(63) bond length is 1.39 Å. The C(61,62)-H(33,34) bond length is 1.09 Å. In the fifty-fifth C site, C(63) is bonded in a distorted trigonal planar geometry to one C(61,62); one C(65); and one H(35,36) atom. The C(63)-C(65) bond length is 1.41 Å. The C(63)-H(35,36) bond length is 1.09 Å. In the fifty-sixth C site, C(64) is bonded in a distorted trigonal planar geometry to one C(61,62); one C(66); and one H(35,36) atom. The C(64)-C(61,62) bond length is 1.39 Å. The C(64)-C(66) bond length is 1.41 Å. The C(64)-H(35,36) bond length is 1.09 Å. In the fifty-seventh C site, C(65) is bonded in a trigonal planar geometry to one C(63), one C(67), and one C(71) atom. The C(65)-C(67) bond length is 1.41 Å. The C(65)-C(71) bond length is 1.48 Å. In the fifty-eighth C site, C(66) is bonded in a trigonal planar geometry to one C(64), one C(68), and one C(72) atom. The C(66)-C(68) bond length is 1.41 Å. The C(66)-C(72) bond length is 1.48 Å. In the fifty-ninth C site, C(67) is bonded in a distorted single-bond geometry to one C(65) and one H(37,38) atom. The C(67)-H(37,38) bond length is 1.09 Å. In the sixtieth C site, C(68) is bonded in a distorted single-bond geometry to one C(66) and one H(37,38) atom. The C(68)-H(37,38) bond length is 1.09 Å. In the sixty-first C site, C(69,70) is bonded in a distorted single-bond geometry to one C(59) and one H(39,40) atom. The C(69,70)-H(39,40) bond length is 1.09 Å. In the sixty-second C site, C(71) is bonded in a trigonal planar geometry to one C(65), one C(73), and one C(81) atom. The C(71)-C(73) bond length is 1.41 Å. The C(71)-C(81) bond length is 1.41 Å. In the sixty-third C site, C(72) is bonded in a trigonal planar geometry to one C(66), one C(74), and one C(82) atom. The C(72)-C(74) bond length is 1.41 Å. The C(72)-C(82) bond length is 1.41 Å. In the sixty-fourth C site, C(73) is bonded in a distorted single-bond geometry to one C(71); one C(75); and one H(41,42) atom. The C(73)-C(75) bond length is 1.39 Å. The C(73)-H(41,42) bond length is 1.09 Å. In the sixty-fifth C site, C(74) is bonded in a distorted single-bond geometry to one C(72); one C(76); and one H(41,42) atom. The C(74)-C(76) bond length is 1.39 Å. The C(74)-H(41,42) bond length is 1.09 Å. In the sixty-sixth C site, C(75) is bonded in a distorted trigonal planar geometry to one C(73), one C(77), and one H(43) atom. The C(75)-C(77) bond length is 1.40 Å. The C(75)-H(43) bond length is 1.09 Å. In the sixty-seventh C site, C(76) is bonded in a distorted trigonal planar geometry to one C(74), one C(78), and one H(44) atom. The C(76)-C(78) bond length is 1.40 Å. The C(76)-H(44) bond length is 1.09 Å. In the sixty-eighth C site, C(77) is bonded in a trigonal planar geometry to one C(75), one C(79), and one C(83) atom. The C(77)-C(79) bond length is 1.40 Å. The C(77)-C(83) bond length is 1.50 Å. In the sixty-ninth C site, C(78) is bonded in a trigonal planar geometry to one C(76), one C(80), and one C(84) atom. The C(78)-C(80) bond length is 1.40 Å. The C(78)-C(84) bond length is 1.50 Å. In the seventieth C site, C(79) is bonded in a distorted single-bond geometry to one C(77); one C(81); and one H(45,46) atom. The C(79)-C(81) bond length is 1.39 Å. The C(79)-H(45,46) bond length is 1.09 Å. In the seventy-first C site, C(80) is bonded in a distorted single-bond geometry to one C(78); one C(82); and one H(45,46) atom. The C(80)-C(82) bond length is 1.39 Å. The C(80)-H(45,46) bond length is 1.09 Å. In the seventy-second C site, C(81) is bonded in a distorted trigonal planar geometry to one C(71), one C(79), and one H(47) atom. The C(81)-H(47) bond length is 1.09 Å. In the seventy-third C site, C(82) is bonded in a distorted trigonal planar geometry to one C(72), one C(80), and one H(48) atom. The C(82)-H(48) bond length is 1.09 Å. In the seventy-fourth C site, C(83) is bonded in a distorted bent 120 degrees geometry to one C(77), one O(21), and one O(23) atom. The C(83)-O(21) bond length is 1.29 Å. The C(83)-O(23) bond length is 1.26 Å. In the seventy-fifth C site, C(84) is bonded in a distorted bent 120 degrees geometry to one C(78), one O(22), and one O(24) atom. The C(84)-O(22) bond length is 1.29 Å. The C(84)-O(24) bond length is 1.26 Å. In the seventy-sixth C site, C(85,86) is bonded in a distorted trigonal planar geometry to one C(87), one N(1), and one H(49) atom. The C(85,86)-C(87) bond length is 1.38 Å. The C(85,86)-N(1) bond length is 1.35 Å. The C(85,86)-H(49) bond length is 1.09 Å. In the seventy-seventh C site, C(87) is bonded in a distorted single-bond geometry to one C(85,86); one C(89,90); and one H(51,52) atom. The C(87)-C(89,90) bond length is 1.41 Å. The C(87)-H(51,52) bond length is 1.09 Å. In the seventy-eighth C site, C(88) is bonded in a distorted single-bond geometry to one C(85,86); one C(89,90); and one H(51,52) atom. The C(88)-C(85,86) bond length is 1.38 Å. The C(88)-C(89,90) bond length is 1.41 Å. The C(88)-H(51,52) bond length is 1.09 Å. In the seventy-ninth C site, C(89,90) is bonded in a trigonal planar geometry to one C(87), one C(91), and one C(95) atom. The C(89,90)-C(91) bond length is 1.40 Å. The C(89,90)-C(95) bond length is 1.46 Å. In the eightieth C site, C(91) is bonded in a distorted single-bond geometry to one C(89,90); one C(93,94); and one H(53,54) atom. The C(91)-C(93,94) bond length is 1.39 Å. The C(91)-H(53,54) bond length is 1.09 Å. In the eighty-first C site, C(92) is bonded in a distorted single-bond geometry to one C(89,90); one C(93,94); and one H(53,54) atom. The C(92)-C(89,90) bond length is 1.40 Å. The C(92)-C(93,94) bond length is 1.39 Å. The C(92)-H(53,54) bond length is 1.09 Å. In the eighty-second C site, C(93,94) is bonded in a distorted trigonal planar geometry to one C(91); one N(1); and one H(55,56) atom. The C(93,94)-N(1) bond length is 1.35 Å. The C(93,94)-H(55,56) bond length is 1.09 Å. In the eighty-third C site, C(95) is bonded in a distorted bent 120 degrees geometry to one C(89,90); one N(3); and one H(57,58) atom. The C(95)-N(3) bond length is 1.29 Å. The C(95)-H(57,58) bond length is 1.10 Å. In the eighty-fourth C site, C(96) is bonded in a distorted bent 120 degrees geometry to one C(89,90); one N(4); and one H(57,58) atom. The C(96)-C(89,90) bond length is 1.46 Å. The C(96)-N(4) bond length is 1.29 Å. The C(96)-H(57,58) bond length is 1.10 Å. In the eighty-fifth C site, C(97) is bonded in a distorted bent 120 degrees geometry to one C(99,100); one N(5,6); and one H(59,60) atom. The C(97)-C(99,100) bond length is 1.46 Å. The C(97)-N(5,6) bond length is 1.29 Å. The C(97)-H(59,60) bond length is 1.10 Å. In the eighty-sixth C site, C(98) is bonded in a distorted bent 120 degrees geometry to one C(99,100); one N(5,6); and one H(59,60) atom. The C(98)-C(99,100) bond length is 1.46 Å. The C(98)-N(5,6) bond length is 1.29 Å. The C(98)-H(59,60) bond length is 1.10 Å. In the eighty-seventh C site, C(99,100) is bonded in a trigonal planar geometry to one C(103), one C(107), and one C(97) atom. The C(99,100)-C(103) bond length is 1.40 Å. The C(99,100)-C(107) bond length is 1.41 Å. In the eighty-eighth C site, C(101) is bonded in a distorted trigonal planar geometry to one C(103); one N(7); and one H(61,62) atom. The C(101)-C(103) bond length is 1.39 Å. The C(101)-N(7) bond length is 1.34 Å. The C(101)-H(61,62) bond length is 1.09 Å. In the eighty-ninth C site, C(102) is bonded in a distorted trigonal planar geometry to one C(104); one N(8); and one H(61,62) atom. The C(102)-C(104) bond length is 1.39 Å. The C(102)-N(8) bond length is 1.34 Å. The C(102)-H(61,62) bond length is 1.09 Å. In the ninetieth C site, C(103) is bonded in a distorted single-bond geometry to one C(101); one C(99,100); and one H(63,64) atom. The C(103)-H(63,64) bond length is 1.09 Å. In the ninety-first C site, C(104) is bonded in a distorted single-bond geometry to one C(102); one C(99,100); and one H(63,64) atom. The C(104)-C(99,100) bond length is 1.40 Å. The C(104)-H(63,64) bond length is 1.09 Å. In the ninety-second C site, C(105) is bonded in a distorted bent 120 degrees geometry to one C(107); one N(7); and one H(65,66) atom. The C(105)-C(107) bond length is 1.38 Å. The C(105)-N(7) bond length is 1.35 Å. The C(105)-H(65,66) bond length is 1.09 Å. In the ninety-third C site, C(106) is bonded in a distorted bent 120 degrees geometry to one C(108); one N(8); and one H(65,66) atom. The C(106)-C(108) bond length is 1.38 Å. The C(106)-N(8) bond length is 1.35 Å. The C(106)-H(65,66) bond length is 1.09 Å. In the ninety-fourth C site, C(107) is bonded in a distorted trigonal planar geometry to one C(105); one C(99,100); and one H(67,68) atom. The C(107)-H(67,68) bond length is 1.09 Å. In the ninety-fifth C site, C(108) is bonded in a distorted trigonal planar geometry to one C(106); one C(99,100); and one H(67,68) atom. The C(108)-C(99,100) bond length is 1.41 Å. The C(108)-H(67,68) bond length is 1.09 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(3,4); one C(85,86); and one C(93,94) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(3,4); one C(85,86); and one C(93,94) atom. The N(2)-Zn(3,4) bond length is 2.03 Å. The N(2)-C(85,86) bond length is 1.35 Å. The N(2)-C(93,94) bond length is 1.35 Å. In the third N site, N(3) is bonded in a distorted single-bond geometry to one C(95) and one N(5,6) atom. The N(3)-N(5,6) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one C(96) and one N(5,6) atom. The N(4)-N(5,6) bond length is 1.36 Å. In the fifth N site, N(5,6) is bonded in a distorted bent 120 degrees geometry to one C(97) and one N(3) atom. In the sixth N site, N(7) is bonded in a trigonal planar geometry to one Zn(6), one C(101), and one C(105) atom. In the seventh N site, N(8) is bonded in a trigonal planar geometry to one Zn(5), one C(102), and one C(106) atom. There are forty-one inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(5,6) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(7,8) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(11,12) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(13,14) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(17,18) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(13,14) is bonded in a single-bond geometry to one C(23) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(25,26) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(25,26) atom. The H(16)-C(25,26) bond length is 1.09 Å. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(33) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(34) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(35) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(36) atom. In the fourteenth H site, H(21,22) is bonded in a single-bond geometry to one C(39) atom. In the fifteenth H site, H(23,24) is bonded in a single-bond geometry to one C(41) atom. In the sixteenth H site, H(25,26) is bonded in a single-bond geometry to one C(45) atom. In the seventeenth H site, H(27) is bonded in a single-bond geometry to one C(47) atom. In the eighteenth H site, H(28) is bonded in a single-bond geometry to one C(48) atom. In the nineteenth H site, H(29,30) is bonded in a single-bond geometry to one C(51) atom. In the twentieth H site, H(31,32) is bonded in a single-bond geometry to one C(53) atom. In the twenty-first H site, H(33,34) is bonded in a single-bond geometry to one C(61,62) atom. In the twenty-second H site, H(35,36) is bonded in a single-bond geometry to one C(63) atom. In the twenty-third H site, H(37,38) is bonded in a single-bond geometry to one C(67) atom. In the twenty-fourth H site, H(39,40) is bonded in a single-bond geometry to one C(69,70) atom. In the twenty-fifth H site, H(41,42) is bonded in a single-bond geometry to one C(73) atom. In the twenty-sixth H site, H(43) is bonded in a single-bond geometry to one C(75) atom. In the twenty-seventh H site, H(44) is bonded in a single-bond geometry to one C(76) atom. In the twenty-eighth H site, H(45,46) is bonded in a single-bond geometry to one C(79) atom. In the twenty-ninth H site, H(47) is bonded in a single-bond geometry to one C(81) atom. In the thirtieth H site, H(48) is bonded in a single-bond geometry to one C(82) atom. In the thirty-first H site, H(49) is bonded in a single-bond geometry to one C(85,86) atom. In the thirty-second H site, H(50) is bonded in a single-bond geometry to one C(85,86) atom. The H(50)-C(85,86) bond length is 1.09 Å. In the thirty-third H site, H(51,52) is bonded in a single-bond geometry to one C(87) atom. In the thirty-fourth H site, H(53,54) is bonded in a single-bond geometry to one C(91) atom. In the thirty-fifth H site, H(55,56) is bonded in a single-bond geometry to one C(93,94) atom. In the thirty-sixth H site, H(57,58) is bonded in a single-bond geometry to one C(95) atom. In the thirty-seventh H site, H(59,60) is bonded in a single-bond geometry to one C(97) atom. In the thirty-eighth H site, H(61,62) is bonded in a single-bond geometry to one C(101) atom. In the thirty-ninth H site, H(63,64) is bonded in a single-bond geometry to one C(103) atom. In the fortieth H site, H(65,66) is bonded in a single-bond geometry to one C(105) atom. In the forty-first H site, H(67,68) is bonded in a single-bond geometry to one C(107) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(3,4) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(3,4) and one C(2) atom. The O(4)-Zn(3,4) bond length is 1.98 Å. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(27) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(28) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(3,4) and one C(27) atom. The O(7)-Zn(3,4) bond length is 1.95 Å. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(3,4) and one C(28) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one Zn(1); one Zn(3,4); and one C(29) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Zn(2); one Zn(3,4); and one C(30) atom. The O(10)-Zn(3,4) bond length is 2.06 Å. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Zn(3,4) and one C(29) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Zn(3,4) and one C(30) atom. The O(12)-Zn(3,4) bond length is 2.41 Å. In the thirteenth O site, O(13) is bonded in an L-shaped geometry to one Zn(5) and one C(55) atom. In the fourteenth O site, O(14) is bonded in an L-shaped geometry to one Zn(6) and one C(56) atom. In the fifteenth O site, O(15) is bonded in a distorted T-shaped geometry to one Zn(1), one Zn(5), and one C(55) atom. In the sixteenth O site, O(16) is bonded in a distorted T-shaped geometry to one Zn(2), one Zn(6), and one C(56) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(57) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(58) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(57) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(58) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(83) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(84) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(83) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(84) atom. Linkers: 4 [CH]([N]/N=C/c1ccncc1)c1ccncc1 ,12 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 O=[C]O[Zn]1O[C]O[Zn]23(O[C]O[Zn](O[C]O2)O[C]O3)O[C]O1. The MOF has largest included sphere 9.08 A, density 0.94 g/cm3, surface area 4605.21 m2/g, accessible volume 0.54 cm3/g