CoC11N2H12O7(CH)5CH2COCHO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules, two dimethyl ether molecules, two methanol molecules, and one CoC11N2H12O7 cluster. In the CoC11N2H12O7 cluster, Co(1) is bonded in an octahedral geometry to one N(1), one N(2), one O(3), one O(7), one O(8), and one O(9) atom. The Co(1)-N(1) bond length is 2.11 Å. The Co(1)-N(2) bond length is 2.12 Å. The Co(1)-O(3) bond length is 2.12 Å. The Co(1)-O(7) bond length is 2.17 Å. The Co(1)-O(8) bond length is 2.03 Å. The Co(1)-O(9) bond length is 2.16 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(5) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one O(1) atom. The C(4)-O(1) bond length is 1.35 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(8) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(2), and one H(9) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-N(2) bond length is 1.35 Å. The C(6)-H(9) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(10) atom. The C(7)-H(10) bond length is 1.09 Å. In the sixth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(12) bond length is 1.09 Å. In the seventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(11)-O(3) bond length is 1.26 Å. The C(11)-O(4) bond length is 1.28 Å. In the eighth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(16) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(16) bond length is 1.09 Å. In the ninth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(19) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(19) bond length is 1.48 Å. In the tenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(17) atom. The C(17)-H(17) bond length is 1.09 Å. In the eleventh C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(6), and one O(7) atom. The C(19)-O(6) bond length is 1.28 Å. The C(19)-O(7) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(10), and one C(6) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) and one O(8) atom. The H(1)-O(7) bond length is 1.73 Å. The H(1)-O(8) bond length is 1.00 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(8) atom. The H(2)-O(8) bond length is 1.00 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(6) and one O(9) atom. The H(3)-O(6) bond length is 1.63 Å. The H(3)-O(9) bond length is 1.01 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(9) atom. The H(4)-O(9) bond length is 1.00 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(19) is bonded in a linear geometry to one O(1) and one O(6) atom. The H(19)-O(1) bond length is 1.02 Å. The H(19)-O(6) bond length is 1.54 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(4) and one H(19) atom. In the second O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(11) atom. In the third O site, O(4) is bonded in a 1-coordinate geometry to one C(11) atom. In the fourth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one C(19), one H(19), and one H(3) atom. In the fifth O site, O(7) is bonded in a 3-coordinate geometry to one Co(1), one C(19), and one H(1) atom. In the sixth O site, O(8) is bonded in a distorted trigonal planar geometry to one Co(1), one H(1), and one H(2) atom. In the seventh O site, O(9) is bonded in a distorted water-like geometry to one Co(1), one H(3), and one H(4) atom. Linkers: 2 [O]C(=O)COc1ccc(C([O])=O)cc1. Metal clusters: 2 [Co]. The MOF has largest included sphere 1.97 A, density 1.66 g/cm3, surface area 4516.48 m2/g, accessible volume 0.09 cm3/g