(CdC20N3H18O4)2(CH2)9 is Indium-derived structured and crystallizes in the orthorhombic C222_1 space group. The structure is zero-dimensional and consists of thirty-six 02329_fluka molecules and eight CdC20N3H18O4 clusters. In each CdC20N3H18O4 cluster, Cd(1) is bonded in a distorted pentagonal bipyramidal geometry to one N(1), one N(2), one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.36 Å. The Cd(1)-N(2) bond length is 2.43 Å. The Cd(1)-N(3) bond length is 2.40 Å. The Cd(1)-O(1) bond length is 2.58 Å. The Cd(1)-O(2) bond length is 2.40 Å. The Cd(1)-O(3) bond length is 2.31 Å. The Cd(1)-O(4) bond length is 2.66 Å. There are twenty inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(15), one C(3), and one H(9) atom. The C(9)-C(15) bond length is 1.40 Å. The C(9)-C(3) bond length is 1.39 Å. The C(9)-H(9) bond length is 1.09 Å. In the second C site, C(10) is bonded in a distorted single-bond geometry to one C(15), one C(4), and one H(10) atom. The C(10)-C(15) bond length is 1.40 Å. The C(10)-C(4) bond length is 1.39 Å. The C(10)-H(10) bond length is 1.09 Å. In the third C site, C(11) is bonded in a distorted single-bond geometry to one C(16), one C(5), and one H(11) atom. The C(11)-C(16) bond length is 1.40 Å. The C(11)-C(5) bond length is 1.39 Å. The C(11)-H(11) bond length is 1.09 Å. In the fourth C site, C(12) is bonded in a distorted single-bond geometry to one C(16), one C(6), and one H(12) atom. The C(12)-C(16) bond length is 1.40 Å. The C(12)-C(6) bond length is 1.39 Å. The C(12)-H(12) bond length is 1.09 Å. In the fifth C site, C(15) is bonded in a trigonal planar geometry to one C(10), one C(17), and one C(9) atom. The C(15)-C(17) bond length is 1.50 Å. In the sixth C site, C(16) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(18) atom. The C(16)-C(18) bond length is 1.50 Å. In the seventh C site, C(17) is bonded in a distorted water-like geometry to one C(15), one H(15), and one H(16) atom. The C(17)-H(15) bond length is 1.10 Å. The C(17)-H(16) bond length is 1.10 Å. In the eighth C site, C(18) is bonded in a distorted water-like geometry to one C(16), one H(17), and one H(18) atom. The C(18)-H(17) bond length is 1.10 Å. The C(18)-H(18) bond length is 1.10 Å. In the ninth C site, C(21) is bonded in a distorted water-like geometry to one C(22), one H(22), and one H(23) atom. The C(21)-C(22) bond length is 1.50 Å. The C(21)-H(22) bond length is 1.10 Å. The C(21)-H(23) bond length is 1.10 Å. In the tenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(24) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(24) bond length is 1.40 Å. In the eleventh C site, C(23) is bonded in a distorted single-bond geometry to one C(22), one C(25), and one H(24) atom. The C(23)-C(25) bond length is 1.39 Å. The C(23)-H(24) bond length is 1.09 Å. In the twelfth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(22), one C(26), and one H(25) atom. The C(24)-C(26) bond length is 1.39 Å. The C(24)-H(25) bond length is 1.09 Å. In the thirteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(23), one N(3), and one H(26) atom. The C(25)-N(3) bond length is 1.35 Å. The C(25)-H(26) bond length is 1.09 Å. In the fourteenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(24), one N(3), and one H(27) atom. The C(26)-N(3) bond length is 1.35 Å. The C(26)-H(27) bond length is 1.09 Å. In the fifteenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the sixteenth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(2)-O(3) bond length is 1.29 Å. The C(2)-O(4) bond length is 1.26 Å. In the seventeenth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(1) atom. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(1) bond length is 1.09 Å. In the eighteenth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(2) atom. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(2) bond length is 1.09 Å. In the nineteenth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one H(3) atom. The C(5)-N(2) bond length is 1.34 Å. The C(5)-H(3) bond length is 1.09 Å. In the twentieth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(4) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-H(4) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(5), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(25), and one C(26) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(21) atom. In the fourteenth H site, H(23) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(24) is bonded in a single-bond geometry to one C(23) atom. In the sixteenth H site, H(25) is bonded in a single-bond geometry to one C(24) atom. In the seventeenth H site, H(26) is bonded in a single-bond geometry to one C(25) atom. In the eighteenth H site, H(27) is bonded in a single-bond geometry to one C(26) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cd(1) and one C(2) atom. Linkers: 2 c1cc(CCCc2ccncc2)ccn1 ,4 [O]C(=O)CCCC([O])=O. Metal clusters: 4 O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 4.45 A, density 1.28 g/cm3, surface area 5001.12 m2/g, accessible volume 0.21 cm3/g