ZnC18H12(N3O2)2C9H6NNNC5H4N is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two schembl1705614 molecules, two NNC5H4N clusters, and two ZnC18H12(N3O2)2 clusters. In each NNC5H4N cluster, there are five inequivalent C sites. In the first C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(16), and one N(9) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(16) bond length is 1.40 Å. The C(11)-N(9) bond length is 1.41 Å. In the second C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(9) atom. The C(12)-H(9) bond length is 1.09 Å. In the third C site, C(31) is bonded in a trigonal planar geometry to one N(1), one N(9), and one H(21) atom. The C(31)-N(1) bond length is 1.33 Å. The C(31)-N(9) bond length is 1.36 Å. The C(31)-H(21) bond length is 1.08 Å. In the fourth C site, C(16) is bonded in a distorted single-bond geometry to one C(11) and one H(12) atom. The C(16)-H(12) bond length is 1.09 Å. In the fifth C site, C(32) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(22) atom. The C(32)-N(1) bond length is 1.37 Å. The C(32)-N(2) bond length is 1.33 Å. The C(32)-H(22) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one C(31) and one C(32) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(32) and one N(9) atom. The N(2)-N(9) bond length is 1.37 Å. In the third N site, N(9) is bonded in a distorted trigonal planar geometry to one C(11), one C(31), and one N(2) atom. There are four inequivalent H sites. In the first H site, H(21) is bonded in a single-bond geometry to one C(31) atom. In the second H site, H(22) is bonded in a single-bond geometry to one C(32) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In each ZnC18H12(N3O2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(3), one N(6), one O(1), and one O(3) atom. The Zn(1)-N(3) bond length is 2.00 Å. The Zn(1)-N(6) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(3) bond length is 1.94 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(1) atom. The C(1)-N(3) bond length is 1.37 Å. The C(1)-N(4) bond length is 1.32 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(3), one N(5), and one H(2) atom. The C(2)-N(3) bond length is 1.33 Å. The C(2)-N(5) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(6), one N(7), and one H(3) atom. The C(3)-N(6) bond length is 1.37 Å. The C(3)-N(7) bond length is 1.32 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(6), one N(8), and one H(4) atom. The C(4)-N(6) bond length is 1.34 Å. The C(4)-N(8) bond length is 1.35 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one N(5) atom. The C(5)-C(10) bond length is 1.40 Å. The C(5)-C(6) bond length is 1.40 Å. The C(5)-N(5) bond length is 1.42 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(5) and one H(8) atom. The C(10)-H(8) bond length is 1.09 Å. In the eighth C site, C(19) is bonded in a distorted single-bond geometry to one C(20) and one H(14) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(14) bond length is 1.09 Å. In the ninth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one N(8) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-N(8) bond length is 1.42 Å. In the tenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(15) atom. The C(21)-H(15) bond length is 1.09 Å. In the eleventh C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(3), and one O(4) atom. The C(23)-C(26) bond length is 1.50 Å. The C(23)-O(3) bond length is 1.30 Å. The C(23)-O(4) bond length is 1.25 Å. In the twelfth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(1), and one O(2) atom. The C(24)-C(29) bond length is 1.50 Å. The C(24)-O(1) bond length is 1.29 Å. The C(24)-O(2) bond length is 1.26 Å. In the thirteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(26) and one H(17) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-H(17) bond length is 1.09 Å. In the fourteenth C site, C(26) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(27) atom. The C(26)-C(27) bond length is 1.40 Å. In the fifteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(18) atom. The C(27)-H(18) bond length is 1.09 Å. In the sixteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(29) and one H(19) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-H(19) bond length is 1.09 Å. In the seventeenth C site, C(29) is bonded in a trigonal planar geometry to one C(24), one C(28), and one C(30) atom. The C(29)-C(30) bond length is 1.40 Å. In the eighteenth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(20) atom. The C(30)-H(20) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. In the second N site, N(4) is bonded in a distorted water-like geometry to one C(1) and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the third N site, N(5) is bonded in a distorted trigonal planar geometry to one C(2), one C(5), and one N(4) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one Zn(1), one C(3), and one C(4) atom. In the fifth N site, N(7) is bonded in a distorted water-like geometry to one C(3) and one N(8) atom. The N(7)-N(8) bond length is 1.37 Å. In the sixth N site, N(8) is bonded in a distorted trigonal planar geometry to one C(20), one C(4), and one N(7) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(27) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(28) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(30) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(24) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(24) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(23) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(23) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)cc1 ,2 [CH]1N=C[N]N1c1ccc(N(c2ccc(N3[CH]N=C[N]3)cc2)c2ccc(-n3cncn3)cc2)cc1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.67 A, density 1.43 g/cm3, surface area 4786.61 m2/g, accessible volume 0.24 cm3/g