AgC5H4(NO)2C13NH7O2CF3 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two trifluoromethane molecules, two AgC5H4(NO)2 clusters, and two C13NH7O2 clusters. In each AgC5H4(NO)2 cluster, Ag(1) is bonded in a 3-coordinate geometry to one N(1), one N(3), and one O(3) atom. The Ag(1)-N(1) bond length is 2.14 Å. The Ag(1)-N(3) bond length is 2.16 Å. The Ag(1)-O(3) bond length is 2.55 Å. There are five inequivalent C sites. In the first C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the second C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(8) atom. The C(13)-N(3) bond length is 1.35 Å. The C(13)-H(8) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the fourth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(11) atom. The C(17)-N(3) bond length is 1.35 Å. The C(17)-H(11) bond length is 1.09 Å. In the fifth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(19)-O(3) bond length is 1.26 Å. The C(19)-O(4) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(13), and one C(17) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one Ag(1) and one C(19) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(19) atom. In each C13NH7O2 cluster, there are thirteen inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.50 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a single-bond geometry to one C(3), one C(7), and one O(1) atom. The C(6)-C(7) bond length is 1.50 Å. The C(6)-O(1) bond length is 1.23 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(2) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-N(2) bond length is 1.34 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(5) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(5) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(6) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(6) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(7) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-H(7) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(2) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-N(2) bond length is 1.34 Å. In the tenth C site, C(12) is bonded in a single-bond geometry to one C(11), one C(15), and one O(2) atom. The C(12)-C(15) bond length is 1.50 Å. The C(12)-O(2) bond length is 1.24 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(9) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(9) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(15)-C(16) bond length is 1.40 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(10) atom. The C(16)-H(10) bond length is 1.08 Å. N(2) is bonded in a bent 120 degrees geometry to one C(11) and one C(7) atom. There are seven inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(16) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(12) atom. Linkers: 2 O=C(c1c[c]ncc1)c1cccc(C(=O)c2ccncc2)n1 ,2 O=C(c1ccncc1)c1cccc(C(=O)c2ccncc2)n1 ,2 O=C(c1[c][c]ncc1)c1cccc(C(=O)c2ccncc2)n1. Metal clusters: 2 [Ag]. The MOF has largest included sphere 1.88 A, density 1.90 g/cm3, surface area 3822.92 m2/g, accessible volume 0.11 cm3/g