CuC3NH6ICH3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CuC3NH6I clusters. In each CuC3NH6I cluster, Cu(1) is bonded in a distorted single-bond geometry to one N(1) and two equivalent I(1) atoms. The Cu(1)-N(1) bond length is 2.04 Å. There is one shorter (2.55 Å) and one longer (2.59 Å) Cu(1)-I(1) bond length. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(1)-N(1) bond length is 1.48 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.11 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent H(3,4) atoms. The C(2)-N(1) bond length is 1.48 Å. There is one shorter (1.10 Å) and one longer (1.11 Å) C(2)-H(3,4) bond length. In the third C site, C(3) is bonded in a 3-coordinate geometry to one N(1), one H(5), and one H(6) atom. The C(3)-N(1) bond length is 1.49 Å. The C(3)-H(5) bond length is 1.11 Å. The C(3)-H(6) bond length is 1.10 Å. N(1) is bonded in a tetrahedral geometry to one Cu(1), one C(1), one C(2), and one C(3) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 1 CCN1CCN(CC)CC1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 1.98 A, density 2.47 g/cm3, surface area 3180.76 m2/g, accessible volume 0.11 cm3/g