AgC10N3H9S2O5CF3 crystallizes in the monoclinic P2_1 space group. The structure consists of two trifluoromethane molecules inside a AgC10N3H9S2O5 framework. In the AgC10N3H9S2O5 framework, Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one O(3), and one O(5) atom. The Ag(1)-N(1) bond length is 2.13 Å. The Ag(1)-N(2) bond length is 2.15 Å. The Ag(1)-O(3) bond length is 2.68 Å. The Ag(1)-O(5) bond length is 2.79 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(2) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(3) atom. The C(2)-C(4) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(10), and one S(2) atom. The C(3)-C(10) bond length is 1.40 Å. The C(3)-S(2) bond length is 1.77 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(10), one C(2), and one H(4) atom. The C(4)-C(10) bond length is 1.39 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(8), one C(9), and one N(3) atom. The C(5)-C(8) bond length is 1.40 Å. The C(5)-C(9) bond length is 1.40 Å. The C(5)-N(3) bond length is 1.42 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(6) atom. The C(7)-N(1) bond length is 1.35 Å. The C(7)-H(6) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(7) atom. The C(8)-N(1) bond length is 1.35 Å. The C(8)-H(7) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(5) and one H(8) atom. The C(9)-H(8) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(3), one C(4), and one H(9) atom. The C(10)-H(9) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(7), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(2) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one H(1), and one S(2) atom. The N(3)-H(1) bond length is 1.04 Å. The N(3)-S(2) bond length is 1.65 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one N(3) and one O(2) atom. The H(1)-O(2) bond length is 1.72 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.45 Å. The S(1)-O(2) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.46 Å. In the second S site, S(2) is bonded in a distorted tetrahedral geometry to one C(3), one N(3), one O(4), and one O(5) atom. The S(2)-O(4) bond length is 1.44 Å. The S(2)-O(5) bond length is 1.44 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one H(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Ag(1) and one S(2) atom. Linkers: 2 O=S(=O)(Nc1cccnc1)c1cccnc1. Metal clusters: 2 O=S=O.[Ag].[O]S([O])([O])C(F)(F)F. The MOF has largest included sphere 4.21 A, density 1.70 g/cm3, surface area 3951.91 m2/g, accessible volume 0.17 cm3/g