Cd5C14H16(N3O4)4(CH2)12 crystallizes in the triclinic P-1 space group. The structure consists of twelve 02329_fluka molecules inside a Cd5C14H16(N3O4)4 framework. In the Cd5C14H16(N3O4)4 framework, there are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one N(3), one N(6), one O(2), one O(3), one O(5), and one O(7) atom to form edge-sharing CdN2O4 octahedra. The Cd(1)-N(3) bond length is 2.31 Å. The Cd(1)-N(6) bond length is 2.29 Å. The Cd(1)-O(2) bond length is 2.30 Å. The Cd(1)-O(3) bond length is 2.36 Å. The Cd(1)-O(5) bond length is 2.41 Å. The Cd(1)-O(7) bond length is 2.31 Å. In the second Cd site, Cd(2) is bonded to one N(1), one N(4), one O(1), one O(3), one O(5), and one O(8) atom to form distorted CdN2O4 octahedra that share  a cornercorner with one Cd(3)N4O2 octahedra and  an edgeedge with one Cd(1)N2O4 octahedra. The corner-sharing octahedral tilt angles are 79°. The Cd(2)-N(1) bond length is 2.30 Å. The Cd(2)-N(4) bond length is 2.27 Å. The Cd(2)-O(1) bond length is 2.50 Å. The Cd(2)-O(3) bond length is 2.67 Å. The Cd(2)-O(5) bond length is 2.24 Å. The Cd(2)-O(8) bond length is 2.48 Å. In the third Cd site, Cd(3) is bonded to two equivalent N(2), two equivalent N(5), and two equivalent O(1) atoms to form corner-sharing CdN4O2 octahedra. The corner-sharing octahedral tilt angles are 79°. Both Cd(3)-N(2) bond lengths are 2.33 Å. Both Cd(3)-N(5) bond lengths are 2.31 Å. Both Cd(3)-O(1) bond lengths are 2.47 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(5) atom. The C(1)-N(2) bond length is 1.33 Å. The C(1)-N(3) bond length is 1.36 Å. The C(1)-H(5) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(6) atom. The C(2)-N(1) bond length is 1.33 Å. The C(2)-N(3) bond length is 1.35 Å. The C(2)-H(6) bond length is 1.08 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(7) atom. The C(3)-N(5) bond length is 1.33 Å. The C(3)-N(6) bond length is 1.35 Å. The C(3)-H(7) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(8) atom. The C(4)-N(4) bond length is 1.33 Å. The C(4)-N(6) bond length is 1.35 Å. The C(4)-H(8) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(5)-O(1) bond length is 1.28 Å. The C(5)-O(2) bond length is 1.26 Å. In the sixth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(10)-O(3) bond length is 1.30 Å. The C(10)-O(4) bond length is 1.25 Å. In the seventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(11)-O(5) bond length is 1.30 Å. The C(11)-O(6) bond length is 1.26 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(2), and one N(2) atom. The N(1)-N(2) bond length is 1.37 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Cd(3), one C(1), and one N(1) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one Cd(2), one C(4), and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cd(3), one C(3), and one N(4) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(3), and one C(4) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. The H(1)-O(7) bond length is 1.00 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. The H(2)-O(7) bond length is 1.00 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(8) atom. The H(3)-O(8) bond length is 1.00 Å. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(4) and one O(8) atom. The H(4)-O(4) bond length is 1.70 Å. The H(4)-O(8) bond length is 1.00 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(2), one Cd(3), and one C(5) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(5) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(10) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one C(10) and one H(4) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(2), and one C(11) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one C(11) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Cd(1), one H(1), and one H(2) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Cd(2), one H(3), and one H(4) atom. Linkers: 3 [O]C(=O)CCCCC([O])=O ,4 C1=NN=C[N]1. Metal clusters: 1 O.O.O.O.O=[C]O[Cd]O[C]O[Cd]12(O[C]O[Cd]O[C]=O)(N=N[Cd](O[C]=O)N=N1)N=N[Cd](O[C]=O)N=N2. RCSR code: sql. The MOF has largest included sphere 2.48 A, density 2.31 g/cm3, surface area 3036.86 m2/g, accessible volume 0.12 cm3/g