V2ZnC8H10(N2O3)2(CH2)2 crystallizes in the monoclinic Cc space group. The structure consists of sixteen 02329_fluka molecules inside a V2ZnC8H10(N2O3)2 framework. In the V2ZnC8H10(N2O3)2 framework, there are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(11), and one O(8) atom to form VO4 tetrahedra that share  a cornercorner with one V(2)O4 tetrahedra,  a cornercorner with one V(4)O4 tetrahedra, and  a cornercorner with one Zn(2)N2O2 tetrahedra. The V(1)-O(1) bond length is 1.81 Å. The V(1)-O(10) bond length is 1.69 Å. The V(1)-O(11) bond length is 1.63 Å. The V(1)-O(8) bond length is 1.79 Å. In the second V site, V(2) is bonded to one O(6), one O(7), one O(8), and one O(9) atom to form VO4 tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(3)O4 tetrahedra, and  a cornercorner with one Zn(1)N2O2 tetrahedra. The V(2)-O(6) bond length is 1.80 Å. The V(2)-O(7) bond length is 1.63 Å. The V(2)-O(8) bond length is 1.79 Å. The V(2)-O(9) bond length is 1.69 Å. In the third V site, V(3) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form VO4 tetrahedra that share  a cornercorner with one V(2)O4 tetrahedra,  a cornercorner with one V(4)O4 tetrahedra, and  a cornercorner with one Zn(2)N2O2 tetrahedra. The V(3)-O(3) bond length is 1.81 Å. The V(3)-O(4) bond length is 1.70 Å. The V(3)-O(5) bond length is 1.63 Å. The V(3)-O(6) bond length is 1.79 Å. In the fourth V site, V(4) is bonded to one O(1), one O(12), one O(2), and one O(3) atom to form VO4 tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(3)O4 tetrahedra, and  a cornercorner with one Zn(1)N2O2 tetrahedra. The V(4)-O(1) bond length is 1.80 Å. The V(4)-O(12) bond length is 1.69 Å. The V(4)-O(2) bond length is 1.63 Å. The V(4)-O(3) bond length is 1.81 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(5), one N(8), one O(12), and one O(9) atom to form ZnN2O2 tetrahedra that share  a cornercorner with one V(2)O4 tetrahedra and  a cornercorner with one V(4)O4 tetrahedra. The Zn(1)-N(5) bond length is 2.01 Å. The Zn(1)-N(8) bond length is 2.00 Å. The Zn(1)-O(12) bond length is 1.96 Å. The Zn(1)-O(9) bond length is 1.96 Å. In the second Zn site, Zn(2) is bonded to one N(1), one N(4), one O(10), and one O(4) atom to form ZnN2O2 tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra and  a cornercorner with one V(3)O4 tetrahedra. The Zn(2)-N(1) bond length is 2.00 Å. The Zn(2)-N(4) bond length is 2.00 Å. The Zn(2)-O(10) bond length is 1.93 Å. The Zn(2)-O(4) bond length is 1.95 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-N(1) bond length is 1.39 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(2), and one H(2) atom. The C(2)-N(2) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-N(2) bond length is 1.35 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent H(4,5) atoms. The C(4)-N(2) bond length is 1.46 Å. Both C(4)-H(4,5) bond lengths are 1.10 Å. In the fifth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(10), and one H(11) atom. The C(7)-N(3) bond length is 1.47 Å. The C(7)-H(10) bond length is 1.10 Å. The C(7)-H(11) bond length is 1.10 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(3), and one H(12) atom. The C(8)-C(9) bond length is 1.37 Å. The C(8)-N(3) bond length is 1.38 Å. The C(8)-H(12) bond length is 1.08 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(4), and one H(13) atom. The C(9)-N(4) bond length is 1.39 Å. The C(9)-H(13) bond length is 1.08 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(14) atom. The C(10)-N(3) bond length is 1.35 Å. The C(10)-N(4) bond length is 1.33 Å. The C(10)-H(14) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(5), and one H(15) atom. The C(11)-C(12) bond length is 1.37 Å. The C(11)-N(5) bond length is 1.39 Å. The C(11)-H(15) bond length is 1.08 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(6), and one H(16) atom. The C(12)-N(6) bond length is 1.38 Å. The C(12)-H(16) bond length is 1.08 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(17) atom. The C(13)-N(5) bond length is 1.34 Å. The C(13)-N(6) bond length is 1.35 Å. The C(13)-H(17) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(18), and one H(19) atom. The C(14)-N(6) bond length is 1.47 Å. The C(14)-H(18) bond length is 1.10 Å. The C(14)-H(19) bond length is 1.10 Å. In the thirteenth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one N(7), one H(24), and one H(25) atom. The C(17)-N(7) bond length is 1.47 Å. The C(17)-H(24) bond length is 1.10 Å. The C(17)-H(25) bond length is 1.10 Å. In the fourteenth C site, C(18) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(26) atom. The C(18)-N(7) bond length is 1.35 Å. The C(18)-N(8) bond length is 1.34 Å. The C(18)-H(26) bond length is 1.09 Å. In the fifteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(8), and one H(27) atom. The C(19)-C(20) bond length is 1.37 Å. The C(19)-N(8) bond length is 1.39 Å. The C(19)-H(27) bond length is 1.08 Å. In the sixteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(7), and one H(28) atom. The C(20)-N(7) bond length is 1.38 Å. The C(20)-H(28) bond length is 1.08 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(8) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(2), one C(10), and one C(9) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(13) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(14) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(20) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Zn(1), one C(18), and one C(19) atom. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4,5) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(14) atom. In the fifteenth H site, H(24) is bonded in a single-bond geometry to one C(17) atom. In the sixteenth H site, H(25) is bonded in a single-bond geometry to one C(17) atom. In the seventeenth H site, H(26) is bonded in a single-bond geometry to one C(18) atom. In the eighteenth H site, H(27) is bonded in a single-bond geometry to one C(19) atom. In the nineteenth H site, H(28) is bonded in a single-bond geometry to one C(20) atom. There are twelve inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one V(3) atom. In the second O site, O(6) is bonded in a bent 150 degrees geometry to one V(2) and one V(3) atom. In the third O site, O(7) is bonded in a single-bond geometry to one V(2) atom. In the fourth O site, O(8) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the fifth O site, O(9) is bonded in a bent 120 degrees geometry to one V(2) and one Zn(1) atom. In the sixth O site, O(10) is bonded in a bent 150 degrees geometry to one V(1) and one Zn(2) atom. In the seventh O site, O(11) is bonded in a single-bond geometry to one V(1) atom. In the eighth O site, O(12) is bonded in a bent 120 degrees geometry to one V(4) and one Zn(1) atom. In the ninth O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one V(4) atom. In the tenth O site, O(2) is bonded in a single-bond geometry to one V(4) atom. In the eleventh O site, O(3) is bonded in a bent 120 degrees geometry to one V(3) and one V(4) atom. In the twelfth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one V(3) and one Zn(2) atom. Linkers: 2 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 8 [V] ,4 [Zn]. The MOF has largest included sphere 2.15 A, density 1.89 g/cm3, surface area 3932.84 m2/g, accessible volume 0.13 cm3/g