(CH2)2CuC20H14S4(N5O7)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one CuC20H14S4(N5O7)2 cluster. In the CuC20H14S4(N5O7)2 cluster, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent N(4) and two equivalent O(1) atoms. Both Cu(1)-N(4) bond lengths are 1.98 Å. Both Cu(1)-O(1) bond lengths are 1.97 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-C(6) bond length is 1.45 Å. The C(1)-N(1) bond length is 1.46 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(2) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-N(2) bond length is 1.45 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(3) atom. The C(5)-C(6) bond length is 1.45 Å. The C(5)-N(3) bond length is 1.45 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one O(1) atom. The C(6)-O(1) bond length is 1.28 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(8), one H(3), one H(4), and one H(5) atom. The C(7)-C(8) bond length is 1.48 Å. The C(7)-H(3) bond length is 1.09 Å. The C(7)-H(4) bond length is 1.10 Å. The C(7)-H(5) bond length is 1.10 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one N(4), and one S(1) atom. The C(8)-N(4) bond length is 1.32 Å. The C(8)-S(1) bond length is 1.72 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one N(5), one S(1), and one S(2) atom. The C(9)-N(5) bond length is 1.31 Å. The C(9)-S(1) bond length is 1.75 Å. The C(9)-S(2) bond length is 1.73 Å. In the tenth C site, C(10) is bonded in a distorted water-like geometry to one H(6), one H(7), and one S(2) atom. The C(10)-H(6) bond length is 1.10 Å. The C(10)-H(7) bond length is 1.10 Å. The C(10)-S(2) bond length is 1.83 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one O(2), and one O(3) atom. The N(1)-O(2) bond length is 1.24 Å. The N(1)-O(3) bond length is 1.25 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(3), one O(4), and one O(5) atom. The N(2)-O(4) bond length is 1.24 Å. The N(2)-O(5) bond length is 1.24 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(5), one O(6), and one O(7) atom. The N(3)-O(6) bond length is 1.24 Å. The N(3)-O(7) bond length is 1.25 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(8), and one N(5) atom. The N(4)-N(5) bond length is 1.36 Å. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(9) and one N(4) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(8) and one C(9) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(10) and one C(9) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one N(3) atom. Linkers: 1 Cc1nnc(SCCCCSc2nnc(C)s2)s1. Metal clusters: 1 [Cu]. The MOF has largest included sphere 1.98 A, density 1.80 g/cm3, surface area 4189.67 m2/g, accessible volume 0.11 cm3/g