(CH)6CH2AgC9NH6O2F is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, two 02329_fluka molecules, and one AgC9NH6O2F cluster. In the AgC9NH6O2F cluster, Ag(1) is bonded in a 3-coordinate geometry to one N(1), one O(1), and one O(2) atom. The Ag(1)-N(1) bond length is 2.43 Å. The Ag(1)-O(1) bond length is 2.24 Å. The Ag(1)-O(2) bond length is 2.22 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.46 Å. The C(1)-N(1) bond length is 1.28 Å. The C(1)-H(1) bond length is 1.10 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.41 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(2) and one F(1) atom. The C(3)-F(1) bond length is 1.37 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the fifth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(6), and one H(7) atom. The C(8)-N(1) bond length is 1.46 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-H(7) bond length is 1.10 Å. In the sixth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(1), and one O(2) atom. The C(10)-C(11) bond length is 1.50 Å. The C(10)-O(1) bond length is 1.28 Å. The C(10)-O(2) bond length is 1.27 Å. In the seventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(16) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(16) bond length is 1.40 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(10) atom. The C(12)-H(10) bond length is 1.09 Å. In the ninth C site, C(16) is bonded in a distorted single-bond geometry to one C(11) and one H(14) atom. The C(16)-H(14) bond length is 1.09 Å. N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(8) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Ag(1) and one C(10) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one C(10) atom. F(1) is bonded in a single-bond geometry to one C(3) atom. Linkers: 1 Fc1ccccc1/C=N/CCCC/N=C/c1ccccc1F ,2 Fc1[c]cccc1/C=N/CCCC/N=C/c1ccccc1F. Metal clusters: 2 [Ag]. The MOF has largest included sphere 1.99 A, density 1.81 g/cm3, surface area 4010.71 m2/g, accessible volume 0.11 cm3/g