Ag2Cd3C50H40(NS4)2(CH)10 crystallizes in the triclinic P-1 space group. The structure consists of forty 02329_fluka molecules inside a Ag2Cd3C50H40(NS4)2 framework. In the Ag2Cd3C50H40(NS4)2 framework, there are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one S(13), one S(5), one S(8), and one S(9) atom to form AgS4 tetrahedra that share  a cornercorner with one Ag(3)S4 tetrahedra,  a cornercorner with one Ag(4)S4 tetrahedra,  a cornercorner with one Cd(5)S4 tetrahedra,  a cornercorner with one Cd(6)S4 tetrahedra,  a cornercorner with one Cd(2)S3N trigonal pyramid, and  a cornercorner with one Cd(4)S3N trigonal pyramid. The Ag(1)-S(13) bond length is 2.61 Å. The Ag(1)-S(5) bond length is 2.58 Å. The Ag(1)-S(8) bond length is 2.52 Å. The Ag(1)-S(9) bond length is 2.55 Å. In the second Ag site, Ag(2) is bonded to one S(10), one S(14), one S(6), and one S(7) atom to form AgS4 tetrahedra that share  a cornercorner with one Ag(3)S4 tetrahedra,  a cornercorner with one Ag(4)S4 tetrahedra,  a cornercorner with one Cd(5)S4 tetrahedra,  a cornercorner with one Cd(6)S4 tetrahedra,  a cornercorner with one Cd(1)S3N trigonal pyramid, and  a cornercorner with one Cd(3)S3N trigonal pyramid. The Ag(2)-S(10) bond length is 2.55 Å. The Ag(2)-S(14) bond length is 2.61 Å. The Ag(2)-S(6) bond length is 2.59 Å. The Ag(2)-S(7) bond length is 2.52 Å. In the third Ag site, Ag(3) is bonded to one S(11), one S(15), one S(5), and one S(7) atom to form AgS4 tetrahedra that share  a cornercorner with one Ag(1)S4 tetrahedra,  a cornercorner with one Ag(2)S4 tetrahedra,  a cornercorner with one Cd(5)S4 tetrahedra,  a cornercorner with one Cd(6)S4 tetrahedra,  a cornercorner with one Cd(1)S3N trigonal pyramid, and  a cornercorner with one Cd(4)S3N trigonal pyramid. The Ag(3)-S(11) bond length is 2.55 Å. The Ag(3)-S(15) bond length is 2.61 Å. The Ag(3)-S(5) bond length is 2.52 Å. The Ag(3)-S(7) bond length is 2.58 Å. In the fourth Ag site, Ag(4) is bonded to one S(12), one S(16), one S(6), and one S(8) atom to form AgS4 tetrahedra that share  a cornercorner with one Ag(1)S4 tetrahedra,  a cornercorner with one Ag(2)S4 tetrahedra,  a cornercorner with one Cd(5)S4 tetrahedra,  a cornercorner with one Cd(6)S4 tetrahedra,  a cornercorner with one Cd(2)S3N trigonal pyramid, and  a cornercorner with one Cd(3)S3N trigonal pyramid. The Ag(4)-S(12) bond length is 2.55 Å. The Ag(4)-S(16) bond length is 2.61 Å. The Ag(4)-S(6) bond length is 2.52 Å. The Ag(4)-S(8) bond length is 2.58 Å. There are six inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one N(1), one S(1), one S(10), and one S(15) atom to form CdS3N trigonal pyramids that share  a cornercorner with one Ag(2)S4 tetrahedra,  a cornercorner with one Ag(3)S4 tetrahedra, and  a cornercorner with one Cd(5)S4 tetrahedra. The Cd(1)-N(1) bond length is 2.41 Å. The Cd(1)-S(1) bond length is 2.55 Å. The Cd(1)-S(10) bond length is 2.52 Å. The Cd(1)-S(15) bond length is 2.49 Å. In the second Cd site, Cd(2) is bonded to one N(2), one S(16), one S(2), and one S(9) atom to form CdS3N trigonal pyramids that share  a cornercorner with one Ag(1)S4 tetrahedra,  a cornercorner with one Ag(4)S4 tetrahedra, and  a cornercorner with one Cd(5)S4 tetrahedra. The Cd(2)-N(2) bond length is 2.41 Å. The Cd(2)-S(16) bond length is 2.49 Å. The Cd(2)-S(2) bond length is 2.55 Å. The Cd(2)-S(9) bond length is 2.52 Å. In the third Cd site, Cd(3) is bonded to one N(3), one S(12), one S(14), and one S(3) atom to form CdS3N trigonal pyramids that share  a cornercorner with one Ag(2)S4 tetrahedra,  a cornercorner with one Ag(4)S4 tetrahedra, and  a cornercorner with one Cd(6)S4 tetrahedra. The Cd(3)-N(3) bond length is 2.41 Å. The Cd(3)-S(12) bond length is 2.52 Å. The Cd(3)-S(14) bond length is 2.49 Å. The Cd(3)-S(3) bond length is 2.55 Å. In the fourth Cd site, Cd(4) is bonded to one N(4), one S(11), one S(13), and one S(4) atom to form CdS3N trigonal pyramids that share  a cornercorner with one Ag(1)S4 tetrahedra,  a cornercorner with one Ag(3)S4 tetrahedra, and  a cornercorner with one Cd(6)S4 tetrahedra. The Cd(4)-N(4) bond length is 2.41 Å. The Cd(4)-S(11) bond length is 2.52 Å. The Cd(4)-S(13) bond length is 2.49 Å. The Cd(4)-S(4) bond length is 2.55 Å. In the fifth Cd site, Cd(5) is bonded to one S(1), one S(2), one S(5), and one S(6) atom to form CdS4 tetrahedra that share  a cornercorner with one Ag(1)S4 tetrahedra,  a cornercorner with one Ag(2)S4 tetrahedra,  a cornercorner with one Ag(3)S4 tetrahedra,  a cornercorner with one Ag(4)S4 tetrahedra,  a cornercorner with one Cd(1)S3N trigonal pyramid, and  a cornercorner with one Cd(2)S3N trigonal pyramid. The Cd(5)-S(1) bond length is 2.57 Å. The Cd(5)-S(2) bond length is 2.57 Å. The Cd(5)-S(5) bond length is 2.57 Å. The Cd(5)-S(6) bond length is 2.57 Å. In the sixth Cd site, Cd(6) is bonded to one S(3), one S(4), one S(7), and one S(8) atom to form CdS4 tetrahedra that share  a cornercorner with one Ag(1)S4 tetrahedra,  a cornercorner with one Ag(2)S4 tetrahedra,  a cornercorner with one Ag(3)S4 tetrahedra,  a cornercorner with one Ag(4)S4 tetrahedra,  a cornercorner with one Cd(3)S3N trigonal pyramid, and  a cornercorner with one Cd(4)S3N trigonal pyramid. The Cd(6)-S(3) bond length is 2.57 Å. The Cd(6)-S(4) bond length is 2.57 Å. The Cd(6)-S(7) bond length is 2.57 Å. The Cd(6)-S(8) bond length is 2.57 Å. There are seventy-one inequivalent C sites. In the first C site, C(1,3) is bonded in a distorted bent 120 degrees geometry to one C(5,7); one N(1); and one H(1,3) atom. The C(1,3)-C(5,7) bond length is 1.39 Å. The C(1,3)-N(1) bond length is 1.35 Å. The C(1,3)-H(1,3) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(6); one N(2); and one H(2,4) atom. The C(2)-C(6) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(2,4) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(8); one N(4); and one H(2,4) atom. The C(4)-C(8) bond length is 1.39 Å. The C(4)-N(4) bond length is 1.35 Å. The C(4)-H(2,4) bond length is 1.09 Å. In the fourth C site, C(5,7) is bonded in a distorted trigonal planar geometry to one C(1,3); one C(9,10,11); and one H(5,6,7) atom. The C(5,7)-C(9,10,11) bond length is 1.41 Å. The C(5,7)-H(5,6,7) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(2); one C(9,10,11); and one H(5,6,7) atom. The C(6)-C(9,10,11) bond length is 1.41 Å. The C(6)-H(5,6,7) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(12), one C(4), and one H(8) atom. The C(8)-C(12) bond length is 1.41 Å. The C(8)-H(8) bond length is 1.09 Å. In the seventh C site, C(9,10,11) is bonded in a trigonal planar geometry to one C(13,14,15); one C(21,22,23); and one C(5,7) atom. The C(9,10,11)-C(13,14,15) bond length is 1.41 Å. The C(9,10,11)-C(21,22,23) bond length is 1.46 Å. In the eighth C site, C(12) is bonded in a trigonal planar geometry to one C(16), one C(24), and one C(8) atom. The C(12)-C(16) bond length is 1.41 Å. The C(12)-C(24) bond length is 1.46 Å. In the ninth C site, C(13,14,15) is bonded in a distorted single-bond geometry to one C(9,10,11) and one H(9,10,11) atom. The C(13,14,15)-H(9,10,11) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(12) and one H(12) atom. The C(16)-H(12) bond length is 1.09 Å. In the eleventh C site, C(17,19) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13,15) atom. The C(17,19)-N(1) bond length is 1.34 Å. The C(17,19)-H(13,15) bond length is 1.09 Å. In the twelfth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(14,16) atom. The C(18)-N(2) bond length is 1.34 Å. The C(18)-H(14,16) bond length is 1.09 Å. In the thirteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(14,16) atom. The C(20)-N(4) bond length is 1.34 Å. The C(20)-H(14,16) bond length is 1.09 Å. In the fourteenth C site, C(21,22,23) is bonded in a distorted single-bond geometry to one C(21,22,23); one C(9,10,11); and one H(17,18,19) atom. The C(21,22,23)-C(21,22,23) bond length is 1.35 Å. The C(21,22,23)-H(17,18,19) bond length is 1.09 Å. In the fifteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(12), one C(24), and one H(20) atom. The C(24)-C(24) bond length is 1.35 Å. The C(24)-H(20) bond length is 1.09 Å. In the sixteenth C site, C(25,26,27) is bonded in a trigonal planar geometry to one C(29,32); one C(45,48); and one S(1) atom. The C(25,26,27)-C(29,32) bond length is 1.40 Å. The C(25,26,27)-C(45,48) bond length is 1.40 Å. The C(25,26,27)-S(1) bond length is 1.79 Å. In the seventeenth C site, C(28) is bonded in a trigonal planar geometry to one C(29,32); one C(45,48); and one S(4) atom. The C(28)-C(29,32) bond length is 1.40 Å. The C(28)-C(45,48) bond length is 1.40 Å. The C(28)-S(4) bond length is 1.79 Å. In the eighteenth C site, C(29,32) is bonded in a distorted trigonal planar geometry to one C(25,26,27); one C(33,34,35); and one H(21,22,23) atom. The C(29,32)-C(33,34,35) bond length is 1.39 Å. The C(29,32)-H(21,22,23) bond length is 1.09 Å. In the nineteenth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(25,26,27); one C(33,34,35); and one H(21,22,23) atom. The C(30)-C(25,26,27) bond length is 1.40 Å. The C(30)-C(33,34,35) bond length is 1.39 Å. The C(30)-H(21,22,23) bond length is 1.09 Å. In the twentieth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(25,26,27); one C(33,34,35); and one H(21,22,23) atom. The C(31)-C(25,26,27) bond length is 1.40 Å. The C(31)-C(33,34,35) bond length is 1.39 Å. The C(31)-H(21,22,23) bond length is 1.09 Å. In the twenty-first C site, C(33,34,35) is bonded in a distorted trigonal planar geometry to one C(29,32); one C(37,40); and one H(25,28) atom. The C(33,34,35)-C(37,40) bond length is 1.40 Å. The C(33,34,35)-H(25,28) bond length is 1.09 Å. In the twenty-second C site, C(36) is bonded in a distorted trigonal planar geometry to one C(29,32); one C(37,40); and one H(25,28) atom. The C(36)-C(29,32) bond length is 1.39 Å. The C(36)-C(37,40) bond length is 1.40 Å. The C(36)-H(25,28) bond length is 1.09 Å. In the twenty-third C site, C(37,40) is bonded in a distorted trigonal planar geometry to one C(33,34,35); one C(41,42,43); and one H(29,30,31) atom. The C(37,40)-C(41,42,43) bond length is 1.40 Å. The C(37,40)-H(29,30,31) bond length is 1.09 Å. In the twenty-fourth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(33,34,35); one C(41,42,43); and one H(29,30,31) atom. The C(38)-C(33,34,35) bond length is 1.40 Å. The C(38)-C(41,42,43) bond length is 1.40 Å. The C(38)-H(29,30,31) bond length is 1.09 Å. In the twenty-fifth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(33,34,35); one C(41,42,43); and one H(29,30,31) atom. The C(39)-C(33,34,35) bond length is 1.40 Å. The C(39)-C(41,42,43) bond length is 1.40 Å. The C(39)-H(29,30,31) bond length is 1.09 Å. In the twenty-sixth C site, C(41,42,43) is bonded in a distorted trigonal planar geometry to one C(37,40); one C(45,48); and one H(33,36) atom. The C(41,42,43)-C(45,48) bond length is 1.40 Å. The C(41,42,43)-H(33,36) bond length is 1.09 Å. In the twenty-seventh C site, C(44) is bonded in a distorted trigonal planar geometry to one C(37,40); one C(45,48); and one H(33,36) atom. The C(44)-C(37,40) bond length is 1.40 Å. The C(44)-C(45,48) bond length is 1.40 Å. The C(44)-H(33,36) bond length is 1.09 Å. In the twenty-eighth C site, C(45,48) is bonded in a distorted single-bond geometry to one C(25,26,27); one C(41,42,43); and one H(37,38,39,40) atom. The C(45,48)-H(37,38,39,40) bond length is 1.09 Å. In the twenty-ninth C site, C(46) is bonded in a distorted single-bond geometry to one C(25,26,27); one C(41,42,43); and one H(37,38,39,40) atom. The C(46)-C(25,26,27) bond length is 1.40 Å. The C(46)-C(41,42,43) bond length is 1.40 Å. The C(46)-H(37,38,39,40) bond length is 1.09 Å. In the thirtieth C site, C(47) is bonded in a distorted single-bond geometry to one C(25,26,27); one C(41,42,43); and one H(37,38,39,40) atom. The C(47)-C(25,26,27) bond length is 1.40 Å. The C(47)-C(41,42,43) bond length is 1.40 Å. The C(47)-H(37,38,39,40) bond length is 1.09 Å. In the thirty-first C site, C(49) is bonded in a trigonal planar geometry to one C(53), one C(69), and one S(5) atom. The C(49)-C(53) bond length is 1.40 Å. The C(49)-C(69) bond length is 1.40 Å. The C(49)-S(5) bond length is 1.78 Å. In the thirty-second C site, C(50) is bonded in a trigonal planar geometry to one C(54), one C(70), and one S(6) atom. The C(50)-C(54) bond length is 1.40 Å. The C(50)-C(70) bond length is 1.40 Å. The C(50)-S(6) bond length is 1.78 Å. In the thirty-third C site, C(51) is bonded in a trigonal planar geometry to one C(55), one C(71), and one S(7) atom. The C(51)-C(55) bond length is 1.40 Å. The C(51)-C(71) bond length is 1.40 Å. The C(51)-S(7) bond length is 1.78 Å. In the thirty-fourth C site, C(52) is bonded in a trigonal planar geometry to one C(56), one C(72), and one S(8) atom. The C(52)-C(56) bond length is 1.40 Å. The C(52)-C(72) bond length is 1.40 Å. The C(52)-S(8) bond length is 1.78 Å. In the thirty-fifth C site, C(53) is bonded in a distorted single-bond geometry to one C(49) and one H(41,42,43,44) atom. The C(53)-H(41,42,43,44) bond length is 1.09 Å. In the thirty-sixth C site, C(54) is bonded in a distorted single-bond geometry to one C(50) and one H(41,42,43,44) atom. The C(54)-H(41,42,43,44) bond length is 1.09 Å. In the thirty-seventh C site, C(55) is bonded in a distorted single-bond geometry to one C(51) and one H(41,42,43,44) atom. The C(55)-H(41,42,43,44) bond length is 1.09 Å. In the thirty-eighth C site, C(56) is bonded in a distorted single-bond geometry to one C(52) and one H(41,42,43,44) atom. The C(56)-H(41,42,43,44) bond length is 1.09 Å. In the thirty-ninth C site, C(65) is bonded in a distorted single-bond geometry to one C(69) and one H(53) atom. The C(65)-C(69) bond length is 1.39 Å. The C(65)-H(53) bond length is 1.09 Å. In the fortieth C site, C(66,67,68) is bonded in a distorted single-bond geometry to one C(70) and one H(54,55,56) atom. The C(66,67,68)-C(70) bond length is 1.39 Å. The C(66,67,68)-H(54,55,56) bond length is 1.09 Å. In the forty-first C site, C(69) is bonded in a distorted trigonal planar geometry to one C(49), one C(65), and one H(57) atom. The C(69)-H(57) bond length is 1.09 Å. In the forty-second C site, C(70) is bonded in a distorted trigonal planar geometry to one C(50); one C(66,67,68); and one H(58,59,60) atom. The C(70)-H(58,59,60) bond length is 1.09 Å. In the forty-third C site, C(71) is bonded in a distorted trigonal planar geometry to one C(51); one C(66,67,68); and one H(58,59,60) atom. The C(71)-C(66,67,68) bond length is 1.39 Å. The C(71)-H(58,59,60) bond length is 1.09 Å. In the forty-fourth C site, C(72) is bonded in a distorted trigonal planar geometry to one C(52); one C(66,67,68); and one H(58,59,60) atom. The C(72)-C(66,67,68) bond length is 1.39 Å. The C(72)-H(58,59,60) bond length is 1.09 Å. In the forty-fifth C site, C(73) is bonded in a trigonal planar geometry to one C(77,78); one C(93,94); and one S(9) atom. The C(73)-C(77,78) bond length is 1.41 Å. The C(73)-C(93,94) bond length is 1.40 Å. The C(73)-S(9) bond length is 1.77 Å. In the forty-sixth C site, C(74) is bonded in a trigonal planar geometry to one C(77,78); one C(93,94); and one S(10) atom. The C(74)-C(77,78) bond length is 1.41 Å. The C(74)-C(93,94) bond length is 1.40 Å. The C(74)-S(10) bond length is 1.77 Å. In the forty-seventh C site, C(75) is bonded in a trigonal planar geometry to one C(79), one C(95), and one S(11) atom. The C(75)-C(79) bond length is 1.41 Å. The C(75)-C(95) bond length is 1.40 Å. The C(75)-S(11) bond length is 1.77 Å. In the forty-eighth C site, C(76) is bonded in a trigonal planar geometry to one C(80), one C(96), and one S(12) atom. The C(76)-C(80) bond length is 1.41 Å. The C(76)-C(96) bond length is 1.40 Å. The C(76)-S(12) bond length is 1.77 Å. In the forty-ninth C site, C(77,78) is bonded in a distorted single-bond geometry to one C(73); one C(81); and one H(61,62,63) atom. The C(77,78)-C(81) bond length is 1.40 Å. The C(77,78)-H(61,62,63) bond length is 1.09 Å. In the fiftieth C site, C(79) is bonded in a distorted single-bond geometry to one C(75); one C(82,83,84); and one H(61,62,63) atom. The C(79)-C(82,83,84) bond length is 1.40 Å. The C(79)-H(61,62,63) bond length is 1.09 Å. In the fifty-first C site, C(80) is bonded in a distorted single-bond geometry to one C(76); one C(82,83,84); and one H(64) atom. The C(80)-C(82,83,84) bond length is 1.40 Å. The C(80)-H(64) bond length is 1.09 Å. In the fifty-second C site, C(81) is bonded in a distorted trigonal planar geometry to one C(77,78); one C(85,86); and one H(65,66) atom. The C(81)-C(85,86) bond length is 1.40 Å. The C(81)-H(65,66) bond length is 1.09 Å. In the fifty-third C site, C(82,83,84) is bonded in a distorted trigonal planar geometry to one C(77,78); one C(85,86); and one H(65,66) atom. The C(82,83,84)-C(77,78) bond length is 1.40 Å. The C(82,83,84)-C(85,86) bond length is 1.40 Å. The C(82,83,84)-H(65,66) bond length is 1.09 Å. In the fifty-fourth C site, C(85,86) is bonded in a distorted trigonal planar geometry to one C(81), one C(89), and one H(69) atom. The C(85,86)-C(89) bond length is 1.40 Å. The C(85,86)-H(69) bond length is 1.09 Å. In the fifty-fifth C site, C(87) is bonded in a distorted trigonal planar geometry to one C(82,83,84); one C(90,91,92); and one H(70,71,72) atom. The C(87)-C(82,83,84) bond length is 1.40 Å. The C(87)-C(90,91,92) bond length is 1.40 Å. The C(87)-H(70,71,72) bond length is 1.09 Å. In the fifty-sixth C site, C(88) is bonded in a distorted trigonal planar geometry to one C(82,83,84); one C(90,91,92); and one H(70,71,72) atom. The C(88)-C(82,83,84) bond length is 1.40 Å. The C(88)-C(90,91,92) bond length is 1.40 Å. The C(88)-H(70,71,72) bond length is 1.09 Å. In the fifty-seventh C site, C(89) is bonded in a distorted trigonal planar geometry to one C(85,86); one C(93,94); and one H(73,74) atom. The C(89)-C(93,94) bond length is 1.39 Å. The C(89)-H(73,74) bond length is 1.09 Å. In the fifty-eighth C site, C(90,91,92) is bonded in a distorted trigonal planar geometry to one C(85,86); one C(93,94); and one H(73,74) atom. The C(90,91,92)-C(85,86) bond length is 1.40 Å. The C(90,91,92)-C(93,94) bond length is 1.39 Å. The C(90,91,92)-H(73,74) bond length is 1.09 Å. In the fifty-ninth C site, C(93,94) is bonded in a distorted trigonal planar geometry to one C(73), one C(89), and one H(77) atom. The C(93,94)-H(77) bond length is 1.09 Å. In the sixtieth C site, C(95) is bonded in a distorted trigonal planar geometry to one C(75); one C(90,91,92); and one H(78,79,80) atom. The C(95)-C(90,91,92) bond length is 1.39 Å. The C(95)-H(78,79,80) bond length is 1.09 Å. In the sixty-first C site, C(96) is bonded in a distorted trigonal planar geometry to one C(76); one C(90,91,92); and one H(78,79,80) atom. The C(96)-C(90,91,92) bond length is 1.39 Å. The C(96)-H(78,79,80) bond length is 1.09 Å. In the sixty-second C site, C(97) is bonded in a trigonal planar geometry to one C(101), one C(117), and one S(13) atom. The C(97)-C(101) bond length is 1.41 Å. The C(97)-C(117) bond length is 1.40 Å. The C(97)-S(13) bond length is 1.77 Å. In the sixty-third C site, C(98) is bonded in a trigonal planar geometry to one C(102,104); one C(118,120); and one S(14) atom. The C(98)-C(102,104) bond length is 1.41 Å. The C(98)-C(118,120) bond length is 1.40 Å. The C(98)-S(14) bond length is 1.77 Å. In the sixty-fourth C site, C(99) is bonded in a trigonal planar geometry to one C(103), one C(119), and one S(15) atom. The C(99)-C(103) bond length is 1.41 Å. The C(99)-C(119) bond length is 1.40 Å. The C(99)-S(15) bond length is 1.77 Å. In the sixty-fifth C site, C(100) is bonded in a trigonal planar geometry to one C(102,104); one C(118,120); and one S(16) atom. The C(100)-C(102,104) bond length is 1.41 Å. The C(100)-C(118,120) bond length is 1.40 Å. The C(100)-S(16) bond length is 1.77 Å. In the sixty-sixth C site, C(101) is bonded in a distorted single-bond geometry to one C(97) and one H(81,82,83) atom. The C(101)-H(81,82,83) bond length is 1.09 Å. In the sixty-seventh C site, C(102,104) is bonded in a distorted single-bond geometry to one C(98) and one H(81,82,83) atom. The C(102,104)-H(81,82,83) bond length is 1.09 Å. In the sixty-eighth C site, C(103) is bonded in a distorted single-bond geometry to one C(99) and one H(81,82,83) atom. The C(103)-H(81,82,83) bond length is 1.09 Å. In the sixty-ninth C site, C(117) is bonded in a distorted single-bond geometry to one C(97) and one H(97,98,99) atom. The C(117)-H(97,98,99) bond length is 1.09 Å. In the seventieth C site, C(118,120) is bonded in a distorted single-bond geometry to one C(98) and one H(97,98,99) atom. The C(118,120)-H(97,98,99) bond length is 1.09 Å. In the seventy-first C site, C(119) is bonded in a distorted single-bond geometry to one C(99) and one H(97,98,99) atom. The C(119)-H(97,98,99) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1); one C(1,3); and one C(17,19) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(18), and one C(2) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(3); one C(1,3); and one C(17,19) atom. The N(3)-C(1,3) bond length is 1.35 Å. The N(3)-C(17,19) bond length is 1.34 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(4), one C(20), and one C(4) atom. There are forty inequivalent H sites. In the first H site, H(1,3) is bonded in a single-bond geometry to one C(1,3) atom. In the second H site, H(2,4) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5,6,7) is bonded in a single-bond geometry to one C(5,7) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(9,10,11) is bonded in a single-bond geometry to one C(13,14,15) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(13,15) is bonded in a single-bond geometry to one C(17,19) atom. In the eighth H site, H(14,16) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(17,18,19) is bonded in a single-bond geometry to one C(21,22,23) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(21,22,23) is bonded in a single-bond geometry to one C(29,32) atom. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(29,32) atom. The H(24)-C(29,32) bond length is 1.09 Å. In the thirteenth H site, H(25,28) is bonded in a single-bond geometry to one C(33,34,35) atom. In the fourteenth H site, H(26,27) is bonded in a single-bond geometry to one C(33,34,35) atom. The H(26,27)-C(33,34,35) bond length is 1.09 Å. In the fifteenth H site, H(29,30,31) is bonded in a single-bond geometry to one C(37,40) atom. In the sixteenth H site, H(32) is bonded in a single-bond geometry to one C(37,40) atom. The H(32)-C(37,40) bond length is 1.09 Å. In the seventeenth H site, H(33,36) is bonded in a single-bond geometry to one C(41,42,43) atom. In the eighteenth H site, H(34) is bonded in a single-bond geometry to one C(41,42,43) atom. The H(34)-C(41,42,43) bond length is 1.09 Å. In the nineteenth H site, H(35) is bonded in a single-bond geometry to one C(41,42,43) atom. The H(35)-C(41,42,43) bond length is 1.09 Å. In the twentieth H site, H(37,38,39,40) is bonded in a single-bond geometry to one C(45,48) atom. In the twenty-first H site, H(41,42,43,44) is bonded in a single-bond geometry to one C(53) atom. In the twenty-second H site, H(53) is bonded in a single-bond geometry to one C(65) atom. In the twenty-third H site, H(54,55,56) is bonded in a single-bond geometry to one C(66,67,68) atom. In the twenty-fourth H site, H(57) is bonded in a single-bond geometry to one C(69) atom. In the twenty-fifth H site, H(58,59,60) is bonded in a single-bond geometry to one C(70) atom. In the twenty-sixth H site, H(61,62,63) is bonded in a single-bond geometry to one C(77,78) atom. In the twenty-seventh H site, H(64) is bonded in a single-bond geometry to one C(80) atom. In the twenty-eighth H site, H(65,66) is bonded in a single-bond geometry to one C(81) atom. In the twenty-ninth H site, H(67) is bonded in a single-bond geometry to one C(82,83,84) atom. The H(67)-C(82,83,84) bond length is 1.09 Å. In the thirtieth H site, H(68) is bonded in a single-bond geometry to one C(82,83,84) atom. The H(68)-C(82,83,84) bond length is 1.09 Å. In the thirty-first H site, H(69) is bonded in a single-bond geometry to one C(85,86) atom. In the thirty-second H site, H(70,71,72) is bonded in a single-bond geometry to one C(85,86) atom. The H(70,71,72)-C(85,86) bond length is 1.09 Å. In the thirty-third H site, H(73,74) is bonded in a single-bond geometry to one C(89) atom. In the thirty-fourth H site, H(75,76) is bonded in a single-bond geometry to one C(90,91,92) atom. The H(75,76)-C(90,91,92) bond length is 1.09 Å. In the thirty-fifth H site, H(77) is bonded in a single-bond geometry to one C(93,94) atom. In the thirty-sixth H site, H(78,79,80) is bonded in a single-bond geometry to one C(93,94) atom. The H(78,79,80)-C(93,94) bond length is 1.09 Å. In the thirty-seventh H site, H(81,82,83) is bonded in a single-bond geometry to one C(101) atom. In the thirty-eighth H site, H(84) is bonded in a single-bond geometry to one C(102,104) atom. The H(84)-C(102,104) bond length is 1.09 Å. In the thirty-ninth H site, H(97,98,99) is bonded in a single-bond geometry to one C(117) atom. In the fortieth H site, H(100) is bonded in a single-bond geometry to one C(118,120) atom. The H(100)-C(118,120) bond length is 1.09 Å. There are sixteen inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Cd(1); one Cd(5); and one C(25,26,27) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Cd(2); one Cd(5); and one C(25,26,27) atom. The S(2)-C(25,26,27) bond length is 1.79 Å. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Cd(3); one Cd(6); and one C(25,26,27) atom. The S(3)-C(25,26,27) bond length is 1.79 Å. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Cd(4), one Cd(6), and one C(28) atom. In the fifth S site, S(5) is bonded to one Ag(1), one Ag(3), one Cd(5), and one C(49) atom to form corner-sharing SCdAg2C tetrahedra. In the sixth S site, S(6) is bonded to one Ag(2), one Ag(4), one Cd(5), and one C(50) atom to form corner-sharing SCdAg2C tetrahedra. In the seventh S site, S(7) is bonded to one Ag(2), one Ag(3), one Cd(6), and one C(51) atom to form corner-sharing SCdAg2C tetrahedra. In the eighth S site, S(8) is bonded to one Ag(1), one Ag(4), one Cd(6), and one C(52) atom to form corner-sharing SCdAg2C tetrahedra. In the ninth S site, S(9) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Cd(2), and one C(73) atom. In the tenth S site, S(10) is bonded in a trigonal non-coplanar geometry to one Ag(2), one Cd(1), and one C(74) atom. In the eleventh S site, S(11) is bonded in a trigonal non-coplanar geometry to one Ag(3), one Cd(4), and one C(75) atom. In the twelfth S site, S(12) is bonded in a trigonal non-coplanar geometry to one Ag(4), one Cd(3), and one C(76) atom. In the thirteenth S site, S(13) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Cd(4), and one C(97) atom. In the fourteenth S site, S(14) is bonded in a trigonal non-coplanar geometry to one Ag(2), one Cd(3), and one C(98) atom. In the fifteenth S site, S(15) is bonded in a trigonal non-coplanar geometry to one Ag(3), one Cd(1), and one C(99) atom. In the sixteenth S site, S(16) is bonded in a trigonal non-coplanar geometry to one Ag(4), one Cd(2), and one C(100) atom. Linkers: 4 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 12 [Cd] ,8 [Ag]. The MOF has largest included sphere 7.92 A, density 1.45 g/cm3, surface area 4178.38 m2/g, accessible volume 0.32 cm3/g