(CoC21H11(OF)6)2H4(C3F2)3 is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two CoC21H11(OF)6 clusters and two H4(C3F2)3 clusters. In each CoC21H11(OF)6 cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 4-coordinate geometry to one O(1), one O(4), one O(5), and one O(8) atom. The Co(1)-O(1) bond length is 1.90 Å. The Co(1)-O(4) bond length is 1.90 Å. The Co(1)-O(5) bond length is 1.91 Å. The Co(1)-O(8) bond length is 1.93 Å. In the second Co site, Co(2) is bonded in a distorted square pyramidal geometry to one O(10), one O(2), one O(3), one O(6), and one O(7) atom. The Co(2)-O(10) bond length is 2.16 Å. The Co(2)-O(2) bond length is 2.01 Å. The Co(2)-O(3) bond length is 2.00 Å. The Co(2)-O(6) bond length is 2.00 Å. The Co(2)-O(7) bond length is 2.06 Å. There are forty-two inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(3) bond length is 1.27 Å. In the second C site, C(2) is bonded in a bent 120 degrees geometry to one C(4), one O(2), and one O(4) atom. The C(2)-C(4) bond length is 1.48 Å. The C(2)-O(2) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.29 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(5) atom. The C(3)-C(13) bond length is 1.40 Å. The C(3)-C(5) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(6) atom. The C(4)-C(14) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(7)-C(9) bond length is 1.40 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(10) and one H(6,12) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-H(6,12) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(7) atom. The C(9)-C(11) bond length is 1.41 Å. The C(9)-C(15) bond length is 1.54 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(8) atom. The C(10)-C(12) bond length is 1.41 Å. The C(10)-C(16) bond length is 1.54 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(13), one C(9), and one H(7) atom. The C(11)-C(13) bond length is 1.39 Å. The C(11)-H(7) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one H(8) atom. The C(12)-C(14) bond length is 1.39 Å. The C(12)-H(8) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(11), one C(3), and one H(9) atom. The C(13)-H(9) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(12), one C(4), and one H(10) atom. The C(14)-H(10) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a tetrahedral geometry to one C(17), one C(19), one C(21), and one C(9) atom. The C(15)-C(17) bond length is 1.54 Å. The C(15)-C(19) bond length is 1.56 Å. The C(15)-C(21) bond length is 1.57 Å. In the sixteenth C site, C(16) is bonded in a tetrahedral geometry to one C(10), one C(18), one C(20), and one C(22) atom. The C(16)-C(18) bond length is 1.54 Å. The C(16)-C(20) bond length is 1.56 Å. The C(16)-C(22) bond length is 1.56 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(15), one C(23), and one C(46) atom. The C(17)-C(23) bond length is 1.40 Å. The C(17)-C(46) bond length is 1.41 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(16), one C(24), and one C(47) atom. The C(18)-C(24) bond length is 1.40 Å. The C(18)-C(47) bond length is 1.41 Å. In the nineteenth C site, C(19) is bonded in a trigonal non-coplanar geometry to one C(15), one F(11), one F(7), and one F(9) atom. The C(19)-F(11) bond length is 1.36 Å. The C(19)-F(7) bond length is 1.37 Å. The C(19)-F(9) bond length is 1.36 Å. In the twentieth C site, C(20) is bonded in a trigonal non-coplanar geometry to one C(16), one F(10), one F(12), and one F(8) atom. The C(20)-F(10) bond length is 1.36 Å. The C(20)-F(12) bond length is 1.36 Å. The C(20)-F(8) bond length is 1.37 Å. In the twenty-first C site, C(21) is bonded in a trigonal non-coplanar geometry to one C(15), one F(1), one F(3), and one F(5) atom. The C(21)-F(1) bond length is 1.36 Å. The C(21)-F(3) bond length is 1.36 Å. The C(21)-F(5) bond length is 1.37 Å. In the twenty-second C site, C(22) is bonded in a trigonal non-coplanar geometry to one C(16), one F(2), one F(4), and one F(6) atom. The C(22)-F(2) bond length is 1.36 Å. The C(22)-F(4) bond length is 1.36 Å. The C(22)-F(6) bond length is 1.37 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(17) and one H(11) atom. The C(23)-H(11) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(18) and one H(6,12) atom. The C(24)-H(6,12) bond length is 1.09 Å. In the twenty-fifth C site, C(25) is bonded in a bent 120 degrees geometry to one C(48), one O(5), and one O(7) atom. The C(25)-C(48) bond length is 1.48 Å. The C(25)-O(5) bond length is 1.28 Å. The C(25)-O(7) bond length is 1.28 Å. In the twenty-sixth C site, C(26) is bonded in a bent 120 degrees geometry to one C(49), one O(6), and one O(8) atom. The C(26)-C(49) bond length is 1.48 Å. The C(26)-O(6) bond length is 1.26 Å. The C(26)-O(8) bond length is 1.30 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(48) and one H(13) atom. The C(27)-C(48) bond length is 1.40 Å. The C(27)-H(13) bond length is 1.09 Å. In the twenty-eighth C site, C(28) is bonded in a distorted single-bond geometry to one C(49) and one H(14) atom. The C(28)-C(49) bond length is 1.40 Å. The C(28)-H(14) bond length is 1.09 Å. In the twenty-ninth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(11), and one O(9) atom. The C(29)-C(31) bond length is 1.49 Å. The C(29)-O(11) bond length is 1.34 Å. The C(29)-O(9) bond length is 1.24 Å. In the thirtieth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(10), and one O(12) atom. The C(30)-C(32) bond length is 1.48 Å. The C(30)-O(10) bond length is 1.25 Å. The C(30)-O(12) bond length is 1.32 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one C(29), one C(33), and one C(41) atom. The C(31)-C(33) bond length is 1.40 Å. The C(31)-C(41) bond length is 1.40 Å. In the thirty-second C site, C(32) is bonded in a trigonal planar geometry to one C(30), one C(34), and one C(42) atom. The C(32)-C(34) bond length is 1.40 Å. The C(32)-C(42) bond length is 1.40 Å. In the thirty-third C site, C(33) is bonded in a distorted single-bond geometry to one C(31) and one H(15) atom. The C(33)-H(15) bond length is 1.09 Å. In the thirty-fourth C site, C(34) is bonded in a distorted single-bond geometry to one C(32) and one H(16) atom. The C(34)-H(16) bond length is 1.09 Å. In the thirty-fifth C site, C(41) is bonded in a distorted single-bond geometry to one C(31) and one H(21) atom. The C(41)-H(21) bond length is 1.09 Å. In the thirty-sixth C site, C(42) is bonded in a distorted single-bond geometry to one C(32) and one H(22) atom. The C(42)-H(22) bond length is 1.08 Å. In the thirty-seventh C site, C(46) is bonded in a distorted single-bond geometry to one C(17) and one H(23) atom. The C(46)-H(23) bond length is 1.09 Å. In the thirty-eighth C site, C(47) is bonded in a distorted single-bond geometry to one C(18) and one H(24) atom. The C(47)-H(24) bond length is 1.09 Å. In the thirty-ninth C site, C(48) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(50) atom. The C(48)-C(50) bond length is 1.40 Å. In the fortieth C site, C(49) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(51) atom. The C(49)-C(51) bond length is 1.40 Å. In the forty-first C site, C(50) is bonded in a distorted single-bond geometry to one C(48) and one H(25) atom. The C(50)-H(25) bond length is 1.09 Å. In the forty-second C site, C(51) is bonded in a distorted single-bond geometry to one C(49) and one H(26) atom. The C(51)-H(26) bond length is 1.09 Å. There are twenty-one inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(11) and one O(8) atom. The H(1)-O(11) bond length is 1.01 Å. The H(1)-O(8) bond length is 1.60 Å. In the second H site, H(2) is bonded in a linear geometry to one O(12) and one O(7) atom. The H(2)-O(12) bond length is 1.02 Å. The H(2)-O(7) bond length is 1.51 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6,12) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(27) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(28) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(33) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(34) atom. In the sixteenth H site, H(21) is bonded in a single-bond geometry to one C(41) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one C(42) atom. In the eighteenth H site, H(23) is bonded in a single-bond geometry to one C(46) atom. In the nineteenth H site, H(24) is bonded in a single-bond geometry to one C(47) atom. In the twentieth H site, H(25) is bonded in a single-bond geometry to one C(50) atom. In the twenty-first H site, H(26) is bonded in a single-bond geometry to one C(51) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(2) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Co(1) and one C(25) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Co(2) and one C(26) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Co(2), one C(25), and one H(2) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Co(1), one C(26), and one H(1) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one C(29) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(30) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one C(29) and one H(1) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one C(30) and one H(2) atom. There are twelve inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(21) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(22) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(21) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(22) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(21) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one C(22) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one C(19) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one C(20) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one C(19) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one C(20) atom. In the eleventh F site, F(11) is bonded in a single-bond geometry to one C(19) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one C(20) atom. In each H4(C3F2)3 cluster, there are nine inequivalent C sites. In the first C site, C(37) is bonded in a trigonal planar geometry to one C(35), one C(39), and one C(43) atom. The C(37)-C(35) bond length is 1.40 Å. The C(37)-C(39) bond length is 1.40 Å. The C(37)-C(43) bond length is 1.54 Å. In the second C site, C(38) is bonded in a trigonal planar geometry to one C(36), one C(40), and one C(43) atom. The C(38)-C(36) bond length is 1.40 Å. The C(38)-C(40) bond length is 1.40 Å. The C(38)-C(43) bond length is 1.54 Å. In the third C site, C(39) is bonded in a distorted single-bond geometry to one C(37) and one H(19) atom. The C(39)-H(19) bond length is 1.09 Å. In the fourth C site, C(40) is bonded in a distorted single-bond geometry to one C(38) and one H(20) atom. The C(40)-H(20) bond length is 1.09 Å. In the fifth C site, C(43) is bonded in a tetrahedral geometry to one C(37), one C(38), one C(44), and one C(45) atom. The C(43)-C(44) bond length is 1.56 Å. The C(43)-C(45) bond length is 1.56 Å. In the sixth C site, C(44) is bonded in a trigonal non-coplanar geometry to one C(43); one F(13); one F(15,16); and one F(17) atom. The C(44)-F(13) bond length is 1.36 Å. The C(44)-F(15,16) bond length is 1.37 Å. The C(44)-F(17) bond length is 1.36 Å. In the seventh C site, C(45) is bonded in a trigonal non-coplanar geometry to one C(43); one F(14); one F(15,16); and one F(18) atom. The C(45)-F(14) bond length is 1.36 Å. The C(45)-F(15,16) bond length is 1.37 Å. The C(45)-F(18) bond length is 1.36 Å. In the eighth C site, C(35) is bonded in a distorted single-bond geometry to one C(37) and one H(17) atom. The C(35)-H(17) bond length is 1.09 Å. In the ninth C site, C(36) is bonded in a distorted single-bond geometry to one C(38) and one H(18) atom. The C(36)-H(18) bond length is 1.09 Å. There are four inequivalent H sites. In the first H site, H(17) is bonded in a single-bond geometry to one C(35) atom. In the second H site, H(18) is bonded in a single-bond geometry to one C(36) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(39) atom. In the fourth H site, H(20) is bonded in a single-bond geometry to one C(40) atom. There are five inequivalent F sites. In the first F site, F(13) is bonded in a single-bond geometry to one C(44) atom. In the second F site, F(14) is bonded in a single-bond geometry to one C(45) atom. In the third F site, F(15,16) is bonded in a single-bond geometry to one C(44) atom. In the fourth F site, F(17) is bonded in a single-bond geometry to one C(44) atom. In the fifth F site, F(18) is bonded in a single-bond geometry to one C(45) atom. Linkers: 4 [O]C(=O)c1ccc(C(c2ccc(C([O])=O)cc2)(C(F)(F)F)C(F)(F)F)cc1. Metal clusters: 4 [Co]. The MOF has largest included sphere 4.94 A, density 1.60 g/cm3, surface area 3900.47 m2/g, accessible volume 0.17 cm3/g