(CdC16H13(NO3)2)2CdC12H12(NO3)2(CH)4(CH2CO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four dimethyl ether molecules, two CdC12H12(NO3)2 clusters, and four CdC16H13(NO3)2 clusters. In each CdC12H12(NO3)2 cluster, Cd(3) is bonded in a distorted octahedral geometry to one N(5), one N(6), one O(11), one O(12), one O(7), and one O(8) atom. The Cd(3)-N(5) bond length is 2.34 Å. The Cd(3)-N(6) bond length is 2.34 Å. The Cd(3)-O(11) bond length is 2.29 Å. The Cd(3)-O(12) bond length is 2.29 Å. The Cd(3)-O(7) bond length is 2.40 Å. The Cd(3)-O(8) bond length is 2.39 Å. There are twelve inequivalent C sites. In the first C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(9) atom. The C(19)-O(11) bond length is 1.27 Å. The C(19)-O(9) bond length is 1.28 Å. In the second C site, C(20) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(12) atom. The C(20)-O(10) bond length is 1.28 Å. The C(20)-O(12) bond length is 1.27 Å. In the third C site, C(43) is bonded in a distorted trigonal planar geometry to one C(44), one C(45), and one N(5) atom. The C(43)-C(44) bond length is 1.49 Å. The C(43)-C(45) bond length is 1.40 Å. The C(43)-N(5) bond length is 1.35 Å. In the fourth C site, C(44) is bonded in a distorted trigonal planar geometry to one C(43), one C(46), and one N(6) atom. The C(44)-C(46) bond length is 1.40 Å. The C(44)-N(6) bond length is 1.35 Å. In the fifth C site, C(45) is bonded in a distorted single-bond geometry to one C(43), one C(47), and one H(39) atom. The C(45)-C(47) bond length is 1.39 Å. The C(45)-H(39) bond length is 1.09 Å. In the sixth C site, C(46) is bonded in a distorted single-bond geometry to one C(44), one C(48), and one H(40) atom. The C(46)-C(48) bond length is 1.39 Å. The C(46)-H(40) bond length is 1.09 Å. In the seventh C site, C(47) is bonded in a distorted trigonal planar geometry to one C(45); one C(49); and one H(41,42) atom. The C(47)-C(49) bond length is 1.39 Å. The C(47)-H(41,42) bond length is 1.09 Å. In the eighth C site, C(48) is bonded in a distorted trigonal planar geometry to one C(46); one C(50); and one H(41,42) atom. The C(48)-C(50) bond length is 1.39 Å. The C(48)-H(41,42) bond length is 1.09 Å. In the ninth C site, C(49) is bonded in a distorted trigonal planar geometry to one C(47), one C(51), and one H(43) atom. The C(49)-C(51) bond length is 1.39 Å. The C(49)-H(43) bond length is 1.09 Å. In the tenth C site, C(50) is bonded in a distorted trigonal planar geometry to one C(48), one C(52), and one H(44) atom. The C(50)-C(52) bond length is 1.39 Å. The C(50)-H(44) bond length is 1.09 Å. In the eleventh C site, C(51) is bonded in a distorted trigonal planar geometry to one C(49), one N(5), and one H(45) atom. The C(51)-N(5) bond length is 1.34 Å. The C(51)-H(45) bond length is 1.09 Å. In the twelfth C site, C(52) is bonded in a distorted trigonal planar geometry to one C(50), one N(6), and one H(46) atom. The C(52)-N(6) bond length is 1.34 Å. The C(52)-H(46) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one Cd(3), one C(43), and one C(51) atom. In the second N site, N(6) is bonded in a trigonal planar geometry to one Cd(3), one C(44), and one C(52) atom. There are eleven inequivalent H sites. In the first H site, H(5) is bonded in a distorted linear geometry to one O(7) and one O(9) atom. The H(5)-O(7) bond length is 1.02 Å. The H(5)-O(9) bond length is 1.57 Å. In the second H site, H(6) is bonded in a distorted linear geometry to one O(10) and one O(8) atom. The H(6)-O(10) bond length is 1.57 Å. The H(6)-O(8) bond length is 1.02 Å. In the third H site, H(7) is bonded in a single-bond geometry to one O(7) atom. The H(7)-O(7) bond length is 0.97 Å. In the fourth H site, H(8) is bonded in a single-bond geometry to one O(8) atom. The H(8)-O(8) bond length is 0.97 Å. In the fifth H site, H(39) is bonded in a single-bond geometry to one C(45) atom. In the sixth H site, H(40) is bonded in a single-bond geometry to one C(46) atom. In the seventh H site, H(41,42) is bonded in a single-bond geometry to one C(47) atom. In the eighth H site, H(43) is bonded in a single-bond geometry to one C(49) atom. In the ninth H site, H(44) is bonded in a single-bond geometry to one C(50) atom. In the tenth H site, H(45) is bonded in a single-bond geometry to one C(51) atom. In the eleventh H site, H(46) is bonded in a single-bond geometry to one C(52) atom. There are six inequivalent O sites. In the first O site, O(7) is bonded in a distorted water-like geometry to one Cd(3), one H(5), and one H(7) atom. In the second O site, O(8) is bonded in a distorted water-like geometry to one Cd(3), one H(6), and one H(8) atom. In the third O site, O(9) is bonded in a distorted bent 120 degrees geometry to one C(19) and one H(5) atom. In the fourth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one C(20) and one H(6) atom. In the fifth O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Cd(3) and one C(19) atom. In the sixth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Cd(3) and one C(20) atom. In each CdC16H13(NO3)2 cluster, Cd(1) is bonded in a 7-coordinate geometry to one N(1), one N(3), one O(1), one O(13), one O(15), one O(3), and one O(5) atom. The Cd(1)-N(1) bond length is 2.36 Å. The Cd(1)-N(3) bond length is 2.35 Å. The Cd(1)-O(1) bond length is 2.62 Å. The Cd(1)-O(13) bond length is 2.31 Å. The Cd(1)-O(15) bond length is 2.53 Å. The Cd(1)-O(3) bond length is 2.43 Å. The Cd(1)-O(5) bond length is 2.41 Å. There are sixteen inequivalent C sites. In the first C site, C(23) is bonded in a distorted trigonal planar geometry to one C(31), one C(33), and one N(1) atom. The C(23)-C(31) bond length is 1.40 Å. The C(23)-C(33) bond length is 1.49 Å. The C(23)-N(1) bond length is 1.35 Å. In the second C site, C(25) is bonded in a distorted trigonal planar geometry to one C(27), one N(1), and one H(23) atom. The C(25)-C(27) bond length is 1.39 Å. The C(25)-N(1) bond length is 1.34 Å. The C(25)-H(23) bond length is 1.09 Å. In the third C site, C(27) is bonded in a distorted single-bond geometry to one C(25) and one H(25) atom. The C(27)-H(25) bond length is 1.09 Å. In the fourth C site, C(31) is bonded in a distorted single-bond geometry to one C(23) and one H(29,30) atom. The C(31)-H(29,30) bond length is 1.09 Å. In the fifth C site, C(33) is bonded in a distorted trigonal planar geometry to one C(23); one C(35,36); and one N(3) atom. The C(33)-C(35,36) bond length is 1.40 Å. The C(33)-N(3) bond length is 1.35 Å. In the sixth C site, C(35,36) is bonded in a distorted single-bond geometry to one C(33) and one H(31,32) atom. The C(35,36)-H(31,32) bond length is 1.09 Å. In the seventh C site, C(37) is bonded in a distorted single-bond geometry to one C(39) and one H(33) atom. The C(37)-C(39) bond length is 1.39 Å. The C(37)-H(33) bond length is 1.09 Å. In the eighth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(37), one C(41), and one H(35) atom. The C(39)-C(41) bond length is 1.39 Å. The C(39)-H(35) bond length is 1.09 Å. In the ninth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(39), one N(3), and one H(37) atom. The C(41)-N(3) bond length is 1.34 Å. The C(41)-H(37) bond length is 1.09 Å. In the tenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(5) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(5) bond length is 1.27 Å. In the eleventh C site, C(3,4) is bonded in a distorted trigonal non-coplanar geometry to one H(11,12); one H(9,10); and one O(19,20) atom. The C(3,4)-H(11,12) bond length is 1.10 Å. The C(3,4)-H(9,10) bond length is 1.10 Å. The C(3,4)-O(19,20) bond length is 1.42 Å. In the twelfth C site, C(5,6) is bonded in a distorted single-bond geometry to one C(7,8) and one O(19,20) atom. The C(5,6)-C(7,8) bond length is 1.40 Å. The C(5,6)-O(19,20) bond length is 1.37 Å. In the thirteenth C site, C(7,8) is bonded in a distorted trigonal planar geometry to one C(5,6); one C(9); and one H(13,14) atom. The C(7,8)-C(9) bond length is 1.40 Å. The C(7,8)-H(13,14) bond length is 1.09 Å. In the fourteenth C site, C(9) is bonded in a trigonal planar geometry to one C(11); one C(13,14); and one C(7,8) atom. The C(9)-C(11) bond length is 1.50 Å. The C(9)-C(13,14) bond length is 1.40 Å. In the fifteenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(13), and one O(15) atom. The C(11)-O(13) bond length is 1.28 Å. The C(11)-O(15) bond length is 1.27 Å. In the sixteenth C site, C(13,14) is bonded in a distorted single-bond geometry to one C(9) and one H(15,16) atom. The C(13,14)-H(15,16) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(23), and one C(25) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(33), and one C(41) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. The H(1)-O(3) bond length is 1.00 Å. In the second H site, H(3) is bonded in a single-bond geometry to one O(3) atom. The H(3)-O(3) bond length is 0.98 Å. In the third H site, H(9,10) is bonded in a single-bond geometry to one C(3,4) atom. In the fourth H site, H(11,12) is bonded in a single-bond geometry to one C(3,4) atom. In the fifth H site, H(13,14) is bonded in a single-bond geometry to one C(7,8) atom. In the sixth H site, H(15,16) is bonded in a single-bond geometry to one C(13,14) atom. In the seventh H site, H(23) is bonded in a single-bond geometry to one C(25) atom. In the eighth H site, H(25) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(29,30) is bonded in a single-bond geometry to one C(31) atom. In the tenth H site, H(31,32) is bonded in a single-bond geometry to one C(35,36) atom. In the eleventh H site, H(33) is bonded in a single-bond geometry to one C(37) atom. In the twelfth H site, H(35) is bonded in a single-bond geometry to one C(39) atom. In the thirteenth H site, H(37) is bonded in a single-bond geometry to one C(41) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(3) is bonded in a water-like geometry to one Cd(1), one H(1), and one H(3) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the fourth O site, O(19,20) is bonded in a bent 120 degrees geometry to one C(3,4) and one C(5,6) atom. In the fifth O site, O(13) is bonded in an L-shaped geometry to one Cd(1) and one C(11) atom. In the sixth O site, O(15) is bonded in a distorted single-bond geometry to one Cd(1) and one C(11) atom. Linkers: 4 [O]C(=O)COc1cc(OCC([O])=O)cc(C([O])=O)c1 ,2 c1ccc(-c2ccccn2)nc1. Metal clusters: 6 [Cd]. The MOF has largest included sphere 3.84 A, density 1.57 g/cm3, surface area 4256.89 m2/g, accessible volume 0.20 cm3/g