(CuC8NH6O4)2(CH2)7 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty-eight 02329_fluka molecules and four CuC8NH6O4 clusters. In each CuC8NH6O4 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(12), one O(16), and one O(5) atom. The Cu(1)-N(1) bond length is 2.17 Å. The Cu(1)-O(1) bond length is 2.02 Å. The Cu(1)-O(12) bond length is 2.01 Å. The Cu(1)-O(16) bond length is 2.02 Å. The Cu(1)-O(5) bond length is 2.01 Å. There are eight inequivalent C sites. In the first C site, C(20) is bonded in a distorted bent 120 degrees geometry to one O(12) and one O(16) atom. The C(20)-O(12) bond length is 1.27 Å. The C(20)-O(16) bond length is 1.27 Å. In the second C site, C(21) is bonded in a distorted trigonal planar geometry to one C(25), one N(1), and one H(25) atom. The C(21)-C(25) bond length is 1.39 Å. The C(21)-N(1) bond length is 1.34 Å. The C(21)-H(25) bond length is 1.09 Å. In the third C site, C(25) is bonded in a distorted trigonal planar geometry to one C(21); one C(29,30,31,32); and one H(29,30,31,32) atom. The C(25)-C(29,30,31,32) bond length is 1.40 Å. The C(25)-H(29,30,31,32) bond length is 1.09 Å. In the fourth C site, C(29,30,31,32) is bonded in a trigonal planar geometry to one C(25), one C(33), and one C(41) atom. The C(29,30,31,32)-C(33) bond length is 1.40 Å. The C(29,30,31,32)-C(41) bond length is 1.50 Å. In the fifth C site, C(33) is bonded in a distorted trigonal planar geometry to one C(29,30,31,32); one C(37); and one H(33,34,35,36) atom. The C(33)-C(37) bond length is 1.39 Å. The C(33)-H(33,34,35,36) bond length is 1.09 Å. In the sixth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(33), one N(1), and one H(37) atom. The C(37)-N(1) bond length is 1.35 Å. The C(37)-H(37) bond length is 1.09 Å. In the seventh C site, C(41) is bonded in a distorted water-like geometry to one C(29,30,31,32); one H(41,42,43,44); and one H(45,46,47,48) atom. The C(41)-H(41,42,43,44) bond length is 1.10 Å. The C(41)-H(45,46,47,48) bond length is 1.10 Å. In the eighth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(5) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(5) bond length is 1.27 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(21), and one C(37) atom. There are six inequivalent H sites. In the first H site, H(25) is bonded in a single-bond geometry to one C(21) atom. In the second H site, H(29,30,31,32) is bonded in a single-bond geometry to one C(25) atom. In the third H site, H(33,34,35,36) is bonded in a single-bond geometry to one C(33) atom. In the fourth H site, H(37) is bonded in a single-bond geometry to one C(37) atom. In the fifth H site, H(41,42,43,44) is bonded in a single-bond geometry to one C(41) atom. In the sixth H site, H(45,46,47,48) is bonded in a single-bond geometry to one C(41) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(12) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(20) atom. In the fourth O site, O(16) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(20) atom. Linkers: 8 [O]C(=O)CCCC([O])=O ,4 c1cc(CCCc2ccncc2)ccn1. Metal clusters: 4 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 6.32 A, density 1.25 g/cm3, surface area 4635.87 m2/g, accessible volume 0.36 cm3/g