CuC4NH2O4(CH3)2C6H4NHOH(CH3CHO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; four dimethyl ether molecules; two n,n-dimethylmethacrylamide molecules; and one CuC4NH2O4 cluster. In the CuC4NH2O4 cluster, Cu(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(7) atom. The Cu(1)-N(1) bond length is 2.18 Å. The Cu(1)-O(1) bond length is 2.01 Å. The Cu(1)-O(2) bond length is 2.00 Å. The Cu(1)-O(3) bond length is 2.01 Å. The Cu(1)-O(7) bond length is 2.01 Å. There are four inequivalent C sites. In the first C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(11)-O(1) bond length is 1.28 Å. The C(11)-O(2) bond length is 1.27 Å. In the second C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(7) atom. The C(13)-O(3) bond length is 1.28 Å. The C(13)-O(7) bond length is 1.28 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(11) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(11) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(13) atom. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(13) atom. Linkers: 1 O=C(c1ccncc1)N1CCOCCOCCN(C(=O)c2ccncc2)CCOCCOCC1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.13 A, density 1.59 g/cm3, surface area 4865.96 m2/g, accessible volume 0.10 cm3/g