Zn4C46N2H28O13(CH4)4 crystallizes in the monoclinic P2 space group. The structure consists of eight 02329_fluka molecules inside a Zn4C46N2H28O13 framework. In the Zn4C46N2H28O13 framework, there are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(11), one O(13), and one O(8) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(11) bond length is 1.96 Å. The Zn(1)-O(13) bond length is 1.96 Å. The Zn(1)-O(8) bond length is 1.96 Å. In the second Zn site, Zn(2) is bonded to one O(12), one O(14), one O(2), and one O(7) atom to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(12) bond length is 1.96 Å. The Zn(2)-O(14) bond length is 1.96 Å. The Zn(2)-O(2) bond length is 1.97 Å. The Zn(2)-O(7) bond length is 1.96 Å. In the third Zn site, Zn(3) is bonded to one O(14), one O(3), one O(6), and one O(9) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(14) bond length is 1.96 Å. The Zn(3)-O(3) bond length is 1.97 Å. The Zn(3)-O(6) bond length is 1.96 Å. The Zn(3)-O(9) bond length is 1.96 Å. In the fourth Zn site, Zn(4) is bonded to one O(10), one O(13), one O(4), and one O(5) atom to form corner-sharing ZnO4 tetrahedra. The Zn(4)-O(10) bond length is 1.96 Å. The Zn(4)-O(13) bond length is 1.96 Å. The Zn(4)-O(4) bond length is 1.97 Å. The Zn(4)-O(5) bond length is 1.96 Å. There are fifty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(5) atom. The C(1)-C(5) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(5) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(2), and one O(6) atom. The C(2)-C(6) bond length is 1.49 Å. The C(2)-O(2) bond length is 1.28 Å. The C(2)-O(6) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(7) atom. The C(3)-C(7) bond length is 1.49 Å. The C(3)-O(3) bond length is 1.28 Å. The C(3)-O(7) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(4), and one O(8) atom. The C(4)-C(8) bond length is 1.49 Å. The C(4)-O(4) bond length is 1.28 Å. The C(4)-O(8) bond length is 1.28 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(25), and one C(9) atom. The C(5)-C(25) bond length is 1.40 Å. The C(5)-C(9) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(26) atom. The C(6)-C(10) bond length is 1.40 Å. The C(6)-C(26) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(27), and one C(3) atom. The C(7)-C(11) bond length is 1.40 Å. The C(7)-C(27) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(28), and one C(4) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(28) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(13), one C(5), and one H(1) atom. The C(9)-C(13) bond length is 1.39 Å. The C(9)-H(1) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(14), one C(6), and one H(2) atom. The C(10)-C(14) bond length is 1.39 Å. The C(10)-H(2) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(15), one C(7), and one H(3) atom. The C(11)-C(15) bond length is 1.39 Å. The C(11)-H(3) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(16), one C(8), and one H(4) atom. The C(12)-C(16) bond length is 1.39 Å. The C(12)-H(4) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(17), one C(9), and one H(5) atom. The C(13)-C(17) bond length is 1.40 Å. The C(13)-H(5) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(10), one C(18), and one H(6) atom. The C(14)-C(18) bond length is 1.40 Å. The C(14)-H(6) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(11), one C(19), and one H(7) atom. The C(15)-C(19) bond length is 1.40 Å. The C(15)-H(7) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(12), one C(20), and one H(8) atom. The C(16)-C(20) bond length is 1.40 Å. The C(16)-H(8) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(13), one C(21), and one C(29) atom. The C(17)-C(21) bond length is 1.40 Å. The C(17)-C(29) bond length is 1.52 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(14), one C(22), and one C(30) atom. The C(18)-C(22) bond length is 1.40 Å. The C(18)-C(30) bond length is 1.51 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(15), one C(23), and one C(31) atom. The C(19)-C(23) bond length is 1.40 Å. The C(19)-C(31) bond length is 1.51 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(16), one C(24), and one C(32) atom. The C(20)-C(24) bond length is 1.40 Å. The C(20)-C(32) bond length is 1.52 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(17) and one H(9,12) atom. The C(21)-H(9,12) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(18), one C(26), and one H(10) atom. The C(22)-C(26) bond length is 1.39 Å. The C(22)-H(10) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(19) and one H(11) atom. The C(23)-H(11) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(20) and one H(9,12) atom. The C(24)-H(9,12) bond length is 1.09 Å. In the twenty-fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(5) and one H(13) atom. The C(25)-H(13) bond length is 1.09 Å. In the twenty-sixth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(22), one C(6), and one H(14) atom. The C(26)-H(14) bond length is 1.09 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(7) and one H(15) atom. The C(27)-H(15) bond length is 1.09 Å. In the twenty-eighth C site, C(28) is bonded in a distorted single-bond geometry to one C(8) and one H(16) atom. The C(28)-H(16) bond length is 1.09 Å. In the twenty-ninth C site, C(29) is bonded in a distorted trigonal non-coplanar geometry to one C(17); one N(1,4); one H(17,20); and one H(21,24) atom. The C(29)-N(1,4) bond length is 1.45 Å. The C(29)-H(17,20) bond length is 1.10 Å. The C(29)-H(21,24) bond length is 1.10 Å. In the thirtieth C site, C(30) is bonded in a distorted trigonal non-coplanar geometry to one C(18), one N(2), one H(18), and one H(22) atom. The C(30)-N(2) bond length is 1.45 Å. The C(30)-H(18) bond length is 1.10 Å. The C(30)-H(22) bond length is 1.10 Å. In the thirty-first C site, C(31) is bonded in a distorted trigonal non-coplanar geometry to one C(19), one N(3), one H(19), and one H(23) atom. The C(31)-N(3) bond length is 1.45 Å. The C(31)-H(19) bond length is 1.10 Å. The C(31)-H(23) bond length is 1.10 Å. In the thirty-second C site, C(32) is bonded in a distorted trigonal non-coplanar geometry to one C(20); one N(1,4); one H(17,20); and one H(21,24) atom. The C(32)-N(1,4) bond length is 1.45 Å. The C(32)-H(17,20) bond length is 1.10 Å. The C(32)-H(21,24) bond length is 1.10 Å. In the thirty-third C site, C(33,35) is bonded in a distorted single-bond geometry to two equivalent C(37,40) and one N(1,4) atom. Both C(33,35)-C(37,40) bond lengths are 1.44 Å. The C(33,35)-N(1,4) bond length is 1.36 Å. In the thirty-fourth C site, C(34) is bonded in a distorted single-bond geometry to two equivalent C(38) and one N(2) atom. Both C(34)-C(38) bond lengths are 1.44 Å. The C(34)-N(2) bond length is 1.36 Å. In the thirty-fifth C site, C(36) is bonded in a distorted single-bond geometry to two equivalent C(37,40) and one N(1,4) atom. Both C(36)-C(37,40) bond lengths are 1.44 Å. The C(36)-N(1,4) bond length is 1.36 Å. In the thirty-sixth C site, C(37,40) is bonded in a distorted single-bond geometry to one C(33,35); one C(41); and one H(25,27) atom. The C(37,40)-C(41) bond length is 1.37 Å. The C(37,40)-H(25,27) bond length is 1.09 Å. In the thirty-seventh C site, C(38) is bonded in a distorted single-bond geometry to one C(34), one C(42), and one H(26) atom. The C(38)-C(42) bond length is 1.37 Å. The C(38)-H(26) bond length is 1.09 Å. In the thirty-eighth C site, C(39) is bonded in a distorted single-bond geometry to one C(33,35); one C(43); and one H(25,27) atom. The C(39)-C(33,35) bond length is 1.44 Å. The C(39)-C(43) bond length is 1.37 Å. The C(39)-H(25,27) bond length is 1.09 Å. In the thirty-ninth C site, C(41) is bonded in a 3-coordinate geometry to one C(37,40); one C(41); and one C(49) atom. The C(41)-C(41) bond length is 1.60 Å. The C(41)-C(49) bond length is 1.36 Å. In the fortieth C site, C(42) is bonded in a 3-coordinate geometry to one C(38), one C(42), and one C(50) atom. The C(42)-C(42) bond length is 1.60 Å. The C(42)-C(50) bond length is 1.36 Å. In the forty-first C site, C(43) is bonded in a 3-coordinate geometry to one C(39), one C(43), and one C(51) atom. The C(43)-C(43) bond length is 1.60 Å. The C(43)-C(51) bond length is 1.36 Å. In the forty-second C site, C(44) is bonded in a 3-coordinate geometry to one C(37,40); one C(44); and one C(52) atom. The C(44)-C(37,40) bond length is 1.37 Å. The C(44)-C(44) bond length is 1.60 Å. The C(44)-C(52) bond length is 1.36 Å. In the forty-third C site, C(49) is bonded in a 3-coordinate geometry to one C(53) and two equivalent C(41) atoms. The C(49)-C(53) bond length is 1.47 Å. In the forty-fourth C site, C(50) is bonded in a 3-coordinate geometry to one C(54) and two equivalent C(42) atoms. The C(50)-C(54) bond length is 1.47 Å. In the forty-fifth C site, C(51) is bonded in a 3-coordinate geometry to one C(55) and two equivalent C(43) atoms. The C(51)-C(55) bond length is 1.47 Å. In the forty-sixth C site, C(52) is bonded in a 3-coordinate geometry to one C(56) and two equivalent C(44) atoms. The C(52)-C(56) bond length is 1.47 Å. In the forty-seventh C site, C(53) is bonded in a distorted bent 120 degrees geometry to one C(49) and two equivalent O(9) atoms. Both C(53)-O(9) bond lengths are 1.28 Å. In the forty-eighth C site, C(54) is bonded in a distorted bent 120 degrees geometry to one C(50) and two equivalent O(10) atoms. Both C(54)-O(10) bond lengths are 1.28 Å. In the forty-ninth C site, C(55) is bonded in a distorted bent 120 degrees geometry to one C(51) and two equivalent O(11) atoms. Both C(55)-O(11) bond lengths are 1.28 Å. In the fiftieth C site, C(56) is bonded in a distorted bent 120 degrees geometry to one C(52) and two equivalent O(12) atoms. Both C(56)-O(12) bond lengths are 1.28 Å. There are three inequivalent N sites. In the first N site, N(1,4) is bonded in a trigonal planar geometry to one C(33,35) and two equivalent C(29) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(34) and two equivalent C(30) atoms. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(33,35) and two equivalent C(31) atoms. The N(3)-C(33,35) bond length is 1.36 Å. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9,12) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(26) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(27) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(28) atom. In the sixteenth H site, H(17,20) is bonded in a single-bond geometry to one C(29) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(31) atom. In the nineteenth H site, H(21,24) is bonded in a single-bond geometry to one C(29) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(30) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the twenty-second H site, H(25,27) is bonded in a single-bond geometry to one C(37,40) atom. In the twenty-third H site, H(26) is bonded in a single-bond geometry to one C(38) atom. In the twenty-fourth H site, H(28) is bonded in a single-bond geometry to one C(37,40) atom. The H(28)-C(37,40) bond length is 1.09 Å. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(53) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(54) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(55) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(56) atom. In the thirteenth O site, O(13) is bonded in a tetrahedral geometry to two equivalent Zn(1) and two equivalent Zn(4) atoms. In the fourteenth O site, O(14) is bonded in a tetrahedral geometry to two equivalent Zn(2) and two equivalent Zn(3) atoms. Linkers: 4 [O]C(=O)[C]1[C]2[CH]C(N(Cc3ccc(C([O])=O)cc3)Cc3ccc(C([O])=O)cc3)=C[C]21. Metal clusters: 2 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: ant. The MOF has largest included sphere 6.38 A, density 0.82 g/cm3, surface area 5109.13 m2/g, accessible volume 0.78 cm3/g