CuC16N3H11O4(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CuC16N3H11O4 clusters. In each CuC16N3H11O4 cluster, Cu(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one O(1), and one O(3) atom. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-N(2) bond length is 1.98 Å. The Cu(1)-O(1) bond length is 1.97 Å. The Cu(1)-O(3) bond length is 2.03 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(2) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(5) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(5) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one N(3) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-N(3) bond length is 1.38 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(2), and one N(3) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-N(2) bond length is 1.35 Å. The C(6)-N(3) bond length is 1.38 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-H(8) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(9) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(9) bond length is 1.08 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-O(1) bond length is 1.30 Å. The C(11)-O(2) bond length is 1.26 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(14) bond length is 1.40 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(13)-H(10) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(14)-H(11) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(3), and one O(4) atom. The C(15)-C(16) bond length is 1.50 Å. The C(15)-O(3) bond length is 1.30 Å. The C(15)-O(4) bond length is 1.26 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(18) bond length is 1.40 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(17)-H(12) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(16) and one H(13) atom. The C(18)-H(13) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(5), one C(6), and one H(1) atom. The N(3)-H(1) bond length is 1.02 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(11) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(11) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cu(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(15) atom. Linkers: 2 c1ccc(Nc2ccccn2)nc1 ,2 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 1.99 A, density 1.68 g/cm3, surface area 4341.20 m2/g, accessible volume 0.11 cm3/g