AgH3(CN)3CH3 crystallizes in the triclinic P-1 space group. The structure consists of eight 02329_fluka molecules inside a AgH3(CN)3 framework. In the AgH3(CN)3 framework, there are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one N(1), one N(12), and one N(7) atom. The Ag(1)-N(1) bond length is 2.32 Å. The Ag(1)-N(12) bond length is 2.15 Å. The Ag(1)-N(7) bond length is 2.18 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one N(11), one N(2), and one N(8) atom. The Ag(2)-N(11) bond length is 2.15 Å. The Ag(2)-N(2) bond length is 2.32 Å. The Ag(2)-N(8) bond length is 2.18 Å. In the third Ag site, Ag(3) is bonded in a distorted trigonal planar geometry to one N(10), one N(3), and one N(6) atom. The Ag(3)-N(10) bond length is 2.28 Å. The Ag(3)-N(3) bond length is 2.15 Å. The Ag(3)-N(6) bond length is 2.23 Å. In the fourth Ag site, Ag(4) is bonded in a distorted trigonal planar geometry to one N(4), one N(5), and one N(9) atom. The Ag(4)-N(4) bond length is 2.15 Å. The Ag(4)-N(5) bond length is 2.23 Å. The Ag(4)-N(9) bond length is 2.28 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one N(5) atom. The C(1)-C(5) bond length is 1.49 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(5) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(6), one N(2), and one N(6) atom. The C(2)-C(6) bond length is 1.49 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-N(6) bond length is 1.36 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(3); one N(5); and one H(1,2) atom. The C(3)-N(3) bond length is 1.34 Å. The C(3)-N(5) bond length is 1.35 Å. The C(3)-H(1,2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(4); one N(6); and one H(1,2) atom. The C(4)-N(4) bond length is 1.34 Å. The C(4)-N(6) bond length is 1.35 Å. The C(4)-H(1,2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted water-like geometry to one C(1); one H(3,4); and one H(5,6) atom. The C(5)-H(3,4) bond length is 1.10 Å. The C(5)-H(5,6) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one C(2); one H(3,4); and one H(5,6) atom. The C(6)-H(3,4) bond length is 1.10 Å. The C(6)-H(5,6) bond length is 1.10 Å. In the seventh C site, C(9,10) is bonded in a distorted trigonal planar geometry to one C(13), one N(11), and one N(7) atom. The C(9,10)-C(13) bond length is 1.49 Å. The C(9,10)-N(11) bond length is 1.36 Å. The C(9,10)-N(7) bond length is 1.34 Å. In the eighth C site, C(11) is bonded in a trigonal planar geometry to one N(11); one N(9); and one H(13,14) atom. The C(11)-N(11) bond length is 1.36 Å. The C(11)-N(9) bond length is 1.33 Å. The C(11)-H(13,14) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a trigonal planar geometry to one N(10); one N(12); and one H(13,14) atom. The C(12)-N(10) bond length is 1.33 Å. The C(12)-N(12) bond length is 1.36 Å. The C(12)-H(13,14) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted water-like geometry to one C(9,10); one H(15,16); and one H(17,18) atom. The C(13)-H(15,16) bond length is 1.10 Å. The C(13)-H(17,18) bond length is 1.10 Å. In the eleventh C site, C(14) is bonded in a distorted water-like geometry to one C(9,10); one H(15,16); and one H(17,18) atom. The C(14)-C(9,10) bond length is 1.49 Å. The C(14)-H(15,16) bond length is 1.10 Å. The C(14)-H(17,18) bond length is 1.10 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one N(3) atom. The N(1)-N(3) bond length is 1.38 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(2), and one N(4) atom. The N(2)-N(4) bond length is 1.38 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(3), one C(3), and one N(1) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(4), one C(4), and one N(2) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Ag(4), one C(1), and one C(3) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Ag(3), one C(2), and one C(4) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Ag(1); one C(9,10); and one N(9) atom. The N(7)-N(9) bond length is 1.37 Å. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Ag(2); one C(9,10); and one N(10) atom. The N(8)-C(9,10) bond length is 1.34 Å. The N(8)-N(10) bond length is 1.37 Å. In the ninth N site, N(9) is bonded in a 3-coordinate geometry to one Ag(4), one C(11), and one N(7) atom. In the tenth N site, N(10) is bonded in a 3-coordinate geometry to one Ag(3), one C(12), and one N(8) atom. In the eleventh N site, N(11) is bonded in a distorted trigonal planar geometry to one Ag(2); one C(11); and one C(9,10) atom. In the twelfth N site, N(12) is bonded in a distorted trigonal planar geometry to one Ag(1); one C(12); and one C(9,10) atom. The N(12)-C(9,10) bond length is 1.36 Å. There are six inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(13,14) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(15,16) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(17,18) is bonded in a single-bond geometry to one C(13) atom. Linkers: 1 CCC1=N[N]C=N1 ,3 CCC1=[N]=CN=N1 ,4 CCC1=NN=C[N]1. Metal clusters: 2 N1=N[Ag]2N=N[Ag]N=N[Ag]2N=N[Ag]1. The MOF has largest included sphere 4.20 A, density 2.03 g/cm3, surface area 3483.95 m2/g, accessible volume 0.19 cm3/g