CdH8(CO4)2(CdC7NH8O6)2(CH)6(CH2CO)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, six dimethyl ether molecules, one CdC7NH8O6 cluster, and one CdH8(CO4)2 cluster. In the CdC7NH8O6 cluster, Cd(1) is bonded in a distorted octahedral geometry to one N(1), one O(10), one O(11), one O(5), one O(6), and one O(7) atom. The Cd(1)-N(1) bond length is 2.31 Å. The Cd(1)-O(10) bond length is 2.36 Å. The Cd(1)-O(11) bond length is 2.43 Å. The Cd(1)-O(5) bond length is 2.27 Å. The Cd(1)-O(6) bond length is 2.31 Å. The Cd(1)-O(7) bond length is 2.56 Å. There are seven inequivalent C sites. In the first C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(8)-O(4) bond length is 1.27 Å. The C(8)-O(5) bond length is 1.28 Å. In the second C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(10)-O(6) bond length is 1.27 Å. The C(10)-O(7) bond length is 1.28 Å. In the third C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(1), and one H(10) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-N(1) bond length is 1.35 Å. The C(13)-H(10) bond length is 1.09 Å. In the fourth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(11) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(11) bond length is 1.09 Å. In the fifth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(16) atom. The C(15)-C(15) bond length is 1.48 Å. The C(15)-C(16) bond length is 1.40 Å. In the sixth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(12) atom. The C(16)-H(12) bond length is 1.09 Å. In the seventh C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(17)-N(1) bond length is 1.35 Å. The C(17)-H(13) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(17) atom. There are eight inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one O(10) atom. The H(14)-O(10) bond length is 1.00 Å. In the sixth H site, H(15) is bonded in a single-bond geometry to one O(10) atom. The H(15)-O(10) bond length is 1.00 Å. In the seventh H site, H(16) is bonded in a single-bond geometry to one O(11) atom. The H(16)-O(11) bond length is 0.97 Å. In the eighth H site, H(17) is bonded in a single-bond geometry to one O(11) atom. The H(17)-O(11) bond length is 1.00 Å. There are six inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one C(8) atom. In the second O site, O(5) is bonded in a distorted water-like geometry to one Cd(1) and one C(8) atom. In the third O site, O(6) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(10) atom. In the fourth O site, O(7) is bonded in a distorted single-bond geometry to one Cd(1) and one C(10) atom. In the fifth O site, O(10) is bonded in a distorted water-like geometry to one Cd(1), one H(14), and one H(15) atom. In the sixth O site, O(11) is bonded in a water-like geometry to one Cd(1), one H(16), and one H(17) atom. In the CdH8(CO4)2 cluster, Cd(2) is bonded in an octahedral geometry to two equivalent O(12), two equivalent O(13), and two equivalent O(9) atoms. Both Cd(2)-O(12) bond lengths are 2.36 Å. Both Cd(2)-O(13) bond lengths are 2.40 Å. Both Cd(2)-O(9) bond lengths are 2.27 Å. C(12) is bonded in a distorted bent 120 degrees geometry to one O(8) and one O(9) atom. The C(12)-O(8) bond length is 1.28 Å. The C(12)-O(9) bond length is 1.26 Å. There are four inequivalent H sites. In the first H site, H(18) is bonded in a single-bond geometry to one O(12) atom. The H(18)-O(12) bond length is 0.99 Å. In the second H site, H(19) is bonded in a single-bond geometry to one O(12) atom. The H(19)-O(12) bond length is 1.00 Å. In the third H site, H(20) is bonded in a single-bond geometry to one O(13) atom. The H(20)-O(13) bond length is 0.98 Å. In the fourth H site, H(21) is bonded in a single-bond geometry to one O(13) atom. The H(21)-O(13) bond length is 1.00 Å. There are four inequivalent O sites. In the first O site, O(9) is bonded in a bent 120 degrees geometry to one Cd(2) and one C(12) atom. In the second O site, O(12) is bonded in a distorted water-like geometry to one Cd(2), one H(18), and one H(19) atom. In the third O site, O(13) is bonded in a distorted water-like geometry to one Cd(2), one H(20), and one H(21) atom. In the fourth O site, O(8) is bonded in a distorted single-bond geometry to one C(12) atom. Linkers: 2 [O]C(=O)COc1cc(OCC([O])=O)cc(OCC([O])=O)c1 ,4 [O]C(=O)COc1cc(OC[C]=O)cc(OCC([O])=O)c1 ,1 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 O.O.O=[C]O[Cd]O[C]=O ,1 O.O.O.O.O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 3.99 A, density 1.84 g/cm3, surface area 3846.09 m2/g, accessible volume 0.16 cm3/g