CuC18H14(N3O2)2(CH)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two CuC18H14(N3O2)2 clusters. In each CuC18H14(N3O2)2 cluster, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(3), one N(6), one O(1), and one O(3) atom. The Cu(1)-N(3) bond length is 1.96 Å. The Cu(1)-N(6) bond length is 1.98 Å. The Cu(1)-O(1) bond length is 2.00 Å. The Cu(1)-O(3) bond length is 2.02 Å. There are eighteen inequivalent C sites. In the first C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(20) atom. The C(16)-C(15) bond length is 1.40 Å. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(20) bond length is 1.50 Å. In the second C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(15) atom. The C(17)-H(15) bond length is 1.09 Å. In the third C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(16) atom. The C(18)-C(13) bond length is 1.40 Å. The C(18)-H(16) bond length is 1.09 Å. In the fourth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(1), and one O(2) atom. The C(19)-C(13) bond length is 1.50 Å. The C(19)-O(1) bond length is 1.29 Å. The C(19)-O(2) bond length is 1.26 Å. In the fifth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(3), and one O(4) atom. The C(20)-O(3) bond length is 1.30 Å. The C(20)-O(4) bond length is 1.25 Å. In the sixth C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.50 Å. In the seventh C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(8) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(8) bond length is 1.52 Å. In the eighth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.10 Å. In the ninth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the tenth C site, C(7) is bonded in a 3-coordinate geometry to one C(1), one N(1), one H(5), and one H(6) atom. The C(7)-N(1) bond length is 1.46 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.09 Å. In the eleventh C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one N(4), one H(7), and one H(8) atom. The C(8)-N(4) bond length is 1.47 Å. The C(8)-H(7) bond length is 1.10 Å. The C(8)-H(8) bond length is 1.10 Å. In the twelfth C site, C(9) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(9) atom. The C(9)-N(2) bond length is 1.33 Å. The C(9)-N(3) bond length is 1.36 Å. The C(9)-H(9) bond length is 1.08 Å. In the thirteenth C site, C(10) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(10) atom. The C(10)-N(1) bond length is 1.34 Å. The C(10)-N(3) bond length is 1.34 Å. The C(10)-H(10) bond length is 1.08 Å. In the fourteenth C site, C(11) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(11) atom. The C(11)-N(5) bond length is 1.33 Å. The C(11)-N(6) bond length is 1.37 Å. The C(11)-H(11) bond length is 1.09 Å. In the fifteenth C site, C(12) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(12) atom. The C(12)-N(4) bond length is 1.34 Å. The C(12)-N(6) bond length is 1.34 Å. The C(12)-H(12) bond length is 1.08 Å. In the sixteenth C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(19) atom. The C(13)-C(14) bond length is 1.40 Å. In the seventeenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(13) atom. The C(14)-H(13) bond length is 1.09 Å. In the eighteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(14) atom. The C(15)-H(14) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(10), one C(7), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(9) and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(9) atom. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one C(12), one C(8), and one N(5) atom. The N(4)-N(5) bond length is 1.36 Å. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(11) and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(12) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(19) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(19) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cu(1) and one C(20) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(20) atom. Linkers: 2 [CH]1N=C[N]N1Cc1ccccc1Cn1cncn1 ,2 [O][C]c1ccc(C(=O)O[Cu]2(OC(=O)c3ccc(C([O])=O)cc3)N3[CH]N(Cc4ccccc4CN4[CH]N(C=N4)[Cu](OC(=O)c4ccc(C([O])=O)cc4)(OC(=O)c4ccc(C([O])=O)cc4)N4[CH]N(Cc5ccccc5CN5[CH]N2C=N5)N=C4)N=C3)cc1 ,1 [O]C(=O)c1ccc(C(=O)O[Cu]2(OC(=O)c3ccc(C([O])=O)cc3)N3[CH]N(Cc4ccccc4CN4[CH]N(C=N4)[Cu](OC(=O)c4ccc(C([O])=O)cc4)(OC(=O)c4ccc(C([O])=O)cc4)N4[CH]N(Cc5ccccc5CN5[CH]N2C=N5)N=C4)N=C3)cc1. Metal clusters: 2 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 3.26 A, density 1.50 g/cm3, surface area 4681.12 m2/g, accessible volume 0.19 cm3/g