Ag3C16N8H12S2O14Cl3 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent N(2), two equivalent N(4), and two equivalent O(8) atoms. Both Ag(1)-N(2) bond lengths are 2.43 Å. Both Ag(1)-N(4) bond lengths are 2.41 Å. Both Ag(1)-O(8) bond lengths are 2.80 Å. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one N(1), one N(3), one O(2), one O(5), and two equivalent O(4) atoms. The Ag(2)-N(1) bond length is 2.20 Å. The Ag(2)-N(3) bond length is 2.23 Å. The Ag(2)-O(2) bond length is 2.83 Å. The Ag(2)-O(5) bond length is 2.78 Å. There is one shorter (2.55 Å) and one longer (2.68 Å) Ag(2)-O(4) bond length. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(2), and one S(1) atom. The C(2)-N(2) bond length is 1.33 Å. The C(2)-S(1) bond length is 1.83 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one N(2) and one H(2) atom. The C(3)-N(2) bond length is 1.34 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(4), and one S(1) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(4) bond length is 1.33 Å. The C(5)-S(1) bond length is 1.82 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(3), and one H(4) atom. The C(6)-N(3) bond length is 1.34 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(3), and one H(5) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(3) bond length is 1.34 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one N(4), and one H(6) atom. The C(8)-N(4) bond length is 1.34 Å. The C(8)-H(6) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(2), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(2), and one C(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(2), one C(6), and one C(7) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(5), and one C(8) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. S(1) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one O(1) atom. The S(1)-O(1) bond length is 1.49 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Ag(2) and one Cl(1) atom. The O(2)-Cl(1) bond length is 1.47 Å. In the third O site, O(3) is bonded in a single-bond geometry to one Cl(1) atom. The O(3)-Cl(1) bond length is 1.45 Å. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Ag(2) and one Cl(1) atom. The O(4)-Cl(1) bond length is 1.48 Å. In the fifth O site, O(5) is bonded in a single-bond geometry to one Ag(2) and one Cl(1) atom. The O(5)-Cl(1) bond length is 1.46 Å. In the sixth O site, O(6) is bonded in a single-bond geometry to one Cl(2) atom. The O(6)-Cl(2) bond length is 1.46 Å. In the seventh O site, O(7) is bonded in a single-bond geometry to one Cl(2) atom. The O(7)-Cl(2) bond length is 1.47 Å. In the eighth O site, O(8) is bonded in a single-bond geometry to one Ag(1) and one Cl(2) atom. The O(8)-Cl(2) bond length is 1.47 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(4), and one O(5) atom. In the second Cl site, Cl(2) is bonded in a tetrahedral geometry to one O(6), one O(7), and two equivalent O(8) atoms. Linkers: 3 O=[S@]1[C]2C=NC=CN2[Ag]2(N3C=CN=C[C]3[S@](=O)[C]3C=NC=CN32)N2C=CN=C[C]21.[O].[O].[O].[O]Cl ,1 O=[S@@]1[C]2C=NC=CN2[Ag@@]2(N3C=CN=C[C]3[S@](=O)C3=CN=C[CH]N32)N2[CH]C=NC=C21.[O].[O].[O].[O]Cl. Metal clusters: 8 [Ag]. The MOF has largest included sphere 3.35 A, density 2.42 g/cm3, surface area 2988.07 m2/g, accessible volume 0.07 cm3/g