Ag2C3H6(NCl)2 crystallizes in the orthorhombic Pnma space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to one N(1), one Cl(3), two equivalent Cl(1), and two equivalent Cl(2) atoms. The Ag(1)-N(1) bond length is 2.45 Å. The Ag(1)-Cl(3) bond length is 2.92 Å. Both Ag(1)-Cl(1) bond lengths are 2.66 Å. There is one shorter (2.90 Å) and one longer (3.13 Å) Ag(1)-Cl(2) bond length. In the second Ag site, Ag(2) is bonded to one N(2), one Cl(3), and two equivalent Cl(1) atoms to form AgNCl3 tetrahedra that share  a cornercorner with one C(3)H2N2 tetrahedra and corners with two equivalent C(2)H2N2 tetrahedra. The Ag(2)-N(2) bond length is 2.39 Å. The Ag(2)-Cl(3) bond length is 2.51 Å. Both Ag(2)-Cl(1) bond lengths are 2.55 Å. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to one N(3), one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. The Ag(3)-N(3) bond length is 2.36 Å. The Ag(3)-Cl(2) bond length is 2.56 Å. The Ag(3)-Cl(3) bond length is 2.78 Å. There is one shorter (2.82 Å) and one longer (3.03 Å) Ag(3)-Cl(1) bond length. There are four inequivalent C sites. In the first C site, C(1) is bonded to one N(1), one N(3), one H(1), and one H(2) atom to form corner-sharing CH2N2 tetrahedra. The C(1)-N(1) bond length is 1.48 Å. The C(1)-N(3) bond length is 1.48 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the second C site, C(2) is bonded to one N(2), one N(3), one H(3), and one H(4) atom to form CH2N2 tetrahedra that share  a cornercorner with one Ag(2)NCl3 tetrahedra,  a cornercorner with one C(1)H2N2 tetrahedra,  a cornercorner with one C(2)H2N2 tetrahedra,  a cornercorner with one C(3)H2N2 tetrahedra, and  a cornercorner with one C(4)H2N2 tetrahedra. The C(2)-N(2) bond length is 1.48 Å. The C(2)-N(3) bond length is 1.48 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. In the third C site, C(3) is bonded to one N(1), one N(2), and two equivalent H(5) atoms to form CH2N2 tetrahedra that share  a cornercorner with one Ag(2)NCl3 tetrahedra, corners with two equivalent C(1)H2N2 tetrahedra, and corners with two equivalent C(2)H2N2 tetrahedra. The C(3)-N(1) bond length is 1.47 Å. The C(3)-N(2) bond length is 1.48 Å. Both C(3)-H(5) bond lengths are 1.10 Å. In the fourth C site, C(4) is bonded to two equivalent N(3), one H(6), and one H(7) atom to form corner-sharing CH2N2 tetrahedra. Both C(4)-N(3) bond lengths are 1.48 Å. The C(4)-H(6) bond length is 1.10 Å. The C(4)-H(7) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded to one Ag(1), one C(3), and two equivalent C(1) atoms to form distorted corner-sharing NAgC3 tetrahedra. In the second N site, N(2) is bonded to one Ag(2), one C(3), and two equivalent C(2) atoms to form distorted corner-sharing NAgC3 tetrahedra. In the third N site, N(3) is bonded to one Ag(3), one C(1), one C(2), and one C(4) atom to form corner-sharing NAgC3 tetrahedra. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), and two equivalent Ag(3) atoms. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Ag(3) atoms. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), and two equivalent Ag(3) atoms. Linkers: 4 C1N2CN3CN1CN(C2)C3. Metal clusters: 16 [Ag]. The MOF has largest included sphere 1.36 A, density 3.61 g/cm3, surface area 1845.33 m2/g, accessible volume 0.01 cm3/g