ZnC14H12(NO)4(CH2)4(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, eight 02329_fluka molecules, and one ZnC14H12(NO)4 cluster. In the ZnC14H12(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(2), one N(3), one O(1), and one O(3) atom. The Zn(1)-N(2) bond length is 2.01 Å. The Zn(1)-N(3) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 1.99 Å. The Zn(1)-O(3) bond length is 1.99 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.51 Å. The C(1)-C(7) bond length is 1.41 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(15), and one C(3) atom. The C(2)-C(15) bond length is 1.40 Å. The C(2)-C(3) bond length is 1.51 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(3)-O(1) bond length is 1.29 Å. The C(3)-O(2) bond length is 1.25 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(4)-N(1) bond length is 1.47 Å. The C(4)-H(1) bond length is 1.10 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(3), and one O(4) atom. The C(6)-O(3) bond length is 1.30 Å. The C(6)-O(4) bond length is 1.26 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one N(2), one N(4), and one H(8) atom. The C(9)-N(2) bond length is 1.34 Å. The C(9)-N(4) bond length is 1.35 Å. The C(9)-H(8) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(4), and one H(9) atom. The C(10)-C(13) bond length is 1.37 Å. The C(10)-N(4) bond length is 1.38 Å. The C(10)-H(9) bond length is 1.08 Å. In the ninth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(13) atom. The C(13)-N(2) bond length is 1.38 Å. The C(13)-H(13) bond length is 1.08 Å. In the tenth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(14), and one H(15) atom. The C(14)-N(4) bond length is 1.46 Å. The C(14)-H(14) bond length is 1.10 Å. The C(14)-H(15) bond length is 1.10 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(2) and one H(16) atom. The C(15)-H(16) bond length is 1.09 Å. In the twelfth C site, C(17) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(19) atom. The C(17)-N(1) bond length is 1.35 Å. The C(17)-N(3) bond length is 1.33 Å. The C(17)-H(19) bond length is 1.08 Å. In the thirteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(1), and one H(21) atom. The C(19)-C(20) bond length is 1.38 Å. The C(19)-N(1) bond length is 1.38 Å. The C(19)-H(21) bond length is 1.09 Å. In the fourteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(3), and one H(22) atom. The C(20)-N(3) bond length is 1.38 Å. The C(20)-H(22) bond length is 1.08 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(17), and one C(20) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(9) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(6) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(6) atom. Linkers: 2 c1cn(CCCCCCn2ccnc2)cn1 ,2 [O]C(=O)c1ccccc1C([O])=O. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.22 A, density 1.50 g/cm3, surface area 5062.56 m2/g, accessible volume 0.16 cm3/g