AgC13H11(NO)3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AgC13H11(NO)3 clusters. Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(6), and two equivalent O(5) atoms. The Ag(1)-N(1) bond length is 2.16 Å. The Ag(1)-N(6) bond length is 2.18 Å. There is one shorter (2.54 Å) and one longer (2.71 Å) Ag(1)-O(5) bond length. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(3) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(3) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(5) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-H(5) bond length is 1.09 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(7) atom. The C(5)-C(11) bond length is 1.51 Å. The C(5)-C(7) bond length is 1.40 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(5), one C(9), and one H(7) atom. The C(7)-C(9) bond length is 1.39 Å. The C(7)-H(7) bond length is 1.09 Å. In the fifth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one H(9) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(9) bond length is 1.09 Å. In the sixth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one N(3), one H(11), and one H(13) atom. The C(11)-N(3) bond length is 1.46 Å. The C(11)-H(11) bond length is 1.10 Å. The C(11)-H(13) bond length is 1.10 Å. In the seventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(3), and one O(1) atom. The C(13)-C(15) bond length is 1.50 Å. The C(13)-N(3) bond length is 1.36 Å. The C(13)-O(1) bond length is 1.24 Å. In the eighth C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(21) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-C(21) bond length is 1.40 Å. In the ninth C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one H(15,16) atom. The C(17)-H(15,16) bond length is 1.09 Å. In the tenth C site, C(20) is bonded in a distorted trigonal planar geometry to one N(6) and one H(17,18) atom. The C(20)-N(6) bond length is 1.35 Å. The C(20)-H(17,18) bond length is 1.09 Å. In the eleventh C site, C(21) is bonded in a distorted single-bond geometry to one C(15) and one H(19,20) atom. The C(21)-H(19,20) bond length is 1.09 Å. In the twelfth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(21,22) atom. The C(24)-N(6) bond length is 1.35 Å. The C(24)-H(21,22) bond length is 1.09 Å. In the thirteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(5) atom. The C(25)-O(3) bond length is 1.27 Å. The C(25)-O(5) bond length is 1.28 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(9) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(11), one C(13), and one H(1) atom. The N(3)-H(1) bond length is 1.01 Å. In the third N site, N(6) is bonded in a trigonal planar geometry to one Ag(1), one C(20), and one C(24) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(15,16) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(17,18) is bonded in a single-bond geometry to one C(19) atom. The H(17,18)-C(19) bond length is 1.09 Å. In the tenth H site, H(19,20) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(21,22) is bonded in a single-bond geometry to one C(23) atom. The H(21,22)-C(23) bond length is 1.09 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(13) atom. In the second O site, O(3) is bonded in a single-bond geometry to one C(25) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one C(25) atom. Linkers: 2 O=C(NCc1ccncc1)c1ccncc1 ,2 [O]C(=O)C([O])=O. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.96 A, density 1.89 g/cm3, surface area 3614.27 m2/g, accessible volume 0.10 cm3/g