Ag4C25N5H20S2O8(CH)5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules and one Ag4C25N5H20S2O8 cluster. In the Ag4C25N5H20S2O8 cluster, there are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one N(1), one O(1), and one O(7) atom. The Ag(1)-N(1) bond length is 2.35 Å. The Ag(1)-O(1) bond length is 2.26 Å. The Ag(1)-O(7) bond length is 2.37 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one N(3), one O(2), and one O(5) atom. The Ag(2)-N(3) bond length is 2.15 Å. The Ag(2)-O(2) bond length is 2.18 Å. The Ag(2)-O(5) bond length is 2.44 Å. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to one N(4), one H(16), one O(3), and one O(5) atom. The Ag(3)-N(4) bond length is 2.17 Å. The Ag(3)-H(16) bond length is 2.36 Å. The Ag(3)-O(3) bond length is 2.55 Å. The Ag(3)-O(5) bond length is 2.17 Å. In the fourth Ag site, Ag(4) is bonded in a 4-coordinate geometry to one N(2), one N(5), one O(3), and one O(6) atom. The Ag(4)-N(2) bond length is 2.21 Å. The Ag(4)-N(5) bond length is 2.23 Å. The Ag(4)-O(3) bond length is 2.68 Å. The Ag(4)-O(6) bond length is 2.46 Å. There are twenty-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.45 Å. The C(5)-N(1) bond length is 1.36 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(7)-C(8) bond length is 1.46 Å. The C(7)-H(6) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(2) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-N(2) bond length is 1.36 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(9) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(9) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one H(10) atom. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(10) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one H(11) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-N(3) bond length is 1.35 Å. The C(13)-H(11) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(12) atom. The C(14)-H(12) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(14) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(14) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one N(3) atom. The C(17)-C(18) bond length is 1.45 Å. The C(17)-N(3) bond length is 1.36 Å. In the fifteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(15) atom. The C(18)-H(15) bond length is 1.10 Å. In the sixteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(20) and one H(16) atom. The C(19)-C(20) bond length is 1.45 Å. The C(19)-H(16) bond length is 1.10 Å. In the seventeenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one N(4) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-N(4) bond length is 1.37 Å. In the eighteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(17) atom. The C(21)-H(17) bond length is 1.09 Å. In the nineteenth C site, C(24) is bonded in a distorted trigonal planar geometry to one N(4) and one H(20) atom. The C(24)-N(4) bond length is 1.34 Å. The C(24)-H(20) bond length is 1.09 Å. In the twentieth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one N(5), and one H(21) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-N(5) bond length is 1.34 Å. The C(25)-H(21) bond length is 1.09 Å. In the twenty-first C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one C(27), and one H(22) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-H(22) bond length is 1.09 Å. In the twenty-second C site, C(27) is bonded in a distorted trigonal planar geometry to one C(26), one C(28), and one H(23) atom. The C(27)-C(28) bond length is 1.39 Å. The C(27)-H(23) bond length is 1.09 Å. In the twenty-third C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one C(29), and one H(24) atom. The C(28)-C(29) bond length is 1.41 Å. The C(28)-H(24) bond length is 1.09 Å. In the twenty-fourth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one C(30), and one N(5) atom. The C(29)-C(30) bond length is 1.45 Å. The C(29)-N(5) bond length is 1.36 Å. In the twenty-fifth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(25) atom. The C(30)-H(25) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Ag(3), one C(20), and one C(24) atom. In the second N site, N(5) is bonded in a distorted trigonal planar geometry to one Ag(4), one C(25), and one C(29) atom. In the third N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the fourth N site, N(2) is bonded in a trigonal planar geometry to one Ag(4), one C(12), and one C(8) atom. In the fifth N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(13), and one C(17) atom. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one Ag(3) and one C(19) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the sixteenth H site, H(21) is bonded in a single-bond geometry to one C(25) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one C(26) atom. In the eighteenth H site, H(23) is bonded in a single-bond geometry to one C(27) atom. In the nineteenth H site, H(24) is bonded in a single-bond geometry to one C(28) atom. In the twentieth H site, H(25) is bonded in a single-bond geometry to one C(30) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The S(1)-O(1) bond length is 1.51 Å. The S(1)-O(2) bond length is 1.52 Å. The S(1)-O(3) bond length is 1.50 Å. The S(1)-O(4) bond length is 1.46 Å. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(5), one O(6), one O(7), and one O(8) atom. The S(2)-O(5) bond length is 1.54 Å. The S(2)-O(6) bond length is 1.50 Å. The S(2)-O(7) bond length is 1.50 Å. The S(2)-O(8) bond length is 1.46 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ag(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(3), one Ag(4), and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Ag(2), one Ag(3), and one S(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Ag(4) and one S(2) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Ag(1) and one S(2) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one S(2) atom. Linkers: 5 C(=C/c1ccccn1)\c1ccccn1. Metal clusters: 1 [N][Ag]1O[S@]2([O])O[Ag]3O[S@@]4([O])O[Ag]([Ag]5O[S@]6([O])O[Ag]([N])[Ag@@]7(O6)O[S@]([O])(O5)O[Ag]37)[Ag@@]1(O2)O4. The MOF has largest included sphere 3.00 A, density 2.18 g/cm3, surface area 2979.43 m2/g, accessible volume 0.09 cm3/g