AgC14H9(N2O)2 is High Pressure (4-7GPa) Tellurium structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AgC14H9(N2O)2 clusters. Ag(1) is bonded in a 3-coordinate geometry to one N(2), one N(3), and one O(2) atom. The Ag(1)-N(2) bond length is 2.63 Å. The Ag(1)-N(3) bond length is 2.15 Å. The Ag(1)-O(2) bond length is 2.10 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.51 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(1) bond length is 1.42 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.25 Å. The C(7)-O(2) bond length is 1.29 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one N(2) atom. The C(8)-C(11) bond length is 1.46 Å. The C(8)-C(9) bond length is 1.42 Å. The C(8)-N(2) bond length is 1.35 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(5) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-H(5) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(1), and one H(6) atom. The C(10)-N(1) bond length is 1.37 Å. The C(10)-H(6) bond length is 1.08 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(14), one C(8), and one N(3) atom. The C(11)-C(14) bond length is 1.40 Å. The C(11)-N(3) bond length is 1.36 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one N(3), and one H(7) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-N(3) bond length is 1.34 Å. The C(12)-H(7) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one N(4), and one H(8) atom. The C(13)-N(4) bond length is 1.35 Å. The C(13)-H(8) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(4), and one H(9) atom. The C(14)-N(4) bond length is 1.33 Å. The C(14)-H(9) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(10), one C(4), and one N(2) atom. The N(1)-N(2) bond length is 1.35 Å. In the second N site, N(2) is bonded in a distorted single-bond geometry to one Ag(1), one C(8), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(11), and one C(12) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(13) and one C(14) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ag(1) and one C(7) atom. Linkers: 4 [O]C(=O)c1ccc(-n2ccc(-c3cnccn3)n2)cc1. Metal clusters: 4 O=[C]O[Ag]. The MOF has largest included sphere 2.14 A, density 1.94 g/cm3, surface area 3799.41 m2/g, accessible volume 0.08 cm3/g