CdC24H14S(NO)4 is Indium-like structured and crystallizes in the orthorhombic Pcca space group. The structure is zero-dimensional and consists of four CdC24H14S(NO)4 clusters. Cd(1) is bonded in a distorted pentagonal pyramidal geometry to one N(3), one N(4), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(3) bond length is 2.32 Å. The Cd(1)-N(4) bond length is 2.36 Å. The Cd(1)-O(1) bond length is 2.32 Å. The Cd(1)-O(2) bond length is 2.33 Å. The Cd(1)-O(3) bond length is 2.44 Å. The Cd(1)-O(4) bond length is 2.38 Å. There are twenty-four inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(1) bond length is 1.39 Å. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.08 Å. In the second C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(23) atom. The C(18)-C(17) bond length is 1.50 Å. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(23) bond length is 1.40 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.47 Å. In the fourth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(11) atom. The C(19)-H(11) bond length is 1.09 Å. In the fifth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the sixth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(12) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(12) bond length is 1.09 Å. In the seventh C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(3), and one H(4) atom. The C(5)-N(3) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the eighth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(24) bond length is 1.50 Å. In the ninth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(7) atom. The C(6)-C(11) bond length is 1.39 Å. The C(6)-C(7) bond length is 1.43 Å. In the tenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(13) atom. The C(22)-H(13) bond length is 1.09 Å. In the eleventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one N(2) atom. The C(7)-N(2) bond length is 1.35 Å. In the twelfth C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(14) atom. The C(23)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one N(1) atom. The C(8)-C(9) bond length is 1.43 Å. The C(8)-N(1) bond length is 1.36 Å. In the fourteenth C site, C(24) is bonded in a bent 120 degrees geometry to one C(21), one O(3), and one O(4) atom. The C(24)-O(3) bond length is 1.28 Å. The C(24)-O(4) bond length is 1.28 Å. In the fifteenth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(8) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(13) bond length is 1.47 Å. In the sixteenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(5) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-H(5) bond length is 1.09 Å. In the seventeenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one H(6) atom. The C(11)-H(6) bond length is 1.09 Å. In the eighteenth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(7,8) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-H(7,8) bond length is 1.09 Å. In the nineteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(9) atom. The C(13)-C(14) bond length is 1.40 Å. In the twentieth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(7,8) atom. The C(14)-H(7,8) bond length is 1.09 Å. In the twenty-first C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(1), and one O(2) atom. The C(17)-O(1) bond length is 1.27 Å. The C(17)-O(2) bond length is 1.28 Å. In the twenty-second C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(9,10) atom. The C(15)-N(4) bond length is 1.34 Å. The C(15)-H(9,10) bond length is 1.09 Å. In the twenty-third C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(9,10) atom. The C(16)-N(4) bond length is 1.34 Å. The C(16)-H(9,10) bond length is 1.09 Å. In the twenty-fourth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(3), and one H(1) atom. The C(1)-N(3) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one C(8) and one S(1) atom. The N(1)-S(1) bond length is 1.62 Å. In the second N site, N(2) is bonded in a water-like geometry to one C(7) and one S(1) atom. The N(2)-S(1) bond length is 1.61 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(15), and one C(16) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(7,8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9,10) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(23) atom. S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Cd(1) and one C(17) atom. In the second O site, O(4) is bonded in an L-shaped geometry to one Cd(1) and one C(24) atom. In the third O site, O(2) is bonded in a distorted water-like geometry to one Cd(1) and one C(17) atom. In the fourth O site, O(3) is bonded in an L-shaped geometry to one Cd(1) and one C(24) atom. Linkers: 8 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 4 [C]1O[Cd]2(O1)O[C]O[Cd]1(O[C]O1)O[C]O2. RCSR code: sql. The MOF has largest included sphere 5.04 A, density 1.42 g/cm3, surface area 4277.18 m2/g, accessible volume 0.29 cm3/g