(CH)2CdC12H6S2(N3O)2 crystallizes in the triclinic P1 space group. The structure consists of four 02329_fluka molecules inside a CdC12H6S2(N3O)2 framework. In the CdC12H6S2(N3O)2 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted octahedral geometry to one N(1), one N(2), one N(5), one N(6), one S(3), and one S(4) atom. The Cd(1)-N(1) bond length is 2.39 Å. The Cd(1)-N(2) bond length is 2.39 Å. The Cd(1)-N(5) bond length is 2.40 Å. The Cd(1)-N(6) bond length is 2.40 Å. The Cd(1)-S(3) bond length is 2.66 Å. The Cd(1)-S(4) bond length is 2.67 Å. In the second Cd site, Cd(2) is bonded in a distorted octahedral geometry to one N(3), one N(4), one N(7), one N(8), one S(1), and one S(2) atom. The Cd(2)-N(3) bond length is 2.39 Å. The Cd(2)-N(4) bond length is 2.40 Å. The Cd(2)-N(7) bond length is 2.40 Å. The Cd(2)-N(8) bond length is 2.40 Å. The Cd(2)-S(1) bond length is 2.66 Å. The Cd(2)-S(2) bond length is 2.67 Å. There are sixteen inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal planar geometry to one C(5,7); one N(1); and one H(1,3) atom. The C(1,2)-C(5,7) bond length is 1.40 Å. The C(1,2)-N(1) bond length is 1.34 Å. The C(1,2)-H(1,3) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(5,7); one N(3); and one H(1,3) atom. The C(3)-C(5,7) bond length is 1.40 Å. The C(3)-N(3) bond length is 1.34 Å. The C(3)-H(1,3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(8), one N(4), and one H(4) atom. The C(4)-C(8) bond length is 1.40 Å. The C(4)-N(4) bond length is 1.34 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5,7) is bonded in a distorted single-bond geometry to one C(1,2) and one H(5,6,8) atom. The C(5,7)-H(5,6,8) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1,2) and one H(5,6,8) atom. The C(6)-C(1,2) bond length is 1.40 Å. The C(6)-H(5,6,8) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(4) and one H(5,6,8) atom. The C(8)-H(5,6,8) bond length is 1.09 Å. In the seventh C site, C(13,15) is bonded in a distorted single-bond geometry to one C(17,18) and one H(13,14,15,16) atom. The C(13,15)-C(17,18) bond length is 1.40 Å. The C(13,15)-H(13,14,15,16) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(17,18) and one H(13,14,15,16) atom. The C(14)-C(17,18) bond length is 1.40 Å. The C(14)-H(13,14,15,16) bond length is 1.09 Å. In the ninth C site, C(16) is bonded in a distorted single-bond geometry to one C(20) and one H(13,14,15,16) atom. The C(16)-C(20) bond length is 1.40 Å. The C(16)-H(13,14,15,16) bond length is 1.09 Å. In the tenth C site, C(17,18) is bonded in a distorted trigonal planar geometry to one C(13,15); one C(21,23); and one N(1) atom. The C(17,18)-C(21,23) bond length is 1.45 Å. The C(17,18)-N(1) bond length is 1.36 Å. In the eleventh C site, C(19) is bonded in a distorted trigonal planar geometry to one C(13,15); one C(21,23); and one N(3) atom. The C(19)-C(13,15) bond length is 1.40 Å. The C(19)-C(21,23) bond length is 1.45 Å. The C(19)-N(3) bond length is 1.36 Å. In the twelfth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(16), one C(24), and one N(4) atom. The C(20)-C(24) bond length is 1.45 Å. The C(20)-N(4) bond length is 1.36 Å. In the thirteenth C site, C(21,23) is bonded in a distorted water-like geometry to one C(17,18); one N(5); and one O(1) atom. The C(21,23)-N(5) bond length is 1.31 Å. The C(21,23)-O(1) bond length is 1.35 Å. In the fourteenth C site, C(22) is bonded in a distorted water-like geometry to one C(17,18); one N(6); and one O(2) atom. The C(22)-C(17,18) bond length is 1.45 Å. The C(22)-N(6) bond length is 1.31 Å. The C(22)-O(2) bond length is 1.35 Å. In the fifteenth C site, C(24) is bonded in a distorted water-like geometry to one C(20), one N(8), and one O(4) atom. The C(24)-N(8) bond length is 1.31 Å. The C(24)-O(4) bond length is 1.35 Å. In the sixteenth C site, C(25,26,27,28) is bonded in a distorted water-like geometry to one N(10), one S(1), and one O(1) atom. The C(25,26,27,28)-N(10) bond length is 1.33 Å. The C(25,26,27,28)-S(1) bond length is 1.69 Å. The C(25,26,27,28)-O(1) bond length is 1.42 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1); one C(1,2); and one C(17,18) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1); one C(1,2); and one C(17,18) atom. The N(2)-C(1,2) bond length is 1.34 Å. The N(2)-C(17,18) bond length is 1.36 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(2), one C(19), and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(2), one C(20), and one C(4) atom. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one Cd(1); one C(21,23); and one N(10) atom. The N(5)-N(10) bond length is 1.38 Å. In the sixth N site, N(6) is bonded in a 3-coordinate geometry to one Cd(1), one C(22), and one N(9) atom. The N(6)-N(9) bond length is 1.38 Å. In the seventh N site, N(7) is bonded in a 3-coordinate geometry to one Cd(2); one C(21,23); and one N(12) atom. The N(7)-C(21,23) bond length is 1.31 Å. The N(7)-N(12) bond length is 1.38 Å. In the eighth N site, N(8) is bonded in a 3-coordinate geometry to one Cd(2), one C(24), and one N(11) atom. The N(8)-N(11) bond length is 1.38 Å. In the ninth N site, N(9) is bonded in a distorted water-like geometry to one C(25,26,27,28) and one N(6) atom. The N(9)-C(25,26,27,28) bond length is 1.33 Å. In the tenth N site, N(10) is bonded in a distorted water-like geometry to one C(25,26,27,28) and one N(5) atom. In the eleventh N site, N(11) is bonded in a distorted water-like geometry to one C(25,26,27,28) and one N(8) atom. The N(11)-C(25,26,27,28) bond length is 1.33 Å. In the twelfth N site, N(12) is bonded in a distorted water-like geometry to one C(25,26,27,28) and one N(7) atom. The N(12)-C(25,26,27,28) bond length is 1.33 Å. There are six inequivalent H sites. In the first H site, H(1,3) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1,2) atom. The H(2)-C(1,2) bond length is 1.09 Å. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5,6,8) is bonded in a single-bond geometry to one C(5,7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(5,7) atom. The H(7)-C(5,7) bond length is 1.09 Å. In the sixth H site, H(13,14,15,16) is bonded in a single-bond geometry to one C(13,15) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Cd(2) and one C(25,26,27,28) atom. In the second S site, S(2) is bonded in a water-like geometry to one Cd(2) and one C(25,26,27,28) atom. The S(2)-C(25,26,27,28) bond length is 1.69 Å. In the third S site, S(3) is bonded in a water-like geometry to one Cd(1) and one C(25,26,27,28) atom. The S(3)-C(25,26,27,28) bond length is 1.69 Å. In the fourth S site, S(4) is bonded in a water-like geometry to one Cd(1) and one C(25,26,27,28) atom. The S(4)-C(25,26,27,28) bond length is 1.69 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(21,23) and one C(25,26,27,28) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(22) and one C(25,26,27,28) atom. The O(2)-C(25,26,27,28) bond length is 1.42 Å. In the third O site, O(3) is bonded in a water-like geometry to one C(21,23) and one C(25,26,27,28) atom. The O(3)-C(21,23) bond length is 1.35 Å. The O(3)-C(25,26,27,28) bond length is 1.42 Å. In the fourth O site, O(4) is bonded in a water-like geometry to one C(24) and one C(25,26,27,28) atom. The O(4)-C(25,26,27,28) bond length is 1.42 Å. Linkers: 4 S=C1[N]N=C(c2ccccn2)O1. Metal clusters: 2 [S][Cd][S]. The MOF has largest included sphere 2.22 A, density 2.02 g/cm3, surface area 3726.65 m2/g, accessible volume 0.05 cm3/g