(FeAg2C16N8H8O)2(C3H2)5(CH)10C5H4 crystallizes in the triclinic P-1 space group. The structure consists of twenty 02329_fluka molecules; five 2,3-dimethyl-1,3-butadiene molecules; and one naphthalene molecule inside a FeAg2C16N8H8O framework. In each FeAg2C16N8H8O framework, there are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in an octahedral geometry to one N(1), one N(16), one N(2), one N(3), one N(4), and one N(5) atom. The Fe(1)-N(1) bond length is 1.88 Å. The Fe(1)-N(16) bond length is 1.97 Å. The Fe(1)-N(2) bond length is 1.89 Å. The Fe(1)-N(3) bond length is 1.88 Å. The Fe(1)-N(4) bond length is 1.88 Å. The Fe(1)-N(5) bond length is 1.97 Å. In the second Fe site, Fe(2) is bonded in an octahedral geometry to one N(10), one N(11), one N(12), one N(13), one N(8), and one N(9) atom. The Fe(2)-N(10) bond length is 2.10 Å. The Fe(2)-N(11) bond length is 2.13 Å. The Fe(2)-N(12) bond length is 2.10 Å. The Fe(2)-N(13) bond length is 2.15 Å. The Fe(2)-N(8) bond length is 2.15 Å. The Fe(2)-N(9) bond length is 2.13 Å. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one C(1) and one C(20) atom. The Ag(1)-C(1) bond length is 2.02 Å. The Ag(1)-C(20) bond length is 2.02 Å. In the second Ag site, Ag(2) is bonded in a linear geometry to one C(19) and one C(2) atom. The Ag(2)-C(19) bond length is 2.03 Å. The Ag(2)-C(2) bond length is 2.03 Å. In the third Ag site, Ag(3) is bonded in a linear geometry to one C(18) and one C(3) atom. The Ag(3)-C(18) bond length is 2.02 Å. The Ag(3)-C(3) bond length is 2.02 Å. In the fourth Ag site, Ag(4) is bonded in a linear geometry to one C(17) and one C(4) atom. The Ag(4)-C(17) bond length is 2.03 Å. The Ag(4)-C(4) bond length is 2.03 Å. There are thirty-two inequivalent C sites. In the first C site, C(19) is bonded in a linear geometry to one Ag(2) and one N(11) atom. The C(19)-N(11) bond length is 1.17 Å. In the second C site, C(20) is bonded in a linear geometry to one Ag(1) and one N(12) atom. The C(20)-N(12) bond length is 1.17 Å. In the third C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one N(13), and one H(9) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-N(13) bond length is 1.35 Å. The C(21)-H(9) bond length is 1.09 Å. In the fourth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(10) atom. The C(22)-C(23) bond length is 1.41 Å. The C(22)-H(10) bond length is 1.09 Å. In the fifth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(26) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(26) bond length is 1.44 Å. In the sixth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(11) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(11) bond length is 1.09 Å. In the seventh C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one N(13), and one H(12) atom. The C(25)-N(13) bond length is 1.35 Å. The C(25)-H(12) bond length is 1.09 Å. In the eighth C site, C(26) is bonded in a distorted water-like geometry to one C(23), one N(14), and one O(2) atom. The C(26)-N(14) bond length is 1.31 Å. The C(26)-O(2) bond length is 1.37 Å. In the ninth C site, C(27) is bonded in a distorted water-like geometry to one C(28), one N(15), and one O(2) atom. The C(27)-C(28) bond length is 1.44 Å. The C(27)-N(15) bond length is 1.32 Å. The C(27)-O(2) bond length is 1.37 Å. In the tenth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(32) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-C(32) bond length is 1.40 Å. In the eleventh C site, C(29) is bonded in a distorted single-bond geometry to one C(28), one C(30), and one H(13) atom. The C(29)-C(30) bond length is 1.38 Å. The C(29)-H(13) bond length is 1.08 Å. In the twelfth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one N(16), and one H(14) atom. The C(30)-N(16) bond length is 1.35 Å. The C(30)-H(14) bond length is 1.08 Å. In the thirteenth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(32), one N(16), and one H(15) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-N(16) bond length is 1.35 Å. The C(31)-H(15) bond length is 1.09 Å. In the fourteenth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(28), one C(31), and one H(16) atom. The C(32)-H(16) bond length is 1.09 Å. In the fifteenth C site, C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. In the sixteenth C site, C(2) is bonded in a linear geometry to one Ag(2) and one N(2) atom. The C(2)-N(2) bond length is 1.17 Å. In the seventeenth C site, C(3) is bonded in a linear geometry to one Ag(3) and one N(3) atom. The C(3)-N(3) bond length is 1.17 Å. In the eighteenth C site, C(4) is bonded in a linear geometry to one Ag(4) and one N(4) atom. The C(4)-N(4) bond length is 1.17 Å. In the nineteenth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(5), and one H(1) atom. The C(5)-C(6) bond length is 1.38 Å. The C(5)-N(5) bond length is 1.35 Å. The C(5)-H(1) bond length is 1.09 Å. In the twentieth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(2) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(2) bond length is 1.09 Å. In the twenty-first C site, C(7) is bonded in a trigonal planar geometry to one C(10), one C(6), and one C(8) atom. The C(7)-C(10) bond length is 1.44 Å. The C(7)-C(8) bond length is 1.40 Å. In the twenty-second C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(3) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(3) bond length is 1.09 Å. In the twenty-third C site, C(9) is bonded in a distorted trigonal planar geometry to one C(8), one N(5), and one H(4) atom. The C(9)-N(5) bond length is 1.35 Å. The C(9)-H(4) bond length is 1.09 Å. In the twenty-fourth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(6), and one O(1) atom. The C(10)-N(6) bond length is 1.31 Å. The C(10)-O(1) bond length is 1.37 Å. In the twenty-fifth C site, C(11) is bonded in a distorted water-like geometry to one C(12), one N(7), and one O(1) atom. The C(11)-C(12) bond length is 1.44 Å. The C(11)-N(7) bond length is 1.32 Å. The C(11)-O(1) bond length is 1.37 Å. In the twenty-sixth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(16) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(16) bond length is 1.40 Å. In the twenty-seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(5) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-H(5) bond length is 1.08 Å. In the twenty-eighth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(8), and one H(6) atom. The C(14)-N(8) bond length is 1.35 Å. The C(14)-H(6) bond length is 1.09 Å. In the twenty-ninth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one N(8), and one H(7) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-N(8) bond length is 1.35 Å. The C(15)-H(7) bond length is 1.09 Å. In the thirtieth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(12), one C(15), and one H(8) atom. The C(16)-H(8) bond length is 1.09 Å. In the thirty-first C site, C(17) is bonded in a linear geometry to one Ag(4) and one N(9) atom. The C(17)-N(9) bond length is 1.17 Å. In the thirty-second C site, C(18) is bonded in a linear geometry to one Ag(3) and one N(10) atom. The C(18)-N(10) bond length is 1.17 Å. There are sixteen inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Fe(1) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Fe(1) and one C(2) atom. In the third N site, N(3) is bonded in a linear geometry to one Fe(1) and one C(3) atom. In the fourth N site, N(4) is bonded in a linear geometry to one Fe(1) and one C(4) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Fe(1), one C(5), and one C(9) atom. In the sixth N site, N(6) is bonded in a distorted water-like geometry to one C(10) and one N(7) atom. The N(6)-N(7) bond length is 1.37 Å. In the seventh N site, N(7) is bonded in a distorted water-like geometry to one C(11) and one N(6) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Fe(2), one C(14), and one C(15) atom. In the ninth N site, N(9) is bonded in a linear geometry to one Fe(2) and one C(17) atom. In the tenth N site, N(10) is bonded in a linear geometry to one Fe(2) and one C(18) atom. In the eleventh N site, N(11) is bonded in a linear geometry to one Fe(2) and one C(19) atom. In the twelfth N site, N(12) is bonded in a linear geometry to one Fe(2) and one C(20) atom. In the thirteenth N site, N(13) is bonded in a trigonal planar geometry to one Fe(2), one C(21), and one C(25) atom. In the fourteenth N site, N(14) is bonded in a distorted water-like geometry to one C(26) and one N(15) atom. The N(14)-N(15) bond length is 1.37 Å. In the fifteenth N site, N(15) is bonded in a distorted water-like geometry to one C(27) and one N(14) atom. In the sixteenth N site, N(16) is bonded in a trigonal planar geometry to one Fe(1), one C(30), and one C(31) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(24) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(29) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(30) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(31) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(32) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(10) and one C(11) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(26) and one C(27) atom. Linkers: 4 c1cc(-c2nnc(-c3ccncc3)o2)ccn1. Metal clusters: 4 [Fe]. The MOF has largest included sphere 2.77 A, density 1.75 g/cm3, surface area 4008.64 m2/g, accessible volume 0.17 cm3/g