MnC28H28S2(N3O)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two MnC28H28S2(N3O)2 clusters. Mn(1) is bonded to two equivalent N(1), two equivalent N(2), and two equivalent O(1) atoms to form MnN4O2 octahedra that share corners with two equivalent C(8)H3O tetrahedra. Both Mn(1)-N(1) bond lengths are 2.12 Å. Both Mn(1)-N(2) bond lengths are 2.24 Å. Both Mn(1)-O(1) bond lengths are 2.20 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(1)-C(4) bond length is 1.45 Å. The C(1)-H(6) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(5), one N(2), and one H(3) atom. The C(2)-C(5) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4), one C(7), and one H(4) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(7) bond length is 1.38 Å. The C(3)-H(4) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(5) atom. The C(4)-C(5) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(2) atom. The C(5)-H(2) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(6)-N(1) bond length is 1.19 Å. The C(6)-S(1) bond length is 1.62 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one H(5) atom. The C(7)-N(2) bond length is 1.35 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded to one H(7), one H(8), one H(9), and one O(1) atom to form CH3O tetrahedra that share  a cornercorner with one Mn(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 54°. The C(8)-H(7) bond length is 1.10 Å. The C(8)-H(8) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. The C(8)-O(1) bond length is 1.43 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(11) and one H(14) atom. The C(9)-C(11) bond length is 1.45 Å. The C(9)-H(14) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one H(10) atom. The C(10)-C(14) bond length is 1.39 Å. The C(10)-N(3) bond length is 1.34 Å. The C(10)-H(10) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(9) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-C(14) bond length is 1.41 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(11) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(11) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one N(3), and one H(12) atom. The C(13)-N(3) bond length is 1.35 Å. The C(13)-H(12) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(10), one C(11), and one H(13) atom. The C(14)-H(13) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted linear geometry to one Mn(1) and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(1), one C(2), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(13), and one H(1) atom. The N(3)-H(1) bond length is 1.58 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one N(3) and one O(1) atom. The H(1)-O(1) bond length is 1.04 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(9) atom. S(1) is bonded in a single-bond geometry to one C(6) atom. O(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(8), and one H(1) atom. Linkers: 2 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 2 [Mn]. The MOF has largest included sphere 2.56 A, density 1.35 g/cm3, surface area 5434.89 m2/g, accessible volume 0.20 cm3/g