AgH3(CN)3CH3 crystallizes in the monoclinic P2_1/c space group. The structure consists of sixteen 02329_fluka molecules inside a AgH3(CN)3 framework. In the AgH3(CN)3 framework, there are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a trigonal planar geometry to one N(11), one N(2), and one N(3) atom. The Ag(1)-N(11) bond length is 2.27 Å. The Ag(1)-N(2) bond length is 2.16 Å. The Ag(1)-N(3) bond length is 2.24 Å. In the second Ag site, Ag(2) is bonded in a distorted trigonal planar geometry to one N(1), one N(12), and one N(4) atom. The Ag(2)-N(1) bond length is 2.31 Å. The Ag(2)-N(12) bond length is 2.16 Å. The Ag(2)-N(4) bond length is 2.19 Å. In the third Ag site, Ag(3) is bonded in a trigonal planar geometry to one N(5), one N(8), and one N(9) atom. The Ag(3)-N(5) bond length is 2.28 Å. The Ag(3)-N(8) bond length is 2.16 Å. The Ag(3)-N(9) bond length is 2.23 Å. In the fourth Ag site, Ag(4) is bonded in a distorted trigonal planar geometry to one N(10), one N(6), and one N(7) atom. The Ag(4)-N(10) bond length is 2.18 Å. The Ag(4)-N(6) bond length is 2.16 Å. The Ag(4)-N(7) bond length is 2.31 Å. There are twelve inequivalent C sites. In the first C site, C(5) is bonded in a distorted trigonal planar geometry to one C(7), one N(4), and one N(6) atom. The C(5)-C(7) bond length is 1.49 Å. The C(5)-N(4) bond length is 1.34 Å. The C(5)-N(6) bond length is 1.36 Å. In the second C site, C(6) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(7) atom. The C(6)-N(5) bond length is 1.33 Å. The C(6)-N(6) bond length is 1.36 Å. The C(6)-H(7) bond length is 1.09 Å. In the third C site, C(7) is bonded in a distorted water-like geometry to one C(5), one H(8), and one H(9) atom. The C(7)-H(8) bond length is 1.10 Å. The C(7)-H(9) bond length is 1.10 Å. In the fourth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(11), one N(7), and one N(9) atom. The C(9)-C(11) bond length is 1.49 Å. The C(9)-N(7) bond length is 1.34 Å. The C(9)-N(9) bond length is 1.36 Å. In the fifth C site, C(10) is bonded in a trigonal planar geometry to one N(8), one N(9), and one H(13) atom. The C(10)-N(8) bond length is 1.34 Å. The C(10)-N(9) bond length is 1.35 Å. The C(10)-H(13) bond length is 1.09 Å. In the sixth C site, C(11) is bonded in a distorted water-like geometry to one C(9), one H(14), and one H(15) atom. The C(11)-H(14) bond length is 1.10 Å. The C(11)-H(15) bond length is 1.10 Å. In the seventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(15), one N(10), and one N(12) atom. The C(13)-C(15) bond length is 1.49 Å. The C(13)-N(10) bond length is 1.34 Å. The C(13)-N(12) bond length is 1.36 Å. In the eighth C site, C(14) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(19) atom. The C(14)-N(11) bond length is 1.33 Å. The C(14)-N(12) bond length is 1.36 Å. The C(14)-H(19) bond length is 1.09 Å. In the ninth C site, C(15) is bonded in a distorted water-like geometry to one C(13), one H(20), and one H(21) atom. The C(15)-H(20) bond length is 1.10 Å. The C(15)-H(21) bond length is 1.10 Å. In the tenth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one N(3) atom. The C(1)-C(3) bond length is 1.49 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(3) bond length is 1.36 Å. In the eleventh C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(1) atom. The C(2)-N(2) bond length is 1.34 Å. The C(2)-N(3) bond length is 1.35 Å. The C(2)-H(1) bond length is 1.09 Å. In the twelfth C site, C(3) is bonded in a distorted water-like geometry to one C(1), one H(2), and one H(3) atom. The C(3)-H(2) bond length is 1.10 Å. The C(3)-H(3) bond length is 1.10 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.38 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(2), and one N(1) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(5), and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one Ag(3), one C(6), and one N(4) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Ag(4), one C(5), and one C(6) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Ag(4), one C(9), and one N(8) atom. The N(7)-N(8) bond length is 1.38 Å. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Ag(3), one C(10), and one N(7) atom. In the ninth N site, N(9) is bonded in a distorted trigonal planar geometry to one Ag(3), one C(10), and one C(9) atom. In the tenth N site, N(10) is bonded in a distorted trigonal planar geometry to one Ag(4), one C(13), and one N(11) atom. The N(10)-N(11) bond length is 1.37 Å. In the eleventh N site, N(11) is bonded in a 3-coordinate geometry to one Ag(1), one C(14), and one N(10) atom. In the twelfth N site, N(12) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(13), and one C(14) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(15) atom. Linkers: 10 CCC1=NN=C[N]1 ,2 CCC1=N[N]C=N1 ,4 CCC1=[N]=CN=N1. Metal clusters: 4 [N]1[N][Ag]2N=N[Ag]N=N[Ag]2N=N[Ag]1. The MOF has largest included sphere 4.20 A, density 2.03 g/cm3, surface area 3494.51 m2/g, accessible volume 0.19 cm3/g