CuC10N5H15S2Cl is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CuC10N5H15S2Cl clusters. Cu(1) is bonded in a tetrahedral geometry to one N(4), one S(1), one S(2), and one Cl(1) atom. The Cu(1)-N(4) bond length is 2.01 Å. The Cu(1)-S(1) bond length is 2.31 Å. The Cu(1)-S(2) bond length is 2.31 Å. The Cu(1)-Cl(1) bond length is 2.30 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one N(5) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(2) bond length is 1.35 Å. The C(2)-N(5) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(4) atom. The C(3)-C(4) bond length is 1.42 Å. The C(3)-N(4) bond length is 1.39 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one N(3) atom. The C(4)-N(1) bond length is 1.36 Å. The C(4)-N(3) bond length is 1.34 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(4) atom. The C(5)-N(4) bond length is 1.33 Å. The C(5)-N(5) bond length is 1.37 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(5), one H(5), and one H(6) atom. The C(6)-N(5) bond length is 1.46 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted water-like geometry to one H(7), one H(8), and one S(1) atom. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.10 Å. The C(7)-S(1) bond length is 1.81 Å. In the eighth C site, C(8) is bonded in a distorted water-like geometry to one H(10), one H(9), and one S(1) atom. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. The C(8)-S(1) bond length is 1.81 Å. In the ninth C site, C(9) is bonded in a distorted water-like geometry to one H(11), one H(12), and one S(2) atom. The C(9)-H(11) bond length is 1.10 Å. The C(9)-H(12) bond length is 1.10 Å. The C(9)-S(2) bond length is 1.81 Å. In the tenth C site, C(10) is bonded in a trigonal non-coplanar geometry to one H(13), one H(14), one H(15), and one S(2) atom. The C(10)-H(13) bond length is 1.10 Å. The C(10)-H(14) bond length is 1.09 Å. The C(10)-H(15) bond length is 1.10 Å. The C(10)-S(2) bond length is 1.81 Å. There are five inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(6) atom. In the second N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(4) atom. In the third N site, N(2) is bonded in a water-like geometry to one C(1) and one C(2) atom. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one C(4), one H(2), and one H(3) atom. The N(3)-H(2) bond length is 1.02 Å. The N(3)-H(3) bond length is 1.03 Å. In the fifth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(3), and one C(5) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(7), and one C(8) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(10), and one C(9) atom. Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 3 CSCCSCCn1cnc2c1[N]C=N[C]2N. Metal clusters: 4 [Cu]. The MOF has largest included sphere 1.99 A, density 1.77 g/cm3, surface area 4416.44 m2/g, accessible volume 0.14 cm3/g