CoH16(C8N5)2(CH)8(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two isobutylene molecules, and one CoH16(C8N5)2 cluster. In the CoH16(C8N5)2 cluster, Co(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(4), and two equivalent N(5) atoms. Both Co(1)-N(1) bond lengths are 2.28 Å. Both Co(1)-N(4) bond lengths are 1.97 Å. Both Co(1)-N(5) bond lengths are 1.97 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(1) atom. The C(1)-N(4) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(2) atom. The C(2)-N(5) bond length is 1.36 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(7) atom. The C(5)-C(11) bond length is 1.50 Å. The C(5)-C(7) bond length is 1.40 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one H(5) atom. The C(7)-C(9) bond length is 1.39 Å. The C(7)-H(5) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(4), and one H(7) atom. The C(9)-N(4) bond length is 1.35 Å. The C(9)-H(7) bond length is 1.08 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(8) atom. The C(10)-N(5) bond length is 1.35 Å. The C(10)-H(8) bond length is 1.08 Å. In the eighth C site, C(11) is bonded in a distorted water-like geometry to one C(5), one H(11), and one H(9) atom. The C(11)-H(11) bond length is 1.10 Å. The C(11)-H(9) bond length is 1.10 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Co(1) and one N(2) atom. The N(1)-N(2) bond length is 1.20 Å. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.18 Å. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(9) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(1), one C(10), and one C(2) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. Linkers: 2 c1cc(CCCc2ccncc2)ccn1. Metal clusters: 1 [Co]. The MOF has largest included sphere 2.73 A, density 1.37 g/cm3, surface area 4753.52 m2/g, accessible volume 0.17 cm3/g