CuC8NH10O3(CH2)2CH3CH3O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 02329_fluka molecules, two methanol molecules, and one CuC8NH10O3 cluster. In the CuC8NH10O3 cluster, Cu(1) is bonded in a 4-coordinate geometry to one N(1), one O(3), and two equivalent O(1) atoms. The Cu(1)-N(1) bond length is 2.08 Å. The Cu(1)-O(3) bond length is 1.93 Å. There is one shorter (1.93 Å) and one longer (1.95 Å) Cu(1)-O(1) bond length. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(2), one H(3), and one O(1) atom. The C(1)-H(2) bond length is 1.11 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-O(1) bond length is 1.41 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(4), and one H(5) atom. The C(2)-N(1) bond length is 1.50 Å. The C(2)-H(4) bond length is 1.10 Å. The C(2)-H(5) bond length is 1.10 Å. In the third C site, C(4) is bonded in a 3-coordinate geometry to one N(1), one H(8), and one H(9) atom. The C(4)-N(1) bond length is 1.49 Å. The C(4)-H(8) bond length is 1.10 Å. The C(4)-H(9) bond length is 1.10 Å. In the fourth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(10), and one H(11) atom. The C(5)-N(1) bond length is 1.48 Å. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(11) bond length is 1.10 Å. In the fifth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(4) atom. The C(9)-C(10) bond length is 1.51 Å. The C(9)-O(3) bond length is 1.30 Å. The C(9)-O(4) bond length is 1.25 Å. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(12) bond length is 1.40 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(19) atom. The C(11)-H(19) bond length is 1.09 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one H(20) atom. The C(12)-H(20) bond length is 1.09 Å. N(1) is bonded in a tetrahedral geometry to one Cu(1), one C(2), one C(4), and one C(5) atom. There are ten inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(12) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Cu(1) and one C(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(9) atom. In the third O site, O(4) is bonded in a single-bond geometry to one C(9) atom. Linkers: 1 [O]C(=O)c1ccc(C([O])=O)cc1 ,2 CCCCN(CC[O])CCO. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.61 A, density 1.45 g/cm3, surface area 5267.88 m2/g, accessible volume 0.19 cm3/g