PbC14H8(N2S)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four PbC14H8(N2S)2 clusters. Pb(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Pb(1)-N(1) bond lengths are 2.65 Å. Both Pb(1)-N(2) bond lengths are 2.55 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.19 Å. The C(1)-S(1) bond length is 1.63 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one H(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(2) bond length is 1.33 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.42 Å. The C(5)-C(7) bond length is 1.43 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(6), and one N(2) atom. The C(6)-C(6) bond length is 1.44 Å. The C(6)-N(2) bond length is 1.36 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one Pb(1) and one C(1) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one Pb(1), one C(2), and one C(6) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. Linkers: 4 N#C[S]. Metal clusters: 2 [Pb]. The MOF has largest included sphere 2.41 A, density 2.33 g/cm3, surface area 2849.87 m2/g, accessible volume 0.05 cm3/g