MgC14H20S2(NO5)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two MgC14H20S2(NO5)2 clusters. Mg(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. Both Mg(1)-O(1) bond lengths are 2.11 Å. Both Mg(1)-O(3) bond lengths are 2.08 Å. Both Mg(1)-O(4) bond lengths are 2.09 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(3), one C(5), and one S(1) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-C(5) bond length is 1.42 Å. The C(1)-S(1) bond length is 1.78 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(4), and one N(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.40 Å. The C(2)-N(1) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(2), and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.46 Å. The C(5)-C(7) bond length is 1.41 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. N(1) is bonded in a 2-coordinate geometry to one C(2), one H(2), and one H(3) atom. The N(1)-H(2) bond length is 1.02 Å. The N(1)-H(3) bond length is 1.03 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(3) atom. The H(7)-O(3) bond length is 0.98 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(3) atom. The H(8)-O(3) bond length is 1.02 Å. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(4) atom. The H(9)-O(4) bond length is 0.99 Å. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(4) atom. The H(10)-O(4) bond length is 0.99 Å. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(2), and one O(5) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(5) bond length is 1.48 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one H(7), and one H(8) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one H(10), and one H(9) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(1) atom. Linkers: 2 Nc1ccc(/C=C/c2ccc(N)cc2S([O])([O])[O])c(S([O])([O])[O])c1 ,2 [C]/C(=C([CH])/C=C/c1ccc(N)cc1S([O])([O])[O])S([O])([O])[O]. Metal clusters: 2 O.O.O.O.O=S(=O)=O.O=S(=O)=O.[Mg]. The MOF has largest included sphere 2.23 A, density 1.65 g/cm3, surface area 4273.08 m2/g, accessible volume 0.12 cm3/g