ZnC8H8(N4S)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ZnC8H8(N4S)2 clusters. Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(13), one N(15), and one N(9) atom. The Zn(1)-N(1) bond length is 2.02 Å. The Zn(1)-N(13) bond length is 1.92 Å. The Zn(1)-N(15) bond length is 1.94 Å. The Zn(1)-N(9) bond length is 2.02 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(5), and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-N(5) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one N(3), one N(5), and one H(3) atom. The C(3)-N(3) bond length is 1.32 Å. The C(3)-N(5) bond length is 1.37 Å. The C(3)-H(3) bond length is 1.08 Å. In the third C site, C(5,6) is bonded in a distorted trigonal non-coplanar geometry to one N(5); one H(5,6); and one H(7,8) atom. The C(5,6)-N(5) bond length is 1.46 Å. The C(5,6)-H(5,6) bond length is 1.10 Å. The C(5,6)-H(7,8) bond length is 1.10 Å. In the fourth C site, C(7,8) is bonded in a 3-coordinate geometry to one N(7); one H(11,12); and one H(9,10) atom. The C(7,8)-N(7) bond length is 1.46 Å. The C(7,8)-H(11,12) bond length is 1.10 Å. The C(7,8)-H(9,10) bond length is 1.10 Å. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(13) atom. The C(9)-N(7) bond length is 1.36 Å. The C(9)-N(9) bond length is 1.32 Å. The C(9)-H(13) bond length is 1.09 Å. In the sixth C site, C(11) is bonded in a trigonal planar geometry to one N(11), one N(7), and one H(15) atom. The C(11)-N(11) bond length is 1.32 Å. The C(11)-N(7) bond length is 1.37 Å. The C(11)-H(15) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a distorted linear geometry to one N(13) and one S(1,2) atom. The C(13)-N(13) bond length is 1.19 Å. The C(13)-S(1,2) bond length is 1.61 Å. In the eighth C site, C(15) is bonded in a distorted linear geometry to one N(15) and one S(3) atom. The C(15)-N(15) bond length is 1.19 Å. The C(15)-S(3) bond length is 1.61 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(1), and one N(3) atom. The N(1)-N(3) bond length is 1.38 Å. In the second N site, N(3) is bonded in a distorted single-bond geometry to one C(3) and one N(1) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one C(1); one C(3); and one C(5,6) atom. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one C(11); one C(7,8); and one C(9) atom. In the fifth N site, N(9) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(9), and one N(11) atom. The N(9)-N(11) bond length is 1.38 Å. In the sixth N site, N(11) is bonded in a distorted water-like geometry to one C(11) and one N(9) atom. In the seventh N site, N(13) is bonded in a linear geometry to one Zn(1) and one C(13) atom. In the eighth N site, N(15) is bonded in a linear geometry to one Zn(1) and one C(15) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(5,6) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(5,6) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(7,8) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(7,8) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent S sites. In the first S site, S(1,2) is bonded in a single-bond geometry to one C(13) atom. In the second S site, S(3) is bonded in a single-bond geometry to one C(15) atom. Linkers: 4 c1nncn1CCn1cnnc1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 2.23 A, density 1.73 g/cm3, surface area 4667.09 m2/g, accessible volume 0.11 cm3/g