CuC6N2H12OCl is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CuC6N2H12OCl cluster. Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one O(1), and one Cl(1) atom. The Cu(1)-N(1) bond length is 1.99 Å. The Cu(1)-N(2) bond length is 1.97 Å. The Cu(1)-O(1) bond length is 2.02 Å. The Cu(1)-Cl(1) bond length is 2.25 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(1) atom. The C(1)-N(2) bond length is 1.31 Å. The C(1)-O(1) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one N(1), one H(3), and one H(4) atom. The C(2)-C(3) bond length is 1.54 Å. The C(2)-N(1) bond length is 1.47 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. In the third C site, C(3) is bonded to one C(2), one C(4), one C(5), and one C(6) atom to form CC4 tetrahedra that share  a cornercorner with one N(1)CuH2C tetrahedra. The C(3)-C(4) bond length is 1.53 Å. The C(3)-C(5) bond length is 1.53 Å. The C(3)-C(6) bond length is 1.54 Å. In the fourth C site, C(4) is bonded in a trigonal non-coplanar geometry to one C(3), one H(5), one H(6), and one H(7) atom. The C(4)-H(5) bond length is 1.10 Å. The C(4)-H(6) bond length is 1.10 Å. The C(4)-H(7) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one H(10), one H(8), and one H(9) atom. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(8) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one N(2), one H(11), and one H(12) atom. The C(6)-N(2) bond length is 1.46 Å. The C(6)-H(11) bond length is 1.10 Å. The C(6)-H(12) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Cu(1), one C(2), one H(1), and one H(2) atom to form distorted NCuH2C tetrahedra that share  a cornercorner with one C(3)C4 tetrahedra. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.03 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(6) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. O(1) is bonded in a water-like geometry to one Cu(1) and one C(1) atom. Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 1 CC(C)(CN)C[N]C(=O)C(=O)[N]CC(C)(C)CN ,2 [CH]C(C)(CN)C[N]C(=O)C(=O)[N]CC(C)(C)CN ,2 CC(C)(C[NH])C[N]C(=O)C(=O)[N]CC(C)(C)CN. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.52 A, density 1.74 g/cm3, surface area 4508.39 m2/g, accessible volume 0.15 cm3/g