ZnC6N2H7O5(CH)2CH2CH2COC4H4O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; two 02329_fluka molecules; two 1-propene, 1-methoxy-, (1z)- molecules; two dimethyl ether molecules; and one ZnC6N2H7O5 cluster. In the ZnC6N2H7O5 cluster, Zn(1) is bonded in a 4-coordinate geometry to one N(1), one O(1), one O(3), and one O(6) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 1.99 Å. The Zn(1)-O(3) bond length is 2.09 Å. The Zn(1)-O(6) bond length is 2.00 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.31 Å. The C(1)-O(2) bond length is 1.24 Å. In the second C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(1), and one H(9) atom. The C(10)-C(11) bond length is 1.37 Å. The C(10)-N(1) bond length is 1.38 Å. The C(10)-H(9) bond length is 1.08 Å. In the third C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(10) atom. The C(11)-N(2) bond length is 1.38 Å. The C(11)-H(10) bond length is 1.08 Å. In the fourth C site, C(12) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(11) atom. The C(12)-N(1) bond length is 1.34 Å. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(11) bond length is 1.09 Å. In the fifth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(12), and one H(13) atom. The C(13)-N(2) bond length is 1.46 Å. The C(13)-H(12) bond length is 1.09 Å. The C(13)-H(13) bond length is 1.10 Å. In the sixth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(15)-O(6) bond length is 1.29 Å. The C(15)-O(7) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(12) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(13) atom. There are seven inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(16) is bonded in a linear geometry to one O(1) and one O(3) atom. The H(16)-O(1) bond length is 1.58 Å. The H(16)-O(3) bond length is 1.02 Å. In the seventh H site, H(17) is bonded in a single-bond geometry to one O(3) atom. The H(17)-O(3) bond length is 0.97 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one H(16) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Zn(1), one H(16), and one H(17) atom. In the fourth O site, O(6) is bonded in a water-like geometry to one Zn(1) and one C(15) atom. In the fifth O site, O(7) is bonded in a single-bond geometry to one C(15) atom. Linkers: 2 [O]C(=O)COc1ccc(OCC([O])=O)cc1 ,1 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 2 O.O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.24 A, density 1.62 g/cm3, surface area 4513.00 m2/g, accessible volume 0.14 cm3/g