AgC17H14(NO2)2(CH)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and two AgC17H14(NO2)2 clusters. In each AgC17H14(NO2)2 cluster, Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Ag(1)-N(1) bond length is 2.20 Å. The Ag(1)-N(2) bond length is 2.20 Å. The Ag(1)-O(1) bond length is 2.65 Å. The Ag(1)-O(2) bond length is 2.61 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.50 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one H(5), one H(6), and one O(3) atom. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. The C(6)-O(3) bond length is 1.42 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one O(3) atom. The C(7)-O(3) bond length is 1.37 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(7) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(7) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(8) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one O(4) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-O(4) bond length is 1.38 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(9) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(9) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(10) atom. The C(12)-H(10) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one C(14), one H(11), one H(12), and one O(4) atom. The C(13)-C(14) bond length is 1.50 Å. The C(13)-H(11) bond length is 1.11 Å. The C(13)-H(12) bond length is 1.10 Å. The C(13)-O(4) bond length is 1.44 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(16) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(16) bond length is 1.40 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(2), and one H(13) atom. The C(15)-N(2) bond length is 1.35 Å. The C(15)-H(13) bond length is 1.09 Å. In the fifteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(14) and one H(14) atom. The C(16)-H(14) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(16) atom. The C(18)-N(2) bond length is 1.35 Å. The C(18)-H(16) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(19)-O(1) bond length is 1.27 Å. The C(19)-O(2) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(15), and one C(18) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ag(1) and one C(19) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Ag(1) and one C(19) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(6) and one C(7) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(10) and one C(13) atom. Linkers: 1 [O]C(=O)/C=C/C([O])=O. Metal clusters: 1 [Ag][Ag].[O][C]=O.[O][C]=O. The MOF has largest included sphere 3.02 A, density 1.69 g/cm3, surface area 4097.49 m2/g, accessible volume 0.12 cm3/g