AgC15H14(NO)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one AgC15H14(NO)2 cluster. Ag(1) is bonded in a linear geometry to one N(2) and one O(2) atom. The Ag(1)-N(2) bond length is 2.08 Å. The Ag(1)-O(2) bond length is 2.09 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one N(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(4) bond length is 1.49 Å. The C(1)-N(1) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(1) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(5), and one N(2) atom. The C(3)-C(5) bond length is 1.49 Å. The C(3)-N(2) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one H(2), one H(3), and one H(4) atom. The C(4)-H(2) bond length is 1.10 Å. The C(4)-H(3) bond length is 1.09 Å. The C(4)-H(4) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one H(5), one H(6), and one H(7) atom. The C(5)-H(5) bond length is 1.10 Å. The C(5)-H(6) bond length is 1.10 Å. The C(5)-H(7) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(7), one N(1), one H(8), and one H(9) atom. The C(6)-C(7) bond length is 1.51 Å. The C(6)-N(1) bond length is 1.45 Å. The C(6)-H(8) bond length is 1.10 Å. The C(6)-H(9) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-C(9) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(10) atom. The C(8)-H(10) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(7) and one H(11) atom. The C(9)-H(11) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(15) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-C(14) bond length is 1.38 Å. The C(10)-C(15) bond length is 1.50 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(12) atom. The C(11)-H(12) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(13) atom. The C(12)-C(13) bond length is 1.42 Å. The C(12)-H(13) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(14) atom. The C(13)-C(13) bond length is 1.44 Å. The C(13)-C(14) bond length is 1.41 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(10), one C(13), and one H(14) atom. The C(14)-H(14) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(1), and one O(2) atom. The C(15)-O(1) bond length is 1.25 Å. The C(15)-O(2) bond length is 1.30 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(1), one C(6), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(3), and one N(1) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(15) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one C(15) atom. Linkers: 1 Cc1cc(C)n(Cc2ccc(Cn3nc(C)cc3C)cc2)n1 ,1 [O]C(=O)c1ccc2cc(C([O])=O)ccc2c1. Metal clusters: 2 O=[C]O[Ag]. The MOF has largest included sphere 2.00 A, density 1.77 g/cm3, surface area 4076.09 m2/g, accessible volume 0.11 cm3/g