InC16H15(NO2)4 crystallizes in the monoclinic Cc space group. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 7-coordinate geometry to one N(1), one N(4), one O(13), one O(16), one O(22), one O(6), and one O(8) atom. The In(1)-N(1) bond length is 2.33 Å. The In(1)-N(4) bond length is 2.32 Å. The In(1)-O(13) bond length is 2.68 Å. The In(1)-O(16) bond length is 2.30 Å. The In(1)-O(22) bond length is 2.22 Å. The In(1)-O(6) bond length is 2.16 Å. The In(1)-O(8) bond length is 2.14 Å. In the second In site, In(2) is bonded in a 7-coordinate geometry to one N(2), one N(5), one O(14), one O(17), one O(23), one O(4), and one O(7) atom. The In(2)-N(2) bond length is 2.33 Å. The In(2)-N(5) bond length is 2.32 Å. The In(2)-O(14) bond length is 2.68 Å. The In(2)-O(17) bond length is 2.30 Å. The In(2)-O(23) bond length is 2.22 Å. The In(2)-O(4) bond length is 2.16 Å. The In(2)-O(7) bond length is 2.13 Å. In the third In site, In(3) is bonded in a 7-coordinate geometry to one N(3), one N(6), one O(15), one O(18), one O(24), one O(5), and one O(9) atom. The In(3)-N(3) bond length is 2.33 Å. The In(3)-N(6) bond length is 2.32 Å. The In(3)-O(15) bond length is 2.67 Å. The In(3)-O(18) bond length is 2.30 Å. The In(3)-O(24) bond length is 2.22 Å. The In(3)-O(5) bond length is 2.16 Å. The In(3)-O(9) bond length is 2.13 Å. There are thirty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4,5,6); one N(1); and one H(1,2,3) atom. The C(1)-C(4,5,6) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1,2,3) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4,5,6); one N(2); and one H(1,2,3) atom. The C(2)-C(4,5,6) bond length is 1.40 Å. The C(2)-N(2) bond length is 1.33 Å. The C(2)-H(1,2,3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4,5,6); one N(3); and one H(1,2,3) atom. The C(3)-C(4,5,6) bond length is 1.40 Å. The C(3)-N(3) bond length is 1.33 Å. The C(3)-H(1,2,3) bond length is 1.09 Å. In the fourth C site, C(4,5,6) is bonded in a trigonal planar geometry to one C(1), one C(31), and one C(7) atom. The C(4,5,6)-C(31) bond length is 1.50 Å. The C(4,5,6)-C(7) bond length is 1.40 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(10,11,12); one C(4,5,6); and one H(4,5,6) atom. The C(7)-C(10,11,12) bond length is 1.39 Å. The C(7)-H(4,5,6) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(10,11,12); one C(4,5,6); and one H(4,5,6) atom. The C(8)-C(10,11,12) bond length is 1.39 Å. The C(8)-C(4,5,6) bond length is 1.40 Å. The C(8)-H(4,5,6) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10,11,12); one C(4,5,6); and one H(4,5,6) atom. The C(9)-C(10,11,12) bond length is 1.39 Å. The C(9)-C(4,5,6) bond length is 1.40 Å. The C(9)-H(4,5,6) bond length is 1.09 Å. In the eighth C site, C(10,11,12) is bonded in a distorted trigonal planar geometry to one C(13), one C(7), and one H(7) atom. The C(10,11,12)-C(13) bond length is 1.40 Å. The C(10,11,12)-H(7) bond length is 1.09 Å. In the ninth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(10,11,12); one C(16,17); and one N(1) atom. The C(13)-C(16,17) bond length is 1.48 Å. The C(13)-N(1) bond length is 1.35 Å. In the tenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(10,11,12); one C(16,17); and one N(2) atom. The C(14)-C(10,11,12) bond length is 1.40 Å. The C(14)-C(16,17) bond length is 1.48 Å. The C(14)-N(2) bond length is 1.35 Å. In the eleventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(10,11,12); one C(18); and one N(3) atom. The C(15)-C(10,11,12) bond length is 1.40 Å. The C(15)-C(18) bond length is 1.48 Å. The C(15)-N(3) bond length is 1.35 Å. In the twelfth C site, C(16,17) is bonded in a distorted trigonal planar geometry to one C(13); one C(19,20,21); and one N(4) atom. The C(16,17)-C(19,20,21) bond length is 1.40 Å. The C(16,17)-N(4) bond length is 1.35 Å. In the thirteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(15); one C(19,20,21); and one N(6) atom. The C(18)-C(19,20,21) bond length is 1.40 Å. The C(18)-N(6) bond length is 1.35 Å. In the fourteenth C site, C(19,20,21) is bonded in a distorted trigonal planar geometry to one C(16,17); one C(22,23); and one H(10,11) atom. The C(19,20,21)-C(22,23) bond length is 1.39 Å. The C(19,20,21)-H(10,11) bond length is 1.09 Å. In the fifteenth C site, C(22,23) is bonded in a distorted trigonal planar geometry to one C(19,20,21); one C(25,26); and one H(13,14,15) atom. The C(22,23)-C(25,26) bond length is 1.40 Å. The C(22,23)-H(13,14,15) bond length is 1.09 Å. In the sixteenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(19,20,21); one C(27); and one H(13,14,15) atom. The C(24)-C(19,20,21) bond length is 1.39 Å. The C(24)-C(27) bond length is 1.40 Å. The C(24)-H(13,14,15) bond length is 1.09 Å. In the seventeenth C site, C(25,26) is bonded in a trigonal planar geometry to one C(22,23); one C(28,29); and one C(34,35) atom. The C(25,26)-C(28,29) bond length is 1.40 Å. The C(25,26)-C(34,35) bond length is 1.51 Å. In the eighteenth C site, C(27) is bonded in a trigonal planar geometry to one C(24), one C(30), and one C(36) atom. The C(27)-C(30) bond length is 1.40 Å. The C(27)-C(36) bond length is 1.51 Å. In the nineteenth C site, C(28,29) is bonded in a distorted bent 120 degrees geometry to one C(25,26); one N(4); and one H(16,17,18) atom. The C(28,29)-N(4) bond length is 1.34 Å. The C(28,29)-H(16,17,18) bond length is 1.09 Å. In the twentieth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(27); one N(6); and one H(16,17,18) atom. The C(30)-N(6) bond length is 1.34 Å. The C(30)-H(16,17,18) bond length is 1.09 Å. In the twenty-first C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(4,5,6); one O(1,2,3); and one O(4) atom. The C(31)-O(1,2,3) bond length is 1.25 Å. The C(31)-O(4) bond length is 1.30 Å. In the twenty-second C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(4,5,6); one O(1,2,3); and one O(5) atom. The C(32)-C(4,5,6) bond length is 1.50 Å. The C(32)-O(1,2,3) bond length is 1.25 Å. The C(32)-O(5) bond length is 1.30 Å. In the twenty-third C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(4,5,6); one O(1,2,3); and one O(6) atom. The C(33)-C(4,5,6) bond length is 1.50 Å. The C(33)-O(1,2,3) bond length is 1.25 Å. The C(33)-O(6) bond length is 1.30 Å. In the twenty-fourth C site, C(34,35) is bonded in a distorted bent 120 degrees geometry to one C(25,26); one O(10,11); and one O(7) atom. The C(34,35)-O(10,11) bond length is 1.24 Å. The C(34,35)-O(7) bond length is 1.30 Å. In the twenty-fifth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(12), and one O(9) atom. The C(36)-O(12) bond length is 1.24 Å. The C(36)-O(9) bond length is 1.30 Å. In the twenty-sixth C site, C(37,38,39) is bonded in a distorted trigonal planar geometry to one C(46), one N(10), and one O(22) atom. The C(37,38,39)-C(46) bond length is 1.50 Å. The C(37,38,39)-N(10) bond length is 1.34 Å. The C(37,38,39)-O(22) bond length is 1.27 Å. In the twenty-seventh C site, C(40,41,42) is bonded to one N(10); one H(19,20,21); one H(22,23,24); and one H(25,26,27) atom to form corner-sharing CH3N tetrahedra. The C(40,41,42)-N(10) bond length is 1.46 Å. The C(40,41,42)-H(19,20,21) bond length is 1.09 Å. The C(40,41,42)-H(22,23,24) bond length is 1.10 Å. The C(40,41,42)-H(25,26,27) bond length is 1.10 Å. In the twenty-eighth C site, C(43,44,45) is bonded to one N(10); one H(28,29,30); one H(31,32,33); and one H(34,35,36) atom to form corner-sharing CH3N tetrahedra. The C(43,44,45)-N(10) bond length is 1.46 Å. The C(43,44,45)-H(28,29,30) bond length is 1.10 Å. The C(43,44,45)-H(31,32,33) bond length is 1.10 Å. The C(43,44,45)-H(34,35,36) bond length is 1.09 Å. In the twenty-ninth C site, C(46) is bonded in a trigonal non-coplanar geometry to one C(37,38,39); one H(37,38,39); one H(40,41,42); and one H(43,44,45) atom. The C(46)-H(37,38,39) bond length is 1.10 Å. The C(46)-H(40,41,42) bond length is 1.09 Å. The C(46)-H(43,44,45) bond length is 1.10 Å. In the thirtieth C site, C(47,48) is bonded in a trigonal non-coplanar geometry to one C(37,38,39); one H(37,38,39); one H(40,41,42); and one H(43,44,45) atom. The C(47,48)-C(37,38,39) bond length is 1.50 Å. The C(47,48)-H(37,38,39) bond length is 1.10 Å. The C(47,48)-H(40,41,42) bond length is 1.09 Å. The C(47,48)-H(43,44,45) bond length is 1.10 Å. There are ten inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one In(1), one C(1), and one C(13) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one In(2), one C(14), and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one In(3), one C(15), and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one In(1); one C(16,17); and one C(28,29) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one In(2); one C(16,17); and one C(28,29) atom. The N(5)-C(16,17) bond length is 1.35 Å. The N(5)-C(28,29) bond length is 1.34 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one In(3), one C(18), and one C(30) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one O(13), one O(16), and one O(19) atom. The N(7)-O(13) bond length is 1.26 Å. The N(7)-O(16) bond length is 1.30 Å. The N(7)-O(19) bond length is 1.24 Å. In the eighth N site, N(8,9) is bonded in a trigonal planar geometry to one O(14), one O(17), and one O(20) atom. The N(8,9)-O(14) bond length is 1.26 Å. The N(8,9)-O(17) bond length is 1.30 Å. The N(8,9)-O(20) bond length is 1.24 Å. In the ninth N site, N(10) is bonded in a trigonal planar geometry to one C(37,38,39); one C(40,41,42); and one C(43,44,45) atom. In the tenth N site, N(11,12) is bonded in a trigonal planar geometry to one C(37,38,39); one C(40,41,42); and one C(43,44,45) atom. The N(11,12)-C(37,38,39) bond length is 1.34 Å. The N(11,12)-C(40,41,42) bond length is 1.46 Å. The N(11,12)-C(43,44,45) bond length is 1.46 Å. There are seventeen inequivalent H sites. In the first H site, H(1,2,3) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4,5,6) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10,11,12) atom. In the fourth H site, H(8,9) is bonded in a single-bond geometry to one C(10,11,12) atom. The H(8,9)-C(10,11,12) bond length is 1.09 Å. In the fifth H site, H(10,11) is bonded in a single-bond geometry to one C(19,20,21) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(19,20,21) atom. The H(12)-C(19,20,21) bond length is 1.09 Å. In the seventh H site, H(13,14,15) is bonded in a single-bond geometry to one C(22,23) atom. In the eighth H site, H(16,17,18) is bonded in a single-bond geometry to one C(28,29) atom. In the ninth H site, H(19,20,21) is bonded in a single-bond geometry to one C(40,41,42) atom. In the tenth H site, H(22,23,24) is bonded in a single-bond geometry to one C(40,41,42) atom. In the eleventh H site, H(25,26,27) is bonded in a single-bond geometry to one C(40,41,42) atom. In the twelfth H site, H(28,29,30) is bonded in a single-bond geometry to one C(43,44,45) atom. In the thirteenth H site, H(31,32,33) is bonded in a single-bond geometry to one C(43,44,45) atom. In the fourteenth H site, H(34,35,36) is bonded in a single-bond geometry to one C(43,44,45) atom. In the fifteenth H site, H(37,38,39) is bonded in a single-bond geometry to one C(46) atom. In the sixteenth H site, H(40,41,42) is bonded in a single-bond geometry to one C(46) atom. In the seventeenth H site, H(43,44,45) is bonded in a single-bond geometry to one C(46) atom. There are twenty-one inequivalent O sites. In the first O site, O(1,2,3) is bonded in a single-bond geometry to one C(31) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one In(2) and one C(31) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one In(3) and one C(32) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one In(1) and one C(33) atom. In the fifth O site, O(7) is bonded in a bent 120 degrees geometry to one In(2) and one C(34,35) atom. In the sixth O site, O(8) is bonded in a bent 120 degrees geometry to one In(1) and one C(34,35) atom. The O(8)-C(34,35) bond length is 1.30 Å. In the seventh O site, O(9) is bonded in a bent 120 degrees geometry to one In(3) and one C(36) atom. In the eighth O site, O(10,11) is bonded in a single-bond geometry to one C(34,35) atom. In the ninth O site, O(12) is bonded in a single-bond geometry to one C(36) atom. In the tenth O site, O(13) is bonded in a single-bond geometry to one In(1) and one N(7) atom. In the eleventh O site, O(14) is bonded in a single-bond geometry to one In(2) and one N(8,9) atom. In the twelfth O site, O(15) is bonded in a single-bond geometry to one In(3) and one N(8,9) atom. The O(15)-N(8,9) bond length is 1.26 Å. In the thirteenth O site, O(16) is bonded in a water-like geometry to one In(1) and one N(7) atom. In the fourteenth O site, O(17) is bonded in a water-like geometry to one In(2) and one N(8,9) atom. In the fifteenth O site, O(18) is bonded in a water-like geometry to one In(3) and one N(8,9) atom. The O(18)-N(8,9) bond length is 1.30 Å. In the sixteenth O site, O(19) is bonded in a single-bond geometry to one N(7) atom. In the seventeenth O site, O(20) is bonded in a single-bond geometry to one N(8,9) atom. In the eighteenth O site, O(21) is bonded in a single-bond geometry to one N(8,9) atom. The O(21)-N(8,9) bond length is 1.24 Å. In the nineteenth O site, O(22) is bonded in a distorted bent 150 degrees geometry to one In(1) and one C(37,38,39) atom. In the twentieth O site, O(23) is bonded in a distorted bent 150 degrees geometry to one In(2) and one C(37,38,39) atom. The O(23)-C(37,38,39) bond length is 1.27 Å. In the twenty-first O site, O(24) is bonded in a distorted bent 150 degrees geometry to one In(3) and one C(37,38,39) atom. The O(24)-C(37,38,39) bond length is 1.27 Å. Linkers: 6 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cn2)nc1. Metal clusters: 6 [In]. The MOF has largest included sphere 8.10 A, density 1.25 g/cm3, surface area 4061.01 m2/g, accessible volume 0.35 cm3/g