Ag2C7H12(SO5)2 crystallizes in the triclinic P-1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to one H(11), one O(1), one O(10), one O(2), one O(3), and one O(9) atom. The Ag(1)-H(11) bond length is 2.45 Å. The Ag(1)-O(1) bond length is 2.44 Å. The Ag(1)-O(10) bond length is 2.71 Å. The Ag(1)-O(2) bond length is 2.44 Å. The Ag(1)-O(3) bond length is 2.39 Å. The Ag(1)-O(9) bond length is 2.46 Å. In the second Ag site, Ag(2) is bonded to one O(1), one O(3), one O(4), one O(8), and two equivalent O(5) atoms to form distorted edge-sharing AgO6 octahedra. The Ag(2)-O(1) bond length is 2.44 Å. The Ag(2)-O(3) bond length is 2.69 Å. The Ag(2)-O(4) bond length is 2.56 Å. The Ag(2)-O(8) bond length is 2.50 Å. There is one shorter (2.50 Å) and one longer (2.52 Å) Ag(2)-O(5) bond length. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-S(1) bond length is 1.77 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one O(10) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-O(10) bond length is 1.36 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one S(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-S(2) bond length is 1.77 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(8) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(8) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(7) bond length is 1.50 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(9) atom. The C(6)-H(9) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one H(10), one H(11), and one H(12) atom. The C(7)-H(10) bond length is 1.10 Å. The C(7)-H(11) bond length is 1.10 Å. The C(7)-H(12) bond length is 1.10 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) and one O(8) atom. The H(1)-O(1) bond length is 0.99 Å. The H(1)-O(8) bond length is 1.72 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. The H(3)-O(3) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(3) atom. The H(4)-O(3) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(5) and one O(7) atom. The H(5)-O(5) bond length is 0.99 Å. The H(5)-O(7) bond length is 1.70 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(5) atom. The H(6)-O(5) bond length is 0.99 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(10) atom. The H(7)-O(10) bond length is 1.00 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one Ag(1) and one C(7) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(2), one O(4), and one O(6) atom. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(4) bond length is 1.47 Å. The S(1)-O(6) bond length is 1.48 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one O(7), one O(8), and one O(9) atom. The S(2)-O(7) bond length is 1.46 Å. The S(2)-O(8) bond length is 1.48 Å. The S(2)-O(9) bond length is 1.49 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ag(1), one Ag(2), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one S(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Ag(1), one Ag(2), one H(3), and one H(4) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(2) and one S(1) atom. In the fifth O site, O(5) is bonded in a water-like geometry to two equivalent Ag(2), one H(5), and one H(6) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one S(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one H(5) and one S(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Ag(2), one H(1), and one S(2) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Ag(1) and one S(2) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Ag(1), one C(2), and one H(7) atom. Linkers: 2 Cc1cc(S([O])([O])[O])c(O)c(S([O])([O])[O])c1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.71 A, density 2.68 g/cm3, surface area 2803.43 m2/g, accessible volume 0.06 cm3/g