AgC6H5(NO)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one N(1), one N(4), one O(1), one O(3), and one O(4) atom. The Ag(1)-N(1) bond length is 2.23 Å. The Ag(1)-N(4) bond length is 2.27 Å. The Ag(1)-O(1) bond length is 2.56 Å. The Ag(1)-O(3) bond length is 2.51 Å. The Ag(1)-O(4) bond length is 2.73 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one N(2), one N(3), one O(2), and one O(4) atom. The Ag(2)-N(2) bond length is 2.26 Å. The Ag(2)-N(3) bond length is 2.22 Å. The Ag(2)-O(2) bond length is 2.69 Å. The Ag(2)-O(4) bond length is 2.46 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(7), one H(5), one H(6), and one H(7) atom. The C(1)-C(7) bond length is 1.49 Å. The C(1)-H(5) bond length is 1.10 Å. The C(1)-H(6) bond length is 1.10 Å. The C(1)-H(7) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(3), and one H(3) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(3) bond length is 1.35 Å. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(9), and one N(4) atom. The C(3)-C(9) bond length is 1.52 Å. The C(3)-N(4) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(2) atom. The C(4)-C(12) bond length is 1.40 Å. The C(4)-N(2) bond length is 1.34 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one C(12), one H(10), one H(8), and one H(9) atom. The C(5)-C(12) bond length is 1.48 Å. The C(5)-H(10) bond length is 1.09 Å. The C(5)-H(8) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(4), and one H(4) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-N(4) bond length is 1.34 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(1), one C(6), and one N(3) atom. The C(7)-N(3) bond length is 1.35 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(10), one C(11), and one N(2) atom. The C(8)-C(10) bond length is 1.52 Å. The C(8)-C(11) bond length is 1.40 Å. The C(8)-N(2) bond length is 1.35 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(4) atom. The C(9)-O(3) bond length is 1.26 Å. The C(9)-O(4) bond length is 1.27 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(1), and one O(2) atom. The C(10)-O(1) bond length is 1.27 Å. The C(10)-O(2) bond length is 1.26 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(8), one N(1), and one H(1) atom. The C(11)-N(1) bond length is 1.34 Å. The C(11)-H(1) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(4), one C(5), and one N(1) atom. The C(12)-N(1) bond length is 1.35 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(11), and one C(12) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(2), one C(4), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(2), one C(2), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(1), one C(3), and one C(6) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(1) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one C(10) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Ag(2) and one C(10) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(1) and one C(9) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one C(9) atom. Linkers: 7 Cc1cnc(C([O])=O)cn1. Metal clusters: 8 [Ag]. The MOF has largest included sphere 1.44 A, density 2.53 g/cm3, surface area 2964.71 m2/g, accessible volume 0.04 cm3/g