ZnC20H17(NO2)2CHCH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two 02329_fluka molecules, and two ZnC20H17(NO2)2 clusters. In each ZnC20H17(NO2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(2), and one O(4) atom. The Zn(1)-N(1) bond length is 2.05 Å. The Zn(1)-N(2) bond length is 2.03 Å. The Zn(1)-O(2) bond length is 1.98 Å. The Zn(1)-O(4) bond length is 1.97 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.31 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(3) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-C(8) bond length is 1.51 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted water-like geometry to one C(6), one H(5), and one H(6) atom. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.10 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(9)-O(3) bond length is 1.25 Å. The C(9)-O(4) bond length is 1.30 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(7) atom. The C(10)-N(1) bond length is 1.35 Å. The C(10)-H(7) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(8) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(8) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(15) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(15) bond length is 1.50 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(9) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(1), and one H(10) atom. The C(14)-N(1) bond length is 1.35 Å. The C(14)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted water-like geometry to one C(12), one H(11), and one H(12) atom. The C(15)-H(11) bond length is 1.10 Å. The C(15)-H(12) bond length is 1.11 Å. In the fifteenth C site, C(17) is bonded in a water-like geometry to one C(18), one H(15), and one H(16) atom. The C(17)-C(18) bond length is 1.50 Å. The C(17)-H(15) bond length is 1.10 Å. The C(17)-H(16) bond length is 1.10 Å. In the sixteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(22) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(22) bond length is 1.40 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(17) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-H(17) bond length is 1.09 Å. In the eighteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one N(2), and one H(18) atom. The C(20)-N(2) bond length is 1.35 Å. The C(20)-H(18) bond length is 1.09 Å. In the nineteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one N(2), and one H(19) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-N(2) bond length is 1.35 Å. The C(21)-H(19) bond length is 1.09 Å. In the twentieth C site, C(22) is bonded in a distorted single-bond geometry to one C(18), one C(21), and one H(20) atom. The C(22)-H(20) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(14) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(20), and one C(21) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(20) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(21) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(22) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(9) atom. Linkers: 2 [O]C(=O)Cc1cccc(C([O])=O)c1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.85 A, density 1.46 g/cm3, surface area 4939.28 m2/g, accessible volume 0.19 cm3/g