MnC9H5(NO2)2(CH)3C2H4S is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two dimethyl sulfide molecules, and one MnC9H5(NO2)2 cluster. In the MnC9H5(NO2)2 cluster, Mn(1) is bonded in a distorted pentagonal pyramidal geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Mn(1)-N(1) bond length is 2.27 Å. The Mn(1)-N(2) bond length is 2.29 Å. The Mn(1)-O(1) bond length is 2.17 Å. The Mn(1)-O(2) bond length is 2.17 Å. The Mn(1)-O(3) bond length is 2.17 Å. The Mn(1)-O(4) bond length is 2.19 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(4)-O(3) bond length is 1.27 Å. The C(4)-O(4) bond length is 1.27 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(5) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(8) bond length is 1.09 Å. In the fifth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(1) atom. The C(9)-C(10) bond length is 1.48 Å. The C(9)-N(1) bond length is 1.35 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one N(2) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-N(2) bond length is 1.35 Å. In the seventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(9) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(9) bond length is 1.09 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(10) atom. The C(12)-H(10) bond length is 1.09 Å. In the ninth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(14)-N(2) bond length is 1.34 Å. The C(14)-H(12) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(1), one C(5), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(1), one C(10), and one C(14) atom. There are five inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(4) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(4) atom. Linkers: 2 [O]C(=O)CSCC([O])=O. Metal clusters: 1 [C]1O[Mn]23O[C]O[Mn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 2.24 A, density 1.75 g/cm3, surface area 4038.97 m2/g, accessible volume 0.11 cm3/g