TbC22H12(NO3)2(CH)2 crystallizes in the triclinic P-1 space group. The structure consists of eight 02329_fluka molecules inside a TbC22H12(NO3)2 framework. In the TbC22H12(NO3)2 framework, there are two inequivalent Tb sites. In the first Tb site, Tb(1) is bonded in a 9-coordinate geometry to one N(1), one N(4), one O(1), one O(10), one O(11), one O(6), one O(7), and two equivalent O(3) atoms. The Tb(1)-N(1) bond length is 2.64 Å. The Tb(1)-N(4) bond length is 2.59 Å. The Tb(1)-O(1) bond length is 2.51 Å. The Tb(1)-O(10) bond length is 2.52 Å. The Tb(1)-O(11) bond length is 2.36 Å. The Tb(1)-O(6) bond length is 2.40 Å. The Tb(1)-O(7) bond length is 2.30 Å. There is one shorter (2.33 Å) and one longer (2.61 Å) Tb(1)-O(3) bond length. In the second Tb site, Tb(2) is bonded in a 8-coordinate geometry to one N(2), one N(3), one O(12), one O(2), one O(4), one O(5), one O(8), and one O(9) atom. The Tb(2)-N(2) bond length is 2.58 Å. The Tb(2)-N(3) bond length is 2.55 Å. The Tb(2)-O(12) bond length is 2.36 Å. The Tb(2)-O(2) bond length is 2.43 Å. The Tb(2)-O(4) bond length is 2.36 Å. The Tb(2)-O(5) bond length is 2.31 Å. The Tb(2)-O(8) bond length is 2.40 Å. The Tb(2)-O(9) bond length is 2.27 Å. There are forty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(10), and one O(3) atom. The C(1)-C(5) bond length is 1.49 Å. The C(1)-O(10) bond length is 1.26 Å. The C(1)-O(3) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(14), one C(3), and one C(6) atom. The C(2)-C(14) bond length is 1.40 Å. The C(2)-C(3) bond length is 1.50 Å. The C(2)-C(6) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(4), and one O(5) atom. The C(3)-O(4) bond length is 1.27 Å. The C(3)-O(5) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(11), one C(18), and one C(8) atom. The C(4)-C(11) bond length is 1.50 Å. The C(4)-C(18) bond length is 1.41 Å. The C(4)-C(8) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(12), and one C(6) atom. The C(5)-C(12) bond length is 1.40 Å. The C(5)-C(6) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(1) atom. The C(6)-H(1) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(8) atom. The C(7)-C(15) bond length is 1.49 Å. The C(7)-C(19) bond length is 1.40 Å. The C(7)-C(8) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(4), one C(7), and one H(2) atom. The C(8)-H(2) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(6), and one O(7) atom. The C(9)-C(22) bond length is 1.50 Å. The C(9)-O(6) bond length is 1.28 Å. The C(9)-O(7) bond length is 1.27 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(13), one C(16), and one C(26) atom. The C(10)-C(13) bond length is 1.49 Å. The C(10)-C(16) bond length is 1.40 Å. The C(10)-C(26) bond length is 1.40 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(12), and one O(9) atom. The C(11)-O(12) bond length is 1.27 Å. The C(11)-O(9) bond length is 1.27 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(27), one C(5), and one H(3) atom. The C(12)-C(27) bond length is 1.39 Å. The C(12)-H(3) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a bent 120 degrees geometry to one C(10), one O(2), and one O(8) atom. The C(13)-O(2) bond length is 1.28 Å. The C(13)-O(8) bond length is 1.29 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(14)-H(4) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(1), and one O(11) atom. The C(15)-O(1) bond length is 1.28 Å. The C(15)-O(11) bond length is 1.28 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(10), one C(22), and one H(5) atom. The C(16)-C(22) bond length is 1.40 Å. The C(16)-H(5) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(28) and one N(1) atom. The C(17)-C(28) bond length is 1.42 Å. The C(17)-N(1) bond length is 1.36 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(18)-H(6) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(20), one C(7), and one H(7) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(7) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(8) atom. The C(20)-H(8) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(34) and one N(4) atom. The C(21)-C(34) bond length is 1.42 Å. The C(21)-N(4) bond length is 1.36 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(16), one C(41), and one C(9) atom. The C(22)-C(41) bond length is 1.41 Å. In the twenty-third C site, C(23) is bonded in a distorted trigonal planar geometry to one C(25), one C(30), and one N(2) atom. The C(23)-C(25) bond length is 1.44 Å. The C(23)-C(30) bond length is 1.42 Å. The C(23)-N(2) bond length is 1.36 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(25), one C(42), and one C(45) atom. The C(24)-C(25) bond length is 1.42 Å. The C(24)-C(42) bond length is 1.41 Å. The C(24)-C(45) bond length is 1.43 Å. In the twenty-fifth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(23), one C(24), and one N(3) atom. The C(25)-N(3) bond length is 1.36 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(10) and one H(9) atom. The C(26)-H(9) bond length is 1.09 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(27)-H(10) bond length is 1.09 Å. In the twenty-eighth C site, C(28) is bonded in a trigonal planar geometry to one C(17), one C(36), and one C(40) atom. The C(28)-C(36) bond length is 1.43 Å. The C(28)-C(40) bond length is 1.41 Å. In the twenty-ninth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(11) atom. The C(29)-N(4) bond length is 1.33 Å. The C(29)-H(11) bond length is 1.09 Å. In the thirtieth C site, C(30) is bonded in a trigonal planar geometry to one C(23), one C(46), and one C(48) atom. The C(30)-C(46) bond length is 1.43 Å. The C(30)-C(48) bond length is 1.41 Å. In the thirty-first C site, C(31) is bonded in a distorted trigonal planar geometry to one C(43), one N(2), and one H(12) atom. The C(31)-C(43) bond length is 1.41 Å. The C(31)-N(2) bond length is 1.33 Å. The C(31)-H(12) bond length is 1.09 Å. In the thirty-second C site, C(34) is bonded in a trigonal planar geometry to one C(21), one C(44), and one C(47) atom. The C(34)-C(44) bond length is 1.43 Å. The C(34)-C(47) bond length is 1.41 Å. In the thirty-third C site, C(36) is bonded in a distorted single-bond geometry to one C(28) and one H(16) atom. The C(36)-H(16) bond length is 1.09 Å. In the thirty-fourth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(18) atom. The C(38)-N(1) bond length is 1.33 Å. The C(38)-H(18) bond length is 1.09 Å. In the thirty-fifth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(19) atom. The C(39)-N(3) bond length is 1.33 Å. The C(39)-H(19) bond length is 1.09 Å. In the thirty-sixth C site, C(40) is bonded in a distorted single-bond geometry to one C(28) and one H(20) atom. The C(40)-H(20) bond length is 1.09 Å. In the thirty-seventh C site, C(41) is bonded in a distorted single-bond geometry to one C(22) and one H(21) atom. The C(41)-H(21) bond length is 1.09 Å. In the thirty-eighth C site, C(42) is bonded in a distorted single-bond geometry to one C(24) and one H(22) atom. The C(42)-H(22) bond length is 1.09 Å. In the thirty-ninth C site, C(43) is bonded in a distorted trigonal planar geometry to one C(31), one C(48), and one H(23) atom. The C(43)-C(48) bond length is 1.38 Å. The C(43)-H(23) bond length is 1.09 Å. In the fortieth C site, C(44) is bonded in a distorted single-bond geometry to one C(34) and one H(24) atom. The C(44)-H(24) bond length is 1.09 Å. In the forty-first C site, C(45) is bonded in a distorted single-bond geometry to one C(24) and one H(25) atom. The C(45)-H(25) bond length is 1.09 Å. In the forty-second C site, C(46) is bonded in a distorted single-bond geometry to one C(30) and one H(26) atom. The C(46)-H(26) bond length is 1.09 Å. In the forty-third C site, C(47) is bonded in a distorted single-bond geometry to one C(34) and one H(27) atom. The C(47)-H(27) bond length is 1.09 Å. In the forty-fourth C site, C(48) is bonded in a distorted single-bond geometry to one C(30), one C(43), and one H(28) atom. The C(48)-H(28) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Tb(1), one C(17), and one C(38) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Tb(2), one C(23), and one C(31) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Tb(2), one C(25), and one C(39) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Tb(1), one C(21), and one C(29) atom. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(27) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(31) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(36) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(38) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(39) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(40) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(41) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(42) atom. In the nineteenth H site, H(23) is bonded in a single-bond geometry to one C(43) atom. In the twentieth H site, H(24) is bonded in a single-bond geometry to one C(44) atom. In the twenty-first H site, H(25) is bonded in a single-bond geometry to one C(45) atom. In the twenty-second H site, H(26) is bonded in a single-bond geometry to one C(46) atom. In the twenty-third H site, H(27) is bonded in a single-bond geometry to one C(47) atom. In the twenty-fourth H site, H(28) is bonded in a single-bond geometry to one C(48) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Tb(1) and one C(15) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Tb(2) and one C(13) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to two equivalent Tb(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Tb(2) and one C(3) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Tb(2) and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Tb(1) and one C(9) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Tb(1) and one C(9) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Tb(2) and one C(13) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Tb(2) and one C(11) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Tb(1) and one C(1) atom. In the eleventh O site, O(11) is bonded in an L-shaped geometry to one Tb(1) and one C(15) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Tb(2) and one C(11) atom. Linkers: 6 [O]C(=O)c1cccc(C([O])=O)c1. Metal clusters: 1 [C]1O[Tb]234(O1)O[C]O[Tb]1(O[C]O1)(O[C]O2)(O[C]O3)O[C]O4 ,2 [Tb]. The MOF has largest included sphere 4.43 A, density 1.72 g/cm3, surface area 3595.09 m2/g, accessible volume 0.19 cm3/g