CdC10H10(NO)4(CH2)2(C4H4O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; four 1-propene, 1-methoxy-, (1z)- molecules; and two CdC10H10(NO)4 clusters. In each CdC10H10(NO)4 cluster, Cd(1) is bonded in a distorted octahedral geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.27 Å. The Cd(1)-N(2) bond length is 2.28 Å. The Cd(1)-O(1) bond length is 2.52 Å. The Cd(1)-O(2) bond length is 2.50 Å. The Cd(1)-O(3) bond length is 2.35 Å. The Cd(1)-O(4) bond length is 2.36 Å. There are ten inequivalent C sites. In the first C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(9)-O(1) bond length is 1.26 Å. The C(9)-O(3) bond length is 1.28 Å. In the second C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(10)-O(2) bond length is 1.26 Å. The C(10)-O(4) bond length is 1.28 Å. In the third C site, C(11) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(9) atom. The C(11)-N(1) bond length is 1.33 Å. The C(11)-N(3) bond length is 1.36 Å. The C(11)-H(9) bond length is 1.09 Å. In the fourth C site, C(12) is bonded in a trigonal planar geometry to one N(2), one N(4), and one H(10) atom. The C(12)-N(2) bond length is 1.33 Å. The C(12)-N(4) bond length is 1.36 Å. The C(12)-H(10) bond length is 1.09 Å. In the fifth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(3), and one H(11) atom. The C(13)-C(15) bond length is 1.38 Å. The C(13)-N(3) bond length is 1.38 Å. The C(13)-H(11) bond length is 1.08 Å. In the sixth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(4), and one H(12) atom. The C(14)-C(16) bond length is 1.38 Å. The C(14)-N(4) bond length is 1.38 Å. The C(14)-H(12) bond length is 1.08 Å. In the seventh C site, C(15) is bonded in a 3-coordinate geometry to one C(13), one N(1), and one H(13) atom. The C(15)-N(1) bond length is 1.38 Å. The C(15)-H(13) bond length is 1.08 Å. In the eighth C site, C(16) is bonded in a 3-coordinate geometry to one C(14), one N(2), and one H(14) atom. The C(16)-N(2) bond length is 1.38 Å. The C(16)-H(14) bond length is 1.08 Å. In the ninth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(15), and one H(17) atom. The C(17)-N(3) bond length is 1.46 Å. The C(17)-H(15) bond length is 1.10 Å. The C(17)-H(17) bond length is 1.10 Å. In the tenth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(16), and one H(18) atom. The C(18)-N(4) bond length is 1.46 Å. The C(18)-H(16) bond length is 1.10 Å. The C(18)-H(18) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one C(15) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(12), and one C(16) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(18) atom. There are ten inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(9) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(10) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(9) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(10) atom. Linkers: 2 c1cn(CCCCn2ccnc2)cn1 ,4 [c]1cn(CCCCn2ccnc2)cn1 ,2 [O]C(=O)COc1ccc(OC[C]=O)cc1 ,2 [O]C(=O)COc1ccc(OCC([O])=O)cc1. Metal clusters: 2 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 3.98 A, density 1.47 g/cm3, surface area 4736.47 m2/g, accessible volume 0.31 cm3/g