ZnC10H10(NO)4(CH2)4CH3CH is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, eight 02329_fluka molecules, two 02329_fluka molecules, and two ZnC10H10(NO)4 clusters. In each ZnC10H10(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Zn(1)-N(1) bond length is 2.00 Å. The Zn(1)-N(2) bond length is 2.05 Å. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(2) bond length is 2.01 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(1)-O(1) bond length is 1.31 Å. The C(1)-O(4) bond length is 1.25 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(2)-O(2) bond length is 1.31 Å. The C(2)-O(3) bond length is 1.25 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one N(2), one N(4), and one H(1) atom. The C(4)-N(2) bond length is 1.33 Å. The C(4)-N(4) bond length is 1.35 Å. The C(4)-H(1) bond length is 1.08 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(2) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-N(3) bond length is 1.35 Å. The C(5)-H(2) bond length is 1.08 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(1), and one H(5) atom. The C(7)-C(10) bond length is 1.38 Å. The C(7)-N(1) bond length is 1.38 Å. The C(7)-H(5) bond length is 1.08 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(6) atom. The C(8)-C(12) bond length is 1.38 Å. The C(8)-N(2) bond length is 1.38 Å. The C(8)-H(6) bond length is 1.08 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(3), and one H(9) atom. The C(10)-N(3) bond length is 1.38 Å. The C(10)-H(9) bond length is 1.09 Å. In the eighth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(4), and one H(12) atom. The C(12)-N(4) bond length is 1.38 Å. The C(12)-H(12) bond length is 1.08 Å. In the ninth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(13), and one H(14) atom. The C(13)-N(3) bond length is 1.47 Å. The C(13)-H(13) bond length is 1.10 Å. The C(13)-H(14) bond length is 1.10 Å. In the tenth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(15), and one H(16) atom. The C(14)-N(4) bond length is 1.46 Å. The C(14)-H(15) bond length is 1.10 Å. The C(14)-H(16) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(5), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(4), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(5) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(4) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(14) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(1) atom. Linkers: 2 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.10 A, density 1.28 g/cm3, surface area 5219.86 m2/g, accessible volume 0.30 cm3/g