CdC28H20(NO2)2(CH)4C2O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two dimethyl ether molecules, and one CdC28H20(NO2)2 cluster. In the CdC28H20(NO2)2 cluster, Cd(1) is bonded in a distorted octahedral geometry to one N(1), one N(2), one O(1), one O(2), one O(4), and one O(5) atom. The Cd(1)-N(1) bond length is 2.35 Å. The Cd(1)-N(2) bond length is 2.35 Å. The Cd(1)-O(1) bond length is 2.31 Å. The Cd(1)-O(2) bond length is 2.28 Å. The Cd(1)-O(4) bond length is 2.39 Å. The Cd(1)-O(5) bond length is 2.52 Å. There are twenty-eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.45 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(7)-C(8) bond length is 1.45 Å. The C(7)-H(6) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(7), and one C(9) atom. The C(8)-C(13) bond length is 1.41 Å. The C(8)-C(9) bond length is 1.41 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(7) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(8) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-H(8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-C(14) bond length is 1.45 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(9) atom. The C(12)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(10,20) atom. The C(13)-H(10,20) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(11), one C(15), and one H(11) atom. The C(14)-C(15) bond length is 1.35 Å. The C(14)-H(11) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(12) atom. The C(15)-C(16) bond length is 1.45 Å. The C(15)-H(12) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(20) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(20) bond length is 1.41 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(13) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(13) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one N(2), and one H(14) atom. The C(18)-N(2) bond length is 1.34 Å. The C(18)-H(14) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(20), one N(2), and one H(15) atom. The C(19)-C(20) bond length is 1.38 Å. The C(19)-N(2) bond length is 1.35 Å. The C(19)-H(15) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(16), one C(19), and one H(16) atom. The C(20)-H(16) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(1), and one O(2) atom. The C(21)-C(22) bond length is 1.50 Å. The C(21)-O(1) bond length is 1.27 Å. The C(21)-O(2) bond length is 1.28 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(27) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(27) bond length is 1.40 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(17) atom. The C(23)-H(17) bond length is 1.09 Å. In the twenty-fourth C site, C(27) is bonded in a distorted single-bond geometry to one C(22) and one H(10,20) atom. The C(27)-H(10,20) bond length is 1.09 Å. In the twenty-fifth C site, C(30) is bonded in a distorted single-bond geometry to one C(31) and one H(22) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-H(22) bond length is 1.09 Å. In the twenty-sixth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(34) atom. The C(31)-C(32) bond length is 1.40 Å. The C(31)-C(34) bond length is 1.50 Å. In the twenty-seventh C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(23) atom. The C(32)-H(23) bond length is 1.09 Å. In the twenty-eighth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(4), and one O(5) atom. The C(34)-O(4) bond length is 1.28 Å. The C(34)-O(5) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(18), and one C(19) atom. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(10,20) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(30) atom. In the nineteenth H site, H(23) is bonded in a single-bond geometry to one C(32) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(34) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one C(34) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(21) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(21) atom. Linkers: 2 C(=C/c1ccc(/C=C/c2ccncc2)cc1)\c1ccncc1 ,2 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 1 [C]1O[Cd]2(O1)O[C]O[Cd]1(O[C]O1)O[C]O2. The MOF has largest included sphere 5.89 A, density 1.15 g/cm3, surface area 4618.36 m2/g, accessible volume 0.43 cm3/g