VCuC16PN2H11O7CH is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one VCuC16PN2H11O7 cluster. In the VCuC16PN2H11O7 cluster, V(1) is bonded to one O(1), one O(2), one O(5), one O(6), and one O(7) atom to form distorted VO5 trigonal bipyramids that share corners with two equivalent P(1)CO3 tetrahedra and  a cornercorner with one Cu(1)N2O3 trigonal bipyramid. The V(1)-O(1) bond length is 1.92 Å. The V(1)-O(2) bond length is 1.95 Å. The V(1)-O(5) bond length is 2.08 Å. The V(1)-O(6) bond length is 1.62 Å. The V(1)-O(7) bond length is 1.69 Å. Cu(1) is bonded to one N(1), one N(2), one O(3), one O(4), and one O(7) atom to form CuN2O3 trigonal bipyramids that share  a cornercorner with one P(1)CO3 tetrahedra and  a cornercorner with one V(1)O5 trigonal bipyramid. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-N(2) bond length is 2.01 Å. The Cu(1)-O(3) bond length is 2.31 Å. The Cu(1)-O(4) bond length is 1.96 Å. The Cu(1)-O(7) bond length is 1.97 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(7), and one P(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.40 Å. The C(1)-P(1) bond length is 1.81 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.50 Å. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(4), and one O(5) atom. The C(5)-O(4) bond length is 1.28 Å. The C(5)-O(5) bond length is 1.28 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(5) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-N(1) bond length is 1.34 Å. The C(8)-H(5) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(9)-H(6) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(7) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(8) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(8) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one N(1) atom. The C(12)-C(13) bond length is 1.47 Å. The C(12)-N(1) bond length is 1.36 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one N(2) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-N(2) bond length is 1.36 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(9) atom. The C(14)-H(9) bond length is 1.09 Å. In the fifteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(11) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(11) bond length is 1.09 Å. In the sixteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(2), and one H(12) atom. The C(17)-N(2) bond length is 1.34 Å. The C(17)-H(12) bond length is 1.09 Å. P(1) is bonded to one C(1), one O(1), one O(2), and one O(3) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one Cu(1)N2O3 trigonal bipyramid and corners with two equivalent V(1)O5 trigonal bipyramids. The P(1)-O(1) bond length is 1.57 Å. The P(1)-O(2) bond length is 1.55 Å. The P(1)-O(3) bond length is 1.51 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(12), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(17) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(17) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(5) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one V(1) and one C(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one V(1) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one V(1) and one Cu(1) atom. Linkers: 2 [O]C(=O)c1ccc(P([O])([O])=O)cc1 ,2 c1ccc(-c2ccccn2)nc1. Metal clusters: 1 [O][V]123O[C]O[Cu](OP(O1)O[V]14([O])O[C]O[Cu](OP(O2)O1)O4)O3. The MOF has largest included sphere 2.20 A, density 2.01 g/cm3, surface area 3332.69 m2/g, accessible volume 0.09 cm3/g