ZnC17N4H16O5(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two ZnC17N4H16O5 clusters. In each ZnC17N4H16O5 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-N(3) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 2.00 Å. The Zn(1)-O(3) bond length is 1.97 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(5) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-C(3) bond length is 1.51 Å. The C(1)-C(5) bond length is 1.40 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one O(2) atom. The C(2)-O(2) bond length is 1.36 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(3), and one O(4) atom. The C(3)-O(3) bond length is 1.30 Å. The C(3)-O(4) bond length is 1.25 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(5) atom. The C(4)-O(1) bond length is 1.29 Å. The C(4)-O(5) bond length is 1.25 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(1), one C(6), and one H(1) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(1) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(14), one C(5), and one H(2) atom. The C(6)-C(14) bond length is 1.40 Å. The C(6)-H(2) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(3), and one H(5) atom. The C(8)-C(10) bond length is 1.38 Å. The C(8)-N(3) bond length is 1.38 Å. The C(8)-H(5) bond length is 1.08 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(6) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-N(2) bond length is 1.35 Å. The C(9)-H(6) bond length is 1.08 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(4), and one H(7) atom. The C(10)-N(4) bond length is 1.38 Å. The C(10)-H(7) bond length is 1.08 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(8) atom. The C(11)-N(3) bond length is 1.33 Å. The C(11)-N(4) bond length is 1.35 Å. The C(11)-H(8) bond length is 1.08 Å. In the eleventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(2), and one H(9) atom. The C(12)-C(16) bond length is 1.37 Å. The C(12)-N(2) bond length is 1.38 Å. The C(12)-H(9) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one H(10), one H(11), and one O(2) atom. The C(13)-H(10) bond length is 1.10 Å. The C(13)-H(11) bond length is 1.10 Å. The C(13)-O(2) bond length is 1.44 Å. In the thirteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(19), one C(6), and one H(12) atom. The C(14)-C(19) bond length is 1.40 Å. The C(14)-H(12) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(12), one N(1), and one H(15) atom. The C(16)-N(1) bond length is 1.38 Å. The C(16)-H(15) bond length is 1.08 Å. In the fifteenth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(16), and one H(17) atom. The C(17)-N(2) bond length is 1.46 Å. The C(17)-H(16) bond length is 1.10 Å. The C(17)-H(17) bond length is 1.10 Å. In the sixteenth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(18), and one H(19) atom. The C(18)-N(4) bond length is 1.46 Å. The C(18)-H(18) bond length is 1.10 Å. The C(18)-H(19) bond length is 1.10 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(20) atom. The C(19)-H(20) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(16), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(12), one C(17), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(8) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(18) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(19) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(13) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(4) atom. Linkers: 2 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.04 A, density 1.45 g/cm3, surface area 4863.64 m2/g, accessible volume 0.17 cm3/g