Zn2C7H5(N4O)2CH crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a Zn2C7H5(N4O)2 framework. In the Zn2C7H5(N4O)2 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(2), one N(5), one O(1), and one O(2) atom to form corner-sharing ZnN2O2 tetrahedra. The Zn(1)-N(2) bond length is 2.01 Å. The Zn(1)-N(5) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 1.94 Å. The Zn(1)-O(2) bond length is 1.93 Å. In the second Zn site, Zn(2) is bonded to one N(4), one N(8), one O(1), and one O(2) atom to form corner-sharing ZnN2O2 tetrahedra. The Zn(2)-N(4) bond length is 2.03 Å. The Zn(2)-N(8) bond length is 2.03 Å. The Zn(2)-O(1) bond length is 1.95 Å. The Zn(2)-O(2) bond length is 1.93 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.46 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(3) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.47 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted water-like geometry to one C(1), one N(1), and one N(4) atom. The C(7)-N(1) bond length is 1.34 Å. The C(7)-N(4) bond length is 1.36 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(5), one N(5), and one N(8) atom. The C(8)-N(5) bond length is 1.34 Å. The C(8)-N(8) bond length is 1.35 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one C(7) and one N(2) atom. The N(1)-N(2) bond length is 1.34 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one N(1), and one N(3) atom. The N(2)-N(3) bond length is 1.32 Å. In the third N site, N(3) is bonded in a water-like geometry to one N(2) and one N(4) atom. The N(3)-N(4) bond length is 1.34 Å. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one Zn(2), one C(7), and one N(3) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(8), and one N(6) atom. The N(5)-N(6) bond length is 1.36 Å. In the sixth N site, N(6) is bonded in a water-like geometry to one N(5) and one N(7) atom. The N(6)-N(7) bond length is 1.30 Å. In the seventh N site, N(7) is bonded in a water-like geometry to one N(6) and one N(8) atom. The N(7)-N(8) bond length is 1.35 Å. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(8), and one N(7) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one O(2) atom. The H(5)-O(2) bond length is 0.99 Å. In the fifth H site, H(6) is bonded in a single-bond geometry to one O(1) atom. The H(6)-O(1) bond length is 0.97 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(2), and one H(6) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(2), and one H(5) atom. Linkers: 4 c1cc(C2=NN=N[N]2)cc(C2=NN=N[N]2)c1. Metal clusters: 8 [Zn]. The MOF has largest included sphere 1.97 A, density 2.16 g/cm3, surface area 3558.24 m2/g, accessible volume 0.08 cm3/g