K2C8N2H9O(CH)8(CH3)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight 02329_fluka molecules, and one K2C8N2H9O cluster. In the K2C8N2H9O cluster, there are two inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one N(1), two equivalent N(2), one H(1), two equivalent H(13), and one O(1) atom. The K(1)-N(1) bond length is 2.82 Å. There is one shorter (2.81 Å) and one longer (2.83 Å) K(1)-N(2) bond length. The K(1)-H(1) bond length is 2.92 Å. There is one shorter (2.77 Å) and one longer (2.79 Å) K(1)-H(13) bond length. The K(1)-O(1) bond length is 2.74 Å. In the second K site, K(2) is bonded in a distorted single-bond geometry to one N(1) atom. The K(2)-N(1) bond length is 2.74 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one H(1) atom. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(6) is bonded in a distorted single-bond geometry to one N(1) atom. The C(6)-N(1) bond length is 1.35 Å. In the third C site, C(7) is bonded in a 2-coordinate geometry to one N(1) and one H(6) atom. The C(7)-N(1) bond length is 1.46 Å. The C(7)-H(6) bond length is 1.11 Å. In the fourth C site, C(10) is bonded in a distorted single-bond geometry to one H(13) atom. The C(10)-H(13) bond length is 1.09 Å. In the fifth C site, C(15) is bonded in a distorted single-bond geometry to one N(2) atom. The C(15)-N(2) bond length is 1.35 Å. In the sixth C site, C(16) is bonded in a 2-coordinate geometry to one N(2) and one H(18) atom. The C(16)-N(2) bond length is 1.46 Å. The C(16)-H(18) bond length is 1.11 Å. In the seventh C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one H(25), one H(26), and one O(1) atom. The C(19)-H(25) bond length is 1.11 Å. The C(19)-H(26) bond length is 1.10 Å. The C(19)-O(1) bond length is 1.43 Å. In the eighth C site, C(20) is bonded in a tetrahedral geometry to one H(27), one H(28), one H(29), and one O(1) atom. The C(20)-H(27) bond length is 1.10 Å. The C(20)-H(28) bond length is 1.10 Å. The C(20)-H(29) bond length is 1.10 Å. The C(20)-O(1) bond length is 1.43 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one K(1), one K(2), one C(6), and one C(7) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to two equivalent K(1), one C(15), and one C(16) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one K(1) and one C(1) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(13) is bonded in a single-bond geometry to two equivalent K(1) and one C(10) atom. In the fourth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(25) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(26) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(27) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(28) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(29) is bonded in a single-bond geometry to one C(20) atom. O(1) is bonded in a distorted bent 120 degrees geometry to one K(1), one C(19), and one C(20) atom. Linkers: 1 COCCOC. Metal clusters: 4 [K]. The MOF has largest included sphere 2.13 A, density 1.26 g/cm3, surface area 4653.49 m2/g, accessible volume 0.13 cm3/g