CHCoC13P2N2H15O6F crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a CoC13P2N2H15O6F framework. In the CoC13P2N2H15O6F framework, Co(1) is bonded to one N(1), one N(2), one O(1), one O(2), one O(4), and one O(6) atom to form CoN2O4 octahedra that share  a cornercorner with one C(8)PH2N tetrahedra,  a cornercorner with one C(9)PH2N tetrahedra, corners with two equivalent P(1)CO3 tetrahedra, and corners with two equivalent P(2)CO3 tetrahedra. The Co(1)-N(1) bond length is 2.31 Å. The Co(1)-N(2) bond length is 2.07 Å. The Co(1)-O(1) bond length is 2.10 Å. The Co(1)-O(2) bond length is 2.01 Å. The Co(1)-O(4) bond length is 2.08 Å. The Co(1)-O(6) bond length is 2.08 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.51 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one F(1) atom. The C(4)-F(1) bond length is 1.38 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one N(1), one H(5), and one H(6) atom. The C(7)-N(1) bond length is 1.50 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. In the seventh C site, C(8) is bonded to one P(2), one N(1), one H(7), and one H(8) atom to form distorted CPH2N tetrahedra that share  a cornercorner with one Co(1)N2O4 octahedra and  a cornercorner with one C(9)PH2N tetrahedra. The corner-sharing octahedral tilt angles are 74°. The C(8)-P(2) bond length is 1.82 Å. The C(8)-N(1) bond length is 1.48 Å. The C(8)-H(7) bond length is 1.10 Å. The C(8)-H(8) bond length is 1.10 Å. In the eighth C site, C(9) is bonded to one P(1), one N(1), one H(10), and one H(9) atom to form distorted CPH2N tetrahedra that share  a cornercorner with one Co(1)N2O4 octahedra and  a cornercorner with one C(8)PH2N tetrahedra. The corner-sharing octahedral tilt angles are 72°. The C(9)-P(1) bond length is 1.82 Å. The C(9)-N(1) bond length is 1.48 Å. The C(9)-H(10) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(2), and one H(11) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(11) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(12) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-H(12) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(13) atom. The C(12)-C(12) bond length is 1.48 Å. The C(12)-C(13) bond length is 1.41 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(13) atom. The C(13)-H(13) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(14) atom. The C(14)-N(2) bond length is 1.35 Å. The C(14)-H(14) bond length is 1.09 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one C(9), one O(1), one O(2), and one O(3) atom to form distorted PCO3 tetrahedra that share corners with two equivalent Co(1)N2O4 octahedra and  a cornercorner with one N(1)CoC3 tetrahedra. The corner-sharing octahedral tilt angles range from 14-67°. The P(1)-O(1) bond length is 1.55 Å. The P(1)-O(2) bond length is 1.50 Å. The P(1)-O(3) bond length is 1.59 Å. In the second P site, P(2) is bonded to one C(8), one O(4), one O(5), and one O(6) atom to form PCO3 tetrahedra that share corners with two equivalent Co(1)N2O4 octahedra and  a cornercorner with one N(1)CoC3 tetrahedra. The corner-sharing octahedral tilt angles range from 41-61°. The P(2)-O(4) bond length is 1.55 Å. The P(2)-O(5) bond length is 1.59 Å. The P(2)-O(6) bond length is 1.51 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Co(1), one C(7), one C(8), and one C(9) atom to form NCoC3 tetrahedra that share  a cornercorner with one P(1)CO3 tetrahedra and  a cornercorner with one P(2)CO3 tetrahedra. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(10), and one C(14) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(15) is bonded in a linear geometry to one O(3) and one O(4) atom. The H(15)-O(3) bond length is 1.03 Å. The H(15)-O(4) bond length is 1.53 Å. In the fifteenth H site, H(16) is bonded in a linear geometry to one O(1) and one O(5) atom. The H(16)-O(1) bond length is 1.53 Å. The H(16)-O(5) bond length is 1.03 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Co(1), one P(1), and one H(16) atom. In the second O site, O(2) is bonded in a linear geometry to one Co(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one H(15) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Co(1), one P(2), and one H(15) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(2) and one H(16) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one P(2) atom. F(1) is bonded in a single-bond geometry to one C(4) atom. Linkers: 1 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Co]. The MOF has largest included sphere 2.68 A, density 1.76 g/cm3, surface area 3720.46 m2/g, accessible volume 0.14 cm3/g