C7N2H16ZnC4H4O9I2 is Indium-derived structured and crystallizes in the orthorhombic Pmn2_1 space group. The structure is zero-dimensional and consists of two 3-(dimethylazaniumyl)propyl-dimethylazanium molecules and two ZnC4H4O9I2 clusters. In each ZnC4H4O9I2 cluster, Zn(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), two equivalent O(2), one I(1), and one I(2) atom. The Zn(1)-O(1) bond length is 2.07 Å. Both Zn(1)-O(2) bond lengths are 2.26 Å. The Zn(1)-I(1) bond length is 2.63 Å. The Zn(1)-I(2) bond length is 2.59 Å. There are two inequivalent C sites. In the first C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(2)-O(2) bond length is 1.26 Å. The C(2)-O(3) bond length is 1.28 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(4)-O(4) bond length is 1.23 Å. The C(4)-O(5) bond length is 1.31 Å. There are two inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one O(1) and one O(3) atom. The H(10)-O(1) bond length is 1.00 Å. The H(10)-O(3) bond length is 1.71 Å. In the second H site, H(11) is bonded in a linear geometry to one O(3) and one O(5) atom. The H(11)-O(3) bond length is 1.46 Å. The H(11)-O(5) bond length is 1.06 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Zn(1) and two equivalent H(10) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Zn(1) and one C(2) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one H(10), and one H(11) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(4) and one H(11) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 1 [O]C(=O)C[NH](CC(=O)O)CCC[NH](CC(=O)O)CC(=O)[O]. Metal clusters: 2 O.O=[C]O[Zn](I)(I)O[C]=O. The MOF has largest included sphere 2.03 A, density 2.32 g/cm3, surface area 3232.95 m2/g, accessible volume 0.09 cm3/g