SmAgC26H18S2(NO4)3(CH)3 crystallizes in the triclinic P-1 space group. The structure consists of six 02329_fluka molecules inside a SmAgC26H18S2(NO4)3 framework. In the SmAgC26H18S2(NO4)3 framework, Sm(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(12), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. The Sm(1)-O(10) bond length is 2.31 Å. The Sm(1)-O(11) bond length is 2.46 Å. The Sm(1)-O(12) bond length is 2.42 Å. The Sm(1)-O(5) bond length is 2.46 Å. The Sm(1)-O(6) bond length is 2.42 Å. The Sm(1)-O(7) bond length is 2.46 Å. The Sm(1)-O(8) bond length is 2.46 Å. The Sm(1)-O(9) bond length is 2.45 Å. Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(2), one N(3), and one O(2) atom. The Ag(1)-N(1) bond length is 2.33 Å. The Ag(1)-N(2) bond length is 2.36 Å. The Ag(1)-N(3) bond length is 2.45 Å. The Ag(1)-O(2) bond length is 2.31 Å. There are twenty-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.49 Å. The C(5)-N(1) bond length is 1.35 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-N(2) bond length is 1.34 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(5) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(16), one C(7), and one C(9) atom. The C(8)-C(16) bond length is 1.48 Å. The C(8)-C(9) bond length is 1.40 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(6) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one N(2) atom. The C(10)-C(11) bond length is 1.50 Å. The C(10)-N(2) bond length is 1.34 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(3) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-N(3) bond length is 1.35 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(9) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one H(10) atom. The C(15)-N(3) bond length is 1.34 Å. The C(15)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(17), one C(21), and one C(8) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(21) bond length is 1.41 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one S(1) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-S(1) bond length is 1.80 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(11) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(11) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one S(2) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-S(2) bond length is 1.78 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(12) atom. The C(20)-H(12) bond length is 1.09 Å. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(13) atom. The C(21)-H(13) bond length is 1.09 Å. In the twentieth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(7), and one O(8) atom. The C(22)-C(23) bond length is 1.49 Å. The C(22)-O(7) bond length is 1.28 Å. The C(22)-O(8) bond length is 1.29 Å. In the twenty-first C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(28) bond length is 1.40 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(14) atom. The C(24)-H(14) bond length is 1.09 Å. In the twenty-third C site, C(26) is bonded in a distorted single-bond geometry to one C(27) and one H(16) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-H(16) bond length is 1.09 Å. In the twenty-fourth C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(29) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-C(29) bond length is 1.49 Å. In the twenty-fifth C site, C(28) is bonded in a distorted single-bond geometry to one C(23), one C(27), and one H(17) atom. The C(28)-H(17) bond length is 1.09 Å. In the twenty-sixth C site, C(29) is bonded in a bent 120 degrees geometry to one C(27), one O(10), and one O(9) atom. The C(29)-O(10) bond length is 1.27 Å. The C(29)-O(9) bond length is 1.28 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(11), and one C(15) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(26) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(28) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one O(11) and one O(3) atom. The H(18)-O(11) bond length is 1.00 Å. The H(18)-O(3) bond length is 1.70 Å. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one O(11) atom. The H(19)-O(11) bond length is 0.97 Å. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one O(12) atom. The H(20)-O(12) bond length is 0.99 Å. In the eighteenth H site, H(21) is bonded in a distorted single-bond geometry to one O(12) and one O(9) atom. The H(21)-O(12) bond length is 1.00 Å. The H(21)-O(9) bond length is 1.66 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(17), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.46 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.48 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one C(19), one O(4), one O(5), and one O(6) atom. The S(2)-O(4) bond length is 1.45 Å. The S(2)-O(5) bond length is 1.48 Å. The S(2)-O(6) bond length is 1.47 Å. There are twelve inequivalent O sites. In the first O site, O(8) is bonded in a distorted single-bond geometry to one Sm(1) and one C(22) atom. In the second O site, O(9) is bonded in a 3-coordinate geometry to one Sm(1), one C(29), and one H(21) atom. In the third O site, O(10) is bonded in a distorted linear geometry to one Sm(1) and one C(29) atom. In the fourth O site, O(11) is bonded in a distorted water-like geometry to one Sm(1), one H(18), and one H(19) atom. In the fifth O site, O(12) is bonded in a distorted water-like geometry to one Sm(1), one H(20), and one H(21) atom. In the sixth O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the seventh O site, O(2) is bonded in a bent 120 degrees geometry to one Ag(1) and one S(1) atom. In the eighth O site, O(3) is bonded in a distorted water-like geometry to one H(18) and one S(1) atom. In the ninth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the tenth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Sm(1) and one S(2) atom. In the eleventh O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Sm(1) and one S(2) atom. In the twelfth O site, O(7) is bonded in a distorted L-shaped geometry to one Sm(1) and one C(22) atom. Linkers: 1 [O]S([O])([O])c1ccc2c(c1)S([O])([O])O[Ag@@]13N4C=CC=C[C]4C4=CC(=C[C](C5=CC=C[CH]N51)N43)c1ccc(S([O])([O])[O])cc1S([O])([O])O[Ag@@]13N4[CH]C=CC=C4C4=CC2=CC(=C2C=CC=CN21)N43 ,2 [O]C(=O)c1cccc(C([O])=O)c1. Metal clusters: 1 O.O.O.O.[O][S@](=O)O[Sm]123(O[C]O[Sm](O[C]=O)(O[C]O1)O[S@@](=O)O2)O[C]O3. RCSR code: sql. The MOF has largest included sphere 2.62 A, density 1.99 g/cm3, surface area 3379.06 m2/g, accessible volume 0.12 cm3/g