Zn3C22H14(N2O3)3 crystallizes in the monoclinic P2_1 space group. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(5), one N(9), one O(1), and one O(13) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-N(5) bond length is 2.00 Å. The Zn(1)-N(9) bond length is 2.02 Å. The Zn(1)-O(1) bond length is 2.23 Å. The Zn(1)-O(13) bond length is 2.17 Å. In the second Zn site, Zn(2) is bonded in a trigonal bipyramidal geometry to one N(10), one N(2), one N(6), one O(14), and one O(2) atom. The Zn(2)-N(10) bond length is 2.04 Å. The Zn(2)-N(2) bond length is 2.00 Å. The Zn(2)-N(6) bond length is 1.99 Å. The Zn(2)-O(14) bond length is 2.16 Å. The Zn(2)-O(2) bond length is 2.20 Å. In the third Zn site, Zn(3) is bonded in a trigonal bipyramidal geometry to one N(11), one N(3), one N(7), one O(15), and one O(3) atom. The Zn(3)-N(11) bond length is 2.02 Å. The Zn(3)-N(3) bond length is 2.01 Å. The Zn(3)-N(7) bond length is 2.00 Å. The Zn(3)-O(15) bond length is 2.17 Å. The Zn(3)-O(3) bond length is 2.23 Å. In the fourth Zn site, Zn(4) is bonded in a trigonal bipyramidal geometry to one N(12), one N(4), one N(8), one O(16), and one O(4) atom. The Zn(4)-N(12) bond length is 2.04 Å. The Zn(4)-N(4) bond length is 2.00 Å. The Zn(4)-N(8) bond length is 1.99 Å. The Zn(4)-O(16) bond length is 2.16 Å. The Zn(4)-O(4) bond length is 2.20 Å. In the fifth Zn site, Zn(5) is bonded in a trigonal bipyramidal geometry to one O(10), one O(17), one O(5), one O(6), and one O(9) atom. The Zn(5)-O(10) bond length is 2.05 Å. The Zn(5)-O(17) bond length is 2.13 Å. The Zn(5)-O(5) bond length is 2.01 Å. The Zn(5)-O(6) bond length is 1.98 Å. The Zn(5)-O(9) bond length is 2.05 Å. In the sixth Zn site, Zn(6) is bonded in a trigonal bipyramidal geometry to one O(11), one O(12), one O(18), one O(7), and one O(8) atom. The Zn(6)-O(11) bond length is 2.05 Å. The Zn(6)-O(12) bond length is 2.05 Å. The Zn(6)-O(18) bond length is 2.14 Å. The Zn(6)-O(7) bond length is 2.01 Å. The Zn(6)-O(8) bond length is 1.98 Å. There are forty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(5) atom. The C(1)-C(5) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(5) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(2), and one O(6) atom. The C(2)-C(6) bond length is 1.49 Å. The C(2)-O(2) bond length is 1.27 Å. The C(2)-O(6) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(7) atom. The C(3)-C(7) bond length is 1.49 Å. The C(3)-O(3) bond length is 1.27 Å. The C(3)-O(7) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(4), and one O(8) atom. The C(4)-C(8) bond length is 1.49 Å. The C(4)-O(4) bond length is 1.27 Å. The C(4)-O(8) bond length is 1.28 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(1), one C(9), and one N(1) atom. The C(5)-C(9) bond length is 1.40 Å. The C(5)-N(1) bond length is 1.38 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(10), one C(2), and one N(2) atom. The C(6)-C(10) bond length is 1.40 Å. The C(6)-N(2) bond length is 1.38 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(11), one C(3), and one N(3) atom. The C(7)-C(11) bond length is 1.40 Å. The C(7)-N(3) bond length is 1.38 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(12), one C(4), and one N(4) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-N(4) bond length is 1.38 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(13), one C(5), and one N(5) atom. The C(9)-C(13) bond length is 1.49 Å. The C(9)-N(5) bond length is 1.38 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(14), one C(6), and one N(6) atom. The C(10)-C(14) bond length is 1.50 Å. The C(10)-N(6) bond length is 1.38 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(15), one C(7), and one N(7) atom. The C(11)-C(15) bond length is 1.49 Å. The C(11)-N(7) bond length is 1.38 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(16), one C(8), and one N(8) atom. The C(12)-C(16) bond length is 1.50 Å. The C(12)-N(8) bond length is 1.38 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(13), and one O(9) atom. The C(13)-O(13) bond length is 1.27 Å. The C(13)-O(9) bond length is 1.27 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(10), and one O(14) atom. The C(14)-O(10) bond length is 1.27 Å. The C(14)-O(14) bond length is 1.27 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(11), and one O(15) atom. The C(15)-O(11) bond length is 1.27 Å. The C(15)-O(15) bond length is 1.27 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(12), and one O(16) atom. The C(16)-O(12) bond length is 1.27 Å. The C(16)-O(16) bond length is 1.27 Å. In the seventeenth C site, C(17,19) is bonded in a trigonal planar geometry to one N(1), one N(5), and one H(5) atom. The C(17,19)-N(1) bond length is 1.34 Å. The C(17,19)-N(5) bond length is 1.34 Å. The C(17,19)-H(5) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one N(2); one N(6); and one H(6,8) atom. The C(18)-N(2) bond length is 1.34 Å. The C(18)-N(6) bond length is 1.34 Å. The C(18)-H(6,8) bond length is 1.09 Å. In the nineteenth C site, C(20) is bonded in a trigonal planar geometry to one N(4); one N(8); and one H(6,8) atom. The C(20)-N(4) bond length is 1.34 Å. The C(20)-N(8) bond length is 1.34 Å. The C(20)-H(6,8) bond length is 1.09 Å. In the twentieth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(25), one N(9), and one H(9) atom. The C(21)-C(25) bond length is 1.38 Å. The C(21)-N(9) bond length is 1.35 Å. The C(21)-H(9) bond length is 1.09 Å. In the twenty-first C site, C(22,24) is bonded in a distorted trigonal planar geometry to one C(26); one N(10); and one H(10,12) atom. The C(22,24)-C(26) bond length is 1.39 Å. The C(22,24)-N(10) bond length is 1.35 Å. The C(22,24)-H(10,12) bond length is 1.09 Å. In the twenty-second C site, C(23) is bonded in a distorted trigonal planar geometry to one C(27), one N(11), and one H(11) atom. The C(23)-C(27) bond length is 1.38 Å. The C(23)-N(11) bond length is 1.35 Å. The C(23)-H(11) bond length is 1.09 Å. In the twenty-third C site, C(25) is bonded in a distorted single-bond geometry to one C(21); one C(29); and one H(13,15) atom. The C(25)-C(29) bond length is 1.41 Å. The C(25)-H(13,15) bond length is 1.09 Å. In the twenty-fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(22,24); one C(30,32); and one H(14,16) atom. The C(26)-C(30,32) bond length is 1.41 Å. The C(26)-H(14,16) bond length is 1.09 Å. In the twenty-fifth C site, C(27) is bonded in a distorted single-bond geometry to one C(23); one C(31); and one H(13,15) atom. The C(27)-C(31) bond length is 1.41 Å. The C(27)-H(13,15) bond length is 1.09 Å. In the twenty-sixth C site, C(28) is bonded in a distorted single-bond geometry to one C(22,24); one C(30,32); and one H(14,16) atom. The C(28)-C(22,24) bond length is 1.39 Å. The C(28)-C(30,32) bond length is 1.41 Å. The C(28)-H(14,16) bond length is 1.09 Å. In the twenty-seventh C site, C(29) is bonded in a trigonal planar geometry to one C(25), one C(33), and one C(41) atom. The C(29)-C(33) bond length is 1.41 Å. The C(29)-C(41) bond length is 1.45 Å. In the twenty-eighth C site, C(30,32) is bonded in a trigonal planar geometry to one C(26), one C(34), and one C(42) atom. The C(30,32)-C(34) bond length is 1.41 Å. The C(30,32)-C(42) bond length is 1.45 Å. In the twenty-ninth C site, C(31) is bonded in a trigonal planar geometry to one C(27), one C(35), and one C(43) atom. The C(31)-C(35) bond length is 1.41 Å. The C(31)-C(43) bond length is 1.45 Å. In the thirtieth C site, C(33) is bonded in a distorted single-bond geometry to one C(29), one C(37), and one H(17) atom. The C(33)-C(37) bond length is 1.38 Å. The C(33)-H(17) bond length is 1.09 Å. In the thirty-first C site, C(34) is bonded in a distorted single-bond geometry to one C(30,32); one C(38,40); and one H(18,20) atom. The C(34)-C(38,40) bond length is 1.39 Å. The C(34)-H(18,20) bond length is 1.09 Å. In the thirty-second C site, C(35) is bonded in a distorted single-bond geometry to one C(31), one C(39), and one H(19) atom. The C(35)-C(39) bond length is 1.38 Å. The C(35)-H(19) bond length is 1.09 Å. In the thirty-third C site, C(36) is bonded in a distorted single-bond geometry to one C(30,32); one C(38,40); and one H(18,20) atom. The C(36)-C(30,32) bond length is 1.41 Å. The C(36)-C(38,40) bond length is 1.39 Å. The C(36)-H(18,20) bond length is 1.09 Å. In the thirty-fourth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(33); one N(9); and one H(21,23) atom. The C(37)-N(9) bond length is 1.35 Å. The C(37)-H(21,23) bond length is 1.09 Å. In the thirty-fifth C site, C(38,40) is bonded in a distorted trigonal planar geometry to one C(34), one N(10), and one H(22) atom. The C(38,40)-N(10) bond length is 1.35 Å. The C(38,40)-H(22) bond length is 1.09 Å. In the thirty-sixth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(35); one N(11); and one H(21,23) atom. The C(39)-N(11) bond length is 1.35 Å. The C(39)-H(21,23) bond length is 1.09 Å. In the thirty-seventh C site, C(41) is bonded in a distorted single-bond geometry to one C(29); one C(43); and one H(25,27) atom. The C(41)-C(43) bond length is 1.35 Å. The C(41)-H(25,27) bond length is 1.09 Å. In the thirty-eighth C site, C(42) is bonded in a distorted single-bond geometry to one C(30,32); one C(44); and one H(26,28) atom. The C(42)-C(44) bond length is 1.35 Å. The C(42)-H(26,28) bond length is 1.09 Å. In the thirty-ninth C site, C(43) is bonded in a distorted single-bond geometry to one C(31); one C(41); and one H(25,27) atom. The C(43)-H(25,27) bond length is 1.09 Å. In the fortieth C site, C(44) is bonded in a distorted single-bond geometry to one C(30,32); one C(42); and one H(26,28) atom. The C(44)-C(30,32) bond length is 1.45 Å. The C(44)-H(26,28) bond length is 1.09 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1); one C(17,19); and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(18), and one C(6) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Zn(3); one C(17,19); and one C(7) atom. The N(3)-C(17,19) bond length is 1.34 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Zn(4), one C(20), and one C(8) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Zn(1); one C(17,19); and one C(9) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(10), and one C(18) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Zn(3); one C(11); and one C(17,19) atom. The N(7)-C(17,19) bond length is 1.34 Å. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Zn(4), one C(12), and one C(20) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Zn(1), one C(21), and one C(37) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Zn(2); one C(22,24); and one C(38,40) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Zn(3), one C(23), and one C(39) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Zn(4); one C(22,24); and one C(38,40) atom. The N(12)-C(22,24) bond length is 1.35 Å. The N(12)-C(38,40) bond length is 1.35 Å. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(17) atom. The H(1)-O(17) bond length is 0.97 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(17) atom. The H(2)-O(17) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(18) atom. The H(3)-O(18) bond length is 0.97 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(18) atom. The H(4)-O(18) bond length is 0.98 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(17,19) atom. In the sixth H site, H(6,8) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(17,19) atom. The H(7)-C(17,19) bond length is 1.09 Å. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(10,12) is bonded in a single-bond geometry to one C(22,24) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(13,15) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(14,16) is bonded in a single-bond geometry to one C(26) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(33) atom. In the fourteenth H site, H(18,20) is bonded in a single-bond geometry to one C(34) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(35) atom. In the sixteenth H site, H(21,23) is bonded in a single-bond geometry to one C(37) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one C(38,40) atom. In the eighteenth H site, H(24) is bonded in a single-bond geometry to one C(38,40) atom. The H(24)-C(38,40) bond length is 1.09 Å. In the nineteenth H site, H(25,27) is bonded in a single-bond geometry to one C(41) atom. In the twentieth H site, H(26,28) is bonded in a single-bond geometry to one C(42) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(2) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(5) and one C(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(4) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(13) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(14) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(15) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(16) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(14) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(15) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(16) atom. In the seventeenth O site, O(17) is bonded in a distorted water-like geometry to one Zn(5), one H(1), and one H(2) atom. In the eighteenth O site, O(18) is bonded in a distorted water-like geometry to one Zn(6), one H(3), and one H(4) atom. Linkers: 4 C(=C/c1ccncc1)\c1ccncc1 ,8 [O]C(=O)[C]1N=CN=C1C([O])=O. Metal clusters: 12 [Zn]. The MOF has largest included sphere 3.13 A, density 1.71 g/cm3, surface area 3833.32 m2/g, accessible volume 0.18 cm3/g