CH2ZnC15N6H12O5F2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two ZnC15N6H12O5F2 clusters. In each ZnC15N6H12O5F2 cluster, there are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(21), one O(19), one O(5), and one O(9) atom. The Zn(1)-N(1) bond length is 2.07 Å. The Zn(1)-N(21) bond length is 2.11 Å. The Zn(1)-O(19) bond length is 2.10 Å. The Zn(1)-O(5) bond length is 2.08 Å. The Zn(1)-O(9) bond length is 2.05 Å. In the second Zn site, Zn(2) is bonded in a trigonal bipyramidal geometry to one N(2), one N(22), one O(10), one O(20), and one O(6) atom. The Zn(2)-N(2) bond length is 2.07 Å. The Zn(2)-N(22) bond length is 2.11 Å. The Zn(2)-O(10) bond length is 2.05 Å. The Zn(2)-O(20) bond length is 2.10 Å. The Zn(2)-O(6) bond length is 2.08 Å. In the third Zn site, Zn(3) is bonded in a trigonal bipyramidal geometry to one N(23,24); one N(3,4); one O(11,12); one O(18); and one O(7,8) atom. The Zn(3)-N(23,24) bond length is 2.11 Å. The Zn(3)-N(3,4) bond length is 2.07 Å. The Zn(3)-O(11,12) bond length is 2.05 Å. The Zn(3)-O(18) bond length is 2.10 Å. The Zn(3)-O(7,8) bond length is 2.08 Å. In the fourth Zn site, Zn(4) is bonded in a trigonal bipyramidal geometry to one N(23,24); one N(3,4); one O(11,12); one O(17); and one O(7,8) atom. The Zn(4)-N(23,24) bond length is 2.11 Å. The Zn(4)-N(3,4) bond length is 2.07 Å. The Zn(4)-O(11,12) bond length is 2.05 Å. The Zn(4)-O(17) bond length is 2.10 Å. The Zn(4)-O(7,8) bond length is 2.08 Å. There are thirty-six inequivalent C sites. In the first C site, C(1,3) is bonded in a trigonal planar geometry to one N(1); one N(5,7,8); and one H(1,3,4) atom. The C(1,3)-N(1) bond length is 1.34 Å. The C(1,3)-N(5,7,8) bond length is 1.34 Å. The C(1,3)-H(1,3,4) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(6), and one H(2) atom. The C(2)-N(2) bond length is 1.34 Å. The C(2)-N(6) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one N(3,4); one N(5,7,8); and one H(1,3,4) atom. The C(4)-N(3,4) bond length is 1.34 Å. The C(4)-N(5,7,8) bond length is 1.34 Å. The C(4)-H(1,3,4) bond length is 1.08 Å. In the fourth C site, C(5,7) is bonded in a trigonal planar geometry to one N(1); one N(9,11,12); and one H(5,7,8) atom. The C(5,7)-N(1) bond length is 1.37 Å. The C(5,7)-N(9,11,12) bond length is 1.32 Å. The C(5,7)-H(5,7,8) bond length is 1.08 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one N(10), one N(2), and one H(6) atom. The C(6)-N(10) bond length is 1.32 Å. The C(6)-N(2) bond length is 1.37 Å. The C(6)-H(6) bond length is 1.08 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one N(3,4); one N(9,11,12); and one H(5,7,8) atom. The C(8)-N(3,4) bond length is 1.37 Å. The C(8)-N(9,11,12) bond length is 1.32 Å. The C(8)-H(5,7,8) bond length is 1.08 Å. In the seventh C site, C(9,10,11,12) is bonded in a distorted trigonal non-coplanar geometry to one N(5,7,8); one H(13,14,15,16); and one H(9,10,11,12) atom. The C(9,10,11,12)-N(5,7,8) bond length is 1.45 Å. The C(9,10,11,12)-H(13,14,15,16) bond length is 1.09 Å. The C(9,10,11,12)-H(9,10,11,12) bond length is 1.09 Å. In the eighth C site, C(13,15,16) is bonded in a distorted single-bond geometry to one C(29,31,32) and one O(1) atom. The C(13,15,16)-C(29,31,32) bond length is 1.53 Å. The C(13,15,16)-O(1) bond length is 1.41 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(30) and one O(2) atom. The C(14)-C(30) bond length is 1.54 Å. The C(14)-O(2) bond length is 1.41 Å. In the tenth C site, C(17,18,19,20) is bonded in a distorted trigonal non-coplanar geometry to one N(13,14,15,16) and two equivalent H(17,18,19,20,21,22,23,24) atoms. The C(17,18,19,20)-N(13,14,15,16) bond length is 1.45 Å. There is one shorter (1.09 Å) and one longer (1.10 Å) C(17,18,19,20)-H(17,18,19,20,21,22,23,24) bond length. In the eleventh C site, C(21,23) is bonded in a trigonal planar geometry to one N(13,14,15,16); one N(21); and one H(25,26,27,28) atom. The C(21,23)-N(13,14,15,16) bond length is 1.34 Å. The C(21,23)-N(21) bond length is 1.34 Å. The C(21,23)-H(25,26,27,28) bond length is 1.09 Å. In the twelfth C site, C(22) is bonded in a trigonal planar geometry to one N(13,14,15,16); one N(22); and one H(25,26,27,28) atom. The C(22)-N(13,14,15,16) bond length is 1.34 Å. The C(22)-N(22) bond length is 1.34 Å. The C(22)-H(25,26,27,28) bond length is 1.09 Å. In the thirteenth C site, C(24) is bonded in a trigonal planar geometry to one N(13,14,15,16); one N(23,24); and one H(25,26,27,28) atom. The C(24)-N(13,14,15,16) bond length is 1.34 Å. The C(24)-N(23,24) bond length is 1.34 Å. The C(24)-H(25,26,27,28) bond length is 1.09 Å. In the fourteenth C site, C(25,27) is bonded in a trigonal planar geometry to one N(17,18,19,20); one N(21); and one H(29,30,31,32) atom. The C(25,27)-N(17,18,19,20) bond length is 1.33 Å. The C(25,27)-N(21) bond length is 1.37 Å. The C(25,27)-H(29,30,31,32) bond length is 1.08 Å. In the fifteenth C site, C(26) is bonded in a trigonal planar geometry to one N(17,18,19,20); one N(22); and one H(29,30,31,32) atom. The C(26)-N(17,18,19,20) bond length is 1.33 Å. The C(26)-N(22) bond length is 1.37 Å. The C(26)-H(29,30,31,32) bond length is 1.08 Å. In the sixteenth C site, C(28) is bonded in a trigonal planar geometry to one N(17,18,19,20); one N(23,24); and one H(29,30,31,32) atom. The C(28)-N(17,18,19,20) bond length is 1.33 Å. The C(28)-N(23,24) bond length is 1.37 Å. The C(28)-H(29,30,31,32) bond length is 1.08 Å. In the seventeenth C site, C(29,31,32) is bonded in a trigonal planar geometry to one C(13,15,16); one C(33); and one C(49) atom. The C(29,31,32)-C(33) bond length is 1.40 Å. The C(29,31,32)-C(49) bond length is 1.40 Å. In the eighteenth C site, C(30) is bonded in a trigonal planar geometry to one C(14); one C(34,35,36); and one C(50,51,52) atom. The C(30)-C(34,35,36) bond length is 1.40 Å. The C(30)-C(50,51,52) bond length is 1.40 Å. In the nineteenth C site, C(33) is bonded in a distorted single-bond geometry to one C(29,31,32); one C(37,39,40); and one F(1,2,3,4) atom. The C(33)-C(37,39,40) bond length is 1.39 Å. The C(33)-F(1,2,3,4) bond length is 1.37 Å. In the twentieth C site, C(34,35,36) is bonded in a distorted single-bond geometry to one C(30); one C(38); and one F(1,2,3,4) atom. The C(34,35,36)-C(38) bond length is 1.39 Å. The C(34,35,36)-F(1,2,3,4) bond length is 1.37 Å. In the twenty-first C site, C(37,39,40) is bonded in a distorted single-bond geometry to one C(33), one C(41), and one H(33) atom. The C(37,39,40)-C(41) bond length is 1.39 Å. The C(37,39,40)-H(33) bond length is 1.09 Å. In the twenty-second C site, C(38) is bonded in a distorted single-bond geometry to one C(34,35,36); one C(42,43,44); and one H(34,35,36) atom. The C(38)-C(42,43,44) bond length is 1.39 Å. The C(38)-H(34,35,36) bond length is 1.09 Å. In the twenty-third C site, C(41) is bonded in a distorted single-bond geometry to one C(37,39,40); one C(45,47,48); and one F(5,7,8) atom. The C(41)-C(45,47,48) bond length is 1.39 Å. The C(41)-F(5,7,8) bond length is 1.37 Å. In the twenty-fourth C site, C(42,43,44) is bonded in a distorted single-bond geometry to one C(38), one C(46), and one F(6) atom. The C(42,43,44)-C(46) bond length is 1.39 Å. The C(42,43,44)-F(6) bond length is 1.37 Å. In the twenty-fifth C site, C(45,47,48) is bonded in a distorted trigonal planar geometry to one C(41), one C(49), and one H(37) atom. The C(45,47,48)-C(49) bond length is 1.39 Å. The C(45,47,48)-H(37) bond length is 1.09 Å. In the twenty-sixth C site, C(46) is bonded in a distorted trigonal planar geometry to one C(42,43,44); one C(50,51,52); and one H(38,39,40) atom. The C(46)-C(50,51,52) bond length is 1.39 Å. The C(46)-H(38,39,40) bond length is 1.09 Å. In the twenty-seventh C site, C(49) is bonded in a distorted single-bond geometry to one C(29,31,32); one C(45,47,48); and one H(41,43,44) atom. The C(49)-H(41,43,44) bond length is 1.09 Å. In the twenty-eighth C site, C(50,51,52) is bonded in a distorted single-bond geometry to one C(30), one C(46), and one H(42) atom. The C(50,51,52)-H(42) bond length is 1.09 Å. In the twenty-ninth C site, C(53) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(9) atom. The C(53)-O(13) bond length is 1.26 Å. The C(53)-O(9) bond length is 1.28 Å. In the thirtieth C site, C(54) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(14) atom. The C(54)-O(10) bond length is 1.28 Å. The C(54)-O(14) bond length is 1.27 Å. In the thirty-first C site, C(55) is bonded in a distorted bent 120 degrees geometry to one O(11,12) and one O(15,16) atom. The C(55)-O(11,12) bond length is 1.28 Å. The C(55)-O(15,16) bond length is 1.26 Å. In the thirty-second C site, C(56) is bonded in a distorted bent 120 degrees geometry to one O(11,12) and one O(15,16) atom. The C(56)-O(11,12) bond length is 1.28 Å. The C(56)-O(15,16) bond length is 1.26 Å. In the thirty-third C site, C(61) is bonded in a distorted bent 120 degrees geometry to one O(17) and one O(5) atom. The C(61)-O(17) bond length is 1.27 Å. The C(61)-O(5) bond length is 1.28 Å. In the thirty-fourth C site, C(62) is bonded in a distorted bent 120 degrees geometry to one O(18) and one O(6) atom. The C(62)-O(18) bond length is 1.27 Å. The C(62)-O(6) bond length is 1.28 Å. In the thirty-fifth C site, C(63) is bonded in a distorted bent 120 degrees geometry to one O(19) and one O(7,8) atom. The C(63)-O(19) bond length is 1.27 Å. The C(63)-O(7,8) bond length is 1.28 Å. In the thirty-sixth C site, C(64) is bonded in a distorted bent 120 degrees geometry to one O(20) and one O(7,8) atom. The C(64)-O(20) bond length is 1.27 Å. The C(64)-O(7,8) bond length is 1.28 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1); one C(1,3); and one C(5,7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(2), and one C(6) atom. In the third N site, N(3,4) is bonded in a trigonal planar geometry to one Zn(3); one C(1,3); and one C(5,7) atom. The N(3,4)-C(1,3) bond length is 1.34 Å. The N(3,4)-C(5,7) bond length is 1.37 Å. In the fourth N site, N(5,7,8) is bonded in a 3-coordinate geometry to one C(1,3); one C(9,10,11,12); and one N(9,11,12) atom. The N(5,7,8)-N(9,11,12) bond length is 1.37 Å. In the fifth N site, N(6) is bonded in a 3-coordinate geometry to one C(2); one C(9,10,11,12); and one N(10) atom. The N(6)-C(9,10,11,12) bond length is 1.45 Å. The N(6)-N(10) bond length is 1.37 Å. In the sixth N site, N(9,11,12) is bonded in a distorted water-like geometry to one C(5,7) and one N(5,7,8) atom. In the seventh N site, N(10) is bonded in a distorted water-like geometry to one C(6) and one N(6) atom. In the eighth N site, N(13,14,15,16) is bonded in a distorted trigonal planar geometry to one C(17,18,19,20); one C(21,23); and one N(17,18,19,20) atom. The N(13,14,15,16)-N(17,18,19,20) bond length is 1.37 Å. In the ninth N site, N(17,18,19,20) is bonded in a water-like geometry to one C(25,27) and one N(13,14,15,16) atom. In the tenth N site, N(21) is bonded in a distorted trigonal planar geometry to one Zn(1); one C(21,23); and one C(25,27) atom. In the eleventh N site, N(22) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(22), and one C(26) atom. In the twelfth N site, N(23,24) is bonded in a distorted trigonal planar geometry to one Zn(3); one C(21,23); and one C(25,27) atom. The N(23,24)-C(21,23) bond length is 1.34 Å. The N(23,24)-C(25,27) bond length is 1.37 Å. There are nineteen inequivalent H sites. In the first H site, H(1,3,4) is bonded in a single-bond geometry to one C(1,3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5,7,8) is bonded in a single-bond geometry to one C(5,7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(9,10,11,12) is bonded in a single-bond geometry to one C(9,10,11,12) atom. In the sixth H site, H(13,14,15,16) is bonded in a single-bond geometry to one C(9,10,11,12) atom. In the seventh H site, H(17,18,19,20,21,22,23,24) is bonded in a single-bond geometry to one C(17,18,19,20) atom. In the eighth H site, H(25,26,27,28) is bonded in a single-bond geometry to one C(21,23) atom. In the ninth H site, H(29,30,31,32) is bonded in a single-bond geometry to one C(25,27) atom. In the tenth H site, H(33) is bonded in a single-bond geometry to one C(37,39,40) atom. In the eleventh H site, H(34,35,36) is bonded in a single-bond geometry to one C(38) atom. In the twelfth H site, H(37) is bonded in a single-bond geometry to one C(45,47,48) atom. In the thirteenth H site, H(38,39,40) is bonded in a single-bond geometry to one C(46) atom. In the fourteenth H site, H(41,43,44) is bonded in a single-bond geometry to one C(49) atom. In the fifteenth H site, H(42) is bonded in a single-bond geometry to one C(50,51,52) atom. In the sixteenth H site, H(53) is bonded in a distorted linear geometry to one O(1) and one O(13) atom. The H(53)-O(1) bond length is 1.02 Å. The H(53)-O(13) bond length is 1.61 Å. In the seventeenth H site, H(54) is bonded in a distorted single-bond geometry to one O(14) and one O(2) atom. The H(54)-O(14) bond length is 1.61 Å. The H(54)-O(2) bond length is 1.02 Å. In the eighteenth H site, H(55) is bonded in a distorted linear geometry to one O(15,16) and one O(3,4) atom. The H(55)-O(15,16) bond length is 1.61 Å. The H(55)-O(3,4) bond length is 1.02 Å. In the nineteenth H site, H(56) is bonded in a distorted linear geometry to one O(15,16) and one O(3,4) atom. The H(56)-O(15,16) bond length is 1.61 Å. The H(56)-O(3,4) bond length is 1.02 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(13,15,16) and one H(53) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(14) and one H(54) atom. In the third O site, O(3,4) is bonded in a water-like geometry to one C(13,15,16) and one H(55) atom. The O(3,4)-C(13,15,16) bond length is 1.41 Å. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(61) atom. In the fifth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(62) atom. In the sixth O site, O(7,8) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(63) atom. In the seventh O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(53) atom. In the eighth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(54) atom. In the ninth O site, O(11,12) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(55) atom. In the tenth O site, O(13) is bonded in a bent 120 degrees geometry to one C(53) and one H(53) atom. In the eleventh O site, O(14) is bonded in a bent 120 degrees geometry to one C(54) and one H(54) atom. In the twelfth O site, O(15,16) is bonded in a bent 120 degrees geometry to one C(55) and one H(55) atom. In the thirteenth O site, O(17) is bonded in a water-like geometry to one Zn(4) and one C(61) atom. In the fourteenth O site, O(18) is bonded in a water-like geometry to one Zn(3) and one C(62) atom. In the fifteenth O site, O(19) is bonded in a water-like geometry to one Zn(1) and one C(63) atom. In the sixteenth O site, O(20) is bonded in a water-like geometry to one Zn(2) and one C(64) atom. There are three inequivalent F sites. In the first F site, F(1,2,3,4) is bonded in a single-bond geometry to one C(33) atom. In the second F site, F(5,7,8) is bonded in a single-bond geometry to one C(41) atom. In the third F site, F(6) is bonded in a single-bond geometry to one C(42,43,44) atom. Linkers: 4 O[C@](CN1[CH]N=C[N]1)(Cn1cncn1)c1ccc(F)cc1F ,1 O[C@@](CN1[CH]N=C[N]1)(Cn1cncn1)c1ccc(F)cc1F ,3 OC(CN1[CH]N=C[N]1)(CN1[CH]N=C[N]1)c1ccc(F)cc1F ,8 [O]C(=O)CC([O])=O. Metal clusters: 2 O=[C]O[Zn]1O[C]O[Zn](O[C]=O)O[C]O[Zn](O[C]=O)O[C]O[Zn](O[C]=O)O[C]O1. The MOF has largest included sphere 2.71 A, density 1.61 g/cm3, surface area 4288.88 m2/g, accessible volume 0.19 cm3/g