(CH2)6(CH3)2ZnC6N2H6(OCl)2ZnC2N2H4(OCl)2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, four 02329_fluka molecules, two ZnC2N2H4(OCl)2 clusters, and two ZnC6N2H6(OCl)2 clusters. In each ZnC2N2H4(OCl)2 cluster, Zn(2) is bonded in a tetrahedral geometry to one O(2), one O(4), one Cl(3), and one Cl(4) atom. The Zn(2)-O(2) bond length is 2.01 Å. The Zn(2)-O(4) bond length is 2.01 Å. The Zn(2)-Cl(3) bond length is 2.27 Å. The Zn(2)-Cl(4) bond length is 2.21 Å. There are two inequivalent C sites. In the first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(4) and one O(2) atom. The C(3)-N(4) bond length is 1.32 Å. The C(3)-O(2) bond length is 1.27 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(3) and one O(4) atom. The C(5)-N(3) bond length is 1.32 Å. The C(5)-O(4) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one C(5), one H(1), and one H(2) atom. The N(3)-H(1) bond length is 1.03 Å. The N(3)-H(2) bond length is 1.03 Å. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(3), one H(5), and one H(6) atom. The N(4)-H(5) bond length is 1.02 Å. The N(4)-H(6) bond length is 1.03 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one N(4) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(3) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(5) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Zn(2) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Zn(2) atom. In each ZnC6N2H6(OCl)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one Cl(1), and one Cl(2) atom. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(3) bond length is 2.02 Å. The Zn(1)-Cl(1) bond length is 2.22 Å. The Zn(1)-Cl(2) bond length is 2.24 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(1) atom. The C(1)-N(2) bond length is 1.35 Å. The C(1)-O(1) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(3) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-O(3) bond length is 1.26 Å. In the third C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(7), and one H(8) atom. The C(6)-N(1) bond length is 1.47 Å. The C(6)-H(7) bond length is 1.10 Å. The C(6)-H(8) bond length is 1.10 Å. In the fourth C site, C(7) is bonded in a distorted water-like geometry to one N(2) and one H(9) atom. The C(7)-N(2) bond length is 1.46 Å. The C(7)-H(9) bond length is 1.10 Å. In the fifth C site, C(10) is bonded in a distorted water-like geometry to one N(1) and one H(14) atom. The C(10)-N(1) bond length is 1.46 Å. The C(10)-H(14) bond length is 1.10 Å. In the sixth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(15), and one H(16) atom. The C(11)-N(2) bond length is 1.47 Å. The C(11)-H(15) bond length is 1.10 Å. The C(11)-H(16) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(7) atom. There are six inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 4 CC[C@@H](C(N)=O)N1CCCC1=O. Metal clusters: 2 [O][Zn]([O])(Cl)Cl ,2 [Zn]. The MOF has largest included sphere 2.00 A, density 1.70 g/cm3, surface area 4647.12 m2/g, accessible volume 0.21 cm3/g