(CH)2ZnC6H8(N3Cl)2CFC4H2OF is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 3-fluoro-2-methylprop-2-en-1-ol molecules, two fluoromethane molecules, and two ZnC6H8(N3Cl)2 clusters. In each ZnC6H8(N3Cl)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(6), one Cl(1), and one Cl(2) atom. The Zn(1)-N(1) bond length is 2.05 Å. The Zn(1)-N(6) bond length is 2.02 Å. The Zn(1)-Cl(1) bond length is 2.27 Å. The Zn(1)-Cl(2) bond length is 2.23 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(3) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(3), and one H(4) atom. The C(3)-N(3) bond length is 1.45 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(4) bond length is 1.10 Å. In the fourth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(4) and two equivalent H(8,9) atoms. The C(11)-N(4) bond length is 1.46 Å. Both C(11)-H(8,9) bond lengths are 1.10 Å. In the fifth C site, C(12) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(10) atom. The C(12)-N(4) bond length is 1.37 Å. The C(12)-N(5) bond length is 1.31 Å. The C(12)-H(10) bond length is 1.08 Å. In the sixth C site, C(13) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(11) atom. The C(13)-N(4) bond length is 1.36 Å. The C(13)-N(6) bond length is 1.32 Å. The C(13)-H(11) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(1) and one N(3) atom. The N(2)-N(3) bond length is 1.37 Å. In the third N site, N(3) is bonded in a 2-coordinate geometry to one C(2), one C(3), and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(13) atom. In the fifth N site, N(5) is bonded in a distorted single-bond geometry to one C(12) and one N(6) atom. The N(5)-N(6) bond length is 1.38 Å. In the sixth N site, N(6) is bonded in a 3-coordinate geometry to one Zn(1), one C(13), and one N(5) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(8,9) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 1 O[C@](CN1[CH]N=C[N]1)(Cn1cnnc1)c1ccc(F)cc1F ,1 O[C@@](CN1[CH]N=C[N]1)(Cn1cnnc1)c1ccc(F)cc1F. Metal clusters: 2 Cl[Zn]Cl. The MOF has largest included sphere 3.36 A, density 1.66 g/cm3, surface area 4380.41 m2/g, accessible volume 0.18 cm3/g