ZnC16H12(NO2)2(CH)2(CH3)2 is Indium-derived structured and crystallizes in the orthorhombic Pnna space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, eight 02329_fluka molecules, and four ZnC16H12(NO2)2 clusters. In each ZnC16H12(NO2)2 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent O(2) atoms. Both Zn(1)-N(1) bond lengths are 2.06 Å. Both Zn(1)-O(2) bond lengths are 1.99 Å. There are eight inequivalent C sites. In the first C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(6) atom. The C(7)-C(6) bond length is 1.35 Å. The C(7)-H(6) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(8)-O(1) bond length is 1.25 Å. The C(8)-O(2) bond length is 1.30 Å. In the fourth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one H(2) atom. The C(2)-C(1) bond length is 1.38 Å. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the fifth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(4) bond length is 1.09 Å. In the sixth C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(1) atom. The C(1)-C(5) bond length is 1.41 Å. The C(1)-H(1) bond length is 1.09 Å. In the seventh C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.46 Å. In the eighth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(2), and one C(3) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(3) is bonded in a single-bond geometry to one C(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(8) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(8) atom. Linkers: 8 [O]C(=O)/C=C/c1ccncc1. Metal clusters: 4 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.62 A, density 1.35 g/cm3, surface area 5513.86 m2/g, accessible volume 0.20 cm3/g