CdC8N5H15S2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CdC8N5H15S2 clusters. Cd(1) is bonded in a distorted octahedral geometry to one N(1), one N(2), one N(3), one N(4), one N(5), and one S(1) atom. The Cd(1)-N(1) bond length is 2.38 Å. The Cd(1)-N(2) bond length is 2.37 Å. The Cd(1)-N(3) bond length is 2.52 Å. The Cd(1)-N(4) bond length is 2.48 Å. The Cd(1)-N(5) bond length is 2.30 Å. The Cd(1)-S(1) bond length is 2.67 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(3), and one H(4) atom. The C(1)-N(1) bond length is 1.47 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-H(4) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(5), and one H(6) atom. The C(2)-N(2) bond length is 1.47 Å. The C(2)-H(5) bond length is 1.10 Å. The C(2)-H(6) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(8), and one H(9) atom. The C(3)-N(2) bond length is 1.47 Å. The C(3)-H(8) bond length is 1.10 Å. The C(3)-H(9) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(10), and one H(11) atom. The C(4)-N(3) bond length is 1.48 Å. The C(4)-H(10) bond length is 1.10 Å. The C(4)-H(11) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(12), and one H(13) atom. The C(5)-N(3) bond length is 1.48 Å. The C(5)-H(12) bond length is 1.09 Å. The C(5)-H(13) bond length is 1.11 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(14), and one H(15) atom. The C(6)-N(3) bond length is 1.48 Å. The C(6)-H(14) bond length is 1.11 Å. The C(6)-H(15) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one N(4) and one S(1) atom. The C(7)-N(4) bond length is 1.18 Å. The C(7)-S(1) bond length is 1.64 Å. In the eighth C site, C(8) is bonded in a distorted linear geometry to one N(5) and one S(2) atom. The C(8)-N(5) bond length is 1.19 Å. The C(8)-S(2) bond length is 1.62 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Cd(1), one C(1), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.02 Å. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Cd(1), one C(2), one C(3), and one H(7) atom. The N(2)-H(7) bond length is 1.03 Å. In the third N site, N(3) is bonded in a distorted tetrahedral geometry to one Cd(1), one C(4), one C(5), and one C(6) atom. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(7) atom. In the fifth N site, N(5) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(8) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(3) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(4) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(4) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(5) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(5) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(6) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Cd(1) and one C(7) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(8) atom. Linkers: 2 NC[CH]N[CH]CN1CCN(CCNCCN)CC1 ,4 [CH]CNCCN1CCN(CCNCCN)CC1 ,2 NCCNCCN1CCN(CCNCCN)CC1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 2.17 A, density 1.86 g/cm3, surface area 4087.18 m2/g, accessible volume 0.12 cm3/g