Cd3C26H14(N3O2)4(CH2)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two Cd3C26H14(N3O2)4 clusters. In each Cd3C26H14(N3O2)4 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one N(1), one N(4), one N(6), one O(1), one O(3), and one O(4) atom to form distorted corner-sharing CdN3O3 pentagonal pyramids. The corner-sharing octahedral tilt angles are 76°. The Cd(1)-N(1) bond length is 2.52 Å. The Cd(1)-N(4) bond length is 2.29 Å. The Cd(1)-N(6) bond length is 2.28 Å. The Cd(1)-O(1) bond length is 2.25 Å. The Cd(1)-O(3) bond length is 2.38 Å. The Cd(1)-O(4) bond length is 2.45 Å. In the second Cd site, Cd(2) is bonded to two equivalent N(5), two equivalent O(2), and two equivalent O(4) atoms to form corner-sharing CdN2O4 octahedra. Both Cd(2)-N(5) bond lengths are 2.33 Å. Both Cd(2)-O(2) bond lengths are 2.36 Å. Both Cd(2)-O(4) bond lengths are 2.38 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(2), and one H(2) atom. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-N(2) bond length is 1.34 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.46 Å. The C(4)-N(1) bond length is 1.35 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(3), and one N(4) atom. The C(5)-N(3) bond length is 1.35 Å. The C(5)-N(4) bond length is 1.35 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(3), and one N(5) atom. The C(6)-C(7) bond length is 1.46 Å. The C(6)-N(3) bond length is 1.35 Å. The C(6)-N(5) bond length is 1.36 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.40 Å. The C(7)-C(8) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(8)-H(4) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(5) atom. The C(9)-N(6) bond length is 1.35 Å. The C(9)-H(5) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(6) atom. The C(10)-N(6) bond length is 1.35 Å. The C(10)-H(6) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(12)-O(1) bond length is 1.28 Å. The C(12)-O(2) bond length is 1.27 Å. In the thirteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(15)-O(3) bond length is 1.27 Å. The C(15)-O(4) bond length is 1.29 Å. There are six inequivalent N sites. In the first N site, N(6) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(9) atom. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(4) atom. In the third N site, N(2) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. In the fourth N site, N(3) is bonded in a water-like geometry to one C(5) and one C(6) atom. In the fifth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(5), and one N(5) atom. The N(4)-N(5) bond length is 1.34 Å. In the sixth N site, N(5) is bonded in a 3-coordinate geometry to one Cd(2), one C(6), and one N(4) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(12) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(2) and one C(12) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(15) atom. Linkers: 1 c1cc(C2=NN=C(c3cnccn3)[N]2)ccn1 ,3 n1ccc(cc1)C1=[N]=C(N=N1)c1cnccn1 ,4 [O]C(=O)CCC([O])=O. Metal clusters: 2 [C]1O[Cd]2[N][N][Cd]34([N][N][Cd](O[C]O3)O[C]O4)(O1)O[C]O2. The MOF has largest included sphere 2.11 A, density 2.09 g/cm3, surface area 3455.28 m2/g, accessible volume 0.11 cm3/g