Co4C38H27(N3O5)3 crystallizes in the triclinic P1 space group. There are seven inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(1), one N(13), one N(7), one O(1), one O(15), and one O(22) atom to form corner-sharing CoN3O3 octahedra. The corner-sharing octahedral tilt angles are 74°. The Co(1)-N(1) bond length is 2.08 Å. The Co(1)-N(13) bond length is 2.08 Å. The Co(1)-N(7) bond length is 2.07 Å. The Co(1)-O(1) bond length is 2.03 Å. The Co(1)-O(15) bond length is 2.21 Å. The Co(1)-O(22) bond length is 2.04 Å. In the second Co site, Co(2) is bonded to one N(14), one N(2), one N(8), one O(16), one O(2), and one O(21) atom to form corner-sharing CoN3O3 octahedra. The corner-sharing octahedral tilt angles are 74°. The Co(2)-N(14) bond length is 2.08 Å. The Co(2)-N(2) bond length is 2.08 Å. The Co(2)-N(8) bond length is 2.08 Å. The Co(2)-O(16) bond length is 2.21 Å. The Co(2)-O(2) bond length is 2.03 Å. The Co(2)-O(21) bond length is 2.04 Å. In the third Co site, Co(3) is bonded in a tetrahedral geometry to one N(3), one N(9), one O(20), and one O(26) atom. The Co(3)-N(3) bond length is 1.99 Å. The Co(3)-N(9) bond length is 1.97 Å. The Co(3)-O(20) bond length is 1.94 Å. The Co(3)-O(26) bond length is 1.93 Å. In the fourth Co site, Co(4) is bonded in a tetrahedral geometry to one N(10), one N(4), one O(19), and one O(25) atom. The Co(4)-N(10) bond length is 1.97 Å. The Co(4)-N(4) bond length is 1.99 Å. The Co(4)-O(19) bond length is 1.94 Å. The Co(4)-O(25) bond length is 1.93 Å. In the fifth Co site, Co(5) is bonded to one N(12), one N(15), one O(15), one O(17), one O(29), and one O(3) atom to form corner-sharing CoN2O4 octahedra. The corner-sharing octahedral tilt angles are 74°. The Co(5)-N(12) bond length is 2.05 Å. The Co(5)-N(15) bond length is 2.05 Å. The Co(5)-O(15) bond length is 2.14 Å. The Co(5)-O(17) bond length is 2.22 Å. The Co(5)-O(29) bond length is 2.22 Å. The Co(5)-O(3) bond length is 2.12 Å. In the sixth Co site, Co(6) is bonded to one N(11), one N(16), one O(16), one O(18), one O(30), and one O(4) atom to form corner-sharing CoN2O4 octahedra. The corner-sharing octahedral tilt angles are 74°. The Co(6)-N(11) bond length is 2.05 Å. The Co(6)-N(16) bond length is 2.06 Å. The Co(6)-O(16) bond length is 2.14 Å. The Co(6)-O(18) bond length is 2.22 Å. The Co(6)-O(30) bond length is 2.22 Å. The Co(6)-O(4) bond length is 2.12 Å. In the seventh Co site, Co(7,8) is bonded in a distorted trigonal bipyramidal geometry to one N(18), one N(5), one O(10), one O(6), and one O(8) atom. The Co(7,8)-N(18) bond length is 1.98 Å. The Co(7,8)-N(5) bond length is 1.98 Å. The Co(7,8)-O(10) bond length is 2.03 Å. The Co(7,8)-O(6) bond length is 1.98 Å. The Co(7,8)-O(8) bond length is 2.31 Å. There are fifty-eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(4) atom. The C(2)-C(4) bond length is 1.50 Å. The C(2)-O(2) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.28 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1); one C(13,14); and one C(5,6) atom. The C(3)-C(13,14) bond length is 1.40 Å. The C(3)-C(5,6) bond length is 1.39 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(13,14); one C(2); and one C(5,6) atom. The C(4)-C(13,14) bond length is 1.40 Å. The C(4)-C(5,6) bond length is 1.39 Å. In the fifth C site, C(5,6) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(1) atom. The C(5,6)-C(7) bond length is 1.40 Å. The C(5,6)-H(1) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(15,16); one C(5,6); and one C(9,10) atom. The C(7)-C(15,16) bond length is 1.48 Å. The C(7)-C(9,10) bond length is 1.40 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(15,16); one C(5,6); and one C(9,10) atom. The C(8)-C(15,16) bond length is 1.48 Å. The C(8)-C(5,6) bond length is 1.40 Å. The C(8)-C(9,10) bond length is 1.40 Å. In the eighth C site, C(9,10) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(7); and one H(3,4) atom. The C(9,10)-C(11,12) bond length is 1.40 Å. The C(9,10)-H(3,4) bond length is 1.09 Å. In the ninth C site, C(11,12) is bonded in a distorted single-bond geometry to one C(9,10) and one O(13,14) atom. The C(11,12)-O(13,14) bond length is 1.37 Å. In the tenth C site, C(13,14) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(13,14)-H(5) bond length is 1.09 Å. In the eleventh C site, C(15,16) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(5), and one O(7) atom. The C(15,16)-O(5) bond length is 1.30 Å. The C(15,16)-O(7) bond length is 1.27 Å. In the twelfth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one C(19,20); one H(7,8); one H(9,10); and one O(13,14) atom. The C(17)-C(19,20) bond length is 1.50 Å. The C(17)-H(7,8) bond length is 1.11 Å. The C(17)-H(9,10) bond length is 1.10 Å. The C(17)-O(13,14) bond length is 1.43 Å. In the thirteenth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one C(19,20); one H(7,8); one H(9,10); and one O(13,14) atom. The C(18)-C(19,20) bond length is 1.50 Å. The C(18)-H(7,8) bond length is 1.11 Å. The C(18)-H(9,10) bond length is 1.10 Å. The C(18)-O(13,14) bond length is 1.43 Å. In the fourteenth C site, C(19,20) is bonded in a trigonal planar geometry to one C(17), one C(21), and one C(29) atom. The C(19,20)-C(21) bond length is 1.40 Å. The C(19,20)-C(29) bond length is 1.40 Å. In the fifteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(19,20) and one H(11,12) atom. The C(21)-H(11,12) bond length is 1.09 Å. In the sixteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(19,20) and one H(11,12) atom. The C(22)-C(19,20) bond length is 1.40 Å. The C(22)-H(11,12) bond length is 1.09 Å. In the seventeenth C site, C(23,24) is bonded in a distorted single-bond geometry to one C(25) and one H(13,14) atom. The C(23,24)-C(25) bond length is 1.40 Å. The C(23,24)-H(13,14) bond length is 1.09 Å. In the eighteenth C site, C(25) is bonded in a trigonal planar geometry to one C(23,24); one C(27,28); and one C(31,32) atom. The C(25)-C(27,28) bond length is 1.41 Å. The C(25)-C(31,32) bond length is 1.46 Å. In the nineteenth C site, C(26) is bonded in a trigonal planar geometry to one C(23,24); one C(27,28); and one C(31,32) atom. The C(26)-C(23,24) bond length is 1.40 Å. The C(26)-C(27,28) bond length is 1.41 Å. The C(26)-C(31,32) bond length is 1.46 Å. In the twentieth C site, C(27,28) is bonded in a distorted single-bond geometry to one C(25); one C(29); and one H(15,16) atom. The C(27,28)-C(29) bond length is 1.39 Å. The C(27,28)-H(15,16) bond length is 1.09 Å. In the twenty-first C site, C(29) is bonded in a distorted trigonal planar geometry to one C(19,20); one C(27,28); and one H(17,18) atom. The C(29)-H(17,18) bond length is 1.09 Å. In the twenty-second C site, C(30) is bonded in a distorted trigonal planar geometry to one C(19,20); one C(27,28); and one H(17,18) atom. The C(30)-C(19,20) bond length is 1.40 Å. The C(30)-C(27,28) bond length is 1.39 Å. The C(30)-H(17,18) bond length is 1.09 Å. In the twenty-third C site, C(31,32) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(11), and one O(9) atom. The C(31,32)-O(11) bond length is 1.35 Å. The C(31,32)-O(9) bond length is 1.25 Å. In the twenty-fourth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(15), and one O(17) atom. The C(33)-C(35) bond length is 1.48 Å. The C(33)-O(15) bond length is 1.30 Å. The C(33)-O(17) bond length is 1.27 Å. In the twenty-fifth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(36), one O(16), and one O(18) atom. The C(34)-C(36) bond length is 1.48 Å. The C(34)-O(16) bond length is 1.30 Å. The C(34)-O(18) bond length is 1.27 Å. In the twenty-sixth C site, C(35) is bonded in a trigonal planar geometry to one C(33), one C(37), and one C(45) atom. The C(35)-C(37) bond length is 1.40 Å. The C(35)-C(45) bond length is 1.39 Å. In the twenty-seventh C site, C(36) is bonded in a trigonal planar geometry to one C(34), one C(38), and one C(46) atom. The C(36)-C(38) bond length is 1.40 Å. The C(36)-C(46) bond length is 1.39 Å. In the twenty-eighth C site, C(37) is bonded in a distorted single-bond geometry to one C(35); one C(39); and one H(19,20) atom. The C(37)-C(39) bond length is 1.40 Å. The C(37)-H(19,20) bond length is 1.09 Å. In the twenty-ninth C site, C(38) is bonded in a distorted single-bond geometry to one C(36); one C(40); and one H(19,20) atom. The C(38)-C(40) bond length is 1.40 Å. The C(38)-H(19,20) bond length is 1.09 Å. In the thirtieth C site, C(39) is bonded in a trigonal planar geometry to one C(37); one C(41,42); and one C(47) atom. The C(39)-C(41,42) bond length is 1.41 Å. The C(39)-C(47) bond length is 1.49 Å. In the thirty-first C site, C(40) is bonded in a trigonal planar geometry to one C(38); one C(41,42); and one C(48) atom. The C(40)-C(41,42) bond length is 1.41 Å. The C(40)-C(48) bond length is 1.49 Å. In the thirty-second C site, C(41,42) is bonded in a distorted single-bond geometry to one C(39) and one H(21,22) atom. The C(41,42)-H(21,22) bond length is 1.09 Å. In the thirty-third C site, C(43,44) is bonded in a distorted single-bond geometry to one O(27,28) atom. The C(43,44)-O(27,28) bond length is 1.36 Å. In the thirty-fourth C site, C(45) is bonded in a distorted single-bond geometry to one C(35) and one H(23,24) atom. The C(45)-H(23,24) bond length is 1.09 Å. In the thirty-fifth C site, C(46) is bonded in a distorted single-bond geometry to one C(36) and one H(23,24) atom. The C(46)-H(23,24) bond length is 1.09 Å. In the thirty-sixth C site, C(47) is bonded in a distorted bent 120 degrees geometry to one C(39), one O(19), and one O(21) atom. The C(47)-O(19) bond length is 1.29 Å. The C(47)-O(21) bond length is 1.27 Å. In the thirty-seventh C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(40), one O(20), and one O(22) atom. The C(48)-O(20) bond length is 1.29 Å. The C(48)-O(22) bond length is 1.27 Å. In the thirty-eighth C site, C(49,50) is bonded in a distorted trigonal non-coplanar geometry to one C(51,52); one H(25,26); one H(27,28); and one O(27,28) atom. The C(49,50)-C(51,52) bond length is 1.50 Å. The C(49,50)-H(25,26) bond length is 1.10 Å. The C(49,50)-H(27,28) bond length is 1.10 Å. The C(49,50)-O(27,28) bond length is 1.45 Å. In the thirty-ninth C site, C(51,52) is bonded in a trigonal planar geometry to one C(49,50); one C(53,54); and one C(61,62) atom. The C(51,52)-C(53,54) bond length is 1.40 Å. The C(51,52)-C(61,62) bond length is 1.40 Å. In the fortieth C site, C(53,54) is bonded in a distorted single-bond geometry to one C(51,52) and one H(29,30) atom. The C(53,54)-H(29,30) bond length is 1.09 Å. In the forty-first C site, C(55,56) is bonded in a distorted single-bond geometry to one C(57,58) and one H(31,32) atom. The C(55,56)-C(57,58) bond length is 1.40 Å. The C(55,56)-H(31,32) bond length is 1.09 Å. In the forty-second C site, C(57,58) is bonded in a trigonal planar geometry to one C(55,56); one C(59,60); and one C(63) atom. The C(57,58)-C(59,60) bond length is 1.40 Å. The C(57,58)-C(63) bond length is 1.50 Å. In the forty-third C site, C(59,60) is bonded in a distorted trigonal planar geometry to one C(57,58); one C(61,62); and one H(33,34) atom. The C(59,60)-C(61,62) bond length is 1.39 Å. The C(59,60)-H(33,34) bond length is 1.09 Å. In the forty-fourth C site, C(61,62) is bonded in a distorted trigonal planar geometry to one C(51,52); one C(59,60); and one H(35,36) atom. The C(61,62)-H(35,36) bond length is 1.09 Å. In the forty-fifth C site, C(63) is bonded in a distorted bent 120 degrees geometry to one C(57,58); one O(23,24); and one O(25) atom. The C(63)-O(23,24) bond length is 1.25 Å. The C(63)-O(25) bond length is 1.31 Å. In the forty-sixth C site, C(64) is bonded in a distorted bent 120 degrees geometry to one C(57,58); one O(23,24); and one O(26) atom. The C(64)-C(57,58) bond length is 1.50 Å. The C(64)-O(23,24) bond length is 1.25 Å. The C(64)-O(26) bond length is 1.31 Å. In the forty-seventh C site, C(65) is bonded in a trigonal planar geometry to one N(1); one N(5); and one H(37,38) atom. The C(65)-N(1) bond length is 1.33 Å. The C(65)-N(5) bond length is 1.36 Å. The C(65)-H(37,38) bond length is 1.08 Å. In the forty-eighth C site, C(66) is bonded in a trigonal planar geometry to one N(2); one N(6); and one H(37,38) atom. The C(66)-N(2) bond length is 1.33 Å. The C(66)-N(6) bond length is 1.36 Å. The C(66)-H(37,38) bond length is 1.08 Å. In the forty-ninth C site, C(67) is bonded in a trigonal planar geometry to one N(3); one N(5); and one H(39,40) atom. The C(67)-N(3) bond length is 1.33 Å. The C(67)-N(5) bond length is 1.36 Å. The C(67)-H(39,40) bond length is 1.08 Å. In the fiftieth C site, C(68) is bonded in a trigonal planar geometry to one N(4); one N(6); and one H(39,40) atom. The C(68)-N(4) bond length is 1.33 Å. The C(68)-N(6) bond length is 1.36 Å. The C(68)-H(39,40) bond length is 1.08 Å. In the fifty-first C site, C(69) is bonded in a trigonal planar geometry to one N(11), one N(9), and one H(41) atom. The C(69)-N(11) bond length is 1.35 Å. The C(69)-N(9) bond length is 1.34 Å. The C(69)-H(41) bond length is 1.09 Å. In the fifty-second C site, C(70) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(42) atom. The C(70)-N(10) bond length is 1.34 Å. The C(70)-N(12) bond length is 1.35 Å. The C(70)-H(42) bond length is 1.09 Å. In the fifty-third C site, C(71) is bonded in a trigonal planar geometry to one N(11); one N(7); and one H(43,44) atom. The C(71)-N(11) bond length is 1.36 Å. The C(71)-N(7) bond length is 1.33 Å. The C(71)-H(43,44) bond length is 1.08 Å. In the fifty-fourth C site, C(72) is bonded in a trigonal planar geometry to one N(12); one N(8); and one H(43,44) atom. The C(72)-N(12) bond length is 1.36 Å. The C(72)-N(8) bond length is 1.33 Å. The C(72)-H(43,44) bond length is 1.08 Å. In the fifty-fifth C site, C(73) is bonded in a trigonal planar geometry to one N(15), one N(17), and one H(45) atom. The C(73)-N(15) bond length is 1.33 Å. The C(73)-N(17) bond length is 1.36 Å. The C(73)-H(45) bond length is 1.08 Å. In the fifty-sixth C site, C(74) is bonded in a trigonal planar geometry to one N(16), one N(18), and one H(46) atom. The C(74)-N(16) bond length is 1.33 Å. The C(74)-N(18) bond length is 1.36 Å. The C(74)-H(46) bond length is 1.08 Å. In the fifty-seventh C site, C(75) is bonded in a trigonal planar geometry to one N(13); one N(17); and one H(47,48) atom. The C(75)-N(13) bond length is 1.33 Å. The C(75)-N(17) bond length is 1.36 Å. The C(75)-H(47,48) bond length is 1.08 Å. In the fifty-eighth C site, C(76) is bonded in a trigonal planar geometry to one N(14); one N(18); and one H(47,48) atom. The C(76)-N(14) bond length is 1.33 Å. The C(76)-N(18) bond length is 1.36 Å. The C(76)-H(47,48) bond length is 1.08 Å. There are eighteen inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Co(1), one C(65), and one N(3) atom. The N(1)-N(3) bond length is 1.37 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Co(2), one C(66), and one N(4) atom. The N(2)-N(4) bond length is 1.37 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Co(3), one C(67), and one N(1) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Co(4), one C(68), and one N(2) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(7,8); one C(65); and one C(67) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Co(7,8); one C(66); and one C(68) atom. The N(6)-Co(7,8) bond length is 1.98 Å. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Co(1), one C(71), and one N(9) atom. The N(7)-N(9) bond length is 1.37 Å. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Co(2), one C(72), and one N(10) atom. The N(8)-N(10) bond length is 1.37 Å. In the ninth N site, N(9) is bonded in a distorted trigonal planar geometry to one Co(3), one C(69), and one N(7) atom. In the tenth N site, N(10) is bonded in a distorted trigonal planar geometry to one Co(4), one C(70), and one N(8) atom. In the eleventh N site, N(11) is bonded in a distorted trigonal planar geometry to one Co(6), one C(69), and one C(71) atom. In the twelfth N site, N(12) is bonded in a distorted trigonal planar geometry to one Co(5), one C(70), and one C(72) atom. In the thirteenth N site, N(13) is bonded in a 3-coordinate geometry to one Co(1), one C(75), and one N(15) atom. The N(13)-N(15) bond length is 1.38 Å. In the fourteenth N site, N(14) is bonded in a 3-coordinate geometry to one Co(2), one C(76), and one N(16) atom. The N(14)-N(16) bond length is 1.38 Å. In the fifteenth N site, N(15) is bonded in a distorted trigonal planar geometry to one Co(5), one C(73), and one N(13) atom. In the sixteenth N site, N(16) is bonded in a distorted trigonal planar geometry to one Co(6), one C(74), and one N(14) atom. In the seventeenth N site, N(17) is bonded in a trigonal planar geometry to one Co(7,8); one C(73); and one C(75) atom. The N(17)-Co(7,8) bond length is 1.98 Å. In the eighteenth N site, N(18) is bonded in a trigonal planar geometry to one Co(7,8); one C(74); and one C(76) atom. There are thirty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5,6) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5,6) atom. The H(2)-C(5,6) bond length is 1.09 Å. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(9,10) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(13,14) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(13,14) atom. The H(6)-C(13,14) bond length is 1.09 Å. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(11,12) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(13,14) is bonded in a single-bond geometry to one C(23,24) atom. In the tenth H site, H(15,16) is bonded in a single-bond geometry to one C(27,28) atom. In the eleventh H site, H(17,18) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(19,20) is bonded in a single-bond geometry to one C(37) atom. In the thirteenth H site, H(21,22) is bonded in a single-bond geometry to one C(41,42) atom. In the fourteenth H site, H(23,24) is bonded in a single-bond geometry to one C(45) atom. In the fifteenth H site, H(25,26) is bonded in a single-bond geometry to one C(49,50) atom. In the sixteenth H site, H(27,28) is bonded in a single-bond geometry to one C(49,50) atom. In the seventeenth H site, H(29,30) is bonded in a single-bond geometry to one C(53,54) atom. In the eighteenth H site, H(31,32) is bonded in a single-bond geometry to one C(55,56) atom. In the nineteenth H site, H(33,34) is bonded in a single-bond geometry to one C(59,60) atom. In the twentieth H site, H(35,36) is bonded in a single-bond geometry to one C(61,62) atom. In the twenty-first H site, H(37,38) is bonded in a single-bond geometry to one C(65) atom. In the twenty-second H site, H(39,40) is bonded in a single-bond geometry to one C(67) atom. In the twenty-third H site, H(41) is bonded in a single-bond geometry to one C(69) atom. In the twenty-fourth H site, H(42) is bonded in a single-bond geometry to one C(70) atom. In the twenty-fifth H site, H(43,44) is bonded in a single-bond geometry to one C(71) atom. In the twenty-sixth H site, H(45) is bonded in a single-bond geometry to one C(73) atom. In the twenty-seventh H site, H(46) is bonded in a single-bond geometry to one C(74) atom. In the twenty-eighth H site, H(47,48) is bonded in a single-bond geometry to one C(75) atom. In the twenty-ninth H site, H(49,50) is bonded in a single-bond geometry to one O(11) atom. The H(49,50)-O(11) bond length is 0.98 Å. In the thirtieth H site, H(51) is bonded in a single-bond geometry to one O(29) atom. The H(51)-O(29) bond length is 0.98 Å. In the thirty-first H site, H(52) is bonded in a single-bond geometry to one O(30) atom. The H(52)-O(30) bond length is 0.98 Å. In the thirty-second H site, H(53) is bonded in a single-bond geometry to one O(29) atom. The H(53)-O(29) bond length is 0.97 Å. In the thirty-third H site, H(54) is bonded in a single-bond geometry to one O(30) atom. The H(54)-O(30) bond length is 0.97 Å. There are twenty-seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Co(2) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(5) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(6) and one C(2) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Co(7,8) and one C(15,16) atom. The O(5)-Co(7,8) bond length is 1.98 Å. In the sixth O site, O(6) is bonded in an L-shaped geometry to one Co(7,8) and one C(15,16) atom. The O(6)-C(15,16) bond length is 1.30 Å. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Co(7,8) and one C(15,16) atom. The O(7)-Co(7,8) bond length is 2.31 Å. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Co(7,8) and one C(15,16) atom. The O(8)-C(15,16) bond length is 1.27 Å. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Co(7,8) and one C(31,32) atom. The O(9)-Co(7,8) bond length is 2.03 Å. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Co(7,8) and one C(31,32) atom. The O(10)-C(31,32) bond length is 1.25 Å. In the eleventh O site, O(11) is bonded in a water-like geometry to one C(31,32) and one H(49,50) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one C(31,32) and one H(49,50) atom. The O(12)-C(31,32) bond length is 1.35 Å. The O(12)-H(49,50) bond length is 0.98 Å. In the thirteenth O site, O(13,14) is bonded in a bent 120 degrees geometry to one C(11,12) and one C(17) atom. In the fourteenth O site, O(15) is bonded in a 3-coordinate geometry to one Co(1), one Co(5), and one C(33) atom. In the fifteenth O site, O(16) is bonded in a 3-coordinate geometry to one Co(2), one Co(6), and one C(34) atom. In the sixteenth O site, O(17) is bonded in an L-shaped geometry to one Co(5) and one C(33) atom. In the seventeenth O site, O(18) is bonded in an L-shaped geometry to one Co(6) and one C(34) atom. In the eighteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Co(4) and one C(47) atom. In the nineteenth O site, O(20) is bonded in a bent 120 degrees geometry to one Co(3) and one C(48) atom. In the twentieth O site, O(21) is bonded in a bent 150 degrees geometry to one Co(2) and one C(47) atom. In the twenty-first O site, O(22) is bonded in a bent 150 degrees geometry to one Co(1) and one C(48) atom. In the twenty-second O site, O(23,24) is bonded in a single-bond geometry to one C(63) atom. In the twenty-third O site, O(25) is bonded in a bent 120 degrees geometry to one Co(4) and one C(63) atom. In the twenty-fourth O site, O(26) is bonded in a bent 120 degrees geometry to one Co(3) and one C(64) atom. In the twenty-fifth O site, O(27,28) is bonded in a bent 120 degrees geometry to one C(43,44) and one C(49,50) atom. In the twenty-sixth O site, O(29) is bonded in a distorted water-like geometry to one Co(5), one H(51), and one H(53) atom. In the twenty-seventh O site, O(30) is bonded in a distorted water-like geometry to one Co(6), one H(52), and one H(54) atom. Linkers: 2 [O]C(=O)c1ccc(COc2cc(C([O])=O)cc(C([O])=O)c2)cc1 ,6 C1=NN=C[N]1 ,2 [O]C(=O)c1cc(OCc2ccc(C(=O)O)cc2)cc(C([O])=O)c1. Metal clusters: 1 O.O=[C]O[Co@]12[N][N][Co]3(N=N[Co]4(O[C]O4)O[C]O3)(N=N1)O[C]O2 ,1 O.O=[C]O[Co@@]12[N][N][Co]3(N=N[Co]4(O[C]O4)O[C]O3)(N=N1)O[C]O2 ,2 O[C]O[Co]1O[C]O1. The MOF has largest included sphere 6.10 A, density 1.42 g/cm3, surface area 3791.91 m2/g, accessible volume 0.27 cm3/g