SrC6H14(O3Cl)2 crystallizes in the monoclinic C2/c space group. Sr(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. Both Sr(1)-O(1) bond lengths are 2.60 Å. Both Sr(1)-O(2) bond lengths are 2.62 Å. Both Sr(1)-O(3) bond lengths are 2.56 Å. Both Sr(1)-Cl(1) bond lengths are 2.94 Å. There are three inequivalent C sites. In the first C site, C(2) is bonded in a distorted water-like geometry to one H(2) and one O(2) atom. The C(2)-H(2) bond length is 1.10 Å. The C(2)-O(2) bond length is 1.44 Å. In the second C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(4), and one O(3) atom. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(4) bond length is 1.10 Å. The C(3)-O(3) bond length is 1.44 Å. In the third C site, C(1) is bonded in a distorted water-like geometry to one H(1) and one O(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-O(1) bond length is 1.44 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(1) and one Cl(1) atom. The H(5)-O(1) bond length is 0.99 Å. The H(5)-Cl(1) bond length is 2.13 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(2) and one Cl(1) atom. The H(6)-O(2) bond length is 0.99 Å. The H(6)-Cl(1) bond length is 2.09 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(3) and one Cl(1) atom. The H(7)-O(3) bond length is 0.99 Å. The H(7)-Cl(1) bond length is 2.15 Å. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted water-like geometry to one Sr(1), one C(2), and one H(6) atom. In the second O site, O(3) is bonded in a distorted water-like geometry to one Sr(1), one C(3), and one H(7) atom. In the third O site, O(1) is bonded in a distorted water-like geometry to one Sr(1), one C(1), and one H(5) atom. Cl(1) is bonded in a 4-coordinate geometry to one Sr(1), one H(5), one H(6), and one H(7) atom. Linkers: 1 OC[C@@H](O)[C@H](O)[C@H](O)[C@@H](O)CO. Metal clusters: 2 [Sr]. The MOF has largest included sphere 1.96 A, density 1.96 g/cm3, surface area 3644.62 m2/g, accessible volume 0.15 cm3/g