Cu2C15H12(N3I)2(CH2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and one Cu2C15H12(N3I)2 cluster. In the Cu2C15H12(N3I)2 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 2-coordinate geometry to one N(1), one N(5), one I(1), and one I(2) atom. The Cu(1)-N(1) bond length is 2.00 Å. The Cu(1)-N(5) bond length is 2.00 Å. The Cu(1)-I(1) bond length is 2.69 Å. The Cu(1)-I(2) bond length is 2.62 Å. In the second Cu site, Cu(2) is bonded in a distorted bent 120 degrees geometry to one N(3), one N(6), one I(1), and one I(2) atom. The Cu(2)-N(3) bond length is 2.00 Å. The Cu(2)-N(6) bond length is 2.00 Å. The Cu(2)-I(1) bond length is 2.69 Å. The Cu(2)-I(2) bond length is 2.70 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(1) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(2) atom. The C(2)-C(4) bond length is 1.40 Å. The C(2)-N(1) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.34 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(13), one C(2), and one N(2) atom. The C(4)-C(13) bond length is 1.51 Å. The C(4)-N(2) bond length is 1.34 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(7), one N(3), and one H(4) atom. The C(5)-C(7) bond length is 1.39 Å. The C(5)-N(3) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(3), and one H(5) atom. The C(6)-C(8) bond length is 1.40 Å. The C(6)-N(3) bond length is 1.34 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(4), and one H(6) atom. The C(7)-N(4) bond length is 1.34 Å. The C(7)-H(6) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(15), one C(6), and one N(4) atom. The C(8)-C(15) bond length is 1.51 Å. The C(8)-N(4) bond length is 1.34 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(5), and one H(7) atom. The C(9)-C(12) bond length is 1.40 Å. The C(9)-N(5) bond length is 1.35 Å. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(8) atom. The C(10)-N(5) bond length is 1.35 Å. The C(10)-H(8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(9) atom. The C(11)-N(6) bond length is 1.35 Å. The C(11)-H(9) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(17), one C(9), and one N(6) atom. The C(12)-C(17) bond length is 1.50 Å. The C(12)-N(6) bond length is 1.36 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(4) and one H(10) atom. The C(13)-H(10) bond length is 1.11 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(8) and one H(13) atom. The C(15)-H(13) bond length is 1.10 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(12) and one H(16) atom. The C(17)-H(16) bond length is 1.10 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(3) and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(2), one C(5), and one C(6) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(7) and one C(8) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(9) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(2), one C(11), and one C(12) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to one Cu(1) and one Cu(2) atom. In the second I site, I(2) is bonded in a 2-coordinate geometry to one Cu(1) and one Cu(2) atom. Linkers: 2 c1cnc([C@H]2C[C@@H](c3cnccn3)C[C@@H](c3cnccn3)C2)cn1. Metal clusters: 2 [Cu][Cu](I)I. The MOF has largest included sphere 4.56 A, density 2.01 g/cm3, surface area 3203.22 m2/g, accessible volume 0.17 cm3/g