CdC8N6H10O5(CH)8CH3CHO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four dimethyl ether molecules, four p-xylene molecules, and two CdC8N6H10O5 clusters. In each CdC8N6H10O5 cluster, Cd(1) is bonded in a distorted pentagonal pyramidal geometry to one N(1), one N(4), one O(1), one O(2), one O(4), and one O(6) atom. The Cd(1)-N(1) bond length is 2.36 Å. The Cd(1)-N(4) bond length is 2.39 Å. The Cd(1)-O(1) bond length is 2.47 Å. The Cd(1)-O(2) bond length is 2.47 Å. The Cd(1)-O(4) bond length is 2.30 Å. The Cd(1)-O(6) bond length is 2.29 Å. There are eight inequivalent C sites. In the first C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(10)-O(3) bond length is 1.27 Å. The C(10)-O(4) bond length is 1.28 Å. In the second C site, C(11) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(9) atom. The C(11)-N(1) bond length is 1.37 Å. The C(11)-N(3) bond length is 1.33 Å. The C(11)-H(9) bond length is 1.09 Å. In the third C site, C(12) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(10) atom. The C(12)-N(1) bond length is 1.33 Å. The C(12)-N(2) bond length is 1.34 Å. The C(12)-H(10) bond length is 1.08 Å. In the fourth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(11), and one H(12) atom. The C(13)-N(2) bond length is 1.45 Å. The C(13)-H(11) bond length is 1.10 Å. The C(13)-H(12) bond length is 1.10 Å. In the fifth C site, C(16) is bonded in a 3-coordinate geometry to one N(5), one H(17), and one H(18) atom. The C(16)-N(5) bond length is 1.46 Å. The C(16)-H(17) bond length is 1.10 Å. The C(16)-H(18) bond length is 1.10 Å. In the sixth C site, C(17) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(19) atom. The C(17)-N(4) bond length is 1.34 Å. The C(17)-N(5) bond length is 1.35 Å. The C(17)-H(19) bond length is 1.09 Å. In the seventh C site, C(18) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(20) atom. The C(18)-N(4) bond length is 1.36 Å. The C(18)-N(6) bond length is 1.33 Å. The C(18)-H(20) bond length is 1.08 Å. In the eighth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.29 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one C(12) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(12), one C(13), and one N(3) atom. The N(2)-N(3) bond length is 1.36 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(11) and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(17), and one C(18) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(16), one C(17), and one N(6) atom. The N(5)-N(6) bond length is 1.37 Å. In the sixth N site, N(6) is bonded in a distorted water-like geometry to one C(18) and one N(5) atom. There are ten inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(21) is bonded in a single-bond geometry to one O(6) atom. The H(21)-O(6) bond length is 1.00 Å. In the tenth H site, H(22) is bonded in a distorted linear geometry to one O(2) and one O(6) atom. The H(22)-O(2) bond length is 1.64 Å. The H(22)-O(6) bond length is 1.01 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Cd(1), one C(1), and one H(22) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one C(10) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Cd(1) and one C(10) atom. In the fifth O site, O(6) is bonded in a distorted water-like geometry to one Cd(1), one H(21), and one H(22) atom. Linkers: 4 [O]C(=O)Cc1ccc(CC([O])=O)cc1 ,3 [CH]1N=C[N]N1CCOCCN1[CH]N=C[N]1 ,1 [CH]1N=C[N]N1CCOCCn1cncn1. Metal clusters: 4 O.O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 3.61 A, density 1.55 g/cm3, surface area 4666.58 m2/g, accessible volume 0.20 cm3/g