(CH)4ZnC20N2H12(OCl)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two ZnC20N2H12(OCl)2 clusters. In each ZnC20N2H12(OCl)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one Cl(1), and one Cl(2) atom. The Zn(1)-N(1) bond length is 2.07 Å. The Zn(1)-N(2) bond length is 2.07 Å. The Zn(1)-Cl(1) bond length is 2.24 Å. The Zn(1)-Cl(2) bond length is 2.22 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-C(7) bond length is 1.45 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(1), one C(8), and one O(1) atom. The C(7)-C(8) bond length is 1.37 Å. The C(7)-O(1) bond length is 1.39 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(1), and one H(6) atom. The C(8)-N(1) bond length is 1.38 Å. The C(8)-H(6) bond length is 1.08 Å. In the seventh C site, C(9) is bonded in a distorted water-like geometry to one C(10), one N(1), and one O(1) atom. The C(9)-C(10) bond length is 1.45 Å. The C(9)-N(1) bond length is 1.32 Å. The C(9)-O(1) bond length is 1.36 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-C(12) bond length is 1.41 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(19) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(18) bond length is 1.41 Å. The C(13)-C(19) bond length is 1.44 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(9) atom. The C(14)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(12) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(12) bond length is 1.09 Å. In the fourteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(13), one C(17), and one H(13) atom. The C(18)-H(13) bond length is 1.09 Å. In the fifteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(13), one C(20), and one O(2) atom. The C(19)-C(20) bond length is 1.37 Å. The C(19)-O(2) bond length is 1.39 Å. In the sixteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(2), and one H(14) atom. The C(20)-N(2) bond length is 1.38 Å. The C(20)-H(14) bond length is 1.08 Å. In the seventeenth C site, C(21) is bonded in a distorted water-like geometry to one C(22), one N(2), and one O(2) atom. The C(21)-C(22) bond length is 1.45 Å. The C(21)-N(2) bond length is 1.32 Å. The C(21)-O(2) bond length is 1.36 Å. In the eighteenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(24) atom. The C(22)-C(23) bond length is 1.41 Å. The C(22)-C(24) bond length is 1.41 Å. In the nineteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(15) atom. The C(23)-H(15) bond length is 1.09 Å. In the twentieth C site, C(24) is bonded in a distorted single-bond geometry to one C(22) and one H(16) atom. The C(24)-H(16) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(8), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(20), and one C(21) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(7) and one C(9) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(19) and one C(21) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 2 c1ccc(-c2cnc(-c3ccc(-c4ncc(-c5ccccc5)o4)cc3)o2)cc1 ,2 [CH]=[C]c1cnc(-c2ccc(-c3ncc(-c4ccccc4)o3)cc2)o1 ,2 [CH]=C[C]c1cnc(-c2ccc(-c3ncc(-c4ccccc4)o3)cc2)o1. Metal clusters: 2 Cl[Zn]Cl. The MOF has largest included sphere 2.57 A, density 1.56 g/cm3, surface area 4697.66 m2/g, accessible volume 0.16 cm3/g