AgC9H6S(NO)2(CH)2CF3 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight trifluoromethane molecules, and four AgC9H6S(NO)2 clusters. In each AgC9H6S(NO)2 cluster, Ag(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one O(2), and two equivalent O(1) atoms. The Ag(1)-N(1) bond length is 2.20 Å. The Ag(1)-N(2) bond length is 2.19 Å. The Ag(1)-O(2) bond length is 2.68 Å. There is one shorter (2.65 Å) and one longer (2.70 Å) Ag(1)-O(1) bond length. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one S(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-S(1) bond length is 1.77 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5) atom. The C(6)-N(2) bond length is 1.35 Å. The C(6)-H(5) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(6) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(7), one C(9), and one S(1) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-S(1) bond length is 1.75 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one N(2) and one H(8) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(8) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(11)-O(1) bond length is 1.26 Å. The C(11)-O(2) bond length is 1.26 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(10), and one C(6) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. S(1) is bonded in a water-like geometry to one C(1) and one C(8) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Ag(1) and one C(11) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Ag(1) and one C(11) atom. Linkers: 4 c1ccc(Sc2ccncc2)nc1. Metal clusters: 2 [Ag].[Ag].[O]C(=O)C(F)(F)F.[O]C(=O)C(F)(F)F. The MOF has largest included sphere 1.96 A, density 2.03 g/cm3, surface area 3802.66 m2/g, accessible volume 0.08 cm3/g