NiC14H12(N2O3)2(CH2)2(H2O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two water molecules, and one NiC14H12(N2O3)2 cluster. In the NiC14H12(N2O3)2 cluster, Ni(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(2) atoms. Both Ni(1)-N(1) bond lengths are 1.90 Å. Both Ni(1)-O(2) bond lengths are 1.86 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.50 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one O(1) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-O(1) bond length is 1.26 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(7)-O(2) bond length is 1.29 Å. The C(7)-O(3) bond length is 1.26 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(6), one H(7), and one H(8) atom. The N(2)-H(7) bond length is 1.03 Å. The N(2)-H(8) bond length is 1.03 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(7) atom. Linkers: 1 [O]C(=O)CCC([O])=O. Metal clusters: 1 [Ni]. The MOF has largest included sphere 1.92 A, density 1.67 g/cm3, surface area 4256.81 m2/g, accessible volume 0.09 cm3/g