CdC14H10(N3O)4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CdC14H10(N3O)4 clusters. Cd(1) is bonded in a distorted hexagonal bipyramidal geometry to two equivalent N(1), two equivalent N(6), two equivalent O(1), and two equivalent O(2) atoms. Both Cd(1)-N(1) bond lengths are 2.53 Å. Both Cd(1)-N(6) bond lengths are 2.48 Å. Both Cd(1)-O(1) bond lengths are 2.37 Å. Both Cd(1)-O(2) bond lengths are 2.58 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(3) atom. The C(3)-N(2) bond length is 1.34 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one N(2) atom. The C(4)-C(5) bond length is 1.47 Å. The C(4)-N(1) bond length is 1.35 Å. The C(4)-N(2) bond length is 1.34 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(3), and one N(6) atom. The C(5)-N(3) bond length is 1.34 Å. The C(5)-N(6) bond length is 1.36 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(4), and one H(5) atom. The C(6)-N(4) bond length is 1.45 Å. The C(6)-H(4) bond length is 1.10 Å. The C(6)-H(5) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(7)-O(1) bond length is 1.27 Å. The C(7)-O(2) bond length is 1.26 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(3) and one C(4) atom. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(5) and one N(4) atom. The N(3)-N(4) bond length is 1.33 Å. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one C(6), one N(3), and one N(5) atom. The N(4)-N(5) bond length is 1.34 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.31 Å. In the sixth N site, N(6) is bonded in a 3-coordinate geometry to one Cd(1), one C(5), and one N(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(7) atom. Linkers: 3 [O]C(=O)CN1[N]N=C(c2ncccn2)[N]1 ,1 [O]C(=O)Cn1nnc(-c2ncccn2)n1. Metal clusters: 2 O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 2.02 A, density 1.91 g/cm3, surface area 3879.35 m2/g, accessible volume 0.11 cm3/g