Zn4C24N3H15O13 crystallizes in the cubic Pa-3 space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1) and three equivalent O(4) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.96 Å. All Zn(1)-O(4) bond lengths are 1.97 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(1) bond length is 1.95 Å. The Zn(2)-O(2) bond length is 1.99 Å. The Zn(2)-O(3) bond length is 1.95 Å. The Zn(2)-O(5) bond length is 1.96 Å. There are eight inequivalent C sites. In the first C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one H(5) atom. The C(6)-C(1) bond length is 1.41 Å. The C(6)-C(5) bond length is 1.38 Å. The C(6)-H(5) bond length is 1.09 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.43 Å. The C(1)-C(7) bond length is 1.48 Å. In the third C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(2), and one O(3) atom. The C(7)-O(2) bond length is 1.29 Å. The C(7)-O(3) bond length is 1.28 Å. In the fourth C site, C(2) is bonded in a single-bond geometry to one C(1) and one N(1) atom. The C(2)-N(1) bond length is 1.36 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(4), and one O(5) atom. The C(8)-C(4) bond length is 1.49 Å. The C(8)-O(4) bond length is 1.28 Å. The C(8)-O(5) bond length is 1.28 Å. In the sixth C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.09 Å. In the seventh C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.41 Å. In the eighth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one C(2), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.01 Å. There are five inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. There are five inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(7) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(8) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(7) atom. In the fifth O site, O(1) is bonded in a tetrahedral geometry to one Zn(1) and three equivalent Zn(2) atoms. Linkers: 24 Nc1cc(C([O])=O)ccc1C([O])=O. Metal clusters: 8 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: pcu. The MOF has largest included sphere 13.60 A, density 0.68 g/cm3, surface area 3830.79 m2/g, accessible volume 1.10 cm3/g