CdC32H28(NO)4(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CdC32H28(NO)4 clusters. In each CdC32H28(NO)4 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.29 Å. The Cd(1)-N(2) bond length is 2.29 Å. The Cd(1)-O(1) bond length is 2.37 Å. The Cd(1)-O(2) bond length is 2.37 Å. The Cd(1)-O(3) bond length is 2.46 Å. The Cd(1)-O(4) bond length is 2.47 Å. There are thirty-two inequivalent C sites. In the first C site, C(34) is bonded in a distorted trigonal planar geometry to one C(24), one C(32), and one H(32) atom. The C(34)-C(24) bond length is 1.40 Å. The C(34)-C(32) bond length is 1.40 Å. The C(34)-H(32) bond length is 1.09 Å. In the second C site, C(33) is bonded in a distorted trigonal planar geometry to one C(23), one C(31), and one H(31) atom. The C(33)-C(23) bond length is 1.40 Å. The C(33)-C(31) bond length is 1.40 Å. The C(33)-H(31) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(3); one H(1,2); one H(3,4); and one H(5,6) atom. The C(1)-C(3) bond length is 1.48 Å. The C(1)-H(1,2) bond length is 1.09 Å. The C(1)-H(3,4) bond length is 1.10 Å. The C(1)-H(5,6) bond length is 1.10 Å. In the fourth C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one C(4); one H(1,2); one H(3,4); and one H(5,6) atom. The C(2)-C(4) bond length is 1.48 Å. The C(2)-H(1,2) bond length is 1.09 Å. The C(2)-H(3,4) bond length is 1.10 Å. The C(2)-H(5,6) bond length is 1.10 Å. In the fifth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one N(3) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-N(3) bond length is 1.37 Å. In the sixth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one N(4) atom. The C(4)-N(2) bond length is 1.34 Å. The C(4)-N(4) bond length is 1.37 Å. In the seventh C site, C(5) is bonded in a distorted single-bond geometry to one C(15), one C(7), and one N(3) atom. The C(5)-C(15) bond length is 1.40 Å. The C(5)-C(7) bond length is 1.42 Å. The C(5)-N(3) bond length is 1.39 Å. In the eighth C site, C(6) is bonded in a distorted single-bond geometry to one C(16), one C(8), and one N(4) atom. The C(6)-C(16) bond length is 1.40 Å. The C(6)-C(8) bond length is 1.42 Å. The C(6)-N(4) bond length is 1.39 Å. In the ninth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one N(1) atom. The C(7)-C(9) bond length is 1.40 Å. The C(7)-N(1) bond length is 1.39 Å. In the tenth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one N(2) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-N(2) bond length is 1.39 Å. In the eleventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(11), one C(7), and one H(7) atom. The C(9)-C(11) bond length is 1.39 Å. The C(9)-H(7) bond length is 1.09 Å. In the twelfth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one H(8) atom. The C(10)-C(12) bond length is 1.39 Å. The C(10)-H(8) bond length is 1.09 Å. In the thirteenth C site, C(11) is bonded in a distorted single-bond geometry to one C(13), one C(9), and one H(9) atom. The C(11)-C(13) bond length is 1.41 Å. The C(11)-H(9) bond length is 1.09 Å. In the fourteenth C site, C(12) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one H(10) atom. The C(12)-C(14) bond length is 1.41 Å. The C(12)-H(10) bond length is 1.09 Å. In the fifteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(11), one C(15), and one H(11) atom. The C(13)-C(15) bond length is 1.39 Å. The C(13)-H(11) bond length is 1.09 Å. In the sixteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(12), one C(16), and one H(12) atom. The C(14)-C(16) bond length is 1.39 Å. The C(14)-H(12) bond length is 1.09 Å. In the seventeenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(13), one C(5), and one H(13) atom. The C(15)-H(13) bond length is 1.09 Å. In the eighteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(14), one C(6), and one H(14) atom. The C(16)-H(14) bond length is 1.09 Å. In the nineteenth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one N(3); one H(15,16); and one H(17,18) atom. The C(17)-N(3) bond length is 1.46 Å. The C(17)-H(15,16) bond length is 1.10 Å. The C(17)-H(17,18) bond length is 1.10 Å. In the twentieth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one N(4); one H(15,16); and one H(17,18) atom. The C(18)-N(4) bond length is 1.46 Å. The C(18)-H(15,16) bond length is 1.10 Å. The C(18)-H(17,18) bond length is 1.10 Å. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(1), and one O(3) atom. The C(21)-C(23) bond length is 1.50 Å. The C(21)-O(1) bond length is 1.29 Å. The C(21)-O(3) bond length is 1.27 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(2), and one O(4) atom. The C(22)-C(24) bond length is 1.50 Å. The C(22)-O(2) bond length is 1.29 Å. The C(22)-O(4) bond length is 1.27 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(33) atom. The C(23)-C(25) bond length is 1.40 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(22), one C(26), and one C(34) atom. The C(24)-C(26) bond length is 1.40 Å. In the twenty-fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(23); one C(27); and one H(23,24) atom. The C(25)-C(27) bond length is 1.39 Å. The C(25)-H(23,24) bond length is 1.09 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(24); one C(28); and one H(23,24) atom. The C(26)-C(28) bond length is 1.39 Å. The C(26)-H(23,24) bond length is 1.09 Å. In the twenty-seventh C site, C(27) is bonded in a distorted trigonal planar geometry to one C(25); one C(29); and one H(25,26) atom. The C(27)-C(29) bond length is 1.40 Å. The C(27)-H(25,26) bond length is 1.09 Å. In the twenty-eighth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(26); one C(30); and one H(25,26) atom. The C(28)-C(30) bond length is 1.40 Å. The C(28)-H(25,26) bond length is 1.09 Å. In the twenty-ninth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(27), one C(31), and one H(27) atom. The C(29)-C(31) bond length is 1.40 Å. The C(29)-H(27) bond length is 1.09 Å. In the thirtieth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(28), one C(32), and one H(28) atom. The C(30)-C(32) bond length is 1.40 Å. The C(30)-H(28) bond length is 1.09 Å. In the thirty-first C site, C(31) is bonded in a distorted single-bond geometry to one C(29), one C(33), and one H(29) atom. The C(31)-H(29) bond length is 1.09 Å. In the thirty-second C site, C(32) is bonded in a distorted single-bond geometry to one C(30), one C(34), and one H(30) atom. The C(32)-H(30) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(3), and one C(7) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(4), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(17), one C(3), and one C(5) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(18), one C(4), and one C(6) atom. There are twenty-one inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(15,16) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(17,18) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(23,24) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(25,26) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(27) is bonded in a single-bond geometry to one C(29) atom. In the seventeenth H site, H(28) is bonded in a single-bond geometry to one C(30) atom. In the eighteenth H site, H(29) is bonded in a single-bond geometry to one C(31) atom. In the nineteenth H site, H(30) is bonded in a single-bond geometry to one C(32) atom. In the twentieth H site, H(31) is bonded in a single-bond geometry to one C(33) atom. In the twenty-first H site, H(32) is bonded in a single-bond geometry to one C(34) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(21) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(22) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(21) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(22) atom. Linkers: 2 Cc1nc2ccccc2n1CCCCn1c(C)nc2ccccc21 ,2 [CH2]c1nc2[c]cccc2n1CCCCn1c(C)nc2ccccc21. Metal clusters: 2 [Cd]. The MOF has largest included sphere 2.67 A, density 1.45 g/cm3, surface area 5141.78 m2/g, accessible volume 0.20 cm3/g