CuC4H4(NCl)2C7H6S2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C7H6S2 clusters and four CuC4H4(NCl)2 clusters. In each C7H6S2 cluster, there are four inequivalent C sites. In the first C site, C(1) is bonded in a water-like geometry to two equivalent H(1) and two equivalent S(1) atoms. Both C(1)-H(1) bond lengths are 1.10 Å. Both C(1)-S(1) bond lengths are 1.81 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one S(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-S(1) bond length is 1.74 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. S(1) is bonded in a water-like geometry to one C(1) and one C(4) atom. In each CuC4H4(NCl)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent Cl(1) atoms. Both Cu(1)-N(1) bond lengths are 2.00 Å. Both Cu(1)-Cl(1) bond lengths are 2.27 Å. There are two inequivalent C sites. In the first C site, C(2) is bonded in a distorted trigonal planar geometry to one N(1) and one H(2) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(6)-N(1) bond length is 1.35 Å. The C(6)-H(5) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(2), and one C(6) atom. There are two inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 2 c1cc(SCSc2ccncc2)ccn1. Metal clusters: 2 Cl[Cu]Cl. The MOF has largest included sphere 4.95 A, density 1.11 g/cm3, surface area 4262.16 m2/g, accessible volume 0.43 cm3/g