Cu2C17H18(NO)6(CH3)2 crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of eight 02329_fluka molecules inside a Cu2C17H18(NO)6 framework. In the Cu2C17H18(NO)6 framework, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square pyramidal geometry to one N(3), one N(6), one O(1), one O(2), and one O(6) atom. The Cu(1)-N(3) bond length is 1.94 Å. The Cu(1)-N(6) bond length is 1.91 Å. The Cu(1)-O(1) bond length is 2.03 Å. The Cu(1)-O(2) bond length is 2.06 Å. The Cu(1)-O(6) bond length is 2.33 Å. In the second Cu site, Cu(2) is bonded in a square pyramidal geometry to one N(4), one N(5), one O(3), one O(4), and one O(5) atom. The Cu(2)-N(4) bond length is 1.92 Å. The Cu(2)-N(5) bond length is 1.96 Å. The Cu(2)-O(3) bond length is 2.05 Å. The Cu(2)-O(4) bond length is 2.10 Å. The Cu(2)-O(5) bond length is 2.34 Å. There are seventeen inequivalent C sites. In the first C site, C(7) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(9) atom. The C(7)-C(13) bond length is 1.40 Å. The C(7)-C(14) bond length is 1.51 Å. The C(7)-C(9) bond length is 1.41 Å. In the second C site, C(8) is bonded in a 2-coordinate geometry to one N(6) and one H(2) atom. The C(8)-N(6) bond length is 1.44 Å. The C(8)-H(2) bond length is 1.10 Å. In the third C site, C(9) is bonded in a distorted trigonal planar geometry to one C(15), one C(7), and one N(5) atom. The C(9)-C(15) bond length is 1.49 Å. The C(9)-N(5) bond length is 1.35 Å. In the fourth C site, C(10) is bonded in a 3-coordinate geometry to one C(17), one C(2), and one N(2) atom. The C(10)-C(17) bond length is 1.49 Å. The C(10)-C(2) bond length is 1.41 Å. The C(10)-N(2) bond length is 1.35 Å. In the fifth C site, C(11) is bonded in a 2-coordinate geometry to one N(4) and one H(3) atom. The C(11)-N(4) bond length is 1.45 Å. The C(11)-H(3) bond length is 1.10 Å. In the sixth C site, C(13) is bonded in a 3-coordinate geometry to one C(16), one C(7), and one N(1) atom. The C(13)-C(16) bond length is 1.49 Å. The C(13)-N(1) bond length is 1.35 Å. In the seventh C site, C(14) is bonded in a water-like geometry to one C(2), one C(7), one H(7), and one H(8) atom. The C(14)-C(2) bond length is 1.51 Å. The C(14)-H(7) bond length is 1.10 Å. The C(14)-H(8) bond length is 1.10 Å. In the eighth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(10), one H(11), and one H(9) atom. The C(15)-H(10) bond length is 1.10 Å. The C(15)-H(11) bond length is 1.10 Å. The C(15)-H(9) bond length is 1.10 Å. In the ninth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one C(13), one H(12), one H(13), and one H(14) atom. The C(16)-H(12) bond length is 1.10 Å. The C(16)-H(13) bond length is 1.10 Å. The C(16)-H(14) bond length is 1.10 Å. In the tenth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one H(15), one H(16), and one H(17) atom. The C(17)-H(15) bond length is 1.10 Å. The C(17)-H(16) bond length is 1.10 Å. The C(17)-H(17) bond length is 1.10 Å. In the eleventh C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one H(18), one H(19), and one H(20) atom. The C(18)-C(6) bond length is 1.49 Å. The C(18)-H(18) bond length is 1.10 Å. The C(18)-H(19) bond length is 1.09 Å. The C(18)-H(20) bond length is 1.10 Å. In the twelfth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(6) and one O(4) atom. The C(1)-N(6) bond length is 1.31 Å. The C(1)-O(4) bond length is 1.28 Å. In the thirteenth C site, C(2) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(6) atom. The C(2)-C(6) bond length is 1.41 Å. In the fourteenth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(4) and one O(2) atom. The C(3)-N(4) bond length is 1.31 Å. The C(3)-O(2) bond length is 1.28 Å. In the fifteenth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(5) atom. The C(4)-O(1) bond length is 1.30 Å. The C(4)-O(5) bond length is 1.25 Å. In the sixteenth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(6) atom. The C(5)-O(3) bond length is 1.30 Å. The C(5)-O(6) bond length is 1.25 Å. In the seventeenth C site, C(6) is bonded in a 3-coordinate geometry to one C(18), one C(2), and one N(3) atom. The C(6)-N(3) bond length is 1.35 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a 1-coordinate geometry to one C(13), one N(5), and one H(21) atom. The N(1)-N(5) bond length is 1.35 Å. The N(1)-H(21) bond length is 1.05 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one C(10), one N(3), and one H(1) atom. The N(2)-N(3) bond length is 1.35 Å. The N(2)-H(1) bond length is 1.05 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(6), and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(11), and one C(3) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(9), and one N(1) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(8) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one N(2) and one O(3) atom. The H(1)-O(3) bond length is 1.67 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the eighteenth H site, H(21) is bonded in a distorted single-bond geometry to one N(1) and one O(1) atom. The H(21)-O(1) bond length is 1.68 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(4), and one H(21) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cu(1) and one C(3) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(5), and one H(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cu(2) and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(4) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Cu(1) and one C(5) atom. Linkers: 4 C[C@H]([N]C(=O)C(=O)[N][C@@H](C)C([O])=O)C([O])=O ,4 Cc1n[nH]c(C)c1Cc1c(C)n[nH]c1C. Metal clusters: 8 [Cu]. The MOF has largest included sphere 5.01 A, density 1.25 g/cm3, surface area 4534.40 m2/g, accessible volume 0.43 cm3/g