CdC14H10(NO2)2(CH)8 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two o-xylene molecules and one CdC14H10(NO2)2 cluster. In the CdC14H10(NO2)2 cluster, Cd(1) is bonded to one N(1), one N(2), one O(1), one O(2), one O(3), and two equivalent O(4) atoms to form distorted edge-sharing CdN2O5 pentagonal bipyramids. The Cd(1)-N(1) bond length is 2.34 Å. The Cd(1)-N(2) bond length is 2.34 Å. The Cd(1)-O(1) bond length is 2.60 Å. The Cd(1)-O(2) bond length is 2.38 Å. The Cd(1)-O(3) bond length is 2.43 Å. There is one shorter (2.34 Å) and one longer (2.67 Å) Cd(1)-O(4) bond length. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(10) is bonded in a bent 120 degrees geometry to one O(3) and one O(4) atom. The C(10)-O(3) bond length is 1.27 Å. The C(10)-O(4) bond length is 1.27 Å. In the third C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(11)-N(2) bond length is 1.35 Å. The C(11)-H(9) bond length is 1.09 Å. In the fourth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-H(10) bond length is 1.09 Å. In the fifth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(22) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(22) bond length is 1.45 Å. In the sixth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(11) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(11) bond length is 1.09 Å. In the seventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(2), and one H(12) atom. The C(15)-N(2) bond length is 1.35 Å. The C(15)-H(12) bond length is 1.09 Å. In the eighth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(16)-N(1) bond length is 1.34 Å. The C(16)-H(13) bond length is 1.09 Å. In the ninth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(14) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(14) bond length is 1.09 Å. In the tenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(21) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-C(21) bond length is 1.45 Å. In the eleventh C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(15) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-H(15) bond length is 1.09 Å. In the twelfth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one N(1), and one H(16) atom. The C(20)-N(1) bond length is 1.35 Å. The C(20)-H(16) bond length is 1.09 Å. In the thirteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(18) and one H(17) atom. The C(21)-H(17) bond length is 1.09 Å. In the fourteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(13) and one H(18) atom. The C(22)-H(18) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(16), and one C(20) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(15) atom. There are ten inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(10) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(10) atom. Linkers: 2 [O]C(=O)Cc1ccccc1CC([O])=O. Metal clusters: 1 O=[C]O[Cd]1O[C]O[Cd](O[C]=O)O[C]O1. The MOF has largest included sphere 2.04 A, density 1.73 g/cm3, surface area 4285.51 m2/g, accessible volume 0.09 cm3/g