ZnC9H8(NO2)2CH(CH3)2 crystallizes in the monoclinic P2_1 space group. The structure consists of six 02329_fluka molecules and twelve 02329_fluka molecules inside a ZnC9H8(NO2)2 framework. In the ZnC9H8(NO2)2 framework, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted trigonal bipyramidal geometry to one N(2), one N(4), one O(1), one O(4), and one O(7) atom. The Zn(1)-N(2) bond length is 2.07 Å. The Zn(1)-N(4) bond length is 2.00 Å. The Zn(1)-O(1) bond length is 2.09 Å. The Zn(1)-O(4) bond length is 2.40 Å. The Zn(1)-O(7) bond length is 1.95 Å. In the second Zn site, Zn(2) is bonded in a distorted trigonal bipyramidal geometry to one N(3), one N(5), one O(2), one O(5), and one O(8) atom. The Zn(2)-N(3) bond length is 2.07 Å. The Zn(2)-N(5) bond length is 2.00 Å. The Zn(2)-O(2) bond length is 2.09 Å. The Zn(2)-O(5) bond length is 2.39 Å. The Zn(2)-O(8) bond length is 1.95 Å. In the third Zn site, Zn(3) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(6), one O(3), one O(6), and one O(9) atom. The Zn(3)-N(1) bond length is 2.07 Å. The Zn(3)-N(6) bond length is 1.99 Å. The Zn(3)-O(3) bond length is 2.09 Å. The Zn(3)-O(6) bond length is 2.40 Å. The Zn(3)-O(9) bond length is 1.95 Å. There are twenty-four inequivalent C sites. In the first C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one C(22), one N(4), one H(16), and one H(19) atom. The C(19)-C(22) bond length is 1.51 Å. The C(19)-N(4) bond length is 1.45 Å. The C(19)-H(16) bond length is 1.10 Å. The C(19)-H(19) bond length is 1.11 Å. In the second C site, C(20) is bonded in a distorted trigonal non-coplanar geometry to one C(23,24); one N(5); one H(17,18); and one H(20,21) atom. The C(20)-C(23,24) bond length is 1.51 Å. The C(20)-N(5) bond length is 1.45 Å. The C(20)-H(17,18) bond length is 1.10 Å. The C(20)-H(20,21) bond length is 1.11 Å. In the third C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one C(23,24); one N(6); one H(17,18); and one H(20,21) atom. The C(21)-C(23,24) bond length is 1.51 Å. The C(21)-N(6) bond length is 1.45 Å. The C(21)-H(17,18) bond length is 1.10 Å. The C(21)-H(20,21) bond length is 1.11 Å. In the fourth C site, C(22) is bonded in a trigonal planar geometry to one C(10,11); one C(19); and one C(25,26) atom. The C(22)-C(10,11) bond length is 1.40 Å. The C(22)-C(25,26) bond length is 1.40 Å. In the fifth C site, C(23,24) is bonded in a trigonal planar geometry to one C(10,11); one C(20); and one C(25,26) atom. The C(23,24)-C(10,11) bond length is 1.40 Å. The C(23,24)-C(25,26) bond length is 1.40 Å. In the sixth C site, C(25,26) is bonded in a distorted single-bond geometry to one C(22) and one H(22) atom. The C(25,26)-H(22) bond length is 1.09 Å. In the seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(23,24) and one H(23,24) atom. The C(27)-C(23,24) bond length is 1.40 Å. The C(27)-H(23,24) bond length is 1.09 Å. In the eighth C site, C(34) is bonded in a trigonal planar geometry to one H(43,44); one O(10,11); and one O(7) atom. The C(34)-H(43,44) bond length is 1.11 Å. The C(34)-O(10,11) bond length is 1.24 Å. The C(34)-O(7) bond length is 1.30 Å. In the ninth C site, C(35) is bonded in a trigonal planar geometry to one H(43,44); one O(10,11); and one O(8) atom. The C(35)-H(43,44) bond length is 1.11 Å. The C(35)-O(10,11) bond length is 1.24 Å. The C(35)-O(8) bond length is 1.30 Å. In the tenth C site, C(36) is bonded in a trigonal planar geometry to one H(45), one O(12), and one O(9) atom. The C(36)-H(45) bond length is 1.11 Å. The C(36)-O(12) bond length is 1.24 Å. The C(36)-O(9) bond length is 1.30 Å. In the eleventh C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(4) bond length is 1.25 Å. In the twelfth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(5) atom. The C(2)-O(2) bond length is 1.26 Å. The C(2)-O(5) bond length is 1.25 Å. In the thirteenth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(6) atom. The C(3)-O(3) bond length is 1.26 Å. The C(3)-O(6) bond length is 1.25 Å. In the fourteenth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(10,11); one N(1); and one H(1,2) atom. The C(4)-C(10,11) bond length is 1.39 Å. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(1,2) bond length is 1.09 Å. In the fifteenth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(10,11); one N(2); and one H(1,2) atom. The C(5)-C(10,11) bond length is 1.39 Å. The C(5)-N(2) bond length is 1.35 Å. The C(5)-H(1,2) bond length is 1.09 Å. In the sixteenth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(3), and one H(3) atom. The C(6)-C(12) bond length is 1.39 Å. The C(6)-N(3) bond length is 1.35 Å. The C(6)-H(3) bond length is 1.09 Å. In the seventeenth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4,5,6) atom. The C(7)-N(1) bond length is 1.35 Å. The C(7)-H(4,5,6) bond length is 1.09 Å. In the eighteenth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(4,5,6) atom. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(4,5,6) bond length is 1.09 Å. In the nineteenth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(4,5,6) atom. The C(9)-N(3) bond length is 1.35 Å. The C(9)-H(4,5,6) bond length is 1.09 Å. In the twentieth C site, C(10,11) is bonded in a distorted trigonal planar geometry to one C(22), one C(4), and one H(7) atom. The C(10,11)-H(7) bond length is 1.09 Å. In the twenty-first C site, C(12) is bonded in a distorted trigonal planar geometry to one C(23,24); one C(6); and one H(8,9) atom. The C(12)-C(23,24) bond length is 1.40 Å. The C(12)-H(8,9) bond length is 1.09 Å. In the twenty-second C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(10) atom. The C(13)-N(4) bond length is 1.40 Å. The C(13)-H(10) bond length is 1.10 Å. In the twenty-third C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(11,12) atom. The C(14)-N(5) bond length is 1.40 Å. The C(14)-H(11,12) bond length is 1.10 Å. In the twenty-fourth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(11,12) atom. The C(15)-N(6) bond length is 1.40 Å. The C(15)-H(11,12) bond length is 1.10 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(3), one C(4), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(5), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(6), and one C(9) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(19) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(2), one C(14), and one C(20) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(3), one C(15), and one C(21) atom. There are fifteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4,5,6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(10,11) atom. In the fifth H site, H(8,9) is bonded in a single-bond geometry to one C(10,11) atom. The H(8,9)-C(10,11) bond length is 1.09 Å. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(17,18) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(20,21) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(25,26) atom. In the thirteenth H site, H(23,24) is bonded in a single-bond geometry to one C(25,26) atom. The H(23,24)-C(25,26) bond length is 1.09 Å. In the fourteenth H site, H(43,44) is bonded in a single-bond geometry to one C(34) atom. In the fifteenth H site, H(45) is bonded in a single-bond geometry to one C(36) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Zn(1) and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Zn(2) and one C(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Zn(3) and one C(3) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(34) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(35) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(36) atom. In the tenth O site, O(10,11) is bonded in a single-bond geometry to one C(34) atom. In the eleventh O site, O(12) is bonded in a single-bond geometry to one C(36) atom. Linkers: 6 CC(C)[C@H]([N]Cc1ccncc1)C([O])=O. Metal clusters: 6 [Zn]. The MOF has largest included sphere 9.22 A, density 1.14 g/cm3, surface area 4838.87 m2/g, accessible volume 0.45 cm3/g