CuC12H6(NO2)2(CH)6(CH2CO)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules, eight dimethyl ether molecules, and four CuC12H6(NO2)2 clusters. In each CuC12H6(NO2)2 cluster, Cu(1) is bonded in a 6-coordinate geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(3) atoms. Both Cu(1)-N(1) bond lengths are 2.00 Å. Both Cu(1)-O(1) bond lengths are 2.00 Å. Both Cu(1)-O(3) bond lengths are 2.56 Å. There are six inequivalent C sites. In the first C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(7) atom. The C(8)-C(10) bond length is 1.41 Å. The C(8)-C(11) bond length is 1.44 Å. The C(8)-C(7) bond length is 1.41 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(3) bond length is 1.25 Å. In the third C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(10)-H(7) bond length is 1.09 Å. In the fourth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(2)-N(1) bond length is 1.33 Å. The C(2)-H(1) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(11)-H(8) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(7), one C(8), and one N(1) atom. The C(7)-C(7) bond length is 1.43 Å. The C(7)-N(1) bond length is 1.36 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(2), and one C(7) atom. There are three inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Cu(1) and one C(1) atom. Linkers: 2 [O]C(=O)COc1ccc(OCC([O])=O)cc1. Metal clusters: 2 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 1.81 A, density 1.66 g/cm3, surface area 4458.96 m2/g, accessible volume 0.16 cm3/g