CuC9N2H10O5CH3(CH)7 crystallizes in the monoclinic P2_1 space group. The structure consists of six 02329_fluka molecules, two 02329_fluka molecules, and two isobutylene molecules inside a CuC9N2H10O5 framework. In the CuC9N2H10O5 framework, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one N(2), one O(1), one O(2), and one O(3) atom. The Cu(1)-N(1) bond length is 2.05 Å. The Cu(1)-N(2) bond length is 2.00 Å. The Cu(1)-O(1) bond length is 1.98 Å. The Cu(1)-O(2) bond length is 1.97 Å. The Cu(1)-O(3) bond length is 2.27 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(1)-O(2) bond length is 1.29 Å. The C(1)-O(4) bond length is 1.26 Å. In the second C site, C(3) is bonded in a 2-coordinate geometry to one N(1) and one H(7) atom. The C(3)-N(1) bond length is 1.48 Å. The C(3)-H(7) bond length is 1.10 Å. In the third C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one N(1), one H(8), and one H(9) atom. The C(4)-C(9) bond length is 1.51 Å. The C(4)-N(1) bond length is 1.48 Å. The C(4)-H(8) bond length is 1.10 Å. The C(4)-H(9) bond length is 1.10 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(5) atom. The C(5)-O(1) bond length is 1.29 Å. The C(5)-O(5) bond length is 1.25 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(10), one N(2), and one H(12) atom. The C(7)-C(10) bond length is 1.39 Å. The C(7)-N(2) bond length is 1.35 Å. The C(7)-H(12) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(4) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(11) bond length is 1.40 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(13) atom. The C(10)-H(13) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(9) and one H(14) atom. The C(11)-H(14) bond length is 1.09 Å. In the ninth C site, C(13) is bonded in a distorted trigonal planar geometry to one N(2) and one H(16) atom. The C(13)-N(2) bond length is 1.34 Å. The C(13)-H(16) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted tetrahedral geometry to one Cu(1), one C(3), one C(4), and one H(1) atom. The N(1)-H(1) bond length is 1.03 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(7) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) and one O(5) atom. The H(2)-O(3) bond length is 1.00 Å. The H(2)-O(5) bond length is 1.72 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(3) and one O(4) atom. The H(3)-O(3) bond length is 1.00 Å. The H(3)-O(4) bond length is 1.68 Å. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(13) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(5) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cu(1), one H(2), and one H(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one C(1) and one H(3) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. Linkers: 2 [O]C(=O)[C@H](Cc1ccccc1)NCc1ccncc1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.41 A, density 1.51 g/cm3, surface area 4813.12 m2/g, accessible volume 0.19 cm3/g