ZnC20H14(NO3)2(C4H3)2(C5H3)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four perylene molecules, four C4H3 clusters, and four ZnC20H14(NO3)2 clusters. In each C4H3 cluster, there are eight inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(2) bond length is 1.41 Å. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.45 Å. In the second C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(9) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-C(8) bond length is 1.41 Å. The C(9)-H(9) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(4)-H(5) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(7) atom. The C(6)-C(7) bond length is 1.35 Å. The C(6)-H(7) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(8) atom. The C(7)-C(8) bond length is 1.45 Å. The C(7)-H(8) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.41 Å. In the seventh C site, C(10) is bonded in a distorted trigonal planar geometry to one C(8), one C(9), and one H(10) atom. The C(10)-H(10) bond length is 1.09 Å. In the eighth C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(2)-H(4) bond length is 1.09 Å. There are six inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In each ZnC20H14(NO3)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(4) atom. The Zn(1)-N(1) bond length is 2.02 Å. The Zn(1)-N(2) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 1.95 Å. The Zn(1)-O(4) bond length is 1.95 Å. There are twenty inequivalent C sites. In the first C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(11) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(2) bond length is 1.35 Å. The C(11)-H(11) bond length is 1.09 Å. In the second C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(12) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-H(12) bond length is 1.09 Å. In the third C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(16) bond length is 1.45 Å. In the fourth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(13) atom. The C(14)-C(15) bond length is 1.38 Å. The C(14)-H(13) bond length is 1.09 Å. In the fifth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(2), and one H(14) atom. The C(15)-N(2) bond length is 1.35 Å. The C(15)-H(14) bond length is 1.09 Å. In the sixth C site, C(16) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one H(15) atom. The C(16)-C(17) bond length is 1.36 Å. The C(16)-H(15) bond length is 1.09 Å. In the seventh C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(16) atom. The C(17)-C(18) bond length is 1.45 Å. The C(17)-H(16) bond length is 1.09 Å. In the eighth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(20) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-C(20) bond length is 1.41 Å. In the ninth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(17) atom. The C(19)-H(17) bond length is 1.09 Å. In the tenth C site, C(20) is bonded in a distorted single-bond geometry to one C(18) and one H(18) atom. The C(20)-H(18) bond length is 1.09 Å. In the eleventh C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(1), and one O(2) atom. The C(21)-C(22) bond length is 1.48 Å. The C(21)-O(1) bond length is 1.28 Å. The C(21)-O(2) bond length is 1.27 Å. In the twelfth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(24) atom. The C(22)-C(23) bond length is 1.42 Å. The C(22)-C(24) bond length is 1.40 Å. In the thirteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one O(3) atom. The C(23)-O(3) bond length is 1.36 Å. In the fourteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(22) and one H(19) atom. The C(24)-H(19) bond length is 1.09 Å. In the fifteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(4), and one O(5) atom. The C(25)-C(26) bond length is 1.48 Å. The C(25)-O(4) bond length is 1.28 Å. The C(25)-O(5) bond length is 1.28 Å. In the sixteenth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(28) atom. The C(26)-C(27) bond length is 1.42 Å. The C(26)-C(28) bond length is 1.40 Å. In the seventeenth C site, C(27) is bonded in a distorted single-bond geometry to one C(26), one C(28), and one O(6) atom. The C(27)-C(28) bond length is 1.39 Å. The C(27)-O(6) bond length is 1.36 Å. In the eighteenth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(26), one C(27), and one H(20) atom. The C(28)-H(20) bond length is 1.09 Å. In the nineteenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(3) bond length is 1.09 Å. In the twentieth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(6) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(15) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a bent 150 degrees geometry to one O(2) and one O(3) atom. The H(1)-O(2) bond length is 1.56 Å. The H(1)-O(3) bond length is 1.02 Å. In the second H site, H(2) is bonded in a bent 150 degrees geometry to one O(5) and one O(6) atom. The H(2)-O(5) bond length is 1.57 Å. The H(2)-O(6) bond length is 1.02 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(28) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(21) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(21) and one H(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(23) and one H(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one C(25) and one H(2) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one C(27) and one H(2) atom. Linkers: 4 C(=C/c1ccc(/C=C/c2ccncc2)cc1)\c1ccncc1 ,4 [O]C(=O)c1cc(O)c(C([O])=O)cc1O ,2 [CH]=C(/C=C\[N])/C=C/c1ccc(/C=C/c2ccncc2)cc1. Metal clusters: 4 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.62 A, density 1.42 g/cm3, surface area 5026.47 m2/g, accessible volume 0.16 cm3/g