Cd3C14H8S6(N5O)2 crystallizes in the monoclinic Cc space group. There are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted octahedral geometry to one N(2), one N(4), one N(7), one N(8), one S(5), and one S(6) atom. The Cd(1)-N(2) bond length is 2.41 Å. The Cd(1)-N(4) bond length is 2.41 Å. The Cd(1)-N(7) bond length is 2.28 Å. The Cd(1)-N(8) bond length is 2.28 Å. The Cd(1)-S(5) bond length is 2.77 Å. The Cd(1)-S(6) bond length is 2.77 Å. In the second Cd site, Cd(2) is bonded to one N(6), one N(9), one S(1), one S(3), one O(1), and one O(2) atom to form distorted edge-sharing CdS2N2O2 octahedra. The Cd(2)-N(6) bond length is 2.24 Å. The Cd(2)-N(9) bond length is 2.21 Å. The Cd(2)-S(1) bond length is 2.74 Å. The Cd(2)-S(3) bond length is 2.69 Å. The Cd(2)-O(1) bond length is 2.50 Å. The Cd(2)-O(2) bond length is 2.44 Å. In the third Cd site, Cd(3) is bonded to one N(10), one N(5), one S(2), one S(4), one O(1), and one O(2) atom to form distorted edge-sharing CdS2N2O2 octahedra. The Cd(3)-N(10) bond length is 2.22 Å. The Cd(3)-N(5) bond length is 2.24 Å. The Cd(3)-S(2) bond length is 2.73 Å. The Cd(3)-S(4) bond length is 2.69 Å. The Cd(3)-O(1) bond length is 2.50 Å. The Cd(3)-O(2) bond length is 2.44 Å. There are ten inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one C(3,4); one N(1); and one H(1,2) atom. The C(1,2)-C(3,4) bond length is 1.38 Å. The C(1,2)-N(1) bond length is 1.36 Å. The C(1,2)-H(1,2) bond length is 1.08 Å. In the second C site, C(3,4) is bonded in a distorted trigonal planar geometry to one C(1,2); one N(2); and one H(3,4) atom. The C(3,4)-N(2) bond length is 1.34 Å. The C(3,4)-H(3,4) bond length is 1.09 Å. In the third C site, C(5,6) is bonded in a distorted trigonal planar geometry to one C(7,8); one N(3); and one H(5,6) atom. The C(5,6)-C(7,8) bond length is 1.38 Å. The C(5,6)-N(3) bond length is 1.36 Å. The C(5,6)-H(5,6) bond length is 1.09 Å. In the fourth C site, C(7,8) is bonded in a distorted trigonal planar geometry to one C(5,6); one N(4); and one H(7,8) atom. The C(7,8)-N(4) bond length is 1.34 Å. The C(7,8)-H(7,8) bond length is 1.09 Å. In the fifth C site, C(9) is bonded in a distorted linear geometry to one N(5) and one S(1) atom. The C(9)-N(5) bond length is 1.18 Å. The C(9)-S(1) bond length is 1.63 Å. In the sixth C site, C(10) is bonded in a distorted linear geometry to one N(6) and one S(2) atom. The C(10)-N(6) bond length is 1.18 Å. The C(10)-S(2) bond length is 1.63 Å. In the seventh C site, C(11) is bonded in a distorted linear geometry to one N(7) and one S(3) atom. The C(11)-N(7) bond length is 1.18 Å. The C(11)-S(3) bond length is 1.63 Å. In the eighth C site, C(12) is bonded in a distorted linear geometry to one N(8) and one S(4) atom. The C(12)-N(8) bond length is 1.18 Å. The C(12)-S(4) bond length is 1.63 Å. In the ninth C site, C(13) is bonded in a distorted linear geometry to one N(9) and one S(5) atom. The C(13)-N(9) bond length is 1.18 Å. The C(13)-S(5) bond length is 1.62 Å. In the tenth C site, C(14) is bonded in a distorted linear geometry to one N(10) and one S(6) atom. The C(14)-N(10) bond length is 1.18 Å. The C(14)-S(6) bond length is 1.62 Å. There are ten inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to two equivalent C(5,6) and one O(2) atom. The N(3)-O(2) bond length is 1.31 Å. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cd(1) and two equivalent C(7,8) atoms. In the third N site, N(5) is bonded in a distorted bent 150 degrees geometry to one Cd(3) and one C(9) atom. In the fourth N site, N(6) is bonded in a distorted bent 150 degrees geometry to one Cd(2) and one C(10) atom. In the fifth N site, N(7) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(11) atom. In the sixth N site, N(8) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(12) atom. In the seventh N site, N(9) is bonded in a linear geometry to one Cd(2) and one C(13) atom. In the eighth N site, N(10) is bonded in a linear geometry to one Cd(3) and one C(14) atom. In the ninth N site, N(1) is bonded in a trigonal planar geometry to two equivalent C(1,2) and one O(1) atom. The N(1)-O(1) bond length is 1.31 Å. In the tenth N site, N(2) is bonded in a trigonal planar geometry to one Cd(1) and two equivalent C(3,4) atoms. There are four inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(3,4) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(5,6) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(7,8) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Cd(2) and one C(9) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Cd(3) and one C(10) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one Cd(2) and one C(11) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one Cd(3) and one C(12) atom. In the fifth S site, S(5) is bonded in an L-shaped geometry to one Cd(1) and one C(13) atom. In the sixth S site, S(6) is bonded in an L-shaped geometry to one Cd(1) and one C(14) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cd(2), one Cd(3), and one N(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Cd(2), one Cd(3), and one N(3) atom. Linkers: 3 [O-][n+]1ccncc1. Metal clusters: 6 [Cd]. The MOF has largest included sphere 2.24 A, density 2.30 g/cm3, surface area 3416.16 m2/g, accessible volume 0.05 cm3/g