Cd3C14H8(N5S3)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(4), and two equivalent S(1) atoms. Both Cd(1)-N(2) bond lengths are 2.29 Å. Both Cd(1)-N(4) bond lengths are 2.38 Å. Both Cd(1)-S(1) bond lengths are 2.74 Å. In the second Cd site, Cd(2) is bonded to two equivalent N(1), two equivalent S(2), and two equivalent S(3) atoms to form corner-sharing CdS4N2 octahedra. The corner-sharing octahedral tilt angles are 50°. Both Cd(2)-N(1) bond lengths are 2.27 Å. Both Cd(2)-S(2) bond lengths are 2.77 Å. Both Cd(2)-S(3) bond lengths are 2.74 Å. In the third Cd site, Cd(3) is bonded to two equivalent N(3), two equivalent N(5), and two equivalent S(2) atoms to form corner-sharing CdS2N4 octahedra. The corner-sharing octahedral tilt angles are 50°. Both Cd(3)-N(3) bond lengths are 2.27 Å. Both Cd(3)-N(5) bond lengths are 2.40 Å. Both Cd(3)-S(2) bond lengths are 2.76 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.63 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(2) atom. The C(2)-N(2) bond length is 1.18 Å. The C(2)-S(2) bond length is 1.64 Å. In the third C site, C(3) is bonded in a distorted linear geometry to one N(3) and one S(3) atom. The C(3)-N(3) bond length is 1.18 Å. The C(3)-S(3) bond length is 1.63 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(1) atom. The C(4)-N(4) bond length is 1.34 Å. The C(4)-N(5) bond length is 1.34 Å. The C(4)-H(1) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(5), and one H(2) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(5) bond length is 1.34 Å. The C(5)-H(2) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(3) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one N(4), and one H(4) atom. The C(7)-N(4) bond length is 1.34 Å. The C(7)-H(4) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Cd(2) and one C(1) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(2) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one Cd(3) and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(4), and one C(7) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cd(3), one C(4), and one C(5) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. In the second S site, S(2) is bonded in a distorted T-shaped geometry to one Cd(2), one Cd(3), and one C(2) atom. In the third S site, S(3) is bonded in a water-like geometry to one Cd(2) and one C(3) atom. Linkers: 2 c1cncnc1. Metal clusters: 3 [Cd]. The MOF has largest included sphere 2.05 A, density 2.28 g/cm3, surface area 3442.61 m2/g, accessible volume 0.09 cm3/g