La2CuC32N2H28S4O19 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(17), one O(18), one O(2), one O(3), one O(5), and one O(9) atom. The La(1)-O(10) bond length is 2.49 Å. The La(1)-O(12) bond length is 2.53 Å. The La(1)-O(17) bond length is 2.45 Å. The La(1)-O(18) bond length is 2.52 Å. The La(1)-O(2) bond length is 2.69 Å. The La(1)-O(3) bond length is 2.46 Å. The La(1)-O(5) bond length is 2.52 Å. The La(1)-O(9) bond length is 2.53 Å. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(13), one O(15), one O(16), one O(19), one O(4), one O(7), one O(8), and one O(9) atom. The La(2)-O(13) bond length is 2.39 Å. The La(2)-O(15) bond length is 2.48 Å. The La(2)-O(16) bond length is 2.51 Å. The La(2)-O(19) bond length is 2.47 Å. The La(2)-O(4) bond length is 2.43 Å. The La(2)-O(7) bond length is 2.50 Å. The La(2)-O(8) bond length is 2.52 Å. The La(2)-O(9) bond length is 2.91 Å. Cu(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(11), one O(14), and one O(6) atom. The Cu(1)-O(1) bond length is 1.95 Å. The Cu(1)-O(11) bond length is 1.95 Å. The Cu(1)-O(14) bond length is 2.00 Å. The Cu(1)-O(6) bond length is 1.97 Å. There are thirty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(5), and one S(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(5) bond length is 1.47 Å. The C(1)-S(1) bond length is 1.72 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(6), and one S(1) atom. The C(4)-C(6) bond length is 1.49 Å. The C(4)-S(1) bond length is 1.72 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(3) atom. The C(5)-O(1) bond length is 1.28 Å. The C(5)-O(3) bond length is 1.27 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(4), and one O(5) atom. The C(6)-O(4) bond length is 1.27 Å. The C(6)-O(5) bond length is 1.28 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(8), and one S(2) atom. The C(7)-C(11) bond length is 1.48 Å. The C(7)-C(8) bond length is 1.39 Å. The C(7)-S(2) bond length is 1.72 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(3) atom. The C(8)-H(3) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(4) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(4) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(12), one C(9), and one S(2) atom. The C(10)-C(12) bond length is 1.47 Å. The C(10)-S(2) bond length is 1.72 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(6), and one O(7) atom. The C(11)-O(6) bond length is 1.28 Å. The C(11)-O(7) bond length is 1.27 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(8), and one O(9) atom. The C(12)-O(8) bond length is 1.28 Å. The C(12)-O(9) bond length is 1.28 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(17), and one S(3) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-C(17) bond length is 1.48 Å. The C(13)-S(3) bond length is 1.72 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(5) atom. The C(14)-H(5) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(6) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(6) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(18), and one S(3) atom. The C(16)-C(18) bond length is 1.48 Å. The C(16)-S(3) bond length is 1.72 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(10), and one O(11) atom. The C(17)-O(10) bond length is 1.27 Å. The C(17)-O(11) bond length is 1.28 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(12), and one O(13) atom. The C(18)-O(12) bond length is 1.27 Å. The C(18)-O(13) bond length is 1.28 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(20), one C(23), and one S(4) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-C(23) bond length is 1.47 Å. The C(19)-S(4) bond length is 1.72 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(7) atom. The C(20)-H(7) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(8) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(8) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(24), and one S(4) atom. The C(22)-C(24) bond length is 1.48 Å. The C(22)-S(4) bond length is 1.72 Å. In the twenty-third C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(14), and one O(15) atom. The C(23)-O(14) bond length is 1.29 Å. The C(23)-O(15) bond length is 1.26 Å. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(16), and one O(17) atom. The C(24)-O(16) bond length is 1.28 Å. The C(24)-O(17) bond length is 1.27 Å. In the twenty-fifth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one N(1), and one O(18) atom. The C(25)-C(26) bond length is 1.51 Å. The C(25)-N(1) bond length is 1.35 Å. The C(25)-O(18) bond length is 1.26 Å. In the twenty-sixth C site, C(26) is bonded in a trigonal non-coplanar geometry to one C(25), one H(10), one H(11), and one H(9) atom. The C(26)-H(10) bond length is 1.10 Å. The C(26)-H(11) bond length is 1.09 Å. The C(26)-H(9) bond length is 1.10 Å. In the twenty-seventh C site, C(27) is bonded to one N(1), one H(12), one H(13), and one H(14) atom to form corner-sharing CH3N tetrahedra. The C(27)-N(1) bond length is 1.46 Å. The C(27)-H(12) bond length is 1.09 Å. The C(27)-H(13) bond length is 1.10 Å. The C(27)-H(14) bond length is 1.10 Å. In the twenty-eighth C site, C(28) is bonded to one N(1), one H(15), one H(16), and one H(17) atom to form corner-sharing CH3N tetrahedra. The C(28)-N(1) bond length is 1.46 Å. The C(28)-H(15) bond length is 1.09 Å. The C(28)-H(16) bond length is 1.10 Å. The C(28)-H(17) bond length is 1.10 Å. In the twenty-ninth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(30), one N(2), and one O(19) atom. The C(29)-C(30) bond length is 1.51 Å. The C(29)-N(2) bond length is 1.34 Å. The C(29)-O(19) bond length is 1.26 Å. In the thirtieth C site, C(30) is bonded in a trigonal non-coplanar geometry to one C(29), one H(18), one H(19), and one H(20) atom. The C(30)-H(18) bond length is 1.10 Å. The C(30)-H(19) bond length is 1.10 Å. The C(30)-H(20) bond length is 1.09 Å. In the thirty-first C site, C(31) is bonded to one N(2), one H(21), one H(22), and one H(23) atom to form corner-sharing CH3N tetrahedra. The C(31)-N(2) bond length is 1.46 Å. The C(31)-H(21) bond length is 1.09 Å. The C(31)-H(22) bond length is 1.10 Å. The C(31)-H(23) bond length is 1.10 Å. In the thirty-second C site, C(32) is bonded to one N(2), one H(24), one H(25), and one H(26) atom to form corner-sharing CH3N tetrahedra. The C(32)-N(2) bond length is 1.45 Å. The C(32)-H(24) bond length is 1.09 Å. The C(32)-H(25) bond length is 1.10 Å. The C(32)-H(26) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(28) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(32) atom. There are twenty-eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(26) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(27) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(27) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(27) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(28) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(28) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(28) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(30) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(30) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(31) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(31) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(32) atom. In the twenty-fifth H site, H(25) is bonded in a single-bond geometry to one C(32) atom. In the twenty-sixth H site, H(26) is bonded in a single-bond geometry to one C(32) atom. In the twenty-seventh H site, H(27) is bonded in a single-bond geometry to one O(2) atom. The H(27)-O(2) bond length is 0.97 Å. In the twenty-eighth H site, H(28) is bonded in a single-bond geometry to one O(2) atom. The H(28)-O(2) bond length is 0.98 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(1) and one C(4) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one C(10) and one C(7) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one C(13) and one C(16) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one C(19) and one C(22) atom. There are nineteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(5) atom. In the second O site, O(2) is bonded in a water-like geometry to one La(1), one H(27), and one H(28) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one La(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one La(2) and one C(6) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one La(1) and one C(6) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(11) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one La(2) and one C(11) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one La(2) and one C(12) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one La(1), one La(2), and one C(12) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one La(1) and one C(17) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(17) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one La(1) and one C(18) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one La(2) and one C(18) atom. In the fourteenth O site, O(14) is bonded in a distorted water-like geometry to one Cu(1) and one C(23) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one La(2) and one C(23) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one La(2) and one C(24) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one La(1) and one C(24) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one La(1) and one C(25) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 150 degrees geometry to one La(2) and one C(29) atom. Linkers: 16 [O]C(=O)c1ccc(C([O])=O)s1. Metal clusters: 8 [La] ,4 [Cu]. The MOF has largest included sphere 4.91 A, density 1.73 g/cm3, surface area 3642.71 m2/g, accessible volume 0.16 cm3/g