Ag2C6H5SO7CH crystallizes in the monoclinic P2/c space group. The structure consists of four 02329_fluka molecules inside a Ag2C6H5SO7 framework. In the Ag2C6H5SO7 framework, there are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(7) atoms to form distorted corner-sharing AgO6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 70-85°. Both Ag(1)-O(1) bond lengths are 2.60 Å. Both Ag(1)-O(2) bond lengths are 2.61 Å. Both Ag(1)-O(7) bond lengths are 2.43 Å. In the second Ag site, Ag(2) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(7) atoms to form distorted corner-sharing AgO6 octahedra. Both Ag(2)-O(2) bond lengths are 2.42 Å. Both Ag(2)-O(3) bond lengths are 2.52 Å. Both Ag(2)-O(7) bond lengths are 2.64 Å. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to two equivalent O(5) and two equivalent O(6) atoms. Both Ag(3)-O(5) bond lengths are 2.36 Å. Both Ag(3)-O(6) bond lengths are 2.51 Å. In the fourth Ag site, Ag(4) is bonded in a 4-coordinate geometry to two equivalent O(3) and two equivalent O(4) atoms. Both Ag(4)-O(3) bond lengths are 2.62 Å. Both Ag(4)-O(4) bond lengths are 2.13 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-C(7) bond length is 1.49 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(4) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(4) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one S(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-S(1) bond length is 1.77 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(4)-H(5) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one O(6) atom. The C(6)-O(6) bond length is 1.36 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(4), and one O(5) atom. The C(7)-O(4) bond length is 1.27 Å. The C(7)-O(5) bond length is 1.29 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a bent 150 degrees geometry to one O(5) and one O(6) atom. The H(1)-O(5) bond length is 1.58 Å. The H(1)-O(6) bond length is 1.02 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. The H(2)-O(7) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(7) atom. The H(3)-O(7) bond length is 0.98 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.48 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one S(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(2), one Ag(4), and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Ag(4) and one C(7) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Ag(3), one C(7), and one H(1) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Ag(3), one C(6), and one H(1) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Ag(1), one Ag(2), one H(2), and one H(3) atom. Linkers: 4 [O]C(=O)c1cc(S([O])([O])[O])ccc1O. Metal clusters: 8 [Ag]. The MOF has largest included sphere 2.10 A, density 3.00 g/cm3, surface area 2187.97 m2/g, accessible volume 0.06 cm3/g