CdC16NH10O4(CH)2 crystallizes in the monoclinic C2/c space group. The structure consists of sixteen 02329_fluka molecules inside a CdC16NH10O4 framework. In the CdC16NH10O4 framework, Cd(1) is bonded in a 7-coordinate geometry to one N(1), one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms. The Cd(1)-N(1) bond length is 2.36 Å. The Cd(1)-O(3) bond length is 2.35 Å. The Cd(1)-O(4) bond length is 2.22 Å. There is one shorter (2.31 Å) and one longer (2.49 Å) Cd(1)-O(1) bond length. There is one shorter (2.60 Å) and one longer (2.74 Å) Cd(1)-O(2) bond length. There are sixteen inequivalent C sites. In the first C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(7)-C(6) bond length is 1.42 Å. The C(7)-H(3) bond length is 1.09 Å. In the second C site, C(10) is bonded in a distorted single-bond geometry to one C(5) and one H(6) atom. The C(10)-C(5) bond length is 1.42 Å. The C(10)-H(6) bond length is 1.09 Å. In the third C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(11)-C(1) bond length is 1.49 Å. The C(11)-O(1) bond length is 1.29 Å. The C(11)-O(2) bond length is 1.26 Å. In the fourth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(12)-C(4) bond length is 1.51 Å. The C(12)-O(3) bond length is 1.26 Å. The C(12)-O(4) bond length is 1.28 Å. In the fifth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(7) atom. The C(13)-N(1) bond length is 1.34 Å. The C(13)-H(7) bond length is 1.09 Å. In the sixth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(8) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(8) bond length is 1.09 Å. In the seventh C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(18) bond length is 1.51 Å. In the eighth C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one H(9) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(9) bond length is 1.09 Å. In the ninth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(1), and one H(10) atom. The C(17)-N(1) bond length is 1.35 Å. The C(17)-H(10) bond length is 1.09 Å. In the tenth C site, C(18) is bonded in a distorted water-like geometry to one C(15), one H(11), and one H(12) atom. The C(18)-H(11) bond length is 1.10 Å. The C(18)-H(12) bond length is 1.10 Å. In the eleventh C site, C(1) is bonded in a trigonal planar geometry to one C(11), one C(2), and one C(6) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.43 Å. In the twelfth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(1) bond length is 1.09 Å. In the thirteenth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourteenth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(5) bond length is 1.43 Å. In the fifteenth C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.44 Å. In the sixteenth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(17) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one C(11) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Cd(1) and one C(11) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(12) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(12) atom. Linkers: 2 c1cc(CCc2ccncc2)ccn1 ,4 [O]C(=O)c1ccc(C([O])=O)c2ccccc12. Metal clusters: 4 [Cd]. The MOF has largest included sphere 2.45 A, density 1.81 g/cm3, surface area 3920.60 m2/g, accessible volume 0.17 cm3/g