ZnC10N2H14SO7 crystallizes in the monoclinic P2_1/c space group. Zn(1) is bonded to one N(1), one N(2), one O(1), one O(2), and one O(4) atom to form ZnN2O3 trigonal bipyramids that share  a cornercorner with one S(1)O4 tetrahedra. The Zn(1)-N(1) bond length is 2.18 Å. The Zn(1)-N(2) bond length is 2.13 Å. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.04 Å. The Zn(1)-O(4) bond length is 2.09 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(7) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(7) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(8) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(8) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. The C(3)-C(3) bond length is 1.48 Å. The C(3)-C(4) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(9) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(9) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(10) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(10) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(2), and one H(11) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-N(2) bond length is 1.35 Å. The C(6)-H(11) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(12) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-H(12) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(7), one C(8), and one C(9) atom. The C(8)-C(8) bond length is 1.48 Å. The C(8)-C(9) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(13) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(13) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(14) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(14) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(6) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(1) and one O(7) atom. The H(1)-O(1) bond length is 1.00 Å. The H(1)-O(7) bond length is 1.63 Å. In the second H site, H(2) is bonded in a distorted linear geometry to one O(1) and one O(3) atom. The H(2)-O(1) bond length is 1.02 Å. The H(2)-O(3) bond length is 1.59 Å. In the third H site, H(3) is bonded in a distorted linear geometry to one O(2) and one O(6) atom. The H(3)-O(2) bond length is 1.01 Å. The H(3)-O(6) bond length is 1.60 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) and one O(7) atom. The H(4)-O(2) bond length is 0.99 Å. The H(4)-O(7) bond length is 1.72 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. The H(5)-O(3) bond length is 0.99 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. The H(6)-O(3) bond length is 0.99 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(1) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(2) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(7) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. S(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form SO4 tetrahedra that share  a cornercorner with one Zn(1)N2O3 trigonal bipyramid. The S(1)-O(4) bond length is 1.53 Å. The S(1)-O(5) bond length is 1.45 Å. The S(1)-O(6) bond length is 1.50 Å. The S(1)-O(7) bond length is 1.50 Å. There are seven inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(6) is bonded in a distorted bent 120 degrees geometry to one H(3) and one S(1) atom. In the third O site, O(7) is bonded in a 3-coordinate geometry to one H(1), one H(4), and one S(1) atom. In the fourth O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one H(1), and one H(2) atom. In the fifth O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one H(3), and one H(4) atom. In the sixth O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one H(2), one H(5), and one H(6) atom. In the seventh O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one S(1) atom. Linkers: 4 c1cc(-c2ccncc2)ccn1. Metal clusters: 4 O.O.[O]S([O])([O])O[Zn]. The MOF has largest included sphere 3.85 A, density 1.61 g/cm3, surface area 4004.75 m2/g, accessible volume 0.16 cm3/g