PdAg2C8(N2O5)2(CH3)4 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a PdAg2C8(N2O5)2 framework. In the PdAg2C8(N2O5)2 framework, Pd(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Pd(1)-O(1) bond lengths are 2.00 Å. Both Pd(1)-O(2) bond lengths are 2.00 Å. Ag(1) is bonded to one N(1), one O(4), one O(5), and two equivalent O(3) atoms to form distorted corner-sharing AgNO4 trigonal bipyramids. The Ag(1)-N(1) bond length is 2.13 Å. The Ag(1)-O(4) bond length is 2.64 Å. The Ag(1)-O(5) bond length is 2.60 Å. There is one shorter (2.35 Å) and one longer (2.40 Å) Ag(1)-O(3) bond length. There are four inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one O(1) atom. The C(2)-C(3) bond length is 1.43 Å. The C(2)-O(1) bond length is 1.28 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.43 Å. The C(3)-C(6) bond length is 1.41 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one O(2) atom. The C(4)-O(2) bond length is 1.28 Å. In the fourth C site, C(6) is bonded in a distorted linear geometry to one C(3) and one N(1) atom. The C(6)-N(1) bond length is 1.17 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Ag(1) and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. The N(2)-O(3) bond length is 1.30 Å. The N(2)-O(4) bond length is 1.25 Å. The N(2)-O(5) bond length is 1.26 Å. There are five inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one C(4) atom. In the second O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one N(2) atom. In the third O site, O(4) is bonded in a distorted single-bond geometry to one Ag(1) and one N(2) atom. In the fourth O site, O(5) is bonded in a distorted single-bond geometry to one Ag(1) and one N(2) atom. In the fifth O site, O(1) is bonded in a bent 120 degrees geometry to one Pd(1) and one C(2) atom. Linkers: 4 CC(=O)[C](C#N)C(C)=O. Metal clusters: 4 [Ag] ,2 [Pd]. The MOF has largest included sphere 1.76 A, density 2.57 g/cm3, surface area 3181.08 m2/g, accessible volume 0.07 cm3/g