CH2CH(CH3)2ZnC8H8Br(NO)2 crystallizes in the monoclinic P2_1 space group. The structure consists of six 02329_fluka molecules, six 02329_fluka molecules, and twelve 02329_fluka molecules inside a ZnC8H8Br(NO)2 framework. In the ZnC8H8Br(NO)2 framework, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(1), one N(5), one O(1), one O(5), and one Br(1) atom to form distorted ZnBrN2O2 trigonal bipyramids that share  a cornercorner with one C(1)HN tetrahedra. The Zn(1)-N(1) bond length is 2.14 Å. The Zn(1)-N(5) bond length is 2.06 Å. The Zn(1)-O(1) bond length is 2.21 Å. The Zn(1)-O(5) bond length is 2.20 Å. The Zn(1)-Br(1) bond length is 2.38 Å. In the second Zn site, Zn(2) is bonded to one N(2), one N(6), one O(2), one O(6), and one Br(2) atom to form distorted ZnBrN2O2 trigonal bipyramids that share  a cornercorner with one C(2)HN tetrahedra. The Zn(2)-N(2) bond length is 2.14 Å. The Zn(2)-N(6) bond length is 2.06 Å. The Zn(2)-O(2) bond length is 2.22 Å. The Zn(2)-O(6) bond length is 2.20 Å. The Zn(2)-Br(2) bond length is 2.38 Å. In the third Zn site, Zn(3) is bonded to one N(3), one N(4), one O(3), one O(4), and one Br(3) atom to form distorted ZnBrN2O2 trigonal bipyramids that share  a cornercorner with one C(3)HN tetrahedra. The Zn(3)-N(3) bond length is 2.14 Å. The Zn(3)-N(4) bond length is 2.06 Å. The Zn(3)-O(3) bond length is 2.22 Å. The Zn(3)-O(4) bond length is 2.20 Å. The Zn(3)-Br(3) bond length is 2.38 Å. There are twenty inequivalent C sites. In the first C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(6) atom. The C(12)-O(3) bond length is 1.27 Å. The C(12)-O(6) bond length is 1.27 Å. In the second C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one C(22,23,24); one N(1); one H(13,14,15); and one H(16,17,18) atom. The C(13)-C(22,23,24) bond length is 1.51 Å. The C(13)-N(1) bond length is 1.48 Å. The C(13)-H(13,14,15) bond length is 1.10 Å. The C(13)-H(16,17,18) bond length is 1.10 Å. In the third C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one C(22,23,24); one N(2); one H(13,14,15); and one H(16,17,18) atom. The C(14)-C(22,23,24) bond length is 1.51 Å. The C(14)-N(2) bond length is 1.48 Å. The C(14)-H(13,14,15) bond length is 1.10 Å. The C(14)-H(16,17,18) bond length is 1.10 Å. In the fourth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one C(22,23,24); one N(3); one H(13,14,15); and one H(16,17,18) atom. The C(15)-C(22,23,24) bond length is 1.51 Å. The C(15)-N(3) bond length is 1.48 Å. The C(15)-H(13,14,15) bond length is 1.10 Å. The C(15)-H(16,17,18) bond length is 1.10 Å. In the fifth C site, C(22,23,24) is bonded in a trigonal planar geometry to one C(13); one C(25,26); and one C(28,29) atom. The C(22,23,24)-C(25,26) bond length is 1.40 Å. The C(22,23,24)-C(28,29) bond length is 1.40 Å. In the sixth C site, C(25,26) is bonded in a distorted trigonal planar geometry to one C(22,23,24); one C(34); and one H(37,38,39) atom. The C(25,26)-C(34) bond length is 1.39 Å. The C(25,26)-H(37,38,39) bond length is 1.09 Å. In the seventh C site, C(27) is bonded in a distorted trigonal planar geometry to one C(22,23,24); one C(36); and one H(37,38,39) atom. The C(27)-C(22,23,24) bond length is 1.40 Å. The C(27)-C(36) bond length is 1.39 Å. The C(27)-H(37,38,39) bond length is 1.09 Å. In the eighth C site, C(28,29) is bonded in a distorted single-bond geometry to one C(22,23,24); one C(31); and one H(40,41,42) atom. The C(28,29)-C(31) bond length is 1.39 Å. The C(28,29)-H(40,41,42) bond length is 1.09 Å. In the ninth C site, C(30) is bonded in a distorted single-bond geometry to one C(22,23,24); one C(33); and one H(40,41,42) atom. The C(30)-C(22,23,24) bond length is 1.40 Å. The C(30)-C(33) bond length is 1.39 Å. The C(30)-H(40,41,42) bond length is 1.09 Å. In the tenth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(28,29); one N(4); and one H(43,44) atom. The C(31)-N(4) bond length is 1.35 Å. The C(31)-H(43,44) bond length is 1.09 Å. In the eleventh C site, C(32) is bonded in a distorted trigonal planar geometry to one C(28,29); one N(5); and one H(43,44) atom. The C(32)-C(28,29) bond length is 1.39 Å. The C(32)-N(5) bond length is 1.35 Å. The C(32)-H(43,44) bond length is 1.09 Å. In the twelfth C site, C(33) is bonded in a distorted trigonal planar geometry to one C(30), one N(6), and one H(45) atom. The C(33)-N(6) bond length is 1.35 Å. The C(33)-H(45) bond length is 1.09 Å. In the thirteenth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(25,26); one N(4); and one H(46,47) atom. The C(34)-N(4) bond length is 1.35 Å. The C(34)-H(46,47) bond length is 1.09 Å. In the fourteenth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(25,26); one N(5); and one H(46,47) atom. The C(35)-C(25,26) bond length is 1.39 Å. The C(35)-N(5) bond length is 1.35 Å. The C(35)-H(46,47) bond length is 1.09 Å. In the fifteenth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(27), one N(6), and one H(48) atom. The C(36)-N(6) bond length is 1.35 Å. The C(36)-H(48) bond length is 1.09 Å. In the sixteenth C site, C(1) is bonded to one N(1) and one H(1,2,3) atom to form distorted CHN tetrahedra that share  a cornercorner with one Zn(1)BrN2O2 trigonal bipyramid. The C(1)-N(1) bond length is 1.47 Å. The C(1)-H(1,2,3) bond length is 1.10 Å. In the seventeenth C site, C(2) is bonded to one N(2) and one H(1,2,3) atom to form distorted CHN tetrahedra that share  a cornercorner with one Zn(2)BrN2O2 trigonal bipyramid. The C(2)-N(2) bond length is 1.47 Å. The C(2)-H(1,2,3) bond length is 1.10 Å. In the eighteenth C site, C(3) is bonded to one N(3) and one H(1,2,3) atom to form distorted CHN tetrahedra that share  a cornercorner with one Zn(3)BrN2O2 trigonal bipyramid. The C(3)-N(3) bond length is 1.47 Å. The C(3)-H(1,2,3) bond length is 1.10 Å. In the nineteenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(10)-O(1) bond length is 1.27 Å. The C(10)-O(4) bond length is 1.27 Å. In the twentieth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(5) atom. The C(11)-O(2) bond length is 1.27 Å. The C(11)-O(5) bond length is 1.27 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted tetrahedral geometry to one Zn(1), one C(1), one C(13), and one H(49) atom. The N(1)-H(49) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted tetrahedral geometry to one Zn(2), one C(14), one C(2), and one H(50) atom. The N(2)-H(50) bond length is 1.03 Å. In the third N site, N(3) is bonded in a distorted tetrahedral geometry to one Zn(3), one C(15), one C(3), and one H(51) atom. The N(3)-H(51) bond length is 1.03 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(3), one C(31), and one C(34) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(1), one C(32), and one C(35) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(2), one C(33), and one C(36) atom. There are twelve inequivalent H sites. In the first H site, H(1,2,3) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(13,14,15) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(16,17,18) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(37,38,39) is bonded in a single-bond geometry to one C(25,26) atom. In the fifth H site, H(40,41,42) is bonded in a single-bond geometry to one C(28,29) atom. In the sixth H site, H(43,44) is bonded in a single-bond geometry to one C(31) atom. In the seventh H site, H(45) is bonded in a single-bond geometry to one C(33) atom. In the eighth H site, H(46,47) is bonded in a single-bond geometry to one C(34) atom. In the ninth H site, H(48) is bonded in a single-bond geometry to one C(36) atom. In the tenth H site, H(49) is bonded in a single-bond geometry to one N(1) atom. In the eleventh H site, H(50) is bonded in a single-bond geometry to one N(2) atom. In the twelfth H site, H(51) is bonded in a single-bond geometry to one N(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(10) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(11) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(12) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(10) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(11) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(12) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Zn(2) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Zn(3) atom. Linkers: 6 CC(C)C[C@H](NCc1ccncc1)C([O])=O. Metal clusters: 6 [Zn]. The MOF has largest included sphere 8.12 A, density 1.15 g/cm3, surface area 4442.51 m2/g, accessible volume 0.44 cm3/g