ZnC28H22(N4O3)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC28H22(N4O3)2 clusters. Zn(1) is bonded in an octahedral geometry to one N(3), one N(4), one O(3), one O(4), one O(5), and one O(6) atom. The Zn(1)-N(3) bond length is 2.18 Å. The Zn(1)-N(4) bond length is 2.18 Å. The Zn(1)-O(3) bond length is 2.10 Å. The Zn(1)-O(4) bond length is 2.10 Å. The Zn(1)-O(5) bond length is 2.19 Å. The Zn(1)-O(6) bond length is 2.19 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3,4); one N(1,2); and one H(1,2) atom. The C(1)-C(3,4) bond length is 1.39 Å. The C(1)-N(1,2) bond length is 1.34 Å. The C(1)-H(1,2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3,4); one N(1,2); and one H(1,2) atom. The C(2)-C(3,4) bond length is 1.39 Å. The C(2)-N(1,2) bond length is 1.34 Å. The C(2)-H(1,2) bond length is 1.09 Å. In the third C site, C(3,4) is bonded in a distorted trigonal planar geometry to one C(1), one N(3), and one H(3) atom. The C(3,4)-N(3) bond length is 1.35 Å. The C(3,4)-H(3) bond length is 1.09 Å. In the fourth C site, C(5,6) is bonded in a distorted trigonal planar geometry to one C(7), one N(3), and one H(5) atom. The C(5,6)-C(7) bond length is 1.41 Å. The C(5,6)-N(3) bond length is 1.34 Å. The C(5,6)-H(5) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5,6); one C(9,10); and one N(1,2) atom. The C(7)-C(9,10) bond length is 1.46 Å. The C(7)-N(1,2) bond length is 1.35 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(5,6); one C(9,10); and one N(1,2) atom. The C(8)-C(5,6) bond length is 1.41 Å. The C(8)-C(9,10) bond length is 1.46 Å. The C(8)-N(1,2) bond length is 1.35 Å. In the seventh C site, C(9,10) is bonded in a distorted single-bond geometry to one C(11,12); one C(7); and one N(5,6) atom. The C(9,10)-C(11,12) bond length is 1.42 Å. The C(9,10)-N(5,6) bond length is 1.35 Å. In the eighth C site, C(11,12) is bonded in a distorted single-bond geometry to one C(13,14); one C(9,10); and one H(7,8) atom. The C(11,12)-C(13,14) bond length is 1.38 Å. The C(11,12)-H(7,8) bond length is 1.08 Å. In the ninth C site, C(13,14) is bonded in a distorted bent 120 degrees geometry to one C(11,12); one N(7); and one H(9,10) atom. The C(13,14)-N(7) bond length is 1.38 Å. The C(13,14)-H(9,10) bond length is 1.09 Å. In the tenth C site, C(15,16) is bonded in a distorted trigonal planar geometry to one C(17), one C(25), and one N(7) atom. The C(15,16)-C(17) bond length is 1.40 Å. The C(15,16)-C(25) bond length is 1.40 Å. The C(15,16)-N(7) bond length is 1.41 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(15,16) and one H(11,12) atom. The C(17)-H(11,12) bond length is 1.09 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(15,16) and one H(11,12) atom. The C(18)-C(15,16) bond length is 1.40 Å. The C(18)-H(11,12) bond length is 1.09 Å. In the thirteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(21) and one H(13,14) atom. The C(19)-C(21) bond length is 1.40 Å. The C(19)-H(13,14) bond length is 1.09 Å. In the fourteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(22) and one H(13,14) atom. The C(20)-C(22) bond length is 1.40 Å. The C(20)-H(13,14) bond length is 1.09 Å. In the fifteenth C site, C(21) is bonded in a trigonal planar geometry to one C(19), one C(23), and one C(27) atom. The C(21)-C(23) bond length is 1.40 Å. The C(21)-C(27) bond length is 1.49 Å. In the sixteenth C site, C(22) is bonded in a trigonal planar geometry to one C(20), one C(24), and one C(28) atom. The C(22)-C(24) bond length is 1.40 Å. The C(22)-C(28) bond length is 1.50 Å. In the seventeenth C site, C(23) is bonded in a distorted single-bond geometry to one C(21) and one H(15,16) atom. The C(23)-H(15,16) bond length is 1.09 Å. In the eighteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(22) and one H(15,16) atom. The C(24)-H(15,16) bond length is 1.09 Å. In the nineteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(15,16) and one H(17,18) atom. The C(25)-H(17,18) bond length is 1.09 Å. In the twentieth C site, C(26) is bonded in a distorted single-bond geometry to one C(15,16) and one H(17,18) atom. The C(26)-C(15,16) bond length is 1.40 Å. The C(26)-H(17,18) bond length is 1.09 Å. In the twenty-first C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(1), and one O(3) atom. The C(27)-O(1) bond length is 1.27 Å. The C(27)-O(3) bond length is 1.28 Å. In the twenty-second C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(2), and one O(4) atom. The C(28)-O(2) bond length is 1.27 Å. The C(28)-O(4) bond length is 1.28 Å. There are six inequivalent N sites. In the first N site, N(1,2) is bonded in a bent 120 degrees geometry to one C(1) and one C(7) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Zn(1); one C(3,4); and one C(5,6) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one Zn(1); one C(3,4); and one C(5,6) atom. The N(4)-C(3,4) bond length is 1.35 Å. The N(4)-C(5,6) bond length is 1.34 Å. In the fourth N site, N(5,6) is bonded in a water-like geometry to one C(9,10) and one N(7) atom. The N(5,6)-N(7) bond length is 1.35 Å. In the fifth N site, N(7) is bonded in a distorted trigonal planar geometry to one C(13,14); one C(15,16); and one N(5,6) atom. In the sixth N site, N(8) is bonded in a distorted trigonal planar geometry to one C(13,14); one C(15,16); and one N(5,6) atom. The N(8)-C(13,14) bond length is 1.38 Å. The N(8)-C(15,16) bond length is 1.41 Å. The N(8)-N(5,6) bond length is 1.35 Å. There are fifteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3,4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(3,4) atom. The H(4)-C(3,4) bond length is 1.09 Å. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(5,6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(5,6) atom. The H(6)-C(5,6) bond length is 1.09 Å. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(11,12) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(13,14) atom. In the eighth H site, H(11,12) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(13,14) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(15,16) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(17,18) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one O(5) atom. The H(19)-O(5) bond length is 0.97 Å. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one O(6) atom. The H(20)-O(6) bond length is 0.97 Å. In the fourteenth H site, H(21) is bonded in a linear geometry to one O(2) and one O(5) atom. The H(21)-O(2) bond length is 1.52 Å. The H(21)-O(5) bond length is 1.04 Å. In the fifteenth H site, H(22) is bonded in a linear geometry to one O(1) and one O(6) atom. The H(22)-O(1) bond length is 1.52 Å. The H(22)-O(6) bond length is 1.04 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(27) and one H(22) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(28) and one H(21) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(27) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(28) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Zn(1), one H(19), and one H(21) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Zn(1), one H(20), and one H(22) atom. Linkers: 4 [O]C(=O)c1ccc(-n2ccc(-c3cnccn3)n2)cc1. Metal clusters: 2 O.O.O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.05 A, density 1.53 g/cm3, surface area 4580.34 m2/g, accessible volume 0.14 cm3/g