CdC14H8(NO2)2C6H5CH(CH2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; eight 02329_fluka molecules; four 4-methyl-1,3-pentadiene molecules; and two CdC14H8(NO2)2 clusters. In each CdC14H8(NO2)2 cluster, Cd(1) is bonded to one N(1), one N(2), one O(3), one O(4), and two equivalent O(2) atoms to form distorted edge-sharing CdN2O4 octahedra. The Cd(1)-N(1) bond length is 2.33 Å. The Cd(1)-N(2) bond length is 2.38 Å. The Cd(1)-O(3) bond length is 2.40 Å. The Cd(1)-O(4) bond length is 2.41 Å. There is one shorter (2.28 Å) and one longer (2.37 Å) Cd(1)-O(2) bond length. There are fourteen inequivalent C sites. In the first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(21)-O(1) bond length is 1.25 Å. The C(21)-O(2) bond length is 1.30 Å. In the second C site, C(23) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(23)-O(3) bond length is 1.28 Å. The C(23)-O(4) bond length is 1.28 Å. In the third C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the fourth C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the fifth C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the sixth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-C(6) bond length is 1.43 Å. In the seventh C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(9), and one N(2) atom. The C(5)-C(9) bond length is 1.45 Å. The C(5)-N(2) bond length is 1.35 Å. In the eighth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the ninth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(7)-C(8) bond length is 1.43 Å. The C(7)-H(5) bond length is 1.09 Å. In the tenth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.41 Å. The C(8)-C(9) bond length is 1.42 Å. In the eleventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(5), one C(8), and one N(1) atom. The C(9)-N(1) bond length is 1.35 Å. In the twelfth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(8), and one H(6) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-H(6) bond length is 1.09 Å. In the thirteenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(7) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-H(7) bond length is 1.09 Å. In the fourteenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one H(8) atom. The C(12)-N(1) bond length is 1.33 Å. The C(12)-H(8) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(12), and one C(9) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(21) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one C(21) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(23) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(23) atom. Linkers: 4 [O]C(=O)CC(CC([O])=O)c1ccccc1 ,4 c1cnc2c(c1)ccc1cccnc12. Metal clusters: 2 O=[C]O[Cd]1O[C]O1.O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 4.10 A, density 1.53 g/cm3, surface area 4419.79 m2/g, accessible volume 0.20 cm3/g