CdC21H18(N4O3)2(CH2)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and two CdC21H18(N4O3)2 clusters. In each CdC21H18(N4O3)2 cluster, Cd(1) is bonded in a pentagonal bipyramidal geometry to one N(1), one N(4), one N(5), one O(1), one O(2), one O(4), and one O(5) atom. The Cd(1)-N(1) bond length is 2.33 Å. The Cd(1)-N(4) bond length is 2.30 Å. The Cd(1)-N(5) bond length is 2.39 Å. The Cd(1)-O(1) bond length is 2.44 Å. The Cd(1)-O(2) bond length is 2.56 Å. The Cd(1)-O(4) bond length is 2.50 Å. The Cd(1)-O(5) bond length is 2.54 Å. There are twenty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.47 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(5) atom. The C(6)-N(2) bond length is 1.28 Å. The C(6)-H(5) bond length is 1.11 Å. In the seventh C site, C(7) is bonded in a distorted tetrahedral geometry to one N(2) and one H(6) atom. The C(7)-N(2) bond length is 1.44 Å. The C(7)-H(6) bond length is 1.11 Å. In the eighth C site, C(11) is bonded in a distorted tetrahedral geometry to one N(3) and one H(13) atom. The C(11)-N(3) bond length is 1.45 Å. The C(11)-H(13) bond length is 1.11 Å. In the ninth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(3), and one H(16) atom. The C(13)-C(14) bond length is 1.47 Å. The C(13)-N(3) bond length is 1.28 Å. The C(13)-H(16) bond length is 1.11 Å. In the tenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(18) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(18) bond length is 1.40 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(17) atom. The C(15)-H(17) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(18) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(18) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(4), and one H(19) atom. The C(17)-N(4) bond length is 1.35 Å. The C(17)-H(19) bond length is 1.09 Å. In the fourteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(14), one N(4), and one H(20) atom. The C(18)-N(4) bond length is 1.34 Å. The C(18)-H(20) bond length is 1.09 Å. In the fifteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(5), and one H(21) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-N(5) bond length is 1.34 Å. The C(19)-H(21) bond length is 1.09 Å. In the sixteenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(24) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(24) bond length is 1.47 Å. In the seventeenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one H(22) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(22) bond length is 1.09 Å. In the eighteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one H(23) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-H(23) bond length is 1.09 Å. In the nineteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one N(5), and one H(24) atom. The C(23)-N(5) bond length is 1.35 Å. The C(23)-H(24) bond length is 1.09 Å. In the twentieth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(6), and one H(25) atom. The C(24)-N(6) bond length is 1.28 Å. The C(24)-H(25) bond length is 1.11 Å. In the twenty-first C site, C(25) is bonded in a distorted tetrahedral geometry to one N(6) and one H(26) atom. The C(25)-N(6) bond length is 1.45 Å. The C(25)-H(26) bond length is 1.11 Å. There are eight inequivalent N sites. In the first N site, N(7) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. The N(7)-O(4) bond length is 1.28 Å. The N(7)-O(5) bond length is 1.29 Å. The N(7)-O(6) bond length is 1.24 Å. In the second N site, N(8) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(8)-O(1) bond length is 1.29 Å. The N(8)-O(2) bond length is 1.28 Å. The N(8)-O(3) bond length is 1.25 Å. In the third N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the fourth N site, N(2) is bonded in a bent 120 degrees geometry to one C(6) and one C(7) atom. In the fifth N site, N(3) is bonded in a bent 120 degrees geometry to one C(11) and one C(13) atom. In the sixth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(17), and one C(18) atom. In the seventh N site, N(5) is bonded in a trigonal planar geometry to one Cd(1), one C(19), and one C(23) atom. In the eighth N site, N(6) is bonded in a bent 120 degrees geometry to one C(24) and one C(25) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(23) is bonded in a single-bond geometry to one C(22) atom. In the sixteenth H site, H(24) is bonded in a single-bond geometry to one C(23) atom. In the seventeenth H site, H(25) is bonded in a single-bond geometry to one C(24) atom. In the eighteenth H site, H(26) is bonded in a single-bond geometry to one C(25) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1) and one N(8) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one N(8) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(8) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one N(7) atom. In the fifth O site, O(5) is bonded in a distorted L-shaped geometry to one Cd(1) and one N(7) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(7) atom. Linkers: 1 C(=N/[C@H]1CC[C@H](/N=C/c2cccnc2)CC1)\c1cccnc1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 2.35 A, density 1.54 g/cm3, surface area 5032.43 m2/g, accessible volume 0.20 cm3/g