CuC7H5(NO)4C3NH2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 2-nitropropene molecules and one CuC7H5(NO)4 cluster. In the CuC7H5(NO)4 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-N(1) bond length is 2.20 Å. The Cu(1)-O(1) bond length is 1.99 Å. The Cu(1)-O(2) bond length is 2.00 Å. The Cu(1)-O(3) bond length is 1.99 Å. The Cu(1)-O(4) bond length is 2.00 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(1)-O(2) bond length is 1.26 Å. The C(1)-O(3) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(8) and one H(1) atom. The C(2)-C(8) bond length is 1.40 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(1), and one O(4) atom. The C(3)-C(8) bond length is 1.50 Å. The C(3)-O(1) bond length is 1.27 Å. The C(3)-O(4) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(8) and one H(2) atom. The C(4)-C(8) bond length is 1.40 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(5), and one H(6) atom. The C(7)-N(2) bond length is 1.45 Å. The C(7)-H(5) bond length is 1.09 Å. The C(7)-H(6) bond length is 1.10 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one N(2), one N(5), and one H(7) atom. The C(9)-N(2) bond length is 1.35 Å. The C(9)-N(5) bond length is 1.32 Å. The C(9)-H(7) bond length is 1.08 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one N(3), and one N(5) atom. The N(1)-N(3) bond length is 1.30 Å. The N(1)-N(5) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(3) atom. The N(2)-N(3) bond length is 1.34 Å. In the third N site, N(3) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the fourth N site, N(5) is bonded in a distorted water-like geometry to one C(9) and one N(1) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. Linkers: 2 [O]C(=O)Cn1cnnn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 3.40 A, density 1.69 g/cm3, surface area 4122.31 m2/g, accessible volume 0.17 cm3/g