CuC22N4H19O5CH3(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 02329_fluka molecules, and one CuC22N4H19O5 cluster. In the CuC22N4H19O5 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. The Cu(1)-O(1) bond length is 2.00 Å. The Cu(1)-O(2) bond length is 2.01 Å. The Cu(1)-O(3) bond length is 1.98 Å. The Cu(1)-O(4) bond length is 1.98 Å. The Cu(1)-O(5) bond length is 2.26 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(2) atom. The C(1)-C(10) bond length is 1.40 Å. The C(1)-C(12) bond length is 1.40 Å. The C(1)-C(2) bond length is 1.49 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(4) atom. The C(2)-O(1) bond length is 1.28 Å. The C(2)-O(4) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(2), and one O(3) atom. The C(3)-C(7) bond length is 1.49 Å. The C(3)-O(2) bond length is 1.28 Å. The C(3)-O(3) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(4)-C(6) bond length is 1.40 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(14) and one N(1) atom. The C(5)-C(14) bond length is 1.42 Å. The C(5)-N(1) bond length is 1.34 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(11), one C(4), and one N(2) atom. The C(6)-C(11) bond length is 1.40 Å. The C(6)-N(2) bond length is 1.42 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(17), one C(3), and one C(9) atom. The C(7)-C(17) bond length is 1.40 Å. The C(7)-C(9) bond length is 1.40 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(1) and one H(8) atom. The C(10)-H(8) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(6) and one H(9) atom. The C(11)-H(9) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(1) and one H(10) atom. The C(12)-H(10) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(22) atom. The C(13)-C(18) bond length is 1.39 Å. The C(13)-C(20) bond length is 1.42 Å. The C(13)-C(22) bond length is 1.49 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(19), one C(22), and one C(5) atom. The C(14)-C(19) bond length is 1.40 Å. The C(14)-C(22) bond length is 1.51 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one N(4) atom. The C(16)-N(4) bond length is 1.41 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(7) and one H(12) atom. The C(17)-H(12) bond length is 1.08 Å. In the sixteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(13), one C(24), and one N(4) atom. The C(18)-C(24) bond length is 1.49 Å. The C(18)-N(4) bond length is 1.39 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14), one C(25), and one N(2) atom. The C(19)-C(25) bond length is 1.49 Å. The C(19)-N(2) bond length is 1.38 Å. In the eighteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(13), one C(23), and one N(3) atom. The C(20)-C(23) bond length is 1.49 Å. The C(20)-N(3) bond length is 1.33 Å. In the nineteenth C site, C(22) is bonded in a water-like geometry to one C(13), one C(14), one H(14), and one H(15) atom. The C(22)-H(14) bond length is 1.10 Å. The C(22)-H(15) bond length is 1.11 Å. In the twentieth C site, C(23) is bonded in a distorted trigonal non-coplanar geometry to one C(20), one H(16), one H(17), and one H(18) atom. The C(23)-H(16) bond length is 1.09 Å. The C(23)-H(17) bond length is 1.10 Å. The C(23)-H(18) bond length is 1.10 Å. In the twenty-first C site, C(24) is bonded in a distorted trigonal non-coplanar geometry to one C(18), one H(19), one H(20), and one H(21) atom. The C(24)-H(19) bond length is 1.10 Å. The C(24)-H(20) bond length is 1.10 Å. The C(24)-H(21) bond length is 1.10 Å. In the twenty-second C site, C(25) is bonded in a distorted trigonal non-coplanar geometry to one C(19), one H(22), one H(23), and one H(24) atom. The C(25)-H(22) bond length is 1.10 Å. The C(25)-H(23) bond length is 1.09 Å. The C(25)-H(24) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one C(5), one N(2), and one H(2) atom. The N(1)-N(2) bond length is 1.36 Å. The N(1)-H(2) bond length is 1.74 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(19), one C(6), and one N(1) atom. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(20) and one N(4) atom. The N(3)-N(4) bond length is 1.37 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one N(3) atom. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. The H(1)-O(5) bond length is 0.97 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) and one O(5) atom. The H(2)-O(5) bond length is 1.01 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(24) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the sixteenth H site, H(21) is bonded in a single-bond geometry to one C(24) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one C(25) atom. In the eighteenth H site, H(23) is bonded in a single-bond geometry to one C(25) atom. In the nineteenth H site, H(24) is bonded in a single-bond geometry to one C(25) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Cu(1), one H(1), and one H(2) atom. Linkers: 2 Cc1nn(-c2ccc(C([O])=O)cc2)c(C)c1Cc1c(C)nn(-c2ccc(C([O])=O)cc2)c1C. Metal clusters: 1 O.O.[C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 5.28 A, density 1.17 g/cm3, surface area 4877.85 m2/g, accessible volume 0.41 cm3/g