Li9C11H8O19(CH3)7 crystallizes in the monoclinic P2_1/c space group. The structure consists of twenty-eight 02329_fluka molecules inside a Li9C11H8O19 framework. In the Li9C11H8O19 framework, there are nine inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(15), one O(3), one O(4), and one O(6) atom to form a mixture of edge and corner-sharing LiO4 tetrahedra. The Li(1)-O(15) bond length is 1.93 Å. The Li(1)-O(3) bond length is 1.91 Å. The Li(1)-O(4) bond length is 1.96 Å. The Li(1)-O(6) bond length is 1.94 Å. In the second Li site, Li(2) is bonded to one O(1), one O(7), and two equivalent O(11) atoms to form a mixture of distorted edge and corner-sharing LiO4 tetrahedra. The Li(2)-O(1) bond length is 1.95 Å. The Li(2)-O(7) bond length is 1.92 Å. There is one shorter (1.92 Å) and one longer (1.94 Å) Li(2)-O(11) bond length. In the third Li site, Li(3) is bonded to one O(17), one O(3), one O(8), and one O(9) atom to form corner-sharing LiO4 tetrahedra. The Li(3)-O(17) bond length is 1.92 Å. The Li(3)-O(3) bond length is 1.97 Å. The Li(3)-O(8) bond length is 1.93 Å. The Li(3)-O(9) bond length is 1.98 Å. In the fourth Li site, Li(4) is bonded to one O(1), one O(10), one O(5), and one O(9) atom to form corner-sharing LiO4 tetrahedra. The Li(4)-O(1) bond length is 2.12 Å. The Li(4)-O(10) bond length is 1.98 Å. The Li(4)-O(5) bond length is 2.00 Å. The Li(4)-O(9) bond length is 1.99 Å. In the fifth Li site, Li(5) is bonded to one O(12), one O(13), one O(16), and one O(2) atom to form a mixture of edge and corner-sharing LiO4 tetrahedra. The Li(5)-O(12) bond length is 1.90 Å. The Li(5)-O(13) bond length is 1.95 Å. The Li(5)-O(16) bond length is 2.03 Å. The Li(5)-O(2) bond length is 1.97 Å. In the sixth Li site, Li(6) is bonded to one O(1), one O(5), one O(7), and one O(8) atom to form a mixture of edge and corner-sharing LiO4 tetrahedra. The Li(6)-O(1) bond length is 1.98 Å. The Li(6)-O(5) bond length is 1.92 Å. The Li(6)-O(7) bond length is 1.95 Å. The Li(6)-O(8) bond length is 1.93 Å. In the seventh Li site, Li(7) is bonded to one O(13), one O(14), one O(18), and one O(19) atom to form corner-sharing LiO4 tetrahedra. The Li(7)-O(13) bond length is 1.96 Å. The Li(7)-O(14) bond length is 1.95 Å. The Li(7)-O(18) bond length is 1.98 Å. The Li(7)-O(19) bond length is 1.90 Å. In the eighth Li site, Li(8) is bonded to one O(14), one O(16), one O(18), and one O(2) atom to form a mixture of edge and corner-sharing LiO4 tetrahedra. The Li(8)-O(14) bond length is 1.91 Å. The Li(8)-O(16) bond length is 2.02 Å. The Li(8)-O(18) bond length is 1.89 Å. The Li(8)-O(2) bond length is 2.00 Å. In the ninth Li site, Li(9) is bonded to one O(10), one O(12), one O(4), and one O(6) atom to form a mixture of edge and corner-sharing LiO4 tetrahedra. The Li(9)-O(10) bond length is 1.91 Å. The Li(9)-O(12) bond length is 1.93 Å. The Li(9)-O(4) bond length is 1.92 Å. The Li(9)-O(6) bond length is 1.92 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(7) atom. The C(1)-O(3) bond length is 1.27 Å. The C(1)-O(7) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(8) atom. The C(2)-O(1) bond length is 1.29 Å. The C(2)-O(8) bond length is 1.27 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(3)-O(5) bond length is 1.28 Å. The C(3)-O(6) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(12), one O(18), and one O(2) atom. The C(4)-C(12) bond length is 1.51 Å. The C(4)-O(18) bond length is 1.27 Å. The C(4)-O(2) bond length is 1.28 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(15) and one O(17) atom. The C(5)-O(15) bond length is 1.29 Å. The C(5)-O(17) bond length is 1.26 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(11) atom. The C(6)-O(10) bond length is 1.27 Å. The C(6)-O(11) bond length is 1.28 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(14) and one O(19) atom. The C(7)-O(14) bond length is 1.28 Å. The C(7)-O(19) bond length is 1.27 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(4) atom. The C(8)-O(13) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.28 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(18), one O(12), and one O(9) atom. The C(9)-C(18) bond length is 1.51 Å. The C(9)-O(12) bond length is 1.28 Å. The C(9)-O(9) bond length is 1.27 Å. In the tenth C site, C(12) is bonded in a trigonal non-coplanar geometry to one C(4), one H(7), one H(8), and one H(9) atom. The C(12)-H(7) bond length is 1.10 Å. The C(12)-H(8) bond length is 1.10 Å. The C(12)-H(9) bond length is 1.10 Å. In the eleventh C site, C(18) is bonded in a trigonal non-coplanar geometry to one C(9), one H(25), one H(26), and one H(27) atom. The C(18)-H(25) bond length is 1.09 Å. The C(18)-H(26) bond length is 1.10 Å. The C(18)-H(27) bond length is 1.10 Å. There are eight inequivalent H sites. In the first H site, H(25) is bonded in a single-bond geometry to one C(18) atom. In the second H site, H(26) is bonded in a single-bond geometry to one C(18) atom. In the third H site, H(27) is bonded in a single-bond geometry to one C(18) atom. In the fourth H site, H(28) is bonded in a single-bond geometry to one O(16) atom. The H(28)-O(16) bond length is 0.97 Å. In the fifth H site, H(29) is bonded in a linear geometry to one O(15) and one O(16) atom. The H(29)-O(15) bond length is 1.58 Å. The H(29)-O(16) bond length is 1.03 Å. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. There are nineteen inequivalent O sites. In the first O site, O(9) is bonded in a trigonal planar geometry to one Li(3), one Li(4), and one C(9) atom. In the second O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(4), one Li(9), and one C(6) atom. In the third O site, O(11) is bonded in a distorted trigonal planar geometry to two equivalent Li(2) and one C(6) atom. In the fourth O site, O(12) is bonded in a distorted trigonal planar geometry to one Li(5), one Li(9), and one C(9) atom. In the fifth O site, O(13) is bonded in a distorted trigonal planar geometry to one Li(5), one Li(7), and one C(8) atom. In the sixth O site, O(14) is bonded in a distorted trigonal planar geometry to one Li(7), one Li(8), and one C(7) atom. In the seventh O site, O(15) is bonded in a trigonal planar geometry to one Li(1), one C(5), and one H(29) atom. In the eighth O site, O(16) is bonded in a distorted tetrahedral geometry to one Li(5), one Li(8), one H(28), and one H(29) atom. In the ninth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Li(3) and one C(5) atom. In the tenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Li(7), one Li(8), and one C(4) atom. In the eleventh O site, O(19) is bonded in a bent 120 degrees geometry to one Li(7) and one C(7) atom. In the twelfth O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one Li(6), and one C(2) atom. In the thirteenth O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(5), one Li(8), and one C(4) atom. In the fourteenth O site, O(3) is bonded in a trigonal planar geometry to one Li(1), one Li(3), and one C(1) atom. In the fifteenth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Li(9), and one C(8) atom. In the sixteenth O site, O(5) is bonded in a trigonal planar geometry to one Li(4), one Li(6), and one C(3) atom. In the seventeenth O site, O(6) is bonded in a distorted T-shaped geometry to one Li(1), one Li(9), and one C(3) atom. In the eighteenth O site, O(7) is bonded in a distorted T-shaped geometry to one Li(2), one Li(6), and one C(1) atom. In the nineteenth O site, O(8) is bonded in a trigonal planar geometry to one Li(3), one Li(6), and one C(2) atom. Linkers: 36 CC([O])=O ,4 O. Metal clusters: 36 [Li]. The MOF has largest included sphere 4.52 A, density 1.15 g/cm3, surface area 4983.73 m2/g, accessible volume 0.35 cm3/g