LaC32N4H21S2O9(CH)3 crystallizes in the triclinic P-1 space group. The structure consists of six 02329_fluka molecules inside a LaC32N4H21S2O9 framework. In the LaC32N4H21S2O9 framework, La(1) is bonded in a 9-coordinate geometry to one N(1), one N(2), one N(3), one N(4), one O(1), one O(4), one O(7), one O(8), and one O(9) atom. The La(1)-N(1) bond length is 2.76 Å. The La(1)-N(2) bond length is 2.75 Å. The La(1)-N(3) bond length is 2.78 Å. The La(1)-N(4) bond length is 2.72 Å. The La(1)-O(1) bond length is 2.51 Å. The La(1)-O(4) bond length is 2.59 Å. The La(1)-O(7) bond length is 2.48 Å. The La(1)-O(8) bond length is 2.53 Å. The La(1)-O(9) bond length is 2.53 Å. There are thirty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(12) bond length is 1.42 Å. The C(4)-C(5) bond length is 1.43 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-C(7) bond length is 1.43 Å. The C(6)-H(5) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.42 Å. The C(7)-C(8) bond length is 1.41 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(6) atom. The C(8)-C(9) bond length is 1.38 Å. The C(8)-H(6) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(7) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-H(7) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.33 Å. The C(10)-H(8) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(7), and one N(2) atom. The C(11)-C(12) bond length is 1.44 Å. The C(11)-N(2) bond length is 1.36 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(4), and one N(1) atom. The C(12)-N(1) bond length is 1.36 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(13)-N(3) bond length is 1.33 Å. The C(13)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(11) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(24) atom. The C(16)-C(17) bond length is 1.43 Å. The C(16)-C(24) bond length is 1.42 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(17)-H(12) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(13) atom. The C(18)-C(19) bond length is 1.43 Å. The C(18)-H(13) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(23) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-C(23) bond length is 1.42 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(14) atom. The C(20)-H(14) bond length is 1.09 Å. In the nineteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(16) atom. The C(22)-N(4) bond length is 1.33 Å. The C(22)-H(16) bond length is 1.09 Å. In the twentieth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(19), one C(24), and one N(4) atom. The C(23)-C(24) bond length is 1.44 Å. The C(23)-N(4) bond length is 1.36 Å. In the twenty-first C site, C(24) is bonded in a distorted trigonal planar geometry to one C(16), one C(23), and one N(3) atom. The C(24)-N(3) bond length is 1.36 Å. In the twenty-second C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one C(29), and one H(17) atom. The C(25)-C(26) bond length is 1.42 Å. The C(25)-C(29) bond length is 1.38 Å. The C(25)-H(17) bond length is 1.09 Å. In the twenty-third C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one S(1) atom. The C(26)-C(27) bond length is 1.38 Å. The C(26)-S(1) bond length is 1.78 Å. In the twenty-fourth C site, C(27) is bonded in a distorted single-bond geometry to one C(26), one C(28), and one H(18) atom. The C(27)-C(28) bond length is 1.42 Å. The C(27)-H(18) bond length is 1.09 Å. In the twenty-fifth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(28), and one C(29) atom. The C(28)-C(28) bond length is 1.43 Å. The C(28)-C(29) bond length is 1.42 Å. In the twenty-sixth C site, C(29) is bonded in a distorted single-bond geometry to one C(25), one C(28), and one H(19) atom. The C(29)-H(19) bond length is 1.09 Å. In the twenty-seventh C site, C(30) is bonded in a distorted single-bond geometry to one C(31), one C(34), and one H(20) atom. The C(30)-C(31) bond length is 1.38 Å. The C(30)-C(34) bond length is 1.42 Å. The C(30)-H(20) bond length is 1.09 Å. In the twenty-eighth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one S(2) atom. The C(31)-C(32) bond length is 1.42 Å. The C(31)-S(2) bond length is 1.79 Å. In the twenty-ninth C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(21) atom. The C(32)-H(21) bond length is 1.09 Å. In the thirtieth C site, C(33) is bonded in a distorted single-bond geometry to one C(34) and one H(22) atom. The C(33)-C(34) bond length is 1.42 Å. The C(33)-H(22) bond length is 1.09 Å. In the thirty-first C site, C(34) is bonded in a trigonal planar geometry to one C(30), one C(33), and one C(34) atom. The C(34)-C(34) bond length is 1.43 Å. In the thirty-second C site, C(35) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(35)-O(7) bond length is 1.27 Å. The C(35)-O(8) bond length is 1.26 Å. There are four inequivalent N sites. In the first N site, N(3) is bonded in a distorted bent 120 degrees geometry to one La(1), one C(13), and one C(24) atom. In the second N site, N(4) is bonded in a distorted bent 120 degrees geometry to one La(1), one C(22), and one C(23) atom. In the third N site, N(1) is bonded in a distorted bent 120 degrees geometry to one La(1), one C(1), and one C(12) atom. In the fourth N site, N(2) is bonded in a distorted bent 120 degrees geometry to one La(1), one C(10), and one C(11) atom. There are twenty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(30) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(32) atom. In the nineteenth H site, H(22) is bonded in a single-bond geometry to one C(33) atom. In the twentieth H site, H(23) is bonded in a single-bond geometry to one O(9) atom. The H(23)-O(9) bond length is 0.99 Å. In the twenty-first H site, H(24) is bonded in a distorted single-bond geometry to one O(3) and one O(9) atom. The H(24)-O(3) bond length is 1.65 Å. The H(24)-O(9) bond length is 1.00 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(26), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.49 Å. The S(1)-O(2) bond length is 1.46 Å. The S(1)-O(3) bond length is 1.47 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one C(31), one O(4), one O(5), and one O(6) atom. The S(2)-O(4) bond length is 1.49 Å. The S(2)-O(5) bond length is 1.45 Å. The S(2)-O(6) bond length is 1.47 Å. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one La(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one H(24) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one La(1) and one S(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one La(1) and one C(35) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one La(1) and one C(35) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one La(1), one H(23), and one H(24) atom. Linkers: 2 [O]S([O])([O])c1ccc2cc(S([O])([O])[O])ccc2c1. Metal clusters: 1 O.O.[O][S@](=O)O[La@]1(O[S@@]([O])=O)OC2=C(O1)O[La@@](O[S@]([O])=O)(O[S@@]([O])=O)O2. RCSR code: sql. The MOF has largest included sphere 2.07 A, density 1.79 g/cm3, surface area 3792.01 m2/g, accessible volume 0.09 cm3/g