CH2C4NH9CH3NH2ZnC2(O2Cl)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four ethyl(dimethyl)azanium molecules, four methylammonium molecules, and four ZnC2(O2Cl)2 clusters. In each ZnC2(O2Cl)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one O(1), one O(4), one Cl(1), and one Cl(2) atom. The Zn(1)-O(1) bond length is 2.00 Å. The Zn(1)-O(4) bond length is 2.00 Å. The Zn(1)-Cl(1) bond length is 2.27 Å. The Zn(1)-Cl(2) bond length is 2.27 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(6)-O(3) bond length is 1.26 Å. The C(6)-O(4) bond length is 1.29 Å. There are four inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to one C(6) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 4 [NH3]CC[NH](CCC(=O)[O])CCC(=O)[O]. Metal clusters: 4 O=[C]O[Zn](Cl)(Cl)O[C]=O. The MOF has largest included sphere 1.93 A, density 1.82 g/cm3, surface area 4273.34 m2/g, accessible volume 0.12 cm3/g