(CH3)4ZnC16H8S2(NO2)2 is Indium-derived structured and crystallizes in the orthorhombic C222_1 space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules and eight ZnC16H8S2(NO2)2 clusters. In each ZnC16H8S2(NO2)2 cluster, Zn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(2), and two equivalent O(4) atoms. Both Zn(1)-N(1) bond lengths are 2.13 Å. Both Zn(1)-O(2) bond lengths are 2.13 Å. Both Zn(1)-O(4) bond lengths are 2.09 Å. There are eight inequivalent C sites. In the first C site, C(15,16) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(15) atom. The C(15,16)-N(1) bond length is 1.35 Å. The C(15,16)-H(15) bond length is 1.09 Å. In the second C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one O(4) atom. The C(8)-C(6) bond length is 1.43 Å. The C(8)-O(4) bond length is 1.27 Å. In the third C site, C(17,18) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(17) atom. The C(17,18)-N(1) bond length is 1.35 Å. The C(17,18)-H(17) bond length is 1.09 Å. In the fourth C site, C(11,12) is bonded in a trigonal planar geometry to one C(13,14); one C(19,20); and one S(1) atom. The C(11,12)-C(13,14) bond length is 1.40 Å. The C(11,12)-C(19,20) bond length is 1.41 Å. The C(11,12)-S(1) bond length is 1.75 Å. In the fifth C site, C(4) is bonded in a distorted single-bond geometry to one C(6) and one O(2) atom. The C(4)-C(6) bond length is 1.43 Å. The C(4)-O(2) bond length is 1.27 Å. In the sixth C site, C(19,20) is bonded in a distorted single-bond geometry to one C(11,12) and one H(19,20) atom. The C(19,20)-H(19,20) bond length is 1.09 Å. In the seventh C site, C(6) is bonded in a trigonal planar geometry to one C(4), one C(8), and one S(2) atom. The C(6)-S(2) bond length is 1.77 Å. In the eighth C site, C(13,14) is bonded in a distorted single-bond geometry to one C(11,12) and one H(13,14) atom. The C(13,14)-H(13,14) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1); one C(15,16); and one C(17,18) atom. There are four inequivalent H sites. In the first H site, H(15) is bonded in a single-bond geometry to one C(15,16) atom. In the second H site, H(17) is bonded in a single-bond geometry to one C(17,18) atom. In the third H site, H(19,20) is bonded in a single-bond geometry to one C(19,20) atom. In the fourth H site, H(13,14) is bonded in a single-bond geometry to one C(13,14) atom. S(2) is bonded in a water-like geometry to one C(11,12) and one C(6) atom. The S(2)-C(11,12) bond length is 1.75 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. Linkers: 8 CC(=O)[C](Sc1ccncc1)C(C)=O. Metal clusters: 4 [Zn]. The MOF has largest included sphere 4.13 A, density 1.28 g/cm3, surface area 4967.40 m2/g, accessible volume 0.26 cm3/g