(CH)2ZnC15N2H9O4Cl crystallizes in the triclinic P-1 space group. The structure consists of eight 02329_fluka molecules inside a ZnC15N2H9O4Cl framework. In each ZnC15N2H9O4Cl framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(7), and one Cl(1) atom. The Zn(1)-O(2) bond length is 2.00 Å. The Zn(1)-O(3) bond length is 2.02 Å. The Zn(1)-O(7) bond length is 1.96 Å. The Zn(1)-Cl(1) bond length is 2.23 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one O(1), one O(4), one O(8), and one Cl(2) atom. The Zn(2)-O(1) bond length is 2.00 Å. The Zn(2)-O(4) bond length is 2.02 Å. The Zn(2)-O(8) bond length is 1.96 Å. The Zn(2)-Cl(2) bond length is 2.23 Å. There are twenty-two inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted single-bond geometry to one C(3); one C(5,6); and one H(1,2) atom. The C(1,2)-C(3) bond length is 1.40 Å. The C(1,2)-C(5,6) bond length is 1.40 Å. The C(1,2)-H(1,2) bond length is 1.09 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(1,2); one C(7,8); and one C(9) atom. The C(3)-C(7,8) bond length is 1.40 Å. The C(3)-C(9) bond length is 1.51 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(1,2); one C(10); and one C(7,8) atom. The C(4)-C(1,2) bond length is 1.40 Å. The C(4)-C(10) bond length is 1.51 Å. The C(4)-C(7,8) bond length is 1.40 Å. In the fourth C site, C(5,6) is bonded in a distorted trigonal planar geometry to one C(1,2); one C(15,16); and one N(1) atom. The C(5,6)-C(15,16) bond length is 1.40 Å. The C(5,6)-N(1) bond length is 1.44 Å. In the fifth C site, C(7,8) is bonded in a distorted single-bond geometry to one C(11,12); one C(3); and one H(3,4) atom. The C(7,8)-C(11,12) bond length is 1.39 Å. The C(7,8)-H(3,4) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(5) atom. The C(9)-O(3) bond length is 1.30 Å. The C(9)-O(5) bond length is 1.25 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(4), and one O(6) atom. The C(10)-O(4) bond length is 1.29 Å. The C(10)-O(6) bond length is 1.25 Å. In the eighth C site, C(11,12) is bonded in a distorted trigonal planar geometry to one C(15,16); one C(7,8); and one N(3,4) atom. The C(11,12)-C(15,16) bond length is 1.40 Å. The C(11,12)-N(3,4) bond length is 1.44 Å. In the ninth C site, C(13) is bonded in a distorted single-bond geometry to one C(31) and one O(7) atom. The C(13)-C(31) bond length is 1.43 Å. The C(13)-O(7) bond length is 1.29 Å. In the tenth C site, C(14) is bonded in a distorted single-bond geometry to one C(32) and one O(8) atom. The C(14)-C(32) bond length is 1.43 Å. The C(14)-O(8) bond length is 1.29 Å. In the eleventh C site, C(15,16) is bonded in a distorted single-bond geometry to one C(11,12); one C(5,6); and one H(5,6) atom. The C(15,16)-H(5,6) bond length is 1.09 Å. In the twelfth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(33); one N(3,4); and one H(7,8) atom. The C(17)-C(33) bond length is 1.37 Å. The C(17)-N(3,4) bond length is 1.37 Å. The C(17)-H(7,8) bond length is 1.09 Å. In the thirteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(34); one N(3,4); and one H(7,8) atom. The C(18)-C(34) bond length is 1.37 Å. The C(18)-N(3,4) bond length is 1.37 Å. The C(18)-H(7,8) bond length is 1.09 Å. In the fourteenth C site, C(21,22) is bonded in a 2-coordinate geometry to one N(3,4) and one H(11,12) atom. The C(21,22)-N(3,4) bond length is 1.37 Å. The C(21,22)-H(11,12) bond length is 1.09 Å. In the fifteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(33) and one O(1) atom. The C(23)-C(33) bond length is 1.44 Å. The C(23)-O(1) bond length is 1.28 Å. In the sixteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(34) and one O(2) atom. The C(24)-C(34) bond length is 1.44 Å. The C(24)-O(2) bond length is 1.28 Å. In the seventeenth C site, C(25,26) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13,14) atom. The C(25,26)-N(1) bond length is 1.37 Å. The C(25,26)-H(13,14) bond length is 1.09 Å. In the eighteenth C site, C(27,28) is bonded in a distorted bent 120 degrees geometry to one C(31), one N(1), and one H(15) atom. The C(27,28)-C(31) bond length is 1.36 Å. The C(27,28)-N(1) bond length is 1.37 Å. The C(27,28)-H(15) bond length is 1.09 Å. In the nineteenth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(13); one C(27,28); and one H(19,20) atom. The C(31)-H(19,20) bond length is 1.09 Å. In the twentieth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(14); one C(27,28); and one H(19,20) atom. The C(32)-C(27,28) bond length is 1.36 Å. The C(32)-H(19,20) bond length is 1.09 Å. In the twenty-first C site, C(33) is bonded in a distorted trigonal planar geometry to one C(17), one C(23), and one H(21) atom. The C(33)-H(21) bond length is 1.09 Å. In the twenty-second C site, C(34) is bonded in a distorted trigonal planar geometry to one C(18), one C(24), and one H(22) atom. The C(34)-H(22) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(25,26); one C(27,28); and one C(5,6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(25,26); one C(27,28); and one C(5,6) atom. The N(2)-C(25,26) bond length is 1.37 Å. The N(2)-C(27,28) bond length is 1.37 Å. The N(2)-C(5,6) bond length is 1.44 Å. In the third N site, N(3,4) is bonded in a trigonal planar geometry to one C(11,12); one C(17); and one C(21,22) atom. There are eleven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(7,8) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(15,16) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(11,12) is bonded in a single-bond geometry to one C(21,22) atom. In the sixth H site, H(13,14) is bonded in a single-bond geometry to one C(25,26) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(27,28) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(27,28) atom. The H(16)-C(27,28) bond length is 1.09 Å. In the ninth H site, H(19,20) is bonded in a single-bond geometry to one C(31) atom. In the tenth H site, H(21) is bonded in a single-bond geometry to one C(33) atom. In the eleventh H site, H(22) is bonded in a single-bond geometry to one C(34) atom. There are eight inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(24) atom. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(23) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(9) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zn(2) and one C(10) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(14) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(2) atom. Linkers: 4 [O]C(=O)c1cc(N2[CH]C=C([O])C=C2)cc(N2[CH]C=C([O])C=C2)c1. Metal clusters: 4 [O][Zn]([O])(Cl)O[C]=O. RCSR code: ths. The MOF has largest included sphere 5.22 A, density 1.36 g/cm3, surface area 4350.14 m2/g, accessible volume 0.36 cm3/g