AgC4NH2O3(CH3)4(CF2)3 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, six difluoromethane molecules, and one AgC4NH2O3 cluster. In the AgC4NH2O3 cluster, Ag(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(3) atom. The Ag(1)-O(1) bond length is 2.19 Å. The Ag(1)-O(2) bond length is 2.22 Å. The Ag(1)-O(3) bond length is 2.47 Å. There are four inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(3) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-O(3) bond length is 1.25 Å. In the second C site, C(6) is bonded in a 2-coordinate geometry to one N(1) and one H(1) atom. The C(6)-N(1) bond length is 1.50 Å. The C(6)-H(1) bond length is 1.09 Å. In the third C site, C(9) is bonded in a distorted water-like geometry to one N(1) and one H(8) atom. The C(9)-N(1) bond length is 1.49 Å. The C(9)-H(8) bond length is 1.09 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.26 Å. N(1) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(9) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(9) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ag(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ag(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(1) and one C(5) atom. Linkers: 2 CC(C)N(C(=O)C(F)(F)C(F)(F)C(F)(F)C([O])=O)C(C)C. Metal clusters: 2 [Ag]. The MOF has largest included sphere 2.42 A, density 1.97 g/cm3, surface area 3877.88 m2/g, accessible volume 0.10 cm3/g