Co3C14H8(NO5)2 crystallizes in the triclinic P1 space group. There are twelve inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(2), one O(2), one O(24), one O(33), one O(35), and one O(9) atom to form CoNO5 octahedra that share  a cornercorner with one Co(7)O6 octahedra,  an edgeedge with one Co(3)NO5 octahedra, and  an edgeedge with one Co(5)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. The Co(1)-N(2) bond length is 2.08 Å. The Co(1)-O(2) bond length is 2.09 Å. The Co(1)-O(24) bond length is 2.05 Å. The Co(1)-O(33) bond length is 2.14 Å. The Co(1)-O(35) bond length is 2.11 Å. The Co(1)-O(9) bond length is 2.07 Å. In the second Co site, Co(2) is bonded to one N(1), one O(1), one O(10), one O(23), one O(34), and one O(36) atom to form CoNO5 octahedra that share  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Co(4)NO5 octahedra, and  an edgeedge with one Co(6)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. The Co(2)-N(1) bond length is 2.07 Å. The Co(2)-O(1) bond length is 2.10 Å. The Co(2)-O(10) bond length is 2.07 Å. The Co(2)-O(23) bond length is 2.04 Å. The Co(2)-O(34) bond length is 2.11 Å. The Co(2)-O(36) bond length is 2.11 Å. In the third Co site, Co(3) is bonded to one N(4), one O(11), one O(22), one O(33), one O(35), and one O(4) atom to form CoNO5 octahedra that share  a cornercorner with one Co(5)O6 octahedra,  an edgeedge with one Co(1)NO5 octahedra, and  an edgeedge with one Co(7)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. The Co(3)-N(4) bond length is 2.08 Å. The Co(3)-O(11) bond length is 2.07 Å. The Co(3)-O(22) bond length is 2.05 Å. The Co(3)-O(33) bond length is 2.12 Å. The Co(3)-O(35) bond length is 2.14 Å. The Co(3)-O(4) bond length is 2.09 Å. In the fourth Co site, Co(4) is bonded to one N(3), one O(12), one O(21), one O(3), one O(34), and one O(36) atom to form CoNO5 octahedra that share  a cornercorner with one Co(6)O6 octahedra,  an edgeedge with one Co(2)NO5 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles are 60°. The Co(4)-N(3) bond length is 2.08 Å. The Co(4)-O(12) bond length is 2.07 Å. The Co(4)-O(21) bond length is 2.04 Å. The Co(4)-O(3) bond length is 2.09 Å. The Co(4)-O(34) bond length is 2.09 Å. The Co(4)-O(36) bond length is 2.16 Å. In the fifth Co site, Co(5) is bonded to one O(13), one O(18), one O(2), one O(29), one O(33), and one O(37) atom to form a mixture of edge and corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 59°. The Co(5)-O(13) bond length is 2.06 Å. The Co(5)-O(18) bond length is 2.05 Å. The Co(5)-O(2) bond length is 2.04 Å. The Co(5)-O(29) bond length is 2.05 Å. The Co(5)-O(33) bond length is 2.11 Å. The Co(5)-O(37) bond length is 2.11 Å. In the sixth Co site, Co(6) is bonded to one O(1), one O(14), one O(17), one O(30), one O(34), and one O(38) atom to form a mixture of edge and corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 60-61°. The Co(6)-O(1) bond length is 2.06 Å. The Co(6)-O(14) bond length is 2.02 Å. The Co(6)-O(17) bond length is 2.07 Å. The Co(6)-O(30) bond length is 2.02 Å. The Co(6)-O(34) bond length is 2.16 Å. The Co(6)-O(38) bond length is 2.11 Å. In the seventh Co site, Co(7) is bonded to one O(15), one O(20), one O(31), one O(35), one O(39), and one O(4) atom to form a mixture of edge and corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 59°. The Co(7)-O(15) bond length is 2.05 Å. The Co(7)-O(20) bond length is 2.04 Å. The Co(7)-O(31) bond length is 2.05 Å. The Co(7)-O(35) bond length is 2.11 Å. The Co(7)-O(39) bond length is 2.11 Å. The Co(7)-O(4) bond length is 2.04 Å. In the eighth Co site, Co(8) is bonded to one O(16), one O(19), one O(3), one O(32), one O(36), and one O(40) atom to form a mixture of edge and corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 59-60°. The Co(8)-O(16) bond length is 2.05 Å. The Co(8)-O(19) bond length is 2.05 Å. The Co(8)-O(3) bond length is 2.05 Å. The Co(8)-O(32) bond length is 2.05 Å. The Co(8)-O(36) bond length is 2.10 Å. The Co(8)-O(40) bond length is 2.11 Å. In the ninth Co site, Co(9) is bonded to one N(6), one O(18), one O(25), one O(37), one O(39), and one O(8) atom to form CoNO5 octahedra that share  a cornercorner with one Co(7)O6 octahedra,  an edgeedge with one Co(11)NO5 octahedra, and  an edgeedge with one Co(5)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. The Co(9)-N(6) bond length is 2.07 Å. The Co(9)-O(18) bond length is 2.09 Å. The Co(9)-O(25) bond length is 2.07 Å. The Co(9)-O(37) bond length is 2.14 Å. The Co(9)-O(39) bond length is 2.11 Å. The Co(9)-O(8) bond length is 2.05 Å. In the tenth Co site, Co(10) is bonded to one N(5), one O(17), one O(26), one O(38), one O(40), and one O(7) atom to form CoNO5 octahedra that share  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Co(12)NO5 octahedra, and  an edgeedge with one Co(6)O6 octahedra. The corner-sharing octahedral tilt angles are 60°. The Co(10)-N(5) bond length is 2.07 Å. The Co(10)-O(17) bond length is 2.09 Å. The Co(10)-O(26) bond length is 2.06 Å. The Co(10)-O(38) bond length is 2.13 Å. The Co(10)-O(40) bond length is 2.10 Å. The Co(10)-O(7) bond length is 2.05 Å. In the eleventh Co site, Co(11) is bonded to one N(8), one O(20), one O(27), one O(37), one O(39), and one O(6) atom to form CoNO5 octahedra that share  a cornercorner with one Co(5)O6 octahedra,  an edgeedge with one Co(9)NO5 octahedra, and  an edgeedge with one Co(7)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. The Co(11)-N(8) bond length is 2.08 Å. The Co(11)-O(20) bond length is 2.09 Å. The Co(11)-O(27) bond length is 2.07 Å. The Co(11)-O(37) bond length is 2.12 Å. The Co(11)-O(39) bond length is 2.13 Å. The Co(11)-O(6) bond length is 2.04 Å. In the twelfth Co site, Co(12) is bonded to one N(7), one O(19), one O(28), one O(38), one O(40), and one O(5) atom to form CoNO5 octahedra that share  a cornercorner with one Co(6)O6 octahedra,  an edgeedge with one Co(10)NO5 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles are 61°. The Co(12)-N(7) bond length is 2.08 Å. The Co(12)-O(19) bond length is 2.09 Å. The Co(12)-O(28) bond length is 2.06 Å. The Co(12)-O(38) bond length is 2.11 Å. The Co(12)-O(40) bond length is 2.15 Å. The Co(12)-O(5) bond length is 2.03 Å. There are fifty-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(21), one C(5), and one N(1) atom. The C(1)-C(21) bond length is 1.49 Å. The C(1)-C(5) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(22), one C(6), and one N(2) atom. The C(2)-C(22) bond length is 1.49 Å. The C(2)-C(6) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.36 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(23), one C(7), and one N(3) atom. The C(3)-C(23) bond length is 1.49 Å. The C(3)-C(7) bond length is 1.39 Å. The C(3)-N(3) bond length is 1.36 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(24), one C(8), and one N(4) atom. The C(4)-C(24) bond length is 1.49 Å. The C(4)-C(8) bond length is 1.39 Å. The C(4)-N(4) bond length is 1.36 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(1), one C(9), and one H(1) atom. The C(5)-C(9) bond length is 1.40 Å. The C(5)-H(1) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(10), one C(2), and one H(2) atom. The C(6)-C(10) bond length is 1.40 Å. The C(6)-H(2) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(11), one C(3), and one H(3) atom. The C(7)-C(11) bond length is 1.40 Å. The C(7)-H(3) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(12), one C(4), and one H(4) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-H(4) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(13), one C(25), and one C(5) atom. The C(9)-C(13) bond length is 1.40 Å. The C(9)-C(25) bond length is 1.50 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(14), one C(26), and one C(6) atom. The C(10)-C(14) bond length is 1.40 Å. The C(10)-C(26) bond length is 1.50 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(15), one C(27), and one C(7) atom. The C(11)-C(15) bond length is 1.40 Å. The C(11)-C(27) bond length is 1.50 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(16), one C(28), and one C(8) atom. The C(12)-C(16) bond length is 1.40 Å. The C(12)-C(28) bond length is 1.51 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(17); one C(9); and one H(5,18) atom. The C(13)-C(17) bond length is 1.39 Å. The C(13)-H(5,18) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(10), one C(18), and one H(6) atom. The C(14)-C(18) bond length is 1.39 Å. The C(14)-H(6) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(11), one C(19), and one H(7) atom. The C(15)-C(19) bond length is 1.39 Å. The C(15)-H(7) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(12), one C(20), and one H(8) atom. The C(16)-C(20) bond length is 1.39 Å. The C(16)-H(8) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(1), and one H(9) atom. The C(17)-N(1) bond length is 1.34 Å. The C(17)-H(9) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(2), and one H(10) atom. The C(18)-N(2) bond length is 1.34 Å. The C(18)-H(10) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(3), and one H(11) atom. The C(19)-N(3) bond length is 1.34 Å. The C(19)-H(11) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(4), and one H(12) atom. The C(20)-N(4) bond length is 1.34 Å. The C(20)-H(12) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(5) atom. The C(21)-O(1) bond length is 1.28 Å. The C(21)-O(5) bond length is 1.26 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(6) atom. The C(22)-O(2) bond length is 1.28 Å. The C(22)-O(6) bond length is 1.26 Å. In the twenty-third C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(7) atom. The C(23)-O(3) bond length is 1.28 Å. The C(23)-O(7) bond length is 1.26 Å. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(4), and one O(8) atom. The C(24)-O(4) bond length is 1.28 Å. The C(24)-O(8) bond length is 1.26 Å. In the twenty-fifth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(13), and one O(9) atom. The C(25)-O(13) bond length is 1.27 Å. The C(25)-O(9) bond length is 1.27 Å. In the twenty-sixth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(10), and one O(14) atom. The C(26)-O(10) bond length is 1.27 Å. The C(26)-O(14) bond length is 1.27 Å. In the twenty-seventh C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(11), and one O(15) atom. The C(27)-O(11) bond length is 1.27 Å. The C(27)-O(15) bond length is 1.27 Å. In the twenty-eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(12), and one O(16) atom. The C(28)-O(12) bond length is 1.27 Å. The C(28)-O(16) bond length is 1.27 Å. In the twenty-ninth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(33), one C(49), and one N(5) atom. The C(29)-C(33) bond length is 1.39 Å. The C(29)-C(49) bond length is 1.50 Å. The C(29)-N(5) bond length is 1.36 Å. In the thirtieth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(34), one C(50), and one N(6) atom. The C(30)-C(34) bond length is 1.39 Å. The C(30)-C(50) bond length is 1.49 Å. The C(30)-N(6) bond length is 1.36 Å. In the thirty-first C site, C(31) is bonded in a distorted trigonal planar geometry to one C(35), one C(51), and one N(7) atom. The C(31)-C(35) bond length is 1.39 Å. The C(31)-C(51) bond length is 1.49 Å. The C(31)-N(7) bond length is 1.36 Å. In the thirty-second C site, C(32) is bonded in a distorted trigonal planar geometry to one C(36), one C(52), and one N(8) atom. The C(32)-C(36) bond length is 1.39 Å. The C(32)-C(52) bond length is 1.49 Å. The C(32)-N(8) bond length is 1.36 Å. In the thirty-third C site, C(33) is bonded in a distorted trigonal planar geometry to one C(29), one C(37), and one H(13) atom. The C(33)-C(37) bond length is 1.40 Å. The C(33)-H(13) bond length is 1.09 Å. In the thirty-fourth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(30), one C(38), and one H(14) atom. The C(34)-C(38) bond length is 1.40 Å. The C(34)-H(14) bond length is 1.09 Å. In the thirty-fifth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(31), one C(39), and one H(15) atom. The C(35)-C(39) bond length is 1.40 Å. The C(35)-H(15) bond length is 1.09 Å. In the thirty-sixth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(32), one C(40), and one H(16) atom. The C(36)-C(40) bond length is 1.40 Å. The C(36)-H(16) bond length is 1.09 Å. In the thirty-seventh C site, C(37) is bonded in a trigonal planar geometry to one C(33), one C(41), and one C(53) atom. The C(37)-C(41) bond length is 1.40 Å. The C(37)-C(53) bond length is 1.50 Å. In the thirty-eighth C site, C(38) is bonded in a trigonal planar geometry to one C(34), one C(42), and one C(54) atom. The C(38)-C(42) bond length is 1.40 Å. The C(38)-C(54) bond length is 1.50 Å. In the thirty-ninth C site, C(39) is bonded in a trigonal planar geometry to one C(35), one C(43), and one C(55) atom. The C(39)-C(43) bond length is 1.40 Å. The C(39)-C(55) bond length is 1.50 Å. In the fortieth C site, C(40) is bonded in a trigonal planar geometry to one C(36), one C(44), and one C(56) atom. The C(40)-C(44) bond length is 1.40 Å. The C(40)-C(56) bond length is 1.50 Å. In the forty-first C site, C(41) is bonded in a distorted trigonal planar geometry to one C(37), one C(45), and one H(17) atom. The C(41)-C(45) bond length is 1.39 Å. The C(41)-H(17) bond length is 1.09 Å. In the forty-second C site, C(42) is bonded in a distorted trigonal planar geometry to one C(38); one C(46); and one H(5,18) atom. The C(42)-C(46) bond length is 1.39 Å. The C(42)-H(5,18) bond length is 1.09 Å. In the forty-third C site, C(43) is bonded in a distorted trigonal planar geometry to one C(39), one C(47), and one H(19) atom. The C(43)-C(47) bond length is 1.39 Å. The C(43)-H(19) bond length is 1.09 Å. In the forty-fourth C site, C(44) is bonded in a distorted trigonal planar geometry to one C(40), one C(48), and one H(20) atom. The C(44)-C(48) bond length is 1.39 Å. The C(44)-H(20) bond length is 1.09 Å. In the forty-fifth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(41), one N(5), and one H(21) atom. The C(45)-N(5) bond length is 1.34 Å. The C(45)-H(21) bond length is 1.09 Å. In the forty-sixth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one C(42), one N(6), and one H(22) atom. The C(46)-N(6) bond length is 1.34 Å. The C(46)-H(22) bond length is 1.09 Å. In the forty-seventh C site, C(47) is bonded in a distorted bent 120 degrees geometry to one C(43), one N(7), and one H(23) atom. The C(47)-N(7) bond length is 1.34 Å. The C(47)-H(23) bond length is 1.09 Å. In the forty-eighth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(44), one N(8), and one H(24) atom. The C(48)-N(8) bond length is 1.34 Å. The C(48)-H(24) bond length is 1.09 Å. In the forty-ninth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(17), and one O(21) atom. The C(49)-O(17) bond length is 1.28 Å. The C(49)-O(21) bond length is 1.26 Å. In the fiftieth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(18), and one O(22) atom. The C(50)-O(18) bond length is 1.28 Å. The C(50)-O(22) bond length is 1.26 Å. In the fifty-first C site, C(51) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(19), and one O(23) atom. The C(51)-O(19) bond length is 1.28 Å. The C(51)-O(23) bond length is 1.26 Å. In the fifty-second C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(20), and one O(24) atom. The C(52)-O(20) bond length is 1.28 Å. The C(52)-O(24) bond length is 1.26 Å. In the fifty-third C site, C(53) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(25), and one O(29) atom. The C(53)-O(25) bond length is 1.27 Å. The C(53)-O(29) bond length is 1.27 Å. In the fifty-fourth C site, C(54) is bonded in a distorted bent 120 degrees geometry to one C(38), one O(26), and one O(30) atom. The C(54)-O(26) bond length is 1.27 Å. The C(54)-O(30) bond length is 1.28 Å. In the fifty-fifth C site, C(55) is bonded in a distorted bent 120 degrees geometry to one C(39), one O(27), and one O(31) atom. The C(55)-O(27) bond length is 1.27 Å. The C(55)-O(31) bond length is 1.27 Å. In the fifty-sixth C site, C(56) is bonded in a distorted bent 120 degrees geometry to one C(40), one O(28), and one O(32) atom. The C(56)-O(28) bond length is 1.27 Å. The C(56)-O(32) bond length is 1.27 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(2), one C(1), and one C(17) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(18), and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(4), one C(19), and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(3), one C(20), and one C(4) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(10), one C(29), and one C(45) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Co(9), one C(30), and one C(46) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Co(12), one C(31), and one C(47) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Co(11), one C(32), and one C(48) atom. There are thirty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5,18) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(33) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(34) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(35) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(36) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(41) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(43) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(44) atom. In the twentieth H site, H(21) is bonded in a single-bond geometry to one C(45) atom. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one C(46) atom. In the twenty-second H site, H(23) is bonded in a single-bond geometry to one C(47) atom. In the twenty-third H site, H(24) is bonded in a single-bond geometry to one C(48) atom. In the twenty-fourth H site, H(25) is bonded in a single-bond geometry to one O(33) atom. The H(25)-O(33) bond length is 0.97 Å. In the twenty-fifth H site, H(26) is bonded in a single-bond geometry to one O(34) atom. The H(26)-O(34) bond length is 0.97 Å. In the twenty-sixth H site, H(27) is bonded in a single-bond geometry to one O(35) atom. The H(27)-O(35) bond length is 0.97 Å. In the twenty-seventh H site, H(28) is bonded in a single-bond geometry to one O(36) atom. The H(28)-O(36) bond length is 0.97 Å. In the twenty-eighth H site, H(29) is bonded in a single-bond geometry to one O(37) atom. The H(29)-O(37) bond length is 0.97 Å. In the twenty-ninth H site, H(30) is bonded in a single-bond geometry to one O(38) atom. The H(30)-O(38) bond length is 0.97 Å. In the thirtieth H site, H(31) is bonded in a single-bond geometry to one O(39) atom. The H(31)-O(39) bond length is 0.97 Å. In the thirty-first H site, H(32) is bonded in a single-bond geometry to one O(40) atom. The H(32)-O(40) bond length is 0.97 Å. There are forty inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(6), and one C(21) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(5), and one C(22) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Co(4), one Co(8), and one C(23) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Co(3), one Co(7), and one C(24) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Co(12) and one C(21) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Co(11) and one C(22) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Co(10) and one C(23) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Co(9) and one C(24) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(25) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(26) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Co(3) and one C(27) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Co(4) and one C(28) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Co(5) and one C(25) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Co(6) and one C(26) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Co(7) and one C(27) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Co(8) and one C(28) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Co(10), one Co(6), and one C(49) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Co(5), one Co(9), and one C(50) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Co(12), one Co(8), and one C(51) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Co(11), one Co(7), and one C(52) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 120 degrees geometry to one Co(4) and one C(49) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Co(3) and one C(50) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Co(2) and one C(51) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(52) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 120 degrees geometry to one Co(9) and one C(53) atom. In the twenty-sixth O site, O(26) is bonded in a distorted bent 120 degrees geometry to one Co(10) and one C(54) atom. In the twenty-seventh O site, O(27) is bonded in a distorted bent 120 degrees geometry to one Co(11) and one C(55) atom. In the twenty-eighth O site, O(28) is bonded in a distorted bent 120 degrees geometry to one Co(12) and one C(56) atom. In the twenty-ninth O site, O(29) is bonded in a bent 120 degrees geometry to one Co(5) and one C(53) atom. In the thirtieth O site, O(30) is bonded in a bent 120 degrees geometry to one Co(6) and one C(54) atom. In the thirty-first O site, O(31) is bonded in a bent 120 degrees geometry to one Co(7) and one C(55) atom. In the thirty-second O site, O(32) is bonded in a bent 120 degrees geometry to one Co(8) and one C(56) atom. In the thirty-third O site, O(33) is bonded in a distorted single-bond geometry to one Co(1), one Co(3), one Co(5), and one H(25) atom. In the thirty-fourth O site, O(34) is bonded in a distorted single-bond geometry to one Co(2), one Co(4), one Co(6), and one H(26) atom. In the thirty-fifth O site, O(35) is bonded in a distorted single-bond geometry to one Co(1), one Co(3), one Co(7), and one H(27) atom. In the thirty-sixth O site, O(36) is bonded in a distorted single-bond geometry to one Co(2), one Co(4), one Co(8), and one H(28) atom. In the thirty-seventh O site, O(37) is bonded in a distorted single-bond geometry to one Co(11), one Co(5), one Co(9), and one H(29) atom. In the thirty-eighth O site, O(38) is bonded in a distorted single-bond geometry to one Co(10), one Co(12), one Co(6), and one H(30) atom. In the thirty-ninth O site, O(39) is bonded in a distorted single-bond geometry to one Co(11), one Co(7), one Co(9), and one H(31) atom. In the fortieth O site, O(40) is bonded in a distorted single-bond geometry to one Co(10), one Co(12), one Co(8), and one H(32) atom. Linkers: 8 [O]C(=O)c1ccnc(C([O])=O)c1. Metal clusters: 12 [Co]. The MOF has largest included sphere 6.32 A, density 1.48 g/cm3, surface area 2858.64 m2/g, accessible volume 0.31 cm3/g