NiC10H9(NO)3(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one NiC10H9(NO)3 cluster. In the NiC10H9(NO)3 cluster, Ni(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(3), and two equivalent O(2) atoms. The Ni(1)-N(1) bond length is 1.87 Å. The Ni(1)-N(3) bond length is 1.89 Å. Both Ni(1)-O(2) bond lengths are 1.87 Å. There are ten inequivalent C sites. In the first C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(3) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-N(1) bond length is 1.36 Å. The C(2)-H(3) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(3)-H(4) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(6) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-H(6) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one N(2) atom. The C(6)-N(1) bond length is 1.35 Å. The C(6)-N(2) bond length is 1.38 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one N(3) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-N(2) bond length is 1.38 Å. The C(7)-N(3) bond length is 1.36 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(7) atom. The C(8)-C(9) bond length is 1.38 Å. The C(8)-H(7) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(8) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(9) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-H(9) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(3), and one H(10) atom. The C(11)-N(3) bond length is 1.36 Å. The C(11)-H(10) bond length is 1.08 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(12)-O(1) bond length is 1.26 Å. The C(12)-O(3) bond length is 1.29 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(2), and one C(6) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one H(1) atom. The N(2)-H(1) bond length is 1.02 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ni(1), one C(11), and one C(7) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(11) is bonded in a distorted linear geometry to one O(2) and one O(3) atom. The H(11)-O(2) bond length is 1.04 Å. The H(11)-O(3) bond length is 1.53 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(12) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Ni(1) and one H(11) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(12) and one H(11) atom. Linkers: 2 c1ccc(Nc2ccccn2)nc1. Metal clusters: 1 O[Ni].O[Ni]. The MOF has largest included sphere 2.30 A, density 1.70 g/cm3, surface area 4158.29 m2/g, accessible volume 0.14 cm3/g