LiSnC7H8(OF2)3(CF3)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six trifluoromethane molecules and one LiSnC7H8(OF2)3 cluster. In the LiSnC7H8(OF2)3 cluster, Li(1) is bonded to one O(1), one O(2), one O(3), and one F(11) atom to form LiO3F trigonal pyramids that share corners with two equivalent Sn(1)C3O2 trigonal bipyramids. The Li(1)-O(1) bond length is 1.85 Å. The Li(1)-O(2) bond length is 1.94 Å. The Li(1)-O(3) bond length is 1.98 Å. The Li(1)-F(11) bond length is 2.12 Å. Sn(1) is bonded to one C(1), one C(3), one C(5), and two equivalent O(1) atoms to form distorted SnC3O2 trigonal bipyramids that share corners with two equivalent Li(1)O3F trigonal pyramids and  an edgeedge with one Sn(1)C3O2 trigonal bipyramid. The Sn(1)-C(1) bond length is 2.28 Å. The Sn(1)-C(3) bond length is 2.28 Å. The Sn(1)-C(5) bond length is 2.35 Å. There is one shorter (2.03 Å) and one longer (2.10 Å) Sn(1)-O(1) bond length. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one Sn(1), one F(1), and one F(2) atom. The C(1)-F(1) bond length is 1.38 Å. The C(1)-F(2) bond length is 1.39 Å. In the second C site, C(3) is bonded in a distorted water-like geometry to one Sn(1), one F(6), and one F(7) atom. The C(3)-F(6) bond length is 1.39 Å. The C(3)-F(7) bond length is 1.38 Å. In the third C site, C(5) is bonded in a distorted water-like geometry to one Sn(1), one F(11), and one F(12) atom. The C(5)-F(11) bond length is 1.42 Å. The C(5)-F(12) bond length is 1.39 Å. In the fourth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one O(2) atom. The C(7)-H(1) bond length is 1.10 Å. The C(7)-H(2) bond length is 1.10 Å. The C(7)-O(2) bond length is 1.44 Å. In the fifth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(4), and one O(2) atom. The C(8)-H(3) bond length is 1.10 Å. The C(8)-H(4) bond length is 1.09 Å. The C(8)-O(2) bond length is 1.44 Å. In the sixth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(6), and one O(3) atom. The C(9)-H(5) bond length is 1.10 Å. The C(9)-H(6) bond length is 1.10 Å. The C(9)-O(3) bond length is 1.45 Å. In the seventh C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one H(7), one H(8), and one O(3) atom. The C(10)-H(7) bond length is 1.09 Å. The C(10)-H(8) bond length is 1.10 Å. The C(10)-O(3) bond length is 1.45 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent Sn(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one Li(1), one C(7), and one C(8) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Li(1), one C(10), and one C(9) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one C(3) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one C(3) atom. In the fifth F site, F(11) is bonded in a bent 120 degrees geometry to one Li(1) and one C(5) atom. In the sixth F site, F(12) is bonded in a single-bond geometry to one C(5) atom. Linkers: 2 C1COCCO1. Metal clusters: 1 [Li]O[Sn]C(F)(F)C(F)(F)F.[Li]O[Sn]C(F)(F)C(F)(F)F. The MOF has largest included sphere 2.47 A, density 2.20 g/cm3, surface area 3294.66 m2/g, accessible volume 0.13 cm3/g