Cu3C24N3H25O11(CH)4(CH3O)2H2O is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, four methanol molecules, two propylene molecules, two water molecules, and two Cu3C24N3H25O11 clusters. In each Cu3C24N3H25O11 cluster, there are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(13), one O(2), and one O(5) atom. The Cu(1)-N(1) bond length is 2.01 Å. The Cu(1)-O(1) bond length is 1.95 Å. The Cu(1)-O(13) bond length is 2.41 Å. The Cu(1)-O(2) bond length is 1.94 Å. The Cu(1)-O(5) bond length is 2.01 Å. In the second Cu site, Cu(2) is bonded in a distorted rectangular see-saw-like geometry to one N(2), one O(1), one O(5), and one O(6) atom. The Cu(2)-N(2) bond length is 1.98 Å. The Cu(2)-O(1) bond length is 1.96 Å. The Cu(2)-O(5) bond length is 1.97 Å. The Cu(2)-O(6) bond length is 1.94 Å. In the third Cu site, Cu(3) is bonded in a 6-coordinate geometry to one N(3), one O(10), one O(2), one O(3), one O(4), and one O(9) atom. The Cu(3)-N(3) bond length is 2.00 Å. The Cu(3)-O(10) bond length is 1.99 Å. The Cu(3)-O(2) bond length is 2.57 Å. The Cu(3)-O(3) bond length is 2.05 Å. The Cu(3)-O(4) bond length is 2.29 Å. The Cu(3)-O(9) bond length is 1.95 Å. There are twenty-four inequivalent C sites. In the first C site, C(25) is bonded in a distorted single-bond geometry to one C(24), one C(26), and one H(26) atom. The C(25)-C(24) bond length is 1.39 Å. The C(25)-C(26) bond length is 1.40 Å. The C(25)-H(26) bond length is 1.09 Å. In the second C site, C(26) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(27) atom. The C(26)-C(21) bond length is 1.42 Å. The C(26)-C(27) bond length is 1.50 Å. In the third C site, C(27) is bonded in a distorted trigonal non-coplanar geometry to one C(26), one N(3), one H(27), and one H(28) atom. The C(27)-N(3) bond length is 1.48 Å. The C(27)-H(27) bond length is 1.10 Å. The C(27)-H(28) bond length is 1.10 Å. In the fourth C site, C(28) is bonded in a distorted water-like geometry to one N(3) and one H(30) atom. The C(28)-N(3) bond length is 1.48 Å. The C(28)-H(30) bond length is 1.10 Å. In the fifth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(11) atom. The C(29)-O(10) bond length is 1.30 Å. The C(29)-O(11) bond length is 1.24 Å. In the sixth C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one O(1) atom. The C(1)-C(6) bond length is 1.42 Å. The C(1)-O(1) bond length is 1.35 Å. In the seventh C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the eighth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.51 Å. In the ninth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one N(1), one H(5), and one H(6) atom. The C(7)-N(1) bond length is 1.49 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. In the tenth C site, C(8) is bonded in a distorted water-like geometry to one N(1) and one H(8) atom. The C(8)-N(1) bond length is 1.48 Å. The C(8)-H(8) bond length is 1.10 Å. In the eleventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(9)-O(2) bond length is 1.28 Å. The C(9)-O(3) bond length is 1.27 Å. In the twelfth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one H(10), one H(9), and one O(4) atom. The C(10)-H(10) bond length is 1.10 Å. The C(10)-H(9) bond length is 1.10 Å. The C(10)-O(4) bond length is 1.42 Å. In the thirteenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(16), and one O(5) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-C(16) bond length is 1.42 Å. The C(11)-O(5) bond length is 1.34 Å. In the fourteenth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(12) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(12) bond length is 1.09 Å. In the fifteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(13) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-H(13) bond length is 1.09 Å. In the sixteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(14) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(14) bond length is 1.09 Å. In the seventeenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(15) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(15) bond length is 1.09 Å. In the eighteenth C site, C(16) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(17) atom. The C(16)-C(17) bond length is 1.51 Å. In the nineteenth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one C(16), one N(2), one H(16), and one H(17) atom. The C(17)-N(2) bond length is 1.48 Å. The C(17)-H(16) bond length is 1.10 Å. The C(17)-H(17) bond length is 1.10 Å. In the twentieth C site, C(18) is bonded in a distorted water-like geometry to one N(2) and one H(19) atom. The C(18)-N(2) bond length is 1.48 Å. The C(18)-H(19) bond length is 1.10 Å. In the twenty-first C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(19)-O(6) bond length is 1.30 Å. The C(19)-O(7) bond length is 1.25 Å. In the twenty-second C site, C(21) is bonded in a distorted single-bond geometry to one C(26) and one O(9) atom. The C(21)-O(9) bond length is 1.34 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(24) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-H(24) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one C(25), and one H(25) atom. The C(24)-H(25) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted tetrahedral geometry to one Cu(1), one C(7), one C(8), and one H(7) atom. The N(1)-H(7) bond length is 1.04 Å. In the second N site, N(2) is bonded in a distorted tetrahedral geometry to one Cu(2), one C(17), one C(18), and one H(18) atom. The N(2)-H(18) bond length is 1.04 Å. In the third N site, N(3) is bonded in a distorted tetrahedral geometry to one Cu(3), one C(27), one C(28), and one H(29) atom. The N(3)-H(29) bond length is 1.03 Å. There are twenty-five inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one O(4) atom. The H(11)-O(4) bond length is 1.00 Å. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one N(2) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the seventeenth H site, H(24) is bonded in a single-bond geometry to one C(23) atom. In the eighteenth H site, H(25) is bonded in a single-bond geometry to one C(24) atom. In the nineteenth H site, H(26) is bonded in a single-bond geometry to one C(25) atom. In the twentieth H site, H(27) is bonded in a single-bond geometry to one C(27) atom. In the twenty-first H site, H(28) is bonded in a single-bond geometry to one C(27) atom. In the twenty-second H site, H(29) is bonded in a single-bond geometry to one N(3) atom. In the twenty-third H site, H(30) is bonded in a single-bond geometry to one C(28) atom. In the twenty-fourth H site, H(34) is bonded in a single-bond geometry to one O(13) atom. The H(34)-O(13) bond length is 0.98 Å. In the twenty-fifth H site, H(35) is bonded in a single-bond geometry to one O(13) atom. The H(35)-O(13) bond length is 0.99 Å. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one Cu(2), and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1), one Cu(3), and one C(9) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cu(3) and one C(9) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Cu(3), one C(10), and one H(11) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Cu(1), one Cu(2), and one C(11) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(19) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(19) atom. In the eighth O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(21) atom. In the ninth O site, O(10) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(29) atom. In the tenth O site, O(11) is bonded in a single-bond geometry to one C(29) atom. In the eleventh O site, O(13) is bonded in a water-like geometry to one Cu(1), one H(34), and one H(35) atom. Linkers: 4 [O]C(=O)[C@H](CO)NCc1ccccc1[O]. Metal clusters: 6 [Cu]. The MOF has largest included sphere 3.59 A, density 1.65 g/cm3, surface area 3972.51 m2/g, accessible volume 0.12 cm3/g