(CH)4SnC22H18(N2O)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four SnC22H18(N2O)2 clusters. In each SnC22H18(N2O)2 cluster, Sn(1) is bonded in a distorted trigonal bipyramidal geometry to one C(1), one C(13), one C(7), one N(1), and one O(1) atom. The Sn(1)-C(1) bond length is 2.14 Å. The Sn(1)-C(13) bond length is 2.14 Å. The Sn(1)-C(7) bond length is 2.14 Å. The Sn(1)-N(1) bond length is 2.60 Å. The Sn(1)-O(1) bond length is 2.16 Å. There are twenty-two inequivalent C sites. In the first C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(8) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(9) bond length is 1.40 Å. The C(10)-H(8) bond length is 1.09 Å. In the second C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(9) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(9) bond length is 1.09 Å. In the third C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(7), and one H(10) atom. The C(12)-C(7) bond length is 1.40 Å. The C(12)-H(10) bond length is 1.09 Å. In the fourth C site, C(13) is bonded in a trigonal planar geometry to one Sn(1), one C(14), and one C(18) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(18) bond length is 1.40 Å. In the fifth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(11) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(11) bond length is 1.09 Å. In the sixth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(12) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(12) bond length is 1.09 Å. In the seventh C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one H(13) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(13) bond length is 1.09 Å. In the eighth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(14) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(14) bond length is 1.09 Å. In the ninth C site, C(18) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one H(15) atom. The C(18)-H(15) bond length is 1.09 Å. In the tenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(16) atom. The C(19)-N(1) bond length is 1.34 Å. The C(19)-H(16) bond length is 1.08 Å. In the eleventh C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(18) atom. The C(21)-N(2) bond length is 1.36 Å. The C(21)-H(18) bond length is 1.08 Å. In the twelfth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(23), one N(3), and one H(19) atom. The C(22)-C(23) bond length is 1.38 Å. The C(22)-N(3) bond length is 1.36 Å. The C(22)-H(19) bond length is 1.08 Å. In the thirteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22), one C(24), and one H(20) atom. The C(23)-C(24) bond length is 1.41 Å. The C(23)-H(20) bond length is 1.08 Å. In the fourteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(23), one N(4), and one H(21) atom. The C(24)-N(4) bond length is 1.34 Å. The C(24)-H(21) bond length is 1.09 Å. In the fifteenth C site, C(25) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one N(3), and one H(22) atom. The C(25)-N(2) bond length is 1.45 Å. The C(25)-N(3) bond length is 1.45 Å. The C(25)-H(22) bond length is 1.10 Å. In the sixteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(26)-O(1) bond length is 1.30 Å. The C(26)-O(2) bond length is 1.23 Å. In the seventeenth C site, C(1) is bonded in a trigonal planar geometry to one Sn(1), one C(2), and one C(6) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. In the eighteenth C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the nineteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the twentieth C site, C(7) is bonded in a trigonal planar geometry to one Sn(1), one C(12), and one C(8) atom. The C(7)-C(8) bond length is 1.40 Å. In the twenty-first C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(6) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(6) bond length is 1.09 Å. In the twenty-second C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one Sn(1), one C(19), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(21), one C(25), and one N(1) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(22), one C(25), and one N(4) atom. The N(3)-N(4) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a distorted water-like geometry to one C(24) and one N(3) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(22) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(23) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(24) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(25) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Sn(1) and one C(26) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(26) atom. Linkers: 4 [O]C(=O)C(n1cccn1)n1cccn1. Metal clusters: 4 O=[C]O[Sn]. The MOF has largest included sphere 5.35 A, density 1.17 g/cm3, surface area 4897.49 m2/g, accessible volume 0.38 cm3/g