ZnC11H11(NO)4CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two ZnC11H11(NO)4 clusters. In one of the ZnC11H11(NO)4 clusters, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(6), one N(8), one O(1), one O(5), and one O(6) atom. The Zn(1)-N(6) bond length is 2.16 Å. The Zn(1)-N(8) bond length is 2.05 Å. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(5) bond length is 2.22 Å. The Zn(1)-O(6) bond length is 2.02 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(14) is bonded in a distorted single-bond geometry to one C(15), one C(19), and one H(16) atom. The C(14)-C(15) bond length is 1.50 Å. The C(14)-C(19) bond length is 1.50 Å. The C(14)-H(16) bond length is 1.10 Å. In the third C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(5), and one N(6) atom. The C(15)-N(5) bond length is 1.36 Å. The C(15)-N(6) bond length is 1.34 Å. In the fourth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(5), and one H(17) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-N(5) bond length is 1.38 Å. The C(16)-H(17) bond length is 1.08 Å. In the fifth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(6), and one H(18) atom. The C(17)-N(6) bond length is 1.38 Å. The C(17)-H(18) bond length is 1.08 Å. In the sixth C site, C(18) is bonded in a tetrahedral geometry to one N(5), one H(19), one H(20), and one H(21) atom. The C(18)-N(5) bond length is 1.46 Å. The C(18)-H(19) bond length is 1.10 Å. The C(18)-H(20) bond length is 1.09 Å. The C(18)-H(21) bond length is 1.10 Å. In the seventh C site, C(19) is bonded in a distorted trigonal planar geometry to one C(14), one N(7), and one N(8) atom. The C(19)-N(7) bond length is 1.36 Å. The C(19)-N(8) bond length is 1.34 Å. In the eighth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(7), and one H(22) atom. The C(20)-C(21) bond length is 1.37 Å. The C(20)-N(7) bond length is 1.38 Å. The C(20)-H(22) bond length is 1.08 Å. In the ninth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(8), and one H(23) atom. The C(21)-N(8) bond length is 1.38 Å. The C(21)-H(23) bond length is 1.08 Å. In the tenth C site, C(22) is bonded in a tetrahedral geometry to one N(7), one H(24), one H(25), and one H(26) atom. The C(22)-N(7) bond length is 1.46 Å. The C(22)-H(24) bond length is 1.10 Å. The C(22)-H(25) bond length is 1.09 Å. The C(22)-H(26) bond length is 1.09 Å. In the eleventh C site, C(23) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(23)-O(5) bond length is 1.26 Å. The C(23)-O(6) bond length is 1.28 Å. There are four inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(18) atom. In the second N site, N(6) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(15), and one C(17) atom. In the third N site, N(7) is bonded in a trigonal planar geometry to one C(19), one C(20), and one C(22) atom. In the fourth N site, N(8) is bonded in a trigonal planar geometry to one Zn(1), one C(19), and one C(21) atom. There are eleven inequivalent H sites. In the first H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the second H site, H(17) is bonded in a single-bond geometry to one C(16) atom. In the third H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(21) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(24) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(25) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(26) is bonded in a single-bond geometry to one C(22) atom. There are four inequivalent O sites. In the first O site, O(5) is bonded in a distorted water-like geometry to one Zn(1) and one C(23) atom. In the second O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(23) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In one of the ZnC11H11(NO)4 clusters, Zn(2) is bonded in a trigonal bipyramidal geometry to one N(2), one N(4), one O(3), one O(7), and one O(8) atom. The Zn(2)-N(2) bond length is 2.13 Å. The Zn(2)-N(4) bond length is 2.06 Å. The Zn(2)-O(3) bond length is 1.96 Å. The Zn(2)-O(7) bond length is 2.23 Å. The Zn(2)-O(8) bond length is 2.02 Å. There are eleven inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one H(3) atom. The C(3)-C(4) bond length is 1.50 Å. The C(3)-C(8) bond length is 1.51 Å. The C(3)-H(3) bond length is 1.10 Å. In the second C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one N(2) atom. The C(4)-N(1) bond length is 1.36 Å. The C(4)-N(2) bond length is 1.34 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one H(4) atom. The C(5)-C(6) bond length is 1.38 Å. The C(5)-N(1) bond length is 1.38 Å. The C(5)-H(4) bond length is 1.08 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(2), and one H(5) atom. The C(6)-N(2) bond length is 1.38 Å. The C(6)-H(5) bond length is 1.08 Å. In the fifth C site, C(7) is bonded in a tetrahedral geometry to one N(1), one H(6), one H(7), and one H(8) atom. The C(7)-N(1) bond length is 1.46 Å. The C(7)-H(6) bond length is 1.10 Å. The C(7)-H(7) bond length is 1.09 Å. The C(7)-H(8) bond length is 1.10 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(3), one N(3), and one N(4) atom. The C(8)-N(3) bond length is 1.36 Å. The C(8)-N(4) bond length is 1.34 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(3), and one H(9) atom. The C(9)-C(10) bond length is 1.37 Å. The C(9)-N(3) bond length is 1.38 Å. The C(9)-H(9) bond length is 1.08 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(4), and one H(10) atom. The C(10)-N(4) bond length is 1.38 Å. The C(10)-H(10) bond length is 1.08 Å. In the ninth C site, C(11) is bonded in a tetrahedral geometry to one N(3), one H(11), one H(12), and one H(13) atom. The C(11)-N(3) bond length is 1.46 Å. The C(11)-H(11) bond length is 1.09 Å. The C(11)-H(12) bond length is 1.09 Å. The C(11)-H(13) bond length is 1.10 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(12)-O(3) bond length is 1.30 Å. The C(12)-O(4) bond length is 1.25 Å. In the eleventh C site, C(24) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(24)-O(7) bond length is 1.26 Å. The C(24)-O(8) bond length is 1.28 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(7) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(4), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(11), one C(8), and one C(9) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(2), one C(10), and one C(8) atom. There are eleven inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(11) atom. There are four inequivalent O sites. In the first O site, O(7) is bonded in a distorted water-like geometry to one Zn(2) and one C(24) atom. In the second O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(24) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(12) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(12) atom. Linkers: 2 [O]C(=O)C([O])=O ,4 Cn1ccnc1C(CC([O])=O)c1nccn1C. Metal clusters: 2 O=[C]O[Zn]1OC2=C(O1)O[Zn](O[C]=O)O2. The MOF has largest included sphere 3.57 A, density 1.50 g/cm3, surface area 4332.91 m2/g, accessible volume 0.23 cm3/g