Cd3C28H14(NO3)4(CH)8(CH2)12 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, twelve 02329_fluka molecules, and one Cd3C28H14(NO3)4 cluster. In the Cd3C28H14(NO3)4 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form edge-sharing CdO6 octahedra. Both Cd(1)-O(2) bond lengths are 2.34 Å. Both Cd(1)-O(4) bond lengths are 2.34 Å. Both Cd(1)-O(6) bond lengths are 2.27 Å. In the second Cd site, Cd(2) is bonded to one N(1), one N(2), one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form distorted edge-sharing CdN2O5 pentagonal bipyramids. The Cd(2)-N(1) bond length is 2.42 Å. The Cd(2)-N(2) bond length is 2.35 Å. The Cd(2)-O(1) bond length is 2.41 Å. The Cd(2)-O(2) bond length is 2.46 Å. The Cd(2)-O(3) bond length is 2.32 Å. The Cd(2)-O(4) bond length is 2.60 Å. The Cd(2)-O(5) bond length is 2.31 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3,4) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3,4) bond length is 1.09 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(12) bond length is 1.42 Å. The C(4)-C(5) bond length is 1.43 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3,4) atom. The C(5)-H(3,4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-C(7) bond length is 1.43 Å. The C(6)-H(5) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.42 Å. The C(7)-C(8) bond length is 1.41 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(6) atom. The C(8)-C(9) bond length is 1.38 Å. The C(8)-H(6) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(7) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(7) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.33 Å. The C(10)-H(8) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(7), and one N(2) atom. The C(11)-C(12) bond length is 1.45 Å. The C(11)-N(2) bond length is 1.35 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(4), and one N(1) atom. The C(12)-N(1) bond length is 1.35 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(13)-O(1) bond length is 1.27 Å. The C(13)-O(2) bond length is 1.28 Å. In the thirteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(20)-O(3) bond length is 1.27 Å. The C(20)-O(4) bond length is 1.29 Å. In the fourteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(21)-O(5) bond length is 1.27 Å. The C(21)-O(6) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(1), and one C(12) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(2), one C(10), and one C(11) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(13) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Cd(1), one Cd(2), and one C(13) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(2) and one C(20) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one Cd(1), one Cd(2), and one C(20) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cd(2) and one C(21) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Cd(1) and one C(21) atom. Linkers: 2 [O]C(=O)[C@H]1CC[C@@H](C([O])=O)CC1 ,1 [O]C(=O)[C@H]1CC[C@H](C([O])=O)CC1. Metal clusters: 1 [C]1O[Cd]2O[C]O[Cd]34(O1)(O[C]O2)O[C]O[Cd](O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 3.09 A, density 1.72 g/cm3, surface area 3992.35 m2/g, accessible volume 0.17 cm3/g