Cu2C7N2H4O7(CH)8CH2(C4NH4O)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules; four isobutylene molecules; two n,n',n''-trimethylbenzene-1,3,5-tricarboxamide molecules; and one Cu2C7N2H4O7 cluster. In the Cu2C7N2H4O7 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one N(5), one O(10), one O(3), one O(6), and one O(9) atom to form distorted corner-sharing CuNO4 trigonal bipyramids. The Cu(1)-N(5) bond length is 2.01 Å. The Cu(1)-O(10) bond length is 1.88 Å. The Cu(1)-O(3) bond length is 2.46 Å. The Cu(1)-O(6) bond length is 1.95 Å. The Cu(1)-O(9) bond length is 1.92 Å. In the second Cu site, Cu(2) is bonded to one N(4), one O(2), one O(5), and two equivalent O(10) atoms to form a mixture of distorted edge and corner-sharing CuNO4 square pyramids. The Cu(2)-N(4) bond length is 1.95 Å. The Cu(2)-O(2) bond length is 1.91 Å. The Cu(2)-O(5) bond length is 2.53 Å. There is one shorter (1.87 Å) and one longer (1.88 Å) Cu(2)-O(10) bond length. There are seven inequivalent C sites. In the first C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(9)-O(2) bond length is 1.29 Å. The C(9)-O(3) bond length is 1.24 Å. In the second C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(12)-O(5) bond length is 1.24 Å. The C(12)-O(6) bond length is 1.30 Å. In the third C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(8) and one O(9) atom. The C(15)-O(8) bond length is 1.24 Å. The C(15)-O(9) bond length is 1.29 Å. In the fourth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(10) atom. The C(16)-N(4) bond length is 1.35 Å. The C(16)-H(10) bond length is 1.09 Å. In the fifth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(13) atom. The C(20)-N(4) bond length is 1.35 Å. The C(20)-H(13) bond length is 1.09 Å. In the sixth C site, C(26) is bonded in a distorted trigonal planar geometry to one N(5) and one H(21) atom. The C(26)-N(5) bond length is 1.35 Å. The C(26)-H(21) bond length is 1.09 Å. In the seventh C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(22) atom. The C(27)-N(5) bond length is 1.35 Å. The C(27)-H(22) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(16), and one C(20) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Cu(1), one C(26), and one C(27) atom. There are four inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the second H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the third H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the fourth H site, H(22) is bonded in a single-bond geometry to one C(27) atom. There are seven inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one Cu(2) and one C(12) atom. In the second O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(12) atom. In the third O site, O(8) is bonded in a single-bond geometry to one C(15) atom. In the fourth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(15) atom. In the fifth O site, O(10) is bonded in a trigonal non-coplanar geometry to one Cu(1) and two equivalent Cu(2) atoms. In the sixth O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(9) atom. In the seventh O site, O(3) is bonded in a distorted single-bond geometry to one Cu(1) and one C(9) atom. Linkers: 2 [O]C(=O)CNC(=O)c1cc(C(=O)NCC([O])=O)cc(C(=O)NCC([O])=O)c1 ,2 c1cc(CCCc2ccncc2)ccn1. Metal clusters: 1 O=[C]O[Cu]O[Cu](O[C]=O)O[C]=O.O=[C]O[Cu]O[Cu](O[C]=O)O[C]=O. The MOF has largest included sphere 5.03 A, density 1.25 g/cm3, surface area 4314.79 m2/g, accessible volume 0.34 cm3/g