AgC12H10(NO)2CHCH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two 02329_fluka molecules, and two AgC12H10(NO)2 clusters. In each AgC12H10(NO)2 cluster, Ag(1) is bonded in a linear geometry to one N(1) and one O(2) atom. The Ag(1)-N(1) bond length is 2.10 Å. The Ag(1)-O(2) bond length is 2.11 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one H(1), one H(2), and one H(3) atom. The C(1)-C(2) bond length is 1.47 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one N(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(2) bond length is 1.37 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one N(2) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(8) bond length is 1.41 Å. The C(3)-N(2) bond length is 1.39 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(5) atom. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(7) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one N(1) atom. The C(8)-N(1) bond length is 1.39 Å. In the eighth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(8), and one H(9) atom. The C(9)-N(2) bond length is 1.46 Å. The C(9)-H(8) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-O(1) bond length is 1.26 Å. The C(11)-O(2) bond length is 1.30 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(14) bond length is 1.40 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(12) atom. The C(13)-H(12) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(13) atom. The C(14)-H(13) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(2), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(9) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(11) atom. In the second O site, O(2) is bonded in a water-like geometry to one Ag(1) and one C(11) atom. Linkers: 1 Cc1nc2ccccc2n1CCCCn1c(C)nc2ccccc21 ,1 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 O=[C]O[Ag]. The MOF has largest included sphere 2.20 A, density 1.85 g/cm3, surface area 4047.85 m2/g, accessible volume 0.13 cm3/g