NdC24N6H20O10Cl(CH)8 is Indium-derived structured and crystallizes in the tetragonal P4_32_12 space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules and four NdC24N6H20O10Cl clusters. In each NdC24N6H20O10Cl cluster, Nd(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(5), and one Cl(1) atom. Both Nd(1)-O(1) bond lengths are 2.61 Å. Both Nd(1)-O(2) bond lengths are 2.40 Å. Both Nd(1)-O(3) bond lengths are 2.58 Å. Both Nd(1)-O(5) bond lengths are 2.41 Å. The Nd(1)-Cl(1) bond length is 2.86 Å. There are twelve inequivalent C sites. In the first C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(4), and one H(5) atom. The C(3)-N(2) bond length is 1.44 Å. The C(3)-H(4) bond length is 1.10 Å. The C(3)-H(5) bond length is 1.11 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(2), and one H(6) atom. The C(4)-C(5) bond length is 1.45 Å. The C(4)-N(2) bond length is 1.28 Å. The C(4)-H(6) bond length is 1.11 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(6) atom. The C(5)-C(10) bond length is 1.40 Å. The C(5)-C(6) bond length is 1.45 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one O(5) atom. The C(6)-O(5) bond length is 1.28 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(5) and one H(10) atom. The C(10)-H(10) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a single-bond geometry to one C(13) and one O(2) atom. The C(12)-C(13) bond length is 1.45 Å. The C(12)-O(2) bond length is 1.28 Å. In the seventh C site, C(13) is bonded in a trigonal planar geometry to one C(1), one C(12), and one C(14) atom. The C(13)-C(1) bond length is 1.45 Å. The C(13)-C(14) bond length is 1.40 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(12) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(12) bond length is 1.09 Å. In the ninth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(13) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(13) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(14) atom. The C(16)-H(14) bond length is 1.09 Å. In the eleventh C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(2), and one H(3) atom. The C(2)-N(3) bond length is 1.43 Å. The C(2)-H(2) bond length is 1.11 Å. The C(2)-H(3) bond length is 1.10 Å. In the twelfth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(3), and one H(1) atom. The C(1)-N(3) bond length is 1.28 Å. The C(1)-H(1) bond length is 1.11 Å. There are three inequivalent N sites. In the first N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(4) atom. The N(1)-O(1) bond length is 1.28 Å. The N(1)-O(3) bond length is 1.29 Å. The N(1)-O(4) bond length is 1.24 Å. In the third N site, N(2) is bonded in a bent 120 degrees geometry to one C(3) and one C(4) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Nd(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one C(12) atom. In the third O site, O(3) is bonded in a water-like geometry to one Nd(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Nd(1) and one C(6) atom. Cl(1) is bonded in a single-bond geometry to one Nd(1) atom. Linkers: 8 [O]c1ccccc1/C=N/CC/N=C/[C]1C=CC=CC1=O. Metal clusters: 4 [Cl].[O][Nd]([O])([O])([O])(O[N+](=O)[O-])O[N+](=O)[O-]. RCSR code: dia. The MOF has largest included sphere 5.91 A, density 1.17 g/cm3, surface area 4433.13 m2/g, accessible volume 0.43 cm3/g