Zn3H16(C3O10)2(CH)6 crystallizes in the monoclinic P2_1/c space group. The structure consists of twenty-four 02329_fluka molecules inside a Zn3H16(C3O10)2 framework. In the Zn3H16(C3O10)2 framework, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(13), one O(14), one O(5), and two equivalent O(15) atoms to form edge-sharing ZnO6 octahedra. The Zn(1)-O(1) bond length is 2.13 Å. The Zn(1)-O(13) bond length is 2.09 Å. The Zn(1)-O(14) bond length is 2.13 Å. The Zn(1)-O(5) bond length is 2.14 Å. There is one shorter (2.10 Å) and one longer (2.20 Å) Zn(1)-O(15) bond length. In the second Zn site, Zn(2) is bonded in an octahedral geometry to one O(12), one O(16), one O(17), one O(18), one O(2), and one O(3) atom. The Zn(2)-O(12) bond length is 2.14 Å. The Zn(2)-O(16) bond length is 2.25 Å. The Zn(2)-O(17) bond length is 2.22 Å. The Zn(2)-O(18) bond length is 2.11 Å. The Zn(2)-O(2) bond length is 2.03 Å. The Zn(2)-O(3) bond length is 2.00 Å. In the third Zn site, Zn(3) is bonded in an octahedral geometry to one O(10), one O(11), one O(19), one O(20), one O(6), and one O(7) atom. The Zn(3)-O(10) bond length is 2.04 Å. The Zn(3)-O(11) bond length is 2.04 Å. The Zn(3)-O(19) bond length is 2.12 Å. The Zn(3)-O(20) bond length is 2.29 Å. The Zn(3)-O(6) bond length is 2.06 Å. The Zn(3)-O(7) bond length is 2.09 Å. There are six inequivalent C sites. In the first C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.27 Å. In the second C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(9)-O(5) bond length is 1.26 Å. The C(9)-O(6) bond length is 1.29 Å. In the third C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(10)-O(7) bond length is 1.29 Å. The C(10)-O(8) bond length is 1.26 Å. In the fourth C site, C(11) is bonded in a bent 120 degrees geometry to one O(10) and one O(9) atom. The C(11)-O(10) bond length is 1.29 Å. The C(11)-O(9) bond length is 1.26 Å. In the fifth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. The C(12)-O(11) bond length is 1.29 Å. The C(12)-O(12) bond length is 1.26 Å. In the sixth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.29 Å. There are sixteen inequivalent H sites. In the first H site, H(7) is bonded in a distorted bent 150 degrees geometry to one O(13) and one O(8) atom. The H(7)-O(13) bond length is 1.01 Å. The H(7)-O(8) bond length is 1.60 Å. In the second H site, H(8) is bonded in a linear geometry to one O(14) and one O(6) atom. The H(8)-O(14) bond length is 1.02 Å. The H(8)-O(6) bond length is 1.58 Å. In the third H site, H(9) is bonded in a linear geometry to one O(16) and one O(4) atom. The H(9)-O(16) bond length is 1.02 Å. The H(9)-O(4) bond length is 1.58 Å. In the fourth H site, H(10) is bonded in a single-bond geometry to one O(17) atom. The H(10)-O(17) bond length is 1.00 Å. In the fifth H site, H(11) is bonded in a distorted single-bond geometry to one O(11) and one O(18) atom. The H(11)-O(11) bond length is 1.65 Å. The H(11)-O(18) bond length is 1.01 Å. In the sixth H site, H(12) is bonded in a distorted single-bond geometry to one O(19) and one O(7) atom. The H(12)-O(19) bond length is 1.01 Å. The H(12)-O(7) bond length is 1.66 Å. In the seventh H site, H(13) is bonded in a single-bond geometry to one O(20) atom. The H(13)-O(20) bond length is 0.98 Å. In the eighth H site, H(14) is bonded in a single-bond geometry to one O(10) and one O(13) atom. The H(14)-O(10) bond length is 1.68 Å. The H(14)-O(13) bond length is 1.00 Å. In the ninth H site, H(15) is bonded in a distorted bent 150 degrees geometry to one O(15) and one O(2) atom. The H(15)-O(15) bond length is 1.01 Å. The H(15)-O(2) bond length is 1.56 Å. In the tenth H site, H(16) is bonded in a single-bond geometry to one O(16) atom. The H(16)-O(16) bond length is 0.97 Å. In the eleventh H site, H(17) is bonded in a single-bond geometry to one O(14) atom. The H(17)-O(14) bond length is 0.99 Å. In the twelfth H site, H(18) is bonded in a single-bond geometry to one O(18) atom. The H(18)-O(18) bond length is 0.98 Å. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one O(19) atom. The H(19)-O(19) bond length is 0.97 Å. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one O(20) atom. The H(20)-O(20) bond length is 0.98 Å. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one O(17) atom. The H(21)-O(17) bond length is 0.98 Å. In the sixteenth H site, H(22) is bonded in a distorted linear geometry to one O(15) and one O(9) atom. The H(22)-O(15) bond length is 1.02 Å. The H(22)-O(9) bond length is 1.53 Å. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one C(1), and one H(15) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(8) and one H(9) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Zn(3), one C(9), and one H(8) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Zn(3), one C(10), and one H(12) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one C(10) and one H(7) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one C(11) and one H(22) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one Zn(3), one C(11), and one H(14) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Zn(3), one C(12), and one H(11) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(12) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one Zn(1), one H(14), and one H(7) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Zn(1), one H(17), and one H(8) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to two equivalent Zn(1), one H(15), and one H(22) atom. In the sixteenth O site, O(16) is bonded in a distorted water-like geometry to one Zn(2), one H(16), and one H(9) atom. In the seventeenth O site, O(17) is bonded in a distorted water-like geometry to one Zn(2), one H(10), and one H(21) atom. In the eighteenth O site, O(18) is bonded in a distorted water-like geometry to one Zn(2), one H(11), and one H(18) atom. In the nineteenth O site, O(19) is bonded in a distorted water-like geometry to one Zn(3), one H(12), and one H(19) atom. In the twentieth O site, O(20) is bonded in a distorted water-like geometry to one Zn(3), one H(13), and one H(20) atom. Linkers: 4 [O]C(=O)[C@H]1[C@@H](C([O])=O)[C@@H](C([O])=O)[C@@H](C([O])=O)[C@@H](C([O])=O)[C@H]1C([O])=O. Metal clusters: 12 [Zn]. The MOF has largest included sphere 3.41 A, density 1.88 g/cm3, surface area 3090.56 m2/g, accessible volume 0.15 cm3/g