Mo2Cu2C10N3H9O8 crystallizes in the triclinic P1 space group. There are six inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(13), one O(5), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one Cu(1)NO5 octahedra,  a cornercorner with one Cu(3)NO5 octahedra,  a cornercorner with one Cu(5)NO5 octahedra, and corners with two equivalent Cu(7)NO5 octahedra. The corner-sharing octahedral tilt angles range from 23-65°. The Mo(1)-O(1) bond length is 1.81 Å. The Mo(1)-O(13) bond length is 1.81 Å. The Mo(1)-O(5) bond length is 1.77 Å. The Mo(1)-O(9) bond length is 1.75 Å. In the second Mo site, Mo(2,4) is bonded to one O(10), one O(14), one O(2), and one O(6) atom to form MoO4 tetrahedra that share corners with two equivalent Cu(2,4)NO5 octahedra. The corner-sharing octahedral tilt angles range from 55-65°. The Mo(2,4)-O(10) bond length is 1.75 Å. The Mo(2,4)-O(14) bond length is 1.81 Å. The Mo(2,4)-O(2) bond length is 1.80 Å. The Mo(2,4)-O(6) bond length is 1.77 Å. In the third Mo site, Mo(3) is bonded to one O(11), one O(15), one O(3), and one O(7) atom to form MoO4 tetrahedra that share  a cornercorner with one Cu(1)NO5 octahedra,  a cornercorner with one Cu(3)NO5 octahedra,  a cornercorner with one Cu(7)NO5 octahedra, and corners with two equivalent Cu(5)NO5 octahedra. The corner-sharing octahedral tilt angles range from 22-65°. The Mo(3)-O(11) bond length is 1.75 Å. The Mo(3)-O(15) bond length is 1.81 Å. The Mo(3)-O(3) bond length is 1.81 Å. The Mo(3)-O(7) bond length is 1.77 Å. In the fourth Mo site, Mo(5) is bonded to one O(17), one O(21), one O(25), and one O(29) atom to form MoO4 tetrahedra that share  a cornercorner with one Cu(3)NO5 octahedra,  a cornercorner with one Cu(5)NO5 octahedra,  a cornercorner with one Cu(7)NO5 octahedra, and corners with two equivalent Cu(1)NO5 octahedra. The corner-sharing octahedral tilt angles range from 48-59°. The Mo(5)-O(17) bond length is 1.82 Å. The Mo(5)-O(21) bond length is 1.78 Å. The Mo(5)-O(25) bond length is 1.81 Å. The Mo(5)-O(29) bond length is 1.74 Å. In the fifth Mo site, Mo(6,8) is bonded to one O(18); one O(22); one O(26); and one O(30,32) atom to form MoO4 tetrahedra that share corners with three equivalent Cu(2,4)NO5 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. The Mo(6,8)-O(18) bond length is 1.82 Å. The Mo(6,8)-O(22) bond length is 1.78 Å. The Mo(6,8)-O(26) bond length is 1.82 Å. The Mo(6,8)-O(30,32) bond length is 1.74 Å. In the sixth Mo site, Mo(7) is bonded to one O(19), one O(23), one O(27), and one O(31) atom to form MoO4 tetrahedra that share  a cornercorner with one Cu(1)NO5 octahedra,  a cornercorner with one Cu(5)NO5 octahedra,  a cornercorner with one Cu(7)NO5 octahedra, and corners with two equivalent Cu(3)NO5 octahedra. The corner-sharing octahedral tilt angles range from 47-59°. The Mo(7)-O(19) bond length is 1.81 Å. The Mo(7)-O(23) bond length is 1.78 Å. The Mo(7)-O(27) bond length is 1.81 Å. The Mo(7)-O(31) bond length is 1.74 Å. There are six inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one N(1), one O(1), one O(15), one O(17), one O(19), and one O(25) atom to form CuNO5 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(7)O4 tetrahedra, corners with two equivalent Mo(5)O4 tetrahedra,  an edgeedge with one Cu(3)NO5 octahedra, and  an edgeedge with one Cu(7)NO5 octahedra. The Cu(1)-N(1) bond length is 1.99 Å. The Cu(1)-O(1) bond length is 1.95 Å. The Cu(1)-O(15) bond length is 1.95 Å. The Cu(1)-O(17) bond length is 2.42 Å. The Cu(1)-O(19) bond length is 2.01 Å. The Cu(1)-O(25) bond length is 2.40 Å. In the second Cu site, Cu(2,4) is bonded to one N(2), one O(16), one O(18), one O(2), one O(20), and one O(26) atom to form CuNO5 octahedra that share corners with two equivalent Mo(2,4)O4 tetrahedra; corners with three equivalent Mo(6,8)O4 tetrahedra; and  an edgeedge with one Cu(2,4)NO5 octahedra. The Cu(2,4)-N(2) bond length is 1.99 Å. The Cu(2,4)-O(16) bond length is 1.95 Å. The Cu(2,4)-O(18) bond length is 2.42 Å. The Cu(2,4)-O(2) bond length is 1.95 Å. The Cu(2,4)-O(20) bond length is 2.00 Å. The Cu(2,4)-O(26) bond length is 2.40 Å. In the third Cu site, Cu(3) is bonded to one N(3), one O(13), one O(17), one O(19), one O(27), and one O(3) atom to form CuNO5 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra, corners with two equivalent Mo(7)O4 tetrahedra,  an edgeedge with one Cu(1)NO5 octahedra, and  an edgeedge with one Cu(5)NO5 octahedra. The Cu(3)-N(3) bond length is 1.99 Å. The Cu(3)-O(13) bond length is 1.95 Å. The Cu(3)-O(17) bond length is 2.00 Å. The Cu(3)-O(19) bond length is 2.43 Å. The Cu(3)-O(27) bond length is 2.41 Å. The Cu(3)-O(3) bond length is 1.95 Å. In the fourth Cu site, Cu(5) is bonded to one N(12), one O(11), one O(21), one O(27), one O(3), and one O(5) atom to form distorted CuNO5 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra,  a cornercorner with one Mo(7)O4 tetrahedra, corners with two equivalent Mo(3)O4 tetrahedra, and  an edgeedge with one Cu(3)NO5 octahedra. The Cu(5)-N(12) bond length is 1.99 Å. The Cu(5)-O(11) bond length is 2.36 Å. The Cu(5)-O(21) bond length is 1.98 Å. The Cu(5)-O(27) bond length is 1.97 Å. The Cu(5)-O(3) bond length is 2.58 Å. The Cu(5)-O(5) bond length is 1.92 Å. In the fifth Cu site, Cu(6,8) is bonded in a 6-coordinate geometry to one N(11), one O(12), one O(22), one O(28), one O(4), and one O(6) atom. The Cu(6,8)-N(11) bond length is 2.00 Å. The Cu(6,8)-O(12) bond length is 2.35 Å. The Cu(6,8)-O(22) bond length is 1.98 Å. The Cu(6,8)-O(28) bond length is 1.97 Å. The Cu(6,8)-O(4) bond length is 2.59 Å. The Cu(6,8)-O(6) bond length is 1.91 Å. In the sixth Cu site, Cu(7) is bonded to one N(10), one O(1), one O(23), one O(25), one O(7), and one O(9) atom to form distorted CuNO5 octahedra that share  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra,  a cornercorner with one Mo(7)O4 tetrahedra, corners with two equivalent Mo(1)O4 tetrahedra, and  an edgeedge with one Cu(1)NO5 octahedra. The Cu(7)-N(10) bond length is 1.99 Å. The Cu(7)-O(1) bond length is 2.58 Å. The Cu(7)-O(23) bond length is 1.98 Å. The Cu(7)-O(25) bond length is 1.97 Å. The Cu(7)-O(7) bond length is 1.92 Å. The Cu(7)-O(9) bond length is 2.36 Å. There are thirty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2,4) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2,3,4) atom. The C(2,4)-N(2) bond length is 1.34 Å. The C(2,4)-H(2,3,4) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(2,3,4) atom. The C(3)-N(3) bond length is 1.34 Å. The C(3)-H(2,3,4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(5)-C(9) bond length is 1.41 Å. The C(5)-H(5) bond length is 1.08 Å. In the fifth C site, C(6,8) is bonded in a distorted single-bond geometry to one C(10,11) and one H(6,7,8) atom. The C(6,8)-C(10,11) bond length is 1.41 Å. The C(6,8)-H(6,7,8) bond length is 1.08 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(10,11) and one H(6,7,8) atom. The C(7)-C(10,11) bond length is 1.41 Å. The C(7)-H(6,7,8) bond length is 1.08 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(13), one C(5), and one N(5) atom. The C(9)-C(13) bond length is 1.41 Å. The C(9)-N(5) bond length is 1.38 Å. In the eighth C site, C(10,11) is bonded in a distorted trigonal planar geometry to one C(14,16); one C(6,8); and one N(6) atom. The C(10,11)-C(14,16) bond length is 1.41 Å. The C(10,11)-N(6) bond length is 1.38 Å. In the ninth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14,16); one C(6,8); and one N(8) atom. The C(12)-C(14,16) bond length is 1.41 Å. The C(12)-C(6,8) bond length is 1.41 Å. The C(12)-N(8) bond length is 1.38 Å. In the tenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(17), one C(9), and one H(9) atom. The C(13)-C(17) bond length is 1.38 Å. The C(13)-H(9) bond length is 1.09 Å. In the eleventh C site, C(14,16) is bonded in a distorted trigonal planar geometry to one C(10,11); one C(18,20); and one H(10,11,12) atom. The C(14,16)-C(18,20) bond length is 1.38 Å. The C(14,16)-H(10,11,12) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(10,11); one C(19); and one H(10,11,12) atom. The C(15)-C(10,11) bond length is 1.41 Å. The C(15)-C(19) bond length is 1.38 Å. The C(15)-H(10,11,12) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(1), and one H(13) atom. The C(17)-N(1) bond length is 1.35 Å. The C(17)-H(13) bond length is 1.09 Å. In the fourteenth C site, C(18,20) is bonded in a distorted bent 120 degrees geometry to one C(14,16); one N(2); and one H(14,15,16) atom. The C(18,20)-N(2) bond length is 1.35 Å. The C(18,20)-H(14,15,16) bond length is 1.09 Å. In the fifteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(15); one N(3); and one H(14,15,16) atom. The C(19)-N(3) bond length is 1.35 Å. The C(19)-H(14,15,16) bond length is 1.09 Å. In the sixteenth C site, C(21,23) is bonded in a distorted bent 120 degrees geometry to one C(25); one N(9); and one H(17,18,19) atom. The C(21,23)-C(25) bond length is 1.39 Å. The C(21,23)-N(9) bond length is 1.34 Å. The C(21,23)-H(17,18,19) bond length is 1.09 Å. In the seventeenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(26); one N(10); and one H(17,18,19) atom. The C(22)-C(26) bond length is 1.39 Å. The C(22)-N(10) bond length is 1.34 Å. The C(22)-H(17,18,19) bond length is 1.09 Å. In the eighteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(28), one N(12), and one H(20) atom. The C(24)-C(28) bond length is 1.39 Å. The C(24)-N(12) bond length is 1.34 Å. The C(24)-H(20) bond length is 1.09 Å. In the nineteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(21,23); one C(29); and one H(21,22,23) atom. The C(25)-C(29) bond length is 1.41 Å. The C(25)-H(21,22,23) bond length is 1.09 Å. In the twentieth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(22); one C(30,31); and one H(21,22,23) atom. The C(26)-C(30,31) bond length is 1.41 Å. The C(26)-H(21,22,23) bond length is 1.09 Å. In the twenty-first C site, C(27) is bonded in a distorted trigonal planar geometry to one C(21,23); one C(30,31); and one H(21,22,23) atom. The C(27)-C(21,23) bond length is 1.39 Å. The C(27)-C(30,31) bond length is 1.41 Å. The C(27)-H(21,22,23) bond length is 1.09 Å. In the twenty-second C site, C(28) is bonded in a distorted trigonal planar geometry to one C(24), one C(32), and one H(24) atom. The C(28)-C(32) bond length is 1.41 Å. The C(28)-H(24) bond length is 1.08 Å. In the twenty-third C site, C(29) is bonded in a distorted trigonal planar geometry to one C(25), one C(33), and one N(5) atom. The C(29)-C(33) bond length is 1.41 Å. The C(29)-N(5) bond length is 1.39 Å. In the twenty-fourth C site, C(30,31) is bonded in a distorted trigonal planar geometry to one C(26), one C(34), and one N(6) atom. The C(30,31)-C(34) bond length is 1.41 Å. The C(30,31)-N(6) bond length is 1.39 Å. In the twenty-fifth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(28), one C(36), and one N(8) atom. The C(32)-C(36) bond length is 1.41 Å. The C(32)-N(8) bond length is 1.39 Å. In the twenty-sixth C site, C(33) is bonded in a distorted trigonal planar geometry to one C(29); one C(37,39); and one H(29,30,31) atom. The C(33)-C(37,39) bond length is 1.38 Å. The C(33)-H(29,30,31) bond length is 1.09 Å. In the twenty-seventh C site, C(34) is bonded in a distorted trigonal planar geometry to one C(30,31); one C(38); and one H(29,30,31) atom. The C(34)-C(38) bond length is 1.38 Å. The C(34)-H(29,30,31) bond length is 1.09 Å. In the twenty-eighth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(30,31); one C(37,39); and one H(29,30,31) atom. The C(35)-C(30,31) bond length is 1.41 Å. The C(35)-C(37,39) bond length is 1.38 Å. The C(35)-H(29,30,31) bond length is 1.09 Å. In the twenty-ninth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(32), one C(40), and one H(32) atom. The C(36)-C(40) bond length is 1.38 Å. The C(36)-H(32) bond length is 1.09 Å. In the thirtieth C site, C(37,39) is bonded in a distorted bent 120 degrees geometry to one C(33); one N(9); and one H(33,35) atom. The C(37,39)-N(9) bond length is 1.35 Å. The C(37,39)-H(33,35) bond length is 1.09 Å. In the thirty-first C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(34), one N(10), and one H(34) atom. The C(38)-N(10) bond length is 1.35 Å. The C(38)-H(34) bond length is 1.09 Å. In the thirty-second C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(36), one N(12), and one H(36) atom. The C(40)-N(12) bond length is 1.35 Å. The C(40)-H(36) bond length is 1.09 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(17) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2,4); one C(18,20); and one C(2,4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(3), one C(19), and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(2,4); one C(18,20); and one C(2,4) atom. The N(4)-Cu(2,4) bond length is 1.99 Å. The N(4)-C(18,20) bond length is 1.35 Å. The N(4)-C(2,4) bond length is 1.34 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(29), one C(9), and one H(25) atom. The N(5)-H(25) bond length is 1.02 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one C(10,11); one C(30,31); and one H(26,27) atom. The N(6)-H(26,27) bond length is 1.02 Å. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one C(10,11); one C(30,31); and one H(26,27) atom. The N(7)-C(10,11) bond length is 1.38 Å. The N(7)-C(30,31) bond length is 1.39 Å. The N(7)-H(26,27) bond length is 1.02 Å. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one C(12), one C(32), and one H(28) atom. The N(8)-H(28) bond length is 1.02 Å. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Cu(6,8); one C(21,23); and one C(37,39) atom. The N(9)-Cu(6,8) bond length is 2.00 Å. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Cu(7), one C(22), and one C(38) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Cu(6,8); one C(21,23); and one C(37,39) atom. The N(11)-C(21,23) bond length is 1.34 Å. The N(11)-C(37,39) bond length is 1.35 Å. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Cu(5), one C(24), and one C(40) atom. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2,3,4) is bonded in a single-bond geometry to one C(2,4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(6,7,8) is bonded in a single-bond geometry to one C(6,8) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(10,11,12) is bonded in a single-bond geometry to one C(14,16) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(14,15,16) is bonded in a single-bond geometry to one C(18,20) atom. In the ninth H site, H(17,18,19) is bonded in a single-bond geometry to one C(21,23) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(21,22,23) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(28) atom. In the thirteenth H site, H(25) is bonded in a single-bond geometry to one N(5) atom. In the fourteenth H site, H(26,27) is bonded in a single-bond geometry to one N(6) atom. In the fifteenth H site, H(28) is bonded in a single-bond geometry to one N(8) atom. In the sixteenth H site, H(29,30,31) is bonded in a single-bond geometry to one C(33) atom. In the seventeenth H site, H(32) is bonded in a single-bond geometry to one C(36) atom. In the eighteenth H site, H(33,35) is bonded in a single-bond geometry to one C(37,39) atom. In the nineteenth H site, H(34) is bonded in a single-bond geometry to one C(38) atom. In the twentieth H site, H(36) is bonded in a single-bond geometry to one C(40) atom. There are thirty-one inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mo(1), one Cu(1), and one Cu(7) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mo(2,4); one Cu(2,4); and one Cu(6,8) atom. The O(2)-Cu(6,8) bond length is 2.59 Å. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mo(3), one Cu(3), and one Cu(5) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Mo(2,4); one Cu(2,4); and one Cu(6,8) atom. The O(4)-Mo(2,4) bond length is 1.80 Å. The O(4)-Cu(2,4) bond length is 1.95 Å. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(1) and one Cu(5) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(2,4) and one Cu(6,8) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Mo(3) and one Cu(7) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mo(2,4) and one Cu(6,8) atom. The O(8)-Mo(2,4) bond length is 1.77 Å. The O(8)-Cu(6,8) bond length is 1.91 Å. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Mo(1) and one Cu(7) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Mo(2,4) and one Cu(6,8) atom. The O(10)-Cu(6,8) bond length is 2.35 Å. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Mo(3) and one Cu(5) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mo(2,4) and one Cu(6,8) atom. The O(12)-Mo(2,4) bond length is 1.75 Å. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Mo(1) and one Cu(3) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Mo(2,4) and one Cu(2,4) atom. The O(14)-Cu(2,4) bond length is 1.95 Å. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Mo(3) and one Cu(1) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Mo(2,4) and one Cu(2,4) atom. The O(16)-Mo(2,4) bond length is 1.81 Å. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Mo(5), one Cu(1), and one Cu(3) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Mo(6,8) and two equivalent Cu(2,4) atoms. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Mo(7), one Cu(1), and one Cu(3) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Mo(6,8) and two equivalent Cu(2,4) atoms. The O(20)-Mo(6,8) bond length is 1.82 Å. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Mo(5) and one Cu(5) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Mo(6,8) and one Cu(6,8) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Mo(7) and one Cu(7) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Mo(6,8) and one Cu(6,8) atom. The O(24)-Mo(6,8) bond length is 1.78 Å. The O(24)-Cu(6,8) bond length is 1.98 Å. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal planar geometry to one Mo(5), one Cu(1), and one Cu(7) atom. In the twenty-sixth O site, O(26) is bonded in a distorted trigonal planar geometry to one Mo(6,8); one Cu(2,4); and one Cu(6,8) atom. The O(26)-Cu(6,8) bond length is 1.97 Å. In the twenty-seventh O site, O(27) is bonded in a distorted trigonal planar geometry to one Mo(7), one Cu(3), and one Cu(5) atom. In the twenty-eighth O site, O(28) is bonded in a distorted trigonal planar geometry to one Mo(6,8); one Cu(2,4); and one Cu(6,8) atom. The O(28)-Mo(6,8) bond length is 1.82 Å. The O(28)-Cu(2,4) bond length is 2.40 Å. In the twenty-ninth O site, O(29) is bonded in a single-bond geometry to one Mo(5) atom. In the thirtieth O site, O(30,32) is bonded in a single-bond geometry to one Mo(6,8) atom. In the thirty-first O site, O(31) is bonded in a single-bond geometry to one Mo(7) atom. Linkers: 4 c1cc(Nc2ccncc2)ccn1. Metal clusters: 8 [Cu] ,8 [Mo]. The MOF has largest included sphere 3.75 A, density 2.29 g/cm3, surface area 2569.06 m2/g, accessible volume 0.11 cm3/g