KC11NH15O3(CH)7CH3CHO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of fourteen 02329_fluka molecules, two dimethyl ether molecules, and one KC11NH15O3 cluster. In the KC11NH15O3 cluster, K(1) is bonded in a 7-coordinate geometry to two equivalent N(1), two equivalent H(1), one O(1), one O(3), and one O(4) atom. There is one shorter (2.77 Å) and one longer (2.87 Å) K(1)-N(1) bond length. There is one shorter (2.70 Å) and one longer (2.86 Å) K(1)-H(1) bond length. The K(1)-O(1) bond length is 2.72 Å. The K(1)-O(3) bond length is 2.64 Å. The K(1)-O(4) bond length is 2.68 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1) atom. The C(1)-N(1) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(7) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one N(1) atom. The C(7)-C(12) bond length is 1.42 Å. The C(7)-C(8) bond length is 1.43 Å. The C(7)-N(1) bond length is 1.38 Å. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the fifth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(10) atom. The C(12)-H(10) bond length is 1.09 Å. In the sixth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one H(11), one H(12), and one O(1) atom. The C(13)-H(11) bond length is 1.11 Å. The C(13)-H(12) bond length is 1.10 Å. The C(13)-O(1) bond length is 1.44 Å. In the seventh C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one H(17), one H(18), and one O(1) atom. The C(16)-H(17) bond length is 1.10 Å. The C(16)-H(18) bond length is 1.11 Å. The C(16)-O(1) bond length is 1.44 Å. In the eighth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one H(19), one H(20), and one O(3) atom. The C(17)-H(19) bond length is 1.11 Å. The C(17)-H(20) bond length is 1.10 Å. The C(17)-O(3) bond length is 1.44 Å. In the ninth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one H(21), one H(22), and one O(3) atom. The C(18)-H(21) bond length is 1.10 Å. The C(18)-H(22) bond length is 1.10 Å. The C(18)-O(3) bond length is 1.44 Å. In the tenth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one H(23), one H(24), and one O(4) atom. The C(19)-H(23) bond length is 1.11 Å. The C(19)-H(24) bond length is 1.10 Å. The C(19)-O(4) bond length is 1.44 Å. In the eleventh C site, C(20) is bonded in a distorted trigonal non-coplanar geometry to one H(25), one H(26), and one O(4) atom. The C(20)-H(25) bond length is 1.10 Å. The C(20)-H(26) bond length is 1.10 Å. The C(20)-O(4) bond length is 1.44 Å. N(1) is bonded in a distorted bent 120 degrees geometry to two equivalent K(1), one C(1), and one C(7) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to two equivalent K(1) and one C(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(20) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(21) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(22) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(23) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(24) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(25) is bonded in a single-bond geometry to one C(20) atom. In the fifteenth H site, H(26) is bonded in a single-bond geometry to one C(20) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one K(1), one C(13), and one C(16) atom. In the second O site, O(3) is bonded in a distorted trigonal planar geometry to one K(1), one C(17), and one C(18) atom. In the third O site, O(4) is bonded in a distorted water-like geometry to one K(1), one C(19), and one C(20) atom. Linkers: 2 c1ccc([N]c2ccccc2)cc1 ,2 C1COCCO1. Metal clusters: 2 [K]. The MOF has largest included sphere 4.10 A, density 1.07 g/cm3, surface area 5323.70 m2/g, accessible volume 0.35 cm3/g