Cu3C48N12H32O13H2O crystallizes in the triclinic P1 space group. The structure consists of one water molecule inside a Cu3C48N12H32O13 framework. In the Cu3C48N12H32O13 framework, there are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(10), one O(1), and one O(10) atom. The Cu(1)-N(1) bond length is 1.97 Å. The Cu(1)-N(10) bond length is 1.96 Å. The Cu(1)-O(1) bond length is 2.01 Å. The Cu(1)-O(10) bond length is 1.97 Å. In the second Cu site, Cu(2) is bonded in a rectangular see-saw-like geometry to one N(6), one N(8), one O(12), and one O(4) atom. The Cu(2)-N(6) bond length is 1.99 Å. The Cu(2)-N(8) bond length is 1.99 Å. The Cu(2)-O(12) bond length is 1.96 Å. The Cu(2)-O(4) bond length is 1.99 Å. In the third Cu site, Cu(3) is bonded in a distorted square pyramidal geometry to one N(12), one N(4), one O(14), one O(5), and one O(7) atom. The Cu(3)-N(12) bond length is 1.98 Å. The Cu(3)-N(4) bond length is 1.99 Å. The Cu(3)-O(14) bond length is 2.48 Å. The Cu(3)-O(5) bond length is 2.01 Å. The Cu(3)-O(7) bond length is 1.99 Å. There are forty-eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.50 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(8) bond length is 1.50 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(9) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(9) bond length is 1.51 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.31 Å. The C(7)-O(2) bond length is 1.24 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.26 Å. The C(8)-O(4) bond length is 1.30 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(5), and one O(6) atom. The C(9)-O(5) bond length is 1.29 Å. The C(9)-O(6) bond length is 1.26 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(16) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.40 Å. The C(10)-C(16) bond length is 1.50 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(4) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(4) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(17) bond length is 1.50 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(5) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-H(5) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(18) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(18) bond length is 1.50 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one H(6) atom. The C(15)-H(6) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(7), and one O(8) atom. The C(16)-O(7) bond length is 1.30 Å. The C(16)-O(8) bond length is 1.26 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(10), and one O(9) atom. The C(17)-O(10) bond length is 1.30 Å. The C(17)-O(9) bond length is 1.25 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(11), and one O(12) atom. The C(18)-O(11) bond length is 1.25 Å. The C(18)-O(12) bond length is 1.30 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(20), one C(24), and one N(2) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-C(24) bond length is 1.40 Å. The C(19)-N(2) bond length is 1.42 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(7) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(7) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one N(3) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-N(3) bond length is 1.41 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one H(8) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-H(8) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one N(5) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-N(5) bond length is 1.42 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(19), one C(23), and one H(9) atom. The C(24)-H(9) bond length is 1.09 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(10) atom. The C(25)-N(1) bond length is 1.32 Å. The C(25)-N(2) bond length is 1.37 Å. The C(25)-H(10) bond length is 1.08 Å. In the twenty-sixth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(27), one N(1), and one H(11) atom. The C(26)-C(27) bond length is 1.37 Å. The C(26)-N(1) bond length is 1.38 Å. The C(26)-H(11) bond length is 1.08 Å. In the twenty-seventh C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(26), one N(2), and one H(12) atom. The C(27)-N(2) bond length is 1.39 Å. The C(27)-H(12) bond length is 1.08 Å. In the twenty-eighth C site, C(28) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(13) atom. The C(28)-N(3) bond length is 1.37 Å. The C(28)-N(4) bond length is 1.32 Å. The C(28)-H(13) bond length is 1.08 Å. In the twenty-ninth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(30), one N(3), and one H(14) atom. The C(29)-C(30) bond length is 1.37 Å. The C(29)-N(3) bond length is 1.39 Å. The C(29)-H(14) bond length is 1.09 Å. In the thirtieth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(29), one N(4), and one H(15) atom. The C(30)-N(4) bond length is 1.39 Å. The C(30)-H(15) bond length is 1.08 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(16) atom. The C(31)-N(5) bond length is 1.37 Å. The C(31)-N(6) bond length is 1.32 Å. The C(31)-H(16) bond length is 1.08 Å. In the thirty-second C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(33), one N(6), and one H(17) atom. The C(32)-C(33) bond length is 1.37 Å. The C(32)-N(6) bond length is 1.38 Å. The C(32)-H(17) bond length is 1.08 Å. In the thirty-third C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(32), one N(5), and one H(18) atom. The C(33)-N(5) bond length is 1.39 Å. The C(33)-H(18) bond length is 1.08 Å. In the thirty-fourth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(35), one C(39), and one N(7) atom. The C(34)-C(35) bond length is 1.40 Å. The C(34)-C(39) bond length is 1.40 Å. The C(34)-N(7) bond length is 1.42 Å. In the thirty-fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(34), one C(36), and one H(19) atom. The C(35)-C(36) bond length is 1.40 Å. The C(35)-H(19) bond length is 1.09 Å. In the thirty-sixth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(35), one C(37), and one N(9) atom. The C(36)-C(37) bond length is 1.40 Å. The C(36)-N(9) bond length is 1.41 Å. In the thirty-seventh C site, C(37) is bonded in a distorted single-bond geometry to one C(36), one C(38), and one H(20) atom. The C(37)-C(38) bond length is 1.40 Å. The C(37)-H(20) bond length is 1.09 Å. In the thirty-eighth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(37), one C(39), and one N(11) atom. The C(38)-C(39) bond length is 1.39 Å. The C(38)-N(11) bond length is 1.41 Å. In the thirty-ninth C site, C(39) is bonded in a distorted single-bond geometry to one C(34), one C(38), and one H(21) atom. The C(39)-H(21) bond length is 1.08 Å. In the fortieth C site, C(40) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(22) atom. The C(40)-N(7) bond length is 1.37 Å. The C(40)-N(8) bond length is 1.33 Å. The C(40)-H(22) bond length is 1.08 Å. In the forty-first C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(42), one N(8), and one H(23) atom. The C(41)-C(42) bond length is 1.37 Å. The C(41)-N(8) bond length is 1.39 Å. The C(41)-H(23) bond length is 1.08 Å. In the forty-second C site, C(42) is bonded in a distorted trigonal planar geometry to one C(41), one N(7), and one H(24) atom. The C(42)-N(7) bond length is 1.39 Å. The C(42)-H(24) bond length is 1.08 Å. In the forty-third C site, C(43) is bonded in a trigonal planar geometry to one N(10), one N(9), and one H(25) atom. The C(43)-N(10) bond length is 1.32 Å. The C(43)-N(9) bond length is 1.37 Å. The C(43)-H(25) bond length is 1.08 Å. In the forty-fourth C site, C(44) is bonded in a distorted bent 120 degrees geometry to one C(45), one N(9), and one H(26) atom. The C(44)-C(45) bond length is 1.37 Å. The C(44)-N(9) bond length is 1.40 Å. The C(44)-H(26) bond length is 1.09 Å. In the forty-fifth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(44), one N(10), and one H(27) atom. The C(45)-N(10) bond length is 1.38 Å. The C(45)-H(27) bond length is 1.08 Å. In the forty-sixth C site, C(46) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(28) atom. The C(46)-N(11) bond length is 1.37 Å. The C(46)-N(12) bond length is 1.32 Å. The C(46)-H(28) bond length is 1.08 Å. In the forty-seventh C site, C(47) is bonded in a 3-coordinate geometry to one C(48), one N(11), and one H(29) atom. The C(47)-C(48) bond length is 1.37 Å. The C(47)-N(11) bond length is 1.39 Å. The C(47)-H(29) bond length is 1.08 Å. In the forty-eighth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(47), one N(12), and one H(30) atom. The C(48)-N(12) bond length is 1.38 Å. The C(48)-H(30) bond length is 1.08 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(25), and one C(26) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(19), one C(25), and one C(27) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(21), one C(28), and one C(29) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(3), one C(28), and one C(30) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(23), one C(31), and one C(33) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(2), one C(31), and one C(32) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(34), one C(40), and one C(42) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Cu(2), one C(40), and one C(41) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(36), one C(43), and one C(44) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Cu(1), one C(43), and one C(45) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one C(38), one C(46), and one C(47) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Cu(3), one C(46), and one C(48) atom. There are thirty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(25) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(26) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(27) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(28) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(29) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(30) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(31) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(32) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(33) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(35) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(37) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(39) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(40) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(41) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(42) atom. In the twenty-fifth H site, H(25) is bonded in a single-bond geometry to one C(43) atom. In the twenty-sixth H site, H(26) is bonded in a single-bond geometry to one C(44) atom. In the twenty-seventh H site, H(27) is bonded in a single-bond geometry to one C(45) atom. In the twenty-eighth H site, H(28) is bonded in a single-bond geometry to one C(46) atom. In the twenty-ninth H site, H(29) is bonded in a single-bond geometry to one C(47) atom. In the thirtieth H site, H(30) is bonded in a single-bond geometry to one C(48) atom. In the thirty-first H site, H(33) is bonded in a single-bond geometry to one O(14) and one O(6) atom. The H(33)-O(14) bond length is 1.00 Å. The H(33)-O(6) bond length is 1.65 Å. In the thirty-second H site, H(34) is bonded in a single-bond geometry to one O(14) atom. The H(34)-O(14) bond length is 0.98 Å. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(7) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cu(2) and one C(8) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(9) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one C(9) and one H(33) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(16) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(17) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(17) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one C(18) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one Cu(2) and one C(18) atom. In the thirteenth O site, O(14) is bonded in a water-like geometry to one Cu(3), one H(33), and one H(34) atom. Linkers: 1 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,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#N.[C]/C([N])=[C]\[C]/N=C/[C][N].[C]/N=C/[CH][N].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]N([Cu])[C][C][N].[C][C].[C][C].[C][C]/[C]=[C]\[C].[C][N]/[C]=C/[C][N].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][C][N].[N][Cu]([O])O[C]=O.[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=C[N].[CH]=N[Cu].[CH]=[N].[CH]=[N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]/C=[C]/C([O])=O.[C]/[C]=[C]\[C]=C/[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C][CH].[C][C]([N])/C=C(\[CH])N([C])[C].[C][C]/[C]=[C]\C(=[CH])[N].[C][C][N].[C][N].[C][N].[C][N]/C=C\[N].[C][N][Cu][O].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[Cu].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O]. Metal clusters: 1 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 4.71 A, density 1.34 g/cm3, surface area 4089.65 m2/g, accessible volume 0.28 cm3/g