CdC18N4H22O5(CH2)2(CH)8 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two p-xylene molecules, and two CdC18N4H22O5 clusters. In each CdC18N4H22O5 cluster, Cd(1) is bonded in a distorted pentagonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(2), one O(3), one O(4), and one O(5) atom. The Cd(1)-N(1) bond length is 2.36 Å. The Cd(1)-N(2) bond length is 2.36 Å. The Cd(1)-O(1) bond length is 2.43 Å. The Cd(1)-O(2) bond length is 2.43 Å. The Cd(1)-O(3) bond length is 2.55 Å. The Cd(1)-O(4) bond length is 2.55 Å. The Cd(1)-O(5) bond length is 2.28 Å. There are nine inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal planar geometry to one C(3,4); one N(1); and one H(3,4) atom. The C(1,2)-C(3,4) bond length is 1.40 Å. The C(1,2)-N(1) bond length is 1.34 Å. The C(1,2)-H(3,4) bond length is 1.09 Å. In the second C site, C(3,4) is bonded in a trigonal planar geometry to one C(1,2); one C(11,12); and one C(5,6) atom. The C(3,4)-C(11,12) bond length is 1.51 Å. The C(3,4)-C(5,6) bond length is 1.40 Å. In the third C site, C(5,6) is bonded in a distorted single-bond geometry to one C(3,4); one C(7,8); and one H(5,6) atom. The C(5,6)-C(7,8) bond length is 1.39 Å. The C(5,6)-H(5,6) bond length is 1.09 Å. In the fourth C site, C(7,8) is bonded in a distorted trigonal planar geometry to one C(5,6); one C(9,10); and one H(7,8) atom. The C(7,8)-C(9,10) bond length is 1.39 Å. The C(7,8)-H(7,8) bond length is 1.09 Å. In the fifth C site, C(9,10) is bonded in a distorted trigonal planar geometry to one C(7,8); one N(1); and one H(9,10) atom. The C(9,10)-N(1) bond length is 1.35 Å. The C(9,10)-H(9,10) bond length is 1.09 Å. In the sixth C site, C(11,12) is bonded in a distorted trigonal non-coplanar geometry to one C(3,4); one N(3,4); one H(11,12); and one H(13,14) atom. The C(11,12)-N(3,4) bond length is 1.46 Å. The C(11,12)-H(11,12) bond length is 1.10 Å. The C(11,12)-H(13,14) bond length is 1.11 Å. In the seventh C site, C(13,14) is bonded in a distorted trigonal non-coplanar geometry to one N(3,4); one H(15,16); and one H(17,18) atom. The C(13,14)-N(3,4) bond length is 1.46 Å. The C(13,14)-H(15,16) bond length is 1.11 Å. The C(13,14)-H(17,18) bond length is 1.10 Å. In the eighth C site, C(15,16) is bonded in a distorted trigonal non-coplanar geometry to one N(3,4); one H(19,20); and one H(21,22) atom. The C(15,16)-N(3,4) bond length is 1.46 Å. The C(15,16)-H(19,20) bond length is 1.10 Å. The C(15,16)-H(21,22) bond length is 1.11 Å. In the ninth C site, C(17,18) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(17,18)-O(1) bond length is 1.28 Å. The C(17,18)-O(3) bond length is 1.27 Å. There are three inequivalent N sites. In the first N site, N(3,4) is bonded in a trigonal non-coplanar geometry to one C(11,12); one C(13,14); and one C(15,16) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Cd(1); one C(1,2); and one C(9,10) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one Cd(1); one C(1,2); and one C(9,10) atom. The N(2)-C(1,2) bond length is 1.34 Å. The N(2)-C(9,10) bond length is 1.35 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. The H(1)-O(5) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(5) atom. The H(2)-O(5) bond length is 0.99 Å. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(1,2) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(5,6) atom. In the fifth H site, H(7,8) is bonded in a single-bond geometry to one C(7,8) atom. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(9,10) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(11,12) atom. In the eighth H site, H(13,14) is bonded in a single-bond geometry to one C(11,12) atom. In the ninth H site, H(15,16) is bonded in a single-bond geometry to one C(13,14) atom. In the tenth H site, H(17,18) is bonded in a single-bond geometry to one C(13,14) atom. In the eleventh H site, H(19,20) is bonded in a single-bond geometry to one C(15,16) atom. In the twelfth H site, H(21,22) is bonded in a single-bond geometry to one C(15,16) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(17,18) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(17,18) atom. The O(2)-C(17,18) bond length is 1.28 Å. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(17,18) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(17,18) atom. The O(4)-C(17,18) bond length is 1.27 Å. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Cd(1), one H(1), and one H(2) atom. Linkers: 2 [O]C(=O)CCc1ccc(CCC([O])=O)cc1 ,2 [c]1cncc(CN2CCN(Cc3cccnc3)CC2)c1 ,2 c1cncc(CN2CCN(Cc3cccnc3)CC2)c1. Metal clusters: 2 O.[C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 1.84 A, density 1.57 g/cm3, surface area 4840.14 m2/g, accessible volume 0.15 cm3/g