(CH2)2CdC11N5H10O2Cl crystallizes in the triclinic P1 space group. The structure consists of four 02329_fluka molecules inside a CdC11N5H10O2Cl framework. In the CdC11N5H10O2Cl framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one N(10), one N(4), one N(5), one O(3), one O(4), and one Cl(1) atom to form distorted corner-sharing CdN3ClO2 pentagonal pyramids. The Cd(1)-N(10) bond length is 2.44 Å. The Cd(1)-N(4) bond length is 2.36 Å. The Cd(1)-N(5) bond length is 2.56 Å. The Cd(1)-O(3) bond length is 2.31 Å. The Cd(1)-O(4) bond length is 2.36 Å. The Cd(1)-Cl(1) bond length is 2.60 Å. In the second Cd site, Cd(2) is bonded to one N(3), one N(6), one N(9), one O(3), one O(4), and one Cl(2) atom to form distorted corner-sharing CdN3ClO2 pentagonal pyramids. The Cd(2)-N(3) bond length is 2.36 Å. The Cd(2)-N(6) bond length is 2.56 Å. The Cd(2)-N(9) bond length is 2.44 Å. The Cd(2)-O(3) bond length is 2.37 Å. The Cd(2)-O(4) bond length is 2.31 Å. The Cd(2)-Cl(2) bond length is 2.60 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one C(3,4); one N(1); and one N(7) atom. The C(1)-C(3,4) bond length is 1.45 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(7) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one C(3,4); one N(2); and one N(8) atom. The C(2)-C(3,4) bond length is 1.45 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-N(8) bond length is 1.36 Å. In the third C site, C(3,4) is bonded in a trigonal planar geometry to one C(1); one C(13,14); and one C(5,6) atom. The C(3,4)-C(13,14) bond length is 1.41 Å. The C(3,4)-C(5,6) bond length is 1.40 Å. In the fourth C site, C(5,6) is bonded in a distorted trigonal planar geometry to one C(3,4); one C(7); and one H(3,4) atom. The C(5,6)-C(7) bond length is 1.39 Å. The C(5,6)-H(3,4) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(5,6); one C(9,10); and one H(5,6) atom. The C(7)-C(9,10) bond length is 1.40 Å. The C(7)-H(5,6) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(5,6); one C(9,10); and one H(5,6) atom. The C(8)-C(5,6) bond length is 1.39 Å. The C(8)-C(9,10) bond length is 1.40 Å. The C(8)-H(5,6) bond length is 1.09 Å. In the seventh C site, C(9,10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(7) atom. The C(9,10)-C(11) bond length is 1.40 Å. The C(9,10)-C(15) bond length is 1.51 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(9,10) and one H(7,8) atom. The C(11)-H(7,8) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(9,10) and one H(7,8) atom. The C(12)-C(9,10) bond length is 1.40 Å. The C(12)-H(7,8) bond length is 1.09 Å. In the tenth C site, C(13,14) is bonded in a distorted single-bond geometry to one C(3,4) and one H(9,10) atom. The C(13,14)-H(9,10) bond length is 1.09 Å. In the eleventh C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one C(9,10); one N(9); one H(11,12); and one H(13,14) atom. The C(15)-N(9) bond length is 1.49 Å. The C(15)-H(11,12) bond length is 1.10 Å. The C(15)-H(13,14) bond length is 1.10 Å. In the twelfth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one C(9,10); one N(10); one H(11,12); and one H(13,14) atom. The C(16)-C(9,10) bond length is 1.51 Å. The C(16)-N(10) bond length is 1.49 Å. The C(16)-H(11,12) bond length is 1.10 Å. The C(16)-H(13,14) bond length is 1.10 Å. In the thirteenth C site, C(17,18) is bonded in a distorted trigonal non-coplanar geometry to one N(9); one H(15,16); and one H(17,18) atom. The C(17,18)-N(9) bond length is 1.48 Å. The C(17,18)-H(15,16) bond length is 1.10 Å. The C(17,18)-H(17,18) bond length is 1.11 Å. In the fourteenth C site, C(23,24) is bonded in a distorted water-like geometry to one N(9) and one H(27,28) atom. The C(23,24)-N(9) bond length is 1.48 Å. The C(23,24)-H(27,28) bond length is 1.10 Å. In the fifteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one O(1,2) and one O(3) atom. The C(25)-O(1,2) bond length is 1.24 Å. The C(25)-O(3) bond length is 1.31 Å. In the sixteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one O(1,2) and one O(4) atom. The C(26)-O(1,2) bond length is 1.24 Å. The C(26)-O(4) bond length is 1.31 Å. There are ten inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one C(1) and one N(3) atom. The N(1)-N(3) bond length is 1.34 Å. In the second N site, N(2) is bonded in a distorted single-bond geometry to one C(2) and one N(4) atom. The N(2)-N(4) bond length is 1.34 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(2), one N(1), and one N(5) atom. The N(3)-N(5) bond length is 1.30 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one N(2), and one N(6) atom. The N(4)-N(6) bond length is 1.30 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cd(1), one N(3), and one N(7) atom. The N(5)-N(7) bond length is 1.34 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cd(2), one N(4), and one N(8) atom. The N(6)-N(8) bond length is 1.34 Å. In the seventh N site, N(7) is bonded in a 3-coordinate geometry to one C(1), one N(5), and one H(1) atom. The N(7)-H(1) bond length is 1.05 Å. In the eighth N site, N(8) is bonded in a 3-coordinate geometry to one C(2), one N(6), and one H(2) atom. The N(8)-H(2) bond length is 1.05 Å. In the ninth N site, N(9) is bonded in a distorted tetrahedral geometry to one Cd(2); one C(15); one C(17,18); and one C(23,24) atom. In the tenth N site, N(10) is bonded in a distorted tetrahedral geometry to one Cd(1); one C(16); one C(17,18); and one C(23,24) atom. The N(10)-C(17,18) bond length is 1.48 Å. The N(10)-C(23,24) bond length is 1.48 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(8) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(5,6) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7,8) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(13,14) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(13,14) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(15,16) is bonded in a single-bond geometry to one C(17,18) atom. In the tenth H site, H(17,18) is bonded in a single-bond geometry to one C(17,18) atom. In the eleventh H site, H(27,28) is bonded in a single-bond geometry to one C(23,24) atom. There are three inequivalent O sites. In the first O site, O(1,2) is bonded in a single-bond geometry to one C(25) atom. In the second O site, O(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one Cd(2), and one C(25) atom. In the third O site, O(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one Cd(2), and one C(26) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Cd(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Cd(2) atom. Linkers: 1 [O]C(=O)[C@H]1CCCN1Cc1ccc(-c2nnn[nH]2)cc1 ,1 [O]C(=O)[C@@H]1CCCN1Cc1ccc(-c2nnn[nH]2)cc1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 3.02 A, density 1.76 g/cm3, surface area 4007.52 m2/g, accessible volume 0.17 cm3/g