CdC8H14Br2(N2O)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CdC8H14Br2(N2O)2 clusters. Cd(1) is bonded to one N(1), one O(1), one O(2), one Br(1), and one Br(2) atom to form distorted CdBr2NO2 trigonal bipyramids that share  a cornercorner with one C(1)H2N2 tetrahedra,  a cornercorner with one C(3)H2N2 tetrahedra, and  a cornercorner with one C(4)H2N2 tetrahedra. The Cd(1)-N(1) bond length is 2.40 Å. The Cd(1)-O(1) bond length is 2.40 Å. The Cd(1)-O(2) bond length is 2.49 Å. The Cd(1)-Br(1) bond length is 2.59 Å. The Cd(1)-Br(2) bond length is 2.57 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded to one N(1), one N(2), one H(1), and one H(2) atom to form CH2N2 tetrahedra that share  a cornercorner with one C(2)H2N2 tetrahedra,  a cornercorner with one C(3)H2N2 tetrahedra,  a cornercorner with one C(4)H2N2 tetrahedra,  a cornercorner with one C(5)H2N2 tetrahedra, and  a cornercorner with one Cd(1)Br2NO2 trigonal bipyramid. The C(1)-N(1) bond length is 1.46 Å. The C(1)-N(2) bond length is 1.53 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the second C site, C(2) is bonded to one N(2), one N(3), one H(3), and one H(4) atom to form corner-sharing CH2N2 tetrahedra. The C(2)-N(2) bond length is 1.55 Å. The C(2)-N(3) bond length is 1.43 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. In the third C site, C(3) is bonded to one N(1), one N(3), one H(5), and one H(6) atom to form CH2N2 tetrahedra that share  a cornercorner with one C(1)H2N2 tetrahedra,  a cornercorner with one C(2)H2N2 tetrahedra,  a cornercorner with one C(4)H2N2 tetrahedra,  a cornercorner with one C(6)H2N2 tetrahedra, and  a cornercorner with one Cd(1)Br2NO2 trigonal bipyramid. The C(3)-N(1) bond length is 1.50 Å. The C(3)-N(3) bond length is 1.46 Å. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(6) bond length is 1.10 Å. In the fourth C site, C(4) is bonded to one N(1), one N(4), one H(7), and one H(8) atom to form CH2N2 tetrahedra that share  a cornercorner with one C(1)H2N2 tetrahedra,  a cornercorner with one C(3)H2N2 tetrahedra,  a cornercorner with one C(5)H2N2 tetrahedra,  a cornercorner with one C(6)H2N2 tetrahedra, and  a cornercorner with one Cd(1)Br2NO2 trigonal bipyramid. The C(4)-N(1) bond length is 1.49 Å. The C(4)-N(4) bond length is 1.46 Å. The C(4)-H(7) bond length is 1.10 Å. The C(4)-H(8) bond length is 1.10 Å. In the fifth C site, C(5) is bonded to one N(2), one N(4), one H(10), and one H(9) atom to form corner-sharing CH2N2 tetrahedra. The C(5)-N(2) bond length is 1.55 Å. The C(5)-N(4) bond length is 1.43 Å. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. In the sixth C site, C(6) is bonded to one N(3), one N(4), one H(11), and one H(12) atom to form corner-sharing CH2N2 tetrahedra. The C(6)-N(3) bond length is 1.47 Å. The C(6)-N(4) bond length is 1.48 Å. The C(6)-H(11) bond length is 1.10 Å. The C(6)-H(12) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(13), and one H(14) atom. The C(7)-N(2) bond length is 1.49 Å. The C(7)-H(13) bond length is 1.10 Å. The C(7)-H(14) bond length is 1.10 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(8)-O(1) bond length is 1.28 Å. The C(8)-O(2) bond length is 1.26 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Cd(1), one C(1), one C(3), and one C(4) atom to form corner-sharing NCdC3 tetrahedra. In the second N site, N(2) is bonded to one C(1), one C(2), one C(5), and one C(7) atom to form corner-sharing NC4 tetrahedra. In the third N site, N(3) is bonded in a trigonal non-coplanar geometry to one C(2), one C(3), and one C(6) atom. In the fourth N site, N(4) is bonded in a trigonal non-coplanar geometry to one C(4), one C(5), and one C(6) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(7) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(8) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(8) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Cd(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Cd(1) atom. Linkers: 4 [O]C(=O)C[N@]12C[N@]3C[N@@](C2)C[N@@](C1)C3. Metal clusters: 4 Br[Cd]1(Br)O[C]O1. The MOF has largest included sphere 1.85 A, density 2.45 g/cm3, surface area 3224.27 m2/g, accessible volume 0.08 cm3/g