In3C34H31O15(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a In3C34H31O15 framework. In the In3C34H31O15 framework, there are four inequivalent In sites. In the first In site, In(1) is bonded to two equivalent O(10), two equivalent O(3), and two equivalent O(7) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles are 66°. Both In(1)-O(10) bond lengths are 2.23 Å. Both In(1)-O(3) bond lengths are 2.13 Å. Both In(1)-O(7) bond lengths are 2.20 Å. In the second In site, In(2) is bonded to one O(11), one O(15), one O(2), one O(3), one O(6), and one O(9) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 66-67°. The In(2)-O(11) bond length is 2.18 Å. The In(2)-O(15) bond length is 2.19 Å. The In(2)-O(2) bond length is 2.14 Å. The In(2)-O(3) bond length is 2.14 Å. The In(2)-O(6) bond length is 2.19 Å. The In(2)-O(9) bond length is 2.18 Å. In the third In site, In(3) is bonded to one O(1), one O(13), one O(14), one O(2), one O(4), and one O(8) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 67-68°. The In(3)-O(1) bond length is 2.14 Å. The In(3)-O(13) bond length is 2.22 Å. The In(3)-O(14) bond length is 2.18 Å. The In(3)-O(2) bond length is 2.13 Å. The In(3)-O(4) bond length is 2.24 Å. The In(3)-O(8) bond length is 2.24 Å. In the fourth In site, In(4) is bonded to two equivalent O(1), two equivalent O(12), and two equivalent O(5) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles are 68°. Both In(4)-O(1) bond lengths are 2.15 Å. Both In(4)-O(12) bond lengths are 2.17 Å. Both In(4)-O(5) bond lengths are 2.21 Å. There are thirty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(4), and one O(5) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(4) bond length is 1.27 Å. The C(1)-O(5) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(4) atom. The C(2)-C(3) bond length is 1.34 Å. The C(2)-H(4) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(5) atom. The C(3)-C(4) bond length is 1.48 Å. The C(3)-H(5) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(9) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(6) atom. The C(5)-C(10) bond length is 1.51 Å. The C(5)-C(6) bond length is 1.42 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(13), one C(5), and one C(7) atom. The C(6)-C(13) bond length is 1.47 Å. The C(6)-C(7) bond length is 1.42 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.51 Å. The C(7)-C(8) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(16), one C(7), and one C(9) atom. The C(8)-C(16) bond length is 1.47 Å. The C(8)-C(9) bond length is 1.41 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(12), one C(4), and one C(8) atom. The C(9)-C(12) bond length is 1.50 Å. In the tenth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one H(6), one H(7), and one H(8) atom. The C(10)-H(6) bond length is 1.10 Å. The C(10)-H(7) bond length is 1.10 Å. The C(10)-H(8) bond length is 1.10 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one C(7), one H(10), one H(11), and one H(9) atom. The C(11)-H(10) bond length is 1.10 Å. The C(11)-H(11) bond length is 1.10 Å. The C(11)-H(9) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(12), one H(13), and one H(14) atom. The C(12)-H(12) bond length is 1.10 Å. The C(12)-H(13) bond length is 1.10 Å. The C(12)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one C(6), and one H(15) atom. The C(13)-C(14) bond length is 1.35 Å. The C(13)-H(15) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(16) atom. The C(14)-C(15) bond length is 1.48 Å. The C(14)-H(16) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one O(6), and one O(7) atom. The C(15)-O(6) bond length is 1.28 Å. The C(15)-O(7) bond length is 1.28 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(8) and one H(17) atom. The C(16)-H(17) bond length is 1.09 Å. In the seventeenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one O(8) and one O(9) atom. The C(18)-O(8) bond length is 1.28 Å. The C(18)-O(9) bond length is 1.28 Å. In the eighteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(11) atom. The C(19)-O(10) bond length is 1.28 Å. The C(19)-O(11) bond length is 1.28 Å. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(20) atom. The C(21)-C(22) bond length is 1.48 Å. The C(21)-H(20) bond length is 1.10 Å. In the twentieth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(27) atom. The C(22)-C(23) bond length is 1.41 Å. The C(22)-C(27) bond length is 1.40 Å. In the twenty-first C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.41 Å. The C(23)-C(28) bond length is 1.51 Å. In the twenty-second C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(31) atom. The C(24)-C(25) bond length is 1.41 Å. The C(24)-C(31) bond length is 1.46 Å. In the twenty-third C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(29) atom. The C(25)-C(26) bond length is 1.41 Å. The C(25)-C(29) bond length is 1.51 Å. In the twenty-fourth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(34) atom. The C(26)-C(27) bond length is 1.42 Å. The C(26)-C(34) bond length is 1.47 Å. In the twenty-fifth C site, C(27) is bonded in a trigonal planar geometry to one C(22), one C(26), and one C(30) atom. The C(27)-C(30) bond length is 1.51 Å. In the twenty-sixth C site, C(28) is bonded in a distorted trigonal non-coplanar geometry to one C(23), one H(21), one H(22), and one H(23) atom. The C(28)-H(21) bond length is 1.10 Å. The C(28)-H(22) bond length is 1.10 Å. The C(28)-H(23) bond length is 1.10 Å. In the twenty-seventh C site, C(29) is bonded in a distorted trigonal non-coplanar geometry to one C(25), one H(24), one H(25), and one H(26) atom. The C(29)-H(24) bond length is 1.10 Å. The C(29)-H(25) bond length is 1.09 Å. The C(29)-H(26) bond length is 1.10 Å. In the twenty-eighth C site, C(30) is bonded in a distorted trigonal non-coplanar geometry to one C(27), one H(27), one H(28), and one H(29) atom. The C(30)-H(27) bond length is 1.09 Å. The C(30)-H(28) bond length is 1.10 Å. The C(30)-H(29) bond length is 1.10 Å. In the twenty-ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(24), one C(32), and one H(30) atom. The C(31)-C(32) bond length is 1.35 Å. The C(31)-H(30) bond length is 1.09 Å. In the thirtieth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31), one C(33), and one H(31) atom. The C(32)-C(33) bond length is 1.47 Å. The C(32)-H(31) bond length is 1.09 Å. In the thirty-first C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(12), and one O(13) atom. The C(33)-O(12) bond length is 1.28 Å. The C(33)-O(13) bond length is 1.28 Å. In the thirty-second C site, C(34) is bonded in a distorted single-bond geometry to one C(26), one C(35), and one H(32) atom. The C(34)-C(35) bond length is 1.35 Å. The C(34)-H(32) bond length is 1.09 Å. In the thirty-third C site, C(35) is bonded in a distorted single-bond geometry to one C(34), one C(36), and one H(33) atom. The C(35)-C(36) bond length is 1.48 Å. The C(35)-H(33) bond length is 1.09 Å. In the thirty-fourth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(14), and one O(15) atom. The C(36)-O(14) bond length is 1.28 Å. The C(36)-O(15) bond length is 1.28 Å. There are thirty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.97 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.97 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. The H(3)-O(3) bond length is 0.97 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(16) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(21) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(28) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(28) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(28) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(29) atom. In the twenty-third H site, H(25) is bonded in a single-bond geometry to one C(29) atom. In the twenty-fourth H site, H(26) is bonded in a single-bond geometry to one C(29) atom. In the twenty-fifth H site, H(27) is bonded in a single-bond geometry to one C(30) atom. In the twenty-sixth H site, H(28) is bonded in a single-bond geometry to one C(30) atom. In the twenty-seventh H site, H(29) is bonded in a single-bond geometry to one C(30) atom. In the twenty-eighth H site, H(30) is bonded in a single-bond geometry to one C(31) atom. In the twenty-ninth H site, H(31) is bonded in a single-bond geometry to one C(32) atom. In the thirtieth H site, H(32) is bonded in a single-bond geometry to one C(34) atom. In the thirty-first H site, H(33) is bonded in a single-bond geometry to one C(35) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one In(3), one In(4), and one H(1) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one In(2), one In(3), and one H(2) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one In(1), one In(2), and one H(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one In(3) and one C(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one In(4) and one C(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one In(2) and one C(15) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one In(1) and one C(15) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one In(3) and one C(18) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one In(2) and one C(18) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one In(1) and one C(19) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one In(2) and one C(19) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one In(4) and one C(33) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one In(3) and one C(33) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one In(3) and one C(36) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one In(2) and one C(36) atom. Linkers: 8 Cc1c(/C=C/C([O])=O)c(C)c(/C=C/C([O])=O)c(C)c1/C=C/C([O])=O. Metal clusters: 12 [In]. The MOF has largest included sphere 8.36 A, density 1.08 g/cm3, surface area 3755.59 m2/g, accessible volume 0.54 cm3/g