Zn2C19N2H14O9CH2(CH)2CH3CHO is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, one 02329_fluka molecule, one dimethyl ether molecule, and one Zn2C19N2H14O9 cluster. In the Zn2C19N2H14O9 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a square pyramidal geometry to one N(2), one O(10), one O(4), one O(6), and one O(8) atom. The Zn(1)-N(2) bond length is 2.06 Å. The Zn(1)-O(10) bond length is 2.05 Å. The Zn(1)-O(4) bond length is 2.09 Å. The Zn(1)-O(6) bond length is 2.05 Å. The Zn(1)-O(8) bond length is 2.06 Å. In the second Zn site, Zn(2) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one O(3), one O(5), one O(7), and one O(9) atom. The Zn(2)-N(1) bond length is 2.07 Å. The Zn(2)-O(3) bond length is 2.05 Å. The Zn(2)-O(5) bond length is 2.07 Å. The Zn(2)-O(7) bond length is 2.08 Å. The Zn(2)-O(9) bond length is 2.06 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(14), one C(2), and one N(1) atom. The C(1)-C(14) bond length is 1.50 Å. The C(1)-C(2) bond length is 1.41 Å. The C(1)-N(1) bond length is 1.35 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(3) atom. The C(2)-C(11) bond length is 1.52 Å. The C(2)-C(3) bond length is 1.41 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(8) bond length is 1.49 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(4)-H(1) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(2) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one N(2) and one H(3) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(4) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(4) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(9)-H(5) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(6) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted water-like geometry to one C(2), one H(7), and one O(1) atom. The C(11)-H(7) bond length is 1.11 Å. The C(11)-O(1) bond length is 1.44 Å. In the twelfth C site, C(14) is bonded in a distorted water-like geometry to one C(1), one H(11), and one H(12) atom. The C(14)-H(11) bond length is 1.11 Å. The C(14)-H(12) bond length is 1.10 Å. In the thirteenth C site, C(15) is bonded in a tetrahedral geometry to one H(13), one H(14), one H(15), and one O(1) atom. The C(15)-H(13) bond length is 1.10 Å. The C(15)-H(14) bond length is 1.10 Å. The C(15)-H(15) bond length is 1.10 Å. The C(15)-O(1) bond length is 1.44 Å. In the fourteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(3), and one O(4) atom. The C(17)-C(18) bond length is 1.48 Å. The C(17)-O(3) bond length is 1.28 Å. The C(17)-O(4) bond length is 1.27 Å. In the fifteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(19) atom. The C(18)-C(19) bond length is 1.34 Å. The C(18)-H(19) bond length is 1.09 Å. In the sixteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(20) atom. The C(19)-H(20) bond length is 1.09 Å. In the seventeenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(20)-O(5) bond length is 1.27 Å. The C(20)-O(6) bond length is 1.28 Å. In the eighteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(21)-O(7) bond length is 1.27 Å. The C(21)-O(8) bond length is 1.28 Å. In the nineteenth C site, C(24) is bonded in a bent 120 degrees geometry to one O(10) and one O(9) atom. The C(24)-O(10) bond length is 1.27 Å. The C(24)-O(9) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(6) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(19) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(11) and one C(15) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(17) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. In the fourth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(20) atom. In the fifth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(20) atom. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(21) atom. In the seventh O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(21) atom. In the eighth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(24) atom. In the ninth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(24) atom. Linkers: 1 CO[C@H]1CCc2nccc(-c3ccncc3)c2[C@H]1OC ,2 [O]C(=O)/C=C/C([O])=O. Metal clusters: 1 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 5.41 A, density 1.06 g/cm3, surface area 4400.94 m2/g, accessible volume 0.54 cm3/g