CHAgC8NH3(OCl)2 crystallizes in the monoclinic C2/c space group. The structure consists of eight 02329_fluka molecules inside a AgC8NH3(OCl)2 framework. In the AgC8NH3(OCl)2 framework, Ag(1) is bonded to one N(1), one O(1), and two equivalent O(2) atoms to form distorted edge-sharing AgNO3 trigonal pyramids. The Ag(1)-N(1) bond length is 2.24 Å. The Ag(1)-O(1) bond length is 2.50 Å. There is one shorter (2.32 Å) and one longer (2.38 Å) Ag(1)-O(2) bond length. There are eight inequivalent C sites. In the first C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. The C(7)-C(6) bond length is 1.52 Å. The C(7)-C(8) bond length is 1.40 Å. The C(7)-C(9) bond length is 1.40 Å. In the second C site, C(8) is bonded in a trigonal planar geometry to one C(7), one C(9), and one Cl(1) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-Cl(1) bond length is 1.73 Å. In the third C site, C(1) is bonded in a distorted trigonal planar geometry to one C(1), one C(2), and one N(1) atom. The C(1)-C(1) bond length is 1.49 Å. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.35 Å. In the fourth C site, C(9) is bonded in a trigonal planar geometry to one C(7), one C(8), and one Cl(2) atom. The C(9)-Cl(2) bond length is 1.72 Å. In the fifth C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the sixth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the seventh C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the eighth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.25 Å. The C(6)-O(2) bond length is 1.28 Å. N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one C(6) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one C(6) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(8) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(9) atom. Linkers: 2 c1ccc(-c2ccccn2)nc1 ,2 [O]C(=O)c1c(Cl)c(Cl)c(C([O])=O)c(Cl)c1Cl. Metal clusters: 4 [Ag]. The MOF has largest included sphere 2.75 A, density 2.19 g/cm3, surface area 3237.53 m2/g, accessible volume 0.10 cm3/g