ZnC20H14(NO)4(CH3)2(CH)2 is Indium-derived structured and crystallizes in the tetragonal P4nc space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, eight 02329_fluka molecules, and four ZnC20H14(NO)4 clusters. In each ZnC20H14(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(2) atoms. Both Zn(1)-N(1) bond lengths are 2.00 Å. Both Zn(1)-O(2) bond lengths are 1.98 Å. There are ten inequivalent C sites. In the first C site, C(6) is bonded in a distorted single-bond geometry to one N(2) atom. The C(6)-N(2) bond length is 1.43 Å. In the second C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(8) bond length is 1.09 Å. In the third C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(9) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(9) bond length is 1.09 Å. In the fourth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(12) bond length is 1.50 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(10) atom. The C(10)-H(10) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(1), and one O(2) atom. The C(12)-O(1) bond length is 1.25 Å. The C(12)-O(2) bond length is 1.30 Å. In the seventh C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-N(1) bond length is 1.38 Å. The C(1)-H(1) bond length is 1.08 Å. In the eighth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(2), and one H(2) atom. The C(2)-N(2) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.08 Å. In the ninth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one N(2) atom. The C(3)-C(4) bond length is 1.49 Å. The C(3)-N(1) bond length is 1.34 Å. The C(3)-N(2) bond length is 1.37 Å. In the tenth C site, C(4) is bonded in a distorted water-like geometry to one C(3), one H(3), and one H(4) atom. The C(4)-H(3) bond length is 1.10 Å. The C(4)-H(4) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(6) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(12) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(12) atom. Linkers: 8 CCc1nccn1-c1ccc(C([O])=O)cc1. Metal clusters: 4 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 5.34 A, density 1.18 g/cm3, surface area 5218.33 m2/g, accessible volume 0.33 cm3/g