(CH)2CH2CuC12H10I(N3O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 02329_fluka molecules, and one CuC12H10I(N3O)2 cluster. In the CuC12H10I(N3O)2 cluster, Cu(1) is bonded to one N(1), one N(6), and two equivalent I(1) atoms to form distorted edge-sharing CuI2N2 tetrahedra. The Cu(1)-N(1) bond length is 2.03 Å. The Cu(1)-N(6) bond length is 2.03 Å. There is one shorter (2.64 Å) and one longer (2.65 Å) Cu(1)-I(1) bond length. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one N(3) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-N(3) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4,11) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4,11) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one N(1) atom. The C(6)-N(1) bond length is 1.38 Å. In the fifth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(6), and one O(1) atom. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. The C(7)-O(1) bond length is 1.47 Å. In the sixth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one H(10), one H(9), and one O(2) atom. The C(9)-H(10) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. The C(9)-O(2) bond length is 1.47 Å. In the seventh C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(15), and one N(6) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.41 Å. The C(10)-N(6) bond length is 1.39 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(4,11) atom. The C(11)-H(4,11) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(12) atom. The C(12)-C(13) bond length is 1.42 Å. The C(12)-H(12) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(13) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(13) bond length is 1.09 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(14) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(14) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one N(4) atom. The C(15)-N(4) bond length is 1.37 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(6), and one N(2) atom. The N(1)-N(2) bond length is 1.32 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.35 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(1), one N(2), and one O(1) atom. The N(3)-O(1) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(15), one N(5), and one O(2) atom. The N(4)-N(5) bond length is 1.34 Å. The N(4)-O(2) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.32 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(10), and one N(5) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4,11) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(7) and one N(3) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(9) and one N(4) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 2 [c]1ccc2nnn(OCCCOn3nnc4ccccc43)c2c1 ,2 c1ccc2c(c1)nnn2OCCCOn1nnc2ccccc21. Metal clusters: 1 I[Cu][Cu]I. The MOF has largest included sphere 2.01 A, density 1.98 g/cm3, surface area 3733.86 m2/g, accessible volume 0.09 cm3/g