ZnC12N4H10O is Indium-like structured and crystallizes in the tetragonal P4_322 space group. The structure is zero-dimensional and consists of four ZnC12N4H10O clusters. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(1), one N(2), one O(1), and one O(2) atom to form distorted corner-sharing ZnN2O2 trigonal pyramids. The Zn(1)-N(1) bond length is 2.27 Å. The Zn(1)-N(2) bond length is 2.17 Å. The Zn(1)-O(1) bond length is 1.90 Å. The Zn(1)-O(2) bond length is 1.88 Å. In the second Zn site, Zn(2) is bonded to two equivalent N(3) and two equivalent O(1) atoms to form distorted corner-sharing ZnN2O2 trigonal pyramids. Both Zn(2)-N(3) bond lengths are 2.20 Å. Both Zn(2)-O(1) bond lengths are 1.89 Å. In the third Zn site, Zn(3) is bonded to two equivalent N(5) and two equivalent O(2) atoms to form distorted corner-sharing ZnN2O2 tetrahedra. Both Zn(3)-N(5) bond lengths are 2.18 Å. Both Zn(3)-O(2) bond lengths are 1.90 Å. There are twenty-four inequivalent C sites. In the first C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(6), and one H(9) atom. The C(11)-C(8) bond length is 1.37 Å. The C(11)-N(6) bond length is 1.39 Å. The C(11)-H(9) bond length is 1.08 Å. In the second C site, C(12) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one N(6) atom. The C(12)-C(18) bond length is 1.40 Å. The C(12)-C(20) bond length is 1.40 Å. The C(12)-N(6) bond length is 1.41 Å. In the third C site, C(13) is bonded in a distorted single-bond geometry to one C(15) and one H(10) atom. The C(13)-C(15) bond length is 1.40 Å. The C(13)-H(10) bond length is 1.09 Å. In the fourth C site, C(14) is bonded in a trigonal planar geometry to one N(2), one N(6), and one H(11) atom. The C(14)-N(2) bond length is 1.32 Å. The C(14)-N(6) bond length is 1.37 Å. The C(14)-H(11) bond length is 1.09 Å. In the fifth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(13), one C(17), and one N(4) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-N(4) bond length is 1.41 Å. In the sixth C site, C(16) is bonded in a distorted single-bond geometry to one C(1) and one H(12,20) atom. The C(16)-C(1) bond length is 1.40 Å. The C(16)-H(12,20) bond length is 1.09 Å. In the seventh C site, C(1) is bonded in a distorted trigonal planar geometry to one C(16), one C(24), and one N(8) atom. The C(1)-C(24) bond length is 1.40 Å. The C(1)-N(8) bond length is 1.41 Å. In the eighth C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one H(13) atom. The C(17)-H(13) bond length is 1.09 Å. In the ninth C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(7), and one H(1) atom. The C(2)-N(1) bond length is 1.32 Å. The C(2)-N(7) bond length is 1.38 Å. The C(2)-H(1) bond length is 1.09 Å. In the tenth C site, C(18) is bonded in a distorted single-bond geometry to one C(12) and one H(14,16) atom. The C(18)-H(14,16) bond length is 1.09 Å. In the eleventh C site, C(3) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(2) atom. The C(3)-N(3) bond length is 1.32 Å. The C(3)-N(4) bond length is 1.38 Å. The C(3)-H(2) bond length is 1.08 Å. In the twelfth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(4), and one H(15) atom. The C(19)-C(4) bond length is 1.37 Å. The C(19)-N(4) bond length is 1.39 Å. The C(19)-H(15) bond length is 1.08 Å. In the thirteenth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(3), and one H(3) atom. The C(4)-N(3) bond length is 1.38 Å. The C(4)-H(3) bond length is 1.08 Å. In the fourteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(12) and one H(14,16) atom. The C(20)-H(14,16) bond length is 1.09 Å. In the fifteenth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4,18) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4,18) bond length is 1.09 Å. In the sixteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(23), one N(8), and one H(17) atom. The C(21)-C(23) bond length is 1.37 Å. The C(21)-N(8) bond length is 1.39 Å. The C(21)-H(17) bond length is 1.08 Å. In the seventeenth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(22), one C(5), and one N(7) atom. The C(6)-C(22) bond length is 1.40 Å. The C(6)-N(7) bond length is 1.41 Å. In the eighteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(6) and one H(4,18) atom. The C(22)-H(4,18) bond length is 1.09 Å. In the nineteenth C site, C(7) is bonded in a trigonal planar geometry to one N(5), one N(8), and one H(5) atom. The C(7)-N(5) bond length is 1.32 Å. The C(7)-N(8) bond length is 1.37 Å. The C(7)-H(5) bond length is 1.09 Å. In the twentieth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(7), and one H(8) atom. The C(10)-C(9) bond length is 1.37 Å. The C(10)-N(7) bond length is 1.39 Å. The C(10)-H(8) bond length is 1.08 Å. In the twenty-first C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(5), and one H(19) atom. The C(23)-N(5) bond length is 1.38 Å. The C(23)-H(19) bond length is 1.08 Å. In the twenty-second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(2), and one H(6) atom. The C(8)-N(2) bond length is 1.38 Å. The C(8)-H(6) bond length is 1.08 Å. In the twenty-third C site, C(24) is bonded in a distorted single-bond geometry to one C(1) and one H(12,20) atom. The C(24)-H(12,20) bond length is 1.09 Å. In the twenty-fourth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(1), and one H(7) atom. The C(9)-N(1) bond length is 1.38 Å. The C(9)-H(7) bond length is 1.08 Å. There are eight inequivalent N sites. In the first N site, N(3) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(3), and one C(4) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(3) atom. In the third N site, N(5) is bonded in a distorted trigonal non-coplanar geometry to one Zn(3), one C(23), and one C(7) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(14) atom. In the fifth N site, N(7) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(6) atom. In the sixth N site, N(8) is bonded in a trigonal planar geometry to one C(1), one C(21), and one C(7) atom. In the seventh N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(14), and one C(8) atom. In the eighth N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one C(2), and one C(9) atom. There are seventeen inequivalent H sites. In the first H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the fourth H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(4,18) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the thirteenth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the fourteenth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the fifteenth H site, H(12,20) is bonded in a single-bond geometry to one C(16) atom. In the sixteenth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the seventeenth H site, H(14,16) is bonded in a single-bond geometry to one C(18) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Zn(1) and one Zn(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one Zn(3) atom. Linkers: 16 c1cn(-c2ccc(-n3ccnc3)cc2)cn1. Metal clusters: 4 O1[Zn]O[Zn]O[Zn]O[Zn]1. The MOF has largest included sphere 3.91 A, density 1.42 g/cm3, surface area 4536.62 m2/g, accessible volume 0.25 cm3/g