CuC7H8(NCl)2CH is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one CuC7H8(NCl)2 cluster. In the CuC7H8(NCl)2 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one Cl(1), and two equivalent Cl(2) atoms. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-Cl(1) bond length is 2.22 Å. There is one shorter (2.36 Å) and one longer (2.57 Å) Cu(1)-Cl(2) bond length. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.46 Å. The C(1)-N(1) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(2), and one H(5) atom. The C(6)-N(2) bond length is 1.31 Å. The C(6)-H(5) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(6), and one H(7) atom. The C(7)-N(2) bond length is 1.46 Å. The C(7)-H(6) bond length is 1.10 Å. The C(7)-H(7) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(8), and one H(9) atom. The C(8)-N(2) bond length is 1.46 Å. The C(8)-H(8) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(6), one C(7), and one C(8) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to two equivalent Cu(1) atoms. Linkers: 1 [CH](c1ccccn1)N1CCN([CH]c2ccccn2)CC1. Metal clusters: 1 Cl[Cu]Cl.Cl[Cu]Cl. The MOF has largest included sphere 2.61 A, density 1.80 g/cm3, surface area 4021.06 m2/g, accessible volume 0.12 cm3/g