CuC9H7(NO)4CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one CuC9H7(NO)4 cluster. In the CuC9H7(NO)4 cluster, Cu(1) is bonded in a trigonal bipyramidal geometry to one N(2), one N(3), one O(1), one O(3), and one O(4) atom. The Cu(1)-N(2) bond length is 1.97 Å. The Cu(1)-N(3) bond length is 2.00 Å. The Cu(1)-O(1) bond length is 2.01 Å. The Cu(1)-O(3) bond length is 1.98 Å. The Cu(1)-O(4) bond length is 2.26 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(3) is bonded in a single-bond geometry to one C(4), one C(7), and one H(5) atom. The C(3)-C(4) bond length is 1.49 Å. The C(3)-C(7) bond length is 1.49 Å. The C(3)-H(5) bond length is 1.10 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one N(2) atom. The C(4)-N(1) bond length is 1.36 Å. The C(4)-N(2) bond length is 1.34 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one H(6) atom. The C(5)-C(6) bond length is 1.37 Å. The C(5)-N(1) bond length is 1.38 Å. The C(5)-H(6) bond length is 1.08 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(2), and one H(7) atom. The C(6)-N(2) bond length is 1.38 Å. The C(6)-H(7) bond length is 1.08 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(3), one N(3), and one N(4) atom. The C(7)-N(3) bond length is 1.33 Å. The C(7)-N(4) bond length is 1.36 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(3), and one H(8) atom. The C(8)-C(9) bond length is 1.37 Å. The C(8)-N(3) bond length is 1.39 Å. The C(8)-H(8) bond length is 1.08 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(4), and one H(9) atom. The C(9)-N(4) bond length is 1.38 Å. The C(9)-H(9) bond length is 1.08 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(10)-O(3) bond length is 1.28 Å. The C(10)-O(4) bond length is 1.26 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(4), one C(5), and one H(1) atom. The N(1)-H(1) bond length is 1.04 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(4), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(7), and one C(8) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(7), one C(9), and one H(2) atom. The N(4)-H(2) bond length is 1.02 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(10) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cu(1) and one C(10) atom. Linkers: 2 [O]C(=O)CC(c1ncc[nH]1)c1ncc[nH]1. Metal clusters: 1 O=[C]O[Cu]1OC2=C(O1)O[Cu](O[C]=O)O2. The MOF has largest included sphere 3.91 A, density 1.58 g/cm3, surface area 3986.25 m2/g, accessible volume 0.16 cm3/g