ZnC18NH14O4C4H5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two isobutylene molecules and one ZnC18NH14O4 cluster. In the ZnC18NH14O4 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 2.05 Å. The Zn(1)-O(2) bond length is 2.06 Å. The Zn(1)-O(3) bond length is 2.09 Å. The Zn(1)-O(4) bond length is 2.08 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.45 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(1), and one O(2) atom. The C(7)-C(8) bond length is 1.49 Å. The C(7)-O(1) bond length is 1.28 Å. The C(7)-O(2) bond length is 1.28 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(7), and one C(9) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(9)-H(6) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(9) atom. The C(13)-H(9) bond length is 1.09 Å. In the eleventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(3), and one O(4) atom. The C(15)-C(16) bond length is 1.50 Å. The C(15)-O(3) bond length is 1.28 Å. The C(15)-O(4) bond length is 1.28 Å. In the twelfth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.40 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(13) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(13) bond length is 1.09 Å. In the fourteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(14) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-H(14) bond length is 1.09 Å. In the fifteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(22) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-C(22) bond length is 1.50 Å. In the sixteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(15) atom. The C(20)-H(15) bond length is 1.09 Å. In the seventeenth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(16) atom. The C(21)-H(16) bond length is 1.09 Å. In the eighteenth C site, C(22) is bonded in a distorted trigonal non-coplanar geometry to one C(19), one H(17), one H(18), and one H(19) atom. The C(22)-H(17) bond length is 1.10 Å. The C(22)-H(18) bond length is 1.10 Å. The C(22)-H(19) bond length is 1.10 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(22) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(15) atom. Linkers: 1 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.35 A, density 1.47 g/cm3, surface area 5001.68 m2/g, accessible volume 0.16 cm3/g