TiC14H10(NO2)2(CH)8 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules, two propylene molecules, and two TiC14H10(NO2)2 clusters. In one of the TiC14H10(NO2)2 clusters, Ti(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(3) atoms. Both Ti(1)-N(1) bond lengths are 2.21 Å. Both Ti(1)-O(1) bond lengths are 1.90 Å. Both Ti(1)-O(3) bond lengths are 1.90 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one O(1) atom. The C(1)-O(1) bond length is 1.33 Å. In the second C site, C(17) is bonded in a distorted single-bond geometry to one O(3) atom. The C(17)-O(3) bond length is 1.34 Å. In the third C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(1), and one H(5) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-N(1) bond length is 1.35 Å. The C(7)-H(5) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(6) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(6) bond length is 1.09 Å. In the fifth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(7) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(7) bond length is 1.09 Å. In the sixth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(8) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(8) bond length is 1.09 Å. In the seventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(9) atom. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(9) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Ti(1), one C(11), and one C(7) atom. There are five inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a bent 150 degrees geometry to one Ti(1) and one C(17) atom. In the second O site, O(1) is bonded in a bent 150 degrees geometry to one Ti(1) and one C(1) atom. In one of the TiC14H10(NO2)2 clusters, Ti(2) is bonded in an octahedral geometry to two equivalent N(2), two equivalent O(2), and two equivalent O(4) atoms. Both Ti(2)-N(2) bond lengths are 2.22 Å. Both Ti(2)-O(2) bond lengths are 1.90 Å. Both Ti(2)-O(4) bond lengths are 1.91 Å. There are seven inequivalent C sites. In the first C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(12) atom. The C(14)-C(13) bond length is 1.40 Å. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(12) bond length is 1.09 Å. In the second C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(13) atom. The C(15)-H(13) bond length is 1.09 Å. In the third C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(14) atom. The C(16)-N(2) bond length is 1.35 Å. The C(16)-H(14) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one O(2) atom. The C(5)-O(2) bond length is 1.34 Å. In the fifth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one N(2), and one H(10) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(10) bond length is 1.09 Å. In the sixth C site, C(21) is bonded in a distorted single-bond geometry to one O(4) atom. The C(21)-O(4) bond length is 1.34 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(11) atom. The C(13)-H(11) bond length is 1.09 Å. N(2) is bonded in a trigonal planar geometry to one Ti(2), one C(12), and one C(16) atom. There are five inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. There are two inequivalent O sites. In the first O site, O(4) is bonded in a bent 150 degrees geometry to one Ti(2) and one C(21) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Ti(2) and one C(5) atom. Linkers: 4 [O]c1cccc([O])c1. Metal clusters: 2 [O][Ti]([O])([O])=O. RCSR code: sql. The MOF has largest included sphere 1.94 A, density 1.49 g/cm3, surface area 5086.15 m2/g, accessible volume 0.15 cm3/g