Zn2C25H29(NO4)3CH2CO crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of four dimethyl ether molecules inside a Zn2C25H29(NO4)3 framework. In the Zn2C25H29(NO4)3 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(7), and one O(9) atom. The Zn(1)-O(2) bond length is 1.99 Å. The Zn(1)-O(3) bond length is 2.03 Å. The Zn(1)-O(7) bond length is 1.98 Å. The Zn(1)-O(9) bond length is 1.99 Å. In the second Zn site, Zn(2) is bonded in an octahedral geometry to one O(1), one O(10), one O(11), one O(12), one O(13), and one O(4) atom. The Zn(2)-O(1) bond length is 2.11 Å. The Zn(2)-O(10) bond length is 2.06 Å. The Zn(2)-O(11) bond length is 2.11 Å. The Zn(2)-O(12) bond length is 2.12 Å. The Zn(2)-O(13) bond length is 2.15 Å. The Zn(2)-O(4) bond length is 2.07 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one O(5) atom. The C(4)-O(5) bond length is 1.36 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(2) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(2) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-C(8) bond length is 1.51 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(3) atom. The C(7)-H(3) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.28 Å. The C(8)-O(4) bond length is 1.27 Å. In the ninth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one H(4), one H(5), and one O(5) atom. The C(9)-H(4) bond length is 1.10 Å. The C(9)-H(5) bond length is 1.10 Å. The C(9)-O(5) bond length is 1.43 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(8) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(8) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(18) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(18) bond length is 1.50 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(9) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(17) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(17) bond length is 1.51 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(10) atom. The C(16)-H(10) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(7), and one O(8) atom. The C(17)-O(7) bond length is 1.30 Å. The C(17)-O(8) bond length is 1.25 Å. In the sixteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(10), and one O(9) atom. The C(18)-O(10) bond length is 1.27 Å. The C(18)-O(9) bond length is 1.28 Å. In the seventeenth C site, C(19) is bonded in a trigonal planar geometry to one N(1), one H(11), and one O(11) atom. The C(19)-N(1) bond length is 1.33 Å. The C(19)-H(11) bond length is 1.10 Å. The C(19)-O(11) bond length is 1.26 Å. In the eighteenth C site, C(20) is bonded to one N(1), one H(12), one H(13), and one H(14) atom to form corner-sharing CH3N tetrahedra. The C(20)-N(1) bond length is 1.46 Å. The C(20)-H(12) bond length is 1.10 Å. The C(20)-H(13) bond length is 1.09 Å. The C(20)-H(14) bond length is 1.10 Å. In the nineteenth C site, C(21) is bonded to one N(1), one H(15), one H(16), and one H(17) atom to form corner-sharing CH3N tetrahedra. The C(21)-N(1) bond length is 1.45 Å. The C(21)-H(15) bond length is 1.10 Å. The C(21)-H(16) bond length is 1.10 Å. The C(21)-H(17) bond length is 1.10 Å. In the twentieth C site, C(22) is bonded in a trigonal planar geometry to one N(2), one H(18), and one O(12) atom. The C(22)-N(2) bond length is 1.34 Å. The C(22)-H(18) bond length is 1.10 Å. The C(22)-O(12) bond length is 1.25 Å. In the twenty-first C site, C(23) is bonded to one N(2), one H(19), one H(20), and one H(21) atom to form corner-sharing CH3N tetrahedra. The C(23)-N(2) bond length is 1.46 Å. The C(23)-H(19) bond length is 1.09 Å. The C(23)-H(20) bond length is 1.10 Å. The C(23)-H(21) bond length is 1.10 Å. In the twenty-second C site, C(24) is bonded to one N(2), one H(22), one H(23), and one H(24) atom to form corner-sharing CH3N tetrahedra. The C(24)-N(2) bond length is 1.46 Å. The C(24)-H(22) bond length is 1.10 Å. The C(24)-H(23) bond length is 1.10 Å. The C(24)-H(24) bond length is 1.10 Å. In the twenty-third C site, C(25) is bonded in a trigonal planar geometry to one N(3), one H(25), and one O(13) atom. The C(25)-N(3) bond length is 1.34 Å. The C(25)-H(25) bond length is 1.10 Å. The C(25)-O(13) bond length is 1.25 Å. In the twenty-fourth C site, C(26,27) is bonded to one N(3), one H(26), one H(27), and one H(28) atom to form corner-sharing CH3N tetrahedra. The C(26,27)-N(3) bond length is 1.45 Å. The C(26,27)-H(26) bond length is 1.10 Å. The C(26,27)-H(27) bond length is 1.10 Å. The C(26,27)-H(28) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one C(25) and two equivalent C(26,27) atoms. In the second N site, N(1) is bonded in a trigonal planar geometry to one C(19), one C(20), and one C(21) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one C(22), one C(23), and one C(24) atom. There are twenty-nine inequivalent H sites. In the first H site, H(31) is bonded in a single-bond geometry to one C(26,27) atom. The H(31)-C(26,27) bond length is 1.09 Å. In the second H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(23) atom. In the twentieth H site, H(21) is bonded in a single-bond geometry to one C(23) atom. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one C(24) atom. In the twenty-second H site, H(23) is bonded in a single-bond geometry to one C(24) atom. In the twenty-third H site, H(24) is bonded in a single-bond geometry to one C(24) atom. In the twenty-fourth H site, H(25) is bonded in a single-bond geometry to one C(25) atom. In the twenty-fifth H site, H(26) is bonded in a single-bond geometry to one C(26,27) atom. In the twenty-sixth H site, H(27) is bonded in a single-bond geometry to one C(26,27) atom. In the twenty-seventh H site, H(28) is bonded in a single-bond geometry to one C(26,27) atom. In the twenty-eighth H site, H(29) is bonded in a single-bond geometry to one C(26,27) atom. The H(29)-C(26,27) bond length is 1.10 Å. In the twenty-ninth H site, H(30) is bonded in a single-bond geometry to one C(26,27) atom. The H(30)-C(26,27) bond length is 1.10 Å. There are twelve inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the third O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(8) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one C(4) and one C(9) atom. In the fifth O site, O(7) is bonded in a water-like geometry to one Zn(1) and one C(17) atom. In the sixth O site, O(8) is bonded in a single-bond geometry to one C(17) atom. In the seventh O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(18) atom. In the eighth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(18) atom. In the ninth O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(19) atom. In the tenth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(22) atom. In the eleventh O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(25) atom. In the twelfth O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. Linkers: 4 [O]C(=O)c1cc(OCCOc2cc(C([O])=O)cc(C([O])=O)c2)cc(C([O])=O)c1. Metal clusters: 8 [Zn]. The MOF has largest included sphere 4.57 A, density 1.40 g/cm3, surface area 4693.31 m2/g, accessible volume 0.26 cm3/g