AgC10NH12S2O3(CH)2(CH2)4 crystallizes in the orthorhombic Pna2_1 space group. The structure consists of eight 02329_fluka molecules and sixteen 02329_fluka molecules inside a AgC10NH12S2O3 framework. In the AgC10NH12S2O3 framework, Ag(1) is bonded in a 5-coordinate geometry to one S(1), one S(2), one O(2), and two equivalent O(1) atoms. The Ag(1)-S(1) bond length is 2.50 Å. The Ag(1)-S(2) bond length is 2.44 Å. The Ag(1)-O(2) bond length is 2.62 Å. There is one shorter (2.40 Å) and one longer (2.81 Å) Ag(1)-O(1) bond length. There are ten inequivalent C sites. In the first C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.41 Å. The C(10)-C(9) bond length is 1.49 Å. In the second C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(17) atom. The C(11)-H(17) bond length is 1.09 Å. In the third C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(18) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(18) bond length is 1.09 Å. In the fourth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(16) bond length is 1.50 Å. In the fifth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(19) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(19) bond length is 1.09 Å. In the sixth C site, C(15) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one H(20) atom. The C(15)-H(20) bond length is 1.09 Å. In the seventh C site, C(16) is bonded in a distorted water-like geometry to one C(13), one H(21), one H(22), and one S(1) atom. The C(16)-H(21) bond length is 1.10 Å. The C(16)-H(22) bond length is 1.10 Å. The C(16)-S(1) bond length is 1.85 Å. In the eighth C site, C(1) is bonded in a distorted water-like geometry to one H(1), one H(2), and one S(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.83 Å. In the ninth C site, C(8) is bonded in a distorted water-like geometry to one H(13), one H(14), and one S(2) atom. The C(8)-H(13) bond length is 1.10 Å. The C(8)-H(14) bond length is 1.10 Å. The C(8)-S(2) bond length is 1.84 Å. In the tenth C site, C(9) is bonded in a distorted water-like geometry to one C(10), one H(15), one H(16), and one S(2) atom. The C(9)-H(15) bond length is 1.10 Å. The C(9)-H(16) bond length is 1.10 Å. The C(9)-S(2) bond length is 1.84 Å. N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(1)-O(1) bond length is 1.29 Å. The N(1)-O(2) bond length is 1.27 Å. The N(1)-O(3) bond length is 1.25 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(16) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(1), and one C(16) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(8), and one C(9) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. Linkers: 4 c1cc2ccc1CSC[C@H]1CC[C@H](CC1)CSC2. Metal clusters: 4 [Ag]. The MOF has largest included sphere 5.04 A, density 1.40 g/cm3, surface area 4223.60 m2/g, accessible volume 0.24 cm3/g