AgC13N7H12 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AgC13N7H12 clusters. Ag(1) is bonded to one N(2), one N(5), and two equivalent N(4) atoms to form distorted edge-sharing AgN4 trigonal pyramids. The Ag(1)-N(2) bond length is 2.17 Å. The Ag(1)-N(5) bond length is 2.18 Å. There is one shorter (2.49 Å) and one longer (2.54 Å) Ag(1)-N(4) bond length. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(1) atom. The C(1)-N(2) bond length is 1.33 Å. The C(1)-N(3) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(3) atom. The C(2)-C(10) bond length is 1.40 Å. The C(2)-C(11) bond length is 1.51 Å. The C(2)-C(3) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2,8) atom. The C(3)-H(2,8) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(4)-C(6) bond length is 1.40 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(2), and one H(4) atom. The C(5)-C(7) bond length is 1.38 Å. The C(5)-N(2) bond length is 1.39 Å. The C(5)-H(4) bond length is 1.08 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(4), one C(9), and one N(1) atom. The C(6)-C(9) bond length is 1.39 Å. The C(6)-N(1) bond length is 1.42 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(3), and one H(5) atom. The C(7)-N(3) bond length is 1.38 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(1), one N(5), and one H(6) atom. The C(8)-N(1) bond length is 1.37 Å. The C(8)-N(5) bond length is 1.33 Å. The C(8)-H(6) bond length is 1.08 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(6) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(2) and one H(2,8) atom. The C(10)-H(2,8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one N(3), one H(10), and one H(9) atom. The C(11)-N(3) bond length is 1.46 Å. The C(11)-H(10) bond length is 1.10 Å. The C(11)-H(9) bond length is 1.10 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(1), and one H(11) atom. The C(12)-C(13) bond length is 1.37 Å. The C(12)-N(1) bond length is 1.39 Å. The C(12)-H(11) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(5), and one H(12) atom. The C(13)-N(5) bond length is 1.38 Å. The C(13)-H(12) bond length is 1.09 Å. There are seven inequivalent N sites. In the first N site, N(7) is bonded in a single-bond geometry to one N(6) atom. The N(7)-N(6) bond length is 1.18 Å. In the second N site, N(1) is bonded in a trigonal planar geometry to one C(12), one C(6), and one C(8) atom. In the third N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(7) atom. In the fifth N site, N(4) is bonded in a distorted trigonal planar geometry to two equivalent Ag(1) and one N(6) atom. The N(4)-N(6) bond length is 1.20 Å. In the sixth N site, N(5) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(13), and one C(8) atom. In the seventh N site, N(6) is bonded in a linear geometry to one N(4) and one N(7) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2,8) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(13) atom. Linkers: 4 c1cn(Cc2ccc(-n3ccnc3)cc2)cn1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 2.12 A, density 1.81 g/cm3, surface area 4101.33 m2/g, accessible volume 0.10 cm3/g