Ag3C31N6H21O5(CH)3(CO2)2(CF3)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, four formic acid molecules, six trifluoromethane molecules, and one Ag3C31N6H21O5 cluster. In the Ag3C31N6H21O5 cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(1,3) is bonded in a 2-coordinate geometry to one N(1,3) and one N(6) atom. The Ag(1,3)-N(1,3) bond length is 2.16 Å. The Ag(1,3)-N(6) bond length is 2.16 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one N(2), one N(4), and one O(5) atom. The Ag(2)-N(2) bond length is 2.16 Å. The Ag(2)-N(4) bond length is 2.16 Å. The Ag(2)-O(5) bond length is 2.67 Å. There are eighteen inequivalent C sites. In the first C site, C(1,3) is bonded in a distorted trigonal planar geometry to one N(1,3) and one H(1,3) atom. The C(1,3)-N(1,3) bond length is 1.35 Å. The C(1,3)-H(1,3) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(2) and one H(2) atom. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(7,8,9) is bonded in a distorted single-bond geometry to one C(10,12) and one H(7,8,9) atom. The C(7,8,9)-C(10,12) bond length is 1.40 Å. The C(7,8,9)-H(7,8,9) bond length is 1.09 Å. In the fourth C site, C(10,12) is bonded in a trigonal planar geometry to one C(13,15); one C(16,17,18); and one C(7,8,9) atom. The C(10,12)-C(13,15) bond length is 1.40 Å. The C(10,12)-C(16,17,18) bond length is 1.49 Å. In the fifth C site, C(11) is bonded in a trigonal planar geometry to one C(14); one C(16,17,18); and one C(7,8,9) atom. The C(11)-C(14) bond length is 1.40 Å. The C(11)-C(16,17,18) bond length is 1.49 Å. The C(11)-C(7,8,9) bond length is 1.40 Å. In the sixth C site, C(13,15) is bonded in a distorted trigonal planar geometry to one C(10,12); one N(1,3); and one H(10,12) atom. The C(13,15)-N(1,3) bond length is 1.35 Å. The C(13,15)-H(10,12) bond length is 1.09 Å. In the seventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one H(11) atom. The C(14)-N(2) bond length is 1.35 Å. The C(14)-H(11) bond length is 1.09 Å. In the eighth C site, C(16,17,18) is bonded in a single-bond geometry to one C(10,12); one C(19,21); and one O(1,3) atom. The C(16,17,18)-C(19,21) bond length is 1.49 Å. The C(16,17,18)-O(1,3) bond length is 1.23 Å. In the ninth C site, C(19,21) is bonded in a trigonal planar geometry to one C(16,17,18); one C(22,23,24); and one C(31) atom. The C(19,21)-C(22,23,24) bond length is 1.40 Å. The C(19,21)-C(31) bond length is 1.40 Å. In the tenth C site, C(20) is bonded in a trigonal planar geometry to one C(16,17,18); one C(22,23,24); and one C(32,33) atom. The C(20)-C(16,17,18) bond length is 1.49 Å. The C(20)-C(22,23,24) bond length is 1.40 Å. The C(20)-C(32,33) bond length is 1.40 Å. In the eleventh C site, C(22,23,24) is bonded in a distorted single-bond geometry to one C(19,21); one C(25,27); and one H(13,15) atom. The C(22,23,24)-C(25,27) bond length is 1.39 Å. The C(22,23,24)-H(13,15) bond length is 1.09 Å. In the twelfth C site, C(25,27) is bonded in a distorted trigonal planar geometry to one C(22,23,24); one C(28); and one H(16,17,18) atom. The C(25,27)-C(28) bond length is 1.39 Å. The C(25,27)-H(16,17,18) bond length is 1.09 Å. In the thirteenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(22,23,24); one C(29,30); and one H(16,17,18) atom. The C(26)-C(22,23,24) bond length is 1.40 Å. The C(26)-C(29,30) bond length is 1.39 Å. The C(26)-H(16,17,18) bond length is 1.09 Å. In the fourteenth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(25,27); one N(4); and one H(19,20,21) atom. The C(28)-N(4) bond length is 1.35 Å. The C(28)-H(19,20,21) bond length is 1.09 Å. In the fifteenth C site, C(29,30) is bonded in a distorted trigonal planar geometry to one C(26); one N(5); and one H(19,20,21) atom. The C(29,30)-N(5) bond length is 1.35 Å. The C(29,30)-H(19,20,21) bond length is 1.09 Å. In the sixteenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(19,21); one N(4); and one H(22,24) atom. The C(31)-N(4) bond length is 1.34 Å. The C(31)-H(22,24) bond length is 1.09 Å. In the seventeenth C site, C(32,33) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(5), and one H(23) atom. The C(32,33)-N(5) bond length is 1.34 Å. The C(32,33)-H(23) bond length is 1.09 Å. In the eighteenth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(8) atom. The C(35)-O(5) bond length is 1.26 Å. The C(35)-O(8) bond length is 1.25 Å. There are five inequivalent N sites. In the first N site, N(1,3) is bonded in a trigonal planar geometry to one Ag(1,3); one C(1,3); and one C(13,15) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(2), one C(14), and one C(2) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one Ag(2), one C(28), and one C(31) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one Ag(1,3); one C(29,30); and one C(32,33) atom. The N(5)-Ag(1,3) bond length is 2.16 Å. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one Ag(1,3); one C(29,30); and one C(32,33) atom. The N(6)-C(29,30) bond length is 1.35 Å. The N(6)-C(32,33) bond length is 1.34 Å. There are eleven inequivalent H sites. In the first H site, H(1,3) is bonded in a single-bond geometry to one C(1,3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(7,8,9) is bonded in a single-bond geometry to one C(7,8,9) atom. In the fourth H site, H(10,12) is bonded in a single-bond geometry to one C(13,15) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(13,15) is bonded in a single-bond geometry to one C(22,23,24) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(22,23,24) atom. The H(14)-C(22,23,24) bond length is 1.09 Å. In the eighth H site, H(16,17,18) is bonded in a single-bond geometry to one C(25,27) atom. In the ninth H site, H(19,20,21) is bonded in a single-bond geometry to one C(28) atom. In the tenth H site, H(22,24) is bonded in a single-bond geometry to one C(31) atom. In the eleventh H site, H(23) is bonded in a single-bond geometry to one C(32,33) atom. There are four inequivalent O sites. In the first O site, O(1,3) is bonded in a single-bond geometry to one C(16,17,18) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(16,17,18) atom. The O(2)-C(16,17,18) bond length is 1.23 Å. In the third O site, O(5) is bonded in a single-bond geometry to one Ag(2) and one C(35) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one C(35) atom. Linkers: 6 O=C(c1cccnc1)c1cccnc1. Metal clusters: 6 [Ag]. The MOF has largest included sphere 8.96 A, density 1.44 g/cm3, surface area 3746.64 m2/g, accessible volume 0.33 cm3/g