CdC15H11(NO)4(CH)3(CH2)3C2O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, six 02329_fluka molecules, two dimethyl ether molecules, and two CdC15H11(NO)4 clusters. In each CdC15H11(NO)4 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.26 Å. The Cd(1)-N(3) bond length is 2.25 Å. The Cd(1)-O(1) bond length is 2.68 Å. The Cd(1)-O(2) bond length is 2.25 Å. The Cd(1)-O(3) bond length is 2.68 Å. The Cd(1)-O(4) bond length is 2.25 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(1) atom. The C(1)-N(3) bond length is 1.33 Å. The C(1)-N(4) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(3), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(3) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(4), and one H(3) atom. The C(3)-N(4) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one N(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(9) bond length is 1.40 Å. The C(4)-N(4) bond length is 1.42 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(4) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(9) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(9) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one N(2) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-N(2) bond length is 1.42 Å. In the ninth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(10) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(10) bond length is 1.09 Å. In the tenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(15)-H(11) bond length is 1.09 Å. In the eleventh C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(16)-N(2) bond length is 1.39 Å. The C(16)-H(12) bond length is 1.08 Å. In the twelfth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(17)-N(1) bond length is 1.38 Å. The C(17)-H(13) bond length is 1.08 Å. In the thirteenth C site, C(18) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(14) atom. The C(18)-N(1) bond length is 1.33 Å. The C(18)-N(2) bond length is 1.36 Å. The C(18)-H(14) bond length is 1.08 Å. In the fourteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(19)-O(1) bond length is 1.27 Å. The C(19)-O(2) bond length is 1.29 Å. In the fifteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(23)-O(3) bond length is 1.27 Å. The C(23)-O(4) bond length is 1.29 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(17), and one C(18) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(13), one C(16), and one C(18) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cd(1) and one C(19) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1) and one C(19) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cd(1) and one C(23) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Cd(1) and one C(23) atom. Linkers: 2 [O]C(=O)CCCC([O])=O. Metal clusters: 2 O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 2.48 A, density 1.61 g/cm3, surface area 4459.54 m2/g, accessible volume 0.16 cm3/g