AgC12H12(N2O)2(CF)2NO3 crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of four fluoromethane molecules, two nitric acid molecules, and two AgC12H12(N2O)2 clusters. In each AgC12H12(N2O)2 cluster, Ag(1) is bonded in a distorted linear geometry to two equivalent N(1) atoms. Both Ag(1)-N(1) bond lengths are 2.14 Å. There are six inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(2) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-N(2) bond length is 1.39 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(2), and one O(1) atom. The C(6)-C(7) bond length is 1.51 Å. The C(6)-N(2) bond length is 1.38 Å. The C(6)-O(1) bond length is 1.23 Å. In the fifth C site, C(7) is bonded in a distorted water-like geometry to one C(6), one H(5), and one H(6) atom. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. In the sixth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(2) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one C(4), one C(6), and one H(1) atom. The N(2)-H(1) bond length is 1.03 Å. In the second N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. O(1) is bonded in a single-bond geometry to one C(6) atom. Linkers: 2 O=C(CCC(=O)Nc1cncc(F)c1)Nc1cncc(F)c1. Metal clusters: 2 [Ag]. The MOF has largest included sphere 1.94 A, density 1.98 g/cm3, surface area 3996.72 m2/g, accessible volume 0.07 cm3/g