ZnC14H12S2(N3O2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two ZnC14H12S2(N3O2)2 clusters. Zn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent O(2) atoms. Both Zn(1)-N(1) bond lengths are 2.19 Å. Both Zn(1)-N(3) bond lengths are 2.12 Å. Both Zn(1)-O(2) bond lengths are 2.20 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(6) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(5) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.45 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4,5) atom. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(4,5) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4,5) atom. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(4,5) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(1) and one H(6) atom. The C(5)-H(6) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one C(1), one N(2), and one O(1) atom. The C(6)-N(2) bond length is 1.31 Å. The C(6)-O(1) bond length is 1.37 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one N(3), one S(1), and one O(1) atom. The C(7)-N(3) bond length is 1.34 Å. The C(7)-S(1) bond length is 1.67 Å. The C(7)-O(1) bond length is 1.40 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a water-like geometry to one C(6) and one N(3) atom. The N(2)-N(3) bond length is 1.38 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Zn(1), one C(7), and one N(2) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4,5) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. S(1) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(6) and one C(7) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one H(1), and one H(2) atom. Linkers: 2 O.O.[N][N]C(=O)C1=C[CH]N([Zn](N2[CH]C=C(C3=N[N]C(=S)O3)C=C2)(n2nc(-c3ccncc3)oc2=S)n2nc(-c3ccncc3)oc2=S)C=C1 ,2 O.O.[N]/C=C\[C]c1nn([Zn](N2[CH]C=C(C3=N[N]C(=S)O3)C=C2)(N2[CH]C=C(C3=N[N]C(=S)O3)C=C2)n2nc(-c3ccncc3)oc2=S)c(=S)o1 ,1 O.O.S=C1[N]N=C(C2=C[CH]N([Zn](N3[CH]C=C(C4=N[N]C(=S)O4)C=C3)(n3nc(-c4ccncc4)oc3=S)n3nc(-c4ccncc4)oc3=S)C=C2)O1. Metal clusters: 1 O.O.[Zn]. The MOF has largest included sphere 4.45 A, density 1.28 g/cm3, surface area 4348.18 m2/g, accessible volume 0.30 cm3/g