AgC4H8(NO4)2AgC14H12(NO2)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four AgC14H12(NO2)2 clusters and four AgC4H8(NO4)2 clusters. In each AgC14H12(NO2)2 cluster, Ag(2) is bonded in a linear geometry to two equivalent N(1) atoms. Both Ag(2)-N(1) bond lengths are 2.13 Å. There are seven inequivalent C sites. In the first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(3)-C(1) bond length is 1.49 Å. The C(3)-O(1) bond length is 1.34 Å. The C(3)-O(2) bond length is 1.23 Å. In the second C site, C(5) is bonded in a distorted single-bond geometry to one C(1), one C(7), and one H(5) atom. The C(5)-C(1) bond length is 1.40 Å. The C(5)-C(7) bond length is 1.39 Å. The C(5)-H(5) bond length is 1.09 Å. In the third C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one H(6) atom. The C(6)-C(1) bond length is 1.40 Å. The C(6)-N(1) bond length is 1.35 Å. The C(6)-H(6) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one H(7) atom. The C(7)-H(7) bond length is 1.09 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(8)-N(1) bond length is 1.35 Å. The C(8)-H(8) bond length is 1.09 Å. In the sixth C site, C(1) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. In the seventh C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one O(1) atom. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. The C(2)-O(1) bond length is 1.46 Å. N(1) is bonded in a trigonal planar geometry to one Ag(2), one C(6), and one C(8) atom. There are six inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In each AgC4H8(NO4)2 cluster, Ag(1) is bonded in a 4-coordinate geometry to two equivalent O(3) and two equivalent O(4) atoms. Both Ag(1)-O(3) bond lengths are 2.59 Å. Both Ag(1)-O(4) bond lengths are 2.30 Å. There are two inequivalent C sites. In the first C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(4), and one O(3) atom. The C(4)-H(3) bond length is 1.10 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-O(3) bond length is 1.43 Å. In the second C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one H(10), one H(9), and one O(3) atom. The C(9)-H(10) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. The C(9)-O(3) bond length is 1.44 Å. N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. The N(2)-O(4) bond length is 1.31 Å. The N(2)-O(5) bond length is 1.25 Å. The N(2)-O(6) bond length is 1.26 Å. There are four inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. There are four inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Ag(1), one C(4), and one C(9) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Ag(1) and one N(2) atom. Linkers: 2 O=C(OCCOCCOCCOC(=O)c1cccnc1)c1cccnc1.O=[N+]([O-])O[Ag]O[N+](=O)[O-]. Metal clusters: 2 [Ag]. The MOF has largest included sphere 1.52 A, density 2.10 g/cm3, surface area 3584.64 m2/g, accessible volume 0.08 cm3/g