Cu(SO)4(CH3)4(CH2)10(BF4)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twenty 02329_fluka molecules, eight 02329_fluka molecules, four BF4 clusters, and two Cu(SO)4 clusters. In each BF4 cluster, B(1) is bonded in a tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. The B(1)-F(1) bond length is 1.42 Å. The B(1)-F(2) bond length is 1.42 Å. The B(1)-F(3) bond length is 1.42 Å. The B(1)-F(4) bond length is 1.42 Å. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one B(1) atom. In each Cu(SO)4 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Cu(1)-O(1) bond lengths are 1.96 Å. Both Cu(1)-O(2) bond lengths are 1.96 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one O(1) atom. The S(1)-O(1) bond length is 1.55 Å. In the second S site, S(2) is bonded in a distorted single-bond geometry to one O(2) atom. The S(2)-O(2) bond length is 1.55 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one S(2) atom. Linkers: 1 [CH2][CH][S@](=O)CCC[S@](=O)CC ,4 CC[S@@](=O)CCC[S@@](=O)CC ,1 [CH2]C[S@](=O)CCC[S@](=O)CC ,1 [CH2]C[S@@](=O)CCC[S@@](=O)CC ,1 [CH2][CH][S@@](=O)CCC[S@@](=O)CC. Metal clusters: 2 [Cu]. The MOF has largest included sphere 1.80 A, density 1.66 g/cm3, surface area 4900.44 m2/g, accessible volume 0.17 cm3/g