CdC24H14(NO)4(CH)2(CH2)6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, twenty-four 02329_fluka molecules, and four CdC24H14(NO)4 clusters. In each CdC24H14(NO)4 cluster, Cd(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent N(2), two equivalent O(1), and two equivalent O(2) atoms. Both Cd(1)-N(1) bond lengths are 2.51 Å. Both Cd(1)-N(2) bond lengths are 2.49 Å. Both Cd(1)-O(1) bond lengths are 2.65 Å. Both Cd(1)-O(2) bond lengths are 2.38 Å. There are twelve inequivalent C sites. In the first C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(12) bond length is 1.42 Å. The C(4)-C(3) bond length is 1.41 Å. The C(4)-C(5) bond length is 1.43 Å. In the second C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-C(7) bond length is 1.43 Å. The C(6)-H(5) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.43 Å. The C(7)-C(8) bond length is 1.41 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-H(7) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.33 Å. The C(10)-H(8) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(7), and one N(2) atom. The C(11)-C(12) bond length is 1.45 Å. The C(11)-N(2) bond length is 1.36 Å. In the ninth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(4), and one N(1) atom. The C(12)-N(1) bond length is 1.35 Å. In the tenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(13)-O(1) bond length is 1.27 Å. The C(13)-O(2) bond length is 1.28 Å. In the eleventh C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the twelfth C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-H(3) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(12) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(11) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cd(1) and one C(13) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1) and one C(13) atom. Linkers: 2 [O]C(=O)CCCCCCC([O])=O. Metal clusters: 2 O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 2.61 A, density 1.53 g/cm3, surface area 4924.63 m2/g, accessible volume 0.10 cm3/g