Ag3C17H13(NO)6 crystallizes in the triclinic P-1 space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted T-shaped geometry to one N(3), one O(2), and one O(3) atom. The Ag(1)-N(3) bond length is 2.38 Å. The Ag(1)-O(2) bond length is 2.22 Å. The Ag(1)-O(3) bond length is 2.24 Å. In the second Ag site, Ag(2) is bonded in a distorted T-shaped geometry to one N(6), one O(1), and one O(6) atom. The Ag(2)-N(6) bond length is 2.42 Å. The Ag(2)-O(1) bond length is 2.20 Å. The Ag(2)-O(6) bond length is 2.21 Å. In the third Ag site, Ag(3) is bonded in a distorted rectangular see-saw-like geometry to one N(2), one N(5), one O(4), and one O(5) atom. The Ag(3)-N(2) bond length is 2.29 Å. The Ag(3)-N(5) bond length is 2.24 Å. The Ag(3)-O(4) bond length is 2.68 Å. The Ag(3)-O(5) bond length is 2.46 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(3), and one H(1) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-N(3) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(13), one C(9), and one H(2) atom. The C(2)-C(13) bond length is 1.39 Å. The C(2)-C(9) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(16), and one H(3) atom. The C(3)-C(16) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(2), and one O(3) atom. The C(4)-C(10) bond length is 1.50 Å. The C(4)-O(2) bond length is 1.27 Å. The C(4)-O(3) bond length is 1.28 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(5)-C(11) bond length is 1.50 Å. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(17), one C(5), and one H(4) atom. The C(6)-C(17) bond length is 1.39 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(10), one C(17), and one H(5) atom. The C(7)-C(10) bond length is 1.40 Å. The C(7)-C(17) bond length is 1.40 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(10), one C(5), and one H(6) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(7) atom. The C(9)-N(2) bond length is 1.34 Å. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(4), one C(7), and one C(8) atom. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(6) atom. The C(11)-O(1) bond length is 1.28 Å. The C(11)-O(6) bond length is 1.27 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one N(1), one N(3), and one N(5) atom. The C(12)-N(1) bond length is 1.34 Å. The C(12)-N(3) bond length is 1.36 Å. The C(12)-N(5) bond length is 1.37 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(2), one N(6), and one H(8) atom. The C(13)-N(6) bond length is 1.34 Å. The C(13)-H(8) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(4), and one O(5) atom. The C(14)-C(17) bond length is 1.50 Å. The C(14)-O(4) bond length is 1.29 Å. The C(14)-O(5) bond length is 1.26 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one N(2), one N(4), and one N(6) atom. The C(15)-N(2) bond length is 1.36 Å. The C(15)-N(4) bond length is 1.35 Å. The C(15)-N(6) bond length is 1.35 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(3), one N(5), and one H(9) atom. The C(16)-N(5) bond length is 1.34 Å. The C(16)-H(9) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(14), one C(6), and one C(7) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(12), one H(10), and one H(11) atom. The N(1)-H(10) bond length is 1.02 Å. The N(1)-H(11) bond length is 1.02 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(3), one C(15), and one C(9) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(12) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(15), one H(12), and one H(13) atom. The N(4)-H(12) bond length is 1.02 Å. The N(4)-H(13) bond length is 1.04 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Ag(3), one C(12), and one C(16) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(13), and one C(15) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(1) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(1) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(4) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one N(4) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one C(11) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one C(4) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one C(4) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Ag(3) and one C(14) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Ag(3) and one C(14) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ag(2) and one C(11) atom. Linkers: 2 [O]C(=O)c1cc(C([O])=O)cc(C([O])=O)c1 ,4 Nc1ncccn1. Metal clusters: 4 [Ag] ,1 [O][C]O[Ag][Ag]O[C][O]. The MOF has largest included sphere 1.88 A, density 2.56 g/cm3, surface area 2575.53 m2/g, accessible volume 0.05 cm3/g