AgC16N3H10O4CH crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a AgC16N3H10O4 framework. In the AgC16N3H10O4 framework, Ag(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one O(1) atom. The Ag(1)-N(1) bond length is 2.16 Å. The Ag(1)-N(2) bond length is 2.13 Å. The Ag(1)-O(1) bond length is 2.52 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.46 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one N(3) atom. The C(6)-N(2) bond length is 1.35 Å. The C(6)-N(3) bond length is 1.36 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one N(2) atom. The C(7)-C(12) bond length is 1.42 Å. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(2) bond length is 1.39 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(5) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(5) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(6) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-H(6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(7) atom. The C(10)-H(7) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(8) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(8) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(7), and one N(3) atom. The C(12)-N(3) bond length is 1.37 Å. In the twelfth C site, C(13) is bonded in a bent 120 degrees geometry to one C(14), one O(1), and one O(2) atom. The C(13)-C(14) bond length is 1.52 Å. The C(13)-O(1) bond length is 1.24 Å. The C(13)-O(2) bond length is 1.31 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.42 Å. The C(14)-C(17) bond length is 1.40 Å. In the fourteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(17) atom. The C(15)-C(16) bond length is 1.52 Å. The C(15)-C(17) bond length is 1.40 Å. In the fifteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(3), and one O(4) atom. The C(16)-O(3) bond length is 1.26 Å. The C(16)-O(4) bond length is 1.28 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(14), one C(15), and one H(9) atom. The C(17)-H(9) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(6), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(12), one C(6), and one H(10) atom. The N(3)-H(10) bond length is 1.06 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(10) is bonded in a distorted linear geometry to one N(3) and one O(3) atom. The H(10)-O(3) bond length is 1.63 Å. In the tenth H site, H(11) is bonded in a linear geometry to one O(2) and one O(4) atom. The H(11)-O(2) bond length is 1.12 Å. The H(11)-O(4) bond length is 1.29 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one C(13) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(13) and one H(11) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(16) and one H(10) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(16) and one H(11) atom. Linkers: 2 [O]C(=O)c1cc(C(=O)O)c(C([O])=O)cc1C(=O)O ,3 c1cncc(-c2nc3ccccc3[nH]2)c1 ,2 [CH]c1nc(-c2cccnc2)[nH]c1[CH]. Metal clusters: 2 O[C]O[Ag] ,2 [Ag]. The MOF has largest included sphere 2.27 A, density 1.94 g/cm3, surface area 3715.32 m2/g, accessible volume 0.09 cm3/g