AgC2NH3O2AgC2NH4O2CH2C2NH2O crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two n-methylformamide molecules, two AgC2NH3O2 clusters, and two AgC2NH4O2 clusters. In each AgC2NH3O2 cluster, Ag(1) is bonded in a linear geometry to one N(1) and one O(5) atom. The Ag(1)-N(1) bond length is 2.16 Å. The Ag(1)-O(5) bond length is 2.17 Å. There are two inequivalent C sites. In the first C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(7)-O(4) bond length is 1.25 Å. The C(7)-O(5) bond length is 1.30 Å. In the second C site, C(3) is bonded in a distorted water-like geometry to one N(1) and one H(3) atom. The C(3)-N(1) bond length is 1.47 Å. The C(3)-H(3) bond length is 1.10 Å. N(1) is bonded in a 4-coordinate geometry to one Ag(1), one C(3), one H(7), and one H(8) atom. The N(1)-H(7) bond length is 1.03 Å. The N(1)-H(8) bond length is 1.02 Å. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(7) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(8) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one C(7) atom. In the second O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one C(7) atom. In each AgC2NH4O2 cluster, Ag(2) is bonded in a linear geometry to one N(3) and one O(2) atom. The Ag(2)-N(3) bond length is 2.17 Å. The Ag(2)-O(2) bond length is 2.15 Å. There are two inequivalent C sites. In the first C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(5), and one H(6) atom. The C(6)-N(3) bond length is 1.47 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.30 Å. N(3) is bonded in a 4-coordinate geometry to one Ag(2), one C(6), one H(10), and one H(11) atom. The N(3)-H(10) bond length is 1.02 Å. The N(3)-H(11) bond length is 1.03 Å. There are four inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(10) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one C(1) atom. Linkers: 2 NC[C@H](NC(=O)[C@@H](N)C[C][O])C([O])=O ,2 NC[C@H](NC(=O)[C@@H](N)CC([O])=O)C([O])=O ,2 [C][C@H](NC(=O)[C@@H](N)CC([O])=O)C([O])=O. Metal clusters: 2 [CH][NH2]/[Ag](=[Ag](\O[C]=O)/[NH2][CH2])/O[C]=O. The MOF has largest included sphere 1.67 A, density 2.81 g/cm3, surface area 2266.80 m2/g, accessible volume 0.04 cm3/g