YC12H14OCl is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one YC12H14OCl cluster. Y(1) is bonded in a 13-coordinate geometry to one C(1), one C(10), one C(2), one C(3), one C(4), one C(5), one C(6), one C(7), one C(8), one C(9), one O(1), and two equivalent Cl(1) atoms. The Y(1)-C(1) bond length is 2.65 Å. The Y(1)-C(10) bond length is 2.70 Å. The Y(1)-C(2) bond length is 2.64 Å. The Y(1)-C(3) bond length is 2.67 Å. The Y(1)-C(4) bond length is 2.67 Å. The Y(1)-C(5) bond length is 2.65 Å. The Y(1)-C(6) bond length is 2.67 Å. The Y(1)-C(7) bond length is 2.64 Å. The Y(1)-C(8) bond length is 2.67 Å. The Y(1)-C(9) bond length is 2.70 Å. The Y(1)-O(1) bond length is 2.61 Å. There is one shorter (2.71 Å) and one longer (2.79 Å) Y(1)-Cl(1) bond length. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one Y(1) and one H(1) atom. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one Y(1) and one H(2,4) atom. The C(2)-H(2,4) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one Y(1) and one H(3) atom. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one Y(1) and one H(2,4) atom. The C(4)-H(2,4) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one Y(1) and one H(5,8) atom. The C(5)-H(5,8) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one Y(1) and one H(6) atom. The C(6)-H(6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one Y(1) and one H(7) atom. The C(7)-H(7) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one Y(1) and one H(5,8) atom. The C(8)-H(5,8) bond length is 1.08 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one Y(1) and one H(9) atom. The C(9)-H(9) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one Y(1) and one H(10) atom. The C(10)-H(10) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one H(11), one H(12), and one O(1) atom. The C(11)-H(11) bond length is 1.09 Å. The C(11)-H(12) bond length is 1.10 Å. The C(11)-O(1) bond length is 1.45 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one H(13), one H(14), and one O(1) atom. The C(12)-H(13) bond length is 1.10 Å. The C(12)-H(14) bond length is 1.09 Å. The C(12)-O(1) bond length is 1.45 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2,4) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5,8) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. O(1) is bonded in a distorted water-like geometry to one Y(1), one C(11), and one C(12) atom. Cl(1) is bonded in a water-like geometry to two equivalent Y(1) atoms. Linkers: 1 C1COCCO1. Metal clusters: 1 Cl[Y].Cl[Y]. The MOF has largest included sphere 2.13 A, density 1.76 g/cm3, surface area 4092.56 m2/g, accessible volume 0.10 cm3/g