CuC4NH7ClCH3C3NH6 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four trimethylamine molecules, and four CuC4NH7Cl clusters. In each CuC4NH7Cl cluster, Cu(1) is bonded in a 4-coordinate geometry to one C(1), one C(2), one N(2), and one Cl(1) atom. The Cu(1)-C(1) bond length is 2.00 Å. The Cu(1)-C(2) bond length is 2.01 Å. The Cu(1)-N(2) bond length is 2.03 Å. The Cu(1)-Cl(1) bond length is 2.22 Å. There are four inequivalent C sites. In the first C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(15), and one H(16) atom. The C(8)-N(2) bond length is 1.48 Å. The C(8)-H(15) bond length is 1.10 Å. The C(8)-H(16) bond length is 1.10 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1), one H(1), and one H(2) atom. The C(1)-H(1) bond length is 1.09 Å. The C(1)-H(2) bond length is 1.09 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one Cu(1) and one H(3) atom. The C(2)-H(3) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted water-like geometry to one N(2) and one H(10) atom. The C(6)-N(2) bond length is 1.48 Å. The C(6)-H(10) bond length is 1.10 Å. N(2) is bonded in a distorted tetrahedral geometry to one Cu(1), one C(6), one C(8), and one H(11) atom. The N(2)-H(11) bond length is 1.04 Å. There are seven inequivalent H sites. In the first H site, H(16) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(8) atom. Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 4 [CH]CN1CCN[C@H](C)C1. Metal clusters: 4 [CH]C[Cu].[Cl].[NH]. The MOF has largest included sphere 2.13 A, density 1.63 g/cm3, surface area 4976.36 m2/g, accessible volume 0.10 cm3/g