(CH)2(CH2)4CdC9N2H5(O2F)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, eight 02329_fluka molecules, and one CdC9N2H5(O2F)2 cluster. In the CdC9N2H5(O2F)2 cluster, Cd(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.25 Å. The Cd(1)-O(1) bond length is 2.30 Å. The Cd(1)-O(2) bond length is 2.25 Å. The Cd(1)-O(3) bond length is 2.29 Å. The Cd(1)-O(4) bond length is 2.29 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.28 Å. The C(8)-O(4) bond length is 1.27 Å. In the third C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(11) atom. The C(9)-N(1) bond length is 1.33 Å. The C(9)-N(2) bond length is 1.36 Å. The C(9)-H(11) bond length is 1.08 Å. In the fourth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(1), and one H(12) atom. The C(10)-C(11) bond length is 1.37 Å. The C(10)-N(1) bond length is 1.38 Å. The C(10)-H(12) bond length is 1.08 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(13) atom. The C(11)-N(2) bond length is 1.38 Å. The C(11)-H(13) bond length is 1.08 Å. In the sixth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(13), one N(2), one H(14), and one H(15) atom. The C(12)-C(13) bond length is 1.51 Å. The C(12)-N(2) bond length is 1.46 Å. The C(12)-H(14) bond length is 1.09 Å. The C(12)-H(15) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(15) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-C(15) bond length is 1.40 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one F(1) atom. The C(14)-F(1) bond length is 1.35 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(13) and one F(2) atom. The C(15)-F(2) bond length is 1.36 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. There are five inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(8) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(14) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(15) atom. Linkers: 2 [N]=C[N]Cc1c(F)c(F)c(Cn2ccnc2)c(F)c1F ,1 Fc1c(F)c(Cn2ccnc2)c(F)c(F)c1Cn1ccnc1 ,2 [O]C(=O)[C@H]1CC[C@@H](C([O])=O)CC1. Metal clusters: 1 [C]1O[Cd]234O[C]O[Cd]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 2.29 A, density 1.82 g/cm3, surface area 4080.31 m2/g, accessible volume 0.10 cm3/g