CoC25N3H20O4(CH)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and two CoC25N3H20O4 clusters. In each CoC25N3H20O4 cluster, Co(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Co(1)-N(1) bond length is 2.18 Å. The Co(1)-O(1) bond length is 2.01 Å. The Co(1)-O(2) bond length is 2.02 Å. The Co(1)-O(3) bond length is 2.01 Å. The Co(1)-O(4) bond length is 2.05 Å. There are twenty-five inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(15) and one H(6,10) atom. The C(9)-C(15) bond length is 1.41 Å. The C(9)-H(6,10) bond length is 1.09 Å. In the second C site, C(10) is bonded in a bent 120 degrees geometry to one C(1), one O(1), and one O(3) atom. The C(10)-C(1) bond length is 1.48 Å. The C(10)-O(1) bond length is 1.28 Å. The C(10)-O(3) bond length is 1.28 Å. In the third C site, C(11) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(7) atom. The C(11)-C(4) bond length is 1.40 Å. The C(11)-C(6) bond length is 1.39 Å. The C(11)-H(7) bond length is 1.09 Å. In the fourth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(8) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(8) bond length is 1.09 Å. In the fifth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(5) atom. The C(13)-C(12) bond length is 1.40 Å. The C(13)-C(16) bond length is 1.40 Å. The C(13)-C(5) bond length is 1.48 Å. In the sixth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(25), one C(27), and one N(2) atom. The C(14)-C(25) bond length is 1.40 Å. The C(14)-C(27) bond length is 1.40 Å. The C(14)-N(2) bond length is 1.42 Å. In the seventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(17), one C(9), and one N(2) atom. The C(15)-C(17) bond length is 1.41 Å. The C(15)-N(2) bond length is 1.40 Å. In the eighth C site, C(16) is bonded in a distorted single-bond geometry to one C(13) and one H(9) atom. The C(16)-C(13) bond length is 1.40 Å. The C(16)-H(9) bond length is 1.09 Å. In the ninth C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one H(6,10) atom. The C(17)-H(6,10) bond length is 1.09 Å. In the tenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(26), one N(1), and one H(11) atom. The C(18)-C(26) bond length is 1.39 Å. The C(18)-N(1) bond length is 1.35 Å. The C(18)-H(11) bond length is 1.09 Å. In the eleventh C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(12), and one H(13) atom. The C(19)-N(3) bond length is 1.46 Å. The C(19)-H(12) bond length is 1.11 Å. The C(19)-H(13) bond length is 1.10 Å. In the twelfth C site, C(20) is bonded in a trigonal planar geometry to one C(21), one C(24), and one C(26) atom. The C(20)-C(21) bond length is 1.51 Å. The C(20)-C(24) bond length is 1.40 Å. The C(20)-C(26) bond length is 1.40 Å. In the thirteenth C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one C(20), one N(3), one H(14), and one H(15) atom. The C(21)-N(3) bond length is 1.46 Å. The C(21)-H(14) bond length is 1.11 Å. The C(21)-H(15) bond length is 1.10 Å. In the fourteenth C site, C(22) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(16), and one H(17) atom. The C(22)-N(3) bond length is 1.46 Å. The C(22)-H(16) bond length is 1.11 Å. The C(22)-H(17) bond length is 1.10 Å. In the fifteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(24), one N(1), and one H(18) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-N(1) bond length is 1.34 Å. The C(23)-H(18) bond length is 1.09 Å. In the sixteenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(20), one C(23), and one H(19) atom. The C(24)-H(19) bond length is 1.09 Å. In the seventeenth C site, C(25) is bonded in a distorted single-bond geometry to one C(14) and one H(20,22) atom. The C(25)-H(20,22) bond length is 1.09 Å. In the eighteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(21) atom. The C(26)-H(21) bond length is 1.09 Å. In the nineteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(14) and one H(20,22) atom. The C(27)-H(20,22) bond length is 1.09 Å. In the twentieth C site, C(1) is bonded in a trigonal planar geometry to one C(10), one C(3), and one C(6) atom. The C(1)-C(3) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. In the twenty-first C site, C(3) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the twenty-second C site, C(4) is bonded in a distorted trigonal planar geometry to one C(11), one C(7), and one N(2) atom. The C(4)-C(7) bond length is 1.40 Å. The C(4)-N(2) bond length is 1.42 Å. In the twenty-third C site, C(5) is bonded in a bent 120 degrees geometry to one C(13), one O(2), and one O(4) atom. The C(5)-O(2) bond length is 1.28 Å. The C(5)-O(4) bond length is 1.28 Å. In the twenty-fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(11), and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the twenty-fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(18), and one C(23) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal non-coplanar geometry to one C(19), one C(21), and one C(22) atom. There are eighteen inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6,10) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(22) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(23) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(24) atom. In the seventeenth H site, H(20,22) is bonded in a single-bond geometry to one C(25) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(26) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(10) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one C(5) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one C(10) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one C(5) atom. Linkers: 4 [O]C(=O)c1ccc(N(c2ccccc2)c2ccc(C([O])=O)cc2)cc1 ,2 c1cc(CN2CCN(Cc3ccncc3)CC2)ccn1. Metal clusters: 2 [C]1O[Co]234O[C]O[Co]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 4.75 A, density 1.27 g/cm3, surface area 4992.84 m2/g, accessible volume 0.28 cm3/g