ZnC18H16(NO)4(C4H5)2(CH2)6(CH)8(H3(CO)2)2(C4NH4SO2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two isobutylene molecules, two isobutylene molecules, two methyl formate molecules, two schembl9269457 molecules, and one ZnC18H16(NO)4 cluster. In the ZnC18H16(NO)4 cluster, Zn(1) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(3), and two equivalent O(1) atoms. Both Zn(1)-N(2) bond lengths are 2.13 Å. Both Zn(1)-N(3) bond lengths are 2.24 Å. Both Zn(1)-O(1) bond lengths are 2.15 Å. There are nine inequivalent C sites. In the first C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(9)-O(1) bond length is 1.27 Å. The C(9)-O(2) bond length is 1.26 Å. In the second C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(2), and one H(16) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-N(2) bond length is 1.35 Å. The C(14)-H(16) bond length is 1.09 Å. In the third C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(17) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(17) bond length is 1.09 Å. In the fourth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(19) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(19) bond length is 1.50 Å. In the fifth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(18) atom. The C(17)-H(18) bond length is 1.09 Å. In the sixth C site, C(18) is bonded in a distorted trigonal planar geometry to one N(2) and one H(19) atom. The C(18)-N(2) bond length is 1.34 Å. The C(18)-H(19) bond length is 1.09 Å. In the seventh C site, C(19) is bonded in a distorted water-like geometry to one C(16), one H(20), and one H(21) atom. The C(19)-H(20) bond length is 1.10 Å. The C(19)-H(21) bond length is 1.10 Å. In the eighth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(27) atom. The C(24)-N(3) bond length is 1.35 Å. The C(24)-H(27) bond length is 1.09 Å. In the ninth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(28) atom. The C(25)-N(3) bond length is 1.35 Å. The C(25)-H(28) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(14), and one C(18) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(24), and one C(25) atom. There are eight inequivalent H sites. In the first H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the second H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the third H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(21) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(27) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(28) is bonded in a single-bond geometry to one C(25) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(9) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(9) atom. Linkers: 2 c1cc(CCCc2ccncc2)ccn1. Metal clusters: 1 [Zn]. The MOF has largest included sphere 2.75 A, density 1.35 g/cm3, surface area 5384.38 m2/g, accessible volume 0.21 cm3/g