AgH8(C2N)4InH8(C2O)8 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AgH8(C2N)4 clusters and two InH8(C2O)8 clusters. In each AgH8(C2N)4 cluster, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Ag(1)-N(1) bond length is 2.31 Å. The Ag(1)-N(2) bond length is 2.31 Å. The Ag(1)-N(3) bond length is 2.31 Å. The Ag(1)-N(4) bond length is 2.31 Å. There are five inequivalent C sites. In the first C site, C(13,14,16) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(13,14,16)-N(1) bond length is 1.35 Å. The C(13,14,16)-H(13) bond length is 1.09 Å. In the second C site, C(9,12) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(9,12)-N(1) bond length is 1.35 Å. The C(9,12)-H(9) bond length is 1.09 Å. In the third C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10,11) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(10,11) bond length is 1.09 Å. In the fourth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(10,11) atom. The C(11)-N(3) bond length is 1.35 Å. The C(11)-H(10,11) bond length is 1.09 Å. In the fifth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(14,15) atom. The C(15)-N(3) bond length is 1.35 Å. The C(15)-H(14,15) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Ag(1); one C(13,14,16); and one C(9,12) atom. The N(4)-C(13,14,16) bond length is 1.35 Å. The N(4)-C(9,12) bond length is 1.35 Å. In the second N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(11), and one C(15) atom. In the third N site, N(1) is bonded in a trigonal planar geometry to one Ag(1); one C(13,14,16); and one C(9,12) atom. In the fourth N site, N(2) is bonded in a trigonal planar geometry to one Ag(1); one C(10); and one C(13,14,16) atom. The N(2)-C(13,14,16) bond length is 1.35 Å. There are six inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(9,12) atom. In the second H site, H(10,11) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(9,12) atom. The H(12)-C(9,12) bond length is 1.09 Å. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(13,14,16) atom. In the fifth H site, H(14,15) is bonded in a single-bond geometry to one C(13,14,16) atom. The H(14,15)-C(13,14,16) bond length is 1.09 Å. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(13,14,16) atom. The H(16)-C(13,14,16) bond length is 1.09 Å. In each InH8(C2O)8 cluster, In(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. The In(1)-O(1) bond length is 2.27 Å. The In(1)-O(2) bond length is 2.27 Å. The In(1)-O(3) bond length is 2.27 Å. The In(1)-O(4) bond length is 2.27 Å. The In(1)-O(5) bond length is 2.39 Å. The In(1)-O(6) bond length is 2.39 Å. The In(1)-O(7) bond length is 2.39 Å. The In(1)-O(8) bond length is 2.39 Å. There are thirteen inequivalent C sites. In the first C site, C(1,3) is bonded in a distorted single-bond geometry to one C(21) and one H(1,2,3,4) atom. The C(1,3)-C(21) bond length is 1.40 Å. The C(1,3)-H(1,2,3,4) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(22) and one H(1,2,3,4) atom. The C(2)-C(22) bond length is 1.40 Å. The C(2)-H(1,2,3,4) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(24) and one H(1,2,3,4) atom. The C(4)-C(24) bond length is 1.40 Å. The C(4)-H(1,2,3,4) bond length is 1.09 Å. In the fourth C site, C(5,7) is bonded in a distorted single-bond geometry to one C(21) and one H(5,6,7,8) atom. The C(5,7)-C(21) bond length is 1.40 Å. The C(5,7)-H(5,6,7,8) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(22) and one H(5,6,7,8) atom. The C(6)-C(22) bond length is 1.40 Å. The C(6)-H(5,6,7,8) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(24) and one H(5,6,7,8) atom. The C(8)-C(24) bond length is 1.40 Å. The C(8)-H(5,6,7,8) bond length is 1.09 Å. In the seventh C site, C(17,19) is bonded in a bent 120 degrees geometry to one C(21), one O(1), and one O(5) atom. The C(17,19)-C(21) bond length is 1.50 Å. The C(17,19)-O(1) bond length is 1.28 Å. The C(17,19)-O(5) bond length is 1.27 Å. In the eighth C site, C(18) is bonded in a bent 120 degrees geometry to one C(22), one O(2), and one O(6) atom. The C(18)-C(22) bond length is 1.50 Å. The C(18)-O(2) bond length is 1.28 Å. The C(18)-O(6) bond length is 1.27 Å. In the ninth C site, C(20) is bonded in a bent 120 degrees geometry to one C(24), one O(4), and one O(8) atom. The C(20)-C(24) bond length is 1.49 Å. The C(20)-O(4) bond length is 1.28 Å. The C(20)-O(8) bond length is 1.27 Å. In the tenth C site, C(21) is bonded in a trigonal planar geometry to one C(1,3); one C(17,19); and one C(5,7) atom. In the eleventh C site, C(22) is bonded in a trigonal planar geometry to one C(18), one C(2), and one C(6) atom. In the twelfth C site, C(23) is bonded in a trigonal planar geometry to one C(1,3); one C(17,19); and one C(5,7) atom. The C(23)-C(1,3) bond length is 1.40 Å. The C(23)-C(17,19) bond length is 1.50 Å. The C(23)-C(5,7) bond length is 1.40 Å. In the thirteenth C site, C(24) is bonded in a trigonal planar geometry to one C(20), one C(4), and one C(8) atom. There are two inequivalent H sites. In the first H site, H(1,2,3,4) is bonded in a single-bond geometry to one C(1,3) atom. In the second H site, H(5,6,7,8) is bonded in a single-bond geometry to one C(5,7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one In(1) and one C(17,19) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one In(1) and one C(18) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one In(1) and one C(17,19) atom. The O(3)-C(17,19) bond length is 1.28 Å. In the fourth O site, O(4) is bonded in an L-shaped geometry to one In(1) and one C(20) atom. In the fifth O site, O(5) is bonded in a distorted L-shaped geometry to one In(1) and one C(17,19) atom. In the sixth O site, O(6) is bonded in a distorted L-shaped geometry to one In(1) and one C(18) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one In(1) and one C(17,19) atom. The O(7)-C(17,19) bond length is 1.27 Å. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one In(1) and one C(20) atom. Linkers: 2 [O]C(=O)C1=C[CH]N([Ag](N2[CH]C=C(C([O])=O)C=C2)(N2[CH]C=C(C([O])=O)C=C2)N2[CH]C=C(C([O])=O)C=C2)C=C1. Metal clusters: 2 O=[C]O[In](O[C]=O)O[C]=O.[O][C]=O. RCSR code: dia. The MOF has largest included sphere 5.93 A, density 1.33 g/cm3, surface area 4099.88 m2/g, accessible volume 0.38 cm3/g