ZnC6H6(N5O2)2(CH3)2 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two ZnC6H6(N5O2)2 clusters. In each ZnC6H6(N5O2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(2) atoms. Both Zn(1)-N(1) bond lengths are 2.00 Å. Both Zn(1)-O(2) bond lengths are 1.99 Å. There are three inequivalent C sites. In the first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(3)-O(1) bond length is 1.25 Å. The C(3)-O(2) bond length is 1.29 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(5) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-N(5) bond length is 1.33 Å. In the third C site, C(2) is bonded in a 2-coordinate geometry to one N(2) and one H(3) atom. The C(2)-N(2) bond length is 1.46 Å. The C(2)-H(3) bond length is 1.10 Å. There are five inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. The N(5)-H(1) bond length is 1.03 Å. The N(5)-H(2) bond length is 1.02 Å. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(1), and one N(3) atom. The N(1)-N(3) bond length is 1.37 Å. In the third N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(2), and one N(4) atom. The N(2)-N(4) bond length is 1.37 Å. In the fourth N site, N(3) is bonded in a water-like geometry to one N(1) and one N(4) atom. The N(3)-N(4) bond length is 1.28 Å. In the fifth N site, N(4) is bonded in a water-like geometry to one N(2) and one N(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the second O site, O(1) is bonded in a single-bond geometry to one C(3) atom. Linkers: 4 C[C@@H](C([O])=O)n1nnnc1N. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.17 A, density 1.80 g/cm3, surface area 4031.35 m2/g, accessible volume 0.15 cm3/g