(CH)7ZnC25H9(N2F)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of fourteen 02329_fluka molecules and two ZnC25H9(N2F)4 clusters. In each ZnC25H9(N2F)4 cluster, Zn(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(5), one N(6), and one N(7) atom. The Zn(1)-N(1) bond length is 2.15 Å. The Zn(1)-N(2) bond length is 2.14 Å. The Zn(1)-N(3) bond length is 2.21 Å. The Zn(1)-N(5) bond length is 2.23 Å. The Zn(1)-N(6) bond length is 2.15 Å. The Zn(1)-N(7) bond length is 2.15 Å. There are twenty-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(5) and one N(7) atom. The C(1)-C(5) bond length is 1.39 Å. The C(1)-N(7) bond length is 1.18 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(21), one C(4), and one C(9) atom. The C(2)-C(21) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.40 Å. The C(2)-C(9) bond length is 1.46 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(11) and one N(1) atom. The C(3)-C(11) bond length is 1.48 Å. The C(3)-N(1) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one F(2) atom. The C(4)-F(2) bond length is 1.36 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(20), and one C(7) atom. The C(5)-C(20) bond length is 1.46 Å. The C(5)-C(7) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(9) and one N(8) atom. The C(6)-C(9) bond length is 1.41 Å. The C(6)-N(8) bond length is 1.18 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one N(4) atom. The C(7)-N(4) bond length is 1.18 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(20) and one F(1) atom. The C(8)-C(20) bond length is 1.40 Å. The C(8)-F(1) bond length is 1.36 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(6) atom. The C(9)-C(10) bond length is 1.38 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one N(2) atom. The C(10)-N(2) bond length is 1.18 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(18), one C(3), and one N(3) atom. The C(11)-C(18) bond length is 1.40 Å. The C(11)-N(3) bond length is 1.35 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one N(6) and one H(1) atom. The C(12)-N(6) bond length is 1.34 Å. The C(12)-H(1) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(2) atom. The C(13)-N(3) bond length is 1.34 Å. The C(13)-H(2) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(14)-N(1) bond length is 1.34 Å. The C(14)-H(3) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(22) and one N(6) atom. The C(15)-C(22) bond length is 1.48 Å. The C(15)-N(6) bond length is 1.35 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(20) and one F(4) atom. The C(16)-C(20) bond length is 1.40 Å. The C(16)-F(4) bond length is 1.37 Å. In the seventeenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(11), one C(24), and one H(5) atom. The C(18)-C(24) bond length is 1.39 Å. The C(18)-H(5) bond length is 1.09 Å. In the eighteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(32), one N(5), and one H(6) atom. The C(19)-C(32) bond length is 1.39 Å. The C(19)-N(5) bond length is 1.34 Å. The C(19)-H(6) bond length is 1.09 Å. In the nineteenth C site, C(20) is bonded in a trigonal planar geometry to one C(16), one C(5), and one C(8) atom. In the twentieth C site, C(21) is bonded in a distorted single-bond geometry to one C(2) and one F(3) atom. The C(21)-F(3) bond length is 1.36 Å. In the twenty-first C site, C(22) is bonded in a distorted trigonal planar geometry to one C(15), one C(27), and one N(5) atom. The C(22)-C(27) bond length is 1.40 Å. The C(22)-N(5) bond length is 1.35 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(18) and one H(8) atom. The C(24)-H(8) bond length is 1.09 Å. In the twenty-third C site, C(26) is bonded in a distorted single-bond geometry to one C(32) and one H(10) atom. The C(26)-C(32) bond length is 1.40 Å. The C(26)-H(10) bond length is 1.09 Å. In the twenty-fourth C site, C(27) is bonded in a distorted single-bond geometry to one C(22) and one H(11) atom. The C(27)-H(11) bond length is 1.09 Å. In the twenty-fifth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(19), one C(26), and one H(16) atom. The C(32)-H(16) bond length is 1.09 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(14), and one C(3) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(10) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(13) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(1), one C(19), and one C(22) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(1), one C(12), and one C(15) atom. In the seventh N site, N(7) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the eighth N site, N(8) is bonded in a single-bond geometry to one C(6) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(24) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(26) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(32) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(8) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(4) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(21) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(16) atom. Linkers: 2 N#C[C](C#N)c1c(F)c(F)c([C](C#N)C#N)c(F)c1F. Metal clusters: 2 [Zn]. The MOF has largest included sphere 4.00 A, density 1.48 g/cm3, surface area 4441.87 m2/g, accessible volume 0.20 cm3/g