CuC12N2H12ICH2C3H2(CH)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; four 02329_fluka molecules; two 2,3-dimethyl-1,3-butadiene molecules; and two CuC12N2H12I clusters. In each CuC12N2H12I cluster, Cu(1) is bonded in a 2-coordinate geometry to two equivalent N(1) and two equivalent I(1) atoms. Both Cu(1)-N(1) bond lengths are 2.01 Å. There is one shorter (2.63 Å) and one longer (2.70 Å) Cu(1)-I(1) bond length. There are six inequivalent C sites. In the first C site, C(6) is bonded in a distorted water-like geometry to one C(3) and two equivalent H(5,6) atoms. The C(6)-C(3) bond length is 1.50 Å. Both C(6)-H(5,6) bond lengths are 1.10 Å. In the second C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the fourth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. In the fifth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the sixth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(6) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 2 c1cc(CCCc2ccncc2)ccn1. Metal clusters: 1 I[Cu][Cu]I. The MOF has largest included sphere 2.32 A, density 1.78 g/cm3, surface area 4260.57 m2/g, accessible volume 0.13 cm3/g