Zn3C30H24(NO6)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form corner-sharing ZnO6 octahedra. Both Zn(1)-O(2) bond lengths are 2.12 Å. Both Zn(1)-O(4) bond lengths are 2.08 Å. Both Zn(1)-O(6) bond lengths are 2.08 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(6), and two equivalent O(5) atoms to form distorted ZnO5 trigonal bipyramids that share  a cornercorner with one Zn(1)O6 octahedra and  an edgeedge with one Zn(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 71°. The Zn(2)-O(1) bond length is 2.02 Å. The Zn(2)-O(3) bond length is 1.99 Å. The Zn(2)-O(6) bond length is 2.10 Å. There is one shorter (2.08 Å) and one longer (2.09 Å) Zn(2)-O(5) bond length. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.50 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.28 Å. The C(8)-O(4) bond length is 1.26 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(13) and one O(5) atom. The C(9)-C(13) bond length is 1.40 Å. The C(9)-O(5) bond length is 1.32 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one O(6) atom. The C(10)-O(6) bond length is 1.30 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(5) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-H(5) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one H(6) atom. The C(12)-N(1) bond length is 1.35 Å. The C(12)-H(6) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(15), one C(9), and one N(1) atom. The C(13)-C(15) bond length is 1.50 Å. The C(13)-N(1) bond length is 1.38 Å. In the fourteenth C site, C(14) is bonded in a tetrahedral geometry to one N(1), one H(7), one H(8), and one H(9) atom. The C(14)-N(1) bond length is 1.47 Å. The C(14)-H(7) bond length is 1.09 Å. The C(14)-H(8) bond length is 1.10 Å. The C(14)-H(9) bond length is 1.10 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one C(13), one H(10), one H(11), and one H(12) atom. The C(15)-H(10) bond length is 1.10 Å. The C(15)-H(11) bond length is 1.10 Å. The C(15)-H(12) bond length is 1.10 Å. N(1) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(14) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. There are six inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(8) atom. In the second O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Zn(2) and one C(9) atom. In the third O site, O(6) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(2), and one C(10) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the fifth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the sixth O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(8) atom. Linkers: 4 [O]C(=O)c1ccc(C([O])=O)cc1 ,3 CC1=C([O])C([O])=C[CH]N1C ,1 C[C]1C([O])=C([O])C=CN1C. Metal clusters: 6 [Zn]. The MOF has largest included sphere 4.32 A, density 1.39 g/cm3, surface area 3901.15 m2/g, accessible volume 0.34 cm3/g