CdC14H9(NO)4CH2 crystallizes in the monoclinic C2/c space group. The structure consists of eight 02329_fluka molecules inside a CdC14H9(NO)4 framework. In the CdC14H9(NO)4 framework, Cd(1) is bonded in a distorted octahedral geometry to one N(1), one N(4), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.41 Å. The Cd(1)-N(4) bond length is 2.31 Å. The Cd(1)-O(1) bond length is 2.24 Å. The Cd(1)-O(2) bond length is 2.39 Å. The Cd(1)-O(3) bond length is 2.41 Å. The Cd(1)-O(4) bond length is 2.43 Å. There are fourteen inequivalent C sites. In the first C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(4), and one H(7) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-N(4) bond length is 1.35 Å. The C(9)-H(7) bond length is 1.09 Å. In the second C site, C(10) is bonded in a distorted single-bond geometry to one C(6), one C(9), and one H(8) atom. The C(10)-C(6) bond length is 1.42 Å. The C(10)-H(8) bond length is 1.09 Å. In the third C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(11)-C(12) bond length is 1.51 Å. The C(11)-O(1) bond length is 1.28 Å. The C(11)-O(2) bond length is 1.26 Å. In the fourth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one N(2) atom. The C(12)-C(13) bond length is 1.34 Å. The C(12)-N(2) bond length is 1.44 Å. In the fifth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(13)-H(11) bond length is 1.09 Å. In the sixth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(15)-O(3) bond length is 1.27 Å. The C(15)-O(4) bond length is 1.28 Å. In the seventh C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the eighth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the ninth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one N(2) atom. The C(3)-N(2) bond length is 1.40 Å. In the tenth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(3) bond length is 1.09 Å. In the eleventh C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the twelfth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(10), one C(7), and one N(3) atom. The C(6)-C(7) bond length is 1.42 Å. The C(6)-N(3) bond length is 1.36 Å. In the thirteenth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.38 Å. The C(7)-H(5) bond length is 1.09 Å. In the fourteenth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one N(4), and one H(6) atom. The C(8)-N(4) bond length is 1.35 Å. The C(8)-H(6) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(12), one C(3), and one N(3) atom. The N(2)-N(3) bond length is 1.33 Å. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one C(6) and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(8), and one C(9) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(15) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(15) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(11) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(11) atom. Linkers: 4 [O]C(=O)C/C=C(/C([O])=O)N([N]c1ccncc1)c1ccncc1. Metal clusters: 2 [C]1O[Cd]2(O1)O[C]O[Cd]1(O[C]O1)O[C]O2. The MOF has largest included sphere 6.20 A, density 1.34 g/cm3, surface area 4010.33 m2/g, accessible volume 0.29 cm3/g