CoC22H18(N4O3)2(CH2)4(CH)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, four 02329_fluka molecules, and one CoC22H18(N4O3)2 cluster. In the CoC22H18(N4O3)2 cluster, Co(1) is bonded in a distorted octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(3) atoms. Both Co(1)-N(1) bond lengths are 1.92 Å. Both Co(1)-O(1) bond lengths are 1.95 Å. Both Co(1)-O(3) bond lengths are 2.35 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(2)-C(3) bond length is 1.46 Å. The C(2)-C(5) bond length is 1.40 Å. The C(2)-C(9) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one N(4) atom. The C(3)-N(2) bond length is 1.36 Å. The C(3)-N(4) bond length is 1.34 Å. In the fourth C site, C(4) is bonded in a distorted water-like geometry to one C(7), one N(2), and one N(3) atom. The C(4)-C(7) bond length is 1.46 Å. The C(4)-N(2) bond length is 1.34 Å. The C(4)-N(3) bond length is 1.36 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(3) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one H(4) atom. The C(6)-C(11) bond length is 1.39 Å. The C(6)-N(1) bond length is 1.35 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(4) atom. The C(7)-C(12) bond length is 1.40 Å. The C(7)-C(13) bond length is 1.40 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(2) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(6) and one H(10) atom. The C(11)-H(10) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(11) atom. The C(12)-H(11) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(7) and one H(12) atom. The C(13)-H(12) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(5), and one C(6) atom. In the second N site, N(2) is bonded in a water-like geometry to one C(3) and one C(4) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to one C(4), one N(4), and one H(2) atom. The N(3)-N(4) bond length is 1.35 Å. The N(3)-H(2) bond length is 1.04 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one C(3) and one N(3) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. The H(1)-O(3) bond length is 1.00 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one O(3) atom. The H(16)-O(3) bond length is 0.98 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Co(1), one H(1), and one H(16) atom. Linkers: 1 [O]C(=O)CCCCC([O])=O. Metal clusters: 1 [Co]. The MOF has largest included sphere 2.15 A, density 1.54 g/cm3, surface area 4726.07 m2/g, accessible volume 0.11 cm3/g