CuC11N5H9I(CH)4CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two 02329_fluka molecules, and one CuC11N5H9I cluster. In the CuC11N5H9I cluster, Cu(1) is bonded in a distorted water-like geometry to one N(1), one N(5), and two equivalent I(1) atoms. The Cu(1)-N(1) bond length is 2.03 Å. The Cu(1)-N(5) bond length is 2.03 Å. There is one shorter (2.63 Å) and one longer (2.68 Å) Cu(1)-I(1) bond length. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.37 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one N(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.42 Å. The C(2)-N(2) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(5) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one N(1) atom. The C(7)-N(1) bond length is 1.39 Å. In the sixth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(6), and one H(7) atom. The C(8)-N(2) bond length is 1.46 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-H(7) bond length is 1.10 Å. In the seventh C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(10), and one H(11) atom. The C(10)-N(3) bond length is 1.45 Å. The C(10)-H(10) bond length is 1.10 Å. The C(10)-H(11) bond length is 1.10 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(16), and one N(5) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(16) bond length is 1.41 Å. The C(11)-N(5) bond length is 1.38 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(12) atom. The C(12)-H(12) bond length is 1.09 Å. In the tenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(15) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(15) bond length is 1.09 Å. In the eleventh C site, C(16) is bonded in a distorted single-bond geometry to one C(11), one C(15), and one N(3) atom. The C(16)-N(3) bond length is 1.37 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(8) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(10), one C(16), and one N(4) atom. The N(3)-N(4) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one N(3) and one N(5) atom. The N(4)-N(5) bond length is 1.31 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(11), and one N(4) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 2 c1ccc2c(c1)ncn2CCCn1nnc2ccccc21. Metal clusters: 1 I[Cu][Cu]I. The MOF has largest included sphere 2.13 A, density 2.01 g/cm3, surface area 3952.02 m2/g, accessible volume 0.12 cm3/g