Ag2C4H10S3O5 crystallizes in the orthorhombic Pnma space group. Ag(1) is bonded in a 5-coordinate geometry to two equivalent S(2), one O(1), one O(2), and one O(4) atom. There is one shorter (2.53 Å) and one longer (2.70 Å) Ag(1)-S(2) bond length. The Ag(1)-O(1) bond length is 2.58 Å. The Ag(1)-O(2) bond length is 2.49 Å. The Ag(1)-O(4) bond length is 2.50 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one H(1), one H(2), and one S(2) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-S(2) bond length is 1.82 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one H(3), one H(4), and one S(2) atom. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. The C(2)-S(2) bond length is 1.82 Å. There are six inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(5) is bonded in a distorted single-bond geometry to one O(3) and one O(4) atom. The H(5)-O(3) bond length is 1.67 Å. The H(5)-O(4) bond length is 1.00 Å. In the fourth H site, H(6) is bonded in a single-bond geometry to one O(4) atom. The H(6)-O(4) bond length is 0.99 Å. In the fifth H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(3) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. The S(1)-O(1) bond length is 1.50 Å. The S(1)-O(3) bond length is 1.51 Å. Both S(1)-O(2) bond lengths are 1.49 Å. In the second S site, S(2) is bonded to two equivalent Ag(1), one C(1), and one C(2) atom to form distorted corner-sharing SAg2C2 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one H(5) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to two equivalent Ag(1), one H(5), and one H(6) atom. Linkers: 4 C1CSCCS1. Metal clusters: 8 [Ag]. The MOF has largest included sphere 1.50 A, density 3.08 g/cm3, surface area 2067.57 m2/g, accessible volume 0.05 cm3/g