CdC14H8(NO2)2C8H8O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 4-methylanisole molecules and one CdC14H8(NO2)2 cluster. In the CdC14H8(NO2)2 cluster, Cd(1) is bonded to one N(1), one N(2), one O(1), one O(2), and two equivalent O(4) atoms to form distorted edge-sharing CdN2O4 pentagonal pyramids. The Cd(1)-N(1) bond length is 2.42 Å. The Cd(1)-N(2) bond length is 2.34 Å. The Cd(1)-O(1) bond length is 2.45 Å. The Cd(1)-O(2) bond length is 2.34 Å. There is one shorter (2.28 Å) and one longer (2.36 Å) Cd(1)-O(4) bond length. There are fourteen inequivalent C sites. In the first C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(8)-O(1) bond length is 1.27 Å. The C(8)-O(2) bond length is 1.28 Å. In the second C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(10)-O(4) bond length is 1.31 Å. The C(10)-O(5) bond length is 1.24 Å. In the third C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(1), and one H(9) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-N(1) bond length is 1.33 Å. The C(11)-H(9) bond length is 1.09 Å. In the fourth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(10) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-H(10) bond length is 1.09 Å. In the fifth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(11) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-H(11) bond length is 1.09 Å. In the sixth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(21) atom. The C(14)-C(15) bond length is 1.42 Å. The C(14)-C(21) bond length is 1.43 Å. In the seventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one N(1) atom. The C(15)-C(16) bond length is 1.45 Å. The C(15)-N(1) bond length is 1.35 Å. In the eighth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one N(2) atom. The C(16)-C(17) bond length is 1.42 Å. The C(16)-N(2) bond length is 1.36 Å. In the ninth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(22) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-C(22) bond length is 1.43 Å. In the tenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(12) atom. The C(18)-C(19) bond length is 1.38 Å. The C(18)-H(12) bond length is 1.09 Å. In the eleventh C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(13) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-H(13) bond length is 1.09 Å. In the twelfth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(2), and one H(14) atom. The C(20)-N(2) bond length is 1.33 Å. The C(20)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(14) and one H(15) atom. The C(21)-H(15) bond length is 1.09 Å. In the fourteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(17) and one H(16) atom. The C(22)-H(16) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one C(15) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(16), and one C(20) atom. There are eight inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(8) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(8) atom. In the third O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(10) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(10) atom. Linkers: 2 c1cnc2c(c1)ccc1cccnc12 ,2 [O]C(=O)COc1ccc(CC([O])=O)cc1. Metal clusters: 1 O=[C]O[Cd]1O[C]O1.O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 3.64 A, density 1.58 g/cm3, surface area 4239.70 m2/g, accessible volume 0.20 cm3/g