Cd2C41N6H27O11 crystallizes in the triclinic P-1 space group. There are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a pentagonal bipyramidal geometry to one N(2), one N(7), one O(13), one O(15), one O(17), one O(19), and one O(21) atom. The Cd(1)-N(2) bond length is 2.36 Å. The Cd(1)-N(7) bond length is 2.34 Å. The Cd(1)-O(13) bond length is 2.48 Å. The Cd(1)-O(15) bond length is 2.49 Å. The Cd(1)-O(17) bond length is 2.59 Å. The Cd(1)-O(19) bond length is 2.40 Å. The Cd(1)-O(21) bond length is 2.41 Å. In the second Cd site, Cd(2) is bonded in a pentagonal bipyramidal geometry to one N(1), one N(8), one O(14), one O(16), one O(18), one O(20), and one O(22) atom. The Cd(2)-N(1) bond length is 2.36 Å. The Cd(2)-N(8) bond length is 2.34 Å. The Cd(2)-O(14) bond length is 2.48 Å. The Cd(2)-O(16) bond length is 2.49 Å. The Cd(2)-O(18) bond length is 2.59 Å. The Cd(2)-O(20) bond length is 2.40 Å. The Cd(2)-O(22) bond length is 2.41 Å. In the third Cd site, Cd(3,4) is bonded in a distorted trigonal bipyramidal geometry to one N(9), one O(11), one O(5), one O(7), and one O(9) atom. The Cd(3,4)-N(9) bond length is 2.22 Å. The Cd(3,4)-O(11) bond length is 2.36 Å. The Cd(3,4)-O(5) bond length is 2.26 Å. The Cd(3,4)-O(7) bond length is 2.24 Å. The Cd(3,4)-O(9) bond length is 2.23 Å. There are sixty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3,4); one N(1); and one H(7,8) atom. The C(1)-C(3,4) bond length is 1.37 Å. The C(1)-N(1) bond length is 1.38 Å. The C(1)-H(7,8) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3,4); one N(2); and one H(7,8) atom. The C(2)-C(3,4) bond length is 1.37 Å. The C(2)-N(2) bond length is 1.38 Å. The C(2)-H(7,8) bond length is 1.08 Å. In the third C site, C(3,4) is bonded in a distorted bent 120 degrees geometry to one C(1); one N(3,4); and one H(9,10) atom. The C(3,4)-N(3,4) bond length is 1.39 Å. The C(3,4)-H(9,10) bond length is 1.08 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one N(1); one N(3,4); and one H(11,12) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-N(3,4) bond length is 1.37 Å. The C(5)-H(11,12) bond length is 1.08 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one N(2); one N(3,4); and one H(11,12) atom. The C(6)-N(2) bond length is 1.33 Å. The C(6)-N(3,4) bond length is 1.37 Å. The C(6)-H(11,12) bond length is 1.08 Å. In the sixth C site, C(7,8) is bonded in a distorted trigonal planar geometry to one C(17,18); one C(9,10); and one N(3,4) atom. The C(7,8)-C(17,18) bond length is 1.40 Å. The C(7,8)-C(9,10) bond length is 1.40 Å. The C(7,8)-N(3,4) bond length is 1.42 Å. In the seventh C site, C(9,10) is bonded in a distorted single-bond geometry to one C(7,8) and one H(13,14) atom. The C(9,10)-H(13,14) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(13) and one H(15,16) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-H(15,16) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(14) and one H(15,16) atom. The C(12)-C(14) bond length is 1.40 Å. The C(12)-H(15,16) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(11), one C(15), and one N(5) atom. The C(13)-C(15) bond length is 1.40 Å. The C(13)-N(5) bond length is 1.42 Å. In the eleventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(12), one C(16), and one N(6) atom. The C(14)-C(16) bond length is 1.40 Å. The C(14)-N(6) bond length is 1.42 Å. In the twelfth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(13); one C(17,18); and one H(17,18) atom. The C(15)-C(17,18) bond length is 1.39 Å. The C(15)-H(17,18) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(14); one C(17,18); and one H(17,18) atom. The C(16)-C(17,18) bond length is 1.39 Å. The C(16)-H(17,18) bond length is 1.09 Å. In the fourteenth C site, C(17,18) is bonded in a distorted trigonal planar geometry to one C(15); one C(7,8); and one H(19,20) atom. The C(17,18)-H(19,20) bond length is 1.09 Å. In the fifteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(21); one N(5); and one H(21,22) atom. The C(19)-C(21) bond length is 1.37 Å. The C(19)-N(5) bond length is 1.39 Å. The C(19)-H(21,22) bond length is 1.08 Å. In the sixteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(22); one N(6); and one H(21,22) atom. The C(20)-C(22) bond length is 1.37 Å. The C(20)-N(6) bond length is 1.39 Å. The C(20)-H(21,22) bond length is 1.08 Å. In the seventeenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(19), one N(7), and one H(23) atom. The C(21)-N(7) bond length is 1.38 Å. The C(21)-H(23) bond length is 1.08 Å. In the eighteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(20), one N(8), and one H(24) atom. The C(22)-N(8) bond length is 1.38 Å. The C(22)-H(24) bond length is 1.08 Å. In the nineteenth C site, C(23) is bonded in a trigonal planar geometry to one N(5); one N(7); and one H(25,26) atom. The C(23)-N(5) bond length is 1.37 Å. The C(23)-N(7) bond length is 1.32 Å. The C(23)-H(25,26) bond length is 1.08 Å. In the twentieth C site, C(24) is bonded in a trigonal planar geometry to one N(6); one N(8); and one H(25,26) atom. The C(24)-N(6) bond length is 1.37 Å. The C(24)-N(8) bond length is 1.32 Å. The C(24)-H(25,26) bond length is 1.08 Å. In the twenty-first C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(17), and one O(19) atom. The C(25)-C(27) bond length is 1.50 Å. The C(25)-O(17) bond length is 1.27 Å. The C(25)-O(19) bond length is 1.29 Å. In the twenty-second C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(18), and one O(20) atom. The C(26)-C(28) bond length is 1.50 Å. The C(26)-O(18) bond length is 1.27 Å. The C(26)-O(20) bond length is 1.29 Å. In the twenty-third C site, C(27) is bonded in a trigonal planar geometry to one C(25); one C(29,30); and one C(37,38) atom. The C(27)-C(29,30) bond length is 1.40 Å. The C(27)-C(37,38) bond length is 1.40 Å. In the twenty-fourth C site, C(28) is bonded in a trigonal planar geometry to one C(26); one C(29,30); and one C(37,38) atom. The C(28)-C(29,30) bond length is 1.40 Å. The C(28)-C(37,38) bond length is 1.40 Å. In the twenty-fifth C site, C(29,30) is bonded in a distorted single-bond geometry to one C(27); one C(31,32); and one H(27,28) atom. The C(29,30)-C(31,32) bond length is 1.40 Å. The C(29,30)-H(27,28) bond length is 1.09 Å. In the twenty-sixth C site, C(31,32) is bonded in a trigonal planar geometry to one C(29,30); one C(33,34); and one C(55,56) atom. The C(31,32)-C(33,34) bond length is 1.41 Å. The C(31,32)-C(55,56) bond length is 1.48 Å. In the twenty-seventh C site, C(33,34) is bonded in a distorted single-bond geometry to one C(31,32); one C(35,36); and one H(29,30) atom. The C(33,34)-C(35,36) bond length is 1.40 Å. The C(33,34)-H(29,30) bond length is 1.09 Å. In the twenty-eighth C site, C(35,36) is bonded in a trigonal planar geometry to one C(33,34); one C(37,38); and one C(39,40) atom. The C(35,36)-C(37,38) bond length is 1.40 Å. The C(35,36)-C(39,40) bond length is 1.49 Å. In the twenty-ninth C site, C(37,38) is bonded in a distorted trigonal planar geometry to one C(27); one C(35,36); and one H(31,32) atom. The C(37,38)-H(31,32) bond length is 1.09 Å. In the thirtieth C site, C(39,40) is bonded in a trigonal planar geometry to one C(35,36); one C(41,42); and one C(49) atom. The C(39,40)-C(41,42) bond length is 1.41 Å. The C(39,40)-C(49) bond length is 1.41 Å. In the thirty-first C site, C(41,42) is bonded in a distorted single-bond geometry to one C(39,40) and one H(33,34) atom. The C(41,42)-H(33,34) bond length is 1.09 Å. In the thirty-second C site, C(43,44) is bonded in a distorted single-bond geometry to one C(45) and one H(35,36) atom. The C(43,44)-C(45) bond length is 1.40 Å. The C(43,44)-H(35,36) bond length is 1.09 Å. In the thirty-third C site, C(45) is bonded in a trigonal planar geometry to one C(43,44); one C(47,48); and one C(51) atom. The C(45)-C(47,48) bond length is 1.40 Å. The C(45)-C(51) bond length is 1.49 Å. In the thirty-fourth C site, C(46) is bonded in a trigonal planar geometry to one C(43,44); one C(47,48); and one C(52) atom. The C(46)-C(43,44) bond length is 1.40 Å. The C(46)-C(47,48) bond length is 1.40 Å. The C(46)-C(52) bond length is 1.49 Å. In the thirty-fifth C site, C(47,48) is bonded in a distorted single-bond geometry to one C(45); one C(49); and one H(37,38) atom. The C(47,48)-C(49) bond length is 1.39 Å. The C(47,48)-H(37,38) bond length is 1.09 Å. In the thirty-sixth C site, C(49) is bonded in a trigonal planar geometry to one C(39,40); one C(47,48); and one C(53,54) atom. The C(49)-C(53,54) bond length is 1.50 Å. In the thirty-seventh C site, C(50) is bonded in a trigonal planar geometry to one C(39,40); one C(47,48); and one C(53,54) atom. The C(50)-C(39,40) bond length is 1.41 Å. The C(50)-C(47,48) bond length is 1.39 Å. The C(50)-C(53,54) bond length is 1.50 Å. In the thirty-eighth C site, C(51) is bonded in a distorted bent 120 degrees geometry to one C(45), one O(1), and one O(3) atom. The C(51)-O(1) bond length is 1.23 Å. The C(51)-O(3) bond length is 1.34 Å. In the thirty-ninth C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(46), one O(2), and one O(4) atom. The C(52)-O(2) bond length is 1.23 Å. The C(52)-O(4) bond length is 1.34 Å. In the fortieth C site, C(53,54) is bonded in a distorted bent 120 degrees geometry to one C(49), one O(5), and one O(7) atom. The C(53,54)-O(5) bond length is 1.27 Å. The C(53,54)-O(7) bond length is 1.27 Å. In the forty-first C site, C(55,56) is bonded in a trigonal planar geometry to one C(31,32); one C(57,58); and one C(65) atom. The C(55,56)-C(57,58) bond length is 1.41 Å. The C(55,56)-C(65) bond length is 1.41 Å. In the forty-second C site, C(57,58) is bonded in a distorted single-bond geometry to one C(55,56) and one H(39,40) atom. The C(57,58)-H(39,40) bond length is 1.09 Å. In the forty-third C site, C(59) is bonded in a distorted single-bond geometry to one C(61) and one H(41,42) atom. The C(59)-C(61) bond length is 1.40 Å. The C(59)-H(41,42) bond length is 1.09 Å. In the forty-fourth C site, C(60) is bonded in a distorted single-bond geometry to one C(62) and one H(41,42) atom. The C(60)-C(62) bond length is 1.40 Å. The C(60)-H(41,42) bond length is 1.09 Å. In the forty-fifth C site, C(61) is bonded in a trigonal planar geometry to one C(59), one C(63), and one C(67) atom. The C(61)-C(63) bond length is 1.40 Å. The C(61)-C(67) bond length is 1.49 Å. In the forty-sixth C site, C(62) is bonded in a trigonal planar geometry to one C(60), one C(64), and one C(68) atom. The C(62)-C(64) bond length is 1.40 Å. The C(62)-C(68) bond length is 1.49 Å. In the forty-seventh C site, C(63) is bonded in a distorted trigonal planar geometry to one C(61); one C(65); and one H(43,44) atom. The C(63)-C(65) bond length is 1.39 Å. The C(63)-H(43,44) bond length is 1.09 Å. In the forty-eighth C site, C(64) is bonded in a distorted trigonal planar geometry to one C(62); one C(66); and one H(43,44) atom. The C(64)-C(66) bond length is 1.39 Å. The C(64)-H(43,44) bond length is 1.09 Å. In the forty-ninth C site, C(65) is bonded in a trigonal planar geometry to one C(55,56); one C(63); and one C(69,70) atom. The C(65)-C(69,70) bond length is 1.50 Å. In the fiftieth C site, C(66) is bonded in a trigonal planar geometry to one C(55,56); one C(64); and one C(69,70) atom. The C(66)-C(55,56) bond length is 1.41 Å. The C(66)-C(69,70) bond length is 1.50 Å. In the fifty-first C site, C(67) is bonded in a distorted bent 120 degrees geometry to one C(61), one O(13), and one O(15) atom. The C(67)-O(13) bond length is 1.27 Å. The C(67)-O(15) bond length is 1.28 Å. In the fifty-second C site, C(68) is bonded in a distorted bent 120 degrees geometry to one C(62), one O(14), and one O(16) atom. The C(68)-O(14) bond length is 1.27 Å. The C(68)-O(16) bond length is 1.28 Å. In the fifty-third C site, C(69,70) is bonded in a distorted bent 120 degrees geometry to one C(65), one O(11), and one O(9) atom. The C(69,70)-O(11) bond length is 1.27 Å. The C(69,70)-O(9) bond length is 1.27 Å. In the fifty-fourth C site, C(71,72) is bonded in a distorted single-bond geometry to one C(73) and one H(45) atom. The C(71,72)-C(73) bond length is 1.40 Å. The C(71,72)-H(45) bond length is 1.09 Å. In the fifty-fifth C site, C(73) is bonded in a distorted trigonal planar geometry to one C(71,72); one C(75,76); and one N(11) atom. The C(73)-C(75,76) bond length is 1.40 Å. The C(73)-N(11) bond length is 1.42 Å. In the fifty-sixth C site, C(74) is bonded in a distorted trigonal planar geometry to one C(71,72); one C(75,76); and one N(12) atom. The C(74)-C(71,72) bond length is 1.40 Å. The C(74)-C(75,76) bond length is 1.40 Å. The C(74)-N(12) bond length is 1.42 Å. In the fifty-seventh C site, C(75,76) is bonded in a distorted single-bond geometry to one C(73) and one H(47) atom. The C(75,76)-H(47) bond length is 1.09 Å. In the fifty-eighth C site, C(77) is bonded in a distorted bent 120 degrees geometry to one C(79,80); one N(11); and one H(49,50) atom. The C(77)-C(79,80) bond length is 1.37 Å. The C(77)-N(11) bond length is 1.39 Å. The C(77)-H(49,50) bond length is 1.08 Å. In the fifty-ninth C site, C(78) is bonded in a distorted bent 120 degrees geometry to one C(79,80); one N(12); and one H(49,50) atom. The C(78)-C(79,80) bond length is 1.37 Å. The C(78)-N(12) bond length is 1.39 Å. The C(78)-H(49,50) bond length is 1.08 Å. In the sixtieth C site, C(79,80) is bonded in a distorted trigonal planar geometry to one C(77), one N(9), and one H(51) atom. The C(79,80)-N(9) bond length is 1.38 Å. The C(79,80)-H(51) bond length is 1.08 Å. In the sixty-first C site, C(81) is bonded in a trigonal planar geometry to one N(11), one N(9), and one H(53) atom. The C(81)-N(11) bond length is 1.36 Å. The C(81)-N(9) bond length is 1.33 Å. The C(81)-H(53) bond length is 1.09 Å. In the sixty-second C site, C(82) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(54) atom. The C(82)-N(10) bond length is 1.33 Å. The C(82)-N(12) bond length is 1.36 Å. The C(82)-H(54) bond length is 1.09 Å. There are eleven inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(2), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(2), and one C(6) atom. In the third N site, N(3,4) is bonded in a trigonal planar geometry to one C(3,4); one C(5); and one C(7,8) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one C(13), one C(19), and one C(23) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one C(14), one C(20), and one C(24) atom. In the sixth N site, N(7) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(21), and one C(23) atom. In the seventh N site, N(8) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(22), and one C(24) atom. In the eighth N site, N(9) is bonded in a trigonal planar geometry to one Cd(3,4); one C(79,80); and one C(81) atom. In the ninth N site, N(10) is bonded in a trigonal planar geometry to one Cd(3,4); one C(79,80); and one C(82) atom. The N(10)-Cd(3,4) bond length is 2.22 Å. The N(10)-C(79,80) bond length is 1.38 Å. In the tenth N site, N(11) is bonded in a trigonal planar geometry to one C(73), one C(77), and one C(81) atom. In the eleventh N site, N(12) is bonded in a trigonal planar geometry to one C(74), one C(78), and one C(82) atom. There are thirty-five inequivalent H sites. In the first H site, H(1) is bonded in a distorted bent 150 degrees geometry to one O(15) and one O(3) atom. The H(1)-O(15) bond length is 1.55 Å. The H(1)-O(3) bond length is 1.03 Å. In the second H site, H(2) is bonded in a distorted bent 150 degrees geometry to one O(16) and one O(4) atom. The H(2)-O(16) bond length is 1.55 Å. The H(2)-O(4) bond length is 1.03 Å. In the third H site, H(3) is bonded in a distorted linear geometry to one O(20) and one O(21) atom. The H(3)-O(20) bond length is 1.66 Å. The H(3)-O(21) bond length is 1.00 Å. In the fourth H site, H(4) is bonded in a distorted linear geometry to one O(19) and one O(22) atom. The H(4)-O(19) bond length is 1.66 Å. The H(4)-O(22) bond length is 1.00 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(21) atom. The H(5)-O(21) bond length is 0.98 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(22) atom. The H(6)-O(22) bond length is 0.98 Å. In the seventh H site, H(7,8) is bonded in a single-bond geometry to one C(1) atom. In the eighth H site, H(9,10) is bonded in a single-bond geometry to one C(3,4) atom. In the ninth H site, H(11,12) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(13,14) is bonded in a single-bond geometry to one C(9,10) atom. In the eleventh H site, H(15,16) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(17,18) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(19,20) is bonded in a single-bond geometry to one C(17,18) atom. In the fourteenth H site, H(21,22) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(23) is bonded in a single-bond geometry to one C(21) atom. In the sixteenth H site, H(24) is bonded in a single-bond geometry to one C(22) atom. In the seventeenth H site, H(25,26) is bonded in a single-bond geometry to one C(23) atom. In the eighteenth H site, H(27,28) is bonded in a single-bond geometry to one C(29,30) atom. In the nineteenth H site, H(29,30) is bonded in a single-bond geometry to one C(33,34) atom. In the twentieth H site, H(31,32) is bonded in a single-bond geometry to one C(37,38) atom. In the twenty-first H site, H(33,34) is bonded in a single-bond geometry to one C(41,42) atom. In the twenty-second H site, H(35,36) is bonded in a single-bond geometry to one C(43,44) atom. In the twenty-third H site, H(37,38) is bonded in a single-bond geometry to one C(47,48) atom. In the twenty-fourth H site, H(39,40) is bonded in a single-bond geometry to one C(57,58) atom. In the twenty-fifth H site, H(41,42) is bonded in a single-bond geometry to one C(59) atom. In the twenty-sixth H site, H(43,44) is bonded in a single-bond geometry to one C(63) atom. In the twenty-seventh H site, H(45) is bonded in a single-bond geometry to one C(71,72) atom. In the twenty-eighth H site, H(46) is bonded in a single-bond geometry to one C(71,72) atom. The H(46)-C(71,72) bond length is 1.09 Å. In the twenty-ninth H site, H(47) is bonded in a single-bond geometry to one C(75,76) atom. In the thirtieth H site, H(48) is bonded in a single-bond geometry to one C(75,76) atom. The H(48)-C(75,76) bond length is 1.09 Å. In the thirty-first H site, H(49,50) is bonded in a single-bond geometry to one C(77) atom. In the thirty-second H site, H(51) is bonded in a single-bond geometry to one C(79,80) atom. In the thirty-third H site, H(52) is bonded in a single-bond geometry to one C(79,80) atom. The H(52)-C(79,80) bond length is 1.08 Å. In the thirty-fourth H site, H(53) is bonded in a single-bond geometry to one C(81) atom. In the thirty-fifth H site, H(54) is bonded in a single-bond geometry to one C(82) atom. There are twenty-two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(51) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(52) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(51) and one H(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(52) and one H(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cd(3,4) and one C(53,54) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cd(3,4) and one C(53,54) atom. The O(6)-Cd(3,4) bond length is 2.26 Å. The O(6)-C(53,54) bond length is 1.27 Å. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cd(3,4) and one C(53,54) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cd(3,4) and one C(53,54) atom. The O(8)-Cd(3,4) bond length is 2.24 Å. The O(8)-C(53,54) bond length is 1.27 Å. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Cd(3,4) and one C(69,70) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Cd(3,4) and one C(69,70) atom. The O(10)-Cd(3,4) bond length is 2.23 Å. The O(10)-C(69,70) bond length is 1.27 Å. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Cd(3,4) and one C(69,70) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Cd(3,4) and one C(69,70) atom. The O(12)-Cd(3,4) bond length is 2.36 Å. The O(12)-C(69,70) bond length is 1.27 Å. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Cd(1) and one C(67) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Cd(2) and one C(68) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Cd(1), one C(67), and one H(1) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Cd(2), one C(68), and one H(2) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one Cd(1) and one C(25) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one Cd(2) and one C(26) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Cd(1), one C(25), and one H(4) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Cd(2), one C(26), and one H(3) atom. In the twenty-first O site, O(21) is bonded in a distorted water-like geometry to one Cd(1), one H(3), and one H(5) atom. In the twenty-second O site, O(22) is bonded in a distorted water-like geometry to one Cd(2), one H(4), and one H(6) atom. Linkers: 6 c1cn(-c2ccc(-n3ccnc3)cc2)cn1 ,4 [O]C(=O)c1cc(-c2ccc(C([O])=O)cc2C([O])=O)cc(-c2ccc(C(=O)O)cc2C([O])=O)c1. Metal clusters: 4 O.O=[C]O[Cd]1O[C]O1 ,2 [C]1O[Cd]234O[C]O[Cd]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 4.75 A, density 1.55 g/cm3, surface area 4043.44 m2/g, accessible volume 0.23 cm3/g