Cd2C46H32S(N2O3)4C6H4SO2 crystallizes in the monoclinic P2/c space group. The structure consists of two di-isopropenylsulfon molecules inside a Cd2C46H32S(N2O3)4 framework. In the Cd2C46H32S(N2O3)4 framework, Cd(1) is bonded in a distorted octahedral geometry to one N(3), one N(4), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(3) bond length is 2.34 Å. The Cd(1)-N(4) bond length is 2.32 Å. The Cd(1)-O(1) bond length is 2.57 Å. The Cd(1)-O(2) bond length is 2.28 Å. The Cd(1)-O(3) bond length is 2.27 Å. The Cd(1)-O(4) bond length is 2.35 Å. There are twenty-three inequivalent C sites. In the first C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(1), and one O(4) atom. The C(14)-C(16) bond length is 1.50 Å. The C(14)-O(1) bond length is 1.29 Å. The C(14)-O(4) bond length is 1.27 Å. In the second C site, C(15) is bonded in a trigonal planar geometry to one C(11), one C(21), and one C(25) atom. The C(15)-C(11) bond length is 1.40 Å. The C(15)-C(21) bond length is 1.40 Å. The C(15)-C(25) bond length is 1.50 Å. In the third C site, C(16) is bonded in a trigonal planar geometry to one C(14), one C(22), and one C(23) atom. The C(16)-C(22) bond length is 1.40 Å. The C(16)-C(23) bond length is 1.41 Å. In the fourth C site, C(17) is bonded in a distorted single-bond geometry to one C(19) and one H(10) atom. The C(17)-C(19) bond length is 1.39 Å. The C(17)-H(10) bond length is 1.09 Å. In the fifth C site, C(19) is bonded in a trigonal planar geometry to one C(17), one C(20), and one S(2) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-S(2) bond length is 1.78 Å. In the sixth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(23), and one H(12) atom. The C(20)-C(23) bond length is 1.39 Å. The C(20)-H(12) bond length is 1.09 Å. In the seventh C site, C(21) is bonded in a distorted single-bond geometry to one C(15) and one H(13) atom. The C(21)-H(13) bond length is 1.09 Å. In the eighth C site, C(22) is bonded in a distorted single-bond geometry to one C(16) and one H(14) atom. The C(22)-H(14) bond length is 1.09 Å. In the ninth C site, C(23) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one H(15) atom. The C(23)-H(15) bond length is 1.09 Å. In the tenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(7), one N(4), and one H(16) atom. The C(24)-C(7) bond length is 1.38 Å. The C(24)-N(4) bond length is 1.35 Å. The C(24)-H(16) bond length is 1.09 Å. In the eleventh C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(2), and one O(3) atom. The C(25)-O(2) bond length is 1.27 Å. The C(25)-O(3) bond length is 1.28 Å. In the twelfth C site, C(1) is bonded in a distorted single-bond geometry to one C(5), one C(6), and one H(1) atom. The C(1)-C(5) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the thirteenth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one O(6) atom. The C(2)-C(6) bond length is 1.50 Å. The C(2)-N(1) bond length is 1.38 Å. The C(2)-O(6) bond length is 1.23 Å. In the fourteenth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(12), one N(3), and one H(2) atom. The C(3)-C(12) bond length is 1.39 Å. The C(3)-N(3) bond length is 1.35 Å. The C(3)-H(2) bond length is 1.09 Å. In the fifteenth C site, C(4) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(7) atom. The C(4)-C(10) bond length is 1.40 Å. The C(4)-C(13) bond length is 1.45 Å. The C(4)-C(7) bond length is 1.41 Å. In the sixteenth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(1), one N(3), and one H(3) atom. The C(5)-N(3) bond length is 1.34 Å. The C(5)-H(3) bond length is 1.09 Å. In the seventeenth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(12), and one C(2) atom. The C(6)-C(12) bond length is 1.40 Å. In the eighteenth C site, C(7) is bonded in a distorted single-bond geometry to one C(24), one C(4), and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the nineteenth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(4), and one H(5) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-N(4) bond length is 1.35 Å. The C(9)-H(5) bond length is 1.09 Å. In the twentieth C site, C(10) is bonded in a distorted single-bond geometry to one C(4), one C(9), and one H(6) atom. The C(10)-H(6) bond length is 1.09 Å. In the twenty-first C site, C(11) is bonded in a distorted single-bond geometry to one C(15) and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. In the twenty-second C site, C(12) is bonded in a distorted single-bond geometry to one C(3), one C(6), and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. In the twenty-third C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(9) atom. The C(13)-N(2) bond length is 1.30 Å. The C(13)-H(9) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one C(2), one N(2), and one H(18) atom. The N(1)-N(2) bond length is 1.35 Å. The N(1)-H(18) bond length is 1.04 Å. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(13) and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(3), and one C(5) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(24), and one C(9) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one N(1) atom. S(2) is bonded in a distorted bent 120 degrees geometry to two equivalent C(19) and two equivalent O(7) atoms. Both S(2)-O(7) bond lengths are 1.45 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(14) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(25) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(25) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Cd(1) and one C(14) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(2) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one S(2) atom. Linkers: 4 [O]C(=O)c1ccc(S(=O)(=O)c2ccc(C([O])=O)cc2)cc1 ,4 O=C(N/N=C/c1ccncc1)c1ccncc1. Metal clusters: 2 [O][C]O[Cd]1O[C]O[Cd](O[C][O])O[C]O1. The MOF has largest included sphere 4.62 A, density 1.32 g/cm3, surface area 4495.23 m2/g, accessible volume 0.29 cm3/g