CoC24H20(N2F)2 is alpha Po structured and crystallizes in the tetragonal P-4c2 space group. The structure is zero-dimensional and consists of two CoC24H20(N2F)2 clusters. Co(1) is bonded in an octahedral geometry to four equivalent N(1) and two equivalent F(1) atoms. All Co(1)-N(1) bond lengths are 2.03 Å. Both Co(1)-F(1) bond lengths are 1.88 Å. There are six inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(2) bond length is 1.41 Å. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.50 Å. In the second C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(6)-H(5) bond length is 1.10 Å. N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. F(1) is bonded in a single-bond geometry to one Co(1) atom. Linkers: 2 c1cc([C@H]2[C@H](c3ccncc3)[C@@H](c3ccncc3)[C@@H]2c2ccncc2)ccn1. Metal clusters: 2 F[Co]F. The MOF has largest included sphere 3.40 A, density 1.38 g/cm3, surface area 4655.01 m2/g, accessible volume 0.17 cm3/g