CuC10H14(NO4)2CH2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and four CuC10H14(NO4)2 clusters. In each CuC10H14(NO4)2 cluster, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent O(2) atoms. Both Cu(1)-N(1) bond lengths are 2.08 Å. Both Cu(1)-O(2) bond lengths are 1.94 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.29 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(2)-N(1) bond length is 1.48 Å. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(3), and one H(4) atom. The C(3)-N(1) bond length is 1.49 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(4) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a 3-coordinate geometry to one N(1), one H(5), and one H(6) atom. The C(4)-N(1) bond length is 1.49 Å. The C(4)-H(5) bond length is 1.10 Å. The C(4)-H(6) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(6)-O(3) bond length is 1.33 Å. The C(6)-O(4) bond length is 1.23 Å. N(1) is bonded to one Cu(1), one C(2), one C(3), and one C(4) atom to form corner-sharing NCuC3 tetrahedra. There are seven inequivalent H sites. In the first H site, H(8) is bonded in a linear geometry to one O(1) and one O(3) atom. The H(8)-O(1) bond length is 1.58 Å. The H(8)-O(3) bond length is 1.02 Å. In the second H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(6) is bonded in a single-bond geometry to one C(4) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a water-like geometry to one C(6) and one H(8) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(6) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one C(1) and one H(8) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. Linkers: 1 [O]C(=O)CN(CCCN(CC([O])=O)CC(=O)O)CC(=O)O. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.47 A, density 1.75 g/cm3, surface area 3896.12 m2/g, accessible volume 0.11 cm3/g