Co2C35N4H25O11(CH)5CH2CO is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of five 02329_fluka molecules, one dimethyl ether molecule, and one Co2C35N4H25O11 cluster. In the Co2C35N4H25O11 cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted octahedral geometry to one N(1), one N(3), one O(1), one O(11), one O(3), and one O(7) atom. The Co(1)-N(1) bond length is 1.89 Å. The Co(1)-N(3) bond length is 1.91 Å. The Co(1)-O(1) bond length is 2.00 Å. The Co(1)-O(11) bond length is 2.12 Å. The Co(1)-O(3) bond length is 2.31 Å. The Co(1)-O(7) bond length is 1.95 Å. In the second Co site, Co(2) is bonded in a distorted octahedral geometry to one N(2), one N(4), one O(12), one O(2), one O(4), and one O(8) atom. The Co(2)-N(2) bond length is 2.10 Å. The Co(2)-N(4) bond length is 2.06 Å. The Co(2)-O(12) bond length is 2.03 Å. The Co(2)-O(2) bond length is 2.16 Å. The Co(2)-O(4) bond length is 2.24 Å. The Co(2)-O(8) bond length is 2.05 Å. There are thirty-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(5) atom. The C(1)-C(3) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(5) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one H(6) atom. The C(2)-C(4) bond length is 1.40 Å. The C(2)-N(2) bond length is 1.33 Å. The C(2)-H(6) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(7) atom. The C(3)-C(5) bond length is 1.39 Å. The C(3)-H(7) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(8) atom. The C(4)-C(6) bond length is 1.38 Å. The C(4)-H(8) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(9) atom. The C(5)-C(7) bond length is 1.41 Å. The C(5)-H(9) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one H(10) atom. The C(6)-C(8) bond length is 1.41 Å. The C(6)-H(10) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(23), one C(5), and one C(9) atom. The C(7)-C(23) bond length is 1.41 Å. The C(7)-C(9) bond length is 1.43 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(24), and one C(6) atom. The C(8)-C(10) bond length is 1.43 Å. The C(8)-C(24) bond length is 1.42 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(7) and one H(11) atom. The C(9)-H(11) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(12) atom. The C(10)-H(12) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(13) and one H(13,27) atom. The C(11)-C(13) bond length is 1.43 Å. The C(11)-H(13,27) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(14) and one H(14) atom. The C(12)-C(14) bond length is 1.43 Å. The C(12)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(21) atom. The C(13)-C(15) bond length is 1.41 Å. The C(13)-C(21) bond length is 1.41 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(22) atom. The C(14)-C(16) bond length is 1.41 Å. The C(14)-C(22) bond length is 1.42 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(13) and one H(15) atom. The C(15)-H(15) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(14) and one H(16) atom. The C(16)-H(16) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a distorted trigonal planar geometry to one N(3) and one H(19) atom. The C(19)-N(3) bond length is 1.34 Å. The C(19)-H(19) bond length is 1.09 Å. In the eighteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(20) atom. The C(20)-N(4) bond length is 1.34 Å. The C(20)-H(20) bond length is 1.09 Å. In the nineteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(13), one C(23), and one N(3) atom. The C(21)-C(23) bond length is 1.41 Å. The C(21)-N(3) bond length is 1.37 Å. In the twentieth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(14), one C(24), and one N(4) atom. The C(22)-C(24) bond length is 1.43 Å. The C(22)-N(4) bond length is 1.36 Å. In the twenty-first C site, C(23) is bonded in a distorted trigonal planar geometry to one C(21), one C(7), and one N(1) atom. The C(23)-N(1) bond length is 1.37 Å. In the twenty-second C site, C(24) is bonded in a distorted trigonal planar geometry to one C(22), one C(8), and one N(2) atom. The C(24)-N(2) bond length is 1.36 Å. In the twenty-third C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(1), and one O(3) atom. The C(25)-C(27) bond length is 1.48 Å. The C(25)-O(1) bond length is 1.30 Å. The C(25)-O(3) bond length is 1.27 Å. In the twenty-fourth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(2), and one O(4) atom. The C(26)-C(28) bond length is 1.48 Å. The C(26)-O(2) bond length is 1.29 Å. The C(26)-O(4) bond length is 1.27 Å. In the twenty-fifth C site, C(27) is bonded in a trigonal planar geometry to one C(25), one C(29), and one C(37) atom. The C(27)-C(29) bond length is 1.40 Å. The C(27)-C(37) bond length is 1.41 Å. In the twenty-sixth C site, C(28) is bonded in a trigonal planar geometry to one C(26), one C(30), and one C(38) atom. The C(28)-C(30) bond length is 1.40 Å. The C(28)-C(38) bond length is 1.41 Å. In the twenty-seventh C site, C(29) is bonded in a distorted single-bond geometry to one C(27), one C(31), and one H(21) atom. The C(29)-C(31) bond length is 1.39 Å. The C(29)-H(21) bond length is 1.09 Å. In the twenty-eighth C site, C(30) is bonded in a distorted single-bond geometry to one C(28) and one H(22) atom. The C(30)-H(22) bond length is 1.09 Å. In the twenty-ninth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(29), one C(33), and one H(23) atom. The C(31)-C(33) bond length is 1.40 Å. The C(31)-H(23) bond length is 1.09 Å. In the thirtieth C site, C(33) is bonded in a distorted single-bond geometry to one C(31) and one O(5) atom. The C(33)-O(5) bond length is 1.36 Å. In the thirty-first C site, C(37) is bonded in a distorted single-bond geometry to one C(27) and one H(13,27) atom. The C(37)-H(13,27) bond length is 1.09 Å. In the thirty-second C site, C(38) is bonded in a distorted single-bond geometry to one C(28) and one H(28) atom. The C(38)-H(28) bond length is 1.09 Å. In the thirty-third C site, C(39) is bonded in a distorted trigonal non-coplanar geometry to one H(29,30); one H(31); and one O(5) atom. The C(39)-H(29,30) bond length is 1.10 Å. The C(39)-H(31) bond length is 1.10 Å. The C(39)-O(5) bond length is 1.42 Å. In the thirty-fourth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(9) atom. The C(41)-O(7) bond length is 1.28 Å. The C(41)-O(9) bond length is 1.26 Å. In the thirty-fifth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(8) atom. The C(42)-O(10) bond length is 1.27 Å. The C(42)-O(8) bond length is 1.27 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(23) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(2), one C(2), and one C(24) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(19), and one C(21) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(2), one C(20), and one C(22) atom. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(10) and one O(11) atom. The H(1)-O(10) bond length is 1.61 Å. The H(1)-O(11) bond length is 1.01 Å. In the second H site, H(2) is bonded in a linear geometry to one O(12) and one O(9) atom. The H(2)-O(12) bond length is 1.02 Å. The H(2)-O(9) bond length is 1.54 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(11) atom. The H(3)-O(11) bond length is 0.98 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(12) atom. The H(4)-O(12) bond length is 0.98 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(13,27) is bonded in a single-bond geometry to one C(11) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(30) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the twenty-second H site, H(28) is bonded in a single-bond geometry to one C(38) atom. In the twenty-third H site, H(29,30) is bonded in a single-bond geometry to one C(39) atom. In the twenty-fourth H site, H(31) is bonded in a single-bond geometry to one C(39) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Co(1) and one C(25) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Co(2) and one C(26) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Co(1) and one C(25) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Co(2) and one C(26) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(33) and one C(39) atom. In the sixth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(41) atom. In the seventh O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one C(42) atom. In the eighth O site, O(9) is bonded in a bent 120 degrees geometry to one C(41) and one H(2) atom. In the ninth O site, O(10) is bonded in a bent 120 degrees geometry to one C(42) and one H(1) atom. In the tenth O site, O(11) is bonded in a distorted water-like geometry to one Co(1), one H(1), and one H(3) atom. In the eleventh O site, O(12) is bonded in a distorted water-like geometry to one Co(2), one H(2), and one H(4) atom. Linkers: 2 [O]C(=O)COc1ccc(C([O])=O)cc1. Metal clusters: 2 O.O=[C]O[Co]1O[C]O1. The MOF has largest included sphere 1.98 A, density 1.67 g/cm3, surface area 4335.67 m2/g, accessible volume 0.11 cm3/g