AgC7H7(NO)2 crystallizes in the monoclinic C2/c space group. Ag(1) is bonded in a 6-coordinate geometry to two equivalent N(1), two equivalent H(4), and two equivalent O(1) atoms. Both Ag(1)-N(1) bond lengths are 2.23 Å. Both Ag(1)-H(4) bond lengths are 2.46 Å. Both Ag(1)-O(1) bond lengths are 2.69 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to two equivalent C(5) and one H(3) atom. Both C(1)-C(5) bond lengths are 1.39 Å. The C(1)-H(3) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(4) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(5) bond length is 1.40 Å. The C(2)-H(4) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(4) and two equivalent C(2) atoms. The C(3)-C(4) bond length is 1.52 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3) and two equivalent O(1) atoms. Both C(4)-O(1) bond lengths are 1.28 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(1), one C(2), and one N(1) atom. The C(5)-N(1) bond length is 1.43 Å. N(1) is bonded in a 2-coordinate geometry to one Ag(1), one C(5), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.03 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one Ag(1) and one C(2) atom. O(1) is bonded in a single-bond geometry to one Ag(1) and one C(4) atom. Linkers: 2 Nc1cc(N)cc(C([O])=O)c1. Metal clusters: 2 [Ag]. The MOF has largest included sphere 1.64 A, density 2.28 g/cm3, surface area 2982.21 m2/g, accessible volume 0.11 cm3/g