ZnC11NH9O5(CH2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two ZnC11NH9O5 clusters. In each ZnC11NH9O5 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), one O(3), and one O(5) atom. The Zn(1)-O(1) bond length is 2.01 Å. The Zn(1)-O(2) bond length is 1.99 Å. The Zn(1)-O(3) bond length is 1.99 Å. The Zn(1)-O(5) bond length is 2.00 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.49 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(8) bond length is 1.50 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.28 Å. The C(7)-O(2) bond length is 1.28 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.30 Å. The C(8)-O(4) bond length is 1.26 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(5) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-O(5) bond length is 1.27 Å. In the tenth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(10), and one H(9) atom. The C(12)-N(1) bond length is 1.46 Å. The C(12)-H(10) bond length is 1.10 Å. The C(12)-H(9) bond length is 1.10 Å. In the eleventh C site, C(13) is bonded in a tetrahedral geometry to one N(1), one H(11), one H(12), and one H(13) atom. The C(13)-N(1) bond length is 1.45 Å. The C(13)-H(11) bond length is 1.10 Å. The C(13)-H(12) bond length is 1.10 Å. The C(13)-H(13) bond length is 1.10 Å. N(1) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(9) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. There are five inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the third O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(7) atom. In the fourth O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(8) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one C(8) atom. Linkers: 4 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 4 [Zn]. RCSR code: fes. The MOF has largest included sphere 1.94 A, density 1.70 g/cm3, surface area 4714.09 m2/g, accessible volume 0.11 cm3/g