Au2CuC28P2H35S2(NO)2(CH2)3(CH)7CO2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of eleven 02329_fluka molecules, six 02329_fluka molecules, two formic acid molecules, one propylene molecule, and two Au2CuC28P2H35S2(NO)2 clusters. In one of the Au2CuC28P2H35S2(NO)2 clusters, there are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted linear geometry to one P(1) and one S(2) atom. The Au(1)-P(1) bond length is 2.27 Å. The Au(1)-S(2) bond length is 2.32 Å. In the second Au site, Au(2) is bonded in a distorted linear geometry to one P(2) and one S(1) atom. The Au(2)-P(2) bond length is 2.29 Å. The Au(2)-S(1) bond length is 2.35 Å. Cu(1) is bonded to one N(1), one N(2), one S(1), one S(2), and one O(1) atom to form distorted CuS2N2O trigonal bipyramids that share  a cornercorner with one C(28)C3S tetrahedra and  a cornercorner with one C(31)C3S tetrahedra. The Cu(1)-N(1) bond length is 2.07 Å. The Cu(1)-N(2) bond length is 2.03 Å. The Cu(1)-S(1) bond length is 2.35 Å. The Cu(1)-S(2) bond length is 2.28 Å. The Cu(1)-O(1) bond length is 2.27 Å. There are twenty-eight inequivalent C sites. In the first C site, C(23) is bonded in a distorted single-bond geometry to one C(19) and one H(24) atom. The C(23)-C(19) bond length is 1.41 Å. The C(23)-H(24) bond length is 1.09 Å. In the second C site, C(28) is bonded to one C(32), one C(33), one C(34), and one S(1) atom to form CC3S tetrahedra that share  a cornercorner with one N(1)CuH2C tetrahedra and  a cornercorner with one Cu(1)S2N2O trigonal bipyramid. The C(28)-C(32) bond length is 1.55 Å. The C(28)-C(33) bond length is 1.53 Å. The C(28)-C(34) bond length is 1.52 Å. The C(28)-S(1) bond length is 1.88 Å. In the third C site, C(31) is bonded to one C(35), one C(36), one C(37), and one S(2) atom to form CC3S tetrahedra that share  a cornercorner with one N(2)CuH2C tetrahedra and  a cornercorner with one Cu(1)S2N2O trigonal bipyramid. The C(31)-C(35) bond length is 1.53 Å. The C(31)-C(36) bond length is 1.54 Å. The C(31)-C(37) bond length is 1.53 Å. The C(31)-S(2) bond length is 1.86 Å. In the fourth C site, C(32) is bonded in a 2-coordinate geometry to one C(28), one N(1), and one H(35) atom. The C(32)-N(1) bond length is 1.48 Å. The C(32)-H(35) bond length is 1.10 Å. In the fifth C site, C(33) is bonded in a distorted trigonal non-coplanar geometry to one C(28), one H(36), one H(37), and one H(38) atom. The C(33)-H(36) bond length is 1.10 Å. The C(33)-H(37) bond length is 1.10 Å. The C(33)-H(38) bond length is 1.10 Å. In the sixth C site, C(34) is bonded in a distorted trigonal non-coplanar geometry to one C(28), one H(39), one H(40), and one H(41) atom. The C(34)-H(39) bond length is 1.10 Å. The C(34)-H(40) bond length is 1.10 Å. The C(34)-H(41) bond length is 1.10 Å. In the seventh C site, C(35) is bonded in a trigonal non-coplanar geometry to one C(31), one H(42), one H(43), and one H(44) atom. The C(35)-H(42) bond length is 1.10 Å. The C(35)-H(43) bond length is 1.10 Å. The C(35)-H(44) bond length is 1.10 Å. In the eighth C site, C(36) is bonded in a distorted water-like geometry to one C(31), one N(2), and one H(45) atom. The C(36)-N(2) bond length is 1.48 Å. The C(36)-H(45) bond length is 1.10 Å. In the ninth C site, C(37) is bonded in a trigonal non-coplanar geometry to one C(31), one H(46), one H(47), and one H(48) atom. The C(37)-H(46) bond length is 1.10 Å. The C(37)-H(47) bond length is 1.10 Å. The C(37)-H(48) bond length is 1.10 Å. In the tenth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(38)-O(1) bond length is 1.28 Å. The C(38)-O(2) bond length is 1.25 Å. In the eleventh C site, C(1) is bonded in a trigonal planar geometry to one C(4), one C(5), and one P(1) atom. The C(1)-C(4) bond length is 1.40 Å. The C(1)-C(5) bond length is 1.41 Å. The C(1)-P(1) bond length is 1.81 Å. In the twelfth C site, C(2) is bonded in a trigonal planar geometry to one C(6), one C(7), and one P(1) atom. The C(2)-C(6) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. The C(2)-P(1) bond length is 1.81 Å. In the thirteenth C site, C(3) is bonded in a distorted water-like geometry to one P(1), one H(1), and one H(2) atom. The C(3)-P(1) bond length is 1.83 Å. The C(3)-H(1) bond length is 1.10 Å. The C(3)-H(2) bond length is 1.10 Å. In the fourteenth C site, C(4) is bonded in a distorted single-bond geometry to one C(1), one C(9), and one H(3) atom. The C(4)-C(9) bond length is 1.40 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifteenth C site, C(5) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the sixteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(11), one C(2), and one H(5) atom. The C(6)-C(11) bond length is 1.40 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventeenth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. In the eighteenth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(14), one C(4), and one H(9) atom. The C(9)-C(14) bond length is 1.40 Å. The C(9)-H(9) bond length is 1.09 Å. In the nineteenth C site, C(10) is bonded in a distorted single-bond geometry to one C(14) and one H(10) atom. The C(10)-C(14) bond length is 1.40 Å. The C(10)-H(10) bond length is 1.09 Å. In the twentieth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(15), one C(6), and one H(11) atom. The C(11)-C(15) bond length is 1.40 Å. The C(11)-H(11) bond length is 1.09 Å. In the twenty-first C site, C(14) is bonded in a distorted trigonal planar geometry to one C(10), one C(9), and one H(15) atom. The C(14)-H(15) bond length is 1.09 Å. In the twenty-second C site, C(15) is bonded in a distorted single-bond geometry to one C(11) and one H(16) atom. The C(15)-H(16) bond length is 1.09 Å. In the twenty-third C site, C(17) is bonded in a distorted water-like geometry to one P(2), one H(19), and one H(20) atom. The C(17)-P(2) bond length is 1.84 Å. The C(17)-H(19) bond length is 1.10 Å. The C(17)-H(20) bond length is 1.10 Å. In the twenty-fourth C site, C(18) is bonded in a trigonal planar geometry to one C(20), one C(21), and one P(2) atom. The C(18)-C(20) bond length is 1.41 Å. The C(18)-C(21) bond length is 1.41 Å. The C(18)-P(2) bond length is 1.82 Å. In the twenty-fifth C site, C(19) is bonded in a trigonal planar geometry to one C(22), one C(23), and one P(2) atom. The C(19)-C(22) bond length is 1.40 Å. The C(19)-P(2) bond length is 1.82 Å. In the twenty-sixth C site, C(20) is bonded in a distorted single-bond geometry to one C(18) and one H(21) atom. The C(20)-H(21) bond length is 1.09 Å. In the twenty-seventh C site, C(21) is bonded in a distorted single-bond geometry to one C(18) and one H(22) atom. The C(21)-H(22) bond length is 1.09 Å. In the twenty-eighth C site, C(22) is bonded in a distorted single-bond geometry to one C(19) and one H(23) atom. The C(22)-H(23) bond length is 1.09 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one Au(1), one C(1), one C(2), and one C(3) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one Au(2), one C(17), one C(18), and one C(19) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Cu(1), one C(32), one H(31), and one H(32) atom to form distorted NCuH2C tetrahedra that share  a cornercorner with one C(28)C3S tetrahedra and  a cornercorner with one N(2)CuH2C tetrahedra. The N(1)-H(31) bond length is 1.02 Å. The N(1)-H(32) bond length is 1.02 Å. In the second N site, N(2) is bonded to one Cu(1), one C(36), one H(33), and one H(34) atom to form distorted NCuH2C tetrahedra that share  a cornercorner with one C(31)C3S tetrahedra and  a cornercorner with one N(1)CuH2C tetrahedra. The N(2)-H(33) bond length is 1.03 Å. The N(2)-H(34) bond length is 1.04 Å. There are thirty-five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(23) is bonded in a single-bond geometry to one C(22) atom. In the sixteenth H site, H(24) is bonded in a single-bond geometry to one C(23) atom. In the seventeenth H site, H(31) is bonded in a single-bond geometry to one N(1) atom. In the eighteenth H site, H(32) is bonded in a single-bond geometry to one N(1) atom. In the nineteenth H site, H(33) is bonded in a single-bond geometry to one N(2) atom. In the twentieth H site, H(34) is bonded in a single-bond geometry to one N(2) atom. In the twenty-first H site, H(35) is bonded in a single-bond geometry to one C(32) atom. In the twenty-second H site, H(36) is bonded in a single-bond geometry to one C(33) atom. In the twenty-third H site, H(37) is bonded in a single-bond geometry to one C(33) atom. In the twenty-fourth H site, H(38) is bonded in a single-bond geometry to one C(33) atom. In the twenty-fifth H site, H(39) is bonded in a single-bond geometry to one C(34) atom. In the twenty-sixth H site, H(40) is bonded in a single-bond geometry to one C(34) atom. In the twenty-seventh H site, H(41) is bonded in a single-bond geometry to one C(34) atom. In the twenty-eighth H site, H(42) is bonded in a single-bond geometry to one C(35) atom. In the twenty-ninth H site, H(43) is bonded in a single-bond geometry to one C(35) atom. In the thirtieth H site, H(44) is bonded in a single-bond geometry to one C(35) atom. In the thirty-first H site, H(45) is bonded in a single-bond geometry to one C(36) atom. In the thirty-second H site, H(46) is bonded in a single-bond geometry to one C(37) atom. In the thirty-third H site, H(47) is bonded in a single-bond geometry to one C(37) atom. In the thirty-fourth H site, H(48) is bonded in a single-bond geometry to one C(37) atom. In the thirty-fifth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one Au(2), one Cu(1), and one C(28) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one Au(1), one Cu(1), and one C(31) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cu(1) and one C(38) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(38) atom. In one of the Au2CuC28P2H35S2(NO)2 clusters, there are two inequivalent Au sites. In the first Au site, Au(3) is bonded in a distorted linear geometry to one P(3) and one S(3) atom. The Au(3)-P(3) bond length is 2.29 Å. The Au(3)-S(3) bond length is 2.33 Å. In the second Au site, Au(4) is bonded in a 2-coordinate geometry to one P(4) and one S(4) atom. The Au(4)-P(4) bond length is 2.27 Å. The Au(4)-S(4) bond length is 2.33 Å. Cu(2) is bonded to one N(3), one N(4), one S(3), one S(4), and one O(7) atom to form distorted CuS2N2O trigonal bipyramids that share  a cornercorner with one C(40)C3S tetrahedra and  a cornercorner with one C(45)C3S tetrahedra. The Cu(2)-N(3) bond length is 2.05 Å. The Cu(2)-N(4) bond length is 2.03 Å. The Cu(2)-S(3) bond length is 2.27 Å. The Cu(2)-S(4) bond length is 2.34 Å. The Cu(2)-O(7) bond length is 2.32 Å. There are twenty-eight inequivalent C sites. In the first C site, C(40) is bonded to one C(41), one C(43), one C(44), and one S(3) atom to form CC3S tetrahedra that share  a cornercorner with one N(3)CuH2C tetrahedra and  a cornercorner with one Cu(2)S2N2O trigonal bipyramid. The C(40)-C(41) bond length is 1.56 Å. The C(40)-C(43) bond length is 1.53 Å. The C(40)-C(44) bond length is 1.53 Å. The C(40)-S(3) bond length is 1.87 Å. In the second C site, C(41) is bonded in a 2-coordinate geometry to one C(40), one N(3), and one H(53) atom. The C(41)-N(3) bond length is 1.48 Å. The C(41)-H(53) bond length is 1.10 Å. In the third C site, C(43) is bonded in a trigonal non-coplanar geometry to one C(40), one H(54), one H(55), and one H(56) atom. The C(43)-H(54) bond length is 1.10 Å. The C(43)-H(55) bond length is 1.10 Å. The C(43)-H(56) bond length is 1.10 Å. In the fourth C site, C(44) is bonded in a trigonal non-coplanar geometry to one C(40), one H(57), one H(58), and one H(59) atom. The C(44)-H(57) bond length is 1.10 Å. The C(44)-H(58) bond length is 1.10 Å. The C(44)-H(59) bond length is 1.10 Å. In the fifth C site, C(45) is bonded to one C(46), one C(48), one C(49), and one S(4) atom to form CC3S tetrahedra that share  a cornercorner with one N(4)CuH2C tetrahedra and  a cornercorner with one Cu(2)S2N2O trigonal bipyramid. The C(45)-C(46) bond length is 1.55 Å. The C(45)-C(48) bond length is 1.52 Å. The C(45)-C(49) bond length is 1.53 Å. The C(45)-S(4) bond length is 1.88 Å. In the sixth C site, C(46) is bonded in a distorted water-like geometry to one C(45), one N(4), and one H(60) atom. The C(46)-N(4) bond length is 1.48 Å. The C(46)-H(60) bond length is 1.10 Å. In the seventh C site, C(47) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(47)-O(7) bond length is 1.27 Å. The C(47)-O(8) bond length is 1.27 Å. In the eighth C site, C(48) is bonded in a trigonal non-coplanar geometry to one C(45), one H(61), one H(62), and one H(63) atom. The C(48)-H(61) bond length is 1.10 Å. The C(48)-H(62) bond length is 1.10 Å. The C(48)-H(63) bond length is 1.10 Å. In the ninth C site, C(49) is bonded in a distorted trigonal non-coplanar geometry to one C(45), one H(64), one H(65), and one H(66) atom. The C(49)-H(64) bond length is 1.10 Å. The C(49)-H(65) bond length is 1.10 Å. The C(49)-H(66) bond length is 1.10 Å. In the tenth C site, C(50) is bonded in a trigonal planar geometry to one C(51), one C(55), and one P(3) atom. The C(50)-C(51) bond length is 1.41 Å. The C(50)-C(55) bond length is 1.41 Å. The C(50)-P(3) bond length is 1.82 Å. In the eleventh C site, C(51) is bonded in a distorted single-bond geometry to one C(50) and one H(67) atom. The C(51)-H(67) bond length is 1.09 Å. In the twelfth C site, C(52) is bonded in a distorted single-bond geometry to one C(53) and one H(68) atom. The C(52)-C(53) bond length is 1.40 Å. The C(52)-H(68) bond length is 1.09 Å. In the thirteenth C site, C(53) is bonded in a distorted trigonal planar geometry to one C(52), one C(54), and one H(69) atom. The C(53)-C(54) bond length is 1.40 Å. The C(53)-H(69) bond length is 1.09 Å. In the fourteenth C site, C(54) is bonded in a distorted trigonal planar geometry to one C(53), one C(55), and one H(70) atom. The C(54)-C(55) bond length is 1.39 Å. The C(54)-H(70) bond length is 1.09 Å. In the fifteenth C site, C(55) is bonded in a distorted single-bond geometry to one C(50), one C(54), and one H(71) atom. The C(55)-H(71) bond length is 1.09 Å. In the sixteenth C site, C(56) is bonded in a trigonal planar geometry to one C(57), one C(61), and one P(3) atom. The C(56)-C(57) bond length is 1.40 Å. The C(56)-C(61) bond length is 1.41 Å. The C(56)-P(3) bond length is 1.82 Å. In the seventeenth C site, C(57) is bonded in a distorted single-bond geometry to one C(56) and one H(72) atom. The C(57)-H(72) bond length is 1.09 Å. In the eighteenth C site, C(61) is bonded in a distorted single-bond geometry to one C(56) and one H(76) atom. The C(61)-H(76) bond length is 1.09 Å. In the nineteenth C site, C(62) is bonded in a trigonal planar geometry to one C(63), one C(67), and one P(4) atom. The C(62)-C(63) bond length is 1.41 Å. The C(62)-C(67) bond length is 1.40 Å. The C(62)-P(4) bond length is 1.82 Å. In the twentieth C site, C(63) is bonded in a distorted single-bond geometry to one C(62) and one H(77) atom. The C(63)-H(77) bond length is 1.09 Å. In the twenty-first C site, C(65) is bonded in a distorted single-bond geometry to one C(66) and one H(79) atom. The C(65)-C(66) bond length is 1.40 Å. The C(65)-H(79) bond length is 1.09 Å. In the twenty-second C site, C(66) is bonded in a distorted single-bond geometry to one C(65), one C(67), and one H(80) atom. The C(66)-C(67) bond length is 1.40 Å. The C(66)-H(80) bond length is 1.09 Å. In the twenty-third C site, C(67) is bonded in a distorted single-bond geometry to one C(62), one C(66), and one H(81) atom. The C(67)-H(81) bond length is 1.09 Å. In the twenty-fourth C site, C(68) is bonded in a trigonal planar geometry to one C(69), one C(73), and one P(4) atom. The C(68)-C(69) bond length is 1.40 Å. The C(68)-C(73) bond length is 1.40 Å. The C(68)-P(4) bond length is 1.82 Å. In the twenty-fifth C site, C(69) is bonded in a distorted single-bond geometry to one C(68) and one H(82) atom. The C(69)-H(82) bond length is 1.09 Å. In the twenty-sixth C site, C(73) is bonded in a distorted single-bond geometry to one C(68) and one H(86) atom. The C(73)-H(86) bond length is 1.09 Å. In the twenty-seventh C site, C(74) is bonded in a distorted water-like geometry to one P(4), one H(87), and one H(88) atom. The C(74)-P(4) bond length is 1.83 Å. The C(74)-H(87) bond length is 1.10 Å. The C(74)-H(88) bond length is 1.10 Å. In the twenty-eighth C site, C(78) is bonded in a distorted water-like geometry to one P(3), one H(95), and one H(96) atom. The C(78)-P(3) bond length is 1.83 Å. The C(78)-H(95) bond length is 1.10 Å. The C(78)-H(96) bond length is 1.10 Å. There are two inequivalent P sites. In the first P site, P(3) is bonded in a tetrahedral geometry to one Au(3), one C(50), one C(56), and one C(78) atom. In the second P site, P(4) is bonded in a tetrahedral geometry to one Au(4), one C(62), one C(68), and one C(74) atom. There are two inequivalent N sites. In the first N site, N(3) is bonded to one Cu(2), one C(41), one H(49), and one H(50) atom to form distorted NCuH2C tetrahedra that share  a cornercorner with one C(40)C3S tetrahedra and  a cornercorner with one N(4)CuH2C tetrahedra. The N(3)-H(49) bond length is 1.02 Å. The N(3)-H(50) bond length is 1.04 Å. In the second N site, N(4) is bonded to one Cu(2), one C(46), one H(51), and one H(52) atom to form distorted NCuH2C tetrahedra that share  a cornercorner with one C(45)C3S tetrahedra and  a cornercorner with one N(3)CuH2C tetrahedra. The N(4)-H(51) bond length is 1.02 Å. The N(4)-H(52) bond length is 1.04 Å. There are thirty-five inequivalent H sites. In the first H site, H(49) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(50) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(51) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(52) is bonded in a single-bond geometry to one N(4) atom. In the fifth H site, H(53) is bonded in a single-bond geometry to one C(41) atom. In the sixth H site, H(54) is bonded in a single-bond geometry to one C(43) atom. In the seventh H site, H(60) is bonded in a single-bond geometry to one C(46) atom. In the eighth H site, H(55) is bonded in a single-bond geometry to one C(43) atom. In the ninth H site, H(56) is bonded in a single-bond geometry to one C(43) atom. In the tenth H site, H(57) is bonded in a single-bond geometry to one C(44) atom. In the eleventh H site, H(58) is bonded in a single-bond geometry to one C(44) atom. In the twelfth H site, H(59) is bonded in a single-bond geometry to one C(44) atom. In the thirteenth H site, H(61) is bonded in a single-bond geometry to one C(48) atom. In the fourteenth H site, H(62) is bonded in a single-bond geometry to one C(48) atom. In the fifteenth H site, H(63) is bonded in a single-bond geometry to one C(48) atom. In the sixteenth H site, H(64) is bonded in a single-bond geometry to one C(49) atom. In the seventeenth H site, H(65) is bonded in a single-bond geometry to one C(49) atom. In the eighteenth H site, H(66) is bonded in a single-bond geometry to one C(49) atom. In the nineteenth H site, H(67) is bonded in a single-bond geometry to one C(51) atom. In the twentieth H site, H(71) is bonded in a single-bond geometry to one C(55) atom. In the twenty-first H site, H(72) is bonded in a single-bond geometry to one C(57) atom. In the twenty-second H site, H(76) is bonded in a single-bond geometry to one C(61) atom. In the twenty-third H site, H(77) is bonded in a single-bond geometry to one C(63) atom. In the twenty-fourth H site, H(70) is bonded in a single-bond geometry to one C(54) atom. In the twenty-fifth H site, H(80) is bonded in a single-bond geometry to one C(66) atom. In the twenty-sixth H site, H(81) is bonded in a single-bond geometry to one C(67) atom. In the twenty-seventh H site, H(82) is bonded in a single-bond geometry to one C(69) atom. In the twenty-eighth H site, H(79) is bonded in a single-bond geometry to one C(65) atom. In the twenty-ninth H site, H(86) is bonded in a single-bond geometry to one C(73) atom. In the thirtieth H site, H(87) is bonded in a single-bond geometry to one C(74) atom. In the thirty-first H site, H(88) is bonded in a single-bond geometry to one C(74) atom. In the thirty-second H site, H(95) is bonded in a single-bond geometry to one C(78) atom. In the thirty-third H site, H(96) is bonded in a single-bond geometry to one C(78) atom. In the thirty-fourth H site, H(68) is bonded in a single-bond geometry to one C(52) atom. In the thirty-fifth H site, H(69) is bonded in a single-bond geometry to one C(53) atom. There are two inequivalent S sites. In the first S site, S(3) is bonded in a trigonal non-coplanar geometry to one Au(3), one Cu(2), and one C(40) atom. In the second S site, S(4) is bonded in a distorted trigonal non-coplanar geometry to one Au(4), one Cu(2), and one C(45) atom. There are two inequivalent O sites. In the first O site, O(7) is bonded in a distorted water-like geometry to one Cu(2) and one C(47) atom. In the second O site, O(8) is bonded in a single-bond geometry to one C(47) atom. Linkers: 1 [CH]=[C]P(CCCCCP(c1ccccc1)c1ccccc1)c1ccccc1 ,2 c1ccc(P(CCCCCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1 ,1 [CH]CCCCP(c1ccccc1)c1ccccc1 ,1 [CH2]CCCCP(c1ccccc1)c1ccccc1 ,1 [CH]/C=C(\[CH])P(CCCCCP(c1ccccc1)c1ccccc1)c1ccccc1. Metal clusters: . The MOF has largest included sphere 3.89 A, density 1.76 g/cm3, surface area 3827.62 m2/g, accessible volume 0.14 cm3/g