Cu2C17H18(NO)6(CH3)3CH2C7H7O crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of four 02329_fluka molecules, twelve 02329_fluka molecules, and four benzyl alcohol molecules inside a Cu2C17H18(NO)6 framework. In the Cu2C17H18(NO)6 framework, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square pyramidal geometry to one N(1), one N(3), one O(2), one O(3), and one O(6) atom. The Cu(1)-N(1) bond length is 1.90 Å. The Cu(1)-N(3) bond length is 1.93 Å. The Cu(1)-O(2) bond length is 2.05 Å. The Cu(1)-O(3) bond length is 2.09 Å. The Cu(1)-O(6) bond length is 2.29 Å. In the second Cu site, Cu(2) is bonded in a square pyramidal geometry to one N(2), one N(6), one O(1), one O(4), and one O(5) atom. The Cu(2)-N(2) bond length is 1.91 Å. The Cu(2)-N(6) bond length is 1.94 Å. The Cu(2)-O(1) bond length is 2.29 Å. The Cu(2)-O(4) bond length is 2.07 Å. The Cu(2)-O(5) bond length is 2.05 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.30 Å. In the second C site, C(3) is bonded in a 2-coordinate geometry to one N(1) and one H(6) atom. The C(3)-N(1) bond length is 1.44 Å. The C(3)-H(6) bond length is 1.10 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(4) atom. The C(4)-N(1) bond length is 1.31 Å. The C(4)-O(4) bond length is 1.28 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(3) atom. The C(5)-N(2) bond length is 1.31 Å. The C(5)-O(3) bond length is 1.29 Å. In the fifth C site, C(6) is bonded in a 2-coordinate geometry to one N(2) and one H(7) atom. The C(6)-N(2) bond length is 1.44 Å. The C(6)-H(7) bond length is 1.10 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(8)-O(5) bond length is 1.30 Å. The C(8)-O(6) bond length is 1.25 Å. In the seventh C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(10); one H(13); and two equivalent H(11,12) atoms. The C(9)-C(10) bond length is 1.49 Å. The C(9)-H(13) bond length is 1.10 Å. Both C(9)-H(11,12) bond lengths are 1.10 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one N(4) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-N(4) bond length is 1.35 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-C(14) bond length is 1.50 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one N(3) atom. The C(12)-C(13) bond length is 1.49 Å. The C(12)-N(3) bond length is 1.34 Å. In the eleventh C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one C(12), one H(14), one H(15), and one H(16) atom. The C(13)-H(14) bond length is 1.10 Å. The C(13)-H(15) bond length is 1.10 Å. The C(13)-H(16) bond length is 1.10 Å. In the twelfth C site, C(14) is bonded in a water-like geometry to one C(11), one C(17), one H(17), and one H(18) atom. The C(14)-C(17) bond length is 1.50 Å. The C(14)-H(17) bond length is 1.10 Å. The C(14)-H(18) bond length is 1.10 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one C(16), one H(19), one H(20), and one H(21) atom. The C(15)-C(16) bond length is 1.49 Å. The C(15)-H(19) bond length is 1.10 Å. The C(15)-H(20) bond length is 1.10 Å. The C(15)-H(21) bond length is 1.10 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one N(6) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-N(6) bond length is 1.35 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(17)-C(18) bond length is 1.40 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one N(5) atom. The C(18)-C(19) bond length is 1.49 Å. The C(18)-N(5) bond length is 1.35 Å. In the seventeenth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one C(18), one H(22), one H(23), and one H(24) atom. The C(19)-H(22) bond length is 1.10 Å. The C(19)-H(23) bond length is 1.10 Å. The C(19)-H(24) bond length is 1.10 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(5), and one C(6) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(12), and one N(4) atom. The N(3)-N(4) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one C(10), one N(3), and one H(1) atom. The N(4)-H(1) bond length is 1.05 Å. In the fifth N site, N(5) is bonded in a 2-coordinate geometry to one C(18), one N(6), and one H(2) atom. The N(5)-N(6) bond length is 1.35 Å. The N(5)-H(2) bond length is 1.04 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(16), and one N(5) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one N(4) and one O(5) atom. The H(1)-O(5) bond length is 1.70 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one N(5) and one O(2) atom. The H(2)-O(2) bond length is 1.69 Å. In the third H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(11,12) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(15) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(15) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(19) atom. In the sixteenth H site, H(23) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(24) is bonded in a single-bond geometry to one C(19) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one H(2) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cu(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cu(2) and one C(4) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Cu(2), one C(8), and one H(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Cu(1) and one C(8) atom. Linkers: 3 C[C@H]([N]C(=O)C(=O)[N][C@@H](C)C([O])=O)C([O])=O ,4 Cc1n[nH]c(C)c1Cc1c(C)n[nH]c1C. Metal clusters: 8 [Cu]. The MOF has largest included sphere 2.38 A, density 1.49 g/cm3, surface area 5083.63 m2/g, accessible volume 0.17 cm3/g