CdC6H4(NO2)2(CH2)2(C3NH3)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, eight 2-propanimine molecules, and two CdC6H4(NO2)2 clusters. In each CdC6H4(NO2)2 cluster, Cd(1) is bonded to one N(3), one N(4), one O(1), one O(2), one O(4), and two equivalent O(3) atoms to form edge-sharing CdN2O5 pentagonal bipyramids. The Cd(1)-N(3) bond length is 2.29 Å. The Cd(1)-N(4) bond length is 2.30 Å. The Cd(1)-O(1) bond length is 2.43 Å. The Cd(1)-O(2) bond length is 2.52 Å. The Cd(1)-O(4) bond length is 2.55 Å. There is one shorter (2.38 Å) and one longer (2.44 Å) Cd(1)-O(3) bond length. There are six inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(3,6) atom. The C(5)-N(3) bond length is 1.35 Å. The C(5)-H(3,6) bond length is 1.09 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(7) atom. The C(6)-N(4) bond length is 1.35 Å. The C(6)-H(7) bond length is 1.09 Å. In the third C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(10) atom. The C(10)-N(4) bond length is 1.35 Å. The C(10)-H(10) bond length is 1.09 Å. In the fourth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(11)-O(1) bond length is 1.27 Å. The C(11)-O(2) bond length is 1.29 Å. In the fifth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(13)-O(3) bond length is 1.28 Å. The C(13)-O(4) bond length is 1.27 Å. In the sixth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(3,6) atom. The C(1)-N(3) bond length is 1.35 Å. The C(1)-H(3,6) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(6) atom. There are three inequivalent H sites. In the first H site, H(3,6) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(11) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(11) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(13) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cd(1) and one C(13) atom. Linkers: 2 [O]C(=O)CCC([O])=O ,2 c1cc(NNc2ccncc2)ccn1. Metal clusters: 1 [C]1O[Cd]2(O1)O[C]O[Cd]1(O[C]O1)O[C]O2. RCSR code: sql. The MOF has largest included sphere 3.62 A, density 1.70 g/cm3, surface area 4064.81 m2/g, accessible volume 0.13 cm3/g