ZnC14N4H8O5(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a ZnC14N4H8O5 framework. In the ZnC14N4H8O5 framework, Zn(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(5) atom. The Zn(1)-O(1) bond length is 1.99 Å. The Zn(1)-O(3) bond length is 1.94 Å. The Zn(1)-O(4) bond length is 1.96 Å. The Zn(1)-O(5) bond length is 1.97 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(3) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(2) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.29 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(8) bond length is 1.47 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one N(4) atom. The C(8)-N(1) bond length is 1.35 Å. The C(8)-N(4) bond length is 1.35 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(2), and one N(3) atom. The C(9)-C(10) bond length is 1.47 Å. The C(9)-N(2) bond length is 1.35 Å. The C(9)-N(3) bond length is 1.36 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-C(15) bond length is 1.40 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(9) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-H(9) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(16) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-C(16) bond length is 1.49 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one H(10) atom. The C(15)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(4), and one O(5) atom. The C(16)-O(4) bond length is 1.28 Å. The C(16)-O(5) bond length is 1.28 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one C(8) and one N(2) atom. The N(1)-N(2) bond length is 1.32 Å. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(9) and one N(1) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one C(9) and one N(4) atom. The N(3)-N(4) bond length is 1.31 Å. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one C(8) and one N(3) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) and one O(2) atom. The H(1)-O(1) bond length is 1.00 Å. The H(1)-O(2) bond length is 1.68 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(1) and one O(2) atom. The H(2)-O(1) bond length is 1.00 Å. The H(2)-O(2) bond length is 1.66 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. There are five inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one C(1), one H(1), and one H(2) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(16) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(16) atom. In the fifth O site, O(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one H(1), and one H(2) atom. Linkers: 4 [O]C(=O)c1cccc(-c2nnc(-c3cccc(C([O])=O)c3)nn2)c1. Metal clusters: 4 [Zn]. RCSR code: fes. The MOF has largest included sphere 1.77 A, density 1.84 g/cm3, surface area 4173.42 m2/g, accessible volume 0.09 cm3/g