C3H2CH2C3NH4ZnC(OCl)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; two 2,3-dimethyl-1,3-butadiene molecules; four trimethylamine molecules; and two ZnC(OCl)2 clusters. In each ZnC(OCl)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one Cl(1), and one Cl(2) atom. The Zn(1)-O(1) bond length is 2.01 Å. The Zn(1)-O(2) bond length is 2.01 Å. The Zn(1)-Cl(1) bond length is 2.24 Å. The Zn(1)-Cl(2) bond length is 2.23 Å. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.27 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 2 [O]C(=O)CCN1[CH]C=C(C2=C[CH]N(CCC([O])=O)C=C2)C=C1. Metal clusters: 2 Cl[Zn]1(Cl)O[C]O[Zn](Cl)(Cl)O[C]O1. The MOF has largest included sphere 2.26 A, density 1.83 g/cm3, surface area 4163.76 m2/g, accessible volume 0.16 cm3/g