ZnC20H16(NO)4(CH)6CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, two 02329_fluka molecules, and one ZnC20H16(NO)4 cluster. In the ZnC20H16(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one O(1), and one O(4) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-N(3) bond length is 2.05 Å. The Zn(1)-O(1) bond length is 1.95 Å. The Zn(1)-O(4) bond length is 1.98 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one N(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one H(1), one H(2), and one H(3) atom. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. The C(2)-H(3) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one N(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(8) bond length is 1.41 Å. The C(3)-N(1) bond length is 1.39 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(7) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one N(2) atom. The C(8)-N(2) bond length is 1.39 Å. In the seventh C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(8), and one H(9) atom. The C(9)-N(2) bond length is 1.46 Å. The C(9)-H(8) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(3), and one N(4) atom. The C(11)-C(12) bond length is 1.48 Å. The C(11)-N(3) bond length is 1.34 Å. The C(11)-N(4) bond length is 1.37 Å. In the ninth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one H(12), one H(13), and one H(14) atom. The C(12)-H(12) bond length is 1.10 Å. The C(12)-H(13) bond length is 1.10 Å. The C(12)-H(14) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one N(3) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(18) bond length is 1.42 Å. The C(13)-N(3) bond length is 1.40 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(15) atom. The C(14)-H(15) bond length is 1.09 Å. In the twelfth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(18) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(18) bond length is 1.09 Å. In the thirteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one N(4) atom. The C(18)-N(4) bond length is 1.39 Å. In the fourteenth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(19), and one H(20) atom. The C(19)-N(4) bond length is 1.46 Å. The C(19)-H(19) bond length is 1.10 Å. The C(19)-H(20) bond length is 1.10 Å. In the fifteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(3), and one O(4) atom. The C(20)-C(21) bond length is 1.51 Å. The C(20)-O(3) bond length is 1.25 Å. The C(20)-O(4) bond length is 1.30 Å. In the sixteenth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(26) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(26) bond length is 1.41 Å. In the seventeenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(21) atom. The C(22)-H(21) bond length is 1.09 Å. In the eighteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(1), and one O(2) atom. The C(25)-C(26) bond length is 1.50 Å. The C(25)-O(1) bond length is 1.30 Å. The C(25)-O(2) bond length is 1.25 Å. In the nineteenth C site, C(26) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(27) atom. The C(26)-C(27) bond length is 1.40 Å. In the twentieth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(24) atom. The C(27)-H(24) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(8), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(13) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(11), one C(18), and one C(19) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(22) atom. In the sixteenth H site, H(24) is bonded in a single-bond geometry to one C(27) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(25) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(20) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(20) atom. Linkers: 2 Cc1nc2ccccc2n1CCCn1c(C)nc2ccccc21 ,2 [O]C(=O)c1ccccc1C([O])=O. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.38 A, density 1.52 g/cm3, surface area 4941.25 m2/g, accessible volume 0.15 cm3/g