(CH)2ZnC4H8S2(NO)4 crystallizes in the orthorhombic Pbcn space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and four ZnC4H8S2(NO)4 clusters. In each ZnC4H8S2(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent S(1) and two equivalent O(1) atoms. Both Zn(1)-S(1) bond lengths are 2.32 Å. Both Zn(1)-O(1) bond lengths are 1.98 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. The C(2)-N(1) bond length is 1.32 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-S(1) bond length is 1.75 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(2), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.04 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one H(3), and one H(4) atom. The N(2)-H(3) bond length is 1.03 Å. The N(2)-H(4) bond length is 1.02 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in an L-shaped geometry to one Zn(1) and one C(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. Linkers: 4 [O]C(=O)/C=C/C([O])=O. Metal clusters: 4 [Zn]. The MOF has largest included sphere 1.98 A, density 1.94 g/cm3, surface area 4166.91 m2/g, accessible volume 0.09 cm3/g