CoC23N2H15O5(CH)5C5H4O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules, two 3-methoxy-2-methylprop-1-ene molecules, and two CoC23N2H15O5 clusters. In each CoC23N2H15O5 cluster, Co(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one O(2), and one O(5) atom. The Co(1)-N(1) bond length is 1.91 Å. The Co(1)-N(2) bond length is 1.90 Å. The Co(1)-O(2) bond length is 1.96 Å. The Co(1)-O(5) bond length is 1.92 Å. There are twenty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.29 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.41 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(6)-C(7) bond length is 1.41 Å. The C(6)-H(4) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(8) atom. The C(7)-C(8) bond length is 1.48 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(7), and one C(9) atom. The C(8)-C(13) bond length is 1.41 Å. The C(8)-C(9) bond length is 1.41 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(9)-H(5) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(13)-H(8) bond length is 1.09 Å. In the ninth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(12) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(12) bond length is 1.09 Å. In the tenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(21) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(21) bond length is 1.49 Å. In the eleventh C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(13) atom. The C(19)-H(13) bond length is 1.09 Å. In the twelfth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(4), and one O(5) atom. The C(21)-O(4) bond length is 1.27 Å. The C(21)-O(5) bond length is 1.29 Å. In the thirteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(23), one N(1), and one H(15) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-N(1) bond length is 1.34 Å. The C(22)-H(15) bond length is 1.09 Å. In the fourteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(16) atom. The C(23)-H(16) bond length is 1.09 Å. In the fifteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(17) atom. The C(24)-C(25) bond length is 1.41 Å. The C(24)-H(17) bond length is 1.09 Å. In the sixteenth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(33) atom. The C(25)-C(26) bond length is 1.44 Å. The C(25)-C(33) bond length is 1.41 Å. In the seventeenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one C(27), and one H(18) atom. The C(26)-C(27) bond length is 1.37 Å. The C(26)-H(18) bond length is 1.09 Å. In the eighteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(26), one C(28), and one H(19) atom. The C(27)-C(28) bond length is 1.43 Å. The C(27)-H(19) bond length is 1.09 Å. In the nineteenth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(32) atom. The C(28)-C(29) bond length is 1.41 Å. The C(28)-C(32) bond length is 1.41 Å. In the twentieth C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(20) atom. The C(29)-H(20) bond length is 1.09 Å. In the twenty-first C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(22) atom. The C(31)-N(2) bond length is 1.34 Å. The C(31)-H(22) bond length is 1.09 Å. In the twenty-second C site, C(32) is bonded in a distorted trigonal planar geometry to one C(28), one C(33), and one N(2) atom. The C(32)-C(33) bond length is 1.41 Å. The C(32)-N(2) bond length is 1.37 Å. In the twenty-third C site, C(33) is bonded in a distorted trigonal planar geometry to one C(25), one C(32), and one N(1) atom. The C(33)-N(1) bond length is 1.37 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(22), and one C(33) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(31), and one C(32) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(29) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(23) is bonded in a distorted linear geometry to one O(4) and one O(6) atom. The H(23)-O(4) bond length is 1.62 Å. The H(23)-O(6) bond length is 1.01 Å. In the fifteenth H site, H(24) is bonded in a distorted linear geometry to one O(1) and one O(6) atom. The H(24)-O(1) bond length is 1.60 Å. The H(24)-O(6) bond length is 1.01 Å. There are five inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one Co(1) and one C(21) atom. In the second O site, O(6) is bonded in a water-like geometry to one H(23) and one H(24) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one C(1) and one H(24) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(1) atom. In the fifth O site, O(4) is bonded in a water-like geometry to one C(21) and one H(23) atom. Linkers: 2 [O]C(=O)c1ccc(OCc2ccc(-c3ccccc3C([O])=O)cc2)cc1 ,2 [O]C(=O)c1ccc(OCc2ccc(-c3cc[c]cc3C([O])=O)cc2)cc1. Metal clusters: 2 O.O=[C]O[Co]O[C]=O. The MOF has largest included sphere 2.38 A, density 1.56 g/cm3, surface area 4380.40 m2/g, accessible volume 0.10 cm3/g