MnC14N2H10O5CH2CH is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two 02329_fluka molecules, and one MnC14N2H10O5 cluster. In the MnC14N2H10O5 cluster, Mn(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(2), one O(2), one O(3), and one O(5) atom. The Mn(1)-N(1) bond length is 2.25 Å. The Mn(1)-N(2) bond length is 2.19 Å. The Mn(1)-O(2) bond length is 2.12 Å. The Mn(1)-O(3) bond length is 2.08 Å. The Mn(1)-O(5) bond length is 2.10 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.29 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(4)-O(3) bond length is 1.31 Å. The C(4)-O(4) bond length is 1.25 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(4) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(5) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-H(5) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(6) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-H(6) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.43 Å. The C(8)-C(9) bond length is 1.42 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(13), one C(8), and one N(1) atom. The C(9)-C(13) bond length is 1.44 Å. The C(9)-N(1) bond length is 1.36 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(10)-H(7) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(8) atom. The C(11)-C(12) bond length is 1.43 Å. The C(11)-H(8) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(16) atom. The C(12)-C(13) bond length is 1.42 Å. The C(12)-C(16) bond length is 1.41 Å. In the eleventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(9), and one N(2) atom. The C(13)-N(2) bond length is 1.36 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(15), one N(2), and one H(9) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-N(2) bond length is 1.33 Å. The C(14)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(10) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(12), one C(15), and one H(11) atom. The C(16)-H(11) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(1), one C(5), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(1), one C(13), and one C(14) atom. There are ten inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(12) is bonded in a distorted bent 150 degrees geometry to one O(1) and one O(5) atom. The H(12)-O(1) bond length is 1.59 Å. The H(12)-O(5) bond length is 1.02 Å. In the tenth H site, H(13) is bonded in a single-bond geometry to one O(3) and one O(5) atom. The H(13)-O(3) bond length is 1.70 Å. The H(13)-O(5) bond length is 0.99 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(1) and one H(12) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(4), and one H(13) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Mn(1), one H(12), and one H(13) atom. Linkers: 1 [O]C(=O)C[C@H](C([O])=O)[C@@H](CC([O])=O)C([O])=O ,1 c1cnc2c(c1)ccc1cccnc12. Metal clusters: 1 [Mn] ,1 O.O=[C]O[Mn]O[C]=O. The MOF has largest included sphere 2.16 A, density 1.73 g/cm3, surface area 4189.38 m2/g, accessible volume 0.10 cm3/g