ZnC21H15(NO2)2ZnC17H12(NO2)2(CH)10C4H3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty 02329_fluka molecules, two isobutylene molecules, two ZnC17H12(NO2)2 clusters, and two ZnC21H15(NO2)2 clusters. In each ZnC17H12(NO2)2 cluster, Zn(2) is bonded in a tetrahedral geometry to one N(2), one N(4), one O(5), and one O(7) atom. The Zn(2)-N(2) bond length is 2.05 Å. The Zn(2)-N(4) bond length is 2.03 Å. The Zn(2)-O(5) bond length is 1.99 Å. The Zn(2)-O(7) bond length is 1.98 Å. There are seventeen inequivalent C sites. In the first C site, C(23) is bonded in a distorted single-bond geometry to one C(22), one C(24), and one H(17) atom. The C(23)-C(22) bond length is 1.41 Å. The C(23)-C(24) bond length is 1.38 Å. The C(23)-H(17) bond length is 1.09 Å. In the second C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one N(2), and one H(18) atom. The C(24)-N(2) bond length is 1.35 Å. The C(24)-H(18) bond length is 1.09 Å. In the third C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(26), one N(2), and one H(19) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-N(2) bond length is 1.35 Å. The C(25)-H(19) bond length is 1.09 Å. In the fourth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(22), one C(25), and one H(20) atom. The C(26)-C(22) bond length is 1.41 Å. The C(26)-H(20) bond length is 1.09 Å. In the fifth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(28) atom. The C(36)-N(4) bond length is 1.35 Å. The C(36)-H(28) bond length is 1.09 Å. In the sixth C site, C(37) is bonded in a 2-coordinate geometry to one N(4) and one H(29) atom. The C(37)-N(4) bond length is 1.35 Å. The C(37)-H(29) bond length is 1.09 Å. In the seventh C site, C(39) is bonded in a bent 120 degrees geometry to one C(40), one O(5), and one O(6) atom. The C(39)-C(40) bond length is 1.50 Å. The C(39)-O(5) bond length is 1.31 Å. The C(39)-O(6) bond length is 1.25 Å. In the eighth C site, C(40) is bonded in a trigonal planar geometry to one C(39), one C(41), and one C(45) atom. The C(40)-C(41) bond length is 1.40 Å. The C(40)-C(45) bond length is 1.40 Å. In the ninth C site, C(41) is bonded in a distorted single-bond geometry to one C(40) and one H(31) atom. The C(41)-H(31) bond length is 1.09 Å. In the tenth C site, C(44) is bonded in a distorted single-bond geometry to one C(45) and one H(34) atom. The C(44)-C(45) bond length is 1.39 Å. The C(44)-H(34) bond length is 1.09 Å. In the eleventh C site, C(45) is bonded in a distorted trigonal planar geometry to one C(40), one C(44), and one H(35) atom. The C(45)-H(35) bond length is 1.09 Å. In the twelfth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one C(47), one O(7), and one O(8) atom. The C(46)-C(47) bond length is 1.50 Å. The C(46)-O(7) bond length is 1.30 Å. The C(46)-O(8) bond length is 1.25 Å. In the thirteenth C site, C(47) is bonded in a trigonal planar geometry to one C(46), one C(48), and one C(52) atom. The C(47)-C(48) bond length is 1.40 Å. The C(47)-C(52) bond length is 1.40 Å. In the fourteenth C site, C(48) is bonded in a distorted single-bond geometry to one C(47) and one H(36) atom. The C(48)-H(36) bond length is 1.09 Å. In the fifteenth C site, C(52) is bonded in a distorted single-bond geometry to one C(47) and one H(40) atom. The C(52)-H(40) bond length is 1.09 Å. In the sixteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(16) atom. The C(21)-C(22) bond length is 1.45 Å. The C(21)-H(16) bond length is 1.09 Å. In the seventeenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(26) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(24), and one C(25) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Zn(2), one C(36), and one C(37) atom. There are twelve inequivalent H sites. In the first H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the second H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the third H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one C(26) atom. In the sixth H site, H(28) is bonded in a single-bond geometry to one C(36) atom. In the seventh H site, H(29) is bonded in a single-bond geometry to one C(37) atom. In the eighth H site, H(31) is bonded in a single-bond geometry to one C(41) atom. In the ninth H site, H(34) is bonded in a single-bond geometry to one C(44) atom. In the tenth H site, H(35) is bonded in a single-bond geometry to one C(45) atom. In the eleventh H site, H(36) is bonded in a single-bond geometry to one C(48) atom. In the twelfth H site, H(40) is bonded in a single-bond geometry to one C(52) atom. There are four inequivalent O sites. In the first O site, O(5) is bonded in a water-like geometry to one Zn(2) and one C(39) atom. In the second O site, O(6) is bonded in a single-bond geometry to one C(39) atom. In the third O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(46) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one C(46) atom. In each ZnC21H15(NO2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 2.08 Å. The Zn(1)-N(3) bond length is 2.02 Å. The Zn(1)-O(1) bond length is 1.98 Å. The Zn(1)-O(3) bond length is 1.96 Å. There are twenty-one inequivalent C sites. In the first C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(28), one N(3), and one H(21) atom. The C(27)-C(28) bond length is 1.38 Å. The C(27)-N(3) bond length is 1.35 Å. The C(27)-H(21) bond length is 1.09 Å. In the second C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one C(29), and one H(22) atom. The C(28)-C(29) bond length is 1.41 Å. The C(28)-H(22) bond length is 1.09 Å. In the third C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(32) atom. The C(29)-C(30) bond length is 1.41 Å. The C(29)-C(32) bond length is 1.45 Å. In the fourth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one C(31), and one H(23) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-H(23) bond length is 1.09 Å. In the fifth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(30), one N(3), and one H(24) atom. The C(31)-N(3) bond length is 1.35 Å. The C(31)-H(24) bond length is 1.09 Å. In the sixth C site, C(32) is bonded in a distorted single-bond geometry to one C(29) and one H(25) atom. The C(32)-H(25) bond length is 1.09 Å. In the seventh C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the eighth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the ninth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the tenth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(4) bond length is 1.09 Å. In the eleventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the twelfth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(8)-C(9) bond length is 1.50 Å. The C(8)-O(3) bond length is 1.30 Å. The C(8)-O(4) bond length is 1.25 Å. In the thirteenth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.40 Å. In the fourteenth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(10)-H(6) bond length is 1.09 Å. In the fifteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(10) atom. The C(14)-H(10) bond length is 1.09 Å. In the sixteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(11) atom. The C(15)-N(1) bond length is 1.35 Å. The C(15)-H(11) bond length is 1.09 Å. In the seventeenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(12) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-H(12) bond length is 1.09 Å. In the eighteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-C(20) bond length is 1.46 Å. In the nineteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(13) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(13) bond length is 1.09 Å. In the twentieth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(1), and one H(14) atom. The C(19)-N(1) bond length is 1.35 Å. The C(19)-H(14) bond length is 1.09 Å. In the twenty-first C site, C(20) is bonded in a distorted single-bond geometry to one C(17) and one H(15) atom. The C(20)-H(15) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(19) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(27), and one C(31) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(27) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(28) atom. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one C(30) atom. In the fourteenth H site, H(24) is bonded in a single-bond geometry to one C(31) atom. In the fifteenth H site, H(25) is bonded in a single-bond geometry to one C(32) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(8) atom. Linkers: 4 C(=C/c1ccncc1)\c1ccncc1 ,4 [c]1cc(/C=C/c2ccncc2)ccn1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 4.55 A, density 1.29 g/cm3, surface area 5184.65 m2/g, accessible volume 0.24 cm3/g