CdC12N3H10O5CH2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and four CdC12N3H10O5 clusters. In each CdC12N3H10O5 cluster, Cd(1) is bonded to one N(3), one O(1), one O(2), one O(3), and two equivalent O(4) atoms to form distorted edge-sharing CdNO5 pentagonal pyramids. The Cd(1)-N(3) bond length is 2.28 Å. The Cd(1)-O(1) bond length is 2.42 Å. The Cd(1)-O(2) bond length is 2.39 Å. The Cd(1)-O(3) bond length is 2.33 Å. Both Cd(1)-O(4) bond lengths are 2.32 Å. There are twelve inequivalent C sites. In the first C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one O(3) atom. The C(7)-C(6) bond length is 1.44 Å. The C(7)-N(1) bond length is 1.41 Å. The C(7)-O(3) bond length is 1.26 Å. In the second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(4), and one O(5) atom. The C(8)-C(6) bond length is 1.50 Å. The C(8)-O(4) bond length is 1.30 Å. The C(8)-O(5) bond length is 1.25 Å. In the third C site, C(9) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(6) atom. The C(9)-N(2) bond length is 1.36 Å. The C(9)-N(3) bond length is 1.33 Å. The C(9)-H(6) bond length is 1.08 Å. In the fourth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(2), and one H(7) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-N(2) bond length is 1.38 Å. The C(10)-H(7) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(3), and one H(8) atom. The C(11)-N(3) bond length is 1.38 Å. The C(11)-H(8) bond length is 1.08 Å. In the sixth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(10), and one H(9) atom. The C(12)-N(2) bond length is 1.46 Å. The C(12)-H(10) bond length is 1.10 Å. The C(12)-H(9) bond length is 1.10 Å. In the seventh C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(5) atom. The C(5)-C(4) bond length is 1.40 Å. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(5) bond length is 1.09 Å. In the eighth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the ninth C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(2)-N(1) bond length is 1.46 Å. The C(2)-H(1) bond length is 1.09 Å. The C(2)-H(2) bond length is 1.10 Å. In the tenth C site, C(3) is bonded in a distorted trigonal planar geometry to one N(1) and one H(3) atom. The C(3)-N(1) bond length is 1.36 Å. The C(3)-H(3) bond length is 1.09 Å. In the eleventh C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-H(4) bond length is 1.09 Å. In the twelfth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(9) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one C(9) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(8) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(8) atom. Linkers: 4 [O]C(=O)Cn1cccc(C([O])=O)c1=O ,2 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 2 [O][Cd]1(O[C]=O)O[C]O1.[O][Cd]1(O[C]=O)O[C]O1. The MOF has largest included sphere 3.43 A, density 1.66 g/cm3, surface area 3863.56 m2/g, accessible volume 0.19 cm3/g