Zn3C26H12(NO3)4(CH3)2 crystallizes in the tetragonal P4_32_12 space group. The structure consists of eight 02329_fluka molecules inside a Zn3C26H12(NO3)4 framework. In the Zn3C26H12(NO3)4 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. Both Zn(1)-O(1) bond lengths are 2.10 Å. Both Zn(1)-O(3) bond lengths are 2.08 Å. Both Zn(1)-O(5) bond lengths are 2.12 Å. In the second Zn site, Zn(2) is bonded in a 5-coordinate geometry to one N(1), one N(2), one O(2), one O(4), and one O(5) atom. The Zn(2)-N(1) bond length is 2.21 Å. The Zn(2)-N(2) bond length is 2.10 Å. The Zn(2)-O(2) bond length is 2.08 Å. The Zn(2)-O(4) bond length is 2.04 Å. The Zn(2)-O(5) bond length is 2.05 Å. There are thirteen inequivalent C sites. In the first C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one N(2) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(2) bond length is 1.35 Å. In the second C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(4) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(4) bond length is 1.09 Å. In the third C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(5) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(5) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(12) bond length is 1.51 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(6) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(6) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(4) atom. The C(12)-O(3) bond length is 1.26 Å. The C(12)-O(4) bond length is 1.27 Å. In the seventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(13)-O(5) bond length is 1.32 Å. The C(13)-O(6) bond length is 1.25 Å. In the eighth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.27 Å. In the ninth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.40 Å. In the tenth C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 1.09 Å. In the eleventh C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(2) bond length is 1.09 Å. In the twelfth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one N(1) atom. The C(5)-N(1) bond length is 1.35 Å. In the thirteenth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(3) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-H(3) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(5), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(11), and one C(7) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(12) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(12) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(2), and one C(13) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(13) atom. Linkers: 8 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cn2)nc1. Metal clusters: 12 [Zn]. The MOF has largest included sphere 6.49 A, density 0.99 g/cm3, surface area 4043.33 m2/g, accessible volume 0.59 cm3/g