(CH)4(CH2)8Pb2C6NH7O8 is Indium-like structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, sixty-four 02329_fluka molecules, and two Pb2C6NH7O8 clusters. In each Pb2C6NH7O8 cluster, there are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to one N(1), one O(1), one O(2), one O(3), one O(4), and one O(6) atom. The Pb(1)-N(1) bond length is 2.81 Å. The Pb(1)-O(1) bond length is 2.73 Å. The Pb(1)-O(2) bond length is 2.80 Å. The Pb(1)-O(3) bond length is 2.41 Å. The Pb(1)-O(4) bond length is 2.51 Å. The Pb(1)-O(6) bond length is 2.56 Å. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to one O(2), one O(5), one O(6), one O(8), and two equivalent O(7) atoms. The Pb(2)-O(2) bond length is 2.39 Å. The Pb(2)-O(5) bond length is 2.41 Å. The Pb(2)-O(6) bond length is 2.61 Å. The Pb(2)-O(8) bond length is 2.41 Å. There is one shorter (2.68 Å) and one longer (2.73 Å) Pb(2)-O(7) bond length. There are six inequivalent C sites. In the first C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(8)-O(7) bond length is 1.28 Å. The C(8)-O(8) bond length is 1.28 Å. In the second C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(13)-O(5) bond length is 1.28 Å. The C(13)-O(6) bond length is 1.28 Å. In the third C site, C(16) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(16)-O(1) bond length is 1.26 Å. The C(16)-O(2) bond length is 1.30 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(1)-O(3) bond length is 1.29 Å. The C(1)-O(4) bond length is 1.27 Å. In the fifth C site, C(17) is bonded to one N(1), one H(21), one H(22), and one H(23) atom to form corner-sharing CH3N tetrahedra. The C(17)-N(1) bond length is 1.47 Å. The C(17)-H(21) bond length is 1.09 Å. The C(17)-H(22) bond length is 1.10 Å. The C(17)-H(23) bond length is 1.10 Å. In the sixth C site, C(18) is bonded to one N(1), one H(24), one H(25), and one H(26) atom to form corner-sharing CH3N tetrahedra. The C(18)-N(1) bond length is 1.47 Å. The C(18)-H(24) bond length is 1.10 Å. The C(18)-H(25) bond length is 1.10 Å. The C(18)-H(26) bond length is 1.10 Å. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pb(1), one C(17), one C(18), and one H(27) atom. The N(1)-H(27) bond length is 1.03 Å. There are seven inequivalent H sites. In the first H site, H(21) is bonded in a single-bond geometry to one C(17) atom. In the second H site, H(22) is bonded in a single-bond geometry to one C(17) atom. In the third H site, H(23) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(24) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(25) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(26) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(27) is bonded in a single-bond geometry to one N(1) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Pb(1) and one C(16) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(2), and one C(16) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Pb(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Pb(1) and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Pb(2) and one C(13) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(2), and one C(13) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to two equivalent Pb(2) and one C(8) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Pb(2) and one C(8) atom. Linkers: 16 [O]C(=O)[C@H]1CC[C@@H](C([O])=O)CC1. Metal clusters: 16 [Pb]. The MOF has largest included sphere 3.27 A, density 2.37 g/cm3, surface area 3024.29 m2/g, accessible volume 0.08 cm3/g