AgC6N3H6O2 is diamond structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AgC6N3H6O2 clusters. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one N(9), one O(1), and one O(3) atom. The Ag(1)-N(9) bond length is 2.17 Å. The Ag(1)-O(1) bond length is 2.33 Å. The Ag(1)-O(3) bond length is 2.32 Å. In the second Ag site, Ag(2,4) is bonded in a 3-coordinate geometry to one N(10), one O(1), and one O(2) atom. The Ag(2,4)-N(10) bond length is 2.17 Å. The Ag(2,4)-O(1) bond length is 2.32 Å. The Ag(2,4)-O(2) bond length is 2.33 Å. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one N(11), one O(3), and one O(4) atom. The Ag(3)-N(11) bond length is 2.17 Å. The Ag(3)-O(3) bond length is 2.33 Å. The Ag(3)-O(4) bond length is 2.32 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1,4); one N(5,8); and one N(9) atom. The C(1)-N(1,4) bond length is 1.35 Å. The C(1)-N(5,8) bond length is 1.35 Å. The C(1)-N(9) bond length is 1.37 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(10); one N(2,3); and one N(6,7) atom. The C(2)-N(10) bond length is 1.37 Å. The C(2)-N(2,3) bond length is 1.35 Å. The C(2)-N(6,7) bond length is 1.35 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(11); one N(2,3); and one N(6,7) atom. The C(3)-N(11) bond length is 1.37 Å. The C(3)-N(2,3) bond length is 1.35 Å. The C(3)-N(6,7) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(1,4); one N(12); and one N(5,8) atom. The C(4)-N(1,4) bond length is 1.35 Å. The C(4)-N(12) bond length is 1.37 Å. The C(4)-N(5,8) bond length is 1.35 Å. In the fifth C site, C(5,6,7) is bonded in a distorted trigonal planar geometry to one C(9,10,11,12); one N(9); and one H(5,6,7,8) atom. The C(5,6,7)-C(9,10,11,12) bond length is 1.39 Å. The C(5,6,7)-N(9) bond length is 1.34 Å. The C(5,6,7)-H(5,6,7,8) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9,10,11,12); one N(12); and one H(5,6,7,8) atom. The C(8)-C(9,10,11,12) bond length is 1.39 Å. The C(8)-N(12) bond length is 1.34 Å. The C(8)-H(5,6,7,8) bond length is 1.09 Å. In the seventh C site, C(9,10,11,12) is bonded in a distorted single-bond geometry to one C(13,14,15); one C(5,6,7); and one H(9,10,11) atom. The C(9,10,11,12)-C(13,14,15) bond length is 1.39 Å. The C(9,10,11,12)-H(9,10,11) bond length is 1.09 Å. In the eighth C site, C(13,14,15) is bonded in a distorted trigonal planar geometry to one C(9,10,11,12); one N(1,4); and one H(13,14,15,16) atom. The C(13,14,15)-N(1,4) bond length is 1.33 Å. The C(13,14,15)-H(13,14,15,16) bond length is 1.09 Å. In the ninth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(9,10,11,12); one N(1,4); and one H(13,14,15,16) atom. The C(16)-C(9,10,11,12) bond length is 1.39 Å. The C(16)-N(1,4) bond length is 1.33 Å. The C(16)-H(13,14,15,16) bond length is 1.09 Å. In the tenth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one N(5,8); one H(17,20); and one H(21,24) atom. The C(17)-N(5,8) bond length is 1.44 Å. The C(17)-H(17,20) bond length is 1.10 Å. The C(17)-H(21,24) bond length is 1.10 Å. In the eleventh C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one N(6,7); one H(18,19); and one H(22,23) atom. The C(18)-N(6,7) bond length is 1.44 Å. The C(18)-H(18,19) bond length is 1.10 Å. The C(18)-H(22,23) bond length is 1.10 Å. In the twelfth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one N(6,7); one H(18,19); and one H(22,23) atom. The C(19)-N(6,7) bond length is 1.44 Å. The C(19)-H(18,19) bond length is 1.10 Å. The C(19)-H(22,23) bond length is 1.10 Å. In the thirteenth C site, C(20) is bonded in a distorted trigonal non-coplanar geometry to one N(5,8); one H(17,20); and one H(21,24) atom. The C(20)-N(5,8) bond length is 1.44 Å. The C(20)-H(17,20) bond length is 1.10 Å. The C(20)-H(21,24) bond length is 1.10 Å. In the fourteenth C site, C(21,22) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(5) atom. The C(21,22)-O(1) bond length is 1.28 Å. The C(21,22)-O(5) bond length is 1.26 Å. In the fifteenth C site, C(23,24) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(7) atom. The C(23,24)-O(3) bond length is 1.28 Å. The C(23,24)-O(7) bond length is 1.26 Å. There are eight inequivalent N sites. In the first N site, N(1,4) is bonded in a bent 120 degrees geometry to one C(1) and one C(13,14,15) atom. In the second N site, N(2,3) is bonded in a bent 120 degrees geometry to one C(13,14,15) and one C(2) atom. The N(2,3)-C(13,14,15) bond length is 1.33 Å. In the third N site, N(5,8) is bonded in a trigonal planar geometry to one C(1), one C(17), and one H(1) atom. The N(5,8)-H(1) bond length is 1.04 Å. In the fourth N site, N(6,7) is bonded in a trigonal planar geometry to one C(18), one C(2), and one H(2) atom. The N(6,7)-H(2) bond length is 1.04 Å. In the fifth N site, N(9) is bonded in a trigonal planar geometry to one Ag(1); one C(1); and one C(5,6,7) atom. In the sixth N site, N(10) is bonded in a trigonal planar geometry to one Ag(2,4); one C(2); and one C(5,6,7) atom. The N(10)-C(5,6,7) bond length is 1.34 Å. In the seventh N site, N(11) is bonded in a trigonal planar geometry to one Ag(3); one C(3); and one C(5,6,7) atom. The N(11)-C(5,6,7) bond length is 1.34 Å. In the eighth N site, N(12) is bonded in a trigonal planar geometry to one Ag(2,4); one C(4); and one C(8) atom. The N(12)-Ag(2,4) bond length is 2.17 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(5,8) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(6,7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(6,7) atom. The H(3)-N(6,7) bond length is 1.04 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(5,8) atom. The H(4)-N(5,8) bond length is 1.04 Å. In the fifth H site, H(5,6,7,8) is bonded in a single-bond geometry to one C(5,6,7) atom. In the sixth H site, H(9,10,11) is bonded in a single-bond geometry to one C(9,10,11,12) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(9,10,11,12) atom. The H(12)-C(9,10,11,12) bond length is 1.09 Å. In the eighth H site, H(13,14,15,16) is bonded in a single-bond geometry to one C(13,14,15) atom. In the ninth H site, H(17,20) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(18,19) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(21,24) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(22,23) is bonded in a single-bond geometry to one C(18) atom. There are eight inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Ag(2,4) and one C(21,22) atom. The O(2)-C(21,22) bond length is 1.28 Å. In the second O site, O(3) is bonded in a distorted trigonal planar geometry to one Ag(1); one Ag(3); and one C(23,24) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to one Ag(1); one Ag(2,4); and one C(21,22) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Ag(2,4); one Ag(3); and one C(23,24) atom. The O(4)-Ag(2,4) bond length is 2.33 Å. The O(4)-C(23,24) bond length is 1.28 Å. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(21,22) atom. The O(6)-C(21,22) bond length is 1.26 Å. In the sixth O site, O(7) is bonded in a single-bond geometry to one C(23,24) atom. In the seventh O site, O(5) is bonded in a single-bond geometry to one C(21,22) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(23,24) atom. The O(8)-C(23,24) bond length is 1.26 Å. Linkers: 8 [O]C(=O)CNc1ncccn1. Metal clusters: 2 O=[C]O[Ag][Ag]O[C]=O.O=[C]O[Ag][Ag]O[C]=O. The MOF has largest included sphere 2.96 A, density 2.34 g/cm3, surface area 2936.83 m2/g, accessible volume 0.09 cm3/g