PbC14H12S2(NO2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two PbC14H12S2(NO2)2 clusters. Pb(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one O(3), and one O(4) atom. The Pb(1)-N(1) bond length is 2.68 Å. The Pb(1)-N(2) bond length is 2.68 Å. The Pb(1)-O(3) bond length is 2.57 Å. The Pb(1)-O(4) bond length is 2.57 Å. There are nine inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal planar geometry to one C(3); one N(1); and one H(1,2) atom. The C(1,2)-C(3) bond length is 1.39 Å. The C(1,2)-N(1) bond length is 1.34 Å. The C(1,2)-H(1,2) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(1,2); one C(5,6); and one H(3,4) atom. The C(3)-C(5,6) bond length is 1.40 Å. The C(3)-H(3,4) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(1,2); one C(5,6); and one H(3,4) atom. The C(4)-C(1,2) bond length is 1.39 Å. The C(4)-C(5,6) bond length is 1.40 Å. The C(4)-H(3,4) bond length is 1.09 Å. In the fourth C site, C(5,6) is bonded in a trigonal planar geometry to one C(3), one C(7), and one S(1) atom. The C(5,6)-C(7) bond length is 1.41 Å. The C(5,6)-S(1) bond length is 1.74 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5,6); one C(9,10); and one H(5,6) atom. The C(7)-C(9,10) bond length is 1.39 Å. The C(7)-H(5,6) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(5,6); one C(9,10); and one H(5,6) atom. The C(8)-C(5,6) bond length is 1.41 Å. The C(8)-C(9,10) bond length is 1.39 Å. The C(8)-H(5,6) bond length is 1.09 Å. In the seventh C site, C(9,10) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one H(7) atom. The C(9,10)-N(1) bond length is 1.35 Å. The C(9,10)-H(7) bond length is 1.09 Å. In the eighth C site, C(11,12) is bonded in a distorted water-like geometry to one H(11,12); one H(9,10); and one S(1) atom. The C(11,12)-H(11,12) bond length is 1.09 Å. The C(11,12)-H(9,10) bond length is 1.10 Å. The C(11,12)-S(1) bond length is 1.80 Å. In the ninth C site, C(13,14) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(13,14)-O(1) bond length is 1.27 Å. The C(13,14)-O(3) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Pb(1); one C(1,2); and one C(9,10) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pb(1); one C(1,2); and one C(9,10) atom. The N(2)-C(1,2) bond length is 1.34 Å. The N(2)-C(9,10) bond length is 1.35 Å. There are seven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(9,10) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(9,10) atom. The H(8)-C(9,10) bond length is 1.09 Å. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(11,12) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(11,12) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(11,12) and one C(5,6) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(11,12) and one C(5,6) atom. The S(2)-C(11,12) bond length is 1.80 Å. The S(2)-C(5,6) bond length is 1.74 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(13,14) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(13,14) atom. The O(2)-C(13,14) bond length is 1.27 Å. In the third O site, O(3) is bonded in a single-bond geometry to one Pb(1) and one C(13,14) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Pb(1) and one C(13,14) atom. The O(4)-C(13,14) bond length is 1.27 Å. Linkers: 4 [O]C(=O)CSc1ccncc1. Metal clusters: 2 [Pb]. The MOF has largest included sphere 1.90 A, density 2.36 g/cm3, surface area 2963.13 m2/g, accessible volume 0.05 cm3/g