AgC3N7H8 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AgC3N7H8 clusters. Ag(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(2), one N(3), and one N(7) atom. The Ag(1)-N(1) bond length is 2.26 Å. The Ag(1)-N(2) bond length is 2.26 Å. The Ag(1)-N(3) bond length is 2.38 Å. The Ag(1)-N(7) bond length is 2.47 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(3), one N(6), and one N(7) atom. The C(1)-N(3) bond length is 1.35 Å. The C(1)-N(6) bond length is 1.35 Å. The C(1)-N(7) bond length is 1.38 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(2)-N(1) bond length is 1.48 Å. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(3), and one H(4) atom. The C(3)-N(2) bond length is 1.47 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(4) bond length is 1.10 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Ag(1), one C(2), one H(5), and one H(8) atom. The N(1)-H(5) bond length is 1.03 Å. The N(1)-H(8) bond length is 1.02 Å. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Ag(1), one C(3), one H(6), and one H(7) atom. The N(2)-H(6) bond length is 1.03 Å. The N(2)-H(7) bond length is 1.03 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Ag(1), one C(1), and one N(4) atom. The N(3)-N(4) bond length is 1.33 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one N(3) and one N(5) atom. The N(4)-N(5) bond length is 1.34 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.33 Å. In the sixth N site, N(6) is bonded in a distorted water-like geometry to one C(1) and one N(5) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one N(7) atom. The N(7)-N(7) bond length is 1.29 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(1) atom. Linkers: 4 [N][N]C(=[N])[N][N][C]1=NN=NN=1 ,2 N1=NN=[C](=N1)[N][N][C]1=NN=NN=1 ,4 NCCN. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.88 A, density 2.31 g/cm3, surface area 3287.86 m2/g, accessible volume 0.07 cm3/g