TlC3NH2O3CH2(CH)7C2NH2O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two n-methylformamide molecules, two toluene molecules, and one TlC3NH2O3 cluster. In the TlC3NH2O3 cluster, Tl(1) is bonded in a 3-coordinate geometry to one O(3) and two equivalent O(1) atoms. The Tl(1)-O(3) bond length is 2.84 Å. There is one shorter (2.79 Å) and one longer (2.82 Å) Tl(1)-O(1) bond length. There are three inequivalent C sites. In the first C site, C(5) is bonded in a distorted water-like geometry to one N(2) and one H(6) atom. The C(5)-N(2) bond length is 1.45 Å. The C(5)-H(6) bond length is 1.10 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(3) atom. The C(6)-N(2) bond length is 1.33 Å. The C(6)-O(3) bond length is 1.26 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.27 Å. N(2) is bonded in a trigonal planar geometry to one C(5), one C(6), and one H(2) atom. The N(2)-H(2) bond length is 1.04 Å. There are two inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(5) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to two equivalent Tl(1) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Tl(1) and one C(6) atom. Linkers: 1 [O]C(=O)C[C@@H]1NC(=O)[C@H](Cc2ccccc2)NC1=O ,1 [O]C(=O)C[C@H]1NC(=O)[C@@H](Cc2ccccc2)NC1=O. Metal clusters: 2 [Tl]. The MOF has largest included sphere 1.95 A, density 2.41 g/cm3, surface area 3063.78 m2/g, accessible volume 0.07 cm3/g