Co3H16(C5O9)2(CF3)6 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of six trifluoromethane molecules and one Co3H16(C5O9)2 cluster. In the Co3H16(C5O9)2 cluster, there are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(17), one O(18), one O(2), one O(5), and one O(6) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 68-71°. The Co(1)-O(1) bond length is 1.92 Å. The Co(1)-O(17) bond length is 2.24 Å. The Co(1)-O(18) bond length is 2.21 Å. The Co(1)-O(2) bond length is 1.93 Å. The Co(1)-O(5) bond length is 1.90 Å. The Co(1)-O(6) bond length is 1.91 Å. In the second Co site, Co(2) is bonded to one O(13), one O(15), one O(17), one O(3), one O(7), and one O(9) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 71°. The Co(2)-O(13) bond length is 2.08 Å. The Co(2)-O(15) bond length is 2.18 Å. The Co(2)-O(17) bond length is 2.07 Å. The Co(2)-O(3) bond length is 2.04 Å. The Co(2)-O(7) bond length is 2.09 Å. The Co(2)-O(9) bond length is 2.07 Å. In the third Co site, Co(3) is bonded to one O(10), one O(14), one O(16), one O(18), one O(4), and one O(8) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 68°. The Co(3)-O(10) bond length is 2.07 Å. The Co(3)-O(14) bond length is 2.07 Å. The Co(3)-O(16) bond length is 2.18 Å. The Co(3)-O(18) bond length is 2.05 Å. The Co(3)-O(4) bond length is 2.05 Å. The Co(3)-O(8) bond length is 2.10 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one O(1) and one O(3) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(3) bond length is 1.26 Å. In the second C site, C(2) is bonded in a 2-coordinate geometry to one O(2) and one O(4) atom. The C(2)-O(2) bond length is 1.26 Å. The C(2)-O(4) bond length is 1.26 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(7) atom. The C(5)-O(5) bond length is 1.27 Å. The C(5)-O(7) bond length is 1.25 Å. In the fourth C site, C(6) is bonded in a 2-coordinate geometry to one O(6) and one O(8) atom. The C(6)-O(6) bond length is 1.27 Å. The C(6)-O(8) bond length is 1.25 Å. In the fifth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(9) atom. The C(9)-O(11) bond length is 1.26 Å. The C(9)-O(9) bond length is 1.27 Å. In the sixth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(12) atom. The C(10)-O(10) bond length is 1.27 Å. The C(10)-O(12) bond length is 1.26 Å. In the seventh C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(3), and one O(13) atom. The C(13)-H(1) bond length is 1.10 Å. The C(13)-H(3) bond length is 1.09 Å. The C(13)-O(13) bond length is 1.45 Å. In the eighth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one H(2), one H(4), and one O(14) atom. The C(14)-H(2) bond length is 1.10 Å. The C(14)-H(4) bond length is 1.09 Å. The C(14)-O(14) bond length is 1.45 Å. In the ninth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(7), and one O(13) atom. The C(15)-H(5) bond length is 1.09 Å. The C(15)-H(7) bond length is 1.10 Å. The C(15)-O(13) bond length is 1.45 Å. In the tenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one H(6), one H(8), and one O(14) atom. The C(16)-H(6) bond length is 1.09 Å. The C(16)-H(8) bond length is 1.10 Å. The C(16)-O(14) bond length is 1.45 Å. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(17) atom. The H(9)-O(17) bond length is 0.98 Å. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(18) atom. The H(10)-O(18) bond length is 0.98 Å. In the eleventh H site, H(11) is bonded in a distorted linear geometry to one O(11) and one O(17) atom. The H(11)-O(11) bond length is 1.47 Å. The H(11)-O(17) bond length is 1.06 Å. In the twelfth H site, H(12) is bonded in a distorted linear geometry to one O(12) and one O(18) atom. The H(12)-O(12) bond length is 1.44 Å. The H(12)-O(18) bond length is 1.07 Å. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one O(15) atom. The H(13)-O(15) bond length is 0.97 Å. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one O(16) atom. The H(14)-O(16) bond length is 0.97 Å. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one O(15) atom. The H(15)-O(15) bond length is 0.97 Å. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one O(16) atom. The H(16)-O(16) bond length is 0.97 Å. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(3) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Co(1) and one C(5) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Co(1) and one C(6) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one C(5) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Co(3) and one C(6) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Co(2) and one C(9) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Co(3) and one C(10) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one C(9) and one H(11) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one C(10) and one H(12) atom. In the thirteenth O site, O(13) is bonded in a trigonal planar geometry to one Co(2), one C(13), and one C(15) atom. In the fourteenth O site, O(14) is bonded in a trigonal planar geometry to one Co(3), one C(14), and one C(16) atom. In the fifteenth O site, O(15) is bonded in a distorted water-like geometry to one Co(2), one H(13), and one H(15) atom. In the sixteenth O site, O(16) is bonded in a distorted water-like geometry to one Co(3), one H(14), and one H(16) atom. In the seventeenth O site, O(17) is bonded in a distorted water-like geometry to one Co(1), one Co(2), one H(11), and one H(9) atom. In the eighteenth O site, O(18) is bonded in a distorted water-like geometry to one Co(1), one Co(3), one H(10), and one H(12) atom. Linkers: 1 C1COCCO1. Metal clusters: 3 [Co]. The MOF has largest included sphere 4.11 A, density 1.74 g/cm3, surface area 3731.97 m2/g, accessible volume 0.15 cm3/g