(CH2)2CdC27N6H25O6Cl is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CdC27N6H25O6Cl clusters. In each CdC27N6H25O6Cl cluster, Cd(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(3), one O(1), one O(2), and one Cl(1) atom. The Cd(1)-N(1) bond length is 2.28 Å. The Cd(1)-N(3) bond length is 2.26 Å. The Cd(1)-O(1) bond length is 2.46 Å. The Cd(1)-O(2) bond length is 2.37 Å. The Cd(1)-Cl(1) bond length is 2.47 Å. There are twenty-seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one N(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.41 Å. The C(2)-N(1) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.43 Å. The C(4)-C(8) bond length is 1.51 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(9) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(9) bond length is 1.50 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(3) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one N(2) atom. The C(7)-N(2) bond length is 1.39 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one H(4), one H(5), and one H(6) atom. The C(8)-H(4) bond length is 1.10 Å. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.10 Å. In the ninth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one H(7), one H(8), and one H(9) atom. The C(9)-H(7) bond length is 1.10 Å. The C(9)-H(8) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. In the tenth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(10), and one H(11) atom. The C(10)-N(2) bond length is 1.46 Å. The C(10)-H(10) bond length is 1.10 Å. The C(10)-H(11) bond length is 1.10 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(14) atom. The C(12)-N(3) bond length is 1.33 Å. The C(12)-N(4) bond length is 1.36 Å. The C(12)-H(14) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one N(3) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(18) bond length is 1.41 Å. The C(13)-N(3) bond length is 1.39 Å. In the thirteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(15) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(15) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(19) atom. The C(15)-C(16) bond length is 1.43 Å. The C(15)-C(19) bond length is 1.50 Å. In the fifteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(20) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(20) bond length is 1.51 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(16) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(16) bond length is 1.09 Å. In the seventeenth C site, C(18) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one N(4) atom. The C(18)-N(4) bond length is 1.39 Å. In the eighteenth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one C(15), one H(17), one H(18), and one H(19) atom. The C(19)-H(17) bond length is 1.10 Å. The C(19)-H(18) bond length is 1.10 Å. The C(19)-H(19) bond length is 1.10 Å. In the nineteenth C site, C(20) is bonded in a distorted trigonal non-coplanar geometry to one C(16), one H(20), one H(21), and one H(22) atom. The C(20)-H(20) bond length is 1.10 Å. The C(20)-H(21) bond length is 1.10 Å. The C(20)-H(22) bond length is 1.10 Å. In the twentieth C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(23), and one H(24) atom. The C(21)-N(4) bond length is 1.46 Å. The C(21)-H(23) bond length is 1.10 Å. The C(21)-H(24) bond length is 1.10 Å. In the twenty-first C site, C(23) is bonded in a trigonal planar geometry to one C(24), one C(28), and one C(29) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-C(28) bond length is 1.40 Å. The C(23)-C(29) bond length is 1.50 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(27) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(27) bond length is 1.09 Å. In the twenty-third C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one C(26), and one N(5) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-N(5) bond length is 1.46 Å. In the twenty-fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(25), one C(27), and one H(28) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-H(28) bond length is 1.09 Å. In the twenty-fifth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(26), one C(28), and one N(6) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-N(6) bond length is 1.47 Å. In the twenty-sixth C site, C(28) is bonded in a distorted single-bond geometry to one C(23), one C(27), and one H(29) atom. The C(28)-H(29) bond length is 1.09 Å. In the twenty-seventh C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(1), and one O(2) atom. The C(29)-O(1) bond length is 1.27 Å. The C(29)-O(2) bond length is 1.28 Å. There are six inequivalent N sites. In the first N site, N(6) is bonded in a trigonal planar geometry to one C(27), one O(5), and one O(6) atom. The N(6)-O(5) bond length is 1.24 Å. The N(6)-O(6) bond length is 1.24 Å. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(7) atom. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(12), and one C(13) atom. In the fifth N site, N(4) is bonded in a trigonal planar geometry to one C(12), one C(18), and one C(21) atom. In the sixth N site, N(5) is bonded in a trigonal planar geometry to one C(25), one O(3), and one O(4) atom. The N(5)-O(3) bond length is 1.24 Å. The N(5)-O(4) bond length is 1.24 Å. There are twenty-five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(20) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(20) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(21) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(21) atom. In the twenty-third H site, H(27) is bonded in a single-bond geometry to one C(24) atom. In the twenty-fourth H site, H(28) is bonded in a single-bond geometry to one C(26) atom. In the twenty-fifth H site, H(29) is bonded in a single-bond geometry to one C(28) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(29) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(29) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(5) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(5) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(6) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(6) atom. Cl(1) is bonded in a single-bond geometry to one Cd(1) atom. Linkers: 2 Cc1cc2ncn(CCCCn3cnc4cc(C)c(C)cc43)c2cc1C ,2 [CH2]/[C]=C/c1[c]ncn1CCCCn1cnc2cc(C)c(C)cc21. Metal clusters: 2 [Cd]. The MOF has largest included sphere 2.94 A, density 1.51 g/cm3, surface area 4876.60 m2/g, accessible volume 0.15 cm3/g