CdC7H6(N2S)2 crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded in a distorted octahedral geometry to one N(1), one N(2), one N(3), one N(4), one S(1), and one S(2) atom. The Cd(1)-N(1) bond length is 2.28 Å. The Cd(1)-N(2) bond length is 2.32 Å. The Cd(1)-N(3) bond length is 2.45 Å. The Cd(1)-N(4) bond length is 2.43 Å. The Cd(1)-S(1) bond length is 2.72 Å. The Cd(1)-S(2) bond length is 2.73 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.63 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(2) atom. The C(2)-N(2) bond length is 1.18 Å. The C(2)-S(2) bond length is 1.63 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(4), and one H(1) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-N(4) bond length is 1.34 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one N(3) atom. The C(4)-C(7) bond length is 1.49 Å. The C(4)-N(3) bond length is 1.35 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(3), and one H(2) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(3) bond length is 1.34 Å. The C(5)-H(2) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(4), and one H(3) atom. The C(6)-N(4) bond length is 1.34 Å. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one H(4), one H(5), and one H(6) atom. The C(7)-H(4) bond length is 1.10 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted linear geometry to one Cd(1) and one C(1) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(2) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(4), and one C(5) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(3), and one C(6) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Cd(1) and one C(2) atom. Linkers: 4 Cc1cnccn1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 2.21 A, density 2.06 g/cm3, surface area 3910.13 m2/g, accessible volume 0.11 cm3/g