CuC24H27(SO)8 crystallizes in the triclinic P-1 space group. Cu(1) is bonded in a tetrahedral geometry to one S(3), one S(4), one S(5), and one S(6) atom. The Cu(1)-S(3) bond length is 2.30 Å. The Cu(1)-S(4) bond length is 2.24 Å. The Cu(1)-S(5) bond length is 2.26 Å. The Cu(1)-S(6) bond length is 2.29 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one S(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(3) bond length is 1.41 Å. The C(1)-S(1) bond length is 1.77 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.50 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one S(2) atom. The C(3)-S(2) bond length is 1.78 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(4)-O(1) bond length is 1.30 Å. The C(4)-O(2) bond length is 1.25 Å. In the fifth C site, C(5) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(1) atom. The C(5)-H(1) bond length is 1.09 Å. The C(5)-H(2) bond length is 1.10 Å. The C(5)-H(3) bond length is 1.10 Å. The C(5)-S(1) bond length is 1.81 Å. In the sixth C site, C(6) is bonded in a trigonal non-coplanar geometry to one H(4), one H(5), one H(6), and one S(2) atom. The C(6)-H(4) bond length is 1.10 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. The C(6)-S(2) bond length is 1.81 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(17), one C(8), and one S(3) atom. The C(7)-C(17) bond length is 1.40 Å. The C(7)-C(8) bond length is 1.41 Å. The C(7)-S(3) bond length is 1.78 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(17), one C(7), and one S(4) atom. The C(8)-C(17) bond length is 1.40 Å. The C(8)-S(4) bond length is 1.79 Å. In the ninth C site, C(9) is bonded in a trigonal non-coplanar geometry to one H(10), one H(8), one H(9), and one S(3) atom. The C(9)-H(10) bond length is 1.09 Å. The C(9)-H(8) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. The C(9)-S(3) bond length is 1.82 Å. In the tenth C site, C(10) is bonded in a trigonal non-coplanar geometry to one H(11), one H(12), one H(13), and one S(4) atom. The C(10)-H(11) bond length is 1.09 Å. The C(10)-H(12) bond length is 1.10 Å. The C(10)-H(13) bond length is 1.09 Å. The C(10)-S(4) bond length is 1.82 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(12), one C(13), and one S(5) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-C(13) bond length is 1.40 Å. The C(11)-S(5) bond length is 1.79 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one S(6) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-S(6) bond length is 1.78 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(14) atom. The C(13)-C(14) bond length is 1.52 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.28 Å. The C(14)-O(4) bond length is 1.26 Å. In the fifteenth C site, C(15) is bonded in a trigonal non-coplanar geometry to one H(14), one H(15), one H(16), and one S(5) atom. The C(15)-H(14) bond length is 1.09 Å. The C(15)-H(15) bond length is 1.10 Å. The C(15)-H(16) bond length is 1.10 Å. The C(15)-S(5) bond length is 1.82 Å. In the sixteenth C site, C(16) is bonded in a trigonal non-coplanar geometry to one H(17), one H(18), one H(19), and one S(6) atom. The C(16)-H(17) bond length is 1.09 Å. The C(16)-H(18) bond length is 1.10 Å. The C(16)-H(19) bond length is 1.09 Å. The C(16)-S(6) bond length is 1.81 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(18), one C(7), and one C(8) atom. The C(17)-C(18) bond length is 1.52 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(5), and one O(6) atom. The C(18)-O(5) bond length is 1.33 Å. The C(18)-O(6) bond length is 1.23 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(20), one C(21), and one S(7) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-C(21) bond length is 1.41 Å. The C(19)-S(7) bond length is 1.77 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one S(8) atom. The C(20)-C(21) bond length is 1.41 Å. The C(20)-S(8) bond length is 1.78 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(19), one C(20), and one C(22) atom. The C(21)-C(22) bond length is 1.51 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(7), and one O(8) atom. The C(22)-O(7) bond length is 1.33 Å. The C(22)-O(8) bond length is 1.23 Å. In the twenty-third C site, C(23) is bonded in a trigonal non-coplanar geometry to one H(21), one H(22), one H(23), and one S(7) atom. The C(23)-H(21) bond length is 1.10 Å. The C(23)-H(22) bond length is 1.10 Å. The C(23)-H(23) bond length is 1.10 Å. The C(23)-S(7) bond length is 1.81 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal non-coplanar geometry to one H(24), one H(25), one H(26), and one S(8) atom. The C(24)-H(24) bond length is 1.10 Å. The C(24)-H(25) bond length is 1.09 Å. The C(24)-H(26) bond length is 1.09 Å. The C(24)-S(8) bond length is 1.82 Å. There are twenty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a linear geometry to one O(1) and one O(3) atom. The H(7)-O(1) bond length is 1.14 Å. The H(7)-O(3) bond length is 1.30 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(15) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(16) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(16) atom. In the twentieth H site, H(20) is bonded in a linear geometry to one O(2) and one O(5) atom. The H(20)-O(2) bond length is 1.49 Å. The H(20)-O(5) bond length is 1.05 Å. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(23) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(23) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(23) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(24) atom. In the twenty-fifth H site, H(25) is bonded in a single-bond geometry to one C(24) atom. In the twenty-sixth H site, H(26) is bonded in a single-bond geometry to one C(24) atom. In the twenty-seventh H site, H(27) is bonded in a distorted bent 150 degrees geometry to one O(4) and one O(7) atom. The H(27)-O(4) bond length is 1.60 Å. The H(27)-O(7) bond length is 1.01 Å. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(1) and one C(5) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(3) and one C(6) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(7), and one C(9) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(10), and one C(8) atom. In the fifth S site, S(5) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(11), and one C(15) atom. In the sixth S site, S(6) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(12), and one C(16) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one C(19) and one C(23) atom. In the eighth S site, S(8) is bonded in a water-like geometry to one C(20) and one C(24) atom. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one C(18) and one H(20) atom. In the second O site, O(6) is bonded in a single-bond geometry to one C(18) atom. In the third O site, O(7) is bonded in a bent 120 degrees geometry to one C(22) and one H(27) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one C(22) atom. In the fifth O site, O(1) is bonded in a bent 120 degrees geometry to one C(4) and one H(7) atom. In the sixth O site, O(2) is bonded in a bent 120 degrees geometry to one C(4) and one H(20) atom. In the seventh O site, O(3) is bonded in a bent 120 degrees geometry to one C(14) and one H(7) atom. In the eighth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one C(14) and one H(27) atom. Linkers: 1 CSc1c(SC)c(C(=O)O)c(SC)c(SC)c1C(=O)O ,2 [CH2]Sc1c(SC)c(C([O])=O)c(SC)c(SC)c1C([O])=O ,1 CSc1c(SC)c(C([O])=O)c(SC)c(SC)c1C([O])=O. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.37 A, density 1.69 g/cm3, surface area 4380.08 m2/g, accessible volume 0.12 cm3/g