Cd2C33H20(N2O3)3(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a Cd2C33H20(N2O3)3 framework. In the Cd2C33H20(N2O3)3 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 6-coordinate geometry to one N(6), one O(1), one O(7), one O(9), and two equivalent O(8) atoms. The Cd(1)-N(6) bond length is 2.37 Å. The Cd(1)-O(1) bond length is 2.33 Å. The Cd(1)-O(7) bond length is 2.42 Å. The Cd(1)-O(9) bond length is 2.31 Å. There is one shorter (2.34 Å) and one longer (2.50 Å) Cd(1)-O(8) bond length. In the second Cd site, Cd(2) is bonded to one N(1), one N(4), one O(3), one O(4), one O(5), and two equivalent O(6) atoms to form distorted edge-sharing CdN2O5 pentagonal bipyramids. The Cd(2)-N(1) bond length is 2.49 Å. The Cd(2)-N(4) bond length is 2.33 Å. The Cd(2)-O(3) bond length is 2.30 Å. The Cd(2)-O(4) bond length is 2.53 Å. The Cd(2)-O(5) bond length is 2.27 Å. There is one shorter (2.41 Å) and one longer (2.65 Å) Cd(2)-O(6) bond length. There are thirty-three inequivalent C sites. In the first C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(7) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(8) bond length is 1.38 Å. The C(9)-H(7) bond length is 1.09 Å. In the second C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(10)-H(8) bond length is 1.09 Å. In the third C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(9) atom. The C(11)-C(12) bond length is 1.42 Å. The C(11)-H(9) bond length is 1.09 Å. In the fourth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(2), and one C(7) atom. The C(12)-C(2) bond length is 1.43 Å. The C(12)-C(7) bond length is 1.44 Å. In the fifth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(5), and one O(6) atom. The C(13)-C(14) bond length is 1.50 Å. The C(13)-O(5) bond length is 1.28 Å. The C(13)-O(6) bond length is 1.28 Å. In the sixth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(24) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-C(24) bond length is 1.43 Å. In the seventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(10) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(10) bond length is 1.09 Å. In the eighth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(11) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(11) bond length is 1.09 Å. In the ninth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(19) atom. The C(17)-C(18) bond length is 1.50 Å. The C(17)-C(19) bond length is 1.43 Å. In the tenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(7), and one O(8) atom. The C(18)-O(7) bond length is 1.27 Å. The C(18)-O(8) bond length is 1.29 Å. In the eleventh C site, C(19) is bonded in a trigonal planar geometry to one C(17), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.42 Å. The C(19)-C(24) bond length is 1.44 Å. In the twelfth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(12) atom. The C(20)-H(12) bond length is 1.09 Å. In the thirteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(15) atom. The C(23)-C(24) bond length is 1.42 Å. The C(23)-H(15) bond length is 1.09 Å. In the fourteenth C site, C(24) is bonded in a trigonal planar geometry to one C(14), one C(19), and one C(23) atom. In the fifteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one N(1), and one H(16) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-N(1) bond length is 1.33 Å. The C(25)-H(16) bond length is 1.09 Å. In the sixteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(25), one N(2), and one H(17) atom. The C(26)-N(2) bond length is 1.34 Å. The C(26)-H(17) bond length is 1.09 Å. In the seventeenth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(28), one N(2), and one H(18) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-N(2) bond length is 1.34 Å. The C(27)-H(18) bond length is 1.09 Å. In the eighteenth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one C(29), and one N(1) atom. The C(28)-C(29) bond length is 1.46 Å. The C(28)-N(1) bond length is 1.35 Å. In the nineteenth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one N(3), and one N(4) atom. The C(29)-N(3) bond length is 1.35 Å. The C(29)-N(4) bond length is 1.34 Å. In the twentieth C site, C(30) is bonded in a distorted water-like geometry to one C(31), one N(3), and one N(5) atom. The C(30)-C(31) bond length is 1.46 Å. The C(30)-N(3) bond length is 1.35 Å. The C(30)-N(5) bond length is 1.36 Å. In the twenty-first C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(35) atom. The C(31)-C(32) bond length is 1.40 Å. The C(31)-C(35) bond length is 1.40 Å. In the twenty-second C site, C(32) is bonded in a distorted single-bond geometry to one C(31), one C(33), and one H(19) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-H(19) bond length is 1.09 Å. In the twenty-third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the twenty-fourth C site, C(33) is bonded in a distorted trigonal planar geometry to one C(32), one N(6), and one H(20) atom. The C(33)-N(6) bond length is 1.34 Å. The C(33)-H(20) bond length is 1.09 Å. In the twenty-fifth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(12), and one C(3) atom. The C(2)-C(3) bond length is 1.38 Å. In the twenty-sixth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(21) atom. The C(34)-N(6) bond length is 1.35 Å. The C(34)-H(21) bond length is 1.09 Å. In the twenty-seventh C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(3)-H(4) bond length is 1.09 Å. In the twenty-eighth C site, C(35) is bonded in a distorted single-bond geometry to one C(31) and one H(22) atom. The C(35)-H(22) bond length is 1.09 Å. In the twenty-ninth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(5) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(5) bond length is 1.09 Å. In the thirtieth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.50 Å. The C(5)-C(7) bond length is 1.43 Å. In the thirty-first C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(3), and one O(4) atom. The C(6)-O(3) bond length is 1.26 Å. The C(6)-O(4) bond length is 1.29 Å. In the thirty-second C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(5), and one C(8) atom. The C(7)-C(8) bond length is 1.42 Å. In the thirty-third C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(6) is bonded in a trigonal planar geometry to one Cd(1), one C(33), and one C(34) atom. In the second N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(29), and one N(5) atom. The N(4)-N(5) bond length is 1.33 Å. In the third N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(25), and one C(28) atom. In the fourth N site, N(2) is bonded in a bent 120 degrees geometry to one C(26) and one C(27) atom. In the fifth N site, N(3) is bonded in a water-like geometry to one C(29) and one C(30) atom. In the sixth N site, N(5) is bonded in a 3-coordinate geometry to one C(30), one N(4), and one H(3) atom. The N(5)-H(3) bond length is 1.08 Å. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(9) atom. The H(1)-O(9) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(9) atom. The H(2)-O(9) bond length is 0.99 Å. In the third H site, H(3) is bonded in a linear geometry to one N(5) and one O(4) atom. The H(3)-O(4) bond length is 1.55 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(27) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(32) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(33) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(34) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(35) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(2) and one C(6) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Cd(2), one C(6), and one H(3) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Cd(2) and one C(13) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Cd(2) and one C(13) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cd(1) and one C(18) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(18) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Cd(1), one H(1), and one H(2) atom. Linkers: 8 [O]C(=O)c1ccc(C([O])=O)c2ccccc12 ,3 c1cc([C]2N=C(c3cnccn3)[N]N2)ccn1 ,1 c1cc(-c2nc(-c3cnccn3)n[nH]2)ccn1. Metal clusters: 8 [Cd]. The MOF has largest included sphere 2.73 A, density 1.89 g/cm3, surface area 3649.91 m2/g, accessible volume 0.09 cm3/g