Na2CdC6N7H14O10CH crystallizes in the monoclinic C2/c space group. The structure consists of four 02329_fluka molecules inside a Na2CdC6N7H14O10 framework. In the Na2CdC6N7H14O10 framework, Na(1) is bonded to one N(4), one O(4), two equivalent O(3), and two equivalent O(5) atoms to form a mixture of distorted edge and corner-sharing NaNO5 octahedra. The corner-sharing octahedral tilt angles are 54°. The Na(1)-N(4) bond length is 2.64 Å. The Na(1)-O(4) bond length is 2.41 Å. There is one shorter (2.40 Å) and one longer (2.46 Å) Na(1)-O(3) bond length. There is one shorter (2.30 Å) and one longer (2.42 Å) Na(1)-O(5) bond length. Cd(1) is bonded to one N(1), four equivalent N(2), and two equivalent O(1) atoms to form edge-sharing CdN5O2 pentagonal bipyramids. The Cd(1)-N(1) bond length is 2.35 Å. There are two shorter (2.35 Å) and two longer (2.40 Å) Cd(1)-N(2) bond lengths. Both Cd(1)-O(1) bond lengths are 2.51 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(1) bond length is 1.34 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(7) atom. The C(3)-H(7) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1) and two equivalent C(2) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to two equivalent Cd(1) and one N(3) atom. The N(2)-N(3) bond length is 1.20 Å. In the third N site, N(3) is bonded in a linear geometry to one N(2) and one N(4) atom. The N(3)-N(4) bond length is 1.17 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one Na(1) and one N(3) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. The H(1)-O(3) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. The H(2)-O(3) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. The H(3)-O(4) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(4) atom. The H(4)-O(4) bond length is 0.98 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(5) atom. The H(5)-O(5) bond length is 0.99 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(5) atom. The H(6)-O(5) bond length is 0.99 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to two equivalent Na(1), one H(1), and one H(2) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Na(1), one H(3), and one H(4) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to two equivalent Na(1), one H(5), and one H(6) atom. Linkers: 8 O ,2 [O]C(=O)c1cccc(C([O])=O)n1 ,4 [N][N][N]. Metal clusters: 4 [Na] ,2 [Cd]. The MOF has largest included sphere 1.50 A, density 2.01 g/cm3, surface area 2982.59 m2/g, accessible volume 0.07 cm3/g