CuC4NH2O4CH(CH3)2C8NH5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, four 02329_fluka molecules, one C8NH5 cluster, and one CuC4NH2O4 cluster. In the C8NH5 cluster, there are eight inequivalent C sites. In the first C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one N(2) atom. The C(2)-C(3) bond length is 1.43 Å. The C(2)-C(7) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.39 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(12), one C(2), and one C(3) atom. The C(3)-C(12) bond length is 1.42 Å. The C(3)-C(3) bond length is 1.43 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(13), one C(5), and one C(9) atom. The C(4)-C(13) bond length is 1.40 Å. The C(4)-C(5) bond length is 1.46 Å. The C(4)-C(9) bond length is 1.41 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(1) atom. The C(5)-N(2) bond length is 1.28 Å. The C(5)-H(1) bond length is 1.11 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(7)-H(2) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(9)-H(4) bond length is 1.09 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(3) and one H(7) atom. The C(12)-H(7) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(4) and one H(8) atom. The C(13)-H(8) bond length is 1.09 Å. N(2) is bonded in a bent 120 degrees geometry to one C(2) and one C(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the CuC4NH2O4 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-N(1) bond length is 2.20 Å. The Cu(1)-O(1) bond length is 2.01 Å. The Cu(1)-O(2) bond length is 2.00 Å. The Cu(1)-O(3) bond length is 2.00 Å. The Cu(1)-O(4) bond length is 2.01 Å. There are four inequivalent C sites. In the first C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(6)-O(1) bond length is 1.27 Å. The C(6)-O(4) bond length is 1.27 Å. In the second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(8)-N(1) bond length is 1.35 Å. The C(8)-H(3) bond length is 1.09 Å. In the third C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(10)-N(1) bond length is 1.34 Å. The C(10)-H(5) bond length is 1.09 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(1)-O(2) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.28 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(8) atom. There are two inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(6) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(6) atom. Linkers: 2 [c]1cc(/C=N/c2cccc3c(/N=C/c4ccncc4)cccc23)ccn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.71 A, density 1.56 g/cm3, surface area 5111.77 m2/g, accessible volume 0.13 cm3/g