ZnC32H28(NO)4(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two ZnC32H28(NO)4 clusters. In each ZnC32H28(NO)4 cluster, Zn(1) is bonded in a 6-coordinate geometry to one N(3); one N(4); two equivalent O(1,2); and two equivalent O(3,4) atoms. The Zn(1)-N(3) bond length is 2.08 Å. The Zn(1)-N(4) bond length is 2.08 Å. Both Zn(1)-O(1,2) bond lengths are 2.11 Å. Both Zn(1)-O(3,4) bond lengths are 2.43 Å. There are twenty-six inequivalent C sites. In the first C site, C(34) is bonded in a distorted trigonal planar geometry to one C(23,24); one C(31,32); and one H(31,32) atom. The C(34)-C(23,24) bond length is 1.40 Å. The C(34)-C(31,32) bond length is 1.39 Å. The C(34)-H(31,32) bond length is 1.09 Å. In the second C site, C(33) is bonded in a distorted trigonal planar geometry to one C(23,24); one C(31,32); and one H(31,32) atom. The C(33)-C(23,24) bond length is 1.40 Å. The C(33)-C(31,32) bond length is 1.39 Å. The C(33)-H(31,32) bond length is 1.09 Å. In the third C site, C(1,2) is bonded in a distorted trigonal non-coplanar geometry to one C(3,4); one H(1,2); one H(3,4); and one H(5,6) atom. The C(1,2)-C(3,4) bond length is 1.48 Å. The C(1,2)-H(1,2) bond length is 1.09 Å. The C(1,2)-H(3,4) bond length is 1.10 Å. The C(1,2)-H(5,6) bond length is 1.10 Å. In the fourth C site, C(3,4) is bonded in a distorted trigonal planar geometry to one C(1,2); one N(1); and one N(3) atom. The C(3,4)-N(1) bond length is 1.37 Å. The C(3,4)-N(3) bond length is 1.34 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one N(1) atom. The C(5)-C(7) bond length is 1.42 Å. The C(5)-C(9) bond length is 1.40 Å. The C(5)-N(1) bond length is 1.39 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one N(2) atom. The C(6)-C(10) bond length is 1.40 Å. The C(6)-C(8) bond length is 1.42 Å. The C(6)-N(2) bond length is 1.39 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(11), one C(5), and one N(3) atom. The C(7)-C(11) bond length is 1.40 Å. The C(7)-N(3) bond length is 1.39 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(12), one C(6), and one N(4) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-N(4) bond length is 1.39 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(13); one C(5); and one H(7,8) atom. The C(9)-C(13) bond length is 1.39 Å. The C(9)-H(7,8) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(14); one C(6); and one H(7,8) atom. The C(10)-C(14) bond length is 1.39 Å. The C(10)-H(7,8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(15); one C(7); and one H(9,10) atom. The C(11)-C(15) bond length is 1.39 Å. The C(11)-H(9,10) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(16); one C(8); and one H(9,10) atom. The C(12)-C(16) bond length is 1.39 Å. The C(12)-H(9,10) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(15), one C(9), and one H(11) atom. The C(13)-C(15) bond length is 1.41 Å. The C(13)-H(11) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(10), one C(16), and one H(12) atom. The C(14)-C(16) bond length is 1.41 Å. The C(14)-H(12) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(13) atom. The C(15)-H(13) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(14) atom. The C(16)-H(14) bond length is 1.09 Å. In the seventeenth C site, C(17,18) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent H(15,16,17,18) atoms. The C(17,18)-N(1) bond length is 1.46 Å. Both C(17,18)-H(15,16,17,18) bond lengths are 1.10 Å. In the eighteenth C site, C(21) is bonded in a bent 120 degrees geometry to one C(23,24); one O(1,2); and one O(3,4) atom. The C(21)-C(23,24) bond length is 1.50 Å. The C(21)-O(1,2) bond length is 1.29 Å. The C(21)-O(3,4) bond length is 1.26 Å. In the nineteenth C site, C(22) is bonded in a bent 120 degrees geometry to one C(23,24); one O(1,2); and one O(3,4) atom. The C(22)-C(23,24) bond length is 1.50 Å. The C(22)-O(1,2) bond length is 1.29 Å. The C(22)-O(3,4) bond length is 1.26 Å. In the twentieth C site, C(23,24) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(33) atom. The C(23,24)-C(25) bond length is 1.40 Å. In the twenty-first C site, C(25) is bonded in a distorted trigonal planar geometry to one C(23,24); one C(27,28); and one H(23,24) atom. The C(25)-C(27,28) bond length is 1.40 Å. The C(25)-H(23,24) bond length is 1.09 Å. In the twenty-second C site, C(26) is bonded in a distorted trigonal planar geometry to one C(23,24); one C(27,28); and one H(23,24) atom. The C(26)-C(23,24) bond length is 1.40 Å. The C(26)-C(27,28) bond length is 1.40 Å. The C(26)-H(23,24) bond length is 1.09 Å. In the twenty-third C site, C(27,28) is bonded in a distorted trigonal planar geometry to one C(25), one C(29), and one H(25) atom. The C(27,28)-C(29) bond length is 1.40 Å. The C(27,28)-H(25) bond length is 1.09 Å. In the twenty-fourth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(27,28); one C(31,32); and one H(27,28) atom. The C(29)-C(31,32) bond length is 1.40 Å. The C(29)-H(27,28) bond length is 1.09 Å. In the twenty-fifth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(27,28); one C(31,32); and one H(27,28) atom. The C(30)-C(27,28) bond length is 1.40 Å. The C(30)-C(31,32) bond length is 1.40 Å. The C(30)-H(27,28) bond length is 1.09 Å. In the twenty-sixth C site, C(31,32) is bonded in a distorted single-bond geometry to one C(29), one C(33), and one H(29) atom. The C(31,32)-H(29) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(17,18); one C(3,4); and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(17,18); one C(3,4); and one C(6) atom. The N(2)-C(17,18) bond length is 1.46 Å. The N(2)-C(3,4) bond length is 1.37 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1); one C(3,4); and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1); one C(3,4); and one C(8) atom. The N(4)-C(3,4) bond length is 1.34 Å. There are seventeen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(1,2) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(1,2) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(15,16,17,18) is bonded in a single-bond geometry to one C(17,18) atom. In the eleventh H site, H(23,24) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(25) is bonded in a single-bond geometry to one C(27,28) atom. In the thirteenth H site, H(26) is bonded in a single-bond geometry to one C(27,28) atom. The H(26)-C(27,28) bond length is 1.09 Å. In the fourteenth H site, H(27,28) is bonded in a single-bond geometry to one C(29) atom. In the fifteenth H site, H(29) is bonded in a single-bond geometry to one C(31,32) atom. In the sixteenth H site, H(30) is bonded in a single-bond geometry to one C(31,32) atom. The H(30)-C(31,32) bond length is 1.09 Å. In the seventeenth H site, H(31,32) is bonded in a single-bond geometry to one C(33) atom. There are two inequivalent O sites. In the first O site, O(1,2) is bonded in a distorted L-shaped geometry to one Zn(1) and one C(21) atom. In the second O site, O(3,4) is bonded in a distorted single-bond geometry to one Zn(1) and one C(21) atom. Linkers: 2 Cc1nc2ccccc2n1CCCCn1c(C)nc2ccccc21. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.64 A, density 1.37 g/cm3, surface area 5251.05 m2/g, accessible volume 0.18 cm3/g