MnCuC14H16(NO4)2 crystallizes in the triclinic P1 space group. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in an octahedral geometry to one O(1), one O(14), one O(18), one O(25), one O(29), and one O(5) atom. The Mn(1)-O(1) bond length is 2.06 Å. The Mn(1)-O(14) bond length is 2.08 Å. The Mn(1)-O(18) bond length is 2.23 Å. The Mn(1)-O(25) bond length is 2.16 Å. The Mn(1)-O(29) bond length is 2.19 Å. The Mn(1)-O(5) bond length is 2.12 Å. In the second Mn site, Mn(2) is bonded in an octahedral geometry to one O(13), one O(17), one O(2), one O(26), one O(30), and one O(6) atom. The Mn(2)-O(13) bond length is 2.08 Å. The Mn(2)-O(17) bond length is 2.23 Å. The Mn(2)-O(2) bond length is 2.06 Å. The Mn(2)-O(26) bond length is 2.16 Å. The Mn(2)-O(30) bond length is 2.19 Å. The Mn(2)-O(6) bond length is 2.12 Å. In the third Mn site, Mn(3) is bonded in an octahedral geometry to one O(16), one O(20), one O(27), one O(3), one O(31), and one O(7) atom. The Mn(3)-O(16) bond length is 2.08 Å. The Mn(3)-O(20) bond length is 2.23 Å. The Mn(3)-O(27) bond length is 2.17 Å. The Mn(3)-O(3) bond length is 2.06 Å. The Mn(3)-O(31) bond length is 2.19 Å. The Mn(3)-O(7) bond length is 2.12 Å. In the fourth Mn site, Mn(4) is bonded in an octahedral geometry to one O(15), one O(19), one O(28), one O(32), one O(4), and one O(8) atom. The Mn(4)-O(15) bond length is 2.08 Å. The Mn(4)-O(19) bond length is 2.23 Å. The Mn(4)-O(28) bond length is 2.16 Å. The Mn(4)-O(32) bond length is 2.19 Å. The Mn(4)-O(4) bond length is 2.06 Å. The Mn(4)-O(8) bond length is 2.11 Å. There are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to one N(1), one N(7), one O(23), and one O(9) atom. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-N(7) bond length is 1.98 Å. The Cu(1)-O(23) bond length is 2.07 Å. The Cu(1)-O(9) bond length is 2.08 Å. In the second Cu site, Cu(2) is bonded in a square co-planar geometry to one N(2), one N(8), one O(10), and one O(24) atom. The Cu(2)-N(2) bond length is 1.98 Å. The Cu(2)-N(8) bond length is 1.98 Å. The Cu(2)-O(10) bond length is 2.08 Å. The Cu(2)-O(24) bond length is 2.07 Å. In the third Cu site, Cu(3) is bonded in a square co-planar geometry to one N(3), one N(5), one O(11), and one O(21) atom. The Cu(3)-N(3) bond length is 1.98 Å. The Cu(3)-N(5) bond length is 1.98 Å. The Cu(3)-O(11) bond length is 2.08 Å. The Cu(3)-O(21) bond length is 2.07 Å. In the fourth Cu site, Cu(4) is bonded in a square co-planar geometry to one N(4), one N(6), one O(12), and one O(22) atom. The Cu(4)-N(4) bond length is 1.98 Å. The Cu(4)-N(6) bond length is 1.99 Å. The Cu(4)-O(12) bond length is 2.08 Å. The Cu(4)-O(22) bond length is 2.07 Å. There are thirty-four inequivalent C sites. In the first C site, C(1,4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(1) atom. The C(1,4)-N(1) bond length is 1.31 Å. The C(1,4)-O(1) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(2) atom. The C(2)-N(2) bond length is 1.31 Å. The C(2)-O(2) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(3) and one O(3) atom. The C(3)-N(3) bond length is 1.32 Å. The C(3)-O(3) bond length is 1.28 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(9) atom. The C(5)-O(5) bond length is 1.26 Å. The C(5)-O(9) bond length is 1.27 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(6) atom. The C(6)-O(10) bond length is 1.27 Å. The C(6)-O(6) bond length is 1.26 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(7) atom. The C(7)-O(11) bond length is 1.28 Å. The C(7)-O(7) bond length is 1.26 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(12) and one O(8) atom. The C(8)-O(12) bond length is 1.27 Å. The C(8)-O(8) bond length is 1.26 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(5) and one O(13) atom. The C(9)-N(5) bond length is 1.32 Å. The C(9)-O(13) bond length is 1.28 Å. In the ninth C site, C(10,11) is bonded in a distorted bent 120 degrees geometry to one N(6) and one O(14) atom. The C(10,11)-N(6) bond length is 1.32 Å. The C(10,11)-O(14) bond length is 1.28 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(8) and one O(16) atom. The C(12)-N(8) bond length is 1.32 Å. The C(12)-O(16) bond length is 1.28 Å. In the eleventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(17) and one O(21) atom. The C(13)-O(17) bond length is 1.26 Å. The C(13)-O(21) bond length is 1.28 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(18) and one O(22) atom. The C(14)-O(18) bond length is 1.26 Å. The C(14)-O(22) bond length is 1.28 Å. In the thirteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(19) and one O(23) atom. The C(15)-O(19) bond length is 1.26 Å. The C(15)-O(23) bond length is 1.28 Å. In the fourteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one O(20) and one O(24) atom. The C(16)-O(20) bond length is 1.26 Å. The C(16)-O(24) bond length is 1.28 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(21,22,24); one C(37,40); and one N(1) atom. The C(17)-C(21,22,24) bond length is 1.41 Å. The C(17)-C(37,40) bond length is 1.41 Å. The C(17)-N(1) bond length is 1.42 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(21,22,24); one C(38,39); and one N(2) atom. The C(18)-C(21,22,24) bond length is 1.41 Å. The C(18)-C(38,39) bond length is 1.41 Å. The C(18)-N(2) bond length is 1.42 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(23); one C(38,39); and one N(3) atom. The C(19)-C(23) bond length is 1.41 Å. The C(19)-C(38,39) bond length is 1.41 Å. The C(19)-N(3) bond length is 1.42 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(21,22,24); one C(37,40); and one N(4) atom. The C(20)-C(21,22,24) bond length is 1.41 Å. The C(20)-C(37,40) bond length is 1.41 Å. The C(20)-N(4) bond length is 1.42 Å. In the nineteenth C site, C(21,22,24) is bonded in a trigonal planar geometry to one C(17); one C(25,27,28); and one C(41,43,44) atom. The C(21,22,24)-C(25,27,28) bond length is 1.40 Å. The C(21,22,24)-C(41,43,44) bond length is 1.50 Å. In the twentieth C site, C(23) is bonded in a trigonal planar geometry to one C(19); one C(25,27,28); and one C(41,43,44) atom. The C(23)-C(25,27,28) bond length is 1.40 Å. The C(23)-C(41,43,44) bond length is 1.50 Å. In the twenty-first C site, C(25,27,28) is bonded in a trigonal planar geometry to one C(21,22,24); one C(29); and one C(45,46,47,48) atom. The C(25,27,28)-C(29) bond length is 1.41 Å. The C(25,27,28)-C(45,46,47,48) bond length is 1.51 Å. In the twenty-second C site, C(26) is bonded in a trigonal planar geometry to one C(21,22,24); one C(30,31); and one C(45,46,47,48) atom. The C(26)-C(21,22,24) bond length is 1.40 Å. The C(26)-C(30,31) bond length is 1.41 Å. The C(26)-C(45,46,47,48) bond length is 1.51 Å. In the twenty-third C site, C(29) is bonded in a distorted trigonal planar geometry to one C(25,27,28); one C(33,34,35,36); and one N(5) atom. The C(29)-C(33,34,35,36) bond length is 1.41 Å. The C(29)-N(5) bond length is 1.42 Å. In the twenty-fourth C site, C(30,31) is bonded in a distorted trigonal planar geometry to one C(26); one C(33,34,35,36); and one N(6) atom. The C(30,31)-C(33,34,35,36) bond length is 1.41 Å. The C(30,31)-N(6) bond length is 1.42 Å. In the twenty-fifth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(25,27,28); one C(33,34,35,36); and one N(8) atom. The C(32)-C(25,27,28) bond length is 1.41 Å. The C(32)-C(33,34,35,36) bond length is 1.41 Å. The C(32)-N(8) bond length is 1.42 Å. In the twenty-sixth C site, C(33,34,35,36) is bonded in a trigonal planar geometry to one C(29); one C(37,40); and one C(49,52) atom. The C(33,34,35,36)-C(37,40) bond length is 1.40 Å. The C(33,34,35,36)-C(49,52) bond length is 1.50 Å. In the twenty-seventh C site, C(37,40) is bonded in a trigonal planar geometry to one C(17); one C(33,34,35,36); and one C(53,54,55,56) atom. The C(37,40)-C(53,54,55,56) bond length is 1.51 Å. In the twenty-eighth C site, C(38,39) is bonded in a trigonal planar geometry to one C(18); one C(33,34,35,36); and one C(53,54,55,56) atom. The C(38,39)-C(33,34,35,36) bond length is 1.40 Å. The C(38,39)-C(53,54,55,56) bond length is 1.51 Å. In the twenty-ninth C site, C(41,43,44) is bonded in a distorted trigonal non-coplanar geometry to one C(21,22,24); one H(1,2,3,4); one H(5,6,7,8); and one H(9,10,12) atom. The C(41,43,44)-H(1,2,3,4) bond length is 1.09 Å. The C(41,43,44)-H(5,6,7,8) bond length is 1.10 Å. The C(41,43,44)-H(9,10,12) bond length is 1.10 Å. In the thirtieth C site, C(42) is bonded in a distorted trigonal non-coplanar geometry to one C(21,22,24); one H(1,2,3,4); one H(5,6,7,8); and one H(9,10,12) atom. The C(42)-C(21,22,24) bond length is 1.50 Å. The C(42)-H(1,2,3,4) bond length is 1.09 Å. The C(42)-H(5,6,7,8) bond length is 1.10 Å. The C(42)-H(9,10,12) bond length is 1.10 Å. In the thirty-first C site, C(45,46,47,48) is bonded in a distorted trigonal non-coplanar geometry to one C(25,27,28); one H(13,14,15,16); and two equivalent H(17,18,19,20,21,22,23,24) atoms. The C(45,46,47,48)-H(13,14,15,16) bond length is 1.10 Å. Both C(45,46,47,48)-H(17,18,19,20,21,22,23,24) bond lengths are 1.10 Å. In the thirty-second C site, C(49,52) is bonded in a distorted trigonal non-coplanar geometry to one C(33,34,35,36); one H(25,26,27,28); one H(29,30,31,32); and one H(33,34,35,36) atom. The C(49,52)-H(25,26,27,28) bond length is 1.10 Å. The C(49,52)-H(29,30,31,32) bond length is 1.09 Å. The C(49,52)-H(33,34,35,36) bond length is 1.10 Å. In the thirty-third C site, C(50,51) is bonded in a distorted trigonal non-coplanar geometry to one C(33,34,35,36); one H(25,26,27,28); one H(29,30,31,32); and one H(33,34,35,36) atom. The C(50,51)-C(33,34,35,36) bond length is 1.50 Å. The C(50,51)-H(25,26,27,28) bond length is 1.10 Å. The C(50,51)-H(29,30,31,32) bond length is 1.09 Å. The C(50,51)-H(33,34,35,36) bond length is 1.10 Å. In the thirty-fourth C site, C(53,54,55,56) is bonded in a distorted trigonal non-coplanar geometry to one C(37,40); one H(37,38,39,40); one H(41,42,43,44); and one H(45,46,47,48) atom. The C(53,54,55,56)-H(37,38,39,40) bond length is 1.10 Å. The C(53,54,55,56)-H(41,42,43,44) bond length is 1.09 Å. The C(53,54,55,56)-H(45,46,47,48) bond length is 1.10 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1); one C(1,4); and one C(17) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(18), and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(3), one C(19), and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(4); one C(1,4); and one C(20) atom. The N(4)-C(1,4) bond length is 1.31 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(3), one C(29), and one C(9) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(4); one C(10,11); and one C(30,31) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Cu(1); one C(10,11); and one C(30,31) atom. The N(7)-C(10,11) bond length is 1.32 Å. The N(7)-C(30,31) bond length is 1.42 Å. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Cu(2), one C(12), and one C(32) atom. There are twenty-six inequivalent H sites. In the first H site, H(1,2,3,4) is bonded in a single-bond geometry to one C(41,43,44) atom. In the second H site, H(5,6,7,8) is bonded in a single-bond geometry to one C(41,43,44) atom. In the third H site, H(9,10,12) is bonded in a single-bond geometry to one C(41,43,44) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(41,43,44) atom. The H(11)-C(41,43,44) bond length is 1.10 Å. In the fifth H site, H(13,14,15,16) is bonded in a single-bond geometry to one C(45,46,47,48) atom. In the sixth H site, H(17,18,19,20,21,22,23,24) is bonded in a single-bond geometry to one C(45,46,47,48) atom. In the seventh H site, H(25,26,27,28) is bonded in a single-bond geometry to one C(49,52) atom. In the eighth H site, H(29,30,31,32) is bonded in a single-bond geometry to one C(49,52) atom. In the ninth H site, H(33,34,35,36) is bonded in a single-bond geometry to one C(49,52) atom. In the tenth H site, H(37,38,39,40) is bonded in a single-bond geometry to one C(53,54,55,56) atom. In the eleventh H site, H(41,42,43,44) is bonded in a single-bond geometry to one C(53,54,55,56) atom. In the twelfth H site, H(45,46,47,48) is bonded in a single-bond geometry to one C(53,54,55,56) atom. In the thirteenth H site, H(49) is bonded in a linear geometry to one O(21) and one O(25) atom. The H(49)-O(21) bond length is 1.64 Å. The H(49)-O(25) bond length is 1.00 Å. In the fourteenth H site, H(50) is bonded in a linear geometry to one O(22) and one O(26) atom. The H(50)-O(22) bond length is 1.64 Å. The H(50)-O(26) bond length is 1.00 Å. In the fifteenth H site, H(51) is bonded in a linear geometry to one O(23) and one O(27) atom. The H(51)-O(23) bond length is 1.64 Å. The H(51)-O(27) bond length is 1.00 Å. In the sixteenth H site, H(52) is bonded in a linear geometry to one O(24) and one O(28) atom. The H(52)-O(24) bond length is 1.64 Å. The H(52)-O(28) bond length is 1.00 Å. In the seventeenth H site, H(53) is bonded in a distorted linear geometry to one O(11) and one O(29) atom. The H(53)-O(11) bond length is 1.67 Å. The H(53)-O(29) bond length is 1.00 Å. In the eighteenth H site, H(54) is bonded in a distorted linear geometry to one O(12) and one O(30) atom. The H(54)-O(12) bond length is 1.67 Å. The H(54)-O(30) bond length is 1.00 Å. In the nineteenth H site, H(55) is bonded in a distorted linear geometry to one O(31) and one O(9) atom. The H(55)-O(31) bond length is 1.00 Å. The H(55)-O(9) bond length is 1.67 Å. In the twentieth H site, H(56) is bonded in a distorted linear geometry to one O(10) and one O(32) atom. The H(56)-O(10) bond length is 1.67 Å. The H(56)-O(32) bond length is 1.00 Å. In the twenty-first H site, H(57,58,60) is bonded in a single-bond geometry to one O(25) atom. The H(57,58,60)-O(25) bond length is 0.97 Å. In the twenty-second H site, H(59) is bonded in a single-bond geometry to one O(27) atom. The H(59)-O(27) bond length is 0.97 Å. In the twenty-third H site, H(61) is bonded in a single-bond geometry to one O(29) atom. The H(61)-O(29) bond length is 0.97 Å. In the twenty-fourth H site, H(62) is bonded in a single-bond geometry to one O(30) atom. The H(62)-O(30) bond length is 0.97 Å. In the twenty-fifth H site, H(63) is bonded in a single-bond geometry to one O(31) atom. The H(63)-O(31) bond length is 0.97 Å. In the twenty-sixth H site, H(64) is bonded in a single-bond geometry to one O(32) atom. The H(64)-O(32) bond length is 0.97 Å. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1,4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(4) and one C(1,4) atom. The O(4)-C(1,4) bond length is 1.28 Å. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Mn(1) and one C(5) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Mn(2) and one C(6) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Mn(3) and one C(7) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mn(4) and one C(8) atom. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Cu(1), one C(5), and one H(55) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Cu(2), one C(6), and one H(56) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Cu(3), one C(7), and one H(53) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Cu(4), one C(8), and one H(54) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(9) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(10,11) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Mn(4) and one C(10,11) atom. The O(15)-C(10,11) bond length is 1.28 Å. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(12) atom. In the seventeenth O site, O(17) is bonded in a water-like geometry to one Mn(2) and one C(13) atom. In the eighteenth O site, O(18) is bonded in a water-like geometry to one Mn(1) and one C(14) atom. In the nineteenth O site, O(19) is bonded in a water-like geometry to one Mn(4) and one C(15) atom. In the twentieth O site, O(20) is bonded in a water-like geometry to one Mn(3) and one C(16) atom. In the twenty-first O site, O(21) is bonded in a trigonal non-coplanar geometry to one Cu(3), one C(13), and one H(49) atom. In the twenty-second O site, O(22) is bonded in a trigonal non-coplanar geometry to one Cu(4), one C(14), and one H(50) atom. In the twenty-third O site, O(23) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(15), and one H(51) atom. In the twenty-fourth O site, O(24) is bonded in a trigonal non-coplanar geometry to one Cu(2), one C(16), and one H(52) atom. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1); one H(49); and one H(57,58,60) atom. In the twenty-sixth O site, O(26) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2); one H(50); and one H(57,58,60) atom. The O(26)-H(57,58,60) bond length is 0.97 Å. In the twenty-seventh O site, O(27) is bonded in a distorted trigonal non-coplanar geometry to one Mn(3), one H(51), and one H(59) atom. In the twenty-eighth O site, O(28) is bonded in a distorted trigonal non-coplanar geometry to one Mn(4); one H(52); and one H(57,58,60) atom. The O(28)-H(57,58,60) bond length is 0.97 Å. In the twenty-ninth O site, O(29) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one H(53), and one H(61) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one H(54), and one H(62) atom. In the thirty-first O site, O(31) is bonded in a distorted trigonal non-coplanar geometry to one Mn(3), one H(55), and one H(63) atom. In the thirty-second O site, O(32) is bonded in a distorted trigonal non-coplanar geometry to one Mn(4), one H(56), and one H(64) atom. Linkers: 4 Cc1c(C)c([N]C(=O)C([O])=O)c(C)c(C)c1[N]C(=O)C([O])=O. Metal clusters: 4 [Mn] ,4 [Cu]. The MOF has largest included sphere 3.64 A, density 1.49 g/cm3, surface area 3846.91 m2/g, accessible volume 0.19 cm3/g