UC12NH12O7(CH)3C2O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two dimethyl ether molecules, and one UC12NH12O7 cluster. In the UC12NH12O7 cluster, U(1) is bonded in a distorted pentagonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. The U(1)-O(1) bond length is 2.40 Å. The U(1)-O(2) bond length is 2.32 Å. The U(1)-O(3) bond length is 2.45 Å. The U(1)-O(4) bond length is 1.81 Å. The U(1)-O(5) bond length is 2.44 Å. The U(1)-O(6) bond length is 2.32 Å. The U(1)-O(8) bond length is 1.82 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one H(1), and one O(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-O(1) bond length is 1.27 Å. In the second C site, C(2) is bonded to one N(1), one H(2), one H(3), and one H(4) atom to form corner-sharing CH3N tetrahedra. The C(2)-N(1) bond length is 1.46 Å. The C(2)-H(2) bond length is 1.10 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.09 Å. In the third C site, C(3) is bonded to one N(1), one H(5), one H(6), and one H(7) atom to form corner-sharing CH3N tetrahedra. The C(3)-N(1) bond length is 1.46 Å. The C(3)-H(5) bond length is 1.09 Å. The C(3)-H(6) bond length is 1.09 Å. The C(3)-H(7) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(2), and one O(6) atom. The C(4)-C(5) bond length is 1.48 Å. The C(4)-O(2) bond length is 1.27 Å. The C(4)-O(6) bond length is 1.28 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(17), one C(4), and one C(6) atom. The C(5)-C(17) bond length is 1.40 Å. The C(5)-C(6) bond length is 1.41 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(8) atom. The C(6)-H(8) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(10) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(10) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(11) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(11) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(15) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(15) bond length is 1.47 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(12) atom. The C(13)-H(12) bond length is 1.09 Å. In the eleventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(3), and one O(5) atom. The C(15)-O(3) bond length is 1.29 Å. The C(15)-O(5) bond length is 1.29 Å. In the twelfth C site, C(17) is bonded in a distorted single-bond geometry to one C(5) and one H(15) atom. The C(17)-H(15) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one U(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one U(1) and one C(4) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one U(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one U(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one U(1) and one C(15) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one U(1) and one C(4) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one U(1) atom. Linkers: 2 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 [U]. The MOF has largest included sphere 2.47 A, density 2.18 g/cm3, surface area 3349.52 m2/g, accessible volume 0.15 cm3/g