ZnC10N2H10O5(CH3)2 crystallizes in the hexagonal P6_1 space group. The structure consists of twelve 02329_fluka molecules inside a ZnC10N2H10O5 framework. In the ZnC10N2H10O5 framework, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(2), and one O(4) atom. The Zn(1)-N(1) bond length is 2.08 Å. The Zn(1)-N(2) bond length is 2.11 Å. The Zn(1)-O(1) bond length is 2.16 Å. The Zn(1)-O(2) bond length is 2.13 Å. The Zn(1)-O(4) bond length is 1.97 Å. There are ten inequivalent C sites. In the first C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one N(2), one H(7), and one H(8) atom. The C(6)-C(3) bond length is 1.50 Å. The C(6)-N(2) bond length is 1.49 Å. The C(6)-H(7) bond length is 1.10 Å. The C(6)-H(8) bond length is 1.10 Å. In the second C site, C(7) is bonded in a 2-coordinate geometry to one N(2) and one H(9) atom. The C(7)-N(2) bond length is 1.47 Å. The C(7)-H(9) bond length is 1.10 Å. In the third C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(8)-O(1) bond length is 1.27 Å. The C(8)-O(2) bond length is 1.27 Å. In the fourth C site, C(9) is bonded in a distorted water-like geometry to one H(10) and one O(3) atom. The C(9)-H(10) bond length is 1.10 Å. The C(9)-O(3) bond length is 1.42 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(11)-O(4) bond length is 1.30 Å. The C(11)-O(5) bond length is 1.26 Å. In the sixth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(3) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(3) bond length is 1.09 Å. In the seventh C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(4) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(4) bond length is 1.09 Å. In the eighth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. In the ninth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(5) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(5) bond length is 1.09 Å. In the tenth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(6) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(6) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted tetrahedral geometry to one Zn(1), one C(6), one C(7), and one H(2) atom. The N(2)-H(2) bond length is 1.03 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(3) and one O(5) atom. The H(1)-O(3) bond length is 1.01 Å. The H(1)-O(5) bond length is 1.61 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(9) and one H(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(11) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(11) and one H(1) atom. Linkers: 6 C[C@@H](O)[C@H](NCc1ccncc1)C([O])=O. Metal clusters: 6 [Zn]. The MOF has largest included sphere 7.69 A, density 1.21 g/cm3, surface area 4574.79 m2/g, accessible volume 0.38 cm3/g