(CH)10CuC16P2H14(OCl)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of forty 02329_fluka molecules and four CuC16P2H14(OCl)2 clusters. In each CuC16P2H14(OCl)2 cluster, Cu(1) is bonded in a distorted see-saw-like geometry to two equivalent O(1) and two equivalent Cl(1) atoms. Both Cu(1)-O(1) bond lengths are 1.98 Å. Both Cu(1)-Cl(1) bond lengths are 2.20 Å. There are eight inequivalent C sites. In the first C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(10) atom. The C(7)-C(2) bond length is 1.40 Å. The C(7)-H(10) bond length is 1.09 Å. In the second C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(9), and one P(1) atom. The C(8)-C(13) bond length is 1.41 Å. The C(8)-C(9) bond length is 1.40 Å. The C(8)-P(1) bond length is 1.80 Å. In the third C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(11) atom. The C(9)-H(11) bond length is 1.09 Å. In the fourth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(4) atom. The C(13)-H(4) bond length is 1.09 Å. In the fifth C site, C(1) is bonded in a distorted water-like geometry to one P(1), one H(1), and one H(5) atom. The C(1)-P(1) bond length is 1.81 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(5) bond length is 1.10 Å. In the sixth C site, C(2) is bonded in a trigonal planar geometry to one C(3), one C(7), and one P(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-P(1) bond length is 1.80 Å. In the seventh C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(6) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(6) bond length is 1.09 Å. In the eighth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(7) atom. The C(4)-H(7) bond length is 1.09 Å. P(1) is bonded in a tetrahedral geometry to one C(1), one C(2), one C(8), and one O(1) atom. The P(1)-O(1) bond length is 1.52 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(9) atom. O(1) is bonded in a bent 150 degrees geometry to one Cu(1) and one P(1) atom. Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 2 O=P(CCP(=O)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 3.07 A, density 1.49 g/cm3, surface area 4989.13 m2/g, accessible volume 0.14 cm3/g