CuC8N4H10I(CH2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two CuC8N4H10I clusters. In each CuC8N4H10I cluster, Cu(1) is bonded in a distorted bent 120 degrees geometry to one N(1), one N(3), and two equivalent I(1) atoms. The Cu(1)-N(1) bond length is 2.01 Å. The Cu(1)-N(3) bond length is 2.02 Å. There is one shorter (2.70 Å) and one longer (2.71 Å) Cu(1)-I(1) bond length. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(1), and one H(2) atom. The C(1)-N(4) bond length is 1.46 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(4), and one H(3) atom. The C(2)-C(10) bond length is 1.39 Å. The C(2)-N(4) bond length is 1.36 Å. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(4) atom. The C(3)-N(3) bond length is 1.35 Å. The C(3)-H(4) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(1), and one H(5) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(5) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(6) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(6) bond length is 1.08 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(2), and one H(7) atom. The C(6)-N(2) bond length is 1.36 Å. The C(6)-H(7) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(8), and one H(9) atom. The C(7)-N(2) bond length is 1.45 Å. The C(7)-H(8) bond length is 1.10 Å. The C(7)-H(9) bond length is 1.10 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(2) and one H(14) atom. The C(10)-H(14) bond length is 1.08 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(4), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one N(1) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(3), and one N(4) atom. The N(3)-N(4) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(1), one C(2), and one N(3) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 2 [c]1cnn(CCCCn2cccn2)c1 ,4 c1cnn(CCCCn2cccn2)c1. Metal clusters: 2 I[Cu][Cu]I. The MOF has largest included sphere 1.89 A, density 2.05 g/cm3, surface area 3971.65 m2/g, accessible volume 0.10 cm3/g