AgC6H14(NO)3 is Indium-like structured and crystallizes in the tetragonal P4_3 space group. The structure is zero-dimensional and consists of four AgC6H14(NO)3 clusters. Ag(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one O(1), one O(2), and one O(3) atom. The Ag(1)-N(1) bond length is 2.35 Å. The Ag(1)-N(2) bond length is 2.33 Å. The Ag(1)-O(1) bond length is 2.55 Å. The Ag(1)-O(2) bond length is 2.66 Å. The Ag(1)-O(3) bond length is 2.52 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(1)-N(1) bond length is 1.48 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(3), and one H(4) atom. The C(2)-N(2) bond length is 1.49 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(5), and one H(6) atom. The C(3)-N(1) bond length is 1.49 Å. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(6) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2); one H(7); and one H(8,10) atom. The C(4)-N(2) bond length is 1.48 Å. The C(4)-H(7) bond length is 1.10 Å. The C(4)-H(8,10) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(1); one H(8,10); and one H(9) atom. The C(5)-N(1) bond length is 1.48 Å. The C(5)-H(8,10) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(11), and one H(12) atom. The C(6)-N(2) bond length is 1.48 Å. The C(6)-H(11) bond length is 1.09 Å. The C(6)-H(12) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded to one Ag(1), one C(1), one C(3), and one C(5) atom to form corner-sharing NAgC3 tetrahedra. In the second N site, N(2) is bonded to one Ag(1), one C(2), one C(4), and one C(6) atom to form corner-sharing NAgC3 tetrahedra. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. The N(3)-O(1) bond length is 1.27 Å. The N(3)-O(2) bond length is 1.27 Å. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8,10) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one O(3) atom. The H(13)-O(3) bond length is 0.99 Å. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one O(3) atom. The H(14)-O(3) bond length is 0.99 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one N(3) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one N(3) atom. In the third O site, O(3) is bonded in a water-like geometry to one Ag(1), one H(13), and one H(14) atom. Linkers: 4 C1CN2CCN1CC2. Metal clusters: 4 O.[O][N]O[Ag]. The MOF has largest included sphere 1.94 A, density 1.99 g/cm3, surface area 3793.95 m2/g, accessible volume 0.08 cm3/g