AgC13PNH10O2(CH)6CF3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules, four trifluoromethane molecules, and two AgC13PNH10O2 clusters. In each AgC13PNH10O2 cluster, Ag(1) is bonded in a 3-coordinate geometry to one P(1), one N(1), and one O(1) atom. The Ag(1)-P(1) bond length is 2.35 Å. The Ag(1)-N(1) bond length is 2.23 Å. The Ag(1)-O(1) bond length is 2.42 Å. There are thirteen inequivalent C sites. In the first C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(16) atom. The C(18)-C(13) bond length is 1.41 Å. The C(18)-H(16) bond length is 1.09 Å. In the second C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(19)-O(1) bond length is 1.27 Å. The C(19)-O(2) bond length is 1.25 Å. In the third C site, C(1) is bonded in a distorted water-like geometry to one C(2), one P(1), one H(1), and one H(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-P(1) bond length is 1.86 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the fourth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.40 Å. In the fifth C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.09 Å. In the sixth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(4) atom. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(4) bond length is 1.09 Å. In the seventh C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(5) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(5) bond length is 1.09 Å. In the eighth C site, C(6) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(6) atom. The C(6)-H(6) bond length is 1.09 Å. In the ninth C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(8), and one P(1) atom. The C(7)-C(12) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.40 Å. The C(7)-P(1) bond length is 1.82 Å. In the tenth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(8)-H(7) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(11) atom. The C(12)-H(11) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(18), and one P(1) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-P(1) bond length is 1.83 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(12) atom. The C(14)-H(12) bond length is 1.09 Å. P(1) is bonded in a tetrahedral geometry to one Ag(1), one C(1), one C(13), and one C(7) atom. N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(4), and one C(5) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Ag(1) and one C(19) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(19) atom. Linkers: 4 c1ccc(P(Cc2ccncc2)c2ccccc2)cc1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 3.77 A, density 1.57 g/cm3, surface area 4333.64 m2/g, accessible volume 0.18 cm3/g