CoC20H14(NO)4(CH)4CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two 02329_fluka molecules, and one CoC20H14(NO)4 cluster. In the CoC20H14(NO)4 cluster, Co(1) is bonded in a tetrahedral geometry to one N(1), one N(4), one O(1), and one O(3) atom. The Co(1)-N(1) bond length is 1.98 Å. The Co(1)-N(4) bond length is 2.01 Å. The Co(1)-O(1) bond length is 1.94 Å. The Co(1)-O(3) bond length is 1.93 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1) atom. The C(1)-N(1) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2) atom. The C(2)-N(2) bond length is 1.39 Å. In the third C site, C(7) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(5) atom. The C(7)-N(1) bond length is 1.33 Å. The C(7)-N(2) bond length is 1.36 Å. The C(7)-H(5) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(6), and one H(7) atom. The C(8)-N(2) bond length is 1.46 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-H(7) bond length is 1.10 Å. In the fifth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(10), and one H(11) atom. The C(10)-N(3) bond length is 1.46 Å. The C(10)-H(10) bond length is 1.10 Å. The C(10)-H(11) bond length is 1.10 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one N(3) atom. The C(11)-C(12) bond length is 1.42 Å. The C(11)-C(16) bond length is 1.40 Å. The C(11)-N(3) bond length is 1.39 Å. In the seventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one N(4) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-N(4) bond length is 1.39 Å. In the eighth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(12) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(12) bond length is 1.09 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(13) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-H(13) bond length is 1.09 Å. In the tenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(14) atom. The C(15)-H(14) bond length is 1.09 Å. In the eleventh C site, C(16) is bonded in a distorted single-bond geometry to one C(11) and one H(15) atom. The C(16)-H(15) bond length is 1.09 Å. In the twelfth C site, C(17) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(16) atom. The C(17)-N(3) bond length is 1.36 Å. The C(17)-N(4) bond length is 1.33 Å. The C(17)-H(16) bond length is 1.09 Å. In the thirteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(3), and one O(4) atom. The C(18)-C(19) bond length is 1.49 Å. The C(18)-O(3) bond length is 1.30 Å. The C(18)-O(4) bond length is 1.25 Å. In the fourteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(21) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-C(21) bond length is 1.40 Å. In the fifteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(17) atom. The C(20)-H(17) bond length is 1.09 Å. In the sixteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(19) and one H(18) atom. The C(21)-H(18) bond length is 1.09 Å. In the seventeenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(1), and one O(2) atom. The C(22)-C(23) bond length is 1.50 Å. The C(22)-O(1) bond length is 1.31 Å. The C(22)-O(2) bond length is 1.25 Å. In the eighteenth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(25) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(25) bond length is 1.40 Å. In the nineteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(19) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(19) bond length is 1.09 Å. In the twentieth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(23), one C(24), and one H(20) atom. The C(25)-H(20) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(7), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(17) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(12), and one C(17) atom. There are fourteen inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(22) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(22) atom. In the third O site, O(3) is bonded in a water-like geometry to one Co(1) and one C(18) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(18) atom. Linkers: 2 c1ccc2c(c1)ncn2CCCn1cnc2ccccc21 ,2 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 O=[C]O[Co]O[C]=O. The MOF has largest included sphere 5.44 A, density 1.15 g/cm3, surface area 4600.71 m2/g, accessible volume 0.33 cm3/g