MoCu3C26N6H20S4O(CH)6C6H5NH2(C3NH4)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules, eight 1-methylethenylamine molecules, four aniline molecules, and two MoCu3C26N6H20S4O clusters. In each MoCu3C26N6H20S4O cluster, Mo(1) is bonded in a distorted single-bond geometry to one S(1), one S(2), one S(3), and one O(1) atom. The Mo(1)-S(1) bond length is 2.27 Å. The Mo(1)-S(2) bond length is 2.27 Å. The Mo(1)-S(3) bond length is 2.28 Å. The Mo(1)-O(1) bond length is 1.73 Å. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 4-coordinate geometry to one N(3), one N(6), one S(1), and one S(3) atom. The Cu(1)-N(3) bond length is 2.11 Å. The Cu(1)-N(6) bond length is 1.91 Å. The Cu(1)-S(1) bond length is 2.30 Å. The Cu(1)-S(3) bond length is 2.29 Å. In the second Cu site, Cu(2) is bonded in a distorted tetrahedral geometry to one N(1), one N(4), one S(2), and one S(3) atom. The Cu(2)-N(1) bond length is 2.01 Å. The Cu(2)-N(4) bond length is 2.01 Å. The Cu(2)-S(2) bond length is 2.26 Å. The Cu(2)-S(3) bond length is 2.28 Å. In the third Cu site, Cu(3) is bonded in a 4-coordinate geometry to one N(2), one N(5), one S(1), and one S(2) atom. The Cu(3)-N(2) bond length is 2.04 Å. The Cu(3)-N(5) bond length is 2.04 Å. The Cu(3)-S(1) bond length is 2.27 Å. The Cu(3)-S(2) bond length is 2.26 Å. There are twenty-six inequivalent C sites. In the first C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(15) atom. The C(20)-C(19) bond length is 1.40 Å. The C(20)-H(15) bond length is 1.09 Å. In the second C site, C(21) is bonded in a distorted trigonal planar geometry to one N(4) and one H(16) atom. The C(21)-N(4) bond length is 1.35 Å. The C(21)-H(16) bond length is 1.09 Å. In the third C site, C(22) is bonded in a trigonal planar geometry to one C(19), one C(23), and one C(26) atom. The C(22)-C(19) bond length is 1.47 Å. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(26) bond length is 1.41 Å. In the fourth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(17) atom. The C(23)-H(17) bond length is 1.09 Å. In the fifth C site, C(24) is bonded in a distorted trigonal planar geometry to one N(5) and one H(18) atom. The C(24)-N(5) bond length is 1.35 Å. The C(24)-H(18) bond length is 1.09 Å. In the sixth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(26), one N(5), and one H(19) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-N(5) bond length is 1.35 Å. The C(25)-H(19) bond length is 1.09 Å. In the seventh C site, C(26) is bonded in a distorted trigonal planar geometry to one C(22), one C(25), and one H(20) atom. The C(26)-H(20) bond length is 1.09 Å. In the eighth C site, C(1) is bonded in a distorted linear geometry to one N(6) and one S(4) atom. The C(1)-N(6) bond length is 1.19 Å. The C(1)-S(4) bond length is 1.62 Å. In the ninth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(1) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(1) bond length is 1.09 Å. In the tenth C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the eleventh C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(5) atom. The C(4)-C(4) bond length is 1.47 Å. The C(4)-C(5) bond length is 1.40 Å. In the twelfth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. In the thirteenth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(6)-N(1) bond length is 1.35 Å. The C(6)-H(4) bond length is 1.09 Å. In the fourteenth C site, C(7) is bonded in a distorted trigonal planar geometry to one N(2) and one H(5) atom. The C(7)-N(2) bond length is 1.35 Å. The C(7)-H(5) bond length is 1.09 Å. In the fifteenth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(6) bond length is 1.09 Å. In the sixteenth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(12) bond length is 1.47 Å. In the seventeenth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(7) atom. The C(10)-H(7) bond length is 1.09 Å. In the eighteenth C site, C(11) is bonded in a distorted trigonal planar geometry to one N(2) and one H(8) atom. The C(11)-N(2) bond length is 1.35 Å. The C(11)-H(8) bond length is 1.09 Å. In the nineteenth C site, C(12) is bonded in a trigonal planar geometry to one C(13), one C(16), and one C(9) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(16) bond length is 1.40 Å. In the twentieth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(9) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(9) bond length is 1.09 Å. In the twenty-first C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(3), and one H(10) atom. The C(14)-N(3) bond length is 1.35 Å. The C(14)-H(10) bond length is 1.09 Å. In the twenty-second C site, C(15) is bonded in a distorted trigonal planar geometry to one N(3) and one H(11) atom. The C(15)-N(3) bond length is 1.35 Å. The C(15)-H(11) bond length is 1.09 Å. In the twenty-third C site, C(16) is bonded in a distorted single-bond geometry to one C(12) and one H(12) atom. The C(16)-H(12) bond length is 1.09 Å. In the twenty-fourth C site, C(17) is bonded in a distorted trigonal planar geometry to one N(4) and one H(13) atom. The C(17)-N(4) bond length is 1.35 Å. The C(17)-H(13) bond length is 1.09 Å. In the twenty-fifth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(14) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-H(14) bond length is 1.09 Å. In the twenty-sixth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(22) atom. There are six inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(17), and one C(21) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Cu(3), one C(24), and one C(25) atom. In the third N site, N(6) is bonded in a linear geometry to one Cu(1) and one C(1) atom. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(14), and one C(15) atom. In the fifth N site, N(2) is bonded in a trigonal planar geometry to one Cu(3), one C(11), and one C(7) atom. In the sixth N site, N(1) is bonded in a trigonal planar geometry to one Cu(2), one C(2), and one C(6) atom. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(26) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Cu(1), and one Cu(3) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Cu(2), and one Cu(3) atom. In the third S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Cu(1), and one Cu(2) atom. In the fourth S site, S(4) is bonded in a single-bond geometry to one C(1) atom. O(1) is bonded in a single-bond geometry to one Mo(1) atom. Linkers: 8 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [O][Mo]1234[S]5[Cu](N=C=S)[S]1[Cu]2[S]3[Cu]54 ,6 [Cu] ,2 [Mo]. The MOF has largest included sphere 2.79 A, density 1.64 g/cm3, surface area 4614.43 m2/g, accessible volume 0.10 cm3/g