C16H14N2O6Ni is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two water molecules, and two NiC13N2H9O5 clusters. In each NiC13N2H9O5 cluster, Ni(1) is bonded in a distorted square pyramidal geometry to one N(1), one N(2), one O(1), one O(3), and one O(5) atom. The Ni(1)-N(1) bond length is 1.89 Å. The Ni(1)-N(2) bond length is 1.87 Å. The Ni(1)-O(1) bond length is 2.45 Å. The Ni(1)-O(3) bond length is 1.86 Å. The Ni(1)-O(5) bond length is 1.90 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(12) bond length is 1.41 Å. The C(4)-C(5) bond length is 1.44 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-C(7) bond length is 1.44 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one N(2) and one H(8) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(8) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(7), and one N(2) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-N(2) bond length is 1.37 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(4), and one N(1) atom. The C(12)-N(1) bond length is 1.37 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(13)-O(1) bond length is 1.25 Å. The C(13)-O(2) bond length is 1.29 Å. In the thirteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(16)-O(3) bond length is 1.31 Å. The C(16)-O(4) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(1), and one C(12) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ni(1), one C(10), and one C(11) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one O(5) atom. The H(11)-O(5) bond length is 0.98 Å. In the ninth H site, H(12) is bonded in a linear geometry to one O(2) and one O(5) atom. The H(12)-O(2) bond length is 1.42 Å. The H(12)-O(5) bond length is 1.08 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ni(1) and one C(13) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(13) and one H(12) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(16) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(16) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Ni(1), one H(11), and one H(12) atom. Linkers: 1 c1cnc2c(c1)ccc1cccnc12. Metal clusters: 1 [Ni]. The MOF has largest included sphere 2.33 A, density 1.64 g/cm3, surface area 4133.71 m2/g, accessible volume 0.16 cm3/g