Cd6C48H12S7(NO2)12 crystallizes in the trigonal R-3 space group. Cd(1) is bonded in a 8-coordinate geometry to one N(1), one S(2), one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms. The Cd(1)-N(1) bond length is 2.36 Å. The Cd(1)-S(2) bond length is 2.81 Å. The Cd(1)-O(2) bond length is 2.75 Å. The Cd(1)-O(3) bond length is 2.63 Å. There is one shorter (2.34 Å) and one longer (2.35 Å) Cd(1)-O(1) bond length. There is one shorter (2.36 Å) and one longer (2.40 Å) Cd(1)-O(4) bond length. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.43 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.42 Å. The C(5)-C(8) bond length is 1.49 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one N(2) atom. The C(6)-N(2) bond length is 1.35 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one N(1) atom. The C(7)-N(1) bond length is 1.35 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.25 Å. The C(8)-O(4) bond length is 1.29 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(7), and one S(1) atom. The N(1)-S(1) bond length is 1.63 Å. In the second N site, N(2) is bonded in a water-like geometry to one C(6) and one S(1) atom. The N(2)-S(1) bond length is 1.60 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in an octahedral geometry to six equivalent Cd(1) atoms. There are four inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Cd(1) and one C(8) atom. In the third O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(8) atom. In the fourth O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one C(1) atom. Linkers: 6 [O]C(=O)c1ccc(C([O])=O)c2nsnc12. Metal clusters: 1 O=[C]O[Cd](O[C]=O)S([Cd](O[C]=O)O[C]=O)([Cd](O[C]=O)O[C]=O)([Cd](O[C]=O)O[C]=O)([Cd](O[C]=O)O[C]=O)[Cd](O[C]=O)O[C]=O. RCSR code: pcu. The MOF has largest included sphere 10.22 A, density 1.56 g/cm3, surface area 2877.14 m2/g, accessible volume 0.31 cm3/g