CdC30H22(N2O)4 crystallizes in the monoclinic C2/c space group. The structure consists of a CdC30H22(N2O)4 framework. Cd(1) is bonded in a 8-coordinate geometry to two N(1,1); two N(4,4); two O(1,1); and two O(2,2) atoms. There is one shorter (2.53 Å) and one longer (2.54 Å) Cd(1)-N(1,1) bond length. Both Cd(1)-N(4,4) bond lengths are 2.43 Å. There is one shorter (2.33 Å) and one longer (2.34 Å) Cd(1)-O(1,1) bond length. Both Cd(1)-O(2,2) bond lengths are 2.68 Å. There are nineteen inequivalent C sites. In the first C site, C(10) is bonded in a distorted water-like geometry to one C(11), one N(1), and one N(3) atom. The C(10)-C(11) bond length is 1.46 Å. The C(10)-N(1) bond length is 1.33 Å. The C(10)-N(3) bond length is 1.37 Å. In the second C site, C(10) is bonded in a distorted water-like geometry to one C(11), one N(1), and one N(3) atom. The C(10)-C(11) bond length is 1.46 Å. The C(10)-N(1) bond length is 1.33 Å. The C(10)-N(3) bond length is 1.37 Å. In the third C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(4) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-N(4) bond length is 1.35 Å. In the fourth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(8) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(8) bond length is 1.09 Å. In the fifth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(9) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(9) bond length is 1.09 Å. In the sixth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(10) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(10) bond length is 1.09 Å. In the seventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(4), and one H(11) atom. The C(15)-N(4) bond length is 1.34 Å. The C(15)-H(11) bond length is 1.09 Å. In the eighth C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.26 Å. In the ninth C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.26 Å. In the tenth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the eleventh C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the twelfth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 1.09 Å. In the thirteenth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(2) bond length is 1.09 Å. In the fourteenth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(3) bond length is 1.43 Å. In the fifteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(3) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(3) bond length is 1.09 Å. In the sixteenth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the seventeenth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(5), one H(6), and one H(7) atom. The C(8)-C(9) bond length is 1.48 Å. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-H(7) bond length is 1.10 Å. In the eighteenth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(5), one H(6), and one H(7) atom. The C(8)-C(9) bond length is 1.48 Å. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-H(7) bond length is 1.10 Å. In the nineteenth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one N(3) atom. The C(9)-N(2) bond length is 1.33 Å. The C(9)-N(3) bond length is 1.38 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one Cd(1), one C(10), and one N(2) atom. The N(1)-N(2) bond length is 1.37 Å. In the second N site, N(1) is bonded in a distorted single-bond geometry to one Cd(1), one C(10), and one N(2) atom. The N(1)-N(2) bond length is 1.37 Å. In the third N site, N(2) is bonded in a distorted water-like geometry to one C(9) and one N(1) atom. In the fourth N site, N(2) is bonded in a distorted water-like geometry to one C(9) and one N(1) atom. The N(2)-C(9) bond length is 1.33 Å. In the fifth N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(5), and one C(9) atom. In the sixth N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(5), and one C(9) atom. The N(3)-C(5) bond length is 1.43 Å. The N(3)-C(9) bond length is 1.38 Å. In the seventh N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(15) atom. In the eighth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(15) atom. The N(4)-C(11) bond length is 1.35 Å. The N(4)-C(15) bond length is 1.34 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1) and one C(1) atom. In the second O site, O(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Cd(1) and one C(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one Cd(1) and one C(1) atom. Linkers: 8 Cc1nnc(-c2ccccn2)n1-c1ccc(C([O])=O)cc1. Metal clusters: 4 O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 5.15 A, density 1.15 g/cm3, surface area 4595.28 m2/g, accessible volume 0.41 cm3/g