Mn2C31N6H36O11(CH2)3 crystallizes in the monoclinic P2_1/c space group. The structure consists of twelve 02329_fluka molecules inside a Mn2C31N6H36O11 framework. In the Mn2C31N6H36O11 framework, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(3), one O(4), one O(6), and one O(9) atom to form distorted corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles are 72°. The Mn(1)-O(1) bond length is 2.06 Å. The Mn(1)-O(11) bond length is 2.10 Å. The Mn(1)-O(3) bond length is 2.32 Å. The Mn(1)-O(4) bond length is 2.28 Å. The Mn(1)-O(6) bond length is 2.06 Å. The Mn(1)-O(9) bond length is 2.28 Å. In the second Mn site, Mn(2) is bonded to one O(10), one O(2), one O(5), one O(7), one O(8), and one O(9) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles are 72°. The Mn(2)-O(10) bond length is 2.11 Å. The Mn(2)-O(2) bond length is 2.11 Å. The Mn(2)-O(5) bond length is 2.11 Å. The Mn(2)-O(7) bond length is 2.31 Å. The Mn(2)-O(8) bond length is 2.28 Å. The Mn(2)-O(9) bond length is 2.31 Å. There are thirty-one inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.50 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(8) bond length is 1.50 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(9) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(9) bond length is 1.48 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.27 Å. The C(7)-O(2) bond length is 1.27 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.28 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(5) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.40 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(4) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(4) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(15) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(15) bond length is 1.50 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(5) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(5) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(16) bond length is 1.50 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(9), and one H(6) atom. The C(14)-H(6) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(7), and one O(8) atom. The C(15)-O(7) bond length is 1.27 Å. The C(15)-O(8) bond length is 1.28 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(5), and one O(6) atom. The C(16)-O(5) bond length is 1.28 Å. The C(16)-O(6) bond length is 1.27 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(9) atom. The C(17)-N(1) bond length is 1.36 Å. The C(17)-N(2) bond length is 1.36 Å. The C(17)-O(9) bond length is 1.28 Å. In the eighteenth C site, C(18) is bonded in a tetrahedral geometry to one N(1), one H(7), one H(8), and one H(9) atom. The C(18)-N(1) bond length is 1.45 Å. The C(18)-H(7) bond length is 1.09 Å. The C(18)-H(8) bond length is 1.10 Å. The C(18)-H(9) bond length is 1.10 Å. In the nineteenth C site, C(19) is bonded in a tetrahedral geometry to one N(2), one H(10), one H(11), and one H(12) atom. The C(19)-N(2) bond length is 1.45 Å. The C(19)-H(10) bond length is 1.09 Å. The C(19)-H(11) bond length is 1.10 Å. The C(19)-H(12) bond length is 1.10 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(13), and one H(14) atom. The C(20)-N(1) bond length is 1.46 Å. The C(20)-H(13) bond length is 1.11 Å. The C(20)-H(14) bond length is 1.10 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(15), and one H(16) atom. The C(21)-N(2) bond length is 1.46 Å. The C(21)-H(15) bond length is 1.10 Å. The C(21)-H(16) bond length is 1.10 Å. In the twenty-second C site, C(23) is bonded in a trigonal planar geometry to one N(3), one N(4), and one O(10) atom. The C(23)-N(3) bond length is 1.37 Å. The C(23)-N(4) bond length is 1.36 Å. The C(23)-O(10) bond length is 1.27 Å. In the twenty-third C site, C(24) is bonded in a tetrahedral geometry to one N(3), one H(19), one H(20), and one H(21) atom. The C(24)-N(3) bond length is 1.45 Å. The C(24)-H(19) bond length is 1.09 Å. The C(24)-H(20) bond length is 1.10 Å. The C(24)-H(21) bond length is 1.10 Å. In the twenty-fourth C site, C(25) is bonded in a tetrahedral geometry to one N(4), one H(22), one H(23), and one H(24) atom. The C(25)-N(4) bond length is 1.45 Å. The C(25)-H(22) bond length is 1.09 Å. The C(25)-H(23) bond length is 1.10 Å. The C(25)-H(24) bond length is 1.10 Å. In the twenty-fifth C site, C(26) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(25), and one H(26) atom. The C(26)-N(4) bond length is 1.46 Å. The C(26)-H(25) bond length is 1.10 Å. The C(26)-H(26) bond length is 1.10 Å. In the twenty-sixth C site, C(28) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(29), and one H(30) atom. The C(28)-N(3) bond length is 1.46 Å. The C(28)-H(29) bond length is 1.10 Å. The C(28)-H(30) bond length is 1.10 Å. In the twenty-seventh C site, C(29) is bonded in a trigonal planar geometry to one N(5), one N(6), and one O(11) atom. The C(29)-N(5) bond length is 1.36 Å. The C(29)-N(6) bond length is 1.36 Å. The C(29)-O(11) bond length is 1.27 Å. In the twenty-eighth C site, C(30) is bonded in a tetrahedral geometry to one N(6), one H(31), one H(32), and one H(33) atom. The C(30)-N(6) bond length is 1.45 Å. The C(30)-H(31) bond length is 1.09 Å. The C(30)-H(32) bond length is 1.11 Å. The C(30)-H(33) bond length is 1.10 Å. In the twenty-ninth C site, C(31) is bonded in a tetrahedral geometry to one N(5), one H(34), one H(35), and one H(36) atom. The C(31)-N(5) bond length is 1.46 Å. The C(31)-H(34) bond length is 1.09 Å. The C(31)-H(35) bond length is 1.10 Å. The C(31)-H(36) bond length is 1.10 Å. In the thirtieth C site, C(32) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(37), and one H(38) atom. The C(32)-N(6) bond length is 1.46 Å. The C(32)-H(37) bond length is 1.10 Å. The C(32)-H(38) bond length is 1.11 Å. In the thirty-first C site, C(34) is bonded in a distorted trigonal non-coplanar geometry to one N(5), one H(41), and one H(42) atom. The C(34)-N(5) bond length is 1.46 Å. The C(34)-H(41) bond length is 1.10 Å. The C(34)-H(42) bond length is 1.10 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(20) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(21) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(23), one C(24), and one C(28) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(26) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(34) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(29), one C(30), and one C(32) atom. There are thirty-six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(24) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(24) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(25) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(25) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(25) atom. In the twenty-third H site, H(25) is bonded in a single-bond geometry to one C(26) atom. In the twenty-fourth H site, H(26) is bonded in a single-bond geometry to one C(26) atom. In the twenty-fifth H site, H(29) is bonded in a single-bond geometry to one C(28) atom. In the twenty-sixth H site, H(30) is bonded in a single-bond geometry to one C(28) atom. In the twenty-seventh H site, H(31) is bonded in a single-bond geometry to one C(30) atom. In the twenty-eighth H site, H(32) is bonded in a single-bond geometry to one C(30) atom. In the twenty-ninth H site, H(33) is bonded in a single-bond geometry to one C(30) atom. In the thirtieth H site, H(34) is bonded in a single-bond geometry to one C(31) atom. In the thirty-first H site, H(35) is bonded in a single-bond geometry to one C(31) atom. In the thirty-second H site, H(36) is bonded in a single-bond geometry to one C(31) atom. In the thirty-third H site, H(37) is bonded in a single-bond geometry to one C(32) atom. In the thirty-fourth H site, H(38) is bonded in a single-bond geometry to one C(32) atom. In the thirty-fifth H site, H(41) is bonded in a single-bond geometry to one C(34) atom. In the thirty-sixth H site, H(42) is bonded in a single-bond geometry to one C(34) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(7) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Mn(1) and one C(8) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Mn(1) and one C(8) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(16) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(16) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Mn(2) and one C(15) atom. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one Mn(2) and one C(15) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one C(17) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(23) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(29) atom. Linkers: 4 [O]C(=O)c1cc(C([O])=O)cc(-c2cc(C([O])=O)cc(C([O])=O)c2)c1. Metal clusters: 8 [Mn]. RCSR code: hwx. The MOF has largest included sphere 4.49 A, density 1.38 g/cm3, surface area 4662.85 m2/g, accessible volume 0.19 cm3/g