CuC7NH4O4C5H8(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four neopentane molecules, and two CuC7NH4O4 clusters. In each CuC7NH4O4 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(3), one O(4), one O(7), and one O(8) atom. The Cu(1)-N(1) bond length is 2.17 Å. The Cu(1)-O(3) bond length is 2.10 Å. The Cu(1)-O(4) bond length is 2.10 Å. The Cu(1)-O(7) bond length is 1.95 Å. The Cu(1)-O(8) bond length is 1.95 Å. In the second Cu site, Cu(2) is bonded in a distorted square pyramidal geometry to one N(2), one O(1), one O(2), one O(5), and one O(6) atom. The Cu(2)-N(2) bond length is 2.18 Å. The Cu(2)-O(1) bond length is 1.94 Å. The Cu(2)-O(2) bond length is 1.94 Å. The Cu(2)-O(5) bond length is 2.11 Å. The Cu(2)-O(6) bond length is 2.11 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(1) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(2) atom. The C(2)-C(4) bond length is 1.39 Å. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(3) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(3), and one C(4) atom. The C(5)-C(10) bond length is 1.48 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5,6) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-H(5,6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5,6) atom. The C(7)-N(2) bond length is 1.34 Å. The C(7)-H(5,6) bond length is 1.09 Å. In the eighth C site, C(8,9) is bonded in a distorted single-bond geometry to one C(10) and one H(7,8) atom. The C(8,9)-C(10) bond length is 1.40 Å. The C(8,9)-H(7,8) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(5) and two equivalent C(8,9) atoms. In the tenth C site, C(11,12) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(11,12)-O(1) bond length is 1.28 Å. The C(11,12)-O(3) bond length is 1.27 Å. In the eleventh C site, C(19,20) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(7) atom. The C(19,20)-O(5) bond length is 1.27 Å. The C(19,20)-O(7) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(6), and one C(7) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(8,9) atom. There are eight inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(11,12) atom. The O(2)-C(11,12) bond length is 1.28 Å. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(11,12) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(11,12) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(11,12) atom. The O(4)-C(11,12) bond length is 1.27 Å. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(19,20) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(19,20) atom. The O(6)-C(19,20) bond length is 1.27 Å. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(19,20) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(19,20) atom. The O(8)-C(19,20) bond length is 1.28 Å. Linkers: 4 [O]C(=O)CC1(CC([O])=O)CCCC1 ,2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 2.37 A, density 1.70 g/cm3, surface area 4117.82 m2/g, accessible volume 0.09 cm3/g