V2MnC3H2(NO3)2CH crystallizes in the monoclinic C2/m space group. The structure consists of four 02329_fluka molecules inside a V2MnC3H2(NO3)2 framework. In the V2MnC3H2(NO3)2 framework, V(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form VO4 tetrahedra that share corners with two equivalent Mn(1)N2O4 octahedra and corners with two equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-47°. The V(1)-O(1) bond length is 1.68 Å. The V(1)-O(2) bond length is 1.80 Å. The V(1)-O(3) bond length is 1.68 Å. The V(1)-O(4) bond length is 1.80 Å. Mn(1) is bonded to two equivalent N(1), two equivalent O(1), and two equivalent O(3) atoms to form MnN2O4 octahedra that share corners with four equivalent V(1)O4 tetrahedra. Both Mn(1)-N(1) bond lengths are 2.25 Å. Both Mn(1)-O(1) bond lengths are 2.02 Å. Both Mn(1)-O(3) bond lengths are 2.05 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(2) and two equivalent N(1) atoms. The C(2)-C(2) bond length is 1.48 Å. Both C(2)-N(1) bond lengths are 1.34 Å. N(1) is bonded in a trigonal planar geometry to one Mn(1), one C(1), and one C(2) atom. H(2) is bonded in a single-bond geometry to one C(1) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Mn(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one V(1) and one Mn(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. Linkers: 1 c1cnc(-c2ncccn2)nc1. Metal clusters: 2 [Mn] ,4 [V]. The MOF has largest included sphere 2.70 A, density 2.41 g/cm3, surface area 2554.21 m2/g, accessible volume 0.07 cm3/g