ZnC10H12(NO)4(CH2)2 crystallizes in the trigonal P3_121 space group. The structure consists of six 02329_fluka molecules inside a ZnC10H12(NO)4 framework. In the ZnC10H12(NO)4 framework, Zn(1) is bonded in a distorted octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. Both Zn(1)-N(1) bond lengths are 2.05 Å. Both Zn(1)-O(1) bond lengths are 2.19 Å. Both Zn(1)-O(2) bond lengths are 2.32 Å. There are five inequivalent C sites. In the first C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(5) atom. The C(4)-C(3) bond length is 1.37 Å. The C(4)-N(2) bond length is 1.38 Å. The C(4)-H(5) bond length is 1.08 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(5)-O(1) bond length is 1.27 Å. The C(5)-O(2) bond length is 1.29 Å. In the third C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one N(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.35 Å. In the fourth C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one H(1), one H(2), and one H(3) atom. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. The C(2)-H(3) bond length is 1.10 Å. In the fifth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(4) atom. The C(3)-N(1) bond length is 1.39 Å. The C(3)-H(4) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(4), and one H(8) atom. The N(2)-H(8) bond length is 1.04 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(8) is bonded in a distorted linear geometry to one N(2) and one O(2) atom. The H(8)-O(2) bond length is 1.71 Å. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Zn(1) and one C(5) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Zn(1), one C(5), and one H(8) atom. Linkers: 3 [O]C(=O)CCC([O])=O. Metal clusters: 3 [Zn]. The MOF has largest included sphere 3.32 A, density 1.36 g/cm3, surface area 4951.18 m2/g, accessible volume 0.23 cm3/g