CH2PbCH2SO6 crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a PbCH2SO6 framework. In the PbCH2SO6 framework, Pb(1) is bonded in a 9-coordinate geometry to one O(3), one O(4), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(6) atoms. The Pb(1)-O(3) bond length is 2.73 Å. The Pb(1)-O(4) bond length is 2.84 Å. The Pb(1)-O(5) bond length is 2.84 Å. There is one shorter (2.53 Å) and one longer (2.81 Å) Pb(1)-O(1) bond length. There is one shorter (2.53 Å) and one longer (2.81 Å) Pb(1)-O(2) bond length. There is one shorter (2.71 Å) and one longer (2.75 Å) Pb(1)-O(6) bond length. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. There are two inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one O(6) atom. The H(3)-O(6) bond length is 0.99 Å. In the second H site, H(4) is bonded in a single-bond geometry to one O(6) atom. The H(4)-O(6) bond length is 0.99 Å. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(3), one O(4), and one O(5) atom. The S(1)-O(3) bond length is 1.46 Å. The S(1)-O(4) bond length is 1.48 Å. The S(1)-O(5) bond length is 1.48 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Pb(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Pb(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Pb(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a water-like geometry to two equivalent Pb(1), one H(3), and one H(4) atom. Linkers: 2 [O]C(=O)CS([O])([O])[O]. Metal clusters: 2 [Pb]. The MOF has largest included sphere 1.45 A, density 3.82 g/cm3, surface area 1809.02 m2/g, accessible volume 0.05 cm3/g