CuC13H9O5CH crystallizes in the monoclinic C2 space group. The structure consists of eight 02329_fluka molecules inside a CuC13H9O5 framework. In the CuC13H9O5 framework, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square pyramidal geometry to one O(1), one O(10), one O(3), one O(5), and one O(8) atom. The Cu(1)-O(1) bond length is 2.33 Å. The Cu(1)-O(10) bond length is 2.01 Å. The Cu(1)-O(3) bond length is 2.00 Å. The Cu(1)-O(5) bond length is 1.94 Å. The Cu(1)-O(8) bond length is 1.98 Å. In the second Cu site, Cu(2) is bonded in a distorted square pyramidal geometry to one O(2), one O(4), one O(6), one O(7), and one O(9) atom. The Cu(2)-O(2) bond length is 2.33 Å. The Cu(2)-O(4) bond length is 2.00 Å. The Cu(2)-O(6) bond length is 1.95 Å. The Cu(2)-O(7) bond length is 1.99 Å. The Cu(2)-O(9) bond length is 2.01 Å. There are twenty-six inequivalent C sites. In the first C site, C(21) is bonded in a distorted single-bond geometry to one C(23) and one H(13) atom. The C(21)-C(23) bond length is 1.40 Å. The C(21)-H(13) bond length is 1.09 Å. In the second C site, C(22) is bonded in a distorted single-bond geometry to one C(24) and one H(14) atom. The C(22)-C(24) bond length is 1.40 Å. The C(22)-H(14) bond length is 1.09 Å. In the third C site, C(23) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(27) atom. The C(23)-C(25) bond length is 1.40 Å. The C(23)-C(27) bond length is 1.49 Å. In the fourth C site, C(24) is bonded in a trigonal planar geometry to one C(22), one C(26), and one C(28) atom. The C(24)-C(26) bond length is 1.40 Å. The C(24)-C(28) bond length is 1.49 Å. In the fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(15), one C(23), and one H(15) atom. The C(25)-C(15) bond length is 1.40 Å. The C(25)-H(15) bond length is 1.09 Å. In the sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(16), one C(24), and one H(16) atom. The C(26)-C(16) bond length is 1.40 Å. The C(26)-H(16) bond length is 1.09 Å. In the seventh C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(7), and one O(9) atom. The C(27)-O(7) bond length is 1.28 Å. The C(27)-O(9) bond length is 1.28 Å. In the eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(10), and one O(8) atom. The C(28)-O(10) bond length is 1.28 Å. The C(28)-O(8) bond length is 1.28 Å. In the ninth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(5) atom. The C(1)-C(3) bond length is 1.49 Å. The C(1)-O(3) bond length is 1.28 Å. The C(1)-O(5) bond length is 1.28 Å. In the tenth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(4), and one O(6) atom. The C(2)-C(4) bond length is 1.49 Å. The C(2)-O(4) bond length is 1.28 Å. The C(2)-O(6) bond length is 1.28 Å. In the eleventh C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(5) atom. The C(3)-C(13) bond length is 1.40 Å. The C(3)-C(5) bond length is 1.40 Å. In the twelfth C site, C(4) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(6) atom. The C(4)-C(14) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.40 Å. In the thirteenth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one H(1) atom. The C(5)-C(7) bond length is 1.39 Å. The C(5)-H(1) bond length is 1.09 Å. In the fourteenth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(4), one C(8), and one H(2) atom. The C(6)-C(8) bond length is 1.39 Å. The C(6)-H(2) bond length is 1.09 Å. In the fifteenth C site, C(7) is bonded in a distorted single-bond geometry to one C(5); one C(9); and one H(3,4) atom. The C(7)-C(9) bond length is 1.41 Å. The C(7)-H(3,4) bond length is 1.09 Å. In the sixteenth C site, C(8) is bonded in a distorted single-bond geometry to one C(10); one C(6); and one H(3,4) atom. The C(8)-C(10) bond length is 1.41 Å. The C(8)-H(3,4) bond length is 1.09 Å. In the seventeenth C site, C(9) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(7) atom. The C(9)-C(11) bond length is 1.41 Å. The C(9)-C(15) bond length is 1.48 Å. In the eighteenth C site, C(10) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(8) atom. The C(10)-C(12) bond length is 1.41 Å. The C(10)-C(16) bond length is 1.48 Å. In the nineteenth C site, C(11) is bonded in a distorted single-bond geometry to one C(9) and one H(5,6) atom. The C(11)-H(5,6) bond length is 1.09 Å. In the twentieth C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one H(5,6) atom. The C(12)-H(5,6) bond length is 1.09 Å. In the twenty-first C site, C(13) is bonded in a distorted single-bond geometry to one C(3) and one H(7) atom. The C(13)-H(7) bond length is 1.09 Å. In the twenty-second C site, C(14) is bonded in a distorted single-bond geometry to one C(4) and one H(8) atom. The C(14)-H(8) bond length is 1.09 Å. In the twenty-third C site, C(15) is bonded in a trigonal planar geometry to one C(17), one C(25), and one C(9) atom. The C(15)-C(17) bond length is 1.41 Å. In the twenty-fourth C site, C(16) is bonded in a trigonal planar geometry to one C(10), one C(18), and one C(26) atom. The C(16)-C(18) bond length is 1.41 Å. In the twenty-fifth C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one H(9,10) atom. The C(17)-H(9,10) bond length is 1.09 Å. In the twenty-sixth C site, C(18) is bonded in a distorted single-bond geometry to one C(16) and one H(9,10) atom. The C(18)-H(9,10) bond length is 1.09 Å. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(26) atom. In the twelfth H site, H(17,18) is bonded in a single-bond geometry to one O(1) atom. The H(17,18)-O(1) bond length is 0.98 Å. In the thirteenth H site, H(19,20) is bonded in a single-bond geometry to one O(1) atom. The H(19,20)-O(1) bond length is 0.97 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cu(1); one H(17,18); and one H(19,20) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cu(2); one H(17,18); and one H(19,20) atom. The O(2)-H(17,18) bond length is 0.98 Å. The O(2)-H(19,20) bond length is 0.97 Å. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(27) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(28) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(27) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(28) atom. Linkers: 4 [O]C(=O)c1ccc(-c2cccc(C([O])=O)c2)cc1. Metal clusters: 2 O.O.[C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: dia. The MOF has largest included sphere 6.02 A, density 1.01 g/cm3, surface area 4526.20 m2/g, accessible volume 0.50 cm3/g