CuC10NH16O5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CuC10NH16O5 cluster. Cu(1) is bonded to one N(1), one O(2), one O(3), one O(4), and two equivalent O(1) atoms to form distorted edge-sharing CuNO5 octahedra. The Cu(1)-N(1) bond length is 2.05 Å. The Cu(1)-O(2) bond length is 2.56 Å. The Cu(1)-O(3) bond length is 1.97 Å. The Cu(1)-O(4) bond length is 2.51 Å. There is one shorter (1.95 Å) and one longer (1.97 Å) Cu(1)-O(1) bond length. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(4), and one O(2) atom. The C(1)-H(3) bond length is 1.10 Å. The C(1)-H(4) bond length is 1.10 Å. The C(1)-O(2) bond length is 1.44 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(5), and one H(6) atom. The C(2)-N(1) bond length is 1.49 Å. The C(2)-H(5) bond length is 1.10 Å. The C(2)-H(6) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(7), and one H(8) atom. The C(3)-N(1) bond length is 1.48 Å. The C(3)-H(7) bond length is 1.10 Å. The C(3)-H(8) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one H(10), one H(9), and one O(4) atom. The C(4)-H(10) bond length is 1.10 Å. The C(4)-H(9) bond length is 1.11 Å. The C(4)-O(4) bond length is 1.42 Å. In the fifth C site, C(5) is bonded in a 3-coordinate geometry to one N(1), one H(11), and one H(12) atom. The C(5)-N(1) bond length is 1.50 Å. The C(5)-H(11) bond length is 1.10 Å. The C(5)-H(12) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one H(13), one H(14), and one O(1) atom. The C(6)-H(13) bond length is 1.11 Å. The C(6)-H(14) bond length is 1.11 Å. The C(6)-O(1) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(3), and one O(5) atom. The C(7)-C(8) bond length is 1.50 Å. The C(7)-O(3) bond length is 1.28 Å. The C(7)-O(5) bond length is 1.27 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(15) atom. The C(9)-H(15) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(16) atom. The C(10)-H(16) bond length is 1.09 Å. N(1) is bonded in a tetrahedral geometry to one Cu(1), one C(2), one C(3), and one C(5) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 0.97 Å. In the second H site, H(2) is bonded in a linear geometry to one O(4) and one O(5) atom. The H(2)-O(4) bond length is 1.01 Å. The H(2)-O(5) bond length is 1.59 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(4) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(5) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(5) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(6) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(6) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(9) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(10) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cu(1) and one C(6) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cu(1), one C(1), and one H(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Cu(1), one C(4), and one H(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(7) and one H(2) atom. Linkers: 2 [O]CCN(CCO)CCO ,1 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.59 A, density 1.63 g/cm3, surface area 4352.26 m2/g, accessible volume 0.13 cm3/g