ZnC28H18(N2O)2(CH)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two ZnC28H18(N2O)2 clusters. In each ZnC28H18(N2O)2 cluster, Zn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent O(1) atoms. Both Zn(1)-N(1) bond lengths are 2.26 Å. Both Zn(1)-N(2) bond lengths are 2.21 Å. Both Zn(1)-O(1) bond lengths are 2.06 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one O(1) atom. The C(1)-O(1) bond length is 1.30 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(7) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(7) bond length is 1.09 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.44 Å. The C(5)-C(7) bond length is 1.42 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one N(1) atom. The C(6)-N(1) bond length is 1.36 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5), one C(8), and one H(3) atom. The C(7)-C(8) bond length is 1.37 Å. The C(7)-H(3) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(1) atom. The C(8)-C(9) bond length is 1.42 Å. The C(8)-H(1) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(1) atom. The C(9)-C(10) bond length is 1.45 Å. The C(9)-N(1) bond length is 1.35 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(10)-H(4) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(6) atom. The C(11)-C(12) bond length is 1.45 Å. The C(11)-H(6) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(16) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-C(16) bond length is 1.41 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(9) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(9) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(2), and one H(2) atom. The C(14)-N(2) bond length is 1.35 Å. The C(14)-H(2) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5) atom. The C(15)-N(2) bond length is 1.34 Å. The C(15)-H(5) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(16)-H(10) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(6), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(14), and one C(15) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. Linkers: 4 [O]c1cccc2ccc(/C=C/c3ccncc3)nc12. Metal clusters: 2 [Zn]. The MOF has largest included sphere 4.53 A, density 1.15 g/cm3, surface area 4800.18 m2/g, accessible volume 0.30 cm3/g