(CH2)2Cd3C28H34S2(N3O5)4 crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a Cd3C28H34S2(N3O5)4 framework. In the Cd3C28H34S2(N3O5)4 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(10), and two equivalent O(9) atoms. Both Cd(1)-N(1) bond lengths are 2.34 Å. Both Cd(1)-O(10) bond lengths are 2.42 Å. Both Cd(1)-O(9) bond lengths are 2.30 Å. In the second Cd site, Cd(2) is bonded in a 5-coordinate geometry to one N(6), one O(4), one O(8), and two equivalent O(1) atoms. The Cd(2)-N(6) bond length is 2.27 Å. The Cd(2)-O(4) bond length is 2.26 Å. The Cd(2)-O(8) bond length is 2.37 Å. There is one shorter (2.30 Å) and one longer (2.46 Å) Cd(2)-O(1) bond length. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-N(3) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(3), and one H(4) atom. The C(3)-N(2) bond length is 1.46 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(4) bond length is 1.10 Å. In the fourth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(7), and one H(8) atom. The C(5)-N(4) bond length is 1.46 Å. The C(5)-H(7) bond length is 1.10 Å. The C(5)-H(8) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(9) atom. The C(6)-N(4) bond length is 1.34 Å. The C(6)-N(6) bond length is 1.34 Å. The C(6)-H(9) bond length is 1.08 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(10) atom. The C(7)-N(5) bond length is 1.33 Å. The C(7)-N(6) bond length is 1.36 Å. The C(7)-H(10) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(9) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-C(14) bond length is 1.50 Å. The C(8)-C(9) bond length is 1.40 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(11) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(11) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(9), and one S(1) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-S(1) bond length is 1.78 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(12) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(12) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(15) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(15) bond length is 1.50 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(13) atom. The C(13)-H(13) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(1), and one O(2) atom. The C(14)-O(1) bond length is 1.30 Å. The C(14)-O(2) bond length is 1.25 Å. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(3), and one O(4) atom. The C(15)-O(3) bond length is 1.27 Å. The C(15)-O(4) bond length is 1.28 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one N(3) atom. The N(2)-N(3) bond length is 1.36 Å. In the third N site, N(3) is bonded in a water-like geometry to one C(1) and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(5), one C(6), and one N(5) atom. The N(4)-N(5) bond length is 1.36 Å. In the fifth N site, N(5) is bonded in a distorted single-bond geometry to one C(7), one N(4), and one H(17) atom. The N(5)-H(17) bond length is 1.75 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(6), and one C(7) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(14) is bonded in a distorted single-bond geometry to one O(3) and one O(8) atom. The H(14)-O(3) bond length is 1.65 Å. The H(14)-O(8) bond length is 1.00 Å. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one O(8) atom. The H(15)-O(8) bond length is 0.98 Å. In the fourteenth H site, H(16) is bonded in a distorted single-bond geometry to one O(6) and one O(9) atom. The H(16)-O(6) bond length is 1.70 Å. The H(16)-O(9) bond length is 1.00 Å. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one N(5) and one O(9) atom. The H(17)-O(9) bond length is 1.00 Å. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one O(10) atom. The H(18)-O(10) bond length is 0.97 Å. In the seventeenth H site, H(19) is bonded in a distorted single-bond geometry to one O(10) and one O(5) atom. The H(19)-O(10) bond length is 1.01 Å. The H(19)-O(5) bond length is 1.67 Å. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one O(5), one O(6), and one O(7) atom. The S(1)-O(5) bond length is 1.48 Å. The S(1)-O(6) bond length is 1.48 Å. The S(1)-O(7) bond length is 1.46 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cd(2) and one C(14) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(14) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one C(15) and one H(14) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cd(2) and one C(15) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one H(19) and one S(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one H(16) and one S(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Cd(2), one H(14), and one H(15) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Cd(1), one H(16), and one H(17) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Cd(1), one H(18), and one H(19) atom. Linkers: 2 [O]C(=O)c1cc(C([O])=O)cc(S([O])([O])[O])c1 ,2 [CH]1N=C[N]N1CCCn1cncn1. Metal clusters: 1 O.O.O.O.[Cd] ,1 O.O.O=[C]O[Cd]O[C]=O.O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 2.44 A, density 1.93 g/cm3, surface area 3707.20 m2/g, accessible volume 0.14 cm3/g