CdC9N5H8O2CH crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of four 02329_fluka molecules inside a CdC9N5H8O2 framework. In the CdC9N5H8O2 framework, Cd(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(2), one N(3), one O(1), and one O(2) atom. The Cd(1)-N(1) bond length is 2.30 Å. The Cd(1)-N(2) bond length is 2.28 Å. The Cd(1)-N(3) bond length is 2.27 Å. The Cd(1)-O(1) bond length is 2.39 Å. The Cd(1)-O(2) bond length is 2.30 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a 2-coordinate geometry to one N(1) and one H(3) atom. The C(2)-N(1) bond length is 1.47 Å. The C(2)-H(3) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted water-like geometry to one C(6), one H(4), and one H(5) atom. The C(3)-C(6) bond length is 1.51 Å. The C(3)-H(4) bond length is 1.10 Å. The C(3)-H(5) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5), one C(6), and one H(6) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.40 Å. The C(4)-H(6) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(8) atom. The C(5)-C(10) bond length is 1.47 Å. The C(5)-C(8) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(9) atom. The C(6)-C(9) bond length is 1.40 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(5) and one H(8) atom. The C(8)-H(8) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(6) and one H(9) atom. The C(9)-H(9) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(5), one N(2), and one N(3) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-N(3) bond length is 1.35 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Cd(1), one C(2), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one N(5) atom. The N(2)-N(5) bond length is 1.36 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Cd(1), one C(10), and one N(4) atom. The N(3)-N(4) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one N(3) and one N(5) atom. The N(4)-N(5) bond length is 1.31 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one N(2) and one N(4) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1) and one C(1) atom. Linkers: 4 N[C@@H](Cc1cccc(C2=NN=N[N]2)c1)C([O])=O. Metal clusters: 4 [Cd]. The MOF has largest included sphere 2.76 A, density 1.96 g/cm3, surface area 3674.25 m2/g, accessible volume 0.10 cm3/g