ZnC14H10(NO)4(CH)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two ZnC14H10(NO)4 clusters. In each ZnC14H10(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-N(2) bond length is 2.03 Å. The Zn(1)-O(3) bond length is 2.00 Å. The Zn(1)-O(4) bond length is 2.00 Å. There are eight inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal planar geometry to one C(3,4); one N(1); and one H(1,2) atom. The C(1,2)-C(3,4) bond length is 1.37 Å. The C(1,2)-N(1) bond length is 1.38 Å. The C(1,2)-H(1,2) bond length is 1.08 Å. In the second C site, C(3,4) is bonded in a distorted bent 120 degrees geometry to one C(1,2); one N(3,4); and one H(3,4) atom. The C(3,4)-N(3,4) bond length is 1.39 Å. The C(3,4)-H(3,4) bond length is 1.08 Å. In the third C site, C(5,6) is bonded in a trigonal planar geometry to one N(1); one N(3,4); and one H(5,6) atom. The C(5,6)-N(1) bond length is 1.33 Å. The C(5,6)-N(3,4) bond length is 1.36 Å. The C(5,6)-H(5,6) bond length is 1.08 Å. In the fourth C site, C(7,8) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(9,10); and one N(3,4) atom. The C(7,8)-C(11,12) bond length is 1.40 Å. The C(7,8)-C(9,10) bond length is 1.40 Å. The C(7,8)-N(3,4) bond length is 1.43 Å. In the fifth C site, C(9,10) is bonded in a distorted single-bond geometry to one C(7,8) and one H(7,8) atom. The C(9,10)-H(7,8) bond length is 1.09 Å. In the sixth C site, C(11,12) is bonded in a distorted single-bond geometry to one C(7,8) and one H(9,10) atom. The C(11,12)-H(9,10) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(13)-O(1) bond length is 1.25 Å. The C(13)-O(3) bond length is 1.31 Å. In the eighth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(14)-O(2) bond length is 1.25 Å. The C(14)-O(4) bond length is 1.31 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1); one C(1,2); and one C(5,6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1); one C(1,2); and one C(5,6) atom. The N(2)-C(1,2) bond length is 1.38 Å. The N(2)-C(5,6) bond length is 1.33 Å. In the third N site, N(3,4) is bonded in a trigonal planar geometry to one C(3,4); one C(5,6); and one C(7,8) atom. There are five inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(3,4) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(5,6) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(9,10) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(11,12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(13) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(14) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(13) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zn(1) and one C(14) atom. Linkers: 2 c1cn(-c2ccc(-n3ccnc3)cc2)cn1 ,2 [O]C(=O)/C=C/C([O])=O. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 1.82 A, density 1.71 g/cm3, surface area 4271.26 m2/g, accessible volume 0.18 cm3/g