CdC7N5H5S2CH crystallizes in the monoclinic C2/c space group. The structure consists of eight 02329_fluka molecules inside a CdC7N5H5S2 framework. In the CdC7N5H5S2 framework, Cd(1) is bonded in a distorted octahedral geometry to one N(1), one N(2), one N(4), one N(5), one S(1), and one S(2) atom. The Cd(1)-N(1) bond length is 2.37 Å. The Cd(1)-N(2) bond length is 2.39 Å. The Cd(1)-N(4) bond length is 2.31 Å. The Cd(1)-N(5) bond length is 2.37 Å. The Cd(1)-S(1) bond length is 2.71 Å. The Cd(1)-S(2) bond length is 2.69 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.49 Å. The C(5)-N(1) bond length is 1.35 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(2), and one N(3) atom. The C(6)-N(2) bond length is 1.32 Å. The C(6)-N(3) bond length is 1.35 Å. In the sixth C site, C(7) is bonded in a distorted linear geometry to one N(4) and one S(1) atom. The C(7)-N(4) bond length is 1.18 Å. The C(7)-S(1) bond length is 1.64 Å. In the seventh C site, C(8) is bonded in a distorted linear geometry to one N(5) and one S(2) atom. The C(8)-N(5) bond length is 1.19 Å. The C(8)-S(2) bond length is 1.63 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(6), and one N(2) atom. The N(2)-N(2) bond length is 1.38 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(6), one H(5), and one H(6) atom. The N(3)-H(5) bond length is 1.02 Å. The N(3)-H(6) bond length is 1.02 Å. In the fourth N site, N(4) is bonded in a distorted linear geometry to one Cd(1) and one C(7) atom. In the fifth N site, N(5) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(8) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Cd(1) and one C(7) atom. In the second S site, S(2) is bonded in a water-like geometry to one Cd(1) and one C(8) atom. Linkers: 2 [NH2]=C(c1ccccn1)[N][N]C(=[NH2])c1ccccn1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 2.92 A, density 1.95 g/cm3, surface area 3570.99 m2/g, accessible volume 0.13 cm3/g