CdC13H7(NO2)2CH(C2NH2S)3CHO2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two formic acid molecules, two C2NH2S clusters, and one CdC13H7(NO2)2 cluster. In each C2NH2S cluster, there are six inequivalent C sites. In the first C site, C(18) is bonded in a distorted water-like geometry to one H(11), one H(12), and one S(1) atom. The C(18)-H(11) bond length is 1.10 Å. The C(18)-H(12) bond length is 1.10 Å. The C(18)-S(1) bond length is 1.80 Å. In the second C site, C(19) is bonded in a distorted water-like geometry to one H(13), one H(14), and one S(3) atom. The C(19)-H(13) bond length is 1.09 Å. The C(19)-H(14) bond length is 1.10 Å. The C(19)-S(3) bond length is 1.80 Å. In the third C site, C(13) is bonded in a distorted trigonal planar geometry to one N(4), one N(5), and one S(3) atom. The C(13)-N(4) bond length is 1.34 Å. The C(13)-N(5) bond length is 1.34 Å. The C(13)-S(3) bond length is 1.75 Å. In the fourth C site, C(14) is bonded in a distorted trigonal planar geometry to one N(3), one N(4), and one S(1) atom. The C(14)-N(3) bond length is 1.34 Å. The C(14)-N(4) bond length is 1.35 Å. The C(14)-S(1) bond length is 1.74 Å. In the fifth C site, C(15) is bonded in a distorted trigonal planar geometry to one N(3), one N(5), and one S(2) atom. The C(15)-N(3) bond length is 1.35 Å. The C(15)-N(5) bond length is 1.34 Å. The C(15)-S(2) bond length is 1.74 Å. In the sixth C site, C(16) is bonded in a distorted water-like geometry to one H(10), one H(9), and one S(2) atom. The C(16)-H(10) bond length is 1.10 Å. The C(16)-H(9) bond length is 1.10 Å. The C(16)-S(2) bond length is 1.81 Å. There are three inequivalent N sites. In the first N site, N(3) is bonded in a bent 120 degrees geometry to one C(14) and one C(15) atom. In the second N site, N(4) is bonded in a bent 120 degrees geometry to one C(13) and one C(14) atom. In the third N site, N(5) is bonded in a bent 120 degrees geometry to one C(13) and one C(15) atom. There are six inequivalent H sites. In the first H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the second H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(14) and one C(18) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(15) and one C(16) atom. In the third S site, S(3) is bonded in a water-like geometry to one C(13) and one C(19) atom. In the CdC13H7(NO2)2 cluster, Cd(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(2), and one O(5) atom. The Cd(1)-N(1) bond length is 2.37 Å. The Cd(1)-N(2) bond length is 2.36 Å. The Cd(1)-O(1) bond length is 2.27 Å. The Cd(1)-O(2) bond length is 2.30 Å. The Cd(1)-O(5) bond length is 2.23 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(12) bond length is 1.42 Å. The C(4)-C(5) bond length is 1.43 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-C(7) bond length is 1.43 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.42 Å. The C(7)-C(8) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(10)-N(2) bond length is 1.33 Å. The C(10)-H(8) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(7), and one N(2) atom. The C(11)-C(12) bond length is 1.45 Å. The C(11)-N(2) bond length is 1.35 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(4), and one N(1) atom. The C(12)-N(1) bond length is 1.35 Å. In the twelfth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(17)-O(1) bond length is 1.26 Å. The C(17)-O(2) bond length is 1.27 Å. In the thirteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(21)-O(5) bond length is 1.29 Å. The C(21)-O(6) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(12) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one C(11) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(17) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(17) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(21) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(21) atom. Linkers: 1 [O]C(=O)CSC1=NC(=[N]=C([N]1)SCC(=O)O)SCC(=O)[O] ,1 [O]C(=O)CSC1=NC(=[N]=C([N]1)SCC(=O)[O])SCC(=O)O. Metal clusters: 1 O=[C]O[Cd]1O[C]O[Cd](O[C]=O)O[C]O1. The MOF has largest included sphere 2.66 A, density 1.82 g/cm3, surface area 4016.97 m2/g, accessible volume 0.12 cm3/g