ZnC11H7(NO2)2(CH)4CHO2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two formic acid molecules, and two ZnC11H7(NO2)2 clusters. In each ZnC11H7(NO2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 2.05 Å. The Zn(1)-N(2) bond length is 2.06 Å. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(3) bond length is 1.98 Å. There are eleven inequivalent C sites. In the first C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(4)-O(1) bond length is 1.31 Å. The C(4)-O(2) bond length is 1.25 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(5)-O(3) bond length is 1.30 Å. The C(5)-O(4) bond length is 1.25 Å. In the third C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(1), and one H(5) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(1) bond length is 1.34 Å. The C(7)-H(5) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(8) bond length is 1.09 Å. In the sixth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(1) atom. The C(11)-C(12) bond length is 1.48 Å. The C(11)-N(1) bond length is 1.36 Å. In the seventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one N(2) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-N(2) bond length is 1.35 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(9) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(9) bond length is 1.09 Å. In the ninth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(10) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(10) bond length is 1.09 Å. In the tenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(11) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(11) bond length is 1.09 Å. In the eleventh C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one N(2), and one H(12) atom. The C(16)-N(2) bond length is 1.34 Å. The C(16)-H(12) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(12), and one C(16) atom. There are seven inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(16) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(5) atom. Linkers: 1 [O]C(=O)[C@@H]1[C@@H](C([O])=O)[C@H](C(=O)O)[C@@H](C([O])=O)[C@H](C([O])=O)[C@H]1C(=O)O. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.08 A, density 1.75 g/cm3, surface area 4052.46 m2/g, accessible volume 0.13 cm3/g