(CH)2(CH3)2CuC9H6S(NO2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four 02329_fluka molecules, and one CuC9H6S(NO2)3 cluster. In the CuC9H6S(NO2)3 cluster, Cu(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(3), one O(1), one O(5), and one O(6) atom. The Cu(1)-N(1) bond length is 1.97 Å. The Cu(1)-N(3) bond length is 2.03 Å. The Cu(1)-O(1) bond length is 2.02 Å. The Cu(1)-O(5) bond length is 1.98 Å. The Cu(1)-O(6) bond length is 2.23 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-S(1) bond length is 1.78 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(6) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(6) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one N(1) atom. The C(6)-N(1) bond length is 1.42 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(2) atom. The C(7)-C(10) bond length is 1.45 Å. The C(7)-C(8) bond length is 1.47 Å. The C(7)-N(2) bond length is 1.35 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one O(4) atom. The C(8)-O(4) bond length is 1.25 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(7) and one O(5) atom. The C(10)-O(5) bond length is 1.27 Å. In the eighth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(13) atom. The C(12)-N(3) bond length is 1.34 Å. The C(12)-H(13) bond length is 1.09 Å. In the ninth C site, C(13) is bonded in a distorted trigonal planar geometry to one N(3) and one H(14) atom. The C(13)-N(3) bond length is 1.34 Å. The C(13)-H(14) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(6), and one N(2) atom. The N(1)-N(2) bond length is 1.28 Å. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(7) and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(12), and one C(13) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(6) atom. The H(1)-O(6) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) and one O(6) atom. The H(2)-O(3) bond length is 1.68 Å. The H(2)-O(6) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(13) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.50 Å. The S(1)-O(2) bond length is 1.46 Å. The S(1)-O(3) bond length is 1.46 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one H(2) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(10) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Cu(1), one H(1), and one H(2) atom. Linkers: 2 CC(=O)C(=N[N]c1ccccc1S([O])([O])[O])C(C)=O. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.13 A, density 1.75 g/cm3, surface area 4213.69 m2/g, accessible volume 0.17 cm3/g