CH2PbC14H10(NO2)2 crystallizes in the triclinic P1 space group. The structure consists of two 02329_fluka molecules inside a PbC14H10(NO2)2 framework. In the PbC14H10(NO2)2 framework, there are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to one N(3), one N(4), one O(1), one O(2), one O(7), and one O(8) atom. The Pb(1)-N(3) bond length is 2.50 Å. The Pb(1)-N(4) bond length is 2.50 Å. The Pb(1)-O(1) bond length is 2.71 Å. The Pb(1)-O(2) bond length is 2.71 Å. The Pb(1)-O(7) bond length is 2.49 Å. The Pb(1)-O(8) bond length is 2.49 Å. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(3), one O(4), one O(5), and one O(6) atom. The Pb(2)-N(1) bond length is 2.50 Å. The Pb(2)-N(2) bond length is 2.50 Å. The Pb(2)-O(3) bond length is 2.71 Å. The Pb(2)-O(4) bond length is 2.71 Å. The Pb(2)-O(5) bond length is 2.49 Å. The Pb(2)-O(6) bond length is 2.49 Å. There are twenty-two inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(1) atom. The C(1,2)-C(5) bond length is 1.39 Å. The C(1,2)-N(1) bond length is 1.34 Å. The C(1,2)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(7), one N(3), and one H(3) atom. The C(3)-C(7) bond length is 1.39 Å. The C(3)-N(3) bond length is 1.34 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(8), one N(4), and one H(4) atom. The C(4)-C(8) bond length is 1.39 Å. The C(4)-N(4) bond length is 1.34 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(1,2); one C(9,10,11); and one H(5,6,7,8) atom. The C(5)-C(9,10,11) bond length is 1.40 Å. The C(5)-H(5,6,7,8) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1,2); one C(9,10,11); and one H(5,6,7,8) atom. The C(6)-C(1,2) bond length is 1.39 Å. The C(6)-C(9,10,11) bond length is 1.40 Å. The C(6)-H(5,6,7,8) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(3); one C(9,10,11); and one H(5,6,7,8) atom. The C(7)-C(9,10,11) bond length is 1.40 Å. The C(7)-H(5,6,7,8) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(12); one C(4); and one H(5,6,7,8) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-H(5,6,7,8) bond length is 1.09 Å. In the eighth C site, C(9,10,11) is bonded in a trigonal planar geometry to one C(13); one C(25,26,27); and one C(5) atom. The C(9,10,11)-C(13) bond length is 1.40 Å. The C(9,10,11)-C(25,26,27) bond length is 1.50 Å. In the ninth C site, C(12) is bonded in a trigonal planar geometry to one C(16), one C(28), and one C(8) atom. The C(12)-C(16) bond length is 1.40 Å. The C(12)-C(28) bond length is 1.50 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(17,18); one C(9,10,11); and one H(9,10,11) atom. The C(13)-C(17,18) bond length is 1.39 Å. The C(13)-H(9,10,11) bond length is 1.09 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(17,18); one C(9,10,11); and one H(9,10,11) atom. The C(14)-C(17,18) bond length is 1.39 Å. The C(14)-C(9,10,11) bond length is 1.40 Å. The C(14)-H(9,10,11) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(19); one C(9,10,11); and one H(9,10,11) atom. The C(15)-C(19) bond length is 1.39 Å. The C(15)-C(9,10,11) bond length is 1.40 Å. The C(15)-H(9,10,11) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(12), one C(20), and one H(12) atom. The C(16)-C(20) bond length is 1.39 Å. The C(16)-H(12) bond length is 1.09 Å. In the fourteenth C site, C(17,18) is bonded in a distorted trigonal planar geometry to one C(13), one C(21), and one N(1) atom. The C(17,18)-C(21) bond length is 1.52 Å. The C(17,18)-N(1) bond length is 1.35 Å. In the fifteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(15), one C(23), and one N(3) atom. The C(19)-C(23) bond length is 1.52 Å. The C(19)-N(3) bond length is 1.35 Å. In the sixteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(16), one C(24), and one N(4) atom. The C(20)-C(24) bond length is 1.52 Å. The C(20)-N(4) bond length is 1.35 Å. In the seventeenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(17,18); one O(1); and one O(5) atom. The C(21)-O(1) bond length is 1.26 Å. The C(21)-O(5) bond length is 1.28 Å. In the eighteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(17,18); one O(2); and one O(6) atom. The C(22)-C(17,18) bond length is 1.52 Å. The C(22)-O(2) bond length is 1.26 Å. The C(22)-O(6) bond length is 1.28 Å. In the nineteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(3), and one O(7) atom. The C(23)-O(3) bond length is 1.26 Å. The C(23)-O(7) bond length is 1.28 Å. In the twentieth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(4), and one O(8) atom. The C(24)-O(4) bond length is 1.26 Å. The C(24)-O(8) bond length is 1.28 Å. In the twenty-first C site, C(25,26,27) is bonded in a distorted water-like geometry to one C(9,10,11); one H(13,14,15,16); and one H(17,18,19,20) atom. The C(25,26,27)-H(13,14,15,16) bond length is 1.10 Å. The C(25,26,27)-H(17,18,19,20) bond length is 1.10 Å. In the twenty-second C site, C(28) is bonded in a distorted water-like geometry to one C(12); one H(13,14,15,16); and one H(17,18,19,20) atom. The C(28)-H(13,14,15,16) bond length is 1.10 Å. The C(28)-H(17,18,19,20) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Pb(2); one C(1,2); and one C(17,18) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Pb(2); one C(1,2); and one C(17,18) atom. The N(2)-C(1,2) bond length is 1.34 Å. The N(2)-C(17,18) bond length is 1.35 Å. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one Pb(1), one C(19), and one C(3) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Pb(1), one C(20), and one C(4) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1,2) atom. The H(2)-C(1,2) bond length is 1.09 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5,6,7,8) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(9,10,11) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(13,14,15,16) is bonded in a single-bond geometry to one C(25,26,27) atom. In the ninth H site, H(17,18,19,20) is bonded in a single-bond geometry to one C(25,26,27) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Pb(1) and one C(21) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Pb(1) and one C(22) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Pb(2) and one C(23) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Pb(2) and one C(24) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Pb(2) and one C(21) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Pb(2) and one C(22) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Pb(1) and one C(23) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Pb(1) and one C(24) atom. Linkers: 2 [O]C(=O)c1cc(CCCc2ccnc(C([O])=O)c2)ccn1 ,2 [O]C(=O)c1cc(CCCc2ccnc(C([O])=O)c2)c[c]n1. Metal clusters: 2 [Pb]. The MOF has largest included sphere 2.49 A, density 2.17 g/cm3, surface area 3089.35 m2/g, accessible volume 0.08 cm3/g