In2C7H8O13CH2O crystallizes in the monoclinic P2_1 space group. The structure consists of two methanol molecules inside a In2C7H8O13 framework. In the In2C7H8O13 framework, there are two inequivalent In sites. In the first In site, In(1) is bonded to one O(1), one O(11), one O(14), one O(3), one O(5), one O(6), and one O(9) atom to form distorted edge-sharing InO7 pentagonal bipyramids. The In(1)-O(1) bond length is 2.42 Å. The In(1)-O(11) bond length is 2.21 Å. The In(1)-O(14) bond length is 2.17 Å. The In(1)-O(3) bond length is 2.32 Å. The In(1)-O(5) bond length is 2.28 Å. The In(1)-O(6) bond length is 2.28 Å. The In(1)-O(9) bond length is 2.19 Å. In the second In site, In(2) is bonded to one O(11), one O(13), one O(2), one O(4), one O(6), and one O(7) atom to form distorted edge-sharing InO6 octahedra. The In(2)-O(11) bond length is 2.18 Å. The In(2)-O(13) bond length is 2.18 Å. The In(2)-O(2) bond length is 2.25 Å. The In(2)-O(4) bond length is 2.18 Å. The In(2)-O(6) bond length is 2.15 Å. The In(2)-O(7) bond length is 2.19 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(1)-O(3) bond length is 1.27 Å. The C(1)-O(4) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one H(7) and one O(5) atom. The C(2)-H(7) bond length is 1.10 Å. The C(2)-O(5) bond length is 1.43 Å. In the third C site, C(3) is bonded in a distorted water-like geometry to one H(8) and one O(6) atom. The C(3)-H(8) bond length is 1.11 Å. The C(3)-O(6) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(4)-O(7) bond length is 1.28 Å. The C(4)-O(8) bond length is 1.26 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(5)-O(10) bond length is 1.27 Å. The C(5)-O(9) bond length is 1.27 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one H(9) and one O(11) atom. The C(6)-H(9) bond length is 1.11 Å. The C(6)-O(11) bond length is 1.40 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(14) atom. The C(8)-O(13) bond length is 1.28 Å. The C(8)-O(14) bond length is 1.27 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. The H(3)-O(2) bond length is 1.00 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.98 Å. In the fifth H site, H(5) is bonded in a linear geometry to one O(5) and one O(8) atom. The H(5)-O(5) bond length is 1.06 Å. The H(5)-O(8) bond length is 1.47 Å. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one In(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one In(2), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one In(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one In(2) and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one In(1), one C(2), and one H(5) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one In(1), one In(2), and one C(3) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one In(2) and one C(4) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one C(4) and one H(5) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one In(1) and one C(5) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one C(5) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one In(1), one In(2), and one C(6) atom. In the twelfth O site, O(13) is bonded in a bent 120 degrees geometry to one In(2) and one C(8) atom. In the thirteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one In(1) and one C(8) atom. Linkers: 3 [O]C(=O)[C@H]([O])[C@@H](O)C([O])=O. Metal clusters: 4 [In]. The MOF has largest included sphere 2.10 A, density 2.68 g/cm3, surface area 2294.65 m2/g, accessible volume 0.06 cm3/g