MnC6H6(N5O)2(CH3)2 crystallizes in the triclinic P1 space group. The structure consists of four 02329_fluka molecules inside a MnC6H6(N5O)2 framework. In the MnC6H6(N5O)2 framework, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in an octahedral geometry to one N(1), one N(11), one N(20), one N(8), one O(1), and one O(3) atom. The Mn(1)-N(1) bond length is 2.18 Å. The Mn(1)-N(11) bond length is 2.18 Å. The Mn(1)-N(20) bond length is 2.27 Å. The Mn(1)-N(8) bond length is 2.23 Å. The Mn(1)-O(1) bond length is 2.26 Å. The Mn(1)-O(3) bond length is 2.23 Å. In the second Mn site, Mn(2) is bonded in an octahedral geometry to one N(12), one N(19), one N(2), one N(7), one O(2), and one O(4) atom. The Mn(2)-N(12) bond length is 2.18 Å. The Mn(2)-N(19) bond length is 2.27 Å. The Mn(2)-N(2) bond length is 2.18 Å. The Mn(2)-N(7) bond length is 2.23 Å. The Mn(2)-O(2) bond length is 2.26 Å. The Mn(2)-O(4) bond length is 2.23 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(7), and one N(9) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(7) bond length is 1.35 Å. The C(1)-N(9) bond length is 1.37 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(10), one N(2), and one N(8) atom. The C(2)-N(10) bond length is 1.37 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-N(8) bond length is 1.35 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(5,6); one N(9); and one O(3) atom. The C(3)-C(5,6) bond length is 1.50 Å. The C(3)-N(9) bond length is 1.36 Å. The C(3)-O(3) bond length is 1.25 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5,6); one N(10); and one O(4) atom. The C(4)-C(5,6) bond length is 1.50 Å. The C(4)-N(10) bond length is 1.36 Å. The C(4)-O(4) bond length is 1.25 Å. In the fifth C site, C(5,6) is bonded in a distorted water-like geometry to one C(3); one H(5,6); and one H(7,8) atom. The C(5,6)-H(5,6) bond length is 1.10 Å. The C(5,6)-H(7,8) bond length is 1.10 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one N(11), one N(15), and one N(19) atom. The C(9)-N(11) bond length is 1.34 Å. The C(9)-N(15) bond length is 1.37 Å. The C(9)-N(19) bond length is 1.35 Å. In the seventh C site, C(10) is bonded in a trigonal planar geometry to one N(12), one N(16), and one N(20) atom. The C(10)-N(12) bond length is 1.34 Å. The C(10)-N(16) bond length is 1.37 Å. The C(10)-N(20) bond length is 1.35 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(13), one N(15), and one O(1) atom. The C(11)-C(13) bond length is 1.51 Å. The C(11)-N(15) bond length is 1.36 Å. The C(11)-O(1) bond length is 1.25 Å. In the ninth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14), one N(16), and one O(2) atom. The C(12)-C(14) bond length is 1.51 Å. The C(12)-N(16) bond length is 1.36 Å. The C(12)-O(2) bond length is 1.25 Å. In the tenth C site, C(13) is bonded in a distorted water-like geometry to one C(11); one H(15,16); and one H(17,18) atom. The C(13)-H(15,16) bond length is 1.10 Å. The C(13)-H(17,18) bond length is 1.10 Å. In the eleventh C site, C(14) is bonded in a distorted water-like geometry to one C(12); one H(15,16); and one H(17,18) atom. The C(14)-H(15,16) bond length is 1.10 Å. The C(14)-H(17,18) bond length is 1.10 Å. There are twenty inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(1), and one N(3) atom. The N(1)-N(3) bond length is 1.35 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Mn(2), one C(2), and one N(4) atom. The N(2)-N(4) bond length is 1.35 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one N(1), one N(5), and one H(4) atom. The N(3)-N(5) bond length is 1.30 Å. The N(3)-H(4) bond length is 1.72 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one N(2), one N(6), and one H(3) atom. The N(4)-N(6) bond length is 1.30 Å. The N(4)-H(3) bond length is 1.72 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one N(3) and one N(7) atom. The N(5)-N(7) bond length is 1.35 Å. In the sixth N site, N(6) is bonded in a water-like geometry to one N(4) and one N(8) atom. The N(6)-N(8) bond length is 1.35 Å. In the seventh N site, N(7) is bonded in a 3-coordinate geometry to one Mn(2), one C(1), and one N(5) atom. In the eighth N site, N(8) is bonded in a 3-coordinate geometry to one Mn(1), one C(2), and one N(6) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The N(9)-H(1) bond length is 1.06 Å. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one C(2), one C(4), and one H(2) atom. The N(10)-H(2) bond length is 1.06 Å. In the eleventh N site, N(11) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(9), and one N(13) atom. The N(11)-N(13) bond length is 1.35 Å. In the twelfth N site, N(12) is bonded in a distorted trigonal planar geometry to one Mn(2), one C(10), and one N(14) atom. The N(12)-N(14) bond length is 1.35 Å. In the thirteenth N site, N(13) is bonded in a distorted trigonal planar geometry to one N(11), one N(17), and one H(2) atom. The N(13)-N(17) bond length is 1.30 Å. The N(13)-H(2) bond length is 1.72 Å. In the fourteenth N site, N(14) is bonded in a distorted trigonal planar geometry to one N(12), one N(18), and one H(1) atom. The N(14)-N(18) bond length is 1.30 Å. The N(14)-H(1) bond length is 1.72 Å. In the fifteenth N site, N(15) is bonded in a trigonal planar geometry to one C(11), one C(9), and one H(3) atom. The N(15)-H(3) bond length is 1.05 Å. In the sixteenth N site, N(16) is bonded in a trigonal planar geometry to one C(10), one C(12), and one H(4) atom. The N(16)-H(4) bond length is 1.05 Å. In the seventeenth N site, N(17) is bonded in a water-like geometry to one N(13) and one N(19) atom. The N(17)-N(19) bond length is 1.36 Å. In the eighteenth N site, N(18) is bonded in a water-like geometry to one N(14) and one N(20) atom. The N(18)-N(20) bond length is 1.36 Å. In the nineteenth N site, N(19) is bonded in a 3-coordinate geometry to one Mn(2), one C(9), and one N(17) atom. In the twentieth N site, N(20) is bonded in a 3-coordinate geometry to one Mn(1), one C(10), and one N(18) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one N(14) and one N(9) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one N(10) and one N(13) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one N(15) and one N(4) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one N(16) and one N(3) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(5,6) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(5,6) atom. In the seventh H site, H(15,16) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(17,18) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(11) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(12) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(4) atom. Linkers: 4 CCC(=O)NC1=NN=N[N]1. Metal clusters: 2 [Mn]. The MOF has largest included sphere 2.16 A, density 1.68 g/cm3, surface area 4363.66 m2/g, accessible volume 0.13 cm3/g