CoC3N8H3CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a CoC3N8H3 framework. In the CoC3N8H3 framework, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent N(6) atoms. Both Co(1)-N(1) bond lengths are 1.96 Å. Both Co(1)-N(3) bond lengths are 1.98 Å. Both Co(1)-N(6) bond lengths are 2.00 Å. In the second Co site, Co(2) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(4), and two equivalent N(7) atoms. Both Co(2)-N(2) bond lengths are 2.10 Å. Both Co(2)-N(4) bond lengths are 2.06 Å. Both Co(2)-N(7) bond lengths are 2.08 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one N(2) and one H(3) atom. The C(3)-N(2) bond length is 1.35 Å. The C(3)-H(3) bond length is 1.09 Å. There are eight inequivalent N sites. In the first N site, N(8) is bonded in a linear geometry to one N(6) and one N(7) atom. The N(8)-N(6) bond length is 1.20 Å. The N(8)-N(7) bond length is 1.18 Å. In the second N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(2) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one Co(2), one C(1), and one C(3) atom. In the fourth N site, N(3) is bonded in a bent 120 degrees geometry to one Co(1) and one N(5) atom. The N(3)-N(5) bond length is 1.19 Å. In the fifth N site, N(4) is bonded in a bent 120 degrees geometry to one Co(2) and one N(5) atom. The N(4)-N(5) bond length is 1.18 Å. In the sixth N site, N(5) is bonded in a linear geometry to one N(3) and one N(4) atom. In the seventh N site, N(6) is bonded in a bent 120 degrees geometry to one Co(1) and one N(8) atom. In the eighth N site, N(7) is bonded in a bent 120 degrees geometry to one Co(2) and one N(8) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. Linkers: 2 c1cncnc1. Metal clusters: 2 [Co]. The MOF has largest included sphere 1.67 A, density 2.09 g/cm3, surface area 3114.81 m2/g, accessible volume 0.08 cm3/g