CdC14N2H7O5(CH)4 crystallizes in the monoclinic P2_1/c space group. The structure consists of sixteen 02329_fluka molecules inside a CdC14N2H7O5 framework. In the CdC14N2H7O5 framework, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.31 Å. The Cd(1)-N(2) bond length is 2.26 Å. The Cd(1)-O(1) bond length is 2.42 Å. The Cd(1)-O(2) bond length is 2.39 Å. The Cd(1)-O(3) bond length is 2.34 Å. The Cd(1)-O(4) bond length is 2.59 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.41 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one O(5) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-O(5) bond length is 1.40 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(8) atom. The C(7)-C(8) bond length is 1.51 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.29 Å. The C(8)-O(4) bond length is 1.26 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(13) and one O(5) atom. The C(9)-C(13) bond length is 1.40 Å. The C(9)-O(5) bond length is 1.37 Å. In the eighth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(12)-N(1) bond length is 1.35 Å. The C(12)-H(6) bond length is 1.09 Å. In the ninth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(7) atom. The C(13)-N(1) bond length is 1.34 Å. The C(13)-H(7) bond length is 1.09 Å. In the tenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(15), one N(2), and one H(8) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-N(2) bond length is 1.35 Å. The C(14)-H(8) bond length is 1.09 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(9) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(9) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(17) atom. The C(16)-C(16) bond length is 1.48 Å. The C(16)-C(17) bond length is 1.40 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(10) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one N(2), and one H(11) atom. The C(18)-N(2) bond length is 1.35 Å. The C(18)-H(11) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(12), and one C(13) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(14), and one C(18) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(18) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cd(1) and one C(8) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(6) and one C(9) atom. Linkers: 4 [O]C(=O)c1cccc(Oc2cccnc2)c1C([O])=O ,2 c1cc(-c2ccncc2)ccn1. Metal clusters: 4 O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 2.22 A, density 1.85 g/cm3, surface area 3703.43 m2/g, accessible volume 0.14 cm3/g