CdC17N2H11O5(CH)4C2O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two dimethyl ether molecules, and one CdC17N2H11O5 cluster. In the CdC17N2H11O5 cluster, Cd(1) is bonded in a distorted pentagonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(2), one O(3), one O(4), and one O(5) atom. The Cd(1)-N(1) bond length is 2.35 Å. The Cd(1)-N(2) bond length is 2.42 Å. The Cd(1)-O(1) bond length is 2.33 Å. The Cd(1)-O(2) bond length is 2.32 Å. The Cd(1)-O(3) bond length is 2.62 Å. The Cd(1)-O(4) bond length is 2.56 Å. The Cd(1)-O(5) bond length is 2.49 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(3) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(3) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(4) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-H(4) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(5) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(5) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(12) bond length is 1.42 Å. The C(4)-C(5) bond length is 1.43 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(5)-H(6) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(6)-C(7) bond length is 1.43 Å. The C(6)-H(7) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.42 Å. The C(7)-C(8) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(8) atom. The C(8)-H(8) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(10) atom. The C(10)-N(1) bond length is 1.33 Å. The C(10)-H(10) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(7), and one N(1) atom. The C(11)-C(12) bond length is 1.44 Å. The C(11)-N(1) bond length is 1.36 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(4), and one N(2) atom. The C(12)-N(2) bond length is 1.35 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(2), and one O(3) atom. The C(13)-C(14) bond length is 1.50 Å. The C(13)-O(2) bond length is 1.29 Å. The C(13)-O(3) bond length is 1.26 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-C(19) bond length is 1.40 Å. In the fourteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(20) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(20) bond length is 1.51 Å. In the fifteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(11) atom. The C(16)-H(11) bond length is 1.09 Å. In the sixteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(13) atom. The C(19)-H(13) bond length is 1.09 Å. In the seventeenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(4), and one O(5) atom. The C(20)-O(4) bond length is 1.28 Å. The C(20)-O(5) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(11) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(12) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(19) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cd(1) and one C(13) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(13) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(20) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one C(20) atom. Linkers: 2 [O]C(=O)c1[c]ccc(Oc2ccc(Oc3ccc(C([O])=O)c(C([O])=O)c3)cc2)c1 ,2 [O]C(=O)c1[c][c]c(Oc2ccc(Oc3ccc(C([O])=O)c(C([O])=O)c3)cc2)cc1C([O])=O ,1 [O]C(=O)c1ccc(Oc2ccc(Oc3ccc(C([O])=O)c(C([O])=O)c3)cc2)cc1C([O])=O. Metal clusters: 2 O.O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 4.79 A, density 1.51 g/cm3, surface area 3687.72 m2/g, accessible volume 0.24 cm3/g