ZnC14H18(NO)4(CH2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and two ZnC14H18(NO)4 clusters. In each ZnC14H18(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(2), one N(3), one O(2), and one O(3) atom. The Zn(1)-N(2) bond length is 2.01 Å. The Zn(1)-N(3) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 1.97 Å. The Zn(1)-O(3) bond length is 1.97 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one C(16), one C(17), one C(2), and one C(8) atom. The C(1)-C(16) bond length is 1.54 Å. The C(1)-C(17) bond length is 1.53 Å. The C(1)-C(2) bond length is 1.54 Å. The C(1)-C(8) bond length is 1.55 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(2)-O(1) bond length is 1.25 Å. The C(2)-O(2) bond length is 1.30 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. The C(4)-N(1) bond length is 1.35 Å. The C(4)-N(2) bond length is 1.33 Å. The C(4)-H(3) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(5)-O(3) bond length is 1.30 Å. The C(5)-O(4) bond length is 1.25 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(3), and one H(4) atom. The C(6)-C(13) bond length is 1.38 Å. The C(6)-N(3) bond length is 1.38 Å. The C(6)-H(4) bond length is 1.08 Å. In the sixth C site, C(8) is bonded in a distorted water-like geometry to one C(1), one H(7), and one H(8) atom. The C(8)-H(7) bond length is 1.10 Å. The C(8)-H(8) bond length is 1.10 Å. In the seventh C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(10), and one H(9) atom. The C(9)-N(1) bond length is 1.46 Å. The C(9)-H(10) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. In the eighth C site, C(11) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(13) atom. The C(11)-N(3) bond length is 1.33 Å. The C(11)-N(4) bond length is 1.35 Å. The C(11)-H(13) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(14), and one H(15) atom. The C(12)-N(4) bond length is 1.46 Å. The C(12)-H(14) bond length is 1.10 Å. The C(12)-H(15) bond length is 1.10 Å. In the tenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(4), and one H(16) atom. The C(13)-N(4) bond length is 1.38 Å. The C(13)-H(16) bond length is 1.08 Å. In the eleventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(1), and one H(17) atom. The C(14)-C(15) bond length is 1.37 Å. The C(14)-N(1) bond length is 1.38 Å. The C(14)-H(17) bond length is 1.08 Å. In the twelfth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(2), and one H(18) atom. The C(15)-N(2) bond length is 1.38 Å. The C(15)-H(18) bond length is 1.08 Å. In the thirteenth C site, C(16) is bonded in a trigonal non-coplanar geometry to one C(1), one H(19), one H(20), and one H(21) atom. The C(16)-H(19) bond length is 1.10 Å. The C(16)-H(20) bond length is 1.10 Å. The C(16)-H(21) bond length is 1.10 Å. In the fourteenth C site, C(17) is bonded in a trigonal non-coplanar geometry to one C(1), one H(22), one H(23), and one H(24) atom. The C(17)-H(22) bond length is 1.10 Å. The C(17)-H(23) bond length is 1.10 Å. The C(17)-H(24) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(14), one C(4), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(13) atom. There are eighteen inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(16) atom. In the sixteenth H site, H(22) is bonded in a single-bond geometry to one C(17) atom. In the seventeenth H site, H(23) is bonded in a single-bond geometry to one C(17) atom. In the eighteenth H site, H(24) is bonded in a single-bond geometry to one C(17) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(5) atom. Linkers: 2 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.26 A, density 1.35 g/cm3, surface area 5303.46 m2/g, accessible volume 0.15 cm3/g