ZnC8H8S4(N3O2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC8H8S4(N3O2)2 clusters. Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(4), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-N(4) bond length is 2.00 Å. The Zn(1)-O(1) bond length is 1.99 Å. The Zn(1)-O(3) bond length is 2.02 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1), one N(3), and one S(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(3) bond length is 1.35 Å. The C(1)-S(1) bond length is 1.74 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2), one S(1), and one S(2) atom. The C(2)-N(2) bond length is 1.30 Å. The C(2)-S(1) bond length is 1.77 Å. The C(2)-S(2) bond length is 1.73 Å. In the third C site, C(3) is bonded in a water-like geometry to one H(1), one H(2), and one S(2) atom. The C(3)-H(1) bond length is 1.10 Å. The C(3)-H(2) bond length is 1.10 Å. The C(3)-S(2) bond length is 1.80 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(4)-O(1) bond length is 1.29 Å. The C(4)-O(2) bond length is 1.25 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(4), one N(6), and one S(3) atom. The C(5)-N(4) bond length is 1.34 Å. The C(5)-N(6) bond length is 1.33 Å. The C(5)-S(3) bond length is 1.75 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one N(5), one S(3), and one S(4) atom. The C(6)-N(5) bond length is 1.31 Å. The C(6)-S(3) bond length is 1.75 Å. The C(6)-S(4) bond length is 1.74 Å. In the seventh C site, C(7) is bonded in a distorted water-like geometry to two equivalent H(3,4) and one S(4) atom. There is one shorter (1.09 Å) and one longer (1.10 Å) C(7)-H(3,4) bond length. The C(7)-S(4) bond length is 1.82 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.29 Å. The C(8)-O(4) bond length is 1.25 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.37 Å. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(2) and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one H(5), and one H(6) atom. The N(3)-H(5) bond length is 1.04 Å. The N(3)-H(6) bond length is 1.01 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(5), and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a distorted single-bond geometry to one C(6) and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(5), one H(7), and one H(8) atom. The N(6)-H(7) bond length is 1.02 Å. The N(6)-H(8) bond length is 1.02 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one N(6) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one N(6) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(1) and one C(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(2) and one C(3) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one C(5) and one C(6) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one C(6) and one C(7) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(8) atom. Linkers: 2 Nc1nnc(SCC([O])=O)s1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 3.43 A, density 1.92 g/cm3, surface area 3837.67 m2/g, accessible volume 0.15 cm3/g