CdC16H14(NO)4(CH)2(C3H2)2(CH2CO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; four 2,3-dimethyl-1,3-butadiene molecules; eight dimethyl ether molecules; and four CdC16H14(NO)4 clusters. In each CdC16H14(NO)4 cluster, Cd(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(4), one O(3), one O(4), and one O(5) atom. The Cd(1)-N(1) bond length is 2.27 Å. The Cd(1)-N(4) bond length is 2.30 Å. The Cd(1)-O(3) bond length is 2.42 Å. The Cd(1)-O(4) bond length is 2.37 Å. The Cd(1)-O(5) bond length is 2.20 Å. There are sixteen inequivalent C sites. In the first C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(16), and one H(17) atom. The C(17)-N(3) bond length is 1.46 Å. The C(17)-H(16) bond length is 1.10 Å. The C(17)-H(17) bond length is 1.10 Å. In the second C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(18) atom. The C(18)-N(3) bond length is 1.38 Å. The C(18)-H(18) bond length is 1.08 Å. In the third C site, C(19) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(19) atom. The C(19)-N(3) bond length is 1.36 Å. The C(19)-N(4) bond length is 1.33 Å. The C(19)-H(19) bond length is 1.08 Å. In the fourth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(20) atom. The C(20)-N(4) bond length is 1.38 Å. The C(20)-H(20) bond length is 1.08 Å. In the fifth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(3), and one O(4) atom. The C(21)-C(22) bond length is 1.50 Å. The C(21)-O(3) bond length is 1.28 Å. The C(21)-O(4) bond length is 1.28 Å. In the sixth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(24) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(24) bond length is 1.40 Å. In the seventh C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(21) atom. The C(23)-H(21) bond length is 1.09 Å. In the eighth C site, C(24) is bonded in a distorted single-bond geometry to one C(22) and one H(22) atom. The C(24)-H(22) bond length is 1.09 Å. In the ninth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(5), and one O(6) atom. The C(25)-C(26) bond length is 1.50 Å. The C(25)-O(5) bond length is 1.29 Å. The C(25)-O(6) bond length is 1.26 Å. In the tenth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(28) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-C(28) bond length is 1.40 Å. In the eleventh C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(23) atom. The C(27)-H(23) bond length is 1.09 Å. In the twelfth C site, C(28) is bonded in a distorted single-bond geometry to one C(26) and one H(24) atom. The C(28)-H(24) bond length is 1.09 Å. In the thirteenth C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.08 Å. In the fourteenth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(1) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the fifteenth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.38 Å. The C(3)-H(3) bond length is 1.08 Å. In the sixteenth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(4), and one H(5) atom. The C(4)-N(2) bond length is 1.46 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(19) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(19), and one C(20) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(24) atom. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one C(27) atom. In the fourteenth H site, H(24) is bonded in a single-bond geometry to one C(28) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(21) atom. In the second O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(21) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(25) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(25) atom. Linkers: 2 c1cn(CCOc2ccc3ccc(OCCn4ccnc4)cc3c2)cn1 ,2 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 4.88 A, density 1.30 g/cm3, surface area 4683.07 m2/g, accessible volume 0.29 cm3/g