CHZnC6H11S(NO4)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a ZnC6H11S(NO4)2 framework. In the ZnC6H11S(NO4)2 framework, Zn(1) is bonded to one N(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form ZnNO5 octahedra that share corners with two equivalent S(1)O4 tetrahedra. The Zn(1)-N(1) bond length is 2.11 Å. The Zn(1)-O(2) bond length is 2.11 Å. The Zn(1)-O(3) bond length is 2.30 Å. The Zn(1)-O(4) bond length is 2.06 Å. The Zn(1)-O(5) bond length is 2.05 Å. The Zn(1)-O(6) bond length is 2.20 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.47 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-C(7) bond length is 1.40 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(2), and one O(2) atom. The C(2)-N(2) bond length is 1.35 Å. The C(2)-O(2) bond length is 1.26 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(5), one C(6), and one H(5) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.39 Å. The C(3)-H(5) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one O(1) atom. The C(5)-O(1) bond length is 1.36 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(7) atom. The C(6)-H(7) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(1) and one H(8) atom. The C(7)-H(8) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one Zn(1), one N(2), one H(2), and one H(3) atom. The N(1)-N(2) bond length is 1.41 Å. The N(1)-H(2) bond length is 1.03 Å. The N(1)-H(3) bond length is 1.03 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one C(2), one N(1), and one H(4) atom. The N(2)-H(4) bond length is 1.03 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) and one O(7) atom. The H(1)-O(1) bond length is 1.01 Å. The H(1)-O(7) bond length is 1.72 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one O(4) atom. The H(9)-O(4) bond length is 0.99 Å. In the ninth H site, H(10) is bonded in a distorted single-bond geometry to one O(4) and one O(6) atom. The H(10)-O(4) bond length is 1.00 Å. The H(10)-O(6) bond length is 1.69 Å. In the tenth H site, H(11) is bonded in a single-bond geometry to one O(5) atom. The H(11)-O(5) bond length is 1.00 Å. In the eleventh H site, H(12) is bonded in a distorted single-bond geometry to one O(5) and one O(8) atom. The H(12)-O(5) bond length is 1.01 Å. The H(12)-O(8) bond length is 1.63 Å. S(1) is bonded to one O(3), one O(6), one O(7), and one O(8) atom to form SO4 tetrahedra that share corners with two equivalent Zn(1)NO5 octahedra. The corner-sharing octahedral tilt angles range from 33-56°. The S(1)-O(3) bond length is 1.47 Å. The S(1)-O(6) bond length is 1.52 Å. The S(1)-O(7) bond length is 1.49 Å. The S(1)-O(8) bond length is 1.50 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one C(5) and one H(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Zn(1), one H(10), and one H(9) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Zn(1), one H(11), and one H(12) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Zn(1), one H(10), and one S(1) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one H(1) and one S(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one H(12) and one S(1) atom. Linkers: 2 NNC(=O)c1ccc(O)cc1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 1.68 A, density 2.05 g/cm3, surface area 3642.96 m2/g, accessible volume 0.08 cm3/g