CuC8H8(NO)4(CH2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CuC8H8(NO)4 clusters. In each CuC8H8(NO)4 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 1.97 Å. Both Cu(1)-O(1) bond lengths are 1.98 Å. There are four inequivalent C sites. In the first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(3) atom. The C(3)-N(2) bond length is 1.35 Å. The C(3)-H(3) bond length is 1.08 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(4)-O(1) bond length is 1.30 Å. The C(4)-O(2) bond length is 1.26 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.08 Å. In the fourth C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.35 Å. In the second N site, N(2) is bonded in a 2-coordinate geometry to one C(3), one N(1), and one H(6) atom. The N(2)-H(6) bond length is 1.04 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one C(4) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(4) atom. Linkers: 2 [O]C(=O)CCC([O])=O. Metal clusters: 2 [Cu]. The MOF has largest included sphere 1.72 A, density 1.75 g/cm3, surface area 4500.20 m2/g, accessible volume 0.15 cm3/g