(CH)2ZnC9H8S(NO)4 crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of eight 02329_fluka molecules inside a ZnC9H8S(NO)4 framework. In the ZnC9H8S(NO)4 framework, Zn(1) is bonded to one N(1), one N(3), one O(1), and one O(2) atom to form ZnN2O2 tetrahedra that share corners with two equivalent S(1)O4 tetrahedra. The Zn(1)-N(1) bond length is 2.00 Å. The Zn(1)-N(3) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(2) bond length is 1.98 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(2) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(3) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(1) bond length is 1.38 Å. The C(2)-H(3) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(4) atom. The C(3)-N(2) bond length is 1.38 Å. The C(3)-H(4) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one N(2), one H(5), and one H(6) atom. The C(4)-C(5) bond length is 1.50 Å. The C(4)-N(2) bond length is 1.46 Å. The C(4)-H(5) bond length is 1.10 Å. The C(4)-H(6) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(3), and one N(4) atom. The C(5)-N(3) bond length is 1.34 Å. The C(5)-N(4) bond length is 1.35 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(11), one C(7), and one N(3) atom. The C(6)-C(11) bond length is 1.42 Å. The C(6)-C(7) bond length is 1.40 Å. The C(6)-N(3) bond length is 1.39 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(7) atom. The C(7)-H(7) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(10) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(10) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(6), and one N(4) atom. The C(11)-N(4) bond length is 1.38 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(5), and one C(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(11), one C(5), and one H(1) atom. The N(4)-H(1) bond length is 1.06 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one N(4) and one O(3) atom. The H(1)-O(3) bond length is 1.64 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with two equivalent Zn(1)N2O2 tetrahedra. The S(1)-O(1) bond length is 1.52 Å. The S(1)-O(2) bond length is 1.52 Å. The S(1)-O(3) bond length is 1.48 Å. The S(1)-O(4) bond length is 1.46 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one H(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. Linkers: 4 c1ccc2[nH]c(Cn3ccnc3)nc2c1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 3.11 A, density 1.80 g/cm3, surface area 4037.39 m2/g, accessible volume 0.16 cm3/g