Co2C36N2H26O11(CH)2 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a Co2C36N2H26O11 framework. In the Co2C36N2H26O11 framework, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(1), one O(1), one O(11), one O(4), one O(5), and one O(9) atom to form distorted corner-sharing CoNO5 octahedra. The corner-sharing octahedral tilt angles are 69°. The Co(1)-N(1) bond length is 2.08 Å. The Co(1)-O(1) bond length is 2.08 Å. The Co(1)-O(11) bond length is 2.12 Å. The Co(1)-O(4) bond length is 2.09 Å. The Co(1)-O(5) bond length is 2.01 Å. The Co(1)-O(9) bond length is 2.30 Å. In the second Co site, Co(2) is bonded to one N(2), one O(10), one O(11), one O(2), one O(3), and one O(6) atom to form distorted corner-sharing CoNO5 octahedra. The corner-sharing octahedral tilt angles are 69°. The Co(2)-N(2) bond length is 2.08 Å. The Co(2)-O(10) bond length is 2.30 Å. The Co(2)-O(11) bond length is 2.12 Å. The Co(2)-O(2) bond length is 2.07 Å. The Co(2)-O(3) bond length is 2.09 Å. The Co(2)-O(6) bond length is 2.01 Å. There are thirty-one inequivalent C sites. In the first C site, C(35) is bonded in a distorted single-bond geometry to one C(25), one C(33), and one H(27) atom. The C(35)-C(25) bond length is 1.40 Å. The C(35)-C(33) bond length is 1.40 Å. The C(35)-H(27) bond length is 1.09 Å. In the second C site, C(36) is bonded in a distorted single-bond geometry to one C(26), one C(34), and one H(28) atom. The C(36)-C(26) bond length is 1.40 Å. The C(36)-C(34) bond length is 1.40 Å. The C(36)-H(28) bond length is 1.09 Å. In the third C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(33); one O(5); and one O(7,8) atom. The C(37)-C(33) bond length is 1.50 Å. The C(37)-O(5) bond length is 1.29 Å. The C(37)-O(7,8) bond length is 1.27 Å. In the fourth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(34); one O(6); and one O(7,8) atom. The C(38)-C(34) bond length is 1.50 Å. The C(38)-O(6) bond length is 1.29 Å. The C(38)-O(7,8) bond length is 1.27 Å. In the fifth C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1,2)-C(3) bond length is 1.50 Å. The C(1,2)-O(1) bond length is 1.27 Å. The C(1,2)-O(3) bond length is 1.28 Å. In the sixth C site, C(3) is bonded in a trigonal planar geometry to one C(1,2); one C(13,14); and one C(5,6) atom. The C(3)-C(13,14) bond length is 1.40 Å. The C(3)-C(5,6) bond length is 1.40 Å. In the seventh C site, C(4) is bonded in a trigonal planar geometry to one C(1,2); one C(13,14); and one C(5,6) atom. The C(4)-C(1,2) bond length is 1.50 Å. The C(4)-C(13,14) bond length is 1.40 Å. The C(4)-C(5,6) bond length is 1.40 Å. In the eighth C site, C(5,6) is bonded in a distorted single-bond geometry to one C(3); one C(7); and one H(7,8) atom. The C(5,6)-C(7) bond length is 1.40 Å. The C(5,6)-H(7,8) bond length is 1.09 Å. In the ninth C site, C(7) is bonded in a trigonal planar geometry to one C(15); one C(5,6); and one C(9,10) atom. The C(7)-C(15) bond length is 1.47 Å. The C(7)-C(9,10) bond length is 1.41 Å. In the tenth C site, C(8) is bonded in a trigonal planar geometry to one C(16); one C(5,6); and one C(9,10) atom. The C(8)-C(16) bond length is 1.47 Å. The C(8)-C(5,6) bond length is 1.40 Å. The C(8)-C(9,10) bond length is 1.41 Å. In the eleventh C site, C(9,10) is bonded in a distorted single-bond geometry to one C(11,12); one C(7); and one H(9,10) atom. The C(9,10)-C(11,12) bond length is 1.39 Å. The C(9,10)-H(9,10) bond length is 1.09 Å. In the twelfth C site, C(11,12) is bonded in a distorted single-bond geometry to one C(13,14); one C(9,10); and one H(11,12) atom. The C(11,12)-C(13,14) bond length is 1.39 Å. The C(11,12)-H(11,12) bond length is 1.09 Å. In the thirteenth C site, C(13,14) is bonded in a distorted single-bond geometry to one C(11,12); one C(3); and one H(13,14) atom. The C(13,14)-H(13,14) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a trigonal planar geometry to one C(17), one C(23), and one C(7) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-C(23) bond length is 1.40 Å. In the fifteenth C site, C(16) is bonded in a trigonal planar geometry to one C(18), one C(24), and one C(8) atom. The C(16)-C(18) bond length is 1.40 Å. The C(16)-C(24) bond length is 1.40 Å. In the sixteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(15); one N(1); and one H(15,16) atom. The C(17)-N(1) bond length is 1.34 Å. The C(17)-H(15,16) bond length is 1.09 Å. In the seventeenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(16); one N(2); and one H(15,16) atom. The C(18)-N(2) bond length is 1.34 Å. The C(18)-H(15,16) bond length is 1.09 Å. In the eighteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(21), one N(1), and one H(17) atom. The C(19)-C(21) bond length is 1.40 Å. The C(19)-N(1) bond length is 1.34 Å. The C(19)-H(17) bond length is 1.09 Å. In the nineteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(22), one N(2), and one H(18) atom. The C(20)-C(22) bond length is 1.40 Å. The C(20)-N(2) bond length is 1.34 Å. The C(20)-H(18) bond length is 1.09 Å. In the twentieth C site, C(21) is bonded in a trigonal planar geometry to one C(19), one C(23), and one C(25) atom. The C(21)-C(23) bond length is 1.40 Å. The C(21)-C(25) bond length is 1.48 Å. In the twenty-first C site, C(22) is bonded in a trigonal planar geometry to one C(20), one C(24), and one C(26) atom. The C(22)-C(24) bond length is 1.40 Å. The C(22)-C(26) bond length is 1.48 Å. In the twenty-second C site, C(23) is bonded in a distorted trigonal planar geometry to one C(15), one C(21), and one H(19) atom. The C(23)-H(19) bond length is 1.09 Å. In the twenty-third C site, C(24) is bonded in a distorted trigonal planar geometry to one C(16), one C(22), and one H(20) atom. The C(24)-H(20) bond length is 1.09 Å. In the twenty-fourth C site, C(25) is bonded in a trigonal planar geometry to one C(21), one C(27), and one C(35) atom. The C(25)-C(27) bond length is 1.41 Å. In the twenty-fifth C site, C(26) is bonded in a trigonal planar geometry to one C(22), one C(28), and one C(36) atom. The C(26)-C(28) bond length is 1.41 Å. In the twenty-sixth C site, C(27) is bonded in a distorted single-bond geometry to one C(25) and one H(21) atom. The C(27)-H(21) bond length is 1.09 Å. In the twenty-seventh C site, C(28) is bonded in a distorted single-bond geometry to one C(26) and one H(22) atom. The C(28)-H(22) bond length is 1.09 Å. In the twenty-eighth C site, C(31) is bonded in a distorted single-bond geometry to one C(33) and one H(25,26) atom. The C(31)-C(33) bond length is 1.40 Å. The C(31)-H(25,26) bond length is 1.09 Å. In the twenty-ninth C site, C(32) is bonded in a distorted single-bond geometry to one C(34) and one H(25,26) atom. The C(32)-C(34) bond length is 1.40 Å. The C(32)-H(25,26) bond length is 1.09 Å. In the thirtieth C site, C(33) is bonded in a trigonal planar geometry to one C(31), one C(35), and one C(37) atom. In the thirty-first C site, C(34) is bonded in a trigonal planar geometry to one C(32), one C(36), and one C(38) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(17), and one C(19) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(2), one C(18), and one C(20) atom. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(9) atom. The H(1)-O(9) bond length is 0.97 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. The H(2)-O(10) bond length is 0.97 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(9) atom. The H(3)-O(9) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(10) atom. The H(4)-O(10) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one O(11) and one O(7,8) atom. The H(5)-O(11) bond length is 1.04 Å. The H(5)-O(7,8) bond length is 1.53 Å. In the sixth H site, H(6) is bonded in a distorted single-bond geometry to one O(11) and one O(7,8) atom. The H(6)-O(11) bond length is 1.04 Å. The H(6)-O(7,8) bond length is 1.53 Å. In the seventh H site, H(7,8) is bonded in a single-bond geometry to one C(5,6) atom. In the eighth H site, H(9,10) is bonded in a single-bond geometry to one C(9,10) atom. In the ninth H site, H(11,12) is bonded in a single-bond geometry to one C(11,12) atom. In the tenth H site, H(13,14) is bonded in a single-bond geometry to one C(13,14) atom. In the eleventh H site, H(15,16) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the sixteenth H site, H(21) is bonded in a single-bond geometry to one C(27) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one C(28) atom. In the eighteenth H site, H(25,26) is bonded in a single-bond geometry to one C(31) atom. In the nineteenth H site, H(27) is bonded in a single-bond geometry to one C(35) atom. In the twentieth H site, H(28) is bonded in a single-bond geometry to one C(36) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(1,2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(1,2) atom. The O(2)-C(1,2) bond length is 1.27 Å. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(1,2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(1,2) atom. The O(4)-C(1,2) bond length is 1.28 Å. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Co(1) and one C(37) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Co(2) and one C(38) atom. In the seventh O site, O(7,8) is bonded in a water-like geometry to one C(37) and one H(6) atom. In the eighth O site, O(9) is bonded in a distorted water-like geometry to one Co(1), one H(1), and one H(3) atom. In the ninth O site, O(10) is bonded in a distorted water-like geometry to one Co(2), one H(2), and one H(4) atom. In the tenth O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Co(1), one Co(2), one H(5), and one H(6) atom. Linkers: 4 [O]C(=O)c1cccc(-c2cncc(-c3cccc(C([O])=O)c3)c2)c1. Metal clusters: 2 O.O.O.O=[C]O[Co]1O[C]O[Co](O[C]=O)O[C]O1. The MOF has largest included sphere 4.50 A, density 1.22 g/cm3, surface area 4196.70 m2/g, accessible volume 0.32 cm3/g