NaZnC20H14(NO4)2CHCH2CO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two dimethyl ether molecules, and one NaZnC20H14(NO4)2 cluster. In the NaZnC20H14(NO4)2 cluster, Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), one O(7), one O(9), and two equivalent O(3) atoms. The Na(1)-O(1) bond length is 2.52 Å. The Na(1)-O(4) bond length is 2.78 Å. The Na(1)-O(7) bond length is 2.32 Å. The Na(1)-O(9) bond length is 2.53 Å. There is one shorter (2.28 Å) and one longer (2.38 Å) Na(1)-O(3) bond length. Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(2), and one O(7) atom. The Zn(1)-N(1) bond length is 2.20 Å. The Zn(1)-N(2) bond length is 2.14 Å. The Zn(1)-O(1) bond length is 2.13 Å. The Zn(1)-O(2) bond length is 2.15 Å. The Zn(1)-O(7) bond length is 2.11 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(5) atom. The C(4)-C(11) bond length is 1.42 Å. The C(4)-C(5) bond length is 1.43 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-C(7) bond length is 1.43 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(10), one C(6), and one C(8) atom. The C(7)-C(10) bond length is 1.42 Å. The C(7)-C(8) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(6) atom. The C(8)-C(9) bond length is 1.38 Å. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(23), one C(8), and one H(7) atom. The C(9)-C(23) bond length is 1.41 Å. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(7), and one N(2) atom. The C(10)-C(11) bond length is 1.44 Å. The C(10)-N(2) bond length is 1.36 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(4), and one N(1) atom. The C(11)-N(1) bond length is 1.35 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(12)-O(7) bond length is 1.28 Å. The C(12)-O(8) bond length is 1.25 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(10) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(11) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-H(11) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.42 Å. The C(17)-C(20) bond length is 1.50 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one O(4) atom. The C(18)-O(4) bond length is 1.37 Å. In the seventeenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(1), and one O(5) atom. The C(20)-O(1) bond length is 1.30 Å. The C(20)-O(5) bond length is 1.26 Å. In the eighteenth C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one H(13), one H(14), and one O(4) atom. The C(21)-H(13) bond length is 1.10 Å. The C(21)-H(14) bond length is 1.10 Å. The C(21)-O(4) bond length is 1.45 Å. In the nineteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(22)-O(2) bond length is 1.28 Å. The C(22)-O(3) bond length is 1.26 Å. In the twentieth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(15) atom. The C(23)-N(2) bond length is 1.33 Å. The C(23)-H(15) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(11) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(23) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one O(1) and one O(9) atom. The H(16)-O(1) bond length is 1.78 Å. The H(16)-O(9) bond length is 1.00 Å. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one O(9) atom. The H(17)-O(9) bond length is 0.97 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), one Zn(1), one C(20), and one H(16) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(22) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one C(22) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Na(1), one C(18), and one C(21) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(20) atom. In the sixth O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Zn(1), and one C(12) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one C(12) atom. In the eighth O site, O(9) is bonded in a water-like geometry to one Na(1), one H(16), and one H(17) atom. Linkers: 2 [O]C(=O)COc1ccc(C([O])=O)c(OCC([O])=O)c1. Metal clusters: 1 O.O.[O]C[C](O[Na])O[Zn](O[C]=O)O[C]=O.[O]C[C](O[Na])O[Zn](O[C]=O)O[C]=O. The MOF has largest included sphere 3.56 A, density 1.62 g/cm3, surface area 3770.62 m2/g, accessible volume 0.17 cm3/g