CH2(C6H5NH)2Zn2C3H2(OBr)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two 14967-65-8 molecules, and two Zn2C3H2(OBr)4 clusters. In each Zn2C3H2(OBr)4 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(4), one Br(3), and one Br(4) atom to form distorted corner-sharing ZnBr2O2 tetrahedra. The Zn(1)-O(1) bond length is 2.07 Å. The Zn(1)-O(4) bond length is 2.04 Å. The Zn(1)-Br(3) bond length is 2.37 Å. The Zn(1)-Br(4) bond length is 2.35 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one Br(1), and one Br(2) atom to form corner-sharing ZnBr2O2 tetrahedra. The Zn(2)-O(1) bond length is 2.03 Å. The Zn(2)-O(3) bond length is 1.98 Å. The Zn(2)-Br(1) bond length is 2.42 Å. The Zn(2)-Br(2) bond length is 2.37 Å. There are three inequivalent C sites. In the first C site, C(16) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(16)-O(3) bond length is 1.28 Å. The C(16)-O(4) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(11), one O(1), and one O(2) atom. The C(2)-C(11) bond length is 1.51 Å. The C(2)-O(1) bond length is 1.33 Å. The C(2)-O(2) bond length is 1.23 Å. In the third C site, C(11) is bonded in a distorted water-like geometry to one C(2), one H(10), and one H(11) atom. The C(11)-H(10) bond length is 1.10 Å. The C(11)-H(11) bond length is 1.10 Å. There are two inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(11) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(16) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(16) atom. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Zn(2) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Zn(2) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Zn(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 2 [O]C(=O)CCN1[CH]C=C(C2=C[CH]N(CCC([O])=O)C=C2)C=C1. Metal clusters: 2 O=[C]O[Zn](Br)(Br)O[C]O[Zn](Br)Br. The MOF has largest included sphere 2.28 A, density 2.25 g/cm3, surface area 3271.29 m2/g, accessible volume 0.08 cm3/g