CHCuC8NH7O3Br is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one CuC8NH7O3Br cluster. In the CuC8NH7O3Br cluster, Cu(1) is bonded in a square co-planar geometry to one N(1), one O(2), and two equivalent O(3) atoms. The Cu(1)-N(1) bond length is 1.91 Å. The Cu(1)-O(2) bond length is 1.92 Å. There is one shorter (1.95 Å) and one longer (1.96 Å) Cu(1)-O(3) bond length. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.43 Å. The C(1)-N(1) bond length is 1.30 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.44 Å. The C(2)-C(7) bond length is 1.42 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one O(2) atom. The C(3)-O(2) bond length is 1.31 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(3) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one Br(1) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-Br(1) bond length is 1.91 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(6), and one O(1) atom. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-O(1) bond length is 1.44 Å. In the eighth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one H(7), one H(8), and one O(3) atom. The C(9)-H(7) bond length is 1.11 Å. The C(9)-H(8) bond length is 1.10 Å. The C(9)-O(3) bond length is 1.41 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one O(1) atom. The N(1)-O(1) bond length is 1.41 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(9) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(8) and one N(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Cu(1) and one C(9) atom. Br(1) is bonded in a single-bond geometry to one C(6) atom. Linkers: 2 [CH]O/N=C/c1cc(Br)ccc1[O] ,2 [C]/C([O])=C([CH])/C=N/OCC[O] ,2 [O]CCO/N=C/c1cc(Br)ccc1[O]. Metal clusters: 1 [CH2]O[Cu][O].[CH2]O[Cu][O]. The MOF has largest included sphere 1.88 A, density 2.20 g/cm3, surface area 3609.64 m2/g, accessible volume 0.06 cm3/g