CuC24H22(NO)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four CuC24H22(NO)4 clusters. Cu(1) is bonded in a square co-planar geometry to two equivalent N(5,7,8) and two equivalent O(2,3) atoms. Both Cu(1)-N(5,7,8) bond lengths are 1.98 Å. Both Cu(1)-O(2,3) bond lengths are 2.00 Å. There are twelve inequivalent C sites. In the first C site, C(21,22,23,24) is bonded in a trigonal planar geometry to one C(25), one C(41), and one C(5) atom. The C(21,22,23,24)-C(25) bond length is 1.41 Å. The C(21,22,23,24)-C(41) bond length is 1.41 Å. The C(21,22,23,24)-C(5) bond length is 1.47 Å. In the second C site, C(25) is bonded in a distorted single-bond geometry to one C(21,22,23,24) and one H(29,30,31,32) atom. The C(25)-H(29,30,31,32) bond length is 1.09 Å. In the third C site, C(30) is bonded in a distorted single-bond geometry to one C(34,35) and one H(33,34,35,36) atom. The C(30)-C(34,35) bond length is 1.40 Å. The C(30)-H(33,34,35,36) bond length is 1.09 Å. In the fourth C site, C(34,35) is bonded in a trigonal planar geometry to one C(30), one C(38), and one C(46) atom. The C(34,35)-C(38) bond length is 1.40 Å. The C(34,35)-C(46) bond length is 1.50 Å. In the fifth C site, C(38) is bonded in a distorted single-bond geometry to one C(34,35) and one H(37,38,39,40) atom. The C(38)-H(37,38,39,40) bond length is 1.09 Å. In the sixth C site, C(41) is bonded in a distorted single-bond geometry to one C(21,22,23,24) and one H(41,42,43,44) atom. The C(41)-H(41,42,43,44) bond length is 1.09 Å. In the seventh C site, C(46) is bonded in a distorted bent 120 degrees geometry to one C(34,35); one O(2,3); and one O(6,7) atom. The C(46)-O(2,3) bond length is 1.31 Å. The C(46)-O(6,7) bond length is 1.25 Å. In the eighth C site, C(1,2,3,4) is bonded in a distorted trigonal planar geometry to one C(13,14,15,16); one C(5); and one N(1) atom. The C(1,2,3,4)-C(13,14,15,16) bond length is 1.48 Å. The C(1,2,3,4)-C(5) bond length is 1.40 Å. The C(1,2,3,4)-N(1) bond length is 1.35 Å. In the ninth C site, C(5) is bonded in a trigonal planar geometry to one C(1,2,3,4); one C(21,22,23,24); and one C(9) atom. The C(5)-C(9) bond length is 1.42 Å. In the tenth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(17,18,19,20); one C(5); and one N(5,7,8) atom. The C(9)-C(17,18,19,20) bond length is 1.49 Å. The C(9)-N(5,7,8) bond length is 1.34 Å. In the eleventh C site, C(13,14,15,16) is bonded in a distorted trigonal non-coplanar geometry to one C(1,2,3,4); one H(13,14,15,16); one H(5,6,7,8); and one H(9,10,11,12) atom. The C(13,14,15,16)-H(13,14,15,16) bond length is 1.10 Å. The C(13,14,15,16)-H(5,6,7,8) bond length is 1.10 Å. The C(13,14,15,16)-H(9,10,11,12) bond length is 1.10 Å. In the twelfth C site, C(17,18,19,20) is bonded in a distorted trigonal non-coplanar geometry to one C(9); one H(17,18,19,20); one H(21,22,23,24); and one H(25,26,27,28) atom. The C(17,18,19,20)-H(17,18,19,20) bond length is 1.10 Å. The C(17,18,19,20)-H(21,22,23,24) bond length is 1.10 Å. The C(17,18,19,20)-H(25,26,27,28) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one C(1,2,3,4); one N(5,7,8); and one H(1,2,3,4) atom. The N(1)-N(5,7,8) bond length is 1.35 Å. The N(1)-H(1,2,3,4) bond length is 1.02 Å. In the second N site, N(5,7,8) is bonded in a 3-coordinate geometry to one Cu(1), one C(9), and one N(1) atom. There are eleven inequivalent H sites. In the first H site, H(1,2,3,4) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(5,6,7,8) is bonded in a single-bond geometry to one C(13,14,15,16) atom. In the third H site, H(9,10,11,12) is bonded in a single-bond geometry to one C(13,14,15,16) atom. In the fourth H site, H(13,14,15,16) is bonded in a single-bond geometry to one C(13,14,15,16) atom. In the fifth H site, H(17,18,19,20) is bonded in a single-bond geometry to one C(17,18,19,20) atom. In the sixth H site, H(21,22,23,24) is bonded in a single-bond geometry to one C(17,18,19,20) atom. In the seventh H site, H(25,26,27,28) is bonded in a single-bond geometry to one C(17,18,19,20) atom. In the eighth H site, H(29,30,31,32) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(33,34,35,36) is bonded in a single-bond geometry to one C(29) atom. The H(33,34,35,36)-C(29) bond length is 1.09 Å. In the tenth H site, H(37,38,39,40) is bonded in a single-bond geometry to one C(37) atom. The H(37,38,39,40)-C(37) bond length is 1.09 Å. In the eleventh H site, H(41,42,43,44) is bonded in a single-bond geometry to one C(41) atom. There are two inequivalent O sites. In the first O site, O(2,3) is bonded in a water-like geometry to one Cu(1) and one C(46) atom. In the second O site, O(6,7) is bonded in a single-bond geometry to one C(46) atom. Linkers: 8 Cc1n[nH]c(C)c1-c1ccc(C([O])=O)cc1. Metal clusters: 4 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 6.15 A, density 1.05 g/cm3, surface area 4918.79 m2/g, accessible volume 0.44 cm3/g