Ag2C6N5H5S2 crystallizes in the orthorhombic Pbcn space group. Ag(1) is bonded in a 4-coordinate geometry to one N(2) and three equivalent S(1) atoms. The Ag(1)-N(2) bond length is 2.27 Å. There are a spread of Ag(1)-S(1) bond distances ranging from 2.52-2.82 Å. There are four inequivalent C sites. In the first C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to two equivalent C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.08 Å. In the third C site, C(4) is bonded in a distorted linear geometry to one N(3) and one S(1) atom. The C(4)-N(3) bond length is 1.18 Å. The C(4)-S(1) bond length is 1.65 Å. In the fourth C site, C(1) is bonded in a trigonal planar geometry to one N(1) and two equivalent N(2) atoms. The C(1)-N(1) bond length is 1.33 Å. Both C(1)-N(2) bond lengths are 1.37 Å. There are three inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(2) atom. In the second N site, N(3) is bonded in a single-bond geometry to one C(4) atom. In the third N site, N(1) is bonded in a trigonal planar geometry to one C(1) and two equivalent H(3) atoms. Both N(1)-H(3) bond lengths are 1.03 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded to three equivalent Ag(1) and one C(4) atom to form distorted corner-sharing SAg3C trigonal pyramids. Linkers: 4 Nc1ncccn1. Metal clusters: 8 [Ag]. The MOF has largest included sphere 1.43 A, density 2.84 g/cm3, surface area 2605.67 m2/g, accessible volume 0.06 cm3/g