ZnC14H18(NO3)2(C9H5)2(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two C9H5 clusters, and two ZnC14H18(NO3)2 clusters. In each C9H5 cluster, there are nine inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(9,10) and one H(1,2) atom. The C(3)-C(9,10) bond length is 1.41 Å. The C(3)-H(1,2) bond length is 1.09 Å. In the second C site, C(19,20) is bonded in a distorted single-bond geometry to one C(5,6) and one H(9,10) atom. The C(19,20)-C(5,6) bond length is 1.43 Å. The C(19,20)-H(9,10) bond length is 1.09 Å. In the third C site, C(5,6) is bonded in a trigonal planar geometry to one C(17); one C(19,20); and one C(7) atom. The C(5,6)-C(17) bond length is 1.42 Å. The C(5,6)-C(7) bond length is 1.45 Å. In the fourth C site, C(7) is bonded in a trigonal planar geometry to one C(17); one C(25,26); and one C(5,6) atom. The C(7)-C(17) bond length is 1.41 Å. The C(7)-C(25,26) bond length is 1.43 Å. In the fifth C site, C(9,10) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(3) atom. The C(9,10)-C(13) bond length is 1.40 Å. The C(9,10)-C(17) bond length is 1.48 Å. In the sixth C site, C(25,26) is bonded in a distorted trigonal planar geometry to one C(27), one C(7), and one H(13) atom. The C(25,26)-C(27) bond length is 1.37 Å. The C(25,26)-H(13) bond length is 1.09 Å. In the seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(25,26) and one H(15,16) atom. The C(27)-H(15,16) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(9,10) and one H(5,6) atom. The C(13)-H(5,6) bond length is 1.09 Å. In the ninth C site, C(17) is bonded in a trigonal planar geometry to one C(5,6); one C(7); and one C(9,10) atom. There are five inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(5,6) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(9,10) is bonded in a single-bond geometry to one C(19,20) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(25,26) atom. In the fifth H site, H(15,16) is bonded in a single-bond geometry to one C(27) atom. In each ZnC14H18(NO3)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(5), and one O(6) atom. The Zn(1)-O(1) bond length is 1.95 Å. The Zn(1)-O(2) bond length is 1.95 Å. The Zn(1)-O(5) bond length is 2.01 Å. The Zn(1)-O(6) bond length is 2.01 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(11,12); one C(15,16); and one C(21,22) atom. The C(1)-C(11,12) bond length is 1.40 Å. The C(1)-C(15,16) bond length is 1.40 Å. The C(1)-C(21,22) bond length is 1.50 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(11,12); one C(15,16); and one C(21,22) atom. The C(2)-C(11,12) bond length is 1.40 Å. The C(2)-C(15,16) bond length is 1.40 Å. The C(2)-C(21,22) bond length is 1.50 Å. In the third C site, C(11,12) is bonded in a distorted single-bond geometry to one C(1) and one H(3,4) atom. The C(11,12)-H(3,4) bond length is 1.09 Å. In the fourth C site, C(15,16) is bonded in a distorted single-bond geometry to one C(1) and one H(7,8) atom. The C(15,16)-H(7,8) bond length is 1.09 Å. In the fifth C site, C(21,22) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(3) atom. The C(21,22)-O(1) bond length is 1.30 Å. The C(21,22)-O(3) bond length is 1.25 Å. In the sixth C site, C(29) is bonded in a trigonal planar geometry to one N(1), one H(17), and one O(5) atom. The C(29)-N(1) bond length is 1.33 Å. The C(29)-H(17) bond length is 1.10 Å. The C(29)-O(5) bond length is 1.27 Å. In the seventh C site, C(30) is bonded in a trigonal planar geometry to one N(2), one H(18), and one O(6) atom. The C(30)-N(2) bond length is 1.33 Å. The C(30)-H(18) bond length is 1.10 Å. The C(30)-O(6) bond length is 1.27 Å. In the eighth C site, C(31,32) is bonded to one N(1); one H(19,20); one H(21,22); and one H(23,24) atom to form corner-sharing CH3N tetrahedra. The C(31,32)-N(1) bond length is 1.46 Å. The C(31,32)-H(19,20) bond length is 1.10 Å. The C(31,32)-H(21,22) bond length is 1.10 Å. The C(31,32)-H(23,24) bond length is 1.09 Å. In the ninth C site, C(33,34) is bonded to one N(1); one H(25,26); one H(27,28); and one H(29,30) atom to form corner-sharing CH3N tetrahedra. The C(33,34)-N(1) bond length is 1.46 Å. The C(33,34)-H(25,26) bond length is 1.10 Å. The C(33,34)-H(27,28) bond length is 1.10 Å. The C(33,34)-H(29,30) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(29); one C(31,32); and one C(33,34) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(30); one C(31,32); and one C(33,34) atom. The N(2)-C(31,32) bond length is 1.46 Å. The N(2)-C(33,34) bond length is 1.46 Å. There are ten inequivalent H sites. In the first H site, H(3,4) is bonded in a single-bond geometry to one C(11,12) atom. In the second H site, H(7,8) is bonded in a single-bond geometry to one C(15,16) atom. In the third H site, H(17) is bonded in a single-bond geometry to one C(29) atom. In the fourth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. In the fifth H site, H(19,20) is bonded in a single-bond geometry to one C(31,32) atom. In the sixth H site, H(21,22) is bonded in a single-bond geometry to one C(31,32) atom. In the seventh H site, H(23,24) is bonded in a single-bond geometry to one C(31,32) atom. In the eighth H site, H(25,26) is bonded in a single-bond geometry to one C(33,34) atom. In the ninth H site, H(27,28) is bonded in a single-bond geometry to one C(33,34) atom. In the tenth H site, H(29,30) is bonded in a single-bond geometry to one C(33,34) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(21,22) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(21,22) atom. The O(2)-C(21,22) bond length is 1.30 Å. In the third O site, O(3) is bonded in a single-bond geometry to one C(21,22) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(21,22) atom. The O(4)-C(21,22) bond length is 1.25 Å. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(29) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(30) atom. Linkers: 2 [O]C(=O)c1ccc(-c2c3ccccc3c(-c3ccc(C([O])=O)cc3)c3ccccc23)cc1 ,4 [O]C(=O)c1ccc(-c2c3c[c]ccc3c(-c3ccc(C([O])=O)cc3)c3ccccc23)cc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.18 A, density 1.44 g/cm3, surface area 5312.96 m2/g, accessible volume 0.14 cm3/g