CdC12H10(NO)4 is Indium-like structured and crystallizes in the orthorhombic Fddd space group. The structure is zero-dimensional and consists of sixteen CdC12H10(NO)4 clusters. Cd(1) is bonded in a distorted octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. Both Cd(1)-N(1) bond lengths are 2.28 Å. Both Cd(1)-O(1) bond lengths are 2.50 Å. Both Cd(1)-O(2) bond lengths are 2.31 Å. There are six inequivalent C sites. In the first C site, C(3) is bonded in a single-bond geometry to one C(2) and one H(1) atom. The C(3)-C(2) bond length is 1.41 Å. The C(3)-H(1) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(2) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.29 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one N(2) atom. The C(5)-N(1) bond length is 1.36 Å. The C(5)-N(2) bond length is 1.35 Å. In the fifth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(6) bond length is 1.38 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one C(5), one H(4), and one H(5) atom. The N(2)-H(4) bond length is 1.02 Å. The N(2)-H(5) bond length is 1.02 Å. In the second N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(4), and one C(5) atom. There are five inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(2) is bonded in a single-bond geometry to one C(4) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the second O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. Linkers: 8 Nc1cc(C([O])=O)ccn1. Metal clusters: 4 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 6.73 A, density 1.34 g/cm3, surface area 3901.14 m2/g, accessible volume 0.38 cm3/g