RuC8H2(O2F)2(CH)6C5NH8 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules; two n,n-dimethylprop-1-en-2-amine molecules; and one RuC8H2(O2F)2 cluster. In the RuC8H2(O2F)2 cluster, Ru(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Ru(1)-O(1) bond length is 2.06 Å. The Ru(1)-O(2) bond length is 2.06 Å. The Ru(1)-O(3) bond length is 2.05 Å. The Ru(1)-O(4) bond length is 2.07 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.41 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(2) and one F(1) atom. The C(3)-F(1) bond length is 1.37 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(8)-C(9) bond length is 1.48 Å. The C(8)-O(3) bond length is 1.28 Å. The C(8)-O(4) bond length is 1.28 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.41 Å. In the seventh C site, C(10) is bonded in a single-bond geometry to one C(9) and one F(2) atom. The C(10)-F(2) bond length is 1.37 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(14)-H(8) bond length is 1.09 Å. There are two inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(14) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(8) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(10) atom. Linkers: 1 CN(C)c1ccc(N(C)C)cc1. Metal clusters: 2 [Ru]. The MOF has largest included sphere 3.08 A, density 1.73 g/cm3, surface area 4090.83 m2/g, accessible volume 0.13 cm3/g