CHCdC14H11S(N2O3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one CdC14H11S(N2O3)2 cluster. In the CdC14H11S(N2O3)2 cluster, Cd(1) is bonded in a distorted pentagonal bipyramidal geometry to one N(1), one N(2), one S(1), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.34 Å. The Cd(1)-N(2) bond length is 2.28 Å. The Cd(1)-S(1) bond length is 2.67 Å. The Cd(1)-O(1) bond length is 2.59 Å. The Cd(1)-O(2) bond length is 2.58 Å. The Cd(1)-O(3) bond length is 2.34 Å. The Cd(1)-O(4) bond length is 2.43 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one C(3), one H(1), one H(2), and one S(1) atom. The C(1)-C(3) bond length is 1.50 Å. The C(1)-H(1) bond length is 1.09 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.84 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(3) atom. The C(2)-C(9) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(9) atom. The C(3)-C(11) bond length is 1.40 Å. The C(3)-C(9) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one H(4) atom. The C(4)-C(11) bond length is 1.39 Å. The C(4)-N(2) bond length is 1.35 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(15), one N(1), and one H(5) atom. The C(5)-C(15) bond length is 1.41 Å. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(7), one C(8), and one S(1) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-C(8) bond length is 1.43 Å. The C(6)-S(1) bond length is 1.77 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(12), one C(6), and one N(1) atom. The C(8)-C(12) bond length is 1.43 Å. The C(8)-N(1) bond length is 1.36 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(2), one C(3), and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(12), one C(15), and one H(8) atom. The C(10)-C(12) bond length is 1.41 Å. The C(10)-C(15) bond length is 1.38 Å. The C(10)-H(8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(3), one C(4), and one H(9) atom. The C(11)-H(9) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(12)-C(14) bond length is 1.42 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(14)-H(11) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(10), one C(5), and one H(12) atom. The C(15)-H(12) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(5), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(2), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(4), and one O(5) atom. The N(3)-O(1) bond length is 1.28 Å. The N(3)-O(4) bond length is 1.29 Å. The N(3)-O(5) bond length is 1.24 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(6) atom. The N(4)-O(2) bond length is 1.27 Å. The N(4)-O(3) bond length is 1.30 Å. The N(4)-O(6) bond length is 1.24 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(15) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Cd(1), one C(1), and one C(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one N(3) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one N(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cd(1) and one N(4) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Cd(1) and one N(3) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(4) atom. Linkers: 2 c1cnc2c(SCc3ccncc3)cccc2c1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 2.01 A, density 1.89 g/cm3, surface area 4053.35 m2/g, accessible volume 0.09 cm3/g