ZnC7N5H9S2CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and two ZnC7N5H9S2 clusters. In each ZnC7N5H9S2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one N(4), and one N(5) atom. The Zn(1)-N(1) bond length is 2.00 Å. The Zn(1)-N(3) bond length is 2.03 Å. The Zn(1)-N(4) bond length is 1.95 Å. The Zn(1)-N(5) bond length is 1.97 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(2) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(3) atom. The C(3)-N(1) bond length is 1.38 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(4), and one H(5) atom. The C(4)-N(2) bond length is 1.46 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(8), and one H(9) atom. The C(6)-N(3) bond length is 1.49 Å. The C(6)-H(8) bond length is 1.10 Å. The C(6)-H(9) bond length is 1.10 Å. In the sixth C site, C(7) is bonded in a distorted linear geometry to one N(4) and one S(1) atom. The C(7)-N(4) bond length is 1.19 Å. The C(7)-S(1) bond length is 1.61 Å. In the seventh C site, C(8) is bonded in a distorted linear geometry to one N(5) and one S(2) atom. The C(8)-N(5) bond length is 1.19 Å. The C(8)-S(2) bond length is 1.61 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(4) atom. In the third N site, N(3) is bonded in a distorted tetrahedral geometry to one Zn(1), one C(6), one H(10), and one H(11) atom. The N(3)-H(10) bond length is 1.03 Å. The N(3)-H(11) bond length is 1.03 Å. In the fourth N site, N(4) is bonded in a linear geometry to one Zn(1) and one C(7) atom. In the fifth N site, N(5) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(8) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one N(3) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one C(7) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(8) atom. Linkers: 2 NCCCn1c[c]nc1 ,2 NCCCn1ccnc1 ,2 [NH]CCCn1ccnc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.78 A, density 1.63 g/cm3, surface area 5027.37 m2/g, accessible volume 0.12 cm3/g