Cu3C19H10O11F6H2O crystallizes in the triclinic P-1 space group. The structure consists of four water molecules inside a Cu3C19H10O11F6 framework. In the Cu3C19H10O11F6 framework, there are eight inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(12), one O(17), and one O(22) atom. The Cu(1)-O(1) bond length is 1.94 Å. The Cu(1)-O(12) bond length is 2.01 Å. The Cu(1)-O(17) bond length is 1.96 Å. The Cu(1)-O(22) bond length is 2.02 Å. In the second Cu site, Cu(2) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(18), one O(2), and one O(21) atom. The Cu(2)-O(11) bond length is 2.01 Å. The Cu(2)-O(18) bond length is 1.97 Å. The Cu(2)-O(2) bond length is 1.94 Å. The Cu(2)-O(21) bond length is 2.02 Å. In the third Cu site, Cu(3) is bonded in a square co-planar geometry to two equivalent O(18) and two equivalent O(9) atoms. Both Cu(3)-O(18) bond lengths are 1.96 Å. Both Cu(3)-O(9) bond lengths are 1.92 Å. In the fourth Cu site, Cu(4) is bonded in a square co-planar geometry to two equivalent O(10) and two equivalent O(17) atoms. Both Cu(4)-O(10) bond lengths are 1.92 Å. Both Cu(4)-O(17) bond lengths are 1.97 Å. In the fifth Cu site, Cu(5) is bonded in a 5-coordinate geometry to one O(13), one O(18), one O(19), one O(21), and one O(6) atom. The Cu(5)-O(13) bond length is 1.93 Å. The Cu(5)-O(18) bond length is 2.44 Å. The Cu(5)-O(19) bond length is 2.08 Å. The Cu(5)-O(21) bond length is 1.98 Å. The Cu(5)-O(6) bond length is 1.95 Å. In the sixth Cu site, Cu(6) is bonded in a 5-coordinate geometry to one O(14), one O(17), one O(20), one O(22), and one O(5) atom. The Cu(6)-O(14) bond length is 1.93 Å. The Cu(6)-O(17) bond length is 2.45 Å. The Cu(6)-O(20) bond length is 2.07 Å. The Cu(6)-O(22) bond length is 1.98 Å. The Cu(6)-O(5) bond length is 1.95 Å. In the seventh Cu site, Cu(7) is bonded in an octahedral geometry to two equivalent O(21), two equivalent O(4), and two equivalent O(8) atoms. Both Cu(7)-O(21) bond lengths are 1.99 Å. Both Cu(7)-O(4) bond lengths are 2.40 Å. Both Cu(7)-O(8) bond lengths are 2.04 Å. In the eighth Cu site, Cu(8) is bonded in an octahedral geometry to two equivalent O(22), two equivalent O(3), and two equivalent O(7) atoms. Both Cu(8)-O(22) bond lengths are 1.98 Å. Both Cu(8)-O(3) bond lengths are 2.40 Å. Both Cu(8)-O(7) bond lengths are 2.03 Å. There are thirty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(4) atom. The C(2)-C(4) bond length is 1.50 Å. The C(2)-O(2) bond length is 1.28 Å. The C(2)-O(4) bond length is 1.27 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(15), and one C(5) atom. The C(3)-C(15) bond length is 1.40 Å. The C(3)-C(5) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(16), one C(2), and one C(6) atom. The C(4)-C(16) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(9) atom. The C(5)-C(7) bond length is 1.50 Å. The C(5)-C(9) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(8) atom. The C(6)-C(10) bond length is 1.40 Å. The C(6)-C(8) bond length is 1.50 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(5), and one O(7) atom. The C(7)-O(5) bond length is 1.27 Å. The C(7)-O(7) bond length is 1.27 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(6), and one O(8) atom. The C(8)-O(6) bond length is 1.28 Å. The C(8)-O(8) bond length is 1.27 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(11,12); one C(5); and one H(1,2) atom. The C(9)-C(11,12) bond length is 1.40 Å. The C(9)-H(1,2) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11,12); one C(6); and one H(1,2) atom. The C(10)-C(11,12) bond length is 1.40 Å. The C(10)-H(1,2) bond length is 1.09 Å. In the eleventh C site, C(11,12) is bonded in a trigonal planar geometry to one C(13,14); one C(17,18); and one C(9) atom. The C(11,12)-C(13,14) bond length is 1.40 Å. The C(11,12)-C(17,18) bond length is 1.54 Å. In the twelfth C site, C(13,14) is bonded in a distorted single-bond geometry to one C(11,12) and one H(3,4) atom. The C(13,14)-H(3,4) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(3) and one H(5,6) atom. The C(15)-H(5,6) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(4) and one H(5,6) atom. The C(16)-H(5,6) bond length is 1.09 Å. In the fifteenth C site, C(17,18) is bonded in a tetrahedral geometry to one C(11,12); one C(19,20); one C(21,22); and one C(23) atom. The C(17,18)-C(19,20) bond length is 1.56 Å. The C(17,18)-C(21,22) bond length is 1.55 Å. The C(17,18)-C(23) bond length is 1.54 Å. In the sixteenth C site, C(19,20) is bonded in a trigonal non-coplanar geometry to one C(17,18); one F(1,2); one F(3,4); and one F(5,6) atom. The C(19,20)-F(1,2) bond length is 1.36 Å. The C(19,20)-F(3,4) bond length is 1.36 Å. The C(19,20)-F(5,6) bond length is 1.37 Å. In the seventeenth C site, C(21,22) is bonded in a trigonal non-coplanar geometry to one C(17,18); one F(11,12); one F(7,8); and one F(9,10) atom. The C(21,22)-F(11,12) bond length is 1.36 Å. The C(21,22)-F(7,8) bond length is 1.37 Å. The C(21,22)-F(9,10) bond length is 1.36 Å. In the eighteenth C site, C(23) is bonded in a trigonal planar geometry to one C(17,18); one C(25,26); and one C(35,36) atom. The C(23)-C(25,26) bond length is 1.40 Å. The C(23)-C(35,36) bond length is 1.40 Å. In the nineteenth C site, C(24) is bonded in a trigonal planar geometry to one C(17,18); one C(25,26); and one C(35,36) atom. The C(24)-C(17,18) bond length is 1.54 Å. The C(24)-C(25,26) bond length is 1.40 Å. The C(24)-C(35,36) bond length is 1.40 Å. In the twentieth C site, C(25,26) is bonded in a distorted single-bond geometry to one C(23), one C(27), and one H(7) atom. The C(25,26)-C(27) bond length is 1.40 Å. The C(25,26)-H(7) bond length is 1.09 Å. In the twenty-first C site, C(27) is bonded in a trigonal planar geometry to one C(25,26); one C(29); and one C(31) atom. The C(27)-C(29) bond length is 1.49 Å. The C(27)-C(31) bond length is 1.41 Å. In the twenty-second C site, C(28) is bonded in a trigonal planar geometry to one C(25,26); one C(30); and one C(32) atom. The C(28)-C(25,26) bond length is 1.40 Å. The C(28)-C(30) bond length is 1.49 Å. The C(28)-C(32) bond length is 1.41 Å. In the twenty-third C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(11), and one O(9) atom. The C(29)-O(11) bond length is 1.28 Å. The C(29)-O(9) bond length is 1.27 Å. In the twenty-fourth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(10), and one O(12) atom. The C(30)-O(10) bond length is 1.27 Å. The C(30)-O(12) bond length is 1.28 Å. In the twenty-fifth C site, C(31) is bonded in a trigonal planar geometry to one C(27), one C(33), and one C(37) atom. The C(31)-C(33) bond length is 1.39 Å. The C(31)-C(37) bond length is 1.51 Å. In the twenty-sixth C site, C(32) is bonded in a trigonal planar geometry to one C(28), one C(34), and one C(38) atom. The C(32)-C(34) bond length is 1.39 Å. The C(32)-C(38) bond length is 1.51 Å. In the twenty-seventh C site, C(33) is bonded in a distorted single-bond geometry to one C(31) and one H(9,10) atom. The C(33)-H(9,10) bond length is 1.08 Å. In the twenty-eighth C site, C(34) is bonded in a distorted single-bond geometry to one C(32) and one H(9,10) atom. The C(34)-H(9,10) bond length is 1.08 Å. In the twenty-ninth C site, C(35,36) is bonded in a distorted single-bond geometry to one C(23) and one H(11,12) atom. The C(35,36)-H(11,12) bond length is 1.09 Å. In the thirtieth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(13), and one O(15) atom. The C(37)-O(13) bond length is 1.29 Å. The C(37)-O(15) bond length is 1.26 Å. In the thirty-first C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(14), and one O(16) atom. The C(38)-O(14) bond length is 1.29 Å. The C(38)-O(16) bond length is 1.26 Å. There are fifteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(13,14) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(25,26) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(25,26) atom. The H(8)-C(25,26) bond length is 1.09 Å. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(33) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(35,36) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one O(17) atom. The H(13)-O(17) bond length is 0.98 Å. In the ninth H site, H(14) is bonded in a single-bond geometry to one O(18) atom. The H(14)-O(18) bond length is 0.98 Å. In the tenth H site, H(15) is bonded in a distorted linear geometry to one O(15) and one O(21) atom. The H(15)-O(15) bond length is 1.58 Å. The H(15)-O(21) bond length is 1.03 Å. In the eleventh H site, H(16) is bonded in a distorted linear geometry to one O(16) and one O(22) atom. The H(16)-O(16) bond length is 1.58 Å. The H(16)-O(22) bond length is 1.03 Å. In the twelfth H site, H(17) is bonded in a single-bond geometry to one O(19) atom. The H(17)-O(19) bond length is 1.01 Å. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one O(20) atom. The H(18)-O(20) bond length is 1.01 Å. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one O(19) atom. The H(19)-O(19) bond length is 0.98 Å. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one O(20) atom. The H(20)-O(20) bond length is 0.98 Å. There are twenty-two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cu(8) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cu(7) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(6) and one C(7) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(5) and one C(8) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(8) and one C(7) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(7) and one C(8) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(29) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(30) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(29) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(30) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Cu(5) and one C(37) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Cu(6) and one C(38) atom. In the fifteenth O site, O(15) is bonded in a water-like geometry to one C(37) and one H(15) atom. In the sixteenth O site, O(16) is bonded in a water-like geometry to one C(38) and one H(16) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Cu(1), one Cu(4), one Cu(6), and one H(13) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one Cu(2), one Cu(3), one Cu(5), and one H(14) atom. In the nineteenth O site, O(19) is bonded in a distorted water-like geometry to one Cu(5), one H(17), and one H(19) atom. In the twentieth O site, O(20) is bonded in a distorted water-like geometry to one Cu(6), one H(18), and one H(20) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one Cu(2), one Cu(5), one Cu(7), and one H(15) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one Cu(1), one Cu(6), one Cu(8), and one H(16) atom. There are six inequivalent F sites. In the first F site, F(1,2) is bonded in a single-bond geometry to one C(19,20) atom. In the second F site, F(3,4) is bonded in a single-bond geometry to one C(19,20) atom. In the third F site, F(5,6) is bonded in a single-bond geometry to one C(19,20) atom. In the fourth F site, F(7,8) is bonded in a single-bond geometry to one C(21,22) atom. In the fifth F site, F(9,10) is bonded in a single-bond geometry to one C(21,22) atom. In the sixth F site, F(11,12) is bonded in a single-bond geometry to one C(21,22) atom. Linkers: 4 [O]C(=O)c1ccc(C(c2ccc(C([O])=O)c(C([O])=O)c2)(C(F)(F)F)C(F)(F)F)cc1C([O])=O. Metal clusters: 12 [Cu]. The MOF has largest included sphere 3.95 A, density 1.94 g/cm3, surface area 3043.28 m2/g, accessible volume 0.19 cm3/g