UCuC13H7(NO5)2CH crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a UCuC13H7(NO5)2 framework. In the UCuC13H7(NO5)2 framework, U(1) is bonded in a distorted pentagonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(5), one O(6), one O(7), and one O(8) atom. The U(1)-O(1) bond length is 1.81 Å. The U(1)-O(2) bond length is 1.81 Å. The U(1)-O(3) bond length is 2.37 Å. The U(1)-O(5) bond length is 2.42 Å. The U(1)-O(6) bond length is 2.35 Å. The U(1)-O(7) bond length is 2.44 Å. The U(1)-O(8) bond length is 2.43 Å. Cu(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(2), one O(10), one O(4), and one O(9) atom. The Cu(1)-N(1) bond length is 1.97 Å. The Cu(1)-N(2) bond length is 1.96 Å. The Cu(1)-O(10) bond length is 1.99 Å. The Cu(1)-O(4) bond length is 2.33 Å. The Cu(1)-O(9) bond length is 2.00 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(1)-O(3) bond length is 1.29 Å. The C(1)-O(4) bond length is 1.24 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(2)-O(5) bond length is 1.27 Å. The C(2)-O(6) bond length is 1.26 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(3)-O(7) bond length is 1.26 Å. The C(3)-O(8) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(4)-O(10) bond length is 1.26 Å. The C(4)-O(9) bond length is 1.27 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(1) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(1) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(2) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(2) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(7)-H(3) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(4) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(1) atom. The C(9)-C(10) bond length is 1.47 Å. The C(9)-N(1) bond length is 1.36 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one N(2) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-N(2) bond length is 1.36 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(11)-H(5) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(7) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(7) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(2), and one H(8) atom. The C(14)-N(2) bond length is 1.34 Å. The C(14)-H(8) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(5), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(14) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(14) atom. There are ten inequivalent O sites. In the first O site, O(7) is bonded in a distorted bent 120 degrees geometry to one U(1) and one C(3) atom. In the second O site, O(8) is bonded in a distorted bent 120 degrees geometry to one U(1) and one C(3) atom. In the third O site, O(9) is bonded in a water-like geometry to one Cu(1) and one C(4) atom. In the fourth O site, O(10) is bonded in a water-like geometry to one Cu(1) and one C(4) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one U(1) atom. In the seventh O site, O(3) is bonded in a distorted bent 120 degrees geometry to one U(1) and one C(1) atom. In the eighth O site, O(4) is bonded in a distorted single-bond geometry to one Cu(1) and one C(1) atom. In the ninth O site, O(5) is bonded in a distorted single-bond geometry to one U(1) and one C(2) atom. In the tenth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one U(1) and one C(2) atom. Linkers: 8 [O]C(=O)C([O])=O ,2 c1ccc(-c2ccccn2)nc1. Metal clusters: 4 [U] ,4 [Cu]. The MOF has largest included sphere 2.18 A, density 2.69 g/cm3, surface area 2744.08 m2/g, accessible volume 0.08 cm3/g