Na2C22N8H32O15(CH2O)2(H2O)2 crystallizes in the triclinic P1 space group. The structure consists of two methanol molecules and two water molecules inside a Na2C22N8H32O15 framework. In the Na2C22N8H32O15 framework, there are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 5-coordinate geometry to one O(13), one O(19), one O(2), one O(5), and one O(7) atom. The Na(1)-O(13) bond length is 2.38 Å. The Na(1)-O(19) bond length is 2.52 Å. The Na(1)-O(2) bond length is 2.41 Å. The Na(1)-O(5) bond length is 2.43 Å. The Na(1)-O(7) bond length is 2.55 Å. In the second Na site, Na(2) is bonded in a trigonal bipyramidal geometry to one O(1), one O(13), one O(17), one O(2), and one O(3) atom. The Na(2)-O(1) bond length is 2.32 Å. The Na(2)-O(13) bond length is 2.40 Å. The Na(2)-O(17) bond length is 2.36 Å. The Na(2)-O(2) bond length is 2.40 Å. The Na(2)-O(3) bond length is 2.34 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted tetrahedral geometry to one C(12), one N(1), and one H(15) atom. The C(1)-C(12) bond length is 1.49 Å. The C(1)-N(1) bond length is 1.48 Å. The C(1)-H(15) bond length is 1.10 Å. In the second C site, C(3) is bonded in a distorted water-like geometry to one H(18) and one O(9) atom. The C(3)-H(18) bond length is 1.10 Å. The C(3)-O(9) bond length is 1.42 Å. In the third C site, C(4) is bonded in a 2-coordinate geometry to one N(1) and one H(20) atom. The C(4)-N(1) bond length is 1.47 Å. The C(4)-H(20) bond length is 1.10 Å. In the fourth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one H(21), one H(22), and one O(10) atom. The C(5)-H(21) bond length is 1.10 Å. The C(5)-H(22) bond length is 1.10 Å. The C(5)-O(10) bond length is 1.44 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one N(1), one O(11), and one O(12) atom. The C(6)-N(1) bond length is 1.36 Å. The C(6)-O(11) bond length is 1.28 Å. The C(6)-O(12) bond length is 1.29 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(25) atom. The C(7)-N(2) bond length is 1.36 Å. The C(7)-N(3) bond length is 1.31 Å. The C(7)-H(25) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(12), one C(9), and one N(3) atom. The C(8)-C(12) bond length is 1.42 Å. The C(8)-C(9) bond length is 1.42 Å. The C(8)-N(3) bond length is 1.37 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one N(4) atom. The C(9)-C(10) bond length is 1.42 Å. The C(9)-N(4) bond length is 1.37 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(2), and one O(13) atom. The C(10)-N(2) bond length is 1.39 Å. The C(10)-O(13) bond length is 1.26 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(4), and one H(27) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(4) bond length is 1.37 Å. The C(11)-H(27) bond length is 1.08 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(8) atom. In the twelfth C site, C(13) is bonded in a 2-coordinate geometry to one C(24), one N(5), and one H(28) atom. The C(13)-C(24) bond length is 1.50 Å. The C(13)-N(5) bond length is 1.48 Å. The C(13)-H(28) bond length is 1.10 Å. In the thirteenth C site, C(15) is bonded in a distorted water-like geometry to one H(31) and one O(15) atom. The C(15)-H(31) bond length is 1.11 Å. The C(15)-O(15) bond length is 1.41 Å. In the fourteenth C site, C(16) is bonded in a 2-coordinate geometry to one N(5) and one H(33) atom. The C(16)-N(5) bond length is 1.48 Å. The C(16)-H(33) bond length is 1.11 Å. In the fifteenth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one H(34), one H(35), and one O(18) atom. The C(17)-H(34) bond length is 1.10 Å. The C(17)-H(35) bond length is 1.11 Å. The C(17)-O(18) bond length is 1.43 Å. In the sixteenth C site, C(18) is bonded in a trigonal planar geometry to one N(5), one O(16), and one O(17) atom. The C(18)-N(5) bond length is 1.38 Å. The C(18)-O(16) bond length is 1.29 Å. The C(18)-O(17) bond length is 1.27 Å. In the seventeenth C site, C(19) is bonded in a trigonal planar geometry to one N(6), one N(7), and one H(38) atom. The C(19)-N(6) bond length is 1.36 Å. The C(19)-N(7) bond length is 1.31 Å. The C(19)-H(38) bond length is 1.09 Å. In the eighteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(21), one C(24), and one N(7) atom. The C(20)-C(21) bond length is 1.42 Å. The C(20)-C(24) bond length is 1.43 Å. The C(20)-N(7) bond length is 1.38 Å. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one N(8) atom. The C(21)-C(22) bond length is 1.42 Å. The C(21)-N(8) bond length is 1.37 Å. In the twentieth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(6), and one O(19) atom. The C(22)-N(6) bond length is 1.39 Å. The C(22)-O(19) bond length is 1.26 Å. In the twenty-first C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(24), one N(8), and one H(40) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-N(8) bond length is 1.37 Å. The C(23)-H(40) bond length is 1.09 Å. In the twenty-second C site, C(24) is bonded in a trigonal planar geometry to one C(13), one C(20), and one C(23) atom. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(7), and one H(24) atom. The N(2)-H(24) bond length is 1.05 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(7) and one C(8) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(11), one C(9), and one H(26) atom. The N(4)-H(26) bond length is 1.03 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(13), one C(16), and one C(18) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(19), one C(22), and one H(37) atom. The N(6)-H(37) bond length is 1.05 Å. In the seventh N site, N(7) is bonded in a bent 120 degrees geometry to one C(19) and one C(20) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(21), one C(23), and one H(39) atom. The N(8)-H(39) bond length is 1.04 Å. There are thirty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. The H(3)-O(2) bond length is 0.97 Å. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 1.01 Å. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one O(12) and one O(3) atom. The H(5)-O(12) bond length is 1.63 Å. The H(5)-O(3) bond length is 1.00 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. The H(6)-O(3) bond length is 0.99 Å. In the seventh H site, H(9) is bonded in a single-bond geometry to one O(5) atom. The H(9)-O(5) bond length is 0.99 Å. In the eighth H site, H(10) is bonded in a single-bond geometry to one O(5) atom. The H(10)-O(5) bond length is 0.99 Å. In the ninth H site, H(13) is bonded in a single-bond geometry to one O(7) atom. The H(13)-O(7) bond length is 1.00 Å. In the tenth H site, H(14) is bonded in a single-bond geometry to one O(7) atom. The H(14)-O(7) bond length is 1.00 Å. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(1) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(3) atom. In the thirteenth H site, H(19) is bonded in a distorted linear geometry to one O(11) and one O(9) atom. The H(19)-O(11) bond length is 1.62 Å. The H(19)-O(9) bond length is 1.01 Å. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(4) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(5) atom. In the sixteenth H site, H(22) is bonded in a single-bond geometry to one C(5) atom. In the seventeenth H site, H(23) is bonded in a distorted linear geometry to one O(10) and one O(12) atom. The H(23)-O(10) bond length is 1.01 Å. The H(23)-O(12) bond length is 1.61 Å. In the eighteenth H site, H(24) is bonded in a distorted linear geometry to one N(2) and one O(17) atom. The H(24)-O(17) bond length is 1.63 Å. In the nineteenth H site, H(25) is bonded in a single-bond geometry to one C(7) atom. In the twentieth H site, H(26) is bonded in a single-bond geometry to one N(4) atom. In the twenty-first H site, H(27) is bonded in a single-bond geometry to one C(11) atom. In the twenty-second H site, H(28) is bonded in a single-bond geometry to one C(13) atom. In the twenty-third H site, H(31) is bonded in a single-bond geometry to one C(15) atom. In the twenty-fourth H site, H(32) is bonded in a distorted linear geometry to one O(15) and one O(16) atom. The H(32)-O(15) bond length is 1.02 Å. The H(32)-O(16) bond length is 1.59 Å. In the twenty-fifth H site, H(33) is bonded in a single-bond geometry to one C(16) atom. In the twenty-sixth H site, H(34) is bonded in a single-bond geometry to one C(17) atom. In the twenty-seventh H site, H(35) is bonded in a single-bond geometry to one C(17) atom. In the twenty-eighth H site, H(36) is bonded in a distorted linear geometry to one O(16) and one O(18) atom. The H(36)-O(16) bond length is 1.58 Å. The H(36)-O(18) bond length is 1.01 Å. In the twenty-ninth H site, H(37) is bonded in a distorted single-bond geometry to one N(6) and one O(11) atom. The H(37)-O(11) bond length is 1.71 Å. In the thirtieth H site, H(38) is bonded in a single-bond geometry to one C(19) atom. In the thirty-first H site, H(39) is bonded in a single-bond geometry to one N(8) atom. In the thirty-second H site, H(40) is bonded in a single-bond geometry to one C(23) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Na(2), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Na(2), one H(5), and one H(6) atom. In the fourth O site, O(5) is bonded in a distorted water-like geometry to one Na(1), one H(10), and one H(9) atom. In the fifth O site, O(7) is bonded in a water-like geometry to one Na(1), one H(13), and one H(14) atom. In the sixth O site, O(9) is bonded in a water-like geometry to one C(3) and one H(19) atom. In the seventh O site, O(10) is bonded in a distorted water-like geometry to one C(5) and one H(23) atom. In the eighth O site, O(11) is bonded in a 3-coordinate geometry to one C(6), one H(19), and one H(37) atom. In the ninth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one H(23), and one H(5) atom. In the tenth O site, O(13) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one C(10) atom. In the eleventh O site, O(15) is bonded in a bent 120 degrees geometry to one C(15) and one H(32) atom. In the twelfth O site, O(16) is bonded in a trigonal planar geometry to one C(18), one H(32), and one H(36) atom. In the thirteenth O site, O(17) is bonded in a 3-coordinate geometry to one Na(2), one C(18), and one H(24) atom. In the fourteenth O site, O(18) is bonded in a water-like geometry to one C(17) and one H(36) atom. In the fifteenth O site, O(19) is bonded in a distorted single-bond geometry to one Na(1) and one C(22) atom. Linkers: 1 [O]C(=O)N1[C@H](CO)[C@@H](O)[C@@H](O)[C@@H]1c1c[nH]c2c(=O)[nH]cnc12. Metal clusters: 2 [Na]. The MOF has largest included sphere 2.50 A, density 1.52 g/cm3, surface area 4367.94 m2/g, accessible volume 0.20 cm3/g