PrC10N5H10O8C5H4N4C2NH2C7N5H6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two n-methyl methanimine molecules, two schembl15367994 molecules, two schembl22322481 molecules, and one PrC10N5H10O8 cluster. In the PrC10N5H10O8 cluster, Pr(1) is bonded in a 9-coordinate geometry to one N(1), one O(1), one O(2), one O(4), one O(6), one O(7), one O(8), and two equivalent O(5) atoms. The Pr(1)-N(1) bond length is 2.72 Å. The Pr(1)-O(1) bond length is 2.46 Å. The Pr(1)-O(2) bond length is 2.63 Å. The Pr(1)-O(4) bond length is 2.41 Å. The Pr(1)-O(6) bond length is 2.53 Å. The Pr(1)-O(7) bond length is 2.55 Å. The Pr(1)-O(8) bond length is 2.55 Å. There is one shorter (2.46 Å) and one longer (2.68 Å) Pr(1)-O(5) bond length. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(16), one N(1), and one H(1) atom. The C(1)-C(16) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(15), one N(1), and one H(2) atom. The C(2)-C(15) bond length is 1.39 Å. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(3)-O(3) bond length is 1.25 Å. The C(3)-O(4) bond length is 1.28 Å. In the fourth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(5) atom. The C(11)-O(2) bond length is 1.25 Å. The C(11)-O(5) bond length is 1.28 Å. In the fifth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one N(8), one H(12), and one H(13) atom. The C(12)-N(8) bond length is 1.45 Å. The C(12)-H(12) bond length is 1.10 Å. The C(12)-H(13) bond length is 1.10 Å. In the sixth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(10), and one N(7) atom. The C(13)-C(14) bond length is 1.46 Å. The C(13)-N(10) bond length is 1.36 Å. The C(13)-N(7) bond length is 1.34 Å. In the seventh C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(16) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(16) bond length is 1.40 Å. In the eighth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(2), and one H(14) atom. The C(15)-H(14) bond length is 1.09 Å. In the ninth C site, C(16) is bonded in a distorted single-bond geometry to one C(1), one C(14), and one H(15) atom. The C(16)-H(15) bond length is 1.09 Å. In the tenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(6) atom. The C(17)-O(1) bond length is 1.26 Å. The C(17)-O(6) bond length is 1.26 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Pr(1), one C(1), and one C(2) atom. In the second N site, N(7) is bonded in a water-like geometry to one C(13) and one N(8) atom. The N(7)-N(8) bond length is 1.32 Å. In the third N site, N(8) is bonded in a distorted trigonal planar geometry to one C(12), one N(7), and one N(9) atom. The N(8)-N(9) bond length is 1.34 Å. In the fourth N site, N(9) is bonded in a distorted water-like geometry to one N(10) and one N(8) atom. The N(9)-N(10) bond length is 1.31 Å. In the fifth N site, N(10) is bonded in a distorted water-like geometry to one C(13) and one N(9) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) and one O(7) atom. The H(3)-O(3) bond length is 1.68 Å. The H(3)-O(7) bond length is 1.01 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(7) atom. The H(4)-O(7) bond length is 1.00 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(8) atom. The H(5)-O(8) bond length is 0.99 Å. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one O(8) atom. The H(22)-O(8) bond length is 0.98 Å. There are eight inequivalent O sites. In the first O site, O(3) is bonded in a distorted water-like geometry to one C(3) and one H(3) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Pr(1) and one C(3) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Pr(1) and one C(11) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Pr(1) and one C(17) atom. In the fifth O site, O(7) is bonded in a water-like geometry to one Pr(1), one H(3), and one H(4) atom. In the sixth O site, O(8) is bonded in a distorted water-like geometry to one Pr(1), one H(22), and one H(5) atom. In the seventh O site, O(1) is bonded in a distorted single-bond geometry to one Pr(1) and one C(17) atom. In the eighth O site, O(2) is bonded in a single-bond geometry to one Pr(1) and one C(11) atom. Linkers: 2 [O]C(=O)Cn1nnc(-c2ccncc2)n1. Metal clusters: 2 [Pr]. The MOF has largest included sphere 3.66 A, density 1.69 g/cm3, surface area 4191.85 m2/g, accessible volume 0.16 cm3/g