(CH)2Cu2C9H7Br3(NO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one Cu2C9H7Br3(NO)2 cluster. In the Cu2C9H7Br3(NO)2 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 5-coordinate geometry to one N(1), one O(1), one Br(1), and two equivalent Br(3) atoms. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-O(1) bond length is 2.00 Å. The Cu(1)-Br(1) bond length is 2.46 Å. There is one shorter (2.39 Å) and one longer (2.81 Å) Cu(1)-Br(3) bond length. In the second Cu site, Cu(2) is bonded in a 4-coordinate geometry to one N(2), one O(1), one Br(1), and one Br(2) atom. The Cu(2)-N(2) bond length is 1.98 Å. The Cu(2)-O(1) bond length is 1.98 Å. The Cu(2)-Br(1) bond length is 2.46 Å. The Cu(2)-Br(2) bond length is 2.36 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one C(2), one C(3), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.54 Å. The C(1)-C(3) bond length is 1.54 Å. The C(1)-O(1) bond length is 1.41 Å. The C(1)-O(2) bond length is 1.42 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(11), and one N(2) atom. The C(2)-C(11) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.35 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(1), one C(4), and one N(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-N(1) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one H(4) atom. The C(6)-C(8) bond length is 1.39 Å. The C(6)-N(2) bond length is 1.34 Å. The C(6)-H(4) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(5) atom. The C(7)-C(10) bond length is 1.39 Å. The C(7)-N(1) bond length is 1.34 Å. The C(7)-H(5) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(7) and one H(8) atom. The C(10)-H(8) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(2) and one H(9) atom. The C(11)-H(9) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(2), and one C(6) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to one Cu(1), one Cu(2), and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(1) and one H(1) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a distorted L-shaped geometry to one Cu(1) and one Cu(2) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Cu(2) atom. In the third Br site, Br(3) is bonded in an L-shaped geometry to two equivalent Cu(1) atoms. Linkers: 2 [O]C(O)(c1ccccn1)c1ccccn1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 2.24 A, density 2.65 g/cm3, surface area 2837.58 m2/g, accessible volume 0.07 cm3/g