CoC12H12(NO)4CoC24H34(NO)4(CH2)4 is Indium-derived structured and crystallizes in the monoclinic P2 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, one CoC12H12(NO)4 cluster, and one CoC24H34(NO)4 cluster. In the CoC12H12(NO)4 cluster, Co(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Co(1)-N(1) bond lengths are 2.00 Å. Both Co(1)-O(1) bond lengths are 1.95 Å. There are six inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(4) atom. The C(5)-C(3) bond length is 1.37 Å. The C(5)-N(2) bond length is 1.38 Å. The C(5)-H(4) bond length is 1.08 Å. In the second C site, C(8) is bonded in a 4-coordinate geometry to one C(13), one N(2), one H(7), and one H(8) atom. The C(8)-C(13) bond length is 1.49 Å. The C(8)-N(2) bond length is 1.48 Å. The C(8)-H(7) bond length is 1.10 Å. The C(8)-H(8) bond length is 1.10 Å. In the third C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(17) atom. The C(13)-H(17) bond length is 1.09 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the fifth C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(1) bond length is 1.09 Å. In the sixth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(2) atom. The C(3)-N(1) bond length is 1.38 Å. The C(3)-H(2) bond length is 1.08 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(8) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the CoC24H34(NO)4 cluster, Co(2) is bonded in a tetrahedral geometry to two equivalent N(4) and two equivalent O(4) atoms. Both Co(2)-N(4) bond lengths are 2.01 Å. Both Co(2)-O(4) bond lengths are 1.96 Å. There are twelve inequivalent C sites. In the first C site, C(4) is bonded in a single-bond geometry to one C(6) and one H(3) atom. The C(4)-C(6) bond length is 1.58 Å. The C(4)-H(3) bond length is 1.10 Å. In the second C site, C(6) is bonded in a tetrahedral geometry to one C(10), one C(11), one C(4), and one C(9) atom. The C(6)-C(10) bond length is 1.54 Å. The C(6)-C(11) bond length is 1.53 Å. The C(6)-C(9) bond length is 1.58 Å. In the third C site, C(9) is bonded in a tetrahedral geometry to one C(12), one C(14), one C(15), and one C(6) atom. The C(9)-C(12) bond length is 1.54 Å. The C(9)-C(14) bond length is 1.53 Å. The C(9)-C(15) bond length is 1.53 Å. In the fourth C site, C(10) is bonded in a trigonal non-coplanar geometry to one C(6), one H(10), one H(11), and one H(9) atom. The C(10)-H(10) bond length is 1.10 Å. The C(10)-H(11) bond length is 1.10 Å. The C(10)-H(9) bond length is 1.10 Å. In the fifth C site, C(11) is bonded in a trigonal non-coplanar geometry to one C(6), one H(12), one H(13), and one H(14) atom. The C(11)-H(12) bond length is 1.10 Å. The C(11)-H(13) bond length is 1.10 Å. The C(11)-H(14) bond length is 1.10 Å. In the sixth C site, C(12) is bonded in a distorted water-like geometry to one C(9), one H(15), and one H(16) atom. The C(12)-H(15) bond length is 1.10 Å. The C(12)-H(16) bond length is 1.10 Å. In the seventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.25 Å. The C(14)-O(4) bond length is 1.30 Å. In the eighth C site, C(15) is bonded in a trigonal non-coplanar geometry to one C(9), one H(18), one H(19), and one H(20) atom. The C(15)-H(18) bond length is 1.10 Å. The C(15)-H(19) bond length is 1.10 Å. The C(15)-H(20) bond length is 1.10 Å. In the ninth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(23), and one H(24) atom. The C(17)-N(3) bond length is 1.46 Å. The C(17)-H(23) bond length is 1.10 Å. The C(17)-H(24) bond length is 1.10 Å. In the tenth C site, C(18) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(25) atom. The C(18)-N(3) bond length is 1.36 Å. The C(18)-N(4) bond length is 1.34 Å. The C(18)-H(25) bond length is 1.08 Å. In the eleventh C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(3), and one H(26) atom. The C(19)-C(20) bond length is 1.37 Å. The C(19)-N(3) bond length is 1.38 Å. The C(19)-H(26) bond length is 1.08 Å. In the twelfth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(4), and one H(27) atom. The C(20)-N(4) bond length is 1.38 Å. The C(20)-H(27) bond length is 1.08 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(19) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Co(2), one C(18), and one C(20) atom. There are seventeen inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(24) is bonded in a single-bond geometry to one C(17) atom. In the fifteenth H site, H(25) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(26) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(27) is bonded in a single-bond geometry to one C(20) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(14) atom. In the second O site, O(4) is bonded in a water-like geometry to one Co(2) and one C(14) atom. Linkers: 2 [CH](CCn1ccnc1)Cn1ccnc1 ,2 CC1(C)[C@@H](C([O])=O)CC[C@@]1(C)C([O])=O. Metal clusters: 2 O=[C]O[Co]O[C]=O. The MOF has largest included sphere 3.45 A, density 1.29 g/cm3, surface area 5142.36 m2/g, accessible volume 0.23 cm3/g