CHZnC14N3H10SO5 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a ZnC14N3H10SO5 framework. In the ZnC14N3H10SO5 framework, Zn(1) is bonded to one N(3), one O(1), one O(3), one O(4), and two equivalent O(5) atoms to form distorted edge-sharing ZnNO5 octahedra. The Zn(1)-N(3) bond length is 2.09 Å. The Zn(1)-O(1) bond length is 2.37 Å. The Zn(1)-O(3) bond length is 2.09 Å. The Zn(1)-O(4) bond length is 2.07 Å. There is one shorter (2.07 Å) and one longer (2.13 Å) Zn(1)-O(5) bond length. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-S(1) bond length is 1.77 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(3) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(4) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(4) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-N(1) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(5) atom. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(6) atom. The C(6)-H(6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one N(2) atom. The C(7)-C(12) bond length is 1.43 Å. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(2) bond length is 1.39 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(8)-H(7) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one O(5) atom. The C(10)-C(11) bond length is 1.45 Å. The C(10)-O(5) bond length is 1.31 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(3) atom. The C(11)-C(12) bond length is 1.42 Å. The C(11)-N(3) bond length is 1.36 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(7) atom. The C(12)-C(13) bond length is 1.41 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(9) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(14)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one N(3) and one H(11) atom. The C(15)-N(3) bond length is 1.33 Å. The C(15)-H(11) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one C(4) and one N(2) atom. The N(1)-N(2) bond length is 1.28 Å. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(7) and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(15) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(4) atom. The H(1)-O(4) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) atom. The H(2)-O(4) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.46 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.48 Å. There are five inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one S(1) atom. In the second O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one S(1) atom. In the third O site, O(4) is bonded in a distorted trigonal planar geometry to one Zn(1), one H(1), and one H(2) atom. In the fourth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Zn(1) and one C(10) atom. In the fifth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one S(1) atom. Linkers: 4 [O]c1ccc([N][N]c2ccc(S([O])([O])[O])cc2)c2cccnc12. Metal clusters: 4 [Zn]. The MOF has largest included sphere 2.69 A, density 1.78 g/cm3, surface area 3900.72 m2/g, accessible volume 0.14 cm3/g