AgC11H5(NO2)3C3NH4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 1-methylethenylamine molecules and two AgC11H5(NO2)3 clusters. In each AgC11H5(NO2)3 cluster, Ag(1) is bonded in a 3-coordinate geometry to one N(4), one O(1), and one O(3) atom. The Ag(1)-N(4) bond length is 2.36 Å. The Ag(1)-O(1) bond length is 2.24 Å. The Ag(1)-O(3) bond length is 2.22 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(12), one C(13), and one H(1) atom. The C(1)-C(12) bond length is 1.40 Å. The C(1)-C(13) bond length is 1.39 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(5) atom. The C(3)-C(11) bond length is 1.39 Å. The C(3)-C(13) bond length is 1.39 Å. The C(3)-H(5) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(4)-C(7) bond length is 1.41 Å. The C(4)-H(6) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(11), one C(12), and one H(7) atom. The C(5)-C(11) bond length is 1.40 Å. The C(5)-C(12) bond length is 1.40 Å. The C(5)-H(7) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(3) atom. The C(6)-C(12) bond length is 1.51 Å. The C(6)-O(1) bond length is 1.27 Å. The C(6)-O(3) bond length is 1.27 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(14), one C(4), and one C(8) atom. The C(7)-C(14) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.41 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(8) atom. The C(8)-H(8) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(3) atom. The C(11)-N(3) bond length is 1.46 Å. In the ninth C site, C(12) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(6) atom. In the tenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(1) atom. The C(13)-N(1) bond length is 1.47 Å. In the eleventh C site, C(14) is bonded in a distorted linear geometry to one C(7) and one N(4) atom. The C(14)-N(4) bond length is 1.17 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(13), one O(4), and one O(5) atom. The N(1)-O(4) bond length is 1.24 Å. The N(1)-O(5) bond length is 1.24 Å. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(11), one O(2), and one O(6) atom. The N(3)-O(2) bond length is 1.24 Å. The N(3)-O(6) bond length is 1.24 Å. In the third N site, N(4) is bonded in a 2-coordinate geometry to one Ag(1) and one C(14) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Ag(1) and one C(6) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one N(3) atom. In the fifth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one C(6) atom. In the sixth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. Linkers: 4 [O]C(=O)c1cc([N+](=O)[O-])cc([N+](=O)[O-])c1 ,4 N#Cc1ccc(N)cc1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 2.88 A, density 1.94 g/cm3, surface area 3812.22 m2/g, accessible volume 0.08 cm3/g