ZnC20N2H19O7(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one ZnC20N2H19O7 cluster. In the ZnC20N2H19O7 cluster, Zn(1) is bonded in a 6-coordinate geometry to one N(1), one O(1), one O(4), one O(5), one O(6), and one O(7) atom. The Zn(1)-N(1) bond length is 2.15 Å. The Zn(1)-O(1) bond length is 2.01 Å. The Zn(1)-O(4) bond length is 2.51 Å. The Zn(1)-O(5) bond length is 2.12 Å. The Zn(1)-O(6) bond length is 2.08 Å. The Zn(1)-O(7) bond length is 2.13 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one O(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-O(3) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(5) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one O(3) atom. The C(8)-O(3) bond length is 1.38 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-H(8) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(14) bond length is 1.49 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(9) atom. The C(12)-H(9) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(4), and one O(5) atom. The C(14)-O(4) bond length is 1.28 Å. The C(14)-O(5) bond length is 1.28 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one N(1), and one H(11) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-N(1) bond length is 1.35 Å. The C(15)-H(11) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one H(12) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(12) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(17), and one C(18) atom. The C(17)-C(17) bond length is 1.48 Å. The C(17)-C(18) bond length is 1.40 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(13) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(13) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(1), and one H(14) atom. The C(19)-N(1) bond length is 1.34 Å. The C(19)-H(14) bond length is 1.09 Å. In the eighteenth C site, C(20) is bonded in a trigonal planar geometry to one N(2), one H(15), and one O(6) atom. The C(20)-N(2) bond length is 1.33 Å. The C(20)-H(15) bond length is 1.10 Å. The C(20)-O(6) bond length is 1.26 Å. In the nineteenth C site, C(21) is bonded to one N(2), one H(16), one H(17), and one H(18) atom to form corner-sharing CH3N tetrahedra. The C(21)-N(2) bond length is 1.46 Å. The C(21)-H(16) bond length is 1.10 Å. The C(21)-H(17) bond length is 1.10 Å. The C(21)-H(18) bond length is 1.10 Å. In the twentieth C site, C(22) is bonded to one N(2), one H(19), one H(20), and one H(21) atom to form corner-sharing CH3N tetrahedra. The C(22)-N(2) bond length is 1.45 Å. The C(22)-H(19) bond length is 1.10 Å. The C(22)-H(20) bond length is 1.10 Å. The C(22)-H(21) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(19) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(20), one C(21), and one C(22) atom. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(7) atom. The H(1)-O(7) bond length is 1.00 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(2) and one O(7) atom. The H(2)-O(2) bond length is 1.62 Å. The H(2)-O(7) bond length is 1.02 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(21) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(22) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(22) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(22) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(1) and one H(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(5) and one C(8) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Zn(1) and one C(14) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Zn(1) and one C(14) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(20) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Zn(1), one H(1), and one H(2) atom. Linkers: 1 c1cc(-c2ccncc2)ccn1 ,2 [c]1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 4.65 A, density 1.32 g/cm3, surface area 5020.09 m2/g, accessible volume 0.35 cm3/g