CdC24H18(N5O2)2(CH)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two CdC24H18(N5O2)2 clusters. In each CdC24H18(N5O2)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(6), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.28 Å. The Cd(1)-N(6) bond length is 2.28 Å. The Cd(1)-O(1) bond length is 2.42 Å. The Cd(1)-O(2) bond length is 2.40 Å. The Cd(1)-O(3) bond length is 2.44 Å. The Cd(1)-O(4) bond length is 2.40 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(28), and one C(3) atom. The C(2)-C(28) bond length is 1.40 Å. The C(2)-C(3) bond length is 1.50 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(3)-O(1) bond length is 1.28 Å. The C(3)-O(2) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(3), and one O(4) atom. The C(4)-C(5) bond length is 1.50 Å. The C(4)-O(3) bond length is 1.27 Å. The C(4)-O(4) bond length is 1.29 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(7) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(6)-H(2) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(7)-H(3) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(4) atom. The C(8)-N(1) bond length is 1.33 Å. The C(8)-N(2) bond length is 1.36 Å. The C(8)-H(4) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(1), and one H(5) atom. The C(9)-C(10) bond length is 1.37 Å. The C(9)-N(1) bond length is 1.39 Å. The C(9)-H(5) bond length is 1.08 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(2), and one H(6) atom. The C(10)-N(2) bond length is 1.38 Å. The C(10)-H(6) bond length is 1.08 Å. In the eleventh C site, C(11) is bonded in a tetrahedral geometry to one N(2), one N(3), one H(7), and one H(8) atom. The C(11)-N(2) bond length is 1.46 Å. The C(11)-N(3) bond length is 1.44 Å. The C(11)-H(7) bond length is 1.10 Å. The C(11)-H(8) bond length is 1.10 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one N(3) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(17) bond length is 1.42 Å. The C(12)-N(3) bond length is 1.37 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(9) atom. The C(13)-H(9) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(12) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(12) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one N(5) atom. The C(17)-N(5) bond length is 1.38 Å. In the sixteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(6), and one H(13) atom. The C(18)-C(19) bond length is 1.37 Å. The C(18)-N(6) bond length is 1.38 Å. The C(18)-H(13) bond length is 1.08 Å. In the seventeenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(7), and one H(14) atom. The C(19)-N(7) bond length is 1.38 Å. The C(19)-H(14) bond length is 1.08 Å. In the eighteenth C site, C(20) is bonded in a trigonal planar geometry to one N(6), one N(7), and one H(15) atom. The C(20)-N(6) bond length is 1.33 Å. The C(20)-N(7) bond length is 1.36 Å. The C(20)-H(15) bond length is 1.09 Å. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(22), one C(26), and one N(8) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(26) bond length is 1.41 Å. The C(21)-N(8) bond length is 1.37 Å. In the twentieth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(16) atom. The C(22)-H(16) bond length is 1.09 Å. In the twenty-first C site, C(25) is bonded in a distorted single-bond geometry to one C(26) and one H(19) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-H(19) bond length is 1.09 Å. In the twenty-second C site, C(26) is bonded in a distorted trigonal planar geometry to one C(21), one C(25), and one N(10) atom. The C(26)-N(10) bond length is 1.38 Å. In the twenty-third C site, C(27) is bonded in a tetrahedral geometry to one N(7), one N(8), one H(20), and one H(21) atom. The C(27)-N(7) bond length is 1.45 Å. The C(27)-N(8) bond length is 1.44 Å. The C(27)-H(20) bond length is 1.09 Å. The C(27)-H(21) bond length is 1.10 Å. In the twenty-fourth C site, C(28) is bonded in a distorted single-bond geometry to one C(2) and one H(22) atom. The C(28)-H(22) bond length is 1.09 Å. There are ten inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(8), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(8) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(11), one C(12), and one N(4) atom. The N(3)-N(4) bond length is 1.37 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one N(3) and one N(5) atom. The N(4)-N(5) bond length is 1.30 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one C(17) and one N(4) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(18), and one C(20) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(19), one C(20), and one C(27) atom. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one C(21), one C(27), and one N(9) atom. The N(8)-N(9) bond length is 1.37 Å. In the ninth N site, N(9) is bonded in a water-like geometry to one N(10) and one N(8) atom. The N(9)-N(10) bond length is 1.30 Å. In the tenth N site, N(10) is bonded in a water-like geometry to one C(26) and one N(9) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(27) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(27) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(28) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(4) atom. In the second O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(3) atom. In the third O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(3) atom. In the fourth O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(4) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 2.33 A, density 1.69 g/cm3, surface area 4451.11 m2/g, accessible volume 0.10 cm3/g