CdC20H18(NO)4(CH2)4(CH)8 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules; eight 02329_fluka molecules; two 2,4-dimethyl-1,4-pentadiene molecules; and two CdC20H18(NO)4 clusters. In each CdC20H18(NO)4 cluster, Cd(1) is bonded in a distorted octahedral geometry to one N(1), one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.30 Å. The Cd(1)-N(3) bond length is 2.30 Å. The Cd(1)-O(1) bond length is 2.35 Å. The Cd(1)-O(2) bond length is 2.42 Å. The Cd(1)-O(3) bond length is 2.50 Å. The Cd(1)-O(4) bond length is 2.35 Å. There are twenty inequivalent C sites. In the first C site, C(32) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(32)-O(3) bond length is 1.27 Å. The C(32)-O(4) bond length is 1.28 Å. In the second C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(7), and one H(8) atom. The C(4)-N(4) bond length is 1.46 Å. The C(4)-H(7) bond length is 1.10 Å. The C(4)-H(8) bond length is 1.10 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(10), one C(6), and one N(4) atom. The C(5)-C(10) bond length is 1.41 Å. The C(5)-C(6) bond length is 1.40 Å. The C(5)-N(4) bond length is 1.39 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(9) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(9) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(10) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-H(10) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(11) atom. The C(8)-H(11) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(12) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(12) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one N(3) atom. The C(10)-N(3) bond length is 1.39 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(3), and one N(4) atom. The C(11)-C(12) bond length is 1.48 Å. The C(11)-N(3) bond length is 1.34 Å. The C(11)-N(4) bond length is 1.37 Å. In the tenth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one H(13), one H(14), and one H(15) atom. The C(12)-H(13) bond length is 1.09 Å. The C(12)-H(14) bond length is 1.10 Å. The C(12)-H(15) bond length is 1.10 Å. In the eleventh C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(18), and one H(19) atom. The C(14)-N(2) bond length is 1.46 Å. The C(14)-H(18) bond length is 1.10 Å. The C(14)-H(19) bond length is 1.10 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one N(2) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(20) bond length is 1.42 Å. The C(15)-N(2) bond length is 1.39 Å. In the thirteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(20) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(20) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(21) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-H(21) bond length is 1.09 Å. In the fifteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(22) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-H(22) bond length is 1.09 Å. In the sixteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(23) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(23) bond length is 1.09 Å. In the seventeenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(15), one C(19), and one N(1) atom. The C(20)-N(1) bond length is 1.39 Å. In the eighteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one N(1), and one N(2) atom. The C(21)-C(22) bond length is 1.48 Å. The C(21)-N(1) bond length is 1.34 Å. The C(21)-N(2) bond length is 1.37 Å. In the nineteenth C site, C(22) is bonded in a distorted trigonal non-coplanar geometry to one C(21), one H(24), one H(25), and one H(26) atom. The C(22)-H(24) bond length is 1.10 Å. The C(22)-H(25) bond length is 1.10 Å. The C(22)-H(26) bond length is 1.09 Å. In the twentieth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(23)-O(1) bond length is 1.28 Å. The C(23)-O(2) bond length is 1.27 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(20), and one C(21) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(21) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one C(11) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(11), one C(4), and one C(5) atom. There are eighteen inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(23) is bonded in a single-bond geometry to one C(19) atom. In the sixteenth H site, H(24) is bonded in a single-bond geometry to one C(22) atom. In the seventeenth H site, H(25) is bonded in a single-bond geometry to one C(22) atom. In the eighteenth H site, H(26) is bonded in a single-bond geometry to one C(22) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(23) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(23) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(32) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(32) atom. Linkers: 2 Cc1nc2ccccc2n1CCCCCCn1c(C)nc2ccccc21. Metal clusters: 2 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 2.49 A, density 1.49 g/cm3, surface area 4954.07 m2/g, accessible volume 0.22 cm3/g