CdC12H10(N4S)2(CH)2 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a CdC12H10(N4S)2 framework. In the CdC12H10(N4S)2 framework, Cd(1,2) is bonded in an octahedral geometry to two equivalent N(5), two equivalent N(8), and two equivalent S(1) atoms. Both Cd(1,2)-N(5) bond lengths are 2.35 Å. Both Cd(1,2)-N(8) bond lengths are 2.31 Å. Both Cd(1,2)-S(1) bond lengths are 2.77 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(7) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(3) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.51 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(8) atom. The C(2)-C(4) bond length is 1.40 Å. The C(2)-C(8) bond length is 1.51 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1) and one H(1,2) atom. The C(3)-H(1,2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(1,2) atom. The C(4)-H(1,2) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(1); one N(1,2); one H(5,6); and one H(7,8) atom. The C(7)-N(1,2) bond length is 1.47 Å. The C(7)-H(5,6) bond length is 1.10 Å. The C(7)-H(7,8) bond length is 1.10 Å. In the sixth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(2); one N(1,2); one H(5,6); and one H(7,8) atom. The C(8)-N(1,2) bond length is 1.47 Å. The C(8)-H(5,6) bond length is 1.10 Å. The C(8)-H(7,8) bond length is 1.10 Å. In the seventh C site, C(9,10) is bonded in a trigonal planar geometry to one N(3,4); one N(5); and one H(9,10) atom. The C(9,10)-N(3,4) bond length is 1.33 Å. The C(9,10)-N(5) bond length is 1.36 Å. The C(9,10)-H(9,10) bond length is 1.08 Å. In the eighth C site, C(11,12) is bonded in a trigonal planar geometry to one N(1,2); one N(5); and one H(11,12) atom. The C(11,12)-N(1,2) bond length is 1.35 Å. The C(11,12)-N(5) bond length is 1.34 Å. The C(11,12)-H(11,12) bond length is 1.09 Å. In the ninth C site, C(13,14) is bonded in a distorted linear geometry to one N(7) and one S(1) atom. The C(13,14)-N(7) bond length is 1.19 Å. The C(13,14)-S(1) bond length is 1.63 Å. There are six inequivalent N sites. In the first N site, N(1,2) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(7); and one N(3,4) atom. The N(1,2)-N(3,4) bond length is 1.37 Å. In the second N site, N(3,4) is bonded in a distorted water-like geometry to one C(9,10) and one N(1,2) atom. In the third N site, N(5) is bonded in a distorted trigonal planar geometry to one Cd(1,2); one C(11,12); and one C(9,10) atom. In the fourth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cd(1,2); one C(11,12); and one C(9,10) atom. The N(6)-Cd(1,2) bond length is 2.35 Å. The N(6)-C(11,12) bond length is 1.34 Å. The N(6)-C(9,10) bond length is 1.36 Å. In the fifth N site, N(7) is bonded in a distorted bent 150 degrees geometry to one Cd(1,2) and one C(13,14) atom. The N(7)-Cd(1,2) bond length is 2.31 Å. In the sixth N site, N(8) is bonded in a distorted bent 150 degrees geometry to one Cd(1,2) and one C(13,14) atom. The N(8)-C(13,14) bond length is 1.19 Å. There are five inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(5,6) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(7,8) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(9,10) is bonded in a single-bond geometry to one C(9,10) atom. In the fifth H site, H(11,12) is bonded in a single-bond geometry to one C(11,12) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Cd(1,2) and one C(13,14) atom. In the second S site, S(2) is bonded in a water-like geometry to one Cd(1,2) and one C(13,14) atom. The S(2)-Cd(1,2) bond length is 2.77 Å. The S(2)-C(13,14) bond length is 1.63 Å. Linkers: 2 [CH]1N=C[N]N1Cc1ccccc1Cn1cncn1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 1.76 A, density 1.89 g/cm3, surface area 4280.27 m2/g, accessible volume 0.13 cm3/g