AuC9PH6ClAuC7PH4Cl(CH)10 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty 02329_fluka molecules, one AuC7PH4Cl cluster, and one AuC9PH6Cl cluster. In the AuC7PH4Cl cluster, Au(2) is bonded in a linear geometry to one P(2) and one Cl(2) atom. The Au(2)-P(2) bond length is 2.24 Å. The Au(2)-Cl(2) bond length is 2.31 Å. There are seven inequivalent C sites. In the first C site, C(26) is bonded in a distorted single-bond geometry to one C(16) and one H(20) atom. The C(26)-C(16) bond length is 1.40 Å. The C(26)-H(20) bond length is 1.09 Å. In the second C site, C(14) is bonded in a distorted single-bond geometry to one C(4) and one H(10) atom. The C(14)-C(4) bond length is 1.40 Å. The C(14)-H(10) bond length is 1.09 Å. In the third C site, C(16) is bonded in a trigonal planar geometry to one C(18), one C(26), and one P(2) atom. The C(16)-C(18) bond length is 1.40 Å. The C(16)-P(2) bond length is 1.82 Å. In the fourth C site, C(2) is bonded in a linear geometry to one C(2) and one P(2) atom. The C(2)-C(2) bond length is 1.22 Å. The C(2)-P(2) bond length is 1.75 Å. In the fifth C site, C(18) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(18)-H(12) bond length is 1.09 Å. In the sixth C site, C(4) is bonded in a trigonal planar geometry to one C(14), one C(6), and one P(2) atom. The C(4)-C(6) bond length is 1.40 Å. The C(4)-P(2) bond length is 1.81 Å. In the seventh C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(6)-H(2) bond length is 1.09 Å. P(2) is bonded in a tetrahedral geometry to one Au(2), one C(16), one C(2), and one C(4) atom. There are four inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(20) is bonded in a single-bond geometry to one C(26) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. Cl(2) is bonded in a single-bond geometry to one Au(2) atom. In the AuC9PH6Cl cluster, Au(1) is bonded in a linear geometry to one P(1) and one Cl(1) atom. The Au(1)-P(1) bond length is 2.24 Å. The Au(1)-Cl(1) bond length is 2.31 Å. There are nine inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(9)-C(7) bond length is 1.40 Å. The C(9)-H(5) bond length is 1.09 Å. In the second C site, C(25) is bonded in a distorted single-bond geometry to one C(15) and one H(19) atom. The C(25)-C(15) bond length is 1.40 Å. The C(25)-H(19) bond length is 1.09 Å. In the third C site, C(13) is bonded in a distorted single-bond geometry to one C(3) and one H(9) atom. The C(13)-C(3) bond length is 1.40 Å. The C(13)-H(9) bond length is 1.09 Å. In the fourth C site, C(15) is bonded in a trigonal planar geometry to one C(17), one C(25), and one P(1) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-P(1) bond length is 1.82 Å. In the fifth C site, C(1) is bonded in a linear geometry to one C(1) and one P(1) atom. The C(1)-C(1) bond length is 1.22 Å. The C(1)-P(1) bond length is 1.75 Å. In the sixth C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one H(11) atom. The C(17)-H(11) bond length is 1.09 Å. In the seventh C site, C(3) is bonded in a trigonal planar geometry to one C(13), one C(5), and one P(1) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-P(1) bond length is 1.81 Å. In the eighth C site, C(5) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(1) atom. The C(5)-C(7) bond length is 1.39 Å. The C(5)-H(1) bond length is 1.09 Å. In the ninth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one H(3) atom. The C(7)-H(3) bond length is 1.09 Å. P(1) is bonded in a tetrahedral geometry to one Au(1), one C(1), one C(15), and one C(3) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. Cl(1) is bonded in a single-bond geometry to one Au(1) atom. Linkers: 4 C(#CP(c1ccccc1)c1ccccc1)P(c1c[c]ccc1)c1ccccc1 ,2 C(#CP(c1ccccc1)c1ccccc1)P(c1ccccc1)c1ccccc1 ,4 C(#CP(c1ccccc1)c1ccccc1)P(c1cc[c]cc1)c1ccccc1. Metal clusters: . The MOF has largest included sphere 2.46 A, density 2.29 g/cm3, surface area 3410.54 m2/g, accessible volume 0.10 cm3/g