ErC29N7H29O16(CH)7 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two propylene molecules, and one ErC29N7H29O16 cluster. In the ErC29N7H29O16 cluster, Er(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(13), one O(14), one O(16), one O(4), one O(7), and one O(8) atom. The Er(1)-O(1) bond length is 2.26 Å. The Er(1)-O(10) bond length is 2.49 Å. The Er(1)-O(11) bond length is 2.41 Å. The Er(1)-O(13) bond length is 2.41 Å. The Er(1)-O(14) bond length is 2.48 Å. The Er(1)-O(16) bond length is 2.27 Å. The Er(1)-O(4) bond length is 2.27 Å. The Er(1)-O(7) bond length is 2.42 Å. The Er(1)-O(8) bond length is 2.46 Å. There are twenty-nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one O(1) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-O(1) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.42 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(2) and one O(2) atom. The C(3)-O(2) bond length is 1.36 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(8) atom. The C(7)-H(8) bond length is 1.09 Å. In the fifth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one H(10), one H(9), and one O(2) atom. The C(8)-C(10) bond length is 1.50 Å. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. The C(8)-O(2) bond length is 1.45 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one O(3) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-O(3) bond length is 1.37 Å. In the seventh C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(8), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(11) atom. The C(11)-H(11) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a tetrahedral geometry to one H(12), one H(13), one H(14), and one O(3) atom. The C(12)-H(12) bond length is 1.10 Å. The C(12)-H(13) bond length is 1.09 Å. The C(12)-H(14) bond length is 1.10 Å. The C(12)-O(3) bond length is 1.43 Å. In the tenth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one C(14), one N(1), one H(15), and one H(16) atom. The C(13)-C(14) bond length is 1.51 Å. The C(13)-N(1) bond length is 1.46 Å. The C(13)-H(15) bond length is 1.10 Å. The C(13)-H(16) bond length is 1.10 Å. In the eleventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one N(2) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-N(2) bond length is 1.35 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(17) atom. The C(15)-H(17) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(18) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(18) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(19) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(19) bond length is 1.09 Å. In the fifteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(2), and one H(20) atom. The C(18)-N(2) bond length is 1.34 Å. The C(18)-H(20) bond length is 1.09 Å. In the sixteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(3), and one O(4) atom. The C(19)-C(20) bond length is 1.49 Å. The C(19)-N(3) bond length is 1.34 Å. The C(19)-O(4) bond length is 1.26 Å. In the seventeenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(25) atom. The C(20)-C(21) bond length is 1.42 Å. The C(20)-C(25) bond length is 1.40 Å. In the eighteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one O(5) atom. The C(21)-O(5) bond length is 1.36 Å. In the nineteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(20) and one H(24) atom. The C(25)-H(24) bond length is 1.09 Å. In the twentieth C site, C(26) is bonded in a distorted trigonal non-coplanar geometry to one C(28), one H(25), one H(26), and one O(5) atom. The C(26)-C(28) bond length is 1.50 Å. The C(26)-H(25) bond length is 1.10 Å. The C(26)-H(26) bond length is 1.10 Å. The C(26)-O(5) bond length is 1.46 Å. In the twenty-first C site, C(27) is bonded in a distorted single-bond geometry to one C(28), one C(29), and one O(6) atom. The C(27)-C(28) bond length is 1.41 Å. The C(27)-C(29) bond length is 1.40 Å. The C(27)-O(6) bond length is 1.37 Å. In the twenty-second C site, C(28) is bonded in a trigonal planar geometry to one C(26), one C(27), and one C(29) atom. The C(28)-C(29) bond length is 1.40 Å. In the twenty-third C site, C(29) is bonded in a distorted trigonal planar geometry to one C(27), one C(28), and one H(27) atom. The C(29)-H(27) bond length is 1.09 Å. In the twenty-fourth C site, C(30) is bonded in a tetrahedral geometry to one H(28), one H(29), one H(30), and one O(6) atom. The C(30)-H(28) bond length is 1.10 Å. The C(30)-H(29) bond length is 1.09 Å. The C(30)-H(30) bond length is 1.10 Å. The C(30)-O(6) bond length is 1.43 Å. In the twenty-fifth C site, C(31) is bonded in a distorted trigonal non-coplanar geometry to one C(32), one N(3), one H(31), and one H(32) atom. The C(31)-C(32) bond length is 1.52 Å. The C(31)-N(3) bond length is 1.45 Å. The C(31)-H(31) bond length is 1.10 Å. The C(31)-H(32) bond length is 1.10 Å. In the twenty-sixth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31), one C(36), and one N(4) atom. The C(32)-C(36) bond length is 1.40 Å. The C(32)-N(4) bond length is 1.35 Å. In the twenty-seventh C site, C(33) is bonded in a distorted trigonal planar geometry to one C(34), one N(4), and one H(33) atom. The C(33)-C(34) bond length is 1.39 Å. The C(33)-N(4) bond length is 1.34 Å. The C(33)-H(33) bond length is 1.09 Å. In the twenty-eighth C site, C(34) is bonded in a distorted single-bond geometry to one C(33) and one H(34) atom. The C(34)-H(34) bond length is 1.09 Å. In the twenty-ninth C site, C(36) is bonded in a distorted single-bond geometry to one C(32) and one H(36) atom. The C(36)-H(36) bond length is 1.09 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(13), and one H(1) atom. The N(1)-H(1) bond length is 1.02 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(14), one C(18), and one H(3) atom. The N(2)-H(3) bond length is 1.68 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(19), one C(31), and one H(2) atom. The N(3)-H(2) bond length is 1.02 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(32), one C(33), and one H(4) atom. The N(4)-H(4) bond length is 1.64 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. The N(5)-O(7) bond length is 1.29 Å. The N(5)-O(8) bond length is 1.29 Å. The N(5)-O(9) bond length is 1.23 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one O(10), one O(11), and one O(12) atom. The N(6)-O(10) bond length is 1.28 Å. The N(6)-O(11) bond length is 1.29 Å. The N(6)-O(12) bond length is 1.24 Å. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one O(13), one O(14), and one O(15) atom. The N(7)-O(13) bond length is 1.29 Å. The N(7)-O(14) bond length is 1.29 Å. The N(7)-O(15) bond length is 1.23 Å. There are twenty-nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one N(2) and one O(16) atom. The H(3)-O(16) bond length is 1.02 Å. In the fourth H site, H(4) is bonded in a distorted linear geometry to one N(4) and one O(16) atom. The H(4)-O(16) bond length is 1.02 Å. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(13) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the eighteenth H site, H(24) is bonded in a single-bond geometry to one C(25) atom. In the nineteenth H site, H(25) is bonded in a single-bond geometry to one C(26) atom. In the twentieth H site, H(26) is bonded in a single-bond geometry to one C(26) atom. In the twenty-first H site, H(27) is bonded in a single-bond geometry to one C(29) atom. In the twenty-second H site, H(28) is bonded in a single-bond geometry to one C(30) atom. In the twenty-third H site, H(29) is bonded in a single-bond geometry to one C(30) atom. In the twenty-fourth H site, H(30) is bonded in a single-bond geometry to one C(30) atom. In the twenty-fifth H site, H(31) is bonded in a single-bond geometry to one C(31) atom. In the twenty-sixth H site, H(32) is bonded in a single-bond geometry to one C(31) atom. In the twenty-seventh H site, H(33) is bonded in a single-bond geometry to one C(33) atom. In the twenty-eighth H site, H(34) is bonded in a single-bond geometry to one C(34) atom. In the twenty-ninth H site, H(36) is bonded in a single-bond geometry to one C(36) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Er(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(3) and one C(8) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(12) and one C(9) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Er(1) and one C(19) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one C(21) and one C(26) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one C(27) and one C(30) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Er(1) and one N(5) atom. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one Er(1) and one N(5) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one N(5) atom. In the tenth O site, O(10) is bonded in a distorted L-shaped geometry to one Er(1) and one N(6) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Er(1) and one N(6) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one N(6) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one Er(1) and one N(7) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Er(1) and one N(7) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one N(7) atom. In the sixteenth O site, O(16) is bonded in a distorted water-like geometry to one Er(1), one H(3), and one H(4) atom. Linkers: 2 COc1cc(COc2ccccc2C(=O)NCc2ccccn2)c(OC)cc1COc1ccccc1C(=O)NCc1ccccn1. Metal clusters: 2 [Er]. The MOF has largest included sphere 3.91 A, density 1.55 g/cm3, surface area 4330.37 m2/g, accessible volume 0.20 cm3/g