CuC8N5H7O3(CH)2CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 02329_fluka molecules, and one CuC8N5H7O3 cluster. In the CuC8N5H7O3 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one N(4), two equivalent N(1), and one O(1) atom. The Cu(1)-N(4) bond length is 1.99 Å. There is one shorter (2.00 Å) and one longer (2.01 Å) Cu(1)-N(1) bond length. The Cu(1)-O(1) bond length is 1.97 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(1) atom. The C(1)-N(4) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-C(6) bond length is 1.51 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(4), and one H(4) atom. The C(5)-N(4) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted water-like geometry to one C(4), one N(5), and one H(11) atom. The C(6)-N(5) bond length is 1.47 Å. The C(6)-H(11) bond length is 1.10 Å. In the sixth C site, C(7) is bonded in a tetrahedral geometry to one N(5), one H(5), one H(6), and one H(7) atom. The C(7)-N(5) bond length is 1.45 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. The C(7)-H(7) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(5) and one O(3) atom. The C(8)-N(5) bond length is 1.36 Å. The C(8)-O(3) bond length is 1.25 Å. In the eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(11)-O(1) bond length is 1.30 Å. The C(11)-O(2) bond length is 1.25 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to two equivalent Cu(1) and one N(2) atom. The N(1)-N(2) bond length is 1.22 Å. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.16 Å. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(6), one C(7), and one C(8) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(6) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(11) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(11) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(8) atom. Linkers: 2 [N][N][N]. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.01 A, density 1.82 g/cm3, surface area 3975.40 m2/g, accessible volume 0.08 cm3/g