(C3H2)2ZnC14H14(N2Cl)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 2,3-dimethyl-1,3-butadiene molecules and two ZnC14H14(N2Cl)2 clusters. In each ZnC14H14(N2Cl)2 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1,2) and two equivalent Cl(1,2) atoms. Both Zn(1)-N(1,2) bond lengths are 2.04 Å. Both Zn(1)-Cl(1,2) bond lengths are 2.25 Å. There are ten inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal planar geometry to one C(3,4); one N(1,2); and one H(1,2) atom. The C(1,2)-C(3,4) bond length is 1.37 Å. The C(1,2)-N(1,2) bond length is 1.38 Å. The C(1,2)-H(1,2) bond length is 1.08 Å. In the second C site, C(3,4) is bonded in a distorted bent 120 degrees geometry to one C(1,2); one N(3,4); and one H(3,4) atom. The C(3,4)-N(3,4) bond length is 1.38 Å. The C(3,4)-H(3,4) bond length is 1.08 Å. In the third C site, C(5,6) is bonded in a trigonal planar geometry to one N(1,2); one N(3,4); and one H(5,6) atom. The C(5,6)-N(1,2) bond length is 1.33 Å. The C(5,6)-N(3,4) bond length is 1.35 Å. The C(5,6)-H(5,6) bond length is 1.08 Å. In the fourth C site, C(7) is bonded in a 3-coordinate geometry to one C(9,10); one N(3,4); one H(7,8); and one H(9,10) atom. The C(7)-C(9,10) bond length is 1.50 Å. The C(7)-N(3,4) bond length is 1.47 Å. The C(7)-H(7,8) bond length is 1.10 Å. The C(7)-H(9,10) bond length is 1.10 Å. In the fifth C site, C(8) is bonded in a 3-coordinate geometry to one C(9,10); one N(3,4); one H(7,8); and one H(9,10) atom. The C(8)-C(9,10) bond length is 1.50 Å. The C(8)-N(3,4) bond length is 1.47 Å. The C(8)-H(7,8) bond length is 1.10 Å. The C(8)-H(9,10) bond length is 1.10 Å. In the sixth C site, C(9,10) is bonded in a trigonal planar geometry to one C(11), one C(19), and one C(7) atom. The C(9,10)-C(11) bond length is 1.40 Å. The C(9,10)-C(19) bond length is 1.40 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(9,10) and one H(11,12) atom. The C(11)-H(11,12) bond length is 1.09 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(9,10) and one H(11,12) atom. The C(12)-C(9,10) bond length is 1.40 Å. The C(12)-H(11,12) bond length is 1.09 Å. In the ninth C site, C(19) is bonded in a distorted single-bond geometry to one C(9,10) and one H(17,18) atom. The C(19)-H(17,18) bond length is 1.09 Å. In the tenth C site, C(20) is bonded in a distorted single-bond geometry to one C(9,10) and one H(17,18) atom. The C(20)-C(9,10) bond length is 1.40 Å. The C(20)-H(17,18) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1,2) is bonded in a trigonal planar geometry to one Zn(1); one C(1,2); and one C(5,6) atom. In the second N site, N(3,4) is bonded in a trigonal planar geometry to one C(3,4); one C(5,6); and one C(7) atom. There are seven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(3,4) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(5,6) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(17,18) is bonded in a single-bond geometry to one C(19) atom. Cl(1,2) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 2 c1cn(Cc2ccc(-c3ccc(Cn4ccnc4)cc3)cc2)cn1. Metal clusters: 2 Cl[Zn]Cl. The MOF has largest included sphere 1.62 A, density 1.63 g/cm3, surface area 4927.99 m2/g, accessible volume 0.11 cm3/g