ZnC7H6(NO3)2(CH2)3 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and four ZnC7H6(NO3)2 clusters. In each ZnC7H6(NO3)2 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(3), one O(4), and one O(5) atom. The Zn(1)-O(1) bond length is 2.02 Å. The Zn(1)-O(3) bond length is 1.99 Å. The Zn(1)-O(4) bond length is 2.03 Å. The Zn(1)-O(5) bond length is 1.99 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a 3-coordinate geometry to one C(2), one N(1), and one O(1) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-N(1) bond length is 1.33 Å. The C(1)-O(1) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one C(1), one H(5), and one H(6) atom. The C(2)-H(5) bond length is 1.10 Å. The C(2)-H(6) bond length is 1.10 Å. In the third C site, C(4) is bonded in a distorted water-like geometry to one N(1) and one H(1) atom. The C(4)-N(1) bond length is 1.45 Å. The C(4)-H(1) bond length is 1.10 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(5)-O(2) bond length is 1.25 Å. The C(5)-O(3) bond length is 1.30 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(4) atom. The C(6)-N(2) bond length is 1.33 Å. The C(6)-O(4) bond length is 1.26 Å. In the sixth C site, C(9) is bonded in a distorted water-like geometry to one N(2) and one H(3) atom. The C(9)-N(2) bond length is 1.46 Å. The C(9)-H(3) bond length is 1.10 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(10)-O(5) bond length is 1.29 Å. The C(10)-O(6) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(4), and one H(2) atom. The N(1)-H(2) bond length is 1.04 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(6), one C(9), and one H(4) atom. The N(2)-H(4) bond length is 1.02 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Zn(1) and one C(10) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(10) atom. Linkers: 8 [O]C(=O)[C@@H]1CCC(=O)N1. Metal clusters: 4 [O][Zn]([O])(O[C]=O)O[C]=O. RCSR code: dia. The MOF has largest included sphere 2.26 A, density 1.74 g/cm3, surface area 4396.44 m2/g, accessible volume 0.12 cm3/g