(CH2)2CdC4H8SO6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two CdC4H8SO6 clusters. In each CdC4H8SO6 cluster, Cd(1) is bonded in a distorted pentagonal bipyramidal geometry to one S(1), one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Cd(1)-S(1) bond length is 2.68 Å. The Cd(1)-O(1) bond length is 2.42 Å. The Cd(1)-O(2) bond length is 2.45 Å. The Cd(1)-O(3) bond length is 2.66 Å. The Cd(1)-O(4) bond length is 2.31 Å. The Cd(1)-O(5) bond length is 2.59 Å. The Cd(1)-O(6) bond length is 2.34 Å. There are four inequivalent C sites. In the first C site, C(2) is bonded in a distorted water-like geometry to one H(3), one H(4), and one S(1) atom. The C(2)-H(3) bond length is 1.09 Å. The C(2)-H(4) bond length is 1.10 Å. The C(2)-S(1) bond length is 1.81 Å. In the second C site, C(3) is bonded in a distorted water-like geometry to one H(5), one H(6), and one S(1) atom. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(6) bond length is 1.09 Å. The C(3)-S(1) bond length is 1.82 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(5)-O(1) bond length is 1.28 Å. The C(5)-O(2) bond length is 1.28 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(6)-O(5) bond length is 1.26 Å. The C(6)-O(6) bond length is 1.29 Å. There are eight inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one O(3) atom. The H(9)-O(3) bond length is 0.99 Å. In the sixth H site, H(10) is bonded in a single-bond geometry to one O(3) atom. The H(10)-O(3) bond length is 1.00 Å. In the seventh H site, H(11) is bonded in a distorted single-bond geometry to one O(4) and one O(6) atom. The H(11)-O(4) bond length is 1.00 Å. The H(11)-O(6) bond length is 1.67 Å. In the eighth H site, H(12) is bonded in a single-bond geometry to one O(4) atom. The H(12)-O(4) bond length is 0.99 Å. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Cd(1), one C(2), and one C(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(5) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(5) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cd(1), one H(10), and one H(9) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Cd(1), one H(11), and one H(12) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Cd(1) and one C(6) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Cd(1), one C(6), and one H(11) atom. Linkers: 4 [O]C(=O)CCSCCC([O])=O. Metal clusters: 4 O.O.O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 2.02 A, density 2.14 g/cm3, surface area 3560.94 m2/g, accessible volume 0.11 cm3/g