CoC8H12(NO)6(CH2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CoC8H12(NO)6 clusters. In each CoC8H12(NO)6 cluster, Co(1) is bonded in an octahedral geometry to two equivalent N(3), two equivalent O(1), and two equivalent O(3) atoms. Both Co(1)-N(3) bond lengths are 2.11 Å. Both Co(1)-O(1) bond lengths are 2.09 Å. Both Co(1)-O(3) bond lengths are 2.11 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(1) atom. The C(1)-N(2) bond length is 1.33 Å. The C(1)-N(3) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(3) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(3), and one H(4) atom. The C(3)-N(1) bond length is 1.46 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(4) bond length is 1.10 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(5)-O(1) bond length is 1.28 Å. The C(5)-O(2) bond length is 1.27 Å. There are three inequivalent N sites. In the first N site, N(2) is bonded in a distorted single-bond geometry to one C(1) and one N(1) atom. The N(2)-N(1) bond length is 1.36 Å. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one N(2) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Co(1), one C(1), and one C(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7) is bonded in a distorted single-bond geometry to one O(2) and one O(3) atom. The H(7)-O(2) bond length is 1.68 Å. The H(7)-O(3) bond length is 1.01 Å. In the sixth H site, H(8) is bonded in a single-bond geometry to one O(3) atom. The H(8)-O(3) bond length is 0.99 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(5) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one C(5) and one H(7) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Co(1), one H(7), and one H(8) atom. Linkers: 4 [O]C(=O)CCn1cncn1. Metal clusters: 2 O.O.O=[C]O[Co]O[C]=O. The MOF has largest included sphere 2.88 A, density 1.64 g/cm3, surface area 4336.71 m2/g, accessible volume 0.15 cm3/g