AuC15PH12Cl is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight AuC15PH12Cl clusters. Au(1) is bonded in a linear geometry to one P(1) and one Cl(1) atom. The Au(1)-P(1) bond length is 2.24 Å. The Au(1)-Cl(1) bond length is 2.30 Å. There are fifteen inequivalent C sites. In the first C site, C(5) is bonded in a trigonal planar geometry to one C(6), one C(7), and one P(1) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(7) bond length is 1.41 Å. The C(5)-P(1) bond length is 1.82 Å. In the second C site, C(6) is bonded in a distorted trigonal planar geometry to one C(13), one C(5), and one H(4) atom. The C(6)-C(13) bond length is 1.40 Å. The C(6)-H(4) bond length is 1.09 Å. In the third C site, C(7) is bonded in a distorted trigonal planar geometry to one C(14), one C(5), and one H(5) atom. The C(7)-C(14) bond length is 1.39 Å. The C(7)-H(5) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(9), and one P(1) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. The C(8)-P(1) bond length is 1.81 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(15), one C(8), and one H(6) atom. The C(9)-C(15) bond length is 1.39 Å. The C(9)-H(6) bond length is 1.09 Å. In the sixth C site, C(10) is bonded in a distorted single-bond geometry to one C(15), one C(2), and one H(7) atom. The C(10)-C(15) bond length is 1.40 Å. The C(10)-C(2) bond length is 1.40 Å. The C(10)-H(7) bond length is 1.09 Å. In the seventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(13), one C(14), and one H(8) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-C(14) bond length is 1.40 Å. The C(11)-H(8) bond length is 1.09 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(2), one C(8), and one H(9) atom. The C(12)-C(2) bond length is 1.40 Å. The C(12)-H(9) bond length is 1.09 Å. In the ninth C site, C(13) is bonded in a distorted single-bond geometry to one C(11), one C(6), and one H(10) atom. The C(13)-H(10) bond length is 1.09 Å. In the tenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(11), one C(7), and one H(11) atom. The C(14)-H(11) bond length is 1.09 Å. In the eleventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(10), one C(9), and one H(12) atom. The C(15)-H(12) bond length is 1.09 Å. In the twelfth C site, C(1) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(1)-C(3) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the thirteenth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the fourteenth C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(4), and one P(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-P(1) bond length is 1.82 Å. In the fifteenth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. P(1) is bonded in a tetrahedral geometry to one Au(1), one C(3), one C(5), and one C(8) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. Cl(1) is bonded in a single-bond geometry to one Au(1) atom. Linkers: 2 [c]1cccc(P(c2ccccc2)c2ccc(P(c3ccccc3)c3ccccc3)cc2)c1 ,2 c1ccc(P(c2ccccc2)c2ccc(P(c3ccccc3)c3ccccc3)cc2)cc1 ,4 [CH]C(=[CH])P(c1ccccc1)c1ccc(P(c2ccccc2)c2ccccc2)cc1. Metal clusters: . The MOF has largest included sphere 1.81 A, density 2.30 g/cm3, surface area 3503.09 m2/g, accessible volume 0.10 cm3/g