Co3C46H38S(N4O9)2(CH)6 crystallizes in the monoclinic C2/c space group. The structure consists of twenty-four 02329_fluka molecules inside a Co3C46H38S(N4O9)2 framework. In the Co3C46H38S(N4O9)2 framework, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(1), one O(1), one O(4), one O(5), one O(6), and one O(9) atom to form CoNO5 octahedra that share  a cornercorner with one Co(2)N2O4 octahedra and  a cornercorner with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 55°. The Co(1)-N(1) bond length is 2.08 Å. The Co(1)-O(1) bond length is 2.06 Å. The Co(1)-O(4) bond length is 2.16 Å. The Co(1)-O(5) bond length is 2.10 Å. The Co(1)-O(6) bond length is 2.13 Å. The Co(1)-O(9) bond length is 2.05 Å. In the second Co site, Co(2) is bonded to two equivalent N(4), two equivalent O(6), and two equivalent O(8) atoms to form CoN2O4 octahedra that share corners with two equivalent Co(1)NO5 octahedra and  an edgeedge with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 55°. Both Co(2)-N(4) bond lengths are 2.11 Å. Both Co(2)-O(6) bond lengths are 2.22 Å. Both Co(2)-O(8) bond lengths are 1.97 Å. There are twenty-three inequivalent C sites. In the first C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(15) atom. The C(18)-C(17) bond length is 1.40 Å. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(15) bond length is 1.09 Å. In the second C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(1), and one H(16) atom. The C(19)-N(1) bond length is 1.35 Å. The C(19)-H(16) bond length is 1.09 Å. In the third C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(2), and one H(17) atom. The C(20)-C(17) bond length is 1.45 Å. The C(20)-N(2) bond length is 1.30 Å. The C(20)-H(17) bond length is 1.10 Å. In the fourth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(3), and one H(18) atom. The C(21)-C(22) bond length is 1.45 Å. The C(21)-N(3) bond length is 1.30 Å. The C(21)-H(18) bond length is 1.10 Å. In the fifth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(24) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(24) bond length is 1.40 Å. In the sixth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(26), and one H(19) atom. The C(23)-C(26) bond length is 1.39 Å. The C(23)-H(19) bond length is 1.09 Å. In the seventh C site, C(24) is bonded in a distorted single-bond geometry to one C(22), one C(25), and one H(20) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-H(20) bond length is 1.09 Å. In the eighth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one N(4), and one H(21) atom. The C(25)-N(4) bond length is 1.35 Å. The C(25)-H(21) bond length is 1.09 Å. In the ninth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(23), one N(4), and one H(22) atom. The C(26)-N(4) bond length is 1.35 Å. The C(26)-H(22) bond length is 1.09 Å. In the tenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(8), and one O(9) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(8) bond length is 1.28 Å. The C(1)-O(9) bond length is 1.27 Å. In the eleventh C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(6) bond length is 1.40 Å. In the twelfth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(5) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(5) bond length is 1.09 Å. In the thirteenth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one H(6) atom. The C(4)-C(7) bond length is 1.40 Å. The C(4)-H(6) bond length is 1.09 Å. In the fourteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(2) and one H(8) atom. The C(6)-H(8) bond length is 1.09 Å. In the fifteenth C site, C(7) is bonded in a distorted single-bond geometry to one C(4) and one O(3) atom. The C(7)-O(3) bond length is 1.38 Å. In the sixteenth C site, C(8) is bonded in a distorted single-bond geometry to one O(3) atom. The C(8)-O(3) bond length is 1.38 Å. In the seventeenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(10) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(10) bond length is 1.09 Å. In the eighteenth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(14) bond length is 1.49 Å. In the nineteenth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(11) atom. The C(12)-H(11) bond length is 1.09 Å. In the twentieth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(1), and one O(2) atom. The C(14)-O(1) bond length is 1.28 Å. The C(14)-O(2) bond length is 1.27 Å. In the twenty-first C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(15)-N(1) bond length is 1.36 Å. The C(15)-H(13) bond length is 1.09 Å. In the twenty-second C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(14) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-H(14) bond length is 1.09 Å. In the twenty-third C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(15), and one C(19) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(20) and one N(3) atom. The N(2)-N(3) bond length is 1.38 Å. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one C(21) and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(2), one C(25), and one C(26) atom. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one O(4) atom. The H(1)-O(2) bond length is 1.66 Å. The H(1)-O(4) bond length is 1.01 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) atom. The H(2)-O(4) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(5) atom. The H(3)-O(5) bond length is 0.98 Å. In the fourth H site, H(4) is bonded in a linear geometry to one O(2) and one O(5) atom. The H(4)-O(2) bond length is 1.59 Å. The H(4)-O(5) bond length is 1.00 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(20) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(21) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(25) atom. In the nineteenth H site, H(22) is bonded in a single-bond geometry to one C(26) atom. S(1) is bonded to two equivalent O(6) and two equivalent O(7) atoms to form SO4 tetrahedra that share corners with two equivalent Co(1)NO5 octahedra and  an edgeedge with one Co(2)N2O4 octahedra. The corner-sharing octahedral tilt angles are 43°. Both S(1)-O(6) bond lengths are 1.52 Å. Both S(1)-O(7) bond lengths are 1.47 Å. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(14) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one C(14), one H(1), and one H(4) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(7) and one C(8) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Co(1), one H(1), and one H(2) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Co(1), one H(3), and one H(4) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Co(1), one Co(2), and one S(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Co(2) and one C(1) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(1) atom. Linkers: 4 [CH]([N][N][CH]c1ccncc1)c1ccncc1 ,4 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 O.O.O.O.[O]S1([O])O[Co](O[C]=O)O[C]O[Co]O[C]O[Co](O[C]=O)O1. The MOF has largest included sphere 4.93 A, density 1.50 g/cm3, surface area 4239.37 m2/g, accessible volume 0.21 cm3/g