MnCuC12H15(NO3)3CH2 crystallizes in the triclinic P1 space group. The structure consists of two 02329_fluka molecules inside a MnCuC12H15(NO3)3 framework. In the MnCuC12H15(NO3)3 framework, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted octahedral geometry to one O(1), one O(12), one O(13), one O(15), one O(17), and one O(3) atom. The Mn(1)-O(1) bond length is 2.21 Å. The Mn(1)-O(12) bond length is 2.17 Å. The Mn(1)-O(13) bond length is 2.34 Å. The Mn(1)-O(15) bond length is 2.15 Å. The Mn(1)-O(17) bond length is 2.12 Å. The Mn(1)-O(3) bond length is 2.10 Å. In the second Mn site, Mn(2) is bonded in a distorted octahedral geometry to one O(11), one O(14), one O(16), one O(18), one O(2), and one O(4) atom. The Mn(2)-O(11) bond length is 2.18 Å. The Mn(2)-O(14) bond length is 2.34 Å. The Mn(2)-O(16) bond length is 2.15 Å. The Mn(2)-O(18) bond length is 2.12 Å. The Mn(2)-O(2) bond length is 2.21 Å. The Mn(2)-O(4) bond length is 2.10 Å. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square pyramidal geometry to one N(1), one N(3), one N(5), one O(10), and one O(5) atom. The Cu(1)-N(1) bond length is 2.02 Å. The Cu(1)-N(3) bond length is 1.95 Å. The Cu(1)-N(5) bond length is 2.05 Å. The Cu(1)-O(10) bond length is 2.53 Å. The Cu(1)-O(5) bond length is 1.96 Å. In the second Cu site, Cu(2) is bonded in a square pyramidal geometry to one N(2), one N(4), one N(6), one O(6), and one O(9) atom. The Cu(2)-N(2) bond length is 2.01 Å. The Cu(2)-N(4) bond length is 1.95 Å. The Cu(2)-N(6) bond length is 2.04 Å. The Cu(2)-O(6) bond length is 1.96 Å. The Cu(2)-O(9) bond length is 2.54 Å. There are twenty-three inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one N(1) and one O(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-O(1) bond length is 1.27 Å. In the second C site, C(2) is bonded in a 2-coordinate geometry to one N(2) and one O(2) atom. The C(2)-N(2) bond length is 1.34 Å. The C(2)-O(2) bond length is 1.27 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(3) and one O(3) atom. The C(3)-N(3) bond length is 1.31 Å. The C(3)-O(3) bond length is 1.29 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(4) and one O(4) atom. The C(4)-N(4) bond length is 1.31 Å. The C(4)-O(4) bond length is 1.29 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(17), and one H(19) atom. The C(5)-N(3) bond length is 1.46 Å. The C(5)-H(17) bond length is 1.10 Å. The C(5)-H(19) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(18), and one H(20) atom. The C(6)-N(4) bond length is 1.46 Å. The C(6)-H(18) bond length is 1.10 Å. The C(6)-H(20) bond length is 1.10 Å. In the seventh C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(5), one H(25), and one H(27) atom. The C(9)-N(5) bond length is 1.48 Å. The C(9)-H(25) bond length is 1.10 Å. The C(9)-H(27) bond length is 1.10 Å. In the eighth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(26), and one H(28) atom. The C(10)-N(6) bond length is 1.47 Å. The C(10)-H(26) bond length is 1.10 Å. The C(10)-H(28) bond length is 1.10 Å. In the ninth C site, C(11) is bonded in a bent 120 degrees geometry to one C(13), one O(5), and one O(7) atom. The C(11)-C(13) bond length is 1.50 Å. The C(11)-O(5) bond length is 1.29 Å. The C(11)-O(7) bond length is 1.26 Å. In the tenth C site, C(12) is bonded in a bent 120 degrees geometry to one C(14), one O(6), and one O(8) atom. The C(12)-C(14) bond length is 1.50 Å. The C(12)-O(6) bond length is 1.29 Å. The C(12)-O(8) bond length is 1.26 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(25) atom. The C(13)-C(15) bond length is 1.43 Å. The C(13)-C(25) bond length is 1.41 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(26) atom. The C(14)-C(16) bond length is 1.43 Å. The C(14)-C(26) bond length is 1.41 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(13), one C(17), and one N(1) atom. The C(15)-C(17) bond length is 1.42 Å. The C(15)-N(1) bond length is 1.40 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one N(2) atom. The C(16)-C(18) bond length is 1.42 Å. The C(16)-N(2) bond length is 1.40 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(15), one C(19), and one H(29) atom. The C(17)-C(19) bond length is 1.39 Å. The C(17)-H(29) bond length is 1.08 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one H(30) atom. The C(18)-C(20) bond length is 1.39 Å. The C(18)-H(30) bond length is 1.08 Å. In the seventeenth C site, C(19) is bonded in a trigonal planar geometry to one C(17); one C(21); and one C(23,24) atom. The C(19)-C(21) bond length is 1.50 Å. The C(19)-C(23,24) bond length is 1.40 Å. In the eighteenth C site, C(20) is bonded in a trigonal planar geometry to one C(18); one C(22); and one C(23,24) atom. The C(20)-C(22) bond length is 1.50 Å. The C(20)-C(23,24) bond length is 1.40 Å. In the nineteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(11), and one O(9) atom. The C(21)-O(11) bond length is 1.28 Å. The C(21)-O(9) bond length is 1.27 Å. In the twentieth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(10), and one O(12) atom. The C(22)-O(10) bond length is 1.27 Å. The C(22)-O(12) bond length is 1.28 Å. In the twenty-first C site, C(23,24) is bonded in a distorted single-bond geometry to one C(19) and one H(31) atom. The C(23,24)-H(31) bond length is 1.09 Å. In the twenty-second C site, C(25) is bonded in a distorted single-bond geometry to one C(13) and one H(33) atom. The C(25)-H(33) bond length is 1.09 Å. In the twenty-third C site, C(26) is bonded in a distorted single-bond geometry to one C(14) and one H(34) atom. The C(26)-H(34) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(15) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(16), and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(5) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(4), and one C(6) atom. In the fifth N site, N(5) is bonded in a distorted tetrahedral geometry to one Cu(1), one C(9), one H(1), and one H(3) atom. The N(5)-H(1) bond length is 1.03 Å. The N(5)-H(3) bond length is 1.03 Å. In the sixth N site, N(6) is bonded in a distorted tetrahedral geometry to one Cu(2), one C(10), one H(2), and one H(4) atom. The N(6)-H(2) bond length is 1.03 Å. The N(6)-H(4) bond length is 1.03 Å. There are thirty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(13) atom. The H(5)-O(13) bond length is 0.98 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(14) atom. The H(6)-O(14) bond length is 0.98 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(13) atom. The H(7)-O(13) bond length is 0.98 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(14) atom. The H(8)-O(14) bond length is 0.98 Å. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(15) and one O(4) atom. The H(9)-O(15) bond length is 0.99 Å. The H(9)-O(4) bond length is 1.74 Å. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(16) and one O(3) atom. The H(10)-O(16) bond length is 0.99 Å. The H(10)-O(3) bond length is 1.74 Å. In the eleventh H site, H(11) is bonded in a distorted single-bond geometry to one O(10) and one O(15) atom. The H(11)-O(10) bond length is 1.61 Å. The H(11)-O(15) bond length is 1.01 Å. In the twelfth H site, H(12) is bonded in a distorted single-bond geometry to one O(16) and one O(9) atom. The H(12)-O(16) bond length is 1.01 Å. The H(12)-O(9) bond length is 1.62 Å. In the thirteenth H site, H(13) is bonded in a distorted linear geometry to one O(17) and one O(8) atom. The H(13)-O(17) bond length is 1.02 Å. The H(13)-O(8) bond length is 1.56 Å. In the fourteenth H site, H(14) is bonded in a distorted linear geometry to one O(18) and one O(7) atom. The H(14)-O(18) bond length is 1.02 Å. The H(14)-O(7) bond length is 1.55 Å. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one O(17) and one O(5) atom. The H(15)-O(17) bond length is 0.99 Å. The H(15)-O(5) bond length is 1.73 Å. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one O(18) and one O(6) atom. The H(16)-O(18) bond length is 0.99 Å. The H(16)-O(6) bond length is 1.74 Å. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(5) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(6) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(5) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(6) atom. In the twenty-first H site, H(25) is bonded in a single-bond geometry to one C(9) atom. In the twenty-second H site, H(26) is bonded in a single-bond geometry to one C(10) atom. In the twenty-third H site, H(27) is bonded in a single-bond geometry to one C(9) atom. In the twenty-fourth H site, H(28) is bonded in a single-bond geometry to one C(10) atom. In the twenty-fifth H site, H(29) is bonded in a single-bond geometry to one C(17) atom. In the twenty-sixth H site, H(30) is bonded in a single-bond geometry to one C(18) atom. In the twenty-seventh H site, H(31) is bonded in a single-bond geometry to one C(23,24) atom. In the twenty-eighth H site, H(32) is bonded in a single-bond geometry to one C(23,24) atom. The H(32)-C(23,24) bond length is 1.09 Å. In the twenty-ninth H site, H(33) is bonded in a single-bond geometry to one C(25) atom. In the thirtieth H site, H(34) is bonded in a single-bond geometry to one C(26) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mn(1), one C(3), and one H(10) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mn(2), one C(4), and one H(9) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Cu(1), one C(11), and one H(15) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Cu(2), one C(12), and one H(16) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one C(11) and one H(14) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one C(12) and one H(13) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Cu(2), one C(21), and one H(12) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one C(22), and one H(11) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(21) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(22) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one Mn(1), one H(5), and one H(7) atom. In the fourteenth O site, O(14) is bonded in a distorted water-like geometry to one Mn(2), one H(6), and one H(8) atom. In the fifteenth O site, O(15) is bonded in a distorted water-like geometry to one Mn(1), one H(11), and one H(9) atom. In the sixteenth O site, O(16) is bonded in a distorted water-like geometry to one Mn(2), one H(10), and one H(12) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Mn(1), one H(13), and one H(15) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Mn(2), one H(14), and one H(16) atom. Linkers: 2 NCCC[N]C(=O)C(=O)[N]c1cc(C([O])=O)ccc1C([O])=O. Metal clusters: 2 [Mn] ,2 [Cu]. The MOF has largest included sphere 3.06 A, density 1.76 g/cm3, surface area 3621.85 m2/g, accessible volume 0.15 cm3/g