MnC66H60(N4O)2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one MnC66H60(N4O)2 cluster. Mn(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one N(5), and one N(6) atom. The Mn(1)-N(1) bond length is 2.03 Å. The Mn(1)-N(2) bond length is 2.04 Å. The Mn(1)-N(3) bond length is 2.04 Å. The Mn(1)-N(4) bond length is 2.04 Å. The Mn(1)-N(5) bond length is 2.26 Å. The Mn(1)-N(6) bond length is 2.07 Å. There are sixty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(19), one C(3), and one N(1) atom. The C(1)-C(19) bond length is 1.40 Å. The C(1)-C(3) bond length is 1.44 Å. The C(1)-N(1) bond length is 1.38 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(20), one C(4), and one N(2) atom. The C(2)-C(20) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.44 Å. The C(2)-N(2) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(3)-H(1) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(4)-H(2) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(7) and one H(3) atom. The C(5)-C(7) bond length is 1.44 Å. The C(5)-H(3) bond length is 1.08 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(8) and one H(4) atom. The C(6)-C(8) bond length is 1.44 Å. The C(6)-H(4) bond length is 1.08 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one N(1) atom. The C(7)-C(9) bond length is 1.40 Å. The C(7)-N(1) bond length is 1.38 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one N(2) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-N(2) bond length is 1.38 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(11), one C(21), and one C(7) atom. The C(9)-C(11) bond length is 1.40 Å. The C(9)-C(21) bond length is 1.49 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(12), one C(22), and one C(8) atom. The C(10)-C(12) bond length is 1.40 Å. The C(10)-C(22) bond length is 1.49 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one N(3) atom. The C(11)-C(13) bond length is 1.44 Å. The C(11)-N(3) bond length is 1.38 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(10), one C(14), and one N(4) atom. The C(12)-C(14) bond length is 1.44 Å. The C(12)-N(4) bond length is 1.38 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(11), one C(15), and one H(5) atom. The C(13)-C(15) bond length is 1.37 Å. The C(13)-H(5) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one H(6) atom. The C(14)-C(16) bond length is 1.37 Å. The C(14)-H(6) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one H(7) atom. The C(15)-C(17) bond length is 1.44 Å. The C(15)-H(7) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one H(8) atom. The C(16)-C(18) bond length is 1.44 Å. The C(16)-H(8) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(15), one C(20), and one N(3) atom. The C(17)-C(20) bond length is 1.40 Å. The C(17)-N(3) bond length is 1.38 Å. In the eighteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(16), one C(19), and one N(4) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-N(4) bond length is 1.38 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(1), one C(18), and one C(39) atom. The C(19)-C(39) bond length is 1.50 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(17), one C(2), and one C(40) atom. The C(20)-C(40) bond length is 1.49 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(23,24); one C(31,32); and one C(9) atom. The C(21)-C(23,24) bond length is 1.41 Å. The C(21)-C(31,32) bond length is 1.41 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(10); one C(23,24); and one C(31,32) atom. The C(22)-C(23,24) bond length is 1.41 Å. The C(22)-C(31,32) bond length is 1.41 Å. In the twenty-third C site, C(23,24) is bonded in a trigonal planar geometry to one C(21); one C(25); and one C(33,34) atom. The C(23,24)-C(25) bond length is 1.40 Å. The C(23,24)-C(33,34) bond length is 1.51 Å. In the twenty-fourth C site, C(25) is bonded in a distorted single-bond geometry to one C(23,24); one C(27,28); and one H(9,10) atom. The C(25)-C(27,28) bond length is 1.40 Å. The C(25)-H(9,10) bond length is 1.09 Å. In the twenty-fifth C site, C(26) is bonded in a distorted single-bond geometry to one C(23,24); one C(27,28); and one H(9,10) atom. The C(26)-C(23,24) bond length is 1.40 Å. The C(26)-C(27,28) bond length is 1.40 Å. The C(26)-H(9,10) bond length is 1.09 Å. In the twenty-sixth C site, C(27,28) is bonded in a trigonal planar geometry to one C(25), one C(29), and one C(35) atom. The C(27,28)-C(29) bond length is 1.40 Å. The C(27,28)-C(35) bond length is 1.50 Å. In the twenty-seventh C site, C(29) is bonded in a distorted trigonal planar geometry to one C(27,28); one C(31,32); and one H(11,12) atom. The C(29)-C(31,32) bond length is 1.40 Å. The C(29)-H(11,12) bond length is 1.09 Å. In the twenty-eighth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(27,28); one C(31,32); and one H(11,12) atom. The C(30)-C(27,28) bond length is 1.40 Å. The C(30)-C(31,32) bond length is 1.40 Å. The C(30)-H(11,12) bond length is 1.09 Å. In the twenty-ninth C site, C(31,32) is bonded in a trigonal planar geometry to one C(21), one C(29), and one C(37) atom. The C(31,32)-C(37) bond length is 1.51 Å. In the thirtieth C site, C(33,34) is bonded in a distorted trigonal non-coplanar geometry to one C(23,24); one H(13,14); one H(15,16); and one H(17,18) atom. The C(33,34)-H(13,14) bond length is 1.10 Å. The C(33,34)-H(15,16) bond length is 1.10 Å. The C(33,34)-H(17,18) bond length is 1.10 Å. In the thirty-first C site, C(35) is bonded in a distorted trigonal non-coplanar geometry to one C(27,28); one H(19,20); one H(21,22); and one H(23,24) atom. The C(35)-H(19,20) bond length is 1.10 Å. The C(35)-H(21,22) bond length is 1.10 Å. The C(35)-H(23,24) bond length is 1.10 Å. In the thirty-second C site, C(36) is bonded in a distorted trigonal non-coplanar geometry to one C(27,28); one H(19,20); one H(21,22); and one H(23,24) atom. The C(36)-C(27,28) bond length is 1.50 Å. The C(36)-H(19,20) bond length is 1.10 Å. The C(36)-H(21,22) bond length is 1.10 Å. The C(36)-H(23,24) bond length is 1.10 Å. In the thirty-third C site, C(37) is bonded in a distorted trigonal non-coplanar geometry to one C(31,32); one H(25,26); one H(27,28); and one H(29,30) atom. The C(37)-H(25,26) bond length is 1.10 Å. The C(37)-H(27,28) bond length is 1.10 Å. The C(37)-H(29,30) bond length is 1.10 Å. In the thirty-fourth C site, C(38) is bonded in a distorted trigonal non-coplanar geometry to one C(31,32); one H(25,26); one H(27,28); and one H(29,30) atom. The C(38)-C(31,32) bond length is 1.51 Å. The C(38)-H(25,26) bond length is 1.10 Å. The C(38)-H(27,28) bond length is 1.10 Å. The C(38)-H(29,30) bond length is 1.10 Å. In the thirty-fifth C site, C(39) is bonded in a trigonal planar geometry to one C(19), one C(41), and one C(49) atom. The C(39)-C(41) bond length is 1.41 Å. The C(39)-C(49) bond length is 1.41 Å. In the thirty-sixth C site, C(40) is bonded in a trigonal planar geometry to one C(20), one C(42), and one C(50) atom. The C(40)-C(42) bond length is 1.41 Å. The C(40)-C(50) bond length is 1.41 Å. In the thirty-seventh C site, C(41) is bonded in a trigonal planar geometry to one C(39), one C(43), and one C(51) atom. The C(41)-C(43) bond length is 1.40 Å. The C(41)-C(51) bond length is 1.51 Å. In the thirty-eighth C site, C(42) is bonded in a trigonal planar geometry to one C(40), one C(44), and one C(52) atom. The C(42)-C(44) bond length is 1.40 Å. The C(42)-C(52) bond length is 1.51 Å. In the thirty-ninth C site, C(43) is bonded in a distorted trigonal planar geometry to one C(41), one C(45), and one H(31) atom. The C(43)-C(45) bond length is 1.40 Å. The C(43)-H(31) bond length is 1.09 Å. In the fortieth C site, C(44) is bonded in a distorted trigonal planar geometry to one C(42), one C(46), and one H(32) atom. The C(44)-C(46) bond length is 1.40 Å. The C(44)-H(32) bond length is 1.09 Å. In the forty-first C site, C(45) is bonded in a trigonal planar geometry to one C(43), one C(47), and one C(53) atom. The C(45)-C(47) bond length is 1.40 Å. The C(45)-C(53) bond length is 1.50 Å. In the forty-second C site, C(46) is bonded in a trigonal planar geometry to one C(44), one C(48), and one C(54) atom. The C(46)-C(48) bond length is 1.40 Å. The C(46)-C(54) bond length is 1.50 Å. In the forty-third C site, C(47) is bonded in a distorted single-bond geometry to one C(45), one C(49), and one H(33) atom. The C(47)-C(49) bond length is 1.40 Å. The C(47)-H(33) bond length is 1.09 Å. In the forty-fourth C site, C(48) is bonded in a distorted single-bond geometry to one C(46), one C(50), and one H(34) atom. The C(48)-C(50) bond length is 1.40 Å. The C(48)-H(34) bond length is 1.09 Å. In the forty-fifth C site, C(49) is bonded in a trigonal planar geometry to one C(39); one C(47); and one C(55,56) atom. The C(49)-C(55,56) bond length is 1.51 Å. In the forty-sixth C site, C(50) is bonded in a trigonal planar geometry to one C(40); one C(48); and one C(55,56) atom. The C(50)-C(55,56) bond length is 1.51 Å. In the forty-seventh C site, C(51) is bonded in a distorted trigonal non-coplanar geometry to one C(41); one H(35,36); one H(37,38); and one H(39,40) atom. The C(51)-H(35,36) bond length is 1.09 Å. The C(51)-H(37,38) bond length is 1.10 Å. The C(51)-H(39,40) bond length is 1.10 Å. In the forty-eighth C site, C(52) is bonded in a distorted trigonal non-coplanar geometry to one C(42); one H(35,36); one H(37,38); and one H(39,40) atom. The C(52)-H(35,36) bond length is 1.09 Å. The C(52)-H(37,38) bond length is 1.10 Å. The C(52)-H(39,40) bond length is 1.10 Å. In the forty-ninth C site, C(53) is bonded in a distorted trigonal non-coplanar geometry to one C(45), one H(41), one H(43), and one H(45) atom. The C(53)-H(41) bond length is 1.10 Å. The C(53)-H(43) bond length is 1.10 Å. The C(53)-H(45) bond length is 1.10 Å. In the fiftieth C site, C(54) is bonded in a distorted trigonal non-coplanar geometry to one C(46), one H(42), one H(44), and one H(46) atom. The C(54)-H(42) bond length is 1.10 Å. The C(54)-H(44) bond length is 1.10 Å. The C(54)-H(46) bond length is 1.10 Å. In the fifty-first C site, C(55,56) is bonded in a distorted trigonal non-coplanar geometry to one C(49); one H(47,48); one H(49,50); and one H(51,52) atom. The C(55,56)-H(47,48) bond length is 1.10 Å. The C(55,56)-H(49,50) bond length is 1.10 Å. The C(55,56)-H(51,52) bond length is 1.10 Å. In the fifty-second C site, C(57) is bonded in a linear geometry to one N(5) and one N(7) atom. The C(57)-N(5) bond length is 1.20 Å. The C(57)-N(7) bond length is 1.27 Å. In the fifty-third C site, C(58) is bonded in a linear geometry to one N(6) and one N(8) atom. The C(58)-N(6) bond length is 1.20 Å. The C(58)-N(8) bond length is 1.27 Å. In the fifty-fourth C site, C(59) is bonded in a distorted trigonal planar geometry to one C(61), one C(64), and one N(7) atom. The C(59)-C(61) bond length is 1.43 Å. The C(59)-C(64) bond length is 1.42 Å. The C(59)-N(7) bond length is 1.36 Å. In the fifty-fifth C site, C(60) is bonded in a distorted trigonal planar geometry to one C(62), one C(63), and one N(8) atom. The C(60)-C(62) bond length is 1.43 Å. The C(60)-C(63) bond length is 1.41 Å. The C(60)-N(8) bond length is 1.37 Å. In the fifty-sixth C site, C(61) is bonded in a distorted single-bond geometry to one C(59) and one O(1) atom. The C(61)-O(1) bond length is 1.36 Å. In the fifty-seventh C site, C(62) is bonded in a distorted single-bond geometry to one C(60) and one O(2) atom. The C(62)-O(2) bond length is 1.36 Å. In the fifty-eighth C site, C(63) is bonded in a distorted single-bond geometry to one C(60) and one H(59) atom. The C(63)-H(59) bond length is 1.09 Å. In the fifty-ninth C site, C(64) is bonded in a distorted single-bond geometry to one C(59) and one H(60) atom. The C(64)-H(60) bond length is 1.09 Å. In the sixtieth C site, C(65) is bonded in a tetrahedral geometry to one H(53,54); one H(55,56); one H(57,58); and one O(1) atom. The C(65)-H(53,54) bond length is 1.09 Å. The C(65)-H(55,56) bond length is 1.10 Å. The C(65)-H(57,58) bond length is 1.10 Å. The C(65)-O(1) bond length is 1.43 Å. In the sixty-first C site, C(66) is bonded in a tetrahedral geometry to one H(53,54); one H(55,56); one H(57,58); and one O(2) atom. The C(66)-H(53,54) bond length is 1.09 Å. The C(66)-H(55,56) bond length is 1.10 Å. The C(66)-H(57,58) bond length is 1.10 Å. The C(66)-O(2) bond length is 1.43 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(1), one C(1), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(1), one C(2), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Mn(1), one C(11), and one C(17) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Mn(1), one C(12), and one C(18) atom. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(57) atom. In the sixth N site, N(6) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(58) atom. In the seventh N site, N(7) is bonded in a bent 120 degrees geometry to one C(57) and one C(59) atom. In the eighth N site, N(8) is bonded in a bent 120 degrees geometry to one C(58) and one C(60) atom. There are forty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9,10) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(11,12) is bonded in a single-bond geometry to one C(29) atom. In the eleventh H site, H(13,14) is bonded in a single-bond geometry to one C(33,34) atom. In the twelfth H site, H(15,16) is bonded in a single-bond geometry to one C(33,34) atom. In the thirteenth H site, H(17,18) is bonded in a single-bond geometry to one C(33,34) atom. In the fourteenth H site, H(19,20) is bonded in a single-bond geometry to one C(35) atom. In the fifteenth H site, H(21,22) is bonded in a single-bond geometry to one C(35) atom. In the sixteenth H site, H(23,24) is bonded in a single-bond geometry to one C(35) atom. In the seventeenth H site, H(25,26) is bonded in a single-bond geometry to one C(37) atom. In the eighteenth H site, H(27,28) is bonded in a single-bond geometry to one C(37) atom. In the nineteenth H site, H(29,30) is bonded in a single-bond geometry to one C(37) atom. In the twentieth H site, H(31) is bonded in a single-bond geometry to one C(43) atom. In the twenty-first H site, H(32) is bonded in a single-bond geometry to one C(44) atom. In the twenty-second H site, H(33) is bonded in a single-bond geometry to one C(47) atom. In the twenty-third H site, H(34) is bonded in a single-bond geometry to one C(48) atom. In the twenty-fourth H site, H(35,36) is bonded in a single-bond geometry to one C(51) atom. In the twenty-fifth H site, H(37,38) is bonded in a single-bond geometry to one C(51) atom. In the twenty-sixth H site, H(39,40) is bonded in a single-bond geometry to one C(51) atom. In the twenty-seventh H site, H(41) is bonded in a single-bond geometry to one C(53) atom. In the twenty-eighth H site, H(42) is bonded in a single-bond geometry to one C(54) atom. In the twenty-ninth H site, H(43) is bonded in a single-bond geometry to one C(53) atom. In the thirtieth H site, H(44) is bonded in a single-bond geometry to one C(54) atom. In the thirty-first H site, H(45) is bonded in a single-bond geometry to one C(53) atom. In the thirty-second H site, H(46) is bonded in a single-bond geometry to one C(54) atom. In the thirty-third H site, H(47,48) is bonded in a single-bond geometry to one C(55,56) atom. In the thirty-fourth H site, H(49,50) is bonded in a single-bond geometry to one C(55,56) atom. In the thirty-fifth H site, H(51,52) is bonded in a single-bond geometry to one C(55,56) atom. In the thirty-sixth H site, H(53,54) is bonded in a single-bond geometry to one C(65) atom. In the thirty-seventh H site, H(55,56) is bonded in a single-bond geometry to one C(65) atom. In the thirty-eighth H site, H(57,58) is bonded in a single-bond geometry to one C(65) atom. In the thirty-ninth H site, H(59) is bonded in a single-bond geometry to one C(63) atom. In the fortieth H site, H(60) is bonded in a single-bond geometry to one C(64) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(61) and one C(65) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(62) and one C(66) atom. Linkers: 1 Cc1cc(C)c(/C2=C3\C=C/C(=C(\c4c(C)cc(C)cc4C)C4=N/C(=C(/c5c(C)cc(C)cc5C)C5=CC=C([N]5)/C(c5c(C)cc(C)cc5C)=C5/C=CC2=N5)C=C4)[N]3)c(C)c1. Metal clusters: 1 [Mn]. The MOF has largest included sphere 5.43 A, density 0.98 g/cm3, surface area 5611.61 m2/g, accessible volume 0.46 cm3/g