CdC6H4S2(N2O)2 crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded in an octahedral geometry to one N(3), one N(4), one S(1), one S(2), one O(1), and one O(2) atom. The Cd(1)-N(3) bond length is 2.30 Å. The Cd(1)-N(4) bond length is 2.30 Å. The Cd(1)-S(1) bond length is 2.68 Å. The Cd(1)-S(2) bond length is 2.68 Å. The Cd(1)-O(1) bond length is 2.40 Å. The Cd(1)-O(2) bond length is 2.40 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-N(1) bond length is 1.37 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(2), and one H(2) atom. The C(2)-N(2) bond length is 1.36 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(3) atom. The C(3)-C(4) bond length is 1.37 Å. The C(3)-N(2) bond length is 1.36 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(4) atom. The C(4)-N(1) bond length is 1.36 Å. The C(4)-H(4) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a distorted linear geometry to one N(3) and one S(2) atom. The C(5)-N(3) bond length is 1.19 Å. The C(5)-S(2) bond length is 1.63 Å. In the sixth C site, C(6) is bonded in a distorted linear geometry to one N(4) and one S(1) atom. The C(6)-N(4) bond length is 1.19 Å. The C(6)-S(1) bond length is 1.63 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(4), and one O(1) atom. The N(1)-O(1) bond length is 1.30 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(3), and one O(2) atom. The N(2)-O(2) bond length is 1.31 Å. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(5) atom. In the fourth N site, N(4) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(6) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Cd(1) and one C(6) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Cd(1) and one C(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cd(1) and one N(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cd(1) and one N(2) atom. Linkers: 4 [O-][n+]1cc[n+]([O-])cc1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 1.67 A, density 2.24 g/cm3, surface area 3527.30 m2/g, accessible volume 0.10 cm3/g