CdC17PH12(NO2)2Cd2C31P2H21(NO2)4(CH)12(CH2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eighteen 02329_fluka molecules, six 02329_fluka molecules, two propylene molecules, two Cd2C31P2H21(NO2)4 clusters, and one CdC17PH12(NO2)2 cluster. In each Cd2C31P2H21(NO2)4 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(2) is bonded in a 6-coordinate geometry to one N(3), one N(4), one O(1), one O(10), one O(7), and one O(8) atom. The Cd(2)-N(3) bond length is 2.41 Å. The Cd(2)-N(4) bond length is 2.39 Å. The Cd(2)-O(1) bond length is 2.27 Å. The Cd(2)-O(10) bond length is 2.26 Å. The Cd(2)-O(7) bond length is 2.55 Å. The Cd(2)-O(8) bond length is 2.32 Å. In the second Cd site, Cd(3) is bonded in a 6-coordinate geometry to one N(5), one N(6), one O(11), one O(12), one O(2), and one O(9) atom. The Cd(3)-N(5) bond length is 2.42 Å. The Cd(3)-N(6) bond length is 2.39 Å. The Cd(3)-O(11) bond length is 2.53 Å. The Cd(3)-O(12) bond length is 2.32 Å. The Cd(3)-O(2) bond length is 2.24 Å. The Cd(3)-O(9) bond length is 2.27 Å. There are thirty-one inequivalent C sites. In the first C site, C(18) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(18)-O(7) bond length is 1.27 Å. The C(18)-O(8) bond length is 1.28 Å. In the second C site, C(19) is bonded in a trigonal planar geometry to one C(20), one C(24), and one P(3) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-C(24) bond length is 1.40 Å. The C(19)-P(3) bond length is 1.82 Å. In the third C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(19) atom. The C(20)-H(19) bond length is 1.09 Å. In the fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(19) and one H(23) atom. The C(24)-H(23) bond length is 1.09 Å. In the fifth C site, C(25) is bonded in a distorted water-like geometry to one P(3), one H(24), and one H(25) atom. The C(25)-P(3) bond length is 1.81 Å. The C(25)-H(24) bond length is 1.10 Å. The C(25)-H(25) bond length is 1.10 Å. In the sixth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. The C(27)-O(11) bond length is 1.27 Å. The C(27)-O(12) bond length is 1.28 Å. In the seventh C site, C(40) is bonded in a distorted trigonal planar geometry to one N(3) and one H(36) atom. The C(40)-N(3) bond length is 1.33 Å. The C(40)-H(36) bond length is 1.09 Å. In the eighth C site, C(42) is bonded in a distorted single-bond geometry to one C(43) and one H(38,40) atom. The C(42)-C(43) bond length is 1.41 Å. The C(42)-H(38,40) bond length is 1.09 Å. In the ninth C site, C(43) is bonded in a trigonal planar geometry to one C(42), one C(44), and one C(51) atom. The C(43)-C(44) bond length is 1.43 Å. The C(43)-C(51) bond length is 1.42 Å. In the tenth C site, C(44) is bonded in a distorted single-bond geometry to one C(43) and one H(39) atom. The C(44)-H(39) bond length is 1.09 Å. In the eleventh C site, C(45) is bonded in a distorted single-bond geometry to one C(46) and one H(38,40) atom. The C(45)-C(46) bond length is 1.43 Å. The C(45)-H(38,40) bond length is 1.09 Å. In the twelfth C site, C(46) is bonded in a trigonal planar geometry to one C(45), one C(47), and one C(50) atom. The C(46)-C(47) bond length is 1.41 Å. The C(46)-C(50) bond length is 1.42 Å. In the thirteenth C site, C(47) is bonded in a distorted single-bond geometry to one C(46) and one H(41) atom. The C(47)-H(41) bond length is 1.09 Å. In the fourteenth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(43) atom. The C(49)-N(4) bond length is 1.33 Å. The C(49)-H(43) bond length is 1.09 Å. In the fifteenth C site, C(50) is bonded in a distorted trigonal planar geometry to one C(46), one C(51), and one N(4) atom. The C(50)-C(51) bond length is 1.45 Å. The C(50)-N(4) bond length is 1.35 Å. In the sixteenth C site, C(51) is bonded in a distorted trigonal planar geometry to one C(43), one C(50), and one N(3) atom. The C(51)-N(3) bond length is 1.35 Å. In the seventeenth C site, C(52) is bonded in a distorted trigonal planar geometry to one N(5) and one H(44) atom. The C(52)-N(5) bond length is 1.33 Å. The C(52)-H(44) bond length is 1.09 Å. In the eighteenth C site, C(54) is bonded in a distorted single-bond geometry to one C(55) and one H(46) atom. The C(54)-C(55) bond length is 1.41 Å. The C(54)-H(46) bond length is 1.09 Å. In the nineteenth C site, C(55) is bonded in a trigonal planar geometry to one C(54), one C(56), and one C(63) atom. The C(55)-C(56) bond length is 1.43 Å. The C(55)-C(63) bond length is 1.42 Å. In the twentieth C site, C(56) is bonded in a distorted single-bond geometry to one C(55) and one H(47) atom. The C(56)-H(47) bond length is 1.09 Å. In the twenty-first C site, C(57) is bonded in a distorted single-bond geometry to one C(58) and one H(48) atom. The C(57)-C(58) bond length is 1.43 Å. The C(57)-H(48) bond length is 1.09 Å. In the twenty-second C site, C(58) is bonded in a trigonal planar geometry to one C(57), one C(59), and one C(62) atom. The C(58)-C(59) bond length is 1.41 Å. The C(58)-C(62) bond length is 1.42 Å. In the twenty-third C site, C(7) is bonded in a distorted water-like geometry to one P(1), one H(6), and one H(7) atom. The C(7)-P(1) bond length is 1.82 Å. The C(7)-H(6) bond length is 1.10 Å. The C(7)-H(7) bond length is 1.10 Å. In the twenty-fourth C site, C(59) is bonded in a distorted single-bond geometry to one C(58), one C(60), and one H(49) atom. The C(59)-C(60) bond length is 1.38 Å. The C(59)-H(49) bond length is 1.09 Å. In the twenty-fifth C site, C(60) is bonded in a distorted trigonal planar geometry to one C(59), one C(61), and one H(50) atom. The C(60)-C(61) bond length is 1.41 Å. The C(60)-H(50) bond length is 1.09 Å. In the twenty-sixth C site, C(61) is bonded in a distorted bent 120 degrees geometry to one C(60), one N(6), and one H(51) atom. The C(61)-N(6) bond length is 1.33 Å. The C(61)-H(51) bond length is 1.09 Å. In the twenty-seventh C site, C(62) is bonded in a distorted trigonal planar geometry to one C(58), one C(63), and one N(6) atom. The C(62)-C(63) bond length is 1.45 Å. The C(62)-N(6) bond length is 1.35 Å. In the twenty-eighth C site, C(63) is bonded in a distorted trigonal planar geometry to one C(55), one C(62), and one N(5) atom. The C(63)-N(5) bond length is 1.35 Å. In the twenty-ninth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(6)-C(1) bond length is 1.40 Å. The C(6)-H(5) bond length is 1.09 Å. In the thirtieth C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one P(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-P(1) bond length is 1.83 Å. In the thirty-first C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one C(1), one C(7), one O(1), and one O(2) atom. The P(1)-O(1) bond length is 1.53 Å. The P(1)-O(2) bond length is 1.53 Å. In the second P site, P(3) is bonded in a tetrahedral geometry to one C(19), one C(25), one O(10), and one O(9) atom. The P(3)-O(10) bond length is 1.53 Å. The P(3)-O(9) bond length is 1.53 Å. There are four inequivalent N sites. In the first N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(40), and one C(51) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cd(2), one C(49), and one C(50) atom. In the third N site, N(5) is bonded in a distorted trigonal planar geometry to one Cd(3), one C(52), and one C(63) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one Cd(3), one C(61), and one C(62) atom. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the sixth H site, H(23) is bonded in a single-bond geometry to one C(24) atom. In the seventh H site, H(24) is bonded in a single-bond geometry to one C(25) atom. In the eighth H site, H(25) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(36) is bonded in a single-bond geometry to one C(40) atom. In the tenth H site, H(38,40) is bonded in a single-bond geometry to one C(42) atom. In the eleventh H site, H(39) is bonded in a single-bond geometry to one C(44) atom. In the twelfth H site, H(41) is bonded in a single-bond geometry to one C(47) atom. In the thirteenth H site, H(43) is bonded in a single-bond geometry to one C(49) atom. In the fourteenth H site, H(44) is bonded in a single-bond geometry to one C(52) atom. In the fifteenth H site, H(46) is bonded in a single-bond geometry to one C(54) atom. In the sixteenth H site, H(47) is bonded in a single-bond geometry to one C(56) atom. In the seventeenth H site, H(48) is bonded in a single-bond geometry to one C(57) atom. In the eighteenth H site, H(49) is bonded in a single-bond geometry to one C(59) atom. In the nineteenth H site, H(50) is bonded in a single-bond geometry to one C(60) atom. In the twentieth H site, H(51) is bonded in a single-bond geometry to one C(61) atom. There are eight inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one Cd(2) and one C(18) atom. In the second O site, O(8) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(18) atom. In the third O site, O(9) is bonded in a bent 120 degrees geometry to one Cd(3) and one P(3) atom. In the fourth O site, O(10) is bonded in a bent 120 degrees geometry to one Cd(2) and one P(3) atom. In the fifth O site, O(11) is bonded in a single-bond geometry to one Cd(3) and one C(27) atom. In the sixth O site, O(12) is bonded in a distorted L-shaped geometry to one Cd(3) and one C(27) atom. In the seventh O site, O(1) is bonded in a bent 120 degrees geometry to one Cd(2) and one P(1) atom. In the eighth O site, O(2) is bonded in a bent 120 degrees geometry to one Cd(3) and one P(1) atom. In the CdC17PH12(NO2)2 cluster, Cd(1) is bonded to one N(1), one N(2), one O(3), one O(4), and two equivalent O(5) atoms to form distorted CdN2O4 octahedra that share corners with two equivalent P(2)C2O2 tetrahedra and  an edgeedge with one Cd(1)N2O4 octahedra. The Cd(1)-N(1) bond length is 2.37 Å. The Cd(1)-N(2) bond length is 2.36 Å. The Cd(1)-O(3) bond length is 2.51 Å. The Cd(1)-O(4) bond length is 2.33 Å. There is one shorter (2.26 Å) and one longer (2.37 Å) Cd(1)-O(5) bond length. There are seventeen inequivalent C sites. In the first C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(9)-O(3) bond length is 1.27 Å. The C(9)-O(4) bond length is 1.28 Å. In the second C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one P(2) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.40 Å. The C(10)-P(2) bond length is 1.81 Å. In the third C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(10) atom. The C(11)-H(10) bond length is 1.09 Å. In the fourth C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one H(14) atom. The C(15)-H(14) bond length is 1.09 Å. In the fifth C site, C(16) is bonded in a distorted water-like geometry to one P(2), one H(15), and one H(16) atom. The C(16)-P(2) bond length is 1.81 Å. The C(16)-H(15) bond length is 1.10 Å. The C(16)-H(16) bond length is 1.10 Å. In the sixth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(28) atom. The C(28)-N(1) bond length is 1.33 Å. The C(28)-H(28) bond length is 1.09 Å. In the seventh C site, C(29) is bonded in a distorted single-bond geometry to one C(30) and one H(29) atom. The C(29)-C(30) bond length is 1.38 Å. The C(29)-H(29) bond length is 1.09 Å. In the eighth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one C(31), and one H(30) atom. The C(30)-C(31) bond length is 1.41 Å. The C(30)-H(30) bond length is 1.09 Å. In the ninth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(39) atom. The C(31)-C(32) bond length is 1.43 Å. The C(31)-C(39) bond length is 1.42 Å. In the tenth C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(31) atom. The C(32)-H(31) bond length is 1.09 Å. In the eleventh C site, C(33) is bonded in a distorted single-bond geometry to one C(34) and one H(32) atom. The C(33)-C(34) bond length is 1.43 Å. The C(33)-H(32) bond length is 1.09 Å. In the twelfth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(38) atom. The C(34)-C(35) bond length is 1.41 Å. The C(34)-C(38) bond length is 1.42 Å. In the thirteenth C site, C(35) is bonded in a distorted single-bond geometry to one C(34), one C(36), and one H(33) atom. The C(35)-C(36) bond length is 1.38 Å. The C(35)-H(33) bond length is 1.09 Å. In the fourteenth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(35), one C(37), and one H(34) atom. The C(36)-C(37) bond length is 1.41 Å. The C(36)-H(34) bond length is 1.09 Å. In the fifteenth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(36), one N(2), and one H(35) atom. The C(37)-N(2) bond length is 1.33 Å. The C(37)-H(35) bond length is 1.09 Å. In the sixteenth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(34), one C(39), and one N(2) atom. The C(38)-C(39) bond length is 1.45 Å. The C(38)-N(2) bond length is 1.35 Å. In the seventeenth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(31), one C(38), and one N(1) atom. The C(39)-N(1) bond length is 1.36 Å. P(2) is bonded to one C(10), one C(16), one O(5), and one O(6) atom to form PC2O2 tetrahedra that share corners with two equivalent Cd(1)N2O4 octahedra. The corner-sharing octahedral tilt angles range from 37-66°. The P(2)-O(5) bond length is 1.56 Å. The P(2)-O(6) bond length is 1.51 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(28), and one C(39) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(37), and one C(38) atom. There are twelve inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(28) is bonded in a single-bond geometry to one C(28) atom. In the sixth H site, H(29) is bonded in a single-bond geometry to one C(29) atom. In the seventh H site, H(30) is bonded in a single-bond geometry to one C(30) atom. In the eighth H site, H(31) is bonded in a single-bond geometry to one C(32) atom. In the ninth H site, H(32) is bonded in a single-bond geometry to one C(33) atom. In the tenth H site, H(33) is bonded in a single-bond geometry to one C(35) atom. In the eleventh H site, H(34) is bonded in a single-bond geometry to one C(36) atom. In the twelfth H site, H(35) is bonded in a single-bond geometry to one C(37) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(9) atom. In the second O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(9) atom. In the third O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one P(2) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one P(2) atom. Linkers: 4 [O]C(=O)CC[P@]([O])(=O)c1ccccc1 ,2 c1cnc2c(c1)ccc1cccnc12 ,2 [O]C(=O)CC[P@@]([O])(=O)c1ccccc1. Metal clusters: 6 [Cd]. The MOF has largest included sphere 5.15 A, density 1.50 g/cm3, surface area 4349.55 m2/g, accessible volume 0.17 cm3/g