ZnC12H12S4(NO2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC12H12S4(NO2)2 clusters. Zn(1) is bonded in a distorted tetrahedral geometry to one S(3), one S(4), one O(1), and one O(2) atom. The Zn(1)-S(3) bond length is 2.31 Å. The Zn(1)-S(4) bond length is 2.31 Å. The Zn(1)-O(1) bond length is 1.99 Å. The Zn(1)-O(2) bond length is 1.99 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(3) bond length is 1.25 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(2)-O(2) bond length is 1.29 Å. The C(2)-O(4) bond length is 1.25 Å. In the third C site, C(3,4) is bonded in a trigonal planar geometry to one C(11,12); one C(7); and one S(1,2) atom. The C(3,4)-C(11,12) bond length is 1.49 Å. The C(3,4)-C(7) bond length is 1.37 Å. The C(3,4)-S(1,2) bond length is 1.74 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1); one S(1,2); and one S(3) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-S(1,2) bond length is 1.72 Å. The C(5)-S(3) bond length is 1.70 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one N(2); one S(1,2); and one S(4) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-S(1,2) bond length is 1.72 Å. The C(6)-S(4) bond length is 1.70 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(3,4); one C(9,10); and one N(1) atom. The C(7)-C(9,10) bond length is 1.49 Å. The C(7)-N(1) bond length is 1.39 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(3,4); one C(9,10); and one N(2) atom. The C(8)-C(3,4) bond length is 1.37 Å. The C(8)-C(9,10) bond length is 1.49 Å. The C(8)-N(2) bond length is 1.39 Å. In the eighth C site, C(9,10) is bonded in a distorted trigonal non-coplanar geometry to one C(7); one H(3,4); one H(5,6); and one H(7,8) atom. The C(9,10)-H(3,4) bond length is 1.10 Å. The C(9,10)-H(5,6) bond length is 1.10 Å. The C(9,10)-H(7,8) bond length is 1.10 Å. In the ninth C site, C(11,12) is bonded in a water-like geometry to one C(3,4); one H(11,12); and one H(9,10) atom. The C(11,12)-H(11,12) bond length is 1.10 Å. The C(11,12)-H(9,10) bond length is 1.11 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(5), one C(7), and one H(1) atom. The N(1)-H(1) bond length is 1.06 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(6), one C(8), and one H(2) atom. The N(2)-H(2) bond length is 1.06 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one N(1) and one O(3) atom. The H(1)-O(3) bond length is 1.70 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one N(2) and one O(4) atom. The H(2)-O(4) bond length is 1.69 Å. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(9,10) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(9,10) atom. In the fifth H site, H(7,8) is bonded in a single-bond geometry to one C(9,10) atom. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(11,12) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(11,12) atom. There are three inequivalent S sites. In the first S site, S(1,2) is bonded in an L-shaped geometry to one C(3,4) and one C(5) atom. In the second S site, S(3) is bonded in a water-like geometry to one Zn(1) and one C(5) atom. In the third S site, S(4) is bonded in a water-like geometry to one Zn(1) and one C(6) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. Linkers: 4 Cc1[nH]c(=S)sc1CC([O])=O. Metal clusters: 2 O=[C]O[Zn]([S])([S])O[C]=O. RCSR code: sql. The MOF has largest included sphere 1.74 A, density 1.92 g/cm3, surface area 4242.04 m2/g, accessible volume 0.13 cm3/g