ZnC16H12(N3O2)2(CH)4 is Indium-derived structured and crystallizes in the tetragonal P4nc space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four ZnC16H12(N3O2)2 clusters. In each ZnC16H12(N3O2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(2) and two equivalent O(1) atoms. Both Zn(1)-N(2) bond lengths are 2.00 Å. Both Zn(1)-O(1) bond lengths are 1.98 Å. There are eight inequivalent C sites. In the first C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(2), and one N(3) atom. The C(9)-C(10) bond length is 1.48 Å. The C(9)-N(2) bond length is 1.33 Å. The C(9)-N(3) bond length is 1.37 Å. In the second C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(6), one H(7), and one H(8) atom. The C(10)-H(6) bond length is 1.10 Å. The C(10)-H(7) bond length is 1.10 Å. The C(10)-H(8) bond length is 1.10 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the fourth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the fifth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the sixth C site, C(5) is bonded in a distorted single-bond geometry to one N(3) atom. The C(5)-N(3) bond length is 1.43 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(5) atom. The C(8)-N(1) bond length is 1.31 Å. The C(8)-N(3) bond length is 1.37 Å. The C(8)-H(5) bond length is 1.08 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one C(8) and one N(2) atom. The N(1)-N(2) bond length is 1.38 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(9), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(5), one C(8), and one C(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Linkers: 8 Cc1nncn1-c1ccc(C([O])=O)cc1. Metal clusters: 4 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 7.05 A, density 1.14 g/cm3, surface area 5026.20 m2/g, accessible volume 0.45 cm3/g