CuC6H8(N3Cl)2(CH2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CuC6H8(N3Cl)2 clusters. In each CuC6H8(N3Cl)2 cluster, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent Cl(1) atoms. Both Cu(1)-N(1) bond lengths are 1.99 Å. Both Cu(1)-Cl(1) bond lengths are 2.33 Å. There are three inequivalent C sites. In the first C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(3), and one H(4) atom. The C(3)-N(2) bond length is 1.46 Å. The C(3)-H(3) bond length is 1.09 Å. The C(3)-H(4) bond length is 1.10 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(2) atom. The C(2)-N(1) bond length is 1.37 Å. The C(2)-N(3) bond length is 1.33 Å. The C(2)-H(2) bond length is 1.08 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(3) atom. The N(2)-N(3) bond length is 1.36 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(2) and one N(2) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 2 [CH]1N=C[N]N1CCCCN1[CH]N=C[N]1 ,2 [c]1ncn(CCCCn2cncn2)n1 ,2 [c]1ncn(CCCCN2[CH]N=C[N]2)n1. Metal clusters: 2 Cl[Cu]Cl. The MOF has largest included sphere 2.46 A, density 1.73 g/cm3, surface area 4184.68 m2/g, accessible volume 0.18 cm3/g