CdC28H20(NO2)2CdC20H14(NO2)2(C4H3)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two isobutylene molecules, one CdC20H14(NO2)2 cluster, and one CdC28H20(NO2)2 cluster. In the CdC20H14(NO2)2 cluster, Cd(2) is bonded in a distorted octahedral geometry to one N(1), one N(2), one O(5), one O(6), one O(7), and one O(8) atom. The Cd(2)-N(1) bond length is 2.31 Å. The Cd(2)-N(2) bond length is 2.31 Å. The Cd(2)-O(5) bond length is 2.51 Å. The Cd(2)-O(6) bond length is 2.51 Å. The Cd(2)-O(7) bond length is 2.31 Å. The Cd(2)-O(8) bond length is 2.31 Å. There are fourteen inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted single-bond geometry to one C(5) and one H(1,2) atom. The C(1,2)-C(5) bond length is 1.45 Å. The C(1,2)-H(1,2) bond length is 1.09 Å. In the second C site, C(5) is bonded in a trigonal planar geometry to one C(1,2); one C(15,16); and one C(25,26) atom. The C(5)-C(15,16) bond length is 1.41 Å. The C(5)-C(25,26) bond length is 1.41 Å. In the third C site, C(6) is bonded in a trigonal planar geometry to one C(1,2); one C(15,16); and one C(25,26) atom. The C(6)-C(1,2) bond length is 1.46 Å. The C(6)-C(15,16) bond length is 1.41 Å. The C(6)-C(25,26) bond length is 1.41 Å. In the fourth C site, C(15,16) is bonded in a distorted single-bond geometry to one C(41), one C(5), and one H(7) atom. The C(15,16)-C(41) bond length is 1.38 Å. The C(15,16)-H(7) bond length is 1.09 Å. In the fifth C site, C(19,20) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(5), and one O(7) atom. The C(19,20)-C(21) bond length is 1.49 Å. The C(19,20)-O(5) bond length is 1.27 Å. The C(19,20)-O(7) bond length is 1.28 Å. In the sixth C site, C(21) is bonded in a trigonal planar geometry to one C(19,20); one C(29,30); and one C(33,34) atom. The C(21)-C(29,30) bond length is 1.41 Å. The C(21)-C(33,34) bond length is 1.40 Å. In the seventh C site, C(22) is bonded in a trigonal planar geometry to one C(19,20); one C(29,30); and one C(33,34) atom. The C(22)-C(19,20) bond length is 1.49 Å. The C(22)-C(29,30) bond length is 1.41 Å. The C(22)-C(33,34) bond length is 1.40 Å. In the eighth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(25,26); one N(1); and one H(11,12) atom. The C(23)-C(25,26) bond length is 1.39 Å. The C(23)-N(1) bond length is 1.35 Å. The C(23)-H(11,12) bond length is 1.09 Å. In the ninth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(25,26); one N(2); and one H(11,12) atom. The C(24)-C(25,26) bond length is 1.39 Å. The C(24)-N(2) bond length is 1.35 Å. The C(24)-H(11,12) bond length is 1.09 Å. In the tenth C site, C(25,26) is bonded in a distorted single-bond geometry to one C(23); one C(5); and one H(13,14) atom. The C(25,26)-H(13,14) bond length is 1.09 Å. In the eleventh C site, C(29,30) is bonded in a distorted single-bond geometry to one C(21) and one H(15,16) atom. The C(29,30)-H(15,16) bond length is 1.09 Å. In the twelfth C site, C(33,34) is bonded in a distorted single-bond geometry to one C(21) and one H(19,20) atom. The C(33,34)-H(19,20) bond length is 1.09 Å. In the thirteenth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(15,16); one N(1); and one H(27,28) atom. The C(41)-N(1) bond length is 1.35 Å. The C(41)-H(27,28) bond length is 1.09 Å. In the fourteenth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(15,16); one N(2); and one H(27,28) atom. The C(42)-C(15,16) bond length is 1.38 Å. The C(42)-N(2) bond length is 1.35 Å. The C(42)-H(27,28) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(2), one C(23), and one C(41) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(2), one C(24), and one C(42) atom. There are eight inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(15,16) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(15,16) atom. The H(8)-C(15,16) bond length is 1.09 Å. In the fourth H site, H(11,12) is bonded in a single-bond geometry to one C(23) atom. In the fifth H site, H(13,14) is bonded in a single-bond geometry to one C(25,26) atom. In the sixth H site, H(15,16) is bonded in a single-bond geometry to one C(29,30) atom. In the seventh H site, H(19,20) is bonded in a single-bond geometry to one C(33,34) atom. In the eighth H site, H(27,28) is bonded in a single-bond geometry to one C(41) atom. There are four inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Cd(2) and one C(19,20) atom. In the second O site, O(6) is bonded in a distorted single-bond geometry to one Cd(2) and one C(19,20) atom. The O(6)-C(19,20) bond length is 1.27 Å. In the third O site, O(7) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(19,20) atom. In the fourth O site, O(8) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(19,20) atom. The O(8)-C(19,20) bond length is 1.28 Å. In the CdC28H20(NO2)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(3), one N(4), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(3) bond length is 2.31 Å. The Cd(1)-N(4) bond length is 2.31 Å. The Cd(1)-O(1) bond length is 2.52 Å. The Cd(1)-O(2) bond length is 2.51 Å. The Cd(1)-O(3) bond length is 2.30 Å. The Cd(1)-O(4) bond length is 2.30 Å. There are twenty-seven inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(7,8); one C(9); and one H(3,4) atom. The C(3)-C(7,8) bond length is 1.41 Å. The C(3)-C(9) bond length is 1.39 Å. The C(3)-H(3,4) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(10); one C(7,8); and one H(3,4) atom. The C(4)-C(10) bond length is 1.39 Å. The C(4)-C(7,8) bond length is 1.41 Å. The C(4)-H(3,4) bond length is 1.09 Å. In the third C site, C(7,8) is bonded in a trigonal planar geometry to one C(17), one C(3), and one C(39) atom. The C(7,8)-C(17) bond length is 1.41 Å. The C(7,8)-C(39) bond length is 1.45 Å. In the fourth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(13); one C(3); and one H(5,6) atom. The C(9)-C(13) bond length is 1.40 Å. The C(9)-H(5,6) bond length is 1.09 Å. In the fifth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(14); one C(4); and one H(5,6) atom. The C(10)-C(14) bond length is 1.40 Å. The C(10)-H(5,6) bond length is 1.09 Å. In the sixth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(1), and one O(3) atom. The C(11)-C(13) bond length is 1.49 Å. The C(11)-O(1) bond length is 1.27 Å. The C(11)-O(3) bond length is 1.28 Å. In the seventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(2), and one O(4) atom. The C(12)-C(14) bond length is 1.49 Å. The C(12)-O(2) bond length is 1.27 Å. The C(12)-O(4) bond length is 1.28 Å. In the eighth C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(37), and one C(9) atom. The C(13)-C(37) bond length is 1.41 Å. In the ninth C site, C(14) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(38) atom. The C(14)-C(38) bond length is 1.41 Å. In the tenth C site, C(17) is bonded in a distorted single-bond geometry to one C(7,8) and one H(9,10) atom. The C(17)-H(9,10) bond length is 1.09 Å. In the eleventh C site, C(18) is bonded in a distorted single-bond geometry to one C(7,8) and one H(9,10) atom. The C(18)-C(7,8) bond length is 1.41 Å. The C(18)-H(9,10) bond length is 1.09 Å. In the twelfth C site, C(37) is bonded in a distorted single-bond geometry to one C(13) and one H(23,24) atom. The C(37)-H(23,24) bond length is 1.09 Å. In the thirteenth C site, C(38) is bonded in a distorted single-bond geometry to one C(14) and one H(23,24) atom. The C(38)-H(23,24) bond length is 1.09 Å. In the fourteenth C site, C(39) is bonded in a distorted single-bond geometry to one C(7,8) and one H(25,26) atom. The C(39)-H(25,26) bond length is 1.09 Å. In the fifteenth C site, C(40) is bonded in a distorted single-bond geometry to one C(7,8) and one H(25,26) atom. The C(40)-C(7,8) bond length is 1.45 Å. The C(40)-H(25,26) bond length is 1.09 Å. In the sixteenth C site, C(43) is bonded in a distorted trigonal planar geometry to one C(45), one N(3), and one H(29) atom. The C(43)-C(45) bond length is 1.38 Å. The C(43)-N(3) bond length is 1.35 Å. The C(43)-H(29) bond length is 1.09 Å. In the seventeenth C site, C(44) is bonded in a distorted trigonal planar geometry to one C(46), one N(4), and one H(30) atom. The C(44)-C(46) bond length is 1.38 Å. The C(44)-N(4) bond length is 1.35 Å. The C(44)-H(30) bond length is 1.09 Å. In the eighteenth C site, C(45) is bonded in a distorted single-bond geometry to one C(43); one C(47); and one H(31,32) atom. The C(45)-C(47) bond length is 1.41 Å. The C(45)-H(31,32) bond length is 1.09 Å. In the nineteenth C site, C(46) is bonded in a distorted single-bond geometry to one C(44); one C(48); and one H(31,32) atom. The C(46)-C(48) bond length is 1.41 Å. The C(46)-H(31,32) bond length is 1.09 Å. In the twentieth C site, C(47) is bonded in a trigonal planar geometry to one C(45), one C(49), and one C(53) atom. The C(47)-C(49) bond length is 1.41 Å. The C(47)-C(53) bond length is 1.45 Å. In the twenty-first C site, C(48) is bonded in a trigonal planar geometry to one C(46), one C(50), and one C(54) atom. The C(48)-C(50) bond length is 1.41 Å. The C(48)-C(54) bond length is 1.45 Å. In the twenty-second C site, C(49) is bonded in a distorted single-bond geometry to one C(47), one C(51), and one H(33) atom. The C(49)-C(51) bond length is 1.39 Å. The C(49)-H(33) bond length is 1.09 Å. In the twenty-third C site, C(50) is bonded in a distorted single-bond geometry to one C(48), one C(52), and one H(34) atom. The C(50)-C(52) bond length is 1.39 Å. The C(50)-H(34) bond length is 1.09 Å. In the twenty-fourth C site, C(51) is bonded in a distorted trigonal planar geometry to one C(49), one N(3), and one H(35) atom. The C(51)-N(3) bond length is 1.35 Å. The C(51)-H(35) bond length is 1.09 Å. In the twenty-fifth C site, C(52) is bonded in a distorted trigonal planar geometry to one C(50), one N(4), and one H(36) atom. The C(52)-N(4) bond length is 1.35 Å. The C(52)-H(36) bond length is 1.09 Å. In the twenty-sixth C site, C(53) is bonded in a distorted single-bond geometry to one C(47) and one H(37,38) atom. The C(53)-H(37,38) bond length is 1.09 Å. In the twenty-seventh C site, C(54) is bonded in a distorted single-bond geometry to one C(48) and one H(37,38) atom. The C(54)-H(37,38) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(43), and one C(51) atom. In the second N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(44), and one C(52) atom. There are thirteen inequivalent H sites. In the first H site, H(3,4) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(5,6) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(9,10) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(23,24) is bonded in a single-bond geometry to one C(37) atom. In the fifth H site, H(25,26) is bonded in a single-bond geometry to one C(39) atom. In the sixth H site, H(29) is bonded in a single-bond geometry to one C(43) atom. In the seventh H site, H(30) is bonded in a single-bond geometry to one C(44) atom. In the eighth H site, H(31,32) is bonded in a single-bond geometry to one C(45) atom. In the ninth H site, H(33) is bonded in a single-bond geometry to one C(49) atom. In the tenth H site, H(34) is bonded in a single-bond geometry to one C(50) atom. In the eleventh H site, H(35) is bonded in a single-bond geometry to one C(51) atom. In the twelfth H site, H(36) is bonded in a single-bond geometry to one C(52) atom. In the thirteenth H site, H(37,38) is bonded in a single-bond geometry to one C(53) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(11) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(12) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(11) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Cd(1) and one C(12) atom. Linkers: 1 [CH]C1=C[CH]N([Cd]23(N4[CH]C=C(/C=C/c5c[c]c(C([O])=O)cc5)C=C4)(O[C](c4ccc(/C=C/c5c[c]ncc5)cc4)O2)O[C](c2ccc(/C=C/c4ccncc4)cc2)O3)C=C1 ,1 [CH]C1=C[CH]N([Cd]23(N4[CH]C=C(/C=C/c5ccc(C([O])=O)cc5)C=C4)(O[C](c4ccc(/C=C/c5ccncc5)cc4)O2)O[C](c2ccc(/C=C/c4ccncc4)cc2)O3)C=C1 ,1 [C]/C=C(C=[CH])/C=C/c1ccc([C]2O[Cd]3(N4[CH]C=C(/C=C/c5ccc(C([O])=O)cc5)C=C4)(N4[CH]C=C(/C=C/c5ccc(C([O])=O)cc5)C=C4)(O2)O[C](c2ccc(/C=C/c4ccncc4)cc2)O3)cc1 ,1 [C][CH]C(/C=C/c1ccc([C]2O[Cd]3(N4[CH]C=C(/C=C/c5c[c]c(C([O])=O)cc5)C=C4)(N4[CH]C=C(/C=C/c5ccc(C([O])=O)cc5)C=C4)(O2)O[C](c2ccc(/C=C/c4ccncc4)cc2)O3)cc1)=C\[C] ,1 [CH]C1=C[CH]N([Cd]23(N4[CH]C=C(/C=C/c5ccc(C([O])=O)cc5)C=C4)(O[C](c4ccc(/C=C/c5c[c]ncc5)cc4)O2)O[C](c2ccc(/C=C/c4ccncc4)cc2)O3)C=C1 ,1 [CH]=[C]/C=C/c1ccc([C]2O[Cd]3(N4[CH]C=C(/C=C/c5c[c]c(C([O])=O)cc5)C=C4)(N4[CH]C=C(/C=C/c5ccc(C([O])=O)cc5)C=C4)(O[C]O3)O2)cc1 ,1 [CH]=[C]/C=C/c1ccc([C]2O[Cd]3(N4[CH]C=C(/C=C/c5ccc(C([O])=O)cc5)C=C4)(N4[CH]C=C(/C=C/c5ccc(C([O])=O)cc5)C=C4)(O[C]O3)O2)cc1. Metal clusters: 1 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 3.17 A, density 1.54 g/cm3, surface area 4770.36 m2/g, accessible volume 0.19 cm3/g