(CH)2Hg3C48N6H40(O4Cl3)2 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two Hg3C48N6H40(O4Cl3)2 clusters. In each Hg3C48N6H40(O4Cl3)2 cluster, there are two inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(2) and two equivalent Cl(1) atoms. Both Hg(1)-N(2) bond lengths are 2.51 Å. Both Hg(1)-Cl(1) bond lengths are 2.38 Å. In the second Hg site, Hg(2) is bonded in a rectangular see-saw-like geometry to one N(1), one N(3), one Cl(2), and one Cl(3) atom. The Hg(2)-N(1) bond length is 2.46 Å. The Hg(2)-N(3) bond length is 2.47 Å. The Hg(2)-Cl(2) bond length is 2.42 Å. The Hg(2)-Cl(3) bond length is 2.38 Å. There are twenty-four inequivalent C sites. In the first C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(7) atom. The C(11)-C(10) bond length is 1.39 Å. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(7) bond length is 1.09 Å. In the second C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one N(1), and one H(8) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-N(1) bond length is 1.34 Å. The C(12)-H(8) bond length is 1.09 Å. In the third C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(9), and one H(9) atom. The C(13)-C(9) bond length is 1.40 Å. The C(13)-H(9) bond length is 1.09 Å. In the fourth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one C(15), one H(10), one H(11), and one O(3) atom. The C(14)-C(15) bond length is 1.51 Å. The C(14)-H(10) bond length is 1.10 Å. The C(14)-H(11) bond length is 1.11 Å. The C(14)-O(3) bond length is 1.42 Å. In the fifth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(19) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(19) bond length is 1.40 Å. In the sixth C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one H(12) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(12) bond length is 1.09 Å. In the seventh C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(2), and one H(13) atom. The C(17)-N(2) bond length is 1.34 Å. The C(17)-H(13) bond length is 1.09 Å. In the eighth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(19), one N(2), and one H(14) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-N(2) bond length is 1.34 Å. The C(18)-H(14) bond length is 1.09 Å. In the ninth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(15), one C(18), and one H(15) atom. The C(19)-H(15) bond length is 1.09 Å. In the tenth C site, C(20) is bonded in a distorted trigonal non-coplanar geometry to one C(21), one H(16), one H(17), and one O(4) atom. The C(20)-C(21) bond length is 1.50 Å. The C(20)-H(16) bond length is 1.10 Å. The C(20)-H(17) bond length is 1.10 Å. The C(20)-O(4) bond length is 1.43 Å. In the eleventh C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(25) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(25) bond length is 1.40 Å. In the twelfth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(18) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(18) bond length is 1.09 Å. In the thirteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one N(3), and one H(19) atom. The C(23)-N(3) bond length is 1.34 Å. The C(23)-H(19) bond length is 1.09 Å. In the fourteenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(25), one N(3), and one H(20) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-N(3) bond length is 1.34 Å. The C(24)-H(20) bond length is 1.09 Å. In the fifteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(21), one C(24), and one H(21) atom. The C(25)-H(21) bond length is 1.09 Å. In the sixteenth C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.49 Å. In the seventeenth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(1) bond length is 1.09 Å. In the eighteenth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one O(3) atom. The C(3)-O(3) bond length is 1.36 Å. In the nineteenth C site, C(5) is bonded in a distorted single-bond geometry to one O(4) atom. The C(5)-O(4) bond length is 1.37 Å. In the twentieth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the twenty-first C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.23 Å. The C(7)-O(2) bond length is 1.35 Å. In the twenty-second C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(4), one H(5), and one O(2) atom. The C(8)-C(9) bond length is 1.50 Å. The C(8)-H(4) bond length is 1.10 Å. The C(8)-H(5) bond length is 1.10 Å. The C(8)-O(2) bond length is 1.45 Å. In the twenty-third C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. In the twenty-fourth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(6) atom. The C(10)-H(6) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Hg(2), one C(11), and one C(12) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Hg(1), one C(17), and one C(18) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Hg(2), one C(23), and one C(24) atom. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(20) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the twentieth H site, H(21) is bonded in a single-bond geometry to one C(25) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(7) and one C(8) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(14) and one C(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(20) and one C(5) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Hg(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Hg(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Hg(2) atom. Linkers: 3 [CH]C(=[CH])COc1cc(OCc2ccncc2)cc(C(=O)OCc2ccncc2)c1 ,2 [C]/C=C(\C=[C]\[C]OCc1ccncc1)OCc1ccncc1 ,3 O=C(OCc1ccncc1)c1cc(OCc2ccncc2)cc(OCc2ccncc2)c1 ,1 [C][CH]/C(=C\[C][C]OCc1ccncc1)OCc1ccncc1. Metal clusters: . The MOF has largest included sphere 8.41 A, density 1.53 g/cm3, surface area 3713.36 m2/g, accessible volume 0.30 cm3/g