SrC24H14(NO2)4 crystallizes in the triclinic P-1 space group. Sr(1) is bonded in a 8-coordinate geometry to one N(1), one N(2), one N(3), one N(4), one O(3), one O(4), one O(5), and one O(6) atom. The Sr(1)-N(1) bond length is 2.74 Å. The Sr(1)-N(2) bond length is 2.74 Å. The Sr(1)-N(3) bond length is 2.76 Å. The Sr(1)-N(4) bond length is 2.77 Å. The Sr(1)-O(3) bond length is 2.57 Å. The Sr(1)-O(4) bond length is 2.56 Å. The Sr(1)-O(5) bond length is 2.57 Å. The Sr(1)-O(6) bond length is 2.56 Å. There are twenty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(1), and one O(3) atom. The C(1)-C(11) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.31 Å. The C(1)-O(3) bond length is 1.25 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(2), and one O(4) atom. The C(2)-C(12) bond length is 1.49 Å. The C(2)-O(2) bond length is 1.31 Å. The C(2)-O(4) bond length is 1.25 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(21) and one H(3,4) atom. The C(3)-C(21) bond length is 1.40 Å. The C(3)-H(3,4) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(22) and one H(3,4) atom. The C(4)-C(22) bond length is 1.40 Å. The C(4)-H(3,4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(15) and one H(5) atom. The C(5)-C(15) bond length is 1.40 Å. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(16) and one H(6) atom. The C(6)-C(16) bond length is 1.40 Å. The C(6)-H(6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(5), and one O(7) atom. The C(7)-C(23) bond length is 1.51 Å. The C(7)-O(5) bond length is 1.26 Å. The C(7)-O(7) bond length is 1.28 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(6), and one O(8) atom. The C(8)-C(24) bond length is 1.51 Å. The C(8)-O(6) bond length is 1.26 Å. The C(8)-O(8) bond length is 1.28 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(23); one N(1); and one H(7,8) atom. The C(9)-C(23) bond length is 1.40 Å. The C(9)-N(1) bond length is 1.33 Å. The C(9)-H(7,8) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(24); one N(2); and one H(7,8) atom. The C(10)-C(24) bond length is 1.40 Å. The C(10)-N(2) bond length is 1.33 Å. The C(10)-H(7,8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(1); one C(13,14); and one C(19,20) atom. The C(11)-C(13,14) bond length is 1.40 Å. The C(11)-C(19,20) bond length is 1.40 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(13,14); one C(19,20); and one C(2) atom. The C(12)-C(13,14) bond length is 1.40 Å. The C(12)-C(19,20) bond length is 1.40 Å. In the thirteenth C site, C(13,14) is bonded in a distorted single-bond geometry to one C(11) and one H(9,10) atom. The C(13,14)-H(9,10) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(21), one C(5), and one N(1) atom. The C(15)-C(21) bond length is 1.48 Å. The C(15)-N(1) bond length is 1.35 Å. In the fifteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(22), one C(6), and one N(2) atom. The C(16)-C(22) bond length is 1.48 Å. The C(16)-N(2) bond length is 1.35 Å. In the sixteenth C site, C(17,18) is bonded in a distorted single-bond geometry to one C(23) and one H(11,12) atom. The C(17,18)-C(23) bond length is 1.40 Å. The C(17,18)-H(11,12) bond length is 1.09 Å. In the seventeenth C site, C(19,20) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(3), and one H(13) atom. The C(19,20)-N(3) bond length is 1.33 Å. The C(19,20)-H(13) bond length is 1.09 Å. In the eighteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(15), one C(3), and one N(3) atom. The C(21)-N(3) bond length is 1.35 Å. In the nineteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(16), one C(4), and one N(4) atom. The C(22)-N(4) bond length is 1.35 Å. In the twentieth C site, C(23) is bonded in a trigonal planar geometry to one C(17,18); one C(7); and one C(9) atom. In the twenty-first C site, C(24) is bonded in a trigonal planar geometry to one C(10); one C(17,18); and one C(8) atom. The C(24)-C(17,18) bond length is 1.40 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Sr(1), one C(15), and one C(9) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one Sr(1), one C(10), and one C(16) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one Sr(1); one C(19,20); and one C(21) atom. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one Sr(1); one C(19,20); and one C(22) atom. The N(4)-C(19,20) bond length is 1.33 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(7) atom. The H(1)-O(2) bond length is 1.10 Å. The H(1)-O(7) bond length is 1.37 Å. In the second H site, H(2) is bonded in a linear geometry to one O(1) and one O(8) atom. The H(2)-O(1) bond length is 1.10 Å. The H(2)-O(8) bond length is 1.37 Å. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(13,14) atom. In the eighth H site, H(11,12) is bonded in a single-bond geometry to one C(17,18) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(19,20) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(19,20) atom. The H(14)-C(19,20) bond length is 1.09 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(1) and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(2) and one H(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sr(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Sr(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Sr(1) and one C(7) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Sr(1) and one C(8) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one C(7) and one H(1) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one C(8) and one H(2) atom. Linkers: 4 [O]C(=O)c1ccc(-c2ccc(C(=O)O)cn2)nc1. Metal clusters: 2 O=[C]O.O=[C]O[Sr]O[C]O.[O][C]=O. The MOF has largest included sphere 1.84 A, density 1.82 g/cm3, surface area 4040.32 m2/g, accessible volume 0.09 cm3/g