AgC8N5H12S2O7(CH)2(CH3)4CH2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four 02329_fluka molecules, sixteen 02329_fluka molecules, and two AgC8N5H12S2O7 clusters. In each AgC8N5H12S2O7 cluster, Ag(1) is bonded to one S(1), two equivalent S(2), and one O(5) atom to form distorted edge-sharing AgS3O trigonal pyramids. The Ag(1)-S(1) bond length is 2.39 Å. There is one shorter (2.40 Å) and one longer (2.94 Å) Ag(1)-S(2) bond length. The Ag(1)-O(5) bond length is 2.51 Å. There are eight inequivalent C sites. In the first C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one H(12), one H(13), and one O(1) atom. The C(4)-H(12) bond length is 1.10 Å. The C(4)-H(13) bond length is 1.10 Å. The C(4)-O(1) bond length is 1.46 Å. In the second C site, C(5) is bonded in a trigonal planar geometry to one N(1), one O(1), and one O(2) atom. The C(5)-N(1) bond length is 1.38 Å. The C(5)-O(1) bond length is 1.34 Å. The C(5)-O(2) bond length is 1.23 Å. In the third C site, C(6) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. The C(6)-N(1) bond length is 1.38 Å. The C(6)-N(2) bond length is 1.33 Å. The C(6)-S(1) bond length is 1.71 Å. In the fourth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(14), and one H(15) atom. The C(7)-N(2) bond length is 1.46 Å. The C(7)-H(14) bond length is 1.10 Å. The C(7)-H(15) bond length is 1.10 Å. In the fifth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(18), and one H(19) atom. The C(9)-N(3) bond length is 1.46 Å. The C(9)-H(18) bond length is 1.10 Å. The C(9)-H(19) bond length is 1.10 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one N(3), one N(4), and one S(2) atom. The C(10)-N(3) bond length is 1.33 Å. The C(10)-N(4) bond length is 1.37 Å. The C(10)-S(2) bond length is 1.71 Å. In the seventh C site, C(11) is bonded in a trigonal planar geometry to one N(4), one O(3), and one O(4) atom. The C(11)-N(4) bond length is 1.38 Å. The C(11)-O(3) bond length is 1.34 Å. The C(11)-O(4) bond length is 1.24 Å. In the eighth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one H(20), one H(21), and one O(3) atom. The C(12)-H(20) bond length is 1.10 Å. The C(12)-H(21) bond length is 1.10 Å. The C(12)-O(3) bond length is 1.45 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(5), one C(6), and one H(1) atom. The N(1)-H(1) bond length is 1.04 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(6), one C(7), and one H(2) atom. The N(2)-H(2) bond length is 1.03 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(9), and one H(3) atom. The N(3)-H(3) bond length is 1.03 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(11), and one H(4) atom. The N(4)-H(4) bond length is 1.04 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one O(5), one O(6), and one O(7) atom. The N(5)-O(5) bond length is 1.29 Å. The N(5)-O(6) bond length is 1.27 Å. The N(5)-O(7) bond length is 1.25 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one Ag(1) and one C(6) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one C(10) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(4) and one C(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(11) and one C(12) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Ag(1) and one N(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(5) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one N(5) atom. Linkers: 4 CC(C)COC(=O)NC(=S)NCCCNC(=S)NC(=O)OCC(C)C ,2 [CH2]C(C)COC(=O)NC(=S)NCCCNC(=S)NC(=O)OCC(C)C ,2 CC(C)COC(=O)NC(=S)NCCCNC(=S)[N][C]=O ,2 CC(C)COC(=O)NC(=S)NCCCNC(=S)NC([O])=O. Metal clusters: 4 [Ag]. The MOF has largest included sphere 3.89 A, density 1.50 g/cm3, surface area 4684.87 m2/g, accessible volume 0.19 cm3/g