Zn2C8N13H12O2CH3 crystallizes in the monoclinic P2_1 space group. The structure consists of four 02329_fluka molecules inside a Zn2C8N13H12O2 framework. In the Zn2C8N13H12O2 framework, there are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one N(4), one N(5), one N(9), and one O(2) atom. The Zn(1)-N(4) bond length is 1.99 Å. The Zn(1)-N(5) bond length is 1.99 Å. The Zn(1)-N(9) bond length is 2.00 Å. The Zn(1)-O(2) bond length is 2.00 Å. In the second Zn site, Zn(2) is bonded in a trigonal bipyramidal geometry to one N(20), one N(24), one N(25), one N(8), and one O(1) atom. The Zn(2)-N(20) bond length is 2.01 Å. The Zn(2)-N(24) bond length is 2.01 Å. The Zn(2)-N(25) bond length is 2.10 Å. The Zn(2)-N(8) bond length is 2.08 Å. The Zn(2)-O(1) bond length is 2.31 Å. In the third Zn site, Zn(3) is bonded in a trigonal bipyramidal geometry to one N(1), one N(12), one N(16), one N(26), and one O(3) atom. The Zn(3)-N(1) bond length is 2.02 Å. The Zn(3)-N(12) bond length is 2.02 Å. The Zn(3)-N(16) bond length is 2.08 Å. The Zn(3)-N(26) bond length is 2.12 Å. The Zn(3)-O(3) bond length is 2.26 Å. In the fourth Zn site, Zn(4) is bonded in a tetrahedral geometry to one N(13), one N(17), one N(21), and one O(4) atom. The Zn(4)-N(13) bond length is 1.99 Å. The Zn(4)-N(17) bond length is 1.99 Å. The Zn(4)-N(21) bond length is 1.99 Å. The Zn(4)-O(4) bond length is 2.00 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one N(4) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(4) bond length is 1.34 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one H(5), one H(6), and one H(7) atom. The C(2)-H(5) bond length is 1.10 Å. The C(2)-H(6) bond length is 1.10 Å. The C(2)-H(7) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(5), and one N(8) atom. The C(3)-C(4) bond length is 1.48 Å. The C(3)-N(5) bond length is 1.35 Å. The C(3)-N(8) bond length is 1.34 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one H(10), one H(8), and one H(9) atom. The C(4)-H(10) bond length is 1.10 Å. The C(4)-H(8) bond length is 1.10 Å. The C(4)-H(9) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(12), and one N(9) atom. The C(5)-C(6) bond length is 1.48 Å. The C(5)-N(12) bond length is 1.34 Å. The C(5)-N(9) bond length is 1.34 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one H(11), one H(12), and one H(13) atom. The C(6)-H(11) bond length is 1.10 Å. The C(6)-H(12) bond length is 1.10 Å. The C(6)-H(13) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(13), and one N(16) atom. The C(7)-C(8) bond length is 1.48 Å. The C(7)-N(13) bond length is 1.35 Å. The C(7)-N(16) bond length is 1.34 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(7), one H(14), one H(15), and one H(16) atom. The C(8)-H(14) bond length is 1.09 Å. The C(8)-H(15) bond length is 1.10 Å. The C(8)-H(16) bond length is 1.10 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(17), and one N(20) atom. The C(9)-C(10) bond length is 1.48 Å. The C(9)-N(17) bond length is 1.34 Å. The C(9)-N(20) bond length is 1.34 Å. In the tenth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(17), one H(18), and one H(19) atom. The C(10)-H(17) bond length is 1.10 Å. The C(10)-H(18) bond length is 1.10 Å. The C(10)-H(19) bond length is 1.10 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(21), and one N(24) atom. The C(11)-C(12) bond length is 1.48 Å. The C(11)-N(21) bond length is 1.34 Å. The C(11)-N(24) bond length is 1.34 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one H(20), one H(21), and one H(22) atom. The C(12)-H(20) bond length is 1.09 Å. The C(12)-H(21) bond length is 1.10 Å. The C(12)-H(22) bond length is 1.10 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(13)-O(1) bond length is 1.26 Å. The C(13)-O(2) bond length is 1.28 Å. In the fourteenth C site, C(14) is bonded in a distorted water-like geometry to one N(25) and one H(23) atom. The C(14)-N(25) bond length is 1.48 Å. The C(14)-H(23) bond length is 1.10 Å. In the fifteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(16)-O(3) bond length is 1.26 Å. The C(16)-O(4) bond length is 1.28 Å. In the sixteenth C site, C(17) is bonded in a 2-coordinate geometry to one N(26) and one H(27) atom. The C(17)-N(26) bond length is 1.48 Å. The C(17)-H(27) bond length is 1.10 Å. There are twenty-six inequivalent N sites. In the first N site, N(13) is bonded in a distorted trigonal planar geometry to one Zn(4), one C(7), and one N(14) atom. The N(13)-N(14) bond length is 1.36 Å. In the second N site, N(14) is bonded in a water-like geometry to one N(13) and one N(15) atom. The N(14)-N(15) bond length is 1.30 Å. In the third N site, N(15) is bonded in a water-like geometry to one N(14) and one N(16) atom. The N(15)-N(16) bond length is 1.36 Å. In the fourth N site, N(16) is bonded in a 3-coordinate geometry to one Zn(3), one C(7), and one N(15) atom. In the fifth N site, N(17) is bonded in a 3-coordinate geometry to one Zn(4), one C(9), and one N(18) atom. The N(17)-N(18) bond length is 1.36 Å. In the sixth N site, N(18) is bonded in a water-like geometry to one N(17) and one N(19) atom. The N(18)-N(19) bond length is 1.30 Å. In the seventh N site, N(19) is bonded in a water-like geometry to one N(18) and one N(20) atom. The N(19)-N(20) bond length is 1.36 Å. In the eighth N site, N(20) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(9), and one N(19) atom. In the ninth N site, N(21) is bonded in a distorted trigonal planar geometry to one Zn(4), one C(11), and one N(22) atom. The N(21)-N(22) bond length is 1.36 Å. In the tenth N site, N(22) is bonded in a water-like geometry to one N(21) and one N(23) atom. The N(22)-N(23) bond length is 1.30 Å. In the eleventh N site, N(23) is bonded in a water-like geometry to one N(22) and one N(24) atom. The N(23)-N(24) bond length is 1.36 Å. In the twelfth N site, N(24) is bonded in a 3-coordinate geometry to one Zn(2), one C(11), and one N(23) atom. In the thirteenth N site, N(25) is bonded in a distorted tetrahedral geometry to one Zn(2), one C(14), one H(1), and one H(2) atom. The N(25)-H(1) bond length is 1.02 Å. The N(25)-H(2) bond length is 1.02 Å. In the fourteenth N site, N(26) is bonded in a distorted tetrahedral geometry to one Zn(3), one C(17), one H(3), and one H(4) atom. The N(26)-H(3) bond length is 1.02 Å. The N(26)-H(4) bond length is 1.02 Å. In the fifteenth N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(3), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the sixteenth N site, N(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.30 Å. In the seventeenth N site, N(3) is bonded in a water-like geometry to one N(2) and one N(4) atom. The N(3)-N(4) bond length is 1.36 Å. In the eighteenth N site, N(4) is bonded in a 3-coordinate geometry to one Zn(1), one C(1), and one N(3) atom. In the nineteenth N site, N(5) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(3), and one N(6) atom. The N(5)-N(6) bond length is 1.36 Å. In the twentieth N site, N(6) is bonded in a water-like geometry to one N(5) and one N(7) atom. The N(6)-N(7) bond length is 1.30 Å. In the twenty-first N site, N(7) is bonded in a water-like geometry to one N(6) and one N(8) atom. The N(7)-N(8) bond length is 1.36 Å. In the twenty-second N site, N(8) is bonded in a 3-coordinate geometry to one Zn(2), one C(3), and one N(7) atom. In the twenty-third N site, N(9) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(5), and one N(10) atom. The N(9)-N(10) bond length is 1.36 Å. In the twenty-fourth N site, N(10) is bonded in a water-like geometry to one N(11) and one N(9) atom. The N(10)-N(11) bond length is 1.30 Å. In the twenty-fifth N site, N(11) is bonded in a water-like geometry to one N(10) and one N(12) atom. The N(11)-N(12) bond length is 1.36 Å. In the twenty-sixth N site, N(12) is bonded in a distorted trigonal planar geometry to one Zn(3), one C(5), and one N(11) atom. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(25) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(25) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(26) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(26) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(4) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(6) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(8) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(8) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(8) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(10) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(10) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(10) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(12) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(12) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(12) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(14) atom. In the twenty-fourth H site, H(27) is bonded in a single-bond geometry to one C(17) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Zn(2) and one C(13) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Zn(3) and one C(16) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(16) atom. Linkers: 12 CC1=NN=N[N]1 ,4 C[C@@H](N)C([O])=O. Metal clusters: 4 C[C@H]1[NH2][Zn]O[C]1O[Zn]. The MOF has largest included sphere 4.27 A, density 1.41 g/cm3, surface area 4524.56 m2/g, accessible volume 0.36 cm3/g