(CH2)5CHCuC5NH6SICH2CO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, ten 02329_fluka molecules, two dimethyl ether molecules, and one CuC5NH6SI cluster. In the CuC5NH6SI cluster, Cu(1) is bonded in a 4-coordinate geometry to one N(1), one S(1), and two equivalent I(1) atoms. The Cu(1)-N(1) bond length is 2.06 Å. The Cu(1)-S(1) bond length is 2.27 Å. There is one shorter (2.61 Å) and one longer (2.70 Å) Cu(1)-I(1) bond length. There are five inequivalent C sites. In the first C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(14) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(14) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one H(3) and one S(1) atom. The C(2)-H(3) bond length is 1.10 Å. The C(2)-S(1) bond length is 1.83 Å. In the third C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(1), and one H(16) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(16) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a distorted water-like geometry to one H(12), one H(13), and one S(1) atom. The C(8)-H(12) bond length is 1.10 Å. The C(8)-H(13) bond length is 1.10 Å. The C(8)-S(1) bond length is 1.82 Å. In the fifth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(17) atom. The C(12)-H(17) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(9) atom. There are six inequivalent H sites. In the first H site, H(16) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(17) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(9) atom. S(1) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(2), and one C(8) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 2 c1cc(OCCSC2CCCCC2)ccn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 4.14 A, density 1.68 g/cm3, surface area 4170.42 m2/g, accessible volume 0.23 cm3/g