CuC14N4H8(OF)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CuC14N4H8(OF)4 cluster. Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 1.97 Å. Both Cu(1)-O(1) bond lengths are 2.02 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(2) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(3) atom. The C(3)-N(1) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(2) atom. The C(4)-C(5) bond length is 1.51 Å. The C(4)-O(1) bond length is 1.29 Å. The C(4)-O(2) bond length is 1.25 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(7) bond length is 1.39 Å. In the sixth C site, C(6) is bonded in a single-bond geometry to one C(5) and one F(1) atom. The C(6)-F(1) bond length is 1.35 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one F(2) atom. The C(7)-F(2) bond length is 1.36 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one H(4) atom. The N(2)-H(4) bond length is 1.03 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(4) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one C(7) atom. In the second F site, F(1) is bonded in a single-bond geometry to one C(6) atom. Linkers: 1 [O]C(=O)c1c(F)c(F)c(C([O])=O)c(F)c1F. Metal clusters: 1 [Cu]. The MOF has largest included sphere 1.98 A, density 1.92 g/cm3, surface area 3712.62 m2/g, accessible volume 0.08 cm3/g