(CH)2CuC16N3H10SO4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one CuC16N3H10SO4 cluster. In the CuC16N3H10SO4 cluster, Cu(1) is bonded to one N(1), one N(2), one N(3), one O(1), and one O(3) atom to form distorted CuN3O2 square pyramids that share corners with two equivalent S(1)O4 tetrahedra. The Cu(1)-N(1) bond length is 2.07 Å. The Cu(1)-N(2) bond length is 1.95 Å. The Cu(1)-N(3) bond length is 2.04 Å. The Cu(1)-O(1) bond length is 2.25 Å. The Cu(1)-O(3) bond length is 1.96 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.47 Å. The C(5)-N(1) bond length is 1.36 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-N(2) bond length is 1.35 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-H(5) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(16), one C(7), and one C(9) atom. The C(8)-C(16) bond length is 1.48 Å. The C(8)-C(9) bond length is 1.41 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(6) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one N(2) atom. The C(10)-C(11) bond length is 1.47 Å. The C(10)-N(2) bond length is 1.34 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(3) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-N(3) bond length is 1.36 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(9) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one H(10) atom. The C(15)-N(3) bond length is 1.34 Å. The C(15)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(8) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(18) bond length is 1.41 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(17)-H(11) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(18)-H(12) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(15) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with two equivalent Cu(1)N3O2 square pyramids. The S(1)-O(1) bond length is 1.50 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.54 Å. The S(1)-O(4) bond length is 1.47 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. Linkers: 2 [c]1cc(-c2ccc(-c3cc(-c4ccccn4)nc(-c4ccccn4)c3)cc2)cc(-c2ccccn2)n1 ,1 c1ccc(-c2cc(-c3ccc(-c4cc(-c5ccccn5)nc(-c5ccccn5)c4)cc3)cc(-c3ccccn3)n2)nc1. Metal clusters: 1 [O]S1([O])O[Cu]OS([O])([O])O[Cu]O1. The MOF has largest included sphere 2.81 A, density 1.84 g/cm3, surface area 3507.59 m2/g, accessible volume 0.09 cm3/g