CuC22H14(N6O7)2(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two CuC22H14(N6O7)2 clusters. In each CuC22H14(N6O7)2 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Cu(1)-N(1) bond length is 1.97 Å. The Cu(1)-N(2) bond length is 1.97 Å. The Cu(1)-O(1) bond length is 1.99 Å. The Cu(1)-O(2) bond length is 2.07 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(1) atom. The C(1)-N(10) bond length is 1.37 Å. The C(1)-N(12) bond length is 1.32 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(10), one N(2), and one H(2) atom. The C(2)-N(10) bond length is 1.36 Å. The C(2)-N(2) bond length is 1.32 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(26), one N(9), and one O(10) atom. The C(3)-C(26) bond length is 1.51 Å. The C(3)-N(9) bond length is 1.39 Å. The C(3)-O(10) bond length is 1.23 Å. In the fourth C site, C(6) is bonded in a single-bond geometry to one C(25) and one H(7) atom. The C(6)-C(25) bond length is 1.51 Å. The C(6)-H(7) bond length is 1.10 Å. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one N(6), one N(7), and one H(14) atom. The C(9)-N(6) bond length is 1.31 Å. The C(9)-N(7) bond length is 1.37 Å. The C(9)-H(14) bond length is 1.08 Å. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one N(1), one N(7), and one H(15) atom. The C(10)-N(1) bond length is 1.32 Å. The C(10)-N(7) bond length is 1.36 Å. The C(10)-H(15) bond length is 1.09 Å. In the seventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(2), and one O(8) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-O(2) bond length is 1.28 Å. The C(11)-O(8) bond length is 1.26 Å. In the eighth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(17) bond length is 1.40 Å. In the ninth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(16) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(16) bond length is 1.09 Å. In the tenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one N(3) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-N(3) bond length is 1.47 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(17) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(17) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one N(4) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-N(4) bond length is 1.47 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one H(18) atom. The C(17)-H(18) bond length is 1.09 Å. In the fourteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(1), and one O(5) atom. The C(18)-C(19) bond length is 1.51 Å. The C(18)-O(1) bond length is 1.30 Å. The C(18)-O(5) bond length is 1.25 Å. In the fifteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-C(24) bond length is 1.40 Å. In the sixteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(19) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(19) bond length is 1.09 Å. In the seventeenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one N(11) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-N(11) bond length is 1.48 Å. In the eighteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(20) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(20) bond length is 1.09 Å. In the nineteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one N(5) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-N(5) bond length is 1.47 Å. In the twentieth C site, C(24) is bonded in a distorted single-bond geometry to one C(19), one C(23), and one H(21) atom. The C(24)-H(21) bond length is 1.09 Å. In the twenty-first C site, C(25) is bonded in a distorted trigonal planar geometry to one C(6), one N(8), and one O(9) atom. The C(25)-N(8) bond length is 1.37 Å. The C(25)-O(9) bond length is 1.24 Å. In the twenty-second C site, C(26) is bonded in a distorted single-bond geometry to one C(3) and one H(22) atom. The C(26)-H(22) bond length is 1.10 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(10), and one N(6) atom. The N(1)-N(6) bond length is 1.38 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(2), and one N(12) atom. The N(2)-N(12) bond length is 1.38 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(14), one O(11), and one O(12) atom. The N(3)-O(11) bond length is 1.24 Å. The N(3)-O(12) bond length is 1.24 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(16), one O(13), and one O(14) atom. The N(4)-O(13) bond length is 1.24 Å. The N(4)-O(14) bond length is 1.24 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(23), one O(6), and one O(7) atom. The N(5)-O(6) bond length is 1.24 Å. The N(5)-O(7) bond length is 1.24 Å. In the sixth N site, N(6) is bonded in a distorted water-like geometry to one C(9) and one N(1) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one C(10), one C(9), and one N(8) atom. The N(7)-N(8) bond length is 1.37 Å. In the eighth N site, N(8) is bonded in a 3-coordinate geometry to one C(25), one N(7), and one H(10) atom. The N(8)-H(10) bond length is 1.04 Å. In the ninth N site, N(9) is bonded in a 3-coordinate geometry to one C(3), one N(10), and one H(13) atom. The N(9)-N(10) bond length is 1.38 Å. The N(9)-H(13) bond length is 1.03 Å. In the tenth N site, N(10) is bonded in a distorted trigonal planar geometry to one C(1), one C(2), and one N(9) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one C(21), one O(3), and one O(4) atom. The N(11)-O(3) bond length is 1.24 Å. The N(11)-O(4) bond length is 1.24 Å. In the twelfth N site, N(12) is bonded in a distorted water-like geometry to one C(1) and one N(2) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one N(8) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one N(9) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(26) atom. There are fourteen inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one N(11) atom. In the second O site, O(5) is bonded in a single-bond geometry to one C(18) atom. In the third O site, O(6) is bonded in a single-bond geometry to one N(5) atom. In the fourth O site, O(7) is bonded in a single-bond geometry to one N(5) atom. In the fifth O site, O(8) is bonded in a distorted single-bond geometry to one C(11) atom. In the sixth O site, O(9) is bonded in a single-bond geometry to one C(25) atom. In the seventh O site, O(10) is bonded in a single-bond geometry to one C(3) atom. In the eighth O site, O(11) is bonded in a single-bond geometry to one N(3) atom. In the ninth O site, O(12) is bonded in a single-bond geometry to one N(3) atom. In the tenth O site, O(13) is bonded in a single-bond geometry to one N(4) atom. In the eleventh O site, O(14) is bonded in a single-bond geometry to one N(4) atom. In the twelfth O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(18) atom. In the thirteenth O site, O(2) is bonded in a distorted water-like geometry to one Cu(1) and one C(11) atom. In the fourteenth O site, O(3) is bonded in a single-bond geometry to one N(11) atom. Linkers: 2 O=C(Nn1cnnc1)[C@H]1CC[C@H](C(=O)Nn2cnnc2)CC1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.97 A, density 1.69 g/cm3, surface area 4418.53 m2/g, accessible volume 0.14 cm3/g