Ag2C3H3(N2O3)2CH crystallizes in the monoclinic Pc space group. The structure consists of two 02329_fluka molecules inside a Ag2C3H3(N2O3)2 framework. In the Ag2C3H3(N2O3)2 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one O(1), and two equivalent O(3) atoms. The Ag(1)-N(1) bond length is 2.19 Å. The Ag(1)-O(1) bond length is 2.34 Å. There is one shorter (2.38 Å) and one longer (2.74 Å) Ag(1)-O(3) bond length. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one N(2), one O(2), and one O(4) atom. The Ag(2)-N(2) bond length is 2.17 Å. The Ag(2)-O(2) bond length is 2.31 Å. The Ag(2)-O(4) bond length is 2.40 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(2) and one H(2,3) atom. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(2,3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2,3) atom. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(2,3) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(2), one C(1), and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(5) atom. The N(3)-O(1) bond length is 1.28 Å. The N(3)-O(3) bond length is 1.28 Å. The N(3)-O(5) bond length is 1.25 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(6) atom. The N(4)-O(2) bond length is 1.28 Å. The N(4)-O(4) bond length is 1.28 Å. The N(4)-O(6) bond length is 1.25 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(2) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one N(3) atom. In the second O site, O(4) is bonded in a 2-coordinate geometry to one Ag(2) and one N(4) atom. In the third O site, O(5) is bonded in a single-bond geometry to one N(3) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one N(4) atom. In the fifth O site, O(1) is bonded in a distorted water-like geometry to one Ag(1) and one N(3) atom. In the sixth O site, O(2) is bonded in a water-like geometry to one Ag(2) and one N(4) atom. Linkers: 2 c1cncnc1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.44 A, density 2.97 g/cm3, surface area 2643.02 m2/g, accessible volume 0.04 cm3/g