MnC17N2H9O5(CH)7 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of fourteen 02329_fluka molecules and one MnC17N2H9O5 cluster. In the MnC17N2H9O5 cluster, Mn(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(4), and one O(5) atom. The Mn(1)-N(1) bond length is 2.25 Å. The Mn(1)-N(2) bond length is 2.25 Å. The Mn(1)-O(1) bond length is 2.08 Å. The Mn(1)-O(2) bond length is 2.12 Å. The Mn(1)-O(4) bond length is 2.41 Å. The Mn(1)-O(5) bond length is 2.22 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one O(3) atom. The C(6)-O(3) bond length is 1.39 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(13) and one O(3) atom. The C(8)-C(13) bond length is 1.41 Å. The C(8)-O(3) bond length is 1.38 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(8) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(8) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(8) atom. The C(13)-C(14) bond length is 1.50 Å. In the ninth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(4), and one O(5) atom. The C(14)-O(4) bond length is 1.27 Å. The C(14)-O(5) bond length is 1.29 Å. In the tenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(15)-N(1) bond length is 1.34 Å. The C(15)-H(9) bond length is 1.09 Å. In the eleventh C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(12) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-H(12) bond length is 1.09 Å. In the twelfth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one N(1) atom. The C(19)-C(20) bond length is 1.48 Å. The C(19)-N(1) bond length is 1.35 Å. In the thirteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one N(2) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-N(2) bond length is 1.35 Å. In the fourteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(13) atom. The C(21)-H(13) bond length is 1.09 Å. In the fifteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(14) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(14) bond length is 1.09 Å. In the sixteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one H(15) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-H(15) bond length is 1.09 Å. In the seventeenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(23), one N(2), and one H(16) atom. The C(24)-N(2) bond length is 1.34 Å. The C(24)-H(16) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(1), one C(15), and one C(19) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(1), one C(20), and one C(24) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(6) and one C(8) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Mn(1) and one C(14) atom. In the fifth O site, O(5) is bonded in a distorted L-shaped geometry to one Mn(1) and one C(14) atom. Linkers: 2 [O]C(=O)c1cccc(Oc2ccccc2C([O])=O)c1. Metal clusters: 1 [C]1O[Mn]2(O1)O[C]O[Mn]1(O[C]O1)O[C]O2. The MOF has largest included sphere 2.73 A, density 1.58 g/cm3, surface area 4419.15 m2/g, accessible volume 0.13 cm3/g