ZnC14H12(NO)4(C3H2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 2,3-dimethyl-1,3-butadiene molecules and four ZnC14H12(NO)4 clusters. In each ZnC14H12(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(2) and two equivalent O(1) atoms. Both Zn(1)-N(2) bond lengths are 2.01 Å. Both Zn(1)-O(1) bond lengths are 1.99 Å. There are seven inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(4) and one H(4,7) atom. The C(9)-C(4) bond length is 1.40 Å. The C(9)-H(4,7) bond length is 1.09 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the third C site, C(10) is bonded in a trigonal planar geometry to one H(8), one O(1), and one O(2) atom. The C(10)-H(8) bond length is 1.11 Å. The C(10)-O(1) bond length is 1.29 Å. The C(10)-O(2) bond length is 1.25 Å. In the fourth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(2) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the fifth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(3) atom. The C(3)-N(1) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.08 Å. In the sixth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one N(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(1) bond length is 1.42 Å. In the seventh C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4,7) atom. The C(5)-H(4,7) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. There are five inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(4,7) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(10) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(10) atom. Linkers: 2 c1cn(-c2ccc(-c3ccc(-n4ccnc4)cc3)cc2)cn1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.89 A, density 1.66 g/cm3, surface area 4703.23 m2/g, accessible volume 0.14 cm3/g