SrCuC14N2H12O11 crystallizes in the triclinic P-1 space group. Sr(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(2), one O(3), one O(6), one O(9), and two equivalent O(7) atoms. The Sr(1)-O(10) bond length is 2.64 Å. The Sr(1)-O(11) bond length is 2.59 Å. The Sr(1)-O(2) bond length is 2.53 Å. The Sr(1)-O(3) bond length is 2.53 Å. The Sr(1)-O(6) bond length is 2.54 Å. The Sr(1)-O(9) bond length is 2.70 Å. There is one shorter (2.66 Å) and one longer (2.76 Å) Sr(1)-O(7) bond length. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in an octahedral geometry to two equivalent N(2), two equivalent O(5), and two equivalent O(8) atoms. Both Cu(1)-N(2) bond lengths are 1.96 Å. Both Cu(1)-O(5) bond lengths are 2.00 Å. Both Cu(1)-O(8) bond lengths are 2.50 Å. In the second Cu site, Cu(2) is bonded in a distorted octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(4) atoms. Both Cu(2)-N(1) bond lengths are 1.96 Å. Both Cu(2)-O(1) bond lengths are 1.96 Å. Both Cu(2)-O(4) bond lengths are 2.60 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.52 Å. The C(1)-N(1) bond length is 1.35 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(7) bond length is 1.52 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(3) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.29 Å. The C(6)-O(2) bond length is 1.25 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(7)-O(3) bond length is 1.27 Å. The C(7)-O(4) bond length is 1.27 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one N(2) atom. The C(8)-C(13) bond length is 1.51 Å. The C(8)-C(9) bond length is 1.40 Å. The C(8)-N(2) bond length is 1.35 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.52 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(8) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(9) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(9) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one H(12) atom. The C(12)-N(2) bond length is 1.34 Å. The C(12)-H(12) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(5), and one O(6) atom. The C(13)-O(5) bond length is 1.29 Å. The C(13)-O(6) bond length is 1.25 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(7), and one O(8) atom. The C(14)-O(7) bond length is 1.27 Å. The C(14)-O(8) bond length is 1.26 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(2), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(12), and one C(8) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(9) atom. The H(4)-O(9) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(9) atom. The H(5)-O(9) bond length is 0.98 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(10) atom. The H(6)-O(10) bond length is 0.98 Å. In the seventh H site, H(7) is bonded in a distorted linear geometry to one O(10) and one O(8) atom. The H(7)-O(10) bond length is 1.01 Å. The H(7)-O(8) bond length is 1.64 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a distorted linear geometry to one O(11) and one O(4) atom. The H(10)-O(11) bond length is 1.02 Å. The H(10)-O(4) bond length is 1.61 Å. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(11) atom. The H(11)-O(11) bond length is 0.98 Å. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(6) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Sr(1) and one C(6) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sr(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Cu(2), one C(7), and one H(10) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(13) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Sr(1) and one C(13) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one C(14) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Cu(1), one C(14), and one H(7) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Sr(1), one H(4), and one H(5) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Sr(1), one H(6), and one H(7) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Sr(1), one H(10), and one H(11) atom. Linkers: 4 [O]C(=O)c1cccnc1C([O])=O. Metal clusters: 2 [Sr] ,2 [Cu]. The MOF has largest included sphere 3.76 A, density 1.85 g/cm3, surface area 3301.04 m2/g, accessible volume 0.15 cm3/g