CuC8N5H7O4(CH2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and one CuC8N5H7O4 cluster. In the CuC8N5H7O4 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(4), one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-N(4) bond length is 2.19 Å. The Cu(1)-O(1) bond length is 2.00 Å. The Cu(1)-O(2) bond length is 1.99 Å. The Cu(1)-O(3) bond length is 2.00 Å. The Cu(1)-O(4) bond length is 2.01 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a tetrahedral geometry to one N(2), one H(2), one H(3), and one H(4) atom. The C(2)-N(2) bond length is 1.46 Å. The C(2)-H(2) bond length is 1.09 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one N(5) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-N(2) bond length is 1.37 Å. The C(3)-N(5) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one N(4) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-N(4) bond length is 1.38 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one N(3) atom. The C(5)-N(1) bond length is 1.38 Å. The C(5)-N(3) bond length is 1.33 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(7) atom. The C(6)-N(4) bond length is 1.35 Å. The C(6)-N(5) bond length is 1.36 Å. The C(6)-H(7) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(7)-O(1) bond length is 1.28 Å. The C(7)-O(2) bond length is 1.27 Å. In the eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(11)-O(3) bond length is 1.28 Å. The C(11)-O(4) bond length is 1.27 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(5), one H(5), and one H(6) atom. The N(3)-H(5) bond length is 1.03 Å. The N(3)-H(6) bond length is 1.03 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(4), and one C(6) atom. In the fifth N site, N(5) is bonded in a water-like geometry to one C(3) and one C(6) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(11) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(11) atom. Linkers: 2 [O]C(=O)CCCC([O])=O. Metal clusters: 2 [Cu]. The MOF has largest included sphere 3.20 A, density 1.62 g/cm3, surface area 4162.57 m2/g, accessible volume 0.17 cm3/g