CHCuC12N6H11OClF2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and four CuC12N6H11OClF2 clusters. In each CuC12N6H11OClF2 cluster, Cu(1) is bonded in a distorted trigonal planar geometry to one N(3), one N(6), and one Cl(1) atom. The Cu(1)-N(3) bond length is 2.00 Å. The Cu(1)-N(6) bond length is 1.92 Å. The Cu(1)-Cl(1) bond length is 2.24 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(2) atom. The C(1)-N(2) bond length is 1.33 Å. The C(1)-N(3) bond length is 1.37 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(3) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-N(3) bond length is 1.34 Å. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(4) atom. The C(3)-N(5) bond length is 1.33 Å. The C(3)-N(6) bond length is 1.38 Å. The C(3)-H(4) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(5) atom. The C(4)-N(4) bond length is 1.34 Å. The C(4)-N(6) bond length is 1.34 Å. The C(4)-H(5) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(6), and one H(7) atom. The C(5)-N(1) bond length is 1.45 Å. The C(5)-H(6) bond length is 1.09 Å. The C(5)-H(7) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(8) and one O(1) atom. The C(6)-C(8) bond length is 1.53 Å. The C(6)-O(1) bond length is 1.42 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(8), and one H(9) atom. The C(7)-N(4) bond length is 1.45 Å. The C(7)-H(8) bond length is 1.09 Å. The C(7)-H(9) bond length is 1.10 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(6), and one C(9) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one F(1) atom. The C(9)-F(1) bond length is 1.38 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one F(2) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-F(2) bond length is 1.37 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(11) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(11) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(12) atom. The C(13)-H(12) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(5), and one N(2) atom. The N(1)-N(2) bond length is 1.37 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(1) and one N(1) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(4), one C(7), and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one C(3) and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(4) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) and one Cl(1) atom. The H(1)-O(1) bond length is 1.00 Å. The H(1)-Cl(1) bond length is 2.10 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(13) atom. O(1) is bonded in a bent 120 degrees geometry to one C(6) and one H(1) atom. Cl(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one H(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(9) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(11) atom. Linkers: 1 O[C@@](CN1[CH]N=C[N]1)(Cn1cncn1)c1ccc(F)cc1F ,1 O[C@](CN1[CH]N=C[N]1)(Cn1cncn1)c1ccc(F)cc1F ,2 OC(Cn1cncn1)(Cn1cncn1)c1ccc(F)cc1F. Metal clusters: 4 Cl[Cu]. The MOF has largest included sphere 2.03 A, density 1.80 g/cm3, surface area 4147.26 m2/g, accessible volume 0.13 cm3/g