CuC19N7H17F6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CuC19N7H17F6 clusters. Cu(1) is bonded in a distorted square pyramidal geometry to one N(2), one N(3), one N(4), one N(6), and one N(7) atom. The Cu(1)-N(2) bond length is 2.03 Å. The Cu(1)-N(3) bond length is 2.01 Å. The Cu(1)-N(4) bond length is 2.04 Å. The Cu(1)-N(6) bond length is 2.46 Å. The Cu(1)-N(7) bond length is 2.09 Å. There are nineteen inequivalent C sites. In the first C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one N(7), one H(8), and one H(9) atom. The C(15)-N(7) bond length is 1.49 Å. The C(15)-H(8) bond length is 1.09 Å. The C(15)-H(9) bond length is 1.10 Å. In the second C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(10), and one H(11) atom. The C(16)-N(6) bond length is 1.48 Å. The C(16)-H(10) bond length is 1.10 Å. The C(16)-H(11) bond length is 1.10 Å. In the third C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one N(7), one H(12), and one H(13) atom. The C(17)-N(7) bond length is 1.49 Å. The C(17)-H(12) bond length is 1.10 Å. The C(17)-H(13) bond length is 1.10 Å. In the fourth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(14), and one H(15) atom. The C(18)-N(6) bond length is 1.48 Å. The C(18)-H(14) bond length is 1.10 Å. The C(18)-H(15) bond length is 1.10 Å. In the fifth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one N(7), one H(16), and one H(17) atom. The C(19)-N(7) bond length is 1.49 Å. The C(19)-H(16) bond length is 1.10 Å. The C(19)-H(17) bond length is 1.10 Å. In the sixth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(13), one C(2), and one N(1) atom. The C(1)-C(13) bond length is 1.48 Å. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.36 Å. In the seventh C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(1) bond length is 1.08 Å. In the eighth C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one N(2) atom. The C(3)-C(4) bond length is 1.45 Å. The C(3)-N(2) bond length is 1.38 Å. In the ninth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one N(3) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(3) bond length is 1.35 Å. In the tenth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(2) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(2) bond length is 1.09 Å. In the eleventh C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(3) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(3) bond length is 1.09 Å. In the twelfth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(4) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(4) bond length is 1.09 Å. In the thirteenth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(3) atom. The C(8)-C(9) bond length is 1.44 Å. The C(8)-N(3) bond length is 1.35 Å. In the fourteenth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one N(4) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-N(4) bond length is 1.38 Å. In the fifteenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(5) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(5) bond length is 1.08 Å. In the sixteenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(5) atom. The C(11)-C(12) bond length is 1.48 Å. The C(11)-N(5) bond length is 1.36 Å. In the seventeenth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one F(1), one F(2), and one F(3) atom. The C(12)-F(1) bond length is 1.38 Å. The C(12)-F(2) bond length is 1.38 Å. The C(12)-F(3) bond length is 1.36 Å. In the eighteenth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one C(1); one F(6); and two equivalent F(4,5) atoms. The C(13)-F(6) bond length is 1.36 Å. Both C(13)-F(4,5) bond lengths are 1.38 Å. In the nineteenth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(6), and one H(7) atom. The C(14)-N(6) bond length is 1.48 Å. The C(14)-H(6) bond length is 1.10 Å. The C(14)-H(7) bond length is 1.10 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one C(1) and one N(2) atom. The N(1)-N(2) bond length is 1.33 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(3), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(4), and one C(8) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(9), and one N(5) atom. The N(4)-N(5) bond length is 1.33 Å. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(11) and one N(4) atom. In the sixth N site, N(6) is bonded to one Cu(1), one C(14), one C(16), and one C(18) atom to form distorted corner-sharing NCuC3 tetrahedra. In the seventh N site, N(7) is bonded to one Cu(1), one C(15), one C(17), and one C(19) atom to form corner-sharing NCuC3 tetrahedra. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(12) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(12) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(12) atom. In the fourth F site, F(4,5) is bonded in a single-bond geometry to one C(13) atom. In the fifth F site, F(6) is bonded in a single-bond geometry to one C(13) atom. Linkers: 4 C1CN2CCN1CC2 ,1 FC(F)(F)C1=NN=C(c2cccc(C3=NN=C(C(F)(F)F)[CH]3)n2)[CH]1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 3.49 A, density 1.48 g/cm3, surface area 4378.79 m2/g, accessible volume 0.17 cm3/g