CdH6(C7N5)2(CH)6 crystallizes in the orthorhombic Fddd space group. The structure consists of ninety-six 02329_fluka molecules inside a CdH6(C7N5)2 framework. In each CdH6(C7N5)2 framework, Cd(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent N(4) atoms. Both Cd(1)-N(1) bond lengths are 2.32 Å. Both Cd(1)-N(4) bond lengths are 2.23 Å. There are seven inequivalent C sites. In the first C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(2) bond length is 1.39 Å. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(2) bond length is 1.09 Å. In the second C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(4)-C(5) bond length is 1.43 Å. The C(4)-C(9) bond length is 1.42 Å. In the third C site, C(9) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(9)-H(6) bond length is 1.09 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one N(1) atom. The C(5)-N(1) bond length is 1.37 Å. In the sixth C site, C(10) is bonded in a distorted water-like geometry to one C(2), one N(2), and one N(3) atom. The C(10)-C(2) bond length is 1.46 Å. The C(10)-N(2) bond length is 1.36 Å. The C(10)-N(3) bond length is 1.35 Å. In the seventh C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(3) atom. There are five inequivalent N sites. In the first N site, N(3) is bonded in a water-like geometry to one C(10) and one N(4) atom. The N(3)-N(4) bond length is 1.33 Å. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one N(3), and one N(5) atom. The N(4)-N(5) bond length is 1.34 Å. In the third N site, N(2) is bonded in a distorted water-like geometry to one C(10) and one N(5) atom. The N(2)-N(5) bond length is 1.33 Å. In the fourth N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the fifth N site, N(5) is bonded in a water-like geometry to one N(2) and one N(4) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(9) atom. Linkers: 8 c1ccc2ncc(C3=NN=N[N]3)cc2c1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 3.97 A, density 1.64 g/cm3, surface area 3992.12 m2/g, accessible volume 0.19 cm3/g