ZnC26H18(N3O4)2C7H6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 2,4-dimethyl-1,4-pentadiene molecules and one ZnC26H18(N3O4)2 cluster. In the ZnC26H18(N3O4)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(4), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 2.00 Å. The Zn(1)-N(4) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(3) bond length is 1.95 Å. There are twenty-six inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the second C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(3) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-N(3) bond length is 1.42 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(8,9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(8,9) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one N(6) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(6) bond length is 1.43 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(8,9) atom. The C(12)-H(8,9) bond length is 1.09 Å. In the seventh C site, C(14) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(11) atom. The C(14)-N(1) bond length is 1.32 Å. The C(14)-N(3) bond length is 1.37 Å. The C(14)-H(11) bond length is 1.09 Å. In the eighth C site, C(15) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(12) atom. The C(15)-N(2) bond length is 1.31 Å. The C(15)-N(3) bond length is 1.38 Å. The C(15)-H(12) bond length is 1.08 Å. In the ninth C site, C(16) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(13) atom. The C(16)-N(4) bond length is 1.32 Å. The C(16)-N(6) bond length is 1.36 Å. The C(16)-H(13) bond length is 1.09 Å. In the tenth C site, C(17) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(14) atom. The C(17)-N(5) bond length is 1.32 Å. The C(17)-N(6) bond length is 1.37 Å. The C(17)-H(14) bond length is 1.09 Å. In the eleventh C site, C(18) is bonded in a trigonal planar geometry to one C(19), one C(20), and one C(21) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(20) bond length is 1.40 Å. The C(18)-C(21) bond length is 1.50 Å. In the twelfth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(15) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-H(15) bond length is 1.09 Å. In the thirteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(18), one C(19), and one H(16) atom. The C(20)-H(16) bond length is 1.09 Å. In the fourteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(1), and one O(2) atom. The C(21)-O(1) bond length is 1.30 Å. The C(21)-O(2) bond length is 1.25 Å. In the fifteenth C site, C(22) is bonded in a trigonal planar geometry to one C(23), one C(24), and one C(25) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(24) bond length is 1.40 Å. The C(22)-C(25) bond length is 1.49 Å. In the sixteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(17) atom. The C(23)-H(17) bond length is 1.09 Å. In the seventeenth C site, C(24) is bonded in a distorted single-bond geometry to one C(22) and one H(18) atom. The C(24)-H(18) bond length is 1.09 Å. In the eighteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(3), and one O(4) atom. The C(25)-O(3) bond length is 1.29 Å. The C(25)-O(4) bond length is 1.26 Å. In the nineteenth C site, C(26) is bonded in a trigonal planar geometry to one C(27), one C(28), and one C(29) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-C(28) bond length is 1.40 Å. The C(26)-C(29) bond length is 1.50 Å. In the twentieth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(20) atom. The C(27)-H(20) bond length is 1.09 Å. In the twenty-first C site, C(28) is bonded in a distorted single-bond geometry to one C(26) and one H(21) atom. The C(28)-H(21) bond length is 1.09 Å. In the twenty-second C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(5), and one O(6) atom. The C(29)-O(5) bond length is 1.24 Å. The C(29)-O(6) bond length is 1.34 Å. In the twenty-third C site, C(30) is bonded in a trigonal planar geometry to one C(31), one C(32), and one C(33) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-C(32) bond length is 1.40 Å. The C(30)-C(33) bond length is 1.49 Å. In the twenty-fourth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(23) atom. The C(31)-H(23) bond length is 1.09 Å. In the twenty-fifth C site, C(32) is bonded in a distorted single-bond geometry to one C(30) and one H(24) atom. The C(32)-H(24) bond length is 1.09 Å. In the twenty-sixth C site, C(33) is bonded in a bent 120 degrees geometry to one C(30), one O(7), and one O(8) atom. The C(33)-O(7) bond length is 1.23 Å. The C(33)-O(8) bond length is 1.34 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Zn(1), one C(14), and one N(2) atom. The N(1)-N(2) bond length is 1.38 Å. In the second N site, N(2) is bonded in a distorted single-bond geometry to one C(15) and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(5) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(16), and one N(5) atom. The N(4)-N(5) bond length is 1.38 Å. In the fifth N site, N(5) is bonded in a distorted single-bond geometry to one C(17), one N(4), and one H(22) atom. The N(5)-H(22) bond length is 1.75 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(11), one C(16), and one C(17) atom. There are seventeen inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(8,9) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the twelfth H site, H(19) is bonded in a linear geometry to one O(4) and one O(6) atom. The H(19)-O(4) bond length is 1.54 Å. The H(19)-O(6) bond length is 1.04 Å. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(27) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(28) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one N(5) and one O(8) atom. The H(22)-O(8) bond length is 1.02 Å. In the sixteenth H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the seventeenth H site, H(24) is bonded in a single-bond geometry to one C(32) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(21) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(21) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one C(25) and one H(19) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(29) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one C(29) and one H(19) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(33) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one C(33) and one H(22) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)cc1 ,2 c1cc(-n2cnnc2)ccc1Cc1ccc(-n2cnnc2)cc1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.58 A, density 1.57 g/cm3, surface area 4780.26 m2/g, accessible volume 0.15 cm3/g