CuC7H6(NO)3CO2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of twelve carbon dioxide molecules and six CuC7H6(NO)3 clusters. In two of the CuC7H6(NO)3 clusters, Cu(3) is bonded in a rectangular see-saw-like geometry to one N(3), one N(6), one O(6), and one O(9) atom. The Cu(3)-N(3) bond length is 1.96 Å. The Cu(3)-N(6) bond length is 1.96 Å. The Cu(3)-O(6) bond length is 2.02 Å. The Cu(3)-O(9) bond length is 1.95 Å. There are seven inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to one N(3); one N(7,9); and one H(1,3) atom. The C(3)-N(3) bond length is 1.34 Å. The C(3)-N(7,9) bond length is 1.35 Å. The C(3)-H(1,3) bond length is 1.08 Å. In the second C site, C(4,5,6) is bonded in a distorted trigonal planar geometry to one C(16); one C(19,21); and one N(1) atom. The C(4,5,6)-C(16) bond length is 1.38 Å. The C(4,5,6)-C(19,21) bond length is 1.49 Å. The C(4,5,6)-N(1) bond length is 1.39 Å. In the third C site, C(8,9) is bonded in a distorted bent 120 degrees geometry to one N(5) and one O(4) atom. The C(8,9)-N(5) bond length is 1.32 Å. The C(8,9)-O(4) bond length is 1.28 Å. In the fourth C site, C(11,12) is bonded in a distorted water-like geometry to one N(5) and one H(4,5) atom. The C(11,12)-N(5) bond length is 1.45 Å. The C(11,12)-H(4,5) bond length is 1.10 Å. In the fifth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(4,5,6); one N(7,9); and one H(10,11,12) atom. The C(18)-C(4,5,6) bond length is 1.38 Å. The C(18)-N(7,9) bond length is 1.38 Å. The C(18)-H(10,11,12) bond length is 1.08 Å. In the sixth C site, C(19,21) is bonded in a distorted water-like geometry to one C(4,5,6); one H(13,14,15); and one H(16,17,18) atom. The C(19,21)-H(13,14,15) bond length is 1.10 Å. The C(19,21)-H(16,17,18) bond length is 1.10 Å. In the seventh C site, C(22,23) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(7) atom. The C(22,23)-O(13) bond length is 1.26 Å. The C(22,23)-O(7) bond length is 1.28 Å. There are three inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Cu(3); one C(3); and one C(4,5,6) atom. The N(3)-C(4,5,6) bond length is 1.39 Å. In the second N site, N(6) is bonded in a trigonal planar geometry to one Cu(3); one C(11,12); and one C(8,9) atom. The N(6)-C(11,12) bond length is 1.45 Å. The N(6)-C(8,9) bond length is 1.32 Å. In the third N site, N(7,9) is bonded in a distorted trigonal planar geometry to one C(1,2); one C(16); and one H(7,8) atom. The N(7,9)-C(1,2) bond length is 1.35 Å. The N(7,9)-C(16) bond length is 1.38 Å. The N(7,9)-H(7,8) bond length is 1.04 Å. There are six inequivalent H sites. In the first H site, H(1,3) is bonded in a single-bond geometry to one C(1,2) atom. The H(1,3)-C(1,2) bond length is 1.08 Å. In the second H site, H(6) is bonded in a single-bond geometry to one C(11,12) atom. The H(6)-C(11,12) bond length is 1.10 Å. In the third H site, H(9) is bonded in a single-bond geometry to one N(7,9) atom. The H(9)-N(7,9) bond length is 1.04 Å. In the fourth H site, H(10,11,12) is bonded in a single-bond geometry to one C(16) atom. The H(10,11,12)-C(16) bond length is 1.08 Å. In the fifth H site, H(13,14,15) is bonded in a single-bond geometry to one C(19,21) atom. In the sixth H site, H(16,17,18) is bonded in a single-bond geometry to one C(19,21) atom. There are three inequivalent O sites. In the first O site, O(6) is bonded in a water-like geometry to one Cu(3) and one C(8,9) atom. The O(6)-C(8,9) bond length is 1.28 Å. In the second O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(22,23) atom. The O(9)-C(22,23) bond length is 1.28 Å. In the third O site, O(14) is bonded in a single-bond geometry to one C(22,23) atom. The O(14)-C(22,23) bond length is 1.26 Å. In four of the CuC7H6(NO)3 clusters, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(4), one O(4), and one O(7) atom. The Cu(1)-N(1) bond length is 1.96 Å. The Cu(1)-N(4) bond length is 1.96 Å. The Cu(1)-O(4) bond length is 2.02 Å. The Cu(1)-O(7) bond length is 1.96 Å. In the second Cu site, Cu(2) is bonded in a rectangular see-saw-like geometry to one N(2), one N(5), one O(5), and one O(8) atom. The Cu(2)-N(2) bond length is 1.96 Å. The Cu(2)-N(5) bond length is 1.96 Å. The Cu(2)-O(5) bond length is 2.02 Å. The Cu(2)-O(8) bond length is 1.95 Å. There are twelve inequivalent C sites. In the first C site, C(24) is bonded in a distorted bent 120 degrees geometry to one O(15) and one O(8) atom. The C(24)-O(15) bond length is 1.26 Å. The C(24)-O(8) bond length is 1.28 Å. In the second C site, C(1,2) is bonded in a trigonal planar geometry to one N(1); one N(7,9); and one H(1,3) atom. The C(1,2)-N(1) bond length is 1.34 Å. In the third C site, C(4,5,6) is bonded in a distorted trigonal planar geometry to one C(16); one C(19,21); and one N(1) atom. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(4) and one O(5) atom. The C(7)-N(4) bond length is 1.32 Å. The C(7)-O(5) bond length is 1.28 Å. In the fifth C site, C(8,9) is bonded in a distorted bent 120 degrees geometry to one N(5) and one O(4) atom. In the sixth C site, C(10) is bonded in a distorted water-like geometry to one N(4) and one H(4,5) atom. The C(10)-N(4) bond length is 1.45 Å. The C(10)-H(4,5) bond length is 1.10 Å. In the seventh C site, C(11,12) is bonded in a distorted water-like geometry to one N(5) and one H(4,5) atom. In the eighth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(4,5,6); one N(7,9); and one H(10,11,12) atom. In the ninth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(4,5,6); one N(8); and one H(10,11,12) atom. The C(17)-C(4,5,6) bond length is 1.38 Å. The C(17)-N(8) bond length is 1.38 Å. The C(17)-H(10,11,12) bond length is 1.08 Å. In the tenth C site, C(19,21) is bonded in a distorted water-like geometry to one C(4,5,6); one H(13,14,15); and one H(16,17,18) atom. In the eleventh C site, C(20) is bonded in a distorted water-like geometry to one C(4,5,6); one H(13,14,15); and one H(16,17,18) atom. The C(20)-C(4,5,6) bond length is 1.49 Å. The C(20)-H(13,14,15) bond length is 1.10 Å. The C(20)-H(16,17,18) bond length is 1.10 Å. In the twelfth C site, C(22,23) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(7) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1); one C(1,2); and one C(4,5,6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2); one C(1,2); and one C(4,5,6) atom. The N(2)-C(1,2) bond length is 1.34 Å. The N(2)-C(4,5,6) bond length is 1.39 Å. In the third N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(7) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one Cu(2); one C(11,12); and one C(8,9) atom. In the fifth N site, N(7,9) is bonded in a distorted trigonal planar geometry to one C(1,2); one C(16); and one H(7,8) atom. In the sixth N site, N(8) is bonded in a distorted trigonal planar geometry to one C(1,2); one C(17); and one H(7,8) atom. The N(8)-C(1,2) bond length is 1.35 Å. The N(8)-H(7,8) bond length is 1.04 Å. There are seven inequivalent H sites. In the first H site, H(1,3) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1,2) atom. The H(2)-C(1,2) bond length is 1.08 Å. In the third H site, H(4,5) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one N(7,9) atom. In the fifth H site, H(10,11,12) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(13,14,15) is bonded in a single-bond geometry to one C(19,21) atom. In the seventh H site, H(16,17,18) is bonded in a single-bond geometry to one C(19,21) atom. There are six inequivalent O sites. In the first O site, O(4) is bonded in a water-like geometry to one Cu(1) and one C(8,9) atom. In the second O site, O(5) is bonded in a water-like geometry to one Cu(2) and one C(7) atom. In the third O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(22,23) atom. In the fourth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(24) atom. In the fifth O site, O(13) is bonded in a single-bond geometry to one C(22,23) atom. In the sixth O site, O(15) is bonded in a single-bond geometry to one C(24) atom. Linkers: 3 [O]C(=O)[C@H](Cc1c[nH]cn1)[N]C(=O)C(=O)[N][C@@H](Cc1c[nH]cn1)C([O])=O. Metal clusters: 6 [Cu]. The MOF has largest included sphere 3.75 A, density 1.76 g/cm3, surface area 3898.55 m2/g, accessible volume 0.15 cm3/g