Hg(CO2)4(HgC10H7(NO)2)2(CH)2(CF3)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, six trifluoromethane molecules, one Hg(CO2)4 cluster, and two HgC10H7(NO)2 clusters. In the Hg(CO2)4 cluster, Hg(1) is bonded in a 4-coordinate geometry to two equivalent O(3) and two equivalent O(6) atoms. Both Hg(1)-O(3) bond lengths are 2.30 Å. Both Hg(1)-O(6) bond lengths are 2.52 Å. There are two inequivalent C sites. In the first C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(13)-O(3) bond length is 1.27 Å. The C(13)-O(4) bond length is 1.25 Å. In the second C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(15)-O(5) bond length is 1.25 Å. The C(15)-O(6) bond length is 1.27 Å. There are four inequivalent O sites. In the first O site, O(6) is bonded in a distorted single-bond geometry to one Hg(1) and one C(15) atom. In the second O site, O(3) is bonded in a distorted water-like geometry to one Hg(1) and one C(13) atom. In the third O site, O(4) is bonded in a single-bond geometry to one C(13) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(15) atom. In each HgC10H7(NO)2 cluster, Hg(2) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one O(1) atom. The Hg(2)-N(1) bond length is 2.25 Å. The Hg(2)-N(2) bond length is 2.36 Å. The Hg(2)-O(1) bond length is 2.16 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.49 Å. The C(1)-N(1) bond length is 1.35 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-N(2) bond length is 1.35 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(5) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(7) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(8) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(11)-O(1) bond length is 1.29 Å. The C(11)-O(2) bond length is 1.24 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Hg(2), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Hg(2), one C(10), and one C(6) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Hg(2) and one C(11) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(11) atom. Linkers: 6 [O]C(=O)C(F)(F)F. Metal clusters: 3 [Hg]. The MOF has largest included sphere 2.18 A, density 2.56 g/cm3, surface area 3158.37 m2/g, accessible volume 0.08 cm3/g