CdC24N4H23O5(CH)2CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 02329_fluka molecules, and one CdC24N4H23O5 cluster. In the CdC24N4H23O5 cluster, Cd(1) is bonded in a distorted octahedral geometry to one N(4), one O(1), one O(2), one O(3), one O(4), and one O(5) atom. The Cd(1)-N(4) bond length is 2.21 Å. The Cd(1)-O(1) bond length is 2.54 Å. The Cd(1)-O(2) bond length is 2.23 Å. The Cd(1)-O(3) bond length is 2.45 Å. The Cd(1)-O(4) bond length is 2.32 Å. The Cd(1)-O(5) bond length is 2.48 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.29 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-H(3) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(1) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-N(1) bond length is 1.39 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one N(1), one H(5), and one H(6) atom. The C(8)-C(9) bond length is 1.51 Å. The C(8)-N(1) bond length is 1.45 Å. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.11 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.40 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(7) atom. The C(10)-H(7) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(8) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(8) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(15) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(15) bond length is 1.50 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(9) atom. The C(13)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(10) atom. The C(14)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one C(12), one N(2), one H(11), and one H(12) atom. The C(15)-N(2) bond length is 1.46 Å. The C(15)-H(11) bond length is 1.10 Å. The C(15)-H(12) bond length is 1.11 Å. In the fifteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one C(21), and one N(2) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(21) bond length is 1.40 Å. The C(16)-N(2) bond length is 1.38 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(13) atom. The C(17)-H(13) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(20) and one H(15) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(15) bond length is 1.09 Å. In the eighteenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(22) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(22) bond length is 1.49 Å. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one H(16) atom. The C(21)-H(16) bond length is 1.09 Å. In the twentieth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(4), and one O(5) atom. The C(22)-O(4) bond length is 1.29 Å. The C(22)-O(5) bond length is 1.27 Å. In the twenty-first C site, C(23) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(17) atom. The C(23)-N(3) bond length is 1.35 Å. The C(23)-N(4) bond length is 1.33 Å. The C(23)-H(17) bond length is 1.08 Å. In the twenty-second C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(25), one N(4), and one H(18) atom. The C(24)-C(25) bond length is 1.37 Å. The C(24)-N(4) bond length is 1.38 Å. The C(24)-H(18) bond length is 1.08 Å. In the twenty-third C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(24), one N(3), and one H(19) atom. The C(25)-N(3) bond length is 1.38 Å. The C(25)-H(19) bond length is 1.08 Å. In the twenty-fourth C site, C(26) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(20), and one H(21) atom. The C(26)-N(3) bond length is 1.46 Å. The C(26)-H(20) bond length is 1.10 Å. The C(26)-H(21) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one C(8), and one H(24) atom. The N(1)-H(24) bond length is 1.02 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(15), one C(16), and one H(25) atom. The N(2)-H(25) bond length is 1.02 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(26) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(23), and one C(24) atom. There are twenty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(26) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the twentieth H site, H(24) is bonded in a single-bond geometry to one N(1) atom. In the twenty-first H site, H(25) is bonded in a single-bond geometry to one N(2) atom. In the twenty-second H site, H(26) is bonded in a single-bond geometry to one O(3) atom. The H(26)-O(3) bond length is 0.99 Å. In the twenty-third H site, H(27) is bonded in a single-bond geometry to one O(3) atom. The H(27)-O(3) bond length is 0.99 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(1), one H(26), and one H(27) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(22) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one C(22) atom. Linkers: 2 [O]/[C]=[C]\[CH]/C(=[NH]/Cc1ccc(cc1)CNc1cccc(c1)C(=O)[O])/[CH] ,2 [O]C(=O)c1cccc(NCc2ccc(CNc3cccc(C([O])=O)c3)cc2)c1 ,1 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 1 O.O.[C]1O[Cd]2(O1)O[C]O[Cd]1(O[C]O1)O[C]O2. The MOF has largest included sphere 2.14 A, density 1.58 g/cm3, surface area 4845.33 m2/g, accessible volume 0.14 cm3/g