AgC23N2H15(CH)3NO3 is Indium-derived structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four nitric acid molecules, four propylene molecules, and four AgC23N2H15 clusters. In each AgC23N2H15 cluster, Ag(1) is bonded in a distorted linear geometry to one N(2) and one N(3) atom. The Ag(1)-N(2) bond length is 2.14 Å. The Ag(1)-N(3) bond length is 2.15 Å. There are twenty-three inequivalent C sites. In the first C site, C(14) is bonded in a distorted trigonal planar geometry to one C(15), one N(3), and one H(10) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-N(3) bond length is 1.35 Å. The C(14)-H(10) bond length is 1.09 Å. In the second C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(11) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(11) bond length is 1.09 Å. In the third C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(25) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(25) bond length is 1.41 Å. In the fourth C site, C(17) is bonded in a linear geometry to one C(16) and one C(18) atom. The C(17)-C(18) bond length is 1.22 Å. In the fifth C site, C(18) is bonded in a linear geometry to one C(17) and one C(19) atom. The C(18)-C(19) bond length is 1.41 Å. In the sixth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-C(24) bond length is 1.41 Å. In the seventh C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one H(12) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(12) bond length is 1.09 Å. In the eighth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one H(13) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-H(13) bond length is 1.09 Å. In the ninth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(14) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(14) bond length is 1.09 Å. In the tenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one H(15) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-H(15) bond length is 1.09 Å. In the eleventh C site, C(24) is bonded in a distorted trigonal planar geometry to one C(19), one C(23), and one H(16) atom. The C(24)-H(16) bond length is 1.09 Å. In the twelfth C site, C(25) is bonded in a distorted single-bond geometry to one C(16), one C(26), and one H(17) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-H(17) bond length is 1.09 Å. In the thirteenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one N(3), and one H(18) atom. The C(26)-N(3) bond length is 1.35 Å. The C(26)-H(18) bond length is 1.09 Å. In the fourteenth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the fifteenth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the sixteenth C site, C(3) is bonded in a trigonal planar geometry to one C(12), one C(2), and one C(4) atom. The C(3)-C(12) bond length is 1.41 Å. The C(3)-C(4) bond length is 1.41 Å. In the seventeenth C site, C(4) is bonded in a linear geometry to one C(3) and one C(5) atom. The C(4)-C(5) bond length is 1.22 Å. In the eighteenth C site, C(5) is bonded in a linear geometry to one C(4) and one C(6) atom. The C(5)-C(6) bond length is 1.42 Å. In the nineteenth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(5), and one C(7) atom. The C(6)-C(11) bond length is 1.41 Å. The C(6)-C(7) bond length is 1.41 Å. In the twentieth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(7)-H(3) bond length is 1.09 Å. In the twenty-first C site, C(11) is bonded in a distorted single-bond geometry to one C(6) and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. In the twenty-second C site, C(12) is bonded in a distorted single-bond geometry to one C(13), one C(3), and one H(8) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(8) bond length is 1.09 Å. In the twenty-third C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(9) atom. The C(13)-N(2) bond length is 1.35 Å. The C(13)-H(9) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(13) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(14), and one C(26) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. Linkers: 4 [O][N+](=O)[O-]. Metal clusters: 4 [Ag]. The MOF has largest included sphere 2.95 A, density 1.52 g/cm3, surface area 4959.44 m2/g, accessible volume 0.16 cm3/g