AgC22P2H24(NO2)2(CH)7 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of fourteen 02329_fluka molecules and two AgC22P2H24(NO2)2 clusters. In each AgC22P2H24(NO2)2 cluster, Ag(1) is bonded in a distorted trigonal pyramidal geometry to one P(1), one P(2), one O(1), and one O(4) atom. The Ag(1)-P(1) bond length is 2.40 Å. The Ag(1)-P(2) bond length is 2.39 Å. The Ag(1)-O(1) bond length is 2.49 Å. The Ag(1)-O(4) bond length is 2.57 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one P(1), one H(1), and one H(2) atom. The C(1)-P(1) bond length is 1.83 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one P(2), one H(3), and one H(4) atom. The C(2)-P(2) bond length is 1.83 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(2), one H(5), and one O(4) atom. The C(3)-N(2) bond length is 1.35 Å. The C(3)-H(5) bond length is 1.11 Å. The C(3)-O(4) bond length is 1.25 Å. In the fourth C site, C(4) is bonded to one N(2), one H(6), one H(7), and one H(8) atom to form corner-sharing CH3N tetrahedra. The C(4)-N(2) bond length is 1.45 Å. The C(4)-H(6) bond length is 1.10 Å. The C(4)-H(7) bond length is 1.10 Å. The C(4)-H(8) bond length is 1.09 Å. In the fifth C site, C(5) is bonded to one N(2), one H(10), one H(11), and one H(9) atom to form corner-sharing CH3N tetrahedra. The C(5)-N(2) bond length is 1.45 Å. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(11) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(7), and one P(1) atom. The C(6)-C(11) bond length is 1.40 Å. The C(6)-C(7) bond length is 1.40 Å. The C(6)-P(1) bond length is 1.83 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(12) atom. The C(7)-H(12) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(6) and one H(16) atom. The C(11)-H(16) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a trigonal planar geometry to one C(13), one C(17), and one P(1) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-C(17) bond length is 1.40 Å. The C(12)-P(1) bond length is 1.82 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(17) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(17) bond length is 1.09 Å. In the eleventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(18) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(18) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(19) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(19) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(20) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(20) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one H(21) atom. The C(17)-H(21) bond length is 1.09 Å. In the fifteenth C site, C(18) is bonded in a trigonal planar geometry to one C(19), one C(23), and one P(2) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(23) bond length is 1.40 Å. The C(18)-P(2) bond length is 1.82 Å. In the sixteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(22) atom. The C(19)-H(22) bond length is 1.09 Å. In the seventeenth C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(26) atom. The C(23)-H(26) bond length is 1.09 Å. In the eighteenth C site, C(24) is bonded in a trigonal planar geometry to one C(25), one C(29), and one P(2) atom. The C(24)-C(25) bond length is 1.41 Å. The C(24)-C(29) bond length is 1.40 Å. The C(24)-P(2) bond length is 1.82 Å. In the nineteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one C(26), and one H(27) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-H(27) bond length is 1.09 Å. In the twentieth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one C(27), and one H(28) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-H(28) bond length is 1.09 Å. In the twenty-first C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(29) atom. The C(27)-H(29) bond length is 1.09 Å. In the twenty-second C site, C(29) is bonded in a distorted single-bond geometry to one C(24) and one H(31) atom. The C(29)-H(31) bond length is 1.09 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one Ag(1), one C(1), one C(12), and one C(6) atom to form distorted corner-sharing PAgC3 tetrahedra. In the second P site, P(2) is bonded to one Ag(1), one C(18), one C(2), and one C(24) atom to form distorted corner-sharing PAgC3 tetrahedra. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(5) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(1)-O(1) bond length is 1.29 Å. The N(1)-O(2) bond length is 1.27 Å. The N(1)-O(3) bond length is 1.26 Å. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(5) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(7) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(11) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(14) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(15) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(16) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(17) atom. In the nineteenth H site, H(22) is bonded in a single-bond geometry to one C(19) atom. In the twentieth H site, H(26) is bonded in a single-bond geometry to one C(23) atom. In the twenty-first H site, H(27) is bonded in a single-bond geometry to one C(25) atom. In the twenty-second H site, H(28) is bonded in a single-bond geometry to one C(26) atom. In the twenty-third H site, H(29) is bonded in a single-bond geometry to one C(27) atom. In the twenty-fourth H site, H(31) is bonded in a single-bond geometry to one C(29) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Ag(1) and one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(1) and one C(3) atom. Linkers: 2 [c]1cccc(P(CCP(c2ccccc2)c2ccccc2)c2ccccc2)c1 ,2 [C]/C=C(\[CH])P(CCP(c1ccccc1)c1ccccc1)c1ccccc1 ,1 c1ccc(P(CCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1. Metal clusters: . The MOF has largest included sphere 2.10 A, density 1.52 g/cm3, surface area 4999.99 m2/g, accessible volume 0.13 cm3/g