CuC8NH5O5(CH)3(CH3)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules, sixteen 02329_fluka molecules, and four CuC8NH5O5 clusters. In each CuC8NH5O5 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1,3) is bonded in a distorted square pyramidal geometry to one N(5), one O(13), one O(21), one O(29), and one O(37) atom. The Cu(1,3)-N(5) bond length is 2.24 Å. The Cu(1,3)-O(13) bond length is 2.01 Å. The Cu(1,3)-O(21) bond length is 2.00 Å. The Cu(1,3)-O(29) bond length is 2.00 Å. The Cu(1,3)-O(37) bond length is 2.01 Å. In the second Cu site, Cu(5,8) is bonded in a distorted square pyramidal geometry to one N(4), one O(17), one O(25), one O(33), and one O(9) atom. The Cu(5,8)-N(4) bond length is 2.22 Å. The Cu(5,8)-O(17) bond length is 2.00 Å. The Cu(5,8)-O(25) bond length is 2.00 Å. The Cu(5,8)-O(33) bond length is 2.00 Å. The Cu(5,8)-O(9) bond length is 2.02 Å. There are sixteen inequivalent C sites. In the first C site, C(13,16) is bonded in a distorted single-bond geometry to one C(17,20) and one H(13,14,15,16) atom. The C(13,16)-C(17,20) bond length is 1.39 Å. The C(13,16)-H(13,14,15,16) bond length is 1.09 Å. In the second C site, C(17,20) is bonded in a distorted trigonal planar geometry to one C(13,16); one C(21); and one N(1) atom. The C(17,20)-C(21) bond length is 1.51 Å. The C(17,20)-N(1) bond length is 1.35 Å. In the third C site, C(24) is bonded in a distorted trigonal non-coplanar geometry to one C(17,20); one H(17,18,19,20); one H(21,22,23,24); and one O(1,2,3,4) atom. The C(24)-C(17,20) bond length is 1.51 Å. The C(24)-H(17,18,19,20) bond length is 1.10 Å. The C(24)-H(21,22,23,24) bond length is 1.10 Å. The C(24)-O(1,2,3,4) bond length is 1.43 Å. In the fourth C site, C(26,28) is bonded in a distorted single-bond geometry to one O(1,2,3,4) atom. The C(26,28)-O(1,2,3,4) bond length is 1.37 Å. In the fifth C site, C(41,42,43,44) is bonded in a distorted single-bond geometry to one O(5,6,7,8) atom. The C(41,42,43,44)-O(5,6,7,8) bond length is 1.37 Å. In the sixth C site, C(49) is bonded in a distorted trigonal non-coplanar geometry to one C(53,55); one H(41,42,43,44); one H(45,46,47,48); and one O(5,6,7,8) atom. The C(49)-C(53,55) bond length is 1.51 Å. The C(49)-H(41,42,43,44) bond length is 1.10 Å. The C(49)-H(45,46,47,48) bond length is 1.10 Å. The C(49)-O(5,6,7,8) bond length is 1.43 Å. In the seventh C site, C(53,55) is bonded in a distorted trigonal planar geometry to one C(49), one C(57), and one N(5) atom. The C(53,55)-C(57) bond length is 1.40 Å. The C(53,55)-N(5) bond length is 1.35 Å. In the eighth C site, C(57) is bonded in a distorted single-bond geometry to one C(53,55); one C(61,62,63,64); and one H(49,50,51,52) atom. The C(57)-C(61,62,63,64) bond length is 1.39 Å. The C(57)-H(49,50,51,52) bond length is 1.09 Å. In the ninth C site, C(61,62,63,64) is bonded in a distorted trigonal planar geometry to one C(57); one C(65,66,67,68); and one H(53,54,55,56) atom. The C(61,62,63,64)-C(65,66,67,68) bond length is 1.40 Å. The C(61,62,63,64)-H(53,54,55,56) bond length is 1.09 Å. In the tenth C site, C(65,66,67,68) is bonded in a distorted single-bond geometry to one C(61,62,63,64) and one H(57,58,59,60) atom. The C(65,66,67,68)-H(57,58,59,60) bond length is 1.09 Å. In the eleventh C site, C(69,71) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(61) atom. The C(69,71)-N(5) bond length is 1.34 Å. The C(69,71)-H(61) bond length is 1.09 Å. In the twelfth C site, C(73) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(9) atom. The C(73)-O(13) bond length is 1.27 Å. The C(73)-O(9) bond length is 1.28 Å. In the thirteenth C site, C(81) is bonded in a distorted bent 120 degrees geometry to one O(17) and one O(21) atom. The C(81)-O(17) bond length is 1.27 Å. The C(81)-O(21) bond length is 1.28 Å. In the fourteenth C site, C(89) is bonded in a distorted bent 120 degrees geometry to one O(25) and one O(29) atom. The C(89)-O(25) bond length is 1.27 Å. The C(89)-O(29) bond length is 1.27 Å. In the fifteenth C site, C(97) is bonded in a distorted bent 120 degrees geometry to one O(33) and one O(37) atom. The C(97)-O(33) bond length is 1.28 Å. The C(97)-O(37) bond length is 1.27 Å. In the sixteenth C site, C(1,4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,4) atom. The C(1,4)-N(1) bond length is 1.34 Å. The C(1,4)-H(1,4) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Cu(5,8); one C(1,4); and one C(17,20) atom. The N(4)-C(1,4) bond length is 1.34 Å. The N(4)-C(17,20) bond length is 1.35 Å. In the second N site, N(5) is bonded in a distorted trigonal planar geometry to one Cu(1,3); one C(53,55); and one C(69,71) atom. There are ten inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(1,4) atom. In the second H site, H(13,14,15,16) is bonded in a single-bond geometry to one C(13,16) atom. In the third H site, H(17,18,19,20) is bonded in a single-bond geometry to one C(21) atom. The H(17,18,19,20)-C(21) bond length is 1.10 Å. In the fourth H site, H(21,22,23,24) is bonded in a single-bond geometry to one C(21) atom. The H(21,22,23,24)-C(21) bond length is 1.10 Å. In the fifth H site, H(41,42,43,44) is bonded in a single-bond geometry to one C(49) atom. In the sixth H site, H(45,46,47,48) is bonded in a single-bond geometry to one C(49) atom. In the seventh H site, H(49,50,51,52) is bonded in a single-bond geometry to one C(57) atom. In the eighth H site, H(53,54,55,56) is bonded in a single-bond geometry to one C(61,62,63,64) atom. In the ninth H site, H(57,58,59,60) is bonded in a single-bond geometry to one C(65,66,67,68) atom. In the tenth H site, H(61) is bonded in a single-bond geometry to one C(69,71) atom. There are ten inequivalent O sites. In the first O site, O(25) is bonded in a bent 120 degrees geometry to one Cu(5,8) and one C(89) atom. In the second O site, O(29) is bonded in a bent 120 degrees geometry to one Cu(1,3) and one C(89) atom. In the third O site, O(33) is bonded in a bent 120 degrees geometry to one Cu(5,8) and one C(97) atom. In the fourth O site, O(37) is bonded in a bent 120 degrees geometry to one Cu(1,3) and one C(97) atom. In the fifth O site, O(1,2,3,4) is bonded in a bent 120 degrees geometry to one C(21) and one C(25,27) atom. The O(1,2,3,4)-C(21) bond length is 1.43 Å. The O(1,2,3,4)-C(25,27) bond length is 1.37 Å. In the sixth O site, O(5,6,7,8) is bonded in a bent 120 degrees geometry to one C(41,42,43,44) and one C(49) atom. In the seventh O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(5,8) and one C(73) atom. In the eighth O site, O(13) is bonded in a bent 120 degrees geometry to one Cu(1,3) and one C(73) atom. In the ninth O site, O(17) is bonded in a bent 120 degrees geometry to one Cu(5,8) and one C(81) atom. In the tenth O site, O(21) is bonded in a bent 120 degrees geometry to one Cu(1,3) and one C(81) atom. Linkers: 4 c1ccc(COc2cccc(OCc3ccccn3)c2)nc1. Metal clusters: 8 [Cu]. The MOF has largest included sphere 2.89 A, density 1.56 g/cm3, surface area 4713.42 m2/g, accessible volume 0.17 cm3/g