Zn5C54H32(N2O9)2(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one Zn5C54H32(N2O9)2 cluster. In the Zn5C54H32(N2O9)2 cluster, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(5), and one O(9) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(2)O6 octahedra and  a cornercorner with one Zn(3)N2O3 square pyramid. The corner-sharing octahedral tilt angles are 67°. The Zn(1)-O(2) bond length is 1.97 Å. The Zn(1)-O(3) bond length is 1.95 Å. The Zn(1)-O(5) bond length is 1.97 Å. The Zn(1)-O(9) bond length is 1.99 Å. In the second Zn site, Zn(2) is bonded to two equivalent O(4), two equivalent O(8), and two equivalent O(9) atoms to form ZnO6 octahedra that share corners with two equivalent Zn(3)N2O3 square pyramids and corners with two equivalent Zn(1)O4 tetrahedra. Both Zn(2)-O(4) bond lengths are 2.32 Å. Both Zn(2)-O(8) bond lengths are 2.07 Å. Both Zn(2)-O(9) bond lengths are 2.06 Å. In the third Zn site, Zn(3) is bonded to one N(1), one N(2), one O(1), one O(7), and one O(9) atom to form ZnN2O3 square pyramids that share  a cornercorner with one Zn(2)O6 octahedra and  a cornercorner with one Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 67°. The Zn(3)-N(1) bond length is 2.10 Å. The Zn(3)-N(2) bond length is 2.15 Å. The Zn(3)-O(1) bond length is 2.07 Å. The Zn(3)-O(7) bond length is 2.10 Å. The Zn(3)-O(9) bond length is 2.02 Å. There are twenty-seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(12) bond length is 1.42 Å. The C(4)-C(5) bond length is 1.43 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-C(7) bond length is 1.43 Å. The C(6)-H(5) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.42 Å. The C(7)-C(8) bond length is 1.41 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(7) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.33 Å. The C(10)-H(8) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(7), and one N(2) atom. The C(11)-C(12) bond length is 1.44 Å. The C(11)-N(2) bond length is 1.36 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(4), and one N(1) atom. The C(12)-N(1) bond length is 1.36 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(15) and one H(9) atom. The C(13)-C(15) bond length is 1.40 Å. The C(13)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(10) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(16) atom. The C(15)-C(16) bond length is 1.50 Å. In the fifteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(1), and one O(2) atom. The C(16)-O(1) bond length is 1.27 Å. The C(16)-O(2) bond length is 1.28 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(11) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(11) bond length is 1.09 Å. In the seventeenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(20) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(20) bond length is 1.49 Å. In the eighteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(12) atom. The C(19)-H(12) bond length is 1.09 Å. In the nineteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(3), and one O(4) atom. The C(20)-O(3) bond length is 1.29 Å. The C(20)-O(4) bond length is 1.27 Å. In the twentieth C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(13,14) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-H(13,14) bond length is 1.09 Å. In the twenty-first C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(24) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(24) bond length is 1.50 Å. In the twenty-second C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(13,14) atom. The C(23)-H(13,14) bond length is 1.09 Å. In the twenty-third C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(5), and one O(6) atom. The C(24)-O(5) bond length is 1.29 Å. The C(24)-O(6) bond length is 1.26 Å. In the twenty-fourth C site, C(25) is bonded in a distorted single-bond geometry to one C(26) and one H(15) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-H(15) bond length is 1.09 Å. In the twenty-fifth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(28) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-C(28) bond length is 1.51 Å. In the twenty-sixth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(16) atom. The C(27)-H(16) bond length is 1.09 Å. In the twenty-seventh C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(7), and one O(8) atom. The C(28)-O(7) bond length is 1.28 Å. The C(28)-O(8) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(3), one C(1), and one C(12) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(3), one C(10), and one C(11) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(13,14) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one O(9) atom. The H(17)-O(9) bond length is 1.00 Å. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(16) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(16) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(20) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(20) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(24) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one C(24) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(28) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(28) atom. In the ninth O site, O(9) is bonded to one Zn(1), one Zn(2), one Zn(3), and one H(17) atom to form distorted corner-sharing OZn3H tetrahedra. Linkers: 4 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 1 O=[C]O[Zn@@]1(O)O[C]O[Zn]O[C]O[Zn@@]2(O[C]O[Zn]O[C]O[Zn@@](O)(O[C]=O)O[C]O2)O[C]O1. RCSR code: ilc. The MOF has largest included sphere 2.93 A, density 1.77 g/cm3, surface area 3727.26 m2/g, accessible volume 0.14 cm3/g