YbC6NH7O7(CH2)3(CH)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, twelve 02329_fluka molecules, and two YbC6NH7O7 clusters. In each YbC6NH7O7 cluster, Yb(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(6), one O(7), and two equivalent O(2) atoms. The Yb(1)-O(1) bond length is 2.36 Å. The Yb(1)-O(3) bond length is 2.24 Å. The Yb(1)-O(4) bond length is 2.28 Å. The Yb(1)-O(5) bond length is 2.35 Å. The Yb(1)-O(6) bond length is 2.30 Å. The Yb(1)-O(7) bond length is 2.30 Å. There is one shorter (2.28 Å) and one longer (2.43 Å) Yb(1)-O(2) bond length. There are six inequivalent C sites. In the first C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(7)-O(1) bond length is 1.27 Å. The C(7)-O(2) bond length is 1.29 Å. In the second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.27 Å. In the third C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(9)-O(5) bond length is 1.28 Å. The C(9)-O(6) bond length is 1.28 Å. In the fourth C site, C(10) is bonded in a trigonal planar geometry to one N(1), one H(10), and one O(7) atom. The C(10)-N(1) bond length is 1.33 Å. The C(10)-H(10) bond length is 1.10 Å. The C(10)-O(7) bond length is 1.26 Å. In the fifth C site, C(11) is bonded to one N(1), one H(11), one H(12), and one H(13) atom to form corner-sharing CH3N tetrahedra. The C(11)-N(1) bond length is 1.46 Å. The C(11)-H(11) bond length is 1.10 Å. The C(11)-H(12) bond length is 1.10 Å. The C(11)-H(13) bond length is 1.10 Å. In the sixth C site, C(12) is bonded to one N(1), one H(14), one H(15), and one H(16) atom to form corner-sharing CH3N tetrahedra. The C(12)-N(1) bond length is 1.46 Å. The C(12)-H(14) bond length is 1.10 Å. The C(12)-H(15) bond length is 1.10 Å. The C(12)-H(16) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(12) atom. There are seven inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(12) atom. There are seven inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Yb(1) and one C(8) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Yb(1) and one C(8) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to one Yb(1) and one C(9) atom. In the fourth O site, O(6) is bonded in a distorted L-shaped geometry to one Yb(1) and one C(9) atom. In the fifth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Yb(1) and one C(10) atom. In the sixth O site, O(1) is bonded in a distorted L-shaped geometry to one Yb(1) and one C(7) atom. In the seventh O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Yb(1) and one C(7) atom. Linkers: 4 [O]C(=O)[C@H]1C[C@@H](C([O])=O)C[C@@H](C([O])=O)C1. Metal clusters: 4 [Yb]. The MOF has largest included sphere 4.61 A, density 1.77 g/cm3, surface area 3327.29 m2/g, accessible volume 0.17 cm3/g