CdC14H16(N5O3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CdC14H16(N5O3)2 clusters. Cd(1) is bonded in an octahedral geometry to two equivalent N(2), two equivalent O(1), and two equivalent O(2) atoms. Both Cd(1)-N(2) bond lengths are 2.36 Å. Both Cd(1)-O(1) bond lengths are 2.37 Å. Both Cd(1)-O(2) bond lengths are 2.31 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(1)-O(2) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(5), and one H(6) atom. The C(2)-N(1) bond length is 1.45 Å. The C(2)-H(5) bond length is 1.10 Å. The C(2)-H(6) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(7) atom. The C(3)-N(1) bond length is 1.38 Å. The C(3)-N(2) bond length is 1.32 Å. The C(3)-H(7) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one N(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-C(7) bond length is 1.41 Å. The C(4)-N(2) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(3), and one H(8) atom. The C(5)-N(3) bond length is 1.34 Å. The C(5)-H(8) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(3), one N(4), and one N(5) atom. The C(6)-N(3) bond length is 1.37 Å. The C(6)-N(4) bond length is 1.35 Å. The C(6)-N(5) bond length is 1.35 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one N(4) atom. The C(7)-N(1) bond length is 1.38 Å. The C(7)-N(4) bond length is 1.33 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(7) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(5) and one C(6) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(6) and one C(7) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(6), one H(3), and one H(4) atom. The N(5)-H(3) bond length is 1.01 Å. The N(5)-H(4) bond length is 1.03 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 1.00 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one N(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. Linkers: 1 Nc1ncc2ncn(CC([O])=O)c2n1 ,3 NC1=N[CH]c2ncn(CC([O])=O)c2[N]1. Metal clusters: 2 O.O.O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 3.02 A, density 1.67 g/cm3, surface area 3978.21 m2/g, accessible volume 0.19 cm3/g