Y3C8H11S2O13(CH)2 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a Y3C8H11S2O13 framework. In the Y3C8H11S2O13 framework, there are three inequivalent Y sites. In the first Y site, Y(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(13), one O(7), one O(9), and two equivalent O(11) atoms. The Y(1)-O(1) bond length is 2.38 Å. The Y(1)-O(10) bond length is 2.39 Å. The Y(1)-O(12) bond length is 2.38 Å. The Y(1)-O(13) bond length is 2.34 Å. The Y(1)-O(7) bond length is 2.40 Å. The Y(1)-O(9) bond length is 2.42 Å. There is one shorter (2.34 Å) and one longer (2.36 Å) Y(1)-O(11) bond length. In the second Y site, Y(2) is bonded in a 8-coordinate geometry to one O(12), one O(13), one O(4), one O(9), two equivalent O(7), and two equivalent O(8) atoms. The Y(2)-O(12) bond length is 2.38 Å. The Y(2)-O(13) bond length is 2.39 Å. The Y(2)-O(4) bond length is 2.47 Å. The Y(2)-O(9) bond length is 2.31 Å. There is one shorter (2.32 Å) and one longer (2.33 Å) Y(2)-O(7) bond length. There is one shorter (2.30 Å) and one longer (2.37 Å) Y(2)-O(8) bond length. In the third Y site, Y(3) is bonded in a 8-coordinate geometry to one O(11), one O(12), one O(13), one O(2), one O(8), one O(9), and two equivalent O(10) atoms. The Y(3)-O(11) bond length is 2.39 Å. The Y(3)-O(12) bond length is 2.37 Å. The Y(3)-O(13) bond length is 2.32 Å. The Y(3)-O(2) bond length is 2.38 Å. The Y(3)-O(8) bond length is 2.48 Å. The Y(3)-O(9) bond length is 2.36 Å. There is one shorter (2.37 Å) and one longer (2.42 Å) Y(3)-O(10) bond length. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(5), and one S(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-C(5) bond length is 1.43 Å. The C(1)-S(1) bond length is 1.77 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(8) atom. The C(2)-H(8) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(10) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-H(10) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(5) atom. The C(5)-C(5) bond length is 1.44 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(10), one C(7), and one S(2) atom. The C(6)-C(10) bond length is 1.43 Å. The C(6)-C(7) bond length is 1.38 Å. The C(6)-S(2) bond length is 1.79 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(11) atom. The C(7)-H(11) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(13) atom. The C(9)-C(10) bond length is 1.42 Å. The C(9)-H(13) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(10), one C(6), and one C(9) atom. The C(10)-C(10) bond length is 1.45 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. The H(1)-O(7) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(8) atom. The H(2)-O(8) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(9) atom. The H(3)-O(9) bond length is 0.98 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(10) atom. The H(4)-O(10) bond length is 0.98 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(11) atom. The H(5)-O(11) bond length is 0.99 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(12) atom. The H(6)-O(12) bond length is 0.98 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(13) atom. The H(7)-O(13) bond length is 0.97 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(2) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(9) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.47 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one O(4), one O(5), and one O(6) atom. The S(2)-O(4) bond length is 1.49 Å. The S(2)-O(5) bond length is 1.47 Å. The S(2)-O(6) bond length is 1.47 Å. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Y(3) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Y(2) and one S(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Y(1), two equivalent Y(2), and one H(1) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Y(3), two equivalent Y(2), and one H(2) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Y(1), one Y(2), one Y(3), and one H(3) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one Y(1), two equivalent Y(3), and one H(4) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Y(3), two equivalent Y(1), and one H(5) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Y(1), one Y(2), one Y(3), and one H(6) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one Y(1), one Y(2), one Y(3), and one H(7) atom. Linkers: 2 [O]S([O])([O])c1cccc2c(S([O])([O])[O])cccc12. Metal clusters: 6 [Y]. The MOF has largest included sphere 2.26 A, density 2.49 g/cm3, surface area 2126.20 m2/g, accessible volume 0.07 cm3/g