CoC36H24(NO2)2 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of eight CoC36H24(NO2)2 clusters. Co(1) is bonded in a 6-coordinate geometry to one N(3), one N(4), one O(1), one O(2), one O(5), and one O(6) atom. The Co(1)-N(3) bond length is 2.02 Å. The Co(1)-N(4) bond length is 2.02 Å. The Co(1)-O(1) bond length is 2.04 Å. The Co(1)-O(2) bond length is 2.04 Å. The Co(1)-O(5) bond length is 2.33 Å. The Co(1)-O(6) bond length is 2.32 Å. There are thirty-two inequivalent C sites. In the first C site, C(29) is bonded in a trigonal planar geometry to one C(17), one C(33), and one C(49) atom. The C(29)-C(17) bond length is 1.47 Å. The C(29)-C(33) bond length is 1.41 Å. The C(29)-C(49) bond length is 1.41 Å. In the second C site, C(30) is bonded in a trigonal planar geometry to one C(18), one C(34), and one C(50) atom. The C(30)-C(18) bond length is 1.47 Å. The C(30)-C(34) bond length is 1.41 Å. The C(30)-C(50) bond length is 1.41 Å. In the third C site, C(33) is bonded in a distorted single-bond geometry to one C(29) and one H(17,18) atom. The C(33)-H(17,18) bond length is 1.09 Å. In the fourth C site, C(34) is bonded in a distorted single-bond geometry to one C(30) and one H(17,18) atom. The C(34)-H(17,18) bond length is 1.09 Å. In the fifth C site, C(38,39) is bonded in a single-bond geometry to one C(42,44) and one H(21,22) atom. The C(38,39)-C(42,44) bond length is 1.41 Å. The C(38,39)-H(21,22) bond length is 1.09 Å. In the sixth C site, C(40) is bonded in a single-bond geometry to one C(42,44) and one H(23,24) atom. The C(40)-C(42,44) bond length is 1.41 Å. The C(40)-H(23,24) bond length is 1.09 Å. In the seventh C site, C(42,44) is bonded in a trigonal planar geometry to one C(38,39); one C(46,47); and one C(54,55) atom. The C(42,44)-C(46,47) bond length is 1.40 Å. The C(42,44)-C(54,55) bond length is 1.47 Å. In the eighth C site, C(43) is bonded in a trigonal planar geometry to one C(38,39); one C(46,47); and one C(54,55) atom. The C(43)-C(38,39) bond length is 1.41 Å. The C(43)-C(46,47) bond length is 1.41 Å. The C(43)-C(54,55) bond length is 1.47 Å. In the ninth C site, C(46,47) is bonded in a distorted single-bond geometry to one C(42,44) and one H(25,26) atom. The C(46,47)-H(25,26) bond length is 1.09 Å. In the tenth C site, C(48) is bonded in a distorted single-bond geometry to one C(42,44) and one H(27,28) atom. The C(48)-C(42,44) bond length is 1.40 Å. The C(48)-H(27,28) bond length is 1.09 Å. In the eleventh C site, C(49) is bonded in a distorted single-bond geometry to one C(29) and one H(29,30) atom. The C(49)-H(29,30) bond length is 1.09 Å. In the twelfth C site, C(50) is bonded in a distorted single-bond geometry to one C(30) and one H(29,30) atom. The C(50)-H(29,30) bond length is 1.09 Å. In the thirteenth C site, C(54,55) is bonded in a trigonal planar geometry to one C(42,44); one C(58,60); and one C(70) atom. The C(54,55)-C(58,60) bond length is 1.40 Å. The C(54,55)-C(70) bond length is 1.41 Å. In the fourteenth C site, C(56) is bonded in a trigonal planar geometry to one C(42,44); one C(58,60); and one C(72) atom. The C(56)-C(42,44) bond length is 1.47 Å. The C(56)-C(58,60) bond length is 1.40 Å. The C(56)-C(72) bond length is 1.41 Å. In the fifteenth C site, C(58,60) is bonded in a distorted single-bond geometry to one C(54,55) and one H(33,34,35) atom. The C(58,60)-H(33,34,35) bond length is 1.09 Å. In the sixteenth C site, C(59) is bonded in a distorted single-bond geometry to one C(54,55) and one H(33,34,35) atom. The C(59)-C(54,55) bond length is 1.40 Å. The C(59)-H(33,34,35) bond length is 1.09 Å. In the seventeenth C site, C(63,64) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(37,39,40) atom. The C(63,64)-N(3) bond length is 1.35 Å. The C(63,64)-H(37,39,40) bond length is 1.09 Å. In the eighteenth C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(5) atom. The C(1,2)-C(5) bond length is 1.49 Å. The C(1,2)-O(1) bond length is 1.29 Å. The C(1,2)-O(5) bond length is 1.27 Å. In the nineteenth C site, C(67) is bonded in a distorted trigonal planar geometry to one C(71); one N(3); and one H(41,43) atom. The C(67)-C(71) bond length is 1.39 Å. The C(67)-N(3) bond length is 1.35 Å. The C(67)-H(41,43) bond length is 1.09 Å. In the twentieth C site, C(68) is bonded in a distorted trigonal planar geometry to one C(72), one N(4), and one H(44) atom. The C(68)-C(72) bond length is 1.39 Å. The C(68)-N(4) bond length is 1.35 Å. The C(68)-H(44) bond length is 1.09 Å. In the twenty-first C site, C(5) is bonded in a trigonal planar geometry to one C(1,2); one C(25,26); and one C(9,10) atom. The C(5)-C(25,26) bond length is 1.40 Å. The C(5)-C(9,10) bond length is 1.40 Å. In the twenty-second C site, C(6) is bonded in a trigonal planar geometry to one C(1,2); one C(25,26); and one C(9,10) atom. The C(6)-C(1,2) bond length is 1.49 Å. The C(6)-C(25,26) bond length is 1.40 Å. The C(6)-C(9,10) bond length is 1.40 Å. In the twenty-third C site, C(71) is bonded in a distorted single-bond geometry to one C(54,55); one C(67); and one H(46,47,48) atom. The C(71)-C(54,55) bond length is 1.41 Å. The C(71)-H(46,47,48) bond length is 1.09 Å. In the twenty-fourth C site, C(72) is bonded in a distorted single-bond geometry to one C(56); one C(68); and one H(46,47,48) atom. The C(72)-H(46,47,48) bond length is 1.09 Å. In the twenty-fifth C site, C(9,10) is bonded in a distorted single-bond geometry to one C(5) and one H(1,3) atom. The C(9,10)-H(1,3) bond length is 1.09 Å. In the twenty-sixth C site, C(13) is bonded in a distorted single-bond geometry to one C(17) and one H(5,6,8) atom. The C(13)-C(17) bond length is 1.41 Å. The C(13)-H(5,6,8) bond length is 1.09 Å. In the twenty-seventh C site, C(14) is bonded in a distorted single-bond geometry to one C(18) and one H(5,6,8) atom. The C(14)-C(18) bond length is 1.41 Å. The C(14)-H(5,6,8) bond length is 1.09 Å. In the twenty-eighth C site, C(25,26) is bonded in a distorted trigonal planar geometry to one C(21); one C(5); and one H(13,15) atom. The C(25,26)-C(21) bond length is 1.39 Å. The C(25,26)-H(13,15) bond length is 1.09 Å. In the twenty-ninth C site, C(17) is bonded in a trigonal planar geometry to one C(13), one C(21), and one C(29) atom. The C(17)-C(21) bond length is 1.41 Å. In the thirtieth C site, C(18) is bonded in a trigonal planar geometry to one C(14), one C(22), and one C(30) atom. The C(18)-C(22) bond length is 1.41 Å. In the thirty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(17); one C(25,26); and one H(9,10,12) atom. The C(21)-H(9,10,12) bond length is 1.09 Å. In the thirty-second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(18); one C(25,26); and one H(9,10,12) atom. The C(22)-C(25,26) bond length is 1.39 Å. The C(22)-H(9,10,12) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Co(1); one C(63,64); and one C(67) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Co(1); one C(63,64); and one C(68) atom. The N(4)-C(63,64) bond length is 1.35 Å. There are sixteen inequivalent H sites. In the first H site, H(1,3) is bonded in a single-bond geometry to one C(9,10) atom. In the second H site, H(2,4) is bonded in a single-bond geometry to one C(9,10) atom. The H(2,4)-C(9,10) bond length is 1.09 Å. In the third H site, H(5,6,8) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(9,10,12) is bonded in a single-bond geometry to one C(21) atom. In the fifth H site, H(13,15) is bonded in a single-bond geometry to one C(25,26) atom. In the sixth H site, H(14,16) is bonded in a single-bond geometry to one C(25,26) atom. The H(14,16)-C(25,26) bond length is 1.09 Å. In the seventh H site, H(17,18) is bonded in a single-bond geometry to one C(33) atom. In the eighth H site, H(23,24) is bonded in a single-bond geometry to one C(38,39) atom. The H(23,24)-C(38,39) bond length is 1.09 Å. In the ninth H site, H(27,28) is bonded in a single-bond geometry to one C(46,47) atom. The H(27,28)-C(46,47) bond length is 1.09 Å. In the tenth H site, H(29,30) is bonded in a single-bond geometry to one C(49) atom. In the eleventh H site, H(33,34,35) is bonded in a single-bond geometry to one C(57) atom. The H(33,34,35)-C(57) bond length is 1.09 Å. In the twelfth H site, H(36) is bonded in a single-bond geometry to one C(58,60) atom. The H(36)-C(58,60) bond length is 1.09 Å. In the thirteenth H site, H(37,39,40) is bonded in a single-bond geometry to one C(61) atom. The H(37,39,40)-C(61) bond length is 1.09 Å. In the fourteenth H site, H(41,43) is bonded in a single-bond geometry to one C(65) atom. The H(41,43)-C(65) bond length is 1.09 Å. In the fifteenth H site, H(44) is bonded in a single-bond geometry to one C(68) atom. In the sixteenth H site, H(46,47,48) is bonded in a single-bond geometry to one C(70) atom. The H(46,47,48)-C(70) bond length is 1.09 Å. There are four inequivalent O sites. In the first O site, O(5) is bonded in a distorted L-shaped geometry to one Co(1) and one C(1,2) atom. In the second O site, O(6) is bonded in a distorted L-shaped geometry to one Co(1) and one C(1,2) atom. The O(6)-C(1,2) bond length is 1.27 Å. In the third O site, O(1) is bonded in an L-shaped geometry to one Co(1) and one C(1,2) atom. In the fourth O site, O(2) is bonded in an L-shaped geometry to one Co(1) and one C(1,2) atom. The O(2)-C(1,2) bond length is 1.29 Å. Linkers: 3 [O][C]c1[c]cc(-c2ccc(C3=C[CH]N([Co]45(N6[CH]C=C(c7ccc(-c8ccc(C([O])=O)cc8)cc7)C=C6)(O[C](c6ccc(-c7ccc(-c8c[c]ncc8)cc7)cc6)O4)O[C](c4ccc(-c6ccc(-c7ccncc7)cc6)cc4)O5)C=C3)cc2)cc1 ,2 [O]C(=O)c1ccc(-c2ccc(C3=C[CH]N([Co]45(N6[CH]C=C(c7ccc(-c8ccc(C([O])=O)cc8)cc7)C=C6)(O[C](c6ccc(-c7ccc(-c8ccncc8)cc7)cc6)O4)O[C](c4ccc(-c6ccc(-c7ccncc7)cc6)cc4)O5)C=C3)cc2)cc1 ,1 [CH]=[C]c1ccc([C]2O[Co]3(N4[CH]C=C(c5ccc(-c6ccc(C([O])=O)cc6)cc5)C=C4)(N4[CH]C=C(c5ccc(-c6ccc(C([O])=O)cc6)cc5)C=C4)(O[C](c4c[c][c]cc4)O3)O2)cc1 ,1 [CH]=[C]c1ccc([C]2O[Co]3(N4[CH]C=C(c5ccc(-c6c[c]c([C][O])cc6)cc5)C=C4)(N4[CH]C=C(c5ccc(-c6ccc(C([O])=O)cc6)cc5)C=C4)(O[C](c4c[c][c]cc4)O3)O2)cc1 ,1 [C]/C=C(\C=[CH])C1=C[CH]N([Co]23(N4[CH]C=C(c5ccc(-c6ccc(C([O])=O)cc6)cc5)C=C4)(O[C](c4ccc(-c5ccc(-c6c[c]ncc6)cc5)cc4)O2)O[C](c2ccc(-c4ccc(-c5ccncc5)cc4)cc2)O3)C=C1 ,1 [C]/C=C(\C=[CH])C1=C[CH]N([Co]23(N4[CH]C=C(c5ccc(-c6ccc(C([O])=O)cc6)cc5)C=C4)(O[C](c4ccc(-c5ccc(-c6ccncc6)cc5)cc4)O2)O[C](c2ccc(-c4ccc(-c5ccncc5)cc4)cc2)O3)C=C1 ,1 [C]/C=C(\C=[CH])C1=C[CH]N([Co]23(N4[CH]C=C(c5ccc(-c6c[c]c([C][O])cc6)cc5)C=C4)(O[C](c4ccc(-c5ccc(-c6c[c]ncc6)cc5)cc4)O2)O[C](c2ccc(-c4ccc(-c5ccncc5)cc4)cc2)O3)C=C1. Metal clusters: 2 [C]1O[Co]2(O1)O[C]O2. The MOF has largest included sphere 8.22 A, density 0.82 g/cm3, surface area 5180.40 m2/g, accessible volume 0.61 cm3/g