ZnC4H10(NO5)2 crystallizes in the monoclinic C2/c space group. Zn(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Zn(1)-O(1) bond lengths are 2.13 Å. Both Zn(1)-O(2) bond lengths are 2.13 Å. Both Zn(1)-O(3) bond lengths are 2.16 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(4), and one O(1) atom. The C(1)-H(3) bond length is 1.10 Å. The C(1)-H(4) bond length is 1.10 Å. The C(1)-O(1) bond length is 1.45 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one H(5) and one O(2) atom. The C(2)-H(5) bond length is 1.10 Å. The C(2)-O(2) bond length is 1.44 Å. N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. The N(1)-O(3) bond length is 1.31 Å. The N(1)-O(4) bond length is 1.24 Å. The N(1)-O(5) bond length is 1.26 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) and one O(5) atom. The H(1)-O(1) bond length is 1.00 Å. The H(1)-O(5) bond length is 1.72 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) and one O(3) atom. The H(2)-O(2) bond length is 1.00 Å. The H(2)-O(3) bond length is 1.69 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one C(1), and one H(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Zn(1), one C(2), and one H(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Zn(1), one N(1), and one H(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one N(1) and one H(1) atom. Linkers: 2 OC[C@@H](O)[C@@H](O)CO. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.62 A, density 2.12 g/cm3, surface area 3530.82 m2/g, accessible volume 0.09 cm3/g