(CH)2CuC18H22S2(NO2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one CuC18H22S2(NO2)4 cluster. In the CuC18H22S2(NO2)4 cluster, Cu(1) is bonded to two equivalent N(1), two equivalent N(2), and two equivalent O(1) atoms to form CuN4O2 octahedra that share corners with two equivalent S(1)CNO2 tetrahedra. Both Cu(1)-N(1) bond lengths are 2.21 Å. Both Cu(1)-N(2) bond lengths are 2.00 Å. Both Cu(1)-O(1) bond lengths are 2.31 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(9) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(3) bond length is 1.50 Å. The C(1)-C(9) bond length is 1.39 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(7), and one S(1) atom. The C(2)-C(7) bond length is 1.39 Å. The C(2)-S(1) bond length is 1.77 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one O(3) atom. The C(3)-N(1) bond length is 1.37 Å. The C(3)-O(3) bond length is 1.25 Å. In the fourth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one H(4), one H(5), and one O(1) atom. The C(5)-H(4) bond length is 1.10 Å. The C(5)-H(5) bond length is 1.10 Å. The C(5)-O(1) bond length is 1.43 Å. In the fifth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one H(6), one H(7), and one O(1) atom. The C(6)-H(6) bond length is 1.10 Å. The C(6)-H(7) bond length is 1.10 Å. The C(6)-O(1) bond length is 1.43 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(8) atom. The C(7)-H(8) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(9) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(9) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(1), one C(8), and one H(10) atom. The C(9)-H(10) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(11), and one H(12) atom. The C(10)-N(2) bond length is 1.48 Å. The C(10)-H(11) bond length is 1.10 Å. The C(10)-H(12) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one S(1) atom. The N(1)-S(1) bond length is 1.64 Å. In the second N site, N(2) is bonded to one Cu(1), one C(10), one H(1), and one H(2) atom to form distorted corner-sharing NCuH2C tetrahedra. The N(2)-H(1) bond length is 1.03 Å. The N(2)-H(2) bond length is 1.02 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(10) atom. S(1) is bonded to one C(2), one N(1), one O(2), and one O(4) atom to form distorted SCNO2 tetrahedra that share  a cornercorner with one Cu(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 55°. The S(1)-O(2) bond length is 1.45 Å. The S(1)-O(4) bond length is 1.46 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1), one C(5), and one C(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. Linkers: 1 NCCOCCOCCN. Metal clusters: 1 [Cu]. The MOF has largest included sphere 1.78 A, density 1.70 g/cm3, surface area 4363.48 m2/g, accessible volume 0.15 cm3/g