PrC15H8(NO3)2(CH2)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and one PrC15H8(NO3)2 cluster. In the PrC15H8(NO3)2 cluster, Pr(1) is bonded in a 9-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), one O(4), one O(6), and two equivalent O(5) atoms. The Pr(1)-N(1) bond length is 2.71 Å. The Pr(1)-N(2) bond length is 2.66 Å. The Pr(1)-O(1) bond length is 2.49 Å. The Pr(1)-O(2) bond length is 2.44 Å. The Pr(1)-O(3) bond length is 2.51 Å. The Pr(1)-O(4) bond length is 2.55 Å. The Pr(1)-O(6) bond length is 2.58 Å. There is one shorter (2.42 Å) and one longer (2.66 Å) Pr(1)-O(5) bond length. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(6)-O(3) bond length is 1.28 Å. The C(6)-O(4) bond length is 1.28 Å. In the third C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(7)-O(5) bond length is 1.28 Å. The C(7)-O(6) bond length is 1.27 Å. In the fourth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one H(13) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-N(1) bond length is 1.33 Å. The C(10)-H(13) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(14) atom. The C(11)-H(14) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(15) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-H(15) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(20) atom. The C(13)-C(14) bond length is 1.42 Å. The C(13)-C(20) bond length is 1.43 Å. In the eighth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one N(1) atom. The C(14)-C(15) bond length is 1.44 Å. The C(14)-N(1) bond length is 1.36 Å. In the ninth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one N(2) atom. The C(15)-C(16) bond length is 1.42 Å. The C(15)-N(2) bond length is 1.36 Å. In the tenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(21) bond length is 1.43 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(16) atom. The C(17)-H(16) bond length is 1.09 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(17) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-H(17) bond length is 1.09 Å. In the thirteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(2), and one H(18) atom. The C(19)-N(2) bond length is 1.33 Å. The C(19)-H(18) bond length is 1.09 Å. In the fourteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(13), one C(21), and one H(19) atom. The C(20)-C(21) bond length is 1.37 Å. The C(20)-H(19) bond length is 1.09 Å. In the fifteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one H(20) atom. The C(21)-H(20) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Pr(1), one C(10), and one C(14) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Pr(1), one C(15), and one C(19) atom. There are eight inequivalent H sites. In the first H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(14) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(21) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pr(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Pr(1) and one C(6) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Pr(1) and one C(6) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to two equivalent Pr(1) and one C(7) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Pr(1) and one C(7) atom. Linkers: 2 c1cnc2c(c1)ccc1cccnc12 ,3 [O]C(=O)CCCCC([O])=O. Metal clusters: 1 [C]1O[Pr]234(O1)O[C]O[Pr]1(O[C]O1)(O[C]O2)(O[C]O3)O[C]O4. The MOF has largest included sphere 2.52 A, density 1.70 g/cm3, surface area 4041.66 m2/g, accessible volume 0.15 cm3/g