MnC14N2H10O5(CH)5CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules, two 02329_fluka molecules, and one MnC14N2H10O5 cluster. In the MnC14N2H10O5 cluster, Mn(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one O(1), one O(2), one O(4), and one O(5) atom. The Mn(1)-N(1) bond length is 2.13 Å. The Mn(1)-O(1) bond length is 2.14 Å. The Mn(1)-O(2) bond length is 2.11 Å. The Mn(1)-O(4) bond length is 2.11 Å. The Mn(1)-O(5) bond length is 2.12 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.41 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one O(3) atom. The C(7)-O(3) bond length is 1.39 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one O(3) atom. The C(8)-O(3) bond length is 1.38 Å. In the sixth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(6) bond length is 1.09 Å. In the seventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(14) bond length is 1.49 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 1.09 Å. In the ninth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(4), and one O(5) atom. The C(14)-O(4) bond length is 1.28 Å. The C(14)-O(5) bond length is 1.28 Å. In the tenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(1), and one H(9) atom. The C(15)-C(16) bond length is 1.37 Å. The C(15)-N(1) bond length is 1.39 Å. The C(15)-H(9) bond length is 1.08 Å. In the eleventh C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(2), and one H(10) atom. The C(16)-N(2) bond length is 1.38 Å. The C(16)-H(10) bond length is 1.08 Å. In the twelfth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(18), one N(1), and one N(2) atom. The C(17)-C(18) bond length is 1.48 Å. The C(17)-N(1) bond length is 1.34 Å. The C(17)-N(2) bond length is 1.36 Å. In the thirteenth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one C(17), one H(11), one H(12), and one H(13) atom. The C(18)-H(11) bond length is 1.10 Å. The C(18)-H(12) bond length is 1.10 Å. The C(18)-H(13) bond length is 1.10 Å. In the fourteenth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(14), and one H(15) atom. The C(19)-N(2) bond length is 1.46 Å. The C(19)-H(14) bond length is 1.10 Å. The C(19)-H(15) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(1), one C(15), and one C(17) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(16), one C(17), and one C(19) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(7) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(14) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(14) atom. Linkers: 2 [O]C(=O)c1ccc(Oc2ccccc2C([O])=O)cc1 ,1 Cc1nccn1CCCCn1ccnc1C. Metal clusters: 1 [C]1O[Mn]234O[C]O[Mn]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 2.62 A, density 1.53 g/cm3, surface area 4374.83 m2/g, accessible volume 0.18 cm3/g