Ag2C2N2HS2Cl crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one N(2), one S(1), and two equivalent Cl(1) atoms to form distorted corner-sharing AgSNCl2 tetrahedra. The Ag(1)-N(2) bond length is 2.30 Å. The Ag(1)-S(1) bond length is 2.44 Å. There is one shorter (2.59 Å) and one longer (2.66 Å) Ag(1)-Cl(1) bond length. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one N(1), two equivalent S(1), and one Cl(1) atom. The Ag(2)-N(1) bond length is 2.22 Å. There is one shorter (2.45 Å) and one longer (2.70 Å) Ag(2)-S(1) bond length. The Ag(2)-Cl(1) bond length is 2.79 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one S(2) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-S(1) bond length is 1.72 Å. The C(1)-S(2) bond length is 1.74 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2), one H(1), and one S(2) atom. The C(2)-N(2) bond length is 1.31 Å. The C(2)-H(1) bond length is 1.09 Å. The C(2)-S(2) bond length is 1.72 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(2), and one N(1) atom. The N(2)-N(1) bond length is 1.37 Å. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(1), and one N(2) atom. H(1) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one Ag(1), two equivalent Ag(2), and one C(1) atom to form corner-sharing SAg3C tetrahedra. In the second S site, S(2) is bonded in an L-shaped geometry to one C(1) and one C(2) atom. Cl(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2) and two equivalent Ag(1) atoms. Linkers: 4 S=C1[N]N=CS1. Metal clusters: 8 [Ag]. The MOF has largest included sphere 1.58 A, density 3.69 g/cm3, surface area 1841.28 m2/g, accessible volume 0.04 cm3/g