CdC14N2H18(O2F)4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CdC14N2H18(O2F)4 clusters. Cd(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. Both Cd(1)-O(1) bond lengths are 2.28 Å. Both Cd(1)-O(3) bond lengths are 2.39 Å. Both Cd(1)-O(4) bond lengths are 2.32 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(4) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one F(1) atom. The C(3)-F(1) bond length is 1.36 Å. In the fourth C site, C(4) is bonded in a single-bond geometry to one C(2) and one F(2) atom. The C(4)-F(2) bond length is 1.36 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(1), one H(1), and one O(3) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(1) bond length is 1.10 Å. The C(5)-O(3) bond length is 1.26 Å. In the sixth C site, C(6) is bonded to one N(1), one H(2), one H(3), and one H(4) atom to form corner-sharing CH3N tetrahedra. The C(6)-N(1) bond length is 1.46 Å. The C(6)-H(2) bond length is 1.10 Å. The C(6)-H(3) bond length is 1.10 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded to one N(1), one H(5), one H(6), and one H(7) atom to form corner-sharing CH3N tetrahedra. The C(7)-N(1) bond length is 1.45 Å. The C(7)-H(5) bond length is 1.09 Å. The C(7)-H(6) bond length is 1.10 Å. The C(7)-H(7) bond length is 1.10 Å. N(1) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(7) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. The H(8)-O(4) bond length is 1.00 Å. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(4) atom. The H(9)-O(4) bond length is 0.99 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cd(1), one H(8), and one H(9) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(4) atom. Linkers: 2 [O][C]c1c(F)c(F)c(C([O])=O)c(F)c1F ,1 [O]C(=O)c1c(F)c(F)c(C([O])=O)c(F)c1F. Metal clusters: 2 [Cd]. The MOF has largest included sphere 1.67 A, density 1.90 g/cm3, surface area 4340.67 m2/g, accessible volume 0.15 cm3/g