AgC4NH8SO2 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four AgC4NH8SO2 clusters. Ag(1) is bonded in a distorted linear geometry to one N(1), one S(1), and one O(2) atom. The Ag(1)-N(1) bond length is 2.18 Å. The Ag(1)-S(1) bond length is 2.86 Å. The Ag(1)-O(2) bond length is 2.15 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.29 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one N(1) and one H(1) atom. The C(2)-N(1) bond length is 1.47 Å. The C(2)-H(1) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted water-like geometry to one H(2), one H(3), and one S(1) atom. The C(3)-H(2) bond length is 1.10 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-S(1) bond length is 1.81 Å. In the fourth C site, C(4) is bonded in a trigonal non-coplanar geometry to one H(4), one H(5), one H(6), and one S(1) atom. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. The C(4)-H(6) bond length is 1.10 Å. The C(4)-S(1) bond length is 1.80 Å. N(1) is bonded in a 4-coordinate geometry to one Ag(1), one C(2), one H(7), and one H(8) atom. The N(1)-H(7) bond length is 1.03 Å. The N(1)-H(8) bond length is 1.03 Å. There are eight inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(7) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one C(3), and one C(4) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one C(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one C(1) atom. Linkers: 3 CSC[C@H](N)C([O])=O. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.71 A, density 2.43 g/cm3, surface area 3074.44 m2/g, accessible volume 0.06 cm3/g