SnC6H10(NBr)2 is alpha structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two SnC6H10(NBr)2 clusters. Sn(1) is bonded in an octahedral geometry to two equivalent C(2), two equivalent N(1), and two equivalent Br(1) atoms. Both Sn(1)-C(2) bond lengths are 2.15 Å. Both Sn(1)-N(1) bond lengths are 2.41 Å. Both Sn(1)-Br(1) bond lengths are 2.75 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(3) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(1), and two equivalent H(2) atoms. The C(2)-H(1) bond length is 1.09 Å. Both C(2)-H(2) bond lengths are 1.10 Å. N(1) is bonded in a trigonal planar geometry to one Sn(1) and two equivalent C(1) atoms. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. Br(1) is bonded in a single-bond geometry to one Sn(1) atom. Linkers: 1 c1cnccn1. Metal clusters: 1 Br[Sn]Br. The MOF has largest included sphere 1.91 A, density 2.43 g/cm3, surface area 3266.31 m2/g, accessible volume 0.09 cm3/g