Ag5C17H11(NO5)2CH(CF3)4 crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules and eight trifluoromethane molecules inside a Ag5C17H11(NO5)2 framework. In the Ag5C17H11(NO5)2 framework, there are five inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted T-shaped geometry to one C(1), one N(2), and one O(1) atom. The Ag(1)-C(1) bond length is 2.11 Å. The Ag(1)-N(2) bond length is 2.16 Å. The Ag(1)-O(1) bond length is 2.44 Å. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one C(1), one C(2), one O(2), and two equivalent O(5) atoms. The Ag(2)-C(1) bond length is 2.39 Å. The Ag(2)-C(2) bond length is 2.43 Å. The Ag(2)-O(2) bond length is 2.39 Å. There is one shorter (2.37 Å) and one longer (2.51 Å) Ag(2)-O(5) bond length. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to two equivalent C(1), one O(7), and one O(9) atom. There is one shorter (2.28 Å) and one longer (2.62 Å) Ag(3)-C(1) bond length. The Ag(3)-O(7) bond length is 2.28 Å. The Ag(3)-O(9) bond length is 2.42 Å. In the fourth Ag site, Ag(4) is bonded in a 6-coordinate geometry to one C(1), one O(10), one O(3), one O(4), one O(6), and one O(8) atom. The Ag(4)-C(1) bond length is 2.41 Å. The Ag(4)-O(10) bond length is 2.57 Å. The Ag(4)-O(3) bond length is 2.80 Å. The Ag(4)-O(4) bond length is 2.49 Å. The Ag(4)-O(6) bond length is 2.48 Å. The Ag(4)-O(8) bond length is 2.61 Å. In the fifth Ag site, Ag(5) is bonded in a 4-coordinate geometry to one C(9), one O(10), one O(3), and one O(4) atom. The Ag(5)-C(9) bond length is 1.99 Å. The Ag(5)-O(10) bond length is 2.52 Å. The Ag(5)-O(3) bond length is 2.31 Å. The Ag(5)-O(4) bond length is 2.35 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a 6-coordinate geometry to one Ag(1), one Ag(2), one Ag(4), two equivalent Ag(3), and one C(2) atom. The C(1)-C(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a 3-coordinate geometry to one Ag(2), one C(1), and one C(3) atom. The C(2)-C(3) bond length is 1.43 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(8) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(4)-H(5) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(7) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(1) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(1) bond length is 1.38 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(8) atom. The C(8)-H(8) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a linear geometry to one Ag(5) and one N(1) atom. The C(9)-N(1) bond length is 1.18 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one H(9) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(9) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(10) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(10) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(13) atom. The C(12)-C(12) bond length is 1.48 Å. The C(12)-C(13) bond length is 1.40 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(11) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(11) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(2), and one H(12) atom. The C(14)-N(2) bond length is 1.35 Å. The C(14)-H(12) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(15)-O(2) bond length is 1.26 Å. The C(15)-O(3) bond length is 1.26 Å. In the fifteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(17)-O(5) bond length is 1.26 Å. The C(17)-O(6) bond length is 1.26 Å. In the sixteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(19)-O(7) bond length is 1.26 Å. The C(19)-O(8) bond length is 1.26 Å. In the seventeenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(21)-O(10) bond length is 1.26 Å. The C(21)-O(9) bond length is 1.26 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one C(7) and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(10), and one C(14) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. The H(3)-O(4) bond length is 1.00 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(4) atom. The H(4)-O(4) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(14) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ag(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(2) and one C(15) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(4), one Ag(5), and one C(15) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Ag(4), one Ag(5), one H(3), and one H(4) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one C(17) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Ag(4) and one C(17) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Ag(3) and one C(19) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Ag(4) and one C(19) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Ag(3) and one C(21) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Ag(4), one Ag(5), and one C(21) atom. Linkers: 1 c1cc(-c2ccncc2)ccn1. Metal clusters: 10 [Ag]. The MOF has largest included sphere 2.28 A, density 2.63 g/cm3, surface area 2836.33 m2/g, accessible volume 0.07 cm3/g