NdCu2C16H15I2(NO4)2CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a NdCu2C16H15I2(NO4)2 framework. In the NdCu2C16H15I2(NO4)2 framework, Nd(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(7), one O(8), and two equivalent O(6) atoms. The Nd(1)-O(1) bond length is 2.51 Å. The Nd(1)-O(2) bond length is 2.50 Å. The Nd(1)-O(3) bond length is 2.53 Å. The Nd(1)-O(4) bond length is 2.57 Å. The Nd(1)-O(5) bond length is 2.52 Å. The Nd(1)-O(7) bond length is 2.49 Å. The Nd(1)-O(8) bond length is 2.48 Å. There is one shorter (2.46 Å) and one longer (2.64 Å) Nd(1)-O(6) bond length. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted single-bond geometry to one N(1), one I(1), and two equivalent I(2) atoms. The Cu(1)-N(1) bond length is 2.03 Å. The Cu(1)-I(1) bond length is 2.69 Å. There is one shorter (2.63 Å) and one longer (2.65 Å) Cu(1)-I(2) bond length. In the second Cu site, Cu(2) is bonded in a 1-coordinate geometry to one N(2), one I(2), and two equivalent I(1) atoms. The Cu(2)-N(2) bond length is 2.03 Å. The Cu(2)-I(2) bond length is 2.66 Å. There is one shorter (2.61 Å) and one longer (2.64 Å) Cu(2)-I(1) bond length. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(13), one C(16), and one C(2) atom. The C(1)-C(13) bond length is 1.40 Å. The C(1)-C(16) bond length is 1.41 Å. The C(1)-C(2) bond length is 1.46 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(1) atom. The C(2)-C(5) bond length is 1.35 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(4)-O(3) bond length is 1.29 Å. The C(4)-O(4) bond length is 1.28 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(3) atom. The C(5)-C(6) bond length is 1.47 Å. The C(5)-H(3) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(5), and one O(6) atom. The C(6)-O(5) bond length is 1.27 Å. The C(6)-O(6) bond length is 1.30 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(8) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one H(9) atom. The C(8)-N(1) bond length is 1.35 Å. The C(8)-H(9) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(15), one N(2), and one H(10) atom. The C(9)-C(15) bond length is 1.39 Å. The C(9)-N(2) bond length is 1.35 Å. The C(9)-H(10) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(10)-C(12) bond length is 1.41 Å. The C(10)-H(11) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(1), and one H(12) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(12) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(14) atom. The C(12)-C(14) bond length is 1.45 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(1), one N(2), and one H(13) atom. The C(13)-N(2) bond length is 1.34 Å. The C(13)-H(13) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(14) atom. The C(14)-H(14) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(9) and one H(15) atom. The C(15)-H(15) bond length is 1.09 Å. In the fifteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(1) and one H(16) atom. The C(16)-H(16) bond length is 1.09 Å. In the sixteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(17)-O(1) bond length is 1.25 Å. The C(17)-O(2) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(13), and one C(9) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a distorted single-bond geometry to one O(3) and one O(7) atom. The H(4)-O(3) bond length is 1.67 Å. The H(4)-O(7) bond length is 1.00 Å. In the fourth H site, H(5) is bonded in a single-bond geometry to one O(7) atom. The H(5)-O(7) bond length is 0.98 Å. In the fifth H site, H(6) is bonded in a distorted single-bond geometry to one O(4) and one O(8) atom. The H(6)-O(4) bond length is 1.66 Å. The H(6)-O(8) bond length is 1.00 Å. In the sixth H site, H(7) is bonded in a distorted single-bond geometry to one O(2) and one O(8) atom. The H(7)-O(2) bond length is 1.63 Å. The H(7)-O(8) bond length is 1.00 Å. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Nd(1) and one C(17) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Nd(1), one C(17), and one H(7) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Nd(1), one C(4), and one H(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Nd(1), one C(4), and one H(6) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Nd(1) and one C(6) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Nd(1) and one C(6) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Nd(1), one H(4), and one H(5) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Nd(1), one H(6), and one H(7) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1) and two equivalent Cu(2) atoms. In the second I site, I(2) is bonded in a distorted T-shaped geometry to one Cu(2) and two equivalent Cu(1) atoms. Linkers: 4 [O]C(=O)/C=C/c1cccnc1. Metal clusters: 2 [Nd] ,4 [Cu]. The MOF has largest included sphere 3.18 A, density 2.48 g/cm3, surface area 2672.62 m2/g, accessible volume 0.10 cm3/g