ZnC22H16(NO3)2(CH)4 is Indium-derived structured and crystallizes in the orthorhombic Aea2 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four ZnC22H16(NO3)2 clusters. In each ZnC22H16(NO3)2 cluster, Zn(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent O(2) atoms. Both Zn(1)-N(1) bond lengths are 2.07 Å. Both Zn(1)-O(2) bond lengths are 2.02 Å. There are eleven inequivalent C sites. In the first C site, C(12) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(9) atom. The C(12)-C(5) bond length is 1.39 Å. The C(12)-N(1) bond length is 1.35 Å. The C(12)-H(9) bond length is 1.09 Å. In the second C site, C(13) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one H(10) atom. The C(13)-C(7) bond length is 1.39 Å. The C(13)-N(1) bond length is 1.34 Å. The C(13)-H(10) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(2), and one O(3) atom. The C(1)-C(6) bond length is 1.49 Å. The C(1)-O(2) bond length is 1.30 Å. The C(1)-O(3) bond length is 1.26 Å. In the fourth C site, C(2) is bonded in a distorted single-bond geometry to one O(1) atom. The C(2)-O(1) bond length is 1.37 Å. In the fifth C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one H(1), one H(2), and one O(1) atom. The C(3)-C(10) bond length is 1.50 Å. The C(3)-H(1) bond length is 1.10 Å. The C(3)-H(2) bond length is 1.10 Å. The C(3)-O(1) bond length is 1.43 Å. In the sixth C site, C(4) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(4)-C(6) bond length is 1.40 Å. The C(4)-H(3) bond length is 1.09 Å. In the seventh C site, C(5) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(4) atom. The C(5)-C(10) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the eighth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(8) atom. The C(6)-C(8) bond length is 1.40 Å. In the ninth C site, C(7) is bonded in a distorted single-bond geometry to one C(10), one C(13), and one H(5) atom. The C(7)-C(10) bond length is 1.40 Å. The C(7)-H(5) bond length is 1.09 Å. In the tenth C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the eleventh C site, C(10) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(12), and one C(13) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. Linkers: 4 [O]C(=O)c1ccc(OCc2ccncc2)cc1 ,1 [O]C(=O)c1ccc(OCc2c[c]ncc2)cc1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.30 A, density 1.42 g/cm3, surface area 5042.86 m2/g, accessible volume 0.21 cm3/g