ZnC26H18S(N2O3)2C6H4SO2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four di-isopropenylsulfon molecules and four ZnC26H18S(N2O3)2 clusters. In two of the ZnC26H18S(N2O3)2 clusters, Zn(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(4), one O(11), and one O(2) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-N(4) bond length is 2.04 Å. The Zn(1)-O(11) bond length is 2.05 Å. The Zn(1)-O(2) bond length is 1.97 Å. There are twenty-six inequivalent C sites. In the first C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(14) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-H(14) bond length is 1.09 Å. In the second C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(28) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(28) bond length is 1.50 Å. In the third C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(15) atom. The C(26)-H(15) bond length is 1.09 Å. In the fourth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(11), and one O(12) atom. The C(28)-O(11) bond length is 1.29 Å. The C(28)-O(12) bond length is 1.26 Å. In the fifth C site, C(29) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(17) atom. The C(29)-N(1) bond length is 1.33 Å. The C(29)-N(2) bond length is 1.36 Å. The C(29)-H(17) bond length is 1.08 Å. In the sixth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(31), one N(1), and one H(18) atom. The C(30)-C(31) bond length is 1.37 Å. The C(30)-N(1) bond length is 1.39 Å. The C(30)-H(18) bond length is 1.08 Å. In the seventh C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(30), one N(2), and one H(19) atom. The C(31)-N(2) bond length is 1.39 Å. The C(31)-H(19) bond length is 1.08 Å. In the eighth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(33), one C(37), and one N(2) atom. The C(32)-C(33) bond length is 1.40 Å. The C(32)-C(37) bond length is 1.40 Å. The C(32)-N(2) bond length is 1.41 Å. In the ninth C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(20) atom. The C(33)-H(20) bond length is 1.09 Å. In the tenth C site, C(34) is bonded in a distorted single-bond geometry to one C(35) and one H(21) atom. The C(34)-C(35) bond length is 1.40 Å. The C(34)-H(21) bond length is 1.09 Å. In the eleventh C site, C(35) is bonded in a trigonal planar geometry to one C(34), one C(36), and one S(3) atom. The C(35)-C(36) bond length is 1.40 Å. The C(35)-S(3) bond length is 1.76 Å. In the twelfth C site, C(36) is bonded in a distorted single-bond geometry to one C(35) and one H(22) atom. The C(36)-H(22) bond length is 1.09 Å. In the thirteenth C site, C(37) is bonded in a distorted single-bond geometry to one C(32) and one H(23) atom. The C(37)-H(23) bond length is 1.09 Å. In the fourteenth C site, C(38) is bonded in a trigonal planar geometry to one C(39), one C(43), and one S(3) atom. The C(38)-C(39) bond length is 1.40 Å. The C(38)-C(43) bond length is 1.40 Å. The C(38)-S(3) bond length is 1.77 Å. In the fifteenth C site, C(39) is bonded in a distorted single-bond geometry to one C(38) and one H(24) atom. The C(39)-H(24) bond length is 1.09 Å. In the sixteenth C site, C(40) is bonded in a distorted single-bond geometry to one C(41) and one H(25) atom. The C(40)-C(41) bond length is 1.40 Å. The C(40)-H(25) bond length is 1.09 Å. In the seventeenth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(40), one C(42), and one N(3) atom. The C(41)-C(42) bond length is 1.40 Å. The C(41)-N(3) bond length is 1.42 Å. In the eighteenth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(41), one C(43), and one H(26) atom. The C(42)-C(43) bond length is 1.39 Å. The C(42)-H(26) bond length is 1.09 Å. In the nineteenth C site, C(43) is bonded in a distorted trigonal planar geometry to one C(38), one C(42), and one H(27) atom. The C(43)-H(27) bond length is 1.09 Å. In the twentieth C site, C(44) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(28) atom. The C(44)-N(3) bond length is 1.36 Å. The C(44)-N(4) bond length is 1.33 Å. The C(44)-H(28) bond length is 1.09 Å. In the twenty-first C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(46), one N(3), and one H(29) atom. The C(45)-C(46) bond length is 1.37 Å. The C(45)-N(3) bond length is 1.39 Å. The C(45)-H(29) bond length is 1.08 Å. In the twenty-second C site, C(46) is bonded in a distorted bent 120 degrees geometry to one C(45), one N(4), and one H(30) atom. The C(46)-N(4) bond length is 1.38 Å. The C(46)-H(30) bond length is 1.09 Å. In the twenty-third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.30 Å. In the twenty-fourth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the twenty-fifth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the twenty-sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(29), and one C(30) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(32) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(41), one C(44), and one C(45) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(44), and one C(46) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(29) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(31) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(33) atom. In the ninth H site, H(21) is bonded in a single-bond geometry to one C(34) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(36) atom. In the eleventh H site, H(23) is bonded in a single-bond geometry to one C(37) atom. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(39) atom. In the thirteenth H site, H(25) is bonded in a single-bond geometry to one C(40) atom. In the fourteenth H site, H(26) is bonded in a single-bond geometry to one C(42) atom. In the fifteenth H site, H(27) is bonded in a single-bond geometry to one C(43) atom. In the sixteenth H site, H(28) is bonded in a single-bond geometry to one C(44) atom. In the seventeenth H site, H(29) is bonded in a single-bond geometry to one C(45) atom. In the eighteenth H site, H(30) is bonded in a single-bond geometry to one C(46) atom. S(3) is bonded in a distorted bent 120 degrees geometry to one C(35), one C(38), one O(13), and one O(14) atom. The S(3)-O(13) bond length is 1.45 Å. The S(3)-O(14) bond length is 1.46 Å. There are six inequivalent O sites. In the first O site, O(11) is bonded in a water-like geometry to one Zn(1) and one C(28) atom. In the second O site, O(12) is bonded in a single-bond geometry to one C(28) atom. In the third O site, O(13) is bonded in a single-bond geometry to one S(3) atom. In the fourth O site, O(14) is bonded in a single-bond geometry to one S(3) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the sixth O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In two of the ZnC26H18S(N2O3)2 clusters, Zn(2) is bonded in a tetrahedral geometry to one N(5), one N(8), one O(6), and one O(7) atom. The Zn(2)-N(5) bond length is 2.01 Å. The Zn(2)-N(8) bond length is 2.04 Å. The Zn(2)-O(6) bond length is 1.99 Å. The Zn(2)-O(7) bond length is 1.99 Å. There are twenty-six inequivalent C sites. In the first C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one S(2) atom. The C(19)-C(18) bond length is 1.40 Å. The C(19)-C(20) bond length is 1.40 Å. The C(19)-S(2) bond length is 1.78 Å. In the second C site, C(21) is bonded in a distorted trigonal planar geometry to one C(16), one C(20), and one H(12) atom. The C(21)-C(16) bond length is 1.40 Å. The C(21)-C(20) bond length is 1.39 Å. The C(21)-H(12) bond length is 1.09 Å. In the third C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one H(11) atom. The C(20)-H(11) bond length is 1.09 Å. In the fourth C site, C(22) is bonded in a trigonal planar geometry to one C(23), one C(27), and one S(2) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(27) bond length is 1.40 Å. The C(22)-S(2) bond length is 1.77 Å. In the fifth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(13) atom. The C(23)-H(13) bond length is 1.09 Å. In the sixth C site, C(27) is bonded in a distorted single-bond geometry to one C(22) and one H(16) atom. The C(27)-H(16) bond length is 1.09 Å. In the seventh C site, C(47) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(31) atom. The C(47)-N(5) bond length is 1.33 Å. The C(47)-N(6) bond length is 1.37 Å. The C(47)-H(31) bond length is 1.08 Å. In the eighth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(49), one N(5), and one H(32) atom. The C(48)-C(49) bond length is 1.37 Å. The C(48)-N(5) bond length is 1.39 Å. The C(48)-H(32) bond length is 1.08 Å. In the ninth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(48), one N(6), and one H(33) atom. The C(49)-N(6) bond length is 1.39 Å. The C(49)-H(33) bond length is 1.08 Å. In the tenth C site, C(50) is bonded in a distorted trigonal planar geometry to one C(51), one C(55), and one N(6) atom. The C(50)-C(51) bond length is 1.40 Å. The C(50)-C(55) bond length is 1.40 Å. The C(50)-N(6) bond length is 1.42 Å. In the eleventh C site, C(51) is bonded in a distorted single-bond geometry to one C(50) and one H(34) atom. The C(51)-H(34) bond length is 1.09 Å. In the twelfth C site, C(55) is bonded in a distorted single-bond geometry to one C(50) and one H(37) atom. The C(55)-H(37) bond length is 1.09 Å. In the thirteenth C site, C(58) is bonded in a distorted single-bond geometry to one C(59) and one H(39) atom. The C(58)-C(59) bond length is 1.40 Å. The C(58)-H(39) bond length is 1.09 Å. In the fourteenth C site, C(59) is bonded in a distorted trigonal planar geometry to one C(58), one C(60), and one N(7) atom. The C(59)-C(60) bond length is 1.40 Å. The C(59)-N(7) bond length is 1.42 Å. In the fifteenth C site, C(60) is bonded in a distorted single-bond geometry to one C(59) and one H(40) atom. The C(60)-H(40) bond length is 1.09 Å. In the sixteenth C site, C(62) is bonded in a distorted bent 120 degrees geometry to one C(63), one N(7), and one H(42) atom. The C(62)-C(63) bond length is 1.37 Å. The C(62)-N(7) bond length is 1.39 Å. The C(62)-H(42) bond length is 1.08 Å. In the seventeenth C site, C(63) is bonded in a distorted bent 120 degrees geometry to one C(62), one N(8), and one H(43) atom. The C(63)-N(8) bond length is 1.38 Å. The C(63)-H(43) bond length is 1.08 Å. In the eighteenth C site, C(64) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(44) atom. The C(64)-N(7) bond length is 1.36 Å. The C(64)-N(8) bond length is 1.33 Å. The C(64)-H(44) bond length is 1.08 Å. In the nineteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(10) atom. The C(18)-C(17) bond length is 1.39 Å. The C(18)-H(10) bond length is 1.09 Å. In the twentieth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(6) bond length is 1.09 Å. In the twenty-first C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(14) bond length is 1.51 Å. In the twenty-second C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 1.09 Å. In the twenty-third C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(9) atom. The C(17)-C(16) bond length is 1.40 Å. The C(17)-H(9) bond length is 1.09 Å. In the twenty-fourth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(5), and one O(6) atom. The C(14)-O(5) bond length is 1.25 Å. The C(14)-O(6) bond length is 1.30 Å. In the twenty-fifth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(7), and one O(8) atom. The C(15)-C(16) bond length is 1.51 Å. The C(15)-O(7) bond length is 1.30 Å. The C(15)-O(8) bond length is 1.24 Å. In the twenty-sixth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. There are four inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one Zn(2), one C(47), and one C(48) atom. In the second N site, N(6) is bonded in a trigonal planar geometry to one C(47), one C(49), and one C(50) atom. In the third N site, N(7) is bonded in a trigonal planar geometry to one C(59), one C(62), and one C(64) atom. In the fourth N site, N(8) is bonded in a trigonal planar geometry to one Zn(2), one C(63), and one C(64) atom. There are eighteen inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(23) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(31) is bonded in a single-bond geometry to one C(47) atom. In the tenth H site, H(32) is bonded in a single-bond geometry to one C(48) atom. In the eleventh H site, H(33) is bonded in a single-bond geometry to one C(49) atom. In the twelfth H site, H(34) is bonded in a single-bond geometry to one C(51) atom. In the thirteenth H site, H(37) is bonded in a single-bond geometry to one C(55) atom. In the fourteenth H site, H(39) is bonded in a single-bond geometry to one C(58) atom. In the fifteenth H site, H(40) is bonded in a single-bond geometry to one C(60) atom. In the sixteenth H site, H(42) is bonded in a single-bond geometry to one C(62) atom. In the seventeenth H site, H(43) is bonded in a single-bond geometry to one C(63) atom. In the eighteenth H site, H(44) is bonded in a single-bond geometry to one C(64) atom. S(2) is bonded in a distorted bent 120 degrees geometry to one C(19), one C(22), one O(10), and one O(9) atom. The S(2)-O(10) bond length is 1.45 Å. The S(2)-O(9) bond length is 1.46 Å. There are six inequivalent O sites. In the first O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(15) atom. In the second O site, O(8) is bonded in a single-bond geometry to one C(15) atom. In the third O site, O(9) is bonded in a single-bond geometry to one S(2) atom. In the fourth O site, O(10) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(14) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(14) atom. Linkers: 1 O=S.O=S.O=S.O=S.O=S=O.O=[C]O[Zn].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C][S]([O])[O].[CH]=[N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/[C]=[C]\[C][S@@](=O)C(=[CH])/[C]=C\[C][N].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C][CH].[C][CH][C].[C][C].[C][C].[C][C].[C][C]/[C]=[C]\[C].[C][N].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N][C][C][N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[S].[S].[Zn].[Zn] ,1 O=S.O=S.O=S.O=S.O=S=O.[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[CH].[CH]=[N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]C=[CH].[C][C].[C][C].[C][C].[C][C]/[C]=[C]\[C].[C][C]=[CH].[C][C][C].[C][C][S].[C][N].[C][N].[C][N][C].[C][S]=O.[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][Zn].[S].[S].[S].[Zn].[Zn]. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.11 A, density 1.50 g/cm3, surface area 4589.29 m2/g, accessible volume 0.20 cm3/g