NiC22N2H15O5C4H3(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two isobutylene molecules, and one NiC22N2H15O5 cluster. In the NiC22N2H15O5 cluster, Ni(1) is bonded in a distorted octahedral geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(5) atom. The Ni(1)-N(1) bond length is 2.01 Å. The Ni(1)-N(2) bond length is 1.99 Å. The Ni(1)-O(1) bond length is 2.10 Å. The Ni(1)-O(2) bond length is 2.27 Å. The Ni(1)-O(3) bond length is 1.98 Å. The Ni(1)-O(5) bond length is 2.15 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-C(8) bond length is 1.46 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(5) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(5) and one H(7) atom. The C(8)-H(7) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(4) atom. The C(9)-C(10) bond length is 1.50 Å. The C(9)-O(3) bond length is 1.29 Å. The C(9)-O(4) bond length is 1.26 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.41 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(11)-H(8) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one H(11) atom. The C(15)-H(11) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(21), one C(28), and one N(1) atom. The C(17)-C(21) bond length is 1.42 Å. The C(17)-C(28) bond length is 1.43 Å. The C(17)-N(1) bond length is 1.36 Å. In the fourteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(18)-N(1) bond length is 1.33 Å. The C(18)-H(13) bond length is 1.09 Å. In the fifteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(15) atom. The C(20)-C(21) bond length is 1.41 Å. The C(20)-H(15) bond length is 1.09 Å. In the sixteenth C site, C(21) is bonded in a trigonal planar geometry to one C(17), one C(20), and one C(22) atom. The C(21)-C(22) bond length is 1.43 Å. In the seventeenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one H(16) atom. The C(22)-C(23) bond length is 1.37 Å. The C(22)-H(16) bond length is 1.09 Å. In the eighteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22), one C(24), and one H(17) atom. The C(23)-C(24) bond length is 1.43 Å. The C(23)-H(17) bond length is 1.09 Å. In the nineteenth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(28) atom. The C(24)-C(25) bond length is 1.41 Å. The C(24)-C(28) bond length is 1.42 Å. In the twentieth C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(18) atom. The C(25)-H(18) bond length is 1.09 Å. In the twenty-first C site, C(27) is bonded in a distorted trigonal planar geometry to one N(2) and one H(20) atom. The C(27)-N(2) bond length is 1.34 Å. The C(27)-H(20) bond length is 1.09 Å. In the twenty-second C site, C(28) is bonded in a distorted trigonal planar geometry to one C(17), one C(24), and one N(2) atom. The C(28)-N(2) bond length is 1.36 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(17), and one C(18) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ni(1), one C(27), and one C(28) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(4) and one O(5) atom. The H(1)-O(4) bond length is 1.63 Å. The H(1)-O(5) bond length is 1.00 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(5) atom. The H(2)-O(5) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(27) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Ni(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Ni(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ni(1) and one C(9) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(9) and one H(1) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Ni(1), one H(1), and one H(2) atom. Linkers: 2 [O]C(=O)c1ccc(/C=C/c2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 O.O=[C]O[Ni]1O[C]O1. The MOF has largest included sphere 3.06 A, density 1.52 g/cm3, surface area 4452.39 m2/g, accessible volume 0.15 cm3/g