CuC2H6(NO2)2(CH2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and four CuC2H6(NO2)2 clusters. In each CuC2H6(NO2)2 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent N(1), one O(1), and one O(3) atom. Both Cu(1)-N(1) bond lengths are 1.99 Å. The Cu(1)-O(1) bond length is 2.02 Å. The Cu(1)-O(3) bond length is 2.03 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(3)-O(3) bond length is 1.30 Å. The C(3)-O(4) bond length is 1.25 Å. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one H(1), one H(2), and one H(3) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.03 Å. The N(1)-H(3) bond length is 1.03 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(3) atom. Linkers: 2 [O]C(=O)CCC([O])=O. Metal clusters: 2 [Cu]. The MOF has largest included sphere 1.41 A, density 2.00 g/cm3, surface area 3693.92 m2/g, accessible volume 0.07 cm3/g