Fe4H21(C3O2)11(CH3)3(CH)5C4H3 crystallizes in the triclinic P1 space group. The structure consists of two 02329_fluka molecules, six 02329_fluka molecules, two isobutylene molecules, and two isobutylene molecules inside a Fe4H21(C3O2)11 framework. In the Fe4H21(C3O2)11 framework, there are eight inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(12), one O(18), one O(32), one O(38), one O(40), and one O(7) atom to form corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 57-59°. The Fe(1)-O(12) bond length is 1.97 Å. The Fe(1)-O(18) bond length is 1.86 Å. The Fe(1)-O(32) bond length is 2.13 Å. The Fe(1)-O(38) bond length is 1.96 Å. The Fe(1)-O(40) bond length is 1.87 Å. The Fe(1)-O(7) bond length is 2.16 Å. In the second Fe site, Fe(2) is bonded to one O(10), one O(19), one O(30), one O(34), one O(37), and one O(5) atom to form corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 60-62°. The Fe(2)-O(10) bond length is 2.00 Å. The Fe(2)-O(19) bond length is 1.99 Å. The Fe(2)-O(30) bond length is 2.08 Å. The Fe(2)-O(34) bond length is 1.98 Å. The Fe(2)-O(37) bond length is 2.05 Å. The Fe(2)-O(5) bond length is 2.07 Å. In the third Fe site, Fe(3) is bonded to one O(11), one O(16), one O(18), one O(3), one O(39), and one O(8) atom to form corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 58-59°. The Fe(3)-O(11) bond length is 2.05 Å. The Fe(3)-O(16) bond length is 2.03 Å. The Fe(3)-O(18) bond length is 2.06 Å. The Fe(3)-O(3) bond length is 2.04 Å. The Fe(3)-O(39) bond length is 1.96 Å. The Fe(3)-O(8) bond length is 1.99 Å. In the fourth Fe site, Fe(4) is bonded to one O(1), one O(14), one O(17), one O(19), one O(6), and one O(9) atom to form corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 58-62°. The Fe(4)-O(1) bond length is 2.08 Å. The Fe(4)-O(14) bond length is 2.05 Å. The Fe(4)-O(17) bond length is 1.96 Å. The Fe(4)-O(19) bond length is 2.00 Å. The Fe(4)-O(6) bond length is 2.00 Å. The Fe(4)-O(9) bond length is 2.05 Å. In the fifth Fe site, Fe(5) is bonded to one O(15), one O(24), one O(29), one O(35), one O(39), and one O(4) atom to form corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles are 58°. The Fe(5)-O(15) bond length is 2.14 Å. The Fe(5)-O(24) bond length is 2.08 Å. The Fe(5)-O(29) bond length is 2.03 Å. The Fe(5)-O(35) bond length is 2.00 Å. The Fe(5)-O(39) bond length is 1.95 Å. The Fe(5)-O(4) bond length is 2.00 Å. In the sixth Fe site, Fe(6) is bonded to one O(13), one O(17), one O(2), one O(22), one O(27), and one O(36) atom to form corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 58-60°. The Fe(6)-O(13) bond length is 2.12 Å. The Fe(6)-O(17) bond length is 1.95 Å. The Fe(6)-O(2) bond length is 1.98 Å. The Fe(6)-O(22) bond length is 2.07 Å. The Fe(6)-O(27) bond length is 2.04 Å. The Fe(6)-O(36) bond length is 1.99 Å. In the seventh Fe site, Fe(7) is bonded to one O(21), one O(25), one O(28), one O(33), one O(35), and one O(40) atom to form corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 57-58°. The Fe(7)-O(21) bond length is 2.07 Å. The Fe(7)-O(25) bond length is 1.99 Å. The Fe(7)-O(28) bond length is 2.06 Å. The Fe(7)-O(33) bond length is 2.01 Å. The Fe(7)-O(35) bond length is 1.97 Å. The Fe(7)-O(40) bond length is 2.02 Å. In the eighth Fe site, Fe(8) is bonded to one O(20), one O(23), one O(26), one O(31), one O(34), and one O(36) atom to form corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles are 60°. The Fe(8)-O(20) bond length is 2.07 Å. The Fe(8)-O(23) bond length is 2.01 Å. The Fe(8)-O(26) bond length is 2.09 Å. The Fe(8)-O(31) bond length is 2.01 Å. The Fe(8)-O(34) bond length is 1.98 Å. The Fe(8)-O(36) bond length is 1.98 Å. There are sixty-six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(55) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(4) bond length is 1.50 Å. The C(1)-C(55) bond length is 1.40 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1,4,6) atom. The C(2)-H(1,4,6) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(53) and one H(2) atom. The C(3)-C(53) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(37) atom. The C(4)-O(1) bond length is 1.27 Å. The C(4)-O(37) bond length is 1.28 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(51), one C(6), and one C(8) atom. The C(5)-C(51) bond length is 1.40 Å. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.49 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(1,4,6) atom. The C(6)-H(1,4,6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(49) and one H(5) atom. The C(7)-C(49) bond length is 1.40 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(3), and one O(38) atom. The C(8)-O(3) bond length is 1.27 Å. The C(8)-O(38) bond length is 1.28 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(31) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(12) bond length is 1.49 Å. The C(9)-C(31) bond length is 1.40 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(1,4,6) atom. The C(10)-H(1,4,6) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(29) and one H(7) atom. The C(11)-C(29) bond length is 1.40 Å. The C(11)-H(7) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(5), and one O(6) atom. The C(12)-O(5) bond length is 1.27 Å. The C(12)-O(6) bond length is 1.28 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(27) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(16) bond length is 1.49 Å. The C(13)-C(27) bond length is 1.40 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(8) atom. The C(14)-H(8) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(25) and one H(9) atom. The C(15)-C(25) bond length is 1.40 Å. The C(15)-H(9) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(7), and one O(8) atom. The C(16)-O(7) bond length is 1.26 Å. The C(16)-O(8) bond length is 1.28 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(39) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(20) bond length is 1.49 Å. The C(17)-C(39) bond length is 1.40 Å. In the eighteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(11) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(11) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(37), and one H(12) atom. The C(19)-C(37) bond length is 1.40 Å. The C(19)-H(12) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(27), and one O(9) atom. The C(20)-O(27) bond length is 1.28 Å. The C(20)-O(9) bond length is 1.27 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(35) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(24) bond length is 1.49 Å. The C(21)-C(35) bond length is 1.40 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(14) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-H(14) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(33), and one H(15) atom. The C(23)-C(33) bond length is 1.40 Å. The C(23)-H(15) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(11), and one O(29) atom. The C(24)-O(11) bond length is 1.28 Å. The C(24)-O(29) bond length is 1.27 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(15), one C(26), and one C(28) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(28) bond length is 1.49 Å. In the twenty-sixth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one C(27), and one H(16) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-H(16) bond length is 1.09 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(13), one C(26), and one H(17) atom. The C(27)-H(17) bond length is 1.09 Å. In the twenty-eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(13), and one O(14) atom. The C(28)-O(13) bond length is 1.26 Å. The C(28)-O(14) bond length is 1.30 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(11), one C(30), and one C(32) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-C(32) bond length is 1.49 Å. In the thirtieth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one C(31), and one H(18) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-H(18) bond length is 1.09 Å. In the thirty-first C site, C(31) is bonded in a distorted single-bond geometry to one C(30), one C(9), and one H(19) atom. The C(31)-H(19) bond length is 1.09 Å. In the thirty-second C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(15), and one O(16) atom. The C(32)-O(15) bond length is 1.27 Å. The C(32)-O(16) bond length is 1.29 Å. In the thirty-third C site, C(33) is bonded in a trigonal planar geometry to one C(23), one C(34), and one C(36) atom. The C(33)-C(34) bond length is 1.40 Å. The C(33)-C(36) bond length is 1.49 Å. In the thirty-fourth C site, C(34) is bonded in a distorted single-bond geometry to one C(33), one C(35), and one H(20) atom. The C(34)-C(35) bond length is 1.39 Å. The C(34)-H(20) bond length is 1.09 Å. In the thirty-fifth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(21), one C(34), and one H(21) atom. The C(35)-H(21) bond length is 1.09 Å. In the thirty-sixth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(33), one O(2), and one O(20) atom. The C(36)-O(2) bond length is 1.28 Å. The C(36)-O(20) bond length is 1.27 Å. In the thirty-seventh C site, C(37) is bonded in a trigonal planar geometry to one C(19), one C(38), and one C(40) atom. The C(37)-C(38) bond length is 1.40 Å. The C(37)-C(40) bond length is 1.49 Å. In the thirty-eighth C site, C(38) is bonded in a distorted single-bond geometry to one C(37), one C(39), and one H(23) atom. The C(38)-C(39) bond length is 1.39 Å. The C(38)-H(23) bond length is 1.09 Å. In the thirty-ninth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(17), one C(38), and one H(24) atom. The C(39)-H(24) bond length is 1.09 Å. In the fortieth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(21), and one O(4) atom. The C(40)-O(21) bond length is 1.28 Å. The C(40)-O(4) bond length is 1.28 Å. In the forty-first C site, C(41) is bonded in a trigonal planar geometry to one C(42), one C(44), and one C(63) atom. The C(41)-C(42) bond length is 1.40 Å. The C(41)-C(44) bond length is 1.49 Å. The C(41)-C(63) bond length is 1.40 Å. In the forty-second C site, C(42) is bonded in a distorted trigonal planar geometry to one C(41), one C(43), and one H(25) atom. The C(42)-C(43) bond length is 1.39 Å. The C(42)-H(25) bond length is 1.09 Å. In the forty-third C site, C(43) is bonded in a distorted single-bond geometry to one C(42), one C(61), and one H(26) atom. The C(43)-C(61) bond length is 1.40 Å. The C(43)-H(26) bond length is 1.09 Å. In the forty-fourth C site, C(44) is bonded in a distorted bent 120 degrees geometry to one C(41), one O(22), and one O(23) atom. The C(44)-O(22) bond length is 1.27 Å. The C(44)-O(23) bond length is 1.28 Å. In the forty-fifth C site, C(45) is bonded in a trigonal planar geometry to one C(46), one C(48), and one C(59) atom. The C(45)-C(46) bond length is 1.40 Å. The C(45)-C(48) bond length is 1.49 Å. The C(45)-C(59) bond length is 1.40 Å. In the forty-sixth C site, C(46) is bonded in a distorted trigonal planar geometry to one C(45), one C(47), and one H(27) atom. The C(46)-C(47) bond length is 1.39 Å. The C(46)-H(27) bond length is 1.09 Å. In the forty-seventh C site, C(47) is bonded in a distorted single-bond geometry to one C(46), one C(57), and one H(28) atom. The C(47)-C(57) bond length is 1.40 Å. The C(47)-H(28) bond length is 1.09 Å. In the forty-eighth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(45), one O(24), and one O(25) atom. The C(48)-O(24) bond length is 1.27 Å. The C(48)-O(25) bond length is 1.28 Å. In the forty-ninth C site, C(49) is bonded in a trigonal planar geometry to one C(50), one C(52), and one C(7) atom. The C(49)-C(50) bond length is 1.40 Å. The C(49)-C(52) bond length is 1.49 Å. In the fiftieth C site, C(50) is bonded in a distorted single-bond geometry to one C(49) and one H(30) atom. The C(50)-H(30) bond length is 1.09 Å. In the fifty-first C site, C(51) is bonded in a distorted single-bond geometry to one C(5) and one H(31,34) atom. The C(51)-H(31,34) bond length is 1.09 Å. In the fifty-second C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(49), one O(10), and one O(26) atom. The C(52)-O(10) bond length is 1.28 Å. The C(52)-O(26) bond length is 1.27 Å. In the fifty-third C site, C(53) is bonded in a trigonal planar geometry to one C(3), one C(54), and one C(56) atom. The C(53)-C(54) bond length is 1.40 Å. The C(53)-C(56) bond length is 1.50 Å. In the fifty-fourth C site, C(54) is bonded in a distorted single-bond geometry to one C(53) and one H(33) atom. The C(54)-H(33) bond length is 1.09 Å. In the fifty-fifth C site, C(55) is bonded in a distorted single-bond geometry to one C(1) and one H(31,34) atom. The C(55)-H(31,34) bond length is 1.09 Å. In the fifty-sixth C site, C(56) is bonded in a distorted bent 120 degrees geometry to one C(53), one O(12), and one O(28) atom. The C(56)-O(12) bond length is 1.29 Å. The C(56)-O(28) bond length is 1.27 Å. In the fifty-seventh C site, C(57) is bonded in a trigonal planar geometry to one C(47), one C(58), and one C(60) atom. The C(57)-C(58) bond length is 1.40 Å. The C(57)-C(60) bond length is 1.49 Å. In the fifty-eighth C site, C(58) is bonded in a distorted single-bond geometry to one C(57) and one H(35) atom. The C(58)-H(35) bond length is 1.09 Å. In the fifty-ninth C site, C(59) is bonded in a distorted single-bond geometry to one C(45) and one H(36) atom. The C(59)-H(36) bond length is 1.09 Å. In the sixtieth C site, C(60) is bonded in a distorted bent 120 degrees geometry to one C(57), one O(30), and one O(31) atom. The C(60)-O(30) bond length is 1.27 Å. The C(60)-O(31) bond length is 1.28 Å. In the sixty-first C site, C(61) is bonded in a trigonal planar geometry to one C(43), one C(62), and one C(64) atom. The C(61)-C(62) bond length is 1.40 Å. The C(61)-C(64) bond length is 1.49 Å. In the sixty-second C site, C(62) is bonded in a distorted single-bond geometry to one C(61) and one H(37) atom. The C(62)-H(37) bond length is 1.09 Å. In the sixty-third C site, C(63) is bonded in a distorted single-bond geometry to one C(41) and one H(38) atom. The C(63)-H(38) bond length is 1.09 Å. In the sixty-fourth C site, C(64) is bonded in a distorted bent 120 degrees geometry to one C(61), one O(32), and one O(33) atom. The C(64)-O(32) bond length is 1.27 Å. The C(64)-O(33) bond length is 1.28 Å. In the sixty-fifth C site, C(70) is bonded in a distorted bent 120 degrees geometry to one O(41) and one O(42) atom. The C(70)-O(41) bond length is 1.34 Å. The C(70)-O(42) bond length is 1.23 Å. In the sixty-sixth C site, C(83) is bonded in a distorted bent 120 degrees geometry to one O(43) and one O(44) atom. The C(83)-O(43) bond length is 1.34 Å. The C(83)-O(44) bond length is 1.23 Å. There are thirty-nine inequivalent H sites. In the first H site, H(1,4,6) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(19) atom. The H(3)-O(19) bond length is 0.97 Å. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one O(18) atom. The H(10)-O(18) bond length is 0.98 Å. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(13) is bonded in a distorted linear geometry to one O(17) and one O(42) atom. The H(13)-O(17) bond length is 1.00 Å. The H(13)-O(42) bond length is 1.64 Å. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(26) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(31) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(34) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(35) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one O(36) atom. The H(22)-O(36) bond length is 0.97 Å. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(38) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(39) atom. In the twenty-third H site, H(25) is bonded in a single-bond geometry to one C(42) atom. In the twenty-fourth H site, H(26) is bonded in a single-bond geometry to one C(43) atom. In the twenty-fifth H site, H(27) is bonded in a single-bond geometry to one C(46) atom. In the twenty-sixth H site, H(28) is bonded in a single-bond geometry to one C(47) atom. In the twenty-seventh H site, H(29) is bonded in a single-bond geometry to one O(35) atom. The H(29)-O(35) bond length is 0.97 Å. In the twenty-eighth H site, H(30) is bonded in a single-bond geometry to one C(50) atom. In the twenty-ninth H site, H(31,34) is bonded in a single-bond geometry to one C(51) atom. In the thirtieth H site, H(32) is bonded in a single-bond geometry to one O(34) atom. The H(32)-O(34) bond length is 0.97 Å. In the thirty-first H site, H(33) is bonded in a single-bond geometry to one C(54) atom. In the thirty-second H site, H(35) is bonded in a single-bond geometry to one C(58) atom. In the thirty-third H site, H(36) is bonded in a single-bond geometry to one C(59) atom. In the thirty-fourth H site, H(37) is bonded in a single-bond geometry to one C(62) atom. In the thirty-fifth H site, H(38) is bonded in a single-bond geometry to one C(63) atom. In the thirty-sixth H site, H(39) is bonded in a distorted single-bond geometry to one O(39) and one O(44) atom. The H(39)-O(39) bond length is 1.00 Å. The H(39)-O(44) bond length is 1.67 Å. In the thirty-seventh H site, H(40) is bonded in a single-bond geometry to one O(40) atom. The H(40)-O(40) bond length is 0.98 Å. In the thirty-eighth H site, H(50) is bonded in a single-bond geometry to one O(41) atom. The H(50)-O(41) bond length is 0.99 Å. In the thirty-ninth H site, H(68) is bonded in a single-bond geometry to one O(43) atom. The H(68)-O(43) bond length is 0.99 Å. There are forty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Fe(4) and one C(4) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Fe(6) and one C(36) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Fe(3) and one C(8) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Fe(5) and one C(40) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Fe(2) and one C(12) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Fe(4) and one C(12) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Fe(1) and one C(16) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Fe(3) and one C(16) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Fe(4) and one C(20) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(52) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Fe(3) and one C(24) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Fe(1) and one C(56) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Fe(6) and one C(28) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Fe(4) and one C(28) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Fe(5) and one C(32) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Fe(3) and one C(32) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Fe(4), one Fe(6), and one H(13) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Fe(1), one Fe(3), and one H(10) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Fe(2), one Fe(4), and one H(3) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Fe(8) and one C(36) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Fe(7) and one C(40) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Fe(6) and one C(44) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 120 degrees geometry to one Fe(8) and one C(44) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Fe(5) and one C(48) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 120 degrees geometry to one Fe(7) and one C(48) atom. In the twenty-sixth O site, O(26) is bonded in a bent 120 degrees geometry to one Fe(8) and one C(52) atom. In the twenty-seventh O site, O(27) is bonded in a distorted bent 120 degrees geometry to one Fe(6) and one C(20) atom. In the twenty-eighth O site, O(28) is bonded in a distorted bent 120 degrees geometry to one Fe(7) and one C(56) atom. In the twenty-ninth O site, O(29) is bonded in a distorted bent 120 degrees geometry to one Fe(5) and one C(24) atom. In the thirtieth O site, O(30) is bonded in a bent 120 degrees geometry to one Fe(2) and one C(60) atom. In the thirty-first O site, O(31) is bonded in a distorted bent 120 degrees geometry to one Fe(8) and one C(60) atom. In the thirty-second O site, O(32) is bonded in a bent 120 degrees geometry to one Fe(1) and one C(64) atom. In the thirty-third O site, O(33) is bonded in a distorted bent 120 degrees geometry to one Fe(7) and one C(64) atom. In the thirty-fourth O site, O(34) is bonded in a distorted trigonal planar geometry to one Fe(2), one Fe(8), and one H(32) atom. In the thirty-fifth O site, O(35) is bonded in a distorted trigonal planar geometry to one Fe(5), one Fe(7), and one H(29) atom. In the thirty-sixth O site, O(36) is bonded in a distorted trigonal planar geometry to one Fe(6), one Fe(8), and one H(22) atom. In the thirty-seventh O site, O(37) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(4) atom. In the thirty-eighth O site, O(38) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(8) atom. In the thirty-ninth O site, O(39) is bonded in a distorted trigonal planar geometry to one Fe(3), one Fe(5), and one H(39) atom. In the fortieth O site, O(40) is bonded in a distorted trigonal planar geometry to one Fe(1), one Fe(7), and one H(40) atom. In the forty-first O site, O(41) is bonded in a bent 120 degrees geometry to one C(70) and one H(50) atom. In the forty-second O site, O(42) is bonded in a bent 120 degrees geometry to one C(70) and one H(13) atom. In the forty-third O site, O(43) is bonded in a bent 120 degrees geometry to one C(83) and one H(68) atom. In the forty-fourth O site, O(44) is bonded in a distorted bent 120 degrees geometry to one C(83) and one H(39) atom. Linkers: 8 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 8 [Fe]. The MOF has largest included sphere 3.22 A, density 1.53 g/cm3, surface area 4006.37 m2/g, accessible volume 0.20 cm3/g