Zn3C38H24(NO4)4(CH)4 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a Zn3C38H24(NO4)4 framework. In the Zn3C38H24(NO4)4 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted trigonal pyramidal geometry to one O(1), one O(5), one O(6), and one O(7) atom. The Zn(1)-O(1) bond length is 2.03 Å. The Zn(1)-O(5) bond length is 1.98 Å. The Zn(1)-O(6) bond length is 1.96 Å. The Zn(1)-O(7) bond length is 2.01 Å. In the second Zn site, Zn(2) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(2), and two equivalent O(3) atoms. Both Zn(2)-N(1) bond lengths are 2.19 Å. Both Zn(2)-O(2) bond lengths are 2.07 Å. Both Zn(2)-O(3) bond lengths are 2.23 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one O(8) atom. The C(1)-O(8) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(5) atom. The C(2)-C(4) bond length is 1.50 Å. The C(2)-O(3) bond length is 1.26 Å. The C(2)-O(5) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(7) atom. The C(3)-C(6) bond length is 1.49 Å. The C(3)-O(1) bond length is 1.28 Å. The C(3)-O(7) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(6) atom. The C(4)-C(10) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(4), and one O(6) atom. The C(5)-C(9) bond length is 1.49 Å. The C(5)-O(4) bond length is 1.27 Å. The C(5)-O(6) bond length is 1.28 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(7) atom. The C(6)-C(7) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(14), one C(6), and one H(1) atom. The C(7)-C(14) bond length is 1.39 Å. The C(7)-H(1) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(13) and one H(2) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-H(2) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(5) atom. The C(9)-C(11) bond length is 1.40 Å. The C(9)-C(15) bond length is 1.40 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(12), one C(4), and one H(3) atom. The C(10)-C(12) bond length is 1.39 Å. The C(10)-H(3) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(11)-H(4) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one O(8) atom. The C(12)-C(14) bond length is 1.40 Å. The C(12)-O(8) bond length is 1.38 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(16), one C(17), and one C(8) atom. The C(13)-C(16) bond length is 1.46 Å. The C(13)-C(17) bond length is 1.40 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(12), one C(7), and one H(5) atom. The C(14)-H(5) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(15)-H(6) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(2), and one H(7) atom. The C(16)-N(2) bond length is 1.29 Å. The C(16)-H(7) bond length is 1.10 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(13), one C(20), and one H(8) atom. The C(17)-C(20) bond length is 1.39 Å. The C(17)-H(8) bond length is 1.09 Å. In the eighteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(17), one N(1), and one H(11) atom. The C(20)-N(1) bond length is 1.35 Å. The C(20)-H(11) bond length is 1.09 Å. In the nineteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one N(1) and one H(12) atom. The C(21)-N(1) bond length is 1.35 Å. The C(21)-H(12) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(20), and one C(21) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(16) and one N(2) atom. The N(2)-N(2) bond length is 1.39 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(13) is bonded in a distorted single-bond geometry to one O(2) and one O(4) atom. The H(13)-O(2) bond length is 0.99 Å. The H(13)-O(4) bond length is 1.69 Å. In the twelfth H site, H(14) is bonded in a distorted single-bond geometry to one O(2) and one O(4) atom. The H(14)-O(2) bond length is 1.00 Å. The H(14)-O(4) bond length is 1.67 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Zn(2), one H(13), and one H(14) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one C(5), one H(13), and one H(14) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Zn(1) and one C(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one C(1) and one C(12) atom. Linkers: 2 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)c(C([O])=O)c2)cc1 ,2 [c]1cc([CH][N][N][CH]c2ccncc2)ccn1 ,1 [CH]([N][N][CH]c1ccncc1)c1ccncc1. Metal clusters: 3 [Zn]. The MOF has largest included sphere 1.81 A, density 1.79 g/cm3, surface area 4044.22 m2/g, accessible volume 0.10 cm3/g