CdC8H8(NO)6(C7H6S)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two C7H6S clusters and one CdC8H8(NO)6 cluster. In each C7H6S cluster, there are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one C(2), one H(1), one H(2), and one S(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-S(2) bond length is 1.83 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.41 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(5) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(6) atom. The C(6)-C(7) bond length is 1.41 Å. The C(6)-H(6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(8) atom. The C(7)-C(8) bond length is 1.50 Å. In the eighth C site, C(8) is bonded in a distorted water-like geometry to one C(7), one H(7), one H(8), and one S(1) atom. The C(8)-H(7) bond length is 1.10 Å. The C(8)-H(8) bond length is 1.10 Å. The C(8)-S(1) bond length is 1.83 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(10) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-H(10) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one S(1) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-S(1) bond length is 1.75 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(11) atom. The C(12)-H(11) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(14) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(18), and one S(2) atom. The C(16)-C(18) bond length is 1.41 Å. The C(16)-S(2) bond length is 1.74 Å. In the fourteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(16) and one H(16) atom. The C(18)-H(16) bond length is 1.09 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(11) and one C(8) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(1) and one C(16) atom. In the CdC8H8(NO)6 cluster, Cd(1) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(3), and two equivalent O(1) atoms. Both Cd(1)-N(2) bond lengths are 2.36 Å. Both Cd(1)-N(3) bond lengths are 2.36 Å. Both Cd(1)-O(1) bond lengths are 2.44 Å. There are four inequivalent C sites. In the first C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(15) atom. The C(17)-N(3) bond length is 1.34 Å. The C(17)-H(15) bond length is 1.09 Å. In the second C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(9)-N(2) bond length is 1.35 Å. The C(9)-H(9) bond length is 1.09 Å. In the third C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(13) atom. The C(14)-N(3) bond length is 1.35 Å. The C(14)-H(13) bond length is 1.09 Å. In the fourth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(13)-N(2) bond length is 1.34 Å. The C(13)-H(12) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(1)-O(1) bond length is 1.30 Å. The N(1)-O(2) bond length is 1.26 Å. The N(1)-O(3) bond length is 1.26 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(14), and one C(17) atom. There are four inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. Linkers: 2 c1ccc(CSc2ccncc2)c(CSc2ccncc2)c1. Metal clusters: 1 [Cd]. The MOF has largest included sphere 5.55 A, density 1.08 g/cm3, surface area 4957.24 m2/g, accessible volume 0.38 cm3/g