UCuC12N2H12SO13 crystallizes in the triclinic P-1 space group. U(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), one O(7), and one O(8) atom to form distorted UO7 pentagonal bipyramids that share  a cornercorner with one Cu(1)N2O4 octahedra and corners with two equivalent S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 28°. The U(1)-O(1) bond length is 1.81 Å. The U(1)-O(2) bond length is 1.82 Å. The U(1)-O(3) bond length is 2.33 Å. The U(1)-O(4) bond length is 2.29 Å. The U(1)-O(6) bond length is 2.49 Å. The U(1)-O(7) bond length is 2.47 Å. The U(1)-O(8) bond length is 2.30 Å. Cu(1) is bonded to one N(1), one N(2), one O(13), one O(2), one O(5), and one O(9) atom to form CuN2O4 octahedra that share  a cornercorner with one U(1)O7 pentagonal bipyramid. The Cu(1)-N(1) bond length is 2.01 Å. The Cu(1)-N(2) bond length is 2.00 Å. The Cu(1)-O(13) bond length is 2.38 Å. The Cu(1)-O(2) bond length is 2.40 Å. The Cu(1)-O(5) bond length is 2.03 Å. The Cu(1)-O(9) bond length is 2.02 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(6), and one O(7) atom. The C(1)-C(5) bond length is 1.50 Å. The C(1)-O(6) bond length is 1.28 Å. The C(1)-O(7) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(10), one C(4), and one N(1) atom. The C(2)-C(10) bond length is 1.39 Å. The C(2)-C(4) bond length is 1.47 Å. The C(2)-N(1) bond length is 1.36 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(5) atom. The C(3)-C(12) bond length is 1.39 Å. The C(3)-N(2) bond length is 1.34 Å. The C(3)-H(5) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(2) atom. The C(4)-C(6) bond length is 1.39 Å. The C(4)-N(2) bond length is 1.36 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(11) atom. The C(5)-C(10) bond length is 1.39 Å. The C(5)-C(11) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4), one C(7), and one H(8) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(8) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(6), and one C(9) atom. The C(7)-C(12) bond length is 1.40 Å. The C(7)-C(9) bond length is 1.51 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one H(9) atom. The C(8)-C(11) bond length is 1.39 Å. The C(8)-N(1) bond length is 1.34 Å. The C(8)-H(9) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(12), and one O(4) atom. The C(9)-O(12) bond length is 1.25 Å. The C(9)-O(4) bond length is 1.29 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(10) atom. The C(10)-H(10) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(5), one C(8), and one H(11) atom. The C(11)-H(11) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(12) atom. The C(12)-H(12) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(2), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(4) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(10) and one O(5) atom. The H(1)-O(10) bond length is 1.57 Å. The H(1)-O(5) bond length is 1.01 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(5) atom. The H(2)-O(5) bond length is 0.97 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(11) and one O(9) atom. The H(3)-O(11) bond length is 1.67 Å. The H(3)-O(9) bond length is 1.00 Å. In the fourth H site, H(4) is bonded in a distorted linear geometry to one O(10) and one O(9) atom. The H(4)-O(10) bond length is 1.59 Å. The H(4)-O(9) bond length is 1.01 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(13) atom. The H(6)-O(13) bond length is 0.99 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(13) atom. The H(7)-O(13) bond length is 0.98 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. S(1) is bonded to one O(10), one O(11), one O(3), and one O(8) atom to form SO4 tetrahedra that share corners with two equivalent U(1)O7 pentagonal bipyramids. The S(1)-O(10) bond length is 1.50 Å. The S(1)-O(11) bond length is 1.46 Å. The S(1)-O(3) bond length is 1.50 Å. The S(1)-O(8) bond length is 1.49 Å. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one U(1) and one Cu(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one U(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one U(1) and one C(9) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one H(1), and one H(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one U(1) and one C(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one U(1) and one C(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one U(1) and one S(1) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Cu(1), one H(3), and one H(4) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one H(1), one H(4), and one S(1) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one H(3) and one S(1) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one C(9) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one Cu(1), one H(6), and one H(7) atom. Linkers: 2 [O]C(=O)c1ccnc(-c2cc(C([O])=O)ccn2)c1. Metal clusters: 1 O.O.O.O.O.O.[O]S1([O])O[U]([O])(O[Cu])(O[C]=O)(O[C]=O)OS([O])([O])O[U]([O])(O[Cu])(O[C]=O)(O[C]=O)O1. The MOF has largest included sphere 2.63 A, density 2.55 g/cm3, surface area 2633.73 m2/g, accessible volume 0.12 cm3/g