ZnC2H8(NCl)2(H2CS)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four dimethyl disulfide molecules and four ZnC2H8(NCl)2 clusters. In each ZnC2H8(NCl)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one Cl(1), and one Cl(2) atom. The Zn(1)-N(1) bond length is 2.05 Å. The Zn(1)-N(2) bond length is 2.05 Å. The Zn(1)-Cl(1) bond length is 2.24 Å. The Zn(1)-Cl(2) bond length is 2.28 Å. There are two inequivalent C sites. In the first C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(11), and one H(12) atom. The C(4)-N(2) bond length is 1.48 Å. The C(4)-H(11) bond length is 1.10 Å. The C(4)-H(12) bond length is 1.10 Å. In the second C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(5), and one H(6) atom. The C(1)-N(1) bond length is 1.48 Å. The C(1)-H(5) bond length is 1.10 Å. The C(1)-H(6) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Zn(1), one C(1), one H(1), and one H(2) atom to form distorted corner-sharing NZnH2C tetrahedra. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.03 Å. In the second N site, N(2) is bonded to one Zn(1), one C(4), one H(3), and one H(4) atom to form distorted corner-sharing NZnH2C tetrahedra. The N(2)-H(3) bond length is 1.03 Å. The N(2)-H(4) bond length is 1.03 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the eighth H site, H(6) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 4 NCCSSCCN. Metal clusters: 4 [Zn]. The MOF has largest included sphere 1.86 A, density 1.85 g/cm3, surface area 4433.14 m2/g, accessible volume 0.11 cm3/g