PbC4H16(N2Cl)2 is gamma plutonium structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two PbC4H16(N2Cl)2 clusters. Pb(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one N(3), one N(4), one Cl(1), and one Cl(2) atom. The Pb(1)-N(1) bond length is 2.49 Å. The Pb(1)-N(2) bond length is 2.49 Å. The Pb(1)-N(3) bond length is 2.63 Å. The Pb(1)-N(4) bond length is 2.63 Å. The Pb(1)-Cl(1) bond length is 3.11 Å. The Pb(1)-Cl(2) bond length is 3.11 Å. There are three inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal non-coplanar geometry to one N(1); one H(11,12); and one H(9,10) atom. The C(1,2)-N(1) bond length is 1.47 Å. The C(1,2)-H(11,12) bond length is 1.10 Å. The C(1,2)-H(9,10) bond length is 1.10 Å. In the second C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(13), and one H(15) atom. The C(3)-N(3) bond length is 1.47 Å. The C(3)-H(13) bond length is 1.10 Å. The C(3)-H(15) bond length is 1.11 Å. In the third C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(14), and one H(16) atom. The C(4)-N(4) bond length is 1.47 Å. The C(4)-H(14) bond length is 1.10 Å. The C(4)-H(16) bond length is 1.11 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pb(1); one C(1,2); one H(1,2); and one H(3,4) atom. The N(1)-H(1,2) bond length is 1.03 Å. The N(1)-H(3,4) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Pb(1); one C(1,2); one H(1,2); and one H(3,4) atom. The N(2)-C(1,2) bond length is 1.47 Å. The N(2)-H(1,2) bond length is 1.03 Å. The N(2)-H(3,4) bond length is 1.03 Å. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Pb(1); one C(3); one H(5); and one H(7,8) atom. The N(3)-H(5) bond length is 1.03 Å. The N(3)-H(7,8) bond length is 1.03 Å. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Pb(1); one C(4); one H(6); and one H(7,8) atom. The N(4)-H(6) bond length is 1.03 Å. The N(4)-H(7,8) bond length is 1.03 Å. There are eleven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one N(4) atom. In the fifth H site, H(7,8) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(1,2) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(1,2) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(3) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(3) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(4) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 1-coordinate geometry to one Pb(1) atom. In the second Cl site, Cl(2) is bonded in a 1-coordinate geometry to one Pb(1) atom. Linkers: 4 NCCN. Metal clusters: 2 [Pb]. The MOF has largest included sphere 2.02 A, density 2.50 g/cm3, surface area 3183.30 m2/g, accessible volume 0.10 cm3/g