WCu2C12H18(NS)4(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two WCu2C12H18(NS)4 clusters. In each WCu2C12H18(NS)4 cluster, W(1) is bonded in a distorted tetrahedral geometry to one Cu(1), one Cu(2), one S(1), one S(2), one S(3), and one S(4) atom. The W(1)-Cu(1) bond length is 2.63 Å. The W(1)-Cu(2) bond length is 2.64 Å. The W(1)-S(1) bond length is 2.23 Å. The W(1)-S(2) bond length is 2.23 Å. The W(1)-S(3) bond length is 2.23 Å. The W(1)-S(4) bond length is 2.22 Å. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 3-coordinate geometry to one W(1), one N(1), one S(1), and one S(2) atom. The Cu(1)-N(1) bond length is 1.92 Å. The Cu(1)-S(1) bond length is 2.23 Å. The Cu(1)-S(2) bond length is 2.23 Å. In the second Cu site, Cu(2) is bonded in a 3-coordinate geometry to one W(1), one N(3), one S(3), and one S(4) atom. The Cu(2)-N(3) bond length is 1.92 Å. The Cu(2)-S(3) bond length is 2.23 Å. The Cu(2)-S(4) bond length is 2.23 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one H(1), one H(2), and one H(3) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(4), and one N(1) atom. The C(2)-C(4) bond length is 1.40 Å. The C(2)-N(1) bond length is 1.35 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4), one C(5), and one N(2) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(5) bond length is 1.48 Å. The C(3)-N(2) bond length is 1.36 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2), one C(3), and one H(4) atom. The C(4)-H(4) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one H(5), one H(6), and one H(7) atom. The C(5)-H(5) bond length is 1.10 Å. The C(5)-H(6) bond length is 1.10 Å. The C(5)-H(7) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(8), and one H(9) atom. The C(6)-N(2) bond length is 1.45 Å. The C(6)-H(8) bond length is 1.10 Å. The C(6)-H(9) bond length is 1.10 Å. In the seventh C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(12), one H(13), and one H(14) atom. The C(8)-C(9) bond length is 1.49 Å. The C(8)-H(12) bond length is 1.10 Å. The C(8)-H(13) bond length is 1.10 Å. The C(8)-H(14) bond length is 1.10 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(3) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-N(3) bond length is 1.35 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(15) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(15) bond length is 1.08 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one N(4) atom. The C(11)-C(12) bond length is 1.49 Å. The C(11)-N(4) bond length is 1.36 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one H(16), one H(17), and one H(18) atom. The C(12)-H(16) bond length is 1.09 Å. The C(12)-H(17) bond length is 1.10 Å. The C(12)-H(18) bond length is 1.10 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(19), and one H(20) atom. The C(13)-N(4) bond length is 1.46 Å. The C(13)-H(19) bond length is 1.10 Å. The C(13)-H(20) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(2), and one N(2) atom. The N(1)-N(2) bond length is 1.37 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(6), and one N(1) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(9), and one N(4) atom. The N(3)-N(4) bond length is 1.37 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one N(3) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(8) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(8) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(10) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(12) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(12) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(13) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 2-coordinate geometry to one W(1) and one Cu(1) atom. In the second S site, S(2) is bonded in a 2-coordinate geometry to one W(1) and one Cu(1) atom. In the third S site, S(3) is bonded in a 2-coordinate geometry to one W(1) and one Cu(2) atom. In the fourth S site, S(4) is bonded in a 2-coordinate geometry to one W(1) and one Cu(2) atom. Linkers: 2 Cc1cc(C)n(CCCCn2nc(C)cc2C)n1 ,2 [C][N]N([C][CH2])CCCCn1nc(C)cc1C ,2 [CH2][C]N([N])CCCCn1nc(C)cc1C. Metal clusters: 2 S1[Cu]2S[W]1234S[Cu]3S4. The MOF has largest included sphere 2.17 A, density 2.23 g/cm3, surface area 3482.49 m2/g, accessible volume 0.12 cm3/g