Cd2C14N10H14O7CHCH2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules and four 02329_fluka molecules inside a Cd2C14N10H14O7 framework. In the Cd2C14N10H14O7 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted pentagonal pyramidal geometry to one N(1), one N(6), one O(1), one O(5), one O(6), and one O(7) atom. The Cd(1)-N(1) bond length is 2.28 Å. The Cd(1)-N(6) bond length is 2.34 Å. The Cd(1)-O(1) bond length is 2.29 Å. The Cd(1)-O(5) bond length is 2.40 Å. The Cd(1)-O(6) bond length is 2.46 Å. The Cd(1)-O(7) bond length is 2.34 Å. In the second Cd site, Cd(2) is bonded in a 7-coordinate geometry to one N(10), one N(5), one N(8), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(2)-N(10) bond length is 2.41 Å. The Cd(2)-N(5) bond length is 2.32 Å. The Cd(2)-N(8) bond length is 2.40 Å. The Cd(2)-O(1) bond length is 2.69 Å. The Cd(2)-O(2) bond length is 2.33 Å. The Cd(2)-O(3) bond length is 2.77 Å. The Cd(2)-O(4) bond length is 2.30 Å. There are fourteen inequivalent C sites. In the first C site, C(16) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(16)-O(3) bond length is 1.26 Å. The C(16)-O(4) bond length is 1.28 Å. In the second C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(3), and one N(4) atom. The C(1)-C(2) bond length is 1.46 Å. The C(1)-N(3) bond length is 1.36 Å. The C(1)-N(4) bond length is 1.35 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.41 Å. In the fourth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 1.09 Å. In the fifth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(5), and one H(2) atom. The C(4)-N(5) bond length is 1.35 Å. The C(4)-H(2) bond length is 1.09 Å. In the sixth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(5), and one H(3) atom. The C(5)-C(6) bond length is 1.38 Å. The C(5)-N(5) bond length is 1.35 Å. The C(5)-H(3) bond length is 1.09 Å. In the seventh C site, C(6) is bonded in a distorted trigonal planar geometry to one C(2), one C(5), and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the eighth C site, C(7) is bonded in a distorted water-like geometry to one C(8), one N(8), and one N(9) atom. The C(7)-C(8) bond length is 1.46 Å. The C(7)-N(8) bond length is 1.36 Å. The C(7)-N(9) bond length is 1.34 Å. In the ninth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the tenth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(9)-H(5) bond length is 1.09 Å. In the eleventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(6) atom. The C(10)-N(10) bond length is 1.35 Å. The C(10)-H(6) bond length is 1.09 Å. In the twelfth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(10), and one H(7) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(10) bond length is 1.35 Å. The C(11)-H(7) bond length is 1.09 Å. In the thirteenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(8), and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. In the fourteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(13)-O(1) bond length is 1.28 Å. The C(13)-O(2) bond length is 1.27 Å. There are ten inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one N(2), and one N(4) atom. The N(1)-N(2) bond length is 1.34 Å. The N(1)-N(4) bond length is 1.33 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.33 Å. In the third N site, N(3) is bonded in a water-like geometry to one C(1) and one N(2) atom. In the fourth N site, N(4) is bonded in a water-like geometry to one C(1) and one N(1) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cd(2), one C(4), and one C(5) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cd(1), one N(7), and one N(9) atom. The N(6)-N(7) bond length is 1.32 Å. The N(6)-N(9) bond length is 1.34 Å. In the seventh N site, N(7) is bonded in a water-like geometry to one N(6) and one N(8) atom. The N(7)-N(8) bond length is 1.34 Å. In the eighth N site, N(8) is bonded in a 3-coordinate geometry to one Cd(2), one C(7), and one N(7) atom. In the ninth N site, N(9) is bonded in a distorted water-like geometry to one C(7) and one N(6) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Cd(2), one C(10), and one C(11) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one O(5) atom. The H(12)-O(5) bond length is 0.98 Å. In the tenth H site, H(13) is bonded in a single-bond geometry to one O(6) atom. The H(13)-O(6) bond length is 0.97 Å. In the eleventh H site, H(14) is bonded in a single-bond geometry to one O(7) atom. The H(14)-O(7) bond length is 0.98 Å. In the twelfth H site, H(15) is bonded in a distorted single-bond geometry to one O(4) and one O(5) atom. The H(15)-O(4) bond length is 1.67 Å. The H(15)-O(5) bond length is 1.00 Å. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one O(6) atom. The H(16)-O(6) bond length is 0.99 Å. In the fourteenth H site, H(17) is bonded in a distorted single-bond geometry to one O(3) and one O(7) atom. The H(17)-O(3) bond length is 1.65 Å. The H(17)-O(7) bond length is 1.00 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Cd(1), one Cd(2), and one C(13) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(2) and one C(13) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Cd(2), one C(16), and one H(17) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(16), and one H(15) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Cd(1), one H(12), and one H(15) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Cd(1), one H(13), and one H(16) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Cd(1), one H(14), and one H(17) atom. Linkers: 6 c1cc(C2=NN=N[N]2)ccn1 ,2 [O]C(=O)C[C@H](C([O])=O)[C@@H](CC([O])=O)C([O])=O ,2 c1cc(C2=N[N]N=N2)ccn1. Metal clusters: 4 O.O.O.O=[C]O[Cd]O[C]O[Cd]. The MOF has largest included sphere 5.87 A, density 1.57 g/cm3, surface area 3705.86 m2/g, accessible volume 0.23 cm3/g