ZnC22H20(NO)4(CH)4C2O is Indium-derived structured and crystallizes in the orthorhombic Pccn space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, eight dimethyl ether molecules, and eight ZnC22H20(NO)4 clusters. In each ZnC22H20(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one O(1), and one O(4) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-N(3) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 1.98 Å. The Zn(1)-O(4) bond length is 1.98 Å. There are twenty-two inequivalent C sites. In the first C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9), one N(3), and one H(9) atom. The C(8)-C(9) bond length is 1.38 Å. The C(8)-N(3) bond length is 1.35 Å. The C(8)-H(9) bond length is 1.09 Å. In the second C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(22) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-H(22) bond length is 1.09 Å. In the third C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(10) atom. The C(9)-C(10) bond length is 1.42 Å. The C(9)-H(10) bond length is 1.08 Å. In the fourth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(28) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(28) bond length is 1.51 Å. In the fifth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one N(4) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-N(4) bond length is 1.37 Å. In the sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(23) atom. The C(26)-H(23) bond length is 1.09 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(11) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-H(11) bond length is 1.09 Å. In the eighth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(3), and one H(12) atom. The C(12)-N(3) bond length is 1.35 Å. The C(12)-H(12) bond length is 1.09 Å. In the ninth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(4), and one O(5) atom. The C(28)-O(4) bond length is 1.30 Å. The C(28)-O(5) bond length is 1.25 Å. In the tenth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(13), and one H(14) atom. The C(13)-N(4) bond length is 1.46 Å. The C(13)-H(13) bond length is 1.09 Å. The C(13)-H(14) bond length is 1.10 Å. In the eleventh C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(15), and one H(16) atom. The C(14)-N(4) bond length is 1.46 Å. The C(14)-H(15) bond length is 1.11 Å. The C(14)-H(16) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(1), and one O(2) atom. The C(15)-C(16) bond length is 1.49 Å. The C(15)-O(1) bond length is 1.31 Å. The C(15)-O(2) bond length is 1.25 Å. In the thirteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.40 Å. In the fourteenth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(17) atom. The C(17)-H(17) bond length is 1.09 Å. In the sixteenth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.42 Å. The C(2)-H(2) bond length is 1.09 Å. In the seventeenth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(2) atom. The C(3)-C(4) bond length is 1.42 Å. The C(3)-N(2) bond length is 1.36 Å. In the eighteenth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(3) bond length is 1.09 Å. In the nineteenth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the twentieth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(20) atom. The C(21)-H(20) bond length is 1.09 Å. In the twenty-first C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(5), and one H(6) atom. The C(6)-N(2) bond length is 1.46 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.11 Å. In the twenty-second C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(7), and one H(8) atom. The C(7)-N(2) bond length is 1.46 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(3), one C(6), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(12), and one C(8) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(14) atom. There are twenty inequivalent H sites. In the first H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the twelfth H site, H(23) is bonded in a single-bond geometry to one C(26) atom. In the thirteenth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the fourteenth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the fifteenth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the sixteenth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the seventeenth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the eighteenth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the nineteenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the twentieth H site, H(14) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(15) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(15) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(28) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(28) atom. Linkers: 8 c1cc(N2CCN(c3ccncc3)CC2)ccn1 ,8 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 8 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.01 A, density 1.34 g/cm3, surface area 4805.27 m2/g, accessible volume 0.30 cm3/g