ZnC4NH2O4(CH3)2C8NH5OF2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four C8NH5OF2 clusters, and two ZnC4NH2O4 clusters. In each C8NH5OF2 cluster, there are eight inequivalent C sites. In the first C site, C(5) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(7) atom. The C(5)-C(11) bond length is 1.51 Å. The C(5)-C(3) bond length is 1.40 Å. The C(5)-C(7) bond length is 1.40 Å. In the second C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the third C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(3), and one O(9) atom. The C(11)-N(3) bond length is 1.35 Å. The C(11)-O(9) bond length is 1.25 Å. In the fourth C site, C(19) is bonded in a distorted single-bond geometry to one C(15) and one F(1) atom. The C(19)-C(15) bond length is 1.40 Å. The C(19)-F(1) bond length is 1.36 Å. In the fifth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one C(15), one N(3), one H(11), and one H(9) atom. The C(13)-C(15) bond length is 1.51 Å. The C(13)-N(3) bond length is 1.46 Å. The C(13)-H(11) bond length is 1.10 Å. The C(13)-H(9) bond length is 1.10 Å. In the sixth C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(19) atom. The C(15)-C(17) bond length is 1.40 Å. In the seventh C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one F(3) atom. The C(17)-F(3) bond length is 1.36 Å. In the eighth C site, C(3) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(3)-H(3) bond length is 1.09 Å. N(3) is bonded in a trigonal planar geometry to one C(11), one C(13), and one H(25) atom. The N(3)-H(25) bond length is 1.03 Å. There are five inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(25) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. O(9) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(19) atom. In the second F site, F(3) is bonded in a single-bond geometry to one C(17) atom. In each ZnC4NH2O4 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to one N(1), one O(1), one O(3), one O(5), and one O(8) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 2.00 Å. The Zn(1)-O(3) bond length is 2.49 Å. The Zn(1)-O(5) bond length is 1.97 Å. The Zn(1)-O(8) bond length is 2.00 Å. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to one N(2), one O(2), one O(6), and one O(7) atom. The Zn(2)-N(2) bond length is 2.04 Å. The Zn(2)-O(2) bond length is 2.00 Å. The Zn(2)-O(6) bond length is 1.97 Å. The Zn(2)-O(7) bond length is 2.00 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,2) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1,2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1,2) atom. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(1,2) bond length is 1.09 Å. In the third C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(7,8) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(7,8) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7,8) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(7,8) bond length is 1.09 Å. In the fifth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(21)-O(1) bond length is 1.29 Å. The C(21)-O(3) bond length is 1.27 Å. In the sixth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(22)-O(2) bond length is 1.29 Å. The C(22)-O(4) bond length is 1.26 Å. In the seventh C site, C(25) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(7) atom. The C(25)-O(5) bond length is 1.27 Å. The C(25)-O(7) bond length is 1.27 Å. In the eighth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(8) atom. The C(26)-O(6) bond length is 1.27 Å. The C(26)-O(8) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(10), and one C(2) atom. There are two inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(7,8) is bonded in a single-bond geometry to one C(9) atom. There are eight inequivalent O sites. In the first O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(26) atom. In the second O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the third O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(25) atom. In the fourth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(26) atom. In the fifth O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(21) atom. In the sixth O site, O(2) is bonded in a water-like geometry to one Zn(2) and one C(22) atom. In the seventh O site, O(3) is bonded in a single-bond geometry to one Zn(1) and one C(21) atom. In the eighth O site, O(4) is bonded in a single-bond geometry to one C(22) atom. Linkers: 2 O=C(NCc1c(F)c(F)c(CNC(=O)c2ccncc2)c(F)c1F)c1ccncc1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 2.17 A, density 1.70 g/cm3, surface area 4761.46 m2/g, accessible volume 0.12 cm3/g