MnC40N6H36(O5F2)2(CH3)2(C3H2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules; one 2,3-dimethyl-1,3-butadiene molecule; and one MnC40N6H36(O5F2)2 cluster. In the MnC40N6H36(O5F2)2 cluster, Mn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. Both Mn(1)-O(1) bond lengths are 1.95 Å. Both Mn(1)-O(3) bond lengths are 1.91 Å. Both Mn(1)-O(4) bond lengths are 2.09 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.43 Å. The C(2)-C(6) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one O(3) atom. The C(3)-C(4) bond length is 1.45 Å. The C(3)-O(3) bond length is 1.29 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-C(7) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(10), one C(4), and one N(3) atom. The C(5)-C(10) bond length is 1.41 Å. The C(5)-N(3) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(2), one N(3), and one H(1) atom. The C(6)-N(3) bond length is 1.36 Å. The C(6)-H(1) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(7)-H(2) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one F(1) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-F(1) bond length is 1.37 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(2) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-N(2) bond length is 1.38 Å. In the tenth C site, C(10) is bonded in a single-bond geometry to one C(5), one C(9), and one F(2) atom. The C(10)-F(2) bond length is 1.37 Å. In the eleventh C site, C(11) is bonded in a 4-coordinate geometry to one C(12), one N(3), one H(3), and one H(4) atom. The C(11)-C(12) bond length is 1.52 Å. The C(11)-N(3) bond length is 1.48 Å. The C(11)-H(3) bond length is 1.10 Å. The C(11)-H(4) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a trigonal non-coplanar geometry to one C(11), one H(5), one H(6), and one H(7) atom. The C(12)-H(5) bond length is 1.10 Å. The C(12)-H(6) bond length is 1.10 Å. The C(12)-H(7) bond length is 1.10 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(8), and one H(9) atom. The C(13)-N(2) bond length is 1.46 Å. The C(13)-H(8) bond length is 1.11 Å. The C(13)-H(9) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(10), and one H(11) atom. The C(14)-N(1) bond length is 1.49 Å. The C(14)-H(10) bond length is 1.10 Å. The C(14)-H(11) bond length is 1.10 Å. In the fifteenth C site, C(15) is bonded in a distorted water-like geometry to one N(1) and one H(12) atom. The C(15)-N(1) bond length is 1.49 Å. The C(15)-H(12) bond length is 1.10 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(13), and one H(14) atom. The C(16)-N(2) bond length is 1.45 Å. The C(16)-H(13) bond length is 1.10 Å. The C(16)-H(14) bond length is 1.11 Å. In the seventeenth C site, C(18) is bonded in a trigonal planar geometry to one C(19), one C(23), and one C(24) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(23) bond length is 1.40 Å. The C(18)-C(24) bond length is 1.50 Å. In the eighteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(18) atom. The C(19)-H(18) bond length is 1.09 Å. In the nineteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(21) atom. The C(23)-H(21) bond length is 1.09 Å. In the twentieth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(4), and one O(5) atom. The C(24)-O(4) bond length is 1.28 Å. The C(24)-O(5) bond length is 1.28 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a tetrahedral geometry to one C(14), one C(15), one H(22), and one H(23) atom. The N(1)-H(22) bond length is 1.06 Å. The N(1)-H(23) bond length is 1.09 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(13), one C(16), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(11), one C(5), and one C(6) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the sixteenth H site, H(21) is bonded in a single-bond geometry to one C(23) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one N(1) atom. In the eighteenth H site, H(23) is bonded in a linear geometry to one N(1) and one O(5) atom. The H(23)-O(5) bond length is 1.55 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(24) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(24) and one H(23) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(8) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(10) atom. Linkers: 1 CCN1C=C(C(=O)[O])C(=C2C1=C(F)C(=C([CH]2)F)N1CC[NH2][C@H](C1)C)[O] ,1 CCN1C=C(C(=O)[O])C(=C2[C]1C(=C(N1CC[NH2][C@@H](C1)C)C(=C2)F)F)[O] ,1 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cc2)cc1. Metal clusters: 1 [O][Mn]([O])(O[C]=O)(O[C]=O)(O[C]=O)O[C]=O. The MOF has largest included sphere 2.36 A, density 1.58 g/cm3, surface area 4275.44 m2/g, accessible volume 0.06 cm3/g