Cd3C77N8H51O13CH crystallizes in the monoclinic Cc space group. The structure consists of four 02329_fluka molecules inside a Cd3C77N8H51O13 framework. In the Cd3C77N8H51O13 framework, there are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one O(1), one O(12), one O(13), one O(2), and one O(8) atom. The Cd(1)-N(1) bond length is 2.29 Å. The Cd(1)-O(1) bond length is 2.57 Å. The Cd(1)-O(12) bond length is 2.26 Å. The Cd(1)-O(13) bond length is 2.40 Å. The Cd(1)-O(2) bond length is 2.27 Å. The Cd(1)-O(8) bond length is 2.37 Å. In the second Cd site, Cd(2) is bonded in a 6-coordinate geometry to one N(3), one N(7), one O(10), one O(3), one O(4), and one O(9) atom. The Cd(2)-N(3) bond length is 2.31 Å. The Cd(2)-N(7) bond length is 2.29 Å. The Cd(2)-O(10) bond length is 2.32 Å. The Cd(2)-O(3) bond length is 2.36 Å. The Cd(2)-O(4) bond length is 2.41 Å. The Cd(2)-O(9) bond length is 2.55 Å. In the third Cd site, Cd(3) is bonded in a 5-coordinate geometry to one N(5), one O(13), one O(6), one O(7), and one O(8) atom. The Cd(3)-N(5) bond length is 2.20 Å. The Cd(3)-O(13) bond length is 2.44 Å. The Cd(3)-O(6) bond length is 2.24 Å. The Cd(3)-O(7) bond length is 2.38 Å. The Cd(3)-O(8) bond length is 2.45 Å. There are seventy-seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.29 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(7) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(7) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(8) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(8) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-C(8) bond length is 1.48 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(9) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(9) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(10) atom. The C(7)-H(10) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(5), and one C(9) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.41 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(11) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(11) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(21), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(21) bond length is 1.48 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(12) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(12) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(14) bond length is 1.47 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(13) atom. The C(13)-H(13) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-C(19) bond length is 1.41 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(14) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(14) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(15) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(15) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(20) bond length is 1.49 Å. In the eighteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(16) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(16) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one H(17) atom. The C(19)-H(17) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(3), and one O(4) atom. The C(20)-O(3) bond length is 1.27 Å. The C(20)-O(4) bond length is 1.29 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(10), one C(22), and one C(26) atom. The C(21)-C(22) bond length is 1.41 Å. The C(21)-C(26) bond length is 1.41 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(18) atom. The C(22)-H(18) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(19) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-H(19) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(27) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-C(27) bond length is 1.49 Å. In the twenty-fifth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one C(26), and one H(20) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-H(20) bond length is 1.09 Å. In the twenty-sixth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(21), one C(25), and one H(21) atom. The C(26)-H(21) bond length is 1.09 Å. In the twenty-seventh C site, C(27) is bonded in a bent 120 degrees geometry to one C(24), one O(5), and one O(6) atom. The C(27)-O(5) bond length is 1.25 Å. The C(27)-O(6) bond length is 1.31 Å. In the twenty-eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(7), and one O(8) atom. The C(28)-C(29) bond length is 1.49 Å. The C(28)-O(7) bond length is 1.27 Å. The C(28)-O(8) bond length is 1.29 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(34) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-C(34) bond length is 1.40 Å. In the thirtieth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(22) atom. The C(30)-H(22) bond length is 1.09 Å. In the thirty-first C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(23,24) atom. The C(31)-C(32) bond length is 1.41 Å. The C(31)-H(23,24) bond length is 1.09 Å. In the thirty-second C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(35) atom. The C(32)-C(33) bond length is 1.41 Å. The C(32)-C(35) bond length is 1.48 Å. In the thirty-third C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(23,24) atom. The C(33)-H(23,24) bond length is 1.09 Å. In the thirty-fourth C site, C(34) is bonded in a distorted single-bond geometry to one C(29) and one H(25) atom. The C(34)-H(25) bond length is 1.09 Å. In the thirty-fifth C site, C(35) is bonded in a trigonal planar geometry to one C(32), one C(36), and one C(40) atom. The C(35)-C(36) bond length is 1.40 Å. The C(35)-C(40) bond length is 1.40 Å. In the thirty-sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(35), one C(37), and one H(26) atom. The C(36)-C(37) bond length is 1.40 Å. The C(36)-H(26) bond length is 1.09 Å. In the thirty-seventh C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one C(48) atom. The C(37)-C(38) bond length is 1.40 Å. The C(37)-C(48) bond length is 1.48 Å. In the thirty-eighth C site, C(38) is bonded in a distorted single-bond geometry to one C(37), one C(39), and one H(27) atom. The C(38)-C(39) bond length is 1.40 Å. The C(38)-H(27) bond length is 1.09 Å. In the thirty-ninth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(41) atom. The C(39)-C(40) bond length is 1.40 Å. The C(39)-C(41) bond length is 1.48 Å. In the fortieth C site, C(40) is bonded in a distorted single-bond geometry to one C(35), one C(39), and one H(28) atom. The C(40)-H(28) bond length is 1.09 Å. In the forty-first C site, C(41) is bonded in a trigonal planar geometry to one C(39), one C(42), and one C(46) atom. The C(41)-C(42) bond length is 1.41 Å. The C(41)-C(46) bond length is 1.41 Å. In the forty-second C site, C(42) is bonded in a distorted single-bond geometry to one C(41), one C(43), and one H(29) atom. The C(42)-C(43) bond length is 1.39 Å. The C(42)-H(29) bond length is 1.09 Å. In the forty-third C site, C(43) is bonded in a distorted trigonal planar geometry to one C(42), one C(44), and one H(30) atom. The C(43)-C(44) bond length is 1.40 Å. The C(43)-H(30) bond length is 1.09 Å. In the forty-fourth C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(47) atom. The C(44)-C(45) bond length is 1.40 Å. The C(44)-C(47) bond length is 1.49 Å. In the forty-fifth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(44), one C(46), and one H(31) atom. The C(45)-C(46) bond length is 1.39 Å. The C(45)-H(31) bond length is 1.09 Å. In the forty-sixth C site, C(46) is bonded in a distorted single-bond geometry to one C(41), one C(45), and one H(32) atom. The C(46)-H(32) bond length is 1.09 Å. In the forty-seventh C site, C(47) is bonded in a distorted bent 120 degrees geometry to one C(44), one O(10), and one O(9) atom. The C(47)-O(10) bond length is 1.31 Å. The C(47)-O(9) bond length is 1.25 Å. In the forty-eighth C site, C(48) is bonded in a trigonal planar geometry to one C(37), one C(49), and one C(53) atom. The C(48)-C(49) bond length is 1.41 Å. The C(48)-C(53) bond length is 1.41 Å. In the forty-ninth C site, C(49) is bonded in a distorted single-bond geometry to one C(48) and one H(33) atom. The C(49)-H(33) bond length is 1.09 Å. In the fiftieth C site, C(50) is bonded in a distorted single-bond geometry to one C(51) and one H(34) atom. The C(50)-C(51) bond length is 1.40 Å. The C(50)-H(34) bond length is 1.09 Å. In the fifty-first C site, C(51) is bonded in a trigonal planar geometry to one C(50), one C(52), and one C(54) atom. The C(51)-C(52) bond length is 1.40 Å. The C(51)-C(54) bond length is 1.50 Å. In the fifty-second C site, C(52) is bonded in a distorted trigonal planar geometry to one C(51), one C(53), and one H(35) atom. The C(52)-C(53) bond length is 1.40 Å. The C(52)-H(35) bond length is 1.09 Å. In the fifty-third C site, C(53) is bonded in a distorted trigonal planar geometry to one C(48), one C(52), and one H(36) atom. The C(53)-H(36) bond length is 1.09 Å. In the fifty-fourth C site, C(54) is bonded in a distorted bent 120 degrees geometry to one C(51), one O(11), and one O(12) atom. The C(54)-O(11) bond length is 1.27 Å. The C(54)-O(12) bond length is 1.29 Å. In the fifty-fifth C site, C(55) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(37) atom. The C(55)-N(1) bond length is 1.34 Å. The C(55)-N(2) bond length is 1.35 Å. The C(55)-H(37) bond length is 1.09 Å. In the fifty-sixth C site, C(56) is bonded in a distorted bent 120 degrees geometry to one C(57), one N(1), and one H(38) atom. The C(56)-C(57) bond length is 1.39 Å. The C(56)-N(1) bond length is 1.38 Å. The C(56)-H(38) bond length is 1.08 Å. In the fifty-seventh C site, C(57) is bonded in a distorted single-bond geometry to one C(56), one C(58), and one N(2) atom. The C(57)-C(58) bond length is 1.46 Å. The C(57)-N(2) bond length is 1.39 Å. In the fifty-eighth C site, C(58) is bonded in a trigonal planar geometry to one C(57), one C(59), and one C(63) atom. The C(58)-C(59) bond length is 1.41 Å. The C(58)-C(63) bond length is 1.40 Å. In the fifty-ninth C site, C(59) is bonded in a distorted single-bond geometry to one C(58) and one H(39) atom. The C(59)-H(39) bond length is 1.09 Å. In the sixtieth C site, C(61) is bonded in a distorted single-bond geometry to one C(62) and one H(41) atom. The C(61)-C(62) bond length is 1.40 Å. The C(61)-H(41) bond length is 1.09 Å. In the sixty-first C site, C(62) is bonded in a trigonal planar geometry to one C(61), one C(63), and one C(64) atom. The C(62)-C(63) bond length is 1.40 Å. The C(62)-C(64) bond length is 1.46 Å. In the sixty-second C site, C(63) is bonded in a distorted single-bond geometry to one C(58), one C(62), and one H(42) atom. The C(63)-H(42) bond length is 1.09 Å. In the sixty-third C site, C(64) is bonded in a distorted single-bond geometry to one C(62), one C(65), and one N(3) atom. The C(64)-C(65) bond length is 1.38 Å. The C(64)-N(3) bond length is 1.39 Å. In the sixty-fourth C site, C(65) is bonded in a distorted bent 120 degrees geometry to one C(64), one N(4), and one H(43) atom. The C(65)-N(4) bond length is 1.37 Å. The C(65)-H(43) bond length is 1.08 Å. In the sixty-fifth C site, C(66) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(44) atom. The C(66)-N(3) bond length is 1.33 Å. The C(66)-N(4) bond length is 1.35 Å. The C(66)-H(44) bond length is 1.08 Å. In the sixty-sixth C site, C(67) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(45) atom. The C(67)-N(5) bond length is 1.34 Å. The C(67)-N(6) bond length is 1.35 Å. The C(67)-H(45) bond length is 1.09 Å. In the sixty-seventh C site, C(68) is bonded in a distorted bent 120 degrees geometry to one C(69), one N(5), and one H(46) atom. The C(68)-C(69) bond length is 1.39 Å. The C(68)-N(5) bond length is 1.38 Å. The C(68)-H(46) bond length is 1.08 Å. In the sixty-eighth C site, C(69) is bonded in a distorted single-bond geometry to one C(68), one C(70), and one N(6) atom. The C(69)-C(70) bond length is 1.46 Å. The C(69)-N(6) bond length is 1.39 Å. In the sixty-ninth C site, C(70) is bonded in a trigonal planar geometry to one C(69), one C(71), and one C(75) atom. The C(70)-C(71) bond length is 1.41 Å. The C(70)-C(75) bond length is 1.40 Å. In the seventieth C site, C(71) is bonded in a distorted trigonal planar geometry to one C(70), one C(72), and one H(47) atom. The C(71)-C(72) bond length is 1.39 Å. The C(71)-H(47) bond length is 1.09 Å. In the seventy-first C site, C(72) is bonded in a distorted trigonal planar geometry to one C(71), one C(73), and one H(48) atom. The C(72)-C(73) bond length is 1.39 Å. The C(72)-H(48) bond length is 1.09 Å. In the seventy-second C site, C(73) is bonded in a distorted single-bond geometry to one C(72), one C(74), and one H(49) atom. The C(73)-C(74) bond length is 1.40 Å. The C(73)-H(49) bond length is 1.09 Å. In the seventy-third C site, C(74) is bonded in a trigonal planar geometry to one C(73), one C(75), and one C(76) atom. The C(74)-C(75) bond length is 1.40 Å. The C(74)-C(76) bond length is 1.46 Å. In the seventy-fourth C site, C(75) is bonded in a distorted single-bond geometry to one C(70), one C(74), and one H(50) atom. The C(75)-H(50) bond length is 1.09 Å. In the seventy-fifth C site, C(76) is bonded in a distorted trigonal planar geometry to one C(74), one C(77), and one N(7) atom. The C(76)-C(77) bond length is 1.38 Å. The C(76)-N(7) bond length is 1.39 Å. In the seventy-sixth C site, C(77) is bonded in a distorted bent 120 degrees geometry to one C(76), one N(8), and one H(51) atom. The C(77)-N(8) bond length is 1.37 Å. The C(77)-H(51) bond length is 1.08 Å. In the seventy-seventh C site, C(78) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(52) atom. The C(78)-N(7) bond length is 1.33 Å. The C(78)-N(8) bond length is 1.35 Å. The C(78)-H(52) bond length is 1.08 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(55), and one C(56) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(55), one C(57), and one H(1) atom. The N(2)-H(1) bond length is 1.05 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(64), and one C(66) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(65), one C(66), and one H(2) atom. The N(4)-H(2) bond length is 1.03 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cd(3), one C(67), and one C(68) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(67), one C(69), and one H(3) atom. The N(6)-H(3) bond length is 1.05 Å. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(76), and one C(78) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(77), one C(78), and one H(4) atom. The N(8)-H(4) bond length is 1.04 Å. There are fifty inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one N(2) and one O(4) atom. The H(1)-O(4) bond length is 1.64 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one N(6) and one O(10) atom. The H(3)-O(10) bond length is 1.62 Å. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one N(8) and one O(6) atom. The H(4)-O(6) bond length is 1.69 Å. In the fifth H site, H(5) is bonded in a distorted linear geometry to one O(11) and one O(13) atom. The H(5)-O(11) bond length is 1.45 Å. The H(5)-O(13) bond length is 1.07 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(13) atom. The H(6)-O(13) bond length is 0.97 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(30) atom. In the twenty-third H site, H(23,24) is bonded in a single-bond geometry to one C(31) atom. In the twenty-fourth H site, H(25) is bonded in a single-bond geometry to one C(34) atom. In the twenty-fifth H site, H(26) is bonded in a single-bond geometry to one C(36) atom. In the twenty-sixth H site, H(27) is bonded in a single-bond geometry to one C(38) atom. In the twenty-seventh H site, H(28) is bonded in a single-bond geometry to one C(40) atom. In the twenty-eighth H site, H(29) is bonded in a single-bond geometry to one C(42) atom. In the twenty-ninth H site, H(30) is bonded in a single-bond geometry to one C(43) atom. In the thirtieth H site, H(31) is bonded in a single-bond geometry to one C(45) atom. In the thirty-first H site, H(32) is bonded in a single-bond geometry to one C(46) atom. In the thirty-second H site, H(33) is bonded in a single-bond geometry to one C(49) atom. In the thirty-third H site, H(34) is bonded in a single-bond geometry to one C(50) atom. In the thirty-fourth H site, H(35) is bonded in a single-bond geometry to one C(52) atom. In the thirty-fifth H site, H(36) is bonded in a single-bond geometry to one C(53) atom. In the thirty-sixth H site, H(37) is bonded in a single-bond geometry to one C(55) atom. In the thirty-seventh H site, H(38) is bonded in a single-bond geometry to one C(56) atom. In the thirty-eighth H site, H(39) is bonded in a single-bond geometry to one C(59) atom. In the thirty-ninth H site, H(41) is bonded in a single-bond geometry to one C(61) atom. In the fortieth H site, H(42) is bonded in a single-bond geometry to one C(63) atom. In the forty-first H site, H(43) is bonded in a single-bond geometry to one C(65) atom. In the forty-second H site, H(44) is bonded in a single-bond geometry to one C(66) atom. In the forty-third H site, H(45) is bonded in a single-bond geometry to one C(67) atom. In the forty-fourth H site, H(46) is bonded in a single-bond geometry to one C(68) atom. In the forty-fifth H site, H(47) is bonded in a single-bond geometry to one C(71) atom. In the forty-sixth H site, H(48) is bonded in a single-bond geometry to one C(72) atom. In the forty-seventh H site, H(49) is bonded in a single-bond geometry to one C(73) atom. In the forty-eighth H site, H(50) is bonded in a single-bond geometry to one C(75) atom. In the forty-ninth H site, H(51) is bonded in a single-bond geometry to one C(77) atom. In the fiftieth H site, H(52) is bonded in a single-bond geometry to one C(78) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Cd(2) and one C(20) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Cd(2), one C(20), and one H(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(27) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Cd(3), one C(27), and one H(4) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Cd(3) and one C(28) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(3), and one C(28) atom. In the ninth O site, O(9) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(47) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Cd(2), one C(47), and one H(3) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one C(54) and one H(5) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(54) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one Cd(1), one Cd(3), one H(5), and one H(6) atom. Linkers: 2 [O]C(=O)c1ccc(-c2cc(-c3ccc([C]4O[Cd](OC(=O)c5ccc(-c6cc(-c7ccc(C([O])=O)cc7)cc(-c7ccc(C([O])=O)cc7)c6)cc5)(N5[CH]NC=C5c5cccc(-c6cnc[nH]6)c5)(N5[CH]NC=C5c5cccc(-c6cnc[nH]6)c5)O4)cc3)cc(-c3ccc(C([O])=O)cc3)c2)cc1 ,1 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C([O])=O)cc3)c2)cc1 ,1 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C(=O)O[Cd]4(N5[CH]NC=C5c5cccc(-c6cnc[nH]6)c5)(N5[CH]NC=C5c5cccc(-c6cnc[nH]6)c5)O[C]O4)cc3)c2)cc1 ,1 [O]C(=O)c1ccc(-c2cc(-c3c[c]c([C]=O)cc3)cc(-c3ccc(C(=O)O[Cd]4(N5[CH]NC=C5c5cccc(-c6cnc[nH]6)c5)(N5[CH]NC=C5c5cccc(-c6cnc[nH]6)c5)O[C](c5ccc(-c6cc(-c7ccc(C([O])=O)cc7)cc(-c7ccc(C([O])=O)cc7)c6)cc5)O4)cc3)c2)cc1 ,1 [C]/C=C(\[CH])c1cc(-c2ccc(C([O])=O)cc2)cc(-c2ccc(C(=O)O[Cd]3(N4[CH]NC=C4c4cccc(-c5cnc[nH]5)c4)(N4[CH]NC=C4c4cccc(-c5cnc[nH]5)c4)O[C](c4ccc(-c5cc(-c6ccc(C([O])=O)cc6)cc(-c6ccc(C([O])=O)cc6)c5)cc4)O3)cc2)c1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 5.39 A, density 1.47 g/cm3, surface area 4273.38 m2/g, accessible volume 0.19 cm3/g