Cd3C24H18(N2O7)2(CH)2(C2NH2S)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two C2NH2S clusters, and one Cd3C24H18(N2O7)2 cluster. In each C2NH2S cluster, there are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(3), and one S(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(3) bond length is 1.34 Å. The C(1)-S(1) bond length is 1.74 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(2) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-S(2) bond length is 1.74 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one N(2), one N(3), and one S(3) atom. The C(3)-N(2) bond length is 1.35 Å. The C(3)-N(3) bond length is 1.34 Å. The C(3)-S(3) bond length is 1.74 Å. In the fourth C site, C(4) is bonded in a distorted water-like geometry to one H(1), one H(2), and one S(1) atom. The C(4)-H(1) bond length is 1.10 Å. The C(4)-H(2) bond length is 1.09 Å. The C(4)-S(1) bond length is 1.82 Å. In the fifth C site, C(6) is bonded in a distorted water-like geometry to one H(3), one H(4), and one S(2) atom. The C(6)-H(3) bond length is 1.10 Å. The C(6)-H(4) bond length is 1.10 Å. The C(6)-S(2) bond length is 1.81 Å. In the sixth C site, C(8) is bonded in a distorted water-like geometry to one H(5), one H(6), and one S(3) atom. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.09 Å. The C(8)-S(3) bond length is 1.81 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(3) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(1) and one C(4) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(2) and one C(6) atom. In the third S site, S(3) is bonded in a water-like geometry to one C(3) and one C(8) atom. In the Cd3C24H18(N2O7)2 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form corner-sharing CdO6 octahedra. The corner-sharing octahedral tilt angles are 77°. Both Cd(1)-O(1) bond lengths are 2.23 Å. Both Cd(1)-O(3) bond lengths are 2.33 Å. Both Cd(1)-O(5) bond lengths are 2.35 Å. In the second Cd site, Cd(2) is bonded to one N(4), one N(5), one O(2), one O(4), one O(5), and one O(7) atom to form distorted corner-sharing CdN2O4 octahedra. The corner-sharing octahedral tilt angles are 77°. The Cd(2)-N(4) bond length is 2.37 Å. The Cd(2)-N(5) bond length is 2.33 Å. The Cd(2)-O(2) bond length is 2.29 Å. The Cd(2)-O(4) bond length is 2.32 Å. The Cd(2)-O(5) bond length is 2.36 Å. The Cd(2)-O(7) bond length is 2.53 Å. There are twelve inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(5)-O(1) bond length is 1.27 Å. The C(5)-O(2) bond length is 1.26 Å. In the second C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(7)-O(3) bond length is 1.26 Å. The C(7)-O(4) bond length is 1.28 Å. In the third C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(9)-O(5) bond length is 1.29 Å. The C(9)-O(6) bond length is 1.26 Å. In the fourth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one N(4), and one H(7) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-N(4) bond length is 1.34 Å. The C(10)-H(7) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(11)-H(8) bond length is 1.09 Å. In the sixth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(10) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-H(10) bond length is 1.09 Å. In the seventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one N(4) atom. The C(14)-C(15) bond length is 1.49 Å. The C(14)-N(4) bond length is 1.35 Å. In the eighth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one N(5) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-N(5) bond length is 1.35 Å. In the ninth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(11) atom. The C(16)-H(11) bond length is 1.09 Å. In the tenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(12) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(12) bond length is 1.09 Å. In the eleventh C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(13) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(13) bond length is 1.09 Å. In the twelfth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(5), and one H(14) atom. The C(19)-N(5) bond length is 1.34 Å. The C(19)-H(14) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Cd(2), one C(10), and one C(14) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Cd(2), one C(15), and one C(19) atom. There are nine inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one O(7) atom. The H(15)-O(7) bond length is 0.97 Å. In the ninth H site, H(16) is bonded in a distorted linear geometry to one O(6) and one O(7) atom. The H(16)-O(6) bond length is 1.61 Å. The H(16)-O(7) bond length is 1.01 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(5) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one C(5) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Cd(2) and one C(7) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Cd(1), one Cd(2), and one C(9) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one C(9) and one H(16) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Cd(2), one H(15), and one H(16) atom. Linkers: 2 [O]C(=O)CSC1=NC(=[N]=C([N]1)SCC(=O)[O])SCC(=O)[O]. Metal clusters: 1 O.O.O=[C]O[Cd]12(O[C]=O)(O[C]O[Cd]O[C]O1)O[C]O[Cd]O[C]O2. RCSR code: kgd. The MOF has largest included sphere 3.29 A, density 1.95 g/cm3, surface area 3730.33 m2/g, accessible volume 0.12 cm3/g