CH2CuC4H9S2IC3NH4O is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; four n,n-dimethylformamide molecules; and two CuC4H9S2I clusters. In each CuC4H9S2I cluster, Cu(1) is bonded to one S(1), one S(2), and two equivalent I(1) atoms to form distorted edge-sharing CuS2I2 tetrahedra. The Cu(1)-S(1) bond length is 2.29 Å. The Cu(1)-S(2) bond length is 2.31 Å. There is one shorter (2.62 Å) and one longer (2.70 Å) Cu(1)-I(1) bond length. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.80 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one H(4), one H(5), and one S(1) atom. The C(2)-H(4) bond length is 1.10 Å. The C(2)-H(5) bond length is 1.10 Å. The C(2)-S(1) bond length is 1.81 Å. In the third C site, C(6) is bonded in a distorted water-like geometry to one H(10), one H(11), and one S(2) atom. The C(6)-H(10) bond length is 1.10 Å. The C(6)-H(11) bond length is 1.10 Å. The C(6)-S(2) bond length is 1.82 Å. In the fourth C site, C(7) is bonded in a distorted water-like geometry to one H(12), one H(13), and one S(2) atom. The C(7)-H(12) bond length is 1.10 Å. The C(7)-H(13) bond length is 1.10 Å. The C(7)-S(2) bond length is 1.82 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(1), and one C(2) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(6), and one C(7) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 4 [C]SCCC(=O)N1CCSCC1. Metal clusters: 2 [CH2][S](C)[Cu](I)[Cu](I)[S]([CH2])C. The MOF has largest included sphere 2.28 A, density 2.15 g/cm3, surface area 3678.94 m2/g, accessible volume 0.11 cm3/g