CuC17H13(NO)4CH is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and four CuC17H13(NO)4 clusters. In each CuC17H13(NO)4 cluster, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one O(1), and one O(3) atom. The Cu(1)-N(1) bond length is 2.00 Å. The Cu(1)-N(2) bond length is 1.99 Å. The Cu(1)-O(1) bond length is 1.98 Å. The Cu(1)-O(3) bond length is 1.97 Å. There are seventeen inequivalent C sites. In the first C site, C(18) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(18)-O(3) bond length is 1.29 Å. The C(18)-O(4) bond length is 1.24 Å. In the second C site, C(1) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one N(1) atom. The C(1)-C(10) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.42 Å. The C(1)-N(1) bond length is 1.39 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one C(11), one C(7), and one N(2) atom. The C(2)-C(11) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.42 Å. The C(2)-N(2) bond length is 1.39 Å. In the fourth C site, C(3) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(1) atom. The C(3)-N(2) bond length is 1.33 Å. The C(3)-N(3) bond length is 1.36 Å. The C(3)-H(1) bond length is 1.09 Å. In the fifth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(13), one C(6), and one H(2) atom. The C(4)-C(13) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.40 Å. The C(4)-H(2) bond length is 1.09 Å. In the sixth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(15), one C(7), and one H(3) atom. The C(5)-C(15) bond length is 1.39 Å. The C(5)-C(7) bond length is 1.40 Å. The C(5)-H(3) bond length is 1.09 Å. In the seventh C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(4), and one N(4) atom. The C(6)-N(4) bond length is 1.39 Å. In the eighth C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one N(3) atom. The C(7)-N(3) bond length is 1.39 Å. In the ninth C site, C(8) is bonded in a trigonal planar geometry to one N(1), one N(4), and one H(4) atom. The C(8)-N(1) bond length is 1.33 Å. The C(8)-N(4) bond length is 1.36 Å. The C(8)-H(4) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(1), one C(14), and one H(6) atom. The C(10)-C(14) bond length is 1.39 Å. The C(10)-H(6) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(2) and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(8), and one H(9) atom. The C(12)-N(4) bond length is 1.45 Å. The C(12)-H(8) bond length is 1.10 Å. The C(12)-H(9) bond length is 1.10 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(14), one C(4), and one H(10) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(10), one C(13), and one H(11) atom. The C(14)-H(11) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(5) and one H(12) atom. The C(15)-H(12) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(3) and two equivalent H(13,14) atoms. The C(16)-N(3) bond length is 1.45 Å. Both C(16)-H(13,14) bond lengths are 1.10 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(17)-O(1) bond length is 1.29 Å. The C(17)-O(2) bond length is 1.24 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(2), and one C(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(16), one C(3), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(12), one C(6), and one C(8) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(13,14) is bonded in a single-bond geometry to one C(16) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(17) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(17) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cu(1) and one C(18) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(18) atom. Linkers: 8 [O]C(=O)Cn1cnc2ccccc21. Metal clusters: 4 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 4.18 A, density 1.41 g/cm3, surface area 4298.58 m2/g, accessible volume 0.23 cm3/g