LuC11N5H12O12(CH)6(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, eight 02329_fluka molecules, and two LuC11N5H12O12 clusters. In each LuC11N5H12O12 cluster, Lu(1) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(12), one O(2), one O(3), one O(5), one O(6), one O(8), and one O(9) atom. The Lu(1)-O(1) bond length is 2.19 Å. The Lu(1)-O(11) bond length is 2.37 Å. The Lu(1)-O(12) bond length is 2.33 Å. The Lu(1)-O(2) bond length is 2.21 Å. The Lu(1)-O(3) bond length is 2.54 Å. The Lu(1)-O(5) bond length is 2.40 Å. The Lu(1)-O(6) bond length is 2.50 Å. The Lu(1)-O(8) bond length is 2.35 Å. The Lu(1)-O(9) bond length is 2.36 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one O(1) atom. The C(1)-C(6) bond length is 1.44 Å. The C(1)-O(1) bond length is 1.30 Å. In the second C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(7) atom. The C(5)-C(6) bond length is 1.42 Å. The C(5)-H(7) bond length is 1.09 Å. In the third C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.41 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one H(8) atom. The C(7)-N(1) bond length is 1.31 Å. The C(7)-H(8) bond length is 1.09 Å. In the fifth C site, C(8) is bonded in a distorted water-like geometry to one N(1) and one H(9) atom. The C(8)-N(1) bond length is 1.46 Å. The C(8)-H(9) bond length is 1.10 Å. In the sixth C site, C(13) is bonded in a distorted water-like geometry to one N(2) and one H(18) atom. The C(13)-N(2) bond length is 1.46 Å. The C(13)-H(18) bond length is 1.10 Å. In the seventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(2), and one H(19) atom. The C(14)-C(15) bond length is 1.42 Å. The C(14)-N(2) bond length is 1.31 Å. The C(14)-H(19) bond length is 1.09 Å. In the eighth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(20) atom. The C(15)-C(16) bond length is 1.42 Å. The C(15)-C(20) bond length is 1.44 Å. In the ninth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(20) atom. The C(16)-H(20) bond length is 1.09 Å. In the tenth C site, C(20) is bonded in a distorted single-bond geometry to one C(15) and one O(2) atom. The C(20)-O(2) bond length is 1.31 Å. In the eleventh C site, C(21) is bonded in a tetrahedral geometry to one H(24), one H(25), one H(26), and one O(12) atom. The C(21)-H(24) bond length is 1.09 Å. The C(21)-H(25) bond length is 1.10 Å. The C(21)-H(26) bond length is 1.10 Å. The C(21)-O(12) bond length is 1.44 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(7), one C(8), and one H(2) atom. The N(1)-H(2) bond length is 1.03 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(13), one C(14), and one H(3) atom. The N(2)-H(3) bond length is 1.03 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. The N(3)-O(3) bond length is 1.27 Å. The N(3)-O(4) bond length is 1.25 Å. The N(3)-O(5) bond length is 1.28 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one O(6), one O(7), and one O(8) atom. The N(4)-O(6) bond length is 1.28 Å. The N(4)-O(7) bond length is 1.23 Å. The N(4)-O(8) bond length is 1.30 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one O(10), one O(11), and one O(9) atom. The N(5)-O(10) bond length is 1.23 Å. The N(5)-O(11) bond length is 1.29 Å. The N(5)-O(9) bond length is 1.29 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(12) atom. The H(1)-O(12) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(20) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(24) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(25) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(26) is bonded in a single-bond geometry to one C(21) atom. There are twelve inequivalent O sites. In the first O site, O(12) is bonded in a 3-coordinate geometry to one Lu(1), one C(21), and one H(1) atom. In the second O site, O(1) is bonded in a bent 150 degrees geometry to one Lu(1) and one C(1) atom. In the third O site, O(2) is bonded in a bent 150 degrees geometry to one Lu(1) and one C(20) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to one Lu(1) and one N(3) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one N(3) atom. In the sixth O site, O(5) is bonded in a distorted water-like geometry to one Lu(1) and one N(3) atom. In the seventh O site, O(6) is bonded in a distorted single-bond geometry to one Lu(1) and one N(4) atom. In the eighth O site, O(7) is bonded in a single-bond geometry to one N(4) atom. In the ninth O site, O(8) is bonded in a distorted water-like geometry to one Lu(1) and one N(4) atom. In the tenth O site, O(9) is bonded in a distorted L-shaped geometry to one Lu(1) and one N(5) atom. In the eleventh O site, O(10) is bonded in a single-bond geometry to one N(5) atom. In the twelfth O site, O(11) is bonded in a distorted L-shaped geometry to one Lu(1) and one N(5) atom. Linkers: 2 [O][N+](=O)[O-]. Metal clusters: 2 CO.[O]N1O[Lu]([O])([O])(O[N+](=O)[O-])O1.[O][N+](=O)[O-]. The MOF has largest included sphere 3.17 A, density 1.81 g/cm3, surface area 3801.90 m2/g, accessible volume 0.12 cm3/g