VC8H4O5(CH2)2C2H4S crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of eight 02329_fluka molecules and four dimethyl sulfide molecules inside a VC8H4O5 framework. In the VC8H4O5 framework, V(1) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form distorted corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 49°. The V(1)-O(2) bond length is 1.98 Å. The V(1)-O(3) bond length is 1.97 Å. The V(1)-O(4) bond length is 1.97 Å. The V(1)-O(5) bond length is 1.98 Å. There is one shorter (1.64 Å) and one longer (2.09 Å) V(1)-O(1) bond length. There are eight inequivalent C sites. In the first C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one H(2) atom. The C(4)-C(3) bond length is 1.39 Å. The C(4)-C(7) bond length is 1.40 Å. The C(4)-H(2) bond length is 1.09 Å. In the second C site, C(5) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(3) atom. The C(5)-C(2) bond length is 1.40 Å. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(3) bond length is 1.09 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(4) atom. The C(6)-C(7) bond length is 1.41 Å. The C(6)-H(4) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(7)-C(8) bond length is 1.48 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(2), and one O(4) atom. The C(8)-O(2) bond length is 1.28 Å. The C(8)-O(4) bond length is 1.28 Å. In the sixth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(5) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(3) bond length is 1.28 Å. The C(1)-O(5) bond length is 1.28 Å. In the seventh C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(5) atom. The C(2)-C(3) bond length is 1.40 Å. In the eighth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one V(1) and one C(8) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to one V(1) and one C(1) atom. In the fourth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one C(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one V(1) and one C(8) atom. Linkers: 4 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 4 [V]. RCSR code: lvt. The MOF has largest included sphere 3.24 A, density 1.44 g/cm3, surface area 4651.74 m2/g, accessible volume 0.22 cm3/g