Cd3C32H22(N2O3)4(CH)6(CH2)8(CH3)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, eight 02329_fluka molecules, six 02329_fluka molecules, and one Cd3C32H22(N2O3)4 cluster. In the Cd3C32H22(N2O3)4 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one N(1), one O(1), one O(2), one O(3), one O(4), and one O(6) atom to form distorted corner-sharing CdNO5 pentagonal pyramids. The corner-sharing octahedral tilt angles are 55°. The Cd(1)-N(1) bond length is 2.29 Å. The Cd(1)-O(1) bond length is 2.45 Å. The Cd(1)-O(2) bond length is 2.37 Å. The Cd(1)-O(3) bond length is 2.51 Å. The Cd(1)-O(4) bond length is 2.37 Å. The Cd(1)-O(6) bond length is 2.27 Å. In the second Cd site, Cd(2) is bonded to two equivalent N(3), two equivalent O(4), and two equivalent O(5) atoms to form corner-sharing CdN2O4 octahedra. Both Cd(2)-N(3) bond lengths are 2.27 Å. Both Cd(2)-O(4) bond lengths are 2.42 Å. Both Cd(2)-O(5) bond lengths are 2.34 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one N(2) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.42 Å. The C(1)-N(2) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one N(1) atom. The C(6)-N(1) bond length is 1.39 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(5) atom. The C(7)-N(1) bond length is 1.33 Å. The C(7)-N(2) bond length is 1.36 Å. The C(7)-H(5) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(6), and one H(7) atom. The C(8)-N(2) bond length is 1.46 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-H(7) bond length is 1.10 Å. In the seventh C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(16), and one H(17) atom. The C(13)-N(4) bond length is 1.46 Å. The C(13)-H(16) bond length is 1.10 Å. The C(13)-H(17) bond length is 1.10 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(15), one C(19), and one N(4) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(19) bond length is 1.42 Å. The C(14)-N(4) bond length is 1.39 Å. In the ninth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(18) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(18) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(19) atom. The C(16)-H(19) bond length is 1.09 Å. In the eleventh C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(21) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-H(21) bond length is 1.09 Å. In the twelfth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one N(3) atom. The C(19)-N(3) bond length is 1.39 Å. In the thirteenth C site, C(20) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(22) atom. The C(20)-N(3) bond length is 1.33 Å. The C(20)-N(4) bond length is 1.36 Å. The C(20)-H(22) bond length is 1.08 Å. In the fourteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(22)-O(1) bond length is 1.27 Å. The C(22)-O(2) bond length is 1.28 Å. In the fifteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(24)-O(3) bond length is 1.26 Å. The C(24)-O(4) bond length is 1.29 Å. In the sixteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(26)-O(5) bond length is 1.27 Å. The C(26)-O(6) bond length is 1.28 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(6), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(7), and one C(8) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(19), and one C(20) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(20) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(21) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(22) is bonded in a single-bond geometry to one C(20) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(24) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(24) atom. In the third O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Cd(2) and one C(26) atom. In the fourth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(26) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(22) atom. In the sixth O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(22) atom. Linkers: 2 c1ccc2c(c1)ncn2CCCCCCn1cnc2ccccc21. Metal clusters: 3 [Cd]. The MOF has largest included sphere 2.08 A, density 1.72 g/cm3, surface area 4623.26 m2/g, accessible volume 0.10 cm3/g