CdC13N11H8(CH)5 crystallizes in the monoclinic Cc space group. The structure consists of twenty 02329_fluka molecules inside a CdC13N11H8 framework. In the CdC13N11H8 framework, Cd(1) is bonded to one N(2), one N(5), two equivalent N(6), and two equivalent N(9) atoms to form edge-sharing CdN6 octahedra. The Cd(1)-N(2) bond length is 2.44 Å. The Cd(1)-N(5) bond length is 2.38 Å. There is one shorter (2.35 Å) and one longer (2.39 Å) Cd(1)-N(6) bond length. There is one shorter (2.34 Å) and one longer (2.49 Å) Cd(1)-N(9) bond length. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(5), one C(6), and one N(1) atom. The C(1)-C(5) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.47 Å. The C(1)-N(1) bond length is 1.35 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one N(2), and one N(4) atom. The C(6)-N(2) bond length is 1.33 Å. The C(6)-N(4) bond length is 1.38 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(13), one N(3), and one N(4) atom. The C(7)-C(13) bond length is 1.46 Å. The C(7)-N(3) bond length is 1.33 Å. The C(7)-N(4) bond length is 1.38 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(12), one C(9), and one N(4) atom. The C(8)-C(12) bond length is 1.39 Å. The C(8)-C(9) bond length is 1.39 Å. The C(8)-N(4) bond length is 1.43 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(9)-H(5) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(6) atom. The C(10)-N(5) bond length is 1.35 Å. The C(10)-H(6) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(5), and one H(7) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(5) bond length is 1.34 Å. The C(11)-H(7) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(8), and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(7) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(18) bond length is 1.41 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(9) atom. The C(14)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(13) atom. The C(18)-H(13) bond length is 1.09 Å. There are eleven inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Cd(1), one C(6), and one N(3) atom. The N(2)-N(3) bond length is 1.37 Å. In the third N site, N(3) is bonded in a distorted single-bond geometry to one C(7) and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(6), one C(7), and one C(8) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(11) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to two equivalent Cd(1) and one N(7) atom. The N(6)-N(7) bond length is 1.21 Å. In the seventh N site, N(7) is bonded in a linear geometry to one N(6) and one N(8) atom. The N(7)-N(8) bond length is 1.16 Å. In the eighth N site, N(8) is bonded in a single-bond geometry to one N(7) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to two equivalent Cd(1) and one N(10) atom. The N(9)-N(10) bond length is 1.21 Å. In the tenth N site, N(10) is bonded in a linear geometry to one N(11) and one N(9) atom. The N(10)-N(11) bond length is 1.17 Å. In the eleventh N site, N(11) is bonded in a single-bond geometry to one N(10) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. Linkers: 2 c1ccc(-c2nnc(-c3ccccn3)n2-c2ccncc2)cc1 ,1 [c]1[c]cc(-c2nnc(-c3ccccn3)n2-c2ccncc2)cc1 ,1 [c]1[c]nc(-c2nnc(-c3ccccc3)n2-c2ccncc2)cc1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 2.06 A, density 1.79 g/cm3, surface area 4300.73 m2/g, accessible volume 0.15 cm3/g