(CH)5CuC9NH10SOI is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of forty 02329_fluka molecules and four CuC9NH10SOI clusters. In each CuC9NH10SOI cluster, Cu(1) is bonded in a 4-coordinate geometry to one N(1), one S(1), one I(1), and one I(2) atom. The Cu(1)-N(1) bond length is 2.05 Å. The Cu(1)-S(1) bond length is 2.28 Å. The Cu(1)-I(1) bond length is 2.63 Å. The Cu(1)-I(2) bond length is 2.67 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(1) atom. The C(1)-C(5) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(1) and one O(1) atom. The C(5)-O(1) bond length is 1.37 Å. In the fourth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(6), and one O(1) atom. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. The C(6)-O(1) bond length is 1.45 Å. In the fifth C site, C(7) is bonded in a distorted water-like geometry to one H(7), one H(8), and one S(1) atom. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.10 Å. The C(7)-S(1) bond length is 1.81 Å. In the sixth C site, C(8) is bonded in a distorted water-like geometry to one C(9), one H(10), one H(9), and one S(1) atom. The C(8)-C(9) bond length is 1.50 Å. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. The C(8)-S(1) bond length is 1.83 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.40 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(11) atom. The C(10)-H(11) bond length is 1.09 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(15) atom. The C(14)-H(15) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. S(1) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(7), and one C(8) atom. O(1) is bonded in a bent 120 degrees geometry to one C(5) and one C(6) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. In the second I site, I(2) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 4 c1ccc(CSCCOc2cccnc2)cc1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 2.26 A, density 2.01 g/cm3, surface area 3899.43 m2/g, accessible volume 0.08 cm3/g