CdC16N3H14O4(CH)6(CH2)2C6H5NH is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four 02329_fluka molecules, two 4-methylpyridine molecules, two isobutylene molecules, and two CdC16N3H14O4 clusters. In each CdC16N3H14O4 cluster, Cd(1) is bonded in a pentagonal bipyramidal geometry to one N(1), one N(2), one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.42 Å. The Cd(1)-N(2) bond length is 2.38 Å. The Cd(1)-N(3) bond length is 2.40 Å. The Cd(1)-O(1) bond length is 2.44 Å. The Cd(1)-O(2) bond length is 2.41 Å. The Cd(1)-O(3) bond length is 2.49 Å. The Cd(1)-O(4) bond length is 2.40 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(3)-O(3) bond length is 1.28 Å. The C(3)-O(4) bond length is 1.28 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(3) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(4) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(4) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(15), one C(6), and one C(8) atom. The C(7)-C(15) bond length is 1.50 Å. The C(7)-C(8) bond length is 1.40 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one N(1) and one H(6) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-H(6) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7,10) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(7,10) bond length is 1.09 Å. In the ninth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7,10) atom. The C(14)-N(2) bond length is 1.35 Å. The C(14)-H(7,10) bond length is 1.09 Å. In the tenth C site, C(15) is bonded in a distorted water-like geometry to one C(7), one H(11), and one H(12) atom. The C(15)-H(11) bond length is 1.10 Å. The C(15)-H(12) bond length is 1.10 Å. In the eleventh C site, C(18) is bonded in a distorted trigonal planar geometry to one C(19), one N(3), and one H(17) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-N(3) bond length is 1.34 Å. The C(18)-H(17) bond length is 1.09 Å. In the twelfth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(18) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(18) bond length is 1.09 Å. In the thirteenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(28) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(28) bond length is 1.51 Å. In the fourteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one H(19) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(19) bond length is 1.09 Å. In the fifteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one N(3), and one H(20) atom. The C(22)-N(3) bond length is 1.35 Å. The C(22)-H(20) bond length is 1.09 Å. In the sixteenth C site, C(28) is bonded in a distorted water-like geometry to one C(20), one H(25), and one H(26) atom. The C(28)-H(25) bond length is 1.11 Å. The C(28)-H(26) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(5), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(14) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(18), and one C(22) atom. There are thirteen inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7,10) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(25) is bonded in a single-bond geometry to one C(28) atom. In the thirteenth H site, H(26) is bonded in a single-bond geometry to one C(28) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(3) atom. Linkers: 2 c1cc(CCCc2ccncc2)ccn1 ,2 [O]C(=O)/C=C/C([O])=O. Metal clusters: 2 [Cd]. The MOF has largest included sphere 4.18 A, density 1.23 g/cm3, surface area 5256.94 m2/g, accessible volume 0.36 cm3/g