CoC8N5H6O4(CH)5(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules, eight 02329_fluka molecules, and one CoC8N5H6O4 cluster. In the CoC8N5H6O4 cluster, Co(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Co(1)-N(1) bond length is 2.46 Å. The Co(1)-O(1) bond length is 1.91 Å. The Co(1)-O(2) bond length is 1.90 Å. The Co(1)-O(3) bond length is 1.91 Å. The Co(1)-O(4) bond length is 1.90 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one N(4) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-N(3) bond length is 1.36 Å. The C(1)-N(4) bond length is 1.34 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(5) atom. The C(2)-N(1) bond length is 1.36 Å. The C(2)-N(2) bond length is 1.35 Å. The C(2)-N(5) bond length is 1.34 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one N(3) atom. The C(3)-C(4) bond length is 1.48 Å. The C(3)-N(2) bond length is 1.34 Å. The C(3)-N(3) bond length is 1.34 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(9) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(5) atom. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(4) and one H(9) atom. The C(9)-H(9) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(10)-O(1) bond length is 1.28 Å. The C(10)-O(2) bond length is 1.28 Å. In the eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(11)-O(3) bond length is 1.28 Å. The C(11)-O(4) bond length is 1.28 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Co(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. The N(4)-H(1) bond length is 1.01 Å. The N(4)-H(2) bond length is 1.02 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(2), one H(3), and one H(4) atom. The N(5)-H(3) bond length is 1.01 Å. The N(5)-H(4) bond length is 1.02 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(10) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(10) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one C(11) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one C(11) atom. Linkers: 2 [O]C(=O)[C@H]1CC[C@@H](C([O])=O)CC1. Metal clusters: 1 [C]1O[Co]234O[C]O[Co]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 2.17 A, density 1.67 g/cm3, surface area 4237.60 m2/g, accessible volume 0.08 cm3/g