Co2C48N4H30O9 crystallizes in the monoclinic C2 space group. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(1), one O(11), one O(15), one O(17), one O(2), and one O(6) atom to form distorted corner-sharing CoNO5 octahedra. The corner-sharing octahedral tilt angles are 75°. The Co(1)-N(1) bond length is 2.05 Å. The Co(1)-O(11) bond length is 1.99 Å. The Co(1)-O(15) bond length is 1.97 Å. The Co(1)-O(17) bond length is 2.27 Å. The Co(1)-O(2) bond length is 2.19 Å. The Co(1)-O(6) bond length is 2.12 Å. In the second Co site, Co(2) is bonded to one N(2), one O(1), one O(12), one O(16), one O(18), and one O(5) atom to form distorted corner-sharing CoNO5 octahedra. The corner-sharing octahedral tilt angles are 74°. The Co(2)-N(2) bond length is 2.04 Å. The Co(2)-O(1) bond length is 2.10 Å. The Co(2)-O(12) bond length is 1.99 Å. The Co(2)-O(16) bond length is 2.01 Å. The Co(2)-O(18) bond length is 2.28 Å. The Co(2)-O(5) bond length is 2.21 Å. In the third Co site, Co(3,4) is bonded to one N(3), one O(13), one O(19), one O(4), one O(8), and one O(9) atom to form distorted corner-sharing CoNO5 octahedra. The corner-sharing octahedral tilt angles are 75°. The Co(3,4)-N(3) bond length is 2.05 Å. The Co(3,4)-O(13) bond length is 1.97 Å. The Co(3,4)-O(19) bond length is 2.27 Å. The Co(3,4)-O(4) bond length is 2.19 Å. The Co(3,4)-O(8) bond length is 2.12 Å. The Co(3,4)-O(9) bond length is 1.99 Å. There are eighty-nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(5); one N(1); and one H(5,7) atom. The C(1)-C(5) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(5,7) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(2), and one H(6) atom. The C(2)-C(6) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(6) bond length is 1.09 Å. In the third C site, C(3,4) is bonded in a distorted bent 120 degrees geometry to one C(7); one N(3); and one H(5,7) atom. The C(3,4)-C(7) bond length is 1.39 Å. The C(3,4)-N(3) bond length is 1.35 Å. The C(3,4)-H(5,7) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(1); one C(9); and one H(9,11,12) atom. The C(5)-C(9) bond length is 1.40 Å. The C(5)-H(9,11,12) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(10), one C(2), and one H(10) atom. The C(6)-C(10) bond length is 1.40 Å. The C(6)-H(10) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(11); one C(3,4); and one H(9,11,12) atom. The C(7)-C(11) bond length is 1.40 Å. The C(7)-H(9,11,12) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(12); one C(3,4); and one H(9,11,12) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(3,4) bond length is 1.39 Å. The C(8)-H(9,11,12) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(13,16); one C(29); and one C(5) atom. The C(9)-C(13,16) bond length is 1.40 Å. The C(9)-C(29) bond length is 1.47 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(14), one C(30), and one C(6) atom. The C(10)-C(14) bond length is 1.40 Å. The C(10)-C(30) bond length is 1.48 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one C(15), one C(31), and one C(7) atom. The C(11)-C(15) bond length is 1.40 Å. The C(11)-C(31) bond length is 1.48 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(13,16); one C(32); and one C(8) atom. The C(12)-C(13,16) bond length is 1.40 Å. The C(12)-C(32) bond length is 1.48 Å. In the twelfth C site, C(13,16) is bonded in a distorted single-bond geometry to one C(9) and one H(13,14,15,16) atom. The C(13,16)-H(13,14,15,16) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(10) and one H(13,14,15,16) atom. The C(14)-H(13,14,15,16) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(11) and one H(13,14,15,16) atom. The C(15)-H(13,14,15,16) bond length is 1.09 Å. In the fifteenth C site, C(17,20) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(17,19) atom. The C(17,20)-N(1) bond length is 1.35 Å. The C(17,20)-H(17,19) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(18) atom. The C(18)-N(2) bond length is 1.35 Å. The C(18)-H(18) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17,19) atom. The C(19)-N(3) bond length is 1.35 Å. The C(19)-H(17,19) bond length is 1.09 Å. In the eighteenth C site, C(21) is bonded in a trigonal planar geometry to one C(25), one C(41), and one N(5) atom. The C(21)-C(25) bond length is 1.40 Å. The C(21)-C(41) bond length is 1.48 Å. The C(21)-N(5) bond length is 1.35 Å. In the nineteenth C site, C(22) is bonded in a trigonal planar geometry to one C(26), one C(42), and one N(6) atom. The C(22)-C(26) bond length is 1.40 Å. The C(22)-C(42) bond length is 1.48 Å. The C(22)-N(6) bond length is 1.35 Å. In the twentieth C site, C(23) is bonded in a trigonal planar geometry to one C(27), one C(43), and one N(7) atom. The C(23)-C(27) bond length is 1.40 Å. The C(23)-C(43) bond length is 1.48 Å. The C(23)-N(7) bond length is 1.35 Å. In the twenty-first C site, C(24) is bonded in a trigonal planar geometry to one C(28), one C(44), and one N(8) atom. The C(24)-C(28) bond length is 1.40 Å. The C(24)-C(44) bond length is 1.48 Å. The C(24)-N(8) bond length is 1.35 Å. In the twenty-second C site, C(25) is bonded in a distorted single-bond geometry to one C(21), one C(29), and one H(21) atom. The C(25)-C(29) bond length is 1.40 Å. The C(25)-H(21) bond length is 1.09 Å. In the twenty-third C site, C(26) is bonded in a distorted single-bond geometry to one C(22), one C(30), and one H(22) atom. The C(26)-C(30) bond length is 1.40 Å. The C(26)-H(22) bond length is 1.09 Å. In the twenty-fourth C site, C(27) is bonded in a distorted single-bond geometry to one C(23); one C(31); and one H(23,24) atom. The C(27)-C(31) bond length is 1.40 Å. The C(27)-H(23,24) bond length is 1.09 Å. In the twenty-fifth C site, C(28) is bonded in a distorted single-bond geometry to one C(24); one C(32); and one H(23,24) atom. The C(28)-C(32) bond length is 1.40 Å. The C(28)-H(23,24) bond length is 1.09 Å. In the twenty-sixth C site, C(29) is bonded in a trigonal planar geometry to one C(25), one C(33), and one C(9) atom. The C(29)-C(33) bond length is 1.40 Å. In the twenty-seventh C site, C(30) is bonded in a trigonal planar geometry to one C(10), one C(26), and one C(34) atom. The C(30)-C(34) bond length is 1.40 Å. In the twenty-eighth C site, C(31) is bonded in a trigonal planar geometry to one C(11), one C(27), and one C(35) atom. The C(31)-C(35) bond length is 1.40 Å. In the twenty-ninth C site, C(32) is bonded in a trigonal planar geometry to one C(12), one C(28), and one C(36) atom. The C(32)-C(36) bond length is 1.40 Å. In the thirtieth C site, C(33) is bonded in a distorted single-bond geometry to one C(29); one C(37); and one H(25,26,27) atom. The C(33)-C(37) bond length is 1.40 Å. The C(33)-H(25,26,27) bond length is 1.09 Å. In the thirty-first C site, C(34) is bonded in a distorted single-bond geometry to one C(30); one C(38); and one H(25,26,27) atom. The C(34)-C(38) bond length is 1.40 Å. The C(34)-H(25,26,27) bond length is 1.09 Å. In the thirty-second C site, C(35) is bonded in a distorted single-bond geometry to one C(31); one C(39); and one H(25,26,27) atom. The C(35)-C(39) bond length is 1.40 Å. The C(35)-H(25,26,27) bond length is 1.09 Å. In the thirty-third C site, C(36) is bonded in a distorted single-bond geometry to one C(32), one C(40), and one H(28) atom. The C(36)-C(40) bond length is 1.40 Å. The C(36)-H(28) bond length is 1.09 Å. In the thirty-fourth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(33), one C(77), and one N(5) atom. The C(37)-C(77) bond length is 1.48 Å. The C(37)-N(5) bond length is 1.34 Å. In the thirty-fifth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(34), one C(78), and one N(6) atom. The C(38)-C(78) bond length is 1.48 Å. The C(38)-N(6) bond length is 1.34 Å. In the thirty-sixth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(35), one C(79), and one N(7) atom. The C(39)-C(79) bond length is 1.48 Å. The C(39)-N(7) bond length is 1.34 Å. In the thirty-seventh C site, C(40) is bonded in a distorted trigonal planar geometry to one C(36), one C(80), and one N(8) atom. The C(40)-C(80) bond length is 1.48 Å. The C(40)-N(8) bond length is 1.34 Å. In the thirty-eighth C site, C(41) is bonded in a trigonal planar geometry to one C(21), one C(45), and one C(61) atom. The C(41)-C(45) bond length is 1.41 Å. The C(41)-C(61) bond length is 1.41 Å. In the thirty-ninth C site, C(42) is bonded in a trigonal planar geometry to one C(22), one C(46), and one C(62) atom. The C(42)-C(46) bond length is 1.41 Å. The C(42)-C(62) bond length is 1.41 Å. In the fortieth C site, C(43) is bonded in a trigonal planar geometry to one C(23), one C(47), and one C(63) atom. The C(43)-C(47) bond length is 1.41 Å. The C(43)-C(63) bond length is 1.41 Å. In the forty-first C site, C(44) is bonded in a trigonal planar geometry to one C(24), one C(48), and one C(64) atom. The C(44)-C(48) bond length is 1.41 Å. The C(44)-C(64) bond length is 1.41 Å. In the forty-second C site, C(45) is bonded in a distorted trigonal planar geometry to one C(41), one C(49), and one H(29) atom. The C(45)-C(49) bond length is 1.39 Å. The C(45)-H(29) bond length is 1.09 Å. In the forty-third C site, C(46) is bonded in a distorted trigonal planar geometry to one C(42); one C(50,52); and one H(30,32) atom. The C(46)-C(50,52) bond length is 1.39 Å. The C(46)-H(30,32) bond length is 1.09 Å. In the forty-fourth C site, C(47) is bonded in a distorted trigonal planar geometry to one C(43), one C(51), and one H(31) atom. The C(47)-C(51) bond length is 1.39 Å. The C(47)-H(31) bond length is 1.09 Å. In the forty-fifth C site, C(48) is bonded in a distorted trigonal planar geometry to one C(44); one C(50,52); and one H(30,32) atom. The C(48)-C(50,52) bond length is 1.39 Å. The C(48)-H(30,32) bond length is 1.09 Å. In the forty-sixth C site, C(49) is bonded in a distorted single-bond geometry to one C(45), one C(53), and one H(33) atom. The C(49)-C(53) bond length is 1.40 Å. The C(49)-H(33) bond length is 1.09 Å. In the forty-seventh C site, C(50,52) is bonded in a distorted single-bond geometry to one C(46); one C(54); and one H(34,35,36) atom. The C(50,52)-C(54) bond length is 1.40 Å. The C(50,52)-H(34,35,36) bond length is 1.09 Å. In the forty-eighth C site, C(51) is bonded in a distorted single-bond geometry to one C(47); one C(55); and one H(34,35,36) atom. The C(51)-C(55) bond length is 1.40 Å. The C(51)-H(34,35,36) bond length is 1.09 Å. In the forty-ninth C site, C(53) is bonded in a trigonal planar geometry to one C(49), one C(57), and one C(65) atom. The C(53)-C(57) bond length is 1.40 Å. The C(53)-C(65) bond length is 1.49 Å. In the fiftieth C site, C(54) is bonded in a trigonal planar geometry to one C(50,52); one C(58,60); and one C(66,67,68) atom. The C(54)-C(58,60) bond length is 1.40 Å. The C(54)-C(66,67,68) bond length is 1.49 Å. In the fifty-first C site, C(55) is bonded in a trigonal planar geometry to one C(51); one C(59); and one C(66,67,68) atom. The C(55)-C(59) bond length is 1.40 Å. The C(55)-C(66,67,68) bond length is 1.49 Å. In the fifty-second C site, C(56) is bonded in a trigonal planar geometry to one C(50,52); one C(58,60); and one C(66,67,68) atom. The C(56)-C(50,52) bond length is 1.40 Å. The C(56)-C(58,60) bond length is 1.40 Å. The C(56)-C(66,67,68) bond length is 1.49 Å. In the fifty-third C site, C(57) is bonded in a distorted single-bond geometry to one C(53), one C(61), and one H(37) atom. The C(57)-C(61) bond length is 1.39 Å. The C(57)-H(37) bond length is 1.09 Å. In the fifty-fourth C site, C(58,60) is bonded in a distorted single-bond geometry to one C(54); one C(62); and one H(38,39) atom. The C(58,60)-C(62) bond length is 1.39 Å. The C(58,60)-H(38,39) bond length is 1.09 Å. In the fifty-fifth C site, C(59) is bonded in a distorted single-bond geometry to one C(55); one C(63); and one H(38,39) atom. The C(59)-C(63) bond length is 1.39 Å. The C(59)-H(38,39) bond length is 1.09 Å. In the fifty-sixth C site, C(61) is bonded in a distorted trigonal planar geometry to one C(41), one C(57), and one H(41) atom. The C(61)-H(41) bond length is 1.09 Å. In the fifty-seventh C site, C(62) is bonded in a distorted trigonal planar geometry to one C(42); one C(58,60); and one H(42,44) atom. The C(62)-H(42,44) bond length is 1.09 Å. In the fifty-eighth C site, C(63) is bonded in a distorted trigonal planar geometry to one C(43), one C(59), and one H(43) atom. The C(63)-H(43) bond length is 1.09 Å. In the fifty-ninth C site, C(64) is bonded in a distorted trigonal planar geometry to one C(44); one C(58,60); and one H(42,44) atom. The C(64)-C(58,60) bond length is 1.39 Å. The C(64)-H(42,44) bond length is 1.09 Å. In the sixtieth C site, C(65) is bonded in a bent 120 degrees geometry to one C(53), one O(1), and one O(5) atom. The C(65)-O(1) bond length is 1.29 Å. The C(65)-O(5) bond length is 1.27 Å. In the sixty-first C site, C(66,67,68) is bonded in a bent 120 degrees geometry to one C(54), one O(2), and one O(6) atom. The C(66,67,68)-O(2) bond length is 1.28 Å. The C(66,67,68)-O(6) bond length is 1.29 Å. In the sixty-second C site, C(69) is bonded in a distorted trigonal planar geometry to one C(73), one C(89), and one H(45) atom. The C(69)-C(73) bond length is 1.39 Å. The C(69)-C(89) bond length is 1.40 Å. The C(69)-H(45) bond length is 1.09 Å. In the sixty-third C site, C(70) is bonded in a distorted trigonal planar geometry to one C(74); one C(90); and one H(46,47) atom. The C(70)-C(74) bond length is 1.39 Å. The C(70)-C(90) bond length is 1.40 Å. The C(70)-H(46,47) bond length is 1.09 Å. In the sixty-fourth C site, C(71) is bonded in a distorted trigonal planar geometry to one C(75); one C(91); and one H(46,47) atom. The C(71)-C(75) bond length is 1.39 Å. The C(71)-C(91) bond length is 1.40 Å. The C(71)-H(46,47) bond length is 1.09 Å. In the sixty-fifth C site, C(72) is bonded in a distorted trigonal planar geometry to one C(76), one C(92), and one H(48) atom. The C(72)-C(76) bond length is 1.39 Å. The C(72)-C(92) bond length is 1.40 Å. The C(72)-H(48) bond length is 1.09 Å. In the sixty-sixth C site, C(73) is bonded in a distorted single-bond geometry to one C(69); one C(77); and one H(49,50) atom. The C(73)-C(77) bond length is 1.41 Å. The C(73)-H(49,50) bond length is 1.09 Å. In the sixty-seventh C site, C(74) is bonded in a distorted single-bond geometry to one C(70); one C(78); and one H(49,50) atom. The C(74)-C(78) bond length is 1.41 Å. The C(74)-H(49,50) bond length is 1.09 Å. In the sixty-eighth C site, C(75) is bonded in a distorted single-bond geometry to one C(71), one C(79), and one H(51) atom. The C(75)-C(79) bond length is 1.41 Å. The C(75)-H(51) bond length is 1.09 Å. In the sixty-ninth C site, C(76) is bonded in a distorted single-bond geometry to one C(72), one C(80), and one H(52) atom. The C(76)-C(80) bond length is 1.41 Å. The C(76)-H(52) bond length is 1.09 Å. In the seventieth C site, C(77) is bonded in a trigonal planar geometry to one C(37), one C(73), and one C(81) atom. The C(77)-C(81) bond length is 1.41 Å. In the seventy-first C site, C(78) is bonded in a trigonal planar geometry to one C(38), one C(74), and one C(82) atom. The C(78)-C(82) bond length is 1.41 Å. In the seventy-second C site, C(79) is bonded in a trigonal planar geometry to one C(39), one C(75), and one C(83) atom. The C(79)-C(83) bond length is 1.41 Å. In the seventy-third C site, C(80) is bonded in a trigonal planar geometry to one C(40), one C(76), and one C(84) atom. The C(80)-C(84) bond length is 1.41 Å. In the seventy-fourth C site, C(81) is bonded in a distorted single-bond geometry to one C(77) and one H(53,54,55) atom. The C(81)-H(53,54,55) bond length is 1.09 Å. In the seventy-fifth C site, C(82) is bonded in a distorted single-bond geometry to one C(78) and one H(53,54,55) atom. The C(82)-H(53,54,55) bond length is 1.09 Å. In the seventy-sixth C site, C(83) is bonded in a distorted single-bond geometry to one C(79) and one H(53,54,55) atom. The C(83)-H(53,54,55) bond length is 1.09 Å. In the seventy-seventh C site, C(84) is bonded in a distorted single-bond geometry to one C(80) and one H(56) atom. The C(84)-H(56) bond length is 1.09 Å. In the seventy-eighth C site, C(85) is bonded in a distorted single-bond geometry to one C(89) and one H(57) atom. The C(85)-C(89) bond length is 1.40 Å. The C(85)-H(57) bond length is 1.09 Å. In the seventy-ninth C site, C(86) is bonded in a distorted single-bond geometry to one C(90) and one H(58,59) atom. The C(86)-C(90) bond length is 1.40 Å. The C(86)-H(58,59) bond length is 1.09 Å. In the eightieth C site, C(87) is bonded in a distorted single-bond geometry to one C(91) and one H(58,59) atom. The C(87)-C(91) bond length is 1.40 Å. The C(87)-H(58,59) bond length is 1.09 Å. In the eighty-first C site, C(88) is bonded in a distorted single-bond geometry to one C(92) and one H(60) atom. The C(88)-C(92) bond length is 1.40 Å. The C(88)-H(60) bond length is 1.09 Å. In the eighty-second C site, C(89) is bonded in a trigonal planar geometry to one C(69), one C(85), and one C(93) atom. The C(89)-C(93) bond length is 1.49 Å. In the eighty-third C site, C(90) is bonded in a trigonal planar geometry to one C(70), one C(86), and one C(94) atom. The C(90)-C(94) bond length is 1.49 Å. In the eighty-fourth C site, C(91) is bonded in a trigonal planar geometry to one C(71), one C(87), and one C(95) atom. The C(91)-C(95) bond length is 1.49 Å. In the eighty-fifth C site, C(92) is bonded in a trigonal planar geometry to one C(72), one C(88), and one C(96) atom. The C(92)-C(96) bond length is 1.50 Å. In the eighty-sixth C site, C(93) is bonded in a distorted bent 120 degrees geometry to one C(89), one O(13), and one O(9) atom. The C(93)-O(13) bond length is 1.28 Å. The C(93)-O(9) bond length is 1.28 Å. In the eighty-seventh C site, C(94) is bonded in a distorted bent 120 degrees geometry to one C(90), one O(10), and one O(14) atom. The C(94)-O(10) bond length is 1.28 Å. The C(94)-O(14) bond length is 1.28 Å. In the eighty-eighth C site, C(95) is bonded in a distorted bent 120 degrees geometry to one C(91), one O(11), and one O(15) atom. The C(95)-O(11) bond length is 1.28 Å. The C(95)-O(15) bond length is 1.28 Å. In the eighty-ninth C site, C(96) is bonded in a distorted bent 120 degrees geometry to one C(92), one O(12), and one O(16) atom. The C(96)-O(12) bond length is 1.27 Å. The C(96)-O(16) bond length is 1.28 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1); one C(1); and one C(17,20) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(2), one C(18), and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(3,4); one C(19); and one C(3,4) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(3,4); one C(17,20); and one C(3,4) atom. The N(4)-Co(3,4) bond length is 2.05 Å. The N(4)-C(17,20) bond length is 1.35 Å. The N(4)-C(3,4) bond length is 1.35 Å. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(21) and one C(37) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one C(22) and one C(38) atom. In the seventh N site, N(7) is bonded in a bent 120 degrees geometry to one C(23) and one C(39) atom. In the eighth N site, N(8) is bonded in a bent 120 degrees geometry to one C(24) and one C(40) atom. There are thirty-eight inequivalent H sites. In the first H site, H(1,3,4) is bonded in a single-bond geometry to one O(17) atom. The H(1,3,4)-O(17) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(18) atom. The H(2)-O(18) bond length is 0.97 Å. In the third H site, H(5,7) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(3,4) atom. The H(8)-C(3,4) bond length is 1.09 Å. In the sixth H site, H(9,11,12) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(13,14,15,16) is bonded in a single-bond geometry to one C(13,16) atom. In the ninth H site, H(17,19) is bonded in a single-bond geometry to one C(17,20) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(17,20) atom. The H(20)-C(17,20) bond length is 1.09 Å. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(26) atom. In the fourteenth H site, H(23,24) is bonded in a single-bond geometry to one C(27) atom. In the fifteenth H site, H(25,26,27) is bonded in a single-bond geometry to one C(33) atom. In the sixteenth H site, H(28) is bonded in a single-bond geometry to one C(36) atom. In the seventeenth H site, H(29) is bonded in a single-bond geometry to one C(45) atom. In the eighteenth H site, H(30,32) is bonded in a single-bond geometry to one C(46) atom. In the nineteenth H site, H(31) is bonded in a single-bond geometry to one C(47) atom. In the twentieth H site, H(33) is bonded in a single-bond geometry to one C(49) atom. In the twenty-first H site, H(34,35,36) is bonded in a single-bond geometry to one C(50,52) atom. In the twenty-second H site, H(37) is bonded in a single-bond geometry to one C(57) atom. In the twenty-third H site, H(38,39) is bonded in a single-bond geometry to one C(58,60) atom. In the twenty-fourth H site, H(40) is bonded in a single-bond geometry to one C(58,60) atom. The H(40)-C(58,60) bond length is 1.09 Å. In the twenty-fifth H site, H(41) is bonded in a single-bond geometry to one C(61) atom. In the twenty-sixth H site, H(42,44) is bonded in a single-bond geometry to one C(62) atom. In the twenty-seventh H site, H(43) is bonded in a single-bond geometry to one C(63) atom. In the twenty-eighth H site, H(45) is bonded in a single-bond geometry to one C(69) atom. In the twenty-ninth H site, H(46,47) is bonded in a single-bond geometry to one C(70) atom. In the thirtieth H site, H(48) is bonded in a single-bond geometry to one C(72) atom. In the thirty-first H site, H(49,50) is bonded in a single-bond geometry to one C(73) atom. In the thirty-second H site, H(51) is bonded in a single-bond geometry to one C(75) atom. In the thirty-third H site, H(52) is bonded in a single-bond geometry to one C(76) atom. In the thirty-fourth H site, H(53,54,55) is bonded in a single-bond geometry to one C(81) atom. In the thirty-fifth H site, H(56) is bonded in a single-bond geometry to one C(84) atom. In the thirty-sixth H site, H(57) is bonded in a single-bond geometry to one C(85) atom. In the thirty-seventh H site, H(58,59) is bonded in a single-bond geometry to one C(86) atom. In the thirty-eighth H site, H(60) is bonded in a single-bond geometry to one C(88) atom. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Co(2) and one C(65) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Co(1) and one C(66,67,68) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Co(3,4) and one C(66,67,68) atom. The O(3)-Co(3,4) bond length is 2.19 Å. The O(3)-C(66,67,68) bond length is 1.28 Å. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Co(3,4) and one C(66,67,68) atom. The O(4)-C(66,67,68) bond length is 1.28 Å. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Co(2) and one C(65) atom. In the sixth O site, O(6) is bonded in an L-shaped geometry to one Co(1) and one C(66,67,68) atom. In the seventh O site, O(7) is bonded in an L-shaped geometry to one Co(3,4) and one C(66,67,68) atom. The O(7)-Co(3,4) bond length is 2.12 Å. The O(7)-C(66,67,68) bond length is 1.29 Å. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Co(3,4) and one C(66,67,68) atom. The O(8)-C(66,67,68) bond length is 1.29 Å. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Co(3,4) and one C(93) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Co(3,4) and one C(94) atom. The O(10)-Co(3,4) bond length is 1.99 Å. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(95) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(96) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Co(3,4) and one C(93) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Co(3,4) and one C(94) atom. The O(14)-Co(3,4) bond length is 1.97 Å. In the fifteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(95) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Co(2) and one C(96) atom. In the seventeenth O site, O(17) is bonded in a water-like geometry to two equivalent Co(1) and two equivalent H(1,3,4) atoms. In the eighteenth O site, O(18) is bonded in a water-like geometry to two equivalent Co(2) and two equivalent H(2) atoms. In the nineteenth O site, O(19) is bonded in a water-like geometry to two equivalent Co(3,4) and two equivalent H(1,3,4) atoms. Both O(19)-H(1,3,4) bond lengths are 0.98 Å. In the twentieth O site, O(20) is bonded in a water-like geometry to two equivalent Co(3,4) and two equivalent H(1,3,4) atoms. Both O(20)-Co(3,4) bond lengths are 2.28 Å. Both O(20)-H(1,3,4) bond lengths are 0.98 Å. Linkers: 8 [O]C(=O)c1ccc(-c2cc(-c3ccncc3)cc(-c3ccc(C([O])=O)cc3)n2)cc1. Metal clusters: 4 O.[C]1O[Co]2(O1)O[C]O[Co]1(O[C]O1)O[C]O2. RCSR code: dia. The MOF has largest included sphere 13.37 A, density 0.44 g/cm3, surface area 4769.61 m2/g, accessible volume 1.93 cm3/g