CuC25PN3H19Br(CH)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules and two CuC25PN3H19Br clusters. In each CuC25PN3H19Br cluster, Cu(1) is bonded to one P(1), one N(1), and two equivalent Br(1) atoms to form distorted edge-sharing CuPBr2N tetrahedra. The Cu(1)-P(1) bond length is 2.19 Å. The Cu(1)-N(1) bond length is 2.00 Å. There is one shorter (2.53 Å) and one longer (2.54 Å) Cu(1)-Br(1) bond length. There are twenty-five inequivalent C sites. In the first C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(5,6); one N(3); and one H(49,50) atom. The C(11)-C(5,6) bond length is 1.45 Å. The C(11)-N(3) bond length is 1.30 Å. The C(11)-H(49,50) bond length is 1.10 Å. In the second C site, C(13) is bonded in a distorted trigonal planar geometry to one C(57,58); one C(61,62); and one H(9,10) atom. The C(13)-C(57,58) bond length is 1.41 Å. The C(13)-C(61,62) bond length is 1.39 Å. The C(13)-H(9,10) bond length is 1.09 Å. In the third C site, C(19) is bonded in a trigonal planar geometry to one C(21), one C(29), and one P(1) atom. The C(19)-C(21) bond length is 1.40 Å. The C(19)-C(29) bond length is 1.40 Å. The C(19)-P(1) bond length is 1.83 Å. In the fourth C site, C(21) is bonded in a distorted single-bond geometry to one C(19) and one H(15,16) atom. The C(21)-H(15,16) bond length is 1.09 Å. In the fifth C site, C(23) is bonded in a distorted single-bond geometry to one C(25,26) and one H(17,18) atom. The C(23)-C(25,26) bond length is 1.40 Å. The C(23)-H(17,18) bond length is 1.09 Å. In the sixth C site, C(25,26) is bonded in a distorted trigonal planar geometry to one C(23), one C(27), and one H(19) atom. The C(25,26)-C(27) bond length is 1.40 Å. The C(25,26)-H(19) bond length is 1.09 Å. In the seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(25,26); one C(29); and one H(21,22) atom. The C(27)-C(29) bond length is 1.40 Å. The C(27)-H(21,22) bond length is 1.09 Å. In the eighth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(19), one C(27), and one H(23) atom. The C(29)-H(23) bond length is 1.09 Å. In the ninth C site, C(31) is bonded in a trigonal planar geometry to one C(33), one C(41), and one P(1) atom. The C(31)-C(33) bond length is 1.40 Å. The C(31)-C(41) bond length is 1.41 Å. The C(31)-P(1) bond length is 1.83 Å. In the tenth C site, C(33) is bonded in a distorted single-bond geometry to one C(31) and one H(25,26) atom. The C(33)-H(25,26) bond length is 1.09 Å. In the eleventh C site, C(41) is bonded in a distorted single-bond geometry to one C(31) and one H(33,34) atom. The C(41)-H(33,34) bond length is 1.09 Å. In the twelfth C site, C(43) is bonded in a trigonal planar geometry to one C(45), one C(53), and one P(1) atom. The C(43)-C(45) bond length is 1.41 Å. The C(43)-C(53) bond length is 1.40 Å. The C(43)-P(1) bond length is 1.84 Å. In the thirteenth C site, C(45) is bonded in a distorted single-bond geometry to one C(43) and one H(35) atom. The C(45)-H(35) bond length is 1.09 Å. In the fourteenth C site, C(49,50) is bonded in a distorted single-bond geometry to one C(51) and one H(39) atom. The C(49,50)-C(51) bond length is 1.40 Å. The C(49,50)-H(39) bond length is 1.09 Å. In the fifteenth C site, C(51) is bonded in a distorted trigonal planar geometry to one C(49,50); one C(53); and one H(41,42) atom. The C(51)-C(53) bond length is 1.40 Å. The C(51)-H(41,42) bond length is 1.09 Å. In the sixteenth C site, C(53) is bonded in a distorted single-bond geometry to one C(43), one C(51), and one H(43) atom. The C(53)-H(43) bond length is 1.09 Å. In the seventeenth C site, C(55) is bonded in a distorted single-bond geometry to one C(57,58) and one N(5) atom. The C(55)-C(57,58) bond length is 1.46 Å. The C(55)-N(5) bond length is 1.31 Å. In the eighteenth C site, C(57,58) is bonded in a trigonal planar geometry to one C(13), one C(55), and one C(59) atom. The C(57,58)-C(59) bond length is 1.41 Å. In the nineteenth C site, C(59) is bonded in a distorted single-bond geometry to one C(57,58) and one H(45,46) atom. The C(59)-H(45,46) bond length is 1.09 Å. In the twentieth C site, C(61,62) is bonded in a distorted single-bond geometry to one C(13) and one H(47,48) atom. The C(61,62)-H(47,48) bond length is 1.09 Å. In the twenty-first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,2) atom. The C(1,2)-N(1) bond length is 1.35 Å. The C(1,2)-H(1,2) bond length is 1.09 Å. In the twenty-second C site, C(3) is bonded in a distorted single-bond geometry to one C(5,6) and one H(3,4) atom. The C(3)-C(5,6) bond length is 1.40 Å. The C(3)-H(3,4) bond length is 1.09 Å. In the twenty-third C site, C(5,6) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(7) atom. The C(5,6)-C(7) bond length is 1.41 Å. In the twenty-fourth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5,6); one C(9,10); and one H(5,6) atom. The C(7)-C(9,10) bond length is 1.38 Å. The C(7)-H(5,6) bond length is 1.09 Å. In the twenty-fifth C site, C(9,10) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(1), and one H(7) atom. The C(9,10)-N(1) bond length is 1.35 Å. The C(9,10)-H(7) bond length is 1.09 Å. P(1) is bonded in a tetrahedral geometry to one Cu(1), one C(19), one C(31), and one C(43) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1); one C(1,2); and one C(9,10) atom. In the second N site, N(3) is bonded in a distorted bent 120 degrees geometry to one C(11) and one N(5) atom. The N(3)-N(5) bond length is 1.38 Å. In the third N site, N(5) is bonded in a distorted single-bond geometry to one C(55) and one N(3) atom. There are nineteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(9,10) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(15,16) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(17,18) is bonded in a single-bond geometry to one C(23) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(25,26) atom. In the ninth H site, H(21,22) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(23) is bonded in a single-bond geometry to one C(29) atom. In the eleventh H site, H(25,26) is bonded in a single-bond geometry to one C(33) atom. In the twelfth H site, H(33,34) is bonded in a single-bond geometry to one C(41) atom. In the thirteenth H site, H(35) is bonded in a single-bond geometry to one C(45) atom. In the fourteenth H site, H(39) is bonded in a single-bond geometry to one C(49,50) atom. In the fifteenth H site, H(41,42) is bonded in a single-bond geometry to one C(51) atom. In the sixteenth H site, H(43) is bonded in a single-bond geometry to one C(53) atom. In the seventeenth H site, H(45,46) is bonded in a single-bond geometry to one C(59) atom. In the eighteenth H site, H(47,48) is bonded in a single-bond geometry to one C(61,62) atom. In the nineteenth H site, H(49,50) is bonded in a single-bond geometry to one C(11) atom. Br(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 2 [CH]([N][N][C]([C]([N][N][CH]c1ccncc1)c1ccccc1)c1ccccc1)c1ccncc1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 5.93 A, density 1.28 g/cm3, surface area 4886.56 m2/g, accessible volume 0.30 cm3/g