CuC8NH5O4(CH2)3CO2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, four carbon dioxide molecules, and two CuC8NH5O4 clusters. In each CuC8NH5O4 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(4), one O(6), and one O(7) atom. The Cu(1)-N(1) bond length is 2.18 Å. The Cu(1)-O(1) bond length is 2.01 Å. The Cu(1)-O(4) bond length is 2.00 Å. The Cu(1)-O(6) bond length is 2.01 Å. The Cu(1)-O(7) bond length is 2.01 Å. There are eight inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(7) atom. The C(5)-O(1) bond length is 1.27 Å. The C(5)-O(7) bond length is 1.28 Å. In the second C site, C(7) is bonded in a distorted single-bond geometry to one C(17) and one H(9) atom. The C(7)-C(17) bond length is 1.41 Å. The C(7)-H(9) bond length is 1.09 Å. In the third C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. The C(10)-O(4) bond length is 1.28 Å. The C(10)-O(6) bond length is 1.27 Å. In the fourth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(21), one N(1), and one H(11) atom. The C(11)-C(21) bond length is 1.39 Å. The C(11)-N(1) bond length is 1.34 Å. The C(11)-H(11) bond length is 1.09 Å. In the fifth C site, C(15) is bonded in a distorted trigonal planar geometry to one N(1) and one H(17) atom. The C(15)-N(1) bond length is 1.35 Å. The C(15)-H(17) bond length is 1.09 Å. In the sixth C site, C(17) is bonded in a trigonal planar geometry to one C(19,20); one C(21); and one C(7) atom. The C(17)-C(19,20) bond length is 1.45 Å. The C(17)-C(21) bond length is 1.41 Å. In the seventh C site, C(19,20) is bonded in a distorted single-bond geometry to one C(17) and one H(19,20) atom. The C(19,20)-H(19,20) bond length is 1.09 Å. In the eighth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(11); one C(17); and one H(21,22) atom. The C(21)-H(21,22) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(15) atom. There are five inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(19,20) is bonded in a single-bond geometry to one C(19,20) atom. In the fifth H site, H(21,22) is bonded in a single-bond geometry to one C(21) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(5) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(10) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(10) atom. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(5) atom. Linkers: 2 C(=C/c1ccncc1)\c1ccncc1 ,4 [O]C(=O)CCCC([O])=O. Metal clusters: 2 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 3.31 A, density 1.60 g/cm3, surface area 4599.36 m2/g, accessible volume 0.16 cm3/g