(CH2)2CuC24H16S8(NO)14 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one CuC24H16S8(NO)14 cluster. In the CuC24H16S8(NO)14 cluster, Cu(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent O(7) atoms. Both Cu(1)-N(1) bond lengths are 2.00 Å. Both Cu(1)-N(3) bond lengths are 2.05 Å. Both Cu(1)-O(7) bond lengths are 2.43 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1), one H(1), and one S(1) atom. The C(1)-N(1) bond length is 1.31 Å. The C(1)-H(1) bond length is 1.09 Å. The C(1)-S(1) bond length is 1.70 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2), one S(1), and one S(2) atom. The C(2)-N(2) bond length is 1.32 Å. The C(2)-S(1) bond length is 1.74 Å. The C(2)-S(2) bond length is 1.73 Å. In the third C site, C(3) is bonded in a distorted water-like geometry to one H(2), one H(3), and one S(2) atom. The C(3)-H(2) bond length is 1.10 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-S(2) bond length is 1.82 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(3), one H(6), and one S(3) atom. The C(5)-N(3) bond length is 1.31 Å. The C(5)-H(6) bond length is 1.09 Å. The C(5)-S(3) bond length is 1.70 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one N(4), one S(3), and one S(4) atom. The C(6)-N(4) bond length is 1.32 Å. The C(6)-S(3) bond length is 1.75 Å. The C(6)-S(4) bond length is 1.73 Å. In the sixth C site, C(7) is bonded in a distorted water-like geometry to one H(7), one H(8), and one S(4) atom. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.10 Å. The C(7)-S(4) bond length is 1.82 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(13), one C(9), and one O(7) atom. The C(8)-C(13) bond length is 1.46 Å. The C(8)-C(9) bond length is 1.46 Å. The C(8)-O(7) bond length is 1.25 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(5) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-N(5) bond length is 1.45 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(9) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(6) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-N(6) bond length is 1.43 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(10) atom. The C(12)-C(13) bond length is 1.37 Å. The C(12)-H(10) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one N(7) atom. The C(13)-N(7) bond length is 1.45 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(2) and one N(1) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(5), and one N(4) atom. The N(3)-N(4) bond length is 1.37 Å. In the fourth N site, N(4) is bonded in a distorted water-like geometry to one C(6) and one N(3) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(9), one O(1), and one O(2) atom. The N(5)-O(1) bond length is 1.24 Å. The N(5)-O(2) bond length is 1.25 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(11), one O(3), and one O(4) atom. The N(6)-O(3) bond length is 1.25 Å. The N(6)-O(4) bond length is 1.25 Å. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(13), one O(5), and one O(6) atom. The N(7)-O(5) bond length is 1.25 Å. The N(7)-O(6) bond length is 1.24 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(1) and one C(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(2) and one C(3) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one C(5) and one C(6) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one C(6) and one C(7) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(6) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(6) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(7) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(7) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cu(1) and one C(8) atom. Linkers: 2 c1nnc(SCCCSc2nncs2)s1 ,2 [c]1nnc(SCCCSc2nncs2)s1 ,2 [N][N][C]SCCCSc1nncs1. Metal clusters: 1 [Cu]. The MOF has largest included sphere 2.39 A, density 1.81 g/cm3, surface area 4068.35 m2/g, accessible volume 0.11 cm3/g