ZnC12N7H5O(CH)4 crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of sixteen 02329_fluka molecules inside a ZnC12N7H5O framework. In the ZnC12N7H5O framework, Zn(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(4), one N(5), one N(7), and one O(1) atom. The Zn(1)-N(1) bond length is 2.12 Å. The Zn(1)-N(2) bond length is 2.21 Å. The Zn(1)-N(4) bond length is 2.11 Å. The Zn(1)-N(5) bond length is 2.03 Å. The Zn(1)-N(7) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 2.40 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.50 Å. The C(5)-N(1) bond length is 1.35 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one O(1) atom. The C(6)-C(7) bond length is 1.48 Å. The C(6)-O(1) bond length is 1.24 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(6), and one C(8) atom. The C(7)-C(12) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.41 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(9) atom. The C(12)-H(9) bond length is 1.09 Å. In the ninth C site, C(13) is bonded in a linear geometry to one N(2) and one N(3) atom. The C(13)-N(2) bond length is 1.18 Å. The C(13)-N(3) bond length is 1.29 Å. In the tenth C site, C(14) is bonded in a linear geometry to one N(3) and one N(4) atom. The C(14)-N(3) bond length is 1.29 Å. The C(14)-N(4) bond length is 1.18 Å. In the eleventh C site, C(15) is bonded in a linear geometry to one N(5) and one N(6) atom. The C(15)-N(5) bond length is 1.18 Å. The C(15)-N(6) bond length is 1.29 Å. In the twelfth C site, C(16) is bonded in a linear geometry to one N(6) and one N(7) atom. The C(16)-N(6) bond length is 1.29 Å. The C(16)-N(7) bond length is 1.17 Å. There are seven inequivalent N sites. In the first N site, N(7) is bonded in a linear geometry to one Zn(1) and one C(16) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the third N site, N(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(13) atom. In the fourth N site, N(3) is bonded in a bent 120 degrees geometry to one C(13) and one C(14) atom. In the fifth N site, N(4) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(14) atom. In the sixth N site, N(5) is bonded in a linear geometry to one Zn(1) and one C(15) atom. In the seventh N site, N(6) is bonded in a bent 120 degrees geometry to one C(15) and one C(16) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. O(1) is bonded in a distorted single-bond geometry to one Zn(1) and one C(6) atom. Linkers: 3 O=C(c1ccccc1)c1ccccn1 ,8 N#C[N]C#N. Metal clusters: 4 [Zn]. The MOF has largest included sphere 2.50 A, density 1.51 g/cm3, surface area 4801.55 m2/g, accessible volume 0.17 cm3/g