(CH)2CuC7N3H7OCl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two CuC7N3H7OCl clusters. In each CuC7N3H7OCl cluster, Cu(1) is bonded in a 5-coordinate geometry to one C(1), one C(2), one N(3), and two equivalent Cl(1) atoms. The Cu(1)-C(1) bond length is 2.02 Å. The Cu(1)-C(2) bond length is 2.02 Å. The Cu(1)-N(3) bond length is 1.97 Å. There is one shorter (2.24 Å) and one longer (2.84 Å) Cu(1)-Cl(1) bond length. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1), one H(1), and one H(2) atom. The C(1)-H(1) bond length is 1.09 Å. The C(1)-H(2) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one Cu(1) and one H(3) atom. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one H(4), one H(5), and one O(1) atom. The C(3)-H(4) bond length is 1.09 Å. The C(3)-H(5) bond length is 1.10 Å. The C(3)-O(1) bond length is 1.50 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(4)-C(9) bond length is 1.41 Å. The C(4)-H(6) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(9) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(9) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one N(1) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-N(1) bond length is 1.37 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one N(3) atom. The C(9)-N(3) bond length is 1.38 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one O(1) atom. The N(1)-N(2) bond length is 1.33 Å. The N(1)-O(1) bond length is 1.36 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.32 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(9), and one N(2) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(7) atom. O(1) is bonded in a water-like geometry to one C(3) and one N(1) atom. Cl(1) is bonded in a distorted L-shaped geometry to two equivalent Cu(1) atoms. Linkers: 4 [CH]COn1nnc2ccccc21. Metal clusters: 4 [CH2][CH][Cu].[Cl]. The MOF has largest included sphere 2.07 A, density 1.71 g/cm3, surface area 4341.15 m2/g, accessible volume 0.20 cm3/g