(ZnC21H11(OF)6)2H4(C3F2)3 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two H4(C3F2)3 clusters and two ZnC21H11(OF)6 clusters. In each H4(C3F2)3 cluster, there are five inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(3) bond length is 1.09 Å. In the second C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.54 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(4,13) atom. The C(6)-H(4,13) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a tetrahedral geometry to two equivalent C(5) and two equivalent C(9) atoms. Both C(8)-C(9) bond lengths are 1.56 Å. In the fifth C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(8), one F(1), one F(2), and one F(3) atom. The C(9)-F(1) bond length is 1.36 Å. The C(9)-F(2) bond length is 1.36 Å. The C(9)-F(3) bond length is 1.37 Å. There are two inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(4,13) is bonded in a single-bond geometry to one C(6) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(9) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(9) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(9) atom. In each ZnC21H11(OF)6 cluster, Zn(1) is bonded in a distorted square pyramidal geometry to one O(1), one O(3), one O(4), one O(5), and one O(6) atom. The Zn(1)-O(1) bond length is 2.03 Å. The Zn(1)-O(3) bond length is 2.00 Å. The Zn(1)-O(4) bond length is 2.02 Å. The Zn(1)-O(5) bond length is 2.23 Å. The Zn(1)-O(6) bond length is 2.03 Å. There are twenty-one inequivalent C sites. In the first C site, C(20) is bonded in a trigonal planar geometry to one C(17), one C(21), and one C(25) atom. The C(20)-C(17) bond length is 1.54 Å. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(25) bond length is 1.40 Å. In the second C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(10) atom. The C(21)-H(10) bond length is 1.09 Å. In the third C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(11) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(11) bond length is 1.09 Å. In the fourth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(26) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(26) bond length is 1.49 Å. In the fifth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(12) atom. The C(24)-H(12) bond length is 1.09 Å. In the sixth C site, C(25) is bonded in a distorted single-bond geometry to one C(20) and one H(4,13) atom. The C(25)-H(4,13) bond length is 1.09 Å. In the seventh C site, C(26) is bonded in a bent 120 degrees geometry to one C(23), one O(5), and one O(6) atom. The C(26)-O(5) bond length is 1.29 Å. The C(26)-O(6) bond length is 1.27 Å. In the eighth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.32 Å. In the ninth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the tenth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the eleventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the twelfth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(3), and one O(4) atom. The C(10)-C(11) bond length is 1.49 Å. The C(10)-O(3) bond length is 1.28 Å. The C(10)-O(4) bond length is 1.27 Å. In the thirteenth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(16) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(16) bond length is 1.40 Å. In the fourteenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(6) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(6) bond length is 1.09 Å. In the fifteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(7) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-H(7) bond length is 1.09 Å. In the sixteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(17) bond length is 1.54 Å. In the seventeenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(8) atom. The C(15)-H(8) bond length is 1.09 Å. In the eighteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(11) and one H(9) atom. The C(16)-H(9) bond length is 1.09 Å. In the nineteenth C site, C(17) is bonded in a tetrahedral geometry to one C(14), one C(18), one C(19), and one C(20) atom. The C(17)-C(18) bond length is 1.56 Å. The C(17)-C(19) bond length is 1.56 Å. In the twentieth C site, C(18) is bonded in a trigonal non-coplanar geometry to one C(17), one F(4), one F(5), and one F(6) atom. The C(18)-F(4) bond length is 1.36 Å. The C(18)-F(5) bond length is 1.36 Å. The C(18)-F(6) bond length is 1.37 Å. In the twenty-first C site, C(19) is bonded in a trigonal non-coplanar geometry to one C(17), one F(7), one F(8), and one F(9) atom. The C(19)-F(7) bond length is 1.36 Å. The C(19)-F(8) bond length is 1.37 Å. The C(19)-F(9) bond length is 1.36 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(5) atom. The H(1)-O(2) bond length is 1.04 Å. The H(1)-O(5) bond length is 1.48 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4,13) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(24) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(1) and one H(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(10) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(10) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Zn(1), one C(26), and one H(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(26) atom. There are six inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one C(18) atom. In the second F site, F(5) is bonded in a single-bond geometry to one C(18) atom. In the third F site, F(6) is bonded in a single-bond geometry to one C(18) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one C(19) atom. In the fifth F site, F(8) is bonded in a single-bond geometry to one C(19) atom. In the sixth F site, F(9) is bonded in a single-bond geometry to one C(19) atom. Linkers: 4 [O]C(=O)c1ccc(C(c2ccc(C([O])=O)cc2)(C(F)(F)F)C(F)(F)F)cc1 ,1 O=C(O)c1ccc(C(c2ccc(C(=O)O)cc2)(C(F)(F)F)C(F)(F)F)cc1 ,1 O=[C]c1ccc(C(c2ccc([C]=O)cc2)(C(F)(F)F)C(F)(F)F)cc1. Metal clusters: 2 O[C]O[Zn]123O[C]O[Zn](O[C]O)(O[C]O1)(O[C]O2)O[C]O3. RCSR code: pcu. The MOF has largest included sphere 4.94 A, density 1.61 g/cm3, surface area 3888.30 m2/g, accessible volume 0.17 cm3/g