Li2C15N9H27S is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Li2C15N9H27S cluster. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one N(1), one N(2), one N(4), and one N(7) atom to form a mixture of edge and corner-sharing LiN4 tetrahedra. The Li(1)-N(1) bond length is 2.04 Å. The Li(1)-N(2) bond length is 2.05 Å. The Li(1)-N(4) bond length is 2.02 Å. The Li(1)-N(7) bond length is 2.08 Å. In the second Li site, Li(2) is bonded to one N(1), one N(2), one N(7), and one N(9) atom to form a mixture of edge and corner-sharing LiN4 tetrahedra. The Li(2)-N(1) bond length is 2.06 Å. The Li(2)-N(2) bond length is 2.09 Å. The Li(2)-N(7) bond length is 2.10 Å. The Li(2)-N(9) bond length is 2.04 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-N(3) bond length is 1.41 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(4), and one H(5) atom. The C(2)-N(1) bond length is 1.48 Å. The C(2)-H(4) bond length is 1.10 Å. The C(2)-H(5) bond length is 1.11 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(6), and one H(7) atom. The C(3)-N(3) bond length is 1.46 Å. The C(3)-H(6) bond length is 1.10 Å. The C(3)-H(7) bond length is 1.11 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(8), and one H(9) atom. The C(4)-N(3) bond length is 1.46 Å. The C(4)-H(8) bond length is 1.11 Å. The C(4)-H(9) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(10), and one H(11) atom. The C(5)-N(2) bond length is 1.48 Å. The C(5)-H(10) bond length is 1.11 Å. The C(5)-H(11) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(4), one N(5), and one N(6) atom. The C(6)-N(4) bond length is 1.30 Å. The C(6)-N(5) bond length is 1.36 Å. The C(6)-N(6) bond length is 1.39 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(12), and one H(13) atom. The C(7)-N(4) bond length is 1.48 Å. The C(7)-H(12) bond length is 1.10 Å. The C(7)-H(13) bond length is 1.10 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(14), and one H(15) atom. The C(8)-N(6) bond length is 1.46 Å. The C(8)-H(14) bond length is 1.11 Å. The C(8)-H(15) bond length is 1.10 Å. In the ninth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(16), and one H(17) atom. The C(9)-N(6) bond length is 1.46 Å. The C(9)-H(16) bond length is 1.10 Å. The C(9)-H(17) bond length is 1.11 Å. In the tenth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(5), one H(18), and one H(19) atom. The C(10)-N(5) bond length is 1.47 Å. The C(10)-H(18) bond length is 1.10 Å. The C(10)-H(19) bond length is 1.10 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(7), one H(20), and one H(21) atom. The C(11)-N(7) bond length is 1.48 Å. The C(11)-H(20) bond length is 1.10 Å. The C(11)-H(21) bond length is 1.10 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one N(8), one H(22), and one H(23) atom. The C(12)-N(8) bond length is 1.46 Å. The C(12)-H(22) bond length is 1.11 Å. The C(12)-H(23) bond length is 1.10 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one N(7), one N(8), and one S(1) atom. The C(13)-N(7) bond length is 1.33 Å. The C(13)-N(8) bond length is 1.38 Å. The C(13)-S(1) bond length is 1.72 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(8), one H(24), and one H(25) atom. The C(14)-N(8) bond length is 1.44 Å. The C(14)-H(24) bond length is 1.11 Å. The C(14)-H(25) bond length is 1.10 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one N(9), one H(26), and one H(27) atom. The C(15)-N(9) bond length is 1.47 Å. The C(15)-H(26) bond length is 1.10 Å. The C(15)-H(27) bond length is 1.10 Å. There are nine inequivalent N sites. In the first N site, N(1) is bonded to one Li(1), one Li(2), one C(1), and one C(2) atom to form NLi2C2 tetrahedra that share  a cornercorner with one N(2)Li2C2 tetrahedra,  a cornercorner with one N(9)LiH2C tetrahedra, corners with two equivalent N(7)Li2C2 tetrahedra, and  an edgeedge with one N(2)Li2C2 tetrahedra. In the second N site, N(2) is bonded to one Li(1), one Li(2), one C(1), and one C(5) atom to form NLi2C2 tetrahedra that share  a cornercorner with one N(1)Li2C2 tetrahedra,  a cornercorner with one N(9)LiH2C tetrahedra, corners with two equivalent N(7)Li2C2 tetrahedra, and  an edgeedge with one N(1)Li2C2 tetrahedra. In the third N site, N(3) is bonded in a trigonal non-coplanar geometry to one C(1), one C(3), and one C(4) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Li(1), one C(6), and one C(7) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one H(1) atom. The N(5)-H(1) bond length is 1.03 Å. In the sixth N site, N(6) is bonded in a trigonal non-coplanar geometry to one C(6), one C(8), and one C(9) atom. In the seventh N site, N(7) is bonded to one Li(1), one Li(2), one C(11), and one C(13) atom to form distorted NLi2C2 tetrahedra that share  a cornercorner with one N(9)LiH2C tetrahedra, corners with two equivalent N(1)Li2C2 tetrahedra, and corners with two equivalent N(2)Li2C2 tetrahedra. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(14) atom. In the ninth N site, N(9) is bonded to one Li(2), one C(15), one H(2), and one H(3) atom to form distorted corner-sharing NLiH2C tetrahedra. The N(9)-H(2) bond length is 1.03 Å. The N(9)-H(3) bond length is 1.02 Å. There are twenty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(9) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(5) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(7) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(7) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(8) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(8) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(9) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(9) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(10) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(10) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(11) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(11) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(12) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(12) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(14) atom. In the twenty-fifth H site, H(25) is bonded in a single-bond geometry to one C(14) atom. In the twenty-sixth H site, H(26) is bonded in a single-bond geometry to one C(15) atom. In the twenty-seventh H site, H(27) is bonded in a single-bond geometry to one C(15) atom. S(1) is bonded in a single-bond geometry to one C(13) atom. Linkers: 2 NCCN1CC[N]C1=S ,2 C1CN2CCN=C2[N]1. Metal clusters: 4 [Li]. The MOF has largest included sphere 4.30 A, density 1.08 g/cm3, surface area 5646.73 m2/g, accessible volume 0.38 cm3/g