AgC7NH2O5(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a AgC7NH2O5 framework. In the AgC7NH2O5 framework, Ag(1) is bonded in a 8-coordinate geometry to one C(6), one C(7), one O(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms. The Ag(1)-C(6) bond length is 2.49 Å. The Ag(1)-C(7) bond length is 2.73 Å. The Ag(1)-O(1) bond length is 2.47 Å. The Ag(1)-O(2) bond length is 2.66 Å. The Ag(1)-O(4) bond length is 2.86 Å. The Ag(1)-O(5) bond length is 2.34 Å. There is one shorter (2.47 Å) and one longer (2.52 Å) Ag(1)-O(3) bond length. There are seven inequivalent C sites. In the first C site, C(6) is bonded in a distorted single-bond geometry to one Ag(1) and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the second C site, C(7) is bonded in a distorted single-bond geometry to one Ag(1), one C(8), and one H(4) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-H(4) bond length is 1.09 Å. In the third C site, C(8) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(9) atom. The C(8)-C(3) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.47 Å. In the fourth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(9), and one N(1) atom. The C(1)-C(2) bond length is 1.43 Å. The C(1)-C(9) bond length is 1.45 Å. The C(1)-N(1) bond length is 1.42 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(1), one C(8), and one O(5) atom. The C(9)-O(5) bond length is 1.26 Å. In the sixth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(3), and one O(4) atom. The C(2)-O(3) bond length is 1.24 Å. The C(2)-O(4) bond length is 1.38 Å. In the seventh C site, C(3) is bonded in a distorted single-bond geometry to one C(8) and one O(4) atom. The C(3)-O(4) bond length is 1.37 Å. N(1) is bonded in a trigonal planar geometry to one C(1), one O(1), and one O(2) atom. The N(1)-O(1) bond length is 1.26 Å. The N(1)-O(2) bond length is 1.26 Å. There are two inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. There are five inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one N(1) atom. In the second O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one C(2) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Ag(1), one C(2), and one C(3) atom. In the fourth O site, O(1) is bonded in a distorted water-like geometry to one Ag(1) and one N(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one C(9) atom. Linkers: 4 O=C1Oc2ccccc2C(=O)[C]1[N+](=O)[O-]. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.53 A, density 2.47 g/cm3, surface area 2741.42 m2/g, accessible volume 0.06 cm3/g