ZnC16H16(NO)4(CH)2 crystallizes in the orthorhombic Pna2_1 space group. The structure consists of eight 02329_fluka molecules inside a ZnC16H16(NO)4 framework. In the ZnC16H16(NO)4 framework, Zn(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(4), one O(1), and one O(4) atom. The Zn(1)-N(1) bond length is 2.02 Å. The Zn(1)-N(4) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 2.02 Å. The Zn(1)-O(4) bond length is 1.96 Å. There are sixteen inequivalent C sites. In the first C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(18) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(18) bond length is 1.09 Å. In the second C site, C(17) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(18) atom. The C(17)-C(12) bond length is 1.41 Å. The C(17)-C(18) bond length is 1.50 Å. In the third C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(3), and one O(4) atom. The C(18)-O(3) bond length is 1.25 Å. The C(18)-O(4) bond length is 1.29 Å. In the fourth C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one H(3), one H(4), and one H(5) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-H(4) bond length is 1.10 Å. The C(1)-H(5) bond length is 1.10 Å. In the fifth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(2) bond length is 1.35 Å. In the sixth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(8) bond length is 1.46 Å. In the seventh C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.49 Å. The C(4)-N(1) bond length is 1.35 Å. In the eighth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one H(6), one H(7), and one H(8) atom. The C(5)-H(6) bond length is 1.10 Å. The C(5)-H(7) bond length is 1.10 Å. The C(5)-H(8) bond length is 1.10 Å. In the ninth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(7), one H(10), one H(11), and one H(9) atom. The C(6)-C(7) bond length is 1.49 Å. The C(6)-H(10) bond length is 1.10 Å. The C(6)-H(11) bond length is 1.10 Å. The C(6)-H(9) bond length is 1.10 Å. In the tenth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one N(3) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(3) bond length is 1.35 Å. In the eleventh C site, C(8) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.41 Å. In the twelfth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(4) atom. The C(9)-C(10) bond length is 1.49 Å. The C(9)-N(4) bond length is 1.35 Å. In the thirteenth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(12), one H(13), and one H(14) atom. The C(10)-H(12) bond length is 1.10 Å. The C(10)-H(13) bond length is 1.10 Å. The C(10)-H(14) bond length is 1.10 Å. In the fourteenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-O(1) bond length is 1.28 Å. The C(11)-O(2) bond length is 1.26 Å. In the fifteenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.40 Å. In the sixteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(15) atom. The C(13)-H(15) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Zn(1), one C(4), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one C(2), one N(1), and one H(1) atom. The N(2)-H(1) bond length is 1.06 Å. In the third N site, N(3) is bonded in a 2-coordinate geometry to one C(7), one N(4), and one H(2) atom. The N(3)-N(4) bond length is 1.36 Å. The N(3)-H(2) bond length is 1.04 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(9), and one N(3) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one N(2) and one O(2) atom. The H(1)-O(2) bond length is 1.56 Å. In the second H site, H(2) is bonded in a distorted bent 150 degrees geometry to one N(3) and one O(3) atom. The H(2)-O(3) bond length is 1.66 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(11) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(11) and one H(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one C(18) and one H(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(18) atom. Linkers: 2 [O]C(=O)c1ccccc1C([O])=O ,1 [CH2].[CH2].[CH2].[CH2]/C([N])=[C]\[C][C][N].[CH3].[CH3].[CH3].[CH3].[CH3].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]O[Zn][O].[C][CH][C].[C][C].[C][C].[C][C].[C][C].[C][C][C].[C][C][N].[C][NH].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N][N].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][Zn].[O][Zn].[O][Zn][O].[Zn].[Zn].[Zn]. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.95 A, density 1.31 g/cm3, surface area 5169.33 m2/g, accessible volume 0.28 cm3/g