CuC12H8(NO3)2(CH2)6CH is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, twelve 02329_fluka molecules, and two CuC12H8(NO3)2 clusters. In each CuC12H8(NO3)2 cluster, Cu(1) is bonded in a square pyramidal geometry to one N(1), one N(2), one O(2), one O(4), and one O(5) atom. The Cu(1)-N(1) bond length is 2.00 Å. The Cu(1)-N(2) bond length is 2.00 Å. The Cu(1)-O(2) bond length is 1.94 Å. The Cu(1)-O(4) bond length is 1.98 Å. The Cu(1)-O(5) bond length is 2.40 Å. There are twelve inequivalent C sites. In the first C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(2)-O(1) bond length is 1.25 Å. The C(2)-O(2) bond length is 1.30 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(3)-O(3) bond length is 1.27 Å. The C(3)-O(4) bond length is 1.29 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(6), one C(9), and one N(2) atom. The C(4)-C(6) bond length is 1.40 Å. The C(4)-C(9) bond length is 1.47 Å. The C(4)-N(2) bond length is 1.36 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(16), one C(4), and one H(4) atom. The C(6)-C(16) bond length is 1.39 Å. The C(6)-H(4) bond length is 1.09 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(7) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(7) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(4), one C(8), and one N(1) atom. The C(9)-N(1) bond length is 1.36 Å. In the seventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(15), one N(1), and one H(10) atom. The C(11)-C(15) bond length is 1.40 Å. The C(11)-N(1) bond length is 1.34 Å. The C(11)-H(10) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(2), and one H(13) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-N(2) bond length is 1.34 Å. The C(13)-H(13) bond length is 1.09 Å. In the ninth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(16), and one H(14) atom. The C(14)-C(16) bond length is 1.39 Å. The C(14)-H(14) bond length is 1.09 Å. In the tenth C site, C(15) is bonded in a distorted single-bond geometry to one C(11) and one H(15) atom. The C(15)-H(15) bond length is 1.09 Å. In the eleventh C site, C(16) is bonded in a distorted trigonal planar geometry to one C(14), one C(6), and one H(16) atom. The C(16)-H(16) bond length is 1.09 Å. In the twelfth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(18)-O(5) bond length is 1.24 Å. The C(18)-O(6) bond length is 1.32 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(4) atom. There are eight inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(21) is bonded in a linear geometry to one O(3) and one O(6) atom. The H(21)-O(3) bond length is 1.44 Å. The H(21)-O(6) bond length is 1.07 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(3) and one H(21) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cu(1) and one C(18) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one C(18) and one H(21) atom. Linkers: 2 [O]C(=O)CCCCC(=O)O. Metal clusters: 2 [Cu]. The MOF has largest included sphere 3.50 A, density 1.44 g/cm3, surface area 4902.17 m2/g, accessible volume 0.17 cm3/g