ZnC8H10(NO2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two ZnC8H10(NO2)2 clusters. Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), and two equivalent O(1) atoms. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-N(2) bond length is 2.02 Å. Both Zn(1)-O(1) bond lengths are 2.01 Å. There are four inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(6) atom. The C(4)-C(2) bond length is 1.40 Å. The C(4)-H(6) bond length is 1.09 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.26 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.40 Å. In the fourth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(3)-H(5) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Zn(1), one H(2), and two equivalent H(1) atoms to form distorted corner-sharing NZnH3 tetrahedra. The N(1)-H(2) bond length is 1.03 Å. Both N(1)-H(1) bond lengths are 1.02 Å. In the second N site, N(2) is bonded to one Zn(1), one H(4), and two equivalent H(3) atoms to form distorted corner-sharing NZnH3 tetrahedra. The N(2)-H(4) bond length is 1.02 Å. Both N(2)-H(3) bond lengths are 1.03 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Linkers: 4 [O]C(=O)c1ccc([C]=O)cc1 ,2 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.43 A, density 1.93 g/cm3, surface area 4142.17 m2/g, accessible volume 0.06 cm3/g