(CH2)2(C6H5NH)2CdC2(O2Cl)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; eight 1-methyl-1,2-dihydropyridine molecules; and four CdC2(O2Cl)2 clusters. In each CdC2(O2Cl)2 cluster, Cd(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent Cl(1) atoms. Both Cd(1)-O(1) bond lengths are 2.29 Å. Both Cd(1)-Cl(1) bond lengths are 2.48 Å. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.25 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Cl(1) is bonded in a single-bond geometry to one Cd(1) atom. Linkers: 2 [O]C(=O)[C@@H](CC[C@@H](C([O])=O)N1[CH]C=CC=C1)N1[CH]C=CC=C1 ,1 [O]C(=O)[C@@H](CC[C@@H](C([O])=O)N1[CH]C=C[C]=C1)N1[CH]C=CC=C1 ,1 [O]C(=O)[C@@H](CC[C@@H](C([O])=O)N1[CH]C=CC=C1)N1[CH][C]=CC=C1. Metal clusters: 2 O=[C]O[Cd](Cl)(Cl)O[C]=O. The MOF has largest included sphere 2.43 A, density 1.79 g/cm3, surface area 4261.03 m2/g, accessible volume 0.16 cm3/g