Mn7C132H84(NO8)6(CH3)4(C3H2S2)10 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules and five tetrathiafulvalene molecules inside a Mn7C132H84(NO8)6 framework. In the Mn7C132H84(NO8)6 framework, there are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(7) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles are 72°. Both Mn(1)-O(3) bond lengths are 2.05 Å. Both Mn(1)-O(6) bond lengths are 2.36 Å. Both Mn(1)-O(7) bond lengths are 2.01 Å. In the second Mn site, Mn(2) is bonded to one O(11), one O(14), one O(20), one O(23), one O(4), and one O(5) atom to form a mixture of edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles are 72°. The Mn(2)-O(11) bond length is 2.04 Å. The Mn(2)-O(14) bond length is 2.12 Å. The Mn(2)-O(20) bond length is 2.28 Å. The Mn(2)-O(23) bond length is 2.10 Å. The Mn(2)-O(4) bond length is 2.27 Å. The Mn(2)-O(5) bond length is 2.06 Å. In the third Mn site, Mn(3) is bonded to one O(17), one O(19), one O(20), one O(4), one O(6), and one O(8) atom to form a mixture of distorted edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles are 72°. The Mn(3)-O(17) bond length is 2.06 Å. The Mn(3)-O(19) bond length is 2.40 Å. The Mn(3)-O(20) bond length is 2.20 Å. The Mn(3)-O(4) bond length is 2.15 Å. The Mn(3)-O(6) bond length is 2.21 Å. The Mn(3)-O(8) bond length is 2.03 Å. In the fourth Mn site, Mn(4) is bonded to one O(12), one O(13), one O(14), one O(15), one O(16), and one O(22) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles are 72°. The Mn(4)-O(12) bond length is 2.19 Å. The Mn(4)-O(13) bond length is 2.07 Å. The Mn(4)-O(14) bond length is 2.28 Å. The Mn(4)-O(15) bond length is 2.29 Å. The Mn(4)-O(16) bond length is 2.14 Å. The Mn(4)-O(22) bond length is 2.07 Å. There are sixty-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(4) and one H(1) atom. The C(1)-C(4) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(62) atom. The C(3)-C(5) bond length is 1.39 Å. The C(3)-C(62) bond length is 1.49 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(6) atom. The C(4)-C(10) bond length is 1.48 Å. The C(4)-C(6) bond length is 1.42 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3), one C(6), and one H(3) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.48 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one O(1) atom. The C(7)-C(8) bond length is 1.48 Å. The C(7)-O(1) bond length is 1.24 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(14), one C(7), and one C(9) atom. The C(8)-C(14) bond length is 1.39 Å. The C(8)-C(9) bond length is 1.41 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(8) atom. The C(9)-C(10) bond length is 1.47 Å. The C(9)-C(11) bond length is 1.40 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(4), one C(9), and one O(2) atom. The C(10)-O(2) bond length is 1.25 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(11)-H(4) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(5,11) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(5,11) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(15) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-C(15) bond length is 1.49 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(8), and one H(6) atom. The C(14)-H(6) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(3), and one O(4) atom. The C(15)-O(3) bond length is 1.27 Å. The C(15)-O(4) bond length is 1.29 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(7), and one O(8) atom. The C(16)-C(17) bond length is 1.49 Å. The C(16)-O(7) bond length is 1.28 Å. The C(16)-O(8) bond length is 1.27 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(19) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-C(19) bond length is 1.41 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(63), and one H(7) atom. The C(18)-C(63) bond length is 1.39 Å. The C(18)-H(7) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(17) and one H(8) atom. The C(19)-H(8) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(9) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(9) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(61), and one C(63) atom. The C(21)-C(61) bond length is 1.47 Å. The C(21)-C(63) bond length is 1.42 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(19), and one O(20) atom. The C(22)-C(29) bond length is 1.49 Å. The C(22)-O(19) bond length is 1.26 Å. The C(22)-O(20) bond length is 1.30 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(25), one C(29), and one H(10) atom. The C(23)-C(25) bond length is 1.40 Å. The C(23)-C(29) bond length is 1.39 Å. The C(23)-H(10) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(25), one C(26), and one C(27) atom. The C(24)-C(25) bond length is 1.42 Å. The C(24)-C(26) bond length is 1.47 Å. The C(24)-C(27) bond length is 1.40 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(23), one C(24), and one C(34) atom. The C(25)-C(34) bond length is 1.48 Å. In the twenty-sixth C site, C(26) is bonded in a single-bond geometry to one C(24), one C(32), and one O(10) atom. The C(26)-C(32) bond length is 1.48 Å. The C(26)-O(10) bond length is 1.25 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(24) and one H(5,11) atom. The C(27)-H(5,11) bond length is 1.09 Å. In the twenty-eighth C site, C(28) is bonded in a distorted single-bond geometry to one C(29) and one H(12) atom. The C(28)-C(29) bond length is 1.41 Å. The C(28)-H(12) bond length is 1.09 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(22), one C(23), and one C(28) atom. In the thirtieth C site, C(30) is bonded in a distorted single-bond geometry to one C(36) and one H(13) atom. The C(30)-C(36) bond length is 1.41 Å. The C(30)-H(13) bond length is 1.09 Å. In the thirty-first C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(14) atom. The C(31)-C(32) bond length is 1.40 Å. The C(31)-H(14) bond length is 1.09 Å. In the thirty-second C site, C(32) is bonded in a trigonal planar geometry to one C(26), one C(31), and one C(33) atom. The C(32)-C(33) bond length is 1.42 Å. In the thirty-third C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(35) atom. The C(33)-C(34) bond length is 1.48 Å. The C(33)-C(35) bond length is 1.40 Å. In the thirty-fourth C site, C(34) is bonded in a distorted single-bond geometry to one C(25), one C(33), and one O(9) atom. The C(34)-O(9) bond length is 1.25 Å. In the thirty-fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(33), one C(36), and one H(15) atom. The C(35)-C(36) bond length is 1.39 Å. The C(35)-H(15) bond length is 1.09 Å. In the thirty-sixth C site, C(36) is bonded in a trigonal planar geometry to one C(30), one C(35), and one C(37) atom. The C(36)-C(37) bond length is 1.50 Å. In the thirty-seventh C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(36), one O(11), and one O(12) atom. The C(37)-O(11) bond length is 1.28 Å. The C(37)-O(12) bond length is 1.27 Å. In the thirty-eighth C site, C(39) is bonded to one N(3), one H(19), one H(20), and one H(21) atom to form corner-sharing CH3N tetrahedra. The C(39)-N(3) bond length is 1.46 Å. The C(39)-H(19) bond length is 1.10 Å. The C(39)-H(20) bond length is 1.10 Å. The C(39)-H(21) bond length is 1.09 Å. In the thirty-ninth C site, C(40) is bonded to one N(1), one H(22), one H(23), and one H(24) atom to form corner-sharing CH3N tetrahedra. The C(40)-N(1) bond length is 1.46 Å. The C(40)-H(22) bond length is 1.10 Å. The C(40)-H(23) bond length is 1.10 Å. The C(40)-H(24) bond length is 1.09 Å. In the fortieth C site, C(41) is bonded to one N(1), one H(25), one H(26), and one H(27) atom to form corner-sharing CH3N tetrahedra. The C(41)-N(1) bond length is 1.46 Å. The C(41)-H(25) bond length is 1.10 Å. The C(41)-H(26) bond length is 1.10 Å. The C(41)-H(27) bond length is 1.09 Å. In the forty-first C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(43), one O(5), and one O(6) atom. The C(42)-C(43) bond length is 1.48 Å. The C(42)-O(5) bond length is 1.27 Å. The C(42)-O(6) bond length is 1.29 Å. In the forty-second C site, C(43) is bonded in a trigonal planar geometry to one C(42), one C(44), and one C(48) atom. The C(43)-C(44) bond length is 1.40 Å. The C(43)-C(48) bond length is 1.40 Å. In the forty-third C site, C(44) is bonded in a distorted trigonal planar geometry to one C(43), one C(45), and one H(28) atom. The C(44)-C(45) bond length is 1.38 Å. The C(44)-H(28) bond length is 1.08 Å. In the forty-fourth C site, C(45) is bonded in a distorted single-bond geometry to one C(44), one C(46), and one H(29) atom. The C(45)-C(46) bond length is 1.40 Å. The C(45)-H(29) bond length is 1.09 Å. In the forty-fifth C site, C(46) is bonded in a trigonal planar geometry to one C(45), one C(47), and one C(61) atom. The C(46)-C(47) bond length is 1.42 Å. The C(46)-C(61) bond length is 1.47 Å. In the forty-sixth C site, C(47) is bonded in a trigonal planar geometry to one C(46), one C(48), and one C(65) atom. The C(47)-C(48) bond length is 1.40 Å. The C(47)-C(65) bond length is 1.48 Å. In the forty-seventh C site, C(48) is bonded in a distorted single-bond geometry to one C(43), one C(47), and one H(30) atom. The C(48)-H(30) bond length is 1.09 Å. In the forty-eighth C site, C(49) is bonded in a distorted single-bond geometry to one C(54) and one H(31) atom. The C(49)-C(54) bond length is 1.40 Å. The C(49)-H(31) bond length is 1.09 Å. In the forty-ninth C site, C(50) is bonded in a distorted single-bond geometry to one C(51) and one H(32) atom. The C(50)-C(51) bond length is 1.41 Å. The C(50)-H(32) bond length is 1.09 Å. In the fiftieth C site, C(51) is bonded in a trigonal planar geometry to one C(50), one C(52), and one C(56) atom. The C(51)-C(52) bond length is 1.39 Å. The C(51)-C(56) bond length is 1.48 Å. In the fifty-first C site, C(52) is bonded in a distorted single-bond geometry to one C(51), one C(53), and one H(33) atom. The C(52)-C(53) bond length is 1.40 Å. The C(52)-H(33) bond length is 1.09 Å. In the fifty-second C site, C(53) is bonded in a trigonal planar geometry to one C(52), one C(54), and one C(55) atom. The C(53)-C(54) bond length is 1.42 Å. The C(53)-C(55) bond length is 1.47 Å. In the fifty-third C site, C(54) is bonded in a trigonal planar geometry to one C(49), one C(53), and one C(55) atom. The C(54)-C(55) bond length is 1.48 Å. In the fifty-fourth C site, C(55) is bonded in a distorted single-bond geometry to one C(53), one C(54), and one O(18) atom. The C(55)-O(18) bond length is 1.25 Å. In the fifty-fifth C site, C(56) is bonded in a bent 120 degrees geometry to one C(51), one O(14), and one O(15) atom. The C(56)-O(14) bond length is 1.29 Å. The C(56)-O(15) bond length is 1.27 Å. In the fifty-sixth C site, C(57) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(16) atom. The C(57)-N(2) bond length is 1.35 Å. The C(57)-O(16) bond length is 1.26 Å. In the fifty-seventh C site, C(59) is bonded to one N(2), one H(37), one H(38), and one H(39) atom to form corner-sharing CH3N tetrahedra. The C(59)-N(2) bond length is 1.47 Å. The C(59)-H(37) bond length is 1.10 Å. The C(59)-H(38) bond length is 1.10 Å. The C(59)-H(39) bond length is 1.10 Å. In the fifty-eighth C site, C(60) is bonded to one N(2), one H(40), one H(41), and one H(42) atom to form corner-sharing CH3N tetrahedra. The C(60)-N(2) bond length is 1.46 Å. The C(60)-H(40) bond length is 1.10 Å. The C(60)-H(41) bond length is 1.10 Å. The C(60)-H(42) bond length is 1.09 Å. In the fifty-ninth C site, C(61) is bonded in a distorted single-bond geometry to one C(21), one C(46), and one O(21) atom. The C(61)-O(21) bond length is 1.25 Å. In the sixtieth C site, C(62) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(22), and one O(23) atom. The C(62)-O(22) bond length is 1.28 Å. The C(62)-O(23) bond length is 1.28 Å. In the sixty-first C site, C(63) is bonded in a trigonal planar geometry to one C(18), one C(21), and one C(65) atom. The C(63)-C(65) bond length is 1.48 Å. In the sixty-second C site, C(64) is bonded to one N(3), one H(43), one H(44), and one H(45) atom to form corner-sharing CH3N tetrahedra. The C(64)-N(3) bond length is 1.46 Å. The C(64)-H(43) bond length is 1.10 Å. The C(64)-H(44) bond length is 1.10 Å. The C(64)-H(45) bond length is 1.09 Å. In the sixty-third C site, C(65) is bonded in a distorted single-bond geometry to one C(47), one C(63), and one O(24) atom. The C(65)-O(24) bond length is 1.24 Å. In the sixty-fourth C site, C(66) is bonded in a distorted trigonal planar geometry to one C(67), one N(3), and one O(17) atom. The C(66)-C(67) bond length is 1.50 Å. The C(66)-N(3) bond length is 1.34 Å. The C(66)-O(17) bond length is 1.27 Å. In the sixty-fifth C site, C(67) is bonded in a trigonal non-coplanar geometry to one C(66), one H(46), one H(47), and one H(48) atom. The C(67)-H(46) bond length is 1.09 Å. The C(67)-H(47) bond length is 1.10 Å. The C(67)-H(48) bond length is 1.10 Å. In the sixty-sixth C site, C(68) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(13) atom. The C(68)-N(1) bond length is 1.34 Å. The C(68)-O(13) bond length is 1.27 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(40), one C(41), and one C(68) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(57), one C(59), and one C(60) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(39), one C(64), and one C(66) atom. There are forty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(5,11) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(28) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(30) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(35) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(39) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(39) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(39) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(40) atom. In the nineteenth H site, H(23) is bonded in a single-bond geometry to one C(40) atom. In the twentieth H site, H(24) is bonded in a single-bond geometry to one C(40) atom. In the twenty-first H site, H(25) is bonded in a single-bond geometry to one C(41) atom. In the twenty-second H site, H(26) is bonded in a single-bond geometry to one C(41) atom. In the twenty-third H site, H(27) is bonded in a single-bond geometry to one C(41) atom. In the twenty-fourth H site, H(28) is bonded in a single-bond geometry to one C(44) atom. In the twenty-fifth H site, H(29) is bonded in a single-bond geometry to one C(45) atom. In the twenty-sixth H site, H(30) is bonded in a single-bond geometry to one C(48) atom. In the twenty-seventh H site, H(31) is bonded in a single-bond geometry to one C(49) atom. In the twenty-eighth H site, H(32) is bonded in a single-bond geometry to one C(50) atom. In the twenty-ninth H site, H(33) is bonded in a single-bond geometry to one C(52) atom. In the thirtieth H site, H(37) is bonded in a single-bond geometry to one C(59) atom. In the thirty-first H site, H(38) is bonded in a single-bond geometry to one C(59) atom. In the thirty-second H site, H(39) is bonded in a single-bond geometry to one C(59) atom. In the thirty-third H site, H(40) is bonded in a single-bond geometry to one C(60) atom. In the thirty-fourth H site, H(41) is bonded in a single-bond geometry to one C(60) atom. In the thirty-fifth H site, H(42) is bonded in a single-bond geometry to one C(60) atom. In the thirty-sixth H site, H(43) is bonded in a single-bond geometry to one C(64) atom. In the thirty-seventh H site, H(44) is bonded in a single-bond geometry to one C(64) atom. In the thirty-eighth H site, H(45) is bonded in a single-bond geometry to one C(64) atom. In the thirty-ninth H site, H(46) is bonded in a single-bond geometry to one C(67) atom. In the fortieth H site, H(47) is bonded in a single-bond geometry to one C(67) atom. In the forty-first H site, H(48) is bonded in a single-bond geometry to one C(67) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(7) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(10) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one C(15) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Mn(2) and one C(42) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Mn(3), and one C(42) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(16) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mn(3) and one C(16) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(34) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(26) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mn(2) and one C(37) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mn(4) and one C(37) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Mn(4) and one C(68) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Mn(2), one Mn(4), and one C(56) atom. In the fifteenth O site, O(15) is bonded in a distorted L-shaped geometry to one Mn(4) and one C(56) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one Mn(4) and one C(57) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Mn(3) and one C(66) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one C(55) atom. In the nineteenth O site, O(19) is bonded in a distorted L-shaped geometry to one Mn(3) and one C(22) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Mn(2), one Mn(3), and one C(22) atom. In the twenty-first O site, O(21) is bonded in a single-bond geometry to one C(61) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Mn(4) and one C(62) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(62) atom. In the twenty-fourth O site, O(24) is bonded in a single-bond geometry to one C(65) atom. Linkers: 1 [O]C(=O)c1ccc2c(c1)C(=O)c1ccc(C([O])=O)cc1C2=O ,6 [O]C(=O)c1ccc2c(c1)C(=O)c1cc(C([O])=O)ccc1C2=O. Metal clusters: 7 [Mn]. The MOF has largest included sphere 2.93 A, density 1.56 g/cm3, surface area 4393.22 m2/g, accessible volume 0.19 cm3/g