CHCH3PbC12N3H10O5CH3CO is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two 02329_fluka molecules, two dimethyl ether molecules, and one PbC12N3H10O5 cluster. In the PbC12N3H10O5 cluster, Pb(1) is bonded in a 5-coordinate geometry to one O(1), one O(4), one O(6), and two equivalent O(3) atoms. The Pb(1)-O(1) bond length is 2.69 Å. The Pb(1)-O(4) bond length is 2.70 Å. The Pb(1)-O(6) bond length is 2.63 Å. There is one shorter (2.42 Å) and one longer (2.51 Å) Pb(1)-O(3) bond length. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(4) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(4) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.49 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(3)-H(5) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(6) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(6) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(7) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(7) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one O(1) atom. The C(6)-N(2) bond length is 1.36 Å. The C(6)-O(1) bond length is 1.26 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(3), and one H(8) atom. The C(7)-C(8) bond length is 1.44 Å. The C(7)-N(3) bond length is 1.30 Å. The C(7)-H(8) bond length is 1.10 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(7), and one C(9) atom. The C(8)-C(13) bond length is 1.41 Å. The C(8)-C(9) bond length is 1.42 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(9) atom. The C(9)-H(9) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one O(3) atom. The C(11)-O(3) bond length is 1.32 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(11) atom. The C(13)-H(11) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(15)-O(4) bond length is 1.28 Å. The C(15)-O(5) bond length is 1.28 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one C(1) and one C(5) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one C(6), one N(3), and one H(3) atom. The N(2)-N(3) bond length is 1.37 Å. The N(2)-H(3) bond length is 1.05 Å. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one C(7) and one N(2) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(6) atom. The H(1)-O(6) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(6) atom. The H(2)-O(6) bond length is 1.00 Å. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Pb(1) and one C(6) atom. In the second O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one C(11) atom. In the third O site, O(4) is bonded in a single-bond geometry to one Pb(1) and one C(15) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(15) atom. In the fifth O site, O(6) is bonded in a water-like geometry to one Pb(1), one H(1), and one H(2) atom. Linkers: 2 COc1cc(/C=N/NC(=O)c2cccnc2)ccc1[O]. Metal clusters: 2 [Pb]. The MOF has largest included sphere 1.74 A, density 2.23 g/cm3, surface area 3247.71 m2/g, accessible volume 0.12 cm3/g