Zn3C36H30(NO3)4(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one Zn3C36H30(NO3)4 cluster. In the Zn3C36H30(NO3)4 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form corner-sharing ZnO6 octahedra. Both Zn(1)-O(1) bond lengths are 2.20 Å. Both Zn(1)-O(2) bond lengths are 2.04 Å. Both Zn(1)-O(5) bond lengths are 2.21 Å. In the second Zn site, Zn(2) is bonded to one N(1), one O(1), one O(3), and one O(4) atom to form corner-sharing ZnNO3 tetrahedra. The corner-sharing octahedral tilt angles are 79°. The Zn(2)-N(1) bond length is 1.99 Å. The Zn(2)-O(1) bond length is 2.01 Å. The Zn(2)-O(3) bond length is 1.94 Å. The Zn(2)-O(4) bond length is 2.00 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(7) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-C(4) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.40 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(2), and one O(4) atom. The C(2)-O(2) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(3), and one O(5) atom. The C(3)-C(15) bond length is 1.50 Å. The C(3)-O(3) bond length is 1.29 Å. The C(3)-O(5) bond length is 1.26 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(4)-H(1) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(1), and one O(6) atom. The C(5)-C(8) bond length is 1.49 Å. The C(5)-O(1) bond length is 1.33 Å. The C(5)-O(6) bond length is 1.24 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(15) and one H(2,6) atom. The C(6)-C(15) bond length is 1.40 Å. The C(6)-H(2,6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(7)-H(3) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(16), and one C(5) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-C(16) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(4), and one H(5) atom. The C(9)-N(2) bond length is 1.46 Å. The C(9)-H(4) bond length is 1.10 Å. The C(9)-H(5) bond length is 1.10 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(12), one C(17), and one N(2) atom. The C(10)-C(12) bond length is 1.39 Å. The C(10)-C(17) bond length is 1.49 Å. The C(10)-N(2) bond length is 1.36 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(15) and one H(2,6) atom. The C(11)-C(15) bond length is 1.40 Å. The C(11)-H(2,6) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(10), one C(19), and one H(7) atom. The C(12)-C(19) bond length is 1.40 Å. The C(12)-H(7) bond length is 1.08 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(13)-H(8) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(6) atom. In the fifteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(8) and one H(11) atom. The C(16)-H(11) bond length is 1.09 Å. In the sixteenth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one H(12), one H(13), and one H(14) atom. The C(17)-H(12) bond length is 1.09 Å. The C(17)-H(13) bond length is 1.10 Å. The C(17)-H(14) bond length is 1.10 Å. In the seventeenth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one C(19), one H(15), one H(16), and one H(17) atom. The C(18)-C(19) bond length is 1.49 Å. The C(18)-H(15) bond length is 1.10 Å. The C(18)-H(16) bond length is 1.10 Å. The C(18)-H(17) bond length is 1.10 Å. In the eighteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(12), one C(18), and one N(1) atom. The C(19)-N(1) bond length is 1.35 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(19), and one N(2) atom. The N(1)-N(2) bond length is 1.37 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(10), one C(9), and one N(1) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2,6) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(18) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(2), and one C(5) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(5) atom. Linkers: 3 [O]C(=O)c1ccc(C([O])=O)cc1 ,2 C[C]N([N])CCCCn1nc(C)cc1C ,1 Cc1cc(C)n(CCCCn2nc(C)cc2C)n1. Metal clusters: 1 O=[C]O[Zn]1O[C]O[Zn]2(O[C]O1)O[C]O[Zn](O[C]=O)O[C]O2. RCSR code: pcu. The MOF has largest included sphere 2.35 A, density 1.73 g/cm3, surface area 4208.64 m2/g, accessible volume 0.13 cm3/g