Zn3H10(C8O5)2(CH3)4(C3NH5O)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of twenty-four 02329_fluka molecules and twelve n,n-dimethylformamide molecules inside a Zn3H10(C8O5)2 framework. In the Zn3H10(C8O5)2 framework, there are five inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to two equivalent O(11), two equivalent O(3), and two equivalent O(9) atoms to form corner-sharing ZnO6 octahedra. Both Zn(1)-O(11) bond lengths are 2.12 Å. Both Zn(1)-O(3) bond lengths are 2.06 Å. Both Zn(1)-O(9) bond lengths are 2.16 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(12), one O(13), one O(2), one O(7), and one O(8) atom to form corner-sharing ZnO6 octahedra. The Zn(2)-O(1) bond length is 2.08 Å. The Zn(2)-O(12) bond length is 2.12 Å. The Zn(2)-O(13) bond length is 2.15 Å. The Zn(2)-O(2) bond length is 2.07 Å. The Zn(2)-O(7) bond length is 2.14 Å. The Zn(2)-O(8) bond length is 2.14 Å. In the third Zn site, Zn(3) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra, and  an edgeedge with one Zn(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 70°. The Zn(3)-O(1) bond length is 2.02 Å. The Zn(3)-O(3) bond length is 2.02 Å. The Zn(3)-O(4) bond length is 1.94 Å. The Zn(3)-O(5) bond length is 1.94 Å. In the fourth Zn site, Zn(4) is bonded to one O(10), one O(6), and two equivalent O(2) atoms to form ZnO4 tetrahedra that share corners with two equivalent Zn(2)O6 octahedra and  an edgeedge with one Zn(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 69-73°. The Zn(4)-O(10) bond length is 1.95 Å. The Zn(4)-O(6) bond length is 1.96 Å. There is one shorter (2.02 Å) and one longer (2.03 Å) Zn(4)-O(2) bond length. In the fifth Zn site, Zn(5) is bonded to one O(1), one O(14), one O(15), and one O(3) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra, and  an edgeedge with one Zn(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 69°. The Zn(5)-O(1) bond length is 2.01 Å. The Zn(5)-O(14) bond length is 1.94 Å. The Zn(5)-O(15) bond length is 1.94 Å. The Zn(5)-O(3) bond length is 2.01 Å. There are twenty-four inequivalent C sites. In the first C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(15) atom. The C(13)-C(12) bond length is 1.40 Å. The C(13)-C(14) bond length is 1.49 Å. The C(13)-C(15) bond length is 1.40 Å. In the second C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(4), and one O(8) atom. The C(14)-O(4) bond length is 1.29 Å. The C(14)-O(8) bond length is 1.27 Å. In the third C site, C(15) is bonded in a distorted trigonal planar geometry to one C(13), one C(16), and one H(10) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(10) bond length is 1.09 Å. In the fourth C site, C(16) is bonded in a distorted single-bond geometry to one C(10), one C(15), and one H(11) atom. The C(16)-C(10) bond length is 1.40 Å. The C(16)-H(11) bond length is 1.09 Å. In the fifth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(13), and one O(15) atom. The C(17)-C(18) bond length is 1.49 Å. The C(17)-O(13) bond length is 1.26 Å. The C(17)-O(15) bond length is 1.29 Å. In the sixth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(24) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(24) bond length is 1.40 Å. In the seventh C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(12) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-H(12) bond length is 1.09 Å. In the eighth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one H(13) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(13) bond length is 1.09 Å. In the ninth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(23) atom. The C(21)-C(22) bond length is 1.50 Å. The C(21)-C(23) bond length is 1.40 Å. In the tenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(14), and one O(9) atom. The C(22)-O(14) bond length is 1.29 Å. The C(22)-O(9) bond length is 1.26 Å. In the eleventh C site, C(23) is bonded in a distorted single-bond geometry to one C(21) and one H(14) atom. The C(23)-H(14) bond length is 1.09 Å. In the twelfth C site, C(24) is bonded in a distorted single-bond geometry to one C(18) and one H(15) atom. The C(24)-H(15) bond length is 1.09 Å. In the thirteenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(12), and one O(6) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(12) bond length is 1.26 Å. The C(1)-O(6) bond length is 1.29 Å. In the fourteenth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(8) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(8) bond length is 1.40 Å. In the fifteenth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(4) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(4) bond length is 1.09 Å. In the sixteenth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(5) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(5) bond length is 1.09 Å. In the seventeenth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.50 Å. The C(5)-C(7) bond length is 1.40 Å. In the eighteenth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(10), and one O(7) atom. The C(6)-O(10) bond length is 1.29 Å. The C(6)-O(7) bond length is 1.27 Å. In the nineteenth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5), one C(8), and one H(6) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(6) bond length is 1.09 Å. In the twentieth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(2), one C(7), and one H(7) atom. The C(8)-H(7) bond length is 1.09 Å. In the twenty-first C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(11), and one O(5) atom. The C(9)-C(10) bond length is 1.49 Å. The C(9)-O(11) bond length is 1.27 Å. The C(9)-O(5) bond length is 1.29 Å. In the twenty-second C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(16), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. In the twenty-third C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(8) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(8) bond length is 1.09 Å. In the twenty-fourth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(9) atom. The C(12)-H(9) bond length is 1.09 Å. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 1.00 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 1.00 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. The H(3)-O(3) bond length is 1.00 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(23) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(24) atom. There are fifteen inequivalent O sites. In the first O site, O(2) is bonded to one Zn(2), two equivalent Zn(4), and one H(2) atom to form a mixture of distorted edge and corner-sharing OZn3H tetrahedra. In the second O site, O(3) is bonded to one Zn(1), one Zn(3), one Zn(5), and one H(3) atom to form a mixture of distorted edge and corner-sharing OZn3H tetrahedra. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(14) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(9) atom. In the fifth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(1) atom. In the sixth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(6) atom. In the seventh O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(14) atom. In the eighth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(22) atom. In the ninth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(6) atom. In the tenth O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the eleventh O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(1) atom. In the twelfth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(17) atom. In the thirteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(22) atom. In the fourteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(17) atom. In the fifteenth O site, O(1) is bonded to one Zn(2), one Zn(3), one Zn(5), and one H(1) atom to form a mixture of distorted edge and corner-sharing OZn3H tetrahedra. Linkers: 12 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 18 [Zn]. The MOF has largest included sphere 2.26 A, density 1.72 g/cm3, surface area 4353.21 m2/g, accessible volume 0.12 cm3/g