CoCuC22H14(N2O3)2(CH)4CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two 02329_fluka molecules, and one CoCuC22H14(N2O3)2 cluster. In the CoCuC22H14(N2O3)2 cluster, Co(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Co(1)-O(1) bond length is 2.03 Å. The Co(1)-O(2) bond length is 2.11 Å. The Co(1)-O(3) bond length is 2.20 Å. The Co(1)-O(4) bond length is 2.12 Å. The Co(1)-O(5) bond length is 1.99 Å. The Co(1)-O(6) bond length is 2.01 Å. Cu(1) is bonded in a square co-planar geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Cu(1)-N(1) bond length is 1.96 Å. The Cu(1)-N(2) bond length is 1.95 Å. The Cu(1)-N(3) bond length is 1.94 Å. The Cu(1)-N(4) bond length is 1.98 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-O(1) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one N(1) atom. The C(2)-C(3) bond length is 1.43 Å. The C(2)-C(7) bond length is 1.42 Å. The C(2)-N(1) bond length is 1.39 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(8) bond length is 1.45 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(4)-H(1) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(5) atom. The C(8)-N(2) bond length is 1.29 Å. The C(8)-H(5) bond length is 1.10 Å. In the seventh C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(6), and one H(7) atom. The C(9)-N(2) bond length is 1.46 Å. The C(9)-H(6) bond length is 1.10 Å. The C(9)-H(7) bond length is 1.10 Å. In the eighth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(10), and one H(11) atom. The C(11)-N(3) bond length is 1.46 Å. The C(11)-H(10) bond length is 1.10 Å. The C(11)-H(11) bond length is 1.10 Å. In the ninth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(3), and one H(12) atom. The C(12)-C(13) bond length is 1.45 Å. The C(12)-N(3) bond length is 1.29 Å. The C(12)-H(12) bond length is 1.10 Å. In the tenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(18) atom. The C(13)-C(14) bond length is 1.43 Å. The C(13)-C(18) bond length is 1.41 Å. In the eleventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one N(4) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-N(4) bond length is 1.39 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(13) atom. The C(15)-H(13) bond length is 1.08 Å. In the thirteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(16) atom. The C(18)-H(16) bond length is 1.09 Å. In the fourteenth C site, C(19) is bonded in a 2-coordinate geometry to one N(4) and one O(2) atom. The C(19)-N(4) bond length is 1.34 Å. The C(19)-O(2) bond length is 1.27 Å. In the fifteenth C site, C(20) is bonded in a bent 120 degrees geometry to one C(21), one O(3), and one O(4) atom. The C(20)-C(21) bond length is 1.49 Å. The C(20)-O(3) bond length is 1.28 Å. The C(20)-O(4) bond length is 1.29 Å. In the sixteenth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(23) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(23) bond length is 1.40 Å. In the seventeenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(17) atom. The C(22)-H(17) bond length is 1.09 Å. In the eighteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(21) and one H(18) atom. The C(23)-H(18) bond length is 1.09 Å. In the nineteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(5), and one O(6) atom. The C(24)-C(25) bond length is 1.50 Å. The C(24)-O(5) bond length is 1.27 Å. The C(24)-O(6) bond length is 1.28 Å. In the twentieth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(27) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(27) bond length is 1.40 Å. In the twenty-first C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(19,20) atom. The C(26)-H(19,20) bond length is 1.09 Å. In the twenty-second C site, C(27) is bonded in a distorted single-bond geometry to one C(25) and one H(19,20) atom. The C(27)-H(19,20) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(8), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(12) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(14), and one C(19) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(19,20) is bonded in a single-bond geometry to one C(26) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(19) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Co(1) and one C(20) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Co(1) and one C(20) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(24) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(24) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)cc1 ,2 O=C1[N]c2ccccc2/C=N/CCC/N=C/c2ccccc2[N]C1=O. Metal clusters: 2 [Co] ,2 [Cu]. RCSR code: bex. The MOF has largest included sphere 2.83 A, density 1.67 g/cm3, surface area 3847.23 m2/g, accessible volume 0.17 cm3/g