US2(NO5)2(CH2)10(CH3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty 02329_fluka molecules, four 02329_fluka molecules, and two US2(NO5)2 clusters. In each US2(NO5)2 cluster, U(1,2) is bonded in a distorted hexagonal bipyramidal geometry to two equivalent O(1), two equivalent O(3), two equivalent O(5), and two equivalent O(9) atoms. Both U(1,2)-O(1) bond lengths are 1.81 Å. Both U(1,2)-O(3) bond lengths are 2.55 Å. Both U(1,2)-O(5) bond lengths are 2.56 Å. Both U(1,2)-O(9) bond lengths are 2.38 Å. N(1,2) is bonded in a trigonal planar geometry to one O(3), one O(5), and one O(7) atom. The N(1,2)-O(3) bond length is 1.29 Å. The N(1,2)-O(5) bond length is 1.29 Å. The N(1,2)-O(7) bond length is 1.23 Å. S(1,2) is bonded in a distorted single-bond geometry to one O(9) atom. The S(1,2)-O(9) bond length is 1.55 Å. There are five inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one N(1,2) atom. In the second O site, O(9) is bonded in a distorted bent 120 degrees geometry to one U(1,2) and one S(1,2) atom. In the third O site, O(1) is bonded in a single-bond geometry to one U(1,2) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to one U(1,2) and one N(1,2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one U(1,2) and one N(1,2) atom. Linkers: 1 [CH2][S@@](=O)CCCC[S@@](=O)CCCC ,1 CCCC[S@@](=O)CCCC[S]=O ,1 [CH2]CCC[S@@](=O)CCCC[S@@](=O)CCCC ,2 CCCC[S@@](=O)CCCC[S@@](=O)CCCC ,1 [CH2][S@](=O)CCCC[S@](=O)CCCC ,1 CCCC[S@](=O)CCCC[S]=O ,1 [CH2]CCC[S@](=O)CCCC[S@](=O)CCCC. Metal clusters: 2 [U]. The MOF has largest included sphere 1.86 A, density 2.12 g/cm3, surface area 3803.42 m2/g, accessible volume 0.08 cm3/g