CuC16H8(N2O3)2(CH)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CuC16H8(N2O3)2 clusters. In each CuC16H8(N2O3)2 cluster, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 1.95 Å. Both Cu(1)-O(1) bond lengths are 1.99 Å. There are eight inequivalent C sites. In the first C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(4)-C(3) bond length is 1.42 Å. The C(4)-C(5) bond length is 1.44 Å. The C(4)-C(9) bond length is 1.42 Å. In the second C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(2) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-N(2) bond length is 1.42 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one O(1) atom. The C(8)-C(9) bond length is 1.45 Å. The C(8)-O(1) bond length is 1.30 Å. In the fifth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(4), one C(8), and one N(1) atom. The C(9)-N(1) bond length is 1.36 Å. In the seventh C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the eighth C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-H(3) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(5), one O(2), and one O(3) atom. The N(2)-O(2) bond length is 1.26 Å. The N(2)-O(3) bond length is 1.25 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(8) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(2) atom. Linkers: 2 [O]c1ccc([N+](=O)[O-])c2cccnc12. Metal clusters: 2 [Cu]. The MOF has largest included sphere 1.44 A, density 1.89 g/cm3, surface area 3939.08 m2/g, accessible volume 0.08 cm3/g