Cu2C22N4H16O9(CH)2 crystallizes in the triclinic P1 space group. The structure consists of eight 02329_fluka molecules inside a Cu2C22N4H16O9 framework. In the Cu2C22N4H16O9 framework, there are eight inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 5-coordinate geometry to one N(1), one N(13), one O(2), one O(6), and one O(9) atom. The Cu(1)-N(1) bond length is 2.03 Å. The Cu(1)-N(13) bond length is 2.27 Å. The Cu(1)-O(2) bond length is 2.04 Å. The Cu(1)-O(6) bond length is 2.02 Å. The Cu(1)-O(9) bond length is 2.04 Å. In the second Cu site, Cu(2) is bonded in a 6-coordinate geometry to one N(14), one N(2), one O(1), one O(10), one O(20), and one O(5) atom. The Cu(2)-N(14) bond length is 2.28 Å. The Cu(2)-N(2) bond length is 2.03 Å. The Cu(2)-O(1) bond length is 2.04 Å. The Cu(2)-O(10) bond length is 2.05 Å. The Cu(2)-O(20) bond length is 2.64 Å. The Cu(2)-O(5) bond length is 2.01 Å. In the third Cu site, Cu(3) is bonded in a 6-coordinate geometry to one N(15), one N(3), one O(11), one O(17), one O(4), and one O(8) atom. The Cu(3)-N(15) bond length is 2.27 Å. The Cu(3)-N(3) bond length is 2.03 Å. The Cu(3)-O(11) bond length is 2.04 Å. The Cu(3)-O(17) bond length is 2.66 Å. The Cu(3)-O(4) bond length is 2.04 Å. The Cu(3)-O(8) bond length is 2.02 Å. In the fourth Cu site, Cu(4) is bonded in a 5-coordinate geometry to one N(16), one N(4), one O(12), one O(3), and one O(7) atom. The Cu(4)-N(16) bond length is 2.27 Å. The Cu(4)-N(4) bond length is 2.03 Å. The Cu(4)-O(12) bond length is 2.04 Å. The Cu(4)-O(3) bond length is 2.04 Å. The Cu(4)-O(7) bond length is 2.02 Å. In the fifth Cu site, Cu(5) is bonded in a distorted octahedral geometry to one N(5), one N(9), one O(12), one O(22), one O(25), and one O(31) atom. The Cu(5)-N(5) bond length is 2.02 Å. The Cu(5)-N(9) bond length is 2.33 Å. The Cu(5)-O(12) bond length is 2.05 Å. The Cu(5)-O(22) bond length is 1.98 Å. The Cu(5)-O(25) bond length is 2.03 Å. The Cu(5)-O(31) bond length is 2.53 Å. In the sixth Cu site, Cu(6) is bonded in a distorted octahedral geometry to one N(10), one N(6), one O(11), one O(21), one O(26), and one O(32) atom. The Cu(6)-N(10) bond length is 2.33 Å. The Cu(6)-N(6) bond length is 2.02 Å. The Cu(6)-O(11) bond length is 2.05 Å. The Cu(6)-O(21) bond length is 1.98 Å. The Cu(6)-O(26) bond length is 2.03 Å. The Cu(6)-O(32) bond length is 2.53 Å. In the seventh Cu site, Cu(7) is bonded in a distorted octahedral geometry to one N(11), one N(7), one O(10), one O(24), one O(27), and one O(29) atom. The Cu(7)-N(11) bond length is 2.34 Å. The Cu(7)-N(7) bond length is 2.02 Å. The Cu(7)-O(10) bond length is 2.05 Å. The Cu(7)-O(24) bond length is 1.98 Å. The Cu(7)-O(27) bond length is 2.04 Å. The Cu(7)-O(29) bond length is 2.51 Å. In the eighth Cu site, Cu(8) is bonded in a distorted octahedral geometry to one N(12), one N(8), one O(23), one O(28), one O(30), and one O(9) atom. The Cu(8)-N(12) bond length is 2.33 Å. The Cu(8)-N(8) bond length is 2.02 Å. The Cu(8)-O(23) bond length is 1.98 Å. The Cu(8)-O(28) bond length is 2.03 Å. The Cu(8)-O(30) bond length is 2.53 Å. The Cu(8)-O(9) bond length is 2.05 Å. There are seventy inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(17); one N(1); and one H(1,3,4) atom. The C(1)-C(17) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1,3,4) bond length is 1.08 Å. In the second C site, C(2,3) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(2), and one H(2) atom. The C(2,3)-C(18) bond length is 1.39 Å. The C(2,3)-N(2) bond length is 1.34 Å. The C(2,3)-H(2) bond length is 1.08 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(20); one N(4); and one H(1,3,4) atom. The C(4)-C(20) bond length is 1.39 Å. The C(4)-N(4) bond length is 1.34 Å. The C(4)-H(1,3,4) bond length is 1.08 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(37); one C(69); and one C(77,79) atom. The C(5)-C(37) bond length is 1.40 Å. The C(5)-C(69) bond length is 1.50 Å. The C(5)-C(77,79) bond length is 1.40 Å. In the fifth C site, C(6,8) is bonded in a trigonal planar geometry to one C(38,40); one C(70); and one C(78,80) atom. The C(6,8)-C(38,40) bond length is 1.40 Å. The C(6,8)-C(70) bond length is 1.50 Å. The C(6,8)-C(78,80) bond length is 1.40 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(39); one C(71); and one C(77,79) atom. The C(7)-C(39) bond length is 1.40 Å. The C(7)-C(71) bond length is 1.50 Å. The C(7)-C(77,79) bond length is 1.40 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(29), and one O(5) atom. The C(9)-C(21) bond length is 1.52 Å. The C(9)-O(29) bond length is 1.25 Å. The C(9)-O(5) bond length is 1.29 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(30), and one O(6) atom. The C(10)-C(22) bond length is 1.52 Å. The C(10)-O(30) bond length is 1.25 Å. The C(10)-O(6) bond length is 1.29 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(31), and one O(7) atom. The C(11)-C(23) bond length is 1.52 Å. The C(11)-O(31) bond length is 1.25 Å. The C(11)-O(7) bond length is 1.29 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(32), and one O(8) atom. The C(12)-C(24) bond length is 1.52 Å. The C(12)-O(32) bond length is 1.25 Å. The C(12)-O(8) bond length is 1.29 Å. In the eleventh C site, C(13,16) is bonded in a distorted trigonal planar geometry to one C(25), one N(13), and one H(5) atom. The C(13,16)-C(25) bond length is 1.40 Å. The C(13,16)-N(13) bond length is 1.34 Å. The C(13,16)-H(5) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(26), one N(14), and one H(6) atom. The C(14)-C(26) bond length is 1.40 Å. The C(14)-N(14) bond length is 1.34 Å. The C(14)-H(6) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(27), one N(15), and one H(7) atom. The C(15)-C(27) bond length is 1.40 Å. The C(15)-N(15) bond length is 1.34 Å. The C(15)-H(7) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a trigonal planar geometry to one C(1), one C(33), and one C(89) atom. The C(17)-C(33) bond length is 1.51 Å. The C(17)-C(89) bond length is 1.40 Å. In the fifteenth C site, C(18) is bonded in a trigonal planar geometry to one C(2,3); one C(34); and one C(90,91) atom. The C(18)-C(34) bond length is 1.51 Å. The C(18)-C(90,91) bond length is 1.40 Å. In the sixteenth C site, C(19) is bonded in a trigonal planar geometry to one C(2,3); one C(35); and one C(90,91) atom. The C(19)-C(2,3) bond length is 1.39 Å. The C(19)-C(35) bond length is 1.51 Å. The C(19)-C(90,91) bond length is 1.40 Å. In the seventeenth C site, C(20) is bonded in a trigonal planar geometry to one C(36), one C(4), and one C(92) atom. The C(20)-C(36) bond length is 1.51 Å. The C(20)-C(92) bond length is 1.40 Å. In the eighteenth C site, C(21) is bonded in a trigonal planar geometry to one C(29); one C(85,87); and one C(9) atom. The C(21)-C(29) bond length is 1.40 Å. The C(21)-C(85,87) bond length is 1.40 Å. In the nineteenth C site, C(22) is bonded in a trigonal planar geometry to one C(10), one C(30), and one C(86) atom. The C(22)-C(30) bond length is 1.40 Å. The C(22)-C(86) bond length is 1.40 Å. In the twentieth C site, C(23) is bonded in a trigonal planar geometry to one C(11); one C(31); and one C(85,87) atom. The C(23)-C(31) bond length is 1.40 Å. The C(23)-C(85,87) bond length is 1.40 Å. In the twenty-first C site, C(24) is bonded in a trigonal planar geometry to one C(12), one C(32), and one C(88) atom. The C(24)-C(32) bond length is 1.40 Å. The C(24)-C(88) bond length is 1.40 Å. In the twenty-second C site, C(25) is bonded in a trigonal planar geometry to one C(13,16); one C(41,42,44); and one C(45) atom. The C(25)-C(41,42,44) bond length is 1.40 Å. The C(25)-C(45) bond length is 1.50 Å. In the twenty-third C site, C(26) is bonded in a trigonal planar geometry to one C(14); one C(41,42,44); and one C(46,48) atom. The C(26)-C(41,42,44) bond length is 1.40 Å. The C(26)-C(46,48) bond length is 1.50 Å. In the twenty-fourth C site, C(27) is bonded in a trigonal planar geometry to one C(15), one C(43), and one C(47) atom. The C(27)-C(43) bond length is 1.40 Å. The C(27)-C(47) bond length is 1.50 Å. In the twenty-fifth C site, C(28) is bonded in a trigonal planar geometry to one C(13,16); one C(41,42,44); and one C(46,48) atom. The C(28)-C(13,16) bond length is 1.40 Å. The C(28)-C(41,42,44) bond length is 1.40 Å. The C(28)-C(46,48) bond length is 1.50 Å. In the twenty-sixth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(5), and one H(9) atom. The C(29)-N(5) bond length is 1.34 Å. The C(29)-H(9) bond length is 1.09 Å. In the twenty-seventh C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(22); one N(6); and one H(10,11) atom. The C(30)-N(6) bond length is 1.34 Å. The C(30)-H(10,11) bond length is 1.09 Å. In the twenty-eighth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(23); one N(7); and one H(10,11) atom. The C(31)-N(7) bond length is 1.34 Å. The C(31)-H(10,11) bond length is 1.09 Å. In the twenty-ninth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(24), one N(8), and one H(12) atom. The C(32)-N(8) bond length is 1.34 Å. The C(32)-H(12) bond length is 1.09 Å. In the thirtieth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(17), and one O(21) atom. The C(33)-O(17) bond length is 1.25 Å. The C(33)-O(21) bond length is 1.29 Å. In the thirty-first C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(18), and one O(22) atom. The C(34)-O(18) bond length is 1.25 Å. The C(34)-O(22) bond length is 1.29 Å. In the thirty-second C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(19), and one O(23) atom. The C(35)-O(19) bond length is 1.25 Å. The C(35)-O(23) bond length is 1.29 Å. In the thirty-third C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(20), and one O(24) atom. The C(36)-O(20) bond length is 1.25 Å. The C(36)-O(24) bond length is 1.29 Å. In the thirty-fourth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(9), and one H(13) atom. The C(37)-N(9) bond length is 1.34 Å. The C(37)-H(13) bond length is 1.09 Å. In the thirty-fifth C site, C(38,40) is bonded in a distorted bent 120 degrees geometry to one C(6,8); one N(10); and one H(14,16) atom. The C(38,40)-N(10) bond length is 1.34 Å. The C(38,40)-H(14,16) bond length is 1.09 Å. In the thirty-sixth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(11), and one H(15) atom. The C(39)-N(11) bond length is 1.34 Å. The C(39)-H(15) bond length is 1.09 Å. In the thirty-seventh C site, C(41,42,44) is bonded in a distorted single-bond geometry to one C(25) and one H(17,18,19,20) atom. The C(41,42,44)-H(17,18,19,20) bond length is 1.09 Å. In the thirty-eighth C site, C(43) is bonded in a distorted single-bond geometry to one C(27) and one H(17,18,19,20) atom. The C(43)-H(17,18,19,20) bond length is 1.09 Å. In the thirty-ninth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(25), and one O(33) atom. The C(45)-O(25) bond length is 1.28 Å. The C(45)-O(33) bond length is 1.27 Å. In the fortieth C site, C(46,48) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(26), and one O(34) atom. The C(46,48)-O(26) bond length is 1.28 Å. The C(46,48)-O(34) bond length is 1.27 Å. In the forty-first C site, C(47) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(27), and one O(35) atom. The C(47)-O(27) bond length is 1.28 Å. The C(47)-O(35) bond length is 1.27 Å. In the forty-second C site, C(49,51,52) is bonded in a distorted single-bond geometry to one C(53) and one H(21,22,23,24) atom. The C(49,51,52)-C(53) bond length is 1.39 Å. The C(49,51,52)-H(21,22,23,24) bond length is 1.09 Å. In the forty-third C site, C(50) is bonded in a distorted single-bond geometry to one C(54,55) and one H(21,22,23,24) atom. The C(50)-C(54,55) bond length is 1.39 Å. The C(50)-H(21,22,23,24) bond length is 1.09 Å. In the forty-fourth C site, C(53) is bonded in a distorted trigonal planar geometry to one C(49,51,52); one N(1); and one H(25,27,28) atom. The C(53)-N(1) bond length is 1.35 Å. The C(53)-H(25,27,28) bond length is 1.09 Å. In the forty-fifth C site, C(54,55) is bonded in a distorted trigonal planar geometry to one C(50), one N(2), and one H(26) atom. The C(54,55)-N(2) bond length is 1.35 Å. The C(54,55)-H(26) bond length is 1.09 Å. In the forty-sixth C site, C(56) is bonded in a distorted trigonal planar geometry to one C(49,51,52); one N(4); and one H(25,27,28) atom. The C(56)-C(49,51,52) bond length is 1.39 Å. The C(56)-N(4) bond length is 1.35 Å. The C(56)-H(25,27,28) bond length is 1.09 Å. In the forty-seventh C site, C(57,60) is bonded in a distorted bent 120 degrees geometry to one N(13) and one H(29) atom. The C(57,60)-N(13) bond length is 1.35 Å. The C(57,60)-H(29) bond length is 1.09 Å. In the forty-eighth C site, C(58) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(30) atom. The C(58)-N(14) bond length is 1.35 Å. The C(58)-H(30) bond length is 1.09 Å. In the forty-ninth C site, C(59) is bonded in a distorted bent 120 degrees geometry to one N(15) and one H(31) atom. The C(59)-N(15) bond length is 1.35 Å. The C(59)-H(31) bond length is 1.09 Å. In the fiftieth C site, C(65) is bonded in a distorted trigonal planar geometry to one C(81,82,83); one N(5); and one H(37,38,39) atom. The C(65)-C(81,82,83) bond length is 1.39 Å. The C(65)-N(5) bond length is 1.35 Å. The C(65)-H(37,38,39) bond length is 1.09 Å. In the fifty-first C site, C(66) is bonded in a distorted trigonal planar geometry to one C(81,82,83); one N(6); and one H(37,38,39) atom. The C(66)-C(81,82,83) bond length is 1.39 Å. The C(66)-N(6) bond length is 1.35 Å. The C(66)-H(37,38,39) bond length is 1.09 Å. In the fifty-second C site, C(67) is bonded in a distorted trigonal planar geometry to one C(81,82,83); one N(7); and one H(37,38,39) atom. The C(67)-C(81,82,83) bond length is 1.39 Å. The C(67)-N(7) bond length is 1.35 Å. The C(67)-H(37,38,39) bond length is 1.09 Å. In the fifty-third C site, C(68) is bonded in a distorted trigonal planar geometry to one C(84), one N(8), and one H(40) atom. The C(68)-C(84) bond length is 1.39 Å. The C(68)-N(8) bond length is 1.35 Å. The C(68)-H(40) bond length is 1.09 Å. In the fifty-fourth C site, C(69) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(13) atom. The C(69)-O(1) bond length is 1.28 Å. The C(69)-O(13) bond length is 1.27 Å. In the fifty-fifth C site, C(70) is bonded in a distorted bent 120 degrees geometry to one C(6,8); one O(14,15); and one O(2) atom. The C(70)-O(14,15) bond length is 1.27 Å. The C(70)-O(2) bond length is 1.28 Å. In the fifty-sixth C site, C(71) is bonded in a distorted bent 120 degrees geometry to one C(7); one O(14,15); and one O(3) atom. The C(71)-O(14,15) bond length is 1.27 Å. The C(71)-O(3) bond length is 1.28 Å. In the fifty-seventh C site, C(72) is bonded in a distorted bent 120 degrees geometry to one C(6,8); one O(16); and one O(4) atom. The C(72)-C(6,8) bond length is 1.50 Å. The C(72)-O(16) bond length is 1.27 Å. The C(72)-O(4) bond length is 1.28 Å. In the fifty-eighth C site, C(77,79) is bonded in a distorted single-bond geometry to one C(5) and one H(45,46,47,48) atom. The C(77,79)-H(45,46,47,48) bond length is 1.09 Å. In the fifty-ninth C site, C(78,80) is bonded in a distorted single-bond geometry to one C(6,8) and one H(45,46,47,48) atom. The C(78,80)-H(45,46,47,48) bond length is 1.09 Å. In the sixtieth C site, C(81,82,83) is bonded in a distorted single-bond geometry to one C(65) and one H(49,50,52) atom. The C(81,82,83)-H(49,50,52) bond length is 1.09 Å. In the sixty-first C site, C(84) is bonded in a distorted single-bond geometry to one C(68) and one H(49,50,52) atom. The C(84)-H(49,50,52) bond length is 1.09 Å. In the sixty-second C site, C(85,87) is bonded in a distorted single-bond geometry to one C(21) and one H(53,55) atom. The C(85,87)-H(53,55) bond length is 1.09 Å. In the sixty-third C site, C(86) is bonded in a distorted single-bond geometry to one C(22) and one H(54,56) atom. The C(86)-H(54,56) bond length is 1.09 Å. In the sixty-fourth C site, C(88) is bonded in a distorted single-bond geometry to one C(24) and one H(54,56) atom. The C(88)-H(54,56) bond length is 1.09 Å. In the sixty-fifth C site, C(89) is bonded in a distorted single-bond geometry to one C(17) and one H(57,58,59,60) atom. The C(89)-H(57,58,59,60) bond length is 1.09 Å. In the sixty-sixth C site, C(90,91) is bonded in a distorted single-bond geometry to one C(18) and one H(57,58,59,60) atom. The C(90,91)-H(57,58,59,60) bond length is 1.09 Å. In the sixty-seventh C site, C(92) is bonded in a distorted single-bond geometry to one C(20) and one H(57,58,59,60) atom. The C(92)-H(57,58,59,60) bond length is 1.09 Å. In the sixty-eighth C site, C(93) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(61) atom. The C(93)-N(9) bond length is 1.34 Å. The C(93)-H(61) bond length is 1.09 Å. In the sixty-ninth C site, C(94,96) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(62,64) atom. The C(94,96)-N(10) bond length is 1.34 Å. The C(94,96)-H(62,64) bond length is 1.09 Å. In the seventieth C site, C(95) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(63) atom. The C(95)-N(11) bond length is 1.34 Å. The C(95)-H(63) bond length is 1.09 Å. There are sixteen inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(53) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2); one C(2,3); and one C(54,55) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(3); one C(2,3); and one C(54,55) atom. The N(3)-C(2,3) bond length is 1.34 Å. The N(3)-C(54,55) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(4), one C(4), and one C(56) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(5), one C(29), and one C(65) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(6), one C(30), and one C(66) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Cu(7), one C(31), and one C(67) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Cu(8), one C(32), and one C(68) atom. In the ninth N site, N(9) is bonded in a distorted trigonal planar geometry to one Cu(5), one C(37), and one C(93) atom. In the tenth N site, N(10) is bonded in a distorted trigonal planar geometry to one Cu(6); one C(38,40); and one C(94,96) atom. In the eleventh N site, N(11) is bonded in a distorted trigonal planar geometry to one Cu(7), one C(39), and one C(95) atom. In the twelfth N site, N(12) is bonded in a distorted trigonal planar geometry to one Cu(8); one C(38,40); and one C(94,96) atom. The N(12)-C(38,40) bond length is 1.34 Å. The N(12)-C(94,96) bond length is 1.34 Å. In the thirteenth N site, N(13) is bonded in a trigonal planar geometry to one Cu(1); one C(13,16); and one C(57,60) atom. In the fourteenth N site, N(14) is bonded in a trigonal planar geometry to one Cu(2), one C(14), and one C(58) atom. In the fifteenth N site, N(15) is bonded in a trigonal planar geometry to one Cu(3), one C(15), and one C(59) atom. In the sixteenth N site, N(16) is bonded in a trigonal planar geometry to one Cu(4); one C(13,16); and one C(57,60) atom. The N(16)-C(13,16) bond length is 1.34 Å. The N(16)-C(57,60) bond length is 1.35 Å. There are thirty-nine inequivalent H sites. In the first H site, H(1,3,4) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2,3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(13,16) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(13,16) atom. The H(8)-C(13,16) bond length is 1.09 Å. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(29) atom. In the eighth H site, H(10,11) is bonded in a single-bond geometry to one C(30) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(32) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(37) atom. In the eleventh H site, H(14,16) is bonded in a single-bond geometry to one C(38,40) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(39) atom. In the thirteenth H site, H(17,18,19,20) is bonded in a single-bond geometry to one C(41,42,44) atom. In the fourteenth H site, H(21,22,23,24) is bonded in a single-bond geometry to one C(49,51,52) atom. In the fifteenth H site, H(25,27,28) is bonded in a single-bond geometry to one C(53) atom. In the sixteenth H site, H(26) is bonded in a single-bond geometry to one C(54,55) atom. In the seventeenth H site, H(29) is bonded in a single-bond geometry to one C(57,60) atom. In the eighteenth H site, H(30) is bonded in a single-bond geometry to one C(58) atom. In the nineteenth H site, H(31) is bonded in a single-bond geometry to one C(59) atom. In the twentieth H site, H(32) is bonded in a single-bond geometry to one C(57,60) atom. The H(32)-C(57,60) bond length is 1.09 Å. In the twenty-first H site, H(37,38,39) is bonded in a single-bond geometry to one C(65) atom. In the twenty-second H site, H(40) is bonded in a single-bond geometry to one C(68) atom. In the twenty-third H site, H(45,46,47,48) is bonded in a single-bond geometry to one C(77,79) atom. In the twenty-fourth H site, H(49,50,52) is bonded in a single-bond geometry to one C(81,82,83) atom. In the twenty-fifth H site, H(51) is bonded in a single-bond geometry to one C(81,82,83) atom. The H(51)-C(81,82,83) bond length is 1.09 Å. In the twenty-sixth H site, H(53,55) is bonded in a single-bond geometry to one C(85,87) atom. In the twenty-seventh H site, H(54,56) is bonded in a single-bond geometry to one C(86) atom. In the twenty-eighth H site, H(57,58,59,60) is bonded in a single-bond geometry to one C(89) atom. In the twenty-ninth H site, H(61) is bonded in a single-bond geometry to one C(93) atom. In the thirtieth H site, H(62,64) is bonded in a single-bond geometry to one C(94,96) atom. In the thirty-first H site, H(63) is bonded in a single-bond geometry to one C(95) atom. In the thirty-second H site, H(65) is bonded in a distorted linear geometry to one O(36) and one O(9) atom. The H(65)-O(36) bond length is 1.44 Å. The H(65)-O(9) bond length is 1.06 Å. In the thirty-third H site, H(66) is bonded in a distorted linear geometry to one O(10) and one O(35) atom. The H(66)-O(10) bond length is 1.06 Å. The H(66)-O(35) bond length is 1.44 Å. In the thirty-fourth H site, H(67) is bonded in a distorted linear geometry to one O(11) and one O(34) atom. The H(67)-O(11) bond length is 1.06 Å. The H(67)-O(34) bond length is 1.44 Å. In the thirty-fifth H site, H(68) is bonded in a distorted linear geometry to one O(12) and one O(33) atom. The H(68)-O(12) bond length is 1.06 Å. The H(68)-O(33) bond length is 1.44 Å. In the thirty-sixth H site, H(69) is bonded in a distorted linear geometry to one O(14,15) and one O(9) atom. The H(69)-O(14,15) bond length is 1.53 Å. The H(69)-O(9) bond length is 1.04 Å. In the thirty-seventh H site, H(70) is bonded in a distorted linear geometry to one O(10) and one O(13) atom. The H(70)-O(10) bond length is 1.03 Å. The H(70)-O(13) bond length is 1.53 Å. In the thirty-eighth H site, H(71) is bonded in a distorted linear geometry to one O(11) and one O(16) atom. The H(71)-O(11) bond length is 1.04 Å. The H(71)-O(16) bond length is 1.53 Å. In the thirty-ninth H site, H(72) is bonded in a distorted linear geometry to one O(12) and one O(14,15) atom. The H(72)-O(12) bond length is 1.04 Å. The H(72)-O(14,15) bond length is 1.53 Å. There are thirty-five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(69) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(70) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one C(71) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one C(72) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(9) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(10) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(11) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(12) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Cu(1), one Cu(8), one H(65), and one H(69) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Cu(2), one Cu(7), one H(66), and one H(70) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Cu(3), one Cu(6), one H(67), and one H(71) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Cu(4), one Cu(5), one H(68), and one H(72) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one C(69) and one H(70) atom. In the fourteenth O site, O(14,15) is bonded in a water-like geometry to one C(70) and one H(69) atom. In the fifteenth O site, O(16) is bonded in a water-like geometry to one C(72) and one H(71) atom. In the sixteenth O site, O(17) is bonded in a single-bond geometry to one Cu(3) and one C(33) atom. In the seventeenth O site, O(18) is bonded in a single-bond geometry to one C(34) atom. In the eighteenth O site, O(19) is bonded in a single-bond geometry to one C(35) atom. In the nineteenth O site, O(20) is bonded in a single-bond geometry to one Cu(2) and one C(36) atom. In the twentieth O site, O(21) is bonded in a bent 120 degrees geometry to one Cu(6) and one C(33) atom. In the twenty-first O site, O(22) is bonded in a bent 120 degrees geometry to one Cu(5) and one C(34) atom. In the twenty-second O site, O(23) is bonded in a bent 120 degrees geometry to one Cu(8) and one C(35) atom. In the twenty-third O site, O(24) is bonded in a bent 120 degrees geometry to one Cu(7) and one C(36) atom. In the twenty-fourth O site, O(25) is bonded in a bent 120 degrees geometry to one Cu(5) and one C(45) atom. In the twenty-fifth O site, O(26) is bonded in a bent 120 degrees geometry to one Cu(6) and one C(46,48) atom. In the twenty-sixth O site, O(27) is bonded in a bent 120 degrees geometry to one Cu(7) and one C(47) atom. In the twenty-seventh O site, O(28) is bonded in a bent 120 degrees geometry to one Cu(8) and one C(46,48) atom. The O(28)-C(46,48) bond length is 1.28 Å. In the twenty-eighth O site, O(29) is bonded in a distorted single-bond geometry to one Cu(7) and one C(9) atom. In the twenty-ninth O site, O(30) is bonded in a single-bond geometry to one Cu(8) and one C(10) atom. In the thirtieth O site, O(31) is bonded in a single-bond geometry to one Cu(5) and one C(11) atom. In the thirty-first O site, O(32) is bonded in a single-bond geometry to one Cu(6) and one C(12) atom. In the thirty-second O site, O(33) is bonded in a water-like geometry to one C(45) and one H(68) atom. In the thirty-third O site, O(34) is bonded in a water-like geometry to one C(46,48) and one H(67) atom. In the thirty-fourth O site, O(35) is bonded in a water-like geometry to one C(47) and one H(66) atom. In the thirty-fifth O site, O(36) is bonded in a water-like geometry to one C(46,48) and one H(65) atom. The O(36)-C(46,48) bond length is 1.27 Å. Linkers: 16 [O]C(=O)c1cccnc1. Metal clusters: 4 O.O=[C]O[Cu]O[C]=O.O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 3.87 A, density 1.53 g/cm3, surface area 3983.59 m2/g, accessible volume 0.20 cm3/g