CH2(CH)3CuC10H9S2IFCF is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, four 02329_fluka molecules, four fluoromethane molecules, and two CuC10H9S2IF clusters. In each CuC10H9S2IF cluster, Cu(1) is bonded to one S(1), one S(2), and two equivalent I(1) atoms to form distorted edge-sharing CuS2I2 tetrahedra. The Cu(1)-S(1) bond length is 2.31 Å. The Cu(1)-S(2) bond length is 2.29 Å. There is one shorter (2.60 Å) and one longer (2.65 Å) Cu(1)-I(1) bond length. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one H(1), one H(2), and one S(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.83 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(12), one C(4), and one S(2) atom. The C(3)-C(12) bond length is 1.40 Å. The C(3)-C(4) bond length is 1.40 Å. The C(3)-S(2) bond length is 1.77 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(5)-C(7) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted water-like geometry to one H(5), one H(6), and one S(2) atom. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. The C(6)-S(2) bond length is 1.82 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(5), one C(8), and one S(1) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-S(1) bond length is 1.78 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(11), one C(7), and one H(7) atom. The C(8)-C(11) bond length is 1.39 Å. The C(8)-H(7) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(14), one C(8), and one H(11) atom. The C(11)-C(14) bond length is 1.39 Å. The C(11)-H(11) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(3) and one H(12) atom. The C(12)-H(12) bond length is 1.09 Å. In the tenth C site, C(14) is bonded in a distorted single-bond geometry to one C(11) and one F(2) atom. The C(14)-F(2) bond length is 1.37 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(1), and one C(7) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(3), and one C(6) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. F(2) is bonded in a single-bond geometry to one C(14) atom. Linkers: 2 Fc1ccc(SCCCSc2ccc(F)cc2)cc1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 2.37 A, density 1.99 g/cm3, surface area 3895.40 m2/g, accessible volume 0.11 cm3/g