AgC18H13(NO2)2(C3H2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 2,3-dimethyl-1,3-butadiene molecules and two AgC18H13(NO2)2 clusters. In each AgC18H13(NO2)2 cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(3), one O(1), and one O(4) atom. The Ag(1)-N(1) bond length is 2.17 Å. The Ag(1)-N(3) bond length is 2.18 Å. The Ag(1)-O(1) bond length is 2.68 Å. The Ag(1)-O(4) bond length is 2.58 Å. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one N(2), one N(4), one O(2), and one O(3) atom. The Ag(2)-N(2) bond length is 2.17 Å. The Ag(2)-N(4) bond length is 2.18 Å. The Ag(2)-O(2) bond length is 2.68 Å. The Ag(2)-O(3) bond length is 2.58 Å. There are thirty-four inequivalent C sites. In the first C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(19,20) atom. The C(30)-N(2) bond length is 1.35 Å. The C(30)-H(19,20) bond length is 1.09 Å. In the second C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(19,20) atom. The C(29)-N(1) bond length is 1.35 Å. The C(29)-H(19,20) bond length is 1.09 Å. In the third C site, C(37) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(25,26) atom. The C(37)-N(1) bond length is 1.35 Å. The C(37)-H(25,26) bond length is 1.09 Å. In the fourth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(25,26) atom. The C(38)-N(2) bond length is 1.35 Å. The C(38)-H(25,26) bond length is 1.09 Å. In the fifth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(27,28) atom. The C(39)-N(3) bond length is 1.35 Å. The C(39)-H(27,28) bond length is 1.09 Å. In the sixth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(27,28) atom. The C(40)-N(4) bond length is 1.35 Å. The C(40)-H(27,28) bond length is 1.09 Å. In the seventh C site, C(47) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(33,34) atom. The C(47)-N(3) bond length is 1.35 Å. The C(47)-H(33,34) bond length is 1.09 Å. In the eighth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(33,34) atom. The C(48)-N(4) bond length is 1.35 Å. The C(48)-H(33,34) bond length is 1.09 Å. In the ninth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(3) bond length is 1.26 Å. In the tenth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(4) atom. The C(2)-C(4) bond length is 1.50 Å. The C(2)-O(2) bond length is 1.29 Å. The C(2)-O(4) bond length is 1.26 Å. In the eleventh C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(5) atom. The C(3)-C(13) bond length is 1.41 Å. The C(3)-C(5) bond length is 1.40 Å. In the twelfth C site, C(4) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(6) atom. The C(4)-C(14) bond length is 1.41 Å. The C(4)-C(6) bond length is 1.40 Å. In the thirteenth C site, C(5) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(3) atom. The C(5)-C(7) bond length is 1.39 Å. The C(5)-H(3) bond length is 1.09 Å. In the fourteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one H(4) atom. The C(6)-C(8) bond length is 1.39 Å. The C(6)-H(4) bond length is 1.09 Å. In the fifteenth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one H(5) atom. The C(7)-C(9) bond length is 1.40 Å. The C(7)-H(5) bond length is 1.09 Å. In the sixteenth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one H(6) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-H(6) bond length is 1.09 Å. In the seventeenth C site, C(9) is bonded in a distorted single-bond geometry to one C(7) and one H(7,8) atom. The C(9)-H(7,8) bond length is 1.09 Å. In the eighteenth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(7,8) atom. The C(10)-H(7,8) bond length is 1.09 Å. In the nineteenth C site, C(11) is bonded in a distorted single-bond geometry to one C(13) and one H(9,10) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-H(9,10) bond length is 1.09 Å. In the twentieth C site, C(12) is bonded in a distorted single-bond geometry to one C(14) and one H(9,10) atom. The C(12)-C(14) bond length is 1.40 Å. The C(12)-H(9,10) bond length is 1.09 Å. In the twenty-first C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(3) atom. The C(13)-C(15) bond length is 1.50 Å. In the twenty-second C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(4) atom. The C(14)-C(16) bond length is 1.50 Å. In the twenty-third C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(25) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-C(25) bond length is 1.41 Å. In the twenty-fourth C site, C(16) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(26) atom. The C(16)-C(18) bond length is 1.40 Å. The C(16)-C(26) bond length is 1.41 Å. In the twenty-fifth C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one H(11,12) atom. The C(17)-H(11,12) bond length is 1.09 Å. In the twenty-sixth C site, C(18) is bonded in a distorted single-bond geometry to one C(16) and one H(11,12) atom. The C(18)-H(11,12) bond length is 1.09 Å. In the twenty-seventh C site, C(19) is bonded in a distorted single-bond geometry to one C(21,22) and one H(13,14) atom. The C(19)-C(21,22) bond length is 1.40 Å. The C(19)-H(13,14) bond length is 1.09 Å. In the twenty-eighth C site, C(20) is bonded in a distorted single-bond geometry to one C(21,22) and one H(13,14) atom. The C(20)-C(21,22) bond length is 1.40 Å. The C(20)-H(13,14) bond length is 1.09 Å. In the twenty-ninth C site, C(21,22) is bonded in a distorted trigonal planar geometry to one C(19), one C(23), and one H(15) atom. The C(21,22)-C(23) bond length is 1.39 Å. The C(21,22)-H(15) bond length is 1.09 Å. In the thirtieth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(21,22); one C(25); and one H(17,18) atom. The C(23)-C(25) bond length is 1.40 Å. The C(23)-H(17,18) bond length is 1.09 Å. In the thirty-first C site, C(24) is bonded in a distorted trigonal planar geometry to one C(21,22); one C(26); and one H(17,18) atom. The C(24)-C(21,22) bond length is 1.39 Å. The C(24)-C(26) bond length is 1.40 Å. The C(24)-H(17,18) bond length is 1.09 Å. In the thirty-second C site, C(25) is bonded in a trigonal planar geometry to one C(15); one C(23); and one C(27,28) atom. The C(25)-C(27,28) bond length is 1.50 Å. In the thirty-third C site, C(26) is bonded in a trigonal planar geometry to one C(16); one C(24); and one C(27,28) atom. The C(26)-C(27,28) bond length is 1.50 Å. In the thirty-fourth C site, C(27,28) is bonded in a distorted bent 120 degrees geometry to one C(25); one O(5); and one O(7,8) atom. The C(27,28)-O(5) bond length is 1.33 Å. The C(27,28)-O(7,8) bond length is 1.23 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(29), and one C(37) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(2), one C(30), and one C(38) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(39), and one C(47) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(2), one C(40), and one C(48) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(5) atom. The H(1)-O(1) bond length is 1.47 Å. The H(1)-O(5) bond length is 1.06 Å. In the second H site, H(2) is bonded in a linear geometry to one O(2) and one O(6) atom. The H(2)-O(2) bond length is 1.47 Å. The H(2)-O(6) bond length is 1.06 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7,8) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(9,10) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(11,12) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(13,14) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(21,22) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(21,22) atom. The H(16)-C(21,22) bond length is 1.09 Å. In the thirteenth H site, H(17,18) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(19,20) is bonded in a single-bond geometry to one C(29) atom. In the fifteenth H site, H(25,26) is bonded in a single-bond geometry to one C(37) atom. In the sixteenth H site, H(27,28) is bonded in a single-bond geometry to one C(39) atom. In the seventeenth H site, H(33,34) is bonded in a single-bond geometry to one C(47) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one C(1), and one H(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(2), one C(2), and one H(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Ag(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Ag(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(27,28) and one H(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one C(27,28) and one H(2) atom. The O(6)-C(27,28) bond length is 1.33 Å. In the seventh O site, O(7,8) is bonded in a single-bond geometry to one C(27,28) atom. Linkers: 4 [O]C(=O)c1ccccc1-c1ccccc1C(=O)O. Metal clusters: 4 [Ag]. The MOF has largest included sphere 4.53 A, density 1.42 g/cm3, surface area 4323.42 m2/g, accessible volume 0.22 cm3/g