ZnC7H12S2(NO)4 is beta Np structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four ZnC7H12S2(NO)4 clusters. Zn(1) is bonded in a distorted tetrahedral geometry to one S(1), one S(2), one O(1), and one O(3) atom. The Zn(1)-S(1) bond length is 2.31 Å. The Zn(1)-S(2) bond length is 2.29 Å. The Zn(1)-O(1) bond length is 2.05 Å. The Zn(1)-O(3) bond length is 2.04 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-S(1) bond length is 1.73 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(3), one N(4), and one S(2) atom. The C(2)-N(3) bond length is 1.33 Å. The C(2)-N(4) bond length is 1.33 Å. The C(2)-S(2) bond length is 1.73 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(3)-C(4) bond length is 1.49 Å. The C(3)-O(1) bond length is 1.29 Å. The C(3)-O(2) bond length is 1.26 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.50 Å. The C(4)-C(7) bond length is 1.34 Å. In the fifth C site, C(5) is bonded in a distorted water-like geometry to one C(4), one H(10), and one H(9) atom. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(6)-O(3) bond length is 1.30 Å. The C(6)-O(4) bond length is 1.26 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(4), one H(11), and one H(12) atom. The C(7)-H(11) bond length is 1.09 Å. The C(7)-H(12) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.02 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. The N(2)-H(3) bond length is 1.02 Å. The N(2)-H(4) bond length is 1.02 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(2), one H(5), and one H(6) atom. The N(3)-H(5) bond length is 1.03 Å. The N(3)-H(6) bond length is 1.02 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(2), one H(7), and one H(8) atom. The N(4)-H(7) bond length is 1.03 Å. The N(4)-H(8) bond length is 1.02 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Zn(1) and one C(2) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(6) atom. Linkers: 4 C=C(CC([O])=O)C([O])=O. Metal clusters: 4 [Zn]. The MOF has largest included sphere 2.41 A, density 1.79 g/cm3, surface area 4334.63 m2/g, accessible volume 0.11 cm3/g