ZnC32H22(NO)4 is Indium-like structured and crystallizes in the orthorhombic Aea2 space group. The structure is zero-dimensional and consists of four ZnC32H22(NO)4 clusters. Zn(1) is bonded in a tetrahedral geometry to two equivalent N(2) and two equivalent O(1) atoms. Both Zn(1)-N(2) bond lengths are 2.02 Å. Both Zn(1)-O(1) bond lengths are 1.96 Å. There are sixteen inequivalent C sites. In the first C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(6) bond length is 1.09 Å. In the second C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(1) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-N(1) bond length is 1.43 Å. In the third C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 1.09 Å. In the fourth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(13)-C(8) bond length is 1.41 Å. The C(13)-H(8) bond length is 1.09 Å. In the fifth C site, C(14) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(9) atom. The C(14)-N(1) bond length is 1.36 Å. The C(14)-N(2) bond length is 1.33 Å. The C(14)-H(9) bond length is 1.08 Å. In the sixth C site, C(15) is bonded in a 3-coordinate geometry to one C(16), one N(2), and one H(10) atom. The C(15)-C(16) bond length is 1.37 Å. The C(15)-N(2) bond length is 1.38 Å. The C(15)-H(10) bond length is 1.08 Å. In the seventh C site, C(16) is bonded in a 3-coordinate geometry to one C(15), one N(1), and one H(11) atom. The C(16)-N(1) bond length is 1.38 Å. The C(16)-H(11) bond length is 1.08 Å. In the eighth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the ninth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the tenth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the eleventh C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(2) bond length is 1.09 Å. In the twelfth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-C(8) bond length is 1.48 Å. In the thirteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(3) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(3) bond length is 1.09 Å. In the fourteenth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the fifteenth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(5), and one C(9) atom. The C(8)-C(9) bond length is 1.41 Å. In the sixteenth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(9)-H(5) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(16) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(14), and one C(15) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(16) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Linkers: 2 [O]C(=O)c1ccc(-c2ccc(-n3ccnc3)cc2)cc1. Metal clusters: 1 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.53 A, density 1.49 g/cm3, surface area 5031.97 m2/g, accessible volume 0.13 cm3/g