ZnC10H14(NO)4(CH2)10(CH3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty 02329_fluka molecules, four 02329_fluka molecules, and two ZnC10H14(NO)4 clusters. In one of the ZnC10H14(NO)4 clusters, Zn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent O(1) atoms. Both Zn(1)-N(1) bond lengths are 2.11 Å. Both Zn(1)-N(2) bond lengths are 2.16 Å. Both Zn(1)-O(1) bond lengths are 2.22 Å. There are five inequivalent C sites. In the first C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(19), and one H(20) atom. The C(9)-N(1) bond length is 1.47 Å. The C(9)-H(19) bond length is 1.11 Å. The C(9)-H(20) bond length is 1.10 Å. In the second C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(11)-O(1) bond length is 1.29 Å. The C(11)-O(2) bond length is 1.26 Å. In the third C site, C(1) is bonded in a 2-coordinate geometry to one N(2) and one H(5) atom. The C(1)-N(2) bond length is 1.49 Å. The C(1)-H(5) bond length is 1.11 Å. In the fourth C site, C(2) is bonded in a distorted water-like geometry to one N(1) and one H(6) atom. The C(2)-N(1) bond length is 1.48 Å. The C(2)-H(6) bond length is 1.10 Å. In the fifth C site, C(7) is bonded in a distorted water-like geometry to one N(2) and one H(15) atom. The C(7)-N(2) bond length is 1.48 Å. The C(7)-H(15) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a 4-coordinate geometry to one Zn(1), one C(1), one C(7), and one H(2) atom. The N(2)-H(2) bond length is 1.03 Å. In the second N site, N(1) is bonded to one Zn(1), one C(2), one C(9), and one H(1) atom to form distorted corner-sharing NZnHC2 tetrahedra. The N(1)-H(1) bond length is 1.04 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(20) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(11) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(11) atom. In one of the ZnC10H14(NO)4 clusters, Zn(2) is bonded in an octahedral geometry to two equivalent N(3), two equivalent N(4), and two equivalent O(4) atoms. Both Zn(2)-N(3) bond lengths are 2.13 Å. Both Zn(2)-N(4) bond lengths are 2.14 Å. Both Zn(2)-O(4) bond lengths are 2.21 Å. There are five inequivalent C sites. In the first C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(12)-O(3) bond length is 1.26 Å. The C(12)-O(4) bond length is 1.29 Å. In the second C site, C(13) is bonded in a 2-coordinate geometry to one N(4) and one H(23) atom. The C(13)-N(4) bond length is 1.48 Å. The C(13)-H(23) bond length is 1.11 Å. In the third C site, C(18) is bonded in a distorted water-like geometry to one N(3) and one H(32) atom. The C(18)-N(3) bond length is 1.48 Å. The C(18)-H(32) bond length is 1.10 Å. In the fourth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(33), and one H(34) atom. The C(19)-N(3) bond length is 1.47 Å. The C(19)-H(33) bond length is 1.10 Å. The C(19)-H(34) bond length is 1.10 Å. In the fifth C site, C(20) is bonded in a distorted water-like geometry to one N(4) and one H(35) atom. The C(20)-N(4) bond length is 1.48 Å. The C(20)-H(35) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded to one Zn(2), one C(18), one C(19), and one H(3) atom to form distorted corner-sharing NZnHC2 tetrahedra. The N(3)-H(3) bond length is 1.02 Å. In the second N site, N(4) is bonded in a 4-coordinate geometry to one Zn(2), one C(13), one C(20), and one H(4) atom. The N(4)-H(4) bond length is 1.05 Å. There are seven inequivalent H sites. In the first H site, H(32) is bonded in a single-bond geometry to one C(18) atom. In the second H site, H(33) is bonded in a single-bond geometry to one C(19) atom. In the third H site, H(34) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(35) is bonded in a single-bond geometry to one C(20) atom. In the sixth H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(23) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(12) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(12) atom. Linkers: 1 C[C@@H]1CCN[C@@H]2CCCC[C@@H]2N[C@@H](C)CCN[C@H]2CCCC[C@H]2N1 ,1 C[C@@H]1CCN[C@@H]2CCCC[C@@H]2N[C@@H](C)CCN[C@H]2CC[CH]C[C@H]2N1 ,1 C[C@@H]1CCN[C@@H]2CC[CH]C[C@@H]2N[C@@H](C)CCN[C@H]2CCCC[C@H]2N1 ,2 [O]C(=O)C([O])=O. Metal clusters: 2 [Zn]. The MOF has largest included sphere 3.24 A, density 1.28 g/cm3, surface area 5119.25 m2/g, accessible volume 0.29 cm3/g