C6SbN2H10S4Br3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 1,3-thiazolidine-2-thione;tribromostibane molecules. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one S(2) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-S(1) bond length is 1.74 Å. The C(1)-S(2) bond length is 1.69 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one H(1), one H(2), and one S(1) atom. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.09 Å. The C(2)-S(1) bond length is 1.83 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(3), and one H(4) atom. The C(3)-N(1) bond length is 1.46 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(4) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one N(2), one S(3), and one S(4) atom. The C(4)-N(2) bond length is 1.33 Å. The C(4)-S(3) bond length is 1.74 Å. The C(4)-S(4) bond length is 1.69 Å. In the fifth C site, C(5) is bonded in a distorted water-like geometry to one H(5), one H(6), and one S(3) atom. The C(5)-H(5) bond length is 1.09 Å. The C(5)-H(6) bond length is 1.10 Å. The C(5)-S(3) bond length is 1.82 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(7), and one H(8) atom. The C(6)-N(2) bond length is 1.46 Å. The C(6)-H(7) bond length is 1.10 Å. The C(6)-H(8) bond length is 1.10 Å. Sb(1) is bonded in a square pyramidal geometry to one S(2), one S(4), one Br(1), one Br(2), and one Br(3) atom. The Sb(1)-S(2) bond length is 2.82 Å. The Sb(1)-S(4) bond length is 2.82 Å. The Sb(1)-Br(1) bond length is 2.59 Å. The Sb(1)-Br(2) bond length is 2.68 Å. The Sb(1)-Br(3) bond length is 2.79 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(3), and one H(9) atom. The N(1)-H(9) bond length is 1.03 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(4), one C(6), and one H(10) atom. The N(2)-H(10) bond length is 1.03 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(1) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(2) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(1) and one C(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(1) and one Sb(1) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one C(4) and one C(5) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one C(4) and one Sb(1) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Sb(1) atom. Linkers: 2 Br[Sb](Br)Br.S=C1NCCS1.S=C1NCCS1. Metal clusters: . The MOF has largest included sphere 1.78 A, density 2.60 g/cm3, surface area 3038.46 m2/g, accessible volume 0.09 cm3/g