AgC24N5H22SO3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one AgC24N5H22SO3 cluster. Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one N(4), one N(5), and two equivalent O(1) atoms. The Ag(1)-N(4) bond length is 2.19 Å. The Ag(1)-N(5) bond length is 2.18 Å. There is one shorter (2.57 Å) and one longer (2.60 Å) Ag(1)-O(1) bond length. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(3) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-C(6) bond length is 1.43 Å. The C(1)-N(3) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-N(1) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one N(2) atom. The C(7)-C(12) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.41 Å. The C(7)-N(2) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(5) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(5) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(6) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(6) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(9), and one S(1) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-S(1) bond length is 1.78 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(9) atom. The C(13)-N(4) bond length is 1.35 Å. The C(13)-H(9) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(10,11) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(10,11) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(20) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-C(20) bond length is 1.48 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(10,11) atom. The C(16)-H(10,11) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(12) atom. The C(17)-N(4) bond length is 1.35 Å. The C(17)-H(12) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(13) atom. The C(18)-N(5) bond length is 1.35 Å. The C(18)-H(13) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(20) and one H(14) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(14) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(21) atom. The C(20)-C(21) bond length is 1.40 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one H(15) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(15) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one N(5), and one H(16) atom. The C(22)-N(5) bond length is 1.35 Å. The C(22)-H(16) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded to one N(3), one H(17), one H(18), and one H(19) atom to form corner-sharing CH3N tetrahedra. The C(23)-N(3) bond length is 1.46 Å. The C(23)-H(17) bond length is 1.09 Å. The C(23)-H(18) bond length is 1.10 Å. The C(23)-H(19) bond length is 1.10 Å. In the twenty-fourth C site, C(24) is bonded to one N(3), one H(20), one H(21), and one H(22) atom to form corner-sharing CH3N tetrahedra. The C(24)-N(3) bond length is 1.45 Å. The C(24)-H(20) bond length is 1.09 Å. The C(24)-H(21) bond length is 1.10 Å. The C(24)-H(22) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one C(4) and one N(2) atom. The N(1)-N(2) bond length is 1.28 Å. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(7) and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(23), and one C(24) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(1), one C(13), and one C(17) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Ag(1), one C(18), and one C(22) atom. There are twenty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(10,11) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(23) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the twentieth H site, H(21) is bonded in a single-bond geometry to one C(24) atom. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one C(24) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.49 Å. The S(1)-O(2) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.47 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Ag]. The MOF has largest included sphere 2.10 A, density 1.69 g/cm3, surface area 4545.14 m2/g, accessible volume 0.12 cm3/g