ZnC15H12(NO2)2NS crystallizes in the monoclinic C2/c space group. The structure consists of four 293-40-3 molecules inside a ZnC15H12(NO2)2 framework. In the ZnC15H12(NO2)2 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(1), one O(1), one O(2), one O(5), and one O(6) atom to form ZnNO4 square pyramids that share  a cornercorner with one C(1)H2N2 tetrahedra,  a cornercorner with one C(2)H2N2 tetrahedra, and  a cornercorner with one C(3)H2N2 tetrahedra. The Zn(1)-N(1) bond length is 2.10 Å. The Zn(1)-O(1) bond length is 2.06 Å. The Zn(1)-O(2) bond length is 2.05 Å. The Zn(1)-O(5) bond length is 2.08 Å. The Zn(1)-O(6) bond length is 2.06 Å. In the second Zn site, Zn(2) is bonded to one N(2), one O(3), one O(7), and one O(8) atom to form distorted ZnNO3 trigonal pyramids that share  a cornercorner with one C(1)H2N2 tetrahedra,  a cornercorner with one C(4)H2N2 tetrahedra, and  a cornercorner with one C(6)H2N2 tetrahedra. The Zn(2)-N(2) bond length is 2.13 Å. The Zn(2)-O(3) bond length is 1.96 Å. The Zn(2)-O(7) bond length is 1.95 Å. The Zn(2)-O(8) bond length is 2.00 Å. There are thirty inequivalent C sites. In the first C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(18) atom. The C(13)-C(12) bond length is 1.39 Å. The C(13)-C(14) bond length is 1.42 Å. The C(13)-C(18) bond length is 1.49 Å. In the second C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(16) atom. The C(14)-H(16) bond length is 1.09 Å. In the third C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(17) atom. The C(15)-C(16) bond length is 1.42 Å. The C(15)-H(17) bond length is 1.09 Å. In the fourth C site, C(16) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(17) atom. The C(16)-C(11) bond length is 1.44 Å. The C(16)-C(17) bond length is 1.41 Å. In the fifth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(8), and one H(18) atom. The C(17)-C(8) bond length is 1.39 Å. The C(17)-H(18) bond length is 1.09 Å. In the sixth C site, C(18) is bonded in a bent 120 degrees geometry to one C(13), one O(3), and one O(4) atom. The C(18)-O(3) bond length is 1.31 Å. The C(18)-O(4) bond length is 1.25 Å. In the seventh C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(5), and one O(6) atom. The C(19)-C(20) bond length is 1.50 Å. The C(19)-O(5) bond length is 1.27 Å. The C(19)-O(6) bond length is 1.28 Å. In the eighth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(22) atom. The C(20)-C(21) bond length is 1.42 Å. The C(20)-C(22) bond length is 1.38 Å. In the ninth C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(24), and one H(19) atom. The C(21)-C(24) bond length is 1.37 Å. The C(21)-H(19) bond length is 1.09 Å. In the tenth C site, C(22) is bonded in a distorted single-bond geometry to one C(20), one C(23), and one H(20) atom. The C(22)-C(23) bond length is 1.41 Å. The C(22)-H(20) bond length is 1.09 Å. In the eleventh C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(23), and one C(24) atom. The C(23)-C(23) bond length is 1.44 Å. The C(23)-C(24) bond length is 1.42 Å. In the twelfth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one H(21) atom. The C(24)-H(21) bond length is 1.09 Å. In the thirteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(7), and one O(8) atom. The C(25)-C(26) bond length is 1.49 Å. The C(25)-O(7) bond length is 1.28 Å. The C(25)-O(8) bond length is 1.27 Å. In the fourteenth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(28) atom. The C(26)-C(27) bond length is 1.42 Å. The C(26)-C(28) bond length is 1.38 Å. In the fifteenth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(26), one C(29), and one H(22) atom. The C(27)-C(29) bond length is 1.37 Å. The C(27)-H(22) bond length is 1.09 Å. In the sixteenth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(26), one C(30), and one H(23) atom. The C(28)-C(30) bond length is 1.41 Å. The C(28)-H(23) bond length is 1.09 Å. In the seventeenth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(27), one C(30), and one H(24) atom. The C(29)-C(30) bond length is 1.42 Å. The C(29)-H(24) bond length is 1.09 Å. In the eighteenth C site, C(30) is bonded in a trigonal planar geometry to one C(28), one C(29), and one C(30) atom. The C(30)-C(30) bond length is 1.44 Å. In the nineteenth C site, C(1) is bonded to one N(1), one N(2), one H(1), and one H(2) atom to form CH2N2 tetrahedra that share  a cornercorner with one Zn(1)NO4 square pyramid,  a cornercorner with one C(2)H2N2 tetrahedra,  a cornercorner with one C(3)H2N2 tetrahedra,  a cornercorner with one C(4)H2N2 tetrahedra,  a cornercorner with one C(6)H2N2 tetrahedra, and  a cornercorner with one Zn(2)NO3 trigonal pyramid. The C(1)-N(1) bond length is 1.49 Å. The C(1)-N(2) bond length is 1.49 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the twentieth C site, C(2) is bonded to one N(1), one N(3), one H(3), and one H(4) atom to form CH2N2 tetrahedra that share  a cornercorner with one Zn(1)NO4 square pyramid,  a cornercorner with one C(1)H2N2 tetrahedra,  a cornercorner with one C(3)H2N2 tetrahedra,  a cornercorner with one C(4)H2N2 tetrahedra, and  a cornercorner with one C(5)H2N2 tetrahedra. The C(2)-N(1) bond length is 1.50 Å. The C(2)-N(3) bond length is 1.46 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. In the twenty-first C site, C(3) is bonded to one N(1), one N(4), one H(5), and one H(6) atom to form CH2N2 tetrahedra that share  a cornercorner with one Zn(1)NO4 square pyramid,  a cornercorner with one C(1)H2N2 tetrahedra,  a cornercorner with one C(2)H2N2 tetrahedra,  a cornercorner with one C(5)H2N2 tetrahedra, and  a cornercorner with one C(6)H2N2 tetrahedra. The C(3)-N(1) bond length is 1.50 Å. The C(3)-N(4) bond length is 1.46 Å. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(6) bond length is 1.10 Å. In the twenty-second C site, C(4) is bonded to one N(2), one N(3), one H(7), and one H(8) atom to form CH2N2 tetrahedra that share  a cornercorner with one C(1)H2N2 tetrahedra,  a cornercorner with one C(2)H2N2 tetrahedra,  a cornercorner with one C(5)H2N2 tetrahedra,  a cornercorner with one C(6)H2N2 tetrahedra, and  a cornercorner with one Zn(2)NO3 trigonal pyramid. The C(4)-N(2) bond length is 1.50 Å. The C(4)-N(3) bond length is 1.46 Å. The C(4)-H(7) bond length is 1.10 Å. The C(4)-H(8) bond length is 1.10 Å. In the twenty-third C site, C(5) is bonded to one N(3), one N(4), one H(10), and one H(9) atom to form corner-sharing CH2N2 tetrahedra. The C(5)-N(3) bond length is 1.48 Å. The C(5)-N(4) bond length is 1.47 Å. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. In the twenty-fourth C site, C(6) is bonded to one N(2), one N(4), one H(11), and one H(12) atom to form CH2N2 tetrahedra that share  a cornercorner with one C(1)H2N2 tetrahedra,  a cornercorner with one C(3)H2N2 tetrahedra,  a cornercorner with one C(4)H2N2 tetrahedra,  a cornercorner with one C(5)H2N2 tetrahedra, and  a cornercorner with one Zn(2)NO3 trigonal pyramid. The C(6)-N(2) bond length is 1.50 Å. The C(6)-N(4) bond length is 1.46 Å. The C(6)-H(11) bond length is 1.10 Å. The C(6)-H(12) bond length is 1.10 Å. In the twenty-fifth C site, C(7) is bonded in a bent 120 degrees geometry to one C(8), one O(1), and one O(2) atom. The C(7)-C(8) bond length is 1.50 Å. The C(7)-O(1) bond length is 1.28 Å. The C(7)-O(2) bond length is 1.28 Å. In the twenty-sixth C site, C(8) is bonded in a trigonal planar geometry to one C(17), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.42 Å. In the twenty-seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(13) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-H(13) bond length is 1.09 Å. In the twenty-eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(14) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-H(14) bond length is 1.09 Å. In the twenty-ninth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(16) atom. The C(11)-C(12) bond length is 1.41 Å. In the thirtieth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(15) atom. The C(12)-H(15) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Zn(1), one C(1), one C(2), and one C(3) atom to form corner-sharing NZnC3 tetrahedra. In the second N site, N(2) is bonded to one Zn(2), one C(1), one C(4), and one C(6) atom to form corner-sharing NZnC3 tetrahedra. In the third N site, N(3) is bonded in a trigonal non-coplanar geometry to one C(2), one C(4), and one C(5) atom. In the fourth N site, N(4) is bonded in a trigonal non-coplanar geometry to one C(3), one C(5), and one C(6) atom. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(12) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(21) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(22) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(24) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(27) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(28) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(29) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(2) and one C(18) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(18) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(19) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(19) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(25) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(25) atom. Linkers: 4 C1N2CN3CN1CN(C2)C3 ,8 [O]C(=O)c1ccc2cc(C([O])=O)ccc2c1. Metal clusters: 2 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4 ,2 O=[C]O[Zn]1O[C]O[Zn](O[C]=O)O[C]O1. The MOF has largest included sphere 11.17 A, density 1.09 g/cm3, surface area 4191.91 m2/g, accessible volume 0.50 cm3/g