CuC9N4H7(CH)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two CuC9N4H7 clusters. In each CuC9N4H7 cluster, Cu(1) is bonded in a 3-coordinate geometry to one N(2), one N(3), and one N(4) atom. The Cu(1)-N(2) bond length is 1.94 Å. The Cu(1)-N(3) bond length is 1.94 Å. The Cu(1)-N(4) bond length is 2.06 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(2) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-N(2) bond length is 1.39 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(5) atom. The C(6)-N(2) bond length is 1.33 Å. The C(6)-N(3) bond length is 1.33 Å. The C(6)-H(5) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(6) atom. The C(7)-N(4) bond length is 1.35 Å. The C(7)-H(6) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one N(3) atom. The C(9)-N(3) bond length is 1.39 Å. In the ninth C site, C(11) is bonded in a 2-coordinate geometry to one N(4) and one H(9) atom. The C(11)-N(4) bond length is 1.35 Å. The C(11)-H(9) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(6), and one C(9) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(7) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. Linkers: 4 [CH]([N]c1ccncc1)[N]c1ccncc1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 5.28 A, density 1.20 g/cm3, surface area 4413.38 m2/g, accessible volume 0.38 cm3/g