Tl(CH)2C5NH2S2O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four 7440-28-0 atoms, and four C5NH2S2O2 clusters. In each C5NH2S2O2 cluster, there are five inequivalent C sites. In the first C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(4) bond length is 1.09 Å. In the second C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(1) bond length is 1.40 Å. The C(6)-C(7) bond length is 1.49 Å. In the third C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one S(2) atom. The C(7)-N(1) bond length is 1.34 Å. The C(7)-S(2) bond length is 1.69 Å. In the fourth C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-S(1) bond length is 1.77 Å. In the fifth C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. N(1) is bonded in a water-like geometry to one C(7) and one S(1) atom. The N(1)-S(1) bond length is 1.65 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted tetrahedral geometry to one C(1), one N(1), one O(1), and one O(2) atom. The S(1)-O(1) bond length is 1.46 Å. The S(1)-O(2) bond length is 1.46 Å. In the second S site, S(2) is bonded in a distorted single-bond geometry to one C(7) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one S(1) atom. Linkers: 4 O=S1(=O)[N]C(=S)c2ccccc21. Metal clusters: 4 [Tl]. The MOF has largest included sphere 1.68 A, density 2.95 g/cm3, surface area 2569.92 m2/g, accessible volume 0.06 cm3/g