(CH2)2ZnC9H8S(NO)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and four ZnC9H8S(NO)4 clusters. In each ZnC9H8S(NO)4 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to one N(4), one S(1), one O(1), and one O(4) atom. The Zn(1)-N(4) bond length is 2.06 Å. The Zn(1)-S(1) bond length is 2.36 Å. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(4) bond length is 2.00 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. The C(1)-N(1) bond length is 1.31 Å. The C(1)-N(2) bond length is 1.38 Å. The C(1)-S(1) bond length is 1.71 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(3), and one H(4) atom. The C(2)-C(3) bond length is 1.46 Å. The C(2)-N(3) bond length is 1.29 Å. The C(2)-H(4) bond length is 1.10 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(7) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(7) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(4)-H(5) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(6) atom. The C(5)-N(4) bond length is 1.34 Å. The C(5)-H(6) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(7) atom. The C(6)-N(4) bond length is 1.35 Å. The C(6)-H(7) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(3) and one H(8) atom. The C(7)-H(8) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(8)-O(1) bond length is 1.30 Å. The C(8)-O(2) bond length is 1.26 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(11)-O(3) bond length is 1.25 Å. The C(11)-O(4) bond length is 1.31 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.05 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one C(1), one N(3), and one H(3) atom. The N(2)-N(3) bond length is 1.34 Å. The N(2)-H(3) bond length is 1.02 Å. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one C(2) and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(5), and one C(6) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a distorted linear geometry to one N(1) and one O(2) atom. The H(2)-O(2) bond length is 1.65 Å. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. S(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a water-like geometry to one Zn(1) and one C(11) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the third O site, O(2) is bonded in a distorted bent 120 degrees geometry to one C(8) and one H(2) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one C(11) atom. Linkers: 4 NC(=S)N/N=C/c1ccncc1 ,4 [O]C(=O)CCC([O])=O. Metal clusters: 4 N[C]S[Zn](O[C]=O)O[C]=O. The MOF has largest included sphere 2.99 A, density 1.59 g/cm3, surface area 4494.85 m2/g, accessible volume 0.19 cm3/g