TbAgC24H14(N3O4)2CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a TbAgC24H14(N3O4)2 framework. In the TbAgC24H14(N3O4)2 framework, Tb(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(3) atoms. The Tb(1)-O(1) bond length is 2.52 Å. The Tb(1)-O(2) bond length is 2.43 Å. The Tb(1)-O(4) bond length is 2.42 Å. The Tb(1)-O(5) bond length is 2.47 Å. The Tb(1)-O(6) bond length is 2.37 Å. The Tb(1)-O(7) bond length is 2.41 Å. The Tb(1)-O(8) bond length is 2.39 Å. There is one shorter (2.37 Å) and one longer (2.54 Å) Tb(1)-O(3) bond length. Ag(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one N(4), and one N(5) atom. The Ag(1)-N(2) bond length is 2.18 Å. The Ag(1)-N(4) bond length is 2.42 Å. The Ag(1)-N(5) bond length is 2.16 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.42 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one N(1) atom. The C(5)-C(6) bond length is 1.42 Å. The C(5)-N(1) bond length is 1.38 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-N(2) bond length is 1.39 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(3) atom. The C(7)-H(3) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(4) atom. The C(8)-N(1) bond length is 1.36 Å. The C(8)-N(2) bond length is 1.33 Å. The C(8)-H(4) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(4) atom. The C(9)-C(10) bond length is 1.48 Å. The C(9)-O(3) bond length is 1.31 Å. The C(9)-O(4) bond length is 1.27 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-C(15) bond length is 1.40 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(11)-H(5) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(6) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(6) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one N(3) atom. The C(13)-C(14) bond length is 1.42 Å. The C(13)-N(3) bond length is 1.38 Å. In the thirteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one N(4) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-N(4) bond length is 1.40 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one H(7) atom. The C(15)-H(7) bond length is 1.09 Å. In the fifteenth C site, C(16) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(8) atom. The C(16)-N(3) bond length is 1.36 Å. The C(16)-N(4) bond length is 1.33 Å. The C(16)-H(8) bond length is 1.08 Å. In the sixteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(5), and one O(6) atom. The C(17)-C(18) bond length is 1.49 Å. The C(17)-O(5) bond length is 1.28 Å. The C(17)-O(6) bond length is 1.28 Å. In the seventeenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(23) atom. The C(18)-C(19) bond length is 1.42 Å. The C(18)-C(23) bond length is 1.40 Å. In the eighteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(9) atom. The C(19)-H(9) bond length is 1.09 Å. In the nineteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(10) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(10) bond length is 1.09 Å. In the twentieth C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one N(6) atom. The C(21)-C(22) bond length is 1.42 Å. The C(21)-N(6) bond length is 1.38 Å. In the twenty-first C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one N(5) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-N(5) bond length is 1.40 Å. In the twenty-second C site, C(23) is bonded in a distorted single-bond geometry to one C(18), one C(22), and one H(11) atom. The C(23)-H(11) bond length is 1.09 Å. In the twenty-third C site, C(24) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(12) atom. The C(24)-N(5) bond length is 1.33 Å. The C(24)-N(6) bond length is 1.36 Å. The C(24)-H(12) bond length is 1.08 Å. In the twenty-fourth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(25)-O(7) bond length is 1.27 Å. The C(25)-O(8) bond length is 1.26 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(5), one C(8), and one H(13) atom. The N(1)-H(13) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(6), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(13), one C(16), and one H(14) atom. The N(3)-H(14) bond length is 1.04 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(14), and one C(16) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(22), and one C(24) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(21), one C(24), and one H(15) atom. The N(6)-H(15) bond length is 1.04 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(24) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one N(1) atom. In the thirteenth H site, H(14) is bonded in a distorted single-bond geometry to one N(3) atom. In the fourteenth H site, H(15) is bonded in a distorted single-bond geometry to one N(6) and one O(2) atom. The H(15)-O(2) bond length is 1.72 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Tb(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Tb(1), one C(1), and one H(15) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Tb(1) and one C(9) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Tb(1) and one C(9) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Tb(1) and one C(17) atom. In the sixth O site, O(6) is bonded in a distorted L-shaped geometry to one Tb(1) and one C(17) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Tb(1) and one C(25) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Tb(1) and one C(25) atom. Linkers: 2 [O]C(=O)c1ccc2c(c1)N([Ag](N1[CH]Nc3ccc(C([O])=O)cc31)N1[CH]Nc3ccc(C([O])=O)cc31)[CH]N2. Metal clusters: 2 [Tb]. RCSR code: sql. The MOF has largest included sphere 2.73 A, density 2.13 g/cm3, surface area 3139.08 m2/g, accessible volume 0.10 cm3/g