CoZnC13NH9SO10(CH3)2 crystallizes in the tetragonal P4_2bc space group. The structure consists of sixteen 02329_fluka molecules inside a CoZnC13NH9SO10 framework. In the CoZnC13NH9SO10 framework, Co(1) is bonded to one O(1), one O(10), one O(4), one O(6), one O(7), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra. The Co(1)-O(1) bond length is 2.11 Å. The Co(1)-O(10) bond length is 2.06 Å. The Co(1)-O(4) bond length is 2.02 Å. The Co(1)-O(6) bond length is 2.04 Å. The Co(1)-O(7) bond length is 2.19 Å. The Co(1)-O(9) bond length is 2.13 Å. Zn(1) is bonded to one O(2), one O(3), one O(5), and one O(7) atom to form ZnO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 76°. The Zn(1)-O(2) bond length is 2.00 Å. The Zn(1)-O(3) bond length is 1.97 Å. The Zn(1)-O(5) bond length is 1.97 Å. The Zn(1)-O(7) bond length is 2.00 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(8) bond length is 1.50 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(1) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(1) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(9) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-C(9) bond length is 1.50 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(10), one C(5), and one C(7) atom. The C(6)-C(10) bond length is 1.50 Å. The C(6)-C(7) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(2) atom. The C(7)-H(2) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.28 Å. The C(8)-O(4) bond length is 1.27 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(5), and one O(6) atom. The C(9)-O(5) bond length is 1.28 Å. The C(9)-O(6) bond length is 1.26 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(7), and one O(8) atom. The C(10)-O(7) bond length is 1.32 Å. The C(10)-O(8) bond length is 1.24 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one N(1), one H(3), and one O(9) atom. The C(11)-N(1) bond length is 1.33 Å. The C(11)-H(3) bond length is 1.10 Å. The C(11)-O(9) bond length is 1.26 Å. In the twelfth C site, C(12) is bonded to one N(1), one H(4), one H(5), and one H(6) atom to form corner-sharing CH3N tetrahedra. The C(12)-N(1) bond length is 1.46 Å. The C(12)-H(4) bond length is 1.09 Å. The C(12)-H(5) bond length is 1.10 Å. The C(12)-H(6) bond length is 1.10 Å. In the thirteenth C site, C(13) is bonded to one N(1), one H(7), one H(8), and one H(9) atom to form corner-sharing CH3N tetrahedra. The C(13)-N(1) bond length is 1.46 Å. The C(13)-H(7) bond length is 1.10 Å. The C(13)-H(8) bond length is 1.10 Å. The C(13)-H(9) bond length is 1.10 Å. N(1) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(13) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. S(1) is bonded in a distorted single-bond geometry to one O(10) atom. The S(1)-O(10) bond length is 1.55 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Co(1) and one C(8) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Zn(1) and one C(9) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(9) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one Zn(1), and one C(10) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Co(1) and one C(11) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Co(1) and one S(1) atom. Linkers: 8 [O]C(=O)c1cc(C([O])=O)c(C([O])=O)cc1C([O])=O. Metal clusters: 8 [Zn] ,8 [Co]. The MOF has largest included sphere 4.80 A, density 1.68 g/cm3, surface area 3733.71 m2/g, accessible volume 0.15 cm3/g