(CH)3ZnC19N3H11SO4 crystallizes in the triclinic P1 space group. The structure consists of six 02329_fluka molecules inside a ZnC19N3H11SO4 framework. In the ZnC19N3H11SO4 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to one N(5), one N(6), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(5) bond length is 2.11 Å. The Zn(1)-N(6) bond length is 2.11 Å. The Zn(1)-O(1) bond length is 2.43 Å. The Zn(1)-O(2) bond length is 2.43 Å. The Zn(1)-O(3) bond length is 2.06 Å. The Zn(1)-O(4) bond length is 2.06 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to two equivalent N(1,2); one O(7); and one O(8) atom. Both Zn(2)-N(1,2) bond lengths are 2.06 Å. The Zn(2)-O(7) bond length is 2.00 Å. The Zn(2)-O(8) bond length is 2.00 Å. There are thirty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1,2); one N(3); and one S(1,2) atom. The C(1)-N(1,2) bond length is 1.34 Å. The C(1)-N(3) bond length is 1.37 Å. The C(1)-S(1,2) bond length is 1.74 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(1,2); one N(4); and one S(1,2) atom. The C(2)-N(1,2) bond length is 1.34 Å. The C(2)-N(4) bond length is 1.37 Å. The C(2)-S(1,2) bond length is 1.74 Å. In the third C site, C(3) is bonded in a 3-coordinate geometry to one C(13), one C(5), and one N(3) atom. The C(3)-C(13) bond length is 1.42 Å. The C(3)-C(5) bond length is 1.40 Å. The C(3)-N(3) bond length is 1.38 Å. In the fourth C site, C(4) is bonded in a 3-coordinate geometry to one C(14), one C(6), and one N(4) atom. The C(4)-C(14) bond length is 1.42 Å. The C(4)-C(6) bond length is 1.40 Å. The C(4)-N(4) bond length is 1.38 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(3,4) atom. The C(5)-H(3,4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(3,4) atom. The C(6)-H(3,4) bond length is 1.09 Å. In the seventh C site, C(11,12) is bonded in a distorted single-bond geometry to one C(13) and one H(9,10) atom. The C(11,12)-C(13) bond length is 1.40 Å. The C(11,12)-H(9,10) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(3); and one N(1,2) atom. The C(13)-N(1,2) bond length is 1.39 Å. In the ninth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(4); and one N(1,2) atom. The C(14)-C(11,12) bond length is 1.40 Å. The C(14)-N(1,2) bond length is 1.39 Å. In the tenth C site, C(15,16) is bonded in a distorted water-like geometry to one C(17); one H(11,12); one H(13,14); and one S(1,2) atom. The C(15,16)-C(17) bond length is 1.50 Å. The C(15,16)-H(11,12) bond length is 1.10 Å. The C(15,16)-H(13,14) bond length is 1.09 Å. The C(15,16)-S(1,2) bond length is 1.85 Å. In the eleventh C site, C(17) is bonded in a trigonal planar geometry to one C(15,16); one C(19,20); and one C(27) atom. The C(17)-C(19,20) bond length is 1.39 Å. The C(17)-C(27) bond length is 1.40 Å. In the twelfth C site, C(18) is bonded in a trigonal planar geometry to one C(15,16); one C(19,20); and one C(28) atom. The C(18)-C(15,16) bond length is 1.50 Å. The C(18)-C(19,20) bond length is 1.39 Å. The C(18)-C(28) bond length is 1.40 Å. In the thirteenth C site, C(19,20) is bonded in a distorted single-bond geometry to one C(17), one C(21), and one H(15) atom. The C(19,20)-C(21) bond length is 1.40 Å. The C(19,20)-H(15) bond length is 1.09 Å. In the fourteenth C site, C(21) is bonded in a trigonal planar geometry to one C(19,20); one C(23); and one C(29,30) atom. The C(21)-C(23) bond length is 1.40 Å. The C(21)-C(29,30) bond length is 1.48 Å. In the fifteenth C site, C(22) is bonded in a trigonal planar geometry to one C(19,20); one C(24); and one C(29,30) atom. The C(22)-C(19,20) bond length is 1.40 Å. The C(22)-C(24) bond length is 1.40 Å. The C(22)-C(29,30) bond length is 1.48 Å. In the sixteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(21), one C(25), and one H(17) atom. The C(23)-C(25) bond length is 1.40 Å. The C(23)-H(17) bond length is 1.09 Å. In the seventeenth C site, C(24) is bonded in a distorted single-bond geometry to one C(22), one C(26), and one H(18) atom. The C(24)-C(26) bond length is 1.40 Å. The C(24)-H(18) bond length is 1.09 Å. In the eighteenth C site, C(25) is bonded in a trigonal planar geometry to one C(23), one C(27), and one C(31) atom. The C(25)-C(27) bond length is 1.40 Å. The C(25)-C(31) bond length is 1.51 Å. In the nineteenth C site, C(26) is bonded in a trigonal planar geometry to one C(24), one C(28), and one C(32) atom. The C(26)-C(28) bond length is 1.40 Å. The C(26)-C(32) bond length is 1.51 Å. In the twentieth C site, C(27) is bonded in a distorted single-bond geometry to one C(17); one C(25); and one H(19,20) atom. The C(27)-H(19,20) bond length is 1.09 Å. In the twenty-first C site, C(28) is bonded in a distorted single-bond geometry to one C(18); one C(26); and one H(19,20) atom. The C(28)-H(19,20) bond length is 1.09 Å. In the twenty-second C site, C(29,30) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(1), and one O(3) atom. The C(29,30)-O(1) bond length is 1.26 Å. The C(29,30)-O(3) bond length is 1.31 Å. In the twenty-third C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(5), and one O(7) atom. The C(31)-O(5) bond length is 1.25 Å. The C(31)-O(7) bond length is 1.30 Å. In the twenty-fourth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(6), and one O(8) atom. The C(32)-O(6) bond length is 1.25 Å. The C(32)-O(8) bond length is 1.30 Å. In the twenty-fifth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(21,22) atom. The C(33)-N(5) bond length is 1.33 Å. The C(33)-H(21,22) bond length is 1.09 Å. In the twenty-sixth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(21,22) atom. The C(34)-N(6) bond length is 1.33 Å. The C(34)-H(21,22) bond length is 1.09 Å. In the twenty-seventh C site, C(35) is bonded in a distorted trigonal planar geometry to one C(36); one C(41,42); and one N(5) atom. The C(35)-C(36) bond length is 1.44 Å. The C(35)-C(41,42) bond length is 1.42 Å. The C(35)-N(5) bond length is 1.36 Å. In the twenty-eighth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(35); one C(41,42); and one N(6) atom. The C(36)-C(41,42) bond length is 1.42 Å. The C(36)-N(6) bond length is 1.36 Å. In the twenty-ninth C site, C(39) is bonded in a distorted single-bond geometry to one C(41,42) and one H(25,26) atom. The C(39)-C(41,42) bond length is 1.41 Å. The C(39)-H(25,26) bond length is 1.09 Å. In the thirtieth C site, C(40) is bonded in a distorted single-bond geometry to one C(41,42) and one H(25,26) atom. The C(40)-C(41,42) bond length is 1.41 Å. The C(40)-H(25,26) bond length is 1.09 Å. In the thirty-first C site, C(41,42) is bonded in a trigonal planar geometry to one C(35), one C(39), and one C(43) atom. The C(41,42)-C(43) bond length is 1.43 Å. In the thirty-second C site, C(43) is bonded in a distorted single-bond geometry to one C(41,42) and one H(27,28) atom. The C(43)-H(27,28) bond length is 1.09 Å. In the thirty-third C site, C(44) is bonded in a distorted single-bond geometry to one C(41,42) and one H(27,28) atom. The C(44)-C(41,42) bond length is 1.43 Å. The C(44)-H(27,28) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(1,2) is bonded in a trigonal planar geometry to one Zn(2), one C(1), and one C(13) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The N(3)-H(1) bond length is 1.04 Å. In the third N site, N(4) is bonded in a trigonal planar geometry to one C(2), one C(4), and one H(2) atom. The N(4)-H(2) bond length is 1.04 Å. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one Zn(1), one C(33), and one C(35) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one Zn(1), one C(34), and one C(36) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(9,10) is bonded in a single-bond geometry to one C(11,12) atom. In the fifth H site, H(11,12) is bonded in a single-bond geometry to one C(15,16) atom. In the sixth H site, H(13,14) is bonded in a single-bond geometry to one C(15,16) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(19,20) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(19,20) atom. The H(16)-C(19,20) bond length is 1.09 Å. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(19,20) is bonded in a single-bond geometry to one C(27) atom. In the twelfth H site, H(21,22) is bonded in a single-bond geometry to one C(33) atom. In the thirteenth H site, H(25,26) is bonded in a single-bond geometry to one C(39) atom. In the fourteenth H site, H(27,28) is bonded in a single-bond geometry to one C(43) atom. S(1,2) is bonded in a water-like geometry to one C(1) and one C(15,16) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Zn(1) and one C(29,30) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Zn(1) and one C(29,30) atom. The O(2)-C(29,30) bond length is 1.26 Å. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Zn(1) and one C(29,30) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Zn(1) and one C(29,30) atom. The O(4)-C(29,30) bond length is 1.31 Å. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(31) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(32) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Zn(2) and one C(31) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Zn(2) and one C(32) atom. Linkers: 2 [O]C(=O)c1cc(CSc2nc3ccccc3[nH]2)cc(C([O])=O)c1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.60 A, density 1.58 g/cm3, surface area 4323.03 m2/g, accessible volume 0.20 cm3/g