CuC14H14(N3O2)2(H2O)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four water molecules and two CuC14H14(N3O2)2 clusters. In each CuC14H14(N3O2)2 cluster, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent N(3) and two equivalent O(1) atoms. Both Cu(1)-N(3) bond lengths are 1.97 Å. Both Cu(1)-O(1) bond lengths are 1.99 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(3) atom. The C(1)-N(2) bond length is 1.33 Å. The C(1)-N(3) bond length is 1.36 Å. The C(1)-H(3) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(4) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(3) bond length is 1.34 Å. The C(2)-H(4) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one N(1), one H(5), and one H(6) atom. The C(3)-C(4) bond length is 1.51 Å. The C(3)-N(1) bond length is 1.46 Å. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(6) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(7) atom. The C(5)-H(7) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(8) atom. The C(6)-H(8) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one H(9), one O(1), and one O(2) atom. The C(7)-H(9) bond length is 1.11 Å. The C(7)-O(1) bond length is 1.28 Å. The C(7)-O(2) bond length is 1.26 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(1) and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. There are seven inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(7) atom. Linkers: 2 c1ncn(Cc2ccc(Cn3cncn3)cc2)n1 ,2 [c]1ncn(Cc2ccc(Cn3cncn3)cc2)n1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 1.80 A, density 1.67 g/cm3, surface area 4716.21 m2/g, accessible volume 0.20 cm3/g