TiC5NH8O4(CH3)8(CH2)2C2NH5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, sixteen 02329_fluka molecules, two dimethylamine molecules, and one TiC5NH8O4 cluster. In the TiC5NH8O4 cluster, Ti(1) is bonded to one N(1), one O(1), one O(2), one O(3), and two equivalent O(4) atoms to form distorted edge-sharing TiNO5 octahedra. The Ti(1)-N(1) bond length is 2.31 Å. The Ti(1)-O(1) bond length is 1.84 Å. The Ti(1)-O(2) bond length is 1.90 Å. The Ti(1)-O(3) bond length is 1.85 Å. There is one shorter (2.08 Å) and one longer (2.09 Å) Ti(1)-O(4) bond length. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one H(1) and one O(1) atom. The C(1)-H(1) bond length is 1.11 Å. The C(1)-O(1) bond length is 1.41 Å. In the second C site, C(4) is bonded in a distorted water-like geometry to one H(8) and one O(2) atom. The C(4)-H(8) bond length is 1.11 Å. The C(4)-O(2) bond length is 1.42 Å. In the third C site, C(7) is bonded in a distorted water-like geometry to one H(15) and one O(3) atom. The C(7)-H(15) bond length is 1.11 Å. The C(7)-O(3) bond length is 1.41 Å. In the fourth C site, C(10) is bonded in a distorted water-like geometry to one H(22) and one O(4) atom. The C(10)-H(22) bond length is 1.10 Å. The C(10)-O(4) bond length is 1.44 Å. In the fifth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(31), and one H(32) atom. The C(13)-N(1) bond length is 1.47 Å. The C(13)-H(31) bond length is 1.10 Å. The C(13)-H(32) bond length is 1.10 Å. N(1) is bonded in a 4-coordinate geometry to one Ti(1), one C(13), one H(29), and one H(30) atom. The N(1)-H(29) bond length is 1.02 Å. The N(1)-H(30) bond length is 1.03 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(22) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(29) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(30) is bonded in a single-bond geometry to one N(1) atom. In the seventh H site, H(31) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(32) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Ti(1) and one C(10) atom. In the second O site, O(1) is bonded in a bent 150 degrees geometry to one Ti(1) and one C(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Ti(1) and one C(4) atom. In the fourth O site, O(3) is bonded in a bent 150 degrees geometry to one Ti(1) and one C(7) atom. Linkers: 2 NC[CH]CNCCCCNCCCN ,1 NCCCNCCCCNCCCN. Metal clusters: . The MOF has largest included sphere 2.04 A, density 1.20 g/cm3, surface area 6714.50 m2/g, accessible volume 0.21 cm3/g