Na3C30H39S7O23(CH3)2(CH2)2CO crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules, four 02329_fluka molecules, and two formaldehyde molecules inside a Na3C30H39S7O23 framework. In the Na3C30H39S7O23 framework, there are three inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(16), one O(18), one O(21), one O(8), and two equivalent O(17) atoms to form a mixture of distorted edge and corner-sharing NaO6 octahedra. The corner-sharing octahedral tilt angles range from 64-66°. The Na(1)-O(16) bond length is 2.46 Å. The Na(1)-O(18) bond length is 2.38 Å. The Na(1)-O(21) bond length is 2.56 Å. The Na(1)-O(8) bond length is 2.41 Å. There is one shorter (2.45 Å) and one longer (2.53 Å) Na(1)-O(17) bond length. In the second Na site, Na(2) is bonded to one O(18), one O(20), one O(21), one O(22), and two equivalent O(19) atoms to form a mixture of edge and corner-sharing NaO6 octahedra. The corner-sharing octahedral tilt angles range from 64-66°. The Na(2)-O(18) bond length is 2.42 Å. The Na(2)-O(20) bond length is 2.41 Å. The Na(2)-O(21) bond length is 2.55 Å. The Na(2)-O(22) bond length is 2.49 Å. There is one shorter (2.35 Å) and one longer (2.46 Å) Na(2)-O(19) bond length. In the third Na site, Na(3) is bonded in a 5-coordinate geometry to one S(3), one O(15), one O(23), one O(3), one O(4), and one O(7) atom. The Na(3)-S(3) bond length is 3.04 Å. The Na(3)-O(15) bond length is 2.38 Å. The Na(3)-O(23) bond length is 2.29 Å. The Na(3)-O(3) bond length is 2.64 Å. The Na(3)-O(4) bond length is 2.34 Å. The Na(3)-O(7) bond length is 2.27 Å. There are thirty inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one O(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.42 Å. The C(1)-O(1) bond length is 1.35 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one S(4) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-S(4) bond length is 1.78 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one S(7) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-S(7) bond length is 1.79 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(2) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(2) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one S(1) atom. The C(6)-S(1) bond length is 1.78 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one O(2) atom. The C(7)-C(12) bond length is 1.40 Å. The C(7)-C(8) bond length is 1.40 Å. The C(7)-O(2) bond length is 1.38 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(7), one C(9), and one S(2) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-S(2) bond length is 1.79 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(3) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(3) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(27), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(27) bond length is 1.53 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(4) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(4) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(7), and one S(1) atom. The C(12)-S(1) bond length is 1.78 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one O(3) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(18) bond length is 1.42 Å. The C(13)-O(3) bond length is 1.34 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one S(3) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-S(3) bond length is 1.78 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(5) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(5) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one S(5) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-S(5) bond length is 1.77 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(6) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(6) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(13), one C(17), and one S(2) atom. The C(18)-S(2) bond length is 1.77 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(20), one C(24), and one O(4) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-C(24) bond length is 1.42 Å. The C(19)-O(4) bond length is 1.34 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one S(3) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-S(3) bond length is 1.78 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one H(7) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(7) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one S(6) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-S(6) bond length is 1.77 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(22), one C(24), and one H(8) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-H(8) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(19), one C(23), and one S(4) atom. The C(24)-S(4) bond length is 1.78 Å. In the twenty-fifth C site, C(25) is bonded in a distorted trigonal non-coplanar geometry to one H(18), one H(19), and one O(2) atom. The C(25)-H(18) bond length is 1.10 Å. The C(25)-H(19) bond length is 1.10 Å. The C(25)-O(2) bond length is 1.45 Å. In the twenty-sixth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(26)-O(5) bond length is 1.23 Å. The C(26)-O(6) bond length is 1.33 Å. In the twenty-seventh C site, C(27) is bonded in a tetrahedral geometry to one C(10), one C(28), one C(29), and one C(30) atom. The C(27)-C(28) bond length is 1.54 Å. The C(27)-C(29) bond length is 1.54 Å. The C(27)-C(30) bond length is 1.53 Å. In the twenty-eighth C site, C(28) is bonded in a trigonal non-coplanar geometry to one C(27); one H(11); and two equivalent H(9,10) atoms. The C(28)-H(11) bond length is 1.10 Å. Both C(28)-H(9,10) bond lengths are 1.10 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal non-coplanar geometry to one C(27), one H(12), one H(13), and one H(14) atom. The C(29)-H(12) bond length is 1.10 Å. The C(29)-H(13) bond length is 1.10 Å. The C(29)-H(14) bond length is 1.10 Å. In the thirtieth C site, C(30) is bonded in a trigonal non-coplanar geometry to one C(27), one H(15), one H(16), and one H(17) atom. The C(30)-H(15) bond length is 1.10 Å. The C(30)-H(16) bond length is 1.10 Å. The C(30)-H(17) bond length is 1.10 Å. There are thirty-eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(9,10) is bonded in a single-bond geometry to one C(28) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(28) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(29) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(29) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(30) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(30) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(30) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(25) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the nineteenth H site, H(20) is bonded in a distorted linear geometry to one O(13) and one O(6) atom. The H(20)-O(13) bond length is 1.61 Å. The H(20)-O(6) bond length is 1.02 Å. In the twentieth H site, H(21) is bonded in a single-bond geometry to one O(1) atom. The H(21)-O(1) bond length is 0.99 Å. In the twenty-first H site, H(22) is bonded in a distorted single-bond geometry to one O(2) and one O(3) atom. The H(22)-O(2) bond length is 1.69 Å. The H(22)-O(3) bond length is 1.00 Å. In the twenty-second H site, H(23) is bonded in a single-bond geometry to one O(4) atom. The H(23)-O(4) bond length is 0.99 Å. In the twenty-third H site, H(24) is bonded in a single-bond geometry to one O(16) atom. The H(24)-O(16) bond length is 0.98 Å. In the twenty-fourth H site, H(25) is bonded in a single-bond geometry to one O(16) and one O(7) atom. The H(25)-O(16) bond length is 0.99 Å. The H(25)-O(7) bond length is 1.70 Å. In the twenty-fifth H site, H(26) is bonded in a single-bond geometry to one O(17) atom. The H(26)-O(17) bond length is 0.98 Å. In the twenty-sixth H site, H(27) is bonded in a single-bond geometry to one O(17) atom. The H(27)-O(17) bond length is 0.99 Å. In the twenty-seventh H site, H(28) is bonded in a single-bond geometry to one O(18) atom. The H(28)-O(18) bond length is 0.98 Å. In the twenty-eighth H site, H(29) is bonded in a single-bond geometry to one O(18) atom. The H(29)-O(18) bond length is 0.99 Å. In the twenty-ninth H site, H(30) is bonded in a single-bond geometry to one O(19) and one O(8) atom. The H(30)-O(19) bond length is 0.99 Å. The H(30)-O(8) bond length is 1.77 Å. In the thirtieth H site, H(31) is bonded in a single-bond geometry to one O(19) atom. The H(31)-O(19) bond length is 0.98 Å. In the thirty-first H site, H(32) is bonded in a single-bond geometry to one O(20) atom. The H(32)-O(20) bond length is 0.99 Å. In the thirty-second H site, H(33) is bonded in a single-bond geometry to one O(20) atom. The H(33)-O(20) bond length is 0.99 Å. In the thirty-third H site, H(34) is bonded in a single-bond geometry to one O(21) atom. The H(34)-O(21) bond length is 0.97 Å. In the thirty-fourth H site, H(35) is bonded in a single-bond geometry to one O(21) atom. The H(35)-O(21) bond length is 0.99 Å. In the thirty-fifth H site, H(36) is bonded in a single-bond geometry to one O(22) atom. The H(36)-O(22) bond length is 0.98 Å. In the thirty-sixth H site, H(37) is bonded in a single-bond geometry to one O(22) atom. The H(37)-O(22) bond length is 0.99 Å. In the thirty-seventh H site, H(38) is bonded in a single-bond geometry to one O(23) atom. The H(38)-O(23) bond length is 0.99 Å. In the thirty-eighth H site, H(39) is bonded in a single-bond geometry to one O(23) atom. The H(39)-O(23) bond length is 0.98 Å. There are seven inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(12) and one C(6) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(18) and one C(8) atom. In the third S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to one Na(3), one C(14), and one C(20) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one C(2) and one C(24) atom. In the fifth S site, S(5) is bonded in a distorted trigonal non-coplanar geometry to one C(16), one O(7), one O(8), and one O(9) atom. The S(5)-O(7) bond length is 1.48 Å. The S(5)-O(8) bond length is 1.47 Å. The S(5)-O(9) bond length is 1.46 Å. In the sixth S site, S(6) is bonded in a distorted trigonal non-coplanar geometry to one C(22), one O(10), one O(11), and one O(12) atom. The S(6)-O(10) bond length is 1.49 Å. The S(6)-O(11) bond length is 1.47 Å. The S(6)-O(12) bond length is 1.47 Å. In the seventh S site, S(7) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one O(13), one O(14), and one O(15) atom. The S(7)-O(13) bond length is 1.49 Å. The S(7)-O(14) bond length is 1.47 Å. The S(7)-O(15) bond length is 1.47 Å. There are twenty-three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(1) and one H(21) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one C(25), one C(7), and one H(22) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(3), one C(13), and one H(22) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(3), one C(19), and one H(23) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(26) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one C(26) and one H(20) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(3), one H(25), and one S(5) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Na(1), one H(30), and one S(5) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one S(5) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one S(6) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one S(6) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one S(6) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one H(20) and one S(7) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one S(7) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Na(3) and one S(7) atom. In the sixteenth O site, O(16) is bonded in a water-like geometry to one Na(1), one H(24), and one H(25) atom. In the seventeenth O site, O(17) is bonded in a distorted water-like geometry to two equivalent Na(1), one H(26), and one H(27) atom. In the eighteenth O site, O(18) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(28), and one H(29) atom. In the nineteenth O site, O(19) is bonded in a distorted water-like geometry to two equivalent Na(2), one H(30), and one H(31) atom. In the twentieth O site, O(20) is bonded in a distorted water-like geometry to one Na(2), one H(32), and one H(33) atom. In the twenty-first O site, O(21) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(34), and one H(35) atom. In the twenty-second O site, O(22) is bonded in a water-like geometry to one Na(2), one H(36), and one H(37) atom. In the twenty-third O site, O(23) is bonded in a distorted water-like geometry to one Na(3), one H(38), and one H(39) atom. Linkers: 2 CC(C)(C)c1cc2c(OCC(=O)O)c(c1)Sc1cc(S([O])([O])[O])cc(c1O)Sc1cc(S([O])([O])[O])cc(c1O)Sc1cc(S([O])([O])[O])cc(c1O)S2. Metal clusters: 6 [Na]. The MOF has largest included sphere 3.06 A, density 1.55 g/cm3, surface area 4151.07 m2/g, accessible volume 0.16 cm3/g