(C7H6)2Pb4H36(C4O)13 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two C7H6 clusters and two Pb4H36(C4O)13 clusters. In each C7H6 cluster, there are seven inequivalent C sites. In the first C site, C(15) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(9) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-C(19) bond length is 1.41 Å. The C(15)-C(9) bond length is 1.48 Å. In the second C site, C(17) is bonded in a distorted single-bond geometry to one C(15); one C(19); and one H(9,10) atom. The C(17)-C(19) bond length is 1.40 Å. The C(17)-H(9,10) bond length is 1.09 Å. In the third C site, C(65) is bonded in a distorted trigonal non-coplanar geometry to one C(19); one H(43,44); one H(45,46); and one H(47,48) atom. The C(65)-C(19) bond length is 1.51 Å. The C(65)-H(43,44) bond length is 1.10 Å. The C(65)-H(45,46) bond length is 1.10 Å. The C(65)-H(47,48) bond length is 1.10 Å. In the fourth C site, C(19) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(65) atom. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one C(11,12); one C(15); and one C(7,8) atom. The C(9)-C(11,12) bond length is 1.41 Å. The C(9)-C(7,8) bond length is 1.40 Å. In the sixth C site, C(11,12) is bonded in a distorted single-bond geometry to one C(9) and one H(5,6) atom. The C(11,12)-H(5,6) bond length is 1.09 Å. In the seventh C site, C(7,8) is bonded in a distorted single-bond geometry to one C(9) and one H(3,4) atom. The C(7,8)-H(3,4) bond length is 1.09 Å. There are six inequivalent H sites. In the first H site, H(3,4) is bonded in a single-bond geometry to one C(7,8) atom. In the second H site, H(5,6) is bonded in a single-bond geometry to one C(11,12) atom. In the third H site, H(9,10) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(43,44) is bonded in a single-bond geometry to one C(65) atom. In the fifth H site, H(45,46) is bonded in a single-bond geometry to one C(65) atom. In the sixth H site, H(47,48) is bonded in a single-bond geometry to one C(65) atom. In each Pb4H36(C4O)13 cluster, there are two inequivalent Pb sites. In the first Pb site, Pb(1,2) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(13), one O(3), one O(4), and one O(5) atom. The Pb(1,2)-O(1) bond length is 2.71 Å. The Pb(1,2)-O(12) bond length is 2.65 Å. The Pb(1,2)-O(13) bond length is 2.29 Å. The Pb(1,2)-O(3) bond length is 2.58 Å. The Pb(1,2)-O(4) bond length is 2.69 Å. The Pb(1,2)-O(5) bond length is 2.57 Å. In the second Pb site, Pb(3,4) is bonded in a 1-coordinate geometry to one O(13) atom. The Pb(3,4)-O(13) bond length is 2.36 Å. There are forty-four inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1,2)-C(3) bond length is 1.49 Å. The C(1,2)-O(1) bond length is 1.27 Å. The C(1,2)-O(3) bond length is 1.30 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(1,2); one C(13,14); and one C(5,6) atom. The C(3)-C(13,14) bond length is 1.40 Å. The C(3)-C(5,6) bond length is 1.40 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(1,2); one C(13,14); and one C(5,6) atom. The C(4)-C(1,2) bond length is 1.49 Å. The C(4)-C(13,14) bond length is 1.40 Å. The C(4)-C(5,6) bond length is 1.40 Å. In the fourth C site, C(5,6) is bonded in a distorted single-bond geometry to one C(3) and one H(1,2) atom. The C(5,6)-H(1,2) bond length is 1.09 Å. In the fifth C site, C(13,14) is bonded in a distorted single-bond geometry to one C(3) and one H(7,8) atom. The C(13,14)-H(7,8) bond length is 1.09 Å. In the sixth C site, C(21,22) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(5), and one O(7) atom. The C(21,22)-C(23) bond length is 1.50 Å. The C(21,22)-O(5) bond length is 1.28 Å. The C(21,22)-O(7) bond length is 1.28 Å. In the seventh C site, C(23) is bonded in a trigonal planar geometry to one C(21,22); one C(25,26); and one C(33,34) atom. The C(23)-C(25,26) bond length is 1.40 Å. The C(23)-C(33,34) bond length is 1.40 Å. In the eighth C site, C(24) is bonded in a trigonal planar geometry to one C(21,22); one C(25,26); and one C(33,34) atom. The C(24)-C(21,22) bond length is 1.50 Å. The C(24)-C(25,26) bond length is 1.40 Å. The C(24)-C(33,34) bond length is 1.40 Å. In the ninth C site, C(25,26) is bonded in a distorted trigonal planar geometry to one C(23), one C(27), and one H(11) atom. The C(25,26)-C(27) bond length is 1.39 Å. The C(25,26)-H(11) bond length is 1.09 Å. In the tenth C site, C(27) is bonded in a distorted single-bond geometry to one C(25,26); one C(29); and one H(13,14) atom. The C(27)-C(29) bond length is 1.40 Å. The C(27)-H(13,14) bond length is 1.09 Å. In the eleventh C site, C(28) is bonded in a distorted single-bond geometry to one C(25,26); one C(30); and one H(13,14) atom. The C(28)-C(25,26) bond length is 1.39 Å. The C(28)-C(30) bond length is 1.40 Å. The C(28)-H(13,14) bond length is 1.09 Å. In the twelfth C site, C(29) is bonded in a trigonal planar geometry to one C(27), one C(31), and one C(35) atom. The C(29)-C(31) bond length is 1.40 Å. The C(29)-C(35) bond length is 1.48 Å. In the thirteenth C site, C(30) is bonded in a trigonal planar geometry to one C(28), one C(32), and one C(36) atom. The C(30)-C(32) bond length is 1.40 Å. The C(30)-C(36) bond length is 1.48 Å. In the fourteenth C site, C(31) is bonded in a distorted single-bond geometry to one C(29) and one H(15,16) atom. The C(31)-H(15,16) bond length is 1.09 Å. In the fifteenth C site, C(32) is bonded in a distorted single-bond geometry to one C(30) and one H(15,16) atom. The C(32)-H(15,16) bond length is 1.09 Å. In the sixteenth C site, C(33,34) is bonded in a distorted single-bond geometry to one C(23) and one H(17,18) atom. The C(33,34)-H(17,18) bond length is 1.09 Å. In the seventeenth C site, C(35) is bonded in a trigonal planar geometry to one C(29), one C(37), and one C(45) atom. The C(35)-C(37) bond length is 1.40 Å. The C(35)-C(45) bond length is 1.41 Å. In the eighteenth C site, C(36) is bonded in a trigonal planar geometry to one C(30), one C(38), and one C(46) atom. The C(36)-C(38) bond length is 1.40 Å. The C(36)-C(46) bond length is 1.41 Å. In the nineteenth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(35); one C(39); and one H(19,20) atom. The C(37)-C(39) bond length is 1.40 Å. The C(37)-H(19,20) bond length is 1.09 Å. In the twentieth C site, C(38) is bonded in a distorted single-bond geometry to one C(36); one C(40); and one H(19,20) atom. The C(38)-C(40) bond length is 1.40 Å. The C(38)-H(19,20) bond length is 1.09 Å. In the twenty-first C site, C(39) is bonded in a trigonal planar geometry to one C(37), one C(41), and one C(47) atom. The C(39)-C(41) bond length is 1.41 Å. The C(39)-C(47) bond length is 1.50 Å. In the twenty-second C site, C(40) is bonded in a trigonal planar geometry to one C(38), one C(42), and one C(48) atom. The C(40)-C(42) bond length is 1.41 Å. The C(40)-C(48) bond length is 1.50 Å. In the twenty-third C site, C(41) is bonded in a trigonal planar geometry to one C(39), one C(43), and one C(59) atom. The C(41)-C(43) bond length is 1.40 Å. The C(41)-C(59) bond length is 1.48 Å. In the twenty-fourth C site, C(42) is bonded in a trigonal planar geometry to one C(40), one C(44), and one C(60) atom. The C(42)-C(44) bond length is 1.40 Å. The C(42)-C(60) bond length is 1.48 Å. In the twenty-fifth C site, C(43) is bonded in a distorted single-bond geometry to one C(41); one C(45); and one H(21,22) atom. The C(43)-C(45) bond length is 1.40 Å. The C(43)-H(21,22) bond length is 1.09 Å. In the twenty-sixth C site, C(44) is bonded in a distorted single-bond geometry to one C(42); one C(46); and one H(21,22) atom. The C(44)-C(46) bond length is 1.40 Å. The C(44)-H(21,22) bond length is 1.09 Å. In the twenty-seventh C site, C(45) is bonded in a trigonal planar geometry to one C(35), one C(43), and one C(49) atom. The C(45)-C(49) bond length is 1.51 Å. In the twenty-eighth C site, C(46) is bonded in a trigonal planar geometry to one C(36), one C(44), and one C(50) atom. The C(46)-C(50) bond length is 1.51 Å. In the twenty-ninth C site, C(47) is bonded in a distorted trigonal non-coplanar geometry to one C(39); one H(23,24); one H(25,26); and one H(27,28) atom. The C(47)-H(23,24) bond length is 1.10 Å. The C(47)-H(25,26) bond length is 1.10 Å. The C(47)-H(27,28) bond length is 1.10 Å. In the thirtieth C site, C(48) is bonded in a distorted trigonal non-coplanar geometry to one C(40); one H(23,24); one H(25,26); and one H(27,28) atom. The C(48)-H(23,24) bond length is 1.10 Å. The C(48)-H(25,26) bond length is 1.10 Å. The C(48)-H(27,28) bond length is 1.10 Å. In the thirty-first C site, C(49) is bonded in a distorted trigonal non-coplanar geometry to one C(45); one H(29,30); one H(31,32); and one H(33,34) atom. The C(49)-H(29,30) bond length is 1.09 Å. The C(49)-H(31,32) bond length is 1.10 Å. The C(49)-H(33,34) bond length is 1.10 Å. In the thirty-second C site, C(50) is bonded in a distorted trigonal non-coplanar geometry to one C(46); one H(29,30); one H(31,32); and one H(33,34) atom. The C(50)-H(29,30) bond length is 1.09 Å. The C(50)-H(31,32) bond length is 1.10 Å. The C(50)-H(33,34) bond length is 1.10 Å. In the thirty-third C site, C(51) is bonded in a distorted bent 120 degrees geometry to one C(53), one O(11), and one O(9) atom. The C(51)-C(53) bond length is 1.49 Å. The C(51)-O(11) bond length is 1.30 Å. The C(51)-O(9) bond length is 1.26 Å. In the thirty-fourth C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(54), one O(10), and one O(12) atom. The C(52)-C(54) bond length is 1.49 Å. The C(52)-O(10) bond length is 1.26 Å. The C(52)-O(12) bond length is 1.30 Å. In the thirty-fifth C site, C(53) is bonded in a trigonal planar geometry to one C(51), one C(55), and one C(63) atom. The C(53)-C(55) bond length is 1.40 Å. The C(53)-C(63) bond length is 1.40 Å. In the thirty-sixth C site, C(54) is bonded in a trigonal planar geometry to one C(52), one C(56), and one C(64) atom. The C(54)-C(56) bond length is 1.40 Å. The C(54)-C(64) bond length is 1.40 Å. In the thirty-seventh C site, C(55) is bonded in a distorted single-bond geometry to one C(53) and one H(35,36) atom. The C(55)-H(35,36) bond length is 1.09 Å. In the thirty-eighth C site, C(56) is bonded in a distorted single-bond geometry to one C(54) and one H(35,36) atom. The C(56)-H(35,36) bond length is 1.09 Å. In the thirty-ninth C site, C(57,58) is bonded in a distorted single-bond geometry to one C(59) and one H(37,38) atom. The C(57,58)-C(59) bond length is 1.41 Å. The C(57,58)-H(37,38) bond length is 1.09 Å. In the fortieth C site, C(59) is bonded in a trigonal planar geometry to one C(41); one C(57,58); and one C(61,62) atom. The C(59)-C(61,62) bond length is 1.41 Å. In the forty-first C site, C(60) is bonded in a trigonal planar geometry to one C(42); one C(57,58); and one C(61,62) atom. The C(60)-C(57,58) bond length is 1.41 Å. The C(60)-C(61,62) bond length is 1.41 Å. In the forty-second C site, C(61,62) is bonded in a distorted single-bond geometry to one C(59) and one H(39,40) atom. The C(61,62)-H(39,40) bond length is 1.09 Å. In the forty-third C site, C(63) is bonded in a distorted single-bond geometry to one C(53) and one H(41,42) atom. The C(63)-H(41,42) bond length is 1.09 Å. In the forty-fourth C site, C(64) is bonded in a distorted single-bond geometry to one C(54) and one H(41,42) atom. The C(64)-H(41,42) bond length is 1.09 Å. There are nineteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(5,6) atom. In the second H site, H(7,8) is bonded in a single-bond geometry to one C(13,14) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(25,26) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(25,26) atom. The H(12)-C(25,26) bond length is 1.09 Å. In the fifth H site, H(13,14) is bonded in a single-bond geometry to one C(27) atom. In the sixth H site, H(15,16) is bonded in a single-bond geometry to one C(31) atom. In the seventh H site, H(17,18) is bonded in a single-bond geometry to one C(33,34) atom. In the eighth H site, H(19,20) is bonded in a single-bond geometry to one C(37) atom. In the ninth H site, H(21,22) is bonded in a single-bond geometry to one C(43) atom. In the tenth H site, H(23,24) is bonded in a single-bond geometry to one C(47) atom. In the eleventh H site, H(25,26) is bonded in a single-bond geometry to one C(47) atom. In the twelfth H site, H(27,28) is bonded in a single-bond geometry to one C(47) atom. In the thirteenth H site, H(29,30) is bonded in a single-bond geometry to one C(49) atom. In the fourteenth H site, H(31,32) is bonded in a single-bond geometry to one C(49) atom. In the fifteenth H site, H(33,34) is bonded in a single-bond geometry to one C(49) atom. In the sixteenth H site, H(35,36) is bonded in a single-bond geometry to one C(55) atom. In the seventeenth H site, H(37,38) is bonded in a single-bond geometry to one C(57,58) atom. In the eighteenth H site, H(39,40) is bonded in a single-bond geometry to one C(61,62) atom. In the nineteenth H site, H(41,42) is bonded in a single-bond geometry to one C(63) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Pb(1,2) and one C(1,2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Pb(1,2) and one C(1,2) atom. The O(2)-Pb(1,2) bond length is 2.71 Å. The O(2)-C(1,2) bond length is 1.27 Å. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Pb(1,2) and one C(1,2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Pb(1,2) and one C(1,2) atom. The O(4)-C(1,2) bond length is 1.30 Å. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Pb(1,2) and one C(21,22) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Pb(1,2) and one C(21,22) atom. The O(6)-Pb(1,2) bond length is 2.57 Å. The O(6)-C(21,22) bond length is 1.28 Å. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(21,22) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(21,22) atom. The O(8)-C(21,22) bond length is 1.28 Å. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(51) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(52) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Pb(1,2) and one C(51) atom. The O(11)-Pb(1,2) bond length is 2.65 Å. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Pb(1,2) and one C(52) atom. In the thirteenth O site, O(13) is bonded in a tetrahedral geometry to two equivalent Pb(1,2) and two equivalent Pb(3,4) atoms. Linkers: 6 Cc1cc(-c2ccc(C([O])=O)cc2)c(C)cc1-c1ccc(C([O])=O)cc1. Metal clusters: 8 [Pb]. The MOF has largest included sphere 5.65 A, density 1.99 g/cm3, surface area 2948.04 m2/g, accessible volume 0.18 cm3/g