Mo2C11H14(NO)6(CH)2CH2 crystallizes in the orthorhombic Pnma space group. The structure consists of eight 02329_fluka molecules and four 02329_fluka molecules inside a Mo2C11H14(NO)6 framework. In the Mo2C11H14(NO)6 framework, Mo(1) is bonded in a 6-coordinate geometry to one N(2), one N(4), one O(1), one O(2), one O(3), and one O(4) atom. The Mo(1)-N(2) bond length is 2.38 Å. The Mo(1)-N(4) bond length is 2.39 Å. The Mo(1)-O(1) bond length is 1.93 Å. The Mo(1)-O(2) bond length is 1.73 Å. The Mo(1)-O(3) bond length is 1.92 Å. The Mo(1)-O(4) bond length is 1.73 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-N(2) bond length is 1.32 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(2) atom. The C(2)-N(3) bond length is 1.37 Å. The C(2)-N(4) bond length is 1.32 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded to one C(4), two equivalent C(8), and one N(1) atom to form distorted corner-sharing CC3N tetrahedra. The C(3)-C(4) bond length is 1.54 Å. Both C(3)-C(8) bond lengths are 1.54 Å. The C(3)-N(1) bond length is 1.48 Å. In the fourth C site, C(4) is bonded in a distorted water-like geometry to one C(3), one C(5), and two equivalent H(3) atoms. The C(4)-C(5) bond length is 1.54 Å. Both C(4)-H(3) bond lengths are 1.10 Å. In the fifth C site, C(5) is bonded to one C(4), two equivalent C(6), and one N(3) atom to form distorted corner-sharing CC3N tetrahedra. Both C(5)-C(6) bond lengths are 1.53 Å. The C(5)-N(3) bond length is 1.48 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one C(5), one H(4), and one H(5) atom. The C(6)-H(4) bond length is 1.10 Å. The C(6)-H(5) bond length is 1.10 Å. In the seventh C site, C(8) is bonded in a distorted water-like geometry to one C(3) and two equivalent H(7,8) atoms. Both C(8)-H(7,8) bond lengths are 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(3) and two equivalent C(1) atoms. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Mo(1), one C(1), and one N(2) atom. The N(2)-N(2) bond length is 1.37 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(5) and two equivalent C(2) atoms. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Mo(1), one C(2), and one N(4) atom. The N(4)-N(4) bond length is 1.37 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(8) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Mo(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third O site, O(3) is bonded in a linear geometry to two equivalent Mo(1) atoms. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. Linkers: 4 c1nncn1[C@]12C[C@H]3C[C@H](C[C@](n4cnnc4)(C3)C1)C2. Metal clusters: 8 [Mo]. The MOF has largest included sphere 3.57 A, density 1.69 g/cm3, surface area 3187.35 m2/g, accessible volume 0.26 cm3/g