(CH2)2CuC8N2H12S2Cl is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four CuC8N2H12S2Cl clusters. In each CuC8N2H12S2Cl cluster, Cu(1) is bonded to one S(1), two equivalent S(2), and one Cl(1) atom to form distorted edge-sharing CuS3Cl tetrahedra. The Cu(1)-S(1) bond length is 2.29 Å. There is one shorter (2.34 Å) and one longer (2.40 Å) Cu(1)-S(2) bond length. The Cu(1)-Cl(1) bond length is 2.30 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one N(1), and one S(1) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-S(1) bond length is 1.69 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one C(1), one H(1), and one H(2) atom. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. In the third C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(5), and one H(6) atom. The C(4)-N(1) bond length is 1.47 Å. The C(4)-H(5) bond length is 1.10 Å. The C(4)-H(6) bond length is 1.10 Å. In the fourth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent H(7,8) atoms. The C(5)-N(1) bond length is 1.45 Å. Both C(5)-H(7,8) bond lengths are 1.10 Å. In the fifth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(10), and one H(9) atom. The C(6)-N(2) bond length is 1.45 Å. The C(6)-H(10) bond length is 1.10 Å. The C(6)-H(9) bond length is 1.10 Å. In the sixth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(11), and one H(12) atom. The C(7)-N(2) bond length is 1.47 Å. The C(7)-H(11) bond length is 1.10 Å. The C(7)-H(12) bond length is 1.10 Å. In the seventh C site, C(9) is bonded in a distorted water-like geometry to one C(10), one H(15), and one H(16) atom. The C(9)-C(10) bond length is 1.50 Å. The C(9)-H(15) bond length is 1.10 Å. The C(9)-H(16) bond length is 1.10 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one S(2) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-S(2) bond length is 1.69 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(6), and one C(7) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(7,8) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(9) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Cu(1) and one C(1) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cu(1) and one C(10) atom. Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 4 S=C1CCCN1CCN1CCCC1=S. Metal clusters: 2 [S][Cu]12(Cl)S[Cu]1([S])(Cl)S2. The MOF has largest included sphere 1.89 A, density 1.77 g/cm3, surface area 4167.08 m2/g, accessible volume 0.11 cm3/g