(CH)2CdC22N8H24SO7 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a CdC22N8H24SO7 framework. In the CdC22N8H24SO7 framework, Cd(1) is bonded to one N(2), one N(5), one N(6), one N(8), one O(3), and one O(4) atom to form CdN4O2 octahedra that share  a cornercorner with one S(1)O4 tetrahedra. The Cd(1)-N(2) bond length is 2.34 Å. The Cd(1)-N(5) bond length is 2.36 Å. The Cd(1)-N(6) bond length is 2.34 Å. The Cd(1)-N(8) bond length is 2.37 Å. The Cd(1)-O(3) bond length is 2.54 Å. The Cd(1)-O(4) bond length is 2.36 Å. There are twenty-two inequivalent C sites. In the first C site, C(6) is bonded in a trigonal planar geometry to one N(3), one N(4), and one O(2) atom. The C(6)-N(3) bond length is 1.39 Å. The C(6)-N(4) bond length is 1.38 Å. The C(6)-O(2) bond length is 1.24 Å. In the second C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(8), one N(4), one H(5), and one H(6) atom. The C(7)-C(8) bond length is 1.51 Å. The C(7)-N(4) bond length is 1.45 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. In the third C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.39 Å. In the fourth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(9) atom. The C(11)-N(8) bond length is 1.35 Å. The C(11)-H(9) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(8), and one H(10) atom. The C(12)-N(8) bond length is 1.34 Å. The C(12)-H(10) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(5), and one H(11) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-N(5) bond length is 1.35 Å. The C(13)-H(11) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(12) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(12) bond length is 1.09 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(13) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(13) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(24) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-C(24) bond length is 1.51 Å. In the eleventh C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(5), and one H(14) atom. The C(17)-N(5) bond length is 1.34 Å. The C(17)-H(14) bond length is 1.09 Å. In the twelfth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(19), one N(6), and one H(16) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-N(6) bond length is 1.35 Å. The C(18)-H(16) bond length is 1.09 Å. In the thirteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(17) atom. The C(19)-H(17) bond length is 1.09 Å. In the fourteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(18) atom. The C(20)-C(21) bond length is 1.41 Å. The C(20)-H(18) bond length is 1.09 Å. In the fifteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one N(7) atom. The C(21)-C(22) bond length is 1.41 Å. The C(21)-N(7) bond length is 1.38 Å. In the sixteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(6), and one H(19) atom. The C(22)-N(6) bond length is 1.34 Å. The C(22)-H(19) bond length is 1.09 Å. In the seventeenth C site, C(23) is bonded in a trigonal planar geometry to one N(1), one N(7), and one O(1) atom. The C(23)-N(1) bond length is 1.37 Å. The C(23)-N(7) bond length is 1.39 Å. The C(23)-O(1) bond length is 1.24 Å. In the eighteenth C site, C(24) is bonded in a distorted trigonal non-coplanar geometry to one C(16), one N(1), one H(23), and one H(24) atom. The C(24)-N(1) bond length is 1.45 Å. The C(24)-H(23) bond length is 1.10 Å. The C(24)-H(24) bond length is 1.10 Å. In the nineteenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1) atom. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the twentieth C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the twenty-first C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(3) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-N(3) bond length is 1.38 Å. In the twenty-second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(4) atom. The C(5)-N(2) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(23), one C(24), and one H(15) atom. The N(1)-H(15) bond length is 1.02 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(4), one C(6), and one H(20) atom. The N(3)-H(20) bond length is 1.04 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(6), one C(7), and one H(21) atom. The N(4)-H(21) bond length is 1.02 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(17) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cd(1), one C(18), and one C(22) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(21), one C(23), and one H(22) atom. The N(7)-H(22) bond length is 1.04 Å. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(12) atom. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one N(1) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(20) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(22) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one N(3) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one N(4) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one N(7) and one O(5) atom. The H(22)-O(5) bond length is 1.72 Å. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(24) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(24) atom. In the twenty-third H site, H(25) is bonded in a distorted single-bond geometry to one O(3) and one O(5) atom. The H(25)-O(3) bond length is 1.01 Å. The H(25)-O(5) bond length is 1.67 Å. In the twenty-fourth H site, H(26) is bonded in a single-bond geometry to one O(3) atom. The H(26)-O(3) bond length is 0.97 Å. S(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 57°. The S(1)-O(4) bond length is 1.50 Å. The S(1)-O(5) bond length is 1.52 Å. The S(1)-O(6) bond length is 1.47 Å. The S(1)-O(7) bond length is 1.49 Å. There are seven inequivalent O sites. In the first O site, O(5) is bonded in a distorted trigonal planar geometry to one H(22), one H(25), and one S(1) atom. In the second O site, O(6) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one S(1) atom. In the fourth O site, O(3) is bonded in a water-like geometry to one Cd(1), one H(25), and one H(26) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one C(23) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one C(6) atom. In the seventh O site, O(4) is bonded in a bent 120 degrees geometry to one Cd(1) and one S(1) atom. Linkers: 2 O.[O]S([O])([O])O[Cd](N1[CH]C=[C][C]=C1)(N1[CH]C=CC(CNC(=O)Nc2cccnc2)=C1)(N1[CH]C=CC(CNC(=O)Nc2cccnc2)=C1)N1[CH]C=CC(NC(=O)NCc2cccnc2)=C1 ,2 O.[O]S([O])([O])O[Cd](N1[CH]C=CC(CNC(=O)Nc2cccnc2)=C1)(N1[CH]C=CC(CNC(=O)Nc2cccnc2)=C1)(N1[CH]C=CC(NC(=O)NCc2cccnc2)=C1)N1[CH]C=CC(NC(=O)NCc2cccnc2)=C1 ,2 O.[O]S([O])([O])O[Cd](N1[CH]C=CC(CNC(=O)Nc2cccnc2)=C1)(N1[CH]C=CC(CNC(=O)Nc2cccnc2)=C1)(N1[CH]C=CC([N][C]=O)=C1)N1[CH]C=CC(NC(=O)NCc2cccnc2)=C1. Metal clusters: 2 O.[O]S([O])([O])O[Cd]. The MOF has largest included sphere 3.59 A, density 1.56 g/cm3, surface area 4332.49 m2/g, accessible volume 0.17 cm3/g