Co(C8H6NO2)2CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and two Co(C8H6NO2)2 clusters. In each Co(C8H6NO2)2 cluster, Co(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Co(1)-N(1) bond length is 2.08 Å. The Co(1)-N(2) bond length is 2.06 Å. The Co(1)-O(1) bond length is 2.27 Å. The Co(1)-O(2) bond length is 2.12 Å. The Co(1)-O(3) bond length is 2.18 Å. The Co(1)-O(4) bond length is 2.19 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(13), one C(2), and one N(1) atom. The C(1)-C(13) bond length is 1.49 Å. The C(1)-C(2) bond length is 1.41 Å. The C(1)-N(1) bond length is 1.34 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(12) bond length is 1.42 Å. The C(4)-C(5) bond length is 1.43 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(6)-C(7) bond length is 1.43 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.42 Å. The C(7)-C(8) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(6) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-H(6) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(14), one C(9), and one N(2) atom. The C(10)-C(14) bond length is 1.49 Å. The C(10)-N(2) bond length is 1.34 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(7), and one N(2) atom. The C(11)-C(12) bond length is 1.43 Å. The C(11)-N(2) bond length is 1.36 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(4), and one N(1) atom. The C(12)-N(1) bond length is 1.36 Å. In the thirteenth C site, C(13) is bonded in a trigonal non-coplanar geometry to one C(1), one H(7), one H(8), and one H(9) atom. The C(13)-H(7) bond length is 1.10 Å. The C(13)-H(8) bond length is 1.09 Å. The C(13)-H(9) bond length is 1.10 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one H(10), one H(11), and one H(12) atom. The C(14)-H(10) bond length is 1.10 Å. The C(14)-H(11) bond length is 1.10 Å. The C(14)-H(12) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(15)-O(1) bond length is 1.27 Å. The C(15)-O(2) bond length is 1.28 Å. In the sixteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(17)-O(3) bond length is 1.28 Å. The C(17)-O(4) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(12) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(10), and one C(11) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Co(1) and one C(15) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Co(1) and one C(15) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Co(1) and one C(17) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Co(1) and one C(17) atom. Linkers: 2 [O]C(=O)CC([O])=O. Metal clusters: 2 [C]1O[Co]2(O1)O[C]O2. The MOF has largest included sphere 1.75 A, density 1.72 g/cm3, surface area 4346.26 m2/g, accessible volume 0.09 cm3/g