AgC24H20(NO)5(CH2)4(CH)4 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, sixteen 02329_fluka molecules, and four AgC24H20(NO)5 clusters. In each AgC24H20(NO)5 cluster, Ag(1) is bonded in a 3-coordinate geometry to one N(1), one N(4), and one O(4) atom. The Ag(1)-N(1) bond length is 2.13 Å. The Ag(1)-N(4) bond length is 2.13 Å. The Ag(1)-O(4) bond length is 2.69 Å. There are twenty-four inequivalent C sites. In the first C site, C(32) is bonded in a distorted single-bond geometry to one C(27) and one H(32) atom. The C(32)-C(27) bond length is 1.40 Å. The C(32)-H(32) bond length is 1.09 Å. In the second C site, C(1) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(1) atom. The C(1)-C(5) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the third C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the fourth C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.09 Å. In the fifth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the sixth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.51 Å. In the seventh C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one N(2), one H(5), and one H(6) atom. The C(6)-N(2) bond length is 1.47 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the eighth C site, C(7) is bonded in a distorted water-like geometry to one N(2) and one H(7) atom. The C(7)-N(2) bond length is 1.47 Å. The C(7)-H(7) bond length is 1.10 Å. In the ninth C site, C(12) is bonded in a distorted water-like geometry to one N(3) and one H(16) atom. The C(12)-N(3) bond length is 1.47 Å. The C(12)-H(16) bond length is 1.10 Å. In the tenth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one C(14), one N(3), one H(17), and one H(18) atom. The C(13)-C(14) bond length is 1.51 Å. The C(13)-N(3) bond length is 1.46 Å. The C(13)-H(17) bond length is 1.10 Å. The C(13)-H(18) bond length is 1.10 Å. In the eleventh C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(18) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(18) bond length is 1.40 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(19) atom. The C(15)-H(19) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(20) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(20) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(4), and one H(21) atom. The C(17)-N(4) bond length is 1.35 Å. The C(17)-H(21) bond length is 1.09 Å. In the fifteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(4), and one H(22) atom. The C(18)-N(4) bond length is 1.34 Å. The C(18)-H(22) bond length is 1.09 Å. In the sixteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(20), one N(2), and one O(1) atom. The C(19)-C(20) bond length is 1.50 Å. The C(19)-N(2) bond length is 1.37 Å. The C(19)-O(1) bond length is 1.25 Å. In the seventeenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(25) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(25) bond length is 1.40 Å. In the eighteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(23) atom. The C(21)-H(23) bond length is 1.09 Å. In the nineteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(20) and one H(27) atom. The C(25)-H(27) bond length is 1.09 Å. In the twentieth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(27), one N(3), and one O(2) atom. The C(26)-C(27) bond length is 1.50 Å. The C(26)-N(3) bond length is 1.37 Å. The C(26)-O(2) bond length is 1.25 Å. In the twenty-first C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(32) atom. The C(27)-C(28) bond length is 1.40 Å. In the twenty-second C site, C(28) is bonded in a distorted single-bond geometry to one C(27), one C(29), and one H(28) atom. The C(28)-C(29) bond length is 1.39 Å. The C(28)-H(28) bond length is 1.09 Å. In the twenty-third C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one C(30), and one H(29) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-H(29) bond length is 1.09 Å. In the twenty-fourth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(30) atom. The C(30)-H(30) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(19), one C(6), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(26) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(1), one C(17), and one C(18) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. The N(5)-O(3) bond length is 1.26 Å. The N(5)-O(4) bond length is 1.27 Å. The N(5)-O(5) bond length is 1.28 Å. There are twenty inequivalent H sites. In the first H site, H(32) is bonded in a single-bond geometry to one C(32) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(17) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(23) is bonded in a single-bond geometry to one C(21) atom. In the seventeenth H site, H(30) is bonded in a single-bond geometry to one C(30) atom. In the eighteenth H site, H(27) is bonded in a single-bond geometry to one C(25) atom. In the nineteenth H site, H(28) is bonded in a single-bond geometry to one C(28) atom. In the twentieth H site, H(29) is bonded in a single-bond geometry to one C(29) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(19) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(26) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(5) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(1) and one N(5) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(5) atom. Linkers: 4 O=C(c1ccccc1)N(Cc1cccnc1)[C@@H]1CCCC[C@H]1N(Cc1cccnc1)C(=O)c1ccccc1. Metal clusters: 4 [Ag].[O][N+](=O)[O-]. The MOF has largest included sphere 4.15 A, density 1.39 g/cm3, surface area 4823.11 m2/g, accessible volume 0.20 cm3/g