AgH16(C7N2)2AgBr2(CH)4 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two dibromosilver molecules, and two AgH16(C7N2)2 clusters. In each AgH16(C7N2)2 cluster, Ag(1) is bonded in a linear geometry to one C(1,2) and one C(3) atom. The Ag(1)-C(1,2) bond length is 2.08 Å. The Ag(1)-C(3) bond length is 2.08 Å. There are fourteen inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal planar geometry to one Ag(1), one N(1), and one N(5) atom. The C(1,2)-N(1) bond length is 1.36 Å. The C(1,2)-N(5) bond length is 1.36 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one N(3), and one N(7) atom. The C(3)-N(3) bond length is 1.36 Å. The C(3)-N(7) bond length is 1.36 Å. In the third C site, C(5,6,8) is bonded in a distorted single-bond geometry to one C(13,14) and one H(1,2) atom. The C(5,6,8)-C(13,14) bond length is 1.39 Å. The C(5,6,8)-H(1,2) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(15) and one H(3) atom. The C(7)-C(15) bond length is 1.39 Å. The C(7)-H(3) bond length is 1.09 Å. In the fifth C site, C(13,14) is bonded in a distorted single-bond geometry to one C(21,22); one C(5,6,8); and one N(5) atom. The C(13,14)-C(21,22) bond length is 1.41 Å. The C(13,14)-N(5) bond length is 1.39 Å. In the sixth C site, C(15) is bonded in a distorted single-bond geometry to one C(23), one C(7), and one N(7) atom. The C(15)-C(23) bond length is 1.41 Å. The C(15)-N(7) bond length is 1.39 Å. In the seventh C site, C(17,18) is bonded in a distorted single-bond geometry to one C(21,22) and one H(9,10,12) atom. The C(17,18)-C(21,22) bond length is 1.39 Å. The C(17,18)-H(9,10,12) bond length is 1.09 Å. In the eighth C site, C(19,20) is bonded in a distorted single-bond geometry to one C(23) and one H(11) atom. The C(19,20)-C(23) bond length is 1.39 Å. The C(19,20)-H(11) bond length is 1.09 Å. In the ninth C site, C(21,22) is bonded in a distorted single-bond geometry to one C(13,14); one C(17,18); and one N(1) atom. The C(21,22)-N(1) bond length is 1.39 Å. In the tenth C site, C(23) is bonded in a distorted single-bond geometry to one C(15); one C(19,20); and one N(3) atom. The C(23)-N(3) bond length is 1.39 Å. In the eleventh C site, C(25,26) is bonded in a tetrahedral geometry to one N(5); one H(13,14); one H(17,18,19,20); and one H(21,22) atom. The C(25,26)-N(5) bond length is 1.46 Å. The C(25,26)-H(13,14) bond length is 1.10 Å. The C(25,26)-H(17,18,19,20) bond length is 1.10 Å. The C(25,26)-H(21,22) bond length is 1.10 Å. In the twelfth C site, C(27,28) is bonded in a tetrahedral geometry to one N(7); one H(15,16); one H(17,18,19,20); and one H(23,24) atom. The C(27,28)-N(7) bond length is 1.46 Å. The C(27,28)-H(15,16) bond length is 1.10 Å. The C(27,28)-H(17,18,19,20) bond length is 1.10 Å. The C(27,28)-H(23,24) bond length is 1.10 Å. In the thirteenth C site, C(29,30) is bonded in a tetrahedral geometry to one N(1); one H(25,26,27,28); one H(29,30,31,32); and one H(33,34,35,36) atom. The C(29,30)-N(1) bond length is 1.45 Å. The C(29,30)-H(25,26,27,28) bond length is 1.10 Å. The C(29,30)-H(29,30,31,32) bond length is 1.10 Å. The C(29,30)-H(33,34,35,36) bond length is 1.10 Å. In the fourteenth C site, C(31) is bonded in a tetrahedral geometry to one N(3); one H(25,26,27,28); one H(29,30,31,32); and one H(33,34,35,36) atom. The C(31)-N(3) bond length is 1.45 Å. The C(31)-H(25,26,27,28) bond length is 1.10 Å. The C(31)-H(29,30,31,32) bond length is 1.10 Å. The C(31)-H(33,34,35,36) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1,2); one C(21,22); and one C(29,30) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(23), one C(3), and one C(31) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one C(1,2); one C(13,14); and one C(25,26) atom. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one C(15); one C(27,28); and one C(3) atom. There are twelve inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(5,6,8) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(9,10,12) is bonded in a single-bond geometry to one C(17,18) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(19,20) atom. In the fifth H site, H(13,14) is bonded in a single-bond geometry to one C(25,26) atom. In the sixth H site, H(15,16) is bonded in a single-bond geometry to one C(27,28) atom. In the seventh H site, H(17,18,19,20) is bonded in a single-bond geometry to one C(25,26) atom. In the eighth H site, H(21,22) is bonded in a single-bond geometry to one C(25,26) atom. In the ninth H site, H(23,24) is bonded in a single-bond geometry to one C(27,28) atom. In the tenth H site, H(25,26,27,28) is bonded in a single-bond geometry to one C(29,30) atom. In the eleventh H site, H(29,30,31,32) is bonded in a single-bond geometry to one C(29,30) atom. In the twelfth H site, H(33,34,35,36) is bonded in a single-bond geometry to one C(29,30) atom. Linkers: 1 CN1[C]N(C)c2ccccc21. Metal clusters: . The MOF has largest included sphere 1.71 A, density 2.27 g/cm3, surface area 3431.60 m2/g, accessible volume 0.07 cm3/g