CH2(CH)2SnC9N2H11O3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 02329_fluka molecules, and one SnC9N2H11O3 cluster. In the SnC9N2H11O3 cluster, Sn(1) is bonded in a 7-coordinate geometry to one C(12), one C(8), one N(2), one O(2), one O(3), and two equivalent O(1) atoms. The Sn(1)-C(12) bond length is 2.13 Å. The Sn(1)-C(8) bond length is 2.13 Å. The Sn(1)-N(2) bond length is 2.26 Å. The Sn(1)-O(2) bond length is 2.22 Å. The Sn(1)-O(3) bond length is 2.67 Å. There is one shorter (2.23 Å) and one longer (2.68 Å) Sn(1)-O(1) bond length. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(2) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-O(2) bond length is 1.30 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(1) atom. The C(2)-C(4) bond length is 1.44 Å. The C(2)-N(2) bond length is 1.30 Å. The C(2)-H(1) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one O(1) atom. The C(3)-C(4) bond length is 1.43 Å. The C(3)-O(1) bond length is 1.32 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(3) atom. The C(4)-C(10) bond length is 1.42 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one O(3) atom. The C(5)-O(3) bond length is 1.38 Å. In the sixth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(5), one H(6), and one H(7) atom. The C(8)-H(5) bond length is 1.09 Å. The C(8)-H(6) bond length is 1.09 Å. The C(8)-H(7) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(4) and one H(9) atom. The C(10)-H(9) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a tetrahedral geometry to one H(10), one H(11), one H(12), and one O(3) atom. The C(11)-H(10) bond length is 1.10 Å. The C(11)-H(11) bond length is 1.09 Å. The C(11)-H(12) bond length is 1.10 Å. The C(11)-O(3) bond length is 1.44 Å. In the ninth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(13), one H(14), and one H(15) atom. The C(12)-H(13) bond length is 1.09 Å. The C(12)-H(14) bond length is 1.09 Å. The C(12)-H(15) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one C(1) and one N(2) atom. The N(1)-N(2) bond length is 1.38 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Sn(1), one C(2), and one N(1) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(12) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent Sn(1) and one C(3) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Sn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Sn(1), one C(11), and one C(5) atom. Linkers: 1 [C]Oc1cccc(/C=N/[N]C(=O)CCC(=O)[N]/N=C/c2cccc(O[C])c2[O])c1[O] ,2 [C]Oc1cccc(/C=N/[N]C(=O)CCC(=O)[N]N=[CH])c1[O]. Metal clusters: 1 CO/[C]=[C]\O[Sn][O].CO/[C]=[C]\O[Sn][O]. The MOF has largest included sphere 2.19 A, density 1.86 g/cm3, surface area 3821.70 m2/g, accessible volume 0.11 cm3/g