CoC10H10(NO)4(CH)8 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two o-xylene molecules and two CoC10H10(NO)4 clusters. In each CoC10H10(NO)4 cluster, Co(1) is bonded in a distorted trigonal pyramidal geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Co(1)-N(1) bond lengths are 2.00 Å. Both Co(1)-O(1) bond lengths are 1.96 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(2), and one H(9) atom. The C(9)-C(6) bond length is 1.37 Å. The C(9)-N(2) bond length is 1.38 Å. The C(9)-H(9) bond length is 1.08 Å. In the third C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(3), and one H(4) atom. The C(4)-N(2) bond length is 1.46 Å. The C(4)-H(3) bond length is 1.09 Å. The C(4)-H(4) bond length is 1.10 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(5) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-N(2) bond length is 1.36 Å. The C(5)-H(5) bond length is 1.08 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(1), and one H(6) atom. The C(6)-N(1) bond length is 1.39 Å. The C(6)-H(6) bond length is 1.08 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(5), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(9) atom. There are five inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Linkers: 2 c1cn(CCn2ccnc2)cn1. Metal clusters: 2 O=[C]O[Co]O[C]=O. The MOF has largest included sphere 2.10 A, density 1.55 g/cm3, surface area 4216.41 m2/g, accessible volume 0.10 cm3/g