Cu5C38N18H24(O7F3)2 crystallizes in the triclinic P-1 space group. There are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one N(3), one N(4), one O(2), one O(3), and one O(7) atom to form distorted edge-sharing CuN2O3 trigonal bipyramids. The Cu(1)-N(3) bond length is 2.04 Å. The Cu(1)-N(4) bond length is 2.01 Å. The Cu(1)-O(2) bond length is 2.00 Å. The Cu(1)-O(3) bond length is 1.96 Å. The Cu(1)-O(7) bond length is 2.36 Å. In the second Cu site, Cu(2) is bonded to two equivalent N(4), two equivalent O(1), and two equivalent O(7) atoms to form edge-sharing CuN2O4 octahedra. Both Cu(2)-N(4) bond lengths are 2.03 Å. Both Cu(2)-O(1) bond lengths are 1.99 Å. Both Cu(2)-O(7) bond lengths are 2.38 Å. In the third Cu site, Cu(3) is bonded to two equivalent N(2), two equivalent N(7), and two equivalent O(5) atoms to form corner-sharing CuN4O2 octahedra. The corner-sharing octahedral tilt angles are 55°. Both Cu(3)-N(2) bond lengths are 2.04 Å. Both Cu(3)-N(7) bond lengths are 2.04 Å. Both Cu(3)-O(5) bond lengths are 2.36 Å. In the fourth Cu site, Cu(4) is bonded to two equivalent N(1), two equivalent N(7), and two equivalent O(6) atoms to form distorted corner-sharing CuN4O2 octahedra. The corner-sharing octahedral tilt angles are 55°. Both Cu(4)-N(1) bond lengths are 2.50 Å. Both Cu(4)-N(7) bond lengths are 2.06 Å. Both Cu(4)-O(6) bond lengths are 1.97 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(3) bond length is 1.29 Å. The C(1)-O(4) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(2) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one F(1,2) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-F(1,2) bond length is 1.36 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(4) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(1), and one O(2) atom. The C(7)-C(8) bond length is 1.50 Å. The C(7)-O(1) bond length is 1.27 Å. The C(7)-O(2) bond length is 1.28 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(2), and one H(5) atom. The C(9)-N(2) bond length is 1.34 Å. The C(9)-H(5) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(10)-H(6) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one F(1,2) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-F(1,2) bond length is 1.35 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one H(7) atom. The C(12)-N(2) bond length is 1.34 Å. The C(12)-H(7) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(5), and one O(6) atom. The C(13)-C(14) bond length is 1.51 Å. The C(13)-O(5) bond length is 1.25 Å. The C(13)-O(6) bond length is 1.29 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(18) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(18) bond length is 1.40 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(8) atom. The C(15)-H(8) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a single-bond geometry to one C(17) and one F(3) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-F(3) bond length is 1.36 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(3), and one H(9) atom. The C(17)-N(3) bond length is 1.35 Å. The C(17)-H(9) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(3), and one H(10) atom. The C(18)-N(3) bond length is 1.34 Å. The C(18)-H(10) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one H(11), one H(12), and one O(7) atom. The C(19)-H(11) bond length is 1.10 Å. The C(19)-H(12) bond length is 1.10 Å. The C(19)-O(7) bond length is 1.43 Å. There are nine inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(4), one C(3), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(3), one C(12), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(17), and one C(18) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one Cu(2), and one N(5) atom. The N(4)-N(5) bond length is 1.22 Å. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.16 Å. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Cu(3), one Cu(4), and one N(8) atom. The N(7)-N(8) bond length is 1.22 Å. In the eighth N site, N(8) is bonded in a linear geometry to one N(7) and one N(9) atom. The N(8)-N(9) bond length is 1.16 Å. In the ninth N site, N(9) is bonded in a single-bond geometry to one N(8) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(4) and one O(7) atom. The H(1)-O(4) bond length is 1.57 Å. The H(1)-O(7) bond length is 1.02 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(1) and one H(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cu(3) and one C(13) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one C(13) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Cu(1), one Cu(2), one C(19), and one H(1) atom. There are two inequivalent F sites. In the first F site, F(1,2) is bonded in a single-bond geometry to one C(5) atom. In the second F site, F(3) is bonded in a single-bond geometry to one C(16) atom. Linkers: 4 [O]C(=O)c1cncc(F)c1 ,1 OCCO. Metal clusters: 5 [Cu]. The MOF has largest included sphere 2.40 A, density 1.96 g/cm3, surface area 3647.02 m2/g, accessible volume 0.11 cm3/g