AgC11H8(NO)2(CH)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; four 2,3-dimethyl-1,3-butadiene molecules; and eight AgC11H8(NO)2 clusters. In each AgC11H8(NO)2 cluster, Ag(1) is bonded in a distorted T-shaped geometry to one N(1), one N(2), and one O(3) atom. The Ag(1)-N(1) bond length is 2.16 Å. The Ag(1)-N(2) bond length is 2.17 Å. The Ag(1)-O(3) bond length is 2.57 Å. There are eleven inequivalent C sites. In the first C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(10)-O(3) bond length is 1.27 Å. The C(10)-O(4) bond length is 1.27 Å. In the second C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(9) bond length is 1.09 Å. In the third C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(10) bond length is 1.09 Å. In the fourth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(16) bond length is 1.47 Å. In the fifth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(14)-H(11) bond length is 1.09 Å. In the sixth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(12) atom. The C(15)-N(1) bond length is 1.35 Å. The C(15)-H(12) bond length is 1.09 Å. In the seventh C site, C(16) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(20) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(20) bond length is 1.40 Å. In the eighth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(13) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(13) bond length is 1.09 Å. In the ninth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one N(2), and one H(14) atom. The C(18)-N(2) bond length is 1.35 Å. The C(18)-H(14) bond length is 1.09 Å. In the tenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(20), one N(2), and one H(15) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-N(2) bond length is 1.35 Å. The C(19)-H(15) bond length is 1.09 Å. In the eleventh C site, C(20) is bonded in a distorted single-bond geometry to one C(16), one C(19), and one H(16) atom. The C(20)-H(16) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(11), and one C(15) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(18), and one C(19) atom. There are eight inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one Ag(1) and one C(10) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(10) atom. Linkers: 8 c1cc(-c2ccncc2)ccn1 ,4 [O]C(=O)Cc1ccccc1CC([O])=O. Metal clusters: 4 O=[C]O[Ag][Ag].[O][C]=O. The MOF has largest included sphere 3.74 A, density 1.66 g/cm3, surface area 3933.76 m2/g, accessible volume 0.16 cm3/g