Zn2C40H28(N2O3)3 crystallizes in the triclinic P1 space group. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one N(6), one N(7), one O(13), and one O(6) atom. The Zn(1)-N(6) bond length is 2.02 Å. The Zn(1)-N(7) bond length is 1.98 Å. The Zn(1)-O(13) bond length is 1.98 Å. The Zn(1)-O(6) bond length is 2.02 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one N(4), one N(8), one O(14), and one O(4) atom. The Zn(2)-N(4) bond length is 2.02 Å. The Zn(2)-N(8) bond length is 1.98 Å. The Zn(2)-O(14) bond length is 1.98 Å. The Zn(2)-O(4) bond length is 2.02 Å. In the third Zn site, Zn(3) is bonded in a tetrahedral geometry to one N(5), one N(9), one O(15), and one O(5) atom. The Zn(3)-N(5) bond length is 2.03 Å. The Zn(3)-N(9) bond length is 1.98 Å. The Zn(3)-O(15) bond length is 1.98 Å. The Zn(3)-O(5) bond length is 2.02 Å. In the fourth Zn site, Zn(4) is bonded in a distorted octahedral geometry to one N(1), one O(1), one O(10), one O(19), one O(25), and one O(7) atom. The Zn(4)-N(1) bond length is 2.07 Å. The Zn(4)-O(1) bond length is 2.12 Å. The Zn(4)-O(10) bond length is 2.49 Å. The Zn(4)-O(19) bond length is 2.09 Å. The Zn(4)-O(25) bond length is 2.21 Å. The Zn(4)-O(7) bond length is 2.06 Å. In the fifth Zn site, Zn(5) is bonded in a distorted octahedral geometry to one N(2), one O(11), one O(2), one O(20), one O(26), and one O(8) atom. The Zn(5)-N(2) bond length is 2.07 Å. The Zn(5)-O(11) bond length is 2.49 Å. The Zn(5)-O(2) bond length is 2.12 Å. The Zn(5)-O(20) bond length is 2.09 Å. The Zn(5)-O(26) bond length is 2.21 Å. The Zn(5)-O(8) bond length is 2.06 Å. In the sixth Zn site, Zn(6) is bonded in a distorted octahedral geometry to one N(3), one O(12), one O(21), one O(27), one O(3), and one O(9) atom. The Zn(6)-N(3) bond length is 2.07 Å. The Zn(6)-O(12) bond length is 2.49 Å. The Zn(6)-O(21) bond length is 2.09 Å. The Zn(6)-O(27) bond length is 2.21 Å. The Zn(6)-O(3) bond length is 2.12 Å. The Zn(6)-O(9) bond length is 2.06 Å. There are eighty-eight inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(10), one O(10), and one O(7) atom. The C(1)-C(10) bond length is 1.50 Å. The C(1)-O(10) bond length is 1.26 Å. The C(1)-O(7) bond length is 1.29 Å. In the second C site, C(2) is bonded in a bent 120 degrees geometry to one C(11,12); one O(11); and one O(8) atom. The C(2)-C(11,12) bond length is 1.50 Å. The C(2)-O(11) bond length is 1.26 Å. The C(2)-O(8) bond length is 1.29 Å. In the third C site, C(3) is bonded in a bent 120 degrees geometry to one C(11,12); one O(12); and one O(9) atom. The C(3)-C(11,12) bond length is 1.50 Å. The C(3)-O(12) bond length is 1.26 Å. The C(3)-O(9) bond length is 1.29 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(1), and one O(4) atom. The C(4)-C(22) bond length is 1.50 Å. The C(4)-O(1) bond length is 1.26 Å. The C(4)-O(4) bond length is 1.28 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(2), and one O(5) atom. The C(5)-C(23) bond length is 1.50 Å. The C(5)-O(2) bond length is 1.26 Å. The C(5)-O(5) bond length is 1.28 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(3), and one O(6) atom. The C(6)-C(24) bond length is 1.50 Å. The C(6)-O(3) bond length is 1.26 Å. The C(6)-O(6) bond length is 1.28 Å. In the seventh C site, C(7,9) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(13), and one O(16) atom. The C(7,9)-C(19) bond length is 1.50 Å. The C(7,9)-O(13) bond length is 1.30 Å. The C(7,9)-O(16) bond length is 1.25 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(14), and one O(17) atom. The C(8)-C(20) bond length is 1.50 Å. The C(8)-O(14) bond length is 1.30 Å. The C(8)-O(17) bond length is 1.25 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(1); one C(13,15); and one C(16,18) atom. The C(10)-C(13,15) bond length is 1.40 Å. The C(10)-C(16,18) bond length is 1.40 Å. In the tenth C site, C(11,12) is bonded in a trigonal planar geometry to one C(14), one C(17), and one C(2) atom. The C(11,12)-C(14) bond length is 1.40 Å. The C(11,12)-C(17) bond length is 1.40 Å. In the eleventh C site, C(13,15) is bonded in a distorted single-bond geometry to one C(10) and one H(1,2,3) atom. The C(13,15)-H(1,2,3) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(11,12) and one H(1,2,3) atom. The C(14)-H(1,2,3) bond length is 1.09 Å. In the thirteenth C site, C(16,18) is bonded in a distorted single-bond geometry to one C(10); one C(19); and one H(4,5,6) atom. The C(16,18)-C(19) bond length is 1.40 Å. The C(16,18)-H(4,5,6) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(11,12); one C(20); and one H(4,5,6) atom. The C(17)-C(20) bond length is 1.40 Å. The C(17)-H(4,5,6) bond length is 1.09 Å. In the fifteenth C site, C(19) is bonded in a trigonal planar geometry to one C(16,18); one C(22); and one C(7,9) atom. The C(19)-C(22) bond length is 1.41 Å. In the sixteenth C site, C(20) is bonded in a trigonal planar geometry to one C(17), one C(23), and one C(8) atom. The C(20)-C(23) bond length is 1.41 Å. In the seventeenth C site, C(21) is bonded in a trigonal planar geometry to one C(16,18); one C(24); and one C(7,9) atom. The C(21)-C(16,18) bond length is 1.40 Å. The C(21)-C(24) bond length is 1.41 Å. The C(21)-C(7,9) bond length is 1.50 Å. In the eighteenth C site, C(22) is bonded in a trigonal planar geometry to one C(19); one C(25,26,27); and one C(4) atom. The C(22)-C(25,26,27) bond length is 1.40 Å. In the nineteenth C site, C(23) is bonded in a trigonal planar geometry to one C(20); one C(25,26,27); and one C(5) atom. The C(23)-C(25,26,27) bond length is 1.40 Å. In the twentieth C site, C(24) is bonded in a trigonal planar geometry to one C(21); one C(25,26,27); and one C(6) atom. The C(24)-C(25,26,27) bond length is 1.40 Å. In the twenty-first C site, C(25,26,27) is bonded in a distorted single-bond geometry to one C(22) and one H(7,8,9) atom. The C(25,26,27)-H(7,8,9) bond length is 1.09 Å. In the twenty-second C site, C(28,30) is bonded in a distorted trigonal planar geometry to one C(49), one N(4), and one H(10) atom. The C(28,30)-C(49) bond length is 1.39 Å. The C(28,30)-N(4) bond length is 1.35 Å. The C(28,30)-H(10) bond length is 1.09 Å. In the twenty-third C site, C(29) is bonded in a distorted trigonal planar geometry to one C(50), one N(5), and one H(11) atom. The C(29)-C(50) bond length is 1.39 Å. The C(29)-N(5) bond length is 1.35 Å. The C(29)-H(11) bond length is 1.09 Å. In the twenty-fourth C site, C(31,33) is bonded in a distorted trigonal planar geometry to one C(43); one N(4); and one H(13,14) atom. The C(31,33)-C(43) bond length is 1.39 Å. The C(31,33)-N(4) bond length is 1.35 Å. The C(31,33)-H(13,14) bond length is 1.09 Å. In the twenty-fifth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(44); one N(5); and one H(13,14) atom. The C(32)-C(44) bond length is 1.39 Å. The C(32)-N(5) bond length is 1.35 Å. The C(32)-H(13,14) bond length is 1.09 Å. In the twenty-sixth C site, C(34,36) is bonded in a distorted trigonal planar geometry to one C(37); one C(55); and one H(16,17,18) atom. The C(34,36)-C(37) bond length is 1.40 Å. The C(34,36)-C(55) bond length is 1.39 Å. The C(34,36)-H(16,17,18) bond length is 1.09 Å. In the twenty-seventh C site, C(35) is bonded in a distorted trigonal planar geometry to one C(38,39); one C(56,57); and one H(16,17,18) atom. The C(35)-C(38,39) bond length is 1.40 Å. The C(35)-C(56,57) bond length is 1.39 Å. The C(35)-H(16,17,18) bond length is 1.09 Å. In the twenty-eighth C site, C(37) is bonded in a trigonal planar geometry to one C(34,36); one C(40,41,42); and one C(85,86,87) atom. The C(37)-C(40,41,42) bond length is 1.40 Å. The C(37)-C(85,86,87) bond length is 1.47 Å. In the twenty-ninth C site, C(38,39) is bonded in a trigonal planar geometry to one C(35); one C(40,41,42); and one C(85,86,87) atom. The C(38,39)-C(40,41,42) bond length is 1.40 Å. The C(38,39)-C(85,86,87) bond length is 1.47 Å. In the thirtieth C site, C(40,41,42) is bonded in a distorted single-bond geometry to one C(37) and one H(19,20,21) atom. The C(40,41,42)-H(19,20,21) bond length is 1.09 Å. In the thirty-first C site, C(43) is bonded in a distorted single-bond geometry to one C(31,33); one C(46); and one H(22,23,24) atom. The C(43)-C(46) bond length is 1.41 Å. The C(43)-H(22,23,24) bond length is 1.09 Å. In the thirty-second C site, C(44) is bonded in a distorted single-bond geometry to one C(32); one C(47); and one H(22,23,24) atom. The C(44)-C(47) bond length is 1.41 Å. The C(44)-H(22,23,24) bond length is 1.09 Å. In the thirty-third C site, C(45) is bonded in a distorted single-bond geometry to one C(31,33); one C(48); and one H(22,23,24) atom. The C(45)-C(31,33) bond length is 1.39 Å. The C(45)-C(48) bond length is 1.41 Å. The C(45)-H(22,23,24) bond length is 1.09 Å. In the thirty-fourth C site, C(46) is bonded in a trigonal planar geometry to one C(115), one C(43), and one C(49) atom. The C(46)-C(115) bond length is 1.47 Å. The C(46)-C(49) bond length is 1.41 Å. In the thirty-fifth C site, C(47) is bonded in a trigonal planar geometry to one C(116), one C(44), and one C(50) atom. The C(47)-C(116) bond length is 1.47 Å. The C(47)-C(50) bond length is 1.41 Å. In the thirty-sixth C site, C(48) is bonded in a trigonal planar geometry to one C(117), one C(45), and one C(51) atom. The C(48)-C(117) bond length is 1.47 Å. The C(48)-C(51) bond length is 1.41 Å. In the thirty-seventh C site, C(49) is bonded in a distorted single-bond geometry to one C(28,30); one C(46); and one H(25,27) atom. The C(49)-H(25,27) bond length is 1.09 Å. In the thirty-eighth C site, C(50) is bonded in a distorted single-bond geometry to one C(29), one C(47), and one H(26) atom. The C(50)-H(26) bond length is 1.09 Å. In the thirty-ninth C site, C(51) is bonded in a distorted single-bond geometry to one C(28,30); one C(48); and one H(25,27) atom. The C(51)-C(28,30) bond length is 1.39 Å. The C(51)-H(25,27) bond length is 1.09 Å. In the fortieth C site, C(52) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(28,30) atom. The C(52)-N(1) bond length is 1.35 Å. The C(52)-H(28,30) bond length is 1.09 Å. In the forty-first C site, C(53,54) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(29) atom. The C(53,54)-N(2) bond length is 1.35 Å. The C(53,54)-H(29) bond length is 1.09 Å. In the forty-second C site, C(55) is bonded in a distorted bent 120 degrees geometry to one C(34,36); one N(1); and one H(31,33) atom. The C(55)-N(1) bond length is 1.35 Å. The C(55)-H(31,33) bond length is 1.09 Å. In the forty-third C site, C(56,57) is bonded in a distorted bent 120 degrees geometry to one C(35), one N(2), and one H(32) atom. The C(56,57)-N(2) bond length is 1.35 Å. The C(56,57)-H(32) bond length is 1.09 Å. In the forty-fourth C site, C(58,60) is bonded in a trigonal planar geometry to one N(13), one N(7), and one H(34) atom. The C(58,60)-N(13) bond length is 1.36 Å. The C(58,60)-N(7) bond length is 1.33 Å. The C(58,60)-H(34) bond length is 1.08 Å. In the forty-fifth C site, C(59) is bonded in a trigonal planar geometry to one N(14,15); one N(8); and one H(35,36) atom. The C(59)-N(14,15) bond length is 1.36 Å. The C(59)-N(8) bond length is 1.33 Å. The C(59)-H(35,36) bond length is 1.08 Å. In the forty-sixth C site, C(61) is bonded in a distorted bent 120 degrees geometry to one C(64), one N(13), and one H(37) atom. The C(61)-C(64) bond length is 1.37 Å. The C(61)-N(13) bond length is 1.39 Å. The C(61)-H(37) bond length is 1.08 Å. In the forty-seventh C site, C(62) is bonded in a distorted bent 120 degrees geometry to one C(65,66); one N(14,15); and one H(38,39) atom. The C(62)-C(65,66) bond length is 1.37 Å. The C(62)-N(14,15) bond length is 1.39 Å. The C(62)-H(38,39) bond length is 1.08 Å. In the forty-eighth C site, C(63) is bonded in a distorted bent 120 degrees geometry to one C(65,66); one N(14,15); and one H(38,39) atom. The C(63)-C(65,66) bond length is 1.37 Å. The C(63)-N(14,15) bond length is 1.39 Å. The C(63)-H(38,39) bond length is 1.08 Å. In the forty-ninth C site, C(64) is bonded in a distorted bent 120 degrees geometry to one C(61), one N(7), and one H(40) atom. The C(64)-N(7) bond length is 1.39 Å. The C(64)-H(40) bond length is 1.08 Å. In the fiftieth C site, C(65,66) is bonded in a distorted bent 120 degrees geometry to one C(62); one N(8); and one H(41,42) atom. The C(65,66)-N(8) bond length is 1.39 Å. The C(65,66)-H(41,42) bond length is 1.08 Å. In the fifty-first C site, C(67) is bonded in a distorted single-bond geometry to one C(70,72) and one H(43,45) atom. The C(67)-C(70,72) bond length is 1.40 Å. The C(67)-H(43,45) bond length is 1.09 Å. In the fifty-second C site, C(68,69) is bonded in a distorted single-bond geometry to one C(71) and one H(44) atom. The C(68,69)-C(71) bond length is 1.40 Å. The C(68,69)-H(44) bond length is 1.09 Å. In the fifty-third C site, C(70,72) is bonded in a distorted trigonal planar geometry to one C(67), one C(73), and one N(13) atom. The C(70,72)-C(73) bond length is 1.40 Å. The C(70,72)-N(13) bond length is 1.42 Å. In the fifty-fourth C site, C(71) is bonded in a distorted trigonal planar geometry to one C(68,69); one C(74,75); and one N(14,15) atom. The C(71)-C(74,75) bond length is 1.40 Å. The C(71)-N(14,15) bond length is 1.42 Å. In the fifty-fifth C site, C(73) is bonded in a distorted single-bond geometry to one C(70,72) and one H(46,48) atom. The C(73)-H(46,48) bond length is 1.09 Å. In the fifty-sixth C site, C(74,75) is bonded in a distorted single-bond geometry to one C(71) and one H(47) atom. The C(74,75)-H(47) bond length is 1.09 Å. In the fifty-seventh C site, C(76,78) is bonded in a distorted single-bond geometry to one C(79,80,81) and one H(49,50,51) atom. The C(76,78)-C(79,80,81) bond length is 1.40 Å. The C(76,78)-H(49,50,51) bond length is 1.09 Å. In the fifty-eighth C site, C(77) is bonded in a distorted single-bond geometry to one C(79,80,81) and one H(49,50,51) atom. The C(77)-C(79,80,81) bond length is 1.40 Å. The C(77)-H(49,50,51) bond length is 1.09 Å. In the fifty-ninth C site, C(79,80,81) is bonded in a distorted trigonal planar geometry to one C(76,78); one C(82,84); and one N(10) atom. The C(79,80,81)-C(82,84) bond length is 1.40 Å. The C(79,80,81)-N(10) bond length is 1.42 Å. In the sixtieth C site, C(82,84) is bonded in a distorted single-bond geometry to one C(79,80,81) and one H(52,53,54) atom. The C(82,84)-H(52,53,54) bond length is 1.09 Å. In the sixty-first C site, C(83) is bonded in a distorted single-bond geometry to one C(79,80,81) and one H(52,53,54) atom. The C(83)-C(79,80,81) bond length is 1.40 Å. The C(83)-H(52,53,54) bond length is 1.09 Å. In the sixty-second C site, C(85,86,87) is bonded in a trigonal planar geometry to one C(100), one C(37), and one C(88) atom. The C(85,86,87)-C(100) bond length is 1.41 Å. The C(85,86,87)-C(88) bond length is 1.41 Å. In the sixty-third C site, C(88) is bonded in a distorted single-bond geometry to one C(85,86,87) and one H(55,56,57) atom. The C(88)-H(55,56,57) bond length is 1.09 Å. In the sixty-fourth C site, C(89,90) is bonded in a distorted single-bond geometry to one C(85,86,87) and one H(55,56,57) atom. The C(89,90)-C(85,86,87) bond length is 1.41 Å. The C(89,90)-H(55,56,57) bond length is 1.09 Å. In the sixty-fifth C site, C(91) is bonded in a distorted single-bond geometry to one C(94,95,96) and one H(58,59,60,61,62,63) atom. The C(91)-C(94,95,96) bond length is 1.41 Å. The C(91)-H(58,59,60,61,62,63) bond length is 1.09 Å. In the sixty-sixth C site, C(92) is bonded in a distorted single-bond geometry to one C(94,95,96) and one H(58,59,60,61,62,63) atom. The C(92)-C(94,95,96) bond length is 1.41 Å. The C(92)-H(58,59,60,61,62,63) bond length is 1.09 Å. In the sixty-seventh C site, C(93) is bonded in a distorted single-bond geometry to one C(94,95,96) and one H(58,59,60,61,62,63) atom. The C(93)-C(94,95,96) bond length is 1.41 Å. The C(93)-H(58,59,60,61,62,63) bond length is 1.09 Å. In the sixty-eighth C site, C(94,95,96) is bonded in a distorted trigonal planar geometry to one C(91), one C(97), and one N(10) atom. The C(94,95,96)-C(97) bond length is 1.40 Å. The C(94,95,96)-N(10) bond length is 1.41 Å. In the sixty-ninth C site, C(97) is bonded in a distorted single-bond geometry to one C(94,95,96) and one H(58,59,60,61,62,63) atom. The C(97)-H(58,59,60,61,62,63) bond length is 1.09 Å. In the seventieth C site, C(98) is bonded in a distorted single-bond geometry to one C(94,95,96) and one H(58,59,60,61,62,63) atom. The C(98)-C(94,95,96) bond length is 1.40 Å. The C(98)-H(58,59,60,61,62,63) bond length is 1.09 Å. In the seventy-first C site, C(99) is bonded in a distorted single-bond geometry to one C(94,95,96) and one H(58,59,60,61,62,63) atom. The C(99)-C(94,95,96) bond length is 1.40 Å. The C(99)-H(58,59,60,61,62,63) bond length is 1.09 Å. In the seventy-second C site, C(100) is bonded in a distorted single-bond geometry to one C(85,86,87) and one H(64,65,66) atom. The C(100)-H(64,65,66) bond length is 1.09 Å. In the seventy-third C site, C(101,102) is bonded in a distorted single-bond geometry to one C(85,86,87) and one H(64,65,66) atom. The C(101,102)-C(85,86,87) bond length is 1.41 Å. The C(101,102)-H(64,65,66) bond length is 1.09 Å. In the seventy-fourth C site, C(103) is bonded in a distorted trigonal planar geometry to one C(106,107); one C(118,119); and one H(67,68) atom. The C(103)-C(106,107) bond length is 1.41 Å. The C(103)-C(118,119) bond length is 1.39 Å. The C(103)-H(67,68) bond length is 1.09 Å. In the seventy-fifth C site, C(104) is bonded in a distorted trigonal planar geometry to one C(106,107); one C(118,119); and one H(67,68) atom. The C(104)-C(106,107) bond length is 1.41 Å. The C(104)-C(118,119) bond length is 1.39 Å. The C(104)-H(67,68) bond length is 1.09 Å. In the seventy-sixth C site, C(105) is bonded in a distorted trigonal planar geometry to one C(108), one C(120), and one H(69) atom. The C(105)-C(108) bond length is 1.41 Å. The C(105)-C(120) bond length is 1.39 Å. The C(105)-H(69) bond length is 1.09 Å. In the seventy-seventh C site, C(106,107) is bonded in a distorted trigonal planar geometry to one C(103), one C(109), and one N(10) atom. The C(106,107)-C(109) bond length is 1.41 Å. The C(106,107)-N(10) bond length is 1.41 Å. In the seventy-eighth C site, C(108) is bonded in a distorted trigonal planar geometry to one C(105), one C(111), and one N(12) atom. The C(108)-C(111) bond length is 1.41 Å. The C(108)-N(12) bond length is 1.41 Å. In the seventy-ninth C site, C(109) is bonded in a distorted trigonal planar geometry to one C(106,107); one C(112,113); and one H(70,71,72) atom. The C(109)-C(112,113) bond length is 1.39 Å. The C(109)-H(70,71,72) bond length is 1.09 Å. In the eightieth C site, C(110) is bonded in a distorted trigonal planar geometry to one C(106,107); one C(112,113); and one H(70,71,72) atom. The C(110)-C(106,107) bond length is 1.41 Å. The C(110)-C(112,113) bond length is 1.39 Å. The C(110)-H(70,71,72) bond length is 1.09 Å. In the eighty-first C site, C(111) is bonded in a distorted trigonal planar geometry to one C(108); one C(114); and one H(70,71,72) atom. The C(111)-C(114) bond length is 1.39 Å. The C(111)-H(70,71,72) bond length is 1.09 Å. In the eighty-second C site, C(112,113) is bonded in a distorted trigonal planar geometry to one C(109); one C(115); and one H(73,74,75) atom. The C(112,113)-C(115) bond length is 1.41 Å. The C(112,113)-H(73,74,75) bond length is 1.09 Å. In the eighty-third C site, C(114) is bonded in a distorted trigonal planar geometry to one C(111); one C(117); and one H(73,74,75) atom. The C(114)-C(117) bond length is 1.41 Å. The C(114)-H(73,74,75) bond length is 1.09 Å. In the eighty-fourth C site, C(115) is bonded in a trigonal planar geometry to one C(112,113); one C(118,119); and one C(46) atom. The C(115)-C(118,119) bond length is 1.41 Å. In the eighty-fifth C site, C(116) is bonded in a trigonal planar geometry to one C(112,113); one C(118,119); and one C(47) atom. The C(116)-C(112,113) bond length is 1.41 Å. The C(116)-C(118,119) bond length is 1.41 Å. In the eighty-sixth C site, C(117) is bonded in a trigonal planar geometry to one C(114), one C(120), and one C(48) atom. The C(117)-C(120) bond length is 1.41 Å. In the eighty-seventh C site, C(118,119) is bonded in a distorted trigonal planar geometry to one C(103); one C(115); and one H(76,77) atom. The C(118,119)-H(76,77) bond length is 1.09 Å. In the eighty-eighth C site, C(120) is bonded in a distorted trigonal planar geometry to one C(105), one C(117), and one H(78) atom. The C(120)-H(78) bond length is 1.09 Å. There are seventeen inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(4), one C(52), and one C(55) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(5); one C(53,54); and one C(56,57) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(6); one C(53,54); and one C(56,57) atom. The N(3)-C(53,54) bond length is 1.35 Å. The N(3)-C(56,57) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(2); one C(28,30); and one C(31,33) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(3), one C(29), and one C(32) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(1); one C(28,30); and one C(31,33) atom. The N(6)-C(28,30) bond length is 1.35 Å. The N(6)-C(31,33) bond length is 1.35 Å. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Zn(1); one C(58,60); and one C(64) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Zn(2); one C(59); and one C(65,66) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Zn(3); one C(58,60); and one C(65,66) atom. The N(9)-C(58,60) bond length is 1.33 Å. The N(9)-C(65,66) bond length is 1.39 Å. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one C(106,107); one C(79,80,81); and one C(94,95,96) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one C(106,107); one C(79,80,81); and one C(94,95,96) atom. The N(11)-C(106,107) bond length is 1.41 Å. The N(11)-C(79,80,81) bond length is 1.42 Å. The N(11)-C(94,95,96) bond length is 1.41 Å. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one C(108); one C(79,80,81); and one C(94,95,96) atom. The N(12)-C(79,80,81) bond length is 1.42 Å. The N(12)-C(94,95,96) bond length is 1.41 Å. In the thirteenth N site, N(13) is bonded in a trigonal planar geometry to one C(58,60); one C(61); and one C(70,72) atom. In the fourteenth N site, N(14,15) is bonded in a trigonal planar geometry to one C(59), one C(62), and one C(71) atom. In the fifteenth N site, N(16) is bonded in a bent 120 degrees geometry to one O(19) and one O(22) atom. The N(16)-O(19) bond length is 1.29 Å. The N(16)-O(22) bond length is 1.25 Å. In the sixteenth N site, N(17) is bonded in a bent 120 degrees geometry to one O(20) and one O(23) atom. The N(17)-O(20) bond length is 1.29 Å. The N(17)-O(23) bond length is 1.25 Å. In the seventeenth N site, N(18) is bonded in a bent 120 degrees geometry to one O(21) and one O(24) atom. The N(18)-O(21) bond length is 1.29 Å. The N(18)-O(24) bond length is 1.25 Å. There are forty-four inequivalent H sites. In the first H site, H(1,2,3) is bonded in a single-bond geometry to one C(13,15) atom. In the second H site, H(4,5,6) is bonded in a single-bond geometry to one C(16,18) atom. In the third H site, H(7,8,9) is bonded in a single-bond geometry to one C(25,26,27) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(28,30) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(29) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(28,30) atom. The H(12)-C(28,30) bond length is 1.09 Å. In the seventh H site, H(13,14) is bonded in a single-bond geometry to one C(31,33) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(31,33) atom. The H(15)-C(31,33) bond length is 1.09 Å. In the ninth H site, H(16,17,18) is bonded in a single-bond geometry to one C(34,36) atom. In the tenth H site, H(19,20,21) is bonded in a single-bond geometry to one C(40,41,42) atom. In the eleventh H site, H(22,23,24) is bonded in a single-bond geometry to one C(43) atom. In the twelfth H site, H(25,27) is bonded in a single-bond geometry to one C(49) atom. In the thirteenth H site, H(26) is bonded in a single-bond geometry to one C(50) atom. In the fourteenth H site, H(28,30) is bonded in a single-bond geometry to one C(52) atom. In the fifteenth H site, H(29) is bonded in a single-bond geometry to one C(53,54) atom. In the sixteenth H site, H(31,33) is bonded in a single-bond geometry to one C(55) atom. In the seventeenth H site, H(32) is bonded in a single-bond geometry to one C(56,57) atom. In the eighteenth H site, H(34) is bonded in a single-bond geometry to one C(58,60) atom. In the nineteenth H site, H(35,36) is bonded in a single-bond geometry to one C(59) atom. In the twentieth H site, H(37) is bonded in a single-bond geometry to one C(61) atom. In the twenty-first H site, H(38,39) is bonded in a single-bond geometry to one C(62) atom. In the twenty-second H site, H(40) is bonded in a single-bond geometry to one C(64) atom. In the twenty-third H site, H(41,42) is bonded in a single-bond geometry to one C(65,66) atom. In the twenty-fourth H site, H(43,45) is bonded in a single-bond geometry to one C(67) atom. In the twenty-fifth H site, H(44) is bonded in a single-bond geometry to one C(68,69) atom. In the twenty-sixth H site, H(46,48) is bonded in a single-bond geometry to one C(73) atom. In the twenty-seventh H site, H(47) is bonded in a single-bond geometry to one C(74,75) atom. In the twenty-eighth H site, H(49,50,51) is bonded in a single-bond geometry to one C(76,78) atom. In the twenty-ninth H site, H(52,53,54) is bonded in a single-bond geometry to one C(82,84) atom. In the thirtieth H site, H(55,56,57) is bonded in a single-bond geometry to one C(88) atom. In the thirty-first H site, H(58,59,60,61,62,63) is bonded in a single-bond geometry to one C(91) atom. In the thirty-second H site, H(64,65,66) is bonded in a single-bond geometry to one C(100) atom. In the thirty-third H site, H(67,68) is bonded in a single-bond geometry to one C(103) atom. In the thirty-fourth H site, H(69) is bonded in a single-bond geometry to one C(105) atom. In the thirty-fifth H site, H(70,71,72) is bonded in a single-bond geometry to one C(109) atom. In the thirty-sixth H site, H(73,74,75) is bonded in a single-bond geometry to one C(112,113) atom. In the thirty-seventh H site, H(76,77) is bonded in a single-bond geometry to one C(118,119) atom. In the thirty-eighth H site, H(78) is bonded in a single-bond geometry to one C(120) atom. In the thirty-ninth H site, H(79) is bonded in a single-bond geometry to one O(23) and one O(25) atom. The H(79)-O(23) bond length is 1.73 Å. The H(79)-O(25) bond length is 1.00 Å. In the fortieth H site, H(80) is bonded in a single-bond geometry to one O(24) and one O(26) atom. The H(80)-O(24) bond length is 1.73 Å. The H(80)-O(26) bond length is 1.00 Å. In the forty-first H site, H(81) is bonded in a single-bond geometry to one O(22) and one O(27) atom. The H(81)-O(22) bond length is 1.73 Å. The H(81)-O(27) bond length is 1.00 Å. In the forty-second H site, H(82) is bonded in a single-bond geometry to one O(25) atom. The H(82)-O(25) bond length is 0.99 Å. In the forty-third H site, H(83) is bonded in a single-bond geometry to one O(26) atom. The H(83)-O(26) bond length is 0.99 Å. In the forty-fourth H site, H(84) is bonded in a single-bond geometry to one O(27) atom. The H(84)-O(27) bond length is 0.99 Å. There are twenty-seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(4) and one C(4) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(5) and one C(5) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(6) and one C(6) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(5) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Zn(4) and one C(1) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Zn(5) and one C(2) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Zn(6) and one C(3) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one Zn(4) and one C(1) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Zn(5) and one C(2) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Zn(6) and one C(3) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7,9) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(8) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(7,9) atom. The O(15)-C(7,9) bond length is 1.30 Å. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one C(7,9) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one C(8) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one C(7,9) atom. The O(18)-C(7,9) bond length is 1.25 Å. In the nineteenth O site, O(19) is bonded in a water-like geometry to one Zn(4) and one N(16) atom. In the twentieth O site, O(20) is bonded in a water-like geometry to one Zn(5) and one N(17) atom. In the twenty-first O site, O(21) is bonded in a water-like geometry to one Zn(6) and one N(18) atom. In the twenty-second O site, O(22) is bonded in a distorted water-like geometry to one N(16) and one H(81) atom. In the twenty-third O site, O(23) is bonded in a distorted water-like geometry to one N(17) and one H(79) atom. In the twenty-fourth O site, O(24) is bonded in a distorted water-like geometry to one N(18) and one H(80) atom. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal non-coplanar geometry to one Zn(4), one H(79), and one H(82) atom. In the twenty-sixth O site, O(26) is bonded in a distorted trigonal non-coplanar geometry to one Zn(5), one H(80), and one H(83) atom. In the twenty-seventh O site, O(27) is bonded in a distorted trigonal non-coplanar geometry to one Zn(6), one H(81), and one H(84) atom. Linkers: 3 c1cc(-c2ccc(N(c3ccc(-c4ccncc4)cc3)c3ccc(-n4ccnc4)cc3)cc2)ccn1 ,2 [O]C(=O)c1ccc(C([O])=O)c(C([O])=O)c1 ,1 [O][C]c1cc(C([O])=O)ccc1C([O])=O. Metal clusters: 3 O.[O][N]O[Zn](O[C]O[Zn]O[C]=O)O[C]=O. The MOF has largest included sphere 6.67 A, density 1.41 g/cm3, surface area 4467.64 m2/g, accessible volume 0.23 cm3/g