CoC42H29(N3O2)2(CH)3C2O is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, four dimethyl ether molecules, and four CoC42H29(N3O2)2 clusters. In each CoC42H29(N3O2)2 cluster, Co(1) is bonded in a distorted octahedral geometry to one N(1), one N(3), one N(5), one O(1), one O(2), and one O(5) atom. The Co(1)-N(1) bond length is 2.07 Å. The Co(1)-N(3) bond length is 2.08 Å. The Co(1)-N(5) bond length is 2.16 Å. The Co(1)-O(1) bond length is 2.20 Å. The Co(1)-O(2) bond length is 2.25 Å. The Co(1)-O(5) bond length is 2.00 Å. There are forty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.37 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(1) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one N(2) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(9) bond length is 1.40 Å. The C(4)-N(2) bond length is 1.42 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4,7) atom. The C(5)-H(4,7) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(10), one C(6), and one C(8) atom. The C(7)-C(10) bond length is 1.48 Å. The C(7)-C(8) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(4) and one H(4,7) atom. The C(9)-H(4,7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(7) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.40 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(8) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(8) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(25) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(25) bond length is 1.48 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(9) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-H(9) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(16) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-C(16) bond length is 1.48 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(10), one C(14), and one H(10) atom. The C(15)-H(10) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(14), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(21) bond length is 1.41 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(17)-H(11) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(12) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-H(12) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one N(4) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-N(4) bond length is 1.42 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(13) atom. The C(20)-H(13) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(14) atom. The C(21)-H(14) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(15) atom. The C(22)-N(3) bond length is 1.33 Å. The C(22)-N(4) bond length is 1.37 Å. The C(22)-H(15) bond length is 1.08 Å. In the twenty-third C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(24), one N(3), and one H(16) atom. The C(23)-C(24) bond length is 1.37 Å. The C(23)-N(3) bond length is 1.39 Å. The C(23)-H(16) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(23), one N(4), and one H(17) atom. The C(24)-N(4) bond length is 1.39 Å. The C(24)-H(17) bond length is 1.08 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(12), one C(26), and one C(30) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(30) bond length is 1.41 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(18) atom. The C(26)-H(18) bond length is 1.09 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(28) and one H(19) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-H(19) bond length is 1.09 Å. In the twenty-eighth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one C(29), and one N(6) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-N(6) bond length is 1.42 Å. In the twenty-ninth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one C(30), and one H(20) atom. The C(29)-C(30) bond length is 1.39 Å. The C(29)-H(20) bond length is 1.09 Å. In the thirtieth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(25), one C(29), and one H(21) atom. The C(30)-H(21) bond length is 1.09 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(22) atom. The C(31)-N(5) bond length is 1.32 Å. The C(31)-N(6) bond length is 1.37 Å. The C(31)-H(22) bond length is 1.08 Å. In the thirty-second C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(33), one N(5), and one H(23) atom. The C(32)-C(33) bond length is 1.37 Å. The C(32)-N(5) bond length is 1.38 Å. The C(32)-H(23) bond length is 1.08 Å. In the thirty-third C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(32), one N(6), and one H(24) atom. The C(33)-N(6) bond length is 1.39 Å. The C(33)-H(24) bond length is 1.08 Å. In the thirty-fourth C site, C(34) is bonded in a bent 120 degrees geometry to one C(35), one O(1), and one O(2) atom. The C(34)-C(35) bond length is 1.49 Å. The C(34)-O(1) bond length is 1.28 Å. The C(34)-O(2) bond length is 1.27 Å. In the thirty-fifth C site, C(35) is bonded in a trigonal planar geometry to one C(34), one C(36), and one C(40) atom. The C(35)-C(36) bond length is 1.40 Å. The C(35)-C(40) bond length is 1.40 Å. In the thirty-sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(35) and one H(25) atom. The C(36)-H(25) bond length is 1.09 Å. In the thirty-seventh C site, C(40) is bonded in a distorted single-bond geometry to one C(35) and one H(28) atom. The C(40)-H(28) bond length is 1.09 Å. In the thirty-eighth C site, C(43) is bonded in a distorted single-bond geometry to one C(44) and one H(30) atom. The C(43)-C(44) bond length is 1.40 Å. The C(43)-H(30) bond length is 1.09 Å. In the thirty-ninth C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(47) atom. The C(44)-C(45) bond length is 1.40 Å. The C(44)-C(47) bond length is 1.50 Å. In the fortieth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(44), one C(46), and one H(31) atom. The C(45)-C(46) bond length is 1.39 Å. The C(45)-H(31) bond length is 1.09 Å. In the forty-first C site, C(46) is bonded in a distorted single-bond geometry to one C(45) and one H(32) atom. The C(46)-H(32) bond length is 1.09 Å. In the forty-second C site, C(47) is bonded in a distorted bent 120 degrees geometry to one C(44), one O(4), and one O(5) atom. The C(47)-O(4) bond length is 1.26 Å. The C(47)-O(5) bond length is 1.29 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Co(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(22), and one C(23) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(19), one C(22), and one C(24) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(1), one C(31), and one C(32) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(28), one C(31), and one C(33) atom. There are twenty-eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4,7) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(24) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(29) atom. In the twentieth H site, H(21) is bonded in a single-bond geometry to one C(30) atom. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one C(31) atom. In the twenty-second H site, H(23) is bonded in a single-bond geometry to one C(32) atom. In the twenty-third H site, H(24) is bonded in a single-bond geometry to one C(33) atom. In the twenty-fourth H site, H(25) is bonded in a single-bond geometry to one C(36) atom. In the twenty-fifth H site, H(28) is bonded in a single-bond geometry to one C(40) atom. In the twenty-sixth H site, H(30) is bonded in a single-bond geometry to one C(43) atom. In the twenty-seventh H site, H(31) is bonded in a single-bond geometry to one C(45) atom. In the twenty-eighth H site, H(32) is bonded in a single-bond geometry to one C(46) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Co(1) and one C(34) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Co(1) and one C(34) atom. In the third O site, O(4) is bonded in a single-bond geometry to one C(47) atom. In the fourth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(47) atom. Linkers: 4 c1cn(-c2ccc(-c3cc(-c4ccc(-n5ccnc5)cc4)cc(-c4ccc(-n5ccnc5)cc4)c3)cc2)cn1 ,2 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 O=[C]O[Co]1O[C]O1. The MOF has largest included sphere 4.43 A, density 1.32 g/cm3, surface area 4769.35 m2/g, accessible volume 0.23 cm3/g