CdC37N5H28O4C3NH2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 1,2-diisopropenylhydrazine molecules and two CdC37N5H28O4 clusters. In each CdC37N5H28O4 cluster, Cd(1) is bonded in a distorted octahedral geometry to one N(1), one N(6), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.34 Å. The Cd(1)-N(6) bond length is 2.36 Å. The Cd(1)-O(1) bond length is 2.38 Å. The Cd(1)-O(2) bond length is 2.40 Å. The Cd(1)-O(3) bond length is 2.40 Å. The Cd(1)-O(4) bond length is 2.33 Å. There are thirty-seven inequivalent C sites. In the first C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(1) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the second C site, C(34) is bonded in a trigonal planar geometry to one C(29), one C(35), and one C(39) atom. The C(34)-C(29) bond length is 1.48 Å. The C(34)-C(35) bond length is 1.41 Å. The C(34)-C(39) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(35) is bonded in a distorted single-bond geometry to one C(34), one C(36), and one H(27) atom. The C(35)-C(36) bond length is 1.39 Å. The C(35)-H(27) bond length is 1.09 Å. In the fifth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one N(2) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(9) bond length is 1.40 Å. The C(4)-N(2) bond length is 1.42 Å. In the sixth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(35), one C(37), and one H(28) atom. The C(36)-C(37) bond length is 1.40 Å. The C(36)-H(28) bond length is 1.09 Å. In the seventh C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(4) bond length is 1.09 Å. In the eighth C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one C(40) atom. The C(37)-C(38) bond length is 1.40 Å. The C(37)-C(40) bond length is 1.50 Å. In the ninth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(5) atom. The C(6)-C(7) bond length is 1.41 Å. The C(6)-H(5) bond length is 1.09 Å. In the tenth C site, C(38) is bonded in a distorted single-bond geometry to one C(37) and one H(29) atom. The C(38)-H(29) bond length is 1.09 Å. In the eleventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(3) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(3) bond length is 1.41 Å. In the twelfth C site, C(39) is bonded in a distorted single-bond geometry to one C(34) and one H(30) atom. The C(39)-H(30) bond length is 1.09 Å. In the thirteenth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(6) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(6) bond length is 1.09 Å. In the fourteenth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(3), and one O(4) atom. The C(40)-O(3) bond length is 1.28 Å. The C(40)-O(4) bond length is 1.28 Å. In the fifteenth C site, C(9) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the sixteenth C site, C(10) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(8) atom. The C(10)-N(5) bond length is 1.37 Å. The C(10)-N(6) bond length is 1.33 Å. The C(10)-H(8) bond length is 1.08 Å. In the seventeenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(6), and one H(9) atom. The C(11)-C(12) bond length is 1.37 Å. The C(11)-N(6) bond length is 1.39 Å. The C(11)-H(9) bond length is 1.08 Å. In the eighteenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(5), and one H(10) atom. The C(12)-N(5) bond length is 1.39 Å. The C(12)-H(10) bond length is 1.08 Å. In the nineteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one N(5) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(18) bond length is 1.41 Å. The C(13)-N(5) bond length is 1.41 Å. In the twentieth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(14)-H(11) bond length is 1.09 Å. In the twenty-first C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(14) atom. The C(18)-H(14) bond length is 1.09 Å. In the twenty-second C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(1), and one O(2) atom. The C(19)-C(20) bond length is 1.50 Å. The C(19)-O(1) bond length is 1.28 Å. The C(19)-O(2) bond length is 1.27 Å. In the twenty-third C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(25) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(25) bond length is 1.40 Å. In the twenty-fourth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(15) atom. The C(21)-H(15) bond length is 1.09 Å. In the twenty-fifth C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(16,17) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(16,17) bond length is 1.09 Å. In the twenty-sixth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(26) atom. The C(23)-C(24) bond length is 1.41 Å. The C(23)-C(26) bond length is 1.49 Å. In the twenty-seventh C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(16,17) atom. The C(24)-H(16,17) bond length is 1.09 Å. In the twenty-eighth C site, C(25) is bonded in a distorted single-bond geometry to one C(20) and one H(18) atom. The C(25)-H(18) bond length is 1.09 Å. In the twenty-ninth C site, C(26) is bonded in a trigonal planar geometry to one C(23), one C(27), and one C(31) atom. The C(26)-C(27) bond length is 1.41 Å. The C(26)-C(31) bond length is 1.40 Å. In the thirtieth C site, C(32) is bonded in a distorted trigonal non-coplanar geometry to one C(27), one H(21), one H(22), and one H(23) atom. The C(32)-C(27) bond length is 1.50 Å. The C(32)-H(21) bond length is 1.10 Å. The C(32)-H(22) bond length is 1.10 Å. The C(32)-H(23) bond length is 1.10 Å. In the thirty-first C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(32) atom. The C(27)-C(28) bond length is 1.40 Å. In the thirty-second C site, C(28) is bonded in a distorted single-bond geometry to one C(27), one C(29), and one H(19) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-H(19) bond length is 1.09 Å. In the thirty-third C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(34) atom. The C(29)-C(30) bond length is 1.41 Å. In the thirty-fourth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(33) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-C(33) bond length is 1.51 Å. In the thirty-fifth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(26), one C(30), and one H(20) atom. The C(31)-H(20) bond length is 1.09 Å. In the thirty-sixth C site, C(33) is bonded in a distorted trigonal non-coplanar geometry to one C(30), one H(24), one H(25), and one H(26) atom. The C(33)-H(24) bond length is 1.10 Å. The C(33)-H(25) bond length is 1.10 Å. The C(33)-H(26) bond length is 1.10 Å. In the thirty-seventh C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-N(2) bond length is 1.37 Å. The C(1)-H(1) bond length is 1.08 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one C(7) and one N(3) atom. The N(3)-N(3) bond length is 1.27 Å. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(13) atom. In the fifth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one C(11) atom. There are twenty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the fourteenth H site, H(16,17) is bonded in a single-bond geometry to one C(22) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(25) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(28) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(31) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(32) atom. In the nineteenth H site, H(22) is bonded in a single-bond geometry to one C(32) atom. In the twentieth H site, H(23) is bonded in a single-bond geometry to one C(32) atom. In the twenty-first H site, H(24) is bonded in a single-bond geometry to one C(33) atom. In the twenty-second H site, H(25) is bonded in a single-bond geometry to one C(33) atom. In the twenty-third H site, H(26) is bonded in a single-bond geometry to one C(33) atom. In the twenty-fourth H site, H(27) is bonded in a single-bond geometry to one C(35) atom. In the twenty-fifth H site, H(28) is bonded in a single-bond geometry to one C(36) atom. In the twenty-sixth H site, H(29) is bonded in a single-bond geometry to one C(38) atom. In the twenty-seventh H site, H(30) is bonded in a single-bond geometry to one C(39) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Cd(1) and one C(19) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Cd(1) and one C(19) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Cd(1) and one C(40) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Cd(1) and one C(40) atom. Linkers: 4 c1cn(-c2ccc([N][N]c3ccc(-n4ccnc4)cc3)cc2)cn1 ,4 Cc1cc(-c2ccc(C([O])=O)cc2)c(C)cc1-c1ccc(C([O])=O)cc1. Metal clusters: 4 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 4.27 A, density 1.33 g/cm3, surface area 4908.20 m2/g, accessible volume 0.26 cm3/g