AgC19PN2H19O3(CH)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and one AgC19PN2H19O3 cluster. In the AgC19PN2H19O3 cluster, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one P(1), one N(2), one O(1), and one O(2) atom. The Ag(1)-P(1) bond length is 2.36 Å. The Ag(1)-N(2) bond length is 2.40 Å. The Ag(1)-O(1) bond length is 2.48 Å. The Ag(1)-O(2) bond length is 2.43 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1) atom. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2) atom. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(4), one C(9), and one P(1) atom. The C(3)-C(4) bond length is 1.42 Å. The C(3)-C(9) bond length is 1.40 Å. The C(3)-P(1) bond length is 1.83 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.50 Å. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one H(3), one H(4), and one H(5) atom. The C(5)-H(3) bond length is 1.10 Å. The C(5)-H(4) bond length is 1.10 Å. The C(5)-H(5) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(6)-H(6) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(3) and one H(9) atom. The C(9)-H(9) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(16), and one P(1) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-C(16) bond length is 1.40 Å. The C(10)-P(1) bond length is 1.82 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(13) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-C(13) bond length is 1.40 Å. In the tenth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one H(10), one H(11), and one H(12) atom. The C(12)-H(10) bond length is 1.10 Å. The C(12)-H(11) bond length is 1.10 Å. The C(12)-H(12) bond length is 1.10 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(11), one C(14), and one H(13) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-H(13) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(14) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(15) atom. The C(15)-H(15) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(10) and one H(16) atom. The C(16)-H(16) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(18), one C(23), and one P(1) atom. The C(17)-C(18) bond length is 1.42 Å. The C(17)-C(23) bond length is 1.40 Å. The C(17)-P(1) bond length is 1.83 Å. In the sixteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(20) atom. The C(18)-C(19) bond length is 1.50 Å. The C(18)-C(20) bond length is 1.40 Å. In the seventeenth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one C(18), one H(17), one H(18), and one H(19) atom. The C(19)-H(17) bond length is 1.10 Å. The C(19)-H(18) bond length is 1.10 Å. The C(19)-H(19) bond length is 1.10 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(18) and one H(20) atom. The C(20)-H(20) bond length is 1.09 Å. In the nineteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(17) and one H(23) atom. The C(23)-H(23) bond length is 1.09 Å. P(1) is bonded in a distorted tetrahedral geometry to one Ag(1), one C(10), one C(17), and one C(3) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(1)-O(1) bond length is 1.29 Å. The N(1)-O(2) bond length is 1.28 Å. The N(1)-O(3) bond length is 1.24 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(2) atom. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the nineteenth H site, H(23) is bonded in a single-bond geometry to one C(23) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Ag(1) and one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. Linkers: 1 c1cnccn1. Metal clusters: 2 [Ag]. The MOF has largest included sphere 1.90 A, density 1.64 g/cm3, surface area 4711.20 m2/g, accessible volume 0.11 cm3/g