UC6H6(N2O5)2(CH2)8 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and one UC6H6(N2O5)2 cluster. In the UC6H6(N2O5)2 cluster, U(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. Both U(1)-O(1) bond lengths are 1.81 Å. Both U(1)-O(2) bond lengths are 2.55 Å. Both U(1)-O(3) bond lengths are 2.57 Å. Both U(1)-O(5) bond lengths are 2.34 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(5) atom. The C(1)-N(2) bond length is 1.33 Å. The C(1)-O(5) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(1), and one H(2) atom. The C(2)-N(2) bond length is 1.47 Å. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. In the third C site, C(5) is bonded in a distorted water-like geometry to one N(2) and one H(7) atom. The C(5)-N(2) bond length is 1.46 Å. The C(5)-H(7) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(4) atom. The N(1)-O(2) bond length is 1.29 Å. The N(1)-O(3) bond length is 1.28 Å. The N(1)-O(4) bond length is 1.23 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(5) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one U(1) and one N(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one U(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one U(1) and one C(1) atom. Linkers: 1 O=C1CCCN1[C@H]1CC[C@H](N2CCCC2=O)CC1. Metal clusters: 1 [O][U]([O])([O])([O])(O[N+](=O)[O-])O[N+](=O)[O-]. The MOF has largest included sphere 1.90 A, density 2.30 g/cm3, surface area 3316.72 m2/g, accessible volume 0.11 cm3/g