Co2C75H51(N3O4)2(CH)7 crystallizes in the triclinic P1 space group. The structure consists of fourteen 02329_fluka molecules inside a Co2C75H51(N3O4)2 framework. In the Co2C75H51(N3O4)2 framework, there are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted octahedral geometry to one N(1), one N(8), one N(9), one O(1), one O(14), and one O(5) atom. The Co(1)-N(1) bond length is 2.07 Å. The Co(1)-N(8) bond length is 2.11 Å. The Co(1)-N(9) bond length is 2.07 Å. The Co(1)-O(1) bond length is 2.34 Å. The Co(1)-O(14) bond length is 2.05 Å. The Co(1)-O(5) bond length is 2.16 Å. In the second Co site, Co(2) is bonded in a distorted octahedral geometry to one N(10), one N(2), one N(7), one O(13), one O(2), and one O(6) atom. The Co(2)-N(10) bond length is 2.08 Å. The Co(2)-N(2) bond length is 2.09 Å. The Co(2)-N(7) bond length is 2.13 Å. The Co(2)-O(13) bond length is 2.04 Å. The Co(2)-O(2) bond length is 2.34 Å. The Co(2)-O(6) bond length is 2.16 Å. In the third Co site, Co(3) is bonded in a distorted square pyramidal geometry to one N(11), one N(3), one N(6), one O(16), and one O(3) atom. The Co(3)-N(11) bond length is 2.08 Å. The Co(3)-N(3) bond length is 1.92 Å. The Co(3)-N(6) bond length is 1.96 Å. The Co(3)-O(16) bond length is 1.95 Å. The Co(3)-O(3) bond length is 1.96 Å. In the fourth Co site, Co(4) is bonded in a distorted octahedral geometry to one N(12), one N(4), one N(5), one O(15), one O(4), and one O(8) atom. The Co(4)-N(12) bond length is 2.07 Å. The Co(4)-N(4) bond length is 2.08 Å. The Co(4)-N(5) bond length is 2.12 Å. The Co(4)-O(15) bond length is 2.03 Å. The Co(4)-O(4) bond length is 2.34 Å. The Co(4)-O(8) bond length is 2.16 Å. There are one hundred and fifty inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(5), one N(5), and one H(1) atom. The C(1)-C(5) bond length is 1.39 Å. The C(1)-N(5) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(6), one N(6), and one H(2) atom. The C(2)-C(6) bond length is 1.38 Å. The C(2)-N(6) bond length is 1.36 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(7), one N(7), and one H(3) atom. The C(3)-C(7) bond length is 1.39 Å. The C(3)-N(7) bond length is 1.35 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(8), one N(8), and one H(4) atom. The C(4)-C(8) bond length is 1.38 Å. The C(4)-N(8) bond length is 1.35 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(1), one C(9), and one H(5) atom. The C(5)-C(9) bond length is 1.41 Å. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(10), one C(2), and one H(6) atom. The C(6)-C(10) bond length is 1.41 Å. The C(6)-H(6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(11), one C(3), and one H(7) atom. The C(7)-C(11) bond length is 1.41 Å. The C(7)-H(7) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(12), one C(4), and one H(8) atom. The C(8)-C(12) bond length is 1.41 Å. The C(8)-H(8) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(13), one C(21), and one C(5) atom. The C(9)-C(13) bond length is 1.41 Å. The C(9)-C(21) bond length is 1.45 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(14), one C(22), and one C(6) atom. The C(10)-C(14) bond length is 1.41 Å. The C(10)-C(22) bond length is 1.45 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(15), one C(23), and one C(7) atom. The C(11)-C(15) bond length is 1.41 Å. The C(11)-C(23) bond length is 1.46 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(16), one C(24), and one C(8) atom. The C(12)-C(16) bond length is 1.41 Å. The C(12)-C(24) bond length is 1.45 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(9) and one H(9) atom. The C(13)-H(9) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(10) and one H(10) atom. The C(14)-H(10) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(11) and one H(11,12) atom. The C(15)-H(11,12) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(12) and one H(11,12) atom. The C(16)-H(11,12) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(13) atom. The C(17)-N(5) bond length is 1.35 Å. The C(17)-H(13) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(14) atom. The C(18)-N(6) bond length is 1.35 Å. The C(18)-H(14) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(15) atom. The C(19)-N(7) bond length is 1.35 Å. The C(19)-H(15) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(16) atom. The C(20)-N(8) bond length is 1.35 Å. The C(20)-H(16) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(25), one C(9), and one H(17) atom. The C(21)-C(25) bond length is 1.35 Å. The C(21)-H(17) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(10), one C(26), and one H(18) atom. The C(22)-C(26) bond length is 1.36 Å. The C(22)-H(18) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted trigonal planar geometry to one C(11), one C(27), and one H(19) atom. The C(23)-C(27) bond length is 1.35 Å. The C(23)-H(19) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(12), one C(28), and one H(20) atom. The C(24)-C(28) bond length is 1.35 Å. The C(24)-H(20) bond length is 1.09 Å. In the twenty-fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(21), one C(29), and one H(21) atom. The C(25)-C(29) bond length is 1.45 Å. The C(25)-H(21) bond length is 1.09 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(22); one C(30); and one H(22,23) atom. The C(26)-C(30) bond length is 1.46 Å. The C(26)-H(22,23) bond length is 1.09 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(23); one C(31); and one H(22,23) atom. The C(27)-C(31) bond length is 1.46 Å. The C(27)-H(22,23) bond length is 1.09 Å. In the twenty-eighth C site, C(28) is bonded in a distorted single-bond geometry to one C(24), one C(32), and one H(24) atom. The C(28)-C(32) bond length is 1.45 Å. The C(28)-H(24) bond length is 1.09 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(25), one C(33), and one C(49) atom. The C(29)-C(33) bond length is 1.41 Å. The C(29)-C(49) bond length is 1.40 Å. In the thirtieth C site, C(30) is bonded in a trigonal planar geometry to one C(26), one C(34), and one C(50) atom. The C(30)-C(34) bond length is 1.41 Å. The C(30)-C(50) bond length is 1.40 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one C(27), one C(35), and one C(51) atom. The C(31)-C(35) bond length is 1.41 Å. The C(31)-C(51) bond length is 1.40 Å. In the thirty-second C site, C(32) is bonded in a trigonal planar geometry to one C(28), one C(36), and one C(52) atom. The C(32)-C(36) bond length is 1.41 Å. The C(32)-C(52) bond length is 1.40 Å. In the thirty-third C site, C(33) is bonded in a distorted single-bond geometry to one C(29), one C(37), and one H(25) atom. The C(33)-C(37) bond length is 1.40 Å. The C(33)-H(25) bond length is 1.09 Å. In the thirty-fourth C site, C(34) is bonded in a distorted single-bond geometry to one C(30); one C(38); and one H(26,27) atom. The C(34)-C(38) bond length is 1.40 Å. The C(34)-H(26,27) bond length is 1.09 Å. In the thirty-fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(31); one C(39); and one H(26,27) atom. The C(35)-C(39) bond length is 1.40 Å. The C(35)-H(26,27) bond length is 1.09 Å. In the thirty-sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(32), one C(40), and one H(28) atom. The C(36)-C(40) bond length is 1.40 Å. The C(36)-H(28) bond length is 1.09 Å. In the thirty-seventh C site, C(37) is bonded in a trigonal planar geometry to one C(33), one C(41), and one C(53) atom. The C(37)-C(41) bond length is 1.40 Å. The C(37)-C(53) bond length is 1.45 Å. In the thirty-eighth C site, C(38) is bonded in a trigonal planar geometry to one C(34), one C(42), and one C(54) atom. The C(38)-C(42) bond length is 1.40 Å. The C(38)-C(54) bond length is 1.45 Å. In the thirty-ninth C site, C(39) is bonded in a trigonal planar geometry to one C(35), one C(43), and one C(55) atom. The C(39)-C(43) bond length is 1.40 Å. The C(39)-C(55) bond length is 1.45 Å. In the fortieth C site, C(40) is bonded in a trigonal planar geometry to one C(36), one C(44), and one C(56) atom. The C(40)-C(44) bond length is 1.40 Å. The C(40)-C(56) bond length is 1.45 Å. In the forty-first C site, C(41) is bonded in a distorted trigonal planar geometry to one C(37); one C(45); and one H(29,30) atom. The C(41)-C(45) bond length is 1.40 Å. The C(41)-H(29,30) bond length is 1.09 Å. In the forty-second C site, C(42) is bonded in a distorted trigonal planar geometry to one C(38); one C(46); and one H(29,30) atom. The C(42)-C(46) bond length is 1.40 Å. The C(42)-H(29,30) bond length is 1.09 Å. In the forty-third C site, C(43) is bonded in a distorted trigonal planar geometry to one C(39), one C(47), and one H(31) atom. The C(43)-C(47) bond length is 1.40 Å. The C(43)-H(31) bond length is 1.09 Å. In the forty-fourth C site, C(44) is bonded in a distorted trigonal planar geometry to one C(40), one C(48), and one H(32) atom. The C(44)-C(48) bond length is 1.40 Å. The C(44)-H(32) bond length is 1.09 Å. In the forty-fifth C site, C(45) is bonded in a trigonal planar geometry to one C(41), one C(49), and one C(81) atom. The C(45)-C(49) bond length is 1.41 Å. The C(45)-C(81) bond length is 1.45 Å. In the forty-sixth C site, C(46) is bonded in a trigonal planar geometry to one C(42), one C(50), and one C(82) atom. The C(46)-C(50) bond length is 1.41 Å. The C(46)-C(82) bond length is 1.45 Å. In the forty-seventh C site, C(47) is bonded in a trigonal planar geometry to one C(43), one C(51), and one C(83) atom. The C(47)-C(51) bond length is 1.41 Å. The C(47)-C(83) bond length is 1.45 Å. In the forty-eighth C site, C(48) is bonded in a trigonal planar geometry to one C(44), one C(52), and one C(84) atom. The C(48)-C(52) bond length is 1.40 Å. The C(48)-C(84) bond length is 1.45 Å. In the forty-ninth C site, C(49) is bonded in a distorted single-bond geometry to one C(29), one C(45), and one H(33) atom. The C(49)-H(33) bond length is 1.09 Å. In the fiftieth C site, C(50) is bonded in a distorted single-bond geometry to one C(30), one C(46), and one H(34) atom. The C(50)-H(34) bond length is 1.09 Å. In the fifty-first C site, C(51) is bonded in a distorted single-bond geometry to one C(31), one C(47), and one H(35) atom. The C(51)-H(35) bond length is 1.09 Å. In the fifty-second C site, C(52) is bonded in a distorted single-bond geometry to one C(32), one C(48), and one H(36) atom. The C(52)-H(36) bond length is 1.09 Å. In the fifty-third C site, C(53) is bonded in a distorted single-bond geometry to one C(37), one C(57), and one H(37) atom. The C(53)-C(57) bond length is 1.35 Å. The C(53)-H(37) bond length is 1.09 Å. In the fifty-fourth C site, C(54) is bonded in a distorted single-bond geometry to one C(38), one C(58), and one H(38) atom. The C(54)-C(58) bond length is 1.35 Å. The C(54)-H(38) bond length is 1.09 Å. In the fifty-fifth C site, C(55) is bonded in a distorted single-bond geometry to one C(39), one C(59), and one H(39) atom. The C(55)-C(59) bond length is 1.35 Å. The C(55)-H(39) bond length is 1.09 Å. In the fifty-sixth C site, C(56) is bonded in a distorted single-bond geometry to one C(40), one C(60), and one H(40) atom. The C(56)-C(60) bond length is 1.35 Å. The C(56)-H(40) bond length is 1.09 Å. In the fifty-seventh C site, C(57) is bonded in a distorted single-bond geometry to one C(53), one C(61), and one H(41) atom. The C(57)-C(61) bond length is 1.45 Å. The C(57)-H(41) bond length is 1.09 Å. In the fifty-eighth C site, C(58) is bonded in a distorted single-bond geometry to one C(54), one C(62), and one H(42) atom. The C(58)-C(62) bond length is 1.45 Å. The C(58)-H(42) bond length is 1.09 Å. In the fifty-ninth C site, C(59) is bonded in a distorted single-bond geometry to one C(55), one C(63), and one H(43) atom. The C(59)-C(63) bond length is 1.45 Å. The C(59)-H(43) bond length is 1.09 Å. In the sixtieth C site, C(60) is bonded in a distorted single-bond geometry to one C(56), one C(64), and one H(44) atom. The C(60)-C(64) bond length is 1.45 Å. The C(60)-H(44) bond length is 1.09 Å. In the sixty-first C site, C(61) is bonded in a trigonal planar geometry to one C(57), one C(65), and one C(77) atom. The C(61)-C(65) bond length is 1.41 Å. The C(61)-C(77) bond length is 1.41 Å. In the sixty-second C site, C(62) is bonded in a trigonal planar geometry to one C(58), one C(66), and one C(78) atom. The C(62)-C(66) bond length is 1.41 Å. The C(62)-C(78) bond length is 1.41 Å. In the sixty-third C site, C(63) is bonded in a trigonal planar geometry to one C(59), one C(67), and one C(79) atom. The C(63)-C(67) bond length is 1.41 Å. The C(63)-C(79) bond length is 1.41 Å. In the sixty-fourth C site, C(64) is bonded in a trigonal planar geometry to one C(60), one C(68), and one C(80) atom. The C(64)-C(68) bond length is 1.41 Å. The C(64)-C(80) bond length is 1.41 Å. In the sixty-fifth C site, C(65) is bonded in a distorted single-bond geometry to one C(61) and one H(45) atom. The C(65)-H(45) bond length is 1.09 Å. In the sixty-sixth C site, C(66) is bonded in a distorted single-bond geometry to one C(62) and one H(46) atom. The C(66)-H(46) bond length is 1.09 Å. In the sixty-seventh C site, C(67) is bonded in a distorted single-bond geometry to one C(63) and one H(47) atom. The C(67)-H(47) bond length is 1.09 Å. In the sixty-eighth C site, C(68) is bonded in a distorted single-bond geometry to one C(64) and one H(48) atom. The C(68)-H(48) bond length is 1.09 Å. In the sixty-ninth C site, C(69) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(49,50) atom. The C(69)-N(9) bond length is 1.35 Å. The C(69)-H(49,50) bond length is 1.09 Å. In the seventieth C site, C(70) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(49,50) atom. The C(70)-N(10) bond length is 1.35 Å. The C(70)-H(49,50) bond length is 1.09 Å. In the seventy-first C site, C(71) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(51) atom. The C(71)-N(11) bond length is 1.35 Å. The C(71)-H(51) bond length is 1.09 Å. In the seventy-second C site, C(72) is bonded in a distorted bent 120 degrees geometry to one N(12) and one H(52) atom. The C(72)-N(12) bond length is 1.35 Å. The C(72)-H(52) bond length is 1.09 Å. In the seventy-third C site, C(73) is bonded in a distorted trigonal planar geometry to one C(77), one N(9), and one H(53) atom. The C(73)-C(77) bond length is 1.39 Å. The C(73)-N(9) bond length is 1.35 Å. The C(73)-H(53) bond length is 1.09 Å. In the seventy-fourth C site, C(74) is bonded in a distorted trigonal planar geometry to one C(78), one N(10), and one H(54) atom. The C(74)-C(78) bond length is 1.39 Å. The C(74)-N(10) bond length is 1.35 Å. The C(74)-H(54) bond length is 1.09 Å. In the seventy-fifth C site, C(75) is bonded in a distorted trigonal planar geometry to one N(11) and one H(55) atom. The C(75)-N(11) bond length is 1.35 Å. The C(75)-H(55) bond length is 1.09 Å. In the seventy-sixth C site, C(76) is bonded in a distorted trigonal planar geometry to one C(80), one N(12), and one H(56) atom. The C(76)-C(80) bond length is 1.39 Å. The C(76)-N(12) bond length is 1.35 Å. The C(76)-H(56) bond length is 1.09 Å. In the seventy-seventh C site, C(77) is bonded in a distorted single-bond geometry to one C(61), one C(73), and one H(57) atom. The C(77)-H(57) bond length is 1.09 Å. In the seventy-eighth C site, C(78) is bonded in a distorted single-bond geometry to one C(62), one C(74), and one H(58) atom. The C(78)-H(58) bond length is 1.09 Å. In the seventy-ninth C site, C(79) is bonded in a distorted single-bond geometry to one C(63) and one H(59) atom. The C(79)-H(59) bond length is 1.09 Å. In the eightieth C site, C(80) is bonded in a distorted single-bond geometry to one C(64), one C(76), and one H(60) atom. The C(80)-H(60) bond length is 1.09 Å. In the eighty-first C site, C(81) is bonded in a distorted single-bond geometry to one C(45), one C(85), and one H(61) atom. The C(81)-C(85) bond length is 1.35 Å. The C(81)-H(61) bond length is 1.09 Å. In the eighty-second C site, C(82) is bonded in a distorted single-bond geometry to one C(46), one C(86), and one H(62) atom. The C(82)-C(86) bond length is 1.35 Å. The C(82)-H(62) bond length is 1.09 Å. In the eighty-third C site, C(83) is bonded in a distorted single-bond geometry to one C(47), one C(87), and one H(63) atom. The C(83)-C(87) bond length is 1.35 Å. The C(83)-H(63) bond length is 1.09 Å. In the eighty-fourth C site, C(84) is bonded in a distorted single-bond geometry to one C(48), one C(88), and one H(64) atom. The C(84)-C(88) bond length is 1.35 Å. The C(84)-H(64) bond length is 1.09 Å. In the eighty-fifth C site, C(85) is bonded in a distorted single-bond geometry to one C(81), one C(89), and one H(65) atom. The C(85)-C(89) bond length is 1.45 Å. The C(85)-H(65) bond length is 1.09 Å. In the eighty-sixth C site, C(86) is bonded in a distorted single-bond geometry to one C(82), one C(90), and one H(66) atom. The C(86)-C(90) bond length is 1.45 Å. The C(86)-H(66) bond length is 1.09 Å. In the eighty-seventh C site, C(87) is bonded in a distorted single-bond geometry to one C(83), one C(91), and one H(67) atom. The C(87)-C(91) bond length is 1.45 Å. The C(87)-H(67) bond length is 1.09 Å. In the eighty-eighth C site, C(88) is bonded in a distorted single-bond geometry to one C(84), one C(92), and one H(68) atom. The C(88)-C(92) bond length is 1.45 Å. The C(88)-H(68) bond length is 1.09 Å. In the eighty-ninth C site, C(89) is bonded in a trigonal planar geometry to one C(105), one C(85), and one C(93) atom. The C(89)-C(105) bond length is 1.41 Å. The C(89)-C(93) bond length is 1.41 Å. In the ninetieth C site, C(90) is bonded in a trigonal planar geometry to one C(106), one C(86), and one C(94) atom. The C(90)-C(106) bond length is 1.41 Å. The C(90)-C(94) bond length is 1.41 Å. In the ninety-first C site, C(91) is bonded in a trigonal planar geometry to one C(107), one C(87), and one C(95) atom. The C(91)-C(107) bond length is 1.41 Å. The C(91)-C(95) bond length is 1.41 Å. In the ninety-second C site, C(92) is bonded in a trigonal planar geometry to one C(108), one C(88), and one C(96) atom. The C(92)-C(108) bond length is 1.41 Å. The C(92)-C(96) bond length is 1.41 Å. In the ninety-third C site, C(93) is bonded in a distorted single-bond geometry to one C(89), one C(97), and one H(69) atom. The C(93)-C(97) bond length is 1.38 Å. The C(93)-H(69) bond length is 1.09 Å. In the ninety-fourth C site, C(94) is bonded in a distorted single-bond geometry to one C(90), one C(98), and one H(70) atom. The C(94)-C(98) bond length is 1.38 Å. The C(94)-H(70) bond length is 1.09 Å. In the ninety-fifth C site, C(95) is bonded in a distorted single-bond geometry to one C(91), one C(99), and one H(71) atom. The C(95)-C(99) bond length is 1.38 Å. The C(95)-H(71) bond length is 1.09 Å. In the ninety-sixth C site, C(96) is bonded in a distorted single-bond geometry to one C(100), one C(92), and one H(72) atom. The C(96)-C(100) bond length is 1.38 Å. The C(96)-H(72) bond length is 1.09 Å. In the ninety-seventh C site, C(97) is bonded in a distorted trigonal planar geometry to one C(93), one N(1), and one H(73) atom. The C(97)-N(1) bond length is 1.35 Å. The C(97)-H(73) bond length is 1.09 Å. In the ninety-eighth C site, C(98) is bonded in a distorted trigonal planar geometry to one C(94), one N(2), and one H(74) atom. The C(98)-N(2) bond length is 1.35 Å. The C(98)-H(74) bond length is 1.09 Å. In the ninety-ninth C site, C(99) is bonded in a distorted trigonal planar geometry to one C(95), one N(3), and one H(75) atom. The C(99)-N(3) bond length is 1.36 Å. The C(99)-H(75) bond length is 1.09 Å. In the one hundredth C site, C(100) is bonded in a distorted trigonal planar geometry to one C(96), one N(4), and one H(76) atom. The C(100)-N(4) bond length is 1.35 Å. The C(100)-H(76) bond length is 1.09 Å. In the one hundred and first C site, C(101) is bonded in a distorted trigonal planar geometry to one C(105), one N(1), and one H(77) atom. The C(101)-C(105) bond length is 1.39 Å. The C(101)-N(1) bond length is 1.35 Å. The C(101)-H(77) bond length is 1.09 Å. In the one hundred and second C site, C(102) is bonded in a distorted trigonal planar geometry to one C(106), one N(2), and one H(78) atom. The C(102)-C(106) bond length is 1.39 Å. The C(102)-N(2) bond length is 1.35 Å. The C(102)-H(78) bond length is 1.09 Å. In the one hundred and third C site, C(103) is bonded in a distorted trigonal planar geometry to one C(107), one N(3), and one H(79) atom. The C(103)-C(107) bond length is 1.39 Å. The C(103)-N(3) bond length is 1.35 Å. The C(103)-H(79) bond length is 1.09 Å. In the one hundred and fourth C site, C(104) is bonded in a distorted trigonal planar geometry to one C(108), one N(4), and one H(80) atom. The C(104)-C(108) bond length is 1.39 Å. The C(104)-N(4) bond length is 1.35 Å. The C(104)-H(80) bond length is 1.09 Å. In the one hundred and fifth C site, C(105) is bonded in a distorted single-bond geometry to one C(101), one C(89), and one H(81) atom. The C(105)-H(81) bond length is 1.09 Å. In the one hundred and sixth C site, C(106) is bonded in a distorted single-bond geometry to one C(102), one C(90), and one H(82) atom. The C(106)-H(82) bond length is 1.09 Å. In the one hundred and seventh C site, C(107) is bonded in a distorted single-bond geometry to one C(103), one C(91), and one H(83) atom. The C(107)-H(83) bond length is 1.09 Å. In the one hundred and eighth C site, C(108) is bonded in a distorted single-bond geometry to one C(104), one C(92), and one H(84) atom. The C(108)-H(84) bond length is 1.09 Å. In the one hundred and ninth C site, C(109) is bonded in a bent 120 degrees geometry to one C(113), one O(1), and one O(5) atom. The C(109)-C(113) bond length is 1.50 Å. The C(109)-O(1) bond length is 1.28 Å. The C(109)-O(5) bond length is 1.28 Å. In the one hundred and tenth C site, C(110) is bonded in a bent 120 degrees geometry to one C(114), one O(2), and one O(6) atom. The C(110)-C(114) bond length is 1.50 Å. The C(110)-O(2) bond length is 1.28 Å. The C(110)-O(6) bond length is 1.28 Å. In the one hundred and eleventh C site, C(111) is bonded in a bent 120 degrees geometry to one C(115), one O(3), and one O(7) atom. The C(111)-C(115) bond length is 1.50 Å. The C(111)-O(3) bond length is 1.31 Å. The C(111)-O(7) bond length is 1.25 Å. In the one hundred and twelfth C site, C(112) is bonded in a bent 120 degrees geometry to one C(116), one O(4), and one O(8) atom. The C(112)-C(116) bond length is 1.50 Å. The C(112)-O(4) bond length is 1.28 Å. The C(112)-O(8) bond length is 1.28 Å. In the one hundred and thirteenth C site, C(113) is bonded in a trigonal planar geometry to one C(109), one C(117), and one C(133) atom. The C(113)-C(117) bond length is 1.41 Å. The C(113)-C(133) bond length is 1.41 Å. In the one hundred and fourteenth C site, C(114) is bonded in a trigonal planar geometry to one C(110), one C(118), and one C(134) atom. The C(114)-C(118) bond length is 1.41 Å. The C(114)-C(134) bond length is 1.41 Å. In the one hundred and fifteenth C site, C(115) is bonded in a trigonal planar geometry to one C(111), one C(119), and one C(135) atom. The C(115)-C(119) bond length is 1.40 Å. The C(115)-C(135) bond length is 1.41 Å. In the one hundred and sixteenth C site, C(116) is bonded in a trigonal planar geometry to one C(112), one C(120), and one C(136) atom. The C(116)-C(120) bond length is 1.41 Å. The C(116)-C(136) bond length is 1.41 Å. In the one hundred and seventeenth C site, C(117) is bonded in a distorted single-bond geometry to one C(113) and one H(85) atom. The C(117)-H(85) bond length is 1.09 Å. In the one hundred and eighteenth C site, C(118) is bonded in a distorted single-bond geometry to one C(114) and one H(86) atom. The C(118)-H(86) bond length is 1.09 Å. In the one hundred and nineteenth C site, C(119) is bonded in a distorted single-bond geometry to one C(115) and one H(87) atom. The C(119)-H(87) bond length is 1.09 Å. In the one hundred and twentieth C site, C(120) is bonded in a distorted single-bond geometry to one C(116) and one H(88) atom. The C(120)-H(88) bond length is 1.09 Å. In the one hundred and twenty-first C site, C(129) is bonded in a distorted single-bond geometry to one C(133) and one H(97) atom. The C(129)-C(133) bond length is 1.41 Å. The C(129)-H(97) bond length is 1.09 Å. In the one hundred and twenty-second C site, C(130) is bonded in a distorted single-bond geometry to one C(134) and one H(98) atom. The C(130)-C(134) bond length is 1.41 Å. The C(130)-H(98) bond length is 1.09 Å. In the one hundred and twenty-third C site, C(131) is bonded in a distorted single-bond geometry to one C(135) and one H(99) atom. The C(131)-C(135) bond length is 1.40 Å. The C(131)-H(99) bond length is 1.09 Å. In the one hundred and twenty-fourth C site, C(132) is bonded in a distorted single-bond geometry to one C(136) and one H(100) atom. The C(132)-C(136) bond length is 1.40 Å. The C(132)-H(100) bond length is 1.09 Å. In the one hundred and twenty-fifth C site, C(133) is bonded in a trigonal planar geometry to one C(113), one C(129), and one C(137) atom. The C(133)-C(137) bond length is 1.49 Å. In the one hundred and twenty-sixth C site, C(134) is bonded in a trigonal planar geometry to one C(114), one C(130), and one C(138) atom. The C(134)-C(138) bond length is 1.49 Å. In the one hundred and twenty-seventh C site, C(135) is bonded in a trigonal planar geometry to one C(115), one C(131), and one C(139) atom. The C(135)-C(139) bond length is 1.49 Å. In the one hundred and twenty-eighth C site, C(136) is bonded in a trigonal planar geometry to one C(116), one C(132), and one C(140) atom. The C(136)-C(140) bond length is 1.49 Å. In the one hundred and twenty-ninth C site, C(137) is bonded in a trigonal planar geometry to one C(133), one C(141), and one C(157) atom. The C(137)-C(141) bond length is 1.40 Å. The C(137)-C(157) bond length is 1.42 Å. In the one hundred and thirtieth C site, C(138) is bonded in a trigonal planar geometry to one C(134), one C(142), and one C(158) atom. The C(138)-C(142) bond length is 1.40 Å. The C(138)-C(158) bond length is 1.42 Å. In the one hundred and thirty-first C site, C(139) is bonded in a trigonal planar geometry to one C(135), one C(143), and one C(159) atom. The C(139)-C(143) bond length is 1.40 Å. The C(139)-C(159) bond length is 1.41 Å. In the one hundred and thirty-second C site, C(140) is bonded in a trigonal planar geometry to one C(136), one C(144), and one C(160) atom. The C(140)-C(144) bond length is 1.40 Å. The C(140)-C(160) bond length is 1.42 Å. In the one hundred and thirty-third C site, C(141) is bonded in a distorted single-bond geometry to one C(137) and one H(101,102) atom. The C(141)-H(101,102) bond length is 1.09 Å. In the one hundred and thirty-fourth C site, C(142) is bonded in a distorted single-bond geometry to one C(138) and one H(101,102) atom. The C(142)-H(101,102) bond length is 1.09 Å. In the one hundred and thirty-fifth C site, C(143) is bonded in a distorted single-bond geometry to one C(139) and one H(103) atom. The C(143)-H(103) bond length is 1.09 Å. In the one hundred and thirty-sixth C site, C(144) is bonded in a distorted single-bond geometry to one C(140) and one H(104) atom. The C(144)-H(104) bond length is 1.09 Å. In the one hundred and thirty-seventh C site, C(149) is bonded in a distorted single-bond geometry to one C(153) and one H(109) atom. The C(149)-C(153) bond length is 1.39 Å. The C(149)-H(109) bond length is 1.09 Å. In the one hundred and thirty-eighth C site, C(151) is bonded in a distorted single-bond geometry to one C(155) and one H(111) atom. The C(151)-C(155) bond length is 1.39 Å. The C(151)-H(111) bond length is 1.09 Å. In the one hundred and thirty-ninth C site, C(153) is bonded in a distorted single-bond geometry to one C(149), one C(157), and one H(113) atom. The C(153)-C(157) bond length is 1.40 Å. The C(153)-H(113) bond length is 1.09 Å. In the one hundred and fortieth C site, C(154) is bonded in a distorted single-bond geometry to one C(158) and one H(114) atom. The C(154)-C(158) bond length is 1.40 Å. The C(154)-H(114) bond length is 1.09 Å. In the one hundred and forty-first C site, C(155) is bonded in a distorted trigonal planar geometry to one C(151), one C(159), and one H(115) atom. The C(155)-C(159) bond length is 1.40 Å. The C(155)-H(115) bond length is 1.09 Å. In the one hundred and forty-second C site, C(156) is bonded in a distorted single-bond geometry to one C(160) and one H(116) atom. The C(156)-C(160) bond length is 1.40 Å. The C(156)-H(116) bond length is 1.09 Å. In the one hundred and forty-third C site, C(157) is bonded in a trigonal planar geometry to one C(137), one C(153), and one C(161) atom. The C(157)-C(161) bond length is 1.52 Å. In the one hundred and forty-fourth C site, C(158) is bonded in a trigonal planar geometry to one C(138), one C(154), and one C(162) atom. The C(158)-C(162) bond length is 1.52 Å. In the one hundred and forty-fifth C site, C(159) is bonded in a trigonal planar geometry to one C(139), one C(155), and one C(163) atom. The C(159)-C(163) bond length is 1.51 Å. In the one hundred and forty-sixth C site, C(160) is bonded in a trigonal planar geometry to one C(140), one C(156), and one C(164) atom. The C(160)-C(164) bond length is 1.51 Å. In the one hundred and forty-seventh C site, C(161) is bonded in a distorted bent 120 degrees geometry to one C(157), one O(13), and one O(9) atom. The C(161)-O(13) bond length is 1.30 Å. The C(161)-O(9) bond length is 1.25 Å. In the one hundred and forty-eighth C site, C(162) is bonded in a distorted bent 120 degrees geometry to one C(158), one O(10), and one O(14) atom. The C(162)-O(10) bond length is 1.25 Å. The C(162)-O(14) bond length is 1.30 Å. In the one hundred and forty-ninth C site, C(163) is bonded in a distorted bent 120 degrees geometry to one C(159), one O(11), and one O(15) atom. The C(163)-O(11) bond length is 1.25 Å. The C(163)-O(15) bond length is 1.30 Å. In the one hundred and fiftieth C site, C(164) is bonded in a distorted bent 120 degrees geometry to one C(160), one O(12), and one O(16) atom. The C(164)-O(12) bond length is 1.24 Å. The C(164)-O(16) bond length is 1.30 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(101), and one C(97) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(2), one C(102), and one C(98) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(3), one C(103), and one C(99) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(4), one C(100), and one C(104) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(4), one C(1), and one C(17) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Co(3), one C(18), and one C(2) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Co(2), one C(19), and one C(3) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Co(1), one C(20), and one C(4) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Co(1), one C(69), and one C(73) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Co(2), one C(70), and one C(74) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Co(3), one C(71), and one C(75) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Co(4), one C(72), and one C(76) atom. There are ninety-six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(11,12) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the twentieth H site, H(21) is bonded in a single-bond geometry to one C(25) atom. In the twenty-first H site, H(22,23) is bonded in a single-bond geometry to one C(26) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(28) atom. In the twenty-third H site, H(25) is bonded in a single-bond geometry to one C(33) atom. In the twenty-fourth H site, H(26,27) is bonded in a single-bond geometry to one C(34) atom. In the twenty-fifth H site, H(28) is bonded in a single-bond geometry to one C(36) atom. In the twenty-sixth H site, H(29,30) is bonded in a single-bond geometry to one C(41) atom. In the twenty-seventh H site, H(31) is bonded in a single-bond geometry to one C(43) atom. In the twenty-eighth H site, H(32) is bonded in a single-bond geometry to one C(44) atom. In the twenty-ninth H site, H(33) is bonded in a single-bond geometry to one C(49) atom. In the thirtieth H site, H(34) is bonded in a single-bond geometry to one C(50) atom. In the thirty-first H site, H(35) is bonded in a single-bond geometry to one C(51) atom. In the thirty-second H site, H(36) is bonded in a single-bond geometry to one C(52) atom. In the thirty-third H site, H(37) is bonded in a single-bond geometry to one C(53) atom. In the thirty-fourth H site, H(38) is bonded in a single-bond geometry to one C(54) atom. In the thirty-fifth H site, H(39) is bonded in a single-bond geometry to one C(55) atom. In the thirty-sixth H site, H(40) is bonded in a single-bond geometry to one C(56) atom. In the thirty-seventh H site, H(41) is bonded in a single-bond geometry to one C(57) atom. In the thirty-eighth H site, H(42) is bonded in a single-bond geometry to one C(58) atom. In the thirty-ninth H site, H(43) is bonded in a single-bond geometry to one C(59) atom. In the fortieth H site, H(44) is bonded in a single-bond geometry to one C(60) atom. In the forty-first H site, H(45) is bonded in a single-bond geometry to one C(65) atom. In the forty-second H site, H(46) is bonded in a single-bond geometry to one C(66) atom. In the forty-third H site, H(47) is bonded in a single-bond geometry to one C(67) atom. In the forty-fourth H site, H(48) is bonded in a single-bond geometry to one C(68) atom. In the forty-fifth H site, H(49,50) is bonded in a single-bond geometry to one C(69) atom. In the forty-sixth H site, H(51) is bonded in a single-bond geometry to one C(71) atom. In the forty-seventh H site, H(52) is bonded in a single-bond geometry to one C(72) atom. In the forty-eighth H site, H(53) is bonded in a single-bond geometry to one C(73) atom. In the forty-ninth H site, H(54) is bonded in a single-bond geometry to one C(74) atom. In the fiftieth H site, H(55) is bonded in a single-bond geometry to one C(75) atom. In the fifty-first H site, H(56) is bonded in a single-bond geometry to one C(76) atom. In the fifty-second H site, H(57) is bonded in a single-bond geometry to one C(77) atom. In the fifty-third H site, H(58) is bonded in a single-bond geometry to one C(78) atom. In the fifty-fourth H site, H(59) is bonded in a single-bond geometry to one C(79) atom. In the fifty-fifth H site, H(60) is bonded in a single-bond geometry to one C(80) atom. In the fifty-sixth H site, H(61) is bonded in a single-bond geometry to one C(81) atom. In the fifty-seventh H site, H(62) is bonded in a single-bond geometry to one C(82) atom. In the fifty-eighth H site, H(63) is bonded in a single-bond geometry to one C(83) atom. In the fifty-ninth H site, H(64) is bonded in a single-bond geometry to one C(84) atom. In the sixtieth H site, H(65) is bonded in a single-bond geometry to one C(85) atom. In the sixty-first H site, H(66) is bonded in a single-bond geometry to one C(86) atom. In the sixty-second H site, H(67) is bonded in a single-bond geometry to one C(87) atom. In the sixty-third H site, H(68) is bonded in a single-bond geometry to one C(88) atom. In the sixty-fourth H site, H(69) is bonded in a single-bond geometry to one C(93) atom. In the sixty-fifth H site, H(70) is bonded in a single-bond geometry to one C(94) atom. In the sixty-sixth H site, H(71) is bonded in a single-bond geometry to one C(95) atom. In the sixty-seventh H site, H(72) is bonded in a single-bond geometry to one C(96) atom. In the sixty-eighth H site, H(73) is bonded in a single-bond geometry to one C(97) atom. In the sixty-ninth H site, H(74) is bonded in a single-bond geometry to one C(98) atom. In the seventieth H site, H(75) is bonded in a single-bond geometry to one C(99) atom. In the seventy-first H site, H(76) is bonded in a single-bond geometry to one C(100) atom. In the seventy-second H site, H(77) is bonded in a single-bond geometry to one C(101) atom. In the seventy-third H site, H(78) is bonded in a single-bond geometry to one C(102) atom. In the seventy-fourth H site, H(79) is bonded in a single-bond geometry to one C(103) atom. In the seventy-fifth H site, H(80) is bonded in a single-bond geometry to one C(104) atom. In the seventy-sixth H site, H(81) is bonded in a single-bond geometry to one C(105) atom. In the seventy-seventh H site, H(82) is bonded in a single-bond geometry to one C(106) atom. In the seventy-eighth H site, H(83) is bonded in a single-bond geometry to one C(107) atom. In the seventy-ninth H site, H(84) is bonded in a single-bond geometry to one C(108) atom. In the eightieth H site, H(85) is bonded in a single-bond geometry to one C(117) atom. In the eighty-first H site, H(86) is bonded in a single-bond geometry to one C(118) atom. In the eighty-second H site, H(87) is bonded in a single-bond geometry to one C(119) atom. In the eighty-third H site, H(88) is bonded in a single-bond geometry to one C(120) atom. In the eighty-fourth H site, H(97) is bonded in a single-bond geometry to one C(129) atom. In the eighty-fifth H site, H(98) is bonded in a single-bond geometry to one C(130) atom. In the eighty-sixth H site, H(99) is bonded in a single-bond geometry to one C(131) atom. In the eighty-seventh H site, H(100) is bonded in a single-bond geometry to one C(132) atom. In the eighty-eighth H site, H(101,102) is bonded in a single-bond geometry to one C(141) atom. In the eighty-ninth H site, H(103) is bonded in a single-bond geometry to one C(143) atom. In the ninetieth H site, H(104) is bonded in a single-bond geometry to one C(144) atom. In the ninety-first H site, H(109) is bonded in a single-bond geometry to one C(149) atom. In the ninety-second H site, H(111) is bonded in a single-bond geometry to one C(151) atom. In the ninety-third H site, H(113) is bonded in a single-bond geometry to one C(153) atom. In the ninety-fourth H site, H(114) is bonded in a single-bond geometry to one C(154) atom. In the ninety-fifth H site, H(115) is bonded in a single-bond geometry to one C(155) atom. In the ninety-sixth H site, H(116) is bonded in a single-bond geometry to one C(156) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Co(1) and one C(109) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Co(2) and one C(110) atom. In the third O site, O(3) is bonded in a water-like geometry to one Co(3) and one C(111) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Co(4) and one C(112) atom. In the fifth O site, O(5) is bonded in a distorted L-shaped geometry to one Co(1) and one C(109) atom. In the sixth O site, O(6) is bonded in a distorted L-shaped geometry to one Co(2) and one C(110) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(111) atom. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one Co(4) and one C(112) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(161) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(162) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one C(163) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one C(164) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Co(2) and one C(161) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Co(1) and one C(162) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Co(4) and one C(163) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Co(3) and one C(164) atom. Linkers: 4 C(=C/c1cc(/C=C/c2ccncc2)cc(/C=C/c2ccncc2)c1)\c1ccncc1 ,4 [O]C(=O)c1ccccc1-c1ccccc1C([O])=O. Metal clusters: 3 O=[C]O[Co]1O[C]O1 ,1 O=[C]O[Co]O[C]=O. The MOF has largest included sphere 4.32 A, density 1.30 g/cm3, surface area 4762.67 m2/g, accessible volume 0.19 cm3/g