ZnC14N2H10O5C4H2O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two furan molecules and one ZnC14N2H10O5 cluster. In the ZnC14N2H10O5 cluster, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(2), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.18 Å. The Zn(1)-N(2) bond length is 2.09 Å. The Zn(1)-O(2) bond length is 2.10 Å. The Zn(1)-O(3) bond length is 2.04 Å. The Zn(1)-O(4) bond length is 2.02 Å. There are fourteen inequivalent C sites. In the first C site, C(4) is bonded in a distorted trigonal planar geometry to one C(13), one C(6), and one N(2) atom. The C(4)-C(13) bond length is 1.42 Å. The C(4)-C(6) bond length is 1.44 Å. The C(4)-N(2) bond length is 1.36 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(6) atom. The C(5)-O(3) bond length is 1.31 Å. The C(5)-O(6) bond length is 1.25 Å. In the third C site, C(6) is bonded in a distorted trigonal planar geometry to one C(12), one C(4), and one N(1) atom. The C(6)-C(12) bond length is 1.42 Å. The C(6)-N(1) bond length is 1.35 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(7)-O(4) bond length is 1.29 Å. The C(7)-O(5) bond length is 1.26 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(12) and one H(2) atom. The C(8)-C(12) bond length is 1.41 Å. The C(8)-H(2) bond length is 1.09 Å. In the sixth C site, C(10) is bonded in a distorted single-bond geometry to one C(13) and one H(4) atom. The C(10)-C(13) bond length is 1.41 Å. The C(10)-H(4) bond length is 1.09 Å. In the seventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(15), one N(1), and one H(5) atom. The C(11)-C(15) bond length is 1.41 Å. The C(11)-N(1) bond length is 1.33 Å. The C(11)-H(5) bond length is 1.09 Å. In the eighth C site, C(12) is bonded in a trigonal planar geometry to one C(18), one C(6), and one C(8) atom. The C(12)-C(18) bond length is 1.43 Å. In the ninth C site, C(13) is bonded in a trigonal planar geometry to one C(10), one C(16), and one C(4) atom. The C(13)-C(16) bond length is 1.43 Å. In the tenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(17), one N(2), and one H(6) atom. The C(14)-C(17) bond length is 1.41 Å. The C(14)-N(2) bond length is 1.33 Å. The C(14)-H(6) bond length is 1.09 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(15)-H(7) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(13) and one H(8) atom. The C(16)-H(8) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(14) and one H(9) atom. The C(17)-H(9) bond length is 1.09 Å. In the fourteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(18)-H(10) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(14), and one C(4) atom. There are ten inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(11) is bonded in a distorted single-bond geometry to one O(2) and one O(5) atom. The H(11)-O(2) bond length is 1.00 Å. The H(11)-O(5) bond length is 1.64 Å. In the tenth H site, H(12) is bonded in a distorted single-bond geometry to one O(2) and one O(3) atom. The H(12)-O(2) bond length is 1.00 Å. The H(12)-O(3) bond length is 1.67 Å. There are five inequivalent O sites. In the first O site, O(2) is bonded in a distorted water-like geometry to one Zn(1), one H(11), and one H(12) atom. In the second O site, O(3) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(5), and one H(12) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the fourth O site, O(5) is bonded in a 2-coordinate geometry to one C(7) and one H(11) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(5) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)o1. Metal clusters: 2 O.O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.89 A, density 1.64 g/cm3, surface area 4292.29 m2/g, accessible volume 0.12 cm3/g