CdC10N5H7S2 crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded in an octahedral geometry to one N(1), one N(3), one N(4), one N(5), one S(1), and one S(2) atom. The Cd(1)-N(1) bond length is 2.34 Å. The Cd(1)-N(3) bond length is 2.34 Å. The Cd(1)-N(4) bond length is 2.39 Å. The Cd(1)-N(5) bond length is 2.32 Å. The Cd(1)-S(1) bond length is 2.77 Å. The Cd(1)-S(2) bond length is 2.73 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.42 Å. The C(2)-C(4) bond length is 1.45 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(2) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(8) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(3), and one H(4) atom. The C(6)-N(3) bond length is 1.35 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(3), and one H(5) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-N(3) bond length is 1.35 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(4), one C(7), and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted linear geometry to one N(4) and one S(1) atom. The C(9)-N(4) bond length is 1.19 Å. The C(9)-S(1) bond length is 1.62 Å. In the tenth C site, C(10) is bonded in a distorted linear geometry to one N(5) and one S(2) atom. The C(10)-N(5) bond length is 1.18 Å. The C(10)-S(2) bond length is 1.63 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Cd(1), one C(3), and one N(2) atom. The N(1)-N(2) bond length is 1.35 Å. In the second N site, N(2) is bonded in a 2-coordinate geometry to one C(1), one N(1), and one H(7) atom. The N(2)-H(7) bond length is 1.03 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(6), and one C(7) atom. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(9) atom. In the fifth N site, N(5) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(10) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Cd(1) and one C(9) atom. In the second S site, S(2) is bonded in a water-like geometry to one Cd(1) and one C(10) atom. Linkers: 4 c1cc(-c2cn[nH]c2)ccn1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 2.54 A, density 1.96 g/cm3, surface area 3885.93 m2/g, accessible volume 0.09 cm3/g