CH(CH3)3Hg2C15H9S(NO2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, six 02329_fluka molecules, and two Hg2C15H9S(NO2)3 clusters. In each Hg2C15H9S(NO2)3 cluster, there are two inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a distorted linear geometry to one C(1) and one O(1) atom. The Hg(1)-C(1) bond length is 2.06 Å. The Hg(1)-O(1) bond length is 2.11 Å. In the second Hg site, Hg(2) is bonded in a distorted rectangular see-saw-like geometry to one N(3), one S(1), one O(2), and one O(5) atom. The Hg(2)-N(3) bond length is 2.58 Å. The Hg(2)-S(1) bond length is 2.43 Å. The Hg(2)-O(2) bond length is 2.32 Å. The Hg(2)-O(5) bond length is 2.29 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one Hg(1), one C(4), and one N(2) atom. The C(1)-C(4) bond length is 1.39 Å. The C(1)-N(2) bond length is 1.38 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. The C(2)-N(1) bond length is 1.37 Å. The C(2)-N(2) bond length is 1.37 Å. The C(2)-S(1) bond length is 1.71 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one H(1) atom. The C(3)-C(7) bond length is 1.37 Å. The C(3)-N(1) bond length is 1.38 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(1), one C(9), and one N(1) atom. The C(4)-C(9) bond length is 1.41 Å. The C(4)-N(1) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(13), one C(6), and one N(3) atom. The C(5)-C(13) bond length is 1.40 Å. The C(5)-C(6) bond length is 1.51 Å. The C(5)-N(3) bond length is 1.35 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one N(2), one H(2), and one H(3) atom. The C(6)-N(2) bond length is 1.47 Å. The C(6)-H(2) bond length is 1.10 Å. The C(6)-H(3) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(9)-H(6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(10)-O(1) bond length is 1.32 Å. The C(10)-O(3) bond length is 1.24 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(3), and one H(7) atom. The C(11)-C(14) bond length is 1.39 Å. The C(11)-N(3) bond length is 1.34 Å. The C(11)-H(7) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(15), one C(5), and one H(11) atom. The C(13)-C(15) bond length is 1.40 Å. The C(13)-H(11) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(11), one C(15), and one H(12) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(12) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(13), one C(14), and one H(13) atom. The C(15)-H(13) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(16)-O(2) bond length is 1.30 Å. The C(16)-O(4) bond length is 1.25 Å. In the fifteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(18)-O(5) bond length is 1.30 Å. The C(18)-O(6) bond length is 1.25 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(6) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one Hg(2), one C(11), and one C(5) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. S(1) is bonded in a water-like geometry to one Hg(2) and one C(2) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Hg(1) and one C(10) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Hg(2) and one C(16) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(10) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(16) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Hg(2) and one C(18) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(18) atom. Linkers: 4 CC([O])=O ,2 S=C1N(Cc2ccccn2)[C]C2=CC=C[CH]N12. Metal clusters: 4 [Hg]. The MOF has largest included sphere 3.13 A, density 2.39 g/cm3, surface area 3215.11 m2/g, accessible volume 0.10 cm3/g