ZnC7H5(N2O)2CH crystallizes in the monoclinic Cc space group. The structure consists of twelve 02329_fluka molecules inside a ZnC7H5(N2O)2 framework. In the ZnC7H5(N2O)2 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1,3) is bonded in a tetrahedral geometry to one N(1), one N(10), one N(5), and one O(4) atom. The Zn(1,3)-N(1) bond length is 1.99 Å. The Zn(1,3)-N(10) bond length is 2.05 Å. The Zn(1,3)-N(5) bond length is 2.01 Å. The Zn(1,3)-O(4) bond length is 2.02 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one N(11), one N(2), one N(4), and one O(6) atom. The Zn(2)-N(11) bond length is 2.05 Å. The Zn(2)-N(2) bond length is 1.99 Å. The Zn(2)-N(4) bond length is 2.01 Å. The Zn(2)-O(6) bond length is 2.02 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(10); one C(4,6); and one H(1,2,3) atom. The C(1)-C(10) bond length is 1.37 Å. The C(1)-C(4,6) bond length is 1.44 Å. The C(1)-H(1,2,3) bond length is 1.09 Å. In the second C site, C(2,3) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(5); and one H(1,2,3) atom. The C(2,3)-C(11,12) bond length is 1.37 Å. The C(2,3)-C(5) bond length is 1.44 Å. The C(2,3)-H(1,2,3) bond length is 1.09 Å. In the third C site, C(4,6) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one O(1) atom. The C(4,6)-N(1) bond length is 1.40 Å. The C(4,6)-O(1) bond length is 1.25 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(2,3); one N(2); and one O(2,3) atom. The C(5)-N(2) bond length is 1.40 Å. The C(5)-O(2,3) bond length is 1.25 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one N(1), one N(4), and one H(4) atom. The C(7)-N(1) bond length is 1.33 Å. The C(7)-N(4) bond length is 1.33 Å. The C(7)-H(4) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one N(2); one N(5); and one H(5,6) atom. The C(8)-N(2) bond length is 1.33 Å. The C(8)-N(5) bond length is 1.33 Å. The C(8)-H(5,6) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one N(3); one N(6); and one H(5,6) atom. The C(9)-N(3) bond length is 1.33 Å. The C(9)-N(6) bond length is 1.33 Å. The C(9)-H(5,6) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(1); one N(4); and one H(7,8) atom. The C(10)-N(4) bond length is 1.38 Å. The C(10)-H(7,8) bond length is 1.09 Å. In the ninth C site, C(11,12) is bonded in a distorted trigonal planar geometry to one C(2,3); one N(5); and one H(7,8) atom. The C(11,12)-N(5) bond length is 1.38 Å. The C(11,12)-H(7,8) bond length is 1.09 Å. In the tenth C site, C(16,17) is bonded in a distorted bent 120 degrees geometry to one N(7) and one O(4) atom. The C(16,17)-N(7) bond length is 1.37 Å. The C(16,17)-O(4) bond length is 1.29 Å. In the eleventh C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(9) and one O(6) atom. The C(18)-N(9) bond length is 1.37 Å. The C(18)-O(6) bond length is 1.29 Å. In the twelfth C site, C(19,21) is bonded in a trigonal planar geometry to one N(10); one N(7); and one H(13,14) atom. The C(19,21)-N(10) bond length is 1.35 Å. The C(19,21)-N(7) bond length is 1.32 Å. The C(19,21)-H(13,14) bond length is 1.09 Å. In the thirteenth C site, C(20) is bonded in a trigonal planar geometry to one N(11); one N(8); and one H(13,14) atom. The C(20)-N(11) bond length is 1.35 Å. The C(20)-N(8) bond length is 1.32 Å. The C(20)-H(13,14) bond length is 1.09 Å. In the fourteenth C site, C(22,24) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(16,17,18) atom. The C(22,24)-N(10) bond length is 1.36 Å. The C(22,24)-H(16,17,18) bond length is 1.09 Å. In the fifteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(16,17,18) atom. The C(23)-N(11) bond length is 1.36 Å. The C(23)-H(16,17,18) bond length is 1.09 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1,3); one C(4,6); and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(5), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1,3); one C(4,6); and one C(9) atom. The N(3)-Zn(1,3) bond length is 1.99 Å. The N(3)-C(4,6) bond length is 1.40 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(2), one C(10), and one C(7) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(1,3); one C(11,12); and one C(8) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(1,3); one C(11,12); and one C(9) atom. The N(6)-Zn(1,3) bond length is 2.01 Å. The N(6)-C(11,12) bond length is 1.38 Å. In the seventh N site, N(7) is bonded in a bent 120 degrees geometry to one C(16,17) and one C(19,21) atom. In the eighth N site, N(8) is bonded in a bent 120 degrees geometry to one C(16,17) and one C(20) atom. The N(8)-C(16,17) bond length is 1.37 Å. In the ninth N site, N(9) is bonded in a bent 120 degrees geometry to one C(18) and one C(19,21) atom. The N(9)-C(19,21) bond length is 1.32 Å. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Zn(1,3); one C(19,21); and one C(22,24) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Zn(2), one C(20), and one C(23) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Zn(1,3); one C(19,21); and one C(22,24) atom. The N(12)-Zn(1,3) bond length is 2.05 Å. The N(12)-C(19,21) bond length is 1.35 Å. The N(12)-C(22,24) bond length is 1.36 Å. There are eight inequivalent H sites. In the first H site, H(1,2,3) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(11,12) atom. The H(9)-C(11,12) bond length is 1.09 Å. In the sixth H site, H(13,14) is bonded in a single-bond geometry to one C(19,21) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(19,21) atom. The H(15)-C(19,21) bond length is 1.09 Å. In the eighth H site, H(16,17,18) is bonded in a single-bond geometry to one C(22,24) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(4,6) atom. In the second O site, O(2,3) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1,3) and one C(16,17) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1,3) and one C(16,17) atom. The O(5)-Zn(1,3) bond length is 2.02 Å. The O(5)-C(16,17) bond length is 1.29 Å. In the fifth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(18) atom. Linkers: 5 O=C1[CH]C=NC=N1 ,4 O=C1C=C[N]C=N1 ,3 O=C1C=CN=C[N]1. Metal clusters: 6 [O][Zn]. The MOF has largest included sphere 2.93 A, density 1.74 g/cm3, surface area 4199.71 m2/g, accessible volume 0.14 cm3/g