ZnC11H12(N3O2)2(C3H2)2(CH)2(CH2CO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; four 2,3-dimethyl-1,3-butadiene molecules; eight dimethyl ether molecules; and four ZnC11H12(N3O2)2 clusters. In each ZnC11H12(N3O2)2 cluster, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(3), one N(5), one O(1), and one O(6) atom. The Zn(1)-N(1) bond length is 2.07 Å. The Zn(1)-N(3) bond length is 2.03 Å. The Zn(1)-N(5) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 2.24 Å. The Zn(1)-O(6) bond length is 2.10 Å. There are eleven inequivalent C sites. In the first C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(14)-O(5) bond length is 1.27 Å. The C(14)-O(6) bond length is 1.27 Å. In the second C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(2), and one H(11) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-N(2) bond length is 1.35 Å. The C(15)-H(11) bond length is 1.08 Å. In the third C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one H(12) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(12) bond length is 1.08 Å. In the fourth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(1), and one H(13) atom. The C(17)-N(1) bond length is 1.35 Å. The C(17)-H(13) bond length is 1.08 Å. In the fifth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(4), and one H(14) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-N(4) bond length is 1.35 Å. The C(18)-H(14) bond length is 1.08 Å. In the sixth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(15) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(15) bond length is 1.08 Å. In the seventh C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(3), and one H(16) atom. The C(20)-N(3) bond length is 1.35 Å. The C(20)-H(16) bond length is 1.08 Å. In the eighth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(17) atom. The C(21)-N(6) bond length is 1.35 Å. The C(21)-H(17) bond length is 1.09 Å. In the ninth C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(18) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(18) bond length is 1.08 Å. In the tenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one N(5), and one H(19) atom. The C(23)-N(5) bond length is 1.35 Å. The C(23)-H(19) bond length is 1.08 Å. In the eleventh C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.26 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(17), and one N(2) atom. The N(1)-N(2) bond length is 1.35 Å. In the second N site, N(2) is bonded in a 2-coordinate geometry to one C(15), one N(1), and one H(20) atom. The N(2)-H(20) bond length is 1.03 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(20), and one N(4) atom. The N(3)-N(4) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a 2-coordinate geometry to one C(18), one N(3), and one H(21) atom. The N(4)-H(21) bond length is 1.06 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(23), and one N(6) atom. The N(5)-N(6) bond length is 1.35 Å. In the sixth N site, N(6) is bonded in a 2-coordinate geometry to one C(21), one N(5), and one H(22) atom. The N(6)-H(22) bond length is 1.06 Å. There are twelve inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one N(2) atom. In the eleventh H site, H(21) is bonded in a linear geometry to one N(4) and one O(5) atom. The H(21)-O(5) bond length is 1.63 Å. In the twelfth H site, H(22) is bonded in a distorted linear geometry to one N(6) and one O(2) atom. The H(22)-O(2) bond length is 1.64 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(1) and one H(22) atom. In the third O site, O(5) is bonded in a water-like geometry to one C(14) and one H(21) atom. In the fourth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(14) atom. Linkers: 4 [O]C(=O)COc1cc2ccccc2cc1OCC([O])=O. Metal clusters: 4 [Zn]. The MOF has largest included sphere 4.95 A, density 1.29 g/cm3, surface area 5002.27 m2/g, accessible volume 0.26 cm3/g