AgC24P3H23(SO)2(CH)10CH3CH2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of twenty 02329_fluka molecules, two 02329_fluka molecules, two 02329_fluka molecules, and two AgC24P3H23(SO)2 clusters. In each AgC24P3H23(SO)2 cluster, Ag(1) is bonded to one P(1), one P(2), one S(1), and one S(2) atom to form AgP2S2 tetrahedra that share  an edgeedge with one P(3)CS2O tetrahedra. The Ag(1)-P(1) bond length is 2.44 Å. The Ag(1)-P(2) bond length is 2.40 Å. The Ag(1)-S(1) bond length is 2.63 Å. The Ag(1)-S(2) bond length is 2.65 Å. There are twenty-four inequivalent C sites. In the first C site, C(24) is bonded in a distorted single-bond geometry to one C(19) and one H(20) atom. The C(24)-C(19) bond length is 1.41 Å. The C(24)-H(20) bond length is 1.09 Å. In the second C site, C(25) is bonded in a distorted trigonal non-coplanar geometry to one H(21), one H(22), and one O(1) atom. The C(25)-H(21) bond length is 1.10 Å. The C(25)-H(22) bond length is 1.10 Å. The C(25)-O(1) bond length is 1.45 Å. In the third C site, C(27) is bonded in a trigonal planar geometry to one C(28), one C(32), and one P(3) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-C(32) bond length is 1.40 Å. The C(27)-P(3) bond length is 1.81 Å. In the fourth C site, C(28) is bonded in a distorted single-bond geometry to one C(27), one C(29), and one H(26) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-H(26) bond length is 1.09 Å. In the fifth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one C(30), and one H(27) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-H(27) bond length is 1.09 Å. In the sixth C site, C(30) is bonded in a distorted single-bond geometry to one C(29), one C(31), and one O(2) atom. The C(30)-C(31) bond length is 1.41 Å. The C(30)-O(2) bond length is 1.37 Å. In the seventh C site, C(31) is bonded in a distorted trigonal planar geometry to one C(30), one C(32), and one H(28) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-H(28) bond length is 1.09 Å. In the eighth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(27), one C(31), and one H(29) atom. The C(32)-H(29) bond length is 1.09 Å. In the ninth C site, C(33) is bonded in a distorted water-like geometry to one P(1), one H(30), and one H(31) atom. The C(33)-P(1) bond length is 1.84 Å. The C(33)-H(30) bond length is 1.10 Å. The C(33)-H(31) bond length is 1.10 Å. In the tenth C site, C(35) is bonded in a distorted water-like geometry to one P(2), one H(34), and one H(35) atom. The C(35)-P(2) bond length is 1.84 Å. The C(35)-H(34) bond length is 1.10 Å. The C(35)-H(35) bond length is 1.10 Å. In the eleventh C site, C(36) is bonded in a tetrahedral geometry to one H(36), one H(37), one H(38), and one O(2) atom. The C(36)-H(36) bond length is 1.10 Å. The C(36)-H(37) bond length is 1.10 Å. The C(36)-H(38) bond length is 1.10 Å. The C(36)-O(2) bond length is 1.43 Å. In the twelfth C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one P(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-P(1) bond length is 1.82 Å. In the thirteenth C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the fourteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the fifteenth C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(8), and one P(1) atom. The C(7)-C(12) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.40 Å. The C(7)-P(1) bond length is 1.82 Å. In the sixteenth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(6) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(6) bond length is 1.09 Å. In the seventeenth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(7) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(7) bond length is 1.09 Å. In the eighteenth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(10)-H(8) bond length is 1.09 Å. In the nineteenth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(10) atom. The C(12)-H(10) bond length is 1.09 Å. In the twentieth C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(17), and one P(2) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(17) bond length is 1.40 Å. The C(13)-P(2) bond length is 1.82 Å. In the twenty-first C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(14)-H(11) bond length is 1.09 Å. In the twenty-second C site, C(17) is bonded in a distorted single-bond geometry to one C(13) and one H(14) atom. The C(17)-H(14) bond length is 1.09 Å. In the twenty-third C site, C(19) is bonded in a trigonal planar geometry to one C(20), one C(24), and one P(2) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-P(2) bond length is 1.82 Å. In the twenty-fourth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(16) atom. The C(20)-H(16) bond length is 1.09 Å. There are three inequivalent P sites. In the first P site, P(1) is bonded to one Ag(1), one C(1), one C(33), and one C(7) atom to form distorted corner-sharing PAgC3 tetrahedra. In the second P site, P(2) is bonded to one Ag(1), one C(13), one C(19), and one C(35) atom to form distorted corner-sharing PAgC3 tetrahedra. In the third P site, P(3) is bonded to one C(27), one S(1), one S(2), and one O(1) atom to form distorted PCS2O tetrahedra that share  an edgeedge with one Ag(1)P2S2 tetrahedra. The P(3)-S(1) bond length is 2.01 Å. The P(3)-S(2) bond length is 2.00 Å. The P(3)-O(1) bond length is 1.63 Å. There are twenty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(26) is bonded in a single-bond geometry to one C(28) atom. In the fourteenth H site, H(27) is bonded in a single-bond geometry to one C(29) atom. In the fifteenth H site, H(28) is bonded in a single-bond geometry to one C(31) atom. In the sixteenth H site, H(29) is bonded in a single-bond geometry to one C(32) atom. In the seventeenth H site, H(30) is bonded in a single-bond geometry to one C(33) atom. In the eighteenth H site, H(31) is bonded in a single-bond geometry to one C(33) atom. In the nineteenth H site, H(34) is bonded in a single-bond geometry to one C(35) atom. In the twentieth H site, H(35) is bonded in a single-bond geometry to one C(35) atom. In the twenty-first H site, H(36) is bonded in a single-bond geometry to one C(36) atom. In the twenty-second H site, H(37) is bonded in a single-bond geometry to one C(36) atom. In the twenty-third H site, H(38) is bonded in a single-bond geometry to one C(36) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Ag(1) and one P(3) atom. In the second S site, S(2) is bonded in a distorted L-shaped geometry to one Ag(1) and one P(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(25) and one P(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(30) and one C(36) atom. Linkers: 1 c1ccc(P(CCCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1 ,1 c1ccc([P]CCCP(c2ccccc2)c2ccccc2)cc1 ,1 CCO[P]([S])([S])c1ccc(OC)cc1 ,1 [CH]=[C]P(CCCP(c1ccccc1)c1ccccc1)c1ccccc1. Metal clusters: 1 [Ag]. The MOF has largest included sphere 3.78 A, density 1.38 g/cm3, surface area 5086.60 m2/g, accessible volume 0.22 cm3/g