CdC14N7H9S2 crystallizes in the triclinic P-1 space group. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(3), and two equivalent S(1) atoms. Both Cd(1)-N(2) bond lengths are 2.29 Å. Both Cd(1)-N(3) bond lengths are 2.38 Å. Both Cd(1)-S(1) bond lengths are 2.79 Å. In the second Cd site, Cd(2) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(4), and two equivalent S(2) atoms. Both Cd(2)-N(1) bond lengths are 2.29 Å. Both Cd(2)-N(4) bond lengths are 2.38 Å. Both Cd(2)-S(2) bond lengths are 2.79 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.63 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(2) atom. The C(2)-N(2) bond length is 1.18 Å. The C(2)-S(2) bond length is 1.63 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one N(3) and one H(2) atom. The C(3)-N(3) bond length is 1.35 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(6), one N(4), and one H(3) atom. The C(4)-C(6) bond length is 1.39 Å. The C(4)-N(4) bond length is 1.35 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(5)-C(7) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one H(5) atom. The C(6)-C(8) bond length is 1.40 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(13,14); one C(5); and one C(9,10) atom. The C(7)-C(13,14) bond length is 1.45 Å. The C(7)-C(9,10) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13,14); one C(6); and one C(9,10) atom. The C(8)-C(13,14) bond length is 1.45 Å. The C(8)-C(9,10) bond length is 1.40 Å. In the ninth C site, C(9,10) is bonded in a distorted trigonal planar geometry to one C(11), one C(7), and one H(6) atom. The C(9,10)-C(11) bond length is 1.39 Å. The C(9,10)-H(6) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(9,10); one N(3); and one H(8,9) atom. The C(11)-N(3) bond length is 1.34 Å. The C(11)-H(8,9) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(9,10); one N(4); and one H(8,9) atom. The C(12)-C(9,10) bond length is 1.39 Å. The C(12)-N(4) bond length is 1.34 Å. The C(12)-H(8,9) bond length is 1.09 Å. In the twelfth C site, C(13,14) is bonded in a distorted water-like geometry to one C(7); one N(5,6); and one N(7) atom. The C(13,14)-N(5,6) bond length is 1.34 Å. The C(13,14)-N(7) bond length is 1.37 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Cd(2) and one C(1) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(2), one C(12), and one C(4) atom. In the fifth N site, N(5,6) is bonded in a distorted single-bond geometry to one C(13,14) atom. In the sixth N site, N(7) is bonded in a trigonal planar geometry to two equivalent C(13,14) and one H(1) atom. The N(7)-H(1) bond length is 1.01 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9,10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9,10) atom. The H(7)-C(9,10) bond length is 1.09 Å. In the eighth H site, H(8,9) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Cd(2) and one C(2) atom. Linkers: 2 c1cc(-c2nnc(-c3ccncc3)[nH]2)ccn1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 4.11 A, density 1.58 g/cm3, surface area 3945.26 m2/g, accessible volume 0.20 cm3/g