(CH)2CuC12H9SI(NO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one CuC12H9SI(NO)2 cluster. In the CuC12H9SI(NO)2 cluster, Cu(1) is bonded in a 5-coordinate geometry to one N(1), one H(11), one S(1), and two equivalent I(1) atoms. The Cu(1)-N(1) bond length is 2.06 Å. The Cu(1)-H(11) bond length is 2.27 Å. The Cu(1)-S(1) bond length is 2.29 Å. There is one shorter (2.61 Å) and one longer (2.63 Å) Cu(1)-I(1) bond length. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one H(1), one H(2), and one S(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.83 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(3), one C(7), and one S(1) atom. The C(2)-C(3) bond length is 1.42 Å. The C(2)-C(7) bond length is 1.40 Å. The C(2)-S(1) bond length is 1.77 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(1) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-N(1) bond length is 1.43 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(1), and one H(7) atom. The C(8)-C(9) bond length is 1.45 Å. The C(8)-N(1) bond length is 1.31 Å. The C(8)-H(7) bond length is 1.10 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(14) bond length is 1.41 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(8) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(8) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(9) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(9) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one N(2) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-N(2) bond length is 1.46 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(13)-H(10) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(11) atom. The C(14)-H(11) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(12), one O(1), and one O(2) atom. The N(2)-O(1) bond length is 1.24 Å. The N(2)-O(2) bond length is 1.25 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one Cu(1) and one C(14) atom. S(1) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(1), and one C(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(2) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 1 O=[N+]([O-])c1ccc(/C=N/c2ccccc2SCCSc2ccccc2/N=C/c2ccc([N+](=O)[O-])cc2)cc1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.80 A, density 2.10 g/cm3, surface area 3303.81 m2/g, accessible volume 0.09 cm3/g