ZnC4H4(NBr)2(C5H5NO)2 is Indium-derived structured and crystallizes in the orthorhombic Pnna space group. The structure is zero-dimensional and consists of eight n-(2-methyl-2-propenyl)formamide molecules and four ZnC4H4(NBr)2 clusters. In each ZnC4H4(NBr)2 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent Br(1) atoms. Both Zn(1)-N(1) bond lengths are 2.05 Å. Both Zn(1)-Br(1) bond lengths are 2.38 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(5) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. There are two inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. Br(1) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 4 O=C(NCc1ccncc1)C(=O)NCc1ccncc1. Metal clusters: 4 Br[Zn]Br. The MOF has largest included sphere 5.49 A, density 1.58 g/cm3, surface area 4055.30 m2/g, accessible volume 0.20 cm3/g