(CH)2(CH2)4ZnC6H14S2(NO4)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, twelve 02329_fluka molecules, and one ZnC6H14S2(NO4)2 cluster. In the ZnC6H14S2(NO4)2 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one O(1), one O(10), one O(2), and one O(5) atom. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(10) bond length is 1.96 Å. The Zn(1)-O(2) bond length is 1.97 Å. The Zn(1)-O(5) bond length is 1.96 Å. In the second Zn site, Zn(2) is bonded in an octahedral geometry to two equivalent O(11), two equivalent O(12), and two equivalent O(4) atoms. Both Zn(2)-O(11) bond lengths are 2.07 Å. Both Zn(2)-O(12) bond lengths are 2.07 Å. Both Zn(2)-O(4) bond lengths are 2.22 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one H(1), and one O(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-O(1) bond length is 1.27 Å. In the second C site, C(2) is bonded to one N(1), one H(2), one H(3), and one H(4) atom to form corner-sharing CH3N tetrahedra. The C(2)-N(1) bond length is 1.46 Å. The C(2)-H(2) bond length is 1.10 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. In the third C site, C(3) is bonded to one N(1), one H(5), one H(6), and one H(7) atom to form corner-sharing CH3N tetrahedra. The C(3)-N(1) bond length is 1.46 Å. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(6) bond length is 1.10 Å. The C(3)-H(7) bond length is 1.09 Å. In the fourth C site, C(13) is bonded in a trigonal planar geometry to one N(2), one H(23), and one O(11) atom. The C(13)-N(2) bond length is 1.33 Å. The C(13)-H(23) bond length is 1.10 Å. The C(13)-O(11) bond length is 1.26 Å. In the fifth C site, C(14) is bonded to one N(2), one H(24), one H(25), and one H(26) atom to form corner-sharing CH3N tetrahedra. The C(14)-N(2) bond length is 1.46 Å. The C(14)-H(24) bond length is 1.10 Å. The C(14)-H(25) bond length is 1.09 Å. The C(14)-H(26) bond length is 1.10 Å. In the sixth C site, C(15) is bonded to one N(2), one H(27), one H(28), and one H(29) atom to form corner-sharing CH3N tetrahedra. The C(15)-N(2) bond length is 1.46 Å. The C(15)-H(27) bond length is 1.09 Å. The C(15)-H(28) bond length is 1.10 Å. The C(15)-H(29) bond length is 1.10 Å. In the seventh C site, C(16) is bonded in a trigonal planar geometry to one N(3), one H(30), and one O(12) atom. The C(16)-N(3) bond length is 1.33 Å. The C(16)-H(30) bond length is 1.10 Å. The C(16)-O(12) bond length is 1.26 Å. In the eighth C site, C(17) is bonded to one N(3), one H(31), one H(32), and one H(33) atom to form corner-sharing CH3N tetrahedra. The C(17)-N(3) bond length is 1.45 Å. The C(17)-H(31) bond length is 1.10 Å. The C(17)-H(32) bond length is 1.09 Å. The C(17)-H(33) bond length is 1.10 Å. In the ninth C site, C(18) is bonded to one N(3), one H(34), one H(35), and one H(36) atom to form corner-sharing CH3N tetrahedra. The C(18)-N(3) bond length is 1.46 Å. The C(18)-H(34) bond length is 1.10 Å. The C(18)-H(35) bond length is 1.09 Å. The C(18)-H(36) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(15) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(16), one C(17), and one C(18) atom. There are twenty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(24) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(25) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(26) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(27) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(28) is bonded in a single-bond geometry to one C(15) atom. In the fourteenth H site, H(29) is bonded in a single-bond geometry to one C(15) atom. In the fifteenth H site, H(30) is bonded in a single-bond geometry to one C(16) atom. In the sixteenth H site, H(31) is bonded in a single-bond geometry to one C(17) atom. In the seventeenth H site, H(32) is bonded in a single-bond geometry to one C(17) atom. In the eighteenth H site, H(33) is bonded in a single-bond geometry to one C(17) atom. In the nineteenth H site, H(34) is bonded in a single-bond geometry to one C(18) atom. In the twentieth H site, H(35) is bonded in a single-bond geometry to one C(18) atom. In the twenty-first H site, H(36) is bonded in a single-bond geometry to one C(18) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(2), one O(3), and one O(4) atom. The S(1)-O(2) bond length is 1.50 Å. The S(1)-O(3) bond length is 1.46 Å. The S(1)-O(4) bond length is 1.48 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one O(5), one O(6), and one O(7) atom. The S(2)-O(5) bond length is 1.51 Å. The S(2)-O(6) bond length is 1.46 Å. The S(2)-O(7) bond length is 1.46 Å. In the third S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to one O(10), one O(8), and one O(9) atom. The S(3)-O(10) bond length is 1.52 Å. The S(3)-O(8) bond length is 1.46 Å. The S(3)-O(9) bond length is 1.46 Å. There are twelve inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one S(1) atom. In the second O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one S(2) atom. In the third O site, O(6) is bonded in a single-bond geometry to one S(2) atom. In the fourth O site, O(7) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(8) is bonded in a single-bond geometry to one S(3) atom. In the sixth O site, O(9) is bonded in a single-bond geometry to one S(3) atom. In the seventh O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(1) and one S(3) atom. In the eighth O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(13) atom. In the ninth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(16) atom. In the tenth O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the eleventh O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one S(1) atom. In the twelfth O site, O(3) is bonded in a single-bond geometry to one S(1) atom. Linkers: 1 [O]S([O])([O])[C@H]1CC[C@H](S([O])([O])[O])CC1. Metal clusters: 3 [Zn]. The MOF has largest included sphere 2.19 A, density 1.63 g/cm3, surface area 4794.22 m2/g, accessible volume 0.16 cm3/g