MnC6H12(N6O)2(CH2)2 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a MnC6H12(N6O)2 framework. In the MnC6H12(N6O)2 framework, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in an octahedral geometry to two equivalent N(5), two equivalent N(7), and two equivalent O(1) atoms. Both Mn(1)-N(5) bond lengths are 2.03 Å. Both Mn(1)-N(7) bond lengths are 2.02 Å. Both Mn(1)-O(1) bond lengths are 2.06 Å. In the second Mn site, Mn(2) is bonded in an octahedral geometry to two equivalent N(6), two equivalent N(8), and two equivalent O(2) atoms. Both Mn(2)-N(6) bond lengths are 2.27 Å. Both Mn(2)-N(8) bond lengths are 2.15 Å. Both Mn(2)-O(2) bond lengths are 2.20 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(3), one N(5), and one H(1) atom. The C(1)-N(3) bond length is 1.33 Å. The C(1)-N(5) bond length is 1.37 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(2) atom. The C(2)-N(4) bond length is 1.33 Å. The C(2)-N(6) bond length is 1.36 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(5), and one H(3) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-N(5) bond length is 1.35 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(2), one N(6), and one H(4) atom. The C(4)-N(2) bond length is 1.34 Å. The C(4)-N(6) bond length is 1.34 Å. The C(4)-H(4) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(5), and one H(7) atom. The C(5)-N(1) bond length is 1.46 Å. The C(5)-H(5) bond length is 1.10 Å. The C(5)-H(7) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(6), and one H(8) atom. The C(6)-N(2) bond length is 1.46 Å. The C(6)-H(6) bond length is 1.10 Å. The C(6)-H(8) bond length is 1.10 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(3) atom. The N(1)-N(3) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(4) atom. The N(2)-N(4) bond length is 1.36 Å. In the third N site, N(3) is bonded in a distorted single-bond geometry to one C(1), one N(1), and one H(16) atom. The N(3)-H(16) bond length is 1.77 Å. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one C(2), one N(2), and one H(15) atom. The N(4)-H(15) bond length is 1.74 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Mn(1), one C(1), and one C(3) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Mn(2), one C(2), and one C(4) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Mn(1), one N(9), and one H(13) atom. The N(7)-N(9) bond length is 1.21 Å. The N(7)-H(13) bond length is 1.77 Å. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Mn(2), one N(10), and one H(14) atom. The N(8)-N(10) bond length is 1.20 Å. The N(8)-H(14) bond length is 1.74 Å. In the ninth N site, N(9) is bonded in a linear geometry to one N(11) and one N(7) atom. The N(9)-N(11) bond length is 1.17 Å. In the tenth N site, N(10) is bonded in a linear geometry to one N(12) and one N(8) atom. The N(10)-N(12) bond length is 1.17 Å. In the eleventh N site, N(11) is bonded in a single-bond geometry to one N(9) atom. In the twelfth N site, N(12) is bonded in a single-bond geometry to one N(10) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one N(7) and one O(1) atom. The H(13)-O(1) bond length is 1.00 Å. In the tenth H site, H(14) is bonded in a single-bond geometry to one N(8) and one O(2) atom. The H(14)-O(2) bond length is 1.00 Å. In the eleventh H site, H(15) is bonded in a single-bond geometry to one N(4) and one O(1) atom. The H(15)-O(1) bond length is 1.00 Å. In the twelfth H site, H(16) is bonded in a single-bond geometry to one N(3) and one O(2) atom. The H(16)-O(2) bond length is 1.00 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Mn(1), one H(13), and one H(15) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Mn(2), one H(14), and one H(16) atom. Linkers: 1 [CH]1N=C[N]N1CCCCN1[CH]N=C[N]1 ,1 [CH]1N=C[N]N1CCCCn1cncn1. Metal clusters: 2 [Mn]. The MOF has largest included sphere 1.63 A, density 1.66 g/cm3, surface area 4568.79 m2/g, accessible volume 0.13 cm3/g