Mn2C19H15(NO5)3 crystallizes in the triclinic P1 space group. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(13), one O(18), one O(27), one O(31), one O(33), and one O(53) atom. The Mn(1)-O(13) bond length is 2.06 Å. The Mn(1)-O(18) bond length is 2.24 Å. The Mn(1)-O(27) bond length is 2.40 Å. The Mn(1)-O(31) bond length is 2.26 Å. The Mn(1)-O(33) bond length is 2.13 Å. The Mn(1)-O(53) bond length is 2.12 Å. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(14), one O(17), one O(28), one O(32), one O(34), and one O(54) atom. The Mn(2)-O(14) bond length is 2.06 Å. The Mn(2)-O(17) bond length is 2.23 Å. The Mn(2)-O(28) bond length is 2.39 Å. The Mn(2)-O(32) bond length is 2.27 Å. The Mn(2)-O(34) bond length is 2.12 Å. The Mn(2)-O(54) bond length is 2.12 Å. In the third Mn site, Mn(3) is bonded in a 6-coordinate geometry to one O(15), one O(20), one O(25), one O(29), one O(35), and one O(55) atom. The Mn(3)-O(15) bond length is 2.06 Å. The Mn(3)-O(20) bond length is 2.23 Å. The Mn(3)-O(25) bond length is 2.39 Å. The Mn(3)-O(29) bond length is 2.27 Å. The Mn(3)-O(35) bond length is 2.12 Å. The Mn(3)-O(55) bond length is 2.12 Å. In the fourth Mn site, Mn(4) is bonded in a 6-coordinate geometry to one O(16), one O(19), one O(26), one O(30), one O(36), and one O(56) atom. The Mn(4)-O(16) bond length is 2.06 Å. The Mn(4)-O(19) bond length is 2.23 Å. The Mn(4)-O(26) bond length is 2.41 Å. The Mn(4)-O(30) bond length is 2.26 Å. The Mn(4)-O(36) bond length is 2.12 Å. The Mn(4)-O(56) bond length is 2.12 Å. In the fifth Mn site, Mn(5) is bonded in an octahedral geometry to one O(19), one O(27), one O(40), one O(45), one O(49), and one O(9) atom. The Mn(5)-O(19) bond length is 2.21 Å. The Mn(5)-O(27) bond length is 2.12 Å. The Mn(5)-O(40) bond length is 2.08 Å. The Mn(5)-O(45) bond length is 2.13 Å. The Mn(5)-O(49) bond length is 2.21 Å. The Mn(5)-O(9) bond length is 2.21 Å. In the sixth Mn site, Mn(6) is bonded in an octahedral geometry to one O(10), one O(20), one O(28), one O(39), one O(46), and one O(50) atom. The Mn(6)-O(10) bond length is 2.21 Å. The Mn(6)-O(20) bond length is 2.21 Å. The Mn(6)-O(28) bond length is 2.12 Å. The Mn(6)-O(39) bond length is 2.07 Å. The Mn(6)-O(46) bond length is 2.13 Å. The Mn(6)-O(50) bond length is 2.21 Å. In the seventh Mn site, Mn(7) is bonded in an octahedral geometry to one O(11), one O(17), one O(25), one O(38), one O(47), and one O(51) atom. The Mn(7)-O(11) bond length is 2.21 Å. The Mn(7)-O(17) bond length is 2.21 Å. The Mn(7)-O(25) bond length is 2.12 Å. The Mn(7)-O(38) bond length is 2.07 Å. The Mn(7)-O(47) bond length is 2.13 Å. The Mn(7)-O(51) bond length is 2.21 Å. In the eighth Mn site, Mn(8) is bonded in an octahedral geometry to one O(12), one O(18), one O(26), one O(37), one O(48), and one O(52) atom. The Mn(8)-O(12) bond length is 2.21 Å. The Mn(8)-O(18) bond length is 2.22 Å. The Mn(8)-O(26) bond length is 2.12 Å. The Mn(8)-O(37) bond length is 2.08 Å. The Mn(8)-O(48) bond length is 2.13 Å. The Mn(8)-O(52) bond length is 2.21 Å. There are fifty-two inequivalent C sites. In the first C site, C(1,2,3,4) is bonded in a distorted trigonal planar geometry to one C(21,22,24); one C(5,6,7); and one N(1,2,3,4) atom. The C(1,2,3,4)-C(21,22,24) bond length is 1.41 Å. The C(1,2,3,4)-C(5,6,7) bond length is 1.39 Å. The C(1,2,3,4)-N(1,2,3,4) bond length is 1.47 Å. In the second C site, C(5,6,7) is bonded in a distorted single-bond geometry to one C(1,2,3,4); one C(9); and one H(1,2,3,4) atom. The C(5,6,7)-C(9) bond length is 1.39 Å. The C(5,6,7)-H(1,2,3,4) bond length is 1.09 Å. In the third C site, C(8) is bonded in a distorted single-bond geometry to one C(1,2,3,4); one C(12); and one H(1,2,3,4) atom. The C(8)-C(1,2,3,4) bond length is 1.39 Å. The C(8)-C(12) bond length is 1.39 Å. The C(8)-H(1,2,3,4) bond length is 1.09 Å. In the fourth C site, C(9) is bonded in a trigonal planar geometry to one C(13,14); one C(49); and one C(5,6,7) atom. The C(9)-C(13,14) bond length is 1.40 Å. The C(9)-C(49) bond length is 1.49 Å. In the fifth C site, C(10) is bonded in a trigonal planar geometry to one C(13,14); one C(5,6,7); and one C(50) atom. The C(10)-C(13,14) bond length is 1.40 Å. The C(10)-C(5,6,7) bond length is 1.39 Å. The C(10)-C(50) bond length is 1.49 Å. In the sixth C site, C(11) is bonded in a trigonal planar geometry to one C(15); one C(5,6,7); and one C(51) atom. The C(11)-C(15) bond length is 1.40 Å. The C(11)-C(5,6,7) bond length is 1.39 Å. The C(11)-C(51) bond length is 1.49 Å. In the seventh C site, C(12) is bonded in a trigonal planar geometry to one C(16), one C(52), and one C(8) atom. The C(12)-C(16) bond length is 1.40 Å. The C(12)-C(52) bond length is 1.49 Å. In the eighth C site, C(13,14) is bonded in a distorted single-bond geometry to one C(17); one C(9); and one H(5,6,7,8) atom. The C(13,14)-C(17) bond length is 1.40 Å. The C(13,14)-H(5,6,7,8) bond length is 1.09 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(11); one C(19); and one H(5,6,7,8) atom. The C(15)-C(19) bond length is 1.40 Å. The C(15)-H(5,6,7,8) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(12); one C(20); and one H(5,6,7,8) atom. The C(16)-C(20) bond length is 1.40 Å. The C(16)-H(5,6,7,8) bond length is 1.09 Å. In the eleventh C site, C(17) is bonded in a trigonal planar geometry to one C(13,14); one C(21,22,24); and one C(53,56) atom. The C(17)-C(21,22,24) bond length is 1.41 Å. The C(17)-C(53,56) bond length is 1.50 Å. In the twelfth C site, C(18) is bonded in a trigonal planar geometry to one C(13,14); one C(21,22,24); and one C(54) atom. The C(18)-C(13,14) bond length is 1.40 Å. The C(18)-C(21,22,24) bond length is 1.41 Å. The C(18)-C(54) bond length is 1.51 Å. In the thirteenth C site, C(19) is bonded in a trigonal planar geometry to one C(15), one C(23), and one C(55) atom. The C(19)-C(23) bond length is 1.41 Å. The C(19)-C(55) bond length is 1.50 Å. In the fourteenth C site, C(20) is bonded in a trigonal planar geometry to one C(16); one C(21,22,24); and one C(53,56) atom. The C(20)-C(21,22,24) bond length is 1.41 Å. The C(20)-C(53,56) bond length is 1.50 Å. In the fifteenth C site, C(21,22,24) is bonded in a trigonal planar geometry to one C(1,2,3,4); one C(17); and one C(25,26) atom. The C(21,22,24)-C(25,26) bond length is 1.49 Å. In the sixteenth C site, C(23) is bonded in a trigonal planar geometry to one C(1,2,3,4); one C(19); and one C(27) atom. The C(23)-C(1,2,3,4) bond length is 1.41 Å. The C(23)-C(27) bond length is 1.49 Å. In the seventeenth C site, C(25,26) is bonded in a trigonal planar geometry to one C(21,22,24); one C(29,31,32); and one C(45,47,48) atom. The C(25,26)-C(29,31,32) bond length is 1.41 Å. The C(25,26)-C(45,47,48) bond length is 1.40 Å. In the eighteenth C site, C(27) is bonded in a trigonal planar geometry to one C(23); one C(29,31,32); and one C(45,47,48) atom. The C(27)-C(29,31,32) bond length is 1.41 Å. The C(27)-C(45,47,48) bond length is 1.40 Å. In the nineteenth C site, C(28) is bonded in a trigonal planar geometry to one C(21,22,24); one C(29,31,32); and one C(45,47,48) atom. The C(28)-C(21,22,24) bond length is 1.49 Å. The C(28)-C(29,31,32) bond length is 1.41 Å. The C(28)-C(45,47,48) bond length is 1.40 Å. In the twentieth C site, C(29,31,32) is bonded in a trigonal planar geometry to one C(25,26); one C(33,34); and one C(57,60) atom. The C(29,31,32)-C(33,34) bond length is 1.40 Å. The C(29,31,32)-C(57,60) bond length is 1.50 Å. In the twenty-first C site, C(30) is bonded in a trigonal planar geometry to one C(25,26); one C(33,34); and one C(58) atom. The C(30)-C(25,26) bond length is 1.41 Å. The C(30)-C(33,34) bond length is 1.40 Å. The C(30)-C(58) bond length is 1.50 Å. In the twenty-second C site, C(33,34) is bonded in a distorted single-bond geometry to one C(29,31,32); one C(37); and one H(9,11,12) atom. The C(33,34)-C(37) bond length is 1.40 Å. The C(33,34)-H(9,11,12) bond length is 1.09 Å. In the twenty-third C site, C(35) is bonded in a distorted single-bond geometry to one C(29,31,32); one C(39); and one H(9,11,12) atom. The C(35)-C(29,31,32) bond length is 1.40 Å. The C(35)-C(39) bond length is 1.40 Å. The C(35)-H(9,11,12) bond length is 1.09 Å. In the twenty-fourth C site, C(36) is bonded in a distorted single-bond geometry to one C(29,31,32); one C(40); and one H(9,11,12) atom. The C(36)-C(29,31,32) bond length is 1.40 Å. The C(36)-C(40) bond length is 1.40 Å. The C(36)-H(9,11,12) bond length is 1.09 Å. In the twenty-fifth C site, C(37) is bonded in a trigonal planar geometry to one C(33,34); one C(41,42); and one C(61) atom. The C(37)-C(41,42) bond length is 1.40 Å. The C(37)-C(61) bond length is 1.49 Å. In the twenty-sixth C site, C(38) is bonded in a trigonal planar geometry to one C(33,34); one C(41,42); and one C(62) atom. The C(38)-C(33,34) bond length is 1.40 Å. The C(38)-C(41,42) bond length is 1.40 Å. The C(38)-C(62) bond length is 1.49 Å. In the twenty-seventh C site, C(39) is bonded in a trigonal planar geometry to one C(35), one C(43), and one C(63) atom. The C(39)-C(43) bond length is 1.40 Å. The C(39)-C(63) bond length is 1.49 Å. In the twenty-eighth C site, C(40) is bonded in a trigonal planar geometry to one C(36), one C(44), and one C(64) atom. The C(40)-C(44) bond length is 1.40 Å. The C(40)-C(64) bond length is 1.49 Å. In the twenty-ninth C site, C(41,42) is bonded in a distorted trigonal planar geometry to one C(37); one C(45,47,48); and one H(13,15,16) atom. The C(41,42)-C(45,47,48) bond length is 1.39 Å. The C(41,42)-H(13,15,16) bond length is 1.09 Å. In the thirtieth C site, C(43) is bonded in a distorted trigonal planar geometry to one C(39); one C(45,47,48); and one H(13,15,16) atom. The C(43)-C(45,47,48) bond length is 1.39 Å. The C(43)-H(13,15,16) bond length is 1.09 Å. In the thirty-first C site, C(44) is bonded in a distorted trigonal planar geometry to one C(40); one C(45,47,48); and one H(13,15,16) atom. The C(44)-C(45,47,48) bond length is 1.39 Å. The C(44)-H(13,15,16) bond length is 1.09 Å. In the thirty-second C site, C(45,47,48) is bonded in a distorted trigonal planar geometry to one C(25,26); one C(41,42); and one N(5,6,7) atom. The C(45,47,48)-N(5,6,7) bond length is 1.47 Å. In the thirty-third C site, C(46) is bonded in a distorted trigonal planar geometry to one C(25,26); one C(41,42); and one N(5,6,7) atom. The C(46)-C(25,26) bond length is 1.40 Å. The C(46)-C(41,42) bond length is 1.39 Å. The C(46)-N(5,6,7) bond length is 1.47 Å. In the thirty-fourth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(13), and one O(9) atom. The C(49)-O(13) bond length is 1.27 Å. The C(49)-O(9) bond length is 1.28 Å. In the thirty-fifth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(10), and one O(14) atom. The C(50)-O(10) bond length is 1.28 Å. The C(50)-O(14) bond length is 1.27 Å. In the thirty-sixth C site, C(51) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(11), and one O(15) atom. The C(51)-O(11) bond length is 1.28 Å. The C(51)-O(15) bond length is 1.27 Å. In the thirty-seventh C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(12), and one O(16) atom. The C(52)-O(12) bond length is 1.28 Å. The C(52)-O(16) bond length is 1.27 Å. In the thirty-eighth C site, C(53,56) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(17), and one O(21) atom. The C(53,56)-O(17) bond length is 1.31 Å. The C(53,56)-O(21) bond length is 1.25 Å. In the thirty-ninth C site, C(54) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(18), and one O(22) atom. The C(54)-O(18) bond length is 1.30 Å. The C(54)-O(22) bond length is 1.25 Å. In the fortieth C site, C(55) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(19), and one O(23) atom. The C(55)-O(19) bond length is 1.30 Å. The C(55)-O(23) bond length is 1.25 Å. In the forty-first C site, C(57,60) is bonded in a distorted bent 120 degrees geometry to one C(29,31,32); one O(25); and one O(29) atom. The C(57,60)-O(25) bond length is 1.28 Å. The C(57,60)-O(29) bond length is 1.26 Å. In the forty-second C site, C(58) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(26), and one O(30) atom. The C(58)-O(26) bond length is 1.28 Å. The C(58)-O(30) bond length is 1.26 Å. In the forty-third C site, C(59) is bonded in a distorted bent 120 degrees geometry to one C(29,31,32); one O(27); and one O(31) atom. The C(59)-C(29,31,32) bond length is 1.50 Å. The C(59)-O(27) bond length is 1.28 Å. The C(59)-O(31) bond length is 1.26 Å. In the forty-fourth C site, C(61) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(33), and one O(37) atom. The C(61)-O(33) bond length is 1.28 Å. The C(61)-O(37) bond length is 1.27 Å. In the forty-fifth C site, C(62) is bonded in a distorted bent 120 degrees geometry to one C(38), one O(34), and one O(38) atom. The C(62)-O(34) bond length is 1.28 Å. The C(62)-O(38) bond length is 1.27 Å. In the forty-sixth C site, C(63) is bonded in a distorted bent 120 degrees geometry to one C(39), one O(35), and one O(39) atom. The C(63)-O(35) bond length is 1.28 Å. The C(63)-O(39) bond length is 1.27 Å. In the forty-seventh C site, C(64) is bonded in a distorted bent 120 degrees geometry to one C(40), one O(36), and one O(40) atom. The C(64)-O(36) bond length is 1.28 Å. The C(64)-O(40) bond length is 1.27 Å. In the forty-eighth C site, C(65) is bonded in a trigonal planar geometry to one N(9), one H(33), and one O(45) atom. The C(65)-N(9) bond length is 1.33 Å. The C(65)-H(33) bond length is 1.10 Å. The C(65)-O(45) bond length is 1.26 Å. In the forty-ninth C site, C(66,67) is bonded in a trigonal planar geometry to one N(10), one H(34), and one O(46) atom. The C(66,67)-N(10) bond length is 1.33 Å. The C(66,67)-H(34) bond length is 1.10 Å. The C(66,67)-O(46) bond length is 1.26 Å. In the fiftieth C site, C(68) is bonded in a trigonal planar geometry to one N(12), one H(36), and one O(48) atom. The C(68)-N(12) bond length is 1.33 Å. The C(68)-H(36) bond length is 1.10 Å. The C(68)-O(48) bond length is 1.26 Å. In the fifty-first C site, C(69,70,71,72) is bonded to one N(9); one H(37,38,39,40); one H(41,42,43,44); and one H(45,46,47,48) atom to form corner-sharing CH3N tetrahedra. The C(69,70,71,72)-N(9) bond length is 1.46 Å. The C(69,70,71,72)-H(37,38,39,40) bond length is 1.10 Å. The C(69,70,71,72)-H(41,42,43,44) bond length is 1.10 Å. The C(69,70,71,72)-H(45,46,47,48) bond length is 1.09 Å. In the fifty-second C site, C(73,74,75,76) is bonded to one N(9); one H(49,50,51,52); one H(53,54,55,56); and one H(57,58,59,60) atom to form corner-sharing CH3N tetrahedra. The C(73,74,75,76)-N(9) bond length is 1.46 Å. The C(73,74,75,76)-H(49,50,51,52) bond length is 1.10 Å. The C(73,74,75,76)-H(53,54,55,56) bond length is 1.10 Å. The C(73,74,75,76)-H(57,58,59,60) bond length is 1.10 Å. There are seven inequivalent N sites. In the first N site, N(1,2,3,4) is bonded in a trigonal planar geometry to one C(1,2,3,4); one O(1,2,3,4); and one O(5,6,7,8) atom. The N(1,2,3,4)-O(1,2,3,4) bond length is 1.24 Å. The N(1,2,3,4)-O(5,6,7,8) bond length is 1.25 Å. In the second N site, N(5,6,7) is bonded in a trigonal planar geometry to one C(45,47,48); one O(41,42,43,44); and one O(57,58,59,60) atom. The N(5,6,7)-O(41,42,43,44) bond length is 1.24 Å. The N(5,6,7)-O(57,58,59,60) bond length is 1.24 Å. In the third N site, N(8) is bonded in a trigonal planar geometry to one C(45,47,48); one O(41,42,43,44); and one O(57,58,59,60) atom. The N(8)-C(45,47,48) bond length is 1.47 Å. The N(8)-O(41,42,43,44) bond length is 1.24 Å. The N(8)-O(57,58,59,60) bond length is 1.24 Å. In the fourth N site, N(9) is bonded in a trigonal planar geometry to one C(65); one C(69,70,71,72); and one C(73,74,75,76) atom. In the fifth N site, N(10) is bonded in a trigonal planar geometry to one C(66,67); one C(69,70,71,72); and one C(73,74,75,76) atom. The N(10)-C(69,70,71,72) bond length is 1.46 Å. The N(10)-C(73,74,75,76) bond length is 1.46 Å. In the sixth N site, N(11) is bonded in a trigonal planar geometry to one C(66,67); one C(69,70,71,72); and one C(73,74,75,76) atom. The N(11)-C(66,67) bond length is 1.33 Å. The N(11)-C(69,70,71,72) bond length is 1.46 Å. The N(11)-C(73,74,75,76) bond length is 1.46 Å. In the seventh N site, N(12) is bonded in a trigonal planar geometry to one C(68); one C(69,70,71,72); and one C(73,74,75,76) atom. The N(12)-C(69,70,71,72) bond length is 1.46 Å. The N(12)-C(73,74,75,76) bond length is 1.46 Å. There are thirty-one inequivalent H sites. In the first H site, H(1,2,3,4) is bonded in a single-bond geometry to one C(5,6,7) atom. In the second H site, H(5,6,7,8) is bonded in a single-bond geometry to one C(13,14) atom. In the third H site, H(9,11,12) is bonded in a single-bond geometry to one C(33,34) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(33,34) atom. The H(10)-C(33,34) bond length is 1.09 Å. In the fifth H site, H(13,15,16) is bonded in a single-bond geometry to one C(41,42) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(41,42) atom. The H(14)-C(41,42) bond length is 1.09 Å. In the seventh H site, H(17) is bonded in a single-bond geometry to one O(49) atom. The H(17)-O(49) bond length is 1.00 Å. In the eighth H site, H(18) is bonded in a single-bond geometry to one O(50) atom. The H(18)-O(50) bond length is 1.00 Å. In the ninth H site, H(19) is bonded in a single-bond geometry to one O(51) atom. The H(19)-O(51) bond length is 1.00 Å. In the tenth H site, H(20) is bonded in a single-bond geometry to one O(52) atom. The H(20)-O(52) bond length is 1.00 Å. In the eleventh H site, H(21) is bonded in a single-bond geometry to one O(49) atom. The H(21)-O(49) bond length is 0.98 Å. In the twelfth H site, H(22) is bonded in a single-bond geometry to one O(50) atom. The H(22)-O(50) bond length is 0.98 Å. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one O(51) atom. The H(23)-O(51) bond length is 0.98 Å. In the fourteenth H site, H(24) is bonded in a single-bond geometry to one O(52) atom. The H(24)-O(52) bond length is 0.98 Å. In the fifteenth H site, H(25) is bonded in a distorted single-bond geometry to one O(12) and one O(53) atom. The H(25)-O(12) bond length is 1.65 Å. The H(25)-O(53) bond length is 1.01 Å. In the sixteenth H site, H(26) is bonded in a distorted single-bond geometry to one O(11) and one O(54) atom. The H(26)-O(11) bond length is 1.65 Å. The H(26)-O(54) bond length is 1.01 Å. In the seventeenth H site, H(27) is bonded in a distorted single-bond geometry to one O(10) and one O(55) atom. The H(27)-O(10) bond length is 1.65 Å. The H(27)-O(55) bond length is 1.01 Å. In the eighteenth H site, H(28) is bonded in a distorted single-bond geometry to one O(56) and one O(9) atom. The H(28)-O(56) bond length is 1.01 Å. The H(28)-O(9) bond length is 1.65 Å. In the nineteenth H site, H(29,30) is bonded in a single-bond geometry to one O(53) atom. The H(29,30)-O(53) bond length is 0.97 Å. In the twentieth H site, H(31) is bonded in a single-bond geometry to one O(55) atom. The H(31)-O(55) bond length is 0.97 Å. In the twenty-first H site, H(32) is bonded in a single-bond geometry to one O(56) atom. The H(32)-O(56) bond length is 0.97 Å. In the twenty-second H site, H(33) is bonded in a single-bond geometry to one C(65) atom. In the twenty-third H site, H(34) is bonded in a single-bond geometry to one C(66,67) atom. In the twenty-fourth H site, H(35) is bonded in a single-bond geometry to one C(66,67) atom. The H(35)-C(66,67) bond length is 1.10 Å. In the twenty-fifth H site, H(36) is bonded in a single-bond geometry to one C(68) atom. In the twenty-sixth H site, H(37,38,39,40) is bonded in a single-bond geometry to one C(69,70,71,72) atom. In the twenty-seventh H site, H(41,42,43,44) is bonded in a single-bond geometry to one C(69,70,71,72) atom. In the twenty-eighth H site, H(45,46,47,48) is bonded in a single-bond geometry to one C(69,70,71,72) atom. In the twenty-ninth H site, H(49,50,51,52) is bonded in a single-bond geometry to one C(73,74,75,76) atom. In the thirtieth H site, H(53,54,55,56) is bonded in a single-bond geometry to one C(73,74,75,76) atom. In the thirty-first H site, H(57,58,59,60) is bonded in a single-bond geometry to one C(73,74,75,76) atom. There are forty-eight inequivalent O sites. In the first O site, O(1,2,3,4) is bonded in a single-bond geometry to one N(1,2,3,4) atom. In the second O site, O(5,6,7,8) is bonded in a single-bond geometry to one N(1,2,3,4) atom. In the third O site, O(9) is bonded in a distorted trigonal planar geometry to one Mn(5), one C(49), and one H(28) atom. In the fourth O site, O(10) is bonded in a distorted trigonal planar geometry to one Mn(6), one C(50), and one H(27) atom. In the fifth O site, O(11) is bonded in a distorted trigonal planar geometry to one Mn(7), one C(51), and one H(26) atom. In the sixth O site, O(12) is bonded in a distorted trigonal planar geometry to one Mn(8), one C(52), and one H(25) atom. In the seventh O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(49) atom. In the eighth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Mn(2) and one C(50) atom. In the ninth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one Mn(3) and one C(51) atom. In the tenth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one Mn(4) and one C(52) atom. In the eleventh O site, O(17) is bonded in a trigonal planar geometry to one Mn(2); one Mn(7); and one C(53,56) atom. In the twelfth O site, O(18) is bonded in a trigonal planar geometry to one Mn(1), one Mn(8), and one C(54) atom. In the thirteenth O site, O(19) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one C(55) atom. In the fourteenth O site, O(20) is bonded in a trigonal planar geometry to one Mn(3); one Mn(6); and one C(53,56) atom. The O(20)-C(53,56) bond length is 1.31 Å. In the fifteenth O site, O(21) is bonded in a single-bond geometry to one C(53,56) atom. In the sixteenth O site, O(22) is bonded in a single-bond geometry to one C(54) atom. In the seventeenth O site, O(23) is bonded in a single-bond geometry to one C(55) atom. In the eighteenth O site, O(24) is bonded in a single-bond geometry to one C(53,56) atom. The O(24)-C(53,56) bond length is 1.25 Å. In the nineteenth O site, O(25) is bonded in a 3-coordinate geometry to one Mn(3); one Mn(7); and one C(57,60) atom. In the twentieth O site, O(26) is bonded in a 3-coordinate geometry to one Mn(4), one Mn(8), and one C(58) atom. In the twenty-first O site, O(27) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(5), and one C(59) atom. In the twenty-second O site, O(28) is bonded in a 3-coordinate geometry to one Mn(2); one Mn(6); and one C(57,60) atom. The O(28)-C(57,60) bond length is 1.28 Å. In the twenty-third O site, O(29) is bonded in a distorted L-shaped geometry to one Mn(3) and one C(57,60) atom. In the twenty-fourth O site, O(30) is bonded in a distorted L-shaped geometry to one Mn(4) and one C(58) atom. In the twenty-fifth O site, O(31) is bonded in a distorted L-shaped geometry to one Mn(1) and one C(59) atom. In the twenty-sixth O site, O(32) is bonded in a distorted L-shaped geometry to one Mn(2) and one C(57,60) atom. The O(32)-C(57,60) bond length is 1.26 Å. In the twenty-seventh O site, O(33) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(61) atom. In the twenty-eighth O site, O(34) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(62) atom. In the twenty-ninth O site, O(35) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(63) atom. In the thirtieth O site, O(36) is bonded in a bent 120 degrees geometry to one Mn(4) and one C(64) atom. In the thirty-first O site, O(37) is bonded in a distorted bent 120 degrees geometry to one Mn(8) and one C(61) atom. In the thirty-second O site, O(38) is bonded in a distorted bent 120 degrees geometry to one Mn(7) and one C(62) atom. In the thirty-third O site, O(39) is bonded in a distorted bent 120 degrees geometry to one Mn(6) and one C(63) atom. In the thirty-fourth O site, O(40) is bonded in a distorted bent 120 degrees geometry to one Mn(5) and one C(64) atom. In the thirty-fifth O site, O(41,42,43,44) is bonded in a single-bond geometry to one N(5,6,7) atom. In the thirty-sixth O site, O(45) is bonded in a distorted bent 120 degrees geometry to one Mn(5) and one C(65) atom. In the thirty-seventh O site, O(46) is bonded in a distorted bent 120 degrees geometry to one Mn(6) and one C(66,67) atom. In the thirty-eighth O site, O(47) is bonded in a distorted bent 120 degrees geometry to one Mn(7) and one C(66,67) atom. The O(47)-C(66,67) bond length is 1.26 Å. In the thirty-ninth O site, O(48) is bonded in a distorted bent 120 degrees geometry to one Mn(8) and one C(68) atom. In the fortieth O site, O(49) is bonded in a distorted trigonal non-coplanar geometry to one Mn(5), one H(17), and one H(21) atom. In the forty-first O site, O(50) is bonded in a distorted trigonal non-coplanar geometry to one Mn(6), one H(18), and one H(22) atom. In the forty-second O site, O(51) is bonded in a distorted trigonal non-coplanar geometry to one Mn(7), one H(19), and one H(23) atom. In the forty-third O site, O(52) is bonded in a distorted trigonal non-coplanar geometry to one Mn(8), one H(20), and one H(24) atom. In the forty-fourth O site, O(53) is bonded in a distorted trigonal planar geometry to one Mn(1); one H(25); and one H(29,30) atom. In the forty-fifth O site, O(54) is bonded in a distorted trigonal planar geometry to one Mn(2); one H(26); and one H(29,30) atom. The O(54)-H(29,30) bond length is 0.97 Å. In the forty-sixth O site, O(55) is bonded in a distorted trigonal planar geometry to one Mn(3), one H(27), and one H(31) atom. In the forty-seventh O site, O(56) is bonded in a distorted trigonal planar geometry to one Mn(4), one H(28), and one H(32) atom. In the forty-eighth O site, O(57,58,59,60) is bonded in a single-bond geometry to one N(5,6,7) atom. Linkers: 4 [O]C(=O)c1cc(C([O])=O)c(-c2c(C([O])=O)cc(C([O])=O)cc2[N+](=O)[O-])c([N+](=O)[O-])c1. Metal clusters: 8 [Mn]. The MOF has largest included sphere 4.95 A, density 1.55 g/cm3, surface area 3567.67 m2/g, accessible volume 0.21 cm3/g