PbC14N2H12(O5Cl)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two PbC14N2H12(O5Cl)2 clusters. Pb(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(6), and one O(7) atom. The Pb(1)-N(1) bond length is 2.56 Å. The Pb(1)-N(2) bond length is 2.55 Å. The Pb(1)-O(1) bond length is 2.59 Å. The Pb(1)-O(2) bond length is 2.70 Å. The Pb(1)-O(6) bond length is 2.78 Å. The Pb(1)-O(7) bond length is 2.63 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one H(3), one H(4), and one O(1) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-H(4) bond length is 1.10 Å. The C(1)-O(1) bond length is 1.43 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(1) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-N(1) bond length is 1.33 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(3)-H(5) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(6) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-H(6) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(6) atom. The C(5)-C(10) bond length is 1.43 Å. The C(5)-C(6) bond length is 1.42 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(1) atom. The C(6)-C(7) bond length is 1.44 Å. The C(6)-N(1) bond length is 1.36 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(2) atom. The C(7)-C(8) bond length is 1.42 Å. The C(7)-N(2) bond length is 1.36 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(7), and one C(9) atom. The C(8)-C(13) bond length is 1.42 Å. The C(8)-C(9) bond length is 1.43 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(5) and one H(8) atom. The C(10)-H(8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one N(2) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-C(14) bond length is 1.50 Å. The C(11)-N(2) bond length is 1.33 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(9) atom. The C(12)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(10) atom. The C(13)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one H(11), one H(12), and one O(2) atom. The C(14)-H(11) bond length is 1.10 Å. The C(14)-H(12) bond length is 1.10 Å. The C(14)-O(2) bond length is 1.43 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Pb(1), one C(2), and one C(6) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one Pb(1), one C(11), and one C(7) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Pb(1), one C(1), and one H(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Pb(1), one C(14), and one H(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cl(1) atom. The O(3)-Cl(1) bond length is 1.45 Å. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cl(1) atom. The O(4)-Cl(1) bond length is 1.47 Å. In the fifth O site, O(5) is bonded in a single-bond geometry to one Cl(1) atom. The O(5)-Cl(1) bond length is 1.46 Å. In the sixth O site, O(6) is bonded in a single-bond geometry to one Pb(1) and one Cl(1) atom. The O(6)-Cl(1) bond length is 1.48 Å. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Pb(1) and one Cl(2) atom. The O(7)-Cl(2) bond length is 1.48 Å. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cl(2) atom. The O(8)-Cl(2) bond length is 1.46 Å. In the ninth O site, O(9) is bonded in a single-bond geometry to one Cl(2) atom. The O(9)-Cl(2) bond length is 1.46 Å. In the tenth O site, O(10) is bonded in a single-bond geometry to one Cl(2) atom. The O(10)-Cl(2) bond length is 1.45 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(5), and one O(6) atom. In the second Cl site, Cl(2) is bonded in a tetrahedral geometry to one O(10), one O(7), one O(8), and one O(9) atom. Linkers: 1 OCc1ccc2ccc3ccc(CO)nc3c2n1. Metal clusters: 2 [Pb]. The MOF has largest included sphere 2.45 A, density 2.37 g/cm3, surface area 3110.88 m2/g, accessible volume 0.09 cm3/g