Ag2C14N4H16S2O7(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two Ag2C14N4H16S2O7 clusters. In each Ag2C14N4H16S2O7 cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted T-shaped geometry to one N(3), one N(4), and one O(7) atom. The Ag(1)-N(3) bond length is 2.13 Å. The Ag(1)-N(4) bond length is 2.12 Å. The Ag(1)-O(7) bond length is 2.55 Å. In the second Ag site, Ag(2) is bonded in a distorted T-shaped geometry to one N(1), one N(2), and one O(4) atom. The Ag(2)-N(1) bond length is 2.15 Å. The Ag(2)-N(2) bond length is 2.15 Å. The Ag(2)-O(4) bond length is 2.69 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(3), and one O(1) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-N(3) bond length is 1.38 Å. The C(1)-O(1) bond length is 1.24 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(4) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(7)-S(1) bond length is 1.77 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(4), and one O(4) atom. The C(8)-C(9) bond length is 1.49 Å. The C(8)-N(4) bond length is 1.37 Å. The C(8)-O(4) bond length is 1.25 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(14) bond length is 1.40 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(5) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(5) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(6) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(6) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(7) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(7) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(8) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(8) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(9), and one S(2) atom. The C(14)-S(2) bond length is 1.77 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(10), and one H(9) atom. The C(15)-N(1) bond length is 1.48 Å. The C(15)-H(10) bond length is 1.10 Å. The C(15)-H(9) bond length is 1.10 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(15), and one H(16) atom. The C(16)-N(2) bond length is 1.48 Å. The C(16)-H(15) bond length is 1.11 Å. The C(16)-H(16) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Ag(2), one C(15), one H(11), and one H(12) atom to form distorted corner-sharing NAgH2C tetrahedra. The N(1)-H(11) bond length is 1.02 Å. The N(1)-H(12) bond length is 1.03 Å. In the second N site, N(2) is bonded to one Ag(2), one C(16), one H(13), and one H(14) atom to form distorted corner-sharing NAgH2C tetrahedra. The N(2)-H(13) bond length is 1.03 Å. The N(2)-H(14) bond length is 1.03 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one S(1) atom. The N(3)-S(1) bond length is 1.64 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(1), one C(8), and one S(2) atom. The N(4)-S(2) bond length is 1.66 Å. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one N(1) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one N(1) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one N(2) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one N(2) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one O(7) atom. The H(17)-O(7) bond length is 0.98 Å. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one O(7) atom. The H(18)-O(7) bond length is 0.98 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted tetrahedral geometry to one C(7), one N(3), one O(2), and one O(3) atom. The S(1)-O(2) bond length is 1.46 Å. The S(1)-O(3) bond length is 1.45 Å. In the second S site, S(2) is bonded in a distorted tetrahedral geometry to one C(14), one N(4), one O(5), and one O(6) atom. The S(2)-O(5) bond length is 1.46 Å. The S(2)-O(6) bond length is 1.45 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Ag(2) and one C(8) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(2) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Ag(1), one H(17), and one H(18) atom. Linkers: 2 NCCN. Metal clusters: 4 [Ag]. The MOF has largest included sphere 2.21 A, density 2.17 g/cm3, surface area 3506.97 m2/g, accessible volume 0.07 cm3/g