CuC14H6(NO2)2(CH)6 crystallizes in the tetragonal P4_22_12 space group. The structure consists of twenty-four 02329_fluka molecules inside a CuC14H6(NO2)2 framework. In the CuC14H6(NO2)2 framework, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 2.00 Å. Both Cu(1)-O(1) bond lengths are 2.00 Å. There are seven inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(3)-C(1) bond length is 1.39 Å. The C(3)-H(1) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(8) and one N(1) atom. The C(4)-C(8) bond length is 1.44 Å. The C(4)-N(1) bond length is 1.37 Å. In the third C site, C(8) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(5) atom. The C(8)-C(1) bond length is 1.43 Å. The C(8)-C(5) bond length is 1.42 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(6)-N(1) bond length is 1.33 Å. The C(6)-H(3) bond length is 1.09 Å. In the fifth C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(8) atom. The C(1)-C(2) bond length is 1.50 Å. In the sixth C site, C(5) is bonded in a distorted single-bond geometry to one C(8) and one H(2) atom. The C(5)-H(2) bond length is 1.09 Å. In the seventh C site, C(2) is bonded in a bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(2)-O(1) bond length is 1.29 Å. The C(2)-O(2) bond length is 1.26 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(4), and one C(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. Linkers: 8 [O]C(=O)c1cccc2ncccc12. Metal clusters: 4 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 6.13 A, density 1.18 g/cm3, surface area 4369.14 m2/g, accessible volume 0.39 cm3/g