ZnC10H10(NO)4(CH)2(C12NH6O2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four C12NH6O2 clusters, and two ZnC10H10(NO)4 clusters. In two of the C12NH6O2 clusters, there are twelve inequivalent C sites. In the first C site, C(5) is bonded in a distorted water-like geometry to one N(3) and one H(7) atom. The C(5)-N(3) bond length is 1.47 Å. The C(5)-H(7) bond length is 1.10 Å. In the second C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(3), and one O(3) atom. The C(7)-C(8) bond length is 1.47 Å. The C(7)-N(3) bond length is 1.40 Å. The C(7)-O(3) bond length is 1.24 Å. In the third C site, C(8) is bonded in a trigonal planar geometry to one C(18), one C(7), and one C(9) atom. The C(8)-C(18) bond length is 1.42 Å. The C(8)-C(9) bond length is 1.39 Å. In the fourth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(8) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-H(8) bond length is 1.09 Å. In the fifth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(9) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-H(9) bond length is 1.09 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(10) atom. The C(11)-C(12) bond length is 1.42 Å. The C(11)-H(10) bond length is 1.09 Å. In the seventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(18) atom. The C(12)-C(13) bond length is 1.42 Å. The C(12)-C(18) bond length is 1.43 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(13)-H(11) bond length is 1.09 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(13) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(13) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. The C(16)-C(17) bond length is 1.48 Å. The C(16)-C(18) bond length is 1.42 Å. In the eleventh C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(3), and one O(4) atom. The C(17)-N(3) bond length is 1.41 Å. The C(17)-O(4) bond length is 1.24 Å. In the twelfth C site, C(18) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(8) atom. N(3) is bonded in a trigonal planar geometry to one C(17), one C(5), and one C(7) atom. There are six inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(7) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(17) atom. In two of the C12NH6O2 clusters, there are twelve inequivalent C sites. In the first C site, C(24) is bonded in a distorted water-like geometry to one N(6) and one H(18) atom. The C(24)-N(6) bond length is 1.47 Å. The C(24)-H(18) bond length is 1.10 Å. In the second C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(26), one N(6), and one O(7) atom. The C(25)-C(26) bond length is 1.47 Å. The C(25)-N(6) bond length is 1.41 Å. The C(25)-O(7) bond length is 1.24 Å. In the third C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(36) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-C(36) bond length is 1.42 Å. In the fourth C site, C(27) is bonded in a distorted single-bond geometry to one C(26), one C(28), and one H(19) atom. The C(27)-C(28) bond length is 1.41 Å. The C(27)-H(19) bond length is 1.09 Å. In the fifth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one C(29), and one H(20) atom. The C(28)-C(29) bond length is 1.38 Å. The C(28)-H(20) bond length is 1.09 Å. In the sixth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one C(30), and one H(21) atom. The C(29)-C(30) bond length is 1.42 Å. The C(29)-H(21) bond length is 1.09 Å. In the seventh C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(36) atom. The C(30)-C(31) bond length is 1.42 Å. The C(30)-C(36) bond length is 1.43 Å. In the eighth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(22) atom. The C(31)-H(22) bond length is 1.09 Å. In the ninth C site, C(33) is bonded in a distorted single-bond geometry to one C(34) and one H(24) atom. The C(33)-C(34) bond length is 1.39 Å. The C(33)-H(24) bond length is 1.09 Å. In the tenth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(36) atom. The C(34)-C(35) bond length is 1.47 Å. The C(34)-C(36) bond length is 1.42 Å. In the eleventh C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(34), one N(6), and one O(8) atom. The C(35)-N(6) bond length is 1.40 Å. The C(35)-O(8) bond length is 1.24 Å. In the twelfth C site, C(36) is bonded in a trigonal planar geometry to one C(26), one C(30), and one C(34) atom. N(6) is bonded in a trigonal planar geometry to one C(24), one C(25), and one C(35) atom. There are six inequivalent H sites. In the first H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the second H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the third H site, H(20) is bonded in a single-bond geometry to one C(28) atom. In the fourth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the fifth H site, H(22) is bonded in a single-bond geometry to one C(31) atom. In the sixth H site, H(24) is bonded in a single-bond geometry to one C(33) atom. There are two inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one C(25) atom. In the second O site, O(8) is bonded in a single-bond geometry to one C(35) atom. In each ZnC10H10(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(4), one O(1), and one O(5) atom. The Zn(1)-N(1) bond length is 1.96 Å. The Zn(1)-N(4) bond length is 1.97 Å. The Zn(1)-O(1) bond length is 2.05 Å. The Zn(1)-O(5) bond length is 1.99 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(3) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one H(4) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(2) bond length is 1.38 Å. The C(2)-H(4) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(1) atom. The C(3)-C(4) bond length is 1.49 Å. The C(3)-N(1) bond length is 1.39 Å. In the fourth C site, C(4) is bonded in a distorted water-like geometry to one C(3), one H(5), and one H(6) atom. The C(4)-H(5) bond length is 1.10 Å. The C(4)-H(6) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(6)-O(1) bond length is 1.30 Å. The C(6)-O(2) bond length is 1.25 Å. In the sixth C site, C(19) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(14) atom. The C(19)-N(4) bond length is 1.34 Å. The C(19)-N(5) bond length is 1.35 Å. The C(19)-H(14) bond length is 1.08 Å. In the seventh C site, C(20) is bonded in a 3-coordinate geometry to one C(21), one N(4), and one H(15) atom. The C(20)-C(21) bond length is 1.38 Å. The C(20)-N(4) bond length is 1.39 Å. The C(20)-H(15) bond length is 1.08 Å. In the eighth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one N(5) atom. The C(21)-C(22) bond length is 1.49 Å. The C(21)-N(5) bond length is 1.38 Å. In the ninth C site, C(22) is bonded in a distorted water-like geometry to one C(21), one H(16), and one H(17) atom. The C(22)-H(16) bond length is 1.10 Å. The C(22)-H(17) bond length is 1.10 Å. In the tenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(23)-O(5) bond length is 1.29 Å. The C(23)-O(6) bond length is 1.25 Å. There are four inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(19), and one C(20) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one C(19), one C(21), and one H(2) atom. The N(5)-H(2) bond length is 1.02 Å. In the third N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(3) atom. In the fourth N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(2), and one H(1) atom. The N(2)-H(1) bond length is 1.04 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(22) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(6) atom. In the third O site, O(5) is bonded in a water-like geometry to one Zn(1) and one C(23) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(23) atom. Linkers: 2 [O]C(=O)[C@H](Cc1cnc[nH]1)N1C(=O)c2cccc3cccc(c23)C1=O. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.74 A, density 1.43 g/cm3, surface area 4569.07 m2/g, accessible volume 0.20 cm3/g