AgC6H6(N2O)3CH2CH3 crystallizes in the orthorhombic Fdd2 space group. The structure consists of sixteen 02329_fluka molecules and sixteen 02329_fluka molecules inside a AgC6H6(N2O)3 framework. In the AgC6H6(N2O)3 framework, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(2), one N(4), and one O(1) atom. The Ag(1)-N(1) bond length is 2.42 Å. The Ag(1)-N(2) bond length is 2.26 Å. The Ag(1)-N(4) bond length is 2.19 Å. The Ag(1)-O(1) bond length is 2.60 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(3) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one N(5) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(2) bond length is 1.35 Å. The C(2)-N(5) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(4) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-N(4) bond length is 1.38 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one N(3) atom. The C(4)-N(1) bond length is 1.36 Å. The C(4)-N(3) bond length is 1.34 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(4) atom. The C(5)-N(4) bond length is 1.33 Å. The C(5)-N(5) bond length is 1.37 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(5), one H(5), and one H(6) atom. The C(6)-N(5) bond length is 1.46 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(2) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(4), one H(1), and one H(2) atom. The N(3)-H(1) bond length is 1.02 Å. The N(3)-H(2) bond length is 1.03 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(1), one C(3), and one C(5) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(6) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(6)-O(1) bond length is 1.29 Å. The N(6)-O(2) bond length is 1.26 Å. The N(6)-O(3) bond length is 1.27 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one N(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(6) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(6) atom. Linkers: 1 CCCN1C=NC2=C(N)N=CN([Ag](N3[CH]N(CCC)C4=C3[C](N)N=C[N]4)N3[CH]N=c4c(ncn4CCC)=C3N)[C]21.[O][N+](=O)[O-] ,1 [CH2]CN1[CH]N([Ag](N2C=NC(N)=C3N=CN(CCC)[C]32)N2[CH]N=C3[N][C]=NC3=C2N)c2c(N)ncnc21.[O][N+](=O)[O-] ,1 CCC[N]/[C]=N\[Ag](N1[CH]N=c2c(ncn2CCC)=C1N)N1[CH]N(CCC)c2ncnc([NH])c21.[O]. Metal clusters: 3 [Ag]. The MOF has largest included sphere 3.05 A, density 1.90 g/cm3, surface area 3873.91 m2/g, accessible volume 0.09 cm3/g