NiC10H14(N2O3)2(CH2)4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four NiC10H14(N2O3)2 clusters. In each NiC10H14(N2O3)2 cluster, Ni(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Ni(1)-N(1) bond lengths are 1.91 Å. Both Ni(1)-O(1) bond lengths are 1.93 Å. There are five inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-N(2) bond length is 1.35 Å. The C(3)-H(3) bond length is 1.08 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(1), and one H(4) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-N(1) bond length is 1.38 Å. The C(4)-H(4) bond length is 1.08 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(5) atom. The C(5)-N(2) bond length is 1.38 Å. The C(5)-H(5) bond length is 1.08 Å. In the fourth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(6), and one H(7) atom. The C(6)-N(2) bond length is 1.46 Å. The C(6)-H(6) bond length is 1.10 Å. The C(6)-H(7) bond length is 1.10 Å. In the fifth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. There are seven inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one O(3) atom. The H(10)-O(3) bond length is 0.99 Å. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(11) is bonded in a single-bond geometry to one O(2) and one O(3) atom. The H(11)-O(2) bond length is 1.68 Å. The H(11)-O(3) bond length is 1.00 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one C(1) and one H(11) atom. In the third O site, O(3) is bonded in a water-like geometry to one H(10) and one H(11) atom. Linkers: 2 c1cn(CCCCn2ccnc2)cn1 ,2 [O]C(=O)CCC([O])=O. Metal clusters: 2 O=[C]O[Ni]O[C]=O. The MOF has largest included sphere 2.44 A, density 1.62 g/cm3, surface area 4677.83 m2/g, accessible volume 0.14 cm3/g