CuC8N5H8ClCH is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and two CuC8N5H8Cl clusters. In each CuC8N5H8Cl cluster, Cu(1) is bonded in a 4-coordinate geometry to one C(8), one C(9), one N(1), and one Cl(1) atom. The Cu(1)-C(8) bond length is 2.02 Å. The Cu(1)-C(9) bond length is 2.01 Å. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-Cl(1) bond length is 2.24 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(1), and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(7) atom. The C(5)-C(7) bond length is 1.46 Å. In the fifth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(5), and one H(6) atom. The C(6)-N(2) bond length is 1.46 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5), one N(3), and one N(4) atom. The C(7)-N(3) bond length is 1.34 Å. The C(7)-N(4) bond length is 1.36 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one Cu(1) and one H(7) atom. The C(8)-H(7) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one Cu(1), one H(8), and one H(9) atom. The C(9)-H(8) bond length is 1.09 Å. The C(9)-H(9) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(6), one N(3), and one N(5) atom. The N(2)-N(3) bond length is 1.33 Å. The N(2)-N(5) bond length is 1.34 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(7) and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted water-like geometry to one C(7) and one N(5) atom. The N(4)-N(5) bond length is 1.32 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one N(2) and one N(4) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 1 [CH]CN1[N]N=C(c2cccnc2)[N]1 ,1 [CH]Cn1nnc(-c2cccnc2)n1. Metal clusters: 2 [CH]C[Cu].[Cl]. The MOF has largest included sphere 2.25 A, density 1.83 g/cm3, surface area 4284.03 m2/g, accessible volume 0.12 cm3/g