LiC16NH12O3(CH)2(CH3)5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, ten 02329_fluka molecules, and one LiC16NH12O3 cluster. In the LiC16NH12O3 cluster, Li(1) is bonded to one C(7), one N(1), one O(1), and one O(3) atom to form distorted LiCNO2 tetrahedra that share  a cornercorner with one C(17)H2O2 tetrahedra and  a cornercorner with one C(20)H3O tetrahedra. The Li(1)-C(7) bond length is 2.14 Å. The Li(1)-N(1) bond length is 2.12 Å. The Li(1)-O(1) bond length is 2.10 Å. The Li(1)-O(3) bond length is 2.08 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. The C(1)-C(5) bond length is 1.48 Å. The C(1)-C(7) bond length is 1.44 Å. The C(1)-C(8) bond length is 1.41 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(7) and one O(1) atom. The C(3)-C(7) bond length is 1.37 Å. The C(3)-O(1) bond length is 1.43 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one N(1) atom. The C(4)-C(10) bond length is 1.42 Å. The C(4)-C(6) bond length is 1.42 Å. The C(4)-N(1) bond length is 1.41 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(1) and one N(1) atom. The C(5)-N(1) bond length is 1.30 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(4) atom. The C(6)-C(13) bond length is 1.40 Å. The C(6)-C(14) bond length is 1.52 Å. In the sixth C site, C(7) is bonded in a 3-coordinate geometry to one Li(1), one C(1), and one C(3) atom. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(8)-H(2) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(3) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(3) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(21), one C(4), and one C(9) atom. The C(10)-C(21) bond length is 1.52 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one O(2) atom. The C(11)-O(2) bond length is 1.37 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(6) and one H(7) atom. The C(13)-H(7) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a single-bond geometry to one C(6) and one H(8) atom. The C(14)-H(8) bond length is 1.10 Å. In the thirteenth C site, C(17) is bonded to one H(13), one H(14), one O(1), and one O(2) atom to form CH2O2 tetrahedra that share  a cornercorner with one Li(1)CNO2 tetrahedra. The C(17)-H(13) bond length is 1.10 Å. The C(17)-H(14) bond length is 1.10 Å. The C(17)-O(1) bond length is 1.43 Å. The C(17)-O(2) bond length is 1.45 Å. In the fourteenth C site, C(20) is bonded to one H(21), one H(22), one H(23), and one O(3) atom to form CH3O tetrahedra that share  a cornercorner with one Li(1)CNO2 tetrahedra. The C(20)-H(21) bond length is 1.10 Å. The C(20)-H(22) bond length is 1.10 Å. The C(20)-H(23) bond length is 1.10 Å. The C(20)-O(3) bond length is 1.44 Å. In the fifteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(10) and one H(24) atom. The C(21)-H(24) bond length is 1.10 Å. In the sixteenth C site, C(23) is bonded in a distorted trigonal non-coplanar geometry to one H(28), one H(29), and one O(3) atom. The C(23)-H(28) bond length is 1.10 Å. The C(23)-H(29) bond length is 1.10 Å. The C(23)-O(3) bond length is 1.44 Å. N(1) is bonded in a trigonal planar geometry to one Li(1), one C(4), and one C(5) atom. There are twelve inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(21) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(22) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(23) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(24) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(28) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(29) is bonded in a single-bond geometry to one C(23) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one C(17), and one C(3) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(11) and one C(17) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one C(20), and one C(23) atom. Linkers: 2 C/C(=N\c1c(C(C)C)cccc1C(C)C)c1[c]c2c(cc1)OCO2 ,1 COCCOC. Metal clusters: 2 [Li]. The MOF has largest included sphere 1.96 A, density 1.24 g/cm3, surface area 5881.59 m2/g, accessible volume 0.18 cm3/g