ZnC8PH8(NO)4(CH)3 is Indium-derived structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules and four ZnC8PH8(NO)4 clusters. In each ZnC8PH8(NO)4 cluster, Zn(1) is bonded to one N(3), one N(4), one O(2), and one O(3) atom to form ZnN2O2 tetrahedra that share  a cornercorner with one P(1)N2O2 tetrahedra. The Zn(1)-N(3) bond length is 2.00 Å. The Zn(1)-N(4) bond length is 2.01 Å. The Zn(1)-O(2) bond length is 1.96 Å. The Zn(1)-O(3) bond length is 1.98 Å. There are eight inequivalent C sites. In the first C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(5) atom. The C(4)-N(3) bond length is 1.35 Å. The C(4)-H(5) bond length is 1.09 Å. In the second C site, C(6) is bonded in a distorted single-bond geometry to one N(2) atom. The C(6)-N(2) bond length is 1.37 Å. In the third C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(8) atom. The C(8)-N(4) bond length is 1.35 Å. The C(8)-H(8) bond length is 1.09 Å. In the fourth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(4), and one H(9) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-N(4) bond length is 1.35 Å. The C(9)-H(9) bond length is 1.09 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(10) atom. The C(10)-H(10) bond length is 1.09 Å. In the sixth C site, C(11) is bonded in a trigonal planar geometry to one H(11), one O(3), and one O(4) atom. The C(11)-H(11) bond length is 1.11 Å. The C(11)-O(3) bond length is 1.29 Å. The C(11)-O(4) bond length is 1.25 Å. In the seventh C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(4) atom. The C(3)-N(3) bond length is 1.36 Å. The C(3)-H(4) bond length is 1.09 Å. In the eighth C site, C(1) is bonded in a distorted single-bond geometry to one N(1) atom. The C(1)-N(1) bond length is 1.37 Å. P(1) is bonded to one N(1), one N(2), one O(1), and one O(2) atom to form PN2O2 tetrahedra that share  a cornercorner with one Zn(1)N2O2 tetrahedra. The P(1)-N(1) bond length is 1.69 Å. The P(1)-N(2) bond length is 1.69 Å. The P(1)-O(1) bond length is 1.49 Å. The P(1)-O(2) bond length is 1.52 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(1), one P(1), and one H(1) atom. The N(1)-H(1) bond length is 1.04 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(6), one P(1), and one H(2) atom. The N(2)-H(2) bond length is 1.04 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(3), and one C(4) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(8), and one C(9) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one N(1) and one O(1) atom. The H(1)-O(1) bond length is 1.69 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one P(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(11) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(11) atom. Linkers: 2 [O][P@@](=O)(NC1=C[CH]N([Zn](OC=O)(OP(=O)(Nc2ccncc2)Nc2ccncc2)N2[CH]C=C(N[P@@]([O])(=O)Nc3ccncc3)C=C2)C=C1)Nc1ccncc1 ,2 [O]P(=O)(Nc1ccncc1)Nc1ccncc1. Metal clusters: 6 O=CO[Zn]OP=O. The MOF has largest included sphere 4.75 A, density 1.18 g/cm3, surface area 4415.48 m2/g, accessible volume 0.44 cm3/g