NdC22N4H14O7CH crystallizes in the monoclinic C2/c space group. The structure consists of eight 02329_fluka molecules inside a NdC22N4H14O7 framework. In the NdC22N4H14O7 framework, Nd(1) is bonded in a 9-coordinate geometry to one O(2), one O(3), one O(4), one O(6), one O(7), two equivalent O(1), and two equivalent O(5) atoms. The Nd(1)-O(2) bond length is 2.54 Å. The Nd(1)-O(3) bond length is 2.45 Å. The Nd(1)-O(4) bond length is 2.45 Å. The Nd(1)-O(6) bond length is 2.56 Å. The Nd(1)-O(7) bond length is 2.46 Å. There is one shorter (2.52 Å) and one longer (2.61 Å) Nd(1)-O(1) bond length. There is one shorter (2.41 Å) and one longer (2.66 Å) Nd(1)-O(5) bond length. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(1)-C(5) bond length is 1.40 Å. The C(1)-H(3) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-H(5) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one C(6), and one N(1) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(6) bond length is 1.50 Å. The C(4)-N(1) bond length is 1.35 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(4) atom. The C(5)-C(11) bond length is 1.49 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(10), one C(4), and one N(2) atom. The C(6)-C(10) bond length is 1.42 Å. The C(6)-N(2) bond length is 1.35 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one H(6) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(2) bond length is 1.34 Å. The C(7)-H(6) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(8)-H(7) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(8) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(12), one C(6), and one C(9) atom. The C(10)-C(12) bond length is 1.51 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(2) atom. The C(11)-O(1) bond length is 1.30 Å. The C(11)-O(2) bond length is 1.26 Å. In the eleventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(4) atom. The C(12)-O(3) bond length is 1.27 Å. The C(12)-O(4) bond length is 1.27 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one H(9) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-N(3) bond length is 1.34 Å. The C(13)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(14)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(11) bond length is 1.09 Å. In the fifteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(18) bond length is 1.50 Å. In the sixteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(17), and one N(3) atom. The C(17)-C(17) bond length is 1.48 Å. The C(17)-N(3) bond length is 1.35 Å. In the seventeenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(5), and one O(6) atom. The C(18)-O(5) bond length is 1.28 Å. The C(18)-O(6) bond length is 1.26 Å. In the eighteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(20), one N(4), and one H(12) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-N(4) bond length is 1.34 Å. The C(19)-H(12) bond length is 1.09 Å. In the nineteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(13) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(13) bond length is 1.09 Å. In the twentieth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(21), and one C(22) atom. The C(21)-C(21) bond length is 1.48 Å. The C(21)-C(22) bond length is 1.41 Å. In the twenty-first C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(14) atom. The C(22)-H(14) bond length is 1.09 Å. In the twenty-second C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(15) atom. The C(23)-N(4) bond length is 1.34 Å. The C(23)-H(15) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(3) and one C(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(6) and one C(7) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(13) and one C(17) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(19), one C(23), and one H(1) atom. The N(4)-H(1) bond length is 1.71 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one N(4) and one O(7) atom. The H(1)-O(7) bond length is 1.01 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. The H(2)-O(7) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Nd(1) and one C(11) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Nd(1) and one C(11) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one C(12) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Nd(1) and one C(12) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Nd(1) and one C(18) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Nd(1) and one C(18) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Nd(1), one H(1), and one H(2) atom. Linkers: 6 [O]C(=O)c1cccnc1-c1ncccc1C([O])=O. Metal clusters: 4 [Nd]. The MOF has largest included sphere 4.06 A, density 1.70 g/cm3, surface area 3426.70 m2/g, accessible volume 0.15 cm3/g