Co2C24N4H18O9CH3CHC6H5OH crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of four 02329_fluka molecules, four 02329_fluka molecules, and four akos004907369 molecules inside a Co2C24N4H18O9 framework. In the Co2C24N4H18O9 framework, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(1), one N(3), one O(1), one O(4), one O(6), and one O(7) atom to form corner-sharing CoN2O4 octahedra. The corner-sharing octahedral tilt angles are 64°. The Co(1)-N(1) bond length is 2.08 Å. The Co(1)-N(3) bond length is 2.14 Å. The Co(1)-O(1) bond length is 2.13 Å. The Co(1)-O(4) bond length is 2.09 Å. The Co(1)-O(6) bond length is 2.08 Å. The Co(1)-O(7) bond length is 2.03 Å. In the second Co site, Co(2) is bonded to one N(2), one N(4), one O(1), one O(5), one O(8), and one O(9) atom to form corner-sharing CoN2O4 octahedra. The corner-sharing octahedral tilt angles are 64°. The Co(2)-N(2) bond length is 2.08 Å. The Co(2)-N(4) bond length is 2.11 Å. The Co(2)-O(1) bond length is 2.19 Å. The Co(2)-O(5) bond length is 1.98 Å. The Co(2)-O(8) bond length is 2.06 Å. The Co(2)-O(9) bond length is 2.14 Å. There are twenty-four inequivalent C sites. In the first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(5), and one O(6) atom. The C(3)-C(12) bond length is 1.50 Å. The C(3)-O(5) bond length is 1.28 Å. The C(3)-O(6) bond length is 1.27 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(5) atom. The C(4)-C(10) bond length is 1.39 Å. The C(4)-N(2) bond length is 1.35 Å. The C(4)-H(5) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(5)-N(2) bond length is 1.35 Å. The C(5)-H(6) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(7) atom. The C(6)-C(2) bond length is 1.39 Å. The C(6)-N(1) bond length is 1.35 Å. The C(6)-H(7) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(4), and one H(8) atom. The C(7)-C(18) bond length is 1.39 Å. The C(7)-N(4) bond length is 1.35 Å. The C(7)-H(8) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(11) and one H(9) atom. The C(8)-C(11) bond length is 1.40 Å. The C(8)-H(9) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(18), one C(23), and one C(24) atom. The C(9)-C(18) bond length is 1.40 Å. The C(9)-C(23) bond length is 1.40 Å. The C(9)-C(24) bond length is 1.51 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(12), one C(4), and one H(10) atom. The C(10)-C(12) bond length is 1.40 Å. The C(10)-H(10) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(8) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-C(14) bond length is 1.50 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(10), one C(15), and one C(3) atom. The C(12)-C(15) bond length is 1.40 Å. In the eleventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(11), one C(20), and one H(11) atom. The C(13)-C(20) bond length is 1.39 Å. The C(13)-H(11) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(3), and one O(8) atom. The C(14)-O(3) bond length is 1.27 Å. The C(14)-O(8) bond length is 1.28 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(12) and one H(12) atom. The C(15)-H(12) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one N(1), and one H(13) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-N(1) bond length is 1.35 Å. The C(16)-H(13) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(19), and one H(14) atom. The C(17)-C(19) bond length is 1.40 Å. The C(17)-H(14) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(15) atom. The C(18)-H(15) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a trigonal planar geometry to one C(17), one C(2), and one C(21) atom. The C(19)-C(2) bond length is 1.40 Å. The C(19)-C(21) bond length is 1.50 Å. In the eighteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(3), and one H(16) atom. The C(20)-N(3) bond length is 1.35 Å. The C(20)-H(16) bond length is 1.09 Å. In the nineteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(7), and one O(9) atom. The C(21)-O(7) bond length is 1.28 Å. The C(21)-O(9) bond length is 1.26 Å. In the twentieth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(17) atom. The C(22)-N(4) bond length is 1.35 Å. The C(22)-H(17) bond length is 1.09 Å. In the twenty-first C site, C(23) is bonded in a distorted single-bond geometry to one C(9) and one H(18) atom. The C(23)-H(18) bond length is 1.09 Å. In the twenty-second C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(2), and one O(4) atom. The C(24)-O(2) bond length is 1.27 Å. The C(24)-O(4) bond length is 1.28 Å. In the twenty-third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(3) atom. The C(1)-N(3) bond length is 1.35 Å. The C(1)-H(3) bond length is 1.09 Å. In the twenty-fourth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(19), one C(6), and one H(4) atom. The C(2)-H(4) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(20) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Co(2), one C(22), and one C(7) atom. In the third N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(16), and one C(6) atom. In the fourth N site, N(2) is bonded in a trigonal planar geometry to one Co(2), one C(4), and one C(5) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(3) atom. The H(1)-O(1) bond length is 1.04 Å. The H(1)-O(3) bond length is 1.49 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) and one O(2) atom. The H(2)-O(1) bond length is 1.01 Å. The H(2)-O(2) bond length is 1.64 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(22) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(23) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Co(1), one Co(2), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(24) and one H(2) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(14) and one H(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one C(24) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(3) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Co(1) and one C(21) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(14) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one Co(2) and one C(21) atom. Linkers: 16 [O]C(=O)c1ccncc1. Metal clusters: 4 O.O=[C]O[Co]1O[C]O[Co](O[C]=O)O[C]O1. The MOF has largest included sphere 5.72 A, density 1.27 g/cm3, surface area 4318.95 m2/g, accessible volume 0.43 cm3/g