AgC5N2H2S(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a AgC5N2H2S framework. In the AgC5N2H2S framework, Ag(1) is bonded to one N(1), one N(2), and two equivalent S(1) atoms to form distorted corner-sharing AgS2N2 tetrahedra. The Ag(1)-N(1) bond length is 2.39 Å. The Ag(1)-N(2) bond length is 2.17 Å. There is one shorter (2.57 Å) and one longer (2.59 Å) Ag(1)-S(1) bond length. There are five inequivalent C sites. In the first C site, C(5) is bonded in a distorted trigonal planar geometry to one C(1), one C(6), and one N(1) atom. The C(5)-C(1) bond length is 1.45 Å. The C(5)-C(6) bond length is 1.42 Å. The C(5)-N(1) bond length is 1.35 Å. In the second C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(5), and one N(1) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-N(1) bond length is 1.35 Å. In the fourth C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the fifth C site, C(3) is bonded in a distorted single-bond geometry to one N(2) and one S(1) atom. The C(3)-N(2) bond length is 1.18 Å. The C(3)-S(1) bond length is 1.64 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a linear geometry to one Ag(1) and one C(3) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. S(1) is bonded in a trigonal non-coplanar geometry to two equivalent Ag(1) and one C(3) atom. Linkers: 2 c1ccc2nc3ccccc3nc2c1 ,2 [C]c1nc2ccccc2nc1C=[C]. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.81 A, density 2.32 g/cm3, surface area 3160.58 m2/g, accessible volume 0.09 cm3/g