CoC14H12Te2(N2Cl)2(C3H2Te)2(C5NH4Te)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of eight C3H2Te clusters, eight C5NH4Te clusters, and four CoC14H12Te2(N2Cl)2 clusters. In each C3H2Te cluster, there are three inequivalent C sites. In the first C site, C(9,10,12,13,14) is bonded in a distorted single-bond geometry to one C(17,18,19,20,21,22,23,24) and one H(9,10,11,12,13,14,15,16) atom. The C(9,10,12,13,14)-C(17,18,19,20,21,22,23,24) bond length is 1.40 Å. The C(9,10,12,13,14)-H(9,10,11,12,13,14,15,16) bond length is 1.09 Å. In the second C site, C(17,18,19,20,21,22,23,24) is bonded in a trigonal planar geometry to one C(25,26,28,29,30); one C(9,10,12,13,14); and one Te(1,2,4,5,6) atom. The C(17,18,19,20,21,22,23,24)-C(25,26,28,29,30) bond length is 1.40 Å. The C(17,18,19,20,21,22,23,24)-Te(1,2,4,5,6) bond length is 2.15 Å. In the third C site, C(25,26,28,29,30) is bonded in a distorted single-bond geometry to one C(17,18,19,20,21,22,23,24) and one H(17,18,19,20,21,22,23,24) atom. The C(25,26,28,29,30)-H(17,18,19,20,21,22,23,24) bond length is 1.09 Å. There are two inequivalent H sites. In the first H site, H(9,10,11,12,13,14,15,16) is bonded in a single-bond geometry to one C(9,10,12,13,14) atom. In the second H site, H(17,18,19,20,21,22,23,24) is bonded in a single-bond geometry to one C(25,26,28,29,30) atom. Te(1,2,4,5,6) is bonded in a single-bond geometry to one C(17,18,19,20,21,22,23,24) atom. In each C5NH4Te cluster, there are five inequivalent C sites. In the first C site, C(105,108,110) is bonded in a distorted single-bond geometry to one C(113,118,119,120); one C(81,86,87,88); and one H(81,86,87,88) atom. The C(105,108,110)-C(113,118,119,120) bond length is 1.40 Å. The C(105,108,110)-C(81,86,87,88) bond length is 1.40 Å. The C(105,108,110)-H(81,86,87,88) bond length is 1.09 Å. In the second C site, C(81,86,87,88) is bonded in a trigonal planar geometry to one C(105,108,110); one C(89,92,94); and one Te(17,20,21,22) atom. The C(81,86,87,88)-C(89,92,94) bond length is 1.40 Å. The C(81,86,87,88)-Te(17,20,21,22) bond length is 2.14 Å. In the third C site, C(113,118,119,120) is bonded in a distorted trigonal planar geometry to one C(105,108,110); one N(17,20,22,23); and one H(89,92,94,95) atom. The C(113,118,119,120)-N(17,20,22,23) bond length is 1.34 Å. The C(113,118,119,120)-H(89,92,94,95) bond length is 1.09 Å. In the fourth C site, C(97,102,103,104) is bonded in a distorted trigonal planar geometry to one C(89,92,94); one N(17,20,22,23); and one H(73,75,76,78,79) atom. The C(97,102,103,104)-C(89,92,94) bond length is 1.40 Å. The C(97,102,103,104)-N(17,20,22,23) bond length is 1.34 Å. The C(97,102,103,104)-H(73,75,76,78,79) bond length is 1.09 Å. In the fifth C site, C(89,92,94) is bonded in a distorted single-bond geometry to one C(81,86,87,88); one C(97,102,103,104); and one H(65,67,68,69,70,71,72) atom. The C(89,92,94)-H(65,67,68,69,70,71,72) bond length is 1.09 Å. N(17,20,22,23) is bonded in a bent 120 degrees geometry to one C(113,118,119,120) and one C(97,102,103,104) atom. There are four inequivalent H sites. In the first H site, H(73,75,76,78,79) is bonded in a single-bond geometry to one C(97,102,103,104) atom. In the second H site, H(81,86,87,88) is bonded in a single-bond geometry to one C(105,108,110) atom. In the third H site, H(89,92,94,95) is bonded in a single-bond geometry to one C(113,118,119,120) atom. In the fourth H site, H(65,67,68,69,70,71,72) is bonded in a single-bond geometry to one C(89,92,94) atom. Te(17,20,21,22) is bonded in a single-bond geometry to one C(81,86,87,88) atom. In each CoC14H12Te2(N2Cl)2 cluster, Co(1) is bonded in an octahedral geometry to one N(1), one N(11), one N(15), one N(5), one Cl(1), and one Cl(5) atom. The Co(1)-N(1) bond length is 2.18 Å. The Co(1)-N(11) bond length is 2.13 Å. The Co(1)-N(15) bond length is 2.13 Å. The Co(1)-N(5) bond length is 2.18 Å. The Co(1)-Cl(1) bond length is 2.48 Å. The Co(1)-Cl(5) bond length is 2.49 Å. There are eleven inequivalent C sites. In the first C site, C(33,37) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(25,26,31) atom. The C(33,37)-N(1) bond length is 1.35 Å. The C(33,37)-H(25,26,31) bond length is 1.09 Å. In the second C site, C(43) is bonded in a distorted trigonal planar geometry to one C(51,53); one N(11); and one H(35,37,40) atom. The C(43)-C(51,53) bond length is 1.39 Å. The C(43)-N(11) bond length is 1.35 Å. The C(43)-H(35,37,40) bond length is 1.09 Å. In the third C site, C(47) is bonded in a distorted trigonal planar geometry to one C(50,55); one N(15); and one H(34,39) atom. The C(47)-C(50,55) bond length is 1.39 Å. The C(47)-N(15) bond length is 1.35 Å. The C(47)-H(34,39) bond length is 1.09 Å. In the fourth C site, C(50,55) is bonded in a distorted trigonal planar geometry to one C(42,44); one C(58,59,60,61,63,64); and one H(42,43,44,45,47,48) atom. The C(50,55)-C(42,44) bond length is 1.39 Å. The C(50,55)-C(58,59,60,61,63,64) bond length is 1.40 Å. The C(50,55)-H(42,43,44,45,47,48) bond length is 1.09 Å. In the fifth C site, C(51,53) is bonded in a distorted trigonal planar geometry to one C(43); one C(58,59,60,61,63,64); and one H(42,43,44,45,47,48) atom. The C(51,53)-C(58,59,60,61,63,64) bond length is 1.40 Å. The C(51,53)-H(42,43,44,45,47,48) bond length is 1.09 Å. In the sixth C site, C(58,59,60,61,63,64) is bonded in a trigonal planar geometry to one C(50,55); one C(66,71); and one Te(10,15,16) atom. The C(58,59,60,61,63,64)-C(66,71) bond length is 1.40 Å. The C(58,59,60,61,63,64)-Te(10,15,16) bond length is 2.14 Å. In the seventh C site, C(66,71) is bonded in a distorted single-bond geometry to one C(58,59,60,61,63,64); one C(74,76); and one H(50,51,52,55,56) atom. The C(66,71)-C(74,76) bond length is 1.39 Å. The C(66,71)-H(50,51,52,55,56) bond length is 1.09 Å. In the eighth C site, C(67,69) is bonded in a distorted single-bond geometry to one C(58,59,60,61,63,64); one C(75); and one H(50,51,52,55,56) atom. The C(67,69)-C(58,59,60,61,63,64) bond length is 1.40 Å. The C(67,69)-C(75) bond length is 1.39 Å. The C(67,69)-H(50,51,52,55,56) bond length is 1.09 Å. In the ninth C site, C(75) is bonded in a distorted trigonal planar geometry to one C(67,69); one N(11); and one H(59,61,64) atom. The C(75)-N(11) bond length is 1.35 Å. The C(75)-H(59,61,64) bond length is 1.09 Å. In the tenth C site, C(79) is bonded in a distorted trigonal planar geometry to one C(66,71); one N(15); and one H(58,63) atom. The C(79)-C(66,71) bond length is 1.39 Å. The C(79)-N(15) bond length is 1.35 Å. The C(79)-H(58,63) bond length is 1.09 Å. In the eleventh C site, C(1,5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,2,7) atom. The C(1,5)-N(1) bond length is 1.35 Å. The C(1,5)-H(1,2,7) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(15) is bonded in a trigonal planar geometry to one Co(1), one C(47), and one C(79) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Co(1); one C(1,5); and one C(33,37) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Co(1); one C(1,5); and one C(33,37) atom. The N(5)-C(1,5) bond length is 1.35 Å. The N(5)-C(33,37) bond length is 1.35 Å. In the fourth N site, N(11) is bonded in a trigonal planar geometry to one Co(1), one C(43), and one C(75) atom. There are ten inequivalent H sites. In the first H site, H(1,2,7) is bonded in a single-bond geometry to one C(1,5) atom. In the second H site, H(5,6) is bonded in a single-bond geometry to one C(1,5) atom. The H(5,6)-C(1,5) bond length is 1.09 Å. In the third H site, H(25,26,31) is bonded in a single-bond geometry to one C(33,37) atom. In the fourth H site, H(29,30) is bonded in a single-bond geometry to one C(33,37) atom. The H(29,30)-C(33,37) bond length is 1.09 Å. In the fifth H site, H(35,37,40) is bonded in a single-bond geometry to one C(43) atom. In the sixth H site, H(34,39) is bonded in a single-bond geometry to one C(42,44) atom. The H(34,39)-C(42,44) bond length is 1.09 Å. In the seventh H site, H(42,43,44,45,47,48) is bonded in a single-bond geometry to one C(50,55) atom. In the eighth H site, H(50,51,52,55,56) is bonded in a single-bond geometry to one C(66,71) atom. In the ninth H site, H(58,63) is bonded in a single-bond geometry to one C(74,76) atom. The H(58,63)-C(74,76) bond length is 1.09 Å. In the tenth H site, H(59,61,64) is bonded in a single-bond geometry to one C(75) atom. There are two inequivalent Te sites. In the first Te site, Te(10,15,16) is bonded in a single-bond geometry to one C(58,59,60,61,63,64) atom. In the second Te site, Te(11,12,13,14) is bonded in a single-bond geometry to one C(58,59,60,61,63,64) atom. The Te(11,12,13,14)-C(58,59,60,61,63,64) bond length is 2.14 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Co(1) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one Co(1) atom. Linkers: 8 c1cc([Te][Te]c2ccncc2)ccn1. Metal clusters: 4 Cl[Co]Cl. The MOF has largest included sphere 1.91 A, density 2.57 g/cm3, surface area 2673.01 m2/g, accessible volume 0.07 cm3/g