Ag(NH3)2Ag5C12H16S2(NO3)4(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, one Ag(NH3)2 cluster, and one Ag5C12H16S2(NO3)4 cluster. In the Ag(NH3)2 cluster, Ag(1) is bonded in a linear geometry to two equivalent N(1) atoms. Both Ag(1)-N(1) bond lengths are 2.15 Å. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one H(1), one H(2), and one H(3) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.03 Å. The N(1)-H(3) bond length is 1.02 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the Ag5C12H16S2(NO3)4 cluster, there are three inequivalent Ag sites. In the first Ag site, Ag(2) is bonded in a linear geometry to one N(2) and one O(4) atom. The Ag(2)-N(2) bond length is 2.09 Å. The Ag(2)-O(4) bond length is 2.10 Å. In the second Ag site, Ag(3) is bonded in a linear geometry to two equivalent O(6) atoms. Both Ag(3)-O(6) bond lengths are 2.15 Å. In the third Ag site, Ag(4) is bonded in a distorted linear geometry to one N(3) and one O(5) atom. The Ag(4)-N(3) bond length is 2.13 Å. The Ag(4)-O(5) bond length is 2.13 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.43 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-S(1) bond length is 1.77 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one O(4) atom. The C(2)-O(4) bond length is 1.31 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(11) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(11) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(7) bond length is 1.48 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(12) atom. The C(6)-H(12) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(5), and one O(6) atom. The C(7)-O(5) bond length is 1.29 Å. The C(7)-O(6) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one H(4), one H(5), and one H(6) atom. The N(2)-H(4) bond length is 1.03 Å. The N(2)-H(5) bond length is 1.03 Å. The N(2)-H(6) bond length is 1.03 Å. In the second N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Ag(4), one H(7), one H(8), and one H(9) atom. The N(3)-H(7) bond length is 1.03 Å. The N(3)-H(8) bond length is 1.02 Å. The N(3)-H(9) bond length is 1.03 Å. There are eight inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.48 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Ag(2) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Ag(4) and one C(7) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ag(3) and one C(7) atom. Linkers: 2 [O]C(=O)c1ccc([O])c(S([O])([O])[O])c1. Metal clusters: 6 [Ag]. The MOF has largest included sphere 1.39 A, density 3.05 g/cm3, surface area 2410.34 m2/g, accessible volume 0.05 cm3/g