Ag2C11H10S2(NO2)3CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a Ag2C11H10S2(NO2)3 framework. In the Ag2C11H10S2(NO2)3 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), and two equivalent O(2) atoms. The Ag(1)-N(1) bond length is 2.13 Å. The Ag(1)-N(2) bond length is 2.13 Å. There is one shorter (2.75 Å) and one longer (2.80 Å) Ag(1)-O(2) bond length. In the second Ag site, Ag(2) is bonded in a distorted tetrahedral geometry to one N(3), one O(1), one O(5), and one O(6) atom. The Ag(2)-N(3) bond length is 2.11 Å. The Ag(2)-O(1) bond length is 2.42 Å. The Ag(2)-O(5) bond length is 2.44 Å. The Ag(2)-O(6) bond length is 2.32 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one S(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-S(1) bond length is 1.79 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5) atom. The C(6)-N(2) bond length is 1.35 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(7) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(7) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(8), and one S(2) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-S(2) bond length is 1.78 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(8) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a linear geometry to one C(12) and one N(3) atom. The C(11)-C(12) bond length is 1.44 Å. The C(11)-N(3) bond length is 1.16 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one H(10), one H(11), and one H(9) atom. The C(12)-H(10) bond length is 1.10 Å. The C(12)-H(11) bond length is 1.10 Å. The C(12)-H(9) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a linear geometry to one Ag(2) and one C(11) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(2) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.46 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one O(4), one O(5), and one O(6) atom. The S(2)-O(4) bond length is 1.46 Å. The S(2)-O(5) bond length is 1.47 Å. The S(2)-O(6) bond length is 1.48 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Ag(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one S(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ag(2) and one S(2) atom. Linkers: 4 [O]S([O])([O])c1cccnc1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.71 A, density 2.32 g/cm3, surface area 3253.14 m2/g, accessible volume 0.09 cm3/g