CdH10(CN)11CH2CH3 crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules and two 02329_fluka molecules inside a CdH10(CN)11 framework. In the CdH10(CN)11 framework, Cd(1) is bonded in an octahedral geometry to one N(1), one N(11), one N(5), one N(6), one N(8), and one N(9) atom. The Cd(1)-N(1) bond length is 2.38 Å. The Cd(1)-N(11) bond length is 2.35 Å. The Cd(1)-N(5) bond length is 2.38 Å. The Cd(1)-N(6) bond length is 2.42 Å. The Cd(1)-N(8) bond length is 2.41 Å. The Cd(1)-N(9) bond length is 2.36 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one N(5) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-N(5) bond length is 1.38 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one N(3) atom. The C(6)-N(3) bond length is 1.37 Å. In the seventh C site, C(7) is bonded in a tetrahedral geometry to one N(2), one N(3), one H(5), and one H(6) atom. The C(7)-N(2) bond length is 1.45 Å. The C(7)-N(3) bond length is 1.45 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(2), and one H(7) atom. The C(8)-C(9) bond length is 1.37 Å. The C(8)-N(2) bond length is 1.39 Å. The C(8)-H(7) bond length is 1.08 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(1), and one H(8) atom. The C(9)-N(1) bond length is 1.39 Å. The C(9)-H(8) bond length is 1.08 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one N(2) atom. The C(10)-C(11) bond length is 1.49 Å. The C(10)-N(1) bond length is 1.34 Å. The C(10)-N(2) bond length is 1.37 Å. In the eleventh C site, C(11) is bonded in a distorted water-like geometry to one C(10), one H(10), and one H(9) atom. The C(11)-H(10) bond length is 1.09 Å. The C(11)-H(9) bond length is 1.10 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(8) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one N(4) atom. The N(3)-N(4) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one N(3) and one N(5) atom. The N(4)-N(5) bond length is 1.31 Å. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one Cd(1), one C(1), and one N(4) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one Cd(1) and one N(7) atom. The N(6)-N(7) bond length is 1.19 Å. In the seventh N site, N(7) is bonded in a linear geometry to one N(6) and one N(8) atom. The N(7)-N(8) bond length is 1.18 Å. In the eighth N site, N(8) is bonded in a bent 120 degrees geometry to one Cd(1) and one N(7) atom. In the ninth N site, N(9) is bonded in a bent 120 degrees geometry to one Cd(1) and one N(10) atom. The N(9)-N(10) bond length is 1.18 Å. In the tenth N site, N(10) is bonded in a linear geometry to two equivalent N(9) atoms. In the eleventh N site, N(11) is bonded in a bent 150 degrees geometry to one Cd(1) and one N(12) atom. The N(11)-N(12) bond length is 1.18 Å. In the twelfth N site, N(12) is bonded in a linear geometry to two equivalent N(11) atoms. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. Linkers: 2 CCCc1nccn1Cn1nnc2ccccc21. Metal clusters: 2 [Cd]. The MOF has largest included sphere 2.55 A, density 1.76 g/cm3, surface area 4275.81 m2/g, accessible volume 0.16 cm3/g