(CH)8CuC20H12S4(NCl)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and two CuC20H12S4(NCl)2 clusters. In each CuC20H12S4(NCl)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent Cl(1) atoms. Both Cu(1)-N(1) bond lengths are 2.00 Å. Both Cu(1)-Cl(1) bond lengths are 2.28 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(8), one N(1), and one S(1) atom. The C(1)-C(8) bond length is 1.47 Å. The C(1)-N(1) bond length is 1.33 Å. The C(1)-S(1) bond length is 1.74 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one N(1) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(7) bond length is 1.40 Å. The C(2)-N(1) bond length is 1.39 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one S(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-S(1) bond length is 1.72 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(4)-H(1) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(9) atom. The C(8)-C(13) bond length is 1.41 Å. The C(8)-C(9) bond length is 1.42 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(8), and one S(2) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-S(2) bond length is 1.78 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(10)-H(5) bond length is 1.09 Å. In the ninth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(13)-H(8) bond length is 1.09 Å. In the tenth C site, C(14) is bonded in a distorted water-like geometry to one H(10), one H(9), and one S(2) atom. The C(14)-H(10) bond length is 1.10 Å. The C(14)-H(9) bond length is 1.10 Å. The C(14)-S(2) bond length is 1.82 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(1) and one C(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(14) and one C(9) atom. Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 2 c1ccc(-c2nc3ccccc3s2)c(SCCSc2ccccc2-c2nc3ccccc3s2)c1 ,2 [C]SC(=[N])c1ccccc1SCCSc1ccccc1-c1nc2ccccc2s1. Metal clusters: 2 Cl[Cu]Cl. The MOF has largest included sphere 1.85 A, density 1.69 g/cm3, surface area 4344.00 m2/g, accessible volume 0.13 cm3/g