ZnC32H24(NO)10(CH)2 crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a ZnC32H24(NO)10 framework. In the ZnC32H24(NO)10 framework, Zn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(5) atoms. Both Zn(1)-N(1) bond lengths are 2.09 Å. Both Zn(1)-O(1) bond lengths are 2.17 Å. Both Zn(1)-O(5) bond lengths are 2.29 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(6) atom. The C(1)-N(5) bond length is 1.34 Å. The C(1)-H(6) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(1) bond length is 1.09 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.46 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(5), and one H(8) atom. The C(5)-N(5) bond length is 1.34 Å. The C(5)-H(8) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one N(3) atom. The C(6)-N(2) bond length is 1.36 Å. The C(6)-N(3) bond length is 1.35 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one N(4) atom. The C(7)-C(8) bond length is 1.46 Å. The C(7)-N(2) bond length is 1.34 Å. The C(7)-N(4) bond length is 1.36 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(9) atom. The C(9)-H(9) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(10) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(10) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(2) atom. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(2) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(1), and one H(3) atom. The C(12)-N(1) bond length is 1.34 Å. The C(12)-H(3) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(1), and one O(2) atom. The C(13)-C(14) bond length is 1.52 Å. The C(13)-O(1) bond length is 1.27 Å. The C(13)-O(2) bond length is 1.26 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(16) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(16) bond length is 1.41 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(11) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(11) bond length is 1.09 Å. In the fifteenth C site, C(16) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(17) atom. The C(16)-C(17) bond length is 1.50 Å. In the sixteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(3), and one O(4) atom. The C(17)-O(3) bond length is 1.23 Å. The C(17)-O(4) bond length is 1.33 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(12) atom. In the second N site, N(2) is bonded in a water-like geometry to one C(6) and one C(7) atom. In the third N site, N(3) is bonded in a 1-coordinate geometry to one C(6) and one N(4) atom. The N(3)-N(4) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one C(7), one N(3), and one H(13) atom. The N(4)-H(13) bond length is 1.07 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(1), one C(5), and one H(12) atom. The N(5)-H(12) bond length is 1.49 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(5) atom. The H(4)-O(5) bond length is 0.97 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(5) atom. The H(5)-O(5) bond length is 1.00 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(1) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(12) is bonded in a linear geometry to one N(5) and one O(4) atom. The H(12)-O(4) bond length is 1.08 Å. In the twelfth H site, H(13) is bonded in a linear geometry to one N(4) and one O(2) atom. The H(13)-O(2) bond length is 1.57 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one C(13) and one H(13) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(17) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(17) and one H(12) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Zn(1), one H(4), and one H(5) atom. Linkers: 1 [O]C(=O)c1cc(C(=O)O)c(C([O])=O)cc1C(=O)O. Metal clusters: 1 [Zn]. The MOF has largest included sphere 2.58 A, density 1.61 g/cm3, surface area 4249.54 m2/g, accessible volume 0.12 cm3/g