CuC14H12Br(NO2)2CuC9H8Br(NO)2C5H4O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two methyl methacrylate molecules, one CuC14H12Br(NO2)2 cluster, and one CuC9H8Br(NO)2 cluster. In the CuC14H12Br(NO2)2 cluster, Cu(1) is bonded to one N(1), one N(2), and two equivalent Br(1) atoms to form distorted edge-sharing CuBr2N2 tetrahedra. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-N(2) bond length is 1.97 Å. There is one shorter (2.48 Å) and one longer (2.56 Å) Cu(1)-Br(1) bond length. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.49 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.36 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.22 Å. The C(6)-O(2) bond length is 1.36 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(6), and one O(2) atom. The C(7)-H(5) bond length is 1.09 Å. The C(7)-H(6) bond length is 1.10 Å. The C(7)-O(2) bond length is 1.45 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(7) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(8) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(13) bond length is 1.49 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(9) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(9) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(2), and one H(10) atom. The C(12)-N(2) bond length is 1.36 Å. The C(12)-H(10) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a bent 120 degrees geometry to one C(10), one O(3), and one O(4) atom. The C(13)-O(3) bond length is 1.23 Å. The C(13)-O(4) bond length is 1.36 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one H(11), one H(12), and one O(4) atom. The C(14)-H(11) bond length is 1.10 Å. The C(14)-H(12) bond length is 1.10 Å. The C(14)-O(4) bond length is 1.45 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(12), and one C(8) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(6) and one C(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(13) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(13) and one C(14) atom. Br(1) is bonded in a distorted L-shaped geometry to two equivalent Cu(1) atoms. In the CuC9H8Br(NO)2 cluster, Cu(2) is bonded to one N(3), one N(4), and two equivalent Br(2) atoms to form distorted edge-sharing CuBr2N2 tetrahedra. The Cu(2)-N(3) bond length is 1.98 Å. The Cu(2)-N(4) bond length is 1.98 Å. There is one shorter (2.46 Å) and one longer (2.56 Å) Cu(2)-Br(2) bond length. There are nine inequivalent C sites. In the first C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one N(3), and one H(13) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-N(3) bond length is 1.35 Å. The C(15)-H(13) bond length is 1.09 Å. In the second C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(14) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(14) bond length is 1.09 Å. In the third C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(20) bond length is 1.49 Å. In the fourth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(15) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(15) bond length is 1.09 Å. In the fifth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(3), and one H(16) atom. The C(19)-N(3) bond length is 1.35 Å. The C(19)-H(16) bond length is 1.09 Å. In the sixth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(5), and one O(6) atom. The C(20)-O(5) bond length is 1.23 Å. The C(20)-O(6) bond length is 1.35 Å. In the seventh C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one H(17), one H(18), and one O(6) atom. The C(21)-H(17) bond length is 1.10 Å. The C(21)-H(18) bond length is 1.10 Å. The C(21)-O(6) bond length is 1.45 Å. In the eighth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(19) atom. The C(22)-N(4) bond length is 1.35 Å. The C(22)-H(19) bond length is 1.09 Å. In the ninth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(22) atom. The C(26)-N(4) bond length is 1.35 Å. The C(26)-H(22) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Cu(2), one C(15), and one C(19) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(22), and one C(26) atom. There are eight inequivalent H sites. In the first H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the second H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(22) is bonded in a single-bond geometry to one C(26) atom. There are two inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one C(20) atom. In the second O site, O(6) is bonded in a bent 120 degrees geometry to one C(20) and one C(21) atom. Br(2) is bonded in a 2-coordinate geometry to two equivalent Cu(2) atoms. Linkers: 4 O=C(OCCOC(=O)c1ccncc1)c1ccncc1. Metal clusters: 1 [Cu]Br.[Cu]Br ,1 Br[Cu][Cu]Br. The MOF has largest included sphere 4.54 A, density 1.52 g/cm3, surface area 4225.76 m2/g, accessible volume 0.26 cm3/g