CdC27N4H22O7(CH)4(CH2)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four 02329_fluka molecules, and one CdC27N4H22O7 cluster. In the CdC27N4H22O7 cluster, Cd(1) is bonded in a distorted pentagonal pyramidal geometry to one N(1), one N(3), one O(1), one O(4), one O(5), and one O(7) atom. The Cd(1)-N(1) bond length is 2.29 Å. The Cd(1)-N(3) bond length is 2.26 Å. The Cd(1)-O(1) bond length is 2.41 Å. The Cd(1)-O(4) bond length is 2.50 Å. The Cd(1)-O(5) bond length is 2.37 Å. The Cd(1)-O(7) bond length is 2.33 Å. There are twenty-seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(1)-C(4) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.31 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(7) atom. The C(2)-C(12) bond length is 1.52 Å. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.43 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one O(3) atom. The C(3)-C(4) bond length is 1.44 Å. The C(3)-O(3) bond length is 1.36 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(5) atom. The C(4)-C(5) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(5) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(5), and one C(7) atom. The C(6)-C(11) bond length is 1.42 Å. The C(6)-C(7) bond length is 1.44 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(8) atom. The C(7)-C(8) bond length is 1.42 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(6) and one H(9) atom. The C(11)-H(9) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a water-like geometry to one C(14), one C(2), one H(10), and one H(11) atom. The C(12)-C(14) bond length is 1.52 Å. The C(12)-H(10) bond length is 1.10 Å. The C(12)-H(11) bond length is 1.10 Å. In the eleventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(4), and one O(5) atom. The C(13)-C(16) bond length is 1.48 Å. The C(13)-O(4) bond length is 1.29 Å. The C(13)-O(5) bond length is 1.27 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(19) bond length is 1.43 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one O(6) atom. The C(15)-C(16) bond length is 1.43 Å. The C(15)-O(6) bond length is 1.36 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(16)-C(17) bond length is 1.38 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(12) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-H(12) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(23) atom. The C(18)-C(19) bond length is 1.44 Å. The C(18)-C(23) bond length is 1.42 Å. In the seventeenth C site, C(19) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(20) atom. The C(19)-C(20) bond length is 1.42 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(13) atom. The C(20)-H(13) bond length is 1.09 Å. In the nineteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(16) atom. The C(23)-H(16) bond length is 1.09 Å. In the twentieth C site, C(24) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(17) atom. The C(24)-N(1) bond length is 1.33 Å. The C(24)-N(2) bond length is 1.36 Å. The C(24)-H(17) bond length is 1.08 Å. In the twenty-first C site, C(25) is bonded in a 3-coordinate geometry to one C(26), one N(1), and one H(18) atom. The C(25)-C(26) bond length is 1.37 Å. The C(25)-N(1) bond length is 1.38 Å. The C(25)-H(18) bond length is 1.08 Å. In the twenty-second C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(25), one N(2), and one H(19) atom. The C(26)-N(2) bond length is 1.38 Å. The C(26)-H(19) bond length is 1.08 Å. In the twenty-third C site, C(27) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(20), and one H(21) atom. The C(27)-N(2) bond length is 1.46 Å. The C(27)-H(20) bond length is 1.10 Å. The C(27)-H(21) bond length is 1.10 Å. In the twenty-fourth C site, C(29) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(24) atom. The C(29)-N(3) bond length is 1.33 Å. The C(29)-N(4) bond length is 1.35 Å. The C(29)-H(24) bond length is 1.08 Å. In the twenty-fifth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(31), one N(4), and one H(25) atom. The C(30)-C(31) bond length is 1.37 Å. The C(30)-N(4) bond length is 1.38 Å. The C(30)-H(25) bond length is 1.08 Å. In the twenty-sixth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(30), one N(3), and one H(26) atom. The C(31)-N(3) bond length is 1.38 Å. The C(31)-H(26) bond length is 1.08 Å. In the twenty-seventh C site, C(32) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(27), and one H(28) atom. The C(32)-N(4) bond length is 1.46 Å. The C(32)-H(27) bond length is 1.10 Å. The C(32)-H(28) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(24), and one C(25) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(27) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(29), and one C(31) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(29), one C(30), and one C(32) atom. There are twenty-two inequivalent H sites. In the first H site, H(1) is bonded in a distorted bent 150 degrees geometry to one O(2) and one O(3) atom. The H(1)-O(2) bond length is 1.59 Å. The H(1)-O(3) bond length is 1.01 Å. In the second H site, H(2) is bonded in a bent 150 degrees geometry to one O(4) and one O(6) atom. The H(2)-O(4) bond length is 1.56 Å. The H(2)-O(6) bond length is 1.02 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(2) and one O(7) atom. The H(3)-O(2) bond length is 1.63 Å. The H(3)-O(7) bond length is 1.01 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(7) atom. The H(4)-O(7) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(27) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(27) atom. In the eighteenth H site, H(24) is bonded in a single-bond geometry to one C(29) atom. In the nineteenth H site, H(25) is bonded in a single-bond geometry to one C(30) atom. In the twentieth H site, H(26) is bonded in a single-bond geometry to one C(31) atom. In the twenty-first H site, H(27) is bonded in a single-bond geometry to one C(32) atom. In the twenty-second H site, H(28) is bonded in a single-bond geometry to one C(32) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one C(1), one H(1), and one H(3) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(3) and one H(1) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Cd(1), one C(13), and one H(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one C(13) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one C(15) and one H(2) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Cd(1), one H(3), and one H(4) atom. Linkers: 2 c1cn(CCCCn2ccnc2)cn1 ,2 [O]C(=O)c1cc2ccccc2c(Cc2c(O)c(C([O])=O)cc3ccccc23)c1O. Metal clusters: 2 O.[O][C]O[Cd]1O[C]O1. The MOF has largest included sphere 2.74 A, density 1.58 g/cm3, surface area 4553.10 m2/g, accessible volume 0.15 cm3/g