CuC20N4H12O5(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CuC20N4H12O5 clusters. In each CuC20N4H12O5 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(2), one N(3), one N(4), one O(1), and one O(5) atom. The Cu(1)-N(2) bond length is 2.03 Å. The Cu(1)-N(3) bond length is 1.92 Å. The Cu(1)-N(4) bond length is 2.02 Å. The Cu(1)-O(1) bond length is 2.27 Å. The Cu(1)-O(5) bond length is 1.94 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(2) atom. The C(5)-C(6) bond length is 1.47 Å. The C(5)-N(2) bond length is 1.36 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one N(3) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-N(3) bond length is 1.34 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-H(5) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(16), one C(7), and one C(9) atom. The C(8)-C(16) bond length is 1.47 Å. The C(8)-C(9) bond length is 1.41 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(6) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one N(3) atom. The C(10)-C(11) bond length is 1.47 Å. The C(10)-N(3) bond length is 1.34 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(4) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(4) bond length is 1.36 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(9) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(4), and one H(10) atom. The C(15)-N(4) bond length is 1.34 Å. The C(15)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(17), one C(21), and one C(8) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(21) bond length is 1.40 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(11,14) atom. The C(17)-H(11,14) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(12) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-H(12) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(22) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-C(22) bond length is 1.50 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(13) atom. The C(20)-H(13) bond length is 1.09 Å. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(11,14) atom. The C(21)-H(11,14) bond length is 1.09 Å. In the twentieth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(4), and one O(5) atom. The C(22)-O(4) bond length is 1.25 Å. The C(22)-O(5) bond length is 1.30 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(1)-O(1) bond length is 1.29 Å. The N(1)-O(2) bond length is 1.26 Å. The N(1)-O(3) bond length is 1.27 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(15) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11,14) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(20) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(22) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(22) atom. Linkers: 1 [O]C(=O)c1ccc(-c2cc(-c3ccccn3)nc(-c3ccccn3)c2)cc1. Metal clusters: 1 [Cu] ,1 O=[C]O[Cu]O[N+](=O)[O-]. The MOF has largest included sphere 2.56 A, density 1.67 g/cm3, surface area 4075.03 m2/g, accessible volume 0.09 cm3/g