(CH)4ZnC4H4(NCl)2C3N2H2O is Indium-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules; eight 1,3-dimethylurea molecules; and eight ZnC4H4(NCl)2 clusters. In each ZnC4H4(NCl)2 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent Cl(1) atoms. Both Zn(1)-N(1) bond lengths are 2.05 Å. Both Zn(1)-Cl(1) bond lengths are 2.24 Å. There are two inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 1 O=C(Nc1cccnc1)Nc1cccnc1 ,2 [C]/N=C\C(=[NH]/C(=O)Nc1cccnc1)\[CH]. Metal clusters: 2 Cl[Zn]Cl. The MOF has largest included sphere 3.01 A, density 1.65 g/cm3, surface area 4385.78 m2/g, accessible volume 0.24 cm3/g