CuC14H8(NO2)2(CH)8 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight isobutylene molecules and four CuC14H8(NO2)2 clusters. In each CuC14H8(NO2)2 cluster, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one O(1), and one O(3) atom. The Cu(1)-N(1) bond length is 2.02 Å. The Cu(1)-N(2) bond length is 2.02 Å. The Cu(1)-O(1) bond length is 1.97 Å. The Cu(1)-O(3) bond length is 1.97 Å. There are fourteen inequivalent C sites. In the first C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(13) atom. The C(16)-C(17) bond length is 1.43 Å. The C(16)-H(13) bond length is 1.09 Å. In the second C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(21) atom. The C(17)-C(18) bond length is 1.42 Å. The C(17)-C(21) bond length is 1.41 Å. In the third C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(14) atom. The C(18)-C(19) bond length is 1.38 Å. The C(18)-H(14) bond length is 1.09 Å. In the fourth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(15) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-H(15) bond length is 1.09 Å. In the fifth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one N(2), and one H(16) atom. The C(20)-N(2) bond length is 1.33 Å. The C(20)-H(16) bond length is 1.09 Å. In the sixth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(17), one C(22), and one N(2) atom. The C(21)-C(22) bond length is 1.43 Å. The C(21)-N(2) bond length is 1.36 Å. In the seventh C site, C(22) is bonded in a distorted trigonal planar geometry to one C(14), one C(21), and one N(1) atom. The C(22)-C(14) bond length is 1.42 Å. The C(22)-N(1) bond length is 1.36 Å. In the eighth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(10)-O(3) bond length is 1.30 Å. The C(10)-O(4) bond length is 1.25 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one N(1) and one H(9) atom. The C(11)-N(1) bond length is 1.33 Å. The C(11)-H(9) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-H(10) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(11) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-H(11) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(22) atom. The C(14)-C(15) bond length is 1.43 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(12) atom. The C(15)-H(12) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(22) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(20), and one C(21) atom. There are eight inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cu(1) and one C(10) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(10) atom. Linkers: 4 [O]C(=O)Cc1ccc(CC([O])=O)cc1 ,1 c1cnc2c(c1)ccc1cccnc12. Metal clusters: 1 [Cu] ,3 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 3.01 A, density 1.50 g/cm3, surface area 4513.41 m2/g, accessible volume 0.20 cm3/g