CuC14H10(N2Br)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CuC14H10(N2Br)2 clusters. Cu(1) is bonded in a distorted square co-planar geometry to two equivalent N(2) and two equivalent Br(1) atoms. Both Cu(1)-N(2) bond lengths are 2.00 Å. Both Cu(1)-Br(1) bond lengths are 2.45 Å. There are seven inequivalent C sites. In the first C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(3) bond length is 1.09 Å. In the second C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(5)-C(2) bond length is 1.47 Å. The C(5)-C(6) bond length is 1.41 Å. The C(5)-C(7) bond length is 1.41 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the fifth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the sixth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(5) atom. The C(2)-C(3) bond length is 1.40 Å. In the seventh C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one N(1) atom. The N(2)-N(1) bond length is 1.33 Å. In the second N site, N(1) is bonded in a distorted bent 120 degrees geometry to one C(4) and one N(2) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. Br(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 4 [CH]/C(=C\[N])c1ccc(-c2ccnnc2)cc1 ,2 c1cc(-c2ccc(-c3ccnnc3)cc2)cnn1. Metal clusters: 2 Br[Cu]Br. The MOF has largest included sphere 1.54 A, density 2.24 g/cm3, surface area 3456.52 m2/g, accessible volume 0.10 cm3/g