RbC17H12(NO3)4(CH)7 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of fourteen 02329_fluka molecules and one RbC17H12(NO3)4 cluster. In the RbC17H12(NO3)4 cluster, Rb(1) is bonded in a 9-coordinate geometry to one O(11), one O(3), one O(5), one O(6), one O(8), two equivalent O(10), and two equivalent O(2) atoms. The Rb(1)-O(11) bond length is 2.85 Å. The Rb(1)-O(3) bond length is 3.05 Å. The Rb(1)-O(5) bond length is 2.93 Å. The Rb(1)-O(6) bond length is 3.26 Å. The Rb(1)-O(8) bond length is 3.22 Å. There is one shorter (3.11 Å) and one longer (3.35 Å) Rb(1)-O(10) bond length. There is one shorter (2.86 Å) and one longer (3.31 Å) Rb(1)-O(2) bond length. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one O(1) atom. The C(1)-C(6) bond length is 1.41 Å. The C(1)-O(1) bond length is 1.35 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(2) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(1) bond length is 1.43 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(3) atom. The C(5)-C(6) bond length is 1.38 Å. The C(5)-H(3) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one O(4) atom. The C(7)-O(4) bond length is 1.31 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(6) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-H(6) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one N(2) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-N(2) bond length is 1.41 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one O(7) atom. The C(13)-O(7) bond length is 1.33 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(10) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(10) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one N(3) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-N(3) bond length is 1.44 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(17)-H(11) bond length is 1.09 Å. In the fourteenth C site, C(19) is bonded in a distorted single-bond geometry to one O(10) atom. The C(19)-O(10) bond length is 1.35 Å. In the fifteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(14) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-H(14) bond length is 1.09 Å. In the sixteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one N(4) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-N(4) bond length is 1.43 Å. In the seventeenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(15) atom. The C(23)-H(15) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(4), one O(2), and one O(3) atom. The N(1)-O(2) bond length is 1.26 Å. The N(1)-O(3) bond length is 1.25 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one O(5), and one O(6) atom. The N(2)-O(5) bond length is 1.25 Å. The N(2)-O(6) bond length is 1.27 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(16), one O(8), and one O(9) atom. The N(3)-O(8) bond length is 1.25 Å. The N(3)-O(9) bond length is 1.25 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(22), one O(11), and one O(12) atom. The N(4)-O(11) bond length is 1.25 Å. The N(4)-O(12) bond length is 1.25 Å. There are twelve inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one O(1) atom. The H(17)-O(1) bond length is 1.00 Å. In the eleventh H site, H(18) is bonded in a linear geometry to one O(4) and one O(7) atom. The H(18)-O(4) bond length is 1.52 Å. The H(18)-O(7) bond length is 1.04 Å. In the twelfth H site, H(19) is bonded in a linear geometry to one O(10) and one O(4) atom. The H(19)-O(10) bond length is 1.05 Å. The H(19)-O(4) bond length is 1.47 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(1) and one H(17) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Rb(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one C(7), one H(18), and one H(19) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Rb(1) and one N(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Rb(1) and one N(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one C(13) and one H(18) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Rb(1) and one N(3) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one N(3) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to two equivalent Rb(1), one C(19), and one H(19) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Rb(1) and one N(4) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one N(4) atom. Linkers: 6 O=[N+]([O-])c1ccc(O)cc1. Metal clusters: 2 [Rb]. The MOF has largest included sphere 2.03 A, density 1.66 g/cm3, surface area 4620.41 m2/g, accessible volume 0.10 cm3/g