Zn3C16H9(N3O)4(CH)5 crystallizes in the triclinic P-1 space group. The structure consists of ten 02329_fluka molecules inside a Zn3C16H9(N3O)4 framework. In the Zn3C16H9(N3O)4 framework, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(1), one N(6), one N(9), one O(1), and one O(4) atom to form ZnN3O2 trigonal bipyramids that share  a cornercorner with one Zn(3)N2O3 trigonal bipyramid and  a cornercorner with one Zn(2)N3O2 trigonal bipyramid. The Zn(1)-N(1) bond length is 2.06 Å. The Zn(1)-N(6) bond length is 2.07 Å. The Zn(1)-N(9) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 2.11 Å. The Zn(1)-O(4) bond length is 2.08 Å. In the second Zn site, Zn(2) is bonded to one N(11), one N(4), one N(5), one O(1), and one O(2) atom to form ZnN3O2 trigonal bipyramids that share  a cornercorner with one Zn(3)N2O3 trigonal bipyramid and  a cornercorner with one Zn(1)N3O2 trigonal bipyramid. The Zn(2)-N(11) bond length is 2.06 Å. The Zn(2)-N(4) bond length is 2.03 Å. The Zn(2)-N(5) bond length is 2.02 Å. The Zn(2)-O(1) bond length is 2.10 Å. The Zn(2)-O(2) bond length is 2.16 Å. In the third Zn site, Zn(3) is bonded to one N(12), one N(2), one O(2), one O(3), and one O(4) atom to form corner-sharing ZnN2O3 trigonal bipyramids. The Zn(3)-N(12) bond length is 2.02 Å. The Zn(3)-N(2) bond length is 2.03 Å. The Zn(3)-O(2) bond length is 2.08 Å. The Zn(3)-O(3) bond length is 1.99 Å. The Zn(3)-O(4) bond length is 2.22 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one O(1) atom. The C(1)-C(6) bond length is 1.43 Å. The C(1)-O(1) bond length is 1.33 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.45 Å. In the sixth C site, C(7) is bonded in a distorted water-like geometry to one C(6), one N(1), and one N(4) atom. The C(7)-N(1) bond length is 1.34 Å. The C(7)-N(4) bond length is 1.36 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(13) and one O(2) atom. The C(8)-C(13) bond length is 1.43 Å. The C(8)-O(2) bond length is 1.34 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(6) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(7) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(7) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(8) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-H(8) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(8) atom. The C(13)-C(14) bond length is 1.45 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(5), and one N(8) atom. The C(14)-N(5) bond length is 1.35 Å. The C(14)-N(8) bond length is 1.36 Å. In the thirteenth C site, C(15) is bonded in a distorted water-like geometry to one C(16), one N(12), and one N(9) atom. The C(15)-C(16) bond length is 1.45 Å. The C(15)-N(12) bond length is 1.34 Å. The C(15)-N(9) bond length is 1.36 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.43 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(9) atom. The C(17)-H(9) bond length is 1.09 Å. In the sixteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one O(4) atom. The C(21)-O(4) bond length is 1.33 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Zn(1), one C(7), and one N(2) atom. The N(1)-N(2) bond length is 1.35 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(3), one N(1), and one N(3) atom. The N(2)-N(3) bond length is 1.31 Å. In the third N site, N(3) is bonded in a water-like geometry to one N(2) and one N(4) atom. The N(3)-N(4) bond length is 1.34 Å. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one Zn(2), one C(7), and one N(3) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(14), and one N(6) atom. The N(5)-N(6) bond length is 1.34 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(1), one N(5), and one N(7) atom. The N(6)-N(7) bond length is 1.31 Å. In the seventh N site, N(7) is bonded in a distorted water-like geometry to one N(6) and one N(8) atom. The N(7)-N(8) bond length is 1.33 Å. In the eighth N site, N(8) is bonded in a 3-coordinate geometry to one C(14), one N(7), and one H(13) atom. The N(8)-H(13) bond length is 1.62 Å. In the ninth N site, N(9) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(15), and one N(10) atom. The N(9)-N(10) bond length is 1.35 Å. In the tenth N site, N(10) is bonded in a water-like geometry to one N(11) and one N(9) atom. The N(10)-N(11) bond length is 1.31 Å. In the eleventh N site, N(11) is bonded in a distorted trigonal planar geometry to one Zn(2), one N(10), and one N(12) atom. The N(11)-N(12) bond length is 1.34 Å. In the twelfth N site, N(12) is bonded in a 3-coordinate geometry to one Zn(3), one C(15), and one N(11) atom. There are nine inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(13) is bonded in a distorted linear geometry to one N(8) and one O(3) atom. The H(13)-O(3) bond length is 1.02 Å. In the ninth H site, H(14) is bonded in a single-bond geometry to one O(3) atom. The H(14)-O(3) bond length is 0.99 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one C(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Zn(2), one Zn(3), and one C(8) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Zn(3), one H(13), and one H(14) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(3), and one C(21) atom. Linkers: 6 [O]c1ccccc1C1=NN=N[N]1. Metal clusters: 6 [Zn]. The MOF has largest included sphere 2.79 A, density 1.96 g/cm3, surface area 3435.29 m2/g, accessible volume 0.12 cm3/g