NiC16H18(NO)4(CH2)10(CH3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules, two 02329_fluka molecules, and one NiC16H18(NO)4 cluster. In the NiC16H18(NO)4 cluster, Ni(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Ni(1)-N(1) bond lengths are 1.95 Å. Both Ni(1)-N(2) bond lengths are 1.94 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one N(1) and one H(3) atom. The C(1)-N(1) bond length is 1.49 Å. The C(1)-H(3) bond length is 1.11 Å. In the second C site, C(6) is bonded in a distorted water-like geometry to one N(2) and one H(12) atom. The C(6)-N(2) bond length is 1.48 Å. The C(6)-H(12) bond length is 1.10 Å. In the third C site, C(7) is bonded in a 2-coordinate geometry to one N(2) and one H(13) atom. The C(7)-N(2) bond length is 1.49 Å. The C(7)-H(13) bond length is 1.10 Å. In the fourth C site, C(10) is bonded in a 3-coordinate geometry to one N(1), one H(19), and one H(20) atom. The C(10)-N(1) bond length is 1.47 Å. The C(10)-H(19) bond length is 1.10 Å. The C(10)-H(20) bond length is 1.10 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(11)-C(12) bond length is 1.51 Å. The C(11)-O(1) bond length is 1.28 Å. The C(11)-O(2) bond length is 1.27 Å. In the sixth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(14) bond length is 1.40 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(21) atom. The C(13)-H(21) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(22) atom. The C(14)-H(22) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Ni(1), one C(1), one C(10), and one H(1) atom to form distorted corner-sharing NNiHC2 tetrahedra. The N(1)-H(1) bond length is 1.07 Å. In the second N site, N(2) is bonded to one Ni(1), one C(6), one C(7), and one H(2) atom to form distorted corner-sharing NNiHC2 tetrahedra. The N(2)-H(2) bond length is 1.05 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one N(1) and one O(2) atom. The H(1)-O(2) bond length is 1.67 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(21) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(22) is bonded in a single-bond geometry to one C(14) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one C(11) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(11) and one H(1) atom. Linkers: 1 [CH][C@H]1N[C@H](C)CCN[C@H]2CCCC[C@@H]2N[C@@H](C)CCN[C@@H]1[CH2] ,1 C[C@@H]1CCN[C@H]2CCCC[C@@H]2N[C@@H](C)CCN[C@@H]2CCCC[C@H]2N1 ,1 [CH][C@H]1NCC[C@H](C)N[C@H]2CCCC[C@@H]2NCC[C@@H](C)N[C@@H]1[CH] ,1 [CH][C@H]1NCC[C@H](C)N[C@H]2CCCC[C@@H]2NCC[C@@H](C)N[C@@H]1C[CH2] ,1 [CH][C@@H]1NCC[C@@H](C)N[C@@H]2CCCC[C@H]2NCC[C@H](C)N[C@H]1C[CH2] ,1 [CH][C@@H]1NCC[C@@H](C)N[C@@H]2CCCC[C@H]2NCC[C@H](C)N[C@H]1[CH] ,1 [CH][C@@H]1N[C@@H](C)CCN[C@@H]2CCCC[C@H]2N[C@H](C)CCN[C@H]1[CH2]. Metal clusters: 1 [NH][Ni]([NH])([NH])[NH]. The MOF has largest included sphere 2.41 A, density 1.29 g/cm3, surface area 5358.17 m2/g, accessible volume 0.25 cm3/g