ZnC8H8(NO)4(CH)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two isobutylene molecules and two ZnC8H8(NO)4 clusters. In each ZnC8H8(NO)4 cluster, Zn(1) is bonded in a 6-coordinate geometry to one N(3), one N(4), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(3) bond length is 2.06 Å. The Zn(1)-N(4) bond length is 2.06 Å. The Zn(1)-O(1) bond length is 2.32 Å. The Zn(1)-O(2) bond length is 2.16 Å. The Zn(1)-O(3) bond length is 2.54 Å. The Zn(1)-O(4) bond length is 2.07 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(1) atom. The C(1)-N(4) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(4) atom. The C(5)-N(4) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the third C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(3), and one H(7) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-N(3) bond length is 1.35 Å. The C(7)-H(7) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(8) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(8) bond length is 1.09 Å. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(12) bond length is 1.50 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(9) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(9) bond length is 1.09 Å. In the seventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(3), and one H(10) atom. The C(11)-N(3) bond length is 1.35 Å. The C(11)-H(10) bond length is 1.09 Å. In the eighth C site, C(12) is bonded in a distorted water-like geometry to one C(9), one H(11), and one H(12) atom. The C(12)-H(11) bond length is 1.10 Å. The C(12)-H(12) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. The N(1)-O(1) bond length is 1.26 Å. The N(1)-O(2) bond length is 1.28 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one O(3) and one O(4) atom. The N(2)-O(3) bond length is 1.25 Å. The N(2)-O(4) bond length is 1.30 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Zn(1) and one N(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Zn(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zn(1) and one N(2) atom. Linkers: 2 c1cc(CCc2ccncc2)ccn1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.83 A, density 1.68 g/cm3, surface area 4835.31 m2/g, accessible volume 0.12 cm3/g