(FeC31H24S2(N3O4)2)2C29H24(NO2)4 crystallizes in the tetragonal P4_2/n space group. The structure consists of two schembl13318829 molecules inside a FeC31H24S2(N3O4)2 framework. In each FeC31H24S2(N3O4)2 framework, Fe(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. Both Fe(1)-N(1) bond lengths are 2.23 Å. Both Fe(1)-N(2) bond lengths are 2.20 Å. Both Fe(1)-N(3) bond lengths are 2.03 Å. There are sixteen inequivalent C sites. In the first C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one N(1), and one H(11) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-N(1) bond length is 1.35 Å. The C(15)-H(11) bond length is 1.09 Å. In the second C site, C(16) is bonded in a distorted single-bond geometry to one C(12), one C(15), and one H(12) atom. The C(16)-C(12) bond length is 1.40 Å. The C(16)-H(12) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted linear geometry to one N(3) and one S(1) atom. The C(1)-N(3) bond length is 1.20 Å. The C(1)-S(1) bond length is 1.60 Å. In the fourth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(6), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(6) bond length is 1.40 Å. The C(2)-H(1) bond length is 1.09 Å. In the fifth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(2) atom. The C(3)-N(2) bond length is 1.35 Å. The C(3)-H(2) bond length is 1.09 Å. In the sixth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(2), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-N(2) bond length is 1.35 Å. The C(4)-H(3) bond length is 1.09 Å. In the seventh C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the eighth C site, C(6) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.49 Å. In the ninth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.23 Å. The C(7)-O(2) bond length is 1.35 Å. In the tenth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(5), one H(6), and one O(2) atom. The C(8)-C(9) bond length is 1.53 Å. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-O(2) bond length is 1.45 Å. In the eleventh C site, C(9) is bonded in a tetrahedral geometry to two equivalent C(10) and two equivalent C(8) atoms. Both C(9)-C(10) bond lengths are 1.54 Å. In the twelfth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(7), one H(8), and one O(3) atom. The C(10)-H(7) bond length is 1.10 Å. The C(10)-H(8) bond length is 1.10 Å. The C(10)-O(3) bond length is 1.45 Å. In the thirteenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(3), and one O(4) atom. The C(11)-C(12) bond length is 1.49 Å. The C(11)-O(3) bond length is 1.35 Å. The C(11)-O(4) bond length is 1.22 Å. In the fourteenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(16) atom. The C(12)-C(13) bond length is 1.40 Å. In the fifteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(9) atom. The C(13)-H(9) bond length is 1.09 Å. In the sixteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(10) atom. The C(14)-N(1) bond length is 1.35 Å. The C(14)-H(10) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Fe(1), one C(14), and one C(15) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Fe(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one Fe(1) and one C(1) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one C(10) and one C(11) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(11) atom. In the third O site, O(1) is bonded in a single-bond geometry to one C(7) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one C(7) and one C(8) atom. Linkers: 4 O=C(OCC(COC(=O)c1ccncc1)(COC(=O)c1ccncc1)COC(=O)c1ccncc1)c1ccncc1. Metal clusters: 4 [Fe]. The MOF has largest included sphere 3.12 A, density 1.41 g/cm3, surface area 4784.78 m2/g, accessible volume 0.23 cm3/g