SnC4H8(OBr2)2 is Indium-like structured and crystallizes in the orthorhombic Pbcn space group. The structure is zero-dimensional and consists of four SnC4H8(OBr2)2 clusters. Sn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent Br(1), and two equivalent Br(2) atoms. Both Sn(1)-O(1) bond lengths are 2.37 Å. Both Sn(1)-Br(1) bond lengths are 2.55 Å. Both Sn(1)-Br(2) bond lengths are 2.56 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one O(1) atom. The C(1)-H(1) bond length is 1.09 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-O(1) bond length is 1.46 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(4), and one O(1) atom. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. The C(2)-O(1) bond length is 1.45 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. O(1) is bonded in a distorted trigonal planar geometry to one Sn(1), one C(1), and one C(2) atom. There are two inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one Sn(1) atom. In the second Br site, Br(1) is bonded in a single-bond geometry to one Sn(1) atom. Linkers: 3 C1COCCO1. Metal clusters: 1 Br[Sn](Br)Br.Br[Sn](Br)Br.C1COCCO1.[Br].[Br] ,2 Br[Sn](Br)(Br)Br. The MOF has largest included sphere 1.94 A, density 3.15 g/cm3, surface area 2320.14 m2/g, accessible volume 0.08 cm3/g