ZnC10H12S2(N2O)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC10H12S2(N2O)4 clusters. Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Zn(1)-N(1) bond length is 2.00 Å. The Zn(1)-N(2) bond length is 2.00 Å. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(2) bond length is 2.01 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(3), one N(5), and one S(1) atom. The C(1)-N(3) bond length is 1.32 Å. The C(1)-N(5) bond length is 1.37 Å. The C(1)-S(1) bond length is 1.73 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one N(5) atom. The C(2)-C(6) bond length is 1.49 Å. The C(2)-N(1) bond length is 1.33 Å. The C(2)-N(5) bond length is 1.37 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one N(6) atom. The C(3)-C(4) bond length is 1.48 Å. The C(3)-N(2) bond length is 1.33 Å. The C(3)-N(6) bond length is 1.37 Å. In the fourth C site, C(4) is bonded in a distorted water-like geometry to one C(3), one H(5), and one H(6) atom. The C(4)-H(5) bond length is 1.10 Å. The C(4)-H(6) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(6), one N(8), and one S(2) atom. The C(5)-N(6) bond length is 1.38 Å. The C(5)-N(8) bond length is 1.32 Å. The C(5)-S(2) bond length is 1.73 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one C(2), one H(7), and one H(8) atom. The C(6)-H(7) bond length is 1.09 Å. The C(6)-H(8) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted water-like geometry to one H(10), one H(9), and one S(1) atom. The C(7)-H(10) bond length is 1.10 Å. The C(7)-H(9) bond length is 1.10 Å. The C(7)-S(1) bond length is 1.80 Å. In the eighth C site, C(8) is bonded in a distorted water-like geometry to one H(11), one H(12), and one S(2) atom. The C(8)-H(11) bond length is 1.10 Å. The C(8)-H(12) bond length is 1.09 Å. The C(8)-S(2) bond length is 1.81 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(9)-O(1) bond length is 1.29 Å. The C(9)-O(3) bond length is 1.26 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(10)-O(2) bond length is 1.29 Å. The C(10)-O(4) bond length is 1.25 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(2), and one N(3) atom. The N(1)-N(3) bond length is 1.38 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(3), and one N(8) atom. The N(2)-N(8) bond length is 1.38 Å. In the third N site, N(3) is bonded in a distorted single-bond geometry to one C(1) and one N(1) atom. In the fourth N site, N(4) is bonded in a distorted water-like geometry to one N(5), one H(1), and one H(2) atom. The N(4)-N(5) bond length is 1.39 Å. The N(4)-H(1) bond length is 1.03 Å. The N(4)-H(2) bond length is 1.03 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(1), one C(2), and one N(4) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(7) atom. The N(6)-N(7) bond length is 1.39 Å. In the seventh N site, N(7) is bonded in a distorted bent 120 degrees geometry to one N(6), one H(3), and one H(4) atom. The N(7)-H(3) bond length is 1.03 Å. The N(7)-H(4) bond length is 1.04 Å. In the eighth N site, N(8) is bonded in a distorted water-like geometry to one C(5) and one N(2) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(8) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(1) and one C(7) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(5) and one C(8) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(9) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(10) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(10) atom. Linkers: 2 Nn1c(CCc2nnc(SCC([O])=O)n2N)nnc1SCC([O])=O. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.54 A, density 1.85 g/cm3, surface area 3649.18 m2/g, accessible volume 0.12 cm3/g