(CH2)2Cu2C2H4SI2 crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of sixteen 02329_fluka molecules inside a Cu2C2H4SI2 framework. In the Cu2C2H4SI2 framework, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 4-coordinate geometry to one S(1), one I(1), one I(2), and one I(4) atom. The Cu(1)-S(1) bond length is 2.28 Å. The Cu(1)-I(1) bond length is 2.70 Å. The Cu(1)-I(2) bond length is 2.70 Å. The Cu(1)-I(4) bond length is 2.71 Å. In the second Cu site, Cu(2) is bonded in a 4-coordinate geometry to one S(2), one I(1), one I(2), and one I(3) atom. The Cu(2)-S(2) bond length is 2.29 Å. The Cu(2)-I(1) bond length is 2.69 Å. The Cu(2)-I(2) bond length is 2.69 Å. The Cu(2)-I(3) bond length is 2.67 Å. In the third Cu site, Cu(3) is bonded in a 4-coordinate geometry to one S(1), one I(1), one I(3), and one I(4) atom. The Cu(3)-S(1) bond length is 2.28 Å. The Cu(3)-I(1) bond length is 2.69 Å. The Cu(3)-I(3) bond length is 2.71 Å. The Cu(3)-I(4) bond length is 2.63 Å. In the fourth Cu site, Cu(4) is bonded in a 4-coordinate geometry to one S(2), one I(2), one I(3), and one I(4) atom. The Cu(4)-S(2) bond length is 2.27 Å. The Cu(4)-I(2) bond length is 2.61 Å. The Cu(4)-I(3) bond length is 2.68 Å. The Cu(4)-I(4) bond length is 2.78 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to two equivalent H(1,2) and one S(1) atom. Both C(1)-H(1,2) bond lengths are 1.10 Å. The C(1)-S(1) bond length is 1.83 Å. In the second C site, C(4) is bonded in a distorted water-like geometry to one H(7), one H(8), and one S(1) atom. The C(4)-H(7) bond length is 1.10 Å. The C(4)-H(8) bond length is 1.10 Å. The C(4)-S(1) bond length is 1.84 Å. In the third C site, C(5) is bonded in a distorted water-like geometry to one H(10), one H(9), and one S(2) atom. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. The C(5)-S(2) bond length is 1.83 Å. In the fourth C site, C(8) is bonded in a distorted water-like geometry to one H(15), one H(16), and one S(2) atom. The C(8)-H(15) bond length is 1.10 Å. The C(8)-H(16) bond length is 1.10 Å. The C(8)-S(2) bond length is 1.84 Å. There are seven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(8) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one Cu(1), one Cu(3), one C(1), and one C(4) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one Cu(2), one Cu(4), one C(5), and one C(8) atom. There are four inequivalent I sites. In the first I site, I(3) is bonded in a 3-coordinate geometry to one Cu(2), one Cu(3), and one Cu(4) atom. In the second I site, I(4) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(3), and one Cu(4) atom. In the third I site, I(1) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(2), and one Cu(3) atom. In the fourth I site, I(2) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(2), and one Cu(4) atom. Linkers: 8 C1CCSC1. Metal clusters: 16 [Cu]. The MOF has largest included sphere 2.29 A, density 3.47 g/cm3, surface area 2292.80 m2/g, accessible volume 0.05 cm3/g