AgC10N5H10S2O3(CH)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one AgC10N5H10S2O3 cluster. In the AgC10N5H10S2O3 cluster, Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(3), one S(1), and one O(1) atom. The Ag(1)-N(1) bond length is 2.27 Å. The Ag(1)-N(3) bond length is 2.22 Å. The Ag(1)-S(1) bond length is 2.70 Å. The Ag(1)-O(1) bond length is 2.43 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-S(1) bond length is 1.76 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one N(1) and one H(3) atom. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted water-like geometry to one H(4), one H(5), and one S(1) atom. The C(5)-H(4) bond length is 1.10 Å. The C(5)-H(5) bond length is 1.10 Å. The C(5)-S(1) bond length is 1.83 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one N(3), one N(4), and one S(2) atom. The C(7)-N(3) bond length is 1.36 Å. The C(7)-N(4) bond length is 1.33 Å. The C(7)-S(2) bond length is 1.75 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(3), and one H(7) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-N(3) bond length is 1.35 Å. The C(8)-H(7) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(8) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(8) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(4), and one H(9) atom. The C(10)-N(4) bond length is 1.34 Å. The C(10)-H(9) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted water-like geometry to one H(10), one H(11), and one S(2) atom. The C(11)-H(10) bond length is 1.10 Å. The C(11)-H(11) bond length is 1.10 Å. The C(11)-S(2) bond length is 1.83 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(7), and one C(8) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(10) and one C(7) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(5)-O(1) bond length is 1.28 Å. The N(5)-O(2) bond length is 1.26 Å. The N(5)-O(3) bond length is 1.27 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one C(1), and one C(5) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(11) and one C(7) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one N(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(5) atom. Linkers: 2 C(=C/CSc1ncccn1)\CSc1ncccn1. Metal clusters: 2 O=[N+]([O-])O[Ag]. The MOF has largest included sphere 2.04 A, density 1.95 g/cm3, surface area 3770.30 m2/g, accessible volume 0.08 cm3/g