MnC24PH14(NO3)2(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one MnC24PH14(NO3)2 cluster. In the MnC24PH14(NO3)2 cluster, Mn(1) is bonded to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(5) atom to form MnN2O4 octahedra that share corners with two equivalent P(1)C2O2 tetrahedra. The Mn(1)-N(1) bond length is 2.11 Å. The Mn(1)-N(2) bond length is 2.27 Å. The Mn(1)-O(1) bond length is 1.99 Å. The Mn(1)-O(2) bond length is 2.21 Å. The Mn(1)-O(3) bond length is 1.96 Å. The Mn(1)-O(5) bond length is 1.85 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one P(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-P(1) bond length is 1.83 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(7) bond length is 1.52 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(7)-O(3) bond length is 1.32 Å. The C(7)-O(4) bond length is 1.24 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(9), and one P(1) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. The C(8)-P(1) bond length is 1.81 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(9)-H(5) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6,7) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(6,7) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(14) bond length is 1.51 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(6,7) atom. The C(12)-H(6,7) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(13)-H(8) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(5), and one O(6) atom. The C(14)-O(5) bond length is 1.31 Å. The C(14)-O(6) bond length is 1.23 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(15)-N(1) bond length is 1.33 Å. The C(15)-H(9) bond length is 1.09 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(11) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-H(11) bond length is 1.09 Å. In the seventeenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(26) atom. The C(18)-C(19) bond length is 1.43 Å. The C(18)-C(26) bond length is 1.42 Å. In the eighteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(12) atom. The C(19)-H(12) bond length is 1.09 Å. In the nineteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(13) atom. The C(20)-C(21) bond length is 1.43 Å. The C(20)-H(13) bond length is 1.09 Å. In the twentieth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(25) atom. The C(21)-C(22) bond length is 1.41 Å. The C(21)-C(25) bond length is 1.42 Å. In the twenty-first C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(14) atom. The C(22)-H(14) bond length is 1.09 Å. In the twenty-second C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(16) atom. The C(24)-N(2) bond length is 1.33 Å. The C(24)-H(16) bond length is 1.09 Å. In the twenty-third C site, C(25) is bonded in a distorted single-bond geometry to one C(21), one C(26), and one N(2) atom. The C(25)-C(26) bond length is 1.44 Å. The C(25)-N(2) bond length is 1.36 Å. In the twenty-fourth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(18), one C(25), and one N(1) atom. The C(26)-N(1) bond length is 1.36 Å. P(1) is bonded to one C(1), one C(8), one O(1), and one O(2) atom to form PC2O2 tetrahedra that share corners with two equivalent Mn(1)N2O4 octahedra. The corner-sharing octahedral tilt angles range from 28-44°. The P(1)-O(1) bond length is 1.54 Å. The P(1)-O(2) bond length is 1.51 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(1), one C(15), and one C(26) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(24), and one C(25) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6,7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(14) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(14) atom. Linkers: 2 [O]C(=O)c1ccc(P([O])(=O)c2ccc(C([O])=O)cc2)cc1. Metal clusters: 1 O=[C]O[Mn]1(O[C]=O)O[P]O[Mn](O[C]=O)(O[C]=O)O[P]O1. RCSR code: kgd. The MOF has largest included sphere 2.40 A, density 1.60 g/cm3, surface area 4134.70 m2/g, accessible volume 0.15 cm3/g