ZnC10H10(NO)4(CH2)4 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four ZnC10H10(NO)4 clusters. In two of the ZnC10H10(NO)4 clusters, Zn(1,2) is bonded in a tetrahedral geometry to one N(1), one N(9), one O(1), and one O(9) atom. The Zn(1,2)-N(1) bond length is 2.01 Å. The Zn(1,2)-N(9) bond length is 2.01 Å. The Zn(1,2)-O(1) bond length is 1.98 Å. The Zn(1,2)-O(9) bond length is 1.97 Å. There are ten inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1,2)-O(1) bond length is 1.31 Å. The C(1,2)-O(3) bond length is 1.25 Å. In the second C site, C(9,10) is bonded in a distorted bent 120 degrees geometry to one O(11,12) and one O(9) atom. The C(9,10)-O(11,12) bond length is 1.26 Å. The C(9,10)-O(9) bond length is 1.30 Å. In the third C site, C(17,18) is bonded in a distorted bent 120 degrees geometry to one C(19,20); one N(1); and one H(17,18) atom. The C(17,18)-C(19,20) bond length is 1.38 Å. The C(17,18)-N(1) bond length is 1.38 Å. The C(17,18)-H(17,18) bond length is 1.08 Å. In the fourth C site, C(19,20) is bonded in a distorted bent 120 degrees geometry to one C(17,18); one N(3,4); and one H(19,20) atom. The C(19,20)-N(3,4) bond length is 1.38 Å. The C(19,20)-H(19,20) bond length is 1.08 Å. In the fifth C site, C(21,22) is bonded in a trigonal planar geometry to one N(1); one N(3,4); and one H(21,22) atom. The C(21,22)-N(1) bond length is 1.34 Å. The C(21,22)-N(3,4) bond length is 1.35 Å. The C(21,22)-H(21,22) bond length is 1.09 Å. In the sixth C site, C(29,30) is bonded in a distorted trigonal non-coplanar geometry to one N(3,4); one H(29,30); and one H(31,32) atom. The C(29,30)-N(3,4) bond length is 1.46 Å. The C(29,30)-H(29,30) bond length is 1.10 Å. The C(29,30)-H(31,32) bond length is 1.10 Å. In the seventh C site, C(37,38) is bonded in a distorted bent 120 degrees geometry to one C(39,40); one N(9); and one H(45,46) atom. The C(37,38)-C(39,40) bond length is 1.38 Å. The C(37,38)-N(9) bond length is 1.38 Å. The C(37,38)-H(45,46) bond length is 1.09 Å. In the eighth C site, C(39,40) is bonded in a distorted bent 120 degrees geometry to one C(37,38); one N(11,12); and one H(47,48) atom. The C(39,40)-N(11,12) bond length is 1.38 Å. The C(39,40)-H(47,48) bond length is 1.08 Å. In the ninth C site, C(41,42) is bonded in a trigonal planar geometry to one N(11,12); one N(9); and one H(49,50) atom. The C(41,42)-N(11,12) bond length is 1.35 Å. The C(41,42)-N(9) bond length is 1.33 Å. The C(41,42)-H(49,50) bond length is 1.09 Å. In the tenth C site, C(49,50) is bonded in a distorted trigonal non-coplanar geometry to one N(11,12); one H(57,58); and one H(59,60) atom. The C(49,50)-N(11,12) bond length is 1.46 Å. The C(49,50)-H(57,58) bond length is 1.10 Å. The C(49,50)-H(59,60) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1,2); one C(17,18); and one C(21,22) atom. In the second N site, N(3,4) is bonded in a trigonal planar geometry to one C(19,20); one C(21,22); and one C(29,30) atom. In the third N site, N(9) is bonded in a trigonal planar geometry to one Zn(1,2); one C(37,38); and one C(41,42) atom. In the fourth N site, N(11,12) is bonded in a trigonal planar geometry to one C(39,40); one C(41,42); and one C(49,50) atom. There are ten inequivalent H sites. In the first H site, H(17,18) is bonded in a single-bond geometry to one C(17,18) atom. In the second H site, H(19,20) is bonded in a single-bond geometry to one C(19,20) atom. In the third H site, H(21,22) is bonded in a single-bond geometry to one C(21,22) atom. In the fourth H site, H(29,30) is bonded in a single-bond geometry to one C(29,30) atom. In the fifth H site, H(31,32) is bonded in a single-bond geometry to one C(29,30) atom. In the sixth H site, H(45,46) is bonded in a single-bond geometry to one C(37,38) atom. In the seventh H site, H(47,48) is bonded in a single-bond geometry to one C(39,40) atom. In the eighth H site, H(49,50) is bonded in a single-bond geometry to one C(41,42) atom. In the ninth H site, H(57,58) is bonded in a single-bond geometry to one C(49,50) atom. In the tenth H site, H(59,60) is bonded in a single-bond geometry to one C(49,50) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1,2) and one C(1,2) atom. In the second O site, O(3) is bonded in a single-bond geometry to one C(1,2) atom. In the third O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(1,2) and one C(9,10) atom. In the fourth O site, O(11,12) is bonded in a single-bond geometry to one C(9,10) atom. In two of the ZnC10H10(NO)4 clusters, Zn(3) is bonded in a tetrahedral geometry to one N(14), one N(5), one O(13), and one O(5) atom. The Zn(3)-N(14) bond length is 2.06 Å. The Zn(3)-N(5) bond length is 2.02 Å. The Zn(3)-O(13) bond length is 1.99 Å. The Zn(3)-O(5) bond length is 1.97 Å. There are ten inequivalent C sites. In the first C site, C(55,56) is bonded in a distorted trigonal non-coplanar geometry to one N(15,16); one H(69,70); and one H(71,72) atom. The C(55,56)-N(15,16) bond length is 1.46 Å. The C(55,56)-H(69,70) bond length is 1.10 Å. The C(55,56)-H(71,72) bond length is 1.10 Å. In the second C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(7) atom. The C(7)-O(5) bond length is 1.30 Å. The C(7)-O(7) bond length is 1.25 Å. In the third C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(15,16) atom. The C(15)-O(13) bond length is 1.30 Å. The C(15)-O(15,16) bond length is 1.25 Å. In the fourth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(25), one N(5), and one H(23) atom. The C(23)-C(25) bond length is 1.37 Å. The C(23)-N(5) bond length is 1.38 Å. The C(23)-H(23) bond length is 1.08 Å. In the fifth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(23); one N(7); and one H(25,26) atom. The C(25)-N(7) bond length is 1.38 Å. The C(25)-H(25,26) bond length is 1.08 Å. In the sixth C site, C(27) is bonded in a trigonal planar geometry to one N(5), one N(7), and one H(27) atom. The C(27)-N(5) bond length is 1.34 Å. The C(27)-N(7) bond length is 1.36 Å. The C(27)-H(27) bond length is 1.09 Å. In the seventh C site, C(35) is bonded in a distorted trigonal non-coplanar geometry to one N(7); one H(41,42); and one H(43,44) atom. The C(35)-N(7) bond length is 1.46 Å. The C(35)-H(41,42) bond length is 1.10 Å. The C(35)-H(43,44) bond length is 1.10 Å. In the eighth C site, C(44) is bonded in a distorted bent 120 degrees geometry to one C(45,46); one N(14); and one H(51,52) atom. The C(44)-C(45,46) bond length is 1.38 Å. The C(44)-N(14) bond length is 1.38 Å. The C(44)-H(51,52) bond length is 1.08 Å. In the ninth C site, C(45,46) is bonded in a distorted bent 120 degrees geometry to one C(43); one N(15,16); and one H(53,54) atom. The C(45,46)-C(43) bond length is 1.38 Å. The C(45,46)-N(15,16) bond length is 1.38 Å. The C(45,46)-H(53,54) bond length is 1.09 Å. In the tenth C site, C(48) is bonded in a trigonal planar geometry to one N(14); one N(15,16); and one H(55,56) atom. The C(48)-N(14) bond length is 1.33 Å. The C(48)-N(15,16) bond length is 1.35 Å. The C(48)-H(55,56) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one Zn(3), one C(23), and one C(27) atom. In the second N site, N(7) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(35) atom. In the third N site, N(14) is bonded in a trigonal planar geometry to one Zn(3), one C(44), and one C(48) atom. In the fourth N site, N(15,16) is bonded in a trigonal planar geometry to one C(45,46); one C(47); and one C(55,56) atom. The N(15,16)-C(47) bond length is 1.35 Å. There are ten inequivalent H sites. In the first H site, H(23) is bonded in a single-bond geometry to one C(23) atom. In the second H site, H(25,26) is bonded in a single-bond geometry to one C(25) atom. In the third H site, H(27) is bonded in a single-bond geometry to one C(27) atom. In the fourth H site, H(41,42) is bonded in a single-bond geometry to one C(35) atom. In the fifth H site, H(43,44) is bonded in a single-bond geometry to one C(35) atom. In the sixth H site, H(51,52) is bonded in a single-bond geometry to one C(43) atom. The H(51,52)-C(43) bond length is 1.08 Å. In the seventh H site, H(53,54) is bonded in a single-bond geometry to one C(45,46) atom. In the eighth H site, H(55,56) is bonded in a single-bond geometry to one C(47) atom. The H(55,56)-C(47) bond length is 1.09 Å. In the ninth H site, H(69,70) is bonded in a single-bond geometry to one C(55,56) atom. In the tenth H site, H(71,72) is bonded in a single-bond geometry to one C(55,56) atom. There are four inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(7) atom. In the second O site, O(7) is bonded in a single-bond geometry to one C(7) atom. In the third O site, O(13) is bonded in a water-like geometry to one Zn(3) and one C(15) atom. In the fourth O site, O(15,16) is bonded in a single-bond geometry to one C(15) atom. Linkers: 1 [N]CCCCN1[CH]N([Zn](OC(=O)CCC([O])=O)(OC(=O)CCC([O])=O)N2[CH]N(CCCCN3[CH]N([Zn](OC(=O)CCC([O])=O)(OC(=O)CCC([O])=O)N4[CH]N(CCCCn5ccnc5)C=C4)C=C3)C=C2)C=C1 ,1 [C]CCCN1[CH]N([Zn](OC(=O)CCC([O])=O)(OC(=O)CCC([O])=O)N2[CH]N(CCCCN3[CH]N([Zn](OC(=O)CCC([O])=O)(OC(=O)CCC([O])=O)N4[CH]N(CCCCn5ccnc5)C=C4)C=C3)C=C2)C=C1 ,1 c1cn(CCCCn2ccnc2)cn1 ,1 [CH2][CH]C(=O)O[Zn](OC(=O)CCC([O])=O)N1[CH]N(CCCCN2[CH]N([Zn@@](O[C]=O)(OC(=O)CCC([O])=O)N3[CH]N(CCCCn4ccnc4)C=C3)C=C2)C=C1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.47 A, density 1.37 g/cm3, surface area 5118.58 m2/g, accessible volume 0.21 cm3/g