NiC12H18(N4S)2(CH2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two NiC12H18(N4S)2 clusters. In each NiC12H18(N4S)2 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent N(4) atoms. Both Ni(1)-N(1) bond lengths are 2.13 Å. Both Ni(1)-N(3) bond lengths are 2.10 Å. Both Ni(1)-N(4) bond lengths are 2.05 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(1)-N(1) bond length is 1.47 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the second C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(5), and one H(6) atom. The C(3)-N(2) bond length is 1.46 Å. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(6) bond length is 1.10 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(2), and one H(7) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-N(2) bond length is 1.38 Å. The C(4)-H(7) bond length is 1.08 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(3), and one H(8) atom. The C(5)-N(3) bond length is 1.38 Å. The C(5)-H(8) bond length is 1.08 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(9) atom. The C(6)-N(2) bond length is 1.36 Å. The C(6)-N(3) bond length is 1.33 Å. The C(6)-H(9) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one N(4) and one S(1) atom. The C(7)-N(4) bond length is 1.19 Å. The C(7)-S(1) bond length is 1.63 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Ni(1), one C(1), one H(10), and one H(11) atom. The N(1)-H(10) bond length is 1.03 Å. The N(1)-H(11) bond length is 1.02 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(6) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ni(1), one C(5), and one C(6) atom. In the fourth N site, N(4) is bonded in a distorted linear geometry to one Ni(1) and one C(7) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one N(1) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a single-bond geometry to one C(7) atom. Linkers: 4 NCCCn1ccnc1. Metal clusters: 2 [Ni]. The MOF has largest included sphere 1.91 A, density 1.53 g/cm3, surface area 5179.37 m2/g, accessible volume 0.16 cm3/g