ZnC9N3H7O5(CH2)6CH is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, twelve 02329_fluka molecules, and one ZnC9N3H7O5 cluster. In the ZnC9N3H7O5 cluster, Zn(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one O(1), one O(3), and one O(5) atom. The Zn(1)-N(1) bond length is 2.12 Å. The Zn(1)-N(2) bond length is 2.19 Å. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(3) bond length is 2.41 Å. The Zn(1)-O(5) bond length is 1.97 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(1)-O(4) bond length is 1.26 Å. The C(1)-O(5) bond length is 1.29 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one C(9), one H(1), and one H(2) atom. The C(2)-C(9) bond length is 1.51 Å. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(3)-O(1) bond length is 1.30 Å. The C(3)-O(2) bond length is 1.25 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(14), one N(2), and one H(5) atom. The C(5)-C(14) bond length is 1.40 Å. The C(5)-N(2) bond length is 1.34 Å. The C(5)-H(5) bond length is 1.09 Å. In the fifth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(2), one N(3), and one O(3) atom. The C(9)-N(3) bond length is 1.38 Å. The C(9)-O(3) bond length is 1.24 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(13), one C(16), and one N(2) atom. The C(10)-C(13) bond length is 1.40 Å. The C(10)-C(16) bond length is 1.46 Å. The C(10)-N(2) bond length is 1.36 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(10) and one H(15) atom. The C(13)-H(15) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(5) and one H(16) atom. The C(14)-H(16) bond length is 1.09 Å. In the ninth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(1), and one H(19) atom. The C(16)-N(1) bond length is 1.29 Å. The C(16)-H(19) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(16), and one N(3) atom. The N(1)-N(3) bond length is 1.34 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(5) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to one C(9), one N(1), and one H(20) atom. The N(3)-H(20) bond length is 1.05 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(20) is bonded in a distorted bent 150 degrees geometry to one N(3) and one O(4) atom. The H(20)-O(4) bond length is 1.66 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Zn(1) and one C(9) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one C(1) and one H(20) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. Linkers: 1 O=C(CCCCC(=O)N/N=C/c1ccccn1)N/N=C/c1ccccn1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.65 A, density 1.56 g/cm3, surface area 4863.82 m2/g, accessible volume 0.17 cm3/g