(CH)2ZnC14N4H14(OCl)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two ZnC14N4H14(OCl)2 clusters. In each ZnC14N4H14(OCl)2 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1,2) and two equivalent Cl(1,2) atoms. Both Zn(1)-N(1,2) bond lengths are 2.07 Å. Both Zn(1)-Cl(1,2) bond lengths are 2.24 Å. There are seven inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one N(1,2) and one H(1,2) atom. The C(1,2)-N(1,2) bond length is 1.35 Å. The C(1,2)-H(1,2) bond length is 1.09 Å. In the second C site, C(5,6) is bonded in a distorted single-bond geometry to one C(7,8) and one H(5,6) atom. The C(5,6)-C(7,8) bond length is 1.40 Å. The C(5,6)-H(5,6) bond length is 1.09 Å. In the third C site, C(7,8) is bonded in a trigonal planar geometry to one C(11,12); one C(5,6); and one C(9,10) atom. The C(7,8)-C(11,12) bond length is 1.50 Å. The C(7,8)-C(9,10) bond length is 1.40 Å. In the fourth C site, C(9,10) is bonded in a distorted trigonal planar geometry to one C(7,8); one N(1,2); and one H(7,8) atom. The C(9,10)-N(1,2) bond length is 1.35 Å. The C(9,10)-H(7,8) bond length is 1.09 Å. In the fifth C site, C(11,12) is bonded in a distorted bent 120 degrees geometry to one C(7,8); one N(3,4); and one O(1,2) atom. The C(11,12)-N(3,4) bond length is 1.35 Å. The C(11,12)-O(1,2) bond length is 1.25 Å. In the sixth C site, C(13,14) is bonded in a distorted trigonal non-coplanar geometry to one N(3,4); one H(11,12); and one H(15,16) atom. The C(13,14)-N(3,4) bond length is 1.46 Å. The C(13,14)-H(11,12) bond length is 1.09 Å. The C(13,14)-H(15,16) bond length is 1.10 Å. In the seventh C site, C(15,16) is bonded in a distorted trigonal non-coplanar geometry to one N(3,4); one H(13,14); and one H(9,10) atom. The C(15,16)-N(3,4) bond length is 1.46 Å. The C(15,16)-H(13,14) bond length is 1.10 Å. The C(15,16)-H(9,10) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1,2) is bonded in a trigonal planar geometry to one Zn(1); one C(1,2); and one C(9,10) atom. In the second N site, N(3,4) is bonded in a trigonal planar geometry to one C(11,12); one C(13,14); and one C(15,16) atom. There are seven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(5,6) is bonded in a single-bond geometry to one C(5,6) atom. In the third H site, H(7,8) is bonded in a single-bond geometry to one C(9,10) atom. In the fourth H site, H(9,10) is bonded in a single-bond geometry to one C(15,16) atom. In the fifth H site, H(11,12) is bonded in a single-bond geometry to one C(13,14) atom. In the sixth H site, H(13,14) is bonded in a single-bond geometry to one C(15,16) atom. In the seventh H site, H(15,16) is bonded in a single-bond geometry to one C(13,14) atom. O(1,2) is bonded in a single-bond geometry to one C(11,12) atom. Cl(1,2) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 2 O=C(c1cccnc1)N1CCN(C(=O)c2cccnc2)CC1 ,4 O=C(c1cc[c]nc1)N1CCN(C(=O)c2cccnc2)CC1. Metal clusters: 2 Cl[Zn]Cl. The MOF has largest included sphere 1.72 A, density 1.69 g/cm3, surface area 4491.37 m2/g, accessible volume 0.17 cm3/g