ZnC8H8(N4S)2(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two ZnC8H8(N4S)2 clusters. In each ZnC8H8(N4S)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(7), and one N(8) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-N(2) bond length is 2.03 Å. The Zn(1)-N(7) bond length is 1.92 Å. The Zn(1)-N(8) bond length is 1.92 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1); one N(3,4); and one H(1,2) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-N(3,4) bond length is 1.33 Å. The C(1)-H(1,2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2); one N(3,4); and one H(1,2) atom. The C(2)-N(2) bond length is 1.37 Å. The C(2)-N(3,4) bond length is 1.33 Å. The C(2)-H(1,2) bond length is 1.09 Å. In the third C site, C(3,4) is bonded in a trigonal planar geometry to one N(1), one N(5), and one H(3) atom. The C(3,4)-N(1) bond length is 1.34 Å. The C(3,4)-N(5) bond length is 1.34 Å. The C(3,4)-H(3) bond length is 1.09 Å. In the fourth C site, C(5,6) is bonded in a distorted trigonal non-coplanar geometry to one N(5), one H(5), and one H(7) atom. The C(5,6)-N(5) bond length is 1.46 Å. The C(5,6)-H(5) bond length is 1.10 Å. The C(5,6)-H(7) bond length is 1.10 Å. In the fifth C site, C(9) is bonded in a distorted linear geometry to one N(7) and one S(1) atom. The C(9)-N(7) bond length is 1.19 Å. The C(9)-S(1) bond length is 1.61 Å. In the sixth C site, C(10) is bonded in a distorted linear geometry to one N(8) and one S(2) atom. The C(10)-N(8) bond length is 1.19 Å. The C(10)-S(2) bond length is 1.61 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1); one C(1); and one C(3,4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1); one C(2); and one C(3,4) atom. The N(2)-C(3,4) bond length is 1.34 Å. In the third N site, N(3,4) is bonded in a water-like geometry to one C(1) and one N(5) atom. The N(3,4)-N(5) bond length is 1.36 Å. In the fourth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(3,4); one C(5,6); and one N(3,4) atom. In the fifth N site, N(6) is bonded in a distorted trigonal planar geometry to one C(3,4); one C(5,6); and one N(3,4) atom. The N(6)-C(3,4) bond length is 1.34 Å. The N(6)-C(5,6) bond length is 1.46 Å. The N(6)-N(3,4) bond length is 1.36 Å. In the sixth N site, N(7) is bonded in a linear geometry to one Zn(1) and one C(9) atom. In the seventh N site, N(8) is bonded in a linear geometry to one Zn(1) and one C(10) atom. There are seven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3,4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(3,4) atom. The H(4)-C(3,4) bond length is 1.09 Å. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(5,6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(5,6) atom. The H(6)-C(5,6) bond length is 1.10 Å. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(5,6) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(5,6) atom. The H(8)-C(5,6) bond length is 1.10 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one C(9) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(10) atom. Linkers: 1 [CH]1N=C[N]N1CCCCn1cncn1 ,1 [CH]1N=C[N]N1CCCCN1[CH]N=C[N]1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.96 A, density 1.54 g/cm3, surface area 5100.00 m2/g, accessible volume 0.16 cm3/g