ZnC22H16(NO)4(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two ZnC22H16(NO)4 clusters. In each ZnC22H16(NO)4 cluster, Zn(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.07 Å. The Zn(1)-N(2) bond length is 2.07 Å. The Zn(1)-O(1) bond length is 2.06 Å. The Zn(1)-O(2) bond length is 2.05 Å. The Zn(1)-O(3) bond length is 2.39 Å. The Zn(1)-O(4) bond length is 2.41 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(1) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one H(2) atom. The C(2)-C(4) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(3) atom. The C(3)-C(5) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(4) atom. The C(4)-C(6) bond length is 1.41 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(17), one C(3), and one C(7) atom. The C(5)-C(17) bond length is 1.41 Å. The C(5)-C(7) bond length is 1.48 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(18), one C(4), and one C(8) atom. The C(6)-C(18) bond length is 1.41 Å. The C(6)-C(8) bond length is 1.48 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(15), one C(5), and one C(9) atom. The C(7)-C(15) bond length is 1.41 Å. The C(7)-C(9) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(16), and one C(6) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-C(16) bond length is 1.41 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(11,12); one C(7); and one H(5,6) atom. The C(9)-C(11,12) bond length is 1.39 Å. The C(9)-H(5,6) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11,12); one C(8); and one H(5,6) atom. The C(10)-C(11,12) bond length is 1.39 Å. The C(10)-H(5,6) bond length is 1.09 Å. In the eleventh C site, C(11,12) is bonded in a distorted trigonal planar geometry to one C(9), one N(3), and one H(7) atom. The C(11,12)-N(3) bond length is 1.34 Å. The C(11,12)-H(7) bond length is 1.09 Å. In the twelfth C site, C(13,14) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(13,14)-N(3) bond length is 1.34 Å. The C(13,14)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(7) and one H(11,12) atom. The C(15)-H(11,12) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(8) and one H(11,12) atom. The C(16)-H(11,12) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(19), one C(5), and one H(13) atom. The C(17)-C(19) bond length is 1.39 Å. The C(17)-H(13) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(20), one C(6), and one H(14) atom. The C(18)-C(20) bond length is 1.39 Å. The C(18)-H(14) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(17), one N(1), and one H(15) atom. The C(19)-N(1) bond length is 1.35 Å. The C(19)-H(15) bond length is 1.09 Å. In the eighteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(18), one N(2), and one H(16) atom. The C(20)-N(2) bond length is 1.35 Å. The C(20)-H(16) bond length is 1.09 Å. In the nineteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(21)-O(1) bond length is 1.29 Å. The C(21)-O(3) bond length is 1.26 Å. In the twentieth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(22)-O(2) bond length is 1.29 Å. The C(22)-O(4) bond length is 1.26 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(19) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(2), and one C(20) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(11,12) and one C(13,14) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(11,12) and one C(13,14) atom. The N(4)-C(11,12) bond length is 1.34 Å. The N(4)-C(13,14) bond length is 1.34 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(11,12) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11,12) atom. The H(8)-C(11,12) bond length is 1.09 Å. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13,14) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(13,14) atom. The H(10)-C(13,14) bond length is 1.09 Å. In the tenth H site, H(11,12) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Zn(1) and one C(21) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(22) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Zn(1) and one C(21) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Zn(1) and one C(22) atom. Linkers: 2 [O]C(=O)CCC([O])=O. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.92 A, density 1.51 g/cm3, surface area 5011.24 m2/g, accessible volume 0.17 cm3/g