PbC14H12(N2O3)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four PbC14H12(N2O3)2 clusters. Pb(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Pb(1)-N(1) bond lengths are 2.51 Å. Both Pb(1)-O(1) bond lengths are 2.67 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-C(6) bond length is 1.49 Å. The C(1)-N(1) bond length is 1.34 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-C(7) bond length is 1.43 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(5), and one N(1) atom. The C(5)-C(5) bond length is 1.44 Å. The C(5)-N(1) bond length is 1.36 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one H(3), one H(4), and one H(5) atom. The C(6)-H(3) bond length is 1.09 Å. The C(6)-H(4) bond length is 1.10 Å. The C(6)-H(5) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Pb(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(2)-O(1) bond length is 1.28 Å. The N(2)-O(2) bond length is 1.28 Å. The N(2)-O(3) bond length is 1.25 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(3) is bonded in a single-bond geometry to one N(2) atom. In the third O site, O(1) is bonded in a single-bond geometry to one Pb(1) and one N(2) atom. Linkers: 4 [O][N+](=O)[O-]. Metal clusters: 2 [Pb]. The MOF has largest included sphere 1.68 A, density 2.28 g/cm3, surface area 3245.47 m2/g, accessible volume 0.08 cm3/g