Sc2C24H15(NO4)3 crystallizes in the cubic P2_13 space group. There are two inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in an octahedral geometry to three equivalent O(1) and three equivalent O(2) atoms. All Sc(1)-O(1) bond lengths are 2.11 Å. All Sc(1)-O(2) bond lengths are 2.10 Å. In the second Sc site, Sc(2) is bonded in an octahedral geometry to three equivalent O(3) and three equivalent O(4) atoms. All Sc(2)-O(3) bond lengths are 2.06 Å. All Sc(2)-O(4) bond lengths are 2.10 Å. There are eight inequivalent C sites. In the first C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(6)-C(1) bond length is 1.39 Å. The C(6)-H(3) bond length is 1.09 Å. In the second C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one N(1) atom. The C(7)-C(5) bond length is 1.41 Å. The C(7)-N(1) bond length is 1.37 Å. In the third C site, C(8) is bonded in a bent 120 degrees geometry to one C(1), one O(1), and one O(3) atom. The C(8)-C(1) bond length is 1.49 Å. The C(8)-O(1) bond length is 1.27 Å. The C(8)-O(3) bond length is 1.27 Å. In the fourth C site, C(1) is bonded in a trigonal planar geometry to one C(3), one C(6), and one C(8) atom. The C(1)-C(3) bond length is 1.40 Å. In the fifth C site, C(2) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(5) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.49 Å. The C(2)-C(5) bond length is 1.40 Å. In the sixth C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(2), and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the seventh C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(4) atom. The C(4)-O(2) bond length is 1.28 Å. The C(4)-O(4) bond length is 1.27 Å. In the eighth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(2), one C(7), and one H(2) atom. The C(5)-H(2) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one C(7), one H(4), and one H(5) atom. The N(1)-H(4) bond length is 1.01 Å. The N(1)-H(5) bond length is 1.02 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Sc(1) and one C(8) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Sc(1) and one C(4) atom. In the third O site, O(3) is bonded in a linear geometry to one Sc(2) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Sc(2) and one C(4) atom. Linkers: 12 Nc1cc(C([O])=O)cc(C([O])=O)c1. Metal clusters: 8 [Sc]. The MOF has largest included sphere 4.81 A, density 1.53 g/cm3, surface area 3872.43 m2/g, accessible volume 0.18 cm3/g