AgC9H6(NO2)2 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one O(3), and two equivalent O(1) atoms. The Ag(1)-N(1) bond length is 2.22 Å. The Ag(1)-N(2) bond length is 2.19 Å. The Ag(1)-O(3) bond length is 2.75 Å. There is one shorter (2.59 Å) and one longer (2.67 Å) Ag(1)-O(1) bond length. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.52 Å. The C(1)-N(1) bond length is 1.35 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.51 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.29 Å. The C(6)-O(2) bond length is 1.25 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(7)-O(3) bond length is 1.24 Å. The C(7)-O(4) bond length is 1.32 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5) atom. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(5) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(9)-N(2) bond length is 1.35 Å. The C(9)-H(6) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(8), and one C(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(4) atom. The H(1)-O(1) bond length is 1.47 Å. The H(1)-O(4) bond length is 1.06 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Ag(1), one C(6), and one H(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(6) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Ag(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(7) and one H(1) atom. Linkers: 2 c1cnccn1 ,4 [O]C(=O)c1ncccc1C(=O)O. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.45 A, density 2.28 g/cm3, surface area 3149.52 m2/g, accessible volume 0.06 cm3/g