Mo4ZnC10H12(N3O8)2(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and one Mo4ZnC10H12(N3O8)2 cluster. In the Mo4ZnC10H12(N3O8)2 cluster, there are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(16), one O(9), and two equivalent O(12) atoms. The Mo(1)-O(10) bond length is 1.79 Å. The Mo(1)-O(11) bond length is 1.98 Å. The Mo(1)-O(16) bond length is 1.93 Å. The Mo(1)-O(9) bond length is 1.72 Å. There is one shorter (2.07 Å) and one longer (2.47 Å) Mo(1)-O(12) bond length. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(13), one O(14), one O(15), and one O(4) atom. The Mo(2)-O(10) bond length is 2.27 Å. The Mo(2)-O(12) bond length is 2.61 Å. The Mo(2)-O(13) bond length is 1.93 Å. The Mo(2)-O(14) bond length is 1.71 Å. The Mo(2)-O(15) bond length is 1.92 Å. The Mo(2)-O(4) bond length is 1.73 Å. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(11), one O(12), one O(13), one O(16), one O(5), and one O(6) atom. The Mo(3)-O(11) bond length is 2.37 Å. The Mo(3)-O(12) bond length is 2.42 Å. The Mo(3)-O(13) bond length is 1.89 Å. The Mo(3)-O(16) bond length is 2.00 Å. The Mo(3)-O(5) bond length is 1.72 Å. The Mo(3)-O(6) bond length is 1.71 Å. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(11), one O(12), one O(15), one O(16), one O(7), and one O(8) atom. The Mo(4)-O(11) bond length is 1.99 Å. The Mo(4)-O(12) bond length is 2.27 Å. The Mo(4)-O(15) bond length is 1.90 Å. The Mo(4)-O(16) bond length is 2.51 Å. The Mo(4)-O(7) bond length is 1.73 Å. The Mo(4)-O(8) bond length is 1.71 Å. Zn(1) is bonded in an octahedral geometry to one N(1), one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-N(3) bond length is 2.09 Å. The Zn(1)-O(1) bond length is 2.14 Å. The Zn(1)-O(2) bond length is 2.18 Å. The Zn(1)-O(3) bond length is 2.14 Å. The Zn(1)-O(4) bond length is 2.32 Å. There are ten inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(6) atom. The C(2)-N(3) bond length is 1.32 Å. The C(2)-N(4) bond length is 1.36 Å. The C(2)-H(6) bond length is 1.08 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(4), and one H(7) atom. The C(3)-C(9) bond length is 1.38 Å. The C(3)-N(4) bond length is 1.37 Å. The C(3)-H(7) bond length is 1.08 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(6) and one O(3) atom. The C(5)-N(6) bond length is 1.34 Å. The C(5)-O(3) bond length is 1.27 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(13) atom. The C(6)-N(2) bond length is 1.37 Å. The C(6)-H(13) bond length is 1.08 Å. In the fifth C site, C(7) is bonded in a distorted water-like geometry to one N(6) and one H(14) atom. The C(7)-N(6) bond length is 1.46 Å. The C(7)-H(14) bond length is 1.10 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one N(1) atom. The C(8)-N(1) bond length is 1.38 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(13), one C(3), and one N(3) atom. The C(9)-C(13) bond length is 1.48 Å. The C(9)-N(3) bond length is 1.38 Å. In the eighth C site, C(12) is bonded in a distorted water-like geometry to one N(5) and one H(19) atom. The C(12)-N(5) bond length is 1.47 Å. The C(12)-H(19) bond length is 1.10 Å. In the ninth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(5), and one O(2) atom. The C(13)-N(5) bond length is 1.34 Å. The C(13)-O(2) bond length is 1.26 Å. In the tenth C site, C(14) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(20) atom. The C(14)-N(1) bond length is 1.32 Å. The C(14)-N(2) bond length is 1.36 Å. The C(14)-H(20) bond length is 1.08 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(14), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(14), one C(6), and one H(5) atom. The N(2)-H(5) bond length is 1.02 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(2), and one C(9) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(2), one C(3), and one H(8) atom. The N(4)-H(8) bond length is 1.02 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(12), one C(13), and one H(11) atom. The N(5)-H(11) bond length is 1.02 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one H(12) atom. The N(6)-H(12) bond length is 1.02 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(1) and one O(5) atom. The H(1)-O(1) bond length is 0.99 Å. The H(1)-O(5) bond length is 1.68 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.98 Å. In the third H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one N(5) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one N(6) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(7) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(14) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Zn(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mo(2) and one Zn(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(3) and one H(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Mo(3) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Mo(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Mo(4) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Mo(1) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the eleventh O site, O(11) is bonded in a trigonal non-coplanar geometry to one Mo(1), one Mo(3), and one Mo(4) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one Mo(2), one Mo(3), one Mo(4), and two equivalent Mo(1) atoms. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(3) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Mo(2) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(4) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(3), and one Mo(4) atom. Linkers: 1 O=C(N[C@H]1CCCC[C@@H]1NC(=O)c1c[nH]cn1)c1c[nH]cn1 ,1 O=C(N[C@@H]1CCCC[C@H]1NC(=O)c1c[nH]cn1)c1c[nH]cn1. Metal clusters: 2 [Zn] ,8 [Mo]. The MOF has largest included sphere 3.09 A, density 2.40 g/cm3, surface area 2666.11 m2/g, accessible volume 0.11 cm3/g