ZnC14PNH11O8(CH3)2 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a ZnC14PNH11O8 framework. In the ZnC14PNH11O8 framework, Zn(1) is bonded to one N(1), one O(1), one O(4), and one O(8) atom to form distorted ZnNO3 tetrahedra that share  a cornercorner with one P(1)CO3 tetrahedra. The Zn(1)-N(1) bond length is 2.05 Å. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(4) bond length is 1.96 Å. The Zn(1)-O(8) bond length is 1.97 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one P(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-P(1) bond length is 1.82 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(4) atom. The C(3)-C(10) bond length is 1.50 Å. The C(3)-C(4) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(8) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(8) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(11), one C(4), and one C(6) atom. The C(5)-C(11) bond length is 1.49 Å. The C(5)-C(6) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted water-like geometry to one H(5) and one O(3) atom. The C(7)-H(5) bond length is 1.10 Å. The C(7)-O(3) bond length is 1.48 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(4), and one O(5) atom. The C(10)-O(4) bond length is 1.30 Å. The C(10)-O(5) bond length is 1.25 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(6), and one O(7) atom. The C(11)-O(6) bond length is 1.25 Å. The C(11)-O(7) bond length is 1.32 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one N(1), and one H(4) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-N(1) bond length is 1.35 Å. The C(12)-H(4) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(2) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-H(2) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(15) atom. The C(14)-C(14) bond length is 1.47 Å. The C(14)-C(15) bond length is 1.40 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(7) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-H(7) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one N(1), and one H(6) atom. The C(16)-N(1) bond length is 1.35 Å. The C(16)-H(6) bond length is 1.09 Å. P(1) is bonded to one C(1), one O(1), one O(2), and one O(3) atom to form PCO3 tetrahedra that share  a cornercorner with one Zn(1)NO3 tetrahedra. The P(1)-O(1) bond length is 1.53 Å. The P(1)-O(2) bond length is 1.52 Å. The P(1)-O(3) bond length is 1.60 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(12), and one C(16) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a distorted linear geometry to one O(2) and one O(8) atom. The H(9)-O(2) bond length is 1.60 Å. The H(9)-O(8) bond length is 1.01 Å. In the tenth H site, H(10) is bonded in a distorted single-bond geometry to one O(2) and one O(8) atom. The H(10)-O(2) bond length is 1.66 Å. The H(10)-O(8) bond length is 1.01 Å. In the eleventh H site, H(15) is bonded in a linear geometry to one O(6) and one O(7) atom. The H(15)-O(6) bond length is 1.56 Å. The H(15)-O(7) bond length is 1.03 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one P(1), one H(10), and one H(9) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(7) and one P(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zn(1) and one C(10) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one C(11) and one H(15) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one C(11) and one H(15) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one H(10), and one H(9) atom. Linkers: 2 CC(C)O[P@@]([O])(=O)c1cc(C([O])=O)cc(C(=O)O)c1 ,1 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.38 A, density 1.68 g/cm3, surface area 4538.89 m2/g, accessible volume 0.12 cm3/g