(ScC3H2O7)2(C4H2O)3 crystallizes in the triclinic P-1 space group. The structure consists of six furan molecules inside a ScC3H2O7 framework. In the ScC3H2O7 framework, there are two inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in an octahedral geometry to one O(1), one O(11), one O(13), one O(14), one O(3), and one O(8) atom. The Sc(1)-O(1) bond length is 2.15 Å. The Sc(1)-O(11) bond length is 2.02 Å. The Sc(1)-O(13) bond length is 2.10 Å. The Sc(1)-O(14) bond length is 2.12 Å. The Sc(1)-O(3) bond length is 2.13 Å. The Sc(1)-O(8) bond length is 2.07 Å. In the second Sc site, Sc(2) is bonded in an octahedral geometry to one O(16), one O(17), one O(2), one O(4), one O(6), and one O(9) atom. The Sc(2)-O(16) bond length is 2.11 Å. The Sc(2)-O(17) bond length is 2.06 Å. The Sc(2)-O(2) bond length is 2.18 Å. The Sc(2)-O(4) bond length is 2.08 Å. The Sc(2)-O(6) bond length is 2.04 Å. The Sc(2)-O(9) bond length is 2.11 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(1)-O(3) bond length is 1.27 Å. The C(1)-O(4) bond length is 1.27 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(6)-O(6) bond length is 1.28 Å. The C(6)-O(7) bond length is 1.27 Å. In the third C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(8) and one O(9) atom. The C(7)-O(8) bond length is 1.27 Å. The C(7)-O(9) bond length is 1.27 Å. In the fourth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. The C(12)-O(11) bond length is 1.29 Å. The C(12)-O(12) bond length is 1.25 Å. In the fifth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(14) atom. The C(13)-O(13) bond length is 1.27 Å. The C(13)-O(14) bond length is 1.27 Å. In the sixth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one O(16) and one O(17) atom. The C(18)-O(16) bond length is 1.26 Å. The C(18)-O(17) bond length is 1.27 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(1) and one O(7) atom. The H(2)-O(1) bond length is 1.00 Å. The H(2)-O(7) bond length is 1.66 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(2) and one O(7) atom. The H(3)-O(2) bond length is 1.01 Å. The H(3)-O(7) bond length is 1.63 Å. In the fourth H site, H(4) is bonded in a distorted linear geometry to one O(12) and one O(2) atom. The H(4)-O(12) bond length is 1.60 Å. The H(4)-O(2) bond length is 1.02 Å. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Sc(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Sc(2), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Sc(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Sc(2) and one C(1) atom. In the fifth O site, O(6) is bonded in a bent 150 degrees geometry to one Sc(2) and one C(6) atom. In the sixth O site, O(7) is bonded in a distorted trigonal planar geometry to one C(6), one H(2), and one H(3) atom. In the seventh O site, O(8) is bonded in a bent 150 degrees geometry to one Sc(1) and one C(7) atom. In the eighth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Sc(2) and one C(7) atom. In the ninth O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Sc(1) and one C(12) atom. In the tenth O site, O(12) is bonded in a water-like geometry to one C(12) and one H(4) atom. In the eleventh O site, O(13) is bonded in a bent 150 degrees geometry to one Sc(1) and one C(13) atom. In the twelfth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Sc(1) and one C(13) atom. In the thirteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Sc(2) and one C(18) atom. In the fourteenth O site, O(17) is bonded in a bent 150 degrees geometry to one Sc(2) and one C(18) atom. Linkers: 6 [O]C(=O)c1ccc(C([O])=O)o1. Metal clusters: 4 [Sc]. The MOF has largest included sphere 2.53 A, density 1.85 g/cm3, surface area 3563.06 m2/g, accessible volume 0.10 cm3/g