CuC7NH4O4CH(CH2)2CH3 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, sixteen 02329_fluka molecules, eight 02329_fluka molecules, and four CuC7NH4O4 clusters. In each CuC7NH4O4 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(3), one O(5), and one O(7) atom. The Cu(1)-N(1) bond length is 2.17 Å. The Cu(1)-O(1) bond length is 2.01 Å. The Cu(1)-O(3) bond length is 2.00 Å. The Cu(1)-O(5) bond length is 2.02 Å. The Cu(1)-O(7) bond length is 2.01 Å. In the second Cu site, Cu(2) is bonded in a distorted square pyramidal geometry to one N(2), one O(2), one O(4), one O(6), and one O(8) atom. The Cu(2)-N(2) bond length is 2.16 Å. The Cu(2)-O(2) bond length is 2.01 Å. The Cu(2)-O(4) bond length is 2.02 Å. The Cu(2)-O(6) bond length is 2.00 Å. The Cu(2)-O(8) bond length is 2.02 Å. There are fourteen inequivalent C sites. In the first C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(15)-O(3) bond length is 1.28 Å. The C(15)-O(4) bond length is 1.27 Å. In the second C site, C(17) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(17)-O(5) bond length is 1.27 Å. The C(17)-O(6) bond length is 1.27 Å. In the third C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(21)-O(7) bond length is 1.28 Å. The C(21)-O(8) bond length is 1.27 Å. In the fourth C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the fifth C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the sixth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(8) bond length is 1.48 Å. In the seventh C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the eighth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the ninth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(2), and one H(5) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-N(2) bond length is 1.35 Å. The C(6)-H(5) bond length is 1.09 Å. In the tenth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(6) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-H(6) bond length is 1.09 Å. In the eleventh C site, C(8) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.40 Å. In the twelfth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the thirteenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(8) bond length is 1.09 Å. In the fourteenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(11)-O(1) bond length is 1.27 Å. The C(11)-O(2) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(10), and one C(6) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(11) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(11) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(15) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(17) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(17) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(21) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(21) atom. Linkers: 4 C[C@H](CCC([O])=O)C([O])=O ,2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 4.18 A, density 1.50 g/cm3, surface area 4315.89 m2/g, accessible volume 0.21 cm3/g