Cd3H60(C11O3)8 crystallizes in the triclinic P-1 space group. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to two equivalent O(10), two equivalent O(5), and two equivalent O(9) atoms to form edge-sharing CdO6 octahedra. Both Cd(1)-O(10) bond lengths are 2.32 Å. Both Cd(1)-O(5) bond lengths are 2.27 Å. Both Cd(1)-O(9) bond lengths are 2.36 Å. In the second Cd site, Cd(2) is bonded to one O(10), one O(11), one O(12), one O(6), one O(7), one O(8), and one O(9) atom to form distorted edge-sharing CdO7 pentagonal bipyramids. The Cd(2)-O(10) bond length is 2.47 Å. The Cd(2)-O(11) bond length is 2.41 Å. The Cd(2)-O(12) bond length is 2.35 Å. The Cd(2)-O(6) bond length is 2.26 Å. The Cd(2)-O(7) bond length is 2.50 Å. The Cd(2)-O(8) bond length is 2.32 Å. The Cd(2)-O(9) bond length is 2.57 Å. There are forty-four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(35), and one C(6) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(35) bond length is 1.50 Å. The C(1)-C(6) bond length is 1.40 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(7) bond length is 1.48 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(4), and one C(8) atom. The C(7)-C(12) bond length is 1.40 Å. The C(7)-C(8) bond length is 1.42 Å. In the eighth C site, C(8) is bonded in a single-bond geometry to one C(7), one C(9), and one O(1) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-O(1) bond length is 1.38 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(19), and one C(8) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(19) bond length is 1.49 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one O(2) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-O(2) bond length is 1.37 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(13) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(13) bond length is 1.48 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(7), and one H(5) atom. The C(12)-H(5) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(18) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(18) bond length is 1.40 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(6) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(6) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(7) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(7) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(36) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(36) bond length is 1.49 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(8) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(8) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one H(9) atom. The C(18)-H(9) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(20), one C(24), and one C(9) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-C(24) bond length is 1.41 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one O(4) atom. The C(20)-C(21) bond length is 1.43 Å. The C(20)-O(4) bond length is 1.36 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(25) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(25) bond length is 1.47 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(10) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(10) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(40) atom. The C(23)-C(24) bond length is 1.42 Å. The C(23)-C(40) bond length is 1.47 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(19), one C(23), and one O(3) atom. The C(24)-O(3) bond length is 1.36 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(21), one C(26), and one C(30) atom. The C(25)-C(26) bond length is 1.41 Å. The C(25)-C(30) bond length is 1.42 Å. In the twenty-sixth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one C(27), and one H(11) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-H(11) bond length is 1.09 Å. In the twenty-seventh C site, C(27) is bonded in a distorted trigonal planar geometry to one C(26), one C(28), and one H(12) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-H(12) bond length is 1.09 Å. In the twenty-eighth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(43) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-C(43) bond length is 1.49 Å. In the twenty-ninth C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(13) atom. The C(29)-H(13) bond length is 1.09 Å. In the thirtieth C site, C(30) is bonded in a distorted single-bond geometry to one C(25) and one H(14) atom. The C(30)-H(14) bond length is 1.09 Å. In the thirty-first C site, C(31) is bonded in a tetrahedral geometry to one H(15), one H(16), one H(17), and one O(1) atom. The C(31)-H(15) bond length is 1.09 Å. The C(31)-H(16) bond length is 1.10 Å. The C(31)-H(17) bond length is 1.09 Å. The C(31)-O(1) bond length is 1.44 Å. In the thirty-second C site, C(32) is bonded in a tetrahedral geometry to one H(18), one H(19), one H(20), and one O(2) atom. The C(32)-H(18) bond length is 1.10 Å. The C(32)-H(19) bond length is 1.10 Å. The C(32)-H(20) bond length is 1.10 Å. The C(32)-O(2) bond length is 1.44 Å. In the thirty-third C site, C(33) is bonded in a tetrahedral geometry to one H(21), one H(22), one H(23), and one O(3) atom. The C(33)-H(21) bond length is 1.10 Å. The C(33)-H(22) bond length is 1.10 Å. The C(33)-H(23) bond length is 1.10 Å. The C(33)-O(3) bond length is 1.44 Å. In the thirty-fourth C site, C(34) is bonded in a tetrahedral geometry to one H(24), one H(25), one H(26), and one O(4) atom. The C(34)-H(24) bond length is 1.10 Å. The C(34)-H(25) bond length is 1.10 Å. The C(34)-H(26) bond length is 1.10 Å. The C(34)-O(4) bond length is 1.44 Å. In the thirty-fifth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(5), and one O(6) atom. The C(35)-O(5) bond length is 1.27 Å. The C(35)-O(6) bond length is 1.27 Å. In the thirty-sixth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(10), and one O(11) atom. The C(36)-O(10) bond length is 1.28 Å. The C(36)-O(11) bond length is 1.27 Å. In the thirty-seventh C site, C(37) is bonded in a trigonal planar geometry to one C(38), one C(42), and one C(44) atom. The C(37)-C(38) bond length is 1.40 Å. The C(37)-C(42) bond length is 1.40 Å. The C(37)-C(44) bond length is 1.50 Å. In the thirty-eighth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(37), one C(39), and one H(27) atom. The C(38)-C(39) bond length is 1.39 Å. The C(38)-H(27) bond length is 1.09 Å. In the thirty-ninth C site, C(39) is bonded in a distorted single-bond geometry to one C(38), one C(40), and one H(28) atom. The C(39)-C(40) bond length is 1.41 Å. The C(39)-H(28) bond length is 1.09 Å. In the fortieth C site, C(40) is bonded in a trigonal planar geometry to one C(23), one C(39), and one C(41) atom. The C(40)-C(41) bond length is 1.41 Å. In the forty-first C site, C(41) is bonded in a distorted single-bond geometry to one C(40) and one H(29) atom. The C(41)-H(29) bond length is 1.09 Å. In the forty-second C site, C(42) is bonded in a distorted single-bond geometry to one C(37) and one H(30) atom. The C(42)-H(30) bond length is 1.09 Å. In the forty-third C site, C(43) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(7), and one O(8) atom. The C(43)-O(7) bond length is 1.27 Å. The C(43)-O(8) bond length is 1.28 Å. In the forty-fourth C site, C(44) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(12), and one O(9) atom. The C(44)-O(12) bond length is 1.27 Å. The C(44)-O(9) bond length is 1.29 Å. There are thirty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(26) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(27) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(29) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(30) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(31) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(31) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(31) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(32) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(32) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(32) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(33) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(33) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(33) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(34) atom. In the twenty-fifth H site, H(25) is bonded in a single-bond geometry to one C(34) atom. In the twenty-sixth H site, H(26) is bonded in a single-bond geometry to one C(34) atom. In the twenty-seventh H site, H(27) is bonded in a single-bond geometry to one C(38) atom. In the twenty-eighth H site, H(28) is bonded in a single-bond geometry to one C(39) atom. In the twenty-ninth H site, H(29) is bonded in a single-bond geometry to one C(41) atom. In the thirtieth H site, H(30) is bonded in a single-bond geometry to one C(42) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(31) and one C(8) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(10) and one C(32) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(24) and one C(33) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(20) and one C(34) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(35) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one C(35) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cd(2) and one C(43) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Cd(2) and one C(43) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(2), and one C(44) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Cd(1), one Cd(2), and one C(36) atom. In the eleventh O site, O(11) is bonded in an L-shaped geometry to one Cd(2) and one C(36) atom. In the twelfth O site, O(12) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(44) atom. Linkers: 2 COc1c(-c2ccc(C([O])=O)cc2)cc(-c2ccc(C([O])=O)cc2)c(OC)c1-c1c(OC)c(-c2ccc(C([O])=O)cc2)cc(-c2ccc(C([O])=O)cc2)c1OC. Metal clusters: 1 [C]1O[Cd]23(O1)O[C]O[Cd]14(O[C]O2)(O[C]O3)O[C]O[Cd]2(O[C]O2)(O[C]O1)O[C]O4. RCSR code: flu. The MOF has largest included sphere 7.83 A, density 0.90 g/cm3, surface area 4407.93 m2/g, accessible volume 0.74 cm3/g