Co3C66N6H37O13(CH)6 crystallizes in the monoclinic C2 space group. The structure consists of twenty-four 02329_fluka molecules inside a Co3C66N6H37O13 framework. In the Co3C66N6H37O13 framework, there are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(3), one O(1), one O(11), one O(2), one O(7), and one O(9) atom to form corner-sharing CoNO5 octahedra. The corner-sharing octahedral tilt angles range from 64-66°. The Co(1)-N(3) bond length is 2.14 Å. The Co(1)-O(1) bond length is 2.05 Å. The Co(1)-O(11) bond length is 2.06 Å. The Co(1)-O(2) bond length is 2.03 Å. The Co(1)-O(7) bond length is 2.01 Å. The Co(1)-O(9) bond length is 2.08 Å. In the second Co site, Co(2) is bonded to one N(2), one O(1), one O(10), one O(12), one O(3), and one O(5) atom to form corner-sharing CoNO5 octahedra. The corner-sharing octahedral tilt angles range from 59-64°. The Co(2)-N(2) bond length is 2.12 Å. The Co(2)-O(1) bond length is 2.03 Å. The Co(2)-O(10) bond length is 2.08 Å. The Co(2)-O(12) bond length is 2.04 Å. The Co(2)-O(3) bond length is 2.06 Å. The Co(2)-O(5) bond length is 2.00 Å. In the third Co site, Co(3) is bonded to one N(1), one O(1), one O(13), one O(4), one O(6), and one O(8) atom to form corner-sharing CoNO5 octahedra. The corner-sharing octahedral tilt angles range from 59-66°. The Co(3)-N(1) bond length is 2.13 Å. The Co(3)-O(1) bond length is 2.03 Å. The Co(3)-O(13) bond length is 2.06 Å. The Co(3)-O(4) bond length is 2.01 Å. The Co(3)-O(6) bond length is 2.05 Å. The Co(3)-O(8) bond length is 2.05 Å. There are sixty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(5) atom. The C(1)-C(4) bond length is 1.50 Å. The C(1)-O(2) bond length is 1.27 Å. The C(1)-O(5) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(3), and one O(6) atom. The C(2)-C(5) bond length is 1.51 Å. The C(2)-O(3) bond length is 1.27 Å. The C(2)-O(6) bond length is 1.27 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(4), and one O(7) atom. The C(3)-C(6) bond length is 1.50 Å. The C(3)-O(4) bond length is 1.28 Å. The C(3)-O(7) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(19), and one C(7) atom. The C(4)-C(19) bond length is 1.40 Å. The C(4)-C(7) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(20), and one C(8) atom. The C(5)-C(20) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.39 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(21), one C(3), and one C(9) atom. The C(6)-C(21) bond length is 1.40 Å. The C(6)-C(9) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(10); one C(4); and one H(2,4) atom. The C(7)-C(10) bond length is 1.40 Å. The C(7)-H(2,4) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(11), one C(5), and one H(3) atom. The C(8)-C(11) bond length is 1.40 Å. The C(8)-H(3) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(12); one C(6); and one H(2,4) atom. The C(9)-C(12) bond length is 1.40 Å. The C(9)-H(2,4) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(13), one C(22), and one C(7) atom. The C(10)-C(13) bond length is 1.40 Å. The C(10)-C(22) bond length is 1.48 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(14), one C(23), and one C(8) atom. The C(11)-C(14) bond length is 1.40 Å. The C(11)-C(23) bond length is 1.48 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(15), one C(24), and one C(9) atom. The C(12)-C(15) bond length is 1.40 Å. The C(12)-C(24) bond length is 1.48 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(10) and one H(5,6,7) atom. The C(13)-H(5,6,7) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(11) and one H(5,6,7) atom. The C(14)-H(5,6,7) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(12) and one H(5,6,7) atom. The C(15)-H(5,6,7) bond length is 1.09 Å. In the sixteenth C site, C(16,18) is bonded in a distorted single-bond geometry to one C(19) and one H(8,10) atom. The C(16,18)-C(19) bond length is 1.40 Å. The C(16,18)-H(8,10) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(20) and one H(9) atom. The C(17)-C(20) bond length is 1.40 Å. The C(17)-H(9) bond length is 1.09 Å. In the eighteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(16,18); one C(4); and one H(11,13) atom. The C(19)-H(11,13) bond length is 1.09 Å. In the nineteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(17), one C(5), and one H(12) atom. The C(20)-H(12) bond length is 1.09 Å. In the twentieth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(16,18); one C(6); and one H(11,13) atom. The C(21)-C(16,18) bond length is 1.40 Å. The C(21)-H(11,13) bond length is 1.09 Å. In the twenty-first C site, C(22) is bonded in a distorted trigonal planar geometry to one C(10), one C(25), and one N(4) atom. The C(22)-C(25) bond length is 1.40 Å. The C(22)-N(4) bond length is 1.34 Å. In the twenty-second C site, C(23) is bonded in a distorted trigonal planar geometry to one C(11), one C(26), and one N(5) atom. The C(23)-C(26) bond length is 1.40 Å. The C(23)-N(5) bond length is 1.34 Å. In the twenty-third C site, C(24) is bonded in a distorted trigonal planar geometry to one C(12), one C(27), and one N(6) atom. The C(24)-C(27) bond length is 1.40 Å. The C(24)-N(6) bond length is 1.34 Å. In the twenty-fourth C site, C(25) is bonded in a distorted single-bond geometry to one C(22), one C(28), and one H(14) atom. The C(25)-C(28) bond length is 1.39 Å. The C(25)-H(14) bond length is 1.09 Å. In the twenty-fifth C site, C(26) is bonded in a distorted single-bond geometry to one C(23), one C(29), and one H(15) atom. The C(26)-C(29) bond length is 1.39 Å. The C(26)-H(15) bond length is 1.09 Å. In the twenty-sixth C site, C(27) is bonded in a distorted single-bond geometry to one C(24), one C(30), and one H(16) atom. The C(27)-C(30) bond length is 1.40 Å. The C(27)-H(16) bond length is 1.09 Å. In the twenty-seventh C site, C(28) is bonded in a trigonal planar geometry to one C(25), one C(31), and one C(46) atom. The C(28)-C(31) bond length is 1.48 Å. The C(28)-C(46) bond length is 1.40 Å. In the twenty-eighth C site, C(29) is bonded in a trigonal planar geometry to one C(26), one C(32), and one C(47) atom. The C(29)-C(32) bond length is 1.48 Å. The C(29)-C(47) bond length is 1.40 Å. In the twenty-ninth C site, C(30) is bonded in a trigonal planar geometry to one C(27), one C(33), and one C(48) atom. The C(30)-C(33) bond length is 1.48 Å. The C(30)-C(48) bond length is 1.40 Å. In the thirtieth C site, C(31) is bonded in a trigonal planar geometry to one C(28), one C(34), and one C(43) atom. The C(31)-C(34) bond length is 1.40 Å. The C(31)-C(43) bond length is 1.41 Å. In the thirty-first C site, C(32) is bonded in a trigonal planar geometry to one C(29), one C(35), and one C(44) atom. The C(32)-C(35) bond length is 1.40 Å. The C(32)-C(44) bond length is 1.41 Å. In the thirty-second C site, C(33) is bonded in a trigonal planar geometry to one C(30), one C(36), and one C(45) atom. The C(33)-C(36) bond length is 1.40 Å. The C(33)-C(45) bond length is 1.41 Å. In the thirty-third C site, C(34) is bonded in a distorted trigonal planar geometry to one C(31), one N(1), and one H(17) atom. The C(34)-N(1) bond length is 1.34 Å. The C(34)-H(17) bond length is 1.09 Å. In the thirty-fourth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(32), one N(2), and one H(18) atom. The C(35)-N(2) bond length is 1.34 Å. The C(35)-H(18) bond length is 1.09 Å. In the thirty-fifth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(33), one N(3), and one H(19) atom. The C(36)-N(3) bond length is 1.34 Å. The C(36)-H(19) bond length is 1.09 Å. In the thirty-sixth C site, C(37) is bonded in a distorted trigonal planar geometry to one N(1) and one H(20) atom. The C(37)-N(1) bond length is 1.34 Å. The C(37)-H(20) bond length is 1.09 Å. In the thirty-seventh C site, C(38) is bonded in a distorted trigonal planar geometry to one N(2) and one H(21) atom. The C(38)-N(2) bond length is 1.34 Å. The C(38)-H(21) bond length is 1.09 Å. In the thirty-eighth C site, C(39) is bonded in a distorted trigonal planar geometry to one N(3) and one H(22) atom. The C(39)-N(3) bond length is 1.34 Å. The C(39)-H(22) bond length is 1.09 Å. In the thirty-ninth C site, C(43) is bonded in a distorted single-bond geometry to one C(31) and one H(26) atom. The C(43)-H(26) bond length is 1.09 Å. In the fortieth C site, C(44) is bonded in a distorted single-bond geometry to one C(32) and one H(27,28) atom. The C(44)-H(27,28) bond length is 1.09 Å. In the forty-first C site, C(45) is bonded in a distorted single-bond geometry to one C(33) and one H(27,28) atom. The C(45)-H(27,28) bond length is 1.09 Å. In the forty-second C site, C(46) is bonded in a distorted single-bond geometry to one C(28); one C(49); and one H(29,31) atom. The C(46)-C(49) bond length is 1.40 Å. The C(46)-H(29,31) bond length is 1.08 Å. In the forty-third C site, C(47) is bonded in a distorted single-bond geometry to one C(29), one C(50), and one H(30) atom. The C(47)-C(50) bond length is 1.40 Å. The C(47)-H(30) bond length is 1.08 Å. In the forty-fourth C site, C(48) is bonded in a distorted single-bond geometry to one C(30); one C(51); and one H(29,31) atom. The C(48)-C(51) bond length is 1.40 Å. The C(48)-H(29,31) bond length is 1.08 Å. In the forty-fifth C site, C(49) is bonded in a distorted trigonal planar geometry to one C(46); one C(52,54); and one N(4) atom. The C(49)-C(52,54) bond length is 1.48 Å. The C(49)-N(4) bond length is 1.35 Å. In the forty-sixth C site, C(50) is bonded in a distorted trigonal planar geometry to one C(47), one C(53), and one N(5) atom. The C(50)-C(53) bond length is 1.48 Å. The C(50)-N(5) bond length is 1.35 Å. In the forty-seventh C site, C(51) is bonded in a distorted trigonal planar geometry to one C(48); one C(52,54); and one N(6) atom. The C(51)-C(52,54) bond length is 1.48 Å. The C(51)-N(6) bond length is 1.35 Å. In the forty-eighth C site, C(52,54) is bonded in a trigonal planar geometry to one C(49); one C(55); and one C(67,68) atom. The C(52,54)-C(55) bond length is 1.40 Å. The C(52,54)-C(67,68) bond length is 1.41 Å. In the forty-ninth C site, C(53) is bonded in a trigonal planar geometry to one C(50); one C(56); and one C(67,68) atom. The C(53)-C(56) bond length is 1.40 Å. The C(53)-C(67,68) bond length is 1.41 Å. In the fiftieth C site, C(55) is bonded in a distorted single-bond geometry to one C(52,54); one C(58); and one H(32,34) atom. The C(55)-C(58) bond length is 1.40 Å. The C(55)-H(32,34) bond length is 1.09 Å. In the fifty-first C site, C(56) is bonded in a distorted single-bond geometry to one C(53), one C(59), and one H(33) atom. The C(56)-C(59) bond length is 1.40 Å. The C(56)-H(33) bond length is 1.09 Å. In the fifty-second C site, C(57) is bonded in a distorted single-bond geometry to one C(52,54); one C(60); and one H(32,34) atom. The C(57)-C(52,54) bond length is 1.40 Å. The C(57)-C(60) bond length is 1.40 Å. The C(57)-H(32,34) bond length is 1.09 Å. In the fifty-third C site, C(58) is bonded in a trigonal planar geometry to one C(55), one C(61), and one C(70) atom. The C(58)-C(61) bond length is 1.40 Å. The C(58)-C(70) bond length is 1.50 Å. In the fifty-fourth C site, C(59) is bonded in a trigonal planar geometry to one C(56), one C(62), and one C(71) atom. The C(59)-C(62) bond length is 1.40 Å. The C(59)-C(71) bond length is 1.50 Å. In the fifty-fifth C site, C(60) is bonded in a trigonal planar geometry to one C(57), one C(63), and one C(72) atom. The C(60)-C(63) bond length is 1.40 Å. The C(60)-C(72) bond length is 1.50 Å. In the fifty-sixth C site, C(61) is bonded in a distorted single-bond geometry to one C(58) and one H(35,37) atom. The C(61)-H(35,37) bond length is 1.09 Å. In the fifty-seventh C site, C(62) is bonded in a distorted single-bond geometry to one C(59) and one H(36) atom. The C(62)-H(36) bond length is 1.09 Å. In the fifty-eighth C site, C(63) is bonded in a distorted single-bond geometry to one C(60) and one H(35,37) atom. The C(63)-H(35,37) bond length is 1.09 Å. In the fifty-ninth C site, C(67,68) is bonded in a distorted single-bond geometry to one C(52,54) and one H(41,43) atom. The C(67,68)-H(41,43) bond length is 1.09 Å. In the sixtieth C site, C(69) is bonded in a distorted single-bond geometry to one C(52,54) and one H(41,43) atom. The C(69)-C(52,54) bond length is 1.41 Å. The C(69)-H(41,43) bond length is 1.09 Å. In the sixty-first C site, C(70) is bonded in a distorted bent 120 degrees geometry to one C(58), one O(11), and one O(8) atom. The C(70)-O(11) bond length is 1.28 Å. The C(70)-O(8) bond length is 1.28 Å. In the sixty-second C site, C(71) is bonded in a distorted bent 120 degrees geometry to one C(59), one O(12), and one O(9) atom. The C(71)-O(12) bond length is 1.28 Å. The C(71)-O(9) bond length is 1.27 Å. In the sixty-third C site, C(72) is bonded in a distorted bent 120 degrees geometry to one C(60), one O(10), and one O(13) atom. The C(72)-O(10) bond length is 1.27 Å. The C(72)-O(13) bond length is 1.28 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(3), one C(34), and one C(37) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(2), one C(35), and one C(38) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(36), and one C(39) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(22) and one C(49) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(23) and one C(50) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one C(24) and one C(51) atom. There are twenty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.98 Å. In the second H site, H(2,4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(5,6,7) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(8,10) is bonded in a single-bond geometry to one C(16,18) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(11,13) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(34) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(35) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(36) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(37) atom. In the sixteenth H site, H(21) is bonded in a single-bond geometry to one C(38) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one C(39) atom. In the eighteenth H site, H(26) is bonded in a single-bond geometry to one C(43) atom. In the nineteenth H site, H(27,28) is bonded in a single-bond geometry to one C(44) atom. In the twentieth H site, H(29,31) is bonded in a single-bond geometry to one C(46) atom. In the twenty-first H site, H(30) is bonded in a single-bond geometry to one C(47) atom. In the twenty-second H site, H(32,34) is bonded in a single-bond geometry to one C(55) atom. In the twenty-third H site, H(33) is bonded in a single-bond geometry to one C(56) atom. In the twenty-fourth H site, H(35,37) is bonded in a single-bond geometry to one C(61) atom. In the twenty-fifth H site, H(36) is bonded in a single-bond geometry to one C(62) atom. In the twenty-sixth H site, H(41,43) is bonded in a single-bond geometry to one C(67,68) atom. In the twenty-seventh H site, H(42) is bonded in a single-bond geometry to one C(67,68) atom. The H(42)-C(67,68) bond length is 1.09 Å. There are thirteen inequivalent O sites. In the first O site, O(10) is bonded in a bent 120 degrees geometry to one Co(2) and one C(72) atom. In the second O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(70) atom. In the third O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(71) atom. In the fourth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Co(3) and one C(72) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to one Co(1), one Co(2), one Co(3), and one H(1) atom. In the sixth O site, O(2) is bonded in a bent 150 degrees geometry to one Co(1) and one C(1) atom. In the seventh O site, O(3) is bonded in a bent 150 degrees geometry to one Co(2) and one C(2) atom. In the eighth O site, O(4) is bonded in a bent 150 degrees geometry to one Co(3) and one C(3) atom. In the ninth O site, O(5) is bonded in a bent 120 degrees geometry to one Co(2) and one C(1) atom. In the tenth O site, O(6) is bonded in a bent 120 degrees geometry to one Co(3) and one C(2) atom. In the eleventh O site, O(7) is bonded in a bent 120 degrees geometry to one Co(1) and one C(3) atom. In the twelfth O site, O(8) is bonded in a bent 120 degrees geometry to one Co(3) and one C(70) atom. In the thirteenth O site, O(9) is bonded in a bent 120 degrees geometry to one Co(1) and one C(71) atom. Linkers: 6 [O]C(=O)c1cccc(-c2cc(-c3cccnc3)cc(-c3cccc(C([O])=O)c3)n2)c1. Metal clusters: 2 O[Co]123O[C]O[Co]4(O[C]O[Co](O[C]O4)(O[C]O1)O[C]O2)O[C]O3. RCSR code: pcu. The MOF has largest included sphere 5.72 A, density 1.25 g/cm3, surface area 4189.88 m2/g, accessible volume 0.29 cm3/g