ZnC14H11(NO2)2(CH)8 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules; two 2,4-dimethyl-1,3-pentadiene molecules; and one ZnC14H11(NO2)2 cluster. In the ZnC14H11(NO2)2 cluster, Zn(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.05 Å. The Zn(1)-O(1) bond length is 2.08 Å. The Zn(1)-O(2) bond length is 2.06 Å. The Zn(1)-O(3) bond length is 2.07 Å. The Zn(1)-O(4) bond length is 2.07 Å. There are fourteen inequivalent C sites. In the first C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(2)-O(1) bond length is 1.28 Å. The C(2)-O(2) bond length is 1.27 Å. In the second C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(10)-O(3) bond length is 1.27 Å. The C(10)-O(4) bond length is 1.27 Å. In the third C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one C(12), one H(10), one H(11), and one H(9) atom. The C(11)-C(12) bond length is 1.48 Å. The C(11)-H(10) bond length is 1.10 Å. The C(11)-H(11) bond length is 1.10 Å. The C(11)-H(9) bond length is 1.09 Å. In the fourth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one N(2) atom. The C(12)-N(1) bond length is 1.34 Å. The C(12)-N(2) bond length is 1.37 Å. In the fifth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one C(21), and one N(1) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(21) bond length is 1.40 Å. The C(13)-N(1) bond length is 1.40 Å. In the sixth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(18), and one N(2) atom. The C(14)-C(18) bond length is 1.40 Å. The C(14)-N(2) bond length is 1.39 Å. In the seventh C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one C(16), one N(2), one H(12), and one H(13) atom. The C(15)-C(16) bond length is 1.51 Å. The C(15)-N(2) bond length is 1.46 Å. The C(15)-H(12) bond length is 1.10 Å. The C(15)-H(13) bond length is 1.10 Å. In the eighth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(22) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(22) bond length is 1.40 Å. In the ninth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(14) atom. The C(17)-H(14) bond length is 1.09 Å. In the tenth C site, C(18) is bonded in a distorted single-bond geometry to one C(14) and one H(15) atom. The C(18)-H(15) bond length is 1.09 Å. In the eleventh C site, C(19) is bonded in a distorted single-bond geometry to one C(20) and one H(16) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-H(16) bond length is 1.09 Å. In the twelfth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one H(17) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(17) bond length is 1.09 Å. In the thirteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(13), one C(20), and one H(18) atom. The C(21)-H(18) bond length is 1.09 Å. In the fourteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(16) and one H(19) atom. The C(22)-H(19) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(12), and one C(13) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(15) atom. There are eleven inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(22) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(10) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(10) atom. Linkers: 2 [C]N(Cc1ccc(Cn2c(C)nc3ccccc32)cc1)C(C)=[N] ,1 Cc1nc2ccccc2n1Cc1ccc(Cn2c(C)nc3ccccc32)cc1 ,2 [O]C(=O)Cc1cccc(CC([O])=O)c1. Metal clusters: 1 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 2.51 A, density 1.54 g/cm3, surface area 4716.21 m2/g, accessible volume 0.17 cm3/g