CdC14N2H14S2O5 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CdC14N2H14S2O5 clusters. Cd(1) is bonded in a distorted pentagonal bipyramidal geometry to two equivalent N(1), one O(3), two equivalent O(1), and two equivalent O(2) atoms. Both Cd(1)-N(1) bond lengths are 2.31 Å. The Cd(1)-O(3) bond length is 2.33 Å. Both Cd(1)-O(1) bond lengths are 2.58 Å. Both Cd(1)-O(2) bond lengths are 2.47 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(5), and one H(2) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(5) bond length is 1.41 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one H(3) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(4) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(5) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(5) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(4), and one S(1) atom. The C(5)-S(1) bond length is 1.74 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one H(6), one H(7), and one S(1) atom. The C(6)-H(6) bond length is 1.10 Å. The C(6)-H(7) bond length is 1.10 Å. The C(6)-S(1) bond length is 1.79 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(7)-O(1) bond length is 1.27 Å. The C(7)-O(2) bond length is 1.27 Å. N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(2), and one C(3) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. The H(1)-O(3) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. S(1) is bonded in a water-like geometry to one C(5) and one C(6) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(7) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(1) and two equivalent H(1) atoms. Linkers: 4 [O]C(=O)CSc1ccncc1. Metal clusters: 2 O.O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 1.85 A, density 1.91 g/cm3, surface area 4052.25 m2/g, accessible volume 0.14 cm3/g