(CH)2(CH2)4ZnC20H14S(N2O3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, eight 02329_fluka molecules, and two ZnC20H14S(N2O3)2 clusters. In each ZnC20H14S(N2O3)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(4), one O(2), and one O(3) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-N(4) bond length is 2.06 Å. The Zn(1)-O(2) bond length is 1.93 Å. The Zn(1)-O(3) bond length is 1.95 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.31 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(5)-O(3) bond length is 1.30 Å. The C(5)-O(4) bond length is 1.25 Å. In the third C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(11) atom. The C(9)-N(1) bond length is 1.33 Å. The C(9)-N(2) bond length is 1.36 Å. The C(9)-H(11) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one H(12) atom. The C(10)-C(11) bond length is 1.37 Å. The C(10)-N(1) bond length is 1.38 Å. The C(10)-H(12) bond length is 1.08 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(13) atom. The C(11)-N(2) bond length is 1.39 Å. The C(11)-H(13) bond length is 1.08 Å. In the sixth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one C(17), and one N(2) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(17) bond length is 1.40 Å. The C(12)-N(2) bond length is 1.42 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(14) atom. The C(13)-H(14) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(15) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(15) bond length is 1.09 Å. In the ninth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one S(1) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-S(1) bond length is 1.78 Å. In the tenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(16) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(16) bond length is 1.09 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one H(17) atom. The C(17)-H(17) bond length is 1.09 Å. In the twelfth C site, C(18) is bonded in a trigonal planar geometry to one C(19), one C(23), and one S(1) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(23) bond length is 1.40 Å. The C(18)-S(1) bond length is 1.77 Å. In the thirteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(18) atom. The C(19)-H(18) bond length is 1.09 Å. In the fourteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(19) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(19) bond length is 1.09 Å. In the fifteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one N(3) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-N(3) bond length is 1.42 Å. In the sixteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(20) atom. The C(22)-H(20) bond length is 1.09 Å. In the seventeenth C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(21) atom. The C(23)-H(21) bond length is 1.09 Å. In the eighteenth C site, C(24) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(22) atom. The C(24)-N(3) bond length is 1.37 Å. The C(24)-N(4) bond length is 1.33 Å. The C(24)-H(22) bond length is 1.08 Å. In the nineteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(26), one N(4), and one H(23) atom. The C(25)-C(26) bond length is 1.37 Å. The C(25)-N(4) bond length is 1.39 Å. The C(25)-H(23) bond length is 1.08 Å. In the twentieth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(25), one N(3), and one H(24) atom. The C(26)-N(3) bond length is 1.39 Å. The C(26)-H(24) bond length is 1.08 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(21), one C(24), and one C(26) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(24), and one C(25) atom. There are fourteen inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(24) atom. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one C(25) atom. In the fourteenth H site, H(24) is bonded in a single-bond geometry to one C(26) atom. S(1) is bonded in a distorted bent 120 degrees geometry to one C(15), one C(18), one O(5), and one O(6) atom. The S(1)-O(5) bond length is 1.46 Å. The S(1)-O(6) bond length is 1.45 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. Linkers: 2 [O]C(=O)[C@H]1CC[C@H](C([O])=O)CC1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.99 A, density 1.47 g/cm3, surface area 4747.53 m2/g, accessible volume 0.18 cm3/g