ZnC13N5H6O4(CH)5C4NH3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twenty 02329_fluka molecules, four methylene propyleneamine molecules, and four ZnC13N5H6O4 clusters. In each ZnC13N5H6O4 cluster, Zn(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(5), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 2.07 Å. The Zn(1)-N(2) bond length is 2.20 Å. The Zn(1)-N(5) bond length is 2.37 Å. The Zn(1)-O(1) bond length is 1.95 Å. The Zn(1)-O(3) bond length is 1.97 Å. There are thirteen inequivalent C sites. In the first C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one N(2), and one H(12) atom. The C(18)-C(17) bond length is 1.40 Å. The C(18)-N(2) bond length is 1.34 Å. The C(18)-H(12) bond length is 1.09 Å. In the second C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(19)-O(1) bond length is 1.30 Å. The C(19)-O(2) bond length is 1.25 Å. In the third C site, C(22) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(22)-O(3) bond length is 1.31 Å. The C(22)-O(4) bond length is 1.25 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one N(3) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(3) bond length is 1.33 Å. In the fifth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(11), and one N(5) atom. The C(2)-C(11) bond length is 1.40 Å. The C(2)-N(5) bond length is 1.35 Å. In the sixth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(15), one C(4), and one N(2) atom. The C(3)-C(15) bond length is 1.40 Å. The C(3)-C(4) bond length is 1.48 Å. The C(3)-N(2) bond length is 1.35 Å. In the seventh C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one N(4) atom. The C(4)-N(1) bond length is 1.34 Å. The C(4)-N(4) bond length is 1.33 Å. In the eighth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(3) and one N(4) atom. The C(5)-N(3) bond length is 1.35 Å. The C(5)-N(4) bond length is 1.35 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(11)-H(5) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(7) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-H(7) bond length is 1.09 Å. In the eleventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(5), and one H(8) atom. The C(14)-N(5) bond length is 1.33 Å. The C(14)-H(8) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(3) and one H(9) atom. The C(15)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(11) atom. The C(17)-H(11) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(18), and one C(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(5) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(4) and one C(5) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(14), and one C(2) atom. There are six inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(19) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(19) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(22) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(22) atom. Linkers: 4 [O]C(=O)/C=C/C([O])=O. Metal clusters: 4 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.68 A, density 1.41 g/cm3, surface area 4597.98 m2/g, accessible volume 0.19 cm3/g