ZnC14N2H14S2O5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC14N2H14S2O5 clusters. Zn(1) is bonded in a distorted pentagonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(2), one O(3), one O(4), and one O(5) atom. The Zn(1)-N(1) bond length is 2.11 Å. The Zn(1)-N(2) bond length is 2.11 Å. The Zn(1)-O(1) bond length is 2.49 Å. The Zn(1)-O(2) bond length is 2.49 Å. The Zn(1)-O(3) bond length is 2.25 Å. The Zn(1)-O(4) bond length is 2.25 Å. The Zn(1)-O(5) bond length is 2.11 Å. There are eight inequivalent C sites. In the first C site, C(1,2) is bonded in a trigonal planar geometry to one C(3,4); one C(9,10); and one S(1,2) atom. The C(1,2)-C(3,4) bond length is 1.41 Å. The C(1,2)-C(9,10) bond length is 1.41 Å. The C(1,2)-S(1,2) bond length is 1.74 Å. In the second C site, C(3,4) is bonded in a distorted trigonal planar geometry to one C(1,2); one C(5,6); and one H(3,4) atom. The C(3,4)-C(5,6) bond length is 1.39 Å. The C(3,4)-H(3,4) bond length is 1.09 Å. In the third C site, C(5,6) is bonded in a distorted trigonal planar geometry to one C(3,4); one N(1); and one H(5,6) atom. The C(5,6)-N(1) bond length is 1.35 Å. The C(5,6)-H(5,6) bond length is 1.09 Å. In the fourth C site, C(7,8) is bonded in a distorted trigonal planar geometry to one C(9,10); one N(1); and one H(7,8) atom. The C(7,8)-C(9,10) bond length is 1.39 Å. The C(7,8)-N(1) bond length is 1.35 Å. The C(7,8)-H(7,8) bond length is 1.09 Å. In the fifth C site, C(9,10) is bonded in a distorted single-bond geometry to one C(1,2); one C(7,8); and one H(9,10) atom. The C(9,10)-H(9,10) bond length is 1.09 Å. In the sixth C site, C(11,12) is bonded in a distorted water-like geometry to one H(11,12); one H(13,14); and one S(1,2) atom. The C(11,12)-H(11,12) bond length is 1.10 Å. The C(11,12)-H(13,14) bond length is 1.10 Å. The C(11,12)-S(1,2) bond length is 1.79 Å. In the seventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(13)-O(1) bond length is 1.27 Å. The C(13)-O(3) bond length is 1.27 Å. In the eighth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(14)-O(2) bond length is 1.27 Å. The C(14)-O(4) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1); one C(5,6); and one C(7,8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1); one C(5,6); and one C(7,8) atom. The N(2)-C(5,6) bond length is 1.35 Å. The N(2)-C(7,8) bond length is 1.35 Å. There are seven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one O(5) atom. The H(1,2)-O(5) bond length is 0.99 Å. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(3,4) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(5,6) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(7,8) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(9,10) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(11,12) atom. In the seventh H site, H(13,14) is bonded in a single-bond geometry to one C(11,12) atom. S(1,2) is bonded in a water-like geometry to one C(1,2) and one C(11,12) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Zn(1) and one C(13) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Zn(1) and one C(14) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Zn(1) and one C(13) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Zn(1) and one C(14) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Zn(1) and two equivalent H(1,2) atoms. Linkers: 4 [O]C(=O)CSc1ccncc1. Metal clusters: 2 O.O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 1.49 A, density 1.80 g/cm3, surface area 4189.01 m2/g, accessible volume 0.09 cm3/g