ZnC4NH2O4(CH)11(C8H5SO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty-two 02329_fluka molecules, two C8H5SO clusters, and one ZnC4NH2O4 cluster. In each C8H5SO cluster, there are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(3), and one O(1) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-C(3) bond length is 1.39 Å. The C(1)-O(1) bond length is 1.37 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(7) atom. The C(2)-C(10) bond length is 1.42 Å. The C(2)-C(7) bond length is 1.43 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(6), and one S(2) atom. The C(3)-C(6) bond length is 1.44 Å. The C(3)-S(2) bond length is 1.77 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(6), one C(7), and one O(2) atom. The C(4)-C(6) bond length is 1.39 Å. The C(4)-C(7) bond length is 1.42 Å. The C(4)-O(2) bond length is 1.37 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(8) and one H(1) atom. The C(5)-C(8) bond length is 1.40 Å. The C(5)-H(1) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(3), one C(4), and one S(1) atom. The C(6)-S(1) bond length is 1.76 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(2), and one C(4) atom. The C(7)-C(12) bond length is 1.42 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(5), and one S(1) atom. The C(8)-C(11) bond length is 1.40 Å. The C(8)-S(1) bond length is 1.77 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(16), one C(17), and one S(2) atom. The C(9)-C(16) bond length is 1.40 Å. The C(9)-C(17) bond length is 1.40 Å. The C(9)-S(2) bond length is 1.78 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(10)-H(2) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(8) and one H(3) atom. The C(11)-H(3) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(12)-H(4) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(16)-H(8) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(9) and one H(9) atom. The C(17)-H(9) bond length is 1.09 Å. In the fifteenth C site, C(24) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(15,16) and one O(1) atom. Both C(24)-H(15,16) bond lengths are 1.10 Å. The C(24)-O(1) bond length is 1.43 Å. In the sixteenth C site, C(25) is bonded in a distorted trigonal non-coplanar geometry to one H(17), one H(18), and one O(2) atom. The C(25)-H(17) bond length is 1.10 Å. The C(25)-H(18) bond length is 1.10 Å. The C(25)-O(2) bond length is 1.44 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(15,16) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(25) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(6) and one C(8) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(3) and one C(9) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(24) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(25) and one C(4) atom. In the ZnC4NH2O4 cluster, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one O(3), one O(4), one O(5), and one O(6) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(3) bond length is 2.05 Å. The Zn(1)-O(4) bond length is 2.12 Å. The Zn(1)-O(5) bond length is 2.06 Å. The Zn(1)-O(6) bond length is 2.10 Å. There are four inequivalent C sites. In the first C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(19) atom. The C(26)-N(1) bond length is 1.35 Å. The C(26)-H(19) bond length is 1.09 Å. In the second C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(20) atom. The C(27)-N(1) bond length is 1.35 Å. The C(27)-H(20) bond length is 1.09 Å. In the third C site, C(31) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(5) atom. The C(31)-O(3) bond length is 1.27 Å. The C(31)-O(5) bond length is 1.27 Å. In the fourth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. The C(23)-O(4) bond length is 1.26 Å. The C(23)-O(6) bond length is 1.27 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(26), and one C(27) atom. There are two inequivalent H sites. In the first H site, H(19) is bonded in a single-bond geometry to one C(26) atom. In the second H site, H(20) is bonded in a single-bond geometry to one C(27) atom. There are four inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(31) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(31) atom. In the third O site, O(4) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(23) atom. In the fourth O site, O(6) is bonded in a water-like geometry to one Zn(1) and one C(23) atom. Linkers: 2 [O]C(=O)COc1c(Sc2ccccc2)c(Sc2ccccc2)c(OCC([O])=O)c2ccccc12. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.42 A, density 1.54 g/cm3, surface area 4590.96 m2/g, accessible volume 0.14 cm3/g