Ag6C6NH9O15(CH)6 crystallizes in the triclinic P-1 space group. The structure consists of twelve 02329_fluka molecules inside a Ag6C6NH9O15 framework. In the Ag6C6NH9O15 framework, there are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(13), one O(3), and two equivalent O(1) atoms. The Ag(1)-O(13) bond length is 2.25 Å. The Ag(1)-O(3) bond length is 2.56 Å. There is one shorter (2.23 Å) and one longer (2.50 Å) Ag(1)-O(1) bond length. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(14), one O(2), and one O(5) atom. The Ag(2)-O(14) bond length is 2.50 Å. The Ag(2)-O(2) bond length is 2.20 Å. The Ag(2)-O(5) bond length is 2.25 Å. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to one O(15), one O(3), one O(6), and one O(7) atom. The Ag(3)-O(15) bond length is 2.32 Å. The Ag(3)-O(3) bond length is 2.33 Å. The Ag(3)-O(6) bond length is 2.50 Å. The Ag(3)-O(7) bond length is 2.36 Å. In the fourth Ag site, Ag(4) is bonded in a distorted T-shaped geometry to one O(12), one O(7), and one O(9) atom. The Ag(4)-O(12) bond length is 2.20 Å. The Ag(4)-O(7) bond length is 2.23 Å. The Ag(4)-O(9) bond length is 2.59 Å. In the fifth Ag site, Ag(5) is bonded in a linear geometry to one O(4) and one O(8) atom. The Ag(5)-O(4) bond length is 2.16 Å. The Ag(5)-O(8) bond length is 2.14 Å. In the sixth Ag site, Ag(6) is bonded in a distorted T-shaped geometry to one N(1), one O(10), and one O(11) atom. The Ag(6)-N(1) bond length is 2.12 Å. The Ag(6)-O(10) bond length is 2.58 Å. The Ag(6)-O(11) bond length is 2.11 Å. There are six inequivalent C sites. In the first C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(7)-O(1) bond length is 1.28 Å. The C(7)-O(2) bond length is 1.27 Å. In the second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.28 Å. The C(8)-O(4) bond length is 1.27 Å. In the third C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(9)-O(5) bond length is 1.29 Å. The C(9)-O(6) bond length is 1.26 Å. In the fourth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(10)-O(7) bond length is 1.28 Å. The C(10)-O(8) bond length is 1.26 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(11)-O(10) bond length is 1.27 Å. The C(11)-O(9) bond length is 1.28 Å. In the sixth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. The C(12)-O(11) bond length is 1.27 Å. The C(12)-O(12) bond length is 1.27 Å. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(6), one H(7), one H(8), and one H(9) atom. The N(1)-H(7) bond length is 1.02 Å. The N(1)-H(8) bond length is 1.03 Å. The N(1)-H(9) bond length is 1.02 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(13) atom. The H(1)-O(13) bond length is 0.99 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(13) and one O(5) atom. The H(2)-O(13) bond length is 1.00 Å. The H(2)-O(5) bond length is 1.61 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(14) atom. The H(3)-O(14) bond length is 1.00 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(14) atom. The H(4)-O(14) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(15) atom. The H(5)-O(15) bond length is 1.00 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(15) atom. The H(6)-O(15) bond length is 1.00 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(1) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(1) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(1) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one C(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ag(2) and one C(7) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(3), and one C(8) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ag(5) and one C(8) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Ag(2), one C(9), and one H(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Ag(3) and one C(9) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Ag(3), one Ag(4), and one C(10) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Ag(5) and one C(10) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Ag(4) and one C(11) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Ag(6) and one C(11) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Ag(6) and one C(12) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Ag(4) and one C(12) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one Ag(1), one H(1), and one H(2) atom. In the fourteenth O site, O(14) is bonded in a water-like geometry to one Ag(2), one H(3), and one H(4) atom. In the fifteenth O site, O(15) is bonded in a distorted water-like geometry to one Ag(3), one H(5), and one H(6) atom. Linkers: 2 [O]C(=O)[C@H]1[C@@H](C([O])=O)[C@@H](C([O])=O)[C@@H](C([O])=O)[C@@H](C([O])=O)[C@H]1C([O])=O. Metal clusters: 12 [Ag]. The MOF has largest included sphere 2.20 A, density 3.59 g/cm3, surface area 1646.36 m2/g, accessible volume 0.04 cm3/g