Ag2C11N6H20O7Cl(CH3CHO)2ClO4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four dimethyl ether molecules, two hypochlorous acid;trihydrate molecules, and one Ag2C11N6H20O7Cl cluster. In the Ag2C11N6H20O7Cl cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one N(1), one O(10), one O(7), and two equivalent O(1) atoms. The Ag(1)-N(1) bond length is 2.25 Å. The Ag(1)-O(10) bond length is 2.72 Å. The Ag(1)-O(7) bond length is 2.63 Å. There is one shorter (2.29 Å) and one longer (2.74 Å) Ag(1)-O(1) bond length. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one N(2) and one O(2) atom. The Ag(2)-N(2) bond length is 2.20 Å. The Ag(2)-O(2) bond length is 2.20 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(2), one N(3), and one N(4) atom. The C(1)-N(2) bond length is 1.37 Å. The C(1)-N(3) bond length is 1.34 Å. The C(1)-N(4) bond length is 1.35 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one N(5) atom. The C(2)-N(1) bond length is 1.38 Å. The C(2)-N(3) bond length is 1.34 Å. The C(2)-N(5) bond length is 1.35 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(6) atom. The C(3)-N(1) bond length is 1.35 Å. The C(3)-N(2) bond length is 1.36 Å. The C(3)-N(6) bond length is 1.36 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(5), one H(5), and one H(6) atom. The C(4)-N(5) bond length is 1.46 Å. The C(4)-H(5) bond length is 1.09 Å. The C(4)-H(6) bond length is 1.10 Å. In the fifth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(11), and one H(12) atom. The C(7)-N(6) bond length is 1.46 Å. The C(7)-H(11) bond length is 1.10 Å. The C(7)-H(12) bond length is 1.11 Å. In the sixth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(17), and one H(18) atom. The C(10)-N(6) bond length is 1.46 Å. The C(10)-H(17) bond length is 1.10 Å. The C(10)-H(18) bond length is 1.09 Å. In the seventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(19), and one H(20) atom. The C(11)-N(4) bond length is 1.46 Å. The C(11)-H(19) bond length is 1.09 Å. The C(11)-H(20) bond length is 1.10 Å. In the eighth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one H(21), one H(22), and one O(7) atom. The C(12)-H(21) bond length is 1.10 Å. The C(12)-H(22) bond length is 1.11 Å. The C(12)-O(7) bond length is 1.44 Å. In the ninth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one H(23), one H(24), and one O(7) atom. The C(13)-H(23) bond length is 1.11 Å. The C(13)-H(24) bond length is 1.10 Å. The C(13)-O(7) bond length is 1.43 Å. In the tenth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(4) and two equivalent H(25,26) atoms. The C(14)-N(4) bond length is 1.46 Å. There is one shorter (1.09 Å) and one longer (1.10 Å) C(14)-H(25,26) bond length. In the eleventh C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one N(5), one H(27), and one H(28) atom. The C(15)-N(5) bond length is 1.46 Å. The C(15)-H(27) bond length is 1.10 Å. The C(15)-H(28) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(1), and one C(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(14) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(15), one C(2), and one C(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(10), one C(3), and one C(7) atom. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. The H(3)-O(1) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(11) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(12) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(12) atom. In the fifteenth H site, H(23) is bonded in a single-bond geometry to one C(13) atom. In the sixteenth H site, H(24) is bonded in a single-bond geometry to one C(13) atom. In the seventeenth H site, H(25,26) is bonded in a single-bond geometry to one C(14) atom. In the eighteenth H site, H(27) is bonded in a single-bond geometry to one C(15) atom. In the nineteenth H site, H(28) is bonded in a single-bond geometry to one C(15) atom. There are seven inequivalent O sites. In the first O site, O(12) is bonded in a single-bond geometry to one Cl(2) atom. The O(12)-Cl(2) bond length is 1.46 Å. In the second O site, O(13) is bonded in a single-bond geometry to one Cl(2) atom. The O(13)-Cl(2) bond length is 1.48 Å. In the third O site, O(1) is bonded in a distorted water-like geometry to two equivalent Ag(1), one H(2), and one H(3) atom. In the fourth O site, O(2) is bonded in a distorted water-like geometry to one Ag(2), one H(1), and one H(4) atom. In the fifth O site, O(7) is bonded in a distorted water-like geometry to one Ag(1), one C(12), and one C(13) atom. In the sixth O site, O(10) is bonded in a distorted single-bond geometry to one Ag(1) and one Cl(2) atom. The O(10)-Cl(2) bond length is 1.46 Å. In the seventh O site, O(11) is bonded in a single-bond geometry to one Cl(2) atom. The O(11)-Cl(2) bond length is 1.46 Å. Cl(2) is bonded in a tetrahedral geometry to one O(10), one O(11), one O(12), and one O(13) atom. Linkers: 2 O1CCN(CC1)C1=NC(=[N]=C([N]1)N1CCOCC1)N1CCOCC1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.81 A, density 2.12 g/cm3, surface area 3511.68 m2/g, accessible volume 0.11 cm3/g