(CH2)2CdC2(O2Br)2(C6H5NH)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; eight 1-methyl-1,2-dihydropyridine molecules; and four CdC2(O2Br)2 clusters. In each CdC2(O2Br)2 cluster, Cd(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent Br(1) atoms. Both Cd(1)-O(1) bond lengths are 2.27 Å. Both Cd(1)-Br(1) bond lengths are 2.61 Å. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.25 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Br(1) is bonded in a single-bond geometry to one Cd(1) atom. Linkers: 1 [C]/C=C\N([C])[C@H]([C]=O)CC[C@H](C([O])=O)N1[CH]C=CC=C1 ,1 [O]C(=O)[C@@H](CC[C@@H](C([O])=O)N1[CH]C=CC=C1)N1[CH][C]=CC=C1 ,2 [O]C(=O)[C@@H](CC[C@@H](C([O])=O)N1[CH]C=CC=C1)N1[CH]C=CC=C1 ,1 [O]C(=O)[C@@H](CC[C@@H](C([O])=O)N1[CH][C]=CC=C1)N1[CH]C=CC=C1 ,1 [C]/C=C\N([C])[C@@H]([C]=O)CC[C@@H](C([O])=O)N1[CH]C=CC=C1. Metal clusters: 2 O=[C]O[Cd](Br)(Br)O[C]=O. The MOF has largest included sphere 2.57 A, density 2.02 g/cm3, surface area 3679.40 m2/g, accessible volume 0.15 cm3/g