(CH)10ZnC16P2H14(OI)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty 02329_fluka molecules and two ZnC16P2H14(OI)2 clusters. In each ZnC16P2H14(OI)2 cluster, Zn(1) is bonded to one O(1), one O(2), one I(1), and one I(2) atom to form distorted ZnI2O2 tetrahedra that share  a cornercorner with one P(1)C3O tetrahedra and  a cornercorner with one P(2)C3O tetrahedra. The Zn(1)-O(1) bond length is 1.98 Å. The Zn(1)-O(2) bond length is 2.00 Å. The Zn(1)-I(1) bond length is 2.59 Å. The Zn(1)-I(2) bond length is 2.57 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one H(1) atom. The C(1)-C(6) bond length is 1.41 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(4) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(5) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(5) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one P(1) atom. The C(6)-P(1) bond length is 1.80 Å. In the fifth C site, C(7) is bonded in a distorted water-like geometry to one P(1), one H(6), and one H(7) atom. The C(7)-P(1) bond length is 1.82 Å. The C(7)-H(6) bond length is 1.10 Å. The C(7)-H(7) bond length is 1.10 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(9), and one P(1) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. The C(8)-P(1) bond length is 1.80 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(9)-H(8) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(12) atom. The C(13)-H(12) bond length is 1.09 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(19) and one H(13) atom. The C(14)-C(19) bond length is 1.40 Å. The C(14)-H(13) bond length is 1.09 Å. In the tenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(16) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(16) bond length is 1.09 Å. In the eleventh C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(17) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-H(17) bond length is 1.09 Å. In the twelfth C site, C(19) is bonded in a trigonal planar geometry to one C(14), one C(18), and one P(2) atom. The C(19)-P(2) bond length is 1.80 Å. In the thirteenth C site, C(20) is bonded in a trigonal planar geometry to one C(21), one C(25), and one P(2) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(25) bond length is 1.40 Å. The C(20)-P(2) bond length is 1.80 Å. In the fourteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(18) atom. The C(21)-H(18) bond length is 1.09 Å. In the fifteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(20) and one H(22) atom. The C(25)-H(22) bond length is 1.09 Å. In the sixteenth C site, C(26) is bonded in a distorted tetrahedral geometry to one P(2), one H(23), and one H(24) atom. The C(26)-P(2) bond length is 1.81 Å. The C(26)-H(23) bond length is 1.10 Å. The C(26)-H(24) bond length is 1.10 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one C(6), one C(7), one C(8), and one O(1) atom to form PC3O tetrahedra that share  a cornercorner with one Zn(1)I2O2 tetrahedra. The P(1)-O(1) bond length is 1.52 Å. In the second P site, P(2) is bonded to one C(19), one C(20), one C(26), and one O(2) atom to form PC3O tetrahedra that share  a cornercorner with one Zn(1)I2O2 tetrahedra. The P(2)-O(2) bond length is 1.53 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one C(26) atom. In the fourteenth H site, H(24) is bonded in a single-bond geometry to one C(26) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(2) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 1 [C]/C=C(\C=[CH])[P@@](=O)(CCP(=O)(c1ccccc1)c1ccccc1)c1ccccc1 ,2 O=P(CCP(=O)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1 ,1 O=[P@](CC[P@@](=O)(c1c[c][c]cc1)c1ccccc1)(c1c[c][c]cc1)c1ccccc1 ,1 O=[P@@](CC[P@](=O)(c1c[c][c]cc1)c1ccccc1)(c1c[c][c]cc1)c1ccccc1 ,1 [C]/C=C(\C=[CH])[P@](=O)(CCP(=O)(c1ccccc1)c1ccccc1)c1ccccc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.67 A, density 1.81 g/cm3, surface area 4265.37 m2/g, accessible volume 0.12 cm3/g