Ag2C16H15(NO2)3 crystallizes in the hexagonal P6_122 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal planar geometry to one N(1) and two equivalent O(1) atoms. The Ag(1)-N(1) bond length is 2.24 Å. Both Ag(1)-O(1) bond lengths are 2.45 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one N(2) and two equivalent O(2) atoms. The Ag(2)-N(2) bond length is 2.37 Å. Both Ag(2)-O(2) bond lengths are 2.21 Å. There are nine inequivalent C sites. In the first C site, C(4) is bonded in a trigonal planar geometry to two equivalent C(3) and one N(3) atom. Both C(4)-C(3) bond lengths are 1.39 Å. The C(4)-N(3) bond length is 1.48 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(5)-C(2) bond length is 1.51 Å. The C(5)-O(1) bond length is 1.27 Å. The C(5)-O(2) bond length is 1.28 Å. In the third C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(3), one H(4), and one H(5) atom. The C(6)-C(9) bond length is 1.50 Å. The C(6)-H(3) bond length is 1.10 Å. The C(6)-H(4) bond length is 1.10 Å. The C(6)-H(5) bond length is 1.10 Å. In the fourth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(8), one H(6), one H(7), and one H(8) atom. The C(7)-C(8) bond length is 1.49 Å. The C(7)-H(6) bond length is 1.10 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.10 Å. In the fifth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(1) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-N(1) bond length is 1.35 Å. In the sixth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(2) atom. The C(9)-N(2) bond length is 1.35 Å. In the seventh C site, C(1) is bonded in a distorted single-bond geometry to two equivalent C(2) and one H(1) atom. Both C(1)-C(2) bond lengths are 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the eighth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(5) atom. The C(2)-C(3) bond length is 1.40 Å. In the ninth C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1) and two equivalent C(8) atoms. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(2) and two equivalent C(9) atoms. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(4) and two equivalent O(3) atoms. Both N(3)-O(3) bond lengths are 1.24 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one C(5) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one C(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(3) atom. Linkers: 6 Cc1nc(C)c(C)nc1C ,6 [O]C(=O)c1cc(C([O])=O)cc([N+](=O)[O-])c1. Metal clusters: 12 [Ag]. The MOF has largest included sphere 5.01 A, density 1.92 g/cm3, surface area 3327.83 m2/g, accessible volume 0.17 cm3/g