NdC6H4SO7CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a NdC6H4SO7 framework. In the NdC6H4SO7 framework, Nd(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), one O(5), one O(7), two equivalent O(2), and two equivalent O(4) atoms. The Nd(1)-O(1) bond length is 2.41 Å. The Nd(1)-O(3) bond length is 2.61 Å. The Nd(1)-O(5) bond length is 2.48 Å. The Nd(1)-O(7) bond length is 2.48 Å. There is one shorter (2.40 Å) and one longer (2.48 Å) Nd(1)-O(2) bond length. There is one shorter (2.41 Å) and one longer (2.46 Å) Nd(1)-O(4) bond length. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-C(7) bond length is 1.48 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one O(4) atom. The C(2)-O(4) bond length is 1.35 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one S(1) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-S(1) bond length is 1.76 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a bent 120 degrees geometry to one C(1), one O(2), and one O(3) atom. The C(7)-O(2) bond length is 1.30 Å. The C(7)-O(3) bond length is 1.26 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) and one O(7) atom. The H(1)-O(1) bond length is 0.99 Å. The H(1)-O(7) bond length is 1.76 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) and one O(6) atom. The H(2)-O(1) bond length is 0.99 Å. The H(2)-O(6) bond length is 1.71 Å. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one O(5), one O(6), and one O(7) atom. The S(1)-O(5) bond length is 1.47 Å. The S(1)-O(6) bond length is 1.46 Å. The S(1)-O(7) bond length is 1.50 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Nd(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Nd(1) and one C(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Nd(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Nd(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one H(2) and one S(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Nd(1), one H(1), and one S(1) atom. Linkers: 2 [O]C(=O)c1cc(S([O])([O])[O])ccc1[O]. Metal clusters: 2 [Nd]. The MOF has largest included sphere 1.53 A, density 2.76 g/cm3, surface area 2366.50 m2/g, accessible volume 0.03 cm3/g