CoC4H4(NCl)2(C5H5NO)2 is Indium-derived structured and crystallizes in the orthorhombic Pnna space group. The structure is zero-dimensional and consists of four dichlorocobalt;dimethylazanide molecules and eight n-(2-methyl-2-propenyl)formamide molecules. Linkers: 4 O=C(NCc1ccncc1)C(=O)NCc1ccncc1. Metal clusters: 4 Cl[Co]Cl. The MOF has largest included sphere 5.32 A, density 1.35 g/cm3, surface area 4391.04 m2/g, accessible volume 0.18 cm3/g