CdC10H8(N5S2)2 crystallizes in the trigonal P3_121 space group. Cd(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent S(2) atoms. Both Cd(1)-N(1) bond lengths are 2.32 Å. Both Cd(1)-S(2) bond lengths are 2.55 Å. There are five inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(3) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one N(3), one H(3), and one H(4) atom. The C(3)-C(4) bond length is 1.50 Å. The C(3)-N(3) bond length is 1.46 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(4) bond length is 1.10 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one N(4), and one S(1) atom. The C(4)-N(4) bond length is 1.31 Å. The C(4)-S(1) bond length is 1.74 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(5), one S(1), and one S(2) atom. The C(5)-N(5) bond length is 1.33 Å. The C(5)-S(1) bond length is 1.75 Å. The C(5)-S(2) bond length is 1.72 Å. In the fifth C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(1) and one N(3) atom. The N(2)-N(3) bond length is 1.36 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one C(4) and one N(5) atom. The N(4)-N(5) bond length is 1.36 Å. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one C(5) and one N(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(4) and one C(5) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Cd(1) and one C(5) atom. Linkers: 6 S=C1[N]N=C(CN2[CH]N=C[N]2)S1. Metal clusters: 3 [S][Cd][S]. The MOF has largest included sphere 2.07 A, density 2.03 g/cm3, surface area 3659.09 m2/g, accessible volume 0.10 cm3/g