(CH2)2CdC14H12Br2(NO2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CdC14H12Br2(NO2)2 clusters. In each CdC14H12Br2(NO2)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one Br(1), and one Br(2) atom. The Cd(1)-O(1) bond length is 2.58 Å. The Cd(1)-O(2) bond length is 2.38 Å. The Cd(1)-O(3) bond length is 2.50 Å. The Cd(1)-O(4) bond length is 2.52 Å. The Cd(1)-Br(1) bond length is 2.64 Å. The Cd(1)-Br(2) bond length is 2.64 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(1)-C(4) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(1) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-N(1) bond length is 1.36 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(5) atom. The C(4)-C(5) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(6)-N(1) bond length is 1.35 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a 3-coordinate geometry to one N(1), one H(5), and one H(6) atom. The C(7)-N(1) bond length is 1.48 Å. The C(7)-H(5) bond length is 1.09 Å. The C(7)-H(6) bond length is 1.10 Å. In the eighth C site, C(10) is bonded in a 3-coordinate geometry to one N(2), one H(11), and one H(12) atom. The C(10)-N(2) bond length is 1.49 Å. The C(10)-H(11) bond length is 1.09 Å. The C(10)-H(12) bond length is 1.10 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(13) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-N(2) bond length is 1.35 Å. The C(11)-H(13) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(14) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(14) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(16) bond length is 1.51 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(15) atom. The C(14)-H(15) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(16) atom. The C(15)-N(2) bond length is 1.35 Å. The C(15)-H(16) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(3), and one O(4) atom. The C(16)-O(3) bond length is 1.28 Å. The C(16)-O(4) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(15) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(15) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(16) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(16) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Cd(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Cd(1) atom. Linkers: 2 [O]C(=O)C1=C[CH]N(CCCCN2[CH]C=C(C([O])=O)C=C2)C=C1. Metal clusters: 2 O=[C]O[Cd]1(Br)(Br)O[C]O1. The MOF has largest included sphere 2.78 A, density 2.08 g/cm3, surface area 3590.05 m2/g, accessible volume 0.09 cm3/g