AgC7NH6O2 crystallizes in the orthorhombic P2_12_12_1 space group. Ag(1) is bonded in a 7-coordinate geometry to one C(2), one C(3), one N(1), one H(1), one O(2), and two equivalent O(1) atoms. The Ag(1)-C(2) bond length is 2.77 Å. The Ag(1)-C(3) bond length is 2.52 Å. The Ag(1)-N(1) bond length is 2.38 Å. The Ag(1)-H(1) bond length is 2.51 Å. The Ag(1)-O(2) bond length is 2.57 Å. There is one shorter (2.36 Å) and one longer (2.52 Å) Ag(1)-O(1) bond length. There are seven inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one Ag(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one Ag(1), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(1) bond length is 1.40 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(1) bond length is 1.40 Å. The C(6)-C(7) bond length is 1.50 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.28 Å. The C(7)-O(2) bond length is 1.28 Å. In the seventh C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one H(1) atom. The C(1)-H(1) bond length is 1.09 Å. N(1) is bonded in a 4-coordinate geometry to one Ag(1), one C(4), one H(5), and one H(6) atom. The N(1)-H(5) bond length is 1.04 Å. The N(1)-H(6) bond length is 1.02 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Ag(1) and one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Ag(1) and one C(7) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one C(7) atom. Linkers: 4 Nc1cccc(C([O])=O)c1. Metal clusters: 4 [Ag]. RCSR code: srs. The MOF has largest included sphere 2.06 A, density 2.41 g/cm3, surface area 2930.63 m2/g, accessible volume 0.08 cm3/g