Ag2C12N5H13O4 is beta Polonium structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Ag2C12N5H13O4 clusters. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one N(2), one N(5), and two equivalent N(1) atoms. The Ag(1)-N(2) bond length is 2.20 Å. The Ag(1)-N(5) bond length is 2.20 Å. There is one shorter (2.53 Å) and one longer (2.71 Å) Ag(1)-N(1) bond length. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one N(3) and one N(4) atom. The Ag(2)-N(3) bond length is 2.17 Å. The Ag(2)-N(4) bond length is 2.17 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1) and one H(6) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(6) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(7) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(8) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(8) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(9) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(9) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.47 Å. The C(5)-N(1) bond length is 1.36 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(2), and one N(3) atom. The C(6)-N(2) bond length is 1.36 Å. The C(6)-N(3) bond length is 1.36 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(8), one C(9), and one N(3) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-C(9) bond length is 1.47 Å. The C(7)-N(3) bond length is 1.37 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(10), one C(7), and one N(2) atom. The C(8)-C(10) bond length is 1.50 Å. The C(8)-N(2) bond length is 1.37 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(4) atom. The C(9)-O(3) bond length is 1.25 Å. The C(9)-O(4) bond length is 1.31 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(1), and one O(2) atom. The C(10)-O(1) bond length is 1.30 Å. The C(10)-O(2) bond length is 1.25 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(10), and one H(11) atom. The C(11)-N(4) bond length is 1.48 Å. The C(11)-H(10) bond length is 1.11 Å. The C(11)-H(11) bond length is 1.10 Å. In the twelfth C site, C(12) is bonded in a 3-coordinate geometry to one N(5), one H(12), and one H(13) atom. The C(12)-N(5) bond length is 1.48 Å. The C(12)-H(12) bond length is 1.10 Å. The C(12)-H(13) bond length is 1.10 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(6), and one C(8) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(6), and one C(7) atom. In the fourth N site, N(4) is bonded in a 4-coordinate geometry to one Ag(2), one C(11), one H(2), and one H(3) atom. The N(4)-H(2) bond length is 1.03 Å. The N(4)-H(3) bond length is 1.03 Å. In the fifth N site, N(5) is bonded in a 4-coordinate geometry to one Ag(1), one C(12), one H(4), and one H(5) atom. The N(5)-H(4) bond length is 1.03 Å. The N(5)-H(5) bond length is 1.02 Å. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(4) atom. The H(1)-O(1) bond length is 1.33 Å. The H(1)-O(4) bond length is 1.11 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(10) and one H(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(10) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(9) and one H(1) atom. Linkers: 3 [O]C(=O)C1=C(C(=O)O)[N]C(c2ccccn2)=N1 ,4 NCCN. Metal clusters: 8 [Ag]. The MOF has largest included sphere 1.89 A, density 2.44 g/cm3, surface area 2951.87 m2/g, accessible volume 0.09 cm3/g