CdC26H22(N2O3)2(CH)4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four CdC26H22(N2O3)2 clusters. In each CdC26H22(N2O3)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to two equivalent N(1), two equivalent O(2), and two equivalent O(3) atoms. Both Cd(1)-N(1) bond lengths are 2.29 Å. Both Cd(1)-O(2) bond lengths are 2.28 Å. Both Cd(1)-O(3) bond lengths are 2.54 Å. There are thirteen inequivalent C sites. In the first C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one O(1) atom. The C(6)-C(5) bond length is 1.41 Å. The C(6)-O(1) bond length is 1.36 Å. In the second C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(8) bond length is 1.09 Å. In the third C site, C(10) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one H(9) atom. The C(10)-C(5) bond length is 1.39 Å. The C(10)-H(9) bond length is 1.09 Å. In the fourth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one H(10), one H(11), and one O(1) atom. The C(11)-H(10) bond length is 1.10 Å. The C(11)-H(11) bond length is 1.10 Å. The C(11)-O(1) bond length is 1.43 Å. In the fifth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(2), and one O(3) atom. The C(12)-C(13) bond length is 1.50 Å. The C(12)-O(2) bond length is 1.29 Å. The C(12)-O(3) bond length is 1.27 Å. In the sixth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(15) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(15) bond length is 1.40 Å. In the seventh C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(12,13) atom. The C(14)-H(12,13) bond length is 1.09 Å. In the eighth C site, C(15) is bonded in a distorted single-bond geometry to one C(13) and one H(12,13) atom. The C(15)-H(12,13) bond length is 1.09 Å. In the ninth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one N(2), one H(4), and one H(5) atom. The C(4)-C(5) bond length is 1.51 Å. The C(4)-N(2) bond length is 1.45 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. In the tenth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-N(1) bond length is 1.38 Å. The C(1)-H(1) bond length is 1.08 Å. In the eleventh C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(2), and one H(2) atom. The C(2)-N(2) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the twelfth C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(6) atom. In the thirteenth C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. The C(3)-N(1) bond length is 1.33 Å. The C(3)-N(2) bond length is 1.36 Å. The C(3)-H(3) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(12,13) is bonded in a single-bond geometry to one C(14) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(11) and one C(6) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(12) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(12) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 3.07 A, density 1.44 g/cm3, surface area 4872.32 m2/g, accessible volume 0.19 cm3/g