CoC8PN2H8O3CH crystallizes in the triclinic P1 space group. The structure consists of four 02329_fluka molecules inside a CoC8PN2H8O3 framework. In the CoC8PN2H8O3 framework, there are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(1), one O(1), one O(12), and one O(6) atom to form CoNO3 tetrahedra that share  a cornercorner with one P(1)HO3 tetrahedra,  a cornercorner with one P(2)HO3 tetrahedra, and  a cornercorner with one P(4)HO3 tetrahedra. The Co(1)-N(1) bond length is 1.98 Å. The Co(1)-O(1) bond length is 1.94 Å. The Co(1)-O(12) bond length is 1.94 Å. The Co(1)-O(6) bond length is 1.95 Å. In the second Co site, Co(2) is bonded to one N(2), one O(11), one O(2), and one O(5) atom to form CoNO3 tetrahedra that share  a cornercorner with one P(1)HO3 tetrahedra,  a cornercorner with one P(2)HO3 tetrahedra, and  a cornercorner with one P(3)HO3 tetrahedra. The Co(2)-N(2) bond length is 1.98 Å. The Co(2)-O(11) bond length is 1.94 Å. The Co(2)-O(2) bond length is 1.94 Å. The Co(2)-O(5) bond length is 1.95 Å. In the third Co site, Co(3) is bonded to one N(3), one O(10), one O(3), and one O(8) atom to form CoNO3 tetrahedra that share  a cornercorner with one P(2)HO3 tetrahedra,  a cornercorner with one P(3)HO3 tetrahedra, and  a cornercorner with one P(4)HO3 tetrahedra. The Co(3)-N(3) bond length is 1.98 Å. The Co(3)-O(10) bond length is 1.94 Å. The Co(3)-O(3) bond length is 1.94 Å. The Co(3)-O(8) bond length is 1.94 Å. In the fourth Co site, Co(4) is bonded to one N(4), one O(4), one O(7), and one O(9) atom to form CoNO3 tetrahedra that share  a cornercorner with one P(1)HO3 tetrahedra,  a cornercorner with one P(3)HO3 tetrahedra, and  a cornercorner with one P(4)HO3 tetrahedra. The Co(4)-N(4) bond length is 1.94 Å. The Co(4)-O(4) bond length is 1.94 Å. The Co(4)-O(7) bond length is 1.94 Å. The Co(4)-O(9) bond length is 1.93 Å. There are thirty inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(5), and one H(5) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(5) bond length is 1.35 Å. The C(1)-H(5) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2); one N(6); and one H(6,7) atom. The C(2)-N(2) bond length is 1.34 Å. The C(2)-N(6) bond length is 1.35 Å. The C(2)-H(6,7) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(3); one N(7); and one H(6,7) atom. The C(3)-N(3) bond length is 1.34 Å. The C(3)-N(7) bond length is 1.35 Å. The C(3)-H(6,7) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(4), one N(8), and one H(8) atom. The C(4)-N(4) bond length is 1.34 Å. The C(4)-N(8) bond length is 1.36 Å. The C(4)-H(8) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(1), and one H(9) atom. The C(5)-C(9) bond length is 1.37 Å. The C(5)-N(1) bond length is 1.39 Å. The C(5)-H(9) bond length is 1.08 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(10) atom. The C(6)-C(10) bond length is 1.37 Å. The C(6)-N(2) bond length is 1.39 Å. The C(6)-H(10) bond length is 1.08 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(3), and one H(11) atom. The C(7)-C(11) bond length is 1.37 Å. The C(7)-N(3) bond length is 1.39 Å. The C(7)-H(11) bond length is 1.08 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(4), and one H(12) atom. The C(8)-C(12) bond length is 1.37 Å. The C(8)-N(4) bond length is 1.39 Å. The C(8)-H(12) bond length is 1.08 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(5), and one H(13) atom. The C(9)-N(5) bond length is 1.38 Å. The C(9)-H(13) bond length is 1.08 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(6); one N(6); and one H(14,15) atom. The C(10)-N(6) bond length is 1.38 Å. The C(10)-H(14,15) bond length is 1.08 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(7); one N(7); and one H(14,15) atom. The C(11)-N(7) bond length is 1.38 Å. The C(11)-H(14,15) bond length is 1.08 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(8), and one H(16) atom. The C(12)-N(8) bond length is 1.38 Å. The C(12)-H(16) bond length is 1.08 Å. In the thirteenth C site, C(13,15) is bonded in a distorted trigonal non-coplanar geometry to one C(17); one N(5); one H(17,19); and one H(21,23) atom. The C(13,15)-C(17) bond length is 1.51 Å. The C(13,15)-N(5) bond length is 1.47 Å. The C(13,15)-H(17,19) bond length is 1.10 Å. The C(13,15)-H(21,23) bond length is 1.10 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one C(18), one N(6), one H(18), and one H(22) atom. The C(14)-C(18) bond length is 1.51 Å. The C(14)-N(6) bond length is 1.47 Å. The C(14)-H(18) bond length is 1.10 Å. The C(14)-H(22) bond length is 1.10 Å. In the fifteenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one C(20), one N(8), one H(20), and one H(24) atom. The C(16)-C(20) bond length is 1.51 Å. The C(16)-N(8) bond length is 1.47 Å. The C(16)-H(20) bond length is 1.10 Å. The C(16)-H(24) bond length is 1.10 Å. In the sixteenth C site, C(17) is bonded in a trigonal planar geometry to one C(13,15); one C(21,23); and one C(25) atom. The C(17)-C(21,23) bond length is 1.38 Å. The C(17)-C(25) bond length is 1.43 Å. In the seventeenth C site, C(18) is bonded in a trigonal planar geometry to one C(14), one C(22), and one C(26) atom. The C(18)-C(22) bond length is 1.38 Å. The C(18)-C(26) bond length is 1.43 Å. In the eighteenth C site, C(19) is bonded in a trigonal planar geometry to one C(13,15); one C(21,23); and one C(27) atom. The C(19)-C(13,15) bond length is 1.51 Å. The C(19)-C(21,23) bond length is 1.38 Å. The C(19)-C(27) bond length is 1.43 Å. In the nineteenth C site, C(20) is bonded in a trigonal planar geometry to one C(16), one C(24), and one C(28) atom. The C(20)-C(24) bond length is 1.38 Å. The C(20)-C(28) bond length is 1.43 Å. In the twentieth C site, C(21,23) is bonded in a distorted single-bond geometry to one C(17) and one H(25,27) atom. The C(21,23)-H(25,27) bond length is 1.09 Å. In the twenty-first C site, C(22) is bonded in a distorted single-bond geometry to one C(18) and one H(26,28) atom. The C(22)-H(26,28) bond length is 1.09 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(20) and one H(26,28) atom. The C(24)-H(26,28) bond length is 1.09 Å. In the twenty-third C site, C(25) is bonded in a trigonal planar geometry to one C(17), one C(26), and one C(29) atom. The C(25)-C(26) bond length is 1.44 Å. The C(25)-C(29) bond length is 1.42 Å. In the twenty-fourth C site, C(26) is bonded in a trigonal planar geometry to one C(18), one C(25), and one C(30) atom. The C(26)-C(30) bond length is 1.42 Å. In the twenty-fifth C site, C(27) is bonded in a trigonal planar geometry to one C(19), one C(28), and one C(31) atom. The C(27)-C(28) bond length is 1.44 Å. The C(27)-C(31) bond length is 1.42 Å. In the twenty-sixth C site, C(28) is bonded in a trigonal planar geometry to one C(20), one C(27), and one C(32) atom. The C(28)-C(32) bond length is 1.42 Å. In the twenty-seventh C site, C(29) is bonded in a distorted single-bond geometry to one C(25) and one H(29,31) atom. The C(29)-H(29,31) bond length is 1.09 Å. In the twenty-eighth C site, C(30) is bonded in a distorted single-bond geometry to one C(26) and one H(30,32) atom. The C(30)-H(30,32) bond length is 1.09 Å. In the twenty-ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(27) and one H(29,31) atom. The C(31)-H(29,31) bond length is 1.09 Å. In the thirtieth C site, C(32) is bonded in a distorted single-bond geometry to one C(28) and one H(30,32) atom. The C(32)-H(30,32) bond length is 1.09 Å. There are four inequivalent P sites. In the first P site, P(1) is bonded to one H(1), one O(1), one O(5), and one O(9) atom to form distorted PHO3 tetrahedra that share  a cornercorner with one Co(1)NO3 tetrahedra,  a cornercorner with one Co(2)NO3 tetrahedra, and  a cornercorner with one Co(4)NO3 tetrahedra. The P(1)-H(1) bond length is 1.41 Å. The P(1)-O(1) bond length is 1.53 Å. The P(1)-O(5) bond length is 1.54 Å. The P(1)-O(9) bond length is 1.54 Å. In the second P site, P(2) is bonded to one H(2), one O(10), one O(2), and one O(6) atom to form distorted PHO3 tetrahedra that share  a cornercorner with one Co(1)NO3 tetrahedra,  a cornercorner with one Co(2)NO3 tetrahedra, and  a cornercorner with one Co(3)NO3 tetrahedra. The P(2)-H(2) bond length is 1.41 Å. The P(2)-O(10) bond length is 1.54 Å. The P(2)-O(2) bond length is 1.53 Å. The P(2)-O(6) bond length is 1.54 Å. In the third P site, P(3) is bonded to one H(3), one O(11), one O(3), and one O(7) atom to form distorted PHO3 tetrahedra that share  a cornercorner with one Co(2)NO3 tetrahedra,  a cornercorner with one Co(3)NO3 tetrahedra, and  a cornercorner with one Co(4)NO3 tetrahedra. The P(3)-H(3) bond length is 1.41 Å. The P(3)-O(11) bond length is 1.54 Å. The P(3)-O(3) bond length is 1.53 Å. The P(3)-O(7) bond length is 1.54 Å. In the fourth P site, P(4) is bonded to one H(4), one O(12), one O(4), and one O(8) atom to form distorted PHO3 tetrahedra that share  a cornercorner with one Co(1)NO3 tetrahedra,  a cornercorner with one Co(3)NO3 tetrahedra, and  a cornercorner with one Co(4)NO3 tetrahedra. The P(4)-H(4) bond length is 1.41 Å. The P(4)-O(12) bond length is 1.54 Å. The P(4)-O(4) bond length is 1.53 Å. The P(4)-O(8) bond length is 1.54 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(2), one C(2), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(3), one C(3), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(4), one C(4), and one C(8) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(1); one C(13,15); and one C(9) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(2) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(11); one C(13,15); and one C(3) atom. The N(7)-C(13,15) bond length is 1.47 Å. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(4) atom. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one P(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one P(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one P(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6,7) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(8) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the thirteenth H site, H(14,15) is bonded in a single-bond geometry to one C(10) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the fifteenth H site, H(17,19) is bonded in a single-bond geometry to one C(13,15) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(14) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(16) atom. In the eighteenth H site, H(21,23) is bonded in a single-bond geometry to one C(13,15) atom. In the nineteenth H site, H(22) is bonded in a single-bond geometry to one C(14) atom. In the twentieth H site, H(24) is bonded in a single-bond geometry to one C(16) atom. In the twenty-first H site, H(25,27) is bonded in a single-bond geometry to one C(21,23) atom. In the twenty-second H site, H(26,28) is bonded in a single-bond geometry to one C(22) atom. In the twenty-third H site, H(29,31) is bonded in a single-bond geometry to one C(29) atom. In the twenty-fourth H site, H(30,32) is bonded in a single-bond geometry to one C(30) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Co(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one P(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Co(3) and one P(3) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Co(4) and one P(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Co(2) and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Co(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Co(4) and one P(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Co(3) and one P(4) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Co(4) and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Co(3) and one P(2) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one P(3) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one P(4) atom. Linkers: 2 c1cc(Cn2ccnc2)c2cccc(Cn3ccnc3)c2c1. Metal clusters: 4 [Co]. The MOF has largest included sphere 3.29 A, density 1.69 g/cm3, surface area 4086.78 m2/g, accessible volume 0.13 cm3/g