(CH)2PbC10H6(N2S)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and four PbC10H6(N2S)2 clusters. In each PbC10H6(N2S)2 cluster, Pb(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Pb(1)-N(1) bond lengths are 2.54 Å. Both Pb(1)-N(2) bond lengths are 2.63 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(5), and one N(1) atom. The C(5)-C(5) bond length is 1.48 Å. The C(5)-N(1) bond length is 1.35 Å. In the fifth C site, C(6) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. The C(6)-N(2) bond length is 1.19 Å. The C(6)-S(1) bond length is 1.63 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a distorted single-bond geometry to one Pb(1) and one C(6) atom. In the second N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Pb(1), one C(1), and one C(5) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. S(1) is bonded in a single-bond geometry to one C(6) atom. Linkers: 2 N#C[S]. Metal clusters: 2 [Pb]. The MOF has largest included sphere 2.07 A, density 2.38 g/cm3, surface area 2834.89 m2/g, accessible volume 0.07 cm3/g