ZnH6(CN)6(CH3)2 crystallizes in the tetragonal P4_32_12 space group. The structure consists of eight 02329_fluka molecules inside a ZnH6(CN)6 framework. In the ZnH6(CN)6 framework, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(3) atoms. Both Zn(1)-N(1) bond lengths are 2.00 Å. Both Zn(1)-N(3) bond lengths are 1.99 Å. There are three inequivalent C sites. In the first C site, C(3) is bonded in a distorted water-like geometry to one C(1), one H(2), and one H(3) atom. The C(3)-C(1) bond length is 1.49 Å. The C(3)-H(2) bond length is 1.10 Å. The C(3)-H(3) bond length is 1.10 Å. In the second C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one N(3) atom. The C(1)-N(2) bond length is 1.33 Å. The C(1)-N(3) bond length is 1.37 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(2)-N(1) bond length is 1.33 Å. The C(2)-N(3) bond length is 1.35 Å. The C(2)-H(1) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(1) and one N(1) atom. The N(2)-N(1) bond length is 1.38 Å. In the third N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(2), and one N(2) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. Linkers: 1 CCC1=NC=N[N]1 ,6 CCC1=N[N]C=N1 ,1 CCC1=[N]=CN=N1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 2.31 A, density 1.48 g/cm3, surface area 5064.49 m2/g, accessible volume 0.21 cm3/g