ZnC6H10(N2S)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC6H10(N2S)2 clusters. Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Zn(1)-N(1) bond length is 1.94 Å. The Zn(1)-N(2) bond length is 1.94 Å. The Zn(1)-N(3) bond length is 2.05 Å. The Zn(1)-N(4) bond length is 2.06 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.19 Å. The C(1)-S(1) bond length is 1.61 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(2) atom. The C(2)-N(2) bond length is 1.19 Å. The C(2)-S(2) bond length is 1.61 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(1), and one H(3) atom. The C(3)-N(3) bond length is 1.49 Å. The C(3)-H(1) bond length is 1.10 Å. The C(3)-H(3) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(5), and one H(7) atom. The C(4)-N(3) bond length is 1.49 Å. The C(4)-H(5) bond length is 1.10 Å. The C(4)-H(7) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(10), and one H(9) atom. The C(5)-N(4) bond length is 1.49 Å. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(4), and one H(8) atom. The C(6)-N(4) bond length is 1.49 Å. The C(6)-H(4) bond length is 1.10 Å. The C(6)-H(8) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(2) atom. In the third N site, N(3) is bonded to one Zn(1), one C(3), one C(4), and one H(2) atom to form distorted corner-sharing NZnHC2 tetrahedra. The N(3)-H(2) bond length is 1.04 Å. In the fourth N site, N(4) is bonded to one Zn(1), one C(5), one C(6), and one H(6) atom to form distorted corner-sharing NZnHC2 tetrahedra. The N(4)-H(6) bond length is 1.04 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one C(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(2) atom. Linkers: 1 C1CNCCN1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.94 A, density 1.72 g/cm3, surface area 4904.07 m2/g, accessible volume 0.18 cm3/g