CdC14H10(NO2)2(CH)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CdC14H10(NO2)2 clusters. In each CdC14H10(NO2)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(2), one N(4), one O(1), one O(3), one O(5), and one O(7) atom. The Cd(1)-N(2) bond length is 2.32 Å. The Cd(1)-N(4) bond length is 2.28 Å. The Cd(1)-O(1) bond length is 2.40 Å. The Cd(1)-O(3) bond length is 2.41 Å. The Cd(1)-O(5) bond length is 2.30 Å. The Cd(1)-O(7) bond length is 2.52 Å. There are fourteen inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1,2)-O(1) bond length is 1.28 Å. The C(1,2)-O(3) bond length is 1.28 Å. In the second C site, C(3,4) is bonded in a distorted single-bond geometry to one C(9,10) and one H(1,2) atom. The C(3,4)-C(9,10) bond length is 1.46 Å. The C(3,4)-H(1,2) bond length is 1.09 Å. In the third C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5,6) atom. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(5,6) bond length is 1.09 Å. In the fourth C site, C(9,10) is bonded in a trigonal planar geometry to one C(13,14); one C(15,16); and one C(3,4) atom. The C(9,10)-C(13,14) bond length is 1.40 Å. The C(9,10)-C(15,16) bond length is 1.41 Å. In the fifth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13,14); one N(2); and one H(7,8) atom. The C(12)-C(13,14) bond length is 1.39 Å. The C(12)-N(2) bond length is 1.34 Å. The C(12)-H(7,8) bond length is 1.09 Å. In the sixth C site, C(13,14) is bonded in a distorted single-bond geometry to one C(11); one C(9,10); and one H(9,10) atom. The C(13,14)-C(11) bond length is 1.39 Å. The C(13,14)-H(9,10) bond length is 1.09 Å. In the seventh C site, C(15,16) is bonded in a distorted single-bond geometry to one C(9,10) and one H(11,12) atom. The C(15,16)-H(11,12) bond length is 1.09 Å. In the eighth C site, C(17,18) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(7) atom. The C(17,18)-O(5) bond length is 1.29 Å. The C(17,18)-O(7) bond length is 1.27 Å. In the ninth C site, C(21,22) is bonded in a distorted trigonal planar geometry to one C(23,24); one N(3); and one H(15,16) atom. The C(21,22)-C(23,24) bond length is 1.39 Å. The C(21,22)-N(3) bond length is 1.35 Å. The C(21,22)-H(15,16) bond length is 1.09 Å. In the tenth C site, C(23,24) is bonded in a distorted single-bond geometry to one C(21,22); one C(25,26); and one H(17,18) atom. The C(23,24)-C(25,26) bond length is 1.40 Å. The C(23,24)-H(17,18) bond length is 1.09 Å. In the eleventh C site, C(25,26) is bonded in a trigonal planar geometry to one C(23,24); one C(27,28); and one C(31,32) atom. The C(25,26)-C(27,28) bond length is 1.41 Å. The C(25,26)-C(31,32) bond length is 1.46 Å. In the twelfth C site, C(27,28) is bonded in a distorted single-bond geometry to one C(25,26) and one H(19,20) atom. The C(27,28)-H(19,20) bond length is 1.09 Å. In the thirteenth C site, C(29,30) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(21,22) atom. The C(29,30)-N(3) bond length is 1.35 Å. The C(29,30)-H(21,22) bond length is 1.09 Å. In the fourteenth C site, C(31,32) is bonded in a distorted single-bond geometry to one C(25,26) and one H(23,24) atom. The C(31,32)-H(23,24) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(12), and one C(8) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cd(1); one C(21,22); and one C(29,30) atom. The N(4)-C(21,22) bond length is 1.35 Å. The N(4)-C(29,30) bond length is 1.35 Å. There are ten inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(3,4) atom. In the second H site, H(5,6) is bonded in a single-bond geometry to one C(7) atom. The H(5,6)-C(7) bond length is 1.09 Å. In the third H site, H(7,8) is bonded in a single-bond geometry to one C(11) atom. The H(7,8)-C(11) bond length is 1.09 Å. In the fourth H site, H(9,10) is bonded in a single-bond geometry to one C(13,14) atom. In the fifth H site, H(11,12) is bonded in a single-bond geometry to one C(15,16) atom. In the sixth H site, H(15,16) is bonded in a single-bond geometry to one C(21,22) atom. In the seventh H site, H(17,18) is bonded in a single-bond geometry to one C(23,24) atom. In the eighth H site, H(19,20) is bonded in a single-bond geometry to one C(27,28) atom. In the ninth H site, H(21,22) is bonded in a single-bond geometry to one C(29,30) atom. In the tenth H site, H(23,24) is bonded in a single-bond geometry to one C(31,32) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1,2) atom. In the second O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1,2) atom. In the third O site, O(5) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(17,18) atom. In the fourth O site, O(7) is bonded in a distorted single-bond geometry to one Cd(1) and one C(17,18) atom. Linkers: 4 [O]C(=O)/C=C/c1ccncc1. Metal clusters: 2 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 3.03 A, density 1.55 g/cm3, surface area 4325.13 m2/g, accessible volume 0.21 cm3/g