CdC8H8(NO)6(H4(C3F)3)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CdC8H8(NO)6 clusters and four H4(C3F)3 clusters. In each CdC8H8(NO)6 cluster, Cd(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent O(1) atoms. Both Cd(1)-N(1) bond lengths are 2.38 Å. Both Cd(1)-N(2) bond lengths are 2.35 Å. Both Cd(1)-O(1) bond lengths are 2.41 Å. There are four inequivalent C sites. In the first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(11) atom. The C(21)-N(2) bond length is 1.35 Å. The C(21)-H(11) bond length is 1.09 Å. In the second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(22)-N(2) bond length is 1.35 Å. The C(22)-H(12) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the fourth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(21), and one C(22) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(3)-O(1) bond length is 1.31 Å. The N(3)-O(2) bond length is 1.26 Å. The N(3)-O(3) bond length is 1.25 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(21) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(22) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cd(1) and one N(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(3) atom. In each H4(C3F)3 cluster, there are eighteen inequivalent C sites. In the first C site, C(3) is bonded in a single-bond geometry to one C(5) and one H(3) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.51 Å. In the fourth C site, C(6) is bonded in a distorted water-like geometry to one C(5), one C(7), one H(5), and one H(6) atom. The C(6)-C(7) bond length is 1.51 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-C(9) bond length is 1.38 Å. In the sixth C site, C(8) is bonded in a single-bond geometry to one C(7) and one F(1) atom. The C(8)-F(1) bond length is 1.36 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(11), one C(7), and one F(2) atom. The C(9)-C(11) bond length is 1.42 Å. The C(9)-F(2) bond length is 1.35 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(12) and one F(3) atom. The C(10)-C(12) bond length is 1.41 Å. The C(10)-F(3) bond length is 1.35 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(9) atom. The C(11)-C(12) bond length is 1.44 Å. The C(11)-C(13) bond length is 1.42 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(14) atom. The C(12)-C(14) bond length is 1.42 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(11), one C(16), and one F(4) atom. The C(13)-C(16) bond length is 1.38 Å. The C(13)-F(4) bond length is 1.36 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one F(5) atom. The C(14)-F(5) bond length is 1.35 Å. In the thirteenth C site, C(15) is bonded in a single-bond geometry to one C(16) and one F(6) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-F(6) bond length is 1.36 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(16)-C(17) bond length is 1.51 Å. In the fifteenth C site, C(17) is bonded in a distorted water-like geometry to one C(16), one C(18), one H(7), and one H(8) atom. The C(17)-C(18) bond length is 1.51 Å. The C(17)-H(7) bond length is 1.10 Å. The C(17)-H(8) bond length is 1.10 Å. In the sixteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(20) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(20) bond length is 1.40 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(9) atom. The C(19)-H(9) bond length is 1.09 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(18) and one H(10) atom. The C(20)-H(10) bond length is 1.09 Å. There are eight inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(20) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(8) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(9) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(10) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(13) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(14) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one C(15) atom. Linkers: 4 Fc1c(Cc2ccncc2)c(F)c2c(F)c(Cc3ccncc3)c(F)c(F)c2c1F. Metal clusters: 2 [Cd]. The MOF has largest included sphere 4.39 A, density 1.33 g/cm3, surface area 4306.84 m2/g, accessible volume 0.28 cm3/g