AgC9H9(SO)3(CH)5(CH2)2CF3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules, four 02329_fluka molecules, two trifluoromethane molecules, and one AgC9H9(SO)3 cluster. In the AgC9H9(SO)3 cluster, Ag(1) is bonded in a distorted trigonal pyramidal geometry to one S(1), one S(2), one O(1), and one O(3) atom. The Ag(1)-S(1) bond length is 2.46 Å. The Ag(1)-S(2) bond length is 2.47 Å. The Ag(1)-O(1) bond length is 2.38 Å. The Ag(1)-O(3) bond length is 2.72 Å. There are nine inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one C(3), one C(7), and one S(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. The C(2)-S(1) bond length is 1.78 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(1) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(4)-H(2) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the fifth C site, C(8) is bonded in a distorted water-like geometry to one H(6), one H(7), and one S(1) atom. The C(8)-H(6) bond length is 1.10 Å. The C(8)-H(7) bond length is 1.10 Å. The C(8)-S(1) bond length is 1.82 Å. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one S(2) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.40 Å. The C(10)-S(2) bond length is 1.79 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(10,14) atom. The C(11)-H(10,14) bond length is 1.09 Å. In the eighth C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one H(10,14) atom. The C(15)-H(10,14) bond length is 1.09 Å. In the ninth C site, C(16) is bonded in a distorted water-like geometry to one H(15), one H(16), and one S(2) atom. The C(16)-H(15) bond length is 1.10 Å. The C(16)-H(16) bond length is 1.10 Å. The C(16)-S(2) bond length is 1.83 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(10,14) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(2), and one C(8) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one C(10), and one C(16) atom. In the third S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. The S(3)-O(1) bond length is 1.47 Å. The S(3)-O(2) bond length is 1.46 Å. The S(3)-O(3) bond length is 1.46 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one S(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Ag(1) and one S(3) atom. Linkers: 2 c1ccc(SCCCCSc2ccccc2)cc1 ,2 [c]1cccc(SCCCCSc2ccccc2)c1. Metal clusters: 2 [Ag]. The MOF has largest included sphere 2.05 A, density 1.82 g/cm3, surface area 4341.17 m2/g, accessible volume 0.13 cm3/g