MgAgC12(NO2)3(CH3)6 crystallizes in the monoclinic P2_1/c space group. The structure consists of twenty-four 02329_fluka molecules inside a MgAgC12(NO2)3 framework. In the MgAgC12(NO2)3 framework, Mg(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Mg(1)-O(1) bond length is 2.07 Å. The Mg(1)-O(2) bond length is 2.04 Å. The Mg(1)-O(3) bond length is 2.06 Å. The Mg(1)-O(4) bond length is 2.06 Å. The Mg(1)-O(5) bond length is 2.06 Å. The Mg(1)-O(6) bond length is 2.06 Å. Ag(1) is bonded to one N(2), one N(3), and two equivalent N(1) atoms to form distorted edge-sharing AgN4 tetrahedra. The Ag(1)-N(2) bond length is 2.21 Å. The Ag(1)-N(3) bond length is 2.15 Å. There is one shorter (2.20 Å) and one longer (2.60 Å) Ag(1)-N(1) bond length. There are twelve inequivalent C sites. In the first C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one O(5) atom. The C(14)-C(15) bond length is 1.45 Å. The C(14)-O(5) bond length is 1.26 Å. In the second C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.44 Å. The C(15)-C(18) bond length is 1.40 Å. In the third C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one O(6) atom. The C(16)-O(6) bond length is 1.26 Å. In the fourth C site, C(18) is bonded in a distorted linear geometry to one C(15) and one N(3) atom. The C(18)-N(3) bond length is 1.17 Å. In the fifth C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one O(1) atom. The C(2)-C(3) bond length is 1.44 Å. The C(2)-O(1) bond length is 1.26 Å. In the sixth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.45 Å. The C(3)-C(6) bond length is 1.39 Å. In the seventh C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one O(2) atom. The C(4)-O(2) bond length is 1.26 Å. In the eighth C site, C(6) is bonded in a distorted linear geometry to one C(3) and one N(1) atom. The C(6)-N(1) bond length is 1.18 Å. In the ninth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one O(3) atom. The C(8)-C(9) bond length is 1.44 Å. The C(8)-O(3) bond length is 1.26 Å. In the tenth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(8) atom. The C(9)-C(10) bond length is 1.45 Å. The C(9)-C(12) bond length is 1.40 Å. In the eleventh C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one O(4) atom. The C(10)-O(4) bond length is 1.26 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(9) and one N(2) atom. The C(12)-N(2) bond length is 1.18 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one C(6) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Ag(1) and one C(12) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one Ag(1) and one C(18) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one C(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one C(4) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mg(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mg(1) and one C(10) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one C(14) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one C(16) atom. Linkers: 12 CC(=O)[C](C#N)C(C)=O. Metal clusters: 4 [Mg] ,4 [Ag]. The MOF has largest included sphere 3.66 A, density 1.44 g/cm3, surface area 4629.90 m2/g, accessible volume 0.25 cm3/g