LiC12N3H10SO(CH)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two LiC12N3H10SO clusters. In each LiC12N3H10SO cluster, Li(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(2), one N(3), and one O(1) atom. The Li(1)-N(1) bond length is 2.11 Å. The Li(1)-N(2) bond length is 2.02 Å. The Li(1)-N(3) bond length is 2.00 Å. The Li(1)-O(1) bond length is 2.03 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1); one H(2,3); and one O(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2,3) bond length is 1.10 Å. The C(1)-O(1) bond length is 1.44 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one H(2,3); one H(4); and one O(1) atom. The C(2)-H(2,3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. The C(2)-O(1) bond length is 1.44 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-H(5) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(8) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(8) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(1) atom. The C(7)-C(8) bond length is 1.46 Å. The C(7)-N(1) bond length is 1.36 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one N(2) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-N(2) bond length is 1.36 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(9) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-H(9) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one N(3) atom. The C(10)-C(11) bond length is 1.45 Å. The C(10)-N(3) bond length is 1.37 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one S(1) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-S(1) bond length is 1.74 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(10) atom. The C(12)-H(10) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-H(11) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one H(12), and one S(1) atom. The C(14)-H(12) bond length is 1.09 Å. The C(14)-S(1) bond length is 1.72 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Li(1), one C(3), and one C(7) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Li(1), one C(8), and one N(3) atom. The N(2)-N(3) bond length is 1.35 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Li(1), one C(10), and one N(2) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. S(1) is bonded in an L-shaped geometry to one C(11) and one C(14) atom. O(1) is bonded in a trigonal planar geometry to one Li(1), one C(1), and one C(2) atom. Linkers: 2 C1COCCO1 ,1 C1=C(c2cccs2)[N]N=C1c1ccccn1 ,2 C1=C(c2ccccn2)[N]N=C1c1cccs1 ,1 [CH]1C(c2ccccn2)=NN=C1c1cccs1. Metal clusters: 2 [Li][N][N].[Li][N][N]. The MOF has largest included sphere 4.51 A, density 1.24 g/cm3, surface area 5259.68 m2/g, accessible volume 0.22 cm3/g