CuH14(C5O4)2(CH)2(CF3)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four trifluoromethane molecules, and two CuH14(C5O4)2 clusters. In each CuH14(C5O4)2 cluster, Cu(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted CuO6 octahedra that share corners with two equivalent C(6)H3O tetrahedra. Both Cu(1)-O(1) bond lengths are 1.97 Å. Both Cu(1)-O(2) bond lengths are 1.94 Å. Both Cu(1)-O(3) bond lengths are 2.59 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one O(1) atom. The C(1)-O(1) bond length is 1.27 Å. In the second C site, C(7) is bonded in a tetrahedral geometry to one H(6), one H(7), one H(8), and one O(4) atom. The C(7)-H(6) bond length is 1.10 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.09 Å. The C(7)-O(4) bond length is 1.44 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one O(2) atom. The C(3)-O(2) bond length is 1.27 Å. In the fourth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one H(2), one O(3), and one O(4) atom. The C(5)-H(2) bond length is 1.11 Å. The C(5)-O(3) bond length is 1.42 Å. The C(5)-O(4) bond length is 1.39 Å. In the fifth C site, C(6) is bonded to one H(3), one H(4), one H(5), and one O(3) atom to form CH3O tetrahedra that share  a cornercorner with one Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles are 68°. The C(6)-H(3) bond length is 1.09 Å. The C(6)-H(4) bond length is 1.10 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-O(3) bond length is 1.44 Å. There are seven inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(7) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. In the second O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1), one C(5), and one C(6) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one C(5) and one C(7) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. Linkers: 2 COC(OC)C(=O)[CH]C(=O)C(F)(F)F ,2 COC(OC)C(=O)/C=[C]/[C](F)F ,1 CO[C@H]([O])C(=O)[CH]C(=O)C(F)(F)F ,1 CO[C@@H]([O])C(=O)[CH]C(=O)C(F)(F)F. Metal clusters: 1 [Cu]. The MOF has largest included sphere 2.03 A, density 1.80 g/cm3, surface area 4510.07 m2/g, accessible volume 0.14 cm3/g