CoC15H11(NO2)2(CH)2H4(C3F2)3 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two CoC15H11(NO2)2 clusters, and four H4(C3F2)3 clusters. In each CoC15H11(NO2)2 cluster, Co(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Co(1)-N(1) bond length is 2.28 Å. The Co(1)-O(1) bond length is 2.01 Å. The Co(1)-O(2) bond length is 2.02 Å. The Co(1)-O(3) bond length is 2.01 Å. The Co(1)-O(4) bond length is 2.02 Å. There are fifteen inequivalent C sites. In the first C site, C(15) is bonded in a distorted trigonal planar geometry to one N(1) and one N(2) atom. The C(15)-N(1) bond length is 1.37 Å. The C(15)-N(2) bond length is 1.36 Å. In the second C site, C(16) is bonded in a distorted single-bond geometry to one C(20) and one H(6) atom. The C(16)-C(20) bond length is 1.40 Å. The C(16)-H(6) bond length is 1.09 Å. In the third C site, C(17) is bonded in a distorted single-bond geometry to one C(12) and one H(7) atom. The C(17)-C(12) bond length is 1.40 Å. The C(17)-H(7) bond length is 1.09 Å. In the fourth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one C(13), one N(2), one H(8), and one H(9) atom. The C(18)-C(13) bond length is 1.52 Å. The C(18)-N(2) bond length is 1.45 Å. The C(18)-H(8) bond length is 1.10 Å. The C(18)-H(9) bond length is 1.11 Å. In the fifth C site, C(19) is bonded in a distorted single-bond geometry to one C(20) and one H(10) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(10) bond length is 1.09 Å. In the sixth C site, C(20) is bonded in a trigonal planar geometry to one C(16), one C(19), and one C(9) atom. The C(20)-C(9) bond length is 1.48 Å. In the seventh C site, C(21) is bonded in a distorted single-bond geometry to one C(13) and one H(11,13) atom. The C(21)-C(13) bond length is 1.40 Å. The C(21)-H(11,13) bond length is 1.09 Å. In the eighth C site, C(22) is bonded in a distorted single-bond geometry to one C(12) and one H(12) atom. The C(22)-C(12) bond length is 1.40 Å. The C(22)-H(12) bond length is 1.09 Å. In the ninth C site, C(23) is bonded in a distorted single-bond geometry to one C(13) and one H(11,13) atom. The C(23)-C(13) bond length is 1.40 Å. The C(23)-H(11,13) bond length is 1.09 Å. In the tenth C site, C(24) is bonded in a distorted single-bond geometry to one C(3) and one H(14) atom. The C(24)-C(3) bond length is 1.39 Å. The C(24)-H(14) bond length is 1.09 Å. In the eleventh C site, C(3) is bonded in a distorted trigonal planar geometry to one C(24), one N(1), and one H(1) atom. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(1) bond length is 1.09 Å. In the twelfth C site, C(5) is bonded in a bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(5)-C(12) bond length is 1.49 Å. The C(5)-O(1) bond length is 1.28 Å. The C(5)-O(2) bond length is 1.28 Å. In the thirteenth C site, C(9) is bonded in a bent 120 degrees geometry to one C(20), one O(3), and one O(4) atom. The C(9)-O(3) bond length is 1.28 Å. The C(9)-O(4) bond length is 1.27 Å. In the fourteenth C site, C(12) is bonded in a trigonal planar geometry to one C(17), one C(22), and one C(5) atom. In the fifteenth C site, C(13) is bonded in a trigonal planar geometry to one C(18), one C(21), and one C(23) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(15), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(15), one C(18), and one H(17) atom. The N(2)-H(17) bond length is 1.02 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(16) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(11,13) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one N(2) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(5) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one C(5) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(9) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one C(9) atom. In each H4(C3F2)3 cluster, there are nine inequivalent C sites. In the first C site, C(26) is bonded in a distorted single-bond geometry to one C(6) and one H(16) atom. The C(26)-C(6) bond length is 1.40 Å. The C(26)-H(16) bond length is 1.09 Å. In the second C site, C(1) is bonded in a tetrahedral geometry to one C(10), one C(2), one C(6), and one C(8) atom. The C(1)-C(10) bond length is 1.57 Å. The C(1)-C(2) bond length is 1.54 Å. The C(1)-C(6) bond length is 1.54 Å. The C(1)-C(8) bond length is 1.56 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(14), and one C(4) atom. The C(2)-C(14) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(26), and one C(7) atom. The C(6)-C(7) bond length is 1.40 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(7)-H(3) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(1), one F(1), one F(2), and one F(3) atom. The C(8)-F(1) bond length is 1.37 Å. The C(8)-F(2) bond length is 1.37 Å. The C(8)-F(3) bond length is 1.35 Å. In the eighth C site, C(10) is bonded in a trigonal non-coplanar geometry to one C(1), one F(4), one F(5), and one F(6) atom. The C(10)-F(4) bond length is 1.36 Å. The C(10)-F(5) bond length is 1.36 Å. The C(10)-F(6) bond length is 1.36 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(14)-H(5) bond length is 1.09 Å. There are four inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(26) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(8) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(8) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one C(10) atom. Linkers: 2 c1ccc(NCc2ccc(CNc3ccccn3)cc2)nc1 ,4 [O]C(=O)c1ccc(C(c2ccc(C([O])=O)cc2)(C(F)(F)F)C(F)(F)F)cc1. Metal clusters: 2 [C]1O[Co]234O[C]O[Co]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 4.61 A, density 1.49 g/cm3, surface area 4107.54 m2/g, accessible volume 0.21 cm3/g