NaCoC15H9(NO3)3(CH)3 crystallizes in the triclinic P1 space group. The structure consists of six 02329_fluka molecules inside a NaCoC15H9(NO3)3 framework. In the NaCoC15H9(NO3)3 framework, there are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(16), one O(17), one O(18), one O(2), and one O(3) atom. The Na(1)-O(1) bond length is 2.48 Å. The Na(1)-O(16) bond length is 2.33 Å. The Na(1)-O(17) bond length is 2.33 Å. The Na(1)-O(18) bond length is 2.33 Å. The Na(1)-O(2) bond length is 2.51 Å. The Na(1)-O(3) bond length is 2.50 Å. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(13), one O(14), one O(15), one O(4), one O(5), and one O(6) atom. The Na(2)-O(13) bond length is 2.33 Å. The Na(2)-O(14) bond length is 2.33 Å. The Na(2)-O(15) bond length is 2.33 Å. The Na(2)-O(4) bond length is 2.48 Å. The Na(2)-O(5) bond length is 2.50 Å. The Na(2)-O(6) bond length is 2.50 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(7), one O(8), and one O(9) atom. The Co(1)-O(1) bond length is 2.07 Å. The Co(1)-O(2) bond length is 2.06 Å. The Co(1)-O(3) bond length is 2.05 Å. The Co(1)-O(7) bond length is 2.05 Å. The Co(1)-O(8) bond length is 2.02 Å. The Co(1)-O(9) bond length is 2.04 Å. In the second Co site, Co(2) is bonded in an octahedral geometry to one O(10), one O(11), one O(12), one O(4), one O(5), and one O(6) atom. The Co(2)-O(10) bond length is 2.05 Å. The Co(2)-O(11) bond length is 2.02 Å. The Co(2)-O(12) bond length is 2.04 Å. The Co(2)-O(4) bond length is 2.07 Å. The Co(2)-O(5) bond length is 2.06 Å. The Co(2)-O(6) bond length is 2.05 Å. There are twenty-nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(1), and one O(1) atom. The C(1)-C(7) bond length is 1.44 Å. The C(1)-N(1) bond length is 1.38 Å. The C(1)-O(1) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(2), and one O(2) atom. The C(2)-C(8) bond length is 1.44 Å. The C(2)-N(2) bond length is 1.38 Å. The C(2)-O(2) bond length is 1.27 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(3), and one O(3) atom. The C(3)-C(9) bond length is 1.44 Å. The C(3)-N(3) bond length is 1.38 Å. The C(3)-O(3) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(4), and one O(4) atom. The C(4)-C(10) bond length is 1.44 Å. The C(4)-N(4) bond length is 1.38 Å. The C(4)-O(4) bond length is 1.27 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(5), and one O(5) atom. The C(5)-C(11) bond length is 1.44 Å. The C(5)-N(5) bond length is 1.38 Å. The C(5)-O(5) bond length is 1.27 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(6), and one O(6) atom. The C(6)-C(12) bond length is 1.44 Å. The C(6)-N(6) bond length is 1.38 Å. The C(6)-O(6) bond length is 1.27 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(31) atom. The C(7)-C(13) bond length is 1.39 Å. The C(7)-C(31) bond length is 1.50 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(32) atom. The C(8)-C(14) bond length is 1.39 Å. The C(8)-C(32) bond length is 1.50 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(15,18); one C(3); and one C(33) atom. The C(9)-C(15,18) bond length is 1.39 Å. The C(9)-C(33) bond length is 1.50 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(16), one C(34), and one C(4) atom. The C(10)-C(16) bond length is 1.39 Å. The C(10)-C(34) bond length is 1.50 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(17), one C(35), and one C(5) atom. The C(11)-C(17) bond length is 1.39 Å. The C(11)-C(35) bond length is 1.50 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(15,18); one C(36); and one C(6) atom. The C(12)-C(15,18) bond length is 1.39 Å. The C(12)-C(36) bond length is 1.50 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(13)-H(7) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(8) and one H(8,9,10) atom. The C(14)-H(8,9,10) bond length is 1.09 Å. In the fifteenth C site, C(15,18) is bonded in a distorted single-bond geometry to one C(9) and one H(8,9,10) atom. The C(15,18)-H(8,9,10) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(10) and one H(8,9,10) atom. The C(16)-H(8,9,10) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(11) and one H(11) atom. The C(17)-H(11) bond length is 1.09 Å. In the eighteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(19,22,24) atom. The C(25)-N(1) bond length is 1.35 Å. The C(25)-H(19,22,24) bond length is 1.09 Å. In the nineteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(20) atom. The C(26)-N(2) bond length is 1.35 Å. The C(26)-H(20) bond length is 1.09 Å. In the twentieth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(21) atom. The C(27)-N(3) bond length is 1.35 Å. The C(27)-H(21) bond length is 1.09 Å. In the twenty-first C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(19,22,24) atom. The C(28)-N(4) bond length is 1.35 Å. The C(28)-H(19,22,24) bond length is 1.09 Å. In the twenty-second C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(23) atom. The C(29)-N(5) bond length is 1.35 Å. The C(29)-H(23) bond length is 1.09 Å. In the twenty-third C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(19,22,24) atom. The C(30)-N(6) bond length is 1.35 Å. The C(30)-H(19,22,24) bond length is 1.09 Å. In the twenty-fourth C site, C(31) is bonded in a bent 120 degrees geometry to one C(7), one O(13), and one O(7) atom. The C(31)-O(13) bond length is 1.27 Å. The C(31)-O(7) bond length is 1.28 Å. In the twenty-fifth C site, C(32) is bonded in a bent 120 degrees geometry to one C(8), one O(14), and one O(8) atom. The C(32)-O(14) bond length is 1.27 Å. The C(32)-O(8) bond length is 1.29 Å. In the twenty-sixth C site, C(33) is bonded in a bent 120 degrees geometry to one C(9), one O(15), and one O(9) atom. The C(33)-O(15) bond length is 1.27 Å. The C(33)-O(9) bond length is 1.28 Å. In the twenty-seventh C site, C(34) is bonded in a bent 120 degrees geometry to one C(10), one O(10), and one O(16) atom. The C(34)-O(10) bond length is 1.28 Å. The C(34)-O(16) bond length is 1.27 Å. In the twenty-eighth C site, C(35) is bonded in a bent 120 degrees geometry to one C(11), one O(11), and one O(17) atom. The C(35)-O(11) bond length is 1.29 Å. The C(35)-O(17) bond length is 1.27 Å. In the twenty-ninth C site, C(36) is bonded in a bent 120 degrees geometry to one C(12), one O(12), and one O(18) atom. The C(36)-O(12) bond length is 1.28 Å. The C(36)-O(18) bond length is 1.27 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(25), and one H(1) atom. The N(1)-H(1) bond length is 1.05 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(26), and one H(2) atom. The N(2)-H(2) bond length is 1.05 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(27), one C(3), and one H(3) atom. The N(3)-H(3) bond length is 1.05 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(28), one C(4), and one H(4) atom. The N(4)-H(4) bond length is 1.05 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(29), one C(5), and one H(5) atom. The N(5)-H(5) bond length is 1.05 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(30), one C(6), and one H(6) atom. The N(6)-H(6) bond length is 1.05 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(8,9,10) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(15,18) atom. The H(12)-C(15,18) bond length is 1.09 Å. In the eleventh H site, H(19,22,24) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(26) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(27) atom. In the fourteenth H site, H(23) is bonded in a single-bond geometry to one C(29) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one Co(1), and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one Co(1), and one C(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(1), one Co(1), and one C(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(2), one Co(2), and one C(4) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(2), one Co(2), and one C(5) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(2), one Co(2), and one C(6) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(31) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(32) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(33) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(34) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(35) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(36) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to one Na(2) and one C(31) atom. In the fourteenth O site, O(14) is bonded in a 2-coordinate geometry to one Na(2) and one C(32) atom. In the fifteenth O site, O(15) is bonded in a 2-coordinate geometry to one Na(2) and one C(33) atom. In the sixteenth O site, O(16) is bonded in a 2-coordinate geometry to one Na(1) and one C(34) atom. In the seventeenth O site, O(17) is bonded in a 2-coordinate geometry to one Na(1) and one C(35) atom. In the eighteenth O site, O(18) is bonded in a 2-coordinate geometry to one Na(1) and one C(36) atom. Linkers: 6 [O]C(=O)c1ccc[nH]c1=O. Metal clusters: 2 [Na] ,2 [Co]. The MOF has largest included sphere 4.55 A, density 1.54 g/cm3, surface area 3529.23 m2/g, accessible volume 0.21 cm3/g