ZnC23N3H14O5(CH)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and one ZnC23N3H14O5 cluster. In the ZnC23N3H14O5 cluster, Zn(1) is bonded in a 5-coordinate geometry to one N(1), one N(3), one O(1), one O(2), and one O(5) atom. The Zn(1)-N(1) bond length is 2.11 Å. The Zn(1)-N(3) bond length is 2.06 Å. The Zn(1)-O(1) bond length is 2.08 Å. The Zn(1)-O(2) bond length is 2.33 Å. The Zn(1)-O(5) bond length is 1.99 Å. There are twenty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.42 Å. The C(1)-N(1) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(5) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(5) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one N(2) atom. The C(6)-N(2) bond length is 1.38 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(1), and one N(2) atom. The C(7)-C(8) bond length is 1.46 Å. The C(7)-N(1) bond length is 1.34 Å. The C(7)-N(2) bond length is 1.36 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(9)-H(6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(7) atom. The C(10)-N(3) bond length is 1.35 Å. The C(10)-H(7) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(8) atom. The C(11)-N(3) bond length is 1.35 Å. The C(11)-H(8) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(8) and one H(9) atom. The C(12)-H(9) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(1), and one O(2) atom. The C(13)-C(14) bond length is 1.49 Å. The C(13)-O(1) bond length is 1.30 Å. The C(13)-O(2) bond length is 1.27 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(19) bond length is 1.40 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(10) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(10) bond length is 1.09 Å. In the fifteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(11) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(11) bond length is 1.09 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one O(3) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-O(3) bond length is 1.39 Å. In the seventeenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(12) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(12) bond length is 1.09 Å. In the eighteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one H(13) atom. The C(19)-H(13) bond length is 1.09 Å. In the nineteenth C site, C(20) is bonded in a distorted single-bond geometry to one O(3) atom. The C(20)-O(3) bond length is 1.38 Å. In the twentieth C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(15) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(15) bond length is 1.09 Å. In the twenty-first C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(26) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(26) bond length is 1.49 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(16) atom. The C(24)-H(16) bond length is 1.09 Å. In the twenty-third C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(4), and one O(5) atom. The C(26)-O(4) bond length is 1.27 Å. The C(26)-O(5) bond length is 1.29 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one C(1), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(6), one C(7), and one H(1) atom. The N(2)-H(1) bond length is 1.06 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(11) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted bent 150 degrees geometry to one N(2) and one O(4) atom. The H(1)-O(4) bond length is 1.65 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Zn(1) and one C(13) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Zn(1) and one C(13) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(17) and one C(20) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one C(26) and one H(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(26) atom. Linkers: 2 c1ccc2[nH]c(-c3ccncc3)nc2c1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.66 A, density 1.65 g/cm3, surface area 4437.89 m2/g, accessible volume 0.09 cm3/g