AgC6H4SO5CH crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a AgC6H4SO5 framework. In the AgC6H4SO5 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), and two equivalent O(6) atoms. The Ag(1)-O(1) bond length is 2.35 Å. The Ag(1)-O(3) bond length is 2.74 Å. The Ag(1)-O(4) bond length is 2.52 Å. There is one shorter (2.36 Å) and one longer (2.55 Å) Ag(1)-O(6) bond length. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one O(2), one O(3), one O(4), and two equivalent O(5) atoms. The Ag(2)-O(2) bond length is 2.35 Å. The Ag(2)-O(3) bond length is 2.52 Å. The Ag(2)-O(4) bond length is 2.73 Å. There is one shorter (2.37 Å) and one longer (2.56 Å) Ag(2)-O(5) bond length. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(11), one C(3), and one S(1) atom. The C(1)-C(11) bond length is 1.40 Å. The C(1)-C(3) bond length is 1.39 Å. The C(1)-S(1) bond length is 1.78 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(12), one C(4), and one S(2) atom. The C(2)-C(12) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.39 Å. The C(2)-S(2) bond length is 1.78 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1); one C(5); and one H(1,2) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-H(1,2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2); one C(6); and one H(1,2) atom. The C(4)-C(6) bond length is 1.40 Å. The C(4)-H(1,2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(13); one C(3); and one C(7,8) atom. The C(5)-C(13) bond length is 1.48 Å. The C(5)-C(7,8) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(14); one C(4); and one C(7,8) atom. The C(6)-C(14) bond length is 1.48 Å. The C(6)-C(7,8) bond length is 1.40 Å. In the seventh C site, C(7,8) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(7,8)-H(3) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(1) and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(2) and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(7), and one O(9) atom. The C(13)-O(7) bond length is 1.32 Å. The C(13)-O(9) bond length is 1.25 Å. In the eleventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(10), and one O(8) atom. The C(14)-O(10) bond length is 1.25 Å. The C(14)-O(8) bond length is 1.32 Å. There are seven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(7,8) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7,8) atom. The H(4)-C(7,8) bond length is 1.09 Å. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(9) is bonded in a linear geometry to one O(7) and one O(9) atom. The H(9)-O(7) bond length is 1.04 Å. The H(9)-O(9) bond length is 1.53 Å. In the seventh H site, H(10) is bonded in a linear geometry to one O(10) and one O(8) atom. The H(10)-O(10) bond length is 1.53 Å. The H(10)-O(8) bond length is 1.04 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(3), and one O(5) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.47 Å. The S(1)-O(5) bond length is 1.49 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one O(2), one O(4), and one O(6) atom. The S(2)-O(2) bond length is 1.47 Å. The S(2)-O(4) bond length is 1.47 Å. The S(2)-O(6) bond length is 1.49 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one S(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one S(2) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to two equivalent Ag(2) and one S(1) atom. In the sixth O site, O(6) is bonded in a 1-coordinate geometry to two equivalent Ag(1) and one S(2) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one C(13) and one H(9) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one C(14) and one H(10) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one C(13) and one H(9) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one C(14) and one H(10) atom. Linkers: 4 [O]S([O])([O])c1cccc(C(=O)O)c1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.40 A, density 2.59 g/cm3, surface area 2633.78 m2/g, accessible volume 0.05 cm3/g