CdC26H22(N2O3)2CdC20H20(NO)4(CH)2(CH2)4 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, eight 02329_fluka molecules, two CdC20H20(NO)4 clusters, and two CdC26H22(N2O3)2 clusters. In each CdC20H20(NO)4 cluster, Cd(2) is bonded in a distorted octahedral geometry to one N(1), one N(2), one O(10), one O(7), one O(8), and one O(9) atom. The Cd(2)-N(1) bond length is 2.34 Å. The Cd(2)-N(2) bond length is 2.34 Å. The Cd(2)-O(10) bond length is 2.51 Å. The Cd(2)-O(7) bond length is 2.32 Å. The Cd(2)-O(8) bond length is 2.32 Å. The Cd(2)-O(9) bond length is 2.51 Å. There are fourteen inequivalent C sites. In the first C site, C(19,20) is bonded in a distorted single-bond geometry to one C(21) and one H(11,12) atom. The C(19,20)-C(21) bond length is 1.40 Å. The C(19,20)-H(11,12) bond length is 1.09 Å. In the second C site, C(21) is bonded in a trigonal planar geometry to one C(19,20); one C(23,24); and one C(27,28) atom. The C(21)-C(23,24) bond length is 1.40 Å. The C(21)-C(27,28) bond length is 1.50 Å. In the third C site, C(22) is bonded in a trigonal planar geometry to one C(19,20); one C(23,24); and one C(27,28) atom. The C(22)-C(19,20) bond length is 1.40 Å. The C(22)-C(23,24) bond length is 1.40 Å. The C(22)-C(27,28) bond length is 1.50 Å. In the fourth C site, C(23,24) is bonded in a distorted trigonal planar geometry to one C(21), one C(25), and one H(13) atom. The C(23,24)-C(25) bond length is 1.39 Å. The C(23,24)-H(13) bond length is 1.09 Å. In the fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(23,24) and one H(15,16) atom. The C(25)-H(15,16) bond length is 1.09 Å. In the sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(23,24) and one H(15,16) atom. The C(26)-C(23,24) bond length is 1.39 Å. The C(26)-H(15,16) bond length is 1.09 Å. In the seventh C site, C(27,28) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(7), and one O(9) atom. The C(27,28)-O(7) bond length is 1.28 Å. The C(27,28)-O(9) bond length is 1.27 Å. In the eighth C site, C(29,30) is bonded in a distorted trigonal non-coplanar geometry to one C(31); one H(17,18); one H(19,20); and one H(21,22) atom. The C(29,30)-C(31) bond length is 1.48 Å. The C(29,30)-H(17,18) bond length is 1.10 Å. The C(29,30)-H(19,20) bond length is 1.10 Å. The C(29,30)-H(21,22) bond length is 1.10 Å. In the ninth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(29,30); one N(1); and one N(3) atom. The C(31)-N(1) bond length is 1.34 Å. The C(31)-N(3) bond length is 1.36 Å. In the tenth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(29,30); one N(2); and one N(4) atom. The C(32)-C(29,30) bond length is 1.49 Å. The C(32)-N(2) bond length is 1.34 Å. The C(32)-N(4) bond length is 1.36 Å. In the eleventh C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(35,36); one N(1); and one H(23,24) atom. The C(33)-C(35,36) bond length is 1.37 Å. The C(33)-N(1) bond length is 1.39 Å. The C(33)-H(23,24) bond length is 1.08 Å. In the twelfth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(35,36); one N(2); and one H(23,24) atom. The C(34)-C(35,36) bond length is 1.37 Å. The C(34)-N(2) bond length is 1.39 Å. The C(34)-H(23,24) bond length is 1.08 Å. In the thirteenth C site, C(35,36) is bonded in a distorted bent 120 degrees geometry to one C(33), one N(3), and one H(25) atom. The C(35,36)-N(3) bond length is 1.38 Å. The C(35,36)-H(25) bond length is 1.08 Å. In the fourteenth C site, C(37,38) is bonded in a distorted trigonal non-coplanar geometry to one N(3); one H(27,28); and one H(29,30) atom. The C(37,38)-N(3) bond length is 1.46 Å. The C(37,38)-H(27,28) bond length is 1.09 Å. The C(37,38)-H(29,30) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(31), and one C(33) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(32), and one C(34) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(31); one C(35,36); and one C(37,38) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(32); one C(35,36); and one C(37,38) atom. The N(4)-C(35,36) bond length is 1.38 Å. The N(4)-C(37,38) bond length is 1.46 Å. There are twelve inequivalent H sites. In the first H site, H(11,12) is bonded in a single-bond geometry to one C(19,20) atom. In the second H site, H(13) is bonded in a single-bond geometry to one C(23,24) atom. In the third H site, H(14) is bonded in a single-bond geometry to one C(23,24) atom. The H(14)-C(23,24) bond length is 1.09 Å. In the fourth H site, H(15,16) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(17,18) is bonded in a single-bond geometry to one C(29,30) atom. In the sixth H site, H(19,20) is bonded in a single-bond geometry to one C(29,30) atom. In the seventh H site, H(21,22) is bonded in a single-bond geometry to one C(29,30) atom. In the eighth H site, H(23,24) is bonded in a single-bond geometry to one C(33) atom. In the ninth H site, H(25) is bonded in a single-bond geometry to one C(35,36) atom. In the tenth H site, H(26) is bonded in a single-bond geometry to one C(35,36) atom. The H(26)-C(35,36) bond length is 1.08 Å. In the eleventh H site, H(27,28) is bonded in a single-bond geometry to one C(37,38) atom. In the twelfth H site, H(29,30) is bonded in a single-bond geometry to one C(37,38) atom. There are four inequivalent O sites. In the first O site, O(7) is bonded in an L-shaped geometry to one Cd(2) and one C(27,28) atom. In the second O site, O(8) is bonded in an L-shaped geometry to one Cd(2) and one C(27,28) atom. The O(8)-C(27,28) bond length is 1.28 Å. In the third O site, O(9) is bonded in a distorted single-bond geometry to one Cd(2) and one C(27,28) atom. In the fourth O site, O(10) is bonded in a distorted single-bond geometry to one Cd(2) and one C(27,28) atom. The O(10)-C(27,28) bond length is 1.27 Å. In each CdC26H22(N2O3)2 cluster, Cd(1) is bonded in a distorted pentagonal pyramidal geometry to one N(7), one N(8), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(7) bond length is 2.29 Å. The Cd(1)-N(8) bond length is 2.29 Å. The Cd(1)-O(1) bond length is 2.46 Å. The Cd(1)-O(2) bond length is 2.46 Å. The Cd(1)-O(3) bond length is 2.37 Å. The Cd(1)-O(4) bond length is 2.37 Å. There are nineteen inequivalent C sites. In the first C site, C(11,12) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one H(5) atom. The C(11,12)-C(13) bond length is 1.39 Å. The C(11,12)-C(9) bond length is 1.40 Å. The C(11,12)-H(5) bond length is 1.09 Å. In the second C site, C(13) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(3); and one H(7,8) atom. The C(13)-C(3) bond length is 1.40 Å. The C(13)-H(7,8) bond length is 1.09 Å. In the third C site, C(14) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(4); and one H(7,8) atom. The C(14)-C(11,12) bond length is 1.39 Å. The C(14)-C(4) bond length is 1.40 Å. The C(14)-H(7,8) bond length is 1.09 Å. In the fourth C site, C(15,16) is bonded in a distorted single-bond geometry to one O(5,6) atom. The C(15,16)-O(5,6) bond length is 1.39 Å. In the fifth C site, C(43,44) is bonded in a distorted trigonal non-coplanar geometry to one N(5,6); one H(39,40); and one H(41,42) atom. The C(43,44)-N(5,6) bond length is 1.46 Å. The C(43,44)-H(39,40) bond length is 1.10 Å. The C(43,44)-H(41,42) bond length is 1.10 Å. In the sixth C site, C(45,46) is bonded in a distorted bent 120 degrees geometry to one C(47,48); one N(5,6); and one H(43,44) atom. The C(45,46)-C(47,48) bond length is 1.37 Å. The C(45,46)-N(5,6) bond length is 1.39 Å. The C(45,46)-H(43,44) bond length is 1.08 Å. In the seventh C site, C(47,48) is bonded in a distorted bent 120 degrees geometry to one C(45,46); one N(7); and one H(45,46) atom. The C(47,48)-N(7) bond length is 1.38 Å. The C(47,48)-H(45,46) bond length is 1.08 Å. In the eighth C site, C(49,50) is bonded in a distorted trigonal planar geometry to one C(51,52); one N(5,6); and one N(7) atom. The C(49,50)-C(51,52) bond length is 1.48 Å. The C(49,50)-N(5,6) bond length is 1.36 Å. The C(49,50)-N(7) bond length is 1.34 Å. In the ninth C site, C(51,52) is bonded in a distorted trigonal non-coplanar geometry to one C(49,50); one H(47,48); one H(49,50); and one H(51,52) atom. The C(51,52)-H(47,48) bond length is 1.10 Å. The C(51,52)-H(49,50) bond length is 1.10 Å. The C(51,52)-H(51,52) bond length is 1.10 Å. In the tenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.28 Å. In the eleventh C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(4) atom. The C(2)-C(4) bond length is 1.49 Å. The C(2)-O(2) bond length is 1.28 Å. The C(2)-O(4) bond length is 1.28 Å. In the twelfth C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(5) atom. The C(3)-C(5) bond length is 1.40 Å. In the thirteenth C site, C(4) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(6) atom. The C(4)-C(6) bond length is 1.40 Å. In the fourteenth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one H(1) atom. The C(5)-C(7) bond length is 1.39 Å. The C(5)-H(1) bond length is 1.09 Å. In the fifteenth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(4), one C(8), and one H(2) atom. The C(6)-C(8) bond length is 1.39 Å. The C(6)-H(2) bond length is 1.09 Å. In the sixteenth C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one H(3,4) atom. The C(7)-H(3,4) bond length is 1.09 Å. In the seventeenth C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one H(3,4) atom. The C(8)-H(3,4) bond length is 1.09 Å. In the eighteenth C site, C(9) is bonded in a distorted single-bond geometry to one C(11,12) and one O(5,6) atom. The C(9)-O(5,6) bond length is 1.37 Å. In the nineteenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11,12) and one O(5,6) atom. The C(10)-C(11,12) bond length is 1.40 Å. The C(10)-O(5,6) bond length is 1.37 Å. There are three inequivalent N sites. In the first N site, N(5,6) is bonded in a trigonal planar geometry to one C(43,44); one C(45,46); and one C(49,50) atom. In the second N site, N(7) is bonded in a distorted trigonal planar geometry to one Cd(1); one C(47,48); and one C(49,50) atom. In the third N site, N(8) is bonded in a distorted trigonal planar geometry to one Cd(1); one C(47,48); and one C(49,50) atom. The N(8)-C(47,48) bond length is 1.38 Å. The N(8)-C(49,50) bond length is 1.34 Å. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(11,12) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(11,12) atom. The H(6)-C(11,12) bond length is 1.09 Å. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(39,40) is bonded in a single-bond geometry to one C(43,44) atom. In the eighth H site, H(41,42) is bonded in a single-bond geometry to one C(43,44) atom. In the ninth H site, H(43,44) is bonded in a single-bond geometry to one C(45,46) atom. In the tenth H site, H(45,46) is bonded in a single-bond geometry to one C(47,48) atom. In the eleventh H site, H(47,48) is bonded in a single-bond geometry to one C(51,52) atom. In the twelfth H site, H(49,50) is bonded in a single-bond geometry to one C(51,52) atom. In the thirteenth H site, H(51,52) is bonded in a single-bond geometry to one C(51,52) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(2) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(2) atom. In the fifth O site, O(5,6) is bonded in a bent 120 degrees geometry to one C(15,16) and one C(9) atom. Linkers: 1 C[C]1N(CCCCn2ccnc2C)C=CN1[Cd]12(N3C=CN(CCCCn4ccnc4C)[C]3C)(O[C](c3ccc(Oc4ccc([C]=O)cc4)cc3)O1)O[C](c1ccc(Oc3ccc(C([O])=O)cc3)cc1)O2 ,2 Cc1nccn1CCCCn1ccnc1C ,1 [CH]C(C=[CH])=C1O[Cd]2(N3C=CN(CCCCn4ccnc4C)[C]3C)(N3C=CN(CCCCn4ccnc4C)[C]3C)(O[C]O2)O1 ,1 [CH2]CCN1C=CN([Cd]23(N4C=CN(C[CH2])[C]4C)(O[C](c4ccc(Oc5ccc(C([O])=O)cc5)cc4)O2)O[C](c2ccc(Oc4ccc(C([O])=O)cc4)cc2)O3)[C]1C ,2 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,1 [O]C(=O)c1ccc(Oc2ccc([C]=O)cc2)cc1. Metal clusters: 3 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 4.40 A, density 1.41 g/cm3, surface area 4767.67 m2/g, accessible volume 0.23 cm3/g