Pr2AgC23NH13O16CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a Pr2AgC23NH13O16 framework. In the Pr2AgC23NH13O16 framework, there are two inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a 9-coordinate geometry to one O(13), one O(15), one O(16), one O(2), one O(3), one O(7), one O(9), and two equivalent O(1) atoms. The Pr(1)-O(13) bond length is 2.42 Å. The Pr(1)-O(15) bond length is 2.61 Å. The Pr(1)-O(16) bond length is 2.63 Å. The Pr(1)-O(2) bond length is 2.54 Å. The Pr(1)-O(3) bond length is 2.49 Å. The Pr(1)-O(7) bond length is 2.45 Å. The Pr(1)-O(9) bond length is 2.59 Å. There is one shorter (2.51 Å) and one longer (2.74 Å) Pr(1)-O(1) bond length. In the second Pr site, Pr(2) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(14), one O(3), one O(5), one O(6), one O(8), and one O(9) atom. The Pr(2)-O(10) bond length is 2.43 Å. The Pr(2)-O(11) bond length is 2.47 Å. The Pr(2)-O(14) bond length is 2.43 Å. The Pr(2)-O(3) bond length is 2.58 Å. The Pr(2)-O(5) bond length is 2.47 Å. The Pr(2)-O(6) bond length is 2.39 Å. The Pr(2)-O(8) bond length is 2.49 Å. The Pr(2)-O(9) bond length is 2.53 Å. Ag(1) is bonded in a distorted T-shaped geometry to one N(1), one O(4), and one O(8) atom. The Ag(1)-N(1) bond length is 2.16 Å. The Ag(1)-O(4) bond length is 2.22 Å. The Ag(1)-O(8) bond length is 2.64 Å. There are twenty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(1)-C(4) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(3), and one O(4) atom. The C(2)-C(5) bond length is 1.50 Å. The C(2)-O(3) bond length is 1.29 Å. The C(2)-O(4) bond length is 1.26 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(5), and one O(6) atom. The C(3)-C(6) bond length is 1.50 Å. The C(3)-O(5) bond length is 1.28 Å. The C(3)-O(6) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(9) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(9) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.41 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(4) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(7), and one O(8) atom. The C(10)-C(13) bond length is 1.50 Å. The C(10)-O(7) bond length is 1.28 Å. The C(10)-O(8) bond length is 1.27 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(10), and one O(9) atom. The C(11)-C(14) bond length is 1.51 Å. The C(11)-O(10) bond length is 1.25 Å. The C(11)-O(9) bond length is 1.29 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(11), and one O(12) atom. The C(12)-C(15) bond length is 1.51 Å. The C(12)-O(11) bond length is 1.31 Å. The C(12)-O(12) bond length is 1.24 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(18) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(18) bond length is 1.40 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(15) atom. The C(14)-C(15) bond length is 1.40 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(15)-C(16) bond length is 1.40 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(8) atom. The C(16)-H(8) bond length is 1.09 Å. In the seventeenth C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(18)-H(10) bond length is 1.09 Å. In the eighteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(13), and one O(14) atom. The C(19)-C(20) bond length is 1.51 Å. The C(19)-O(13) bond length is 1.27 Å. The C(19)-O(14) bond length is 1.26 Å. In the nineteenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(24) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(24) bond length is 1.40 Å. In the twentieth C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one H(11) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(11) bond length is 1.09 Å. In the twenty-first C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one N(1), and one H(12) atom. The C(22)-N(1) bond length is 1.35 Å. The C(22)-H(12) bond length is 1.09 Å. In the twenty-second C site, C(23) is bonded in a distorted trigonal planar geometry to one C(24), one N(1), and one H(13) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-N(1) bond length is 1.35 Å. The C(23)-H(13) bond length is 1.09 Å. In the twenty-third C site, C(24) is bonded in a distorted trigonal planar geometry to one C(20), one C(23), and one H(14) atom. The C(24)-H(14) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(22), and one C(23) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(15) atom. The H(1)-O(15) bond length is 0.98 Å. In the second H site, H(2) is bonded in a distorted linear geometry to one O(11) and one O(15) atom. The H(2)-O(11) bond length is 1.64 Å. The H(2)-O(15) bond length is 1.02 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(16) atom. The H(3)-O(16) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(16) atom. The H(4)-O(16) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Pr(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Pr(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Pr(1), one Pr(2), and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Ag(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Pr(2) and one C(3) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Pr(2) and one C(3) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Pr(1) and one C(10) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Pr(2), one Ag(1), and one C(10) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Pr(1), one Pr(2), and one C(11) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Pr(2) and one C(11) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one Pr(2), one C(12), and one H(2) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one C(19) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Pr(2) and one C(19) atom. In the fifteenth O site, O(15) is bonded in a water-like geometry to one Pr(1), one H(1), and one H(2) atom. In the sixteenth O site, O(16) is bonded in a water-like geometry to one Pr(1), one H(3), and one H(4) atom. Linkers: 2 [O]C(=O)c1ccncc1 ,4 [O]C(=O)c1cccc(C([O])=O)c1C([O])=O. Metal clusters: 4 [Pr] ,2 [Ag]. The MOF has largest included sphere 3.37 A, density 2.48 g/cm3, surface area 2434.14 m2/g, accessible volume 0.05 cm3/g