Ni2C22N4H14O9(CH)2 crystallizes in the triclinic P1 space group. The structure consists of eight 02329_fluka molecules inside a Ni2C22N4H14O9 framework. In the Ni2C22N4H14O9 framework, there are eight inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one N(13), one N(7), one O(1), one O(21), one O(33), and one O(9) atom to form corner-sharing NiN2O4 octahedra. The corner-sharing octahedral tilt angles are 60°. The Ni(1)-N(13) bond length is 2.04 Å. The Ni(1)-N(7) bond length is 2.02 Å. The Ni(1)-O(1) bond length is 2.03 Å. The Ni(1)-O(21) bond length is 2.05 Å. The Ni(1)-O(33) bond length is 1.79 Å. The Ni(1)-O(9) bond length is 2.03 Å. In the second Ni site, Ni(2) is bonded to one N(14), one N(8), one O(10), one O(2), one O(22), and one O(34) atom to form corner-sharing NiN2O4 octahedra. The corner-sharing octahedral tilt angles are 56°. The Ni(2)-N(14) bond length is 2.04 Å. The Ni(2)-N(8) bond length is 2.12 Å. The Ni(2)-O(10) bond length is 2.07 Å. The Ni(2)-O(2) bond length is 2.04 Å. The Ni(2)-O(22) bond length is 2.08 Å. The Ni(2)-O(34) bond length is 1.78 Å. In the third Ni site, Ni(3) is bonded to one N(15), one N(5), one O(11), one O(23), one O(3), and one O(35) atom to form corner-sharing NiN2O4 octahedra. The corner-sharing octahedral tilt angles are 60°. The Ni(3)-N(15) bond length is 2.05 Å. The Ni(3)-N(5) bond length is 2.03 Å. The Ni(3)-O(11) bond length is 2.04 Å. The Ni(3)-O(23) bond length is 2.04 Å. The Ni(3)-O(3) bond length is 2.02 Å. The Ni(3)-O(35) bond length is 1.79 Å. In the fourth Ni site, Ni(4) is bonded to one N(16), one N(6), one O(12), one O(24), one O(36), and one O(4) atom to form corner-sharing NiN2O4 octahedra. The corner-sharing octahedral tilt angles are 59°. The Ni(4)-N(16) bond length is 2.05 Å. The Ni(4)-N(6) bond length is 2.04 Å. The Ni(4)-O(12) bond length is 2.02 Å. The Ni(4)-O(24) bond length is 2.05 Å. The Ni(4)-O(36) bond length is 1.79 Å. The Ni(4)-O(4) bond length is 2.04 Å. In the fifth Ni site, Ni(5) is bonded to one N(11), one N(4), one O(13), one O(17), one O(31), and one O(33) atom to form corner-sharing NiN2O4 octahedra. The corner-sharing octahedral tilt angles are 60°. The Ni(5)-N(11) bond length is 2.02 Å. The Ni(5)-N(4) bond length is 2.02 Å. The Ni(5)-O(13) bond length is 2.02 Å. The Ni(5)-O(17) bond length is 2.10 Å. The Ni(5)-O(31) bond length is 2.01 Å. The Ni(5)-O(33) bond length is 1.79 Å. In the sixth Ni site, Ni(6) is bonded to one N(12), one N(3), one O(14), one O(18), one O(32), and one O(34) atom to form corner-sharing NiN2O4 octahedra. The corner-sharing octahedral tilt angles are 56°. The Ni(6)-N(12) bond length is 2.07 Å. The Ni(6)-N(3) bond length is 2.00 Å. The Ni(6)-O(14) bond length is 2.07 Å. The Ni(6)-O(18) bond length is 2.10 Å. The Ni(6)-O(32) bond length is 2.06 Å. The Ni(6)-O(34) bond length is 1.78 Å. In the seventh Ni site, Ni(7) is bonded to one N(2), one N(9), one O(15), one O(19), one O(29), and one O(35) atom to form corner-sharing NiN2O4 octahedra. The corner-sharing octahedral tilt angles are 60°. The Ni(7)-N(2) bond length is 2.03 Å. The Ni(7)-N(9) bond length is 2.02 Å. The Ni(7)-O(15) bond length is 2.03 Å. The Ni(7)-O(19) bond length is 2.09 Å. The Ni(7)-O(29) bond length is 2.02 Å. The Ni(7)-O(35) bond length is 1.79 Å. In the eighth Ni site, Ni(8) is bonded to one N(1), one N(10), one O(16), one O(20), one O(30), and one O(36) atom to form corner-sharing NiN2O4 octahedra. The corner-sharing octahedral tilt angles are 59°. The Ni(8)-N(1) bond length is 2.03 Å. The Ni(8)-N(10) bond length is 2.03 Å. The Ni(8)-O(16) bond length is 2.03 Å. The Ni(8)-O(20) bond length is 2.09 Å. The Ni(8)-O(30) bond length is 2.02 Å. The Ni(8)-O(36) bond length is 1.79 Å. There are eighty-eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(5) atom. The C(1)-C(5) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(5) bond length is 1.24 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(2), and one O(6) atom. The C(2)-C(6) bond length is 1.52 Å. The C(2)-O(2) bond length is 1.30 Å. The C(2)-O(6) bond length is 1.24 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(7) atom. The C(3)-C(7) bond length is 1.52 Å. The C(3)-O(3) bond length is 1.30 Å. The C(3)-O(7) bond length is 1.24 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(4), and one O(8) atom. The C(4)-C(8) bond length is 1.52 Å. The C(4)-O(4) bond length is 1.30 Å. The C(4)-O(8) bond length is 1.24 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(21), and one C(9) atom. The C(5)-C(21) bond length is 1.39 Å. The C(5)-C(9) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(22) atom. The C(6)-C(10) bond length is 1.40 Å. The C(6)-C(22) bond length is 1.39 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(23), and one C(3) atom. The C(7)-C(11) bond length is 1.40 Å. The C(7)-C(23) bond length is 1.39 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(24), and one C(4) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(24) bond length is 1.39 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(13), one C(5), and one H(1) atom. The C(9)-C(13) bond length is 1.39 Å. The C(9)-H(1) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(6) and one H(2) atom. The C(10)-H(2) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(15), one C(7), and one H(3) atom. The C(11)-C(15) bond length is 1.39 Å. The C(11)-H(3) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(8) and one H(4) atom. The C(12)-H(4) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(17), one C(9), and one H(5) atom. The C(13)-C(17) bond length is 1.39 Å. The C(13)-H(5) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(11), one C(19), and one H(7) atom. The C(15)-C(19) bond length is 1.39 Å. The C(15)-H(7) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(1), and one H(9) atom. The C(17)-N(1) bond length is 1.34 Å. The C(17)-H(9) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(18)-N(2) bond length is 1.34 Å. The C(18)-H(10) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(3), and one H(11) atom. The C(19)-N(3) bond length is 1.34 Å. The C(19)-H(11) bond length is 1.09 Å. In the eighteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(12) atom. The C(20)-N(4) bond length is 1.34 Å. The C(20)-H(12) bond length is 1.09 Å. In the nineteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(1), and one H(13) atom. The C(21)-N(1) bond length is 1.34 Å. The C(21)-H(13) bond length is 1.09 Å. In the twentieth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(2), and one H(14) atom. The C(22)-N(2) bond length is 1.34 Å. The C(22)-H(14) bond length is 1.09 Å. In the twenty-first C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(3), and one H(15) atom. The C(23)-N(3) bond length is 1.34 Å. The C(23)-H(15) bond length is 1.09 Å. In the twenty-second C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(4), and one H(16) atom. The C(24)-N(4) bond length is 1.34 Å. The C(24)-H(16) bond length is 1.09 Å. In the twenty-third C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(21) atom. The C(29)-N(5) bond length is 1.35 Å. The C(29)-H(21) bond length is 1.09 Å. In the twenty-fourth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(22) atom. The C(30)-N(6) bond length is 1.35 Å. The C(30)-H(22) bond length is 1.09 Å. In the twenty-fifth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(23) atom. The C(31)-N(7) bond length is 1.35 Å. The C(31)-H(23) bond length is 1.09 Å. In the twenty-sixth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(24) atom. The C(32)-N(8) bond length is 1.35 Å. The C(32)-H(24) bond length is 1.09 Å. In the twenty-seventh C site, C(33) is bonded in a 2-coordinate geometry to one C(41), one N(5), and one H(25) atom. The C(33)-C(41) bond length is 1.40 Å. The C(33)-N(5) bond length is 1.34 Å. The C(33)-H(25) bond length is 1.08 Å. In the twenty-eighth C site, C(34) is bonded in a 3-coordinate geometry to one C(42), one N(6), and one H(26) atom. The C(34)-C(42) bond length is 1.40 Å. The C(34)-N(6) bond length is 1.34 Å. The C(34)-H(26) bond length is 1.08 Å. In the twenty-ninth C site, C(35) is bonded in a 2-coordinate geometry to one C(43), one N(7), and one H(27) atom. The C(35)-C(43) bond length is 1.39 Å. The C(35)-N(7) bond length is 1.34 Å. The C(35)-H(27) bond length is 1.08 Å. In the thirtieth C site, C(36) is bonded in a 3-coordinate geometry to one C(44), one N(8), and one H(28) atom. The C(36)-C(44) bond length is 1.40 Å. The C(36)-N(8) bond length is 1.34 Å. The C(36)-H(28) bond length is 1.08 Å. In the thirty-first C site, C(37) is bonded in a distorted single-bond geometry to one C(41) and one H(29,31) atom. The C(37)-C(41) bond length is 1.40 Å. The C(37)-H(29,31) bond length is 1.09 Å. In the thirty-second C site, C(38) is bonded in a distorted single-bond geometry to one C(42) and one H(30) atom. The C(38)-C(42) bond length is 1.40 Å. The C(38)-H(30) bond length is 1.09 Å. In the thirty-third C site, C(39) is bonded in a distorted single-bond geometry to one C(43) and one H(29,31) atom. The C(39)-C(43) bond length is 1.40 Å. The C(39)-H(29,31) bond length is 1.09 Å. In the thirty-fourth C site, C(40) is bonded in a distorted single-bond geometry to one C(44) and one H(32) atom. The C(40)-C(44) bond length is 1.40 Å. The C(40)-H(32) bond length is 1.09 Å. In the thirty-fifth C site, C(41) is bonded in a trigonal planar geometry to one C(33), one C(37), and one C(45) atom. The C(41)-C(45) bond length is 1.51 Å. In the thirty-sixth C site, C(42) is bonded in a trigonal planar geometry to one C(34), one C(38), and one C(46) atom. The C(42)-C(46) bond length is 1.51 Å. In the thirty-seventh C site, C(43) is bonded in a trigonal planar geometry to one C(35), one C(39), and one C(47) atom. The C(43)-C(47) bond length is 1.51 Å. In the thirty-eighth C site, C(44) is bonded in a trigonal planar geometry to one C(36), one C(40), and one C(48) atom. The C(44)-C(48) bond length is 1.51 Å. In the thirty-ninth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(41), one O(13), and one O(9) atom. The C(45)-O(13) bond length is 1.27 Å. The C(45)-O(9) bond length is 1.27 Å. In the fortieth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one C(42), one O(10), and one O(14) atom. The C(46)-O(10) bond length is 1.27 Å. The C(46)-O(14) bond length is 1.27 Å. In the forty-first C site, C(47) is bonded in a distorted bent 120 degrees geometry to one C(43), one O(11), and one O(15) atom. The C(47)-O(11) bond length is 1.27 Å. The C(47)-O(15) bond length is 1.27 Å. In the forty-second C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(44), one O(12), and one O(16) atom. The C(48)-O(12) bond length is 1.27 Å. The C(48)-O(16) bond length is 1.27 Å. In the forty-third C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(53), one O(17), and one O(21) atom. The C(49)-C(53) bond length is 1.50 Å. The C(49)-O(17) bond length is 1.27 Å. The C(49)-O(21) bond length is 1.27 Å. In the forty-fourth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one C(54), one O(18), and one O(22) atom. The C(50)-C(54) bond length is 1.51 Å. The C(50)-O(18) bond length is 1.27 Å. The C(50)-O(22) bond length is 1.27 Å. In the forty-fifth C site, C(51) is bonded in a distorted bent 120 degrees geometry to one C(55), one O(19), and one O(23) atom. The C(51)-C(55) bond length is 1.50 Å. The C(51)-O(19) bond length is 1.27 Å. The C(51)-O(23) bond length is 1.27 Å. In the forty-sixth C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(56), one O(20), and one O(24) atom. The C(52)-C(56) bond length is 1.50 Å. The C(52)-O(20) bond length is 1.27 Å. The C(52)-O(24) bond length is 1.27 Å. In the forty-seventh C site, C(53) is bonded in a trigonal planar geometry to one C(49), one C(57), and one C(69) atom. The C(53)-C(57) bond length is 1.40 Å. The C(53)-C(69) bond length is 1.39 Å. In the forty-eighth C site, C(54) is bonded in a trigonal planar geometry to one C(50), one C(58), and one C(70) atom. The C(54)-C(58) bond length is 1.40 Å. The C(54)-C(70) bond length is 1.39 Å. In the forty-ninth C site, C(55) is bonded in a trigonal planar geometry to one C(51), one C(59), and one C(71) atom. The C(55)-C(59) bond length is 1.40 Å. The C(55)-C(71) bond length is 1.39 Å. In the fiftieth C site, C(56) is bonded in a trigonal planar geometry to one C(52), one C(60), and one C(72) atom. The C(56)-C(60) bond length is 1.40 Å. The C(56)-C(72) bond length is 1.39 Å. In the fifty-first C site, C(57) is bonded in a distorted single-bond geometry to one C(53) and one H(33) atom. The C(57)-H(33) bond length is 1.09 Å. In the fifty-second C site, C(58) is bonded in a distorted single-bond geometry to one C(54) and one H(34) atom. The C(58)-H(34) bond length is 1.09 Å. In the fifty-third C site, C(59) is bonded in a distorted single-bond geometry to one C(55) and one H(35) atom. The C(59)-H(35) bond length is 1.09 Å. In the fifty-fourth C site, C(60) is bonded in a distorted single-bond geometry to one C(56) and one H(36) atom. The C(60)-H(36) bond length is 1.09 Å. In the fifty-fifth C site, C(61) is bonded in a distorted single-bond geometry to one C(65) and one H(37) atom. The C(61)-C(65) bond length is 1.39 Å. The C(61)-H(37) bond length is 1.09 Å. In the fifty-sixth C site, C(62) is bonded in a distorted single-bond geometry to one C(66) and one H(38) atom. The C(62)-C(66) bond length is 1.39 Å. The C(62)-H(38) bond length is 1.09 Å. In the fifty-seventh C site, C(63) is bonded in a distorted single-bond geometry to one C(67) and one H(39) atom. The C(63)-C(67) bond length is 1.39 Å. The C(63)-H(39) bond length is 1.09 Å. In the fifty-eighth C site, C(64) is bonded in a distorted single-bond geometry to one C(68) and one H(40) atom. The C(64)-C(68) bond length is 1.39 Å. The C(64)-H(40) bond length is 1.09 Å. In the fifty-ninth C site, C(65) is bonded in a distorted trigonal planar geometry to one C(61), one N(9), and one H(41) atom. The C(65)-N(9) bond length is 1.35 Å. The C(65)-H(41) bond length is 1.09 Å. In the sixtieth C site, C(66) is bonded in a distorted trigonal planar geometry to one C(62), one N(10), and one H(42) atom. The C(66)-N(10) bond length is 1.35 Å. The C(66)-H(42) bond length is 1.09 Å. In the sixty-first C site, C(67) is bonded in a distorted trigonal planar geometry to one C(63), one N(11), and one H(43) atom. The C(67)-N(11) bond length is 1.35 Å. The C(67)-H(43) bond length is 1.09 Å. In the sixty-second C site, C(68) is bonded in a distorted trigonal planar geometry to one C(64), one N(12), and one H(44) atom. The C(68)-N(12) bond length is 1.35 Å. The C(68)-H(44) bond length is 1.09 Å. In the sixty-third C site, C(69) is bonded in a distorted bent 120 degrees geometry to one C(53), one N(9), and one H(45) atom. The C(69)-N(9) bond length is 1.34 Å. The C(69)-H(45) bond length is 1.08 Å. In the sixty-fourth C site, C(70) is bonded in a distorted bent 120 degrees geometry to one C(54), one N(10), and one H(46) atom. The C(70)-N(10) bond length is 1.34 Å. The C(70)-H(46) bond length is 1.08 Å. In the sixty-fifth C site, C(71) is bonded in a distorted bent 120 degrees geometry to one C(55), one N(11), and one H(47) atom. The C(71)-N(11) bond length is 1.34 Å. The C(71)-H(47) bond length is 1.08 Å. In the sixty-sixth C site, C(72) is bonded in a distorted bent 120 degrees geometry to one C(56), one N(12), and one H(48) atom. The C(72)-N(12) bond length is 1.34 Å. The C(72)-H(48) bond length is 1.08 Å. In the sixty-seventh C site, C(73) is bonded in a distorted bent 120 degrees geometry to one C(77), one O(25), and one O(29) atom. The C(73)-C(77) bond length is 1.52 Å. The C(73)-O(25) bond length is 1.24 Å. The C(73)-O(29) bond length is 1.30 Å. In the sixty-eighth C site, C(74) is bonded in a distorted bent 120 degrees geometry to one C(78), one O(26), and one O(30) atom. The C(74)-C(78) bond length is 1.52 Å. The C(74)-O(26) bond length is 1.24 Å. The C(74)-O(30) bond length is 1.30 Å. In the sixty-ninth C site, C(75) is bonded in a distorted bent 120 degrees geometry to one C(79), one O(27), and one O(31) atom. The C(75)-C(79) bond length is 1.52 Å. The C(75)-O(27) bond length is 1.24 Å. The C(75)-O(31) bond length is 1.30 Å. In the seventieth C site, C(76) is bonded in a distorted bent 120 degrees geometry to one C(80), one O(28), and one O(32) atom. The C(76)-C(80) bond length is 1.52 Å. The C(76)-O(28) bond length is 1.24 Å. The C(76)-O(32) bond length is 1.29 Å. In the seventy-first C site, C(77) is bonded in a trigonal planar geometry to one C(73), one C(81), and one C(93) atom. The C(77)-C(81) bond length is 1.40 Å. The C(77)-C(93) bond length is 1.39 Å. In the seventy-second C site, C(78) is bonded in a trigonal planar geometry to one C(74), one C(82), and one C(94) atom. The C(78)-C(82) bond length is 1.40 Å. The C(78)-C(94) bond length is 1.40 Å. In the seventy-third C site, C(79) is bonded in a trigonal planar geometry to one C(75), one C(83), and one C(95) atom. The C(79)-C(83) bond length is 1.40 Å. The C(79)-C(95) bond length is 1.39 Å. In the seventy-fourth C site, C(80) is bonded in a trigonal planar geometry to one C(76), one C(84), and one C(96) atom. The C(80)-C(84) bond length is 1.40 Å. The C(80)-C(96) bond length is 1.40 Å. In the seventy-fifth C site, C(81) is bonded in a distorted single-bond geometry to one C(77) and one H(49) atom. The C(81)-H(49) bond length is 1.09 Å. In the seventy-sixth C site, C(82) is bonded in a distorted single-bond geometry to one C(78) and one H(50) atom. The C(82)-H(50) bond length is 1.09 Å. In the seventy-seventh C site, C(83) is bonded in a distorted single-bond geometry to one C(79) and one H(51) atom. The C(83)-H(51) bond length is 1.09 Å. In the seventy-eighth C site, C(84) is bonded in a distorted single-bond geometry to one C(80) and one H(52) atom. The C(84)-H(52) bond length is 1.09 Å. In the seventy-ninth C site, C(86) is bonded in a distorted single-bond geometry to one C(90) and one H(54) atom. The C(86)-C(90) bond length is 1.39 Å. The C(86)-H(54) bond length is 1.09 Å. In the eightieth C site, C(88) is bonded in a distorted single-bond geometry to one C(92) and one H(56) atom. The C(88)-C(92) bond length is 1.39 Å. The C(88)-H(56) bond length is 1.09 Å. In the eighty-first C site, C(89) is bonded in a distorted trigonal planar geometry to one N(13) and one H(57) atom. The C(89)-N(13) bond length is 1.35 Å. The C(89)-H(57) bond length is 1.09 Å. In the eighty-second C site, C(90) is bonded in a distorted trigonal planar geometry to one C(86), one N(14), and one H(58) atom. The C(90)-N(14) bond length is 1.35 Å. The C(90)-H(58) bond length is 1.09 Å. In the eighty-third C site, C(91) is bonded in a distorted trigonal planar geometry to one N(15) and one H(59) atom. The C(91)-N(15) bond length is 1.35 Å. The C(91)-H(59) bond length is 1.09 Å. In the eighty-fourth C site, C(92) is bonded in a distorted trigonal planar geometry to one C(88), one N(16), and one H(60) atom. The C(92)-N(16) bond length is 1.35 Å. The C(92)-H(60) bond length is 1.09 Å. In the eighty-fifth C site, C(93) is bonded in a distorted bent 120 degrees geometry to one C(77), one N(13), and one H(61) atom. The C(93)-N(13) bond length is 1.34 Å. The C(93)-H(61) bond length is 1.08 Å. In the eighty-sixth C site, C(94) is bonded in a distorted bent 120 degrees geometry to one C(78), one N(14), and one H(62) atom. The C(94)-N(14) bond length is 1.34 Å. The C(94)-H(62) bond length is 1.08 Å. In the eighty-seventh C site, C(95) is bonded in a distorted bent 120 degrees geometry to one C(79), one N(15), and one H(63) atom. The C(95)-N(15) bond length is 1.34 Å. The C(95)-H(63) bond length is 1.08 Å. In the eighty-eighth C site, C(96) is bonded in a distorted bent 120 degrees geometry to one C(80), one N(16), and one H(64) atom. The C(96)-N(16) bond length is 1.34 Å. The C(96)-H(64) bond length is 1.08 Å. There are sixteen inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(8), one C(17), and one C(21) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ni(7), one C(18), and one C(22) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ni(6), one C(19), and one C(23) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ni(5), one C(20), and one C(24) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Ni(3), one C(29), and one C(33) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Ni(4), one C(30), and one C(34) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Ni(1), one C(31), and one C(35) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Ni(2), one C(32), and one C(36) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Ni(7), one C(65), and one C(69) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Ni(8), one C(66), and one C(70) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Ni(5), one C(67), and one C(71) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Ni(6), one C(68), and one C(72) atom. In the thirteenth N site, N(13) is bonded in a trigonal planar geometry to one Ni(1), one C(89), and one C(93) atom. In the fourteenth N site, N(14) is bonded in a trigonal planar geometry to one Ni(2), one C(90), and one C(94) atom. In the fifteenth N site, N(15) is bonded in a trigonal planar geometry to one Ni(3), one C(91), and one C(95) atom. In the sixteenth N site, N(16) is bonded in a trigonal planar geometry to one Ni(4), one C(92), and one C(96) atom. There are fifty-five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the sixteenth H site, H(22) is bonded in a single-bond geometry to one C(30) atom. In the seventeenth H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the eighteenth H site, H(24) is bonded in a single-bond geometry to one C(32) atom. In the nineteenth H site, H(25) is bonded in a single-bond geometry to one C(33) atom. In the twentieth H site, H(26) is bonded in a single-bond geometry to one C(34) atom. In the twenty-first H site, H(27) is bonded in a single-bond geometry to one C(35) atom. In the twenty-second H site, H(28) is bonded in a single-bond geometry to one C(36) atom. In the twenty-third H site, H(29,31) is bonded in a single-bond geometry to one C(37) atom. In the twenty-fourth H site, H(30) is bonded in a single-bond geometry to one C(38) atom. In the twenty-fifth H site, H(32) is bonded in a single-bond geometry to one C(40) atom. In the twenty-sixth H site, H(33) is bonded in a single-bond geometry to one C(57) atom. In the twenty-seventh H site, H(34) is bonded in a single-bond geometry to one C(58) atom. In the twenty-eighth H site, H(35) is bonded in a single-bond geometry to one C(59) atom. In the twenty-ninth H site, H(36) is bonded in a single-bond geometry to one C(60) atom. In the thirtieth H site, H(37) is bonded in a single-bond geometry to one C(61) atom. In the thirty-first H site, H(38) is bonded in a single-bond geometry to one C(62) atom. In the thirty-second H site, H(39) is bonded in a single-bond geometry to one C(63) atom. In the thirty-third H site, H(40) is bonded in a single-bond geometry to one C(64) atom. In the thirty-fourth H site, H(41) is bonded in a single-bond geometry to one C(65) atom. In the thirty-fifth H site, H(42) is bonded in a single-bond geometry to one C(66) atom. In the thirty-sixth H site, H(43) is bonded in a single-bond geometry to one C(67) atom. In the thirty-seventh H site, H(44) is bonded in a single-bond geometry to one C(68) atom. In the thirty-eighth H site, H(45) is bonded in a single-bond geometry to one C(69) atom. In the thirty-ninth H site, H(46) is bonded in a single-bond geometry to one C(70) atom. In the fortieth H site, H(47) is bonded in a single-bond geometry to one C(71) atom. In the forty-first H site, H(48) is bonded in a single-bond geometry to one C(72) atom. In the forty-second H site, H(49) is bonded in a single-bond geometry to one C(81) atom. In the forty-third H site, H(50) is bonded in a single-bond geometry to one C(82) atom. In the forty-fourth H site, H(51) is bonded in a single-bond geometry to one C(83) atom. In the forty-fifth H site, H(52) is bonded in a single-bond geometry to one C(84) atom. In the forty-sixth H site, H(54) is bonded in a single-bond geometry to one C(86) atom. In the forty-seventh H site, H(56) is bonded in a single-bond geometry to one C(88) atom. In the forty-eighth H site, H(57) is bonded in a single-bond geometry to one C(89) atom. In the forty-ninth H site, H(58) is bonded in a single-bond geometry to one C(90) atom. In the fiftieth H site, H(59) is bonded in a single-bond geometry to one C(91) atom. In the fifty-first H site, H(60) is bonded in a single-bond geometry to one C(92) atom. In the fifty-second H site, H(61) is bonded in a single-bond geometry to one C(93) atom. In the fifty-third H site, H(62) is bonded in a single-bond geometry to one C(94) atom. In the fifty-fourth H site, H(63) is bonded in a single-bond geometry to one C(95) atom. In the fifty-fifth H site, H(64) is bonded in a single-bond geometry to one C(96) atom. There are thirty-six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ni(2) and one C(2) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ni(3) and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ni(4) and one C(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(45) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Ni(2) and one C(46) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Ni(3) and one C(47) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Ni(4) and one C(48) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Ni(5) and one C(45) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Ni(6) and one C(46) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Ni(7) and one C(47) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Ni(8) and one C(48) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Ni(5) and one C(49) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Ni(6) and one C(50) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Ni(7) and one C(51) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Ni(8) and one C(52) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(49) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Ni(2) and one C(50) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Ni(3) and one C(51) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Ni(4) and one C(52) atom. In the twenty-fifth O site, O(25) is bonded in a single-bond geometry to one C(73) atom. In the twenty-sixth O site, O(26) is bonded in a single-bond geometry to one C(74) atom. In the twenty-seventh O site, O(27) is bonded in a single-bond geometry to one C(75) atom. In the twenty-eighth O site, O(28) is bonded in a single-bond geometry to one C(76) atom. In the twenty-ninth O site, O(29) is bonded in a distorted bent 120 degrees geometry to one Ni(7) and one C(73) atom. In the thirtieth O site, O(30) is bonded in a distorted bent 120 degrees geometry to one Ni(8) and one C(74) atom. In the thirty-first O site, O(31) is bonded in a distorted bent 120 degrees geometry to one Ni(5) and one C(75) atom. In the thirty-second O site, O(32) is bonded in a distorted bent 120 degrees geometry to one Ni(6) and one C(76) atom. In the thirty-third O site, O(33) is bonded in a bent 120 degrees geometry to one Ni(1) and one Ni(5) atom. In the thirty-fourth O site, O(34) is bonded in a bent 120 degrees geometry to one Ni(2) and one Ni(6) atom. In the thirty-fifth O site, O(35) is bonded in a bent 120 degrees geometry to one Ni(3) and one Ni(7) atom. In the thirty-sixth O site, O(36) is bonded in a bent 120 degrees geometry to one Ni(4) and one Ni(8) atom. Linkers: 15 [O]C(=O)c1cccnc1. Metal clusters: 4 [Ni] ,2 O=[C]O[Ni@]12O[C]O[Ni@](O[C]=O)(O[C]O1)O2. The MOF has largest included sphere 3.62 A, density 1.58 g/cm3, surface area 3678.86 m2/g, accessible volume 0.21 cm3/g