CuC12NH8O4CuC14NH14O5(CH)3C3H2(C2O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules; two 2,3-dimethyl-1,3-butadiene molecules; eight dimethyl ether molecules; two CuC12NH8O4 clusters; and two CuC14NH14O5 clusters. In each CuC12NH8O4 cluster, Cu(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(3), one O(5), and one O(7) atom. The Cu(1)-N(1) bond length is 2.17 Å. The Cu(1)-O(1) bond length is 2.02 Å. The Cu(1)-O(3) bond length is 2.02 Å. The Cu(1)-O(5) bond length is 1.98 Å. The Cu(1)-O(7) bond length is 2.01 Å. There are twelve inequivalent C sites. In the first C site, C(15) is bonded in a distorted single-bond geometry to one C(5) and one H(5,6) atom. The C(15)-C(5) bond length is 1.40 Å. The C(15)-H(5,6) bond length is 1.09 Å. In the second C site, C(21,22) is bonded in a distorted single-bond geometry to one C(25,26) and one H(7,8) atom. The C(21,22)-C(25,26) bond length is 1.39 Å. The C(21,22)-H(7,8) bond length is 1.09 Å. In the third C site, C(25,26) is bonded in a distorted trigonal planar geometry to one C(21,22); one C(45,46); and one H(11,12) atom. The C(25,26)-C(45,46) bond length is 1.40 Å. The C(25,26)-H(11,12) bond length is 1.09 Å. In the fourth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(5), one C(59), and one H(19) atom. The C(41)-C(5) bond length is 1.40 Å. The C(41)-C(59) bond length is 1.39 Å. The C(41)-H(19) bond length is 1.09 Å. In the fifth C site, C(45,46) is bonded in a trigonal planar geometry to one C(1,2); one C(25,26); and one C(57,58) atom. The C(45,46)-C(1,2) bond length is 1.49 Å. The C(45,46)-C(57,58) bond length is 1.40 Å. In the sixth C site, C(57,58) is bonded in a distorted single-bond geometry to one C(45,46) and one H(31,32) atom. The C(57,58)-H(31,32) bond length is 1.09 Å. In the seventh C site, C(59) is bonded in a distorted single-bond geometry to one C(41) and one H(33,34) atom. The C(59)-H(33,34) bond length is 1.09 Å. In the eighth C site, C(61,62) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(35) atom. The C(61,62)-N(1) bond length is 1.34 Å. The C(61,62)-H(35) bond length is 1.09 Å. In the ninth C site, C(63,64) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(37) atom. The C(63,64)-N(1) bond length is 1.34 Å. The C(63,64)-H(37) bond length is 1.09 Å. In the tenth C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one C(45,46); one O(1); and one O(3) atom. The C(1,2)-O(1) bond length is 1.28 Å. The C(1,2)-O(3) bond length is 1.28 Å. In the eleventh C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(5), and one O(7) atom. The C(3)-C(5) bond length is 1.49 Å. The C(3)-O(5) bond length is 1.28 Å. The C(3)-O(7) bond length is 1.28 Å. In the twelfth C site, C(5) is bonded in a trigonal planar geometry to one C(15), one C(3), and one C(41) atom. N(1) is bonded in a trigonal planar geometry to one Cu(1); one C(61,62); and one C(63,64) atom. There are eight inequivalent H sites. In the first H site, H(5,6) is bonded in a single-bond geometry to one C(15) atom. In the second H site, H(7,8) is bonded in a single-bond geometry to one C(21,22) atom. In the third H site, H(11,12) is bonded in a single-bond geometry to one C(25,26) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(41) atom. In the fifth H site, H(31,32) is bonded in a single-bond geometry to one C(57,58) atom. In the sixth H site, H(33,34) is bonded in a single-bond geometry to one C(59) atom. In the seventh H site, H(35) is bonded in a single-bond geometry to one C(61,62) atom. In the eighth H site, H(37) is bonded in a single-bond geometry to one C(63,64) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1,2) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1,2) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. In each CuC14NH14O5 cluster, Cu(3) is bonded in a distorted square pyramidal geometry to one O(12), one O(14), one O(17), one O(21), and one O(9) atom. The Cu(3)-O(12) bond length is 1.99 Å. The Cu(3)-O(14) bond length is 2.01 Å. The Cu(3)-O(17) bond length is 1.98 Å. The Cu(3)-O(21) bond length is 2.27 Å. The Cu(3)-O(9) bond length is 1.99 Å. There are fourteen inequivalent C sites. In the first C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(39), one O(17), and one O(9) atom. The C(7)-C(39) bond length is 1.49 Å. The C(7)-O(17) bond length is 1.28 Å. The C(7)-O(9) bond length is 1.28 Å. In the second C site, C(71,72) is bonded to one N(3,4); one H(49,50); one H(51,52); and one H(53,54) atom to form corner-sharing CH3N tetrahedra. The C(71,72)-N(3,4) bond length is 1.46 Å. The C(71,72)-H(49,50) bond length is 1.09 Å. The C(71,72)-H(51,52) bond length is 1.10 Å. The C(71,72)-H(53,54) bond length is 1.10 Å. In the third C site, C(14) is bonded in a trigonal planar geometry to one C(20); one C(23,24); and one C(37,38) atom. The C(14)-C(20) bond length is 1.50 Å. The C(14)-C(23,24) bond length is 1.40 Å. The C(14)-C(37,38) bond length is 1.40 Å. In the fourth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(12), and one O(14) atom. The C(20)-O(12) bond length is 1.28 Å. The C(20)-O(14) bond length is 1.28 Å. In the fifth C site, C(23,24) is bonded in a distorted trigonal planar geometry to one C(13); one C(49,50); and one H(9,10) atom. The C(23,24)-C(13) bond length is 1.40 Å. The C(23,24)-C(49,50) bond length is 1.39 Å. The C(23,24)-H(9,10) bond length is 1.09 Å. In the sixth C site, C(27,28) is bonded in a distorted trigonal planar geometry to one C(35), one C(39), and one H(13) atom. The C(27,28)-C(35) bond length is 1.39 Å. The C(27,28)-C(39) bond length is 1.40 Å. The C(27,28)-H(13) bond length is 1.09 Å. In the seventh C site, C(35) is bonded in a distorted single-bond geometry to one C(27,28) and one H(15,16) atom. The C(35)-H(15,16) bond length is 1.09 Å. In the eighth C site, C(37,38) is bonded in a distorted trigonal planar geometry to one C(13), one C(43), and one H(17) atom. The C(37,38)-C(13) bond length is 1.40 Å. The C(37,38)-C(43) bond length is 1.39 Å. The C(37,38)-H(17) bond length is 1.09 Å. In the ninth C site, C(39) is bonded in a trigonal planar geometry to one C(27,28); one C(53,54); and one C(7) atom. The C(39)-C(53,54) bond length is 1.40 Å. In the tenth C site, C(44) is bonded in a distorted single-bond geometry to one C(37,38) and one H(21,22) atom. The C(44)-C(37,38) bond length is 1.39 Å. The C(44)-H(21,22) bond length is 1.09 Å. In the eleventh C site, C(49,50) is bonded in a distorted single-bond geometry to one C(23,24) and one H(25,26) atom. The C(49,50)-H(25,26) bond length is 1.09 Å. In the twelfth C site, C(53,54) is bonded in a distorted single-bond geometry to one C(39) and one H(27) atom. The C(53,54)-H(27) bond length is 1.09 Å. In the thirteenth C site, C(65) is bonded in a trigonal planar geometry to one N(3,4); one H(39,40); and one O(21) atom. The C(65)-N(3,4) bond length is 1.34 Å. The C(65)-H(39,40) bond length is 1.11 Å. The C(65)-O(21) bond length is 1.25 Å. In the fourteenth C site, C(69,70) is bonded to one N(3,4); one H(43,44); one H(45,46); and one H(47,48) atom to form corner-sharing CH3N tetrahedra. The C(69,70)-N(3,4) bond length is 1.45 Å. The C(69,70)-H(43,44) bond length is 1.10 Å. The C(69,70)-H(45,46) bond length is 1.10 Å. The C(69,70)-H(47,48) bond length is 1.10 Å. N(3,4) is bonded in a trigonal planar geometry to one C(65); one C(69,70); and one C(71,72) atom. There are fourteen inequivalent H sites. In the first H site, H(9,10) is bonded in a single-bond geometry to one C(23,24) atom. In the second H site, H(13) is bonded in a single-bond geometry to one C(27,28) atom. In the third H site, H(15,16) is bonded in a single-bond geometry to one C(35) atom. In the fourth H site, H(18) is bonded in a single-bond geometry to one C(37,38) atom. The H(18)-C(37,38) bond length is 1.09 Å. In the fifth H site, H(21,22) is bonded in a single-bond geometry to one C(43) atom. The H(21,22)-C(43) bond length is 1.09 Å. In the sixth H site, H(25,26) is bonded in a single-bond geometry to one C(49,50) atom. In the seventh H site, H(27) is bonded in a single-bond geometry to one C(53,54) atom. In the eighth H site, H(39,40) is bonded in a single-bond geometry to one C(65) atom. In the ninth H site, H(43,44) is bonded in a single-bond geometry to one C(69,70) atom. In the tenth H site, H(45,46) is bonded in a single-bond geometry to one C(69,70) atom. In the eleventh H site, H(47,48) is bonded in a single-bond geometry to one C(69,70) atom. In the twelfth H site, H(49,50) is bonded in a single-bond geometry to one C(71,72) atom. In the thirteenth H site, H(51,52) is bonded in a single-bond geometry to one C(71,72) atom. In the fourteenth H site, H(53,54) is bonded in a single-bond geometry to one C(71,72) atom. There are five inequivalent O sites. In the first O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(7) atom. In the second O site, O(12) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(20) atom. In the third O site, O(14) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(20) atom. In the fourth O site, O(17) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(7) atom. In the fifth O site, O(21) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(65) atom. Linkers: 8 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4 ,4 [Cu]. The MOF has largest included sphere 6.70 A, density 1.17 g/cm3, surface area 4530.57 m2/g, accessible volume 0.38 cm3/g