AgC7H15S(NO2)2CH2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and four AgC7H15S(NO2)2 clusters. In each AgC7H15S(NO2)2 cluster, Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one O(2), and one O(4) atom. The Ag(1)-N(1) bond length is 2.25 Å. The Ag(1)-N(2) bond length is 2.27 Å. The Ag(1)-O(2) bond length is 2.73 Å. The Ag(1)-O(4) bond length is 2.64 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(2), and one H(3) atom. The C(1)-N(1) bond length is 1.49 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.11 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1); one H(4); and one H(5,11) atom. The C(2)-N(1) bond length is 1.49 Å. The C(2)-H(4) bond length is 1.11 Å. The C(2)-H(5,11) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(6), and one H(7) atom. The C(3)-N(2) bond length is 1.48 Å. The C(3)-H(6) bond length is 1.11 Å. The C(3)-H(7) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(8), and one H(9) atom. The C(4)-N(2) bond length is 1.48 Å. The C(4)-H(8) bond length is 1.10 Å. The C(4)-H(9) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(1); one H(10); and one H(5,11) atom. The C(5)-N(1) bond length is 1.49 Å. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(5,11) bond length is 1.11 Å. In the sixth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(14), and one H(15) atom. The C(7)-N(2) bond length is 1.49 Å. The C(7)-H(14) bond length is 1.10 Å. The C(7)-H(15) bond length is 1.10 Å. In the seventh C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one H(16), one H(17), and one O(4) atom. The C(8)-H(16) bond length is 1.10 Å. The C(8)-H(17) bond length is 1.10 Å. The C(8)-O(4) bond length is 1.44 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Ag(1), one C(1), one C(2), and one C(5) atom to form corner-sharing NAgC3 tetrahedra. In the second N site, N(2) is bonded to one Ag(1), one C(3), one C(4), and one C(7) atom to form corner-sharing NAgC3 tetrahedra. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(4) atom. The H(1)-O(4) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5,11) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(7) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(7) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(8) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(8) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(2) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.47 Å. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted water-like geometry to one Ag(1), one C(8), and one H(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Ag(1) and one S(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one S(1) atom. Linkers: 4 [O]S([O])([O])CCN1CC[N]CC1. Metal clusters: 4 O=S(=O)=O.OCC[N][Ag]. The MOF has largest included sphere 3.41 A, density 1.64 g/cm3, surface area 3643.22 m2/g, accessible volume 0.18 cm3/g