(CH)2PbC16H8(NO2)2(CF3)4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, sixteen trifluoromethane molecules, and four PbC16H8(NO2)2 clusters. In each PbC16H8(NO2)2 cluster, Pb(1) is bonded in a 6-coordinate geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. Both Pb(1)-N(1) bond lengths are 2.55 Å. Both Pb(1)-O(1) bond lengths are 2.71 Å. Both Pb(1)-O(2) bond lengths are 2.75 Å. There are eight inequivalent C sites. In the first C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(6)-N(1) bond length is 1.33 Å. The C(6)-H(2) bond length is 1.09 Å. In the second C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-H(4) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one O(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-O(1) bond length is 1.27 Å. In the fourth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(8) atom. The C(9)-C(10) bond length is 1.42 Å. The C(9)-C(11) bond length is 1.43 Å. In the fifth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(1) bond length is 1.09 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(10), one C(9), and one N(1) atom. The C(10)-C(10) bond length is 1.44 Å. The C(10)-N(1) bond length is 1.36 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(11)-H(5) bond length is 1.09 Å. In the eighth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one O(2) atom. The C(3)-O(2) bond length is 1.26 Å. N(1) is bonded in a distorted bent 120 degrees geometry to one Pb(1), one C(10), and one C(6) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Pb(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Pb(1) and one C(3) atom. Linkers: 4 O=C([CH]C(=O)C(F)(F)F)C(F)(F)F. Metal clusters: 2 [Pb]. The MOF has largest included sphere 1.81 A, density 2.26 g/cm3, surface area 3266.28 m2/g, accessible volume 0.07 cm3/g