CdC23N2H15O5(CH)5C5H4O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules, two 3-methoxy-2-methylprop-1-ene molecules, and one CdC23N2H15O5 cluster. In the CdC23N2H15O5 cluster, Cd(1) is bonded to one N(1), one N(2), one O(1), one O(6), and two equivalent O(4) atoms to form distorted edge-sharing CdN2O4 octahedra. The Cd(1)-N(1) bond length is 2.34 Å. The Cd(1)-N(2) bond length is 2.34 Å. The Cd(1)-O(1) bond length is 2.26 Å. The Cd(1)-O(6) bond length is 2.41 Å. There is one shorter (2.35 Å) and one longer (2.38 Å) Cd(1)-O(4) bond length. There are twenty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(8) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-H(8) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(15) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-C(15) bond length is 1.48 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(9) atom. The C(13)-H(9) bond length is 1.09 Å. In the eighth C site, C(15) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(20) atom. The C(15)-C(16) bond length is 1.42 Å. The C(15)-C(20) bond length is 1.41 Å. In the ninth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.51 Å. In the tenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(17)-H(11) bond length is 1.09 Å. In the eleventh C site, C(20) is bonded in a distorted single-bond geometry to one C(15) and one H(14) atom. The C(20)-H(14) bond length is 1.09 Å. In the twelfth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(4), and one O(5) atom. The C(21)-O(4) bond length is 1.29 Å. The C(21)-O(5) bond length is 1.25 Å. In the thirteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one N(1) and one H(15) atom. The C(22)-N(1) bond length is 1.33 Å. The C(22)-H(15) bond length is 1.09 Å. In the fourteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(17) atom. The C(24)-C(25) bond length is 1.41 Å. The C(24)-H(17) bond length is 1.09 Å. In the fifteenth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(33) atom. The C(25)-C(26) bond length is 1.43 Å. The C(25)-C(33) bond length is 1.42 Å. In the sixteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(18) atom. The C(26)-H(18) bond length is 1.09 Å. In the seventeenth C site, C(27) is bonded in a distorted single-bond geometry to one C(28) and one H(19) atom. The C(27)-C(28) bond length is 1.43 Å. The C(27)-H(19) bond length is 1.09 Å. In the eighteenth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(32) atom. The C(28)-C(29) bond length is 1.41 Å. The C(28)-C(32) bond length is 1.42 Å. In the nineteenth C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(20) atom. The C(29)-H(20) bond length is 1.09 Å. In the twentieth C site, C(30) is bonded in a distorted single-bond geometry to one C(31) and one H(21) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-H(21) bond length is 1.09 Å. In the twenty-first C site, C(31) is bonded in a distorted trigonal planar geometry to one C(30), one N(2), and one H(22) atom. The C(31)-N(2) bond length is 1.33 Å. The C(31)-H(22) bond length is 1.09 Å. In the twenty-second C site, C(32) is bonded in a distorted trigonal planar geometry to one C(28), one C(33), and one N(2) atom. The C(32)-C(33) bond length is 1.45 Å. The C(32)-N(2) bond length is 1.36 Å. In the twenty-third C site, C(33) is bonded in a distorted trigonal planar geometry to one C(25), one C(32), and one N(1) atom. The C(33)-N(1) bond length is 1.36 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(22), and one C(33) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(31), and one C(32) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(30) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(23) is bonded in a distorted single-bond geometry to one O(2) and one O(6) atom. The H(23)-O(2) bond length is 1.62 Å. The H(23)-O(6) bond length is 1.01 Å. In the fifteenth H site, H(24) is bonded in a distorted single-bond geometry to one O(5) and one O(6) atom. The H(24)-O(5) bond length is 1.67 Å. The H(24)-O(6) bond length is 1.00 Å. There are five inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 120 degrees geometry to one C(21) and one H(24) atom. In the second O site, O(6) is bonded in a water-like geometry to one Cd(1), one H(23), and one H(24) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(1) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one C(1) and one H(23) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(21) atom. Linkers: 2 [O]C(=O)c1ccc(OCc2ccc(-c3ccccc3C([O])=O)cc2)cc1 ,2 [O]C(=O)c1ccc(OCc2ccc(-c3cc[c]cc3C([O])=O)cc2)cc1. Metal clusters: 1 O.O.O=[C]O[Cd]O[C]=O.O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 2.26 A, density 1.65 g/cm3, surface area 4379.61 m2/g, accessible volume 0.10 cm3/g