CuC14N2H12O11(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CuC14N2H12O11 clusters. In each CuC14N2H12O11 cluster, Cu(1) is bonded in a square pyramidal geometry to one O(10), one O(11), one O(5), one O(6), and one O(9) atom. The Cu(1)-O(10) bond length is 2.01 Å. The Cu(1)-O(11) bond length is 2.27 Å. The Cu(1)-O(5) bond length is 1.97 Å. The Cu(1)-O(6) bond length is 1.97 Å. The Cu(1)-O(9) bond length is 2.01 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(5) atom. The C(1)-C(3) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(5) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one H(6) atom. The C(2)-C(4) bond length is 1.38 Å. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(6) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(5) atom. The C(3)-C(11) bond length is 1.47 Å. The C(3)-C(5) bond length is 1.42 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(2), and one C(6) atom. The C(4)-C(12) bond length is 1.47 Å. The C(4)-C(6) bond length is 1.42 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(7) atom. The C(5)-H(7) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(8) atom. The C(6)-H(8) bond length is 1.09 Å. In the seventh C site, C(9,10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(5) atom. The C(9,10)-N(1) bond length is 1.41 Å. The C(9,10)-O(5) bond length is 1.26 Å. In the eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(11)-O(1) bond length is 1.36 Å. The C(11)-O(3) bond length is 1.23 Å. In the ninth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(4) atom. The C(12)-O(2) bond length is 1.36 Å. The C(12)-O(4) bond length is 1.23 Å. In the tenth C site, C(13,14) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent H(11,12,13,14) atoms. The C(13,14)-N(1) bond length is 1.46 Å. There is one shorter (1.09 Å) and one longer (1.10 Å) C(13,14)-H(11,12,13,14) bond length. In the eleventh C site, C(15,16) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(9) atom. The C(15,16)-O(7) bond length is 1.25 Å. The C(15,16)-O(9) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1); one C(13,14); and one C(9,10) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(13,14); one C(2); and one C(9,10) atom. The N(2)-C(13,14) bond length is 1.46 Å. The N(2)-C(9,10) bond length is 1.41 Å. There are eight inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one O(1) atom. The H(1,2)-O(1) bond length is 0.98 Å. In the second H site, H(3) is bonded in a single-bond geometry to one O(11) atom. The H(3)-O(11) bond length is 0.99 Å. In the third H site, H(4) is bonded in a single-bond geometry to one O(11) atom. The H(4)-O(11) bond length is 0.99 Å. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(11,12,13,14) is bonded in a single-bond geometry to one C(13,14) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(11) and one H(1,2) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(12) and one H(1,2) atom. The O(2)-H(1,2) bond length is 0.98 Å. In the third O site, O(3) is bonded in a single-bond geometry to one C(11) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(12) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(9,10) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(9,10) atom. The O(6)-C(9,10) bond length is 1.26 Å. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(15,16) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(15,16) atom. The O(8)-C(15,16) bond length is 1.25 Å. In the ninth O site, O(9) is bonded in a water-like geometry to one Cu(1) and one C(15,16) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Cu(1) and one C(15,16) atom. The O(10)-C(15,16) bond length is 1.28 Å. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Cu(1), one H(3), and one H(4) atom. Linkers: 4 [O]C(=O)Cn1cc(C(=O)O)ccc1=O. Metal clusters: 2 O.[O][Cu]([O])(O[C]=O)O[C]=O. The MOF has largest included sphere 2.72 A, density 1.69 g/cm3, surface area 4339.21 m2/g, accessible volume 0.15 cm3/g