WCu3C30N10H25S3OBr is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two WCu3C30N10H25S3OBr clusters. W(1) is bonded in a distorted single-bond geometry to one S(1), one S(2), one S(3), and one O(1) atom. The W(1)-S(1) bond length is 2.28 Å. The W(1)-S(2) bond length is 2.27 Å. The W(1)-S(3) bond length is 2.28 Å. The W(1)-O(1) bond length is 1.76 Å. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one N(10), one N(5), one S(1), and one S(3) atom to form distorted CuS2N2 tetrahedra that share  a cornercorner with one Cu(3)S2BrN tetrahedra and  a cornercorner with one Cu(2)S2N2 tetrahedra. The Cu(1)-N(10) bond length is 2.03 Å. The Cu(1)-N(5) bond length is 2.06 Å. The Cu(1)-S(1) bond length is 2.29 Å. The Cu(1)-S(3) bond length is 2.29 Å. In the second Cu site, Cu(2) is bonded to one N(3), one N(7), one S(1), and one S(2) atom to form distorted CuS2N2 tetrahedra that share  a cornercorner with one Cu(3)S2BrN tetrahedra and  a cornercorner with one Cu(1)S2N2 tetrahedra. The Cu(2)-N(3) bond length is 2.02 Å. The Cu(2)-N(7) bond length is 2.02 Å. The Cu(2)-S(1) bond length is 2.27 Å. The Cu(2)-S(2) bond length is 2.28 Å. In the third Cu site, Cu(3) is bonded to one N(1), one S(2), one S(3), and one Br(1) atom to form distorted corner-sharing CuS2BrN tetrahedra. The Cu(3)-N(1) bond length is 2.02 Å. The Cu(3)-S(2) bond length is 2.28 Å. The Cu(3)-S(3) bond length is 2.31 Å. The Cu(3)-Br(1) bond length is 2.52 Å. There are thirty inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.37 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(2), and one H(2) atom. The C(2)-C(17) bond length is 1.37 Å. The C(2)-N(2) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(30), one C(4), and one N(2) atom. The C(3)-C(30) bond length is 1.40 Å. The C(3)-C(4) bond length is 1.40 Å. The C(3)-N(2) bond length is 1.42 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3,25) atom. The C(4)-H(3,25) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(28), one N(3), and one H(4) atom. The C(5)-C(28) bond length is 1.37 Å. The C(5)-N(3) bond length is 1.38 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(5) atom. The C(6)-N(3) bond length is 1.32 Å. The C(6)-N(4) bond length is 1.37 Å. The C(6)-H(5) bond length is 1.08 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(20), one C(27), and one N(4) atom. The C(7)-C(20) bond length is 1.40 Å. The C(7)-C(27) bond length is 1.40 Å. The C(7)-N(4) bond length is 1.42 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(15), one N(10), and one H(6) atom. The C(8)-C(15) bond length is 1.37 Å. The C(8)-N(10) bond length is 1.39 Å. The C(8)-H(6) bond length is 1.08 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(7), and one H(7) atom. The C(9)-C(22) bond length is 1.37 Å. The C(9)-N(7) bond length is 1.39 Å. The C(9)-H(7) bond length is 1.08 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(26), and one N(6) atom. The C(11)-C(26) bond length is 1.40 Å. The C(11)-N(6) bond length is 1.42 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(16), one C(21), and one N(8) atom. The C(12)-C(16) bond length is 1.40 Å. The C(12)-C(21) bond length is 1.40 Å. The C(12)-N(8) bond length is 1.42 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(19), one C(29), and one N(9) atom. The C(13)-C(19) bond length is 1.40 Å. The C(13)-C(29) bond length is 1.40 Å. The C(13)-N(9) bond length is 1.42 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one N(5), one N(9), and one H(9) atom. The C(14)-N(5) bond length is 1.33 Å. The C(14)-N(9) bond length is 1.37 Å. The C(14)-H(9) bond length is 1.08 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(6), and one H(10) atom. The C(15)-N(6) bond length is 1.39 Å. The C(15)-H(10) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(16)-H(11) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(12) atom. The C(17)-N(1) bond length is 1.38 Å. The C(17)-H(12) bond length is 1.08 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one N(10), one N(6), and one H(13) atom. The C(18)-N(10) bond length is 1.33 Å. The C(18)-N(6) bond length is 1.37 Å. The C(18)-H(13) bond length is 1.08 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(13) and one H(14) atom. The C(19)-H(14) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(7) and one H(15,22) atom. The C(20)-H(15,22) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(12) and one H(16) atom. The C(21)-H(16) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(8), and one H(17) atom. The C(22)-N(8) bond length is 1.39 Å. The C(22)-H(17) bond length is 1.08 Å. In the twenty-third C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(25), one N(5), and one H(18) atom. The C(23)-C(25) bond length is 1.37 Å. The C(23)-N(5) bond length is 1.38 Å. The C(23)-H(18) bond length is 1.08 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(19) atom. The C(24)-N(7) bond length is 1.33 Å. The C(24)-N(8) bond length is 1.37 Å. The C(24)-H(19) bond length is 1.08 Å. In the twenty-fifth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(23), one N(9), and one H(20) atom. The C(25)-N(9) bond length is 1.39 Å. The C(25)-H(20) bond length is 1.08 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(11) and one H(21) atom. The C(26)-H(21) bond length is 1.09 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(7) and one H(15,22) atom. The C(27)-H(15,22) bond length is 1.09 Å. In the twenty-eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(4), and one H(23) atom. The C(28)-N(4) bond length is 1.39 Å. The C(28)-H(23) bond length is 1.09 Å. In the twenty-ninth C site, C(29) is bonded in a distorted single-bond geometry to one C(13) and one H(24) atom. The C(29)-H(24) bond length is 1.09 Å. In the thirtieth C site, C(30) is bonded in a distorted single-bond geometry to one C(3) and one H(3,25) atom. The C(30)-H(3,25) bond length is 1.09 Å. There are ten inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cu(2), one C(5), and one C(6) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one C(28), one C(6), and one C(7) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one Cu(1), one C(14), and one C(23) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(18) atom. In the sixth N site, N(7) is bonded in a trigonal planar geometry to one Cu(2), one C(24), and one C(9) atom. In the seventh N site, N(8) is bonded in a trigonal planar geometry to one C(12), one C(22), and one C(24) atom. In the eighth N site, N(9) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(25) atom. In the ninth N site, N(10) is bonded in a trigonal planar geometry to one Cu(1), one C(18), and one C(8) atom. In the tenth N site, N(1) is bonded in a trigonal planar geometry to one Cu(3), one C(1), and one C(17) atom. There are twenty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3,25) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(15,22) is bonded in a single-bond geometry to one C(20) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(22) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(23) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(24) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the twenty-second H site, H(23) is bonded in a single-bond geometry to one C(28) atom. In the twenty-third H site, H(24) is bonded in a single-bond geometry to one C(29) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one W(1), one Cu(1), and one Cu(2) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one W(1), one Cu(2), and one Cu(3) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to one W(1), one Cu(1), and one Cu(3) atom. O(1) is bonded in a single-bond geometry to one W(1) atom. Br(1) is bonded in a single-bond geometry to one Cu(3) atom. Linkers: 4 c1cn(-c2ccc(-n3ccnc3)cc2)cn1. Metal clusters: 6 [Cu] ,2 [W]. The MOF has largest included sphere 3.19 A, density 2.11 g/cm3, surface area 3374.44 m2/g, accessible volume 0.13 cm3/g