Cd2C8H10S(N2O5)2 crystallizes in the triclinic P-1 space group. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one N(1), one O(1), one O(2), one O(4), one O(5), and one O(7) atom to form CdNO5 octahedra that share corners with two equivalent Cd(2)NO5 octahedra and  a cornercorner with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 65-69°. The Cd(1)-N(1) bond length is 2.25 Å. The Cd(1)-O(1) bond length is 2.46 Å. The Cd(1)-O(2) bond length is 2.32 Å. The Cd(1)-O(4) bond length is 2.31 Å. The Cd(1)-O(5) bond length is 2.25 Å. The Cd(1)-O(7) bond length is 2.40 Å. In the second Cd site, Cd(2) is bonded to one N(3), one O(1), one O(3), one O(5), one O(6), and one O(9) atom to form CdNO5 octahedra that share corners with two equivalent Cd(1)NO5 octahedra and  a cornercorner with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 65-69°. The Cd(2)-N(3) bond length is 2.27 Å. The Cd(2)-O(1) bond length is 2.27 Å. The Cd(2)-O(3) bond length is 2.35 Å. The Cd(2)-O(5) bond length is 2.41 Å. The Cd(2)-O(6) bond length is 2.31 Å. The Cd(2)-O(9) bond length is 2.37 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(4) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(4) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one N(1) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-N(1) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(1) atom. The C(3)-N(2) bond length is 1.37 Å. The C(3)-H(1) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(2) atom. The C(4)-N(1) bond length is 1.32 Å. The C(4)-N(2) bond length is 1.36 Å. The C(4)-H(2) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(5), and one O(6) atom. The C(5)-C(6) bond length is 1.48 Å. The C(5)-O(5) bond length is 1.29 Å. The C(5)-O(6) bond length is 1.26 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one N(3) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-N(3) bond length is 1.38 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(4), and one H(3) atom. The C(7)-N(4) bond length is 1.37 Å. The C(7)-H(3) bond length is 1.08 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(4) atom. The C(8)-N(3) bond length is 1.33 Å. The C(8)-N(4) bond length is 1.36 Å. The C(8)-H(4) bond length is 1.08 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(2), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(3), one C(4), and one H(5) atom. The N(2)-H(5) bond length is 1.04 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(6), and one C(8) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(7), one C(8), and one H(6) atom. The N(4)-H(6) bond length is 1.04 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one N(2) and one O(8) atom. The H(5)-O(8) bond length is 1.68 Å. In the sixth H site, H(6) is bonded in a distorted single-bond geometry to one N(4) and one O(9) atom. The H(6)-O(9) bond length is 1.72 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(10) and one O(2) atom. The H(7)-O(10) bond length is 1.70 Å. The H(7)-O(2) bond length is 1.00 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(2) and one O(8) atom. The H(8)-O(2) bond length is 1.00 Å. The H(8)-O(8) bond length is 1.70 Å. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(10) and one O(3) atom. The H(9)-O(10) bond length is 1.75 Å. The H(9)-O(3) bond length is 1.00 Å. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(3) and one O(7) atom. The H(10)-O(3) bond length is 1.00 Å. The H(10)-O(7) bond length is 1.75 Å. S(1) is bonded to one O(10), one O(7), one O(8), and one O(9) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(1)NO5 octahedra and  a cornercorner with one Cd(2)NO5 octahedra. The corner-sharing octahedral tilt angles range from 50-56°. The S(1)-O(10) bond length is 1.49 Å. The S(1)-O(7) bond length is 1.50 Å. The S(1)-O(8) bond length is 1.48 Å. The S(1)-O(9) bond length is 1.50 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(2), and one C(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1), one H(7), and one H(8) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(2), one H(10), and one H(9) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Cd(1), one Cd(2), and one C(5) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Cd(2) and one C(5) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Cd(1), one H(10), and one S(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one H(5), one H(8), and one S(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Cd(2), one H(6), and one S(1) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one H(7), one H(9), and one S(1) atom. Linkers: 4 [O]C(=O)c1c[nH]cn1 ,2 [O]S([O])(=O)=O. Metal clusters: 4 [Cd]. The MOF has largest included sphere 1.98 A, density 2.53 g/cm3, surface area 2941.03 m2/g, accessible volume 0.07 cm3/g