ZnC23H15(NO2)2(CH)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and two ZnC23H15(NO2)2 clusters. In each ZnC23H15(NO2)2 cluster, Zn(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Zn(1)-N(1) bond length is 2.10 Å. The Zn(1)-N(2) bond length is 2.10 Å. The Zn(1)-O(1) bond length is 1.98 Å. The Zn(1)-O(2) bond length is 1.98 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.31 Å. The C(1)-O(3) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(4) atom. The C(2)-C(4) bond length is 1.49 Å. The C(2)-O(2) bond length is 1.31 Å. The C(2)-O(4) bond length is 1.26 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(21) atom. The C(3)-C(11) bond length is 1.40 Å. The C(3)-C(21) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(2), and one C(22) atom. The C(4)-C(12) bond length is 1.40 Å. The C(4)-C(22) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(1) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one H(2) atom. The C(6)-C(8) bond length is 1.40 Å. The C(6)-N(2) bond length is 1.34 Å. The C(6)-H(2) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(8)-H(4) bond length is 1.09 Å. In the eighth C site, C(9,10) is bonded in a distorted single-bond geometry to one C(23) and one H(5,6) atom. The C(9,10)-C(23) bond length is 1.40 Å. The C(9,10)-H(5,6) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(3) and one H(7,8) atom. The C(11)-H(7,8) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(4) and one H(7,8) atom. The C(12)-H(7,8) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(15) and one H(9,10) atom. The C(13)-C(15) bond length is 1.41 Å. The C(13)-H(9,10) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(16) and one H(9,10) atom. The C(14)-C(16) bond length is 1.41 Å. The C(14)-H(9,10) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(19) atom. The C(15)-C(17) bond length is 1.46 Å. The C(15)-C(19) bond length is 1.41 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(20) atom. The C(16)-C(18) bond length is 1.46 Å. The C(16)-C(20) bond length is 1.41 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one H(11,12) atom. The C(17)-H(11,12) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(16) and one H(11,12) atom. The C(18)-H(11,12) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(15), one C(21), and one H(13) atom. The C(19)-C(21) bond length is 1.39 Å. The C(19)-H(13) bond length is 1.09 Å. In the eighteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(16), one C(22), and one H(14) atom. The C(20)-C(22) bond length is 1.39 Å. The C(20)-H(14) bond length is 1.09 Å. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(19), one C(3), and one H(15) atom. The C(21)-H(15) bond length is 1.09 Å. In the twentieth C site, C(22) is bonded in a distorted single-bond geometry to one C(20), one C(4), and one H(16) atom. The C(22)-H(16) bond length is 1.09 Å. In the twenty-first C site, C(23) is bonded in a distorted trigonal planar geometry to one C(24); one C(9,10); and one N(1) atom. The C(23)-C(24) bond length is 1.48 Å. The C(23)-N(1) bond length is 1.35 Å. In the twenty-second C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23); one C(9,10); and one N(2) atom. The C(24)-C(9,10) bond length is 1.40 Å. The C(24)-N(2) bond length is 1.35 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(23), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(24), and one C(6) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(9,10) atom. In the fifth H site, H(7,8) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(22) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(2) atom. Linkers: 2 [O]C(=O)c1ccc(/C=C/c2ccc(C([O])=O)cc2)cc1 ,2 c1ccc(-c2ccccn2)nc1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 8.83 A, density 0.79 g/cm3, surface area 5158.96 m2/g, accessible volume 0.80 cm3/g