Dy2C8PNH13O16(CH2)3 crystallizes in the triclinic P-1 space group. The structure consists of six 02329_fluka molecules inside a Dy2C8PNH13O16 framework. In the Dy2C8PNH13O16 framework, there are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(14), one O(15), one O(3), one O(4), one O(6), and one O(9) atom. The Dy(1)-O(1) bond length is 2.32 Å. The Dy(1)-O(11) bond length is 2.43 Å. The Dy(1)-O(14) bond length is 2.36 Å. The Dy(1)-O(15) bond length is 2.44 Å. The Dy(1)-O(3) bond length is 2.25 Å. The Dy(1)-O(4) bond length is 2.38 Å. The Dy(1)-O(6) bond length is 2.47 Å. The Dy(1)-O(9) bond length is 2.38 Å. In the second Dy site, Dy(2) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(13), one O(16), one O(2), one O(5), one O(7), and one O(8) atom. The Dy(2)-O(10) bond length is 2.32 Å. The Dy(2)-O(12) bond length is 2.41 Å. The Dy(2)-O(13) bond length is 2.38 Å. The Dy(2)-O(16) bond length is 2.42 Å. The Dy(2)-O(2) bond length is 2.26 Å. The Dy(2)-O(5) bond length is 2.41 Å. The Dy(2)-O(7) bond length is 2.34 Å. The Dy(2)-O(8) bond length is 2.47 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted tetrahedral geometry to one P(1), one N(1), one H(2), and one H(3) atom. The C(1)-P(1) bond length is 1.85 Å. The C(1)-N(1) bond length is 1.49 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. In the second C site, C(2) is bonded in a 3-coordinate geometry to one N(1), one H(4), and one H(5) atom. The C(2)-N(1) bond length is 1.51 Å. The C(2)-H(4) bond length is 1.10 Å. The C(2)-H(5) bond length is 1.10 Å. In the third C site, C(6) is bonded in a 3-coordinate geometry to one N(1), one H(12), and one H(13) atom. The C(6)-N(1) bond length is 1.51 Å. The C(6)-H(12) bond length is 1.10 Å. The C(6)-H(13) bond length is 1.10 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(7)-O(4) bond length is 1.26 Å. The C(7)-O(5) bond length is 1.27 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(8)-O(6) bond length is 1.26 Å. The C(8)-O(7) bond length is 1.27 Å. In the sixth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(8) and one O(9) atom. The C(9)-O(8) bond length is 1.27 Å. The C(9)-O(9) bond length is 1.26 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(11) atom. The C(10)-O(10) bond length is 1.27 Å. The C(10)-O(11) bond length is 1.26 Å. In the eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(12) and one O(13) atom. The C(11)-O(12) bond length is 1.26 Å. The C(11)-O(13) bond length is 1.27 Å. P(1) is bonded to one C(1), one O(1), one O(2), and one O(3) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one N(1)HC3 tetrahedra. The P(1)-O(1) bond length is 1.53 Å. The P(1)-O(2) bond length is 1.53 Å. The P(1)-O(3) bond length is 1.54 Å. N(1) is bonded to one C(1), one C(2), one C(6), and one H(1) atom to form NHC3 tetrahedra that share  a cornercorner with one P(1)CO3 tetrahedra. The N(1)-H(1) bond length is 1.05 Å. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one O(14) atom. The H(14)-O(14) bond length is 0.98 Å. In the ninth H site, H(15) is bonded in a single-bond geometry to one O(14) atom. The H(15)-O(14) bond length is 0.99 Å. In the tenth H site, H(16) is bonded in a single-bond geometry to one O(15) atom. The H(16)-O(15) bond length is 0.98 Å. In the eleventh H site, H(17) is bonded in a single-bond geometry to one O(15) atom. The H(17)-O(15) bond length is 0.98 Å. In the twelfth H site, H(18) is bonded in a single-bond geometry to one O(16) and one O(3) atom. The H(18)-O(16) bond length is 1.00 Å. The H(18)-O(3) bond length is 1.75 Å. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one O(16) atom. The H(19)-O(16) bond length is 0.99 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Dy(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Dy(2) and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Dy(1), one P(1), and one H(18) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Dy(1) and one C(7) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Dy(2) and one C(7) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Dy(1) and one C(8) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Dy(2) and one C(8) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Dy(2) and one C(9) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Dy(1) and one C(9) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Dy(2) and one C(10) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Dy(1) and one C(10) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Dy(2) and one C(11) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Dy(2) and one C(11) atom. In the fourteenth O site, O(14) is bonded in a distorted water-like geometry to one Dy(1), one H(14), and one H(15) atom. In the fifteenth O site, O(15) is bonded in a distorted water-like geometry to one Dy(1), one H(16), and one H(17) atom. In the sixteenth O site, O(16) is bonded in a distorted water-like geometry to one Dy(2), one H(18), and one H(19) atom. Linkers: 4 [O]C(=O)C([O])=O. Metal clusters: 4 [Dy]. The MOF has largest included sphere 2.22 A, density 2.60 g/cm3, surface area 2464.87 m2/g, accessible volume 0.07 cm3/g