(CH2)4ZnC6H8(N3Cl)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two ZnC6H8(N3Cl)2 clusters. In each ZnC6H8(N3Cl)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one Cl(1), and one Cl(2) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-N(2) bond length is 2.04 Å. The Zn(1)-Cl(1) bond length is 2.24 Å. The Zn(1)-Cl(2) bond length is 2.24 Å. There are three inequivalent C sites. In the first C site, C(1,2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1,2)-N(1) bond length is 1.34 Å. The C(1,2)-N(3) bond length is 1.34 Å. The C(1,2)-H(1) bond length is 1.08 Å. In the second C site, C(3,4) is bonded in a trigonal planar geometry to one N(1), one N(5), and one H(3) atom. The C(3,4)-N(1) bond length is 1.37 Å. The C(3,4)-N(5) bond length is 1.32 Å. The C(3,4)-H(3) bond length is 1.08 Å. In the third C site, C(5,6) is bonded in a distorted trigonal non-coplanar geometry to one N(3); one H(5,6); and one H(7,8) atom. The C(5,6)-N(3) bond length is 1.46 Å. The C(5,6)-H(5,6) bond length is 1.10 Å. The C(5,6)-H(7,8) bond length is 1.10 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1); one C(1,2); and one C(3,4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1); one C(1,2); and one C(3,4) atom. The N(2)-C(1,2) bond length is 1.34 Å. The N(2)-C(3,4) bond length is 1.37 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(1,2); one C(5,6); and one N(5) atom. The N(3)-N(5) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(1,2); one C(5,6); and one N(6) atom. The N(4)-C(1,2) bond length is 1.34 Å. The N(4)-C(5,6) bond length is 1.46 Å. The N(4)-N(6) bond length is 1.36 Å. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(3,4) and one N(3) atom. In the sixth N site, N(6) is bonded in a distorted water-like geometry to one C(3,4) and one N(4) atom. The N(6)-C(3,4) bond length is 1.32 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1,2) atom. The H(2)-C(1,2) bond length is 1.08 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(3,4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3,4) atom. The H(4)-C(3,4) bond length is 1.08 Å. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(5,6) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(5,6) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 2 [N]N(C=[N])CCCCCCN1[CH]N=C[N]1 ,2 [c]1ncn(CCCCCCN2[CH]N=C[N]2)n1 ,2 [N]N(C=[N])CCCCCCn1cncn1 ,1 [CH]1N=C[N]N1CCCCCCn1cncn1. Metal clusters: 2 Cl[Zn]Cl. The MOF has largest included sphere 1.96 A, density 1.62 g/cm3, surface area 5318.32 m2/g, accessible volume 0.14 cm3/g