CuC26H18(NO2)2(CH)4(CF3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two trifluoromethane molecules, and one CuC26H18(NO2)2 cluster. In the CuC26H18(NO2)2 cluster, Cu(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. Both Cu(1)-N(1) bond lengths are 2.43 Å. Both Cu(1)-O(1) bond lengths are 2.03 Å. Both Cu(1)-O(2) bond lengths are 1.94 Å. There are thirteen inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one O(1) atom. The C(2)-O(1) bond length is 1.28 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one O(2) atom. The C(4)-C(5) bond length is 1.49 Å. The C(4)-O(2) bond length is 1.28 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(6) atom. The C(5)-C(10) bond length is 1.41 Å. The C(5)-C(6) bond length is 1.41 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(2) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(2) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(3) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(3) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(8)-H(4) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(5) and one H(6) atom. The C(10)-H(6) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(1), and one H(7) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(1) bond length is 1.34 Å. The C(11)-H(7) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(8) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-H(8) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(16) bond length is 1.46 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(9) atom. The C(14)-H(9) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a distorted trigonal planar geometry to one N(1) and one H(10) atom. The C(15)-N(1) bond length is 1.35 Å. The C(15)-H(10) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(16)-H(11) bond length is 1.09 Å. N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(11), and one C(15) atom. There are nine inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(4) atom. Linkers: 2 O=C([CH]C(=O)C(F)(F)F)c1ccccc1 ,1 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 1 [Cu]. The MOF has largest included sphere 2.30 A, density 1.62 g/cm3, surface area 4825.02 m2/g, accessible volume 0.15 cm3/g