UC5NH6O7(CH2)2CH3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four 02329_fluka molecules, and two UC5NH6O7 clusters. In each UC5NH6O7 cluster, U(1) is bonded in a distorted pentagonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. The U(1)-O(1) bond length is 1.82 Å. The U(1)-O(2) bond length is 1.81 Å. The U(1)-O(3) bond length is 2.34 Å. The U(1)-O(4) bond length is 2.29 Å. The U(1)-O(5) bond length is 2.50 Å. The U(1)-O(6) bond length is 2.45 Å. The U(1)-O(7) bond length is 2.35 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(1)-O(3) bond length is 1.27 Å. The C(1)-O(4) bond length is 1.27 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(4)-O(5) bond length is 1.28 Å. The C(4)-O(6) bond length is 1.28 Å. In the third C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(7) atom. The C(6)-N(1) bond length is 1.33 Å. The C(6)-O(7) bond length is 1.28 Å. In the fourth C site, C(7) is bonded to one N(1), one H(10), one H(8), and one H(9) atom to form corner-sharing CH3N tetrahedra. The C(7)-N(1) bond length is 1.46 Å. The C(7)-H(10) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.09 Å. The C(7)-H(9) bond length is 1.10 Å. In the fifth C site, C(8) is bonded to one N(1), one H(11), one H(12), and one H(13) atom to form corner-sharing CH3N tetrahedra. The C(8)-N(1) bond length is 1.46 Å. The C(8)-H(11) bond length is 1.09 Å. The C(8)-H(12) bond length is 1.10 Å. The C(8)-H(13) bond length is 1.10 Å. N(1) is bonded in a trigonal planar geometry to one C(6), one C(7), and one C(8) atom. There are six inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(8) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one U(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one U(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one U(1) and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one U(1) and one C(4) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one U(1) and one C(4) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one U(1) and one C(6) atom. Linkers: 4 [O]C(=O)CCC([O])=O. Metal clusters: 4 [U]. RCSR code: fes. The MOF has largest included sphere 2.08 A, density 2.62 g/cm3, surface area 3009.20 m2/g, accessible volume 0.10 cm3/g