CdC24N4H16O5(CH)2 crystallizes in the triclinic P-1 space group. The structure consists of eight 02329_fluka molecules inside a CdC24N4H16O5 framework. In the CdC24N4H16O5 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 7-coordinate geometry to one N(2), one N(7), one O(3), one O(6), one O(8), and two equivalent O(1) atoms. The Cd(1)-N(2) bond length is 2.34 Å. The Cd(1)-N(7) bond length is 2.26 Å. The Cd(1)-O(3) bond length is 2.53 Å. The Cd(1)-O(6) bond length is 2.68 Å. The Cd(1)-O(8) bond length is 2.26 Å. There is one shorter (2.39 Å) and one longer (2.71 Å) Cd(1)-O(1) bond length. In the second Cd site, Cd(2) is bonded in a 7-coordinate geometry to one N(1), one N(8), one O(4), one O(5), one O(7), and two equivalent O(2) atoms. The Cd(2)-N(1) bond length is 2.34 Å. The Cd(2)-N(8) bond length is 2.26 Å. The Cd(2)-O(4) bond length is 2.53 Å. The Cd(2)-O(5) bond length is 2.68 Å. The Cd(2)-O(7) bond length is 2.26 Å. There is one shorter (2.40 Å) and one longer (2.71 Å) Cd(2)-O(2) bond length. There are forty-four inequivalent C sites. In the first C site, C(1,2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(5) atom. The C(1,2)-N(1) bond length is 1.33 Å. The C(1,2)-N(3) bond length is 1.36 Å. The C(1,2)-H(5) bond length is 1.08 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(5,6); one N(1); and one H(7,8) atom. The C(3)-C(5,6) bond length is 1.39 Å. The C(3)-N(1) bond length is 1.38 Å. The C(3)-H(7,8) bond length is 1.08 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5,6); one N(2); and one H(7,8) atom. The C(4)-C(5,6) bond length is 1.39 Å. The C(4)-N(2) bond length is 1.38 Å. The C(4)-H(7,8) bond length is 1.08 Å. In the fourth C site, C(5,6) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one N(3) atom. The C(5,6)-C(7) bond length is 1.46 Å. The C(5,6)-N(3) bond length is 1.39 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(17); one C(5,6); and one C(9,10) atom. The C(7)-C(17) bond length is 1.40 Å. The C(7)-C(9,10) bond length is 1.41 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(18); one C(5,6); and one C(9,10) atom. The C(8)-C(18) bond length is 1.40 Å. The C(8)-C(5,6) bond length is 1.46 Å. The C(8)-C(9,10) bond length is 1.41 Å. In the seventh C site, C(9,10) is bonded in a distorted single-bond geometry to one C(7) and one H(9,10) atom. The C(9,10)-H(9,10) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(15) and one H(13,14) atom. The C(13)-C(15) bond length is 1.41 Å. The C(13)-H(13,14) bond length is 1.09 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(16) and one H(13,14) atom. The C(14)-C(16) bond length is 1.41 Å. The C(14)-H(13,14) bond length is 1.09 Å. In the tenth C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(19) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-C(19) bond length is 1.46 Å. In the eleventh C site, C(16) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(20) atom. The C(16)-C(18) bond length is 1.40 Å. The C(16)-C(20) bond length is 1.46 Å. In the twelfth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(15); one C(7); and one H(15,16) atom. The C(17)-H(15,16) bond length is 1.09 Å. In the thirteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(16); one C(8); and one H(15,16) atom. The C(18)-H(15,16) bond length is 1.09 Å. In the fourteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(15), one C(21), and one N(5) atom. The C(19)-C(21) bond length is 1.39 Å. The C(19)-N(5) bond length is 1.38 Å. In the fifteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(16), one C(22), and one N(6) atom. The C(20)-C(22) bond length is 1.39 Å. The C(20)-N(6) bond length is 1.38 Å. In the sixteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(7), and one H(17) atom. The C(21)-N(7) bond length is 1.37 Å. The C(21)-H(17) bond length is 1.08 Å. In the seventeenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(8), and one H(18) atom. The C(22)-N(8) bond length is 1.37 Å. The C(22)-H(18) bond length is 1.08 Å. In the eighteenth C site, C(23) is bonded in a trigonal planar geometry to one N(5), one N(7), and one H(19) atom. The C(23)-N(5) bond length is 1.35 Å. The C(23)-N(7) bond length is 1.34 Å. The C(23)-H(19) bond length is 1.08 Å. In the nineteenth C site, C(24) is bonded in a trigonal planar geometry to one N(6), one N(8), and one H(20) atom. The C(24)-N(6) bond length is 1.35 Å. The C(24)-N(8) bond length is 1.34 Å. The C(24)-H(20) bond length is 1.08 Å. In the twentieth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(1), and one O(3) atom. The C(25)-C(27) bond length is 1.49 Å. The C(25)-O(1) bond length is 1.28 Å. The C(25)-O(3) bond length is 1.28 Å. In the twenty-first C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(2), and one O(4) atom. The C(26)-C(28) bond length is 1.49 Å. The C(26)-O(2) bond length is 1.28 Å. The C(26)-O(4) bond length is 1.28 Å. In the twenty-second C site, C(27) is bonded in a trigonal planar geometry to one C(25), one C(29), and one C(37) atom. The C(27)-C(29) bond length is 1.40 Å. The C(27)-C(37) bond length is 1.40 Å. In the twenty-third C site, C(28) is bonded in a trigonal planar geometry to one C(26), one C(30), and one C(38) atom. The C(28)-C(30) bond length is 1.40 Å. The C(28)-C(38) bond length is 1.40 Å. In the twenty-fourth C site, C(29) is bonded in a distorted single-bond geometry to one C(27), one C(31), and one H(21) atom. The C(29)-C(31) bond length is 1.39 Å. The C(29)-H(21) bond length is 1.09 Å. In the twenty-fifth C site, C(30) is bonded in a distorted single-bond geometry to one C(28), one C(32), and one H(22) atom. The C(30)-C(32) bond length is 1.39 Å. The C(30)-H(22) bond length is 1.09 Å. In the twenty-sixth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(29), one C(33), and one H(23) atom. The C(31)-C(33) bond length is 1.40 Å. The C(31)-H(23) bond length is 1.09 Å. In the twenty-seventh C site, C(32) is bonded in a distorted trigonal planar geometry to one C(30), one C(34), and one H(24) atom. The C(32)-C(34) bond length is 1.40 Å. The C(32)-H(24) bond length is 1.09 Å. In the twenty-eighth C site, C(33) is bonded in a distorted single-bond geometry to one C(31) and one O(9) atom. The C(33)-O(9) bond length is 1.38 Å. In the twenty-ninth C site, C(34) is bonded in a distorted single-bond geometry to one C(32) and one O(10) atom. The C(34)-O(10) bond length is 1.38 Å. In the thirtieth C site, C(37) is bonded in a distorted single-bond geometry to one C(27) and one H(27,28) atom. The C(37)-H(27,28) bond length is 1.09 Å. In the thirty-first C site, C(38) is bonded in a distorted single-bond geometry to one C(28) and one H(27,28) atom. The C(38)-H(27,28) bond length is 1.09 Å. In the thirty-second C site, C(39) is bonded in a distorted single-bond geometry to one C(41) and one O(9) atom. The C(39)-C(41) bond length is 1.39 Å. The C(39)-O(9) bond length is 1.39 Å. In the thirty-third C site, C(40) is bonded in a distorted single-bond geometry to one C(42) and one O(10) atom. The C(40)-C(42) bond length is 1.39 Å. The C(40)-O(10) bond length is 1.40 Å. In the thirty-fourth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(39), one C(43), and one H(29) atom. The C(41)-C(43) bond length is 1.39 Å. The C(41)-H(29) bond length is 1.09 Å. In the thirty-fifth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(40), one C(44), and one H(30) atom. The C(42)-C(44) bond length is 1.39 Å. The C(42)-H(30) bond length is 1.09 Å. In the thirty-sixth C site, C(43) is bonded in a distorted trigonal planar geometry to one C(41), one C(45), and one H(31) atom. The C(43)-C(45) bond length is 1.40 Å. The C(43)-H(31) bond length is 1.09 Å. In the thirty-seventh C site, C(44) is bonded in a distorted trigonal planar geometry to one C(42), one C(46), and one H(32) atom. The C(44)-C(46) bond length is 1.40 Å. The C(44)-H(32) bond length is 1.09 Å. In the thirty-eighth C site, C(45) is bonded in a trigonal planar geometry to one C(43), one C(47), and one C(51) atom. The C(45)-C(47) bond length is 1.40 Å. The C(45)-C(51) bond length is 1.50 Å. In the thirty-ninth C site, C(46) is bonded in a trigonal planar geometry to one C(44), one C(48), and one C(52) atom. The C(46)-C(48) bond length is 1.40 Å. The C(46)-C(52) bond length is 1.50 Å. In the fortieth C site, C(47) is bonded in a distorted trigonal planar geometry to one C(45); one C(49,50); and one H(33,34) atom. The C(47)-C(49,50) bond length is 1.39 Å. The C(47)-H(33,34) bond length is 1.09 Å. In the forty-first C site, C(48) is bonded in a distorted trigonal planar geometry to one C(46); one C(49,50); and one H(33,34) atom. The C(48)-C(49,50) bond length is 1.39 Å. The C(48)-H(33,34) bond length is 1.09 Å. In the forty-second C site, C(49,50) is bonded in a distorted single-bond geometry to one C(47) and one H(35,36) atom. The C(49,50)-H(35,36) bond length is 1.09 Å. In the forty-third C site, C(51) is bonded in a bent 120 degrees geometry to one C(45), one O(5), and one O(7) atom. The C(51)-O(5) bond length is 1.26 Å. The C(51)-O(7) bond length is 1.29 Å. In the forty-fourth C site, C(52) is bonded in a bent 120 degrees geometry to one C(46), one O(6), and one O(8) atom. The C(52)-O(6) bond length is 1.26 Å. The C(52)-O(8) bond length is 1.29 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(2); one C(1,2); and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1); one C(1,2); and one C(4) atom. The N(2)-C(1,2) bond length is 1.33 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1,2); one C(5,6); and one H(1,2) atom. The N(3)-H(1,2) bond length is 1.01 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1,2); one C(5,6); and one H(1,2) atom. The N(4)-C(1,2) bond length is 1.36 Å. The N(4)-C(5,6) bond length is 1.39 Å. The N(4)-H(1,2) bond length is 1.01 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(19), one C(23), and one H(3) atom. The N(5)-H(3) bond length is 1.04 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(20), one C(24), and one H(4) atom. The N(6)-H(4) bond length is 1.04 Å. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Cd(1), one C(21), and one C(23) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Cd(2), one C(22), and one C(24) atom. There are twenty-four inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(3) is bonded in a distorted linear geometry to one N(5) and one O(4) atom. The H(3)-O(4) bond length is 1.69 Å. In the third H site, H(4) is bonded in a distorted linear geometry to one N(6) and one O(3) atom. The H(4)-O(3) bond length is 1.68 Å. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(1,2) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(1,2) atom. The H(6)-C(1,2) bond length is 1.08 Å. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(9,10) atom. In the eighth H site, H(13,14) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(15,16) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(30) atom. In the sixteenth H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the seventeenth H site, H(24) is bonded in a single-bond geometry to one C(32) atom. In the eighteenth H site, H(27,28) is bonded in a single-bond geometry to one C(37) atom. In the nineteenth H site, H(29) is bonded in a single-bond geometry to one C(41) atom. In the twentieth H site, H(30) is bonded in a single-bond geometry to one C(42) atom. In the twenty-first H site, H(31) is bonded in a single-bond geometry to one C(43) atom. In the twenty-second H site, H(32) is bonded in a single-bond geometry to one C(44) atom. In the twenty-third H site, H(33,34) is bonded in a single-bond geometry to one C(47) atom. In the twenty-fourth H site, H(35,36) is bonded in a single-bond geometry to one C(49,50) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(25) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Cd(2) and one C(26) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Cd(1), one C(25), and one H(4) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(2), one C(26), and one H(3) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Cd(2) and one C(51) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Cd(1) and one C(52) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Cd(2) and one C(51) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Cd(1) and one C(52) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one C(33) and one C(39) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one C(34) and one C(40) atom. Linkers: 4 c1cc(-c2cnc[nH]2)cc(-c2cnc[nH]2)c1 ,4 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 O=[C]O[Cd]1O[C]O1.O=[C]O[Cd]1O[C]O1. RCSR code: sql. The MOF has largest included sphere 4.12 A, density 1.43 g/cm3, surface area 4393.43 m2/g, accessible volume 0.29 cm3/g