CdC14N5H9O4(CH2)2(CH)2 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, eight 02329_fluka molecules, and two CdC14N5H9O4 clusters. In each CdC14N5H9O4 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(4), one O(1), one O(3), and two equivalent O(4) atoms. The Cd(1)-N(1) bond length is 2.36 Å. The Cd(1)-N(4) bond length is 2.31 Å. The Cd(1)-O(1) bond length is 2.22 Å. The Cd(1)-O(3) bond length is 2.32 Å. There is one shorter (2.42 Å) and one longer (2.61 Å) Cd(1)-O(4) bond length. There are fourteen inequivalent C sites. In the first C site, C(17) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(17)-O(3) bond length is 1.27 Å. The C(17)-O(4) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(2)-O(1) bond length is 1.30 Å. The C(2)-O(2) bond length is 1.26 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. The C(3)-N(1) bond length is 1.36 Å. The C(3)-N(2) bond length is 1.35 Å. The C(3)-N(3) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(12), one C(5), and one N(3) atom. The C(4)-C(12) bond length is 1.48 Å. The C(4)-C(5) bond length is 1.41 Å. The C(4)-N(3) bond length is 1.33 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(5) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(5) bond length is 1.08 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(1) atom. The C(6)-C(7) bond length is 1.49 Å. The C(6)-N(1) bond length is 1.35 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(4) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(4) bond length is 1.35 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(8) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(4), and one H(9) atom. The C(11)-N(4) bond length is 1.34 Å. The C(11)-H(9) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one C(4), and one N(5) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-N(5) bond length is 1.35 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(13)-H(10) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(12) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one N(5), and one H(13) atom. The C(16)-N(5) bond length is 1.34 Å. The C(16)-H(13) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(3), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(3), one H(1), and one H(2) atom. The N(2)-H(1) bond length is 1.01 Å. The N(2)-H(2) bond length is 1.02 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(3) and one C(4) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(7) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(12) and one C(16) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cd(1) and one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(1) and one C(17) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(17) atom. Linkers: 4 [O]C(=O)CCC([O])=O. Metal clusters: 2 O=[C]O[Cd]1O[C]O[Cd](O[C]=O)O[C]O1. The MOF has largest included sphere 3.37 A, density 1.71 g/cm3, surface area 4263.31 m2/g, accessible volume 0.11 cm3/g