CH2CH3AgC6N5H4O3Cl crystallizes in the monoclinic Cc space group. The structure consists of eight 02329_fluka molecules and eight 02329_fluka molecules inside a AgC6N5H4O3Cl framework. In the AgC6N5H4O3Cl framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(4), one N(8), and one O(3) atom. The Ag(1)-N(1) bond length is 2.40 Å. The Ag(1)-N(4) bond length is 2.33 Å. The Ag(1)-N(8) bond length is 2.25 Å. The Ag(1)-O(3) bond length is 2.45 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one N(2), one N(3), one N(7), and one O(4) atom. The Ag(2)-N(2) bond length is 2.41 Å. The Ag(2)-N(3) bond length is 2.32 Å. The Ag(2)-N(7) bond length is 2.24 Å. The Ag(2)-O(4) bond length is 2.46 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-N(3) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(4), and one H(2) atom. The C(2)-N(2) bond length is 1.35 Å. The C(2)-N(4) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(5), one N(3), and one N(9) atom. The C(3)-C(5) bond length is 1.42 Å. The C(3)-N(3) bond length is 1.34 Å. The C(3)-N(9) bond length is 1.37 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(6), one N(10), and one N(4) atom. The C(4)-C(6) bond length is 1.42 Å. The C(4)-N(10) bond length is 1.37 Å. The C(4)-N(4) bond length is 1.34 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one N(7) atom. The C(5)-C(7) bond length is 1.39 Å. The C(5)-N(7) bond length is 1.38 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(4), one C(8), and one N(8) atom. The C(6)-C(8) bond length is 1.39 Å. The C(6)-N(8) bond length is 1.38 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one Cl(1) atom. The C(7)-N(1) bond length is 1.34 Å. The C(7)-Cl(1) bond length is 1.71 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(6), one N(2), and one Cl(2) atom. The C(8)-N(2) bond length is 1.34 Å. The C(8)-Cl(2) bond length is 1.71 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(3) atom. The C(9)-N(7) bond length is 1.33 Å. The C(9)-N(9) bond length is 1.37 Å. The C(9)-H(3) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one N(10), one N(8), and one H(4) atom. The C(10)-N(10) bond length is 1.37 Å. The C(10)-N(8) bond length is 1.33 Å. The C(10)-H(4) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(9), one H(5), and one H(7) atom. The C(11)-N(9) bond length is 1.46 Å. The C(11)-H(5) bond length is 1.10 Å. The C(11)-H(7) bond length is 1.10 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one N(10), one H(6), and one H(8) atom. The C(12)-N(10) bond length is 1.47 Å. The C(12)-H(6) bond length is 1.10 Å. The C(12)-H(8) bond length is 1.10 Å. There are ten inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(7) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(2), and one C(8) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(1), and one C(3) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(2), and one C(4) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(5) atom. The N(5)-O(1) bond length is 1.27 Å. The N(5)-O(3) bond length is 1.28 Å. The N(5)-O(5) bond length is 1.26 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(6) atom. The N(6)-O(2) bond length is 1.27 Å. The N(6)-O(4) bond length is 1.28 Å. The N(6)-O(6) bond length is 1.26 Å. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(5), and one C(9) atom. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(10), and one C(6) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(9) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(4) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(6) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one N(5) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one N(6) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(6) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(7) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(8) atom. Linkers: 4 CCCn1cnc2c1[N]C=N[C]2Cl. Metal clusters: 4 O=[N+]([O-])O[Ag]. The MOF has largest included sphere 3.11 A, density 1.98 g/cm3, surface area 3655.84 m2/g, accessible volume 0.10 cm3/g