Cu5C12H10(N3O8)2(CH)2(CH2)2(H2O)2 crystallizes in the monoclinic P2_1 space group. The structure consists of four 02329_fluka molecules, four 02329_fluka molecules, and four water molecules inside a Cu5C12H10(N3O8)2 framework. In the Cu5C12H10(N3O8)2 framework, there are five inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square co-planar geometry to one N(3), one N(4), one O(10), and one O(9) atom. The Cu(1)-N(3) bond length is 1.96 Å. The Cu(1)-N(4) bond length is 1.96 Å. The Cu(1)-O(10) bond length is 2.05 Å. The Cu(1)-O(9) bond length is 2.05 Å. In the second Cu site, Cu(2) is bonded in a square pyramidal geometry to one N(2), one O(12), one O(14), one O(15), and one O(5) atom. The Cu(2)-N(2) bond length is 2.00 Å. The Cu(2)-O(12) bond length is 2.02 Å. The Cu(2)-O(14) bond length is 1.92 Å. The Cu(2)-O(15) bond length is 2.24 Å. The Cu(2)-O(5) bond length is 1.99 Å. In the third Cu site, Cu(3) is bonded in a square pyramidal geometry to one N(1), one O(11), one O(13), one O(16), and one O(6) atom. The Cu(3)-N(1) bond length is 2.00 Å. The Cu(3)-O(11) bond length is 2.02 Å. The Cu(3)-O(13) bond length is 1.93 Å. The Cu(3)-O(16) bond length is 2.24 Å. The Cu(3)-O(6) bond length is 1.98 Å. In the fourth Cu site, Cu(4) is bonded in a 6-coordinate geometry to one N(5), one O(1), one O(13), one O(15), one O(3), and one O(7) atom. The Cu(4)-N(5) bond length is 1.94 Å. The Cu(4)-O(1) bond length is 2.54 Å. The Cu(4)-O(13) bond length is 1.92 Å. The Cu(4)-O(15) bond length is 2.63 Å. The Cu(4)-O(3) bond length is 2.00 Å. The Cu(4)-O(7) bond length is 1.94 Å. In the fifth Cu site, Cu(5) is bonded in a 6-coordinate geometry to one N(6), one O(14), one O(16), one O(2), one O(4), and one O(8) atom. The Cu(5)-N(6) bond length is 1.94 Å. The Cu(5)-O(14) bond length is 1.92 Å. The Cu(5)-O(16) bond length is 2.63 Å. The Cu(5)-O(2) bond length is 2.54 Å. The Cu(5)-O(4) bond length is 2.00 Å. The Cu(5)-O(8) bond length is 1.94 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(7) atom. The C(1)-O(5) bond length is 1.27 Å. The C(1)-O(7) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(8) atom. The C(2)-O(6) bond length is 1.27 Å. The C(2)-O(8) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(9) atom. The C(3)-O(11) bond length is 1.27 Å. The C(3)-O(9) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(12) atom. The C(4)-O(10) bond length is 1.28 Å. The C(4)-O(12) bond length is 1.27 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(3), one N(5), and one H(9) atom. The C(5)-N(3) bond length is 1.35 Å. The C(5)-N(5) bond length is 1.33 Å. The C(5)-H(9) bond length is 1.08 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(10) atom. The C(6)-N(4) bond length is 1.35 Å. The C(6)-N(6) bond length is 1.33 Å. The C(6)-H(10) bond length is 1.08 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(11) atom. The C(7)-N(1) bond length is 1.33 Å. The C(7)-N(3) bond length is 1.36 Å. The C(7)-H(11) bond length is 1.08 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(2), one N(4), and one H(12) atom. The C(8)-N(2) bond length is 1.33 Å. The C(8)-N(4) bond length is 1.36 Å. The C(8)-H(12) bond length is 1.08 Å. In the ninth C site, C(9) is bonded in a bent 120 degrees geometry to one O(15) and one O(3) atom. The C(9)-O(15) bond length is 1.26 Å. The C(9)-O(3) bond length is 1.30 Å. In the tenth C site, C(10) is bonded in a bent 120 degrees geometry to one O(16) and one O(4) atom. The C(10)-O(16) bond length is 1.26 Å. The C(10)-O(4) bond length is 1.30 Å. In the eleventh C site, C(13) is bonded in a distorted water-like geometry to one H(15) and one O(13) atom. The C(13)-H(15) bond length is 1.11 Å. The C(13)-O(13) bond length is 1.41 Å. In the twelfth C site, C(14) is bonded in a distorted water-like geometry to one H(16) and one O(14) atom. The C(14)-H(16) bond length is 1.11 Å. The C(14)-O(14) bond length is 1.41 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(3), one C(7), and one N(5) atom. The N(1)-N(5) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(8), and one N(6) atom. The N(2)-N(6) bond length is 1.36 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(5), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(6), and one C(8) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cu(4), one C(5), and one N(1) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cu(5), one C(6), and one N(2) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. The H(3)-O(1) bond length is 0.97 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.97 Å. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(14) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(4), one H(1), and one H(3) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cu(5), one H(2), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cu(4) and one C(9) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cu(5) and one C(10) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(1) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(5) and one C(2) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(3) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(3) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(4) atom. In the thirteenth O site, O(13) is bonded in a trigonal planar geometry to one Cu(3), one Cu(4), and one C(13) atom. In the fourteenth O site, O(14) is bonded in a trigonal planar geometry to one Cu(2), one Cu(5), and one C(14) atom. In the fifteenth O site, O(15) is bonded in a 2-coordinate geometry to one Cu(2), one Cu(4), and one C(9) atom. In the sixteenth O site, O(16) is bonded in a 2-coordinate geometry to one Cu(3), one Cu(5), and one C(10) atom. Linkers: 2 [O]C(=O)/C=C/C([O])=O ,2 [O]C(=O)C[C@@H]([O])C([O])=O ,4 C1=NN=C[N]1 ,2 [O]C(=O)C[C@H]([O])C([O])=O. Metal clusters: 10 [Cu]. The MOF has largest included sphere 2.97 A, density 2.02 g/cm3, surface area 3379.87 m2/g, accessible volume 0.18 cm3/g