(ZnC13N3H9O5)2(CH2)3(CH3)2 crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of twelve 02329_fluka molecules and eight 02329_fluka molecules inside a ZnC13N3H9O5 framework. In the ZnC13N3H9O5 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(6), one O(2), one O(4), one O(6), and one O(9) atom. The Zn(1)-N(6) bond length is 2.02 Å. The Zn(1)-O(2) bond length is 2.07 Å. The Zn(1)-O(4) bond length is 2.09 Å. The Zn(1)-O(6) bond length is 2.06 Å. The Zn(1)-O(9) bond length is 2.07 Å. In the second Zn site, Zn(2) is bonded in a trigonal bipyramidal geometry to one N(4), one O(1), one O(10), one O(3), and one O(7) atom. The Zn(2)-N(4) bond length is 2.02 Å. The Zn(2)-O(1) bond length is 2.07 Å. The Zn(2)-O(10) bond length is 2.06 Å. The Zn(2)-O(3) bond length is 2.06 Å. The Zn(2)-O(7) bond length is 2.10 Å. There are twenty-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(5) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(8) atom. The C(2)-C(13) bond length is 1.50 Å. The C(2)-C(8) bond length is 1.40 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(31) atom. The C(3)-C(11) bond length is 1.39 Å. The C(3)-C(14) bond length is 1.40 Å. The C(3)-C(31) bond length is 1.50 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(10), one C(8), and one C(9) atom. The C(4)-C(10) bond length is 1.40 Å. The C(4)-C(8) bond length is 1.40 Å. The C(4)-C(9) bond length is 1.50 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(1), one C(10), and one N(2) atom. The C(5)-C(10) bond length is 1.39 Å. The C(5)-N(2) bond length is 1.44 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(21) atom. The C(6)-C(11) bond length is 1.40 Å. The C(6)-C(12) bond length is 1.40 Å. The C(6)-C(21) bond length is 1.50 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one N(3) atom. The C(7)-C(12) bond length is 1.40 Å. The C(7)-C(14) bond length is 1.39 Å. The C(7)-N(3) bond length is 1.44 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(2) atom. The C(8)-H(2) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(9)-O(1) bond length is 1.27 Å. The C(9)-O(2) bond length is 1.27 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(4), one C(5), and one H(3) atom. The C(10)-H(3) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(3), one C(6), and one H(4) atom. The C(11)-H(4) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(6), one C(7), and one H(5) atom. The C(12)-H(5) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(13)-O(3) bond length is 1.27 Å. The C(13)-O(4) bond length is 1.27 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(6) atom. The C(14)-H(6) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(24), one N(1), and one H(7) atom. The C(15)-C(24) bond length is 1.37 Å. The C(15)-N(1) bond length is 1.39 Å. The C(15)-H(7) bond length is 1.08 Å. In the sixteenth C site, C(16) is bonded in a 3-coordinate geometry to one N(1), one H(8), and one H(9) atom. The C(16)-N(1) bond length is 1.46 Å. The C(16)-H(8) bond length is 1.10 Å. The C(16)-H(9) bond length is 1.10 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(23), one N(1), and one N(4) atom. The C(17)-C(23) bond length is 1.49 Å. The C(17)-N(1) bond length is 1.37 Å. The C(17)-N(4) bond length is 1.34 Å. In the eighteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(6), and one O(7) atom. The C(21)-O(6) bond length is 1.27 Å. The C(21)-O(7) bond length is 1.27 Å. In the nineteenth C site, C(23) is bonded in a distorted water-like geometry to one C(17), one H(19), and one H(20) atom. The C(23)-H(19) bond length is 1.10 Å. The C(23)-H(20) bond length is 1.10 Å. In the twentieth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(15), one N(4), and one H(21) atom. The C(24)-N(4) bond length is 1.38 Å. The C(24)-H(21) bond length is 1.08 Å. In the twenty-first C site, C(25) is bonded in a distorted trigonal non-coplanar geometry to one N(5), one H(22), and one H(23) atom. The C(25)-N(5) bond length is 1.46 Å. The C(25)-H(22) bond length is 1.10 Å. The C(25)-H(23) bond length is 1.10 Å. In the twenty-second C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(29), one N(5), and one H(24) atom. The C(26)-C(29) bond length is 1.37 Å. The C(26)-N(5) bond length is 1.39 Å. The C(26)-H(24) bond length is 1.08 Å. In the twenty-third C site, C(27) is bonded in a distorted trigonal planar geometry to one C(28), one N(5), and one N(6) atom. The C(27)-C(28) bond length is 1.49 Å. The C(27)-N(5) bond length is 1.37 Å. The C(27)-N(6) bond length is 1.34 Å. In the twenty-fourth C site, C(28) is bonded in a distorted water-like geometry to one C(27), one H(25), and one H(26) atom. The C(28)-H(25) bond length is 1.10 Å. The C(28)-H(26) bond length is 1.10 Å. In the twenty-fifth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(26), one N(6), and one H(27) atom. The C(29)-N(6) bond length is 1.38 Å. The C(29)-H(27) bond length is 1.08 Å. In the twenty-sixth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(10), and one O(9) atom. The C(31)-O(10) bond length is 1.27 Å. The C(31)-O(9) bond length is 1.27 Å. There are six inequivalent N sites. In the first N site, N(2) is bonded in a distorted trigonal planar geometry to one C(5), one N(3), and one O(8) atom. The N(2)-N(3) bond length is 1.34 Å. The N(2)-O(8) bond length is 1.27 Å. In the second N site, N(3) is bonded in a distorted trigonal planar geometry to one C(7), one N(2), and one O(5) atom. The N(3)-O(5) bond length is 1.28 Å. In the third N site, N(4) is bonded in a trigonal planar geometry to one Zn(2), one C(17), and one C(24) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one C(25), one C(26), and one C(27) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one Zn(1), one C(27), and one C(29) atom. In the sixth N site, N(1) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(17) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(24) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(25) atom. In the fourteenth H site, H(23) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(24) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(25) is bonded in a single-bond geometry to one C(28) atom. In the seventeenth H site, H(26) is bonded in a single-bond geometry to one C(28) atom. In the eighteenth H site, H(27) is bonded in a single-bond geometry to one C(29) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(9) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(13) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(13) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(21) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(21) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one N(2) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(31) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(31) atom. Linkers: 4 CCc1nccn1CCCCCn1ccnc1CC ,4 [O]C(=O)c1cc(C([O])=O)cc(N([O])N([O])c2cc(C([O])=O)cc(C([O])=O)c2)c1. Metal clusters: 4 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: lvt. The MOF has largest included sphere 4.70 A, density 1.35 g/cm3, surface area 4641.06 m2/g, accessible volume 0.29 cm3/g