(CH2)8(C5H3)2(CH)4CuC20H24S2(N2O)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; eight 02329_fluka molecules; one 1,2,4,5-tetramethylbenzene molecule; and one CuC20H24S2(N2O)4 cluster. In the CuC20H24S2(N2O)4 cluster, Cu(1) is bonded in a distorted octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent O(2) atoms. Both Cu(1)-N(1) bond lengths are 1.95 Å. Both Cu(1)-N(2) bond lengths are 2.03 Å. Both Cu(1)-O(2) bond lengths are 2.60 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.19 Å. The C(1)-S(1) bond length is 1.62 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(6), and one N(3) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(6) bond length is 1.41 Å. The C(2)-N(3) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(2) atom. The C(3)-N(2) bond length is 1.34 Å. The C(3)-H(2) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one N(2), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-N(2) bond length is 1.34 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(3) and one O(1) atom. The C(7)-N(3) bond length is 1.37 Å. The C(7)-O(1) bond length is 1.24 Å. In the eighth C site, C(12) is bonded in a trigonal planar geometry to one N(4), one H(14), and one O(2) atom. The C(12)-N(4) bond length is 1.35 Å. The C(12)-H(14) bond length is 1.11 Å. The C(12)-O(2) bond length is 1.24 Å. In the ninth C site, C(13) is bonded to one N(4), one H(15), one H(16), and one H(17) atom to form corner-sharing CH3N tetrahedra. The C(13)-N(4) bond length is 1.45 Å. The C(13)-H(15) bond length is 1.10 Å. The C(13)-H(16) bond length is 1.10 Å. The C(13)-H(17) bond length is 1.10 Å. In the tenth C site, C(14) is bonded to one N(4), one H(18), one H(19), and one H(20) atom to form corner-sharing CH3N tetrahedra. The C(14)-N(4) bond length is 1.45 Å. The C(14)-H(18) bond length is 1.09 Å. The C(14)-H(19) bond length is 1.10 Å. The C(14)-H(20) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Cu(1) and one C(1) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(2), one C(7), and one H(1) atom. The N(3)-H(1) bond length is 1.03 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(14) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(14) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(7) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cu(1) and one C(12) atom. Linkers: 2 O=C(CCCCCCCCC(=O)Nc1cccnc1)Nc1c[c]cnc1 ,1 O=C(CCCCCCCCC(=O)Nc1cccnc1)Nc1cccnc1. Metal clusters: 1 S=C=N[Cu]N=C=S. The MOF has largest included sphere 2.02 A, density 1.40 g/cm3, surface area 5819.22 m2/g, accessible volume 0.17 cm3/g