(CoH30(C22N3)2)3CO2 crystallizes in the triclinic P-1 space group. The structure consists of one carbon dioxide molecule inside a CoH30(C22N3)2 framework. In the CoH30(C22N3)2 framework, there are three inequivalent Co sites. In the first Co site, Co(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(4), and two equivalent N(8) atoms. Both Co(1)-N(1) bond lengths are 2.00 Å. Both Co(1)-N(4) bond lengths are 1.99 Å. Both Co(1)-N(8) bond lengths are 2.24 Å. In the second Co site, Co(2) is bonded in an octahedral geometry to two equivalent N(2,3); two equivalent N(5,6); and two equivalent N(9) atoms. Both Co(2)-N(2,3) bond lengths are 2.00 Å. Both Co(2)-N(5,6) bond lengths are 1.99 Å. Both Co(2)-N(9) bond lengths are 2.24 Å. In the third Co site, Co(3) is bonded in an octahedral geometry to two equivalent N(2,3); two equivalent N(5,6); and two equivalent N(7) atoms. Both Co(3)-N(2,3) bond lengths are 2.00 Å. Both Co(3)-N(5,6) bond lengths are 1.99 Å. Both Co(3)-N(7) bond lengths are 2.24 Å. There are forty-two inequivalent C sites. In the first C site, C(19,20,21) is bonded in a distorted trigonal planar geometry to one C(16,18); one C(22,23,24); and one H(7,8,9) atom. The C(19,20,21)-C(16,18) bond length is 1.44 Å. The C(19,20,21)-C(22,23,24) bond length is 1.36 Å. The C(19,20,21)-H(7,8,9) bond length is 1.08 Å. In the second C site, C(22,23,24) is bonded in a distorted single-bond geometry to one C(19,20,21); one C(25,27); and one H(10,11,12) atom. The C(22,23,24)-C(25,27) bond length is 1.44 Å. The C(22,23,24)-H(10,11,12) bond length is 1.08 Å. In the third C site, C(25,27) is bonded in a distorted single-bond geometry to one C(22,23,24); one C(28,29); and one N(4) atom. The C(25,27)-C(28,29) bond length is 1.39 Å. The C(25,27)-N(4) bond length is 1.38 Å. In the fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(22,23,24); one C(28,29); and one N(5,6) atom. The C(26)-C(22,23,24) bond length is 1.44 Å. The C(26)-C(28,29) bond length is 1.39 Å. The C(26)-N(5,6) bond length is 1.38 Å. In the fifth C site, C(28,29) is bonded in a trigonal planar geometry to one C(1,3); one C(25,27); and one C(31,32,33) atom. The C(28,29)-C(1,3) bond length is 1.39 Å. The C(28,29)-C(31,32,33) bond length is 1.48 Å. In the sixth C site, C(30) is bonded in a trigonal planar geometry to one C(1,3); one C(25,27); and one C(31,32,33) atom. The C(30)-C(1,3) bond length is 1.39 Å. The C(30)-C(25,27) bond length is 1.39 Å. The C(30)-C(31,32,33) bond length is 1.48 Å. In the seventh C site, C(31,32,33) is bonded in a trigonal planar geometry to one C(28,29); one C(34,35); and one C(43,44) atom. The C(31,32,33)-C(34,35) bond length is 1.40 Å. The C(31,32,33)-C(43,44) bond length is 1.40 Å. In the eighth C site, C(34,35) is bonded in a distorted single-bond geometry to one C(31,32,33) and one H(13,14,15) atom. The C(34,35)-H(13,14,15) bond length is 1.09 Å. In the ninth C site, C(36) is bonded in a distorted single-bond geometry to one C(31,32,33) and one H(13,14,15) atom. The C(36)-C(31,32,33) bond length is 1.40 Å. The C(36)-H(13,14,15) bond length is 1.09 Å. In the tenth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(16,17,18) atom. The C(37)-N(7) bond length is 1.34 Å. The C(37)-H(16,17,18) bond length is 1.09 Å. In the eleventh C site, C(38) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(16,17,18) atom. The C(38)-N(8) bond length is 1.34 Å. The C(38)-H(16,17,18) bond length is 1.09 Å. In the twelfth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(16,17,18) atom. The C(39)-N(9) bond length is 1.34 Å. The C(39)-H(16,17,18) bond length is 1.09 Å. In the thirteenth C site, C(40) is bonded in a distorted trigonal planar geometry to one C(43,44); one N(7); and one H(19,20) atom. The C(40)-C(43,44) bond length is 1.39 Å. The C(40)-N(7) bond length is 1.34 Å. The C(40)-H(19,20) bond length is 1.09 Å. In the fourteenth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(43,44); one N(8); and one H(19,20) atom. The C(41)-C(43,44) bond length is 1.39 Å. The C(41)-N(8) bond length is 1.34 Å. The C(41)-H(19,20) bond length is 1.09 Å. In the fifteenth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(45), one N(9), and one H(21) atom. The C(42)-C(45) bond length is 1.39 Å. The C(42)-N(9) bond length is 1.34 Å. The C(42)-H(21) bond length is 1.09 Å. In the sixteenth C site, C(43,44) is bonded in a distorted single-bond geometry to one C(31,32,33); one C(40); and one H(22,23,24) atom. The C(43,44)-H(22,23,24) bond length is 1.09 Å. In the seventeenth C site, C(45) is bonded in a distorted single-bond geometry to one C(31,32,33); one C(42); and one H(22,23,24) atom. The C(45)-C(31,32,33) bond length is 1.40 Å. The C(45)-H(22,23,24) bond length is 1.09 Å. In the eighteenth C site, C(46,47,48) is bonded in a trigonal planar geometry to one C(13), one C(49), and one C(61) atom. The C(46,47,48)-C(13) bond length is 1.49 Å. The C(46,47,48)-C(49) bond length is 1.40 Å. The C(46,47,48)-C(61) bond length is 1.40 Å. In the nineteenth C site, C(49) is bonded in a distorted single-bond geometry to one C(46,47,48); one C(52,53,54); and one H(25,26,27) atom. The C(49)-C(52,53,54) bond length is 1.40 Å. The C(49)-H(25,26,27) bond length is 1.09 Å. In the twentieth C site, C(50) is bonded in a distorted single-bond geometry to one C(46,47,48); one C(52,53,54); and one H(25,26,27) atom. The C(50)-C(46,47,48) bond length is 1.41 Å. The C(50)-C(52,53,54) bond length is 1.40 Å. The C(50)-H(25,26,27) bond length is 1.09 Å. In the twenty-first C site, C(51) is bonded in a distorted single-bond geometry to one C(46,47,48); one C(52,53,54); and one H(25,26,27) atom. The C(51)-C(46,47,48) bond length is 1.40 Å. The C(51)-C(52,53,54) bond length is 1.40 Å. The C(51)-H(25,26,27) bond length is 1.09 Å. In the twenty-second C site, C(52,53,54) is bonded in a distorted trigonal planar geometry to one C(49), one C(55), and one H(28) atom. The C(52,53,54)-C(55) bond length is 1.40 Å. The C(52,53,54)-H(28) bond length is 1.09 Å. In the twenty-third C site, C(55) is bonded in a trigonal planar geometry to one C(52,53,54); one C(58,59,60); and one C(64,65,66) atom. The C(55)-C(58,59,60) bond length is 1.40 Å. The C(55)-C(64,65,66) bond length is 1.51 Å. In the twenty-fourth C site, C(56,57) is bonded in a trigonal planar geometry to one C(52,53,54); one C(58,59,60); and one C(64,65,66) atom. The C(56,57)-C(52,53,54) bond length is 1.40 Å. The C(56,57)-C(58,59,60) bond length is 1.40 Å. The C(56,57)-C(64,65,66) bond length is 1.51 Å. In the twenty-fifth C site, C(58,59,60) is bonded in a distorted single-bond geometry to one C(55) and one H(31,32,33) atom. The C(58,59,60)-H(31,32,33) bond length is 1.09 Å. In the twenty-sixth C site, C(61) is bonded in a distorted single-bond geometry to one C(46,47,48) and one H(34,35,36) atom. The C(61)-H(34,35,36) bond length is 1.09 Å. In the twenty-seventh C site, C(62) is bonded in a distorted single-bond geometry to one C(46,47,48) and one H(34,35,36) atom. The C(62)-C(46,47,48) bond length is 1.40 Å. The C(62)-H(34,35,36) bond length is 1.09 Å. In the twenty-eighth C site, C(63) is bonded in a distorted single-bond geometry to one C(46,47,48) and one H(34,35,36) atom. The C(63)-C(46,47,48) bond length is 1.40 Å. The C(63)-H(34,35,36) bond length is 1.09 Å. In the twenty-ninth C site, C(64,65,66) is bonded in a distorted trigonal non-coplanar geometry to one C(55); one H(37,38,39); one H(40,41,42); and one H(43,44,45) atom. The C(64,65,66)-H(37,38,39) bond length is 1.10 Å. The C(64,65,66)-H(40,41,42) bond length is 1.10 Å. The C(64,65,66)-H(43,44,45) bond length is 1.10 Å. In the thirtieth C site, C(1,3) is bonded in a distorted single-bond geometry to one C(28,29); one C(4,5); and one N(1) atom. The C(1,3)-C(4,5) bond length is 1.44 Å. The C(1,3)-N(1) bond length is 1.38 Å. In the thirty-first C site, C(2) is bonded in a distorted single-bond geometry to one C(28,29); one C(4,5); and one N(2,3) atom. The C(2)-C(28,29) bond length is 1.39 Å. The C(2)-C(4,5) bond length is 1.44 Å. The C(2)-N(2,3) bond length is 1.38 Å. In the thirty-second C site, C(4,5) is bonded in a distorted single-bond geometry to one C(1,3); one C(7,8); and one H(1,2,3) atom. The C(4,5)-C(7,8) bond length is 1.36 Å. The C(4,5)-H(1,2,3) bond length is 1.09 Å. In the thirty-third C site, C(6) is bonded in a distorted single-bond geometry to one C(1,3); one C(9); and one H(1,2,3) atom. The C(6)-C(1,3) bond length is 1.44 Å. The C(6)-C(9) bond length is 1.36 Å. The C(6)-H(1,2,3) bond length is 1.09 Å. In the thirty-fourth C site, C(7,8) is bonded in a distorted single-bond geometry to one C(10,12); one C(4,5); and one H(4,5,6) atom. The C(7,8)-C(10,12) bond length is 1.44 Å. The C(7,8)-H(4,5,6) bond length is 1.08 Å. In the thirty-fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(10,12); one C(6); and one H(4,5,6) atom. The C(9)-C(10,12) bond length is 1.44 Å. The C(9)-H(4,5,6) bond length is 1.08 Å. In the thirty-sixth C site, C(10,12) is bonded in a distorted single-bond geometry to one C(13); one C(7,8); and one N(1) atom. The C(10,12)-C(13) bond length is 1.40 Å. The C(10,12)-N(1) bond length is 1.39 Å. In the thirty-seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(14); one C(7,8); and one N(2,3) atom. The C(11)-C(14) bond length is 1.40 Å. The C(11)-C(7,8) bond length is 1.44 Å. The C(11)-N(2,3) bond length is 1.39 Å. In the thirty-eighth C site, C(13) is bonded in a trigonal planar geometry to one C(10,12); one C(16,18); and one C(46,47,48) atom. The C(13)-C(16,18) bond length is 1.40 Å. In the thirty-ninth C site, C(14) is bonded in a trigonal planar geometry to one C(11); one C(17); and one C(46,47,48) atom. The C(14)-C(17) bond length is 1.40 Å. The C(14)-C(46,47,48) bond length is 1.49 Å. In the fortieth C site, C(15) is bonded in a trigonal planar geometry to one C(10,12); one C(16,18); and one C(46,47,48) atom. The C(15)-C(10,12) bond length is 1.40 Å. The C(15)-C(16,18) bond length is 1.40 Å. The C(15)-C(46,47,48) bond length is 1.49 Å. In the forty-first C site, C(16,18) is bonded in a distorted single-bond geometry to one C(13); one C(19,20,21); and one N(4) atom. The C(16,18)-N(4) bond length is 1.39 Å. In the forty-second C site, C(17) is bonded in a distorted single-bond geometry to one C(14); one C(19,20,21); and one N(5,6) atom. The C(17)-C(19,20,21) bond length is 1.44 Å. The C(17)-N(5,6) bond length is 1.39 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1); one C(1,3); and one C(10,12) atom. In the second N site, N(2,3) is bonded in a trigonal planar geometry to one Co(2), one C(11), and one C(2) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one Co(1); one C(16,18); and one C(25,27) atom. In the fourth N site, N(5,6) is bonded in a trigonal planar geometry to one Co(2), one C(17), and one C(26) atom. In the fifth N site, N(7) is bonded in a trigonal planar geometry to one Co(3), one C(37), and one C(40) atom. In the sixth N site, N(8) is bonded in a trigonal planar geometry to one Co(1), one C(38), and one C(41) atom. In the seventh N site, N(9) is bonded in a trigonal planar geometry to one Co(2), one C(39), and one C(42) atom. There are seventeen inequivalent H sites. In the first H site, H(1,2,3) is bonded in a single-bond geometry to one C(4,5) atom. In the second H site, H(4,5,6) is bonded in a single-bond geometry to one C(7,8) atom. In the third H site, H(7,8,9) is bonded in a single-bond geometry to one C(19,20,21) atom. In the fourth H site, H(10,11,12) is bonded in a single-bond geometry to one C(22,23,24) atom. In the fifth H site, H(13,14,15) is bonded in a single-bond geometry to one C(34,35) atom. In the sixth H site, H(16,17,18) is bonded in a single-bond geometry to one C(37) atom. In the seventh H site, H(19,20) is bonded in a single-bond geometry to one C(40) atom. In the eighth H site, H(21) is bonded in a single-bond geometry to one C(42) atom. In the ninth H site, H(22,23,24) is bonded in a single-bond geometry to one C(43,44) atom. In the tenth H site, H(25,26,27) is bonded in a single-bond geometry to one C(49) atom. In the eleventh H site, H(28) is bonded in a single-bond geometry to one C(52,53,54) atom. In the twelfth H site, H(29,30) is bonded in a single-bond geometry to one C(52,53,54) atom. The H(29,30)-C(52,53,54) bond length is 1.09 Å. In the thirteenth H site, H(31,32,33) is bonded in a single-bond geometry to one C(58,59,60) atom. In the fourteenth H site, H(34,35,36) is bonded in a single-bond geometry to one C(61) atom. In the fifteenth H site, H(37,38,39) is bonded in a single-bond geometry to one C(64,65,66) atom. In the sixteenth H site, H(40,41,42) is bonded in a single-bond geometry to one C(64,65,66) atom. In the seventeenth H site, H(43,44,45) is bonded in a single-bond geometry to one C(64,65,66) atom. Linkers: 1 [CH]=[C]/C1=C2\C=C/C(=C(\c3ccncc3)C3=N/C(=C(/c4ccc(C)cc4)C4=CC=C([N]4)/C(c4ccncc4)=C4/C=CC1=N4)C=C3)[N]2 ,3 Cc1ccc(/C2=C3\C=C/C(=C(\c4ccncc4)C4=N/C(=C(/c5ccc(C)cc5)C5=CC=C([N]5)/C(c5ccncc5)=C5/C=CC2=N5)C=C4)[N]3)cc1 ,1 [C]/C1=C2\[C]=CC(=N2)/C(c2ccncc2)=C2/C=C/C(=C(\c3ccc(C)cc3)C3=N/C(=C(/c4ccncc4)C4=CC=C1[N]4)C=C3)[N]2 ,1 [CH]=[C]/C1=C2\C=CC(=N2)/C(c2ccncc2)=C2/C=C/C(=C(\c3ccc(C)cc3)C3=N/C(=C(/c4ccncc4)C4=CC=C1[N]4)C=C3)[N]2 ,1 [C]/C1=C2\C=C/C(=C(\c3ccncc3)C3=N/C(=C(/c4ccc(C)cc4)C4=CC=C([N]4)/C(c4ccncc4)=C4/C=[C]C1=N4)C=C3)[N]2. Metal clusters: 3 [Co]. The MOF has largest included sphere 3.59 A, density 1.26 g/cm3, surface area 4750.98 m2/g, accessible volume 0.25 cm3/g