CdC20N3H15O5(CH)4C2O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two dimethyl ether molecules, and one CdC20N3H15O5 cluster. In the CdC20N3H15O5 cluster, Cd(1) is bonded in a distorted octahedral geometry to one N(1), one O(1), one O(2), one O(3), one O(5), and one O(6) atom. The Cd(1)-N(1) bond length is 2.36 Å. The Cd(1)-O(1) bond length is 2.29 Å. The Cd(1)-O(2) bond length is 2.33 Å. The Cd(1)-O(3) bond length is 2.51 Å. The Cd(1)-O(5) bond length is 2.49 Å. The Cd(1)-O(6) bond length is 2.29 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(2) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(4) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.46 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(5) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one N(3) atom. The C(6)-N(2) bond length is 1.37 Å. The C(6)-N(3) bond length is 1.34 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one N(3) atom. The C(7)-C(12) bond length is 1.42 Å. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(3) bond length is 1.38 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(8) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(9) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(9) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(7), and one N(2) atom. The C(12)-N(2) bond length is 1.39 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(2), and one O(3) atom. The C(13)-C(14) bond length is 1.49 Å. The C(13)-O(2) bond length is 1.28 Å. The C(13)-O(3) bond length is 1.29 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-C(19) bond length is 1.40 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(10) atom. The C(15)-H(10) bond length is 1.09 Å. In the sixteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(13) atom. The C(19)-H(13) bond length is 1.09 Å. In the seventeenth C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(15) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(15) bond length is 1.09 Å. In the eighteenth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(26) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(26) bond length is 1.49 Å. In the nineteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(16) atom. The C(24)-H(16) bond length is 1.09 Å. In the twentieth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(5), and one O(6) atom. The C(26)-O(5) bond length is 1.28 Å. The C(26)-O(6) bond length is 1.29 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(12), one C(6), and one H(1) atom. The N(2)-H(1) bond length is 1.02 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(6), one C(7), and one H(18) atom. The N(3)-H(18) bond length is 1.68 Å. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(18) is bonded in a distorted single-bond geometry to one N(3) and one O(1) atom. The H(18)-O(1) bond length is 1.01 Å. In the fifteenth H site, H(19) is bonded in a distorted single-bond geometry to one O(1) and one O(3) atom. The H(19)-O(1) bond length is 1.00 Å. The H(19)-O(3) bond length is 1.65 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1), one H(18), and one H(19) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(13) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Cd(1), one C(13), and one H(19) atom. In the fourth O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one C(26) atom. In the fifth O site, O(6) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(26) atom. Linkers: 2 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 2.11 A, density 1.71 g/cm3, surface area 4304.25 m2/g, accessible volume 0.15 cm3/g