CuC10H8(NO2)2(CH)10(H2O)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four isobutylene molecules, four water molecules, and two CuC10H8(NO2)2 clusters. In each CuC10H8(NO2)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 1.99 Å. Both Cu(1)-O(1) bond lengths are 2.00 Å. There are five inequivalent C sites. In the first C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one H(5) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-N(1) bond length is 1.35 Å. The C(6)-H(5) bond length is 1.09 Å. In the second C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. In the third C site, C(8) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(7) atom. The C(8)-C(10) bond length is 1.39 Å. The C(8)-N(1) bond length is 1.35 Å. The C(8)-H(7) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(9) atom. The C(10)-H(9) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(5)-O(1) bond length is 1.28 Å. The C(5)-O(3) bond length is 1.27 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(6), and one C(8) atom. There are four inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one C(5) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(5) atom. Linkers: 2 [O]C(=O)Cc1ccc(CC([O])=O)cc1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 1.73 A, density 1.61 g/cm3, surface area 5034.00 m2/g, accessible volume 0.09 cm3/g