(CuCNH4I)2CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CuCNH4I clusters. In each CuCNH4I cluster, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted single-bond geometry to one N(1,2); one I(1); one I(3); and one I(4) atom. The Cu(1)-N(1,2) bond length is 2.04 Å. The Cu(1)-I(1) bond length is 2.72 Å. The Cu(1)-I(3) bond length is 2.68 Å. The Cu(1)-I(4) bond length is 2.84 Å. In the second Cu site, Cu(2) is bonded in a distorted single-bond geometry to one N(1,2); one I(2); one I(3); and one I(4) atom. The Cu(2)-N(1,2) bond length is 2.04 Å. The Cu(2)-I(2) bond length is 2.72 Å. The Cu(2)-I(3) bond length is 2.83 Å. The Cu(2)-I(4) bond length is 2.68 Å. In the third Cu site, Cu(3) is bonded in a distorted single-bond geometry to one N(3), one I(1), one I(2), and one I(3) atom. The Cu(3)-N(3) bond length is 2.03 Å. The Cu(3)-I(1) bond length is 2.70 Å. The Cu(3)-I(2) bond length is 2.68 Å. The Cu(3)-I(3) bond length is 2.74 Å. In the fourth Cu site, Cu(4) is bonded in a distorted single-bond geometry to one N(4), one I(1), one I(2), and one I(4) atom. The Cu(4)-N(4) bond length is 2.03 Å. The Cu(4)-I(1) bond length is 2.69 Å. The Cu(4)-I(2) bond length is 2.70 Å. The Cu(4)-I(4) bond length is 2.74 Å. There are three inequivalent C sites. In the first C site, C(1,2) is bonded in a 3-coordinate geometry to one N(1,2); one H(11,12); and one H(9,10) atom. The C(1,2)-N(1,2) bond length is 1.48 Å. The C(1,2)-H(11,12) bond length is 1.10 Å. The C(1,2)-H(9,10) bond length is 1.10 Å. In the second C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(3); one H(17,18); and one H(19,20) atom. The C(5)-N(3) bond length is 1.48 Å. The C(5)-H(17,18) bond length is 1.10 Å. The C(5)-H(19,20) bond length is 1.10 Å. In the third C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(4); one H(17,18); and one H(19,20) atom. The C(6)-N(4) bond length is 1.48 Å. The C(6)-H(17,18) bond length is 1.10 Å. The C(6)-H(19,20) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(1,2) is bonded in a distorted tetrahedral geometry to one Cu(1); one C(1,2); one H(1,2); and one H(3,4) atom. The N(1,2)-H(1,2) bond length is 1.03 Å. The N(1,2)-H(3,4) bond length is 1.03 Å. In the second N site, N(3) is bonded in a distorted tetrahedral geometry to one Cu(3), one C(5), one H(5), and one H(7) atom. The N(3)-H(5) bond length is 1.03 Å. The N(3)-H(7) bond length is 1.03 Å. In the third N site, N(4) is bonded in a distorted tetrahedral geometry to one Cu(4), one C(6), one H(6), and one H(8) atom. The N(4)-H(6) bond length is 1.03 Å. The N(4)-H(8) bond length is 1.03 Å. There are ten inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one N(1,2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one N(1,2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one N(4) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(1,2) atom. In the eighth H site, H(11,12) is bonded in a single-bond geometry to one C(1,2) atom. In the ninth H site, H(17,18) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(19,20) is bonded in a single-bond geometry to one C(5) atom. There are four inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(3), and one Cu(4) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one Cu(2), one Cu(3), and one Cu(4) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(2), and one Cu(3) atom. In the fourth I site, I(4) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(2), and one Cu(4) atom. Linkers: 4 NCCCN. Metal clusters: 2 [CH2][NH2][Cu]12(I)[Cu]3([Cu]1([Cu]23(I)[NH2][CH2])(I)[NH2][CH2])(I)[NH2][CH2]. RCSR code: sql. The MOF has largest included sphere 2.39 A, density 3.33 g/cm3, surface area 2382.05 m2/g, accessible volume 0.07 cm3/g