Ag2C15H15S(NO2)3CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a Ag2C15H15S(NO2)3 framework. In the Ag2C15H15S(NO2)3 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted T-shaped geometry to one N(1), one N(3), and one O(1) atom. The Ag(1)-N(1) bond length is 2.16 Å. The Ag(1)-N(3) bond length is 2.19 Å. The Ag(1)-O(1) bond length is 2.48 Å. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one N(2), one O(1), one O(5), and one O(6) atom. The Ag(2)-N(2) bond length is 2.46 Å. The Ag(2)-O(1) bond length is 2.63 Å. The Ag(2)-O(5) bond length is 2.23 Å. The Ag(2)-O(6) bond length is 2.25 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-S(1) bond length is 1.78 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one O(4) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-O(4) bond length is 1.35 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(7) bond length is 1.49 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(5), and one O(6) atom. The C(7)-O(5) bond length is 1.29 Å. The C(7)-O(6) bond length is 1.26 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(1), and one H(4) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-N(1) bond length is 1.34 Å. The C(8)-H(4) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(2) atom. The C(9)-C(10) bond length is 1.49 Å. The C(9)-N(2) bond length is 1.35 Å. In the ninth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(5), one H(6), and one H(7) atom. The C(10)-H(5) bond length is 1.10 Å. The C(10)-H(6) bond length is 1.10 Å. The C(10)-H(7) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(2), and one H(8) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(8) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one N(1) atom. The C(12)-C(13) bond length is 1.49 Å. The C(12)-N(1) bond length is 1.35 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one C(12), one H(10), one H(11), and one H(9) atom. The C(13)-H(10) bond length is 1.10 Å. The C(13)-H(11) bond length is 1.10 Å. The C(13)-H(9) bond length is 1.10 Å. In the thirteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(15), one C(16), and one N(3) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(16) bond length is 1.49 Å. The C(14)-N(3) bond length is 1.35 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one H(12) atom. The C(15)-N(3) bond length is 1.34 Å. The C(15)-H(12) bond length is 1.09 Å. In the fifteenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one C(14), one H(13), one H(14), and one H(15) atom. The C(16)-H(13) bond length is 1.10 Å. The C(16)-H(14) bond length is 1.10 Å. The C(16)-H(15) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(12), and one C(8) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(11), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(14), and one C(15) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(16) is bonded in a bent 150 degrees geometry to one O(4) and one O(5) atom. The H(16)-O(4) bond length is 1.02 Å. The H(16)-O(5) bond length is 1.57 Å. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.49 Å. The S(1)-O(2) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.46 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(4) and one H(16) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(7), and one H(16) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one C(7) atom. Linkers: 3 Cc1cnc(C)cn1 ,2 [O]C(=O)c1cc(S([O])([O])[O])ccc1O. Metal clusters: 1 [C]1O[Ag]2O[C]O[Ag]2O1.[O][S@@](=O)O[Ag].[O][S@@](=O)O[Ag]. The MOF has largest included sphere 2.98 A, density 2.12 g/cm3, surface area 3262.81 m2/g, accessible volume 0.08 cm3/g