Cu3C42H22(NO3)6(CH)2(C3H2)4(C2NH2)2 crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules; two 2,3-dimethyl-1,3-butadiene molecules; and two n-methyl methanimine molecules inside a Cu3C42H22(NO3)6 framework. In the Cu3C42H22(NO3)6 framework, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to two equivalent O(1), two equivalent O(6), and two equivalent O(8) atoms to form distorted corner-sharing CuO6 octahedra. Both Cu(1)-O(1) bond lengths are 2.01 Å. Both Cu(1)-O(6) bond lengths are 1.93 Å. Both Cu(1)-O(8) bond lengths are 2.58 Å. In the second Cu site, Cu(2) is bonded to one N(2), one N(3), one O(2), one O(7), and one O(8) atom to form corner-sharing CuN2O3 trigonal bipyramids. The corner-sharing octahedral tilt angles are 83°. The Cu(2)-N(2) bond length is 2.02 Å. The Cu(2)-N(3) bond length is 2.02 Å. The Cu(2)-O(2) bond length is 1.98 Å. The Cu(2)-O(7) bond length is 2.26 Å. The Cu(2)-O(8) bond length is 1.98 Å. There are twenty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.41 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-N(1) bond length is 1.45 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one O(5) atom. The C(5)-O(5) bond length is 1.35 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(7)-H(3) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one O(5) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-O(5) bond length is 1.41 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(4) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(4) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.50 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(5) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(5) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(14) bond length is 1.50 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(6) atom. The C(13)-H(6) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(6), and one O(7) atom. The C(14)-O(6) bond length is 1.29 Å. The C(14)-O(7) bond length is 1.26 Å. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(8), and one O(9) atom. The C(15)-O(8) bond length is 1.31 Å. The C(15)-O(9) bond length is 1.25 Å. In the fifteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one N(2), and one H(7) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-N(2) bond length is 1.35 Å. The C(16)-H(7) bond length is 1.09 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(8) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(8) bond length is 1.09 Å. In the seventeenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(19) atom. The C(18)-C(18) bond length is 1.48 Å. The C(18)-C(19) bond length is 1.41 Å. In the eighteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(9) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-H(9) bond length is 1.09 Å. In the nineteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one N(2), and one H(10) atom. The C(20)-N(2) bond length is 1.35 Å. The C(20)-H(10) bond length is 1.09 Å. In the twentieth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(11) atom. The C(21)-N(3) bond length is 1.35 Å. The C(21)-H(11) bond length is 1.09 Å. In the twenty-first C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(14) atom. The C(25)-N(3) bond length is 1.34 Å. The C(25)-H(14) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(4), one O(3), and one O(4) atom. The N(1)-O(3) bond length is 1.26 Å. The N(1)-O(4) bond length is 1.24 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(16), and one C(20) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(2), one C(21), and one C(25) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(25) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(5) and one C(8) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(14) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(14) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Cu(1), one Cu(2), and one C(15) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(15) atom. Linkers: 2 [O]C(=O)c1cc(Oc2ccc(C([O])=O)cc2[N+](=O)[O-])cc(C([O])=O)c1 ,1 c1cc(-c2ccncc2)ccn1. Metal clusters: 3 [Cu]. The MOF has largest included sphere 3.49 A, density 1.54 g/cm3, surface area 4292.02 m2/g, accessible volume 0.19 cm3/g