Co3C56H32(N2O7)2(CH)8C2O is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, four dimethyl ether molecules, and four Co3C56H32(N2O7)2 clusters. In each Co3C56H32(N2O7)2 cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(1), one N(2), one O(1), one O(2), one O(4), and one O(6) atom to form distorted corner-sharing CoN2O4 octahedra. The corner-sharing octahedral tilt angles are 73°. The Co(1)-N(1) bond length is 2.07 Å. The Co(1)-N(2) bond length is 2.09 Å. The Co(1)-O(1) bond length is 2.23 Å. The Co(1)-O(2) bond length is 2.17 Å. The Co(1)-O(4) bond length is 2.00 Å. The Co(1)-O(6) bond length is 1.97 Å. In the second Co site, Co(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 73°. Both Co(2)-O(1) bond lengths are 2.15 Å. Both Co(2)-O(3) bond lengths are 2.05 Å. Both Co(2)-O(5) bond lengths are 2.09 Å. There are twenty-eight inequivalent C sites. In the first C site, C(25) is bonded in a distorted single-bond geometry to one C(20) and one H(16) atom. The C(25)-C(20) bond length is 1.40 Å. The C(25)-H(16) bond length is 1.09 Å. In the second C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(3), and one O(4) atom. The C(26)-C(27) bond length is 1.50 Å. The C(26)-O(3) bond length is 1.27 Å. The C(26)-O(4) bond length is 1.28 Å. In the third C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(32) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-C(32) bond length is 1.40 Å. In the fourth C site, C(28) is bonded in a distorted single-bond geometry to one C(27), one C(29), and one H(17) atom. The C(28)-C(29) bond length is 1.39 Å. The C(28)-H(17) bond length is 1.09 Å. In the fifth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one C(30), and one H(18) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-H(18) bond length is 1.09 Å. In the sixth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one O(8) atom. The C(30)-O(8) bond length is 1.40 Å. In the seventh C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(19) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-H(19) bond length is 1.09 Å. In the eighth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(27), one C(31), and one H(20) atom. The C(32)-H(20) bond length is 1.09 Å. In the ninth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the tenth C site, C(33) is bonded in a distorted single-bond geometry to one O(8) atom. The C(33)-O(8) bond length is 1.38 Å. In the eleventh C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.09 Å. In the twelfth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the thirteenth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(12) bond length is 1.42 Å. The C(4)-C(5) bond length is 1.43 Å. In the fourteenth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the fifteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-C(7) bond length is 1.43 Å. The C(6)-H(5) bond length is 1.09 Å. In the sixteenth C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.42 Å. The C(7)-C(8) bond length is 1.41 Å. In the seventeenth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(6) atom. The C(8)-C(9) bond length is 1.38 Å. The C(8)-H(6) bond length is 1.09 Å. In the eighteenth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the nineteenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(10)-N(1) bond length is 1.33 Å. The C(10)-H(8) bond length is 1.09 Å. In the twentieth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(7), and one N(1) atom. The C(11)-C(12) bond length is 1.43 Å. The C(11)-N(1) bond length is 1.36 Å. In the twenty-first C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(4), and one N(2) atom. The C(12)-N(2) bond length is 1.36 Å. In the twenty-second C site, C(13) is bonded in a bent 120 degrees geometry to one C(14), one O(1), and one O(2) atom. The C(13)-C(14) bond length is 1.48 Å. The C(13)-O(1) bond length is 1.29 Å. The C(13)-O(2) bond length is 1.28 Å. In the twenty-third C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(17) bond length is 1.40 Å. In the twenty-fourth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(9) atom. The C(15)-H(9) bond length is 1.09 Å. In the twenty-fifth C site, C(17) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(17)-H(11) bond length is 1.09 Å. In the twenty-sixth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(5), and one O(6) atom. The C(19)-C(20) bond length is 1.50 Å. The C(19)-O(5) bond length is 1.27 Å. The C(19)-O(6) bond length is 1.28 Å. In the twenty-seventh C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(25) atom. The C(20)-C(21) bond length is 1.40 Å. In the twenty-eighth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(13) atom. The C(21)-H(13) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(10), and one C(11) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(12) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(28) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(29) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(31) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(32) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Co(1), one Co(2), and one C(13) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Co(1) and one C(13) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Co(2) and one C(26) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one C(26) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Co(2) and one C(19) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(19) atom. In the seventh O site, O(8) is bonded in a bent 120 degrees geometry to one C(30) and one C(33) atom. Linkers: 6 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,2 c1cnc2c(c1)ccc1cccnc12. Metal clusters: 2 [C]1O[Co]2O[C]O[Co]34(O1)(O[C]O2)O[C]O[Co](O[C]O3)O[C]O4. RCSR code: pcu. The MOF has largest included sphere 4.62 A, density 1.38 g/cm3, surface area 4269.02 m2/g, accessible volume 0.22 cm3/g