(CH3)2ZnC16H14S4(NO)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and four ZnC16H14S4(NO)2 clusters. In each ZnC16H14S4(NO)2 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent S(1) atoms. Both Zn(1)-N(1) bond lengths are 2.06 Å. Both Zn(1)-S(1) bond lengths are 2.32 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one S(1), one S(2), and one O(1) atom. The C(1)-S(1) bond length is 1.73 Å. The C(1)-S(2) bond length is 1.66 Å. The C(1)-O(1) bond length is 1.35 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one O(1) atom. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. The C(2)-O(1) bond length is 1.46 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(6) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(6) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(7) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-H(7) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(6)-C(7) bond length is 1.41 Å. The C(6)-C(9) bond length is 1.46 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(8) atom. The C(7)-H(8) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(8)-N(1) bond length is 1.35 Å. The C(8)-H(9) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(6) and one H(10) atom. The C(9)-H(10) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(4), and one C(8) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(9) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(1) atom. O(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. Linkers: 2 [c]1cc(/C=C/c2ccncc2)ccn1 ,2 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.86 A, density 1.61 g/cm3, surface area 4890.09 m2/g, accessible volume 0.11 cm3/g