Zn2C16N3H9O8(CH)2(CH2CO)2 is Indium-derived structured and crystallizes in the orthorhombic Pbcn space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, sixteen dimethyl ether molecules, and four Zn2C16N3H9O8 clusters. In each Zn2C16N3H9O8 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(4), one O(5), and one O(7) atom to form corner-sharing ZnO4 tetrahedra. The corner-sharing octahedral tilt angles range from 59-80°. The Zn(1)-O(1) bond length is 1.98 Å. The Zn(1)-O(4) bond length is 2.04 Å. The Zn(1)-O(5) bond length is 1.95 Å. The Zn(1)-O(7) bond length is 1.98 Å. In the second Zn site, Zn(2) is bonded to one N(1), one N(3), one O(3), one O(6), and two equivalent O(7) atoms to form distorted ZnN2O4 octahedra that share corners with two equivalent Zn(1)O4 tetrahedra and  an edgeedge with one Zn(2)N2O4 octahedra. The Zn(2)-N(1) bond length is 2.17 Å. The Zn(2)-N(3) bond length is 2.48 Å. The Zn(2)-O(3) bond length is 2.08 Å. The Zn(2)-O(6) bond length is 2.06 Å. There is one shorter (2.10 Å) and one longer (2.14 Å) Zn(2)-O(7) bond length. There are sixteen inequivalent C sites. In the first C site, C(16) is bonded in a distorted single-bond geometry to one C(4) and one H(8) atom. The C(16)-C(4) bond length is 1.40 Å. The C(16)-H(8) bond length is 1.09 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(3) atom. The C(1)-C(4) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.27 Å. In the third C site, C(17) is bonded in a distorted trigonal planar geometry to one C(22), one C(8), and one H(9) atom. The C(17)-C(22) bond length is 1.40 Å. The C(17)-C(8) bond length is 1.40 Å. The C(17)-H(9) bond length is 1.09 Å. In the fourth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. The C(2)-O(4) bond length is 1.27 Å. The C(2)-O(6) bond length is 1.26 Å. In the fifth C site, C(19) is bonded in a distorted single-bond geometry to one C(6) and one N(1) atom. The C(19)-C(6) bond length is 1.41 Å. The C(19)-N(1) bond length is 1.33 Å. In the sixth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(16), and one C(20) atom. The C(4)-C(20) bond length is 1.40 Å. In the seventh C site, C(20) is bonded in a distorted single-bond geometry to one C(4) and one H(11) atom. The C(20)-H(11) bond length is 1.09 Å. In the eighth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(9) atom. The C(5)-O(5) bond length is 1.31 Å. The C(5)-O(9) bond length is 1.24 Å. In the ninth C site, C(6) is bonded in a trigonal planar geometry to one C(19), one C(22), and one C(7) atom. The C(6)-C(22) bond length is 1.40 Å. The C(6)-C(7) bond length is 1.48 Å. In the tenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(17), one C(6), and one H(13) atom. The C(22)-H(13) bond length is 1.09 Å. In the eleventh C site, C(7) is bonded in a distorted single-bond geometry to one C(10), one C(6), and one N(2) atom. The C(7)-C(10) bond length is 1.48 Å. The C(7)-N(2) bond length is 1.30 Å. In the twelfth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(1), and one H(1) atom. The C(8)-N(1) bond length is 1.35 Å. The C(8)-H(1) bond length is 1.09 Å. In the thirteenth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(2) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(2) bond length is 1.09 Å. In the fourteenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(7), and one C(9) atom. The C(10)-C(11) bond length is 1.41 Å. In the fifteenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one N(3) atom. The C(11)-N(3) bond length is 1.33 Å. In the sixteenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(3) atom. The C(12)-N(3) bond length is 1.35 Å. The C(12)-H(3) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(19), and one C(8) atom. In the second N site, N(2) is bonded in a water-like geometry to one C(7) and one O(10) atom. The N(2)-O(10) bond length is 1.39 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Zn(2), one C(11), and one C(12) atom. There are nine inequivalent H sites. In the first H site, H(15) is bonded in a single-bond geometry to one O(10) atom. The H(15)-O(10) bond length is 0.98 Å. In the second H site, H(1) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one O(7) atom. The H(14)-O(7) bond length is 0.97 Å. There are eight inequivalent O sites. In the first O site, O(7) is bonded in a distorted single-bond geometry to one Zn(1), two equivalent Zn(2), and one H(14) atom. In the second O site, O(9) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(10) is bonded in a distorted water-like geometry to one N(2) and one H(15) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the fifth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(2) atom. In the seventh O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the eighth O site, O(5) is bonded in a water-like geometry to one Zn(1) and one C(5) atom. Linkers: 8 [O]C(=O)COc1cc(OCC([O])=O)cc(C([O])=O)c1. Metal clusters: 16 [Zn]. The MOF has largest included sphere 4.28 A, density 1.57 g/cm3, surface area 4089.77 m2/g, accessible volume 0.18 cm3/g