CHZnC6H11SO10 crystallizes in the monoclinic Cc space group. The structure consists of four 02329_fluka molecules inside a ZnC6H11SO10 framework. In the ZnC6H11SO10 framework, Zn(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Zn(1)-O(1) bond length is 2.08 Å. The Zn(1)-O(2) bond length is 2.18 Å. The Zn(1)-O(3) bond length is 2.06 Å. The Zn(1)-O(4) bond length is 2.10 Å. The Zn(1)-O(5) bond length is 2.21 Å. The Zn(1)-O(6) bond length is 2.12 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one O(7) atom. The C(1)-C(6) bond length is 1.42 Å. The C(1)-O(7) bond length is 1.34 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(2) bond length is 1.09 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one S(1) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-S(1) bond length is 1.76 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(3) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(3) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.48 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(5), and one O(6) atom. The C(7)-O(5) bond length is 1.28 Å. The C(7)-O(6) bond length is 1.29 Å. There are eleven inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a distorted bent 150 degrees geometry to one O(6) and one O(7) atom. The H(4)-O(6) bond length is 1.63 Å. The H(4)-O(7) bond length is 1.01 Å. In the fourth H site, H(5) is bonded in a single-bond geometry to one O(1) and one O(9) atom. The H(5)-O(1) bond length is 0.99 Å. The H(5)-O(9) bond length is 1.73 Å. In the fifth H site, H(6) is bonded in a single-bond geometry to one O(1) and one O(10) atom. The H(6)-O(1) bond length is 0.99 Å. The H(6)-O(10) bond length is 1.75 Å. In the sixth H site, H(7) is bonded in a single-bond geometry to one O(10) and one O(2) atom. The H(7)-O(10) bond length is 1.71 Å. The H(7)-O(2) bond length is 1.00 Å. In the seventh H site, H(8) is bonded in a single-bond geometry to one O(2) and one O(8) atom. The H(8)-O(2) bond length is 1.00 Å. The H(8)-O(8) bond length is 1.69 Å. In the eighth H site, H(9) is bonded in a distorted single-bond geometry to one O(3) and one O(9) atom. The H(9)-O(3) bond length is 0.99 Å. The H(9)-O(9) bond length is 1.68 Å. In the ninth H site, H(10) is bonded in a single-bond geometry to one O(3) and one O(8) atom. The H(10)-O(3) bond length is 0.99 Å. The H(10)-O(8) bond length is 1.73 Å. In the tenth H site, H(11) is bonded in a single-bond geometry to one O(4) atom. The H(11)-O(4) bond length is 0.99 Å. In the eleventh H site, H(12) is bonded in a single-bond geometry to one O(4) and one O(5) atom. The H(12)-O(4) bond length is 1.00 Å. The H(12)-O(5) bond length is 1.76 Å. S(1) is bonded in a distorted tetrahedral geometry to one C(4), one O(10), one O(8), and one O(9) atom. The S(1)-O(10) bond length is 1.48 Å. The S(1)-O(8) bond length is 1.47 Å. The S(1)-O(9) bond length is 1.48 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Zn(1), one H(5), and one H(6) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Zn(1), one H(7), and one H(8) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one H(10), and one H(9) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Zn(1), one H(11), and one H(12) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Zn(1), one C(7), and one H(12) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(7), and one H(4) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one C(1) and one H(4) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one H(10), one H(8), and one S(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one H(5), one H(9), and one S(1) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one H(6), one H(7), and one S(1) atom. Linkers: 2 [O]C(=O)c1cc(S([O])([O])[O])ccc1O. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.89 A, density 1.98 g/cm3, surface area 3635.73 m2/g, accessible volume 0.10 cm3/g