(CH3)2ZnC16N4H10(OF)4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and four ZnC16N4H10(OF)4 clusters. In each ZnC16N4H10(OF)4 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Zn(1)-N(1) bond lengths are 2.01 Å. Both Zn(1)-O(1) bond lengths are 1.99 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-N(1) bond length is 1.38 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(2), and one H(2) atom. The C(2)-N(2) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. The C(3)-N(1) bond length is 1.33 Å. The C(3)-N(2) bond length is 1.36 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one N(2), one H(4), and one H(5) atom. The C(4)-C(5) bond length is 1.51 Å. The C(4)-N(2) bond length is 1.47 Å. The C(4)-H(4) bond length is 1.09 Å. The C(4)-H(5) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(7) bond length is 1.39 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one F(1) atom. The C(6)-F(1) bond length is 1.36 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one F(2) atom. The C(7)-F(2) bond length is 1.36 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(8)-O(1) bond length is 1.30 Å. The C(8)-O(2) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(8) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(6) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(7) atom. Linkers: 2 Fc1c(F)c(Cn2ccnc2)c(F)c(F)c1Cn1ccnc1 ,4 [CH]N(C=[N])Cc1c(F)c(F)c(Cn2ccnc2)c(F)c1F. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.03 A, density 1.71 g/cm3, surface area 4696.79 m2/g, accessible volume 0.09 cm3/g