Cu5C24H16(N3O10)2 crystallizes in the triclinic P1 space group. There are ten inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 6-coordinate geometry to one N(1), one O(20), one O(28), one O(33), one O(37), and one O(5) atom. The Cu(1)-N(1) bond length is 2.01 Å. The Cu(1)-O(20) bond length is 2.68 Å. The Cu(1)-O(28) bond length is 2.45 Å. The Cu(1)-O(33) bond length is 1.92 Å. The Cu(1)-O(37) bond length is 1.99 Å. The Cu(1)-O(5) bond length is 1.96 Å. In the second Cu site, Cu(2) is bonded in a 6-coordinate geometry to one N(2), one O(19), one O(27), one O(34), one O(38), and one O(6) atom. The Cu(2)-N(2) bond length is 2.01 Å. The Cu(2)-O(19) bond length is 2.68 Å. The Cu(2)-O(27) bond length is 2.47 Å. The Cu(2)-O(34) bond length is 1.92 Å. The Cu(2)-O(38) bond length is 1.99 Å. The Cu(2)-O(6) bond length is 1.96 Å. In the third Cu site, Cu(3) is bonded in a 6-coordinate geometry to one N(3), one O(18), one O(26), one O(35), one O(39), and one O(7) atom. The Cu(3)-N(3) bond length is 2.01 Å. The Cu(3)-O(18) bond length is 2.69 Å. The Cu(3)-O(26) bond length is 2.45 Å. The Cu(3)-O(35) bond length is 1.93 Å. The Cu(3)-O(39) bond length is 1.99 Å. The Cu(3)-O(7) bond length is 1.96 Å. In the fourth Cu site, Cu(4) is bonded in a 6-coordinate geometry to one N(4), one O(17), one O(25), one O(36), one O(40), and one O(8) atom. The Cu(4)-N(4) bond length is 2.02 Å. The Cu(4)-O(17) bond length is 2.67 Å. The Cu(4)-O(25) bond length is 2.47 Å. The Cu(4)-O(36) bond length is 1.91 Å. The Cu(4)-O(40) bond length is 2.00 Å. The Cu(4)-O(8) bond length is 1.95 Å. In the fifth Cu site, Cu(5) is bonded to one N(5,7); one O(1); one O(28); one O(33); and one O(35) atom to form distorted edge-sharing CuNO4 trigonal bipyramids. The Cu(5)-N(5,7) bond length is 1.99 Å. The Cu(5)-O(1) bond length is 1.98 Å. The Cu(5)-O(28) bond length is 1.94 Å. The Cu(5)-O(33) bond length is 2.54 Å. The Cu(5)-O(35) bond length is 1.94 Å. In the sixth Cu site, Cu(6) is bonded in a 5-coordinate geometry to one N(8), one O(2), one O(27), one O(34), and one O(36) atom. The Cu(6)-N(8) bond length is 2.00 Å. The Cu(6)-O(2) bond length is 1.99 Å. The Cu(6)-O(27) bond length is 1.93 Å. The Cu(6)-O(34) bond length is 2.56 Å. The Cu(6)-O(36) bond length is 1.92 Å. In the seventh Cu site, Cu(7) is bonded to one N(5,7); one O(26); one O(3); one O(33); and one O(35) atom to form distorted edge-sharing CuNO4 trigonal bipyramids. The Cu(7)-N(5,7) bond length is 1.99 Å. The Cu(7)-O(26) bond length is 1.94 Å. The Cu(7)-O(3) bond length is 1.98 Å. The Cu(7)-O(33) bond length is 1.94 Å. The Cu(7)-O(35) bond length is 2.54 Å. In the eighth Cu site, Cu(8) is bonded in a distorted rectangular see-saw-like geometry to one N(6), one O(25), one O(34), and one O(4) atom. The Cu(8)-N(6) bond length is 1.99 Å. The Cu(8)-O(25) bond length is 1.94 Å. The Cu(8)-O(34) bond length is 1.93 Å. The Cu(8)-O(4) bond length is 1.98 Å. In the ninth Cu site, Cu(9) is bonded in a rectangular see-saw-like geometry to one O(10), one O(19), one O(20), and one O(9) atom. The Cu(9)-O(10) bond length is 1.94 Å. The Cu(9)-O(19) bond length is 1.96 Å. The Cu(9)-O(20) bond length is 1.96 Å. The Cu(9)-O(9) bond length is 1.94 Å. In the tenth Cu site, Cu(10) is bonded in a rectangular see-saw-like geometry to one O(11), one O(12), one O(17), and one O(18) atom. The Cu(10)-O(11) bond length is 1.95 Å. The Cu(10)-O(12) bond length is 1.95 Å. The Cu(10)-O(17) bond length is 1.96 Å. The Cu(10)-O(18) bond length is 1.96 Å. There are forty-three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(5,7); one N(9); and one H(17,19) atom. The C(1)-N(5,7) bond length is 1.33 Å. The C(1)-N(9) bond length is 1.35 Å. The C(1)-H(17,19) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(10), one N(6), and one H(18) atom. The C(2)-N(10) bond length is 1.35 Å. The C(2)-N(6) bond length is 1.33 Å. The C(2)-H(18) bond length is 1.08 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(11); one N(5,7); and one H(17,19) atom. The C(3)-N(11) bond length is 1.35 Å. The C(3)-N(5,7) bond length is 1.33 Å. The C(3)-H(17,19) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(12), one N(8), and one H(20) atom. The C(4)-N(12) bond length is 1.36 Å. The C(4)-N(8) bond length is 1.33 Å. The C(4)-H(20) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(1); one N(9); and one H(21,23) atom. The C(5)-N(1) bond length is 1.32 Å. The C(5)-N(9) bond length is 1.36 Å. The C(5)-H(21,23) bond length is 1.08 Å. In the sixth C site, C(6,7) is bonded in a trigonal planar geometry to one N(10), one N(2), and one H(22) atom. The C(6,7)-N(10) bond length is 1.36 Å. The C(6,7)-N(2) bond length is 1.32 Å. The C(6,7)-H(22) bond length is 1.08 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one N(12), one N(4), and one H(24) atom. The C(8)-N(12) bond length is 1.36 Å. The C(8)-N(4) bond length is 1.32 Å. The C(8)-H(24) bond length is 1.08 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(13); one C(29,32); and one C(33) atom. The C(9)-C(13) bond length is 1.41 Å. The C(9)-C(29,32) bond length is 1.40 Å. The C(9)-C(33) bond length is 1.50 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(14), one C(30), and one C(34) atom. The C(10)-C(14) bond length is 1.41 Å. The C(10)-C(30) bond length is 1.40 Å. The C(10)-C(34) bond length is 1.50 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one C(15), one C(31), and one C(35) atom. The C(11)-C(15) bond length is 1.41 Å. The C(11)-C(31) bond length is 1.40 Å. The C(11)-C(35) bond length is 1.50 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(16); one C(29,32); and one C(36) atom. The C(12)-C(16) bond length is 1.41 Å. The C(12)-C(29,32) bond length is 1.40 Å. The C(12)-C(36) bond length is 1.50 Å. In the twelfth C site, C(13) is bonded in a trigonal planar geometry to one C(17,19); one C(37); and one C(9) atom. The C(13)-C(17,19) bond length is 1.39 Å. The C(13)-C(37) bond length is 1.50 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(10); one C(18,20); and one C(38) atom. The C(14)-C(18,20) bond length is 1.39 Å. The C(14)-C(38) bond length is 1.50 Å. In the fourteenth C site, C(15) is bonded in a trigonal planar geometry to one C(11); one C(17,19); and one C(39) atom. The C(15)-C(17,19) bond length is 1.39 Å. The C(15)-C(39) bond length is 1.50 Å. In the fifteenth C site, C(16) is bonded in a trigonal planar geometry to one C(12); one C(18,20); and one C(40) atom. The C(16)-C(18,20) bond length is 1.39 Å. The C(16)-C(40) bond length is 1.50 Å. In the sixteenth C site, C(17,19) is bonded in a distorted trigonal planar geometry to one C(13); one C(21); and one H(25,28) atom. The C(17,19)-C(21) bond length is 1.39 Å. The C(17,19)-H(25,28) bond length is 1.09 Å. In the seventeenth C site, C(18,20) is bonded in a distorted trigonal planar geometry to one C(14), one C(22), and one H(26) atom. The C(18,20)-C(22) bond length is 1.39 Å. The C(18,20)-H(26) bond length is 1.09 Å. In the eighteenth C site, C(21) is bonded in a trigonal planar geometry to one C(17,19); one C(25); and one C(41) atom. The C(21)-C(25) bond length is 1.40 Å. The C(21)-C(41) bond length is 1.49 Å. In the nineteenth C site, C(22) is bonded in a trigonal planar geometry to one C(18,20); one C(26); and one C(42) atom. The C(22)-C(26) bond length is 1.40 Å. The C(22)-C(42) bond length is 1.49 Å. In the twentieth C site, C(23) is bonded in a trigonal planar geometry to one C(17,19); one C(27); and one C(43) atom. The C(23)-C(17,19) bond length is 1.39 Å. The C(23)-C(27) bond length is 1.40 Å. The C(23)-C(43) bond length is 1.49 Å. In the twenty-first C site, C(24) is bonded in a trigonal planar geometry to one C(18,20); one C(28); and one C(44) atom. The C(24)-C(18,20) bond length is 1.39 Å. The C(24)-C(28) bond length is 1.40 Å. The C(24)-C(44) bond length is 1.49 Å. In the twenty-second C site, C(25) is bonded in a trigonal planar geometry to one C(21); one C(29,32); and one C(45) atom. The C(25)-C(29,32) bond length is 1.40 Å. The C(25)-C(45) bond length is 1.50 Å. In the twenty-third C site, C(26) is bonded in a trigonal planar geometry to one C(22); one C(30); and one C(46,48) atom. The C(26)-C(30) bond length is 1.40 Å. The C(26)-C(46,48) bond length is 1.50 Å. In the twenty-fourth C site, C(27) is bonded in a trigonal planar geometry to one C(23), one C(31), and one C(47) atom. The C(27)-C(31) bond length is 1.40 Å. The C(27)-C(47) bond length is 1.50 Å. In the twenty-fifth C site, C(28) is bonded in a trigonal planar geometry to one C(24); one C(29,32); and one C(46,48) atom. The C(28)-C(29,32) bond length is 1.40 Å. The C(28)-C(46,48) bond length is 1.50 Å. In the twenty-sixth C site, C(29,32) is bonded in a distorted single-bond geometry to one C(25); one C(9); and one H(29,30,31,32) atom. The C(29,32)-H(29,30,31,32) bond length is 1.09 Å. In the twenty-seventh C site, C(30) is bonded in a distorted single-bond geometry to one C(10); one C(26); and one H(29,30,31,32) atom. The C(30)-H(29,30,31,32) bond length is 1.09 Å. In the twenty-eighth C site, C(31) is bonded in a distorted single-bond geometry to one C(11); one C(27); and one H(29,30,31,32) atom. The C(31)-H(29,30,31,32) bond length is 1.09 Å. In the twenty-ninth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(1), and one O(5) atom. The C(33)-O(1) bond length is 1.28 Å. The C(33)-O(5) bond length is 1.27 Å. In the thirtieth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(2), and one O(6) atom. The C(34)-O(2) bond length is 1.28 Å. The C(34)-O(6) bond length is 1.27 Å. In the thirty-first C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(3), and one O(7) atom. The C(35)-O(3) bond length is 1.28 Å. The C(35)-O(7) bond length is 1.27 Å. In the thirty-second C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(4), and one O(8) atom. The C(36)-O(4) bond length is 1.28 Å. The C(36)-O(8) bond length is 1.27 Å. In the thirty-third C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(13), and one O(9) atom. The C(37)-O(13) bond length is 1.25 Å. The C(37)-O(9) bond length is 1.29 Å. In the thirty-fourth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(10), and one O(14) atom. The C(38)-O(10) bond length is 1.29 Å. The C(38)-O(14) bond length is 1.25 Å. In the thirty-fifth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(11), and one O(15) atom. The C(39)-O(11) bond length is 1.29 Å. The C(39)-O(15) bond length is 1.25 Å. In the thirty-sixth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(12), and one O(16) atom. The C(40)-O(12) bond length is 1.29 Å. The C(40)-O(16) bond length is 1.25 Å. In the thirty-seventh C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(17), and one O(21) atom. The C(41)-O(17) bond length is 1.28 Å. The C(41)-O(21) bond length is 1.27 Å. In the thirty-eighth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(18), and one O(22) atom. The C(42)-O(18) bond length is 1.28 Å. The C(42)-O(22) bond length is 1.27 Å. In the thirty-ninth C site, C(43) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(19), and one O(23) atom. The C(43)-O(19) bond length is 1.28 Å. The C(43)-O(23) bond length is 1.27 Å. In the fortieth C site, C(44) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(20), and one O(24) atom. The C(44)-O(20) bond length is 1.28 Å. The C(44)-O(24) bond length is 1.27 Å. In the forty-first C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(25), and one O(29) atom. The C(45)-O(25) bond length is 1.29 Å. The C(45)-O(29) bond length is 1.25 Å. In the forty-second C site, C(46,48) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(26), and one O(30) atom. The C(46,48)-O(26) bond length is 1.29 Å. The C(46,48)-O(30) bond length is 1.25 Å. In the forty-third C site, C(47) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(27), and one O(31) atom. The C(47)-O(27) bond length is 1.29 Å. The C(47)-O(31) bond length is 1.25 Å. There are eleven inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1); one C(5); and one N(5,7) atom. The N(1)-N(5,7) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(2); one C(6,7); and one N(6) atom. The N(2)-N(6) bond length is 1.36 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(3); one C(6,7); and one N(5,7) atom. The N(3)-C(6,7) bond length is 1.32 Å. The N(3)-N(5,7) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cu(4), one C(8), and one N(8) atom. The N(4)-N(8) bond length is 1.35 Å. In the fifth N site, N(5,7) is bonded in a distorted trigonal planar geometry to one Cu(7), one C(1), and one N(1) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cu(8), one C(2), and one N(2) atom. In the seventh N site, N(8) is bonded in a distorted trigonal planar geometry to one Cu(6), one C(4), and one N(4) atom. In the eighth N site, N(9) is bonded in a trigonal planar geometry to one C(1), one C(5), and one H(1) atom. The N(9)-H(1) bond length is 1.05 Å. In the ninth N site, N(10) is bonded in a trigonal planar geometry to one C(2); one C(6,7); and one H(2) atom. The N(10)-H(2) bond length is 1.05 Å. In the tenth N site, N(11) is bonded in a trigonal planar geometry to one C(3); one C(6,7); and one H(3) atom. The N(11)-C(6,7) bond length is 1.36 Å. The N(11)-H(3) bond length is 1.05 Å. In the eleventh N site, N(12) is bonded in a trigonal planar geometry to one C(4), one C(8), and one H(4) atom. The N(12)-H(4) bond length is 1.05 Å. There are twenty-six inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one N(9) and one O(21) atom. The H(1)-O(21) bond length is 1.69 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one N(10) and one O(22) atom. The H(2)-O(22) bond length is 1.69 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one N(11) and one O(23) atom. The H(3)-O(23) bond length is 1.69 Å. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one N(12) and one O(24) atom. The H(4)-O(24) bond length is 1.70 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(33) atom. The H(5)-O(33) bond length is 1.00 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(34) atom. The H(6)-O(34) bond length is 1.00 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(35) atom. The H(7)-O(35) bond length is 1.00 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(36) atom. The H(8)-O(36) bond length is 1.00 Å. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(37) atom. The H(9)-O(37) bond length is 1.00 Å. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(38) atom. The H(10)-O(38) bond length is 1.00 Å. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(39) atom. The H(11)-O(39) bond length is 1.00 Å. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(40) atom. The H(12)-O(40) bond length is 1.00 Å. In the thirteenth H site, H(13) is bonded in a distorted single-bond geometry to one O(24) and one O(37) atom. The H(13)-O(24) bond length is 1.66 Å. The H(13)-O(37) bond length is 1.00 Å. In the fourteenth H site, H(14) is bonded in a distorted single-bond geometry to one O(23) and one O(38) atom. The H(14)-O(23) bond length is 1.66 Å. The H(14)-O(38) bond length is 1.00 Å. In the fifteenth H site, H(15) is bonded in a distorted single-bond geometry to one O(22) and one O(39) atom. The H(15)-O(22) bond length is 1.66 Å. The H(15)-O(39) bond length is 1.00 Å. In the sixteenth H site, H(16) is bonded in a distorted single-bond geometry to one O(21) and one O(40) atom. The H(16)-O(21) bond length is 1.66 Å. The H(16)-O(40) bond length is 1.00 Å. In the seventeenth H site, H(17,19) is bonded in a single-bond geometry to one C(1) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(2) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(4) atom. In the twentieth H site, H(21,23) is bonded in a single-bond geometry to one C(5) atom. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one C(6,7) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(8) atom. In the twenty-third H site, H(25,28) is bonded in a single-bond geometry to one C(17,19) atom. In the twenty-fourth H site, H(26) is bonded in a single-bond geometry to one C(18,20) atom. In the twenty-fifth H site, H(27) is bonded in a single-bond geometry to one C(17,19) atom. The H(27)-C(17,19) bond length is 1.09 Å. In the twenty-sixth H site, H(29,30,31,32) is bonded in a single-bond geometry to one C(29,32) atom. There are forty inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(5) and one C(33) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(6) and one C(34) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(7) and one C(35) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(8) and one C(36) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one C(33) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Cu(2) and one C(34) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Cu(3) and one C(35) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Cu(4) and one C(36) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Cu(9) and one C(37) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Cu(9) and one C(38) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Cu(10) and one C(39) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one Cu(10) and one C(40) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one C(37) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one C(38) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one C(39) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one C(40) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Cu(10), one Cu(4), and one C(41) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Cu(10), one Cu(3), and one C(42) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Cu(2), one Cu(9), and one C(43) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Cu(1), one Cu(9), and one C(44) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one C(41), one H(1), and one H(16) atom. In the twenty-second O site, O(22) is bonded in a distorted trigonal planar geometry to one C(42), one H(15), and one H(2) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one C(43), one H(14), and one H(3) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one C(44), one H(13), and one H(4) atom. In the twenty-fifth O site, O(25) is bonded in a 3-coordinate geometry to one Cu(4), one Cu(8), and one C(45) atom. In the twenty-sixth O site, O(26) is bonded in a 3-coordinate geometry to one Cu(3); one Cu(7); and one C(46,48) atom. In the twenty-seventh O site, O(27) is bonded in a 3-coordinate geometry to one Cu(2), one Cu(6), and one C(47) atom. In the twenty-eighth O site, O(28) is bonded in a 3-coordinate geometry to one Cu(1); one Cu(5); and one C(46,48) atom. The O(28)-C(46,48) bond length is 1.29 Å. In the twenty-ninth O site, O(29) is bonded in a distorted single-bond geometry to one C(45) atom. In the thirtieth O site, O(30) is bonded in a distorted single-bond geometry to one C(46,48) atom. In the thirty-first O site, O(31) is bonded in a distorted single-bond geometry to one C(47) atom. In the thirty-second O site, O(32) is bonded in a distorted single-bond geometry to one C(46,48) atom. The O(32)-C(46,48) bond length is 1.25 Å. In the thirty-third O site, O(33) is bonded in a 1-coordinate geometry to one Cu(1), one Cu(5), one Cu(7), and one H(5) atom. In the thirty-fourth O site, O(34) is bonded in a 1-coordinate geometry to one Cu(2), one Cu(6), one Cu(8), and one H(6) atom. In the thirty-fifth O site, O(35) is bonded in a 1-coordinate geometry to one Cu(3), one Cu(5), one Cu(7), and one H(7) atom. In the thirty-sixth O site, O(36) is bonded in a 1-coordinate geometry to one Cu(4), one Cu(6), and one H(8) atom. In the thirty-seventh O site, O(37) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one H(13), and one H(9) atom. In the thirty-eighth O site, O(38) is bonded in a distorted trigonal non-coplanar geometry to one Cu(2), one H(10), and one H(14) atom. In the thirty-ninth O site, O(39) is bonded in a distorted trigonal non-coplanar geometry to one Cu(3), one H(11), and one H(15) atom. In the fortieth O site, O(40) is bonded in a distorted trigonal non-coplanar geometry to one Cu(4), one H(12), and one H(16) atom. Linkers: 4 [O]C(=O)c1cc(C([O])=O)c(C([O])=O)cc1C([O])=O ,4 c1nnc[nH]1. Metal clusters: 2 O.O.O=[C]O[Cu]1/N=N\[Cu](O)O[C]O[Cu](O[C]=O)/N=N\[Cu](O)O[C]O1 ,2 O=[C]O[Cu](O[C]=O)(O[C]=O)O[C]=O. The MOF has largest included sphere 2.35 A, density 2.29 g/cm3, surface area 2917.10 m2/g, accessible volume 0.04 cm3/g