AgC13H19S4O3C5H9C3NH6 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two neopentane molecules, two trimethylamine molecules, and two AgC13H19S4O3 clusters. In each AgC13H19S4O3 cluster, Ag(1) is bonded in a 4-coordinate geometry to one S(1), one S(2), one S(3), and one O(1) atom. The Ag(1)-S(1) bond length is 2.46 Å. The Ag(1)-S(2) bond length is 2.58 Å. The Ag(1)-S(3) bond length is 2.51 Å. The Ag(1)-O(1) bond length is 2.49 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one H(1), one H(2), and one S(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.82 Å. In the second C site, C(3) is bonded in a distorted water-like geometry to one H(5), one H(6), and one S(1) atom. The C(3)-H(5) bond length is 1.09 Å. The C(3)-H(6) bond length is 1.10 Å. The C(3)-S(1) bond length is 1.82 Å. In the third C site, C(5) is bonded in a distorted water-like geometry to one H(10), one H(9), and one S(2) atom. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. The C(5)-S(2) bond length is 1.83 Å. In the fourth C site, C(7) is bonded in a distorted water-like geometry to one H(13), one H(14), and one S(2) atom. The C(7)-H(13) bond length is 1.10 Å. The C(7)-H(14) bond length is 1.10 Å. The C(7)-S(2) bond length is 1.84 Å. In the fifth C site, C(9) is bonded in a distorted water-like geometry to one H(17), one H(18), and one S(3) atom. The C(9)-H(17) bond length is 1.10 Å. The C(9)-H(18) bond length is 1.10 Å. The C(9)-S(3) bond length is 1.82 Å. In the sixth C site, C(11) is bonded in a distorted water-like geometry to one H(21), one H(22), and one S(3) atom. The C(11)-H(21) bond length is 1.10 Å. The C(11)-H(22) bond length is 1.10 Å. The C(11)-S(3) bond length is 1.82 Å. In the seventh C site, C(15) is bonded in a trigonal planar geometry to one C(16), one C(21), and one S(4) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(21) bond length is 1.39 Å. The C(15)-S(4) bond length is 1.79 Å. In the eighth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(28) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(28) bond length is 1.09 Å. In the ninth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(29) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-H(29) bond length is 1.09 Å. In the tenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(20) atom. The C(18)-C(19) bond length is 1.50 Å. The C(18)-C(20) bond length is 1.40 Å. In the eleventh C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one C(18), one H(30), one H(31), and one H(32) atom. The C(19)-H(30) bond length is 1.10 Å. The C(19)-H(31) bond length is 1.10 Å. The C(19)-H(32) bond length is 1.10 Å. In the twelfth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(18), one C(21), and one H(33) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(33) bond length is 1.09 Å. In the thirteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(15), one C(20), and one H(34) atom. The C(21)-H(34) bond length is 1.09 Å. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(11) atom. In the thirteenth H site, H(28) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(29) is bonded in a single-bond geometry to one C(17) atom. In the fifteenth H site, H(30) is bonded in a single-bond geometry to one C(19) atom. In the sixteenth H site, H(31) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(32) is bonded in a single-bond geometry to one C(19) atom. In the eighteenth H site, H(33) is bonded in a single-bond geometry to one C(20) atom. In the nineteenth H site, H(34) is bonded in a single-bond geometry to one C(21) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(1), and one C(3) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(5), and one C(7) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(11), and one C(9) atom. In the fourth S site, S(4) is bonded in a distorted trigonal non-coplanar geometry to one C(15), one O(1), one O(2), and one O(3) atom. The S(4)-O(1) bond length is 1.49 Å. The S(4)-O(2) bond length is 1.47 Å. The S(4)-O(3) bond length is 1.46 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Ag(1) and one S(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(4) atom. Linkers: 2 CC12CCSCCN(CCSCC1)CCSCC2. Metal clusters: 2 [Ag]. The MOF has largest included sphere 3.64 A, density 1.50 g/cm3, surface area 4412.45 m2/g, accessible volume 0.13 cm3/g