LiC6H12O3ICH3CHO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four dimethyl ether molecules and four LiC6H12O3I clusters. In each LiC6H12O3I cluster, Li(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(3), one O(4), and one I(1) atom. The Li(1)-O(1) bond length is 1.93 Å. The Li(1)-O(3) bond length is 1.94 Å. The Li(1)-O(4) bond length is 1.94 Å. The Li(1)-I(1) bond length is 2.65 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1); one H(2,7); and one O(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2,7) bond length is 1.10 Å. The C(1)-O(1) bond length is 1.45 Å. In the second C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one H(2,7); one H(8); and one O(1) atom. The C(4)-H(2,7) bond length is 1.10 Å. The C(4)-H(8) bond length is 1.10 Å. The C(4)-O(1) bond length is 1.45 Å. In the third C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one H(10); one H(9,16); and one O(3) atom. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(9,16) bond length is 1.10 Å. The C(5)-O(3) bond length is 1.44 Å. In the fourth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one H(11), one H(12), and one O(4) atom. The C(6)-H(11) bond length is 1.10 Å. The C(6)-H(12) bond length is 1.11 Å. The C(6)-O(4) bond length is 1.44 Å. In the fifth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one H(13), one H(14), and one O(4) atom. The C(7)-H(13) bond length is 1.10 Å. The C(7)-H(14) bond length is 1.10 Å. The C(7)-O(4) bond length is 1.45 Å. In the sixth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one H(15); one H(9,16); and one O(3) atom. The C(8)-H(15) bond length is 1.10 Å. The C(8)-H(9,16) bond length is 1.10 Å. The C(8)-O(3) bond length is 1.45 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2,7) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(9,16) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(8) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to one Li(1), one C(1), and one C(4) atom. In the second O site, O(3) is bonded in a trigonal non-coplanar geometry to one Li(1), one C(5), and one C(8) atom. In the third O site, O(4) is bonded in a trigonal planar geometry to one Li(1), one C(6), and one C(7) atom. I(1) is bonded in a single-bond geometry to one Li(1) atom. Linkers: 4 C1COCCO1. Metal clusters: 4 [Li]. The MOF has largest included sphere 1.69 A, density 1.77 g/cm3, surface area 4534.63 m2/g, accessible volume 0.10 cm3/g