Cu2C16N5H13O7CH2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a Cu2C16N5H13O7 framework. In the Cu2C16N5H13O7 framework, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one N(1), one N(5), one O(1), and two equivalent O(7) atoms to form distorted CuN2O3 trigonal bipyramids that share corners with two equivalent Cu(2)NO4 square pyramids and  an edgeedge with one Cu(1)N2O3 trigonal bipyramid. The Cu(1)-N(1) bond length is 2.07 Å. The Cu(1)-N(5) bond length is 1.99 Å. The Cu(1)-O(1) bond length is 1.97 Å. There is one shorter (1.93 Å) and one longer (2.45 Å) Cu(1)-O(7) bond length. In the second Cu site, Cu(2) is bonded to one N(2), one O(2), one O(3), one O(5), and one O(7) atom to form corner-sharing CuNO4 square pyramids. The Cu(2)-N(2) bond length is 2.02 Å. The Cu(2)-O(2) bond length is 2.28 Å. The Cu(2)-O(3) bond length is 1.97 Å. The Cu(2)-O(5) bond length is 1.95 Å. The Cu(2)-O(7) bond length is 1.93 Å. There are sixteen inequivalent C sites. In the first C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(3), and one O(4) atom. The C(16)-C(11) bond length is 1.50 Å. The C(16)-O(3) bond length is 1.30 Å. The C(16)-O(4) bond length is 1.25 Å. In the second C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(5), and one O(6) atom. The C(17)-C(13) bond length is 1.50 Å. The C(17)-O(5) bond length is 1.28 Å. The C(17)-O(6) bond length is 1.27 Å. In the third C site, C(1) is bonded in a 3-coordinate geometry to one N(3), one H(2), and one H(3) atom. The C(1)-N(3) bond length is 1.48 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. In the fourth C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(6), and one H(7) atom. The C(3)-N(4) bond length is 1.46 Å. The C(3)-H(6) bond length is 1.10 Å. The C(3)-H(7) bond length is 1.10 Å. In the fifth C site, C(4) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(8) atom. The C(4)-N(1) bond length is 1.32 Å. The C(4)-N(3) bond length is 1.36 Å. The C(4)-H(8) bond length is 1.08 Å. In the sixth C site, C(5) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(9) atom. The C(5)-N(2) bond length is 1.32 Å. The C(5)-N(3) bond length is 1.36 Å. The C(5)-H(9) bond length is 1.08 Å. In the seventh C site, C(6) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(10) atom. The C(6)-N(4) bond length is 1.35 Å. The C(6)-N(5) bond length is 1.33 Å. The C(6)-H(10) bond length is 1.08 Å. In the eighth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(5), and one H(11) atom. The C(7)-C(8) bond length is 1.37 Å. The C(7)-N(5) bond length is 1.38 Å. The C(7)-H(11) bond length is 1.08 Å. In the ninth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(4), and one H(12) atom. The C(8)-N(4) bond length is 1.38 Å. The C(8)-H(12) bond length is 1.08 Å. In the tenth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(15) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.40 Å. The C(9)-C(15) bond length is 1.50 Å. In the eleventh C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(13) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(13) bond length is 1.09 Å. In the twelfth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(16) atom. The C(11)-C(12) bond length is 1.40 Å. In the thirteenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(14) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(14) bond length is 1.09 Å. In the fourteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(17) atom. The C(13)-C(14) bond length is 1.40 Å. In the fifteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(9), and one H(15) atom. The C(14)-H(15) bond length is 1.09 Å. In the sixteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(1), and one O(2) atom. The C(15)-O(1) bond length is 1.30 Å. The C(15)-O(2) bond length is 1.25 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(4), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(5), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(5) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(3), one C(6), and one C(8) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(1), one C(6), and one C(7) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. The H(1)-O(7) bond length is 1.00 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(15) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(15) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cu(2) and one C(16) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(16) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(17) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(17) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cu(2), two equivalent Cu(1), and one H(1) atom. Linkers: 4 c1cn(CCCn2cnnc2)cn1 ,4 [O]C(=O)c1cc(C([O])=O)cc(C([O])=O)c1. Metal clusters: 2 O=[C]O[Cu]1(O)(O[C]=O)[N][N][Cu]O[C]O[Cu](O)(O[C]=O)(O[C]=O)[N][N][Cu]O[C]O1. The MOF has largest included sphere 4.20 A, density 1.60 g/cm3, surface area 3663.40 m2/g, accessible volume 0.20 cm3/g