ZnC10H10(NO)4(CH)2(CH2)2C4H4OCH2CO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; four 02329_fluka molecules; two 1-propene, 1-methoxy-, (1z)- molecules; two dimethyl ether molecules; and two ZnC10H10(NO)4 clusters. In each ZnC10H10(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(3), one N(4), one O(3), and one O(5) atom. The Zn(1)-N(3) bond length is 2.01 Å. The Zn(1)-N(4) bond length is 2.00 Å. The Zn(1)-O(3) bond length is 1.98 Å. The Zn(1)-O(5) bond length is 2.00 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(6) atom. The C(1)-O(3) bond length is 1.29 Å. The C(1)-O(6) bond length is 1.25 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(2) atom. The C(3)-N(1) bond length is 1.35 Å. The C(3)-N(3) bond length is 1.34 Å. The C(3)-H(2) bond length is 1.08 Å. In the third C site, C(4) is bonded in a 3-coordinate geometry to one C(15), one N(1), and one H(3) atom. The C(4)-C(15) bond length is 1.37 Å. The C(4)-N(1) bond length is 1.38 Å. The C(4)-H(3) bond length is 1.08 Å. In the fourth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(6), and one H(7) atom. The C(8)-N(2) bond length is 1.46 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-H(7) bond length is 1.10 Å. In the fifth C site, C(9) is bonded in a distorted tetrahedral geometry to one N(1), one H(8), and one H(9) atom. The C(9)-N(1) bond length is 1.47 Å. The C(9)-H(8) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. In the sixth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(13)-O(4) bond length is 1.25 Å. The C(13)-O(5) bond length is 1.29 Å. In the seventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(3), and one H(17) atom. The C(15)-N(3) bond length is 1.38 Å. The C(15)-H(17) bond length is 1.08 Å. In the eighth C site, C(16) is bonded in a trigonal planar geometry to one N(2), one N(4), and one H(18) atom. The C(16)-N(2) bond length is 1.35 Å. The C(16)-N(4) bond length is 1.33 Å. The C(16)-H(18) bond length is 1.09 Å. In the ninth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(20), one N(4), and one H(20) atom. The C(18)-C(20) bond length is 1.37 Å. The C(18)-N(4) bond length is 1.38 Å. The C(18)-H(20) bond length is 1.08 Å. In the tenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(2), and one H(22) atom. The C(20)-N(2) bond length is 1.38 Å. The C(20)-H(22) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(16), and one C(18) atom. There are ten inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(13) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(1) atom. Linkers: 2 c1cn(CCCCn2ccnc2)cn1 ,2 [O]C(=O)COc1ccccc1OCC([O])=O. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 5.50 A, density 1.25 g/cm3, surface area 4818.63 m2/g, accessible volume 0.30 cm3/g