CdC8N5H7O3(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a CdC8N5H7O3 framework. In the CdC8N5H7O3 framework, Cd(1) is bonded to one N(1), one N(2), two equivalent N(3), one O(1), and one O(2) atom to form edge-sharing CdN4O2 octahedra. The Cd(1)-N(1) bond length is 2.33 Å. The Cd(1)-N(2) bond length is 2.33 Å. There is one shorter (2.32 Å) and one longer (2.48 Å) Cd(1)-N(3) bond length. The Cd(1)-O(1) bond length is 2.31 Å. The Cd(1)-O(2) bond length is 2.34 Å. There are eight inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(3) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(10), one C(5), and one N(1) atom. The C(4)-C(10) bond length is 1.49 Å. The C(4)-C(5) bond length is 1.43 Å. The C(4)-N(1) bond length is 1.36 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one O(3) atom. The C(5)-O(3) bond length is 1.34 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(2), and one H(4) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-N(2) bond length is 1.34 Å. The C(6)-H(4) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one O(2) atom. The C(9)-C(10) bond length is 1.43 Å. The C(9)-O(2) bond length is 1.33 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(4), one C(9), and one N(2) atom. The C(10)-N(2) bond length is 1.35 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one N(4) atom. The N(3)-N(4) bond length is 1.20 Å. In the fourth N site, N(4) is bonded in a linear geometry to one N(3) and one N(5) atom. The N(4)-N(5) bond length is 1.17 Å. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(8) atom. The N(5)-H(8) bond length is 1.80 Å. There are seven inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a distorted single-bond geometry to one O(1) and one O(3) atom. The H(7)-O(1) bond length is 1.00 Å. The H(7)-O(3) bond length is 1.68 Å. In the sixth H site, H(8) is bonded in a single-bond geometry to one N(5) and one O(1) atom. The H(8)-O(1) bond length is 0.99 Å. In the seventh H site, H(9) is bonded in a linear geometry to one O(2) and one O(3) atom. The H(9)-O(2) bond length is 1.29 Å. The H(9)-O(3) bond length is 1.11 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1), one H(7), and one H(8) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(9), and one H(9) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one C(5), one H(7), and one H(9) atom. Linkers: 4 [O]c1cccnc1-c1ncccc1O. Metal clusters: 4 [Cd]. The MOF has largest included sphere 1.89 A, density 2.01 g/cm3, surface area 3727.30 m2/g, accessible volume 0.12 cm3/g