MnC12H8(N3O2)2(CH)2 crystallizes in the triclinic P1 space group. The structure consists of four 02329_fluka molecules inside a MnC12H8(N3O2)2 framework. In the MnC12H8(N3O2)2 framework, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in an octahedral geometry to one N(5), one N(9), one O(2), one O(3), one O(6), and one O(7) atom. The Mn(1)-N(5) bond length is 2.17 Å. The Mn(1)-N(9) bond length is 2.15 Å. The Mn(1)-O(2) bond length is 2.31 Å. The Mn(1)-O(3) bond length is 2.31 Å. The Mn(1)-O(6) bond length is 2.15 Å. The Mn(1)-O(7) bond length is 2.17 Å. In the second Mn site, Mn(2) is bonded in an octahedral geometry to one N(10), one N(6), one O(1), one O(4), one O(5), and one O(8) atom. The Mn(2)-N(10) bond length is 2.00 Å. The Mn(2)-N(6) bond length is 1.99 Å. The Mn(2)-O(1) bond length is 2.26 Å. The Mn(2)-O(4) bond length is 2.24 Å. The Mn(2)-O(5) bond length is 2.00 Å. The Mn(2)-O(8) bond length is 2.00 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(27) and one H(1) atom. The C(1)-C(27) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(28) and one H(2) atom. The C(2)-C(28) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(5) atom. The C(3)-O(3) bond length is 1.27 Å. The C(3)-O(5) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. The C(4)-O(4) bond length is 1.28 Å. The C(4)-O(6) bond length is 1.26 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(7) atom. The C(5)-O(1) bond length is 1.28 Å. The C(5)-O(7) bond length is 1.26 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(8) atom. The C(6)-O(2) bond length is 1.27 Å. The C(6)-O(8) bond length is 1.28 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(19), one C(23), and one H(9) atom. The C(9)-C(19) bond length is 1.40 Å. The C(9)-C(23) bond length is 1.39 Å. The C(9)-H(9) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(20), one C(24), and one H(10) atom. The C(10)-C(20) bond length is 1.40 Å. The C(10)-C(24) bond length is 1.39 Å. The C(10)-H(10) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one N(9) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-C(17) bond length is 1.41 Å. The C(11)-N(9) bond length is 1.38 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one N(10) atom. The C(12)-C(14) bond length is 1.40 Å. The C(12)-C(18) bond length is 1.42 Å. The C(12)-N(10) bond length is 1.38 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(11) and one H(11) atom. The C(13)-H(11) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(12) atom. The C(14)-H(12) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(17), one C(25), and one H(13) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-C(25) bond length is 1.39 Å. The C(15)-H(13) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(18), one C(26), and one H(14) atom. The C(16)-C(18) bond length is 1.40 Å. The C(16)-C(26) bond length is 1.39 Å. The C(16)-H(14) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(11), one C(15), and one N(7) atom. The C(17)-N(7) bond length is 1.37 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one N(8) atom. The C(18)-N(8) bond length is 1.37 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(27), one C(9), and one N(11) atom. The C(19)-C(27) bond length is 1.42 Å. The C(19)-N(11) bond length is 1.37 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(10), one C(28), and one N(12) atom. The C(20)-C(28) bond length is 1.42 Å. The C(20)-N(12) bond length is 1.37 Å. In the nineteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(9) and one H(17) atom. The C(23)-H(17) bond length is 1.09 Å. In the twentieth C site, C(24) is bonded in a distorted single-bond geometry to one C(10) and one H(18) atom. The C(24)-H(18) bond length is 1.09 Å. In the twenty-first C site, C(25) is bonded in a distorted single-bond geometry to one C(15) and one H(19) atom. The C(25)-H(19) bond length is 1.09 Å. In the twenty-second C site, C(26) is bonded in a distorted single-bond geometry to one C(16) and one H(20) atom. The C(26)-H(20) bond length is 1.09 Å. In the twenty-third C site, C(27) is bonded in a distorted single-bond geometry to one C(1), one C(19), and one N(5) atom. The C(27)-N(5) bond length is 1.38 Å. In the twenty-fourth C site, C(28) is bonded in a distorted single-bond geometry to one C(2), one C(20), and one N(6) atom. The C(28)-N(6) bond length is 1.39 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one N(11) and one N(5) atom. The N(1)-N(11) bond length is 1.33 Å. The N(1)-N(5) bond length is 1.32 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(12) and one N(6) atom. The N(2)-N(12) bond length is 1.34 Å. The N(2)-N(6) bond length is 1.32 Å. In the third N site, N(3) is bonded in a water-like geometry to one N(7) and one N(9) atom. The N(3)-N(7) bond length is 1.33 Å. The N(3)-N(9) bond length is 1.32 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one N(10) and one N(8) atom. The N(4)-N(10) bond length is 1.32 Å. The N(4)-N(8) bond length is 1.34 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(27), and one N(1) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Mn(2), one C(28), and one N(2) atom. In the seventh N site, N(7) is bonded in a 3-coordinate geometry to one C(17), one N(3), and one H(3) atom. The N(7)-H(3) bond length is 1.05 Å. In the eighth N site, N(8) is bonded in a 3-coordinate geometry to one C(18), one N(4), and one H(4) atom. The N(8)-H(4) bond length is 1.04 Å. In the ninth N site, N(9) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(11), and one N(3) atom. In the tenth N site, N(10) is bonded in a distorted trigonal planar geometry to one Mn(2), one C(12), and one N(4) atom. In the eleventh N site, N(11) is bonded in a 3-coordinate geometry to one C(19), one N(1), and one H(5) atom. The N(11)-H(5) bond length is 1.05 Å. In the twelfth N site, N(12) is bonded in a 3-coordinate geometry to one C(20), one N(2), and one H(6) atom. The N(12)-H(6) bond length is 1.04 Å. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one N(7) and one O(1) atom. The H(3)-O(1) bond length is 1.66 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(8) atom. In the fifth H site, H(5) is bonded in a linear geometry to one N(11) and one O(4) atom. The H(5)-O(4) bond length is 1.66 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(26) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one C(5), and one H(3) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Mn(1) and one C(6) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Mn(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mn(2), one C(4), and one H(5) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(4) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(5) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(6) atom. Linkers: 2 [O]C(=O)C([O])=O. Metal clusters: 2 [Mn]. The MOF has largest included sphere 2.84 A, density 1.59 g/cm3, surface area 4306.91 m2/g, accessible volume 0.20 cm3/g