Zn2C24H18(N2O3)3(CH)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and one Zn2C24H18(N2O3)3 cluster. In the Zn2C24H18(N2O3)3 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(4), and one O(8) atom. The Zn(1)-N(1) bond length is 2.07 Å. The Zn(1)-N(2) bond length is 2.18 Å. The Zn(1)-O(1) bond length is 2.03 Å. The Zn(1)-O(4) bond length is 2.00 Å. The Zn(1)-O(8) bond length is 2.11 Å. In the second Zn site, Zn(2) is bonded in a distorted trigonal bipyramidal geometry to one N(4), one N(5), one O(2), one O(5), and one O(9) atom. The Zn(2)-N(4) bond length is 2.11 Å. The Zn(2)-N(5) bond length is 2.18 Å. The Zn(2)-O(2) bond length is 2.14 Å. The Zn(2)-O(5) bond length is 1.98 Å. The Zn(2)-O(9) bond length is 2.15 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(3) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(3) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(2)-H(4) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(6) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(6) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.46 Å. The C(5)-N(1) bond length is 1.36 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.41 Å. The C(6)-N(2) bond length is 1.35 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(7) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(7) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(3), and one H(8) atom. The C(8)-N(3) bond length is 1.36 Å. The C(8)-H(8) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(10), and one H(9) atom. The C(9)-N(3) bond length is 1.44 Å. The C(9)-H(10) bond length is 1.09 Å. The C(9)-H(9) bond length is 1.10 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(10)-O(1) bond length is 1.28 Å. The C(10)-O(2) bond length is 1.26 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(4), and one H(11) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(4) bond length is 1.34 Å. The C(11)-H(11) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(12) atom. The C(12)-H(12) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(14) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one N(4) atom. The C(15)-C(16) bond length is 1.46 Å. The C(15)-N(4) bond length is 1.36 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one N(5) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-N(5) bond length is 1.35 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(15) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(15) bond length is 1.08 Å. In the sixteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(6), and one H(16) atom. The C(18)-N(6) bond length is 1.36 Å. The C(18)-H(16) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(17), and one H(18) atom. The C(19)-N(6) bond length is 1.45 Å. The C(19)-H(17) bond length is 1.10 Å. The C(19)-H(18) bond length is 1.10 Å. In the eighteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(20)-O(3) bond length is 1.25 Å. The C(20)-O(4) bond length is 1.28 Å. In the nineteenth C site, C(21) is bonded in a trigonal planar geometry to one C(22), one C(26), and one C(27) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(26) bond length is 1.41 Å. The C(21)-C(27) bond length is 1.51 Å. In the twentieth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(19) atom. The C(22)-H(19) bond length is 1.09 Å. In the twenty-first C site, C(25) is bonded in a distorted single-bond geometry to one C(26) and one H(22) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-H(22) bond length is 1.09 Å. In the twenty-second C site, C(26) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(28) atom. The C(26)-C(28) bond length is 1.51 Å. In the twenty-third C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(5), and one O(6) atom. The C(27)-O(5) bond length is 1.30 Å. The C(27)-O(6) bond length is 1.25 Å. In the twenty-fourth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(7), and one O(8) atom. The C(28)-O(7) bond length is 1.27 Å. The C(28)-O(8) bond length is 1.28 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Zn(1), one C(6), and one N(3) atom. The N(2)-N(3) bond length is 1.34 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(8), one C(9), and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(2), one C(11), and one C(15) atom. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one Zn(2), one C(16), and one N(6) atom. The N(5)-N(6) bond length is 1.34 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one C(18), one C(19), and one N(5) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(7) and one O(9) atom. The H(1)-O(7) bond length is 1.63 Å. The H(1)-O(9) bond length is 1.01 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(9) atom. The H(2)-O(9) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(22) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(25) atom. There are nine inequivalent O sites. In the first O site, O(7) is bonded in a bent 120 degrees geometry to one C(28) and one H(1) atom. In the second O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(28) atom. In the third O site, O(9) is bonded in a distorted water-like geometry to one Zn(2), one H(1), and one H(2) atom. In the fourth O site, O(1) is bonded in a 2-coordinate geometry to one Zn(1) and one C(10) atom. In the fifth O site, O(2) is bonded in a water-like geometry to one Zn(2) and one C(10) atom. In the sixth O site, O(3) is bonded in a single-bond geometry to one C(20) atom. In the seventh O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(20) atom. In the eighth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(27) atom. In the ninth O site, O(6) is bonded in a single-bond geometry to one C(27) atom. Linkers: 2 [O]C(=O)c1ccccc1C([O])=O ,4 [O]C(=O)Cn1ccc(-c2ccccn2)n1. Metal clusters: 2 O.O=[C]O[Zn]O[C]O[Zn](O[C]=O)O[C]=O. The MOF has largest included sphere 3.16 A, density 1.70 g/cm3, surface area 4127.27 m2/g, accessible volume 0.13 cm3/g