Co2C28N4H22O11(CH)2(C4H4S)2(C5H4O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four 3-methoxy-2-methylprop-1-ene molecules, two 699-20-7 molecules, and two Co2C28N4H22O11 clusters. In each Co2C28N4H22O11 cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(2), one N(3), one O(12), one O(13), one O(3), and one O(9) atom to form corner-sharing CoN2O4 octahedra. The corner-sharing octahedral tilt angles are 68°. The Co(1)-N(2) bond length is 2.07 Å. The Co(1)-N(3) bond length is 2.10 Å. The Co(1)-O(12) bond length is 2.05 Å. The Co(1)-O(13) bond length is 2.18 Å. The Co(1)-O(3) bond length is 2.08 Å. The Co(1)-O(9) bond length is 2.09 Å. In the second Co site, Co(2) is bonded to one N(1), one N(4), one O(10), one O(11), one O(13), and one O(4) atom to form corner-sharing CoN2O4 octahedra. The corner-sharing octahedral tilt angles are 68°. The Co(2)-N(1) bond length is 2.07 Å. The Co(2)-N(4) bond length is 2.10 Å. The Co(2)-O(10) bond length is 2.09 Å. The Co(2)-O(11) bond length is 2.05 Å. The Co(2)-O(13) bond length is 2.18 Å. The Co(2)-O(4) bond length is 2.08 Å. There are seventeen inequivalent C sites. In the first C site, C(23,24) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17,18) atom. The C(23,24)-N(3) bond length is 1.34 Å. The C(23,24)-H(17,18) bond length is 1.09 Å. In the second C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(23,24) atom. The C(31)-N(3) bond length is 1.35 Å. The C(31)-H(23,24) bond length is 1.09 Å. In the third C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(23,24) atom. The C(32)-N(4) bond length is 1.35 Å. The C(32)-H(23,24) bond length is 1.09 Å. In the fourth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(3) atom. The C(33)-C(1) bond length is 1.51 Å. The C(33)-O(1) bond length is 1.27 Å. The C(33)-O(3) bond length is 1.28 Å. In the fifth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(4) atom. The C(34)-C(2) bond length is 1.51 Å. The C(34)-O(2) bond length is 1.27 Å. The C(34)-O(4) bond length is 1.28 Å. In the sixth C site, C(35,36) is bonded in a distorted trigonal non-coplanar geometry to one C(17,18); one H(25,26); one H(27,28); and one O(5,6) atom. The C(35,36)-C(17,18) bond length is 1.50 Å. The C(35,36)-H(25,26) bond length is 1.10 Å. The C(35,36)-H(27,28) bond length is 1.11 Å. The C(35,36)-O(5,6) bond length is 1.43 Å. In the seventh C site, C(47,48) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(9) atom. The C(47,48)-O(11) bond length is 1.27 Å. The C(47,48)-O(9) bond length is 1.27 Å. In the eighth C site, C(1) is bonded in a trigonal planar geometry to one C(11,12); one C(3,4); and one C(33) atom. The C(1)-C(11,12) bond length is 1.40 Å. The C(1)-C(3,4) bond length is 1.40 Å. In the ninth C site, C(2) is bonded in a trigonal planar geometry to one C(11,12); one C(3,4); and one C(34) atom. The C(2)-C(11,12) bond length is 1.40 Å. The C(2)-C(3,4) bond length is 1.40 Å. In the tenth C site, C(3,4) is bonded in a distorted single-bond geometry to one C(1) and one H(3,4) atom. The C(3,4)-H(3,4) bond length is 1.08 Å. In the eleventh C site, C(5,6) is bonded in a distorted single-bond geometry to one O(5,6) atom. The C(5,6)-O(5,6) bond length is 1.37 Å. In the twelfth C site, C(11,12) is bonded in a distorted single-bond geometry to one C(1) and one H(7,8) atom. The C(11,12)-H(7,8) bond length is 1.09 Å. In the thirteenth C site, C(13,14) is bonded in a distorted bent 120 degrees geometry to one C(15,16); one N(1); and one H(9,10) atom. The C(13,14)-C(15,16) bond length is 1.39 Å. The C(13,14)-N(1) bond length is 1.35 Å. The C(13,14)-H(9,10) bond length is 1.09 Å. In the fourteenth C site, C(15,16) is bonded in a distorted trigonal planar geometry to one C(13,14); one C(17,18); and one H(11,12) atom. The C(15,16)-C(17,18) bond length is 1.40 Å. The C(15,16)-H(11,12) bond length is 1.09 Å. In the fifteenth C site, C(17,18) is bonded in a trigonal planar geometry to one C(15,16); one C(19,20); and one C(35,36) atom. The C(17,18)-C(19,20) bond length is 1.40 Å. In the sixteenth C site, C(19,20) is bonded in a distorted single-bond geometry to one C(17,18) and one H(13,14,21,22) atom. The C(19,20)-H(13,14,21,22) bond length is 1.09 Å. In the seventeenth C site, C(21,22) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(15,16) atom. The C(21,22)-N(1) bond length is 1.35 Å. The C(21,22)-H(15,16) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(2); one C(13,14); and one C(21,22) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1); one C(13,14); and one C(21,22) atom. The N(2)-C(13,14) bond length is 1.35 Å. The N(2)-C(21,22) bond length is 1.35 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1); one C(23,24); and one C(31) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(2); one C(23,24); and one C(32) atom. The N(4)-C(23,24) bond length is 1.34 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(1) and one O(13) atom. The H(1)-O(1) bond length is 1.59 Å. The H(1)-O(13) bond length is 1.02 Å. In the second H site, H(2) is bonded in a distorted linear geometry to one O(13) and one O(2) atom. The H(2)-O(13) bond length is 1.02 Å. The H(2)-O(2) bond length is 1.59 Å. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(3,4) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(11,12) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(13,14) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(15,16) atom. In the seventh H site, H(13,14,21,22) is bonded in a single-bond geometry to one C(19,20) atom. In the eighth H site, H(15,16) is bonded in a single-bond geometry to one C(21,22) atom. In the ninth H site, H(17,18) is bonded in a single-bond geometry to one C(23,24) atom. In the tenth H site, H(23,24) is bonded in a single-bond geometry to one C(31) atom. In the eleventh H site, H(25,26) is bonded in a single-bond geometry to one C(35,36) atom. In the twelfth H site, H(27,28) is bonded in a single-bond geometry to one C(35,36) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(33) and one H(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(34) and one H(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one C(33) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(2) and one C(34) atom. In the fifth O site, O(5,6) is bonded in a bent 120 degrees geometry to one C(35,36) and one C(5,6) atom. In the sixth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(47,48) atom. In the seventh O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(47,48) atom. The O(10)-C(47,48) bond length is 1.27 Å. In the eighth O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(47,48) atom. In the ninth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(47,48) atom. The O(12)-C(47,48) bond length is 1.27 Å. In the tenth O site, O(13) is bonded in a distorted water-like geometry to one Co(1), one Co(2), one H(1), and one H(2) atom. Linkers: 4 [O]C(=O)c1cc(OCc2ccncc2)cc(OCc2ccncc2)c1 ,2 [CH]=[C]COc1cc(OCc2ccncc2)cc(C([O])=O)c1 ,2 [O]C(=O)c1cc([O])cc(OCc2ccncc2)c1 ,2 [O]C(=O)CSc1ccc(SCC([O])=O)cc1. Metal clusters: 2 O.O=[C]O[Co]1O[C]O[Co](O[C]=O)O[C]O1. The MOF has largest included sphere 3.91 A, density 1.38 g/cm3, surface area 4348.77 m2/g, accessible volume 0.24 cm3/g