W6O19(CuH17(C7N2)3)2(CH)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, one CuH17(C7N2)3 cluster, and one W6O19 cluster. In the CuH17(C7N2)3 cluster, Cu(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Cu(1)-N(1) bond length is 2.00 Å. The Cu(1)-N(2) bond length is 2.01 Å. The Cu(1)-N(3) bond length is 2.02 Å. The Cu(1)-N(4) bond length is 2.02 Å. There are twenty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(2) and one H(1) atom. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(2) atom. The C(5)-C(6) bond length is 1.45 Å. The C(5)-N(2) bond length is 1.37 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one N(3) atom. The C(6)-C(7) bond length is 1.41 Å. The C(6)-N(3) bond length is 1.35 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.38 Å. The C(7)-H(5) bond length is 1.08 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(5), and one H(6) atom. The C(8)-N(5) bond length is 1.36 Å. The C(8)-H(6) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one N(5), one H(7), and one H(8) atom. The C(9)-C(10) bond length is 1.50 Å. The C(9)-N(5) bond length is 1.46 Å. The C(9)-H(7) bond length is 1.10 Å. The C(9)-H(8) bond length is 1.10 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(12) bond length is 1.40 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(9) atom. The C(11)-H(9) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one H(10) atom. The C(12)-H(10) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(1), and one H(11) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-N(1) bond length is 1.35 Å. The C(13)-H(11) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(12) atom. The C(14)-H(12) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(14) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(14) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one N(1) atom. The C(17)-C(18) bond length is 1.45 Å. The C(17)-N(1) bond length is 1.37 Å. In the fifteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one N(4) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-N(4) bond length is 1.35 Å. In the sixteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(15) atom. The C(19)-C(20) bond length is 1.38 Å. The C(19)-H(15) bond length is 1.08 Å. In the seventeenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(6), and one H(16) atom. The C(20)-N(6) bond length is 1.36 Å. The C(20)-H(16) bond length is 1.08 Å. In the eighteenth C site, C(21) is bonded in a trigonal planar geometry to one C(22), one C(23), and one C(24) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(23) bond length is 1.51 Å. The C(21)-C(24) bond length is 1.40 Å. In the nineteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(24), and one H(17) atom. The C(22)-C(24) bond length is 1.39 Å. The C(22)-H(17) bond length is 1.09 Å. In the twentieth C site, C(23) is bonded in a distorted trigonal non-coplanar geometry to one C(21), one N(6), one H(18), and one H(19) atom. The C(23)-N(6) bond length is 1.46 Å. The C(23)-H(18) bond length is 1.10 Å. The C(23)-H(19) bond length is 1.10 Å. In the twenty-first C site, C(24) is bonded in a distorted trigonal planar geometry to one C(21), one C(22), and one H(20) atom. The C(24)-H(20) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(17) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Cu(1), one C(6), and one N(5) atom. The N(3)-N(5) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one Cu(1), one C(18), and one N(6) atom. The N(4)-N(6) bond length is 1.35 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(8), one C(9), and one N(3) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one C(20), one C(23), and one N(4) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(22) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(23) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the W6O19 cluster, there are three inequivalent W sites. In the first W site, W(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(6), one O(8), and one O(9) atom. The W(1)-O(2) bond length is 1.73 Å. The W(1)-O(3) bond length is 1.94 Å. The W(1)-O(4) bond length is 1.96 Å. The W(1)-O(6) bond length is 1.93 Å. The W(1)-O(8) bond length is 1.95 Å. The W(1)-O(9) bond length is 2.35 Å. In the second W site, W(2) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(3), one O(7), one O(8), and one O(9) atom. The W(2)-O(1) bond length is 1.73 Å. The W(2)-O(10) bond length is 1.93 Å. The W(2)-O(3) bond length is 1.94 Å. The W(2)-O(7) bond length is 1.95 Å. The W(2)-O(8) bond length is 1.95 Å. The W(2)-O(9) bond length is 2.35 Å. In the third W site, W(3) is bonded in a 6-coordinate geometry to one O(10), one O(4), one O(5), one O(6), one O(7), and one O(9) atom. The W(3)-O(10) bond length is 1.94 Å. The W(3)-O(4) bond length is 1.93 Å. The W(3)-O(5) bond length is 1.73 Å. The W(3)-O(6) bond length is 1.95 Å. The W(3)-O(7) bond length is 1.94 Å. The W(3)-O(9) bond length is 2.35 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one W(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one W(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one W(1) and one W(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one W(1) and one W(3) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one W(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one W(1) and one W(3) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one W(2) and one W(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one W(1) and one W(2) atom. In the ninth O site, O(9) is bonded in an octahedral geometry to two equivalent W(1), two equivalent W(2), and two equivalent W(3) atoms. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one W(2) and one W(3) atom. Linkers: 2 c1ccc(-c2ccn(Cc3ccc(Cn4ccc(-c5ccccn5)n4)cc3)n2)nc1 ,2 [c]1[c]nn(Cc2ccc(Cn3ccc(-c4ccccn4)n3)cc2)c1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.79 A, density 2.73 g/cm3, surface area 2527.08 m2/g, accessible volume 0.10 cm3/g