CuC22H28(NO2)2 is beta Polonium structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CuC22H28(NO2)2 cluster. Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 1.98 Å. Both Cu(1)-O(1) bond lengths are 1.98 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.54 Å. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a tetrahedral geometry to one C(1), one C(3), one C(4), and one C(5) atom. The C(2)-C(3) bond length is 1.53 Å. The C(2)-C(4) bond length is 1.53 Å. The C(2)-C(5) bond length is 1.54 Å. In the third C site, C(3) is bonded in a trigonal non-coplanar geometry to one C(2), one H(1), one H(2), and one H(3) atom. The C(3)-H(1) bond length is 1.10 Å. The C(3)-H(2) bond length is 1.10 Å. The C(3)-H(3) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a trigonal non-coplanar geometry to one C(2), one H(4), one H(5), and one H(6) atom. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. The C(4)-H(6) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a trigonal non-coplanar geometry to one C(2), one H(7), one H(8), and one H(9) atom. The C(5)-H(7) bond length is 1.10 Å. The C(5)-H(8) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one H(10) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-N(1) bond length is 1.34 Å. The C(6)-H(10) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(11) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-H(11) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(7), and one C(9) atom. The C(8)-C(11) bond length is 1.45 Å. The C(8)-C(9) bond length is 1.41 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(12) atom. The C(9)-H(12) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one N(1) and one H(13) atom. The C(10)-N(1) bond length is 1.35 Å. The C(10)-H(13) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(8) and one H(14) atom. The C(11)-H(14) bond length is 1.10 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(6) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Linkers: 1 C(=C/c1ccncc1)\c1ccncc1 ,2 [c]1cc(/C=C/c2ccncc2)ccn1. Metal clusters: 1 [Cu]. The MOF has largest included sphere 2.67 A, density 1.30 g/cm3, surface area 5869.72 m2/g, accessible volume 0.18 cm3/g