CuC4NH2O4(CH2)3C5H5NCH3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules; four allylamine, n,n,2-trimethyl- molecules; and two CuC4NH2O4 clusters. In each CuC4NH2O4 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-N(1) bond length is 2.18 Å. The Cu(1)-O(1) bond length is 2.00 Å. The Cu(1)-O(2) bond length is 2.00 Å. The Cu(1)-O(3) bond length is 2.01 Å. The Cu(1)-O(4) bond length is 2.02 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(9)-O(1) bond length is 1.28 Å. The C(9)-O(2) bond length is 1.27 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(13)-O(3) bond length is 1.27 Å. The C(13)-O(4) bond length is 1.27 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(9) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(9) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(13) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(13) atom. Linkers: 2 c1cc(CN2CCN(Cc3ccncc3)CC2)ccn1 ,4 [O]C(=O)CCCC([O])=O. Metal clusters: 2 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 3.38 A, density 1.43 g/cm3, surface area 4487.17 m2/g, accessible volume 0.23 cm3/g