(CH)2ZnC12H10(N4Cl)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one ZnC12H10(N4Cl)2 cluster. In the ZnC12H10(N4Cl)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(6), one Cl(1), and one Cl(2) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-N(6) bond length is 2.03 Å. The Zn(1)-Cl(1) bond length is 2.23 Å. The Zn(1)-Cl(2) bond length is 2.25 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(3) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(7), one N(3), one H(3), and one H(4) atom. The C(3)-C(7) bond length is 1.51 Å. The C(3)-N(3) bond length is 1.46 Å. The C(3)-H(3) bond length is 1.09 Å. The C(3)-H(4) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(13), one C(7), and one N(7) atom. The C(4)-C(13) bond length is 1.51 Å. The C(4)-C(7) bond length is 1.43 Å. The C(4)-N(7) bond length is 1.32 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(12), one C(9), and one N(7) atom. The C(5)-C(12) bond length is 1.42 Å. The C(5)-C(9) bond length is 1.43 Å. The C(5)-N(7) bond length is 1.36 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(5) atom. The C(6)-N(4) bond length is 1.32 Å. The C(6)-N(6) bond length is 1.37 Å. The C(6)-H(5) bond length is 1.08 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(3), one C(4), and one N(8) atom. The C(7)-N(8) bond length is 1.32 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(6) atom. The C(8)-N(5) bond length is 1.34 Å. The C(8)-N(6) bond length is 1.34 Å. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(11), one C(5), and one N(8) atom. The C(9)-C(11) bond length is 1.42 Å. The C(9)-N(8) bond length is 1.36 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(11)-H(8) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(5) and one H(9) atom. The C(12)-H(9) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one N(5), one H(10), and one H(11) atom. The C(13)-N(5) bond length is 1.46 Å. The C(13)-H(10) bond length is 1.10 Å. The C(13)-H(11) bond length is 1.10 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(1) and one N(3) atom. The N(2)-N(3) bond length is 1.36 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted water-like geometry to one C(6) and one N(5) atom. The N(4)-N(5) bond length is 1.36 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(13), one C(8), and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(1), one C(6), and one C(8) atom. In the seventh N site, N(7) is bonded in a bent 120 degrees geometry to one C(4) and one C(5) atom. In the eighth N site, N(8) is bonded in a bent 120 degrees geometry to one C(7) and one C(9) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 1 c1ccc2nc(Cn3cncn3)c(Cn3cncn3)nc2c1 ,1 [c]1[c]c2nc(Cn3cncn3)c(CN3[CH]N=C[N]3)nc2cc1 ,1 [CH]1N=C[N]N1Cc1nc2ccccc2nc1Cn1cncn1 ,1 [c]1[c]c2nc(Cn3cncn3)c(Cn3cncn3)nc2cc1. Metal clusters: 2 Cl[Zn]Cl. The MOF has largest included sphere 1.73 A, density 1.78 g/cm3, surface area 4508.96 m2/g, accessible volume 0.11 cm3/g