ZnC15N3H14O5CH is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and four ZnC15N3H14O5 clusters. In each ZnC15N3H14O5 cluster, Zn(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one O(1), one O(2), and one O(5) atom. The Zn(1)-N(1) bond length is 2.12 Å. The Zn(1)-N(2) bond length is 2.21 Å. The Zn(1)-N(3) bond length is 2.11 Å. The Zn(1)-O(1) bond length is 2.20 Å. The Zn(1)-O(2) bond length is 2.18 Å. The Zn(1)-O(5) bond length is 2.04 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one N(2), one H(4), and one H(5) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-N(2) bond length is 1.46 Å. The C(1)-H(4) bond length is 1.10 Å. The C(1)-H(5) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(3) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(3) bond length is 1.35 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(6) atom. The C(3)-H(6) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(6) and one H(7) atom. The C(4)-C(6) bond length is 1.39 Å. The C(4)-H(7) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(4), one N(3), and one H(9) atom. The C(6)-N(3) bond length is 1.34 Å. The C(6)-H(9) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(8), one N(2), one H(10), and one H(11) atom. The C(7)-C(8) bond length is 1.52 Å. The C(7)-N(2) bond length is 1.46 Å. The C(7)-H(10) bond length is 1.10 Å. The C(7)-H(11) bond length is 1.10 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(1) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-N(1) bond length is 1.34 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(12) atom. The C(9)-H(12) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(13) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(13) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(14) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(14) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one H(15) atom. The C(12)-N(1) bond length is 1.34 Å. The C(12)-H(15) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one O(1) atom. The C(13)-O(1) bond length is 1.26 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one O(2) atom. The C(14)-O(2) bond length is 1.27 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one O(3) atom. The C(15)-O(3) bond length is 1.26 Å. In the fifteenth C site, C(16) is bonded in a distorted single-bond geometry to one O(4) atom. The C(16)-O(4) bond length is 1.26 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(12), and one C(8) atom. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Zn(1), one C(1), one C(7), and one H(3) atom. The N(2)-H(3) bond length is 1.02 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(2), and one C(6) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(4) and one O(5) atom. The H(1)-O(4) bond length is 1.55 Å. The H(1)-O(5) bond length is 1.02 Å. In the second H site, H(2) is bonded in a distorted linear geometry to one O(3) and one O(5) atom. The H(2)-O(3) bond length is 1.56 Å. The H(2)-O(5) bond length is 1.02 Å. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(11) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(12) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(15) and one H(2) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(16) and one H(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one H(1), and one H(2) atom. Linkers: 2 c1ccc(CNCc2ccccn2)nc1 ,4 O=C1C(=O)C(=O)C1=O. Metal clusters: 4 [Zn]. The MOF has largest included sphere 3.08 A, density 1.50 g/cm3, surface area 4709.07 m2/g, accessible volume 0.21 cm3/g