AuCuC4N2H4S(CH2)2 crystallizes in the monoclinic Cc space group. The structure consists of sixteen 02329_fluka molecules inside a AuCuC4N2H4S framework. In each AuCuC4N2H4S framework, there are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a linear geometry to one C(1) and one C(2) atom. The Au(1)-C(1) bond length is 1.98 Å. The Au(1)-C(2) bond length is 1.97 Å. In the second Au site, Au(2) is bonded in a linear geometry to one C(3) and one C(4) atom. The Au(2)-C(3) bond length is 1.97 Å. The Au(2)-C(4) bond length is 1.97 Å. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one N(1), one N(4), one S(1), and one S(2) atom to form distorted corner-sharing CuS2N2 tetrahedra. The Cu(1)-N(1) bond length is 1.92 Å. The Cu(1)-N(4) bond length is 1.90 Å. The Cu(1)-S(1) bond length is 2.27 Å. The Cu(1)-S(2) bond length is 2.44 Å. In the second Cu site, Cu(2) is bonded to one N(2), one N(3), one S(1), and one S(2) atom to form corner-sharing CuS2N2 tetrahedra. The Cu(2)-N(2) bond length is 1.91 Å. The Cu(2)-N(3) bond length is 1.93 Å. The Cu(2)-S(1) bond length is 2.37 Å. The Cu(2)-S(2) bond length is 2.32 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one Au(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. In the second C site, C(2) is bonded in a single-bond geometry to one Au(1) and one N(2) atom. The C(2)-N(2) bond length is 1.17 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one Au(2) and one N(3) atom. The C(3)-N(3) bond length is 1.17 Å. In the fourth C site, C(4) is bonded in a single-bond geometry to one Au(2) and one N(4) atom. The C(4)-N(4) bond length is 1.17 Å. In the fifth C site, C(5) is bonded in a distorted water-like geometry to one H(1), one H(2), and one S(1) atom. The C(5)-H(1) bond length is 1.10 Å. The C(5)-H(2) bond length is 1.10 Å. The C(5)-S(1) bond length is 1.85 Å. In the sixth C site, C(8) is bonded in a distorted water-like geometry to one H(7), one H(8), and one S(1) atom. The C(8)-H(7) bond length is 1.10 Å. The C(8)-H(8) bond length is 1.10 Å. The C(8)-S(1) bond length is 1.84 Å. In the seventh C site, C(9) is bonded in a distorted water-like geometry to one H(10), one H(9), and one S(2) atom. The C(9)-H(10) bond length is 1.09 Å. The C(9)-H(9) bond length is 1.09 Å. The C(9)-S(2) bond length is 1.84 Å. In the eighth C site, C(12) is bonded in a distorted water-like geometry to one H(15), one H(16), and one S(2) atom. The C(12)-H(15) bond length is 1.10 Å. The C(12)-H(16) bond length is 1.10 Å. The C(12)-S(2) bond length is 1.83 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Cu(1) and one C(1) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Cu(2) and one C(2) atom. In the third N site, N(3) is bonded in a linear geometry to one Cu(2) and one C(3) atom. In the fourth N site, N(4) is bonded in a linear geometry to one Cu(1) and one C(4) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one Cu(1), one Cu(2), one C(5), and one C(8) atom to form corner-sharing SCu2C2 tetrahedra. In the second S site, S(2) is bonded to one Cu(1), one Cu(2), one C(12), and one C(9) atom to form corner-sharing SCu2C2 trigonal pyramids. Linkers: 4 C1CCSC1 ,8 [C]#N. Metal clusters: 4 [Cu] ,4 [Au]. The MOF has largest included sphere 2.61 A, density 2.91 g/cm3, surface area 2678.61 m2/g, accessible volume 0.12 cm3/g