CdC32N2H18O5(CH)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and one CdC32N2H18O5 cluster. In the CdC32N2H18O5 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(4), and one O(5) atom. The Cd(1)-N(1) bond length is 2.41 Å. The Cd(1)-N(2) bond length is 2.35 Å. The Cd(1)-O(1) bond length is 2.42 Å. The Cd(1)-O(2) bond length is 2.53 Å. The Cd(1)-O(4) bond length is 2.32 Å. The Cd(1)-O(5) bond length is 2.29 Å. There are thirty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(13), one C(2), and one C(4) atom. The C(3)-C(13) bond length is 1.48 Å. The C(3)-C(4) bond length is 1.43 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(12) bond length is 1.43 Å. The C(4)-C(5) bond length is 1.42 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.45 Å. The C(5)-N(1) bond length is 1.36 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(10), one C(5), and one N(2) atom. The C(6)-C(10) bond length is 1.42 Å. The C(6)-N(2) bond length is 1.35 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(3) atom. The C(7)-N(2) bond length is 1.33 Å. The C(7)-H(3) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(4) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(19), and one C(8) atom. The C(9)-C(10) bond length is 1.43 Å. The C(9)-C(19) bond length is 1.48 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(9) atom. The C(10)-C(11) bond length is 1.43 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(11)-H(5) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(12)-H(6) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(3) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(18) bond length is 1.41 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(7) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(7) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(8) atom. The C(15)-H(8) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(9) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(9) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(10) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(10) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one H(11) atom. The C(18)-H(11) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(9) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-C(22) bond length is 1.41 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(12,14) atom. The C(20)-H(12,14) bond length is 1.09 Å. In the twenty-first C site, C(22) is bonded in a distorted single-bond geometry to one C(19) and one H(12,14) atom. The C(22)-H(12,14) bond length is 1.09 Å. In the twenty-second C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(1), and one O(2) atom. The C(23)-C(24) bond length is 1.50 Å. The C(23)-O(1) bond length is 1.28 Å. The C(23)-O(2) bond length is 1.27 Å. In the twenty-third C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(29) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-C(29) bond length is 1.40 Å. In the twenty-fourth C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(15) atom. The C(25)-H(15) bond length is 1.09 Å. In the twenty-fifth C site, C(27) is bonded in a distorted single-bond geometry to one C(28) and one O(3) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-O(3) bond length is 1.40 Å. In the twenty-sixth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one C(29), and one H(17) atom. The C(28)-C(29) bond length is 1.39 Å. The C(28)-H(17) bond length is 1.09 Å. In the twenty-seventh C site, C(29) is bonded in a distorted single-bond geometry to one C(24), one C(28), and one H(18) atom. The C(29)-H(18) bond length is 1.09 Å. In the twenty-eighth C site, C(30) is bonded in a distorted single-bond geometry to one O(3) atom. The C(30)-O(3) bond length is 1.39 Å. In the twenty-ninth C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(20,21) atom. The C(32)-C(33) bond length is 1.40 Å. The C(32)-H(20,21) bond length is 1.09 Å. In the thirtieth C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(36) atom. The C(33)-C(34) bond length is 1.40 Å. The C(33)-C(36) bond length is 1.50 Å. In the thirty-first C site, C(34) is bonded in a distorted single-bond geometry to one C(33) and one H(20,21) atom. The C(34)-H(20,21) bond length is 1.09 Å. In the thirty-second C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(33), one O(4), and one O(5) atom. The C(36)-O(4) bond length is 1.27 Å. The C(36)-O(5) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(6), and one C(7) atom. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(12,14) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(28) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(29) atom. In the sixteenth H site, H(20,21) is bonded in a single-bond geometry to one C(32) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(23) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cd(1) and one C(23) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(27) and one C(30) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(36) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Cd(1) and one C(36) atom. Linkers: 2 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 1 [C]1O[Cd]2(O1)O[C]O[Cd]1(O[C]O1)O[C]O2. The MOF has largest included sphere 2.62 A, density 1.63 g/cm3, surface area 4450.61 m2/g, accessible volume 0.17 cm3/g