(ZnC12H8(N2I)2)6(CH2)5(CH)2CH3COC4H2O3C7H7O crystallizes in the triclinic P1 space group. The structure consists of four 02329_fluka molecules, ten 02329_fluka molecules, two 02329_fluka molecules, two benzyl alcohol molecules, two formaldehyde molecules, and two trimethoxymethane molecules inside a ZnC12H8(N2I)2 framework. In each ZnC12H8(N2I)2 framework, there are five inequivalent Zn sites. In the first Zn site, Zn(1,2) is bonded in a distorted tetrahedral geometry to one N(1); one N(21,22); one I(1); and one I(3) atom. The Zn(1,2)-N(1) bond length is 2.12 Å. The Zn(1,2)-N(21,22) bond length is 2.08 Å. The Zn(1,2)-I(1) bond length is 2.56 Å. The Zn(1,2)-I(3) bond length is 2.55 Å. In the second Zn site, Zn(3) is bonded in a distorted tetrahedral geometry to one N(24); one N(9); one I(5,6); and one I(7,8) atom. The Zn(3)-N(24) bond length is 2.09 Å. The Zn(3)-N(9) bond length is 2.09 Å. The Zn(3)-I(5,6) bond length is 2.54 Å. The Zn(3)-I(7,8) bond length is 2.56 Å. In the third Zn site, Zn(4) is bonded in a distorted tetrahedral geometry to one N(10); one N(23); one I(5,6); and one I(7,8) atom. The Zn(4)-N(10) bond length is 2.09 Å. The Zn(4)-N(23) bond length is 2.09 Å. The Zn(4)-I(5,6) bond length is 2.54 Å. The Zn(4)-I(7,8) bond length is 2.56 Å. In the fourth Zn site, Zn(5) is bonded in a distorted tetrahedral geometry to one N(11), one N(13), one I(11), and one I(9) atom. The Zn(5)-N(11) bond length is 2.10 Å. The Zn(5)-N(13) bond length is 2.10 Å. The Zn(5)-I(11) bond length is 2.55 Å. The Zn(5)-I(9) bond length is 2.55 Å. In the fifth Zn site, Zn(6) is bonded in a distorted tetrahedral geometry to one N(12), one N(14), one I(10), and one I(12) atom. The Zn(6)-N(12) bond length is 2.10 Å. The Zn(6)-N(14) bond length is 2.10 Å. The Zn(6)-I(10) bond length is 2.55 Å. The Zn(6)-I(12) bond length is 2.55 Å. There are forty-five inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal planar geometry to one C(3,4); one N(1); and one H(1,2) atom. The C(1,2)-C(3,4) bond length is 1.39 Å. The C(1,2)-N(1) bond length is 1.35 Å. The C(1,2)-H(1,2) bond length is 1.09 Å. In the second C site, C(3,4) is bonded in a distorted trigonal planar geometry to one C(1,2); one C(5,6); and one H(3,4) atom. The C(3,4)-C(5,6) bond length is 1.40 Å. The C(3,4)-H(3,4) bond length is 1.09 Å. In the third C site, C(5,6) is bonded in a trigonal planar geometry to one C(11,12); one C(3,4); and one C(7,8) atom. The C(5,6)-C(11,12) bond length is 1.48 Å. The C(5,6)-C(7,8) bond length is 1.40 Å. In the fourth C site, C(7,8) is bonded in a distorted single-bond geometry to one C(5,6); one C(9,10); and one H(5,6) atom. The C(7,8)-C(9,10) bond length is 1.39 Å. The C(7,8)-H(5,6) bond length is 1.09 Å. In the fifth C site, C(9,10) is bonded in a distorted trigonal planar geometry to one C(7,8); one N(1); and one H(7,8) atom. The C(9,10)-N(1) bond length is 1.35 Å. The C(9,10)-H(7,8) bond length is 1.09 Å. In the sixth C site, C(11,12) is bonded in a distorted trigonal planar geometry to one C(5,6); one N(3,4); and one N(7,8) atom. The C(11,12)-N(3,4) bond length is 1.34 Å. The C(11,12)-N(7,8) bond length is 1.34 Å. In the seventh C site, C(13,14) is bonded in a distorted bent 120 degrees geometry to one C(21,22); one N(3,4); and one N(5,6) atom. The C(13,14)-C(21,22) bond length is 1.48 Å. The C(13,14)-N(3,4) bond length is 1.35 Å. The C(13,14)-N(5,6) bond length is 1.35 Å. In the eighth C site, C(15,16) is bonded in a distorted bent 120 degrees geometry to one C(31,32); one N(5,6); and one N(7,8) atom. The C(15,16)-C(31,32) bond length is 1.48 Å. The C(15,16)-N(5,6) bond length is 1.34 Å. The C(15,16)-N(7,8) bond length is 1.34 Å. In the ninth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(19,20); one N(9); and one H(9,10) atom. The C(17)-C(19,20) bond length is 1.39 Å. The C(17)-N(9) bond length is 1.35 Å. The C(17)-H(9,10) bond length is 1.09 Å. In the tenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(19,20); one N(10); and one H(9,10) atom. The C(18)-C(19,20) bond length is 1.39 Å. The C(18)-N(10) bond length is 1.35 Å. The C(18)-H(9,10) bond length is 1.09 Å. In the eleventh C site, C(19,20) is bonded in a distorted single-bond geometry to one C(17); one C(21,22); and one H(11,12) atom. The C(19,20)-C(21,22) bond length is 1.40 Å. The C(19,20)-H(11,12) bond length is 1.09 Å. In the twelfth C site, C(21,22) is bonded in a trigonal planar geometry to one C(13,14); one C(19,20); and one C(23,24) atom. The C(21,22)-C(23,24) bond length is 1.40 Å. In the thirteenth C site, C(23,24) is bonded in a distorted single-bond geometry to one C(21,22) and one H(13,14) atom. The C(23,24)-H(13,14) bond length is 1.09 Å. In the fourteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(15,16) atom. The C(25)-N(9) bond length is 1.35 Å. The C(25)-H(15,16) bond length is 1.09 Å. In the fifteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(15,16) atom. The C(26)-N(10) bond length is 1.35 Å. The C(26)-H(15,16) bond length is 1.09 Å. In the sixteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(17,18) atom. The C(27)-N(11) bond length is 1.35 Å. The C(27)-H(17,18) bond length is 1.09 Å. In the seventeenth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(12) and one H(17,18) atom. The C(28)-N(12) bond length is 1.35 Å. The C(28)-H(17,18) bond length is 1.09 Å. In the eighteenth C site, C(29,30) is bonded in a distorted single-bond geometry to one C(31,32) and one H(19,20) atom. The C(29,30)-C(31,32) bond length is 1.40 Å. The C(29,30)-H(19,20) bond length is 1.09 Å. In the nineteenth C site, C(31,32) is bonded in a trigonal planar geometry to one C(15,16); one C(29,30); and one C(33,34) atom. The C(31,32)-C(33,34) bond length is 1.40 Å. In the twentieth C site, C(33,34) is bonded in a distorted single-bond geometry to one C(31,32); one C(35); and one H(21,22) atom. The C(33,34)-C(35) bond length is 1.39 Å. The C(33,34)-H(21,22) bond length is 1.09 Å. In the twenty-first C site, C(35) is bonded in a distorted trigonal planar geometry to one C(33,34); one N(11); and one H(23,24) atom. The C(35)-N(11) bond length is 1.35 Å. The C(35)-H(23,24) bond length is 1.09 Å. In the twenty-second C site, C(36) is bonded in a distorted trigonal planar geometry to one C(33,34); one N(12); and one H(23,24) atom. The C(36)-C(33,34) bond length is 1.39 Å. The C(36)-N(12) bond length is 1.35 Å. The C(36)-H(23,24) bond length is 1.09 Å. In the twenty-third C site, C(37,38) is bonded in a distorted trigonal planar geometry to one C(39), one N(13), and one H(25) atom. The C(37,38)-C(39) bond length is 1.39 Å. The C(37,38)-N(13) bond length is 1.35 Å. The C(37,38)-H(25) bond length is 1.09 Å. In the twenty-fourth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(37,38); one C(41,42); and one H(27,28) atom. The C(39)-C(41,42) bond length is 1.40 Å. The C(39)-H(27,28) bond length is 1.09 Å. In the twenty-fifth C site, C(40) is bonded in a distorted trigonal planar geometry to one C(37,38); one C(41,42); and one H(27,28) atom. The C(40)-C(37,38) bond length is 1.39 Å. The C(40)-C(41,42) bond length is 1.40 Å. The C(40)-H(27,28) bond length is 1.09 Å. In the twenty-sixth C site, C(41,42) is bonded in a trigonal planar geometry to one C(39); one C(43); and one C(47,48) atom. The C(41,42)-C(43) bond length is 1.40 Å. The C(41,42)-C(47,48) bond length is 1.48 Å. In the twenty-seventh C site, C(43) is bonded in a distorted trigonal planar geometry to one C(41,42); one C(45); and one H(29,30) atom. The C(43)-C(45) bond length is 1.39 Å. The C(43)-H(29,30) bond length is 1.09 Å. In the twenty-eighth C site, C(44) is bonded in a distorted trigonal planar geometry to one C(41,42); one C(46); and one H(29,30) atom. The C(44)-C(41,42) bond length is 1.40 Å. The C(44)-C(46) bond length is 1.39 Å. The C(44)-H(29,30) bond length is 1.09 Å. In the twenty-ninth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(43), one N(13), and one H(31) atom. The C(45)-N(13) bond length is 1.35 Å. The C(45)-H(31) bond length is 1.09 Å. In the thirtieth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one C(44), one N(14), and one H(32) atom. The C(46)-N(14) bond length is 1.35 Å. The C(46)-H(32) bond length is 1.09 Å. In the thirty-first C site, C(47,48) is bonded in a distorted trigonal planar geometry to one C(41,42); one N(15,16); and one N(19,20) atom. The C(47,48)-N(15,16) bond length is 1.34 Å. The C(47,48)-N(19,20) bond length is 1.34 Å. In the thirty-second C site, C(49,50) is bonded in a distorted trigonal planar geometry to one C(57,58); one N(15,16); and one N(17,18) atom. The C(49,50)-C(57,58) bond length is 1.48 Å. The C(49,50)-N(15,16) bond length is 1.34 Å. The C(49,50)-N(17,18) bond length is 1.34 Å. In the thirty-third C site, C(51,52) is bonded in a distorted trigonal planar geometry to one C(67,68); one N(17,18); and one N(19,20) atom. The C(51,52)-C(67,68) bond length is 1.48 Å. The C(51,52)-N(17,18) bond length is 1.34 Å. The C(51,52)-N(19,20) bond length is 1.34 Å. In the thirty-fourth C site, C(53,54) is bonded in a distorted trigonal planar geometry to one C(55,56); one N(21,22); and one H(33,34) atom. The C(53,54)-C(55,56) bond length is 1.39 Å. The C(53,54)-N(21,22) bond length is 1.35 Å. The C(53,54)-H(33,34) bond length is 1.09 Å. In the thirty-fifth C site, C(55,56) is bonded in a distorted single-bond geometry to one C(53,54); one C(57,58); and one H(35,36) atom. The C(55,56)-C(57,58) bond length is 1.40 Å. The C(55,56)-H(35,36) bond length is 1.09 Å. In the thirty-sixth C site, C(57,58) is bonded in a trigonal planar geometry to one C(49,50); one C(55,56); and one C(59,60) atom. The C(57,58)-C(59,60) bond length is 1.40 Å. In the thirty-seventh C site, C(59,60) is bonded in a distorted trigonal planar geometry to one C(57,58); one C(61,62); and one H(37,38) atom. The C(59,60)-C(61,62) bond length is 1.39 Å. The C(59,60)-H(37,38) bond length is 1.09 Å. In the thirty-eighth C site, C(61,62) is bonded in a distorted bent 120 degrees geometry to one C(59,60); one N(21,22); and one H(39,40) atom. The C(61,62)-N(21,22) bond length is 1.35 Å. The C(61,62)-H(39,40) bond length is 1.09 Å. In the thirty-ninth C site, C(63) is bonded in a distorted trigonal planar geometry to one C(65,66); one N(23); and one H(41,42) atom. The C(63)-C(65,66) bond length is 1.39 Å. The C(63)-N(23) bond length is 1.35 Å. The C(63)-H(41,42) bond length is 1.09 Å. In the fortieth C site, C(64) is bonded in a distorted trigonal planar geometry to one C(65,66); one N(24); and one H(41,42) atom. The C(64)-C(65,66) bond length is 1.39 Å. The C(64)-N(24) bond length is 1.35 Å. The C(64)-H(41,42) bond length is 1.09 Å. In the forty-first C site, C(65,66) is bonded in a distorted single-bond geometry to one C(63); one C(67,68); and one H(43,44) atom. The C(65,66)-C(67,68) bond length is 1.40 Å. The C(65,66)-H(43,44) bond length is 1.09 Å. In the forty-second C site, C(67,68) is bonded in a trigonal planar geometry to one C(51,52); one C(65,66); and one C(69,70) atom. The C(67,68)-C(69,70) bond length is 1.40 Å. In the forty-third C site, C(69,70) is bonded in a distorted trigonal planar geometry to one C(67,68); one C(71); and one H(45,46) atom. The C(69,70)-C(71) bond length is 1.39 Å. The C(69,70)-H(45,46) bond length is 1.09 Å. In the forty-fourth C site, C(71) is bonded in a distorted trigonal planar geometry to one C(69,70); one N(23); and one H(47,48) atom. The C(71)-N(23) bond length is 1.35 Å. The C(71)-H(47,48) bond length is 1.09 Å. In the forty-fifth C site, C(72) is bonded in a distorted trigonal planar geometry to one C(69,70); one N(24); and one H(47,48) atom. The C(72)-C(69,70) bond length is 1.39 Å. The C(72)-N(24) bond length is 1.35 Å. The C(72)-H(47,48) bond length is 1.09 Å. There are seventeen inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1,2); one C(1,2); and one C(9,10) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1,2); one C(1,2); and one C(9,10) atom. The N(2)-Zn(1,2) bond length is 2.12 Å. The N(2)-C(1,2) bond length is 1.35 Å. The N(2)-C(9,10) bond length is 1.35 Å. In the third N site, N(3,4) is bonded in a bent 120 degrees geometry to one C(11,12) and one C(13,14) atom. In the fourth N site, N(5,6) is bonded in a bent 120 degrees geometry to one C(13,14) and one C(15,16) atom. In the fifth N site, N(7,8) is bonded in a bent 120 degrees geometry to one C(11,12) and one C(15,16) atom. In the sixth N site, N(9) is bonded in a trigonal planar geometry to one Zn(3), one C(17), and one C(25) atom. In the seventh N site, N(10) is bonded in a trigonal planar geometry to one Zn(4), one C(18), and one C(26) atom. In the eighth N site, N(11) is bonded in a trigonal planar geometry to one Zn(5), one C(27), and one C(35) atom. In the ninth N site, N(12) is bonded in a trigonal planar geometry to one Zn(6), one C(28), and one C(36) atom. In the tenth N site, N(13) is bonded in a trigonal planar geometry to one Zn(5); one C(37,38); and one C(45) atom. In the eleventh N site, N(14) is bonded in a trigonal planar geometry to one Zn(6); one C(37,38); and one C(46) atom. The N(14)-C(37,38) bond length is 1.35 Å. In the twelfth N site, N(15,16) is bonded in a bent 120 degrees geometry to one C(47,48) and one C(49,50) atom. In the thirteenth N site, N(17,18) is bonded in a bent 120 degrees geometry to one C(49,50) and one C(51,52) atom. In the fourteenth N site, N(19,20) is bonded in a bent 120 degrees geometry to one C(47,48) and one C(51,52) atom. In the fifteenth N site, N(21,22) is bonded in a trigonal planar geometry to one Zn(1,2); one C(53,54); and one C(61,62) atom. In the sixteenth N site, N(23) is bonded in a trigonal planar geometry to one Zn(4), one C(63), and one C(71) atom. In the seventeenth N site, N(24) is bonded in a trigonal planar geometry to one Zn(3), one C(64), and one C(72) atom. There are twenty-six inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(3,4) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(7,8) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(9,10) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(19,20) atom. In the seventh H site, H(13,14) is bonded in a single-bond geometry to one C(23,24) atom. In the eighth H site, H(15,16) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(17,18) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(19,20) is bonded in a single-bond geometry to one C(29,30) atom. In the eleventh H site, H(21,22) is bonded in a single-bond geometry to one C(33,34) atom. In the twelfth H site, H(23,24) is bonded in a single-bond geometry to one C(35) atom. In the thirteenth H site, H(25) is bonded in a single-bond geometry to one C(37,38) atom. In the fourteenth H site, H(26) is bonded in a single-bond geometry to one C(37,38) atom. The H(26)-C(37,38) bond length is 1.09 Å. In the fifteenth H site, H(27,28) is bonded in a single-bond geometry to one C(39) atom. In the sixteenth H site, H(29,30) is bonded in a single-bond geometry to one C(43) atom. In the seventeenth H site, H(31) is bonded in a single-bond geometry to one C(45) atom. In the eighteenth H site, H(32) is bonded in a single-bond geometry to one C(46) atom. In the nineteenth H site, H(33,34) is bonded in a single-bond geometry to one C(53,54) atom. In the twentieth H site, H(35,36) is bonded in a single-bond geometry to one C(55,56) atom. In the twenty-first H site, H(37,38) is bonded in a single-bond geometry to one C(59,60) atom. In the twenty-second H site, H(39,40) is bonded in a single-bond geometry to one C(61,62) atom. In the twenty-third H site, H(41,42) is bonded in a single-bond geometry to one C(63) atom. In the twenty-fourth H site, H(43,44) is bonded in a single-bond geometry to one C(65,66) atom. In the twenty-fifth H site, H(45,46) is bonded in a single-bond geometry to one C(69,70) atom. In the twenty-sixth H site, H(47,48) is bonded in a single-bond geometry to one C(71) atom. There are ten inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Zn(1,2) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Zn(1,2) atom. The I(2)-Zn(1,2) bond length is 2.56 Å. In the third I site, I(3) is bonded in a single-bond geometry to one Zn(1,2) atom. In the fourth I site, I(4) is bonded in a single-bond geometry to one Zn(1,2) atom. The I(4)-Zn(1,2) bond length is 2.55 Å. In the fifth I site, I(5,6) is bonded in a single-bond geometry to one Zn(3) atom. In the sixth I site, I(7,8) is bonded in a single-bond geometry to one Zn(3) atom. In the seventh I site, I(9) is bonded in a single-bond geometry to one Zn(5) atom. In the eighth I site, I(10) is bonded in a single-bond geometry to one Zn(6) atom. In the ninth I site, I(11) is bonded in a single-bond geometry to one Zn(5) atom. In the tenth I site, I(12) is bonded in a single-bond geometry to one Zn(6) atom. Linkers: 8 n1ccc(cc1)C1=NC(=[N]=C([N]1)c1ccncc1)c1ccncc1. Metal clusters: 12 I[Zn]I. The MOF has largest included sphere 6.89 A, density 1.50 g/cm3, surface area 3550.03 m2/g, accessible volume 0.37 cm3/g