AgC21P2H18O2(CH)6CF3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, two trifluoromethane molecules, and two AgC21P2H18O2 clusters. In each AgC21P2H18O2 cluster, Ag(1) is bonded in a distorted trigonal planar geometry to one P(1), one P(2), and one O(1) atom. The Ag(1)-P(1) bond length is 2.40 Å. The Ag(1)-P(2) bond length is 2.39 Å. The Ag(1)-O(1) bond length is 2.37 Å. There are twenty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(4), one C(8), and one P(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(8) bond length is 1.40 Å. The C(3)-P(1) bond length is 1.83 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(1) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(2) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(2) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(3) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(3) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(4) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(4) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one P(1) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.40 Å. The C(9)-P(1) bond length is 1.82 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(10)-H(6) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(7) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(7) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(8) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(8) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(9) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one H(10) atom. The C(14)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted water-like geometry to one P(1), one H(11), and one H(12) atom. The C(15)-P(1) bond length is 1.83 Å. The C(15)-H(11) bond length is 1.10 Å. The C(15)-H(12) bond length is 1.10 Å. In the fifteenth C site, C(16) is bonded in a trigonal planar geometry to one C(17), one C(21), and one P(2) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.41 Å. The C(16)-P(2) bond length is 1.82 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(13) atom. The C(17)-H(13) bond length is 1.09 Å. In the seventeenth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(17) atom. The C(21)-H(17) bond length is 1.09 Å. In the eighteenth C site, C(22) is bonded in a trigonal planar geometry to one C(23), one C(27), and one P(2) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(27) bond length is 1.40 Å. The C(22)-P(2) bond length is 1.82 Å. In the nineteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(18,22) atom. The C(23)-H(18,22) bond length is 1.09 Å. In the twentieth C site, C(27) is bonded in a distorted single-bond geometry to one C(22) and one H(18,22) atom. The C(27)-H(18,22) bond length is 1.09 Å. In the twenty-first C site, C(28) is bonded in a distorted water-like geometry to one P(2), one H(23), and one H(24) atom. The C(28)-P(2) bond length is 1.84 Å. The C(28)-H(23) bond length is 1.10 Å. The C(28)-H(24) bond length is 1.10 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one Ag(1), one C(15), one C(3), and one C(9) atom to form distorted corner-sharing PAgC3 tetrahedra. In the second P site, P(2) is bonded to one Ag(1), one C(16), one C(22), and one C(28) atom to form distorted corner-sharing PAgC3 tetrahedra. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(18,22) is bonded in a single-bond geometry to one C(23) atom. In the sixteenth H site, H(23) is bonded in a single-bond geometry to one C(28) atom. In the seventeenth H site, H(24) is bonded in a single-bond geometry to one C(28) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Ag(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Linkers: 2 [c]1cccc(P(CCP(c2ccccc2)c2ccccc2)c2ccccc2)c1 ,1 [C][CH]/C(=C\[CH])P(CCP(c1ccccc1)c1ccccc1)c1ccccc1 ,2 c1ccc(P(CCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1 ,1 [C]/C=C(\C=[CH])P(CCP(c1ccccc1)c1ccccc1)c1ccccc1 ,2 [c]1[c]cc(P(CCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1. Metal clusters: . The MOF has largest included sphere 2.63 A, density 1.59 g/cm3, surface area 4668.60 m2/g, accessible volume 0.19 cm3/g