ZnC12H18(N2I)2(CH2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and four ZnC12H18(N2I)2 clusters. In each ZnC12H18(N2I)2 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent I(1) atoms. Both Zn(1)-N(1) bond lengths are 2.06 Å. Both Zn(1)-I(1) bond lengths are 2.60 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(3), and one N(2) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(3) bond length is 1.49 Å. The C(1)-N(2) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(1) atom. The C(2)-C(5) bond length is 1.40 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one H(2), one H(3), and one H(4) atom. The C(3)-H(2) bond length is 1.10 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(4) bond length is 1.10 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(2), one C(7), and one N(1) atom. The C(5)-C(7) bond length is 1.49 Å. The C(5)-N(1) bond length is 1.35 Å. In the fifth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(7), and one H(8) atom. The C(6)-N(2) bond length is 1.46 Å. The C(6)-H(7) bond length is 1.10 Å. The C(6)-H(8) bond length is 1.10 Å. In the sixth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one H(10), one H(11), and one H(9) atom. The C(7)-H(10) bond length is 1.09 Å. The C(7)-H(11) bond length is 1.10 Å. The C(7)-H(9) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(5), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(6), and one N(1) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(7) atom. I(1) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 2 Cc1cc(C)n(CCCCn2nc(C)cc2C)n1 ,2 [CH2]c1cc(C)nn1CCCCn1nc(C)cc1C. Metal clusters: 2 I[Zn]I. The MOF has largest included sphere 2.79 A, density 1.91 g/cm3, surface area 4061.76 m2/g, accessible volume 0.19 cm3/g