(CH2)12CuC4H6S2I is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules and one CuC4H6S2I cluster. In the CuC4H6S2I cluster, Cu(1) is bonded to one S(1), one S(2), and two equivalent I(1) atoms to form edge-sharing CuS2I2 tetrahedra. The Cu(1)-S(1) bond length is 2.27 Å. The Cu(1)-S(2) bond length is 2.27 Å. There is one shorter (2.65 Å) and one longer (2.71 Å) Cu(1)-I(1) bond length. There are four inequivalent C sites. In the first C site, C(7) is bonded in a distorted water-like geometry to one H(12), one H(13), and one S(1) atom. The C(7)-H(12) bond length is 1.10 Å. The C(7)-H(13) bond length is 1.10 Å. The C(7)-S(1) bond length is 1.82 Å. In the second C site, C(10) is bonded in a distorted water-like geometry to one H(18), one H(19), and one S(2) atom. The C(10)-H(18) bond length is 1.10 Å. The C(10)-H(19) bond length is 1.10 Å. The C(10)-S(2) bond length is 1.82 Å. In the third C site, C(11) is bonded in a distorted single-bond geometry to one H(20) and one S(2) atom. The C(11)-H(20) bond length is 1.10 Å. The C(11)-S(2) bond length is 1.83 Å. In the fourth C site, C(1) is bonded in a distorted single-bond geometry to one H(1) and one S(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.83 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(18) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(20) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(10), and one C(11) atom. In the second S site, S(1) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(1), and one C(7) atom. I(1) is bonded in a distorted L-shaped geometry to two equivalent Cu(1) atoms. Linkers: 2 C1CCC(SCCCCSC2CCCCC2)CC1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.08 A, density 1.79 g/cm3, surface area 4497.46 m2/g, accessible volume 0.14 cm3/g