AlC8H5O5C7NH6S2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four schembl9702205 molecules inside a AlC8H5O5 framework. In the AlC8H5O5 framework, there are two inequivalent Al sites. In the first Al site, Al(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form corner-sharing AlO6 octahedra. The corner-sharing octahedral tilt angles are 52°. Both Al(1)-O(1) bond lengths are 1.85 Å. Both Al(1)-O(2) bond lengths are 1.92 Å. Both Al(1)-O(5) bond lengths are 1.94 Å. In the second Al site, Al(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form corner-sharing AlO6 octahedra. The corner-sharing octahedral tilt angles are 52°. Both Al(2)-O(1) bond lengths are 1.86 Å. Both Al(2)-O(3) bond lengths are 1.91 Å. Both Al(2)-O(4) bond lengths are 1.91 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(5) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(3) bond length is 1.27 Å. The C(1)-O(5) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(2) atom. The C(3)-C(6) bond length is 1.39 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(2), and one O(4) atom. The C(4)-C(5) bond length is 1.49 Å. The C(4)-O(2) bond length is 1.27 Å. The C(4)-O(4) bond length is 1.27 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(8), and one H(4) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(4) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. There are five inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Al(2) and one C(1) atom. In the second O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Al(2) and one C(4) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Al(1) and one C(1) atom. In the fourth O site, O(1) is bonded in a trigonal planar geometry to one Al(1), one Al(2), and one H(1) atom. In the fifth O site, O(2) is bonded in a bent 120 degrees geometry to one Al(1) and one C(4) atom. Linkers: 4 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 4 [Al]. RCSR code: lvt. The MOF has largest included sphere 2.07 A, density 1.69 g/cm3, surface area 4263.93 m2/g, accessible volume 0.11 cm3/g