CoC16H19(NO2)2CH2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CoC16H19(NO2)2 clusters. In each CoC16H19(NO2)2 cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(4), one O(5), and one O(8) atom. The Co(1)-N(1) bond length is 2.11 Å. The Co(1)-O(1) bond length is 2.00 Å. The Co(1)-O(4) bond length is 2.11 Å. The Co(1)-O(5) bond length is 2.07 Å. The Co(1)-O(8) bond length is 2.00 Å. In the second Co site, Co(2) is bonded in a distorted square pyramidal geometry to one N(4), one O(2), one O(3), one O(6), and one O(7) atom. The Co(2)-N(4) bond length is 2.11 Å. The Co(2)-O(2) bond length is 2.03 Å. The Co(2)-O(3) bond length is 2.04 Å. The Co(2)-O(6) bond length is 2.07 Å. The Co(2)-O(7) bond length is 2.02 Å. There are thirty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.53 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a tetrahedral geometry to one C(1), one C(3), one C(6), and one C(8) atom. The C(2)-C(3) bond length is 1.54 Å. The C(2)-C(6) bond length is 1.58 Å. The C(2)-C(8) bond length is 1.54 Å. In the third C site, C(3) is bonded in a distorted water-like geometry to one C(2), one H(1), and one H(2) atom. The C(3)-H(1) bond length is 1.10 Å. The C(3)-H(2) bond length is 1.10 Å. In the fourth C site, C(5) is bonded in a single-bond geometry to one C(6) and one H(5) atom. The C(5)-C(6) bond length is 1.57 Å. The C(5)-H(5) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a tetrahedral geometry to one C(10), one C(2), one C(5), and one C(9) atom. The C(6)-C(10) bond length is 1.53 Å. The C(6)-C(9) bond length is 1.54 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(7)-O(3) bond length is 1.28 Å. The C(7)-O(4) bond length is 1.27 Å. In the seventh C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(2), one H(6), one H(7), and one H(8) atom. The C(8)-H(6) bond length is 1.10 Å. The C(8)-H(7) bond length is 1.10 Å. The C(8)-H(8) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(6), one H(10), one H(11), and one H(9) atom. The C(9)-H(10) bond length is 1.10 Å. The C(9)-H(11) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. In the ninth C site, C(10) is bonded in a trigonal non-coplanar geometry to one C(6), one H(12), one H(13), and one H(14) atom. The C(10)-H(12) bond length is 1.10 Å. The C(10)-H(13) bond length is 1.10 Å. The C(10)-H(14) bond length is 1.10 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(5), and one O(6) atom. The C(11)-C(12) bond length is 1.53 Å. The C(11)-O(5) bond length is 1.28 Å. The C(11)-O(6) bond length is 1.27 Å. In the eleventh C site, C(12) is bonded in a tetrahedral geometry to one C(11), one C(13), one C(16), and one C(18) atom. The C(12)-C(13) bond length is 1.55 Å. The C(12)-C(16) bond length is 1.58 Å. The C(12)-C(18) bond length is 1.53 Å. In the twelfth C site, C(13) is bonded in a distorted water-like geometry to one C(12) and two equivalent H(15,16) atoms. There is one shorter (1.09 Å) and one longer (1.10 Å) C(13)-H(15,16) bond length. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(19) atom. The C(15)-C(16) bond length is 1.56 Å. The C(15)-H(19) bond length is 1.10 Å. In the fourteenth C site, C(16) is bonded in a tetrahedral geometry to one C(12), one C(15), one C(19), and one C(20) atom. The C(16)-C(19) bond length is 1.53 Å. The C(16)-C(20) bond length is 1.54 Å. In the fifteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(17)-O(7) bond length is 1.28 Å. The C(17)-O(8) bond length is 1.28 Å. In the sixteenth C site, C(18) is bonded in a trigonal non-coplanar geometry to one C(12), one H(20), one H(21), and one H(22) atom. The C(18)-H(20) bond length is 1.10 Å. The C(18)-H(21) bond length is 1.10 Å. The C(18)-H(22) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a trigonal non-coplanar geometry to one C(16), one H(23), one H(24), and one H(25) atom. The C(19)-H(23) bond length is 1.10 Å. The C(19)-H(24) bond length is 1.10 Å. The C(19)-H(25) bond length is 1.10 Å. In the eighteenth C site, C(20) is bonded in a trigonal non-coplanar geometry to one C(16), one H(26), one H(27), and one H(28) atom. The C(20)-H(26) bond length is 1.10 Å. The C(20)-H(27) bond length is 1.10 Å. The C(20)-H(28) bond length is 1.10 Å. In the nineteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(1), and one H(29) atom. The C(21)-C(22) bond length is 1.37 Å. The C(21)-N(1) bond length is 1.38 Å. The C(21)-H(29) bond length is 1.08 Å. In the twentieth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(2), and one H(30) atom. The C(22)-N(2) bond length is 1.39 Å. The C(22)-H(30) bond length is 1.08 Å. In the twenty-first C site, C(23) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(31) atom. The C(23)-N(1) bond length is 1.33 Å. The C(23)-N(2) bond length is 1.36 Å. The C(23)-H(31) bond length is 1.08 Å. In the twenty-second C site, C(24) is bonded in a distorted trigonal non-coplanar geometry to one C(25), one N(2), one H(32), and one H(33) atom. The C(24)-C(25) bond length is 1.52 Å. The C(24)-N(2) bond length is 1.45 Å. The C(24)-H(32) bond length is 1.10 Å. The C(24)-H(33) bond length is 1.10 Å. In the twenty-third C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(30) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(30) bond length is 1.40 Å. In the twenty-fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(34) atom. The C(26)-H(34) bond length is 1.09 Å. In the twenty-fifth C site, C(27) is bonded in a distorted single-bond geometry to one C(28) and one H(35) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-H(35) bond length is 1.09 Å. In the twenty-sixth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(31) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-C(31) bond length is 1.51 Å. In the twenty-seventh C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(36) atom. The C(29)-H(36) bond length is 1.09 Å. In the twenty-eighth C site, C(30) is bonded in a distorted single-bond geometry to one C(25) and one H(37) atom. The C(30)-H(37) bond length is 1.09 Å. In the twenty-ninth C site, C(31) is bonded in a distorted trigonal non-coplanar geometry to one C(28), one N(3), one H(38), and one H(39) atom. The C(31)-N(3) bond length is 1.46 Å. The C(31)-H(38) bond length is 1.10 Å. The C(31)-H(39) bond length is 1.10 Å. In the thirtieth C site, C(32) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(40) atom. The C(32)-N(3) bond length is 1.36 Å. The C(32)-N(4) bond length is 1.33 Å. The C(32)-H(40) bond length is 1.08 Å. In the thirty-first C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(34), one N(4), and one H(41) atom. The C(33)-C(34) bond length is 1.37 Å. The C(33)-N(4) bond length is 1.38 Å. The C(33)-H(41) bond length is 1.08 Å. In the thirty-second C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(33), one N(3), and one H(42) atom. The C(34)-N(3) bond length is 1.39 Å. The C(34)-H(42) bond length is 1.08 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(21), and one C(23) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(22), one C(23), and one C(24) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(31), one C(32), and one C(34) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(2), one C(32), and one C(33) atom. There are thirty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(15,16) is bonded in a single-bond geometry to one C(13) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(15) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(21) is bonded in a single-bond geometry to one C(18) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one C(18) atom. In the eighteenth H site, H(23) is bonded in a single-bond geometry to one C(19) atom. In the nineteenth H site, H(24) is bonded in a single-bond geometry to one C(19) atom. In the twentieth H site, H(25) is bonded in a single-bond geometry to one C(19) atom. In the twenty-first H site, H(26) is bonded in a single-bond geometry to one C(20) atom. In the twenty-second H site, H(27) is bonded in a single-bond geometry to one C(20) atom. In the twenty-third H site, H(28) is bonded in a single-bond geometry to one C(20) atom. In the twenty-fourth H site, H(29) is bonded in a single-bond geometry to one C(21) atom. In the twenty-fifth H site, H(30) is bonded in a single-bond geometry to one C(22) atom. In the twenty-sixth H site, H(31) is bonded in a single-bond geometry to one C(23) atom. In the twenty-seventh H site, H(32) is bonded in a single-bond geometry to one C(24) atom. In the twenty-eighth H site, H(33) is bonded in a single-bond geometry to one C(24) atom. In the twenty-ninth H site, H(34) is bonded in a single-bond geometry to one C(26) atom. In the thirtieth H site, H(35) is bonded in a single-bond geometry to one C(27) atom. In the thirty-first H site, H(36) is bonded in a single-bond geometry to one C(29) atom. In the thirty-second H site, H(37) is bonded in a single-bond geometry to one C(30) atom. In the thirty-third H site, H(38) is bonded in a single-bond geometry to one C(31) atom. In the thirty-fourth H site, H(39) is bonded in a single-bond geometry to one C(31) atom. In the thirty-fifth H site, H(40) is bonded in a single-bond geometry to one C(32) atom. In the thirty-sixth H site, H(41) is bonded in a single-bond geometry to one C(33) atom. In the thirty-seventh H site, H(42) is bonded in a single-bond geometry to one C(34) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(2) and one C(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Co(2) and one C(7) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(7) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Co(1) and one C(11) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(11) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Co(2) and one C(17) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Co(1) and one C(17) atom. Linkers: 4 CC1(C)[C@@H](C([O])=O)CC[C@@]1(C)C([O])=O ,2 c1cn(Cc2ccc(Cn3ccnc3)cc2)cn1. Metal clusters: 2 [C]1O[Co]234O[C]O[Co]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 2.78 A, density 1.42 g/cm3, surface area 4644.13 m2/g, accessible volume 0.20 cm3/g