ZnC16H12(NO2)2(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two ZnC16H12(NO2)2 clusters. In each ZnC16H12(NO2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to two N(1,1) and two O(1,1) atoms. Both Zn(1)-N(1,1) bond lengths are 2.03 Å. Both Zn(1)-O(1,1) bond lengths are 1.99 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(3) bond length is 1.40 Å. The C(1)-C(4) bond length is 1.50 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(3) bond length is 1.40 Å. The C(1)-C(4) bond length is 1.50 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the fourth C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the fifth C site, C(3) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the sixth C site, C(3) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the seventh C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(4)-O(1) bond length is 1.30 Å. The C(4)-O(2) bond length is 1.25 Å. In the eighth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(4)-O(1) bond length is 1.30 Å. The C(4)-O(2) bond length is 1.25 Å. In the ninth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and one H(3) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(3) bond length is 1.09 Å. In the tenth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(5) bond length is 1.09 Å. In the eleventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(6) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(6) bond length is 1.09 Å. In the twelfth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(6) atom. The C(8)-C(7) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(6) bond length is 1.09 Å. In the thirteenth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(1), and one H(7) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(7) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(5), and one C(9) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(5), and one C(9) atom. The N(1)-C(5) bond length is 1.35 Å. The N(1)-C(9) bond length is 1.35 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(5) atom. The H(3)-C(5) bond length is 1.09 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. The H(7)-C(9) bond length is 1.09 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(4) atom. In the second O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(4) atom. In the third O site, O(2) is bonded in a single-bond geometry to one C(4) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one C(4) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.30 A, density 1.50 g/cm3, surface area 4943.55 m2/g, accessible volume 0.16 cm3/g