(AgC8H6(NO)2)2(CH2)7(C3H2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of fourteen 02329_fluka molecules; two 2,3-dimethyl-1,3-butadiene molecules; and two AgC8H6(NO)2 clusters. In each AgC8H6(NO)2 cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(3), one O(1), and one O(2) atom. The Ag(1)-N(1) bond length is 2.16 Å. The Ag(1)-N(3) bond length is 2.17 Å. The Ag(1)-O(1) bond length is 2.63 Å. The Ag(1)-O(2) bond length is 2.51 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one N(2), one N(4), one O(3), and one O(4) atom. The Ag(2)-N(2) bond length is 2.17 Å. The Ag(2)-N(4) bond length is 2.17 Å. The Ag(2)-O(3) bond length is 2.49 Å. The Ag(2)-O(4) bond length is 2.71 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(9)-O(3) bond length is 1.28 Å. The C(9)-O(4) bond length is 1.27 Å. In the third C site, C(10) is bonded in a distorted trigonal planar geometry to one N(1) and one H(15) atom. The C(10)-N(1) bond length is 1.35 Å. The C(10)-H(15) bond length is 1.09 Å. In the fourth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(18) atom. The C(14)-N(1) bond length is 1.35 Å. The C(14)-H(18) bond length is 1.09 Å. In the fifth C site, C(17) is bonded in a distorted trigonal planar geometry to one N(2) and one H(20) atom. The C(17)-N(2) bond length is 1.35 Å. The C(17)-H(20) bond length is 1.09 Å. In the sixth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(21) atom. The C(18)-N(2) bond length is 1.35 Å. The C(18)-H(21) bond length is 1.09 Å. In the seventh C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(23) atom. The C(20)-N(3) bond length is 1.35 Å. The C(20)-H(23) bond length is 1.09 Å. In the eighth C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(24) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-H(24) bond length is 1.09 Å. In the ninth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(27) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(27) bond length is 1.48 Å. In the tenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22), one C(24), and one H(25) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-H(25) bond length is 1.09 Å. In the eleventh C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one N(3), and one H(26) atom. The C(24)-N(3) bond length is 1.35 Å. The C(24)-H(26) bond length is 1.09 Å. In the twelfth C site, C(25) is bonded in a distorted trigonal planar geometry to one N(4) and one H(27) atom. The C(25)-N(4) bond length is 1.35 Å. The C(25)-H(27) bond length is 1.09 Å. In the thirteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(27) and one H(28) atom. The C(26)-C(27) bond length is 1.41 Å. The C(26)-H(28) bond length is 1.09 Å. In the fourteenth C site, C(27) is bonded in a trigonal planar geometry to one C(22), one C(26), and one C(28) atom. The C(27)-C(28) bond length is 1.40 Å. In the fifteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(27), one C(29), and one H(29) atom. The C(28)-C(29) bond length is 1.39 Å. The C(28)-H(29) bond length is 1.09 Å. In the sixteenth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one N(4), and one H(30) atom. The C(29)-N(4) bond length is 1.35 Å. The C(29)-H(30) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Ag(2), one C(25), and one C(29) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(10), and one C(14) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one Ag(2), one C(17), and one C(18) atom. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(20), and one C(24) atom. There are twelve inequivalent H sites. In the first H site, H(15) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(18) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(20) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(21) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(23) is bonded in a single-bond geometry to one C(20) atom. In the sixth H site, H(24) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(25) is bonded in a single-bond geometry to one C(23) atom. In the eighth H site, H(26) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(27) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(28) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(29) is bonded in a single-bond geometry to one C(28) atom. In the twelfth H site, H(30) is bonded in a single-bond geometry to one C(29) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ag(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(2) and one C(9) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Ag(2) and one C(9) atom. Linkers: 2 [C][CH]N(C=[CH])[Ag](OC(=O)CCCCCCCC([O])=O)N1[CH]C=C(c2ccncc2)C=C1 ,2 [O]C(=O)CCCCCCCC(=O)O[Ag](N1[CH]C=C(c2ccncc2)C=C1)N1[CH]C=C(c2ccncc2)C=C1 ,2 [O]C(=O)CCCCCCCC(=O)O[Ag](N1[CH]C=C(c2c[c]ncc2)C=C1)N1[CH]C=C(c2ccncc2)C=C1. Metal clusters: 1 O=[C]O[Ag][Ag]O[C]=O. The MOF has largest included sphere 3.40 A, density 1.63 g/cm3, surface area 4263.33 m2/g, accessible volume 0.22 cm3/g