CoC14H16(NO2)2CH2(CH)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two isobutylene molecules, and one CoC14H16(NO2)2 cluster. In the CoC14H16(NO2)2 cluster, Co(1) is bonded in a distorted octahedral geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Co(1)-N(1) bond length is 2.10 Å. The Co(1)-N(2) bond length is 2.11 Å. The Co(1)-O(1) bond length is 2.02 Å. The Co(1)-O(2) bond length is 2.21 Å. The Co(1)-O(3) bond length is 1.99 Å. The Co(1)-O(4) bond length is 2.21 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(2), and one O(4) atom. The C(2)-C(10) bond length is 1.54 Å. The C(2)-O(2) bond length is 1.28 Å. The C(2)-O(4) bond length is 1.28 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(1) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(16) atom. The C(5)-C(14) bond length is 1.40 Å. The C(5)-C(15) bond length is 1.50 Å. The C(5)-C(16) bond length is 1.40 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(6)-N(1) bond length is 1.35 Å. The C(6)-H(2) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted water-like geometry to one C(10), one H(3), and one H(4) atom. The C(7)-C(10) bond length is 1.54 Å. The C(7)-H(3) bond length is 1.10 Å. The C(7)-H(4) bond length is 1.10 Å. In the seventh C site, C(10) is bonded in a tetrahedral geometry to one C(18), one C(19), one C(2), and one C(7) atom. The C(10)-C(18) bond length is 1.53 Å. The C(10)-C(19) bond length is 1.54 Å. In the eighth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14), one N(2), and one H(9) atom. The C(12)-C(14) bond length is 1.39 Å. The C(12)-N(2) bond length is 1.34 Å. The C(12)-H(9) bond length is 1.09 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(12), one C(5), and one H(12) atom. The C(14)-H(12) bond length is 1.09 Å. In the tenth C site, C(15) is bonded in a distorted water-like geometry to one C(5), one H(13), and one H(14) atom. The C(15)-H(13) bond length is 1.10 Å. The C(15)-H(14) bond length is 1.10 Å. In the eleventh C site, C(16) is bonded in a distorted single-bond geometry to one C(17), one C(5), and one H(15) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(15) bond length is 1.09 Å. In the twelfth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(2), and one H(16) atom. The C(17)-N(2) bond length is 1.35 Å. The C(17)-H(16) bond length is 1.09 Å. In the thirteenth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one H(17), one H(18), and one H(19) atom. The C(18)-H(17) bond length is 1.09 Å. The C(18)-H(18) bond length is 1.10 Å. The C(18)-H(19) bond length is 1.10 Å. In the fourteenth C site, C(19) is bonded in a trigonal non-coplanar geometry to one C(10), one H(20), one H(21), and one H(22) atom. The C(19)-H(20) bond length is 1.10 Å. The C(19)-H(21) bond length is 1.10 Å. The C(19)-H(22) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(4), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(12), and one C(17) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(19) atom. In the sixteenth H site, H(22) is bonded in a single-bond geometry to one C(19) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Co(1) and one C(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Co(1) and one C(2) atom. Linkers: 2 c1cc(CCc2ccncc2)ccn1 ,2 CC(C)(CCC([O])=O)C([O])=O. Metal clusters: 1 [C]1O[Co]2(O1)O[C]O[Co]1(O[C]O1)O[C]O2. The MOF has largest included sphere 2.20 A, density 1.50 g/cm3, surface area 4758.80 m2/g, accessible volume 0.15 cm3/g