Zn2C23H11O11 crystallizes in the triclinic P1 space group. There are seven inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to one O(13), one O(22), one O(31), one O(41), one O(6), and one O(9) atom. The Zn(1)-O(13) bond length is 2.25 Å. The Zn(1)-O(22) bond length is 2.00 Å. The Zn(1)-O(31) bond length is 2.00 Å. The Zn(1)-O(41) bond length is 2.34 Å. The Zn(1)-O(6) bond length is 2.10 Å. The Zn(1)-O(9) bond length is 2.15 Å. In the second Zn site, Zn(2) is bonded in a 6-coordinate geometry to one O(10), one O(14), one O(21), one O(32), one O(42), and one O(5) atom. The Zn(2)-O(10) bond length is 2.15 Å. The Zn(2)-O(14) bond length is 2.24 Å. The Zn(2)-O(21) bond length is 2.00 Å. The Zn(2)-O(32) bond length is 2.00 Å. The Zn(2)-O(42) bond length is 2.33 Å. The Zn(2)-O(5) bond length is 2.11 Å. In the third Zn site, Zn(3,4) is bonded in a 6-coordinate geometry to one O(11), one O(15), one O(24), one O(29), one O(43), and one O(8) atom. The Zn(3,4)-O(11) bond length is 2.14 Å. The Zn(3,4)-O(15) bond length is 2.25 Å. The Zn(3,4)-O(24) bond length is 2.00 Å. The Zn(3,4)-O(29) bond length is 2.00 Å. The Zn(3,4)-O(43) bond length is 2.33 Å. The Zn(3,4)-O(8) bond length is 2.11 Å. In the fourth Zn site, Zn(5) is bonded in a 5-coordinate geometry to one O(1), one O(17), one O(28), one O(35), and one O(39) atom. The Zn(5)-O(1) bond length is 2.01 Å. The Zn(5)-O(17) bond length is 2.00 Å. The Zn(5)-O(28) bond length is 1.99 Å. The Zn(5)-O(35) bond length is 2.02 Å. The Zn(5)-O(39) bond length is 2.45 Å. In the fifth Zn site, Zn(6) is bonded in a 5-coordinate geometry to one O(18), one O(2), one O(27), one O(36), and one O(40) atom. The Zn(6)-O(18) bond length is 1.99 Å. The Zn(6)-O(2) bond length is 2.01 Å. The Zn(6)-O(27) bond length is 1.98 Å. The Zn(6)-O(36) bond length is 2.01 Å. The Zn(6)-O(40) bond length is 2.46 Å. In the sixth Zn site, Zn(7) is bonded in a 5-coordinate geometry to one O(19), one O(26), one O(3), one O(33), and one O(37) atom. The Zn(7)-O(19) bond length is 1.99 Å. The Zn(7)-O(26) bond length is 1.98 Å. The Zn(7)-O(3) bond length is 2.01 Å. The Zn(7)-O(33) bond length is 2.01 Å. The Zn(7)-O(37) bond length is 2.46 Å. In the seventh Zn site, Zn(8) is bonded in a 5-coordinate geometry to one O(20), one O(25), one O(34), one O(38), and one O(4) atom. The Zn(8)-O(20) bond length is 1.99 Å. The Zn(8)-O(25) bond length is 1.98 Å. The Zn(8)-O(34) bond length is 2.01 Å. The Zn(8)-O(38) bond length is 2.46 Å. The Zn(8)-O(4) bond length is 2.01 Å. There are seventy-nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(5) atom. The C(1)-C(5) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(5) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(2), and one O(6) atom. The C(2)-C(6) bond length is 1.50 Å. The C(2)-O(2) bond length is 1.27 Å. The C(2)-O(6) bond length is 1.27 Å. In the third C site, C(3,4) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(7) atom. The C(3,4)-C(7) bond length is 1.50 Å. The C(3,4)-O(3) bond length is 1.27 Å. The C(3,4)-O(7) bond length is 1.27 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(25), and one C(9) atom. The C(5)-C(25) bond length is 1.40 Å. The C(5)-C(9) bond length is 1.40 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(26) atom. The C(6)-C(10) bond length is 1.40 Å. The C(6)-C(26) bond length is 1.40 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(11,12); one C(27,28); and one C(3,4) atom. The C(7)-C(11,12) bond length is 1.40 Å. The C(7)-C(27,28) bond length is 1.40 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(11,12); one C(27,28); and one C(3,4) atom. The C(8)-C(11,12) bond length is 1.40 Å. The C(8)-C(27,28) bond length is 1.40 Å. The C(8)-C(3,4) bond length is 1.50 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(13,14); one C(5); and one H(9,10) atom. The C(9)-C(13,14) bond length is 1.41 Å. The C(9)-H(9,10) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(13,14); one C(6); and one H(9,10) atom. The C(10)-C(13,14) bond length is 1.41 Å. The C(10)-H(9,10) bond length is 1.09 Å. In the tenth C site, C(11,12) is bonded in a distorted single-bond geometry to one C(15); one C(7); and one H(11,12) atom. The C(11,12)-C(15) bond length is 1.41 Å. The C(11,12)-H(11,12) bond length is 1.09 Å. In the eleventh C site, C(13,14) is bonded in a trigonal planar geometry to one C(17,18); one C(53); and one C(9) atom. The C(13,14)-C(17,18) bond length is 1.40 Å. The C(13,14)-C(53) bond length is 1.47 Å. In the twelfth C site, C(15) is bonded in a trigonal planar geometry to one C(11,12); one C(19,20); and one C(55,56) atom. The C(15)-C(19,20) bond length is 1.40 Å. The C(15)-C(55,56) bond length is 1.47 Å. In the thirteenth C site, C(16) is bonded in a trigonal planar geometry to one C(11,12); one C(19,20); and one C(55,56) atom. The C(16)-C(11,12) bond length is 1.41 Å. The C(16)-C(19,20) bond length is 1.40 Å. The C(16)-C(55,56) bond length is 1.47 Å. In the fourteenth C site, C(17,18) is bonded in a single-bond geometry to one C(13,14); one C(21,22); and one H(13,14) atom. The C(17,18)-C(21,22) bond length is 1.40 Å. The C(17,18)-H(13,14) bond length is 1.09 Å. In the fifteenth C site, C(19,20) is bonded in a single-bond geometry to one C(15), one C(23), and one H(15) atom. The C(19,20)-C(23) bond length is 1.40 Å. The C(19,20)-H(15) bond length is 1.09 Å. In the sixteenth C site, C(21,22) is bonded in a trigonal planar geometry to one C(17,18); one C(25); and one C(85,86) atom. The C(21,22)-C(25) bond length is 1.41 Å. The C(21,22)-C(85,86) bond length is 1.47 Å. In the seventeenth C site, C(23) is bonded in a trigonal planar geometry to one C(19,20); one C(27,28); and one C(87) atom. The C(23)-C(27,28) bond length is 1.41 Å. The C(23)-C(87) bond length is 1.47 Å. In the eighteenth C site, C(24) is bonded in a trigonal planar geometry to one C(19,20); one C(27,28); and one C(88) atom. The C(24)-C(19,20) bond length is 1.40 Å. The C(24)-C(27,28) bond length is 1.41 Å. The C(24)-C(88) bond length is 1.47 Å. In the nineteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(21,22); one C(5); and one H(17,18,19,20) atom. The C(25)-H(17,18,19,20) bond length is 1.09 Å. In the twentieth C site, C(26) is bonded in a distorted single-bond geometry to one C(21,22); one C(6); and one H(17,18,19,20) atom. The C(26)-C(21,22) bond length is 1.41 Å. The C(26)-H(17,18,19,20) bond length is 1.09 Å. In the twenty-first C site, C(27,28) is bonded in a distorted single-bond geometry to one C(23); one C(7); and one H(17,18,19,20) atom. The C(27,28)-H(17,18,19,20) bond length is 1.09 Å. In the twenty-second C site, C(29,31) is bonded in a bent 120 degrees geometry to one C(37), one O(13), and one O(9) atom. The C(29,31)-C(37) bond length is 1.49 Å. The C(29,31)-O(13) bond length is 1.28 Å. The C(29,31)-O(9) bond length is 1.28 Å. In the twenty-third C site, C(30) is bonded in a bent 120 degrees geometry to one C(38), one O(10), and one O(14) atom. The C(30)-C(38) bond length is 1.49 Å. The C(30)-O(10) bond length is 1.28 Å. The C(30)-O(14) bond length is 1.28 Å. In the twenty-fourth C site, C(32) is bonded in a bent 120 degrees geometry to one C(40), one O(12), and one O(16) atom. The C(32)-C(40) bond length is 1.49 Å. The C(32)-O(12) bond length is 1.28 Å. The C(32)-O(16) bond length is 1.28 Å. In the twenty-fifth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(45), one O(17), and one O(21) atom. The C(33)-C(45) bond length is 1.50 Å. The C(33)-O(17) bond length is 1.28 Å. The C(33)-O(21) bond length is 1.27 Å. In the twenty-sixth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(46), one O(18), and one O(22) atom. The C(34)-C(46) bond length is 1.50 Å. The C(34)-O(18) bond length is 1.28 Å. The C(34)-O(22) bond length is 1.27 Å. In the twenty-seventh C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(47), one O(19), and one O(23) atom. The C(35)-C(47) bond length is 1.50 Å. The C(35)-O(19) bond length is 1.28 Å. The C(35)-O(23) bond length is 1.27 Å. In the twenty-eighth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(48), one O(20), and one O(24) atom. The C(36)-C(48) bond length is 1.50 Å. The C(36)-O(20) bond length is 1.28 Å. The C(36)-O(24) bond length is 1.27 Å. In the twenty-ninth C site, C(37) is bonded in a trigonal planar geometry to one C(29,31); one C(41,42); and one C(57,58) atom. The C(37)-C(41,42) bond length is 1.40 Å. The C(37)-C(57,58) bond length is 1.40 Å. In the thirtieth C site, C(38) is bonded in a trigonal planar geometry to one C(30); one C(41,42); and one C(57,58) atom. The C(38)-C(41,42) bond length is 1.40 Å. The C(38)-C(57,58) bond length is 1.40 Å. In the thirty-first C site, C(39) is bonded in a trigonal planar geometry to one C(29,31); one C(43); and one C(59) atom. The C(39)-C(29,31) bond length is 1.49 Å. The C(39)-C(43) bond length is 1.40 Å. The C(39)-C(59) bond length is 1.40 Å. In the thirty-second C site, C(40) is bonded in a trigonal planar geometry to one C(32), one C(44), and one C(60) atom. The C(40)-C(44) bond length is 1.40 Å. The C(40)-C(60) bond length is 1.40 Å. In the thirty-third C site, C(41,42) is bonded in a distorted single-bond geometry to one C(37), one C(45), and one H(21) atom. The C(41,42)-C(45) bond length is 1.40 Å. The C(41,42)-H(21) bond length is 1.09 Å. In the thirty-fourth C site, C(43) is bonded in a distorted single-bond geometry to one C(39); one C(47); and one H(23,24) atom. The C(43)-C(47) bond length is 1.40 Å. The C(43)-H(23,24) bond length is 1.09 Å. In the thirty-fifth C site, C(44) is bonded in a distorted single-bond geometry to one C(40); one C(48); and one H(23,24) atom. The C(44)-C(48) bond length is 1.40 Å. The C(44)-H(23,24) bond length is 1.09 Å. In the thirty-sixth C site, C(45) is bonded in a trigonal planar geometry to one C(33); one C(41,42); and one C(49,50) atom. The C(45)-C(49,50) bond length is 1.39 Å. In the thirty-seventh C site, C(46) is bonded in a trigonal planar geometry to one C(34); one C(41,42); and one C(49,50) atom. The C(46)-C(41,42) bond length is 1.40 Å. The C(46)-C(49,50) bond length is 1.39 Å. In the thirty-eighth C site, C(47) is bonded in a trigonal planar geometry to one C(35), one C(43), and one C(51) atom. The C(47)-C(51) bond length is 1.39 Å. In the thirty-ninth C site, C(48) is bonded in a trigonal planar geometry to one C(36), one C(44), and one C(52) atom. The C(48)-C(52) bond length is 1.39 Å. In the fortieth C site, C(49,50) is bonded in a distorted single-bond geometry to one C(45), one C(53), and one H(25) atom. The C(49,50)-C(53) bond length is 1.41 Å. The C(49,50)-H(25) bond length is 1.09 Å. In the forty-first C site, C(51) is bonded in a distorted single-bond geometry to one C(47); one C(55,56); and one H(27,28) atom. The C(51)-C(55,56) bond length is 1.41 Å. The C(51)-H(27,28) bond length is 1.09 Å. In the forty-second C site, C(52) is bonded in a distorted single-bond geometry to one C(48); one C(55,56); and one H(27,28) atom. The C(52)-C(55,56) bond length is 1.41 Å. The C(52)-H(27,28) bond length is 1.09 Å. In the forty-third C site, C(53) is bonded in a trigonal planar geometry to one C(13,14); one C(49,50); and one C(57,58) atom. The C(53)-C(57,58) bond length is 1.41 Å. In the forty-fourth C site, C(54) is bonded in a trigonal planar geometry to one C(13,14); one C(49,50); and one C(57,58) atom. The C(54)-C(13,14) bond length is 1.47 Å. The C(54)-C(49,50) bond length is 1.41 Å. The C(54)-C(57,58) bond length is 1.41 Å. In the forty-fifth C site, C(55,56) is bonded in a trigonal planar geometry to one C(15), one C(51), and one C(59) atom. The C(55,56)-C(59) bond length is 1.41 Å. In the forty-sixth C site, C(57,58) is bonded in a distorted single-bond geometry to one C(37); one C(53); and one H(29,30) atom. The C(57,58)-H(29,30) bond length is 1.09 Å. In the forty-seventh C site, C(59) is bonded in a distorted single-bond geometry to one C(39); one C(55,56); and one H(31,32) atom. The C(59)-H(31,32) bond length is 1.09 Å. In the forty-eighth C site, C(60) is bonded in a distorted single-bond geometry to one C(40); one C(55,56); and one H(31,32) atom. The C(60)-C(55,56) bond length is 1.41 Å. The C(60)-H(31,32) bond length is 1.09 Å. In the forty-ninth C site, C(61) is bonded in a distorted bent 120 degrees geometry to one C(69), one O(25), and one O(29) atom. The C(61)-C(69) bond length is 1.50 Å. The C(61)-O(25) bond length is 1.27 Å. The C(61)-O(29) bond length is 1.27 Å. In the fiftieth C site, C(62) is bonded in a distorted bent 120 degrees geometry to one C(70), one O(26), and one O(30) atom. The C(62)-C(70) bond length is 1.50 Å. The C(62)-O(26) bond length is 1.27 Å. The C(62)-O(30) bond length is 1.27 Å. In the fifty-first C site, C(63) is bonded in a distorted bent 120 degrees geometry to one C(71), one O(27), and one O(31) atom. The C(63)-C(71) bond length is 1.50 Å. The C(63)-O(27) bond length is 1.27 Å. The C(63)-O(31) bond length is 1.27 Å. In the fifty-second C site, C(64) is bonded in a distorted bent 120 degrees geometry to one C(72), one O(28), and one O(32) atom. The C(64)-C(72) bond length is 1.50 Å. The C(64)-O(28) bond length is 1.27 Å. The C(64)-O(32) bond length is 1.27 Å. In the fifty-third C site, C(65) is bonded in a bent 120 degrees geometry to one C(77), one O(33), and one O(37) atom. The C(65)-C(77) bond length is 1.49 Å. The C(65)-O(33) bond length is 1.29 Å. The C(65)-O(37) bond length is 1.26 Å. In the fifty-fourth C site, C(66) is bonded in a bent 120 degrees geometry to one C(78), one O(34), and one O(38) atom. The C(66)-C(78) bond length is 1.49 Å. The C(66)-O(34) bond length is 1.29 Å. The C(66)-O(38) bond length is 1.26 Å. In the fifty-fifth C site, C(67) is bonded in a bent 120 degrees geometry to one C(79), one O(35), and one O(39) atom. The C(67)-C(79) bond length is 1.49 Å. The C(67)-O(35) bond length is 1.29 Å. The C(67)-O(39) bond length is 1.26 Å. In the fifty-sixth C site, C(68) is bonded in a bent 120 degrees geometry to one C(80), one O(36), and one O(40) atom. The C(68)-C(80) bond length is 1.49 Å. The C(68)-O(36) bond length is 1.29 Å. The C(68)-O(40) bond length is 1.26 Å. In the fifty-seventh C site, C(69) is bonded in a trigonal planar geometry to one C(61), one C(73), and one C(89) atom. The C(69)-C(73) bond length is 1.40 Å. The C(69)-C(89) bond length is 1.39 Å. In the fifty-eighth C site, C(70) is bonded in a trigonal planar geometry to one C(62), one C(74), and one C(90) atom. The C(70)-C(74) bond length is 1.40 Å. The C(70)-C(90) bond length is 1.39 Å. In the fifty-ninth C site, C(71) is bonded in a trigonal planar geometry to one C(63), one C(75), and one C(91) atom. The C(71)-C(75) bond length is 1.40 Å. The C(71)-C(91) bond length is 1.39 Å. In the sixtieth C site, C(72) is bonded in a trigonal planar geometry to one C(64), one C(76), and one C(92) atom. The C(72)-C(76) bond length is 1.40 Å. The C(72)-C(92) bond length is 1.39 Å. In the sixty-first C site, C(73) is bonded in a distorted single-bond geometry to one C(69); one C(77); and one H(33,34,36) atom. The C(73)-C(77) bond length is 1.40 Å. The C(73)-H(33,34,36) bond length is 1.09 Å. In the sixty-second C site, C(74) is bonded in a distorted single-bond geometry to one C(70); one C(78); and one H(33,34,36) atom. The C(74)-C(78) bond length is 1.40 Å. The C(74)-H(33,34,36) bond length is 1.09 Å. In the sixty-third C site, C(75) is bonded in a distorted single-bond geometry to one C(71), one C(79), and one H(35) atom. The C(75)-C(79) bond length is 1.40 Å. The C(75)-H(35) bond length is 1.09 Å. In the sixty-fourth C site, C(76) is bonded in a distorted single-bond geometry to one C(72); one C(80); and one H(33,34,36) atom. The C(76)-C(80) bond length is 1.40 Å. The C(76)-H(33,34,36) bond length is 1.09 Å. In the sixty-fifth C site, C(77) is bonded in a trigonal planar geometry to one C(65), one C(73), and one C(81) atom. The C(77)-C(81) bond length is 1.40 Å. In the sixty-sixth C site, C(78) is bonded in a trigonal planar geometry to one C(66), one C(74), and one C(82) atom. The C(78)-C(82) bond length is 1.40 Å. In the sixty-seventh C site, C(79) is bonded in a trigonal planar geometry to one C(67), one C(75), and one C(83) atom. The C(79)-C(83) bond length is 1.40 Å. In the sixty-eighth C site, C(80) is bonded in a trigonal planar geometry to one C(68), one C(76), and one C(84) atom. The C(80)-C(84) bond length is 1.40 Å. In the sixty-ninth C site, C(81) is bonded in a distorted single-bond geometry to one C(77); one C(85,86); and one H(37,38) atom. The C(81)-C(85,86) bond length is 1.41 Å. The C(81)-H(37,38) bond length is 1.09 Å. In the seventieth C site, C(82) is bonded in a distorted single-bond geometry to one C(78); one C(85,86); and one H(37,38) atom. The C(82)-C(85,86) bond length is 1.41 Å. The C(82)-H(37,38) bond length is 1.09 Å. In the seventy-first C site, C(83) is bonded in a distorted single-bond geometry to one C(79); one C(87); and one H(39,40) atom. The C(83)-C(87) bond length is 1.41 Å. The C(83)-H(39,40) bond length is 1.09 Å. In the seventy-second C site, C(84) is bonded in a distorted single-bond geometry to one C(80); one C(88); and one H(39,40) atom. The C(84)-C(88) bond length is 1.41 Å. The C(84)-H(39,40) bond length is 1.09 Å. In the seventy-third C site, C(85,86) is bonded in a trigonal planar geometry to one C(21,22); one C(81); and one C(89) atom. The C(85,86)-C(89) bond length is 1.41 Å. In the seventy-fourth C site, C(87) is bonded in a trigonal planar geometry to one C(23), one C(83), and one C(91) atom. The C(87)-C(91) bond length is 1.41 Å. In the seventy-fifth C site, C(88) is bonded in a trigonal planar geometry to one C(24), one C(84), and one C(92) atom. The C(88)-C(92) bond length is 1.41 Å. In the seventy-sixth C site, C(89) is bonded in a distorted single-bond geometry to one C(69); one C(85,86); and one H(41,42) atom. The C(89)-H(41,42) bond length is 1.09 Å. In the seventy-seventh C site, C(90) is bonded in a distorted single-bond geometry to one C(70); one C(85,86); and one H(41,42) atom. The C(90)-C(85,86) bond length is 1.41 Å. The C(90)-H(41,42) bond length is 1.09 Å. In the seventy-eighth C site, C(91) is bonded in a distorted single-bond geometry to one C(71), one C(87), and one H(43) atom. The C(91)-H(43) bond length is 1.09 Å. In the seventy-ninth C site, C(92) is bonded in a distorted single-bond geometry to one C(72), one C(88), and one H(44) atom. The C(92)-H(44) bond length is 1.09 Å. There are twenty-six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(41) atom. The H(1)-O(41) bond length is 0.98 Å. In the second H site, H(2,4) is bonded in a single-bond geometry to one O(42) atom. The H(2,4)-O(42) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(43) atom. The H(3)-O(43) bond length is 0.98 Å. In the fourth H site, H(5) is bonded in a single-bond geometry to one O(41) atom. The H(5)-O(41) bond length is 0.98 Å. In the fifth H site, H(6,7,8) is bonded in a single-bond geometry to one O(42) atom. The H(6,7,8)-O(42) bond length is 0.98 Å. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(11,12) atom. In the eighth H site, H(13,14) is bonded in a single-bond geometry to one C(17,18) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(19,20) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(19,20) atom. The H(16)-C(19,20) bond length is 1.09 Å. In the eleventh H site, H(17,18,19,20) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(41,42) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(41,42) atom. The H(22)-C(41,42) bond length is 1.09 Å. In the fourteenth H site, H(23,24) is bonded in a single-bond geometry to one C(43) atom. In the fifteenth H site, H(25) is bonded in a single-bond geometry to one C(49,50) atom. In the sixteenth H site, H(26) is bonded in a single-bond geometry to one C(49,50) atom. The H(26)-C(49,50) bond length is 1.09 Å. In the seventeenth H site, H(27,28) is bonded in a single-bond geometry to one C(51) atom. In the eighteenth H site, H(29,30) is bonded in a single-bond geometry to one C(57,58) atom. In the nineteenth H site, H(31,32) is bonded in a single-bond geometry to one C(59) atom. In the twentieth H site, H(33,34,36) is bonded in a single-bond geometry to one C(73) atom. In the twenty-first H site, H(35) is bonded in a single-bond geometry to one C(75) atom. In the twenty-second H site, H(37,38) is bonded in a single-bond geometry to one C(81) atom. In the twenty-third H site, H(39,40) is bonded in a single-bond geometry to one C(83) atom. In the twenty-fourth H site, H(41,42) is bonded in a single-bond geometry to one C(89) atom. In the twenty-fifth H site, H(43) is bonded in a single-bond geometry to one C(91) atom. In the twenty-sixth H site, H(44) is bonded in a single-bond geometry to one C(92) atom. There are forty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(3,4) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(8) and one C(3,4) atom. The O(4)-C(3,4) bond length is 1.27 Å. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Zn(3,4) and one C(3,4) atom. The O(7)-Zn(3,4) bond length is 2.11 Å. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Zn(3,4) and one C(3,4) atom. The O(8)-C(3,4) bond length is 1.27 Å. In the ninth O site, O(9) is bonded in an L-shaped geometry to one Zn(1) and one C(29,31) atom. In the tenth O site, O(10) is bonded in an L-shaped geometry to one Zn(2) and one C(30) atom. In the eleventh O site, O(11) is bonded in an L-shaped geometry to one Zn(3,4) and one C(29,31) atom. The O(11)-C(29,31) bond length is 1.28 Å. In the twelfth O site, O(12) is bonded in an L-shaped geometry to one Zn(3,4) and one C(32) atom. The O(12)-Zn(3,4) bond length is 2.14 Å. In the thirteenth O site, O(13) is bonded in an L-shaped geometry to one Zn(1) and one C(29,31) atom. In the fourteenth O site, O(14) is bonded in an L-shaped geometry to one Zn(2) and one C(30) atom. In the fifteenth O site, O(15) is bonded in an L-shaped geometry to one Zn(3,4) and one C(29,31) atom. The O(15)-C(29,31) bond length is 1.28 Å. In the sixteenth O site, O(16) is bonded in an L-shaped geometry to one Zn(3,4) and one C(32) atom. The O(16)-Zn(3,4) bond length is 2.25 Å. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(33) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(34) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(35) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Zn(8) and one C(36) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(33) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(34) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Zn(3,4) and one C(35) atom. The O(23)-Zn(3,4) bond length is 2.00 Å. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Zn(3,4) and one C(36) atom. In the twenty-fifth O site, O(25) is bonded in a bent 150 degrees geometry to one Zn(8) and one C(61) atom. In the twenty-sixth O site, O(26) is bonded in a bent 150 degrees geometry to one Zn(7) and one C(62) atom. In the twenty-seventh O site, O(27) is bonded in a bent 150 degrees geometry to one Zn(6) and one C(63) atom. In the twenty-eighth O site, O(28) is bonded in a bent 150 degrees geometry to one Zn(5) and one C(64) atom. In the twenty-ninth O site, O(29) is bonded in a bent 120 degrees geometry to one Zn(3,4) and one C(61) atom. In the thirtieth O site, O(30) is bonded in a bent 120 degrees geometry to one Zn(3,4) and one C(62) atom. The O(30)-Zn(3,4) bond length is 2.00 Å. In the thirty-first O site, O(31) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(63) atom. In the thirty-second O site, O(32) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(64) atom. In the thirty-third O site, O(33) is bonded in a water-like geometry to one Zn(7) and one C(65) atom. In the thirty-fourth O site, O(34) is bonded in a water-like geometry to one Zn(8) and one C(66) atom. In the thirty-fifth O site, O(35) is bonded in a water-like geometry to one Zn(5) and one C(67) atom. In the thirty-sixth O site, O(36) is bonded in a water-like geometry to one Zn(6) and one C(68) atom. In the thirty-seventh O site, O(37) is bonded in a distorted single-bond geometry to one Zn(7) and one C(65) atom. In the thirty-eighth O site, O(38) is bonded in a distorted single-bond geometry to one Zn(8) and one C(66) atom. In the thirty-ninth O site, O(39) is bonded in a distorted single-bond geometry to one Zn(5) and one C(67) atom. In the fortieth O site, O(40) is bonded in a distorted single-bond geometry to one Zn(6) and one C(68) atom. In the forty-first O site, O(41) is bonded in a distorted water-like geometry to one Zn(1), one H(1), and one H(5) atom. In the forty-second O site, O(42) is bonded in a distorted water-like geometry to one Zn(2); one H(2,4); and one H(6,7,8) atom. In the forty-third O site, O(43) is bonded in a distorted water-like geometry to one Zn(3,4); one H(3); and one H(6,7,8) atom. The O(43)-H(6,7,8) bond length is 0.98 Å. In the forty-fourth O site, O(44) is bonded in a distorted water-like geometry to one Zn(3,4); one H(2,4); and one H(6,7,8) atom. The O(44)-Zn(3,4) bond length is 2.33 Å. The O(44)-H(2,4) bond length is 0.98 Å. The O(44)-H(6,7,8) bond length is 0.98 Å. Linkers: 4 [O]C(=O)c1cc(C([O])=O)cc(-c2cc(C([O])=O)cc(-c3cc(C([O])=O)cc(C([O])=O)c3)c2)c1. Metal clusters: 4 O.O=[C]O[Zn]12O[C]O[Zn]3(O[C]O1)(O[C]O2)O[C]O3. RCSR code: vbk. The MOF has largest included sphere 5.76 A, density 0.98 g/cm3, surface area 4119.44 m2/g, accessible volume 0.52 cm3/g