HoC15N6H18O13(CH)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two HoC15N6H18O13 clusters. In each HoC15N6H18O13 cluster, Ho(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(4), one O(5), one O(7), and one O(8) atom. The Ho(1)-O(1) bond length is 2.48 Å. The Ho(1)-O(10) bond length is 2.32 Å. The Ho(1)-O(11) bond length is 2.27 Å. The Ho(1)-O(12) bond length is 2.25 Å. The Ho(1)-O(2) bond length is 2.46 Å. The Ho(1)-O(4) bond length is 2.48 Å. The Ho(1)-O(5) bond length is 2.47 Å. The Ho(1)-O(7) bond length is 2.48 Å. The Ho(1)-O(8) bond length is 2.41 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one H(2), one H(3), one H(4), and one O(10) atom. The C(1)-H(2) bond length is 1.09 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-H(4) bond length is 1.10 Å. The C(1)-O(10) bond length is 1.44 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(4) and one O(11) atom. The C(2)-N(4) bond length is 1.39 Å. The C(2)-O(11) bond length is 1.27 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(7) atom. The C(5)-C(6) bond length is 1.37 Å. The C(5)-H(7) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(4), and one H(8) atom. The C(6)-N(4) bond length is 1.37 Å. The C(6)-H(8) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(10), and one H(9) atom. The C(7)-N(4) bond length is 1.47 Å. The C(7)-H(10) bond length is 1.09 Å. The C(7)-H(9) bond length is 1.10 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(5) and one O(12) atom. The C(8)-N(5) bond length is 1.40 Å. The C(8)-O(12) bond length is 1.27 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(13) atom. The C(11)-C(12) bond length is 1.37 Å. The C(11)-H(13) bond length is 1.09 Å. In the eighth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(5), and one H(14) atom. The C(12)-N(5) bond length is 1.37 Å. The C(12)-H(14) bond length is 1.09 Å. In the ninth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(5), one H(15), and one H(16) atom. The C(13)-N(5) bond length is 1.47 Å. The C(13)-H(15) bond length is 1.10 Å. The C(13)-H(16) bond length is 1.10 Å. In the tenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(6) and one O(13) atom. The C(14)-N(6) bond length is 1.40 Å. The C(14)-O(13) bond length is 1.26 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(17) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-H(17) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(18) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-H(18) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(19) atom. The C(17)-C(18) bond length is 1.37 Å. The C(17)-H(19) bond length is 1.09 Å. In the fourteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one N(6), and one H(20) atom. The C(18)-N(6) bond length is 1.36 Å. The C(18)-H(20) bond length is 1.09 Å. In the fifteenth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(21), and one H(22) atom. The C(19)-N(6) bond length is 1.46 Å. The C(19)-H(21) bond length is 1.10 Å. The C(19)-H(22) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(1)-O(1) bond length is 1.29 Å. The N(1)-O(2) bond length is 1.29 Å. The N(1)-O(3) bond length is 1.23 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. The N(2)-O(4) bond length is 1.29 Å. The N(2)-O(5) bond length is 1.29 Å. The N(2)-O(6) bond length is 1.24 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. The N(3)-O(7) bond length is 1.28 Å. The N(3)-O(8) bond length is 1.29 Å. The N(3)-O(9) bond length is 1.24 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(8) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(19) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(10) and one O(13) atom. The H(1)-O(10) bond length is 1.02 Å. The H(1)-O(13) bond length is 1.55 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(19) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(19) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Ho(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Ho(1) and one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Ho(1) and one N(2) atom. In the fifth O site, O(5) is bonded in a distorted L-shaped geometry to one Ho(1) and one N(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Ho(1) and one N(3) atom. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one Ho(1) and one N(3) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one N(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Ho(1), one C(1), and one H(1) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Ho(1) and one C(2) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Ho(1) and one C(8) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one C(14) and one H(1) atom. Linkers: 2 O=c1ccccn1CCn1ccccc1=O. Metal clusters: 2 CO.[O][Ho]([O])(O[N+](=O)[O-])(O[N+](=O)[O-])O[N+](=O)[O-]. The MOF has largest included sphere 2.04 A, density 1.89 g/cm3, surface area 3877.61 m2/g, accessible volume 0.11 cm3/g