CuC24H18(NO4)2 is Indium-like structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two CuC24H18(NO4)2 clusters. Cu(1) is bonded in a distorted square co-planar geometry to one N(1), one N(2), and two equivalent O(1) atoms. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-N(2) bond length is 1.99 Å. Both Cu(1)-O(1) bond lengths are 2.00 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(6) and two equivalent C(2) atoms. The C(3)-C(6) bond length is 1.47 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(3) atom. The C(4)-N(2) bond length is 1.35 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(3) and two equivalent C(5) atoms. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(1), and one O(2) atom. The C(7)-C(8) bond length is 1.48 Å. The C(7)-O(1) bond length is 1.28 Å. The C(7)-O(2) bond length is 1.29 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(7), and one C(9) atom. The C(8)-C(13) bond length is 1.41 Å. The C(8)-C(9) bond length is 1.42 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one O(3) atom. The C(9)-O(3) bond length is 1.36 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(6) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(7) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-H(7) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one O(4) atom. The C(12)-O(4) bond length is 1.37 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(9) atom. The C(13)-H(9) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1) and two equivalent C(1) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1) and two equivalent C(4) atoms. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a bent 150 degrees geometry to one O(2) and one O(3) atom. The H(5)-O(2) bond length is 1.57 Å. The H(5)-O(3) bond length is 1.02 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a distorted linear geometry to one O(2) and one O(4) atom. The H(8)-O(2) bond length is 1.57 Å. The H(8)-O(4) bond length is 1.02 Å. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one C(7), one H(5), and one H(8) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(9) and one H(5) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one C(12) and one H(8) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 4.45 A, density 1.26 g/cm3, surface area 4485.84 m2/g, accessible volume 0.29 cm3/g