AgC8N2H8SO3CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one AgC8N2H8SO3 cluster. In the AgC8N2H8SO3 cluster, Ag(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one O(2) atom. The Ag(1)-N(1) bond length is 2.14 Å. The Ag(1)-N(2) bond length is 2.21 Å. The Ag(1)-O(2) bond length is 2.51 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-S(1) bond length is 1.77 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.50 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one O(2) atom. The C(7)-N(1) bond length is 1.37 Å. The C(7)-O(2) bond length is 1.24 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(5), and one H(6) atom. The C(8)-N(2) bond length is 1.48 Å. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(7), and one S(1) atom. The N(1)-S(1) bond length is 1.64 Å. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Ag(1), one C(8), one H(10), and one H(9) atom. The N(2)-H(10) bond length is 1.02 Å. The N(2)-H(9) bond length is 1.03 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one N(2) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a distorted tetrahedral geometry to one C(1), one N(1), one O(1), and one O(3) atom. The S(1)-O(1) bond length is 1.46 Å. The S(1)-O(3) bond length is 1.46 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one C(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. Linkers: 1 NCCCCN. Metal clusters: 2 [Ag]. The MOF has largest included sphere 1.82 A, density 2.08 g/cm3, surface area 3458.04 m2/g, accessible volume 0.08 cm3/g