CHPbC13H5(NO2)2 crystallizes in the triclinic P-1 space group. The structure consists of eight 02329_fluka molecules inside a PbC13H5(NO2)2 framework. In the PbC13H5(NO2)2 framework, there are four inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 8-coordinate geometry to one N(1), one N(3), one O(11), one O(14), one O(16), one O(4), one O(5), and one O(7) atom. The Pb(1)-N(1) bond length is 2.82 Å. The Pb(1)-N(3) bond length is 2.73 Å. The Pb(1)-O(11) bond length is 2.62 Å. The Pb(1)-O(14) bond length is 2.60 Å. The Pb(1)-O(16) bond length is 2.72 Å. The Pb(1)-O(4) bond length is 2.73 Å. The Pb(1)-O(5) bond length is 2.88 Å. The Pb(1)-O(7) bond length is 2.63 Å. In the second Pb site, Pb(2) is bonded in a 8-coordinate geometry to one N(2), one N(4), one O(12), one O(13), one O(15), one O(3), one O(6), and one O(8) atom. The Pb(2)-N(2) bond length is 2.82 Å. The Pb(2)-N(4) bond length is 2.73 Å. The Pb(2)-O(12) bond length is 2.62 Å. The Pb(2)-O(13) bond length is 2.60 Å. The Pb(2)-O(15) bond length is 2.72 Å. The Pb(2)-O(3) bond length is 2.73 Å. The Pb(2)-O(6) bond length is 2.89 Å. The Pb(2)-O(8) bond length is 2.63 Å. In the third Pb site, Pb(3) is bonded in a 4-coordinate geometry to one O(1), one O(13), one O(6), and one O(9) atom. The Pb(3)-O(1) bond length is 2.47 Å. The Pb(3)-O(13) bond length is 2.71 Å. The Pb(3)-O(6) bond length is 2.46 Å. The Pb(3)-O(9) bond length is 2.44 Å. In the fourth Pb site, Pb(4) is bonded in a 4-coordinate geometry to one O(10), one O(14), one O(2), and one O(5) atom. The Pb(4)-O(10) bond length is 2.45 Å. The Pb(4)-O(14) bond length is 2.71 Å. The Pb(4)-O(2) bond length is 2.47 Å. The Pb(4)-O(5) bond length is 2.46 Å. There are forty-three inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1,2)-N(1) bond length is 1.33 Å. The C(1,2)-H(1) bond length is 1.09 Å. In the second C site, C(5,6) is bonded in a distorted single-bond geometry to one C(7) and one H(5,6) atom. The C(5,6)-C(7) bond length is 1.41 Å. The C(5,6)-H(5,6) bond length is 1.09 Å. In the third C site, C(7) is bonded in a trigonal planar geometry to one C(23,24); one C(5,6); and one C(9,10) atom. The C(7)-C(23,24) bond length is 1.41 Å. The C(7)-C(9,10) bond length is 1.46 Å. In the fourth C site, C(8) is bonded in a trigonal planar geometry to one C(23,24); one C(5,6); and one C(9,10) atom. The C(8)-C(23,24) bond length is 1.41 Å. The C(8)-C(5,6) bond length is 1.41 Å. The C(8)-C(9,10) bond length is 1.46 Å. In the fifth C site, C(9,10) is bonded in a distorted single-bond geometry to one C(7) and one N(5) atom. The C(9,10)-N(5) bond length is 1.33 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(13,14) and one N(7,8) atom. The C(11)-C(13,14) bond length is 1.46 Å. The C(11)-N(7,8) bond length is 1.33 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13,14) and one N(7,8) atom. The C(12)-C(13,14) bond length is 1.46 Å. The C(12)-N(7,8) bond length is 1.33 Å. In the eighth C site, C(13,14) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(21) atom. The C(13,14)-C(15) bond length is 1.41 Å. The C(13,14)-C(21) bond length is 1.42 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(13,14) and one H(7,8) atom. The C(15)-H(7,8) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(13,14) and one H(7,8) atom. The C(16)-C(13,14) bond length is 1.41 Å. The C(16)-H(7,8) bond length is 1.09 Å. In the eleventh C site, C(19,20) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(11,12) atom. The C(19,20)-N(3) bond length is 1.33 Å. The C(19,20)-H(11,12) bond length is 1.09 Å. In the twelfth C site, C(21) is bonded in a distorted single-bond geometry to one C(13,14) and one N(3) atom. The C(21)-N(3) bond length is 1.35 Å. In the thirteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(13,14) and one N(4) atom. The C(22)-C(13,14) bond length is 1.42 Å. The C(22)-N(4) bond length is 1.35 Å. In the fourteenth C site, C(23,24) is bonded in a distorted single-bond geometry to one C(7) and one N(1) atom. The C(23,24)-N(1) bond length is 1.35 Å. In the fifteenth C site, C(25,26) is bonded in a distorted trigonal planar geometry to one C(27), one C(35), and one N(5) atom. The C(25,26)-C(27) bond length is 1.42 Å. The C(25,26)-C(35) bond length is 1.44 Å. The C(25,26)-N(5) bond length is 1.35 Å. In the sixteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(25,26); one C(29); and one H(13,14) atom. The C(27)-C(29) bond length is 1.38 Å. The C(27)-H(13,14) bond length is 1.09 Å. In the seventeenth C site, C(28) is bonded in a distorted single-bond geometry to one C(25,26); one C(30); and one H(13,14) atom. The C(28)-C(25,26) bond length is 1.41 Å. The C(28)-C(30) bond length is 1.38 Å. The C(28)-H(13,14) bond length is 1.09 Å. In the eighteenth C site, C(29) is bonded in a trigonal planar geometry to one C(27), one C(31), and one C(37) atom. The C(29)-C(31) bond length is 1.42 Å. The C(29)-C(37) bond length is 1.50 Å. In the nineteenth C site, C(30) is bonded in a trigonal planar geometry to one C(28), one C(32), and one C(38) atom. The C(30)-C(32) bond length is 1.42 Å. The C(30)-C(38) bond length is 1.50 Å. In the twentieth C site, C(31) is bonded in a distorted single-bond geometry to one C(29) and one H(15,16) atom. The C(31)-H(15,16) bond length is 1.09 Å. In the twenty-first C site, C(32) is bonded in a distorted single-bond geometry to one C(30) and one H(15,16) atom. The C(32)-H(15,16) bond length is 1.09 Å. In the twenty-second C site, C(33,34) is bonded in a distorted single-bond geometry to one C(35) and one H(17) atom. The C(33,34)-C(35) bond length is 1.42 Å. The C(33,34)-H(17) bond length is 1.09 Å. In the twenty-third C site, C(35) is bonded in a distorted trigonal planar geometry to one C(25,26); one C(33,34); and one N(7,8) atom. The C(35)-N(7,8) bond length is 1.35 Å. In the twenty-fourth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(25,26); one C(33,34); and one N(7,8) atom. The C(36)-C(25,26) bond length is 1.44 Å. The C(36)-C(33,34) bond length is 1.42 Å. The C(36)-N(7,8) bond length is 1.35 Å. In the twenty-fifth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(1), and one O(3) atom. The C(37)-O(1) bond length is 1.28 Å. The C(37)-O(3) bond length is 1.27 Å. In the twenty-sixth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(2), and one O(4) atom. The C(38)-O(2) bond length is 1.28 Å. The C(38)-O(4) bond length is 1.27 Å. In the twenty-seventh C site, C(39,40) is bonded in a trigonal planar geometry to one C(41), one C(49), and one C(51) atom. The C(39,40)-C(41) bond length is 1.40 Å. The C(39,40)-C(49) bond length is 1.39 Å. The C(39,40)-C(51) bond length is 1.50 Å. In the twenty-eighth C site, C(41) is bonded in a distorted single-bond geometry to one C(39,40); one C(43); and one H(19,20) atom. The C(41)-C(43) bond length is 1.40 Å. The C(41)-H(19,20) bond length is 1.09 Å. In the twenty-ninth C site, C(42) is bonded in a distorted single-bond geometry to one C(39,40); one C(44); and one H(19,20) atom. The C(42)-C(39,40) bond length is 1.40 Å. The C(42)-C(44) bond length is 1.40 Å. The C(42)-H(19,20) bond length is 1.09 Å. In the thirtieth C site, C(43) is bonded in a trigonal planar geometry to one C(41), one C(45), and one C(55) atom. The C(43)-C(45) bond length is 1.40 Å. The C(43)-C(55) bond length is 1.50 Å. In the thirty-first C site, C(44) is bonded in a trigonal planar geometry to one C(42), one C(46), and one C(56) atom. The C(44)-C(46) bond length is 1.40 Å. The C(44)-C(56) bond length is 1.50 Å. In the thirty-second C site, C(45) is bonded in a distorted trigonal planar geometry to one C(43); one C(47); and one H(21,22) atom. The C(45)-C(47) bond length is 1.40 Å. The C(45)-H(21,22) bond length is 1.09 Å. In the thirty-third C site, C(46) is bonded in a distorted trigonal planar geometry to one C(44); one C(48); and one H(21,22) atom. The C(46)-C(48) bond length is 1.40 Å. The C(46)-H(21,22) bond length is 1.09 Å. In the thirty-fourth C site, C(47) is bonded in a trigonal planar geometry to one C(45), one C(49), and one C(53) atom. The C(47)-C(49) bond length is 1.40 Å. The C(47)-C(53) bond length is 1.50 Å. In the thirty-fifth C site, C(48) is bonded in a trigonal planar geometry to one C(46), one C(50), and one C(54) atom. The C(48)-C(50) bond length is 1.40 Å. The C(48)-C(54) bond length is 1.50 Å. In the thirty-sixth C site, C(49) is bonded in a distorted single-bond geometry to one C(39,40); one C(47); and one H(23,24) atom. The C(49)-H(23,24) bond length is 1.09 Å. In the thirty-seventh C site, C(50) is bonded in a distorted single-bond geometry to one C(39,40); one C(48); and one H(23,24) atom. The C(50)-C(39,40) bond length is 1.39 Å. The C(50)-H(23,24) bond length is 1.09 Å. In the thirty-eighth C site, C(51) is bonded in a distorted bent 120 degrees geometry to one C(39,40); one O(5); and one O(7) atom. The C(51)-O(5) bond length is 1.29 Å. The C(51)-O(7) bond length is 1.26 Å. In the thirty-ninth C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(39,40); one O(6); and one O(8) atom. The C(52)-C(39,40) bond length is 1.50 Å. The C(52)-O(6) bond length is 1.29 Å. The C(52)-O(8) bond length is 1.26 Å. In the fortieth C site, C(53) is bonded in a bent 120 degrees geometry to one C(47), one O(11), and one O(9) atom. The C(53)-O(11) bond length is 1.27 Å. The C(53)-O(9) bond length is 1.28 Å. In the forty-first C site, C(54) is bonded in a bent 120 degrees geometry to one C(48), one O(10), and one O(12) atom. The C(54)-O(10) bond length is 1.28 Å. The C(54)-O(12) bond length is 1.27 Å. In the forty-second C site, C(55) is bonded in a distorted bent 120 degrees geometry to one C(43), one O(13), and one O(15) atom. The C(55)-O(13) bond length is 1.29 Å. The C(55)-O(15) bond length is 1.27 Å. In the forty-third C site, C(56) is bonded in a distorted bent 120 degrees geometry to one C(44), one O(14), and one O(16) atom. The C(56)-O(14) bond length is 1.29 Å. The C(56)-O(16) bond length is 1.27 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Pb(1); one C(1,2); and one C(23,24) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pb(2); one C(1,2); and one C(23,24) atom. The N(2)-C(1,2) bond length is 1.33 Å. The N(2)-C(23,24) bond length is 1.35 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one Pb(1); one C(19,20); and one C(21) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Pb(2); one C(19,20); and one C(22) atom. The N(4)-C(19,20) bond length is 1.33 Å. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(25,26) and one C(9,10) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one C(25,26) and one C(9,10) atom. The N(6)-C(25,26) bond length is 1.35 Å. The N(6)-C(9,10) bond length is 1.33 Å. In the seventh N site, N(7,8) is bonded in a bent 120 degrees geometry to one C(11) and one C(35) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1,2) atom. The H(2)-C(1,2) bond length is 1.09 Å. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(5,6) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(11,12) is bonded in a single-bond geometry to one C(19,20) atom. In the sixth H site, H(13,14) is bonded in a single-bond geometry to one C(27) atom. In the seventh H site, H(15,16) is bonded in a single-bond geometry to one C(31) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(33,34) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(33,34) atom. The H(18)-C(33,34) bond length is 1.09 Å. In the tenth H site, H(19,20) is bonded in a single-bond geometry to one C(41) atom. In the eleventh H site, H(21,22) is bonded in a single-bond geometry to one C(45) atom. In the twelfth H site, H(23,24) is bonded in a single-bond geometry to one C(49) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pb(3) and one C(37) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Pb(4) and one C(38) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Pb(2) and one C(37) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Pb(1) and one C(38) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(4), and one C(51) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Pb(2), one Pb(3), and one C(52) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Pb(1) and one C(51) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Pb(2) and one C(52) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Pb(3) and one C(53) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Pb(4) and one C(54) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Pb(1) and one C(53) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Pb(2) and one C(54) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one Pb(2), one Pb(3), and one C(55) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Pb(1), one Pb(4), and one C(56) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one Pb(2) and one C(55) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Pb(1) and one C(56) atom. Linkers: 4 [O]C(=O)c1ccc2nc3c4cccnc4c4ncccc4c3nc2c1 ,4 [O]C(=O)c1cc(C([O])=O)cc(C([O])=O)c1. Metal clusters: 8 [Pb]. The MOF has largest included sphere 3.55 A, density 2.32 g/cm3, surface area 2585.19 m2/g, accessible volume 0.12 cm3/g