Cd2C22N3H23O11CNCH3 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules and two 1,2-dimethylhydrazine molecules inside a Cd2C22N3H23O11 framework. In the Cd2C22N3H23O11 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(4), one O(5), and one O(9) atom. The Cd(1)-O(1) bond length is 2.36 Å. The Cd(1)-O(10) bond length is 2.23 Å. The Cd(1)-O(11) bond length is 2.50 Å. The Cd(1)-O(4) bond length is 2.35 Å. The Cd(1)-O(5) bond length is 2.27 Å. The Cd(1)-O(9) bond length is 2.26 Å. In the second Cd site, Cd(2) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(5), one O(6), one O(7), and one O(8) atom. The Cd(2)-O(2) bond length is 2.27 Å. The Cd(2)-O(3) bond length is 2.34 Å. The Cd(2)-O(5) bond length is 2.32 Å. The Cd(2)-O(6) bond length is 2.62 Å. The Cd(2)-O(7) bond length is 2.38 Å. The Cd(2)-O(8) bond length is 2.31 Å. There are twenty-two inequivalent C sites. In the first C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(4) bond length is 1.40 Å. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.50 Å. In the second C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(3) atom. The C(6)-C(1) bond length is 1.40 Å. The C(6)-H(3) bond length is 1.09 Å. In the third C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(2) atom. The C(7)-C(3) bond length is 1.50 Å. The C(7)-O(1) bond length is 1.28 Å. The C(7)-O(2) bond length is 1.27 Å. In the fourth C site, C(8) is bonded in a bent 120 degrees geometry to one C(5), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.28 Å. In the fifth C site, C(10) is bonded in a single-bond geometry to one C(11) and one H(4) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(4) bond length is 1.09 Å. In the sixth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(15) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(15) bond length is 1.49 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(5) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(5) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(16) bond length is 1.50 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(6) atom. The C(14)-H(6) bond length is 1.09 Å. In the tenth C site, C(15) is bonded in a bent 120 degrees geometry to one C(11), one O(5), and one O(6) atom. The C(15)-O(5) bond length is 1.31 Å. The C(15)-O(6) bond length is 1.25 Å. In the eleventh C site, C(16) is bonded in a bent 120 degrees geometry to one C(13), one O(7), and one O(8) atom. The C(16)-O(7) bond length is 1.27 Å. The C(16)-O(8) bond length is 1.28 Å. In the twelfth C site, C(17) is bonded in a trigonal non-coplanar geometry to one C(18), one H(7), one H(8), and one H(9) atom. The C(17)-C(18) bond length is 1.51 Å. The C(17)-H(7) bond length is 1.10 Å. The C(17)-H(8) bond length is 1.10 Å. The C(17)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one N(3), and one O(9) atom. The C(18)-N(3) bond length is 1.35 Å. The C(18)-O(9) bond length is 1.26 Å. In the fourteenth C site, C(19) is bonded to one N(3), one H(10), one H(11), and one H(12) atom to form corner-sharing CH3N tetrahedra. The C(19)-N(3) bond length is 1.46 Å. The C(19)-H(10) bond length is 1.10 Å. The C(19)-H(11) bond length is 1.10 Å. The C(19)-H(12) bond length is 1.09 Å. In the fifteenth C site, C(20) is bonded to one N(3), one H(13), one H(14), and one H(15) atom to form corner-sharing CH3N tetrahedra. The C(20)-N(3) bond length is 1.46 Å. The C(20)-H(13) bond length is 1.10 Å. The C(20)-H(14) bond length is 1.10 Å. The C(20)-H(15) bond length is 1.09 Å. In the sixteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(4) and one O(10) atom. The C(22)-N(4) bond length is 1.34 Å. The C(22)-O(10) bond length is 1.27 Å. In the seventeenth C site, C(23) is bonded to one N(4), one H(19), one H(20), and one H(21) atom to form corner-sharing CH3N tetrahedra. The C(23)-N(4) bond length is 1.47 Å. The C(23)-H(19) bond length is 1.10 Å. The C(23)-H(20) bond length is 1.09 Å. The C(23)-H(21) bond length is 1.10 Å. In the eighteenth C site, C(24) is bonded to one N(4), one H(22), one H(23), and one H(24) atom to form corner-sharing CH3N tetrahedra. The C(24)-N(4) bond length is 1.47 Å. The C(24)-H(22) bond length is 1.10 Å. The C(24)-H(23) bond length is 1.09 Å. The C(24)-H(24) bond length is 1.09 Å. In the nineteenth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.42 Å. In the twentieth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(1) bond length is 1.09 Å. In the twenty-first C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(7) atom. The C(3)-C(4) bond length is 1.40 Å. In the twenty-second C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(2) atom. The C(4)-H(2) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one C(1) and one N(1) atom. The N(1)-N(1) bond length is 1.27 Å. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(18), one C(19), and one C(20) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one C(22), one C(23), and one C(24) atom. There are twenty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(23) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(23) atom. In the nineteenth H site, H(22) is bonded in a single-bond geometry to one C(24) atom. In the twentieth H site, H(23) is bonded in a single-bond geometry to one C(24) atom. In the twenty-first H site, H(24) is bonded in a single-bond geometry to one C(24) atom. In the twenty-second H site, H(25) is bonded in a single-bond geometry to one O(11) atom. The H(25)-O(11) bond length is 0.99 Å. In the twenty-third H site, H(26) is bonded in a single-bond geometry to one O(11) atom. The H(26)-O(11) bond length is 0.97 Å. There are eleven inequivalent O sites. In the first O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(18) atom. In the second O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(22) atom. In the third O site, O(11) is bonded in a distorted water-like geometry to one Cd(1), one H(25), and one H(26) atom. In the fourth O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(7) atom. In the fifth O site, O(7) is bonded in an L-shaped geometry to one Cd(2) and one C(16) atom. In the sixth O site, O(2) is bonded in a bent 120 degrees geometry to one Cd(2) and one C(7) atom. In the seventh O site, O(3) is bonded in a water-like geometry to one Cd(2) and one C(8) atom. In the eighth O site, O(4) is bonded in a 2-coordinate geometry to one Cd(1) and one C(8) atom. In the ninth O site, O(5) is bonded in a distorted T-shaped geometry to one Cd(1), one Cd(2), and one C(15) atom. In the tenth O site, O(6) is bonded in a distorted single-bond geometry to one Cd(2) and one C(15) atom. In the eleventh O site, O(8) is bonded in an L-shaped geometry to one Cd(2) and one C(16) atom. Linkers: 4 [O]C(=O)c1cc([N][N]c2cc(C([O])=O)cc(C([O])=O)c2)cc(C([O])=O)c1. Metal clusters: 8 [Cd]. The MOF has largest included sphere 7.18 A, density 1.10 g/cm3, surface area 4365.45 m2/g, accessible volume 0.46 cm3/g