ZnC14H18(NO)6 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four ZnC14H18(NO)6 clusters. Zn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent O(1) atoms. Both Zn(1)-N(1) bond lengths are 2.15 Å. Both Zn(1)-N(3) bond lengths are 2.17 Å. Both Zn(1)-O(1) bond lengths are 2.31 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(1)-N(1) bond length is 1.48 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one N(1), one H(3), and one H(4) atom. The C(2)-C(3) bond length is 1.51 Å. The C(2)-N(1) bond length is 1.47 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(5) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(5) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(4)-H(5) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(6) atom. The C(5)-H(6) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(7) atom. The C(6)-N(3) bond length is 1.35 Å. The C(6)-H(7) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(8) atom. The C(7)-N(3) bond length is 1.35 Å. The C(7)-H(8) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Zn(1), one C(1), one C(2), and one H(9) atom. The N(1)-H(9) bond length is 1.03 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(2)-O(1) bond length is 1.30 Å. The N(2)-O(2) bond length is 1.25 Å. The N(2)-O(3) bond length is 1.27 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(6), and one C(7) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one N(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(2) atom. Linkers: 2 c1cc(CNCCNCc2ccncc2)ccn1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 4.06 A, density 1.46 g/cm3, surface area 4550.89 m2/g, accessible volume 0.21 cm3/g