CdC15NH11O7CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a CdC15NH11O7 framework. In the CdC15NH11O7 framework, Cd(1) is bonded in a 7-coordinate geometry to one N(1), one O(1), one O(2), one O(3), one O(7), and two equivalent O(4) atoms. The Cd(1)-N(1) bond length is 2.32 Å. The Cd(1)-O(1) bond length is 2.41 Å. The Cd(1)-O(2) bond length is 2.28 Å. The Cd(1)-O(3) bond length is 2.69 Å. The Cd(1)-O(7) bond length is 2.36 Å. There is one shorter (2.42 Å) and one longer (2.47 Å) Cd(1)-O(4) bond length. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(4) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(4) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(5) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(5) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.45 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(6) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(6) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(7) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(7) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(8) atom. The C(6)-H(8) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(9) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-C(14) bond length is 1.51 Å. The C(8)-C(9) bond length is 1.41 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(15), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(15) bond length is 1.51 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(10) atom. The C(10)-H(10) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(11) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(16) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(16) bond length is 1.48 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(12) atom. The C(13)-H(12) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(1), and one O(2) atom. The C(14)-O(1) bond length is 1.26 Å. The C(14)-O(2) bond length is 1.28 Å. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(15)-O(3) bond length is 1.26 Å. The C(15)-O(4) bond length is 1.27 Å. In the fifteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(5), and one O(6) atom. The C(16)-O(5) bond length is 1.25 Å. The C(16)-O(6) bond length is 1.33 Å. N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(5) and one O(6) atom. The H(1)-O(5) bond length is 1.55 Å. The H(1)-O(6) bond length is 1.03 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. The H(2)-O(7) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(7) atom. The H(3)-O(7) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(13) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(14) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cd(1) and one C(14) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(15) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(16) and one H(1) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one C(16) and one H(1) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Cd(1), one H(2), and one H(3) atom. Linkers: 2 [O]C(=O)c1ccc(C(=O)O)cc1C([O])=O ,2 [O]C(=O)c1cc(C(=O)O)ccc1[C]=O ,1 C(/C=C/c1ccncc1)=C\c1ccncc1 ,2 [O]C(=O)c1ccc(C([O])=O)c(C([O])=O)c1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 1.63 A, density 2.01 g/cm3, surface area 3749.34 m2/g, accessible volume 0.09 cm3/g