CuC8N4H11SO5CF3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two trifluoromethane molecules and one CuC8N4H11SO5 cluster. In the CuC8N4H11SO5 cluster, Cu(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(2), one N(3), one O(2), and one O(5) atom. The Cu(1)-N(1) bond length is 1.95 Å. The Cu(1)-N(2) bond length is 1.93 Å. The Cu(1)-N(3) bond length is 2.02 Å. The Cu(1)-O(2) bond length is 1.95 Å. The Cu(1)-O(5) bond length is 2.49 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-C(3) bond length is 1.49 Å. The C(1)-C(4) bond length is 1.41 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(7), and one N(2) atom. The C(2)-C(7) bond length is 1.44 Å. The C(2)-N(2) bond length is 1.37 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one H(1), one H(2), and one H(3) atom. The C(3)-H(1) bond length is 1.09 Å. The C(3)-H(2) bond length is 1.10 Å. The C(3)-H(3) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.46 Å. The C(4)-N(1) bond length is 1.36 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one N(3) atom. The C(5)-C(6) bond length is 1.49 Å. The C(5)-N(3) bond length is 1.31 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one H(4), one H(5), and one H(6) atom. The C(6)-H(4) bond length is 1.09 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(8), and one N(4) atom. The C(7)-C(8) bond length is 1.50 Å. The C(7)-N(4) bond length is 1.31 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(7); one H(7); and two equivalent H(8,9) atoms. The C(8)-H(7) bond length is 1.10 Å. Both C(8)-H(8,9) bond lengths are 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(4), and one N(2) atom. The N(1)-N(2) bond length is 1.31 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(2), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(5), and one O(1) atom. The N(3)-O(1) bond length is 1.37 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(7), one H(10), and one O(2) atom. The N(4)-H(10) bond length is 1.05 Å. The N(4)-O(2) bond length is 1.32 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8,9) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one N(4) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one O(1) atom. The H(11)-O(1) bond length is 1.00 Å. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(3), one O(4), and one O(5) atom. The S(1)-O(3) bond length is 1.47 Å. The S(1)-O(4) bond length is 1.46 Å. The S(1)-O(5) bond length is 1.46 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one N(3) and one H(11) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one N(4) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one S(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cu(1) and one S(1) atom. Linkers: 1 C[C](N[O])C1=C(C)[C](/C(C)=N/O)N=N1 ,1 CC1=C(/C(C)=N/O)N=N/C1=C(/C)N[O]. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.04 A, density 1.95 g/cm3, surface area 4081.82 m2/g, accessible volume 0.10 cm3/g