CdC36N6H24(O3F4)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CdC36N6H24(O3F4)2 cluster. Cd(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent O(1) atoms. Both Cd(1)-N(1) bond lengths are 2.42 Å. Both Cd(1)-N(2) bond lengths are 2.34 Å. Both Cd(1)-O(1) bond lengths are 2.35 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(1) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(2) atom. The C(2)-C(4) bond length is 1.39 Å. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one H(3) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.51 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one C(5), one C(7), one H(5), and one H(6) atom. The C(6)-C(7) bond length is 1.51 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-C(9) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one F(1,2) atom. The C(8)-F(1,2) bond length is 1.36 Å. In the ninth C site, C(9) is bonded in a single-bond geometry to one C(7) and one F(1,2) atom. The C(9)-F(1,2) bond length is 1.36 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(7) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(2), and one H(8) atom. The C(11)-C(13) bond length is 1.39 Å. The C(11)-N(2) bond length is 1.35 Å. The C(11)-H(8) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(14) and one H(9) atom. The C(12)-C(14) bond length is 1.40 Å. The C(12)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(11), one C(14), and one H(10) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(15) atom. The C(14)-C(15) bond length is 1.51 Å. In the fifteenth C site, C(15) is bonded in a distorted water-like geometry to one C(14), one C(16), one H(11), and one H(12) atom. The C(15)-C(16) bond length is 1.50 Å. The C(15)-H(11) bond length is 1.10 Å. The C(15)-H(12) bond length is 1.10 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-C(18) bond length is 1.39 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one F(3) atom. The C(17)-F(3) bond length is 1.37 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(16) and one F(4) atom. The C(18)-F(4) bond length is 1.36 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one C(11) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(3)-O(1) bond length is 1.30 Å. The N(3)-O(2) bond length is 1.26 Å. The N(3)-O(3) bond length is 1.25 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one N(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(3) atom. There are three inequivalent F sites. In the first F site, F(1,2) is bonded in a single-bond geometry to one C(8) atom. In the second F site, F(3) is bonded in a single-bond geometry to one C(17) atom. In the third F site, F(4) is bonded in a single-bond geometry to one C(18) atom. Linkers: 2 Fc1c(F)c(Cc2ccncc2)c(F)c(F)c1Cc1ccncc1 ,2 Fc1c(F)c(Cc2ccncc2)c(F)c(F)c1Cc1c[c]ncc1. Metal clusters: 1 [Cd]. The MOF has largest included sphere 3.64 A, density 1.49 g/cm3, surface area 4460.27 m2/g, accessible volume 0.23 cm3/g