CdC10NH4O5(CH)3 crystallizes in the triclinic P-1 space group. The structure consists of twelve 02329_fluka molecules inside a CdC10NH4O5 framework. In the CdC10NH4O5 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one O(4), one O(5), one O(6), one O(8), and one O(9) atom. The Cd(1)-N(1) bond length is 2.37 Å. The Cd(1)-O(4) bond length is 2.41 Å. The Cd(1)-O(5) bond length is 2.55 Å. The Cd(1)-O(6) bond length is 2.40 Å. The Cd(1)-O(8) bond length is 2.27 Å. The Cd(1)-O(9) bond length is 2.34 Å. In the second Cd site, Cd(2) is bonded in a 6-coordinate geometry to one N(2), one O(10), one O(3), one O(5), one O(6), and one O(7) atom. The Cd(2)-N(2) bond length is 2.37 Å. The Cd(2)-O(10) bond length is 2.33 Å. The Cd(2)-O(3) bond length is 2.41 Å. The Cd(2)-O(5) bond length is 2.39 Å. The Cd(2)-O(6) bond length is 2.56 Å. The Cd(2)-O(7) bond length is 2.27 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(1) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one H(2) atom. The C(2)-C(4) bond length is 1.40 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(9) and one O(1) atom. The C(7)-C(9) bond length is 1.39 Å. The C(7)-O(1) bond length is 1.38 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(10) and one O(2) atom. The C(8)-C(10) bond length is 1.39 Å. The C(8)-O(2) bond length is 1.38 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one H(7) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-H(7) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(8) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(21) and one O(1) atom. The C(11)-C(21) bond length is 1.40 Å. The C(11)-O(1) bond length is 1.39 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(22) and one O(2) atom. The C(12)-C(22) bond length is 1.40 Å. The C(12)-O(2) bond length is 1.39 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(19) and one H(13,14) atom. The C(17)-C(19) bond length is 1.40 Å. The C(17)-H(13,14) bond length is 1.09 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(20) and one H(13,14) atom. The C(18)-C(20) bond length is 1.40 Å. The C(18)-H(13,14) bond length is 1.09 Å. In the thirteenth C site, C(19) is bonded in a trigonal planar geometry to one C(17), one C(21), and one C(23) atom. The C(19)-C(21) bond length is 1.41 Å. The C(19)-C(23) bond length is 1.49 Å. In the fourteenth C site, C(20) is bonded in a trigonal planar geometry to one C(18), one C(22), and one C(24) atom. The C(20)-C(22) bond length is 1.41 Å. The C(20)-C(24) bond length is 1.50 Å. In the fifteenth C site, C(21) is bonded in a trigonal planar geometry to one C(11), one C(19), and one C(25) atom. The C(21)-C(25) bond length is 1.51 Å. In the sixteenth C site, C(22) is bonded in a trigonal planar geometry to one C(12), one C(20), and one C(26) atom. The C(22)-C(26) bond length is 1.51 Å. In the seventeenth C site, C(23) is bonded in a bent 120 degrees geometry to one C(19), one O(3), and one O(5) atom. The C(23)-O(3) bond length is 1.27 Å. The C(23)-O(5) bond length is 1.28 Å. In the eighteenth C site, C(24) is bonded in a bent 120 degrees geometry to one C(20), one O(4), and one O(6) atom. The C(24)-O(4) bond length is 1.27 Å. The C(24)-O(6) bond length is 1.28 Å. In the nineteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(7), and one O(9) atom. The C(25)-O(7) bond length is 1.26 Å. The C(25)-O(9) bond length is 1.28 Å. In the twentieth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(10), and one O(8) atom. The C(26)-O(10) bond length is 1.28 Å. The C(26)-O(8) bond length is 1.26 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(2), one C(10), and one C(2) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(13,14) is bonded in a single-bond geometry to one C(17) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(11) and one C(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(12) and one C(8) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(2) and one C(23) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(24) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(23) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(24) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Cd(2) and one C(25) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Cd(1) and one C(26) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Cd(1) and one C(25) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Cd(2) and one C(26) atom. Linkers: 4 [O]C(=O)c1cccc(Oc2cccnc2)c1C([O])=O. Metal clusters: 4 [Cd]. The MOF has largest included sphere 2.12 A, density 2.04 g/cm3, surface area 3310.42 m2/g, accessible volume 0.13 cm3/g