CuC14H12(NO)4 is beta Polonium structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CuC14H12(NO)4 clusters. Cu(1) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent O(2) atoms. Both Cu(1)-N(2) bond lengths are 1.98 Å. Both Cu(1)-O(2) bond lengths are 1.99 Å. There are seven inequivalent C sites. In the first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(2) atom. The C(3)-C(4) bond length is 1.37 Å. The C(3)-N(1) bond length is 1.39 Å. The C(3)-H(2) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(3) atom. The C(4)-N(2) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.08 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(5)-C(2) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(5) atom. The C(6)-N(1) bond length is 1.36 Å. The C(6)-N(2) bond length is 1.33 Å. The C(6)-H(5) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(6) atom. The C(7)-C(2) bond length is 1.40 Å. The C(7)-H(6) bond length is 1.09 Å. In the sixth C site, C(1) is bonded in a trigonal planar geometry to one H(1), one O(1), and one O(2) atom. The C(1)-H(1) bond length is 1.11 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.29 Å. In the seventh C site, C(2) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(1) atom. The C(2)-N(1) bond length is 1.42 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(4), and one C(6) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(6) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a water-like geometry to one Cu(1) and one C(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one C(1) atom. Linkers: 2 c1cn(-c2ccc(-n3ccnc3)cc2)cn1 ,2 [c]1cn(-c2ccc(-n3ccnc3)cc2)cn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 1.83 A, density 1.77 g/cm3, surface area 4572.80 m2/g, accessible volume 0.11 cm3/g