AgC6H12S4O3CF3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two trifluoromethane molecules and two AgC6H12S4O3 clusters. In each AgC6H12S4O3 cluster, Ag(1) is bonded in a distorted tetrahedral geometry to one S(1), one S(2), one S(3), and one O(3) atom. The Ag(1)-S(1) bond length is 2.49 Å. The Ag(1)-S(2) bond length is 2.48 Å. The Ag(1)-S(3) bond length is 2.48 Å. The Ag(1)-O(3) bond length is 2.66 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one H(1), one H(2), and one S(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.82 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one H(3), one H(4), and one S(1) atom. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. The C(2)-S(1) bond length is 1.82 Å. In the third C site, C(3) is bonded in a distorted water-like geometry to one H(5), one H(6), and one S(2) atom. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(6) bond length is 1.10 Å. The C(3)-S(2) bond length is 1.81 Å. In the fourth C site, C(4) is bonded in a distorted water-like geometry to one H(7), one H(8), and one S(2) atom. The C(4)-H(7) bond length is 1.10 Å. The C(4)-H(8) bond length is 1.10 Å. The C(4)-S(2) bond length is 1.82 Å. In the fifth C site, C(5) is bonded in a distorted water-like geometry to one H(10), one H(9), and one S(3) atom. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. The C(5)-S(3) bond length is 1.82 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one H(11), one H(12), and one S(3) atom. The C(6)-H(11) bond length is 1.10 Å. The C(6)-H(12) bond length is 1.10 Å. The C(6)-S(3) bond length is 1.82 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(1), and one C(2) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(3), and one C(4) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(5), and one C(6) atom. In the fourth S site, S(4) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. The S(4)-O(1) bond length is 1.46 Å. The S(4)-O(2) bond length is 1.45 Å. The S(4)-O(3) bond length is 1.47 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(4) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(1) and one S(4) atom. Linkers: 3 C1CSCCS1. Metal clusters: 2 [Ag].[O]S([O])([O])C(F)(F)F. The MOF has largest included sphere 1.69 A, density 2.23 g/cm3, surface area 3461.74 m2/g, accessible volume 0.05 cm3/g