CdC14H15(N4S)2(CH2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and one CdC14H15(N4S)2 cluster. In the CdC14H15(N4S)2 cluster, Cd(1) is bonded in a distorted octahedral geometry to one N(1), one N(3), one N(5), one N(7), one N(8), and one S(1) atom. The Cd(1)-N(1) bond length is 2.35 Å. The Cd(1)-N(3) bond length is 2.34 Å. The Cd(1)-N(5) bond length is 2.36 Å. The Cd(1)-N(7) bond length is 2.32 Å. The Cd(1)-N(8) bond length is 2.34 Å. The Cd(1)-S(1) bond length is 2.86 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(2) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-N(2) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(3) atom. The C(3)-N(1) bond length is 1.38 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(4) atom. The C(4)-N(3) bond length is 1.33 Å. The C(4)-N(4) bond length is 1.36 Å. The C(4)-H(4) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(4), and one H(5) atom. The C(5)-C(6) bond length is 1.38 Å. The C(5)-N(4) bond length is 1.38 Å. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(3), and one H(6) atom. The C(6)-N(3) bond length is 1.38 Å. The C(6)-H(6) bond length is 1.08 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(7), and one H(8) atom. The C(7)-N(2) bond length is 1.46 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.10 Å. In the eighth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(13), and one H(14) atom. The C(10)-N(4) bond length is 1.46 Å. The C(10)-H(13) bond length is 1.10 Å. The C(10)-H(14) bond length is 1.10 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(15) atom. The C(11)-N(5) bond length is 1.33 Å. The C(11)-N(6) bond length is 1.36 Å. The C(11)-H(15) bond length is 1.08 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(6), and one H(16) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-N(6) bond length is 1.38 Å. The C(12)-H(16) bond length is 1.08 Å. In the eleventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(5), and one H(17) atom. The C(13)-N(5) bond length is 1.38 Å. The C(13)-H(17) bond length is 1.08 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(18), and one H(19) atom. The C(14)-N(6) bond length is 1.46 Å. The C(14)-H(18) bond length is 1.10 Å. The C(14)-H(19) bond length is 1.10 Å. In the thirteenth C site, C(16) is bonded in a distorted linear geometry to one N(7) and one S(1) atom. The C(16)-N(7) bond length is 1.18 Å. The C(16)-S(1) bond length is 1.63 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one N(8) and one S(2) atom. The C(17)-N(8) bond length is 1.19 Å. The C(17)-S(2) bond length is 1.62 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(7) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(4), and one C(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(5) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one C(13) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(14) atom. In the seventh N site, N(7) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(16) atom. In the eighth N site, N(8) is bonded in a distorted linear geometry to one Cd(1) and one C(17) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(14) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(14) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Cd(1) and one C(16) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(17) atom. Linkers: 3 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 1.99 A, density 1.66 g/cm3, surface area 4771.06 m2/g, accessible volume 0.14 cm3/g