(C3H2)2CdC14H28S2(N2O3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one 2,3-dimethyl-1,3-butadiene molecule and one CdC14H28S2(N2O3)2 cluster. In the CdC14H28S2(N2O3)2 cluster, Cd(1) is bonded to two equivalent N(1), two equivalent N(2), and two equivalent O(1) atoms to form CdN4O2 octahedra that share corners with two equivalent C(10)H3N tetrahedra and corners with two equivalent C(7)H3N tetrahedra. Both Cd(1)-N(1) bond lengths are 2.36 Å. Both Cd(1)-N(2) bond lengths are 2.38 Å. Both Cd(1)-O(1) bond lengths are 2.44 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-S(1) bond length is 1.78 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(6) atom. The C(6)-H(6) bond length is 1.09 Å. In the fourth C site, C(7) is bonded to one N(1), one H(7), one H(8), and one H(9) atom to form CH3N tetrahedra that share  a cornercorner with one Cd(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 63°. The C(7)-N(1) bond length is 1.47 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.09 Å. The C(7)-H(9) bond length is 1.10 Å. In the fifth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(1); one H(10); and one H(11,12) atom. The C(8)-N(1) bond length is 1.47 Å. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(11,12) bond length is 1.10 Å. In the sixth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(2); one H(11,12); and one H(13) atom. The C(9)-N(2) bond length is 1.47 Å. The C(9)-H(11,12) bond length is 1.11 Å. The C(9)-H(13) bond length is 1.10 Å. In the seventh C site, C(10) is bonded to one N(2), one H(14), one H(15), and one H(16) atom to form CH3N tetrahedra that share  a cornercorner with one Cd(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 65°. The C(10)-N(2) bond length is 1.47 Å. The C(10)-H(14) bond length is 1.10 Å. The C(10)-H(15) bond length is 1.10 Å. The C(10)-H(16) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Cd(1), one C(7), one C(8), and one H(1) atom. The N(1)-H(1) bond length is 1.03 Å. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Cd(1), one C(10), one C(9), and one H(2) atom. The N(2)-H(2) bond length is 1.03 Å. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(11,12) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(10) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(2) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.46 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cd(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. Linkers: 1 [O]S([O])([O])c1ccc(-c2ccc(S([O])([O])[O])cc2)cc1. Metal clusters: 1 [Cd]. The MOF has largest included sphere 1.86 A, density 1.72 g/cm3, surface area 4489.83 m2/g, accessible volume 0.10 cm3/g