Mn3C54H30(N2O7)2(CH)10C2O is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of twenty 02329_fluka molecules, two dimethyl ether molecules, and two Mn3C54H30(N2O7)2 clusters. In each Mn3C54H30(N2O7)2 cluster, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one N(1), one N(5), one O(1), one O(12), one O(14), and one O(8) atom. The Mn(1)-N(1) bond length is 2.23 Å. The Mn(1)-N(5) bond length is 2.24 Å. The Mn(1)-O(1) bond length is 2.07 Å. The Mn(1)-O(12) bond length is 2.20 Å. The Mn(1)-O(14) bond length is 2.07 Å. The Mn(1)-O(8) bond length is 2.41 Å. In the second Mn site, Mn(3) is bonded in a 6-coordinate geometry to one N(3), one N(7), one O(10), one O(16), one O(3), and one O(6) atom. The Mn(3)-N(3) bond length is 2.23 Å. The Mn(3)-N(7) bond length is 2.24 Å. The Mn(3)-O(10) bond length is 2.20 Å. The Mn(3)-O(16) bond length is 2.06 Å. The Mn(3)-O(3) bond length is 2.07 Å. The Mn(3)-O(6) bond length is 2.40 Å. In the third Mn site, Mn(6) is bonded in an octahedral geometry to one O(17), one O(19), one O(22), one O(24), one O(6), and one O(8) atom. The Mn(6)-O(17) bond length is 2.18 Å. The Mn(6)-O(19) bond length is 2.18 Å. The Mn(6)-O(22) bond length is 2.15 Å. The Mn(6)-O(24) bond length is 2.15 Å. The Mn(6)-O(6) bond length is 2.24 Å. The Mn(6)-O(8) bond length is 2.24 Å. There are thirty-nine inequivalent C sites. In the first C site, C(44) is bonded in a trigonal planar geometry to one C(37,38,39,40); one C(45,46,47,48); and one C(56) atom. The C(44)-C(37,38,39,40) bond length is 1.40 Å. The C(44)-C(45,46,47,48) bond length is 1.40 Å. The C(44)-C(56) bond length is 1.48 Å. In the second C site, C(45,46,47,48) is bonded in a distorted single-bond geometry to one C(41,42,43) and one H(25,26,27,28) atom. The C(45,46,47,48)-C(41,42,43) bond length is 1.41 Å. The C(45,46,47,48)-H(25,26,27,28) bond length is 1.09 Å. In the third C site, C(54) is bonded in a bent 120 degrees geometry to one C(41,42,43); one O(10); and one O(6) atom. The C(54)-C(41,42,43) bond length is 1.48 Å. The C(54)-O(10) bond length is 1.28 Å. The C(54)-O(6) bond length is 1.29 Å. In the fourth C site, C(56) is bonded in a bent 120 degrees geometry to one C(44), one O(12), and one O(8) atom. The C(56)-O(12) bond length is 1.28 Å. The C(56)-O(8) bond length is 1.29 Å. In the fifth C site, C(58) is bonded in a distorted bent 120 degrees geometry to one C(62), one O(14), and one O(22) atom. The C(58)-C(62) bond length is 1.50 Å. The C(58)-O(14) bond length is 1.28 Å. The C(58)-O(22) bond length is 1.27 Å. In the sixth C site, C(60) is bonded in a distorted bent 120 degrees geometry to one C(64), one O(16), and one O(24) atom. The C(60)-C(64) bond length is 1.50 Å. The C(60)-O(16) bond length is 1.28 Å. The C(60)-O(24) bond length is 1.27 Å. In the seventh C site, C(62) is bonded in a trigonal planar geometry to one C(58); one C(66,68); and one C(82,84) atom. The C(62)-C(66,68) bond length is 1.40 Å. The C(62)-C(82,84) bond length is 1.40 Å. In the eighth C site, C(64) is bonded in a trigonal planar geometry to one C(60); one C(66,68); and one C(82,84) atom. The C(64)-C(66,68) bond length is 1.40 Å. The C(64)-C(82,84) bond length is 1.40 Å. In the ninth C site, C(66,68) is bonded in a distorted single-bond geometry to one C(62) and one H(33,34,35,36) atom. The C(66,68)-H(33,34,35,36) bond length is 1.09 Å. In the tenth C site, C(82,84) is bonded in a distorted single-bond geometry to one C(62) and one H(45,46,47,48) atom. The C(82,84)-H(45,46,47,48) bond length is 1.09 Å. In the eleventh C site, C(85,86,87,88) is bonded in a distorted trigonal planar geometry to one C(89), one N(1), and one H(49) atom. The C(85,86,87,88)-C(89) bond length is 1.41 Å. The C(85,86,87,88)-N(1) bond length is 1.33 Å. The C(85,86,87,88)-H(49) bond length is 1.09 Å. In the twelfth C site, C(89) is bonded in a distorted single-bond geometry to one C(85,86,87,88) and one H(53,54,55,56) atom. The C(89)-H(53,54,55,56) bond length is 1.09 Å. In the thirteenth C site, C(91) is bonded in a distorted single-bond geometry to one C(85,86,87,88) and one H(53,54,55,56) atom. The C(91)-C(85,86,87,88) bond length is 1.41 Å. The C(91)-H(53,54,55,56) bond length is 1.09 Å. In the fourteenth C site, C(93,94,95,96) is bonded in a distorted single-bond geometry to one C(97) and one H(57,58,59,60) atom. The C(93,94,95,96)-C(97) bond length is 1.41 Å. The C(93,94,95,96)-H(57,58,59,60) bond length is 1.09 Å. In the fifteenth C site, C(97) is bonded in a trigonal planar geometry to one C(101); one C(113,114,115,116); and one C(93,94,95,96) atom. The C(97)-C(101) bond length is 1.42 Å. The C(97)-C(113,114,115,116) bond length is 1.43 Å. In the sixteenth C site, C(99) is bonded in a trigonal planar geometry to one C(102,103,104); one C(113,114,115,116); and one C(93,94,95,96) atom. The C(99)-C(102,103,104) bond length is 1.42 Å. The C(99)-C(113,114,115,116) bond length is 1.43 Å. The C(99)-C(93,94,95,96) bond length is 1.41 Å. In the seventeenth C site, C(101) is bonded in a distorted trigonal planar geometry to one C(105), one C(97), and one N(1) atom. The C(101)-C(105) bond length is 1.44 Å. The C(101)-N(1) bond length is 1.36 Å. In the eighteenth C site, C(102,103,104) is bonded in a distorted trigonal planar geometry to one C(106,108); one C(98,100); and one N(2) atom. The C(102,103,104)-C(106,108) bond length is 1.44 Å. The C(102,103,104)-C(98,100) bond length is 1.42 Å. The C(102,103,104)-N(2) bond length is 1.36 Å. In the nineteenth C site, C(105) is bonded in a distorted trigonal planar geometry to one C(101), one C(109), and one N(5) atom. The C(105)-C(109) bond length is 1.42 Å. The C(105)-N(5) bond length is 1.35 Å. In the twentieth C site, C(107) is bonded in a distorted trigonal planar geometry to one C(102,103,104); one C(110,111,112); and one N(7) atom. The C(107)-C(102,103,104) bond length is 1.44 Å. The C(107)-C(110,111,112) bond length is 1.42 Å. The C(107)-N(7) bond length is 1.35 Å. In the twenty-first C site, C(109) is bonded in a trigonal planar geometry to one C(105); one C(117,118,119,120); and one C(121,122,123,124) atom. The C(109)-C(117,118,119,120) bond length is 1.43 Å. The C(109)-C(121,122,123,124) bond length is 1.41 Å. In the twenty-second C site, C(110,111,112) is bonded in a trigonal planar geometry to one C(106,108); one C(117,118,119,120); and one C(121,122,123,124) atom. The C(110,111,112)-C(106,108) bond length is 1.42 Å. The C(110,111,112)-C(117,118,119,120) bond length is 1.43 Å. The C(110,111,112)-C(121,122,123,124) bond length is 1.41 Å. In the twenty-third C site, C(113,114,115,116) is bonded in a distorted single-bond geometry to one C(97) and one H(61,62,63,64) atom. The C(113,114,115,116)-H(61,62,63,64) bond length is 1.09 Å. In the twenty-fourth C site, C(117,118,119,120) is bonded in a distorted single-bond geometry to one C(109) and one H(65,66,67,68) atom. The C(117,118,119,120)-H(65,66,67,68) bond length is 1.09 Å. In the twenty-fifth C site, C(121,122,123,124) is bonded in a distorted trigonal planar geometry to one C(109); one C(125); and one H(69,70,71,72) atom. The C(121,122,123,124)-C(125) bond length is 1.38 Å. The C(121,122,123,124)-H(69,70,71,72) bond length is 1.09 Å. In the twenty-sixth C site, C(125) is bonded in a distorted trigonal planar geometry to one C(121,122,123,124); one C(129,130,131,132); and one H(73,74,75,76) atom. The C(125)-C(129,130,131,132) bond length is 1.40 Å. The C(125)-H(73,74,75,76) bond length is 1.09 Å. In the twenty-seventh C site, C(126,127,128) is bonded in a distorted trigonal planar geometry to one C(121,122,123,124); one C(129,130,131,132); and one H(73,74,75,76) atom. The C(126,127,128)-C(121,122,123,124) bond length is 1.38 Å. The C(126,127,128)-C(129,130,131,132) bond length is 1.40 Å. The C(126,127,128)-H(73,74,75,76) bond length is 1.09 Å. In the twenty-eighth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(17) atom. The C(1)-C(5) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(17) bond length is 1.27 Å. In the twenty-ninth C site, C(129,130,131,132) is bonded in a distorted bent 120 degrees geometry to one C(125), one N(5), and one H(77) atom. The C(129,130,131,132)-N(5) bond length is 1.33 Å. The C(129,130,131,132)-H(77) bond length is 1.09 Å. In the thirtieth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(19), and one O(3) atom. The C(3)-C(7) bond length is 1.50 Å. The C(3)-O(19) bond length is 1.27 Å. The C(3)-O(3) bond length is 1.28 Å. In the thirty-first C site, C(5) is bonded in a trigonal planar geometry to one C(1); one C(25,26,27,28); and one C(9,10,11,12) atom. The C(5)-C(25,26,27,28) bond length is 1.40 Å. The C(5)-C(9,10,11,12) bond length is 1.40 Å. In the thirty-second C site, C(7) is bonded in a trigonal planar geometry to one C(25,26,27,28); one C(3); and one C(9,10,11,12) atom. The C(7)-C(25,26,27,28) bond length is 1.40 Å. The C(7)-C(9,10,11,12) bond length is 1.40 Å. In the thirty-third C site, C(9,10,11,12) is bonded in a distorted single-bond geometry to one C(13,14,15,16); one C(5); and one H(1,2,3,4) atom. The C(9,10,11,12)-C(13,14,15,16) bond length is 1.39 Å. The C(9,10,11,12)-H(1,2,3,4) bond length is 1.09 Å. In the thirty-fourth C site, C(13,14,15,16) is bonded in a distorted trigonal planar geometry to one C(17,19); one C(9,10,11,12); and one H(5,6,7,8) atom. The C(13,14,15,16)-C(17,19) bond length is 1.40 Å. The C(13,14,15,16)-H(5,6,7,8) bond length is 1.09 Å. In the thirty-fifth C site, C(17,19) is bonded in a distorted single-bond geometry to one C(13,14,15,16) and one O(25,26,27,28) atom. The C(17,19)-O(25,26,27,28) bond length is 1.40 Å. In the thirty-sixth C site, C(25,26,27,28) is bonded in a distorted single-bond geometry to one C(5) and one H(13,14,15,16) atom. The C(25,26,27,28)-H(13,14,15,16) bond length is 1.09 Å. In the thirty-seventh C site, C(29,31) is bonded in a distorted single-bond geometry to one O(25,26,27,28) atom. The C(29,31)-O(25,26,27,28) bond length is 1.38 Å. In the thirty-eighth C site, C(37,38,39,40) is bonded in a distorted single-bond geometry to one C(41,42,43) and one H(21,22,23,24) atom. The C(37,38,39,40)-C(41,42,43) bond length is 1.40 Å. The C(37,38,39,40)-H(21,22,23,24) bond length is 1.09 Å. In the thirty-ninth C site, C(41,42,43) is bonded in a trigonal planar geometry to one C(37,38,39,40); one C(45,46,47,48); and one C(53,55) atom. The C(41,42,43)-C(53,55) bond length is 1.48 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(1); one C(101); and one C(85,86,87,88) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Mn(3); one C(102,103,104); and one C(85,86,87,88) atom. The N(3)-C(102,103,104) bond length is 1.36 Å. The N(3)-C(85,86,87,88) bond length is 1.33 Å. In the third N site, N(5) is bonded in a trigonal planar geometry to one Mn(1); one C(105); and one C(129,130,131,132) atom. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one Mn(3); one C(107); and one C(129,130,131,132) atom. The N(7)-C(129,130,131,132) bond length is 1.33 Å. There are seventeen inequivalent H sites. In the first H site, H(1,2,3,4) is bonded in a single-bond geometry to one C(9,10,11,12) atom. In the second H site, H(5,6,7,8) is bonded in a single-bond geometry to one C(13,14,15,16) atom. In the third H site, H(13,14,15,16) is bonded in a single-bond geometry to one C(25,26,27,28) atom. In the fourth H site, H(21,22,23,24) is bonded in a single-bond geometry to one C(37,38,39,40) atom. In the fifth H site, H(25,26,27,28) is bonded in a single-bond geometry to one C(45,46,47,48) atom. In the sixth H site, H(33,34,35,36) is bonded in a single-bond geometry to one C(65,67) atom. The H(33,34,35,36)-C(65,67) bond length is 1.09 Å. In the seventh H site, H(45,46,47,48) is bonded in a single-bond geometry to one C(81,83) atom. The H(45,46,47,48)-C(81,83) bond length is 1.09 Å. In the eighth H site, H(49) is bonded in a single-bond geometry to one C(85,86,87,88) atom. In the ninth H site, H(51) is bonded in a single-bond geometry to one C(85,86,87,88) atom. The H(51)-C(85,86,87,88) bond length is 1.09 Å. In the tenth H site, H(53,54,55,56) is bonded in a single-bond geometry to one C(89) atom. In the eleventh H site, H(57,58,59,60) is bonded in a single-bond geometry to one C(93,94,95,96) atom. In the twelfth H site, H(61,62,63,64) is bonded in a single-bond geometry to one C(113,114,115,116) atom. In the thirteenth H site, H(65,66,67,68) is bonded in a single-bond geometry to one C(117,118,119,120) atom. In the fourteenth H site, H(69,70,71,72) is bonded in a single-bond geometry to one C(121,122,123,124) atom. In the fifteenth H site, H(73,74,75,76) is bonded in a single-bond geometry to one C(125) atom. In the sixteenth H site, H(77) is bonded in a single-bond geometry to one C(129,130,131,132) atom. In the seventeenth H site, H(78,79,80) is bonded in a single-bond geometry to one C(129,130,131,132) atom. The H(78,79,80)-C(129,130,131,132) bond length is 1.09 Å. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(3) atom. In the third O site, O(6) is bonded in a 3-coordinate geometry to one Mn(3), one Mn(6), and one C(54) atom. In the fourth O site, O(8) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(6), and one C(56) atom. In the fifth O site, O(25,26,27,28) is bonded in a bent 120 degrees geometry to one C(17,19) and one C(29,31) atom. In the sixth O site, O(10) is bonded in a distorted L-shaped geometry to one Mn(3) and one C(54) atom. In the seventh O site, O(12) is bonded in a distorted L-shaped geometry to one Mn(1) and one C(56) atom. In the eighth O site, O(14) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(58) atom. In the ninth O site, O(16) is bonded in a bent 150 degrees geometry to one Mn(3) and one C(60) atom. In the tenth O site, O(17) is bonded in a bent 150 degrees geometry to one Mn(6) and one C(1) atom. In the eleventh O site, O(19) is bonded in a bent 150 degrees geometry to one Mn(6) and one C(3) atom. In the twelfth O site, O(22) is bonded in a bent 120 degrees geometry to one Mn(6) and one C(58) atom. In the thirteenth O site, O(24) is bonded in a bent 120 degrees geometry to one Mn(6) and one C(60) atom. Linkers: 6 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,2 c1cnc2c(c1)ccc1cccnc12. Metal clusters: 2 [C]1O[Mn]2O[C]O[Mn]34(O1)(O[C]O2)O[C]O[Mn](O[C]O3)O[C]O4. RCSR code: pcu. The MOF has largest included sphere 4.85 A, density 1.34 g/cm3, surface area 4319.52 m2/g, accessible volume 0.27 cm3/g