(CH2)2CuC8N16H12(O3Cl)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one CuC8N16H12(O3Cl)2 cluster. In the CuC8N16H12(O3Cl)2 cluster, Cu(1) is bonded in an octahedral geometry to two equivalent N(4), two equivalent N(8), and two equivalent O(1) atoms. Both Cu(1)-N(4) bond lengths are 2.00 Å. Both Cu(1)-N(8) bond lengths are 2.02 Å. Both Cu(1)-O(1) bond lengths are 2.50 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(4), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(4) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(2), and one H(3) atom. The C(2)-N(1) bond length is 1.46 Å. The C(2)-H(2) bond length is 1.09 Å. The C(2)-H(3) bond length is 1.10 Å. In the third C site, C(4) is bonded in a 3-coordinate geometry to one N(6), one H(6), and one H(7) atom. The C(4)-N(6) bond length is 1.47 Å. The C(4)-H(6) bond length is 1.10 Å. The C(4)-H(7) bond length is 1.10 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one N(5), one N(8), and one H(8) atom. The C(5)-N(5) bond length is 1.33 Å. The C(5)-N(8) bond length is 1.36 Å. The C(5)-H(8) bond length is 1.08 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(1), one C(2), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.29 Å. In the third N site, N(3) is bonded in a water-like geometry to one N(2) and one N(4) atom. The N(3)-N(4) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one N(3) atom. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(5) and one N(6) atom. The N(5)-N(6) bond length is 1.34 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one C(4), one N(5), and one N(7) atom. The N(6)-N(7) bond length is 1.31 Å. In the seventh N site, N(7) is bonded in a water-like geometry to one N(6) and one N(8) atom. The N(7)-N(8) bond length is 1.32 Å. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(5), and one N(7) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one Cl(1) atom. The O(1)-Cl(1) bond length is 1.51 Å. In the second O site, O(2) is bonded in a single-bond geometry to one Cl(1) atom. The O(2)-Cl(1) bond length is 1.50 Å. In the third O site, O(3) is bonded in a single-bond geometry to one Cl(1) atom. The O(3)-Cl(1) bond length is 1.50 Å. Cl(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. Linkers: 2 c1nnn(CCCn2cnnn2)n1. Metal clusters: 1 [Cu]. The MOF has largest included sphere 1.95 A, density 1.87 g/cm3, surface area 4097.74 m2/g, accessible volume 0.11 cm3/g