NdC6NH7O8CH crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a NdC6NH7O8 framework. In the NdC6NH7O8 framework, Nd(1) is bonded in a 8-coordinate geometry to one N(1), one O(1), one O(2), one O(3), one O(5), one O(6), one O(7), and one O(8) atom. The Nd(1)-N(1) bond length is 2.57 Å. The Nd(1)-O(1) bond length is 2.45 Å. The Nd(1)-O(2) bond length is 2.45 Å. The Nd(1)-O(3) bond length is 2.52 Å. The Nd(1)-O(5) bond length is 2.39 Å. The Nd(1)-O(6) bond length is 2.67 Å. The Nd(1)-O(7) bond length is 2.44 Å. The Nd(1)-O(8) bond length is 2.41 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(1) atom. The C(2)-N(1) bond length is 1.35 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one O(5) atom. The C(4)-O(5) bond length is 1.31 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(8) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(8) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(1) atom. The C(6)-C(7) bond length is 1.52 Å. The C(6)-N(1) bond length is 1.35 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(3), and one O(4) atom. The C(7)-O(3) bond length is 1.29 Å. The C(7)-O(4) bond length is 1.26 Å. N(1) is bonded in a distorted trigonal planar geometry to one Nd(1), one C(2), and one C(6) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(6) atom. The H(1)-O(6) bond length is 0.97 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(6) atom. The H(2)-O(6) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) and one O(7) atom. The H(3)-O(4) bond length is 1.70 Å. The H(3)-O(7) bond length is 1.00 Å. In the fourth H site, H(4) is bonded in a distorted linear geometry to one O(1) and one O(7) atom. The H(4)-O(1) bond length is 1.62 Å. The H(4)-O(7) bond length is 1.01 Å. In the fifth H site, H(5) is bonded in a distorted linear geometry to one O(5) and one O(8) atom. The H(5)-O(5) bond length is 1.60 Å. The H(5)-O(8) bond length is 1.01 Å. In the sixth H site, H(6) is bonded in a distorted single-bond geometry to one O(3) and one O(8) atom. The H(6)-O(3) bond length is 1.66 Å. The H(6)-O(8) bond length is 1.00 Å. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(5) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Nd(1), one C(1), and one H(4) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Nd(1), one C(7), and one H(6) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one C(7) and one H(3) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Nd(1), one C(4), and one H(5) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Nd(1), one H(1), and one H(2) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Nd(1), one H(3), and one H(4) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Nd(1), one H(5), and one H(6) atom. Linkers: 4 [O]C(=O)c1cc([O])cc(C([O])=O)n1. Metal clusters: 4 [Nd]. The MOF has largest included sphere 2.25 A, density 2.29 g/cm3, surface area 2798.05 m2/g, accessible volume 0.09 cm3/g