CuC11H8(NO2)2(CH)4CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two 02329_fluka molecules, and one CuC11H8(NO2)2 cluster. In the CuC11H8(NO2)2 cluster, Cu(1) is bonded to one N(1), one N(2), one O(3), and two equivalent O(1) atoms to form edge-sharing CuN2O3 square pyramids. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-N(2) bond length is 2.00 Å. The Cu(1)-O(3) bond length is 1.96 Å. There is one shorter (1.97 Å) and one longer (2.38 Å) Cu(1)-O(1) bond length. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.47 Å. The C(5)-N(1) bond length is 1.36 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-N(2) bond length is 1.36 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one N(2) and one H(8) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(8) bond length is 1.09 Å. In the seventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(1), and one O(2) atom. The C(11)-C(13) bond length is 1.53 Å. The C(11)-O(1) bond length is 1.31 Å. The C(11)-O(2) bond length is 1.24 Å. In the eighth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(3), and one O(4) atom. The C(12)-C(13) bond length is 1.54 Å. The C(12)-O(3) bond length is 1.30 Å. The C(12)-O(4) bond length is 1.24 Å. In the ninth C site, C(13) is bonded in a tetrahedral geometry to one C(11), one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.54 Å. The C(13)-C(16) bond length is 1.57 Å. In the tenth C site, C(14) is bonded in a distorted water-like geometry to one C(13), one H(10), and one H(9) atom. The C(14)-H(10) bond length is 1.10 Å. The C(14)-H(9) bond length is 1.10 Å. In the eleventh C site, C(16) is bonded in a distorted water-like geometry to one C(13), one H(13), and one H(14) atom. The C(16)-H(13) bond length is 1.10 Å. The C(16)-H(14) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(6) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Cu(1) and one C(11) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(11) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(12) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(12) atom. Linkers: 2 [O]C(=O)C1(C([O])=O)CCC1. Metal clusters: 1 O=[C]O[Cu]O[C]=O.O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 2.06 A, density 1.69 g/cm3, surface area 4303.52 m2/g, accessible volume 0.12 cm3/g