ZnC14H10(NO2)2CH3(CH)8 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules; two 02329_fluka molecules; two 2,4-dimethyl-1,3-pentadiene molecules; and one ZnC14H10(NO2)2 cluster. In the ZnC14H10(NO2)2 cluster, Zn(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.06 Å. The Zn(1)-O(1) bond length is 2.06 Å. The Zn(1)-O(2) bond length is 2.08 Å. The Zn(1)-O(3) bond length is 2.07 Å. The Zn(1)-O(4) bond length is 2.08 Å. There are fourteen inequivalent C sites. In the first C site, C(2) is bonded in a distorted water-like geometry to one C(3), one H(4), and one H(5) atom. The C(2)-C(3) bond length is 1.49 Å. The C(2)-H(4) bond length is 1.09 Å. The C(2)-H(5) bond length is 1.10 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one N(2) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-N(2) bond length is 1.37 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one N(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(9) bond length is 1.41 Å. The C(4)-N(1) bond length is 1.40 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(6) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(6) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(7) atom. The C(6)-C(7) bond length is 1.41 Å. The C(6)-H(7) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(8) atom. The C(7)-H(8) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(9) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(9) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one N(2) atom. The C(9)-N(2) bond length is 1.39 Å. In the ninth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one N(2), one H(10), and one H(11) atom. The C(10)-C(11) bond length is 1.51 Å. The C(10)-N(2) bond length is 1.46 Å. The C(10)-H(10) bond length is 1.10 Å. The C(10)-H(11) bond length is 1.10 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(13) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(13) bond length is 1.40 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(12) atom. The C(12)-H(12) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(11) and one H(13) atom. The C(13)-H(13) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(14)-O(1) bond length is 1.27 Å. The C(14)-O(2) bond length is 1.28 Å. In the fourteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(23)-O(3) bond length is 1.27 Å. The C(23)-O(4) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(3), and one C(9) atom. There are ten inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(23) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(23) atom. Linkers: 2 [O]C(=O)Cc1cccc(CC([O])=O)c1 ,1 CCc1nc2ccccc2n1Cc1ccc(Cn2c(CC)nc3ccccc32)cc1. Metal clusters: 1 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 2.15 A, density 1.58 g/cm3, surface area 4670.15 m2/g, accessible volume 0.13 cm3/g