AgC8H8S4(NO)3(CH)2 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four AgC8H8S4(NO)3 clusters. In each AgC8H8S4(NO)3 cluster, Ag(1) is bonded in a trigonal pyramidal geometry to one N(1), one N(2), one S(4), and one O(1) atom. The Ag(1)-N(1) bond length is 2.29 Å. The Ag(1)-N(2) bond length is 2.25 Å. The Ag(1)-S(4) bond length is 2.48 Å. The Ag(1)-O(1) bond length is 2.57 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-N(1) bond length is 1.37 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one H(2), and one S(1) atom. The C(2)-H(2) bond length is 1.09 Å. The C(2)-S(1) bond length is 1.72 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one S(2) atom. The C(3)-N(1) bond length is 1.33 Å. The C(3)-S(1) bond length is 1.73 Å. The C(3)-S(2) bond length is 1.73 Å. In the fourth C site, C(4) is bonded in a distorted water-like geometry to one H(3), one H(4), and one S(2) atom. The C(4)-H(3) bond length is 1.10 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-S(2) bond length is 1.83 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(2), and one H(6) atom. The C(6)-C(7) bond length is 1.37 Å. The C(6)-N(2) bond length is 1.38 Å. The C(6)-H(6) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one H(7), and one S(3) atom. The C(7)-H(7) bond length is 1.08 Å. The C(7)-S(3) bond length is 1.72 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one N(2), one S(3), and one S(4) atom. The C(8)-N(2) bond length is 1.33 Å. The C(8)-S(3) bond length is 1.73 Å. The C(8)-S(4) bond length is 1.74 Å. In the eighth C site, C(9) is bonded in a distorted water-like geometry to one H(8), one H(9), and one S(4) atom. The C(9)-H(8) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. The C(9)-S(4) bond length is 1.83 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(6), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(3)-O(1) bond length is 1.28 Å. The N(3)-O(2) bond length is 1.27 Å. The N(3)-O(3) bond length is 1.26 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(2) and one C(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(3) and one C(4) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one C(7) and one C(8) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(8), and one C(9) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Ag(1) and one N(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(3) atom. Linkers: 4 C(=C/CSc1nccs1)\CSc1nccs1. Metal clusters: 4 [Ag].[O][N+](=O)[O-]. The MOF has largest included sphere 1.70 A, density 2.03 g/cm3, surface area 3780.93 m2/g, accessible volume 0.08 cm3/g