RhCu3C9H12S6(NI)3(CH2)6 crystallizes in the cubic I-43d space group. The structure consists of ninety-six 02329_fluka molecules inside a RhCu3C9H12S6(NI)3 framework. In each RhCu3C9H12S6(NI)3 framework, Rh(1) is bonded in an octahedral geometry to three equivalent S(1) and three equivalent S(2) atoms. All Rh(1)-S(1) bond lengths are 2.35 Å. All Rh(1)-S(2) bond lengths are 2.40 Å. Cu(1) is bonded in a 4-coordinate geometry to one S(1), one S(2), and two equivalent I(1) atoms. The Cu(1)-S(1) bond length is 2.35 Å. The Cu(1)-S(2) bond length is 2.36 Å. There is one shorter (2.60 Å) and one longer (2.64 Å) Cu(1)-I(1) bond length. There are three inequivalent C sites. In the first C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(7), and one H(8) atom. The C(5)-N(1) bond length is 1.47 Å. The C(5)-H(7) bond length is 1.10 Å. The C(5)-H(8) bond length is 1.10 Å. In the second C site, C(1) is bonded in a distorted single-bond geometry to one N(1), one S(1), and one S(2) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-S(1) bond length is 1.73 Å. The C(1)-S(2) bond length is 1.73 Å. In the third C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(2)-N(1) bond length is 1.47 Å. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. N(1) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(5) atom. There are four inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a distorted T-shaped geometry to one Rh(1), one Cu(1), and one C(1) atom. In the second S site, S(1) is bonded in a distorted T-shaped geometry to one Rh(1), one Cu(1), and one C(1) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 24 [S]C(=S)N1CCCC1. Metal clusters: 24 [Cu]. The MOF has largest included sphere 4.69 A, density 2.36 g/cm3, surface area 2847.75 m2/g, accessible volume 0.16 cm3/g