CuC7NH2O4 crystallizes in the monoclinic C2/c space group. Cu(1) is bonded in a trigonal bipyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-N(1) bond length is 2.01 Å. The Cu(1)-O(1) bond length is 1.98 Å. The Cu(1)-O(2) bond length is 2.32 Å. The Cu(1)-O(3) bond length is 1.97 Å. The Cu(1)-O(4) bond length is 1.99 Å. There are seven inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(2) bond length is 1.39 Å. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the second C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(7) bond length is 1.50 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(5), and one N(1) atom. The C(5)-C(5) bond length is 1.49 Å. The C(5)-N(1) bond length is 1.35 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(6)-C(1) bond length is 1.51 Å. The C(6)-O(1) bond length is 1.29 Å. The C(6)-O(2) bond length is 1.25 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(7)-O(3) bond length is 1.27 Å. The C(7)-O(4) bond length is 1.27 Å. In the sixth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. In the seventh C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Cu(1) and one C(6) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(6) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)c(-c2nc(C([O])=O)ccc2C([O])=O)n1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 1.59 A, density 2.38 g/cm3, surface area 2699.17 m2/g, accessible volume 0.07 cm3/g