Ag3C10H10S2(NO4)3 crystallizes in the monoclinic Pc space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), one O(10), one O(4), one O(5), and one O(9) atom to form distorted corner-sharing AgO5 trigonal bipyramids. The Ag(1)-O(1) bond length is 2.53 Å. The Ag(1)-O(10) bond length is 2.48 Å. The Ag(1)-O(4) bond length is 2.46 Å. The Ag(1)-O(5) bond length is 2.43 Å. The Ag(1)-O(9) bond length is 2.41 Å. In the second Ag site, Ag(2) is bonded to one O(1), one O(12), one O(3), one O(6), and one O(7) atom to form distorted corner-sharing AgO5 trigonal bipyramids. The Ag(2)-O(1) bond length is 2.60 Å. The Ag(2)-O(12) bond length is 2.67 Å. The Ag(2)-O(3) bond length is 2.35 Å. The Ag(2)-O(6) bond length is 2.35 Å. The Ag(2)-O(7) bond length is 2.56 Å. In the third Ag site, Ag(3) is bonded in a distorted see-saw-like geometry to one O(11), one O(12), one O(2), and one O(7) atom. The Ag(3)-O(11) bond length is 2.52 Å. The Ag(3)-O(12) bond length is 2.34 Å. The Ag(3)-O(2) bond length is 2.38 Å. The Ag(3)-O(7) bond length is 2.40 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(5), and one S(1) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-C(5) bond length is 1.37 Å. The C(1)-S(1) bond length is 1.77 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(5) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-H(5) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(6) atom. The C(3)-C(4) bond length is 1.43 Å. The C(3)-H(6) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one O(4) atom. The C(4)-N(1) bond length is 1.39 Å. The C(4)-O(4) bond length is 1.27 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one H(7) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(7) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(10), one C(7), and one S(2) atom. The C(6)-C(10) bond length is 1.37 Å. The C(6)-C(7) bond length is 1.42 Å. The C(6)-S(2) bond length is 1.76 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(8) atom. The C(7)-H(8) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(9) atom. The C(8)-C(9) bond length is 1.43 Å. The C(8)-H(9) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(2), and one O(8) atom. The C(9)-N(2) bond length is 1.38 Å. The C(9)-O(8) bond length is 1.28 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(2), and one H(10) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(10) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(4), one C(5), and one H(3) atom. The N(1)-H(3) bond length is 1.05 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(9), and one H(4) atom. The N(2)-H(4) bond length is 1.06 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(10), one O(11), and one O(9) atom. The N(3)-O(10) bond length is 1.28 Å. The N(3)-O(11) bond length is 1.26 Å. The N(3)-O(9) bond length is 1.27 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(12) and one O(8) atom. The H(1)-O(12) bond length is 1.01 Å. The H(1)-O(8) bond length is 1.65 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(10) and one O(12) atom. The H(2)-O(10) bond length is 1.66 Å. The H(2)-O(12) bond length is 1.00 Å. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a distorted linear geometry to one N(2) and one O(4) atom. The H(4)-O(4) bond length is 1.64 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.48 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one O(5), one O(6), and one O(7) atom. The S(2)-O(5) bond length is 1.47 Å. The S(2)-O(6) bond length is 1.48 Å. The S(2)-O(7) bond length is 1.48 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one S(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Ag(1), one C(4), and one H(4) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one S(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ag(2) and one S(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Ag(2), one Ag(3), and one S(2) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one C(9) and one H(1) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one N(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Ag(1), one N(3), and one H(2) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one N(3) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Ag(2), one Ag(3), one H(1), and one H(2) atom. Linkers: 2 [O]S([O])([O])c1ccc(=O)[nH]c1. Metal clusters: 6 [Ag]. The MOF has largest included sphere 1.92 A, density 2.86 g/cm3, surface area 2358.79 m2/g, accessible volume 0.05 cm3/g