ZnC11H8(N3O2)2(CH2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and one ZnC11H8(N3O2)2 cluster. In the ZnC11H8(N3O2)2 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.05 Å. The Zn(1)-O(1) bond length is 2.08 Å. The Zn(1)-O(2) bond length is 2.08 Å. The Zn(1)-O(3) bond length is 2.09 Å. The Zn(1)-O(4) bond length is 2.06 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(5)-O(3) bond length is 1.27 Å. The C(5)-O(4) bond length is 1.28 Å. In the third C site, C(6) is bonded in a distorted trigonal planar geometry to one C(11), one C(7), and one N(1) atom. The C(6)-C(11) bond length is 1.42 Å. The C(6)-C(7) bond length is 1.40 Å. The C(6)-N(1) bond length is 1.39 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(8) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(8) bond length is 1.09 Å. In the fifth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(9) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-H(9) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(10) atom. The C(9)-H(10) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(11) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(11) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(6), and one N(2) atom. The C(11)-N(2) bond length is 1.39 Å. In the ninth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one N(1), and one N(2) atom. The C(12)-C(13) bond length is 1.49 Å. The C(12)-N(1) bond length is 1.33 Å. The C(12)-N(2) bond length is 1.36 Å. In the tenth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one C(12), one N(3), one H(12), and one H(13) atom. The C(13)-N(3) bond length is 1.46 Å. The C(13)-H(12) bond length is 1.10 Å. The C(13)-H(13) bond length is 1.10 Å. In the eleventh C site, C(14) is bonded in a trigonal planar geometry to one N(3), one N(6), and one H(14) atom. The C(14)-N(3) bond length is 1.34 Å. The C(14)-N(6) bond length is 1.33 Å. The C(14)-H(14) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(12), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(12), and one H(1) atom. The N(2)-H(1) bond length is 1.02 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(13), one C(14), and one N(4) atom. The N(3)-N(4) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one N(3) and one N(5) atom. The N(4)-N(5) bond length is 1.30 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.37 Å. In the sixth N site, N(6) is bonded in a distorted water-like geometry to one C(14) and one N(5) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. Linkers: 2 [O]C(=O)CCCC([O])=O. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.86 A, density 1.67 g/cm3, surface area 4320.34 m2/g, accessible volume 0.15 cm3/g