Cu2C13H11(N3I)2(CH2)3CH is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, six 02329_fluka molecules, and one Cu2C13H11(N3I)2 cluster. In the Cu2C13H11(N3I)2 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 1-coordinate geometry to one N(1), one I(1), and two equivalent I(2) atoms. The Cu(1)-N(1) bond length is 2.00 Å. The Cu(1)-I(1) bond length is 2.55 Å. There is one shorter (2.70 Å) and one longer (2.80 Å) Cu(1)-I(2) bond length. In the second Cu site, Cu(2) is bonded in a distorted bent 120 degrees geometry to one N(2), one N(6), one I(1), and one I(2) atom. The Cu(2)-N(2) bond length is 1.99 Å. The Cu(2)-N(6) bond length is 2.02 Å. The Cu(2)-I(1) bond length is 2.62 Å. The Cu(2)-I(2) bond length is 2.75 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-N(1) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one N(3) atom. The C(6)-N(3) bond length is 1.37 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(5), and one H(6) atom. The C(7)-N(3) bond length is 1.45 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. In the eighth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(13), and one H(14) atom. The C(11)-N(4) bond length is 1.46 Å. The C(11)-H(13) bond length is 1.10 Å. The C(11)-H(14) bond length is 1.10 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one N(4) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(17) bond length is 1.41 Å. The C(12)-N(4) bond length is 1.37 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(15) atom. The C(13)-H(15) bond length is 1.09 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(17) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(17) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(18) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(18) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(12), one C(16), and one N(6) atom. The C(17)-N(6) bond length is 1.38 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.32 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(2), one N(1), and one N(3) atom. The N(2)-N(3) bond length is 1.36 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(11), one C(12), and one N(5) atom. The N(4)-N(5) bond length is 1.35 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.31 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(17), and one N(5) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(16) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to one Cu(1) and one Cu(2) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one Cu(2) and two equivalent Cu(1) atoms. Linkers: 2 c1ccc2c(c1)nnn2CCCCCn1nnc2ccccc21. Metal clusters: 1 I[Cu]12(I)N=N[Cu][Cu]1(I)(I)N=N[Cu]2. The MOF has largest included sphere 2.78 A, density 2.29 g/cm3, surface area 3374.61 m2/g, accessible volume 0.10 cm3/g