CuC12H9(NO3)2CH is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one CuC12H9(NO3)2 cluster. In the CuC12H9(NO3)2 cluster, Cu(1) is bonded in a square pyramidal geometry to one N(2), one O(1), one O(3), one O(5), and one O(6) atom. The Cu(1)-N(2) bond length is 1.98 Å. The Cu(1)-O(1) bond length is 1.97 Å. The Cu(1)-O(3) bond length is 1.94 Å. The Cu(1)-O(5) bond length is 2.00 Å. The Cu(1)-O(6) bond length is 2.38 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-N(1) bond length is 1.37 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(3) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(1) atom. The C(6)-C(7) bond length is 1.52 Å. The C(6)-N(1) bond length is 1.37 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(4), and one O(5) atom. The C(7)-O(4) bond length is 1.24 Å. The C(7)-O(5) bond length is 1.28 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(2), and one H(4) atom. The C(8)-C(9) bond length is 1.38 Å. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(4) bond length is 1.08 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(5) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-H(5) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(9) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-C(13) bond length is 1.45 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(6) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(6) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one H(7) atom. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(7) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(13)-H(8) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one O(3) atom. The N(1)-O(3) bond length is 1.33 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(12), and one C(8) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one O(6) atom. The H(9)-O(6) bond length is 0.97 Å. In the ninth H site, H(10) is bonded in a single-bond geometry to one O(6) atom. The H(10)-O(6) bond length is 0.99 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Cu(1), one H(10), and one H(9) atom. Linkers: 2 [O]C(=O)c1cccc(C([O])=O)[n+]1[O-] ,1 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 2 O.[O][Cu](O[C]=O)O[C]=O. The MOF has largest included sphere 3.18 A, density 1.67 g/cm3, surface area 4021.60 m2/g, accessible volume 0.11 cm3/g