CHCdC14N4H10O2Cl crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a CdC14N4H10O2Cl framework. In the CdC14N4H10O2Cl framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 6-coordinate geometry to one N(3), one N(7), one O(2), one O(4), and two equivalent Cl(1) atoms. The Cd(1)-N(3) bond length is 2.32 Å. The Cd(1)-N(7) bond length is 2.40 Å. The Cd(1)-O(2) bond length is 2.29 Å. The Cd(1)-O(4) bond length is 2.68 Å. There is one shorter (2.54 Å) and one longer (2.69 Å) Cd(1)-Cl(1) bond length. In the second Cd site, Cd(2) is bonded in a 6-coordinate geometry to one N(4), one N(8), one O(1), one O(3), and two equivalent Cl(2) atoms. The Cd(2)-N(4) bond length is 2.32 Å. The Cd(2)-N(8) bond length is 2.40 Å. The Cd(2)-O(1) bond length is 2.29 Å. The Cd(2)-O(3) bond length is 2.68 Å. There is one shorter (2.54 Å) and one longer (2.69 Å) Cd(2)-Cl(2) bond length. There are twenty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(3) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(4) atom. The C(2)-C(4) bond length is 1.51 Å. The C(2)-O(2) bond length is 1.29 Å. The C(2)-O(4) bond length is 1.26 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(5) atom. The C(3)-C(13) bond length is 1.40 Å. The C(3)-C(5) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(6) atom. The C(4)-C(14) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(1,2) atom. The C(5)-H(1,2) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(1,2) atom. The C(6)-H(1,2) bond length is 1.09 Å. In the seventh C site, C(7,8) is bonded in a distorted single-bond geometry to one C(9) and one H(3,4) atom. The C(7,8)-C(9) bond length is 1.40 Å. The C(7,8)-H(3,4) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(7,8); and one N(1,2) atom. The C(9)-C(11,12) bond length is 1.40 Å. The C(9)-N(1,2) bond length is 1.43 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(7,8); and one N(1,2) atom. The C(10)-C(11,12) bond length is 1.40 Å. The C(10)-C(7,8) bond length is 1.40 Å. The C(10)-N(1,2) bond length is 1.43 Å. In the tenth C site, C(11,12) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one H(5) atom. The C(11,12)-C(13) bond length is 1.39 Å. The C(11,12)-H(5) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(11,12); one C(3); and one H(7,8) atom. The C(13)-H(7,8) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(11,12); one C(4); and one H(7,8) atom. The C(14)-C(11,12) bond length is 1.39 Å. The C(14)-H(7,8) bond length is 1.09 Å. In the thirteenth C site, C(15,16) is bonded in a distorted trigonal non-coplanar geometry to one C(17), one H(11), one H(13), and one H(9) atom. The C(15,16)-C(17) bond length is 1.47 Å. The C(15,16)-H(11) bond length is 1.10 Å. The C(15,16)-H(13) bond length is 1.09 Å. The C(15,16)-H(9) bond length is 1.10 Å. In the fourteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(15,16); one N(1,2); and one N(3) atom. The C(17)-N(1,2) bond length is 1.37 Å. The C(17)-N(3) bond length is 1.33 Å. In the fifteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(15,16); one N(1,2); and one N(4) atom. The C(18)-C(15,16) bond length is 1.47 Å. The C(18)-N(1,2) bond length is 1.37 Å. The C(18)-N(4) bond length is 1.33 Å. In the sixteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(21,22); one N(1,2); and one N(5) atom. The C(19)-C(21,22) bond length is 1.46 Å. The C(19)-N(1,2) bond length is 1.38 Å. The C(19)-N(5) bond length is 1.32 Å. In the seventeenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(21,22); one N(1,2); and one N(6) atom. The C(20)-C(21,22) bond length is 1.46 Å. The C(20)-N(1,2) bond length is 1.38 Å. The C(20)-N(6) bond length is 1.32 Å. In the eighteenth C site, C(21,22) is bonded in a trigonal planar geometry to one C(19); one C(23,24); and one C(29) atom. The C(21,22)-C(23,24) bond length is 1.40 Å. The C(21,22)-C(29) bond length is 1.40 Å. In the nineteenth C site, C(23,24) is bonded in a distorted single-bond geometry to one C(21,22) and one H(15,16) atom. The C(23,24)-H(15,16) bond length is 1.09 Å. In the twentieth C site, C(27) is bonded in a distorted trigonal planar geometry to one N(7) and one H(19,20) atom. The C(27)-N(7) bond length is 1.34 Å. The C(27)-H(19,20) bond length is 1.09 Å. In the twenty-first C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(19,20) atom. The C(28)-N(8) bond length is 1.34 Å. The C(28)-H(19,20) bond length is 1.09 Å. In the twenty-second C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(21,22); one N(7); and one H(21,22) atom. The C(29)-N(7) bond length is 1.34 Å. The C(29)-H(21,22) bond length is 1.09 Å. In the twenty-third C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(21,22); one N(8); and one H(21,22) atom. The C(30)-C(21,22) bond length is 1.40 Å. The C(30)-N(8) bond length is 1.34 Å. The C(30)-H(21,22) bond length is 1.09 Å. There are seven inequivalent N sites. In the first N site, N(1,2) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(9) atom. In the second N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(17), and one N(5) atom. The N(3)-N(5) bond length is 1.37 Å. In the third N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(18), and one N(6) atom. The N(4)-N(6) bond length is 1.37 Å. In the fourth N site, N(5) is bonded in a distorted water-like geometry to one C(19) and one N(3) atom. In the fifth N site, N(6) is bonded in a distorted water-like geometry to one C(20) and one N(4) atom. In the sixth N site, N(7) is bonded in a trigonal planar geometry to one Cd(1), one C(27), and one C(29) atom. In the seventh N site, N(8) is bonded in a trigonal planar geometry to one Cd(2), one C(28), and one C(30) atom. There are fourteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(7,8) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(11,12) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(11,12) atom. The H(6)-C(11,12) bond length is 1.09 Å. In the fifth H site, H(7,8) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(15,16) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(15,16) atom. The H(10)-C(15,16) bond length is 1.10 Å. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(15,16) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(15,16) atom. The H(12)-C(15,16) bond length is 1.10 Å. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(15,16) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(15,16) atom. The H(14)-C(15,16) bond length is 1.09 Å. In the twelfth H site, H(15,16) is bonded in a single-bond geometry to one C(23,24) atom. In the thirteenth H site, H(19,20) is bonded in a single-bond geometry to one C(27) atom. In the fourteenth H site, H(21,22) is bonded in a single-bond geometry to one C(29) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(2) and one C(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1) and one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cd(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cd(1) and one C(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in an L-shaped geometry to two equivalent Cd(1) atoms. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to two equivalent Cd(2) atoms. Linkers: 4 Cc1nnc(-c2cccnc2)n1-c1ccc(C([O])=O)cc1. Metal clusters: 2 O=[C]O[Cd]Cl.O=[C]O[Cd]Cl. The MOF has largest included sphere 3.51 A, density 1.71 g/cm3, surface area 4035.04 m2/g, accessible volume 0.16 cm3/g