NaC6NH6(CH3)2(CH)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight 02329_fluka molecules, and two NaC6NH6 clusters. In each NaC6NH6 cluster, Na(1) is bonded in a 4-coordinate geometry to one C(6), two equivalent N(1), and one H(16) atom. The Na(1)-C(6) bond length is 2.54 Å. There is one shorter (2.40 Å) and one longer (2.50 Å) Na(1)-N(1) bond length. The Na(1)-H(16) bond length is 2.57 Å. There are six inequivalent C sites. In the first C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(12) atom. The C(8)-C(7) bond length is 1.41 Å. The C(8)-H(12) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(8), and one H(9) atom. The C(4)-N(1) bond length is 1.45 Å. The C(4)-H(8) bond length is 1.12 Å. The C(4)-H(9) bond length is 1.11 Å. In the third C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(16) atom. The C(12)-C(7) bond length is 1.40 Å. The C(12)-H(16) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(7) and one N(1) atom. The C(5)-C(7) bond length is 1.50 Å. The C(5)-N(1) bond length is 1.35 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one Na(1), one H(10), and one H(11) atom. The C(6)-H(10) bond length is 1.09 Å. The C(6)-H(11) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(5), and one C(8) atom. N(1) is bonded in a 4-coordinate geometry to two equivalent Na(1), one C(4), and one C(5) atom. There are six inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(16) is bonded in a single-bond geometry to one Na(1) and one C(12) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(8) atom. Linkers: 4 C=C([N]CC(C)C)c1ccccc1. Metal clusters: 4 [Na]. The MOF has largest included sphere 1.95 A, density 1.18 g/cm3, surface area 5850.59 m2/g, accessible volume 0.20 cm3/g