(CH)3CH2CuC15H17S2O2Br is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two 02329_fluka molecules, and one CuC15H17S2O2Br cluster. In the CuC15H17S2O2Br cluster, Cu(1) is bonded to one S(1), one S(2), and two equivalent Br(1) atoms to form edge-sharing CuS2Br2 tetrahedra. The Cu(1)-S(1) bond length is 2.26 Å. The Cu(1)-S(2) bond length is 2.27 Å. There is one shorter (2.46 Å) and one longer (2.49 Å) Cu(1)-Br(1) bond length. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one O(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-O(1) bond length is 1.43 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(4), and one O(2) atom. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. The C(2)-O(2) bond length is 1.43 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(8) and one O(2) atom. The C(3)-C(8) bond length is 1.41 Å. The C(3)-O(2) bond length is 1.37 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(8) bond length is 1.09 Å. In the fifth C site, C(8) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.50 Å. In the sixth C site, C(9) is bonded in a distorted water-like geometry to one C(8), one H(10), one H(9), and one S(1) atom. The C(9)-H(10) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. The C(9)-S(1) bond length is 1.83 Å. In the seventh C site, C(10) is bonded in a distorted water-like geometry to one H(11), one H(12), and one S(1) atom. The C(10)-H(11) bond length is 1.10 Å. The C(10)-H(12) bond length is 1.10 Å. The C(10)-S(1) bond length is 1.82 Å. In the eighth C site, C(12) is bonded in a distorted water-like geometry to one H(15), one H(16), and one S(2) atom. The C(12)-H(15) bond length is 1.10 Å. The C(12)-H(16) bond length is 1.10 Å. The C(12)-S(2) bond length is 1.82 Å. In the ninth C site, C(13) is bonded in a distorted water-like geometry to one C(14), one H(17), one H(18), and one S(2) atom. The C(13)-C(14) bond length is 1.49 Å. The C(13)-H(17) bond length is 1.10 Å. The C(13)-H(18) bond length is 1.10 Å. The C(13)-S(2) bond length is 1.85 Å. In the tenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(19) bond length is 1.41 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(19) atom. The C(15)-H(19) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(20) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(20) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(21) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(21) bond length is 1.09 Å. In the fourteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(22) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-H(22) bond length is 1.09 Å. In the fifteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one O(1) atom. The C(19)-O(1) bond length is 1.37 Å. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(13) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(15) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(16) atom. In the sixteenth H site, H(21) is bonded in a single-bond geometry to one C(17) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one C(18) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(10), and one C(9) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(12), and one C(13) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(19) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. Br(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 2 c1ccc2c(c1)CSCCCSCc1ccccc1OCCO2. Metal clusters: 1 Br[Cu][Cu]Br. The MOF has largest included sphere 3.54 A, density 1.55 g/cm3, surface area 4405.72 m2/g, accessible volume 0.20 cm3/g