AgC6N2H4S crystallizes in the monoclinic C2/c space group. Ag(1) is bonded in a 2-coordinate geometry to one N(1), one N(2), and two equivalent S(1) atoms. The Ag(1)-N(1) bond length is 2.20 Å. The Ag(1)-N(2) bond length is 2.11 Å. There is one shorter (2.83 Å) and one longer (3.07 Å) Ag(1)-S(1) bond length. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. The C(3)-C(3) bond length is 1.47 Å. The C(3)-C(4) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. The C(6)-N(2) bond length is 1.18 Å. The C(6)-S(1) bond length is 1.63 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a linear geometry to one Ag(1) and one C(6) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. S(1) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one C(6) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.42 A, density 2.49 g/cm3, surface area 3071.31 m2/g, accessible volume 0.06 cm3/g