AgC17N3H10SO4CHCF3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two trifluoromethane molecules, and one AgC17N3H10SO4 cluster. In the AgC17N3H10SO4 cluster, Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one O(2), and one O(3) atom. The Ag(1)-N(1) bond length is 2.15 Å. The Ag(1)-N(2) bond length is 2.32 Å. The Ag(1)-O(2) bond length is 2.50 Å. The Ag(1)-O(3) bond length is 2.75 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(5) atom. The C(1)-C(14) bond length is 1.40 Å. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(5) bond length is 1.47 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(4) bond length is 1.08 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.41 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.48 Å. The C(6)-N(2) bond length is 1.34 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(13), one C(6), and one C(8) atom. The C(7)-C(13) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.40 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(6) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-C(12) bond length is 1.41 Å. In the tenth C site, C(11) is bonded in a distorted linear geometry to one C(10) and one N(1) atom. The C(11)-N(1) bond length is 1.17 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(12)-H(7) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(7) and one H(8) atom. The C(13)-H(8) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(1), one C(15), and one N(3) atom. The C(14)-C(15) bond length is 1.44 Å. The C(14)-N(3) bond length is 1.35 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one O(1) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-O(1) bond length is 1.38 Å. In the fifteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one H(9) atom. The C(16)-C(17) bond length is 1.42 Å. The C(16)-H(9) bond length is 1.09 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(10) atom. The C(17)-H(10) bond length is 1.08 Å. In the seventeenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one H(11) and one O(1) atom. The C(18)-H(11) bond length is 1.08 Å. The C(18)-O(1) bond length is 1.37 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Ag(1) and one C(11) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(6), and one N(3) atom. The N(2)-N(3) bond length is 1.34 Å. In the third N site, N(3) is bonded in a 2-coordinate geometry to one C(14), one N(2), and one H(1) atom. The N(3)-H(1) bond length is 1.02 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(2), one O(3), and one O(4) atom. The S(1)-O(2) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.46 Å. The S(1)-O(4) bond length is 1.46 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(15) and one C(18) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Ag(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. Linkers: 2 [O]S([O])([O])C(F)(F)F ,2 N#Cc1ccc(-c2n[nH]c(-c3cc[c]o3)c3cccc2-3)cc1 ,2 [c]1[c]cc(-c2n[nH]c(-c3ccco3)c3cccc2-3)cc1 ,2 N#Cc1ccc(-c2n[nH]c(-c3ccco3)c3cccc2-3)cc1. Metal clusters: 2 [Ag]. The MOF has largest included sphere 1.91 A, density 1.92 g/cm3, surface area 3768.10 m2/g, accessible volume 0.10 cm3/g