SnC4H8(SBr2)2 is Indium structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two methylsulfanylmethane;tetrabromostannane molecules. Sn(1) is bonded in an octahedral geometry to two equivalent S(1), two equivalent Br(1), and two equivalent Br(2) atoms. Both Sn(1)-S(1) bond lengths are 2.69 Å. Both Sn(1)-Br(1) bond lengths are 2.62 Å. Both Sn(1)-Br(2) bond lengths are 2.60 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one H(1), one H(2), and one S(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.81 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one H(3), one H(4), and one S(1) atom. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. The C(2)-S(1) bond length is 1.81 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. S(1) is bonded in a trigonal non-coplanar geometry to one Sn(1), one C(1), and one C(2) atom. There are two inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one Sn(1) atom. In the second Br site, Br(1) is bonded in a single-bond geometry to one Sn(1) atom. Linkers: 2 C1CSCCS1. Metal clusters: 2 Br[Sn](Br)(Br)Br. The MOF has largest included sphere 1.84 A, density 3.10 g/cm3, surface area 2353.12 m2/g, accessible volume 0.06 cm3/g