CuC14N2H14O5(CH)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CuC14N2H14O5 clusters. In each CuC14N2H14O5 cluster, Cu(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(2), and one O(4) atom. The Cu(1)-N(1) bond length is 2.00 Å. The Cu(1)-N(2) bond length is 1.99 Å. The Cu(1)-O(1) bond length is 1.97 Å. The Cu(1)-O(2) bond length is 2.37 Å. The Cu(1)-O(4) bond length is 1.99 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(3) bond length is 1.26 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(4)-O(4) bond length is 1.29 Å. The C(4)-O(5) bond length is 1.26 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(3) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(4) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(4) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(15), one C(6), and one C(8) atom. The C(7)-C(15) bond length is 1.49 Å. The C(7)-C(8) bond length is 1.40 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(5) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(5) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(1) atom. The C(9)-C(10) bond length is 1.47 Å. The C(9)-N(1) bond length is 1.36 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one N(2) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-N(2) bond length is 1.36 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(6) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(6) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(16) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(16) bond length is 1.50 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(7) atom. The C(13)-H(7) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(14)-N(2) bond length is 1.34 Å. The C(14)-H(8) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one C(7), one H(10), one H(11), and one H(9) atom. The C(15)-H(10) bond length is 1.10 Å. The C(15)-H(11) bond length is 1.10 Å. The C(15)-H(9) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one C(12), one H(12), one H(13), and one H(14) atom. The C(16)-H(12) bond length is 1.10 Å. The C(16)-H(13) bond length is 1.10 Å. The C(16)-H(14) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(5), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(14) atom. There are fourteen inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one O(2) atom. The H(15)-O(2) bond length is 0.99 Å. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one O(2) atom. The H(16)-O(2) bond length is 1.00 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cu(1), one H(15), and one H(16) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cu(1) and one C(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(4) atom. Linkers: 2 [O]C(=O)/C=C/C([O])=O. Metal clusters: 2 O.O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 2.04 A, density 1.63 g/cm3, surface area 4673.59 m2/g, accessible volume 0.15 cm3/g