ZnC9H7(NO2)2(CH)2CH2CH2CO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 02329_fluka molecules, two dimethyl ether molecules, and one ZnC9H7(NO2)2 cluster. In the ZnC9H7(NO2)2 cluster, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(2) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 2.07 Å. The Zn(1)-O(2) bond length is 2.09 Å. The Zn(1)-O(3) bond length is 2.09 Å. The Zn(1)-O(4) bond length is 2.08 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.26 Å. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(7) atom. The C(10)-N(1) bond length is 1.35 Å. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(7) bond length is 1.08 Å. In the seventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(2), and one H(8) atom. The C(11)-C(12) bond length is 1.37 Å. The C(11)-N(2) bond length is 1.38 Å. The C(11)-H(8) bond length is 1.08 Å. In the eighth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(1), and one H(9) atom. The C(12)-N(1) bond length is 1.38 Å. The C(12)-H(9) bond length is 1.08 Å. In the ninth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(10), and one H(11) atom. The C(13)-N(1) bond length is 1.46 Å. The C(13)-H(10) bond length is 1.10 Å. The C(13)-H(11) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(13) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(11) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(8) atom. Linkers: 1 c1cn(CCCCn2ccnc2)cn1 ,2 [O]C(=O)COc1ccc(C([O])=O)cc1. Metal clusters: 1 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 1.86 A, density 1.77 g/cm3, surface area 4429.38 m2/g, accessible volume 0.15 cm3/g