Cd3C26H28S2(NO2)10 crystallizes in the triclinic P-1 space group. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted pentagonal bipyramidal geometry to one N(1), one O(1), one O(2), one O(3), one O(4), one O(5), and one O(7) atom. The Cd(1)-N(1) bond length is 2.31 Å. The Cd(1)-O(1) bond length is 2.41 Å. The Cd(1)-O(2) bond length is 2.38 Å. The Cd(1)-O(3) bond length is 2.66 Å. The Cd(1)-O(4) bond length is 2.30 Å. The Cd(1)-O(5) bond length is 2.60 Å. The Cd(1)-O(7) bond length is 2.36 Å. In the second Cd site, Cd(2) is bonded in an octahedral geometry to two equivalent N(2), two equivalent O(6), and two equivalent O(8) atoms. Both Cd(2)-N(2) bond lengths are 2.44 Å. Both Cd(2)-O(6) bond lengths are 2.35 Å. Both Cd(2)-O(8) bond lengths are 2.28 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.49 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(10) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(10) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(8) bond length is 1.49 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(11) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(11) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one S(1) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-S(1) bond length is 1.78 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(12) atom. The C(6)-H(12) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(3) atom. The C(7)-O(1) bond length is 1.29 Å. The C(7)-O(3) bond length is 1.27 Å. In the eighth C site, C(8) is bonded in a bent 120 degrees geometry to one C(3), one O(5), and one O(7) atom. The C(8)-O(5) bond length is 1.26 Å. The C(8)-O(7) bond length is 1.29 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(13) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-N(2) bond length is 1.34 Å. The C(9)-H(13) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one N(5) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-N(2) bond length is 1.37 Å. The C(10)-N(5) bond length is 1.33 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(13), and one N(3) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-N(3) bond length is 1.39 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(14) atom. The C(12)-N(3) bond length is 1.33 Å. The C(12)-N(4) bond length is 1.37 Å. The C(12)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one N(4) atom. The C(13)-N(1) bond length is 1.35 Å. The C(13)-N(4) bond length is 1.37 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(9) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(10), and one C(9) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(11), one C(12), and one H(4) atom. The N(3)-H(4) bond length is 1.75 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(12), one C(13), and one H(7) atom. The N(4)-H(7) bond length is 1.03 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(10), one H(8), and one H(9) atom. The N(5)-H(8) bond length is 1.03 Å. The N(5)-H(9) bond length is 1.02 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) and one O(7) atom. The H(2)-O(2) bond length is 1.00 Å. The H(2)-O(7) bond length is 1.71 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. The H(3)-O(4) bond length is 0.98 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) and one O(4) atom. The H(4)-O(4) bond length is 1.01 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(6) atom. The H(5)-O(6) bond length is 0.99 Å. In the sixth H site, H(6) is bonded in a distorted linear geometry to one O(10) and one O(6) atom. The H(6)-O(10) bond length is 1.59 Å. The H(6)-O(6) bond length is 1.01 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(2) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(4) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one O(10), one O(8), and one O(9) atom. The S(1)-O(10) bond length is 1.47 Å. The S(1)-O(8) bond length is 1.48 Å. The S(1)-O(9) bond length is 1.46 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1), one H(1), and one H(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cd(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Cd(1), one H(3), and one H(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Cd(1) and one C(8) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Cd(2), one H(5), and one H(6) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cd(1), one C(8), and one H(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Cd(2) and one S(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one H(6) and one S(1) atom. Linkers: 2 [O]C(=O)c1cc(C([O])=O)cc(S([O])([O])[O])c1 ,2 Nc1ncnc2[nH]cnc12. Metal clusters: 2 O.O.O=[C]O[Cd]O[C]=O ,1 O.O.[O][S@@](=O)O[Cd]O[S@@]([O])=O. The MOF has largest included sphere 2.01 A, density 2.21 g/cm3, surface area 3098.06 m2/g, accessible volume 0.08 cm3/g