AgC9N3H7SO4(CH)2CF3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four trifluoromethane molecules, and four AgC9N3H7SO4 clusters. In each AgC9N3H7SO4 cluster, Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one N(3), and one O(2) atom. The Ag(1)-N(1) bond length is 2.13 Å. The Ag(1)-N(2) bond length is 2.17 Å. The Ag(1)-N(3) bond length is 2.63 Å. The Ag(1)-O(2) bond length is 2.76 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2,3) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2,3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.49 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(2,3) atom. The C(4)-H(2,3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one N(3) atom. The C(6)-C(7) bond length is 1.47 Å. The C(6)-N(3) bond length is 1.30 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(2) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(2) bond length is 1.36 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one N(2) and one H(8) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(8) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(11), and one C(7) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one C(6), and one O(1) atom. The N(3)-O(1) bond length is 1.38 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one O(1) atom. The H(9)-O(1) bond length is 1.00 Å. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(2), one O(3), and one O(4) atom. The S(1)-O(2) bond length is 1.46 Å. The S(1)-O(3) bond length is 1.45 Å. The S(1)-O(4) bond length is 1.48 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one N(3) and one H(9) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Ag(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one S(1) atom. Linkers: 3 O/N=C(\c1ccncc1)c1ccccn1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 2.53 A, density 1.95 g/cm3, surface area 3784.70 m2/g, accessible volume 0.14 cm3/g