CdC16H20(N4Cl)2(CH2)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two CdC16H20(N4Cl)2 clusters. In each CdC16H20(N4Cl)2 cluster, Cd(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(4), and two equivalent Cl(1) atoms. Both Cd(1)-N(1) bond lengths are 2.33 Å. Both Cd(1)-N(4) bond lengths are 2.39 Å. Both Cd(1)-Cl(1) bond lengths are 2.71 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(4) atom. The C(3)-C(10) bond length is 1.38 Å. The C(3)-N(2) bond length is 1.38 Å. The C(3)-H(4) bond length is 1.08 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(5) atom. The C(4)-N(3) bond length is 1.36 Å. The C(4)-N(4) bond length is 1.33 Å. The C(4)-H(5) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(8), and one H(9) atom. The C(6)-N(3) bond length is 1.46 Å. The C(6)-H(8) bond length is 1.10 Å. The C(6)-H(9) bond length is 1.10 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(3), and one H(10) atom. The C(7)-C(8) bond length is 1.38 Å. The C(7)-N(3) bond length is 1.38 Å. The C(7)-H(10) bond length is 1.08 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(4), and one H(11) atom. The C(8)-N(4) bond length is 1.38 Å. The C(8)-H(11) bond length is 1.08 Å. In the seventh C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(12), and one H(13) atom. The C(9)-N(2) bond length is 1.46 Å. The C(9)-H(12) bond length is 1.10 Å. The C(9)-H(13) bond length is 1.10 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(14) atom. The C(10)-N(1) bond length is 1.38 Å. The C(10)-H(14) bond length is 1.08 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(10) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(4), and one C(8) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. Cl(1) is bonded in a single-bond geometry to one Cd(1) atom. Linkers: 4 c1cn(CCCCn2ccnc2)cn1 ,2 [c]1cn(CCCCn2ccnc2)cn1. Metal clusters: 2 Cl[Cd]Cl. The MOF has largest included sphere 2.07 A, density 1.64 g/cm3, surface area 4879.39 m2/g, accessible volume 0.16 cm3/g