ZnC10NH6O4(CH)10(C3H2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 2,3-dimethyl-1,3-butadiene molecules; four CH clusters; and four ZnC10NH6O4 clusters. In each CH cluster, there are ten inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.46 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one H(5) atom. The C(6)-C(7) bond length is 1.35 Å. The C(6)-H(5) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(6) atom. The C(7)-C(8) bond length is 1.48 Å. The C(7)-H(6) bond length is 1.10 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.41 Å. The C(8)-C(9) bond length is 1.42 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(8) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(11) bond length is 1.51 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(12), one C(8), and one C(9) atom. The C(10)-C(12) bond length is 1.51 Å. In the ninth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(7), one H(8), and one H(9) atom. The C(11)-H(7) bond length is 1.09 Å. The C(11)-H(8) bond length is 1.10 Å. The C(11)-H(9) bond length is 1.10 Å. In the tenth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one H(10), one H(11), and one H(12) atom. The C(12)-H(10) bond length is 1.09 Å. The C(12)-H(11) bond length is 1.10 Å. The C(12)-H(12) bond length is 1.10 Å. There are ten inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In each ZnC10NH6O4 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 2.08 Å. The Zn(1)-O(2) bond length is 2.05 Å. The Zn(1)-O(3) bond length is 2.07 Å. The Zn(1)-O(4) bond length is 2.06 Å. There are ten inequivalent C sites. In the first C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(19) atom. The C(23)-C(22) bond length is 1.40 Å. The C(23)-H(19) bond length is 1.09 Å. In the second C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(1), and one O(2) atom. The C(25)-C(13) bond length is 1.50 Å. The C(25)-O(1) bond length is 1.27 Å. The C(25)-O(2) bond length is 1.27 Å. In the third C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(3), and one O(4) atom. The C(26)-C(22) bond length is 1.50 Å. The C(26)-O(3) bond length is 1.28 Å. The C(26)-O(4) bond length is 1.28 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(25) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(18) bond length is 1.40 Å. In the seventh C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(13) atom. The C(14)-H(13) bond length is 1.09 Å. In the eighth C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(18) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-H(18) bond length is 1.09 Å. In the ninth C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(16) atom. The C(18)-H(16) bond length is 1.09 Å. In the tenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(26) atom. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(26) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(26) atom. Linkers: 2 Cc1c(C)c(/C=C/c2ccncc2)c(C)c(C)c1/C=C/c1ccncc1 ,4 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 5.23 A, density 1.21 g/cm3, surface area 5048.07 m2/g, accessible volume 0.30 cm3/g