ZnC9H12(NO3)2CH2 crystallizes in the tetragonal P4_3 space group. The structure consists of four 02329_fluka molecules inside a ZnC9H12(NO3)2 framework. In the ZnC9H12(NO3)2 framework, Zn(1) is bonded in an octahedral geometry to one N(1), one N(2), one O(1), one O(3), one O(5), and one O(6) atom. The Zn(1)-N(1) bond length is 2.16 Å. The Zn(1)-N(2) bond length is 2.07 Å. The Zn(1)-O(1) bond length is 2.17 Å. The Zn(1)-O(3) bond length is 2.16 Å. The Zn(1)-O(5) bond length is 2.29 Å. The Zn(1)-O(6) bond length is 2.12 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a 2-coordinate geometry to one N(1) and one H(6) atom. The C(2)-N(1) bond length is 1.47 Å. The C(2)-H(6) bond length is 1.10 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(4)-O(3) bond length is 1.28 Å. The C(4)-O(4) bond length is 1.27 Å. In the fourth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one C(8), one N(1), one H(10), and one H(9) atom. The C(5)-C(8) bond length is 1.51 Å. The C(5)-N(1) bond length is 1.47 Å. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(11) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-H(11) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(12) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(12) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.40 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(13) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(13) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(14) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(14) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Zn(1), one C(2), one C(5), and one H(5) atom. The N(1)-H(5) bond length is 1.03 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(6) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. The H(1)-O(5) bond length is 0.97 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(5) atom. The H(2)-O(5) bond length is 1.00 Å. In the third H site, H(3) is bonded in a distorted linear geometry to one O(4) and one O(6) atom. The H(3)-O(4) bond length is 1.58 Å. The H(3)-O(6) bond length is 1.02 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(6) atom. The H(4)-O(6) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(7) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one H(3), and one H(4) atom. In the second O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the fourth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one C(4) and one H(3) atom. In the sixth O site, O(5) is bonded in a distorted water-like geometry to one Zn(1), one H(1), and one H(2) atom. Linkers: 4 [O]C(=O)C[C@H](NCc1ccncc1)C([O])=O. Metal clusters: 4 [Zn]. The MOF has largest included sphere 2.55 A, density 1.68 g/cm3, surface area 4098.63 m2/g, accessible volume 0.13 cm3/g