MnCu2C44H40(NO2)4(CH2)2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two MnCu2C44H40(NO2)4 clusters. In each MnCu2C44H40(NO2)4 cluster, Mn(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form MnO6 octahedra that share  an edgeedge with one Cu(1)N2O3 square pyramid and  an edgeedge with one Cu(2)N2O3 square pyramid. The Mn(1)-O(1) bond length is 2.10 Å. The Mn(1)-O(2) bond length is 2.10 Å. Both Mn(1)-O(3) bond lengths are 2.22 Å. Both Mn(1)-O(4) bond lengths are 2.22 Å. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to two equivalent N(1), one O(5), and two equivalent O(3) atoms to form CuN2O3 square pyramids that share  an edgeedge with one Mn(1)O6 octahedra. Both Cu(1)-N(1) bond lengths are 1.98 Å. The Cu(1)-O(5) bond length is 2.21 Å. Both Cu(1)-O(3) bond lengths are 2.01 Å. In the second Cu site, Cu(2) is bonded to two equivalent N(2), one O(6), and two equivalent O(4) atoms to form CuN2O3 square pyramids that share  an edgeedge with one Mn(1)O6 octahedra. Both Cu(2)-N(2) bond lengths are 1.98 Å. The Cu(2)-O(6) bond length is 2.21 Å. Both Cu(2)-O(4) bond lengths are 2.01 Å. There are twenty-one inequivalent C sites. In the first C site, C(23) is bonded in a distorted trigonal non-coplanar geometry to one C(13); one H(17); one H(19,20); and one H(21) atom. The C(23)-C(13) bond length is 1.50 Å. The C(23)-H(17) bond length is 1.10 Å. The C(23)-H(19,20) bond length is 1.09 Å. The C(23)-H(21) bond length is 1.09 Å. In the second C site, C(24) is bonded in a distorted trigonal non-coplanar geometry to one C(14); one H(18); one H(19,20); and one H(22) atom. The C(24)-C(14) bond length is 1.50 Å. The C(24)-H(18) bond length is 1.10 Å. The C(24)-H(19,20) bond length is 1.09 Å. The C(24)-H(22) bond length is 1.09 Å. In the third C site, C(25,26) is bonded in a distorted trigonal planar geometry to one C(17,18); one C(27,28); and one H(23,24) atom. The C(25,26)-C(17,18) bond length is 1.39 Å. The C(25,26)-C(27,28) bond length is 1.40 Å. The C(25,26)-H(23,24) bond length is 1.09 Å. In the fourth C site, C(27,28) is bonded in a distorted trigonal planar geometry to one C(19,20); one C(25,26); and one H(25,26) atom. The C(27,28)-C(19,20) bond length is 1.38 Å. The C(27,28)-H(25,26) bond length is 1.09 Å. In the fifth C site, C(1) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(7) atom. The C(1)-C(4) bond length is 1.40 Å. The C(1)-C(5) bond length is 1.50 Å. The C(1)-C(7) bond length is 1.40 Å. In the sixth C site, C(2) is bonded in a trigonal planar geometry to one C(3), one C(6), and one C(8) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.50 Å. The C(2)-C(8) bond length is 1.40 Å. In the seventh C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1,2) atom. The C(3)-H(1,2) bond length is 1.09 Å. In the eighth C site, C(4) is bonded in a distorted single-bond geometry to one C(1) and one H(1,2) atom. The C(4)-H(1,2) bond length is 1.09 Å. In the ninth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(5) atom. The C(5)-O(1) bond length is 1.28 Å. The C(5)-O(5) bond length is 1.27 Å. In the tenth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(6) atom. The C(6)-O(2) bond length is 1.28 Å. The C(6)-O(6) bond length is 1.27 Å. In the eleventh C site, C(7) is bonded in a distorted single-bond geometry to one C(1) and one H(3,4) atom. The C(7)-H(3,4) bond length is 1.09 Å. In the twelfth C site, C(8) is bonded in a distorted single-bond geometry to one C(2) and one H(3,4) atom. The C(8)-H(3,4) bond length is 1.09 Å. In the thirteenth C site, C(9) is bonded in a distorted single-bond geometry to one C(11) and one O(3) atom. The C(9)-C(11) bond length is 1.43 Å. The C(9)-O(3) bond length is 1.33 Å. In the fourteenth C site, C(10) is bonded in a distorted single-bond geometry to one C(12) and one O(4) atom. The C(10)-C(12) bond length is 1.43 Å. The C(10)-O(4) bond length is 1.33 Å. In the fifteenth C site, C(11) is bonded in a trigonal planar geometry to one C(13); one C(19,20); and one C(9) atom. The C(11)-C(13) bond length is 1.46 Å. The C(11)-C(19,20) bond length is 1.42 Å. In the sixteenth C site, C(12) is bonded in a trigonal planar geometry to one C(10); one C(14); and one C(19,20) atom. The C(12)-C(14) bond length is 1.46 Å. The C(12)-C(19,20) bond length is 1.42 Å. In the seventeenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(11), one C(23), and one N(1) atom. The C(13)-N(1) bond length is 1.31 Å. In the eighteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(12), one C(24), and one N(2) atom. The C(14)-N(2) bond length is 1.31 Å. In the nineteenth C site, C(15,16) is bonded in a 3-coordinate geometry to one N(1), one H(5), and one H(7) atom. The C(15,16)-N(1) bond length is 1.47 Å. The C(15,16)-H(5) bond length is 1.10 Å. The C(15,16)-H(7) bond length is 1.10 Å. In the twentieth C site, C(17,18) is bonded in a distorted single-bond geometry to one C(25,26) and one H(9,10) atom. The C(17,18)-H(9,10) bond length is 1.09 Å. In the twenty-first C site, C(19,20) is bonded in a distorted single-bond geometry to one C(11); one C(27,28); and one H(11,12) atom. The C(19,20)-H(11,12) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1); one C(13); and one C(15,16) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2); one C(14); and one C(15,16) atom. The N(2)-C(15,16) bond length is 1.47 Å. There are fifteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(15,16) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(15,16) atom. The H(6)-C(15,16) bond length is 1.10 Å. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(15,16) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(15,16) atom. The H(8)-C(15,16) bond length is 1.11 Å. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(17,18) atom. In the eighth H site, H(11,12) is bonded in a single-bond geometry to one C(19,20) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(19,20) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(23,24) is bonded in a single-bond geometry to one C(25,26) atom. In the fifteenth H site, H(25,26) is bonded in a single-bond geometry to one C(27,28) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(5) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(6) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one Cu(1), and one C(9) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mn(1), one Cu(2), and one C(10) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(5) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(6) atom. Linkers: 1 [O]C(=O)c1ccc(C([O])=O)cc1 ,2 C/C(=N\CCC/N=C(\C)c1ccccc1[O])c1ccccc1[O]. Metal clusters: 1 [C]1O[Cu]2O[Mn]34(O1)(O[C]O[Cu](O3)O4)O2. The MOF has largest included sphere 5.44 A, density 1.36 g/cm3, surface area 4229.02 m2/g, accessible volume 0.25 cm3/g