AgC7N3H9O2AgC13H18(N3O)2CHCH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two 02329_fluka molecules, two AgC13H18(N3O)2 clusters, and one AgC7N3H9O2 cluster. In each AgC13H18(N3O)2 cluster, Ag(2) is bonded in a 3-coordinate geometry to one N(4), one N(7), and one O(4) atom. The Ag(2)-N(4) bond length is 2.16 Å. The Ag(2)-N(7) bond length is 2.18 Å. The Ag(2)-O(4) bond length is 2.45 Å. There are thirteen inequivalent C sites. In the first C site, C(7) is bonded in a trigonal planar geometry to one N(7), one N(8), and one N(9) atom. The C(7)-N(7) bond length is 1.36 Å. The C(7)-N(8) bond length is 1.35 Å. The C(7)-N(9) bond length is 1.35 Å. In the second C site, C(8) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one N(7) atom. The C(8)-C(11) bond length is 1.49 Å. The C(8)-C(9) bond length is 1.39 Å. The C(8)-N(7) bond length is 1.35 Å. In the third C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(8) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(12), one C(9), and one N(9) atom. The C(10)-C(12) bond length is 1.49 Å. The C(10)-N(9) bond length is 1.34 Å. In the fifth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one C(8), one H(10), one H(11), and one H(9) atom. The C(11)-H(10) bond length is 1.10 Å. The C(11)-H(11) bond length is 1.09 Å. The C(11)-H(9) bond length is 1.10 Å. In the sixth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one H(12), one H(13), and one H(14) atom. The C(12)-H(12) bond length is 1.10 Å. The C(12)-H(13) bond length is 1.10 Å. The C(12)-H(14) bond length is 1.10 Å. In the seventh C site, C(13) is bonded in a trigonal planar geometry to one N(4), one N(5), and one N(6) atom. The C(13)-N(4) bond length is 1.37 Å. The C(13)-N(5) bond length is 1.34 Å. The C(13)-N(6) bond length is 1.36 Å. In the eighth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(15), one C(18), and one N(6) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(18) bond length is 1.50 Å. The C(14)-N(6) bond length is 1.34 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(15) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(15) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one N(4) atom. The C(16)-C(17) bond length is 1.50 Å. The C(16)-N(4) bond length is 1.35 Å. In the eleventh C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one C(16), one H(16), one H(17), and one H(18) atom. The C(17)-H(16) bond length is 1.10 Å. The C(17)-H(17) bond length is 1.10 Å. The C(17)-H(18) bond length is 1.10 Å. In the twelfth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one C(14), one H(19), one H(20), and one H(21) atom. The C(18)-H(19) bond length is 1.09 Å. The C(18)-H(20) bond length is 1.10 Å. The C(18)-H(21) bond length is 1.10 Å. In the thirteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(22)-O(3) bond length is 1.28 Å. The C(22)-O(4) bond length is 1.27 Å. There are six inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Ag(2), one C(13), and one C(16) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one C(13), one H(27), and one H(28) atom. The N(5)-H(27) bond length is 1.04 Å. The N(5)-H(28) bond length is 1.04 Å. In the third N site, N(6) is bonded in a bent 120 degrees geometry to one C(13) and one C(14) atom. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one Ag(2), one C(7), and one C(8) atom. In the fifth N site, N(8) is bonded in a distorted trigonal planar geometry to one C(7), one H(29), and one H(30) atom. The N(8)-H(29) bond length is 1.02 Å. The N(8)-H(30) bond length is 1.04 Å. In the sixth N site, N(9) is bonded in a bent 120 degrees geometry to one C(10) and one C(7) atom. There are eighteen inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(27) is bonded in a single-bond geometry to one N(5) atom. In the sixteenth H site, H(28) is bonded in a single-bond geometry to one N(5) atom. In the seventeenth H site, H(29) is bonded in a single-bond geometry to one N(8) atom. In the eighteenth H site, H(30) is bonded in a single-bond geometry to one N(8) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(22) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Ag(2) and one C(22) atom. In the AgC7N3H9O2 cluster, Ag(1) is bonded in a 3-coordinate geometry to one N(1) and two equivalent O(1) atoms. The Ag(1)-N(1) bond length is 2.17 Å. There is one shorter (2.29 Å) and one longer (2.32 Å) Ag(1)-O(1) bond length. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-N(3) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(6), and one N(3) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.49 Å. The C(2)-N(3) bond length is 1.34 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.49 Å. The C(4)-N(1) bond length is 1.35 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one H(2), one H(3), and one H(4) atom. The C(5)-H(2) bond length is 1.10 Å. The C(5)-H(3) bond length is 1.09 Å. The C(5)-H(4) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one H(5), one H(6), and one H(7) atom. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. The C(6)-H(7) bond length is 1.10 Å. In the seventh C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(19)-O(1) bond length is 1.29 Å. The C(19)-O(2) bond length is 1.26 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one H(25), and one H(26) atom. The N(2)-H(25) bond length is 1.03 Å. The N(2)-H(26) bond length is 1.04 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(25) is bonded in a single-bond geometry to one N(2) atom. In the ninth H site, H(26) is bonded in a single-bond geometry to one N(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one C(19) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one C(19) atom. Linkers: 1 [O]C(=O)C[C@H](C([O])=O)[C@@H](CC([O])=O)C([O])=O. Metal clusters: 4 [Ag]. The MOF has largest included sphere 2.61 A, density 1.84 g/cm3, surface area 4014.55 m2/g, accessible volume 0.12 cm3/g