CdC8N2H8O5(CH)8(CH2CO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, four dimethyl ether molecules, and two CdC8N2H8O5 clusters. In each CdC8N2H8O5 cluster, Cd(1) is bonded in a pentagonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(2), one O(3), one O(4), and one O(7) atom. The Cd(1)-N(1) bond length is 2.33 Å. The Cd(1)-N(2) bond length is 2.33 Å. The Cd(1)-O(1) bond length is 2.55 Å. The Cd(1)-O(2) bond length is 2.55 Å. The Cd(1)-O(3) bond length is 2.48 Å. The Cd(1)-O(4) bond length is 2.48 Å. The Cd(1)-O(7) bond length is 2.32 Å. There are seven inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1,2)-O(1) bond length is 1.27 Å. The C(1,2)-O(3) bond length is 1.27 Å. In the second C site, C(11) is bonded in a distorted trigonal planar geometry to one N(1) and one H(11) atom. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(11) bond length is 1.09 Å. In the third C site, C(12) is bonded in a distorted trigonal planar geometry to one N(2) and one H(12) atom. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(12) bond length is 1.09 Å. In the fourth C site, C(17) is bonded in a distorted single-bond geometry to one C(19) and one H(17,18) atom. The C(17)-C(19) bond length is 1.39 Å. The C(17)-H(17,18) bond length is 1.09 Å. In the fifth C site, C(18) is bonded in a distorted single-bond geometry to one C(20) and one H(17,18) atom. The C(18)-C(20) bond length is 1.39 Å. The C(18)-H(17,18) bond length is 1.09 Å. In the sixth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(17), one N(1), and one H(19) atom. The C(19)-N(1) bond length is 1.35 Å. The C(19)-H(19) bond length is 1.09 Å. In the seventh C site, C(20) is bonded in a distorted trigonal planar geometry to one C(18), one N(2), and one H(20) atom. The C(20)-N(2) bond length is 1.35 Å. The C(20)-H(20) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(19) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(12), and one C(20) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. The H(1)-O(7) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. The H(2)-O(7) bond length is 0.99 Å. In the third H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(17,18) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(20) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1,2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1,2) atom. The O(2)-C(1,2) bond length is 1.27 Å. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1,2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1,2) atom. The O(4)-C(1,2) bond length is 1.27 Å. In the fifth O site, O(7) is bonded in a distorted water-like geometry to one Cd(1), one H(1), and one H(2) atom. Linkers: 2 [O]C(=O)COc1ccc(OCC([O])=O)cc1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 1.53 A, density 1.77 g/cm3, surface area 4557.74 m2/g, accessible volume 0.09 cm3/g