(CH2)4CuC28N4H24(OCl)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two CuC28N4H24(OCl)2 clusters. In each CuC28N4H24(OCl)2 cluster, Cu(1) is bonded in a distorted trigonal pyramidal geometry to two equivalent N(1) and two equivalent Cl(1) atoms. Both Cu(1)-N(1) bond lengths are 2.02 Å. Both Cu(1)-Cl(1) bond lengths are 2.23 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(1), and one H(1) atom. The C(1)-C(5) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.51 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one N(2), one H(5), and one H(6) atom. The C(6)-N(2) bond length is 1.46 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted water-like geometry to one N(2) and one H(7) atom. The C(7)-N(2) bond length is 1.48 Å. The C(7)-H(7) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(2), and one O(1) atom. The C(10)-C(11) bond length is 1.50 Å. The C(10)-N(2) bond length is 1.37 Å. The C(10)-O(1) bond length is 1.25 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(16) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(16) bond length is 1.40 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(12) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(12) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(13) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-H(13) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(14) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(15) atom. The C(15)-H(15) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(11) and one H(16) atom. The C(16)-H(16) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(6), and one C(7) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. O(1) is bonded in a single-bond geometry to one C(10) atom. Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 1 O=C(c1ccccc1)N(Cc1cccnc1)[C@@H]1CCCC[C@H]1N(Cc1cccnc1)C(=O)c1ccccc1. Metal clusters: 1 Cl[Cu]Cl. The MOF has largest included sphere 2.58 A, density 1.50 g/cm3, surface area 4797.30 m2/g, accessible volume 0.13 cm3/g