CdC24H10(NO4)2(CH)2 crystallizes in the monoclinic C2/c space group. The structure consists of eight 02329_fluka molecules inside a CdC24H10(NO4)2 framework. In the CdC24H10(NO4)2 framework, Cd(1) is bonded in a distorted pentagonal pyramidal geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. Both Cd(1)-N(1) bond lengths are 2.39 Å. Both Cd(1)-O(1) bond lengths are 2.24 Å. Both Cd(1)-O(2) bond lengths are 2.39 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one O(3) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-O(3) bond length is 1.38 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(6) atom. The C(5)-C(5) bond length is 1.42 Å. The C(5)-C(6) bond length is 1.41 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-C(8) bond length is 1.47 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(2) atom. The C(7)-H(2) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.40 Å. The C(8)-O(4) bond length is 1.22 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(3) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-N(1) bond length is 1.34 Å. The C(9)-H(3) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(10)-H(4) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(6) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(6) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(13), and one N(1) atom. The C(13)-C(13) bond length is 1.49 Å. The C(13)-N(1) bond length is 1.35 Å. N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(9) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(4) and one C(8) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(8) atom. Linkers: 2 c1ccc(-c2ccccn2)nc1 ,2 [O]C(=O)c1cc2oc(=O)c3cc(C([O])=O)cc4oc(=O)c(c1)c2c43. Metal clusters: 2 [Cd]. RCSR code: pts. The MOF has largest included sphere 3.28 A, density 1.77 g/cm3, surface area 3984.34 m2/g, accessible volume 0.15 cm3/g