ZnC26H18(NO)4(C6H4)2NH is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four schembl11168711 molecules and four ZnC26H18(NO)4 clusters. In each ZnC26H18(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one O(1), and one O(4) atom. The Zn(1)-N(1) bond length is 2.00 Å. The Zn(1)-N(3) bond length is 2.06 Å. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(4) bond length is 1.98 Å. There are twenty-six inequivalent C sites. In the first C site, C(37) is bonded in a trigonal planar geometry to one N(1), one N(5), and one H(26) atom. The C(37)-N(1) bond length is 1.33 Å. The C(37)-N(5) bond length is 1.36 Å. The C(37)-H(26) bond length is 1.08 Å. In the second C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(5), and one H(27) atom. The C(38)-C(1) bond length is 1.37 Å. The C(38)-N(5) bond length is 1.39 Å. The C(38)-H(27) bond length is 1.08 Å. In the third C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(8) bond length is 1.09 Å. In the fourth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(14) bond length is 1.50 Å. In the fifth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(9) atom. The C(12)-H(9) bond length is 1.09 Å. In the sixth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.25 Å. The C(14)-O(4) bond length is 1.31 Å. In the seventh C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(12) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(12) bond length is 1.09 Å. In the eighth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(21) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(21) bond length is 1.50 Å. In the ninth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(13) atom. The C(19)-H(13) bond length is 1.09 Å. In the tenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(1), and one O(2) atom. The C(21)-O(1) bond length is 1.30 Å. The C(21)-O(2) bond length is 1.25 Å. In the eleventh C site, C(22) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(15) atom. The C(22)-N(3) bond length is 1.33 Å. The C(22)-N(4) bond length is 1.36 Å. The C(22)-H(15) bond length is 1.08 Å. In the twelfth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(24), one N(4), and one H(16) atom. The C(23)-C(24) bond length is 1.37 Å. The C(23)-N(4) bond length is 1.39 Å. The C(23)-H(16) bond length is 1.08 Å. In the thirteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(23), one N(3), and one H(17) atom. The C(24)-N(3) bond length is 1.38 Å. The C(24)-H(17) bond length is 1.09 Å. In the fourteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one C(30), and one N(4) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(30) bond length is 1.40 Å. The C(25)-N(4) bond length is 1.42 Å. In the fifteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(18) atom. The C(26)-H(18) bond length is 1.09 Å. In the sixteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(28) and one H(19) atom. The C(27)-C(28) bond length is 1.41 Å. The C(27)-H(19) bond length is 1.09 Å. In the seventeenth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(31) atom. The C(28)-C(29) bond length is 1.41 Å. The C(28)-C(31) bond length is 1.47 Å. In the eighteenth C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(20) atom. The C(29)-H(20) bond length is 1.09 Å. In the nineteenth C site, C(30) is bonded in a distorted single-bond geometry to one C(25) and one H(21) atom. The C(30)-H(21) bond length is 1.09 Å. In the twentieth C site, C(31) is bonded in a trigonal planar geometry to one C(28), one C(32), and one C(36) atom. The C(31)-C(32) bond length is 1.41 Å. The C(31)-C(36) bond length is 1.41 Å. In the twenty-first C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31), one C(33), and one H(22) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-H(22) bond length is 1.09 Å. In the twenty-second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(38), one N(1), and one H(1) atom. The C(1)-N(1) bond length is 1.38 Å. The C(1)-H(1) bond length is 1.08 Å. In the twenty-third C site, C(33) is bonded in a distorted single-bond geometry to one C(32), one C(34), and one H(23) atom. The C(33)-C(34) bond length is 1.40 Å. The C(33)-H(23) bond length is 1.09 Å. In the twenty-fourth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(33), one C(35), and one N(5) atom. The C(34)-C(35) bond length is 1.40 Å. The C(34)-N(5) bond length is 1.42 Å. In the twenty-fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(34) and one H(24) atom. The C(35)-H(24) bond length is 1.09 Å. In the twenty-sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(31) and one H(25) atom. The C(36)-H(25) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(37) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(22), and one C(24) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one C(22), one C(23), and one C(25) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one C(34), one C(37), and one C(38) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(30) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(32) atom. In the fourteenth H site, H(23) is bonded in a single-bond geometry to one C(33) atom. In the fifteenth H site, H(24) is bonded in a single-bond geometry to one C(35) atom. In the sixteenth H site, H(25) is bonded in a single-bond geometry to one C(36) atom. In the seventeenth H site, H(26) is bonded in a single-bond geometry to one C(37) atom. In the eighteenth H site, H(27) is bonded in a single-bond geometry to one C(38) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(21) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(21) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(14) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zn(1) and one C(14) atom. Linkers: 2 c1cn(-c2ccc(-c3ccc(-n4ccnc4)cc3)cc2)cn1 ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]/C=C\C=[C]\[N][C]/C=C\[C]=[CH].[CH]=[C]N=[CH].[CH]=[N].[CH]=[N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]=O.[C]=O.[C][CH].[C][C]/[C]=[C]\[C]N=[CH].[C][C]C([O])=O.[C][N].[C][N].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][Zn].[Zn] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[CH].[CH]=[C]C([O])=O.[CH]=[N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/C=C\C=[CH].[C]=O.[C]=O.[C]=O.[C]C=[CH].[C][CH].[C][N].[C][N].[C][N][C].[C]c1cc[c]cc1.[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O][Zn].[Zn] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/C=C\[CH].[C]/C=[C]\C(=[CH])[N].[C]/C=[C]\C=[CH].[C]=C[N][CH].[C]=O.[C]=O.[C]=O.[C]=O.[C][CH][C].[C][C]C(=O)O[Zn]OC([C])=O.[C][C][N].[C][C][N][C].[C][N].[C][N].[C][N].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[Zn].[Zn] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=C[C][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/C=C\[C].[C]/C=[C]/C(=O)O[Zn].[C]=C[N].[C]=O.[C]=O.[C]=O.[C]=O.[C]C=[CH].[C][CH].[C][CH][C].[C][CH][C].[C][C]=[CH].[C][C]=[CH].[C][C][C][O].[C][N].[C][N].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[Zn].[Zn] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C]C([O])=O.[CH]=[N].[CH][C]=[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/C=[C]/N([C])[C]=[CH].[C]=O.[C]=O.[C]=O.[C]C=[CH].[C][CH].[C][C].[C][N].[C][N].[C][N][C].[C]c1cc[c]cc1.[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O][Zn].[Zn] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/[C]=C(\[CH][C])N=[CH].[C]=O.[C]=O.[C]=O.[C]=O.[C][CH].[C][CH].[C][CH]/C=C\[CH].[C][C].[C][N].[C][N].[C][N].[C]c1ccc([N])cc1.[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O][Zn].[O][Zn]O[C]=O. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.28 A, density 1.16 g/cm3, surface area 5201.59 m2/g, accessible volume 0.34 cm3/g