ZnC16N2H12O5(CH)3C2O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two dimethyl ether molecules, and one ZnC16N2H12O5 cluster. In the ZnC16N2H12O5 cluster, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(2), one O(3), one O(4), and one O(6) atom. The Zn(1)-N(1) bond length is 2.15 Å. The Zn(1)-N(2) bond length is 2.08 Å. The Zn(1)-O(3) bond length is 1.99 Å. The Zn(1)-O(4) bond length is 1.98 Å. The Zn(1)-O(6) bond length is 2.17 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(3) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(3) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(4) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(4) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(5) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(5) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(6) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(6) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(2) atom. The C(5)-C(6) bond length is 1.48 Å. The C(5)-N(2) bond length is 1.35 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(1) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-N(1) bond length is 1.35 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(7) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(7) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(8) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(8) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(9) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(9) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(10) atom. The C(10)-N(1) bond length is 1.34 Å. The C(10)-H(10) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(4), and one O(5) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-O(4) bond length is 1.29 Å. The C(11)-O(5) bond length is 1.27 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-C(17) bond length is 1.40 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(18) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(18) bond length is 1.51 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(14)-H(11) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(12) and one H(13) atom. The C(17)-H(13) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(2), and one O(3) atom. The C(18)-O(2) bond length is 1.26 Å. The C(18)-O(3) bond length is 1.29 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(6) atom. The H(1)-O(6) bond length is 1.00 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(5) and one O(6) atom. The H(2)-O(5) bond length is 1.63 Å. The H(2)-O(6) bond length is 1.02 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. There are five inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one C(18) atom. In the second O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(18) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(11) atom. In the fourth O site, O(5) is bonded in a water-like geometry to one C(11) and one H(2) atom. In the fifth O site, O(6) is bonded in a distorted water-like geometry to one Zn(1), one H(1), and one H(2) atom. Linkers: 2 [O]C(=O)[C]/C=[C]/Oc1ccc(Oc2ccc(C([O])=O)c(C([O])=O)c2)cc1 ,1 [O]C(=O)c1ccc(Oc2ccc(Oc3ccc(C([O])=O)c(C([O])=O)c3)cc2)cc1C([O])=O ,2 c1ccc(-c2ccccn2)nc1. Metal clusters: 2 O.O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.99 A, density 1.59 g/cm3, surface area 4236.38 m2/g, accessible volume 0.16 cm3/g