ZnC16NH10O5C9H6N is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C9H6N clusters and four ZnC16NH10O5 clusters. In each C9H6N cluster, there are nine inequivalent C sites. In the first C site, C(7) is bonded in a distorted trigonal planar geometry to one C(11), one C(8), and one H(6) atom. The C(7)-C(11) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(6) bond length is 1.09 Å. In the second C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(2) atom. The C(8)-C(9) bond length is 1.43 Å. The C(8)-N(2) bond length is 1.40 Å. In the third C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(8), and one C(9) atom. The C(9)-C(10) bond length is 1.42 Å. The C(9)-C(9) bond length is 1.43 Å. In the fourth C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(7) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-H(7) bond length is 1.09 Å. In the sixth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.46 Å. In the seventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(7), and one H(8) atom. The C(11)-H(8) bond length is 1.09 Å. In the eighth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the ninth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(5) atom. The C(6)-N(2) bond length is 1.29 Å. The C(6)-H(5) bond length is 1.10 Å. N(2) is bonded in a bent 120 degrees geometry to one C(6) and one C(8) atom. There are six inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In each ZnC16NH10O5 cluster, Zn(1) is bonded in a 5-coordinate geometry to one N(1), one O(1), one O(2), one O(4), and one O(5) atom. The Zn(1)-N(1) bond length is 2.06 Å. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.40 Å. The Zn(1)-O(4) bond length is 1.97 Å. The Zn(1)-O(5) bond length is 2.02 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the third C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(1), and one O(2) atom. The C(12)-C(13) bond length is 1.48 Å. The C(12)-O(1) bond length is 1.30 Å. The C(12)-O(2) bond length is 1.26 Å. In the fourth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(18) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(18) bond length is 1.40 Å. In the fifth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(9) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(9) bond length is 1.09 Å. In the sixth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(10) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(10) bond length is 1.09 Å. In the seventh C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one O(3) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-O(3) bond length is 1.38 Å. In the eighth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(11) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(11) bond length is 1.09 Å. In the ninth C site, C(18) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one H(12) atom. The C(18)-H(12) bond length is 1.09 Å. In the tenth C site, C(19) is bonded in a distorted single-bond geometry to one O(3) atom. The C(19)-O(3) bond length is 1.40 Å. In the eleventh C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(13) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(13) bond length is 1.09 Å. In the twelfth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one H(14) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(25) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(25) bond length is 1.50 Å. In the fourteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one H(15) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-H(15) bond length is 1.09 Å. In the fifteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(16) atom. The C(24)-H(16) bond length is 1.09 Å. In the sixteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(4), and one O(5) atom. The C(25)-O(4) bond length is 1.27 Å. The C(25)-O(5) bond length is 1.27 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(12) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Zn(1) and one C(12) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(16) and one C(19) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(25) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(25) atom. Linkers: 2 C(=N/c1cccc2c(/N=C/c3ccncc3)cccc12)\c1ccncc1 ,4 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 O=[C]O[Zn]1O[C]O[Zn](O[C]=O)O[C]O1. The MOF has largest included sphere 7.09 A, density 1.14 g/cm3, surface area 4850.99 m2/g, accessible volume 0.36 cm3/g