CuC17H20S2OBr2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CuC17H20S2OBr2 cluster. Cu(1) is bonded to one S(1), one S(2), one O(1), one Br(1), and one Br(2) atom to form CuS2Br2O square pyramids that share  a cornercorner with one C(17)H3O tetrahedra. The Cu(1)-S(1) bond length is 2.36 Å. The Cu(1)-S(2) bond length is 2.36 Å. The Cu(1)-O(1) bond length is 2.26 Å. The Cu(1)-Br(1) bond length is 2.47 Å. The Cu(1)-Br(2) bond length is 2.42 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one C(2), one H(1), one H(2), and one S(1) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.83 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.51 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted water-like geometry to one C(5), one H(7), one H(8), and one S(2) atom. The C(8)-H(7) bond length is 1.10 Å. The C(8)-H(8) bond length is 1.10 Å. The C(8)-S(2) bond length is 1.83 Å. In the ninth C site, C(9) is bonded in a distorted water-like geometry to one C(10), one H(10), one H(9), and one S(1) atom. The C(9)-C(10) bond length is 1.51 Å. The C(9)-H(10) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. The C(9)-S(1) bond length is 1.83 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.40 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(12) atom. The C(11)-H(12) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(13,14) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(13,14) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(16) bond length is 1.50 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(13,14) atom. The C(14)-H(13,14) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one H(11) atom. The C(15)-H(11) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted water-like geometry to one C(13), one H(15), one H(16), and one S(2) atom. The C(16)-H(15) bond length is 1.10 Å. The C(16)-H(16) bond length is 1.10 Å. The C(16)-S(2) bond length is 1.84 Å. In the seventeenth C site, C(17) is bonded to one H(18), one H(19), one H(20), and one O(1) atom to form CH3O tetrahedra that share  a cornercorner with one Cu(1)S2Br2O square pyramid. The C(17)-H(18) bond length is 1.10 Å. The C(17)-H(19) bond length is 1.10 Å. The C(17)-H(20) bond length is 1.10 Å. The C(17)-O(1) bond length is 1.43 Å. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the thirteenth H site, H(13,14) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one O(1) and one Br(1) atom. The H(17)-O(1) bond length is 0.99 Å. The H(17)-Br(1) bond length is 2.24 Å. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(17) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(1), and one C(9) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(16), and one C(8) atom. O(1) is bonded in a 3-coordinate geometry to one Cu(1), one C(17), and one H(17) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one H(17) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 2 c1cc2ccc1CSCc1ccc(cc1)CSC2. Metal clusters: 2 Br[Cu]Br.CO. The MOF has largest included sphere 1.75 A, density 2.00 g/cm3, surface area 3740.63 m2/g, accessible volume 0.13 cm3/g