CuC8H8(NO)3CH3 crystallizes in the triclinic P1 space group. The structure consists of eight 02329_fluka molecules inside a CuC8H8(NO)3 framework. In the CuC8H8(NO)3 framework, there are eight inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square pyramidal geometry to one N(1), one N(9), one O(1), one O(19), and one O(5) atom. The Cu(1)-N(1) bond length is 1.91 Å. The Cu(1)-N(9) bond length is 1.95 Å. The Cu(1)-O(1) bond length is 2.02 Å. The Cu(1)-O(19) bond length is 2.30 Å. The Cu(1)-O(5) bond length is 2.06 Å. In the second Cu site, Cu(2) is bonded in a square pyramidal geometry to one N(10), one N(2), one O(2), one O(20), and one O(6) atom. The Cu(2)-N(10) bond length is 1.95 Å. The Cu(2)-N(2) bond length is 1.91 Å. The Cu(2)-O(2) bond length is 2.03 Å. The Cu(2)-O(20) bond length is 2.29 Å. The Cu(2)-O(6) bond length is 2.07 Å. In the third Cu site, Cu(3) is bonded in a square pyramidal geometry to one N(11), one N(3), one O(17), one O(3), and one O(7) atom. The Cu(3)-N(11) bond length is 1.95 Å. The Cu(3)-N(3) bond length is 1.91 Å. The Cu(3)-O(17) bond length is 2.30 Å. The Cu(3)-O(3) bond length is 2.02 Å. The Cu(3)-O(7) bond length is 2.06 Å. In the fourth Cu site, Cu(4) is bonded in a square pyramidal geometry to one N(12), one N(4), one O(18), one O(4), and one O(8) atom. The Cu(4)-N(12) bond length is 1.95 Å. The Cu(4)-N(4) bond length is 1.91 Å. The Cu(4)-O(18) bond length is 2.30 Å. The Cu(4)-O(4) bond length is 2.02 Å. The Cu(4)-O(8) bond length is 2.06 Å. In the fifth Cu site, Cu(5) is bonded in a square pyramidal geometry to one N(21); one N(5,7); one O(13); one O(21,23); and one O(9,11) atom. The Cu(5)-N(21) bond length is 1.95 Å. The Cu(5)-N(5,7) bond length is 1.92 Å. The Cu(5)-O(13) bond length is 2.02 Å. The Cu(5)-O(21,23) bond length is 2.28 Å. The Cu(5)-O(9,11) bond length is 2.06 Å. In the sixth Cu site, Cu(6) is bonded in a square pyramidal geometry to one N(22), one N(6), one O(10), one O(14), and one O(24) atom. The Cu(6)-N(22) bond length is 1.95 Å. The Cu(6)-N(6) bond length is 1.91 Å. The Cu(6)-O(10) bond length is 2.07 Å. The Cu(6)-O(14) bond length is 2.03 Å. The Cu(6)-O(24) bond length is 2.27 Å. In the seventh Cu site, Cu(7) is bonded in a square pyramidal geometry to one N(23); one N(5,7); one O(15); one O(21,23); and one O(9,11) atom. The Cu(7)-N(23) bond length is 1.95 Å. The Cu(7)-N(5,7) bond length is 1.92 Å. The Cu(7)-O(15) bond length is 2.02 Å. The Cu(7)-O(21,23) bond length is 2.29 Å. The Cu(7)-O(9,11) bond length is 2.06 Å. In the eighth Cu site, Cu(8) is bonded in a square pyramidal geometry to one N(24), one N(8), one O(12), one O(16), and one O(22) atom. The Cu(8)-N(24) bond length is 1.95 Å. The Cu(8)-N(8) bond length is 1.92 Å. The Cu(8)-O(12) bond length is 2.06 Å. The Cu(8)-O(16) bond length is 2.02 Å. The Cu(8)-O(22) bond length is 2.28 Å. There are forty-four inequivalent C sites. In the first C site, C(5,7) is bonded in a 2-coordinate geometry to one N(1) and one H(21,23,24) atom. The C(5,7)-N(1) bond length is 1.44 Å. The C(5,7)-H(21,23,24) bond length is 1.10 Å. In the second C site, C(6) is bonded in a 2-coordinate geometry to one N(2) and one H(22) atom. The C(6)-N(2) bond length is 1.44 Å. The C(6)-H(22) bond length is 1.10 Å. In the third C site, C(8) is bonded in a 2-coordinate geometry to one N(4) and one H(21,23,24) atom. The C(8)-N(4) bond length is 1.44 Å. The C(8)-H(21,23,24) bond length is 1.10 Å. In the fourth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(21,23) atom. The C(9)-O(1) bond length is 1.31 Å. The C(9)-O(21,23) bond length is 1.24 Å. In the fifth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(22) atom. The C(10)-O(2) bond length is 1.31 Å. The C(10)-O(22) bond length is 1.24 Å. In the sixth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(21,23) and one O(3) atom. The C(11)-O(21,23) bond length is 1.24 Å. The C(11)-O(3) bond length is 1.31 Å. In the seventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(24) and one O(4) atom. The C(12)-O(24) bond length is 1.24 Å. The C(12)-O(4) bond length is 1.31 Å. In the eighth C site, C(13,15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(9,11) atom. The C(13,15)-N(1) bond length is 1.31 Å. The C(13,15)-O(9,11) bond length is 1.28 Å. In the ninth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(10) atom. The C(14)-N(2) bond length is 1.31 Å. The C(14)-O(10) bond length is 1.28 Å. In the tenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(4) and one O(12) atom. The C(16)-N(4) bond length is 1.31 Å. The C(16)-O(12) bond length is 1.28 Å. In the eleventh C site, C(17,19) is bonded in a distorted bent 120 degrees geometry to one N(5,7) and one O(5) atom. The C(17,19)-N(5,7) bond length is 1.31 Å. The C(17,19)-O(5) bond length is 1.28 Å. In the twelfth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(6) and one O(6) atom. The C(18)-N(6) bond length is 1.31 Å. The C(18)-O(6) bond length is 1.28 Å. In the thirteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(8) and one O(8) atom. The C(20)-N(8) bond length is 1.31 Å. The C(20)-O(8) bond length is 1.28 Å. In the fourteenth C site, C(21,23) is bonded in a 2-coordinate geometry to one N(5,7) and one H(25,27) atom. The C(21,23)-N(5,7) bond length is 1.45 Å. The C(21,23)-H(25,27) bond length is 1.11 Å. In the fifteenth C site, C(22) is bonded in a 2-coordinate geometry to one N(6) and one H(26) atom. The C(22)-N(6) bond length is 1.44 Å. The C(22)-H(26) bond length is 1.11 Å. In the sixteenth C site, C(24) is bonded in a 2-coordinate geometry to one N(8) and one H(28) atom. The C(24)-N(8) bond length is 1.45 Å. The C(24)-H(28) bond length is 1.11 Å. In the seventeenth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(17) atom. The C(29)-O(13) bond length is 1.31 Å. The C(29)-O(17) bond length is 1.25 Å. In the eighteenth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one O(14) and one O(18) atom. The C(30)-O(14) bond length is 1.31 Å. The C(30)-O(18) bond length is 1.25 Å. In the nineteenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one O(15) and one O(19) atom. The C(31)-O(15) bond length is 1.31 Å. The C(31)-O(19) bond length is 1.24 Å. In the twentieth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one O(16) and one O(20) atom. The C(32)-O(16) bond length is 1.31 Å. The C(32)-O(20) bond length is 1.25 Å. In the twenty-first C site, C(33,35,36) is bonded in a distorted trigonal non-coplanar geometry to one C(37,39); one H(41,43); one H(45,47); and one H(49,51) atom. The C(33,35,36)-C(37,39) bond length is 1.49 Å. The C(33,35,36)-H(41,43) bond length is 1.10 Å. The C(33,35,36)-H(45,47) bond length is 1.10 Å. The C(33,35,36)-H(49,51) bond length is 1.10 Å. In the twenty-second C site, C(34) is bonded in a distorted trigonal non-coplanar geometry to one C(38), one H(42), one H(46), and one H(50) atom. The C(34)-C(38) bond length is 1.49 Å. The C(34)-H(42) bond length is 1.10 Å. The C(34)-H(46) bond length is 1.10 Å. The C(34)-H(50) bond length is 1.10 Å. In the twenty-third C site, C(37,39) is bonded in a distorted trigonal planar geometry to one C(33,35,36); one C(41); and one N(9) atom. The C(37,39)-C(41) bond length is 1.42 Å. The C(37,39)-N(9) bond length is 1.35 Å. In the twenty-fourth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(34), one C(42), and one N(10) atom. The C(38)-C(42) bond length is 1.42 Å. The C(38)-N(10) bond length is 1.35 Å. In the twenty-fifth C site, C(40) is bonded in a distorted trigonal planar geometry to one C(33,35,36); one C(43,44); and one N(12) atom. The C(40)-C(33,35,36) bond length is 1.49 Å. The C(40)-C(43,44) bond length is 1.42 Å. The C(40)-N(12) bond length is 1.35 Å. In the twenty-sixth C site, C(41) is bonded in a trigonal planar geometry to one C(37,39); one C(42); and one C(45) atom. The C(41)-C(42) bond length is 1.46 Å. The C(41)-C(45) bond length is 1.41 Å. In the twenty-seventh C site, C(42) is bonded in a trigonal planar geometry to one C(38), one C(41), and one C(46) atom. The C(42)-C(46) bond length is 1.41 Å. In the twenty-eighth C site, C(43,44) is bonded in a trigonal planar geometry to one C(37,39); one C(43,44); and one C(47) atom. The C(43,44)-C(37,39) bond length is 1.42 Å. The C(43,44)-C(43,44) bond length is 1.46 Å. The C(43,44)-C(47) bond length is 1.41 Å. In the twenty-ninth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(41); one C(49,50,51,52); and one N(13,15) atom. The C(45)-C(49,50,51,52) bond length is 1.49 Å. The C(45)-N(13,15) bond length is 1.35 Å. In the thirtieth C site, C(46) is bonded in a distorted trigonal planar geometry to one C(42); one C(49,50,51,52); and one N(14) atom. The C(46)-C(49,50,51,52) bond length is 1.49 Å. The C(46)-N(14) bond length is 1.35 Å. In the thirty-first C site, C(47) is bonded in a distorted trigonal planar geometry to one C(43,44); one C(49,50,51,52); and one N(13,15) atom. The C(47)-C(49,50,51,52) bond length is 1.49 Å. The C(47)-N(13,15) bond length is 1.35 Å. In the thirty-second C site, C(48) is bonded in a distorted trigonal planar geometry to one C(43,44); one C(49,50,51,52); and one N(16) atom. The C(48)-C(43,44) bond length is 1.41 Å. The C(48)-C(49,50,51,52) bond length is 1.49 Å. The C(48)-N(16) bond length is 1.35 Å. In the thirty-third C site, C(49,50,51,52) is bonded in a distorted trigonal non-coplanar geometry to one C(45); one H(53,54,55,56); one H(57,58,59,60); and one H(61,62,63,64) atom. The C(49,50,51,52)-H(53,54,55,56) bond length is 1.10 Å. The C(49,50,51,52)-H(57,58,59,60) bond length is 1.10 Å. The C(49,50,51,52)-H(61,62,63,64) bond length is 1.10 Å. In the thirty-fourth C site, C(53,54,55,56) is bonded in a distorted trigonal non-coplanar geometry to one C(57); one H(65,66,67,68); one H(69,70,71,72); and one H(73,74,75,76) atom. The C(53,54,55,56)-C(57) bond length is 1.49 Å. The C(53,54,55,56)-H(65,66,67,68) bond length is 1.10 Å. The C(53,54,55,56)-H(69,70,71,72) bond length is 1.10 Å. The C(53,54,55,56)-H(73,74,75,76) bond length is 1.10 Å. In the thirty-fifth C site, C(57) is bonded in a distorted trigonal planar geometry to one C(53,54,55,56); one C(61); and one N(17,19) atom. The C(57)-C(61) bond length is 1.40 Å. The C(57)-N(17,19) bond length is 1.35 Å. In the thirty-sixth C site, C(58) is bonded in a distorted trigonal planar geometry to one C(53,54,55,56); one C(62,63,64); and one N(18) atom. The C(58)-C(53,54,55,56) bond length is 1.49 Å. The C(58)-C(62,63,64) bond length is 1.40 Å. The C(58)-N(18) bond length is 1.35 Å. In the thirty-seventh C site, C(59) is bonded in a distorted trigonal planar geometry to one C(53,54,55,56); one C(62,63,64); and one N(17,19) atom. The C(59)-C(53,54,55,56) bond length is 1.49 Å. The C(59)-C(62,63,64) bond length is 1.40 Å. The C(59)-N(17,19) bond length is 1.35 Å. In the thirty-eighth C site, C(60) is bonded in a distorted trigonal planar geometry to one C(53,54,55,56); one C(62,63,64); and one N(20) atom. The C(60)-C(53,54,55,56) bond length is 1.49 Å. The C(60)-C(62,63,64) bond length is 1.40 Å. The C(60)-N(20) bond length is 1.35 Å. In the thirty-ninth C site, C(61) is bonded in a trigonal planar geometry to one C(57); one C(62,63,64); and one C(65,67) atom. The C(61)-C(62,63,64) bond length is 1.46 Å. The C(61)-C(65,67) bond length is 1.42 Å. In the fortieth C site, C(62,63,64) is bonded in a trigonal planar geometry to one C(58), one C(61), and one C(66) atom. The C(62,63,64)-C(66) bond length is 1.42 Å. In the forty-first C site, C(65,67) is bonded in a distorted trigonal planar geometry to one C(61); one C(69,70,71,72); and one N(21) atom. The C(65,67)-C(69,70,71,72) bond length is 1.49 Å. The C(65,67)-N(21) bond length is 1.34 Å. In the forty-second C site, C(66) is bonded in a distorted trigonal planar geometry to one C(62,63,64); one C(69,70,71,72); and one N(22) atom. The C(66)-C(69,70,71,72) bond length is 1.49 Å. The C(66)-N(22) bond length is 1.35 Å. In the forty-third C site, C(68) is bonded in a distorted trigonal planar geometry to one C(62,63,64); one C(69,70,71,72); and one N(24) atom. The C(68)-C(62,63,64) bond length is 1.42 Å. The C(68)-C(69,70,71,72) bond length is 1.49 Å. The C(68)-N(24) bond length is 1.34 Å. In the forty-fourth C site, C(69,70,71,72) is bonded in a distorted trigonal non-coplanar geometry to one C(65,67); one H(77,79,80); one H(81,83,84); and one H(85,87,88) atom. The C(69,70,71,72)-H(77,79,80) bond length is 1.10 Å. The C(69,70,71,72)-H(81,83,84) bond length is 1.10 Å. The C(69,70,71,72)-H(85,87,88) bond length is 1.10 Å. There are twenty-one inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1); one C(13,15); and one C(5,7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(14), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(3); one C(13,15); and one C(5,7) atom. The N(3)-C(13,15) bond length is 1.31 Å. The N(3)-C(5,7) bond length is 1.44 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(4), one C(16), and one C(8) atom. In the fifth N site, N(5,7) is bonded in a trigonal planar geometry to one Cu(5); one C(17,19); and one C(21,23) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(6), one C(18), and one C(22) atom. In the seventh N site, N(8) is bonded in a trigonal planar geometry to one Cu(8), one C(20), and one C(24) atom. In the eighth N site, N(9) is bonded in a distorted trigonal planar geometry to one Cu(1); one C(37,39); and one N(13,15) atom. The N(9)-N(13,15) bond length is 1.35 Å. In the ninth N site, N(10) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(38), and one N(14) atom. The N(10)-N(14) bond length is 1.35 Å. In the tenth N site, N(11) is bonded in a distorted trigonal planar geometry to one Cu(3); one C(37,39); and one N(13,15) atom. The N(11)-C(37,39) bond length is 1.35 Å. The N(11)-N(13,15) bond length is 1.35 Å. In the eleventh N site, N(12) is bonded in a distorted trigonal planar geometry to one Cu(4), one C(40), and one N(16) atom. The N(12)-N(16) bond length is 1.35 Å. In the twelfth N site, N(13,15) is bonded in a 3-coordinate geometry to one C(45), one N(9), and one H(1) atom. The N(13,15)-H(1) bond length is 1.05 Å. In the thirteenth N site, N(14) is bonded in a 3-coordinate geometry to one C(46), one N(10), and one H(2) atom. The N(14)-H(2) bond length is 1.05 Å. In the fourteenth N site, N(16) is bonded in a 3-coordinate geometry to one C(48), one N(12), and one H(4) atom. The N(16)-H(4) bond length is 1.05 Å. In the fifteenth N site, N(17,19) is bonded in a 3-coordinate geometry to one C(57), one N(21), and one H(5) atom. The N(17,19)-N(21) bond length is 1.35 Å. The N(17,19)-H(5) bond length is 1.05 Å. In the sixteenth N site, N(18) is bonded in a 3-coordinate geometry to one C(58), one N(22), and one H(6) atom. The N(18)-N(22) bond length is 1.35 Å. The N(18)-H(6) bond length is 1.05 Å. In the seventeenth N site, N(20) is bonded in a 3-coordinate geometry to one C(60), one N(24), and one H(8) atom. The N(20)-N(24) bond length is 1.35 Å. The N(20)-H(8) bond length is 1.05 Å. In the eighteenth N site, N(21) is bonded in a distorted trigonal planar geometry to one Cu(5); one C(65,67); and one N(17,19) atom. In the nineteenth N site, N(22) is bonded in a distorted trigonal planar geometry to one Cu(6), one C(66), and one N(18) atom. In the twentieth N site, N(23) is bonded in a distorted trigonal planar geometry to one Cu(7); one C(65,67); and one N(17,19) atom. The N(23)-C(65,67) bond length is 1.35 Å. The N(23)-N(17,19) bond length is 1.35 Å. In the twenty-first N site, N(24) is bonded in a distorted trigonal planar geometry to one Cu(8), one C(68), and one N(20) atom. There are thirty-four inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one N(13,15) and one O(15) atom. The H(1)-O(15) bond length is 1.70 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one N(14) and one O(16) atom. The H(2)-O(16) bond length is 1.70 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one N(13,15) and one O(13) atom. The H(3)-N(13,15) bond length is 1.05 Å. The H(3)-O(13) bond length is 1.70 Å. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one N(16) and one O(14) atom. The H(4)-O(14) bond length is 1.70 Å. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one N(17,19) and one O(3) atom. The H(5)-O(3) bond length is 1.70 Å. In the sixth H site, H(6) is bonded in a distorted single-bond geometry to one N(18) and one O(4) atom. The H(6)-O(4) bond length is 1.70 Å. In the seventh H site, H(7) is bonded in a distorted single-bond geometry to one N(17,19) and one O(1) atom. The H(7)-N(17,19) bond length is 1.05 Å. The H(7)-O(1) bond length is 1.70 Å. In the eighth H site, H(8) is bonded in a distorted single-bond geometry to one N(20) and one O(2) atom. The H(8)-O(2) bond length is 1.70 Å. In the ninth H site, H(21,23,24) is bonded in a single-bond geometry to one C(5,7) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(6) atom. In the eleventh H site, H(25,27) is bonded in a single-bond geometry to one C(21,23) atom. In the twelfth H site, H(26) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(28) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(41,43) is bonded in a single-bond geometry to one C(33,35,36) atom. In the fifteenth H site, H(42) is bonded in a single-bond geometry to one C(34) atom. In the sixteenth H site, H(44) is bonded in a single-bond geometry to one C(33,35,36) atom. The H(44)-C(33,35,36) bond length is 1.10 Å. In the seventeenth H site, H(45,47) is bonded in a single-bond geometry to one C(33,35,36) atom. In the eighteenth H site, H(46) is bonded in a single-bond geometry to one C(34) atom. In the nineteenth H site, H(48) is bonded in a single-bond geometry to one C(33,35,36) atom. The H(48)-C(33,35,36) bond length is 1.10 Å. In the twentieth H site, H(49,51) is bonded in a single-bond geometry to one C(33,35,36) atom. In the twenty-first H site, H(50) is bonded in a single-bond geometry to one C(34) atom. In the twenty-second H site, H(52) is bonded in a single-bond geometry to one C(33,35,36) atom. The H(52)-C(33,35,36) bond length is 1.10 Å. In the twenty-third H site, H(53,54,55,56) is bonded in a single-bond geometry to one C(49,50,51,52) atom. In the twenty-fourth H site, H(57,58,59,60) is bonded in a single-bond geometry to one C(49,50,51,52) atom. In the twenty-fifth H site, H(61,62,63,64) is bonded in a single-bond geometry to one C(49,50,51,52) atom. In the twenty-sixth H site, H(65,66,67,68) is bonded in a single-bond geometry to one C(53,54,55,56) atom. In the twenty-seventh H site, H(69,70,71,72) is bonded in a single-bond geometry to one C(53,54,55,56) atom. In the twenty-eighth H site, H(73,74,75,76) is bonded in a single-bond geometry to one C(53,54,55,56) atom. In the twenty-ninth H site, H(77,79,80) is bonded in a single-bond geometry to one C(69,70,71,72) atom. In the thirtieth H site, H(78) is bonded in a single-bond geometry to one C(69,70,71,72) atom. The H(78)-C(69,70,71,72) bond length is 1.10 Å. In the thirty-first H site, H(81,83,84) is bonded in a single-bond geometry to one C(69,70,71,72) atom. In the thirty-second H site, H(82) is bonded in a single-bond geometry to one C(69,70,71,72) atom. The H(82)-C(69,70,71,72) bond length is 1.10 Å. In the thirty-third H site, H(85,87,88) is bonded in a single-bond geometry to one C(69,70,71,72) atom. In the thirty-fourth H site, H(86) is bonded in a single-bond geometry to one C(69,70,71,72) atom. The H(86)-C(69,70,71,72) bond length is 1.10 Å. There are twenty-two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Cu(1), one C(9), and one H(7) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Cu(2), one C(10), and one H(8) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Cu(3), one C(11), and one H(5) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Cu(4), one C(12), and one H(6) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Cu(1) and one C(17,19) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Cu(2) and one C(18) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Cu(3) and one C(17,19) atom. The O(7)-C(17,19) bond length is 1.28 Å. In the eighth O site, O(8) is bonded in a water-like geometry to one Cu(4) and one C(20) atom. In the ninth O site, O(9,11) is bonded in a water-like geometry to one Cu(5) and one C(13,15) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Cu(6) and one C(14) atom. In the eleventh O site, O(12) is bonded in a water-like geometry to one Cu(8) and one C(16) atom. In the twelfth O site, O(13) is bonded in a 3-coordinate geometry to one Cu(5), one C(29), and one H(3) atom. In the thirteenth O site, O(14) is bonded in a 3-coordinate geometry to one Cu(6), one C(30), and one H(4) atom. In the fourteenth O site, O(15) is bonded in a 3-coordinate geometry to one Cu(7), one C(31), and one H(1) atom. In the fifteenth O site, O(16) is bonded in a 3-coordinate geometry to one Cu(8), one C(32), and one H(2) atom. In the sixteenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one C(29) atom. In the seventeenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one C(30) atom. In the eighteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(31) atom. In the nineteenth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(32) atom. In the twentieth O site, O(21,23) is bonded in a distorted single-bond geometry to one Cu(7) and one C(9) atom. In the twenty-first O site, O(22) is bonded in a distorted single-bond geometry to one Cu(8) and one C(10) atom. In the twenty-second O site, O(24) is bonded in a distorted single-bond geometry to one Cu(6) and one C(12) atom. Linkers: 4 Cc1n[nH]c(C)c1-c1c(C)n[nH]c1C ,3 C[C@@H]([N]C(=O)C(=O)[N][C@H](C)C([O])=O)C([O])=O. Metal clusters: 8 [Cu]. The MOF has largest included sphere 4.13 A, density 1.31 g/cm3, surface area 4457.56 m2/g, accessible volume 0.28 cm3/g