CuC14N3H11O8(CH)2(CH3)2 crystallizes in the orthorhombic Pca2_1 space group. The structure consists of eight 02329_fluka molecules and eight 02329_fluka molecules inside a CuC14N3H11O8 framework. In the CuC14N3H11O8 framework, Cu(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(3), one O(5), and one O(6) atom. The Cu(1)-N(1) bond length is 2.00 Å. The Cu(1)-O(1) bond length is 1.97 Å. The Cu(1)-O(3) bond length is 1.99 Å. The Cu(1)-O(5) bond length is 2.01 Å. The Cu(1)-O(6) bond length is 2.23 Å. There are fourteen inequivalent C sites. In the first C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(13)-O(3) bond length is 1.28 Å. The C(13)-O(4) bond length is 1.28 Å. In the second C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(15)-O(5) bond length is 1.29 Å. The C(15)-O(6) bond length is 1.26 Å. In the third C site, C(17) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(17)-O(7) bond length is 1.34 Å. The C(17)-O(8) bond length is 1.23 Å. In the fourth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(4) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(4) bond length is 1.09 Å. In the fifth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(5) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(5) bond length is 1.09 Å. In the sixth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(2) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-N(2) bond length is 1.38 Å. In the seventh C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(6) atom. The C(4)-H(6) bond length is 1.09 Å. In the eighth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and one H(7) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(7) bond length is 1.09 Å. In the ninth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(3), and one H(8) atom. The C(6)-C(7) bond length is 1.37 Å. The C(6)-N(3) bond length is 1.35 Å. The C(6)-H(8) bond length is 1.09 Å. In the tenth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(9) atom. The C(7)-C(8) bond length is 1.42 Å. The C(7)-H(9) bond length is 1.09 Å. In the eleventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(2) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-N(2) bond length is 1.37 Å. In the twelfth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(10) atom. The C(9)-H(10) bond length is 1.08 Å. In the thirteenth C site, C(10) is bonded in a distorted trigonal planar geometry to one N(3) and one H(11) atom. The C(10)-N(3) bond length is 1.35 Å. The C(10)-H(11) bond length is 1.09 Å. In the fourteenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(11)-O(1) bond length is 1.28 Å. The C(11)-O(2) bond length is 1.26 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(3), one C(8), and one H(2) atom. The N(2)-H(2) bond length is 1.05 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(6), and one H(3) atom. The N(3)-H(3) bond length is 1.06 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(4) and one O(7) atom. The H(1)-O(4) bond length is 1.63 Å. The H(1)-O(7) bond length is 1.01 Å. In the second H site, H(2) is bonded in a distorted linear geometry to one N(2) and one O(2) atom. The H(2)-O(2) bond length is 1.63 Å. In the third H site, H(3) is bonded in a linear geometry to one N(3) and one O(4) atom. The H(3)-O(4) bond length is 1.62 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(10) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(11) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one C(11) and one H(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(13) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one C(13), one H(1), and one H(3) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Cu(1) and one C(15) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Cu(1) and one C(15) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one C(17) and one H(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(17) atom. Linkers: 4 CC(C([O])=O)C(=O)O. Metal clusters: 4 [Cu]. The MOF has largest included sphere 3.00 A, density 1.53 g/cm3, surface area 4574.06 m2/g, accessible volume 0.15 cm3/g