CdC32H24(N3Cl)2(C3H2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 2,3-dimethyl-1,3-butadiene molecules and two CdC32H24(N3Cl)2 clusters. In each CdC32H24(N3Cl)2 cluster, Cd(1) is bonded in a distorted pentagonal pyramidal geometry to one N(1), one N(2), one N(3), one N(4), one Cl(1), and one Cl(2) atom. The Cd(1)-N(1) bond length is 2.42 Å. The Cd(1)-N(2) bond length is 2.42 Å. The Cd(1)-N(3) bond length is 2.58 Å. The Cd(1)-N(4) bond length is 2.58 Å. The Cd(1)-Cl(1) bond length is 2.50 Å. The Cd(1)-Cl(2) bond length is 2.50 Å. There are twenty-nine inequivalent C sites. In the first C site, C(38) is bonded in a distorted single-bond geometry to one C(13,14) and one H(27,28) atom. The C(38)-C(13,14) bond length is 1.40 Å. The C(38)-H(27,28) bond length is 1.09 Å. In the second C site, C(37) is bonded in a distorted single-bond geometry to one C(13,14) and one H(27,28) atom. The C(37)-C(13,14) bond length is 1.40 Å. The C(37)-H(27,28) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(13,14); one N(5); one H(1,2); and one H(3,4) atom. The C(3)-C(13,14) bond length is 1.51 Å. The C(3)-N(5) bond length is 1.46 Å. The C(3)-H(1,2) bond length is 1.10 Å. The C(3)-H(3,4) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one C(13,14); one N(6); one H(1,2); and one H(3,4) atom. The C(4)-C(13,14) bond length is 1.51 Å. The C(4)-N(6) bond length is 1.46 Å. The C(4)-H(1,2) bond length is 1.10 Å. The C(4)-H(3,4) bond length is 1.10 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one N(3) atom. The C(7)-C(11) bond length is 1.47 Å. The C(7)-C(9) bond length is 1.40 Å. The C(7)-N(3) bond length is 1.35 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(4) atom. The C(8)-C(10) bond length is 1.41 Å. The C(8)-C(12) bond length is 1.47 Å. The C(8)-N(4) bond length is 1.35 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(27,28); one C(7); and one H(7,8) atom. The C(9)-C(27,28) bond length is 1.39 Å. The C(9)-H(7,8) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(27,28); one C(8); and one H(7,8) atom. The C(10)-C(27,28) bond length is 1.39 Å. The C(10)-H(7,8) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one N(5) atom. The C(11)-N(1) bond length is 1.34 Å. The C(11)-N(5) bond length is 1.38 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one N(6) atom. The C(12)-N(2) bond length is 1.34 Å. The C(12)-N(6) bond length is 1.38 Å. In the eleventh C site, C(13,14) is bonded in a trigonal planar geometry to one C(15), one C(3), and one C(37) atom. The C(13,14)-C(15) bond length is 1.40 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(13,14) and one H(9,10) atom. The C(15)-H(9,10) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(13,14) and one H(9,10) atom. The C(16)-C(13,14) bond length is 1.40 Å. The C(16)-H(9,10) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one N(1) atom. The C(17)-C(21) bond length is 1.42 Å. The C(17)-C(23) bond length is 1.40 Å. The C(17)-N(1) bond length is 1.38 Å. In the fifteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one N(2) atom. The C(18)-C(22) bond length is 1.42 Å. The C(18)-C(24) bond length is 1.40 Å. The C(18)-N(2) bond length is 1.38 Å. In the sixteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(23); one C(31,32); and one H(11,12) atom. The C(19)-C(23) bond length is 1.39 Å. The C(19)-C(31,32) bond length is 1.41 Å. The C(19)-H(11,12) bond length is 1.09 Å. In the seventeenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(24); one C(31,32); and one H(11,12) atom. The C(20)-C(24) bond length is 1.39 Å. The C(20)-C(31,32) bond length is 1.41 Å. The C(20)-H(11,12) bond length is 1.09 Å. In the eighteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(17), one C(33), and one N(5) atom. The C(21)-C(33) bond length is 1.40 Å. The C(21)-N(5) bond length is 1.38 Å. In the nineteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(18), one C(34), and one N(6) atom. The C(22)-C(34) bond length is 1.40 Å. The C(22)-N(6) bond length is 1.38 Å. In the twentieth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(13) atom. The C(23)-H(13) bond length is 1.09 Å. In the twenty-first C site, C(24) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(14) atom. The C(24)-H(14) bond length is 1.09 Å. In the twenty-second C site, C(27,28) is bonded in a distorted trigonal planar geometry to one C(35); one C(9); and one H(17,18) atom. The C(27,28)-C(35) bond length is 1.39 Å. The C(27,28)-H(17,18) bond length is 1.09 Å. In the twenty-third C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(35), one N(3), and one H(19) atom. The C(29)-C(35) bond length is 1.39 Å. The C(29)-N(3) bond length is 1.33 Å. The C(29)-H(19) bond length is 1.09 Å. In the twenty-fourth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(36), one N(4), and one H(20) atom. The C(30)-C(36) bond length is 1.39 Å. The C(30)-N(4) bond length is 1.33 Å. The C(30)-H(20) bond length is 1.09 Å. In the twenty-fifth C site, C(31,32) is bonded in a distorted single-bond geometry to one C(19) and one H(21,22) atom. The C(31,32)-H(21,22) bond length is 1.09 Å. In the twenty-sixth C site, C(33) is bonded in a distorted single-bond geometry to one C(21) and one H(23,24) atom. The C(33)-H(23,24) bond length is 1.09 Å. In the twenty-seventh C site, C(34) is bonded in a distorted single-bond geometry to one C(22) and one H(23,24) atom. The C(34)-H(23,24) bond length is 1.09 Å. In the twenty-eighth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(27,28); one C(29); and one H(25,26) atom. The C(35)-H(25,26) bond length is 1.09 Å. In the twenty-ninth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(27,28); one C(30); and one H(25,26) atom. The C(36)-C(27,28) bond length is 1.39 Å. The C(36)-H(25,26) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one C(17) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(12), and one C(18) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one Cd(1), one C(29), and one C(7) atom. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one Cd(1), one C(30), and one C(8) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(11), one C(21), and one C(3) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(12), one C(22), and one C(4) atom. There are fourteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(7,8) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(9,10) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(11,12) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(17,18) is bonded in a single-bond geometry to one C(27,28) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(30) atom. In the eleventh H site, H(21,22) is bonded in a single-bond geometry to one C(31,32) atom. In the twelfth H site, H(23,24) is bonded in a single-bond geometry to one C(33) atom. In the thirteenth H site, H(25,26) is bonded in a single-bond geometry to one C(35) atom. In the fourteenth H site, H(27,28) is bonded in a single-bond geometry to one C(37) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cd(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cd(1) atom. Linkers: 2 c1ccc(-c2nc3ccccc3n2Cc2ccc(-c3ccc(Cn4c(-c5ccccn5)nc5ccccc54)cc3)cc2)nc1 ,2 [CH]c1nc(-c2ccccn2)n(Cc2ccc(-c3ccc(Cn4c(-c5ccccn5)nc5ccccc54)cc3)cc2)c1[CH]. Metal clusters: 2 Cl[Cd]Cl. The MOF has largest included sphere 4.30 A, density 1.47 g/cm3, surface area 4575.99 m2/g, accessible volume 0.16 cm3/g