Cd3C36H16(N2O3)4(CH)12(CH2)12(CF)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, twelve 02329_fluka molecules, two fluoromethane molecules, and one Cd3C36H16(N2O3)4 cluster. In the Cd3C36H16(N2O3)4 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 7-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(4), one O(5), and one O(6) atom. The Cd(1)-N(1) bond length is 2.30 Å. The Cd(1)-N(2) bond length is 2.43 Å. The Cd(1)-O(1) bond length is 2.53 Å. The Cd(1)-O(2) bond length is 2.45 Å. The Cd(1)-O(4) bond length is 2.28 Å. The Cd(1)-O(5) bond length is 2.34 Å. The Cd(1)-O(6) bond length is 2.61 Å. In the second Cd site, Cd(2) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. Both Cd(2)-O(1) bond lengths are 2.37 Å. Both Cd(2)-O(3) bond lengths are 2.24 Å. Both Cd(2)-O(5) bond lengths are 2.34 Å. There are eighteen inequivalent C sites. In the first C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(2)-O(1) bond length is 1.28 Å. The C(2)-O(2) bond length is 1.28 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(3)-O(3) bond length is 1.28 Å. The C(3)-O(4) bond length is 1.27 Å. In the third C site, C(7) is bonded in a distorted trigonal planar geometry to one N(1) and one H(7) atom. The C(7)-N(1) bond length is 1.33 Å. The C(7)-H(7) bond length is 1.09 Å. In the fourth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(9) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-H(9) bond length is 1.09 Å. In the fifth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(18), and one C(9) atom. The C(10)-C(11) bond length is 1.43 Å. The C(10)-C(18) bond length is 1.42 Å. In the sixth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(1) atom. The C(11)-C(12) bond length is 1.46 Å. The C(11)-N(1) bond length is 1.35 Å. In the seventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(16), and one N(2) atom. The C(12)-C(16) bond length is 1.43 Å. The C(12)-N(2) bond length is 1.35 Å. In the eighth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(2), and one H(10) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-N(2) bond length is 1.33 Å. The C(13)-H(10) bond length is 1.09 Å. In the ninth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(11) atom. The C(14)-C(15) bond length is 1.38 Å. The C(14)-H(11) bond length is 1.09 Å. In the tenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(12) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(12) bond length is 1.09 Å. In the eleventh C site, C(16) is bonded in a trigonal planar geometry to one C(12), one C(15), and one C(17) atom. The C(16)-C(17) bond length is 1.43 Å. In the twelfth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one N(3) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-N(3) bond length is 1.37 Å. In the thirteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(10), one C(17), and one N(4) atom. The C(18)-N(4) bond length is 1.37 Å. In the fourteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(20), one N(3), and one N(4) atom. The C(19)-C(20) bond length is 1.46 Å. The C(19)-N(3) bond length is 1.34 Å. The C(19)-N(4) bond length is 1.37 Å. In the fifteenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(25) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(25) bond length is 1.41 Å. In the sixteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(13) atom. The C(21)-H(13) bond length is 1.09 Å. In the seventeenth C site, C(25) is bonded in a distorted single-bond geometry to one C(20) and one H(16) atom. The C(25)-H(16) bond length is 1.09 Å. In the eighteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(26)-O(5) bond length is 1.30 Å. The C(26)-O(6) bond length is 1.26 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(7) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(12), and one C(13) atom. In the third N site, N(3) is bonded in a water-like geometry to one C(17) and one C(19) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(18), one C(19), and one H(26) atom. The N(4)-H(26) bond length is 1.03 Å. There are eight inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the eighth H site, H(26) is bonded in a single-bond geometry to one N(4) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one C(3) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(3) atom. In the third O site, O(5) is bonded in a distorted T-shaped geometry to one Cd(1), one Cd(2), and one C(26) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one Cd(1) and one C(26) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(2) atom. In the sixth O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(2) atom. Linkers: 2 Fc1ccc(-c2nc3c4cccnc4c4ncccc4c3[nH]2)cc1 ,1 [O]C(=O)[C@H]1CC[C@H](C([O])=O)CC1 ,2 [O]C(=O)[C@H]1CC[C@@H](C([O])=O)CC1. Metal clusters: 1 O=[C]O[Cd]1O[C]O[Cd]2(O[C]O1)O[C]O[Cd](O[C]=O)O[C]O2. The MOF has largest included sphere 2.80 A, density 1.76 g/cm3, surface area 3931.13 m2/g, accessible volume 0.12 cm3/g