(CH)5AgC15PNH11SO3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules and one AgC15PNH11SO3 cluster. In the AgC15PNH11SO3 cluster, Ag(1) is bonded in a distorted T-shaped geometry to one P(1), one N(1), and one O(1) atom. The Ag(1)-P(1) bond length is 2.33 Å. The Ag(1)-N(1) bond length is 2.15 Å. The Ag(1)-O(1) bond length is 2.57 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one O(3) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-N(1) bond length is 1.37 Å. The C(1)-O(3) bond length is 1.24 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(4) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(7)-S(1) bond length is 1.77 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(9), and one P(1) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. The C(8)-P(1) bond length is 1.82 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(5) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(5) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(6) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(6) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(7) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(7) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(8) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(8) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(9) atom. The C(13)-H(9) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one C(15), one C(19), and one P(1) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(19) bond length is 1.40 Å. The C(14)-P(1) bond length is 1.82 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(10) atom. The C(15)-H(10) bond length is 1.09 Å. In the fourteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(14) atom. The C(19)-H(14) bond length is 1.09 Å. In the fifteenth C site, C(20) is bonded in a distorted water-like geometry to one P(1), one H(15), and one H(16) atom. The C(20)-P(1) bond length is 1.83 Å. The C(20)-H(15) bond length is 1.10 Å. The C(20)-H(16) bond length is 1.10 Å. P(1) is bonded in a tetrahedral geometry to one Ag(1), one C(14), one C(20), and one C(8) atom. N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one S(1) atom. The N(1)-S(1) bond length is 1.64 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(20) atom. S(1) is bonded in a distorted tetrahedral geometry to one C(7), one N(1), one O(1), and one O(2) atom. The S(1)-O(1) bond length is 1.46 Å. The S(1)-O(2) bond length is 1.45 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. Linkers: 2 [c]1[c]cc(P(CCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1 ,1 c1ccc(P(CCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1 ,2 O=C1[N]S(=O)(=O)c2ccccc21. Metal clusters: 2 [Ag]. The MOF has largest included sphere 4.18 A, density 1.58 g/cm3, surface area 4390.24 m2/g, accessible volume 0.16 cm3/g