CdC7N2H6O5(CH3)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a CdC7N2H6O5 framework. In the CdC7N2H6O5 framework, Cd(1) is bonded in a 7-coordinate geometry to one N(1), one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms. The Cd(1)-N(1) bond length is 2.41 Å. The Cd(1)-O(2) bond length is 2.63 Å. The Cd(1)-O(3) bond length is 2.35 Å. The Cd(1)-O(4) bond length is 2.39 Å. The Cd(1)-O(5) bond length is 2.26 Å. There is one shorter (2.31 Å) and one longer (2.66 Å) Cd(1)-O(1) bond length. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-N(2) bond length is 1.42 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(6)-O(2) bond length is 1.28 Å. The C(6)-O(3) bond length is 1.27 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(8)-O(1) bond length is 1.28 Å. The C(8)-O(4) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(3) and one N(2) atom. The N(2)-N(2) bond length is 1.27 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(11) is bonded in a linear geometry to one O(2) and one O(5) atom. The H(11)-O(2) bond length is 1.60 Å. The H(11)-O(5) bond length is 1.01 Å. In the sixth H site, H(12) is bonded in a distorted single-bond geometry to one O(4) and one O(5) atom. The H(12)-O(4) bond length is 1.65 Å. The H(12)-O(5) bond length is 1.00 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent Cd(1) and one C(8) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(1), one C(6), and one H(11) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(1) and one C(6) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Cd(1), one C(8), and one H(12) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Cd(1), one H(11), and one H(12) atom. Linkers: 2 c1cc([N][N]c2ccncc2)ccn1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 3.12 A, density 1.62 g/cm3, surface area 4220.08 m2/g, accessible volume 0.22 cm3/g