ZnC14N9H14(C4H3)2C2NH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four isobutylene molecules, two n-methyl methanimine molecules, and one ZnC14N9H14 cluster. In the ZnC14N9H14 cluster, Zn(1) is bonded in an octahedral geometry to one N(1), one N(3), one N(4), one N(7), one N(8), and one N(9) atom. The Zn(1)-N(1) bond length is 2.42 Å. The Zn(1)-N(3) bond length is 2.17 Å. The Zn(1)-N(4) bond length is 2.09 Å. The Zn(1)-N(7) bond length is 2.18 Å. The Zn(1)-N(8) bond length is 2.13 Å. The Zn(1)-N(9) bond length is 2.18 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one C(3), one H(1), and one H(2) atom. The C(1)-C(3) bond length is 1.50 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(7) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(7) bond length is 1.40 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(7), and one H(5) atom. The C(5)-N(7) bond length is 1.34 Å. The C(5)-H(5) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(6) atom. The C(6)-N(7) bond length is 1.35 Å. The C(6)-H(6) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(3) and one H(7) atom. The C(7)-H(7) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(9) atom. The C(10)-N(8) bond length is 1.35 Å. The C(10)-H(9) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(10) atom. The C(11)-N(8) bond length is 1.34 Å. The C(11)-H(10) bond length is 1.09 Å. In the ninth C site, C(13) is bonded in a distorted water-like geometry to one C(15), one H(12), and one H(13) atom. The C(13)-C(15) bond length is 1.50 Å. The C(13)-H(12) bond length is 1.10 Å. The C(13)-H(13) bond length is 1.10 Å. In the tenth C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(16), and one C(19) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(19) bond length is 1.40 Å. In the eleventh C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one H(15) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(15) bond length is 1.09 Å. In the twelfth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(9), and one H(16) atom. The C(17)-N(9) bond length is 1.35 Å. The C(17)-H(16) bond length is 1.09 Å. In the thirteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(17) atom. The C(18)-N(9) bond length is 1.35 Å. The C(18)-H(17) bond length is 1.09 Å. In the fourteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(15) and one H(18) atom. The C(19)-H(18) bond length is 1.09 Å. There are nine inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one N(2) atom. The N(1)-N(2) bond length is 1.18 Å. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.19 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one N(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one N(5) atom. The N(4)-N(5) bond length is 1.20 Å. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.17 Å. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Zn(1), one C(5), and one C(6) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(11) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Zn(1), one C(17), and one C(18) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. Linkers: 1 [CH]C(=[CH])C[C@H](c1ccncc1)[C@@H](Cc1ccncc1)c1ccncc1 ,2 c1cc(C[C@H](c2ccncc2)[C@@H](Cc2ccncc2)c2ccncc2)ccn1 ,1 [c]1cc(C[C@H](c2ccncc2)[C@@H](Cc2ccncc2)c2ccncc2)ccn1 ,1 [CH]C(=[CH])C[C@@H](c1ccncc1)[C@H](Cc1ccncc1)c1ccncc1 ,1 [c]1cc(C[C@@H](c2ccncc2)[C@H](Cc2ccncc2)c2ccncc2)ccn1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.19 A, density 1.49 g/cm3, surface area 4855.68 m2/g, accessible volume 0.16 cm3/g