CdC12N5H15S2CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CdC12N5H15S2 clusters. In each CdC12N5H15S2 cluster, Cd(1) is bonded to one N(1), one N(2), one N(3), one S(2), and two equivalent S(1) atoms to form distorted edge-sharing CdS3N3 octahedra. The Cd(1)-N(1) bond length is 2.35 Å. The Cd(1)-N(2) bond length is 2.35 Å. The Cd(1)-N(3) bond length is 2.38 Å. The Cd(1)-S(2) bond length is 2.70 Å. There is one shorter (2.72 Å) and one longer (2.90 Å) Cd(1)-S(1) bond length. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(5) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(5) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(6) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(6) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.50 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(7,23) atom. The C(4)-H(7,23) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(8) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(3); one H(10,26); one H(11,28); and one H(9) atom. The C(6)-H(10,26) bond length is 1.10 Å. The C(6)-H(11,28) bond length is 1.10 Å. The C(6)-H(9) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2); one H(12,30); and one H(13,29) atom. The C(7)-N(2) bond length is 1.48 Å. The C(7)-H(12,30) bond length is 1.10 Å. The C(7)-H(13,29) bond length is 1.10 Å. In the eighth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(3); one H(16,34); and one H(17,33) atom. The C(9)-N(3) bond length is 1.47 Å. The C(9)-H(16,34) bond length is 1.10 Å. The C(9)-H(17,33) bond length is 1.10 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one S(1), and one S(2) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-S(1) bond length is 1.73 Å. The C(10)-S(2) bond length is 1.71 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(13) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-C(13) bond length is 1.41 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one N(4) atom. The C(12)-N(4) bond length is 1.18 Å. In the twelfth C site, C(13) is bonded in a distorted linear geometry to one C(11) and one N(5) atom. The C(13)-N(5) bond length is 1.18 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Cd(1), one C(7), one H(1), and one H(2) atom. The N(2)-H(1) bond length is 1.03 Å. The N(2)-H(2) bond length is 1.03 Å. In the third N site, N(3) is bonded in a 4-coordinate geometry to one Cd(1), one C(9), one H(3), and one H(4) atom. The N(3)-H(3) bond length is 1.02 Å. The N(3)-H(4) bond length is 1.03 Å. In the fourth N site, N(4) is bonded in a single-bond geometry to one C(12) atom. In the fifth N site, N(5) is bonded in a single-bond geometry to one C(13) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7,23) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(10,26) is bonded in a single-bond geometry to one C(6) atom. In the eleventh H site, H(11,28) is bonded in a single-bond geometry to one C(6) atom. In the twelfth H site, H(12,30) is bonded in a single-bond geometry to one C(7) atom. In the thirteenth H site, H(13,29) is bonded in a single-bond geometry to one C(7) atom. In the fourteenth H site, H(16,34) is bonded in a single-bond geometry to one C(9) atom. In the fifteenth H site, H(17,33) is bonded in a single-bond geometry to one C(9) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one C(10) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Cd(1) and one C(10) atom. Linkers: 2 NCCCN. Metal clusters: 4 [Cd]. The MOF has largest included sphere 3.69 A, density 1.57 g/cm3, surface area 4791.49 m2/g, accessible volume 0.22 cm3/g