AgH3(CN)3CH2CH3 crystallizes in the monoclinic C2/c space group. The structure consists of sixteen 02329_fluka molecules and sixteen 02329_fluka molecules inside a AgH3(CN)3 framework. In the AgH3(CN)3 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(4), and one N(6) atom. The Ag(1)-N(1) bond length is 2.32 Å. The Ag(1)-N(4) bond length is 2.18 Å. The Ag(1)-N(6) bond length is 2.16 Å. In the second Ag site, Ag(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one N(5) atom. The Ag(2)-N(2) bond length is 2.15 Å. The Ag(2)-N(3) bond length is 2.21 Å. The Ag(2)-N(5) bond length is 2.30 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one N(3) atom. The C(1)-C(3) bond length is 1.49 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(3) bond length is 1.36 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(1) atom. The C(2)-N(2) bond length is 1.34 Å. The C(2)-N(3) bond length is 1.35 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted water-like geometry to one C(1) and two equivalent H(2,3) atoms. Both C(3)-H(2,3) bond lengths are 1.10 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(8), one N(4), and one N(6) atom. The C(6)-C(8) bond length is 1.49 Å. The C(6)-N(4) bond length is 1.34 Å. The C(6)-N(6) bond length is 1.36 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(9) atom. The C(7)-N(5) bond length is 1.33 Å. The C(7)-N(6) bond length is 1.35 Å. The C(7)-H(9) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted water-like geometry to one C(6), one H(10), and one H(11) atom. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(11) bond length is 1.10 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Ag(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.38 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Ag(2), one C(2), and one N(1) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(1), and one C(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(6), and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one Ag(2), one C(7), and one N(4) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(6), and one C(7) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(8) atom. Linkers: 4 CCCC1=NN=C[N]1 ,3 CCCC1=[N]=CN=N1 ,1 CCCC1=N[N]C=N1. Metal clusters: 2 [N]1[N][Ag]2N=N[Ag][N][N][Ag]2N=N[Ag]1. The MOF has largest included sphere 3.51 A, density 2.05 g/cm3, surface area 3704.12 m2/g, accessible volume 0.19 cm3/g