SmC24H11S(N2O3)2(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a SmC24H11S(N2O3)2 framework. In the SmC24H11S(N2O3)2 framework, Sm(1) is bonded in a 9-coordinate geometry to one N(1), one N(2), one O(1), one O(3), one O(4), one O(5), one O(6), and two equivalent O(2) atoms. The Sm(1)-N(1) bond length is 2.68 Å. The Sm(1)-N(2) bond length is 2.63 Å. The Sm(1)-O(1) bond length is 2.34 Å. The Sm(1)-O(3) bond length is 2.54 Å. The Sm(1)-O(4) bond length is 2.45 Å. The Sm(1)-O(5) bond length is 2.54 Å. The Sm(1)-O(6) bond length is 2.42 Å. There is one shorter (2.37 Å) and one longer (2.64 Å) Sm(1)-O(2) bond length. There are twenty-four inequivalent C sites. In the first C site, C(19) is bonded in a distorted trigonal planar geometry to one C(20), one N(3), and one N(4) atom. The C(19)-C(20) bond length is 1.46 Å. The C(19)-N(3) bond length is 1.38 Å. The C(19)-N(4) bond length is 1.34 Å. In the second C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(22) atom. The C(20)-C(21) bond length is 1.41 Å. The C(20)-C(22) bond length is 1.41 Å. In the third C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(10) atom. The C(21)-H(10) bond length is 1.09 Å. In the fourth C site, C(22) is bonded in a distorted single-bond geometry to one C(20), one C(24), and one H(11) atom. The C(22)-C(24) bond length is 1.39 Å. The C(22)-H(11) bond length is 1.09 Å. In the fifth C site, C(23) is bonded in a distorted single-bond geometry to one C(25) and one H(12) atom. The C(23)-C(25) bond length is 1.40 Å. The C(23)-H(12) bond length is 1.09 Å. In the sixth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(22), one C(25), and one H(13) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-H(13) bond length is 1.09 Å. In the seventh C site, C(25) is bonded in a trigonal planar geometry to one C(23), one C(24), and one C(26) atom. The C(25)-C(26) bond length is 1.50 Å. In the eighth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(2), and one O(3) atom. The C(26)-O(2) bond length is 1.29 Å. The C(26)-O(3) bond length is 1.26 Å. In the ninth C site, C(1) is bonded in a bent 120 degrees geometry to one C(6), one O(4), and one O(5) atom. The C(1)-C(6) bond length is 1.47 Å. The C(1)-O(4) bond length is 1.30 Å. The C(1)-O(5) bond length is 1.26 Å. In the tenth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(4), one C(7), and one N(1) atom. The C(2)-C(4) bond length is 1.45 Å. The C(2)-C(7) bond length is 1.43 Å. The C(2)-N(1) bond length is 1.36 Å. In the eleventh C site, C(3) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-H(1) bond length is 1.09 Å. In the twelfth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(2), one C(9), and one N(2) atom. The C(4)-C(9) bond length is 1.43 Å. The C(4)-N(2) bond length is 1.36 Å. In the thirteenth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2) atom. The C(5)-N(2) bond length is 1.33 Å. The C(5)-H(2) bond length is 1.09 Å. In the fourteenth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(11), and one S(1) atom. The C(6)-C(11) bond length is 1.39 Å. The C(6)-S(1) bond length is 1.72 Å. In the fifteenth C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(2) atom. The C(7)-C(12) bond length is 1.42 Å. The C(7)-C(13) bond length is 1.41 Å. In the sixteenth C site, C(9) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(4) atom. The C(9)-C(14) bond length is 1.43 Å. The C(9)-C(15) bond length is 1.41 Å. In the seventeenth C site, C(11) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(11)-H(5) bond length is 1.09 Å. In the eighteenth C site, C(12) is bonded in a distorted single-bond geometry to one C(14), one C(7), and one N(3) atom. The C(12)-C(14) bond length is 1.40 Å. The C(12)-N(3) bond length is 1.37 Å. In the nineteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(13)-H(6) bond length is 1.09 Å. In the twentieth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(12), one C(9), and one N(4) atom. The C(14)-N(4) bond length is 1.37 Å. In the twenty-first C site, C(15) is bonded in a distorted single-bond geometry to one C(9) and one H(7) atom. The C(15)-H(7) bond length is 1.09 Å. In the twenty-second C site, C(16) is bonded in a trigonal planar geometry to one C(17), one C(18), and one S(1) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-C(18) bond length is 1.48 Å. The C(16)-S(1) bond length is 1.72 Å. In the twenty-third C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(8) atom. The C(17)-H(8) bond length is 1.09 Å. In the twenty-fourth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(1), and one O(6) atom. The C(18)-O(1) bond length is 1.27 Å. The C(18)-O(6) bond length is 1.28 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Sm(1), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Sm(1), one C(4), and one C(5) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(12), one C(19), and one H(9) atom. The N(3)-H(9) bond length is 1.04 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one C(14) and one C(19) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(9) is bonded in a distorted single-bond geometry to one N(3) and one O(4) atom. The H(9)-O(4) bond length is 1.71 Å. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(24) atom. S(1) is bonded in an L-shaped geometry to one C(16) and one C(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Sm(1) and one C(18) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Sm(1) and one C(26) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sm(1) and one C(26) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Sm(1), one C(1), and one H(9) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Sm(1) and one C(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Sm(1) and one C(18) atom. Linkers: 4 [O]C(=O)c1ccc(-c2nc3c4cccnc4c4ncccc4c3[nH]2)cc1 ,4 [O]C(=O)c1ccc(C([O])=O)s1. Metal clusters: 2 [C]1O[Sm]234(O1)O[C]O[Sm]1(O[C]O1)(O[C]O2)(O[C]O3)O[C]O4. The MOF has largest included sphere 3.78 A, density 1.73 g/cm3, surface area 3419.00 m2/g, accessible volume 0.20 cm3/g