CuC12N6H10Br(CH)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four CuC12N6H10Br clusters. In each CuC12N6H10Br cluster, Cu(1) is bonded to one N(3), one N(4), and two equivalent Br(1) atoms to form distorted edge-sharing CuBr2N2 tetrahedra. The Cu(1)-N(3) bond length is 1.99 Å. The Cu(1)-N(4) bond length is 1.99 Å. There is one shorter (2.47 Å) and one longer (2.55 Å) Cu(1)-Br(1) bond length. There are twelve inequivalent C sites. In the first C site, C(7) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one N(6) atom. The C(7)-C(12) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.43 Å. The C(7)-N(6) bond length is 1.36 Å. In the second C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one N(4) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-N(4) bond length is 1.37 Å. In the third C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(9)-H(5) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-H(6) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(7) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-H(7) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(7), and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(10), and one H(9) atom. The C(13)-N(1) bond length is 1.45 Å. The C(13)-H(10) bond length is 1.10 Å. The C(13)-H(9) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(5), one H(11), and one H(12) atom. The C(14)-N(5) bond length is 1.46 Å. The C(14)-H(11) bond length is 1.10 Å. The C(14)-H(12) bond length is 1.10 Å. In the ninth C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one N(3) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-N(3) bond length is 1.38 Å. In the tenth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one N(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(1) bond length is 1.37 Å. In the eleventh C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the twelfth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(13), one C(2), and one N(2) atom. The N(1)-N(2) bond length is 1.35 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.32 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(8), and one N(5) atom. The N(4)-N(5) bond length is 1.34 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(14), one N(4), and one N(6) atom. The N(5)-N(6) bond length is 1.33 Å. In the sixth N site, N(6) is bonded in a water-like geometry to one C(7) and one N(5) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. Br(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 4 c1ccc2nn(CCn3nnc4ccccc43)nc2c1. Metal clusters: 2 Br[Cu][Cu]Br. The MOF has largest included sphere 2.08 A, density 1.84 g/cm3, surface area 4127.77 m2/g, accessible volume 0.15 cm3/g