ZnC14H14(N5O4)2(CH)2(CH3)4 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, eight 02329_fluka molecules, and two ZnC14H14(N5O4)2 clusters. In each ZnC14H14(N5O4)2 cluster, Zn(1) is bonded in a distorted trigonal bipyramidal geometry to one N(10), one O(1), one O(3), one O(5), and one O(8) atom. The Zn(1)-N(10) bond length is 2.07 Å. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(3) bond length is 2.08 Å. The Zn(1)-O(5) bond length is 1.98 Å. The Zn(1)-O(8) bond length is 2.44 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. The C(1)-N(1) bond length is 1.39 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-N(3) bond length is 1.34 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one N(4) atom. The C(2)-C(3) bond length is 1.46 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-N(4) bond length is 1.33 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one N(5) atom. The C(3)-C(4) bond length is 1.46 Å. The C(3)-N(5) bond length is 1.34 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one O(4) atom. The C(4)-N(1) bond length is 1.40 Å. The C(4)-O(4) bond length is 1.24 Å. In the fifth C site, C(5) is bonded in a tetrahedral geometry to one N(1), one H(1), one H(2), and one H(3) atom. The C(5)-N(1) bond length is 1.46 Å. The C(5)-H(1) bond length is 1.09 Å. The C(5)-H(2) bond length is 1.10 Å. The C(5)-H(3) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one N(3) and one H(5) atom. The C(6)-N(3) bond length is 1.45 Å. The C(6)-H(5) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(7)-O(1) bond length is 1.30 Å. The C(7)-O(2) bond length is 1.25 Å. In the eighth C site, C(11) is bonded in a trigonal planar geometry to one N(6), one N(7), and one N(8) atom. The C(11)-N(6) bond length is 1.39 Å. The C(11)-N(7) bond length is 1.33 Å. The C(11)-N(8) bond length is 1.34 Å. In the ninth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one N(7), and one N(9) atom. The C(12)-C(13) bond length is 1.44 Å. The C(12)-N(7) bond length is 1.35 Å. The C(12)-N(9) bond length is 1.32 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one N(10) atom. The C(13)-C(14) bond length is 1.45 Å. The C(13)-N(10) bond length is 1.35 Å. In the eleventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(6), and one O(8) atom. The C(14)-N(6) bond length is 1.39 Å. The C(14)-O(8) bond length is 1.25 Å. In the twelfth C site, C(15) is bonded in a tetrahedral geometry to one N(6), one H(15), one H(16), and one H(17) atom. The C(15)-N(6) bond length is 1.47 Å. The C(15)-H(15) bond length is 1.10 Å. The C(15)-H(16) bond length is 1.09 Å. The C(15)-H(17) bond length is 1.10 Å. In the thirteenth C site, C(16) is bonded in a distorted water-like geometry to one N(8) and one H(19) atom. The C(16)-N(8) bond length is 1.46 Å. The C(16)-H(19) bond length is 1.10 Å. In the fourteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(17)-O(5) bond length is 1.30 Å. The C(17)-O(6) bond length is 1.24 Å. There are ten inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(5) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(6), and one H(4) atom. The N(3)-H(4) bond length is 1.02 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(2), one H(13), and one H(14) atom. The N(4)-H(13) bond length is 1.03 Å. The N(4)-H(14) bond length is 1.03 Å. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(3) and one O(3) atom. The N(5)-O(3) bond length is 1.31 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(15) atom. In the seventh N site, N(7) is bonded in a bent 120 degrees geometry to one C(11) and one C(12) atom. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one C(11), one C(16), and one H(18) atom. The N(8)-H(18) bond length is 1.02 Å. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(12), one H(27), and one H(28) atom. The N(9)-H(27) bond length is 1.02 Å. The N(9)-H(28) bond length is 1.03 Å. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one O(7) atom. The N(10)-O(7) bond length is 1.27 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one N(8) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(27) is bonded in a single-bond geometry to one N(9) atom. In the fourteenth H site, H(28) is bonded in a single-bond geometry to one N(9) atom. There are eight inequivalent O sites. In the first O site, O(6) is bonded in a single-bond geometry to one C(17) atom. In the second O site, O(7) is bonded in a single-bond geometry to one N(10) atom. In the third O site, O(8) is bonded in a distorted single-bond geometry to one Zn(1) and one C(14) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the fifth O site, O(2) is bonded in a single-bond geometry to one C(7) atom. In the sixth O site, O(3) is bonded in a distorted water-like geometry to one Zn(1) and one N(5) atom. In the seventh O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the eighth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. Linkers: 2 CC(C)[C@H](N[C]1N=C(N)/C(=N\[O])C(=O)N1C)C([O])=O. Metal clusters: 2 [Zn]. The MOF has largest included sphere 3.31 A, density 1.42 g/cm3, surface area 4790.08 m2/g, accessible volume 0.20 cm3/g