UC7NH6SO8(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a UC7NH6SO8 framework. In the UC7NH6SO8 framework, U(1) is bonded in a distorted pentagonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. The U(1)-O(1) bond length is 1.80 Å. The U(1)-O(2) bond length is 1.81 Å. The U(1)-O(3) bond length is 2.36 Å. The U(1)-O(4) bond length is 2.35 Å. The U(1)-O(5) bond length is 2.45 Å. The U(1)-O(6) bond length is 2.41 Å. The U(1)-O(8) bond length is 2.38 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(3) bond length is 1.28 Å. The C(1)-O(4) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one S(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-S(1) bond length is 1.78 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(7) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-N(1) bond length is 1.34 Å. The C(8)-H(7) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(8), one N(1), and one H(8) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-H(8) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one C(8), one C(9), and one H(2) atom. The N(1)-H(2) bond length is 1.62 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(8) atom. The H(1)-O(8) bond length is 0.99 Å. In the second H site, H(2) is bonded in a distorted linear geometry to one N(1) and one O(8) atom. The H(2)-O(8) bond length is 1.04 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one O(5), one O(6), and one O(7) atom. The S(1)-O(5) bond length is 1.48 Å. The S(1)-O(6) bond length is 1.49 Å. The S(1)-O(7) bond length is 1.46 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one U(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one U(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one U(1) and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one U(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one U(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one U(1), one H(1), and one H(2) atom. Linkers: 4 [O]C(=O)c1ccccc1S([O])([O])[O]. Metal clusters: 4 [U]. The MOF has largest included sphere 1.96 A, density 2.80 g/cm3, surface area 2544.86 m2/g, accessible volume 0.08 cm3/g