Cd2C26H20(N2O3)3(CH)2 crystallizes in the monoclinic C2/c space group. The structure consists of eight 02329_fluka molecules inside a Cd2C26H20(N2O3)3 framework. In the Cd2C26H20(N2O3)3 framework, Cd(1) is bonded to one N(1), one N(3), one O(1), two equivalent O(2), and two equivalent O(3) atoms to form a mixture of face and edge-sharing CdN2O5 pentagonal bipyramids. The Cd(1)-N(1) bond length is 2.35 Å. The Cd(1)-N(3) bond length is 2.28 Å. The Cd(1)-O(1) bond length is 2.42 Å. There is one shorter (2.35 Å) and one longer (2.49 Å) Cd(1)-O(2) bond length. There is one shorter (2.39 Å) and one longer (2.48 Å) Cd(1)-O(3) bond length. There are thirteen inequivalent C sites. In the first C site, C(9) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(4) atom. The C(9)-N(2) bond length is 1.36 Å. The C(9)-N(3) bond length is 1.33 Å. The C(9)-H(4) bond length is 1.09 Å. In the second C site, C(10) is bonded in a distorted trigonal planar geometry to one C(13), one N(3), and one H(5) atom. The C(10)-C(13) bond length is 1.38 Å. The C(10)-N(3) bond length is 1.38 Å. The C(10)-H(5) bond length is 1.08 Å. In the third C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(2), and one O(4) atom. The C(11)-C(1) bond length is 1.52 Å. The C(11)-O(2) bond length is 1.30 Å. The C(11)-O(4) bond length is 1.24 Å. In the fourth C site, C(12) is bonded in a distorted single-bond geometry to one C(6) and one H(6) atom. The C(12)-C(6) bond length is 1.40 Å. The C(12)-H(6) bond length is 1.09 Å. In the fifth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(7) atom. The C(13)-N(2) bond length is 1.39 Å. The C(13)-H(7) bond length is 1.08 Å. In the sixth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one H(10), one H(8), and one H(9) atom. The C(14)-C(3) bond length is 1.50 Å. The C(14)-H(10) bond length is 1.10 Å. The C(14)-H(8) bond length is 1.10 Å. The C(14)-H(9) bond length is 1.10 Å. In the seventh C site, C(1) is bonded in a distorted trigonal planar geometry to one C(11), one C(2), and one N(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.34 Å. In the eighth C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the ninth C site, C(3) is bonded in a trigonal planar geometry to one C(14), one C(5), and one C(8) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-C(8) bond length is 1.41 Å. In the tenth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(3), and one O(5) atom. The C(4)-C(6) bond length is 1.52 Å. The C(4)-O(3) bond length is 1.28 Å. The C(4)-O(5) bond length is 1.26 Å. In the eleventh C site, C(5) is bonded in a distorted single-bond geometry to one C(3), one C(8), and one H(2) atom. The C(5)-C(8) bond length is 1.39 Å. The C(5)-H(2) bond length is 1.09 Å. In the twelfth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(12), one C(4), and one N(1) atom. The C(6)-N(1) bond length is 1.34 Å. In the thirteenth C site, C(8) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one N(2) atom. The C(8)-N(2) bond length is 1.43 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(13), one C(8), and one C(9) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one C(9) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(11) is bonded in a distorted single-bond geometry to one O(1) and one O(5) atom. The H(11)-O(1) bond length is 1.01 Å. The H(11)-O(5) bond length is 1.64 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent Cd(1) and two equivalent H(11) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one C(11) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(4) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one C(4) and one H(11) atom. Linkers: 2 Cc1cc(-n2ccnc2)c(C)cc1-n1ccnc1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 1.96 A, density 1.90 g/cm3, surface area 3733.48 m2/g, accessible volume 0.12 cm3/g