CoC14H12(NO2)2(CH)3CH2C2O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, four 02329_fluka molecules, four dimethyl ether molecules, and two CoC14H12(NO2)2 clusters. In each CoC14H12(NO2)2 cluster, Co(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(3), one O(6), and one O(8) atom. The Co(1)-N(1) bond length is 2.20 Å. The Co(1)-O(1) bond length is 2.03 Å. The Co(1)-O(3) bond length is 2.00 Å. The Co(1)-O(6) bond length is 2.05 Å. The Co(1)-O(8) bond length is 2.03 Å. There are fourteen inequivalent C sites. In the first C site, C(29,30) is bonded in a distorted bent 120 degrees geometry to one C(31), one N(1), and one H(17) atom. The C(29,30)-C(31) bond length is 1.37 Å. The C(29,30)-N(1) bond length is 1.38 Å. The C(29,30)-H(17) bond length is 1.08 Å. In the second C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(29,30); one N(3); and one H(19,20) atom. The C(31)-N(3) bond length is 1.38 Å. The C(31)-H(19,20) bond length is 1.08 Å. In the third C site, C(33) is bonded in a distorted trigonal planar geometry to one C(35), one N(1), and one N(3) atom. The C(33)-C(35) bond length is 1.48 Å. The C(33)-N(1) bond length is 1.34 Å. The C(33)-N(3) bond length is 1.37 Å. In the fourth C site, C(35) is bonded in a distorted trigonal non-coplanar geometry to one C(33); one H(21,22); one H(23,24); and one H(25,26) atom. The C(35)-H(21,22) bond length is 1.09 Å. The C(35)-H(23,24) bond length is 1.10 Å. The C(35)-H(25,26) bond length is 1.10 Å. In the fifth C site, C(37,38) is bonded in a distorted trigonal non-coplanar geometry to one N(3) and two equivalent H(27,28,29,30) atoms. The C(37,38)-N(3) bond length is 1.46 Å. Both C(37,38)-H(27,28,29,30) bond lengths are 1.10 Å. In the sixth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.28 Å. In the seventh C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(5) atom. The C(3)-C(13) bond length is 1.40 Å. The C(3)-C(5) bond length is 1.40 Å. In the eighth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(3); one C(7,8); and one H(1,2) atom. The C(5)-C(7,8) bond length is 1.39 Å. The C(5)-H(1,2) bond length is 1.09 Å. In the ninth C site, C(7,8) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(7,8)-H(3) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(3) and one H(7,8) atom. The C(13)-H(7,8) bond length is 1.09 Å. In the eleventh C site, C(19,20) is bonded in a distorted single-bond geometry to one C(21,22) and one H(11,12) atom. The C(19,20)-C(21,22) bond length is 1.40 Å. The C(19,20)-H(11,12) bond length is 1.09 Å. In the twelfth C site, C(21,22) is bonded in a trigonal planar geometry to one C(19,20); one C(23,24); and one C(27,28) atom. The C(21,22)-C(23,24) bond length is 1.40 Å. The C(21,22)-C(27,28) bond length is 1.49 Å. In the thirteenth C site, C(23,24) is bonded in a distorted single-bond geometry to one C(21,22) and one H(13,14) atom. The C(23,24)-H(13,14) bond length is 1.09 Å. In the fourteenth C site, C(27,28) is bonded in a bent 120 degrees geometry to one C(21,22); one O(5); and one O(7) atom. The C(27,28)-O(5) bond length is 1.28 Å. The C(27,28)-O(7) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Co(1); one C(29,30); and one C(33) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(31); one C(33); and one C(37,38) atom. There are eleven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(7,8) atom. In the third H site, H(7,8) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(11,12) is bonded in a single-bond geometry to one C(19,20) atom. In the fifth H site, H(13,14) is bonded in a single-bond geometry to one C(23,24) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(29,30) atom. In the seventh H site, H(19,20) is bonded in a single-bond geometry to one C(31) atom. In the eighth H site, H(21,22) is bonded in a single-bond geometry to one C(35) atom. In the ninth H site, H(23,24) is bonded in a single-bond geometry to one C(35) atom. In the tenth H site, H(25,26) is bonded in a single-bond geometry to one C(35) atom. In the eleventh H site, H(27,28,29,30) is bonded in a single-bond geometry to one C(37,38) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to one Co(1) and one C(27,28) atom. The O(6)-C(27,28) bond length is 1.28 Å. In the fourth O site, O(8) is bonded in a bent 120 degrees geometry to one Co(1) and one C(27,28) atom. The O(8)-C(27,28) bond length is 1.28 Å. Linkers: 4 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,2 Cc1nccn1CCCCn1ccnc1C. Metal clusters: 2 [C]1O[Co]234O[C]O[Co]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 4.66 A, density 1.39 g/cm3, surface area 4603.72 m2/g, accessible volume 0.24 cm3/g