ZnC12H14(NO3)2(CH2)2(CH)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four 02329_fluka molecules, and two ZnC12H14(NO3)2 clusters. In each ZnC12H14(NO3)2 cluster, Zn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(3) atoms. Both Zn(1)-N(1) bond lengths are 2.15 Å. Both Zn(1)-O(1) bond lengths are 2.14 Å. Both Zn(1)-O(3) bond lengths are 2.17 Å. There are six inequivalent C sites. In the first C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(6) atom. The C(5)-C(1) bond length is 1.51 Å. The C(5)-C(4) bond length is 1.40 Å. The C(5)-C(6) bond length is 1.40 Å. In the second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(10) atom. The C(8)-N(1) bond length is 1.34 Å. The C(8)-H(10) bond length is 1.09 Å. In the third C site, C(1) is bonded in a water-like geometry to one C(5) and two equivalent H(1,2) atoms. Both C(1)-H(1,2) bond lengths are 1.10 Å. In the fourth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(3)-O(1) bond length is 1.27 Å. The C(3)-O(2) bond length is 1.28 Å. In the fifth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(7) atom. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(7) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(8) atom. The C(6)-H(8) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(4), and one C(8) atom. There are six inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(5) is bonded in a single-bond geometry to one O(3) atom. The H(5)-O(3) bond length is 1.00 Å. In the fourth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. The H(6)-O(3) bond length is 1.00 Å. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Zn(1), one H(5), and one H(6) atom. Linkers: 1 O.O.[CH]C(=O)O[Zn](OC(=O)CCc1cccnc1)(N1[CH]C=CC(CCC([O])=O)=C1)N1[CH]C=CC(CCC([O])=O)=C1 ,2 O.O.[O]C(=O)C[CH]C1=[C]C=CN([Zn](OC(=O)CCc2cccnc2)(OC(=O)CCc2cccnc2)N2[CH]C(CCC([O])=O)=CC=C2)[CH]1 ,2 O.O.[CH]CC1=CC=CN([Zn@](OC(=O)CC/C([CH])=C/[N])(OC(=O)CCc2cccnc2)N2[CH]C(CCC([O])=O)=CC=C2)[CH]1 ,1 O.O.[O]C(=O)CCC1=CC=CN([Zn](OC(=O)CCc2cccnc2)(OC(=O)CCc2cccnc2)N2[CH]C(CCC([O])=O)=CC=C2)[CH]1 ,1 O.O.[CH]C(=O)O[Zn](OC(=O)CCc1cccnc1)(N1[CH]C(CCC([O])=O)=CC=C1)N1[CH]C(CCC([O])=O)=CC=C1. Metal clusters: 1 O.O.O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 1.79 A, density 1.68 g/cm3, surface area 4503.61 m2/g, accessible volume 0.13 cm3/g