NiC16H24(NO)4(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two NiC16H24(NO)4 clusters. In each NiC16H24(NO)4 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent O(1) atoms. Both Ni(1)-N(1) bond lengths are 2.09 Å. Both Ni(1)-N(3) bond lengths are 2.09 Å. Both Ni(1)-O(1) bond lengths are 2.09 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1); one H(3); and one H(5,6) atom. The C(1)-N(1) bond length is 1.47 Å. The C(1)-H(3) bond length is 1.11 Å. The C(1)-H(5,6) bond length is 1.10 Å. In the second C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(7), and one H(9) atom. The C(3)-N(3) bond length is 1.47 Å. The C(3)-H(7) bond length is 1.10 Å. The C(3)-H(9) bond length is 1.10 Å. In the third C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(13), and one H(15) atom. The C(5)-N(3) bond length is 1.47 Å. The C(5)-H(13) bond length is 1.10 Å. The C(5)-H(15) bond length is 1.11 Å. In the fourth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(1); one H(21,22); and one H(23,24) atom. The C(9)-N(1) bond length is 1.47 Å. The C(9)-H(21,22) bond length is 1.11 Å. The C(9)-H(23,24) bond length is 1.10 Å. In the fifth C site, C(11) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-C(15) bond length is 1.40 Å. The C(11)-C(17) bond length is 1.51 Å. In the sixth C site, C(13) is bonded in a distorted single-bond geometry to one C(11) and one H(25,27) atom. The C(13)-H(25,27) bond length is 1.09 Å. In the seventh C site, C(15) is bonded in a distorted single-bond geometry to one C(11) and one H(25,27) atom. The C(15)-H(25,27) bond length is 1.09 Å. In the eighth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(1), and one O(3) atom. The C(17)-O(1) bond length is 1.28 Å. The C(17)-O(3) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Ni(1), one C(1), one C(9), and one H(1) atom. The N(1)-H(1) bond length is 1.04 Å. In the second N site, N(3) is bonded to one Ni(1), one C(3), one C(5), and one H(11) atom to form distorted corner-sharing NNiHC2 tetrahedra. The N(3)-H(11) bond length is 1.03 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(21,22) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(23,24) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(25,27) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(17) atom. In the second O site, O(3) is bonded in a single-bond geometry to one C(17) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)cc1 ,2 C1CNCCNCCCNCCNC1. Metal clusters: 1 [Ni] ,1 [NH][Ni]([NH])([NH])([NH])(O[C]=O)O[C]=O. The MOF has largest included sphere 2.81 A, density 1.43 g/cm3, surface area 4640.20 m2/g, accessible volume 0.18 cm3/g