ZnC7H5(N2S)2CH crystallizes in the orthorhombic Pna2_1 space group. The structure consists of four 02329_fluka molecules inside a ZnC7H5(N2S)2 framework. In the ZnC7H5(N2S)2 framework, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one N(4), and one S(1) atom. The Zn(1)-N(1) bond length is 2.10 Å. The Zn(1)-N(3) bond length is 2.07 Å. The Zn(1)-N(4) bond length is 2.03 Å. The Zn(1)-S(1) bond length is 2.35 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-S(1) bond length is 1.74 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(3), one N(4), and one S(2) atom. The C(5)-N(3) bond length is 1.38 Å. The C(5)-N(4) bond length is 1.38 Å. The C(5)-S(2) bond length is 1.69 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(4) atom. The C(6)-N(4) bond length is 1.34 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(6) atom. The C(8)-N(3) bond length is 1.34 Å. The C(8)-H(6) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(5), and one C(8) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(5), and one C(6) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(5) atom. Linkers: 4 S=C1N=C[CH]C=N1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 2.18 A, density 1.92 g/cm3, surface area 3842.49 m2/g, accessible volume 0.09 cm3/g