AuC12PH11ClAuC7PH6Cl(CH)7(CH2)5 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of twenty-eight 02329_fluka molecules, twenty 02329_fluka molecules, four AuC12PH11Cl clusters, and four AuC7PH6Cl clusters. In each AuC12PH11Cl cluster, Au(1) is bonded in a linear geometry to one P(1) and one Cl(1) atom. The Au(1)-P(1) bond length is 2.25 Å. The Au(1)-Cl(1) bond length is 2.32 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one P(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-P(1) bond length is 1.82 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(3) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(8), and one P(1) atom. The C(7)-C(12) bond length is 1.40 Å. The C(7)-C(8) bond length is 1.40 Å. The C(7)-P(1) bond length is 1.82 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(7) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(8) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(8) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(9) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(9) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(7), and one H(10) atom. The C(12)-H(10) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted water-like geometry to one P(1), one H(11), and one H(12) atom. The C(13)-P(1) bond length is 1.82 Å. The C(13)-H(11) bond length is 1.10 Å. The C(13)-H(12) bond length is 1.10 Å. P(1) is bonded in a tetrahedral geometry to one Au(1), one C(1), one C(13), and one C(7) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(13) atom. Cl(1) is bonded in a single-bond geometry to one Au(1) atom. In each AuC7PH6Cl cluster, Au(2) is bonded in a linear geometry to one P(2) and one Cl(2) atom. The Au(2)-P(2) bond length is 2.25 Å. The Au(2)-Cl(2) bond length is 2.31 Å. There are seven inequivalent C sites. In the first C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(25) atom. The C(21)-C(20) bond length is 1.40 Å. The C(21)-H(25) bond length is 1.09 Å. In the second C site, C(25) is bonded in a distorted single-bond geometry to one C(20) and one H(29) atom. The C(25)-C(20) bond length is 1.40 Å. The C(25)-H(29) bond length is 1.09 Å. In the third C site, C(26) is bonded in a trigonal planar geometry to one C(27), one C(31), and one P(2) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-C(31) bond length is 1.40 Å. The C(26)-P(2) bond length is 1.81 Å. In the fourth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(30) atom. The C(27)-H(30) bond length is 1.09 Å. In the fifth C site, C(31) is bonded in a distorted single-bond geometry to one C(26) and one H(34) atom. The C(31)-H(34) bond length is 1.09 Å. In the sixth C site, C(19) is bonded in a distorted water-like geometry to one P(2), one H(23), and one H(24) atom. The C(19)-P(2) bond length is 1.83 Å. The C(19)-H(23) bond length is 1.10 Å. The C(19)-H(24) bond length is 1.10 Å. In the seventh C site, C(20) is bonded in a trigonal planar geometry to one C(21), one C(25), and one P(2) atom. The C(20)-P(2) bond length is 1.82 Å. P(2) is bonded in a tetrahedral geometry to one Au(2), one C(19), one C(20), and one C(26) atom. There are six inequivalent H sites. In the first H site, H(29) is bonded in a single-bond geometry to one C(25) atom. In the second H site, H(30) is bonded in a single-bond geometry to one C(27) atom. In the third H site, H(34) is bonded in a single-bond geometry to one C(31) atom. In the fourth H site, H(23) is bonded in a single-bond geometry to one C(19) atom. In the fifth H site, H(24) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(25) is bonded in a single-bond geometry to one C(21) atom. Cl(2) is bonded in a single-bond geometry to one Au(2) atom. Linkers: 1 [c]1ccc(P(CCCCCCCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1 ,1 c1ccc(P(CCCCCCCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1 ,1 [P][CH]C[CH]CCCCP(c1c[c][c]cc1)c1ccccc1. Metal clusters: . The MOF has largest included sphere 3.67 A, density 1.99 g/cm3, surface area 3838.85 m2/g, accessible volume 0.15 cm3/g