CH2CuC15N6H12O5F2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two CuC15N6H12O5F2 clusters. In each CuC15N6H12O5F2 cluster, there are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(21), one O(1), one O(12), and one O(13) atom. The Cu(1)-N(1) bond length is 2.20 Å. The Cu(1)-N(21) bond length is 1.97 Å. The Cu(1)-O(1) bond length is 2.00 Å. The Cu(1)-O(12) bond length is 2.10 Å. The Cu(1)-O(13) bond length is 1.95 Å. In the second Cu site, Cu(2) is bonded in a distorted trigonal bipyramidal geometry to one N(2), one N(22), one O(11), one O(14), and one O(2) atom. The Cu(2)-N(2) bond length is 2.20 Å. The Cu(2)-N(22) bond length is 1.97 Å. The Cu(2)-O(11) bond length is 2.10 Å. The Cu(2)-O(14) bond length is 1.95 Å. The Cu(2)-O(2) bond length is 2.00 Å. In the third Cu site, Cu(3,4) is bonded in a distorted trigonal bipyramidal geometry to one N(23), one N(3), one O(15), one O(3), and one O(9) atom. The Cu(3,4)-N(23) bond length is 1.97 Å. The Cu(3,4)-N(3) bond length is 2.20 Å. The Cu(3,4)-O(15) bond length is 1.95 Å. The Cu(3,4)-O(3) bond length is 2.00 Å. The Cu(3,4)-O(9) bond length is 2.10 Å. There are thirty-four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1); one N(5,6,7,8); and one H(5,6,7,8) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-N(5,6,7,8) bond length is 1.33 Å. The C(1)-H(5,6,7,8) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2); one N(5,6,7,8); and one H(5,6,7,8) atom. The C(2)-N(2) bond length is 1.37 Å. The C(2)-N(5,6,7,8) bond length is 1.33 Å. The C(2)-H(5,6,7,8) bond length is 1.08 Å. In the third C site, C(3,4) is bonded in a trigonal planar geometry to one N(3); one N(5,6,7,8); and one H(5,6,7,8) atom. The C(3,4)-N(3) bond length is 1.37 Å. The C(3,4)-N(5,6,7,8) bond length is 1.33 Å. The C(3,4)-H(5,6,7,8) bond length is 1.08 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one N(1); one N(9,10,11,12); and one H(9,10,11,12) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-N(9,10,11,12) bond length is 1.35 Å. The C(5)-H(9,10,11,12) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one N(2); one N(9,10,11,12); and one H(9,10,11,12) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-N(9,10,11,12) bond length is 1.35 Å. The C(6)-H(9,10,11,12) bond length is 1.09 Å. In the sixth C site, C(7,8) is bonded in a trigonal planar geometry to one N(3); one N(9,10,11,12); and one H(9,10,11,12) atom. The C(7,8)-N(3) bond length is 1.34 Å. The C(7,8)-N(9,10,11,12) bond length is 1.35 Å. The C(7,8)-H(9,10,11,12) bond length is 1.09 Å. In the seventh C site, C(9,10,11,12) is bonded in a distorted trigonal non-coplanar geometry to one N(9,10,11,12); one H(13,14,15,16); and one H(17,18,19,20) atom. The C(9,10,11,12)-N(9,10,11,12) bond length is 1.45 Å. The C(9,10,11,12)-H(13,14,15,16) bond length is 1.09 Å. The C(9,10,11,12)-H(17,18,19,20) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(29,32) and one O(17) atom. The C(13)-C(29,32) bond length is 1.53 Å. The C(13)-O(17) bond length is 1.41 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(30,31) and one O(18) atom. The C(14)-C(30,31) bond length is 1.53 Å. The C(14)-O(18) bond length is 1.41 Å. In the tenth C site, C(15) is bonded in a distorted single-bond geometry to one C(30,31) and one O(19) atom. The C(15)-C(30,31) bond length is 1.53 Å. The C(15)-O(19) bond length is 1.41 Å. In the eleventh C site, C(16) is bonded in a distorted single-bond geometry to one C(29,32) and one O(20) atom. The C(16)-C(29,32) bond length is 1.53 Å. The C(16)-O(20) bond length is 1.41 Å. In the twelfth C site, C(17,18,19,20) is bonded in a distorted trigonal non-coplanar geometry to one N(13); one H(21,22,23,24); and one H(25,26,27,28) atom. The C(17,18,19,20)-N(13) bond length is 1.45 Å. The C(17,18,19,20)-H(21,22,23,24) bond length is 1.10 Å. The C(17,18,19,20)-H(25,26,27,28) bond length is 1.09 Å. In the thirteenth C site, C(21) is bonded in a trigonal planar geometry to one N(13), one N(21), and one H(29) atom. The C(21)-N(13) bond length is 1.34 Å. The C(21)-N(21) bond length is 1.34 Å. The C(21)-H(29) bond length is 1.09 Å. In the fourteenth C site, C(22) is bonded in a trigonal planar geometry to one N(14,15,16); one N(22); and one H(30,31,32) atom. The C(22)-N(14,15,16) bond length is 1.34 Å. The C(22)-N(22) bond length is 1.34 Å. The C(22)-H(30,31,32) bond length is 1.09 Å. In the fifteenth C site, C(23,24) is bonded in a trigonal planar geometry to one N(14,15,16); one N(23); and one H(30,31,32) atom. The C(23,24)-N(14,15,16) bond length is 1.34 Å. The C(23,24)-N(23) bond length is 1.34 Å. The C(23,24)-H(30,31,32) bond length is 1.09 Å. In the sixteenth C site, C(25) is bonded in a trigonal planar geometry to one N(17), one N(21), and one H(33) atom. The C(25)-N(17) bond length is 1.33 Å. The C(25)-N(21) bond length is 1.37 Å. The C(25)-H(33) bond length is 1.08 Å. In the seventeenth C site, C(26) is bonded in a trigonal planar geometry to one N(18,19,20); one N(22); and one H(34,35,36) atom. The C(26)-N(18,19,20) bond length is 1.33 Å. The C(26)-N(22) bond length is 1.37 Å. The C(26)-H(34,35,36) bond length is 1.08 Å. In the eighteenth C site, C(27,28) is bonded in a trigonal planar geometry to one N(18,19,20); one N(23); and one H(34,35,36) atom. The C(27,28)-N(18,19,20) bond length is 1.33 Å. The C(27,28)-N(23) bond length is 1.37 Å. The C(27,28)-H(34,35,36) bond length is 1.08 Å. In the nineteenth C site, C(29,32) is bonded in a trigonal planar geometry to one C(13); one C(33,34,35); and one C(49,50,51,52) atom. The C(29,32)-C(33,34,35) bond length is 1.40 Å. The C(29,32)-C(49,50,51,52) bond length is 1.40 Å. In the twentieth C site, C(30,31) is bonded in a trigonal planar geometry to one C(14); one C(33,34,35); and one C(49,50,51,52) atom. The C(30,31)-C(33,34,35) bond length is 1.40 Å. The C(30,31)-C(49,50,51,52) bond length is 1.40 Å. In the twenty-first C site, C(33,34,35) is bonded in a distorted single-bond geometry to one C(29,32); one C(37,38,39,40); and one F(1,2,3,4) atom. The C(33,34,35)-C(37,38,39,40) bond length is 1.39 Å. The C(33,34,35)-F(1,2,3,4) bond length is 1.37 Å. In the twenty-second C site, C(36) is bonded in a distorted single-bond geometry to one C(29,32); one C(37,38,39,40); and one F(1,2,3,4) atom. The C(36)-C(29,32) bond length is 1.40 Å. The C(36)-C(37,38,39,40) bond length is 1.39 Å. The C(36)-F(1,2,3,4) bond length is 1.37 Å. In the twenty-third C site, C(37,38,39,40) is bonded in a distorted single-bond geometry to one C(33,34,35); one C(41,42,43,44); and one H(37,38,39,40) atom. The C(37,38,39,40)-C(41,42,43,44) bond length is 1.39 Å. The C(37,38,39,40)-H(37,38,39,40) bond length is 1.09 Å. In the twenty-fourth C site, C(41,42,43,44) is bonded in a distorted single-bond geometry to one C(37,38,39,40); one C(45,46,47,48); and one F(5,6,7,8) atom. The C(41,42,43,44)-C(45,46,47,48) bond length is 1.39 Å. The C(41,42,43,44)-F(5,6,7,8) bond length is 1.37 Å. In the twenty-fifth C site, C(45,46,47,48) is bonded in a distorted trigonal planar geometry to one C(41,42,43,44); one C(49,50,51,52); and one H(41,42,43,44) atom. The C(45,46,47,48)-C(49,50,51,52) bond length is 1.39 Å. The C(45,46,47,48)-H(41,42,43,44) bond length is 1.09 Å. In the twenty-sixth C site, C(49,50,51,52) is bonded in a distorted single-bond geometry to one C(29,32); one C(45,46,47,48); and one H(45,46,47,48) atom. The C(49,50,51,52)-H(45,46,47,48) bond length is 1.09 Å. In the twenty-seventh C site, C(53) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(5) atom. The C(53)-O(1) bond length is 1.28 Å. The C(53)-O(5) bond length is 1.26 Å. In the twenty-eighth C site, C(54) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(6) atom. The C(54)-O(2) bond length is 1.28 Å. The C(54)-O(6) bond length is 1.26 Å. In the twenty-ninth C site, C(55) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(7) atom. The C(55)-O(3) bond length is 1.28 Å. The C(55)-O(7) bond length is 1.26 Å. In the thirtieth C site, C(56) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(8) atom. The C(56)-O(4) bond length is 1.28 Å. The C(56)-O(8) bond length is 1.26 Å. In the thirty-first C site, C(61) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(9) atom. The C(61)-O(13) bond length is 1.28 Å. The C(61)-O(9) bond length is 1.27 Å. In the thirty-second C site, C(62) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(14) atom. The C(62)-O(10) bond length is 1.27 Å. The C(62)-O(14) bond length is 1.28 Å. In the thirty-third C site, C(63) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(15) atom. The C(63)-O(11) bond length is 1.27 Å. The C(63)-O(15) bond length is 1.28 Å. In the thirty-fourth C site, C(64) is bonded in a distorted bent 120 degrees geometry to one O(12) and one O(16) atom. The C(64)-O(12) bond length is 1.27 Å. The C(64)-O(16) bond length is 1.28 Å. There are fourteen inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(2), and one C(6) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(3,4); one C(3,4); and one C(7,8) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cu(3,4); one C(3,4); and one C(7,8) atom. The N(4)-Cu(3,4) bond length is 2.20 Å. The N(4)-C(3,4) bond length is 1.37 Å. The N(4)-C(7,8) bond length is 1.34 Å. In the fifth N site, N(5,6,7,8) is bonded in a distorted water-like geometry to one C(1) and one N(9,10,11,12) atom. The N(5,6,7,8)-N(9,10,11,12) bond length is 1.37 Å. In the sixth N site, N(9,10,11,12) is bonded in a 3-coordinate geometry to one C(5); one C(9,10,11,12); and one N(5,6,7,8) atom. In the seventh N site, N(13) is bonded in a distorted trigonal planar geometry to one C(17,18,19,20); one C(21); and one N(17) atom. The N(13)-N(17) bond length is 1.37 Å. In the eighth N site, N(14,15,16) is bonded in a distorted trigonal planar geometry to one C(17,18,19,20); one C(22); and one N(18,19,20) atom. The N(14,15,16)-C(17,18,19,20) bond length is 1.45 Å. The N(14,15,16)-N(18,19,20) bond length is 1.37 Å. In the ninth N site, N(17) is bonded in a water-like geometry to one C(25) and one N(13) atom. In the tenth N site, N(18,19,20) is bonded in a water-like geometry to one C(26) and one N(14,15,16) atom. In the eleventh N site, N(21) is bonded in a trigonal planar geometry to one Cu(1), one C(21), and one C(25) atom. In the twelfth N site, N(22) is bonded in a trigonal planar geometry to one Cu(2), one C(22), and one C(26) atom. In the thirteenth N site, N(23) is bonded in a trigonal planar geometry to one Cu(3,4); one C(23,24); and one C(27,28) atom. In the fourteenth N site, N(24) is bonded in a trigonal planar geometry to one Cu(3,4); one C(23,24); and one C(27,28) atom. The N(24)-Cu(3,4) bond length is 1.97 Å. The N(24)-C(23,24) bond length is 1.34 Å. The N(24)-C(27,28) bond length is 1.37 Å. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(17) and one O(5) atom. The H(1)-O(17) bond length is 1.01 Å. The H(1)-O(5) bond length is 1.62 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(18) and one O(6) atom. The H(2)-O(18) bond length is 1.01 Å. The H(2)-O(6) bond length is 1.63 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(19) and one O(7) atom. The H(3)-O(19) bond length is 1.01 Å. The H(3)-O(7) bond length is 1.62 Å. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(20) and one O(8) atom. The H(4)-O(20) bond length is 1.01 Å. The H(4)-O(8) bond length is 1.62 Å. In the fifth H site, H(5,6,7,8) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(9,10,11,12) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(13,14,15,16) is bonded in a single-bond geometry to one C(9,10,11,12) atom. In the eighth H site, H(17,18,19,20) is bonded in a single-bond geometry to one C(9,10,11,12) atom. In the ninth H site, H(21,22,23,24) is bonded in a single-bond geometry to one C(17,18,19,20) atom. In the tenth H site, H(25,26,27,28) is bonded in a single-bond geometry to one C(17,18,19,20) atom. In the eleventh H site, H(29) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(30,31,32) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(33) is bonded in a single-bond geometry to one C(25) atom. In the fourteenth H site, H(34,35,36) is bonded in a single-bond geometry to one C(26) atom. In the fifteenth H site, H(37,38,39,40) is bonded in a single-bond geometry to one C(37,38,39,40) atom. In the sixteenth H site, H(41,42,43,44) is bonded in a single-bond geometry to one C(45,46,47,48) atom. In the seventeenth H site, H(45,46,47,48) is bonded in a single-bond geometry to one C(49,50,51,52) atom. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(53) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(54) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(3,4) and one C(55) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(3,4) and one C(56) atom. The O(4)-Cu(3,4) bond length is 2.00 Å. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(53) and one H(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one C(54) and one H(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one C(55) and one H(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one C(56) and one H(4) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Cu(3,4) and one C(61) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Cu(3,4) and one C(62) atom. The O(10)-Cu(3,4) bond length is 2.10 Å. In the eleventh O site, O(11) is bonded in a water-like geometry to one Cu(2) and one C(63) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one Cu(1) and one C(64) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(61) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(62) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Cu(3,4) and one C(63) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Cu(3,4) and one C(64) atom. The O(16)-Cu(3,4) bond length is 1.95 Å. In the seventeenth O site, O(17) is bonded in a water-like geometry to one C(13) and one H(1) atom. In the eighteenth O site, O(18) is bonded in a water-like geometry to one C(14) and one H(2) atom. In the nineteenth O site, O(19) is bonded in a water-like geometry to one C(15) and one H(3) atom. In the twentieth O site, O(20) is bonded in a water-like geometry to one C(16) and one H(4) atom. There are two inequivalent F sites. In the first F site, F(1,2,3,4) is bonded in a single-bond geometry to one C(33,34,35) atom. In the second F site, F(5,6,7,8) is bonded in a single-bond geometry to one C(41,42,43,44) atom. Linkers: 1 O[C@](CN1[CH]N=C[N]1)(Cn1cn[c]n1)c1ccc(F)cc1F ,2 OC(Cn1cncn1)(Cn1cncn1)c1ccc(F)cc1F ,3 OC(CN1[CH]N=C[N]1)(CN1[CH]N=C[N]1)c1ccc(F)cc1F ,1 OC(CN1[CH]N=C[N]1)(CN1[CH]N=C[N]1)c1c[c][c]cc1F ,1 O[C@](CN1[CH]N=C[N]1)(Cn1cncn1)c1ccc(F)cc1F ,1 O[C@@](CN1[CH]N=C[N]1)(Cn1cncn1)c1ccc(F)cc1F ,8 [O]C(=O)CC([O])=O ,1 OC(Cn1cncn1)(Cn1cncn1)c1c[c][c]cc1F ,1 O[C@](Cn1cn[c]n1)(Cn1cncn1)c1ccc(F)cc1F. Metal clusters: 8 [Cu]. The MOF has largest included sphere 2.70 A, density 1.62 g/cm3, surface area 4161.82 m2/g, accessible volume 0.17 cm3/g