C3H2(CH)6CuC14PNH11O3Br is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules; one 2,3-dimethyl-1,3-butadiene molecule; two propylene molecules; and one CuC14PNH11O3Br cluster. In the CuC14PNH11O3Br cluster, Cu(1) is bonded to one P(1), one N(1), and two equivalent Br(1) atoms to form distorted edge-sharing CuPBr2N tetrahedra. The Cu(1)-P(1) bond length is 2.16 Å. The Cu(1)-N(1) bond length is 2.01 Å. There is one shorter (2.48 Å) and one longer (2.58 Å) Cu(1)-Br(1) bond length. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1,4) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1,4) bond length is 1.09 Å. In the second C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1,4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(1,4) bond length is 1.09 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(11), one C(7), and one O(1) atom. The C(6)-C(11) bond length is 1.39 Å. The C(6)-C(7) bond length is 1.39 Å. The C(6)-O(1) bond length is 1.40 Å. In the fourth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(5) bond length is 1.09 Å. In the fifth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(6) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(6) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(8) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one H(9) atom. The C(11)-H(9) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one O(2) atom. The C(12)-O(2) bond length is 1.39 Å. In the tenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19), one C(23), and one O(3) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-C(23) bond length is 1.39 Å. The C(18)-O(3) bond length is 1.41 Å. In the eleventh C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(15) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-H(15) bond length is 1.09 Å. In the twelfth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(16) atom. The C(20)-H(16) bond length is 1.09 Å. In the thirteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(18) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(18) bond length is 1.09 Å. In the fourteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(18), one C(22), and one H(19) atom. The C(23)-H(19) bond length is 1.09 Å. P(1) is bonded in a 4-coordinate geometry to one Cu(1), one O(1), one O(2), and one O(3) atom. The P(1)-O(1) bond length is 1.64 Å. The P(1)-O(2) bond length is 1.64 Å. The P(1)-O(3) bond length is 1.62 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. There are ten inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(6) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(12) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(18) and one P(1) atom. Br(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 1 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.54 A, density 1.67 g/cm3, surface area 4549.21 m2/g, accessible volume 0.13 cm3/g