VC8H4O5C3H4(CH)2CH2 crystallizes in the triclinic P1 space group. The structure consists of eight 02329_fluka molecules, four 02329_fluka molecules, and four propylene molecules inside a VC8H4O5 framework. In the VC8H4O5 framework, there are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(15), one O(20), one O(4), one O(6), and one O(9) atom to form distorted corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 48°. The V(1)-O(1) bond length is 1.65 Å. The V(1)-O(15) bond length is 1.99 Å. The V(1)-O(20) bond length is 1.99 Å. The V(1)-O(4) bond length is 2.08 Å. The V(1)-O(6) bond length is 1.98 Å. The V(1)-O(9) bond length is 1.98 Å. In the second V site, V(2,3) is bonded to one O(10), one O(16), one O(19), one O(2), one O(3), and one O(5) atom to form distorted corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 48°. The V(2,3)-O(10) bond length is 1.97 Å. The V(2,3)-O(16) bond length is 1.98 Å. The V(2,3)-O(19) bond length is 1.97 Å. The V(2,3)-O(2) bond length is 1.64 Å. The V(2,3)-O(3) bond length is 2.09 Å. The V(2,3)-O(5) bond length is 1.97 Å. In the third V site, V(4) is bonded to one O(1), one O(12), one O(14), one O(17), one O(4), and one O(7) atom to form distorted corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 48°. The V(4)-O(1) bond length is 2.08 Å. The V(4)-O(12) bond length is 1.98 Å. The V(4)-O(14) bond length is 1.99 Å. The V(4)-O(17) bond length is 1.99 Å. The V(4)-O(4) bond length is 1.65 Å. The V(4)-O(7) bond length is 1.98 Å. There are thirty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(13), and one O(5) atom. The C(1)-C(5) bond length is 1.48 Å. The C(1)-O(13) bond length is 1.28 Å. The C(1)-O(5) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(14), and one O(6) atom. The C(2)-C(6) bond length is 1.48 Å. The C(2)-O(14) bond length is 1.28 Å. The C(2)-O(6) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(15), and one O(7) atom. The C(3)-C(7) bond length is 1.48 Å. The C(3)-O(15) bond length is 1.28 Å. The C(3)-O(7) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(16), and one O(8) atom. The C(4)-C(8) bond length is 1.48 Å. The C(4)-O(16) bond length is 1.28 Å. The C(4)-O(8) bond length is 1.28 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1); one C(13); and one C(9,12) atom. The C(5)-C(13) bond length is 1.40 Å. The C(5)-C(9,12) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(2) atom. The C(6)-C(10) bond length is 1.40 Å. The C(6)-C(14) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(3) atom. The C(7)-C(11) bond length is 1.40 Å. The C(7)-C(15) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(16); one C(4); and one C(9,12) atom. The C(8)-C(16) bond length is 1.40 Å. The C(8)-C(9,12) bond length is 1.40 Å. In the ninth C site, C(9,12) is bonded in a distorted trigonal planar geometry to one C(25), one C(5), and one H(1) atom. The C(9,12)-C(25) bond length is 1.39 Å. The C(9,12)-H(1) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(26); one C(6); and one H(2,3) atom. The C(10)-C(26) bond length is 1.39 Å. The C(10)-H(2,3) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(27); one C(7); and one H(2,3) atom. The C(11)-C(27) bond length is 1.39 Å. The C(11)-H(2,3) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(5) and one H(5,8) atom. The C(13)-H(5,8) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(6) and one H(6,7) atom. The C(14)-H(6,7) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(7) and one H(6,7) atom. The C(15)-H(6,7) bond length is 1.09 Å. In the fifteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(8) and one H(5,8) atom. The C(16)-H(5,8) bond length is 1.09 Å. In the sixteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(17), and one O(9) atom. The C(17)-C(21) bond length is 1.48 Å. The C(17)-O(17) bond length is 1.28 Å. The C(17)-O(9) bond length is 1.28 Å. In the seventeenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(10), and one O(18) atom. The C(18)-C(22) bond length is 1.48 Å. The C(18)-O(10) bond length is 1.28 Å. The C(18)-O(18) bond length is 1.28 Å. In the eighteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(11), and one O(19) atom. The C(19)-C(23) bond length is 1.48 Å. The C(19)-O(11) bond length is 1.28 Å. The C(19)-O(19) bond length is 1.28 Å. In the nineteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(12), and one O(20) atom. The C(20)-C(24) bond length is 1.48 Å. The C(20)-O(12) bond length is 1.28 Å. The C(20)-O(20) bond length is 1.28 Å. In the twentieth C site, C(21) is bonded in a trigonal planar geometry to one C(17), one C(25), and one C(29) atom. The C(21)-C(25) bond length is 1.40 Å. The C(21)-C(29) bond length is 1.40 Å. In the twenty-first C site, C(22) is bonded in a trigonal planar geometry to one C(18), one C(26), and one C(30) atom. The C(22)-C(26) bond length is 1.40 Å. The C(22)-C(30) bond length is 1.40 Å. In the twenty-second C site, C(23) is bonded in a trigonal planar geometry to one C(19), one C(27), and one C(31) atom. The C(23)-C(27) bond length is 1.40 Å. The C(23)-C(31) bond length is 1.41 Å. In the twenty-third C site, C(24) is bonded in a trigonal planar geometry to one C(20), one C(28), and one C(32) atom. The C(24)-C(28) bond length is 1.40 Å. The C(24)-C(32) bond length is 1.40 Å. In the twenty-fourth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(21); one C(9,12); and one H(9,12) atom. The C(25)-H(9,12) bond length is 1.09 Å. In the twenty-fifth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(10); one C(22); and one H(10,11) atom. The C(26)-H(10,11) bond length is 1.09 Å. In the twenty-sixth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(11); one C(23); and one H(10,11) atom. The C(27)-H(10,11) bond length is 1.09 Å. In the twenty-seventh C site, C(28) is bonded in a distorted trigonal planar geometry to one C(24); one C(9,12); and one H(9,12) atom. The C(28)-C(9,12) bond length is 1.39 Å. The C(28)-H(9,12) bond length is 1.09 Å. In the twenty-eighth C site, C(29) is bonded in a distorted single-bond geometry to one C(21) and one H(13,14,15,16) atom. The C(29)-H(13,14,15,16) bond length is 1.09 Å. In the twenty-ninth C site, C(30) is bonded in a distorted single-bond geometry to one C(22) and one H(13,14,15,16) atom. The C(30)-H(13,14,15,16) bond length is 1.09 Å. In the thirtieth C site, C(31) is bonded in a distorted single-bond geometry to one C(23) and one H(13,14,15,16) atom. The C(31)-H(13,14,15,16) bond length is 1.09 Å. In the thirty-first C site, C(32) is bonded in a distorted single-bond geometry to one C(24) and one H(13,14,15,16) atom. The C(32)-H(13,14,15,16) bond length is 1.09 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(9,12) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(9,12) atom. The H(4)-C(9,12) bond length is 1.09 Å. In the fourth H site, H(5,8) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(6,7) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(9,12) is bonded in a single-bond geometry to one C(25) atom. In the seventh H site, H(10,11) is bonded in a single-bond geometry to one C(26) atom. In the eighth H site, H(13,14,15,16) is bonded in a single-bond geometry to one C(29) atom. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one V(4) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent V(2,3) atoms. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to two equivalent V(2,3) atoms. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one V(1) and one V(4) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one V(2,3) and one C(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one V(1) and one C(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one V(4) and one C(3) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one V(2,3) and one C(4) atom. The O(8)-V(2,3) bond length is 1.97 Å. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(1) and one C(17) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(2,3) and one C(18) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one V(2,3) and one C(19) atom. The O(11)-V(2,3) bond length is 1.96 Å. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one V(4) and one C(20) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one V(2,3) and one C(1) atom. The O(13)-V(2,3) bond length is 1.97 Å. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one V(4) and one C(2) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one V(1) and one C(3) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one V(2,3) and one C(4) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one V(4) and one C(17) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one V(2,3) and one C(18) atom. The O(18)-V(2,3) bond length is 1.97 Å. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one V(2,3) and one C(19) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one V(1) and one C(20) atom. Linkers: 4 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 4 [V]. RCSR code: lvt. The MOF has largest included sphere 3.09 A, density 1.36 g/cm3, surface area 4817.67 m2/g, accessible volume 0.33 cm3/g