CoC22H22(NO2)4(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one CoC22H22(NO2)4 cluster. In the CoC22H22(NO2)4 cluster, Co(1) is bonded in a distorted octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. Both Co(1)-N(1) bond lengths are 1.93 Å. Both Co(1)-O(1) bond lengths are 1.94 Å. Both Co(1)-O(2) bond lengths are 2.30 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(2)-H(5) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(6) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-C(6) bond length is 1.50 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(7) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(7) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one O(4) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-O(4) bond length is 1.25 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(8), and one H(9) atom. The C(7)-N(2) bond length is 1.45 Å. The C(7)-H(8) bond length is 1.10 Å. The C(7)-H(9) bond length is 1.10 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(1), and one O(3) atom. The C(10)-C(11) bond length is 1.50 Å. The C(10)-O(1) bond length is 1.29 Å. The C(10)-O(3) bond length is 1.27 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(13) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(13) bond length is 1.40 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(14) atom. The C(12)-H(14) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(11) and one H(15) atom. The C(13)-H(15) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(6), one C(7), and one H(4) atom. The N(2)-H(4) bond length is 1.02 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.99 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(2) and one O(3) atom. The H(3)-O(2) bond length is 1.00 Å. The H(3)-O(3) bond length is 1.68 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(10) atom. In the second O site, O(2) is bonded in a water-like geometry to one Co(1), one H(2), and one H(3) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one C(10) and one H(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(6) atom. Linkers: 2 O=C(NCCCCCCNC(=O)c1cccnc1)c1c[c]cnc1 ,1 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 1 O.O.O=[C]O[Co]O[C]=O. The MOF has largest included sphere 1.95 A, density 1.58 g/cm3, surface area 4473.99 m2/g, accessible volume 0.11 cm3/g