ZnC13H7(NO2)2(CH2)2CHC8NH9SO2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, four 02329_fluka molecules, two n-methyl-p-toluenesulfonamide molecules, and one ZnC13H7(NO2)2 cluster. In the ZnC13H7(NO2)2 cluster, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(2), and one O(4) atom. The Zn(1)-N(1) bond length is 2.16 Å. The Zn(1)-N(2) bond length is 2.12 Å. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.07 Å. The Zn(1)-O(4) bond length is 2.00 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(5)-O(3) bond length is 1.26 Å. The C(5)-O(4) bond length is 1.29 Å. In the third C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(13) atom. The C(13)-N(2) bond length is 1.33 Å. The C(13)-H(13) bond length is 1.09 Å. In the fourth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(15) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(15) bond length is 1.09 Å. In the fifth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.42 Å. The C(16)-C(21) bond length is 1.43 Å. In the sixth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one N(2) atom. The C(17)-C(18) bond length is 1.44 Å. The C(17)-N(2) bond length is 1.36 Å. In the seventh C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one N(1) atom. The C(18)-C(19) bond length is 1.42 Å. The C(18)-N(1) bond length is 1.35 Å. In the eighth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(22) atom. The C(19)-C(20) bond length is 1.43 Å. The C(19)-C(22) bond length is 1.41 Å. In the ninth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one H(16) atom. The C(20)-C(21) bond length is 1.37 Å. The C(20)-H(16) bond length is 1.09 Å. In the tenth C site, C(21) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one H(17) atom. The C(21)-H(17) bond length is 1.09 Å. In the eleventh C site, C(22) is bonded in a distorted single-bond geometry to one C(19) and one H(18) atom. The C(22)-H(18) bond length is 1.09 Å. In the twelfth C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(19) atom. The C(23)-C(24) bond length is 1.41 Å. The C(23)-H(19) bond length is 1.09 Å. In the thirteenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one N(1), and one H(20) atom. The C(24)-N(1) bond length is 1.33 Å. The C(24)-H(20) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(18), and one C(24) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(17) atom. There are seven inequivalent H sites. In the first H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the third H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(24) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. Linkers: 2 c1cnc2c(c1)ccc1cccnc12 ,1 Cc1ccc(S(=O)(=O)N[C@H](CCC([O])=O)C([O])=O)cc1 ,1 Cc1ccc(S(=O)(=O)N[C@@H](CCC([O])=O)C([O])=O)cc1. Metal clusters: 1 O=[C]O[Zn]1O[C]O[Zn](O[C]=O)O[C]O1. The MOF has largest included sphere 2.16 A, density 1.64 g/cm3, surface area 4462.84 m2/g, accessible volume 0.09 cm3/g