AgC8N2H10SO3C5H5NCH3CF3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two allylamine, n,n,2-trimethyl- molecules; two trifluoromethane molecules; and two AgC8N2H10SO3 clusters. In each AgC8N2H10SO3 cluster, Ag(1) is bonded in a distorted T-shaped geometry to one N(1), one N(2), and one O(1) atom. The Ag(1)-N(1) bond length is 2.14 Å. The Ag(1)-N(2) bond length is 2.24 Å. The Ag(1)-O(1) bond length is 2.64 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1,4) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1,4) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.51 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(1,4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one N(2), one H(5), and one H(6) atom. The C(6)-N(2) bond length is 1.49 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(7), and one H(8) atom. The C(7)-N(2) bond length is 1.48 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.10 Å. In the eighth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(13), and one H(14) atom. The C(10)-N(2) bond length is 1.48 Å. The C(10)-H(13) bond length is 1.10 Å. The C(10)-H(14) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a tetrahedral geometry to one Ag(1), one C(10), one C(6), and one C(7) atom. There are nine inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.46 Å. The S(1)-O(2) bond length is 1.46 Å. The S(1)-O(3) bond length is 1.46 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. Linkers: 1 c1cc(CN2CCN(Cc3ccc(CN4CCN(Cc5ccncc5)CC4)cc3)CC2)ccn1 ,2 [CH2][N]Cc1ccc(CN2CCN(Cc3ccncc3)CC2)cc1. Metal clusters: 2 [Ag].[O]S([O])([O])C(F)(F)F. The MOF has largest included sphere 1.95 A, density 1.86 g/cm3, surface area 4027.53 m2/g, accessible volume 0.14 cm3/g