Mn3C36H22(NO3)4(CH)20 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four isobutylene molecules, and one Mn3C36H22(NO3)4 cluster. In the Mn3C36H22(NO3)4 cluster, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Mn(1)-O(1) bond length is 2.11 Å. The Mn(1)-O(2) bond length is 2.12 Å. The Mn(1)-O(3) bond length is 2.29 Å. The Mn(1)-O(4) bond length is 2.28 Å. The Mn(1)-O(5) bond length is 2.19 Å. The Mn(1)-O(6) bond length is 2.19 Å. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one N(1), one N(3), one O(1), one O(11), one O(7), and one O(9) atom. The Mn(2)-N(1) bond length is 2.31 Å. The Mn(2)-N(3) bond length is 2.17 Å. The Mn(2)-O(1) bond length is 2.50 Å. The Mn(2)-O(11) bond length is 2.04 Å. The Mn(2)-O(7) bond length is 2.24 Å. The Mn(2)-O(9) bond length is 2.07 Å. In the third Mn site, Mn(3) is bonded in a 6-coordinate geometry to one N(2), one N(4), one O(10), one O(12), one O(2), and one O(8) atom. The Mn(3)-N(2) bond length is 2.31 Å. The Mn(3)-N(4) bond length is 2.17 Å. The Mn(3)-O(10) bond length is 2.07 Å. The Mn(3)-O(12) bond length is 2.04 Å. The Mn(3)-O(2) bond length is 2.51 Å. The Mn(3)-O(8) bond length is 2.23 Å. There are twenty-five inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal planar geometry to one C(5,6); one N(3); and one H(1,2) atom. The C(1,2)-C(5,6) bond length is 1.39 Å. The C(1,2)-N(3) bond length is 1.34 Å. The C(1,2)-H(1,2) bond length is 1.09 Å. In the second C site, C(3,4) is bonded in a distorted trigonal planar geometry to one C(55,56); one N(1); and one H(3,4) atom. The C(3,4)-C(55,56) bond length is 1.40 Å. The C(3,4)-N(1) bond length is 1.34 Å. The C(3,4)-H(3,4) bond length is 1.09 Å. In the third C site, C(5,6) is bonded in a distorted trigonal planar geometry to one C(1,2); one C(53,54); and one H(5,6) atom. The C(5,6)-C(53,54) bond length is 1.39 Å. The C(5,6)-H(5,6) bond length is 1.09 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(5) atom. The C(7)-O(11) bond length is 1.27 Å. The C(7)-O(5) bond length is 1.27 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(12) and one O(6) atom. The C(8)-O(12) bond length is 1.27 Å. The C(8)-O(6) bond length is 1.27 Å. In the sixth C site, C(9,10) is bonded in a distorted trigonal planar geometry to one C(21,22); one C(25,26); and one N(1) atom. The C(9,10)-C(21,22) bond length is 1.48 Å. The C(9,10)-C(25,26) bond length is 1.40 Å. The C(9,10)-N(1) bond length is 1.35 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(19) and one H(7,8) atom. The C(11)-C(19) bond length is 1.40 Å. The C(11)-H(7,8) bond length is 1.09 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(20) and one H(7,8) atom. The C(12)-C(20) bond length is 1.40 Å. The C(12)-H(7,8) bond length is 1.09 Å. In the ninth C site, C(15,16) is bonded in a distorted single-bond geometry to one C(41) and one H(11,12) atom. The C(15,16)-C(41) bond length is 1.40 Å. The C(15,16)-H(11,12) bond length is 1.09 Å. In the tenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(3), and one O(9) atom. The C(17)-C(19) bond length is 1.50 Å. The C(17)-O(3) bond length is 1.27 Å. The C(17)-O(9) bond length is 1.29 Å. In the eleventh C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(10), and one O(4) atom. The C(18)-C(20) bond length is 1.50 Å. The C(18)-O(10) bond length is 1.28 Å. The C(18)-O(4) bond length is 1.27 Å. In the twelfth C site, C(19) is bonded in a trigonal planar geometry to one C(11), one C(17), and one C(23) atom. The C(19)-C(23) bond length is 1.40 Å. In the thirteenth C site, C(20) is bonded in a trigonal planar geometry to one C(12), one C(18), and one C(24) atom. The C(20)-C(24) bond length is 1.40 Å. In the fourteenth C site, C(21,22) is bonded in a distorted trigonal planar geometry to one C(27,28); one C(9,10); and one N(3) atom. The C(21,22)-C(27,28) bond length is 1.40 Å. The C(21,22)-N(3) bond length is 1.36 Å. In the fifteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(19) and one H(13,14) atom. The C(23)-H(13,14) bond length is 1.09 Å. In the sixteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(20) and one H(13,14) atom. The C(24)-H(13,14) bond length is 1.09 Å. In the seventeenth C site, C(25,26) is bonded in a distorted single-bond geometry to one C(9,10) and one H(15,16) atom. The C(25,26)-H(15,16) bond length is 1.09 Å. In the eighteenth C site, C(27,28) is bonded in a distorted single-bond geometry to one C(21,22) and one H(17,18) atom. The C(27,28)-H(17,18) bond length is 1.09 Å. In the nineteenth C site, C(37) is bonded in a bent 120 degrees geometry to one C(41), one O(1), and one O(7) atom. The C(37)-C(41) bond length is 1.49 Å. The C(37)-O(1) bond length is 1.29 Å. The C(37)-O(7) bond length is 1.28 Å. In the twentieth C site, C(38) is bonded in a bent 120 degrees geometry to one C(42), one O(2), and one O(8) atom. The C(38)-C(42) bond length is 1.49 Å. The C(38)-O(2) bond length is 1.28 Å. The C(38)-O(8) bond length is 1.28 Å. In the twenty-first C site, C(41) is bonded in a trigonal planar geometry to one C(15,16); one C(37); and one C(43,44) atom. The C(41)-C(43,44) bond length is 1.40 Å. In the twenty-second C site, C(42) is bonded in a trigonal planar geometry to one C(15,16); one C(38); and one C(43,44) atom. The C(42)-C(15,16) bond length is 1.40 Å. The C(42)-C(43,44) bond length is 1.40 Å. In the twenty-third C site, C(43,44) is bonded in a distorted single-bond geometry to one C(41) and one H(25,26) atom. The C(43,44)-H(25,26) bond length is 1.09 Å. In the twenty-fourth C site, C(53,54) is bonded in a distorted single-bond geometry to one C(5,6) and one H(39,40) atom. The C(53,54)-H(39,40) bond length is 1.09 Å. In the twenty-fifth C site, C(55,56) is bonded in a distorted single-bond geometry to one C(3,4) and one H(41,42) atom. The C(55,56)-H(41,42) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(2); one C(3,4); and one C(9,10) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(3); one C(3,4); and one C(9,10) atom. The N(2)-C(3,4) bond length is 1.34 Å. The N(2)-C(9,10) bond length is 1.35 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Mn(2); one C(1,2); and one C(21,22) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Mn(3); one C(1,2); and one C(21,22) atom. The N(4)-C(1,2) bond length is 1.34 Å. The N(4)-C(21,22) bond length is 1.36 Å. There are eleven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(3,4) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(5,6) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(11,12) is bonded in a single-bond geometry to one C(15,16) atom. In the sixth H site, H(13,14) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(15,16) is bonded in a single-bond geometry to one C(25,26) atom. In the eighth H site, H(17,18) is bonded in a single-bond geometry to one C(27,28) atom. In the ninth H site, H(25,26) is bonded in a single-bond geometry to one C(43,44) atom. In the tenth H site, H(39,40) is bonded in a single-bond geometry to one C(53,54) atom. In the eleventh H site, H(41,42) is bonded in a single-bond geometry to one C(55,56) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(2), and one C(37) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(3), and one C(38) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(17) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(18) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(7) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(8) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Mn(2) and one C(37) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Mn(3) and one C(38) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(17) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(18) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(7) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(8) atom. Linkers: 2 [O]C(=O)c1ccc(CC(Cc2ccc(C([O])=O)cc2)C([O])=O)cc1 ,2 c1ccc(-c2ccccn2)nc1. Metal clusters: 1 [C]1O[Mn]2O[C]O[Mn]34(O1)(O[C]O2)O[C]O[Mn](O[C]O3)O[C]O4. RCSR code: kgd. The MOF has largest included sphere 2.32 A, density 1.62 g/cm3, surface area 3974.00 m2/g, accessible volume 0.09 cm3/g