(CH3)4(CH2)4CuS4(O6Cl)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, eight 02329_fluka molecules, and two CuS4(O6Cl)2 clusters. In each CuS4(O6Cl)2 cluster, Cu(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted CuO6 octahedra that share corners with two equivalent Cl(1)O4 tetrahedra. Both Cu(1)-O(1) bond lengths are 2.00 Å. Both Cu(1)-O(2) bond lengths are 1.98 Å. Both Cu(1)-O(3) bond lengths are 2.57 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one O(1) atom. The S(1)-O(1) bond length is 1.55 Å. In the second S site, S(2) is bonded in a distorted single-bond geometry to one O(2) atom. The S(2)-O(2) bond length is 1.55 Å. There are six inequivalent O sites. In the first O site, O(6) is bonded in a single-bond geometry to one Cl(1) atom. The O(6)-Cl(1) bond length is 1.46 Å. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one S(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one S(2) atom. In the fourth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one Cl(1) atom. The O(3)-Cl(1) bond length is 1.48 Å. In the fifth O site, O(4) is bonded in a single-bond geometry to one Cl(1) atom. The O(4)-Cl(1) bond length is 1.46 Å. In the sixth O site, O(5) is bonded in a single-bond geometry to one Cl(1) atom. The O(5)-Cl(1) bond length is 1.46 Å. Cl(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form ClO4 tetrahedra that share  a cornercorner with one Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles are 56°. Linkers: 2 C[S@](=O)CC[S@](C)=O ,2 C[S@@](=O)CC[S@@](C)=O. Metal clusters: 2 CSO[Cu](OSC)(OSC)OSC. RCSR code: sql. The MOF has largest included sphere 1.61 A, density 1.98 g/cm3, surface area 3757.84 m2/g, accessible volume 0.08 cm3/g