SmCuC16H12S(NO3)3CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a SmCuC16H12S(NO3)3 framework. In the SmCuC16H12S(NO3)3 framework, Sm(1) is bonded in a 9-coordinate geometry to one N(1), one O(1), one O(2), one O(3), one O(5), one O(7), one O(9), and two equivalent O(8) atoms. The Sm(1)-N(1) bond length is 2.53 Å. The Sm(1)-O(1) bond length is 2.48 Å. The Sm(1)-O(2) bond length is 2.57 Å. The Sm(1)-O(3) bond length is 2.38 Å. The Sm(1)-O(5) bond length is 2.41 Å. The Sm(1)-O(7) bond length is 2.51 Å. The Sm(1)-O(9) bond length is 2.48 Å. There is one shorter (2.44 Å) and one longer (2.61 Å) Sm(1)-O(8) bond length. Cu(1) is bonded in a distorted T-shaped geometry to one N(2), one N(3), and one O(4) atom. The Cu(1)-N(2) bond length is 1.89 Å. The Cu(1)-N(3) bond length is 1.90 Å. The Cu(1)-O(4) bond length is 2.36 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(3) bond length is 1.28 Å. The C(1)-O(4) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(1) bond length is 1.34 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(5) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(1) atom. The C(6)-C(7) bond length is 1.51 Å. The C(6)-N(1) bond length is 1.34 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(5), and one O(6) atom. The C(7)-O(5) bond length is 1.30 Å. The C(7)-O(6) bond length is 1.24 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(6) atom. The C(8)-C(9) bond length is 1.38 Å. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(6) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(7) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(7) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(9) atom. The C(10)-C(10) bond length is 1.48 Å. The C(10)-C(11) bond length is 1.41 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(8) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(8) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one H(9) atom. The C(12)-N(2) bond length is 1.36 Å. The C(12)-H(9) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one H(10) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-N(3) bond length is 1.35 Å. The C(13)-H(10) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(11) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(11) bond length is 1.08 Å. In the fourteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(16) atom. The C(15)-C(15) bond length is 1.48 Å. The C(15)-C(16) bond length is 1.41 Å. In the fifteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one H(12) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(12) bond length is 1.09 Å. In the sixteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(3), and one H(13) atom. The C(17)-N(3) bond length is 1.36 Å. The C(17)-H(13) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Sm(1), one C(2), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(12), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(17) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(5) and one O(9) atom. The H(1)-O(5) bond length is 1.60 Å. The H(1)-O(9) bond length is 1.02 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(9) atom. The H(2)-O(9) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(7), and one O(8) atom. The S(1)-O(1) bond length is 1.49 Å. The S(1)-O(2) bond length is 1.49 Å. The S(1)-O(7) bond length is 1.49 Å. The S(1)-O(8) bond length is 1.51 Å. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Sm(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Sm(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Sm(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cu(1) and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Sm(1), one C(7), and one H(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Sm(1) and one S(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to two equivalent Sm(1) and one S(1) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Sm(1), one H(1), and one H(2) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1 ,2 [c]1cc(-c2ccncc2)ccn1. Metal clusters: 2 [Sm] ,2 [Cu]. The MOF has largest included sphere 2.69 A, density 2.17 g/cm3, surface area 3036.96 m2/g, accessible volume 0.10 cm3/g