Li3C6H12SO12CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a Li3C6H12SO12 framework. In the Li3C6H12SO12 framework, there are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(4), one O(5), one O(6), one O(7), and two equivalent O(2) atoms to form distorted LiO6 octahedra that share  an edgeedge with one Li(1)O6 octahedra and  an edgeedge with one Li(2)O4 tetrahedra. The Li(1)-O(4) bond length is 2.18 Å. The Li(1)-O(5) bond length is 2.41 Å. The Li(1)-O(6) bond length is 2.14 Å. The Li(1)-O(7) bond length is 2.07 Å. There is one shorter (2.04 Å) and one longer (2.11 Å) Li(1)-O(2) bond length. In the second Li site, Li(2) is bonded to one O(12), one O(3), one O(4), and one O(5) atom to form edge-sharing LiO4 tetrahedra. The Li(2)-O(12) bond length is 2.00 Å. The Li(2)-O(3) bond length is 1.88 Å. The Li(2)-O(4) bond length is 1.92 Å. The Li(2)-O(5) bond length is 1.94 Å. In the third Li site, Li(3) is bonded to one O(10), one O(9), and two equivalent O(8) atoms to form edge-sharing LiO4 tetrahedra. The Li(3)-O(10) bond length is 2.03 Å. The Li(3)-O(9) bond length is 1.94 Å. There is one shorter (2.06 Å) and one longer (2.10 Å) Li(3)-O(8) bond length. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.43 Å. The C(1)-C(6) bond length is 1.38 Å. The C(1)-S(1) bond length is 1.75 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one O(7) atom. The C(2)-O(7) bond length is 1.31 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one O(9) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-O(9) bond length is 1.36 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(7) bond length is 1.46 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(13) atom. The C(6)-H(13) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(11), and one O(12) atom. The C(7)-O(11) bond length is 1.28 Å. The C(7)-O(12) bond length is 1.29 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(11) and one O(2) atom. The H(2)-O(11) bond length is 1.68 Å. The H(2)-O(2) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. The H(3)-O(4) bond length is 0.98 Å. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(4) and one O(7) atom. The H(4)-O(4) bond length is 1.00 Å. The H(4)-O(7) bond length is 1.65 Å. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one O(5) and one O(7) atom. The H(5)-O(5) bond length is 1.01 Å. The H(5)-O(7) bond length is 1.65 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(5) atom. The H(6)-O(5) bond length is 0.99 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(8) atom. The H(7)-O(8) bond length is 1.00 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(8) atom. The H(8)-O(8) bond length is 1.00 Å. In the ninth H site, H(9) is bonded in a bent 150 degrees geometry to one O(11) and one O(9) atom. The H(9)-O(11) bond length is 1.48 Å. The H(9)-O(9) bond length is 1.05 Å. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(10) atom. The H(10)-O(10) bond length is 0.99 Å. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(10) atom. The H(11)-O(10) bond length is 0.99 Å. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(6) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(3), and one O(6) atom. The S(1)-O(1) bond length is 1.49 Å. The S(1)-O(3) bond length is 1.46 Å. The S(1)-O(6) bond length is 1.48 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to two equivalent Li(1), one H(1), and one H(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Li(2) and one S(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one H(3), and one H(4) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Li(1), one Li(2), one H(5), and one H(6) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal pyramidal geometry to one Li(1), one C(2), one H(4), and one H(5) atom. In the eighth O site, O(8) is bonded to two equivalent Li(3), one H(7), and one H(8) atom to form distorted edge-sharing OLi2H2 tetrahedra. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(3), one C(4), and one H(9) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(3), one H(10), and one H(11) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one C(7), one H(2), and one H(9) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Li(2) and one C(7) atom. Linkers: 2 [O]C(=O)c1cc(S([O])([O])[O])c([O])cc1O. Metal clusters: 4 [Li] ,1 O.O.O.O.[Li]O.[Li]O. The MOF has largest included sphere 1.93 A, density 1.78 g/cm3, surface area 3339.09 m2/g, accessible volume 0.08 cm3/g