CoC14H8(N2Cl)2(CH)6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules and four CoC14H8(N2Cl)2 clusters. In each CoC14H8(N2Cl)2 cluster, Co(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one Cl(1), and one Cl(2) atom. The Co(1)-N(1) bond length is 2.00 Å. The Co(1)-N(3) bond length is 1.98 Å. The Co(1)-Cl(1) bond length is 2.22 Å. The Co(1)-Cl(2) bond length is 2.20 Å. There are fourteen inequivalent C sites. In the first C site, C(18) is bonded in a distorted single-bond geometry to one N(4) atom. The C(18)-N(4) bond length is 1.42 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(5) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.37 Å. The C(1)-H(5) bond length is 1.08 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one N(1) atom. The C(2)-N(1) bond length is 1.40 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one N(2) atom. The C(7)-N(2) bond length is 1.40 Å. In the fifth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(10), one C(9), and one N(2) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. The C(8)-N(2) bond length is 1.42 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(10)-H(8) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(9) atom. The C(11)-N(3) bond length is 1.33 Å. The C(11)-N(4) bond length is 1.37 Å. The C(11)-H(9) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one C(17), and one N(3) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(17) bond length is 1.41 Å. The C(12)-N(3) bond length is 1.40 Å. In the tenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(10) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(10) bond length is 1.09 Å. In the eleventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(4) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-H(4) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(15)-H(11) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(12) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(12) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(12), one C(16), and one N(4) atom. The C(17)-N(4) bond length is 1.40 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(7), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(11), and one C(12) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(11), one C(17), and one C(18) atom. There are eight inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(14) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Co(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Co(1) atom. Linkers: 4 c1ccc2c(c1)ncn2-c1ccc(-n2cnc3ccccc32)cc1. Metal clusters: 4 Cl[Co]Cl. The MOF has largest included sphere 5.28 A, density 1.07 g/cm3, surface area 4833.00 m2/g, accessible volume 0.43 cm3/g