ZnC6H8(NO3)2(C7H5)2(CH)12(C3H2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules; one 2,3-dimethyl-1,3-butadiene molecule; two 2,4-dimethyl-1,4-pentadiene molecules; two propylene molecules; and one ZnC6H8(NO3)2 cluster. In the ZnC6H8(NO3)2 cluster, Zn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(3) atoms. Both Zn(1)-N(1) bond lengths are 2.27 Å. Both Zn(1)-O(1) bond lengths are 2.13 Å. Both Zn(1)-O(3) bond lengths are 2.15 Å. There are three inequivalent C sites. In the first C site, C(19) is bonded in a distorted trigonal planar geometry to one N(1) and one H(15) atom. The C(19)-N(1) bond length is 1.35 Å. The C(19)-H(15) bond length is 1.09 Å. In the second C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(12) atom. The C(15)-N(1) bond length is 1.35 Å. The C(15)-H(12) bond length is 1.09 Å. In the third C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(14)-O(1) bond length is 1.29 Å. The C(14)-O(2) bond length is 1.26 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(19) atom. There are four inequivalent H sites. In the first H site, H(17) is bonded in a single-bond geometry to one O(3) atom. The H(17)-O(3) bond length is 0.99 Å. In the second H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(16) is bonded in a distorted linear geometry to one O(2) and one O(3) atom. The H(16)-O(2) bond length is 1.57 Å. The H(16)-O(3) bond length is 1.02 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(14) and one H(16) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Zn(1), one H(16), and one H(17) atom. Linkers: 1 c1cc(-c2ccncc2)ccn1. Metal clusters: 1 [Zn]. The MOF has largest included sphere 2.22 A, density 1.54 g/cm3, surface area 5095.39 m2/g, accessible volume 0.08 cm3/g