(CH2)6(C7H4)2(CH)2CuC16H14S2(N3O)2(C3NH7O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules; six 02329_fluka molecules; one 1,4,5,8-tetramethylnaphthalene molecule; two n,n-dimethylformamide molecules; and one CuC16H14S2(N3O)2 cluster. In the CuC16H14S2(N3O)2 cluster, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent N(3) atoms. Both Cu(1)-N(1) bond lengths are 1.93 Å. Both Cu(1)-N(3) bond lengths are 2.03 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.62 Å. In the second C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one C(9), and one N(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(9) bond length is 1.40 Å. The C(5)-N(4) bond length is 1.40 Å. In the third C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(3), and one H(8) atom. The C(6)-N(3) bond length is 1.34 Å. The C(6)-H(8) bond length is 1.08 Å. In the fourth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(3), and one H(9) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-N(3) bond length is 1.34 Å. The C(7)-H(9) bond length is 1.09 Å. In the fifth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(10) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(10) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(5), one C(8), and one H(11) atom. The C(9)-H(11) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a 3-coordinate geometry to one C(11), one N(4), and one O(2) atom. The C(10)-C(11) bond length is 1.51 Å. The C(10)-N(4) bond length is 1.37 Å. The C(10)-O(2) bond length is 1.24 Å. In the eighth C site, C(11) is bonded in a distorted water-like geometry to one C(10), one H(13), and one H(14) atom. The C(11)-H(13) bond length is 1.10 Å. The C(11)-H(14) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Cu(1) and one C(1) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(6), and one C(7) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(5), and one H(12) atom. The N(4)-H(12) bond length is 1.03 Å. There are seven inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(11) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. O(2) is bonded in a single-bond geometry to one C(10) atom. Linkers: 2 O=C(CCCCCCCCC(=O)Nc1cccnc1)Nc1c[c]cnc1 ,2 O=C(CCCCCCCCC(=O)Nc1cccnc1)Nc1c[c][c]nc1. Metal clusters: 1 [Cu]. The MOF has largest included sphere 2.08 A, density 1.41 g/cm3, surface area 5592.46 m2/g, accessible volume 0.15 cm3/g