CuC12N3H9O4(CH)2(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, eight 02329_fluka molecules, and one CuC12N3H9O4 cluster. In the CuC12N3H9O4 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-N(1) bond length is 2.21 Å. The Cu(1)-O(1) bond length is 1.99 Å. The Cu(1)-O(2) bond length is 2.00 Å. The Cu(1)-O(3) bond length is 2.00 Å. The Cu(1)-O(4) bond length is 2.01 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(17), one N(3), and one H(2) atom. The C(1)-C(17) bond length is 1.39 Å. The C(1)-N(3) bond length is 1.34 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(10), one C(13), and one N(2) atom. The C(2)-C(10) bond length is 1.40 Å. The C(2)-C(13) bond length is 1.41 Å. The C(2)-N(2) bond length is 1.39 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one N(3) and one H(4) atom. The C(4)-N(3) bond length is 1.35 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(5)-C(7) bond length is 1.41 Å. The C(5)-H(5) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(6)-O(3) bond length is 1.27 Å. The C(6)-O(4) bond length is 1.28 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(17), one C(5), and one N(2) atom. The C(7)-C(17) bond length is 1.41 Å. The C(7)-N(2) bond length is 1.38 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(8)-N(1) bond length is 1.35 Å. The C(8)-H(6) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(2) and one H(8) atom. The C(10)-H(8) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(12)-O(1) bond length is 1.27 Å. The C(12)-O(2) bond length is 1.27 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(16), one C(2), and one H(11) atom. The C(13)-C(16) bond length is 1.39 Å. The C(13)-H(11) bond length is 1.09 Å. In the eleventh C site, C(16) is bonded in a distorted trigonal planar geometry to one C(13), one N(1), and one H(16) atom. The C(16)-N(1) bond length is 1.35 Å. The C(16)-H(16) bond length is 1.09 Å. In the twelfth C site, C(17) is bonded in a distorted single-bond geometry to one C(1), one C(7), and one H(17) atom. The C(17)-H(17) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(16), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(7), and one H(1) atom. The N(2)-H(1) bond length is 1.02 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(4) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(12) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(12) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(6) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(6) atom. Linkers: 2 [O]C(=O)[C@H]1CC[C@@H](C([O])=O)CC1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.60 A, density 1.56 g/cm3, surface area 4716.00 m2/g, accessible volume 0.17 cm3/g