CoC36H34(NO3)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoC36H34(NO3)2 cluster. Co(1) is bonded in a distorted square co-planar geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Co(1)-O(1) bond lengths are 2.40 Å. Both Co(1)-O(2) bond lengths are 1.92 Å. Both Co(1)-O(3) bond lengths are 1.94 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(18), one C(2), and one C(6) atom. The C(1)-C(18) bond length is 1.49 Å. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(7) bond length is 1.48 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(4), one C(8), and one C(9) atom. The C(7)-C(8) bond length is 1.37 Å. The C(7)-C(9) bond length is 1.48 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(7) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(14) bond length is 1.41 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(10)-H(6) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(7) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(7) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(8) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(8) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(9) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(9) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(9), and one H(10) atom. The C(14)-H(10) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one N(1), one H(11), and one O(2) atom. The C(15)-N(1) bond length is 1.33 Å. The C(15)-H(11) bond length is 1.10 Å. The C(15)-O(2) bond length is 1.27 Å. In the sixteenth C site, C(16) is bonded to one N(1), one H(12), one H(13), and one H(14) atom to form corner-sharing CH3N tetrahedra. The C(16)-N(1) bond length is 1.46 Å. The C(16)-H(12) bond length is 1.10 Å. The C(16)-H(13) bond length is 1.10 Å. The C(16)-H(14) bond length is 1.10 Å. In the seventeenth C site, C(17) is bonded to one N(1), one H(15), one H(16), and one H(17) atom to form corner-sharing CH3N tetrahedra. The C(17)-N(1) bond length is 1.46 Å. The C(17)-H(15) bond length is 1.09 Å. The C(17)-H(16) bond length is 1.10 Å. The C(17)-H(17) bond length is 1.10 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(3) atom. The C(18)-O(1) bond length is 1.27 Å. The C(18)-O(3) bond length is 1.29 Å. N(1) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(17) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Co(1) and one C(18) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one C(15) atom. In the third O site, O(3) is bonded in a water-like geometry to one Co(1) and one C(18) atom. Linkers: 2 [CH]=[C]/C(=C/C=C(/c1ccccc1)c1ccc(C([O])=O)cc1)c1ccc(C([O])=O)cc1 ,1 [O]C(=O)c1ccc(/C(=C\C=C(\c2ccccc2)c2ccc(C([O])=O)cc2)c2ccccc2)cc1. Metal clusters: 1 [Co]. The MOF has largest included sphere 2.03 A, density 1.43 g/cm3, surface area 5120.43 m2/g, accessible volume 0.14 cm3/g