ZnC12H8(N4S)2(CH)4(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four 02329_fluka molecules, and two ZnC12H8(N4S)2 clusters. In each ZnC12H8(N4S)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(4), one N(7), and one N(8) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-N(4) bond length is 2.05 Å. The Zn(1)-N(7) bond length is 1.93 Å. The Zn(1)-N(8) bond length is 1.92 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-N(1) bond length is 1.38 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one N(3) atom. The C(6)-N(3) bond length is 1.37 Å. In the fifth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(5), and one H(6) atom. The C(7)-N(3) bond length is 1.46 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. In the sixth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(11), and one H(12) atom. The C(10)-N(6) bond length is 1.47 Å. The C(10)-H(11) bond length is 1.10 Å. The C(10)-H(12) bond length is 1.10 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one N(6) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(16) bond length is 1.41 Å. The C(11)-N(6) bond length is 1.37 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(13) atom. The C(12)-H(13) bond length is 1.09 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(16) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(16) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(11), one C(15), and one N(4) atom. The C(16)-N(4) bond length is 1.38 Å. In the eleventh C site, C(17) is bonded in a distorted linear geometry to one N(7) and one S(1) atom. The C(17)-N(7) bond length is 1.19 Å. The C(17)-S(1) bond length is 1.61 Å. In the twelfth C site, C(18) is bonded in a distorted linear geometry to one N(8) and one S(2) atom. The C(18)-N(8) bond length is 1.19 Å. The C(18)-S(2) bond length is 1.61 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.32 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.34 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(16), and one N(5) atom. The N(4)-N(5) bond length is 1.32 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.34 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one C(10), one C(11), and one N(5) atom. In the seventh N site, N(7) is bonded in a linear geometry to one Zn(1) and one C(17) atom. In the eighth N site, N(8) is bonded in a linear geometry to one Zn(1) and one C(18) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(15) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one C(17) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(18) atom. Linkers: 2 c1ccc2c(c1)nnn2CCCCn1nnc2ccccc21 ,2 [C][CH]c1[c]nnn1CCCCn1nnc2ccccc21 ,2 [CH]c1[c]nnn1CCCCn1nnc2ccccc21. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.23 A, density 1.56 g/cm3, surface area 5250.23 m2/g, accessible volume 0.17 cm3/g