KC16H19I(NO3)2CH(CH2)9 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, eighteen 02329_fluka molecules, and one KC16H19I(NO3)2 cluster. In the KC16H19I(NO3)2 cluster, K(1) is bonded in a 8-coordinate geometry to one H(25), one O(1), one O(3), one O(4), one O(5), one O(6), and two equivalent I(1) atoms. The K(1)-H(25) bond length is 3.09 Å. The K(1)-O(1) bond length is 2.76 Å. The K(1)-O(3) bond length is 2.81 Å. The K(1)-O(4) bond length is 2.93 Å. The K(1)-O(5) bond length is 2.75 Å. The K(1)-O(6) bond length is 2.98 Å. There is one shorter (3.48 Å) and one longer (3.63 Å) K(1)-I(1) bond length. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(13), one C(2), and one C(6) atom. The C(1)-C(13) bond length is 1.50 Å. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1,3) atom. The C(2)-H(1,3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one O(3) atom. The C(3)-O(3) bond length is 1.38 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one O(6) atom. The C(4)-O(6) bond length is 1.38 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(1,3) atom. The C(6)-H(1,3) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one H(4), one H(5), and one O(3) atom. The C(7)-H(4) bond length is 1.10 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-O(3) bond length is 1.45 Å. In the seventh C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one H(6), one H(7), and one O(4) atom. The C(8)-H(6) bond length is 1.11 Å. The C(8)-H(7) bond length is 1.11 Å. The C(8)-O(4) bond length is 1.43 Å. In the eighth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one H(8), one H(9), and one O(4) atom. The C(9)-H(8) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.11 Å. The C(9)-O(4) bond length is 1.43 Å. In the ninth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one H(10), one H(11), and one O(5) atom. The C(10)-H(10) bond length is 1.10 Å. The C(10)-H(11) bond length is 1.10 Å. The C(10)-O(5) bond length is 1.43 Å. In the tenth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one H(12), one H(13), and one O(5) atom. The C(11)-H(12) bond length is 1.10 Å. The C(11)-H(13) bond length is 1.10 Å. The C(11)-O(5) bond length is 1.43 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one H(14), one H(15), and one O(6) atom. The C(12)-H(14) bond length is 1.10 Å. The C(12)-H(15) bond length is 1.10 Å. The C(12)-O(6) bond length is 1.44 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one O(1) atom. The C(13)-N(1) bond length is 1.37 Å. The C(13)-O(1) bond length is 1.25 Å. In the thirteenth C site, C(14) is bonded in a distorted water-like geometry to one N(1) and one H(16) atom. The C(14)-N(1) bond length is 1.48 Å. The C(14)-H(16) bond length is 1.10 Å. In the fourteenth C site, C(19) is bonded in a distorted water-like geometry to one H(25) and one H(26) atom. The C(19)-H(25) bond length is 1.10 Å. The C(19)-H(26) bond length is 1.10 Å. In the fifteenth C site, C(20) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(2) atom. The C(20)-N(1) bond length is 1.45 Å. The C(20)-N(2) bond length is 1.34 Å. The C(20)-O(2) bond length is 1.24 Å. In the sixteenth C site, C(21) is bonded in a distorted water-like geometry to one N(2) and one H(27) atom. The C(21)-N(2) bond length is 1.46 Å. The C(21)-H(27) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(20) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(20), one C(21), and one H(38) atom. The N(2)-H(38) bond length is 1.03 Å. There are eighteen inequivalent H sites. In the first H site, H(1,3) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(12) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the fifteenth H site, H(25) is bonded in a single-bond geometry to one K(1) and one C(19) atom. In the sixteenth H site, H(26) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(27) is bonded in a single-bond geometry to one C(21) atom. In the eighteenth H site, H(38) is bonded in a single-bond geometry to one N(2) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one C(13) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(20) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one K(1), one C(3), and one C(7) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one K(1), one C(8), and one C(9) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one K(1), one C(10), and one C(11) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one K(1), one C(12), and one C(4) atom. I(1) is bonded in a distorted L-shaped geometry to two equivalent K(1) atoms. Linkers: 2 O=C(NC1CCCCC1)N(C(=O)c1ccc2c(c1)OCCOCCOCCO2)C1CCCCC1. Metal clusters: 2 [K]. The MOF has largest included sphere 2.63 A, density 1.52 g/cm3, surface area 4380.42 m2/g, accessible volume 0.19 cm3/g