CuC10H10(NO2)2(CH)2(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, eight 02329_fluka molecules, and one CuC10H10(NO2)2 cluster. In the CuC10H10(NO2)2 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-N(1) bond length is 2.22 Å. The Cu(1)-O(1) bond length is 2.00 Å. The Cu(1)-O(2) bond length is 2.00 Å. The Cu(1)-O(3) bond length is 2.00 Å. The Cu(1)-O(4) bond length is 2.01 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.27 Å. In the third C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(11) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(11) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(12) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(12) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(14) bond length is 1.51 Å. In the sixth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(13) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(13) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one N(1), and one H(14) atom. The C(13)-N(1) bond length is 1.34 Å. The C(13)-H(14) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one N(2), one H(15), and one H(16) atom. The C(14)-N(2) bond length is 1.45 Å. The C(14)-H(15) bond length is 1.10 Å. The C(14)-H(16) bond length is 1.11 Å. In the ninth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(17), and one H(18) atom. The C(15)-N(2) bond length is 1.46 Å. The C(15)-H(17) bond length is 1.10 Å. The C(15)-H(18) bond length is 1.11 Å. In the tenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(19), and one H(20) atom. The C(16)-N(2) bond length is 1.46 Å. The C(16)-H(19) bond length is 1.12 Å. The C(16)-H(20) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one C(14), one C(15), and one C(16) atom. There are ten inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(16) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(8) atom. Linkers: 1 c1cc(CN2CCN(Cc3ccncc3)CC2)ccn1 ,2 [O]C(=O)[C@H]1CC[C@@H](C([O])=O)CC1. Metal clusters: 1 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 3.35 A, density 1.49 g/cm3, surface area 4511.93 m2/g, accessible volume 0.18 cm3/g