AgC7NH5O2CH is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and four AgC7NH5O2 clusters. In each AgC7NH5O2 cluster, Ag(1) is bonded in a linear geometry to one N(1) and one O(2) atom. The Ag(1)-N(1) bond length is 2.12 Å. The Ag(1)-O(2) bond length is 2.14 Å. There are seven inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(1) bond length is 1.39 Å. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.46 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(8)-O(1) bond length is 1.26 Å. The C(8)-O(2) bond length is 1.30 Å. In the seventh C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(8) atom. In the second O site, O(2) is bonded in a water-like geometry to one Ag(1) and one C(8) atom. Linkers: 2 [O]C(=O)/C=C/c1ccncc1. Metal clusters: 4 O=[C]O[Ag]. The MOF has largest included sphere 1.54 A, density 2.35 g/cm3, surface area 3318.89 m2/g, accessible volume 0.08 cm3/g