CuC15N2H12O5(CH)3(CH2)3CH2CO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, six 02329_fluka molecules, two dimethyl ether molecules, and one CuC15N2H12O5 cluster. In the CuC15N2H12O5 cluster, Cu(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(5), and one O(6) atom. The Cu(1)-N(1) bond length is 2.12 Å. The Cu(1)-O(1) bond length is 2.03 Å. The Cu(1)-O(2) bond length is 2.03 Å. The Cu(1)-O(5) bond length is 2.00 Å. The Cu(1)-O(6) bond length is 1.98 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(4) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(2), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(7), and one H(3) atom. The C(5)-C(7) bond length is 1.40 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one O(3) atom. The C(7)-O(3) bond length is 1.36 Å. In the seventh C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(6), and one O(3) atom. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-O(3) bond length is 1.44 Å. In the eighth C site, C(15) is bonded in a distorted single-bond geometry to one C(17) and one H(15) atom. The C(15)-C(17) bond length is 1.41 Å. The C(15)-H(15) bond length is 1.09 Å. In the ninth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(16) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(16) bond length is 1.09 Å. In the tenth C site, C(17) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(18) atom. The C(17)-C(18) bond length is 1.49 Å. In the eleventh C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(5), and one O(6) atom. The C(18)-O(5) bond length is 1.28 Å. The C(18)-O(6) bond length is 1.28 Å. In the twelfth C site, C(19) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(17) atom. The C(19)-N(1) bond length is 1.33 Å. The C(19)-N(2) bond length is 1.36 Å. The C(19)-H(17) bond length is 1.09 Å. In the thirteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(1), and one H(18) atom. The C(20)-C(21) bond length is 1.38 Å. The C(20)-N(1) bond length is 1.38 Å. The C(20)-H(18) bond length is 1.08 Å. In the fourteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(2), and one H(19) atom. The C(21)-N(2) bond length is 1.38 Å. The C(21)-H(19) bond length is 1.08 Å. In the fifteenth C site, C(22) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(20), and one H(21) atom. The C(22)-N(2) bond length is 1.46 Å. The C(22)-H(20) bond length is 1.10 Å. The C(22)-H(21) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(19), and one C(20) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(22) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(22) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(7) and one C(8) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(18) atom. In the fifth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(18) atom. Linkers: 1 c1cn(CCCCn2ccnc2)cn1 ,2 [O]C(=O)c1ccc(OCCCCOc2ccc(C([O])=O)cc2)cc1. Metal clusters: 1 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 2.88 A, density 1.44 g/cm3, surface area 4969.52 m2/g, accessible volume 0.20 cm3/g