AgC12N3H12O5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one AgC12N3H12O5 cluster. Ag(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one O(2) atom. The Ag(1)-N(1) bond length is 2.22 Å. The Ag(1)-N(3) bond length is 2.28 Å. The Ag(1)-O(2) bond length is 2.30 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(7) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(3) bond length is 1.41 Å. The C(1)-C(7) bond length is 1.47 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(1), one C(2), and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(10), one C(5), and one C(6) atom. The C(4)-C(10) bond length is 1.47 Å. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one O(1) atom. The C(7)-N(1) bond length is 1.29 Å. The C(7)-O(1) bond length is 1.36 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(5), and one H(6) atom. The C(8)-N(1) bond length is 1.48 Å. The C(8)-H(5) bond length is 1.10 Å. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one H(7), one H(8), and one O(1) atom. The C(9)-H(7) bond length is 1.10 Å. The C(9)-H(8) bond length is 1.09 Å. The C(9)-O(1) bond length is 1.47 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(3), and one O(5) atom. The C(10)-N(3) bond length is 1.29 Å. The C(10)-O(5) bond length is 1.36 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(3) and two equivalent H(9,10) atoms. The C(11)-N(3) bond length is 1.48 Å. Both C(11)-H(9,10) bond lengths are 1.10 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one H(11), one H(12), and one O(5) atom. The C(12)-H(11) bond length is 1.10 Å. The C(12)-H(12) bond length is 1.10 Å. The C(12)-O(5) bond length is 1.47 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(7), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(4) atom. The N(2)-O(2) bond length is 1.31 Å. The N(2)-O(3) bond length is 1.25 Å. The N(2)-O(4) bond length is 1.26 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(10), and one C(11) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(9,10) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(12) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(7) and one C(9) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Ag(1) and one N(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one C(10) and one C(12) atom. Linkers: 2 c1cc(C2=NCCO2)ccc1C1=NCCO1. Metal clusters: 2 O=[N+]([O-])O[Ag]. The MOF has largest included sphere 1.62 A, density 2.02 g/cm3, surface area 3771.54 m2/g, accessible volume 0.07 cm3/g