(CH)3CH2HgC5H6SBr2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two 02329_fluka molecules, and one HgC5H6SBr2 cluster. In the HgC5H6SBr2 cluster, Hg(1) is bonded to one S(1), one Br(2), and two equivalent Br(1) atoms to form edge-sharing HgSBr3 trigonal pyramids. The Hg(1)-S(1) bond length is 2.59 Å. The Hg(1)-Br(2) bond length is 2.61 Å. There is one shorter (2.59 Å) and one longer (2.96 Å) Hg(1)-Br(1) bond length. There are five inequivalent C sites. In the first C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(5) bond length is 1.09 Å. In the second C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(1) bond length is 1.40 Å. The C(6)-C(7) bond length is 1.50 Å. In the third C site, C(7) is bonded in a distorted water-like geometry to one C(6), one H(6), one H(7), and one S(1) atom. The C(7)-H(6) bond length is 1.10 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-S(1) bond length is 1.84 Å. In the fourth C site, C(8) is bonded in a distorted water-like geometry to one H(8), one H(9), and one S(1) atom. The C(8)-H(8) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. The C(8)-S(1) bond length is 1.82 Å. In the fifth C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one H(1) atom. The C(1)-H(1) bond length is 1.09 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. S(1) is bonded in a trigonal non-coplanar geometry to one Hg(1), one C(7), and one C(8) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to two equivalent Hg(1) atoms. In the second Br site, Br(2) is bonded in a single-bond geometry to one Hg(1) atom. Linkers: 1 c1ccc(CSCCCCSCc2ccccc2)cc1. Metal clusters: 2 [Hg]. The MOF has largest included sphere 1.73 A, density 2.89 g/cm3, surface area 2876.29 m2/g, accessible volume 0.10 cm3/g