CuC24N5H14O4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CuC24N5H14O4 cluster. Cu(1) is bonded in a square pyramidal geometry to one N(1), one N(3), one N(4), one O(2), and one O(3) atom. The Cu(1)-N(1) bond length is 2.05 Å. The Cu(1)-N(3) bond length is 1.94 Å. The Cu(1)-N(4) bond length is 2.04 Å. The Cu(1)-O(2) bond length is 2.16 Å. The Cu(1)-O(3) bond length is 1.96 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(2), and one H(2) atom. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-N(2) bond length is 1.34 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.47 Å. The C(4)-N(1) bond length is 1.36 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one N(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(3) bond length is 1.34 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(4) atom. The C(6)-C(7) bond length is 1.41 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(14), one C(6), and one C(8) atom. The C(7)-C(14) bond length is 1.47 Å. The C(7)-C(8) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(5) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(5) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one N(3) atom. The C(9)-C(10) bond length is 1.47 Å. The C(9)-N(3) bond length is 1.34 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one N(4) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-N(4) bond length is 1.36 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(5), and one H(6) atom. The C(11)-N(5) bond length is 1.34 Å. The C(11)-H(6) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(5), and one H(7) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-N(5) bond length is 1.34 Å. The C(12)-H(7) bond length is 1.10 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one N(4), and one H(8) atom. The C(13)-N(4) bond length is 1.33 Å. The C(13)-H(8) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(7) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-C(19) bond length is 1.41 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(9,12) atom. The C(15)-H(9,12) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(10) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(10) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(20) bond length is 1.51 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(11) atom. The C(18)-H(11) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(9,12) atom. The C(19)-H(9,12) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(1), and one O(2) atom. The C(20)-O(1) bond length is 1.26 Å. The C(20)-O(2) bond length is 1.29 Å. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(3), and one O(4) atom. The C(21)-C(23) bond length is 1.51 Å. The C(21)-O(3) bond length is 1.30 Å. The C(21)-O(4) bond length is 1.25 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(23), one C(24), and one H(13) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(24) bond length is 1.39 Å. The C(22)-H(13) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(21), one C(22), and one C(24) atom. The C(23)-C(24) bond length is 1.40 Å. In the twenty-fourth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(22), one C(23), and one H(14) atom. The C(24)-H(14) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(5), and one C(9) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(13) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(11) and one C(12) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(9,12) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(20) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(20) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(21) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(21) atom. Linkers: 2 [O]C(=O)c1ccc(-c2cc(-c3cnccn3)nc(-c3cnccn3)c2)cc1 ,1 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 3.43 A, density 1.57 g/cm3, surface area 3956.34 m2/g, accessible volume 0.19 cm3/g