NaC8NH9O5(CH)2CH2C2H5S is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 02329_fluka molecules, two dimethyl sulfide molecules, and one NaC8NH9O5 cluster. In the NaC8NH9O5 cluster, Na(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(5), and two equivalent O(2) atoms. The Na(1)-O(1) bond length is 2.36 Å. The Na(1)-O(3) bond length is 2.42 Å. The Na(1)-O(5) bond length is 2.32 Å. There is one shorter (2.37 Å) and one longer (2.47 Å) Na(1)-O(2) bond length. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one O(3) atom. The C(1)-O(3) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(5) and one H(1) atom. The C(2)-C(5) bond length is 1.42 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted water-like geometry to one N(1) and one H(2) atom. The C(3)-N(1) bond length is 1.45 Å. The C(3)-H(2) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(4)-O(2) bond length is 1.28 Å. The C(4)-O(4) bond length is 1.26 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(7) atom. The C(5)-C(10) bond length is 1.41 Å. The C(5)-C(7) bond length is 1.45 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one O(1) atom. The C(7)-O(1) bond length is 1.29 Å. In the seventh C site, C(9) is bonded in a tetrahedral geometry to one H(6), one H(7), one H(8), and one O(3) atom. The C(9)-H(6) bond length is 1.10 Å. The C(9)-H(7) bond length is 1.09 Å. The C(9)-H(8) bond length is 1.10 Å. The C(9)-O(3) bond length is 1.44 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(1), and one H(9) atom. The C(10)-N(1) bond length is 1.32 Å. The C(10)-H(9) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one C(10), one C(3), and one H(16) atom. The N(1)-H(16) bond length is 1.04 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one N(1) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one O(5) atom. The H(17)-O(5) bond length is 0.98 Å. In the ninth H site, H(18) is bonded in a distorted single-bond geometry to one O(4) and one O(5) atom. The H(18)-O(4) bond length is 1.67 Å. The H(18)-O(5) bond length is 1.00 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Na(1) and one C(7) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one C(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Na(1), one C(1), and one C(9) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one C(4) and one H(18) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Na(1), one H(17), and one H(18) atom. Linkers: 2 [CH2]SCC[C](/[NH]=C/c1cccc(c1[O])O[C])[C]=O ,1 CSCC[C@H](C(=O)[O])/[NH]=C/c1cccc(c1[O])O[C] ,1 CSCC[C@@H](C(=O)[O])/[NH]=C/c1cccc(c1[O])O[C] ,1 CSCC[C@H](C(=O)[O])/[NH]=C/C1=C([O])[C]=CC=C1 ,1 CSCC[C@@H](C(=O)[O])/[NH]=C/C1=CC=C[C]=C1[O]. Metal clusters: 1 CO[C][C][O].CO[C][C][O].O.O.[Na].[Na].[O][C]=O.[O][C]=O. The MOF has largest included sphere 1.99 A, density 1.46 g/cm3, surface area 4786.79 m2/g, accessible volume 0.09 cm3/g