Cd2C6N13H7O crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one N(12), one N(2), one N(3), one N(9), and two equivalent O(1) atoms to form CdN4O2 octahedra that share corners with two equivalent Cd(2)N5O octahedra and  an edgeedge with one Cd(1)N4O2 octahedra. The corner-sharing octahedral tilt angles range from 57-72°. The Cd(1)-N(12) bond length is 2.37 Å. The Cd(1)-N(2) bond length is 2.54 Å. The Cd(1)-N(3) bond length is 2.47 Å. The Cd(1)-N(9) bond length is 2.33 Å. There is one shorter (2.29 Å) and one longer (2.31 Å) Cd(1)-O(1) bond length. In the second Cd site, Cd(2) is bonded to one N(1), one N(10), one N(11), one N(4), one N(6), and one O(1) atom to form corner-sharing CdN5O octahedra. The corner-sharing octahedral tilt angles range from 57-72°. The Cd(2)-N(1) bond length is 2.38 Å. The Cd(2)-N(10) bond length is 2.39 Å. The Cd(2)-N(11) bond length is 2.55 Å. The Cd(2)-N(4) bond length is 2.42 Å. The Cd(2)-N(6) bond length is 2.35 Å. The Cd(2)-O(1) bond length is 2.33 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one N(4) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(4) bond length is 1.34 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one N(5), one H(1), and one H(2) atom. The C(2)-N(5) bond length is 1.46 Å. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(6), and one N(9) atom. The C(3)-C(4) bond length is 1.49 Å. The C(3)-N(6) bond length is 1.34 Å. The C(3)-N(9) bond length is 1.34 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one N(5), one H(3), and one H(4) atom. The C(4)-N(5) bond length is 1.47 Å. The C(4)-H(3) bond length is 1.10 Å. The C(4)-H(4) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(10), and one N(13) atom. The C(5)-C(6) bond length is 1.49 Å. The C(5)-N(10) bond length is 1.35 Å. The C(5)-N(13) bond length is 1.34 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one N(5), one H(5), and one H(6) atom. The C(6)-N(5) bond length is 1.45 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. There are thirteen inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.34 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one N(1), and one N(3) atom. The N(2)-N(3) bond length is 1.32 Å. In the third N site, N(3) is bonded in a trigonal non-coplanar geometry to one Cd(1), one N(2), and one N(4) atom. The N(3)-N(4) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(1), and one N(3) atom. In the fifth N site, N(5) is bonded in a trigonal non-coplanar geometry to one C(2), one C(4), and one C(6) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(3), and one N(7) atom. The N(6)-N(7) bond length is 1.35 Å. In the seventh N site, N(7) is bonded in a water-like geometry to one N(6) and one N(8) atom. The N(7)-N(8) bond length is 1.31 Å. In the eighth N site, N(8) is bonded in a water-like geometry to one N(7) and one N(9) atom. The N(8)-N(9) bond length is 1.36 Å. In the ninth N site, N(9) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(3), and one N(8) atom. In the tenth N site, N(10) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(5), and one N(11) atom. The N(10)-N(11) bond length is 1.34 Å. In the eleventh N site, N(11) is bonded in a trigonal non-coplanar geometry to one Cd(2), one N(10), and one N(12) atom. The N(11)-N(12) bond length is 1.32 Å. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Cd(1), one N(11), and one N(13) atom. The N(12)-N(13) bond length is 1.34 Å. In the thirteenth N site, N(13) is bonded in a distorted water-like geometry to one C(5) and one N(12) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(1) atom. The H(7)-O(1) bond length is 0.99 Å. O(1) is bonded in a distorted single-bond geometry to one Cd(2), two equivalent Cd(1), and one H(7) atom. Linkers: 4 C(C1=NN=N[N]1)N(CC1=NN=N[N]1)CC1=NN=N[N]1. Metal clusters: 8 [Cd]. The MOF has largest included sphere 1.89 A, density 2.81 g/cm3, surface area 2486.22 m2/g, accessible volume 0.04 cm3/g