(CH)3CuC7N3H7OBrCuC8N3H8OBr is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, one CuC7N3H7OBr cluster, and one CuC8N3H8OBr cluster. In the CuC7N3H7OBr cluster, Cu(1) is bonded in a 5-coordinate geometry to one C(17), one C(18), one N(3), and two equivalent Br(1) atoms. The Cu(1)-C(17) bond length is 2.04 Å. The Cu(1)-C(18) bond length is 2.03 Å. The Cu(1)-N(3) bond length is 1.99 Å. There is one shorter (2.39 Å) and one longer (3.00 Å) Cu(1)-Br(1) bond length. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one N(3) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.42 Å. The C(1)-N(3) bond length is 1.38 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one N(1) atom. The C(6)-N(1) bond length is 1.36 Å. In the fifth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(6), and one O(1) atom. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. The C(7)-O(1) bond length is 1.48 Å. In the sixth C site, C(17) is bonded in a distorted single-bond geometry to one Cu(1) and one H(16) atom. The C(17)-H(16) bond length is 1.10 Å. In the seventh C site, C(18) is bonded in a distorted bent 120 degrees geometry to one Cu(1), one H(17), and one H(18) atom. The C(18)-H(17) bond length is 1.09 Å. The C(18)-H(18) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(6), one N(2), and one O(1) atom. The N(1)-N(2) bond length is 1.33 Å. The N(1)-O(1) bond length is 1.37 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.33 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one N(2) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(18) atom. O(1) is bonded in a water-like geometry to one C(7) and one N(1) atom. Br(1) is bonded in a distorted L-shaped geometry to two equivalent Cu(1) atoms. In the CuC8N3H8OBr cluster, Cu(2) is bonded in a 5-coordinate geometry to one C(8), one C(9), one N(4), and two equivalent Br(2) atoms. The Cu(2)-C(8) bond length is 2.08 Å. The Cu(2)-C(9) bond length is 2.06 Å. The Cu(2)-N(4) bond length is 2.03 Å. There is one shorter (2.42 Å) and one longer (2.71 Å) Cu(2)-Br(2) bond length. There are eight inequivalent C sites. In the first C site, C(8) is bonded in a distorted single-bond geometry to one Cu(2) and one H(7) atom. The C(8)-H(7) bond length is 1.09 Å. In the second C site, C(9) is bonded in a distorted bent 120 degrees geometry to one Cu(2), one H(8), and one H(9) atom. The C(9)-H(8) bond length is 1.09 Å. The C(9)-H(9) bond length is 1.09 Å. In the third C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(15), and one N(6) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.42 Å. The C(10)-N(6) bond length is 1.37 Å. In the fourth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(10) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(10) bond length is 1.09 Å. In the fifth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(11) atom. The C(12)-H(11) bond length is 1.09 Å. In the sixth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(13) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(13) bond length is 1.09 Å. In the seventh C site, C(15) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one N(4) atom. The C(15)-N(4) bond length is 1.38 Å. In the eighth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one H(14), one H(15), and one O(2) atom. The C(16)-H(14) bond length is 1.10 Å. The C(16)-H(15) bond length is 1.10 Å. The C(16)-O(2) bond length is 1.49 Å. There are three inequivalent N sites. In the first N site, N(4) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(15), and one N(5) atom. The N(4)-N(5) bond length is 1.32 Å. In the second N site, N(5) is bonded in a water-like geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.34 Å. In the third N site, N(6) is bonded in a distorted trigonal planar geometry to one C(10), one N(5), and one O(2) atom. The N(6)-O(2) bond length is 1.37 Å. There are eight inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. O(2) is bonded in a water-like geometry to one C(16) and one N(6) atom. Br(2) is bonded in a distorted L-shaped geometry to two equivalent Cu(2) atoms. Linkers: 1 [CH]COn1nnc2ccccc21 ,2 C=CCOn1nnc2ccccc21. Metal clusters: 1 [Br].[CH]C[Cu] ,3 [Cu]. The MOF has largest included sphere 1.80 A, density 2.13 g/cm3, surface area 3782.02 m2/g, accessible volume 0.08 cm3/g