CoC14H12(N2O3)2(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and one CoC14H12(N2O3)2 cluster. In the CoC14H12(N2O3)2 cluster, Co(1) is bonded in a distorted octahedral geometry to one N(1), one N(3), one O(3), one O(4), one O(5), and one O(6) atom. The Co(1)-N(1) bond length is 2.11 Å. The Co(1)-N(3) bond length is 2.10 Å. The Co(1)-O(3) bond length is 2.27 Å. The Co(1)-O(4) bond length is 2.20 Å. The Co(1)-O(5) bond length is 2.01 Å. The Co(1)-O(6) bond length is 1.99 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(5) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(5) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(6) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(6) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.50 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(7) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(7) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(8) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(8) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one O(1) atom. The C(6)-N(2) bond length is 1.35 Å. The C(6)-O(1) bond length is 1.24 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(3), and one H(9) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-N(3) bond length is 1.35 Å. The C(7)-H(9) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(10) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(10) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(12) bond length is 1.50 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(11) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(11) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(3), and one H(12) atom. The C(11)-N(3) bond length is 1.35 Å. The C(11)-H(12) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(4), and one O(2) atom. The C(12)-N(4) bond length is 1.34 Å. The C(12)-O(2) bond length is 1.26 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(13)-O(3) bond length is 1.28 Å. The C(13)-O(4) bond length is 1.27 Å. In the fourteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(18)-O(5) bond length is 1.28 Å. The C(18)-O(6) bond length is 1.27 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(6), one H(1), and one H(2) atom. The N(2)-H(1) bond length is 1.02 Å. The N(2)-H(2) bond length is 1.03 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(11), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(12), one H(3), and one H(4) atom. The N(4)-H(3) bond length is 1.04 Å. The N(4)-H(4) bond length is 1.01 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(12) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Co(1) and one C(13) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Co(1) and one C(13) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(18) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Co(1) and one C(18) atom. Linkers: 2 [O]C(=O)CCCCC([O])=O. Metal clusters: 2 [Co]. The MOF has largest included sphere 4.69 A, density 1.33 g/cm3, surface area 4485.06 m2/g, accessible volume 0.28 cm3/g