ZnC15H12(NO)4(CH2)3C7H4O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, four 27132-81-6 molecules, and four ZnC15H12(NO)4 clusters. In each ZnC15H12(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(5), one N(7), one O(1), and one O(8) atom. The Zn(1)-N(5) bond length is 2.04 Å. The Zn(1)-N(7) bond length is 2.02 Å. The Zn(1)-O(1) bond length is 1.95 Å. The Zn(1)-O(8) bond length is 1.97 Å. There are fifteen inequivalent C sites. In the first C site, C(19) is bonded in a distorted trigonal planar geometry to one C(21), one C(29), and one N(1) atom. The C(19)-C(21) bond length is 1.40 Å. The C(19)-C(29) bond length is 1.40 Å. The C(19)-N(1) bond length is 1.42 Å. In the second C site, C(21) is bonded in a distorted single-bond geometry to one C(19) and one H(23) atom. The C(21)-H(23) bond length is 1.09 Å. In the third C site, C(29) is bonded in a distorted single-bond geometry to one C(19) and one H(29) atom. The C(29)-H(29) bond length is 1.09 Å. In the fourth C site, C(37,38) is bonded in a distorted single-bond geometry to one C(39) and one H(33,35) atom. The C(37,38)-C(39) bond length is 1.40 Å. The C(37,38)-H(33,35) bond length is 1.09 Å. In the fifth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(37,38); one C(41,42); and one N(3,4) atom. The C(39)-C(41,42) bond length is 1.40 Å. The C(39)-N(3,4) bond length is 1.42 Å. In the sixth C site, C(41,42) is bonded in a distorted single-bond geometry to one C(39) and one H(33,35) atom. The C(41,42)-H(33,35) bond length is 1.09 Å. In the seventh C site, C(45) is bonded in a trigonal planar geometry to one N(3,4); one N(5); and one H(39,40) atom. The C(45)-N(3,4) bond length is 1.37 Å. The C(45)-N(5) bond length is 1.32 Å. The C(45)-H(39,40) bond length is 1.09 Å. In the eighth C site, C(47,48) is bonded in a distorted bent 120 degrees geometry to one C(49); one N(5); and one H(41,42) atom. The C(47,48)-C(49) bond length is 1.37 Å. The C(47,48)-N(5) bond length is 1.39 Å. The C(47,48)-H(41,42) bond length is 1.08 Å. In the ninth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(47,48); one N(3,4); and one H(43,44) atom. The C(49)-N(3,4) bond length is 1.40 Å. The C(49)-H(43,44) bond length is 1.08 Å. In the tenth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.53 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(3) bond length is 1.25 Å. In the eleventh C site, C(3) is bonded in a distorted water-like geometry to one C(1); one H(1,2); and one H(3,4) atom. The C(3)-H(1,2) bond length is 1.10 Å. The C(3)-H(3,4) bond length is 1.10 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(8) atom. The C(12)-O(6) bond length is 1.25 Å. The C(12)-O(8) bond length is 1.31 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one N(1); one N(7); and one H(17,18) atom. The C(13)-N(1) bond length is 1.37 Å. The C(13)-N(7) bond length is 1.33 Å. The C(13)-H(17,18) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(17); one N(7); and one H(19,20) atom. The C(15)-C(17) bond length is 1.37 Å. The C(15)-N(7) bond length is 1.39 Å. The C(15)-H(19,20) bond length is 1.08 Å. In the fifteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(15), one N(1), and one H(21) atom. The C(17)-N(1) bond length is 1.39 Å. The C(17)-H(21) bond length is 1.08 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(19) atom. In the second N site, N(3,4) is bonded in a trigonal planar geometry to one C(39), one C(45), and one C(49) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Zn(1); one C(45); and one C(47,48) atom. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(15) atom. There are eleven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(17,18) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(19,20) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(21) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(23) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(29) is bonded in a single-bond geometry to one C(29) atom. In the eighth H site, H(33,35) is bonded in a single-bond geometry to one C(37,38) atom. In the ninth H site, H(39,40) is bonded in a single-bond geometry to one C(45) atom. In the tenth H site, H(41,42) is bonded in a single-bond geometry to one C(47,48) atom. In the eleventh H site, H(43,44) is bonded in a single-bond geometry to one C(49) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(6) is bonded in a single-bond geometry to one C(12) atom. In the fourth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(12) atom. Linkers: 4 [O]C(=O)CCCCC([O])=O ,2 O=C(c1ccc(-n2ccnc2)cc1)c1ccc(-n2ccnc2)cc1. Metal clusters: 4 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.67 A, density 1.41 g/cm3, surface area 4780.87 m2/g, accessible volume 0.22 cm3/g