InC24N2H14O5 crystallizes in the orthorhombic Cmmm space group. In(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles are 60°. Both In(1)-O(2) bond lengths are 2.11 Å. All In(1)-O(1) bond lengths are 2.19 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(4) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.49 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(1) atom. The C(2)-C(3) bond length is 1.46 Å. The C(2)-N(1) bond length is 1.37 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one N(2) atom. The C(4)-C(5) bond length is 1.44 Å. The C(4)-N(2) bond length is 1.38 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 1.08 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(1) and two equivalent C(7) atoms. Both C(6)-C(7) bond lengths are 1.40 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(6) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10) and two equivalent C(8) atoms. The C(9)-C(10) bond length is 1.50 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(9) and two equivalent O(1) atoms. Both C(10)-O(1) bond lengths are 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to two equivalent C(2) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to two equivalent C(4) and one H(2) atom. The N(2)-H(2) bond length is 1.02 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 0.97 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one In(1) and one C(10) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent In(1) and one H(1) atom. Linkers: 1 [O]C(=O)c1ccc(-c2c3nc(c(-c4ccc(C([O])=O)cc4)c4ccc([nH]4)c(-c4ccc(C([O])=O)cc4)c4nc(c(-c5ccc(C([O])=O)cc5)c5ccc2[nH]5)C=C4)C=C3)cc1. Metal clusters: 2 [In]. RCSR code: scu. The MOF has largest included sphere 8.06 A, density 0.84 g/cm3, surface area 4048.14 m2/g, accessible volume 0.76 cm3/g