AgC7N2H6S4O3 crystallizes in the orthorhombic P2_12_12 space group. Ag(1) is bonded in a 7-coordinate geometry to one N(1), one S(3), one S(4), one O(2), one O(3), and two equivalent O(1) atoms. The Ag(1)-N(1) bond length is 2.27 Å. The Ag(1)-S(3) bond length is 2.71 Å. The Ag(1)-S(4) bond length is 2.72 Å. The Ag(1)-O(2) bond length is 2.55 Å. The Ag(1)-O(3) bond length is 2.65 Å. There is one shorter (2.63 Å) and one longer (2.82 Å) Ag(1)-O(1) bond length. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(4), one S(1), and one S(2) atom. The C(1)-C(4) bond length is 1.40 Å. The C(1)-S(1) bond length is 1.73 Å. The C(1)-S(2) bond length is 1.72 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(3), one S(1), and one S(3) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-S(1) bond length is 1.74 Å. The C(2)-S(3) bond length is 1.73 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one S(2), and one S(4) atom. The C(3)-S(2) bond length is 1.75 Å. The C(3)-S(4) bond length is 1.74 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(5) atom. The C(4)-C(4) bond length is 1.49 Å. The C(4)-C(5) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted linear geometry to one C(4) and one N(1) atom. The C(5)-N(1) bond length is 1.18 Å. In the sixth C site, C(6) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(3) atom. The C(6)-H(1) bond length is 1.10 Å. The C(6)-H(2) bond length is 1.10 Å. The C(6)-H(3) bond length is 1.10 Å. The C(6)-S(3) bond length is 1.81 Å. In the seventh C site, C(7) is bonded in a trigonal non-coplanar geometry to one H(4), one H(5), one H(6), and one S(4) atom. The C(7)-H(4) bond length is 1.09 Å. The C(7)-H(5) bond length is 1.09 Å. The C(7)-H(6) bond length is 1.10 Å. The C(7)-S(4) bond length is 1.82 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(2)-O(1) bond length is 1.27 Å. The N(2)-O(2) bond length is 1.27 Å. The N(2)-O(3) bond length is 1.27 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(1) and one C(2) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one C(1) and one C(3) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(2), and one C(6) atom. In the fourth S site, S(4) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one C(3), and one C(7) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one N(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Ag(1) and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(1) and one N(2) atom. Linkers: 2 CSC1=C(SC)SC(=C(C#N)C(C#N)=C2SC(SC)=C(SC)S2)S1 ,2 CSC1=[C]S/C(=C(C#N)\C(C#N)=C2/S[C]=C(SC)S2)S1 ,2 [C]C(=C1SC(SC)=C(SC)S1)C([C])=C1SC(SC)=C(SC)S1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.87 A, density 2.24 g/cm3, surface area 3217.84 m2/g, accessible volume 0.07 cm3/g