ZnC12H6(NO2)2(CH)6(CH2CO)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules, eight dimethyl ether molecules, and four ZnC12H6(NO2)2 clusters. In each ZnC12H6(NO2)2 cluster, Zn(1) is bonded in a distorted octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. Both Zn(1)-N(1) bond lengths are 2.11 Å. Both Zn(1)-O(1) bond lengths are 2.24 Å. Both Zn(1)-O(2) bond lengths are 2.17 Å. There are six inequivalent C sites. In the first C site, C(8) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(8)-C(10) bond length is 1.41 Å. The C(8)-H(7) bond length is 1.09 Å. In the second C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(9)-C(10) bond length is 1.43 Å. The C(9)-H(8) bond length is 1.09 Å. In the third C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(8), and one C(9) atom. The C(10)-C(11) bond length is 1.42 Å. In the fourth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(11), and one N(1) atom. The C(11)-C(11) bond length is 1.44 Å. The C(11)-N(1) bond length is 1.36 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(5)-O(1) bond length is 1.28 Å. The C(5)-O(2) bond length is 1.27 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(6)-N(1) bond length is 1.33 Å. The C(6)-H(5) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(6) atom. There are three inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Zn(1) and one C(5) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Zn(1) and one C(5) atom. Linkers: 2 [O]C(=O)COc1ccc(OCC([O])=O)cc1. Metal clusters: 2 [C]1O[Zn]2(O1)O[C]O2. The MOF has largest included sphere 2.07 A, density 1.63 g/cm3, surface area 4551.71 m2/g, accessible volume 0.18 cm3/g