NiC8P2H12S4(NO2)2(CH3)4SC6H4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two dii-propenyl sulfide molecules, and two NiC8P2H12S4(NO2)2 clusters. In one of the NiC8P2H12S4(NO2)2 clusters, Ni(1) is bonded to two equivalent N(1), two equivalent S(1), and two equivalent S(2) atoms to form distorted NiS4N2 octahedra that share edges with two equivalent P(1)S2O2 tetrahedra. Both Ni(1)-N(1) bond lengths are 2.07 Å. Both Ni(1)-S(1) bond lengths are 2.47 Å. Both Ni(1)-S(2) bond lengths are 2.46 Å. There are four inequivalent C sites. In the first C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one H(6), one H(7), and one O(2) atom. The C(3)-H(6) bond length is 1.10 Å. The C(3)-H(7) bond length is 1.10 Å. The C(3)-O(2) bond length is 1.46 Å. In the second C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(21) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(21) bond length is 1.09 Å. In the third C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(24) atom. The C(13)-N(1) bond length is 1.35 Å. The C(13)-H(24) bond length is 1.09 Å. In the fourth C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one O(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-O(1) bond length is 1.46 Å. P(1) is bonded to one S(1), one S(2), one O(1), and one O(2) atom to form distorted PS2O2 tetrahedra that share  an edgeedge with one Ni(1)S4N2 octahedra. The P(1)-S(1) bond length is 1.99 Å. The P(1)-S(2) bond length is 2.00 Å. The P(1)-O(1) bond length is 1.61 Å. The P(1)-O(2) bond length is 1.60 Å. N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(13), and one C(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(21) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(24) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Ni(1) and one P(1) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Ni(1) and one P(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(3) and one P(1) atom. In one of the NiC8P2H12S4(NO2)2 clusters, Ni(2) is bonded to two equivalent N(2), two equivalent S(3), and two equivalent S(4) atoms to form distorted NiS4N2 octahedra that share edges with two equivalent P(2)S2O2 tetrahedra. Both Ni(2)-N(2) bond lengths are 2.07 Å. Both Ni(2)-S(3) bond lengths are 2.48 Å. Both Ni(2)-S(4) bond lengths are 2.46 Å. There are four inequivalent C sites. In the first C site, C(18) is bonded in a distorted trigonal planar geometry to one N(2) and one H(28) atom. The C(18)-N(2) bond length is 1.34 Å. The C(18)-H(28) bond length is 1.09 Å. In the second C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one H(11), one H(12), and one O(3) atom. The C(5)-H(11) bond length is 1.10 Å. The C(5)-H(12) bond length is 1.10 Å. The C(5)-O(3) bond length is 1.45 Å. In the third C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one H(16), one H(17), and one O(4) atom. The C(7)-H(16) bond length is 1.10 Å. The C(7)-H(17) bond length is 1.10 Å. The C(7)-O(4) bond length is 1.46 Å. In the fourth C site, C(14) is bonded in a distorted trigonal planar geometry to one N(2) and one H(25) atom. The C(14)-N(2) bond length is 1.35 Å. The C(14)-H(25) bond length is 1.09 Å. P(2) is bonded to one S(3), one S(4), one O(3), and one O(4) atom to form distorted PS2O2 tetrahedra that share  an edgeedge with one Ni(2)S4N2 octahedra. The P(2)-S(3) bond length is 1.99 Å. The P(2)-S(4) bond length is 2.00 Å. The P(2)-O(3) bond length is 1.61 Å. The P(2)-O(4) bond length is 1.61 Å. N(2) is bonded in a trigonal planar geometry to one Ni(2), one C(14), and one C(18) atom. There are six inequivalent H sites. In the first H site, H(16) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(17) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(28) is bonded in a single-bond geometry to one C(18) atom. In the fourth H site, H(25) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent S sites. In the first S site, S(3) is bonded in an L-shaped geometry to one Ni(2) and one P(2) atom. In the second S site, S(4) is bonded in an L-shaped geometry to one Ni(2) and one P(2) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one C(5) and one P(2) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one C(7) and one P(2) atom. Linkers: 2 c1cc(Sc2ccncc2)ccn1. Metal clusters: 2 [Ni]. The MOF has largest included sphere 2.38 A, density 1.58 g/cm3, surface area 4766.65 m2/g, accessible volume 0.13 cm3/g