(CH)3C2NH5Cu2C15H17S2(OI)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules, eight dimethylamine molecules, and four Cu2C15H17S2(OI)2 clusters. In each Cu2C15H17S2(OI)2 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 4-coordinate geometry to two equivalent Cu(2), one S(2), one I(1), and two equivalent I(2) atoms. There is one shorter (2.60 Å) and one longer (2.61 Å) Cu(1)-Cu(2) bond length. The Cu(1)-S(2) bond length is 2.27 Å. The Cu(1)-I(1) bond length is 2.65 Å. There is one shorter (2.73 Å) and one longer (2.74 Å) Cu(1)-I(2) bond length. In the second Cu site, Cu(2) is bonded in a 7-coordinate geometry to one Cu(2), two equivalent Cu(1), one S(1), one I(2), and two equivalent I(1) atoms. The Cu(2)-Cu(2) bond length is 2.56 Å. The Cu(2)-S(1) bond length is 2.28 Å. The Cu(2)-I(2) bond length is 2.81 Å. There is one shorter (2.65 Å) and one longer (2.67 Å) Cu(2)-I(1) bond length. There are fifteen inequivalent C sites. In the first C site, C(13) is bonded in a distorted water-like geometry to one H(18), one H(19), and one S(2) atom. The C(13)-H(18) bond length is 1.10 Å. The C(13)-H(19) bond length is 1.10 Å. The C(13)-S(2) bond length is 1.81 Å. In the second C site, C(14) is bonded in a distorted water-like geometry to one C(15), one H(20), one H(21), and one S(2) atom. The C(14)-C(15) bond length is 1.49 Å. The C(14)-H(20) bond length is 1.10 Å. The C(14)-H(21) bond length is 1.10 Å. The C(14)-S(2) bond length is 1.84 Å. In the third C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(20) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(20) bond length is 1.41 Å. In the fourth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(22) atom. The C(16)-H(22) bond length is 1.09 Å. In the fifth C site, C(20) is bonded in a distorted single-bond geometry to one C(15) and one O(1) atom. The C(20)-O(1) bond length is 1.37 Å. In the sixth C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(2), one H(3), and one O(1) atom. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-O(1) bond length is 1.43 Å. In the seventh C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one H(4), one H(5), and one O(2) atom. The C(2)-H(4) bond length is 1.10 Å. The C(2)-H(5) bond length is 1.10 Å. The C(2)-O(2) bond length is 1.43 Å. In the eighth C site, C(3) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one O(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(8) bond length is 1.41 Å. The C(3)-O(2) bond length is 1.37 Å. In the ninth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(6) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(6) bond length is 1.09 Å. In the tenth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(7) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(7) bond length is 1.09 Å. In the eleventh C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(8) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(8) bond length is 1.09 Å. In the twelfth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(9) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(8) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.49 Å. In the fourteenth C site, C(9) is bonded in a distorted water-like geometry to one C(8), one H(10), one H(11), and one S(1) atom. The C(9)-H(10) bond length is 1.10 Å. The C(9)-H(11) bond length is 1.10 Å. The C(9)-S(1) bond length is 1.85 Å. In the fifteenth C site, C(10) is bonded in a distorted water-like geometry to one H(12), one H(13), and one S(1) atom. The C(10)-H(12) bond length is 1.10 Å. The C(10)-H(13) bond length is 1.10 Å. The C(10)-S(1) bond length is 1.83 Å. There are seventeen inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(13) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(13) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(14) atom. In the sixteenth H site, H(21) is bonded in a single-bond geometry to one C(14) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one C(16) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(13), and one C(14) atom. In the second S site, S(1) is bonded in a trigonal non-coplanar geometry to one Cu(2), one C(10), and one C(9) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(20) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one Cu(1) and two equivalent Cu(2) atoms. In the second I site, I(2) is bonded in a 3-coordinate geometry to one Cu(2) and two equivalent Cu(1) atoms. Linkers: 4 c1ccc2c(c1)CSCCNCCSCc1ccccc1OCCO2. Metal clusters: 2 I[Cu]12(I)[Cu]3[Cu]1[Cu]32(I)I. The MOF has largest included sphere 5.14 A, density 1.65 g/cm3, surface area 3586.83 m2/g, accessible volume 0.27 cm3/g