Ag3C24H17(NO2)4 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent N(1) atoms. Both Ag(1)-N(1) bond lengths are 2.12 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one N(2), one O(1), and one O(3) atom. The Ag(2)-N(2) bond length is 2.13 Å. The Ag(2)-O(1) bond length is 2.74 Å. The Ag(2)-O(3) bond length is 2.11 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(2) atom. The C(1)-C(3) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.30 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(5) bond length is 1.39 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(6) atom. The C(3)-C(6) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(3) atom. The C(4)-C(6) bond length is 1.39 Å. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(3), one C(4), and one H(5) atom. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(4) atom. The C(7)-C(10) bond length is 1.51 Å. The C(7)-O(3) bond length is 1.29 Å. The C(7)-O(4) bond length is 1.25 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(6) atom. The C(8)-C(12) bond length is 1.39 Å. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one H(7) atom. The C(9)-C(11) bond length is 1.39 Å. The C(9)-N(2) bond length is 1.35 Å. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(7) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(12) bond length is 1.40 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(9), and one H(8) atom. The C(11)-H(8) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(9) atom. The C(12)-H(9) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(4), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(2), one C(8), and one C(9) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a linear geometry to two equivalent O(2) atoms. Both H(2)-O(2) bond lengths are 1.22 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ag(2) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(1) and one H(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ag(2) and one C(7) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(7) atom. Linkers: 1 O=[C]O[Ag].[Ag].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C][C].[C][C].[C][N].[C][N][C].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[O].[O].[O].[O]C(=O)c1ccncc1.[O][Ag].[O][Ag]N1[CH]C=[C]C=C1.[O][C]=O ,1 O=[C]O[Ag].[Ag].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C][N][C].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[O].[O].[O].[O].[O].[O]C(=O)c1ccncc1.[O][Ag].[O][Ag]N1[CH]C=[C]C=C1 ,1 [Ag].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C]C(=O)O[Ag]N1[CH]C=[C]C=C1.[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]C(=[CH])[C][O].[C][N][CH].[H].[H].[H].[H].[H].[N].[N].[N][Ag][O].[O].[O].[O].[O].[O]C(=O)c1ccncc1.[O][Ag] ,1 O=[C]O[Ag]N1[CH]C=[C]C=C1.[Ag].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]N([CH])[Ag][O].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C][CH].[C][N][C].[H].[H].[H].[H].[H].[N].[N].[O].[O].[O].[O].[O].[O]C(=O)c1ccncc1.[O][Ag]. Metal clusters: 2 [Ag]. The MOF has largest included sphere 1.68 A, density 2.29 g/cm3, surface area 3332.53 m2/g, accessible volume 0.06 cm3/g