TbC13NH8O7CH2 crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of four 02329_fluka molecules inside a TbC13NH8O7 framework. In the TbC13NH8O7 framework, Tb(1) is bonded in a pentagonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. The Tb(1)-O(1) bond length is 2.32 Å. The Tb(1)-O(2) bond length is 2.39 Å. The Tb(1)-O(3) bond length is 2.33 Å. The Tb(1)-O(4) bond length is 2.27 Å. The Tb(1)-O(5) bond length is 2.32 Å. The Tb(1)-O(6) bond length is 2.28 Å. The Tb(1)-O(7) bond length is 2.34 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(8) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(8) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.50 Å. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(5)-O(3) bond length is 1.27 Å. The C(5)-O(4) bond length is 1.27 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4), one C(7), and one H(2) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(2) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-C(9) bond length is 1.51 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(2), one C(7), and one H(3) atom. The C(8)-H(3) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(7), one N(1), one H(4), and one H(5) atom. The C(9)-N(1) bond length is 1.46 Å. The C(9)-H(4) bond length is 1.10 Å. The C(9)-H(5) bond length is 1.10 Å. In the tenth C site, C(10) is bonded in a distorted water-like geometry to one N(1) and one H(6) atom. The C(10)-N(1) bond length is 1.46 Å. The C(10)-H(6) bond length is 1.10 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(11)-O(5) bond length is 1.27 Å. The C(11)-O(6) bond length is 1.26 Å. In the twelfth C site, C(13) is bonded in a distorted water-like geometry to one C(14), one H(10), and one H(9) atom. The C(13)-C(14) bond length is 1.51 Å. The C(13)-H(10) bond length is 1.10 Å. The C(13)-H(9) bond length is 1.10 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(1), and one O(7) atom. The C(14)-N(1) bond length is 1.35 Å. The C(14)-O(7) bond length is 1.25 Å. N(1) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(9) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Tb(1) and one C(14) atom. In the second O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Tb(1) and one C(1) atom. In the third O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Tb(1) and one C(1) atom. In the fourth O site, O(3) is bonded in a bent 150 degrees geometry to one Tb(1) and one C(5) atom. In the fifth O site, O(4) is bonded in a distorted linear geometry to one Tb(1) and one C(5) atom. In the sixth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Tb(1) and one C(11) atom. In the seventh O site, O(6) is bonded in a bent 150 degrees geometry to one Tb(1) and one C(11) atom. Linkers: 4 [O]C(=O)c1cc(CN2C(=O)CC[C@H]2C([O])=O)cc(C([O])=O)c1. Metal clusters: 4 [Tb]. The MOF has largest included sphere 4.06 A, density 1.80 g/cm3, surface area 3143.66 m2/g, accessible volume 0.23 cm3/g