ZnC10NH12O8CH3 crystallizes in the triclinic P1 space group. The structure consists of two 02329_fluka molecules inside a ZnC10NH12O8 framework. In the ZnC10NH12O8 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(12), one O(13), one O(6), and one O(7) atom. The Zn(1)-O(1) bond length is 2.13 Å. The Zn(1)-O(11) bond length is 2.02 Å. The Zn(1)-O(12) bond length is 2.02 Å. The Zn(1)-O(13) bond length is 2.26 Å. The Zn(1)-O(6) bond length is 2.48 Å. The Zn(1)-O(7) bond length is 2.12 Å. In the second Zn site, Zn(2) is bonded in a distorted octahedral geometry to one O(10), one O(14), one O(15), one O(16), one O(4), and one O(5) atom. The Zn(2)-O(10) bond length is 2.02 Å. The Zn(2)-O(14) bond length is 2.12 Å. The Zn(2)-O(15) bond length is 2.08 Å. The Zn(2)-O(16) bond length is 2.10 Å. The Zn(2)-O(4) bond length is 2.19 Å. The Zn(2)-O(5) bond length is 2.39 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.29 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(15) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(15) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(16) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(16) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-C(8) bond length is 1.49 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(17) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(17) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(18) atom. The C(7)-H(18) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(1), and one O(3) atom. The C(8)-N(1) bond length is 1.34 Å. The C(8)-O(3) bond length is 1.27 Å. In the ninth C site, C(9) is bonded in a distorted water-like geometry to one N(1) and one H(19) atom. The C(9)-N(1) bond length is 1.45 Å. The C(9)-H(19) bond length is 1.10 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(11)-O(4) bond length is 1.28 Å. The C(11)-O(5) bond length is 1.27 Å. In the eleventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(12)-O(6) bond length is 1.27 Å. The C(12)-O(7) bond length is 1.28 Å. In the twelfth C site, C(13) is bonded in a distorted water-like geometry to one N(2) and one H(23) atom. The C(13)-N(2) bond length is 1.44 Å. The C(13)-H(23) bond length is 1.10 Å. In the thirteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(2), and one O(8) atom. The C(15)-C(16) bond length is 1.49 Å. The C(15)-N(2) bond length is 1.34 Å. The C(15)-O(8) bond length is 1.26 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.41 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(27) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(27) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(28) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-H(28) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(22) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-C(22) bond length is 1.50 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(29) atom. The C(20)-H(29) bond length is 1.09 Å. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(30) atom. The C(21)-H(30) bond length is 1.09 Å. In the twentieth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(10), and one O(9) atom. The C(22)-O(10) bond length is 1.28 Å. The C(22)-O(9) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(8), one C(9), and one H(13) atom. The N(1)-H(13) bond length is 1.03 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(13), one C(15), and one H(14) atom. The N(2)-H(14) bond length is 1.03 Å. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(11) and one O(2) atom. The H(1)-O(11) bond length is 1.01 Å. The H(1)-O(2) bond length is 1.62 Å. In the second H site, H(2) is bonded in a distorted linear geometry to one O(11) and one O(5) atom. The H(2)-O(11) bond length is 1.02 Å. The H(2)-O(5) bond length is 1.55 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(12) and one O(8) atom. The H(3)-O(12) bond length is 1.01 Å. The H(3)-O(8) bond length is 1.63 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(12) and one O(9) atom. The H(4)-O(12) bond length is 1.00 Å. The H(4)-O(9) bond length is 1.70 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(13) atom. The H(5)-O(13) bond length is 0.97 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(13) atom. The H(6)-O(13) bond length is 0.99 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(14) atom. The H(7)-O(14) bond length is 0.99 Å. In the eighth H site, H(8) is bonded in a distorted single-bond geometry to one O(14) and one O(2) atom. The H(8)-O(14) bond length is 1.00 Å. The H(8)-O(2) bond length is 1.69 Å. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(15) atom. The H(9)-O(15) bond length is 1.00 Å. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(15) atom. The H(10)-O(15) bond length is 0.98 Å. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(16) atom. The H(11)-O(16) bond length is 0.99 Å. In the twelfth H site, H(12) is bonded in a distorted single-bond geometry to one O(16) and one O(9) atom. The H(12)-O(16) bond length is 1.01 Å. The H(12)-O(9) bond length is 1.62 Å. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one N(1) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one N(2) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(3) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(4) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(6) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(7) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(9) atom. In the twentieth H site, H(23) is bonded in a single-bond geometry to one C(13) atom. In the twenty-first H site, H(27) is bonded in a single-bond geometry to one C(17) atom. In the twenty-second H site, H(28) is bonded in a single-bond geometry to one C(18) atom. In the twenty-third H site, H(29) is bonded in a single-bond geometry to one C(20) atom. In the twenty-fourth H site, H(30) is bonded in a single-bond geometry to one C(21) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one H(1), and one H(8) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Zn(2) and one C(11) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Zn(2), one C(11), and one H(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Zn(1) and one C(12) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Zn(1) and one C(12) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one C(15) and one H(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one C(22), one H(12), and one H(4) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(22) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Zn(1), one H(1), and one H(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one H(3), and one H(4) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one Zn(1), one H(5), and one H(6) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one H(7), and one H(8) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one H(10), and one H(9) atom. In the sixteenth O site, O(16) is bonded in a distorted water-like geometry to one Zn(2), one H(11), and one H(12) atom. Linkers: 2 C[C@H](NC(=O)c1ccc(C([O])=O)cc1)C([O])=O. Metal clusters: 1 O.O.O.[O][C]O[Zn]O[C]=O ,1 O.O.O.O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.94 A, density 1.63 g/cm3, surface area 4147.69 m2/g, accessible volume 0.18 cm3/g