(CH)2CdC10N4H8OI2 is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CdC10N4H8OI2 clusters. In each CdC10N4H8OI2 cluster, Cd(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(4), one I(1), and one I(2) atom. The Cd(1)-N(1) bond length is 2.39 Å. The Cd(1)-N(2) bond length is 2.50 Å. The Cd(1)-N(4) bond length is 2.69 Å. The Cd(1)-I(1) bond length is 2.79 Å. The Cd(1)-I(2) bond length is 2.76 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.46 Å. The C(1)-N(1) bond length is 1.35 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and one H(5) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(5) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(2), and one H(6) atom. The C(6)-N(2) bond length is 1.29 Å. The C(6)-H(6) bond length is 1.10 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(3), and one O(1) atom. The C(7)-C(8) bond length is 1.49 Å. The C(7)-N(3) bond length is 1.38 Å. The C(7)-O(1) bond length is 1.24 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(8) atom. The C(10)-N(4) bond length is 1.34 Å. The C(10)-H(8) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(9) atom. The C(11)-N(4) bond length is 1.34 Å. The C(11)-H(9) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(8) and one H(10) atom. The C(12)-H(10) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(6), and one N(3) atom. The N(2)-N(3) bond length is 1.34 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one C(7), one N(2), and one H(1) atom. The N(3)-H(1) bond length is 1.03 Å. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one Cd(1), one C(10), and one C(11) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. O(1) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Cd(1) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Cd(1) atom. Linkers: 2 O=C(N/N=C/c1ccccn1)c1ccncc1. Metal clusters: 2 I[Cd]I. The MOF has largest included sphere 1.71 A, density 2.63 g/cm3, surface area 3004.48 m2/g, accessible volume 0.07 cm3/g