AgC9H8(NO)2C5H4O2NO3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four methyl methacrylate molecules, four nitric acid molecules, and four AgC9H8(NO)2 clusters. In each AgC9H8(NO)2 cluster, Ag(1) is bonded in a 2-coordinate geometry to one N(1) and one N(2) atom. The Ag(1)-N(1) bond length is 2.19 Å. The Ag(1)-N(2) bond length is 2.19 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one H(7), one H(8), and one O(3) atom. The C(8)-H(7) bond length is 1.10 Å. The C(8)-H(8) bond length is 1.10 Å. The C(8)-O(3) bond length is 1.45 Å. In the fourth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(4) atom. The C(9)-C(10) bond length is 1.49 Å. The C(9)-O(3) bond length is 1.35 Å. The C(9)-O(4) bond length is 1.22 Å. In the fifth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(13) bond length is 1.40 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(9) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(9) bond length is 1.09 Å. In the seventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one H(10) atom. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(10) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one H(11) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(11) bond length is 1.09 Å. In the ninth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(2), and one H(12) atom. The C(14)-N(2) bond length is 1.35 Å. The C(14)-H(12) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(12), and one C(14) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one C(8) and one C(9) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(9) atom. Linkers: 4 O=C(OCCOC(=O)c1ccncc1)c1ccncc1. Metal clusters: 4 [Ag].[O][N+](=O)[O-]. The MOF has largest included sphere 1.84 A, density 1.92 g/cm3, surface area 3928.39 m2/g, accessible volume 0.11 cm3/g