ZnC6H3(N2O)2CH3 crystallizes in the tetragonal I-4 space group. The structure consists of eight 02329_fluka molecules inside a ZnC6H3(N2O)2 framework. In the ZnC6H3(N2O)2 framework, Zn(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(2), one N(4), and one O(1) atom. The Zn(1)-N(1) bond length is 2.02 Å. The Zn(1)-N(2) bond length is 2.05 Å. The Zn(1)-N(4) bond length is 2.06 Å. The Zn(1)-O(1) bond length is 2.00 Å. There are six inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(2) atom. The C(3)-N(3) bond length is 1.33 Å. The C(3)-N(4) bond length is 1.36 Å. The C(3)-H(2) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(4), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-N(4) bond length is 1.35 Å. The C(4)-H(3) bond length is 1.09 Å. In the third C site, C(5) is bonded in a 3-coordinate geometry to one C(2), one C(4), and one N(1) atom. The C(5)-C(2) bond length is 1.42 Å. The C(5)-N(1) bond length is 1.39 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(6)-O(1) bond length is 1.30 Å. The C(6)-O(2) bond length is 1.25 Å. In the fifth C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.09 Å. In the sixth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(2), and one N(3) atom. The C(2)-N(2) bond length is 1.37 Å. The C(2)-N(3) bond length is 1.34 Å. There are four inequivalent N sites. In the first N site, N(3) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(3), and one C(4) atom. In the fourth N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(6) atom. Linkers: 1 N1=CC2=NC=NC2=[N]=C1 ,2 C1=N[C]2C(=[N]=CN=C2)[N]1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 7.07 A, density 1.46 g/cm3, surface area 4170.82 m2/g, accessible volume 0.29 cm3/g