Zn2C13NH12O8(CH3)2(CH)3C4H4O crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of twelve 02329_fluka molecules, eight 02329_fluka molecules, and four methallyl alcohol molecules inside a Zn2C13NH12O8 framework. In the Zn2C13NH12O8 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(5), one O(7), and one O(8) atom to form corner-sharing ZnO5 trigonal bipyramids. The Zn(1)-O(2) bond length is 2.01 Å. The Zn(1)-O(3) bond length is 2.00 Å. The Zn(1)-O(5) bond length is 2.15 Å. The Zn(1)-O(7) bond length is 1.96 Å. The Zn(1)-O(8) bond length is 2.14 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(4), one O(5), one O(6), and one O(7) atom to form corner-sharing ZnO5 trigonal bipyramids. The Zn(2)-O(1) bond length is 2.02 Å. The Zn(2)-O(4) bond length is 2.01 Å. The Zn(2)-O(5) bond length is 2.17 Å. The Zn(2)-O(6) bond length is 2.05 Å. The Zn(2)-O(7) bond length is 1.98 Å. There are thirteen inequivalent C sites. In the first C site, C(6) is bonded in a distorted trigonal planar geometry to one C(4), one C(7), and one H(4) atom. The C(6)-C(4) bond length is 1.39 Å. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(4) bond length is 1.09 Å. In the second C site, C(7) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(8) atom. The C(7)-C(5) bond length is 1.40 Å. The C(7)-C(8) bond length is 1.50 Å. In the third C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.28 Å. The C(8)-O(4) bond length is 1.27 Å. In the fourth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(9)-O(5) bond length is 1.28 Å. The C(9)-O(6) bond length is 1.26 Å. In the fifth C site, C(10) is bonded in a distorted water-like geometry to one H(5) and one O(7) atom. The C(10)-H(5) bond length is 1.10 Å. The C(10)-O(7) bond length is 1.42 Å. In the sixth C site, C(12) is bonded in a trigonal planar geometry to one N(1), one H(9), and one O(8) atom. The C(12)-N(1) bond length is 1.33 Å. The C(12)-H(9) bond length is 1.10 Å. The C(12)-O(8) bond length is 1.26 Å. In the seventh C site, C(13) is bonded to one N(1), one H(10), one H(11), and one H(12) atom to form corner-sharing CH3N tetrahedra. The C(13)-N(1) bond length is 1.45 Å. The C(13)-H(10) bond length is 1.09 Å. The C(13)-H(11) bond length is 1.10 Å. The C(13)-H(12) bond length is 1.10 Å. In the eighth C site, C(14) is bonded to one N(1), one H(13), one H(14), and one H(15) atom to form corner-sharing CH3N tetrahedra. The C(14)-N(1) bond length is 1.45 Å. The C(14)-H(13) bond length is 1.10 Å. The C(14)-H(14) bond length is 1.10 Å. The C(14)-H(15) bond length is 1.10 Å. In the ninth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the tenth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.40 Å. In the eleventh C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(5), and one H(1) atom. The C(3)-C(5) bond length is 1.39 Å. The C(3)-H(1) bond length is 1.09 Å. In the twelfth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(2) atom. The C(4)-H(2) bond length is 1.09 Å. In the thirteenth C site, C(5) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(14) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(8) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Zn(1), one Zn(2), and one C(9) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(9) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one C(10) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(12) atom. Linkers: 4 [O]C(=O)c1ccc(C([O])=O)cc1 ,4 C[C@H]([O])C([O])=O. Metal clusters: 8 [Zn]. The MOF has largest included sphere 2.88 A, density 1.56 g/cm3, surface area 4736.57 m2/g, accessible volume 0.13 cm3/g