Mn3C20H16(NO)10(CH)4 crystallizes in the triclinic P1 space group. The structure consists of four 02329_fluka molecules inside a Mn3C20H16(NO)10 framework. In the Mn3C20H16(NO)10 framework, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one N(1), one N(2), one O(10), one O(5), one O(6), and one O(9) atom to form corner-sharing MnN2O4 octahedra. The corner-sharing octahedral tilt angles range from 59-61°. The Mn(1)-N(1) bond length is 2.22 Å. The Mn(1)-N(2) bond length is 2.20 Å. The Mn(1)-O(10) bond length is 2.15 Å. The Mn(1)-O(5) bond length is 2.26 Å. The Mn(1)-O(6) bond length is 2.15 Å. The Mn(1)-O(9) bond length is 2.10 Å. In the second Mn site, Mn(2) is bonded to one N(1), one N(10), one N(8), one O(1), one O(3), and one O(7) atom to form corner-sharing MnN3O3 octahedra. The corner-sharing octahedral tilt angles are 59°. The Mn(2)-N(1) bond length is 2.21 Å. The Mn(2)-N(10) bond length is 2.02 Å. The Mn(2)-N(8) bond length is 1.99 Å. The Mn(2)-O(1) bond length is 2.11 Å. The Mn(2)-O(3) bond length is 1.95 Å. The Mn(2)-O(7) bond length is 1.98 Å. In the third Mn site, Mn(3) is bonded to one N(2), one N(7), one N(9), one O(2), one O(4), and one O(8) atom to form corner-sharing MnN3O3 octahedra. The corner-sharing octahedral tilt angles are 61°. The Mn(3)-N(2) bond length is 2.16 Å. The Mn(3)-N(7) bond length is 2.25 Å. The Mn(3)-N(9) bond length is 2.25 Å. The Mn(3)-O(2) bond length is 2.21 Å. The Mn(3)-O(4) bond length is 2.16 Å. The Mn(3)-O(8) bond length is 2.15 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(5) atom. The C(1)-C(3) bond length is 1.48 Å. The C(1)-O(3) bond length is 1.28 Å. The C(1)-O(5) bond length is 1.29 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(4), and one O(6) atom. The C(2)-C(4) bond length is 1.49 Å. The C(2)-O(4) bond length is 1.27 Å. The C(2)-O(6) bond length is 1.29 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(5) atom. The C(3)-C(11) bond length is 1.40 Å. The C(3)-C(5) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(2), and one C(6) atom. The C(4)-C(12) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(3), one N(7), and one H(5) atom. The C(5)-N(7) bond length is 1.34 Å. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(8), and one H(6) atom. The C(6)-N(8) bond length is 1.35 Å. The C(6)-H(6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(7) atom. The C(7)-N(7) bond length is 1.35 Å. The C(7)-H(7) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one N(8) and one H(8) atom. The C(8)-N(8) bond length is 1.36 Å. The C(8)-H(8) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(3) and one H(11) atom. The C(11)-H(11) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(4) and one H(12) atom. The C(12)-H(12) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(7), and one O(9) atom. The C(13)-C(15) bond length is 1.49 Å. The C(13)-O(7) bond length is 1.29 Å. The C(13)-O(9) bond length is 1.26 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(10), and one O(8) atom. The C(14)-C(16) bond length is 1.50 Å. The C(14)-O(10) bond length is 1.28 Å. The C(14)-O(8) bond length is 1.27 Å. In the thirteenth C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(23) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-C(23) bond length is 1.40 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(24) atom. The C(16)-C(18) bond length is 1.40 Å. The C(16)-C(24) bond length is 1.40 Å. In the fifteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(9), and one H(13) atom. The C(17)-N(9) bond length is 1.34 Å. The C(17)-H(13) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(10), and one H(14) atom. The C(18)-N(10) bond length is 1.36 Å. The C(18)-H(14) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(15) atom. The C(19)-N(9) bond length is 1.35 Å. The C(19)-H(15) bond length is 1.09 Å. In the eighteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one N(10) and one H(16) atom. The C(20)-N(10) bond length is 1.36 Å. The C(20)-H(16) bond length is 1.09 Å. In the nineteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(15) and one H(19) atom. The C(23)-H(19) bond length is 1.09 Å. In the twentieth C site, C(24) is bonded in a distorted single-bond geometry to one C(16) and one H(20) atom. The C(24)-H(20) bond length is 1.09 Å. There are ten inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one N(3) atom. The N(1)-N(3) bond length is 1.21 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one N(4) atom. The N(2)-N(4) bond length is 1.21 Å. In the third N site, N(3) is bonded in a linear geometry to one N(1) and one N(5) atom. The N(3)-N(5) bond length is 1.17 Å. In the fourth N site, N(4) is bonded in a linear geometry to one N(2) and one N(6) atom. The N(4)-N(6) bond length is 1.17 Å. In the fifth N site, N(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(4) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Mn(3), one C(5), and one C(7) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Mn(2), one C(6), and one C(8) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Mn(3), one C(17), and one C(19) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Mn(2), one C(18), and one C(20) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(1) and one O(6) atom. The H(1)-O(1) bond length is 1.00 Å. The H(1)-O(6) bond length is 1.65 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. The H(3)-O(1) bond length is 1.00 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Mn(2), one H(1), and one H(3) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Mn(3), one H(2), and one H(4) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(2) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Mn(1) and one C(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(2), and one H(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(13) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mn(3) and one C(14) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(13) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(14) atom. Linkers: 4 [O]C(=O)c1cccnc1. Metal clusters: 3 [Mn]. The MOF has largest included sphere 2.44 A, density 1.86 g/cm3, surface area 3281.25 m2/g, accessible volume 0.08 cm3/g