MoZnC14H18(NO)4 crystallizes in the monoclinic C2 space group. Mo(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form MoO4 tetrahedra that share corners with two equivalent Zn(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 42°. Both Mo(1)-O(1) bond lengths are 1.79 Å. Both Mo(1)-O(2) bond lengths are 1.77 Å. Zn(1) is bonded to two equivalent N(1), two equivalent N(2), and two equivalent O(1) atoms to form ZnN4O2 octahedra that share corners with two equivalent Mo(1)O4 tetrahedra. Both Zn(1)-N(1) bond lengths are 2.21 Å. Both Zn(1)-N(2) bond lengths are 2.19 Å. Both Zn(1)-O(1) bond lengths are 2.12 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one N(1), one H(1), and one H(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-N(1) bond length is 1.47 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(5) atom. The C(2)-C(4) bond length is 1.40 Å. The C(2)-C(5) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(3), and one H(4) atom. The C(3)-N(1) bond length is 1.47 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(4) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(4)-H(5) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(6) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(6) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(2), and one H(7) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-H(7) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(7)-N(2) bond length is 1.35 Å. The C(7)-H(8) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Zn(1), one C(1), one C(3), and one H(9) atom. The N(1)-H(9) bond length is 1.04 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(6), and one C(7) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one Zn(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Mo(1) atom. Linkers: 1 c1cc(CNCCNCc2ccncc2)ccn1. Metal clusters: 1 [Zn] ,1 [Mo]. The MOF has largest included sphere 5.95 A, density 1.26 g/cm3, surface area 3906.58 m2/g, accessible volume 0.35 cm3/g