K3PtC43N4H24S3O9CH crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a K3PtC43N4H24S3O9 framework. In the K3PtC43N4H24S3O9 framework, there are three inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(7), one O(9), two equivalent O(1), and two equivalent O(8) atoms. The K(1)-O(2) bond length is 2.85 Å. The K(1)-O(3) bond length is 3.24 Å. The K(1)-O(7) bond length is 3.28 Å. The K(1)-O(9) bond length is 2.77 Å. There is one shorter (2.80 Å) and one longer (2.85 Å) K(1)-O(1) bond length. There is one shorter (2.60 Å) and one longer (2.64 Å) K(1)-O(8) bond length. In the second K site, K(2) is bonded in a 5-coordinate geometry to one O(2), one O(3), one O(6), one O(7), and one O(9) atom. The K(2)-O(2) bond length is 2.79 Å. The K(2)-O(3) bond length is 3.25 Å. The K(2)-O(6) bond length is 2.62 Å. The K(2)-O(7) bond length is 2.81 Å. The K(2)-O(9) bond length is 2.84 Å. In the third K site, K(3) is bonded in a distorted pentagonal planar geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. The K(3)-O(1) bond length is 2.77 Å. The K(3)-O(2) bond length is 2.87 Å. The K(3)-O(3) bond length is 2.75 Å. The K(3)-O(4) bond length is 2.86 Å. The K(3)-O(5) bond length is 2.73 Å. Pt(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Pt(1)-N(1) bond length is 2.02 Å. The Pt(1)-N(2) bond length is 2.02 Å. The Pt(1)-N(3) bond length is 2.02 Å. The Pt(1)-N(4) bond length is 2.02 Å. There are forty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(20), and one N(1) atom. The C(1)-C(2) bond length is 1.44 Å. The C(1)-C(20) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2,3) atom. The C(3)-C(4) bond length is 1.44 Å. The C(3)-H(2,3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(1) bond length is 1.38 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(21), one C(4), and one C(6) atom. The C(5)-C(21) bond length is 1.49 Å. The C(5)-C(6) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.44 Å. The C(6)-N(2) bond length is 1.38 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(2,3) atom. The C(7)-H(2,3) bond length is 1.08 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(8)-C(9) bond length is 1.44 Å. The C(8)-H(4) bond length is 1.08 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(2) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-N(2) bond length is 1.38 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(27), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(27) bond length is 1.48 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(3) atom. The C(11)-C(12) bond length is 1.44 Å. The C(11)-N(3) bond length is 1.38 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(5) atom. The C(12)-C(13) bond length is 1.36 Å. The C(12)-H(5) bond length is 1.08 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(6) atom. The C(13)-C(14) bond length is 1.44 Å. The C(13)-H(6) bond length is 1.08 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one N(3) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-N(3) bond length is 1.39 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(33) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(33) bond length is 1.49 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one N(4) atom. The C(16)-C(17) bond length is 1.44 Å. The C(16)-N(4) bond length is 1.39 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(7) atom. The C(17)-C(18) bond length is 1.36 Å. The C(17)-H(7) bond length is 1.08 Å. In the eighteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(8) atom. The C(18)-C(19) bond length is 1.44 Å. The C(18)-H(8) bond length is 1.08 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one N(4) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-N(4) bond length is 1.38 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(1), one C(19), and one C(39) atom. The C(20)-C(39) bond length is 1.49 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(22), one C(26), and one C(5) atom. The C(21)-C(22) bond length is 1.41 Å. The C(21)-C(26) bond length is 1.41 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(9) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-H(9) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one H(10) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-H(10) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(11) atom. The C(24)-H(11) bond length is 1.09 Å. In the twenty-fifth C site, C(26) is bonded in a distorted single-bond geometry to one C(21) and one H(13) atom. The C(26)-H(13) bond length is 1.09 Å. In the twenty-sixth C site, C(27) is bonded in a trigonal planar geometry to one C(10), one C(28), and one C(32) atom. The C(27)-C(28) bond length is 1.41 Å. The C(27)-C(32) bond length is 1.41 Å. In the twenty-seventh C site, C(28) is bonded in a distorted single-bond geometry to one C(27), one C(29), and one H(14) atom. The C(28)-C(29) bond length is 1.39 Å. The C(28)-H(14) bond length is 1.09 Å. In the twenty-eighth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one C(30), and one H(15) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-H(15) bond length is 1.09 Å. In the twenty-ninth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one S(1) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-S(1) bond length is 1.78 Å. In the thirtieth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(30), one C(32), and one H(16) atom. The C(31)-C(32) bond length is 1.40 Å. The C(31)-H(16) bond length is 1.09 Å. In the thirty-first C site, C(32) is bonded in a distorted single-bond geometry to one C(27), one C(31), and one H(17) atom. The C(32)-H(17) bond length is 1.09 Å. In the thirty-second C site, C(33) is bonded in a trigonal planar geometry to one C(15), one C(34), and one C(38) atom. The C(33)-C(34) bond length is 1.41 Å. The C(33)-C(38) bond length is 1.40 Å. In the thirty-third C site, C(34) is bonded in a distorted single-bond geometry to one C(33), one C(35), and one H(18) atom. The C(34)-C(35) bond length is 1.39 Å. The C(34)-H(18) bond length is 1.09 Å. In the thirty-fourth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(34), one C(36), and one H(19) atom. The C(35)-C(36) bond length is 1.40 Å. The C(35)-H(19) bond length is 1.09 Å. In the thirty-fifth C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one S(2) atom. The C(36)-C(37) bond length is 1.40 Å. The C(36)-S(2) bond length is 1.79 Å. In the thirty-sixth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(36), one C(38), and one H(20) atom. The C(37)-C(38) bond length is 1.39 Å. The C(37)-H(20) bond length is 1.09 Å. In the thirty-seventh C site, C(38) is bonded in a distorted single-bond geometry to one C(33), one C(37), and one H(21) atom. The C(38)-H(21) bond length is 1.09 Å. In the thirty-eighth C site, C(39) is bonded in a trigonal planar geometry to one C(20), one C(40), and one C(44) atom. The C(39)-C(40) bond length is 1.40 Å. The C(39)-C(44) bond length is 1.40 Å. In the thirty-ninth C site, C(40) is bonded in a distorted trigonal planar geometry to one C(39), one C(41), and one H(22) atom. The C(40)-C(41) bond length is 1.39 Å. The C(40)-H(22) bond length is 1.09 Å. In the fortieth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(40), one C(42), and one H(23) atom. The C(41)-C(42) bond length is 1.40 Å. The C(41)-H(23) bond length is 1.09 Å. In the forty-first C site, C(42) is bonded in a trigonal planar geometry to one C(41), one C(43), and one S(3) atom. The C(42)-C(43) bond length is 1.40 Å. The C(42)-S(3) bond length is 1.78 Å. In the forty-second C site, C(43) is bonded in a distorted trigonal planar geometry to one C(42), one C(44), and one H(24) atom. The C(43)-C(44) bond length is 1.40 Å. The C(43)-H(24) bond length is 1.09 Å. In the forty-third C site, C(44) is bonded in a distorted single-bond geometry to one C(39), one C(43), and one H(25) atom. The C(44)-H(25) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pt(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pt(1), one C(6), and one C(9) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Pt(1), one C(11), and one C(14) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Pt(1), one C(16), and one C(19) atom. There are twenty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(26) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(28) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(29) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(31) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(32) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(34) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(35) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(37) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(38) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(40) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(41) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(43) atom. In the twenty-third H site, H(25) is bonded in a single-bond geometry to one C(44) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(30), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.46 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one C(36), one O(4), one O(5), and one O(6) atom. The S(2)-O(4) bond length is 1.48 Å. The S(2)-O(5) bond length is 1.48 Å. The S(2)-O(6) bond length is 1.47 Å. In the third S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to one C(42), one O(7), one O(8), and one O(9) atom. The S(3)-O(7) bond length is 1.47 Å. The S(3)-O(8) bond length is 1.49 Å. The S(3)-O(9) bond length is 1.47 Å. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(3), two equivalent K(1), and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), one K(3), and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(1), one K(2), one K(3), and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one K(3) and one S(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(3) and one S(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one K(2) and one S(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one K(1), one K(2), and one S(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to two equivalent K(1) and one S(3) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one S(3) atom. Linkers: 1 [C]/C=C\[C](C1=C2C=CC3=[N]2[Pt@@]24n5c1ccc5C(=C1[N]2=C(C=C1)C(=c1n4c(=C3c2ccc(cc2)S([O])([O])[O])cc1)c1ccc(cc1)S([O])([O])[O])c1ccccc1)[C] ,2 [O]S(c1ccc(cc1)C1=C2C=CC3=[N]2[Pt@@]24n5c1ccc5C(=C1[N]2=C(C=C1)C(=c1n4c(=C3c2ccc(cc2)S([O])([O])[O])cc1)c1ccccc1)c1ccc(cc1)S([O])([O])[O])([O])[O] ,2 [O]S(c1ccc(cc1)C1=c2ccc3=C(C4=[N]5[Pt@]6([N]7=C1C=CC7=C(c1ccc(cc1)S([O])([O])[O])c1n6c(C(=C5C=C4)c4ccccc4)cc1)n23)c1ccc(cc1)S([O])([O])[O])([O])[O] ,1 [O][S](c1ccc(cc1)C1=C2C=CC3=[N]2[Pt@]24n5c1ccc5C(=C1[N]2=C(C=C1)C(=c1n4c(=C3c2ccc(cc2)S([O])([O])[O])cc1)c1ccc(cc1)S([O])([O])[O])c1ccccc1)[O] ,1 [O][S](c1ccc(cc1)C1=c2ccc3=C(C4=[N]5[Pt@@]6([N]7=C1C=CC7=C(c1ccc(cc1)S([O])([O])[O])c1n6c(cc1)C(=C5C=C4)c1ccc(cc1)S([O])([O])[O])n23)c1ccccc1)[O] ,1 [C]/C=C\[C](C1=c2ccc3=C(C4=[N]5[Pt@]6([N]7=C1C=CC7=C(c1ccc(cc1)S([O])([O])[O])c1n6c(C(=C5C=C4)c4ccc(cc4)S([O])([O])[O])cc1)n23)c1ccccc1)[C]. Metal clusters: 12 [K]. The MOF has largest included sphere 7.88 A, density 1.31 g/cm3, surface area 3229.72 m2/g, accessible volume 0.21 cm3/g