Cu2C9N4H12O5(CH2)2(CO)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four formaldehyde molecules, and one Cu2C9N4H12O5 cluster. In the Cu2C9N4H12O5 cluster, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one N(1), one N(3), one O(1), one O(7), and one O(9) atom to form distorted corner-sharing CuN2O3 square pyramids. The Cu(1)-N(1) bond length is 1.99 Å. The Cu(1)-N(3) bond length is 1.96 Å. The Cu(1)-O(1) bond length is 2.03 Å. The Cu(1)-O(7) bond length is 2.42 Å. The Cu(1)-O(9) bond length is 2.06 Å. In the second Cu site, Cu(2) is bonded to one N(2), one N(4), one O(10), one O(2), and one O(8) atom to form distorted corner-sharing CuN2O3 square pyramids. The Cu(2)-N(2) bond length is 1.99 Å. The Cu(2)-N(4) bond length is 1.96 Å. The Cu(2)-O(10) bond length is 2.05 Å. The Cu(2)-O(2) bond length is 2.03 Å. The Cu(2)-O(8) bond length is 2.41 Å. In the third Cu site, Cu(3) is bonded to one N(5), one N(7), one O(3), one O(6), and one O(8) atom to form distorted corner-sharing CuN2O3 square pyramids. The Cu(3)-N(5) bond length is 1.97 Å. The Cu(3)-N(7) bond length is 1.98 Å. The Cu(3)-O(3) bond length is 2.02 Å. The Cu(3)-O(6) bond length is 2.07 Å. The Cu(3)-O(8) bond length is 2.42 Å. In the fourth Cu site, Cu(4) is bonded to one N(6), one N(8), one O(4), one O(5), and one O(7) atom to form distorted corner-sharing CuN2O3 square pyramids. The Cu(4)-N(6) bond length is 1.97 Å. The Cu(4)-N(8) bond length is 1.99 Å. The Cu(4)-O(4) bond length is 2.02 Å. The Cu(4)-O(5) bond length is 2.06 Å. The Cu(4)-O(7) bond length is 2.42 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(11), and one H(9) atom. The C(1)-N(1) bond length is 1.47 Å. The C(1)-H(11) bond length is 1.10 Å. The C(1)-H(9) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(10), and one H(12) atom. The C(2)-N(2) bond length is 1.48 Å. The C(2)-H(10) bond length is 1.10 Å. The C(2)-H(12) bond length is 1.10 Å. In the third C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(17), and one H(19) atom. The C(5)-N(3) bond length is 1.45 Å. The C(5)-H(17) bond length is 1.10 Å. The C(5)-H(19) bond length is 1.10 Å. In the fourth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(18), and one H(20) atom. The C(6)-N(4) bond length is 1.45 Å. The C(6)-H(18) bond length is 1.10 Å. The C(6)-H(20) bond length is 1.10 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(3) and one O(3) atom. The C(7)-N(3) bond length is 1.31 Å. The C(7)-O(3) bond length is 1.29 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(4) and one O(4) atom. The C(8)-N(4) bond length is 1.31 Å. The C(8)-O(4) bond length is 1.29 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(5) and one O(1) atom. The C(9)-N(5) bond length is 1.31 Å. The C(9)-O(1) bond length is 1.29 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(6) and one O(2) atom. The C(10)-N(6) bond length is 1.31 Å. The C(10)-O(2) bond length is 1.29 Å. In the ninth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(5), one H(21), and one H(23) atom. The C(11)-N(5) bond length is 1.46 Å. The C(11)-H(21) bond length is 1.10 Å. The C(11)-H(23) bond length is 1.10 Å. In the tenth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(22), and one H(24) atom. The C(12)-N(6) bond length is 1.46 Å. The C(12)-H(22) bond length is 1.10 Å. The C(12)-H(24) bond length is 1.10 Å. In the eleventh C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one N(7), one H(29), and one H(31) atom. The C(15)-N(7) bond length is 1.48 Å. The C(15)-H(29) bond length is 1.10 Å. The C(15)-H(31) bond length is 1.10 Å. In the twelfth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(8), one H(30), and one H(32) atom. The C(16)-N(8) bond length is 1.48 Å. The C(16)-H(30) bond length is 1.10 Å. The C(16)-H(32) bond length is 1.10 Å. In the thirteenth C site, C(17) is bonded in a single-bond geometry to one O(5) atom. The C(17)-O(5) bond length is 1.27 Å. In the fourteenth C site, C(18) is bonded in a single-bond geometry to one O(6) atom. The C(18)-O(6) bond length is 1.27 Å. In the fifteenth C site, C(19) is bonded in a distorted single-bond geometry to one O(7) atom. The C(19)-O(7) bond length is 1.26 Å. In the sixteenth C site, C(20) is bonded in a distorted single-bond geometry to one O(8) atom. The C(20)-O(8) bond length is 1.26 Å. In the seventeenth C site, C(21) is bonded in a distorted single-bond geometry to one O(9) atom. The C(21)-O(9) bond length is 1.27 Å. In the eighteenth C site, C(22) is bonded in a distorted single-bond geometry to one O(10) atom. The C(22)-O(10) bond length is 1.27 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted tetrahedral geometry to one Cu(1), one C(1), one H(1), and one H(3) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(3) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted tetrahedral geometry to one Cu(2), one C(2), one H(2), and one H(4) atom. The N(2)-H(2) bond length is 1.03 Å. The N(2)-H(4) bond length is 1.03 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(5), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(6), and one C(8) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(3), one C(11), and one C(9) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(4), one C(10), and one C(12) atom. In the seventh N site, N(7) is bonded in a distorted tetrahedral geometry to one Cu(3), one C(15), one H(5), and one H(7) atom. The N(7)-H(5) bond length is 1.03 Å. The N(7)-H(7) bond length is 1.03 Å. In the eighth N site, N(8) is bonded in a distorted tetrahedral geometry to one Cu(4), one C(16), one H(6), and one H(8) atom. The N(8)-H(6) bond length is 1.03 Å. The N(8)-H(8) bond length is 1.03 Å. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(1) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(2) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(1) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(2) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(5) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(6) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(5) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(6) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(11) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(12) atom. In the nineteenth H site, H(23) is bonded in a single-bond geometry to one C(11) atom. In the twentieth H site, H(24) is bonded in a single-bond geometry to one C(12) atom. In the twenty-first H site, H(29) is bonded in a single-bond geometry to one C(15) atom. In the twenty-second H site, H(30) is bonded in a single-bond geometry to one C(16) atom. In the twenty-third H site, H(31) is bonded in a single-bond geometry to one C(15) atom. In the twenty-fourth H site, H(32) is bonded in a single-bond geometry to one C(16) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(9) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cu(2) and one C(10) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cu(3) and one C(7) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cu(4) and one C(8) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Cu(4) and one C(17) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Cu(3) and one C(18) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cu(1), one Cu(4), and one C(19) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Cu(2), one Cu(3), and one C(20) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Cu(1) and one C(21) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Cu(2) and one C(22) atom. Linkers: 2 NCCC[N]C(=O)C(=O)[N]CCCN. Metal clusters: 4 [Cu]. The MOF has largest included sphere 3.04 A, density 1.73 g/cm3, surface area 4017.35 m2/g, accessible volume 0.16 cm3/g