CuC9H14(NO2)2CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one CuC9H14(NO2)2 cluster. In the CuC9H14(NO2)2 cluster, Cu(1) is bonded to one N(1), one N(2), one O(1), one O(2), and one O(4) atom to form distorted CuN2O3 square pyramids that share  a cornercorner with one C(5)H3N tetrahedra and  a cornercorner with one C(6)H3N tetrahedra. The Cu(1)-N(1) bond length is 1.96 Å. The Cu(1)-N(2) bond length is 2.10 Å. The Cu(1)-O(1) bond length is 2.03 Å. The Cu(1)-O(2) bond length is 1.99 Å. The Cu(1)-O(4) bond length is 2.37 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(1) atom. The C(1)-N(1) bond length is 1.31 Å. The C(1)-O(1) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(3), and one H(4) atom. The C(2)-N(1) bond length is 1.45 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. In the third C site, C(4) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(7,8) atoms. The C(4)-N(2) bond length is 1.49 Å. Both C(4)-H(7,8) bond lengths are 1.10 Å. In the fourth C site, C(5) is bonded to one N(2), one H(10), one H(11), and one H(9) atom to form CH3N tetrahedra that share  a cornercorner with one Cu(1)N2O3 square pyramid and  a cornercorner with one C(6)H3N tetrahedra. The C(5)-N(2) bond length is 1.48 Å. The C(5)-H(10) bond length is 1.09 Å. The C(5)-H(11) bond length is 1.11 Å. The C(5)-H(9) bond length is 1.09 Å. In the fifth C site, C(6) is bonded to one N(2), one H(12), one H(13), and one H(14) atom to form CH3N tetrahedra that share  a cornercorner with one Cu(1)N2O3 square pyramid and  a cornercorner with one C(5)H3N tetrahedra. The C(6)-N(2) bond length is 1.48 Å. The C(6)-H(12) bond length is 1.10 Å. The C(6)-H(13) bond length is 1.09 Å. The C(6)-H(14) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(2), and one O(3) atom. The C(7)-C(8) bond length is 1.50 Å. The C(7)-O(2) bond length is 1.29 Å. The C(7)-O(3) bond length is 1.26 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(15) atom. The C(9)-H(15) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(16) atom. The C(10)-H(16) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a tetrahedral geometry to one Cu(1), one C(4), one C(5), and one C(6) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(4) atom. The H(1)-O(4) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) and one O(4) atom. The H(2)-O(3) bond length is 1.69 Å. The H(2)-O(4) bond length is 1.00 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(7,8) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(6) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(6) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(9) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one C(7) and one H(2) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cu(1), one H(1), and one H(2) atom. Linkers: 2 [CH2][N]C(=O)C(=O)[N]CCCN(C)C ,1 CN(C)CCC[N]C(=O)C(=O)[N]CCCN(C)C ,1 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.25 A, density 1.68 g/cm3, surface area 4477.30 m2/g, accessible volume 0.15 cm3/g