CoC10NH6O4(C4H3)2C6H4SO2C3H2Cl is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one 1,4-dichlorobenzene molecule; two di-isopropenylsulfon molecules; four isobutylene molecules; and one CoC10NH6O4 cluster. In the CoC10NH6O4 cluster, Co(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(5), and one O(6) atom. The Co(1)-N(1) bond length is 2.08 Å. The Co(1)-O(1) bond length is 1.93 Å. The Co(1)-O(2) bond length is 1.89 Å. The Co(1)-O(5) bond length is 1.92 Å. The Co(1)-O(6) bond length is 1.90 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the third C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(11)-C(12) bond length is 1.49 Å. The C(11)-O(1) bond length is 1.28 Å. The C(11)-O(2) bond length is 1.28 Å. In the fourth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(17) bond length is 1.40 Å. In the fifth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(9,12) atom. The C(13)-H(9,12) bond length is 1.09 Å. In the sixth C site, C(17) is bonded in a distorted single-bond geometry to one C(12) and one H(9,12) atom. The C(17)-H(9,12) bond length is 1.09 Å. In the seventh C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(14) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(14) bond length is 1.09 Å. In the eighth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(24) bond length is 1.49 Å. In the ninth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(15) atom. The C(22)-H(15) bond length is 1.09 Å. In the tenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(5), and one O(6) atom. The C(24)-O(5) bond length is 1.28 Å. The C(24)-O(6) bond length is 1.28 Å. N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(9,12) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(11) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one C(11) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Co(1) and one C(24) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one Co(1) and one C(24) atom. Linkers: 1 C(=C/c1ccc(/C=C/c2ccncc2)cc1)\c1ccncc1 ,2 [O]C(=O)c1ccc(S(=O)(=O)c2ccc(C([O])=O)cc2)cc1. Metal clusters: 1 [C]1O[Co]234O[C]O[Co]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 2.43 A, density 1.65 g/cm3, surface area 4173.84 m2/g, accessible volume 0.11 cm3/g