(CH)2ZnC32H30S2(N5O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one ZnC32H30S2(N5O2)2 cluster. In the ZnC32H30S2(N5O2)2 cluster, Zn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent N(5) atoms. Both Zn(1)-N(1) bond lengths are 2.23 Å. Both Zn(1)-N(3) bond lengths are 2.22 Å. Both Zn(1)-N(5) bond lengths are 2.10 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.50 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one O(2) atom. The C(6)-N(2) bond length is 1.36 Å. The C(6)-O(2) bond length is 1.24 Å. In the sixth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(5), and one H(6) atom. The C(7)-N(2) bond length is 1.46 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(7), and one H(8) atom. The C(8)-N(2) bond length is 1.46 Å. The C(8)-H(7) bond length is 1.09 Å. The C(8)-H(8) bond length is 1.10 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(3), and one H(9) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-N(3) bond length is 1.35 Å. The C(9)-H(9) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(10) atom. The C(10)-H(10) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(11) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(14) bond length is 1.50 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(3), and one H(12) atom. The C(13)-N(3) bond length is 1.34 Å. The C(13)-H(12) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(4), and one O(1) atom. The C(14)-N(4) bond length is 1.36 Å. The C(14)-O(1) bond length is 1.25 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(13), and one H(14) atom. The C(15)-N(4) bond length is 1.46 Å. The C(15)-H(13) bond length is 1.09 Å. The C(15)-H(14) bond length is 1.10 Å. In the fifteenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(15), and one H(16) atom. The C(16)-N(4) bond length is 1.46 Å. The C(16)-H(15) bond length is 1.11 Å. The C(16)-H(16) bond length is 1.10 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one N(5) and one S(1) atom. The C(17)-N(5) bond length is 1.19 Å. The C(17)-S(1) bond length is 1.61 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(6), one C(7), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(9) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(16) atom. In the fifth N site, N(5) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(17) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. S(1) is bonded in a single-bond geometry to one C(17) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(14) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(6) atom. Linkers: 2 O=C(c1cccnc1)N1CCN(C(=O)c2cccnc2)CC1 ,4 O=C(c1cc[c]nc1)N1CCN(C(=O)c2cccnc2)CC1. Metal clusters: 1 [Zn]. The MOF has largest included sphere 2.86 A, density 1.46 g/cm3, surface area 4756.11 m2/g, accessible volume 0.17 cm3/g