ZnC13NH7O5(CH)3C5H5N is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules, four C5H5N clusters, and four ZnC13NH7O5 clusters. In each C5H5N cluster, there are five inequivalent C sites. In the first C site, C(10) is bonded in a distorted trigonal planar geometry to one C(20), one C(7), and one N(2) atom. The C(10)-C(20) bond length is 1.50 Å. The C(10)-C(7) bond length is 1.48 Å. The C(10)-N(2) bond length is 1.31 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(7) and one H(2) atom. The C(3)-C(7) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the third C site, C(20) is bonded in a trigonal non-coplanar geometry to one C(10), one H(12), one H(13), and one H(14) atom. The C(20)-H(12) bond length is 1.09 Å. The C(20)-H(13) bond length is 1.10 Å. The C(20)-H(14) bond length is 1.10 Å. In the fourth C site, C(14) is bonded in a distorted single-bond geometry to one C(7) and one H(8) atom. The C(14)-C(7) bond length is 1.41 Å. The C(14)-H(8) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(3) atom. N(2) is bonded in a distorted bent 120 degrees geometry to one C(10) and one N(2) atom. The N(2)-N(2) bond length is 1.37 Å. There are five inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In each ZnC13NH7O5 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 2.07 Å. The Zn(1)-O(2) bond length is 2.07 Å. The Zn(1)-O(3) bond length is 2.07 Å. The Zn(1)-O(4) bond length is 2.07 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(5) and one H(1) atom. The C(1)-C(5) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(2), and one O(3) atom. The C(2)-C(6) bond length is 1.50 Å. The C(2)-O(2) bond length is 1.27 Å. The C(2)-O(3) bond length is 1.28 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(4) atom. The C(4)-C(5) bond length is 1.50 Å. The C(4)-O(1) bond length is 1.27 Å. The C(4)-O(4) bond length is 1.28 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(15), and one C(4) atom. The C(5)-C(15) bond length is 1.40 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(16), one C(2), and one C(9) atom. The C(6)-C(16) bond length is 1.40 Å. The C(6)-C(9) bond length is 1.40 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(8)-N(1) bond length is 1.34 Å. The C(8)-H(3) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(9)-H(4) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(5) bond length is 1.09 Å. In the ninth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(19), one C(5), and one H(9) atom. The C(15)-C(19) bond length is 1.39 Å. The C(15)-H(9) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(6) and one H(10) atom. The C(16)-H(10) bond length is 1.09 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(19) and one O(5) atom. The C(17)-C(19) bond length is 1.40 Å. The C(17)-O(5) bond length is 1.39 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one O(5) atom. The C(18)-O(5) bond length is 1.38 Å. In the thirteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(11) atom. The C(19)-H(11) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(8) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(17) and one C(18) atom. Linkers: 4 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,2 C[C]([N][N][C](C)c1ccncc1)c1ccncc1. Metal clusters: 2 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 4.69 A, density 1.17 g/cm3, surface area 4610.79 m2/g, accessible volume 0.42 cm3/g