VCuC12PN3H10O6F(CH)4 crystallizes in the monoclinic C2 space group. The structure consists of sixteen 02329_fluka molecules inside a VCuC12PN3H10O6F framework. In the VCuC12PN3H10O6F framework, V(1) is bonded to one O(3), one O(4), one O(5), one O(6), and one F(1) atom to form distorted VO4F trigonal bipyramids that share corners with two equivalent P(1)CO3 tetrahedra. The V(1)-O(3) bond length is 2.00 Å. The V(1)-O(4) bond length is 1.65 Å. The V(1)-O(5) bond length is 1.99 Å. The V(1)-O(6) bond length is 1.63 Å. The V(1)-F(1) bond length is 1.92 Å. Cu(1) is bonded to one N(1), one N(2), one N(3), one O(1), and one O(2) atom to form distorted CuN3O2 square pyramids that share  a cornercorner with one P(1)CO3 tetrahedra. The Cu(1)-N(1) bond length is 2.02 Å. The Cu(1)-N(2) bond length is 1.95 Å. The Cu(1)-N(3) bond length is 2.04 Å. The Cu(1)-O(1) bond length is 2.21 Å. The Cu(1)-O(2) bond length is 1.91 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(3) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(6) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(6) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.47 Å. The C(5)-N(1) bond length is 1.36 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(6), and one N(2) atom. The C(6)-C(6) bond length is 1.42 Å. The C(6)-N(2) bond length is 1.34 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(7), one C(8), and one N(2) atom. The C(7)-C(7) bond length is 1.42 Å. The C(7)-C(8) bond length is 1.47 Å. The C(7)-N(2) bond length is 1.34 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(3) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-N(3) bond length is 1.36 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the eighth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(10) atom. The C(12)-N(3) bond length is 1.34 Å. The C(12)-H(10) bond length is 1.09 Å. In the ninth C site, C(13) is bonded in a distorted water-like geometry to one C(14), one P(1), one H(11), and one H(12) atom. The C(13)-C(14) bond length is 1.50 Å. The C(13)-P(1) bond length is 1.83 Å. The C(13)-H(11) bond length is 1.10 Å. The C(13)-H(12) bond length is 1.10 Å. In the tenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(17) bond length is 1.41 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(13) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(13) bond length is 1.09 Å. In the twelfth C site, C(16) is bonded in a distorted trigonal planar geometry to two equivalent C(15) and one H(14) atom. The C(16)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to two equivalent C(14) and one H(15) atom. The C(17)-H(15) bond length is 1.09 Å. P(1) is bonded to one C(13), one O(2), one O(3), and one O(5) atom to form PCO3 tetrahedra that share  a cornercorner with one Cu(1)N3O2 square pyramid and corners with two equivalent V(1)O4F trigonal bipyramids. The P(1)-O(2) bond length is 1.54 Å. The P(1)-O(3) bond length is 1.54 Å. The P(1)-O(5) bond length is 1.53 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(6), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(12), and one C(8) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(1) and one O(4) atom. The H(1)-O(1) bond length is 1.00 Å. The H(1)-O(4) bond length is 1.62 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(1) and one F(1) atom. The H(2)-O(1) bond length is 0.99 Å. The H(2)-F(1) bond length is 1.60 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(17) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cu(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Cu(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one H(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one V(1) atom. F(1) is bonded in a water-like geometry to one V(1) and one H(2) atom. Linkers: 1 [O]P([O])(=O)Cc1cccc(CP([O])([O])=O)c1 ,2 [c]1[c]nc(-c2nc(-c3ccc[c]n3)c(-c3ccccn3)nc2-c2ccccn2)cc1 ,1 c1ccc(-c2nc(-c3ccccn3)c(-c3ccccn3)nc2-c2ccccn2)nc1. Metal clusters: 2 [V] ,2 [Cu]. The MOF has largest included sphere 2.59 A, density 1.92 g/cm3, surface area 3557.24 m2/g, accessible volume 0.10 cm3/g