CuC6H4(N2O)2(CF)2 crystallizes in the triclinic P1 space group. The structure consists of sixteen fluoromethane molecules inside a CuC6H4(N2O)2 framework. In the CuC6H4(N2O)2 framework, there are eight inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to one N(1), one N(17), one N(31), and one N(9) atom. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-N(17) bond length is 1.98 Å. The Cu(1)-N(31) bond length is 1.98 Å. The Cu(1)-N(9) bond length is 1.99 Å. In the second Cu site, Cu(2) is bonded in a square co-planar geometry to one N(10), one N(18), one N(2), and one N(32) atom. The Cu(2)-N(10) bond length is 1.99 Å. The Cu(2)-N(18) bond length is 1.98 Å. The Cu(2)-N(2) bond length is 1.98 Å. The Cu(2)-N(32) bond length is 1.98 Å. In the third Cu site, Cu(3) is bonded in a square co-planar geometry to one N(11), one N(19), one N(3), and one N(30) atom. The Cu(3)-N(11) bond length is 1.99 Å. The Cu(3)-N(19) bond length is 1.97 Å. The Cu(3)-N(3) bond length is 1.98 Å. The Cu(3)-N(30) bond length is 1.97 Å. In the fourth Cu site, Cu(4) is bonded in a square co-planar geometry to one N(12), one N(20), one N(29), and one N(4) atom. The Cu(4)-N(12) bond length is 1.99 Å. The Cu(4)-N(20) bond length is 1.98 Å. The Cu(4)-N(29) bond length is 1.98 Å. The Cu(4)-N(4) bond length is 1.98 Å. In the fifth Cu site, Cu(5) is bonded in a square co-planar geometry to one N(13), one N(21), one N(26), and one N(5) atom. The Cu(5)-N(13) bond length is 1.99 Å. The Cu(5)-N(21) bond length is 1.98 Å. The Cu(5)-N(26) bond length is 1.98 Å. The Cu(5)-N(5) bond length is 1.98 Å. In the sixth Cu site, Cu(6) is bonded in a square co-planar geometry to one N(14), one N(22), one N(25), and one N(6) atom. The Cu(6)-N(14) bond length is 2.00 Å. The Cu(6)-N(22) bond length is 1.98 Å. The Cu(6)-N(25) bond length is 1.97 Å. The Cu(6)-N(6) bond length is 1.97 Å. In the seventh Cu site, Cu(7) is bonded in a square co-planar geometry to one N(15), one N(23), one N(27), and one N(7) atom. The Cu(7)-N(15) bond length is 1.99 Å. The Cu(7)-N(23) bond length is 1.98 Å. The Cu(7)-N(27) bond length is 1.98 Å. The Cu(7)-N(7) bond length is 1.98 Å. In the eighth Cu site, Cu(8) is bonded in a square co-planar geometry to one N(16), one N(24), one N(28), and one N(8) atom. The Cu(8)-N(16) bond length is 1.99 Å. The Cu(8)-N(24) bond length is 1.98 Å. The Cu(8)-N(28) bond length is 1.98 Å. The Cu(8)-N(8) bond length is 1.98 Å. There are forty-one inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(1) atom. The C(1)-N(1) bond length is 1.39 Å. The C(1)-N(2) bond length is 1.39 Å. The C(1)-O(1) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(3), one N(4), and one O(2) atom. The C(2)-N(3) bond length is 1.39 Å. The C(2)-N(4) bond length is 1.39 Å. The C(2)-O(2) bond length is 1.25 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(5), one N(7), and one O(3) atom. The C(3)-N(5) bond length is 1.39 Å. The C(3)-N(7) bond length is 1.39 Å. The C(3)-O(3) bond length is 1.25 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(6), one N(8), and one O(4) atom. The C(4)-N(6) bond length is 1.39 Å. The C(4)-N(8) bond length is 1.39 Å. The C(4)-O(4) bond length is 1.25 Å. In the fifth C site, C(5,9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,4) atom. The C(5,9)-N(1) bond length is 1.33 Å. The C(5,9)-H(1,4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2,5,6,7) atom. The C(6)-N(2) bond length is 1.33 Å. The C(6)-H(2,5,6,7) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(3) atom. The C(7)-N(3) bond length is 1.33 Å. The C(7)-H(3) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(1,4) atom. The C(8)-N(4) bond length is 1.33 Å. The C(8)-H(1,4) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(2,5,6,7) atom. The C(10)-N(6) bond length is 1.33 Å. The C(10)-H(2,5,6,7) bond length is 1.09 Å. In the tenth C site, C(11,12) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(2,5,6,7) atom. The C(11,12)-N(7) bond length is 1.33 Å. The C(11,12)-H(2,5,6,7) bond length is 1.09 Å. In the eleventh C site, C(17) is bonded in a trigonal planar geometry to one N(12), one N(9), and one O(5) atom. The C(17)-N(12) bond length is 1.39 Å. The C(17)-N(9) bond length is 1.39 Å. The C(17)-O(5) bond length is 1.24 Å. In the twelfth C site, C(18) is bonded in a trigonal planar geometry to one N(10), one N(11), and one O(6) atom. The C(18)-N(10) bond length is 1.39 Å. The C(18)-N(11) bond length is 1.39 Å. The C(18)-O(6) bond length is 1.24 Å. In the thirteenth C site, C(19) is bonded in a trigonal planar geometry to one N(13), one N(14), and one O(7) atom. The C(19)-N(13) bond length is 1.39 Å. The C(19)-N(14) bond length is 1.39 Å. The C(19)-O(7) bond length is 1.24 Å. In the fourteenth C site, C(20) is bonded in a trigonal planar geometry to one N(15), one N(16), and one O(8) atom. The C(20)-N(15) bond length is 1.39 Å. The C(20)-N(16) bond length is 1.39 Å. The C(20)-O(8) bond length is 1.24 Å. In the fifteenth C site, C(21,24,25) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(9) atom. The C(21,24,25)-N(9) bond length is 1.33 Å. The C(21,24,25)-H(9) bond length is 1.09 Å. In the sixteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(10) atom. The C(22)-N(10) bond length is 1.33 Å. The C(22)-H(10) bond length is 1.09 Å. In the seventeenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(11) atom. The C(23)-N(11) bond length is 1.33 Å. The C(23)-H(11) bond length is 1.09 Å. In the eighteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(14) atom. The C(26)-N(14) bond length is 1.33 Å. The C(26)-H(14) bond length is 1.09 Å. In the nineteenth C site, C(27,28) is bonded in a distorted bent 120 degrees geometry to one N(15) and one H(15,16) atom. The C(27,28)-N(15) bond length is 1.33 Å. The C(27,28)-H(15,16) bond length is 1.09 Å. In the twentieth C site, C(33) is bonded in a trigonal planar geometry to one N(17), one N(25), and one O(9) atom. The C(33)-N(17) bond length is 1.39 Å. The C(33)-N(25) bond length is 1.39 Å. The C(33)-O(9) bond length is 1.24 Å. In the twenty-first C site, C(34) is bonded in a trigonal planar geometry to one N(18); one N(26); and one O(10,13) atom. The C(34)-N(18) bond length is 1.39 Å. The C(34)-N(26) bond length is 1.39 Å. The C(34)-O(10,13) bond length is 1.25 Å. In the twenty-second C site, C(35) is bonded in a trigonal planar geometry to one N(19), one N(27), and one O(11) atom. The C(35)-N(19) bond length is 1.39 Å. The C(35)-N(27) bond length is 1.39 Å. The C(35)-O(11) bond length is 1.24 Å. In the twenty-third C site, C(36) is bonded in a trigonal planar geometry to one N(20), one N(28), and one O(12) atom. The C(36)-N(20) bond length is 1.39 Å. The C(36)-N(28) bond length is 1.39 Å. The C(36)-O(12) bond length is 1.24 Å. In the twenty-fourth C site, C(37) is bonded in a trigonal planar geometry to one N(21); one N(29); and one O(10,13) atom. The C(37)-N(21) bond length is 1.39 Å. The C(37)-N(29) bond length is 1.39 Å. The C(37)-O(10,13) bond length is 1.25 Å. In the twenty-fifth C site, C(38) is bonded in a trigonal planar geometry to one N(22), one N(30), and one O(14) atom. The C(38)-N(22) bond length is 1.39 Å. The C(38)-N(30) bond length is 1.39 Å. The C(38)-O(14) bond length is 1.24 Å. In the twenty-sixth C site, C(39) is bonded in a trigonal planar geometry to one N(23), one N(31), and one O(15) atom. The C(39)-N(23) bond length is 1.39 Å. The C(39)-N(31) bond length is 1.39 Å. The C(39)-O(15) bond length is 1.25 Å. In the twenty-seventh C site, C(40) is bonded in a trigonal planar geometry to one N(24), one N(32), and one O(16) atom. The C(40)-N(24) bond length is 1.39 Å. The C(40)-N(32) bond length is 1.39 Å. The C(40)-O(16) bond length is 1.24 Å. In the twenty-eighth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(25) and one H(17) atom. The C(41)-N(25) bond length is 1.34 Å. The C(41)-H(17) bond length is 1.09 Å. In the twenty-ninth C site, C(42,47) is bonded in a distorted bent 120 degrees geometry to one N(26) and one H(18,20,21,22) atom. The C(42,47)-N(26) bond length is 1.34 Å. The C(42,47)-H(18,20,21,22) bond length is 1.09 Å. In the thirtieth C site, C(43) is bonded in a distorted bent 120 degrees geometry to one N(27) and one H(19) atom. The C(43)-N(27) bond length is 1.34 Å. The C(43)-H(19) bond length is 1.09 Å. In the thirty-first C site, C(44,48) is bonded in a distorted bent 120 degrees geometry to one N(28) and one H(18,20,21,22) atom. The C(44,48)-N(28) bond length is 1.34 Å. The C(44,48)-H(18,20,21,22) bond length is 1.09 Å. In the thirty-second C site, C(45) is bonded in a distorted bent 120 degrees geometry to one N(29) and one H(18,20,21,22) atom. The C(45)-N(29) bond length is 1.34 Å. The C(45)-H(18,20,21,22) bond length is 1.09 Å. In the thirty-third C site, C(46) is bonded in a distorted bent 120 degrees geometry to one N(30) and one H(18,20,21,22) atom. The C(46)-N(30) bond length is 1.34 Å. The C(46)-H(18,20,21,22) bond length is 1.09 Å. In the thirty-fourth C site, C(57) is bonded in a distorted bent 120 degrees geometry to one N(17) and one H(25,30) atom. The C(57)-N(17) bond length is 1.33 Å. The C(57)-H(25,30) bond length is 1.09 Å. In the thirty-fifth C site, C(58) is bonded in a distorted bent 120 degrees geometry to one N(18) and one H(26,29,31,32) atom. The C(58)-N(18) bond length is 1.33 Å. The C(58)-H(26,29,31,32) bond length is 1.09 Å. In the thirty-sixth C site, C(59) is bonded in a distorted bent 120 degrees geometry to one N(19) and one H(27) atom. The C(59)-N(19) bond length is 1.33 Å. The C(59)-H(27) bond length is 1.09 Å. In the thirty-seventh C site, C(60) is bonded in a distorted bent 120 degrees geometry to one N(20) and one H(28) atom. The C(60)-N(20) bond length is 1.33 Å. The C(60)-H(28) bond length is 1.09 Å. In the thirty-eighth C site, C(61) is bonded in a distorted bent 120 degrees geometry to one N(21) and one H(26,29,31,32) atom. The C(61)-N(21) bond length is 1.33 Å. The C(61)-H(26,29,31,32) bond length is 1.09 Å. In the thirty-ninth C site, C(62) is bonded in a distorted bent 120 degrees geometry to one N(22) and one H(25,30) atom. The C(62)-N(22) bond length is 1.33 Å. The C(62)-H(25,30) bond length is 1.09 Å. In the fortieth C site, C(63) is bonded in a distorted bent 120 degrees geometry to one N(23) and one H(26,29,31,32) atom. The C(63)-N(23) bond length is 1.33 Å. The C(63)-H(26,29,31,32) bond length is 1.09 Å. In the forty-first C site, C(64) is bonded in a distorted bent 120 degrees geometry to one N(24) and one H(26,29,31,32) atom. The C(64)-N(24) bond length is 1.33 Å. The C(64)-H(26,29,31,32) bond length is 1.09 Å. There are thirty-two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1); one C(1); and one C(5,9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(1), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(3), one C(2), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(4), one C(2), and one C(8) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(5); one C(3); and one C(5,9) atom. The N(5)-C(5,9) bond length is 1.33 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(6), one C(10), and one C(4) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Cu(7); one C(11,12); and one C(3) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Cu(8); one C(11,12); and one C(4) atom. The N(8)-C(11,12) bond length is 1.33 Å. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Cu(1); one C(17); and one C(21,24,25) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Cu(2), one C(18), and one C(22) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Cu(3), one C(18), and one C(23) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Cu(4); one C(17); and one C(21,24,25) atom. The N(12)-C(21,24,25) bond length is 1.33 Å. In the thirteenth N site, N(13) is bonded in a trigonal planar geometry to one Cu(5); one C(19); and one C(21,24,25) atom. The N(13)-C(21,24,25) bond length is 1.33 Å. In the fourteenth N site, N(14) is bonded in a trigonal planar geometry to one Cu(6), one C(19), and one C(26) atom. In the fifteenth N site, N(15) is bonded in a trigonal planar geometry to one Cu(7); one C(20); and one C(27,28) atom. In the sixteenth N site, N(16) is bonded in a trigonal planar geometry to one Cu(8); one C(20); and one C(27,28) atom. The N(16)-C(27,28) bond length is 1.33 Å. In the seventeenth N site, N(17) is bonded in a trigonal planar geometry to one Cu(1), one C(33), and one C(57) atom. In the eighteenth N site, N(18) is bonded in a trigonal planar geometry to one Cu(2), one C(34), and one C(58) atom. In the nineteenth N site, N(19) is bonded in a trigonal planar geometry to one Cu(3), one C(35), and one C(59) atom. In the twentieth N site, N(20) is bonded in a trigonal planar geometry to one Cu(4), one C(36), and one C(60) atom. In the twenty-first N site, N(21) is bonded in a trigonal planar geometry to one Cu(5), one C(37), and one C(61) atom. In the twenty-second N site, N(22) is bonded in a trigonal planar geometry to one Cu(6), one C(38), and one C(62) atom. In the twenty-third N site, N(23) is bonded in a trigonal planar geometry to one Cu(7), one C(39), and one C(63) atom. In the twenty-fourth N site, N(24) is bonded in a trigonal planar geometry to one Cu(8), one C(40), and one C(64) atom. In the twenty-fifth N site, N(25) is bonded in a trigonal planar geometry to one Cu(6), one C(33), and one C(41) atom. In the twenty-sixth N site, N(26) is bonded in a trigonal planar geometry to one Cu(5); one C(34); and one C(42,47) atom. In the twenty-seventh N site, N(27) is bonded in a trigonal planar geometry to one Cu(7), one C(35), and one C(43) atom. In the twenty-eighth N site, N(28) is bonded in a trigonal planar geometry to one Cu(8); one C(36); and one C(44,48) atom. In the twenty-ninth N site, N(29) is bonded in a trigonal planar geometry to one Cu(4), one C(37), and one C(45) atom. In the thirtieth N site, N(30) is bonded in a trigonal planar geometry to one Cu(3), one C(38), and one C(46) atom. In the thirty-first N site, N(31) is bonded in a trigonal planar geometry to one Cu(1); one C(39); and one C(42,47) atom. The N(31)-C(42,47) bond length is 1.34 Å. In the thirty-second N site, N(32) is bonded in a trigonal planar geometry to one Cu(2); one C(40); and one C(44,48) atom. The N(32)-C(44,48) bond length is 1.34 Å. There are nineteen inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(5,9) atom. In the second H site, H(2,5,6,7) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(11,12) atom. The H(8)-C(11,12) bond length is 1.09 Å. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(21,24,25) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(22) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(23) atom. In the eighth H site, H(12,13) is bonded in a single-bond geometry to one C(21,24,25) atom. The H(12,13)-C(21,24,25) bond length is 1.09 Å. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(15,16) is bonded in a single-bond geometry to one C(27,28) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(41) atom. In the twelfth H site, H(18,20,21,22) is bonded in a single-bond geometry to one C(42,47) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(43) atom. In the fourteenth H site, H(23) is bonded in a single-bond geometry to one C(42,47) atom. The H(23)-C(42,47) bond length is 1.09 Å. In the fifteenth H site, H(24) is bonded in a single-bond geometry to one C(44,48) atom. The H(24)-C(44,48) bond length is 1.09 Å. In the sixteenth H site, H(25,30) is bonded in a single-bond geometry to one C(57) atom. In the seventeenth H site, H(26,29,31,32) is bonded in a single-bond geometry to one C(58) atom. In the eighteenth H site, H(27) is bonded in a single-bond geometry to one C(59) atom. In the nineteenth H site, H(28) is bonded in a single-bond geometry to one C(60) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(17) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(18) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(19) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(20) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(33) atom. In the tenth O site, O(10,13) is bonded in a single-bond geometry to one C(34) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one C(35) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one C(36) atom. In the thirteenth O site, O(14) is bonded in a single-bond geometry to one C(38) atom. In the fourteenth O site, O(15) is bonded in a single-bond geometry to one C(39) atom. In the fifteenth O site, O(16) is bonded in a single-bond geometry to one C(40) atom. Linkers: 16 O=C1N=C[C](F)C=N1. Metal clusters: 8 [Cu]. The MOF has largest included sphere 3.37 A, density 1.75 g/cm3, surface area 3993.72 m2/g, accessible volume 0.17 cm3/g