ZnC28N5H22O4(CH)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and two ZnC28N5H22O4 clusters. In each ZnC28N5H22O4 cluster, Zn(1) is bonded in a distorted trigonal bipyramidal geometry to one N(5); two equivalent N(1,2); and two equivalent O(1,2) atoms. The Zn(1)-N(5) bond length is 2.01 Å. Both Zn(1)-N(1,2) bond lengths are 2.01 Å. Both Zn(1)-O(1,2) bond lengths are 2.22 Å. There are fourteen inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted trigonal non-coplanar geometry to one C(3,4); one H(1,2); one H(3,4); and one H(5,6) atom. The C(1,2)-C(3,4) bond length is 1.48 Å. The C(1,2)-H(1,2) bond length is 1.10 Å. The C(1,2)-H(3,4) bond length is 1.10 Å. The C(1,2)-H(5,6) bond length is 1.10 Å. In the second C site, C(3,4) is bonded in a distorted trigonal planar geometry to one C(1,2); one N(1,2); and one N(3,4) atom. The C(3,4)-N(1,2) bond length is 1.34 Å. The C(3,4)-N(3,4) bond length is 1.36 Å. In the third C site, C(5,6) is bonded in a distorted single-bond geometry to one C(15,16); one C(7,8); and one N(1,2) atom. The C(5,6)-C(15,16) bond length is 1.41 Å. The C(5,6)-C(7,8) bond length is 1.40 Å. The C(5,6)-N(1,2) bond length is 1.39 Å. In the fourth C site, C(7,8) is bonded in a distorted single-bond geometry to one C(5,6) and one H(7,8) atom. The C(7,8)-H(7,8) bond length is 1.09 Å. In the fifth C site, C(11,12) is bonded in a distorted single-bond geometry to one C(13,14) and one H(11,12) atom. The C(11,12)-C(13,14) bond length is 1.39 Å. The C(11,12)-H(11,12) bond length is 1.09 Å. In the sixth C site, C(13,14) is bonded in a distorted trigonal planar geometry to one C(11,12); one C(15,16); and one H(13,14) atom. The C(13,14)-C(15,16) bond length is 1.40 Å. The C(13,14)-H(13,14) bond length is 1.09 Å. In the seventh C site, C(15,16) is bonded in a distorted single-bond geometry to one C(13,14); one C(5,6); and one N(3,4) atom. The C(15,16)-N(3,4) bond length is 1.39 Å. In the eighth C site, C(17,18) is bonded in a distorted trigonal non-coplanar geometry to one C(19,20); one N(3,4); one H(15,16); and one H(17,18) atom. The C(17,18)-C(19,20) bond length is 1.51 Å. The C(17,18)-N(3,4) bond length is 1.46 Å. The C(17,18)-H(15,16) bond length is 1.10 Å. The C(17,18)-H(17,18) bond length is 1.10 Å. In the ninth C site, C(19,20) is bonded in a trigonal planar geometry to one C(17,18); one C(21,22); and one C(23,24) atom. The C(19,20)-C(21,22) bond length is 1.40 Å. The C(19,20)-C(23,24) bond length is 1.40 Å. In the tenth C site, C(21,22) is bonded in a distorted single-bond geometry to one C(19,20) and one H(19,20,21,22) atom. The C(21,22)-H(19,20,21,22) bond length is 1.09 Å. In the eleventh C site, C(23,24) is bonded in a distorted single-bond geometry to one C(19,20) and one H(19,20,21,22) atom. The C(23,24)-H(19,20,21,22) bond length is 1.09 Å. In the twelfth C site, C(25,26) is bonded in a distorted bent 120 degrees geometry to one C(27,28); one O(1,2); and one O(3,4) atom. The C(25,26)-C(27,28) bond length is 1.53 Å. The C(25,26)-O(1,2) bond length is 1.28 Å. The C(25,26)-O(3,4) bond length is 1.25 Å. In the thirteenth C site, C(27,28) is bonded in a distorted trigonal planar geometry to one C(25,26); one C(29,30); and one N(5) atom. The C(27,28)-C(29,30) bond length is 1.40 Å. The C(27,28)-N(5) bond length is 1.34 Å. In the fourteenth C site, C(29,30) is bonded in a distorted single-bond geometry to one C(27,28) and one H(23,24) atom. The C(29,30)-H(23,24) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1,2) is bonded in a trigonal planar geometry to one Zn(1); one C(3,4); and one C(5,6) atom. In the second N site, N(3,4) is bonded in a trigonal planar geometry to one C(15,16); one C(17,18); and one C(3,4) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Zn(1) and two equivalent C(27,28) atoms. There are ten inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(1,2) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(1,2) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(7,8) atom. In the fifth H site, H(11,12) is bonded in a single-bond geometry to one C(11,12) atom. In the sixth H site, H(13,14) is bonded in a single-bond geometry to one C(13,14) atom. In the seventh H site, H(15,16) is bonded in a single-bond geometry to one C(17,18) atom. In the eighth H site, H(17,18) is bonded in a single-bond geometry to one C(17,18) atom. In the ninth H site, H(19,20,21,22) is bonded in a single-bond geometry to one C(21,22) atom. In the tenth H site, H(23,24) is bonded in a single-bond geometry to one C(29,30) atom. There are two inequivalent O sites. In the first O site, O(3,4) is bonded in a single-bond geometry to one C(25,26) atom. In the second O site, O(1,2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(25,26) atom. Linkers: 2 Cc1nc2ccccc2n1Cc1ccc(Cn2c(C)nc3ccccc32)cc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 3.31 A, density 1.38 g/cm3, surface area 4743.14 m2/g, accessible volume 0.21 cm3/g