ZnC14H12(NO2)2(CH)2(CH2)5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, ten 02329_fluka molecules, and two ZnC14H12(NO2)2 clusters. In each ZnC14H12(NO2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(4) atom. The Zn(1)-N(1) bond length is 2.06 Å. The Zn(1)-N(2) bond length is 2.05 Å. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(4) bond length is 1.97 Å. There are fourteen inequivalent C sites. In the first C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(7)-O(1) bond length is 1.31 Å. The C(7)-O(2) bond length is 1.24 Å. In the second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.25 Å. The C(8)-O(4) bond length is 1.31 Å. In the third C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(11) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(11) bond length is 1.10 Å. In the fourth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(12) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(12) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(19) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(19) bond length is 1.51 Å. In the sixth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(13) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-H(13) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(1), and one H(14) atom. The C(13)-N(1) bond length is 1.35 Å. The C(13)-H(14) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(15), one N(2), and one H(15) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-N(2) bond length is 1.34 Å. The C(14)-H(15) bond length is 1.09 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(16) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(16) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.50 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(17) atom. The C(17)-H(17) bond length is 1.09 Å. In the twelfth C site, C(18) is bonded in a distorted trigonal planar geometry to one N(2) and one H(18) atom. The C(18)-N(2) bond length is 1.34 Å. The C(18)-H(18) bond length is 1.09 Å. In the thirteenth C site, C(19) is bonded in a distorted water-like geometry to one C(11), one H(19), and one H(20) atom. The C(19)-H(19) bond length is 1.10 Å. The C(19)-H(20) bond length is 1.11 Å. In the fourteenth C site, C(21) is bonded in a distorted water-like geometry to one C(16) and two equivalent H(23,24) atoms. Both C(21)-H(23,24) bond lengths are 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(14), and one C(18) atom. There are eleven inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(23,24) is bonded in a single-bond geometry to one C(21) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(7) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zn(1) and one C(8) atom. Linkers: 2 [O]C(=O)[C@H]1CC[C@@H](C([O])=O)CC1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 5.07 A, density 1.19 g/cm3, surface area 5296.23 m2/g, accessible volume 0.30 cm3/g