TbC26H14(NO2)4(CH)4NO3 crystallizes in the triclinic P-1 space group. The structure consists of eight 02329_fluka molecules and two nitric acid molecules inside a TbC26H14(NO2)4 framework. In the TbC26H14(NO2)4 framework, Tb(1) is bonded in a distorted pentagonal pyramidal geometry to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. The Tb(1)-O(3) bond length is 2.27 Å. The Tb(1)-O(4) bond length is 2.27 Å. The Tb(1)-O(5) bond length is 2.28 Å. The Tb(1)-O(6) bond length is 2.29 Å. The Tb(1)-O(7) bond length is 2.31 Å. The Tb(1)-O(8) bond length is 2.31 Å. There are twenty-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(11), one C(3), and one N(3) atom. The C(1)-C(11) bond length is 1.41 Å. The C(1)-C(3) bond length is 1.39 Å. The C(1)-N(3) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(12), one C(4), and one N(4) atom. The C(2)-C(12) bond length is 1.41 Å. The C(2)-C(4) bond length is 1.39 Å. The C(2)-N(4) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(3)-H(1) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(4)-H(2) bond length is 1.08 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(9)-C(11) bond length is 1.40 Å. The C(9)-H(7) bond length is 1.09 Å. In the sixth C site, C(10) is bonded in a distorted single-bond geometry to one C(12) and one H(8) atom. The C(10)-C(12) bond length is 1.40 Å. The C(10)-H(8) bond length is 1.09 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(1), one C(9), and one N(1) atom. The C(11)-N(1) bond length is 1.38 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(10), one C(2), and one N(2) atom. The C(12)-N(2) bond length is 1.38 Å. In the ninth C site, C(13) is bonded in a distorted water-like geometry to one C(15), one N(1), and one N(3) atom. The C(13)-C(15) bond length is 1.45 Å. The C(13)-N(1) bond length is 1.35 Å. The C(13)-N(3) bond length is 1.36 Å. In the tenth C site, C(14) is bonded in a distorted water-like geometry to one C(16), one N(2), and one N(4) atom. The C(14)-C(16) bond length is 1.45 Å. The C(14)-N(2) bond length is 1.35 Å. The C(14)-N(4) bond length is 1.36 Å. In the eleventh C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(27) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-C(27) bond length is 1.40 Å. In the twelfth C site, C(16) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(28) atom. The C(16)-C(18) bond length is 1.40 Å. The C(16)-C(28) bond length is 1.40 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(15), one C(19), and one H(9) atom. The C(17)-C(19) bond length is 1.39 Å. The C(17)-H(9) bond length is 1.09 Å. In the fourteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one H(10) atom. The C(18)-C(20) bond length is 1.39 Å. The C(18)-H(10) bond length is 1.09 Å. In the fifteenth C site, C(19) is bonded in a trigonal planar geometry to one C(17), one C(21), and one C(23) atom. The C(19)-C(21) bond length is 1.50 Å. The C(19)-C(23) bond length is 1.40 Å. In the sixteenth C site, C(20) is bonded in a trigonal planar geometry to one C(18), one C(22), and one C(24) atom. The C(20)-C(22) bond length is 1.50 Å. The C(20)-C(24) bond length is 1.40 Å. In the seventeenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(1), and one O(3) atom. The C(21)-O(1) bond length is 1.27 Å. The C(21)-O(3) bond length is 1.27 Å. In the eighteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(2), and one O(4) atom. The C(22)-O(2) bond length is 1.27 Å. The C(22)-O(4) bond length is 1.27 Å. In the nineteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(19), one C(25), and one H(11) atom. The C(23)-C(25) bond length is 1.40 Å. The C(23)-H(11) bond length is 1.09 Å. In the twentieth C site, C(24) is bonded in a distorted single-bond geometry to one C(20), one C(26), and one H(12) atom. The C(24)-C(26) bond length is 1.40 Å. The C(24)-H(12) bond length is 1.09 Å. In the twenty-first C site, C(25) is bonded in a trigonal planar geometry to one C(23), one C(27), and one C(29) atom. The C(25)-C(27) bond length is 1.39 Å. The C(25)-C(29) bond length is 1.51 Å. In the twenty-second C site, C(26) is bonded in a trigonal planar geometry to one C(24), one C(28), and one C(30) atom. The C(26)-C(28) bond length is 1.39 Å. The C(26)-C(30) bond length is 1.51 Å. In the twenty-third C site, C(27) is bonded in a distorted single-bond geometry to one C(15), one C(25), and one H(13) atom. The C(27)-H(13) bond length is 1.08 Å. In the twenty-fourth C site, C(28) is bonded in a distorted single-bond geometry to one C(16), one C(26), and one H(14) atom. The C(28)-H(14) bond length is 1.08 Å. In the twenty-fifth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(5), and one O(7) atom. The C(29)-O(5) bond length is 1.27 Å. The C(29)-O(7) bond length is 1.27 Å. In the twenty-sixth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(6), and one O(8) atom. The C(30)-O(6) bond length is 1.27 Å. The C(30)-O(8) bond length is 1.27 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(11), one C(13), and one H(15) atom. The N(1)-H(15) bond length is 1.09 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(12), one C(14), and one H(16) atom. The N(2)-H(16) bond length is 1.09 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(13), and one H(17) atom. The N(3)-H(17) bond length is 1.04 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(14), one C(2), and one H(18) atom. The N(4)-H(18) bond length is 1.03 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(23) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(28) atom. In the eleventh H site, H(15) is bonded in a linear geometry to one N(1) and one O(1) atom. The H(15)-O(1) bond length is 1.52 Å. In the twelfth H site, H(16) is bonded in a linear geometry to one N(2) and one O(2) atom. The H(16)-O(2) bond length is 1.52 Å. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one N(3) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one N(4) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(21) and one H(15) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(22) and one H(16) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Tb(1) and one C(21) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Tb(1) and one C(22) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Tb(1) and one C(29) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Tb(1) and one C(30) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Tb(1) and one C(29) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Tb(1) and one C(30) atom. Linkers: 4 [O]C(=O)c1cc([C]2Nc3ccccc3N2)cc(C([O])=O)c1. Metal clusters: 2 [Tb]. The MOF has largest included sphere 1.79 A, density 1.99 g/cm3, surface area 3381.84 m2/g, accessible volume 0.06 cm3/g