ZnC11H9(NO)4CH(CH2)2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, eight 02329_fluka molecules, and four ZnC11H9(NO)4 clusters. In each ZnC11H9(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(4), one O(1), and one O(4) atom. The Zn(1)-N(1) bond length is 2.02 Å. The Zn(1)-N(4) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 2.01 Å. The Zn(1)-O(4) bond length is 1.99 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(4), and one H(3) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(4) bond length is 1.36 Å. The C(1)-H(3) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(2)-H(4) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one N(3) atom. The C(3)-N(3) bond length is 1.36 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(6) atom. The C(5)-N(4) bond length is 1.35 Å. The C(5)-H(6) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one H(7) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-N(1) bond length is 1.35 Å. The C(6)-H(7) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(8) atom. The C(7)-H(8) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one N(2) atom. The C(8)-N(2) bond length is 1.36 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(9) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-H(9) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(10) atom. The C(10)-N(1) bond length is 1.35 Å. The C(10)-H(10) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(11)-O(1) bond length is 1.29 Å. The C(11)-O(2) bond length is 1.26 Å. In the eleventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(14)-O(3) bond length is 1.24 Å. The C(14)-O(4) bond length is 1.32 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(6) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one C(8), one N(3), and one H(1) atom. The N(2)-N(3) bond length is 1.39 Å. The N(2)-H(1) bond length is 1.04 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one C(3), one N(2), and one H(2) atom. The N(3)-H(2) bond length is 1.04 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a distorted linear geometry to one N(3) and one O(2) atom. The H(2)-O(2) bond length is 1.66 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(11) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one C(11) and one H(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(14) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Zn(1) and one C(14) atom. Linkers: 1 c1cc(NNc2ccncc2)ccn1 ,2 [O]C(=O)CCC([O])=O. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.39 A, density 1.57 g/cm3, surface area 4541.10 m2/g, accessible volume 0.20 cm3/g