Nd2C24H24S3(NO8)2 crystallizes in the triclinic P-1 space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(11), one O(16), one O(4), one O(5), one O(6), and one O(7) atom. The Nd(1)-O(1) bond length is 2.52 Å. The Nd(1)-O(10) bond length is 2.66 Å. The Nd(1)-O(11) bond length is 2.44 Å. The Nd(1)-O(16) bond length is 2.38 Å. The Nd(1)-O(4) bond length is 2.52 Å. The Nd(1)-O(5) bond length is 2.38 Å. The Nd(1)-O(6) bond length is 2.47 Å. The Nd(1)-O(7) bond length is 2.42 Å. In the second Nd site, Nd(2) is bonded in a 8-coordinate geometry to one O(12), one O(13), one O(14), one O(15), one O(2), one O(3), one O(8), and one O(9) atom. The Nd(2)-O(12) bond length is 2.41 Å. The Nd(2)-O(13) bond length is 2.46 Å. The Nd(2)-O(14) bond length is 2.38 Å. The Nd(2)-O(15) bond length is 2.58 Å. The Nd(2)-O(2) bond length is 2.45 Å. The Nd(2)-O(3) bond length is 2.44 Å. The Nd(2)-O(8) bond length is 2.63 Å. The Nd(2)-O(9) bond length is 2.42 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded to one N(2), one H(1), one H(2), and one H(3) atom to form corner-sharing CH3N tetrahedra. The C(1)-N(2) bond length is 1.45 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.09 Å. The C(1)-H(3) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(6), and one O(7) atom. The C(2)-C(12) bond length is 1.47 Å. The C(2)-O(6) bond length is 1.28 Å. The C(2)-O(7) bond length is 1.27 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(13), and one O(9) atom. The C(3)-C(6) bond length is 1.49 Å. The C(3)-O(13) bond length is 1.27 Å. The C(3)-O(9) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(6) atom. The C(4)-C(10) bond length is 1.41 Å. The C(4)-C(12) bond length is 1.39 Å. The C(4)-H(6) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(19), one C(20), and one S(2) atom. The C(5)-C(19) bond length is 1.39 Å. The C(5)-C(20) bond length is 1.48 Å. The C(5)-S(2) bond length is 1.72 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(22), one C(3), and one S(3) atom. The C(6)-C(22) bond length is 1.39 Å. The C(6)-S(3) bond length is 1.72 Å. In the seventh C site, C(7) is bonded in a bent 120 degrees geometry to one C(14), one O(1), and one O(16) atom. The C(7)-C(14) bond length is 1.47 Å. The C(7)-O(1) bond length is 1.28 Å. The C(7)-O(16) bond length is 1.27 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(14), and one O(2) atom. The C(8)-C(16) bond length is 1.48 Å. The C(8)-O(14) bond length is 1.27 Å. The C(8)-O(2) bond length is 1.27 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one N(1), one H(23), and one O(8) atom. The C(9)-N(1) bond length is 1.33 Å. The C(9)-H(23) bond length is 1.10 Å. The C(9)-O(8) bond length is 1.26 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(4), and one H(7) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(7) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(13), and one S(1) atom. The C(11)-C(13) bond length is 1.48 Å. The C(11)-S(1) bond length is 1.71 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(2), one C(4), and one S(1) atom. The C(12)-S(1) bond length is 1.72 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(11), and one O(5) atom. The C(13)-O(11) bond length is 1.27 Å. The C(13)-O(5) bond length is 1.27 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(15), one C(7), and one S(2) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-S(2) bond length is 1.72 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(8) atom. The C(15)-H(8) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(23), one C(8), and one S(3) atom. The C(16)-C(23) bond length is 1.39 Å. The C(16)-S(3) bond length is 1.73 Å. In the seventeenth C site, C(17) is bonded to one N(2), one H(10), one H(11), and one H(9) atom to form corner-sharing CH3N tetrahedra. The C(17)-N(2) bond length is 1.45 Å. The C(17)-H(10) bond length is 1.10 Å. The C(17)-H(11) bond length is 1.10 Å. The C(17)-H(9) bond length is 1.10 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one N(2), one H(24), and one O(4) atom. The C(18)-N(2) bond length is 1.34 Å. The C(18)-H(24) bond length is 1.10 Å. The C(18)-O(4) bond length is 1.25 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(5) and one H(12) atom. The C(19)-H(12) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(12), and one O(3) atom. The C(20)-O(12) bond length is 1.27 Å. The C(20)-O(3) bond length is 1.27 Å. In the twenty-first C site, C(21) is bonded to one N(1), one H(13), one H(14), and one H(15) atom to form corner-sharing CH3N tetrahedra. The C(21)-N(1) bond length is 1.46 Å. The C(21)-H(13) bond length is 1.10 Å. The C(21)-H(14) bond length is 1.10 Å. The C(21)-H(15) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(6) and one H(18) atom. The C(22)-H(18) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(16) and one H(19) atom. The C(23)-H(19) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded to one N(1), one H(20), one H(21), and one H(22) atom to form corner-sharing CH3N tetrahedra. The C(24)-N(1) bond length is 1.46 Å. The C(24)-H(20) bond length is 1.10 Å. The C(24)-H(21) bond length is 1.10 Å. The C(24)-H(22) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(21), one C(24), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(17), and one C(18) atom. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(10) atom. The H(4)-O(10) bond length is 0.98 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(10) atom. The H(5)-O(10) bond length is 0.99 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one O(15) atom. The H(16)-O(15) bond length is 0.99 Å. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one O(15) atom. The H(17)-O(15) bond length is 0.97 Å. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(24) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(24) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(9) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(18) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(11) and one C(12) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one C(14) and one C(5) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one C(16) and one C(6) atom. There are sixteen inequivalent O sites. In the first O site, O(10) is bonded in a water-like geometry to one Nd(1), one H(4), and one H(5) atom. In the second O site, O(11) is bonded in a 2-coordinate geometry to one Nd(1) and one C(13) atom. In the third O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Nd(2) and one C(20) atom. In the fourth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Nd(2) and one C(3) atom. In the fifth O site, O(14) is bonded in a linear geometry to one Nd(2) and one C(8) atom. In the sixth O site, O(15) is bonded in a water-like geometry to one Nd(2), one H(16), and one H(17) atom. In the seventh O site, O(16) is bonded in a distorted linear geometry to one Nd(1) and one C(7) atom. In the eighth O site, O(1) is bonded in a distorted water-like geometry to one Nd(1) and one C(7) atom. In the ninth O site, O(2) is bonded in a distorted single-bond geometry to one Nd(2) and one C(8) atom. In the tenth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Nd(2) and one C(20) atom. In the eleventh O site, O(4) is bonded in a distorted single-bond geometry to one Nd(1) and one C(18) atom. In the twelfth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one C(13) atom. In the thirteenth O site, O(6) is bonded in a distorted single-bond geometry to one Nd(1) and one C(2) atom. In the fourteenth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one C(2) atom. In the fifteenth O site, O(8) is bonded in a single-bond geometry to one Nd(2) and one C(9) atom. In the sixteenth O site, O(9) is bonded in a distorted single-bond geometry to one Nd(2) and one C(3) atom. Linkers: 6 [O]C(=O)c1ccc(C([O])=O)s1. Metal clusters: 4 [Nd]. The MOF has largest included sphere 3.86 A, density 1.84 g/cm3, surface area 3458.79 m2/g, accessible volume 0.20 cm3/g