(CH3)2CdC10N4H8S2O crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a CdC10N4H8S2O framework. In the CdC10N4H8S2O framework, Cd(1) is bonded in a distorted octahedral geometry to one N(1), one N(2), one N(3), one S(1), one S(2), and one O(1) atom. The Cd(1)-N(1) bond length is 2.29 Å. The Cd(1)-N(2) bond length is 2.29 Å. The Cd(1)-N(3) bond length is 2.36 Å. The Cd(1)-S(1) bond length is 2.76 Å. The Cd(1)-S(2) bond length is 2.65 Å. The Cd(1)-O(1) bond length is 2.45 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.63 Å. In the second C site, C(3) is bonded in a 3-coordinate geometry to one N(4), one H(2), and one H(3) atom. The C(3)-N(4) bond length is 1.47 Å. The C(3)-H(2) bond length is 1.10 Å. The C(3)-H(3) bond length is 1.10 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one N(2) and one S(2) atom. The C(5)-N(2) bond length is 1.18 Å. The C(5)-S(2) bond length is 1.63 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(3), and one H(1) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-N(3) bond length is 1.34 Å. The C(6)-H(1) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.50 Å. The C(7)-C(8) bond length is 1.40 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(8)-H(7) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(8) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(3), and one H(9) atom. The C(10)-N(3) bond length is 1.34 Å. The C(10)-H(9) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(4), and one O(1) atom. The C(11)-N(4) bond length is 1.35 Å. The C(11)-O(1) bond length is 1.26 Å. In the tenth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(10), and one H(11) atom. The C(12)-N(4) bond length is 1.47 Å. The C(12)-H(10) bond length is 1.10 Å. The C(12)-H(11) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(3) atom. In the second N site, N(1) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(1) atom. In the third N site, N(2) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(5) atom. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(6) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Cd(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Cd(1) and one C(5) atom. O(1) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(11) atom. Linkers: 4 CCN(CC)C(=O)c1cccnc1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 2.34 A, density 1.69 g/cm3, surface area 4492.74 m2/g, accessible volume 0.14 cm3/g