CoC17H13(NO)4(CH2)6(CH)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, twelve 02329_fluka molecules, and two CoC17H13(NO)4 clusters. In each CoC17H13(NO)4 cluster, Co(1) is bonded in a tetrahedral geometry to one N(2), one N(4), one O(1), and one O(2) atom. The Co(1)-N(2) bond length is 1.99 Å. The Co(1)-N(4) bond length is 2.00 Å. The Co(1)-O(1) bond length is 1.96 Å. The Co(1)-O(2) bond length is 1.94 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(10), one C(5), and one N(3) atom. The C(1)-C(10) bond length is 1.40 Å. The C(1)-C(5) bond length is 1.42 Å. The C(1)-N(3) bond length is 1.39 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(4), and one H(1) atom. The C(2)-N(1) bond length is 1.36 Å. The C(2)-N(4) bond length is 1.33 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(19), one C(7), and one N(1) atom. The C(3)-C(19) bond length is 1.40 Å. The C(3)-C(7) bond length is 1.42 Å. The C(3)-N(1) bond length is 1.39 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(2) atom. The C(4)-N(2) bond length is 1.33 Å. The C(4)-N(3) bond length is 1.36 Å. The C(4)-H(2) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(1), one C(11), and one N(2) atom. The C(5)-C(11) bond length is 1.40 Å. The C(5)-N(2) bond length is 1.39 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(22), one C(3), and one N(4) atom. The C(7)-C(22) bond length is 1.40 Å. The C(7)-N(4) bond length is 1.40 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(8)-O(1) bond length is 1.31 Å. The C(8)-O(4) bond length is 1.25 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(1), one C(20), and one H(7) atom. The C(10)-C(20) bond length is 1.39 Å. The C(10)-H(7) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(5) and one H(8) atom. The C(11)-H(8) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(12)-O(2) bond length is 1.31 Å. The C(12)-O(3) bond length is 1.25 Å. In the eleventh C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(10), and one H(9) atom. The C(13)-N(1) bond length is 1.46 Å. The C(13)-H(10) bond length is 1.10 Å. The C(13)-H(9) bond length is 1.10 Å. In the twelfth C site, C(19) is bonded in a distorted single-bond geometry to one C(3) and one H(18) atom. The C(19)-H(18) bond length is 1.09 Å. In the thirteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(10), one C(23), and one H(19) atom. The C(20)-C(23) bond length is 1.41 Å. The C(20)-H(19) bond length is 1.09 Å. In the fourteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(25), one C(7), and one H(22) atom. The C(22)-C(25) bond length is 1.39 Å. The C(22)-H(22) bond length is 1.09 Å. In the fifteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(20) and one H(23) atom. The C(23)-H(23) bond length is 1.09 Å. In the sixteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(22) and one H(26) atom. The C(25)-H(26) bond length is 1.09 Å. In the seventeenth C site, C(26) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(27), and one H(28) atom. The C(26)-N(3) bond length is 1.46 Å. The C(26)-H(27) bond length is 1.10 Å. The C(26)-H(28) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(13), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(4), and one C(5) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(26), and one C(4) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(2), and one C(7) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(22) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(23) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(26) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(27) is bonded in a single-bond geometry to one C(26) atom. In the thirteenth H site, H(28) is bonded in a single-bond geometry to one C(26) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Co(1) and one C(8) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one C(12) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(12) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(8) atom. Linkers: 2 [O]C(=O)[C@H]1CC[C@@H](C([O])=O)CC1. Metal clusters: 2 O=[C]O[Co]O[C]=O. The MOF has largest included sphere 2.59 A, density 1.46 g/cm3, surface area 4972.13 m2/g, accessible volume 0.25 cm3/g