Zn2C7H11(NS)2CH crystallizes in the orthorhombic Cmc2_1 space group. The structure consists of four 02329_fluka molecules inside a Zn2C7H11(NS)2 framework. In the Zn2C7H11(NS)2 framework, Zn(1) is bonded to one N(1) and three equivalent S(1) atoms to form corner-sharing ZnS3N tetrahedra. The Zn(1)-N(1) bond length is 2.12 Å. There are a spread of Zn(1)-S(1) bond distances ranging from 2.31-2.35 Å. There are four inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(6) atom. The C(4)-C(2) bond length is 1.40 Å. The C(4)-H(6) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(1) bond length is 1.40 Å. The C(2)-C(3) bond length is 1.51 Å. In the third C site, C(1) is bonded in a distorted single-bond geometry to two equivalent C(2) and one H(1) atom. The C(1)-H(1) bond length is 1.09 Å. In the fourth C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one N(1), one H(4), and one H(5) atom. The C(3)-N(1) bond length is 1.47 Å. The C(3)-H(4) bond length is 1.10 Å. The C(3)-H(5) bond length is 1.10 Å. N(1) is bonded in a distorted tetrahedral geometry to one Zn(1), one C(3), one H(2), and one H(3) atom. The N(1)-H(2) bond length is 1.03 Å. The N(1)-H(3) bond length is 1.03 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. S(1) is bonded in a trigonal non-coplanar geometry to three equivalent Zn(1) atoms. Linkers: 2 NCc1cccc(CN)c1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 1.55 A, density 2.24 g/cm3, surface area 3302.52 m2/g, accessible volume 0.04 cm3/g