CuC14N6H9S crystallizes in the orthorhombic Ama2 space group. Cu(1) is bonded in a tetrahedral geometry to one N(1), two equivalent N(2), and one S(1) atom. The Cu(1)-N(1) bond length is 1.92 Å. Both Cu(1)-N(2) bond lengths are 2.02 Å. The Cu(1)-S(1) bond length is 2.29 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.19 Å. The C(1)-S(1) bond length is 1.63 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(7) bond length is 1.47 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(2), and one H(4) atom. The C(6)-N(2) bond length is 1.35 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(4), one N(3), and one N(4) atom. The C(7)-N(3) bond length is 1.35 Å. The C(7)-N(4) bond length is 1.35 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to two equivalent N(4) and one H(5) atom. Both C(8)-N(4) bond lengths are 1.33 Å. The C(8)-H(5) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Cu(1) and one C(1) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(2), and one C(6) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to two equivalent C(7) atoms. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(7) and one C(8) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. S(1) is bonded in a water-like geometry to one Cu(1) and one C(1) atom. Linkers: 1 n1ccc(cc1)C1=NC(=[N]=C[N]1)c1ccncc1 ,1 n1ccc(cc1)C1=[N]=C(N=C[N]1)c1ccncc1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 1.53 A, density 1.79 g/cm3, surface area 4287.39 m2/g, accessible volume 0.12 cm3/g