Cd2C30H34(N2O3)3(CH)4(CH2)2 crystallizes in the triclinic P-1 space group. The structure consists of eight 02329_fluka molecules and four 02329_fluka molecules inside a Cd2C30H34(N2O3)3 framework. In the Cd2C30H34(N2O3)3 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted pentagonal bipyramidal geometry to one N(1), one N(4), one O(1), one O(2), one O(4), one O(7), and one O(8) atom. The Cd(1)-N(1) bond length is 2.39 Å. The Cd(1)-N(4) bond length is 2.36 Å. The Cd(1)-O(1) bond length is 2.51 Å. The Cd(1)-O(2) bond length is 2.35 Å. The Cd(1)-O(4) bond length is 2.38 Å. The Cd(1)-O(7) bond length is 2.61 Å. The Cd(1)-O(8) bond length is 2.30 Å. In the second Cd site, Cd(2) is bonded in a 6-coordinate geometry to one N(5), one O(3), one O(4), one O(5), one O(6), and one O(9) atom. The Cd(2)-N(5) bond length is 2.30 Å. The Cd(2)-O(3) bond length is 2.35 Å. The Cd(2)-O(4) bond length is 2.46 Å. The Cd(2)-O(5) bond length is 2.23 Å. The Cd(2)-O(6) bond length is 2.59 Å. The Cd(2)-O(9) bond length is 2.35 Å. There are thirty inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(3) bond length is 1.40 Å. The C(1)-C(4) bond length is 1.51 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(3) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(1), one C(2), and one H(4) atom. The C(3)-H(4) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one N(3), one H(5), and one H(6) atom. The C(4)-N(3) bond length is 1.47 Å. The C(4)-H(5) bond length is 1.10 Å. The C(4)-H(6) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(7) atom. The C(5)-N(1) bond length is 1.32 Å. The C(5)-N(3) bond length is 1.36 Å. The C(5)-H(7) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(8) atom. The C(6)-N(2) bond length is 1.32 Å. The C(6)-N(3) bond length is 1.37 Å. The C(6)-H(8) bond length is 1.08 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(10), one C(8), and one C(9) atom. The C(7)-C(10) bond length is 1.51 Å. The C(7)-C(8) bond length is 1.40 Å. The C(7)-C(9) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(9) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(9) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(7), one C(8), and one H(10) atom. The C(9)-H(10) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(7), one N(6), one H(11), and one H(12) atom. The C(10)-N(6) bond length is 1.46 Å. The C(10)-H(11) bond length is 1.10 Å. The C(10)-H(12) bond length is 1.10 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(13) atom. The C(11)-N(4) bond length is 1.32 Å. The C(11)-N(6) bond length is 1.36 Å. The C(11)-H(13) bond length is 1.08 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(14) atom. The C(12)-N(5) bond length is 1.32 Å. The C(12)-N(6) bond length is 1.36 Å. The C(12)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded to one C(14), one C(15), one C(16), and one C(23) atom to form corner-sharing CC4 tetrahedra. The C(13)-C(14) bond length is 1.54 Å. The C(13)-C(15) bond length is 1.55 Å. The C(13)-C(16) bond length is 1.54 Å. The C(13)-C(23) bond length is 1.53 Å. In the fourteenth C site, C(14) is bonded in a distorted water-like geometry to one C(13), one C(17), one H(15), and one H(16) atom. The C(14)-C(17) bond length is 1.55 Å. The C(14)-H(15) bond length is 1.10 Å. The C(14)-H(16) bond length is 1.10 Å. In the fifteenth C site, C(15) is bonded in a distorted water-like geometry to one C(13), one H(17), and one H(18) atom. The C(15)-H(17) bond length is 1.10 Å. The C(15)-H(18) bond length is 1.10 Å. In the sixteenth C site, C(16) is bonded in a distorted water-like geometry to one C(13) and two equivalent H(19,20) atoms. Both C(16)-H(19,20) bond lengths are 1.10 Å. In the seventeenth C site, C(17) is bonded to one C(14), one C(20), one C(21), and one C(24) atom to form corner-sharing CC4 tetrahedra. The C(17)-C(20) bond length is 1.54 Å. The C(17)-C(21) bond length is 1.54 Å. The C(17)-C(24) bond length is 1.52 Å. In the eighteenth C site, C(20) is bonded in a distorted water-like geometry to one C(17), one H(23), and one H(24) atom. The C(20)-H(23) bond length is 1.10 Å. The C(20)-H(24) bond length is 1.10 Å. In the nineteenth C site, C(21) is bonded in a distorted water-like geometry to one C(17), one H(25), and one H(26) atom. The C(21)-H(25) bond length is 1.10 Å. The C(21)-H(26) bond length is 1.10 Å. In the twentieth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(1), and one O(2) atom. The C(23)-O(1) bond length is 1.28 Å. The C(23)-O(2) bond length is 1.27 Å. In the twenty-first C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(3), and one O(4) atom. The C(24)-O(3) bond length is 1.28 Å. The C(24)-O(4) bond length is 1.29 Å. In the twenty-second C site, C(25) is bonded to one C(26), one C(27), one C(28), and one C(35) atom to form corner-sharing CC4 tetrahedra. The C(25)-C(26) bond length is 1.54 Å. The C(25)-C(27) bond length is 1.55 Å. The C(25)-C(28) bond length is 1.54 Å. The C(25)-C(35) bond length is 1.53 Å. In the twenty-third C site, C(26) is bonded in a distorted water-like geometry to one C(25), one C(29), one H(29), and one H(30) atom. The C(26)-C(29) bond length is 1.54 Å. The C(26)-H(29) bond length is 1.10 Å. The C(26)-H(30) bond length is 1.10 Å. In the twenty-fourth C site, C(27) is bonded in a distorted water-like geometry to one C(25), one H(31), and one H(32) atom. The C(27)-H(31) bond length is 1.10 Å. The C(27)-H(32) bond length is 1.10 Å. In the twenty-fifth C site, C(28) is bonded in a distorted water-like geometry to one C(25), one H(33), and one H(34) atom. The C(28)-H(33) bond length is 1.10 Å. The C(28)-H(34) bond length is 1.10 Å. In the twenty-sixth C site, C(29) is bonded to one C(26), one C(32), one C(33), and one C(36) atom to form corner-sharing CC4 tetrahedra. The C(29)-C(32) bond length is 1.55 Å. The C(29)-C(33) bond length is 1.54 Å. The C(29)-C(36) bond length is 1.53 Å. In the twenty-seventh C site, C(32) is bonded in a distorted water-like geometry to one C(29), one H(37), and one H(38) atom. The C(32)-H(37) bond length is 1.10 Å. The C(32)-H(38) bond length is 1.10 Å. In the twenty-eighth C site, C(33) is bonded in a distorted water-like geometry to one C(29), one H(39), and one H(40) atom. The C(33)-H(39) bond length is 1.10 Å. The C(33)-H(40) bond length is 1.10 Å. In the twenty-ninth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(5), and one O(6) atom. The C(35)-O(5) bond length is 1.29 Å. The C(35)-O(6) bond length is 1.27 Å. In the thirtieth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(7), and one O(8) atom. The C(36)-O(7) bond length is 1.27 Å. The C(36)-O(8) bond length is 1.28 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Cd(1), one C(5), and one N(2) atom. The N(1)-N(2) bond length is 1.38 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(6) and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(6) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(12), and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(12) atom. There are thirty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(9) atom. The H(1)-O(9) bond length is 0.97 Å. In the second H site, H(2) is bonded in a linear geometry to one O(1) and one O(9) atom. The H(2)-O(1) bond length is 1.56 Å. The H(2)-O(9) bond length is 1.02 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(15) atom. In the nineteenth H site, H(19,20) is bonded in a single-bond geometry to one C(16) atom. In the twentieth H site, H(23) is bonded in a single-bond geometry to one C(20) atom. In the twenty-first H site, H(24) is bonded in a single-bond geometry to one C(20) atom. In the twenty-second H site, H(25) is bonded in a single-bond geometry to one C(21) atom. In the twenty-third H site, H(26) is bonded in a single-bond geometry to one C(21) atom. In the twenty-fourth H site, H(29) is bonded in a single-bond geometry to one C(26) atom. In the twenty-fifth H site, H(30) is bonded in a single-bond geometry to one C(26) atom. In the twenty-sixth H site, H(31) is bonded in a single-bond geometry to one C(27) atom. In the twenty-seventh H site, H(32) is bonded in a single-bond geometry to one C(27) atom. In the twenty-eighth H site, H(33) is bonded in a single-bond geometry to one C(28) atom. In the twenty-ninth H site, H(34) is bonded in a single-bond geometry to one C(28) atom. In the thirtieth H site, H(37) is bonded in a single-bond geometry to one C(32) atom. In the thirty-first H site, H(38) is bonded in a single-bond geometry to one C(32) atom. In the thirty-second H site, H(39) is bonded in a single-bond geometry to one C(33) atom. In the thirty-third H site, H(40) is bonded in a single-bond geometry to one C(33) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cd(1), one C(23), and one H(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(23) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(24) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(24) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Cd(2) and one C(35) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Cd(2) and one C(35) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Cd(1) and one C(36) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Cd(1) and one C(36) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Cd(2), one H(1), and one H(2) atom. Linkers: 2 c1cc(Cn2cnnc2)ccc1Cn1cnnc1 ,4 [O]C(=O)[C@]12C[C@H]3C[C@H](C[C@](C([O])=O)(C3)C1)C2. Metal clusters: 2 O.O=[C]O[Cd]1N=N[Cd]2(O[C]=O)(O[C]O1)O[C]O2. The MOF has largest included sphere 4.57 A, density 1.56 g/cm3, surface area 4157.70 m2/g, accessible volume 0.19 cm3/g