CdC20H18(N3O2)2(CH3)2 crystallizes in the triclinic P-1 space group. The structure consists of eight 02329_fluka molecules inside a CdC20H18(N3O2)2 framework. In each CdC20H18(N3O2)2 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted trigonal bipyramidal geometry to one N(12), one N(3), one N(7), one O(1), and one O(5) atom. The Cd(1)-N(12) bond length is 2.45 Å. The Cd(1)-N(3) bond length is 2.29 Å. The Cd(1)-N(7) bond length is 2.41 Å. The Cd(1)-O(1) bond length is 2.22 Å. The Cd(1)-O(5) bond length is 2.29 Å. In the second Cd site, Cd(2) is bonded in a distorted trigonal bipyramidal geometry to one N(11), one N(4), one N(8), one O(2), and one O(6) atom. The Cd(2)-N(11) bond length is 2.46 Å. The Cd(2)-N(4) bond length is 2.28 Å. The Cd(2)-N(8) bond length is 2.41 Å. The Cd(2)-O(2) bond length is 2.22 Å. The Cd(2)-O(6) bond length is 2.29 Å. There are thirty-six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(11); one C(13); and one C(3,4) atom. The C(1)-C(11) bond length is 1.40 Å. The C(1)-C(13) bond length is 1.51 Å. The C(1)-C(3,4) bond length is 1.39 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(12); one C(14); and one C(3,4) atom. The C(2)-C(12) bond length is 1.40 Å. The C(2)-C(14) bond length is 1.51 Å. The C(2)-C(3,4) bond length is 1.39 Å. In the third C site, C(3,4) is bonded in a distorted single-bond geometry to one C(1); one C(5,6); and one H(1,2) atom. The C(3,4)-C(5,6) bond length is 1.40 Å. The C(3,4)-H(1,2) bond length is 1.09 Å. In the fourth C site, C(5,6) is bonded in a trigonal planar geometry to one C(21,22); one C(3,4); and one C(7) atom. The C(5,6)-C(21,22) bond length is 1.51 Å. The C(5,6)-C(7) bond length is 1.40 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(5,6); one C(9,10); and one H(3,4) atom. The C(7)-C(9,10) bond length is 1.40 Å. The C(7)-H(3,4) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(5,6); one C(9,10); and one H(3,4) atom. The C(8)-C(5,6) bond length is 1.40 Å. The C(8)-C(9,10) bond length is 1.40 Å. The C(8)-H(3,4) bond length is 1.09 Å. In the seventh C site, C(9,10) is bonded in a trigonal planar geometry to one C(11), one C(29), and one C(7) atom. The C(9,10)-C(11) bond length is 1.39 Å. The C(9,10)-C(29) bond length is 1.51 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(1); one C(9,10); and one H(5) atom. The C(11)-H(5) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(2); one C(9,10); and one H(6) atom. The C(12)-C(9,10) bond length is 1.39 Å. The C(12)-H(6) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one C(1); one N(1); one H(7,8); and one H(9,10) atom. The C(13)-N(1) bond length is 1.45 Å. The C(13)-H(7,8) bond length is 1.10 Å. The C(13)-H(9,10) bond length is 1.10 Å. In the eleventh C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one C(2); one N(2); one H(7,8); and one H(9,10) atom. The C(14)-N(2) bond length is 1.45 Å. The C(14)-H(7,8) bond length is 1.10 Å. The C(14)-H(9,10) bond length is 1.10 Å. In the twelfth C site, C(15) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(11) atom. The C(15)-N(1) bond length is 1.36 Å. The C(15)-N(3) bond length is 1.33 Å. The C(15)-H(11) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a trigonal planar geometry to one N(2), one N(4), and one H(12) atom. The C(16)-N(2) bond length is 1.36 Å. The C(16)-N(4) bond length is 1.33 Å. The C(16)-H(12) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(3), and one H(13) atom. The C(17)-C(19) bond length is 1.37 Å. The C(17)-N(3) bond length is 1.38 Å. The C(17)-H(13) bond length is 1.08 Å. In the fifteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(4), and one H(14) atom. The C(18)-C(20) bond length is 1.37 Å. The C(18)-N(4) bond length is 1.38 Å. The C(18)-H(14) bond length is 1.08 Å. In the sixteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(17); one N(1); and one H(15,16) atom. The C(19)-N(1) bond length is 1.38 Å. The C(19)-H(15,16) bond length is 1.08 Å. In the seventeenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(18); one N(2); and one H(15,16) atom. The C(20)-N(2) bond length is 1.38 Å. The C(20)-H(15,16) bond length is 1.08 Å. In the eighteenth C site, C(21,22) is bonded in a distorted trigonal non-coplanar geometry to one C(5,6); one N(5); one H(17,18); and one H(19,20) atom. The C(21,22)-N(5) bond length is 1.47 Å. The C(21,22)-H(17,18) bond length is 1.10 Å. The C(21,22)-H(19,20) bond length is 1.10 Å. In the nineteenth C site, C(23) is bonded in a trigonal planar geometry to one N(5), one N(7), and one H(21) atom. The C(23)-N(5) bond length is 1.36 Å. The C(23)-N(7) bond length is 1.33 Å. The C(23)-H(21) bond length is 1.08 Å. In the twentieth C site, C(24) is bonded in a trigonal planar geometry to one N(6), one N(8), and one H(22) atom. The C(24)-N(6) bond length is 1.36 Å. The C(24)-N(8) bond length is 1.33 Å. The C(24)-H(22) bond length is 1.08 Å. In the twenty-first C site, C(25) is bonded in a distorted trigonal planar geometry to one C(27), one N(7), and one H(23) atom. The C(25)-C(27) bond length is 1.38 Å. The C(25)-N(7) bond length is 1.38 Å. The C(25)-H(23) bond length is 1.08 Å. In the twenty-second C site, C(26) is bonded in a distorted trigonal planar geometry to one C(28), one N(8), and one H(24) atom. The C(26)-C(28) bond length is 1.38 Å. The C(26)-N(8) bond length is 1.38 Å. The C(26)-H(24) bond length is 1.08 Å. In the twenty-third C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(25); one N(5); and one H(25,26) atom. The C(27)-N(5) bond length is 1.38 Å. The C(27)-H(25,26) bond length is 1.08 Å. In the twenty-fourth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(26); one N(6); and one H(25,26) atom. The C(28)-N(6) bond length is 1.38 Å. The C(28)-H(25,26) bond length is 1.08 Å. In the twenty-fifth C site, C(29) is bonded in a distorted trigonal non-coplanar geometry to one C(9,10); one N(9); one H(27,28); and one H(29,30) atom. The C(29)-N(9) bond length is 1.46 Å. The C(29)-H(27,28) bond length is 1.10 Å. The C(29)-H(29,30) bond length is 1.10 Å. In the twenty-sixth C site, C(30) is bonded in a distorted trigonal non-coplanar geometry to one C(9,10); one N(10); one H(27,28); and one H(29,30) atom. The C(30)-C(9,10) bond length is 1.51 Å. The C(30)-N(10) bond length is 1.46 Å. The C(30)-H(27,28) bond length is 1.10 Å. The C(30)-H(29,30) bond length is 1.10 Å. In the twenty-seventh C site, C(31) is bonded in a trigonal planar geometry to one N(11), one N(9), and one H(31) atom. The C(31)-N(11) bond length is 1.33 Å. The C(31)-N(9) bond length is 1.36 Å. The C(31)-H(31) bond length is 1.09 Å. In the twenty-eighth C site, C(32) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(32) atom. The C(32)-N(10) bond length is 1.36 Å. The C(32)-N(12) bond length is 1.33 Å. The C(32)-H(32) bond length is 1.09 Å. In the twenty-ninth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(35), one N(11), and one H(33) atom. The C(33)-C(35) bond length is 1.38 Å. The C(33)-N(11) bond length is 1.38 Å. The C(33)-H(33) bond length is 1.09 Å. In the thirtieth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(36), one N(12), and one H(34) atom. The C(34)-C(36) bond length is 1.38 Å. The C(34)-N(12) bond length is 1.38 Å. The C(34)-H(34) bond length is 1.09 Å. In the thirty-first C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(33), one N(9), and one H(35) atom. The C(35)-N(9) bond length is 1.38 Å. The C(35)-H(35) bond length is 1.09 Å. In the thirty-second C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(34), one N(10), and one H(36) atom. The C(36)-N(10) bond length is 1.38 Å. The C(36)-H(36) bond length is 1.09 Å. In the thirty-third C site, C(37) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(37)-O(1) bond length is 1.29 Å. The C(37)-O(3) bond length is 1.27 Å. In the thirty-fourth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(38)-O(2) bond length is 1.29 Å. The C(38)-O(4) bond length is 1.27 Å. In the thirty-fifth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(7) atom. The C(41)-O(5) bond length is 1.29 Å. The C(41)-O(7) bond length is 1.27 Å. In the thirty-sixth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(8) atom. The C(42)-O(6) bond length is 1.29 Å. The C(42)-O(8) bond length is 1.27 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(19) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(20) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(15), and one C(17) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(16), and one C(18) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(21,22); one C(23); and one C(27) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(21,22); one C(24); and one C(28) atom. The N(6)-C(21,22) bond length is 1.47 Å. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(23), and one C(25) atom. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(24), and one C(26) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(35) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(36) atom. In the eleventh N site, N(11) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(31), and one C(33) atom. In the twelfth N site, N(12) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(32), and one C(34) atom. There are twenty-six inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(3,4) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(7,8) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(15,16) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(17,18) is bonded in a single-bond geometry to one C(21,22) atom. In the thirteenth H site, H(19,20) is bonded in a single-bond geometry to one C(21,22) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(23) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(24) atom. In the sixteenth H site, H(23) is bonded in a single-bond geometry to one C(25) atom. In the seventeenth H site, H(24) is bonded in a single-bond geometry to one C(26) atom. In the eighteenth H site, H(25,26) is bonded in a single-bond geometry to one C(27) atom. In the nineteenth H site, H(27,28) is bonded in a single-bond geometry to one C(29) atom. In the twentieth H site, H(29,30) is bonded in a single-bond geometry to one C(29) atom. In the twenty-first H site, H(31) is bonded in a single-bond geometry to one C(31) atom. In the twenty-second H site, H(32) is bonded in a single-bond geometry to one C(32) atom. In the twenty-third H site, H(33) is bonded in a single-bond geometry to one C(33) atom. In the twenty-fourth H site, H(34) is bonded in a single-bond geometry to one C(34) atom. In the twenty-fifth H site, H(35) is bonded in a single-bond geometry to one C(35) atom. In the twenty-sixth H site, H(36) is bonded in a single-bond geometry to one C(36) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cd(1) and one C(37) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cd(2) and one C(38) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(37) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(38) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Cd(1) and one C(41) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Cd(2) and one C(42) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(41) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(42) atom. Linkers: 4 c1cn(Cc2cc(Cn3ccnc3)cc(Cn3ccnc3)c2)cn1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 2.62 A, density 1.50 g/cm3, surface area 5022.42 m2/g, accessible volume 0.24 cm3/g