AgC6H6(NO)3(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one AgC6H6(NO)3 cluster. In the AgC6H6(NO)3 cluster, Ag(1) is bonded in a distorted trigonal pyramidal geometry to one N(2), one N(3), one O(1), and one O(2) atom. The Ag(1)-N(2) bond length is 2.34 Å. The Ag(1)-N(3) bond length is 2.20 Å. The Ag(1)-O(1) bond length is 2.46 Å. The Ag(1)-O(2) bond length is 2.42 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one N(3) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-N(3) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(6) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(6) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one N(1) atom. The C(6)-N(1) bond length is 1.37 Å. In the fifth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(7), and one H(8) atom. The C(7)-N(1) bond length is 1.45 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.10 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(8)-O(1) bond length is 1.26 Å. The C(8)-O(3) bond length is 1.28 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one N(2) atom. The N(1)-N(2) bond length is 1.35 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one N(1), and one N(3) atom. The N(2)-N(3) bond length is 1.32 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one N(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(2) and one O(3) atom. The H(1)-O(2) bond length is 1.01 Å. The H(1)-O(3) bond length is 1.62 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one C(8) atom. In the second O site, O(2) is bonded in a water-like geometry to one Ag(1), one H(1), and one H(2) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one C(8) and one H(1) atom. Linkers: 2 [O]C(=O)Cn1nnc2ccccc21. Metal clusters: 1 O.O.O=[C]O[Ag]1[N][N][Ag](O[C]=O)[N][N]1. The MOF has largest included sphere 1.87 A, density 2.21 g/cm3, surface area 3376.49 m2/g, accessible volume 0.09 cm3/g