AgC10N2H10SO3CF3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two trifluoromethane molecules and one AgC10N2H10SO3 cluster. In the AgC10N2H10SO3 cluster, Ag(1) is bonded to one N(1), one N(2), and two equivalent O(1) atoms to form distorted edge-sharing AgN2O2 trigonal pyramids. The Ag(1)-N(1) bond length is 2.27 Å. The Ag(1)-N(2) bond length is 2.15 Å. There is one shorter (2.63 Å) and one longer (2.64 Å) Ag(1)-O(1) bond length. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(4) and one H(1) atom. The C(1)-C(4) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(2), and one H(3) atom. The C(2)-N(1) bond length is 1.49 Å. The C(2)-H(2) bond length is 1.09 Å. The C(2)-H(3) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one N(1), one H(4), and one H(5) atom. The C(3)-C(4) bond length is 1.50 Å. The C(3)-N(1) bond length is 1.50 Å. The C(3)-H(4) bond length is 1.10 Å. The C(3)-H(5) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(3) atom. The C(4)-C(11) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(6), and one H(7) atom. The C(5)-N(1) bond length is 1.49 Å. The C(5)-H(6) bond length is 1.10 Å. The C(5)-H(7) bond length is 1.11 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(8) atom. The C(6)-C(10) bond length is 1.41 Å. The C(6)-C(7) bond length is 1.42 Å. The C(6)-C(8) bond length is 1.41 Å. In the seventh C site, C(7) is bonded in a distorted linear geometry to one C(6) and one N(2) atom. The C(7)-N(2) bond length is 1.17 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one H(8) atom. The C(8)-H(8) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(6) and one H(9) atom. The C(10)-H(9) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(4) and one H(10) atom. The C(11)-H(10) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a tetrahedral geometry to one Ag(1), one C(2), one C(3), and one C(5) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Ag(1) and one C(7) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(2) bond length is 1.45 Å. The S(1)-O(3) bond length is 1.45 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. Linkers: 1 N#Cc1ccc(CN2CCN(Cc3ccc(C#N)cc3)CC2)cc1 ,2 N#Cc1ccc(CN2CCN(Cc3cc[c]cc3)CC2)cc1. Metal clusters: 2 [Ag]. The MOF has largest included sphere 1.89 A, density 2.10 g/cm3, surface area 3569.51 m2/g, accessible volume 0.09 cm3/g