CdC32H24(N2O)4(C6H4SO2)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of four di-isopropenylsulfon molecules and two CdC32H24(N2O)4 clusters. In each CdC32H24(N2O)4 cluster, Cd(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent N(2), two equivalent O(3), and two equivalent O(4) atoms. Both Cd(1)-N(1) bond lengths are 2.35 Å. Both Cd(1)-N(2) bond lengths are 2.35 Å. Both Cd(1)-O(3) bond lengths are 2.75 Å. Both Cd(1)-O(4) bond lengths are 2.75 Å. There are twelve inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(1), and one H(1) atom. The C(1,2)-C(5) bond length is 1.37 Å. The C(1,2)-N(1) bond length is 1.38 Å. The C(1,2)-H(1) bond length is 1.08 Å. In the second C site, C(3,4) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(3) atom. The C(3,4)-N(1) bond length is 1.32 Å. The C(3,4)-N(3) bond length is 1.37 Å. The C(3,4)-H(3) bond length is 1.08 Å. In the third C site, C(5) is bonded in a 3-coordinate geometry to one C(1,2); one N(3); and one H(5,6) atom. The C(5)-N(3) bond length is 1.39 Å. The C(5)-H(5,6) bond length is 1.08 Å. In the fourth C site, C(6) is bonded in a 3-coordinate geometry to one C(1,2); one N(4); and one H(5,6) atom. The C(6)-C(1,2) bond length is 1.37 Å. The C(6)-N(4) bond length is 1.39 Å. The C(6)-H(5,6) bond length is 1.08 Å. In the fifth C site, C(7,8) is bonded in a distorted trigonal planar geometry to one C(17), one C(9), and one N(3) atom. The C(7,8)-C(17) bond length is 1.40 Å. The C(7,8)-C(9) bond length is 1.40 Å. The C(7,8)-N(3) bond length is 1.41 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(7,8) and one H(7,8) atom. The C(9)-H(7,8) bond length is 1.09 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(7,8) and one H(7,8) atom. The C(10)-C(7,8) bond length is 1.40 Å. The C(10)-H(7,8) bond length is 1.09 Å. In the eighth C site, C(17) is bonded in a distorted single-bond geometry to one C(7,8) and one H(13,14) atom. The C(17)-H(13,14) bond length is 1.09 Å. In the ninth C site, C(18) is bonded in a distorted single-bond geometry to one C(7,8) and one H(13,14) atom. The C(18)-C(7,8) bond length is 1.40 Å. The C(18)-H(13,14) bond length is 1.09 Å. In the tenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(3), and one O(4) atom. The C(19)-C(20) bond length is 1.50 Å. The C(19)-O(3) bond length is 1.27 Å. The C(19)-O(4) bond length is 1.27 Å. In the eleventh C site, C(20) is bonded in a trigonal planar geometry to one C(19) and two equivalent C(21,22) atoms. Both C(20)-C(21,22) bond lengths are 1.40 Å. In the twelfth C site, C(21,22) is bonded in a distorted single-bond geometry to one C(20) and one H(15,16) atom. The C(21,22)-H(15,16) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1); one C(1,2); and one C(3,4) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1); one C(1,2); and one C(3,4) atom. The N(2)-C(1,2) bond length is 1.38 Å. The N(2)-C(3,4) bond length is 1.32 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(3,4); one C(5); and one C(7,8) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(3,4); one C(6); and one C(7,8) atom. The N(4)-C(3,4) bond length is 1.37 Å. The N(4)-C(7,8) bond length is 1.41 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1,2) atom. The H(2)-C(1,2) bond length is 1.08 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(3,4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3,4) atom. The H(4)-C(3,4) bond length is 1.08 Å. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(13,14) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(15,16) is bonded in a single-bond geometry to one C(21,22) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Cd(1) and one C(19) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Cd(1) and one C(19) atom. Linkers: 2 O=S(=O)(c1ccc(-n2ccnc2)cc1)c1ccc(-n2ccnc2)cc1 ,2 O=S(=O)(c1ccc(-n2c[c]nc2)cc1)c1ccc(-n2ccnc2)cc1 ,1 O=S(=O)(c1ccc(-n2c[c]nc2)cc1)c1ccc(-n2c[c]nc2)cc1 ,1 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 1 [Cd].[O][C]=O.[O][C]=O. The MOF has largest included sphere 2.93 A, density 1.63 g/cm3, surface area 4592.69 m2/g, accessible volume 0.14 cm3/g