CdC20N5H14O8(CH2)3(CH3)6C7H4O is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two (1e)-1-methoxy-2,3-dimethylbuta-1,3-diene molecules; six 02329_fluka molecules; twelve 02329_fluka molecules; and two CdC20N5H14O8 clusters. In each CdC20N5H14O8 cluster, Cd(1) is bonded in a pentagonal bipyramidal geometry to one N(1), one N(3), one N(5), one O(10), one O(11), one O(7), and one O(8) atom. The Cd(1)-N(1) bond length is 2.30 Å. The Cd(1)-N(3) bond length is 2.33 Å. The Cd(1)-N(5) bond length is 2.33 Å. The Cd(1)-O(10) bond length is 2.43 Å. The Cd(1)-O(11) bond length is 2.62 Å. The Cd(1)-O(7) bond length is 2.66 Å. The Cd(1)-O(8) bond length is 2.37 Å. There are twenty inequivalent C sites. In the first C site, C(49) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(57) atom. The C(49)-N(5) bond length is 1.35 Å. The C(49)-H(57) bond length is 1.09 Å. In the second C site, C(53) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(60) atom. The C(53)-N(5) bond length is 1.35 Å. The C(53)-H(60) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the fourth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the fifth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.47 Å. In the sixth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the seventh C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the eighth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(7) atom. The C(6)-C(11) bond length is 1.42 Å. The C(6)-C(7) bond length is 1.40 Å. In the ninth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(6) and one O(2) atom. The C(11)-O(2) bond length is 1.36 Å. In the eleventh C site, C(16) is bonded in a distorted water-like geometry to one H(16) and one O(2) atom. The C(16)-H(16) bond length is 1.10 Å. The C(16)-O(2) bond length is 1.45 Å. In the twelfth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one N(3), and one H(29) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-N(3) bond length is 1.35 Å. The C(25)-H(29) bond length is 1.09 Å. In the thirteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(25), one C(27), and one H(30) atom. The C(26)-C(27) bond length is 1.41 Å. The C(26)-H(30) bond length is 1.09 Å. In the fourteenth C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(30) atom. The C(27)-C(28) bond length is 1.41 Å. The C(27)-C(30) bond length is 1.48 Å. In the fifteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(27), one C(29), and one H(31) atom. The C(28)-C(29) bond length is 1.38 Å. The C(28)-H(31) bond length is 1.09 Å. In the sixteenth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one N(3), and one H(32) atom. The C(29)-N(3) bond length is 1.35 Å. The C(29)-H(32) bond length is 1.09 Å. In the seventeenth C site, C(30) is bonded in a trigonal planar geometry to one C(27), one C(31), and one C(35) atom. The C(30)-C(31) bond length is 1.42 Å. The C(30)-C(35) bond length is 1.40 Å. In the eighteenth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one O(3) atom. The C(31)-O(3) bond length is 1.36 Å. In the nineteenth C site, C(35) is bonded in a distorted single-bond geometry to one C(30) and one H(34) atom. The C(35)-H(34) bond length is 1.08 Å. In the twentieth C site, C(36) is bonded in a distorted water-like geometry to one H(35) and one O(3) atom. The C(36)-H(35) bond length is 1.10 Å. The C(36)-O(3) bond length is 1.46 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(25), and one C(29) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Cd(1), one C(49), and one C(53) atom. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. The N(7)-O(7) bond length is 1.27 Å. The N(7)-O(8) bond length is 1.30 Å. The N(7)-O(9) bond length is 1.24 Å. In the fifth N site, N(8) is bonded in a trigonal planar geometry to one O(10), one O(11), and one O(12) atom. The N(8)-O(10) bond length is 1.29 Å. The N(8)-O(11) bond length is 1.28 Å. The N(8)-O(12) bond length is 1.25 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(29) is bonded in a single-bond geometry to one C(25) atom. In the eighth H site, H(32) is bonded in a single-bond geometry to one C(29) atom. In the ninth H site, H(31) is bonded in a single-bond geometry to one C(28) atom. In the tenth H site, H(34) is bonded in a single-bond geometry to one C(35) atom. In the eleventh H site, H(30) is bonded in a single-bond geometry to one C(26) atom. In the twelfth H site, H(35) is bonded in a single-bond geometry to one C(36) atom. In the thirteenth H site, H(57) is bonded in a single-bond geometry to one C(49) atom. In the fourteenth H site, H(60) is bonded in a single-bond geometry to one C(53) atom. There are eight inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one C(11) and one C(16) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one C(31) and one C(36) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Cd(1) and one N(7) atom. In the fourth O site, O(8) is bonded in a water-like geometry to one Cd(1) and one N(7) atom. In the fifth O site, O(9) is bonded in a single-bond geometry to one N(7) atom. In the sixth O site, O(10) is bonded in a distorted water-like geometry to one Cd(1) and one N(8) atom. In the seventh O site, O(11) is bonded in a distorted single-bond geometry to one Cd(1) and one N(8) atom. In the eighth O site, O(12) is bonded in a single-bond geometry to one N(8) atom. Linkers: 1 C[CH]Oc1cc(C2=C[CH]N([Cd](O[N+](=O)[O-])(O[N+](=O)[O-])(N3[CH]C=C(c4cc(O[C@H](C)CC)c(-c5ccncc5)cc4O[C@H](C)CC)C=C3)N3[CH]C=C(c4cc(O[C@H](C)CC)c(-c5ccncc5)cc4O[C@H](C)CC)C=C3)C=C2)c(O[C@H](C)CC)cc1-c1c[c]ncc1 ,1 [CH2][C@H]([CH]C)Oc1[c]cc(O[C@H](C)CC)c(C2=C[CH]N([Cd](O[N+](=O)[O-])(O[N+](=O)[O-])(N3[CH]C=C(c4cc(O[C@H](C)CC)c(-c5ccncc5)cc4O[C@H](C)CC)C=C3)N3[CH]C=C(c4cc(O[C@H](C)CC)c(-c5ccncc5)cc4O[C@H](C)CC)C=C3)C=C2)c1 ,1 CC[C@@H](C)Oc1cc(-c2ccncc2)c(O[C@H](C)CC)cc1C1=C[CH]N([Cd](O[N+](=O)[O-])(O[N+](=O)[O-])(N2[CH]C=C(c3cc(O[C@H](C)CC)c(-c4ccncc4)cc3O[C@H](C)CC)C=C2)N2[CH]C=C(c3cc(O[C@H](C)CC)c(-c4ccncc4)cc3O[C@H](C)CC)C=C2)C=C1 ,1 CC[C@@H](C)Oc1cc(-c2ccncc2)c([O])cc1C1=C[CH]N([Cd](O[N][O])(O[N+](=O)[O-])(N2[CH]C=C(c3cc(O[C@H](C)CC)c(-c4ccncc4)cc3[O])C=C2)N2[CH]C=C(c3cc(O[C@H](C)CC)c(-c4ccncc4)cc3O[C@H](C)CC)C=C2)C=C1 ,1 [C][C](C=[CH])c1cc(OC([CH2])C)c(C2=C[CH]N([Cd](O[N+](=O)[O-])(O[N+](=O)[O-])(N3[CH]C=C(c4cc(O[C@H](C)CC)c(-c5ccncc5)cc4O[C@H](C)CC)C=C3)N3[CH]C=C(c4cc(O[C@H](C)CC)c(-c5ccncc5)cc4O[C@H](C)CC)C=C3)C=C2)cc1O[C@H](C)CC ,1 [CH]=C(/C=C\[N])c1cc(O[C@H]([CH2])CC)c(C2=C[CH]N([Cd](O[N+](=O)[O-])(O[N+](=O)[O-])(N3[CH]C=C(c4cc(O[C@H]([CH2])[CH]C)[c]cc4O[C@H](C)CC)C=C3)N3[CH]C=C(c4cc(O[C@H](C)CC)c(-c5ccncc5)cc4O[C@H](C)CC)C=C3)C=C2)cc1O[C@H](C)CC ,1 [CH]=C(/C=C\[N])c1cc(O[C@H]([CH2])CC)c(C2=C[CH]N([Cd](O[N+](=O)[O-])(O[N+](=O)[O-])(N3[CH]C=C(c4cc(O[C@H](C)CC)c(-c5ccncc5)cc4O[C@H](C)CC)C=C3)N3[CH]C=C(c4cc(O[C@H](C)CC)c(-c5ccncc5)cc4O[C@H](C)CC)C=C3)C=C2)cc1O[C@H](C)CC ,1 C[CH]Oc1cc(C2=C[CH]N([Cd](O[N+](=O)[O-])(O[N+](=O)[O-])(N3[CH]C=[C]C=C3)N3[CH]C=C(c4cc(O[C@H](C)CC)c(-c5ccncc5)cc4O[C@H](C)CC)C=C3)C=C2)c(O[C@H](C)CC)cc1-c1c[c]ncc1 ,1 CC[C@@H](C)Oc1cc(-c2ccncc2)c(O[C@H](C)CC)cc1C1=C[CH]N([Cd](O[N+](=O)[O-])(O[N+](=O)[O-])(N2[CH]C=[C]C=C2)N2[CH]C=C(c3cc(O[C@H](C)CC)c(-c4ccncc4)cc3O[C@H](C)CC)C=C2)C=C1 ,1 [CH]=C(/C=C\[N])c1cc(O[C@H]([CH2])CC)c(C2=C[CH]N([Cd](O[N+](=O)[O-])(O[N+](=O)[O-])(N3[CH]C=[C]C=C3)N3[CH]C=C(c4cc(O[C@H](C)CC)c(-c5ccncc5)cc4O[C@H](C)CC)C=C3)C=C2)cc1O[C@H](C)CC. Metal clusters: 1 O=[N+]([O-])O[Cd]O[N+](=O)[O-]. The MOF has largest included sphere 4.25 A, density 1.29 g/cm3, surface area 5134.18 m2/g, accessible volume 0.32 cm3/g