ZnSiC19H29O2CH3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one ZnSiC19H29O2 cluster. In the ZnSiC19H29O2 cluster, Zn(1) is bonded to one C(13), one O(2), and two equivalent O(1) atoms to form distorted edge-sharing ZnCO3 trigonal pyramids. The Zn(1)-C(13) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.23 Å. There is one shorter (1.97 Å) and one longer (2.01 Å) Zn(1)-O(1) bond length. Si(1) is bonded in a tetrahedral geometry to one C(11), one C(16), one C(17), and one C(18) atom. The Si(1)-C(11) bond length is 1.86 Å. The Si(1)-C(16) bond length is 1.88 Å. The Si(1)-C(17) bond length is 1.88 Å. The Si(1)-C(18) bond length is 1.88 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one O(1) atom. The C(1)-C(2) bond length is 1.53 Å. The C(1)-C(5) bond length is 1.53 Å. The C(1)-O(1) bond length is 1.44 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.36 Å. The C(2)-C(7) bond length is 1.49 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.49 Å. The C(3)-C(8) bond length is 1.49 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(4)-C(5) bond length is 1.35 Å. The C(4)-C(9) bond length is 1.49 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(4) atom. The C(5)-C(10) bond length is 1.48 Å. In the sixth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one H(4), one H(5), and one H(6) atom. The C(7)-H(4) bond length is 1.10 Å. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. In the seventh C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one H(7), one H(8), and one H(9) atom. The C(8)-H(7) bond length is 1.10 Å. The C(8)-H(8) bond length is 1.10 Å. The C(8)-H(9) bond length is 1.10 Å. In the eighth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one H(10), one H(11), and one H(12) atom. The C(9)-H(10) bond length is 1.10 Å. The C(9)-H(11) bond length is 1.10 Å. The C(9)-H(12) bond length is 1.10 Å. In the ninth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one H(13), one H(14), and one H(15) atom. The C(10)-H(13) bond length is 1.10 Å. The C(10)-H(14) bond length is 1.10 Å. The C(10)-H(15) bond length is 1.10 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one Si(1), one C(12), and one C(15) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(15) bond length is 1.45 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(16) atom. The C(12)-C(13) bond length is 1.46 Å. The C(12)-H(16) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a 4-coordinate geometry to one Zn(1), one C(12), one C(14), and one H(17) atom. The C(13)-C(14) bond length is 1.46 Å. The C(13)-H(17) bond length is 1.10 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(18) atom. The C(14)-H(18) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(11) and one H(19) atom. The C(15)-H(19) bond length is 1.09 Å. In the fifteenth C site, C(16) is bonded to one Si(1), one H(20), one H(21), and one H(22) atom to form corner-sharing CSiH3 tetrahedra. The C(16)-H(20) bond length is 1.10 Å. The C(16)-H(21) bond length is 1.10 Å. The C(16)-H(22) bond length is 1.10 Å. In the sixteenth C site, C(17) is bonded to one Si(1); one H(23); one H(24); and one H(25,28) atom to form corner-sharing CSiH3 tetrahedra. The C(17)-H(23) bond length is 1.10 Å. The C(17)-H(24) bond length is 1.10 Å. The C(17)-H(25,28) bond length is 1.10 Å. In the seventeenth C site, C(18) is bonded to one Si(1); one H(25,28); one H(26); and one H(27) atom to form corner-sharing CSiH3 tetrahedra. The C(18)-H(25,28) bond length is 1.10 Å. The C(18)-H(26) bond length is 1.10 Å. The C(18)-H(27) bond length is 1.10 Å. In the eighteenth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one H(29), one H(30), and one O(2) atom. The C(19)-H(29) bond length is 1.10 Å. The C(19)-H(30) bond length is 1.10 Å. The C(19)-O(2) bond length is 1.44 Å. In the nineteenth C site, C(20) is bonded in a distorted trigonal non-coplanar geometry to one H(31), one H(32), and one O(2) atom. The C(20)-H(31) bond length is 1.10 Å. The C(20)-H(32) bond length is 1.10 Å. The C(20)-O(2) bond length is 1.44 Å. There are twenty-eight inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(14) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(15) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(16) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(16) atom. In the nineteenth H site, H(22) is bonded in a single-bond geometry to one C(16) atom. In the twentieth H site, H(23) is bonded in a single-bond geometry to one C(17) atom. In the twenty-first H site, H(24) is bonded in a single-bond geometry to one C(17) atom. In the twenty-second H site, H(25,28) is bonded in a single-bond geometry to one C(17) atom. In the twenty-third H site, H(26) is bonded in a single-bond geometry to one C(18) atom. In the twenty-fourth H site, H(27) is bonded in a single-bond geometry to one C(18) atom. In the twenty-fifth H site, H(29) is bonded in a single-bond geometry to one C(19) atom. In the twenty-sixth H site, H(30) is bonded in a single-bond geometry to one C(19) atom. In the twenty-seventh H site, H(31) is bonded in a single-bond geometry to one C(20) atom. In the twenty-eighth H site, H(32) is bonded in a single-bond geometry to one C(20) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(19), and one C(20) atom. Linkers: 1 C1COCCO1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 4.01 A, density 1.17 g/cm3, surface area 6273.56 m2/g, accessible volume 0.27 cm3/g