NaC6NH9O2(CH)5(CH3)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, eight 02329_fluka molecules, four propylene molecules, and two NaC6NH9O2 clusters. In each NaC6NH9O2 cluster, Na(1) is bonded in a 4-coordinate geometry to two equivalent N(1), one O(1), and one O(2) atom. There is one shorter (2.39 Å) and one longer (2.49 Å) Na(1)-N(1) bond length. The Na(1)-O(1) bond length is 2.33 Å. The Na(1)-O(2) bond length is 2.32 Å. There are six inequivalent C sites. In the first C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one H(17), one H(18), and one O(2) atom. The C(12)-H(17) bond length is 1.10 Å. The C(12)-H(18) bond length is 1.10 Å. The C(12)-O(2) bond length is 1.44 Å. In the second C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one H(19), one H(20), and one O(2) atom. The C(13)-H(19) bond length is 1.10 Å. The C(13)-H(20) bond length is 1.11 Å. The C(13)-O(2) bond length is 1.44 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one N(1) atom. The C(6)-N(1) bond length is 1.36 Å. In the fourth C site, C(7) is bonded in a 2-coordinate geometry to one N(1) and one H(6) atom. The C(7)-N(1) bond length is 1.46 Å. The C(7)-H(6) bond length is 1.11 Å. In the fifth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one H(13), one H(14), and one O(1) atom. The C(10)-H(13) bond length is 1.10 Å. The C(10)-H(14) bond length is 1.10 Å. The C(10)-O(1) bond length is 1.44 Å. In the sixth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one H(15), one H(16), and one O(1) atom. The C(11)-H(15) bond length is 1.10 Å. The C(11)-H(16) bond length is 1.11 Å. The C(11)-O(1) bond length is 1.44 Å. N(1) is bonded in a 4-coordinate geometry to two equivalent Na(1), one C(6), and one C(7) atom. There are nine inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(20) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Na(1), one C(10), and one C(11) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Na(1), one C(12), and one C(13) atom. Linkers: 4 CC(C)[N]c1ccccc1 ,4 C1COCCO1. Metal clusters: 4 [Na]. The MOF has largest included sphere 5.07 A, density 0.92 g/cm3, surface area 5766.95 m2/g, accessible volume 0.48 cm3/g