CuC14H8(NO)3CuC4NH2O4(CH)3(CH3)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, six 02329_fluka molecules, one CuC14H8(NO)3 cluster, and one CuC4NH2O4 cluster. In the CuC14H8(NO)3 cluster, Cu(1) is bonded to one N(1), one N(2), one O(1), and two equivalent O(2) atoms to form edge-sharing CuN2O3 square pyramids. The Cu(1)-N(1) bond length is 2.00 Å. The Cu(1)-N(2) bond length is 1.94 Å. The Cu(1)-O(1) bond length is 2.02 Å. There is one shorter (1.94 Å) and one longer (2.33 Å) Cu(1)-O(2) bond length. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.48 Å. The C(5)-N(1) bond length is 1.36 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(13), one C(5), and one N(2) atom. The C(6)-C(13) bond length is 1.47 Å. The C(6)-N(2) bond length is 1.32 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(3), and one O(1) atom. The C(7)-C(8) bond length is 1.48 Å. The C(7)-N(3) bond length is 1.35 Å. The C(7)-O(1) bond length is 1.29 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(7), and one C(9) atom. The C(8)-C(11) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(9)-H(5) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(6) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(18) bond length is 1.41 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(9) atom. The C(14)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(13) atom. The C(18)-H(13) bond length is 1.09 Å. In the fourteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(19)-O(2) bond length is 1.31 Å. The C(19)-O(3) bond length is 1.24 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(6), and one N(3) atom. The N(2)-N(3) bond length is 1.34 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(7) and one N(2) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(7) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Cu(1) and one C(19) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(19) atom. In the CuC4NH2O4 cluster, Cu(2) is bonded in a square pyramidal geometry to one N(4), one O(4), one O(5), one O(6), and one O(7) atom. The Cu(2)-N(4) bond length is 2.19 Å. The Cu(2)-O(4) bond length is 2.02 Å. The Cu(2)-O(5) bond length is 2.02 Å. The Cu(2)-O(6) bond length is 2.00 Å. The Cu(2)-O(7) bond length is 2.01 Å. There are four inequivalent C sites. In the first C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(6) atom. The C(10)-N(4) bond length is 1.34 Å. The C(10)-H(6) bond length is 1.09 Å. In the second C site, C(12) is bonded in a distorted trigonal planar geometry to one N(4) and one H(8) atom. The C(12)-N(4) bond length is 1.35 Å. The C(12)-H(8) bond length is 1.09 Å. In the third C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(21)-O(6) bond length is 1.28 Å. The C(21)-O(7) bond length is 1.28 Å. In the fourth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(23)-O(4) bond length is 1.27 Å. The C(23)-O(5) bond length is 1.27 Å. N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(10), and one C(12) atom. There are two inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(23) atom. In the second O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(23) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(21) atom. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(21) atom. Linkers: 2 O=C([N]/N=C(\c1ccccc1)c1ccccn1)c1ccncc1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 2.67 A, density 1.66 g/cm3, surface area 4482.26 m2/g, accessible volume 0.14 cm3/g