ZnC12H10I2(N2O)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ZnC12H10I2(N2O)2 clusters. Zn(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(4), one I(1), and one I(2) atom. The Zn(1)-N(1) bond length is 2.09 Å. The Zn(1)-N(4) bond length is 2.10 Å. The Zn(1)-I(1) bond length is 2.56 Å. The Zn(1)-I(2) bond length is 2.55 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(3) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(3) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(2)-H(4) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(5) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(5) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(2) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(2) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(6) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(6) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(1) atom. The C(6)-N(2) bond length is 1.35 Å. The C(6)-O(1) bond length is 1.24 Å. In the seventh C site, C(7) is bonded in a 2-coordinate geometry to one N(3) and one O(2) atom. The C(7)-N(3) bond length is 1.36 Å. The C(7)-O(2) bond length is 1.23 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(9), and one N(3) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. The C(8)-N(3) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(4), and one H(9) atom. The C(11)-N(4) bond length is 1.34 Å. The C(11)-H(9) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(4), and one H(10) atom. The C(12)-N(4) bond length is 1.35 Å. The C(12)-H(10) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(4), one C(6), and one H(1) atom. The N(2)-H(1) bond length is 1.03 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(7), one C(8), and one H(2) atom. The N(3)-H(2) bond length is 1.02 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(12) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 4 O=C(Nc1cccnc1)C(=O)Nc1cccnc1. Metal clusters: 4 I[Zn]I. The MOF has largest included sphere 4.85 A, density 1.67 g/cm3, surface area 3344.60 m2/g, accessible volume 0.31 cm3/g