Na2Zn3C4H10(SO10)2(CH)2(CH2)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules and four 02329_fluka molecules inside a Na2Zn3C4H10(SO10)2 framework. In the Na2Zn3C4H10(SO10)2 framework, Na(1) is bonded to one O(10), one O(2), one O(6), one O(7), one O(8), and one O(9) atom to form NaO6 octahedra that share  a cornercorner with one Zn(2)O4 tetrahedra and  an edgeedge with one Zn(2)O4 tetrahedra. The Na(1)-O(10) bond length is 2.33 Å. The Na(1)-O(2) bond length is 2.48 Å. The Na(1)-O(6) bond length is 2.31 Å. The Na(1)-O(7) bond length is 2.40 Å. The Na(1)-O(8) bond length is 2.52 Å. The Na(1)-O(9) bond length is 2.38 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. Both Zn(1)-O(1) bond lengths are 2.10 Å. Both Zn(1)-O(3) bond lengths are 2.09 Å. Both Zn(1)-O(5) bond lengths are 2.08 Å. In the second Zn site, Zn(2) is bonded to one O(2), one O(4), and two equivalent O(8) atoms to form ZnO4 tetrahedra that share  a cornercorner with one Na(1)O6 octahedra, corners with two equivalent Zn(2)O4 tetrahedra, and  an edgeedge with one Na(1)O6 octahedra. The corner-sharing octahedral tilt angles are 61°. The Zn(2)-O(2) bond length is 2.04 Å. The Zn(2)-O(4) bond length is 2.02 Å. There is one shorter (1.95 Å) and one longer (1.97 Å) Zn(2)-O(8) bond length. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(4)-O(3) bond length is 1.26 Å. The C(4)-O(4) bond length is 1.29 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(8) atom. The H(1)-O(8) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(9) atom. The H(2)-O(9) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(9) atom. The H(3)-O(9) bond length is 0.98 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(10) atom. The H(4)-O(10) bond length is 0.98 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(10) atom. The H(5)-O(10) bond length is 0.98 Å. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(5), one O(6), and one O(7) atom. The S(1)-O(5) bond length is 1.48 Å. The S(1)-O(6) bond length is 1.46 Å. The S(1)-O(7) bond length is 1.48 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one Zn(2), and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Na(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Na(1) and one S(1) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one Na(1), two equivalent Zn(2), and one H(1) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Na(1), one H(2), and one H(3) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Na(1), one H(4), and one H(5) atom. Linkers: 2 [O]C(=O)C[C@H](C([O])=O)S([O])([O])[O] ,2 [O]C(=O)C[C@@H](C([O])=O)S([O])([O])[O]. Metal clusters: 4 [Na] ,6 [Zn]. The MOF has largest included sphere 1.67 A, density 2.39 g/cm3, surface area 2524.59 m2/g, accessible volume 0.08 cm3/g