CuC12N2H12ICH2C4H5(CH)2CNH2C7H9N is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 02329_fluka molecules, two isobutylene molecules, two methylamine molecules, two p-toluidine molecules, and one CuC12N2H12I cluster. In the CuC12N2H12I cluster, Cu(1) is bonded in a 2-coordinate geometry to one N(1), one N(2), and two equivalent I(1) atoms. The Cu(1)-N(1) bond length is 2.01 Å. The Cu(1)-N(2) bond length is 2.01 Å. There is one shorter (2.64 Å) and one longer (2.68 Å) Cu(1)-I(1) bond length. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.50 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one C(3), one H(5), and one H(6) atom. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the seventh C site, C(8) is bonded in a distorted water-like geometry to one C(9) and two equivalent H(9,10) atoms. The C(8)-C(9) bond length is 1.50 Å. Both C(8)-H(9,10) bond lengths are 1.10 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(13) bond length is 1.40 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(11) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(11) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(2), and one H(12) atom. The C(11)-N(2) bond length is 1.35 Å. The C(11)-H(12) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one N(2), and one H(13) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(13) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(9), and one H(14) atom. The C(13)-H(14) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(12) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(13) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 1 Cc1ccc(N)cc1. Metal clusters: 1 I[Cu][Cu]I. The MOF has largest included sphere 2.10 A, density 1.59 g/cm3, surface area 5166.06 m2/g, accessible volume 0.11 cm3/g