CoC4H10(NCl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CoC4H10(NCl)2 clusters. Co(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one Cl(1), and one Cl(2) atom. The Co(1)-N(1) bond length is 2.04 Å. The Co(1)-N(2) bond length is 2.02 Å. The Co(1)-Cl(1) bond length is 2.23 Å. The Co(1)-Cl(2) bond length is 2.23 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(1)-N(1) bond length is 1.48 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(10), and one H(3) atom. The C(2)-N(1) bond length is 1.48 Å. The C(2)-H(10) bond length is 1.10 Å. The C(2)-H(3) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(4), and one H(5) atom. The C(3)-N(2) bond length is 1.49 Å. The C(3)-H(4) bond length is 1.10 Å. The C(3)-H(5) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(6), and one H(7) atom. The C(4)-N(2) bond length is 1.48 Å. The C(4)-H(6) bond length is 1.10 Å. The C(4)-H(7) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Co(1), one C(1), one C(2), and one H(9) atom to form distorted corner-sharing NCoHC2 tetrahedra. The N(1)-H(9) bond length is 1.03 Å. In the second N site, N(2) is bonded to one Co(1), one C(3), one C(4), and one H(8) atom to form distorted corner-sharing NCoHC2 tetrahedra. The N(2)-H(8) bond length is 1.04 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(1) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Co(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Co(1) atom. Linkers: 3 C1CNCCN1. Metal clusters: 2 [Co] ,2 [NH][Co]([NH])(Cl)Cl. The MOF has largest included sphere 1.65 A, density 1.92 g/cm3, surface area 4119.83 m2/g, accessible volume 0.10 cm3/g