(CH)4CuC14H10S2(NO)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two CuC14H10S2(NO)4 clusters. In each CuC14H10S2(NO)4 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(2) atoms. Both Cu(1)-N(1) bond lengths are 1.95 Å. Both Cu(1)-O(2) bond lengths are 2.02 Å. There are seven inequivalent C sites. In the first C site, C(2) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(2) bond length is 1.36 Å. The C(2)-S(1) bond length is 1.73 Å. In the second C site, C(3) is bonded in a distorted water-like geometry to one H(2), one H(3), and one S(1) atom. The C(3)-H(2) bond length is 1.10 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-S(1) bond length is 1.82 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one N(2) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-C(7) bond length is 1.39 Å. The C(4)-N(2) bond length is 1.38 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-N(1) bond length is 1.39 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(4) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the seventh C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(2), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(1) atom. The N(2)-H(1) bond length is 1.04 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. S(1) is bonded in a water-like geometry to one C(2) and one C(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cu(1) and one C(1) atom. Linkers: 2 [C][CH]C1=C([CH])N[C](SCC([O])=O)N1[Cu@@](OC(=O)CS[C])(OC(=O)CSc1nc2ccccc2[nH]1)N1[C](SCC([O])=O)Nc2ccccc21 ,2 [C][CH]C1=C([CH])N[C](SCC([O])=O)N1[Cu@@](OC(=O)CSc1nc([CH][C])c([CH])[nH]1)(OC(=O)CSc1nc2ccccc2[nH]1)N1[C](SCC([O])=O)Nc2ccccc21 ,1 [O]C(=O)CS[C]1Nc2ccccc2N1[Cu](OC(=O)CSc1nc2ccccc2[nH]1)(OC(=O)CSc1nc2ccccc2[nH]1)N1[C](SCC([O])=O)Nc2ccccc21 ,2 [C]SCC(=O)O[Cu](OC(=O)CSc1nc2ccccc2[nH]1)(N1[C](SCC([O])=O)Nc2ccccc21)N1[C](SCC([O])=O)Nc2ccccc21. Metal clusters: 1 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 2.25 A, density 1.70 g/cm3, surface area 4479.77 m2/g, accessible volume 0.14 cm3/g