FeC14H16(NO3)2 is Tungsten structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two FeC14H16(NO3)2 clusters. Fe(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(3) atoms. Both Fe(1)-N(1) bond lengths are 1.98 Å. Both Fe(1)-O(1) bond lengths are 2.03 Å. Both Fe(1)-O(3) bond lengths are 2.10 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(7) atom. The C(2)-C(5) bond length is 1.39 Å. The C(2)-C(6) bond length is 1.51 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(1) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(3) atom. The C(5)-N(1) bond length is 1.36 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one C(2), one H(4), and one H(5) atom. The C(6)-H(4) bond length is 1.10 Å. The C(6)-H(5) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Fe(1), one C(3), and one C(5) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(3) atom. The H(7)-O(3) bond length is 1.00 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(3) atom. The H(8)-O(3) bond length is 1.00 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Fe(1), one H(7), and one H(8) atom. Linkers: 4 [O]C(=O)Cc1cccnc1. Metal clusters: 2 O.O.O=[C]O[Fe]O[C]=O. The MOF has largest included sphere 1.89 A, density 1.75 g/cm3, surface area 3641.86 m2/g, accessible volume 0.11 cm3/g