CdC10H10(NO)4(CH2)8 is Indium-derived structured and crystallizes in the orthorhombic Pbcn space group. The structure is zero-dimensional and consists of sixty-four 02329_fluka molecules and eight CdC10H10(NO)4 clusters. In each CdC10H10(NO)4 cluster, Cd(1) is bonded in a distorted pentagonal pyramidal geometry to one N(1), one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.28 Å. The Cd(1)-N(3) bond length is 2.29 Å. The Cd(1)-O(1) bond length is 2.40 Å. The Cd(1)-O(2) bond length is 2.41 Å. The Cd(1)-O(3) bond length is 2.34 Å. The Cd(1)-O(4) bond length is 2.49 Å. There are ten inequivalent C sites. In the first C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.28 Å. The C(8)-O(4) bond length is 1.28 Å. In the second C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(13) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-N(1) bond length is 1.38 Å. The C(9)-H(13) bond length is 1.09 Å. In the third C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(2), and one H(14) atom. The C(10)-N(2) bond length is 1.38 Å. The C(10)-H(14) bond length is 1.08 Å. In the fourth C site, C(11) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(15) atom. The C(11)-N(1) bond length is 1.33 Å. The C(11)-N(2) bond length is 1.36 Å. The C(11)-H(15) bond length is 1.09 Å. In the fifth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(16), and one H(17) atom. The C(12)-N(2) bond length is 1.46 Å. The C(12)-H(16) bond length is 1.10 Å. The C(12)-H(17) bond length is 1.10 Å. In the sixth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(15), one N(3), and one H(20) atom. The C(14)-C(15) bond length is 1.38 Å. The C(14)-N(3) bond length is 1.38 Å. The C(14)-H(20) bond length is 1.09 Å. In the seventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(4), and one H(21) atom. The C(15)-N(4) bond length is 1.38 Å. The C(15)-H(21) bond length is 1.08 Å. In the eighth C site, C(16) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(22) atom. The C(16)-N(3) bond length is 1.33 Å. The C(16)-N(4) bond length is 1.36 Å. The C(16)-H(22) bond length is 1.09 Å. In the ninth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.28 Å. In the tenth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(23), and one H(24) atom. The C(17)-N(4) bond length is 1.46 Å. The C(17)-H(23) bond length is 1.10 Å. The C(17)-H(24) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(17) atom. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one C(9) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(12) atom. In the fourth N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(14), and one C(16) atom. There are ten inequivalent H sites. In the first H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(17) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(20) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(21) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(22) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(23) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(24) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(8) atom. Linkers: 8 c1cn(CCCCn2ccnc2)cn1 ,8 [O]C(=O)CCCCCCC([O])=O. Metal clusters: 8 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 3.30 A, density 1.43 g/cm3, surface area 5027.49 m2/g, accessible volume 0.20 cm3/g