Mo6Cu5C24As6H32(N4O5)6(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one Mo6Cu5C24As6H32(N4O5)6 cluster. In the Mo6Cu5C24As6H32(N4O5)6 cluster, there are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(12), one O(2), one O(6), and one O(9) atom. The Mo(1)-O(10) bond length is 1.74 Å. The Mo(1)-O(11) bond length is 1.72 Å. The Mo(1)-O(12) bond length is 1.93 Å. The Mo(1)-O(2) bond length is 2.29 Å. The Mo(1)-O(6) bond length is 2.41 Å. The Mo(1)-O(9) bond length is 1.93 Å. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(12), one O(13), one O(14), one O(15), one O(2), and one O(5) atom. The Mo(2)-O(12) bond length is 1.93 Å. The Mo(2)-O(13) bond length is 1.72 Å. The Mo(2)-O(14) bond length is 1.74 Å. The Mo(2)-O(15) bond length is 1.90 Å. The Mo(2)-O(2) bond length is 2.31 Å. The Mo(2)-O(5) bond length is 2.44 Å. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(15), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. The Mo(3)-O(15) bond length is 1.94 Å. The Mo(3)-O(5) bond length is 2.27 Å. The Mo(3)-O(6) bond length is 2.32 Å. The Mo(3)-O(7) bond length is 1.73 Å. The Mo(3)-O(8) bond length is 1.75 Å. The Mo(3)-O(9) bond length is 1.92 Å. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a T-shaped geometry to one N(1), one N(5), and one O(10) atom. The Cu(1)-N(1) bond length is 1.87 Å. The Cu(1)-N(5) bond length is 1.87 Å. The Cu(1)-O(10) bond length is 2.46 Å. In the second Cu site, Cu(2) is bonded in a T-shaped geometry to one N(4), one N(7), and one O(8) atom. The Cu(2)-N(4) bond length is 1.87 Å. The Cu(2)-N(7) bond length is 1.88 Å. The Cu(2)-O(8) bond length is 2.25 Å. In the third Cu site, Cu(3) is bonded in an octahedral geometry to two equivalent O(2), two equivalent O(5), and two equivalent O(6) atoms. Both Cu(3)-O(2) bond lengths are 2.28 Å. Both Cu(3)-O(5) bond lengths are 2.01 Å. Both Cu(3)-O(6) bond lengths are 2.01 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(9), and one H(1) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-N(9) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(10), one N(4), and one H(2) atom. The C(2)-N(10) bond length is 1.32 Å. The C(2)-N(4) bond length is 1.37 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(11), one N(5), and one H(3) atom. The C(3)-N(11) bond length is 1.33 Å. The C(3)-N(5) bond length is 1.37 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(12), one N(7), and one H(4) atom. The C(4)-N(12) bond length is 1.33 Å. The C(4)-N(7) bond length is 1.37 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(5) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-N(2) bond length is 1.34 Å. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(6), and one H(7) atom. The C(6)-N(2) bond length is 1.45 Å. The C(6)-H(6) bond length is 1.10 Å. The C(6)-H(7) bond length is 1.10 Å. In the seventh C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(10), and one H(11) atom. The C(8)-N(3) bond length is 1.46 Å. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(11) bond length is 1.10 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(12) atom. The C(9)-N(3) bond length is 1.34 Å. The C(9)-N(4) bond length is 1.34 Å. The C(9)-H(12) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(13) atom. The C(10)-N(5) bond length is 1.34 Å. The C(10)-N(6) bond length is 1.34 Å. The C(10)-H(13) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(14), and one H(15) atom. The C(11)-N(6) bond length is 1.46 Å. The C(11)-H(14) bond length is 1.10 Å. The C(11)-H(15) bond length is 1.10 Å. In the eleventh C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(8), one H(18), and one H(19) atom. The C(13)-N(8) bond length is 1.46 Å. The C(13)-H(18) bond length is 1.10 Å. The C(13)-H(19) bond length is 1.10 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(20) atom. The C(14)-N(7) bond length is 1.34 Å. The C(14)-N(8) bond length is 1.34 Å. The C(14)-H(20) bond length is 1.08 Å. There are three inequivalent As sites. In the first As site, As(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(4), and one O(5) atom. The As(1)-O(1) bond length is 1.81 Å. The As(1)-O(4) bond length is 1.82 Å. The As(1)-O(5) bond length is 1.83 Å. In the second As site, As(2) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. The As(2)-O(1) bond length is 1.83 Å. The As(2)-O(2) bond length is 1.81 Å. The As(2)-O(3) bond length is 1.84 Å. In the third As site, As(3) is bonded in a distorted trigonal non-coplanar geometry to one O(3), one O(4), and one O(6) atom. The As(3)-O(3) bond length is 1.83 Å. The As(3)-O(4) bond length is 1.82 Å. The As(3)-O(6) bond length is 1.83 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(5), one C(6), and one N(9) atom. The N(2)-N(9) bond length is 1.36 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(8), one C(9), and one N(10) atom. The N(3)-N(10) bond length is 1.37 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(2), and one C(9) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(3) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one C(10), one C(11), and one N(11) atom. The N(6)-N(11) bond length is 1.37 Å. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Cu(2), one C(14), and one C(4) atom. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one C(13), one C(14), and one N(12) atom. The N(8)-N(12) bond length is 1.36 Å. In the ninth N site, N(9) is bonded in a distorted water-like geometry to one C(1) and one N(2) atom. In the tenth N site, N(10) is bonded in a distorted water-like geometry to one C(2) and one N(3) atom. In the eleventh N site, N(11) is bonded in a water-like geometry to one C(3) and one N(6) atom. In the twelfth N site, N(12) is bonded in a distorted water-like geometry to one C(4) and one N(8) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(11) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(13) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(13) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(14) atom. There are fifteen inequivalent O sites. In the first O site, O(11) is bonded in a single-bond geometry to one Mo(1) atom. In the second O site, O(12) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the third O site, O(13) is bonded in a single-bond geometry to one Mo(2) atom. In the fourth O site, O(14) is bonded in a single-bond geometry to one Mo(2) atom. In the fifth O site, O(15) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(3) atom. In the sixth O site, O(1) is bonded in a bent 120 degrees geometry to one As(1) and one As(2) atom. In the seventh O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Mo(1), one Mo(2), one Cu(3), and one As(2) atom. In the eighth O site, O(3) is bonded in a bent 120 degrees geometry to one As(2) and one As(3) atom. In the ninth O site, O(4) is bonded in a bent 120 degrees geometry to one As(1) and one As(3) atom. In the tenth O site, O(5) is bonded in a 4-coordinate geometry to one Mo(2), one Mo(3), one Cu(3), and one As(1) atom. In the eleventh O site, O(6) is bonded in a 4-coordinate geometry to one Mo(1), one Mo(3), one Cu(3), and one As(3) atom. In the twelfth O site, O(7) is bonded in a single-bond geometry to one Mo(3) atom. In the thirteenth O site, O(8) is bonded in a bent 120 degrees geometry to one Mo(3) and one Cu(2) atom. In the fourteenth O site, O(9) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(3) atom. In the fifteenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Cu(1) atom. Linkers: 2 c1ncn(CCCn2cncn2)n1 ,2 [CH]1N=C[N]N1CCCn1cncn1 ,2 [O][As]1O[As]([O])O[As]([O])O1. Metal clusters: 1 [Cu].[Cu].[O][Mo]1([O])O[Mo]2([O])([O])O[Cu]3456O[Mo]([O])([O])(O[Mo]([O])([O])O[Mo]([O])(O[Cu])(O2)(O3)O4)O[Mo]([O])(O[Cu])(O1)(O5)O6. The MOF has largest included sphere 3.51 A, density 2.60 g/cm3, surface area 2549.85 m2/g, accessible volume 0.10 cm3/g