PtCdC16H16(N3O)2(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a PtCdC16H16(N3O)2 framework. In the PtCdC16H16(N3O)2 framework, Pt(1) is bonded in a square co-planar geometry to two equivalent C(1) and two equivalent C(2) atoms. Both Pt(1)-C(1) bond lengths are 1.98 Å. Both Pt(1)-C(2) bond lengths are 1.97 Å. Cd(1) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(3), and two equivalent O(1) atoms. Both Cd(1)-N(2) bond lengths are 2.36 Å. Both Cd(1)-N(3) bond lengths are 2.34 Å. Both Cd(1)-O(1) bond lengths are 2.34 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Pt(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. In the second C site, C(2) is bonded in a linear geometry to one Pt(1) and one N(2) atom. The C(2)-N(2) bond length is 1.17 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one H(2), one H(3), and one O(1) atom. The C(3)-H(2) bond length is 1.10 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-O(1) bond length is 1.44 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(7), one N(3), and one H(4) atom. The C(4)-C(7) bond length is 1.39 Å. The C(4)-N(3) bond length is 1.35 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(3) atom. The C(5)-C(6) bond length is 1.50 Å. The C(5)-C(8) bond length is 1.40 Å. The C(5)-N(3) bond length is 1.35 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one C(5), one H(5), and one H(6) atom. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(4) and one H(7) atom. The C(7)-H(7) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(5) and one H(8) atom. The C(8)-H(8) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one C(1) and one H(1) atom. The N(1)-H(1) bond length is 1.64 Å. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(4), and one C(5) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one N(1) and one O(1) atom. The H(1)-O(1) bond length is 1.01 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. O(1) is bonded in a 3-coordinate geometry to one Cd(1), one C(3), and one H(1) atom. Linkers: 2 OCCc1ccccn1. Metal clusters: 2 [Cd] ,2 [Pt]. The MOF has largest included sphere 1.91 A, density 2.20 g/cm3, surface area 3636.77 m2/g, accessible volume 0.09 cm3/g