MnC17H10S2O5 crystallizes in the monoclinic P2_1 space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted octahedral geometry to one O(10), one O(13), one O(24), one O(25), one O(28), and one O(5) atom. The Mn(1)-O(10) bond length is 2.12 Å. The Mn(1)-O(13) bond length is 2.10 Å. The Mn(1)-O(24) bond length is 2.12 Å. The Mn(1)-O(25) bond length is 2.53 Å. The Mn(1)-O(28) bond length is 2.23 Å. The Mn(1)-O(5) bond length is 2.14 Å. In the second Mn site, Mn(2) is bonded in a distorted octahedral geometry to one O(11), one O(14), one O(22), one O(26), one O(29), and one O(6) atom. The Mn(2)-O(11) bond length is 2.12 Å. The Mn(2)-O(14) bond length is 2.10 Å. The Mn(2)-O(22) bond length is 2.12 Å. The Mn(2)-O(26) bond length is 2.53 Å. The Mn(2)-O(29) bond length is 2.23 Å. The Mn(2)-O(6) bond length is 2.14 Å. In the third Mn site, Mn(3) is bonded in a distorted octahedral geometry to one O(12), one O(15), one O(23), one O(27), one O(30), and one O(4) atom. The Mn(3)-O(12) bond length is 2.12 Å. The Mn(3)-O(15) bond length is 2.10 Å. The Mn(3)-O(23) bond length is 2.12 Å. The Mn(3)-O(27) bond length is 2.53 Å. The Mn(3)-O(30) bond length is 2.23 Å. The Mn(3)-O(4) bond length is 2.14 Å. In the fourth Mn site, Mn(4) is bonded in a 5-coordinate geometry to one O(1), one O(18), one O(19), one O(4), and one O(8) atom. The Mn(4)-O(1) bond length is 2.15 Å. The Mn(4)-O(18) bond length is 2.02 Å. The Mn(4)-O(19) bond length is 2.10 Å. The Mn(4)-O(4) bond length is 2.38 Å. The Mn(4)-O(8) bond length is 2.01 Å. In the fifth Mn site, Mn(5) is bonded in a 5-coordinate geometry to one O(16), one O(2), one O(20), one O(5), and one O(9) atom. The Mn(5)-O(16) bond length is 2.02 Å. The Mn(5)-O(2) bond length is 2.15 Å. The Mn(5)-O(20) bond length is 2.09 Å. The Mn(5)-O(5) bond length is 2.38 Å. The Mn(5)-O(9) bond length is 2.01 Å. In the sixth Mn site, Mn(6) is bonded in a 5-coordinate geometry to one O(17), one O(21), one O(3), one O(6), and one O(7) atom. The Mn(6)-O(17) bond length is 2.02 Å. The Mn(6)-O(21) bond length is 2.09 Å. The Mn(6)-O(3) bond length is 2.15 Å. The Mn(6)-O(6) bond length is 2.38 Å. The Mn(6)-O(7) bond length is 2.01 Å. There are sixty-eight inequivalent C sites. In the first C site, C(1,3) is bonded in a trigonal planar geometry to one C(4,5,6); one S(10,11,12); and one S(7,9) atom. The C(1,3)-C(4,5,6) bond length is 1.36 Å. The C(1,3)-S(10,11,12) bond length is 1.75 Å. The C(1,3)-S(7,9) bond length is 1.75 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(4,5,6); one S(10,11,12); and one S(8) atom. The C(2)-C(4,5,6) bond length is 1.36 Å. The C(2)-S(10,11,12) bond length is 1.75 Å. The C(2)-S(8) bond length is 1.75 Å. In the third C site, C(4,5,6) is bonded in a trigonal planar geometry to one C(1,3); one S(1,3); and one S(4,6) atom. The C(4,5,6)-S(1,3) bond length is 1.75 Å. The C(4,5,6)-S(4,6) bond length is 1.75 Å. In the fourth C site, C(7) is bonded in a trigonal planar geometry to one C(10,11,12); one C(28,29,30); and one S(1,3) atom. The C(7)-C(10,11,12) bond length is 1.37 Å. The C(7)-C(28,29,30) bond length is 1.47 Å. The C(7)-S(1,3) bond length is 1.76 Å. In the fifth C site, C(8) is bonded in a trigonal planar geometry to one C(10,11,12); one C(28,29,30); and one S(2) atom. The C(8)-C(10,11,12) bond length is 1.37 Å. The C(8)-C(28,29,30) bond length is 1.47 Å. The C(8)-S(2) bond length is 1.76 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10,11,12); one C(28,29,30); and one S(1,3) atom. The C(9)-C(10,11,12) bond length is 1.37 Å. The C(9)-C(28,29,30) bond length is 1.47 Å. The C(9)-S(1,3) bond length is 1.76 Å. In the seventh C site, C(10,11,12) is bonded in a trigonal planar geometry to one C(49,51); one C(7); and one S(4,6) atom. The C(10,11,12)-C(49,51) bond length is 1.47 Å. The C(10,11,12)-S(4,6) bond length is 1.75 Å. In the eighth C site, C(13,14,15) is bonded in a trigonal planar geometry to one C(16,18); one C(70); and one S(7,9) atom. The C(13,14,15)-C(16,18) bond length is 1.37 Å. The C(13,14,15)-C(70) bond length is 1.47 Å. The C(13,14,15)-S(7,9) bond length is 1.75 Å. In the ninth C site, C(16,18) is bonded in a trigonal planar geometry to one C(13,14,15); one C(91,92,93); and one S(10,11,12) atom. The C(16,18)-C(91,92,93) bond length is 1.47 Å. The C(16,18)-S(10,11,12) bond length is 1.76 Å. In the tenth C site, C(17) is bonded in a trigonal planar geometry to one C(13,14,15); one C(91,92,93); and one S(10,11,12) atom. The C(17)-C(13,14,15) bond length is 1.37 Å. The C(17)-C(91,92,93) bond length is 1.47 Å. The C(17)-S(10,11,12) bond length is 1.76 Å. In the eleventh C site, C(19) is bonded in a trigonal planar geometry to one C(22,23,24); one C(34,35,36); and one C(37) atom. The C(19)-C(22,23,24) bond length is 1.41 Å. The C(19)-C(34,35,36) bond length is 1.40 Å. The C(19)-C(37) bond length is 1.47 Å. In the twelfth C site, C(20) is bonded in a trigonal planar geometry to one C(22,23,24); one C(34,35,36); and one C(38) atom. The C(20)-C(22,23,24) bond length is 1.41 Å. The C(20)-C(34,35,36) bond length is 1.40 Å. The C(20)-C(38) bond length is 1.47 Å. In the thirteenth C site, C(21) is bonded in a trigonal planar geometry to one C(22,23,24); one C(34,35,36); and one C(39) atom. The C(21)-C(22,23,24) bond length is 1.41 Å. The C(21)-C(34,35,36) bond length is 1.40 Å. The C(21)-C(39) bond length is 1.47 Å. In the fourteenth C site, C(22,23,24) is bonded in a distorted trigonal planar geometry to one C(19), one C(25), and one H(1) atom. The C(22,23,24)-C(25) bond length is 1.39 Å. The C(22,23,24)-H(1) bond length is 1.09 Å. In the fifteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(22,23,24); one C(28,29,30); and one H(4,5,6) atom. The C(25)-C(28,29,30) bond length is 1.41 Å. The C(25)-H(4,5,6) bond length is 1.09 Å. In the sixteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(22,23,24); one C(28,29,30); and one H(4,5,6) atom. The C(26)-C(22,23,24) bond length is 1.39 Å. The C(26)-C(28,29,30) bond length is 1.41 Å. The C(26)-H(4,5,6) bond length is 1.09 Å. In the seventeenth C site, C(27) is bonded in a distorted single-bond geometry to one C(22,23,24); one C(28,29,30); and one H(4,5,6) atom. The C(27)-C(22,23,24) bond length is 1.39 Å. The C(27)-C(28,29,30) bond length is 1.41 Å. The C(27)-H(4,5,6) bond length is 1.09 Å. In the eighteenth C site, C(28,29,30) is bonded in a trigonal planar geometry to one C(25), one C(31), and one C(7) atom. The C(28,29,30)-C(31) bond length is 1.41 Å. In the nineteenth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(28,29,30); one C(34,35,36); and one H(7,8,9) atom. The C(31)-C(34,35,36) bond length is 1.39 Å. The C(31)-H(7,8,9) bond length is 1.09 Å. In the twentieth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(28,29,30); one C(34,35,36); and one H(7,8,9) atom. The C(32)-C(28,29,30) bond length is 1.41 Å. The C(32)-C(34,35,36) bond length is 1.39 Å. The C(32)-H(7,8,9) bond length is 1.09 Å. In the twenty-first C site, C(33) is bonded in a distorted trigonal planar geometry to one C(28,29,30); one C(34,35,36); and one H(7,8,9) atom. The C(33)-C(28,29,30) bond length is 1.41 Å. The C(33)-C(34,35,36) bond length is 1.39 Å. The C(33)-H(7,8,9) bond length is 1.09 Å. In the twenty-second C site, C(34,35,36) is bonded in a distorted trigonal planar geometry to one C(19); one C(31); and one H(10,12) atom. The C(34,35,36)-H(10,12) bond length is 1.09 Å. In the twenty-third C site, C(37) is bonded in a bent 120 degrees geometry to one C(19), one O(1), and one O(4) atom. The C(37)-O(1) bond length is 1.29 Å. The C(37)-O(4) bond length is 1.29 Å. In the twenty-fourth C site, C(38) is bonded in a bent 120 degrees geometry to one C(20), one O(2), and one O(5) atom. The C(38)-O(2) bond length is 1.29 Å. The C(38)-O(5) bond length is 1.29 Å. In the twenty-fifth C site, C(39) is bonded in a bent 120 degrees geometry to one C(21), one O(3), and one O(6) atom. The C(39)-O(3) bond length is 1.29 Å. The C(39)-O(6) bond length is 1.29 Å. In the twenty-sixth C site, C(40) is bonded in a trigonal planar geometry to one C(43,45); one C(55,57); and one C(58) atom. The C(40)-C(43,45) bond length is 1.40 Å. The C(40)-C(55,57) bond length is 1.40 Å. The C(40)-C(58) bond length is 1.49 Å. In the twenty-seventh C site, C(41) is bonded in a trigonal planar geometry to one C(44), one C(56), and one C(59) atom. The C(41)-C(44) bond length is 1.40 Å. The C(41)-C(56) bond length is 1.40 Å. The C(41)-C(59) bond length is 1.49 Å. In the twenty-eighth C site, C(42) is bonded in a trigonal planar geometry to one C(43,45); one C(55,57); and one C(60) atom. The C(42)-C(43,45) bond length is 1.40 Å. The C(42)-C(55,57) bond length is 1.40 Å. The C(42)-C(60) bond length is 1.49 Å. In the twenty-ninth C site, C(43,45) is bonded in a distorted single-bond geometry to one C(40); one C(46,47,48); and one H(13,14,15) atom. The C(43,45)-C(46,47,48) bond length is 1.39 Å. The C(43,45)-H(13,14,15) bond length is 1.09 Å. In the thirtieth C site, C(44) is bonded in a distorted single-bond geometry to one C(41); one C(46,47,48); and one H(13,14,15) atom. The C(44)-C(46,47,48) bond length is 1.39 Å. The C(44)-H(13,14,15) bond length is 1.09 Å. In the thirty-first C site, C(46,47,48) is bonded in a distorted trigonal planar geometry to one C(43,45); one C(49,51); and one H(16,18) atom. The C(46,47,48)-C(49,51) bond length is 1.41 Å. The C(46,47,48)-H(16,18) bond length is 1.09 Å. In the thirty-second C site, C(49,51) is bonded in a trigonal planar geometry to one C(10,11,12); one C(46,47,48); and one C(52,53,54) atom. The C(49,51)-C(52,53,54) bond length is 1.41 Å. In the thirty-third C site, C(50) is bonded in a trigonal planar geometry to one C(10,11,12); one C(46,47,48); and one C(52,53,54) atom. The C(50)-C(10,11,12) bond length is 1.47 Å. The C(50)-C(46,47,48) bond length is 1.41 Å. The C(50)-C(52,53,54) bond length is 1.41 Å. In the thirty-fourth C site, C(52,53,54) is bonded in a distorted single-bond geometry to one C(49,51); one C(55,57); and one H(19,20,21) atom. The C(52,53,54)-C(55,57) bond length is 1.39 Å. The C(52,53,54)-H(19,20,21) bond length is 1.09 Å. In the thirty-fifth C site, C(55,57) is bonded in a distorted trigonal planar geometry to one C(40); one C(52,53,54); and one H(22,23,24) atom. The C(55,57)-H(22,23,24) bond length is 1.09 Å. In the thirty-sixth C site, C(56) is bonded in a distorted trigonal planar geometry to one C(41); one C(52,53,54); and one H(22,23,24) atom. The C(56)-C(52,53,54) bond length is 1.39 Å. The C(56)-H(22,23,24) bond length is 1.09 Å. In the thirty-seventh C site, C(58) is bonded in a bent 120 degrees geometry to one C(40), one O(10), and one O(7) atom. The C(58)-O(10) bond length is 1.27 Å. The C(58)-O(7) bond length is 1.28 Å. In the thirty-eighth C site, C(59) is bonded in a bent 120 degrees geometry to one C(41), one O(11), and one O(8) atom. The C(59)-O(11) bond length is 1.27 Å. The C(59)-O(8) bond length is 1.28 Å. In the thirty-ninth C site, C(60) is bonded in a bent 120 degrees geometry to one C(42), one O(12), and one O(9) atom. The C(60)-O(12) bond length is 1.27 Å. The C(60)-O(9) bond length is 1.28 Å. In the fortieth C site, C(61) is bonded in a trigonal planar geometry to one C(64), one C(76), and one C(79) atom. The C(61)-C(64) bond length is 1.40 Å. The C(61)-C(76) bond length is 1.40 Å. The C(61)-C(79) bond length is 1.49 Å. In the forty-first C site, C(62) is bonded in a trigonal planar geometry to one C(65), one C(77), and one C(80) atom. The C(62)-C(65) bond length is 1.40 Å. The C(62)-C(77) bond length is 1.40 Å. The C(62)-C(80) bond length is 1.49 Å. In the forty-second C site, C(63) is bonded in a trigonal planar geometry to one C(66), one C(78), and one C(81) atom. The C(63)-C(66) bond length is 1.40 Å. The C(63)-C(78) bond length is 1.40 Å. The C(63)-C(81) bond length is 1.49 Å. In the forty-third C site, C(64) is bonded in a distorted trigonal planar geometry to one C(61); one C(67,68,69); and one H(25,26,27) atom. The C(64)-C(67,68,69) bond length is 1.39 Å. The C(64)-H(25,26,27) bond length is 1.09 Å. In the forty-fourth C site, C(65) is bonded in a distorted trigonal planar geometry to one C(62); one C(67,68,69); and one H(25,26,27) atom. The C(65)-C(67,68,69) bond length is 1.39 Å. The C(65)-H(25,26,27) bond length is 1.09 Å. In the forty-fifth C site, C(66) is bonded in a distorted trigonal planar geometry to one C(63); one C(67,68,69); and one H(25,26,27) atom. The C(66)-C(67,68,69) bond length is 1.39 Å. The C(66)-H(25,26,27) bond length is 1.09 Å. In the forty-sixth C site, C(67,68,69) is bonded in a distorted single-bond geometry to one C(64); one C(70); and one H(28,30) atom. The C(67,68,69)-C(70) bond length is 1.41 Å. The C(67,68,69)-H(28,30) bond length is 1.09 Å. In the forty-seventh C site, C(70) is bonded in a trigonal planar geometry to one C(13,14,15); one C(67,68,69); and one C(73,74,75) atom. The C(70)-C(73,74,75) bond length is 1.41 Å. In the forty-eighth C site, C(71) is bonded in a trigonal planar geometry to one C(13,14,15); one C(67,68,69); and one C(73,74,75) atom. The C(71)-C(13,14,15) bond length is 1.47 Å. The C(71)-C(67,68,69) bond length is 1.41 Å. The C(71)-C(73,74,75) bond length is 1.41 Å. In the forty-ninth C site, C(72) is bonded in a trigonal planar geometry to one C(13,14,15); one C(67,68,69); and one C(73,74,75) atom. The C(72)-C(13,14,15) bond length is 1.47 Å. The C(72)-C(67,68,69) bond length is 1.41 Å. The C(72)-C(73,74,75) bond length is 1.41 Å. In the fiftieth C site, C(73,74,75) is bonded in a distorted trigonal planar geometry to one C(70); one C(76); and one H(31,32) atom. The C(73,74,75)-C(76) bond length is 1.39 Å. The C(73,74,75)-H(31,32) bond length is 1.09 Å. In the fifty-first C site, C(76) is bonded in a distorted single-bond geometry to one C(61); one C(73,74,75); and one H(34,35,36) atom. The C(76)-H(34,35,36) bond length is 1.09 Å. In the fifty-second C site, C(77) is bonded in a distorted single-bond geometry to one C(62); one C(73,74,75); and one H(34,35,36) atom. The C(77)-C(73,74,75) bond length is 1.39 Å. The C(77)-H(34,35,36) bond length is 1.09 Å. In the fifty-third C site, C(78) is bonded in a distorted single-bond geometry to one C(63); one C(73,74,75); and one H(34,35,36) atom. The C(78)-C(73,74,75) bond length is 1.39 Å. The C(78)-H(34,35,36) bond length is 1.09 Å. In the fifty-fourth C site, C(79) is bonded in a distorted bent 120 degrees geometry to one C(61), one O(13), and one O(16) atom. The C(79)-O(13) bond length is 1.27 Å. The C(79)-O(16) bond length is 1.28 Å. In the fifty-fifth C site, C(80) is bonded in a distorted bent 120 degrees geometry to one C(62), one O(14), and one O(17) atom. The C(80)-O(14) bond length is 1.27 Å. The C(80)-O(17) bond length is 1.28 Å. In the fifty-sixth C site, C(81) is bonded in a distorted bent 120 degrees geometry to one C(63), one O(15), and one O(18) atom. The C(81)-O(15) bond length is 1.27 Å. The C(81)-O(18) bond length is 1.28 Å. In the fifty-seventh C site, C(82) is bonded in a trigonal planar geometry to one C(100); one C(85,86,87); and one C(97,98,99) atom. The C(82)-C(100) bond length is 1.48 Å. The C(82)-C(85,86,87) bond length is 1.40 Å. The C(82)-C(97,98,99) bond length is 1.41 Å. In the fifty-eighth C site, C(83,84) is bonded in a trigonal planar geometry to one C(101); one C(85,86,87); and one C(97,98,99) atom. The C(83,84)-C(101) bond length is 1.48 Å. The C(83,84)-C(85,86,87) bond length is 1.40 Å. The C(83,84)-C(97,98,99) bond length is 1.41 Å. In the fifty-ninth C site, C(85,86,87) is bonded in a distorted trigonal planar geometry to one C(82); one C(88,90); and one H(37,38,39) atom. The C(85,86,87)-C(88,90) bond length is 1.39 Å. The C(85,86,87)-H(37,38,39) bond length is 1.09 Å. In the sixtieth C site, C(88,90) is bonded in a distorted trigonal planar geometry to one C(85,86,87); one C(91,92,93); and one H(40,41,42) atom. The C(88,90)-C(91,92,93) bond length is 1.41 Å. The C(88,90)-H(40,41,42) bond length is 1.09 Å. In the sixty-first C site, C(89) is bonded in a distorted trigonal planar geometry to one C(85,86,87); one C(91,92,93); and one H(40,41,42) atom. The C(89)-C(85,86,87) bond length is 1.39 Å. The C(89)-C(91,92,93) bond length is 1.41 Å. The C(89)-H(40,41,42) bond length is 1.09 Å. In the sixty-second C site, C(91,92,93) is bonded in a trigonal planar geometry to one C(16,18); one C(88,90); and one C(94,96) atom. The C(91,92,93)-C(94,96) bond length is 1.41 Å. In the sixty-third C site, C(94,96) is bonded in a distorted single-bond geometry to one C(91,92,93); one C(97,98,99); and one H(43,44,45) atom. The C(94,96)-C(97,98,99) bond length is 1.39 Å. The C(94,96)-H(43,44,45) bond length is 1.09 Å. In the sixty-fourth C site, C(95) is bonded in a distorted single-bond geometry to one C(91,92,93); one C(97,98,99); and one H(43,44,45) atom. The C(95)-C(91,92,93) bond length is 1.41 Å. The C(95)-C(97,98,99) bond length is 1.39 Å. The C(95)-H(43,44,45) bond length is 1.09 Å. In the sixty-fifth C site, C(97,98,99) is bonded in a distorted trigonal planar geometry to one C(82); one C(94,96); and one H(46,47,48) atom. The C(97,98,99)-H(46,47,48) bond length is 1.09 Å. In the sixty-sixth C site, C(100) is bonded in a bent 120 degrees geometry to one C(82), one O(19), and one O(22) atom. The C(100)-O(19) bond length is 1.30 Å. The C(100)-O(22) bond length is 1.27 Å. In the sixty-seventh C site, C(101) is bonded in a bent 120 degrees geometry to one C(83,84); one O(20); and one O(23) atom. The C(101)-O(20) bond length is 1.30 Å. The C(101)-O(23) bond length is 1.27 Å. In the sixty-eighth C site, C(102) is bonded in a bent 120 degrees geometry to one C(83,84); one O(21); and one O(24) atom. The C(102)-C(83,84) bond length is 1.48 Å. The C(102)-O(21) bond length is 1.30 Å. The C(102)-O(24) bond length is 1.27 Å. There are thirty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(22,23,24) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(22,23,24) atom. The H(2,3)-C(22,23,24) bond length is 1.09 Å. In the third H site, H(4,5,6) is bonded in a single-bond geometry to one C(25) atom. In the fourth H site, H(7,8,9) is bonded in a single-bond geometry to one C(31) atom. In the fifth H site, H(10,12) is bonded in a single-bond geometry to one C(34,35,36) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(34,35,36) atom. The H(11)-C(34,35,36) bond length is 1.09 Å. In the seventh H site, H(13,14,15) is bonded in a single-bond geometry to one C(43,45) atom. In the eighth H site, H(16,18) is bonded in a single-bond geometry to one C(46,47,48) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(46,47,48) atom. The H(17)-C(46,47,48) bond length is 1.09 Å. In the tenth H site, H(19,20,21) is bonded in a single-bond geometry to one C(52,53,54) atom. In the eleventh H site, H(22,23,24) is bonded in a single-bond geometry to one C(55,57) atom. In the twelfth H site, H(25,26,27) is bonded in a single-bond geometry to one C(64) atom. In the thirteenth H site, H(28,30) is bonded in a single-bond geometry to one C(67,68,69) atom. In the fourteenth H site, H(29) is bonded in a single-bond geometry to one C(67,68,69) atom. The H(29)-C(67,68,69) bond length is 1.09 Å. In the fifteenth H site, H(31,32) is bonded in a single-bond geometry to one C(73,74,75) atom. In the sixteenth H site, H(33) is bonded in a single-bond geometry to one C(73,74,75) atom. The H(33)-C(73,74,75) bond length is 1.09 Å. In the seventeenth H site, H(34,35,36) is bonded in a single-bond geometry to one C(76) atom. In the eighteenth H site, H(37,38,39) is bonded in a single-bond geometry to one C(85,86,87) atom. In the nineteenth H site, H(40,41,42) is bonded in a single-bond geometry to one C(88,90) atom. In the twentieth H site, H(43,44,45) is bonded in a single-bond geometry to one C(94,96) atom. In the twenty-first H site, H(46,47,48) is bonded in a single-bond geometry to one C(97,98,99) atom. In the twenty-second H site, H(49) is bonded in a single-bond geometry to one O(25) atom. The H(49)-O(25) bond length is 0.97 Å. In the twenty-third H site, H(50) is bonded in a single-bond geometry to one O(26) atom. The H(50)-O(26) bond length is 0.97 Å. In the twenty-fourth H site, H(51) is bonded in a single-bond geometry to one O(27) atom. The H(51)-O(27) bond length is 0.97 Å. In the twenty-fifth H site, H(52) is bonded in a single-bond geometry to one O(20) and one O(25) atom. The H(52)-O(20) bond length is 1.69 Å. The H(52)-O(25) bond length is 1.00 Å. In the twenty-sixth H site, H(53) is bonded in a single-bond geometry to one O(21) and one O(26) atom. The H(53)-O(21) bond length is 1.69 Å. The H(53)-O(26) bond length is 1.00 Å. In the twenty-seventh H site, H(54) is bonded in a single-bond geometry to one O(19) and one O(27) atom. The H(54)-O(19) bond length is 1.69 Å. The H(54)-O(27) bond length is 1.00 Å. In the twenty-eighth H site, H(55) is bonded in a single-bond geometry to one O(28) and one O(3) atom. The H(55)-O(28) bond length is 0.99 Å. The H(55)-O(3) bond length is 1.74 Å. In the twenty-ninth H site, H(56) is bonded in a single-bond geometry to one O(1) and one O(29) atom. The H(56)-O(1) bond length is 1.74 Å. The H(56)-O(29) bond length is 0.99 Å. In the thirtieth H site, H(57) is bonded in a single-bond geometry to one O(2) and one O(30) atom. The H(57)-O(2) bond length is 1.74 Å. The H(57)-O(30) bond length is 0.99 Å. In the thirty-first H site, H(58) is bonded in a single-bond geometry to one O(28) atom. The H(58)-O(28) bond length is 0.98 Å. In the thirty-second H site, H(59) is bonded in a single-bond geometry to one O(29) atom. The H(59)-O(29) bond length is 0.98 Å. In the thirty-third H site, H(60) is bonded in a single-bond geometry to one O(30) atom. The H(60)-O(30) bond length is 0.98 Å. There are seven inequivalent S sites. In the first S site, S(1,3) is bonded in an L-shaped geometry to one C(4,5,6) and one C(7) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one C(4,5,6) and one C(8) atom. The S(2)-C(4,5,6) bond length is 1.75 Å. In the third S site, S(4,6) is bonded in an L-shaped geometry to one C(10,11,12) and one C(4,5,6) atom. In the fourth S site, S(5) is bonded in an L-shaped geometry to one C(10,11,12) and one C(4,5,6) atom. The S(5)-C(10,11,12) bond length is 1.75 Å. The S(5)-C(4,5,6) bond length is 1.75 Å. In the fifth S site, S(7,9) is bonded in an L-shaped geometry to one C(1,3) and one C(13,14,15) atom. In the sixth S site, S(8) is bonded in an L-shaped geometry to one C(13,14,15) and one C(2) atom. The S(8)-C(13,14,15) bond length is 1.75 Å. In the seventh S site, S(10,11,12) is bonded in an L-shaped geometry to one C(1,3) and one C(16,18) atom. There are thirty inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mn(4), one C(37), and one H(56) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mn(5), one C(38), and one H(57) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mn(6), one C(39), and one H(55) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mn(3), one Mn(4), and one C(37) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(5), and one C(38) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mn(2), one Mn(6), and one C(39) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mn(6) and one C(58) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mn(4) and one C(59) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Mn(5) and one C(60) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(58) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(59) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(60) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(79) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Mn(2) and one C(80) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Mn(3) and one C(81) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Mn(5) and one C(79) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Mn(6) and one C(80) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Mn(4) and one C(81) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Mn(4), one C(100), and one H(54) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Mn(5), one C(101), and one H(52) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Mn(6), one C(102), and one H(53) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(100) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 120 degrees geometry to one Mn(3) and one C(101) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(102) atom. In the twenty-fifth O site, O(25) is bonded in a water-like geometry to one Mn(1), one H(49), and one H(52) atom. In the twenty-sixth O site, O(26) is bonded in a water-like geometry to one Mn(2), one H(50), and one H(53) atom. In the twenty-seventh O site, O(27) is bonded in a water-like geometry to one Mn(3), one H(51), and one H(54) atom. In the twenty-eighth O site, O(28) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one H(55), and one H(58) atom. In the twenty-ninth O site, O(29) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one H(56), and one H(59) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal non-coplanar geometry to one Mn(3), one H(57), and one H(60) atom. Linkers: 6 [O]C(=O)c1ccc(C2=C(c3ccc(C([O])=O)cc3)SC(=C3SC(c4ccc(C([O])=O)cc4)=C(c4ccc(C([O])=O)cc4)S3)S2)cc1. Metal clusters: 12 [Mn]. The MOF has largest included sphere 5.33 A, density 1.23 g/cm3, surface area 4010.82 m2/g, accessible volume 0.36 cm3/g