CdC15H9(N3O)2CH crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a CdC15H9(N3O)2 framework. In the CdC15H9(N3O)2 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one N(11), one N(3), one N(4), one O(2), one O(3), and one O(4) atom to form distorted corner-sharing CdN3O3 octahedra. The corner-sharing octahedral tilt angles are 66°. The Cd(1)-N(11) bond length is 2.33 Å. The Cd(1)-N(3) bond length is 2.40 Å. The Cd(1)-N(4) bond length is 2.29 Å. The Cd(1)-O(2) bond length is 2.42 Å. The Cd(1)-O(3) bond length is 2.46 Å. The Cd(1)-O(4) bond length is 2.38 Å. In the second Cd site, Cd(2) is bonded to one N(10), one N(2), one N(7), one N(8), one O(1), and one O(2) atom to form distorted corner-sharing CdN4O2 octahedra. The corner-sharing octahedral tilt angles are 66°. The Cd(2)-N(10) bond length is 2.32 Å. The Cd(2)-N(2) bond length is 2.44 Å. The Cd(2)-N(7) bond length is 2.34 Å. The Cd(2)-N(8) bond length is 2.32 Å. The Cd(2)-O(1) bond length is 2.35 Å. The Cd(2)-O(2) bond length is 2.54 Å. There are thirty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(2) atom. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(3), and one O(4) atom. The C(7)-C(8) bond length is 1.50 Å. The C(7)-O(3) bond length is 1.27 Å. The C(7)-O(4) bond length is 1.28 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(5) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(5) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(6) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(6) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one N(2) and one H(7) atom. The C(11)-N(2) bond length is 1.35 Å. The C(11)-H(7) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(4), and one N(7) atom. The C(13)-C(14) bond length is 1.47 Å. The C(13)-N(4) bond length is 1.35 Å. The C(13)-N(7) bond length is 1.35 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(22) atom. The C(14)-C(15) bond length is 1.42 Å. The C(14)-C(22) bond length is 1.38 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one H(9) atom. The C(15)-N(3) bond length is 1.32 Å. The C(15)-H(9) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one C(21), and one N(3) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(21) bond length is 1.43 Å. The C(16)-N(3) bond length is 1.38 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(10) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-H(10) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(11) atom. The C(18)-C(19) bond length is 1.42 Å. The C(18)-H(11) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(12) atom. The C(19)-C(20) bond length is 1.38 Å. The C(19)-H(12) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(13) atom. The C(20)-C(21) bond length is 1.42 Å. The C(20)-H(13) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(22) atom. The C(21)-C(22) bond length is 1.41 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(14), one C(21), and one H(14) atom. The C(22)-H(14) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted trigonal planar geometry to one C(24), one N(12), and one N(9) atom. The C(23)-C(24) bond length is 1.46 Å. The C(23)-N(12) bond length is 1.35 Å. The C(23)-N(9) bond length is 1.35 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(32) atom. The C(24)-C(25) bond length is 1.42 Å. The C(24)-C(32) bond length is 1.38 Å. In the twenty-fifth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one N(8), and one H(15) atom. The C(25)-N(8) bond length is 1.33 Å. The C(25)-H(15) bond length is 1.09 Å. In the twenty-sixth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(27), one C(31), and one N(8) atom. The C(26)-C(27) bond length is 1.41 Å. The C(26)-C(31) bond length is 1.43 Å. The C(26)-N(8) bond length is 1.37 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(16) atom. The C(27)-H(16) bond length is 1.09 Å. In the twenty-eighth C site, C(30) is bonded in a distorted single-bond geometry to one C(31) and one H(19) atom. The C(30)-C(31) bond length is 1.42 Å. The C(30)-H(19) bond length is 1.09 Å. In the twenty-ninth C site, C(31) is bonded in a trigonal planar geometry to one C(26), one C(30), and one C(32) atom. The C(31)-C(32) bond length is 1.41 Å. In the thirtieth C site, C(32) is bonded in a distorted single-bond geometry to one C(24), one C(31), and one H(20) atom. The C(32)-H(20) bond length is 1.09 Å. There are twelve inequivalent N sites. In the first N site, N(11) is bonded in a trigonal planar geometry to one Cd(1), one N(10), and one N(12) atom. The N(11)-N(10) bond length is 1.33 Å. The N(11)-N(12) bond length is 1.33 Å. In the second N site, N(12) is bonded in a distorted water-like geometry to one C(23) and one N(11) atom. In the third N site, N(1) is bonded in a bent 120 degrees geometry to one C(4) and one C(5) atom. In the fourth N site, N(2) is bonded in a trigonal planar geometry to one Cd(2), one C(10), and one C(11) atom. In the fifth N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(15), and one C(16) atom. In the sixth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(13), and one N(5) atom. The N(4)-N(5) bond length is 1.35 Å. In the seventh N site, N(5) is bonded in a water-like geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.31 Å. In the eighth N site, N(6) is bonded in a water-like geometry to one N(5) and one N(7) atom. The N(6)-N(7) bond length is 1.36 Å. In the ninth N site, N(7) is bonded in a 3-coordinate geometry to one Cd(2), one C(13), and one N(6) atom. In the tenth N site, N(8) is bonded in a trigonal planar geometry to one Cd(2), one C(25), and one C(26) atom. In the eleventh N site, N(9) is bonded in a water-like geometry to one C(23) and one N(10) atom. The N(9)-N(10) bond length is 1.33 Å. In the twelfth N site, N(10) is bonded in a trigonal planar geometry to one Cd(2), one N(11), and one N(9) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(30) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(32) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(2) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(1) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(7) atom. Linkers: 1 c1ccc2ncc(C3=N[N]N=N3)cc2c1 ,3 c1ccc2ncc(C3=NN=N[N]3)cc2c1 ,2 [O]C(=O)c1ccncc1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 2.82 A, density 1.74 g/cm3, surface area 3852.29 m2/g, accessible volume 0.14 cm3/g