MoAg2CuC10N4H6(O3F2)2 crystallizes in the monoclinic P2_1/c space group. Mo(1) is bonded to two equivalent O(3), two equivalent F(1), and two equivalent F(2) atoms to form MoO2F4 octahedra that share corners with two equivalent Cu(1)N2O2F2 octahedra. The corner-sharing octahedral tilt angles are 40°. Both Mo(1)-O(3) bond lengths are 1.81 Å. Both Mo(1)-F(1) bond lengths are 1.95 Å. Both Mo(1)-F(2) bond lengths are 1.93 Å. Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one N(2), one O(2), and two equivalent O(3) atoms. The Ag(1)-N(2) bond length is 2.27 Å. The Ag(1)-O(2) bond length is 2.32 Å. There is one shorter (2.35 Å) and one longer (2.54 Å) Ag(1)-O(3) bond length. Cu(1) is bonded to two equivalent N(1), two equivalent O(1), and two equivalent F(1) atoms to form CuN2O2F2 octahedra that share corners with two equivalent Mo(1)O2F4 octahedra. The corner-sharing octahedral tilt angles are 40°. Both Cu(1)-N(1) bond lengths are 1.96 Å. Both Cu(1)-O(1) bond lengths are 1.99 Å. Both Cu(1)-F(1) bond lengths are 2.39 Å. There are five inequivalent C sites. In the first C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(3) bond length is 1.09 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(5)-C(1) bond length is 1.50 Å. The C(5)-O(1) bond length is 1.29 Å. The C(5)-O(2) bond length is 1.26 Å. In the third C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one N(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. In the fourth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(2), and one H(1) atom. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(1) bond length is 1.09 Å. In the fifth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2) atom. The C(3)-N(2) bond length is 1.35 Å. The C(3)-H(2) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(2), and one C(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(5) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Ag(1) and one C(5) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mo(1) and two equivalent Ag(1) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Mo(1) atom. In the second F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Cu(1) atom. Linkers: 4 [O]C(=O)c1cnccn1. Metal clusters: 2 [Cu] ,4 [Ag] ,2 [Mo]. The MOF has largest included sphere 1.66 A, density 2.96 g/cm3, surface area 2235.80 m2/g, accessible volume 0.04 cm3/g