AgC3H3(NO2)2(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a AgC3H3(NO2)2 framework. In the AgC3H3(NO2)2 framework, Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Ag(1)-O(1) bond length is 2.28 Å. The Ag(1)-O(2) bond length is 2.40 Å. The Ag(1)-O(3) bond length is 2.46 Å. The Ag(1)-O(4) bond length is 2.52 Å. There are three inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-H(4) bond length is 1.08 Å. In the second C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(5) atom. The C(5)-N(1) bond length is 1.36 Å. The C(5)-H(5) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(1) atom. The C(1)-N(1) bond length is 1.38 Å. The C(1)-O(1) bond length is 1.29 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(5), and one H(1) atom. The N(1)-H(1) bond length is 1.05 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(4) atom. The N(2)-O(2) bond length is 1.27 Å. The N(2)-O(3) bond length is 1.26 Å. The N(2)-O(4) bond length is 1.27 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one N(1) and one O(1) atom. The H(1)-O(1) bond length is 1.70 Å. In the second H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(5) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one N(2) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one H(1) atom. In the third O site, O(2) is bonded in a distorted water-like geometry to one Ag(1) and one N(2) atom. In the fourth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one N(2) atom. Linkers: 4 [O][N+](=O)[O-]. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.59 A, density 2.45 g/cm3, surface area 3082.15 m2/g, accessible volume 0.06 cm3/g