ZnC15H11(NO2)2(CH)3(C3NH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules; two 1,2-diisopropenylhydrazine molecules; and two ZnC15H11(NO2)2 clusters. In each ZnC15H11(NO2)2 cluster, Zn(1) is bonded in a 5-coordinate geometry to one N(3), one N(4), one O(1), one O(2), and one O(3) atom. The Zn(1)-N(3) bond length is 2.10 Å. The Zn(1)-N(4) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 2.08 Å. The Zn(1)-O(2) bond length is 2.41 Å. The Zn(1)-O(3) bond length is 1.94 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one H(1) atom. The C(1)-C(6) bond length is 1.41 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the third C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.50 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.30 Å. The C(7)-O(2) bond length is 1.26 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(13) and one H(5,8) atom. The C(8)-C(13) bond length is 1.41 Å. The C(8)-H(5,8) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(5,8) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(5,8) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(8) atom. The C(13)-C(14) bond length is 1.50 Å. In the eighth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.31 Å. The C(14)-O(4) bond length is 1.25 Å. In the ninth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one N(4), and one H(9) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-N(4) bond length is 1.35 Å. The C(15)-H(9) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(10) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(10) bond length is 1.09 Å. In the eleventh C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(11) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(11) bond length is 1.09 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(12) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(12) bond length is 1.09 Å. In the thirteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(4), and one H(13) atom. The C(19)-N(4) bond length is 1.35 Å. The C(19)-H(13) bond length is 1.09 Å. In the fourteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(14) atom. The C(20)-N(3) bond length is 1.35 Å. The C(20)-H(14) bond length is 1.09 Å. In the fifteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(18) atom. The C(24)-N(3) bond length is 1.35 Å. The C(24)-H(18) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(20), and one C(24) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(19) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5,8) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Zn(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Zn(1) and one C(7) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(14) atom. Linkers: 2 [O]C(=O)c1ccc([N][N]c2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.21 A, density 1.55 g/cm3, surface area 4858.94 m2/g, accessible volume 0.12 cm3/g