KC8PH9S2O3(CH)2(CH3)3(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four 02329_fluka molecules, six 02329_fluka molecules, and one KC8PH9S2O3 cluster. In the KC8PH9S2O3 cluster, K(1) is bonded in a 3-coordinate geometry to one S(1), two equivalent S(2), one O(1), one O(2), and one O(3) atom. The K(1)-S(1) bond length is 3.20 Å. There is one shorter (3.17 Å) and one longer (3.19 Å) K(1)-S(2) bond length. The K(1)-O(1) bond length is 2.83 Å. The K(1)-O(2) bond length is 2.81 Å. The K(1)-O(3) bond length is 2.65 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one P(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-P(1) bond length is 1.82 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one O(2) atom. The C(4)-O(2) bond length is 1.37 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a tetrahedral geometry to one H(5), one H(6), one H(7), and one O(2) atom. The C(7)-H(5) bond length is 1.10 Å. The C(7)-H(6) bond length is 1.10 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-O(2) bond length is 1.44 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one O(1) atom. The C(8)-O(1) bond length is 1.49 Å. In the seventh C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one H(17), one H(18), and one O(3) atom. The C(12)-H(17) bond length is 1.10 Å. The C(12)-H(18) bond length is 1.10 Å. The C(12)-O(3) bond length is 1.45 Å. In the eighth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one H(23), one H(24), and one O(3) atom. The C(15)-H(23) bond length is 1.10 Å. The C(15)-H(24) bond length is 1.10 Å. The C(15)-O(3) bond length is 1.45 Å. P(1) is bonded in a distorted tetrahedral geometry to one C(1), one S(1), one S(2), and one O(1) atom. The P(1)-S(1) bond length is 1.99 Å. The P(1)-S(2) bond length is 2.00 Å. The P(1)-O(1) bond length is 1.65 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(24) is bonded in a single-bond geometry to one C(15) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted L-shaped geometry to one K(1) and one P(1) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one P(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one K(1), one C(8), and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one K(1), one C(4), and one C(7) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one K(1), one C(12), and one C(15) atom. Linkers: 2 COc1ccc([P]([S])([S])OC(C)(C)C)cc1. Metal clusters: 2 [K]. The MOF has largest included sphere 1.74 A, density 1.39 g/cm3, surface area 4824.08 m2/g, accessible volume 0.10 cm3/g