Zn3C36H20(NO3)4(CH)2 crystallizes in the tetragonal P4_32_12 space group. The structure consists of eight 02329_fluka molecules inside a Zn3C36H20(NO3)4 framework. In the Zn3C36H20(NO3)4 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(1), one N(2), one O(1), one O(3), one O(5), and one O(6) atom to form distorted corner-sharing ZnN2O4 octahedra. The corner-sharing octahedral tilt angles are 77°. The Zn(1)-N(1) bond length is 2.10 Å. The Zn(1)-N(2) bond length is 2.18 Å. The Zn(1)-O(1) bond length is 2.17 Å. The Zn(1)-O(3) bond length is 2.09 Å. The Zn(1)-O(5) bond length is 2.07 Å. The Zn(1)-O(6) bond length is 2.31 Å. In the second Zn site, Zn(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form corner-sharing ZnO6 octahedra. The corner-sharing octahedral tilt angles are 77°. Both Zn(2)-O(1) bond lengths are 2.22 Å. Both Zn(2)-O(2) bond lengths are 2.05 Å. Both Zn(2)-O(4) bond lengths are 2.05 Å. There are eighteen inequivalent C sites. In the first C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(6)-C(1) bond length is 1.40 Å. The C(6)-H(5) bond length is 1.09 Å. In the second C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(2), and one O(3) atom. The C(7)-C(8) bond length is 1.50 Å. The C(7)-O(2) bond length is 1.27 Å. The C(7)-O(3) bond length is 1.27 Å. In the third C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the fourth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(8), one N(1), and one H(6) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-H(6) bond length is 1.09 Å. In the fifth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one N(1) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(13) bond length is 1.48 Å. The C(10)-N(1) bond length is 1.35 Å. In the sixth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(7) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(7) bond length is 1.09 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(8), and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(10), one C(14), and one N(2) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-N(2) bond length is 1.35 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(9) atom. The C(14)-H(9) bond length is 1.09 Å. In the tenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(2), and one H(10) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-N(2) bond length is 1.34 Å. The C(15)-H(10) bond length is 1.09 Å. In the eleventh C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(18) bond length is 1.50 Å. In the twelfth C site, C(1) is bonded in a trigonal planar geometry to one C(19), one C(2), and one C(6) atom. The C(1)-C(19) bond length is 1.50 Å. The C(1)-C(2) bond length is 1.40 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(17)-H(11) bond length is 1.09 Å. In the fourteenth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(1) bond length is 1.09 Å. In the fifteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(4), and one O(5) atom. The C(18)-O(4) bond length is 1.26 Å. The C(18)-O(5) bond length is 1.27 Å. In the sixteenth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(2) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(6) atom. The C(19)-O(1) bond length is 1.30 Å. The C(19)-O(6) bond length is 1.26 Å. In the eighteenth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(15) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(9) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Zn(1), one Zn(2), and one C(19) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(7) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(18) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(18) atom. In the sixth O site, O(6) is bonded in a distorted L-shaped geometry to one Zn(1) and one C(19) atom. Linkers: 8 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cn2)nc1. Metal clusters: 12 [Zn]. The MOF has largest included sphere 4.85 A, density 1.27 g/cm3, surface area 4059.70 m2/g, accessible volume 0.35 cm3/g