DyC31NH19S4O8(CH)2 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a DyC31NH19S4O8 framework. In the DyC31NH19S4O8 framework, Dy(1) is bonded in a 8-coordinate geometry to one N(1), one O(1), one O(3), one O(4), one O(5), one O(6), and two equivalent O(2) atoms. The Dy(1)-N(1) bond length is 2.53 Å. The Dy(1)-O(1) bond length is 2.34 Å. The Dy(1)-O(3) bond length is 2.29 Å. The Dy(1)-O(4) bond length is 2.34 Å. The Dy(1)-O(5) bond length is 2.47 Å. The Dy(1)-O(6) bond length is 2.34 Å. There is one shorter (2.30 Å) and one longer (2.59 Å) Dy(1)-O(2) bond length. There are thirty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(4) atom. The C(2)-C(4) bond length is 1.48 Å. The C(2)-O(2) bond length is 1.29 Å. The C(2)-O(4) bond length is 1.27 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(6) atom. The C(3)-C(5) bond length is 1.42 Å. The C(3)-C(6) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(2) atom. The C(4)-C(10) bond length is 1.42 Å. The C(4)-C(11) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(12), one C(3), and one S(1) atom. The C(5)-C(12) bond length is 1.40 Å. The C(5)-S(1) bond length is 1.78 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(13), one C(3), and one H(1) atom. The C(6)-C(13) bond length is 1.39 Å. The C(6)-H(1) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(5), and one O(6) atom. The C(7)-C(14) bond length is 1.48 Å. The C(7)-O(5) bond length is 1.28 Å. The C(7)-O(6) bond length is 1.28 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(15), one N(1), and one H(2) atom. The C(8)-C(15) bond length is 1.39 Å. The C(8)-N(1) bond length is 1.35 Å. The C(8)-H(2) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(1), and one H(3) atom. The C(9)-C(16) bond length is 1.39 Å. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(3) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(17), one C(4), and one S(2) atom. The C(10)-C(17) bond length is 1.40 Å. The C(10)-S(2) bond length is 1.78 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(11)-H(4) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(5) and one H(5) atom. The C(12)-H(5) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(19), one C(6), and one H(6) atom. The C(13)-C(19) bond length is 1.40 Å. The C(13)-H(6) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(20), one C(21), and one C(7) atom. The C(14)-C(20) bond length is 1.41 Å. The C(14)-C(21) bond length is 1.40 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(22), one C(8), and one H(7) atom. The C(15)-C(22) bond length is 1.40 Å. The C(15)-H(7) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(22), one C(9), and one H(8) atom. The C(16)-C(22) bond length is 1.41 Å. The C(16)-H(8) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(10) and one H(9) atom. The C(17)-H(9) bond length is 1.09 Å. In the eighteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(13) and one H(11,21) atom. The C(19)-H(11,21) bond length is 1.09 Å. In the nineteenth C site, C(20) is bonded in a trigonal planar geometry to one C(14), one C(24), and one S(3) atom. The C(20)-C(24) bond length is 1.40 Å. The C(20)-S(3) bond length is 1.79 Å. In the twentieth C site, C(21) is bonded in a distorted single-bond geometry to one C(14), one C(25), and one H(12) atom. The C(21)-C(25) bond length is 1.39 Å. The C(21)-H(12) bond length is 1.09 Å. In the twenty-first C site, C(22) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(22) atom. The C(22)-C(22) bond length is 1.48 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(20) and one H(14) atom. The C(24)-H(14) bond length is 1.09 Å. In the twenty-third C site, C(25) is bonded in a distorted trigonal planar geometry to one C(21), one C(26), and one H(15) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-H(15) bond length is 1.09 Å. In the twenty-fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(16) atom. The C(26)-H(16) bond length is 1.09 Å. In the twenty-fifth C site, C(27) is bonded in a trigonal planar geometry to one C(28), one C(29), and one S(4) atom. The C(27)-C(28) bond length is 1.42 Å. The C(27)-C(29) bond length is 1.40 Å. The C(27)-S(4) bond length is 1.78 Å. In the twenty-sixth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(30), and one C(31) atom. The C(28)-C(30) bond length is 1.47 Å. The C(28)-C(31) bond length is 1.41 Å. In the twenty-seventh C site, C(29) is bonded in a distorted single-bond geometry to one C(27), one C(32), and one H(17) atom. The C(29)-C(32) bond length is 1.39 Å. The C(29)-H(17) bond length is 1.09 Å. In the twenty-eighth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(7), and one O(8) atom. The C(30)-O(7) bond length is 1.25 Å. The C(30)-O(8) bond length is 1.33 Å. In the twenty-ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(28) and one H(18) atom. The C(31)-H(18) bond length is 1.09 Å. In the thirtieth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(29), one C(33), and one H(19) atom. The C(32)-C(33) bond length is 1.40 Å. The C(32)-H(19) bond length is 1.09 Å. In the thirty-first C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(11,21) atom. The C(33)-H(11,21) bond length is 1.09 Å. N(1) is bonded in a distorted trigonal planar geometry to one Dy(1), one C(8), and one C(9) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(11,21) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(26) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(29) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(31) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(32) atom. In the eighteenth H site, H(20) is bonded in a linear geometry to one O(7) and one O(8) atom. The H(20)-O(7) bond length is 1.61 Å. The H(20)-O(8) bond length is 1.02 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(5) and one S(2) atom. The S(1)-S(2) bond length is 2.05 Å. In the second S site, S(2) is bonded in a distorted water-like geometry to one C(10) and one S(1) atom. In the third S site, S(3) is bonded in a water-like geometry to one C(20) and one S(4) atom. The S(3)-S(4) bond length is 2.07 Å. In the fourth S site, S(4) is bonded in a water-like geometry to one C(27) and one S(3) atom. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Dy(1) and one C(7) atom. In the second O site, O(6) is bonded in a distorted L-shaped geometry to one Dy(1) and one C(7) atom. In the third O site, O(7) is bonded in a bent 120 degrees geometry to one C(30) and one H(20) atom. In the fourth O site, O(8) is bonded in a water-like geometry to one C(30) and one H(20) atom. In the fifth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Dy(1) and one C(1) atom. In the sixth O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Dy(1) and one C(2) atom. In the seventh O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one C(1) atom. In the eighth O site, O(4) is bonded in a distorted water-like geometry to one Dy(1) and one C(2) atom. Linkers: 2 [O]C(=O)c1ccccc1SSc1ccccc1C([O])=O. Metal clusters: 2 [Dy]. The MOF has largest included sphere 3.25 A, density 1.88 g/cm3, surface area 3614.30 m2/g, accessible volume 0.13 cm3/g