CuC12H14(NO2)2(CH)4C7N3H5 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules; four 2,6-bis(methylamino)pyridine molecules; and four CuC12H14(NO2)2 clusters. In each CuC12H14(NO2)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 2.00 Å. Both Cu(1)-O(1) bond lengths are 2.00 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.50 Å. The C(10)-C(12) bond length is 1.34 Å. The C(10)-C(9) bond length is 1.50 Å. In the third C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one H(10), one H(8), and one H(9) atom. The C(11)-H(10) bond length is 1.10 Å. The C(11)-H(8) bond length is 1.10 Å. The C(11)-H(9) bond length is 1.10 Å. In the fourth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(10), one H(11), and one H(12) atom. The C(12)-H(11) bond length is 1.09 Å. The C(12)-H(12) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(5)-N(1) bond length is 1.36 Å. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(1), and one O(2) atom. The C(9)-O(1) bond length is 1.30 Å. The C(9)-O(2) bond length is 1.26 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. There are seven inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(9) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(9) atom. Linkers: 2 c1cc(Nc2ccncc2)nc(Nc2ccncc2)c1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 4.34 A, density 1.24 g/cm3, surface area 5057.35 m2/g, accessible volume 0.32 cm3/g