Na2C13NH11O5(CH)2 crystallizes in the monoclinic P2_1 space group. The structure consists of twelve 02329_fluka molecules inside a Na2C13NH11O5 framework. In the Na2C13NH11O5 framework, there are six inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(2), one O(4), one O(8), and one O(9) atom. The Na(1)-O(1) bond length is 2.50 Å. The Na(1)-O(12) bond length is 2.56 Å. The Na(1)-O(2) bond length is 2.28 Å. The Na(1)-O(4) bond length is 2.55 Å. The Na(1)-O(8) bond length is 2.25 Å. The Na(1)-O(9) bond length is 2.46 Å. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(3), one O(5), one O(7), and one O(9) atom. The Na(2)-O(10) bond length is 2.56 Å. The Na(2)-O(2) bond length is 2.51 Å. The Na(2)-O(3) bond length is 2.27 Å. The Na(2)-O(5) bond length is 2.55 Å. The Na(2)-O(7) bond length is 2.46 Å. The Na(2)-O(9) bond length is 2.25 Å. In the third Na site, Na(3) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(3), one O(6), one O(7), and one O(8) atom. The Na(3)-O(1) bond length is 2.27 Å. The Na(3)-O(11) bond length is 2.56 Å. The Na(3)-O(3) bond length is 2.51 Å. The Na(3)-O(6) bond length is 2.55 Å. The Na(3)-O(7) bond length is 2.25 Å. The Na(3)-O(8) bond length is 2.46 Å. In the fourth Na site, Na(4) is bonded in a trigonal bipyramidal geometry to one O(1), one O(10), one O(13), one O(6), and one O(9) atom. The Na(4)-O(1) bond length is 2.35 Å. The Na(4)-O(10) bond length is 2.29 Å. The Na(4)-O(13) bond length is 2.36 Å. The Na(4)-O(6) bond length is 2.33 Å. The Na(4)-O(9) bond length is 2.37 Å. In the fifth Na site, Na(5) is bonded in a trigonal bipyramidal geometry to one O(11), one O(14), one O(2), one O(4), and one O(7) atom. The Na(5)-O(11) bond length is 2.29 Å. The Na(5)-O(14) bond length is 2.36 Å. The Na(5)-O(2) bond length is 2.35 Å. The Na(5)-O(4) bond length is 2.33 Å. The Na(5)-O(7) bond length is 2.36 Å. In the sixth Na site, Na(6) is bonded in a trigonal bipyramidal geometry to one O(12), one O(15), one O(3), one O(5), and one O(8) atom. The Na(6)-O(12) bond length is 2.28 Å. The Na(6)-O(15) bond length is 2.35 Å. The Na(6)-O(3) bond length is 2.34 Å. The Na(6)-O(5) bond length is 2.33 Å. The Na(6)-O(8) bond length is 2.37 Å. There are twenty-one inequivalent C sites. In the first C site, C(28,29,30) is bonded in a distorted single-bond geometry to one C(31,33) and one H(16,17,18) atom. The C(28,29,30)-C(31,33) bond length is 1.39 Å. The C(28,29,30)-H(16,17,18) bond length is 1.09 Å. In the second C site, C(31,33) is bonded in a trigonal planar geometry to one C(28,29,30); one C(34,35); and one C(7,8,9) atom. The C(31,33)-C(34,35) bond length is 1.51 Å. The C(31,33)-C(7,8,9) bond length is 1.44 Å. In the third C site, C(32) is bonded in a trigonal planar geometry to one C(28,29,30); one C(34,35); and one C(7,8,9) atom. The C(32)-C(28,29,30) bond length is 1.39 Å. The C(32)-C(34,35) bond length is 1.51 Å. The C(32)-C(7,8,9) bond length is 1.44 Å. In the fourth C site, C(34,35) is bonded in a distorted bent 120 degrees geometry to one C(31,33); one O(10); and one O(7) atom. The C(34,35)-O(10) bond length is 1.27 Å. The C(34,35)-O(7) bond length is 1.28 Å. In the fifth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(31,33); one O(12); and one O(9) atom. The C(36)-C(31,33) bond length is 1.51 Å. The C(36)-O(12) bond length is 1.27 Å. The C(36)-O(9) bond length is 1.28 Å. In the sixth C site, C(37,38) is bonded in a trigonal planar geometry to one N(1), one H(19), and one O(13) atom. The C(37,38)-N(1) bond length is 1.34 Å. The C(37,38)-H(19) bond length is 1.11 Å. The C(37,38)-O(13) bond length is 1.25 Å. In the seventh C site, C(39) is bonded in a trigonal planar geometry to one N(3), one H(21), and one O(15) atom. The C(39)-N(3) bond length is 1.34 Å. The C(39)-H(21) bond length is 1.11 Å. The C(39)-O(15) bond length is 1.25 Å. In the eighth C site, C(40,41,42) is bonded to one N(1); one H(22,23); one H(25,26); and one H(28,29) atom to form corner-sharing CH3N tetrahedra. The C(40,41,42)-N(1) bond length is 1.46 Å. The C(40,41,42)-H(22,23) bond length is 1.10 Å. The C(40,41,42)-H(25,26) bond length is 1.10 Å. The C(40,41,42)-H(28,29) bond length is 1.10 Å. In the ninth C site, C(43,44,45) is bonded to one N(1); one H(31,32,33); one H(34,35,36); and one H(37,38,39) atom to form corner-sharing CH3N tetrahedra. The C(43,44,45)-N(1) bond length is 1.45 Å. The C(43,44,45)-H(31,32,33) bond length is 1.10 Å. The C(43,44,45)-H(34,35,36) bond length is 1.09 Å. The C(43,44,45)-H(37,38,39) bond length is 1.10 Å. In the tenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4,6); one O(1); and one O(4) atom. The C(1)-C(4,6) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(4) bond length is 1.26 Å. In the eleventh C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(2), and one O(5) atom. The C(2)-C(5) bond length is 1.51 Å. The C(2)-O(2) bond length is 1.28 Å. The C(2)-O(5) bond length is 1.26 Å. In the twelfth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4,6); one O(3); and one O(6) atom. The C(3)-C(4,6) bond length is 1.51 Å. The C(3)-O(3) bond length is 1.28 Å. The C(3)-O(6) bond length is 1.26 Å. In the thirteenth C site, C(4,6) is bonded in a trigonal planar geometry to one C(1); one C(10,12); and one C(13,14,15) atom. The C(4,6)-C(10,12) bond length is 1.43 Å. The C(4,6)-C(13,14,15) bond length is 1.38 Å. In the fourteenth C site, C(5) is bonded in a trigonal planar geometry to one C(11); one C(13,14,15); and one C(2) atom. The C(5)-C(11) bond length is 1.43 Å. The C(5)-C(13,14,15) bond length is 1.38 Å. In the fifteenth C site, C(7,8,9) is bonded in a trigonal planar geometry to one C(10,12); one C(16,18); and one C(31,33) atom. The C(7,8,9)-C(10,12) bond length is 1.44 Å. The C(7,8,9)-C(16,18) bond length is 1.42 Å. In the sixteenth C site, C(10,12) is bonded in a trigonal planar geometry to one C(19,20,21); one C(4,6); and one C(7,8,9) atom. The C(10,12)-C(19,20,21) bond length is 1.42 Å. In the seventeenth C site, C(11) is bonded in a trigonal planar geometry to one C(19,20,21); one C(5); and one C(7,8,9) atom. The C(11)-C(19,20,21) bond length is 1.42 Å. The C(11)-C(7,8,9) bond length is 1.44 Å. In the eighteenth C site, C(13,14,15) is bonded in a distorted single-bond geometry to one C(4,6) and one H(1,2,3) atom. The C(13,14,15)-H(1,2,3) bond length is 1.09 Å. In the nineteenth C site, C(16,18) is bonded in a distorted single-bond geometry to one C(7,8,9) and one H(4,5,6) atom. The C(16,18)-H(4,5,6) bond length is 1.09 Å. In the twentieth C site, C(17) is bonded in a distorted single-bond geometry to one C(7,8,9) and one H(4,5,6) atom. The C(17)-C(7,8,9) bond length is 1.42 Å. The C(17)-H(4,5,6) bond length is 1.09 Å. In the twenty-first C site, C(19,20,21) is bonded in a distorted single-bond geometry to one C(10,12) and one H(7,8,9) atom. The C(19,20,21)-H(7,8,9) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(37,38); one C(40,41,42); and one C(43,44,45) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(37,38); one C(40,41,42); and one C(43,44,45) atom. The N(2)-C(37,38) bond length is 1.34 Å. The N(2)-C(40,41,42) bond length is 1.46 Å. The N(2)-C(43,44,45) bond length is 1.45 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(39); one C(40,41,42); and one C(43,44,45) atom. The N(3)-C(40,41,42) bond length is 1.46 Å. The N(3)-C(43,44,45) bond length is 1.45 Å. There are sixteen inequivalent H sites. In the first H site, H(1,2,3) is bonded in a single-bond geometry to one C(13,14,15) atom. In the second H site, H(4,5,6) is bonded in a single-bond geometry to one C(16,18) atom. In the third H site, H(7,8,9) is bonded in a single-bond geometry to one C(19,20,21) atom. In the fourth H site, H(16,17,18) is bonded in a single-bond geometry to one C(28,29,30) atom. In the fifth H site, H(19) is bonded in a single-bond geometry to one C(37,38) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one C(37,38) atom. The H(20)-C(37,38) bond length is 1.11 Å. In the seventh H site, H(21) is bonded in a single-bond geometry to one C(39) atom. In the eighth H site, H(22,23) is bonded in a single-bond geometry to one C(40,41,42) atom. In the ninth H site, H(24) is bonded in a single-bond geometry to one C(40,41,42) atom. The H(24)-C(40,41,42) bond length is 1.10 Å. In the tenth H site, H(25,26) is bonded in a single-bond geometry to one C(40,41,42) atom. In the eleventh H site, H(27) is bonded in a single-bond geometry to one C(40,41,42) atom. The H(27)-C(40,41,42) bond length is 1.10 Å. In the twelfth H site, H(28,29) is bonded in a single-bond geometry to one C(40,41,42) atom. In the thirteenth H site, H(30) is bonded in a single-bond geometry to one C(40,41,42) atom. The H(30)-C(40,41,42) bond length is 1.10 Å. In the fourteenth H site, H(31,32,33) is bonded in a single-bond geometry to one C(43,44,45) atom. In the fifteenth H site, H(34,35,36) is bonded in a single-bond geometry to one C(43,44,45) atom. In the sixteenth H site, H(37,38,39) is bonded in a single-bond geometry to one C(43,44,45) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), one Na(3), one Na(4), and one C(1) atom to form a mixture of distorted edge and corner-sharing ONa3C trigonal pyramids. In the second O site, O(2) is bonded to one Na(1), one Na(2), one Na(5), and one C(2) atom to form a mixture of distorted edge and corner-sharing ONa3C trigonal pyramids. In the third O site, O(3) is bonded to one Na(2), one Na(3), one Na(6), and one C(3) atom to form a mixture of distorted edge and corner-sharing ONa3C trigonal pyramids. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(1), one Na(5), and one C(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(2), one Na(6), and one C(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(3), one Na(4), and one C(3) atom. In the seventh O site, O(7) is bonded to one Na(2); one Na(3); one Na(5); and one C(34,35) atom to form a mixture of distorted edge and corner-sharing ONa3C trigonal pyramids. In the eighth O site, O(8) is bonded to one Na(1); one Na(3); one Na(6); and one C(34,35) atom to form a mixture of distorted edge and corner-sharing ONa3C trigonal pyramids. The O(8)-C(34,35) bond length is 1.28 Å. In the ninth O site, O(9) is bonded to one Na(1), one Na(2), one Na(4), and one C(36) atom to form a mixture of distorted edge and corner-sharing ONa3C trigonal pyramids. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Na(2); one Na(4); and one C(34,35) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Na(3); one Na(5); and one C(34,35) atom. The O(11)-C(34,35) bond length is 1.27 Å. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Na(1), one Na(6), and one C(36) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Na(4) and one C(37,38) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Na(5) and one C(37,38) atom. The O(14)-C(37,38) bond length is 1.25 Å. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Na(6) and one C(39) atom. Linkers: 6 [O]C(=O)c1ccc(C([O])=O)c2ccccc12. Metal clusters: 12 [Na]. The MOF has largest included sphere 5.20 A, density 1.36 g/cm3, surface area 4379.60 m2/g, accessible volume 0.20 cm3/g