Cu2C14N7H9S2 crystallizes in the triclinic P-1 space group. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 4-coordinate geometry to one N(2), one N(3), and two equivalent S(1) atoms. The Cu(1)-N(2) bond length is 1.89 Å. The Cu(1)-N(3) bond length is 1.98 Å. There is one shorter (2.37 Å) and one longer (2.50 Å) Cu(1)-S(1) bond length. In the second Cu site, Cu(2) is bonded in a 4-coordinate geometry to one N(1), one N(4), and two equivalent S(2) atoms. The Cu(2)-N(1) bond length is 1.88 Å. The Cu(2)-N(4) bond length is 1.98 Å. There is one shorter (2.37 Å) and one longer (2.51 Å) Cu(2)-S(2) bond length. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.63 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2) and one S(2) atom. The C(2)-N(2) bond length is 1.18 Å. The C(2)-S(2) bond length is 1.63 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(5), one N(3), and one H(2) atom. The C(3)-C(5) bond length is 1.39 Å. The C(3)-N(3) bond length is 1.35 Å. The C(3)-H(2) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(6), one N(4), and one H(3) atom. The C(4)-C(6) bond length is 1.39 Å. The C(4)-N(4) bond length is 1.35 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3); one C(7); and one H(4,5) atom. The C(5)-C(7) bond length is 1.40 Å. The C(5)-H(4,5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4); one C(8); and one H(4,5) atom. The C(6)-C(8) bond length is 1.40 Å. The C(6)-H(4,5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(13,14); one C(5); and one C(9) atom. The C(7)-C(13,14) bond length is 1.45 Å. The C(7)-C(9) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10); one C(13,14); and one C(6) atom. The C(8)-C(10) bond length is 1.41 Å. The C(8)-C(13,14) bond length is 1.45 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(11), one C(7), and one H(6) atom. The C(9)-C(11) bond length is 1.38 Å. The C(9)-H(6) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(7) atom. The C(10)-C(12) bond length is 1.38 Å. The C(10)-H(7) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(9), one N(3), and one H(8) atom. The C(11)-N(3) bond length is 1.36 Å. The C(11)-H(8) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(10), one N(4), and one H(9) atom. The C(12)-N(4) bond length is 1.36 Å. The C(12)-H(9) bond length is 1.09 Å. In the thirteenth C site, C(13,14) is bonded in a distorted trigonal planar geometry to one C(7); one N(5,6); and one N(7) atom. The C(13,14)-N(5,6) bond length is 1.34 Å. The C(13,14)-N(7) bond length is 1.37 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted linear geometry to one Cu(2) and one C(1) atom. In the second N site, N(2) is bonded in a distorted linear geometry to one Cu(1) and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(12), and one C(4) atom. In the fifth N site, N(5,6) is bonded in a distorted water-like geometry to one C(13,14) and one N(5,6) atom. The N(5,6)-N(5,6) bond length is 1.36 Å. In the sixth N site, N(7) is bonded in a trigonal planar geometry to two equivalent C(13,14) and one H(1) atom. The N(7)-H(1) bond length is 1.02 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4,5) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cu(1) and one C(1) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cu(2) and one C(2) atom. Linkers: 2 c1cc(-c2nnc(-c3ccncc3)[nH]2)ccn1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 1.33 A, density 2.15 g/cm3, surface area 3447.31 m2/g, accessible volume 0.10 cm3/g