CdC7NH6O5C4N2H4S3 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 7653-69-2 molecules inside a CdC7NH6O5 framework. In the CdC7NH6O5 framework, Cd(1) is bonded in a 7-coordinate geometry to one N(3), one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms. The Cd(1)-N(3) bond length is 2.31 Å. The Cd(1)-O(1) bond length is 2.53 Å. The Cd(1)-O(2) bond length is 2.40 Å. The Cd(1)-O(3) bond length is 2.42 Å. The Cd(1)-O(5) bond length is 2.26 Å. There is one shorter (2.36 Å) and one longer (2.68 Å) Cd(1)-O(4) bond length. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(6)-O(3) bond length is 1.27 Å. The C(6)-O(4) bond length is 1.26 Å. In the third C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(3), and one H(5) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-N(3) bond length is 1.34 Å. The C(7)-H(5) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(6) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-H(6) bond length is 1.09 Å. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(8), and one C(9) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(9) bond length is 1.48 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(7) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(7) bond length is 1.09 Å. In the seventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(3), and one H(8) atom. The C(11)-N(3) bond length is 1.34 Å. The C(11)-H(8) bond length is 1.09 Å. N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(7) atom. There are six inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(9) is bonded in a linear geometry to one O(3) and one O(5) atom. The H(9)-O(3) bond length is 1.59 Å. The H(9)-O(5) bond length is 1.00 Å. In the sixth H site, H(10) is bonded in a distorted linear geometry to one O(1) and one O(5) atom. The H(10)-O(1) bond length is 1.61 Å. The H(10)-O(5) bond length is 1.01 Å. There are five inequivalent O sites. In the first O site, O(5) is bonded in a distorted water-like geometry to one Cd(1), one H(10), and one H(9) atom. In the second O site, O(1) is bonded in a 3-coordinate geometry to one Cd(1), one C(1), and one H(10) atom. In the third O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one Cd(1), one C(6), and one H(9) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(6) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1 ,4 [O]C(=O)CSc1nnc(SCC([O])=O)s1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 1.88 A, density 2.07 g/cm3, surface area 3620.72 m2/g, accessible volume 0.10 cm3/g