AgC24H21(N3O)3(CH)3 crystallizes in the monoclinic P2_1 space group. The structure consists of six 02329_fluka molecules inside a AgC24H21(N3O)3 framework. In each AgC24H21(N3O)3 framework, Ag(1) is bonded in a trigonal bipyramidal geometry to one N(4), one N(5), one N(6), one N(7), and one N(9) atom. The Ag(1)-N(4) bond length is 2.32 Å. The Ag(1)-N(5) bond length is 2.32 Å. The Ag(1)-N(6) bond length is 2.32 Å. The Ag(1)-N(7) bond length is 2.60 Å. The Ag(1)-N(9) bond length is 2.60 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(1)-C(4) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.49 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(8) atom. The C(2)-C(4) bond length is 1.40 Å. The C(2)-C(5) bond length is 1.39 Å. The C(2)-C(8) bond length is 1.49 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(9) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.39 Å. The C(3)-C(9) bond length is 1.49 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(1), one C(2), and one H(4) atom. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(2), one C(3), and one H(5) atom. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(6) atom. The C(6)-H(6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one O(1) atom. The C(7)-N(1) bond length is 1.35 Å. The C(7)-O(1) bond length is 1.25 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(2); one N(2); and one O(2,3) atom. The C(8)-N(2) bond length is 1.35 Å. The C(8)-O(2,3) bond length is 1.25 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(3); one N(3); and one O(2,3) atom. The C(9)-N(3) bond length is 1.35 Å. The C(9)-O(2,3) bond length is 1.25 Å. In the tenth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(16), one N(1), one H(10), and one H(7) atom. The C(10)-C(16) bond length is 1.51 Å. The C(10)-N(1) bond length is 1.46 Å. The C(10)-H(10) bond length is 1.10 Å. The C(10)-H(7) bond length is 1.10 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one C(17), one N(2), one H(11), and one H(8) atom. The C(11)-C(17) bond length is 1.51 Å. The C(11)-N(2) bond length is 1.46 Å. The C(11)-H(11) bond length is 1.10 Å. The C(11)-H(8) bond length is 1.10 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(18), one N(3), one H(12), and one H(9) atom. The C(12)-C(18) bond length is 1.51 Å. The C(12)-N(3) bond length is 1.46 Å. The C(12)-H(12) bond length is 1.10 Å. The C(12)-H(9) bond length is 1.10 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(16); one N(4); and one H(13,14) atom. The C(13)-C(16) bond length is 1.40 Å. The C(13)-N(4) bond length is 1.35 Å. The C(13)-H(13,14) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(17); one N(5); and one H(13,14) atom. The C(14)-C(17) bond length is 1.40 Å. The C(14)-N(5) bond length is 1.35 Å. The C(14)-H(13,14) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(18), one N(6), and one H(15) atom. The C(15)-C(18) bond length is 1.40 Å. The C(15)-N(6) bond length is 1.35 Å. The C(15)-H(15) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(19) atom. The C(16)-C(19) bond length is 1.40 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(20) atom. The C(17)-C(20) bond length is 1.40 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(12), one C(15), and one C(21) atom. The C(18)-C(21) bond length is 1.40 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(16) and one H(16,17) atom. The C(19)-H(16,17) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(17) and one H(16,17) atom. The C(20)-H(16,17) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(18) and one H(18) atom. The C(21)-H(18) bond length is 1.09 Å. In the twenty-second C site, C(25) is bonded in a distorted trigonal planar geometry to one N(4) and one H(22,23,24) atom. The C(25)-N(4) bond length is 1.35 Å. The C(25)-H(22,23,24) bond length is 1.09 Å. In the twenty-third C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(22,23,24) atom. The C(26)-N(5) bond length is 1.35 Å. The C(26)-H(22,23,24) bond length is 1.09 Å. In the twenty-fourth C site, C(27) is bonded in a distorted trigonal planar geometry to one N(6) and one H(22,23,24) atom. The C(27)-N(6) bond length is 1.35 Å. The C(27)-H(22,23,24) bond length is 1.09 Å. There are nine inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(10); one C(7); and one H(1,3) atom. The N(1)-H(1,3) bond length is 1.03 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(8), and one H(2) atom. The N(2)-H(2) bond length is 1.03 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(12); one C(9); and one H(1,3) atom. The N(3)-H(1,3) bond length is 1.03 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(13), and one C(25) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(14), and one C(26) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(15), and one C(27) atom. In the seventh N site, N(7) is bonded in a linear geometry to one Ag(1) and one N(8) atom. The N(7)-N(8) bond length is 1.19 Å. In the eighth N site, N(8) is bonded in a linear geometry to one N(7) and one N(9) atom. The N(8)-N(9) bond length is 1.19 Å. In the ninth N site, N(9) is bonded in a linear geometry to one Ag(1) and one N(8) atom. There are sixteen inequivalent H sites. In the first H site, H(1,3) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(13,14) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the fourteenth H site, H(16,17) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(21) atom. In the sixteenth H site, H(22,23,24) is bonded in a single-bond geometry to one C(25) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(7) atom. In the second O site, O(2,3) is bonded in a single-bond geometry to one C(8) atom. Linkers: 2 [N][N][N]. Metal clusters: 2 [Ag]. The MOF has largest included sphere 2.03 A, density 1.66 g/cm3, surface area 4423.82 m2/g, accessible volume 0.14 cm3/g