Ag2C5H3(SO4)2CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a Ag2C5H3(SO4)2 framework. In the Ag2C5H3(SO4)2 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one O(7), two equivalent O(1), and two equivalent O(5) atoms. The Ag(1)-O(7) bond length is 2.69 Å. There is one shorter (2.42 Å) and one longer (2.49 Å) Ag(1)-O(1) bond length. There is one shorter (2.39 Å) and one longer (2.42 Å) Ag(1)-O(5) bond length. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one O(8), two equivalent O(2), and two equivalent O(6) atoms. The Ag(2)-O(8) bond length is 2.69 Å. There is one shorter (2.42 Å) and one longer (2.49 Å) Ag(2)-O(2) bond length. There is one shorter (2.40 Å) and one longer (2.42 Å) Ag(2)-O(6) bond length. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(3), and one H(3) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(3) bond length is 1.39 Å. The C(1)-H(3) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(4), and one S(1) atom. The C(2)-C(4) bond length is 1.41 Å. The C(2)-S(1) bond length is 1.77 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(5), and one S(2) atom. The C(3)-C(5) bond length is 1.41 Å. The C(3)-S(2) bond length is 1.77 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one O(7) atom. The C(4)-O(7) bond length is 1.35 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one O(8) atom. The C(5)-O(8) bond length is 1.35 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(3) and one O(7) atom. The H(1)-O(3) bond length is 1.64 Å. The H(1)-O(7) bond length is 1.00 Å. In the second H site, H(2) is bonded in a distorted linear geometry to one O(4) and one O(8) atom. The H(2)-O(4) bond length is 1.64 Å. The H(2)-O(8) bond length is 1.00 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one O(1), one O(3), and one O(5) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.46 Å. The S(1)-O(5) bond length is 1.49 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one O(2), one O(4), and one O(6) atom. The S(2)-O(2) bond length is 1.48 Å. The S(2)-O(4) bond length is 1.46 Å. The S(2)-O(6) bond length is 1.49 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(2) and one S(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one H(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one H(2) and one S(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to two equivalent Ag(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to two equivalent Ag(2) and one S(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one C(4), and one H(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Ag(2), one C(5), and one H(2) atom. Linkers: 2 [O]S([O])([O])c1cc(S([O])([O])[O])c(O)cc1O. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.42 A, density 3.27 g/cm3, surface area 1999.65 m2/g, accessible volume 0.02 cm3/g