CuC37H23(NO2)4(CH)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and one CuC37H23(NO2)4 cluster. In the CuC37H23(NO2)4 cluster, Cu(1) is bonded to one N(2), one N(3), one O(2), and two equivalent O(1) atoms to form distorted edge-sharing CuN2O3 square pyramids. The Cu(1)-N(2) bond length is 2.01 Å. The Cu(1)-N(3) bond length is 2.00 Å. The Cu(1)-O(2) bond length is 1.98 Å. There is one shorter (1.99 Å) and one longer (2.44 Å) Cu(1)-O(1) bond length. There are thirty-seven inequivalent C sites. In the first C site, C(39) is bonded in a distorted trigonal planar geometry to one C(27), one C(36), and one H(25) atom. The C(39)-C(27) bond length is 1.40 Å. The C(39)-C(36) bond length is 1.39 Å. The C(39)-H(25) bond length is 1.09 Å. In the second C site, C(40) is bonded in a distorted single-bond geometry to one C(26) and one H(26) atom. The C(40)-C(26) bond length is 1.42 Å. The C(40)-H(26) bond length is 1.09 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(1), and one O(4) atom. The C(1)-C(13) bond length is 1.47 Å. The C(1)-N(1) bond length is 1.40 Å. The C(1)-O(4) bond length is 1.24 Å. In the fourth C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one C(27), one N(4), one H(1), and one H(2) atom. The C(2)-C(27) bond length is 1.51 Å. The C(2)-N(4) bond length is 1.46 Å. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. In the fifth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(3)-O(1) bond length is 1.31 Å. The C(3)-O(3) bond length is 1.25 Å. In the sixth C site, C(4) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(23) atom. The C(4)-C(10) bond length is 1.42 Å. The C(4)-C(13) bond length is 1.42 Å. The C(4)-C(23) bond length is 1.43 Å. In the seventh C site, C(5) is bonded in a distorted single-bond geometry to one C(9) and one H(3) atom. The C(5)-C(9) bond length is 1.34 Å. The C(5)-H(3) bond length is 1.09 Å. In the eighth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(17), and one C(20) atom. The C(6)-C(11) bond length is 1.50 Å. The C(6)-C(17) bond length is 1.40 Å. The C(6)-C(20) bond length is 1.40 Å. In the ninth C site, C(7) is bonded in a distorted single-bond geometry to one C(10), one C(25), and one H(4) atom. The C(7)-C(10) bond length is 1.39 Å. The C(7)-C(25) bond length is 1.41 Å. The C(7)-H(4) bond length is 1.09 Å. In the tenth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(26), and one C(33) atom. The C(8)-C(12) bond length is 1.42 Å. The C(8)-C(26) bond length is 1.43 Å. The C(8)-C(33) bond length is 1.42 Å. In the eleventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(24), one C(5), and one H(5) atom. The C(9)-C(24) bond length is 1.49 Å. The C(9)-H(5) bond length is 1.09 Å. In the twelfth C site, C(10) is bonded in a trigonal planar geometry to one C(15), one C(4), and one C(7) atom. The C(10)-C(15) bond length is 1.47 Å. In the thirteenth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one N(1), one H(6), and one H(7) atom. The C(11)-N(1) bond length is 1.47 Å. The C(11)-H(6) bond length is 1.10 Å. The C(11)-H(7) bond length is 1.09 Å. In the fourteenth C site, C(12) is bonded in a trigonal planar geometry to one C(30), one C(31), and one C(8) atom. The C(12)-C(30) bond length is 1.47 Å. The C(12)-C(31) bond length is 1.39 Å. In the fifteenth C site, C(13) is bonded in a trigonal planar geometry to one C(1), one C(21), and one C(4) atom. The C(13)-C(21) bond length is 1.39 Å. In the sixteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(33), one N(4), and one O(7) atom. The C(14)-C(33) bond length is 1.48 Å. The C(14)-N(4) bond length is 1.41 Å. The C(14)-O(7) bond length is 1.23 Å. In the seventeenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(1), and one O(5) atom. The C(15)-N(1) bond length is 1.40 Å. The C(15)-O(5) bond length is 1.24 Å. In the eighteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one N(3), and one H(8) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-N(3) bond length is 1.34 Å. The C(16)-H(8) bond length is 1.09 Å. In the nineteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(6), and one H(9) atom. The C(17)-H(9) bond length is 1.09 Å. In the twentieth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(18)-N(2) bond length is 1.34 Å. The C(18)-H(10) bond length is 1.09 Å. In the twenty-first C site, C(19) is bonded in a distorted single-bond geometry to one C(33) and one H(11) atom. The C(19)-C(33) bond length is 1.39 Å. The C(19)-H(11) bond length is 1.09 Å. In the twenty-second C site, C(20) is bonded in a distorted trigonal planar geometry to one C(28), one C(6), and one H(12) atom. The C(20)-C(28) bond length is 1.39 Å. The C(20)-H(12) bond length is 1.09 Å. In the twenty-third C site, C(21) is bonded in a distorted single-bond geometry to one C(13) and one H(13) atom. The C(21)-H(13) bond length is 1.09 Å. In the twenty-fourth C site, C(22) is bonded in a distorted single-bond geometry to one C(26) and one H(14) atom. The C(22)-C(26) bond length is 1.42 Å. The C(22)-H(14) bond length is 1.09 Å. In the twenty-fifth C site, C(23) is bonded in a trigonal planar geometry to one C(34), one C(35), and one C(4) atom. The C(23)-C(34) bond length is 1.42 Å. The C(23)-C(35) bond length is 1.42 Å. In the twenty-sixth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(2), and one O(6) atom. The C(24)-O(2) bond length is 1.30 Å. The C(24)-O(6) bond length is 1.25 Å. In the twenty-seventh C site, C(25) is bonded in a distorted trigonal planar geometry to one C(35), one C(7), and one H(15) atom. The C(25)-C(35) bond length is 1.39 Å. The C(25)-H(15) bond length is 1.09 Å. In the twenty-eighth C site, C(26) is bonded in a trigonal planar geometry to one C(22), one C(40), and one C(8) atom. In the twenty-ninth C site, C(27) is bonded in a trigonal planar geometry to one C(2), one C(32), and one C(39) atom. The C(27)-C(32) bond length is 1.40 Å. In the thirtieth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(3), and one H(16) atom. The C(28)-N(3) bond length is 1.34 Å. The C(28)-H(16) bond length is 1.09 Å. In the thirty-first C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(4), and one O(8) atom. The C(30)-N(4) bond length is 1.40 Å. The C(30)-O(8) bond length is 1.24 Å. In the thirty-second C site, C(31) is bonded in a distorted single-bond geometry to one C(12) and one H(18) atom. The C(31)-H(18) bond length is 1.09 Å. In the thirty-third C site, C(32) is bonded in a distorted single-bond geometry to one C(27) and one H(19) atom. The C(32)-H(19) bond length is 1.09 Å. In the thirty-fourth C site, C(33) is bonded in a trigonal planar geometry to one C(14), one C(19), and one C(8) atom. In the thirty-fifth C site, C(34) is bonded in a distorted single-bond geometry to one C(23) and one H(20) atom. The C(34)-H(20) bond length is 1.09 Å. In the thirty-sixth C site, C(35) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(21) atom. The C(35)-H(21) bond length is 1.09 Å. In the thirty-seventh C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(39), one N(2), and one H(22) atom. The C(36)-N(2) bond length is 1.35 Å. The C(36)-H(22) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(15) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(18), and one C(36) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(16), and one C(28) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(30) atom. There are twenty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(28) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(31) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(32) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(34) atom. In the twentieth H site, H(21) is bonded in a single-bond geometry to one C(35) atom. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one C(36) atom. In the twenty-second H site, H(25) is bonded in a single-bond geometry to one C(39) atom. In the twenty-third H site, H(26) is bonded in a single-bond geometry to one C(40) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Cu(1) and one C(3) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cu(1) and one C(24) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(15) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(24) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(14) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(30) atom. Linkers: 2 [O]C(=O)/C=C/C([O])=O. Metal clusters: 2 [Cu]. The MOF has largest included sphere 5.37 A, density 1.24 g/cm3, surface area 4615.27 m2/g, accessible volume 0.33 cm3/g