(H7(C2N)3)2CdC24N12H28(O4Cl)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ampyzine molecules and one CdC24N12H28(O4Cl)2 cluster. In the CdC24N12H28(O4Cl)2 cluster, Cd(1) is bonded to two equivalent N(1), two equivalent N(7), and two equivalent O(1) atoms to form CdN4O2 octahedra that share corners with two equivalent Cl(1)O4 tetrahedra. Both Cd(1)-N(1) bond lengths are 2.37 Å. Both Cd(1)-N(7) bond lengths are 2.36 Å. Both Cd(1)-O(1) bond lengths are 2.44 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(2), and one H(2) atom. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one N(3) atom. The C(3)-C(4) bond length is 1.42 Å. The C(3)-N(2) bond length is 1.35 Å. The C(3)-N(3) bond length is 1.37 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(3) atom. The C(4)-N(1) bond length is 1.33 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(4), and one H(5) atom. The C(5)-N(3) bond length is 1.45 Å. The C(5)-H(4) bond length is 1.11 Å. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(10), and one H(11) atom. The C(8)-N(3) bond length is 1.46 Å. The C(8)-H(10) bond length is 1.09 Å. The C(8)-H(11) bond length is 1.11 Å. In the seventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(7), and one H(15) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-N(7) bond length is 1.35 Å. The C(13)-H(15) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(8), and one H(16) atom. The C(14)-N(8) bond length is 1.34 Å. The C(14)-H(16) bond length is 1.09 Å. In the ninth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one N(8), and one N(9) atom. The C(15)-C(16) bond length is 1.42 Å. The C(15)-N(8) bond length is 1.35 Å. The C(15)-N(9) bond length is 1.36 Å. In the tenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one N(7), and one H(17) atom. The C(16)-N(7) bond length is 1.33 Å. The C(16)-H(17) bond length is 1.09 Å. In the eleventh C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one N(9), one H(18), and one H(19) atom. The C(17)-N(9) bond length is 1.46 Å. The C(17)-H(18) bond length is 1.09 Å. The C(17)-H(19) bond length is 1.10 Å. In the twelfth C site, C(18) is bonded in a distorted trigonal non-coplanar geometry to one N(9), one H(20), and one H(21) atom. The C(18)-N(9) bond length is 1.46 Å. The C(18)-H(20) bond length is 1.10 Å. The C(18)-H(21) bond length is 1.10 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(16) atom. In the fifth N site, N(8) is bonded in a bent 120 degrees geometry to one C(14) and one C(15) atom. In the sixth N site, N(9) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Cd(1) and one Cl(1) atom. The O(1)-Cl(1) bond length is 1.49 Å. In the second O site, O(2) is bonded in a single-bond geometry to one Cl(1) atom. The O(2)-Cl(1) bond length is 1.47 Å. In the third O site, O(3) is bonded in a single-bond geometry to one Cl(1) atom. The O(3)-Cl(1) bond length is 1.45 Å. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cl(1) atom. The O(4)-Cl(1) bond length is 1.45 Å. Cl(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form ClO4 tetrahedra that share  a cornercorner with one Cd(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 38°. Linkers: 1 c1cnc(N2CCN(c3cnccn3)CC2)cn1 ,2 [N][C](C=[N])N1CCN(c2cnccn2)CC1. Metal clusters: 1 [Cd]. The MOF has largest included sphere 1.98 A, density 1.72 g/cm3, surface area 4386.82 m2/g, accessible volume 0.09 cm3/g