SrC16H8(NO2)4(CH)4(CH3CO)2 crystallizes in the tetragonal I4_1/a space group. The structure consists of thirty-two 02329_fluka molecules and sixteen dimethyl ether molecules inside a SrC16H8(NO2)4 framework. In the SrC16H8(NO2)4 framework, Sr(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent O(4), and four equivalent O(2) atoms. Both Sr(1)-N(1) bond lengths are 2.74 Å. Both Sr(1)-O(4) bond lengths are 2.50 Å. There are two shorter (2.55 Å) and two longer (2.78 Å) Sr(1)-O(2) bond lengths. There are eight inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(2) bond length is 1.09 Å. In the second C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.46 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one N(2) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-N(2) bond length is 1.37 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(10), one C(9), and one N(2) atom. The C(7)-C(10) bond length is 1.48 Å. The C(7)-C(9) bond length is 1.39 Å. The C(7)-N(2) bond length is 1.37 Å. In the sixth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(11), one C(7), and one N(1) atom. The C(9)-C(11) bond length is 1.48 Å. The C(9)-N(1) bond length is 1.38 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(2), and one O(3) atom. The C(10)-O(2) bond length is 1.26 Å. The C(10)-O(3) bond length is 1.28 Å. In the eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(4), and one O(5) atom. The C(11)-O(4) bond length is 1.25 Å. The C(11)-O(5) bond length is 1.31 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one Sr(1), one C(6), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(6), one C(7), and one H(8) atom. The N(2)-H(8) bond length is 1.04 Å. There are four inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(8) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(9) is bonded in a linear geometry to one O(3) and one O(5) atom. The H(9)-O(3) bond length is 1.42 Å. The H(9)-O(5) bond length is 1.07 Å. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one C(10) atom. In the second O site, O(3) is bonded in a water-like geometry to one C(10) and one H(9) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Sr(1) and one C(11) atom. In the fourth O site, O(5) is bonded in a water-like geometry to one C(11) and one H(9) atom. Linkers: 6 COc1cccc(-c2nc(C(=O)O)c(C([O])=O)[nH]2)c1. Metal clusters: 4 [Sr]. The MOF has largest included sphere 3.10 A, density 1.65 g/cm3, surface area 4195.08 m2/g, accessible volume 0.14 cm3/g