MnC14H14S2(N2O3)2 is Indium structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one MnC14H14S2(N2O3)2 cluster. Mn(1) is bonded in a distorted octahedral geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(5) atom. The Mn(1)-N(1) bond length is 2.24 Å. The Mn(1)-N(2) bond length is 2.24 Å. The Mn(1)-O(1) bond length is 2.23 Å. The Mn(1)-O(2) bond length is 2.29 Å. The Mn(1)-O(3) bond length is 2.11 Å. The Mn(1)-O(5) bond length is 2.18 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-C(4) bond length is 1.45 Å. The C(1)-N(1) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one H(9), and one S(1) atom. The C(2)-H(9) bond length is 1.09 Å. The C(2)-S(1) bond length is 1.72 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1), one N(3), and one S(1) atom. The C(3)-N(1) bond length is 1.32 Å. The C(3)-N(3) bond length is 1.36 Å. The C(3)-S(1) bond length is 1.75 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one N(2) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-N(2) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one H(10), and one S(2) atom. The C(5)-H(10) bond length is 1.08 Å. The C(5)-S(2) bond length is 1.73 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one N(2), one N(4), and one S(2) atom. The C(6)-N(2) bond length is 1.33 Å. The C(6)-N(4) bond length is 1.34 Å. The C(6)-S(2) bond length is 1.75 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(3), and one O(4) atom. The C(7)-C(8) bond length is 1.50 Å. The C(7)-O(3) bond length is 1.28 Å. The C(7)-O(4) bond length is 1.28 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(11) atom. The C(9)-H(11) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(12) atom. The C(10)-H(12) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(5), and one O(6) atom. The C(11)-C(12) bond length is 1.49 Å. The C(11)-O(5) bond length is 1.29 Å. The C(11)-O(6) bond length is 1.27 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(14) bond length is 1.40 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(13) atom. The C(13)-H(13) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(14) atom. The C(14)-H(14) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(1), one C(4), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal non-coplanar geometry to one C(3), one H(5), and one H(6) atom. The N(3)-H(5) bond length is 1.03 Å. The N(3)-H(6) bond length is 1.02 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(6), one H(7), and one H(8) atom. The N(4)-H(7) bond length is 1.02 Å. The N(4)-H(8) bond length is 1.03 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. In the second H site, H(2) is bonded in a distorted linear geometry to one O(1) and one O(4) atom. The H(2)-O(1) bond length is 1.02 Å. The H(2)-O(4) bond length is 1.61 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(2) and one O(6) atom. The H(3)-O(2) bond length is 1.03 Å. The H(3)-O(6) bond length is 1.58 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.97 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(2) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(2) and one C(3) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one C(5) and one C(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Mn(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Mn(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(7) and one H(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(11) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one C(11) and one H(3) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 O.O.O=[C]O[Mn]O[C]=O. The MOF has largest included sphere 2.93 A, density 1.66 g/cm3, surface area 4009.58 m2/g, accessible volume 0.14 cm3/g