(CuC44N6H30O5)2CuC44H32(NO)6 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CuC44H32(NO)6 cluster and two CuC44N6H30O5 clusters. In the CuC44H32(NO)6 cluster, Cu(2) is bonded in a distorted octahedral geometry to two equivalent N(7), two equivalent O(3), and two equivalent O(8) atoms. Both Cu(2)-N(7) bond lengths are 2.00 Å. Both Cu(2)-O(3) bond lengths are 2.03 Å. Both Cu(2)-O(8) bond lengths are 2.52 Å. There are twenty-two inequivalent C sites. In the first C site, C(33) is bonded in a distorted single-bond geometry to one C(34) and one H(21) atom. The C(33)-C(34) bond length is 1.40 Å. The C(33)-H(21) bond length is 1.09 Å. In the second C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(36) atom. The C(34)-C(35) bond length is 1.50 Å. The C(34)-C(36) bond length is 1.40 Å. In the third C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(34), one O(3), and one O(4) atom. The C(35)-O(3) bond length is 1.28 Å. The C(35)-O(4) bond length is 1.27 Å. In the fourth C site, C(36) is bonded in a distorted single-bond geometry to one C(34) and one H(22) atom. The C(36)-H(22) bond length is 1.09 Å. In the fifth C site, C(45) is bonded in a distorted single-bond geometry to one C(49) and one H(29) atom. The C(45)-C(49) bond length is 1.40 Å. The C(45)-H(29) bond length is 1.09 Å. In the sixth C site, C(46) is bonded in a distorted trigonal planar geometry to one N(7) and one H(30) atom. The C(46)-N(7) bond length is 1.35 Å. The C(46)-H(30) bond length is 1.09 Å. In the seventh C site, C(47) is bonded in a distorted trigonal planar geometry to one C(48), one N(7), and one H(31) atom. The C(47)-C(48) bond length is 1.39 Å. The C(47)-N(7) bond length is 1.35 Å. The C(47)-H(31) bond length is 1.09 Å. In the eighth C site, C(48) is bonded in a distorted single-bond geometry to one C(47), one C(49), and one H(32) atom. The C(48)-C(49) bond length is 1.40 Å. The C(48)-H(32) bond length is 1.09 Å. In the ninth C site, C(49) is bonded in a trigonal planar geometry to one C(45), one C(48), and one C(50) atom. The C(49)-C(50) bond length is 1.48 Å. In the tenth C site, C(50) is bonded in a distorted trigonal planar geometry to one C(49), one C(51), and one N(8) atom. The C(50)-C(51) bond length is 1.40 Å. The C(50)-N(8) bond length is 1.35 Å. In the eleventh C site, C(51) is bonded in a distorted single-bond geometry to one C(50), one C(52), and one H(33) atom. The C(51)-C(52) bond length is 1.40 Å. The C(51)-H(33) bond length is 1.09 Å. In the twelfth C site, C(52) is bonded in a trigonal planar geometry to one C(51), one C(53), and one C(60) atom. The C(52)-C(53) bond length is 1.47 Å. The C(52)-C(60) bond length is 1.40 Å. In the thirteenth C site, C(53) is bonded in a trigonal planar geometry to one C(52), one C(54), and one C(59) atom. The C(53)-C(54) bond length is 1.40 Å. The C(53)-C(59) bond length is 1.40 Å. In the fourteenth C site, C(54) is bonded in a distorted single-bond geometry to one C(53) and one H(20,34,37) atom. The C(54)-H(20,34,37) bond length is 1.09 Å. In the fifteenth C site, C(59) is bonded in a distorted single-bond geometry to one C(53) and one H(20,34,37) atom. The C(59)-H(20,34,37) bond length is 1.09 Å. In the sixteenth C site, C(60) is bonded in a distorted single-bond geometry to one C(52), one C(61), and one H(38) atom. The C(60)-C(61) bond length is 1.40 Å. The C(60)-H(38) bond length is 1.09 Å. In the seventeenth C site, C(61) is bonded in a distorted trigonal planar geometry to one C(60), one C(62), and one N(8) atom. The C(61)-C(62) bond length is 1.48 Å. The C(61)-N(8) bond length is 1.35 Å. In the eighteenth C site, C(62) is bonded in a trigonal planar geometry to one C(61), one C(63), and one C(66) atom. The C(62)-C(63) bond length is 1.40 Å. The C(62)-C(66) bond length is 1.40 Å. In the nineteenth C site, C(63) is bonded in a distorted single-bond geometry to one C(62) and one H(39) atom. The C(63)-H(39) bond length is 1.09 Å. In the twentieth C site, C(64) is bonded in a distorted trigonal planar geometry to one N(9) and one H(40) atom. The C(64)-N(9) bond length is 1.35 Å. The C(64)-H(40) bond length is 1.09 Å. In the twenty-first C site, C(65) is bonded in a distorted trigonal planar geometry to one C(66), one N(9), and one H(41) atom. The C(65)-C(66) bond length is 1.39 Å. The C(65)-N(9) bond length is 1.34 Å. The C(65)-H(41) bond length is 1.09 Å. In the twenty-second C site, C(66) is bonded in a distorted single-bond geometry to one C(62), one C(65), and one H(42) atom. The C(66)-H(42) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(7) is bonded in a trigonal planar geometry to one Cu(2), one C(46), and one C(47) atom. In the second N site, N(8) is bonded in a bent 120 degrees geometry to one C(50) and one C(61) atom. In the third N site, N(9) is bonded in a bent 120 degrees geometry to one C(64) and one C(65) atom. There are fifteen inequivalent H sites. In the first H site, H(20,34,37) is bonded in a single-bond geometry to one C(32) atom. The H(20,34,37)-C(32) bond length is 1.09 Å. In the second H site, H(21) is bonded in a single-bond geometry to one C(33) atom. In the third H site, H(22) is bonded in a single-bond geometry to one C(36) atom. In the fourth H site, H(29) is bonded in a single-bond geometry to one C(45) atom. In the fifth H site, H(30) is bonded in a single-bond geometry to one C(46) atom. In the sixth H site, H(31) is bonded in a single-bond geometry to one C(47) atom. In the seventh H site, H(32) is bonded in a single-bond geometry to one C(48) atom. In the eighth H site, H(33) is bonded in a single-bond geometry to one C(51) atom. In the ninth H site, H(38) is bonded in a single-bond geometry to one C(60) atom. In the tenth H site, H(39) is bonded in a single-bond geometry to one C(63) atom. In the eleventh H site, H(40) is bonded in a single-bond geometry to one C(64) atom. In the twelfth H site, H(41) is bonded in a single-bond geometry to one C(65) atom. In the thirteenth H site, H(42) is bonded in a single-bond geometry to one C(66) atom. In the fourteenth H site, H(45) is bonded in a single-bond geometry to one O(8) atom. The H(45)-O(8) bond length is 1.00 Å. In the fifteenth H site, H(46) is bonded in a single-bond geometry to one O(8) atom. The H(46)-O(8) bond length is 0.99 Å. There are three inequivalent O sites. In the first O site, O(8) is bonded in a water-like geometry to one Cu(2), one H(45), and one H(46) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(35) atom. In the third O site, O(4) is bonded in a distorted single-bond geometry to one C(35) atom. In each CuC44N6H30O5 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one N(4), one O(1), one O(5), and one O(7) atom. The Cu(1)-N(1) bond length is 2.01 Å. The Cu(1)-N(4) bond length is 2.00 Å. The Cu(1)-O(1) bond length is 2.02 Å. The Cu(1)-O(5) bond length is 1.97 Å. The Cu(1)-O(7) bond length is 2.35 Å. There are forty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(5) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one H(2) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.48 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-N(2) bond length is 1.34 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(16), one C(7), and one C(9) atom. The C(8)-C(16) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.48 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(15), and one C(8) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(15) bond length is 1.40 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(10)-H(6) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(7) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(7) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.51 Å. The C(12)-C(14) bond length is 1.40 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(5), and one O(6) atom. The C(13)-O(5) bond length is 1.31 Å. The C(13)-O(6) bond length is 1.24 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(8) atom. The C(14)-H(8) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(9) and one H(9) atom. The C(15)-H(9) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17), one C(8), and one H(10) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(10) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one N(2) atom. The C(17)-C(18) bond length is 1.49 Å. The C(17)-N(2) bond length is 1.34 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(22) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(22) bond length is 1.40 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(11) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(11) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one N(3), and one H(12) atom. The C(20)-N(3) bond length is 1.34 Å. The C(20)-H(12) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one N(3), and one H(13) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-N(3) bond length is 1.34 Å. The C(21)-H(13) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(18), one C(21), and one H(14) atom. The C(22)-H(14) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(24), one C(27), and one H(15) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-C(27) bond length is 1.40 Å. The C(23)-H(15) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one N(4), and one H(16) atom. The C(24)-N(4) bond length is 1.35 Å. The C(24)-H(16) bond length is 1.09 Å. In the twenty-fifth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one N(4), and one H(17) atom. The C(25)-C(26) bond length is 1.38 Å. The C(25)-N(4) bond length is 1.35 Å. The C(25)-H(17) bond length is 1.09 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(25), one C(27), and one H(18) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-H(18) bond length is 1.09 Å. In the twenty-seventh C site, C(27) is bonded in a trigonal planar geometry to one C(23), one C(26), and one C(28) atom. The C(27)-C(28) bond length is 1.48 Å. In the twenty-eighth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one C(29), and one N(5) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-N(5) bond length is 1.34 Å. In the twenty-ninth C site, C(29) is bonded in a distorted single-bond geometry to one C(28), one C(30), and one H(19) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-H(19) bond length is 1.09 Å. In the thirtieth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(38) atom. The C(30)-C(31) bond length is 1.48 Å. The C(30)-C(38) bond length is 1.40 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(37) atom. The C(31)-C(32) bond length is 1.40 Å. The C(31)-C(37) bond length is 1.40 Å. In the thirty-second C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(20,34,37) atom. In the thirty-third C site, C(37) is bonded in a distorted single-bond geometry to one C(31) and one H(23) atom. The C(37)-H(23) bond length is 1.09 Å. In the thirty-fourth C site, C(38) is bonded in a distorted single-bond geometry to one C(30), one C(39), and one H(24) atom. The C(38)-C(39) bond length is 1.40 Å. The C(38)-H(24) bond length is 1.09 Å. In the thirty-fifth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(38), one C(40), and one N(5) atom. The C(39)-C(40) bond length is 1.48 Å. The C(39)-N(5) bond length is 1.34 Å. In the thirty-sixth C site, C(40) is bonded in a trigonal planar geometry to one C(39), one C(41), and one C(44) atom. The C(40)-C(41) bond length is 1.40 Å. The C(40)-C(44) bond length is 1.40 Å. In the thirty-seventh C site, C(41) is bonded in a distorted single-bond geometry to one C(40), one C(42), and one H(25) atom. The C(41)-C(42) bond length is 1.39 Å. The C(41)-H(25) bond length is 1.09 Å. In the thirty-eighth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(41), one N(6), and one H(26) atom. The C(42)-N(6) bond length is 1.34 Å. The C(42)-H(26) bond length is 1.09 Å. In the thirty-ninth C site, C(43) is bonded in a distorted trigonal planar geometry to one C(44), one N(6), and one H(27) atom. The C(43)-C(44) bond length is 1.40 Å. The C(43)-N(6) bond length is 1.34 Å. The C(43)-H(27) bond length is 1.09 Å. In the fortieth C site, C(44) is bonded in a distorted single-bond geometry to one C(40), one C(43), and one H(28) atom. The C(44)-H(28) bond length is 1.09 Å. In the forty-first C site, C(55) is bonded in a distorted single-bond geometry to one C(56) and one H(35) atom. The C(55)-C(56) bond length is 1.40 Å. The C(55)-H(35) bond length is 1.09 Å. In the forty-second C site, C(56) is bonded in a trigonal planar geometry to one C(55), one C(57), and one C(58) atom. The C(56)-C(57) bond length is 1.50 Å. The C(56)-C(58) bond length is 1.40 Å. In the forty-third C site, C(57) is bonded in a distorted bent 120 degrees geometry to one C(56), one O(1), and one O(2) atom. The C(57)-O(1) bond length is 1.29 Å. The C(57)-O(2) bond length is 1.27 Å. In the forty-fourth C site, C(58) is bonded in a distorted single-bond geometry to one C(56) and one H(36) atom. The C(58)-H(36) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(17) and one C(6) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(20) and one C(21) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(24), and one C(25) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(28) and one C(39) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one C(42) and one C(43) atom. There are thirty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the twentieth H site, H(20,34,37) is bonded in a single-bond geometry to one C(32) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(37) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(38) atom. In the twenty-third H site, H(25) is bonded in a single-bond geometry to one C(41) atom. In the twenty-fourth H site, H(26) is bonded in a single-bond geometry to one C(42) atom. In the twenty-fifth H site, H(27) is bonded in a single-bond geometry to one C(43) atom. In the twenty-sixth H site, H(28) is bonded in a single-bond geometry to one C(44) atom. In the twenty-seventh H site, H(35) is bonded in a single-bond geometry to one C(55) atom. In the twenty-eighth H site, H(36) is bonded in a single-bond geometry to one C(58) atom. In the twenty-ninth H site, H(43) is bonded in a single-bond geometry to one O(7) atom. The H(43)-O(7) bond length is 0.99 Å. In the thirtieth H site, H(44) is bonded in a distorted single-bond geometry to one O(2) and one O(7) atom. The H(44)-O(2) bond length is 1.64 Å. The H(44)-O(7) bond length is 1.00 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(57) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one C(57) and one H(44) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(13) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(13) atom. In the fifth O site, O(7) is bonded in a water-like geometry to one Cu(1), one H(43), and one H(44) atom. Linkers: 1 O.O.[C]/[C]=C\[C]([C])c1[c][c]nc(C2=C[CH]N([Cu@]3(OC(=O)c4ccc(-c5cc(C([CH])=[CH])nc(-c6c[c]ncc6)c5)cc4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N(C=C4)[Cu@@](OC(=O)c4ccc(-c5cc(-c6ccncc6)nc(-c6ccncc6)c5)cc4)(N4[CH]C=C(c5cc(-c6ccc(C([O])=O)cc6)cc(-c6ccncc6)n5)C=C4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N3C=C4)C=C2)c1 ,1 O.O.[CH]C(=[CH])c1cc(-c2ccc(C(=O)O[Cu@@]3(N4[CH]C=C(c5cc(-c6c[c][c]cc6)cc(-c6ccncc6)n5)C=C4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N(C=C4)[Cu@@](OC(=O)c4ccc(-c5cc(-c6ccncc6)nc(-c6ccncc6)c5)cc4)(N4[CH]C=C(c5cc(-c6ccc(C([O])=O)cc6)cc(-c6ccncc6)n5)C=C4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N3C=C4)cc2)cc(-c2c[c]ncc2)n1 ,1 O.O.[C]/[C]=C\[C]([C])c1[c][c]nc(C2=C[CH]N([Cu@]3(OC(=O)c4ccc(-c5cc(-c6c[c]ncc6)nc(-c6ccncc6)c5)cc4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N(C=C4)[Cu@@](OC(=O)c4ccc(-c5cc(C([CH])=[CH])nc(-c6ccncc6)c5)cc4)(N4[CH]C=C(c5cc(-c6ccc(C([O])=O)cc6)cc(-c6ccncc6)n5)C=C4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N3C=C4)C=C2)c1 ,1 O.[C]/C(=N\C(=[CH])c1ccncc1)C1=C[CH]N([Cu@@](OC(=O)c2ccc([C])cc2)(OC(=O)c2ccc(-c3cc(-c4ccncc4)nc(-c4ccncc4)c3)cc2)N2[CH]C=C(c3cc(-c4ccc(C([O])=O)cc4)cc(-c4ccncc4)n3)C=C2)C=C1 ,1 O.O.[CH]C(=[CH])c1cc(-c2ccc(C(=O)O[Cu@@]3(N4[CH]C=C(c5cc(-c6ccc(C([O])=O)cc6)cc(-c6ccncc6)n5)C=C4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N(C=C4)[Cu@@](OC(=O)c4ccc(-c5cc(-c6c[c]ncc6)nc(-c6ccncc6)c5)cc4)(N4[CH]C=C(c5cc(-c6c[c][c]cc6)cc(-c6ccncc6)n5)C=C4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N3C=C4)cc2)cc(-c2ccncc2)n1 ,1 O.O.[CH]C(=[CH])c1cc(-c2ccc(C(=O)O[Cu@]3(N4[CH]C=C(c5cc(-c6ccc(C([O])=O)cc6)cc(-c6ccncc6)n5)C=C4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N(C=C4)[Cu@](OC(=O)c4ccc(-c5cc(-c6c[c]ncc6)nc(-c6ccncc6)c5)cc4)(N4[CH]C=C(c5cc(-c6c[c][c]cc6)cc(-c6ccncc6)n5)C=C4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N3C=C4)cc2)cc(-c2ccncc2)n1 ,1 O.O.[C]/[C]=C\[C]([C])c1[c][c]nc(C2=C[CH]N([Cu@@]3(OC(=O)c4ccc(-c5cc(-c6c[c]ncc6)nc(-c6ccncc6)c5)cc4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N(C=C4)[Cu@](OC(=O)c4ccc(-c5cc(C([CH])=[CH])nc(-c6ccncc6)c5)cc4)(N4[CH]C=C(c5cc(-c6ccc(C([O])=O)cc6)cc(-c6ccncc6)n5)C=C4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N3C=C4)C=C2)c1 ,1 O.O.[CH]C(=[CH])c1cc(-c2ccc(C(=O)O[Cu@]3(N4[CH]C=C(c5cc(-c6c[c][c]cc6)cc(-c6ccncc6)n5)C=C4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N(C=C4)[Cu@](OC(=O)c4ccc(-c5cc(-c6ccncc6)nc(-c6ccncc6)c5)cc4)(N4[CH]C=C(c5cc(-c6ccc(C([O])=O)cc6)cc(-c6ccncc6)n5)C=C4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N3C=C4)cc2)cc(-c2c[c]ncc2)n1 ,1 O.O.[C]/[C]=C\[C]([C])c1[c][c]nc(C2=C[CH]N([Cu@@]3(OC(=O)c4ccc(-c5cc(C([CH])=[CH])nc(-c6c[c]ncc6)c5)cc4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N(C=C4)[Cu@](OC(=O)c4ccc(-c5cc(-c6ccncc6)nc(-c6ccncc6)c5)cc4)(N4[CH]C=C(c5cc(-c6ccc(C([O])=O)cc6)cc(-c6ccncc6)n5)C=C4)OC(=O)c4ccc(cc4)-c4cc(nc(-c5ccncc5)c4)C4=C[CH]N3C=C4)C=C2)c1 ,1 O.[C]/C(=N\C(=[CH])c1ccncc1)C1=C[CH]N([Cu@](OC(=O)c2ccc([C])cc2)(OC(=O)c2ccc(-c3cc(-c4ccncc4)nc(-c4ccncc4)c3)cc2)N2[CH]C=C(c3cc(-c4ccc(C([O])=O)cc4)cc(-c4ccncc4)n3)C=C2)C=C1. Metal clusters: 1 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 3.92 A, density 1.44 g/cm3, surface area 4692.57 m2/g, accessible volume 0.14 cm3/g