Mn3C16H8(NO6)2(CH2)4 crystallizes in the triclinic P1 space group. The structure consists of four 02329_fluka molecules inside a Mn3C16H8(NO6)2 framework. In the Mn3C16H8(NO6)2 framework, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(7), and one O(8) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles are 66°. The Mn(1)-O(1) bond length is 2.09 Å. The Mn(1)-O(11) bond length is 2.15 Å. The Mn(1)-O(12) bond length is 2.14 Å. The Mn(1)-O(2) bond length is 2.10 Å. The Mn(1)-O(7) bond length is 2.19 Å. The Mn(1)-O(8) bond length is 2.17 Å. In the second Mn site, Mn(2) is bonded to one N(1), one O(10), one O(3), one O(5), one O(8), and one O(9) atom to form distorted MnNO5 octahedra that share  a cornercorner with one Mn(1)O6 octahedra and  an edgeedge with one Mn(3)NO5 octahedra. The corner-sharing octahedral tilt angles are 66°. The Mn(2)-N(1) bond length is 2.28 Å. The Mn(2)-O(10) bond length is 2.21 Å. The Mn(2)-O(3) bond length is 2.12 Å. The Mn(2)-O(5) bond length is 2.12 Å. The Mn(2)-O(8) bond length is 2.23 Å. The Mn(2)-O(9) bond length is 2.24 Å. In the third Mn site, Mn(3) is bonded to one N(2), one O(10), one O(4), one O(6), one O(7), and one O(9) atom to form distorted MnNO5 octahedra that share  a cornercorner with one Mn(1)O6 octahedra and  an edgeedge with one Mn(2)NO5 octahedra. The corner-sharing octahedral tilt angles are 66°. The Mn(3)-N(2) bond length is 2.28 Å. The Mn(3)-O(10) bond length is 2.24 Å. The Mn(3)-O(4) bond length is 2.13 Å. The Mn(3)-O(6) bond length is 2.12 Å. The Mn(3)-O(7) bond length is 2.24 Å. The Mn(3)-O(9) bond length is 2.21 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(4) atom. The C(2)-C(4) bond length is 1.50 Å. The C(2)-O(2) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.27 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(5) atom. The C(3)-C(11) bond length is 1.40 Å. The C(3)-C(5) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(2), and one C(6) atom. The C(4)-C(12) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3); one C(7); and one H(1,2) atom. The C(5)-C(7) bond length is 1.38 Å. The C(5)-H(1,2) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4); one C(8); and one H(1,2) atom. The C(6)-C(8) bond length is 1.39 Å. The C(6)-H(1,2) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(3) atom. The C(7)-N(1) bond length is 1.35 Å. The C(7)-H(3) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(6), one N(2), and one H(4) atom. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(4) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one H(5) atom. The C(9)-C(11) bond length is 1.39 Å. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(5) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(6) atom. The C(10)-C(12) bond length is 1.39 Å. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(6) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(3), one C(9), and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(10), one C(4), and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(7) atom. The C(13)-O(5) bond length is 1.26 Å. The C(13)-O(7) bond length is 1.30 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(8) atom. The C(14)-O(6) bond length is 1.26 Å. The C(14)-O(8) bond length is 1.30 Å. In the fifteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(9) atom. The C(19)-O(11) bond length is 1.26 Å. The C(19)-O(9) bond length is 1.29 Å. In the sixteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(12) atom. The C(20)-O(10) bond length is 1.29 Å. The C(20)-O(12) bond length is 1.26 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(2), one C(7), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(3), one C(10), and one C(8) atom. There are seven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(12) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mn(2) and one C(13) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mn(3) and one C(14) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Mn(3), and one C(13) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Mn(2), and one C(14) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one C(19) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one C(20) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(19) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(20) atom. Linkers: 2 [O]C(=O)CCC([O])=O ,2 [O]C(=O)c1ccncc1. Metal clusters: 3 [Mn]. The MOF has largest included sphere 1.92 A, density 1.97 g/cm3, surface area 3230.34 m2/g, accessible volume 0.09 cm3/g