CuC12H16(N7O3)2(CH2)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one CuC12H16(N7O3)2 cluster. In the CuC12H16(N7O3)2 cluster, Cu(1) is bonded in an octahedral geometry to one N(1), one N(12), one N(6), one N(7), one O(1), and one O(4) atom. The Cu(1)-N(1) bond length is 2.02 Å. The Cu(1)-N(12) bond length is 2.00 Å. The Cu(1)-N(6) bond length is 2.00 Å. The Cu(1)-N(7) bond length is 2.02 Å. The Cu(1)-O(1) bond length is 2.49 Å. The Cu(1)-O(4) bond length is 2.48 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(2) atom. The C(2)-N(1) bond length is 1.37 Å. The C(2)-N(3) bond length is 1.33 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(3), and one H(4) atom. The C(3)-N(2) bond length is 1.46 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(4) bond length is 1.10 Å. In the fourth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(7), and one H(8) atom. The C(5)-N(4) bond length is 1.46 Å. The C(5)-H(7) bond length is 1.10 Å. The C(5)-H(8) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(9) atom. The C(6)-N(4) bond length is 1.34 Å. The C(6)-N(6) bond length is 1.34 Å. The C(6)-H(9) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(10) atom. The C(7)-N(5) bond length is 1.33 Å. The C(7)-N(6) bond length is 1.37 Å. The C(7)-H(10) bond length is 1.08 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(11) atom. The C(8)-N(7) bond length is 1.34 Å. The C(8)-N(8) bond length is 1.34 Å. The C(8)-H(11) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(12) atom. The C(9)-N(7) bond length is 1.37 Å. The C(9)-N(9) bond length is 1.33 Å. The C(9)-H(12) bond length is 1.08 Å. In the ninth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(8), one H(13), and one H(14) atom. The C(10)-N(8) bond length is 1.46 Å. The C(10)-H(13) bond length is 1.10 Å. The C(10)-H(14) bond length is 1.10 Å. In the tenth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one N(10), one H(17), and one H(18) atom. The C(12)-N(10) bond length is 1.46 Å. The C(12)-H(17) bond length is 1.10 Å. The C(12)-H(18) bond length is 1.10 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(19) atom. The C(13)-N(10) bond length is 1.34 Å. The C(13)-N(12) bond length is 1.34 Å. The C(13)-H(19) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(20) atom. The C(14)-N(11) bond length is 1.33 Å. The C(14)-N(12) bond length is 1.37 Å. The C(14)-H(20) bond length is 1.08 Å. There are fourteen inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(3) atom. The N(2)-N(3) bond length is 1.36 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(2) and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(5), one C(6), and one N(5) atom. The N(4)-N(5) bond length is 1.36 Å. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(7) and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(6), and one C(7) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Cu(1), one C(8), and one C(9) atom. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(9) atom. The N(8)-N(9) bond length is 1.36 Å. In the ninth N site, N(9) is bonded in a distorted water-like geometry to one C(9) and one N(8) atom. In the tenth N site, N(10) is bonded in a distorted trigonal planar geometry to one C(12), one C(13), and one N(11) atom. The N(10)-N(11) bond length is 1.36 Å. In the eleventh N site, N(11) is bonded in a distorted water-like geometry to one C(14) and one N(10) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(14) atom. In the thirteenth N site, N(13) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(13)-O(1) bond length is 1.28 Å. The N(13)-O(2) bond length is 1.26 Å. The N(13)-O(3) bond length is 1.27 Å. In the fourteenth N site, N(14) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. The N(14)-O(4) bond length is 1.28 Å. The N(14)-O(5) bond length is 1.26 Å. The N(14)-O(6) bond length is 1.27 Å. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(12) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(12) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(13) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(14) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one N(13) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(13) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(13) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one N(14) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(14) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(14) atom. Linkers: 1 [c]1ncn(CCCN2[CH]N=C[N]2)n1 ,2 [CH]1N=C[N]N1CCCn1cncn1 ,1 [c]1ncn(CCCn2cncn2)n1. Metal clusters: 1 [Cu]. The MOF has largest included sphere 1.65 A, density 1.73 g/cm3, surface area 4552.21 m2/g, accessible volume 0.12 cm3/g