CoC6H4(N2O)2(CF)2 crystallizes in the trigonal R3m space group. The structure consists of thirty-six fluoromethane molecules inside a CoC6H4(N2O)2 framework. In the CoC6H4(N2O)2 framework, Co(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Co(1)-N(1) bond length is 1.99 Å. The Co(1)-N(2) bond length is 1.99 Å. The Co(1)-N(3) bond length is 1.98 Å. The Co(1)-N(4) bond length is 1.98 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(4), and one O(1) atom. The C(1)-N(1) bond length is 1.38 Å. The C(1)-N(4) bond length is 1.39 Å. The C(1)-O(1) bond length is 1.25 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to two equivalent N(2) and one O(2) atom. Both C(3)-N(2) bond lengths are 1.39 Å. The C(3)-O(2) bond length is 1.25 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2) atom. The C(4)-N(2) bond length is 1.34 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to two equivalent N(3) and one O(3) atom. Both C(5)-N(3) bond lengths are 1.38 Å. The C(5)-O(3) bond length is 1.25 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(3) atom. The C(6)-N(3) bond length is 1.34 Å. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(4) atom. The C(7)-N(4) bond length is 1.34 Å. The C(7)-H(4) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(5), and one C(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(7) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(5) atom. Linkers: 12 O=C1N=C[C](F)C=N1. Metal clusters: 6 [Co]. The MOF has largest included sphere 5.32 A, density 1.50 g/cm3, surface area 3795.33 m2/g, accessible volume 0.25 cm3/g