(CH)3CuC16H14S2(N3O)2C3NH2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two 2-nitropropene molecules, and two CuC16H14S2(N3O)2 clusters. In one of the CuC16H14S2(N3O)2 clusters, Cu(1) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent N(3) atoms. Both Cu(1)-N(2) bond lengths are 1.93 Å. Both Cu(1)-N(3) bond lengths are 2.04 Å. There are eight inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one N(2) and one S(2) atom. The C(2)-N(2) bond length is 1.19 Å. The C(2)-S(2) bond length is 1.61 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one C(7), and one N(4) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(7) bond length is 1.40 Å. The C(3)-N(4) bond length is 1.40 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one N(3), and one H(2) atom. The C(4)-N(3) bond length is 1.33 Å. The C(4)-H(2) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(3), and one H(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(3) bond length is 1.34 Å. The C(5)-H(3) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(7)-H(5) bond length is 1.08 Å. In the seventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(4), and one O(1) atom. The C(13)-C(14) bond length is 1.51 Å. The C(13)-N(4) bond length is 1.38 Å. The C(13)-O(1) bond length is 1.24 Å. In the eighth C site, C(14) is bonded in a distorted water-like geometry to one C(13), one H(11), and one H(12) atom. The C(14)-H(11) bond length is 1.10 Å. The C(14)-H(12) bond length is 1.10 Å. There are three inequivalent N sites. In the first N site, N(2) is bonded in a bent 150 degrees geometry to one Cu(1) and one C(2) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(4), and one C(5) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one C(13), one C(3), and one H(1) atom. The N(4)-H(1) bond length is 1.02 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(14) atom. S(2) is bonded in a distorted single-bond geometry to one C(2) atom. O(1) is bonded in a single-bond geometry to one C(13) atom. In one of the CuC16H14S2(N3O)2 clusters, Cu(2) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(5) atoms. Both Cu(2)-N(1) bond lengths are 1.92 Å. Both Cu(2)-N(5) bond lengths are 2.07 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.19 Å. The C(1)-S(1) bond length is 1.61 Å. In the second C site, C(8) is bonded in a distorted trigonal planar geometry to one C(12), one C(9), and one N(6) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. The C(8)-N(6) bond length is 1.40 Å. In the third C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(5), and one H(7) atom. The C(9)-N(5) bond length is 1.34 Å. The C(9)-H(7) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one N(5), and one H(8) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-N(5) bond length is 1.34 Å. The C(10)-H(8) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(9) atom. The C(11)-H(9) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(8) and one H(10) atom. The C(12)-H(10) bond length is 1.09 Å. In the seventh C site, C(15) is bonded in a distorted water-like geometry to one C(16), one H(13), and one H(14) atom. The C(15)-C(16) bond length is 1.52 Å. The C(15)-H(13) bond length is 1.10 Å. The C(15)-H(14) bond length is 1.10 Å. In the eighth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one N(6), and one O(2) atom. The C(16)-N(6) bond length is 1.38 Å. The C(16)-O(2) bond length is 1.24 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Cu(2) and one C(1) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Cu(2), one C(10), and one C(9) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one C(16), one C(8), and one H(6) atom. The N(6)-H(6) bond length is 1.02 Å. There are seven inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one N(6) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(15) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. O(2) is bonded in a single-bond geometry to one C(16) atom. Linkers: 1 O=C(CCC(=O)Nc1cccnc1)NC1=CC=CN([Cu](N=C=S)(N=C=S)N2[CH]C(NC(=O)CCC(=O)Nc3cccnc3)=CC=C2)[CH]1. Metal clusters: 1 [Cu]. The MOF has largest included sphere 4.56 A, density 1.29 g/cm3, surface area 4946.99 m2/g, accessible volume 0.27 cm3/g