MnC23N3H20O8F(CH2)2C7H4O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two 27132-81-6 molecules, and one MnC23N3H20O8F cluster. In the MnC23N3H20O8F cluster, Mn(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(4), one O(5), one O(6), and one O(8) atom. The Mn(1)-O(1) bond length is 2.09 Å. The Mn(1)-O(2) bond length is 2.42 Å. The Mn(1)-O(4) bond length is 2.12 Å. The Mn(1)-O(5) bond length is 2.10 Å. The Mn(1)-O(6) bond length is 2.15 Å. The Mn(1)-O(8) bond length is 2.08 Å. There are twenty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(3) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(3) atom. The C(2)-C(10) bond length is 1.38 Å. The C(2)-C(3) bond length is 1.44 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one O(4) atom. The C(3)-C(4) bond length is 1.46 Å. The C(3)-O(4) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(9) bond length is 1.42 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(1) atom. The C(5)-C(6) bond length is 1.37 Å. The C(5)-H(1) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a single-bond geometry to one C(5), one C(7), and one F(1) atom. The C(6)-C(7) bond length is 1.43 Å. The C(6)-F(1) bond length is 1.37 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(2) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(2) bond length is 1.38 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(2) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(2) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(4), one C(8), and one N(3) atom. The C(9)-N(3) bond length is 1.40 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(2), one N(3), and one H(3) atom. The C(10)-N(3) bond length is 1.35 Å. The C(10)-H(3) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted water-like geometry to one N(3) and one H(4) atom. The C(11)-N(3) bond length is 1.45 Å. The C(11)-H(4) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one C(15), one N(2), one H(10), and one H(9) atom. The C(14)-C(15) bond length is 1.51 Å. The C(14)-N(2) bond length is 1.46 Å. The C(14)-H(10) bond length is 1.09 Å. The C(14)-H(9) bond length is 1.11 Å. In the thirteenth C site, C(15) is bonded in a 4-coordinate geometry to one C(14), one N(1), one H(11), and one H(12) atom. The C(15)-N(1) bond length is 1.50 Å. The C(15)-H(11) bond length is 1.10 Å. The C(15)-H(12) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a 3-coordinate geometry to one N(1), one H(13), and one H(14) atom. The C(16)-N(1) bond length is 1.51 Å. The C(16)-H(13) bond length is 1.10 Å. The C(16)-H(14) bond length is 1.10 Å. In the fifteenth C site, C(17) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(15), and one H(16) atom. The C(17)-N(2) bond length is 1.46 Å. The C(17)-H(15) bond length is 1.10 Å. The C(17)-H(16) bond length is 1.10 Å. In the sixteenth C site, C(18) is bonded in a trigonal planar geometry to one C(19), one C(23), and one C(31) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(23) bond length is 1.40 Å. The C(18)-C(31) bond length is 1.49 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(17) atom. The C(19)-H(17) bond length is 1.09 Å. In the eighteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(20) atom. The C(23)-H(20) bond length is 1.09 Å. In the nineteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(28) and one H(22) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-H(22) bond length is 1.09 Å. In the twentieth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(32) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-C(32) bond length is 1.49 Å. In the twenty-first C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(23) atom. The C(29)-H(23) bond length is 1.09 Å. In the twenty-second C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(5), and one O(6) atom. The C(31)-O(5) bond length is 1.27 Å. The C(31)-O(6) bond length is 1.28 Å. In the twenty-third C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(8), and one O(9) atom. The C(32)-O(8) bond length is 1.28 Å. The C(32)-O(9) bond length is 1.27 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted tetrahedral geometry to one C(15), one C(16), one H(25), and one H(26) atom. The N(1)-H(25) bond length is 1.03 Å. The N(1)-H(26) bond length is 1.08 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(14), one C(17), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(9) atom. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(23) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(23) is bonded in a single-bond geometry to one C(29) atom. In the seventeenth H site, H(25) is bonded in a single-bond geometry to one N(1) atom. In the eighteenth H site, H(26) is bonded in a single-bond geometry to one N(1) atom. In the nineteenth H site, H(27) is bonded in a distorted linear geometry to one O(2) and one O(9) atom. The H(27)-O(2) bond length is 1.02 Å. The H(27)-O(9) bond length is 1.61 Å. In the twentieth H site, H(28) is bonded in a single-bond geometry to one O(2) atom. The H(28)-O(2) bond length is 0.98 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Mn(1), one H(27), and one H(28) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(3) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(31) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(31) atom. In the seventh O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(32) atom. In the eighth O site, O(9) is bonded in a water-like geometry to one C(32) and one H(27) atom. F(1) is bonded in a single-bond geometry to one C(6) atom. Linkers: 2 Fc1cc2c(cc1N1CC[NH2]CC1)n(cc(c2=O)C(=O)[O])C1CC1 ,2 [O]C(=O)c1ccc(C(=O)c2ccc(C([O])=O)cc2)cc1. Metal clusters: 1 O.O.[O][Mn]1(O[C]=O)(O[C]=O)O[C]O[Mn]([O])(O[C]=O)(O[C]=O)O[C]O1. The MOF has largest included sphere 2.81 A, density 1.56 g/cm3, surface area 4343.48 m2/g, accessible volume 0.20 cm3/g