AgC7H4(N2O)2CF3 crystallizes in the orthorhombic Pnma space group. The structure consists of four trifluoromethane molecules inside a AgC7H4(N2O)2 framework. In the AgC7H4(N2O)2 framework, Ag(1) is bonded in a distorted pentagonal pyramidal geometry to two equivalent N(1), two equivalent N(2), and two equivalent O(1) atoms. Both Ag(1)-N(1) bond lengths are 2.57 Å. Both Ag(1)-N(2) bond lengths are 2.39 Å. Both Ag(1)-O(1) bond lengths are 2.65 Å. There are four inequivalent C sites. In the first C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(2) atom. The C(3)-C(2) bond length is 1.41 Å. The C(3)-N(2) bond length is 1.32 Å. The C(3)-H(2) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to two equivalent O(1) atoms. Both C(4)-O(1) bond lengths are 1.26 Å. In the third C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 1.09 Å. In the fourth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. The C(2)-C(2) bond length is 1.40 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(3), and one N(1) atom. The N(2)-N(1) bond length is 1.37 Å. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one N(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. O(1) is bonded in a single-bond geometry to one Ag(1) and one C(4) atom. Linkers: 4 c1nncc2cnncc12. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.95 A, density 2.26 g/cm3, surface area 3133.82 m2/g, accessible volume 0.09 cm3/g