Ni3C30N3H18O13Ni3C44N4H26O13(C14NH8)5 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of five C14NH8 clusters, one Ni3C30N3H18O13 cluster, and one Ni3C44N4H26O13 cluster. In each C14NH8 cluster, there are fourteen inequivalent C sites. In the first C site, C(42) is bonded in a distorted single-bond geometry to one C(54) and one H(14,18) atom. The C(42)-C(54) bond length is 1.40 Å. The C(42)-H(14,18) bond length is 1.09 Å. In the second C site, C(49) is bonded in a trigonal planar geometry to one C(37), one C(61), and one C(85) atom. The C(49)-C(37) bond length is 1.40 Å. The C(49)-C(61) bond length is 1.41 Å. The C(49)-C(85) bond length is 1.48 Å. In the third C site, C(54) is bonded in a trigonal planar geometry to one C(42), one C(66), and one C(90) atom. The C(54)-C(66) bond length is 1.41 Å. The C(54)-C(90) bond length is 1.48 Å. In the fourth C site, C(61) is bonded in a distorted single-bond geometry to one C(49) and one H(25,27,31,33,34,35,36) atom. The C(61)-H(25,27,31,33,34,35,36) bond length is 1.09 Å. In the fifth C site, C(66) is bonded in a distorted single-bond geometry to one C(54) and one H(26,29,30) atom. The C(66)-H(26,29,30) bond length is 1.09 Å. In the sixth C site, C(85) is bonded in a distorted trigonal planar geometry to one C(49), one C(97), and one N(7) atom. The C(85)-C(97) bond length is 1.40 Å. The C(85)-N(7) bond length is 1.35 Å. In the seventh C site, C(90) is bonded in a distorted trigonal planar geometry to one C(102), one C(54), and one N(7) atom. The C(90)-C(102) bond length is 1.40 Å. The C(90)-N(7) bond length is 1.35 Å. In the eighth C site, C(97) is bonded in a distorted single-bond geometry to one C(109); one C(85); and one H(49,52) atom. The C(97)-C(109) bond length is 1.40 Å. The C(97)-H(49,52) bond length is 1.09 Å. In the ninth C site, C(102) is bonded in a distorted single-bond geometry to one C(109), one C(90), and one H(54) atom. The C(102)-C(109) bond length is 1.40 Å. The C(102)-H(54) bond length is 1.09 Å. In the tenth C site, C(109) is bonded in a trigonal planar geometry to one C(102), one C(115), and one C(97) atom. The C(109)-C(115) bond length is 1.47 Å. In the eleventh C site, C(115) is bonded in a trigonal planar geometry to one C(109), one C(121), and one C(126) atom. The C(115)-C(121) bond length is 1.40 Å. The C(115)-C(126) bond length is 1.40 Å. In the twelfth C site, C(121) is bonded in a distorted single-bond geometry to one C(115) and one H(61,66,70) atom. The C(121)-H(61,66,70) bond length is 1.09 Å. In the thirteenth C site, C(126) is bonded in a distorted single-bond geometry to one C(115) and one H(61,66,70) atom. The C(126)-H(61,66,70) bond length is 1.09 Å. In the fourteenth C site, C(37) is bonded in a distorted single-bond geometry to one C(49) and one H(13,15,19,21,22,23,24) atom. The C(37)-H(13,15,19,21,22,23,24) bond length is 1.09 Å. N(7) is bonded in a bent 120 degrees geometry to one C(85) and one C(90) atom. There are seven inequivalent H sites. In the first H site, H(13,15,19,21,22,23,24) is bonded in a single-bond geometry to one C(37) atom. In the second H site, H(14,18) is bonded in a single-bond geometry to one C(38) atom. The H(14,18)-C(38) bond length is 1.09 Å. In the third H site, H(25,27,31,33,34,35,36) is bonded in a single-bond geometry to one C(61) atom. In the fourth H site, H(26,29,30) is bonded in a single-bond geometry to one C(62) atom. The H(26,29,30)-C(62) bond length is 1.09 Å. In the fifth H site, H(49,52) is bonded in a single-bond geometry to one C(97) atom. In the sixth H site, H(54) is bonded in a single-bond geometry to one C(102) atom. In the seventh H site, H(61,66,70) is bonded in a single-bond geometry to one C(121) atom. In the Ni3C30N3H18O13 cluster, there are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one N(1), one O(1), one O(11), one O(13), one O(21), and one O(26) atom to form corner-sharing NiNO5 octahedra. The corner-sharing octahedral tilt angles range from 60-61°. The Ni(1)-N(1) bond length is 2.11 Å. The Ni(1)-O(1) bond length is 1.87 Å. The Ni(1)-O(11) bond length is 1.94 Å. The Ni(1)-O(13) bond length is 1.94 Å. The Ni(1)-O(21) bond length is 2.13 Å. The Ni(1)-O(26) bond length is 2.11 Å. In the second Ni site, Ni(3) is bonded to one N(3), one O(1), one O(10), one O(14), one O(23), and one O(24) atom to form corner-sharing NiNO5 octahedra. The corner-sharing octahedral tilt angles range from 60-61°. The Ni(3)-N(3) bond length is 2.12 Å. The Ni(3)-O(1) bond length is 1.88 Å. The Ni(3)-O(10) bond length is 1.96 Å. The Ni(3)-O(14) bond length is 1.93 Å. The Ni(3)-O(23) bond length is 2.11 Å. The Ni(3)-O(24) bond length is 2.12 Å. In the third Ni site, Ni(2) is bonded to one N(2), one O(1), one O(12), one O(22), one O(25), and one O(9) atom to form distorted corner-sharing NiNO5 octahedra. The corner-sharing octahedral tilt angles are 61°. The Ni(2)-N(2) bond length is 2.25 Å. The Ni(2)-O(1) bond length is 1.88 Å. The Ni(2)-O(12) bond length is 1.97 Å. The Ni(2)-O(22) bond length is 2.10 Å. The Ni(2)-O(25) bond length is 2.06 Å. The Ni(2)-O(9) bond length is 2.00 Å. There are thirty inequivalent C sites. In the first C site, C(79) is bonded in a distorted single-bond geometry to one C(19) and one H(43) atom. The C(79)-C(19) bond length is 1.40 Å. The C(79)-H(43) bond length is 1.09 Å. In the second C site, C(80) is bonded in a distorted single-bond geometry to one C(20) and one H(44,45,47) atom. The C(80)-C(20) bond length is 1.40 Å. The C(80)-H(44,45,47) bond length is 1.09 Å. In the third C site, C(81) is bonded in a distorted single-bond geometry to one C(21) and one H(44,45,47) atom. The C(81)-C(21) bond length is 1.40 Å. The C(81)-H(44,45,47) bond length is 1.09 Å. In the fourth C site, C(82) is bonded in a distorted single-bond geometry to one C(22) and one H(46) atom. The C(82)-C(22) bond length is 1.40 Å. The C(82)-H(46) bond length is 1.09 Å. In the fifth C site, C(83) is bonded in a distorted single-bond geometry to one C(23) and one H(44,45,47) atom. The C(83)-C(23) bond length is 1.40 Å. The C(83)-H(44,45,47) bond length is 1.09 Å. In the sixth C site, C(84) is bonded in a distorted single-bond geometry to one C(24) and one H(48) atom. The C(84)-C(24) bond length is 1.40 Å. The C(84)-H(48) bond length is 1.09 Å. In the seventh C site, C(133) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(73) atom. The C(133)-N(1) bond length is 1.34 Å. The C(133)-H(73) bond length is 1.09 Å. In the eighth C site, C(134) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(74) atom. The C(134)-N(2) bond length is 1.34 Å. The C(134)-H(74) bond length is 1.09 Å. In the ninth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(21), and one O(9) atom. The C(7)-C(19) bond length is 1.51 Å. The C(7)-O(21) bond length is 1.27 Å. The C(7)-O(9) bond length is 1.27 Å. In the tenth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(10), and one O(22) atom. The C(8)-C(20) bond length is 1.51 Å. The C(8)-O(10) bond length is 1.27 Å. The C(8)-O(22) bond length is 1.27 Å. In the eleventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(11), and one O(23) atom. The C(9)-C(21) bond length is 1.51 Å. The C(9)-O(11) bond length is 1.27 Å. The C(9)-O(23) bond length is 1.27 Å. In the twelfth C site, C(138) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(78) atom. The C(138)-N(1) bond length is 1.34 Å. The C(138)-H(78) bond length is 1.09 Å. In the thirteenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(13), and one O(25) atom. The C(11)-C(23) bond length is 1.51 Å. The C(11)-O(13) bond length is 1.27 Å. The C(11)-O(25) bond length is 1.27 Å. In the fourteenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(14), and one O(26) atom. The C(12)-C(24) bond length is 1.51 Å. The C(12)-O(14) bond length is 1.27 Å. The C(12)-O(26) bond length is 1.27 Å. In the fifteenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(12), and one O(24) atom. The C(10)-C(22) bond length is 1.51 Å. The C(10)-O(12) bond length is 1.27 Å. The C(10)-O(24) bond length is 1.27 Å. In the sixteenth C site, C(137) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(77) atom. The C(137)-N(2) bond length is 1.34 Å. The C(137)-H(77) bond length is 1.09 Å. In the seventeenth C site, C(135) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(75) atom. The C(135)-N(3) bond length is 1.34 Å. The C(135)-H(75) bond length is 1.09 Å. In the eighteenth C site, C(136) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(76) atom. The C(136)-N(3) bond length is 1.34 Å. The C(136)-H(76) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(31), one C(7), and one C(79) atom. The C(19)-C(31) bond length is 1.40 Å. In the twentieth C site, C(21) is bonded in a trigonal planar geometry to one C(33), one C(81), and one C(9) atom. The C(21)-C(33) bond length is 1.40 Å. In the twenty-first C site, C(20) is bonded in a trigonal planar geometry to one C(32), one C(8), and one C(80) atom. The C(20)-C(32) bond length is 1.40 Å. In the twenty-second C site, C(23) is bonded in a trigonal planar geometry to one C(11), one C(35), and one C(83) atom. The C(23)-C(35) bond length is 1.40 Å. In the twenty-third C site, C(24) is bonded in a trigonal planar geometry to one C(12), one C(36), and one C(84) atom. The C(24)-C(36) bond length is 1.40 Å. In the twenty-fourth C site, C(22) is bonded in a trigonal planar geometry to one C(10), one C(34), and one C(82) atom. The C(22)-C(34) bond length is 1.40 Å. In the twenty-fifth C site, C(31) is bonded in a distorted single-bond geometry to one C(19) and one H(7) atom. The C(31)-H(7) bond length is 1.09 Å. In the twenty-sixth C site, C(32) is bonded in a distorted single-bond geometry to one C(20) and one H(8,9,11) atom. The C(32)-H(8,9,11) bond length is 1.09 Å. In the twenty-seventh C site, C(33) is bonded in a distorted single-bond geometry to one C(21) and one H(8,9,11) atom. The C(33)-H(8,9,11) bond length is 1.09 Å. In the twenty-eighth C site, C(34) is bonded in a distorted single-bond geometry to one C(22) and one H(10) atom. The C(34)-H(10) bond length is 1.09 Å. In the twenty-ninth C site, C(35) is bonded in a distorted single-bond geometry to one C(23) and one H(8,9,11) atom. The C(35)-H(8,9,11) bond length is 1.09 Å. In the thirtieth C site, C(36) is bonded in a distorted single-bond geometry to one C(24) and one H(6,12) atom. The C(36)-H(6,12) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(133), and one C(138) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ni(2), one C(134), and one C(137) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ni(3), one C(135), and one C(136) atom. There are fourteen inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(31) atom. In the second H site, H(8,9,11) is bonded in a single-bond geometry to one C(32) atom. In the third H site, H(6,12) is bonded in a single-bond geometry to one C(30) atom. The H(6,12)-C(30) bond length is 1.09 Å. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(34) atom. In the fifth H site, H(43) is bonded in a single-bond geometry to one C(79) atom. In the sixth H site, H(44,45,47) is bonded in a single-bond geometry to one C(80) atom. In the seventh H site, H(46) is bonded in a single-bond geometry to one C(82) atom. In the eighth H site, H(48) is bonded in a single-bond geometry to one C(84) atom. In the ninth H site, H(73) is bonded in a single-bond geometry to one C(133) atom. In the tenth H site, H(74) is bonded in a single-bond geometry to one C(134) atom. In the eleventh H site, H(75) is bonded in a single-bond geometry to one C(135) atom. In the twelfth H site, H(76) is bonded in a single-bond geometry to one C(136) atom. In the thirteenth H site, H(77) is bonded in a single-bond geometry to one C(137) atom. In the fourteenth H site, H(78) is bonded in a single-bond geometry to one C(138) atom. There are thirteen inequivalent O sites. In the first O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(9) atom. In the second O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(11) atom. In the third O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Ni(3) and one C(12) atom. In the fourth O site, O(12) is bonded in a bent 120 degrees geometry to one Ni(2) and one C(10) atom. In the fifth O site, O(21) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(7) atom. In the sixth O site, O(22) is bonded in a bent 120 degrees geometry to one Ni(2) and one C(8) atom. In the seventh O site, O(23) is bonded in a bent 120 degrees geometry to one Ni(3) and one C(9) atom. In the eighth O site, O(24) is bonded in a bent 120 degrees geometry to one Ni(3) and one C(10) atom. In the ninth O site, O(25) is bonded in a bent 120 degrees geometry to one Ni(2) and one C(11) atom. In the tenth O site, O(26) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(12) atom. In the eleventh O site, O(1) is bonded in a trigonal planar geometry to one Ni(1), one Ni(2), and one Ni(3) atom. In the twelfth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Ni(2) and one C(7) atom. In the thirteenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Ni(3) and one C(8) atom. In the Ni3C44N4H26O13 cluster, there are three inequivalent Ni sites. In the first Ni site, Ni(4) is bonded to one N(4), one O(15), one O(2), one O(20), one O(5), and one O(7) atom to form corner-sharing NiNO5 octahedra. The corner-sharing octahedral tilt angles are 60°. The Ni(4)-N(4) bond length is 2.10 Å. The Ni(4)-O(15) bond length is 2.12 Å. The Ni(4)-O(2) bond length is 1.87 Å. The Ni(4)-O(20) bond length is 2.08 Å. The Ni(4)-O(5) bond length is 1.97 Å. The Ni(4)-O(7) bond length is 1.96 Å. In the second Ni site, Ni(5) is bonded to one N(5), one O(16), one O(19), one O(2), one O(3), and one O(6) atom to form distorted corner-sharing NiNO5 octahedra. The corner-sharing octahedral tilt angles range from 60-63°. The Ni(5)-N(5) bond length is 2.30 Å. The Ni(5)-O(16) bond length is 2.25 Å. The Ni(5)-O(19) bond length is 2.20 Å. The Ni(5)-O(2) bond length is 1.88 Å. The Ni(5)-O(3) bond length is 1.97 Å. The Ni(5)-O(6) bond length is 2.00 Å. In the third Ni site, Ni(6) is bonded to one N(6), one O(17), one O(18), one O(2), one O(4), and one O(8) atom to form distorted corner-sharing NiNO5 octahedra. The corner-sharing octahedral tilt angles range from 60-63°. The Ni(6)-N(6) bond length is 2.28 Å. The Ni(6)-O(17) bond length is 2.24 Å. The Ni(6)-O(18) bond length is 2.24 Å. The Ni(6)-O(2) bond length is 1.87 Å. The Ni(6)-O(4) bond length is 2.00 Å. The Ni(6)-O(8) bond length is 1.96 Å. There are forty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(15), and one O(3) atom. The C(1)-C(13) bond length is 1.51 Å. The C(1)-O(15) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(16), and one O(4) atom. The C(2)-C(14) bond length is 1.51 Å. The C(2)-O(16) bond length is 1.26 Å. The C(2)-O(4) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(17), and one O(5) atom. The C(3)-C(15) bond length is 1.51 Å. The C(3)-O(17) bond length is 1.26 Å. The C(3)-O(5) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(18), and one O(6) atom. The C(4)-C(16) bond length is 1.51 Å. The C(4)-O(18) bond length is 1.26 Å. The C(4)-O(6) bond length is 1.28 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(19), and one O(7) atom. The C(5)-C(17) bond length is 1.50 Å. The C(5)-O(19) bond length is 1.26 Å. The C(5)-O(7) bond length is 1.28 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(20), and one O(8) atom. The C(6)-C(18) bond length is 1.50 Å. The C(6)-O(20) bond length is 1.27 Å. The C(6)-O(8) bond length is 1.27 Å. In the seventh C site, C(13) is bonded in a trigonal planar geometry to one C(1), one C(25), and one C(73) atom. The C(13)-C(25) bond length is 1.40 Å. The C(13)-C(73) bond length is 1.40 Å. In the eighth C site, C(14) is bonded in a trigonal planar geometry to one C(2), one C(26), and one C(74) atom. The C(14)-C(26) bond length is 1.40 Å. The C(14)-C(74) bond length is 1.40 Å. In the ninth C site, C(15) is bonded in a trigonal planar geometry to one C(27), one C(3), and one C(75) atom. The C(15)-C(27) bond length is 1.40 Å. The C(15)-C(75) bond length is 1.40 Å. In the tenth C site, C(16) is bonded in a trigonal planar geometry to one C(28), one C(4), and one C(76) atom. The C(16)-C(28) bond length is 1.40 Å. The C(16)-C(76) bond length is 1.40 Å. In the eleventh C site, C(17) is bonded in a trigonal planar geometry to one C(29), one C(5), and one C(77) atom. The C(17)-C(29) bond length is 1.40 Å. The C(17)-C(77) bond length is 1.40 Å. In the twelfth C site, C(18) is bonded in a trigonal planar geometry to one C(30), one C(6), and one C(78) atom. The C(18)-C(30) bond length is 1.40 Å. The C(18)-C(78) bond length is 1.40 Å. In the thirteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(13) and one H(1) atom. The C(25)-H(1) bond length is 1.09 Å. In the fourteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(14) and one H(2,4) atom. The C(26)-H(2,4) bond length is 1.09 Å. In the fifteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(15) and one H(3,39) atom. The C(27)-H(3,39) bond length is 1.09 Å. In the sixteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(16) and one H(2,4) atom. The C(28)-H(2,4) bond length is 1.09 Å. In the seventeenth C site, C(29) is bonded in a distorted single-bond geometry to one C(17), one C(41), and one H(5) atom. The C(29)-C(41) bond length is 1.39 Å. The C(29)-H(5) bond length is 1.09 Å. In the eighteenth C site, C(30) is bonded in a distorted single-bond geometry to one C(18) and one H(6,12) atom. In the nineteenth C site, C(38) is bonded in a distorted single-bond geometry to one C(50) and one H(14,18) atom. The C(38)-C(50) bond length is 1.40 Å. In the twentieth C site, C(41) is bonded in a distorted single-bond geometry to one C(29), one C(53), and one H(17) atom. The C(41)-C(53) bond length is 1.40 Å. The C(41)-H(17) bond length is 1.09 Å. In the twenty-first C site, C(50) is bonded in a trigonal planar geometry to one C(38), one C(62), and one C(86) atom. The C(50)-C(62) bond length is 1.41 Å. The C(50)-C(86) bond length is 1.48 Å. In the twenty-second C site, C(53) is bonded in a trigonal planar geometry to one C(41), one C(65), and one C(89) atom. The C(53)-C(65) bond length is 1.41 Å. The C(53)-C(89) bond length is 1.48 Å. In the twenty-third C site, C(62) is bonded in a distorted single-bond geometry to one C(50) and one H(26,29,30) atom. In the twenty-fourth C site, C(65) is bonded in a distorted single-bond geometry to one C(53) and one H(26,29,30) atom. The C(65)-H(26,29,30) bond length is 1.09 Å. In the twenty-fifth C site, C(73) is bonded in a distorted single-bond geometry to one C(13) and one H(37,42) atom. The C(73)-H(37,42) bond length is 1.09 Å. In the twenty-sixth C site, C(74) is bonded in a distorted single-bond geometry to one C(14) and one H(38,40,41) atom. The C(74)-H(38,40,41) bond length is 1.09 Å. In the twenty-seventh C site, C(75) is bonded in a distorted single-bond geometry to one C(15) and one H(3,39) atom. The C(75)-H(3,39) bond length is 1.09 Å. In the twenty-eighth C site, C(76) is bonded in a distorted single-bond geometry to one C(16) and one H(38,40,41) atom. The C(76)-H(38,40,41) bond length is 1.09 Å. In the twenty-ninth C site, C(77) is bonded in a distorted single-bond geometry to one C(17) and one H(38,40,41) atom. The C(77)-H(38,40,41) bond length is 1.09 Å. In the thirtieth C site, C(78) is bonded in a distorted single-bond geometry to one C(18) and one H(37,42) atom. The C(78)-H(37,42) bond length is 1.09 Å. In the thirty-first C site, C(86) is bonded in a distorted trigonal planar geometry to one C(50), one C(98), and one N(8) atom. The C(86)-C(98) bond length is 1.40 Å. The C(86)-N(8) bond length is 1.35 Å. In the thirty-second C site, C(89) is bonded in a distorted trigonal planar geometry to one C(101), one C(53), and one N(8) atom. The C(89)-C(101) bond length is 1.40 Å. The C(89)-N(8) bond length is 1.35 Å. In the thirty-third C site, C(98) is bonded in a distorted single-bond geometry to one C(110); one C(86); and one H(50,53,57,58) atom. The C(98)-C(110) bond length is 1.40 Å. The C(98)-H(50,53,57,58) bond length is 1.09 Å. In the thirty-fourth C site, C(101) is bonded in a distorted single-bond geometry to one C(110); one C(89); and one H(50,53,57,58) atom. The C(101)-C(110) bond length is 1.40 Å. The C(101)-H(50,53,57,58) bond length is 1.09 Å. In the thirty-fifth C site, C(110) is bonded in a trigonal planar geometry to one C(101), one C(116), and one C(98) atom. The C(110)-C(116) bond length is 1.47 Å. In the thirty-sixth C site, C(116) is bonded in a trigonal planar geometry to one C(110), one C(122), and one C(125) atom. The C(116)-C(122) bond length is 1.40 Å. The C(116)-C(125) bond length is 1.40 Å. In the thirty-seventh C site, C(122) is bonded in a distorted single-bond geometry to one C(116) and one H(62,65,68,69,71) atom. The C(122)-H(62,65,68,69,71) bond length is 1.09 Å. In the thirty-eighth C site, C(125) is bonded in a distorted single-bond geometry to one C(116) and one H(62,65,68,69,71) atom. The C(125)-H(62,65,68,69,71) bond length is 1.09 Å. In the thirty-ninth C site, C(139) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(79,84) atom. The C(139)-N(4) bond length is 1.34 Å. The C(139)-H(79,84) bond length is 1.09 Å. In the fortieth C site, C(140) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(80) atom. The C(140)-N(5) bond length is 1.34 Å. The C(140)-H(80) bond length is 1.09 Å. In the forty-first C site, C(141) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(81,82) atom. The C(141)-N(6) bond length is 1.34 Å. The C(141)-H(81,82) bond length is 1.09 Å. In the forty-second C site, C(142) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(81,82) atom. The C(142)-N(6) bond length is 1.34 Å. The C(142)-H(81,82) bond length is 1.09 Å. In the forty-third C site, C(143) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(83) atom. The C(143)-N(5) bond length is 1.34 Å. The C(143)-H(83) bond length is 1.09 Å. In the forty-fourth C site, C(144) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(79,84) atom. The C(144)-N(4) bond length is 1.34 Å. The C(144)-H(79,84) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Ni(4), one C(139), and one C(144) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Ni(5), one C(140), and one C(143) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Ni(6), one C(141), and one C(142) atom. In the fourth N site, N(8) is bonded in a bent 120 degrees geometry to one C(86) and one C(89) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(25) atom. In the second H site, H(2,4) is bonded in a single-bond geometry to one C(26) atom. In the third H site, H(3,39) is bonded in a single-bond geometry to one C(27) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(29) atom. In the fifth H site, H(6,12) is bonded in a single-bond geometry to one C(30) atom. In the sixth H site, H(14,18) is bonded in a single-bond geometry to one C(38) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(41) atom. In the eighth H site, H(26,29,30) is bonded in a single-bond geometry to one C(62) atom. In the ninth H site, H(37,42) is bonded in a single-bond geometry to one C(73) atom. In the tenth H site, H(38,40,41) is bonded in a single-bond geometry to one C(74) atom. In the eleventh H site, H(50,53,57,58) is bonded in a single-bond geometry to one C(98) atom. In the twelfth H site, H(62,65,68,69,71) is bonded in a single-bond geometry to one C(122) atom. In the thirteenth H site, H(79,84) is bonded in a single-bond geometry to one C(139) atom. In the fourteenth H site, H(80) is bonded in a single-bond geometry to one C(140) atom. In the fifteenth H site, H(81,82) is bonded in a single-bond geometry to one C(141) atom. In the sixteenth H site, H(83) is bonded in a single-bond geometry to one C(143) atom. There are thirteen inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to one Ni(4), one Ni(5), and one Ni(6) atom. In the second O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ni(5) and one C(1) atom. In the third O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ni(6) and one C(2) atom. In the fourth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Ni(4) and one C(3) atom. In the fifth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Ni(5) and one C(4) atom. In the sixth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Ni(4) and one C(5) atom. In the seventh O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Ni(6) and one C(6) atom. In the eighth O site, O(15) is bonded in a bent 120 degrees geometry to one Ni(4) and one C(1) atom. In the ninth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Ni(5) and one C(2) atom. In the tenth O site, O(17) is bonded in a bent 120 degrees geometry to one Ni(6) and one C(3) atom. In the eleventh O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Ni(6) and one C(4) atom. In the twelfth O site, O(19) is bonded in a bent 120 degrees geometry to one Ni(5) and one C(5) atom. In the thirteenth O site, O(20) is bonded in a bent 120 degrees geometry to one Ni(4) and one C(6) atom. Linkers: 6 [O]C(=O)c1ccc(-c2cc(-c3ccncc3)cc(-c3ccc(C([O])=O)cc3)n2)cc1. Metal clusters: 2 [C]1O[Ni]23O[C]O[Ni]45(O1)O[C]O[Ni](O[C]O2)(O[C]O3)(O[C]O4)O5. RCSR code: pcu. The MOF has largest included sphere 3.15 A, density 1.53 g/cm3, surface area 3911.07 m2/g, accessible volume 0.17 cm3/g