(CH)2ZnC15N2H8O5F3CF is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two fluoromethane molecules, and one ZnC15N2H8O5F3 cluster. In the ZnC15N2H8O5F3 cluster, Zn(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(3), and one O(5) atom. The Zn(1)-N(1) bond length is 2.11 Å. The Zn(1)-N(2) bond length is 2.08 Å. The Zn(1)-O(1) bond length is 2.10 Å. The Zn(1)-O(3) bond length is 2.10 Å. The Zn(1)-O(5) bond length is 2.09 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.48 Å. The C(5)-N(1) bond length is 1.35 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-N(2) bond length is 1.35 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(7) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(8) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(11)-C(12) bond length is 1.52 Å. The C(11)-O(1) bond length is 1.27 Å. The C(11)-O(2) bond length is 1.26 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-C(14) bond length is 1.39 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(15), and one F(1) atom. The C(13)-C(15) bond length is 1.40 Å. The C(13)-F(1) bond length is 1.36 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one F(4) atom. The C(14)-F(4) bond length is 1.35 Å. In the thirteenth C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(18) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-C(18) bond length is 1.51 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one F(2) atom. The C(17)-F(2) bond length is 1.36 Å. In the fifteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(3), and one O(4) atom. The C(18)-O(3) bond length is 1.27 Å. The C(18)-O(4) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(6) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one O(5) atom. The H(9)-O(5) bond length is 1.00 Å. In the eighth H site, H(10) is bonded in a distorted single-bond geometry to one O(2) and one O(5) atom. The H(10)-O(2) bond length is 1.64 Å. The H(10)-O(5) bond length is 1.01 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(11) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(11) and one H(10) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(18) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one C(18) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Zn(1), one H(10), and one H(9) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(13) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(17) atom. In the third F site, F(4) is bonded in a single-bond geometry to one C(14) atom. Linkers: 2 [O]C(=O)c1c(F)c(F)c(F)c(C([O])=O)c1F. Metal clusters: 2 O.O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.37 A, density 1.84 g/cm3, surface area 3898.81 m2/g, accessible volume 0.09 cm3/g