(CH)2NiC18N2H16(O3F2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one NiC18N2H16(O3F2)2 cluster. In the NiC18N2H16(O3F2)2 cluster, Ni(1) is bonded to two equivalent N(1), two equivalent O(1), and two equivalent O(3) atoms to form NiN2O4 octahedra that share corners with two equivalent C(10)H3O tetrahedra. Both Ni(1)-N(1) bond lengths are 2.02 Å. Both Ni(1)-O(1) bond lengths are 2.11 Å. Both Ni(1)-O(3) bond lengths are 2.22 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(4) bond length is 1.39 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(2) and one F(2) atom. The C(3)-F(2) bond length is 1.36 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one F(1) atom. The C(4)-F(1) bond length is 1.36 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(2) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(2) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(3) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(7)-H(4) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one N(1) and one H(6) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded to one H(7), one H(8), one H(9), and one O(3) atom to form CH3O tetrahedra that share  a cornercorner with one Ni(1)N2O4 octahedra. The corner-sharing octahedral tilt angles are 58°. The C(10)-H(7) bond length is 1.10 Å. The C(10)-H(8) bond length is 1.10 Å. The C(10)-H(9) bond length is 1.10 Å. The C(10)-O(3) bond length is 1.43 Å. N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(5), and one C(9) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one O(3) atom. The H(1)-O(2) bond length is 1.61 Å. The H(1)-O(3) bond length is 1.01 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(1) and one H(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Ni(1), one C(10), and one H(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(4) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(3) atom. Linkers: 1 [O]C(=O)c1c(F)c(F)c(C([O])=O)c(F)c1F. Metal clusters: 1 [Ni]. The MOF has largest included sphere 2.05 A, density 1.65 g/cm3, surface area 4620.67 m2/g, accessible volume 0.19 cm3/g