MnC14H16(N7S)2(CH2)4(CH3NO2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, two nitromethane molecules, and one MnC14H16(N7S)2 cluster. In the MnC14H16(N7S)2 cluster, Mn(1) is bonded in an octahedral geometry to two equivalent N(3), two equivalent N(6), and two equivalent N(7) atoms. Both Mn(1)-N(3) bond lengths are 2.28 Å. Both Mn(1)-N(6) bond lengths are 2.27 Å. Both Mn(1)-N(7) bond lengths are 2.14 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(1)-N(1) bond length is 1.46 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the second C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(7), and one H(8) atom. The C(4)-N(4) bond length is 1.46 Å. The C(4)-H(7) bond length is 1.10 Å. The C(4)-H(8) bond length is 1.10 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(9) atom. The C(5)-N(2) bond length is 1.33 Å. The C(5)-N(3) bond length is 1.37 Å. The C(5)-H(9) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(10) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-N(3) bond length is 1.34 Å. The C(6)-H(10) bond length is 1.08 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(11) atom. The C(7)-N(5) bond length is 1.33 Å. The C(7)-N(6) bond length is 1.36 Å. The C(7)-H(11) bond length is 1.08 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(12) atom. The C(8)-N(4) bond length is 1.34 Å. The C(8)-N(6) bond length is 1.34 Å. The C(8)-H(12) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted linear geometry to one N(7) and one S(1) atom. The C(9)-N(7) bond length is 1.19 Å. The C(9)-S(1) bond length is 1.62 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(1), one C(6), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(5) and one N(1) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(5), and one C(6) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(4), one C(8), and one N(5) atom. The N(4)-N(5) bond length is 1.36 Å. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(7) and one N(4) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(7), and one C(8) atom. In the seventh N site, N(7) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(9) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(8) atom. S(1) is bonded in a single-bond geometry to one C(9) atom. Linkers: 2 c1ncn(CCCCn2cncn2)n1. Metal clusters: 1 [Mn]. The MOF has largest included sphere 1.94 A, density 1.50 g/cm3, surface area 5449.39 m2/g, accessible volume 0.15 cm3/g