CdC7H7(NO2)2(CH)8CH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, four isobutylene molecules, and one CdC7H7(NO2)2 cluster. In the CdC7H7(NO2)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one O(1), one O(3), one O(4), and two equivalent O(2) atoms. The Cd(1)-N(1) bond length is 2.23 Å. The Cd(1)-O(1) bond length is 2.57 Å. The Cd(1)-O(3) bond length is 2.28 Å. The Cd(1)-O(4) bond length is 2.47 Å. There is one shorter (2.35 Å) and one longer (2.37 Å) Cd(1)-O(2) bond length. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.29 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(6)-O(3) bond length is 1.29 Å. The C(6)-O(4) bond length is 1.27 Å. In the third C site, C(11) is bonded in a distorted trigonal planar geometry to one C(16), one N(1), and one N(2) atom. The C(11)-C(16) bond length is 1.48 Å. The C(11)-N(1) bond length is 1.34 Å. The C(11)-N(2) bond length is 1.36 Å. In the fourth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(2), and one H(9) atom. The C(12)-C(13) bond length is 1.37 Å. The C(12)-N(2) bond length is 1.38 Å. The C(12)-H(9) bond length is 1.08 Å. In the fifth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(1), and one H(10) atom. The C(13)-N(1) bond length is 1.38 Å. The C(13)-H(10) bond length is 1.08 Å. In the sixth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(11), and one H(12) atom. The C(14)-N(2) bond length is 1.46 Å. The C(14)-H(11) bond length is 1.10 Å. The C(14)-H(12) bond length is 1.10 Å. In the seventh C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one H(15), one H(16), and one H(17) atom. The C(16)-H(15) bond length is 1.10 Å. The C(16)-H(16) bond length is 1.10 Å. The C(16)-H(17) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(13) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(14) atom. There are seven inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(16) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(6) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(6) atom. Linkers: 1 Cc1nccn1CCCCn1ccnc1C ,2 [O][C]Cc1ccc(CC([O])=O)cc1 ,2 [O]C(=O)Cc1ccc(CC([O])=O)cc1. Metal clusters: 1 O=[C]O[Cd]1O[C]O1.O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 2.23 A, density 1.80 g/cm3, surface area 4208.26 m2/g, accessible volume 0.11 cm3/g