ZnC12N2H8O5(C4H3)2(CH)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two isobutylene molecules, one p-xylene molecule, and one ZnC12N2H8O5 cluster. In the ZnC12N2H8O5 cluster, Zn(1) is bonded in a distorted octahedral geometry to one N(1), one N(2), one O(1), one O(3), one O(4), and one O(5) atom. The Zn(1)-N(1) bond length is 2.21 Å. The Zn(1)-N(2) bond length is 2.15 Å. The Zn(1)-O(1) bond length is 2.05 Å. The Zn(1)-O(3) bond length is 2.35 Å. The Zn(1)-O(4) bond length is 2.21 Å. The Zn(1)-O(5) bond length is 2.05 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted trigonal planar geometry to one C(15), one C(6), and one N(1) atom. The C(4)-C(15) bond length is 1.44 Å. The C(4)-C(6) bond length is 1.42 Å. The C(4)-N(1) bond length is 1.35 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(22) atom. The C(5)-C(15) bond length is 1.42 Å. The C(5)-C(16) bond length is 1.41 Å. The C(5)-C(22) bond length is 1.43 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one C(18), one C(23), and one C(4) atom. The C(6)-C(18) bond length is 1.41 Å. The C(6)-C(23) bond length is 1.43 Å. In the fifth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(4), one C(5), and one N(2) atom. The C(15)-N(2) bond length is 1.36 Å. In the sixth C site, C(16) is bonded in a distorted single-bond geometry to one C(5) and one H(10) atom. The C(16)-H(10) bond length is 1.09 Å. In the seventh C site, C(18) is bonded in a distorted single-bond geometry to one C(6) and one H(12) atom. The C(18)-H(12) bond length is 1.09 Å. In the eighth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(5) atom. The C(20)-O(2) bond length is 1.26 Å. The C(20)-O(5) bond length is 1.29 Å. In the ninth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(21)-O(3) bond length is 1.28 Å. The C(21)-O(4) bond length is 1.28 Å. In the tenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(23), one C(5), and one H(14) atom. The C(22)-C(23) bond length is 1.37 Å. The C(22)-H(14) bond length is 1.09 Å. In the eleventh C site, C(23) is bonded in a distorted single-bond geometry to one C(22), one C(6), and one H(15) atom. The C(23)-H(15) bond length is 1.09 Å. In the twelfth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(16) atom. The C(24)-N(2) bond length is 1.33 Å. The C(24)-H(16) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(24) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the seventh H site, H(17) is bonded in a distorted linear geometry to one O(1) and one O(2) atom. The H(17)-O(1) bond length is 1.02 Å. The H(17)-O(2) bond length is 1.59 Å. In the eighth H site, H(18) is bonded in a distorted single-bond geometry to one O(1) and one O(3) atom. The H(18)-O(1) bond length is 1.00 Å. The H(18)-O(3) bond length is 1.68 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one H(17), and one H(18) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one C(20) and one H(17) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Zn(1), one C(21), and one H(18) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Zn(1) and one C(21) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(20) atom. Linkers: 2 [O]C(=O)/C=C/c1ccc(/C=C/C([O])=O)cc1. Metal clusters: 2 O.O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.18 A, density 1.53 g/cm3, surface area 4694.41 m2/g, accessible volume 0.16 cm3/g