ZnC14H10(NO2)2(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two ZnC14H10(NO2)2 clusters. In each ZnC14H10(NO2)2 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a square pyramidal geometry to one N(3), one O(1), one O(4), one O(5), and one O(7) atom. The Zn(1)-N(3) bond length is 2.05 Å. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(4) bond length is 2.04 Å. The Zn(1)-O(5) bond length is 2.08 Å. The Zn(1)-O(7) bond length is 2.09 Å. In the second Zn site, Zn(2) is bonded in a square pyramidal geometry to one N(4), one O(2), one O(3), one O(6), and one O(8) atom. The Zn(2)-N(4) bond length is 2.05 Å. The Zn(2)-O(2) bond length is 2.04 Å. The Zn(2)-O(3) bond length is 2.03 Å. The Zn(2)-O(6) bond length is 2.08 Å. The Zn(2)-O(8) bond length is 2.09 Å. There are twenty-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(4) atom. The C(2)-C(4) bond length is 1.49 Å. The C(2)-O(2) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.27 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-C(7) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(8) atom. The C(4)-C(6) bond length is 1.40 Å. The C(4)-C(8) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(1,3) atom. The C(5)-H(1,3) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(6)-H(2) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(3) and one H(1,3) atom. The C(7)-H(1,3) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(8)-H(4) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a bent 120 degrees geometry to one C(10), one O(5), and one O(6) atom. The C(9)-C(10) bond length is 1.50 Å. The C(9)-O(5) bond length is 1.27 Å. The C(9)-O(6) bond length is 1.27 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(12) bond length is 1.40 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(5,6) atom. The C(11)-H(5,6) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one H(5,6) atom. The C(12)-H(5,6) bond length is 1.09 Å. In the thirteenth C site, C(13,14) is bonded in a distorted single-bond geometry to one C(16) and one H(7,8) atom. The C(13,14)-C(16) bond length is 1.40 Å. The C(13,14)-H(7,8) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(7), and one O(8) atom. The C(15)-C(16) bond length is 1.50 Å. The C(15)-O(7) bond length is 1.28 Å. The C(15)-O(8) bond length is 1.28 Å. In the fifteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15) and two equivalent C(13,14) atoms. In the sixteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(19), one C(27), and one N(1) atom. The C(17)-C(19) bond length is 1.41 Å. The C(17)-C(27) bond length is 1.40 Å. The C(17)-N(1) bond length is 1.39 Å. In the seventeenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(20), one C(28), and one N(2) atom. The C(18)-C(20) bond length is 1.41 Å. The C(18)-C(28) bond length is 1.40 Å. The C(18)-N(2) bond length is 1.39 Å. In the eighteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(17), one C(21), and one N(3) atom. The C(19)-C(21) bond length is 1.40 Å. The C(19)-N(3) bond length is 1.39 Å. In the nineteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(18), one C(22), and one N(4) atom. The C(20)-C(22) bond length is 1.40 Å. The C(20)-N(4) bond length is 1.39 Å. In the twentieth C site, C(21) is bonded in a single-bond geometry to one C(19) and one H(9,10) atom. The C(21)-H(9,10) bond length is 1.09 Å. In the twenty-first C site, C(22) is bonded in a single-bond geometry to one C(20) and one H(9,10) atom. The C(22)-H(9,10) bond length is 1.09 Å. In the twenty-second C site, C(27) is bonded in a distorted single-bond geometry to one C(17) and one H(15,16) atom. The C(27)-H(15,16) bond length is 1.09 Å. In the twenty-third C site, C(28) is bonded in a distorted single-bond geometry to one C(18) and one H(15,16) atom. The C(28)-H(15,16) bond length is 1.09 Å. In the twenty-fourth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(31,32); one N(1); and one N(3) atom. The C(29)-C(31,32) bond length is 1.48 Å. The C(29)-N(1) bond length is 1.37 Å. The C(29)-N(3) bond length is 1.33 Å. In the twenty-fifth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(31,32); one N(2); and one N(4) atom. The C(30)-C(31,32) bond length is 1.48 Å. The C(30)-N(2) bond length is 1.37 Å. The C(30)-N(4) bond length is 1.33 Å. In the twenty-sixth C site, C(31,32) is bonded in a distorted trigonal non-coplanar geometry to one C(29); one H(17); one H(19,20); and one H(21,22) atom. The C(31,32)-H(17) bond length is 1.10 Å. The C(31,32)-H(19,20) bond length is 1.10 Å. The C(31,32)-H(21,22) bond length is 1.10 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(17); one C(29); and one H(23,24) atom. The N(1)-H(23,24) bond length is 1.01 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(18); one C(30); and one H(23,24) atom. The N(2)-H(23,24) bond length is 1.01 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(19), and one C(29) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(2), one C(20), and one C(30) atom. There are twelve inequivalent H sites. In the first H site, H(1,3) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(7,8) is bonded in a single-bond geometry to one C(13,14) atom. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(15,16) is bonded in a single-bond geometry to one C(27) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(31,32) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(31,32) atom. The H(18)-C(31,32) bond length is 1.10 Å. In the tenth H site, H(19,20) is bonded in a single-bond geometry to one C(31,32) atom. In the eleventh H site, H(21,22) is bonded in a single-bond geometry to one C(31,32) atom. In the twelfth H site, H(23,24) is bonded in a single-bond geometry to one N(1) atom. There are eight inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(9) atom. In the fifth O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(15) atom. In the sixth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(15) atom. In the seventh O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the eighth O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(2) atom. Linkers: 4 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 5.86 A, density 0.97 g/cm3, surface area 4782.21 m2/g, accessible volume 0.50 cm3/g