SrNiC4H10O13(CH2)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a SrNiC4H10O13 framework. In the SrNiC4H10O13 framework, Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(12), one O(5), one O(6), two equivalent O(13), and two equivalent O(2) atoms. The Sr(1)-O(1) bond length is 2.81 Å. The Sr(1)-O(11) bond length is 2.58 Å. The Sr(1)-O(12) bond length is 2.55 Å. The Sr(1)-O(5) bond length is 3.05 Å. The Sr(1)-O(6) bond length is 2.58 Å. There is one shorter (2.63 Å) and one longer (2.64 Å) Sr(1)-O(13) bond length. There is one shorter (2.62 Å) and one longer (2.70 Å) Sr(1)-O(2) bond length. Ni(1) is bonded in a distorted square pyramidal geometry to one O(1), one O(10), one O(4), one O(5), and one O(7) atom. The Ni(1)-O(1) bond length is 1.91 Å. The Ni(1)-O(10) bond length is 2.49 Å. The Ni(1)-O(4) bond length is 1.92 Å. The Ni(1)-O(5) bond length is 1.90 Å. The Ni(1)-O(7) bond length is 1.92 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(3)-O(3) bond length is 1.26 Å. The C(3)-O(4) bond length is 1.29 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(4)-O(5) bond length is 1.28 Å. The C(4)-O(6) bond length is 1.27 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(6)-O(7) bond length is 1.29 Å. The C(6)-O(8) bond length is 1.26 Å. There are ten inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one O(8) and one O(9) atom. The H(5)-O(8) bond length is 1.70 Å. The H(5)-O(9) bond length is 1.00 Å. In the second H site, H(6) is bonded in a single-bond geometry to one O(9) atom. The H(6)-O(9) bond length is 0.97 Å. In the third H site, H(7) is bonded in a single-bond geometry to one O(10) atom. The H(7)-O(10) bond length is 0.99 Å. In the fourth H site, H(8) is bonded in a single-bond geometry to one O(10) atom. The H(8)-O(10) bond length is 0.99 Å. In the fifth H site, H(9) is bonded in a single-bond geometry to one O(11) atom. The H(9)-O(11) bond length is 0.99 Å. In the sixth H site, H(10) is bonded in a distorted single-bond geometry to one O(11) and one O(8) atom. The H(10)-O(11) bond length is 1.00 Å. The H(10)-O(8) bond length is 1.67 Å. In the seventh H site, H(11) is bonded in a single-bond geometry to one O(12) atom. The H(11)-O(12) bond length is 0.98 Å. In the eighth H site, H(12) is bonded in a single-bond geometry to one O(12) atom. The H(12)-O(12) bond length is 0.99 Å. In the ninth H site, H(13) is bonded in a single-bond geometry to one O(13) atom. The H(13)-O(13) bond length is 0.99 Å. In the tenth H site, H(14) is bonded in a distorted single-bond geometry to one O(13) atom. The H(14)-O(13) bond length is 1.00 Å. There are thirteen inequivalent O sites. In the first O site, O(11) is bonded in a distorted water-like geometry to one Sr(1), one H(10), and one H(9) atom. In the second O site, O(12) is bonded in a distorted water-like geometry to one Sr(1), one H(11), and one H(12) atom. In the third O site, O(13) is bonded in a water-like geometry to two equivalent Sr(1), one H(13), and one H(14) atom. In the fourth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sr(1), one Ni(1), and one C(1) atom. In the fifth O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one C(1) atom. In the sixth O site, O(3) is bonded in a distorted single-bond geometry to one C(3) atom. In the seventh O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(3) atom. In the eighth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Sr(1), one Ni(1), and one C(4) atom. In the ninth O site, O(6) is bonded in a distorted single-bond geometry to one Sr(1) and one C(4) atom. In the tenth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(6) atom. In the eleventh O site, O(8) is bonded in a 3-coordinate geometry to one C(6), one H(10), and one H(5) atom. In the twelfth O site, O(9) is bonded in a water-like geometry to one H(5) and one H(6) atom. In the thirteenth O site, O(10) is bonded in a water-like geometry to one Ni(1), one H(7), and one H(8) atom. Linkers: 8 [O]C(=O)CC([O])=O. Metal clusters: 4 [Sr] ,4 [Ni]. The MOF has largest included sphere 2.51 A, density 1.98 g/cm3, surface area 3498.41 m2/g, accessible volume 0.10 cm3/g