(CH2)3CHCH3Sn2C6H12O5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, six 02329_fluka molecules, two 02329_fluka molecules, and one Sn2C6H12O5 cluster. In the Sn2C6H12O5 cluster, there are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a trigonal bipyramidal geometry to one C(8), one C(9), one O(1), one O(4), and one O(5) atom. The Sn(1)-C(8) bond length is 2.13 Å. The Sn(1)-C(9) bond length is 2.13 Å. The Sn(1)-O(1) bond length is 2.26 Å. The Sn(1)-O(4) bond length is 2.24 Å. The Sn(1)-O(5) bond length is 2.06 Å. In the second Sn site, Sn(2) is bonded in a 6-coordinate geometry to one C(10), one C(11), one O(1), one O(3), and two equivalent O(5) atoms. The Sn(2)-C(10) bond length is 2.13 Å. The Sn(2)-C(11) bond length is 2.13 Å. The Sn(2)-O(1) bond length is 2.57 Å. The Sn(2)-O(3) bond length is 2.30 Å. There is one shorter (2.08 Å) and one longer (2.17 Å) Sn(2)-O(5) bond length. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.31 Å. The C(1)-O(2) bond length is 1.24 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(6)-O(3) bond length is 1.27 Å. The C(6)-O(4) bond length is 1.28 Å. In the third C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(11), one H(12), and one H(13) atom. The C(8)-H(11) bond length is 1.10 Å. The C(8)-H(12) bond length is 1.09 Å. The C(8)-H(13) bond length is 1.10 Å. In the fourth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(14), one H(15), and one H(16) atom. The C(9)-H(14) bond length is 1.10 Å. The C(9)-H(15) bond length is 1.09 Å. The C(9)-H(16) bond length is 1.09 Å. In the fifth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one Sn(2), one H(17), one H(18), and one H(19) atom. The C(10)-H(17) bond length is 1.10 Å. The C(10)-H(18) bond length is 1.09 Å. The C(10)-H(19) bond length is 1.09 Å. In the sixth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one Sn(2), one H(20), one H(21), and one H(22) atom. The C(11)-H(20) bond length is 1.09 Å. The C(11)-H(21) bond length is 1.10 Å. The C(11)-H(22) bond length is 1.10 Å. There are twelve inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(11) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Sn(1), one Sn(2), and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sn(2) and one C(6) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Sn(1) and one C(6) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Sn(1) and two equivalent Sn(2) atoms. Linkers: 1 C[C@@H](CCC([O])=O)CC([O])=O ,1 C[C@H](CCC([O])=O)CC([O])=O. Metal clusters: 1 O=[C]O[Sn]1O[C]O[Sn]O1.O=[C]O[Sn]1O[C]O[Sn]O1. The MOF has largest included sphere 2.59 A, density 1.97 g/cm3, surface area 3764.59 m2/g, accessible volume 0.16 cm3/g