Zn5C46H38S2(N3O5)4 crystallizes in the triclinic P-1 space group. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(2), one O(4), one O(6), and one O(7) atom to form ZnNO3 tetrahedra that share  a cornercorner with one Zn(3)N2O4 octahedra and  a cornercorner with one Zn(2)NO3 tetrahedra. The corner-sharing octahedral tilt angles are 62°. The Zn(1)-N(2) bond length is 2.04 Å. The Zn(1)-O(4) bond length is 2.02 Å. The Zn(1)-O(6) bond length is 1.91 Å. The Zn(1)-O(7) bond length is 1.93 Å. In the second Zn site, Zn(2) is bonded to one N(3), one O(7), one O(8), and one O(9) atom to form distorted corner-sharing ZnNO3 tetrahedra. The Zn(2)-N(3) bond length is 2.07 Å. The Zn(2)-O(7) bond length is 1.93 Å. The Zn(2)-O(8) bond length is 2.06 Å. The Zn(2)-O(9) bond length is 1.97 Å. In the third Zn site, Zn(3) is bonded to two equivalent N(1), two equivalent O(5), and two equivalent O(6) atoms to form corner-sharing ZnN2O4 octahedra. Both Zn(3)-N(1) bond lengths are 2.21 Å. Both Zn(3)-O(5) bond lengths are 2.20 Å. Both Zn(3)-O(6) bond lengths are 2.00 Å. There are twenty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(4), and one O(5) atom. The C(1)-C(4) bond length is 1.50 Å. The C(1)-O(4) bond length is 1.30 Å. The C(1)-O(5) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(21), one C(3), and one H(5) atom. The C(2)-C(21) bond length is 1.40 Å. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(5) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(6) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-H(6) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(7), and one C(8) atom. The C(4)-C(7) bond length is 1.40 Å. The C(4)-C(8) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(13), one N(1), and one H(7) atom. The C(5)-C(13) bond length is 1.39 Å. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(7) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(17), one C(20), and one H(8) atom. The C(6)-C(17) bond length is 1.40 Å. The C(6)-C(20) bond length is 1.39 Å. The C(6)-H(8) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(11), one C(4), and one H(9) atom. The C(7)-C(11) bond length is 1.39 Å. The C(7)-H(9) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(4), one C(9), and one H(10) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(10) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(15), one C(18), and one C(8) atom. The C(9)-C(15) bond length is 1.50 Å. The C(9)-C(18) bond length is 1.40 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(22), one N(2), and one H(11) atom. The C(10)-C(22) bond length is 1.39 Å. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(11) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(18), one C(7), and one S(1) atom. The C(11)-C(18) bond length is 1.40 Å. The C(11)-S(1) bond length is 1.79 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one N(6) atom. The C(12)-C(14) bond length is 1.40 Å. The C(12)-C(16) bond length is 1.40 Å. The C(12)-N(6) bond length is 1.42 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(21), one C(5), and one H(12) atom. The C(13)-C(21) bond length is 1.40 Å. The C(13)-H(12) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(12), one C(19), and one H(13) atom. The C(14)-C(19) bond length is 1.39 Å. The C(14)-H(13) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a bent 120 degrees geometry to one C(9), one O(10), and one O(9) atom. The C(15)-O(10) bond length is 1.26 Å. The C(15)-O(9) bond length is 1.30 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(12), one C(23), and one H(14) atom. The C(16)-C(23) bond length is 1.38 Å. The C(16)-H(14) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(22), one C(6), and one N(4) atom. The C(17)-C(22) bond length is 1.40 Å. The C(17)-N(4) bond length is 1.42 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(15) atom. The C(18)-H(15) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one H(16) atom. The C(19)-N(3) bond length is 1.35 Å. The C(19)-H(16) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(6), one N(2), and one H(17) atom. The C(20)-N(2) bond length is 1.35 Å. The C(20)-H(17) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(13), one C(2), and one N(5) atom. The C(21)-N(5) bond length is 1.41 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(10), one C(17), and one H(18) atom. The C(22)-H(18) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted trigonal planar geometry to one C(16), one N(3), and one H(19) atom. The C(23)-N(3) bond length is 1.35 Å. The C(23)-H(19) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(3), one C(3), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(20) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(19), and one C(23) atom. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one C(17) and one N(5) atom. The N(4)-N(5) bond length is 1.26 Å. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one C(21) and one N(4) atom. In the sixth N site, N(6) is bonded in a distorted bent 120 degrees geometry to one C(12) and one N(6) atom. The N(6)-N(6) bond length is 1.26 Å. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(6) atom. The H(1)-O(6) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) and one O(7) atom. The H(2)-O(4) bond length is 1.72 Å. The H(2)-O(7) bond length is 0.99 Å. In the third H site, H(3) is bonded in a distorted bent 150 degrees geometry to one O(3) and one O(8) atom. The H(3)-O(3) bond length is 1.60 Å. The H(3)-O(8) bond length is 1.01 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(8) atom. The H(4)-O(8) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(20) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(2) bond length is 1.46 Å. The S(1)-O(3) bond length is 1.49 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one H(3) and one S(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Zn(1), one C(1), and one H(2) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Zn(3) and one C(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(3), and one H(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(2), and one H(2) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one H(3), and one H(4) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Zn(2) and one C(15) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(15) atom. Linkers: 2 [O]C(=O)c1cc(C([O])=O)cc(S([O])([O])[O])c1 ,3 c1cc([N][N]c2ccncc2)ccn1. Metal clusters: 1 O.O.O=[C]O[Zn]O.O=[C]O[Zn]O.O[Zn]O[C]O[Zn]O[C]O[Zn]O. The MOF has largest included sphere 5.16 A, density 1.50 g/cm3, surface area 4154.86 m2/g, accessible volume 0.27 cm3/g