(CH)6(CH2)6Sn2C9H13O10CHO2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, twelve 02329_fluka molecules, two formic acid molecules, and two Sn2C9H13O10 clusters. In each Sn2C9H13O10 cluster, there are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a distorted pentagonal bipyramidal geometry to one C(10), one C(11), one O(1), one O(10), one O(2), one O(3), and one O(4) atom. The Sn(1)-C(10) bond length is 2.12 Å. The Sn(1)-C(11) bond length is 2.12 Å. The Sn(1)-O(1) bond length is 2.20 Å. The Sn(1)-O(10) bond length is 2.66 Å. The Sn(1)-O(2) bond length is 2.53 Å. The Sn(1)-O(3) bond length is 2.21 Å. The Sn(1)-O(4) bond length is 2.62 Å. In the second Sn site, Sn(2) is bonded in a 7-coordinate geometry to one C(21), one C(22), one O(10), one O(2), one O(7), one O(8), and one O(9) atom. The Sn(2)-C(21) bond length is 2.12 Å. The Sn(2)-C(22) bond length is 2.12 Å. The Sn(2)-O(10) bond length is 2.55 Å. The Sn(2)-O(2) bond length is 2.72 Å. The Sn(2)-O(7) bond length is 2.20 Å. The Sn(2)-O(8) bond length is 2.54 Å. The Sn(2)-O(9) bond length is 2.19 Å. There are nine inequivalent C sites. In the first C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(7)-O(1) bond length is 1.30 Å. The C(7)-O(2) bond length is 1.27 Å. In the second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.29 Å. The C(8)-O(4) bond length is 1.27 Å. In the third C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(9)-O(5) bond length is 1.34 Å. The C(9)-O(6) bond length is 1.23 Å. In the fourth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(11), one H(12), and one H(13) atom. The C(10)-H(11) bond length is 1.09 Å. The C(10)-H(12) bond length is 1.09 Å. The C(10)-H(13) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(14), one H(15), and one H(16) atom. The C(11)-H(14) bond length is 1.09 Å. The C(11)-H(15) bond length is 1.09 Å. The C(11)-H(16) bond length is 1.09 Å. In the sixth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(18)-O(7) bond length is 1.30 Å. The C(18)-O(8) bond length is 1.27 Å. In the seventh C site, C(20) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(20)-O(10) bond length is 1.27 Å. The C(20)-O(9) bond length is 1.30 Å. In the eighth C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one Sn(2), one H(27), one H(28), and one H(29) atom. The C(21)-H(27) bond length is 1.10 Å. The C(21)-H(28) bond length is 1.09 Å. The C(21)-H(29) bond length is 1.09 Å. In the ninth C site, C(22) is bonded in a distorted trigonal non-coplanar geometry to one Sn(2), one H(30), one H(31), and one H(32) atom. The C(22)-H(30) bond length is 1.09 Å. The C(22)-H(31) bond length is 1.09 Å. The C(22)-H(32) bond length is 1.09 Å. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(4) and one O(5) atom. The H(1)-O(4) bond length is 1.62 Å. The H(1)-O(5) bond length is 1.01 Å. In the second H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(27) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(28) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(29) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(30) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(31) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(32) is bonded in a single-bond geometry to one C(22) atom. There are ten inequivalent O sites. In the first O site, O(9) is bonded in a distorted water-like geometry to one Sn(2) and one C(20) atom. In the second O site, O(10) is bonded in a single-bond geometry to one Sn(1), one Sn(2), and one C(20) atom. In the third O site, O(1) is bonded in a distorted water-like geometry to one Sn(1) and one C(7) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one Sn(1), one Sn(2), and one C(7) atom. In the fifth O site, O(3) is bonded in a distorted water-like geometry to one Sn(1) and one C(8) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Sn(1), one C(8), and one H(1) atom. In the seventh O site, O(5) is bonded in a water-like geometry to one C(9) and one H(1) atom. In the eighth O site, O(6) is bonded in a single-bond geometry to one C(9) atom. In the ninth O site, O(7) is bonded in a distorted water-like geometry to one Sn(2) and one C(18) atom. In the tenth O site, O(8) is bonded in a 1-coordinate geometry to one Sn(2) and one C(18) atom. Linkers: 4 [O]C(=O)[C@@H]1C[C@H](C([O])=O)C[C@H](C(=O)O)C1. Metal clusters: 2 O=[C]O[Sn]O[C]=O.O=[C]O[Sn]O[C]=O. The MOF has largest included sphere 2.32 A, density 1.84 g/cm3, surface area 3823.58 m2/g, accessible volume 0.12 cm3/g