CdC22N4H18O5(CH)2(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, sixteen 02329_fluka molecules, and two CdC22N4H18O5 clusters. In each CdC22N4H18O5 cluster, Cd(1) is bonded in a pentagonal bipyramidal geometry to one N(1), one N(5), one O(1), one O(4), one O(6), one O(7), and one O(9) atom. The Cd(1)-N(1) bond length is 2.38 Å. The Cd(1)-N(5) bond length is 2.40 Å. The Cd(1)-O(1) bond length is 2.41 Å. The Cd(1)-O(4) bond length is 2.53 Å. The Cd(1)-O(6) bond length is 2.32 Å. The Cd(1)-O(7) bond length is 2.49 Å. The Cd(1)-O(9) bond length is 2.42 Å. There are twenty-two inequivalent C sites. In the first C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(9) atom. The C(15)-O(7) bond length is 1.28 Å. The C(15)-O(9) bond length is 1.28 Å. In the second C site, C(17) is bonded in a distorted trigonal planar geometry to one C(19), one N(1), and one H(21) atom. The C(17)-C(19) bond length is 1.39 Å. The C(17)-N(1) bond length is 1.34 Å. The C(17)-H(21) bond length is 1.09 Å. In the third C site, C(19) is bonded in a distorted single-bond geometry to one C(17); one C(21,22); and one H(23,24) atom. The C(19)-C(21,22) bond length is 1.41 Å. The C(19)-H(23,24) bond length is 1.09 Å. In the fourth C site, C(21,22) is bonded in a trigonal planar geometry to one C(19), one C(23), and one C(27) atom. The C(21,22)-C(23) bond length is 1.40 Å. The C(21,22)-C(27) bond length is 1.48 Å. In the fifth C site, C(23) is bonded in a distorted single-bond geometry to one C(21,22) and one H(25,26) atom. The C(23)-H(25,26) bond length is 1.09 Å. In the sixth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(27) atom. The C(25)-N(1) bond length is 1.34 Å. The C(25)-H(27) bond length is 1.09 Å. In the seventh C site, C(27) is bonded in a trigonal planar geometry to one C(21,22); one C(29,30); and one C(35) atom. The C(27)-C(29,30) bond length is 1.40 Å. The C(27)-C(35) bond length is 1.41 Å. In the eighth C site, C(29,30) is bonded in a distorted single-bond geometry to one C(27) and one H(29,30) atom. The C(29,30)-H(29,30) bond length is 1.09 Å. In the ninth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(31) atom. The C(31)-N(3) bond length is 1.34 Å. The C(31)-H(31) bond length is 1.09 Å. In the tenth C site, C(33) is bonded in a distorted trigonal planar geometry to one C(35), one N(3), and one H(33) atom. The C(33)-C(35) bond length is 1.39 Å. The C(33)-N(3) bond length is 1.34 Å. The C(33)-H(33) bond length is 1.09 Å. In the eleventh C site, C(35) is bonded in a distorted single-bond geometry to one C(27); one C(33); and one H(35,36) atom. The C(35)-H(35,36) bond length is 1.09 Å. In the twelfth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(39,40); one N(5); and one H(37,38) atom. The C(37)-C(39,40) bond length is 1.39 Å. The C(37)-N(5) bond length is 1.35 Å. The C(37)-H(37,38) bond length is 1.09 Å. In the thirteenth C site, C(39,40) is bonded in a distorted single-bond geometry to one C(37); one C(41); and one H(39,40) atom. The C(39,40)-C(41) bond length is 1.40 Å. The C(39,40)-H(39,40) bond length is 1.09 Å. In the fourteenth C site, C(41) is bonded in a trigonal planar geometry to one C(39,40); one C(43,44); and one C(47) atom. The C(41)-C(43,44) bond length is 1.40 Å. The C(41)-C(47) bond length is 1.48 Å. In the fifteenth C site, C(43,44) is bonded in a distorted single-bond geometry to one C(41); one C(45); and one H(41,42) atom. The C(43,44)-C(45) bond length is 1.39 Å. The C(43,44)-H(41,42) bond length is 1.09 Å. In the sixteenth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(43,44); one N(5); and one H(43,44) atom. The C(45)-N(5) bond length is 1.34 Å. The C(45)-H(43,44) bond length is 1.09 Å. In the seventeenth C site, C(47) is bonded in a trigonal planar geometry to one C(41), one C(49), and one C(55) atom. The C(47)-C(49) bond length is 1.41 Å. The C(47)-C(55) bond length is 1.40 Å. In the eighteenth C site, C(49) is bonded in a distorted single-bond geometry to one C(47); one C(51,52); and one H(45,46) atom. The C(49)-C(51,52) bond length is 1.39 Å. The C(49)-H(45,46) bond length is 1.09 Å. In the nineteenth C site, C(51,52) is bonded in a distorted trigonal planar geometry to one C(49), one N(7), and one H(47) atom. The C(51,52)-N(7) bond length is 1.34 Å. The C(51,52)-H(47) bond length is 1.09 Å. In the twentieth C site, C(53,54) is bonded in a distorted trigonal planar geometry to one C(55), one N(7), and one H(49) atom. The C(53,54)-C(55) bond length is 1.39 Å. The C(53,54)-N(7) bond length is 1.35 Å. The C(53,54)-H(49) bond length is 1.09 Å. In the twenty-first C site, C(55) is bonded in a distorted single-bond geometry to one C(47); one C(53,54); and one H(51,52) atom. The C(55)-H(51,52) bond length is 1.09 Å. In the twenty-second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. The C(2)-O(4) bond length is 1.27 Å. The C(2)-O(6) bond length is 1.28 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(17), and one C(25) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(31), one C(33), and one H(53) atom. The N(3)-H(53) bond length is 1.70 Å. In the third N site, N(5) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(37), and one C(45) atom. In the fourth N site, N(7) is bonded in a bent 120 degrees geometry to one C(51,52) and one C(53,54) atom. There are eighteen inequivalent H sites. In the first H site, H(21) is bonded in a single-bond geometry to one C(17) atom. In the second H site, H(23,24) is bonded in a single-bond geometry to one C(19) atom. In the third H site, H(25,26) is bonded in a single-bond geometry to one C(23) atom. In the fourth H site, H(27) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(29,30) is bonded in a single-bond geometry to one C(29,30) atom. In the sixth H site, H(31) is bonded in a single-bond geometry to one C(31) atom. In the seventh H site, H(33) is bonded in a single-bond geometry to one C(33) atom. In the eighth H site, H(35,36) is bonded in a single-bond geometry to one C(35) atom. In the ninth H site, H(37,38) is bonded in a single-bond geometry to one C(37) atom. In the tenth H site, H(39,40) is bonded in a single-bond geometry to one C(39,40) atom. In the eleventh H site, H(41,42) is bonded in a single-bond geometry to one C(43,44) atom. In the twelfth H site, H(43,44) is bonded in a single-bond geometry to one C(45) atom. In the thirteenth H site, H(45,46) is bonded in a single-bond geometry to one C(49) atom. In the fourteenth H site, H(47) is bonded in a single-bond geometry to one C(51,52) atom. In the fifteenth H site, H(49) is bonded in a single-bond geometry to one C(53,54) atom. In the sixteenth H site, H(51,52) is bonded in a single-bond geometry to one C(55) atom. In the seventeenth H site, H(53) is bonded in a distorted linear geometry to one N(3) and one O(1) atom. The H(53)-O(1) bond length is 1.01 Å. In the eighteenth H site, H(55) is bonded in a single-bond geometry to one O(1) atom. The H(55)-O(1) bond length is 0.97 Å. There are five inequivalent O sites. In the first O site, O(7) is bonded in a distorted single-bond geometry to one Cd(1) and one C(15) atom. In the second O site, O(9) is bonded in a distorted single-bond geometry to one Cd(1) and one C(15) atom. In the third O site, O(1) is bonded in a distorted water-like geometry to one Cd(1), one H(53), and one H(55) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(2) atom. In the fifth O site, O(6) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(2) atom. Linkers: 4 [O]C(=O)[C@H]1CCCC[C@H]1C([O])=O. Metal clusters: 4 [Cd]. The MOF has largest included sphere 3.61 A, density 1.50 g/cm3, surface area 4683.10 m2/g, accessible volume 0.19 cm3/g