Zn6C102H58S12O29H2O crystallizes in the monoclinic P2_1 space group. The structure consists of two water molecules inside a Zn6C102H58S12O29 framework. In the Zn6C102H58S12O29 framework, there are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to one O(10), one O(13), one O(24), one O(5), and one O(7) atom. The Zn(1)-O(10) bond length is 2.48 Å. The Zn(1)-O(13) bond length is 2.00 Å. The Zn(1)-O(24) bond length is 1.97 Å. The Zn(1)-O(5) bond length is 1.97 Å. The Zn(1)-O(7) bond length is 2.04 Å. In the second Zn site, Zn(2) is bonded in a 5-coordinate geometry to one O(11), one O(14), one O(22), one O(6), and one O(8) atom. The Zn(2)-O(11) bond length is 2.47 Å. The Zn(2)-O(14) bond length is 2.00 Å. The Zn(2)-O(22) bond length is 1.97 Å. The Zn(2)-O(6) bond length is 1.97 Å. The Zn(2)-O(8) bond length is 2.04 Å. In the third Zn site, Zn(3) is bonded in a 5-coordinate geometry to one O(12), one O(15), one O(23), one O(4), and one O(9) atom. The Zn(3)-O(12) bond length is 2.48 Å. The Zn(3)-O(15) bond length is 2.00 Å. The Zn(3)-O(23) bond length is 1.97 Å. The Zn(3)-O(4) bond length is 1.97 Å. The Zn(3)-O(9) bond length is 2.04 Å. In the fourth Zn site, Zn(4) is bonded in a 5-coordinate geometry to one O(10), one O(17), one O(21), one O(28), and one O(3) atom. The Zn(4)-O(10) bond length is 2.09 Å. The Zn(4)-O(17) bond length is 2.12 Å. The Zn(4)-O(21) bond length is 2.05 Å. The Zn(4)-O(28) bond length is 2.12 Å. The Zn(4)-O(3) bond length is 2.03 Å. In the fifth Zn site, Zn(5) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(18), one O(19), and one O(29) atom. The Zn(5)-O(1) bond length is 2.02 Å. The Zn(5)-O(11) bond length is 2.10 Å. The Zn(5)-O(18) bond length is 2.12 Å. The Zn(5)-O(19) bond length is 2.05 Å. The Zn(5)-O(29) bond length is 2.12 Å. In the sixth Zn site, Zn(6) is bonded in a 5-coordinate geometry to one O(12), one O(16), one O(2), one O(20), and one O(30) atom. The Zn(6)-O(12) bond length is 2.10 Å. The Zn(6)-O(16) bond length is 2.12 Å. The Zn(6)-O(2) bond length is 2.02 Å. The Zn(6)-O(20) bond length is 2.05 Å. The Zn(6)-O(30) bond length is 2.12 Å. There are seventy-one inequivalent C sites. In the first C site, C(1,3) is bonded in a trigonal planar geometry to one C(4,6); one S(1,3); and one S(4,6) atom. The C(1,3)-C(4,6) bond length is 1.36 Å. The C(1,3)-S(1,3) bond length is 1.75 Å. The C(1,3)-S(4,6) bond length is 1.75 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(5), one S(2), and one S(5) atom. The C(2)-C(5) bond length is 1.36 Å. The C(2)-S(2) bond length is 1.75 Å. The C(2)-S(5) bond length is 1.75 Å. In the third C site, C(4,6) is bonded in a trigonal planar geometry to one C(1,3); one S(10,12); and one S(7,9) atom. The C(4,6)-S(10,12) bond length is 1.75 Å. The C(4,6)-S(7,9) bond length is 1.75 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one S(11), and one S(8) atom. The C(5)-S(11) bond length is 1.75 Å. The C(5)-S(8) bond length is 1.75 Å. In the fifth C site, C(7,9) is bonded in a trigonal planar geometry to one C(10); one C(28,29,30); and one S(1,3) atom. The C(7,9)-C(10) bond length is 1.37 Å. The C(7,9)-C(28,29,30) bond length is 1.47 Å. The C(7,9)-S(1,3) bond length is 1.75 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(11); one C(28,29,30); and one S(2) atom. The C(8)-C(11) bond length is 1.37 Å. The C(8)-C(28,29,30) bond length is 1.47 Å. The C(8)-S(2) bond length is 1.75 Å. In the seventh C site, C(10) is bonded in a trigonal planar geometry to one C(49); one C(7,9); and one S(4,6) atom. The C(10)-C(49) bond length is 1.47 Å. The C(10)-S(4,6) bond length is 1.76 Å. In the eighth C site, C(11) is bonded in a trigonal planar geometry to one C(50), one C(8), and one S(5) atom. The C(11)-C(50) bond length is 1.47 Å. The C(11)-S(5) bond length is 1.76 Å. In the ninth C site, C(12) is bonded in a trigonal planar geometry to one C(51); one C(7,9); and one S(4,6) atom. The C(12)-C(51) bond length is 1.47 Å. The C(12)-C(7,9) bond length is 1.37 Å. The C(12)-S(4,6) bond length is 1.76 Å. In the tenth C site, C(13,15) is bonded in a trigonal planar geometry to one C(16,18); one C(70,72); and one S(7,9) atom. The C(13,15)-C(16,18) bond length is 1.37 Å. The C(13,15)-C(70,72) bond length is 1.47 Å. The C(13,15)-S(7,9) bond length is 1.76 Å. In the eleventh C site, C(14) is bonded in a trigonal planar geometry to one C(17), one C(71), and one S(8) atom. The C(14)-C(17) bond length is 1.37 Å. The C(14)-C(71) bond length is 1.47 Å. The C(14)-S(8) bond length is 1.76 Å. In the twelfth C site, C(16,18) is bonded in a trigonal planar geometry to one C(13,15); one C(91,93); and one S(10,12) atom. The C(16,18)-C(91,93) bond length is 1.47 Å. The C(16,18)-S(10,12) bond length is 1.75 Å. In the thirteenth C site, C(17) is bonded in a trigonal planar geometry to one C(14), one C(92), and one S(11) atom. The C(17)-C(92) bond length is 1.47 Å. The C(17)-S(11) bond length is 1.75 Å. In the fourteenth C site, C(19) is bonded in a trigonal planar geometry to one C(22,23,24); one C(34,35,36); and one C(37) atom. The C(19)-C(22,23,24) bond length is 1.40 Å. The C(19)-C(34,35,36) bond length is 1.40 Å. The C(19)-C(37) bond length is 1.49 Å. In the fifteenth C site, C(20) is bonded in a trigonal planar geometry to one C(22,23,24); one C(34,35,36); and one C(38) atom. The C(20)-C(22,23,24) bond length is 1.40 Å. The C(20)-C(34,35,36) bond length is 1.40 Å. The C(20)-C(38) bond length is 1.49 Å. In the sixteenth C site, C(21) is bonded in a trigonal planar geometry to one C(22,23,24); one C(34,35,36); and one C(39) atom. The C(21)-C(22,23,24) bond length is 1.40 Å. The C(21)-C(34,35,36) bond length is 1.40 Å. The C(21)-C(39) bond length is 1.49 Å. In the seventeenth C site, C(22,23,24) is bonded in a distorted trigonal planar geometry to one C(19); one C(31,32,33); and one H(1,2,3) atom. The C(22,23,24)-C(31,32,33) bond length is 1.39 Å. The C(22,23,24)-H(1,2,3) bond length is 1.09 Å. In the eighteenth C site, C(25,26,27) is bonded in a distorted trigonal planar geometry to one C(28,29,30); one C(34,35,36); and one H(4,5,6) atom. The C(25,26,27)-C(28,29,30) bond length is 1.41 Å. The C(25,26,27)-C(34,35,36) bond length is 1.39 Å. The C(25,26,27)-H(4,5,6) bond length is 1.09 Å. In the nineteenth C site, C(28,29,30) is bonded in a trigonal planar geometry to one C(25,26,27); one C(31,32,33); and one C(7,9) atom. The C(28,29,30)-C(31,32,33) bond length is 1.41 Å. In the twentieth C site, C(31,32,33) is bonded in a distorted single-bond geometry to one C(22,23,24); one C(28,29,30); and one H(7,8,9) atom. The C(31,32,33)-H(7,8,9) bond length is 1.09 Å. In the twenty-first C site, C(34,35,36) is bonded in a distorted single-bond geometry to one C(19); one C(25,26,27); and one H(10,11,12) atom. The C(34,35,36)-H(10,11,12) bond length is 1.09 Å. In the twenty-second C site, C(37) is bonded in a bent 120 degrees geometry to one C(19), one O(1), and one O(4) atom. The C(37)-O(1) bond length is 1.27 Å. The C(37)-O(4) bond length is 1.28 Å. In the twenty-third C site, C(38) is bonded in a bent 120 degrees geometry to one C(20), one O(2), and one O(5) atom. The C(38)-O(2) bond length is 1.27 Å. The C(38)-O(5) bond length is 1.28 Å. In the twenty-fourth C site, C(39) is bonded in a bent 120 degrees geometry to one C(21), one O(3), and one O(6) atom. The C(39)-O(3) bond length is 1.27 Å. The C(39)-O(6) bond length is 1.28 Å. In the twenty-fifth C site, C(40) is bonded in a trigonal planar geometry to one C(43), one C(55), and one C(58) atom. The C(40)-C(43) bond length is 1.40 Å. The C(40)-C(55) bond length is 1.40 Å. The C(40)-C(58) bond length is 1.48 Å. In the twenty-sixth C site, C(41) is bonded in a trigonal planar geometry to one C(44), one C(56), and one C(59) atom. The C(41)-C(44) bond length is 1.40 Å. The C(41)-C(56) bond length is 1.40 Å. The C(41)-C(59) bond length is 1.48 Å. In the twenty-seventh C site, C(42) is bonded in a trigonal planar geometry to one C(45), one C(57), and one C(60) atom. The C(42)-C(45) bond length is 1.40 Å. The C(42)-C(57) bond length is 1.40 Å. The C(42)-C(60) bond length is 1.48 Å. In the twenty-eighth C site, C(43) is bonded in a distorted trigonal planar geometry to one C(40), one C(46), and one H(13) atom. The C(43)-C(46) bond length is 1.39 Å. The C(43)-H(13) bond length is 1.09 Å. In the twenty-ninth C site, C(44) is bonded in a distorted trigonal planar geometry to one C(41); one C(47); and one H(14,15) atom. The C(44)-C(47) bond length is 1.39 Å. The C(44)-H(14,15) bond length is 1.09 Å. In the thirtieth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(42); one C(48); and one H(14,15) atom. The C(45)-C(48) bond length is 1.39 Å. The C(45)-H(14,15) bond length is 1.09 Å. In the thirty-first C site, C(46) is bonded in a distorted single-bond geometry to one C(43); one C(49); and one H(16,17,18) atom. The C(46)-C(49) bond length is 1.41 Å. The C(46)-H(16,17,18) bond length is 1.09 Å. In the thirty-second C site, C(47) is bonded in a distorted single-bond geometry to one C(44); one C(50); and one H(16,17,18) atom. The C(47)-C(50) bond length is 1.41 Å. The C(47)-H(16,17,18) bond length is 1.09 Å. In the thirty-third C site, C(48) is bonded in a distorted single-bond geometry to one C(45); one C(51); and one H(16,17,18) atom. The C(48)-C(51) bond length is 1.41 Å. The C(48)-H(16,17,18) bond length is 1.09 Å. In the thirty-fourth C site, C(49) is bonded in a trigonal planar geometry to one C(10), one C(46), and one C(52) atom. The C(49)-C(52) bond length is 1.41 Å. In the thirty-fifth C site, C(50) is bonded in a trigonal planar geometry to one C(11), one C(47), and one C(53) atom. The C(50)-C(53) bond length is 1.41 Å. In the thirty-sixth C site, C(51) is bonded in a trigonal planar geometry to one C(12), one C(48), and one C(54) atom. The C(51)-C(54) bond length is 1.41 Å. In the thirty-seventh C site, C(52) is bonded in a distorted trigonal planar geometry to one C(49), one C(55), and one H(19) atom. The C(52)-C(55) bond length is 1.39 Å. The C(52)-H(19) bond length is 1.09 Å. In the thirty-eighth C site, C(53) is bonded in a distorted trigonal planar geometry to one C(50); one C(56); and one H(20,21) atom. The C(53)-C(56) bond length is 1.39 Å. The C(53)-H(20,21) bond length is 1.09 Å. In the thirty-ninth C site, C(54) is bonded in a distorted trigonal planar geometry to one C(51); one C(57); and one H(20,21) atom. The C(54)-C(57) bond length is 1.39 Å. The C(54)-H(20,21) bond length is 1.09 Å. In the fortieth C site, C(55) is bonded in a distorted trigonal planar geometry to one C(40); one C(52); and one H(22,24) atom. The C(55)-H(22,24) bond length is 1.09 Å. In the forty-first C site, C(56) is bonded in a distorted trigonal planar geometry to one C(41), one C(53), and one H(23) atom. The C(56)-H(23) bond length is 1.09 Å. In the forty-second C site, C(57) is bonded in a distorted trigonal planar geometry to one C(42); one C(54); and one H(22,24) atom. The C(57)-H(22,24) bond length is 1.09 Å. In the forty-third C site, C(58) is bonded in a bent 120 degrees geometry to one C(40), one O(10), and one O(7) atom. The C(58)-O(10) bond length is 1.27 Å. The C(58)-O(7) bond length is 1.29 Å. In the forty-fourth C site, C(59) is bonded in a bent 120 degrees geometry to one C(41), one O(11), and one O(8) atom. The C(59)-O(11) bond length is 1.27 Å. The C(59)-O(8) bond length is 1.29 Å. In the forty-fifth C site, C(60) is bonded in a bent 120 degrees geometry to one C(42), one O(12), and one O(9) atom. The C(60)-O(12) bond length is 1.27 Å. The C(60)-O(9) bond length is 1.29 Å. In the forty-sixth C site, C(61) is bonded in a trigonal planar geometry to one C(64,65,66); one C(76,77,78); and one C(79) atom. The C(61)-C(64,65,66) bond length is 1.40 Å. The C(61)-C(76,77,78) bond length is 1.40 Å. The C(61)-C(79) bond length is 1.49 Å. In the forty-seventh C site, C(62) is bonded in a trigonal planar geometry to one C(64,65,66); one C(76,77,78); and one C(80) atom. The C(62)-C(64,65,66) bond length is 1.40 Å. The C(62)-C(76,77,78) bond length is 1.40 Å. The C(62)-C(80) bond length is 1.49 Å. In the forty-eighth C site, C(63) is bonded in a trigonal planar geometry to one C(64,65,66); one C(76,77,78); and one C(81) atom. The C(63)-C(64,65,66) bond length is 1.40 Å. The C(63)-C(76,77,78) bond length is 1.40 Å. The C(63)-C(81) bond length is 1.49 Å. In the forty-ninth C site, C(64,65,66) is bonded in a distorted trigonal planar geometry to one C(61); one C(67,68,69); and one H(25,26,27) atom. The C(64,65,66)-C(67,68,69) bond length is 1.39 Å. The C(64,65,66)-H(25,26,27) bond length is 1.09 Å. In the fiftieth C site, C(67,68,69) is bonded in a distorted single-bond geometry to one C(64,65,66); one C(70,72); and one H(28,29,30) atom. The C(67,68,69)-C(70,72) bond length is 1.41 Å. The C(67,68,69)-H(28,29,30) bond length is 1.09 Å. In the fifty-first C site, C(70,72) is bonded in a trigonal planar geometry to one C(13,15); one C(67,68,69); and one C(73,74,75) atom. The C(70,72)-C(73,74,75) bond length is 1.41 Å. In the fifty-second C site, C(71) is bonded in a trigonal planar geometry to one C(14); one C(67,68,69); and one C(73,74,75) atom. The C(71)-C(67,68,69) bond length is 1.41 Å. The C(71)-C(73,74,75) bond length is 1.41 Å. In the fifty-third C site, C(73,74,75) is bonded in a distorted trigonal planar geometry to one C(70,72); one C(76,77,78); and one H(31,32,33) atom. The C(73,74,75)-C(76,77,78) bond length is 1.39 Å. The C(73,74,75)-H(31,32,33) bond length is 1.09 Å. In the fifty-fourth C site, C(76,77,78) is bonded in a distorted single-bond geometry to one C(61); one C(73,74,75); and one H(34,35,36) atom. The C(76,77,78)-H(34,35,36) bond length is 1.09 Å. In the fifty-fifth C site, C(79) is bonded in a bent 120 degrees geometry to one C(61), one O(13), and one O(16) atom. The C(79)-O(13) bond length is 1.30 Å. The C(79)-O(16) bond length is 1.27 Å. In the fifty-sixth C site, C(80) is bonded in a bent 120 degrees geometry to one C(62), one O(14), and one O(17) atom. The C(80)-O(14) bond length is 1.30 Å. The C(80)-O(17) bond length is 1.27 Å. In the fifty-seventh C site, C(81) is bonded in a bent 120 degrees geometry to one C(63), one O(15), and one O(18) atom. The C(81)-O(15) bond length is 1.30 Å. The C(81)-O(18) bond length is 1.27 Å. In the fifty-eighth C site, C(82) is bonded in a trigonal planar geometry to one C(100); one C(85,86,87); and one C(97,98,99) atom. The C(82)-C(100) bond length is 1.50 Å. The C(82)-C(85,86,87) bond length is 1.40 Å. The C(82)-C(97,98,99) bond length is 1.40 Å. In the fifty-ninth C site, C(83) is bonded in a trigonal planar geometry to one C(101); one C(85,86,87); and one C(97,98,99) atom. The C(83)-C(101) bond length is 1.50 Å. The C(83)-C(85,86,87) bond length is 1.40 Å. The C(83)-C(97,98,99) bond length is 1.40 Å. In the sixtieth C site, C(84) is bonded in a trigonal planar geometry to one C(102); one C(85,86,87); and one C(97,98,99) atom. The C(84)-C(102) bond length is 1.50 Å. The C(84)-C(85,86,87) bond length is 1.40 Å. The C(84)-C(97,98,99) bond length is 1.40 Å. In the sixty-first C site, C(85,86,87) is bonded in a distorted single-bond geometry to one C(82); one C(88,90); and one H(37,38,39) atom. The C(85,86,87)-C(88,90) bond length is 1.39 Å. The C(85,86,87)-H(37,38,39) bond length is 1.09 Å. In the sixty-second C site, C(88,90) is bonded in a distorted trigonal planar geometry to one C(85,86,87); one C(91,93); and one H(40,41,42) atom. The C(88,90)-C(91,93) bond length is 1.41 Å. The C(88,90)-H(40,41,42) bond length is 1.09 Å. In the sixty-third C site, C(89) is bonded in a distorted trigonal planar geometry to one C(85,86,87); one C(92); and one H(40,41,42) atom. The C(89)-C(85,86,87) bond length is 1.39 Å. The C(89)-C(92) bond length is 1.41 Å. The C(89)-H(40,41,42) bond length is 1.09 Å. In the sixty-fourth C site, C(91,93) is bonded in a trigonal planar geometry to one C(16,18); one C(88,90); and one C(94,96) atom. The C(91,93)-C(94,96) bond length is 1.41 Å. In the sixty-fifth C site, C(92) is bonded in a trigonal planar geometry to one C(17), one C(89), and one C(95) atom. The C(92)-C(95) bond length is 1.41 Å. In the sixty-sixth C site, C(94,96) is bonded in a distorted single-bond geometry to one C(91,93); one C(97,98,99); and one H(43,44,45) atom. The C(94,96)-C(97,98,99) bond length is 1.39 Å. The C(94,96)-H(43,44,45) bond length is 1.09 Å. In the sixty-seventh C site, C(95) is bonded in a distorted single-bond geometry to one C(92); one C(97,98,99); and one H(43,44,45) atom. The C(95)-C(97,98,99) bond length is 1.39 Å. The C(95)-H(43,44,45) bond length is 1.09 Å. In the sixty-eighth C site, C(97,98,99) is bonded in a distorted trigonal planar geometry to one C(82); one C(94,96); and one H(46,47,48) atom. The C(97,98,99)-H(46,47,48) bond length is 1.09 Å. In the sixty-ninth C site, C(100) is bonded in a distorted bent 120 degrees geometry to one C(82), one O(19), and one O(22) atom. The C(100)-O(19) bond length is 1.27 Å. The C(100)-O(22) bond length is 1.28 Å. In the seventieth C site, C(101) is bonded in a distorted bent 120 degrees geometry to one C(83), one O(20), and one O(23) atom. The C(101)-O(20) bond length is 1.27 Å. The C(101)-O(23) bond length is 1.29 Å. In the seventy-first C site, C(102) is bonded in a distorted bent 120 degrees geometry to one C(84), one O(21), and one O(24) atom. The C(102)-O(21) bond length is 1.27 Å. The C(102)-O(24) bond length is 1.28 Å. There are twenty-nine inequivalent H sites. In the first H site, H(1,2,3) is bonded in a single-bond geometry to one C(22,23,24) atom. In the second H site, H(4,5,6) is bonded in a single-bond geometry to one C(25,26,27) atom. In the third H site, H(7,8,9) is bonded in a single-bond geometry to one C(31,32,33) atom. In the fourth H site, H(10,11,12) is bonded in a single-bond geometry to one C(34,35,36) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(43) atom. In the sixth H site, H(14,15) is bonded in a single-bond geometry to one C(44) atom. In the seventh H site, H(16,17,18) is bonded in a single-bond geometry to one C(46) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(52) atom. In the ninth H site, H(20,21) is bonded in a single-bond geometry to one C(53) atom. In the tenth H site, H(22,24) is bonded in a single-bond geometry to one C(55) atom. In the eleventh H site, H(23) is bonded in a single-bond geometry to one C(56) atom. In the twelfth H site, H(25,26,27) is bonded in a single-bond geometry to one C(64,65,66) atom. In the thirteenth H site, H(28,29,30) is bonded in a single-bond geometry to one C(67,68,69) atom. In the fourteenth H site, H(31,32,33) is bonded in a single-bond geometry to one C(73,74,75) atom. In the fifteenth H site, H(34,35,36) is bonded in a single-bond geometry to one C(76,77,78) atom. In the sixteenth H site, H(37,38,39) is bonded in a single-bond geometry to one C(85,86,87) atom. In the seventeenth H site, H(40,41,42) is bonded in a single-bond geometry to one C(88,90) atom. In the eighteenth H site, H(43,44,45) is bonded in a single-bond geometry to one C(94,96) atom. In the nineteenth H site, H(46,47,48) is bonded in a single-bond geometry to one C(97,98,99) atom. In the twentieth H site, H(49) is bonded in a single-bond geometry to one O(13) and one O(25) atom. The H(49)-O(13) bond length is 1.73 Å. The H(49)-O(25) bond length is 0.99 Å. In the twenty-first H site, H(51) is bonded in a single-bond geometry to one O(15) and one O(27) atom. The H(51)-O(15) bond length is 1.73 Å. The H(51)-O(27) bond length is 0.99 Å. In the twenty-second H site, H(52) is bonded in a single-bond geometry to one O(25) atom. The H(52)-O(25) bond length is 0.97 Å. In the twenty-third H site, H(54) is bonded in a single-bond geometry to one O(27) atom. The H(54)-O(27) bond length is 0.97 Å. In the twenty-fourth H site, H(55) is bonded in a single-bond geometry to one O(28) atom. The H(55)-O(28) bond length is 0.99 Å. In the twenty-fifth H site, H(56) is bonded in a single-bond geometry to one O(29) atom. The H(56)-O(29) bond length is 0.99 Å. In the twenty-sixth H site, H(57) is bonded in a single-bond geometry to one O(30) atom. The H(57)-O(30) bond length is 0.99 Å. In the twenty-seventh H site, H(58) is bonded in a single-bond geometry to one O(28) atom. The H(58)-O(28) bond length is 0.98 Å. In the twenty-eighth H site, H(59) is bonded in a single-bond geometry to one O(29) atom. The H(59)-O(29) bond length is 0.98 Å. In the twenty-ninth H site, H(60) is bonded in a single-bond geometry to one O(30) atom. The H(60)-O(30) bond length is 0.98 Å. There are eight inequivalent S sites. In the first S site, S(1,3) is bonded in an L-shaped geometry to one C(1,3) and one C(7,9) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one C(2) and one C(8) atom. In the third S site, S(4,6) is bonded in an L-shaped geometry to one C(1,3) and one C(10) atom. In the fourth S site, S(5) is bonded in an L-shaped geometry to one C(11) and one C(2) atom. In the fifth S site, S(7,9) is bonded in an L-shaped geometry to one C(13,15) and one C(4,6) atom. In the sixth S site, S(8) is bonded in an L-shaped geometry to one C(14) and one C(5) atom. In the seventh S site, S(10,12) is bonded in an L-shaped geometry to one C(16,18) and one C(4,6) atom. In the eighth S site, S(11) is bonded in an L-shaped geometry to one C(17) and one C(5) atom. There are twenty-nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(37) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(38) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(39) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(37) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(38) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(39) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Zn(1) and one C(58) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Zn(2) and one C(59) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Zn(3) and one C(60) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Zn(1), one Zn(4), and one C(58) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Zn(2), one Zn(5), and one C(59) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Zn(3), one Zn(6), and one C(60) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Zn(1), one C(79), and one H(49) atom. In the fourteenth O site, O(14) is bonded in a 2-coordinate geometry to one Zn(2) and one C(80) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Zn(3), one C(81), and one H(51) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(79) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(80) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(81) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 150 degrees geometry to one Zn(5) and one C(100) atom. In the twentieth O site, O(20) is bonded in a distorted bent 150 degrees geometry to one Zn(6) and one C(101) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 150 degrees geometry to one Zn(4) and one C(102) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(100) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(101) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(102) atom. In the twenty-fifth O site, O(25) is bonded in a water-like geometry to one H(49) and one H(52) atom. In the twenty-sixth O site, O(27) is bonded in a water-like geometry to one H(51) and one H(54) atom. In the twenty-seventh O site, O(28) is bonded in a distorted trigonal non-coplanar geometry to one Zn(4), one H(55), and one H(58) atom. In the twenty-eighth O site, O(29) is bonded in a distorted trigonal non-coplanar geometry to one Zn(5), one H(56), and one H(59) atom. In the twenty-ninth O site, O(30) is bonded in a distorted trigonal non-coplanar geometry to one Zn(6), one H(57), and one H(60) atom. Linkers: 6 [O]C(=O)c1ccc(C2=C(c3ccc(C([O])=O)cc3)SC(=C3SC(c4ccc(C([O])=O)cc4)=C(c4ccc(C([O])=O)cc4)S3)S2)cc1. Metal clusters: 12 [Zn]. The MOF has largest included sphere 5.48 A, density 1.27 g/cm3, surface area 4096.33 m2/g, accessible volume 0.32 cm3/g