CdC8H10(N2S)2(CH)8C9H8O4 is Indium-derived structured and crystallizes in the tetragonal P4_2/n space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules; four 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and four CdC8H10(N2S)2 clusters. In each CdC8H10(N2S)2 cluster, Cd(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent S(1) atoms. Both Cd(1)-N(1) bond lengths are 2.53 Å. Both Cd(1)-N(2) bond lengths are 2.48 Å. Both Cd(1)-S(1) bond lengths are 2.60 Å. There are four inequivalent C sites. In the first C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(9)-N(2) bond length is 1.34 Å. The C(9)-H(9) bond length is 1.09 Å. In the second C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(13)-N(2) bond length is 1.35 Å. The C(13)-H(12) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(9) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(13) is bonded in a single-bond geometry to one S(1) atom. The H(13)-S(1) bond length is 1.35 Å. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. S(1) is bonded in a distorted single-bond geometry to one Cd(1) and one H(13) atom. Linkers: 4 c1cc(OCC(COc2ccncc2)(COc2ccncc2)COc2ccncc2)ccn1. Metal clusters: 4 S[Cd]S. The MOF has largest included sphere 6.97 A, density 1.05 g/cm3, surface area 4814.09 m2/g, accessible volume 0.46 cm3/g