SmC12N3H9O9F4CH3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one SmC12N3H9O9F4 cluster. In the SmC12N3H9O9F4 cluster, Sm(1) is bonded in a 9-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(1) atoms. The Sm(1)-O(2) bond length is 2.46 Å. The Sm(1)-O(3) bond length is 2.45 Å. The Sm(1)-O(4) bond length is 2.48 Å. The Sm(1)-O(5) bond length is 2.36 Å. The Sm(1)-O(6) bond length is 2.60 Å. The Sm(1)-O(7) bond length is 2.49 Å. The Sm(1)-O(8) bond length is 2.47 Å. There is one shorter (2.42 Å) and one longer (2.53 Å) Sm(1)-O(1) bond length. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(3) and one F(3,4) atom. The C(1)-C(3) bond length is 1.40 Å. The C(1)-F(3,4) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(8) atom. The C(2)-C(3) bond length is 1.52 Å. The C(2)-O(3) bond length is 1.26 Å. The C(2)-O(8) bond length is 1.26 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(5) atom. The C(3)-C(5) bond length is 1.39 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(10), one C(6), and one C(9) atom. The C(4)-C(10) bond length is 1.53 Å. The C(4)-C(6) bond length is 1.39 Å. The C(4)-C(9) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one F(3,4) atom. The C(5)-F(3,4) bond length is 1.36 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one F(1) atom. The C(6)-F(1) bond length is 1.37 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(6) atom. The C(7)-O(1) bond length is 1.30 Å. The C(7)-O(6) bond length is 1.26 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(3), one H(5), and one O(7) atom. The C(8)-N(3) bond length is 1.34 Å. The C(8)-H(5) bond length is 1.10 Å. The C(8)-O(7) bond length is 1.25 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(4) and one F(2) atom. The C(9)-F(2) bond length is 1.37 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(5), and one O(9) atom. The C(10)-O(5) bond length is 1.28 Å. The C(10)-O(9) bond length is 1.25 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one N(2), one H(6), and one O(2) atom. The C(11)-N(2) bond length is 1.32 Å. The C(11)-H(6) bond length is 1.10 Å. The C(11)-O(2) bond length is 1.26 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one N(1), one H(7), and one O(4) atom. The C(12)-N(1) bond length is 1.32 Å. The C(12)-H(7) bond length is 1.10 Å. The C(12)-O(4) bond length is 1.26 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(12), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.02 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one H(3), and one H(4) atom. The N(2)-H(3) bond length is 1.03 Å. The N(2)-H(4) bond length is 1.01 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(8), one H(8), and one H(9) atom. The N(3)-H(8) bond length is 1.02 Å. The N(3)-H(9) bond length is 1.01 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(3) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Sm(1) and one C(7) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Sm(1) and one C(11) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sm(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Sm(1) and one C(12) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Sm(1) and one C(10) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Sm(1) and one C(7) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Sm(1) and one C(8) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Sm(1) and one C(2) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(10) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(6) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(9) atom. In the third F site, F(3,4) is bonded in a single-bond geometry to one C(1) atom. Linkers: 2 [O]C(=O)c1c(F)c(F)c(C([O])=O)c(F)c1F. Metal clusters: 2 [Sm]. RCSR code: bex. The MOF has largest included sphere 4.15 A, density 1.56 g/cm3, surface area 3480.57 m2/g, accessible volume 0.22 cm3/g