(ZnC20NH12S(O2F)2)2CF2 crystallizes in the triclinic P-1 space group. The structure consists of four difluoromethane molecules inside a ZnC20NH12S(O2F)2 framework. In each ZnC20NH12S(O2F)2 framework, there are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(4), one O(12), one O(16), one O(4), and one O(6) atom. The Zn(1)-N(4) bond length is 2.08 Å. The Zn(1)-O(12) bond length is 2.07 Å. The Zn(1)-O(16) bond length is 2.06 Å. The Zn(1)-O(4) bond length is 2.03 Å. The Zn(1)-O(6) bond length is 2.08 Å. In the second Zn site, Zn(2) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(8), and one O(9) atom. The Zn(2)-N(1) bond length is 2.04 Å. The Zn(2)-O(1) bond length is 2.05 Å. The Zn(2)-O(2) bond length is 2.04 Å. The Zn(2)-O(8) bond length is 2.07 Å. The Zn(2)-O(9) bond length is 2.11 Å. In the third Zn site, Zn(3) is bonded in a square pyramidal geometry to one N(3), one O(13), one O(15), one O(3), and one O(5) atom. The Zn(3)-N(3) bond length is 2.04 Å. The Zn(3)-O(13) bond length is 2.11 Å. The Zn(3)-O(15) bond length is 2.08 Å. The Zn(3)-O(3) bond length is 2.03 Å. The Zn(3)-O(5) bond length is 2.04 Å. In the fourth Zn site, Zn(4) is bonded in a distorted trigonal bipyramidal geometry to one N(2), one O(10), one O(11), one O(14), and one O(7) atom. The Zn(4)-N(2) bond length is 2.08 Å. The Zn(4)-O(10) bond length is 2.07 Å. The Zn(4)-O(11) bond length is 2.08 Å. The Zn(4)-O(14) bond length is 2.07 Å. The Zn(4)-O(7) bond length is 2.04 Å. There are eighty inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(25) and one H(1) atom. The C(1)-C(25) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(26) and one H(2) atom. The C(2)-C(26) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(25) and one H(3) atom. The C(3)-C(25) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(42) and one H(4) atom. The C(4)-C(42) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(10), one C(26), and one H(5) atom. The C(5)-C(10) bond length is 1.39 Å. The C(5)-C(26) bond length is 1.40 Å. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(24), one C(30), and one C(34) atom. The C(6)-C(24) bond length is 1.50 Å. The C(6)-C(30) bond length is 1.40 Å. The C(6)-C(34) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(19), one C(35), and one C(36) atom. The C(7)-C(19) bond length is 1.50 Å. The C(7)-C(35) bond length is 1.40 Å. The C(7)-C(36) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(20) and one H(6) atom. The C(8)-C(20) bond length is 1.40 Å. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(42) and one H(7) atom. The C(9)-C(42) bond length is 1.40 Å. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(20), one C(5), and one H(8) atom. The C(10)-C(20) bond length is 1.40 Å. The C(10)-H(8) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(42), one O(2), and one O(4) atom. The C(11)-C(42) bond length is 1.49 Å. The C(11)-O(2) bond length is 1.27 Å. The C(11)-O(4) bond length is 1.28 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(11), and one O(15) atom. The C(12)-C(14) bond length is 1.50 Å. The C(12)-O(11) bond length is 1.28 Å. The C(12)-O(15) bond length is 1.27 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(1), and one O(6) atom. The C(13)-C(20) bond length is 1.49 Å. The C(13)-O(1) bond length is 1.27 Å. The C(13)-O(6) bond length is 1.27 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(51), and one C(53) atom. The C(14)-C(51) bond length is 1.40 Å. The C(14)-C(53) bond length is 1.40 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(16), one C(33), and one C(37) atom. The C(15)-C(16) bond length is 1.50 Å. The C(15)-C(33) bond length is 1.40 Å. The C(15)-C(37) bond length is 1.40 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(13), and one O(14) atom. The C(16)-O(13) bond length is 1.27 Å. The C(16)-O(14) bond length is 1.28 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(3), and one O(7) atom. The C(17)-C(26) bond length is 1.49 Å. The C(17)-O(3) bond length is 1.27 Å. The C(17)-O(7) bond length is 1.28 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(27) atom. The C(18)-C(21) bond length is 1.41 Å. The C(18)-C(23) bond length is 1.46 Å. The C(18)-C(27) bond length is 1.41 Å. In the nineteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(12), and one O(8) atom. The C(19)-O(12) bond length is 1.28 Å. The C(19)-O(8) bond length is 1.27 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(8) atom. In the twenty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(18), one C(29), and one H(9) atom. The C(21)-C(29) bond length is 1.39 Å. The C(21)-H(9) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(10), and one O(5) atom. The C(22)-C(25) bond length is 1.49 Å. The C(22)-O(10) bond length is 1.27 Å. The C(22)-O(5) bond length is 1.27 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(18), one C(39), and one S(2) atom. The C(23)-C(39) bond length is 1.38 Å. The C(23)-S(2) bond length is 1.74 Å. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(16), and one O(9) atom. The C(24)-O(16) bond length is 1.28 Å. The C(24)-O(9) bond length is 1.27 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(1), one C(22), and one C(3) atom. In the twenty-sixth C site, C(26) is bonded in a trigonal planar geometry to one C(17), one C(2), and one C(5) atom. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(18) and one H(10) atom. The C(27)-H(10) bond length is 1.09 Å. In the twenty-eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(11) atom. The C(28)-N(1) bond length is 1.35 Å. The C(28)-H(11) bond length is 1.09 Å. In the twenty-ninth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(1), and one H(12) atom. The C(29)-N(1) bond length is 1.35 Å. The C(29)-H(12) bond length is 1.09 Å. In the thirtieth C site, C(30) is bonded in a distorted single-bond geometry to one C(35), one C(6), and one H(13) atom. The C(30)-C(35) bond length is 1.39 Å. The C(30)-H(13) bond length is 1.09 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one C(45), one C(46), and one C(49) atom. The C(31)-C(45) bond length is 1.37 Å. The C(31)-C(46) bond length is 1.45 Å. The C(31)-C(49) bond length is 1.51 Å. In the thirty-second C site, C(32) is bonded in a trigonal planar geometry to one C(46), one C(56), and one S(2) atom. The C(32)-C(46) bond length is 1.40 Å. The C(32)-C(56) bond length is 1.49 Å. The C(32)-S(2) bond length is 1.71 Å. In the thirty-third C site, C(33) is bonded in a distorted single-bond geometry to one C(15) and one H(14) atom. The C(33)-H(14) bond length is 1.09 Å. In the thirty-fourth C site, C(34) is bonded in a distorted single-bond geometry to one C(6) and one H(15) atom. The C(34)-H(15) bond length is 1.09 Å. In the thirty-fifth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(30), one C(7), and one H(16) atom. The C(35)-H(16) bond length is 1.09 Å. In the thirty-sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(7) and one H(17) atom. The C(36)-H(17) bond length is 1.09 Å. In the thirty-seventh C site, C(37) is bonded in a distorted single-bond geometry to one C(15) and one H(18) atom. The C(37)-H(18) bond length is 1.09 Å. In the thirty-eighth C site, C(38) is bonded in a distorted single-bond geometry to one C(40), one C(41), and one H(19) atom. The C(38)-C(40) bond length is 1.39 Å. The C(38)-C(41) bond length is 1.41 Å. The C(38)-H(19) bond length is 1.09 Å. In the thirty-ninth C site, C(39) is bonded in a distorted single-bond geometry to one C(23), one C(46), and one H(20) atom. The C(39)-C(46) bond length is 1.43 Å. The C(39)-H(20) bond length is 1.09 Å. In the fortieth C site, C(40) is bonded in a distorted trigonal planar geometry to one C(38), one N(2), and one H(21) atom. The C(40)-N(2) bond length is 1.34 Å. The C(40)-H(21) bond length is 1.09 Å. In the forty-first C site, C(41) is bonded in a trigonal planar geometry to one C(38), one C(48), and one C(50) atom. The C(41)-C(48) bond length is 1.41 Å. The C(41)-C(50) bond length is 1.46 Å. In the forty-second C site, C(42) is bonded in a trigonal planar geometry to one C(11), one C(4), and one C(9) atom. In the forty-third C site, C(43) is bonded in a distorted trigonal planar geometry to one C(48), one N(2), and one H(22) atom. The C(43)-C(48) bond length is 1.38 Å. The C(43)-N(2) bond length is 1.35 Å. The C(43)-H(22) bond length is 1.09 Å. In the forty-fourth C site, C(44) is bonded in a water-like geometry to one C(45), one F(2), and one F(5) atom. The C(44)-C(45) bond length is 1.51 Å. The C(44)-F(2) bond length is 1.38 Å. The C(44)-F(5) bond length is 1.39 Å. In the forty-fifth C site, C(45) is bonded in a trigonal planar geometry to one C(31), one C(44), and one C(57) atom. The C(45)-C(57) bond length is 1.46 Å. In the forty-sixth C site, C(46) is bonded in a trigonal planar geometry to one C(31), one C(32), and one C(39) atom. In the forty-seventh C site, C(47) is bonded in a distorted single-bond geometry to one C(50), one C(57), and one H(23) atom. The C(47)-C(50) bond length is 1.38 Å. The C(47)-C(57) bond length is 1.42 Å. The C(47)-H(23) bond length is 1.09 Å. In the forty-eighth C site, C(48) is bonded in a distorted single-bond geometry to one C(41), one C(43), and one H(24) atom. The C(48)-H(24) bond length is 1.09 Å. In the forty-ninth C site, C(49) is bonded in a water-like geometry to one C(31), one F(4), and one F(6) atom. The C(49)-F(4) bond length is 1.37 Å. The C(49)-F(6) bond length is 1.39 Å. In the fiftieth C site, C(50) is bonded in a trigonal planar geometry to one C(41), one C(47), and one S(1) atom. The C(50)-S(1) bond length is 1.74 Å. In the fifty-first C site, C(51) is bonded in a distorted single-bond geometry to one C(14) and one H(25,26) atom. The C(51)-H(25,26) bond length is 1.09 Å. In the fifty-second C site, C(53) is bonded in a distorted single-bond geometry to one C(14) and one H(25,26) atom. The C(53)-H(25,26) bond length is 1.09 Å. In the fifty-third C site, C(54) is bonded in a distorted trigonal non-coplanar geometry to one C(55), one H(27), one H(28), and one H(29) atom. The C(54)-C(55) bond length is 1.49 Å. The C(54)-H(27) bond length is 1.10 Å. The C(54)-H(28) bond length is 1.10 Å. The C(54)-H(29) bond length is 1.10 Å. In the fifty-fourth C site, C(55) is bonded in a trigonal planar geometry to one C(54), one C(57), and one S(1) atom. The C(55)-C(57) bond length is 1.40 Å. The C(55)-S(1) bond length is 1.72 Å. In the fifty-fifth C site, C(56) is bonded in a distorted trigonal non-coplanar geometry to one C(32), one H(30), one H(31), and one H(32) atom. The C(56)-H(30) bond length is 1.10 Å. The C(56)-H(31) bond length is 1.10 Å. The C(56)-H(32) bond length is 1.10 Å. In the fifty-sixth C site, C(57) is bonded in a trigonal planar geometry to one C(45), one C(47), and one C(55) atom. In the fifty-seventh C site, C(58) is bonded in a distorted trigonal planar geometry to one C(61), one C(69), and one H(33) atom. The C(58)-C(61) bond length is 1.40 Å. The C(58)-C(69) bond length is 1.39 Å. The C(58)-H(33) bond length is 1.09 Å. In the fifty-eighth C site, C(59) is bonded in a trigonal planar geometry to one C(61), one C(78), and one S(3) atom. The C(59)-C(61) bond length is 1.46 Å. The C(59)-C(78) bond length is 1.38 Å. The C(59)-S(3) bond length is 1.74 Å. In the fifty-ninth C site, C(60) is bonded in a distorted trigonal planar geometry to one C(61), one C(70), and one H(34) atom. The C(60)-C(61) bond length is 1.41 Å. The C(60)-C(70) bond length is 1.38 Å. The C(60)-H(34) bond length is 1.09 Å. In the sixtieth C site, C(61) is bonded in a trigonal planar geometry to one C(58), one C(59), and one C(60) atom. In the sixty-first C site, C(62) is bonded in a distorted single-bond geometry to one C(63), one C(65), and one H(35) atom. The C(62)-C(63) bond length is 1.39 Å. The C(62)-C(65) bond length is 1.41 Å. The C(62)-H(35) bond length is 1.09 Å. In the sixty-second C site, C(63) is bonded in a distorted trigonal planar geometry to one C(62), one N(4), and one H(36) atom. The C(63)-N(4) bond length is 1.34 Å. The C(63)-H(36) bond length is 1.09 Å. In the sixty-third C site, C(64) is bonded in a distorted single-bond geometry to one C(65), one C(66), and one H(37) atom. The C(64)-C(65) bond length is 1.41 Å. The C(64)-C(66) bond length is 1.38 Å. The C(64)-H(37) bond length is 1.09 Å. In the sixty-fourth C site, C(65) is bonded in a trigonal planar geometry to one C(62), one C(64), and one C(68) atom. The C(65)-C(68) bond length is 1.46 Å. In the sixty-fifth C site, C(66) is bonded in a distorted trigonal planar geometry to one C(64), one N(4), and one H(38) atom. The C(66)-N(4) bond length is 1.35 Å. The C(66)-H(38) bond length is 1.09 Å. In the sixty-sixth C site, C(67) is bonded in a distorted single-bond geometry to one C(68), one C(71), and one H(39) atom. The C(67)-C(68) bond length is 1.38 Å. The C(67)-C(71) bond length is 1.42 Å. The C(67)-H(39) bond length is 1.08 Å. In the sixty-seventh C site, C(68) is bonded in a trigonal planar geometry to one C(65), one C(67), and one S(4) atom. The C(68)-S(4) bond length is 1.73 Å. In the sixty-eighth C site, C(69) is bonded in a distorted bent 120 degrees geometry to one C(58), one N(3), and one H(40) atom. The C(69)-N(3) bond length is 1.35 Å. The C(69)-H(40) bond length is 1.09 Å. In the sixty-ninth C site, C(70) is bonded in a distorted bent 120 degrees geometry to one C(60), one N(3), and one H(41) atom. The C(70)-N(3) bond length is 1.35 Å. The C(70)-H(41) bond length is 1.09 Å. In the seventieth C site, C(71) is bonded in a trigonal planar geometry to one C(67), one C(72), and one C(80) atom. The C(71)-C(72) bond length is 1.40 Å. The C(71)-C(80) bond length is 1.46 Å. In the seventy-first C site, C(72) is bonded in a trigonal planar geometry to one C(71), one C(75), and one S(4) atom. The C(72)-C(75) bond length is 1.49 Å. The C(72)-S(4) bond length is 1.72 Å. In the seventy-second C site, C(73) is bonded in a water-like geometry to one C(74), one F(10), and one F(8) atom. The C(73)-C(74) bond length is 1.51 Å. The C(73)-F(10) bond length is 1.39 Å. The C(73)-F(8) bond length is 1.37 Å. In the seventy-third C site, C(74) is bonded in a trigonal planar geometry to one C(73), one C(80), and one C(82) atom. The C(74)-C(80) bond length is 1.37 Å. The C(74)-C(82) bond length is 1.45 Å. In the seventy-fourth C site, C(75) is bonded in a distorted trigonal non-coplanar geometry to one C(72), one H(42), one H(43), and one H(44) atom. The C(75)-H(42) bond length is 1.10 Å. The C(75)-H(43) bond length is 1.10 Å. The C(75)-H(44) bond length is 1.10 Å. In the seventy-fifth C site, C(76) is bonded in a water-like geometry to one C(80), one F(12), and one F(9) atom. The C(76)-C(80) bond length is 1.51 Å. The C(76)-F(12) bond length is 1.39 Å. The C(76)-F(9) bond length is 1.38 Å. In the seventy-sixth C site, C(78) is bonded in a distorted single-bond geometry to one C(59), one C(82), and one H(45) atom. The C(78)-C(82) bond length is 1.43 Å. The C(78)-H(45) bond length is 1.09 Å. In the seventy-seventh C site, C(79) is bonded in a trigonal planar geometry to one C(81), one C(82), and one S(3) atom. The C(79)-C(81) bond length is 1.49 Å. The C(79)-C(82) bond length is 1.40 Å. The C(79)-S(3) bond length is 1.71 Å. In the seventy-eighth C site, C(80) is bonded in a trigonal planar geometry to one C(71), one C(74), and one C(76) atom. In the seventy-ninth C site, C(81) is bonded in a distorted trigonal non-coplanar geometry to one C(79), one H(46), one H(47), and one H(48) atom. The C(81)-H(46) bond length is 1.10 Å. The C(81)-H(47) bond length is 1.10 Å. The C(81)-H(48) bond length is 1.10 Å. In the eightieth C site, C(82) is bonded in a trigonal planar geometry to one C(74), one C(78), and one C(79) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(28), and one C(29) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(4), one C(40), and one C(43) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(3), one C(69), and one C(70) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(63), and one C(66) atom. There are forty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(27) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(28) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(29) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(30) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(33) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(34) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(35) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(36) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(37) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(38) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(39) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(40) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(43) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(47) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(48) atom. In the twenty-fifth H site, H(25,26) is bonded in a single-bond geometry to one C(51) atom. In the twenty-sixth H site, H(27) is bonded in a single-bond geometry to one C(54) atom. In the twenty-seventh H site, H(28) is bonded in a single-bond geometry to one C(54) atom. In the twenty-eighth H site, H(29) is bonded in a single-bond geometry to one C(54) atom. In the twenty-ninth H site, H(30) is bonded in a single-bond geometry to one C(56) atom. In the thirtieth H site, H(31) is bonded in a single-bond geometry to one C(56) atom. In the thirty-first H site, H(32) is bonded in a single-bond geometry to one C(56) atom. In the thirty-second H site, H(33) is bonded in a single-bond geometry to one C(58) atom. In the thirty-third H site, H(34) is bonded in a single-bond geometry to one C(60) atom. In the thirty-fourth H site, H(35) is bonded in a single-bond geometry to one C(62) atom. In the thirty-fifth H site, H(36) is bonded in a single-bond geometry to one C(63) atom. In the thirty-sixth H site, H(37) is bonded in a single-bond geometry to one C(64) atom. In the thirty-seventh H site, H(38) is bonded in a single-bond geometry to one C(66) atom. In the thirty-eighth H site, H(39) is bonded in a single-bond geometry to one C(67) atom. In the thirty-ninth H site, H(40) is bonded in a single-bond geometry to one C(69) atom. In the fortieth H site, H(41) is bonded in a single-bond geometry to one C(70) atom. In the forty-first H site, H(42) is bonded in a single-bond geometry to one C(75) atom. In the forty-second H site, H(43) is bonded in a single-bond geometry to one C(75) atom. In the forty-third H site, H(44) is bonded in a single-bond geometry to one C(75) atom. In the forty-fourth H site, H(45) is bonded in a single-bond geometry to one C(78) atom. In the forty-fifth H site, H(46) is bonded in a single-bond geometry to one C(81) atom. In the forty-sixth H site, H(47) is bonded in a single-bond geometry to one C(81) atom. In the forty-seventh H site, H(48) is bonded in a single-bond geometry to one C(81) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(50) and one C(55) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one C(23) and one C(32) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one C(59) and one C(79) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one C(68) and one C(72) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(13) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(11) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(17) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(11) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(22) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(17) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(19) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(24) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(22) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(12) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(19) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(16) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(16) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(12) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(24) atom. There are eight inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one C(44) atom. In the second F site, F(4) is bonded in a single-bond geometry to one C(49) atom. In the third F site, F(5) is bonded in a single-bond geometry to one C(44) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one C(49) atom. In the fifth F site, F(8) is bonded in a single-bond geometry to one C(73) atom. In the sixth F site, F(9) is bonded in a single-bond geometry to one C(76) atom. In the seventh F site, F(10) is bonded in a single-bond geometry to one C(73) atom. In the eighth F site, F(12) is bonded in a single-bond geometry to one C(76) atom. Linkers: 4 Cc1sc(-c2ccncc2)cc1C1=C(c2cc(-c3ccncc3)sc2C)C(F)(F)C(F)(F)C1(F)F ,8 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4 ,2 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: sql. The MOF has largest included sphere 5.20 A, density 1.29 g/cm3, surface area 4232.99 m2/g, accessible volume 0.33 cm3/g