CuC8NH5O4(CH2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and two CuC8NH5O4 clusters. In each CuC8NH5O4 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(3), one O(6), and one O(8) atom. The Cu(1)-N(1) bond length is 2.19 Å. The Cu(1)-O(1) bond length is 2.01 Å. The Cu(1)-O(3) bond length is 2.01 Å. The Cu(1)-O(6) bond length is 2.00 Å. The Cu(1)-O(8) bond length is 2.01 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(1) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(1); one C(5,6); and one H(3,4) atom. The C(3)-C(5,6) bond length is 1.41 Å. The C(3)-H(3,4) bond length is 1.09 Å. In the third C site, C(5,6) is bonded in a trigonal planar geometry to one C(11,12); one C(3); and one C(7) atom. The C(5,6)-C(11,12) bond length is 1.45 Å. The C(5,6)-C(7) bond length is 1.41 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(5,6); one C(9); and one H(5,6) atom. The C(7)-C(9) bond length is 1.39 Å. The C(7)-H(5,6) bond length is 1.09 Å. In the fifth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one H(7) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(7) bond length is 1.09 Å. In the sixth C site, C(11,12) is bonded in a distorted single-bond geometry to one C(5,6) and one H(9,10) atom. The C(11,12)-H(9,10) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(13)-O(1) bond length is 1.28 Å. The C(13)-O(3) bond length is 1.27 Å. In the eighth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(8) atom. The C(22)-O(6) bond length is 1.28 Å. The C(22)-O(8) bond length is 1.28 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(9) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(11,12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(13) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(13) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(22) atom. In the fourth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(22) atom. Linkers: 4 [O]C(=O)CCCC([O])=O ,2 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 2 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 5.52 A, density 1.36 g/cm3, surface area 4340.34 m2/g, accessible volume 0.32 cm3/g