(CH2)2CHCdC21H17Br2(N2O3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, four 02329_fluka molecules, and two CdC21H17Br2(N2O3)2 clusters. In each CdC21H17Br2(N2O3)2 cluster, Cd(1) is bonded in a 5-coordinate geometry to one N(1), one N(3), one O(1), one O(2), and one O(4) atom. The Cd(1)-N(1) bond length is 2.21 Å. The Cd(1)-N(3) bond length is 2.24 Å. The Cd(1)-O(1) bond length is 2.57 Å. The Cd(1)-O(2) bond length is 2.36 Å. The Cd(1)-O(4) bond length is 2.23 Å. There are twenty-one inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(2) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(3) atom. The C(3)-N(1) bond length is 1.38 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(4), and one H(5) atom. The C(4)-N(2) bond length is 1.46 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(8) atom. The C(6)-N(3) bond length is 1.33 Å. The C(6)-N(4) bond length is 1.36 Å. The C(6)-H(8) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(3), and one H(9) atom. The C(7)-C(8) bond length is 1.37 Å. The C(7)-N(3) bond length is 1.38 Å. The C(7)-H(9) bond length is 1.08 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(4), and one H(10) atom. The C(8)-N(4) bond length is 1.38 Å. The C(8)-H(10) bond length is 1.08 Å. In the eighth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(11), and one H(12) atom. The C(9)-N(4) bond length is 1.46 Å. The C(9)-H(11) bond length is 1.10 Å. The C(9)-H(12) bond length is 1.10 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(17) atom. The C(11)-C(12) bond length is 1.42 Å. The C(11)-C(16) bond length is 1.40 Å. The C(11)-C(17) bond length is 1.48 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one O(3) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-O(3) bond length is 1.35 Å. In the eleventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(15) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(15) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(16) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(16) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one Br(1) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-Br(1) bond length is 1.91 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(11), one C(15), and one H(17) atom. The C(16)-H(17) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(1), and one O(2) atom. The C(17)-O(1) bond length is 1.30 Å. The C(17)-O(2) bond length is 1.27 Å. In the sixteenth C site, C(18) is bonded in a trigonal planar geometry to one C(19), one C(23), and one C(24) atom. The C(18)-C(19) bond length is 1.42 Å. The C(18)-C(23) bond length is 1.40 Å. The C(18)-C(24) bond length is 1.49 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one O(6) atom. The C(19)-O(6) bond length is 1.35 Å. In the eighteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(19) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-H(19) bond length is 1.09 Å. In the nineteenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one Br(2) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-Br(2) bond length is 1.91 Å. In the twentieth C site, C(23) is bonded in a distorted single-bond geometry to one C(18), one C(22), and one H(20) atom. The C(23)-H(20) bond length is 1.09 Å. In the twenty-first C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(4), and one O(5) atom. The C(24)-O(4) bond length is 1.28 Å. The C(24)-O(5) bond length is 1.28 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(4) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(6), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(23) atom. In the sixteenth H site, H(21) is bonded in a bent 150 degrees geometry to one O(1) and one O(3) atom. The H(21)-O(1) bond length is 1.52 Å. The H(21)-O(3) bond length is 1.03 Å. In the seventeenth H site, H(22) is bonded in a bent 150 degrees geometry to one O(5) and one O(6) atom. The H(22)-O(5) bond length is 1.57 Å. The H(22)-O(6) bond length is 1.03 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1), one C(17), and one H(21) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(17) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(12) and one H(21) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cd(1) and one C(24) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one C(24) and one H(22) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one C(19) and one H(22) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one C(15) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one C(22) atom. Linkers: 2 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 2.24 A, density 1.85 g/cm3, surface area 4043.94 m2/g, accessible volume 0.11 cm3/g