CuC4N5H4O3C3NH2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 1,2-diisopropenylhydrazine molecules and two CuC4N5H4O3 clusters. In each CuC4N5H4O3 cluster, Cu(1) is bonded in a square pyramidal geometry to one N(1), one N(2), one N(5), one O(1), and one O(3) atom. The Cu(1)-N(1) bond length is 2.00 Å. The Cu(1)-N(2) bond length is 1.98 Å. The Cu(1)-N(5) bond length is 1.99 Å. The Cu(1)-O(1) bond length is 2.02 Å. The Cu(1)-O(3) bond length is 2.23 Å. There are four inequivalent C sites. In the first C site, C(2) is bonded in a distorted water-like geometry to one C(1), one N(1), and one N(4) atom. The C(2)-C(1) bond length is 1.49 Å. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(4) bond length is 1.34 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(1) atom. The C(3)-N(5) bond length is 1.35 Å. The C(3)-H(1) bond length is 1.09 Å. In the third C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(4) atom. The C(7)-N(5) bond length is 1.35 Å. The C(7)-H(4) bond length is 1.09 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.25 Å. There are five inequivalent N sites. In the first N site, N(3) is bonded in a distorted water-like geometry to one N(2) and one N(4) atom. The N(3)-N(2) bond length is 1.33 Å. The N(3)-N(4) bond length is 1.34 Å. In the second N site, N(4) is bonded in a distorted water-like geometry to one C(2) and one N(3) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(7) atom. In the fourth N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(1), one N(1), and one N(3) atom. The N(2)-N(1) bond length is 1.33 Å. In the fifth N site, N(1) is bonded in a 3-coordinate geometry to one Cu(1), one C(2), and one N(2) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one O(3) atom. The H(5)-O(3) bond length is 0.99 Å. In the fourth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. The H(6)-O(3) bond length is 1.00 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cu(1), one H(5), and one H(6) atom. Linkers: 2 c1cc([N][N]c2ccncc2)ccn1 ,3 [O]C(=O)C1=NN=N[N]1 ,1 [O]C(=O)C1=N[N]N=N1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 1.67 A, density 1.99 g/cm3, surface area 3611.08 m2/g, accessible volume 0.09 cm3/g