ZnC10H10(NO)4(CH2)6 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and two ZnC10H10(NO)4 clusters. In each ZnC10H10(NO)4 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Zn(1)-N(1) bond lengths are 2.02 Å. Both Zn(1)-O(1) bond lengths are 1.98 Å. There are five inequivalent C sites. In the first C site, C(6) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(7) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-N(2) bond length is 1.35 Å. The C(6)-H(7) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(1), and one H(5) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-N(1) bond length is 1.38 Å. The C(4)-H(5) bond length is 1.08 Å. In the third C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(8), and one H(9) atom. The C(7)-N(2) bond length is 1.46 Å. The C(7)-H(8) bond length is 1.10 Å. The C(7)-H(9) bond length is 1.10 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(6) atom. The C(5)-N(2) bond length is 1.38 Å. The C(5)-H(6) bond length is 1.08 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(4), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(7) atom. There are five inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. Linkers: 2 [O]C(=O)CCCCC([O])=O ,2 c1cn(CCCCn2ccnc2)cn1 ,4 [c]1cn(CCCCn2ccnc2)cn1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.10 A, density 1.52 g/cm3, surface area 5033.59 m2/g, accessible volume 0.15 cm3/g