ZnC14H10(NO)4ZnC15H11(NO)4(CH)3 is Indium-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, four ZnC14H10(NO)4 clusters, and four ZnC15H11(NO)4 clusters. In each ZnC14H10(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(2), one N(4), one O(3), and one O(6) atom. The Zn(1)-N(2) bond length is 2.03 Å. The Zn(1)-N(4) bond length is 2.05 Å. The Zn(1)-O(3) bond length is 1.97 Å. The Zn(1)-O(6) bond length is 1.95 Å. There are fourteen inequivalent C sites. In the first C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(7)-O(6) bond length is 1.31 Å. The C(7)-O(7) bond length is 1.26 Å. In the second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(2), and one H(4) atom. The C(8)-C(17) bond length is 1.38 Å. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(4) bond length is 1.09 Å. In the third C site, C(9) is bonded in a distorted trigonal planar geometry to one C(19), one C(32), and one H(5) atom. The C(9)-C(19) bond length is 1.35 Å. The C(9)-C(32) bond length is 1.44 Å. The C(9)-H(5) bond length is 1.09 Å. In the fourth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(3), and one O(4) atom. The C(14)-C(28) bond length is 1.48 Å. The C(14)-O(3) bond length is 1.30 Å. The C(14)-O(4) bond length is 1.26 Å. In the fifth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(5), one C(8), and one H(12) atom. The C(17)-C(5) bond length is 1.40 Å. The C(17)-H(12) bond length is 1.09 Å. In the sixth C site, C(18) is bonded in a distorted single-bond geometry to one N(7) atom. The C(18)-N(7) bond length is 1.42 Å. In the seventh C site, C(19) is bonded in a distorted single-bond geometry to one C(9) and one H(13) atom. The C(19)-H(13) bond length is 1.09 Å. In the eighth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(6), one N(2), and one H(17) atom. The C(23)-C(6) bond length is 1.38 Å. The C(23)-N(2) bond length is 1.35 Å. The C(23)-H(17) bond length is 1.09 Å. In the ninth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(14), one C(32), and one H(20) atom. The C(28)-C(32) bond length is 1.35 Å. The C(28)-H(20) bond length is 1.09 Å. In the tenth C site, C(29) is bonded in a distorted trigonal planar geometry to one N(4) and one H(21) atom. The C(29)-N(4) bond length is 1.35 Å. The C(29)-H(21) bond length is 1.09 Å. In the eleventh C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(22) atom. The C(30)-N(4) bond length is 1.35 Å. The C(30)-H(22) bond length is 1.09 Å. In the twelfth C site, C(32) is bonded in a distorted single-bond geometry to one C(28), one C(9), and one H(24) atom. The C(32)-H(24) bond length is 1.09 Å. In the thirteenth C site, C(5) is bonded in a distorted single-bond geometry to one C(17) and one N(8) atom. The C(5)-N(8) bond length is 1.39 Å. In the fourteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(23) and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(7) is bonded in a water-like geometry to one C(18) and one N(8) atom. The N(7)-N(8) bond length is 1.26 Å. In the second N site, N(8) is bonded in a bent 120 degrees geometry to one C(5) and one N(7) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(23), and one C(8) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(29), and one C(30) atom. There are ten inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(28) atom. In the eighth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the ninth H site, H(22) is bonded in a single-bond geometry to one C(30) atom. In the tenth H site, H(24) is bonded in a single-bond geometry to one C(32) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(14) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the fourth O site, O(7) is bonded in a single-bond geometry to one C(7) atom. In each ZnC15H11(NO)4 cluster, Zn(2) is bonded in a tetrahedral geometry to one N(1), one N(3), one O(2), and one O(5) atom. The Zn(2)-N(1) bond length is 2.10 Å. The Zn(2)-N(3) bond length is 2.09 Å. The Zn(2)-O(2) bond length is 1.97 Å. The Zn(2)-O(5) bond length is 1.98 Å. There are fifteen inequivalent C sites. In the first C site, C(10) is bonded in a distorted trigonal planar geometry to one C(26), one N(1), and one H(6) atom. The C(10)-C(26) bond length is 1.39 Å. The C(10)-N(1) bond length is 1.35 Å. The C(10)-H(6) bond length is 1.09 Å. In the second C site, C(12) is bonded in a distorted trigonal planar geometry to one C(15), one C(3), and one H(8) atom. The C(12)-C(15) bond length is 1.44 Å. The C(12)-C(3) bond length is 1.35 Å. The C(12)-H(8) bond length is 1.09 Å. In the third C site, C(13) is bonded in a 2-coordinate geometry to one N(3) and one H(9) atom. The C(13)-N(3) bond length is 1.35 Å. The C(13)-H(9) bond length is 1.09 Å. In the fourth C site, C(15) is bonded in a distorted single-bond geometry to one C(12), one C(31), and one H(10) atom. The C(15)-C(31) bond length is 1.35 Å. The C(15)-H(10) bond length is 1.09 Å. In the fifth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(20), one N(1), and one H(11) atom. The C(16)-C(20) bond length is 1.39 Å. The C(16)-N(1) bond length is 1.35 Å. The C(16)-H(11) bond length is 1.09 Å. In the sixth C site, C(20) is bonded in a distorted single-bond geometry to one C(16), one C(4), and one H(14) atom. The C(20)-C(4) bond length is 1.40 Å. The C(20)-H(14) bond length is 1.09 Å. In the seventh C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one N(3), and one H(15) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-N(3) bond length is 1.36 Å. The C(21)-H(15) bond length is 1.09 Å. In the eighth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(16) atom. The C(22)-H(16) bond length is 1.09 Å. In the ninth C site, C(24) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. The C(24)-O(1) bond length is 1.26 Å. The C(24)-O(2) bond length is 1.30 Å. In the tenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(10), one C(4), and one H(19) atom. The C(26)-C(4) bond length is 1.41 Å. The C(26)-H(19) bond length is 1.09 Å. In the eleventh C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(5), and one O(8) atom. The C(27)-C(31) bond length is 1.48 Å. The C(27)-O(5) bond length is 1.30 Å. The C(27)-O(8) bond length is 1.26 Å. In the twelfth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(15), one C(27), and one H(23) atom. The C(31)-H(23) bond length is 1.09 Å. In the thirteenth C site, C(2) is bonded in a distorted single-bond geometry to one N(6) atom. The C(2)-N(6) bond length is 1.41 Å. In the fourteenth C site, C(3) is bonded in a distorted single-bond geometry to one C(12) and one H(2) atom. The C(3)-H(2) bond length is 1.09 Å. In the fifteenth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(20), one C(26), and one N(5) atom. The C(4)-N(5) bond length is 1.41 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(10), and one C(16) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(13), and one C(21) atom. In the third N site, N(5) is bonded in a distorted bent 120 degrees geometry to one C(4) and one N(6) atom. The N(5)-N(6) bond length is 1.24 Å. In the fourth N site, N(6) is bonded in a distorted bent 120 degrees geometry to one C(2) and one N(5) atom. There are eleven inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(23) is bonded in a single-bond geometry to one C(31) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(24) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(2) and one C(24) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(27) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one C(27) atom. Linkers: 8 [O]C(=O)/C=C/C=C/C([O])=O. Metal clusters: 8 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.68 A, density 1.16 g/cm3, surface area 4735.92 m2/g, accessible volume 0.35 cm3/g