AgCO2(CH)2C2HO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four dimethyl ether molecules, and two AgCO2 clusters. In each AgCO2 cluster, Ag(1) is bonded in a 2-coordinate geometry to one O(2) and one O(3) atom. The Ag(1)-O(2) bond length is 2.17 Å. The Ag(1)-O(3) bond length is 2.18 Å. C(5) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(5)-O(2) bond length is 1.27 Å. The C(5)-O(3) bond length is 1.28 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Ag(1) and one C(5) atom. In the second O site, O(3) is bonded in a 2-coordinate geometry to one Ag(1) and one C(5) atom. Linkers: 4 [O]C(=O)c1ccco1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 1.70 A, density 2.63 g/cm3, surface area 2701.14 m2/g, accessible volume 0.06 cm3/g