Li2C13H14O5 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(13), one O(5), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one C(37)H3O tetrahedra, and  an edgeedge with one Li(5)O4 tetrahedra. The Li(1)-O(1) bond length is 1.97 Å. The Li(1)-O(13) bond length is 1.96 Å. The Li(1)-O(5) bond length is 1.94 Å. The Li(1)-O(7) bond length is 1.94 Å. In the second Li site, Li(2) is bonded to one O(14), one O(2), one O(6), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one C(38)H3O tetrahedra, and  an edgeedge with one Li(6)O4 tetrahedra. The Li(2)-O(14) bond length is 1.96 Å. The Li(2)-O(2) bond length is 1.96 Å. The Li(2)-O(6) bond length is 1.94 Å. The Li(2)-O(8) bond length is 1.94 Å. In the third Li site, Li(3) is bonded to one O(15), one O(3), one O(4), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one C(39)H3O tetrahedra, and  an edgeedge with one Li(4)O4 tetrahedra. The Li(3)-O(15) bond length is 1.96 Å. The Li(3)-O(3) bond length is 1.97 Å. The Li(3)-O(4) bond length is 1.94 Å. The Li(3)-O(9) bond length is 1.94 Å. In the fourth Li site, Li(4) is bonded to one O(1), one O(10), one O(4), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra;  a cornercorner with one C(34,35,36)H3O tetrahedra; and  an edgeedge with one Li(3)O4 tetrahedra. The Li(4)-O(1) bond length is 1.96 Å. The Li(4)-O(10) bond length is 1.96 Å. The Li(4)-O(4) bond length is 1.98 Å. The Li(4)-O(9) bond length is 1.93 Å. In the fifth Li site, Li(5) is bonded to one O(11), one O(2), one O(5), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra;  a cornercorner with one C(34,35,36)H3O tetrahedra; and  an edgeedge with one Li(1)O4 tetrahedra. The Li(5)-O(11) bond length is 1.96 Å. The Li(5)-O(2) bond length is 1.96 Å. The Li(5)-O(5) bond length is 1.98 Å. The Li(5)-O(7) bond length is 1.93 Å. In the sixth Li site, Li(6) is bonded to one O(12), one O(3), one O(6), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(3)O4 tetrahedra;  a cornercorner with one C(34,35,36)H3O tetrahedra; and  an edgeedge with one Li(2)O4 tetrahedra. The Li(6)-O(12) bond length is 1.96 Å. The Li(6)-O(3) bond length is 1.96 Å. The Li(6)-O(6) bond length is 1.98 Å. The Li(6)-O(8) bond length is 1.94 Å. There are thirty-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(22,24); one O(4); and one O(7) atom. The C(1)-C(22,24) bond length is 1.49 Å. The C(1)-O(4) bond length is 1.28 Å. The C(1)-O(7) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(5), and one O(8) atom. The C(2)-C(23) bond length is 1.49 Å. The C(2)-O(5) bond length is 1.28 Å. The C(2)-O(8) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(22,24); one O(6); and one O(9) atom. The C(3)-C(22,24) bond length is 1.49 Å. The C(3)-O(6) bond length is 1.28 Å. The C(3)-O(9) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one O(1) atom. The C(4)-O(1) bond length is 1.34 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(11) and one O(2) atom. The C(5)-C(11) bond length is 1.40 Å. The C(5)-O(2) bond length is 1.34 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(12) and one O(3) atom. The C(6)-C(12) bond length is 1.40 Å. The C(6)-O(3) bond length is 1.33 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(10), one C(16), and one C(28) atom. The C(7)-C(10) bond length is 1.41 Å. The C(7)-C(16) bond length is 1.44 Å. The C(7)-C(28) bond length is 1.43 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(17), and one C(29) atom. The C(8)-C(11) bond length is 1.41 Å. The C(8)-C(17) bond length is 1.44 Å. The C(8)-C(29) bond length is 1.43 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(12), one C(18), and one C(30) atom. The C(9)-C(12) bond length is 1.41 Å. The C(9)-C(18) bond length is 1.44 Å. The C(9)-C(30) bond length is 1.43 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(7) and one H(1) atom. The C(10)-H(1) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(5); one C(8); and one H(2,3) atom. The C(11)-H(2,3) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(6); one C(9); and one H(2,3) atom. The C(12)-H(2,3) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(16); one C(25,27); and one H(4,6) atom. The C(13)-C(16) bond length is 1.42 Å. The C(13)-C(25,27) bond length is 1.37 Å. The C(13)-H(4,6) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(17), one C(26), and one H(5) atom. The C(14)-C(17) bond length is 1.42 Å. The C(14)-C(26) bond length is 1.37 Å. The C(14)-H(5) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(18); one C(25,27); and one H(4,6) atom. The C(15)-C(18) bond length is 1.42 Å. The C(15)-C(25,27) bond length is 1.37 Å. The C(15)-H(4,6) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(13), one C(19), and one C(7) atom. The C(16)-C(19) bond length is 1.41 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(14), one C(20), and one C(8) atom. The C(17)-C(20) bond length is 1.41 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(15), one C(21), and one C(9) atom. The C(18)-C(21) bond length is 1.41 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(16); one C(22,24); and one H(7,8,9) atom. The C(19)-C(22,24) bond length is 1.39 Å. The C(19)-H(7,8,9) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(17); one C(23); and one H(7,8,9) atom. The C(20)-C(23) bond length is 1.39 Å. The C(20)-H(7,8,9) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(18); one C(22,24); and one H(7,8,9) atom. The C(21)-C(22,24) bond length is 1.39 Å. The C(21)-H(7,8,9) bond length is 1.09 Å. In the twenty-second C site, C(22,24) is bonded in a trigonal planar geometry to one C(1), one C(19), and one C(31) atom. The C(22,24)-C(31) bond length is 1.42 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(2), one C(20), and one C(32) atom. The C(23)-C(32) bond length is 1.42 Å. In the twenty-fourth C site, C(25,27) is bonded in a distorted single-bond geometry to one C(13) and one H(10,11) atom. The C(25,27)-H(10,11) bond length is 1.09 Å. In the twenty-fifth C site, C(26) is bonded in a distorted single-bond geometry to one C(14) and one H(10,11) atom. The C(26)-H(10,11) bond length is 1.09 Å. In the twenty-sixth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(31); one C(7); and one H(13,14,15) atom. The C(28)-C(31) bond length is 1.38 Å. The C(28)-H(13,14,15) bond length is 1.09 Å. In the twenty-seventh C site, C(29) is bonded in a distorted trigonal planar geometry to one C(32); one C(8); and one H(13,14,15) atom. The C(29)-C(32) bond length is 1.38 Å. The C(29)-H(13,14,15) bond length is 1.09 Å. In the twenty-eighth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(33); one C(9); and one H(13,14,15) atom. The C(30)-C(33) bond length is 1.38 Å. The C(30)-H(13,14,15) bond length is 1.09 Å. In the twenty-ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(22,24); one C(28); and one H(16,18) atom. The C(31)-H(16,18) bond length is 1.09 Å. In the thirtieth C site, C(32) is bonded in a distorted single-bond geometry to one C(23), one C(29), and one H(17) atom. The C(32)-H(17) bond length is 1.09 Å. In the thirty-first C site, C(33) is bonded in a distorted single-bond geometry to one C(22,24); one C(30); and one H(16,18) atom. The C(33)-C(22,24) bond length is 1.42 Å. The C(33)-H(16,18) bond length is 1.09 Å. In the thirty-second C site, C(34,35,36) is bonded to one H(22), one H(25), one H(28), and one O(10) atom to form CH3O tetrahedra that share  a cornercorner with one Li(4)O4 tetrahedra. The C(34,35,36)-H(22) bond length is 1.10 Å. The C(34,35,36)-H(25) bond length is 1.10 Å. The C(34,35,36)-H(28) bond length is 1.10 Å. The C(34,35,36)-O(10) bond length is 1.44 Å. In the thirty-third C site, C(37) is bonded to one H(34,36); one H(37,39); one H(40,42); and one O(13) atom to form CH3O tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra. The C(37)-H(34,36) bond length is 1.10 Å. The C(37)-H(37,39) bond length is 1.10 Å. The C(37)-H(40,42) bond length is 1.10 Å. The C(37)-O(13) bond length is 1.44 Å. In the thirty-fourth C site, C(38) is bonded to one H(35), one H(38), one H(41), and one O(14) atom to form CH3O tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra. The C(38)-H(35) bond length is 1.10 Å. The C(38)-H(38) bond length is 1.10 Å. The C(38)-H(41) bond length is 1.10 Å. The C(38)-O(14) bond length is 1.44 Å. In the thirty-fifth C site, C(39) is bonded to one H(34,36); one H(37,39); one H(40,42); and one O(15) atom to form CH3O tetrahedra that share  a cornercorner with one Li(3)O4 tetrahedra. The C(39)-H(34,36) bond length is 1.10 Å. The C(39)-H(37,39) bond length is 1.10 Å. The C(39)-H(40,42) bond length is 1.10 Å. The C(39)-O(15) bond length is 1.44 Å. There are twenty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(4,6) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(7,8,9) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(10,11) is bonded in a single-bond geometry to one C(25,27) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(25,27) atom. The H(12)-C(25,27) bond length is 1.09 Å. In the eighth H site, H(13,14,15) is bonded in a single-bond geometry to one C(28) atom. In the ninth H site, H(16,18) is bonded in a single-bond geometry to one C(31) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(32) atom. In the eleventh H site, H(19,21) is bonded in a single-bond geometry to one O(10) atom. The H(19,21)-O(10) bond length is 0.98 Å. In the twelfth H site, H(20) is bonded in a single-bond geometry to one O(11) atom. The H(20)-O(11) bond length is 0.98 Å. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(34,35,36) atom. In the fourteenth H site, H(23,24) is bonded in a single-bond geometry to one C(34,35,36) atom. The H(23,24)-C(34,35,36) bond length is 1.10 Å. In the fifteenth H site, H(25) is bonded in a single-bond geometry to one C(34,35,36) atom. In the sixteenth H site, H(26,27) is bonded in a single-bond geometry to one C(34,35,36) atom. The H(26,27)-C(34,35,36) bond length is 1.10 Å. In the seventeenth H site, H(28) is bonded in a single-bond geometry to one C(34,35,36) atom. In the eighteenth H site, H(29,30) is bonded in a single-bond geometry to one C(34,35,36) atom. The H(29,30)-C(34,35,36) bond length is 1.10 Å. In the nineteenth H site, H(31) is bonded in a distorted single-bond geometry to one O(13) and one O(3) atom. The H(31)-O(13) bond length is 1.01 Å. The H(31)-O(3) bond length is 1.62 Å. In the twentieth H site, H(32) is bonded in a distorted single-bond geometry to one O(1) and one O(14) atom. The H(32)-O(1) bond length is 1.62 Å. The H(32)-O(14) bond length is 1.01 Å. In the twenty-first H site, H(33) is bonded in a distorted single-bond geometry to one O(15) and one O(2) atom. The H(33)-O(15) bond length is 1.01 Å. The H(33)-O(2) bond length is 1.62 Å. In the twenty-second H site, H(34,36) is bonded in a single-bond geometry to one C(37) atom. In the twenty-third H site, H(35) is bonded in a single-bond geometry to one C(38) atom. In the twenty-fourth H site, H(37,39) is bonded in a single-bond geometry to one C(37) atom. In the twenty-fifth H site, H(38) is bonded in a single-bond geometry to one C(38) atom. In the twenty-sixth H site, H(40,42) is bonded in a single-bond geometry to one C(37) atom. In the twenty-seventh H site, H(41) is bonded in a single-bond geometry to one C(38) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted tetrahedral geometry to one Li(1), one Li(4), one C(4), and one H(32) atom. In the second O site, O(2) is bonded in a distorted tetrahedral geometry to one Li(2), one Li(5), one C(5), and one H(33) atom. In the third O site, O(3) is bonded in a distorted tetrahedral geometry to one Li(3), one Li(6), one C(6), and one H(31) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(3), one Li(4), and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Li(1), one Li(5), and one C(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(2), one Li(6), and one C(3) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Li(1), one Li(5), and one C(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(2), one Li(6), and one C(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(3), one Li(4), and one C(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(4); one C(34,35,36); and one H(19,21) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Li(5); one C(34,35,36); and one H(20) atom. The O(11)-C(34,35,36) bond length is 1.44 Å. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Li(6); one C(34,35,36); and one H(19,21) atom. The O(12)-C(34,35,36) bond length is 1.44 Å. The O(12)-H(19,21) bond length is 0.98 Å. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one C(37), and one H(31) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal non-coplanar geometry to one Li(2), one C(38), and one H(32) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one C(39), and one H(33) atom. Linkers: 3 [O]C(=O)c1ccc2cc([O])ccc2c1. Metal clusters: 6 [Li]. The MOF has largest included sphere 3.13 A, density 1.17 g/cm3, surface area 5123.79 m2/g, accessible volume 0.25 cm3/g