CdC12N4H12SO5 crystallizes in the triclinic P-1 space group. Cd(1) is bonded in a distorted octahedral geometry to one N(1), one N(3), one O(1), one O(3), one O(4), and one O(5) atom. The Cd(1)-N(1) bond length is 2.30 Å. The Cd(1)-N(3) bond length is 2.29 Å. The Cd(1)-O(1) bond length is 2.32 Å. The Cd(1)-O(3) bond length is 2.36 Å. The Cd(1)-O(4) bond length is 2.58 Å. The Cd(1)-O(5) bond length is 2.45 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(2), and one O(3) atom. The C(1)-C(5) bond length is 1.48 Å. The C(1)-O(2) bond length is 1.26 Å. The C(1)-O(3) bond length is 1.29 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(1) atom. The C(2)-N(3) bond length is 1.34 Å. The C(2)-N(4) bond length is 1.36 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(3), and one H(2) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-N(3) bond length is 1.38 Å. The C(3)-H(2) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(4), and one H(3) atom. The C(4)-N(4) bond length is 1.38 Å. The C(4)-H(3) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(6), and one S(1) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-S(1) bond length is 1.72 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(8) atom. The C(6)-H(8) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(9) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(9) bond length is 1.08 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(7), one C(9), and one S(1) atom. The C(8)-C(9) bond length is 1.47 Å. The C(8)-S(1) bond length is 1.72 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(4), and one O(5) atom. The C(9)-O(4) bond length is 1.27 Å. The C(9)-O(5) bond length is 1.28 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(10) atom. The C(10)-N(1) bond length is 1.33 Å. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(10) bond length is 1.08 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(1), and one H(11) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-N(1) bond length is 1.38 Å. The C(11)-H(11) bond length is 1.08 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(2), and one H(12) atom. The C(12)-N(2) bond length is 1.38 Å. The C(12)-H(12) bond length is 1.08 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one C(11) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(12), and one H(4) atom. The N(2)-H(4) bond length is 1.04 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(2), and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(2), one C(4), and one H(5) atom. The N(4)-H(5) bond length is 1.04 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one N(2) and one O(5) atom. The H(4)-O(5) bond length is 1.67 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) and one O(3) atom. The H(5)-O(3) bond length is 1.73 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(1) atom. The H(6)-O(1) bond length is 0.99 Å. In the seventh H site, H(7) is bonded in a distorted single-bond geometry to one O(1) and one O(2) atom. The H(7)-O(1) bond length is 1.00 Å. The H(7)-O(2) bond length is 1.68 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. S(1) is bonded in an L-shaped geometry to one C(5) and one C(8) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1), one H(6), and one H(7) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one C(1) and one H(7) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Cd(1), one C(1), and one H(5) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(9) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Cd(1), one C(9), and one H(4) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)s1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 2.68 A, density 1.87 g/cm3, surface area 4125.44 m2/g, accessible volume 0.13 cm3/g