CdC10H12S2(NO4)2 crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(4) atoms. Both Cd(1)-N(1) bond lengths are 2.35 Å. Both Cd(1)-O(1) bond lengths are 2.37 Å. Both Cd(1)-O(4) bond lengths are 2.31 Å. There are five inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-C(2) bond length is 1.39 Å. The C(3)-H(2) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the fifth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one S(1) atom. The C(2)-S(1) bond length is 1.78 Å. N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(2) and one O(4) atom. The H(5)-O(2) bond length is 1.71 Å. The H(5)-O(4) bond length is 0.99 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) and one O(4) atom. The H(6)-O(3) bond length is 1.74 Å. The H(6)-O(4) bond length is 0.99 Å. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(2) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.46 Å. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one H(5) and one S(1) atom. In the second O site, O(4) is bonded in a distorted water-like geometry to one Cd(1), one H(5), and one H(6) atom. In the third O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one S(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to one H(6) and one S(1) atom. Linkers: 4 [O]S([O])([O])c1cccnc1. Metal clusters: 2 O.O.[O][S@](=O)O[Cd]O[S@]([O])=O. The MOF has largest included sphere 2.13 A, density 2.11 g/cm3, surface area 3666.92 m2/g, accessible volume 0.09 cm3/g