AgC5H10(SO)2CH2CF2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two difluoromethane molecules, and one AgC5H10(SO)2 cluster. In the AgC5H10(SO)2 cluster, Ag(1) is bonded in a 3-coordinate geometry to one S(1), two equivalent S(2), and one O(2) atom. The Ag(1)-S(1) bond length is 2.44 Å. There is one shorter (2.51 Å) and one longer (3.05 Å) Ag(1)-S(2) bond length. The Ag(1)-O(2) bond length is 2.32 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(3) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(2) atom. The C(3)-H(1) bond length is 1.10 Å. The C(3)-H(2) bond length is 1.10 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-S(2) bond length is 1.80 Å. In the third C site, C(4) is bonded in a distorted water-like geometry to one H(4), one H(5), and one S(1) atom. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. The C(4)-S(1) bond length is 1.82 Å. In the fourth C site, C(5) is bonded in a trigonal non-coplanar geometry to one H(6), one H(7), one H(8), and one S(1) atom. The C(5)-H(6) bond length is 1.10 Å. The C(5)-H(7) bond length is 1.10 Å. The C(5)-H(8) bond length is 1.10 Å. The C(5)-S(1) bond length is 1.81 Å. In the fifth C site, C(6) is bonded in a distorted water-like geometry to one H(10), one H(9), and one S(2) atom. The C(6)-H(10) bond length is 1.10 Å. The C(6)-H(9) bond length is 1.10 Å. The C(6)-S(2) bond length is 1.81 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(4), and one C(5) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1), one C(3), and one C(6) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Ag(1) and one C(1) atom. Linkers: 2 CSCCCSC ,1 [O]C(=O)C(F)(F)C(F)(F)C([O])=O. Metal clusters: 2 [Ag]. RCSR code: bey. The MOF has largest included sphere 2.07 A, density 2.09 g/cm3, surface area 3877.05 m2/g, accessible volume 0.11 cm3/g