NaC24H24(N2O)3(CH2)6 crystallizes in the monoclinic C2/c space group. The structure consists of forty-eight 02329_fluka molecules inside a NaC24H24(N2O)3 framework. In each NaC24H24(N2O)3 framework, Na(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one O(1), one O(2), and one O(3) atom. The Na(1)-N(1) bond length is 2.41 Å. The Na(1)-N(2) bond length is 2.49 Å. The Na(1)-N(3) bond length is 2.48 Å. The Na(1)-O(1) bond length is 2.60 Å. The Na(1)-O(2) bond length is 2.37 Å. The Na(1)-O(3) bond length is 2.43 Å. There are twenty-four inequivalent C sites. In the first C site, C(23) is bonded in a distorted trigonal non-coplanar geometry to one H(25), one H(26), and one O(3) atom. The C(23)-H(25) bond length is 1.10 Å. The C(23)-H(26) bond length is 1.10 Å. The C(23)-O(3) bond length is 1.45 Å. In the second C site, C(26) is bonded in a distorted trigonal non-coplanar geometry to one H(31), one H(32), and one O(3) atom. The C(26)-H(31) bond length is 1.10 Å. The C(26)-H(32) bond length is 1.10 Å. The C(26)-O(3) bond length is 1.45 Å. In the third C site, C(27) is bonded in a distorted single-bond geometry to one C(16), one C(28), and one H(33) atom. The C(27)-C(16) bond length is 1.41 Å. The C(27)-C(28) bond length is 1.39 Å. The C(27)-H(33) bond length is 1.09 Å. In the fourth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one N(3), and one H(34) atom. The C(28)-N(3) bond length is 1.35 Å. The C(28)-H(34) bond length is 1.09 Å. In the fifth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(30), one N(3), and one H(35) atom. The C(29)-C(30) bond length is 1.39 Å. The C(29)-N(3) bond length is 1.35 Å. The C(29)-H(35) bond length is 1.09 Å. In the sixth C site, C(30) is bonded in a distorted single-bond geometry to one C(16), one C(29), and one H(36) atom. The C(30)-C(16) bond length is 1.41 Å. The C(30)-H(36) bond length is 1.09 Å. In the seventh C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the eighth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.09 Å. In the ninth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.45 Å. In the tenth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the eleventh C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the twelfth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(3), one N(4), and one N(5) atom. The C(6)-N(4) bond length is 1.38 Å. The C(6)-N(5) bond length is 1.34 Å. In the thirteenth C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(7)-C(11) bond length is 1.40 Å. The C(7)-C(15) bond length is 1.40 Å. The C(7)-C(9) bond length is 1.48 Å. In the fourteenth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(16), one N(5), and one N(6) atom. The C(8)-C(16) bond length is 1.46 Å. The C(8)-N(5) bond length is 1.34 Å. The C(8)-N(6) bond length is 1.38 Å. In the fifteenth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(7), one N(4), and one N(6) atom. The C(9)-N(4) bond length is 1.33 Å. The C(9)-N(6) bond length is 1.34 Å. In the sixteenth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(6), and one O(1) atom. The C(10)-H(5) bond length is 1.10 Å. The C(10)-H(6) bond length is 1.10 Å. The C(10)-O(1) bond length is 1.44 Å. In the seventeenth C site, C(11) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(11)-H(7) bond length is 1.09 Å. In the eighteenth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one H(8), one H(9), and one O(2) atom. The C(12)-H(8) bond length is 1.10 Å. The C(12)-H(9) bond length is 1.10 Å. The C(12)-O(2) bond length is 1.44 Å. In the nineteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(13)-N(2) bond length is 1.35 Å. The C(13)-H(10) bond length is 1.09 Å. In the twentieth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(15), one N(2), and one H(11) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-N(2) bond length is 1.35 Å. The C(14)-H(11) bond length is 1.09 Å. In the twenty-first C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(7), and one H(12) atom. The C(15)-H(12) bond length is 1.09 Å. In the twenty-second C site, C(16) is bonded in a trigonal planar geometry to one C(27), one C(30), and one C(8) atom. In the twenty-third C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one H(17), one H(18), and one O(1) atom. The C(19)-H(17) bond length is 1.10 Å. The C(19)-H(18) bond length is 1.11 Å. The C(19)-O(1) bond length is 1.44 Å. In the twenty-fourth C site, C(22) is bonded in a distorted trigonal non-coplanar geometry to one H(23), one H(24), and one O(2) atom. The C(22)-H(23) bond length is 1.10 Å. The C(22)-H(24) bond length is 1.10 Å. The C(22)-O(2) bond length is 1.44 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Na(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Na(1), one C(13), and one C(14) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Na(1), one C(28), and one C(29) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(6) and one C(9) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(6) and one C(8) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one C(8) and one C(9) atom. There are twenty-four inequivalent H sites. In the first H site, H(31) is bonded in a single-bond geometry to one C(26) atom. In the second H site, H(32) is bonded in a single-bond geometry to one C(26) atom. In the third H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(33) is bonded in a single-bond geometry to one C(27) atom. In the fifth H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(34) is bonded in a single-bond geometry to one C(28) atom. In the seventh H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(35) is bonded in a single-bond geometry to one C(29) atom. In the ninth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(36) is bonded in a single-bond geometry to one C(30) atom. In the eleventh H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the fourteenth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the fifteenth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the sixteenth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the seventeenth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eighteenth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the nineteenth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the twentieth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(22) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(22) atom. In the twenty-third H site, H(25) is bonded in a single-bond geometry to one C(23) atom. In the twenty-fourth H site, H(26) is bonded in a single-bond geometry to one C(23) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Na(1), one C(10), and one C(19) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Na(1), one C(12), and one C(22) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Na(1), one C(23), and one C(26) atom. Linkers: 4 n1ccc(cc1)C1=NC(=[N]=C([N]1)c1ccncc1)c1ccncc1. Metal clusters: 4 [Na]. The MOF has largest included sphere 4.92 A, density 1.13 g/cm3, surface area 5715.90 m2/g, accessible volume 0.27 cm3/g