Zn3C24H16(N5O3)2(CH)4 crystallizes in the monoclinic C2/c space group. The structure consists of sixteen 02329_fluka molecules inside a Zn3C24H16(N5O3)2 framework. In the Zn3C24H16(N5O3)2 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to two equivalent N(4), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing ZnN2O4 octahedra. Both Zn(1)-N(4) bond lengths are 2.22 Å. Both Zn(1)-O(1) bond lengths are 2.05 Å. Both Zn(1)-O(2) bond lengths are 2.16 Å. In the second Zn site, Zn(2) is bonded to one N(1), one N(3), one O(1), and one O(3) atom to form corner-sharing ZnN2O2 tetrahedra. The corner-sharing octahedral tilt angles are 60°. The Zn(2)-N(1) bond length is 2.03 Å. The Zn(2)-N(3) bond length is 2.01 Å. The Zn(2)-O(1) bond length is 1.94 Å. The Zn(2)-O(3) bond length is 1.97 Å. There are twelve inequivalent C sites. In the first C site, C(11) is bonded in a distorted trigonal planar geometry to one C(13), one C(14), and one H(8) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-C(14) bond length is 1.40 Å. The C(11)-H(8) bond length is 1.09 Å. In the second C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(8), and one C(9) atom. The C(13)-C(8) bond length is 1.40 Å. The C(13)-C(9) bond length is 1.52 Å. In the third C site, C(14) is bonded in a distorted single-bond geometry to one C(11) and one H(10) atom. The C(14)-H(10) bond length is 1.09 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(1)-O(2) bond length is 1.26 Å. The C(1)-O(3) bond length is 1.29 Å. In the fifth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(1) atom. The C(2)-C(4) bond length is 1.39 Å. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(1) bond length is 1.09 Å. In the sixth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(2) atom. The C(3)-C(5) bond length is 1.38 Å. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(2) bond length is 1.09 Å. In the seventh C site, C(4) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(3) atom. The C(4)-C(6) bond length is 1.40 Å. The C(4)-H(3) bond length is 1.09 Å. In the eighth C site, C(5) is bonded in a distorted single-bond geometry to one C(3), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the ninth C site, C(6) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.45 Å. In the tenth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one N(2), and one N(5) atom. The C(7)-N(2) bond length is 1.35 Å. The C(7)-N(5) bond length is 1.36 Å. In the eleventh C site, C(8) is bonded in a distorted single-bond geometry to one C(13) and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the twelfth C site, C(9) is bonded in a distorted water-like geometry to one C(13), one H(6), and one O(1) atom. The C(9)-H(6) bond length is 1.11 Å. The C(9)-O(1) bond length is 1.41 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(7) and one N(3) atom. The N(2)-N(3) bond length is 1.32 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Zn(2), one N(2), and one N(4) atom. The N(3)-N(4) bond length is 1.34 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one N(3), and one N(5) atom. The N(4)-N(5) bond length is 1.32 Å. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(7) and one N(4) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(1) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one C(9) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(2) and one C(1) atom. Linkers: 4 c1cc(C2=N[N]N=N2)ccn1 ,2 [O]C(=O)[C@@H]([O])c1ccccc1 ,2 [O]C(=O)[C@H]([O])c1ccccc1. Metal clusters: 6 [Zn]. The MOF has largest included sphere 3.71 A, density 1.62 g/cm3, surface area 4364.43 m2/g, accessible volume 0.19 cm3/g