LiC4N2H6O2Cl(CH2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two LiC4N2H6O2Cl clusters. In each LiC4N2H6O2Cl cluster, Li(1) is bonded to one O(1), one O(2), and two equivalent Cl(1) atoms to form distorted edge-sharing LiCl2O2 tetrahedra. The Li(1)-O(1) bond length is 1.89 Å. The Li(1)-O(2) bond length is 1.88 Å. There is one shorter (2.34 Å) and one longer (2.46 Å) Li(1)-Cl(1) bond length. There are four inequivalent C sites. In the first C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(1) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-O(1) bond length is 1.25 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(2) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-O(2) bond length is 1.25 Å. In the third C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(7), and one H(8) atom. The C(5)-N(1) bond length is 1.44 Å. The C(5)-H(7) bond length is 1.10 Å. The C(5)-H(8) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(5), and one H(6) atom. The C(4)-N(1) bond length is 1.46 Å. The C(4)-H(5) bond length is 1.10 Å. The C(4)-H(6) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(6), one H(10), and one H(9) atom. The N(2)-H(10) bond length is 1.03 Å. The N(2)-H(9) bond length is 1.02 Å. There are six inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(9) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(10) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one C(6) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one C(1) atom. Cl(1) is bonded in a distorted L-shaped geometry to two equivalent Li(1) atoms. Linkers: 4 NC(=O)CN1CCCC1=O. Metal clusters: 2 N[C]=O.N[C]=O.[Cl].[Cl].[Li][O].[Li][O]. RCSR code: sql. The MOF has largest included sphere 2.04 A, density 1.43 g/cm3, surface area 5306.90 m2/g, accessible volume 0.15 cm3/g