ZnC14H8(NO4)2(CH)6 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules and four ZnC14H8(NO4)2 clusters. In each ZnC14H8(NO4)2 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Zn(1)-N(1) bond lengths are 2.05 Å. Both Zn(1)-O(1) bond lengths are 1.98 Å. There are seven inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the second C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.43 Å. The C(4)-C(6) bond length is 1.42 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(9)-O(3) bond length is 1.23 Å. The C(9)-O(4) bond length is 1.34 Å. In the fifth C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(6)-C(6) bond length is 1.44 Å. The C(6)-N(1) bond length is 1.36 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(7)-O(1) bond length is 1.29 Å. The C(7)-O(2) bond length is 1.27 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(6) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(6) is bonded in a linear geometry to one O(2) and one O(4) atom. The H(6)-O(2) bond length is 1.55 Å. The H(6)-O(4) bond length is 1.03 Å. There are four inequivalent O sites. In the first O site, O(4) is bonded in a water-like geometry to one C(9) and one H(6) atom. In the second O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one C(7) and one H(6) atom. Linkers: 2 c1cnc2c(c1)ccc1cccnc12 ,2 [O]C(=O)/C=C/C([O])=O. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 2.17 A, density 1.67 g/cm3, surface area 4654.16 m2/g, accessible volume 0.11 cm3/g