CuC11H7(N3O2)2(CH)3 crystallizes in the monoclinic Cc space group. The structure consists of twelve 02329_fluka molecules inside a CuC11H7(N3O2)2 framework. In the CuC11H7(N3O2)2 framework, Cu(1) is bonded in a distorted octahedral geometry to one N(3), one N(5), one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-N(3) bond length is 2.00 Å. The Cu(1)-N(5) bond length is 1.99 Å. The Cu(1)-O(1) bond length is 2.42 Å. The Cu(1)-O(2) bond length is 2.36 Å. The Cu(1)-O(3) bond length is 2.02 Å. The Cu(1)-O(4) bond length is 2.03 Å. There are eleven inequivalent C sites. In the first C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(2)-O(2) bond length is 1.26 Å. The C(2)-O(3) bond length is 1.27 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(3)-O(1) bond length is 1.26 Å. The C(3)-O(4) bond length is 1.27 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(5) atom. The C(5)-C(10) bond length is 1.40 Å. The C(5)-C(12) bond length is 1.39 Å. The C(5)-H(5) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one N(5) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-C(9) bond length is 1.41 Å. The C(6)-N(5) bond length is 1.38 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(6) atom. The C(7)-H(6) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one H(7) atom. The C(8)-C(13) bond length is 1.39 Å. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(7) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one N(4) atom. The C(9)-N(4) bond length is 1.37 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(14), one C(5), and one N(6) atom. The C(10)-C(14) bond length is 1.42 Å. The C(10)-N(6) bond length is 1.37 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(5) and one H(9) atom. The C(12)-H(9) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(10) atom. The C(13)-H(10) bond length is 1.09 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(10) and one N(3) atom. The C(14)-N(3) bond length is 1.38 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one N(3) and one N(6) atom. The N(1)-N(3) bond length is 1.32 Å. The N(1)-N(6) bond length is 1.33 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(4) and one N(5) atom. The N(2)-N(4) bond length is 1.33 Å. The N(2)-N(5) bond length is 1.32 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(14), and one N(1) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one C(9), one N(2), and one H(2) atom. The N(4)-H(2) bond length is 1.06 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(6), and one N(2) atom. In the sixth N site, N(6) is bonded in a 3-coordinate geometry to one C(10), one N(1), and one H(3) atom. The N(6)-H(3) bond length is 1.06 Å. There are seven inequivalent H sites. In the first H site, H(2) is bonded in a distorted linear geometry to one N(4) and one O(1) atom. The H(2)-O(1) bond length is 1.66 Å. In the second H site, H(3) is bonded in a linear geometry to one N(6) and one O(2) atom. The H(3)-O(2) bond length is 1.66 Å. In the third H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(3), and one H(2) atom. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to one Cu(1), one C(2), and one H(3) atom. Linkers: 2 [O]C(=O)C([O])=O. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.85 A, density 1.66 g/cm3, surface area 4299.54 m2/g, accessible volume 0.15 cm3/g