KCu4C22H51S4(N2O11)2(CH2)4 crystallizes in the monoclinic Cc space group. The structure consists of sixteen 02329_fluka molecules inside a KCu4C22H51S4(N2O11)2 framework. In the KCu4C22H51S4(N2O11)2 framework, K(1) is bonded in a 6-coordinate geometry to one H(57), one O(10), one O(13), one O(20), one O(21), and one O(5) atom. The K(1)-H(57) bond length is 2.86 Å. The K(1)-O(10) bond length is 2.67 Å. The K(1)-O(13) bond length is 2.81 Å. The K(1)-O(20) bond length is 2.65 Å. The K(1)-O(21) bond length is 2.68 Å. The K(1)-O(5) bond length is 2.66 Å. There are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one O(1), one O(11), one O(2), and one O(3) atom. The Cu(1)-N(1) bond length is 2.05 Å. The Cu(1)-O(1) bond length is 1.97 Å. The Cu(1)-O(11) bond length is 1.97 Å. The Cu(1)-O(2) bond length is 2.32 Å. The Cu(1)-O(3) bond length is 2.05 Å. In the second Cu site, Cu(2) is bonded in a 5-coordinate geometry to one N(3), one O(11), one O(12), one O(14), and one O(6) atom. The Cu(2)-N(3) bond length is 2.05 Å. The Cu(2)-O(11) bond length is 2.02 Å. The Cu(2)-O(12) bond length is 2.37 Å. The Cu(2)-O(14) bond length is 1.95 Å. The Cu(2)-O(6) bond length is 1.99 Å. In the third Cu site, Cu(3) is bonded in a distorted trigonal bipyramidal geometry to one N(2), one O(16), one O(6), one O(7), and one O(8) atom. The Cu(3)-N(2) bond length is 2.05 Å. The Cu(3)-O(16) bond length is 1.94 Å. The Cu(3)-O(6) bond length is 1.95 Å. The Cu(3)-O(7) bond length is 2.33 Å. The Cu(3)-O(8) bond length is 2.03 Å. In the fourth Cu site, Cu(4) is bonded in a 6-coordinate geometry to one N(4), one O(1), one O(11), one O(14), one O(16), and one O(17) atom. The Cu(4)-N(4) bond length is 2.08 Å. The Cu(4)-O(1) bond length is 1.98 Å. The Cu(4)-O(11) bond length is 2.53 Å. The Cu(4)-O(14) bond length is 2.01 Å. The Cu(4)-O(16) bond length is 2.01 Å. The Cu(4)-O(17) bond length is 2.36 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one O(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.11 Å. The C(1)-O(1) bond length is 1.42 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(3), and one H(4) atom. The C(2)-N(1) bond length is 1.49 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(6), and one O(2) atom. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(6) bond length is 1.10 Å. The C(3)-O(2) bond length is 1.43 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(7), and one H(8) atom. The C(4)-N(1) bond length is 1.49 Å. The C(4)-H(7) bond length is 1.10 Å. The C(4)-H(8) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent H(11,12) atoms. The C(6)-N(1) bond length is 1.49 Å. Both C(6)-H(11,12) bond lengths are 1.10 Å. In the sixth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one H(13), one H(14), and one O(6) atom. The C(7)-H(13) bond length is 1.10 Å. The C(7)-H(14) bond length is 1.11 Å. The C(7)-O(6) bond length is 1.41 Å. In the seventh C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(15), and one H(16) atom. The C(8)-N(2) bond length is 1.49 Å. The C(8)-H(15) bond length is 1.10 Å. The C(8)-H(16) bond length is 1.10 Å. In the eighth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one H(17), one H(18), and one O(7) atom. The C(9)-H(17) bond length is 1.10 Å. The C(9)-H(18) bond length is 1.10 Å. The C(9)-O(7) bond length is 1.44 Å. In the ninth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(19), and one H(20) atom. The C(10)-N(2) bond length is 1.50 Å. The C(10)-H(19) bond length is 1.10 Å. The C(10)-H(20) bond length is 1.10 Å. In the tenth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(23), and one H(24) atom. The C(12)-N(2) bond length is 1.49 Å. The C(12)-H(23) bond length is 1.10 Å. The C(12)-H(24) bond length is 1.10 Å. In the eleventh C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one H(25), one H(26), and one O(11) atom. The C(13)-H(25) bond length is 1.10 Å. The C(13)-H(26) bond length is 1.11 Å. The C(13)-O(11) bond length is 1.42 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(27), and one H(28) atom. The C(14)-N(3) bond length is 1.49 Å. The C(14)-H(27) bond length is 1.10 Å. The C(14)-H(28) bond length is 1.10 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one H(29), one H(30), and one O(12) atom. The C(15)-H(29) bond length is 1.10 Å. The C(15)-H(30) bond length is 1.10 Å. The C(15)-O(12) bond length is 1.43 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(31), and one H(32) atom. The C(16)-N(3) bond length is 1.48 Å. The C(16)-H(31) bond length is 1.10 Å. The C(16)-H(32) bond length is 1.10 Å. In the fifteenth C site, C(18) is bonded in a 3-coordinate geometry to one N(3), one H(35), and one H(36) atom. The C(18)-N(3) bond length is 1.48 Å. The C(18)-H(35) bond length is 1.10 Å. The C(18)-H(36) bond length is 1.10 Å. In the sixteenth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one H(37), one H(38), and one O(16) atom. The C(19)-H(37) bond length is 1.10 Å. The C(19)-H(38) bond length is 1.10 Å. The C(19)-O(16) bond length is 1.43 Å. In the seventeenth C site, C(20) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(39), and one H(40) atom. The C(20)-N(4) bond length is 1.48 Å. The C(20)-H(39) bond length is 1.10 Å. The C(20)-H(40) bond length is 1.10 Å. In the eighteenth C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one H(41), one H(42), and one O(17) atom. The C(21)-H(41) bond length is 1.10 Å. The C(21)-H(42) bond length is 1.10 Å. The C(21)-O(17) bond length is 1.44 Å. In the nineteenth C site, C(22) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(43), and one H(44) atom. The C(22)-N(4) bond length is 1.49 Å. The C(22)-H(43) bond length is 1.10 Å. The C(22)-H(44) bond length is 1.10 Å. In the twentieth C site, C(24) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(47), and one H(48) atom. The C(24)-N(4) bond length is 1.49 Å. The C(24)-H(47) bond length is 1.10 Å. The C(24)-H(48) bond length is 1.10 Å. In the twenty-first C site, C(25) is bonded in a tetrahedral geometry to one H(49), one H(50), one H(51), and one O(14) atom. The C(25)-H(49) bond length is 1.11 Å. The C(25)-H(50) bond length is 1.10 Å. The C(25)-H(51) bond length is 1.10 Å. The C(25)-O(14) bond length is 1.41 Å. In the twenty-second C site, C(26) is bonded in a tetrahedral geometry to one H(57), one H(58), one H(59), and one O(21) atom. The C(26)-H(57) bond length is 1.10 Å. The C(26)-H(58) bond length is 1.10 Å. The C(26)-H(59) bond length is 1.11 Å. The C(26)-O(21) bond length is 1.43 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a tetrahedral geometry to one Cu(1), one C(2), one C(4), and one C(6) atom. In the second N site, N(2) is bonded in a tetrahedral geometry to one Cu(3), one C(10), one C(12), and one C(8) atom. In the third N site, N(3) is bonded in a tetrahedral geometry to one Cu(2), one C(14), one C(16), and one C(18) atom. In the fourth N site, N(4) is bonded in a tetrahedral geometry to one Cu(4), one C(20), one C(22), and one C(24) atom. There are fifty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(11,12) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(7) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(7) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(8) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(8) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(9) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(9) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(10) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(10) atom. In the eighteenth H site, H(23) is bonded in a single-bond geometry to one C(12) atom. In the nineteenth H site, H(24) is bonded in a single-bond geometry to one C(12) atom. In the twentieth H site, H(25) is bonded in a single-bond geometry to one C(13) atom. In the twenty-first H site, H(26) is bonded in a single-bond geometry to one C(13) atom. In the twenty-second H site, H(27) is bonded in a single-bond geometry to one C(14) atom. In the twenty-third H site, H(28) is bonded in a single-bond geometry to one C(14) atom. In the twenty-fourth H site, H(29) is bonded in a single-bond geometry to one C(15) atom. In the twenty-fifth H site, H(30) is bonded in a single-bond geometry to one C(15) atom. In the twenty-sixth H site, H(31) is bonded in a single-bond geometry to one C(16) atom. In the twenty-seventh H site, H(32) is bonded in a single-bond geometry to one C(16) atom. In the twenty-eighth H site, H(35) is bonded in a single-bond geometry to one C(18) atom. In the twenty-ninth H site, H(36) is bonded in a single-bond geometry to one C(18) atom. In the thirtieth H site, H(37) is bonded in a single-bond geometry to one C(19) atom. In the thirty-first H site, H(38) is bonded in a single-bond geometry to one C(19) atom. In the thirty-second H site, H(39) is bonded in a single-bond geometry to one C(20) atom. In the thirty-third H site, H(40) is bonded in a single-bond geometry to one C(20) atom. In the thirty-fourth H site, H(41) is bonded in a single-bond geometry to one C(21) atom. In the thirty-fifth H site, H(42) is bonded in a single-bond geometry to one C(21) atom. In the thirty-sixth H site, H(43) is bonded in a single-bond geometry to one C(22) atom. In the thirty-seventh H site, H(44) is bonded in a single-bond geometry to one C(22) atom. In the thirty-eighth H site, H(47) is bonded in a single-bond geometry to one C(24) atom. In the thirty-ninth H site, H(48) is bonded in a single-bond geometry to one C(24) atom. In the fortieth H site, H(49) is bonded in a single-bond geometry to one C(25) atom. In the forty-first H site, H(50) is bonded in a single-bond geometry to one C(25) atom. In the forty-second H site, H(51) is bonded in a single-bond geometry to one C(25) atom. In the forty-third H site, H(52) is bonded in a distorted single-bond geometry to one O(18) and one O(2) atom. The H(52)-O(18) bond length is 1.63 Å. The H(52)-O(2) bond length is 1.01 Å. In the forty-fourth H site, H(53) is bonded in a single-bond geometry to one O(7) atom. The H(53)-O(7) bond length is 1.00 Å. In the forty-fifth H site, H(54) is bonded in a distorted single-bond geometry to one O(12) and one O(4) atom. The H(54)-O(12) bond length is 1.00 Å. The H(54)-O(4) bond length is 1.66 Å. In the forty-sixth H site, H(55) is bonded in a single-bond geometry to one O(17) and one O(9) atom. The H(55)-O(17) bond length is 0.99 Å. The H(55)-O(9) bond length is 1.71 Å. In the forty-seventh H site, H(56) is bonded in a single-bond geometry to one O(21) atom. The H(56)-O(21) bond length is 0.99 Å. In the forty-eighth H site, H(57) is bonded in a single-bond geometry to one K(1) and one C(26) atom. In the forty-ninth H site, H(58) is bonded in a single-bond geometry to one C(26) atom. In the fiftieth H site, H(59) is bonded in a single-bond geometry to one C(26) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(3), one O(4), and one O(5) atom. The S(1)-O(3) bond length is 1.49 Å. The S(1)-O(4) bond length is 1.47 Å. The S(1)-O(5) bond length is 1.46 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one O(10), one O(8), and one O(9) atom. The S(2)-O(10) bond length is 1.46 Å. The S(2)-O(8) bond length is 1.50 Å. The S(2)-O(9) bond length is 1.47 Å. In the third S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to one O(13), one O(15), and one O(22) atom. The S(3)-O(13) bond length is 1.47 Å. The S(3)-O(15) bond length is 1.48 Å. The S(3)-O(22) bond length is 1.47 Å. In the fourth S site, S(4) is bonded in a distorted trigonal non-coplanar geometry to one O(18), one O(19), and one O(20) atom. The S(4)-O(18) bond length is 1.49 Å. The S(4)-O(19) bond length is 1.46 Å. The S(4)-O(20) bond length is 1.47 Å. There are twenty-two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to one Cu(1), one Cu(4), and one C(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cu(1), one C(3), and one H(52) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one H(54) and one S(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one K(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Cu(2), one Cu(3), and one C(7) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Cu(3), one C(9), and one H(53) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(3) and one S(2) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one H(55) and one S(2) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one K(1) and one S(2) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(2), one Cu(4), and one C(13) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Cu(2), one C(15), and one H(54) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one K(1) and one S(3) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Cu(2), one Cu(4), and one C(25) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one S(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal non-coplanar geometry to one Cu(3), one Cu(4), and one C(19) atom. In the seventeenth O site, O(17) is bonded in a 2-coordinate geometry to one Cu(4), one C(21), and one H(55) atom. In the eighteenth O site, O(18) is bonded in a water-like geometry to one H(52) and one S(4) atom. In the nineteenth O site, O(19) is bonded in a single-bond geometry to one S(4) atom. In the twentieth O site, O(20) is bonded in a distorted bent 150 degrees geometry to one K(1) and one S(4) atom. In the twenty-first O site, O(21) is bonded in a distorted water-like geometry to one K(1), one C(26), and one H(56) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one S(3) atom. Linkers: 8 [O]CCN(CCO)CCS([O])([O])[O]. Metal clusters: 2 [K] ,8 [Cu]. The MOF has largest included sphere 3.80 A, density 1.68 g/cm3, surface area 3665.25 m2/g, accessible volume 0.17 cm3/g