ZnC16H14(NO)4(CH2)2(C3NH2O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four 2-nitropropene molecules, and two ZnC16H14(NO)4 clusters. In each ZnC16H14(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(3), one N(4), one O(1), and one O(2) atom. The Zn(1)-N(3) bond length is 2.02 Å. The Zn(1)-N(4) bond length is 2.02 Å. The Zn(1)-O(1) bond length is 2.00 Å. The Zn(1)-O(2) bond length is 2.00 Å. There are thirteen inequivalent C sites. In the first C site, C(1,2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1,2)-N(1) bond length is 1.35 Å. The C(1,2)-N(3) bond length is 1.34 Å. The C(1,2)-H(1) bond length is 1.08 Å. In the second C site, C(3,4) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(3), and one H(3) atom. The C(3,4)-C(5) bond length is 1.37 Å. The C(3,4)-N(3) bond length is 1.38 Å. The C(3,4)-H(3) bond length is 1.08 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(3,4); one N(1); and one H(5,6) atom. The C(5)-N(1) bond length is 1.38 Å. The C(5)-H(5,6) bond length is 1.08 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(3,4); one N(2); and one H(5,6) atom. The C(6)-C(3,4) bond length is 1.37 Å. The C(6)-N(2) bond length is 1.38 Å. The C(6)-H(5,6) bond length is 1.08 Å. In the fifth C site, C(7,8) is bonded in a distorted trigonal non-coplanar geometry to one N(1); one H(7,8); and one H(9,10) atom. The C(7,8)-N(1) bond length is 1.46 Å. The C(7,8)-H(7,8) bond length is 1.10 Å. The C(7,8)-H(9,10) bond length is 1.10 Å. In the sixth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(1), and one O(3) atom. The C(11)-C(13) bond length is 1.51 Å. The C(11)-O(1) bond length is 1.30 Å. The C(11)-O(3) bond length is 1.25 Å. In the seventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(2), and one O(4) atom. The C(12)-C(14) bond length is 1.51 Å. The C(12)-O(2) bond length is 1.30 Å. The C(12)-O(4) bond length is 1.25 Å. In the eighth C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(23) atom. The C(13)-C(15) bond length is 1.40 Å. The C(13)-C(23) bond length is 1.40 Å. In the ninth C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(24) atom. The C(14)-C(16) bond length is 1.40 Å. The C(14)-C(24) bond length is 1.40 Å. In the tenth C site, C(15) is bonded in a distorted single-bond geometry to one C(13) and one H(15,16) atom. The C(15)-H(15,16) bond length is 1.09 Å. In the eleventh C site, C(16) is bonded in a distorted single-bond geometry to one C(14) and one H(15,16) atom. The C(16)-H(15,16) bond length is 1.09 Å. In the twelfth C site, C(23) is bonded in a distorted single-bond geometry to one C(13) and one H(21,22) atom. The C(23)-H(21,22) bond length is 1.09 Å. In the thirteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(14) and one H(21,22) atom. The C(24)-H(21,22) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1,2); one C(5); and one C(7,8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1,2); one C(6); and one C(7,8) atom. The N(2)-C(1,2) bond length is 1.35 Å. The N(2)-C(7,8) bond length is 1.46 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1); one C(1,2); and one C(3,4) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1); one C(1,2); and one C(3,4) atom. The N(4)-C(1,2) bond length is 1.34 Å. The N(4)-C(3,4) bond length is 1.38 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1,2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1,2) atom. The H(2)-C(1,2) bond length is 1.08 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(3,4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3,4) atom. The H(4)-C(3,4) bond length is 1.08 Å. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(7,8) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(7,8) atom. In the eighth H site, H(15,16) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(21,22) is bonded in a single-bond geometry to one C(23) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(11) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(12) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(11) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(12) atom. Linkers: 2 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 1.79 A, density 1.63 g/cm3, surface area 4858.79 m2/g, accessible volume 0.12 cm3/g