Cu2C17H14(N2O)4(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one Cu2C17H14(N2O)4 cluster. In the Cu2C17H14(N2O)4 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one N(5), two equivalent N(6), one O(1), and one O(4) atom to form a mixture of edge and corner-sharing CuN3O2 trigonal bipyramids. The Cu(1)-N(5) bond length is 2.26 Å. Both Cu(1)-N(6) bond lengths are 2.02 Å. The Cu(1)-O(1) bond length is 1.95 Å. The Cu(1)-O(4) bond length is 1.96 Å. In the second Cu site, Cu(2) is bonded to one N(1), one N(2), one N(5), one O(2), and one O(3) atom to form corner-sharing CuN3O2 square pyramids. The Cu(2)-N(1) bond length is 2.01 Å. The Cu(2)-N(2) bond length is 2.02 Å. The Cu(2)-N(5) bond length is 1.98 Å. The Cu(2)-O(2) bond length is 2.26 Å. The Cu(2)-O(3) bond length is 2.03 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one C(3), one H(1), and one H(2) atom. The C(2)-C(3) bond length is 1.50 Å. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(8) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(5) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(5) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(6) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-H(6) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.51 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(3), and one O(4) atom. The C(9)-O(3) bond length is 1.28 Å. The C(9)-O(4) bond length is 1.28 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(7) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(9) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(9) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(10) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(10) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(2), and one H(11) atom. The C(14)-N(2) bond length is 1.35 Å. The C(14)-H(11) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one C(19), and one H(12) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-C(19) bond length is 1.39 Å. The C(15)-H(12) bond length is 1.09 Å. In the fifteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(1), and one H(13) atom. The C(16)-N(1) bond length is 1.35 Å. The C(16)-H(13) bond length is 1.09 Å. In the sixteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one N(1) and one H(14) atom. The C(17)-N(1) bond length is 1.35 Å. The C(17)-H(14) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(15) and one H(16) atom. The C(19)-H(16) bond length is 1.09 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(2), one C(16), and one C(17) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(10), and one C(14) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(4) atom. The N(3)-N(4) bond length is 1.17 Å. In the fourth N site, N(4) is bonded in a linear geometry to one N(3) and one N(5) atom. The N(4)-N(5) bond length is 1.21 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cu(1), one Cu(2), and one N(4) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to two equivalent Cu(1) and one N(7) atom. The N(6)-N(7) bond length is 1.21 Å. In the seventh N site, N(7) is bonded in a linear geometry to one N(6) and one N(8) atom. The N(7)-N(8) bond length is 1.16 Å. In the eighth N site, N(8) is bonded in a single-bond geometry to one N(7) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cu(2) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(9) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(9) atom. Linkers: 2 [O]C(=O)Cc1ccccc1C([O])=O. Metal clusters: 4 [Cu]. The MOF has largest included sphere 2.70 A, density 1.68 g/cm3, surface area 4398.83 m2/g, accessible volume 0.14 cm3/g