MnC8N3H6O2Cl(CH)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one MnC8N3H6O2Cl cluster. In the MnC8N3H6O2Cl cluster, Mn(1) is bonded to one N(2), one N(3), one O(1), one O(2), and two equivalent Cl(1) atoms to form distorted edge-sharing MnN2Cl2O2 pentagonal pyramids. The Mn(1)-N(2) bond length is 2.19 Å. The Mn(1)-N(3) bond length is 2.24 Å. The Mn(1)-O(1) bond length is 2.22 Å. The Mn(1)-O(2) bond length is 2.36 Å. There is one shorter (2.49 Å) and one longer (2.54 Å) Mn(1)-Cl(1) bond length. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one N(2) atom. The C(3)-C(4) bond length is 1.46 Å. The C(3)-N(2) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(3) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(3) bond length is 1.36 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(6) atom. The C(8)-N(3) bond length is 1.34 Å. The C(8)-H(6) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(7), and one H(8) atom. The C(9)-N(1) bond length is 1.45 Å. The C(9)-H(7) bond length is 1.10 Å. The C(9)-H(8) bond length is 1.10 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(10)-O(1) bond length is 1.27 Å. The C(10)-O(2) bond length is 1.27 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(1), one C(9), and one N(2) atom. The N(1)-N(2) bond length is 1.35 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Mn(1), one C(3), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Mn(1), one C(4), and one C(8) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Mn(1) and one C(10) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Mn(1) and one C(10) atom. Cl(1) is bonded in an L-shaped geometry to two equivalent Mn(1) atoms. Linkers: 2 [O]C(=O)Cn1ccc(-c2ccccn2)n1. Metal clusters: 1 Cl[Mn]1O[C]O1.Cl[Mn]1O[C]O1. The MOF has largest included sphere 2.25 A, density 1.78 g/cm3, surface area 3797.42 m2/g, accessible volume 0.11 cm3/g