ZnC15NH10O4(CH)8C4H2F is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, two 1-fluoro-2-methylprop-1-ene molecules, and one ZnC15NH10O4 cluster. In the ZnC15NH10O4 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 2.09 Å. The Zn(1)-O(2) bond length is 2.05 Å. The Zn(1)-O(3) bond length is 2.10 Å. The Zn(1)-O(4) bond length is 2.08 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.49 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(6)-H(5) bond length is 1.10 Å. In the seventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(1), and one O(2) atom. The C(14)-C(15) bond length is 1.50 Å. The C(14)-O(1) bond length is 1.28 Å. The C(14)-O(2) bond length is 1.27 Å. In the eighth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(20) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(20) bond length is 1.40 Å. In the ninth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(11) atom. The C(16)-H(11) bond length is 1.09 Å. In the tenth C site, C(20) is bonded in a distorted single-bond geometry to one C(15) and one H(15) atom. The C(20)-H(15) bond length is 1.09 Å. In the eleventh C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(3), and one O(4) atom. The C(21)-C(22) bond length is 1.50 Å. The C(21)-O(3) bond length is 1.27 Å. The C(21)-O(4) bond length is 1.28 Å. In the twelfth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(27) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(27) bond length is 1.40 Å. In the thirteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(16) atom. The C(23)-H(16) bond length is 1.09 Å. In the fourteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(27) and one H(19) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-H(19) bond length is 1.09 Å. In the fifteenth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(22), one C(26), and one H(20) atom. The C(27)-H(20) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(27) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(21) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(21) atom. Linkers: 1 [C][CH]/C(=[C]/F)[C@H]1[C@H](c2ccncc2)[C@H](c2ccccc2F)[C@H]1c1ccncc1 ,1 Fc1ccccc1[C@H]1[C@H](c2ccncc2)[C@H](c2ccccc2F)[C@H]1c1ccncc1 ,1 [C][CH]/C(=[C]/F)[C@H]1[C@@H](c2ccncc2)[C@H](c2ccccc2F)[C@@H]1c1ccncc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.37 A, density 1.52 g/cm3, surface area 4779.99 m2/g, accessible volume 0.15 cm3/g