C4H5CuC10NH10SO6C4NH5SO2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four isobutylene molecules, four schembl9269457 molecules, and two CuC10NH10SO6 clusters. In each CuC10NH10SO6 cluster, Cu(1) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(6) atom to form CuO5 square pyramids that share  a cornercorner with one S(1)CNO2 tetrahedra. The Cu(1)-O(1) bond length is 2.00 Å. The Cu(1)-O(2) bond length is 2.00 Å. The Cu(1)-O(4) bond length is 2.22 Å. The Cu(1)-O(5) bond length is 1.99 Å. The Cu(1)-O(6) bond length is 1.98 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(2)-N(1) bond length is 1.45 Å. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(4), one C(8), and one S(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(8) bond length is 1.40 Å. The C(3)-S(1) bond length is 1.76 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(5) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-C(9) bond length is 1.50 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(6) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(6) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one H(7) atom. The C(8)-H(7) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one H(10), one H(8), and one H(9) atom. The C(9)-H(10) bond length is 1.10 Å. The C(9)-H(8) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(10)-O(5) bond length is 1.27 Å. The C(10)-O(6) bond length is 1.27 Å. N(1) is bonded in a distorted trigonal planar geometry to one C(2), one H(3), and one S(1) atom. The N(1)-H(3) bond length is 1.03 Å. The N(1)-S(1) bond length is 1.63 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. S(1) is bonded to one C(3), one N(1), one O(3), and one O(4) atom to form distorted SCNO2 tetrahedra that share  a cornercorner with one Cu(1)O5 square pyramid. The S(1)-O(3) bond length is 1.45 Å. The S(1)-O(4) bond length is 1.46 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(10) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(10) atom. Linkers: 4 Cc1ccc(S(=O)(=O)NCC([O])=O)cc1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 4.63 A, density 1.50 g/cm3, surface area 4441.40 m2/g, accessible volume 0.18 cm3/g