AgC8H8S2(NO2)4 crystallizes in the monoclinic C2/c space group. Ag(1) is bonded to one N(1), one N(2), two equivalent N(3), and two equivalent O(2) atoms to form AgN4O2 octahedra that share corners with two equivalent S(1)O4 tetrahedra. The Ag(1)-N(1) bond length is 2.23 Å. The Ag(1)-N(2) bond length is 2.21 Å. Both Ag(1)-N(3) bond lengths are 2.21 Å. Both Ag(1)-O(2) bond lengths are 2.70 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(2), and one H(2) atom. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(3), and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-N(3) bond length is 1.34 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one N(3), and one H(4) atom. The C(4)-N(3) bond length is 1.34 Å. The C(4)-H(4) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1) and two equivalent C(1) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1) and two equivalent C(2) atoms. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(3), and one C(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share  a cornercorner with one Ag(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 48°. The S(1)-O(1) bond length is 1.68 Å. The S(1)-O(2) bond length is 1.46 Å. The S(1)-O(3) bond length is 1.46 Å. The S(1)-O(4) bond length is 1.45 Å. There are four inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Ag(1) and one S(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(1) is bonded in a distorted water-like geometry to one S(1) and one O(1) atom. The O(1)-O(1) bond length is 1.52 Å. Linkers: 4 c1cnccn1 ,2 [O]S([O])([O])OOS([O])([O])[O]. Metal clusters: 2 O=S(=O)=O.O=S(=O)=O.[Ag]. The MOF has largest included sphere 1.63 A, density 2.24 g/cm3, surface area 3259.11 m2/g, accessible volume 0.07 cm3/g