(CH)3PbC21N6H15O7 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules and eight PbC21N6H15O7 clusters. In each PbC21N6H15O7 cluster, Pb(1) is bonded in a 7-coordinate geometry to one N(1), one N(2), one N(3), one N(4), one O(2), one O(3), and one O(7) atom. The Pb(1)-N(1) bond length is 2.75 Å. The Pb(1)-N(2) bond length is 2.67 Å. The Pb(1)-N(3) bond length is 2.62 Å. The Pb(1)-N(4) bond length is 2.76 Å. The Pb(1)-O(2) bond length is 2.84 Å. The Pb(1)-O(3) bond length is 2.74 Å. The Pb(1)-O(7) bond length is 2.83 Å. There are twenty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one H(1) atom. The C(1)-C(6) bond length is 1.41 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one O(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-O(1) bond length is 1.39 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-H(4) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one N(1) atom. The C(6)-N(1) bond length is 1.41 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(1), and one H(5) atom. The C(7)-C(8) bond length is 1.46 Å. The C(7)-N(1) bond length is 1.29 Å. The C(7)-H(5) bond length is 1.10 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(2) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-N(2) bond length is 1.35 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(6) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(7) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(7) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(11)-H(8) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(12)-N(2) bond length is 1.34 Å. The C(12)-H(9) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(3), and one H(10) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-N(3) bond length is 1.34 Å. The C(13)-H(10) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(11) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(11) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(17), and one H(12) atom. The C(15)-C(17) bond length is 1.39 Å. The C(15)-H(12) bond length is 1.09 Å. In the fifteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one C(18), and one N(3) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(18) bond length is 1.46 Å. The C(16)-N(3) bond length is 1.35 Å. In the sixteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(15), one C(16), and one H(13) atom. The C(17)-H(13) bond length is 1.09 Å. In the seventeenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(4), and one H(14) atom. The C(18)-N(4) bond length is 1.29 Å. The C(18)-H(14) bond length is 1.10 Å. In the eighteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(20), one C(24), and one N(4) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-C(24) bond length is 1.41 Å. The C(19)-N(4) bond length is 1.41 Å. In the nineteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(15) atom. The C(20)-H(15) bond length is 1.09 Å. In the twentieth C site, C(22) is bonded in a distorted single-bond geometry to one O(1) atom. The C(22)-O(1) bond length is 1.38 Å. In the twenty-first C site, C(24) is bonded in a distorted single-bond geometry to one C(19) and one H(18) atom. The C(24)-H(18) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Pb(1), one C(6), and one C(7) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pb(1), one C(12), and one C(8) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one Pb(1), one C(13), and one C(16) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Pb(1), one C(18), and one C(19) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(4) atom. The N(5)-O(2) bond length is 1.28 Å. The N(5)-O(3) bond length is 1.29 Å. The N(5)-O(4) bond length is 1.25 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one O(5), one O(6), and one O(7) atom. The N(6)-O(5) bond length is 1.28 Å. The N(6)-O(6) bond length is 1.27 Å. The N(6)-O(7) bond length is 1.27 Å. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(22) and one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Pb(1) and one N(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Pb(1) and one N(5) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(5) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(6) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(6) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Pb(1) and one N(6) atom. Linkers: 2 [c]1[c]cc(Oc2ccc(/N=C/c3ccccn3)cc2)cc1 ,2 [CH]=NC(=[CH])/C=N/c1ccc(Oc2ccc(/N=C/c3ccccn3)cc2)cc1 ,4 C(=N/c1ccc(Oc2ccc(/N=C/c3ccccn3)cc2)cc1)\c1ccccn1. Metal clusters: 2 [O][N+](=O)[O-].[O][N+](=O)[O-].[O][N+](=O)[O-].[O][N+](=O)[O-].[Pb].[Pb]. The MOF has largest included sphere 5.09 A, density 1.67 g/cm3, surface area 3607.18 m2/g, accessible volume 0.16 cm3/g