CuH10(C5O4)2(C3H2)4(CH2)2(CH3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules; two 02329_fluka molecules; two 2,3-dimethyl-1,3-butadiene molecules; and one CuH10(C5O4)2 cluster. In the CuH10(C5O4)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(4) atoms. Both Cu(1)-O(2) bond lengths are 1.92 Å. Both Cu(1)-O(4) bond lengths are 2.01 Å. There are five inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(7) and one O(1) atom. The C(3)-C(7) bond length is 1.42 Å. The C(3)-O(1) bond length is 1.35 Å. In the second C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(9) atom. The C(7)-C(12) bond length is 1.50 Å. The C(7)-C(9) bond length is 1.41 Å. In the third C site, C(9) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(9)-H(5) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one H(6), one H(7), and one O(1) atom. The C(10)-H(6) bond length is 1.11 Å. The C(10)-H(7) bond length is 1.10 Å. The C(10)-O(1) bond length is 1.43 Å. In the fifth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(2), and one O(3) atom. The C(12)-O(2) bond length is 1.28 Å. The C(12)-O(3) bond length is 1.28 Å. There are five inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(13) is bonded in a distorted single-bond geometry to one O(3) and one O(4) atom. The H(13)-O(3) bond length is 1.65 Å. The H(13)-O(4) bond length is 1.02 Å. In the fifth H site, H(14) is bonded in a single-bond geometry to one O(4) atom. The H(14)-O(4) bond length is 0.99 Å. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted water-like geometry to one C(12) and one H(13) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one C(10) and one C(3) atom. In the third O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one H(13), and one H(14) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(12) atom. Linkers: 2 [CH2]Oc1cc(-c2ccc(-c3ccc(C([O])=O)c(OCCC)c3)cc2)ccc1C([O])=O ,2 [CH]Oc1cc(-c2ccc(-c3ccc(C([O])=O)c(OCCC)c3)cc2)ccc1C([O])=O. Metal clusters: 1 O.O.O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 2.81 A, density 1.45 g/cm3, surface area 4834.42 m2/g, accessible volume 0.19 cm3/g