Zn2C57H37(N6O7)2(CH)3 crystallizes in the triclinic P1 space group. The structure consists of three 02329_fluka molecules inside a Zn2C57H37(N6O7)2 framework. In the Zn2C57H37(N6O7)2 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(2), one N(3), and one O(1) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-N(2) bond length is 2.01 Å. The Zn(1)-N(3) bond length is 2.00 Å. The Zn(1)-O(1) bond length is 1.97 Å. In the second Zn site, Zn(2) is bonded in a distorted tetrahedral geometry to one N(7), one N(8), one N(9), and one O(7) atom. The Zn(2)-N(7) bond length is 2.05 Å. The Zn(2)-N(8) bond length is 2.01 Å. The Zn(2)-N(9) bond length is 2.03 Å. The Zn(2)-O(7) bond length is 1.97 Å. There are fifty-seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(4), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(4) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(2)-N(1) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(2) atom. The C(3)-C(5) bond length is 1.49 Å. The C(3)-O(1) bond length is 1.30 Å. The C(3)-O(2) bond length is 1.26 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(3) atom. The C(4)-N(4) bond length is 1.39 Å. The C(4)-H(3) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(8) atom. The C(5)-C(7) bond length is 1.41 Å. The C(5)-C(8) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(10), one C(9), and one N(4) atom. The C(6)-C(10) bond length is 1.39 Å. The C(6)-C(9) bond length is 1.39 Å. The C(6)-N(4) bond length is 1.42 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(5) atom. The C(7)-C(11) bond length is 1.52 Å. The C(7)-C(12) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(13), one C(5), and one H(4) atom. The C(8)-C(13) bond length is 1.39 Å. The C(8)-H(4) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(14), one C(6), and one H(5) atom. The C(9)-C(14) bond length is 1.40 Å. The C(9)-H(5) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(15), one C(6), and one H(6) atom. The C(10)-C(15) bond length is 1.40 Å. The C(10)-H(6) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(4) atom. The C(11)-O(3) bond length is 1.26 Å. The C(11)-O(4) bond length is 1.28 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one O(5) atom. The C(12)-O(5) bond length is 1.41 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(16), one C(8), and one H(7) atom. The C(13)-C(16) bond length is 1.39 Å. The C(13)-H(7) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(17), one C(9), and one N(5) atom. The C(14)-C(17) bond length is 1.39 Å. The C(14)-N(5) bond length is 1.42 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(10), one C(17), and one N(6) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-N(6) bond length is 1.41 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(13) and one H(8) atom. The C(16)-H(8) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(14), one C(15), and one H(9) atom. The C(17)-H(9) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one O(5) atom. The C(18)-O(5) bond length is 1.37 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one N(5), one N(7), and one H(10) atom. The C(19)-N(5) bond length is 1.36 Å. The C(19)-N(7) bond length is 1.33 Å. The C(19)-H(10) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(11) atom. The C(20)-N(5) bond length is 1.39 Å. The C(20)-H(11) bond length is 1.08 Å. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(26), one N(6), and one H(12) atom. The C(21)-C(26) bond length is 1.36 Å. The C(21)-N(6) bond length is 1.39 Å. The C(21)-H(12) bond length is 1.08 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one N(3), one N(6), and one H(13) atom. The C(22)-N(3) bond length is 1.33 Å. The C(22)-N(6) bond length is 1.37 Å. The C(22)-H(13) bond length is 1.08 Å. In the twenty-third C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(16) atom. The C(25)-N(7) bond length is 1.39 Å. The C(25)-H(16) bond length is 1.08 Å. In the twenty-fourth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(21), one N(3), and one H(17) atom. The C(26)-N(3) bond length is 1.39 Å. The C(26)-H(17) bond length is 1.08 Å. In the twenty-fifth C site, C(27) is bonded in a distorted single-bond geometry to one C(29) and one H(18) atom. The C(27)-C(29) bond length is 1.40 Å. The C(27)-H(18) bond length is 1.09 Å. In the twenty-sixth C site, C(28) is bonded in a distorted single-bond geometry to one C(29) and one H(19) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-H(19) bond length is 1.09 Å. In the twenty-seventh C site, C(29) is bonded in a trigonal planar geometry to one C(27), one C(28), and one C(30) atom. The C(29)-C(30) bond length is 1.48 Å. In the twenty-eighth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(8), and one O(9) atom. The C(30)-O(8) bond length is 1.24 Å. The C(30)-O(9) bond length is 1.34 Å. In the twenty-ninth C site, C(31) is bonded in a trigonal planar geometry to one N(10), one N(8), and one H(20) atom. The C(31)-N(10) bond length is 1.37 Å. The C(31)-N(8) bond length is 1.33 Å. The C(31)-H(20) bond length is 1.08 Å. In the thirtieth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(34), one N(8), and one H(21) atom. The C(32)-C(34) bond length is 1.36 Å. The C(32)-N(8) bond length is 1.38 Å. The C(32)-H(21) bond length is 1.08 Å. In the thirty-first C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(6), and one O(7) atom. The C(33)-C(35) bond length is 1.50 Å. The C(33)-O(6) bond length is 1.26 Å. The C(33)-O(7) bond length is 1.30 Å. In the thirty-second C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(32), one N(10), and one H(23) atom. The C(34)-N(10) bond length is 1.39 Å. The C(34)-H(23) bond length is 1.08 Å. In the thirty-third C site, C(35) is bonded in a trigonal planar geometry to one C(33), one C(37), and one C(38) atom. The C(35)-C(37) bond length is 1.41 Å. The C(35)-C(38) bond length is 1.40 Å. In the thirty-fourth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(39), one C(40), and one N(10) atom. The C(36)-C(39) bond length is 1.39 Å. The C(36)-C(40) bond length is 1.39 Å. The C(36)-N(10) bond length is 1.42 Å. In the thirty-fifth C site, C(37) is bonded in a trigonal planar geometry to one C(35), one C(41), and one C(42) atom. The C(37)-C(41) bond length is 1.52 Å. The C(37)-C(42) bond length is 1.40 Å. In the thirty-sixth C site, C(38) is bonded in a distorted single-bond geometry to one C(35), one C(43), and one H(24) atom. The C(38)-C(43) bond length is 1.39 Å. The C(38)-H(24) bond length is 1.09 Å. In the thirty-seventh C site, C(39) is bonded in a distorted trigonal planar geometry to one C(36), one C(44), and one H(25) atom. The C(39)-C(44) bond length is 1.39 Å. The C(39)-H(25) bond length is 1.09 Å. In the thirty-eighth C site, C(40) is bonded in a distorted single-bond geometry to one C(36), one C(45), and one H(26) atom. The C(40)-C(45) bond length is 1.39 Å. The C(40)-H(26) bond length is 1.09 Å. In the thirty-ninth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(10), and one O(11) atom. The C(41)-O(10) bond length is 1.26 Å. The C(41)-O(11) bond length is 1.28 Å. In the fortieth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(37), one C(46), and one O(12) atom. The C(42)-C(46) bond length is 1.39 Å. The C(42)-O(12) bond length is 1.41 Å. In the forty-first C site, C(43) is bonded in a distorted trigonal planar geometry to one C(38), one C(46), and one H(27) atom. The C(43)-C(46) bond length is 1.40 Å. The C(43)-H(27) bond length is 1.09 Å. In the forty-second C site, C(44) is bonded in a distorted trigonal planar geometry to one C(39), one C(47), and one N(11) atom. The C(44)-C(47) bond length is 1.39 Å. The C(44)-N(11) bond length is 1.43 Å. In the forty-third C site, C(45) is bonded in a distorted trigonal planar geometry to one C(40), one C(47), and one N(12) atom. The C(45)-C(47) bond length is 1.40 Å. The C(45)-N(12) bond length is 1.42 Å. In the forty-fourth C site, C(46) is bonded in a distorted single-bond geometry to one C(42), one C(43), and one H(28) atom. The C(46)-H(28) bond length is 1.09 Å. In the forty-fifth C site, C(47) is bonded in a distorted single-bond geometry to one C(44), one C(45), and one H(29) atom. The C(47)-H(29) bond length is 1.09 Å. In the forty-sixth C site, C(48) is bonded in a distorted single-bond geometry to one C(53) and one O(12) atom. The C(48)-C(53) bond length is 1.40 Å. The C(48)-O(12) bond length is 1.37 Å. In the forty-seventh C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(55), one N(11), and one H(30) atom. The C(49)-C(55) bond length is 1.37 Å. The C(49)-N(11) bond length is 1.39 Å. The C(49)-H(30) bond length is 1.08 Å. In the forty-eighth C site, C(50) is bonded in a trigonal planar geometry to one N(11), one N(9), and one H(31) atom. The C(50)-N(11) bond length is 1.36 Å. The C(50)-N(9) bond length is 1.33 Å. The C(50)-H(31) bond length is 1.08 Å. In the forty-ninth C site, C(51) is bonded in a trigonal planar geometry to one N(12), one N(2), and one H(32) atom. The C(51)-N(12) bond length is 1.37 Å. The C(51)-N(2) bond length is 1.33 Å. The C(51)-H(32) bond length is 1.08 Å. In the fiftieth C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(56), one N(12), and one H(33) atom. The C(52)-C(56) bond length is 1.37 Å. The C(52)-N(12) bond length is 1.39 Å. The C(52)-H(33) bond length is 1.09 Å. In the fifty-first C site, C(53) is bonded in a distorted trigonal planar geometry to one C(48), one C(57), and one H(34) atom. The C(53)-C(57) bond length is 1.39 Å. The C(53)-H(34) bond length is 1.09 Å. In the fifty-second C site, C(55) is bonded in a distorted bent 120 degrees geometry to one C(49), one N(9), and one H(36) atom. The C(55)-N(9) bond length is 1.39 Å. The C(55)-H(36) bond length is 1.08 Å. In the fifty-third C site, C(56) is bonded in a distorted trigonal planar geometry to one C(52), one N(2), and one H(37) atom. The C(56)-N(2) bond length is 1.39 Å. The C(56)-H(37) bond length is 1.08 Å. In the fifty-fourth C site, C(57) is bonded in a distorted single-bond geometry to one C(53), one C(59), and one H(38) atom. The C(57)-C(59) bond length is 1.41 Å. The C(57)-H(38) bond length is 1.09 Å. In the fifty-fifth C site, C(58) is bonded in a distorted single-bond geometry to one C(59) and one H(39) atom. The C(58)-C(59) bond length is 1.41 Å. The C(58)-H(39) bond length is 1.09 Å. In the fifty-sixth C site, C(59) is bonded in a trigonal planar geometry to one C(57), one C(58), and one C(60) atom. The C(59)-C(60) bond length is 1.49 Å. In the fifty-seventh C site, C(60) is bonded in a distorted bent 120 degrees geometry to one C(59), one O(13), and one O(14) atom. The C(60)-O(13) bond length is 1.33 Å. The C(60)-O(14) bond length is 1.25 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(51), and one C(56) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(22), and one C(26) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(6) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(14), one C(19), and one C(20) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(15), one C(21), and one C(22) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Zn(2), one C(19), and one C(25) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Zn(2), one C(31), and one C(32) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Zn(2), one C(50), and one C(55) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one C(31), one C(34), and one C(36) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one C(44), one C(49), and one C(50) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one C(45), one C(51), and one C(52) atom. There are thirty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(27) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(28) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(31) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(32) atom. In the twentieth H site, H(22) is bonded in a linear geometry to one O(4) and one O(9) atom. The H(22)-O(4) bond length is 1.45 Å. The H(22)-O(9) bond length is 1.06 Å. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(34) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(38) atom. In the twenty-third H site, H(25) is bonded in a single-bond geometry to one C(39) atom. In the twenty-fourth H site, H(26) is bonded in a single-bond geometry to one C(40) atom. In the twenty-fifth H site, H(27) is bonded in a single-bond geometry to one C(43) atom. In the twenty-sixth H site, H(28) is bonded in a single-bond geometry to one C(46) atom. In the twenty-seventh H site, H(29) is bonded in a single-bond geometry to one C(47) atom. In the twenty-eighth H site, H(30) is bonded in a single-bond geometry to one C(49) atom. In the twenty-ninth H site, H(31) is bonded in a single-bond geometry to one C(50) atom. In the thirtieth H site, H(32) is bonded in a single-bond geometry to one C(51) atom. In the thirty-first H site, H(33) is bonded in a single-bond geometry to one C(52) atom. In the thirty-second H site, H(34) is bonded in a single-bond geometry to one C(53) atom. In the thirty-third H site, H(36) is bonded in a single-bond geometry to one C(55) atom. In the thirty-fourth H site, H(37) is bonded in a single-bond geometry to one C(56) atom. In the thirty-fifth H site, H(38) is bonded in a single-bond geometry to one C(57) atom. In the thirty-sixth H site, H(39) is bonded in a single-bond geometry to one C(58) atom. In the thirty-seventh H site, H(40) is bonded in a linear geometry to one O(11) and one O(13) atom. The H(40)-O(11) bond length is 1.43 Å. The H(40)-O(13) bond length is 1.07 Å. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(11) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one C(11) and one H(22) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(12) and one C(18) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(33) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Zn(2) and one C(33) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(30) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one C(30) and one H(22) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(41) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one C(41) and one H(40) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one C(42) and one C(48) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one C(60) and one H(40) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one C(60) atom. Linkers: 2 c1cn(-c2cc(-n3ccnc3)cc(-n3ccnc3)c2)cn1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 3.81 A, density 1.47 g/cm3, surface area 4555.00 m2/g, accessible volume 0.22 cm3/g