ZnC10NH6O4(HC2N)2C6H4SO2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two di-isopropenylsulfon molecules, one HC2N cluster, and one ZnC10NH6O4 cluster. In the HC2N cluster, there are four inequivalent C sites. In the first C site, C(6) is bonded in a trigonal planar geometry to one C(10), one C(17), and one C(7) atom. The C(6)-C(10) bond length is 1.40 Å. The C(6)-C(17) bond length is 1.47 Å. The C(6)-C(7) bond length is 1.40 Å. In the second C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the third C site, C(10) is bonded in a distorted single-bond geometry to one C(6) and one H(7) atom. The C(10)-H(7) bond length is 1.09 Å. In the fourth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(6), one N(2), and one N(3) atom. The C(17)-N(2) bond length is 1.35 Å. The C(17)-N(3) bond length is 1.35 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(17) and one N(3) atom. The N(2)-N(3) bond length is 1.32 Å. In the second N site, N(3) is bonded in a distorted bent 120 degrees geometry to one C(17) and one N(2) atom. There are two inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the ZnC10NH6O4 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 2.06 Å. The Zn(1)-O(2) bond length is 2.08 Å. The Zn(1)-O(3) bond length is 2.10 Å. The Zn(1)-O(4) bond length is 2.05 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(8) and one H(1) atom. The C(1)-C(8) bond length is 1.40 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(2), and one O(3) atom. The C(4)-C(11) bond length is 1.51 Å. The C(4)-O(2) bond length is 1.27 Å. The C(4)-O(3) bond length is 1.27 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 1.09 Å. In the fourth C site, C(8) is bonded in a trigonal planar geometry to one C(1), one C(12), and one C(13) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(13) bond length is 1.50 Å. In the fifth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-H(6) bond length is 1.09 Å. In the sixth C site, C(11) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(4) atom. The C(11)-C(18) bond length is 1.40 Å. The C(11)-C(20) bond length is 1.40 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. In the eighth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(1), and one O(4) atom. The C(13)-O(1) bond length is 1.28 Å. The C(13)-O(4) bond length is 1.27 Å. In the ninth C site, C(18) is bonded in a distorted single-bond geometry to one C(11) and one H(10) atom. The C(18)-H(10) bond length is 1.09 Å. In the tenth C site, C(20) is bonded in a distorted single-bond geometry to one C(11) and one H(12) atom. The C(20)-H(12) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(5), and one C(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(4) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(13) atom. Linkers: 1 c1cc(-c2nnc(-c3ccncc3)nn2)ccn1 ,2 [O]C(=O)c1ccc(S(=O)(=O)c2ccc(C([O])=O)cc2)cc1. Metal clusters: 1 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 5.05 A, density 1.33 g/cm3, surface area 4171.80 m2/g, accessible volume 0.23 cm3/g