DyC35H20(NO4)2CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a DyC35H20(NO4)2 framework. In the DyC35H20(NO4)2 framework, Dy(1) is bonded in a 8-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Dy(1)-N(1) bond length is 2.51 Å. The Dy(1)-N(2) bond length is 2.52 Å. The Dy(1)-O(1) bond length is 2.24 Å. The Dy(1)-O(2) bond length is 2.38 Å. The Dy(1)-O(3) bond length is 2.47 Å. The Dy(1)-O(4) bond length is 2.37 Å. The Dy(1)-O(5) bond length is 2.44 Å. The Dy(1)-O(6) bond length is 2.26 Å. There are thirty-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1) atom. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(12) bond length is 1.43 Å. The C(4)-C(5) bond length is 1.42 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(2) atom. The C(5)-C(6) bond length is 1.44 Å. The C(5)-N(2) bond length is 1.36 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(10), one C(5), and one N(1) atom. The C(6)-C(10) bond length is 1.42 Å. The C(6)-N(1) bond length is 1.36 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(1), and one H(4) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(1) bond length is 1.34 Å. The C(7)-H(4) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(6) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-H(6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(9) atom. The C(10)-C(11) bond length is 1.43 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(7) atom. The C(11)-C(12) bond length is 1.37 Å. The C(11)-H(7) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(4), and one H(8) atom. The C(12)-H(8) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(4), and one O(5) atom. The C(13)-C(14) bond length is 1.49 Å. The C(13)-O(4) bond length is 1.28 Å. The C(13)-O(5) bond length is 1.28 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(16) atom. The C(14)-C(15) bond length is 1.42 Å. The C(14)-C(16) bond length is 1.39 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one H(9) atom. The C(15)-C(18) bond length is 1.38 Å. The C(15)-H(9) bond length is 1.09 Å. In the fifteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(14), one C(17), and one H(10) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-H(10) bond length is 1.09 Å. In the sixteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(17), and one C(18) atom. The C(17)-C(17) bond length is 1.44 Å. The C(17)-C(18) bond length is 1.42 Å. In the seventeenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(11) atom. The C(18)-H(11) bond length is 1.09 Å. In the eighteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(1), and one O(6) atom. The C(19)-C(20) bond length is 1.49 Å. The C(19)-O(1) bond length is 1.27 Å. The C(19)-O(6) bond length is 1.27 Å. In the nineteenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(22) atom. The C(20)-C(21) bond length is 1.42 Å. The C(20)-C(22) bond length is 1.38 Å. In the twentieth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(12,17) atom. The C(21)-H(12,17) bond length is 1.09 Å. In the twenty-first C site, C(22) is bonded in a distorted trigonal planar geometry to one C(20), one C(23), and one H(13) atom. The C(22)-C(23) bond length is 1.41 Å. The C(22)-H(13) bond length is 1.09 Å. In the twenty-second C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(23), and one C(24) atom. The C(23)-C(23) bond length is 1.44 Å. The C(23)-C(24) bond length is 1.42 Å. In the twenty-third C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(14,20) atom. The C(24)-H(14,20) bond length is 1.09 Å. In the twenty-fourth C site, C(25) is bonded in a bent 120 degrees geometry to one C(26), one O(2), and one O(3) atom. The C(25)-C(26) bond length is 1.48 Å. The C(25)-O(2) bond length is 1.28 Å. The C(25)-O(3) bond length is 1.29 Å. In the twenty-fifth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(29) atom. The C(26)-C(27) bond length is 1.38 Å. The C(26)-C(29) bond length is 1.42 Å. In the twenty-sixth C site, C(27) is bonded in a distorted single-bond geometry to one C(26), one C(28), and one H(15) atom. The C(27)-C(28) bond length is 1.41 Å. The C(27)-H(15) bond length is 1.09 Å. In the twenty-seventh C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(28), and one C(30) atom. The C(28)-C(28) bond length is 1.43 Å. The C(28)-C(30) bond length is 1.42 Å. In the twenty-eighth C site, C(29) is bonded in a distorted single-bond geometry to one C(26) and one H(16) atom. The C(29)-H(16) bond length is 1.09 Å. In the twenty-ninth C site, C(30) is bonded in a distorted single-bond geometry to one C(28) and one H(12,17) atom. The C(30)-H(12,17) bond length is 1.09 Å. In the thirtieth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(7), and one O(8) atom. The C(31)-C(32) bond length is 1.49 Å. The C(31)-O(7) bond length is 1.23 Å. The C(31)-O(8) bond length is 1.34 Å. In the thirty-first C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(34) atom. The C(32)-C(33) bond length is 1.42 Å. The C(32)-C(34) bond length is 1.39 Å. In the thirty-second C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(18) atom. The C(33)-H(18) bond length is 1.09 Å. In the thirty-third C site, C(34) is bonded in a distorted single-bond geometry to one C(32), one C(35), and one H(19) atom. The C(34)-C(35) bond length is 1.41 Å. The C(34)-H(19) bond length is 1.09 Å. In the thirty-fourth C site, C(35) is bonded in a trigonal planar geometry to one C(34), one C(35), and one C(36) atom. The C(35)-C(35) bond length is 1.44 Å. The C(35)-C(36) bond length is 1.42 Å. In the thirty-fifth C site, C(36) is bonded in a distorted single-bond geometry to one C(35) and one H(14,20) atom. The C(36)-H(14,20) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Dy(1), one C(6), and one C(7) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Dy(1), one C(1), and one C(5) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(12,17) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(14,20) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(27) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(29) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(33) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(34) atom. In the eighteenth H site, H(21) is bonded in a distorted bent 150 degrees geometry to one O(3) and one O(8) atom. The H(21)-O(3) bond length is 1.63 Å. The H(21)-O(8) bond length is 1.01 Å. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Dy(1) and one C(13) atom. In the second O site, O(6) is bonded in a bent 150 degrees geometry to one Dy(1) and one C(19) atom. In the third O site, O(7) is bonded in a single-bond geometry to one C(31) atom. In the fourth O site, O(8) is bonded in a bent 120 degrees geometry to one C(31) and one H(21) atom. In the fifth O site, O(1) is bonded in a bent 150 degrees geometry to one Dy(1) and one C(19) atom. In the sixth O site, O(2) is bonded in a distorted L-shaped geometry to one Dy(1) and one C(25) atom. In the seventh O site, O(3) is bonded in a 3-coordinate geometry to one Dy(1), one C(25), and one H(21) atom. In the eighth O site, O(4) is bonded in a distorted L-shaped geometry to one Dy(1) and one C(13) atom. Linkers: 3 [O]C(=O)c1ccc2cc(C([O])=O)ccc2c1. Metal clusters: 1 [C]1O[Dy]23(O1)(O[C]O2)O[C]O[Dy]12(O[C]O1)(O[C]O2)O[C]O3. RCSR code: pcu. The MOF has largest included sphere 2.96 A, density 1.71 g/cm3, surface area 3901.40 m2/g, accessible volume 0.17 cm3/g