LaC34N4H16O7Br6(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a LaC34N4H16O7Br6 framework. In the LaC34N4H16O7Br6 framework, La(1) is bonded in a 8-coordinate geometry to one N(1), one N(2), one N(3), one N(4), one O(3), one O(4), one O(5), and one O(6) atom. The La(1)-N(1) bond length is 2.77 Å. The La(1)-N(2) bond length is 2.76 Å. The La(1)-N(3) bond length is 2.77 Å. The La(1)-N(4) bond length is 2.73 Å. The La(1)-O(3) bond length is 2.34 Å. The La(1)-O(4) bond length is 2.38 Å. The La(1)-O(5) bond length is 2.54 Å. The La(1)-O(6) bond length is 2.50 Å. There are thirty-four inequivalent C sites. In the first C site, C(14) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(6) atom. The C(14)-C(11) bond length is 1.52 Å. The C(14)-C(12) bond length is 1.40 Å. The C(14)-C(6) bond length is 1.40 Å. In the second C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(23) atom. The C(15)-C(13) bond length is 1.40 Å. The C(15)-C(17) bond length is 1.40 Å. The C(15)-C(23) bond length is 1.53 Å. In the third C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(35), one N(3), and one H(3) atom. The C(16)-C(35) bond length is 1.41 Å. The C(16)-N(3) bond length is 1.33 Å. The C(16)-H(3) bond length is 1.09 Å. In the fourth C site, C(17) is bonded in a trigonal planar geometry to one C(12), one C(15), and one Br(6) atom. The C(17)-C(12) bond length is 1.40 Å. The C(17)-Br(6) bond length is 1.90 Å. In the fifth C site, C(18) is bonded in a trigonal planar geometry to one C(26), one C(3), and one C(4) atom. The C(18)-C(26) bond length is 1.43 Å. The C(18)-C(3) bond length is 1.43 Å. The C(18)-C(4) bond length is 1.41 Å. In the sixth C site, C(19) is bonded in a trigonal planar geometry to one C(8), one C(9), and one Br(2) atom. The C(19)-C(8) bond length is 1.40 Å. The C(19)-C(9) bond length is 1.40 Å. The C(19)-Br(2) bond length is 1.90 Å. In the seventh C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(20)-N(2) bond length is 1.33 Å. The C(20)-H(6) bond length is 1.09 Å. In the eighth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(1), and one O(3) atom. The C(21)-C(9) bond length is 1.53 Å. The C(21)-O(1) bond length is 1.24 Å. The C(21)-O(3) bond length is 1.29 Å. In the ninth C site, C(22) is bonded in a distorted single-bond geometry to one C(5) and one H(7) atom. The C(22)-C(5) bond length is 1.41 Å. The C(22)-H(7) bond length is 1.09 Å. In the tenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(5), and one O(7) atom. The C(23)-O(5) bond length is 1.27 Å. The C(23)-O(7) bond length is 1.26 Å. In the eleventh C site, C(24) is bonded in a distorted trigonal planar geometry to one C(28), one N(1), and one H(8) atom. The C(24)-C(28) bond length is 1.41 Å. The C(24)-N(1) bond length is 1.33 Å. The C(24)-H(8) bond length is 1.09 Å. In the twelfth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(1), one C(30), and one N(4) atom. The C(25)-C(1) bond length is 1.44 Å. The C(25)-C(30) bond length is 1.42 Å. The C(25)-N(4) bond length is 1.36 Å. In the thirteenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(10), one C(18), and one H(9) atom. The C(26)-C(10) bond length is 1.36 Å. The C(26)-H(9) bond length is 1.09 Å. In the fourteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(10) atom. The C(27)-N(4) bond length is 1.33 Å. The C(27)-H(10) bond length is 1.09 Å. In the fifteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(24) and one H(11) atom. The C(28)-H(11) bond length is 1.09 Å. In the sixteenth C site, C(30) is bonded in a trigonal planar geometry to one C(25), one C(32), and one C(36) atom. The C(30)-C(32) bond length is 1.41 Å. The C(30)-C(36) bond length is 1.43 Å. In the seventeenth C site, C(32) is bonded in a distorted single-bond geometry to one C(30) and one H(14) atom. The C(32)-H(14) bond length is 1.09 Å. In the eighteenth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(25), one C(7), and one N(3) atom. The C(1)-C(7) bond length is 1.42 Å. The C(1)-N(3) bond length is 1.36 Å. In the nineteenth C site, C(33) is bonded in a distorted trigonal planar geometry to one C(35), one C(7), and one H(15) atom. The C(33)-C(35) bond length is 1.38 Å. The C(33)-C(7) bond length is 1.41 Å. The C(33)-H(15) bond length is 1.09 Å. In the twentieth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(2) atom. The C(2)-C(3) bond length is 1.44 Å. The C(2)-C(5) bond length is 1.42 Å. The C(2)-N(2) bond length is 1.36 Å. In the twenty-first C site, C(34) is bonded in a distorted single-bond geometry to one C(7) and one H(16) atom. The C(34)-C(7) bond length is 1.43 Å. The C(34)-H(16) bond length is 1.09 Å. In the twenty-second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(18), one C(2), and one N(1) atom. The C(3)-N(1) bond length is 1.36 Å. In the twenty-third C site, C(35) is bonded in a distorted trigonal planar geometry to one C(16), one C(33), and one H(17) atom. The C(35)-H(17) bond length is 1.09 Å. In the twenty-fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(18) and one H(1) atom. The C(4)-H(1) bond length is 1.09 Å. In the twenty-fifth C site, C(36) is bonded in a distorted single-bond geometry to one C(30) and one H(18) atom. The C(36)-H(18) bond length is 1.09 Å. In the twenty-sixth C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(22) atom. The C(5)-C(10) bond length is 1.43 Å. In the twenty-seventh C site, C(6) is bonded in a trigonal planar geometry to one C(13), one C(14), and one Br(1) atom. The C(6)-C(13) bond length is 1.40 Å. The C(6)-Br(1) bond length is 1.90 Å. In the twenty-eighth C site, C(7) is bonded in a trigonal planar geometry to one C(1), one C(33), and one C(34) atom. In the twenty-ninth C site, C(8) is bonded in a trigonal planar geometry to one C(19), one C(9), and one Br(3) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-Br(3) bond length is 1.90 Å. In the thirtieth C site, C(9) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(8) atom. In the thirty-first C site, C(10) is bonded in a distorted single-bond geometry to one C(26), one C(5), and one H(2) atom. The C(10)-H(2) bond length is 1.09 Å. In the thirty-second C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(2), and one O(4) atom. The C(11)-O(2) bond length is 1.25 Å. The C(11)-O(4) bond length is 1.28 Å. In the thirty-third C site, C(12) is bonded in a trigonal planar geometry to one C(14), one C(17), and one Br(4) atom. The C(12)-Br(4) bond length is 1.89 Å. In the thirty-fourth C site, C(13) is bonded in a trigonal planar geometry to one C(15), one C(6), and one Br(5) atom. The C(13)-Br(5) bond length is 1.89 Å. There are four inequivalent N sites. In the first N site, N(4) is bonded in a distorted trigonal planar geometry to one La(1), one C(25), and one C(27) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one La(1), one C(2), and one C(20) atom. In the third N site, N(1) is bonded in a distorted trigonal planar geometry to one La(1), one C(24), and one C(3) atom. In the fourth N site, N(3) is bonded in a distorted bent 120 degrees geometry to one La(1), one C(1), and one C(16) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(6) and one O(7) atom. The H(4)-O(6) bond length is 1.01 Å. The H(4)-O(7) bond length is 1.66 Å. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one O(2) and one O(6) atom. The H(5)-O(2) bond length is 1.67 Å. The H(5)-O(6) bond length is 1.00 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(27) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(28) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(32) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(33) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(34) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(35) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(36) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(21) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one C(11) and one H(5) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one La(1) and one C(21) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one La(1) and one C(11) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one La(1) and one C(23) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one La(1), one H(4), and one H(5) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one C(23) and one H(4) atom. There are six inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one C(6) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one C(19) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one C(12) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one C(13) atom. In the sixth Br site, Br(6) is bonded in a single-bond geometry to one C(17) atom. Linkers: 6 [O]C(=O)c1c(Br)c(Br)c(C([O])=O)c(Br)c1Br ,2 c1cnc2c(c1)ccc1cccnc12. Metal clusters: 4 O.O=[C]O[La](O[C]=O)O[C]=O. RCSR code: hcb. The MOF has largest included sphere 3.38 A, density 2.06 g/cm3, surface area 3228.05 m2/g, accessible volume 0.13 cm3/g