CHPbC14AsNH9O12 crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a PbC14AsNH9O12 framework. In the PbC14AsNH9O12 framework, Pb(1) is bonded in a 4-coordinate geometry to one O(11), one O(6), and two equivalent O(10) atoms. The Pb(1)-O(11) bond length is 2.37 Å. The Pb(1)-O(6) bond length is 2.67 Å. There is one shorter (2.44 Å) and one longer (2.65 Å) Pb(1)-O(10) bond length. There are fourteen inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one O(3) atom. The C(2)-C(3) bond length is 1.42 Å. The C(2)-O(3) bond length is 1.33 Å. In the second C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-N(1) bond length is 1.43 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(2) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one As(1) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-As(1) bond length is 1.93 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(4) atom. The C(7)-C(12) bond length is 1.39 Å. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(4) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(14), one C(7), and one C(9) atom. The C(8)-C(14) bond length is 1.48 Å. The C(8)-C(9) bond length is 1.40 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(5) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(5) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.51 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(6) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(6) bond length is 1.08 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(7) atom. The C(12)-C(13) bond length is 1.49 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(8), and one O(9) atom. The C(13)-O(8) bond length is 1.31 Å. The C(13)-O(9) bond length is 1.25 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(4), and one O(5) atom. The C(14)-O(4) bond length is 1.32 Å. The C(14)-O(5) bond length is 1.25 Å. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(6), and one O(7) atom. The C(15)-O(6) bond length is 1.26 Å. The C(15)-O(7) bond length is 1.29 Å. As(1) is bonded in a tetrahedral geometry to one C(5), one O(10), one O(11), and one O(12) atom. The As(1)-O(10) bond length is 1.71 Å. The As(1)-O(11) bond length is 1.68 Å. The As(1)-O(12) bond length is 1.78 Å. N(1) is bonded in a trigonal planar geometry to one C(3), one O(1), and one O(2) atom. The N(1)-O(1) bond length is 1.27 Å. The N(1)-O(2) bond length is 1.24 Å. There are nine inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one O(3) atom. The H(7)-O(3) bond length is 1.00 Å. In the seventh H site, H(8) is bonded in a linear geometry to one O(4) and one O(5) atom. The H(8)-O(4) bond length is 1.04 Å. The H(8)-O(5) bond length is 1.52 Å. In the eighth H site, H(9) is bonded in a linear geometry to one O(7) and one O(8) atom. The H(9)-O(7) bond length is 1.43 Å. The H(9)-O(8) bond length is 1.06 Å. In the ninth H site, H(10) is bonded in a linear geometry to one O(12) and one O(9) atom. The H(10)-O(12) bond length is 1.02 Å. The H(10)-O(9) bond length is 1.60 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(2) and one H(7) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(14) and one H(8) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(14) and one H(8) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Pb(1) and one C(15) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one C(15) and one H(9) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one C(13) and one H(9) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one C(13) and one H(10) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to two equivalent Pb(1) and one As(1) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Pb(1) and one As(1) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one As(1) and one H(10) atom. Linkers: 2 O=[N+]([O-])c1c[c]ccc1O.[O][As]([O])O. Metal clusters: 2 [Pb]. The MOF has largest included sphere 2.01 A, density 2.55 g/cm3, surface area 2907.30 m2/g, accessible volume 0.07 cm3/g