ZnC15H7(NO)4(CH)3 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and one ZnC15H7(NO)4 cluster. In the ZnC15H7(NO)4 cluster, Zn(1) is bonded to one N(1), one N(3), one O(2), and two equivalent O(1) atoms to form distorted edge-sharing ZnN2O3 trigonal bipyramids. The Zn(1)-N(1) bond length is 2.06 Å. The Zn(1)-N(3) bond length is 2.11 Å. The Zn(1)-O(2) bond length is 1.97 Å. There is one shorter (1.98 Å) and one longer (2.47 Å) Zn(1)-O(1) bond length. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(3) atom. The C(1)-C(7) bond length is 1.41 Å. The C(1)-C(9) bond length is 1.45 Å. The C(1)-N(3) bond length is 1.35 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(16), one C(8), and one C(9) atom. The C(2)-C(16) bond length is 1.41 Å. The C(2)-C(8) bond length is 1.45 Å. The C(2)-C(9) bond length is 1.41 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(7), one C(8), and one N(4) atom. The C(3)-C(7) bond length is 1.46 Å. The C(3)-C(8) bond length is 1.42 Å. The C(3)-N(4) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(7) and one H(1) atom. The C(4)-C(7) bond length is 1.41 Å. The C(4)-H(1) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(6)-O(1) bond length is 1.32 Å. The C(6)-O(3) bond length is 1.25 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one N(2) atom. The C(8)-N(2) bond length is 1.35 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(1), one C(2), and one N(1) atom. The C(9)-N(1) bond length is 1.36 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one N(3), and one H(3) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-N(3) bond length is 1.33 Å. The C(10)-H(3) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(4) atom. The C(11)-H(4) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(12)-O(2) bond length is 1.31 Å. The C(12)-O(4) bond length is 1.25 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(14)-N(1) bond length is 1.34 Å. The C(14)-H(6) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(2) and one H(8) atom. The C(16)-H(8) bond length is 1.09 Å. In the fourteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(18), one N(4), and one H(9) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-N(4) bond length is 1.33 Å. The C(17)-H(9) bond length is 1.09 Å. In the fifteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one N(2), and one H(10) atom. The C(18)-N(2) bond length is 1.33 Å. The C(18)-H(10) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(14), and one C(9) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(18) and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(10) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(17) and one C(3) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Zn(1) and one C(6) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(12) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(12) atom. Linkers: 2 [O]C(=O)/C=C/C([O])=O. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 1.97 A, density 1.80 g/cm3, surface area 3884.25 m2/g, accessible volume 0.09 cm3/g