SrCuC14H6(NO4)2 crystallizes in the monoclinic C2/c space group. Sr(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(4) atoms. Both Sr(1)-O(2) bond lengths are 2.66 Å. Both Sr(1)-O(3) bond lengths are 2.61 Å. There are two shorter (2.54 Å) and two longer (2.74 Å) Sr(1)-O(4) bond lengths. Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 1.96 Å. Both Cu(1)-O(1) bond lengths are 1.95 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(7) atom. The C(1)-C(3) bond length is 1.40 Å. The C(1)-C(4) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.51 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(4), one C(5), and one N(1) atom. The C(2)-C(4) bond length is 1.38 Å. The C(2)-C(5) bond length is 1.50 Å. The C(2)-N(1) bond length is 1.35 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(6), and one H(1) atom. The C(3)-C(6) bond length is 1.40 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(1), one C(2), and one H(2) atom. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(3) atom. The C(5)-O(1) bond length is 1.29 Å. The C(5)-O(3) bond length is 1.25 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(3) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(2), and one O(4) atom. The C(7)-O(2) bond length is 1.27 Å. The C(7)-O(4) bond length is 1.27 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(2), and one C(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(5) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Sr(1) and one C(7) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Sr(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one C(7) atom. Linkers: 4 [O]C(=O)c1ccnc(C([O])=O)c1. Metal clusters: 2 [Sr] ,2 [Cu]. The MOF has largest included sphere 1.52 A, density 2.24 g/cm3, surface area 2963.70 m2/g, accessible volume 0.09 cm3/g