CoC28N8H30(O5F4)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoC28N8H30(O5F4)2 cluster. Co(1) is bonded to two equivalent N(1), two equivalent O(1), and two equivalent O(3) atoms to form distorted CoN2O4 octahedra that share corners with two equivalent C(5)H2N2 tetrahedra, corners with two equivalent C(6)H2N2 tetrahedra, and corners with two equivalent C(7)H2N2 tetrahedra. Both Co(1)-N(1) bond lengths are 2.06 Å. Both Co(1)-O(1) bond lengths are 1.94 Å. Both Co(1)-O(3) bond lengths are 2.54 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(4) bond length is 1.40 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(2) and one F(1) atom. The C(3)-F(1) bond length is 1.36 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one F(2) atom. The C(4)-F(2) bond length is 1.36 Å. In the fifth C site, C(5) is bonded to one N(1), one N(3), one H(3), and one H(4) atom to form CH2N2 tetrahedra that share  a cornercorner with one Co(1)N2O4 octahedra,  a cornercorner with one C(6)H2N2 tetrahedra,  a cornercorner with one C(7)H2N2 tetrahedra,  a cornercorner with one C(8)H2N2 tetrahedra, and  a cornercorner with one C(9)H2N2 tetrahedra. The corner-sharing octahedral tilt angles are 74°. The C(5)-N(1) bond length is 1.51 Å. The C(5)-N(3) bond length is 1.45 Å. The C(5)-H(3) bond length is 1.10 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded to one N(1), one N(4), one H(5), and one H(6) atom to form CH2N2 tetrahedra that share  a cornercorner with one Co(1)N2O4 octahedra,  a cornercorner with one C(10)H2N2 tetrahedra,  a cornercorner with one C(5)H2N2 tetrahedra,  a cornercorner with one C(7)H2N2 tetrahedra, and  a cornercorner with one C(9)H2N2 tetrahedra. The corner-sharing octahedral tilt angles are 67°. The C(6)-N(1) bond length is 1.49 Å. The C(6)-N(4) bond length is 1.50 Å. The C(6)-H(5) bond length is 1.09 Å. The C(6)-H(6) bond length is 1.09 Å. In the seventh C site, C(7) is bonded to one N(1), one N(2), one H(7), and one H(8) atom to form CH2N2 tetrahedra that share  a cornercorner with one Co(1)N2O4 octahedra,  a cornercorner with one C(10)H2N2 tetrahedra,  a cornercorner with one C(5)H2N2 tetrahedra,  a cornercorner with one C(6)H2N2 tetrahedra, and  a cornercorner with one C(8)H2N2 tetrahedra. The corner-sharing octahedral tilt angles are 64°. The C(7)-N(1) bond length is 1.52 Å. The C(7)-N(2) bond length is 1.45 Å. The C(7)-H(7) bond length is 1.09 Å. The C(7)-H(8) bond length is 1.10 Å. In the eighth C site, C(8) is bonded to one N(2), one N(3), one H(10), and one H(9) atom to form corner-sharing CH2N2 tetrahedra. The C(8)-N(2) bond length is 1.47 Å. The C(8)-N(3) bond length is 1.47 Å. The C(8)-H(10) bond length is 1.09 Å. The C(8)-H(9) bond length is 1.10 Å. In the ninth C site, C(9) is bonded to one N(3), one N(4), one H(11), and one H(12) atom to form corner-sharing CH2N2 tetrahedra. The C(9)-N(3) bond length is 1.44 Å. The C(9)-N(4) bond length is 1.51 Å. The C(9)-H(11) bond length is 1.09 Å. The C(9)-H(12) bond length is 1.10 Å. In the tenth C site, C(10) is bonded to one N(2), one N(4), one H(13), and one H(14) atom to form corner-sharing CH2N2 tetrahedra. The C(10)-N(2) bond length is 1.45 Å. The C(10)-N(4) bond length is 1.51 Å. The C(10)-H(13) bond length is 1.10 Å. The C(10)-H(14) bond length is 1.10 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(4), and one O(5) atom. The C(11)-C(12) bond length is 1.51 Å. The C(11)-O(4) bond length is 1.29 Å. The C(11)-O(5) bond length is 1.25 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-C(14) bond length is 1.40 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one F(3) atom. The C(13)-F(3) bond length is 1.36 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one F(4) atom. The C(14)-F(4) bond length is 1.36 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Co(1), one C(5), one C(6), and one C(7) atom to form NCoC3 tetrahedra that share  a cornercorner with one N(1)CoC3 tetrahedra and  a cornercorner with one N(4)HC3 tetrahedra. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one C(10), one C(7), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal non-coplanar geometry to one C(5), one C(8), and one C(9) atom. In the fourth N site, N(4) is bonded to one C(10), one C(6), one C(9), and one H(15) atom to form corner-sharing NHC3 tetrahedra. The N(4)-H(15) bond length is 1.13 Å. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. The H(1)-O(3) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. The H(2)-O(3) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the fifteenth H site, H(15) is bonded in a linear geometry to one N(4) and one O(4) atom. The H(15)-O(4) bond length is 1.41 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Co(1), one H(1), and one H(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(11) and one H(15) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(11) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(4) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(13) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(14) atom. Linkers: 1 [O]C(=O)c1c(F)c(F)c(C([O])=O)c(F)c1F. Metal clusters: 1 [Co]. The MOF has largest included sphere 3.83 A, density 1.72 g/cm3, surface area 3549.81 m2/g, accessible volume 0.12 cm3/g