(CH)2CdC18N3H11SO4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one CdC18N3H11SO4 cluster. In the CdC18N3H11SO4 cluster, Cd(1) is bonded in a 7-coordinate geometry to one N(1), one N(2), one O(1), one O(3), one O(4), and two equivalent O(2) atoms. The Cd(1)-N(1) bond length is 2.37 Å. The Cd(1)-N(2) bond length is 2.38 Å. The Cd(1)-O(1) bond length is 2.33 Å. The Cd(1)-O(3) bond length is 2.27 Å. The Cd(1)-O(4) bond length is 2.74 Å. There is one shorter (2.39 Å) and one longer (2.68 Å) Cd(1)-O(2) bond length. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(12), one C(5), and one N(2) atom. The C(1)-C(12) bond length is 1.44 Å. The C(1)-C(5) bond length is 1.42 Å. The C(1)-N(2) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(2) and one H(1) atom. The C(2)-N(2) bond length is 1.33 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(3) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.43 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(4) atom. The C(6)-C(7) bond length is 1.37 Å. The C(6)-H(4) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.43 Å. The C(7)-H(5) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.42 Å. The C(8)-C(9) bond length is 1.41 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(9)-H(6) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-H(7) bond length is 1.09 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(8) atom. The C(11)-N(1) bond length is 1.33 Å. The C(11)-H(8) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(1), one C(8), and one N(1) atom. The C(12)-N(1) bond length is 1.36 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(3), and one O(4) atom. The C(13)-C(14) bond length is 1.50 Å. The C(13)-O(3) bond length is 1.29 Å. The C(13)-O(4) bond length is 1.26 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(18) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(18) bond length is 1.42 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(9) atom. The C(15)-H(9) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(11) atom. The C(17)-N(3) bond length is 1.34 Å. The C(17)-H(11) bond length is 1.09 Å. In the sixteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one S(1) atom. The C(18)-N(3) bond length is 1.35 Å. The C(18)-S(1) bond length is 1.76 Å. In the seventeenth C site, C(19) is bonded in a distorted water-like geometry to one H(12), one H(13), and one S(1) atom. The C(19)-H(12) bond length is 1.10 Å. The C(19)-H(13) bond length is 1.10 Å. The C(19)-S(1) bond length is 1.80 Å. In the eighteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(20)-O(1) bond length is 1.27 Å. The C(20)-O(2) bond length is 1.28 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one C(12) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(17) and one C(18) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(19) atom. S(1) is bonded in a water-like geometry to one C(18) and one C(19) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1) and one C(20) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(20) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cd(1) and one C(13) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cd(1) and one C(13) atom. Linkers: 2 [O]C(=O)CSc1ncccc1C([O])=O. Metal clusters: 1 O=[C]O[Cd]1O[C]O[Cd](O[C]=O)O[C]O1. The MOF has largest included sphere 2.02 A, density 1.91 g/cm3, surface area 3642.74 m2/g, accessible volume 0.07 cm3/g