Ni2C24N4H18O9(C3H2)4(CH)8(C2O)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules; eight 2,3-dimethyl-1,3-butadiene molecules; eight dimethyl ether molecules; and four Ni2C24N4H18O9 clusters. In each Ni2C24N4H18O9 cluster, Ni(1) is bonded to one N(1), one N(2), one O(1), one O(4), one O(5), and one O(6) atom to form corner-sharing NiN2O4 octahedra. The corner-sharing octahedral tilt angles are 72°. The Ni(1)-N(1) bond length is 2.10 Å. The Ni(1)-N(2) bond length is 2.09 Å. The Ni(1)-O(1) bond length is 2.07 Å. The Ni(1)-O(4) bond length is 2.14 Å. The Ni(1)-O(5) bond length is 2.20 Å. The Ni(1)-O(6) bond length is 2.15 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1) and one H(2,5) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(2,5) bond length is 1.09 Å. In the second C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and one H(2,5) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(2,5) bond length is 1.09 Å. In the third C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(7) bond length is 1.09 Å. In the fourth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(9)-N(2) bond length is 1.35 Å. The C(9)-H(8) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-O(1) bond length is 1.29 Å. The C(11)-O(2) bond length is 1.27 Å. In the sixth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(17) bond length is 1.40 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(13)-H(10) bond length is 1.09 Å. In the eighth C site, C(17) is bonded in a distorted single-bond geometry to one C(12) and one H(13) atom. The C(17)-H(13) bond length is 1.09 Å. In the ninth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(15) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(15) bond length is 1.09 Å. In the tenth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(24) bond length is 1.50 Å. In the eleventh C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(16) atom. The C(22)-H(16) bond length is 1.09 Å. In the twelfth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(4), and one O(5) atom. The C(24)-O(4) bond length is 1.28 Å. The C(24)-O(5) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ni(1), one C(8), and one C(9) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one O(6) atom. The H(1)-O(2) bond length is 1.59 Å. The H(1)-O(6) bond length is 1.03 Å. In the second H site, H(2,5) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(11) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one C(11) and one H(1) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(24) atom. In the fourth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(24) atom. In the fifth O site, O(6) is bonded in a distorted bent 120 degrees geometry to two equivalent Ni(1) and two equivalent H(1) atoms. Linkers: 4 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,4 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 O.O=[C]O[Ni]1O[C]O[Ni](O[C]=O)O[C]O1. RCSR code: sql. The MOF has largest included sphere 4.85 A, density 1.36 g/cm3, surface area 4253.89 m2/g, accessible volume 0.24 cm3/g