(CH2)3Zn2C31N6H21(O4F3)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of twelve 02329_fluka molecules inside a Zn2C31N6H21(O4F3)2 framework. In the Zn2C31N6H21(O4F3)2 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one N(1), one O(2), one O(3), and one O(8) atom. The Zn(1)-N(1) bond length is 1.99 Å. The Zn(1)-O(2) bond length is 2.03 Å. The Zn(1)-O(3) bond length is 1.99 Å. The Zn(1)-O(8) bond length is 1.99 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one N(4), one N(5), one O(1), and one O(5) atom. The Zn(2)-N(4) bond length is 1.99 Å. The Zn(2)-N(5) bond length is 2.00 Å. The Zn(2)-O(1) bond length is 2.02 Å. The Zn(2)-O(5) bond length is 1.98 Å. There are thirty-one inequivalent C sites. In the first C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(4), and one H(5) atom. The C(4)-N(2) bond length is 1.46 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. In the second C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(3) and two equivalent H(10,11) atoms. The C(7)-N(3) bond length is 1.46 Å. Both C(7)-H(10,11) bond lengths are 1.10 Å. In the third C site, C(8) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(12) atom. The C(8)-N(3) bond length is 1.35 Å. The C(8)-N(4) bond length is 1.34 Å. The C(8)-H(12) bond length is 1.09 Å. In the fourth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(4), and one H(13) atom. The C(9)-C(10) bond length is 1.37 Å. The C(9)-N(4) bond length is 1.38 Å. The C(9)-H(13) bond length is 1.08 Å. In the fifth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(3), and one H(14) atom. The C(10)-N(3) bond length is 1.38 Å. The C(10)-H(14) bond length is 1.08 Å. In the sixth C site, C(11) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(15) atom. The C(11)-N(5) bond length is 1.34 Å. The C(11)-N(6) bond length is 1.35 Å. The C(11)-H(15) bond length is 1.09 Å. In the seventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(5), and one H(16) atom. The C(12)-C(13) bond length is 1.37 Å. The C(12)-N(5) bond length is 1.38 Å. The C(12)-H(16) bond length is 1.08 Å. In the eighth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(6), and one H(17) atom. The C(13)-N(6) bond length is 1.38 Å. The C(13)-H(17) bond length is 1.08 Å. In the ninth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(18), and one H(19) atom. The C(14)-N(6) bond length is 1.47 Å. The C(14)-H(18) bond length is 1.10 Å. The C(14)-H(19) bond length is 1.10 Å. In the tenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(1), and one O(2) atom. The C(16)-C(17) bond length is 1.50 Å. The C(16)-O(1) bond length is 1.27 Å. The C(16)-O(2) bond length is 1.27 Å. In the eleventh C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(22) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(22) bond length is 1.40 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(22) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(22) bond length is 1.09 Å. In the thirteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(23) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(23) bond length is 1.09 Å. In the fourteenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(24) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(24) bond length is 1.54 Å. In the fifteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one H(24) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(24) bond length is 1.09 Å. In the sixteenth C site, C(22) is bonded in a trigonal planar geometry to one C(17), one C(21), and one C(23) atom. The C(22)-C(23) bond length is 1.51 Å. In the seventeenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(3), and one O(4) atom. The C(23)-O(3) bond length is 1.30 Å. The C(23)-O(4) bond length is 1.25 Å. In the eighteenth C site, C(24) is bonded in a tetrahedral geometry to one C(20), one C(25), one C(26), and one C(27) atom. The C(24)-C(25) bond length is 1.56 Å. The C(24)-C(26) bond length is 1.56 Å. The C(24)-C(27) bond length is 1.54 Å. In the nineteenth C site, C(25) is bonded in a trigonal non-coplanar geometry to one C(24), one F(1), one F(2), and one F(3) atom. The C(25)-F(1) bond length is 1.36 Å. The C(25)-F(2) bond length is 1.37 Å. The C(25)-F(3) bond length is 1.36 Å. In the twentieth C site, C(26) is bonded in a trigonal non-coplanar geometry to one C(24), one F(4), one F(5), and one F(6) atom. The C(26)-F(4) bond length is 1.36 Å. The C(26)-F(5) bond length is 1.37 Å. The C(26)-F(6) bond length is 1.36 Å. In the twenty-first C site, C(27) is bonded in a trigonal planar geometry to one C(24), one C(28), and one C(34) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-C(34) bond length is 1.40 Å. In the twenty-second C site, C(28) is bonded in a distorted single-bond geometry to one C(27) and one H(25) atom. The C(28)-H(25) bond length is 1.09 Å. In the twenty-third C site, C(34) is bonded in a distorted single-bond geometry to one C(27), one C(32), and one H(27) atom. The C(34)-C(32) bond length is 1.40 Å. The C(34)-H(27) bond length is 1.09 Å. In the twenty-fourth C site, C(29) is bonded in a distorted single-bond geometry to one C(30) and one H(26) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-H(26) bond length is 1.09 Å. In the twenty-fifth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(32) atom. The C(30)-C(31) bond length is 1.50 Å. The C(30)-C(32) bond length is 1.41 Å. In the twenty-sixth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(5), and one O(6) atom. The C(31)-O(5) bond length is 1.31 Å. The C(31)-O(6) bond length is 1.25 Å. In the twenty-seventh C site, C(32) is bonded in a trigonal planar geometry to one C(30), one C(33), and one C(34) atom. The C(32)-C(33) bond length is 1.51 Å. In the twenty-eighth C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.09 Å. In the twenty-ninth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(7), and one O(8) atom. The C(33)-O(7) bond length is 1.24 Å. The C(33)-O(8) bond length is 1.30 Å. In the thirtieth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(1) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the thirty-first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.38 Å. The C(3)-H(3) bond length is 1.08 Å. There are six inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(8) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one Zn(2), one C(8), and one C(9) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one Zn(2), one C(11), and one C(12) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. In the sixth N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(10,11) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(14) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(23) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(24) is bonded in a single-bond geometry to one C(21) atom. In the eighteenth H site, H(25) is bonded in a single-bond geometry to one C(28) atom. In the nineteenth H site, H(26) is bonded in a single-bond geometry to one C(29) atom. In the twentieth H site, H(27) is bonded in a single-bond geometry to one C(34) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(16) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(16) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(23) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(23) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Zn(2) and one C(31) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(31) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(33) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(33) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(25) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(25) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(25) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(26) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(26) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one C(26) atom. Linkers: 4 c1cn(CCCCn2ccnc2)cn1 ,4 [O]C(=O)c1ccc(C(c2ccc(C([O])=O)c(C([O])=O)c2)(C(F)(F)F)C(F)(F)F)cc1C([O])=O. Metal clusters: 8 [Zn]. The MOF has largest included sphere 4.34 A, density 1.49 g/cm3, surface area 4417.36 m2/g, accessible volume 0.26 cm3/g