Cu(H2NC6H4COO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, one CuC10H8(NO2)2 cluster, and one CuC12H10(NO2)2 cluster. In the CuC10H8(NO2)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(6) atoms. Both Cu(1)-N(1) bond lengths are 2.04 Å. Both Cu(1)-O(6) bond lengths are 1.95 Å. There are five inequivalent C sites. In the first C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(6)-O(5) bond length is 1.25 Å. The C(6)-O(6) bond length is 1.30 Å. In the second C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(1), and one H(4) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-N(1) bond length is 1.35 Å. The C(7)-H(4) bond length is 1.09 Å. In the third C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the fourth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(7) bond length is 1.09 Å. In the fifth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(8) atom. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(8) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(7) atom. There are four inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent O sites. In the first O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(6) atom. In the second O site, O(5) is bonded in a single-bond geometry to one C(6) atom. In the CuC12H10(NO2)2 cluster, Cu(2) is bonded in a 5-coordinate geometry to one N(2), one N(3), one O(4), and two equivalent O(2) atoms. The Cu(2)-N(2) bond length is 2.01 Å. The Cu(2)-N(3) bond length is 2.03 Å. The Cu(2)-O(4) bond length is 2.02 Å. There is one shorter (2.00 Å) and one longer (2.47 Å) Cu(2)-O(2) bond length. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.31 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(2)-C(3) bond length is 1.35 Å. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(5) atom. The C(3)-C(4) bond length is 1.50 Å. The C(3)-C(5) bond length is 1.49 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(4) atom. The C(4)-O(3) bond length is 1.25 Å. The C(4)-O(4) bond length is 1.30 Å. In the fifth C site, C(5) is bonded in a distorted water-like geometry to one C(3), one H(2), and one H(3) atom. The C(5)-H(2) bond length is 1.10 Å. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(12) is bonded in a distorted trigonal planar geometry to one N(2) and one H(9) atom. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(9) bond length is 1.09 Å. In the seventh C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(12) bond length is 1.09 Å. In the eighth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one N(2), and one H(13) atom. The C(16)-N(2) bond length is 1.35 Å. The C(16)-H(13) bond length is 1.09 Å. In the ninth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(18), one N(3), and one H(14) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-N(3) bond length is 1.35 Å. The C(17)-H(14) bond length is 1.09 Å. In the tenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(15) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(15) bond length is 1.09 Å. In the eleventh C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(16) atom. The C(19)-H(16) bond length is 1.09 Å. In the twelfth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(18) atom. The C(21)-N(3) bond length is 1.35 Å. The C(21)-H(18) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(12), and one C(16) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cu(2), one C(17), and one C(21) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(21) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Cu(2) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cu(2) and one C(4) atom. Linkers: 2 [O]C(=O)/C=C(\CC([O])=O)C([O])=O. Metal clusters: 3 [Cu]. The MOF has largest included sphere 4.51 A, density 1.44 g/cm3, surface area 4497.57 m2/g, accessible volume 0.25 cm3/g