SmV2C44N4H24S4O13 crystallizes in the triclinic P1 space group. There are two inequivalent Sm sites. In the first Sm site, Sm(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. The Sm(1)-O(1) bond length is 2.36 Å. The Sm(1)-O(2) bond length is 2.39 Å. The Sm(1)-O(3) bond length is 2.44 Å. The Sm(1)-O(4) bond length is 2.45 Å. The Sm(1)-O(5) bond length is 2.44 Å. The Sm(1)-O(6) bond length is 2.45 Å. The Sm(1)-O(7) bond length is 2.36 Å. The Sm(1)-O(8) bond length is 2.38 Å. In the second Sm site, Sm(2) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(12), one O(13), one O(14), one O(15), one O(16), and one O(9) atom. The Sm(2)-O(10) bond length is 2.44 Å. The Sm(2)-O(11) bond length is 2.38 Å. The Sm(2)-O(12) bond length is 2.36 Å. The Sm(2)-O(13) bond length is 2.39 Å. The Sm(2)-O(14) bond length is 2.36 Å. The Sm(2)-O(15) bond length is 2.45 Å. The Sm(2)-O(16) bond length is 2.44 Å. The Sm(2)-O(9) bond length is 2.45 Å. There are four inequivalent V sites. In the first V site, V(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(2), one N(3), one N(4), and one O(25) atom. The V(1)-N(1) bond length is 2.01 Å. The V(1)-N(2) bond length is 2.10 Å. The V(1)-N(3) bond length is 2.02 Å. The V(1)-N(4) bond length is 2.11 Å. The V(1)-O(25) bond length is 1.89 Å. In the second V site, V(2) is bonded in a 3-coordinate geometry to one C(54), one N(6), one N(8), and one O(25) atom. The V(2)-C(54) bond length is 2.38 Å. The V(2)-N(6) bond length is 2.09 Å. The V(2)-N(8) bond length is 2.02 Å. The V(2)-O(25) bond length is 1.70 Å. In the third V site, V(3) is bonded in a 3-coordinate geometry to one C(50), one N(2), one N(4), and one O(26) atom. The V(3)-C(50) bond length is 2.37 Å. The V(3)-N(2) bond length is 2.09 Å. The V(3)-N(4) bond length is 2.02 Å. The V(3)-O(26) bond length is 1.70 Å. In the fourth V site, V(4) is bonded in a distorted trigonal bipyramidal geometry to one N(5), one N(6), one N(7), one N(8), and one O(26) atom. The V(4)-N(5) bond length is 2.01 Å. The V(4)-N(6) bond length is 2.10 Å. The V(4)-N(7) bond length is 2.02 Å. The V(4)-N(8) bond length is 2.11 Å. The V(4)-O(26) bond length is 1.89 Å. There are eighty-four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(18), one C(9), and one S(1) atom. The C(1)-C(18) bond length is 1.40 Å. The C(1)-C(9) bond length is 1.40 Å. The C(1)-S(1) bond length is 1.78 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(10), one C(17), and one S(2) atom. The C(2)-C(10) bond length is 1.40 Å. The C(2)-C(17) bond length is 1.40 Å. The C(2)-S(2) bond length is 1.79 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(11), one C(20), and one S(3) atom. The C(3)-C(11) bond length is 1.40 Å. The C(3)-C(20) bond length is 1.40 Å. The C(3)-S(3) bond length is 1.78 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(19), and one S(4) atom. The C(4)-C(12) bond length is 1.40 Å. The C(4)-C(19) bond length is 1.40 Å. The C(4)-S(4) bond length is 1.78 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(13), one C(22), and one S(5) atom. The C(5)-C(13) bond length is 1.40 Å. The C(5)-C(22) bond length is 1.40 Å. The C(5)-S(5) bond length is 1.78 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(14), one C(21), and one S(6) atom. The C(6)-C(14) bond length is 1.40 Å. The C(6)-C(21) bond length is 1.40 Å. The C(6)-S(6) bond length is 1.79 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(15), one C(24), and one S(7) atom. The C(7)-C(15) bond length is 1.40 Å. The C(7)-C(24) bond length is 1.40 Å. The C(7)-S(7) bond length is 1.78 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(16), one C(23), and one S(8) atom. The C(8)-C(16) bond length is 1.40 Å. The C(8)-C(23) bond length is 1.40 Å. The C(8)-S(8) bond length is 1.78 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(1), one C(25), and one H(1) atom. The C(9)-C(25) bond length is 1.39 Å. The C(9)-H(1) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(2), one C(26), and one H(2) atom. The C(10)-C(26) bond length is 1.40 Å. The C(10)-H(2) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(27), one C(3), and one H(3) atom. The C(11)-C(27) bond length is 1.39 Å. The C(11)-H(3) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(28), one C(4), and one H(4) atom. The C(12)-C(28) bond length is 1.39 Å. The C(12)-H(4) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(29), one C(5), and one H(5) atom. The C(13)-C(29) bond length is 1.39 Å. The C(13)-H(5) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(30), one C(6), and one H(6) atom. The C(14)-C(30) bond length is 1.39 Å. The C(14)-H(6) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(31), one C(7), and one H(7) atom. The C(15)-C(31) bond length is 1.39 Å. The C(15)-H(7) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(32), one C(8), and one H(8) atom. The C(16)-C(32) bond length is 1.39 Å. The C(16)-H(8) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(2), one C(33), and one H(9) atom. The C(17)-C(33) bond length is 1.39 Å. The C(17)-H(9) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(1), one C(34), and one H(10) atom. The C(18)-C(34) bond length is 1.39 Å. The C(18)-H(10) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(35), one C(4), and one H(11) atom. The C(19)-C(35) bond length is 1.39 Å. The C(19)-H(11) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(3), one C(36), and one H(12) atom. The C(20)-C(36) bond length is 1.39 Å. The C(20)-H(12) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(37), one C(6), and one H(13) atom. The C(21)-C(37) bond length is 1.40 Å. The C(21)-H(13) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(38), one C(5), and one H(14) atom. The C(22)-C(38) bond length is 1.39 Å. The C(22)-H(14) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted trigonal planar geometry to one C(39), one C(8), and one H(15) atom. The C(23)-C(39) bond length is 1.39 Å. The C(23)-H(15) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(40), one C(7), and one H(16) atom. The C(24)-C(40) bond length is 1.39 Å. The C(24)-H(16) bond length is 1.09 Å. In the twenty-fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(41), one C(9), and one H(17) atom. The C(25)-C(41) bond length is 1.40 Å. The C(25)-H(17) bond length is 1.09 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(10), one C(42), and one H(18) atom. The C(26)-C(42) bond length is 1.40 Å. The C(26)-H(18) bond length is 1.09 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(11), one C(43), and one H(19) atom. The C(27)-C(43) bond length is 1.40 Å. The C(27)-H(19) bond length is 1.09 Å. In the twenty-eighth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(12); one C(44); and one H(20,31) atom. The C(28)-C(44) bond length is 1.40 Å. The C(28)-H(20,31) bond length is 1.09 Å. In the twenty-ninth C site, C(29) is bonded in a distorted single-bond geometry to one C(13), one C(45), and one H(21) atom. The C(29)-C(45) bond length is 1.40 Å. The C(29)-H(21) bond length is 1.09 Å. In the thirtieth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(14), one C(46), and one H(22) atom. The C(30)-C(46) bond length is 1.40 Å. The C(30)-H(22) bond length is 1.09 Å. In the thirty-first C site, C(31) is bonded in a distorted trigonal planar geometry to one C(15), one C(47), and one H(23) atom. The C(31)-C(47) bond length is 1.40 Å. The C(31)-H(23) bond length is 1.09 Å. In the thirty-second C site, C(32) is bonded in a distorted single-bond geometry to one C(16), one C(48), and one H(24) atom. The C(32)-C(48) bond length is 1.40 Å. The C(32)-H(24) bond length is 1.09 Å. In the thirty-third C site, C(33) is bonded in a distorted trigonal planar geometry to one C(17), one C(42), and one H(25) atom. The C(33)-C(42) bond length is 1.40 Å. The C(33)-H(25) bond length is 1.09 Å. In the thirty-fourth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(18), one C(41), and one H(26) atom. The C(34)-C(41) bond length is 1.40 Å. The C(34)-H(26) bond length is 1.09 Å. In the thirty-fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(19), one C(44), and one H(27) atom. The C(35)-C(44) bond length is 1.40 Å. The C(35)-H(27) bond length is 1.09 Å. In the thirty-sixth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(20), one C(43), and one H(28) atom. The C(36)-C(43) bond length is 1.40 Å. The C(36)-H(28) bond length is 1.09 Å. In the thirty-seventh C site, C(37) is bonded in a distorted single-bond geometry to one C(21), one C(46), and one H(29) atom. The C(37)-C(46) bond length is 1.40 Å. The C(37)-H(29) bond length is 1.09 Å. In the thirty-eighth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(22), one C(45), and one H(30) atom. The C(38)-C(45) bond length is 1.40 Å. The C(38)-H(30) bond length is 1.09 Å. In the thirty-ninth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(23); one C(48); and one H(20,31) atom. The C(39)-C(48) bond length is 1.40 Å. The C(39)-H(20,31) bond length is 1.09 Å. In the fortieth C site, C(40) is bonded in a distorted single-bond geometry to one C(24), one C(47), and one H(32) atom. The C(40)-C(47) bond length is 1.40 Å. The C(40)-H(32) bond length is 1.09 Å. In the forty-first C site, C(41) is bonded in a trigonal planar geometry to one C(25), one C(34), and one C(49) atom. The C(41)-C(49) bond length is 1.49 Å. In the forty-second C site, C(42) is bonded in a trigonal planar geometry to one C(26), one C(33), and one C(50) atom. The C(42)-C(50) bond length is 1.50 Å. In the forty-third C site, C(43) is bonded in a trigonal planar geometry to one C(27), one C(36), and one C(51) atom. The C(43)-C(51) bond length is 1.50 Å. In the forty-fourth C site, C(44) is bonded in a trigonal planar geometry to one C(28), one C(35), and one C(52) atom. The C(44)-C(52) bond length is 1.49 Å. In the forty-fifth C site, C(45) is bonded in a trigonal planar geometry to one C(29), one C(38), and one C(53) atom. The C(45)-C(53) bond length is 1.49 Å. In the forty-sixth C site, C(46) is bonded in a trigonal planar geometry to one C(30), one C(37), and one C(54) atom. The C(46)-C(54) bond length is 1.50 Å. In the forty-seventh C site, C(47) is bonded in a trigonal planar geometry to one C(31), one C(40), and one C(55) atom. The C(47)-C(55) bond length is 1.50 Å. In the forty-eighth C site, C(48) is bonded in a trigonal planar geometry to one C(32), one C(39), and one C(56) atom. The C(48)-C(56) bond length is 1.49 Å. In the forty-ninth C site, C(49) is bonded in a trigonal planar geometry to one C(41), one C(57), and one C(81) atom. The C(49)-C(57) bond length is 1.40 Å. The C(49)-C(81) bond length is 1.40 Å. In the fiftieth C site, C(50) is bonded in a 4-coordinate geometry to one V(3), one C(42), one C(58), and one C(82) atom. The C(50)-C(58) bond length is 1.42 Å. The C(50)-C(82) bond length is 1.42 Å. In the fifty-first C site, C(51) is bonded in a trigonal planar geometry to one C(43), one C(59), and one C(83) atom. The C(51)-C(59) bond length is 1.42 Å. The C(51)-C(83) bond length is 1.38 Å. In the fifty-second C site, C(52) is bonded in a trigonal planar geometry to one C(44), one C(60), and one C(84) atom. The C(52)-C(60) bond length is 1.39 Å. The C(52)-C(84) bond length is 1.42 Å. In the fifty-third C site, C(53) is bonded in a trigonal planar geometry to one C(45), one C(61), and one C(85) atom. The C(53)-C(61) bond length is 1.40 Å. The C(53)-C(85) bond length is 1.40 Å. In the fifty-fourth C site, C(54) is bonded in a 4-coordinate geometry to one V(2), one C(46), one C(62), and one C(86) atom. The C(54)-C(62) bond length is 1.42 Å. The C(54)-C(86) bond length is 1.42 Å. In the fifty-fifth C site, C(55) is bonded in a trigonal planar geometry to one C(47), one C(63), and one C(87) atom. The C(55)-C(63) bond length is 1.42 Å. The C(55)-C(87) bond length is 1.38 Å. In the fifty-sixth C site, C(56) is bonded in a trigonal planar geometry to one C(48), one C(64), and one C(88) atom. The C(56)-C(64) bond length is 1.39 Å. The C(56)-C(88) bond length is 1.42 Å. In the fifty-seventh C site, C(57) is bonded in a distorted trigonal planar geometry to one C(49), one C(65), and one N(1) atom. The C(57)-C(65) bond length is 1.43 Å. The C(57)-N(1) bond length is 1.39 Å. In the fifty-eighth C site, C(58) is bonded in a 1-coordinate geometry to one C(50) and one N(2) atom. The C(58)-N(2) bond length is 1.42 Å. In the fifty-ninth C site, C(59) is bonded in a distorted trigonal planar geometry to one C(51); one C(67,71); and one N(3) atom. The C(59)-C(67,71) bond length is 1.43 Å. The C(59)-N(3) bond length is 1.39 Å. In the sixtieth C site, C(60) is bonded in a distorted trigonal planar geometry to one C(52), one C(68), and one N(4) atom. The C(60)-C(68) bond length is 1.44 Å. The C(60)-N(4) bond length is 1.41 Å. In the sixty-first C site, C(61) is bonded in a distorted trigonal planar geometry to one C(53), one C(69), and one N(5) atom. The C(61)-C(69) bond length is 1.43 Å. The C(61)-N(5) bond length is 1.39 Å. In the sixty-second C site, C(62) is bonded in a 1-coordinate geometry to one C(54) and one N(6) atom. The C(62)-N(6) bond length is 1.42 Å. In the sixty-third C site, C(63) is bonded in a distorted trigonal planar geometry to one C(55); one C(67,71); and one N(7) atom. The C(63)-C(67,71) bond length is 1.43 Å. The C(63)-N(7) bond length is 1.39 Å. In the sixty-fourth C site, C(64) is bonded in a distorted trigonal planar geometry to one C(56), one C(72), and one N(8) atom. The C(64)-C(72) bond length is 1.44 Å. The C(64)-N(8) bond length is 1.41 Å. In the sixty-fifth C site, C(65) is bonded in a distorted single-bond geometry to one C(57); one C(73); and one H(33,37) atom. The C(65)-C(73) bond length is 1.38 Å. The C(65)-H(33,37) bond length is 1.09 Å. In the sixty-sixth C site, C(66) is bonded in a distorted single-bond geometry to one C(74,78) and one H(34,38) atom. The C(66)-C(74,78) bond length is 1.36 Å. The C(66)-H(34,38) bond length is 1.09 Å. In the sixty-seventh C site, C(67,71) is bonded in a distorted single-bond geometry to one C(59); one C(75,79); and one H(35,39) atom. The C(67,71)-C(75,79) bond length is 1.37 Å. The C(67,71)-H(35,39) bond length is 1.09 Å. In the sixty-eighth C site, C(68) is bonded in a distorted single-bond geometry to one C(60); one C(76,80); and one H(36,40) atom. The C(68)-C(76,80) bond length is 1.37 Å. The C(68)-H(36,40) bond length is 1.09 Å. In the sixty-ninth C site, C(69) is bonded in a distorted single-bond geometry to one C(61); one C(77); and one H(33,37) atom. The C(69)-C(77) bond length is 1.38 Å. The C(69)-H(33,37) bond length is 1.09 Å. In the seventieth C site, C(70) is bonded in a distorted single-bond geometry to one C(74,78) and one H(34,38) atom. The C(70)-C(74,78) bond length is 1.36 Å. The C(70)-H(34,38) bond length is 1.09 Å. In the seventy-first C site, C(72) is bonded in a distorted single-bond geometry to one C(64); one C(76,80); and one H(36,40) atom. The C(72)-C(76,80) bond length is 1.37 Å. The C(72)-H(36,40) bond length is 1.09 Å. In the seventy-second C site, C(73) is bonded in a distorted single-bond geometry to one C(65), one C(84), and one H(41) atom. The C(73)-C(84) bond length is 1.43 Å. The C(73)-H(41) bond length is 1.08 Å. In the seventy-third C site, C(74,78) is bonded in a distorted single-bond geometry to one C(66), one C(83), and one H(42) atom. The C(74,78)-C(83) bond length is 1.44 Å. The C(74,78)-H(42) bond length is 1.09 Å. In the seventy-fourth C site, C(75,79) is bonded in a distorted single-bond geometry to one C(67,71); one C(81); and one H(43,47) atom. The C(75,79)-C(81) bond length is 1.43 Å. The C(75,79)-H(43,47) bond length is 1.09 Å. In the seventy-fifth C site, C(76,80) is bonded in a distorted single-bond geometry to one C(68), one C(82), and one H(44) atom. The C(76,80)-C(82) bond length is 1.44 Å. The C(76,80)-H(44) bond length is 1.09 Å. In the seventy-sixth C site, C(77) is bonded in a distorted single-bond geometry to one C(69), one C(88), and one H(45) atom. The C(77)-C(88) bond length is 1.43 Å. The C(77)-H(45) bond length is 1.08 Å. In the seventy-seventh C site, C(81) is bonded in a distorted trigonal planar geometry to one C(49); one C(75,79); and one N(3) atom. The C(81)-N(3) bond length is 1.39 Å. In the seventy-eighth C site, C(82) is bonded in a distorted single-bond geometry to one C(50); one C(76,80); and one N(4) atom. The C(82)-N(4) bond length is 1.42 Å. In the seventy-ninth C site, C(83) is bonded in a distorted trigonal planar geometry to one C(51); one C(74,78); and one N(2) atom. The C(83)-N(2) bond length is 1.41 Å. In the eightieth C site, C(84) is bonded in a distorted trigonal planar geometry to one C(52), one C(73), and one N(1) atom. The C(84)-N(1) bond length is 1.39 Å. In the eighty-first C site, C(85) is bonded in a distorted trigonal planar geometry to one C(53); one C(75,79); and one N(7) atom. The C(85)-C(75,79) bond length is 1.43 Å. The C(85)-N(7) bond length is 1.39 Å. In the eighty-second C site, C(86) is bonded in a distorted single-bond geometry to one C(54); one C(76,80); and one N(8) atom. The C(86)-C(76,80) bond length is 1.44 Å. The C(86)-N(8) bond length is 1.42 Å. In the eighty-third C site, C(87) is bonded in a distorted trigonal planar geometry to one C(55); one C(74,78); and one N(6) atom. The C(87)-C(74,78) bond length is 1.44 Å. The C(87)-N(6) bond length is 1.41 Å. In the eighty-fourth C site, C(88) is bonded in a distorted trigonal planar geometry to one C(56), one C(77), and one N(5) atom. The C(88)-N(5) bond length is 1.39 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one V(1), one C(57), and one C(84) atom. In the second N site, N(2) is bonded in a 4-coordinate geometry to one V(1), one V(3), one C(58), and one C(83) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one V(1), one C(59), and one C(81) atom. In the fourth N site, N(4) is bonded in a 4-coordinate geometry to one V(1), one V(3), one C(60), and one C(82) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one V(4), one C(61), and one C(88) atom. In the sixth N site, N(6) is bonded in a 4-coordinate geometry to one V(2), one V(4), one C(62), and one C(87) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one V(4), one C(63), and one C(85) atom. In the eighth N site, N(8) is bonded in a 4-coordinate geometry to one V(2), one V(4), one C(64), and one C(86) atom. There are forty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the twentieth H site, H(20,31) is bonded in a single-bond geometry to one C(28) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(30) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(32) atom. In the twenty-fifth H site, H(25) is bonded in a single-bond geometry to one C(33) atom. In the twenty-sixth H site, H(26) is bonded in a single-bond geometry to one C(34) atom. In the twenty-seventh H site, H(27) is bonded in a single-bond geometry to one C(35) atom. In the twenty-eighth H site, H(28) is bonded in a single-bond geometry to one C(36) atom. In the twenty-ninth H site, H(29) is bonded in a single-bond geometry to one C(37) atom. In the thirtieth H site, H(30) is bonded in a single-bond geometry to one C(38) atom. In the thirty-first H site, H(32) is bonded in a single-bond geometry to one C(40) atom. In the thirty-second H site, H(33,37) is bonded in a single-bond geometry to one C(65) atom. In the thirty-third H site, H(34,38) is bonded in a single-bond geometry to one C(66) atom. In the thirty-fourth H site, H(35,39) is bonded in a single-bond geometry to one C(67,71) atom. In the thirty-fifth H site, H(36,40) is bonded in a single-bond geometry to one C(68) atom. In the thirty-sixth H site, H(41) is bonded in a single-bond geometry to one C(73) atom. In the thirty-seventh H site, H(42) is bonded in a single-bond geometry to one C(74,78) atom. In the thirty-eighth H site, H(43,47) is bonded in a single-bond geometry to one C(75,79) atom. In the thirty-ninth H site, H(44) is bonded in a single-bond geometry to one C(76,80) atom. In the fortieth H site, H(45) is bonded in a single-bond geometry to one C(77) atom. In the forty-first H site, H(46) is bonded in a single-bond geometry to one C(74,78) atom. The H(46)-C(74,78) bond length is 1.09 Å. In the forty-second H site, H(48) is bonded in a single-bond geometry to one C(76,80) atom. The H(48)-C(76,80) bond length is 1.09 Å. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(10), and one O(17) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(10) bond length is 1.48 Å. The S(1)-O(17) bond length is 1.45 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one C(2); one O(18,22); one O(2); and one O(9) atom. The S(2)-O(18,22) bond length is 1.45 Å. The S(2)-O(2) bond length is 1.48 Å. The S(2)-O(9) bond length is 1.47 Å. In the third S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one O(12), one O(19), and one O(3) atom. The S(3)-O(12) bond length is 1.48 Å. The S(3)-O(19) bond length is 1.45 Å. The S(3)-O(3) bond length is 1.48 Å. In the fourth S site, S(4) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one O(11), one O(20), and one O(4) atom. The S(4)-O(11) bond length is 1.48 Å. The S(4)-O(20) bond length is 1.45 Å. The S(4)-O(4) bond length is 1.48 Å. In the fifth S site, S(5) is bonded in a distorted trigonal non-coplanar geometry to one C(5), one O(14), one O(21), and one O(5) atom. The S(5)-O(14) bond length is 1.48 Å. The S(5)-O(21) bond length is 1.45 Å. The S(5)-O(5) bond length is 1.48 Å. In the sixth S site, S(6) is bonded in a distorted trigonal non-coplanar geometry to one C(6); one O(13); one O(18,22); and one O(6) atom. The S(6)-O(13) bond length is 1.48 Å. The S(6)-O(18,22) bond length is 1.45 Å. The S(6)-O(6) bond length is 1.47 Å. In the seventh S site, S(7) is bonded in a distorted trigonal non-coplanar geometry to one C(7), one O(16), one O(23), and one O(7) atom. The S(7)-O(16) bond length is 1.48 Å. The S(7)-O(23) bond length is 1.45 Å. The S(7)-O(7) bond length is 1.48 Å. In the eighth S site, S(8) is bonded in a distorted trigonal non-coplanar geometry to one C(8), one O(15), one O(24), and one O(8) atom. The S(8)-O(15) bond length is 1.48 Å. The S(8)-O(24) bond length is 1.45 Å. The S(8)-O(8) bond length is 1.48 Å. There are twenty-five inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Sm(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Sm(1) and one S(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Sm(1) and one S(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Sm(1) and one S(4) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Sm(1) and one S(5) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Sm(1) and one S(6) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sm(1) and one S(7) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sm(1) and one S(8) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Sm(2) and one S(2) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Sm(2) and one S(1) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to one Sm(2) and one S(4) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one Sm(2) and one S(3) atom. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one Sm(2) and one S(6) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Sm(2) and one S(5) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one Sm(2) and one S(8) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one Sm(2) and one S(7) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one S(1) atom. In the eighteenth O site, O(18,22) is bonded in a single-bond geometry to one S(2) atom. In the nineteenth O site, O(19) is bonded in a single-bond geometry to one S(3) atom. In the twentieth O site, O(20) is bonded in a single-bond geometry to one S(4) atom. In the twenty-first O site, O(21) is bonded in a single-bond geometry to one S(5) atom. In the twenty-second O site, O(23) is bonded in a single-bond geometry to one S(7) atom. In the twenty-third O site, O(24) is bonded in a single-bond geometry to one S(8) atom. In the twenty-fourth O site, O(25) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the twenty-fifth O site, O(26) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. Linkers: 2 [O]S([O])([O])c1ccc(/C2=C3\C=C/C(=C(\c4ccc(S([O])([O])[O])cc4)C4=N/C(=C(/c5ccc(S([O])([O])[O])cc5)C5=CC=C([N]5)/C(c5ccc(S([O])([O])[O])cc5)=C5/C=CC2=N5)C=C4)[N]3)cc1. Metal clusters: 2 [Sm] ,4 [V]. The MOF has largest included sphere 4.73 A, density 1.70 g/cm3, surface area 3364.15 m2/g, accessible volume 0.14 cm3/g