ZnC11H10(N2Cl)2C7H6N2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two C7H6N2 clusters and two ZnC11H10(N2Cl)2 clusters. In each C7H6N2 cluster, there are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.37 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(16) atom. The C(18)-C(13) bond length is 1.40 Å. The C(18)-H(16) bond length is 1.09 Å. In the third C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(3), and one H(2) atom. The C(2)-N(3) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.09 Å. In the fourth C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(13), one N(3), one H(3), and one H(4) atom. The C(3)-C(13) bond length is 1.51 Å. The C(3)-N(3) bond length is 1.46 Å. The C(3)-H(3) bond length is 1.09 Å. The C(3)-H(4) bond length is 1.10 Å. In the fifth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(12), one N(1), and one N(3) atom. The C(12)-C(12) bond length is 1.45 Å. The C(12)-N(1) bond length is 1.34 Å. The C(12)-N(3) bond length is 1.38 Å. In the sixth C site, C(5) is bonded in a distorted single-bond geometry to one C(13) and one H(5) atom. The C(5)-C(13) bond length is 1.40 Å. The C(5)-H(5) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a trigonal planar geometry to one C(18), one C(3), and one C(5) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one C(1) and one C(12) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(12), one C(2), and one C(3) atom. There are six inequivalent H sites. In the first H site, H(16) is bonded in a single-bond geometry to one C(18) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In each ZnC11H10(N2Cl)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(2), one N(6), one Cl(1), and one Cl(2) atom. The Zn(1)-N(2) bond length is 2.05 Å. The Zn(1)-N(6) bond length is 2.05 Å. The Zn(1)-Cl(1) bond length is 2.25 Å. The Zn(1)-Cl(2) bond length is 2.22 Å. There are eleven inequivalent C sites. In the first C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one N(6), and one H(14) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-N(6) bond length is 1.35 Å. The C(16)-H(14) bond length is 1.09 Å. In the second C site, C(17) is bonded in a distorted single-bond geometry to one C(15), one C(16), and one H(15) atom. The C(17)-C(15) bond length is 1.40 Å. The C(17)-H(15) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(4), one N(4), and one N(5) atom. The C(4)-C(4) bond length is 1.44 Å. The C(4)-N(4) bond length is 1.34 Å. The C(4)-N(5) bond length is 1.38 Å. In the fourth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(15), one N(5), one H(6), and one H(7) atom. The C(6)-C(15) bond length is 1.51 Å. The C(6)-N(5) bond length is 1.45 Å. The C(6)-H(6) bond length is 1.10 Å. The C(6)-H(7) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(10), one C(15), and one H(8) atom. The C(7)-C(10) bond length is 1.39 Å. The C(7)-C(15) bond length is 1.40 Å. The C(7)-H(8) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9), one N(4), and one H(9) atom. The C(8)-C(9) bond length is 1.38 Å. The C(8)-N(4) bond length is 1.37 Å. The C(8)-H(9) bond length is 1.08 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(5), and one H(10) atom. The C(9)-N(5) bond length is 1.38 Å. The C(9)-H(10) bond length is 1.08 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(6), and one H(11) atom. The C(10)-N(6) bond length is 1.35 Å. The C(10)-H(11) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(11)-N(2) bond length is 1.35 Å. The C(11)-H(12) bond length is 1.09 Å. In the tenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(13) atom. The C(14)-N(2) bond length is 1.35 Å. The C(14)-H(13) bond length is 1.09 Å. In the eleventh C site, C(15) is bonded in a trigonal planar geometry to one C(17), one C(6), and one C(7) atom. There are four inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(14) atom. In the second N site, N(4) is bonded in a water-like geometry to one C(4) and one C(8) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(9) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(16) atom. There are ten inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 4 [c]1cc(Cn2ccnc2-c2nccn2Cc2ccncc2)ccn1 ,4 c1cc(Cn2ccnc2-c2nccn2Cc2ccncc2)ccn1. Metal clusters: 4 Cl[Zn]Cl. The MOF has largest included sphere 4.69 A, density 1.30 g/cm3, surface area 4914.35 m2/g, accessible volume 0.37 cm3/g