CuC19N6H13I(CH)7 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of fourteen 02329_fluka molecules and one CuC19N6H13I cluster. In the CuC19N6H13I cluster, Cu(1) is bonded in a distorted water-like geometry to one N(1), one N(6), and two equivalent I(1) atoms. The Cu(1)-N(1) bond length is 2.03 Å. The Cu(1)-N(6) bond length is 2.03 Å. There is one shorter (2.64 Å) and one longer (2.65 Å) Cu(1)-I(1) bond length. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.45 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(5) atom. The C(6)-N(2) bond length is 1.30 Å. The C(6)-H(5) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one N(3) atom. The C(7)-C(8) bond length is 1.47 Å. The C(7)-N(3) bond length is 1.30 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(7), and one C(9) atom. The C(8)-C(13) bond length is 1.41 Å. The C(8)-C(9) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(9)-H(6) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(10) atom. The C(13)-H(10) bond length is 1.09 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one N(4) atom. The C(14)-C(15) bond length is 1.47 Å. The C(14)-N(4) bond length is 1.30 Å. In the twelfth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(20) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-C(20) bond length is 1.41 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(11,15) atom. The C(16)-H(11,15) bond length is 1.09 Å. In the fourteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(15) and one H(11,15) atom. The C(20)-H(11,15) bond length is 1.09 Å. In the fifteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(5), and one H(16) atom. The C(21)-C(22) bond length is 1.45 Å. The C(21)-N(5) bond length is 1.29 Å. The C(21)-H(16) bond length is 1.10 Å. In the sixteenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(26) atom. The C(22)-C(23) bond length is 1.41 Å. The C(22)-C(26) bond length is 1.40 Å. In the seventeenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(17) atom. The C(23)-H(17) bond length is 1.09 Å. In the eighteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(19) atom. The C(25)-N(6) bond length is 1.35 Å. The C(25)-H(19) bond length is 1.09 Å. In the nineteenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(22), one N(6), and one H(20) atom. The C(26)-N(6) bond length is 1.34 Å. The C(26)-H(20) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(6) and one N(3) atom. The N(2)-N(3) bond length is 1.39 Å. In the third N site, N(3) is bonded in a distorted single-bond geometry to one C(7) and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one C(14) and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one C(21) and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(25), and one C(26) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(11,15) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(26) atom. I(1) is bonded in a 2-coordinate geometry to two equivalent Cu(1) atoms. Linkers: 2 [CH]([N]/N=C(C(=N/[N][CH]c1cccnc1)\c1ccccc1)/c1ccccc1)c1cccnc1 ,2 [c]1ccc([CH][N]/N=C(C(=N/[N][CH]c2cccnc2)\c2ccccc2)/c2ccccc2)cn1. Metal clusters: 1 I[Cu][Cu]I. The MOF has largest included sphere 4.97 A, density 1.49 g/cm3, surface area 4504.31 m2/g, accessible volume 0.19 cm3/g