Cu3C8N2H18SOCl3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Cu3C8N2H18SOCl3 clusters. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one N(2), one S(1), one Cl(1), and one Cl(3) atom to form corner-sharing CuSNCl2 tetrahedra. The Cu(1)-N(2) bond length is 2.04 Å. The Cu(1)-S(1) bond length is 2.18 Å. The Cu(1)-Cl(1) bond length is 2.36 Å. The Cu(1)-Cl(3) bond length is 2.44 Å. In the second Cu site, Cu(2) is bonded to one N(1), one Cl(1), one Cl(2), and one Cl(3) atom to form distorted corner-sharing CuNCl3 tetrahedra. The Cu(2)-N(1) bond length is 2.11 Å. The Cu(2)-Cl(1) bond length is 2.48 Å. The Cu(2)-Cl(2) bond length is 2.28 Å. The Cu(2)-Cl(3) bond length is 2.30 Å. In the third Cu site, Cu(3) is bonded in a distorted trigonal planar geometry to one Cl(1), one Cl(2), and one Cl(3) atom. The Cu(3)-Cl(1) bond length is 2.32 Å. The Cu(3)-Cl(2) bond length is 2.25 Å. The Cu(3)-Cl(3) bond length is 2.42 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(1)-N(1) bond length is 1.49 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(3), and one H(4) atom. The C(2)-N(2) bond length is 1.49 Å. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(4) bond length is 1.10 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(5), and one H(6) atom. The C(3)-N(1) bond length is 1.49 Å. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(6) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(7), and one H(8) atom. The C(4)-N(2) bond length is 1.49 Å. The C(4)-H(7) bond length is 1.10 Å. The C(4)-H(8) bond length is 1.10 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(10), and one H(9) atom. The C(5)-N(1) bond length is 1.49 Å. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(9) bond length is 1.10 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(11), and one H(12) atom. The C(6)-N(2) bond length is 1.49 Å. The C(6)-H(11) bond length is 1.10 Å. The C(6)-H(12) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a trigonal non-coplanar geometry to one H(13), one H(14), one H(15), and one S(1) atom. The C(7)-H(13) bond length is 1.10 Å. The C(7)-H(14) bond length is 1.10 Å. The C(7)-H(15) bond length is 1.10 Å. The C(7)-S(1) bond length is 1.79 Å. In the eighth C site, C(8) is bonded in a trigonal non-coplanar geometry to one H(16), one H(17), one H(18), and one S(1) atom. The C(8)-H(16) bond length is 1.10 Å. The C(8)-H(17) bond length is 1.10 Å. The C(8)-H(18) bond length is 1.09 Å. The C(8)-S(1) bond length is 1.79 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a tetrahedral geometry to one Cu(2), one C(1), one C(3), and one C(5) atom. In the second N site, N(2) is bonded to one Cu(1), one C(2), one C(4), and one C(6) atom to form NCuC3 tetrahedra that share  a cornercorner with one S(1)CuC2O tetrahedra. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(7) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(7) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(7) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(8) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(8) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(8) atom. S(1) is bonded to one Cu(1), one C(7), one C(8), and one O(1) atom to form distorted SCuC2O tetrahedra that share  a cornercorner with one N(2)CuC3 tetrahedra. The S(1)-O(1) bond length is 1.50 Å. O(1) is bonded in a single-bond geometry to one S(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one Cu(2), and one Cu(3) atom. In the second Cl site, Cl(2) is bonded in a 2-coordinate geometry to one Cu(2) and one Cu(3) atom. In the third Cl site, Cl(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one Cu(2), and one Cu(3) atom. Linkers: 3 C1CN2CCN1CC2. Metal clusters: 12 [Cu]. The MOF has largest included sphere 2.29 A, density 2.20 g/cm3, surface area 3535.38 m2/g, accessible volume 0.10 cm3/g