CdC15H11(NO)4(CH)5(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules, four 02329_fluka molecules, and two CdC15H11(NO)4 clusters. In each CdC15H11(NO)4 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.28 Å. The Cd(1)-N(3) bond length is 2.30 Å. The Cd(1)-O(1) bond length is 2.30 Å. The Cd(1)-O(2) bond length is 2.52 Å. The Cd(1)-O(3) bond length is 2.28 Å. The Cd(1)-O(4) bond length is 2.54 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one N(1) atom. The C(2)-C(3) bond length is 1.42 Å. The C(2)-C(7) bond length is 1.40 Å. The C(2)-N(1) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one N(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-N(2) bond length is 1.39 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(7)-H(5) bond length is 1.09 Å. In the seventh C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(6), and one H(7) atom. The C(8)-N(2) bond length is 1.47 Å. The C(8)-H(6) bond length is 1.10 Å. The C(8)-H(7) bond length is 1.10 Å. In the eighth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(12), and one H(13) atom. The C(11)-N(4) bond length is 1.46 Å. The C(11)-H(12) bond length is 1.10 Å. The C(11)-H(13) bond length is 1.10 Å. In the ninth C site, C(12) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(14) atom. The C(12)-N(3) bond length is 1.33 Å. The C(12)-N(4) bond length is 1.36 Å. The C(12)-H(14) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one N(3) atom. The C(13)-C(14) bond length is 1.42 Å. The C(13)-C(18) bond length is 1.40 Å. The C(13)-N(3) bond length is 1.39 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one N(4) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-N(4) bond length is 1.39 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(15) atom. The C(15)-H(15) bond length is 1.09 Å. In the thirteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(18) atom. The C(18)-H(18) bond length is 1.09 Å. In the fourteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(19)-O(1) bond length is 1.29 Å. The C(19)-O(2) bond length is 1.27 Å. In the fifteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(21)-O(3) bond length is 1.29 Å. The C(21)-O(4) bond length is 1.27 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(8) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(12), and one C(13) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(14) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(19) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(19) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(21) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(21) atom. Linkers: 2 [O]C(=O)/C=C/C([O])=O. Metal clusters: 2 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 2.07 A, density 1.68 g/cm3, surface area 4636.44 m2/g, accessible volume 0.11 cm3/g