DyC9N5H8O7CHCH3 crystallizes in the monoclinic C2/c space group. The structure consists of eight 02329_fluka molecules and eight 02329_fluka molecules inside a DyC9N5H8O7 framework. In the DyC9N5H8O7 framework, Dy(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(4), one O(5), one O(6), one O(7), and two equivalent O(3) atoms. The Dy(1)-O(1) bond length is 2.32 Å. The Dy(1)-O(2) bond length is 2.27 Å. The Dy(1)-O(4) bond length is 2.32 Å. The Dy(1)-O(5) bond length is 2.32 Å. The Dy(1)-O(6) bond length is 2.42 Å. The Dy(1)-O(7) bond length is 2.43 Å. There is one shorter (2.35 Å) and one longer (2.51 Å) Dy(1)-O(3) bond length. There are nine inequivalent C sites. In the first C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(2), and one O(4) atom. The C(7)-C(3) bond length is 1.49 Å. The C(7)-O(2) bond length is 1.27 Å. The C(7)-O(4) bond length is 1.28 Å. In the second C site, C(8) is bonded in a distorted trigonal planar geometry to one C(5), one C(6), and one N(1) atom. The C(8)-C(5) bond length is 1.42 Å. The C(8)-C(6) bond length is 1.40 Å. The C(8)-N(1) bond length is 1.38 Å. In the third C site, C(9) is bonded in a trigonal planar geometry to one N(2), one N(3), and one N(5) atom. The C(9)-N(2) bond length is 1.38 Å. The C(9)-N(3) bond length is 1.33 Å. The C(9)-N(5) bond length is 1.38 Å. In the fourth C site, C(10) is bonded in a trigonal planar geometry to one N(2), one N(4), and one H(9) atom. The C(10)-N(2) bond length is 1.36 Å. The C(10)-N(4) bond length is 1.33 Å. The C(10)-H(9) bond length is 1.08 Å. In the fifth C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one O(1) atom. The C(2)-C(3) bond length is 1.43 Å. The C(2)-O(1) bond length is 1.31 Å. In the sixth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(3)-C(6) bond length is 1.39 Å. In the seventh C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(6) atom. The C(4)-O(3) bond length is 1.30 Å. The C(4)-O(6) bond length is 1.26 Å. In the eighth C site, C(5) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(5)-H(7) bond length is 1.09 Å. In the ninth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(3), one C(8), and one H(8) atom. The C(6)-H(8) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one C(8) and one N(5) atom. The N(1)-N(5) bond length is 1.29 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(10), one C(9), and one H(5) atom. The N(2)-H(5) bond length is 1.01 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(9) and one N(4) atom. The N(3)-N(4) bond length is 1.37 Å. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one C(10), one N(3), and one H(2) atom. The N(4)-H(2) bond length is 1.68 Å. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(9) and one N(1) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(4) and one O(5) atom. The H(1)-O(4) bond length is 1.76 Å. The H(1)-O(5) bond length is 0.99 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one N(4) and one O(5) atom. The H(2)-O(5) bond length is 1.01 Å. In the third H site, H(3) is bonded in a distorted linear geometry to one O(1) and one O(7) atom. The H(3)-O(1) bond length is 1.61 Å. The H(3)-O(7) bond length is 1.01 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(7) atom. The H(4)-O(7) bond length is 0.97 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a distorted water-like geometry to one Dy(1), one H(3), and one H(4) atom. In the second O site, O(5) is bonded in a distorted water-like geometry to one Dy(1), one H(1), and one H(2) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to one Dy(1), one C(2), and one H(3) atom. In the fourth O site, O(2) is bonded in a bent 150 degrees geometry to one Dy(1) and one C(7) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Dy(1) and one C(4) atom. In the sixth O site, O(4) is bonded in a 3-coordinate geometry to one Dy(1), one C(7), and one H(1) atom. In the seventh O site, O(6) is bonded in a distorted single-bond geometry to one Dy(1) and one C(4) atom. Linkers: 4 [O]C(=O)c1cc([N][N]c2nnc[nH]2)ccc1[O]. Metal clusters: 4 [Dy]. The MOF has largest included sphere 3.89 A, density 1.74 g/cm3, surface area 3303.59 m2/g, accessible volume 0.21 cm3/g