UAg2C24N4H12(O5Cl2)2 crystallizes in the triclinic P-1 space group. U(1) is bonded in a distorted hexagonal bipyramidal geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Both U(1)-O(1) bond lengths are 2.56 Å. Both U(1)-O(2) bond lengths are 1.82 Å. Both U(1)-O(3) bond lengths are 2.55 Å. Both U(1)-O(4) bond lengths are 2.36 Å. Ag(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one O(1), one O(2), and one O(5) atom. The Ag(1)-N(1) bond length is 2.46 Å. The Ag(1)-N(2) bond length is 2.19 Å. The Ag(1)-O(1) bond length is 2.78 Å. The Ag(1)-O(2) bond length is 2.74 Å. The Ag(1)-O(5) bond length is 2.25 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(3) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(1) atom. The C(3)-C(6) bond length is 1.39 Å. The C(3)-H(1) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(5), and one Cl(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-Cl(1) bond length is 1.73 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(2) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(2) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(3) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-H(3) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(4), and one O(5) atom. The C(7)-C(9) bond length is 1.51 Å. The C(7)-O(4) bond length is 1.28 Å. The C(7)-O(5) bond length is 1.26 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(9), and one Cl(2) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. The C(8)-Cl(2) bond length is 1.72 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(11), one C(7), and one C(8) atom. The C(9)-C(11) bond length is 1.40 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(2), and one H(4) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(4) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(11)-H(5) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(6) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(5), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(10), and one C(12) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one U(1), one Ag(1), and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one U(1) and one Ag(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one U(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one U(1) and one C(7) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Ag(1) and one C(7) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(4) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(8) atom. Linkers: 4 [O]C(=O)c1ccncc1Cl. Metal clusters: 1 [U] ,2 [Ag]. The MOF has largest included sphere 2.95 A, density 2.39 g/cm3, surface area 2791.80 m2/g, accessible volume 0.09 cm3/g