CuC4H8(NO2)2(CH2)8 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and two CuC4H8(NO2)2 clusters. In each CuC4H8(NO2)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 2.01 Å. Both Cu(1)-O(1) bond lengths are 2.02 Å. There are two inequivalent C sites. In the first C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(6)-O(1) bond length is 1.31 Å. The C(6)-O(2) bond length is 1.25 Å. In the second C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(8), and one H(9) atom. The C(1)-N(1) bond length is 1.48 Å. The C(1)-H(8) bond length is 1.10 Å. The C(1)-H(9) bond length is 1.10 Å. N(1) is bonded to one Cu(1), one C(1), one H(6), and one H(7) atom to form distorted corner-sharing NCuH2C tetrahedra. The N(1)-H(6) bond length is 1.04 Å. The N(1)-H(7) bond length is 1.03 Å. There are four inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(7) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cu(1) and one C(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(6) atom. Linkers: 4 NCCCCCC([O])=O. Metal clusters: 2 [Cu]. RCSR code: sql. The MOF has largest included sphere 2.54 A, density 1.34 g/cm3, surface area 5237.55 m2/g, accessible volume 0.22 cm3/g