(CH)3(CH2)2C3NH6ZnC9NH6O3Cl2CH3CO is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, four 02329_fluka molecules, two dimethyl ether molecules, two trimethylammonium molecules, and two ZnC9NH6O3Cl2 clusters. In one of the ZnC9NH6O3Cl2 clusters, Zn(1) is bonded in a tetrahedral geometry to one N(1), one O(7), one Cl(1), and one Cl(2) atom. The Zn(1)-N(1) bond length is 2.06 Å. The Zn(1)-O(7) bond length is 1.99 Å. The Zn(1)-Cl(1) bond length is 2.25 Å. The Zn(1)-Cl(2) bond length is 2.32 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.43 Å. The C(1)-N(1) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(5)-C(6) bond length is 1.42 Å. The C(5)-H(3) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.43 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.52 Å. The C(7)-C(8) bond length is 1.38 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(4) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(4) bond length is 1.09 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(8), one N(1), and one H(5) atom. The C(9)-N(1) bond length is 1.33 Å. The C(9)-H(5) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted water-like geometry to one C(7), one H(9), and one O(2) atom. The C(11)-H(9) bond length is 1.10 Å. The C(11)-O(2) bond length is 1.43 Å. In the ninth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(38)-O(7) bond length is 1.29 Å. The C(38)-O(8) bond length is 1.24 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(43) is bonded in a single-bond geometry to one O(2) atom. The H(43)-O(2) bond length is 0.98 Å. There are three inequivalent O sites. In the first O site, O(2) is bonded in a water-like geometry to one C(11) and one H(43) atom. In the second O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(38) atom. In the third O site, O(8) is bonded in a single-bond geometry to one C(38) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. In one of the ZnC9NH6O3Cl2 clusters, Zn(2) is bonded in a tetrahedral geometry to one N(3), one O(3), one Cl(3), and one Cl(4) atom. The Zn(2)-N(3) bond length is 2.10 Å. The Zn(2)-O(3) bond length is 2.01 Å. The Zn(2)-Cl(3) bond length is 2.26 Å. The Zn(2)-Cl(4) bond length is 2.27 Å. There are nine inequivalent C sites. In the first C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(19)-O(3) bond length is 1.30 Å. The C(19)-O(4) bond length is 1.24 Å. In the second C site, C(20) is bonded in a distorted trigonal planar geometry to one C(21), one C(25), and one N(3) atom. The C(20)-C(21) bond length is 1.42 Å. The C(20)-C(25) bond length is 1.44 Å. The C(20)-N(3) bond length is 1.37 Å. In the third C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(21) atom. The C(21)-H(21) bond length is 1.09 Å. In the fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(23) atom. The C(24)-C(25) bond length is 1.42 Å. The C(24)-H(23) bond length is 1.08 Å. In the fifth C site, C(25) is bonded in a trigonal planar geometry to one C(20), one C(24), and one C(26) atom. The C(25)-C(26) bond length is 1.44 Å. In the sixth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(30) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-C(30) bond length is 1.54 Å. In the seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(26), one C(28), and one H(24) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-H(24) bond length is 1.09 Å. In the eighth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one N(3), and one H(25) atom. The C(28)-N(3) bond length is 1.33 Å. The C(28)-H(25) bond length is 1.09 Å. In the ninth C site, C(30) is bonded in a distorted water-like geometry to one C(26), one H(29), and one O(6) atom. The C(30)-H(29) bond length is 1.11 Å. The C(30)-O(6) bond length is 1.42 Å. N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(20), and one C(28) atom. There are six inequivalent H sites. In the first H site, H(21) is bonded in a single-bond geometry to one C(21) atom. In the second H site, H(23) is bonded in a single-bond geometry to one C(24) atom. In the third H site, H(24) is bonded in a single-bond geometry to one C(27) atom. In the fourth H site, H(25) is bonded in a single-bond geometry to one C(28) atom. In the fifth H site, H(29) is bonded in a single-bond geometry to one C(30) atom. In the sixth H site, H(44) is bonded in a single-bond geometry to one O(6) atom. The H(44)-O(6) bond length is 0.99 Å. There are three inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(19) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(19) atom. In the third O site, O(6) is bonded in a water-like geometry to one C(30) and one H(44) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Zn(2) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Zn(2) atom. Linkers: 2 COc1ccc2c(c1)c(ccn2)[C@H]([C@@H]1C[N@@H]2CC[C@H]1C[C@@H]2C(=O)[O])O. Metal clusters: 2 O=[C]O[Zn](Cl)Cl. The MOF has largest included sphere 2.94 A, density 1.57 g/cm3, surface area 4188.17 m2/g, accessible volume 0.13 cm3/g