TbC30N5H24O8 crystallizes in the triclinic P-1 space group. There are two inequivalent Tb sites. In the first Tb site, Tb(1) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(14), one O(15), one O(5), one O(7), one O(9), and two equivalent O(3) atoms. The Tb(1)-O(1) bond length is 2.44 Å. The Tb(1)-O(12) bond length is 2.33 Å. The Tb(1)-O(14) bond length is 2.32 Å. The Tb(1)-O(15) bond length is 2.55 Å. The Tb(1)-O(5) bond length is 2.37 Å. The Tb(1)-O(7) bond length is 2.45 Å. The Tb(1)-O(9) bond length is 2.47 Å. There is one shorter (2.29 Å) and one longer (2.74 Å) Tb(1)-O(3) bond length. In the second Tb site, Tb(2) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(13), one O(16), one O(2), one O(6), one O(8), and two equivalent O(4) atoms. The Tb(2)-O(10) bond length is 2.47 Å. The Tb(2)-O(11) bond length is 2.33 Å. The Tb(2)-O(13) bond length is 2.32 Å. The Tb(2)-O(16) bond length is 2.55 Å. The Tb(2)-O(2) bond length is 2.44 Å. The Tb(2)-O(6) bond length is 2.37 Å. The Tb(2)-O(8) bond length is 2.45 Å. There is one shorter (2.29 Å) and one longer (2.74 Å) Tb(2)-O(4) bond length. There are fifty inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(45,46); one N(3); and one N(5) atom. The C(1)-C(45,46) bond length is 1.48 Å. The C(1)-N(3) bond length is 1.35 Å. The C(1)-N(5) bond length is 1.34 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(45,46); one N(4); and one N(6) atom. The C(2)-C(45,46) bond length is 1.48 Å. The C(2)-N(4) bond length is 1.35 Å. The C(2)-N(6) bond length is 1.34 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(1), and one N(3) atom. The C(3)-C(15) bond length is 1.48 Å. The C(3)-N(1) bond length is 1.35 Å. The C(3)-N(3) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(2), and one N(4) atom. The C(4)-C(16) bond length is 1.48 Å. The C(4)-N(2) bond length is 1.35 Å. The C(4)-N(4) bond length is 1.35 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(31), one N(1), and one N(5) atom. The C(5)-C(31) bond length is 1.47 Å. The C(5)-N(1) bond length is 1.35 Å. The C(5)-N(5) bond length is 1.34 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(32), one N(2), and one N(6) atom. The C(6)-C(32) bond length is 1.47 Å. The C(6)-N(2) bond length is 1.35 Å. The C(6)-N(6) bond length is 1.34 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(1), and one O(7) atom. The C(7)-C(17) bond length is 1.50 Å. The C(7)-O(1) bond length is 1.27 Å. The C(7)-O(7) bond length is 1.28 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(2), and one O(8) atom. The C(8)-C(18) bond length is 1.50 Å. The C(8)-O(2) bond length is 1.27 Å. The C(8)-O(8) bond length is 1.28 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(11), one C(19), and one C(21) atom. The C(9)-C(11) bond length is 1.49 Å. The C(9)-C(19) bond length is 1.40 Å. The C(9)-C(21) bond length is 1.40 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(12), one C(20), and one C(22) atom. The C(10)-C(12) bond length is 1.49 Å. The C(10)-C(20) bond length is 1.40 Å. The C(10)-C(22) bond length is 1.40 Å. In the eleventh C site, C(11) is bonded in a bent 120 degrees geometry to one C(9), one O(3), and one O(5) atom. The C(11)-O(3) bond length is 1.28 Å. The C(11)-O(5) bond length is 1.27 Å. In the twelfth C site, C(12) is bonded in a bent 120 degrees geometry to one C(10), one O(4), and one O(6) atom. The C(12)-O(4) bond length is 1.28 Å. The C(12)-O(6) bond length is 1.27 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(31) and one H(1,2) atom. The C(13)-C(31) bond length is 1.40 Å. The C(13)-H(1,2) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(32) and one H(1,2) atom. The C(14)-C(32) bond length is 1.40 Å. The C(14)-H(1,2) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(23), one C(3), and one C(35) atom. The C(15)-C(23) bond length is 1.41 Å. The C(15)-C(35) bond length is 1.41 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(24), one C(36), and one C(4) atom. The C(16)-C(24) bond length is 1.41 Å. The C(16)-C(36) bond length is 1.41 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(29), one C(37), and one C(7) atom. The C(17)-C(29) bond length is 1.40 Å. The C(17)-C(37) bond length is 1.40 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(30), one C(38), and one C(8) atom. The C(18)-C(30) bond length is 1.40 Å. The C(18)-C(38) bond length is 1.40 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(9) and one H(3,4) atom. The C(19)-H(3,4) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(10) and one H(3,4) atom. The C(20)-H(3,4) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(39); one C(9); and one H(5,6) atom. The C(21)-C(39) bond length is 1.39 Å. The C(21)-H(5,6) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(10); one C(40); and one H(5,6) atom. The C(22)-C(40) bond length is 1.39 Å. The C(22)-H(5,6) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted trigonal planar geometry to one C(15), one C(29), and one H(7) atom. The C(23)-C(29) bond length is 1.39 Å. The C(23)-H(7) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(16), one C(30), and one H(8) atom. The C(24)-C(30) bond length is 1.39 Å. The C(24)-H(8) bond length is 1.09 Å. In the twenty-fifth C site, C(25,26) is bonded in a distorted bent 120 degrees geometry to one C(33), one O(11), and one O(13) atom. The C(25,26)-C(33) bond length is 1.50 Å. The C(25,26)-O(11) bond length is 1.27 Å. The C(25,26)-O(13) bond length is 1.27 Å. In the twenty-sixth C site, C(27,28) is bonded in a distorted trigonal planar geometry to one C(33), one C(41), and one H(9) atom. The C(27,28)-C(33) bond length is 1.40 Å. The C(27,28)-C(41) bond length is 1.39 Å. The C(27,28)-H(9) bond length is 1.09 Å. In the twenty-seventh C site, C(29) is bonded in a distorted single-bond geometry to one C(17), one C(23), and one H(11) atom. The C(29)-H(11) bond length is 1.09 Å. In the twenty-eighth C site, C(30) is bonded in a distorted single-bond geometry to one C(18), one C(24), and one H(12) atom. The C(30)-H(12) bond length is 1.09 Å. In the twenty-ninth C site, C(31) is bonded in a trigonal planar geometry to one C(13), one C(39), and one C(5) atom. The C(31)-C(39) bond length is 1.41 Å. In the thirtieth C site, C(32) is bonded in a trigonal planar geometry to one C(14), one C(40), and one C(6) atom. The C(32)-C(40) bond length is 1.41 Å. In the thirty-first C site, C(33) is bonded in a trigonal planar geometry to one C(25,26); one C(27,28); and one C(43,44) atom. The C(33)-C(43,44) bond length is 1.40 Å. In the thirty-second C site, C(34) is bonded in a trigonal planar geometry to one C(25,26); one C(27,28); and one C(43,44) atom. The C(34)-C(25,26) bond length is 1.50 Å. The C(34)-C(27,28) bond length is 1.40 Å. The C(34)-C(43,44) bond length is 1.40 Å. In the thirty-third C site, C(35) is bonded in a distorted single-bond geometry to one C(15) and one H(13,14) atom. The C(35)-H(13,14) bond length is 1.09 Å. In the thirty-fourth C site, C(36) is bonded in a distorted single-bond geometry to one C(16) and one H(13,14) atom. The C(36)-H(13,14) bond length is 1.09 Å. In the thirty-fifth C site, C(37) is bonded in a distorted single-bond geometry to one C(17) and one H(15,16) atom. The C(37)-H(15,16) bond length is 1.09 Å. In the thirty-sixth C site, C(38) is bonded in a distorted single-bond geometry to one C(18) and one H(15,16) atom. The C(38)-H(15,16) bond length is 1.09 Å. In the thirty-seventh C site, C(39) is bonded in a distorted trigonal planar geometry to one C(21); one C(31); and one H(17,18) atom. The C(39)-H(17,18) bond length is 1.09 Å. In the thirty-eighth C site, C(40) is bonded in a distorted trigonal planar geometry to one C(22); one C(32); and one H(17,18) atom. The C(40)-H(17,18) bond length is 1.09 Å. In the thirty-ninth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(27,28); one C(45,46); and one H(19,20) atom. The C(41)-C(45,46) bond length is 1.41 Å. The C(41)-H(19,20) bond length is 1.09 Å. In the fortieth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(27,28); one C(45,46); and one H(19,20) atom. The C(42)-C(27,28) bond length is 1.39 Å. The C(42)-C(45,46) bond length is 1.41 Å. The C(42)-H(19,20) bond length is 1.09 Å. In the forty-first C site, C(43,44) is bonded in a distorted single-bond geometry to one C(33), one C(47), and one H(21) atom. The C(43,44)-C(47) bond length is 1.39 Å. The C(43,44)-H(21) bond length is 1.09 Å. In the forty-second C site, C(45,46) is bonded in a trigonal planar geometry to one C(1), one C(41), and one C(47) atom. The C(45,46)-C(47) bond length is 1.41 Å. In the forty-third C site, C(47) is bonded in a distorted trigonal planar geometry to one C(43,44); one C(45,46); and one H(23,24) atom. The C(47)-H(23,24) bond length is 1.09 Å. In the forty-fourth C site, C(48) is bonded in a distorted trigonal planar geometry to one C(43,44); one C(45,46); and one H(23,24) atom. The C(48)-C(43,44) bond length is 1.39 Å. The C(48)-C(45,46) bond length is 1.41 Å. The C(48)-H(23,24) bond length is 1.09 Å. In the forty-fifth C site, C(49,50) is bonded in a bent 120 degrees geometry to one N(7) and one O(9) atom. The C(49,50)-N(7) bond length is 1.32 Å. The C(49,50)-O(9) bond length is 1.23 Å. In the forty-sixth C site, C(51,52) is bonded to one N(7); one H(25,26); one H(27,28); and one H(29,30) atom to form corner-sharing CH3N tetrahedra. The C(51,52)-N(7) bond length is 1.47 Å. The C(51,52)-H(25,26) bond length is 1.10 Å. The C(51,52)-H(27,28) bond length is 1.10 Å. The C(51,52)-H(29,30) bond length is 1.09 Å. In the forty-seventh C site, C(53,54) is bonded to one N(7); one H(31,32); one H(33,34); and one H(35,36) atom to form corner-sharing CH3N tetrahedra. The C(53,54)-N(7) bond length is 1.46 Å. The C(53,54)-H(31,32) bond length is 1.10 Å. The C(53,54)-H(33,34) bond length is 1.09 Å. The C(53,54)-H(35,36) bond length is 1.10 Å. In the forty-eighth C site, C(55,56) is bonded in a bent 120 degrees geometry to one N(9) and one O(15) atom. The C(55,56)-N(9) bond length is 1.32 Å. The C(55,56)-O(15) bond length is 1.22 Å. In the forty-ninth C site, C(57,58) is bonded to one N(9); one H(37,38); one H(39,40); and one H(41,42) atom to form corner-sharing CH3N tetrahedra. The C(57,58)-N(9) bond length is 1.47 Å. The C(57,58)-H(37,38) bond length is 1.10 Å. The C(57,58)-H(39,40) bond length is 1.10 Å. The C(57,58)-H(41,42) bond length is 1.10 Å. In the fiftieth C site, C(59,60) is bonded to one N(9); one H(43,44); one H(45,46); and one H(47,48) atom to form corner-sharing CH3N tetrahedra. The C(59,60)-N(9) bond length is 1.46 Å. The C(59,60)-H(43,44) bond length is 1.10 Å. The C(59,60)-H(45,46) bond length is 1.09 Å. The C(59,60)-H(47,48) bond length is 1.10 Å. There are ten inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(3) and one C(5) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(4) and one C(6) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(3) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(2) and one C(4) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(1) and one C(5) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one C(2) and one C(6) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(49,50); one C(51,52); and one C(53,54) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(49,50); one C(51,52); and one C(53,54) atom. The N(8)-C(49,50) bond length is 1.32 Å. The N(8)-C(51,52) bond length is 1.47 Å. The N(8)-C(53,54) bond length is 1.46 Å. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(55,56); one C(57,58); and one C(59,60) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one C(55,56); one C(57,58); and one C(59,60) atom. The N(10)-C(55,56) bond length is 1.32 Å. The N(10)-C(57,58) bond length is 1.47 Å. The N(10)-C(59,60) bond length is 1.46 Å. There are twenty-eight inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(19) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(21) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(23) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(24) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(27,28) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(27,28) atom. The H(10)-C(27,28) bond length is 1.09 Å. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(29) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(30) atom. In the tenth H site, H(13,14) is bonded in a single-bond geometry to one C(35) atom. In the eleventh H site, H(15,16) is bonded in a single-bond geometry to one C(37) atom. In the twelfth H site, H(17,18) is bonded in a single-bond geometry to one C(39) atom. In the thirteenth H site, H(19,20) is bonded in a single-bond geometry to one C(41) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(43,44) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(43,44) atom. The H(22)-C(43,44) bond length is 1.09 Å. In the sixteenth H site, H(23,24) is bonded in a single-bond geometry to one C(47) atom. In the seventeenth H site, H(25,26) is bonded in a single-bond geometry to one C(51,52) atom. In the eighteenth H site, H(27,28) is bonded in a single-bond geometry to one C(51,52) atom. In the nineteenth H site, H(29,30) is bonded in a single-bond geometry to one C(51,52) atom. In the twentieth H site, H(31,32) is bonded in a single-bond geometry to one C(53,54) atom. In the twenty-first H site, H(33,34) is bonded in a single-bond geometry to one C(53,54) atom. In the twenty-second H site, H(35,36) is bonded in a single-bond geometry to one C(53,54) atom. In the twenty-third H site, H(37,38) is bonded in a single-bond geometry to one C(57,58) atom. In the twenty-fourth H site, H(39,40) is bonded in a single-bond geometry to one C(57,58) atom. In the twenty-fifth H site, H(41,42) is bonded in a single-bond geometry to one C(57,58) atom. In the twenty-sixth H site, H(43,44) is bonded in a single-bond geometry to one C(59,60) atom. In the twenty-seventh H site, H(45,46) is bonded in a single-bond geometry to one C(59,60) atom. In the twenty-eighth H site, H(47,48) is bonded in a single-bond geometry to one C(59,60) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Tb(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Tb(2) and one C(8) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to two equivalent Tb(1) and one C(11) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to two equivalent Tb(2) and one C(12) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Tb(1) and one C(11) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Tb(2) and one C(12) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Tb(1) and one C(7) atom. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one Tb(2) and one C(8) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Tb(1) and one C(49,50) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Tb(2) and one C(49,50) atom. The O(10)-C(49,50) bond length is 1.23 Å. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Tb(2) and one C(25,26) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Tb(1) and one C(25,26) atom. The O(12)-C(25,26) bond length is 1.27 Å. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Tb(2) and one C(25,26) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Tb(1) and one C(25,26) atom. The O(14)-C(25,26) bond length is 1.27 Å. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Tb(1) and one C(55,56) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one Tb(2) and one C(55,56) atom. The O(16)-C(55,56) bond length is 1.22 Å. Linkers: 4 [O]C(=O)c1ccc(cc1)C1=NC(=[N]=C([N]1)c1ccc(cc1)C(=O)[O])c1ccc(cc1)C(=O)[O]. Metal clusters: 4 [Tb]. The MOF has largest included sphere 5.74 A, density 1.18 g/cm3, surface area 4373.21 m2/g, accessible volume 0.41 cm3/g