HgC10H8(NBr)2HgC12H10(NBr)2(CH)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two HgC10H8(NBr)2 clusters, and one HgC12H10(NBr)2 cluster. In each HgC10H8(NBr)2 cluster, Hg(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(2), one Br(1), and one Br(2) atom. The Hg(1)-N(1) bond length is 2.54 Å. The Hg(1)-N(2) bond length is 2.48 Å. The Hg(1)-Br(1) bond length is 2.52 Å. The Hg(1)-Br(2) bond length is 2.56 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(2) atom. The C(5)-C(6) bond length is 1.49 Å. The C(5)-N(2) bond length is 1.35 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(1) atom. The C(6)-C(7) bond length is 1.49 Å. The C(6)-N(1) bond length is 1.28 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(6), and one C(8) atom. The C(7)-C(12) bond length is 1.40 Å. The C(7)-C(8) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(9) atom. The C(12)-H(9) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(10), and one H(11) atom. The C(13)-N(1) bond length is 1.45 Å. The C(13)-H(10) bond length is 1.10 Å. The C(13)-H(11) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Hg(1), one C(13), and one C(6) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Hg(1), one C(1), and one C(5) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Hg(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Hg(1) atom. In the HgC12H10(NBr)2 cluster, Hg(2) is bonded in a 5-coordinate geometry to one N(3), one N(4), one Br(4), and two equivalent Br(3) atoms. The Hg(2)-N(3) bond length is 2.34 Å. The Hg(2)-N(4) bond length is 2.46 Å. The Hg(2)-Br(4) bond length is 2.57 Å. There is one shorter (2.71 Å) and one longer (3.16 Å) Hg(2)-Br(3) bond length. There are twelve inequivalent C sites. In the first C site, C(14) is bonded in a distorted trigonal planar geometry to one C(15), one N(3), and one H(12) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-N(3) bond length is 1.34 Å. The C(14)-H(12) bond length is 1.09 Å. In the second C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(13) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(13) bond length is 1.09 Å. In the third C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(14) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(14) bond length is 1.09 Å. In the fourth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(15) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(15) bond length is 1.09 Å. In the fifth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one N(3) atom. The C(18)-C(19) bond length is 1.50 Å. The C(18)-N(3) bond length is 1.35 Å. In the sixth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one N(4) atom. The C(19)-C(20) bond length is 1.49 Å. The C(19)-N(4) bond length is 1.29 Å. In the seventh C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(25) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(25) bond length is 1.40 Å. In the eighth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(16) atom. The C(21)-H(16) bond length is 1.09 Å. In the ninth C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(18) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-H(18) bond length is 1.09 Å. In the tenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one C(25), and one H(19) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(19) bond length is 1.09 Å. In the eleventh C site, C(25) is bonded in a distorted single-bond geometry to one C(20), one C(24), and one H(20) atom. The C(25)-H(20) bond length is 1.09 Å. In the twelfth C site, C(26) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(21), and one H(22) atom. The C(26)-N(4) bond length is 1.44 Å. The C(26)-H(21) bond length is 1.10 Å. The C(26)-H(22) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Hg(2), one C(14), and one C(18) atom. In the second N site, N(4) is bonded in a distorted bent 120 degrees geometry to one Hg(2), one C(19), and one C(26) atom. There are ten inequivalent H sites. In the first H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the second H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the third H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(26) atom. There are two inequivalent Br sites. In the first Br site, Br(3) is bonded in a distorted L-shaped geometry to two equivalent Hg(2) atoms. In the second Br site, Br(4) is bonded in a single-bond geometry to one Hg(2) atom. Linkers: 2 [c]1[c]cc(/C(=N\CC/N=C(\c2ccccc2)c2ccccn2)c2ccccn2)cc1 ,2 [N][C]/C(=N/CC/N=C(\c1ccccc1)c1ccccn1)c1ccccc1 ,2 c1ccc(/C(=N\CC/N=C(\c2ccccc2)c2ccccn2)c2ccccn2)cc1 ,2 [CH]=C([N])/C(=N/CC/N=C(\c1ccccc1)c1ccccn1)c1ccccc1. Metal clusters: . The MOF has largest included sphere 2.06 A, density 2.65 g/cm3, surface area 2991.44 m2/g, accessible volume 0.09 cm3/g