CdC14H10(NO)4(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CdC14H10(NO)4 clusters. In each CdC14H10(NO)4 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.26 Å. The Cd(1)-N(2) bond length is 2.26 Å. The Cd(1)-O(1) bond length is 2.24 Å. The Cd(1)-O(2) bond length is 2.24 Å. The Cd(1)-O(3) bond length is 2.70 Å. The Cd(1)-O(4) bond length is 2.70 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(3) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(2)-O(2) bond length is 1.30 Å. The C(2)-O(4) bond length is 1.26 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(5) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-N(3) bond length is 1.36 Å. The C(5)-H(5) bond length is 1.08 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one N(2), one N(4), and one H(6) atom. The C(6)-N(2) bond length is 1.33 Å. The C(6)-N(4) bond length is 1.36 Å. The C(6)-H(6) bond length is 1.08 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(3), and one H(7) atom. The C(7)-C(9) bond length is 1.37 Å. The C(7)-N(3) bond length is 1.39 Å. The C(7)-H(7) bond length is 1.08 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(4), and one H(8) atom. The C(8)-C(10) bond length is 1.37 Å. The C(8)-N(4) bond length is 1.39 Å. The C(8)-H(8) bond length is 1.08 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(1), and one H(9) atom. The C(9)-N(1) bond length is 1.38 Å. The C(9)-H(9) bond length is 1.08 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(2), and one H(10) atom. The C(10)-N(2) bond length is 1.38 Å. The C(10)-H(10) bond length is 1.08 Å. In the ninth C site, C(11,12) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one N(3) atom. The C(11,12)-C(13) bond length is 1.40 Å. The C(11,12)-C(15) bond length is 1.40 Å. The C(11,12)-N(3) bond length is 1.43 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(11,12) and one H(11,12) atom. The C(13)-H(11,12) bond length is 1.09 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(11,12) and one H(11,12) atom. The C(14)-C(11,12) bond length is 1.40 Å. The C(14)-H(11,12) bond length is 1.09 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(11,12) and one H(13,14) atom. The C(15)-H(13,14) bond length is 1.09 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(11,12) and one H(13,14) atom. The C(16)-C(11,12) bond length is 1.40 Å. The C(16)-H(13,14) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(5), and one C(9) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(11,12); one C(5); and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(11,12); one C(6); and one C(8) atom. The N(4)-C(11,12) bond length is 1.42 Å. There are eight inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(13,14) is bonded in a single-bond geometry to one C(15) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cd(1) and one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cd(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cd(1) and one C(2) atom. Linkers: 2 c1cn(-c2ccc(-n3ccnc3)cc2)cn1 ,2 [O]C(=O)CCC([O])=O. Metal clusters: 2 O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 1.87 A, density 1.80 g/cm3, surface area 4160.20 m2/g, accessible volume 0.13 cm3/g