(CH)2ZnC4H8S2(NO)4 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two ZnC4H8S2(NO)4 clusters. In each ZnC4H8S2(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one O(1), and one O(3) atom. The Zn(1)-S(1) bond length is 2.33 Å. The Zn(1)-S(2) bond length is 2.34 Å. The Zn(1)-O(1) bond length is 2.01 Å. The Zn(1)-O(3) bond length is 1.99 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-S(1) bond length is 1.73 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(3), one N(4), and one S(2) atom. The C(2)-N(3) bond length is 1.33 Å. The C(2)-N(4) bond length is 1.34 Å. The C(2)-S(2) bond length is 1.72 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(3)-O(1) bond length is 1.30 Å. The C(3)-O(2) bond length is 1.26 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(5)-O(3) bond length is 1.30 Å. The C(5)-O(4) bond length is 1.25 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.01 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. The N(2)-H(3) bond length is 1.03 Å. The N(2)-H(4) bond length is 1.03 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(2), one H(5), and one H(6) atom. The N(3)-H(5) bond length is 1.02 Å. The N(3)-H(6) bond length is 1.02 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(2), one H(7), and one H(8) atom. The N(4)-H(7) bond length is 1.02 Å. The N(4)-H(8) bond length is 1.01 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Zn(1) and one C(2) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(5) atom. Linkers: 2 [O]C(=O)/C=C/C([O])=O. Metal clusters: 2 [Zn]. The MOF has largest included sphere 3.06 A, density 1.67 g/cm3, surface area 4529.43 m2/g, accessible volume 0.17 cm3/g