AgC6H12S3O4Cl is Indium-like structured and crystallizes in the trigonal R-3m space group. The structure is zero-dimensional and consists of six AgC6H12S3O4Cl clusters. Ag(1) is bonded to three equivalent S(1) and one O(1) atom to form AgS3O tetrahedra that share  a cornercorner with one Cl(1)O4 tetrahedra. All Ag(1)-S(1) bond lengths are 2.49 Å. The Ag(1)-O(1) bond length is 2.63 Å. C(1) is bonded in a distorted water-like geometry to one H(1), one H(2), and one S(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.82 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1) and two equivalent C(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Ag(1) and one Cl(1) atom. The O(1)-Cl(1) bond length is 1.48 Å. In the second O site, O(2) is bonded in a single-bond geometry to one Cl(1) atom. The O(2)-Cl(1) bond length is 1.46 Å. Cl(1) is bonded to one O(1) and three equivalent O(2) atoms to form ClO4 tetrahedra that share  a cornercorner with one Ag(1)S3O tetrahedra. Linkers: 3 C1CSCCS1. Metal clusters: 2 [Ag].[O].[O].[O].[O]Cl. The MOF has largest included sphere 1.61 A, density 2.24 g/cm3, surface area 3383.24 m2/g, accessible volume 0.08 cm3/g