Zn2C27H17(N2O5)2(CH)5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules and two Zn2C27H17(N2O5)2 clusters. In each Zn2C27H17(N2O5)2 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted octahedral geometry to one N(2), one N(4), one O(1), one O(3), one O(4), and one O(5) atom. The Zn(1)-N(2) bond length is 2.16 Å. The Zn(1)-N(4) bond length is 2.17 Å. The Zn(1)-O(1) bond length is 2.27 Å. The Zn(1)-O(3) bond length is 2.11 Å. The Zn(1)-O(4) bond length is 2.24 Å. The Zn(1)-O(5) bond length is 1.99 Å. In the second Zn site, Zn(2) is bonded in a 6-coordinate geometry to one N(1), one N(3), one O(2), one O(4), one O(6), and one O(7) atom. The Zn(2)-N(1) bond length is 2.18 Å. The Zn(2)-N(3) bond length is 2.12 Å. The Zn(2)-O(2) bond length is 2.02 Å. The Zn(2)-O(4) bond length is 2.16 Å. The Zn(2)-O(6) bond length is 2.50 Å. The Zn(2)-O(7) bond length is 2.16 Å. There are twenty-seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(5) atom. The C(1)-O(10) bond length is 1.25 Å. The C(1)-O(5) bond length is 1.29 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(8) atom. The C(2)-O(2) bond length is 1.29 Å. The C(2)-O(8) bond length is 1.26 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. The C(3)-O(4) bond length is 1.29 Å. The C(3)-O(6) bond length is 1.25 Å. In the fourth C site, C(5) is bonded in a distorted water-like geometry to one H(3) and one O(1) atom. The C(5)-H(3) bond length is 1.10 Å. The C(5)-O(1) bond length is 1.45 Å. In the fifth C site, C(6) is bonded in a distorted water-like geometry to one H(4) and one O(1) atom. The C(6)-H(4) bond length is 1.10 Å. The C(6)-O(1) bond length is 1.45 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(11), one C(14), and one N(1) atom. The C(7)-C(11) bond length is 1.44 Å. The C(7)-C(14) bond length is 1.42 Å. The C(7)-N(1) bond length is 1.35 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(12), one C(19), and one N(2) atom. The C(9)-C(12) bond length is 1.44 Å. The C(9)-C(19) bond length is 1.42 Å. The C(9)-N(2) bond length is 1.36 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(9) atom. The C(10)-O(3) bond length is 1.28 Å. The C(10)-O(9) bond length is 1.26 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(17), one C(7), and one N(3) atom. The C(11)-C(17) bond length is 1.42 Å. The C(11)-N(3) bond length is 1.36 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one N(4) atom. The C(12)-C(13) bond length is 1.42 Å. The C(12)-N(4) bond length is 1.36 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(28), and one C(31) atom. The C(13)-C(28) bond length is 1.43 Å. The C(13)-C(31) bond length is 1.41 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one C(23), one C(24), and one C(7) atom. The C(14)-C(23) bond length is 1.43 Å. The C(14)-C(24) bond length is 1.41 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(17) and one H(6) atom. The C(15)-C(17) bond length is 1.43 Å. The C(15)-H(6) bond length is 1.09 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(7) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-H(7) bond length is 1.09 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(16) atom. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19), one C(30), and one H(8) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-C(30) bond length is 1.38 Å. The C(18)-H(8) bond length is 1.09 Å. In the seventeenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(27), and one C(9) atom. The C(19)-C(27) bond length is 1.43 Å. In the eighteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(9) atom. The C(20)-N(4) bond length is 1.33 Å. The C(20)-H(9) bond length is 1.09 Å. In the nineteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one N(1) and one H(10) atom. The C(21)-N(1) bond length is 1.33 Å. The C(21)-H(10) bond length is 1.09 Å. In the twentieth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(11) atom. The C(22)-N(2) bond length is 1.33 Å. The C(22)-H(11) bond length is 1.09 Å. In the twenty-first C site, C(23) is bonded in a distorted single-bond geometry to one C(14) and one H(12) atom. The C(23)-H(12) bond length is 1.09 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(14) and one H(13) atom. The C(24)-H(13) bond length is 1.09 Å. In the twenty-third C site, C(26) is bonded in a distorted trigonal planar geometry to one N(3) and one H(15) atom. The C(26)-N(3) bond length is 1.33 Å. The C(26)-H(15) bond length is 1.09 Å. In the twenty-fourth C site, C(27) is bonded in a distorted single-bond geometry to one C(19) and one H(16) atom. The C(27)-H(16) bond length is 1.09 Å. In the twenty-fifth C site, C(28) is bonded in a distorted single-bond geometry to one C(13) and one H(17) atom. The C(28)-H(17) bond length is 1.09 Å. In the twenty-sixth C site, C(30) is bonded in a distorted single-bond geometry to one C(18) and one H(19) atom. The C(30)-H(19) bond length is 1.09 Å. In the twenty-seventh C site, C(31) is bonded in a distorted single-bond geometry to one C(13) and one H(20) atom. The C(31)-H(20) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(21), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(22), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(11), and one C(26) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(12), and one C(20) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(7) and one O(8) atom. The H(1)-O(7) bond length is 1.03 Å. The H(1)-O(8) bond length is 1.54 Å. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(24) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(28) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(30) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(31) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one O(7) atom. The H(22)-O(7) bond length is 0.98 Å. There are ten inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(6) is bonded in a single-bond geometry to one Zn(2) and one C(3) atom. In the third O site, O(7) is bonded in a distorted water-like geometry to one Zn(2), one H(1), and one H(22) atom. In the fourth O site, O(8) is bonded in a water-like geometry to one C(2) and one H(1) atom. In the fifth O site, O(9) is bonded in a single-bond geometry to one C(10) atom. In the sixth O site, O(10) is bonded in a single-bond geometry to one C(1) atom. In the seventh O site, O(1) is bonded in a trigonal non-coplanar geometry to one Zn(1), one C(5), and one C(6) atom. In the eighth O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(2) atom. In the ninth O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(10) atom. In the tenth O site, O(4) is bonded in a 3-coordinate geometry to one Zn(1), one Zn(2), and one C(3) atom. Linkers: 2 [O]C(=O)[C@@H]1[C@H](C([O])=O)[C@@H](C([O])=O)O[C@H]1C([O])=O. Metal clusters: 4 [Zn]. The MOF has largest included sphere 3.28 A, density 1.68 g/cm3, surface area 4112.57 m2/g, accessible volume 0.14 cm3/g