ZnC13NH9O5 crystallizes in the triclinic P-1 space group. Zn(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(5) atom. The Zn(1)-N(1) bond length is 2.02 Å. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(2) bond length is 1.96 Å. The Zn(1)-O(3) bond length is 2.41 Å. The Zn(1)-O(5) bond length is 2.11 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(8) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(8) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.51 Å. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(5)-O(3) bond length is 1.27 Å. The C(5)-O(4) bond length is 1.28 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4), one C(7), and one H(4) atom. The C(6)-C(7) bond length is 1.41 Å. The C(6)-H(4) bond length is 1.09 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(7), and one C(8) atom. The C(7)-C(7) bond length is 1.49 Å. The C(7)-C(8) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(2), one C(7), and one H(5) atom. The C(8)-H(5) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(6) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(6) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(7) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(7) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(12) atom. The C(11)-C(11) bond length is 1.48 Å. The C(11)-C(12) bond length is 1.41 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(8) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-H(8) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one N(1), and one H(9) atom. The C(13)-N(1) bond length is 1.35 Å. The C(13)-H(9) bond length is 1.09 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(9) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(4) and one O(5) atom. The H(1)-O(4) bond length is 1.66 Å. The H(1)-O(5) bond length is 1.02 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) and one O(5) atom. The H(2)-O(4) bond length is 1.71 Å. The H(2)-O(5) bond length is 1.00 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one C(5), one H(1), and one H(2) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Zn(1), one H(1), and one H(2) atom. Linkers: 1 [O]C(=O)c1cc(C([O])=O)cc(-c2cc(C([O])=O)cc(C([O])=O)c2)c1 ,1 c1cc(-c2ccncc2)ccn1. Metal clusters: 1 O.O.[C]1O[Zn]O[C]O[Zn]O1.[O][C]=O.[O][C]=O. RCSR code: sql. The MOF has largest included sphere 2.00 A, density 1.93 g/cm3, surface area 3660.96 m2/g, accessible volume 0.07 cm3/g