CHPbC9N5H10S2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and one PbC9N5H10S2 cluster. In the PbC9N5H10S2 cluster, Pb(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one S(2), and two equivalent S(1) atoms. The Pb(1)-N(1) bond length is 2.54 Å. The Pb(1)-N(2) bond length is 2.50 Å. The Pb(1)-S(2) bond length is 2.97 Å. There is one shorter (2.77 Å) and one longer (3.01 Å) Pb(1)-S(1) bond length. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.47 Å. The C(1)-N(1) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(2)-H(4) bond length is 1.09 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2) bond length is 1.09 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(3) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(3) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.50 Å. The C(6)-N(2) bond length is 1.32 Å. In the sixth C site, C(7) is bonded in a trigonal non-coplanar geometry to one C(6), one H(6), one H(7), and one H(8) atom. The C(7)-H(6) bond length is 1.09 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(8) bond length is 1.10 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one N(3), one N(4), and one S(1) atom. The C(8)-N(3) bond length is 1.33 Å. The C(8)-N(4) bond length is 1.34 Å. The C(8)-S(1) bond length is 1.76 Å. In the eighth C site, C(9) is bonded in a tetrahedral geometry to one N(4), one H(10), one H(11), and one H(9) atom. The C(9)-N(4) bond length is 1.45 Å. The C(9)-H(10) bond length is 1.10 Å. The C(9)-H(11) bond length is 1.10 Å. The C(9)-H(9) bond length is 1.10 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one N(5) and one S(2) atom. The C(10)-N(5) bond length is 1.18 Å. The C(10)-S(2) bond length is 1.64 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Pb(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Pb(1), one C(6), and one N(3) atom. The N(2)-N(3) bond length is 1.34 Å. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one C(8) and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(8), one C(9), and one H(1) atom. The N(4)-H(1) bond length is 1.03 Å. In the fifth N site, N(5) is bonded in a single-bond geometry to one C(10) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Pb(1) and one C(8) atom. In the second S site, S(2) is bonded in a distorted water-like geometry to one Pb(1) and one C(10) atom. Linkers: 2 CNC(=S)[N]/N=C(\C)c1ccccn1. Metal clusters: 2 [Pb]. The MOF has largest included sphere 1.78 A, density 2.37 g/cm3, surface area 3145.44 m2/g, accessible volume 0.09 cm3/g