Cd2C22N3H19O10(CH)4(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four 02329_fluka molecules, and one Cd2C22N3H19O10 cluster. In the Cd2C22N3H19O10 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(5), and one O(6) atom. The Cd(1)-N(1) bond length is 2.35 Å. The Cd(1)-N(2) bond length is 2.39 Å. The Cd(1)-O(1) bond length is 2.29 Å. The Cd(1)-O(5) bond length is 2.33 Å. The Cd(1)-O(6) bond length is 2.24 Å. In the second Cd site, Cd(2) is bonded in a distorted octahedral geometry to one N(3), one O(2), one O(4), one O(7), one O(8), and one O(9) atom. The Cd(2)-N(3) bond length is 2.38 Å. The Cd(2)-O(2) bond length is 2.37 Å. The Cd(2)-O(4) bond length is 2.33 Å. The Cd(2)-O(7) bond length is 2.34 Å. The Cd(2)-O(8) bond length is 2.48 Å. The Cd(2)-O(9) bond length is 2.26 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(5) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(5) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(6) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(6) bond length is 1.09 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.50 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(7) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(7) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(8) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(8) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(9) atom. The C(6)-H(9) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(10) atom. The C(7)-C(8) bond length is 1.50 Å. The C(7)-H(10) bond length is 1.10 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(11) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(11) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(12) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(12) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(13) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(13) bond length is 1.09 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(8) and one H(14) atom. The C(12)-H(14) bond length is 1.09 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one H(15) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-N(3) bond length is 1.35 Å. The C(13)-H(15) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(16) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-H(16) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-C(18) bond length is 1.45 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(17) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(17) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(3), and one H(18) atom. The C(17)-N(3) bond length is 1.34 Å. The C(17)-H(18) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(15) and one H(19) atom. The C(18)-H(19) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(19)-O(1) bond length is 1.28 Å. The C(19)-O(3) bond length is 1.27 Å. In the twentieth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(26)-O(5) bond length is 1.27 Å. The C(26)-O(6) bond length is 1.27 Å. In the twenty-first C site, C(27) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(27)-O(7) bond length is 1.27 Å. The C(27)-O(8) bond length is 1.28 Å. In the twenty-second C site, C(28) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(28)-O(10) bond length is 1.26 Å. The C(28)-O(9) bond length is 1.29 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(11) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(2), one C(13), and one C(17) atom. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.99 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(3) and one O(4) atom. The H(3)-O(3) bond length is 1.63 Å. The H(3)-O(4) bond length is 1.01 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(4) atom. The H(4)-O(4) bond length is 0.98 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(16) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(18) atom. There are ten inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(26) atom. In the second O site, O(6) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(26) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Cd(2) and one C(27) atom. In the fourth O site, O(8) is bonded in a distorted single-bond geometry to one Cd(2) and one C(27) atom. In the fifth O site, O(9) is bonded in a distorted water-like geometry to one Cd(2) and one C(28) atom. In the sixth O site, O(10) is bonded in a distorted single-bond geometry to one C(28) atom. In the seventh O site, O(1) is bonded in a distorted water-like geometry to one Cd(1) and one C(19) atom. In the eighth O site, O(2) is bonded in a distorted water-like geometry to one Cd(2), one H(1), and one H(2) atom. In the ninth O site, O(3) is bonded in a distorted water-like geometry to one C(19) and one H(3) atom. In the tenth O site, O(4) is bonded in a distorted water-like geometry to one Cd(2), one H(3), and one H(4) atom. Linkers: 2 [O]C(=O)[C@H]1C[C@@H](C([O])=O)[C@@H](C([O])=O)C[C@H]1C([O])=O ,1 c1cc([C@H]2[C@H](c3ccncc3)[C@H](c3ccncc3)[C@H]2c2ccncc2)ccn1 ,1 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 1 O=[C]O[Cd]1O[C]O[Cd](O[C]=O)O[C]O1 ,2 O.O.O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 3.88 A, density 1.61 g/cm3, surface area 3753.02 m2/g, accessible volume 0.18 cm3/g