(CH2)10Cu4C14N2H16S2OI4CH2CO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty 02329_fluka molecules, two dimethyl ether molecules, and two Cu4C14N2H16S2OI4 clusters. In each Cu4C14N2H16S2OI4 cluster, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 4-coordinate geometry to one Cu(2), one S(1), one I(1), one I(3), and one I(4) atom. The Cu(1)-Cu(2) bond length is 2.59 Å. The Cu(1)-S(1) bond length is 2.27 Å. The Cu(1)-I(1) bond length is 2.72 Å. The Cu(1)-I(3) bond length is 2.72 Å. The Cu(1)-I(4) bond length is 2.68 Å. In the second Cu site, Cu(2) is bonded in a 7-coordinate geometry to one Cu(1), one Cu(3), one Cu(4), one S(2), one I(2), one I(3), and one I(4) atom. The Cu(2)-Cu(3) bond length is 2.57 Å. The Cu(2)-Cu(4) bond length is 2.58 Å. The Cu(2)-S(2) bond length is 2.26 Å. The Cu(2)-I(2) bond length is 2.79 Å. The Cu(2)-I(3) bond length is 2.71 Å. The Cu(2)-I(4) bond length is 2.73 Å. In the third Cu site, Cu(3) is bonded in a distorted single-bond geometry to one Cu(2), one N(1), one I(1), one I(2), and one I(3) atom. The Cu(3)-N(1) bond length is 2.02 Å. The Cu(3)-I(1) bond length is 2.64 Å. The Cu(3)-I(2) bond length is 2.69 Å. The Cu(3)-I(3) bond length is 2.72 Å. In the fourth Cu site, Cu(4) is bonded in a distorted single-bond geometry to one Cu(2), one N(2), one I(1), one I(2), and one I(4) atom. The Cu(4)-N(2) bond length is 2.01 Å. The Cu(4)-I(1) bond length is 2.82 Å. The Cu(4)-I(2) bond length is 2.67 Å. The Cu(4)-I(4) bond length is 2.71 Å. There are fourteen inequivalent C sites. In the first C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one H(35) atom. The C(23)-C(22) bond length is 1.40 Å. The C(23)-C(24) bond length is 1.38 Å. The C(23)-H(35) bond length is 1.09 Å. In the second C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one N(2), and one H(36) atom. The C(24)-N(2) bond length is 1.35 Å. The C(24)-H(36) bond length is 1.09 Å. In the third C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one N(2), and one H(37) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-N(2) bond length is 1.35 Å. The C(25)-H(37) bond length is 1.09 Å. In the fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(22), one C(25), and one H(38) atom. The C(26)-C(22) bond length is 1.40 Å. The C(26)-H(38) bond length is 1.09 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one H(11) and one S(1) atom. The C(6)-H(11) bond length is 1.11 Å. The C(6)-S(1) bond length is 1.84 Å. In the sixth C site, C(7) is bonded in a distorted water-like geometry to one H(12), one H(13), and one S(1) atom. The C(7)-H(12) bond length is 1.10 Å. The C(7)-H(13) bond length is 1.10 Å. The C(7)-S(1) bond length is 1.81 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(16) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-H(16) bond length is 1.09 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(17) atom. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(17) bond length is 1.09 Å. In the ninth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one N(1), and one H(18) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-N(1) bond length is 1.34 Å. The C(12)-H(18) bond length is 1.09 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(19) atom. The C(13)-H(19) bond length is 1.09 Å. In the eleventh C site, C(19) is bonded in a distorted single-bond geometry to one H(30) and one S(2) atom. The C(19)-H(30) bond length is 1.10 Å. The C(19)-S(2) bond length is 1.83 Å. In the twelfth C site, C(20) is bonded in a distorted water-like geometry to one H(31), one H(32), and one S(2) atom. The C(20)-H(31) bond length is 1.10 Å. The C(20)-H(32) bond length is 1.10 Å. The C(20)-S(2) bond length is 1.81 Å. In the thirteenth C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one H(33), one H(34), and one O(2) atom. The C(21)-H(33) bond length is 1.10 Å. The C(21)-H(34) bond length is 1.10 Å. The C(21)-O(2) bond length is 1.45 Å. In the fourteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(23), one C(26), and one O(2) atom. The C(22)-O(2) bond length is 1.35 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(3), one C(11), and one C(12) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(4), one C(24), and one C(25) atom. There are sixteen inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(30) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(31) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(32) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(33) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(34) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(35) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(36) is bonded in a single-bond geometry to one C(24) atom. In the fifteenth H site, H(37) is bonded in a single-bond geometry to one C(25) atom. In the sixteenth H site, H(38) is bonded in a single-bond geometry to one C(26) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Cu(1), one C(6), and one C(7) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Cu(2), one C(19), and one C(20) atom. O(2) is bonded in a bent 120 degrees geometry to one C(21) and one C(22) atom. There are four inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(3), and one Cu(4) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one Cu(2), one Cu(3), and one Cu(4) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(2), and one Cu(3) atom. In the fourth I site, I(4) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(2), and one Cu(4) atom. Linkers: 4 c1cc(OCCSC2CCCCC2)ccn1. Metal clusters: 8 [Cu]. The MOF has largest included sphere 4.60 A, density 2.11 g/cm3, surface area 3245.57 m2/g, accessible volume 0.16 cm3/g