Cu2C17H18(NO)6(CH3)2 crystallizes in the monoclinic C2 space group. The structure consists of sixteen 02329_fluka molecules inside a Cu2C17H18(NO)6 framework. In the Cu2C17H18(NO)6 framework, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square pyramidal geometry to one N(1), one N(9), one O(2), one O(7), and one O(9) atom. The Cu(1)-N(1) bond length is 1.92 Å. The Cu(1)-N(9) bond length is 1.95 Å. The Cu(1)-O(2) bond length is 2.05 Å. The Cu(1)-O(7) bond length is 2.30 Å. The Cu(1)-O(9) bond length is 2.02 Å. In the second Cu site, Cu(2) is bonded in a square pyramidal geometry to one N(10); one N(2,4); one O(1,4); one O(10); and one O(5,8) atom. The Cu(2)-N(10) bond length is 1.95 Å. The Cu(2)-N(2,4) bond length is 1.92 Å. The Cu(2)-O(1,4) bond length is 2.05 Å. The Cu(2)-O(10) bond length is 2.02 Å. The Cu(2)-O(5,8) bond length is 2.30 Å. In the third Cu site, Cu(3) is bonded in a square pyramidal geometry to one N(11), one N(3), one O(11), one O(3), and one O(6) atom. The Cu(3)-N(11) bond length is 1.95 Å. The Cu(3)-N(3) bond length is 1.92 Å. The Cu(3)-O(11) bond length is 2.02 Å. The Cu(3)-O(3) bond length is 2.06 Å. The Cu(3)-O(6) bond length is 2.31 Å. In the fourth Cu site, Cu(4) is bonded in a square pyramidal geometry to one N(12); one N(2,4); one O(1,4); one O(12); and one O(5,8) atom. The Cu(4)-N(12) bond length is 1.95 Å. The Cu(4)-N(2,4) bond length is 1.92 Å. The Cu(4)-O(1,4) bond length is 2.05 Å. The Cu(4)-O(12) bond length is 2.02 Å. The Cu(4)-O(5,8) bond length is 2.30 Å. There are twenty-three inequivalent C sites. In the first C site, C(25,26,27) is bonded in a distorted water-like geometry to two equivalent C(5,8) and two equivalent H(45,46,47,48) atoms. Both C(25,26,27)-C(5,8) bond lengths are 1.51 Å. Both C(25,26,27)-H(45,46,47,48) bond lengths are 1.10 Å. In the second C site, C(28,31) is bonded in a distorted trigonal non-coplanar geometry to one C(17); one H(13,14,15,16); one H(17,18,19,20); and one H(9,10,11,12) atom. The C(28,31)-C(17) bond length is 1.49 Å. The C(28,31)-H(13,14,15,16) bond length is 1.10 Å. The C(28,31)-H(17,18,19,20) bond length is 1.10 Å. The C(28,31)-H(9,10,11,12) bond length is 1.09 Å. In the third C site, C(29,30) is bonded in a distorted trigonal non-coplanar geometry to one C(18); one H(13,14,15,16); one H(17,18,19,20); and one H(9,10,11,12) atom. The C(29,30)-C(18) bond length is 1.49 Å. The C(29,30)-H(13,14,15,16) bond length is 1.10 Å. The C(29,30)-H(17,18,19,20) bond length is 1.10 Å. The C(29,30)-H(9,10,11,12) bond length is 1.09 Å. In the fourth C site, C(32,33,34,35) is bonded in a distorted trigonal non-coplanar geometry to one C(21,24); one H(21,22,23,24); one H(25,26,27,28); and one H(29,30,31,32) atom. The C(32,33,34,35)-C(21,24) bond length is 1.49 Å. The C(32,33,34,35)-H(21,22,23,24) bond length is 1.10 Å. The C(32,33,34,35)-H(25,26,27,28) bond length is 1.10 Å. The C(32,33,34,35)-H(29,30,31,32) bond length is 1.10 Å. In the fifth C site, C(1,4) is bonded in a 2-coordinate geometry to one N(1) and one H(1,2,4) atom. The C(1,4)-N(1) bond length is 1.44 Å. The C(1,4)-H(1,2,4) bond length is 1.10 Å. In the sixth C site, C(2) is bonded in a 2-coordinate geometry to one N(2,4) and one H(1,2,4) atom. The C(2)-N(2,4) bond length is 1.44 Å. The C(2)-H(1,2,4) bond length is 1.10 Å. In the seventh C site, C(3) is bonded in a 2-coordinate geometry to one N(3) and one H(3) atom. The C(3)-N(3) bond length is 1.45 Å. The C(3)-H(3) bond length is 1.10 Å. In the eighth C site, C(5,8) is bonded in a trigonal planar geometry to one C(17); one C(21,24); and one C(25,26,27) atom. The C(5,8)-C(17) bond length is 1.40 Å. The C(5,8)-C(21,24) bond length is 1.41 Å. In the ninth C site, C(6,7) is bonded in a trigonal planar geometry to one C(18); one C(22); and one C(25,26,27) atom. The C(6,7)-C(18) bond length is 1.40 Å. The C(6,7)-C(22) bond length is 1.41 Å. The C(6,7)-C(25,26,27) bond length is 1.51 Å. In the tenth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(5,8) and one O(9) atom. The C(9)-O(5,8) bond length is 1.25 Å. The C(9)-O(9) bond length is 1.30 Å. In the eleventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(6) atom. The C(10)-O(10) bond length is 1.30 Å. The C(10)-O(6) bond length is 1.25 Å. In the twelfth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(7) atom. The C(11)-O(11) bond length is 1.30 Å. The C(11)-O(7) bond length is 1.25 Å. In the thirteenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(12) and one O(5,8) atom. The C(12)-O(12) bond length is 1.30 Å. The C(12)-O(5,8) bond length is 1.25 Å. In the fourteenth C site, C(13,16) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(1,4) atom. The C(13,16)-N(1) bond length is 1.31 Å. The C(13,16)-O(1,4) bond length is 1.28 Å. In the fifteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(2,4) and one O(2) atom. The C(14)-N(2,4) bond length is 1.31 Å. The C(14)-O(2) bond length is 1.28 Å. In the sixteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one O(3) atom. The C(15)-N(3) bond length is 1.31 Å. The C(15)-O(3) bond length is 1.28 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(28,31); one C(5,8); and one N(5) atom. The C(17)-N(5) bond length is 1.36 Å. In the eighteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(29,30); one C(6,7); and one N(6) atom. The C(18)-N(6) bond length is 1.36 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(29,30); one C(6,7); and one N(7) atom. The C(19)-C(29,30) bond length is 1.49 Å. The C(19)-C(6,7) bond length is 1.40 Å. The C(19)-N(7) bond length is 1.36 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(28,31); one C(5,8); and one N(8) atom. The C(20)-C(28,31) bond length is 1.49 Å. The C(20)-C(5,8) bond length is 1.40 Å. The C(20)-N(8) bond length is 1.36 Å. In the twenty-first C site, C(21,24) is bonded in a distorted trigonal planar geometry to one C(32,33,34,35); one C(5,8); and one N(9) atom. The C(21,24)-N(9) bond length is 1.35 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(32,33,34,35); one C(6,7); and one N(10) atom. The C(22)-C(32,33,34,35) bond length is 1.49 Å. The C(22)-N(10) bond length is 1.35 Å. In the twenty-third C site, C(23) is bonded in a distorted trigonal planar geometry to one C(32,33,34,35); one C(6,7); and one N(11) atom. The C(23)-C(32,33,34,35) bond length is 1.49 Å. The C(23)-C(6,7) bond length is 1.41 Å. The C(23)-N(11) bond length is 1.35 Å. There are eleven inequivalent N sites. In the first N site, N(11) is bonded in a distorted trigonal planar geometry to one Cu(3), one C(23), and one N(7) atom. The N(11)-N(7) bond length is 1.35 Å. In the second N site, N(9) is bonded in a distorted trigonal planar geometry to one Cu(1); one C(21,24); and one N(5) atom. The N(9)-N(5) bond length is 1.35 Å. In the third N site, N(1) is bonded in a trigonal planar geometry to one Cu(1); one C(1,4); and one C(13,16) atom. In the fourth N site, N(2,4) is bonded in a trigonal planar geometry to one Cu(2), one C(14), and one C(2) atom. In the fifth N site, N(3) is bonded in a trigonal planar geometry to one Cu(3), one C(15), and one C(3) atom. In the sixth N site, N(10) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(22), and one N(6) atom. The N(10)-N(6) bond length is 1.35 Å. In the seventh N site, N(5) is bonded in a 2-coordinate geometry to one C(17), one N(9), and one H(5) atom. The N(5)-H(5) bond length is 1.04 Å. In the eighth N site, N(6) is bonded in a 2-coordinate geometry to one C(18), one N(10), and one H(6) atom. The N(6)-H(6) bond length is 1.04 Å. In the ninth N site, N(7) is bonded in a 2-coordinate geometry to one C(19), one N(11), and one H(7) atom. The N(7)-H(7) bond length is 1.04 Å. In the tenth N site, N(8) is bonded in a 2-coordinate geometry to one C(20), one N(12), and one H(8) atom. The N(8)-N(12) bond length is 1.35 Å. The N(8)-H(8) bond length is 1.04 Å. In the eleventh N site, N(12) is bonded in a distorted trigonal planar geometry to one Cu(4); one C(21,24); and one N(8) atom. The N(12)-C(21,24) bond length is 1.35 Å. There are thirteen inequivalent H sites. In the first H site, H(1,2,4) is bonded in a single-bond geometry to one C(1,4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5) is bonded in a distorted single-bond geometry to one N(5) and one O(11) atom. The H(5)-O(11) bond length is 1.73 Å. In the fourth H site, H(6) is bonded in a distorted single-bond geometry to one N(6) and one O(12) atom. The H(6)-O(12) bond length is 1.73 Å. In the fifth H site, H(7) is bonded in a distorted single-bond geometry to one N(7) and one O(10) atom. The H(7)-O(10) bond length is 1.73 Å. In the sixth H site, H(8) is bonded in a distorted single-bond geometry to one N(8) and one O(9) atom. The H(8)-O(9) bond length is 1.73 Å. In the seventh H site, H(9,10,11,12) is bonded in a single-bond geometry to one C(28,31) atom. In the eighth H site, H(13,14,15,16) is bonded in a single-bond geometry to one C(28,31) atom. In the ninth H site, H(17,18,19,20) is bonded in a single-bond geometry to one C(28,31) atom. In the tenth H site, H(21,22,23,24) is bonded in a single-bond geometry to one C(32,33,34,35) atom. In the eleventh H site, H(25,26,27,28) is bonded in a single-bond geometry to one C(32,33,34,35) atom. In the twelfth H site, H(29,30,31,32) is bonded in a single-bond geometry to one C(32,33,34,35) atom. In the thirteenth H site, H(45,46,47,48) is bonded in a single-bond geometry to one C(25,26,27) atom. There are ten inequivalent O sites. In the first O site, O(1,4) is bonded in a water-like geometry to one Cu(2) and one C(13,16) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cu(1) and one C(14) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cu(3) and one C(15) atom. In the fourth O site, O(5,8) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one C(9) atom. In the fifth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one C(10) atom. In the sixth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(11) atom. In the seventh O site, O(9) is bonded in a 3-coordinate geometry to one Cu(1), one C(9), and one H(8) atom. In the eighth O site, O(10) is bonded in a 3-coordinate geometry to one Cu(2), one C(10), and one H(7) atom. In the ninth O site, O(11) is bonded in a 3-coordinate geometry to one Cu(3), one C(11), and one H(5) atom. In the tenth O site, O(12) is bonded in a 3-coordinate geometry to one Cu(4), one C(12), and one H(6) atom. Linkers: 4 C[C@H]([N]C(=O)C(=O)[N][C@@H](C)C([O])=O)C([O])=O ,4 Cc1n[nH]c(C)c1Cc1c(C)n[nH]c1C. Metal clusters: 8 [Cu]. The MOF has largest included sphere 3.67 A, density 1.36 g/cm3, surface area 4628.97 m2/g, accessible volume 0.27 cm3/g