CuC16H14(NO)4(CH3)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CuC16H14(NO)4 clusters. In one of the CuC16H14(NO)4 clusters, Cu(1) is bonded in a square co-planar geometry to one N(1), one N(4), one O(1), and one O(3) atom. The Cu(1)-N(1) bond length is 1.99 Å. The Cu(1)-N(4) bond length is 1.99 Å. The Cu(1)-O(1) bond length is 1.99 Å. The Cu(1)-O(3) bond length is 2.00 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(3)-O(3) bond length is 1.30 Å. The C(3)-O(4) bond length is 1.25 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(7) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-N(2) bond length is 1.35 Å. The C(5)-H(7) bond length is 1.08 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(2), and one H(8) atom. The C(6)-C(7) bond length is 1.37 Å. The C(6)-N(2) bond length is 1.38 Å. The C(6)-H(8) bond length is 1.08 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one H(9) atom. The C(7)-N(1) bond length is 1.38 Å. The C(7)-H(9) bond length is 1.08 Å. In the sixth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one N(2), one H(10), and one H(11) atom. The C(8)-C(9) bond length is 1.51 Å. The C(8)-N(2) bond length is 1.47 Å. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(11) bond length is 1.10 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.40 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(12,14) atom. The C(10)-H(12,14) bond length is 1.09 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(13,15) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(13,15) bond length is 1.09 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(15) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(15) bond length is 1.51 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(12,14) atom. The C(13)-H(12,14) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(13,15) atom. The C(14)-H(13,15) bond length is 1.09 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one C(12), one N(3), one H(16), and one H(17) atom. The C(15)-N(3) bond length is 1.47 Å. The C(15)-H(16) bond length is 1.10 Å. The C(15)-H(17) bond length is 1.10 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(18) atom. The C(16)-N(3) bond length is 1.35 Å. The C(16)-N(4) bond length is 1.34 Å. The C(16)-H(18) bond length is 1.08 Å. In the fifteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(4), and one H(19) atom. The C(17)-C(18) bond length is 1.37 Å. The C(17)-N(4) bond length is 1.38 Å. The C(17)-H(19) bond length is 1.08 Å. In the sixteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(3), and one H(20) atom. The C(18)-N(3) bond length is 1.38 Å. The C(18)-H(20) bond length is 1.08 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(5), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(18) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(16), and one C(17) atom. There are twelve inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(12,14) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(13,15) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cu(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(3) atom. In one of the CuC16H14(NO)4 clusters, Cu(2) is bonded in a rectangular see-saw-like geometry to one N(5), one N(8), one O(5), and one O(7) atom. The Cu(2)-N(5) bond length is 1.97 Å. The Cu(2)-N(8) bond length is 1.97 Å. The Cu(2)-O(5) bond length is 1.99 Å. The Cu(2)-O(7) bond length is 1.99 Å. There are sixteen inequivalent C sites. In the first C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(19)-O(5) bond length is 1.30 Å. The C(19)-O(6) bond length is 1.26 Å. In the second C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(21)-O(7) bond length is 1.30 Å. The C(21)-O(8) bond length is 1.26 Å. In the third C site, C(23) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(27) atom. The C(23)-N(5) bond length is 1.34 Å. The C(23)-N(6) bond length is 1.35 Å. The C(23)-H(27) bond length is 1.08 Å. In the fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(25), one N(6), and one H(28) atom. The C(24)-C(25) bond length is 1.37 Å. The C(24)-N(6) bond length is 1.38 Å. The C(24)-H(28) bond length is 1.08 Å. In the fifth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(24), one N(5), and one H(29) atom. The C(25)-N(5) bond length is 1.38 Å. The C(25)-H(29) bond length is 1.08 Å. In the sixth C site, C(26) is bonded in a distorted trigonal non-coplanar geometry to one C(27), one N(6), one H(30), and one H(31) atom. The C(26)-C(27) bond length is 1.50 Å. The C(26)-N(6) bond length is 1.47 Å. The C(26)-H(30) bond length is 1.09 Å. The C(26)-H(31) bond length is 1.10 Å. In the seventh C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(32) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-C(32) bond length is 1.40 Å. In the eighth C site, C(28) is bonded in a distorted single-bond geometry to one C(27) and one H(32) atom. The C(28)-H(32) bond length is 1.09 Å. In the ninth C site, C(29) is bonded in a distorted single-bond geometry to one C(30) and one H(33) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-H(33) bond length is 1.09 Å. In the tenth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(33) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-C(33) bond length is 1.50 Å. In the eleventh C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(34) atom. The C(31)-H(34) bond length is 1.09 Å. In the twelfth C site, C(32) is bonded in a distorted single-bond geometry to one C(27) and one H(35) atom. The C(32)-H(35) bond length is 1.09 Å. In the thirteenth C site, C(33) is bonded in a distorted trigonal non-coplanar geometry to one C(30), one N(7), one H(36), and one H(37) atom. The C(33)-N(7) bond length is 1.47 Å. The C(33)-H(36) bond length is 1.09 Å. The C(33)-H(37) bond length is 1.10 Å. In the fourteenth C site, C(34) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(38) atom. The C(34)-N(7) bond length is 1.35 Å. The C(34)-N(8) bond length is 1.34 Å. The C(34)-H(38) bond length is 1.08 Å. In the fifteenth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(36), one N(8), and one H(39) atom. The C(35)-C(36) bond length is 1.37 Å. The C(35)-N(8) bond length is 1.38 Å. The C(35)-H(39) bond length is 1.08 Å. In the sixteenth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(35), one N(7), and one H(40) atom. The C(36)-N(7) bond length is 1.38 Å. The C(36)-H(40) bond length is 1.08 Å. There are four inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one Cu(2), one C(23), and one C(25) atom. In the second N site, N(6) is bonded in a trigonal planar geometry to one C(23), one C(24), and one C(26) atom. In the third N site, N(7) is bonded in a trigonal planar geometry to one C(33), one C(34), and one C(36) atom. In the fourth N site, N(8) is bonded in a trigonal planar geometry to one Cu(2), one C(34), and one C(35) atom. There are fourteen inequivalent H sites. In the first H site, H(27) is bonded in a single-bond geometry to one C(23) atom. In the second H site, H(28) is bonded in a single-bond geometry to one C(24) atom. In the third H site, H(29) is bonded in a single-bond geometry to one C(25) atom. In the fourth H site, H(30) is bonded in a single-bond geometry to one C(26) atom. In the fifth H site, H(31) is bonded in a single-bond geometry to one C(26) atom. In the sixth H site, H(32) is bonded in a single-bond geometry to one C(28) atom. In the seventh H site, H(33) is bonded in a single-bond geometry to one C(29) atom. In the eighth H site, H(34) is bonded in a single-bond geometry to one C(31) atom. In the ninth H site, H(35) is bonded in a single-bond geometry to one C(32) atom. In the tenth H site, H(36) is bonded in a single-bond geometry to one C(33) atom. In the eleventh H site, H(37) is bonded in a single-bond geometry to one C(33) atom. In the twelfth H site, H(38) is bonded in a single-bond geometry to one C(34) atom. In the thirteenth H site, H(39) is bonded in a single-bond geometry to one C(35) atom. In the fourteenth H site, H(40) is bonded in a single-bond geometry to one C(36) atom. There are four inequivalent O sites. In the first O site, O(5) is bonded in a water-like geometry to one Cu(2) and one C(19) atom. In the second O site, O(6) is bonded in a single-bond geometry to one C(19) atom. In the third O site, O(7) is bonded in a water-like geometry to one Cu(2) and one C(21) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one C(21) atom. Linkers: 1 [CH]N(C=[N])Cc1ccc(Cn2ccnc2)cc1 ,2 c1cn(Cc2ccc(Cn3ccnc3)cc2)cn1 ,1 [C]N(C=[N])Cc1ccc(Cn2ccnc2)cc1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 2.29 A, density 1.53 g/cm3, surface area 4838.03 m2/g, accessible volume 0.17 cm3/g