ZnC15H7(NO2)2(CH)5 crystallizes in the tetragonal P4_12_12 space group. The structure consists of forty 02329_fluka molecules inside a ZnC15H7(NO2)2 framework. In each ZnC15H7(NO2)2 framework, Zn(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one O(1), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.09 Å. The Zn(1)-N(2) bond length is 2.08 Å. The Zn(1)-O(1) bond length is 2.29 Å. The Zn(1)-O(3) bond length is 2.14 Å. The Zn(1)-O(4) bond length is 2.03 Å. There are fifteen inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(9) and one N(1) atom. The C(4)-C(9) bond length is 1.44 Å. The C(4)-N(1) bond length is 1.37 Å. In the second C site, C(20) is bonded in a trigonal planar geometry to one C(1), one C(19), and one C(9) atom. The C(20)-C(1) bond length is 1.50 Å. The C(20)-C(19) bond length is 1.39 Å. The C(20)-C(9) bond length is 1.43 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(14), one C(17), and one H(1) atom. The C(5)-C(14) bond length is 1.38 Å. The C(5)-C(17) bond length is 1.41 Å. The C(5)-H(1) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(2), and one O(4) atom. The C(6)-C(3) bond length is 1.50 Å. The C(6)-O(2) bond length is 1.26 Å. The C(6)-O(4) bond length is 1.30 Å. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(20), and one C(4) atom. The C(9)-C(10) bond length is 1.42 Å. In the sixth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(10)-H(4) bond length is 1.09 Å. In the seventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(16), one C(5), and one H(8) atom. The C(14)-C(16) bond length is 1.42 Å. The C(14)-H(8) bond length is 1.09 Å. In the eighth C site, C(15) is bonded in a distorted single-bond geometry to one C(3) and one H(9) atom. The C(15)-C(3) bond length is 1.38 Å. The C(15)-H(9) bond length is 1.09 Å. In the ninth C site, C(16) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(3) atom. The C(16)-C(2) bond length is 1.43 Å. The C(16)-C(3) bond length is 1.43 Å. In the tenth C site, C(19) is bonded in a distorted single-bond geometry to one C(20) and one H(12) atom. The C(19)-H(12) bond length is 1.09 Å. In the eleventh C site, C(1) is bonded in a bent 120 degrees geometry to one C(20), one O(1), and one O(3) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.29 Å. In the twelfth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(2), and one H(10) atom. The C(17)-N(2) bond length is 1.33 Å. The C(17)-H(10) bond length is 1.09 Å. In the thirteenth C site, C(2) is bonded in a distorted single-bond geometry to one C(16) and one N(2) atom. The C(2)-N(2) bond length is 1.37 Å. In the fourteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(11) atom. The C(18)-N(1) bond length is 1.33 Å. The C(18)-H(11) bond length is 1.09 Å. In the fifteenth C site, C(3) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(6) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(18), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(17), and one C(2) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(19) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(6) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Zn(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zn(1) and one C(6) atom. Linkers: 16 [O]C(=O)c1cccc2ncccc12. Metal clusters: 8 O=[C]O[Zn]1O[C]O1. The MOF has largest included sphere 5.70 A, density 1.19 g/cm3, surface area 4548.38 m2/g, accessible volume 0.29 cm3/g