Co2C42N4H28O9 crystallizes in the triclinic P1 space group. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(6), one N(9), one O(19), one O(25), one O(4), and one O(7) atom to form corner-sharing CoN2O4 octahedra. The corner-sharing octahedral tilt angles are 64°. The Co(1)-N(6) bond length is 2.14 Å. The Co(1)-N(9) bond length is 2.10 Å. The Co(1)-O(19) bond length is 2.09 Å. The Co(1)-O(25) bond length is 2.12 Å. The Co(1)-O(4) bond length is 2.05 Å. The Co(1)-O(7) bond length is 2.04 Å. In the second Co site, Co(2) is bonded to one N(5), one N(7), one O(20), one O(26), one O(6), and one O(8) atom to form corner-sharing CoN2O4 octahedra. The corner-sharing octahedral tilt angles are 64°. The Co(2)-N(5) bond length is 2.15 Å. The Co(2)-N(7) bond length is 2.10 Å. The Co(2)-O(20) bond length is 2.09 Å. The Co(2)-O(26) bond length is 2.12 Å. The Co(2)-O(6) bond length is 2.05 Å. The Co(2)-O(8) bond length is 2.04 Å. In the third Co site, Co(3) is bonded to one N(4), one N(8), one O(21), one O(27), one O(5), and one O(9) atom to form corner-sharing CoN2O4 octahedra. The corner-sharing octahedral tilt angles are 64°. The Co(3)-N(4) bond length is 2.13 Å. The Co(3)-N(8) bond length is 2.10 Å. The Co(3)-O(21) bond length is 2.08 Å. The Co(3)-O(27) bond length is 2.12 Å. The Co(3)-O(5) bond length is 2.08 Å. The Co(3)-O(9) bond length is 2.03 Å. In the fourth Co site, Co(4) is bonded to one N(12), one N(3), one O(1), one O(10), one O(22), and one O(25) atom to form corner-sharing CoN2O4 octahedra. The corner-sharing octahedral tilt angles are 64°. The Co(4)-N(12) bond length is 2.10 Å. The Co(4)-N(3) bond length is 2.13 Å. The Co(4)-O(1) bond length is 2.07 Å. The Co(4)-O(10) bond length is 2.03 Å. The Co(4)-O(22) bond length is 2.08 Å. The Co(4)-O(25) bond length is 2.12 Å. In the fifth Co site, Co(5) is bonded to one N(10), one N(2), one O(11), one O(23), one O(27), and one O(3) atom to form corner-sharing CoN2O4 octahedra. The corner-sharing octahedral tilt angles are 64°. The Co(5)-N(10) bond length is 2.10 Å. The Co(5)-N(2) bond length is 2.14 Å. The Co(5)-O(11) bond length is 2.04 Å. The Co(5)-O(23) bond length is 2.09 Å. The Co(5)-O(27) bond length is 2.12 Å. The Co(5)-O(3) bond length is 2.05 Å. In the sixth Co site, Co(6) is bonded to one N(1), one N(11), one O(12), one O(2), one O(24), and one O(26) atom to form corner-sharing CoN2O4 octahedra. The corner-sharing octahedral tilt angles are 64°. The Co(6)-N(1) bond length is 2.13 Å. The Co(6)-N(11) bond length is 2.10 Å. The Co(6)-O(12) bond length is 2.03 Å. The Co(6)-O(2) bond length is 2.08 Å. The Co(6)-O(24) bond length is 2.08 Å. The Co(6)-O(26) bond length is 2.11 Å. There are one hundred and ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(1), and one O(7) atom. The C(1)-C(7) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(7) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(2), and one O(8) atom. The C(2)-C(8) bond length is 1.51 Å. The C(2)-O(2) bond length is 1.26 Å. The C(2)-O(8) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(3), and one O(9) atom. The C(3)-C(9) bond length is 1.50 Å. The C(3)-O(3) bond length is 1.27 Å. The C(3)-O(9) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(10), and one O(4) atom. The C(4)-C(10) bond length is 1.50 Å. The C(4)-O(10) bond length is 1.27 Å. The C(4)-O(4) bond length is 1.27 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(11), and one O(5) atom. The C(5)-C(11) bond length is 1.51 Å. The C(5)-O(11) bond length is 1.28 Å. The C(5)-O(5) bond length is 1.26 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(12), and one O(6) atom. The C(6)-C(12) bond length is 1.50 Å. The C(6)-O(12) bond length is 1.27 Å. The C(6)-O(6) bond length is 1.27 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(31) atom. The C(7)-C(13) bond length is 1.40 Å. The C(7)-C(31) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(32) atom. The C(8)-C(14) bond length is 1.40 Å. The C(8)-C(32) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(15), one C(3), and one C(33) atom. The C(9)-C(15) bond length is 1.40 Å. The C(9)-C(33) bond length is 1.40 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(16), one C(34), and one C(4) atom. The C(10)-C(16) bond length is 1.40 Å. The C(10)-C(34) bond length is 1.40 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(17), one C(35), and one C(5) atom. The C(11)-C(17) bond length is 1.40 Å. The C(11)-C(35) bond length is 1.40 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(18), one C(36), and one C(6) atom. The C(12)-C(18) bond length is 1.40 Å. The C(12)-C(36) bond length is 1.40 Å. In the thirteenth C site, C(13) is bonded in a single-bond geometry to one C(19), one C(7), and one H(1) atom. The C(13)-C(19) bond length is 1.40 Å. The C(13)-H(1) bond length is 1.09 Å. In the fourteenth C site, C(14) is bonded in a single-bond geometry to one C(20), one C(8), and one H(2) atom. The C(14)-C(20) bond length is 1.40 Å. The C(14)-H(2) bond length is 1.09 Å. In the fifteenth C site, C(15) is bonded in a single-bond geometry to one C(21); one C(9); and one H(3,6) atom. The C(15)-C(21) bond length is 1.40 Å. The C(15)-H(3,6) bond length is 1.09 Å. In the sixteenth C site, C(16) is bonded in a single-bond geometry to one C(10), one C(22), and one H(4) atom. The C(16)-C(22) bond length is 1.40 Å. The C(16)-H(4) bond length is 1.09 Å. In the seventeenth C site, C(17) is bonded in a single-bond geometry to one C(11), one C(23), and one H(5) atom. The C(17)-C(23) bond length is 1.40 Å. The C(17)-H(5) bond length is 1.09 Å. In the eighteenth C site, C(18) is bonded in a single-bond geometry to one C(12); one C(24); and one H(3,6) atom. The C(18)-C(24) bond length is 1.40 Å. The C(18)-H(3,6) bond length is 1.09 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(13), one C(25), and one C(85) atom. The C(19)-C(25) bond length is 1.40 Å. The C(19)-C(85) bond length is 1.48 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(14); one C(26,29); and one C(86,89) atom. The C(20)-C(26,29) bond length is 1.40 Å. The C(20)-C(86,89) bond length is 1.48 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(15); one C(27,28); and one C(87,88) atom. The C(21)-C(27,28) bond length is 1.40 Å. The C(21)-C(87,88) bond length is 1.48 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(16); one C(27,28); and one C(87,88) atom. The C(22)-C(27,28) bond length is 1.40 Å. The C(22)-C(87,88) bond length is 1.48 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(17); one C(26,29); and one C(86,89) atom. The C(23)-C(26,29) bond length is 1.40 Å. The C(23)-C(86,89) bond length is 1.48 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(18), one C(30), and one C(90) atom. The C(24)-C(30) bond length is 1.40 Å. The C(24)-C(90) bond length is 1.48 Å. In the twenty-fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(19); one C(37); and one H(7,9,10,12) atom. The C(25)-C(37) bond length is 1.40 Å. The C(25)-H(7,9,10,12) bond length is 1.09 Å. In the twenty-sixth C site, C(26,29) is bonded in a distorted single-bond geometry to one C(20); one C(38); and one H(8,11) atom. The C(26,29)-C(38) bond length is 1.40 Å. The C(26,29)-H(8,11) bond length is 1.09 Å. In the twenty-seventh C site, C(27,28) is bonded in a distorted single-bond geometry to one C(21); one C(39); and one H(7,9,10,12) atom. The C(27,28)-C(39) bond length is 1.40 Å. The C(27,28)-H(7,9,10,12) bond length is 1.09 Å. In the twenty-eighth C site, C(30) is bonded in a distorted single-bond geometry to one C(24); one C(42); and one H(7,9,10,12) atom. The C(30)-C(42) bond length is 1.40 Å. The C(30)-H(7,9,10,12) bond length is 1.09 Å. In the twenty-ninth C site, C(31) is bonded in a single-bond geometry to one C(37); one C(7); and one H(13,17) atom. The C(31)-C(37) bond length is 1.40 Å. The C(31)-H(13,17) bond length is 1.09 Å. In the thirtieth C site, C(32) is bonded in a single-bond geometry to one C(38), one C(8), and one H(14) atom. The C(32)-C(38) bond length is 1.40 Å. The C(32)-H(14) bond length is 1.09 Å. In the thirty-first C site, C(33) is bonded in a single-bond geometry to one C(39); one C(9); and one H(15,18) atom. The C(33)-C(39) bond length is 1.40 Å. The C(33)-H(15,18) bond length is 1.09 Å. In the thirty-second C site, C(34) is bonded in a single-bond geometry to one C(10), one C(40), and one H(16) atom. The C(34)-C(40) bond length is 1.40 Å. The C(34)-H(16) bond length is 1.09 Å. In the thirty-third C site, C(35) is bonded in a single-bond geometry to one C(11); one C(41); and one H(13,17) atom. The C(35)-C(41) bond length is 1.40 Å. The C(35)-H(13,17) bond length is 1.09 Å. In the thirty-fourth C site, C(36) is bonded in a single-bond geometry to one C(12); one C(42); and one H(15,18) atom. The C(36)-C(42) bond length is 1.40 Å. The C(36)-H(15,18) bond length is 1.09 Å. In the thirty-fifth C site, C(37) is bonded in a trigonal planar geometry to one C(25); one C(31); and one C(43,45,46) atom. The C(37)-C(43,45,46) bond length is 1.48 Å. In the thirty-sixth C site, C(38) is bonded in a trigonal planar geometry to one C(26,29); one C(32); and one C(44,47) atom. The C(38)-C(44,47) bond length is 1.47 Å. In the thirty-seventh C site, C(39) is bonded in a trigonal planar geometry to one C(27,28); one C(33); and one C(43,45,46) atom. The C(39)-C(43,45,46) bond length is 1.48 Å. In the thirty-eighth C site, C(40) is bonded in a trigonal planar geometry to one C(27,28); one C(34); and one C(43,45,46) atom. The C(40)-C(27,28) bond length is 1.40 Å. The C(40)-C(43,45,46) bond length is 1.48 Å. In the thirty-ninth C site, C(41) is bonded in a trigonal planar geometry to one C(26,29); one C(35); and one C(44,47) atom. The C(41)-C(26,29) bond length is 1.40 Å. The C(41)-C(44,47) bond length is 1.48 Å. In the fortieth C site, C(42) is bonded in a trigonal planar geometry to one C(30), one C(36), and one C(48) atom. The C(42)-C(48) bond length is 1.48 Å. In the forty-first C site, C(43,45,46) is bonded in a trigonal planar geometry to one C(37); one C(49,52); and one C(67,68,70) atom. The C(43,45,46)-C(49,52) bond length is 1.40 Å. The C(43,45,46)-C(67,68,70) bond length is 1.41 Å. In the forty-second C site, C(44,47) is bonded in a trigonal planar geometry to one C(38); one C(50); and one C(67,68,70) atom. The C(44,47)-C(50) bond length is 1.40 Å. The C(44,47)-C(67,68,70) bond length is 1.40 Å. In the forty-third C site, C(48) is bonded in a trigonal planar geometry to one C(42), one C(54), and one C(72) atom. The C(48)-C(54) bond length is 1.40 Å. The C(48)-C(72) bond length is 1.40 Å. In the forty-fourth C site, C(49,52) is bonded in a distorted single-bond geometry to one C(43,45,46) and one H(19,20,21,22,23,24,37,38,39,40,41,42) atom. The C(49,52)-H(19,20,21,22,23,24,37,38,39,40,41,42) bond length is 1.09 Å. In the forty-fifth C site, C(50) is bonded in a distorted single-bond geometry to one C(44,47) and one H(19,20,21,22,23,24,37,38,39,40,41,42) atom. The C(50)-H(19,20,21,22,23,24,37,38,39,40,41,42) bond length is 1.09 Å. In the forty-sixth C site, C(51) is bonded in a distorted single-bond geometry to one C(43,45,46) and one H(19,20,21,22,23,24,37,38,39,40,41,42) atom. The C(51)-C(43,45,46) bond length is 1.40 Å. The C(51)-H(19,20,21,22,23,24,37,38,39,40,41,42) bond length is 1.09 Å. In the forty-seventh C site, C(53) is bonded in a distorted single-bond geometry to one C(44,47) and one H(19,20,21,22,23,24,37,38,39,40,41,42) atom. The C(53)-C(44,47) bond length is 1.40 Å. The C(53)-H(19,20,21,22,23,24,37,38,39,40,41,42) bond length is 1.09 Å. In the forty-eighth C site, C(54) is bonded in a distorted single-bond geometry to one C(48) and one H(19,20,21,22,23,24,37,38,39,40,41,42) atom. The C(54)-H(19,20,21,22,23,24,37,38,39,40,41,42) bond length is 1.09 Å. In the forty-ninth C site, C(55) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(25,28) atom. The C(55)-N(1) bond length is 1.35 Å. The C(55)-H(25,28) bond length is 1.09 Å. In the fiftieth C site, C(56) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(26,30) atom. The C(56)-N(2) bond length is 1.35 Å. The C(56)-H(26,30) bond length is 1.09 Å. In the fifty-first C site, C(57) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(27) atom. The C(57)-N(3) bond length is 1.35 Å. The C(57)-H(27) bond length is 1.09 Å. In the fifty-second C site, C(58) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(25,28) atom. The C(58)-N(4) bond length is 1.35 Å. The C(58)-H(25,28) bond length is 1.09 Å. In the fifty-third C site, C(59) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(29) atom. The C(59)-N(5) bond length is 1.35 Å. The C(59)-H(29) bond length is 1.09 Å. In the fifty-fourth C site, C(60) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(26,30) atom. The C(60)-N(6) bond length is 1.35 Å. The C(60)-H(26,30) bond length is 1.09 Å. In the fifty-fifth C site, C(61) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(31,34) atom. The C(61)-N(1) bond length is 1.35 Å. The C(61)-H(31,34) bond length is 1.09 Å. In the fifty-sixth C site, C(62) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(32,36) atom. The C(62)-N(2) bond length is 1.35 Å. The C(62)-H(32,36) bond length is 1.09 Å. In the fifty-seventh C site, C(63) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(33) atom. The C(63)-N(3) bond length is 1.35 Å. The C(63)-H(33) bond length is 1.09 Å. In the fifty-eighth C site, C(64) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(31,34) atom. The C(64)-N(4) bond length is 1.35 Å. The C(64)-H(31,34) bond length is 1.09 Å. In the fifty-ninth C site, C(65) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(35) atom. The C(65)-N(5) bond length is 1.35 Å. The C(65)-H(35) bond length is 1.09 Å. In the sixtieth C site, C(66) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(32,36) atom. The C(66)-N(6) bond length is 1.35 Å. The C(66)-H(32,36) bond length is 1.09 Å. In the sixty-first C site, C(67,68,70) is bonded in a distorted single-bond geometry to one C(43,45,46) and one H(19,20,21,22,23,24,37,38,39,40,41,42) atom. The C(67,68,70)-H(19,20,21,22,23,24,37,38,39,40,41,42) bond length is 1.09 Å. In the sixty-second C site, C(69) is bonded in a distorted single-bond geometry to one C(43,45,46) and one H(19,20,21,22,23,24,37,38,39,40,41,42) atom. The C(69)-C(43,45,46) bond length is 1.41 Å. The C(69)-H(19,20,21,22,23,24,37,38,39,40,41,42) bond length is 1.09 Å. In the sixty-third C site, C(71) is bonded in a distorted single-bond geometry to one C(44,47) and one H(19,20,21,22,23,24,37,38,39,40,41,42) atom. The C(71)-C(44,47) bond length is 1.40 Å. The C(71)-H(19,20,21,22,23,24,37,38,39,40,41,42) bond length is 1.09 Å. In the sixty-fourth C site, C(72) is bonded in a distorted single-bond geometry to one C(48) and one H(19,20,21,22,23,24,37,38,39,40,41,42) atom. The C(72)-H(19,20,21,22,23,24,37,38,39,40,41,42) bond length is 1.09 Å. In the sixty-fifth C site, C(73) is bonded in a distorted bent 120 degrees geometry to one C(79), one N(7), and one H(43) atom. The C(73)-C(79) bond length is 1.39 Å. The C(73)-N(7) bond length is 1.35 Å. The C(73)-H(43) bond length is 1.09 Å. In the sixty-sixth C site, C(74) is bonded in a distorted bent 120 degrees geometry to one C(80), one N(8), and one H(44) atom. The C(74)-C(80) bond length is 1.39 Å. The C(74)-N(8) bond length is 1.35 Å. The C(74)-H(44) bond length is 1.09 Å. In the sixty-seventh C site, C(75) is bonded in a distorted bent 120 degrees geometry to one C(81), one N(9), and one H(45) atom. The C(75)-C(81) bond length is 1.39 Å. The C(75)-N(9) bond length is 1.35 Å. The C(75)-H(45) bond length is 1.09 Å. In the sixty-eighth C site, C(76) is bonded in a distorted bent 120 degrees geometry to one C(82), one N(10), and one H(46) atom. The C(76)-C(82) bond length is 1.39 Å. The C(76)-N(10) bond length is 1.35 Å. The C(76)-H(46) bond length is 1.09 Å. In the sixty-ninth C site, C(77) is bonded in a distorted bent 120 degrees geometry to one C(83), one N(11), and one H(47) atom. The C(77)-C(83) bond length is 1.39 Å. The C(77)-N(11) bond length is 1.35 Å. The C(77)-H(47) bond length is 1.09 Å. In the seventieth C site, C(78) is bonded in a distorted bent 120 degrees geometry to one C(84), one N(12), and one H(48) atom. The C(78)-C(84) bond length is 1.39 Å. The C(78)-N(12) bond length is 1.35 Å. The C(78)-H(48) bond length is 1.09 Å. In the seventy-first C site, C(79) is bonded in a distorted trigonal planar geometry to one C(73); one C(85); and one H(49,50,52,53,54) atom. The C(79)-C(85) bond length is 1.41 Å. The C(79)-H(49,50,52,53,54) bond length is 1.09 Å. In the seventy-second C site, C(80) is bonded in a distorted trigonal planar geometry to one C(74); one C(86,89); and one H(49,50,52,53,54) atom. The C(80)-C(86,89) bond length is 1.41 Å. The C(80)-H(49,50,52,53,54) bond length is 1.09 Å. In the seventy-third C site, C(81) is bonded in a distorted trigonal planar geometry to one C(75); one C(87,88); and one H(51) atom. The C(81)-C(87,88) bond length is 1.41 Å. The C(81)-H(51) bond length is 1.09 Å. In the seventy-fourth C site, C(82) is bonded in a distorted trigonal planar geometry to one C(76); one C(87,88); and one H(49,50,52,53,54) atom. The C(82)-C(87,88) bond length is 1.41 Å. The C(82)-H(49,50,52,53,54) bond length is 1.09 Å. In the seventy-fifth C site, C(83) is bonded in a distorted trigonal planar geometry to one C(77); one C(86,89); and one H(49,50,52,53,54) atom. The C(83)-C(86,89) bond length is 1.41 Å. The C(83)-H(49,50,52,53,54) bond length is 1.09 Å. In the seventy-sixth C site, C(84) is bonded in a distorted trigonal planar geometry to one C(78); one C(90); and one H(49,50,52,53,54) atom. The C(84)-C(90) bond length is 1.41 Å. The C(84)-H(49,50,52,53,54) bond length is 1.09 Å. In the seventy-seventh C site, C(85) is bonded in a trigonal planar geometry to one C(19), one C(79), and one C(91) atom. The C(85)-C(91) bond length is 1.41 Å. In the seventy-eighth C site, C(86,89) is bonded in a trigonal planar geometry to one C(20), one C(80), and one C(92) atom. The C(86,89)-C(92) bond length is 1.41 Å. In the seventy-ninth C site, C(87,88) is bonded in a trigonal planar geometry to one C(21), one C(81), and one C(93) atom. The C(87,88)-C(93) bond length is 1.41 Å. In the eightieth C site, C(90) is bonded in a trigonal planar geometry to one C(24), one C(84), and one C(96) atom. The C(90)-C(96) bond length is 1.41 Å. In the eighty-first C site, C(91) is bonded in a distorted trigonal planar geometry to one C(85); one C(97); and one H(55,58) atom. The C(91)-C(97) bond length is 1.39 Å. The C(91)-H(55,58) bond length is 1.09 Å. In the eighty-second C site, C(92) is bonded in a distorted trigonal planar geometry to one C(86,89); one C(98); and one H(56,59,60) atom. The C(92)-C(98) bond length is 1.39 Å. The C(92)-H(56,59,60) bond length is 1.09 Å. In the eighty-third C site, C(93) is bonded in a distorted trigonal planar geometry to one C(87,88); one C(99); and one H(57) atom. The C(93)-C(99) bond length is 1.39 Å. The C(93)-H(57) bond length is 1.09 Å. In the eighty-fourth C site, C(94) is bonded in a distorted trigonal planar geometry to one C(100); one C(87,88); and one H(55,58) atom. The C(94)-C(100) bond length is 1.39 Å. The C(94)-C(87,88) bond length is 1.41 Å. The C(94)-H(55,58) bond length is 1.09 Å. In the eighty-fifth C site, C(95) is bonded in a distorted trigonal planar geometry to one C(101); one C(86,89); and one H(56,59,60) atom. The C(95)-C(101) bond length is 1.39 Å. The C(95)-C(86,89) bond length is 1.41 Å. The C(95)-H(56,59,60) bond length is 1.09 Å. In the eighty-sixth C site, C(96) is bonded in a distorted trigonal planar geometry to one C(102); one C(90); and one H(56,59,60) atom. The C(96)-C(102) bond length is 1.39 Å. The C(96)-H(56,59,60) bond length is 1.09 Å. In the eighty-seventh C site, C(97) is bonded in a distorted bent 120 degrees geometry to one C(91), one N(7), and one H(61) atom. The C(97)-N(7) bond length is 1.35 Å. The C(97)-H(61) bond length is 1.09 Å. In the eighty-eighth C site, C(98) is bonded in a distorted bent 120 degrees geometry to one C(92), one N(8), and one H(62) atom. The C(98)-N(8) bond length is 1.35 Å. The C(98)-H(62) bond length is 1.09 Å. In the eighty-ninth C site, C(99) is bonded in a distorted bent 120 degrees geometry to one C(93), one N(9), and one H(63) atom. The C(99)-N(9) bond length is 1.35 Å. The C(99)-H(63) bond length is 1.09 Å. In the ninetieth C site, C(100) is bonded in a distorted bent 120 degrees geometry to one C(94), one N(10), and one H(64) atom. The C(100)-N(10) bond length is 1.35 Å. The C(100)-H(64) bond length is 1.09 Å. In the ninety-first C site, C(101) is bonded in a distorted bent 120 degrees geometry to one C(95), one N(11), and one H(65) atom. The C(101)-N(11) bond length is 1.35 Å. The C(101)-H(65) bond length is 1.09 Å. In the ninety-second C site, C(102) is bonded in a distorted bent 120 degrees geometry to one C(96), one N(12), and one H(66) atom. The C(102)-N(12) bond length is 1.35 Å. The C(102)-H(66) bond length is 1.09 Å. In the ninety-third C site, C(103) is bonded in a distorted bent 120 degrees geometry to one C(109,110,113); one O(13,17); and one O(19) atom. The C(103)-C(109,110,113) bond length is 1.50 Å. The C(103)-O(13,17) bond length is 1.27 Å. The C(103)-O(19) bond length is 1.28 Å. In the ninety-fourth C site, C(104) is bonded in a distorted bent 120 degrees geometry to one C(109,110,113); one O(14); and one O(20) atom. The C(104)-C(109,110,113) bond length is 1.50 Å. The C(104)-O(14) bond length is 1.27 Å. The C(104)-O(20) bond length is 1.28 Å. In the ninety-fifth C site, C(105) is bonded in a distorted bent 120 degrees geometry to one C(111,112,114); one O(15,16); and one O(21) atom. The C(105)-C(111,112,114) bond length is 1.50 Å. The C(105)-O(15,16) bond length is 1.27 Å. The C(105)-O(21) bond length is 1.28 Å. In the ninety-sixth C site, C(106) is bonded in a distorted bent 120 degrees geometry to one C(111,112,114); one O(15,16); and one O(22) atom. The C(106)-C(111,112,114) bond length is 1.50 Å. The C(106)-O(15,16) bond length is 1.27 Å. The C(106)-O(22) bond length is 1.28 Å. In the ninety-seventh C site, C(107) is bonded in a distorted bent 120 degrees geometry to one C(109,110,113); one O(13,17); and one O(23) atom. The C(107)-C(109,110,113) bond length is 1.50 Å. The C(107)-O(13,17) bond length is 1.27 Å. The C(107)-O(23) bond length is 1.28 Å. In the ninety-eighth C site, C(108) is bonded in a distorted bent 120 degrees geometry to one C(111,112,114); one O(18); and one O(24) atom. The C(108)-C(111,112,114) bond length is 1.50 Å. The C(108)-O(18) bond length is 1.27 Å. The C(108)-O(24) bond length is 1.28 Å. In the ninety-ninth C site, C(109,110,113) is bonded in a trigonal planar geometry to one C(103); one C(115,119); and one C(121,125) atom. The C(109,110,113)-C(115,119) bond length is 1.40 Å. The C(109,110,113)-C(121,125) bond length is 1.40 Å. In the one hundredth C site, C(111,112,114) is bonded in a trigonal planar geometry to one C(105), one C(117), and one C(123) atom. The C(111,112,114)-C(117) bond length is 1.40 Å. The C(111,112,114)-C(123) bond length is 1.40 Å. In the one hundred and first C site, C(115,119) is bonded in a distorted single-bond geometry to one C(109,110,113) and one H(67,68,71) atom. The C(115,119)-H(67,68,71) bond length is 1.09 Å. In the one hundred and second C site, C(116) is bonded in a distorted single-bond geometry to one C(109,110,113) and one H(67,68,71) atom. The C(116)-C(109,110,113) bond length is 1.40 Å. The C(116)-H(67,68,71) bond length is 1.09 Å. In the one hundred and third C site, C(117) is bonded in a distorted single-bond geometry to one C(111,112,114) and one H(69,70,72) atom. The C(117)-H(69,70,72) bond length is 1.09 Å. In the one hundred and fourth C site, C(118) is bonded in a distorted single-bond geometry to one C(111,112,114) and one H(69,70,72) atom. The C(118)-C(111,112,114) bond length is 1.40 Å. The C(118)-H(69,70,72) bond length is 1.09 Å. In the one hundred and fifth C site, C(120) is bonded in a distorted single-bond geometry to one C(111,112,114) and one H(69,70,72) atom. The C(120)-C(111,112,114) bond length is 1.40 Å. The C(120)-H(69,70,72) bond length is 1.09 Å. In the one hundred and sixth C site, C(121,125) is bonded in a distorted single-bond geometry to one C(109,110,113) and one H(73,74,77) atom. The C(121,125)-H(73,74,77) bond length is 1.09 Å. In the one hundred and seventh C site, C(122) is bonded in a distorted single-bond geometry to one C(109,110,113) and one H(73,74,77) atom. The C(122)-C(109,110,113) bond length is 1.40 Å. The C(122)-H(73,74,77) bond length is 1.09 Å. In the one hundred and eighth C site, C(123) is bonded in a distorted single-bond geometry to one C(111,112,114) and one H(75,76,78) atom. The C(123)-H(75,76,78) bond length is 1.09 Å. In the one hundred and ninth C site, C(124) is bonded in a distorted single-bond geometry to one C(111,112,114) and one H(75,76,78) atom. The C(124)-C(111,112,114) bond length is 1.40 Å. The C(124)-H(75,76,78) bond length is 1.09 Å. In the one hundred and tenth C site, C(126) is bonded in a distorted single-bond geometry to one C(111,112,114) and one H(75,76,78) atom. The C(126)-C(111,112,114) bond length is 1.40 Å. The C(126)-H(75,76,78) bond length is 1.09 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(6), one C(55), and one C(61) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(5), one C(56), and one C(62) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(4), one C(57), and one C(63) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(3), one C(58), and one C(64) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(2), one C(59), and one C(65) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Co(1), one C(60), and one C(66) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Co(2), one C(73), and one C(97) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Co(3), one C(74), and one C(98) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Co(1), one C(75), and one C(99) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Co(5), one C(100), and one C(76) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Co(6), one C(101), and one C(77) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Co(4), one C(102), and one C(78) atom. There are forty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(3,6) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(7,9,10,12) is bonded in a single-bond geometry to one C(25) atom. In the seventh H site, H(8,11) is bonded in a single-bond geometry to one C(26,29) atom. In the eighth H site, H(13,17) is bonded in a single-bond geometry to one C(31) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(32) atom. In the tenth H site, H(15,18) is bonded in a single-bond geometry to one C(33) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(34) atom. In the twelfth H site, H(19,20,21,22,23,24,37,38,39,40,41,42) is bonded in a single-bond geometry to one C(49,52) atom. In the thirteenth H site, H(25,28) is bonded in a single-bond geometry to one C(55) atom. In the fourteenth H site, H(26,30) is bonded in a single-bond geometry to one C(56) atom. In the fifteenth H site, H(27) is bonded in a single-bond geometry to one C(57) atom. In the sixteenth H site, H(29) is bonded in a single-bond geometry to one C(59) atom. In the seventeenth H site, H(31,34) is bonded in a single-bond geometry to one C(61) atom. In the eighteenth H site, H(32,36) is bonded in a single-bond geometry to one C(62) atom. In the nineteenth H site, H(33) is bonded in a single-bond geometry to one C(63) atom. In the twentieth H site, H(35) is bonded in a single-bond geometry to one C(65) atom. In the twenty-first H site, H(43) is bonded in a single-bond geometry to one C(73) atom. In the twenty-second H site, H(44) is bonded in a single-bond geometry to one C(74) atom. In the twenty-third H site, H(45) is bonded in a single-bond geometry to one C(75) atom. In the twenty-fourth H site, H(46) is bonded in a single-bond geometry to one C(76) atom. In the twenty-fifth H site, H(47) is bonded in a single-bond geometry to one C(77) atom. In the twenty-sixth H site, H(48) is bonded in a single-bond geometry to one C(78) atom. In the twenty-seventh H site, H(49,50,52,53,54) is bonded in a single-bond geometry to one C(79) atom. In the twenty-eighth H site, H(51) is bonded in a single-bond geometry to one C(81) atom. In the twenty-ninth H site, H(55,58) is bonded in a single-bond geometry to one C(91) atom. In the thirtieth H site, H(56,59,60) is bonded in a single-bond geometry to one C(92) atom. In the thirty-first H site, H(57) is bonded in a single-bond geometry to one C(93) atom. In the thirty-second H site, H(61) is bonded in a single-bond geometry to one C(97) atom. In the thirty-third H site, H(62) is bonded in a single-bond geometry to one C(98) atom. In the thirty-fourth H site, H(63) is bonded in a single-bond geometry to one C(99) atom. In the thirty-fifth H site, H(64) is bonded in a single-bond geometry to one C(100) atom. In the thirty-sixth H site, H(65) is bonded in a single-bond geometry to one C(101) atom. In the thirty-seventh H site, H(66) is bonded in a single-bond geometry to one C(102) atom. In the thirty-eighth H site, H(67,68,71) is bonded in a single-bond geometry to one C(115,119) atom. In the thirty-ninth H site, H(69,70,72) is bonded in a single-bond geometry to one C(117) atom. In the fortieth H site, H(73,74,77) is bonded in a single-bond geometry to one C(121,125) atom. In the forty-first H site, H(75,76,78) is bonded in a single-bond geometry to one C(123) atom. In the forty-second H site, H(79) is bonded in a distorted single-bond geometry to one O(15,16) and one O(25) atom. The H(79)-O(15,16) bond length is 1.50 Å. The H(79)-O(25) bond length is 1.04 Å. In the forty-third H site, H(80) is bonded in a distorted single-bond geometry to one O(18) and one O(26) atom. The H(80)-O(18) bond length is 1.50 Å. The H(80)-O(26) bond length is 1.04 Å. In the forty-fourth H site, H(81) is bonded in a distorted single-bond geometry to one O(13,17) and one O(27) atom. The H(81)-O(13,17) bond length is 1.49 Å. The H(81)-O(27) bond length is 1.04 Å. In the forty-fifth H site, H(82) is bonded in a distorted single-bond geometry to one O(13,17) and one O(25) atom. The H(82)-O(13,17) bond length is 1.50 Å. The H(82)-O(25) bond length is 1.04 Å. In the forty-sixth H site, H(83) is bonded in a distorted single-bond geometry to one O(15,16) and one O(27) atom. The H(83)-O(15,16) bond length is 1.50 Å. The H(83)-O(27) bond length is 1.04 Å. In the forty-seventh H site, H(84) is bonded in a distorted single-bond geometry to one O(14) and one O(26) atom. The H(84)-O(14) bond length is 1.50 Å. The H(84)-O(26) bond length is 1.04 Å. There are twenty-five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Co(4) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Co(6) and one C(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Co(5) and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(4) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Co(3) and one C(5) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one C(6) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Co(2) and one C(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Co(3) and one C(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Co(4) and one C(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Co(5) and one C(5) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Co(6) and one C(6) atom. In the thirteenth O site, O(13,17) is bonded in a water-like geometry to one C(103) and one H(82) atom. In the fourteenth O site, O(14) is bonded in a water-like geometry to one C(104) and one H(84) atom. In the fifteenth O site, O(15,16) is bonded in a water-like geometry to one C(105) and one H(83) atom. In the sixteenth O site, O(18) is bonded in a water-like geometry to one C(108) and one H(80) atom. In the seventeenth O site, O(19) is bonded in a bent 120 degrees geometry to one Co(1) and one C(103) atom. In the eighteenth O site, O(20) is bonded in a bent 120 degrees geometry to one Co(2) and one C(104) atom. In the nineteenth O site, O(21) is bonded in a bent 120 degrees geometry to one Co(3) and one C(105) atom. In the twentieth O site, O(22) is bonded in a bent 120 degrees geometry to one Co(4) and one C(106) atom. In the twenty-first O site, O(23) is bonded in a bent 120 degrees geometry to one Co(5) and one C(107) atom. In the twenty-second O site, O(24) is bonded in a bent 120 degrees geometry to one Co(6) and one C(108) atom. In the twenty-third O site, O(25) is bonded in a distorted water-like geometry to one Co(1), one Co(4), one H(79), and one H(82) atom. In the twenty-fourth O site, O(26) is bonded in a distorted water-like geometry to one Co(2), one Co(6), one H(80), and one H(84) atom. In the twenty-fifth O site, O(27) is bonded in a distorted water-like geometry to one Co(3), one Co(5), one H(81), and one H(83) atom. Linkers: 6 [O]C(=O)c1cc(-c2ccncc2)cc(-c2ccncc2)c1 ,3 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 3 O.O=[C]O[Co]1O[C]O[Co](O[C]=O)O[C]O1. The MOF has largest included sphere 8.88 A, density 0.74 g/cm3, surface area 4404.48 m2/g, accessible volume 0.94 cm3/g