MnC8H8(NO)4C4H2O is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four furan molecules and four MnC8H8(NO)4 clusters. In each MnC8H8(NO)4 cluster, Mn(1) is bonded in a 5-coordinate geometry to one N(1), one N(3), one O(1), one O(2), and one O(4) atom. The Mn(1)-N(1) bond length is 2.09 Å. The Mn(1)-N(3) bond length is 2.09 Å. The Mn(1)-O(1) bond length is 2.17 Å. The Mn(1)-O(2) bond length is 2.41 Å. The Mn(1)-O(4) bond length is 2.12 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(6)-O(4) bond length is 1.30 Å. The C(6)-O(5) bond length is 1.25 Å. In the third C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(1), and one H(4) atom. The C(7)-C(8) bond length is 1.37 Å. The C(7)-N(1) bond length is 1.39 Å. The C(7)-H(4) bond length is 1.08 Å. In the fourth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(2), and one H(5) atom. The C(8)-N(2) bond length is 1.38 Å. The C(8)-H(5) bond length is 1.08 Å. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(6) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-N(2) bond length is 1.35 Å. The C(9)-H(6) bond length is 1.09 Å. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(8) atom. The C(10)-N(3) bond length is 1.34 Å. The C(10)-N(4) bond length is 1.35 Å. The C(10)-H(8) bond length is 1.08 Å. In the seventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(3), and one H(9) atom. The C(11)-C(12) bond length is 1.37 Å. The C(11)-N(3) bond length is 1.39 Å. The C(11)-H(9) bond length is 1.08 Å. In the eighth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(4), and one H(10) atom. The C(12)-N(4) bond length is 1.38 Å. The C(12)-H(10) bond length is 1.08 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(1), one C(7), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(8), one C(9), and one H(3) atom. The N(2)-H(3) bond length is 1.03 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Mn(1), one C(10), and one C(11) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(12), and one H(7) atom. The N(4)-H(7) bond length is 1.04 Å. There are eight inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Mn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Mn(1) and one C(1) atom. In the third O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(6) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(6) atom. Linkers: 4 [O]C(=O)c1ccc(C([O])=O)o1. Metal clusters: 4 [Mn]. The MOF has largest included sphere 2.67 A, density 1.56 g/cm3, surface area 4242.86 m2/g, accessible volume 0.19 cm3/g