RuC13N2H4(OF)4(CH)2(CF)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, sixteen fluoromethane molecules, and two RuC13N2H4(OF)4 clusters. In each RuC13N2H4(OF)4 cluster, Ru(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Ru(1)-N(1) bond length is 2.11 Å. The Ru(1)-O(1) bond length is 2.02 Å. The Ru(1)-O(2) bond length is 2.06 Å. The Ru(1)-O(3) bond length is 2.06 Å. The Ru(1)-O(4) bond length is 2.03 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(2) and one F(1) atom. The C(3)-F(1) bond length is 1.35 Å. In the fourth C site, C(7) is bonded in a single-bond geometry to one C(2) and one F(4) atom. The C(7)-F(4) bond length is 1.35 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(8)-C(9) bond length is 1.49 Å. The C(8)-O(3) bond length is 1.28 Å. The C(8)-O(4) bond length is 1.28 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(14) bond length is 1.41 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one F(5,8) atom. The C(10)-F(5,8) bond length is 1.35 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one F(5,8) atom. The C(14)-F(5,8) bond length is 1.35 Å. In the ninth C site, C(15) is bonded in a linear geometry to one N(1) and one N(2) atom. The C(15)-N(1) bond length is 1.20 Å. The C(15)-N(2) bond length is 1.27 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(18) and one N(2) atom. The C(16)-C(18) bond length is 1.44 Å. The C(16)-N(2) bond length is 1.36 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(3) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-H(3) bond length is 1.09 Å. In the twelfth C site, C(18) is bonded in a trigonal planar geometry to one C(16), one C(17), and one C(19) atom. The C(18)-C(19) bond length is 1.49 Å. In the thirteenth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one C(18), one H(4), one H(5), and one H(6) atom. The C(19)-H(4) bond length is 1.09 Å. The C(19)-H(5) bond length is 1.10 Å. The C(19)-H(6) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Ru(1) and one C(15) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(15) and one C(16) atom. There are four inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(17) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(19) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(19) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(8) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(3) atom. In the second F site, F(4) is bonded in a single-bond geometry to one C(7) atom. In the third F site, F(5,8) is bonded in a single-bond geometry to one C(10) atom. Linkers: 2 Cc1cc([N]C#N)c(C)cc1[N]C#N ,8 [O]C(=O)c1c(F)c(F)cc(F)c1F. Metal clusters: 4 [Ru]. The MOF has largest included sphere 2.93 A, density 1.82 g/cm3, surface area 3721.66 m2/g, accessible volume 0.14 cm3/g