CuC24H18(NO)6(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one CuC24H18(NO)6 cluster. In the CuC24H18(NO)6 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent O(3) atoms. Both Cu(1)-N(2) bond lengths are 1.97 Å. Both Cu(1)-O(3) bond lengths are 2.03 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(3), and one H(2) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-N(3) bond length is 1.34 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.49 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one O(1) atom. The C(4)-N(1) bond length is 1.38 Å. The C(4)-O(1) bond length is 1.24 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one C(9), and one N(1) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-C(9) bond length is 1.41 Å. The C(5)-N(1) bond length is 1.39 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(4) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(4) bond length is 1.08 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one N(2), and one H(5) atom. The C(7)-N(2) bond length is 1.35 Å. The C(7)-H(5) bond length is 1.09 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(6) atom. The C(8)-C(9) bond length is 1.38 Å. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(6) bond length is 1.09 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(5), one C(8), and one H(7) atom. The C(9)-H(7) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(10)-O(2) bond length is 1.26 Å. The C(10)-O(3) bond length is 1.29 Å. In the eleventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one H(12) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-N(3) bond length is 1.34 Å. The C(13)-H(12) bond length is 1.09 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(13) atom. The C(14)-H(13) bond length is 1.09 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(4), one C(5), and one H(1) atom. The N(1)-H(1) bond length is 1.03 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(7), and one C(8) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(13) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(10) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cu(1) and one C(10) atom. Linkers: 1 [O]C(=O)CCCCC([O])=O. Metal clusters: 1 [Cu]. The MOF has largest included sphere 2.43 A, density 1.54 g/cm3, surface area 4732.41 m2/g, accessible volume 0.18 cm3/g