ZnC9N5H8O6(C3H2)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four 2,3-dimethyl-1,3-butadiene molecules and two ZnC9N5H8O6 clusters. In each ZnC9N5H8O6 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1,2); one N(5); one N(9); one O(1); and one O(13,14) atom. The Zn(1)-N(1,2) bond length is 2.15 Å. The Zn(1)-N(5) bond length is 2.16 Å. The Zn(1)-N(9) bond length is 2.11 Å. The Zn(1)-O(1) bond length is 2.11 Å. The Zn(1)-O(13,14) bond length is 2.08 Å. In the second Zn site, Zn(2) is bonded in a trigonal bipyramidal geometry to one N(1,2); one N(10); one N(6); one O(13,14); and one O(2) atom. The Zn(2)-N(1,2) bond length is 2.15 Å. The Zn(2)-N(10) bond length is 2.11 Å. The Zn(2)-N(6) bond length is 2.17 Å. The Zn(2)-O(13,14) bond length is 2.08 Å. The Zn(2)-O(2) bond length is 2.12 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1,2) and one H(1,2,3) atom. The C(1)-N(1,2) bond length is 1.35 Å. The C(1)-H(1,2,3) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1,2) and one H(1,2,3) atom. The C(2)-N(1,2) bond length is 1.35 Å. The C(2)-H(1,2,3) bond length is 1.09 Å. In the third C site, C(17) is bonded in a distorted trigonal planar geometry to one N(1,2) and one H(13,14,15) atom. The C(17)-N(1,2) bond length is 1.35 Å. The C(17)-H(13,14,15) bond length is 1.09 Å. In the fourth C site, C(18) is bonded in a distorted trigonal planar geometry to one N(1,2) and one H(13,14,15) atom. The C(18)-N(1,2) bond length is 1.35 Å. The C(18)-H(13,14,15) bond length is 1.09 Å. In the fifth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(17,18) atom. The C(21)-N(5) bond length is 1.34 Å. The C(21)-H(17,18) bond length is 1.09 Å. In the sixth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(17,18) atom. The C(22)-N(6) bond length is 1.34 Å. The C(22)-H(17,18) bond length is 1.09 Å. In the seventh C site, C(37) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(29,30) atom. The C(37)-N(5) bond length is 1.35 Å. The C(37)-H(29,30) bond length is 1.09 Å. In the eighth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(29,30) atom. The C(38)-N(6) bond length is 1.35 Å. The C(38)-H(29,30) bond length is 1.09 Å. In the ninth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(45,46); one N(9); and one H(33,34) atom. The C(41)-C(45,46) bond length is 1.39 Å. The C(41)-N(9) bond length is 1.35 Å. The C(41)-H(33,34) bond length is 1.09 Å. In the tenth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(45,46); one N(10); and one H(33,34) atom. The C(42)-C(45,46) bond length is 1.39 Å. The C(42)-N(10) bond length is 1.35 Å. The C(42)-H(33,34) bond length is 1.09 Å. In the eleventh C site, C(45,46) is bonded in a distorted trigonal planar geometry to one C(41); one C(49); and one H(37,40) atom. The C(45,46)-C(49) bond length is 1.40 Å. The C(45,46)-H(37,40) bond length is 1.09 Å. In the twelfth C site, C(49) is bonded in a trigonal planar geometry to one C(45,46); one C(50); and one C(53,54) atom. The C(49)-C(50) bond length is 1.47 Å. The C(49)-C(53,54) bond length is 1.40 Å. In the thirteenth C site, C(50) is bonded in a trigonal planar geometry to one C(45,46); one C(49); and one C(53,54) atom. The C(50)-C(45,46) bond length is 1.40 Å. The C(50)-C(53,54) bond length is 1.40 Å. In the fourteenth C site, C(53,54) is bonded in a distorted trigonal planar geometry to one C(49); one C(57); and one H(41,43,44) atom. The C(53,54)-C(57) bond length is 1.39 Å. The C(53,54)-H(41,43,44) bond length is 1.09 Å. In the fifteenth C site, C(57) is bonded in a distorted trigonal planar geometry to one C(53,54); one N(9); and one H(45,46) atom. The C(57)-N(9) bond length is 1.35 Å. The C(57)-H(45,46) bond length is 1.09 Å. In the sixteenth C site, C(58) is bonded in a distorted trigonal planar geometry to one C(53,54); one N(10); and one H(45,46) atom. The C(58)-C(53,54) bond length is 1.39 Å. The C(58)-N(10) bond length is 1.35 Å. The C(58)-H(45,46) bond length is 1.09 Å. There are nine inequivalent N sites. In the first N site, N(18) is bonded in a trigonal planar geometry to one O(13,14); one O(17,18); and one O(21,22) atom. The N(18)-O(13,14) bond length is 1.32 Å. The N(18)-O(17,18) bond length is 1.26 Å. The N(18)-O(21,22) bond length is 1.24 Å. In the second N site, N(17) is bonded in a trigonal planar geometry to one O(13,14); one O(17,18); and one O(21,22) atom. The N(17)-O(13,14) bond length is 1.31 Å. The N(17)-O(17,18) bond length is 1.26 Å. The N(17)-O(21,22) bond length is 1.24 Å. In the third N site, N(1,2) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(17) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one Zn(1), one C(21), and one C(37) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one Zn(2), one C(22), and one C(38) atom. In the sixth N site, N(9) is bonded in a trigonal planar geometry to one Zn(1), one C(41), and one C(57) atom. In the seventh N site, N(10) is bonded in a trigonal planar geometry to one Zn(2), one C(42), and one C(58) atom. In the eighth N site, N(13) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(9) atom. The N(13)-O(1) bond length is 1.30 Å. The N(13)-O(5) bond length is 1.26 Å. The N(13)-O(9) bond length is 1.24 Å. In the ninth N site, N(14) is bonded in a trigonal planar geometry to one O(10), one O(2), and one O(6) atom. The N(14)-O(10) bond length is 1.24 Å. The N(14)-O(2) bond length is 1.30 Å. The N(14)-O(6) bond length is 1.26 Å. There are ten inequivalent H sites. In the first H site, H(1,2,3) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(13,14,15) is bonded in a single-bond geometry to one C(17) atom. In the third H site, H(17,18) is bonded in a single-bond geometry to one C(21) atom. In the fourth H site, H(29,30) is bonded in a single-bond geometry to one C(37) atom. In the fifth H site, H(33,34) is bonded in a single-bond geometry to one C(41) atom. In the sixth H site, H(37,40) is bonded in a single-bond geometry to one C(45,46) atom. In the seventh H site, H(38,39) is bonded in a single-bond geometry to one C(45,46) atom. The H(38,39)-C(45,46) bond length is 1.09 Å. In the eighth H site, H(41,43,44) is bonded in a single-bond geometry to one C(53,54) atom. In the ninth H site, H(42) is bonded in a single-bond geometry to one C(53,54) atom. The H(42)-C(53,54) bond length is 1.09 Å. In the tenth H site, H(45,46) is bonded in a single-bond geometry to one C(57) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one N(13) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(2) and one N(14) atom. In the third O site, O(5) is bonded in a single-bond geometry to one N(13) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one N(14) atom. In the fifth O site, O(9) is bonded in a single-bond geometry to one N(13) atom. In the sixth O site, O(10) is bonded in a single-bond geometry to one N(14) atom. In the seventh O site, O(13,14) is bonded in a bent 120 degrees geometry to one Zn(1) and one N(17) atom. In the eighth O site, O(17,18) is bonded in a single-bond geometry to one N(17) atom. In the ninth O site, O(21,22) is bonded in a single-bond geometry to one N(17) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 4.16 A, density 1.40 g/cm3, surface area 4568.41 m2/g, accessible volume 0.33 cm3/g