MnC34H36(NO)10(CH3)2(C3H2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules; one 2,3-dimethyl-1,3-butadiene molecule; and one MnC34H36(NO)10 cluster. In the MnC34H36(NO)10 cluster, Mn(1) is bonded in an octahedral geometry to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Both Mn(1)-O(2) bond lengths are 2.07 Å. Both Mn(1)-O(3) bond lengths are 2.23 Å. Both Mn(1)-O(4) bond lengths are 2.19 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(8) atom. The C(2)-C(3) bond length is 1.44 Å. The C(2)-C(8) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one O(3) atom. The C(3)-C(4) bond length is 1.46 Å. The C(3)-O(3) bond length is 1.29 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.43 Å. The C(4)-C(7) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a 2-coordinate geometry to one C(4), one N(3), and one H(1) atom. The C(5)-N(3) bond length is 1.45 Å. The C(5)-H(1) bond length is 1.09 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(2), one N(3), and one N(4) atom. The C(6)-N(2) bond length is 1.35 Å. The C(6)-N(3) bond length is 1.32 Å. The C(6)-N(4) bond length is 1.38 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(4), one N(4), and one N(5) atom. The C(7)-N(4) bond length is 1.42 Å. The C(7)-N(5) bond length is 1.37 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(5), and one H(2) atom. The C(8)-N(5) bond length is 1.35 Å. The C(8)-H(2) bond length is 1.08 Å. In the ninth C site, C(9) is bonded in a 3-coordinate geometry to one N(5), one H(3), and one H(4) atom. The C(9)-N(5) bond length is 1.48 Å. The C(9)-H(3) bond length is 1.10 Å. The C(9)-H(4) bond length is 1.10 Å. In the tenth C site, C(11) is bonded in a 3-coordinate geometry to one N(2), one H(8), and one H(9) atom. The C(11)-N(2) bond length is 1.46 Å. The C(11)-H(8) bond length is 1.10 Å. The C(11)-H(9) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(10), and one H(11) atom. The C(12)-N(1) bond length is 1.49 Å. The C(12)-H(10) bond length is 1.10 Å. The C(12)-H(11) bond length is 1.10 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(12), and one H(13) atom. The C(13)-N(1) bond length is 1.49 Å. The C(13)-H(12) bond length is 1.09 Å. The C(13)-H(13) bond length is 1.10 Å. In the thirteenth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(14), and one H(15) atom. The C(14)-N(2) bond length is 1.46 Å. The C(14)-H(14) bond length is 1.10 Å. The C(14)-H(15) bond length is 1.10 Å. In the fourteenth C site, C(15) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(21) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(20) bond length is 1.40 Å. The C(15)-C(21) bond length is 1.50 Å. In the fifteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(16) atom. The C(16)-H(16) bond length is 1.09 Å. In the sixteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(15) and one H(19) atom. The C(20)-H(19) bond length is 1.09 Å. In the seventeenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(4), and one O(5) atom. The C(21)-O(4) bond length is 1.29 Å. The C(21)-O(5) bond length is 1.27 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a tetrahedral geometry to one C(12), one C(13), one H(20), and one H(21) atom. The N(1)-H(20) bond length is 1.09 Å. The N(1)-H(21) bond length is 1.06 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(5), one C(6), and one H(22) atom. The N(3)-H(22) bond length is 1.04 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one H(23) atom. The N(4)-H(23) bond length is 1.02 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(7), one C(8), and one C(9) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the fifteenth H site, H(20) is bonded in a linear geometry to one N(1) and one O(1) atom. The H(20)-O(1) bond length is 1.57 Å. In the sixteenth H site, H(21) is bonded in a single-bond geometry to one N(1) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one N(3) atom. In the eighteenth H site, H(23) is bonded in a single-bond geometry to one N(4) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(1) and one H(20) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(21) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one C(21) atom. Linkers: 2 CCN1[CH]C(=C(C2=C1N[C](N[CH]2)N1CC[NH2]CC1)[O])C(=O)[O] ,2 [C]c1ccc(-c2ccc(C([O])=O)cc2)cc1 ,1 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cc2)cc1. Metal clusters: 1 [O][Mn]([O])(O[C]=O)(O[C]=O)(O[C]=O)O[C]=O. The MOF has largest included sphere 1.84 A, density 1.64 g/cm3, surface area 4020.22 m2/g, accessible volume 0.12 cm3/g