CdC11H8(NO2)2CH2CHO crystallizes in the monoclinic C2/c space group. The structure consists of eight 02329_fluka molecules and eight methanol molecules inside a CdC11H8(NO2)2 framework. In the CdC11H8(NO2)2 framework, Cd(1) is bonded in a 7-coordinate geometry to one N(1), one O(1), one O(2), two equivalent O(4), and two equivalent O(5) atoms. The Cd(1)-N(1) bond length is 2.23 Å. The Cd(1)-O(1) bond length is 2.24 Å. The Cd(1)-O(2) bond length is 2.69 Å. There is one shorter (2.46 Å) and one longer (2.58 Å) Cd(1)-O(4) bond length. There is one shorter (2.36 Å) and one longer (2.52 Å) Cd(1)-O(5) bond length. There are eleven inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-C(8) bond length is 1.40 Å. The C(9)-H(7) bond length is 1.09 Å. In the second C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(4), and one O(5) atom. The C(10)-C(8) bond length is 1.49 Å. The C(10)-O(4) bond length is 1.28 Å. The C(10)-O(5) bond length is 1.28 Å. In the third C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(8), and one H(9) atom. The C(12)-N(2) bond length is 1.46 Å. The C(12)-H(8) bond length is 1.10 Å. The C(12)-H(9) bond length is 1.10 Å. In the fourth C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(6) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(5) bond length is 1.50 Å. The C(1)-C(6) bond length is 1.40 Å. In the fifth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(8), and one H(1) atom. The C(2)-C(8) bond length is 1.40 Å. The C(2)-H(1) bond length is 1.09 Å. In the sixth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(2) atom. The C(3)-C(4) bond length is 1.37 Å. The C(3)-N(2) bond length is 1.38 Å. The C(3)-H(2) bond length is 1.08 Å. In the seventh C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(3) atom. The C(4)-N(1) bond length is 1.38 Å. The C(4)-H(3) bond length is 1.08 Å. In the eighth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(5)-O(1) bond length is 1.29 Å. The C(5)-O(2) bond length is 1.26 Å. In the ninth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 1.09 Å. In the tenth C site, C(7) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(5) atom. The C(7)-N(1) bond length is 1.33 Å. The C(7)-N(2) bond length is 1.35 Å. The C(7)-H(5) bond length is 1.08 Å. In the eleventh C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(9) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(4), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(7) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cd(1) and one C(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cd(1) and one C(5) atom. In the third O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(10) atom. In the fourth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(10) atom. Linkers: 2 c1cn(CCCCn2ccnc2)cn1 ,4 [O]C(=O)c1cc(O)cc(C([O])=O)c1. Metal clusters: 4 [Cd]. RCSR code: umc. The MOF has largest included sphere 2.29 A, density 1.98 g/cm3, surface area 3609.77 m2/g, accessible volume 0.11 cm3/g