CuC5H7(NO)3CHCH2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four 02329_fluka molecules, and two CuC5H7(NO)3 clusters. In each CuC5H7(NO)3 cluster, Cu(1) is bonded in a 5-coordinate geometry to one C(1), one C(2), one N(2), and two equivalent O(3) atoms. The Cu(1)-C(1) bond length is 2.00 Å. The Cu(1)-C(2) bond length is 2.00 Å. The Cu(1)-N(2) bond length is 1.89 Å. There is one shorter (2.02 Å) and one longer (2.59 Å) Cu(1)-O(3) bond length. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1), one H(1), and one H(2) atom. The C(1)-H(1) bond length is 1.09 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one Cu(1) and one H(3) atom. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(4), and one H(5) atom. The C(3)-N(1) bond length is 1.49 Å. The C(3)-H(4) bond length is 1.10 Å. The C(3)-H(5) bond length is 1.10 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(6), and one H(7) atom. The C(4)-N(1) bond length is 1.48 Å. The C(4)-H(6) bond length is 1.10 Å. The C(4)-H(7) bond length is 1.10 Å. In the fifth C site, C(7) is bonded in a linear geometry to one N(1) and one N(2) atom. The C(7)-N(1) bond length is 1.30 Å. The C(7)-N(2) bond length is 1.17 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(7) atom. In the second N site, N(2) is bonded in a linear geometry to one Cu(1) and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(3)-O(1) bond length is 1.25 Å. The N(3)-O(2) bond length is 1.25 Å. The N(3)-O(3) bond length is 1.31 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to two equivalent Cu(1) and one N(3) atom. Linkers: 4 [CH2][CH]CN(C#N)CC=C. Metal clusters: 4 [Cu]. The MOF has largest included sphere 1.93 A, density 1.68 g/cm3, surface area 4795.95 m2/g, accessible volume 0.12 cm3/g