Zn2C22N8H30S2O15 crystallizes in the monoclinic P2/c space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal bipyramidal geometry to two equivalent N(2), one O(5), and two equivalent O(3) atoms. Both Zn(1)-N(2) bond lengths are 2.04 Å. The Zn(1)-O(5) bond length is 2.00 Å. Both Zn(1)-O(3) bond lengths are 2.22 Å. In the second Zn site, Zn(2) is bonded to two equivalent N(1), two equivalent O(2), and two equivalent O(8) atoms to form ZnN2O4 octahedra that share corners with two equivalent S(1)O4 tetrahedra. Both Zn(2)-N(1) bond lengths are 2.06 Å. Both Zn(2)-O(2) bond lengths are 2.24 Å. Both Zn(2)-O(8) bond lengths are 2.20 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(11), one C(2), and one H(2) atom. The C(1)-C(11) bond length is 1.39 Å. The C(1)-C(2) bond length is 1.39 Å. The C(1)-H(2) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(2), and one H(3) atom. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(3) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(11), one C(7), and one N(3) atom. The C(3)-C(11) bond length is 1.41 Å. The C(3)-C(7) bond length is 1.41 Å. The C(3)-N(3) bond length is 1.39 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(8) and one H(4) atom. The C(4)-C(8) bond length is 1.41 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(8), one N(1), and one H(5) atom. The C(5)-C(8) bond length is 1.41 Å. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(5) bond length is 1.08 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(3), one N(4), and one O(7) atom. The C(6)-N(3) bond length is 1.38 Å. The C(6)-N(4) bond length is 1.38 Å. The C(6)-O(7) bond length is 1.24 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one H(7) atom. The C(7)-N(2) bond length is 1.34 Å. The C(7)-H(7) bond length is 1.08 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(4), one C(5), and one N(4) atom. The C(8)-N(4) bond length is 1.39 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(8) bond length is 1.09 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(9) atom. The C(10)-N(1) bond length is 1.35 Å. The C(10)-H(9) bond length is 1.09 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(10) atom. The C(11)-H(10) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(10), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(2), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(3), one C(6), and one H(1) atom. The N(3)-H(1) bond length is 1.04 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(6), one C(8), and one H(6) atom. The N(4)-H(6) bond length is 1.04 Å. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a distorted single-bond geometry to one N(4) and one O(4) atom. The H(6)-O(4) bond length is 1.71 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(11) is bonded in a distorted single-bond geometry to one O(5) and one O(6) atom. The H(11)-O(5) bond length is 1.01 Å. The H(11)-O(6) bond length is 1.65 Å. In the twelfth H site, H(12) is bonded in a distorted single-bond geometry to one O(1) and one O(2) atom. The H(12)-O(1) bond length is 1.64 Å. The H(12)-O(2) bond length is 1.01 Å. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one O(3) atom. The H(13)-O(3) bond length is 0.97 Å. In the fourteenth H site, H(14) is bonded in a distorted linear geometry to one O(3) and one O(4) atom. The H(14)-O(3) bond length is 1.01 Å. The H(14)-O(4) bond length is 1.61 Å. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one O(2) atom. The H(15)-O(2) bond length is 0.97 Å. S(1) is bonded to one O(1), one O(4), one O(6), and one O(8) atom to form SO4 tetrahedra that share  a cornercorner with one Zn(2)N2O4 octahedra. The corner-sharing octahedral tilt angles are 48°. The S(1)-O(1) bond length is 1.51 Å. The S(1)-O(4) bond length is 1.51 Å. The S(1)-O(6) bond length is 1.48 Å. The S(1)-O(8) bond length is 1.49 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one H(12) and one S(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Zn(2), one H(12), and one H(15) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Zn(1), one H(13), and one H(14) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one H(14), one H(6), and one S(1) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Zn(1) and two equivalent H(11) atoms. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one H(11) and one S(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one S(1) atom. Linkers: 2 O.O.O.O=C(NC1=CC=CN([Zn]N2[CH]C=CC(NC(=O)Nc3cccnc3)=C2)[CH]1)Nc1cccnc1. Metal clusters: 2 O.O.[O]S([O])([O])O[Zn]OS([O])([O])[O]. The MOF has largest included sphere 3.01 A, density 1.64 g/cm3, surface area 4183.40 m2/g, accessible volume 0.17 cm3/g