KC13NH28SeO6 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one KC13NH28SeO6 cluster. K(1) is bonded in a 10-coordinate geometry to one N(1), one H(25), two equivalent Se(1), one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The K(1)-N(1) bond length is 2.92 Å. The K(1)-H(25) bond length is 2.88 Å. There is one shorter (3.24 Å) and one longer (3.34 Å) K(1)-Se(1) bond length. The K(1)-O(1) bond length is 2.89 Å. The K(1)-O(2) bond length is 3.10 Å. The K(1)-O(3) bond length is 2.97 Å. The K(1)-O(4) bond length is 2.88 Å. The K(1)-O(5) bond length is 2.81 Å. The K(1)-O(6) bond length is 3.04 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one O(5) atom. The C(1)-H(1) bond length is 1.11 Å. The C(1)-H(2) bond length is 1.11 Å. The C(1)-O(5) bond length is 1.42 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(4), and one O(6) atom. The C(2)-H(3) bond length is 1.11 Å. The C(2)-H(4) bond length is 1.11 Å. The C(2)-O(6) bond length is 1.43 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(6), and one O(2) atom. The C(3)-H(5) bond length is 1.11 Å. The C(3)-H(6) bond length is 1.11 Å. The C(3)-O(2) bond length is 1.43 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one H(7), one H(8), and one O(3) atom. The C(4)-H(7) bond length is 1.11 Å. The C(4)-H(8) bond length is 1.11 Å. The C(4)-O(3) bond length is 1.44 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one H(10), one H(9), and one O(4) atom. The C(5)-H(10) bond length is 1.11 Å. The C(5)-H(9) bond length is 1.10 Å. The C(5)-O(4) bond length is 1.43 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one H(11), one H(12), and one O(4) atom. The C(6)-H(11) bond length is 1.10 Å. The C(6)-H(12) bond length is 1.11 Å. The C(6)-O(4) bond length is 1.43 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one H(13), one H(14), and one O(1) atom. The C(7)-H(13) bond length is 1.11 Å. The C(7)-H(14) bond length is 1.10 Å. The C(7)-O(1) bond length is 1.43 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one H(15), one H(16), and one O(6) atom. The C(8)-H(15) bond length is 1.11 Å. The C(8)-H(16) bond length is 1.11 Å. The C(8)-O(6) bond length is 1.43 Å. In the ninth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one H(17), one H(18), and one O(3) atom. The C(9)-H(17) bond length is 1.11 Å. The C(9)-H(18) bond length is 1.11 Å. The C(9)-O(3) bond length is 1.43 Å. In the tenth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one H(19), one H(20), and one O(2) atom. The C(10)-H(19) bond length is 1.10 Å. The C(10)-H(20) bond length is 1.10 Å. The C(10)-O(2) bond length is 1.44 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one H(21), one H(22), and one O(5) atom. The C(11)-H(21) bond length is 1.11 Å. The C(11)-H(22) bond length is 1.11 Å. The C(11)-O(5) bond length is 1.42 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(23,24) and one O(1) atom. Both C(12)-H(23,24) bond lengths are 1.11 Å. The C(12)-O(1) bond length is 1.42 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(27), and one H(28) atom. The C(13)-N(1) bond length is 1.46 Å. The C(13)-H(27) bond length is 1.11 Å. The C(13)-H(28) bond length is 1.10 Å. N(1) is bonded in a distorted trigonal non-coplanar geometry to one K(1), one C(13), one H(25), and one H(26) atom. The N(1)-H(25) bond length is 1.02 Å. The N(1)-H(26) bond length is 1.02 Å. There are twenty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(7) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(7) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(8) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(8) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(9) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(9) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(10) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(10) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(11) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(11) atom. In the twenty-third H site, H(23,24) is bonded in a single-bond geometry to one C(12) atom. In the twenty-fourth H site, H(25) is bonded in a single-bond geometry to one K(1) and one N(1) atom. In the twenty-fifth H site, H(26) is bonded in a single-bond geometry to one N(1) atom. In the twenty-sixth H site, H(27) is bonded in a single-bond geometry to one C(13) atom. In the twenty-seventh H site, H(28) is bonded in a single-bond geometry to one C(13) atom. Se(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Se(1) atom. The Se(1)-Se(1) bond length is 2.43 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one K(1), one C(12), and one C(7) atom. In the second O site, O(2) is bonded in a water-like geometry to one K(1), one C(10), and one C(3) atom. In the third O site, O(3) is bonded in a water-like geometry to one K(1), one C(4), and one C(9) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one K(1), one C(5), and one C(6) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one K(1), one C(1), and one C(11) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one K(1), one C(2), and one C(8) atom. Linkers: 2 C1COCCOCCOCCOCCOCCO1. Metal clusters: 2 [K]. The MOF has largest included sphere 2.10 A, density 1.53 g/cm3, surface area 4369.98 m2/g, accessible volume 0.13 cm3/g