ZnC26H18(NO2)2(CH)2C14NH10C2NH2(C5H4O)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules; eight 1,3-bis(methoxymethyl)benzene molecules; eight n-methyl methanimine molecules; eight schembl10066584 molecules; and four ZnC26H18(NO2)2 clusters. In each ZnC26H18(NO2)2 cluster, Zn(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.18 Å. The Zn(1)-N(2) bond length is 2.14 Å. The Zn(1)-O(1) bond length is 2.49 Å. The Zn(1)-O(2) bond length is 2.12 Å. The Zn(1)-O(3) bond length is 2.05 Å. The Zn(1)-O(4) bond length is 2.04 Å. There are twenty-six inequivalent C sites. In the first C site, C(15) is bonded in a distorted single-bond geometry to one C(17), one C(9), and one H(10) atom. The C(15)-C(17) bond length is 1.39 Å. The C(15)-C(9) bond length is 1.41 Å. The C(15)-H(10) bond length is 1.09 Å. In the second C site, C(17) is bonded in a distorted trigonal planar geometry to one C(15), one N(1), and one H(12) atom. The C(17)-N(1) bond length is 1.35 Å. The C(17)-H(12) bond length is 1.09 Å. In the third C site, C(18) is bonded in a distorted trigonal planar geometry to one N(1) and one H(13) atom. The C(18)-N(1) bond length is 1.35 Å. The C(18)-H(13) bond length is 1.09 Å. In the fourth C site, C(19) is bonded in a trigonal planar geometry to one C(24), one C(27), and one C(9) atom. The C(19)-C(24) bond length is 1.41 Å. The C(19)-C(27) bond length is 1.41 Å. The C(19)-C(9) bond length is 1.48 Å. In the fifth C site, C(20) is bonded in a distorted single-bond geometry to one C(31) and one H(14) atom. The C(20)-C(31) bond length is 1.39 Å. The C(20)-H(14) bond length is 1.09 Å. In the sixth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(3), and one O(4) atom. The C(21)-C(12) bond length is 1.50 Å. The C(21)-O(3) bond length is 1.27 Å. The C(21)-O(4) bond length is 1.28 Å. In the seventh C site, C(22) is bonded in a distorted single-bond geometry to one C(28), one C(31), and one H(15) atom. The C(22)-C(28) bond length is 1.40 Å. The C(22)-C(31) bond length is 1.40 Å. The C(22)-H(15) bond length is 1.09 Å. In the eighth C site, C(23) is bonded in a trigonal planar geometry to one C(32), one C(35), and one C(7) atom. The C(23)-C(32) bond length is 1.41 Å. The C(23)-C(35) bond length is 1.41 Å. The C(23)-C(7) bond length is 1.48 Å. In the ninth C site, C(24) is bonded in a distorted single-bond geometry to one C(19) and one H(16) atom. The C(24)-H(16) bond length is 1.09 Å. In the tenth C site, C(27) is bonded in a distorted single-bond geometry to one C(19) and one H(19) atom. The C(27)-H(19) bond length is 1.09 Å. In the eleventh C site, C(28) is bonded in a trigonal planar geometry to one C(2), one C(22), and one C(6) atom. The C(28)-C(2) bond length is 1.50 Å. The C(28)-C(6) bond length is 1.40 Å. In the twelfth C site, C(30) is bonded in a distorted single-bond geometry to one C(38), one C(7), and one H(21) atom. The C(30)-C(38) bond length is 1.39 Å. The C(30)-C(7) bond length is 1.41 Å. The C(30)-H(21) bond length is 1.09 Å. In the thirteenth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one H(22) atom. The C(31)-H(22) bond length is 1.09 Å. In the fourteenth C site, C(32) is bonded in a distorted single-bond geometry to one C(23) and one H(23,25) atom. The C(32)-H(23,25) bond length is 1.09 Å. In the fifteenth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(36), one N(2), and one H(1) atom. The C(1)-C(36) bond length is 1.39 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the sixteenth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(1), and one O(2) atom. The C(2)-O(1) bond length is 1.26 Å. The C(2)-O(2) bond length is 1.29 Å. In the seventeenth C site, C(35) is bonded in a distorted single-bond geometry to one C(23) and one H(23,25) atom. The C(35)-H(23,25) bond length is 1.09 Å. In the eighteenth C site, C(4) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(4)-C(9) bond length is 1.41 Å. The C(4)-H(4) bond length is 1.09 Å. In the nineteenth C site, C(36) is bonded in a distorted single-bond geometry to one C(1), one C(7), and one H(26) atom. The C(36)-C(7) bond length is 1.41 Å. The C(36)-H(26) bond length is 1.09 Å. In the twentieth C site, C(6) is bonded in a distorted single-bond geometry to one C(28) and one H(6) atom. The C(6)-H(6) bond length is 1.09 Å. In the twenty-first C site, C(38) is bonded in a distorted trigonal planar geometry to one C(30), one N(2), and one H(28) atom. The C(38)-N(2) bond length is 1.35 Å. The C(38)-H(28) bond length is 1.09 Å. In the twenty-second C site, C(7) is bonded in a trigonal planar geometry to one C(23), one C(30), and one C(36) atom. In the twenty-third C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(8) atom. The C(13)-C(12) bond length is 1.40 Å. The C(13)-H(8) bond length is 1.09 Å. In the twenty-fourth C site, C(9) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(4) atom. In the twenty-fifth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(7) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(7) bond length is 1.09 Å. In the twenty-sixth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(21) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(17), and one C(18) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(38) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(30) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(31) atom. In the fifteenth H site, H(23,25) is bonded in a single-bond geometry to one C(32) atom. In the sixteenth H site, H(26) is bonded in a single-bond geometry to one C(36) atom. In the seventeenth H site, H(28) is bonded in a single-bond geometry to one C(38) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Zn(1) and one C(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(21) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(21) atom. Linkers: 4 [O]C(=O)c1cccc(OCc2cccc(COc3cccc(C([O])=O)c3)c2)c1. Metal clusters: 2 O=[C]O[Zn]1O[C]O[Zn](O[C]=O)O[C]O1. The MOF has largest included sphere 2.32 A, density 1.45 g/cm3, surface area 5133.86 m2/g, accessible volume 0.14 cm3/g