Ag3C9H12S2(N3O2)3(CH2)3SO3 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two sulfur trioxide molecules, and one Ag3C9H12S2(N3O2)3 cluster. In the Ag3C9H12S2(N3O2)3 cluster, there are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one N(4), one N(8), and one O(2) atom. The Ag(1)-N(4) bond length is 2.14 Å. The Ag(1)-N(8) bond length is 2.15 Å. The Ag(1)-O(2) bond length is 2.62 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one N(2), one N(5), and one O(1) atom. The Ag(2)-N(2) bond length is 2.12 Å. The Ag(2)-N(5) bond length is 2.11 Å. The Ag(2)-O(1) bond length is 2.70 Å. In the third Ag site, Ag(3) is bonded in a distorted see-saw-like geometry to one N(1), one N(7), one O(1), and one O(6) atom. The Ag(3)-N(1) bond length is 2.12 Å. The Ag(3)-N(7) bond length is 2.12 Å. The Ag(3)-O(1) bond length is 2.68 Å. The Ag(3)-O(6) bond length is 2.59 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-N(3) bond length is 1.36 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(2) atom. The C(2)-N(2) bond length is 1.32 Å. The C(2)-N(3) bond length is 1.36 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(3), and one H(4) atom. The C(3)-N(3) bond length is 1.46 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(4) bond length is 1.10 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(7) atom. The C(5)-N(5) bond length is 1.32 Å. The C(5)-N(6) bond length is 1.36 Å. The C(5)-H(7) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(8) atom. The C(6)-N(4) bond length is 1.32 Å. The C(6)-N(6) bond length is 1.36 Å. The C(6)-H(8) bond length is 1.09 Å. In the sixth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(6), one H(10), and one H(9) atom. The C(7)-N(6) bond length is 1.47 Å. The C(7)-H(10) bond length is 1.10 Å. The C(7)-H(9) bond length is 1.10 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(13) atom. The C(9)-N(7) bond length is 1.32 Å. The C(9)-N(9) bond length is 1.36 Å. The C(9)-H(13) bond length is 1.09 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one N(8), one N(9), and one H(14) atom. The C(10)-N(8) bond length is 1.32 Å. The C(10)-N(9) bond length is 1.36 Å. The C(10)-H(14) bond length is 1.08 Å. In the ninth C site, C(11) is bonded in a 3-coordinate geometry to one N(9), one H(15), and one H(16) atom. The C(11)-N(9) bond length is 1.47 Å. The C(11)-H(15) bond length is 1.10 Å. The C(11)-H(16) bond length is 1.10 Å. There are nine inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(3), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.38 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(2), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(6), and one N(5) atom. The N(4)-N(5) bond length is 1.38 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(5), and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(7) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Ag(3), one C(9), and one N(8) atom. The N(7)-N(8) bond length is 1.38 Å. In the eighth N site, N(8) is bonded in a 3-coordinate geometry to one Ag(1), one C(10), and one N(7) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(9) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.47 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. The S(2)-O(4) bond length is 1.46 Å. The S(2)-O(5) bond length is 1.47 Å. The S(2)-O(6) bond length is 1.49 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(2), one Ag(3), and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Ag(3) and one S(2) atom. Linkers: 6 [O]S([O])([O])CCn1cnnc1. Metal clusters: 1 N1=N\[Ag]/N=N\[Ag](=[Ag]2/N=N\[Ag]/N=N\[Ag]/N=N\2)/N=N\[Ag]/1.O=S(=O)=O.O=S(=O)=O.O=S(=O)=O.O=S(=O)=O. The MOF has largest included sphere 3.93 A, density 2.11 g/cm3, surface area 3040.56 m2/g, accessible volume 0.17 cm3/g