CdC24N5H14(OF)6H4(C3F)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CdC24N5H14(OF)6 clusters and one H4(C3F)3 cluster. In each CdC24N5H14(OF)6 cluster, Cd(1) is bonded in a pentagonal bipyramidal geometry to one N(1), one N(2), one N(3), one O(1), one O(2), one O(4), and one O(5) atom. The Cd(1)-N(1) bond length is 2.32 Å. The Cd(1)-N(2) bond length is 2.35 Å. The Cd(1)-N(3) bond length is 2.35 Å. The Cd(1)-O(1) bond length is 2.58 Å. The Cd(1)-O(2) bond length is 2.41 Å. The Cd(1)-O(4) bond length is 2.57 Å. The Cd(1)-O(5) bond length is 2.42 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.09 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(1) and one H(2) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-H(3) bond length is 1.09 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(4) bond length is 1.09 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.52 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one C(5), one C(7), one H(5), and one H(6) atom. The C(6)-C(7) bond length is 1.51 Å. The C(6)-H(5) bond length is 1.10 Å. The C(6)-H(6) bond length is 1.10 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-C(9) bond length is 1.38 Å. In the eighth C site, C(8) is bonded in a single-bond geometry to one C(7) and one F(1) atom. The C(8)-F(1) bond length is 1.36 Å. In the ninth C site, C(9) is bonded in a single-bond geometry to one C(11), one C(7), and one F(2) atom. The C(9)-C(11) bond length is 1.42 Å. The C(9)-F(2) bond length is 1.36 Å. In the tenth C site, C(10) is bonded in a single-bond geometry to one C(12) and one F(3) atom. The C(10)-C(12) bond length is 1.42 Å. The C(10)-F(3) bond length is 1.36 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(9) atom. The C(11)-C(12) bond length is 1.44 Å. The C(11)-C(13) bond length is 1.41 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(14) atom. The C(12)-C(14) bond length is 1.42 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(11) and one F(4) atom. The C(13)-F(4) bond length is 1.35 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one F(5) atom. The C(14)-C(16) bond length is 1.38 Å. The C(14)-F(5) bond length is 1.37 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one F(6) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-F(6) bond length is 1.35 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(17) atom. The C(16)-C(17) bond length is 1.51 Å. In the seventeenth C site, C(17) is bonded in a distorted water-like geometry to one C(16), one C(18), one H(7), and one H(8) atom. The C(17)-C(18) bond length is 1.51 Å. The C(17)-H(7) bond length is 1.10 Å. The C(17)-H(8) bond length is 1.10 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(20) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(20) bond length is 1.40 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(21), and one H(9) atom. The C(19)-C(21) bond length is 1.39 Å. The C(19)-H(9) bond length is 1.09 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(18), one C(22), and one H(10) atom. The C(20)-C(22) bond length is 1.39 Å. The C(20)-H(10) bond length is 1.09 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(19), one N(2), and one H(11) atom. The C(21)-N(2) bond length is 1.35 Å. The C(21)-H(11) bond length is 1.09 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(20), one N(2), and one H(12) atom. The C(22)-N(2) bond length is 1.35 Å. The C(22)-H(12) bond length is 1.09 Å. In the twenty-third C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(13,14) atom. The C(23)-N(3) bond length is 1.35 Å. The C(23)-H(13,14) bond length is 1.09 Å. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(13,14) atom. The C(24)-N(3) bond length is 1.35 Å. The C(24)-H(13,14) bond length is 1.09 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(21), and one C(22) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(23), and one C(24) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. The N(4)-O(4) bond length is 1.28 Å. The N(4)-O(5) bond length is 1.29 Å. The N(4)-O(6) bond length is 1.24 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(5)-O(1) bond length is 1.29 Å. The N(5)-O(2) bond length is 1.29 Å. The N(5)-O(3) bond length is 1.24 Å. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(13,14) is bonded in a single-bond geometry to one C(23) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one N(5) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cd(1) and one N(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(5) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one N(4) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Cd(1) and one N(4) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(4) atom. There are six inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one C(9) atom. In the second F site, F(3) is bonded in a single-bond geometry to one C(10) atom. In the third F site, F(4) is bonded in a single-bond geometry to one C(13) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one C(14) atom. In the fifth F site, F(6) is bonded in a single-bond geometry to one C(15) atom. In the sixth F site, F(1) is bonded in a single-bond geometry to one C(8) atom. In the H4(C3F)3 cluster, there are nine inequivalent C sites. In the first C site, C(30) is bonded in a single-bond geometry to one C(29), one C(31), and one F(7) atom. The C(30)-C(29) bond length is 1.38 Å. The C(30)-C(31) bond length is 1.41 Å. The C(30)-F(7) bond length is 1.36 Å. In the second C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(31), and one C(32) atom. The C(31)-C(31) bond length is 1.44 Å. The C(31)-C(32) bond length is 1.42 Å. In the third C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one F(8) atom. The C(32)-F(8) bond length is 1.36 Å. In the fourth C site, C(33) is bonded in a distorted single-bond geometry to one C(29) and one F(9) atom. The C(33)-C(29) bond length is 1.41 Å. The C(33)-F(9) bond length is 1.36 Å. In the fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(27) and one H(15) atom. The C(25)-C(27) bond length is 1.40 Å. The C(25)-H(15) bond length is 1.09 Å. In the sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(27) and one H(16) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-H(16) bond length is 1.09 Å. In the seventh C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(33) atom. The C(29)-C(28) bond length is 1.51 Å. In the eighth C site, C(27) is bonded in a trigonal planar geometry to one C(25), one C(26), and one C(28) atom. The C(27)-C(28) bond length is 1.51 Å. In the ninth C site, C(28) is bonded in a distorted water-like geometry to one C(27), one C(29), one H(17), and one H(18) atom. The C(28)-H(17) bond length is 1.10 Å. The C(28)-H(18) bond length is 1.10 Å. There are four inequivalent H sites. In the first H site, H(16) is bonded in a single-bond geometry to one C(26) atom. In the second H site, H(17) is bonded in a single-bond geometry to one C(28) atom. In the third H site, H(18) is bonded in a single-bond geometry to one C(28) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. There are three inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one C(30) atom. In the second F site, F(8) is bonded in a single-bond geometry to one C(32) atom. In the third F site, F(9) is bonded in a single-bond geometry to one C(33) atom. Linkers: 2 Fc1c(Cc2ccncc2)c(F)c2c(F)c(F)c(Cc3ccncc3)c(F)c2c1F. Metal clusters: 2 [Cd]. The MOF has largest included sphere 3.75 A, density 1.72 g/cm3, surface area 4158.72 m2/g, accessible volume 0.10 cm3/g