CuC12H16(N6Cl)2(CH2)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two CuC12H16(N6Cl)2 clusters. In each CuC12H16(N6Cl)2 cluster, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent N(1), two equivalent N(6), and two equivalent Cl(1) atoms. Both Cu(1)-N(1) bond lengths are 2.00 Å. Both Cu(1)-N(6) bond lengths are 2.03 Å. Both Cu(1)-Cl(1) bond lengths are 2.89 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-N(3) bond length is 1.33 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(2) bond length is 1.34 Å. The C(2)-H(2) bond length is 1.09 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(3), and one H(4) atom. The C(3)-N(2) bond length is 1.45 Å. The C(3)-H(3) bond length is 1.10 Å. The C(3)-H(4) bond length is 1.10 Å. In the fourth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(10), and one H(9) atom. The C(6)-N(4) bond length is 1.46 Å. The C(6)-H(10) bond length is 1.10 Å. The C(6)-H(9) bond length is 1.10 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(11) atom. The C(7)-N(4) bond length is 1.34 Å. The C(7)-N(6) bond length is 1.34 Å. The C(7)-H(11) bond length is 1.08 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(12) atom. The C(8)-N(5) bond length is 1.33 Å. The C(8)-N(6) bond length is 1.37 Å. The C(8)-H(12) bond length is 1.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one N(3) atom. The N(2)-N(3) bond length is 1.37 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(1) and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one N(5) atom. The N(4)-N(5) bond length is 1.36 Å. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(8) and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(7), and one C(8) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(8) atom. Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 4 [CH]1N=C[N]N1CCCCn1cncn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 1.56 A, density 1.67 g/cm3, surface area 4848.29 m2/g, accessible volume 0.10 cm3/g