NaB2C6NH18O2(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and one NaB2C6NH18O2 cluster. In the NaB2C6NH18O2 cluster, Na(1) is bonded in a 9-coordinate geometry to one H(1), one H(4), one H(5), two equivalent H(2), two equivalent H(3), one O(1), and one O(2) atom. The Na(1)-H(1) bond length is 2.43 Å. The Na(1)-H(4) bond length is 2.36 Å. The Na(1)-H(5) bond length is 2.38 Å. There is one shorter (2.34 Å) and one longer (2.62 Å) Na(1)-H(2) bond length. There is one shorter (2.43 Å) and one longer (2.62 Å) Na(1)-H(3) bond length. The Na(1)-O(1) bond length is 2.37 Å. The Na(1)-O(2) bond length is 2.39 Å. There are two inequivalent B sites. In the first B site, B(1) is bonded to one N(1), one H(1), one H(2), and one H(3) atom to form corner-sharing BH3N tetrahedra. The B(1)-N(1) bond length is 1.58 Å. The B(1)-H(1) bond length is 1.23 Å. The B(1)-H(2) bond length is 1.22 Å. The B(1)-H(3) bond length is 1.23 Å. In the second B site, B(2) is bonded to one N(1), one H(4), one H(5), and one H(6) atom to form corner-sharing BH3N tetrahedra. The B(2)-N(1) bond length is 1.59 Å. The B(2)-H(4) bond length is 1.23 Å. The B(2)-H(5) bond length is 1.22 Å. The B(2)-H(6) bond length is 1.22 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(7), and one H(8) atom. The C(1)-N(1) bond length is 1.50 Å. The C(1)-H(7) bond length is 1.10 Å. The C(1)-H(8) bond length is 1.09 Å. In the second C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(13), and one H(14) atom. The C(4)-N(1) bond length is 1.49 Å. The C(4)-H(13) bond length is 1.09 Å. The C(4)-H(14) bond length is 1.10 Å. In the third C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one H(15), one H(16), and one O(1) atom. The C(5)-H(15) bond length is 1.10 Å. The C(5)-H(16) bond length is 1.10 Å. The C(5)-O(1) bond length is 1.44 Å. In the fourth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one H(17), one H(18), and one O(1) atom. The C(6)-H(17) bond length is 1.10 Å. The C(6)-H(18) bond length is 1.11 Å. The C(6)-O(1) bond length is 1.44 Å. In the fifth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one H(19), one H(20), and one O(2) atom. The C(7)-H(19) bond length is 1.10 Å. The C(7)-H(20) bond length is 1.10 Å. The C(7)-O(2) bond length is 1.44 Å. In the sixth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one H(21), one H(22), and one O(2) atom. The C(8)-H(21) bond length is 1.10 Å. The C(8)-H(22) bond length is 1.11 Å. The C(8)-O(2) bond length is 1.44 Å. N(1) is bonded in a tetrahedral geometry to one B(1), one B(2), one C(1), and one C(4) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one Na(1) and one B(1) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to two equivalent Na(1) and one B(1) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to two equivalent Na(1) and one B(1) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one Na(1) and one B(2) atom. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one Na(1) and one B(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one B(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(1) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(1) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(4) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(5) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(5) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(6) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(6) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(7) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(7) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(8) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(8) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one C(5), and one C(6) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Na(1), one C(7), and one C(8) atom. Linkers: 2 [BH3][N]1([BH3])CCCC1 ,1 C1COCCO1. Metal clusters: 2 [Na]. The MOF has largest included sphere 2.23 A, density 1.18 g/cm3, surface area 5845.10 m2/g, accessible volume 0.13 cm3/g