(CH2)2ZnC10N4H9O4Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two ZnC10N4H9O4Cl clusters. In each ZnC10N4H9O4Cl cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one O(3), and one Cl(1) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-N(3) bond length is 2.03 Å. The Zn(1)-O(3) bond length is 1.97 Å. The Zn(1)-Cl(1) bond length is 2.21 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one N(2) atom. The C(1)-C(7) bond length is 1.46 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(1) bond length is 1.38 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.38 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one H(4), and one H(5) atom. The C(4)-N(2) bond length is 1.46 Å. The C(4)-H(4) bond length is 1.10 Å. The C(4)-H(5) bond length is 1.10 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(6)-O(1) bond length is 1.23 Å. The C(6)-O(2) bond length is 1.34 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(1), one N(3), and one N(4) atom. The C(7)-N(3) bond length is 1.34 Å. The C(7)-N(4) bond length is 1.36 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(3), and one H(8) atom. The C(8)-C(9) bond length is 1.37 Å. The C(8)-N(3) bond length is 1.38 Å. The C(8)-H(8) bond length is 1.08 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(4), and one H(9) atom. The C(9)-N(4) bond length is 1.38 Å. The C(9)-H(9) bond length is 1.09 Å. In the ninth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(10), and one H(11) atom. The C(10)-N(4) bond length is 1.47 Å. The C(10)-H(10) bond length is 1.10 Å. The C(10)-H(11) bond length is 1.10 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(12)-O(3) bond length is 1.29 Å. The C(12)-O(4) bond length is 1.26 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(7), and one C(8) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(4) atom. The H(1)-O(2) bond length is 1.03 Å. The H(1)-O(4) bond length is 1.55 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a water-like geometry to one C(6) and one H(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(12) atom. In the third O site, O(4) is bonded in a distorted bent 120 degrees geometry to one C(12) and one H(1) atom. In the fourth O site, O(1) is bonded in a single-bond geometry to one C(6) atom. Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. Linkers: 1 [O]C(=O)CCN1C=CN([Zn@@](Cl)(OC(=O)CCn2ccnc2-c2nccn2CCC(=O)O)N2C=CN(CCC(=O)O)[C]2c2nccn2CCC([O])=O)[C]1c1nccn1CC[C]O ,1 [CH]Cn1ccnc1[C]1N(CCC(=O)O)C=CN1[Zn@](Cl)(OC(=O)CCn1ccnc1-c1nccn1CCC(=O)O)N1C=CN(CCC([O])=O)[C]1c1nccn1CCC(=O)O ,1 [O]C(=O)CCN1C=CN([Zn@@](Cl)(OC(=O)CCn2ccnc2-c2nccn2CCC(=O)O)N2C=CN(CCC(=O)O)[C]2c2nccn2CCC([O])=O)[C]1c1nccn1CCC(=O)O ,1 [CH]N(CCC(=O)O[Zn@@](Cl)(N1C=CN(CC[C]O)[C]1c1nccn1CCC([O])=O)N1C=CN(CCC([O])=O)[C]1c1nccn1CCC(=O)O)C(=[N])c1nccn1CCC(=O)O ,1 [CH]CN1C=CN([Zn@@](Cl)(OC(=O)CCn2ccnc2[C][N])N2C=CN(CCC(=O)O)[C]2c2nccn2CCC([O])=O)[C]1c1nccn1CCC(=O)O. Metal clusters: 3 [Zn]. The MOF has largest included sphere 2.42 A, density 1.70 g/cm3, surface area 4426.26 m2/g, accessible volume 0.18 cm3/g