CuC6NH5O3CHCH2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four 02329_fluka molecules, and one CuC6NH5O3 cluster. In the CuC6NH5O3 cluster, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 6-coordinate geometry to one N(1), one O(1), one O(12), one O(2), one O(3), and one O(5) atom. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-O(1) bond length is 2.01 Å. The Cu(1)-O(12) bond length is 2.47 Å. The Cu(1)-O(2) bond length is 2.62 Å. The Cu(1)-O(3) bond length is 1.95 Å. The Cu(1)-O(5) bond length is 1.96 Å. In the second Cu site, Cu(2) is bonded in a 6-coordinate geometry to one N(2), one O(1), one O(11), one O(2), one O(4), and one O(6) atom. The Cu(2)-N(2) bond length is 1.98 Å. The Cu(2)-O(1) bond length is 2.57 Å. The Cu(2)-O(11) bond length is 2.51 Å. The Cu(2)-O(2) bond length is 1.99 Å. The Cu(2)-O(4) bond length is 1.96 Å. The Cu(2)-O(6) bond length is 1.96 Å. In the third Cu site, Cu(3) is bonded in a 6-coordinate geometry to one N(3), one O(2), one O(3), one O(4), one O(7), and one O(9) atom. The Cu(3)-N(3) bond length is 1.97 Å. The Cu(3)-O(2) bond length is 1.95 Å. The Cu(3)-O(3) bond length is 2.00 Å. The Cu(3)-O(4) bond length is 2.59 Å. The Cu(3)-O(7) bond length is 1.96 Å. The Cu(3)-O(9) bond length is 2.49 Å. In the fourth Cu site, Cu(4) is bonded in a 6-coordinate geometry to one N(4), one O(1), one O(10), one O(3), one O(4), and one O(8) atom. The Cu(4)-N(4) bond length is 1.98 Å. The Cu(4)-O(1) bond length is 1.96 Å. The Cu(4)-O(10) bond length is 2.49 Å. The Cu(4)-O(3) bond length is 2.60 Å. The Cu(4)-O(4) bond length is 2.00 Å. The Cu(4)-O(8) bond length is 1.96 Å. There are twenty inequivalent C sites. In the first C site, C(1,4) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(1) atom. The C(1,4)-C(5) bond length is 1.39 Å. The C(1,4)-N(1) bond length is 1.35 Å. The C(1,4)-H(1) bond length is 1.09 Å. In the second C site, C(2,3) is bonded in a distorted trigonal planar geometry to one C(6), one N(2), and one H(2) atom. The C(2,3)-C(6) bond length is 1.39 Å. The C(2,3)-N(2) bond length is 1.35 Å. The C(2,3)-H(2) bond length is 1.09 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(1,4) and one H(5,6,7,8) atom. The C(5)-H(5,6,7,8) bond length is 1.09 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(2,3) and one H(5,6,7,8) atom. The C(6)-H(5,6,7,8) bond length is 1.09 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(2,3) and one H(5,6,7,8) atom. The C(7)-C(2,3) bond length is 1.39 Å. The C(7)-H(5,6,7,8) bond length is 1.09 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(1,4) and one H(5,6,7,8) atom. The C(8)-C(1,4) bond length is 1.39 Å. The C(8)-H(5,6,7,8) bond length is 1.09 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(17,20) and one H(13,16) atom. The C(13)-C(17,20) bond length is 1.40 Å. The C(13)-H(13,16) bond length is 1.09 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(18,19) and one H(14,15) atom. The C(14)-C(18,19) bond length is 1.40 Å. The C(14)-H(14,15) bond length is 1.09 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(18,19) and one H(14,15) atom. The C(15)-C(18,19) bond length is 1.40 Å. The C(15)-H(14,15) bond length is 1.09 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17,20) and one H(13,16) atom. The C(16)-C(17,20) bond length is 1.40 Å. The C(16)-H(13,16) bond length is 1.09 Å. In the eleventh C site, C(17,20) is bonded in a distorted trigonal planar geometry to one C(13), one C(21), and one N(1) atom. The C(17,20)-C(21) bond length is 1.51 Å. The C(17,20)-N(1) bond length is 1.35 Å. In the twelfth C site, C(18,19) is bonded in a distorted trigonal planar geometry to one C(14), one C(22), and one N(2) atom. The C(18,19)-C(22) bond length is 1.51 Å. The C(18,19)-N(2) bond length is 1.35 Å. In the thirteenth C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one C(17,20); one H(17,20); one H(21,24); and one O(1) atom. The C(21)-H(17,20) bond length is 1.11 Å. The C(21)-H(21,24) bond length is 1.11 Å. The C(21)-O(1) bond length is 1.40 Å. In the fourteenth C site, C(22) is bonded in a distorted trigonal non-coplanar geometry to one C(18,19); one H(18,19); one H(22,23); and one O(2) atom. The C(22)-H(18,19) bond length is 1.11 Å. The C(22)-H(22,23) bond length is 1.11 Å. The C(22)-O(2) bond length is 1.40 Å. In the fifteenth C site, C(23) is bonded in a distorted trigonal non-coplanar geometry to one C(18,19); one H(18,19); one H(22,23); and one O(3) atom. The C(23)-C(18,19) bond length is 1.51 Å. The C(23)-H(18,19) bond length is 1.11 Å. The C(23)-H(22,23) bond length is 1.11 Å. The C(23)-O(3) bond length is 1.40 Å. In the sixteenth C site, C(24) is bonded in a distorted trigonal non-coplanar geometry to one C(17,20); one H(17,20); one H(21,24); and one O(4) atom. The C(24)-C(17,20) bond length is 1.51 Å. The C(24)-H(17,20) bond length is 1.11 Å. The C(24)-H(21,24) bond length is 1.11 Å. The C(24)-O(4) bond length is 1.40 Å. In the seventeenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(9) atom. The C(25)-O(5) bond length is 1.30 Å. The C(25)-O(9) bond length is 1.25 Å. In the eighteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(6) atom. The C(26)-O(10) bond length is 1.25 Å. The C(26)-O(6) bond length is 1.30 Å. In the nineteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(7) atom. The C(27)-O(11) bond length is 1.25 Å. The C(27)-O(7) bond length is 1.30 Å. In the twentieth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one O(12) and one O(8) atom. The C(28)-O(12) bond length is 1.25 Å. The C(28)-O(8) bond length is 1.30 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1); one C(1,4); and one C(17,20) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2); one C(18,19); and one C(2,3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(3); one C(18,19); and one C(2,3) atom. The N(3)-C(18,19) bond length is 1.35 Å. The N(3)-C(2,3) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(4); one C(1,4); and one C(17,20) atom. The N(4)-C(1,4) bond length is 1.35 Å. The N(4)-C(17,20) bond length is 1.35 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1,4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2,3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2,3) atom. The H(3)-C(2,3) bond length is 1.09 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1,4) atom. The H(4)-C(1,4) bond length is 1.09 Å. In the fifth H site, H(5,6,7,8) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(13,16) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(14,15) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(17,20) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(18,19) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(21,24) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(22,23) is bonded in a single-bond geometry to one C(22) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(2), one Cu(4), and one C(21) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(2), one Cu(3), and one C(22) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(3), one Cu(4), and one C(23) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Cu(2), one Cu(3), one Cu(4), and one C(24) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(25) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(26) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(27) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(28) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Cu(3) and one C(25) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Cu(4) and one C(26) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Cu(2) and one C(27) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Cu(1) and one C(28) atom. Linkers: 2 [O]C(=O)CCC([O])=O. Metal clusters: 4 [Cu]. The MOF has largest included sphere 4.57 A, density 1.70 g/cm3, surface area 3998.32 m2/g, accessible volume 0.12 cm3/g