CdC26H18(NO2)2(CH)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CdC26H18(NO2)2 clusters. In each CdC26H18(NO2)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(4), one O(1), one O(4), one O(5), and one O(8) atom. The Cd(1)-N(1) bond length is 2.30 Å. The Cd(1)-N(4) bond length is 2.30 Å. The Cd(1)-O(1) bond length is 2.65 Å. The Cd(1)-O(4) bond length is 2.65 Å. The Cd(1)-O(5) bond length is 2.28 Å. The Cd(1)-O(8) bond length is 2.28 Å. There are sixteen inequivalent C sites. In the first C site, C(1,4) is bonded in a distorted bent 120 degrees geometry to one C(5,8); one O(1); and one O(5) atom. The C(1,4)-C(5,8) bond length is 1.50 Å. The C(1,4)-O(1) bond length is 1.26 Å. The C(1,4)-O(5) bond length is 1.29 Å. In the second C site, C(5,8) is bonded in a trigonal planar geometry to one C(1,4); one C(25,26,27,28); and one C(9,10,11,12) atom. The C(5,8)-C(25,26,27,28) bond length is 1.40 Å. The C(5,8)-C(9,10,11,12) bond length is 1.40 Å. In the third C site, C(9,10,11,12) is bonded in a distorted single-bond geometry to one C(13,14,15,16); one C(5,8); and one H(1,2,3,4) atom. The C(9,10,11,12)-C(13,14,15,16) bond length is 1.41 Å. The C(9,10,11,12)-H(1,2,3,4) bond length is 1.09 Å. In the fourth C site, C(13,14,15,16) is bonded in a trigonal planar geometry to one C(17,18,19,20); one C(29,30,31,32); and one C(9,10,11,12) atom. The C(13,14,15,16)-C(17,18,19,20) bond length is 1.41 Å. The C(13,14,15,16)-C(29,30,31,32) bond length is 1.46 Å. In the fifth C site, C(17,18,19,20) is bonded in a distorted single-bond geometry to one C(13,14,15,16) and one H(5,6,7,8) atom. The C(17,18,19,20)-H(5,6,7,8) bond length is 1.09 Å. In the sixth C site, C(25,26,27,28) is bonded in a distorted single-bond geometry to one C(5,8) and one H(13,14,15,16) atom. The C(25,26,27,28)-H(13,14,15,16) bond length is 1.09 Å. In the seventh C site, C(29,30,31,32) is bonded in a distorted single-bond geometry to one C(13,14,15,16) and one H(17,18,19,20) atom. The C(29,30,31,32)-H(17,18,19,20) bond length is 1.09 Å. In the eighth C site, C(33,34) is bonded in a distorted single-bond geometry to one C(37,40) and one H(21,22,23,24) atom. The C(33,34)-C(37,40) bond length is 1.45 Å. The C(33,34)-H(21,22,23,24) bond length is 1.09 Å. In the ninth C site, C(36) is bonded in a distorted single-bond geometry to one C(37,40) and one H(21,22,23,24) atom. The C(36)-C(37,40) bond length is 1.45 Å. The C(36)-H(21,22,23,24) bond length is 1.09 Å. In the tenth C site, C(37,40) is bonded in a trigonal planar geometry to one C(33,34); one C(41,42); and one C(53,54) atom. The C(37,40)-C(41,42) bond length is 1.41 Å. The C(37,40)-C(53,54) bond length is 1.41 Å. In the eleventh C site, C(41,42) is bonded in a distorted single-bond geometry to one C(37,40); one C(45,48); and one H(25,27,28) atom. The C(41,42)-C(45,48) bond length is 1.39 Å. The C(41,42)-H(25,27,28) bond length is 1.09 Å. In the twelfth C site, C(44) is bonded in a distorted single-bond geometry to one C(37,40); one C(45,48); and one H(25,27,28) atom. The C(44)-C(37,40) bond length is 1.41 Å. The C(44)-C(45,48) bond length is 1.39 Å. The C(44)-H(25,27,28) bond length is 1.09 Å. In the thirteenth C site, C(45,48) is bonded in a distorted trigonal planar geometry to one C(41,42); one N(1); and one H(29,30,31,32) atom. The C(45,48)-N(1) bond length is 1.35 Å. The C(45,48)-H(29,30,31,32) bond length is 1.09 Å. In the fourteenth C site, C(49,52) is bonded in a distorted trigonal planar geometry to one C(53,54); one N(1); and one H(33,34,35) atom. The C(49,52)-C(53,54) bond length is 1.39 Å. The C(49,52)-N(1) bond length is 1.35 Å. The C(49,52)-H(33,34,35) bond length is 1.09 Å. In the fifteenth C site, C(53,54) is bonded in a distorted single-bond geometry to one C(37,40); one C(49,52); and one H(37,38,40) atom. The C(53,54)-H(37,38,40) bond length is 1.09 Å. In the sixteenth C site, C(56) is bonded in a distorted single-bond geometry to one C(37,40); one C(49,52); and one H(37,38,40) atom. The C(56)-C(37,40) bond length is 1.41 Å. The C(56)-C(49,52) bond length is 1.39 Å. The C(56)-H(37,38,40) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1); one C(45,48); and one C(49,52) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cd(1); one C(45,48); and one C(49,52) atom. The N(4)-C(45,48) bond length is 1.35 Å. The N(4)-C(49,52) bond length is 1.35 Å. There are ten inequivalent H sites. In the first H site, H(1,2,3,4) is bonded in a single-bond geometry to one C(9,10,11,12) atom. In the second H site, H(5,6,7,8) is bonded in a single-bond geometry to one C(17,18,19,20) atom. In the third H site, H(13,14,15,16) is bonded in a single-bond geometry to one C(25,26,27,28) atom. In the fourth H site, H(17,18,19,20) is bonded in a single-bond geometry to one C(29,30,31,32) atom. In the fifth H site, H(21,22,23,24) is bonded in a single-bond geometry to one C(33,34) atom. In the sixth H site, H(25,27,28) is bonded in a single-bond geometry to one C(41,42) atom. In the seventh H site, H(29,30,31,32) is bonded in a single-bond geometry to one C(45,48) atom. In the eighth H site, H(33,34,35) is bonded in a single-bond geometry to one C(49,52) atom. In the ninth H site, H(36) is bonded in a single-bond geometry to one C(49,52) atom. The H(36)-C(49,52) bond length is 1.09 Å. In the tenth H site, H(37,38,40) is bonded in a single-bond geometry to one C(53,54) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cd(1) and one C(1,4) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Cd(1) and one C(1,4) atom. The O(4)-C(1,4) bond length is 1.26 Å. In the third O site, O(5) is bonded in a distorted water-like geometry to one Cd(1) and one C(1,4) atom. In the fourth O site, O(8) is bonded in a distorted water-like geometry to one Cd(1) and one C(1,4) atom. The O(8)-C(1,4) bond length is 1.29 Å. Linkers: 2 [O]C(=O)c1cccc(/C=C/c2ccncc2)c1. Metal clusters: 1 O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 2.25 A, density 1.64 g/cm3, surface area 4411.40 m2/g, accessible volume 0.14 cm3/g