ZnC28H24(NO)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC28H24(NO)4 clusters. Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Zn(1)-N(1) bond length is 2.02 Å. The Zn(1)-N(2) bond length is 2.02 Å. The Zn(1)-O(1) bond length is 1.98 Å. The Zn(1)-O(2) bond length is 1.98 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(3) bond length is 1.35 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(4), and one H(2) atom. The C(2)-N(2) bond length is 1.33 Å. The C(2)-N(4) bond length is 1.35 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(5,6); one N(1); and one H(3,4) atom. The C(3)-C(5,6) bond length is 1.37 Å. The C(3)-N(1) bond length is 1.38 Å. The C(3)-H(3,4) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5,6); one N(2); and one H(3,4) atom. The C(4)-C(5,6) bond length is 1.37 Å. The C(4)-N(2) bond length is 1.38 Å. The C(4)-H(3,4) bond length is 1.08 Å. In the fifth C site, C(5,6) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(3), and one H(5) atom. The C(5,6)-N(3) bond length is 1.38 Å. The C(5,6)-H(5) bond length is 1.08 Å. In the sixth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one N(3), one H(7), and one H(9) atom. The C(7)-C(9) bond length is 1.51 Å. The C(7)-N(3) bond length is 1.46 Å. The C(7)-H(7) bond length is 1.10 Å. The C(7)-H(9) bond length is 1.10 Å. In the seventh C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one N(4), one H(10), and one H(8) atom. The C(8)-C(10) bond length is 1.51 Å. The C(8)-N(4) bond length is 1.46 Å. The C(8)-H(10) bond length is 1.10 Å. The C(8)-H(8) bond length is 1.10 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(11), one C(19), and one C(7) atom. The C(9)-C(11) bond length is 1.40 Å. The C(9)-C(19) bond length is 1.40 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(12), one C(20), and one C(8) atom. The C(10)-C(12) bond length is 1.40 Å. The C(10)-C(20) bond length is 1.40 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one H(11) atom. The C(11)-C(13) bond length is 1.40 Å. The C(11)-H(11) bond length is 1.09 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(10), one C(14), and one H(12) atom. The C(12)-C(14) bond length is 1.40 Å. The C(12)-H(12) bond length is 1.09 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(11), one C(15), and one H(13) atom. The C(13)-C(15) bond length is 1.40 Å. The C(13)-H(13) bond length is 1.09 Å. In the thirteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(12), one C(16), and one H(14) atom. The C(14)-C(16) bond length is 1.40 Å. The C(14)-H(14) bond length is 1.09 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(13) and one H(15) atom. The C(15)-H(15) bond length is 1.09 Å. In the fifteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one H(16) atom. The C(16)-C(18) bond length is 1.40 Å. The C(16)-H(16) bond length is 1.09 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(19) and one H(17) atom. The C(17)-C(19) bond length is 1.40 Å. The C(17)-H(17) bond length is 1.09 Å. In the seventeenth C site, C(18) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one H(18) atom. The C(18)-C(20) bond length is 1.40 Å. The C(18)-H(18) bond length is 1.09 Å. In the eighteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(17), one C(9), and one H(19) atom. The C(19)-H(19) bond length is 1.09 Å. In the nineteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(10), one C(18), and one H(20) atom. The C(20)-H(20) bond length is 1.09 Å. In the twentieth C site, C(21,22) is bonded in a bent 120 degrees geometry to one C(23), one O(1), and one O(3) atom. The C(21,22)-C(23) bond length is 1.50 Å. The C(21,22)-O(1) bond length is 1.31 Å. The C(21,22)-O(3) bond length is 1.25 Å. In the twenty-first C site, C(23) is bonded in a trigonal planar geometry to one C(21,22); one C(25,26); and one C(27,28) atom. The C(23)-C(25,26) bond length is 1.40 Å. The C(23)-C(27,28) bond length is 1.40 Å. In the twenty-second C site, C(24) is bonded in a trigonal planar geometry to one C(21,22); one C(25,26); and one C(27,28) atom. The C(24)-C(21,22) bond length is 1.50 Å. The C(24)-C(25,26) bond length is 1.40 Å. The C(24)-C(27,28) bond length is 1.40 Å. In the twenty-third C site, C(25,26) is bonded in a distorted single-bond geometry to one C(23) and one H(21) atom. The C(25,26)-H(21) bond length is 1.09 Å. In the twenty-fourth C site, C(27,28) is bonded in a distorted single-bond geometry to one C(23) and one H(23) atom. The C(27,28)-H(23) bond length is 1.09 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(2), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1); one C(5,6); and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(2); one C(5,6); and one C(8) atom. The N(4)-C(5,6) bond length is 1.38 Å. There are twenty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(5,6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(5,6) atom. The H(6)-C(5,6) bond length is 1.08 Å. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the twentieth H site, H(21) is bonded in a single-bond geometry to one C(25,26) atom. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one C(25,26) atom. The H(22)-C(25,26) bond length is 1.09 Å. In the twenty-second H site, H(23) is bonded in a single-bond geometry to one C(27,28) atom. In the twenty-third H site, H(24) is bonded in a single-bond geometry to one C(27,28) atom. The H(24)-C(27,28) bond length is 1.09 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(21,22) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(21,22) atom. The O(2)-C(21,22) bond length is 1.31 Å. In the third O site, O(3) is bonded in a single-bond geometry to one C(21,22) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(21,22) atom. The O(4)-C(21,22) bond length is 1.25 Å. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 2.03 A, density 1.48 g/cm3, surface area 5419.11 m2/g, accessible volume 0.17 cm3/g